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Sample records for parent material soil

  1. Soil Inorganic Carbon Formation: Can Parent Material Overcome Climate?

    NASA Astrophysics Data System (ADS)

    Stanbery, C.; Will, R. M.; Seyfried, M. S.; Benner, S. G.; Flores, A. N.; Guilinger, J.; Lohse, K. A.; Good, A.; Black, C.; Pierce, J. L.

    2014-12-01

    Soil carbon is the third largest carbon reservoir and is composed of both organic and inorganic constituents. However, the storage and flux of soil carbon within the global carbon cycle are not fully understood. While organic carbon is often the focus of research, the factors controlling the formation and dissolution of soil inorganic carbon (SIC) are complex. Climate is largely accepted as the primary control on SIC, but the effects of soil parent material are less clear. We hypothesize that effects of parent material are significant and that SIC accumulation will be greater in soils formed from basalts than granites due to the finer textured soils and more abundant calcium and magnesium cations. This research is being conducted in the Reynolds Creek Experimental Watershed (RCEW) in southwestern Idaho. The watershed is an ideal location because it has a range of gradients in precipitation (250 mm to 1200 mm), ecology (sagebrush steppe to juniper), and parent materials (a wide array of igneous and sedimentary rock types) over a relatively small area. Approximately 20 soil profiles will be excavated throughout the watershed and will capture the effects of differing precipitation amounts and parent material on soil characteristics. Several samples at each site will be collected for analysis of SIC content and grain size distribution using a pressure calcimeter and hydrometers, respectively. Initial field data suggests that soils formed over basalts have a higher concentration of SIC than those on granitic material. If precipitation is the only control on SIC, we would expect to see comparable amounts in soils formed on both rock types within the same precipitation zone. However, field observations suggest that for all but the driest sites, soils formed over granite had no SIC detected while basalt soils with comparable precipitation had measurable amounts of SIC. Grain size distribution appears to be a large control on SIC as the sandier, granitic soils promote

  2. Dryland soil microbial communities display spatial biogeographic patterns associated with soil depth and soil parent material

    USGS Publications Warehouse

    Steven, Blaire; Gallegos-Graves, La Verne; Belnap, Jayne; Kuske, Cheryl R.

    2013-01-01

    Biological soil crusts (biocrusts) are common to drylands worldwide. We employed replicated, spatially nested sampling and 16S rRNA gene sequencing to describe the soil microbial communities in three soils derived from different parent material (sandstone, shale, and gypsum). For each soil type, two depths (biocrusts, 0–1 cm; below-crust soils, 2–5 cm) and two horizontal spatial scales (15 cm and 5 m) were sampled. In all three soils, Cyanobacteria and Proteobacteria demonstrated significantly higher relative abundance in the biocrusts, while Chloroflexi and Archaea were significantly enriched in the below-crust soils. Biomass and diversity of the communities in biocrusts or below-crust soils did not differ with soil type. However, biocrusts on gypsum soil harbored significantly larger populations of Actinobacteria and Proteobacteria and lower populations of Cyanobacteria. Numerically dominant operational taxonomic units (OTU; 97% sequence identity) in the biocrusts were conserved across the soil types, whereas two dominant OTUs in the below-crust sand and shale soils were not identified in the gypsum soil. The uniformity with which small-scale vertical community differences are maintained across larger horizontal spatial scales and soil types is a feature of dryland ecosystems that should be considered when designing management plans and determining the response of biocrusts to environmental disturbances.

  3. Dryland soil microbial communities display spatial biogeographic patterns associated with soil depth and soil parent material.

    PubMed

    Steven, Blaire; Gallegos-Graves, La Verne; Belnap, Jayne; Kuske, Cheryl R

    2013-10-01

    Biological soil crusts (biocrusts) are common to drylands worldwide. We employed replicated, spatially nested sampling and 16S rRNA gene sequencing to describe the soil microbial communities in three soils derived from different parent material (sandstone, shale, and gypsum). For each soil type, two depths (biocrusts, 0-1 cm; below-crust soils, 2-5 cm) and two horizontal spatial scales (15 cm and 5 m) were sampled. In all three soils, Cyanobacteria and Proteobacteria demonstrated significantly higher relative abundance in the biocrusts, while Chloroflexi and Archaea were significantly enriched in the below-crust soils. Biomass and diversity of the communities in biocrusts or below-crust soils did not differ with soil type. However, biocrusts on gypsum soil harbored significantly larger populations of Actinobacteria and Proteobacteria and lower populations of Cyanobacteria. Numerically dominant operational taxonomic units (OTU; 97% sequence identity) in the biocrusts were conserved across the soil types, whereas two dominant OTUs in the below-crust sand and shale soils were not identified in the gypsum soil. The uniformity with which small-scale vertical community differences are maintained across larger horizontal spatial scales and soil types is a feature of dryland ecosystems that should be considered when designing management plans and determining the response of biocrusts to environmental disturbances. PMID:23621290

  4. Parental material and cultivation determine soil bacterial community structure and fertility.

    PubMed

    Sun, Li; Gao, Jusheng; Huang, Ting; Kendall, Joshua R A; Shen, Qirong; Zhang, Ruifu

    2015-01-01

    Microbes are the key components of the soil environment, playing important roles during soil development. Soil parent material provides the foundation elements that comprise the basic nutritional environment for the development of microbial community. After 30 years artificial maturation of cultivation, the soil developments of three different parental materials were evaluated and bacterial community compositions were investigated using the high-throughput sequencing approach. Thirty years of cultivation increased the soil fertility and soil microbial biomass, richness and diversity, greatly changed the soil bacterial communities, the proportion of phylum Actinobacteria decreased significantly, while the relative abundances of the phyla Acidobacteria, Chloroflexi, Gemmatimonadetes, Armatimonadetes and Nitrospira were significantly increased. Soil bacterial communities of parental materials were separated with the cultivated ones, and comparisons of different soil types, granite soil and quaternary red clay soil were similar and different with purple sandy shale soil in both parental materials and cultivated treatments. Bacterial community variations in the three soil types were affected by different factors, and their alteration patterns in the soil development also varied with soil type. Soil properties (except total potassium) had a significant effect on the soil bacterial communities in all three soil types and a close relationship with abundant bacterial phyla. The amounts of nitrogen-fixing bacteria as well as the abundances of the nifH gene in all cultivated soils were higher than those in the parental materials; Burkholderia and Rhizobacte were enriched significantly with long-term cultivation. The results suggested that crop system would not deplete the nutrients of soil parental materials in early stage of soil maturation, instead it increased soil fertility and changed bacterial community, specially enriched the nitrogen-fixing bacteria to accumulate

  5. Climatic controls on soil hydraulic properties along soil chronosequences on volcanic parent material

    NASA Astrophysics Data System (ADS)

    Beal, L. K.; Lohse, K. A.; Godsey, S.; Huber, D. P.

    2013-12-01

    . We observe that θ decreases with age, and α occurs at higher tensions. Soil horizons are developed dominantly on the cinder cones. These model estimates appear to match well with preliminary field measurements. Tropical climates enhance the weathering of basaltic parent material. The mean annual precipitation in the Hawaiian site is 2500 mm, and 310 mm at COTM. Accumulation of rainfall increases the weathering rate of the parent material. Using previous work characterizing the physical characteristics of soil across the Hawaii chronosequence to model the contrasting soils, we found that the 0.3 and 20 ka Hawaii soils had similar hydraulic properties; θ values were approximately 0.45 cm3/cm3 and Ks values were 6 cm/hr. However, these Hawaiian soils contrasted and were quantitatively lower than the entire COTM chronosequence. At the 2.1 ka COTM soil, Ks was 17 cm/hr and θ was 0.52-0.65 cm3/cm3 whereas at the 13.9 ka soil, Ks was 12 cm/hr and θ was 0.52 cm3/cm3. The 0.3 ka Hawaiian soil had a 20-30% higher silt content than the 2.1 ka COTM soil. Our models help quantify rates of soil development and hydraulic properties developed through time on volcanic parent materials.

  6. Nature and properties of lateritic soils derived from different parent materials in Taiwan.

    PubMed

    Ko, Tzu-Hsing

    2014-01-01

    The objective of this study was to investigate the physical, chemical, and mineralogical composition of lateritic soils in order to use these soils as potential commercial products for industrial application in the future. Five lateritic soils derived from various parent materials in Taiwan, including andesite, diluvium, shale stone, basalt, and Pleistocene deposit, were collected from the Bt1 level of soil samples. Based on the analyses, the Tungwei soil is an alfisol, whereas other lateritic soils are ultisol. Higher pH value of Tungwei is attributed to the large amounts of Ca(2+) and Mg(2+). Loupi and Pingchen soils would be the older lateritic soils because of the lower active iron ratio. For the iron minerals, the magnetic iron oxides such as major amounts of magnetite and maghemite were found for Tamshui and Tungwei lateritic soils, respectively. Lepidocrocite was only found in Soka soil and intermediate amounts of goethite were detected for Loupi and Pingchen soils. After Mg-saturated and K-saturated processes, major amounts of mixed layer were observed in Loupi and Soka soils, whereas the montmorillonite was only detected in Tungwei soil. The investigation results revealed that the parent materials would play an important role during soil weathering process and physical, chemical, and mineralogy compositions strongly affect the formation of lateritic soils. PMID:24883366

  7. Nature and Properties of Lateritic Soils Derived from Different Parent Materials in Taiwan

    PubMed Central

    2014-01-01

    The objective of this study was to investigate the physical, chemical, and mineralogical composition of lateritic soils in order to use these soils as potential commercial products for industrial application in the future. Five lateritic soils derived from various parent materials in Taiwan, including andesite, diluvium, shale stone, basalt, and Pleistocene deposit, were collected from the Bt1 level of soil samples. Based on the analyses, the Tungwei soil is an alfisol, whereas other lateritic soils are ultisol. Higher pH value of Tungwei is attributed to the large amounts of Ca2+ and Mg2+. Loupi and Pingchen soils would be the older lateritic soils because of the lower active iron ratio. For the iron minerals, the magnetic iron oxides such as major amounts of magnetite and maghemite were found for Tamshui and Tungwei lateritic soils, respectively. Lepidocrocite was only found in Soka soil and intermediate amounts of goethite were detected for Loupi and Pingchen soils. After Mg-saturated and K-saturated processes, major amounts of mixed layer were observed in Loupi and Soka soils, whereas the montmorillonite was only detected in Tungwei soil. The investigation results revealed that the parent materials would play an important role during soil weathering process and physical, chemical, and mineralogy compositions strongly affect the formation of lateritic soils. PMID:24883366

  8. Controls of Parent Material and Topography on Soil Carbon Storage in the Critical Zone

    NASA Astrophysics Data System (ADS)

    Patton, N. R.; Seyfried, M. S.; Lohse, K. A.; Link, T. E.

    2014-12-01

    Semi-arid environments make up a large percentage of the world's terrestrial ecosystems, and climate is a major factor influencing soil carbon storage and release. However, the roles of local controls such as parent material, aspect and microtopography have received less attention and are important for consideration in soil carbon modeling. The purpose of this study is to understand the role that parent material, aspect and micro-topography play in storage and release of soil carbon along an elevation gradient in a semi-arid climate. Johnston Draw (JD) is a first order watershed within the Reynolds Creek Critical Zone Observatory in southwestern Idaho with underlining late cretaceous, granitic Idaho batholith bedrock. Upper Sheep Creek (USC) is a first order watershed consisting of basalt. Both watersheds were chosen for this project due to similar size, aspect, elevation, vegetation and for the contrast in parent material. Two transects, totaling approximately nine soil pits, were excavated on both the north and south facing slopes of each watershed running parallel to the water channel. Soil carbon was generally higher in basalt compared to the granite parent material in pits with similar aspect, elevation and vegetation. Preliminary data using soil organic matter (SOM) as a proxy for organic carbon (OC) and soil water dynamics showed that percent OC declines markedly with elevation in JD and soil depth at lower elevations and is more homogenous throughout the profile moving up elevation (1646 meters 4.3-9.7%; 1707 meters 6.87-3.83%). Similarly, aspect controls patterns of SOM at depth more strongly at lower elevations. Findings from our study suggest that parent material and topography may play as important roles in semi-arid ecosystems as climate factors in controlling soil carbon storage.

  9. Assessment of soil parent material formation in periglacial environments through medium scale landscape evolution modelling

    NASA Astrophysics Data System (ADS)

    Bock, M.; Günther, A.; Ringeler, A.; Baritz, R.; Böhner, J.

    2012-04-01

    Soil parental materials represent the weathering product of any surficial geological substrates comprising in-situ fragmented and dissolved rocks, unconsolidated sediments of various types and origins, or even paleosoils. Weathering, erosion, transport and accumulation processes of geological materials governing the formation of soil parent materials display a highly complex non-linear behaviour at larger spatial scales over smaller geological time periods (< 50.000 years) in lithologically complex settings. This is particularly evident in periglacial environments where regional allochthonous sediment supply contributes to soil parent material formation. We propose a GIS implementation of a landscape evolution model (LEM) for the spatiotemporal investigation of soil parent material evolution following a lithologically differentiated approach. The well-established LEM tool GOLEM has been adapted and realized as a module for the open-source GIS SAGA to operate in a spatially distributed framework, taking advantage of the highly developed capabilities of SAGA for morphometric digital terrain analysis. The LEM is driven by high-resolution paleo-climatic data (temperature, precipitation) representative for periglacial areas in Northern Germany over the last 50.000 years. The initial conditions of the LEM are determined for a test site by a digital terrain model and a geological model. The geological model was parameterized through geological field data derived from rock mass rating procedures and soft sediment analyses to account for a lithologically differentiated LEM set up with respect to first-order mechanical properties of both rock-type and unconsolidated lithologies. Weathering, erosion and transport functions of the LEM are calibrated using the extrinsic (climatic) and intrinsic (lithology) parameter data. First results indicate that our differentiated LEM-based approach displays some evidence for the spatiotemporal prediction of important soil parental material

  10. Soil deepening by trees and the effects of parent material

    NASA Astrophysics Data System (ADS)

    Shouse, Michael; Phillips, Jonathan

    2016-09-01

    In some cases biomechanical effects of individual trees may locally deepen or thicken regolith, especially in relatively shallow soils. This biogeomorphic ecosystem engineering phenomenon is at least partly contingent on the geological setting. The purpose of this research was to gain further insight into the biogeomorphic phenomenon, and to assess the relative importance of biomechanical and geological effects. Earlier studies in the Ouachita Mountains of Arkansas showed that individual trees locally thicken the regolith via mechanisms associated with root penetration of bedrock. However, that work was conducted mainly in areas of strongly dipping and contorted rock, where joints and bedding planes susceptible to root penetration were thought to be common and accessible. This project extended the research to the Cumberland Plateau region of Kentucky, where flat, level-bedded sedimentary rocks are dominant. Soil depth beneath trees was compared to that of non-tree sites by measuring depth to bedrock beneath rotted tree stumps and at adjacent sites with 1.0 m. While soil thickness beneath stumps was greater in the Ouachita Mountains compared to the Kentucky sites, in both regions soils beneath stumps are significantly deeper than adjacent soils. Further, there were no statistically significant differences in the difference between stump and adjacent sites between the two regions. This suggests the local deepening effects of trees occur in flat-bedded as well as steeply dipping lithologies.

  11. A Linkage Between Parent Materials of Soil and Potential Risk of Heavy Metals in Yunnan province, China

    NASA Astrophysics Data System (ADS)

    Cheng, X.

    2015-12-01

    A large area exceeding soil quality standards for heavy metals in South western China has been identified previously reported on a nationwide survey of soil pollution, yet the ecological risk of heavy metal in soil is unknown or uncertainty.To assess thoroughly the ecological risk in this region, seven soil profiles with a depth of 2m on the different parent materials of soil were conducted in Yunnan province, China, and the level of total concentrations and the fraction of water soluble, ion exchangeable, carbonates, humic acid, iron and manganese oxides and organic matter of As, Cd, Hg and Pb was investigated in soil profiles. The results indicate that parent materials of soil critically influenced the ecological risk of heavy metal.The fraction of water soluble and ion exchangeable of Cd and Hg in alluvial material and in terrigenous clastic rocks showed 2-6 times higher than those in carbonate rock; As and Pb has almost same fraction of water soluble and ion exchangeable in three parent materials of soil.The findings suggest that parent materials of soil play a critical role in ecological risk of heavy metal.Thus, more studies are needed to better understand a linkage between the parent materials of soil, different soil-forming processes and the potential risk of heavy metals under various geographic conditions, which is the key for the evaluating soil quality and food safety. Those soils with high concentration of Cd and Hg originated alluvial material and terrigenous clastic rocks need to be continuously monitored before determining a cost-effective remediation technology. Keywords: Heavy metals; Ecological risk;Parent materials of soil;China

  12. Fe-C interactions and soil organic matter stability in two tropical soils of contrasting parent materials

    NASA Astrophysics Data System (ADS)

    Coward, E.; Thompson, A.; Plante, A. F.

    2014-12-01

    The long residence time of soil organic matter (SOM) is a dynamic property, reflecting the diversity of stabilization mechanisms active within the soil matrix. Climate and ecosystem properties act at the broadest scale, while biochemical recalcitrance, physical occlusion and mineral association drive stability at the microscale. Increasing evidence suggests that the stability of SOM is dominated by organo-mineral interactions. However, the 2:1 clays that provide much of the stabilization capacity in temperate soils are typically absent in tropical soils due to weathering. In contrast, these soils may contain an abundance of iron and aluminium oxides and oxyhydroxides, known as short-range-order (SRO) minerals. These SRO minerals are capable of SOM stabilization through adsorption or co-precipitation, a faculty largely enabled by their high specific surface area (SSA). As such, despite their relatively small mass, SRO minerals may contribute substantially to the SOM stabilization capacity of tropical soils. The objective of this work is to characterize and quantify these Fe-C interactions. Surface (0-20 cm) soil samples were taken from 20 quantitative soil pits dug within the Luquillo Critical Zone Observatory in northeast Puerto Rico. Soils were stratified across granodiorite and volcaniclastic parent materials. Four extraction procedures were used to isolate three different forms of Fe-C interactions: sodium pyrophosphate to isolate organo-metallic complexes, hydroxylamine and oxalate to isolate SRO Fe- and Al-hydroxides, and dithionite to isolate crystalline Fe-oxyhydroxides. Extracts were analysed for DOC and Fe and Al concentrations to estimate the amount of SOM associated with each mineral type. Soils were subjected to SSA and solid-phase C analyses before and after extraction to determine the contribution of the various Fe mineral types to soil SSA, and therefore to potential stabilization capacity through organo-mineral complexation. Preliminary results

  13. Unexpected dominance of parent-material strontium in a tropical forest on highly weathered soils

    USGS Publications Warehouse

    Bern, C.R.; Townsend, A.R.; Farmer, G.L.

    2005-01-01

    Controls over nutrient supply are key to understanding the structure and functioning of terrestrial ecosystems. Conceptual models once held that in situ mineral weathering was the primary long-term control over the availability of many plant nutrients, including the base cations calcium (Ca), magnesium (Mg), and potassium (K). Recent evidence has shown that atmospheric sources of these "rock-derived" nutrients can dominate actively cycling ecosystem pools, especially in systems on highly weathered soils. Such studies have relied heavily on the use of strontium isotopes as a proxy for base-cation cycling. Here we show that vegetation and soil-exchangeable pools of strontium in a tropical rainforest on highly weathered soils are still dominated by local rock sources. This pattern exists despite substantial atmospheric inputs of Sr, Ca, K, and Mg, and despite nearly 100% depletion of these elements from the top 1 m of soil. We present a model demonstrating that modest weathering inputs, resulting from tectonically driven erosion, could maintain parent-material dominance of actively cycling Sr. The majority of tropical forests are on highly weathered soils, but our results suggest that these forests may still show considerable variation in their primary sources of essential nutrients. ?? 2005 by the Ecological Society of America.

  14. Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

    USGS Publications Warehouse

    Klassen, R.A.

    2009-01-01

    As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

  15. Regional mapping of soil parent material by machine learning based on point data

    NASA Astrophysics Data System (ADS)

    Lacoste, Marine; Lemercier, Blandine; Walter, Christian

    2011-10-01

    A machine learning system (MART) has been used to predict soil parent material (SPM) at the regional scale with a 50-m resolution. The use of point-specific soil observations as training data was tested as a replacement for the soil maps introduced in previous studies, with the aim of generating a more even distribution of training data over the study area and reducing information uncertainty. The 27,020-km 2 study area (Brittany, northwestern France) contains mainly metamorphic, igneous and sedimentary substrates. However, superficial deposits (aeolian loam, colluvial and alluvial deposits) very often represent the actual SPM and are typically under-represented in existing geological maps. In order to calibrate the predictive model, a total of 4920 point soil descriptions were used as training data along with 17 environmental predictors (terrain attributes derived from a 50-m DEM, as well as emissions of K, Th and U obtained by means of airborne gamma-ray spectrometry, geological variables at the 1:250,000 scale and land use maps obtained by remote sensing). Model predictions were then compared: i) during SPM model creation to point data not used in model calibration (internal validation), ii) to the entire point dataset (point validation), and iii) to existing detailed soil maps (external validation). The internal, point and external validation accuracy rates were 56%, 81% and 54%, respectively. Aeolian loam was one of the three most closely predicted substrates. Poor prediction results were associated with uncommon materials and areas with high geological complexity, i.e. areas where existing maps used for external validation were also imprecise. The resultant predictive map turned out to be more accurate than existing geological maps and moreover indicated surface deposits whose spatial coverage is consistent with actual knowledge of the area. This method proves quite useful in predicting SPM within areas where conventional mapping techniques might be too

  16. Geochemical evidence of Saharan dust parent material for soils developed on Quaternary limestones of Caribbean and western Atlantic islands

    USGS Publications Warehouse

    Muhs, D.R.; Bush, C.A.; Stewart, K.C.; Rowland, T.R.; Crittenden, R.C.

    1990-01-01

    Most previous workers have regarded the insoluble residues of high-purity Quaternary limestones (coral reefs and oolites) as the most important parent material for well-developed, clay-rich soils on Caribbean and western Atlantic islands, but this genetic mechanism requires unreasonable amounts of limestone solution in Quaternary time. Other possible parent materials from external sources are volcanic ash from the Lesser Antilles island arc and Saharan dust carried across the Atlantic Ocean on the northeast trade winds. Soils on Quaternary coral terraces and carbonate eolianites on Barbados, Jamaica, the Florida Keys (United States), and New Providence Island (Bahamas) were studied to determine which, if either, external source was important. Caribbean volcanic ashes and Saharan dust can be clearly distinguished using ratios of relatively immobile elements ( Al2O3 TiO2, Ti Y, Ti Zr, and Ti Th). Comparison of these ratios in 25 soils, where estimated ages range from 125,000 to about 870,000 yr, shows that Saharan dust is the most important parent material for soils on all islands. These results indicate that the northeast trade winds have been an important component of the regional climatology for much of the Quaterary. Saharan dust may also be an important parent material for Caribbean island bauxites of much greater age. ?? 1990.

  17. Parent material, vegetation or slope position - which soil-forming factor controls the intensity of podzolization process in the soils of the Sudety Mountains montane zone?

    NASA Astrophysics Data System (ADS)

    Musielok, Łukasz

    2016-04-01

    Climatic conditions, parent material and vegetation type are considered to be the main soil-forming factors controlling podzolization process advancement. Moreover, in hilly and mountainous areas properties of soils that are undergoing podzolization process are influenced significantly by its location on a slope, due to lateral translocation of soil solutions. The Sudety Mts. are a medium-high mountain range characterized by geological mosaic with many different sedimentary, igneous and metamorphic rocks, mostly poor in alkali elements. Most of the Sudety Mts. area lies in a lower montane zone, where the dominant natural vegetation were temperate mixed and deciduous forests. However, since 18th century natural vegetation was significantly transformed by widespread introduction of spruce monocultures. These distinguishing features of the Sudety Mts. natural environment are considered to be responsible for prevalence of podzolized soil in this area, however the intensity of podzolization process is very differentiated. The aim of presented research was to determine the influence of varying parent material, different vegetation types and different slope positions the on the soil properties variability, and thus, to answer the question which of the analyzed soil-forming factors is controlling the podzolization process advancement in the Sudety Mountains montane zone? Data from A, E, Bs and C horizons of 16 soil profiles developed from different parent materials (granite, sandstone, andesites and mica schists), located under various types of vegetation (spruce and beech forests) and in different slope positions (upper, middle and lower parts of the slopes) were taken into the analysis. All analyzed soil profiles were located in lower montane zone between 550 and 950 m a. s. l. to avoid the influence of varying climatic conditions. One-way ANOVA and Principal Components Analysis (PCA) were used to analyze differentiation of soil texture, pH, organic carbon and nitrogen

  18. The importance of parent material information derived from globally available small scale legacy data for soil mapping at medium scale

    NASA Astrophysics Data System (ADS)

    Schuler, U.; Bock, M.; Günther, A.; Willer, J.; Pickert, E.; Asch, K.; Baritz, R.

    2012-04-01

    Up to now, harmonized global soil information is solely available from the FAO-Unesco Soil map of the world at 1:5M scale (FAO-Unesco 1974-1981). However, for monitoring global environmental changes and sustainable land resource management, higher resolution soil maps are urgently needed. At the global scale, the soil forming factors climate, soil parent material (SPM) and topography can be considered the most important parameters for spatial prediction of soil associations and their properties. While topographic and climatic information is available at high spatial resolutions, SPM information can only be derived from small-scale geological maps or soil maps. The objective of this study is to investigate the potential of commonly available SPM data derived from small scale soil and geological maps for soil mapping at the 1:250k scale. The study was conducted for a test site in Southern Saxony, Germany, 140*85 km wide, representing diverse soil landscapes. Additionally, SPM maps were derived from a reclassification of the geological overview map of Germany at 1:1M scale, and the European Soil database. The proposed SPM classification, developed in the framework of the EU-FP7 eSOTER project, is based on the degree of SPM consolidation, its geochemical character, and the major bedrock types. In addition, SPM-related surface processes are characterized since SPM is defined here as the original lithological material before the onset of weathering and soil formation processes. To assess the potential of SPM data for the spatial delineation of soil associations, random forest-based predictions of soils and its properties were carried out using relief attributes from digital elevation model data. Model runs were performed (i) with and (ii) without spatial information on SPM properties. The outputs were compared with independent soil information of model validation areas. Training and validation point data was selected from a comprehensive dataset representing more than 14

  19. Parent material and vegetation influence soil microbial community structure following 30-years of rock weathering and pedogenesis.

    PubMed

    Yarwood, Stephanie; Wick, Abbey; Williams, Mark; Daniels, W Lee

    2015-02-01

    The process of pedogenesis and the development of biological communities during primary succession begin on recently exposed mineral surfaces. Following 30 years of surface exposure of reclaimed surface mining sites (Appalachian Mountains, USA), it was hypothesized that microbial communities would differ between sandstone and siltstone parent materials and to a lesser extent between vegetation types. Microbial community composition was examined by targeting bacterial and archaeal (16S ribosomal RNA (rRNA)) and fungal (internal transcribed spacer (ITS)) genes and analyzed using Illumina sequencing. Microbial community composition significantly differed between parent materials and between plots established with tall fescue grass or pitch x loblolly pine vegetation types, suggesting that both factors are important in shaping community assembly during early pedogenesis. At the phylum level, Acidobacteria and Proteobacteria differed in relative abundance between sandstone and siltstone. The amount of the heavy fraction carbon (C) was significantly different between sandstone (2.0 mg g(-1)) and siltstone (5.2 mg g(-1)) and correlated with microbial community composition. Soil nitrogen (N) cycling was examined by determining gene copy numbers of ureC, archaeal amoA, and bacterial amoA. Gene quantities tended to be higher in siltstone compared to sandstone but did not differ by vegetation type. This was consistent with differences in extractable ammonium (NH4 (+)) concentrations between sandstone and siltstone (16.4 vs 8.5 μg NH4 (+)-N g(-1) soil), suggesting that nitrification rates may be higher in siltstone. Parent material and early vegetation are important determinants of early microbial community assembly and could be drivers for the trajectory of ecosystem development over longer time scales. PMID:25370885

  20. Dynamics of soil organic carbon fractions in olive groves in Andalusia (Southern Spain) in soils with contrasted parent material and under different management practices

    NASA Astrophysics Data System (ADS)

    Vicente-Vicente, Jose Luis; García-Ruiz, Roberto; Calero, Julio; Aranda, Victor

    2016-04-01

    Spain has 2.5 million hectares of olive groves, 60 % of which are situated in Andalusia (Southern Spain). The most common agricultural management consist of a conventional or reduced tillage combined with herbicides to eliminate weeds. This might lead to some ecological problems (e.g. erosion, soil nutrient and organic carbon losses). The recommended management consist of a plant cover of spontaneous herbaceous plant in the inter row of olive oil orchards which are usually mowed early in spring. In this study, we assessed the influence of: i) two soil managements: non-covered and weed-covered, and ii) soil parent material (carbonated and siliceous), on soil organic carbon (SOC) fractions. In addition, we assessed the existence of a saturation limit for the different SOC fractions by including calcareous and siliceous soils under natural vegetation. Weed-covered soils accumulated more total SOC than soils under the non-covered management and this was independent on the parent material type. Same was true for most of the SOC fractions. However, the relative proportion of the SOC fractions was not affected by the presence of weeds, but it was due to the parent material type; carbonated soils had more unprotected and physically protected SOC, whereas the siliceous soils were relatively enriched in biochemically protected pool. Otherwise, table 1 shows that the chemically protected SOC pool was best fit to a saturation function, especially in the siliceous plots. The other fractions were best fit to a linear function. Therefore, these results suggest that chemically protected pools are the only protected fractions which can be saturated considering the SOC in the natural vegetation soils as the SOC limit. Considering SOC levels in the weed-covered and non-covered managements of all protected fractions and their respective limits of total SOC, saturation deficits in the non-covered and weed-covered plots were 75% and 60% of total SOC, respectively. Table 1. Significance

  1. Classification of Moscow soils and parent materials and its possible inclusion in the classification system of Russian soils

    NASA Astrophysics Data System (ADS)

    Prokofyeva, T. V.; Martynenko, I. A.; Ivannikov, F. A.

    2011-05-01

    The Law on Urban Soils was adopted by the Moscow Government in 2007. In the course of working out by-laws for its implementation, the systematization of Moscow soils was developed aimed at providing scientific grounds for the urban soils' inventory, mapping, and evaluation. The classification of Moscow soils comprises a description of the diagnostic horizons and soil types with the subtype subdivision fitting the principles of the new All-Russia soil classification. The authors hope that the developed system may trigger new discussions about the place of anthropogenically transformed soils and soil-like bodies in the Classification and Diagnostics of the Soils of Russia.

  2. Effect of aging on the bioavailability and fractionation of arsenic in soils derived from five parent materials in a red soil region of Southern China.

    PubMed

    Wang, Yanan; Zeng, Xibai; Lu, Yahai; Su, Shiming; Bai, Lingyu; Li, Lianfang; Wu, Cuixia

    2015-12-01

    The effects of aging time and soil parent materials on the bioavailability and fractionations of arsenic (As) in five red soils were studied. The results indicated that As bioavailability in all soils decreased during aging, especially with a sharp decline occurring in the first 30 days. After aging for 360 days, the highest available As concentration, which accounted for 12.3% of the total, was observed in soils derived from purple sandy shale. While 2.67% was the lowest proportion of the available As in soils derived from quaternary red clay. Furthermore, the best fit of the available As changing with aging time was obtained using the pseudo-second-order model (R(2) = 0.939-0.998, P < 0.05). Notably, Al oxides played a more crucial role (R(2) = 0.89, P<0.05) than did Fe oxides in controlling the rate of As aging. The non-specially and specially absorbed As constituted the primary forms of available As. PMID:26349069

  3. A comparison of rates of hornblende etching in soils in glacial deposits of the northern Rocky Mountains: Influence of climate and characteristics of parent material

    SciTech Connect

    Horn, L.L. . Dept. of Geology); Hall, R.D. . Dept. of Geology)

    1993-04-01

    Etching rates of hornblende grains in the soil matrix of glacial deposits in the Northern Rocky Mountains are dependent primarily upon the influences on soil moisture of the climate and texture of the parent materials. Etching is measured as the deepest penetration of weathering along cleavages. Previous works have shown that hornblende etching is a logarithmic function of depth. Hornblende etching is also a logarithmic function of age of the parent material, with etching rates declining rapidly after initially high rates during the first 10 to 15 kyr after deposition. A comparison of etching rates was made among four chronosequences from the Wind River Range, Wyoming and the Tobacco Root Range, Montana, which have differences in mean annual precipitation (MAP) and texture of the till parent materials. Using rates calculated from both ranges for the first 12 kyr after deposition, etching is slowest (0.02 [mu]m/1,000 yrs) in coarse-textured granitic parent materials where the MAP is 25--40 cm. In contrast, etching is faster by an order of magnitude (0.21 [mu]m/1,000 yrs) where MAP is 110--150 cm and the parent material is finer textured due to about 15% sedimentary rock material mixed with a granitic component. Within individual chronosequences, deposits at higher elevations have accelerated etching rates due to higher orographic precipitation or the influence of late-lying snow. These factors result in higher soil moisture content.

  4. Soil production rates on silicate parent material in high-mountains: different approaches - different results?

    NASA Astrophysics Data System (ADS)

    Egli, Markus; Dahms, Dennis; Norton, Kevin

    2013-04-01

    High-mountain soils develop in particularly sensitive environments. Consequently, deciphering and predicting what drives the rates of soil formation in such environments is a major challenge. In terms of soil production from chemical weathering, the predominating perception for high-mountain soils and cold environments often is that the chemical weathering 'portion' of soil development is temperature-inhibited, often to the point of non-occurrence. Several concepts exist to determine long-term rates of soil formation and development. We present three different approaches: (1) quantification of soil formation from minimally eroded soils of known age using chronosequences (known surface age and soil thickness - SAST), (2) determination of soil residence times (SRT) and production rates through chemical weathering using (un)stable isotopes (e.g. 230Th / 234U activity ratios), and (3) a steady state approach using cosmogenic isotopes (e.g. 10Be). Data form different climate zones, and particularly from high-mountains (alpine environment), were compared. The SAST and steady state approach gave quite similar results for alpine environments (European Alps and the Wind River Range (Rocky Mountains USA)). Soil formation rates in mountain areas (but having a temperate climate) using the SRT approach, did not differ greatly from the SAST and Steady State approaches. Independent of the chosen approach, the results seem moderately comparable. Soil formation rates in high-mountain areas (alpine climate) ranged from very low to extremely high values and showed a clear decreasing tendency with time. Very young soils have up to 3 - 4 orders of magnitude higher rates of development than old soils (105 to 106 years). This is due to the fact that weathering is kinetically limited in regions having young surfaces and supply limited on old surfaces. Soil production rates cannot be infinitely high. Consequently, a speed limit must exist. In the literature, this limit has been set at

  5. Fluorine sorption by soils developed from various parent materials in Galicia (NW Spain).

    PubMed

    Gago, C; Romar, A; Fernández-Marcos, M L; Álvarez, E

    2012-05-15

    Fluorine is a phytotoxic element that can reach the soil from various industrial activities. Fluorine sorption by soil is crucial to protect water and food chain from fluorine pollution. In Galicia (NW Spain), various activities emit fluorine into the atmosphere, mainly ceramic industries and an aluminium smelter. This study, aiming to investigate fluorine sorption by Galician soils, was conducted on natural soil horizons representative of the area. Most soils were acid and rich in organic matter and showed strong fluorine sorption. The lowest sorptions were exhibited by a near-neutral serpentinite-derived soil (1001 mg kg(-1)) and the B horizons of soils developed from quartz schist (989 mg kg(-1)), and the highest by the A horizons of amphibolite-derived soils (1783 mg kg(-1)). In soils developed from quartz schist, biotitic schist and amphibolite, A horizons sorbed more fluoride than the corresponding B horizons (average 1621 and 1324 mg kg(-1), respectively), while the opposite is true in granite-derived soils (average 1644 and 1324 mg kg(-1), respectively). In the A horizons, the F sorption significantly correlated to soil pH (r=-0.79), pH in NaF (r=0.83) and oxalate Al (r=0.81). In the B horizons, sorption correlated to soil pH (r=-0.78), oxalate Fe (r=0.71) and organic C (r=0.66). F sorption can be described by both the Langmuir and Freundlich equations. The concentration of free fluoride in the equilibrium solutions increased above pH 6. PMID:22340953

  6. Phyllosilicate weathering pathways in chlorite-talc bearing soil parent materials, D.R. Congo: early findings.

    NASA Astrophysics Data System (ADS)

    Dumon, Mathijs; Oostermeyer, Fran; Timmermans, Els; De Meulemeester, Aschwin; Mees, Florias; Van Driessche, Isabel; Erens, Hans; Bazirake Mujinya, Basile; Van Ranst, Eric

    2015-04-01

    The study of the formation and transformation of clay minerals is of the upmost importance to understand soil formation and to adjust land-use management to the land surface conditions. These clay minerals determine to a large extent the soil physical and chemical properties. It is commonly observed that over time the mineralogy of any parent material is transformed to a simple assemblage composed mostly of Al and Fe oxides and low-activity clays, e.g. kaolinite. This is especially obvious in the humid tropics, which have been protected from glacial erosion, allowing deep, highly weathered soils to form. Despite the abundant presence of kaolinite in these soils, its formation pathways are still under debate: either neoformation by dissolution-crystallisation reactions or solid-state transformation of 2:1 phyllosilicates. To elucidate this, weathering sequences in a unique 40 m core taken below a termite mound, reaching a talc-chlorite bearing substrate in the Lubumbashi area, Katanga, DR Congo are being investigated in detail using a.o. quantitative X-ray diffraction analysis, chemical characterization, micromorphology and µXRF-scanning with the main objective to improve the understanding of the formation pathways of kaolinite subgroup minerals in humid tropical environments. Based on an initial characterization of the core, two zones of interest were selected for more detailed analysis, for which the early findings will be presented. The first zone extends from ca. 9 m to 11 m below the surface is dominated by kaolinite but shows early traces of primary talc and micas. The second zone extends from 34 to 36 m below the surface and contains large amounts of chlorite, with smaller amounts of talc, micas and kaolinite.

  7. Impact of climate and parent material on chemical weathering in Loess-derived soils of the Mississippi River valley

    USGS Publications Warehouse

    Muhs, D.R.; Bettis, E. Arthur, III; Been, J.; McGeehin, J.P.

    2001-01-01

    Peoria Loess-derived soils on uplands east of the Mississippi River valley were studied from Louisiana to Iowa, along a south-to-north gradient of decreasing precipitation and temperature. Major element analyses of deep loess in Mississippi and Illinois show that the composition of the parent material is similar in the northern and southern parts of the valley. We hypothesized that in the warmer, wetter parts of the transect, mineral weathering should be greater than in the cooler, drier parts of the transect. Profile average values of CaO/TiO2, MgO/ TiO2, K2O/TiO2, and Na2O/TiO2, Sr/Zr, Ba/Zr, and Rb/Zr represent proxies for depletion of loess minerals such as calcite, dolomite, hornblende, mica, and plagioclase. All ratios show increases from south to north, supporting the hypothesis of greater chemical weathering in the southern part of the valley. An unexpected result is that profile average values of Al2O3/TiO2 and Fe2O3/TiO2 (proxies for the relative abundance of clay minerals) show increases from south to north. This finding, while contrary to the evidence of greater chemical weathering in the southern part of the transect, is consistent with an earlier study which showed higher clay contents in Bt horizons of loess-derived soils in the northern part of the transect. We hypothesize that soils in the northern part of the valley received fine-grained loess from sources to the west of the Mississippi River valley either late in the last glacial period, during the Holocene or both. In contrast, soils in the southern part of the valley were unaffected by such additions.

  8. Modeling Water Flux at the Base of the Rooting Zone for Soils with Varying Glacial Parent Materials

    NASA Astrophysics Data System (ADS)

    Naylor, S.; Ellett, K. M.; Ficklin, D. L.; Olyphant, G. A.

    2013-12-01

    Soils of varying glacial parent materials in the Great Lakes Region (USA) are characterized by thin unsaturated zones and widespread use of agricultural pesticides and nutrients that affect shallow groundwater. To better our understanding of the fate and transport of contaminants, improved models of water fluxes through the vadose zones of various hydrogeologic settings are warranted. Furthermore, calibrated unsaturated zone models can be coupled with watershed models, providing a means for predicting the impact of varying climate scenarios on agriculture in the region. To address these issues, a network of monitoring sites was developed in Indiana that provides continuous measurements of precipitation, potential evapotranspiration (PET), soil volumetric water content (VWC), and soil matric potential to parameterize and calibrate models. Flux at the base of the root zone is simulated using two models of varying complexity: 1) the HYDRUS model, which numerically solves the Richards equation, and 2) the soil-water-balance (SWB) model, which assumes vertical flow under a unit gradient with infiltration and evapotranspiration treated as separate, sequential processes. Soil hydraulic parameters are determined based on laboratory data, a pedo-transfer function (ROSETTA), field measurements (Guelph permeameter), and parameter optimization. Groundwater elevation data are available at three of six sites to establish the base of the unsaturated zone model domain. Initial modeling focused on the groundwater recharge season (Nov-Feb) when PET is limited and much of the annual vertical flux occurs. HYDRUS results indicate that base of root zone fluxes at a site underlain by glacial ice-contact parent materials are 48% of recharge season precipitation (VWC RMSE=8.2%), while SWB results indicate that fluxes are 43% (VWC RMSE=3.7%). Due in part to variations in surface boundary conditions, more variable fluxes were obtained for a site underlain by alluvium with the SWB model (68

  9. A landscape-scale study of land use and parent material effects on soil organic carbon and total nitrogen in the Konya Basin, Turkey

    NASA Astrophysics Data System (ADS)

    Mayes, M. T.; Marin-Spiotta, E.; Ozdogan, M.; Erdogan, M. A.

    2011-12-01

    In ecosystems where intensive farming and grazing have been occurring for millennia, there is poor understanding of how present-day soil biogeochemical properties relate to factors associated with soil parent materials (e.g. texture, mineralogy), and the net effects of long-term land use practices. Soil organic carbon (SOC) and total soil nitrogen (TN) are important for their roles in maintaining soil structure, moisture, fertility and contributing to carbon sequestration. Our research used a state factor approach (Jenny 1981) to study effects of soil parent materials and land use practices on SOC, TN, and other properties across thirty-five sites in the Konya Basin, an arid region in south-central Turkey farmed and grazed for over 8,000 years. This project is one of the first to study land use impacts on soils at a landscape scale (500 km2) in south-central Turkey, and incorporate geospatial data (e.g. a satellite imagery-derived land cover map we developed) to aid selection of field sites. Focusing on the plough layer (0-25cm) in two depth intervals, we compared effects of agriculture, orchard cultivation and grazing land use practices and clay-loam alluvial, sandy-loam volcanic and lacustrine clay soils on soil properties using standard least squares regression analyses. SOC and TN depended strongly on parent materials, but not on land use. Averaged across both depth intervals, alluvial soil SOC and TN concentrations (19.4 ± 1.32 Mg/ha SOC, 2.86 ± 1.23 Mg/ha TN) were higher and significantly different than lacustrine (9.72 ± 3.01 Mg/ha SOC, 1.57 ± 0.69 Mg/ha TN) and volcanic soil concentrations (7.40 ± 1.72 Mg/ha SOC, 1.02 ± 0.35 Mg/ha TN). Land use significantly affected SOC and TN on alluvial soils, but not on volcanic or lacustrine soils. Our results demonstrate the potential for land use to have different effects on different soils in this region. Our data on SOC, TN and other soil properties illustrate patterns in regional SOC and TN variability not

  10. Effects of Subsetting by Parent Materials on Prediction of Soil Organic Matter Content in a Hilly Area Using Vis-NIR Spectroscopy.

    PubMed

    Xu, Shengxiang; Shi, Xuezheng; Wang, Meiyan; Zhao, Yongcun

    2016-01-01

    Assessment and monitoring of soil organic matter (SOM) quality are important for understanding SOM dynamics and developing management practices that will enhance and maintain the productivity of agricultural soils. Visible and near-infrared (Vis-NIR) diffuse reflectance spectroscopy (350-2500 nm) has received increasing attention over the recent decades as a promising technique for SOM analysis. While heterogeneity of sample sets is one critical factor that complicates the prediction of soil properties from Vis-NIR spectra, a spectral library representing the local soil diversity needs to be constructed. The study area, covering a surface of 927 km2 and located in Yujiang County of Jiangsu Province, is characterized by a hilly area with different soil parent materials (e.g., red sandstone, shale, Quaternary red clay, and river alluvium). In total, 232 topsoil (0-20 cm) samples were collected for SOM analysis and scanned with a Vis-NIR spectrometer in the laboratory. Reflectance data were related to surface SOM content by means of a partial least square regression (PLSR) method and several data pre-processing techniques, such as first and second derivatives with a smoothing filter. The performance of the PLSR model was tested under different combinations of calibration/validation sets (global and local calibrations stratified according to parent materials). The results showed that the models based on the global calibrations can only make approximate predictions for SOM content (RMSE (root mean squared error) = 4.23-4.69 g kg-1; R2 (coefficient of determination) = 0.80-0.84; RPD (ratio of standard deviation to RMSE) = 2.19-2.44; RPIQ (ratio of performance to inter-quartile distance) = 2.88-3.08). Under the local calibrations, the individual PLSR models for each parent material improved SOM predictions (RMSE = 2.55-3.49 g kg-1; R2 = 0.87-0.93; RPD = 2.67-3.12; RPIQ = 3.15-4.02). Among the four different parent materials, the largest R2 and the smallest RMSE were

  11. Effects of Subsetting by Parent Materials on Prediction of Soil Organic Matter Content in a Hilly Area Using Vis–NIR Spectroscopy

    PubMed Central

    Xu, Shengxiang; Shi, Xuezheng; Wang, Meiyan; Zhao, Yongcun

    2016-01-01

    Assessment and monitoring of soil organic matter (SOM) quality are important for understanding SOM dynamics and developing management practices that will enhance and maintain the productivity of agricultural soils. Visible and near-infrared (Vis–NIR) diffuse reflectance spectroscopy (350–2500 nm) has received increasing attention over the recent decades as a promising technique for SOM analysis. While heterogeneity of sample sets is one critical factor that complicates the prediction of soil properties from Vis–NIR spectra, a spectral library representing the local soil diversity needs to be constructed. The study area, covering a surface of 927 km2 and located in Yujiang County of Jiangsu Province, is characterized by a hilly area with different soil parent materials (e.g., red sandstone, shale, Quaternary red clay, and river alluvium). In total, 232 topsoil (0–20 cm) samples were collected for SOM analysis and scanned with a Vis–NIR spectrometer in the laboratory. Reflectance data were related to surface SOM content by means of a partial least square regression (PLSR) method and several data pre-processing techniques, such as first and second derivatives with a smoothing filter. The performance of the PLSR model was tested under different combinations of calibration/validation sets (global and local calibrations stratified according to parent materials). The results showed that the models based on the global calibrations can only make approximate predictions for SOM content (RMSE (root mean squared error) = 4.23–4.69 g kg−1; R2 (coefficient of determination) = 0.80–0.84; RPD (ratio of standard deviation to RMSE) = 2.19–2.44; RPIQ (ratio of performance to inter-quartile distance) = 2.88–3.08). Under the local calibrations, the individual PLSR models for each parent material improved SOM predictions (RMSE = 2.55–3.49 g kg−1; R2 = 0.87–0.93; RPD = 2.67–3.12; RPIQ = 3.15–4.02). Among the four different parent materials, the largest R2

  12. The interaction between parent material, climate and volcanism as the major soil forming factor in the Ecuadorian high Andes region

    NASA Astrophysics Data System (ADS)

    Buytaert, W.; Duyck, H.; Dercon, G.; Deckers, J.; Wyseure, G.

    2003-04-01

    The high Andes region of Ecuador and Colombia (>3500m a.s.l.) is covered by the so-called páramo ecosystem, characterised by a cold climate, a typical grass or small shrub vegetation and volcanic soils. Soil profiles of the paramo in the Austro Ecuatoriano, South Ecuador, were studied in order to reveal genetic relationships with geology, volcanic ash deposits, climate and land use. A gradual diminuation of Andic properties was found, related to the distance of the pedon to the active volcanoes of the Northern Volcanic Zone of the Andes. Pedons in the north of the region, closer to these volcanoes (Sangay, Tungurahua) are classified as non-allophanic Histic Andosols. The influence of the vicinity of the volcanoes leads to a higher oxalate extractable aluminium and iron. The genesis of the Andosols seems to be strongly related to the presence and thickness of volcanic ash depositions. The limit of these depositions is situated south of the city of Cuenca. Pedons further to the south are classified as Histosols. However, they also have clear Andic properties. Several differences in chemical properties between the Western and Eastern cordilleras where found, that are most probable related with a difference in mother material, and maybe also a different climatic regime. Correlation of the chemical properties with land use reveals that no chemical differences can be found that are invoked by occupying natural Andosols for agricultural purposes, within the first five years of cultivation. At last, the conclusions were used to revisit the World Reference Base for Soil Resources in order to sharpen up differenciation between Andosols and Histosols.

  13. Elemental and strontium isotopic geochemistry of the soil profiles developed on limestone and sandstone in karstic terrain on Yunnan-Guizhou Plateau, China: Implications for chemical weathering and parent materials

    NASA Astrophysics Data System (ADS)

    Liu, Wen-Jing; Liu, Cong-Qiang; Zhao, Zhi-Qi; Xu, Zhi-Fang; Liang, Chong-Shan; Li, Long-bo; Feng, Jia-Yi

    2013-05-01

    The limestone and yellow sandstone soil profiles from SW China were measured for chemical and Sr isotope compositions of the bulk soils and their sequential leachates (labile, carbonate, and residue or silicate fraction), aiming to characterize the parent materials of the soils, to understand the soil weathering and formation processes, and to discuss the origin of the red residua (terra rossa). The studied yellow sandstone soil, yellow limestone soil, and black limestone soil show different pH values, SiO2 contents, Rb/Sr abundance ratios, and 87Sr/86Sr ratios. The sequential leachates of different soil types also have different 87Sr/86Sr and Ca/Sr ratios. The major chemical compositions of the studied soil profiles suggest that all the sandstone and limestone soils are developing at a stage that feldspar is exhausting and the clay minerals are changing from smectite to kaolinite and gibbsite. As compared with the red residua distributed in the karst region, the soils studied here show lower CIA values (58-84), but both higher Na2O/K2O (0.9-2.7) and Na2O/Al2O3 concentration ratios (0.07-0.26) on average, suggesting a lower weathering intensity than that of the red residua. The depth profiles of soil CIA values, Na2O/K2O and Rb/Sr ratios, and 87Sr/86Sr ratios indicate that the weathering intensity is slightly lower for the upper and higher for the deeper soils, which suggest that the sandstone and limestone soil profiles were formed through both accumulation and weathering of in situ weathering residue and input of external detritus or soil from upper land. During weathering of the soils, preferential release of Ca and retention of Sr in soil result in higher Ca/Sr ratios in both labile and carbonate fractions than those in the residue fractions of all soil profiles. The co-variations of Hf/Nb and Zr/Nb ratios, together with those Rb/Sr and 87Sr/86Sr ratios of limestone soils, sandstone soils, and the red residua, demonstrate that their parent materials are

  14. Possibilities of including the taxonomy of soils and parent materials of Moscow city into the classification system of the soils of Russia

    NASA Astrophysics Data System (ADS)

    Lebedeva, I. I.; Gerasimova, M. I.

    2011-05-01

    The analysis of the taxonomy of the soils and soil-forming rocks of Moscow city was performed in view of the compatibility of the taxonomy proposed with the new classification system of the soils of Russia. The common platform, which determines the possibility to incorporate the taxonomy of urban soils into the new classification system, is the principle of the priority of the diagnostic horizons, which provides the properties-oriented conceptual background of the compared systems. It was shown that the considered classification developments do not have any fundamental differences either in ideology or in concrete manifestations. Some contradictions in place can be eliminated by respective discussions and agreements.

  15. Interactions between organisms and parent materials of a constructed Technosol shape its hydrostructural properties

    NASA Astrophysics Data System (ADS)

    Deeb, Maha; Grimaldi, Michel; Lerch, Thomas Z.; Pando, Anne; Gigon, Agnès; Blouin, Manuel

    2016-04-01

    There is no information on how organisms influence hydrostructural properties of constructed Technosols and how such influence will be affected by the parent-material composition factor. In a laboratory experiment, parent materials, which were excavated deep horizons of soils and green waste compost (GWC), were mixed at six levels of GWC (from 0 to 50 %). Each mixture was set up in the presence/absence of plants and/or earthworms, in a full factorial design (n = 96). After 21 weeks, hydrostructural properties of constructed Technosols were characterized by soil shrinkage curves. Organisms explained the variance of hydrostructural characteristics (19 %) a little better than parent-material composition (14 %). The interaction between the effects of organisms and parent-material composition explained the variance far better (39 %) than each single factor. To summarize, compost and plants played a positive role in increasing available water in macropores and micropores; plants were extending the positive effect of compost up to 40 and 50 % GWC. Earthworms affected the void ratio for mixtures from 0 to 30 % GWC and available water in micropores, but not in macropores. Earthworms also acted synergistically with plants by increasing their root biomass, resulting in positive effects on available water in macropores. Organisms and their interaction with parent materials positively affected the hydrostructural properties of constructed Technosols, with potential positive consequences on resistance to drought or compaction. Considering organisms when creating Technosols could be a promising approach to improve their fertility.

  16. Parents.

    ERIC Educational Resources Information Center

    Lao Parents and Teachers Association, Minneapolis, MN.

    This collection presents advice to help parents help their children succeed in school. Information sheets are included from many sources, in English and translated into Lao by the Lao Parents and Teachers Association. The emphasis is on the elementary grades, although some of the materials are useful for parents of high school students. The…

  17. DETERMINATION OF EFFECTIVE POROSITY OF SOIL MATERIALS

    EPA Science Inventory

    The performance of a compacted soil liner is partly a function of the porosity, where the transport of materials through the liner occurs via the pore space. The project studies the pore spaces of compacted soil materials to estimate the effective porosity, which is the portion o...

  18. Background levels of some major, trace, and rare earth elements in indigenous plant species growing in Norway and the influence of soil acidification, soil parent material, and seasonal variation on these levels.

    PubMed

    Gjengedal, Elin; Martinsen, Thomas; Steinnes, Eiliv

    2015-06-01

    Baseline levels of 43 elements, including major, trace, and rare earth elements (REEs) in several native plant species growing in boreal and alpine areas, are presented. Focus is placed on species metal levels at different soil conditions, temporal variations in plant tissue metal concentrations, and interspecies variation in metal concentrations. Vegetation samples were collected at Sogndal, a pristine site in western Norway, and at Risdalsheia, an acidified site in southernmost Norway. Metal concentrations in the different species sampled in western Norway are compared with relevant literature data from Norway, Finland, and northwest Russia, assumed to represent natural conditions. Except for aluminium (Al) and macronutrients, the levels of metals were generally lower in western Norway than in southern Norway and may be considered close to natural background levels. In southern Norway, the levels of cadmium (Cd) and lead (Pb) in particular appear to be affected by air pollution, either by direct atmospheric supply or through soil acidification. Levels of some elements show considerable variability between as well as within plant species. Calcium (Ca), magnesium (Mg), and potassium (K) are higher in most species at Sogndal compared to Risdalsheia, despite increased extractable concentrations in surface soil in the south, probably attributed to different buffer mechanisms in surface soil. Antagonism on plant uptake is suggested between Ca, Mg, and K on one hand and Al on the other. Tolerance among calcifuges to acid conditions and a particular ability to detoxify or avoid uptake of Al ions are noticeable for Vaccinium vitis-idaea. PMID:26022847

  19. Infrared optical properties of Mars soil analog materials: Palagonites

    NASA Technical Reports Server (NTRS)

    Roush, Ted L.

    1992-01-01

    The globally distributed bright soils on Mars represent products of chemical alteration of primary igneous materials. As such, understanding the chemistry and mineralogy of these soils provides clues about the nature of the parent materials and the type, duration, and extent of the chemical weathering environments on Mars. Such clues are key in developing an understanding of the interior and surficial processes that have operated throughout Mars' history to yield the surface as it is currently observed. The generally homogeneous nature of these soils is illustrated by a variety of observational data. These data include (1) direct determination of elemental abundances by the X-ray fluorescence instruments on both Viking Landers, (2) Earth-based telescopic observations, and (3) space-based observations. Based on their spectral properties in the visible and near-infrared, terrestrial palagonitic soils have been suggested as analogs for the bright regions on Mars. Palagonites represent the weathering products of basaltic glass and as such are composed of a variety of minerals/materials. In order to gain an understanding regarding the chemical, mineralogical, and spectral properties of a broad suite of palagonites, several samples were collected from the eastern and central regions of the island of Hawaii.

  20. EPR-based material modelling of soils

    NASA Astrophysics Data System (ADS)

    Faramarzi, Asaad; Alani, Amir M.

    2013-04-01

    In the past few decades, as a result of the rapid developments in computational software and hardware, alternative computer aided pattern recognition approaches have been introduced to modelling many engineering problems, including constitutive modelling of materials. The main idea behind pattern recognition systems is that they learn adaptively from experience and extract various discriminants, each appropriate for its purpose. In this work an approach is presented for developing material models for soils based on evolutionary polynomial regression (EPR). EPR is a recently developed hybrid data mining technique that searches for structured mathematical equations (representing the behaviour of a system) using genetic algorithm and the least squares method. Stress-strain data from triaxial tests are used to train and develop EPR-based material models for soil. The developed models are compared with some of the well-known conventional material models and it is shown that EPR-based models can provide a better prediction for the behaviour of soils. The main benefits of using EPR-based material models are that it provides a unified approach to constitutive modelling of all materials (i.e., all aspects of material behaviour can be implemented within a unified environment of an EPR model); it does not require any arbitrary choice of constitutive (mathematical) models. In EPR-based material models there are no material parameters to be identified. As the model is trained directly from experimental data therefore, EPR-based material models are the shortest route from experimental research (data) to numerical modelling. Another advantage of EPR-based constitutive model is that as more experimental data become available, the quality of the EPR prediction can be improved by learning from the additional data, and therefore, the EPR model can become more effective and robust. The developed EPR-based material models can be incorporated in finite element (FE) analysis.

  1. Parenting

    MedlinePlus

    ... parents, people are always ready to offer advice. Parenting tips, parents' survival guides, dos, don'ts, shoulds ... right" way to be a good parent. Good parenting includes Keeping your child safe Showing affection and ...

  2. Interactions between organisms and parent materials of a constructed Technosol shape its hydrostructural properties

    NASA Astrophysics Data System (ADS)

    Deeb, M.; Grimaldi, M.; Lerch, T. Z.; Pando, A.; Gigon, A.; Blouin, M.

    2015-12-01

    Constructed Technosols provide an opportunity to recycle urban waste, and are an alternative to the uptake of topsoil from the countryside. Despite potential problems of erosion, compaction or water holding capacity, their physical properties and the resulting water regulation services are poorly documented. In a laboratory experiment, excavated deep horizons of soils and green waste compost (GWC) were mixed at six levels of GWC (from 0 to 50 %). Each mixture was set up in the presence/absence of plants and/or earthworms, in a full factorial design (n = 96). After 21 weeks, hydrostructural properties of constructed Technosols were characterized by soil shrinkage curves. Organisms explained the variance of hydrostructural characteristics (19 %) a little better than parent-material composition (14 %). The interaction between the effects of organisms and parent-material composition explained the variance far better (39 %) than each single factor. To summarize, compost and plants played a positive role in increasing available water in macropores and micropores; plants were extending the positive effect of compost up to 40 and 50 % GWC. Earthworms affected the void ratio for mixtures from 0 to 30 % GWC and available water in micropores, not in macropores. Earthworms also acted synergistically with plants by increasing their root biomass and the resulting positive effects on available water in macropores. Organisms and their interaction with parent materials thus positively affected the hydro-structural properties of constructed Technosols, with potential positive consequences on resistance to drought or compaction. Considering organisms when creating Technosols could be a promising approach to improve their fertility.

  3. Soil carbonates and soil water

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The presence of soil carbonates occurring as solidified masses or dispersed particles can alter soil water dynamics from what would be expected based on non-carbonate soil properties. Carbonate minerals in the soil can be derived from high carbonate parent material, additions in the form of carbonat...

  4. Carbonaceous materials in soil-derived dusts

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Wind erosion affects over 500 million ha of land worldwide and creates between 500 and 5000 Tg of fugitive dust annually. This dust carries a disproportionate amount of organic and inorganic carbon when compared to the soil of origin. This loss of soil carbon degrades the soil of origin and may re...

  5. Multi-Elemental Nuclear Analysis of soil reference material

    NASA Astrophysics Data System (ADS)

    Metairon, S.; Zamboni, C. B.; Medeiros, I. M. M. Amaral; Menezes, M. À. B. C.

    2011-08-01

    The elements concentration in the soil reference material (IAEA/SOIL-7) was obtained using the parametric Neutron Activation Analysis technique in the IEA-R1 nuclear reactor at IPEN (CNEN-SP). The results obtained were in good agreement with the respective nominal values from this reference material suggesting the viability of using this parametric procedure for environmental investigations.

  6. Optimal mapping of terrestrial gamma dose rates using geological parent material and aerogeophysical survey data.

    PubMed

    Rawlins, B G; Scheib, C; Tyler, A N; Beamish, D

    2012-12-01

    Regulatory authorities need ways to estimate natural terrestrial gamma radiation dose rates (nGy h⁻¹) across the landscape accurately, to assess its potential deleterious health effects. The primary method for estimating outdoor dose rate is to use an in situ detector supported 1 m above the ground, but such measurements are costly and cannot capture the landscape-scale variation in dose rates which are associated with changes in soil and parent material mineralogy. We investigate the potential for improving estimates of terrestrial gamma dose rates across Northern Ireland (13,542 km²) using measurements from 168 sites and two sources of ancillary data: (i) a map based on a simplified classification of soil parent material, and (ii) dose estimates from a national-scale, airborne radiometric survey. We used the linear mixed modelling framework in which the two ancillary variables were included in separate models as fixed effects, plus a correlation structure which captures the spatially correlated variance component. We used a cross-validation procedure to determine the magnitude of the prediction errors for the different models. We removed a random subset of 10 terrestrial measurements and formed the model from the remainder (n = 158), and then used the model to predict values at the other 10 sites. We repeated this procedure 50 times. The measurements of terrestrial dose vary between 1 and 103 (nGy h⁻¹). The median absolute model prediction errors (nGy h⁻¹) for the three models declined in the following order: no ancillary data (10.8) > simple geological classification (8.3) > airborne radiometric dose (5.4) as a single fixed effect. Estimates of airborne radiometric gamma dose rate can significantly improve the spatial prediction of terrestrial dose rate. PMID:23147566

  7. [Parenting].

    ERIC Educational Resources Information Center

    Pawl, Jeree, Ed.

    1990-01-01

    Contributions to this theme issue of a bulletin on infants aged birth to three, point out that becoming a parent is an evolving process and that infants' meanings to their parents shape parenting behavior and the capacity to change. Articles also examine the challenge of how to support parents as they come to, and continue in, the process of…

  8. Contrasting environmental memories by ancient soils on different parent rocks in the South-western Italian Alps

    NASA Astrophysics Data System (ADS)

    D'Amico, Michele; Catoni, Marcella; Bonifacio, Eleonora; Zanini, Ermanno

    2014-05-01

    Ancient soils (pre-Holocenic paleosols and vetusols) are uncommon on the Alps, because of the extensive Pleistocenic glaciations which erased most of the previously existing soils, the slope steepness and climatic conditions favoring soil erosion. However, in few sites, particularly in the outermost sections of the Alpine range, Pleistocene glaciers covered only small and scattered surfaces because of the low altitude reached in the basins, and ancient soils could be preserved for long periods of time on particularly stable surfaces. We described and sampled soils on 11 stable surfaces in the Upper Tanaro valley, Ligurian Alps (Southwestern Piemonte, Italy). The sampling sites were characterized by low steepness and elevation between 600 to 1600 m, under present day lower montane Castanea sativa/Ostrya carpinifolia forests, montane Fagus sylvatica and Pinus uncinata forests or montane heath/grazed grassland, on different substrata. In particular, we sampled soils developed on dolomite, limestone, quartzite, gneiss and shales. The soils were always well representative of the pedogenic trends active on the respective parent materials, i.e. the skeletal fraction in each soil was always composed of just one rock type, despite the proximity of lithological boundaries and the small dimensions of the different outcrops, often coexisting on the same stable surface. All the considered profiles showed signs of extremely long pedogenesis and/or different phases of intense pedogenesis interrupted by the deposition of periglacial cover beds in the steepest sites. Up to four phases of intense pedogenesis were recognized where cover beds were developed, presumably during cold Pleistocene phases, as present-day climate is not cold enough to create such periglacial morphologies. In such cases, each cover bed underwent similar pedogenesis, strongly dependent on the parent material: on quartzite, podzols with thick E horizons and well developed placic ones were formed in all phases

  9. Modification of hydraulic conductivity in granular soils using waste materials.

    PubMed

    Akbulut, S; Saglamer, A

    2004-01-01

    This paper evaluates the use of waste products such as silica fume and fly ash in modification of the granular soils in order to remove some environmental problems and create new useful findings in the field of engineering. It is known that silica fume and fly ash, as well as clay material, are used in geotechnical engineering because of their pozzolanic reactivity and fineness to improve the soil properties needed with respect to engineering purposes. The main objective of this research project was to investigate the use of these materials in geotechnical engineering and to improve the hydraulic properties of soils by means of grouting. For this reason, firstly, suitable grouts in suspension forms were prepared by using silica fume, fly ash, clay and cement in different percentages. The properties of these cement-based grouts were then determined to obtain the desired optimum values for grouting. After that, these grouts were penetrated into the soil samples under pressure. The experimental work indicates that these waste materials and clay improved the physical properties and the fluidity of the cement-based grouts and they also decreased the hydraulic conductivity of the grouted soil samples by sealing the voids of the soil. The results of this study have important findings concerning the use of these materials in soil treatment and the improvement of hydraulic conductivity of the soils. PMID:15120433

  10. Hygrothermal Material Properties for Soils in Building Science

    SciTech Connect

    Pallin, Simon B; Kehrer, Manfred

    2013-01-01

    Hygrothermal performance of soils coupled to buildings is complicated because of the dearth of information on soil properties. However they are important when numerical simulation of coupled heat and moisture transport for below-grade building components are performed as their temperature and moisture content has an influence on the durability of the below-grade building component. Soils can be classified by soil texture. According to the Unified Soil Classification System (USCA), 12 different soils can be defined on the basis of three soil components: clay, sand, and silt. This study shows how existing material properties for typical American soils can be transferred and used for the calculation of the coupled heat and moisture transport of building components in contact with soil. Furthermore a thermal validation with field measurements under known boundary conditions is part of this study, too. Field measurements for soil temperature and moisture content for two specified soils are carried out right now under known boundary conditions. As these field measurements are not finished yet, the full hygrothermal validation is still missing.

  11. Hygrothermal Simulations of Foundations: Part 1 - Soil Material Properties

    SciTech Connect

    Pallin, Simon B; Kehrer, Manfred

    2013-01-01

    Hygrothermal performance of soils coupled to buildings is a complicated process. The computational approach for heat transfer via the ground is well defined (EN-ISO-13370:, 2007) together with simplified methods (Staszczuk, Radon, & Holm). Though the soil moisture transfer is generally ignored, it is proven not negligible (Janssen, Carmeliet, & Hens, 2004). Even though reliable material properties of soils are required to perform realistic hygrothermal calculations of soils coupled to buildings, such material properties have not been well defined in hygrothermal calculations tools. Typical building constructions which are greatly influenced by soils are basements, crawl spaces and slab on grade and reliable hygrothermal performance of such construction are highly requested; as it is ranked within the top 10 Building America Enclosure Research Ideas according to Enclosures STC - Residential Energy Efficiency Stakeholder Meeting, February 29, 2012 Austin, TX. There exists an extensive amount of measurements on soil properties in Soil Science though this information must be gathered as well as adapted to be applicable in Building Science and for hygrothermal simulation purposes. Soil properties are important when analyzing and designing both new building constructions and retrofitting measures, where the outer boundary of the buildings enclosure consists of soil materials. Concerning basement energy retrofits, interior solutions of improving the energy demand has to cooperate with the existing soil properties and must therefore be designed thereafter. In concerns of exterior retrofits, the soil material can be replaced, if needed, with a more suitable filling material, though this approach applies only for basement walls. The soil material beneath the basement floor can naturally not be replaced hence the soil properties of this part of the buildings enclosure still must be taken into consideration. This study is divided into several parts. The intention of the first

  12. Bibliotherapy for Children with Anxiety Disorders Using Written Materials for Parents: A Randomized Controlled Trial

    ERIC Educational Resources Information Center

    Rapee, Ronald M.; Abbott, Maree J.; Lyneham, Heidi J.

    2006-01-01

    The current trial examined the value of modifying empirically validated treatment for childhood anxiety for application via written materials for parents of anxious children. Two hundred sixty-seven clinically anxious children ages 6-12 years and their parents were randomly allocated to standard group treatment, wait list, or a bibliotherapy…

  13. Soil Surface Composition Effects on the Wettability of Aquifer Materials

    NASA Astrophysics Data System (ADS)

    Ryder, J. L.; Demond, A. H.

    2004-05-01

    The wettability of subsurface porous media is critical for determining the distribution of non-aqueous phase liquids. Variations in the wettability of subsurface materials are generally attributed to sorption of hydrophobic contaminants. However, naturally occurring carbonaceous materials may influence the wettability as well. A series of seven soil materials were selected to determine the effect of organic carbon surfaces on soil wetting behavior. The materials represent organic carbon containing surfaces that may be found in soils from young humic matter to mature coal and shale kerogen. Measurements of organic liquid-water contact angle against cut rock faces reveal that surface composition alters the contact angle from the completely water wetted condition of quartz in the case of the mature carbon materials (Lachine Shale, Garfield Shale, Waynesburg Coal, and Plumbago Mineral Carbon). An examination of the soil elemental composition confirms that the bulk elemental composition of each material is separated on a plot of hydrogen to carbon versus oxygen to carbon ratios. The functional groups present at the surface of the soil materials were obtained with Fourier Transform Infrared Spectroscopy (FT-IR) analysis and indicate that the presence of oxygen containing surface functional groups is positively correlated with increased organic-liquid wetting. This study demonstrates that even in the absence of sorbing contaminants the subsurface is fractionally water-wet. This finding may help explain why subsurface distributions of non aqueous phase liquids can vary from those determined with laboratory sands.

  14. Artificial soil formation and stabilization of material cycles in closed ecological systems for Mars habitats

    NASA Astrophysics Data System (ADS)

    Borchardt, Joshua D.

    Scientists are increasingly pressured to investigate novel ways in which to feed astronauts for the first mission to Mars in the 2030s. It is the aim of this thesis to conduct a preliminary investigation for soil formation of NASA JSC Mars-1A Regolith Simulant in an environmentally closed ecosystem to simulate plant growth within these initial habitats, and the prospect of soil formation from a Mars parent material for agricultural purposes. The rhizosphere and plant stress will be the main regions of research focus. It is hypothesized rhizosphere activity will determine the rate of stable soil formation adequate to support the agricultural needs of Mars's first human inhabitants. A Brassica rapa (Wisconsin FastPlant(TM)) was grown on several different substrates, and evaluated for plant stress, elemental analysis, soil fertility, and mineralogical analysis to identify the biogeochemical factors related to areas inside and outside of the rhizosphere, which affect soil formation. In addition, multiple plant generations were grown to investigate bioavailability of nutrients within the system, and lay down preliminary approaches for mathematical model development in order to predict & evaluate future conditions and applications under reduced resource availability situations. Overall, the story of early soil formation from a Mars regolith simulant is further defined to aid in the success of our first human adventurers to the red planet.

  15. Hygrothermal Simulation of Foundations: Part 1 - Soil Material Properties

    SciTech Connect

    Kehrer, Manfred; Pallin, Simon B

    2012-10-01

    The hygrothermal performance of soils coupled to buildings is a complicated process. A computational approach for heat transfer through the ground has been well defined (EN ISO 13370:2007, 2007), and simplified methods have been developed (Staszczuk, Radon, and Holm 2010). However, these approaches generally ignore the transfer of soil moisture, which is not negligible (Janssen, Carmeliet, and Hens 2004). This study is divided into several parts. The intention of the first part is to gather, comprehend and adapt soil properties from Soil Science. The obtained information must be applicable to related tasks in Building Science and validated with hygrothermal calculation tools. Future parts of this study will focus on the validation aspect of the soil properties to be implemented. Basic changes in the software code may be requested at this time. Different types of basement construction will be created with a hygrothermal calculation tool, WUFI. Simulations from WUFI will be compared with existing or ongoing measurements. The intentions of the first part of this study have been fulfilled. The soil properties of interest in Building Science have been defined for 12 different soil textures. These properties will serve as input parameters when performing hygrothermal calculations of building constructions coupled to soil materials. The reliability of the soil parameters will be further evaluated with measurements in Part 2.

  16. Parenting.

    ERIC Educational Resources Information Center

    Ziff, Barry, Ed.; Hostettler, Karen, Ed.

    1989-01-01

    The newsletter of the California Association for the Gifted includes the following brief articles on parenting: "Your Challenge, Their Lives" (Barry Ziff); "Courage to Be Who I Am, Unafraid" (Elizabeth Meckstroth); "Attribution: A Key to Encouraging More Responsible Behavior in the Gifted" (Saundra Sparling); "A Parent's Perspective" (Carolyn…

  17. Parenting.

    ERIC Educational Resources Information Center

    Markun, Patricia Maloney, Ed.

    This document contains 11 articles which are concerned with the education and development of people who are, or will be, parents. The term "parenting" is used to emphasize the need to help fathers and mothers to deal effectively with their own children. Also, the term reflects the growing awareness that child rearing is the function of many…

  18. Mobility of organic solvents in water-saturated soil materials

    USGS Publications Warehouse

    Roy, W.R.; Griffin, R.A.

    1985-01-01

    This investigation presents an analysis of the mobility of 37 organic solvents in saturated soil-water systems, focusing on adsorption phenomena at the solid-liquid interface This analysis was made, in part, by applying predictive expressions that estimate the potential magnitude of adsorption by soil materials Of the 37 solvents considered, 19 were classified as either "very highly mobile" or "highly mobile" and, thus, would have little tendency to be retained by soils to a significant extent, 12 were considered to have medium mobility and 6 low mobility None of these solvents were in the immobile class The limited information available indicates that these predictive expressions yield satisfactory first approximations of the magnitude of adsorption of these solvents by soil materials ?? 1985 Springer-Verlag New York Inc.

  19. On identifying parent plutonic rocks from lunar breccia and soil fragments

    NASA Technical Reports Server (NTRS)

    Haskin, Larry A.; Lindstrom, David J.

    1988-01-01

    Breccia fragments expected from a well-studied boulder of Stillwater anorthosite have been modeled to test the ability to identify parental rock types from examination of breccia and soil fragments. Depending on their size, the boulder fragments give distributions that suggest mixtures of rock types, including monominerallic anorthosite with subordinant amounts of more gabbroic anorthosite, anorthosite, and gabbro for small fragments. The distribution of FeO in samples of lunar ferroan anorthosite (FAN) indicates that FAN has a heterogeneous distribution of mafic minerals like the boulder.

  20. Readability of Educational Materials to Support Parent Sexual Communication With Their Children and Adolescents.

    PubMed

    Ballonoff Suleiman, Ahna; Lin, Jessica S; Constantine, Norman A

    2016-05-01

    Sexual communication is a principal means of transmitting sexual values, expectations, and knowledge from parents to their children and adolescents. Many parents seek information and guidance to support talking with their children about sex and sexuality. Parent education materials can deliver this guidance but must use appropriate readability levels to facilitate comprehension and motivation. This study appraised the readability of educational materials to support parent sexual communication with their children. Fifty brochures, pamphlets, and booklets were analyzed using the Flesch-Kincaid, Gunning Fog, and Simple Measure of Gobbledygook (SMOG) index methods. Mean readability grade-level scores were 8.3 (range = 4.5-12.8), 9.7 (range = 5.5-14.9), and 10.1 (range = 6.7-13.9), respectively. Informed by National Institutes of Health-recommended 6th to 7th grade levels and American Medical Association-recommended 5th to 6th grade levels, percentages falling at or below the 7.0 grade level were calculated as 38%, 12%, and 2% and those falling at or below the 6.0 grade level were calculated as 12%, 2%, and 0% based on the Flesch-Kincaid, Gunning Fog, and SMOG methods, respectively. These analyses indicate that the majority of educational materials available online to support parents' communication with their children about sex and sexuality do not meet the needs of many or most parents. Efforts to improve the accessibility of these materials are warranted. PMID:27116292

  1. Multi-Media Instructional Materials for Child Development/Parent Education Programs.

    ERIC Educational Resources Information Center

    Bjorklund, Gail; Briggs, Anne

    Multi-media materials were used in a federally funded project, Facilitative Environment Encouraging Development (FEED), to teach child development and parenting skills to junior high students. Six criteria were used in material selection: (1) Content reflects a developmental approach; (2) Learning is characterized by an active, doing approach; (3)…

  2. EFFECTS OF DRYING TREATMENTS ON POROSITY OF SOIL MATERIALS

    EPA Science Inventory

    The effects of three drying techniques on total porosity and pore size distribution of three soil materials were studied by Hg intrusion porosimetry. Some samples were dried in an oven at 40 C for 7 d; some samples were quick frozen in liquid N and lyophilized; some samples were ...

  3. Development of a material processing plant for lunar soil

    NASA Technical Reports Server (NTRS)

    Goettsch, Ulix; Ousterhout, Karl

    1992-01-01

    Currently there is considerable interest in developing in-situ materials processing plants for both the Moon and Mars. Two of the most important aspects of developing such a materials processing plant is the overall system design and the integration of the different technologies into a reliable, lightweight, and cost-effective unit. The concept of an autonomous materials processing plant that is capable of producing useful substances from lunar regolith was developed. In order for such a materials processing plant to be considered as a viable option, it must be totally self-contained, able to operate autonomously, cost effective, light weight, and fault tolerant. In order to assess the impact of different technologies on the overall systems design and integration, a one-half scale model was constructed that is capable of scooping up (or digging) lunar soil, transferring the soil to a solar furnace, heating the soil in the furnace to liberate the gasses, and transferring the spent soil to a 'tile' processing center. All aspects of the control system are handled by a 386 class PC via D/A, A/D, and DSP (Digital Signal Processor) control cards.

  4. Parenting.

    ERIC Educational Resources Information Center

    Spock, Benjamin; And Others

    Various aspects of child-rearing are covered in this transcript of a program broadcast in the National Public Radio weekly series, "Options in Education." Authors of current popular books on parenting are interviewed. Benjamin Spock discusses changes (including sex role revisions) in his "Baby and Child Care" since the 1946 first edition. Eda…

  5. Parenting.

    ERIC Educational Resources Information Center

    Jochim, Lisa; Mueller, Andrea

    This guide contains 15 learning activities that can be used in parenting classes, especially for adults with limited literacy skills. Activities include quotations for discussion and suggestions for conducting group discussions and writing lessons. The following activities are included: interpreting quotations about raising children; positive…

  6. EPR-based material modelling of soils considering volume changes

    NASA Astrophysics Data System (ADS)

    Faramarzi, Asaad; Javadi, Akbar A.; Alani, Amir M.

    2012-11-01

    In this paper an approach is presented for developing material models for soils based on evolutionary polynomial regression (EPR), taking into account its volumetric behaviour. EPR is a recently developed hybrid data mining technique that searches for structured mathematical equations (representing the behaviour of a system) using genetic algorithm and the least squares method. Stress-strain data from triaxial test are used to train and develop EPR-based material models for soil. The developed models are compared with some of the well known conventional material models. In particular, the capability of the developed EPR models in predicting volume change behaviour of soils is illustrated. It is also shown that the developed EPR-based material models can be incorporated in finite element (FE) analysis. Two geotechnical examples are presented to verify the developed EPR-based FE model (EPR-FEM). The results of the EPR-FEM are compared with those of a standard FEM where conventional constitutive models are used to describe the material behaviour. The results show that EPR-FEM can be successfully employed to analyse geotechnical engineering problems. The advantages of the proposed EPR models are highlighted.

  7. Comparison of phosphate materials for immobilizing cadmium in soil.

    PubMed

    Hong, Chang Oh; Chung, Doug Young; Lee, Do Kyoung; Kim, Pil Joo

    2010-02-01

    A study was conducted to compare the effects of phosphate (P) materials in reducing cadmium extractability. Seven P materials (commercial P fertilizers--fused phosphate (FP), 'fused and superphosphate' [FSP], and rock phosphate [RP]; P chemicals--Ca[H(2)PO(4)](2).H(2)O, [NH(4)](2)HPO(4), KH(2)PO(4), and K(2)HPO(4)) were selected for the test. The selected P source was mixed with Cd-contaminated soil at the rate of 0, 200, 400, 800, and 1,600 mg P kg(-1) under controlled moisture conditions at 70% of water holding capacity, then incubated for 8 weeks. FP, Ca(H(2)PO(4))(2) H(2)O, KH(2)PO(4), and K(2)HPO(4) significantly decreased NH(4)OAc-extractable Cd (plant-available form) concentrations with increasing application rates. Compared to other phosphate materials used, K(2)HPO(4) was found to be the most effective in reducing the plant-available Cd concentration in soil, mainly due to the negative charge increase caused by soil pH and phosphate adsorption. Contrary to the general information, FSP and (NH(4))(2)HPO(4) increased Cd extractability at low levels of P application (<400 mg kg(-1)), and thereafter Cd extractability decreased significantly with increasing application rate. RP scarcely had an effect on reducing Cd extractability. Ion activity products of CdHPO(4), Cd(OH)(2), and CdCO(3) analyzed by the MINTEQ program were significantly increased by K(2)HPO(4) addition, but the effect of Cd-P compound formation on reducing Cd extractability was negligible. Conclusively, the P-induced alleviation of Cd extractability can be attributed primarily to Cd immobilization due to the increase in soil pH and negative charge rather than Cd-P precipitation, and therefore, alkaline P materials such as K(2)HPO(4) are effective for immobilizing soil Cd. PMID:19633979

  8. Synergetic toxic effect of an explosive material mixture in soil.

    PubMed

    Panz, Katarzyna; Miksch, Korneliusz; Sójka, Tadeusz

    2013-11-01

    Explosives materials are stable in soil and recalcitrant to biodegradation. Different authors report that TNT (2,4,6-trinitrotoluene), RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) are toxic, but most investigations have been performed in artificial soil with individual substances. The aim of the presented research was to assess the toxicity of forest soil contaminated with these substances both individually as well in combinations of these substances. TNT was the most toxic substance. Although RDX and HMX did not have adverse effects on plants, these compounds did cause earthworm mortality, which has not been reported in earlier research. Synergistic effects of explosives mixture were observed. PMID:24005241

  9. Microbial properties of mine spoil materials in the initial stages of soil development

    SciTech Connect

    Machulla, G.; Bruns, M.A.; Scow, K.M.

    2005-08-01

    The early years of soil genesis during mine spoil reclamation are critical for vegetative establishment and may help predict reclamation success. Mine spoils in the Halle-Leipzig region of Germany were analyzed for microbial changes following a hay mulch-seeding treatment without topsoil or fertilizer application. Microbial biomass carbon (C{sub mic}) and dehydrogenase activity (DHA) of spoils were measured each year in the first 3 yr after treatment. In the third year, bacterial community DNA fingerprints were compared with those from a reference soil. Microbial indicators were measured at three depths in the upper 10 cm of spoils at three sites with contrasting parent materials: glacial till (sandy loam), limnic tertiary sediments (high-lignite sandy clay loam), and quaternary sand and gravel (loamy sand). Before reclamation, C{sub mic} means and standard deviations of surface spoils (0-1 cm) were 9{+-}6, 39{+-}11, and 38{+-}16 mg kg{sup -1} for the loamy sand, high-lignite sandy clay loam, and sandy loam spoils, respectively. Within one year, mean C{sub mic} at the surface increased to 148{+-}70, 229{+-}64, and 497{+-}167 mg kg{sup -1}, respectively, and was significantly higher at 0 to 1 cm than at lower depths. Highest DHA and DNA yields were obtained in the 0- to 1-cm depth of the sandy loam spoils. Microbial biomass C values exhibited significant correlations with DHA, DNA yield, and extractable C for all three mine spoils. Soil microbial indices were more responsive than plant measurements to differences in parent materials.

  10. Sulphate release from construction and demolition material in soils

    NASA Astrophysics Data System (ADS)

    Abel, Stefan; Wessolek, Gerd

    2013-04-01

    In Berlin and many other cities soils are heavily influenced by anthropogenic activities and deposited substrates. A widespread technical substrate in technosols is construction and demolition material from residential and industrial buildings. Existing rubble landfills without sealing facilities pose threats to ground water quality. In the central city of Berlin rising sulphate concentrations of groundwaters (up to 1200 mg/L) are measured since more than two decades. Previous studies point out that the high sulphate concentrations are mainly attributed to World War II rubble. The major part of debris was deposited in form of landfills and contains approximately 0.3 wt% gypsum. The scope of our research is to determine mechanisms of sulphate release from debris material, interactions between sulphate release, soil hydraulic properties and potential sinks of sulphur. To estimate equilibrium concentration and kinetics of sulphate release of various debris components batch and column experiments are conducted. The same method is applied to determine potential adsorptive character of common debris components. To analyse the impacts of soil hydraulic properties on sulphate leaching we carry out soil column experiments with defined upper and lower boundary conditions, varying water flow velocity and induced preferential flow. Simultaneously we monitor sulphate concentration of soil leachate in a 2 m³ lysimeter. First results of the batch experiments show that gypsum from broken stucco is the main source of sulphate in the observed technosols. Other components as mortar and slag show a quite low sulphate release. Similar results are found within the column experiments. For brigs medium and strongly time dependent sulphate release is determined. Concentrations up to 1500 mg/L are measured in the soil leachate from the lysimeter.

  11. Differentiating pedogenesis from diagenesis in early terrestrial paleoweathering surfaces formed on granitic composition parent materials

    USGS Publications Warehouse

    Driese, S.G.; Medaris, L.G., Jr.; Ren, M.; Runkel, Anthony C.; Langford, R.P.

    2007-01-01

    Unconformable surfaces separating Precambrian crystalline basement and overlying Proterozoic to Cambrian sedimentary rocks provide an exceptional opportunity to examine the role of primitive soil ecosystems in weathering and resultant formation of saprolite (weathered rock retaining rock structure) and regolith (weathered rock without rock structure), but many appear to have been affected by burial diagenesis and hydrothermal fluid flow, leading some researchers to discount their suitability for such studies. We examine one modern weathering profile (Cecil series), four Cambrian paleoweathering profiles from the North American craton (Squaw Creek, Franklin Mountains, Core SQ-8, and Core 4), one Neoproterozoic profile (Sheigra), and one late Paleoproterozoic profile (Baraboo), to test the hypothesis that these paleoweathering profiles do provide evidence of primitive terrestrial weathering despite their diagenetic and hydrothermal overprinting, especially additions of potassium. We employ an integrated approach using (1) detailed thin-section investigations to identify characteristic pedogenic features associated with saprolitization and formation of well-drained regoliths, (2) electron microprobe analysis to identify specific weathered and new mineral phases, and (3) geochemical mass balance techniques to characterize volume changes during weathering and elemental gains and losses of major and minor elements relative to the inferred parent materials. There is strong pedogenic evidence of paleoweathering, such as clay illuviation, sepic-plasmic fabrics, redoximorphic features, and dissolution and alteration of feldspars and mafic minerals to kaolinite, gibbsite, and Fe oxides, as well as geochemical evidence, such as whole-rock losses of Na, Ca, Mg, Si, Sr, Fe, and Mn greater than in modern profiles. Evidence of diagenesis includes net additions of K, Ba, and Rb determined through geochemical mass balance, K-feldspar overgrowths in overlying sandstone sections, and

  12. Forming artificial soils from waste materials for mine site rehabilitation

    NASA Astrophysics Data System (ADS)

    Yellishetty, Mohan; Wong, Vanessa; Taylor, Michael; Li, Johnson

    2014-05-01

    Surface mining activities often produce large volumes of solid wastes which invariably requires the removal of significant quantities of waste rock (overburden). As mines expand, larger volumes of waste rock need to be moved which also require extensive areas for their safe disposal and containment. The erosion of these dumps may result in landform instability, which in turn may result in exposure of contaminants such as trace metals, elevated sediment delivery in adjacent waterways, and the subsequent degradation of downstream water quality. The management of solid waste materials from industrial operations is also a key component for a sustainable economy. For example, in addition to overburden, coal mines produce large amounts of waste in the form of fly ash while sewage treatment plants require disposal of large amounts of compost. Similarly, paper mills produce large volumes of alkaline rejected wood chip waste which is usually disposed of in landfill. These materials, therefore, presents a challenge in their use, and re-use in the rehabilitation of mine sites and provides a number of opportunities for innovative waste disposal. The combination of solid wastes sourced from mines, which are frequently nutrient poor and acidic, with nutrient-rich composted material produced from sewage treatment and alkaline wood chip waste has the potential to lead to a soil suitable for mine rehabilitation and successful seed germination and plant growth. This paper presents findings from two pilot projects which investigated the potential of artificial soils to support plant growth for mine site rehabilitation. We found that pH increased in all the artificial soil mixtures and were able to support plant establishment. Plant growth was greatest in those soils with the greatest proportion of compost due to the higher nutrient content. These pot trials suggest that the use of different waste streams to form an artificial soil can potentially be used in mine site rehabilitation

  13. Probing soil and aquifer material porosity with nuclear magnetic resonance

    NASA Astrophysics Data System (ADS)

    Hinedi, Z. R.; Kabala, Z. J.; Skaggs, T. H.; Borchardt, D. B.; Lee, R. W. K.; Chang, A. C.

    1993-12-01

    Nuclear magnetic resonance relaxation measurements were used to identify different characteristic porosity domains in soil and aquifer materials. The porosity distribution can be inferred from these measurements by a regularization method applicable to any nuclear magnetic resonance (NMR) relaxation, or by an analytic method applicable only to multiexponential relaxations (D. Orazio et al., 1989). The porosity distribution obtained from NMR relaxation measurements strongly depends on the pore shape factor. For the Borden aquifer material, both the regularized and the analytic pore size distribution obtained from NMR relaxation measurements are consistent with those obtained by Ball et al. (1990) using Hg porosimetry and N2 adsorption. For the Eustis and the Webster soils, the measured porosity domains are qualitatively consistent with those expected based on their respective composition. Our findings suggest that due to the long time required to saturate fine pores, NMR measurements of porosity distribution that are collected at short saturation times are biased toward larger pore sizes.

  14. Workshop on Parent-Body and Nebular Modification of Chondritic Materials

    NASA Astrophysics Data System (ADS)

    Zolensky, M. E.; Krot, A. N.; Scott, E. R. D.

    1997-01-01

    This volume contains abstracts that have been accepted for presentation at the Workshop on Parent-Body and Nebular Modification of Chondritic Materials. Logistics and administrative and publications support for the workshop were provided by the staff of the Lunar and Planetary Institute.

  15. Impacts of Marital Status and Parental Presence on the Material Hardship of Families with Children.

    ERIC Educational Resources Information Center

    Lerman, Robert I.

    This study investigated how marriage, cohabitation, single parenthood, and the presence of biological parents affected the incomes and material hardships of children. Data from the 1997 and 1999 National Survey of America's Families were used to examine recent changes in the marital status and household structure of families with children, how…

  16. Materials for Sex Equality Education for Use by Teachers, Parents, and Young People.

    ERIC Educational Resources Information Center

    National Organization for Women, Champaign, IL. Greater Champaign Area Chapter.

    These materials were compiled to help provide a better education for all children by increasing parents' and teachers' awareness of sexism and by providing new ideas and programs for helping people to overcome sex-role stereotyping in the schools. Included in the packet are: (1) a questionnaire designed to provoke thought before the beginning of a…

  17. Challenging Ideological Exclusion of Curriculum Material: Rights of Students and Parents.

    ERIC Educational Resources Information Center

    Stern, Nat

    1979-01-01

    Argues that, as a matter of constitutional law, public school boards of education do not possess unrestricted authority to exclude material from the curriculum on the basis of ideological content, and explores the rights of students and parents to challenge such exclusions. Available from Harvard Civil Rights-Civil Liberties Law Review, Harvard…

  18. Parent Involvement.

    ERIC Educational Resources Information Center

    LaCrosse, Ed

    The paper discusses the rationale and guidelines for parent involvement in HCEEP (Handicapped Children's Early Education Program) projects. Ways of assessing parents' needs are reviewed, as are four types of services to meet the identified needs: parent education, direct participation, parent counseling, and parent provided programs. Materials and…

  19. Use of Biochar from the Pyrolysis of Waste Organic Material as a Soil Amendment

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biochar is being promoted for its potential to improve soil properties, fertility and carbon sequestration in soil. How this material might impact agricultural soils within temperate regions is largely unknown, Validation of biochar as a beneficial soil amendment and carbon sink would add important...

  20. Parental separation and adult psychological distress: an investigation of material and relational mechanisms

    PubMed Central

    2014-01-01

    Background An association between parental separation or divorce occurring in childhood and increased psychological distress in adulthood is well established. However relatively little is known about why this association exists and how the mechanisms might differ for men and women. We investigate why this association exists, focussing on material and relational mechanisms and in particular on the way in which these link across the life course. Methods This study used the 1970 British Cohort Study (n = 10,714) to investigate material (through adolescent and adult material disadvantage, and educational attainment) and relational (through parent–child relationship quality and adult partnership status) pathways between parental separation (0–16 years) and psychological distress (30 years). Psychological distress was measured using Rutter’s Malaise Inventory. The inter-linkages between these two broad mechanisms across the life course were also investigated. Missing data were multiply imputed by chained equations. Path analysis was used to explicitly model prospectively-collected measures across the life course, therefore methodologically extending previous work. Results Material and relational pathways partially explained the association between parental separation in childhood and adult psychological distress (indirect effect = 33.3% men; 60.0% women). The mechanisms were different for men and women, for instance adult partnership status was found to be more important for men. Material and relational factors were found to interlink across the life course. Mechanisms acting through educational attainment were found to be particularly important. Conclusions This study begins to disentangle the mechanisms between parental separation in childhood and adult psychological distress. Interventions which aim to support children through education, in particular, are likely to be particularly beneficial for later psychological health. PMID:24655926

  1. Adaptive transgenerational plasticity in an annual plant: grandparental and parental drought stress enhance performance of seedlings in dry soil.

    PubMed

    Herman, Jacob J; Sultan, Sonia E; Horgan-Kobelski, Tim; Riggs, Charlotte

    2012-07-01

    Stressful parental (usually maternal) environments can dramatically influence expression of traits in offspring, in some cases resulting in phenotypes that are adaptive to the inducing stress. The ecological and evolutionary impact of such transgenerational plasticity depends on both its persistence across generations and its adaptive value. Few studies have examined both aspects of transgenerational plasticity within a given system. Here we report the results of a growth-chamber study of adaptive transgenerational plasticity across two generations, using the widespread annual plant Polygonum persicaria as a naturally evolved model system. We grew five inbred Polygonum genetic lines in controlled dry vs. moist soil environments for two generations in a fully factorial design, producing replicate individuals of each genetic line with all permutations of grandparental and parental environment. We then measured the effects of these two-generational stress histories on traits critical for functioning in dry soil, in a third (grandchild) generation of seedling offspring raised in the dry treatment. Both grandparental and parental moisture environment significantly influenced seedling development: seedlings of drought-stressed grandparents or parents produced longer root systems that extended deeper and faster into dry soil compared with seedlings of the same genetic lines whose grandparents and/or parents had been amply watered. Offspring of stressed individuals also grew to a greater biomass than offspring of nonstressed parents and grandparents. Importantly, the effects of drought were cumulative over the course of two generations: when both grandparents and parents were drought-stressed, offspring had the greatest provisioning, germinated earliest, and developed into the largest seedlings with the most extensive root systems. Along with these functionally appropriate developmental effects, seedlings produced after two previous drought-stressed generations had

  2. Microbiological destruction of composite polymeric materials in soils

    NASA Astrophysics Data System (ADS)

    Legonkova, O. A.; Selitskaya, O. V.

    2009-01-01

    Representatives of the same species of microscopic fungi developed on composite materials with similar polymeric matrices independently from the type of soils, in which the incubation was performed. Trichoderma harzianum, Penicillium auranthiogriseum, and Clonostachys solani were isolated from the samples of polyurethane. Fusarium solani, Clonostachys rosea, and Trichoderma harzianum predominated on the surface of ultrathene samples. Ulocladium botrytis, Penicillium auranthiogriseum, and Fusarium solani predominated in the variants with polyamide. Trichoderma harzianum, Penicillium chrysogenum, Aspergillus ochraceus, and Acremonium strictum were isolated from Lentex-based composite materials. Mucor circinelloides, Trichoderma harzianum, and Penicillium auranthiogriseum were isolated from composite materials based on polyvinyl alcohol. Electron microscopy demonstrated changes in the structure of polymer surface (loosening and an increase in porosity) under the impact of fungi. The physicochemical properties of polymers, including their strength, also changed. The following substances were identified as primary products of the destruction of composite materials: stearic acid for polyurethane-based materials; imide of dithiocarbonic acid and 1-nonadecen in variants with ultrathene; and tetraaminopyrimidine and isocyanatodecan in variants with polyamide. N,N-dimethyldodecan amide, 2-methyloximundecanon and 2-nonacosane were identified for composites on the base of Lentex A4-1. Allyl methyl sulfide and imide of dithiocarbonic acid were found in variants with the samples of composites based on polyvinyl alcohol. The identified primary products of the destruction of composite materials belong to nontoxic compounds.

  3. Gender and Material Transfers between Older Parents and Children in Ismailia, Egypt

    PubMed Central

    Yount, Kathryn M.; Cunningham, Solveig A.; Engelman, Michal; Agree, Emily M.

    2011-01-01

    In Egypt, kin relations have been governed by a patriarchal contract, which defines expectations for intergenerational support along gendered lines. Social changes may be disrupting these customs and bringing attention to the ways gender may influence intergenerational support in rapidly changing contexts. Using data from 4,465 parent–child dyads in Ismailia, Egypt, we examined whether intergenerational material transfers favored women over men and whether gaps in needs and endowments accounted for gender differences in transfers. Fathers gave children money and goods more often than did mothers; mothers received material transfers from children more often than did fathers. Compared to sons, daughters made transfers to parents less often and received transfers from parents more often. We found residual advantages to mothers and daughters, even adjusting for differential needs and endowments. Findings corroborate persistent norms of gender complementarity, patrilocal endogamy, and reciprocation for women’s caregiving, despite changes that have threatened patriarchal rules of exchange. PMID:22448075

  4. Processing lunar soils for oxygen and other materials

    NASA Technical Reports Server (NTRS)

    Knudsen, Christian W.; Gibson, Michael A.

    1992-01-01

    Two types of lunar materials are excellent candidates for lunar oxygen production: ilmenite and silicates such as anorthite. Both are lunar surface minable, occurring in soils, breccias, and basalts. Because silicates are considerably more abundant than ilmenite, they may be preferred as source materials. Depending on the processing method chosen for oxygen production and the feedstock material, various useful metals and bulk materials can be produced as byproducts. Available processing techniques include hydrogen reduction of ilmenite and electrochemical and chemical reductions of silicates. Processes in these categories are generally in preliminary development stages and need significant research and development support to carry them to practical deployment, particularly as a lunar-based operation. The goal of beginning lunar processing operations by 2010 requires that planning and research and development emphasize the simplest processing schemes. However, more complex schemes that now appear to present difficult technical challenges may offer more valuable metal byproducts later. While they require more time and effort to perfect, the more complex or difficult schemes may provide important processing and product improvements with which to extend and elaborate the initial lunar processing facilities. A balanced R&D program should take this into account. The following topics are discussed: (1) ilmenite--semi-continuous process; (2) ilmenite--continuous fluid-bed reduction; (3) utilization of spent ilmenite to produce bulk materials; (4) silicates--electrochemical reduction; and (5) silicates--chemical reduction.

  5. Non-volcanic andic soils - a new soil type?

    NASA Astrophysics Data System (ADS)

    Bäumler, Rupert

    2014-05-01

    Numerous sites are described all over the world with soils fulfilling all requirements of andic soil properties developed in non-volcanic and non-allophanic parent materials, and in different bioclimatic zones. Up to now these soils are mainly assigned to Andisols/Andosols or andic Inceptisols in WRB and US Soil Taxonomy. Common factors and properties of this group of soils are in general acid parent materials, advanced soil development, comparably high amounts of oxidic Fe and Al compounds, leaching environment, and a probably underestimated role of iron with respect to the specific soil properties, e.g. extremely stabile, pseudo-sand like micro-aggregates. Considering the worldwide occurrence of these soils and the specificity of their physicochemical properties, I suggest soil forming processes and a new soil type clearly different from Andosols/Andisols in a narrow sense.

  6. Workshop on Parent-Body and Nebular Modification of Chondritic Materials

    NASA Technical Reports Server (NTRS)

    Zolensky, M. E. (Editor); Krot, A. N. (Editor); Scott, E. R. D. (Editor)

    1997-01-01

    Topics considered include: thermal Metamorphosed Antarctic CM and CI Carbonaceous Chondrites in Japanese Collections, and Transformation Processes of Phyllosilicates; use of Oxygen Isotopes to Constrain the Nebular and Asteroidal Modification of Chondritic Materials; effect of Revised Nebular Water Distribution on Enstatite Chondrite Formation; interstellar Hydroxyls in Meteoritic Chondrules: Implications for the Origin of Water in the Inner Solar System; theoretical Models and Experimental Studies of Gas-Grain Chemistry in the Solar Nebula; chemical Alteration of Chondrules on Parent Bodies; thermal Quenching of Silicate Grains in Protostellar Sources; an Experimental Study of Magnetite Formation in the Solar Nebula; the Kaidun Meteorite: Evidence for Pre- and Postaccretionary Aqueous Alteration; a Transmission Electron Microscope Study of the Matrix Mineralogy of the Leoville CV3 (Reduced-Group) Carbonaceous Chondrite: Nebular and Parent-Body Features; rubidium-Strontium Isotopic Systematic of Chondrules from the Antarctic CV Chondrites Yamato 86751 and Yamato 86009: Additional Evidence for Late Parent-Body Modification; oxygen-Fugacity Indicators in Carbonaceous Chondrites: Parent-Body Alteration or High-Temperature Nebular Oxidation; thermodynamic Modeling of Aqueous Alteration in CV Chondrites; asteroidal Modification of C and O Chondrites: Myths and Models; oxygen Fugacity in the Solar Nebular; and the History of Metal and Sulfides in Chondrites.

  7. The effect of parent metal properties on the performance of Lattice Block Material{trademark}

    SciTech Connect

    Renauld, M.L.; Giamei, A.F.; Thompson, M.S.; Priluck, J.

    1998-12-31

    Lattice Block Material{trademark}, or LBM{trademark} is a unique lightweight structure consisting of repeated cells with an internal node connected to, in the most common configuration, 14 ligaments. In its metallic version, this product is available in a variety of castable metals including aluminum alloys, copper alloys, nickel alloys and steels. The relationship between LBM structural performance (strength and stiffness) and parent metal properties is investigated using compression tests in three primary orientations and 3-pt. bend tests. Analytical assessment of the LBM via finite element analysis shows reasonable agreement with experimental findings and provides predictions for LBM capabilities with different materials, unit cell sizes and ligament geometries.

  8. Assessing lithologic discontinuities and parent material uniformity within the Texas sandy mantle and implications for archaeological burial and preservation potential in upland settings

    NASA Astrophysics Data System (ADS)

    Ahr, Steven W.; Nordt, Lee C.; Driese, Steven G.

    2012-07-01

    Alfisols within the Texas Gulf Coast Plain commonly exhibit textural contrasts between sandy, artifact-bearing A-E horizons (i.e., sandy mantle), and artifact-sterile clay-rich Bt (argillic) horizons. This has invoked debate about parent material uniformity and pedogenic versus geomorphic sandy mantle origins, which has implications for the scientific value of buried archaeological sites. To improve our understanding of archaeological burial in upland settings, we evaluated parent material uniformity within five pedons to distinguish pedogenically derived textural changes from geomorphologically created lithologic discontinuities. Depth trends in clay-free particle size classes and stable/immobile Ti and Zr constituents failed to reveal lithologic discontinuities between the sandy mantle and Bt horizons, and the observed textural differences are interpreted to have resulted from pedogenic processes. This interpretation is supported by clay skins, fine clay increases in Bt horizons, and micromorphological observations. Consequently, artifacts buried in upland summits have likely moved down the soil profile due to biomantle processes. Deep sandy mantle sites, non-parallel contacts between the sandy mantle and Bt horizons, and paleogullies incised into Eocene bedrock are better explained by colluvial/soil creep processes adjacent to summits, where archaeological materials may exhibit preservation potential. No single explanation can account for sandy mantle origins, and we advocate a case-by-case approach.

  9. Predicting the preservation of cultural artefacts and buried materials in soil.

    PubMed

    Kibblewhite, Mark; Tóth, Gergely; Hermann, Tamás

    2015-10-01

    This study identifies factors affecting the fate of buried objects in soil and develops a method for assessing where preservation of different materials and stratigraphic evidence is more or less likely in the landscape. The results inform the extent of the cultural service that soil supports by preserving artefacts from and information about past societies. They are also relevant to predicting the state of existing and planned buried infrastructure and the persistence of materials spread on land. Soils are variable and preserve different materials and stratigraphic evidence differently. This study identifies the material and soil properties that affect preservation and relates these to soil types; it assesses their preservation capacities for bones, teeth and shells, organic materials, metals (Au, Ag, Cu, Fe, Pb and bronze), ceramics, glass and stratigraphic evidence. Preservation of Au, Pb and ceramics, glass and phytoliths is good in most soils but degradation rates of other materials (e.g. Fe and organic materials) is strongly influenced by soil type. A method is proposed for using data on the distribution of soil types to map the variable preservation capacities of soil for different materials. This is applied at a continental scale across the EU for bones, teeth and shells, organic materials, metals (Cu, bronze and Fe) and stratigraphic evidence. The maps produced demonstrate how soil provides an extensive but variable preservation of buried objects. PMID:26022409

  10. Soils regulate and mitigate climate change

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Background/Question/Methods: The interaction of soil science and ecology can be traced back to the origins of soil science as an independent discipline within the natural sciences. Vasili Dokuchaev, the founder of modern soil science, identified five soil forming factors: parent material, climate, o...

  11. Laboratory evaluation of frozen soil target materials with a fused interface.

    SciTech Connect

    Bronowski, David R.; Lee, Moo Yul

    2004-10-01

    To investigate the performance of artificial frozen soil materials with a fused interface, split tension (or 'Brazilian') tests and unconfined uniaxial compression tests were carried out in a low temperature environmental chamber. Intact and fused specimens were fabricated from four different soil mixtures (962: clay-rich soil with bentonite; DNA1: clay-poor soil; DNA2: clay-poor soil with vermiculite; and DNA3: clay-poor soil with perlite). Based on the 'Brazilian' test results and density measurements, the DNA3 mixture was selected to closely represent the mechanical properties of the Alaskan frozen soil. The healed-interface by the same soil layer sandwiched between two blocks of the same material yielded the highest 'Brazilian' tensile strength of the interface. Based on unconfined uniaxial compression tests, the frictional strength of the fused DNA3 specimens with the same soil appears to exceed the shear strength of the intact specimen.

  12. The Medical Geochemistry of Dusts, Soils, and Other Earth Materials

    NASA Astrophysics Data System (ADS)

    Plumlee, G. S.; Ziegler, T. L.

    2003-12-01

    "Town clenched in suffocating grip of asbestos"USA Today, article on Libby,Montana, February, 2000"Researchers find volcanoes are bad for your health… long after they finish erupting"University of WarwickPress Release, 1999"Toxic soils plague city - arsenic, lead in 5 neighborhoods could imperil 17,000 residents"Denver Post, 2002"Ill winds - dust storms ferry toxic agents between countries and even continents"Science News, 2002A quick scan of newspapers, television, science magazines, or the internet on any given day has a fairly high likelihood of encountering a story (usually accompanied by a creative headline such as those above) regarding human health concerns linked to dusts, soils, or other earth materials. Many such concerns have been recognized and studied for decades, but new concerns arise regularly.Earth scientists have played significant roles in helping the medical community understand some important links between earth materials and human health, such as the role of asbestos mineralogy in disease (Skinner et al., 1988; Ross, 1999; Holland and Smith, 2001), and the role of dusts generated by the 1994 Northridge, California, earthquake in an outbreak of Valley Fever ( Jibson et al., 1998; Schneider et al., 1997).Earth science activities tied to health issues are growing (Skinner and Berger, 2003), and are commonly classified under the emerging discipline of medical geology (Finkelman et al., 2001; Selinus and Frank, 2000; Selinus, in press).Medical geochemistry (also referred to as environmental geochemistry and health: Smith and Huyck (1999), Appleton et al. (1996)) can be considered as a diverse subdiscipline of medical geology that deals with human and animal health in the context of the Earth's geochemical cycle ( Figure 1). Many medical geochemistry studies have focused on how chemical elements in rocks, soils, and sediments are transmitted via water or vegetation into the food chain, and how regional geochemical variations can result in disease

  13. Measurement and modeling of energetic-material mass transfer to soil-pore water - Project CP-1227 final technical report.

    SciTech Connect

    Stein, Joshua S.; Sallaberry, Cedric M.; Webb, Stephen Walter; Phelan, James M.; Hadgu, Teklu

    2006-05-01

    Military test and training ranges operate with live-fire engagements to provide realism important to the maintenance of key tactical skills. Ordnance detonations during these operations typically produce minute residues of parent explosive chemical compounds. Occasional low-order detonations also disperse solid-phase energetic material onto the surface soil. These detonation remnants are implicated in chemical contamination impacts to groundwater on a limited set of ranges where environmental characterization projects have occurred. Key questions arise regarding how these residues and the environmental conditions (e.g., weather and geostratigraphy) contribute to groundwater pollution. This final report documents the results of experimental and simulation model development for evaluating mass transfer processes from solid-phase energetics to soil-pore water.

  14. As(V) and P Competitive Sorption on Soils, By-Products and Waste Materials.

    PubMed

    Rivas-Pérez, Ivana María; Paradelo-Núñez, Remigio; Nóvoa-Muñoz, Juan Carlos; Arias-Estévez, Manuel; Fernández-Sanjurjo, María José; Álvarez-Rodríguez, Esperanza; Núñez-Delgado, Avelino

    2015-12-01

    Batch-type experiments were used to study competitive As(V) and P sorption on various soils and sorbent materials. The materials assayed were a forest soil, a vineyard soil, pyritic material, granitic material, coarsely and finely ground mussel shell, calcinated mussel shell ash, pine sawdust and slate processing fines. Competition between As(V) and P was pronounced in the case of both soils, granitic material, slate fines, both shells and pine sawdust, showing more affinity for P. Contrary, the pyritic material and mussel shell ash showed high and similar affinity for As(V) and P. These results could be useful to make a correct use of the soils and materials assayed when focusing on As and P removal in solid or liquid media, in circumstances where both pollutants may compete for sorption sites. PMID:26690456

  15. As(V) and P Competitive Sorption on Soils, By-Products and Waste Materials

    PubMed Central

    Rivas-Pérez, Ivana María; Paradelo-Núñez, Remigio; Nóvoa-Muñoz, Juan Carlos; Arias-Estévez, Manuel; Fernández-Sanjurjo, María José; Álvarez-Rodríguez, Esperanza; Núñez-Delgado, Avelino

    2015-01-01

    Batch-type experiments were used to study competitive As(V) and P sorption on various soils and sorbent materials. The materials assayed were a forest soil, a vineyard soil, pyritic material, granitic material, coarsely and finely ground mussel shell, calcinated mussel shell ash, pine sawdust and slate processing fines. Competition between As(V) and P was pronounced in the case of both soils, granitic material, slate fines, both shells and pine sawdust, showing more affinity for P. Contrary, the pyritic material and mussel shell ash showed high and similar affinity for As(V) and P. These results could be useful to make a correct use of the soils and materials assayed when focusing on As and P removal in solid or liquid media, in circumstances where both pollutants may compete for sorption sites. PMID:26690456

  16. MOBILE SYSTEM FOR EXTRACTING SPILLED HAZARDOUS MATERIALS FROM EXCAVATED SOILS

    EPA Science Inventory

    Laboratory tests were conducted with three separate pollutants (phenol, arsenic trioxide, and polychlorinated biphenyls (PCB's) and two soils of widely different characteristics (sand/gravel/silt/clay and organic loam) to evaluate techniques for cleansing soil contaminated with r...

  17. Impact of carbonaceous materials in soil on the transport of soil-bound PAHs during rainfall-runoff events.

    PubMed

    Luo, Xiaolin; Zheng, Yi; Wu, Bin; Lin, Zhongrong; Han, Feng; Zhang, Wei; Wang, Xuejun

    2013-11-01

    Polycyclic Aromatic Hydrocarbons (PAHs) transported from contaminated soils by surface runoff pose significant risk for aquatic ecosystems. Based on a rainfall-runoff simulation experiment, this study investigated the impact of carbonaceous materials (CMs) in soil, identified by organic petrology analysis, on the transport of soil-bound PAHs under rainfall conditions. The hypothesis that composition of soil organic matter significantly impacts the enrichment and transport of PAHs was proved. CMs in soil, varying significantly in content, mobility and adsorption capacity, act differently on the transport of PAHs. Anthropogenic CMs like black carbon (BC) largely control the transport, as PAHs may be preferentially attached to them. Eventually, this study led to a rethink of the traditional enrichment theory. An important implication is that CMs in soil have to be explicitly considered to appropriately model the nonpoint source pollution of PAHs (possibly other hydrophobic chemicals as well) and assess its environmental risk. PMID:23938446

  18. Chemical analyses of soils and other surficial materials, Alaska

    USGS Publications Warehouse

    Gough, L.P.; Peard, J.L.; Severson, R.C.; Shacklette, H.T.; Thompkins, M.L.; Stewart, K.C.; Briggs, P.H.

    1984-01-01

    Introduction: The favorable response to the reports on the geochemistry of unconsolidated surficial materials of the conterminous United States (informally called the '50-mile geochemical survey,' Shacklette and others, 1971a, 1971b, 1973, and 1974) led us, in 1975, to initiate a somewhat similar survey of Alaska. The principal objective of studies of this type is to establish estimates of the abundance of elements in soils and other surficial materials. Such information is useful in the evaluation of geochemical data for (1) mineral resources, (2) environmental appraisals, and (3) the definition of broad-scale geochemical patterns. For about six years this effort progressed slowly on a non-funded, time-available basis. During fiscal years 1982 and 1983, however, some funds were made available through the USGS Energy Lands and Alaska Mineral Surveys programs which allowed for the completion of the field-work phase of the project. The sampling plan was kept simple because, as with the 50-mile study, the acquisition of samples depended on the voluntary cooperation of field personnel (only about 40 percent of the total number of samples was obtained by the authors).

  19. Soils and Fertilizers. Competency Based Teaching Materials in Horticulture.

    ERIC Educational Resources Information Center

    Legacy, Jim; And Others

    This competency-based curriculum unit on soils and fertilizers is one of four developed for classroom use in teaching the turf and lawn services area of horticulture. The four sections are each divided into teaching content (in a question-and-answer format) and student skills that outline taking soil samples, testing samples, preparing soil for…

  20. CLASSIFICATION OF COAL SURFACE MINE SOIL MATERIAL FOR VEGETATION MANAGEMENT AND SOIL WATER QUALITY

    EPA Science Inventory

    An Alabama minesoil classification system was developed based on soil texture, soil color value and soil pH. Only five different soil classes were found in this study. However, the classification scheme allows for the inclusion of any minesoil that occurs on the basis of its text...

  1. Element concentrations in soils and other surficial materials of Alaska

    USGS Publications Warehouse

    Gough, L.P.; Severson, R.C.; Shacklette, H.T.

    1988-01-01

    Mean concentrations of 35 elements, ash yields, and pH have been estimated for samples of sils and other unconsolidated surficial materials from 266 collection locations throughout Alaska. These background values can be applied to studies of environmental geochemistry and health, wildlife management, and soil-forming processes in cold climates and to computation of element abundances on a regional or worldwide scale. Limited data for an additoinal eight elements are also presented. Materials were collected using a one-way, three-level, analysis-of-variance samplling design in which collecting procedures were simplified for the convenience of the many volunteer field workers. The sample collectors were asked to avoid locations of known mineral deposits and obvious contamination, to take samples at a depth of about 20 cm where possible, and to take a replicate sample about 100 m distant from the first sample collected. With more than 60 percent of the samples replicated and 14 percent of the samples split for duplicate laboratory analyses, reliable estimates were made of the variability in element concentrations at two geographic scales and of the error associated with sample handling and laboratory procedures. Mean concentrations of most elements in surficial materials from the state of alaska correspond well with those reported in similar materials from the conterminous United STatess. Most element concentrations and ranges in samples of stream and lake sediments from Alaska, however, as reported in the literature, do not correspond well with those found in surficial materials of this study. This lack of correspondence is attributed to (1) a merger of two kinds ofsediments (stream and lake) for calculating means; (2) elimination from the sediment mean calculations of values below the limit of quantitative determination; (3) analytical methods different from those of the surficial materials study; and (4) most importantly, the inherent differences in chemistry of

  2. Parent Education Workbook for Mainstreamed Students. Teachers Guide. Contemporary Parenting Choices: Materials for Mainstreamed Classrooms. Module 4.

    ERIC Educational Resources Information Center

    Iowa State Univ. of Science and Technology, Ames. Dept. of Home Economics Education.

    The fourth part of a parenthood education curriculum series, the Parent Education Workbook consists of a teachers guide (and 12 student lesson units not replicated in the guide) divided into two parts, the first part focusing on relationships and the second on child care. The units are intended for use by mainstreamed mentally disabled (MD) and…

  3. Helium effects on the post-implantation creep properties and the microstructure of AISI 316L welds and parent material

    NASA Astrophysics Data System (ADS)

    Dai, Yong; Schroeder, Herbert

    1992-09-01

    The influence of implanted helium on the creep properties in electron-beam welds of the Next European Torus (NET) reference material, AISI 316L, and its parent material in the as-received condition has been investigated at 873 K. Helium degredation effects (i.e. reduced creep rupture time and creep rupture strain) are more serious in the parent material than in the welds. The fracture mode for implanted weld specimens is usually transgranular, while for the parent material specimens it is mixed trans- and intergranular. TEM investigations show that in the welds there is a lot of σ-ferrite at grain boundaries (occupying about 50% of grain boundary area) and in the interior of grains as well. Helium bubble sizes increase with increasing helium concentration, while helium bubble densities remain constant. Helium bubbles in the matrix are larger in size but much lower in density than those at boundaries or interfaces.

  4. Effect of Polycyclic Aromatic Hydrocarbon Source Materials and Soil Components on Partitioning and Dermal Uptake.

    PubMed

    Xia, Huan; Gomez-Eyles, Jose L; Ghosh, Upal

    2016-04-01

    The bioavailability of polycyclic aromatic hydrocarbons (PAHs) in soils can be influenced by the source material they are emitted within, the properties of the receiving soil, weathering processes, and the concentration of PAHs. In this study 30 contaminated soils were constructed with common PAH sources (fuel oil, soot, coal tar based skeet particles) and direct spike with a solvent added to different types and contents of soil organic matter and minerals to achieve PAH concentrations spanning 4 orders of magnitude. Source material had the greatest impact on PAH partitioning. Soils containing skeet generally exhibited the highest KD values, followed by soot, fuel oil, and solvent spiked soils. Among all soil compositions, the presence of 2% charcoal had the largest enhancement of KD. Partitioning behavior could not be predicted by an organic carbon and black carbon partitioning model. Including independently measured partitioning behavior of the soil components and PAH sources allowed better prediction but still suffered from issues of interaction (oil sorption in peat) and highly nonlinear partitioning with depletion (for skeet). Dermal absorption of PAHs measured using pig skin was directly related to the freely dissolved aqueous concentration in soil and not the total concentration in the soil. Overall, we show that PAH source materials have a dominating influence on partitioning, highlighting the importance of using native field soils in bioavailability and risk assessments. PMID:26964018

  5. [Delphi method to identify education material on healthy food for teachers, school-age children and their parents].

    PubMed

    Vio, Fernando; Lera, Lydia; Fuentes-García, Alejandra; Salinas, Judith

    2012-09-01

    Delphi method to identify education material on healthy food for teachers, school-age children and their parents. Delphi method applied to get expert consensus about healthy food topics to include in educational materials for preschool and school-age children, their parents and teachers is described. The questionnaire was developed with the results of surveys and focus groups in children, parents and teachers made previously. The questionnaire was mailed to 54 experts in nutrition, education and communication in a first round. The results were analyzed and forwarded in a second round with the subjects without consensus. The cycle was completed by a validation conducted with teachers and parents and were prioritized by audiovisual educational materials on the writings, favoring participatory activities such as cooking workshops, games, activities over the passive (information at parent meetings, delivery of educational materials and conferences of experts). There was consensus on education in health behaviors such as not giving them money to carry to school, make healthy food choices on family outings and recreational activities associated with healthy eating during weekends; prefer healthy food prepared at home instead of the processed food; restrict eating out candy and prefer family meals without watching TV and food instead of taking a snack in the evening. These results are critical to design educational materials on healthy eating plans to change current eating habits that are contributing significantly to increase the childhood obesity. PMID:24617030

  6. Mobile system for extracting spilled hazardous materials from excavated soils. Final report Dec 76-Apr 82

    SciTech Connect

    Scholz, R.; Milanowski, J.

    1983-10-01

    Laboratory tests were conducted with three separate pollutants (phenol, arsenic trioxide, and polychlorinated biphenyls (PCB's) and two soils of widely different characteristics (sand/gravel/silt/clay and organic loam) to evaluate techniques for cleansing soil contaminated with released or spilled hazardous materials. The tests show that scrubbing of excavated soil on site is an efficient approach for freeing soils of certain contaminants but that the effectiveness depends on the washing fluid (water + additives) and on the soil composition and particle size distribution. Based on the test results, a full-scale, field-use system was designed, engineered, fabricated, assembled, and briefly tested; the unit is now ready for field demonstrations.

  7. Overview of recent magnetic studies of high T c cuprate parent compounds and related materials

    NASA Astrophysics Data System (ADS)

    Johnston, D. C.; Ami, T.; Borsa, F.; Canfield, P. C.; Carretta, P.; Cho, B. K.; Cho, J. H.; Chou, F. C.; Corti, M.; Crawford, M. K.; Dervenagas, P.; Erwin, R. W.; Fernandez-Baca, J. A.; Goldman, A. I.; Gooding, R. J.; Huang, Q.; Hundley, M. F.; Harlow, R. L.; Harmon, B. N.; Lascialfari, A.; Miller, L. L.; Ostenson, J. E.; Salem, N. M.; Stassis, C.; Sternlieb, B.; Suh, B. J.; Torgeson, D. R.; Vaknin, D.; Vos, K. J. E.; Wang, X.-L.; Wang, Z. R.; Xu, M.; Zarestky, J.

    Recent studies of the magnetic properties of several high superconducting transition temperature (T c ) cuprate parent compounds and related materials will be reviewed. The observations of a Heisenberg to XY-like crossover upon cooling below ˜ 300 K towards the Néel temperature T N =257 K and a subsequent magnetic field-induced XY-like to Ising-like crossover near T N in single crystals of the K2NiF4-type spin 1/2 model compound Sr2CuO2Cl2 will be described. The spin 1/2 linear chain compound Sr2CuO3, the parent of the Sr2CuO3+δ oxygen-doped superconductors, is found to exhibit classic Bonner-Fisher magnetic behavior, with a large antiferromagnetic Cu-Cu superexchange coupling constant. Studies of the evolution of La2-x SrxCuO4 with Sr doping in the insulating regime (x<0.05) will be summarized, which indicate that the doped holes reside in walls separating undoped domains. We have found that BaCuO2.1, a copper-oxygen cluster compound, exhibits ferromagnetic rather than antiferromagnetic Cu-Cu superexchange interactions. Finally, a summary of the magnetic properties of single crystals of the recently discovered RNi2B2C layered structure superconductors will be given.

  8. Economic Development Planning for Single Parents. Curriculum Materials for Vocational Teachers of Adolescents and Single Parents. Special Emphasis on Meeting the Needs of the Teen Parent.

    ERIC Educational Resources Information Center

    Simpson, Kawanna J.; And Others

    This guide is intended for use in school-based intervention programs intended to help single parents (particularly teenagers who are expecting or already have a child) master basic money management and consumer skills. The guide is divided into sections dealing with the following topics: interpersonal relationships, value clarification,…

  9. Income Is Not Enough: Incorporating Material Hardship Into Models of Income Associations With Parenting and Child Development

    PubMed Central

    Gershoff, Elizabeth T.; Aber, J. Lawrence; Raver, C. Cybele; Lennon, Mary Clare

    2010-01-01

    Although research has clearly established that low family income has negative impacts on children’s cognitive skills and social – emotional competence, less often is a family’s experience of material hardship considered. Using the Early Childhood Longitudinal Study, Kindergarten Class of 1998–1999 (N = 21,255), this study examined dual components of family income and material hardship along with parent mediators of stress, positive parenting, and investment as predictors of 6-year-old children’s cognitive skills and social – emotional competence. Support was found for a model that identified unique parent-mediated paths from income to cognitive skills and from income and material hardship to social – emotional competence. The findings have implications for future study of family income and child development and for identification of promising targets for policy intervention. PMID:17328694

  10. Dissolved Organic Matter Composition of Arctic Rivers: Linking Permafrost, Parent Material, and Groundwater to Riverine Carbon

    NASA Astrophysics Data System (ADS)

    O'Donnell, J. A.; Aiken, G.; Butler, K. D.; Swanson, D. K.

    2015-12-01

    Recent warming in the Arctic is modifying the chemical composition of riverine dissolved organic matter (DOM) through changes in growing season length, wildfire, and permafrost thaw. In arctic rivers, DOM composition is an important control on nutrient availability, trace metal mobilization, and greenhouse gas emissions. As a result, shifts in DOM associated with a changing arctic landscape may alter how aquatic ecosystems function in this region. Here, we examined spatial variation in DOM composition in 72 rivers in the Brooks Range and Seward Peninsula of northern Alaska. We characterized DOM using a suite of techniques, including dissolved organic carbon (DOC) concentration, absorbance spectra, fluorescence, and chemical fractionation. Watersheds were classified based on traits that influence subsurface hydrology, including parent material (volcanic deposits, loess, sand, glacial moraine, bedrock) and permafrost extent (continuous vs. discontinuous zone) and state (ice-rich vs. ice-poor). We observed considerable variability in DOM composition across rivers. DOC concentrations were lowest in rivers influenced by glacial deposits (<2 mgC L-1) and highest in rivers draining lowland tundra or extensive wetlands (>10 mgC L-1). Specific ultraviolet absorbance (SUVA254), which serves as an index of DOM aromaticity, was also variable across rivers; spring-fed mountain streams had the lowest SUVA254 values (<1.5 L mgC-1 m-1), whereas tundra and wetland-dominated streams had the highest values (>4 L mgC-1 m-1). While hydrophobic organic acids were the dominant DOM fraction in all rivers, we observed a significant increase in the proportion of hydrophilic compounds during winter flow and in groundwater-fed systems. We also observed variation in DOM composition with permafrost extent and ground ice distribution across the region. Model projections over the next century suggest a heterogeneous response of DOM to thaw, likely mediated by spatial variations in ground ice and

  11. Hygrothermal Material Properties for Soils in Building Science

    SciTech Connect

    Kehrer, Manfred; Pallin, Simon B

    2013-01-01

    Saving energy in buildings is top of mind with today s building professionals. Although designing energy-efficient walls and roofs is mostly a no-brainer, ensuring that below-grade foundations do not generate moisture problems has become even more complex, particularly because of how soil is involved. Hygrothermal performance of soils coupled to buildings is complicated because of the dearth of information on soil properties. A computational approach for heat transfer through the ground has been well-defined, and simplified methods have been developed. These approaches, however, generally ignore the transfer of soil moisture, which is not negligible. The intention of an ongoing study at Oak Ridge (TN) National Laboratory, therefore, is to gather, comprehend and adapt soil properties from soil science as well. The obtained information must be applicable to related tasks in building science and validated with hygrothermal calculation tools, where additional plugins to the existing software code WUFI (an acronym for Warme unde Felichte Instructionar, which translates to unsteady heat and moisture) are required. (See the sidebar, opposite page, for specifics on WUFI.)Simulation results from WUFI are being compared with existing thermal-only measurements and are being accomplished with ongoing hygrothermal measurements. The final outcome of the study will be the evaluation of several soil types in several climate zones for a number of basement assembly types. The study will define the type of soil, together with the type of building construction considered most and least reliable with respect to energy consumption and moisture safety. Furthermore, the study will determine the influences that different soils have on total energy loss through the ground.

  12. Development of the Intervention Materials for the HomeStyles Obesity Prevention Program for Parents of Preschoolers

    PubMed Central

    Martin-Biggers, Jennifer; Spaccarotella, Kim; Delaney, Colleen; Koenings, Mallory; Alleman, Gayle; Hongu, Nobuko; Worobey, John; Byrd-Bredbenner, Carol

    2015-01-01

    Home environment is key to the development of obesity-preventing behaviors during childhood, yet few resources help preschool parents address factors at home associated with obesity risk. This paper describes creation of materials for an in-home intervention (HomeStyles) with this population. An advisory group of stakeholders and target audience members determined salient factors affecting childhood obesity to address in-home and developed program materials. The Social Cognitive Theory, Faith’s Core Behavior Change Strategies to Treat Childhood Obesity, Adult Learning Theory and motivational interviewing techniques guided development of 12 guides targeting strategies parents can use to shape the home environment. Interviews were conducted to determine effectiveness of the guides. Cognitive testing of guide design (n = 251) and content (n = 261) occurred in English and Spanish in New Jersey and Arizona with parents and home visitation staff who would present the guides. Interviews investigated perceptions of content usefulness and parent comprehension. Findings were also examined in light of theoretical underpinnings. Both home visitation staff and parents felt the guides were very readable and useful. Parents appreciated use of motivational interviewing techniques and Adult Learning Theory. Current research is testing these guides through an in-home, randomized control trial. PMID:26266419

  13. Measurement and modeling of energetic material mass transfer to soil pore water :project CP-1227 FY03 annual technical report.

    SciTech Connect

    Phelan, James M.; Barnett, James L.; Kerr, Dayle R.

    2004-01-01

    Military test and training ranges operate with live fire engagements to provide realism important to the maintenance of key tactical skills. Ordnance detonations during these operations typically produce minute residues of parent explosive chemical compounds. Occasional low order detonations also disperse solid phase energetic material onto the surface soil. These detonation remnants are implicated in chemical contamination impacts to groundwater on a limited set of ranges where environmental characterization projects have occurred. Key questions arise regarding how these residues and the environmental conditions (e.g., weather and geostratigraphy) contribute to groundwater pollution impacts. This report documents interim results of experimental work evaluating mass transfer processes from solid phase energetics to soil pore water. The experimental work is used as a basis to formulate a mass transfer numerical model, which has been incorporated into the porous media simulation code T2TNT. This report documents the results of the Phase III experimental effort, which evaluated the impacts of surface deposits versus buried deposits, energetic material particle size, and low order detonation debris. Next year, the energetic material mass transfer model will be refined and a 2-d screening model will be developed for initial site-specific applications. A technology development roadmap was created to show how specific R&D efforts are linked to technology and products for key customers.

  14. Adolescent Connections: A Guide to Selecting Resource Materials for Parents of Adolescents.

    ERIC Educational Resources Information Center

    Sheriff, Christine M.

    Since 1989, ParentLink has been devoted to supporting Missouri families and children by working with community teams to promote and support parenting efforts through a variety of means. Noting the widespread problem with high-risk behavior among Missouri adolescents and the importance of communication between parents and their adolescents in…

  15. Military Curriculum Materials for Vocational and Technical Education. Soils Engineering 3-1. Edition 1.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This individualized, self-paced course for independent study in soils engineering was adapted from military curriculum materials for use in vocational education. The course is designed to acquaint students with various soil types and their characteristics using various procedures, tests, and recording forms. Some of these duties are determining…

  16. Reduction and persulfate oxidation of nitro explosives in contaminated soils using Fe-bearing materials.

    PubMed

    Oh, Seok-Young; Yoon, Hyun-Su; Jeong, Tae-Yong; Kim, Sang Don; Kim, Dong-Wook

    2016-07-13

    The oxidative and reductive transformation of nitro explosives in contaminated soils with Fe-bearing materials and persulfate (S2O8(2-)) was examined via batch experiments. Zero-valent cast iron [Fe(0)], steel dust from a steel manufacturing plant, and FeS rapidly reduced 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in soil under anaerobic conditions as long as a sufficient amount of water was present. The Fe-bearing materials also effectively activated persulfate to enhance the oxidative transformation of TNT and RDX in soil-water systems. Kinetically, reductive and oxidative transformations removed more than 90% of the explosives from a soil-water system within 5 h under the given conditions. Pseudo-first-order rates in the range of 0.7-23.4 h(-1) were observed. By increasing the concentration of persulfate or Fe-bearing materials, the oxidative transformation could be promoted. Treated soils via redox reactions using the Fe-bearing materials did not show significant toxicity, except for the case of TNT-contaminated soils oxidized by FeS-assisted persulfate. Considering the kinetics of explosive degradation and the toxicity of treated wastewaters and soils, Fe(0) or steel dust-assisted persulfate oxidation may be a safe option as an ex situ remediation process for the treatment of explosive-contaminated soils. PMID:27327861

  17. Unit The World of the Soil, First Trial Materials, Inspection Set, [Australian Science Education Project].

    ERIC Educational Resources Information Center

    Australian Council for Educational Research, Hawthorn.

    The Australian Science Education project is producing materials designed for use in grades 7 - 10 of Australian schools. This is the first trial version of a unit expected to take about 20 40-minute periods to complete. Included are a teacher's guide to the unit, four pupil booklets ("Looking at Soils,""Things to do With Soils,""What is it…

  18. Using soil E horizon in salvaged topsoil material - effect on soil texture

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Topsoil is a limited natural resource that needs to be efficiently salvaged during landscape reconstruction operations for its further use as topsoil. Current guidelines for borrowed topsoil define topsoil as the surface layer of native soil, or soil A horizon. Using information from nearly 8,000 ...

  19. Trace elements in soil and biota in confined disposal facilities for dredged material.

    PubMed

    Beyer, W N; Miller, G; Simmers, J W

    1990-01-01

    We studied the relation of trace element concentrations in soil to those in house mice (Mus musculus), common reed (Phragmites australis) and ladybugs (Coccinella septempunctata at five disposal facilities for dredged material. The sites had a wide range of soil trace element concentrations, acid soils and a depauperate fauna. They were very poor wildlife habitat because they were dominated by the common reed. Bioassay earthworms exposed to surface soils from three of the five sites died, whereas those exposed to four of five soils collected a meter deep survived, presumably because the deeper, unoxidized soil, was not as acid. Concentrations of Ni and Cr in the biota from each of the sites did not seem to be related to the concentrations of the same elements in soil. Although Pb, Zn and Cu concentrations in biota were correlated with those in soil, the range of concentrations in the biota was quite small compared to that in soil. The concentrations of Pb detected in mice were about as high as the concentrations previously reported in control mice from other studies. Mice from the most contaminated site (530 ppm Pb in soil) contained only slightly more Pb (8 ppm dry wt) than did mice (2-6 ppm dry wt) from sites containing much less Pb (22-92 ppm in soil). Despite the acid soil conditions, very little Cd was incorporated into food chains. Rather, Cd was leaching from the surface soil. We concluded that even the relatively high concentrations of trace elements in the acid dredged material studied did not cause high concentrations of trace elements in the biota. PMID:15092276

  20. Inexpensive and Easily Made Instructional Materials: A Training Manual for Teachers and Parents for Working with Preschool Children.

    ERIC Educational Resources Information Center

    Kutac, Ethel M., Comp.

    Intended for use in parent education activities, the manual presents guidelines for making 24 instructional toys and lesson plans for using the toys with preschool handicapped children. Each toy is presented in terms of an illustration, a list of specific skills to be developed by the child using the toy, materials needed, time required to make…

  1. Online Soil Science Lesson 3: Soil Forming Factors

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This lesson explores the five major factors of soil formation, namely: 1) climate; 2) organisms; 3) time; 4) topography; and 5) parent material and their influence in forming soil. The distinction between active and passive factors, moisture and temperature regimes, organism and topographic influen...

  2. F sorption/desorption on two soils and on different by-products and waste materials.

    PubMed

    Quintáns-Fondo, Ana; Ferreira-Coelho, Gustavo; Paradelo-Núñez, Remigio; Nóvoa-Muñoz, Juan Carlos; Arias-Estévez, Manuel; Fernández-Sanjurjo, María J; Álvarez-Rodríguez, Esperanza; Núñez-Delgado, Avelino

    2016-07-01

    We used batch-type experiments to study F sorption/desorption on a forest soil, a vineyard soil, pyritic material, granitic material, finely and coarsely ground mussel shell, mussel shell calcination ash, oak wood ash, pine-sawdust, slate processing fines, and three different mixtures that included three components: sewage sludge, mussel shell ash, and calcined mussel shell or pine wood ash. The three waste mixtures, forest soil, pyritic material, and shell ash showed high sorption capacity (73-91 % of added F) and low desorption, even when 100 mg F L(-1) was added. All these materials (and to a lower extent wood ash) could be useful to remove F from polluted media (as certain soils, dumping sites, and contaminated waters). The vineyard soil, the granitic material, mussel shell, slate fines, and pine-sawdust were less effective in F removal. In most cases, sorption data fitted better to the Freundlich than to the Langmuir equation. These results can be useful to program the correct management of the soils, by-products, and waste materials assayed, mostly in situations where F concentrations are excessive and F removal should be promoted. PMID:27250088

  3. Does thermal carbonization (Biochar) of organic material increase more merits for their amendments of sandy soil?

    NASA Astrophysics Data System (ADS)

    Wu, Y.; Xu, G.; Sun, J. N.; Shao, H. B.

    2014-02-01

    Organic materials (e.g. furfural residue) are generally believed to improve the physical and chemical properties of the soils with low fertility. Recently, biochar have been received more attention as a possible measure to improve the carbon balance and improve soil quality in some degraded soils. However, little is known about their different amelioration of a sandy saline soil. In this study, 56d incubation experiment was conducted to evaluate the influence of furfural and its biochar on the properties of saline soil. The results showed that both furfural and biochar greatly reduced pH, increased soil organic carbon (SOC) content and cation exchange capacity (CEC), and enhanced the available phosphorus (P) in the soil. Furfural is more efficient than biochar in reducing pH: 5% furfural lowered the soil pH by 0.5-0.8 (soil pH: 8.3-8.6), while 5% biochar decreased by 0.25-0.4 due to the loss of acidity in pyrolysis process. With respect to available P, 5% of the furfural addition increased available P content by 4-6 times in comparison to 2-5 times with biochar application. In reducing soil exchangeable sodium percentage (ESP), biochar is slightly superior to furfural because soil ESP reduced by 51% and 43% with 5% furfural and 5% biochar addition at the end of incubation. In addition, no significant differences were observed between furfural and biochar about their capacity to retain N, P in leaching solution and to increase CEC in soil. These facts may be caused by the relatively short incubation time. In general, furfural and biochar have different amendments depending on soil properties: furfural was more effectively to decrease pH and to increase available P, whereas biochar played a more important role in increasing SOC and reducing ESP of saline soil.

  4. Minimizing soil remediation volume through specification of excavation and materials handling procedures

    SciTech Connect

    Oresik, W.L.S.; Otten, M.T.; Nelson, M.D.

    1994-12-31

    The technologies currently available for treating soils contaminated with the explosives 2,4,6-trinitroluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazene (RDX) are both limited and expensive. Therefore, an important consideration in soils remediation is the preparation of construction specifications and contract drawings which limit the volume of soil that will be required to undergo treatment. Construction specifications and contract drawings were developed for the Contaminated Soil Remediation of the Explosives Washout Lagoons at Umatilla Depot Activity (UMDA) with the following primary objectives: (1) limit the volume of soil excavated from the Explosives Washout Lagoons and Explosives Washout Plant Areas, (2) minimize materials handling, and (3) reduce the excavated volume of soil which will undergo treatment.

  5. Soil Materials and Health: An new experience for teaching

    NASA Astrophysics Data System (ADS)

    Del Hoyo Martínez, Carmen

    2014-05-01

    Cationic clays are very extended compounds on the earth surface so they constitute the main component of soils and sedimentary rocks. Due to their presence and special properties that they have, mankind has used them with therapeutic aims from Prehistory, not being rare to find references to this subject in works of classic authors. During the Renaissance and with the appearance of the first Pharmacopeia, its use was regulated to a certain extent. The scientific development reached during the XXth century has allowed to understand and to study the reasons of the useful and peculiar properties of clays, directly related to their colloidal size and crystalline structure. These properties are translated in a high specific surface area, optimal rheological properties and/or excellent sorptive capacity; everything makes cationic clays very useful for a wide range of applications. In the field of health, cationic clays are used in Pharmaceutical Technology and Dermopharmacy as ideal excipients and substances of suitable biological activity due to their chemical inertness and low or null toxicity for the patient (Carretero, 2002; Lopez Galindo et al., 2005; Choy et al., 2007; del Hoyo, 2007). Cationic clays can be used in a wide range of applications in health. However, it must be also considered that the risk exposure to cationic clays may cause several diseases, as it has been seen above. Cationic clays have been used as excipients and active principles in the pharmaceutical industry. The last tendencies are their use in geomedicine, as much to come up as to treat diseases. One stands out his presence in spas and aesthetic medicine. Development of new pharmaceutical formulations is observed, based on cationic clays, for cancer therapy. It has to emphasize the importance in the synthesis of biosensors with cationic clays. Cationic clays can be considered a group of promising materials in the development of new health applications. The study of the use of the cationic

  6. Geobotanical discrimination of ultramafic parent materials An evaluation of remote sensing techniques

    NASA Technical Reports Server (NTRS)

    Mouat, D. A.; Morrissey, L. A.; Horn, E. M.

    1984-01-01

    Color and color infrared aerial photography and imagery acquired from a Daedalus DEI-1260 multispectral airborne scanner were employed in an investigation to discriminate ultramafic rock types in a test site in southwest Oregon. An analysis of the relationships between vegetation characteristics and parent materials was performed using a vegetation classification and map developed for the project, lithologic information derived from published geologic maps of the region, and terrain information gathered in the field. Several analytical methods, including visual image analysis, band ratioing, principal components analysis, and contrast enhancement and subsequent color composite generation were used in the investigation. There was a close correspondence between vegetation types and major rock types. These were readily discriminated by the remote sensing techniques. It was found that ultramafic rock types were separable from non-ultramafic rock types and serpentine was distinguishable from non-serpentinized peridotite. Further investigations involving spectroradiometric and digital classification techniques are being performed to further identify rock types and to discriminate chromium and nickel-bearing rock types.

  7. Development of Low Cost Soil Stabilization Using Recycled Material

    NASA Astrophysics Data System (ADS)

    Ahmad, F.; Yahaya, A. S.; Safari, A.

    2016-07-01

    Recycled tyres have been used in many geotechnical engineering projects such as soil improvement, soil erosion and slope stability. Recycled tyres mainly in chip and shredded form are highly compressible under low and normal pressures. This characteristic would cause challenging problems in some applications of soil stabilization such as retaining wall and river bank projects. For high tensile stress and low tensile strain the use of fiberglass would be a good alternative for recycled tyre in some cases. To evaluate fiberglass as an alternative for recycled tyre, this paper focused on tests of tensile tests which have been carried out between fiberglass and recycled tyre strips. Fibreglass samples were produced from chopped strand fibre mat, a very low-cost type of fibreglass, which is cured by resin and hardener. Fibreglass samples in the thickness of 1 mm, 2 mm, 3 mm and 4 mm were developed 100 mm x 300 mm pieces. It was found that 3 mm fibreglass exhibited the maximum tensile load (MTL) and maximum tensile stress (MTS) greater than other samples. Statistical analysis on 3 mm fibreglass indicated that in the approximately equal MTL fibreglass samples experienced 2% while tyre samples experienced 33.9% ultimate tensile strain (UTST) respectively. The results also showed an approximately linear relationship between stress and strain for fibreglass samples and Young's modulus (E), ranging from 3581 MPa to 4728 MPa.

  8. Mineral materials as feasible amendments to stabilize heavy metals in polluted urban soils.

    PubMed

    Zhang, Mingkui; Pu, Jincheng

    2011-01-01

    Four minerals, agricultural limestone (AL), rock phosphate (RP), palygorskite (PG), and calcium magnesium phosphate (CMP), were evaluated by means of chemical fractions of heavy metals in soils and concentrations of heavy metals in leachates from columns to determine their ability to stabilize heavy metals in polluted urban soils. Two urban soils (calcareous soil and acidic soil) polluted with cadmium, copper, zinc and lead were selected and amended in the laboratory with the mineral materials) for 12 months. Results indicated that application of the mineral materials reduced exchangeable metals in the sequence of Pb, Cd > Cu > Zn. The reduction of exchangeable fraction of heavy metals in the soils amended with different mineral materials followed the sequence of CMP, PG > AL > RP. Reductions of heavy metals leached were based on comparison with cumulative totals of heavy metals eluted through 12 pore volumes from an untreated soil. The reductions of the metals eluted from the calcareous soil amended with the RP, AL, PG and CMP were 1.98%, 38.89%, 64.81% and 75.93% for Cd, 8.51%, 40.42%, 60.64% and 55.32% for Cu, 1.76%, 52.94%, 70.00% and 74.12% for Pb, and 28.42%, 52.74%, 64.38% and 49.66% for Zn. Those from the acidic soil amended with the CMP, PG, AL, and RP were 25.65%, 68.06%, 78.01% and 79.06% for Cd, 26.56%, 49.64%, 43.40% and 34.68% for Cu, 44.44%, 33.32%, 61.11% and 69.44% for Pb, and 18.46%, 43.77%, 41.98% and 40.68% for Zn. The CMP and PG treatments were superior to the AL and RP for stabilizing heavy metals in the polluted urban soils. PMID:21793403

  9. Factor analysis of the elemental composition of Pteridium aquilinum from serpentine and granite soils as a tool in the classification of relations between this composition and the type of parent rock in the Ślęża Massif in Lower Silesia, Poland

    NASA Astrophysics Data System (ADS)

    Samecka-Cymerman, A.; Garbiec, K.; Kolon, K.; Kempers, A. J.

    2009-08-01

    Concentrations of the elements N, P, K, Ca, Mg, S, Fe, Mn, Cu, Zn, Ni, Cr, Co, Mo, Cd and Pb were measured in serpentine and granite soils and in the fern Pteridium aquilinum sampled from the Ślęża Massif in Lower Silesia, Poland. The serpentine soils were typical for serpentine soils in general with deficiency of K and Ca and excess of Mg, Ni and Cr. The principal component analysis (PCA) ordination based on the matrix of concentrations of elements in plants growing on serpentine and granite soils enabled the identification of the parent material from which ferns in this study were collected. This method indicated that the ferns from granite soils were distinguished by higher concentrations of Mo and Pb, while those from serpentine soils were distinguished by higher concentrations of Mg, Ni, Cr and Co. These differences in bioaccumulation reflect the higher concentrations of total and plant-available forms of Mg, Ni, Cr, Co in serpentinite and the higher concentrations of total Mo and total and plant-available Pb in granites as reported in literature. The different parent material types in the Ślęża Massif on which the investigated soils were developed influence the concentration and type of elements accumulated in P. aquilinum.

  10. Correspondence and Least Squares Analyses of Soil and Rock Compositions for the Viking Lander 1 and Pathfinder Sites

    NASA Technical Reports Server (NTRS)

    Larsen, K. W.; Arvidson, R. E.; Jolliff, B. L.; Clark, B. C.

    2000-01-01

    Correspondence and Least Squares Mixing Analysis techniques are applied to the chemical composition of Viking 1 soils and Pathfinder rocks and soils. Implications for the parent composition of local and global materials are discussed.

  11. How physical alteration of technic materials affects mobility and phytoavailabilty of metals in urban soils?

    PubMed

    El Khalil, Hicham; Schwartz, Christophe; El Hamiani, Ouafae; Sirguey, Catherine; Kubiniok, Jochen; Boularbah, Ali

    2016-06-01

    One fundamental characteristic distinguishing urban soils from natural soils is the presence of technic materials or artefacts underlining the influence of human activity. These technic materials have different nature (organic or inorganic) and origins. They contribute to the enrichment of the soil solution by metallic trace elements. The present study aims to determine the effect of physical alteration of the technic coarse fraction on the bioavailability of metallic trace elements in urban Technosols. In general, results show that physical alteration increases the metallic trace elements water extractible concentrations of technic materials. The ability of lettuce to accumulate metallic trace elements, even at low concentrations, underlines the capacity of technic materials to contaminate the anthropised soil solution by bioavailable metals. The highest metal levels, accumulated by the various organs of the lettuce (leaves and roots), were measured in plants grown in presence of metallic particles mixtures. This indicates that the majority of metallic trace elements released by this technic constituent is bioavailable and explains the low plant biomass obtained. The abundant part of metallic trace elements released by the other technic constituents (building materials, bones, wood, plastic and fabric-paper) remains less bioavailable. Under anthropised soil conditions, technic materials have a significant effect on the metallic trace elements behavior. They impact the flow of these metallic elements in Technosols, which can increase their bioavailability and, therefore, the contamination of the food chain. PMID:26999750

  12. Experimental study of nonlinear ultrasonic behavior of soil materials during the compaction.

    PubMed

    Chen, Jun; Wang, Hao; Yao, Yangping

    2016-07-01

    In this paper, the nonlinear ultrasonic behavior of unconsolidated granular medium - soil during the compaction is experimentally studied. The second harmonic generation technique is adopted to investigate the change of microstructural void in materials during the compaction process of loose soils. The nonlinear parameter is measured with the change of two important environmental factors i.e. moisture content and impact energy of compaction. It is found the nonlinear parameter of soil material presents a similar variation pattern with the void ratio of soil samples, corresponding to the increased moisture content and impact energy. A same optimum moisture content is found by observing the variation of nonlinear parameter and void ratio with respect to moisture content. The results indicate that the unconsolidated soil is manipulated by a strong material nonlinearity during the compaction procedure. The developed experimental technique based on the second harmonic generation could be a fast and convenient testing method for the determination of optimum moisture content of soil materials, which is very useful for the better compaction effect of filled embankment for civil infrastructures in-situ. PMID:27010698

  13. Use of Biochar from the Pyrolysis of Waste Organic Material as a Soil Amendment

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Biochar is a charcoal-like material produced by the thermochemical pyrolysis of biomass materials. It is being considered as a potentially significant means of storing carbon for long periods to mitigate greenhouse gases. Much of the interest comes from studies of Amazonian soils that appear to have...

  14. The Use of Soil Forming Factors in the Development of Soil Taxonomy

    NASA Astrophysics Data System (ADS)

    Bockheim, JG; Gennadiyev, AN; Hartemink, Alfred E.; Brevik, Eric C.

    2014-05-01

    The past and present roles of the five soil-forming factors in creating categories in USDA Soil Taxonomy have been analyzed. The factorial and genetic approach is clearly present in Soil Taxonomy, but was not so evident in the 7th Approximation of 1960. Soil climate is the most important factor in Soil Taxonomy. Climate is used at the highest level to define two of the 12 soil orders: Aridisols, the soils of the dry regions, and Gelisols, the permafrost-affected soils and is also used to differentiate suborders in eight of the remaining orders. Parent material is used to fully define two orders: Histosols and Andisols, and partially to define the suborders in the Entisol order (Fluvents, Psamments). Only one group of organisms, the worms (Verm-), is used at the great-group and subgroup levels in several orders. Relief and time are not used in defining taxa in Soil Taxonomy. Three of the eight epipedons are defined on the basis of parent material (folistic, histic, melanic), two on the basis of human activities (anthropic and plaggen), and two from the interaction of climate and vegetation (mollic and umbric). Of the 19 subsurface horizons, 11 originate from the interaction of climate and parent material. This analysis reveals there is an imbalance in the utilization of the soil-forming factors in Soil Taxonomy, with an emphasis on climate and parent material.

  15. Immobilisation of Cu, Pb and Zn in Scrap Metal Yard Soil Using Selected Waste Materials.

    PubMed

    Kamari, A; Putra, W P; Yusoff, S N M; Ishak, C F; Hashim, N; Mohamed, A; Isa, I M; Bakar, S A

    2015-12-01

    Immobilisation of heavy metals in a 30-year old active scrap metal yard soil using three waste materials, namely coconut tree sawdust (CTS), sugarcane bagasse (SB) and eggshell (ES) was investigated. The contaminated soil was amended with amendments at application rates of 0 %, 1 % and 3 % (w/w). The effects of amendments on metal accumulation in water spinach (Ipomoea aquatica) and soil metal bioavailability were studied in a pot experiment. All amendments increased biomass yield and reduced metal accumulation in the plant shoots. The bioconcentration factor and translocation factor values of the metals were in the order of Zn > Cu > Pb. The addition of ES, an alternative source of calcium carbonate (CaCO3), has significantly increased soil pH and resulted in marked reduction in soil metal bioavailability. Therefore, CTS, SB and ES are promising low-cost immobilising agents to restore metal contaminated land. PMID:26395356

  16. Diverse Chemical Zoning Trends in Acapulco Chromites: How Many Sources for the Parental Materials?

    NASA Astrophysics Data System (ADS)

    El Goresy, A.; Janicke, J.

    1995-09-01

    Acapulco is considered to be a link between primitive chondritic meteorites and the differentiated achondrites. Its parent body presumably formed by accretion of material of chondritic compositions at an fO2 that lies between that of H- and enstatite chondrites [1]. The accreted chondritic material was subjected 4.557 Gyr ago to peak temperatures close to 1200 degrees C that lead to partial melting and extensive recrystallization [1, 2]. Seven morphologically different types of graphite with large variations in C- and N-isotopic compositions were recently reported from Acapulco [3, 4]. At least four distinct isotopic reservoirs are required to explain the C- and N-isotopic compositions of these graphites [3, 4]. While the silicate minerals in Acapulco have isotopically heavy N (delta^(15)N = + 15 per mil) chromites were found to be isotopically light (delta^(15)N = _ 75 to _ 82 per mil). Chromite occurs in Acapulco in six different assemblages: (1) as inclusions in silicates, (2) in FeNi, (3) in troilite, (4) with FeNi and troilite, (5) with FeNi and silicates, and (6) with troilite and silicates. It is also rarely present as small idiomorphic inclusions in plagioclase. Chromites in contact with silicates display no chemical zoning for Cr, Al, Ti, Fe, Mg, Mn, or Zn to the silicate borders thus indicating high degree of equilibration with the silicate neighbours. The MgO-contents of chromites in metals and troilites (4.74 to 7.2 %) are relatively lower and their compositional ranges are relatively wider than those in contact with silicates (6.1 to 7.69 %). Zoning profiles of MgO and FeO in chromites in all assemblages are quite flat. Chromites in contact with metals and troilite display a variety of zoning patterns of Cr, Al, Ti, and Zn. All these chromite types , however, depict the same MnO zoning trends with low MnO-contents in their cores (0.96 to 2.14 %) than in their rims to metal or troilite (1.7 to 3.1 %). With few exceptions, the zoning behaviour of Cr, Al

  17. [Effect and mechanism of immobilization of cadmium and lead compound contaminated soil using new hybrid material].

    PubMed

    Wang, Lin; Xu, Ying-Ming; Liang, Xue-Feng; Sun, Yang; Qin, Xu

    2011-02-01

    The effect of new hybrid material and its compound treatments with phosphate on immobilization of cadmium and lead in contaminated soil was investigated using a pot-culture experiment, and the immobilization mechanism of hybrid material was clarified through analysis of heavy metal fractions, sorption equilibration experiment and X-ray photoelectron spectroscopy (XPS). The single treatments of hybrid material could not significantly promote growth of Brassica chinensis, while the compound treatments of hybrid material and phosphate markedly increased dry biomass of shoots and roots, with maximal increases of 75.53% and 151.22%, respectively. Different hybrid material treatments could significantly reduce Cd and Pb concentrations in shoots, with maximal reductions of 66.79% and 48.62%, respectively, and the compound amendment treatments appeared more efficient than the single amendment treatments in reducing Cd and Pb uptake of B. chinensis. Different hybrid material treatments could significantly decrease concentrations of toxicity characteristic leaching procedure (TCLP) extractable Cd and Pb, and the compound hybrid material treatments appeared more efficient than the single treatments in reducing TCLP extractable Cd and Pb. Through the formation of bidentate ligand between metal ions and surface sulfhydryl by complexing reaction, the hybrid material could absorb and fix mobile fractions of Cd and Pb in soil, and promote transformation of acid extractable Cd and Pb into residual fraction, resulting in significant reduction of heavy metals bioavailability and mobility and then fixing remediation of contaminated soil. In summary, the compound treatment of hybrid material and phosphate is the most effective treatment for immobilization of Cd and Pb in contaminated soils, and the hybrid material inactivates Cd and Pb in soil mainly through special chemical adsorption. PMID:21528587

  18. Plastic Fibre Reinforced Soil Blocks as a Sustainable Building Material

    NASA Astrophysics Data System (ADS)

    Prasad, C. K. Subramania; Nambiar, E. K. Kunhanandan; Abraham, Benny Mathews

    2012-10-01

    Solid waste management, especially the huge quantity of waste plastics, is one of the major environmental concerns nowadays. Their employability in block making in the form of fibres, as one of the methods of waste management, can be investigated through a fundamental research. This paper highlights the salient observations from a systematic investigation on the effect of embedded fibre from plastic waste on the performance of stabilised mud blocks. Stabilisation of the soil was done by adding cement, lime and their combination. Plastic fibre in chopped form from carry bags and mineral water bottles were added (0.1% & 0.2% by weight of soil) as reinforcement. The blocks were tested for density, and compressive strength, and observed failure patterns were analysed. Blocks with 0.1% of plastic fibres showed an increase in strength of about 3 to 10%. From the observations of failure pattern it can be concluded that benefits of fibre reinforcement includes both improved ductility in comparison with raw blocks and inhibition of crack propogation after its initial formation.

  19. Soil Loss From Tillage Ridge as Affected by Waste Materials and Soil Amendments

    Technology Transfer Automated Retrieval System (TEKTRAN)

    In semi-arid regions with low crop residues, tillage ridges are used to mitigate wind and water erosion. Unfortunately, without sufficient immobile soil aggregates, bare ridges also often need additional protection. From late winter through early summer of 2006-2008 the reduction in erosion by vario...

  20. Soil as an inexhaustible and high-performance anode material for Li-ion batteries.

    PubMed

    Hu, Xiaofei; Zhang, Kai; Cong, Liang; Cheng, Fangyi; Chen, Jun

    2015-11-11

    Herein, we demonstrate that by a simple treatment of heating and ball-milling, soil is endowed with a 77.2% degree of defects and acts as a high-performance anode material for soil/Li half cells and 18650-type LiNi0.915Co0.075Al0.1O2 (NCA)/soil full batteries that displayed a high and stable capacity of 3200 mA h (corresponding to 176 W h kg(-1) and 522 W h L(-1)) in the 200th cycle at a high current of 4 A. PMID:26372419

  1. [Study on Paddy Soil Chronosequences Based on Visiblc-Near Infrared Diffuse Reflectance Spectra].

    PubMed

    Wu, Deng-wei; Zhang, Gan-lin

    2015-12-01

    To investigate spectral characteristics of different soil compositions, eight soil profiles from two paddy soil chronosequences developed on red clays and red sandstones respectively were collected in Jiangxi Province. A total of 37 soil samples were taken from each soil horizons of the profiles. The paddy soil chronosequences were chosen mainly because all soil profiles have the same land management and thus parent materials and rice cultivation time would be two major soil formative factors. This makes it possible to study spectral response characteristics of soil organic matter (SOM) and parent material characteristics. We measured diffuse reflectance spectra data of soil samples using the Cary 5000 spectrophotometer at 350-2500 nm spectral range. Spectral response characteristics of SOM and inorganic minerals in paddy soils were analyzed according to different soil horizons, soil forming times and parent materials. Experiment results showed that for soil samples from a single parent material, overall reflectance presented by PC_1 score can be calibrated for soil organic matter (SOM) content with high precision (R(RC)² = 0.91, R(RS)² = 0.79), even though the SOM content was low (not more than 20 g · kg⁻¹). The absorption strength (AS) at 1400, 1900 and 2200 nm was mainly affected by the minerals inherited from parent materials. And the more the sample was near to bottom of a soil profile, the higher the AS value. Samples with the same mineral components had the similar AS ratio among these three wavelength locations. The differences in parent materials can significantly affect spectral curve shape and spectral absorption strength. To make the calibration more interpretative, parent material factors should be considered. PMID:26964213

  2. Shock-treated Lunar Soil Simulant: Preliminary Assessment as a Construction Material

    NASA Technical Reports Server (NTRS)

    Boslough, Mark B.; Bernold, Leonhard E.; Horie, Yasuyuki

    1992-01-01

    In an effort to examine the feasibility of applying dynamic compaction techniques to fabricate construction materials from lunar regolith, preliminary explosive shock-loading experiments on lunar soil simulants were carried out. Analysis of our shock-treated samples suggests that binding additives, such as metallic aluminum powder, may provide the necessary characteristics to fabricate a strong and durable building material (lunar adobe) that takes advantage of a cheap base material available in abundance: lunar regolith.

  3. Shock-treated lunar soil simulant: Preliminary assessment as a construction material

    NASA Astrophysics Data System (ADS)

    Boslough, Mark B.; Bernold, Leonhard E.; Horie, Yasuyuki

    In an effort to examine the feasibility of applying dynamic compaction techniques to fabricate construction materials from lunar regolith, preliminary explosive shock-loading experiments on lunar soil simulants were carried out. Analysis of our shock-treated samples suggests that binding additives, such as metallic aluminum powder, may provide the necessary characteristics to fabricate a strong and durable building material (lunar adobe) that takes advantage of a cheap base material available in abundance: lunar regolith.

  4. Inorganic materials as ameliorants for soil remediation of metal toxicity to wild mustard (Sinapis arvensis L.).

    PubMed

    Ribeiro Filho, Mateus Rosas; Siqueira, José Oswaldo; Vangronsveld, Jaco; Soares, Cláudio Roberto Fonsêca Sousa; Curi, Nilton

    2011-01-01

    The ameliorating effects of different inorganic materials were investigated on a soil originating from a zinc smelter dumping site contaminated by toxic metals. Wild mustard (Sinapis arvensis L.) was used as a test plant. The soil was amended with different doses of mining sludge, Perferric Red Latosol (LVj), steel shots, cyclonic ash, silifertil, and superphosphate. The most effective amendments improved plant growth with 45% and reduced metal uptake by over 70% in comparison to untreated soil. Reductions in availability as estimated by BaCl2-extractable metals reached up to 90% for Zn and 65% for Cd as compared to unamended soil. These reductions were associated with lower shoot and root metal contents. Shoot Zn content was reduced from 1,369 microg g(-1) in plants grown on untreated soil to 377 microg g(-1) when grown on cyclonic ash amended soil while Cd decreased from 267 to 44 microg g(-1) in steel shots amended soil. Superphosphate addition had no ameliorating effect. On the contrary, it increased BaCl2-extractable amounts of Zn. Considering all parameters we determined, steel shots, cyclonic ash and silifertil are the most promising for remediating metal contaminated soil in the tropics. Further studies evaluating impacts, cost-effectiveness and durability of effects will be conducted. PMID:21598779

  5. Carbon dioxide emissions from agricultural soils amended with livestock-derived organic materials

    NASA Astrophysics Data System (ADS)

    Pezzolla, D.; Said-Pullicino, D.; Gigliotti, G.

    2009-04-01

    Carbon dioxide gas xchange between terrestrial ecosystems and the atmosphere, as well as the carbon sink strength of various arable land ecosystems, is of primary interest for global change research. Measures for increasing soil C inputs include the preferential use of livestock-derived organic materials (e.g. animal manure and slurries, digestate from biogas production plants and compost). The application of such materials to agricultural soils returns essential nutrients for plant growth and organic matter to maintain long-term fertility. Whether or not such practices ultimately result in sustained C sequestration at the ecosystem level will depend on their mineralization rates. This work presents preliminary results from a laboratory incubation trial to evaluate carbon dioxide fluxes from two agricultural soils (a calcareous silt loam and a silty clay loam) amended with agricultural doses of (i) pig slurry (PSL), (ii) the digestate from the anaerobic fermentation of pig slurries (AAS) and (ii) a compost from the aerobic stabilisation of the digestate (LDC). These subsequent steps of slurry stabilisation resulted in a decrease in the content of labile organic matter which was reflected in a reduction in maximum carbon dioxide emission rates from amended soils. Measurements have shown that peak emissions from soils occur immediately after application of these organic materials (within 5 days) and decrease in the order PSL > AAS > LDC. Moreover, mean cumulative emissions over the first 40 days showed that a higher percentage (about 44%) of the C added with PSL was mineralised respect to C added with AAS (39%) and LDC (25%). Although it was hypothesised that apart from the quantity and stability of the added organic materials, even soil characteristics could influence C mineralisation rates, no significant differences were observed between emission fluxes for similarly treated soils. Mean cumulative emission fluxes after 40 days from treatment were of 114, 103 and

  6. Chemical immobilization of Pb, Cu, and Cd by phosphate materials and calcium carbonate in contaminated soils.

    PubMed

    Huang, Guoyong; Su, Xiaojuan; Rizwan, Muhammad Shahid; Zhu, Yifei; Hu, Hongqing

    2016-08-01

    Soil contamination with toxic metals has increasingly become a global concern over the past few decades. Phosphate and carbonate compounds are good passivation materials for Pb immobilization, while the effect of phosphate and carbonate on the immobilization of multiple heavy metals (Pb, Cu, and Cd) in contaminated soils was seldom investigated. In this study, bone meal (BM), phosphate rock (PR), oxalic acid-activated phosphate rock (APR), super phosphate (SP), and calcium carbonate (CC) were added to the contaminated soils to evaluate the effect of phosphate materials and calcium carbonate on the immobilization of Pb, Cu, and Cd. The results showed that the pH of the treated soils increased 1.3-2.7, except SP which decreased 0.5 at most. Compared to the control treatment, all phosphates and calcium carbonate added to the polluted soils increased the fraction of residual metals, and the application of APR, PR, BM, and CC significantly reduced exchangeable and carbonate-bound fraction metals. PR and APR were the most effective for the immobilization of Pb, Cu, and Cd in the soils among these materials. Moreover, the concentrations of all metals in the toxicity characteristic leaching procedure (TCLP) leachate decreased with increasing amounts of amendments, and the concentrations of Pb in the TCLP leachate for soils treated with PR and APR were below the nonhazardous regulatory limit of 5 mg L(-1) (US Environmental Protection Agency). Based on our results, phosphate rock and oxalic acid-activated phosphate rock are effective in the immobilization of multiple metals by reducing their mobility in the co-contaminated soils. PMID:27197655

  7. Beneficial Use of Dredge Materials for Soil Reconstruction and Development of Dredge Screening Protocols.

    PubMed

    Koropchak, Sara C; Daniels, W Lee; Wick, Abbey; Whittecar, G Richard; Haus, Nick

    2016-01-01

    Upland placement of dredge sediments has the potential to provide beneficial reuse of suitable sediments for agricultural uses or urban soil reconstruction. However, the use of many dredge materials is limited by contaminants, and most established screening protocols focus on limiting major contaminants such as heavy metals and polycyclic aromatic hydrocarbons and generally ignore fundamental agronomic parameters. Since 2001, we have placed over 450,000 m of Potomac River fresh water dredge materials and 250,000 m of saline materials from various locations into monitored confined upland facilities in Charles City, VA, and documented their conversion to agricultural uses. Groundwater and soil quality monitoring has indicated no adverse effects from material placement and outstanding agricultural productivity for the freshwater materials. Once placed, saline materials rapidly leach and ripen with quick declines in pH, electrical conductivity, and sodicity, but potentials for local groundwater impacts must be considered. Our experience to date indicates that the most important primary screening parameter is acid-base accounting (potential acidity or lime demand), which should become a mandatory analytical requirement. Our second level of acceptance screening is based on a combination of federal and state residual waste and soil screening standards and basic agronomic principles. High silt+clay and total organic C may also limit rapid use of many dredge materials due to extended dewatering times and physical limitations. This dredge material screening system separates potential upland placement candidates into three soil quality management categories (unsuitable, suitable, and clean fill) with differing monitoring requirements. Similar use of these sediments in urban soil reconstruction is also recommended. PMID:26828161

  8. Lunar surface - Identification of the dark mantling material in the Apollo 17 soil samples

    NASA Technical Reports Server (NTRS)

    Pieters, C.; Charette, M. P.; Adams, J. B.; Mccord, T. B.

    1974-01-01

    Evidence indicates that Apollo 17 sample 74001, a soil consisting of very dark spheres, is composed almost entirely of the dark mantling material that covers a large region of the southeastern boundary of Mare Serenitatis. Other Apollo 17 samples contain only a component of this material. The underlying basalt in the Taurus-Littrow valley appears to be an extension of material forming the low-albedo ring around part of Mare Serenitatis and much of the surface of Mare Tranquillitatis. The surface of this basalt region is spectrally distinct from areas with dark mantling material. These results are derived from telescopic and laboratory measurements of the optical properties of lunar soil. Digital vidicon color images are used to map the extent of these material units in the Taurus-Littrow region.

  9. Solar distillation of water from soil and plant materials: a simple desert survival technique.

    PubMed

    Jackson, R D; Van Bavel, C H

    1965-09-17

    Water obtained from soil and plant materials by a simple distillation technique can provide a means for survival under desert conditions. A hemispherical hole in soil (in some cases containing cut plant material) is covered with plastic film formed and held in a conical shape by a rock placed in the center. Water collects on the under side of the plastic, runs to the point of the cone, and drops into the container. A yield of 1.5 liters per day of potable water was obtained from a single "survival still." PMID:5826532

  10. CHARACTERISTICS OF FLORIDA FILL MATERIALS AND SOILS 1990

    EPA Science Inventory

    The report gives results of laboratory work by the University of Florida in support of the Foundation Fill Data Base project of the Foundation Fill Materials Specifications Task Area of the Florida Radon Research Program (FRRP). Work included determination of radon concentrations...

  11. Strontium-doped hematite as a possible humidity sensing material for soil water content determination.

    PubMed

    Tulliani, Jean-Marc; Baroni, Chiara; Zavattaro, Laura; Grignani, Carlo

    2013-01-01

    The aim of this work is to study the sensing behavior of Sr-doped hematite for soil water content measurement. The material was prepared by solid state reaction from commercial hematite and strontium carbonate heat treated at 900 °C. X-Ray diffraction, scanning electron microscopy and mercury intrusion porosimetry were used for microstructural characterization of the synthesized powder. Sensors were then prepared by uniaxially pressing and by screen-printing, on an alumina substrate, the prepared powder and subsequent firing in the 800-1,000 °C range. These sensors were first tested in a laboratory apparatus under humid air and then in an homogenized soil and finally in field. The results evidenced that the screen printed film was able to give a response for a soil matric potential from about 570 kPa, that is to say well below the wilting point in the used soil. PMID:24025555

  12. Strontium-Doped Hematite as a Possible Humidity Sensing Material for Soil Water Content Determination

    PubMed Central

    Tulliani, Jean-Marc; Baroni, Chiara; Zavattaro, Laura; Grignani, Carlo

    2013-01-01

    The aim of this work is to study the sensing behavior of Sr-doped hematite for soil water content measurement. The material was prepared by solid state reaction from commercial hematite and strontium carbonate heat treated at 900 °C. X-Ray diffraction, scanning electron microscopy and mercury intrusion porosimetry were used for microstructural characterization of the synthesized powder. Sensors were then prepared by uniaxially pressing and by screen-printing, on an alumina substrate, the prepared powder and subsequent firing in the 800–1,000 °C range. These sensors were first tested in a laboratory apparatus under humid air and then in an homogenized soil and finally in field. The results evidenced that the screen printed film was able to give a response for a soil matric potential from about 570 kPa, that is to say well below the wilting point in the used soil. PMID:24025555

  13. Heavy metal fractionation and pedogenesis in subalpine and alpine soils on ophiolitic materials, western Alps

    NASA Astrophysics Data System (ADS)

    D'Amico, M.; Previtali, F.

    2009-04-01

    Soils on ultramafic materials are usually rich in Mg, Fe and heavy metals (particularly Ni, Cr, Mn, Co). These chemical properties could cause toxicity effects on biological communities. Metal fractionation shows the soil phases to which metals are associated (exchangeable, associated with organic matter, with amorphous or crystalline Fe or Mn oxides, in the crystal structure of primary minerals), and thus it is strictly related with metal mobilization and bioavailability. Ni, Cr, Mn, Co and Fe fractionations (6 fractions, analysed by a selective sequential extraction technique) were analysed in 6 subalpine and in 17 alpine soils (i.e., respectively under coniferous forest or above the present-day treeline) in the ophiolitic area of Mont Avic Natural Park (Valle d'Aosta, Italian Alps), on soils formed from metal-rich serpentinite or from metal-poor mafic rocks and calcschists. The results show a tight relationship between vegetation, soil forming processes, metal fractionation and bioavailability: below and above the present-day treeline soil forming processes and metal speciation change dramatically. Serpentinite soils are always extremely rich in metals, but metal speciation in analogous habitats is similar on every substrate. The results show a tight relationship between vegetation, soil forming processes, metal fractionation and bioavailability: below and above the present-day treeline soil forming processes and metal speciation change dramatically. Serpentinite soils are always extremely rich in metals, but metal speciation in analogous habitats is similar on every substrate. Under subalpine forest, the main pedogenic process is podzolization. In the extremely acidic and leached podzolic soils, all metals are mobilized and their lowest concentration is in the bleached E horizon, while there is a higher content in organic matter-rich surface horizon and in the spodic (illuvial) B. Not considering the amount associated with primary minerals (residual fraction

  14. Effect of organic materials on the chemical properties of saline soil in the Yellow River Delta of China

    NASA Astrophysics Data System (ADS)

    Yu, Yan; Liu, Jie; Liu, Chunmeng; Zong, Shuang; Lu, Zhaohua

    2015-06-01

    A 180-day incubation experiment was conducted to investigate the effect of different organic materials on the chemical properties of coastal soil with high salinity and relatively low pH. Four organic materials (three kinds of plant residues: straw, composted straw, and fresh reed; and one kind of poultry manure: chicken manure) were applied at a ratio of 15 g·kg-1 to samples of costal saline soil from the Yellow River Delta of China. The results showed that the soil pH and exchangeable sodium percentage (ESP) decreased, whereas soil cation exchangeable capacity (CEC) and macronutrient concentrations increased, regardless of the type of organic material used. All treatments showed a remarkable increase in soil soluble organic carbon (SOC) during the 180-day incubation. The peak values of SOC in descending order were chicken manure, reed, composted straw, straw, and control soil. At the end of incubation, the highest level of SOC occurred in the straw-amended soil, followed by composted straw, reed, and chicken manureamended soils. Soil respiration rate and available nitrogen were significantly influenced by the type of material used. Although reed-amended soil had a relatively high SOC and respiration rate, the ESP was reduced the least. Considering the possible risk of heavy metals caused by chicken manure, it is proposed that straw and composted straw are the more efficient materials to use for reclaiming costal saline soil and improving the availability of macronutrients.

  15. Effect of organic materials on the chemical properties of saline soil in the Yellow River Delta of China

    NASA Astrophysics Data System (ADS)

    Yu, Yan; Liu, Jie; Liu, Chunmeng; Zong, Shuang; Lu, Zhaohua

    2014-09-01

    A 180-day incubation experiment was conducted to investigate the effect of different organic materials on the chemical properties of coastal soil with high salinity and relatively low pH. Four organic materials (three kinds of plant residues: straw, composted straw, and fresh reed; and one kind of poultry manure: chicken manure) were applied at a ratio of 15 g·kg-1 to samples of costal saline soil from the Yellow River Delta of China. The results showed that the soil pH and exchangeable sodium percentage (ESP) decreased, whereas soil cation exchangeable capacity (CEC) and macronutrient concentrations increased, regardless of the type of organic material used. All treatments showed a remarkable increase in soil soluble organic carbon (SOC) during the 180-day incubation. The peak values of SOC in descending order were chicken manure, reed, composted straw, straw, and control soil. At the end of incubation, the highest level of SOC occurred in the straw-amended soil, followed by composted straw, reed, and chicken manureamended soils. Soil respiration rate and available nitrogen were significantly influenced by the type of material used. Although reed-amended soil had a relatively high SOC and respiration rate, the ESP was reduced the least. Considering the possible risk of heavy metals caused by chicken manure, it is proposed that straw and composted straw are the more efficient materials to use for reclaiming costal saline soil and improving the availability of macronutrients.

  16. Development of Paving Material for Footpath and CAR Park Pavement Using Granite Soil

    NASA Astrophysics Data System (ADS)

    Nagamachi, Masaharu; Mizuguchi, Hiroyuki; Inoue, Kentaro; Kamada, Koichi

    It is required to develop new paving materials for pavements, such as footpaths, car parks, etc., in parks, having good landscape. Such paving materials have been already developed, but these do not have sufficient strength, abrasion resistance and frost resistance. In this study, a new paving was examined material using cement, sand and granite soil. The mix proportion of this material tested was 2:4:4 of cement, sand and granite soil by mass. The maximum flexural and compressive strength were both obtained at a water content of 14% of the total mass, and the strength were several times larger than that of paving material on the market consisting of 10% of cement and 90% granite soil. The abrasion resistance was tested according to ASTM C 779, and this resistance was about four times greater than that of the paving material on the market. The frost resistance was obtained high value compared with the concrete of 72% in water cement ratio by a new simple resisting test method for freezing and thawing using liquid nitrogen and warm water. It is considered that this new paving material is applicable to pavement for footpath, car park, etc.

  17. Influence of soil moisture on soil respiration

    NASA Astrophysics Data System (ADS)

    Fer, Miroslav; Kodesova, Radka; Nikodem, Antonin; Klement, Ales; Jelenova, Klara

    2015-04-01

    The aim of this work was to describe an impact of soil moisture on soil respiration. Study was performed on soil samples from morphologically diverse study site in loess region of Southern Moravia, Czech Republic. The original soil type is Haplic Chernozem, which was due to erosion changed into Regosol (steep parts) and Colluvial soil (base slope and the tributary valley). Soil samples were collected from topsoils at 5 points of the selected elevation transect and also from the parent material (loess). Grab soil samples, undisturbed soil samples (small - 100 cm3, and large - 713 cm3) and undisturbed soil blocks were taken. Basic soil properties were determined on grab soil samples. Small undisturbed soil samples were used to determine the soil water retention curves and the hydraulic conductivity functions using the multiple outflow tests in Tempe cells and a numerical inversion with HYDRUS 1-D. During experiments performed in greenhouse dry large undisturbed soil samples were wetted from below using a kaolin tank and cumulative water inflow due to capillary rise was measured. Simultaneously net CO2 exchange rate and net H2O exchange rate were measured using LCi-SD portable photosynthesis system with Soil Respiration Chamber. Numerical inversion of the measured cumulative capillary rise data using the HYDRUS-1D program was applied to modify selected soil hydraulic parameters for particular conditions and to simulate actual soil water distribution within each soil column in selected times. Undisturbed soil blocks were used to prepare thin soil sections to study soil-pore structure. Results for all soil samples showed that at the beginning of soil samples wetting the CO2 emission increased because of improving condition for microbes' activity. The maximum values were reached for soil column average soil water content between 0.10 and 0.15 cm3/cm3. Next CO2 emission decreased since the pore system starts filling by water (i.e. aggravated conditions for microbes

  18. Studies related to the evolution of the lunar soil materials

    NASA Technical Reports Server (NTRS)

    Carter, J. L.

    1973-01-01

    Studies of the chemistry and morphology of the lunar samples are reported. The presence of fragments of plagoclase in the centers of the impact craters indicate that the glass spheres were derived by meteoritic impact from high velocity particles, while the glass was at high temperatures. From the study of the Apollo 16 samples, it is suggested that this material was formed in a hot impact ejecta blanket, or in an igneous environment, and later exposed to meteoritic impact. It is suggested that particles from Apollo 17 were formed in a cloud of siliceous vapors.

  19. Analyses of exobiological and potential resource materials in the Martian soil

    NASA Technical Reports Server (NTRS)

    Mancinelli, Rocco L.; Marshall, John R.; White, Melisa R.

    1992-01-01

    Potential Martian soil components relevant to exobiology include water, organic matter, evaporites, clays, and oxides. These materials are also resources for human expeditions to Mars. When found in particular combinations, some of these materials constitute diagnostic paleobiomarker suites, allowing insight to be gained into the probability of life originating on Mars. Critically important to exobiology is the method of data analysis and data interpretation. To that end, methods of analysis of potential biomarker and paleobiomarker compounds and resource materials in soils and rocks pertinent to Martian geology are investigated. Differential thermal analysis coupled with gas chromotography is shown to be a highly useful analytical technique for detecting this wide and complex variety of materials.

  20. Fate of organic carbon from different waste materials in cropland soils

    NASA Astrophysics Data System (ADS)

    Paetsch, Lydia; Mueller, Carsten; Rumpel, Cornelia; Houot, Sabine; Kögel-Knabner, Ingrid

    2015-04-01

    Organic amendments are widely used to enhance the fertility of cropland soils. However, there is only scarce knowledge about the long term impact of added organic matter (OM) on the soil organic carbon (SOC) pool. Therefore, we analyzed a long-term field experiment in Feucherolles (France), which regularly received three different composts (home sorted bio-waste mixed with green waste (BIO), municipal solid waste (MSW) and a mixture of green waste and sewage sludge (GWS) and cattle manure since 1998. With these organic materials approximately 4 Mg total OC were added to the soil in two year intervals. The experiment was fully randomized with 4 replicates for each amendment. In September 2013 we took samples from the surface soil (0-5 cm of Ap horizon) of all 4 treatments and the unamended control. To study the chemical alteration and the fate of the added OC into different soil compartments, we fractionated the soils by physical means using a combined density and particle size protocol. Carbon and N content were determined in bulk soils, amendments as well as in size fractions (fPOM, oPOM <20µm and oPOM >20µm, sand, silt and a combined fine silt-clay fraction). Chemical composition was determined by solid-state 13C CPMAS NMR spectroscopy. We found significant higher C contents for the oPOM small and sand fraction of BIO treated soil and for the clay fraction of GWS treated soils (p<0.05). Nitrogen contents were significantly higher for BIO treated soils in bulk soil, fPOM, oPOM small and for GWS treated soils in bulk soil, fPOM and oPOM. The NMR measurements revealed that only the chemical composition of the fPOM differed according to the treatment; towards the more altered fractions as the oPOM small, the compositional differences leveled out and became almost homogeneous. Furthermore, the NMR measurements indicate a similar OC composition within the independent field replicates regarding the different amendments and fractions. As previously shown, N was found

  1. Gender and Material Transfers between Older Parents and Children in Ismailia, Egypt

    ERIC Educational Resources Information Center

    Yount, Kathryn M.; Cunningham, Solveig A.; Engelman, Michal; Agree, Emily M.

    2012-01-01

    In Egypt, kin relations have been governed by a patriarchal contract, which defines expectations for intergenerational support along gendered lines. Social changes may be disrupting these customs and bringing attention to the ways gender may influence intergenerational support in rapidly changing contexts. Using data from 4,465 parent-child dyads…

  2. Data collection handbook to support modeling the impacts of radioactive material in soil

    SciTech Connect

    Yu, C.; Cheng, J.J.; Jones, L.G.; Wang, Y.Y.; Faillace, E.; Loureiro, C.; Chia, Y.P.

    1993-04-01

    A pathway analysis computer code called RESRAD has been developed for implementing US Department of Energy Residual Radioactive Material Guidelines. Hydrogeological, meteorological, geochemical, geometrical (size, area, depth), and material-related (soil, concrete) parameters are used in the RESRAD code. This handbook discusses parameter definitions, typical ranges, variations, measurement methodologies, and input screen locations. Although this handbook was developed primarily to support the application of RESRAD, the discussions and values are valid for other model applications.

  3. Assessment of the Use of Natural Materials for the Remediation of Cadmium Soil Contamination

    PubMed Central

    de O. Pinto, Tatiana; García, Andrés C.; Guedes, Jair do N.; do A. Sobrinho, Nelson M. B.; Tavares, Orlando C. H.

    2016-01-01

    Rice plants accumulate cadmium (Cd2+) within the grain, increasing the danger of human exposure. Natural materials have been used in soil remediation, but few studies have examined the risks (based on the bioavailability of these metals to plants) of using these materials, so the practice remains controversial. In the present study, we evaluated the effectiveness of biochar produced from sugarcane bagasse, vermicompost (VC), vermicompost solid residue (VCR) and humin for remediation of Cd2+-contaminated soils. We characterized the interactions between these materials and Cd2+ and evaluated their capacity to alter Cd2+ availability to rice plants. Our results show that under the conditions in this study, biochar and humin were not effective for soil remediation. Although biochar had high Cd2+ retention, it was associated with high Cd2+ bioavailability and increased Cd2+ accumulation in rice plants. VC and VCR had high Cd2+ retention capacity as well as low Cd2+ availability to plants. These characteristics were especially notable for VCR, which was most effective for soil remediation. The results of our study demonstrate that in the tested materials, the bioavailability of Cd2+ to plants is related to their structural characteristics, which in turn determine their retention of Cd2+. PMID:27341440

  4. METHOD OF ESTIMATING THE TRAVEL TIME OF NONINTERACTING SOLUTES THROUGH COMPACTED SOIL MATERIAL

    EPA Science Inventory

    The pollutant travel time through compacted soil material (i.e., when a pollutant introduced at the top first appears at the bottom) cannot be accurately predicted from the permeability (saturated hydraulic conductivity) alone. The travel time is also dependent on the effective p...

  5. Development of alternating current transmitter of detection system for magnetic material in soil subsurface

    NASA Astrophysics Data System (ADS)

    Indrasari, Widyaningrum; Djamal, Mitra; Srigutomo, Wahyu; Ramli

    2016-03-01

    Generally, detection system for magnetic material in soil subsurface using electromagnetic induction method consists of two parts, they are transmitter and receiver unit. A transmitter must be able to produce a continuous and stable AC current at a certain frequency, meanwhile receiver should be able to catch the secondary magnetic field of magnetic material in soil subsurface. The aim of this study was to develop a new AC current transmitter of detection system for the magnetic material in soil subsurface. This paper will describe the results of the development of AC current transmitter systems, distance characterization of the sensor detection toward horizontal solenoid positions, and characterization of magnetic material in the soil subsurface. It has successfully made the AC current transmitter system, composed of a sinusoidal signal generator, power amplifier, and a source of AC magnetic field. The output of the generator has a frequency varies: 1 kHz, 2 kHz, 5 kHz, and 10 kHz. We found that the AC current transmitter that has been developed able to work properly up to a frequency of 10 kHz.

  6. Assessment of the Use of Natural Materials for the Remediation of Cadmium Soil Contamination.

    PubMed

    de O Pinto, Tatiana; García, Andrés C; Guedes, Jair do N; do A Sobrinho, Nelson M B; Tavares, Orlando C H; Berbara, Ricardo L L

    2016-01-01

    Rice plants accumulate cadmium (Cd2+) within the grain, increasing the danger of human exposure. Natural materials have been used in soil remediation, but few studies have examined the risks (based on the bioavailability of these metals to plants) of using these materials, so the practice remains controversial. In the present study, we evaluated the effectiveness of biochar produced from sugarcane bagasse, vermicompost (VC), vermicompost solid residue (VCR) and humin for remediation of Cd2+-contaminated soils. We characterized the interactions between these materials and Cd2+ and evaluated their capacity to alter Cd2+ availability to rice plants. Our results show that under the conditions in this study, biochar and humin were not effective for soil remediation. Although biochar had high Cd2+ retention, it was associated with high Cd2+ bioavailability and increased Cd2+ accumulation in rice plants. VC and VCR had high Cd2+ retention capacity as well as low Cd2+ availability to plants. These characteristics were especially notable for VCR, which was most effective for soil remediation. The results of our study demonstrate that in the tested materials, the bioavailability of Cd2+ to plants is related to their structural characteristics, which in turn determine their retention of Cd2+. PMID:27341440

  7. Free and Inexpensive Materials Available for Teaching Conservation Education: Soil and Water.

    ERIC Educational Resources Information Center

    Cousins, Genevieve; Smith, Bonnie Mae

    This publication was prepared to accompany the revised "Soil and Water Section" of "Guides for Teacher Conservation in the Schools of Louisiana." Its purpose is to provide teachers with information about possible sources of teaching materials that can be obtained free or with only a small expenditure of funds. Each item listed is annotated for the…

  8. Air-surface exchange of mercury with soils amended with ash materials.

    PubMed

    Ericksen, Jody; Gustin, Mae Sexauer

    2006-07-01

    Air-surface exchange of mercury (Hg) was measured from soil low in Hg (0.013 mg/kg) amended with four different ash materials: a wood ash containing -10% coal ash (0.070 mg/kg Hg), a mixture of two subbituminous coal fly ashes (0.075 mg/kg Hg), a subbituminous coal ash containing -10% petroleum coke ash (1.2 mg/kg Hg), and an ash from incinerated municipal sewage sludge (4.3 mg/kg Hg) using a dynamic flux chamber. Ash was added to soil to simulate agricultural supplements, soil stabilization, and pad layers used in livestock areas. For the agricultural amendment, -0.4% ash was well mixed into the soil. To make the stabilized soil that could be used for construction purposes, -20% ash was mixed into soil with water. The pad layer consisted of a wetted 1-cm layer of ash material on the soil surface. Diel trends of Hg flux were observed for all of the substrates with significantly higher Hg emissions during the day and negligible flux or deposition of Hg during the night. Hg fluxes, which were measured in the summer months, were best correlated with solar radiation, temperature, and air O3 concentrations. Mean Hg fluxes measured outdoors for unamended soils ranged from 19 to 140 ng/m2 day, whereas those for soil amended with ash to simulate an agricultural application ranged from 7.2 to 230 ng/m2 day. Fluxes for soil stabilized with ash ranged from 77 to 530 ng/m2 day and for soil with pads constructed of ash ranged from -50 to 90 ng/m2 day. Simple analytical tests (i.e., total Hg content, synthetic precipitation leaching procedure, heating, and indoor gas-exchange experiments) were performed to assess whether algorithms based on these tests could be used to predict Hg fluxes observed outdoors using the flux chamber. Based on this study, no consistent relationships could be developed. More work is needed to assess long-term and seasonal variations in Hg flux from (intact and disturbed) substrates before annual estimates of emissions can be developed. PMID:16878589

  9. Air-surface exchange of mercury with soils amended with ash materials

    SciTech Connect

    Jody Ericksen; Mae Sexauer Gustin

    2006-07-15

    Air-surface exchange of mercury (Hg) was measured from soil low in Hg amended with four different ash materials: a wood ash containing {approximately} 10% coal ash, amixture of two subbituminous coal fly ashes, a subbituminous coal ash containing {approximately} 10% petroleum coke ash and an ash from incinerated municipal sewage sludge (4.3 mg/kg Hg) using a dynamic flux chamber. Ash was added to soil to simulate agricultural supplements, soil stabilization, and pad layers used in livestock areas. For the agricultural amendment, {approximately} 0.4% ash was well mixed into the soil. To make the stabilized soil that could be used for construction purposes, {approximately} 20% ash was mixed into soil with water. The pad layer consisted of a wetted 1-cm layer of ash material on the soil surface. Diel trends of Hg flux were observed for all of the substrates with significantly higher Hg emissions during the day and negligible flux or deposition of Hg during the night. Hg fluxes, which were measured in the summer months, were best correlated with solar radiation, temperature, and air O{sub 3} concentrations. Mean Hg fluxes measured outdoors for unamended soils ranged from 19 to 140 ng/m{sup 2} day, whereas those for soil amended with ash to simulate an agricultural application ranged from 7.2 to 230 ng/m{sup 2} day. Fluxes for soil stabilized with ash ranged from 77 to 530 ng/m{sup 2} day and for soil with pads constructed of ash ranged from -50 to 90 ng/m{sup 2} day. Simple analytical tests were performed to assess whether algorithms based on these tests could be used to predict Hg fluxes observed outdoors using the flux chamber. Based on this study, no consistent relationships could be developed. More work is needed to assess long-term and seasonal variations in Hg flux from substrates before annual estimates of emissions can be developed. 45 refs., 8 figs., 3 tabs.

  10. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials.

    PubMed

    Rachor, Ingke; Gebert, Julia; Gröngröft, Alexander; Pfeiffer, Eva-Maria

    2011-05-01

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm(-3), reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100g CH(4)m(-2)d(-1), covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH(4)m(-2)d(-1) and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of

  11. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect

    Rachor, Ingke; Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria

    2011-05-15

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity

  12. Use of Fly Ash as a Liming Material for Corn and Soybean Production on an Acidic Sandy Soil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Fly ash (FA) produced from subbituminous coal combustion can potentially serve as a lime material for crop production in acidic soils in areas. A five-year study was conducted to determine if FA can be used as a liming material in an acid sandy soil under corn and soybean grain production. Fly ash...

  13. Thermal analysis of soil treated with biochars from different raw materials

    NASA Astrophysics Data System (ADS)

    Ana, Méndez; Paola, Cely; Gabriel, Gascó

    2014-05-01

    Thermal analysis (DTA, DSC, TG and dTG) has been used for decades to characterize carbonaceous materials used as fuels (oil, coal). In the last years, these techniques has been used with soils in order to assess proportions of labile and recalcitrant organic matter and to study the evolution of organic matter in amended soils during laboratory incubations. Indeed, thermogravimetric behaviour of soils can be quantified as the weight loss of samples attributed to different temperature ranges: WL1 from 25 to 150ºC; WL2 from 200 to 350ºC and WL3 from 375 to 600ºC . WL2 and WL3 correspond to weight loss associated to organic matter combustion (Worg=WL2+WL3). It is established that first peak was associated with combustion of less humified organic matter, while the second one was related to the more humified. Also, the WL3/WL2 ratio, named thermostability index, was previously identified as a reliable parameter for evaluating the level of stability of organic matter in composts and other organic wastes that indicated the relative amount of the thermally more stable fraction of organic matter with respect to less stable one. These stability can be related with the soil CO2 emmisions after biochar application. The objective of this presentation is to show the application of thermal analysis to study the stability of soil organic matter in soils treated with different biochars.

  14. [Diagnosis and integrative evaluation on soil fertility of three Chinese medicinal materials in GAP plots].

    PubMed

    Pan, Chaomei; Huang, Haibo; Zhan, Ruoting; Xu, Honghua; Liao, Guanrong

    2002-03-01

    The fertility of soil was diagnosed and integratively evaluated by modified Nemoro Index with eight indexes, i.e. pH, organic matter, total N, P, K and available N, P, K on three national Chinese medicinal materials GAP (Good Agricultural Practice) experimental plots of Pogostemon cablin, Citrus medica and Morinda officinalis in Guangdong. The results showed that the pH, organic matter and other major nutrient contents were low and imbalance. There are lots of nutritive disturbance factors. The level of soil integrative fertility in any of the plots was poor. PMID:12583155

  15. Overview of recent magnetic studies of high T{sub c} cuprate parent compounds and related materials

    SciTech Connect

    Johnston, D.C.; Ami, T.; Borsa, F.

    1995-12-01

    Recent studies of the magnetic properties of several high superconducting transition temperature (T{sub c}) cuprate parent compounds and related materials will be reviewed. The observations of a Heisenberg to XY-like crossover upon cooling below {approximately}300K towards the Neel temperature T{sub N} = 257 K and a subsequent magnetic field-induced XY-like to Ising-like crossover near TN in single crystals of the K{sub 2}NiF{sub 4} type spin 1/2 model compound Sr{sub 2}CuO{sub 2}Cl{sub 2} will be described.

  16. Effect of different mulch materials on the soil dehydrogenase activity (DHA) in an organic pepper crop

    NASA Astrophysics Data System (ADS)

    Moreno, Marta M.; Peco, Jesús; Campos, Juan; Villena, Jaime; González, Sara; Moreno, Carmen

    2016-04-01

    The use biodegradable materials (biopolymers of different composition and papers) as an alternative to conventional mulches has increased considerably during the last years mainly for environmental reason. In order to assess the effect of these materials on the soil microbial activity during the season of a pepper crop organically grown in Central Spain, the soil dehydrogenase activity (DHA) was measured in laboratory. The mulch materials tested were: 1) black polyethylene (PE, 15 μm); black biopolymers (15 μm): 2) Mater-Bi® (corn starch based), 3) Sphere 4® (potato starch based), 4) Sphere 6® (potato starch based), 5) Bioflex® (polylactic acid based), 6) Ecovio® (polylactic acid based), 7) Mimgreen® (black paper, 85 g/m2). A randomized complete block design with four replications was adopted. The crop was drip irrigated following the water demand of each treatment. Soil samples (5-10 cm depth) under the different mulches were taken at different dates (at the beginning of the crop cycle and at different dates throughout the crop season). Additionally, samples of bare soil in a manual weeding and in an untreated control were taken. The results obtained show the negative effect of black PE on the DHA activity, mainly as result of the higher temperature reached under the mulch and the reduction in the gas interchange between the soil and the atmosphere. The values corresponding to the biodegradable materials were variable, although highlighting the low DHA activity observed under Bioflex®. In general, the uncovered treatments showed higher values than those reached under mulches, especially in the untreated control. Keywords: mulch, biodegradable, biopolymer, paper, dehydrogenase activity (DHA). Acknowledgements: the research was funded by Project RTA2011-00104-C04-03 from the INIA (Spanish Ministry of Economy and Competitiveness).

  17. Effect of soil properties and a synthetic municipal landfill leachate on the retention of Cd, Ni, Pb, and Zn in soil and sediment materials

    SciTech Connect

    LaBauve, J.M.; Kotuby-Amacher, J.; Gambrell, R.P.

    1988-03-01

    Batch equilibrium metal immobilization studies were conducted using seven soils and sediment materials spiked with varying concentrations of Cd, Ni, Pb, and Zn. The objective was to examine the potential mobility of metals in subsoils of metals-contaminated sites. Soil pH influenced metal immobilization more than other properties. The inclusion of other property values improved correlation of retention and concentration. Among the metals, Pb was most strongly retained, while Ni was the most mobile. The presence of a synthetic municipal landfill leachate enhanced the dissolved levels of two metals studied (Cd, Ni) in all soil materials.

  18. The Soil Series in Soil Classifications of the United States

    NASA Astrophysics Data System (ADS)

    Indorante, Samuel; Beaudette, Dylan; Brevik, Eric C.

    2014-05-01

    Organized national soil survey began in the United States in 1899, with soil types as the units being mapped. The soil series concept was introduced into the U.S. soil survey in 1903 as a way to relate soils being mapped in one area to the soils of other areas. The original concept of a soil series was all soil types formed in the same parent materials that were of the same geologic age. However, within about 15 years soil series became the primary units being mapped in U.S. soil survey. Soil types became subdivisions of soil series, with the subdivisions based on changes in texture. As the soil series became the primary mapping unit the concept of what a soil series was also changed. Instead of being based on parent materials and geologic age, the soil series of the 1920s was based on the morphology and composition of the soil profile. Another major change in the concept of soil series occurred when U.S. Soil Taxonomy was released in 1975. Under Soil Taxonomy, the soil series subdivisions were based on the uses the soils might be put to, particularly their agricultural uses (Simonson, 1997). While the concept of the soil series has changed over the years, the term soil series has been the longest-lived term in U.S. soil classification. It has appeared in every official classification system used by the U.S. soil survey (Brevik and Hartemink, 2013). The first classification system was put together by Milton Whitney in 1909 and had soil series at its second lowest level, with soil type at the lowest level. The second classification system used by the U.S. soil survey was developed by C.F. Marbut, H.H. Bennett, J.E. Lapham, and M.H. Lapham in 1913. It had soil series at the second highest level, with soil classes and soil types at more detailed levels. This was followed by another system in 1938 developed by M. Baldwin, C.E. Kellogg, and J. Thorp. In this system soil series were again at the second lowest level with soil types at the lowest level. The soil type

  19. Evaluation of Varying Biochars as Carrier Materials for Bacterial Soil Inoculants

    NASA Astrophysics Data System (ADS)

    Hale, Lauren; Crowley, David

    2014-05-01

    The incorporation of biochar into agricultural soils for carbon sequestration and improved soil fertility creates an opportunity to simultaneously deliver plant-growth promoting rhizobacteria (PGPR). Many characteristics of biochar materials indicate that these particles could be conducive as inoculum carriers. This could provide a value-added component for biochar marketing and has an advantage over traditional carrier materials, which can be unsustainable or expensive to produce. Here, we assessed the suitability of 10 biochar types, made from 5 feedstocks at 2 pyrolysis temperatures (300°C and 600°C), to serve as carriers for 2 model PGPR strains, Enterobacter cloacae UW5 and Pseudomonas putida UW4. All biochars were characterized based on BET specific surface area, C-N content, pH, EC, and their abilities to adsorb bacterial cells from a liquid inoculum. Further studies incorporated qPCR to quantify the survival of inoculants after introduction into soils via biochar carriers. The biochars that performed well were further assayed for their influence on PGPR traits, 1-aminocyclopropane-1-carboxylate (ACC) deaminase and auxin production. Peat and vermiculite served as traditional carrier materials to which we compared the biochars. Our findings indicated that biochars varied in their interactions with our model PGPR strains. Based on our analysis several biochar types were able to serve as carriers which were as good, if not better than, the traditional carrier materials. Future work should seek to assess shelf life and varying inoculation methods for the biochar-inoculant complexes.

  20. Investigation of fracture mechanical behavior of nodular cast iron and welded joints with parent-material-like weld metal

    SciTech Connect

    Baer, W.; Pusch, G.

    1995-12-31

    The focus of the investigations was the determination of fracture mechanical characteristics and crack resistance curves of the J-Integral and CTOD concept by application of the partial unloading compliance technique and D.C. potential drop technique (four point bend) under static load. The results show a close correlation between crack initiation values as well as crack resistance curves and graphite morphology parameters determined by means of quantitative microstructural analysis where the influence of the matrix (distance of graphite particles) dominates the crack resistance and fracture performance of ferritic nodular cast iron under consideration of the notch effect of graphite particles. SEM in-situ tensile tests showed that due to a beneficial shielding effect of the strength overmatching parent-material-like weld metal (mis-match ratio M = 1.21), cracks positioned directly in the plane of the fusion line did not deviate into the weld metal in spite of its lower toughness compared to that of the parent material. They also showed an unsymmetrical formation of damage in front of the crack tip.

  1. Stress-dilatancy based modelling of granular materials and extensions to soils with crushable grains

    NASA Astrophysics Data System (ADS)

    Desimone, Antonio; Tamagnini, Claudio

    2005-01-01

    Stress-dilatancy relations have played a crucial role in the understanding of the mechanical behaviour of soils and in the development of realistic constitutive models for their response. Recent investigations on the mechanical behaviour of materials with crushable grains have called into question the validity of classical relations such as those used in critical state soil mechanics.In this paper, a method to construct thermodynamically consistent (isotropic, three-invariant) elasto-plastic models based on a given stress-dilatancy relation is discussed. Extensions to cover the case of granular materials with crushable grains are also presented, based on the interpretation of some classical model parameters (e.g. the stress ratio at critical state) as internal variables that evolve according to suitable hardening laws. Copyright

  2. Analysis of glyphosate and aminomethylphosphonic acid in water, plant materials and soil.

    PubMed

    Koskinen, William C; Marek, LeEtta J; Hall, Kathleen E

    2016-03-01

    There is a need for simple, fast, efficient and sensitive methods of analysis for glyphosate and its degradate aminomethylphosphonic acid (AMPA) in diverse matrices such as water, plant materials and soil to facilitate environmental research needed to address the continuing concerns related to increasing glyphosate use. A variety of water-based solutions have been used to extract the chemicals from different matrices. Many methods require extensive sample preparation, including derivatization and clean-up, prior to analysis by a variety of detection techniques. This review summarizes methods used during the past 15 years for analysis of glyphosate and AMPA in water, plant materials and soil. The simplest methods use aqueous extraction of glyphosate and AMPA from plant materials and soil, no derivatization, solid-phase extraction (SPE) columns for clean-up, guard columns for separation and confirmation of the analytes by mass spectrometry and quantitation using isotope-labeled internal standards. They have levels of detection (LODs) below the regulatory limits in North America. These methods are discussed in more detail in the review. © 2015 Society of Chemical Industry. PMID:26454260

  3. Electrokinetic removal of charged contaminant species from soil and other media using moderately conductive adsorptive materials

    DOEpatents

    Lindgren, Eric R.; Mattson, Earl D.

    2001-01-01

    Method for collecting and concentrating charged species, specifically, contaminant species in a medium, preferably soil. The method utilizes electrokinesis to drive contaminant species into and through a bed adjacent to a drive electrode. The bed comprises a moderately electrically conductive adsorbent material which is porous and is infused with water or other solvent capable of conducting electrical current. The bed material, preferably activated carbon, is easily removed and disposed of. Preferably, where activated carbon is used, after contaminant species are collected and concentrated, the mixture of activated carbon and contaminant species is removed and burned to form a stable and easily disposable waste product.

  4. Possible sources of H2 to H2O enrichment at evaporation of parent chondritic material

    NASA Technical Reports Server (NTRS)

    Makalkin, A. B.; Dorofeyeva, V. A.; Vityazev, A. V.

    1993-01-01

    One of the results obtained from thermodynamic simulation of recondensation of the source chondritic material is that at 1500-1800 K it's possible to form iron-rich olivine by reaction between enstatite, metallic iron and water vapor in the case of (H2O)/(H2) approximately equal to 0.1. This could be reached if the gas depletion in hydrogen is 200-300 times relative to solar abundance. To get this range of depletion one needs some source material more rich in hydrogen than the carbonaceous CI material which is the richest in volatiles among chondrites. In the case of recondensation at impact heating and evaporation of colliding planetesimals composed of CI material, we obtain insufficiently high value of (H2)/(H2O) ratio. In the present paper we consider some possible source materials and physical conditions necessary to reach gas composition with (H2)/(H2O) approximately 10 at high temperature.

  5. Soiled-based uranium disequilibrium and mixed uranium-thorium series radionuclide reference materials

    SciTech Connect

    Donivan, S.; Chessmore, R.

    1988-12-01

    The US Department of Energy (DOE) Office of Remedial Action and Waste Technology has assigned the Technical Measurements Center (TMC), located at the DOE Grand Junction Colorado, Projects Office and operated by UNC Geotech (UNC), the task of supporting ongoing remedial action programs by providing both technical guidance and assistance in making the various measurements required in all phases of remedial action work. Pursuant to this task, the Technical Measurements Center prepared two sets of radionuclide reference materials for use by remedial action contractors and cognizant federal and state agencies. A total of six reference materials, two sets comprising three reference materials each, were prepared with varying concentrations of radionuclides using mill tailings materials, ores, and a river-bottom soil diluent. One set (disequilibrium set) contains varying amounts of uranium with nominal amounts of radium-226. The other set (mixed-nuclide set) contains varying amounts of uranium-238 and thorium-232 decay series nuclides. 14 refs., 10 tabs.

  6. Materials testing for in situ stabilization treatability study of INEEL mixed wastes soils

    SciTech Connect

    Heiser, J.; Fuhrmann, M.

    1997-09-01

    This report describes the contaminant-specific materials testing phase of the In Situ Stabilization Comprehensive Environment Response, Compensation, and Liability Act (CERCLA) Treatability Study (TS). The purpose of materials testing is to measure the effectiveness of grouting agents to stabilize Idaho National Engineering and Environmental Laboratory (INEEL) Acid Pit soils and select a grout material for use in the Cold Test Demonstration and Acid Pit Stabilization Treatability Study within the Subsurface Disposal Area (SDA) at the Radioactive Waste Management Complex (RWMC). Test results will assist the selecting a grout material for the follow-on demonstrations described in Test Plan for the Cold Test Demonstration and Acid Pit Stabilization Phases of the In Situ Stabilization Treatability Study at the Radioactive Waste Management Complex.

  7. Correlations between soil magnetic susceptibility and the content of particular elements as a reflection of pollution level, land use and parent rocks

    NASA Astrophysics Data System (ADS)

    Rachwał, Marzena; Magiera, Tadeusz; Bens, Oliver; Kardel, Kati

    2015-04-01

    Magnetic susceptibility is a worldwide used measure of (ferri)magnetic minerals occurring in soils, sediments and dusts. In soils, these minerals are of various origin: air-derived particulate pollutions, parent rocks or pedogenesis. Human activity causes different changes in the content of magnetic minerals as well as their spatial and vertical distribution in soil profiles. Magnetic minerals are characterized by an affinity for other elements occurring in the soil, so positive correlations between magnetic susceptibility and particular elements like macrocomponents or heavy metals often occurs. The archival soil samples collected from different soil horizons in the territory of the Free State of Saxony (Germany) were subjected to the magnetic susceptibility measurements using Bartington MS2B. Additionally, samples were chemically analyzed by the S Helmholtz Centre Potsdam, GFZ German Research Centre for Geosciences in Potsdam. Values of magnetic susceptibility varied from 9.3 to 1382 ×10-8 m3/kg in organic soil horizon and from 0.1 to 2105 ×10-8 m3/kg in dipper layers. Calculated correlation coefficients between magnetic susceptibility and some elements indicate significant relationships characteristic for different factors influenced soil properties (pollution level, land use and parent rocks). The northern part of Saxony is divided by the Elbe into two parts: east part with loose sedimentary rocks and the west one with more solid loess bedrock enriched by spectrum of elements from the Ore Mountains. Correlations between magnetic susceptibility and Ca, Fe, Mn, and Zn were stated in the eastern, while soil magnetic susceptibility of the western part revealed a correlation with Fe, P, Cd, Cu, Pb, Zn, Mo, U, V, and W. Taking into account influences of industry and urbanization, soil magnetic susceptibility is enhanced in the areas with higher population density comparing with rural sites. In the area of Hoyerswerda and Weisswasser with low magnetic natural

  8. Parenting: The Underdeveloped Skill.

    ERIC Educational Resources Information Center

    National PTA, Chicago, IL.

    This parent education curriculum contains a variety of materials designed to help local Parent Teacher Associations (PTAs) hold meetings for parents on child rearing. The materials help organizers plan meetings on topics such as dating, drugs, and careers. The unit contains a leader's guide, which contains a description of how to plan meetings,…

  9. Improving quality of textile wastewater with organic materials as multi soil layering

    NASA Astrophysics Data System (ADS)

    Supriyadi; Widijanto, H.; Pranoto; Dewi, AK

    2016-02-01

    On agricultural land, fresh water is needed especially for irrigation. Alternative ways to fulfill needs of fresh water is by utilizing wastewater from industry. Wastewater that produced in the industry in Surakarta is over flowing especially textile wastewater. Wastewater that produced from industry has many pollutants that affected decreasing fresh water quality for irrigation. Multi Soil Layering (MSL) is one of method that utilize the soil ability as main media by increasing its function of soil structure to purify wastewater, so it does not contaminate the environment and reusable. This research was purposed to know affectivity of organic materials (such as rice straw, baggase, sawdust, coconut fibre, and corncob) and dosage (5%, 10% and 25%) in MSL, also get alternative purification ways with easy and cheaper price as natural adsorbent. This study using field and laboratory experiment. The result shows that MSL can be an alternative method of purification of wastewater. The appropriate composition of organic materials that can be used as adsorbent is MSL with wood sawdust 10% dosage because it can increase pH, decrease the number of Cr, ammonia, and phosphate but less effective to decrease BOD and COD.

  10. Dependence of the tensile properties of 316 L parent material and welds on implanted hydrogen and/or helium

    NASA Astrophysics Data System (ADS)

    Schroeder, Herbert; Liu, Wanpei

    1992-09-01

    The interest in the low temperature tensile properties of candidate alloys for first wall and blanket structures of future fusion devices is due to the possible low pressure water cooling and the associated low operation temperature in recent design studies. Therefore, the tensile properties of hydrogen and/or helium implanted 316 L stainless steel and its weldments as a function of gas concentrations and temperature were investigated. The main effects of the implantation are hardening, resulting in large increases of the yield strength proportional to the implanted gas concentration, and a gradual decrease of the corresponding rupture strain. The ultimate tensile stresses are less affected. The effect of helium implantation seems to be more pronounced than that of hydrogen implantation. At 673 K most of the implantation induced changes are recovered. Generally parent material and welds still show large ductility (≥20%) under all conditions investigated.

  11. Some adverse effects of soil amendment with organic Materials-The case of soils polluted by copper industry phytostabilized with red fescue.

    PubMed

    Cuske, Mateusz; Karczewska, Anna; Gałka, Bernard; Dradrach, Agnieszka

    2016-08-01

    The study was aimed to examine the effects of soil amendment with organic waste materials on the growth of red fescue and the uptake of Cu and Zn by this grass, in view of its potential usage for phytostabilization of Cu-polluted soils. Five soils, containing 301-5180 mg/kg Cu, were collected from the surroundings of copper smelter Legnica, and amended with lignite (LG) and limed sewage sludge (SS). Plant growth and the concentrations of Cu and Zn in the shoots and roots of grass were measured in a pot experiment and related to the results of Pytotoxkit and Microtox® tests performed on soil solution. The effects of soil amendment with LG and SS differed greatly, and depended on soil properties. In some cases, the application of alkaline SS resulted in dramatic increase of Cu phytotoxicity and its enhanced uptake by plants, while application of LG to slightly acidic soil caused increased accumulation of Zn in plants, particularly in their roots. The study confirmed good suitability of red fescue for phytostabilization of Cu-contaminated soils except for those extremely polluted. Organic amendments to be used for metal immobilization should be thoroughly examined prior to application. PMID:26853183

  12. Diffusion of Iodine and Rhenium in Category 3 Waste Encasement Concrete and Soil Fill Material

    SciTech Connect

    Wellman, Dawn M.; Mattigod, Shas V.; Whyatt, Greg A.; Powers, Laura; Parker, Kent E.; Wood, Marcus I.

    2006-12-15

    Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e. sorption or precipitation). This understanding will enable accurate prediction of radionuclide fate when the waste forms come in contact with groundwater. A set of diffusion experiments using carbonated and non-carbonated concrete-soil half cells was conducted under unsaturated conditions (4% and 7% by wt moisture content). Spiked concrete half-cell specimens were prepared with and without colloidal metallic iron addition and were carbonated using supercritical carbon dioxide. Spikes of I and Re were added to achieve measurable diffusion profile in the soil part of the half-cell. In addition, properties of concrete materials likely to influence radionuclide migration such as carbonation were evaluated in an effort to correlate these properties with the release of iodine and rhenium.

  13. Development of laboratory reference material: Soil 1. Baseline and highly elevated concentrations of metals and polycyclic aromatic hydrocarbons.

    PubMed

    Kupiec, K; Konieczka, P; Namieśnik, J

    2011-01-01

    Reference materials play a key part in systems of inspection and quality control of results of analytical measurements. The main limitation in using certified reference materials (CRM) is their high price, which results from the long and costly process of producing the reference material. An alternative to costly CRM materials is the employment of laboratory reference materials, particularly for interlaboratory control of measurement results and procedures. Under the auspices of the Chair of Analytical Chemistry at the Chemical Department of Gdansk University of Technology, research on the development of new reference materials is being conducted. At present, the research is aimed at producing a new laboratory reference material (LRM): 'Soil 1. Baseline and Highly Elevated Concentrations of Metals and Polycyclic Aromatic Hydrocarbons' - LRM soil 1. This paper presents the production stages of the developed laboratory reference material: acquisition of raw material from soil samples taken from the environment of the Tri-city (in Polish, Trójmiasto Gdansk, Sopot, Gdynia) bypass road, homogenization and subsequent dosage into appropriate containers, tests of homogeneity of sampled material within one container and between containers, based on the results of the determination of selected parameters (total carbon, content of optional metals - Hg, Fe, Cu Zn, Mn, Mg, water content, content of PAH-group analytes). The obtained results of homogeneity tests of the proposed future laboratory reference material have confirmed the homogeneity of soil samples within a container and between containers. Currently, interlaboratory tests are being carried out to determine the reference value. PMID:21473281

  14. THE DEVELOPMENT OF SYNTHETIC SOIL MATERIALS FOR THE SUCCESSFUL RECLAMATION OF ABANDONED MINED LAND SITES

    SciTech Connect

    Song Jin

    2006-03-01

    Abandoned mine sites associated with coal and metal mining across the western United States have been left as unproductive wastelands. The availability of soil materials or other materials to support the restoration of the vegetative cover and enhance the recovery of such areas is limited. The restoration of these areas often requires the use of available amendments such as organic waste products or to help stabilize the soil. Many of the organic waste products, including sewage sludge, clarifier sludge, fly ash sludge, and other by-products from the agricultural industries such as compost can be employed for beneficial uses. This study looked at the feasibility of applying organic waste products to a mine soil in Montana to increase soil fertility and enhance plant productivity. Waste rock samples were tested for acid forming potential via acid base accounting. Samples cores were constructed and leached with simulated rainwater to determine amendment affect on metal leaching. A greenhouse study was completed to determine the most suitable amendment(s) for the field mine land site. Results from the acid base accounting indicate that acid formed from the waste rock would be neutralized with the alkalinity in the system. Results also show that metals in solution are easily held by organics from the amendments and not allowed to leach in to the surrounding water system. Data from the greenhouse study indicated that the amendment of sewage sludge was most promising. Application of 2% sewage sludge along with 1% sewage sludge plus 1% clarifier sludge, 2% compost, and no treatment were used for mine land application. Initial results were encouraging and it appears that sewage sludge may be a good reclamation option for mine lands.

  15. Development of construction materials like concrete from lunar soils without water

    NASA Technical Reports Server (NTRS)

    Desai, Chandra S.; Saadatmanesh, H.; Frantziskonis, G.

    1989-01-01

    The development of construction materials such as concrete from lunar soils without the use of water requires a different methodology than that used for conventional terrestrial concrete. A unique approach is attempted that utilizes factors such as initial vacuum and then cyclic loading to enhance the mechanical properties of dry materials similar to those available on the moon. The application of such factors is expected to allow reorientation, and coming together, of particles of the materials toward the maximum theoretical density. If such a density can provide deformation and strength properties for even a limited type of construction, the approach can have significant application potential, although other factors such as heat and chemicals may be needed for specific construction objectives.

  16. Elaidate-Intercalated hydrotalcite as a sorbent material for metalaxyl immobilitzation in soil

    NASA Astrophysics Data System (ADS)

    López-Cabeza, Rocío; Cornejo, Juan; Hermosín, María C.; Cox, Lucía; Celis, Rafael

    2015-04-01

    Layered double hydroxides (LDHs), also known as hydrotalcite-like compounds (HTs), comprise a special group of layered materials. Their structure consists of positively charged layers of mixed divalent (MII) and trivalent (MIII) metal hydroxide [MII1-xMIIIx(OH)2]x+, with the positive charge being balanced by inorganic hydrated anions (An-x/n·mH2O), which occupy the interlayer space. LDHs have anion exchange properties and, therefore, are good sorbents for anionic pollutants. In addition, the anionic exchange properties of LDHs allow the intercalation of organic anions in the interlayer space to render the LDH surface hydrophobic. This increases its affinity to hydrophobic organic compounds. Pesticides with chiral centers are an emerging class of organic pollutants and it has become clear that addressing the different efficacy, toxicity, and environmental behavior of chiral pesticide enantiomers is necessary to avoid the incorrect assumption that enantiomers have identical environmental behavior. Appropriate soil remediation strategies accounting for the enantioselective behavior of chiral pesticide enantiomers are also needed. In this work, we evaluated the performance of elaidate-modified hydrotalcite (HT-ELA) as a sorbent to remove the chiral fungicide metalaxyl from aqueous solution and as an amendment for metalaxyl immobilization in soil. Analysis of metalaxyl by chiral high-performance liquid chromatography allowed us to monitor the sorption and mobility of the two enantiomers of metalaxyl, S-(+)-metalaxyl and R-(-)-metalaxyl, independently. Batch sorption experiments showed that HT-ELA [Mg3Al(OH)8ELA] displayed an excellent performance as an sorbent of the two enantiomers of metalaxyl from aqueous solution and that its addition to a sandy loam agricultural soil at a rate of 1% greatly enhanced the sorption of metalaxyl enantiomers by the soil. Column leaching experiments demonstrated that amending the soil top layer (0-2.5 cm) with HT-ELA at a rate of 1

  17. Reflectance and Mossbauer spectroscopy of ferrihydrite-montmorillonite assemblages as Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, J. L.; Pieters, C. M.; Burns, R. G.; Chang, S. (Principal Investigator)

    1993-01-01

    Spectroscopic analyses show that Fe(3+)-doped smectites prepared in the laboratory exhibit important similarities to the soils on Mars. Ferrihydrite has been identified as the interlayer ferric component in Fe(3+)-doped smectites by a low quadrupole splitting and magnetic field strength of approximately 48 tesla in Mossbauer spectra measured at 4.2 K, as well as a crystal field transition at 0.92 micrometer. Ferrihydrite in these smectites explains features in the visible-near infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. Clay silicates have met resistance in the past as Mars soil analogs because terrestrial clay silicates exhibit prominent hydrous spectral features at 1.4, 1.9, and 2.2 micrometers; and these are observed weakly, if at all, in reflectance spectra of Mars. However, several mechanisms can weaken or compress these features, including desiccation under low-humidity conditions. The hydration properties of the interlayer cations also effect band strengths, such that a ferrihydrite-bearing smectite in the Martian environment would exhibit a 1.9 micrometers H2O absorption that is even weaker than the 2.2 micrometers structural OH absorption. Mixing experiments demonstrate that infrared spectral features of clays can be significantly suppressed and that the reflectance can be significantly darkened by mixing with only a few percent of a strongly absorbing opaque material. Therefore, the absolute reflectance of a soil on Mars may be disproportionately sensitive to a minor component. For this reason, the shape and position of spectral features and the chemical composition of potential analogs are of utmost importance in assessing the composition of the soil on Mars. Given the remarkable similarity between visible-infrared reflectance spectra of soils in bright regions on Mars and Fe(3+)-doped montmorillonites, coupled with recent observations of smectites in SNC

  18. Orientation Booklet for Parents Enrolled in Parent Education Cooperative Groups. Columbia Basin College Parent Education Program.

    ERIC Educational Resources Information Center

    Debban, Barbara, Comp.; And Others

    This booklet provides parents with information to help them get the most from their enrollment in parent education cooperative groups. Orientation information is presented for both the Parent Walkabout/Parent Toddler Programs and the Parent Cooperative Preschool Programs at Columbia Basin College (CBC), Washington. Informative material on the…

  19. Introduction to Foster Parenting - II: Working with Agency, Natural Parent Separation, Family Relationships. Foster Parent Curriculum.

    ERIC Educational Resources Information Center

    Marr, Pam

    This instructor's guide for a foster parent curriculum consists of specific introductory curriculum material for the study of foster parent and state agency relations, the foster child's feelings and reactions to separation from his natural parents, and foster parent and natural parent relations with the foster child. Section 1 provides an outline…

  20. Biogeochemistry of hydrothermally and adjacent non-altered soils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    As a field/lab project, students in the Soil Biogeochemistry class of the University of Nevada, Reno described and characterized seven pedons, developed in hydrothermally and adjacent non-hydrothermally altered andesitic parent material near Reno, NV. Hydrothermally altered soils had considerably lo...

  1. Soils, time, and primate paleoenvironments

    USGS Publications Warehouse

    Bown, T.M.; Kraus, M.J.

    1993-01-01

    Soils are the skin of the earth. From both poles to the equator, wherever rocks or sediment are exposed at the surface, soils are forming through the physical and chemical action of climate and living organisms. The physical attributes (color, texture, thickness) and chemical makeup of soils vary considerably, depending on the composition of the parent material and other variables: temperature, rainfall and soil moisture, vegetation, soil fauna, and the length of time that soil-forming processes have been at work. United States soil scientists1 have classified modern soils into ten major groups and numerous subgroups, each reflecting the composition and architecture of the soils and, to some extent, the processes that led to their formation. The physical and chemical processes of soil formation have been active throughout geologic time; the organic processes have been active at least since the Ordovician.2 Consequently, nearly all sedimentary rocks that were deposited in nonmarine settings and exposed to the elements contain a record of ancient, buried soils or paleosols. A sequence of these rocks, such as most ancient fluvial (stream) deposits, provides a record of soil paleoenvironments through time. Paleosols are also repositories of the fossils of organisms (body fossils) and the traces of those organisms burrowing, food-seeking, and dwelling activities (ichnofossils). Indeed, most fossil primates are found in paleosols. Careful study of ancient soils gives new, valuable insights into the correct temporal reconstruction of the primate fossil record and the nature of primate paleoenvironments. ?? 1993 Wiley-Liss, Inc.

  2. Effects of oyster shell on soil chemical and biological properties and cabbage productivity as a liming materials.

    PubMed

    Lee, Chang Hoon; Lee, Do Kyoung; Ali, Muhammad Aslam; Kim, Pil Joo

    2008-12-01

    Oyster shell, a byproduct of shellfish-farming in Korea and containing a high amount of CaCO(3), has a high potential to be used as a liming material in agriculture. However, the agricultural utilization of oyster shell is limited due to its high concentration NaCl. The oyster-shell meal collected had a low concentration of water soluble NaCl (mean 2.7 g kg(-1)), which might be a result of stacking the material for 6 months in the open field. It has a very similar liming potential with calcium carbonate, with 3.4 and 3.8 Mg ha(-1) for silt loam (SiL, pH 6.2) and sandy loam (SL, pH 5.8) to bring the soil pH to 6.5, respectively. To determine the effect of crushed oyster-shell meal on improving soil chemical and biological properties and crop plant productivity, oyster-shell meal was applied at rates of 0, 4, 8, 12, and 16 Mg ha(-1) before transplanting Chinese cabbage (Brassica campestris L.) in the two soils mentioned above. Soil pH was significantly increased to 6.9 and 7.4 by 16 Mg ha(-1) shell meal application (4 times higher level than the recommendation) in SiL and SL, respectively, at harvesting stage. The effect of liming was found higher in SL compared to SiL soil, probably due to the different buffering capacity of the two soils. The concentration of NaCl and EC value of soils were found slightly increased with shell meal applications, but no salt damage was observed. Oyster-shell meal application increased soil organic matter, available P, and exchangeable cations concentrations. The improved soil pH and nutrient status significantly increased the microbial biomass C and N concentrations and stimulated soil enzyme activities. With the exception of acid phosphomonoesterase (PMEase) activity, which decreased with increasing soil pH in SL but slightly increased in SiL, the activities of urease and alkali PMEase increased markedly with increasing soil pH by shell meal application. The improved soil chemical and biological properties resulted in increased crop

  3. Parents' Regulation and Self-Regulation and Performance in Children with Intellectual Disability in Problem-Solving Using Physical Materials or Computers

    ERIC Educational Resources Information Center

    Nader-Grosbois, Nathalie; Lefevre, Nathalie

    2012-01-01

    This study compared mothers and fathers' regulation with respect to 29 children with intellectual disability (ID) and 30 typically developing (TD) children, matched on their mental age (MA), as they solved eight tasks using physical materials and computers. Seven parents' regulatory strategies were coded as they supported their child's…

  4. Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, Janice L.; Pieters, Carle M.

    1995-01-01

    Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrate and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O and adsorbed H2O. The spectal character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micrometers, 2.2 micrometers, 2.7 micrometers, 3 micrometers, and 6 micrometers are reported here in spetra measured under Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micrometer band depth is 8-17%; this band is much stonger under moist conditions. Under Marslike atmospheric conditions the 1.9-micrometer feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micrometer feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3- micrometer band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micromter band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural

  5. Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, Janice L.; Pieters, Carle M.

    1995-01-01

    Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrite and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O, and adsorbed H2O. The spectral character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micron, 2.2 micron, 2.7 micron, 3 micron, and 6 microns are reported here in spectra measured under a Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micron band depth is 8-17%; this band is much stronger under moist conditions. Under Marslike atmospheric conditions the 1.9-micron feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micron feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3-micron band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micron band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural OH features observed in these materials

  6. Evaluation of bottom ash and composted manure blends as a soil amendment material.

    PubMed

    Mukhtar, S; Kenimer, A L; Sadaka, S S; Mathis, J G

    2003-09-01

    The long-term goal of this project was to find alternative uses for bottom ash (BA) and composted dairy manure (CM), by-products of coal combustion and livestock production, respectively. The study discussed in this paper focused on potential water quality impacts associated with using blended BA and CM as a soil amendment. The constituents of BA and CM include heavy metals and other chemicals that, while essential nutrients for plant growth, also pose a potential threat to water quality. Four blends (BA:CM, v/v) namely, B1 (100%:0%), B2 (70%:30%), B3 (50%:50%) and B4 (0%:100%), were subjected to flow-through water table management and two blends, B2 (70%:30%) and B3 (50%:50%), were subjected to constant head water table management using de-ionized water. Leachate and standing water from saturated and flooded blends of BA and CM were examined for total solids (TS), volatile solids (VS), COD, pH, total Kjeldahl nitrogen (TKN), NO(3)-N, total P, total K as well as selected metals over a 5 and 7 week period for flow-through and constant head watertables, respectively. The results showed that higher CM content resulted in higher TS, VS, TKN, P and K concentrations in the leachate and standing water. Concentrations of these constituents were higher in leachate than in the standing water. Even though, marked reductions of most chemicals in the leachate and standing water were realized within one to three weeks, initially high concentrations of chemicals in leachate and standing water from these particular blends made them unsuitable as soil amendment material. Based upon these results, it was concluded that additional column studies of BA and CM blends with reduced CM content (5%, 10% and 20%) should be performed to further assess the feasibility of BA and CM blends as an environmentally safe soil amendment material. PMID:12798111

  7. Biotic carbon feedbacks in a materially closed soil-vegetation-atmosphere system

    NASA Astrophysics Data System (ADS)

    Milcu, Alexandru; Lukac, Martin; Subke, Jens-Arne; Manning, Pete; Heinemeyer, Andreas; Wildman, Dennis; Anderson, Robert; Ineson, Phil

    2012-04-01

    The magnitude and direction of the coupled feedbacks between the biotic and abiotic components of the terrestrial carbon cycle is a major source of uncertainty in coupled climate-carbon-cycle models. Materially closed, energetically open biological systems continuously and simultaneously allow the two-way feedback loop between the biotic and abiotic components to take place, but so far have not been used to their full potential in ecological research, owing to the challenge of achieving sustainable model systems. We show that using materially closed soil-vegetation-atmosphere systems with pro rata carbon amounts for the main terrestrial carbon pools enables the establishment of conditions that balance plant carbon assimilation, and autotrophic and heterotrophic respiration fluxes over periods suitable to investigate short-term biotic carbon feedbacks. Using this approach, we tested an alternative way of assessing the impact of increased CO2 and temperature on biotic carbon feedbacks. The results show that without nutrient and water limitations, the short-term biotic responses could potentially buffer a temperature increase of 2.3°C without significant positive feedbacks to atmospheric CO2. We argue that such closed-system research represents an important test-bed platform for model validation and parameterization of plant and soil biotic responses to environmental changes.

  8. Evaluation of lunar rocks and soils for resource utilization: Detailed image analysis of raw materials and beneficiated products

    NASA Technical Reports Server (NTRS)

    Taylor, Lawrence A.; Chambers, John G.; Patchen, Allan; Jerde, Eric A.; Mckay, David S.; Graf, John; Oder, Robin R.

    1993-01-01

    The rocks and soils of the Moon will be the raw materials for fuels and construction needs at a lunar base. This includes sources of materials for the generation of hydrogen, oxygen, metals, and other potential construction materials. For most of the bulk material needs, the regolith, and its less than 1 cm fraction, the soil, will suffice. But for specific mineral resources, it may be necessary to concentrate minerals from rocks or soils, and it is not always obvious which is the more appropriate feedstock. Besides an appreciation of site geology, the mineralogy and petrography of local rocks and soils is important for consideration of the resources which can provide feedstocks of ilmenite, glass, agglutinates, anorthite, etc. In such studies, it is very time-consuming and practically impossible to correlate particle counts (the traditional method of characterizing lunar soil petrography) with accurate modal analyses and with mineral associations in multi-mineralic grains. But x ray digital imaging, using x rays characteristic of each element, makes all this possible and much more (e.g., size and shape analysis). An application of beneficiation image analysis, in use in our lab (Oxford Instr. EDS and Cameca SX-50 EMP), was demonstrated to study mineral liberation from lunar rocks and soils. Results of x ray image analysis are presented.

  9. Long Term Effects of Fluidized Bed Material Applied at Disposal Levels on Soil Metals and Nutrient Concentrations as Related to Soil Depth

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study was conducted to assess the movement of macro and micro elements in an old apple [Malus domestica Borkh.] orchard that received a one time application of 36 kg m-2 of fluidized bed combustion material (FBC) 23 years earlier. Soil samples were taken in an area where 15 trees were planted ...

  10. Effect of Ground Rubber vs. ZnSO4 on Spinach Accumulation of Cd from Cd-Mineralized California Soil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Certain soils derived from marine shale in Salinas Valley, CA, USA, contain significant levels of natural Cd but normal levels of Zn, all derived from the soil parent materials. Crops grown on these soils contain high levels of Cd, and because of the high Cd:Zn, this Cd is highly bioavailable and a...

  11. Material properties data and volume estimate of silt loam soil at the NRDWL Reserve, McGee Ranch

    SciTech Connect

    Not Available

    1994-02-17

    A closure and postclosure plan for the Hanford Site Nonradioactive Dangerous Waste Landfill (NRDWL) was prepared by Westinghouse Hanford Company (WHC) and submitted for regulatory agency review in 1990. In the closure plan, construction of a final cover over the NRDWL is proposed. The design specifies a topsoil component consisting of layers of compacted and noncompacted fine-textured soil. The objective of compacting a portion of the topsoil layer is to impede infiltration of soil moisture. The McGee Ranch area on the Hanford Site is proposed as the source area for fine-textured soils to support cover construction. A number of data needs are identified in the closure plan for definitive design of the NRDWL final cover. Specifically, the plan identifies a need to characterize potential borrow areas for fine-textured soil, to ensure that (1) material properties vary within acceptable limits for the application, and (2) sufficient quantities of suitable material are available.

  12. Plant material as bioaccumulator of arsenic in soils affected by mining activities

    NASA Astrophysics Data System (ADS)

    Martínez-López, Salvadora; Martínez-Sánchez, Maria Jose; García-Lorenzo, Maria Luz; Pérez-Sirvent, Carmen

    2010-05-01

    Heavy metal contamination is an important environmental problem, since the metals are harmful to humans, animals and tend to bioaccumulate in the food chain. The aim of this study was to determine the total concentration of As, As (III) and As(V) in soil samples, leaves and roots of plant material, growing in a mining area in Spain (Murcia). Ditichia viscosa was used as the plant of reference. The concentrations of bioavailable As in plant samples were calculated by different soil chemical extraction methods; deionized water, 0.5N NaHCO3 (Olsen extraction), oxidizable medium, 0.5 HCl, 0.05M (NH4)2SO4, 0.005M DTPA and Mehra-Jackson extraction. For this study, fourteen samples were collected in the surrounding area of Sierra Minera and Portman Bay (Murcia, SE Spain). Samples were air dried and sieved to < 2mm for general analytical determinations. To determine the As content, soil samples were first ground to a fine powder using an agate ball mill. Fresh vegetable samples were separated into root and aboveground biomass and then lyophilized. Arsenic levels were obtained by using atomic fluorescence spectrometry with an automated continuous flow hydride generation (HG-AFS) spectrometer. Samples showed pH average values close to neutrality. Most samples showed a very low organic matter percentage. Electrical conductivity and calcium carbonate content were considerably low in most samples. The mineralogical analysis showed that the main minerals were quartz, muscovite, kaolinite and illite, while the minority minerals were alteration products derived of mining activities (iron oxides and hydroxides, siderite, jarosite and gypsum), calcite and feldspars. Although the plants do not absorb arsenic in the same proportion, the results suggest that a good relationship exists between the total content of As in soil and the total content in plant. The results showed that the arsenic content in roots was positively correlated with the oxidizable-organic matter and sulfides

  13. Environmental materials for remediation of soils contaminated with lead and cadmium using maize (Zea mays L.) growth as a bioindicator.

    PubMed

    Shi, Yu; Huang, Zhanbin; Liu, Xiujie; Imran, Suheryani; Peng, Licheng; Dai, Rongji; Deng, Yulin

    2016-04-01

    Heavy metal pollution is a severe environmental problem. Remediation of contaminated soils can be accomplished using environmental materials that are low cost and environmentally friendly. We evaluated the individual and combination effects of humic acid (HA), super absorbent polymer (SAP), zeolite (ZE), and fly ash composites (FC) on immobilization of lead (Pb) and cadmium (Cd) in contaminated soils. We also investigated long-term practical approaches for remediation of heavy metal pollution in soil. The biochemical and morphological properties of maize (Zea mays L.) were selected as biomarkers to assess the effects of environmental materials on heavy metal immobilization. The results showed that addition of test materials to soil effectively reduced heavy metal accumulation in maize foliage, improving chlorophyll levels, plant growth, and antioxidant enzyme activity. The test materials reduced heavy metal injury to maize throughout the growth period. A synergistic effect from combinations of different materials on immobilization of Pb and Cd was determined based on the reduction of morphological and biochemical injuries to maize. The combination of zeolite and humic acid was especially effective. Treatment with a combination of HA + SAP + ZE + FC was superior for remediation of soils contaminated with high levels of Pb and Cd. PMID:26604199

  14. Assessment of soil organic carbon distribution in Europe scale by spatio-temporal data and geostatistics

    NASA Astrophysics Data System (ADS)

    Aksoy, Ece; Panagos, Panos; Montanarella, Luca

    2013-04-01

    Accuracy in assessing the distribution of soil organic carbon (SOC) is an important issue because SOC is an important soil component that plays key roles in the functions of both natural ecosystems and agricultural systems. The SOC content varies from place to place and it is strongly related with climate variables (temperature and rainfall), terrain features, soil texture, parent material, vegetation, land-use types, and human management (management and degradation) at different spatial scales. Geostatistical techniques allow for the prediction of soil properties using soil information and environmental covariates. In this study, assessment of SOC distribution has been predicted using combination of LUCAS soil samples with local soil data and ten spatio-temporal predictors (slope, aspect, elevation, CTI, CORINE land-cover classification, parent material, texture, WRB soil classification, average temperature and precipitation) with Regression-Kriging method in Europe scale. Significant correlation between the covariates and the organic carbon dependent variable was found.

  15. Schoolwide Programs: Parents' Guide & Capacity-Building Materials = Programas Schoolwide: Una Guia para Padres y Materias de Capacitacion.

    ERIC Educational Resources Information Center

    WestEd, San Francisco, CA.

    The reauthorization of Title I (Improving America's Schools Act--IASA) made the Schoolwide Program (Schoolwide) a major strategy for schools with high poverty rates and stressed the importance of parent involvement. This guide was developed to provide professional development and parent education on Schoolwide implementation in California. The…

  16. A sequential extraction procedure to evaluate the mobilization behavior of rare earth elements in soils and tailings materials.

    PubMed

    Mittermüller, Marc; Saatz, Jessica; Daus, Birgit

    2016-03-01

    A novel sequential extraction method for evaluation of the mobilization behavior of rare earth elements in soils and mine tailings materials is presented. The sequence consists of the following four steps: 0.05 mol L(-1) calcium nitrate (easily soluble and ion exchange fraction), 0.1 mol L(-1) citric acid (fraction mobilized by complexation and carbonate bound), 0.05 mol L(-1) hydroxylamine hydrochloride (pH = 2) (reducible fraction), 1.4 mol L(-1) nitric acid (acid soluble fraction). The procedure was optimized with a certified soil material and a mine tailings material and was applied to eight samples of a soil profile. The different results obtained by using either the developed method or the widespread used BCR-Method for comparison are discussed. There were clear advantages using the newly created sequential extraction procedure in getting more detailed information about the bioavailable fraction and a fraction addressing REE phosphates. PMID:26766351

  17. A framework for assessing ecological risks of petroleum-derived materials in soil

    SciTech Connect

    Suter, G.W. II

    1997-05-01

    Ecological risk assessment estimates the nature and likelihood of effects of human actions on nonhuman organisms, populations, and ecosystems. It is intended to be clearer and more rigorous in its approach to estimation of effects and uncertainties than previously employed methods of ecological assessment. Ecological risk assessment is characterized by a standard paradigm that includes problem formulation, analysis of exposure and effects, risk characterization, and communication with a risk manager. This report provides a framework that applies the paradigm to the specific problem of assessing the ecological risks of petroleum in soil. This type of approach requires that assessments be performed in phases: (1) a scoping assessment to determine whether there is a potential route of exposure for potentially significant ecological receptors; (2) a screening assessment to determine whether exposures could potentially reach toxic levels; and (3) a definitive assessment to estimate the nature, magnitude, and extent of risks. The principal technical issue addressed is the chemically complex nature of petroleum--a complexity that may be dealt with by assessing risks on the basis of properties of the whole material, properties of individual chemicals that are representative of chemical classes, distributions of properties of the constituents of chemical classes, properties of chemicals detected in the soil, and properties of indicator chemicals. The advantages and feasibility of these alternatives are discussed. The report concludes with research recommendations for improving each stage in the assessment process.

  18. Reclamation with Recovery of Radionuclides and Toxic Metals from Contaminated Materials, Soils, and Wastes

    NASA Technical Reports Server (NTRS)

    Francis, A. J.; Dodge, C. J.

    1993-01-01

    A process has been developed at Brookhaven National Laboratory (BNL) for the removal of metals and radionuclides from contaminated materials, soils, and waste sites. In this process, citric acid, a naturally occurring organic complexing agent, is used to extract metals such as Ba, Cd, Cr, Ni, Zn, and radionuclides Co, Sr, Th, and U from solid wastes by formation of water soluble, metal-citrate complexes. Citric acid forms different types of complexes with the transition metals and actinides, and may involve formation of a bidentate, tridentate, binuclear, or polynuclear complex species. The extract containing radionuclide/metal complex is then subjected to microbiological degradation followed by photochemical degradation under aerobic conditions. Several metal citrate complexes are biodegraded, and the metals are recovered in a concentrated form with the bacterial biomass. Uranium forms binuclear complex with citric acid and is not biodegraded. The supernatant containing uranium citrate complex is separated and upon exposure to light, undergoes rapid degradation resulting in the formation of an insoluble, stable polymeric form of uranium. Uranium is recovered as a precipitate (polyuranate) in a concentrated form for recycling or for appropriate disposal. This treatment process, unlike others which use caustic reagents, does not create additional hazardous wastes for disposal and causes little damage to soil which can then be returned to normal use.

  19. Management of Plant-parasitic Nematodes with a Chitin-Urea Soil Amendment and Other Materials

    PubMed Central

    Westerdahl, B. B.; Carlson, H. L.; Grant, J.; Radewald, J. D.; Welch, N.; Anderson, C. A.; Darso, J.; Kirby, D.; Shibuya, F.

    1992-01-01

    Field trials were conducted with a chitin-urea soil amendment and several other nematicides on four crop-nematode combinations: tomato-Meloidogyne incognita; potato-Meloidogyne chitwoodi; walnut-Pratylenchus vulnus; and brussels sprouts-Heterodera schachtii. Significant (P ≤ 0.10) nematode population reductions were obtained with the chitin-urea soil amendment in the trims on potato and walnut. In the trials on brussels sprouts and on tomato, phytotoxicity occurred at rates of 1,868 and 1,093 kg/ha, respectively. Significant (P ≤ 0.10) nematode reductions were also obtained with metham sodium on potato; with 1,3-D on tomato and brussels sprouts; and with sodium tetrathiocarbonate, XRM 5053, fenamiphos, ethoprop, LX1075-05, LX1075-07, and SN 109106 on tomato. The following materials did not provide significant nematode control under the conditions of the particular experiments: metham sodium, oxamyl, and Yucca extract on tomato; and dazomet granules on brussels sprouts. PMID:19283044

  20. Thermodynamic properties of several soil- and sediment-derived natural organic materials.

    PubMed

    DeLapp, Rossane C; LeBoeuf, Eugene J; Bell, Katherine D

    2004-01-01

    Improved understanding of the structure of soil- and sediment-derived organic matter is critical to elucidating the mechanisms that control the reactivity and transport of contaminants in the environment. This work focuses on an experimental investigation of thermodynamic properties that are a function of the macromolecular structure of natural organic matter (NOM). A suite of thermal analysis instruments were employed to quantify glass transition temperatures (Tg), constant-pressure specific heat capacities (Cp), and thermal expansion coefficients (alpha) of several International Humic Substances Society (IHSS) soil-, sediment-, and aquatic-derived NOMs. Thermal mechanical analysis (TMA) of selected NOMs identified Tgs between 36 and 72 degrees C, and alphas ranging from 11 mum/m degrees C below the Tg to 242 mum/m degrees C above the Tg. Standard differential scanning calorimetry (DSC) and temperature-modulated differential scanning calorimetry (TMDSC) measurements provided additional evidence of glass transition behavior, including identification of multiple transition behavior in two aquatic samples. TMDSC also provided quantitative measures of Cp at 0 and 25 degrees C, ranging from 1.27 to 1.44 J/g degrees C. Results from TMA, DSC, and TMDSC analyses are consistent with glass transition theories for organic macromolecules, and the glass transition behavior of other NOM materials reported in previous studies. Discussion of the importance of quantifying these thermodynamic properties is presented in terms of improved physical and chemical characterization of NOM structures, and in terms of providing constraints to molecular simulation models of NOM structures. PMID:14581055

  1. Management of Plant-parasitic Nematodes with a Chitin-Urea Soil Amendment and Other Materials.

    PubMed

    Westerdahl, B B; Carlson, H L; Grant, J; Radewald, J D; Welch, N; Anderson, C A; Darso, J; Kirby, D; Shibuya, F

    1992-12-01

    Field trials were conducted with a chitin-urea soil amendment and several other nematicides on four crop-nematode combinations: tomato-Meloidogyne incognita; potato-Meloidogyne chitwoodi; walnut-Pratylenchus vulnus; and brussels sprouts-Heterodera schachtii. Significant (P soil amendment in the trims on potato and walnut. In the trials on brussels sprouts and on tomato, phytotoxicity occurred at rates of 1,868 and 1,093 kg/ha, respectively. Significant (P materials did not provide significant nematode control under the conditions of the particular experiments: metham sodium, oxamyl, and Yucca extract on tomato; and dazomet granules on brussels sprouts. PMID:19283044

  2. Removal and recovery of radionuclides and toxic metals from wastes, soils and materials

    SciTech Connect

    Francis, A.J.

    1993-07-01

    A process has been developed at Brookhaven National Laboratory (BNL) for the removal of metals and radionuclides from contaminated materials, soils, and waste sites (Figure 1). In this process, citric acid, a naturally occurring organic complexing agent, is used to extract metals such as Ba, Cd, Cr, Ni, Zn, and radionuclides Co, Sr, Th, and U from solid wastes by formation of water soluble, metal-citrate complexes. Citric acid forms different types of complexes with the transition metals and actinides, and may involve formation of a bidentate, tridentate, binuclear, or polynuclear complex species. The extract containing radionuclide/metal complex is then subjected to microbiological degradation followed by photochemical degradation under aerobic conditions. Several metal citrate complexes are biodegraded and the metals are recovered in a concentrated form with the bacterial biomass. Uranium forms binuclear complex with citric acid and is not biodegraded. The supernatant containing uranium citrate complex is separated and upon exposure to light, undergoes rapid degradation resulting in the formation of an insoluble, stable polymeric form of uranium. Uranium is recovered as a precipitate (uranium trioxide) in a concentrated form for recycling or for appropriate disposal. This treatment process, unlike others which use caustic reagents, does not create additional hazardous wastes for disposal and causes little damage to soil which can then be returned to normal use.

  3. Effect of Soil Solid-Phase Material Migration on Soil Properties within a Small Watershed Detected Using the Magnetic Tracer Method

    NASA Astrophysics Data System (ADS)

    Koshovskii, Timur; Gennadiev, Alexander; Zhidkin, Andrei

    2014-05-01

    We have performed detailed studies of the lateral migration of the solid soil material and the soil cover within a small catchment area (Russia, Tula region, Lokna river basin). The main goal of this work is to characterize the migration and accumulation features of the soil solid-phase material within a small watershed and to analyze the effect of the lateral mass transfer on the crucial soil fertility-related properties in the catchment basin under study. The total area of the catchment and the ravine network elements is 96 ha. The catchment basin is drop-shaped; it slightly curves and is latitudinally oriented. The catchment basin's slopes are of southern, eastern, northern, and intermediate exposures with average inclination of 1,5-5 degrees. The magnetic tracer method was used to assess the volumes and rates of the lateral migration of the solid-phase soil material on the selected territory. This method is based on the investigation of the spherical magnetic particles (SMPs), which fall onto the soil cover from the atmosphere, where they arrive at the burning of coals and some other fuels, mostly in steam locomotives. The period of the most intensive emission of SMPs into the soil in the territory of Russia corresponds to the last 100-150 years [1]. The reserve of SMPs in the 0- to 25-cm layer is estimated to be 3.8 g/m2on the least eroded sub-horizontal surface. The zones with the concentration of SMPs lower than their average content on the least eroded surface were characterized as dispersion zones. The zones of the basin with significant exceeding the value of 3.8 g/m2 were marked as accumulation zones of the soil solid-phase material. Dispersion zones are found in the middle part of the ridge in the north-eastern area, in the middle part of a longslope in the south-western area of the catchment basin, and other [2]. Accumulation zones are observed in a cup-shaped depression on the plowed slope adjacent to the ravine's head, on steep unplowed slopes of the

  4. MICHIGAN SOIL VAPOR EXTRACTION REMEDIATION (MISER) MODEL: A COMPUTER PROGRAM TO MODEL SOIL VAPORT EXTRACTION AND BIOVENTING OF ORGANIC MATERIALS IN UNSATURATED GEOLOGICAL MATERIAL

    EPA Science Inventory

    This report describes the formulation, numerical development, and use of a multiphase, multicomponent, biodegradation model designed to simulate physical, chemical, and biological interactions occurring primarily in field scale soil vapor extraction (SVE) and bioventing (B...

  5. The influence of maternal self-objectification, materialism and parenting style on potentially sexualized 'grown up' behaviours and appearance concerns in 5-8year old girls.

    PubMed

    Slater, Amy; Tiggemann, Marika

    2016-08-01

    There is widespread concern about young girls displaying 'grown up' or sexualized behaviours, as well as experiencing body image and appearance concerns that were previously thought to only impact much older girls. The present study examined the influence of three maternal attributes, self-objectification, materialism and parenting style, on sexualized behaviours and appearance concerns in young girls. A sample of 252 Australian mothers of 5-8year old girls reported on the behaviours and appearance concerns observed in their daughters and also completed measures of their own self-objectification, materialism and parenting style. It was found that a significant proportion of young girls were engaging with 'teen' culture, using beauty products and expressing some degree of appearance concern. Maternal self-objectification was related to daughters' engagement in teen culture, use of beauty products and appearance concern. Maternal materialism was related to girls' engagement in teen culture and appearance concern, while an authoritative parenting style was negatively related to girls' use of beauty products. The findings suggest that maternal self-objectification and materialism play a role in the body image and appearance concerns of young girls, and in so doing, identify these maternal attributes as novel potential targets for intervention. PMID:27203569

  6. Helping Parents to Help Children.

    ERIC Educational Resources Information Center

    Lapides, Joseph

    Provided are materials from a workshop on parental attitudes toward their handicapped children and professionals' attitudes toward parents. Listed are four workshop objectives: to develop an existential view of parental attitudes, to identify the five frequently observed parent attitudes, to provide experience in working through four parental…

  7. Impact of rock materials and biofertilizations on P and K availability for maize (Zea Maize) under calcareous soil conditions

    PubMed Central

    Abou-el-Seoud, I.I.; Abdel-Megeed, A.

    2011-01-01

    The present work evaluated the synergistic effects of soil fertilization with rock P and K materials and co-inoculation with P and K-dissolving bacteria [PDB (Bacillus megaterium var. phosphaticum) and KDB (Bacillus mucilaginosus and B. subtilis)] on the improvement of P and K uptake, P and K availability and growth of maize plant grown under limited P and K soil conditions (calcareous soil). The experiment was establishment with eight treatments: without rock P and K materials or bacteria inoculation (control), rock P (RP), rock K (RK), RP + PDB, RK + KDB and R(P + K)+(P + K)DB. Under the same conditions of this study, co-inoculation of PDB and KDB in conjunction with direct application of rock P and K materials (R(P + K)) into the soil increased P and K availability and uptake, and the plant growth (shoot and root growth) of maize plants grown on P and K limited soils. PMID:23961162

  8. Impact of rock materials and biofertilizations on P and K availability for maize (Zea Maize) under calcareous soil conditions.

    PubMed

    Abou-El-Seoud, I I; Abdel-Megeed, A

    2012-01-01

    The present work evaluated the synergistic effects of soil fertilization with rock P and K materials and co-inoculation with P and K-dissolving bacteria [PDB (Bacillus megaterium var. phosphaticum) and KDB (Bacillus mucilaginosus and B. subtilis)] on the improvement of P and K uptake, P and K availability and growth of maize plant grown under limited P and K soil conditions (calcareous soil). The experiment was establishment with eight treatments: without rock P and K materials or bacteria inoculation (control), rock P (RP), rock K (RK), RP + PDB, RK + KDB and R(P + K)+(P + K)DB. Under the same conditions of this study, co-inoculation of PDB and KDB in conjunction with direct application of rock P and K materials (R(P + K)) into the soil increased P and K availability and uptake, and the plant growth (shoot and root growth) of maize plants grown on P and K limited soils. PMID:23961162

  9. Data Collection Handbook to Support Modeling Impacts of Radioactive Material in Soil and Building Structures

    SciTech Connect

    Yu, Charley; Kamboj, Sunita; Wang, Cheng; Cheng, Jing-Jy

    2015-09-01

    This handbook is an update of the 1993 version of the Data Collection Handbook and the Radionuclide Transfer Factors Report to support modeling the impact of radioactive material in soil. Many new parameters have been added to the RESRAD Family of Codes, and new measurement methodologies are available. A detailed review of available parameter databases was conducted in preparation of this new handbook. This handbook is a companion document to the user manuals when using the RESRAD (onsite) and RESRAD-OFFSITE code. It can also be used for RESRAD-BUILD code because some of the building-related parameters are included in this handbook. The RESRAD (onsite) has been developed for implementing U.S. Department of Energy Residual Radioactive Material Guidelines. Hydrogeological, meteorological, geochemical, geometrical (size, area, depth), crops and livestock, human intake, source characteristic, and building characteristic parameters are used in the RESRAD (onsite) code. The RESRAD-OFFSITE code is an extension of the RESRAD (onsite) code and can also model the transport of radionuclides to locations outside the footprint of the primary contamination. This handbook discusses parameter definitions, typical ranges, variations, and measurement methodologies. It also provides references for sources of additional information. Although this handbook was developed primarily to support the application of RESRAD Family of Codes, the discussions and values are valid for use of other pathway analysis models and codes.

  10. [Effects of Different Kinds of Organic Materials on Soil Heavy Metal Phytoremediation Efficiency by Sedum alfredii Hance].

    PubMed

    Yao, Gui-hua; Xu, Hai-zhou; Zhu, Lin-gang; Ma, Jia-wei; Liu, Dan; Ye, Zheng-qian

    2015-11-01

    In this study, a pot experiment was conducted to investigate the effect of clean organic materials i. e., biogas residue (BR), mushroom residue (MR), and bamboo shell (BS) on phytoextraction remediation of two heavy metal contaminated soils (collected from Wenzhou and Fuyang, which referred to "Wenzhou soil" and "Fuyang soil", respectively.) using a cadmium (Cd) and zinc (Zn) hyperaccumulator Sedum alfredii Hance. The results indicated that the effects of organic materials on availabilities of soil heavy metals were different due to different kinds of heavy metals, organic materials, and the application rates of the organic materials. Addition with 5% BR showed the greatest activation to copper (Cu), Zn in Wenzhou soil, and in Fuyang soil 1% BS had the highest activation for Cu, Zn, lead ( Ph) and Cd. Growth of shoot biomass of Sedum alfredii Hance increased with the addition rate of organic materials, and the plant dry weights were increased by 23.7%-93.0%. In Wenzhou soil, only 1% BS treatment had the best effect on Cd uptake and accumulation in shoots of Sedum alfredii Hance, increased by 22.6%, while other treatments were inferior to the control. For Zn, MR treatments were inferior to the control, while other treafments were superior to the control, of which 5% BR, 1% BS and 5% BS exceeded the control by 39. 6%, 32.6% and 23.8%, respectively. In Fuyang soil, for Cd, the treatment effects of 5% BS, 1% BR and 5% BR were the greatest, of which Cd accumulation in shoots exceeded the control by 12.9%, 12.8% and 6.2%, respectively, while Cd accumulations in shoots in all other treatments were less than that of control. For Zn, the treatments of adding organic materials promoted Zn accumulation in shoots of Sedum alfredii Hance, and the best treatments were as follows: 5% BS. 5% BR and 5% MR, exceeded the control by 38.4%, 25.7% and 22.4%, respectively. PMID:26911018

  11. PRODUCTION OF METHYL SULFIDE AND DIMETHYL DISULFIDE FROM SOIL-INCORPORATED PLANT MATERIALS AND IMPLICATIONS FOR CONTROLLING SOILBORNE PATHOGENS

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil-incorporated plant materials have been associated with reduction in soilborne pathogens and diseases. Most credits have been given to secondary products of glucosinolate hydrolysis. Little is known about the production of volatile sulfur compounds and even less on their efficacy against soilb...

  12. Effectiveness of mineral soil to adsorb the natural occurring radioactive material (norm), uranium and thorium

    SciTech Connect

    Amir, Muhammad Nur Iman; Ismail, Nurul Izzatiafifi; Wood, Ab. Khalik Saat, Ahmad; Hamzah, Zaini

    2015-04-29

    A study has been performed on U-soil and Th-soil adsorption of three types of soil collected from Selangor State of Malaysia which are Saujana Putra, Bukit Changgang and Jenderam Hilir. In this study, natural radionuclide (U and Th) soil adsorption based on batch experiments with various initial concentrations of the radionuclide elements were carried out. Parameters that were set constant include pH at 5;amount of soil used was 5 g each, contact time was 24 hour and different initial concentration for each solution of U and Th which is 5 mg/L, 10 mg/L, 15 mg/L, 20 mg/L, 25 mg/L and 40 mg/L were used. The K{sub d} values for each type of soil were determined in this batch experiments which was based on US-EPA method, in order to estimate adsorption capacity of the soil.The K{sub d} values of Th found higher than Kd values of U for all of the soil samples, and the highest was found on the soil collected from Bukit Changgang. The soil clay content was one of factors to influence the adsorption of both U and Th from dilute initial solution. The U-soil and Th-soil adsorption process for all the soil samples studied are generally obeying unimolecular layer Langmuir isotherm model. From Langmuir isotherm, the maximum adsorption capacity for U was 0.393mg/g and for Th was 1.53 mg/g for the soil that was taken from Bukit Changgang. From the study, it suggested that the soil from Bukit Changgang applicable as potential enhanced barrier for site disposing waste containing U and Th.

  13. Effectiveness of mineral soil to adsorb the natural occurring radioactive material (norm), uranium and thorium

    NASA Astrophysics Data System (ADS)

    Amir, Muhammad Nur Iman; Ismail, Nurul Izzatiafifi; Wood, Ab. Khalik; Saat, Ahmad; Hamzah, Zaini

    2015-04-01

    A study has been performed on U-soil and Th-soil adsorption of three types of soil collected from Selangor State of Malaysia which are Saujana Putra, Bukit Changgang and Jenderam Hilir. In this study, natural radionuclide (U and Th) soil adsorption based on batch experiments with various initial concentrations of the radionuclide elements were carried out. Parameters that were set constant include pH at 5;amount of soil used was 5 g each, contact time was 24 hour and different initial concentration for each solution of U and Th which is 5 mg/L, 10 mg/L, 15 mg/L, 20 mg/L, 25 mg/L and 40 mg/L were used. The Kd values for each type of soil were determined in this batch experiments which was based on US-EPA method, in order to estimate adsorption capacity of the soil.The Kd values of Th found higher than Kd values of U for all of the soil samples, and the highest was found on the soil collected from Bukit Changgang. The soil clay content was one of factors to influence the adsorption of both U and Th from dilute initial solution. The U-soil and Th-soil adsorption process for all the soil samples studied are generally obeying unimolecular layer Langmuir isotherm model. From Langmuir isotherm, the maximum adsorption capacity for U was 0.393mg/g and for Th was 1.53 mg/g for the soil that was taken from Bukit Changgang. From the study, it suggested that the soil from Bukit Changgang applicable as potential enhanced barrier for site disposing waste containing U and Th.

  14. Dinosaur Reproduction and Parenting

    NASA Astrophysics Data System (ADS)

    Horner, John R.

    Non-avian dinosaur reproductive and parenting behaviors were mostly similar to those of extant archosaurs. Non-avian dinosaurs were probably sexually dimorphic and some may have engaged in hierarchical rituals. Non-avian coelurosaurs (e.g. Troodontidae, Oviraptorosauria) had two active oviducts, each of which produced single eggs on a daily or greater time scale. The eggs of non-coelurosaurian dinosaurs (e.g. Ornithischia, Sauropoda) were incubated in soils, whereas the eggs of non-avian coelurosaurs (e.g. Troodon, Oviraptor) were incubated with a combination of soil and direct parental contact. Parental attention to the young was variable, ranging from protection from predators to possible parental feeding of nest-bound hatchlings. Semi-altricial hadrosaur hatchlings exited their respective nests near the time of their first linear doubling. Some reproductive behaviors, once thought exclusive to Aves, arose first in non-avian dinosaurs. The success of the Dinosauria may be related to reproductive strategies.

  15. Modeling soil magnetic susceptibility and frequency-dependent susceptibility to aid landmine clearance.

    NASA Astrophysics Data System (ADS)

    Hannam, Jacqueline A.; Dearing, John A.

    2006-05-01

    Information on the electromagnetic properties of soils and their effects on metal detectors is increasingly necessary for effective demining due to limited detector efficacy in highly magnetic soils and the difficulty of detecting minimummetal mines. Magnetic measurements of soils, such as magnetic susceptibility and frequency dependent susceptibility can aid the detection of problem soils, but are not part of standard soil analyses. Consequently, little information about soil magnetism exists within the soil, environmental science and environmental geophysics communities. Lack of empirical data may be compensated through the estimation of soil magnetic characteristics by predictive modeling approaches. Initial modeling of soil types in Bosnia and Herzegovina (BiH) was attempted by expert and analogue approaches, using only coarse scale soil type information, which resulted in the production of national soil maps for low field and frequency-dependent susceptibility. Validation of the maps was achieved by comparison of empirical magnetic data from soil samples in the National Bosnian soil archive in Sarajevo. Discrepancies between the model and empirical data are explained in part by the differences in soil parent material within each soil type, which controls the amount of Fe released into the soil system available for in situ conversion to magnetic Fe oxides. The integration of soil information (type and parent material), expert knowledge and empirical data refines the predictive modeling of soil magnetic characteristics in temperate-Mediterranean environments such as BiH. Further spatial separation of soil types in the landscape can be achieved by digital terrain modeling. Preliminary fine-scale, landscape-soil modeling indicates improved spatial resolution of soil types compared with the original coarsely-mapped soil units, and the potential to synthesize local scale soil magnetic maps.

  16. Soil magnetic susceptibility reflects soil moisture regimes and the adaptability of tree species to these regimes

    USGS Publications Warehouse

    Wang, J.-S.; Grimley, D.A.; Xu, C.; Dawson, J.O.

    2008-01-01

    Flooded, saturated or poorly drained soils are frequently anaerobic, leading to dissolution of the strongly magnetic minerals, magnetite and maghemite, and a corresponding decrease in soil magnetic susceptibility (MS). In this study of five temperate deciduous forests in east-central Illinois, USA, mean surface soil MS was significantly higher adjacent to upland tree species (31 ?? 10-5 SI) than adjacent to floodplain or lowland tree species (17 ?? 10-5 SI), when comparing regional soils with similar parent material of loessal silt. Although the sites differ in average soil MS for each tree species, the relative order of soil MS means for associated tree species at different locations is similar. Lowland tree species, Celtis occidentalis L., Ulmus americana L., Acer saccharinum L., Carya laciniosa (Michx. f.) Loud., and Fraxinus pennsylvanica Marsh. were associated with the lowest measured soil MS mean values overall and at each site. Tree species' flood tolerance rankings increased significantly, as soil MS values declined, the published rankings having significant correlations with soil MS values for the same species groups. The three published classifications of tree species' flood tolerance were significantly correlated with associated soil MS values at all sites, but most strongly at Allerton Park, the site with the widest range of soil drainage classes and MS values. Using soil MS measurements in forests with soil parent material containing similar initial levels of strongly magnetic minerals can provide a simple, rapid and quantitative method to classify soils according to hydric regimes, including dry conditions, and associated plant composition. Soil MS values thus have the capacity to quantify the continuum of hydric tolerances of tree species and guide tree species selection for reforestation. ?? 2007 Elsevier B.V. All rights reserved.

  17. Tillage and crop rotation effects on soil quality in two Iowa fields

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil quality is affected by inherent (parent material, climate, and topography) and anthropogenic (tillage and crop rotation) factors. We evaluated effects of five tillage treatments on 23 potential soil quality indicators after 31 years in a corn (Zea mays L.)/soybean [Glycine max (L.) Merr.] rotat...

  18. Quantitative Relationships Between Net Volume Change and Fabric Properties During Soil Evolution

    NASA Technical Reports Server (NTRS)

    Chadwick, O. A.; Nettleton, W. D.

    1993-01-01

    The state of soil evolution can be charted by net long-term volume and elemental mass changes for individual horizons compared with parent material. Volume collapse or dilation depends on relative elemental mass fluxes associated with losses form or additions to soil horizons.

  19. Curriculum Guide for Parent Education Programs (Including Special Sections for Rural Parents, Single Parents, Working Parents, and High Risk Parents). Columbia Basin College Parent Education Program.

    ERIC Educational Resources Information Center

    Hare, Jo Ann; And Others

    This curriculum for parent education through cooperative preschools has a sequential approach, with topics developed for parents with different age children enrolled in the various laboratory settings. Introductory materials include the goals and objectives for community college parent cooperative programs, methods of presentation, and a…

  20. Rehabilitation materials from surface- coal mines in western U.S.A. III. Relations between elements in mine soil and uptake by plants.

    USGS Publications Warehouse

    Severson, R.C.; Gough, L.P.

    1984-01-01

    Plant uptake of Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn from mine soils was assessed using alfalfa Medicago sativa, sainfoin Onobrychis viciaefolia, smooth brome Bromus inermis, crested wheatgrass Agropyron cristatum, slender wheatgrass A. trachycaulum and intermediate wheatgrass A. intermedium; mine soil (cover-soil and spoil material) samples were collected from rehabilitated areas of 11 western US surface-coal mines in North Dakota, Montana, Wyoming and Colorado. Correlations between metals in plants and DTPA-extractable metals from mine soils were generally not statistically significant and showed no consistent patterns for a single metal or for a single plant species. Metal uptake by plants, relative to amounts in DTPA extracts of mine soil, was positively related to mine soil organic matter content or negatively related to mine soil pH. DTPA-extractable metal levels were significantly correlated with mine soil pH and organic-matter content.-from Authors

  1. Conserving Soil.

    ERIC Educational Resources Information Center

    Soil Conservation Service (USDA), Washington, DC.

    Designed as enrichment materials for grades six through nine, this program is an interdisciplinary study of soils. As part of the program students: (1) examine soil organisms; (2) research history of local Native Americans to see how they and others have used the land and its soils; (3) investigate how soils are degraded and how they are conserved…

  2. Immobilization of heavy metals in polluted soils by the addition of zeolitic material synthesized from coal fly ash.

    PubMed

    Querol, Xavier; Alastuey, Andrés; Moreno, Natàlia; Alvarez-Ayuso, Esther; García-Sánchez, Antonio; Cama, Jordi; Ayora, Carles; Simón, Mariano

    2006-01-01

    The use of zeolitic material synthesized from coal fly ash for the immobilization of pollutants in contaminated soils was investigated in experimental plots in the Guadiamar Valley (SW Spain). This area was affected by a pyrite slurry spill in April 1998. Although reclamation activities were completed in a few months, residual pyrite slurry mixed with soil accounted for relatively high leachable levels of trace elements such as Zn, Pb, As, Cu, Sb, Co, Tl and Cd. Phytoremediation strategies were adopted for the final recovery of the polluted soils. The immobilization of metals had previously been undertaken to avoid leaching processes and the consequent groundwater pollution. To this end, 1100 kg of high NaP1 (Na6[(AlO2)6(SiO2)10] .15H2O) zeolitic material was synthesized using fly ash from the Teruel power plant (NE Spain), in a 10 m3 reactor. This zeolitic material was manually applied using different doses (10000-25000 kg per hectare), into the 25 cm topsoil. Another plot (control) was maintained without zeolite. Sampling was carried out 1 and 2 years after the zeolite addition. The results show that the zeolitic material considerably decreases the leaching of Cd, Co, Cu, Ni, and Zn. The sorption of metals in soil clay minerals (illite) proved to be the main cause contributing to the immobilization of these pollutants. This sorption could be a consequence of the rise in pH from 3.3 to 7.6 owing to the alkalinity of the zeolitic material added (caused by traces of free lime in the fly ash, or residual NaOH from synthesis). PMID:16039695

  3. Effects of soil management techniques on soil water erosion in apricot orchards.

    PubMed

    Keesstra, Saskia; Pereira, Paulo; Novara, Agata; Brevik, Eric C; Azorin-Molina, Cesar; Parras-Alcántara, Luis; Jordán, Antonio; Cerdà, Artemi

    2016-05-01

    Soil erosion is extreme in Mediterranean orchards due to management impact, high rainfall intensities, steep slopes and erodible parent material. Vall d'Albaida is a traditional fruit production area which, due to the Mediterranean climate and marly soils, produces sweet fruits. However, these highly productive soils are left bare under the prevailing land management and marly soils are vulnerable to soil water erosion when left bare. In this paper we study the impact of different agricultural land management strategies on soil properties (bulk density, soil organic matter, soil moisture), soil water erosion and runoff, by means of simulated rainfall experiments and soil analyses. Three representative land managements (tillage/herbicide/covered with vegetation) were selected, where 20 paired plots (60 plots) were established to determine soil losses and runoff. The simulated rainfall was carried out at 55mmh(-1) in the summer of 2013 (<8% soil moisture) for one hour on 0.25m(2) circular plots. The results showed that vegetation cover, soil moisture and organic matter were significantly higher in covered plots than in tilled and herbicide treated plots. However, runoff coefficient, total runoff, sediment yield and soil erosion were significantly higher in herbicide treated plots compared to the others. Runoff sediment concentration was significantly higher in tilled plots. The lowest values were identified in covered plots. Overall, tillage, but especially herbicide treatment, decreased vegetation cover, soil moisture, soil organic matter, and increased bulk density, runoff coefficient, total runoff, sediment yield and soil erosion. Soil erosion was extremely high in herbicide plots with 0.91Mgha(-1)h(-1) of soil lost; in the tilled fields erosion rates were lower with 0.51Mgha(-1)h(-1). Covered soil showed an erosion rate of 0.02Mgha(-1)h(-1). These results showed that agricultural management influenced water and sediment dynamics and that tillage and herbicide

  4. Effect of Magnesium as Substitute Material in Enzyme-Mediated Calcite Precipitation for Soil-Improvement Technique.

    PubMed

    Putra, Heriansyah; Yasuhara, Hideaki; Kinoshita, Naoki; Neupane, Debendra; Lu, Chih-Wei

    2016-01-01

    The optimization of enzyme-mediated calcite precipitation was evaluated as a soil-improvement technique. In our previous works, purified urease was utilized to bio-catalyze the hydrolysis of urea, which causes the supplied Ca(2+) to precipitate with [Formula: see text] as calcium carbonate. In the present work, magnesium chloride was newly added to the injecting solutions to delay the reaction rate and to enhance the amount of carbonate precipitation. Soil specimens were prepared in PVC cylinders and treated with concentration-controlled solutions composed of urea, urease, calcium, and magnesium chloride. The mechanical properties of the treated soil specimens were examined through unconfined compressive strength (UCS) tests. A precipitation ratio of the carbonate up to 90% of the maximum theoretical precipitation was achieved by adding a small amount of magnesium chloride. Adding magnesium chloride as a delaying agent was indeed found to reduce the reaction rate of the precipitation, which may increase the volume of the treated soil if used in real fields because of the slower precipitation rate and the resulting higher injectivity. A mineralogical analysis revealed that magnesium chloride decreases the crystal size of the precipitated materials and that another carbonate of aragonite is newly formed. Mechanical test results indicated that carbonate precipitates within the soils and brings about a significant improvement in strength. A maximum UCS of 0.6 MPa was obtained from the treated samples. PMID:27200343

  5. Effect of different mulch materials on winter wheat production in desalinized soil in Heilonggang region of North China*

    PubMed Central

    Yang, Yan-min; Liu, Xiao-jing; Li, Wei-qiang; Li, Cun-zhen

    2006-01-01

    Freshwater shortage is the main problem in Heilonggang lower-lying plain, while a considerable amount of underground saline water is available. We wanted to find an effective way to use the brackish water in winter wheat production. Surface mulch has significant effect in reducing evaporation and decreasing soil salinity level. This research was aimed at comparing the effect of different mulch materials on winter wheat production. The experiment was conducted during 2002~2003 and 2003~2004. Four treatments were setup: (1) no mulch, (2) mulch with plastic film, (3) mulch with corn straw, (4) mulch with concrete slab between the rows. The result indicated that concrete mulch and straw mulch was effective in conserving soil water compared to plastic film mulch which increased soil temperature. Concrete mulch decreases surface soil salinity better in comparison to other mulches used. Straw mulch conserved more soil water but decreased wheat grain yield probably due to low temperature. Concrete mulch had similar effect with plastic film mulch on promoting winter wheat development and growth. PMID:17048298

  6. Comparison of American Society of Testing Materials and Soil Science Society of America Hydrometer Methods for Particle-Size Analysis

    SciTech Connect

    Keller, Jason M.; Gee, Glendon W.

    2006-05-31

    Particle-size analysis (PSA) is widely used in both soil science and geo-engineering. Soil classification schemes are built on PSA values while recent developments in pedotransfer functions rely on PSA to estimate soil hydraulic properties. Because PSA is method dependent, the standardization of experimental procedures is important for the comparison of reported results. A study was conducted to compare the American Society of Testing Materials (ASTM) hydrometer method (D422) for particle-size analysis with the hydrometer method published by the Soil Science Society of America (SSSA). Tests on soils ranging in texture from sand to a sandy clay loam were conducted at temperatures ranging from 20 C to 30 C. The main difference between methods is the temperature correction, with the ASTM method relying on an empirical correction and the SSSA method using a blank hydrometer reading. Identical texture estimates for all but one sample was observed between methods. Percent fines, silt, and clay demonstrated relatively consistent values between methods. D50 and D30 showed reasonable agreement between methods, with differences of less than 4 percent and 8 percent. For D10 values, the agreement was less satisfactory, with uncertainties of as much as 10 percent. The results suggest that ASTM and SSSA methods can be used interchangeably for textural analysis.

  7. Quantification of the vertical translocation rate of soil solid-phase material by the magnetic tracer method

    NASA Astrophysics Data System (ADS)

    Zhidkin, A. P.; Gennadiev, A. N.

    2016-07-01

    Approaches to the quantification of the vertical translocation rate of soil solid-phase material by the magnetic tracer method have been developed; the tracer penetration depth and rate have been determined, as well as the radial distribution of the tracer in chernozems (Chernozems) and dark gray forest soils (Luvisols) of Belgorod oblast under natural steppe and forest vegetation and in arable lands under agricultural use of different durations. It has been found that the penetration depth of spherical magnetic particles (SMPs) during their 150-year-occurrence in soils of a forest plot is 68 cm under forest, 58 cm on a 100-year old plowland, and only 49 cm on a 150-year-old plowland. In the chernozems of the steppe plot, the penetration depth of SMPs exceeds the studied depth of 70 cm both under natural vegetation and on the plowlands. The penetration rates of SMPs deep into the soil vary significantly among the key plots: 0.92-1.32 mm/year on the forest plot and 1.47-1.63 mm/year on the steppe plot, probably because of the more active recent turbation activity of soil animals.

  8. Effect of Magnesium as Substitute Material in Enzyme-Mediated Calcite Precipitation for Soil-Improvement Technique

    PubMed Central

    Putra, Heriansyah; Yasuhara, Hideaki; Kinoshita, Naoki; Neupane, Debendra; Lu, Chih-Wei

    2016-01-01

    The optimization of enzyme-mediated calcite precipitation was evaluated as a soil-improvement technique. In our previous works, purified urease was utilized to bio-catalyze the hydrolysis of urea, which causes the supplied Ca2+ to precipitate with CO32− as calcium carbonate. In the present work, magnesium chloride was newly added to the injecting solutions to delay the reaction rate and to enhance the amount of carbonate precipitation. Soil specimens were prepared in PVC cylinders and treated with concentration-controlled solutions composed of urea, urease, calcium, and magnesium chloride. The mechanical properties of the treated soil specimens were examined through unconfined compressive strength (UCS) tests. A precipitation ratio of the carbonate up to 90% of the maximum theoretical precipitation was achieved by adding a small amount of magnesium chloride. Adding magnesium chloride as a delaying agent was indeed found to reduce the reaction rate of the precipitation, which may increase the volume of the treated soil if used in real fields because of the slower precipitation rate and the resulting higher injectivity. A mineralogical analysis revealed that magnesium chloride decreases the crystal size of the precipitated materials and that another carbonate of aragonite is newly formed. Mechanical test results indicated that carbonate precipitates within the soils and brings about a significant improvement in strength. A maximum UCS of 0.6 MPa was obtained from the treated samples. PMID:27200343

  9. Particle size distribution of eroded material from semi-arid soils

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The particle size distribution (PSD) of eroded sediments can be used to deduce potential nutrient losses, pollution hazards and the redistribution of soil components over the landscape. We studied eroded sediments from three semi-arid soils, with different clay contents, that were wetted at a slow (...

  10. Contributions of pyrogenic materials on the accumulation of soil organic matter

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Soil amendment of charcoal co-product (HHVdb as high as coal) from thermochemical waste biomass-to-energy conversion (slow/fast pyrolysis and gasification) has received considerable interests for both contaminated and agricultural lands. Biochar amendment not only increases soil organic carbon cont...

  11. An interdisciplinary approach to decipher different phases of soil formation using root abundances and geochemical methods

    NASA Astrophysics Data System (ADS)

    Wiesenberg, Guido; Gocke, Martina

    2015-04-01

    Pedogenic processes are commonly thought to be restricted mainly to the uppermost few dm of soils. However, often processes like water infiltration and - more obviously - rooting lead to much deeper penetration of soil, soil parent material and, if present, paleosols. The extent to which root penetration and subsequent organic matter incorporation, release of root exudates and microbial activity influence the general chemical and physical properties of deeper soil horizons remains largely unknown. We determined the lateral extent of root-derived overprint of the soil parent material as well as the overprint of the chemical properties in paleosols by combining root quantities obtained in the field with a large variety of inorganic and organic chemical as well as microbial properties in bulk soils and rhizosphere samples. Soils, soil parent material and paleosols were sampled along a transect from The Netherlands via Germany and Hungary towards Serbia, where soil and underlying loess, sand, and paleosol profiles were excavated in pits of 2 m to 13 m depth. Root counting on horizontal levels and profile walls during field campaigns, assisted by three-dimensional X-ray microtomographic scanning of undisturbed samples, enabled the quantitative assessment of recent and ancient root systems. Ages were determined by 14C dating for the latter, and by OSL dating for sediments, respectively. The bulk elemental composition of soils, sediments and paleosols and molecular structure of organic matter therein helped to quantitatively assess the root-related overprint in different depth intervals. The results point to the significance of deep roots as a soil forming factor extending into soil parent material, as well as the overprint of geochemical proxies in paleosols due to intense root penetration at various phases after burial. The shown examples highlight potential pitfalls in assessing rooted soil and paleosol profiles and their ages, and provide potential solutions for

  12. Spatial disaggregation of complex soil map units at regional scale based on soil-landscape relationships

    NASA Astrophysics Data System (ADS)

    Vincent, Sébastien; Lemercier, Blandine; Berthier, Lionel; Walter, Christian

    2015-04-01

    Accurate soil information over large extent is essential to manage agronomical and environmental issues. Where it exists, information on soil is often sparse or available at coarser resolution than required. Typically, the spatial distribution of soil at regional scale is represented as a set of polygons defining soil map units (SMU), each one describing several soil types not spatially delineated, and a semantic database describing these objects. Delineation of soil types within SMU, ie spatial disaggregation of SMU allows improved soil information's accuracy using legacy data. The aim of this study was to predict soil types by spatial disaggregation of SMU through a decision tree approach, considering expert knowledge on soil-landscape relationships embedded in soil databases. The DSMART (Disaggregation and Harmonization of Soil Map Units Through resampled Classification Trees) algorithm developed by Odgers et al. (2014) was used. It requires soil information, environmental covariates, and calibration samples, to build then extrapolate decision trees. To assign a soil type to a particular spatial position, a weighed random allocation approach is applied: each soil type in the SMU is weighted according to its assumed proportion of occurrence in the SMU. Thus soil-landscape relationships are not considered in the current version of DSMART. Expert rules on soil distribution considering the relief, parent material and wetlands location were proposed to drive the procedure of allocation of soil type to sampled positions, in order to integrate the soil-landscape relationships. Semantic information about spatial organization of soil types within SMU and exhaustive landscape descriptors were used. In the eastern part of Brittany (NW France), 171 soil types were described; their relative area in the SMU were estimated, geomorphological and geological contexts were recorded. The model predicted 144 soil types. An external validation was performed by comparing predicted

  13. Derivation of guidelines for uranium residual radioactive material in soil at the New Brunswick Site, Middlesex County, New Jersey

    SciTech Connect

    Dunning, D.; Kamboj, S.; Nimmagadda, M.; Yu, C.

    1996-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the New Brunswick Site, located in Middlesex County, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program of the US Department of Energy (DOE). Residual radioactive material guidelines for individual radionuclides of concern and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the New Brunswick Site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation; RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines. The guidelines derived in this report are intended to apply to the remediation of these remaining residual radioactive materials at the site. The primary radionuclides of concern in these remaining materials are expected to be radium-226 and, to a lesser extent, natural uranium and thorium. The DOE has established generic cleanup guidelines for radium and thorium in soil; however, cleanup guidelines for other radionuclides must be derived on a site-specific basis.

  14. Rock types present in lunar highland soils

    NASA Technical Reports Server (NTRS)

    Reid, A. M.

    1974-01-01

    Several investigators have studied soils from the lunar highlands with the objective of recognizing the parent rocks that have contributed significant amounts of material to these soils. Comparing only major element data, and thus avoiding the problems induced by individual classifications, these data appear to converge on a relatively limited number of rock types. The highland soils are derived from a suite of highly feldspathic rocks comprising anorthositic gabbros (or norites), high alumina basalts, troctolites, and less abundant gabbroic (or noritic) anorthosites, anorthosites, and KREEP basalts.

  15. The Teaching Parents Program.

    ERIC Educational Resources Information Center

    Wallace, Gail R.

    The Teaching Parents Program at a center for moderately retarded students (5 to 13 years old) who may also be visually handicapped, multiply handicapped, or emotionally disturbed allows parents to learn principles of behavior modification, task analysis, and data collection while working with a child in the classroom. Materials used in the program…

  16. The Stress Corrosion Resistance and the Cryogenic Temperature Mechanical Behavior of 18-3 Mn (Nitronic 33) Stainless Steel Parent and Welded Material

    NASA Technical Reports Server (NTRS)

    Montano, J. W.

    1976-01-01

    The ambient and cryogenic temperature mechanical properties and the ambient temperature stress corrosion results of 18-3 Mn (Nitronic 33)stainless steel, longitudinal and transverse, as received and as welded (TIG) material specimens manufactured from 0.063 inch thick sheet material, were described. The tensile test results indicate an increase in ultimate tensile and yield strengths with decreasing temperature. The elongation remained fairly constant to -200 F, but below that temperature the elongation decreased to less than 6.0% at liquid hydrogen temperature. The notched tensile strength (NTS) for the parent metal increased with decreasing temperature to liquid nitrogen temperature. Below -320 F the NTS decreased rapidly. The notched/unnotched (N/U) tensile ratio of the parent material specimens remained above 0.9 from ambient to -200 F, and decreased to approximately 0.65 and 0.62, respectively, for the longitudinal and transverse directions at liquid hydrogen temperature. After 180 days of testing, only those specimens exposed to the salt spray indicated pitting and some degradation of mechanical properties.

  17. Protective barrier materials analysis: Fine soil site characterization: A research report for Westinghouse Hanford Company

    SciTech Connect

    Last, G.V.; Glennon, M.A.; Young, M.A.; Gee, G.W.

    1987-11-01

    We collected soil samples for the physical characterization of a potential fine-soil quarry site at the McGee Ranch, which is located approximately 1 km northwest of the Hanford Site's Yakima Barricade. Forty test borings were made using a hollow-stem auger. Field moisture content and grain-size distribution were determined. The samples were classified into one of 19 sediment classes based on their grain-size distributions. Maps and cross sections were constructed from both the field and laboratory data to delineate the distributions of the various sediment classes. Statistical evaluations were made to determine the variations within the fine-soil fraction of the various sediment classes. Volume estimates were then made of the amounts of soil meeting the preliminary grain-size criteria. The physical characterization of the fine soils sampled near the McGee Ranch site indicated that approximately 3.4 million cubic meters of soil met or exceeded the minimum grain-size criteria for the fine soils needed for the protective barriers program. 11 refs., 14 figs., 6 tabs.

  18. Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

    NASA Technical Reports Server (NTRS)

    Bishop, J. L.; Pieters, C. M.; Burns, R. G.; Edwards, J. O.; Mancinelli, R. L.; Froschl, H.

    1995-01-01

    Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water

  19. Parents as Partners in Career Education.

    ERIC Educational Resources Information Center

    Kucker, Marsha; Smith-Rockhold, Gloria; Bemis, Dodie; Wiese, Vickie

    This document is a compilation of materials on improving parent involvement in career education. Section 1 contains the following informative materials and exercises: a parent's guide to the career development alphabet, involvement continuum, self-assessment, influences on parents' career decisions, and parental influence exercises; and sample…

  20. Distribution and variation of arsenic in Wisconsin surface soils, with data on other trace elements

    USGS Publications Warehouse

    Stensvold, Krista A.

    2012-01-01

    Soils with sandy glacial outwash as a parent material have a lower median arsenic concentration (1.0 mg/kg) than soils forming in other parent materials (1.5 to 3.0 mg/kg). Soil texture and drainage category also influence median arsenic concentration. Finer grained soils have a higher observed range of concentrations. For loamy and loess-dominated soil groups, drainage category influences the median arsenic concentration and observed range of values, but a consistent relationship within the data is not apparent. Statistical analysis of the 16 other elements are presented in this report, but the relationships of concentrations to soil properties or geographic areas were not examined.

  1. Research on the degradation of tropical arable land soil: Part III. The distribution of Cd in western part of Hainan Island

    NASA Astrophysics Data System (ADS)

    Wang, Dengfeng; Wei, Zhiyuan; Qi, Zhiping

    Research on arable land soil Cadmium (Cd) distribution is basic to Cd contamination control, especially in tropical areas with lower soil pH. This study, taking west Hainan as study area, collected soil samples from different soil horizons and demonstrated the distribution of Cd content. Soil Cd mainly inherits from the parent materials and the concentration of soil Cd is below 6 μg kg-1. Generally, the content of Cd in Aa horizon is lower than the C horizon, but the higher variability of Aa horizon Cd concentration is more likely subject to outer source pollution. The soil parent material distribution is primary factor which may affect the spatial distribution of Cd in soil. The content of Cd is higher in the northern Andisol. In addition, the spatial analysis tool can be used to identify regions with significant different contents of elements in different horizons.

  2. Continental-scale patterns in soil geochemistry and mineralogy: results from two transects across the United States and Canada

    USGS Publications Warehouse

    Woodruff, L.G.; Cannon, W.F.; Eberl, D.D.; Smith, D.B.; Kilburn, J.E.; Horton, J.D.; Garrett, R.G.; Klassen, R.A.

    2009-01-01

    In 2004, the US Geological Survey (USGS) and the Geological Survey of Canada (GSC) initiated a pilot study that involved collection of more than 1500 soil samples from 221 sites along two continental transects across Canada and the United States. The pilot study was designed to test and refine protocols for a soil geochemical survey of North America. The two transects crossed a wide array of soil parent materials, soil ages, climatic conditions, landforms, land covers and land uses. Sample sites were selected randomly at approximately 40-km intervals from a population defined as all soils of the continent. At each site, soils representing 0 to 5 cm depth, and the O, A, and C horizons, if present, were collected and analyzed for their near-total content of over 40 major and trace elements. Soils from 0–5 cm depth were also collected for analysis of organic compounds. Results from the transects confirm that soil samples collected at a 40-km spacing reveal coherent, continental- to subcontinental-scale geochemical and mineralogical patterns that can be correlated to aspects of underlying soil parent material, soil age and climate influence. The geochemical data also demonstrate that at the continental-scale the dominance of any of these major factors that control soil geochemistry can change across the landscape. Along both transects, soil mineralogy and geochemistry change abruptly with changes in soil parent materials. However, the chemical influence of a soil’s parent material can be obscured by changing climatic conditions. For the transects, increasing precipitation from west to east and increasing temperature from north to south affect both soil mineralogy and geochemistry because of climate effects on soil weathering and leaching, and plant productivity. Regional anomalous metal concentrations can be linked to natural variations in soil parent materials, such as high Ni and Cr in soils developed on ultramafic rocks in California or high P in soils formed on

  3. The Effect of Equilibration Time and Tubing Material on Soil Gas Measurements

    EPA Science Inventory

    The collection of soil vapor samples representative of in-situ conditions presents challenges associated with the unavoidable disturbance of the subsurface and potential losses to the atmosphere. This article evaluates the effects of two variables that influence the concentration...

  4. Composition and Color of Martian Soil from Oxidation of Meteoritic Material

    NASA Technical Reports Server (NTRS)

    Yen, A. S.

    2001-01-01

    Aqueous weathering is not necessary for formation of the martian soils. The chemical composition and oxidation state of the surface fines can be attributed to meteoritic influx. Additional information is contained in the original extended abstract.

  5. Mass Transport within Soils

    SciTech Connect

    McKone, Thomas E.

    2009-03-01

    Contaminants in soil can impact human health and the environment through a complex web of interactions. Soils exist where the atmosphere, hydrosphere, geosphere, and biosphere converge. Soil is the thin outer zone of the earth's crust that supports rooted plants and is the product of climate and living organisms acting on rock. A true soil is a mixture of air, water, mineral, and organic components. The relative proportions of these components determine the value of the soil for agricultural and for other human uses. These proportions also determine, to a large extent, how a substance added to soil is transported and/or transformed within the soil (Spositio, 2004). In mass-balance models, soil compartments play a major role, functioning both as reservoirs and as the principal media for transport among air, vegetation, surface water, deeper soil, and ground water (Mackay, 2001). Quantifying the mass transport of chemicals within soil and between soil and atmosphere is important for understanding the role soil plays in controlling fate, transport, and exposure to multimedia pollutants. Soils are characteristically heterogeneous. A trench dug into soil typically reveals several horizontal layers having different colors and textures. As illustrated in Figure 1, these multiple layers are often divided into three major horizons: (1) the A horizon, which encompasses the root zone and contains a high concentration of organic matter; (2) the B horizon, which is unsaturated, lies below the roots of most plants, and contains a much lower organic carbon content; and (3) the C horizon, which is the unsaturated zone of weathered parent rock consisting of bedrock, alluvial material, glacial material, and/or soil of an earlier geological period. Below these three horizons lies the saturated zone - a zone that encompasses the area below ground surface in which all interconnected openings within the geologic media are completely filled with water. Similarly to the unsaturated zone

  6. A Male Perspective on Parenting and Non-Parenting.

    ERIC Educational Resources Information Center

    Levant, Ronald F.

    This paper presents a literature review and the author's views on the male role in parenting, including the choice not to parent. The traditional view of male parenting is reviewed, with an emphasis on the effects of the traditional paternal role on the development of children. The materials shift in focus to a broader consideration of the…

  7. Genesis of marine terrace soils, Barbados, West Indies: evidence from mineralogy and geochemistry

    USGS Publications Warehouse

    Muhs, D.R.; Crittenden, R.C.; Rosholt, J.N.; Bush, C.A.; Stewart, K.C.

    1987-01-01

    Well-developed, clay-rich soils dominated by interstratified kaolinite-smectite are found on the uplifted coral reef terraces on the island of Barbados. The reef limestone is unlikely to have been the soil parent material however, because it is 98% CaCO 3 and geomorphic evidence argues against the 20 m of reef solution required to produce the soils by this process. The mineralogy of the sand, silt, and clay fractions of the soils, and trace element geochemistry, suggest that aeolian materials carried on the trade winds from Africa, volcanic ash from the island of St. Vincent, and quartz from Tertiary bedrock on the island itself are the parent materials for the soils. -Authors

  8. Influence of soils on Landsat spectral signatures of corn

    NASA Technical Reports Server (NTRS)

    Dalsted, K. J.; Worcester, B. K.; Devries, M. E.

    1980-01-01

    Landsat data have been investigated extensively to determine crop types and acreage. However, confounding site factors have been found to reduce accuracy. Soils data in a small, contiguous area in southeast South Dakota were used to stratify Landsat data. A June 5 and July 29 CCT were used in a statistical analysis of corn training data. Significant soil parameters causing differences in study area soils were slope and parent material. Implication of the results is that, in this region, stratification of CCT data along parent material boundaries would improve corn classification accuracy. Research expanding on the interaction of soils and crops is both in progress and scheduled for additional studies in east central South Dakota.

  9. Mathematical modelling and optimization of synthetic textile dye removal using soil composites as highly competent liner material.

    PubMed

    Das, Papita; Banerjee, Priya; Mondal, Sandip

    2015-01-01

    Soil is widely used as adsorbent for removing toxic pollutants from their aqueous solutions due to its wide availability and cost efficiency. This study investigates the potential of soil and soil composites for removal of crystal violet (CV) dye from solution on a comparative scale. Optimisation of different process parameters was carried out using a novel approach of response surface methodology (RSM) and a central composite design (CCD) was used for determining the optimum experimental conditions, as well as the result of their interactions. Around 99.85 % removal of CV was obtained at initial pH 6.4, which further increased to 99.98 % on using soil and cement composite proving it to be the best admixture of those selected. The phenomenon was found to be represented best by the Langmuir isotherm at different temperatures. The process followed the pseudo-second-order kinetic model and was determined to be spontaneous chemisorption in nature. This adsorbent can hence be suggested as an appropriate liner material for the removal of CV dye. PMID:25138552

  10. Bacterial biodegradation of melamine-contaminated aged soil: influence of different pre-culture media or addition of activation material.

    PubMed

    Hatakeyama, Takashi; Takagi, Kazuhiro

    2016-08-01

    This study aimed to investigate the biodegrading potential of Arthrobacter sp. MCO, Arthrobacter sp. CSP, and Nocardioides sp. ATD6 in melamine-contaminated upland soil (melamine: approx. 10.5 mg/kg dry weight) after 30 days of incubation. The soil sample used in this study had undergone annual treatment of lime nitrogen, which included melamine; it was aged for more than 10 years in field. When R2A broth was used as the pre-culture medium, Arthrobacter sp. MCO could degrade 55 % of melamine after 30 days of incubation, but the other strains could hardly degrade melamine (approximately 25 %). The addition of trimethylglycine (betaine) in soil as an activation material enhanced the degradation rate of melamine by each strain; more than 50 % of melamine was degraded by all strains after 30 days of incubation. In particular, strain MCO could degrade 72 % of melamine. When the strains were pre-cultured in R2A broth containing melamine, the degradation rate of melamine in soil increased remarkably. The highest (72 %) melamine degradation rate was noted when strain MCO was used with betaine addition. PMID:27080407

  11. Breaking Bad News to Parents.

    ERIC Educational Resources Information Center

    Miller, Susan A.

    1996-01-01

    Discusses the difficulty of breaking bad news to parents, whether the news pertains to center policy or a child's behavior. Provides strategies for presenting news and for helping parents to overcome difficult situations, including gathering facts in advance, arranging an appropriate time, and having resource materials available for parents. (MOK)

  12. Water in the critical zone: soil, water and life from profile to planet

    NASA Astrophysics Data System (ADS)

    Kirkby, Mike

    2015-04-01

    of both soil and landscape. For example, the soil hydrological regime helps to contrast soils that accumulate more and less soluble constituents of the parent material.

  13. Immobilization of Cu, Pb and Zn in mine-contaminated soils using reactive materials.

    PubMed

    Navarro, Andrés; Cardellach, Esteve; Corbella, Mercé

    2011-02-28

    Immobilization processes were used to chemically stabilize soil contaminated with Cu, Pb and Zn from mine tailings and industrial impoundments. We examined the effectiveness of ordinary Portland cement (OPC), phosphoric acid and MgO at immobilizing Cu, Pb and Zn in soil contaminated by either mine tailings or industrial and mine wastes. The effectiveness was evaluated using column leaching experiments and geochemical modelling, in which we assessed possible mechanisms for metal immobilization using PHREEQC and Medusa numerical codes. Experimental results showed that Cu was mobilized in all the experiments, whereas Pb immobilization with H(3)PO(4) may have been related to the precipitation of chloropyromorphite. Thus, the Pb concentrations of leachates of pure mining and industrial contaminated soils (32-410 μg/l and 430-1000 μg/l, respectively) were reduced to 1-60 and 3-360 μg/l, respectively, in the phosphoric acid experiment. The mobilization of Pb at high alkaline conditions, when Pb(OH)(4)(-) is the most stable species, may be the main obstacle to the use of OPC and MgO in the immobilization of this metal. In the mining- and industry-contaminated soil, Zn was retained by OPC but removed by MgO. The experiments with OPC showed the Zn decrease in the leachates of mining soil from 226-1960 μg/l to 92-121 μg/l. In the industrial contaminated soil, the Zn decrease in the leachates was most elevated, showing >2500 μg/l in the leachates of contaminated soil and 76-173 μg/l in the OPC experiment. Finally, when H(3)PO(4) was added, Zn was mobilized. PMID:21190796

  14. Glass and Glass-Ceramic Materials from Simulated Composition of Lunar and Martian Soils: Selected Properties and Potential Applications

    NASA Technical Reports Server (NTRS)

    Ray, C. S.; Sen, S.; Reis, S. T.; Kim, C. W.

    2005-01-01

    In-situ resource processing and utilization on planetary bodies is an important and integral part of NASA's space exploration program. Within this scope and context, our general effort is primarily aimed at developing glass and glass-ceramic type materials using lunar and martian soils, and exploring various applications of these materials for planetary surface operations. Our preliminary work to date have demonstrated that glasses can be successfully prepared from melts of the simulated composition of both lunar and martian soils, and the melts have a viscosity-temperature window appropriate for drawing continuous glass fibers. The glasses are shown to have the potential for immobilizing certain types of nuclear wastes without deteriorating their chemical durability and thermal stability. This has a direct impact on successfully and economically disposing nuclear waste generated from a nuclear power plant on a planetary surface. In addition, these materials display characteristics that can be manipulated using appropriate processing protocols to develop glassy or glass-ceramic magnets. Also discussed in this presentation are other potential applications along with a few selected thermal, chemical, and structural properties as evaluated up to this time for these materials.

  15. Sampling Soil for Characterization and Site Description

    NASA Technical Reports Server (NTRS)

    Levine, Elissa

    1999-01-01

    The sampling scheme for soil characterization within the GLOBE program is uniquely different from the sampling methods of the other protocols. The strategy is based on an understanding of the 5 soil forming factors (parent material, climate, biota, topography, and time) at each study site, and how each of these interact to produce a soil profile with unique characteristics and unique input and control into the atmospheric, biological, and hydrological systems. Soil profile characteristics, as opposed to soil moisture and temperature, vegetative growth, and atmospheric and hydrologic conditions, change very slowly, depending on the parameter being measured, ranging from seasonally to many thousands of years. Thus, soil information, including profile description and lab analysis, is collected only one time for each profile at a site. These data serve two purposes: 1) to supplement existing spatial information about soil profile characteristics across the landscape at local, regional, and global scales, and 2) to provide specific information within a given area about the basic substrate to which elements within the other protocols are linked. Because of the intimate link between soil properties and these other environmental elements, the static soil properties at a given site are needed to accurately interpret and understand the continually changing dynamics of soil moisture and temperature, vegetation growth and phenology, atmospheric conditions, and chemistry and turbidity in surface waters. Both the spatial and specific soil information can be used for modeling purposes to assess and make predictions about global change.

  16. The disposal of a lime water treatment residue on soil and spoil material from a coalmine: a glasshouse investigation.

    PubMed

    Titshall, L W; Hughes, J C; Morris, C D; Zacharias, P J K

    2007-01-01

    Eragrostis tef (Zucc.), Cenchrus ciliaris L., and Digitaria eriantha Steud. were grown in a soil (Psammentic Haplustalf) and spoil material from a coalmine both treated with a lime water treatment residue (WTR) at rates of 0, 50, 100, 200, and 400 g kg(-1). The yield of the grasses, from the sum of the three harvests, and concentrations of B, Ca, Cu, K, Fe, Mg, Mn, N, Na, P, and Zn in foliage from the second harvest were determined. The yield of grasses grown in the soil decreased exponentially as WTR application increased. The yields of C. ciliaris, D. eriantha, and E. tef (in the 400 g kg(-1) WTR treated soil) decreased by 74.4, 78.7, and 59.8%, respectively, when compared with the control treatments. In the spoil, the yield of E. tef and D. eriantha decreased by 13.6% and and D. eriantha by 23.9%, while an increase was observed for C. ciliaris (45.4%), at the highest WTR application rate. No relationship existed between yield of E. tef and WTR application rate when grown in the spoil, while a weak negative linear relationship (p < 0.05) was found for D. eriantha and a positive linear relationship existed for C. ciliaris. Magnesium concentrations of the grasses were positively correlated to WTR application rate. Grasses grown in the soil had higher Na concentrations, while those grown in the spoil typically had higher B, N, and Zn concentrations. The decreases in yield were attributed to nutrient deficiencies (notably Zn), induced by high WTR application rates that led to high substrate pH. Disposal of high rates of WTR on the mine materials was not recommended. PMID:17332261

  17. Effect of 10 different TiO2 and ZrO2 (nano)materials on the soil invertebrate Enchytraeus crypticus.

    PubMed

    Gomes, Susana I L; Caputo, Gianvito; Pinna, Nicola; Scott-Fordsmand, Janeck J; Amorim, Mónica J B

    2015-10-01

    Nearly 80% of all the nano-powders produced worldwide are metal oxides, and among these materials titanium dioxide (TiO2 ) is one of the most produced. Titanium dioxide's toxicity is estimated as low to soil organisms, but some studies have shown that TiO2 nanoparticles can cause oxidative stress. Additionally, it is known that TiO2 is activated by ultraviolet (UV) radiation, which can promote photocatalytic generation of reactive oxygen species, which is seldom taken into account in toxicity testing. In the present study, the authors investigated the effects of different TiO2 and zirconium materials on the soil oligochaete Enchytraeus crypticus, using exposure via soil, water, and soil:water extracts, and studied the effects combined with UV radiation. The results showed that zirconium dioxide (bulk and nano) was not toxic, whereas zirconium tetrachloride reduced enchytraeid reproduction in soil (50% effect concentration = 502 mg/kg). The TiO2 materials were also not toxic via soil exposure or under UV radiation. However, pre-exposure to TiO2 and UV radiation via aqueous media caused a lower reproductive output post-exposure in clean soil (20-50% less but only observed at the lowest concentration tested, 1 mg/L); that is, the effect of TiO2 in water was potentiated by the UV radiation and measurable as a decrease in reproduction in soil media. PMID:26013659

  18. Underestimation of boreal soil carbon stocks by mathematical soil carbon models linked to soil nutrient status

    NASA Astrophysics Data System (ADS)

    Ťupek, Boris; Ortiz, Carina A.; Hashimoto, Shoji; Stendahl, Johan; Dahlgren, Jonas; Karltun, Erik; Lehtonen, Aleksi

    2016-08-01

    Inaccurate estimate of the largest terrestrial carbon pool, soil organic carbon (SOC) stock, is the major source of uncertainty in simulating feedback of climate warming on ecosystem-atmosphere carbon dioxide exchange by process-based ecosystem and soil carbon models. Although the models need to simplify complex environmental processes of soil carbon sequestration, in a large mosaic of environments a missing key driver could lead to a modeling bias in predictions of SOC stock change.We aimed to evaluate SOC stock estimates of process-based models (Yasso07, Q, and CENTURY soil sub-model v4) against a massive Swedish forest soil inventory data set (3230 samples) organized by a recursive partitioning method into distinct soil groups with underlying SOC stock development linked to physicochemical conditions.For two-thirds of measurements all models predicted accurate SOC stock levels regardless of the detail of input data, e.g., whether they ignored or included soil properties. However, in fertile sites with high N deposition, high cation exchange capacity, or moderately increased soil water content, Yasso07 and Q models underestimated SOC stocks. In comparison to Yasso07 and Q, accounting for the site-specific soil characteristics (e. g. clay content and topsoil mineral N) by CENTURY improved SOC stock estimates for sites with high clay content, but not for sites with high N deposition.Our analysis suggested that the soils with poorly predicted SOC stocks, as characterized by the high nutrient status and well-sorted parent material, indeed have had other predominant drivers of SOC stabilization lacking in the models, presumably the mycorrhizal organic uptake and organo-mineral stabilization processes. Our results imply that the role of soil nutrient status as regulator of organic matter mineralization has to be re-evaluated, since correct SOC stocks are decisive for predicting future SOC change and soil CO2 efflux.

  19. System for high throughput water extraction from soil material for stable isotope analysis of water

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A major limitation in the use of stable isotope of water in ecological studies is the time that is required to extract water from soil and plant samples. Using vacuum distillation the extraction time can be less than one hour per sample. Therefore, assembling a distillation system that can process m...

  20. Soil Organic Carbon Mapping by Geostatistics in Europe Scale

    NASA Astrophysics Data System (ADS)

    Aksoy, E.; Panagos, P.; Montanarella, L.

    2013-12-01

    Accuracy in assessing the distribution of soil organic carbon (SOC) is an important issue because SOC is an important soil component that plays key roles in the functions of both natural ecosystems and agricultural systems. The SOC content varies from place to place and it is strongly related with climate variables (temperature and rainfall), terrain features, soil texture, parent material, vegetation, land-use types, and human management (management and degradation) at different spatial scales. Geostatistical techniques allow for the prediction of soil properties using soil information and environmental covariates. In this study, assessment of SOC distribution has been predicted with Regression-Kriging method in Europe scale. In this prediction, combination of the soil samples which were collected from the LUCAS (European Land Use/Cover Area frame statistical Survey) & BioSoil Projects, with local soil data which were collected from six different CZOs in Europe and ten spatial predictors (slope, aspect, elevation, CTI, CORINE land-cover classification, parent material, texture, WRB soil classification, annual average temperature and precipitation) were used. Significant correlation between the covariates and the organic carbon dependent variable was found. Moreover, investigating the contribution of local dataset in watershed scale into regional dataset in European scale was an important challenge.

  1. Modelling Soil Profiles in their Landscape Context.

    NASA Astrophysics Data System (ADS)

    Kirkby, M. J.

    2015-12-01

    Through models, explores the relationships between the interacting drivers of soil profile evolution. Soil hydrology drives the partition of precipitation between overland flow, shallow subsurface flow and deeper percolation/ lateral flow. Critical parts of this interchange occurs close to the surface, within the zone of strong bioturbation, where inorganic composition is determined by the balance between erosion and weathering rates expressed in the chemical depletion ratio. The intensity of organic matter cycling may also limit the final composition of weathering products. Erosion rates are partly driven by the geomorphic environment, through gradient and hydrology, but also constrained by the degree of soil weathering, through particle size and mineralogy. Weathering rates are determined by water movement below the bioturbation zone and ionic diffusion from parent material, which control the rate of decline with soil depth. These interactions are explored through simple equilibrium and evolutionary models for the soil profile that are applicable across a wide range of geological and climatic environments.

  2. Geo-pedological control of soil organic carbon and nitrogen stocks at the landscape scale

    NASA Astrophysics Data System (ADS)

    Barré, Pierre; Durand, Hermine; Chenu, Claire; Meunier, Patrick; Montagne, David; Castel, Géraldine; Billiou, Daniel; Cécillon, Lauric

    2015-04-01

    Geo-pedology, here defined as soil type (or Reference Soil Group) and parent material, can have a major impact on ecosystem (vegetation and soil) functioning. Geo-pedology can therefore deeply influence soil organic matter (SOM) stock. Nonetheless, the effect of geo-pedology on soil organic C (SOC) and N stocks has seldom been investigated. Indeed, factors known to influence SOM stocks such as land use and climate frequently co-vary with geo-pedology, so that testing the influence on SOM stocks of the factor "geo-pedology" alone is challenging. In this work, we studied SOM stocks of forest and cropland soils in a small landscape (17 km²) of the Paris basin (AgroParisTech domain, Thiverval-Grignon, France). We collected soil samples (0-30 cm) in 50 forest and cropland plots, located in five geo-pedological contexts: Luvisols developed on loess deposit, Cambisols developed on hard limestone, Cambisols developed on shelly limestone, Cambisols developed on chalk and Cambisols developed on calcareous clay deposits. We then determined SOM stocks (organic C and total N) and SOM distribution across different particle size fractions (coarse sand, fine sand and silt-clay). As expected, SOC stocks were much higher in forests (~ 83 tC ha-1) than in cultivated soils (~ 49 tC ha-1). Interestingly, Cambisols had higher SOC stocks than Luvisols (69 vs 56 tC ha-1) and the difference between SOC stocks in forest and cultivated soils was much higher for Cambisols compared to Luvisols. Within Cambisols, parent material did not influence SOC stocks but the interaction between parent material and land use was significant, indicating that the effect of land use on SOC stocks was modulated by parent material. Similar trends were observed for soil N stocks. Conversely, soil type and parent material did not control SOM distribution in soil size fractions, while forest soils showed a higher distribution of SOC and N in the sand-size fraction than cropland soils. Overall, our study evidenced

  3. Trace element distribution and mobilization in Scottish soils with particular reference to cobalt, copper and molybdenum.

    PubMed

    Berrow, M L; Ure, A M

    1986-03-01

    Total and extractable trace element contents have been determined in about 1000 soil profiles representing the main soil series occurring throughout Scotland. The frequency distributions of a number of trace elements in these soils are described and some relationships between total and extractable contents discussed. The geological nature of the soil parent material, soil texture, organic matter content and environmental contamination are the principal factors controlling soil total contents. Soil drainage class, because of its effect on mineral weathering and soil oxidation-reduction conditions, has a major influence on soil extractable contents, availability to plants and crop uptake. Particular attention is paid to cobalt, copper and molybdenum because of their importance for animal health in Scotland. PMID:24213839

  4. A Multi-Wavelength Grain-by-Grain Survey of Lunar Soils in Search of Rare Materials

    NASA Astrophysics Data System (ADS)

    Crites, S.; Lucey, P. G.; Viti, T.

    2014-12-01

    The Moon is unique among terrestrial planets for its lack of an atmosphere and global tectonic or volcanic processes. These factors and its position in the inner solar system mean that it is a potential repository of meteoritic material from all of the terrestrial planets. The National Research Council's 2007 report on the Scientific Context for the Exploration of the Moon highlighted this unique possibility and defined the search for rare materials including those from the early Earth as a key goal for future lunar exploration. Armstrong et al. (2002) estimated that Earth material could be present at the 7 ppm level in surface lunar regolith and emphasized that since a single gram of lunar fines contains over 10 million particles, the search for terran material in lunar soils should begin with the current stock of lunar samples. Joy et al. (2012) demonstrated that mineral and lithologic relics of impactors can survive and be recognized in lunar samples, and recent work by Burchell et al. (2014) suggests that fossil fragments from Earth could survive the extreme shocks associated with transport to the Moon. Following the concept laid out by Armstrong et al. (2002), we are conducting a survey of lunar soil samples using microscopic hyperspectral imaging spectroscopy across visible, near-infrared, and thermal infrared wavelengths to conduct a search for rare particles, including those that could be sourced from the early Earth. Our system currently consists of three microscopic imaging spectrometers with ~30 micron spatial resolution, permitting resolved imaging of individual grains. Fields of view of at least 1 cm and scan rates near 1 mm/sec permit rapid processing of relatively large quantities of sample. Existing spectrometers cover the 0.5 to 2.5 micron region, permitting detection and characterization of the common iron-bearing lunar minerals olivine and pyroxene, and the 8-14 micron region, which permits detection of other, rarer minerals of interest such as

  5. Method for recovery of hydrocarbons form contaminated soil or refuse materials

    DOEpatents

    Ignasiak, Teresa; Turak, Ali A.; Pawlak, Wanda; Ignasiak, Boleslaw L.; Guerra, Carlos R.; Zwillenberg, Melvin L.

    1991-01-01

    A method is provided for separating an inert solid substantially inorganic fraction comprising sand or soil from a tarry or oily organic matter in a feedstock. The feedstock may be contaminated soil or tarry waste. The feedstock is combined with pulverized coal and water. The ratio (oil or tar to dry weight of coal) of about 1.0:10 to about 4.0:10 at a temperature in the range of 60.degree.-95.degree. C. The mixture is agitated, the coarse particles are removed, and up to about 0.10% by weight (based on weight of coal) of a frothing agent is added. The mixture is then subjected to flotation, and the froth is removed from the mixture.

  6. Methods using earthworms for the evaluation of potentially toxic materials in soils

    SciTech Connect

    Neuhauser, E.F.; Loehr, R.C.; Malecki, M.R.

    1982-01-01

    The purpose of this study was to investigate the feasibility of using earthworms to indicate effects of potentially toxic wastes when such wastes are intentionally or accidentally added to soils. Initial work with metals has shown that earthworms exhibit specific growth and reproductive responses. These responses are related to the concentration and solubility of the metal. Of the metals tested, cadmium was found to be the most toxic, followed by nickel, copper, zinc, and lead. The metal concentration in earthworm tissue and the background manure-metal mixture was measured, permitting the concentration factor to be computed. The concentration factor is the ratio of the metal in the worm tissue to that in the surrounding manure-metal mixture. These and other studies in our laboratory have demonstrated that the methods described in this paper may be used to predict the effect of land-applied or atmospherically deposited residues on the soil biota.

  7. Does the feedstock origin of pyrolyzed materials influence the leaching quality and quantity of dissolved organic carbon from soils?

    NASA Astrophysics Data System (ADS)

    Suddick, E.; Spencer, R. G.; Pereira, E. I.; Six, J. W.

    2011-12-01

    Soils play a major role in the global C cycle and can be both a source of C emissions to the atmosphere and also a C sink. In order to sequester vast quantities of C and increase soil C stocks, which may be used to partly offset greenhouse gas (GHG) emissions in the future, new technologies are needed. Recently, there has been an abundance of interest in the use of pyrolyzed biomass C, termed biochar, as an amendment to terrestrial ecosystems to provide a large and long term sink of C. However, the stability and permanence of this black C source in soil is still relatively unknown and the uncertainty surrounding its turnover time may have implications for both C sequestration and the fate and transport of dissolved organic C leached to nearby water resources. Biochar can be derived from a multitude of feed stocks (e.g. walnut shells, wood chippings, poultry litter) and under a variety of pyrolysis conditions (e.g. high temperature or low temperatures); each process and feed stock can yield very different materials that has many different physical (e.g. surface area) and chemical (e.g. CEC, C and N content) properties. Each feed stock and pyrolysis condition may consequently contribute to a distinct recalcitrance in soil. Therefore, we undertook a pot trial to evaluate the chemical characteristics of leachate from soils incubated with biochars derived from 15 different feed stocks. Using optical property parameters such as SUVA, chromophoric dissolved organic matter (CDOM) slope parameter and fluorescence characteristics, we were able to determine the C leaching potential of each feedstock. Preliminary data suggests that there are distinct variations in optical properties with feed stock origin, for example an algae digestate showed a lower absorbance at 350 nm (a350) (25.7 m-1) and a steeper spectral slope at 290-350 nm (S290-350 x10-3) (17.7 nm-1) indicative of the presence of lower molecular weight compounds compared to control treatment with a signature typical

  8. RCRA materials analysis by laser-induced breakdown spectroscopy: Detection limits in soils

    SciTech Connect

    Koskelo, A.; Cremers, D.A.

    1994-09-01

    The goal of the Technical Task Plan (TTP) that this report supports is research, development, testing and evaluation of a portable analyzer for RCRA and other metals. The instrumentation to be built will be used for field-screening of soils. Data quality is expected to be suitable for this purpose. The data presented in this report were acquired to demonstrate the detection limits for laser-induced breakdown spectroscopy (LIBS) of soils using instrument parameters suitable for fieldable instrumentation. The data are not expected to be the best achievable with the high pulse energies available in laboratory lasers. The report presents work to date on the detection limits for several elements in soils using LIBS. The elements targeted in the Technical Task Plan are antimony, arsenic, beryllium, cadmium, chromium, lead, selenium, and zirconium. Data for these elements are presented in this report. Also included are other data of interest to potential customers for the portable LIBS apparatus. These data are for barium, mercury, cesium and strontium. Data for uranium and thorium will be acquired during the tasks geared toward mixed waste characterization.

  9. Parenting Matters

    ERIC Educational Resources Information Center

    Bornstein, Marc H.

    2005-01-01

    Parenting is a subject about which people typically hold strong opinions, but about which too little solid information or considered reflection exists. And clearly critical questions about parenting abound. Moreover, the family generally, and parenting specifically, are today in a greater state of flux, question, and re-definition than perhaps…

  10. Derivation of guidelines for uranium residual radioactive material in soil at the Colonie Site, Colonie, New York

    SciTech Connect

    Dunning, D.

    1996-05-01

    Residual radioactive material guidelines for uranium in soil were derived for the Colonie site located in Colonie, New York. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the U.S. Department of Energy (DOE). The site became contaminated with radioactive material as a result of operations conducted by National Lead (NL) Industries from 1958 to 1984; these activities included brass foundry operations, electroplating of metal products, machining of various components using depleted uranium, and limited work with small amounts of enriched uranium and thorium. The Colonie site comprises the former NL Industries property, now designated the Colonie Interim Storage Site (CISS), and 56 vicinity properties contaminated by fallout from airborne emissions; 53 of the vicinity properties were previously remediated between 1984 and 1988. In 1984, DOE accepted ownership of the CISS property from NL Industries. Residual radioactive material guidelines for individual radionuclides and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the site should not exceed a dose of 30 mrem/yr following remedial action for the current use and likely future use scenarios or a dose of 100 mrem/yr for less likely future use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation; RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines.

  11. Assessment of some straw-derived materials for reducing the leaching potential of Metribuzin residues in the soil

    NASA Astrophysics Data System (ADS)

    Cara, Irina Gabriela; Trincă, Lucia Carmen; Trofin, Alina Elena; Cazacu, Ana; Ţopa, Denis; Peptu, Cătălina Anişoara; Jităreanu, Gerard

    2015-12-01

    Biomass (straw waste) can be used as raw to obtain materials for herbicide removal from wastewater. These by-products have some important advantages, being environmentally friendly, easily available, presenting low costs, and requiring little processing to increase their adsorptive capacity. In the present study, some materials derived from agricultural waste (wheat, corn and soybean straw) were investigated as potential adsorbents for metribuzin removal from aqueous solutions. The straw wastes were processed by grinding, mineralisation (850 °C) and KOH activation in order to improve their functional surface activity. The materials surface characteristics were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy and atomic force microscopy. The adsorbents capacity was evaluated using batch sorption tests and liquid chromatography coupled with mass spectrometry for herbicide determination. For adsorption isotherms, the equilibrium time considered was 3 h. The experimental adsorption data were modelled by Freundlich and Langmuir models. The activated straw and ash-derived materials from wheat, corn and soybean increased the adsorption capacity of metribuzin with an asymmetrical behaviour. Overall, our results sustain that activated ash-derived from straw and activated straw materials can be a valuable solution for reducing the leaching potential of metribuzin through soil.

  12. The Toxicological Geochemistry of Dusts, Soils, and Other Earth Materials: Insights From In Vitro Physiologically-based Geochemical Leach Tests

    NASA Astrophysics Data System (ADS)

    Plumlee, G. S.; Ziegler, T. L.; Lamothe, P.; Meeker, G. P.; Sutley, S.

    2003-12-01

    Exposure to mineral dusts, soils, and other earth materials results in chemical reactions between the materials and different body fluids that include, depending upon the exposure route, lung fluids, gastrointestinal fluids, and perspiration. In vitro physiologically-based geochemical leach tests provide useful insights into these chemical reactions and their potential toxicological implications. We have conducted such leach tests on a variety of earth materials, including asbestos, volcanic ash, dusts from dry lake beds, mine wastes, wastes left from the roasting of mercury ores, mineral processing wastes, coal dusts and coal fly ash, various soils, and complex dusts generated by the World Trade Center collapse. Size-fractionated samples of earth materials that have been well-characterized mineralogically and chemically are reacted at body temperature (37 C) for periods from 2 hours up to multiple days with various proportions of simulated lung, gastric, intestinal, and/or plasma-based fluids. Results indicate that different earth materials may have quite different solubility and dissolution behavior in vivo, depending upon a) the mineralogic makeup of the material, and b) the exposure route. For example, biodurable minerals such as asbestos and volcanic ash particles, whose health effects result because they dissolve very slowly in vivo, bleed off low levels of trace metals into the simulated lung fluids; these include metals such as Fe and Cr that are suspected by health scientists of contributing to the generation of reactive oxygen species and resulting DNA damage in vivo. In contrast, dry lake bed dusts and concrete-rich dusts are highly alkaline and bioreactive, and cause substantial pH increases and other chemical changes in the simulated body fluids. Many of the earth materials tested contain a variety of metals that can be quite soluble (bioaccessible), depending upon the material and the simulated body fluid composition. For example, due to their acidic

  13. Attenuation coefficients of soils and some building materials of Bangladesh in the energy range 276-1332 keV.

    PubMed

    Alam, M N; Miah, M M; Chowdhury, M I; Kamal, M; Ghose, S; Rahman, R

    2001-06-01

    The linear and mass attenuation coefficients of different types of soil, sand, building materials and heavy beach mineral samples from the Chittagong and Cox's Bazar area of Bangladesh were measured using a high-resolution HPGe detector and the gamma-ray energies 276.1, 302.8, 356.0, 383.8, 661.6 and 1173.2 and 1332.5 keV emitted from point sources of 133Ba, 137Cs and 60Co, respectively. The linear attenuation coefficients show a linear relationship with the corresponding densities of the samples studied. The variations of the mass attenuation coefficient with gamma-ray energy were exponential in nature. The measured mass attenuation coefficient values were compared with measurements made in other countries for similar kinds of materials. The values are in good agreement with each other in most cases. PMID:11300413

  14. Effects of polyacrylamide on soil erosion and nutrient losses from substrate material in steep rocky slope stabilization projects.

    PubMed

    Chen, Zhang; Chen, Wenlu; Li, Chengjun; Pu, Yanpin; Sun, Haifeng

    2016-06-01

    Erosion of denuded steep rocky slopes causes increasing losses of nitrogen and phosphorus, which is a severe problem in rocky slope protection. Thus, it is important to determine the appropriate materials that can reduce the erodibility and losses of nitrogen and phosphorus of the soil. In this paper, twenty-seven simulated rainfall events were carried out in a greenhouse, in which the substrate material was artificial soil; nine types of anionic polyacrylamide (PAM) were studied, which consisted of three molecular weight (6, 12, and 18 Mg mol(-1)) and three charge density (10, 20, and 30%) formulations in a 3 by 3 factorial design. The results showed that: (1) Polyacrylamide application reduced total nitrogen losses by 35.3% to 50.0% and total phosphorus losses by 34.9% to 48.0% relative to the control group. (2) The losses of total nitrogen and total phosphorus had significant correlation with the molecular weight. Besides, the losses of total phosphorus, particulate-bound phosphorus and inorganic nitrogen (NH4-N) were significantly correlated with their molecular weight and charge density. However, the losses of dissolved organic nitrogen, inorganic nitrogen (NO3-N), dissolved organic phosphorus, inorganic phosphorus (PO4-P) were non-significantly correlated with molecular weight and charge density. (3) Particulate-bound nitrogen and phosphorus were responsible for the losses of nitrogen and phosphorus during runoff events, where particulate-bound nitrogen made up 71.7% to 73.2% of total nitrogen losses, and particulate-bound phosphorus made up 82.3% to 85.2% of total phosphorus losses. (4) Polyacrylamide treatments increased water-stable aggregates content by 32.3% to 59.1%, total porosity by 11.3% to 49.0%, final infiltrative rate by 41.3% to 72.5%, and reduced soil erosion by 18.9% to 39.8% compared with the control group. Overall, the results of this study indicated that polyacrylamide application in the steep rocky slope stabilization projects could

  15. Parents Helping Parents: Mutual Parenting Network Handbook.

    ERIC Educational Resources Information Center

    Simkinson, Charles H.; Redmond, Robert F.

    Guidelines for mutual parenting are provided in this handbook. "Mutual parenting" means that everyone in the community shares the responsibility for the safety and well-being of the community's youngsters. Several topics are discussed in the 15 brief chapters of the handbook. Chapters 1 through 3 focus on the formation of a mutual parenting…

  16. Soil experiment

    NASA Technical Reports Server (NTRS)

    Hutcheson, Linton; Butler, Todd; Smith, Mike; Cline, Charles; Scruggs, Steve; Zakhia, Nadim

    1987-01-01

    An experimental procedure was devised to investigate the effects of the lunar environment on the physical properties of simulated lunar soil. The test equipment and materials used consisted of a vacuum chamber, direct shear tester, static penetrometer, and fine grained basalt as the simulant. The vacuum chamber provides a medium for applying the environmental conditions to the soil experiment with the exception of gravity. The shear strength parameters are determined by the direct shear test. Strength parameters and the resistance of soil penetration by static loading will be investigated by the use of a static cone penetrometer. In order to conduct a soil experiment without going to the moon, a suitable lunar simulant must be selected. This simulant must resemble lunar soil in both composition and particle size. The soil that most resembles actual lunar soil is basalt. The soil parameters, as determined by the testing apparatus, will be used as design criteria for lunar soil engagement equipment.

  17. Report: Potential environmental impact of exempt site materials - a case study of bituminous road planings and waste soils.

    PubMed

    Bark, Marjorie; Bland, Michael; Grimes, Sue

    2009-09-01

    The use of waste materials for ecological benefit, agricultural improvement or as part of construction works are often exempt from waste management control in order to maximize the reuse of material that would otherwise be disposed of to landfill. It is important, however, to determine whether there is potential for such waste to cause environmental harm in the context of the basis for granting exemptions under the relevant framework objective to ensure that waste is recovered or disposed of without risk to water, air, soil, plants or animals. The potential for environmental harm was investigated by leaching studies on two wastes commonly found at exempt sites: bituminous road planings and waste soils. For bituminous road planings, the organic components of the waste were identified by their solubility in organic solvents but these components would have low environmental impact in terms of bioavailability. Leaching studies of the heavy metals copper, lead and zinc, into the environment, under specific conditions and particularly those modelling acid rain and landfill leachate conditions showed that, except for copper, the amounts leached fell within Waste Acceptance Criteria compliance limits for defining waste as inert waste. The fact that the amount of copper leached was greater than the Waste Acceptance Criteria level suggests that either additional testing of wastes regarded as exempt should be carried out to ensure that they are in analytical compliance or that legislation should allow for the potential benefits of reuse to supersede deviations from analytical compliance. PMID:19423579

  18. Soil Mineralogy and Substrate Quality Effects on Microbial Priming

    NASA Astrophysics Data System (ADS)

    Finley, B. K.; Rasmussen, C.; Dijkstra, P.; Schwartz, E.; Mau, R. L.; Liu, X. J. A.; Hungate, B. A.

    2014-12-01

    Soil carbon (C) cycling can slow or accelerate in response to new C inputs from fresh organic matter. This change in native C mineralization, known as the "microbial priming effect," is difficult to predict because the underlying mechanisms of priming are still poorly understood. We hypothesized that soil mineral assemblage, specifically short-range-order (SRO) minerals, influences microbial responses to different quality C substrate inputs. To test this, we added 350 μg C g-1soil weekly of an artificial root exudates mixture primarily comprised of glucose, sucrose, lactate and fructose (a simple C source) or ground ponderosa pine litter (a complex C source) for six weeks to three soil types from similar ecosystems derived from different parent material. The soils, from andesite, basalt, and granite parent materials, had decreasing abundance in SRO minerals, respectively. We found that the simple C substrate induced 63 ±16.3% greater positive priming than the complex C across all soil types. The quantity of soil SRO materials was negatively correlated with soil respiration, but positively correlated with priming. The lowest SRO soil amended with litter primed the least (14 ± 11 μgCO2-C g-1), while the largest priming effect occurring in the highest SRO soil amended with simple substrate (246 ± 18 μgCO2-C g-1). Our results indicate that higher SRO mineral content could accelerate microorganisms' capacity to mineralize native soil organic carbon and respond more strongly to labile C inputs. However, while all treatments exhibited positive priming, the amount of C added over the six-week incubation was greater than total CO2 respired. This suggests that despite a relative stimulation of native C mineralization, these soils act as C sinks rather than sources in response to fresh organic matter inputs.

  19. Map Scale in the Context of Progress in Soil Geography

    NASA Astrophysics Data System (ADS)

    Miller, Bradley; Schaetzl, Randall

    2014-05-01

    In this presentation, we review historical soil maps from a geographical perspective, in contrast to the more traditional temporal perspective. Our geographical perspective is operationalized by comparing soil maps based on their scale and classification system. To analyze the connection between scale in historical soil maps and their associated classification systems, we place soil maps into three categories of cartographic scale. We then examine how categories of cartographic scale correspond to the selection of environmental soil predictors used to initially create the maps, as reflected by the maps' legend. Previous analyses of soil mapping from the temporal perspective have concluded that soil classification systems have co-evolved with gains in soil knowledge. We conclude that paradigm shifts in soil mapping and classification can be better explained by their correlation to historical improvements in scientific understanding, differences in purpose for mapping, and advancement in geographic technologies. We observe that, throughout history, small cartographic scale maps have tended to emphasize climate-vegetation zonation. Medium cartographic scale maps have put more emphasis on parent material as a variable to explain soil distributions. And finally, soil maps at large cartographic scales have relied more on topography as a predictive factor. Importantly, a key characteristic of modern soil classification systems is their multi-scale approach, which incorporates these phenomena scales within their classification hierarchies. Although most modern soil classification systems are based on soil properties, the soil map remains a model, the purpose of which is to predict the spatial distributions of those properties. Hence, multi-scale classification systems still tend to be organized, at least in part, by this observed spatial hierarchy. Although the hierarchy observed in this study is generally known in pedology today, it also represents a new view on the

  20. Soil erosion survey using remote sensing images

    NASA Astrophysics Data System (ADS)

    Jakab, Gergely; Kertész, Ádám; Madarász, Balázs; Pálinkás, Melinda; Tóth, Adrienn

    2016-04-01

    Soil erosion is one of the most effective soil degradation processes reducing crop production on arable fields significantly. It also leads to serious environmental hazards such as eutrophication, mud and flesh floods. Beyond the processes there is an urgent need to survey and descript the current degree of erosion of arable lands in order to provide adequate land use techniques and mitigate the harmful effects. Surveying soil erosion is a very time consuming process since soil loss and deposition take place next to each other resulting a rather diverse erosion pattern even within a plot. Remote sensing is a possible way to determine the degree of soil erosion without special efforts taken in the field. The application of images can provide high resolution erosion maps of almost any type of arable fields. The method is based on the identification of the origin of the surface soil layer, i.e. whether it represents an originally deeper laying horizon (e.g. B horizon), or the parent material. A case study was carried out on a Cambisol formed on loess parent material. The soil and the parent rock have various reflectance spectra in the visible range, so this strip was used for the investigations. For map creation "training sites" were used in ArcMap environment. The obtained results suggest that the method is highly effective and useful, however, other properties like moisture content and plant cover can limit automated application. In this case new training sites are needed. The study was supported by the National Research, Development and Innovation Office (NKFIH),), project Nr. 108755 and the support is gratefully acknowledged here. G. Jakab was supported by the János Bolyai Fellowship.

  1. Landscape development in the context of soil distribution in Jordan

    NASA Astrophysics Data System (ADS)

    Lucke, Bernhard

    2016-04-01

    Processes of landscape change can be assessed by studying the distribution of soil types and their connection to climate, the geology, and land use. In this context, even in areas where no virgin soils are available, paleosols pre-dating the introduction of agriculture can be utilized for estimating potential soil development without human impact. Soil distribution in Jordan follows closely the climate and topography: specific soil orders can be found within the dry and hot subtropical, subhumid-semiarid, semiarid-arid, and arid regions. The pattern of soil and paleosol distribution in Jordan points to an important role of the geology (bedrock and relief), and of climate in their formation, both locally such as in the vicinity of the ancient site of Abila, and regionally in the whole country. In contrast, the impact of land use appears relatively limited: overall erosion has been estimated not to exceed the expected geological rate, and Jordan is considered to be in the stable state of completed geologic erosion. This is further supported by strongly varying soil properties and archaeological material on agricultural fields, which suggests that overall erosion processes during historical periods were limited. The presence of a quite uniform 4 m thick loess cover around the site of Umm el-Jimal in north-east Jordan suggests that aeolian deposits are probably the by far dominating parent material of current soils in northern Jordan. In this context, an apparent division of some soil profiles into subsoil and topsoil could correspond to dominant in-situ soil formation out of bedrock weathering at the bottom, while the upper part of the profiles could correspond to aeolian dust as main parent material. A stone line or lithological discontinuity separating these two parts of the profile might refer to a major erosion event. If true, this could indicate that current soils in Jordan might represent a mixture of at least two phases of soil development with probably

  2. Efficiency of a Multi-Soil-Layering System on Wastewater Treatment Using Environment-Friendly Filter Materials

    PubMed Central

    Ho, Chia-Chun; Wang, Pei-Hao

    2015-01-01

    The multi-soil-layering (MSL) system primarily comprises two parts, specifically, the soil mixture layer (SML) and the permeable layer (PL). In Japan, zeolite is typically used as the permeable layer material. In the present study, zeolite was substituted with comparatively cheaper and more environmentally friendly materials, such as expanded clay aggregates, oyster shells, and already-used granular activated carbon collected from water purification plants. A series of indoor tests indicated that the suspended solid (SS) removal efficiency of granular activated carbon was between 76.2% and 94.6%; zeolite and expanded clay aggregates achieved similar efficiencies that were between 53.7% and 87.4%, and oyster shells presented the lowest efficiency that was between 29.8% and 61.8%. Further results show that the oyster shell system required an increase of wastewater retention time by 2 to 4 times that of the zeolite system to maintain similar chemical oxygen demand (COD) removal efficiency. Among the four MSL samples, the zeolite system and granular activated carbon system demonstrated a stable NH3-N removal performance at 92.3%–99.8%. The expanded clay aggregate system present lower removal performance because of its low adsorption capacity and excessively large pores, causing NO3−-N to be leached away under high hydraulic loading rate conditions. The total phosphorous (TP) removal efficiency of the MSL systems demonstrated no direct correlation with the permeable layer material. Therefore, all MSL samples achieved a TP efficiency of between 92.1% and 99.2%. PMID:25809517

  3. Efficiency of a multi-soil-layering system on wastewater treatment using environment-friendly filter materials.

    PubMed

    Ho, Chia-Chun; Wang, Pei-Hao

    2015-03-01

    The multi-soil-layering (MSL) system primarily comprises two parts, specifically, the soil mixture layer (SML) and the permeable layer (PL). In Japan, zeolite is typically used as the permeable layer material. In the present study, zeolite was substituted with comparatively cheaper and more environmentally friendly materials, such as expanded clay aggregates, oyster shells, and already-used granular activated carbon collected from water purification plants. A series of indoor tests indicated that the suspended solid (SS) removal efficiency of granular activated carbon was between 76.2% and 94.6%; zeolite and expanded clay aggregates achieved similar efficiencies that were between 53.7% and 87.4%, and oyster shells presented the lowest efficiency that was between 29.8% and 61.8%. Further results show that the oyster shell system required an increase of wastewater retention time by 2 to 4 times that of the zeolite system to maintain similar chemical oxygen demand (COD) removal efficiency. Among the four MSL samples, the zeolite system and granular activated carbon system demonstrated a stable NH3-N removal performance at 92.3%-99.8%. The expanded clay aggregate system present lower removal performance because of its low adsorption capacity and excessively large pores, causing NO3--N to be leached away under high hydraulic loading rate conditions. The total phosphorous (TP) removal efficiency of the MSL systems demonstrated no direct correlation with the permeable layer material. Therefore, all MSL samples achieved a TP efficiency of between 92.1% and 99.2%. PMID:25809517

  4. Survey and evaluation of contaminants in earthworms and in soils derived from dredged material at confined disposal facilities in the Great Lakes Region.

    PubMed

    Beyer, W N; Stafford, C

    1993-01-01

    Soils derived from dredged material were collected, together with earthworms from nine confined disposal facilities located in the Great Lakes Region. These samples were analyzed for 18 elements, 11 organochlorine pesticides, PCBs, and 24 polycyclic aromatic hydrocarbons. The concentrations detected in earthworms were evaluated in terms of their potential hazard to wildlife, which for the sake of the evaluation were assumed to prey entirely either on earthworms or on other soil invertebrates having similar concentrations. The soil concentrations (dry wt.) of the contaminants of greatest concern were <1.9 to 32 ppm Cd, <0.053 to 0.94 ppm Hg, 4.6 to 550 ppm Pb, and <0.1 to 1.0 ppm PCBs. The concentrations in earthworms (dry wt., ingested soil included) were as high as 91 ppm Cd, 1.6 ppm Hg, 200 ppm Pb, and 1.8 ppm PCBs. Based on laboratory toxicity studies of relatively sensitive species, and on concentration factors calculated from the earthworm and soil data, we estimated that lethal or serious sublethal effects on wildlife might be expected at concentrations of 10 ppm Cd, 3 ppm Hg, 670 ppm Pb, and 1.7 ppm PCBs in alkaline surface soils derived from dredged material. Concentrations of polycyclic aromatic hydrocarbons in earthworms were well below those in soil. PMID:24227260

  5. Survey and evaluation of contaminants in earthworms and in soils derived from dredged material at confined disposal facilities in the Great Lakes region

    USGS Publications Warehouse

    Beyer, W.N.; Stafford, C.

    1993-01-01

    Soils derived from dredged material were collected, together with earthworms from nine confined disposal facilities located in the Great Lakes Region. These samples were analyzed for 18 elements, 11 organochlorine pesticides, PCBs, and 24 polycyclic aromatic hydrocarbons. The concentrations detected in earthworms were evaluated in terms of their potential hazard to wildlife, which for the sake of the evaluation were assumed to prey entirely either on earthworms or on other soil invertebrates having similar concentrations. The soil concentrations (dry wt.) of the contaminants of greatest concern were < 1.9 to 32 ppm Cd, < 0.053 to 0.94 ppm Hg, 4.6 to 550 ppm Pb, and < 0.1 to 1.0 ppm PCBs. The concentrations in earthworms (dry wt., ingested soil included) were as high as 91 ppm Cd, 1.6 ppm Hg, 200 ppm Pb, and 1.8 ppm PCBs. Based on laboratory toxicity studies of relatively sensitive species, and on concentration factors calculated from the earthworm and soil data, we estimated that lethal or serious sublethal effects on wildlife might be expected at concentrations of 10 ppm Cd, 3 ppm Hg, 670 ppm Pb, and 1.7 ppm PCBs in alkaline surface soils derived from dredged material. Concentrations of polycyclic aromatic hydrocarbons in earthworms were well below those in soil.

  6. Aggregating available soil water holding capacity data for crop yield models

    NASA Technical Reports Server (NTRS)

    Seubert, C. E.; Daughtry, C. S. T.; Holt, D. A.; Baumgardner, M. F.

    1984-01-01

    The total amount of water available to plants that is held against gravity in a soil is usually estimated as the amount present at -0.03 MPa average water potential minus the amount present at -1.5 MPa water potential. This value, designated available water-holding capacity (AWHC), is a very important soil characteristic that is strongly and positively correlated to the inherent productivity of soils. In various applications, including assessing soil moisture status over large areas, it is necessary to group soil types or series as to their productivity. Current methods to classify AWHC of soils consider only total capacity of soil profiles and thus may group together soils which differ greatly in AWHC as a function of depth in the profile. A general approach for evaluating quantitatively the multidimensional nature of AWHC in soils is described. Data for 902 soil profiles, representing 184 soil series, in Indiana were obtained from the Soil Characterization Laboratory at Purdue University. The AWHC for each of ten 150-mm layers in each soil was established, based on soil texture and parent material. A multivariate clustering procedure was used to classify each soil profile into one of 4, 8, or 12 classes based upon ten-dimensional AWHC values. The optimum number of classes depends on the range of AWHC in the population of oil profiles analyzed and on the sensitivity of a crop to differences in distribution of water within the soil profile.

  7. Soil map of the Russian Arctic on a 1 : 1 M scale: Contents and compilation methods

    NASA Astrophysics Data System (ADS)

    Mikhailov, I. S.

    2016-04-01

    A new soil map of the Russian Arctic on a scale of 1 : 1 M shows the soil cover in the north of Eurasia and on the islands of the Arctic Ocean to the north of 68° N. This map has been developed in a geoinformation system in the vector format with the wide use of remote sensing data. The delineated soil polygons show dominant and accompanying soils and the structure of soil cover patterns with indication of soil associations and soil complexes, the character of parent materials, and the topographic conditions. The map of the soil-geographic zoning of the Russian Arctic developed on the basis of the soil map differs from its earlier analogues in a greater degree of detail. The soil map of the Russian Arctic on a scale of 1 : 1 M displays the most detailed information on the soil cover patterns and can be used for solving various problems related to the exploration and development of this territory. Soil names from the new classification system of Russian soils [10] have been introduced into the legend of the map. New soil information and the use of remote sensing data have made it possible to enlarge the number of soil polygons shown on the map and to correct their boundaries in comparison with previous soil maps of the Russian Arctic.

  8. Intrinsic W nucleosynthetic isotope variations in carbonaceous chondrites: Implications for W nucleosynthesis and nebular vs. parent body processing of presolar materials

    NASA Astrophysics Data System (ADS)

    Burkhardt, Christoph; Schönbächler, Maria

    2015-09-01

    The progressive dissolution of the carbonaceous chondrites Orgueil (CI1), Murchison (CM2) and Allende (CV3) with acids of increasing strength reveals correlated W isotope variations ranging from 3.5 ε182W and 6.5 ε183W in the initial leachate (acetic acid) to -60 ε182W and -40 ε183W in the leachate residue. The observed variations are readily explained by variable mixing of s-process depleted and s-process enriched components. One W s-process carrier is SiC, however, the observed anomaly patterns and mass-balance considerations require at least on additional s-process carrier, possibly a silicate or sulfide. The data reveal well-defined correlations, which provide a test for s-process nucleosynthesis models. The correlations demonstrate that current models need to be revised and highlight the need for more precise W isotope data of SiC grains. Furthermore the correlations provide a mean to disentangle nucleosynthetic and radiogenic contributions to 182W (ε182Wcorrected = ε182Wmeasured - (1.41 ± 0.05) × ε183Wmeasured; ε182Wcorrected = ε182Wmeasured - (-0.12 ± 0.06) × ε184Wmeasured), a prerequisite for the successful application of the Hf-W chronometer to samples with nucleosynthetic anomalies. The overall magnitude of the W isotope variations decreases in the order CI1 > CM2 > CV3. This can be interpreted as the progressive thermal destruction of an initially homogeneous mixture of presolar grains by parent-body processing. However, not only the magnitude but also the W anomaly patterns of the three chondrites are different. In particular leach step 2, that employs nitric acid, reveals a s-deficit signature for Murchison, but a s-excess for Orgueil and Allende. This could be the result of redistribution of anomalous W into a new phase by parent-body alteration, or, the fingerprint of dust processing in the solar nebula. Given that the thermal and aqueous alteration of Murchison is between the CI and CV3 chondrites, parent-body processing is probably

  9. MOELCULAR SIZE EXCLUSION BY SOIL ORGANIC MATERIALS ESTIMATED FROM THEIR SWELLING IN ORGANIC SOLVENTS

    EPA Science Inventory

    A published method previously developed to measure the swelling characteristics of pow dered coal samples has been adapted for swelling measurements on various peat, pollen, chain, and cellulose samples The swelling of these macromolecular materials is the volumetric manifestatio...

  10. Coal tar, material used in soil improvement for use in road engineering

    NASA Astrophysics Data System (ADS)

    Ochoa Díaz, R.; Montañez, A.; Cuentas, J.

    2016-02-01

    Coal tar is a by-product of coal distillation in the absence of oxygen to obtain metallurgical coke; its colour varies from dark coffee to black, slightly viscous and its density is greater than that of water. Taking into account the previous characteristics, this document presents a study of the feasibility of using coal tar for the improvement of physical properties, mechanics and dynamics of materials used in road engineering. In this way, the origin, characteristics, and properties of tar are first described. Next, its combination with which granular-based material is evaluated through the CBR test procedure to determine its resistance and to compare it with the non-stabilized material. Finally, the behaviour of the material when subjected to dead loads by means of resistant modules found with the NAT (Nottingham Asphalt Tester) is explored. As a result, the option of using coal tar as a stabilizer was identified due to its use under specific conditions.

  11. Suppression of Boride Formation in Transient Liquid Phase Bonding of Pairings of Parent Superalloy Materials with Different Compositions and Grain Structures and Resulting Mechanical Properties

    NASA Astrophysics Data System (ADS)

    Steuer, Susanne; Singer, Robert F.

    2014-07-01

    Two Ni-based superalloys, columnar grained Alloy 247 and single-crystal PWA1483, are joined by transient liquid phase bonding using an amorphous brazing foil containing boron as a melting point depressant. At lower brazing temperatures, two different morphologies of borides develop in both base materials: plate-like and globular ones. Their ratio to each other is temperature dependent. With very high brazing temperatures, the deleterious boride formation in Alloy 247 can be totally avoided, probably because the three-phase-field moves to higher alloying element contents. For the superalloy PWA1483, the formation of borides cannot be completely avoided at high brazing temperatures as incipient melting occurs. During subsequent solidification of these areas, Chinese-script-like borides precipitate. The mechanical properties (tensile tests at room and elevated temperatures and short-term creep rupture tests at elevated temperatures) for brazed samples without boride precipitation are very promising. Tensile strengths and creep times to 1 pct strain are comparable, respectively, higher than the ones of the weaker parent material for all tested temperatures and creep conditions (from 90 to 100 pct rsp. 175 to 250 pct).

  12. Physiochemical, site, and bidirectional reflectance factor characteristics of uniformly moist soils. [Brazil, Spain and the United States of America

    NASA Technical Reports Server (NTRS)

    Stoner, E. R.; Baumgardner, M. F. (Principal Investigator)

    1980-01-01

    The author has identified the following significant results. The bidirectional reflectance factor (0.5 micron to 2.3 micron wavelength interval) and physiochemical properties of over 500 soils from 39 states, Brazil and Spain were measured. Site characteristics of soil temperature regime and moisture zone were used as selection criteria. Parent material and internal drainage were noted for each soil. At least five general types of soil reflectance curves were identified based primarily on the presence or absence of ferric iron absorption bands, organic matter content, and soil drainage characteristics. Reflectance in 10 bands across the spectrum was found to be negatively correlated with the natural log of organic matter content.

  13. Analysis of remotely sensed data for detecting soil limitations

    NASA Technical Reports Server (NTRS)

    Benson, L. A.; Frazee, C. J.; Waltz, F. A.

    1973-01-01

    During 1971 and 1972 a detailed study was conducted on a fallow field in the proposed Oahe Irrigation Project to determine the relationship between the tonal variation observed on aerial photographs and the properties of eroded soil. Correlation and regression analysis of digitized, multiemulsion, color infrared film (2443) data and detailed field data revealed a highly significant correlation between film transmittance and several soil properties indicative of the erosion limitation. Computer classification of the multiemulsion film data resulted in maps portraying the eroded soil and the normal soil. Both correlation and computer classification results were best using the reflectance data from the red spectral band. The results showed film transmittance was actually measuring the reflectivity of the soil surface which was increased by the incorporation of the light colored, calcareous parent material exposed by erosion or tillage on soils with thin surface horizons.

  14. Major soil element (Ca, Mg, K, Na, Al, Fe) distribution along the Qinghai-Tibet Railway

    NASA Astrophysics Data System (ADS)

    Wang, Z.; Zhang, Y.; Zhang, H.; Ding, M.; Lin, X.

    2011-12-01

    The Tibetan Plateau (TP), which has been called the third polar region, is the highest plateau in the world. There are a series of special soils present in the TP, which are extremely important in soil sciences for their particularities. Soil chemical composition is one of the necessary indices of soil characteristics. The major element content of the soil, such as Ca, Mg, K, Na, not only can affect the soil pH value and soil fertility but also are the main drivers of soil geochemical processes. It is helpful to understand the TP environmental characteristics, to study the major soil element content.The Qinghai-Tibet Railway (QTR) is the highest-elevation and the longest highland railway on earth. There are nearly all types of TP soil along the QTR. Most of the areas along the QTR are in fairly pristine condition. This offers a good platform to study the natural environmental characteristics of the soil. This study selected 240 soil samples from 28 sample areas along the Qinghai-Tibet Railway, and the aluminum, iron, calcium, sodium, potassium and magnesium content in the soil were measured with ICP-AES. The results indicated: (1) Compared with the national soil background values, the Ca content in soil was higher along the QTR and Al was lower; but the Fe, Mg, K and Na contents were similar. (2) Along the whole QTR, the soil Al, Fe and Mg content showed a decreasing trend from Xining to Lhasa, the changes in K and Na values were relatively complex, and the distribution of Ca could be divided three sections. (3) The soil element contents varied with different soil types and parent materials. Most of the six elements content was minimum in soil, which derived from debris materials for ice and water, and the elements content was maximum in soil, which evolved from debris for flood, and the content of soil Ca developed from debris for lake was maximum. The amount of each element present in the Hapli-Cryic Aridosols and Calci-Cryic Aridosols was relatively higher than

  15. Remediation of metal-contaminated soils with the addition of materials--part I: characterization and viability studies for the selection of non-hazardous waste materials and silicates.

    PubMed

    González-Núñez, R; Alba, M D; Orta, M M; Vidal, M; Rigol, A

    2011-11-01

    Contamination episodes in soils require interventions to attenuate their impact. These actions are often based on the addition of materials to increase contaminant retention in the soil and to dilute the contaminant concentration. Here, non-hazardous wastes (such as sugar foam, fly ash and a material produced by the zeolitization of fly ash) and silicates (including bentonites) were tested and fully characterized in the laboratory to select suitable materials for remediating metal-contaminated soils. Data from X-ray fluorescence (XRF), N(2) adsorption/desorption isotherms, X-ray diffraction (XRD) and scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM-EDX) analyses revealed the chemical composition, specific surface area and the phases appearing in the materials. A pH titration test allowed the calculation of their acid neutralization capacity (ANC). The metal sorption and desorption capacities of the waste materials and silicates were also estimated. Sugar foam, fly ash and the zeolitic material were the best candidate materials. Sugar foam was selected because of its high ANC (17000 meq kg(-1)), and the others were selected because of their larger distribution coefficients and lower sorption reversibilities than those predicted in the contaminated soils. PMID:22018740

  16. Derivation of guidelines for uranium residual radioactive material in soil at the former Baker Brothers, Inc., Site, Toledo, Ohio

    SciTech Connect

    Nimmagadda, M.; Kamboj, S.; Yu, C.

    1995-04-01

    Residual radioactive material guidelines for uranium in soil were derived for the former Baker Brothers, Inc., site in Toledo, Ohio. This site has been identified for remedial action under the U.S. Department of Energy`s (DOE`s) Formerly Utilized Sites Remedial Action Program (FUSRAP). Single-nuclide and total-uranium guidelines were derived on the basis of the requirement that following remedial action, the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the site should not exceed a dose constraint of 30 mrem/yr for the current use and likely future use scenarios or a dose limit of 100 mrem/yr for less likely future use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation; RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines. Three scenarios were considered; each assumed that for a period of 1,000 years following remedial action, the site would be used without radiological restrictions. The three scenarios varied with regard to the type of site use, time spent at the site by the exposed individual, and sources of food and water consumed. The evaluation indicates that the dose constraint of 30 mrem/yr would not be exceeded for uranium (including uranium-234, uranium-235, and uranium-238) within 1,000 years, provided that the soil concentration of total combined uranium (uranium-234, uranium-235, and uranium-238) at the former Baker Brothers site did not exceed 710 pCi/g for Scenario A (industrial worker, current use) or 210 pCi/g for Scenario B (resident - municipal water supply, a likely future use). The dose limit of 100 mrem/yr would not be exceeded at the site if the total uranium concentration of the soil did not exceed 500 pCi/g for Scenario C (subsistence farmer - on-site well water, a plausible but unlikely future use).

  17. Derivation of guidelines for uranium residual radioactive material in soil at the B&T Metals Company site, Columbus, Ohio

    SciTech Connect

    Kamboj, S.; Nimmagadda, Mm.; Yu, C

    1996-01-01

    Guidelines for uranium residual radioactive material in soil were derived for the B&T Metals Company site in Columbus, Ohio. This site has been identified for remedial action under the US Department of Energy`s (DOE`s) Formerly Utilized Sites Remedial Action Program (FUSRAP). Single-nuclide and total-uranium guidelines were derived on the basis of the requirement that following remedial action, the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the site should not exceed a dose constraint of 30 mrem/yr for the current use and likely future use scenarios or a dose limit of 100 n-mrem/yr for less likely future use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation. RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines. Three scenarios were considered; each assumed that for a period of 1,000 years following remedial action, the site would be used without radiological restrictions. The three scenarios varied with regard to the type of site use, time spent at the site by the exposed individual, and sources of food and water consumed. The evaluations indicate that the dose constraint of 30 mrem/yr would not be exceeded for uranium (including uranium-234, uranium-235, and uranium-238) within 1,000 years, provided that the soil concentration of total uranium (uranium-234, uranium-235, and uranium-238) at the B&T Metals site did not exceed 1, I 00 pCi/g for Scenario A (industrial worker, current use) or 300 pCi/g for Scenario B (resident with municipal water supply, a likely future use). The dose limit of 100 mrem/yr would not be exceeded at the site if the total uranium concentration of the soil did not exceed 880 pCi/g for Scenario C (resident with an on-site water well, a plausible but unlikely future use).

  18. Soil magnetic susceptibility: A quantitative proxy of soil drainage for use in ecological restoration

    USGS Publications Warehouse

    Grimley, D.A.; Wang, J.-S.; Liebert, D.A.; Dawson, J.O.

    2008-01-01

    Flooded, saturated, or poorly drained soils are commonly anaerobic, leading to microbially induced magnetite/maghemite dissolution and decreased soil magnetic susceptibility (MS). Thus, MS is considerably higher in well-drained soils (MS typically 40-80 ?? 10-5 standard international [SI]) compared to poorly drained soils (MS typically 10-25 ?? 10-5 SI) in Illinois, other soil-forming factors being equal. Following calibration to standard soil probings, MS values can be used to rapidly and precisely delineate hydric from nonhydric soils in areas with relatively uniform parent material. Furthermore, soil MS has a moderate to strong association with individual tree species' distribution across soil moisture regimes, correlating inversely with independently reported rankings of a tree species' flood tolerance. Soil MS mapping can thus provide a simple, rapid, and quantitative means for precisely guiding reforestation with respect to plant species' adaptations to soil drainage classes. For instance, in native woodlands of east-central Illinois, Quercus alba , Prunus serotina, and Liriodendron tulipifera predominantly occur in moderately well-drained soils (MS 40-60 ?? 10-5 SI), whereas Acer saccharinum, Carya laciniosa, and Fraxinus pennsylvanica predominantly occur in poorly drained soils (MS <20 ?? 10-5 SI). Using a similar method, an MS contour map was used to guide restoration of mesic, wet mesic, and wet prairie species to pre-settlement distributions at Meadowbrook Park (Urbana, IL, U.S.A.). Through use of soil MS maps calibrated to soil drainage class and native vegetation occurrence, restoration efforts can be conducted more successfully and species distributions more accurately reconstructed at the microecosystem level. ?? 2008 Society for Ecological Restoration International.

  19. Temperature response of litter and soil organic matter decomposition is determined by chemical composition of organic material.

    PubMed

    Erhagen, Björn; Öquist, Mats; Sparrman, Tobias; Haei, Mahsa; Ilstedt, Ulrik; Hedenström, Mattias; Schleucher, Jürgen; Nilsson, Mats B

    2013-12-01

    The global soil carbon pool is approximately three times larger than the contemporary atmospheric pool, therefore even minor changes to its integrity may have major implications for atmospheric CO2 concentrations. While theory predicts that the chemical composition of organic matter should constitute a master control on the temperature response of its decomposition, this relationship has not yet been fully demonstrated. We used laboratory incubations of forest soil organic matter (SOM) and fresh litter material together with NMR spectroscopy to make this connection between organic chemical composition and temperature sensitivity of decomposition. Temperature response of decomposition in both fresh litter and SOM was directly related to the chemical composition of the constituent organic matter, explaining 90% and 70% of the variance in Q10 in litter and SOM, respectively. The Q10 of litter decreased with increasing proportions of aromatic and O-aromatic compounds, and increased with increased contents of alkyl- and O-alkyl carbons. In contrast, in SOM, decomposition was affected only by carbonyl compounds. To reveal why a certain group of organic chemical compounds affected the temperature sensitivity of organic matter decomposition in litter and SOM, a more detailed characterization of the (13) C aromatic region using Heteronuclear Single Quantum Coherence (HSQC) was conducted. The results revealed considerable differences in the aromatic region between litter and SOM. This suggests that the correlation between chemical composition of organic matter and the temperature response of decomposition differed between litter and SOM. The temperature response of soil decomposition processes can thus be described by the chemical composition of its constituent organic matter, this paves the way for improved ecosystem modeling of biosphere feedbacks under a changing climate. PMID:23907960

  20. Development of a standard reference material for Cr(vi) in contaminated soil

    USGS Publications Warehouse

    Nagourney, S.J.; Wilson, S.A.; Buckley, B.; Kingston, H.M.S.; Yang, S.-Y.; Long, S.E.

    2008-01-01

    Over the last several decades, considerable contamination by hexavalent chromium has resulted from the land disposal of Chromite Ore Processing Residue (COPR). COPR contains a number of hexavalent chromium-bearing compounds that were produced in high temperature industrial processes. Concern over the carcinogenic potential of this chromium species, and its environmental mobility, has resulted in efforts to remediate these waste sites. To provide support to analytical measurements of hexavalent chromium, a candidate National Institute of Standards and Technology (NIST) Standard Reference Material?? (SRM 2701), having a hexavalent chromium content of approximately 500 mg kg -1, has been developed using material collected from a waste site in Hudson County, New Jersey, USA. The collection, processing, preparation and preliminary physico-chemical characterization of the material are discussed. A two-phase multi-laboratory testing study was carried out to provide data on material homogeneity and to assess the stability of the material over the duration of the study. The study was designed to incorporate several United States Environmental Protection Agency (USEPA) determinative methods for hexavalent chromium, including Method 6800 which is based on speciated isotope dilution mass spectrometry (SIDMS), an approach which can account for chromium species inter-conversion during the extraction and measurement sequence. This journal is ?? The Royal Society of Chemistry 2008.

  1. The informativeness of coefficients a and b of the soil line for the analysis of remote sensing materials

    NASA Astrophysics Data System (ADS)

    Rukhovich, D. I.; Rukhovich, A. D.; Rukhovich, D. D.; Simakova, M. S.; Kulyanitsa, A. L.; Bryzzhev, A. V.; Koroleva, P. V.

    2016-08-01

    The coefficients of the soil line are often taken into account in calculations of vegetation indices. These coefficients are usually calculated for the entire satellite image, or are taken as constants without any calculations. In both cases, the informativeness of these coefficients is low and insufficient for the needs of soil mapping. In our study, we calculated soil line coefficients at 8000 lattice points for the territory of Plavsk, Arsen'evsk, and Chern districts of Tula oblast on the basis of 34 Landsat 5, 7, and 8 images obtained in 1985-2014. In order to distinguish between the soil line calculated for a given image and the soil line calculated for lattice points on the basis of dozens of multitemporal images, we suggest that the latter can be referred to as the temporal soil line. The temporal soil line is described by a classical equation: NIR = RED a + b, where a is its slope relative to the horizontal axis (RED), and b is the Y-axis (NIR) intercept. Both coefficients were used to create soil maps. The verification of the maps was performed with the use of data on 1985 soil pits. The informativeness of these coefficients appeared to be sufficient for delineation of eight groups of soils of different taxonomic levels: soddy moderately podzolic soils, soddy slightly podzolic soils, soddy-podzolic soils, light gray forest soils, gray forest soils, dark gray forest soils, podzolized chernozems, and leached chernozems. The b coefficient proved to be more informative, as it allowed us to create the soil map precisely on its basis. In order to create the soil map on the basis of the a coefficient, we had to apply some threshold values of the b coefficient. The bare soil on each of Landsat scenes was separated with the help of the mask of agricultural fields and the notion of the spectral neighborhood of soil line (SNSL).

  2. Chemical characterization of iron-mediated soil organic matter stabilization in tropical subsoils

    NASA Astrophysics Data System (ADS)

    Coward, E.; Plante, A. F.; Thompson, A.

    2015-12-01

    Tropical forest soils contribute disproportionately to the poorly-characterized and persistent deep soil carbon (C) pool. Highly-weathered and often extending one to two meters deep, these soils also contain an abundance of semicrystalline, Fe- and Al-containing short-range-order (SRO) minerals, metastable derivatives of framework silicate and ferromagnesian parent materials. SRO minerals are capable of soil organic matter (SOM) stabilization through sorption or co-precipitation, a faculty enhanced by their high specific surface area (SSA). As such, SRO-mediated organomineral associations may prove a critical, yet matrix-selective, driver of SOM stabilization capacity in tropical soils, particularly at depth. Surface (0-20 cm) and subsoil (50-80 cm) samples were taken from 20 quantitative soil pits dug in the Luquillo Critical Zone Observatory, located in northeast Puerto Rico. Soils were stratified across granodiorite and volcaniclastic parent materials, spanning primary mineral contents of 5 to 40%. Selective dissolution procedures were used to isolate distinct forms of Fe-C interactions: (1) sodium pyrophosphate to isolate organo-mineral complexes, (2) hydroxylamine and (3) oxalate to isolate SRO phases, and (4) inorganic dithionite to isolate crystalline Fe oxides. Extracts were analysed for dissolved organic C (DOC) and Fe and Al concentrations to estimate SOM associated with each mineral phase. Soils were also subjected to SSA analysis, 57Fe-Mössbauer spectroscopy and X-ray diffraction before and after extraction to determine the contribution of extracted mineral phases to SOM stabilization capacity. Preliminary results indicate a dominance of secondary (hydr)oxides and kaolin minerals in surface soils, strongly driven by parent material. With depth, however, we observe a marked shift towards SRO mineral phases across both parent materials, suggesting that SRO-mediated organomineral associations are significant contributors to observed C storage in tropical

  3. Sulfate reduction in sulfuric material after re-flooding: Effectiveness of organic carbon addition and pH increase depends on soil properties.

    PubMed

    Yuan, Chaolei; Fitzpatrick, Rob; Mosley, Luke M; Marschner, Petra

    2015-11-15

    Sulfuric material is formed upon oxidation of sulfidic material; it is extremely acidic, and therefore, an environmental hazard. One option for increasing pH of sulfuric material may be stimulation of bacterial sulfate reduction. We investigated the effects of organic carbon addition and pH increase on sulfate reduction after re-flooding in ten sulfuric materials with four treatments: control, pH increase to 5.5 (+pH), organic carbon addition with 2% w/w finely ground wheat straw (+C), and organic carbon addition and pH increase (+C+pH). After 36 weeks, in five of the ten soils, only treatment +C+pH significantly increased the concentration of reduced inorganic sulfur (RIS) compared to the control and increased the soil pore water pH compared to treatment+pH. In four other soils, pH increase or/and organic carbon addition had no significant effect on RIS concentration compared to the control. The RIS concentration in treatment +C+pH as percentage of the control was negatively correlated with soil clay content and initial nitrate concentration. The results suggest that organic carbon addition and pH increase can stimulate sulfate reduction after re-flooding, but the effectiveness of this treatment depends on soil properties. PMID:26024614

  4. Summary of hydrologic and physical properties of rock and soil materials, as analyzed by the hydrologic laboratory of the U.S. Geological Survey, 1948-60

    USGS Publications Warehouse

    Morris, D.A.; Johnson, A.I.

    1967-01-01

    The Hydrologic Laboratory was established in 1948 to serve as the central testing laboratory for the Water Resources Division of the U.S. Geological Survey. Since then, thousands of samples of rock and soil materials have been analyzed in the laboratory. Analytical data on samples from 42 States and for the period 1948-60 are summarized in this report. The data are presented in a form that allows easy comparison of the physical and hydrologic properties of many sedimentary, igneous, and metamorphic rock and soil materials. Sedimentary rocks--the principal water-bearing rocks analyzed--are discussed in detail.

  5. Soil Chemistry Still Affected 23 Years After Large Application of Fluidized Bed Material

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This study was conducted to assess the movement of arsenic, aluminum, calcium, copper, iron, lead, magnesium, manganese, mercury and zinc in an old apple (Malus domestica Borkh) orchard that received a one time application of 36 kg/ m2 of fluidized bed combustion material (FBCM) 23 years earlier. S...

  6. Cr(VI) adsorption/desorption on untreated and mussel shell-treated soil materials: fractionation and effects of pH and chromium concentration

    NASA Astrophysics Data System (ADS)

    Otero, M.; Cutillas-Barreiro, L.; Nóvoa-Muñoz, J. C.; Arias-Estévez, M.; Fernández-Sanjurjo, M. J.; Álvarez-Rodríguez, E.; Núñez-Delgado, A.

    2014-12-01

    We used batch-type experiments to study Cr(VI) adsorption/desorption on granitic material, forest soil, pyritic material, mussel shell, and on forest soil and granitic material amended with 12 t ha-1 shell, considering the effects of varying Cr(VI) concentration and pH. Sequential extractions were carried out to fractionate adsorbed Cr(VI) and to determine the stability of Cr(VI) retention. The pyritic material had the highest Cr(VI) retention capacity, whereas the granitic material showed the lowest retention potential. When high Cr concentrations were added, some saturation of the adsorbent surfaces became apparent, but Cr release remained low. The highest Cr retention was achieved at very acid pH value, with release progressively increasing as a function of increasing pH. The amendment with 12 t ha-1 mussel shell did not cause marked changes in Cr(VI) retention. Adsorption data were satisfactory adjusted to the Freundlich model. Regarding Cr(VI) fractionation, the soluble fraction (weakly bound) was the dominant in mussel shell and in the un-amended and amended granitic material, whereas more stable fractions dominated in the pyritic material (residual fraction) and in the forest soil (oxidizable fraction). In conclusion, the pyritic material presented the highest Cr(VI) retention capacity, while the retention was low and weak on the granitic material; mussel shell was characterized by not marked Cr(VI) retention potential, and it did not cause remarkable increase in Cr(VI) retention when used to amend the granitic material or the forest soil.

  7. Cr(VI) sorption/desorption on untreated and mussel-shell-treated soil materials: fractionation and effects of pH and chromium concentration

    NASA Astrophysics Data System (ADS)

    Otero, M.; Cutillas-Barreiro, L.; Nóvoa-Muñoz, J. C.; Arias-Estévez, M.; Fernández-Sanjurjo, M. J.; Álvarez-Rodríguez, E.; Núñez-Delgado, A.

    2015-04-01

    We used batch-type experiments to study Cr(VI) sorption/desorption on granitic material, forest soil, pyritic material, mussel shell, and on forest soil and granitic material amended with 12 t ha-1 (1.2 kg m -2) shell, considering the effects of varying Cr(VI) concentration and pH. Sequential extractions were carried out to fractionate adsorbed Cr(VI) and to determine the stability of Cr(VI) retention. The pyritic material had the highest Cr(VI) retention capacity, whereas the granitic material showed the lowest retention potential. When high Cr concentrations were added, some saturation of the adsorbent surfaces became apparent, but Cr release remained low. The highest Cr retention was achieved at a very acid pH value, with release progressively increasing as a function of increasing pH. The amendment with 12 t ha-1 mussel shell did not cause marked changes in Cr(VI) retention. Sorption data were satisfactory adjusted to the Freundlich model. Regarding Cr(VI) fractionation, the soluble fraction (weakly bound) was dominant in mussel shell and in the unamended and amended granitic material, whereas more stable fractions dominated in the pyritic material (residual fraction) and in the forest soil (oxidizable fraction). In conclusion, the pyritic material presented the highest Cr(VI) retention capacity, while the retention was low and weak on the granitic material; mussel shell was not characterized by a marked Cr(VI) retention potential, and it did not cause remarkable increase in Cr(VI) retention when used to amend the granitic material or the forest soil.

  8. MICHIGAN SOIL VAPOR EXTRACTION REMEDIATION (MISER) MODEL: A COMPUTER PROGRAM TO MODEL SOIL VAPOR EXTRACTION AND BIOVENTING OF ORGANIC CHEMICALS IN UNSATURATED GEOLOGICAL MATERIAL

    EPA Science Inventory

    Soil vapor extraction (SVE) and bioventing (BV) are proven strategies for remediation of unsaturated zone soils. Mathematical models are powerful tools that can be used to integrate and quantify the interaction of physical, chemical, and biological processes occurring in field sc...

  9. Archaeological implications of time as a factor of soil formation

    SciTech Connect

    Holliday, V.T.

    1985-01-01

    Soils in sediments at archaeological sites have long been used as stratigraphic markers and often as indicators of local environments. However, because soil formation requires time, soils are also significant as age indicators; being so-used quite successfully in many studies of Quaternary stratigraphy and recently as part of investigations of archaeological geology on the Southern High Plains. Moreover, a soil or soils in a sedimentary sequence marks the passage of some amount of time between depositional episodes under conditions of landscape stability, whereas the sediments themselves (the parent material for the soil) may have accumulated quite rapidly. For example, at the Lubbock Lake site (Texas plains) and Wilson-Leonard site (central Texas) several thousands years of cultural history is compressed into zones several centimeters thick (buried surface horizons), but the parent materials of those soil are up to several meters thick and accumulated well within 1000 years. This situation probably obtains at many other sites and can profoundly influence interpretations of cultural chronology.

  10. Synthesis and Characterization of the Hybrid Clay- Based Material Montmorillonite-Melanoidin: A Potential Soil Model

    SciTech Connect

    V Vilas; B Matthiasch; J Huth; J Kratz; S Rubert de la Rosa; P Michel; T Schäfer

    2011-12-31

    The study of the interactions among metals, minerals, and humic substances is essential in understanding the migration of inorganic pollutants in the geosphere. A considerable amount of organic matter in the environment is associated with clay minerals. To understand the role of organic matter in the environment and its association with clay minerals, a hybrid clay-based material (HCM), montmorillonite (STx-1)-melanoidin, was prepared from L-tyrosine and L-glutamic acid by the Maillard reaction. The HCM was characterized by elemental analysis, nuclear magnetic resonance, x-ray photoelectron spectroscopy (XPS), scanning transmission x-ray microscopy (STXM), and thermal analysis. The presence of organic materials on the surface was confirmed by XPS and STXM. The STXM results showed the presence of organic spots on the surface of the STx-1 and the characterization of the functional groups present in those spots. Thermal analysis confirmed the existence of organic materials in the montmorillonite interlayer, indicating the formation of a composite of melanoidin and montmorillonite. The melanoidin appeared to be located partially between the layers of montmorillonite and partially at the surface, forming a structure that resembles the way a cork sits on the top of a champagne bottle.

  11. Valuing Parents

    ERIC Educational Resources Information Center

    Gerdes, Eugenia Proctor

    2004-01-01

    Recently, a young faculty member commented that e-mail and inexpensive long distance rates were hampering her first-year students' development by making it too easy for them to stay in touch with their parents. Similarly, Judith Shapiro, president of Barnard College, argued in her August 22, 2002, New York Times op-ed piece, "Keeping Parents Off…

  12. Leadership Parenting.

    ERIC Educational Resources Information Center

    Elkind, David

    1999-01-01

    Describes how three principles of leadership presented by Heifetz (1994) in "Leadership Without Easy Answers" can be translated into the leadership parenting of young children. Focuses on distinguishing between child-rearing issues that require parents to act as trainers versus those demanding a problem-solving role, on responding to children's…

  13. Parents' Role.

    ERIC Educational Resources Information Center

    Hall, George C.

    A psychologist discusses efforts at the Boston Center for Blind Children to help parents adjust to the demands of their multiply-handicapped, visually-impaired children. The following programs are found to be helpful: an infant home visiting program (see EC 062 470)in which parents develop their role through participating in an individualized…

  14. Parent Express.

    ERIC Educational Resources Information Center

    Kazanjian, Elise, Ed.

    1988-01-01

    Intended for use by parents of infants and toddlers, this series of 27 8-page month-by-month newsletters provides research-based information on infant and child development and care from 0 to 36 months. Topics in the series for infants include: becoming a parent; getting ready for child birth; the newborn child; and characteristics of the child at…

  15. Derivation of residual radioactive material guidelines for uranium in soil at the Middlesex Sampling Plant Site, Middlesex, New Jersey

    SciTech Connect

    Dunning, D.E.

    1995-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the Middlesex Sampling Plant (MSP) site in Middlesex, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the US Department of Energy. The site became contaminated from operations conducted in support of the Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC) between 1943 and 1967. Activities conducted at the site included sampling, storage, and shipment of uranium, thorium, and beryllium ores and residues. Uranium guidelines for single radioisotopes and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the MSP site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The RESRAD computer code, which implements the methodology described in the DOE manual for establishing residual radioactive material guidelines, was used in this evaluation. Four scenarios were considered for the site. These scenarios vary regarding future land use at the site, sources of water used, and sources of food consumed.

  16. Soil chemistry in lithologically diverse datasets: the quartz dilution effect

    USGS Publications Warehouse

    Bern, Carleton R.

    2009-01-01

    National- and continental-scale soil geochemical datasets are likely to move our understanding of broad soil geochemistry patterns forward significantly. Patterns of chemistry and mineralogy delineated from these datasets are strongly influenced by the composition of the soil parent material, which itself is largely a function of lithology and particle size sorting. Such controls present a challenge by obscuring subtler patterns arising from subsequent pedogenic processes. Here the effect of quartz concentration is examined in moist-climate soils from a pilot dataset of the North American Soil Geochemical Landscapes Project. Due to variable and high quartz contents (6.2–81.7 wt.%), and its residual and inert nature in soil, quartz is demonstrated to influence broad patterns in soil chemistry. A dilution effect is observed whereby concentrations of various elements are significantly and strongly negatively correlated with quartz. Quartz content drives artificial positive correlations between concentrations of some elements and obscures negative correlations between others. Unadjusted soil data show the highly mobile base cations Ca, Mg, and Na to be often strongly positively correlated with intermediately mobile Al or Fe, and generally uncorrelated with the relatively immobile high-field-strength elements (HFS) Ti and Nb. Both patterns are contrary to broad expectations for soils being weathered and leached. After transforming bulk soil chemistry to a quartz-free basis, the base cations are generally uncorrelated with Al and Fe, and negative correlations generally emerge with the HFS elements. Quartz-free element data may be a useful tool for elucidating patterns of weathering or parent-material chemistry in large soil datasets.

  17. Soils of the Galindez Island, Argentine archipelago, Western Antarctica

    NASA Astrophysics Data System (ADS)

    Abakumov, Evgeny; Parnikoza, Ivan

    2015-04-01

    Antarctic Peninsula is a part of Antarctica which is characterized by increased soil diversity, caused by specific of parent materials and diversity of non-vascular and vascular plants. Soils of Galindez Island have been investigated during the 18-th Ukranian Antarctic Expedition 2013/14. This Island situated in Argentine archipelago (coastal part of Antarctic Peninsula). Soils of Galindez Island presented by following types: Leptosols, Lithosols, Histic Lithosols and Leptosols and some Gleyic soils, located in lowlands and coastal parts. An average solum profile thickness is 3-19 cm which result from the small depth of debris's, underplayed by massive crystallic rocks. The permafrost layer is located within the massive rock, but not in coarse friable parent material. The soils with bird influence are widely spread both in coastal and central part of Island. In the coastal parts we can find typical Ornithosols in the penguin rockeries areas. The main aim of our investigation was characterization of soils formed under vegetation, exactly under Deschampsia antarctica Desv. localities. Argentine Islands is the central part of D. antarctica spreading area in region of Antarctic peninsula. Probably, these islands colonized by hairgrass mainly due to ornitogenic activity. So, coastal population appearance related with Larus dominicanus nest areas and feeding activity. Thus, we found typical post ornithogenic soils here. This kind of soils we also observed in population of hairgrass of Galindez mainland where it was connected with the other Antarctic bird - Catharacta maccormicki activity. Thus, the soil diversity and soil geochemistry of the Galindez Island are closely related to the activity of birds. The spatial pattern of soils, their chemistry and organic matter quality is discussed in relation with distribution of bird nesting and feeding activity.

  18. Titanium Mass-balance Analysis of Paso Robles Soils: Elemental Gains and Losses as Affected by Acid Alteration Fluids

    NASA Technical Reports Server (NTRS)

    Sutter, Brad; Ming, Douglas W.

    2010-01-01

    The Columbia Hills soils have been exposed to aqueous alteration in alkaline [1] as well as acid conditions [2,3]. The Paso Robles class soils are bright soils that possess the highest S concentration of any soil measured on Mars [2]. Ferric-sulfate detection by Moessbauer analysis indicated that acid solutions were involved in forming these soils [4]. These soils are proposed to have formed by alteration of nearby rock by volcanic hydrothermal or fumarolic activity. The Paso Robles soils consist of the original Paso Robles-disturbed-Pasadena (PR-dist), Paso Robles- PasoLight (PR-PL), Arad-Samra, Arad-Hula, Tyrone- Berker Island1 and Tyrone-MountDarwin [2 ,3. ]Chemical characteristics indicate that the PR-dist and PR-PL soils could be derived from acid weathering of local Wishstone rocks while the Samra and Hula soils are likely derived from local Algonquin-Iroquet rock [3]. The Paso Robles soils were exposed to acidic sulfur bearing fluids; however, little else is known about the chemistry of the alteration fluid and its effects on the alteration of the proposed parent materials. The objectives of this work are to conduct titanium normalized mass-balance analysis to1) assess elemental gains and losses from the parent materials in the formation of the Paso Robles soils and 2) utilize this information to indicate the chemical nature of the alteration fluids.

  19. A quantitative comparison of Soil Development in four climatic regimes

    USGS Publications Warehouse

    Harden, J.W.; Taylor, E.M.

    1983-01-01

    A new quantitative Soil Development Index based on field data has been applied to chronosequences formed under different climatic regimes. The four soil chronosequences, developed primarily on sandy deposits, have some numeric age control and are located in xeric-inland (Merced, Calif.), xeric-coastal (Ventura, Calif.), aridic (Las Cruces, N. Mex.), and udic (Susquehanna Valley, Pa.) soil-moisture regimes. To quantify field properties, points are assigned for developmental increases in soil properties in comparison to the parent material. Currently ten soil-field properties are quantified and normalized for each horizon in a given chronosequence, including two new properties for carbonate-rich soils in addition to the eight properties previously defined. When individual properties or the combined indexes are plotted as a function of numeric age, rates of soil development can be compared in different climates. The results demonstrate that (1) the Soil Development Index can be applied to very different soil types, (2) many field properties develop systematically in different climatic regimes, (3) certain properties appear to have similar rates of development in different climates, and (4) the Profile Index that combines different field properties increases significantly with age and appears to develop at similar rates in different climates. The Soil Development Index can serve as a preliminary guide to soil age where other age control is lacking and can be used to correlate deposits of different geographical and climatic regions. ?? 1983.

  20. Soiling of building envelope surfaces and its effect on solar reflectance – Part II: Development of an accelerated aging method for roofing materials

    SciTech Connect

    Sleiman, Mohamad; Kirchstetter, Thomas W.; Berdahl, Paul; Gilbert, Haley E.; Quelen, Sarah; Marlot, Lea; Preble, Chelsea V.; Chen, Sharon; Montalbano, Amandine; Rosseler, Olivier; Akbari, Hashem; Levinson, Ronnen; Destaillats, Hugo

    2014-01-09

    Highly reflective roofs can decrease the energy required for building air conditioning, help mitigate the urban heat island effect, and slow global warming. However, these benefits are diminished by soiling and weathering processes that reduce the solar reflectance of most roofing materials. Soiling results from the deposition of atmospheric particulate matter and the growth of microorganisms, each of which absorb sunlight. Weathering of materials occurs with exposure to water, sunlight, and high temperatures. This study developed an accelerated aging method that incorporates features of soiling and weathering. The method sprays a calibrated aqueous soiling mixture of dust minerals, black carbon, humic acid, and salts onto preconditioned coupons of roofing materials, then subjects the soiled coupons to cycles of ultraviolet radiation, heat and water in a commercial weatherometer. Three soiling mixtures were optimized to reproduce the site-specific solar spectral reflectance features of roofing products exposed for 3 years in a hot and humid climate (Miami, Florida); a hot and dry climate (Phoenix, Arizona); and a polluted atmosphere in a temperate climate (Cleveland, Ohio). A fourth mixture was designed to reproduce the three-site average values of solar reflectance and thermal emittance attained after 3 years of natural exposure, which the Cool Roof Rating Council (CRRC) uses to rate roofing products sold in the US. This accelerated aging method was applied to 25 products₋single ply membranes, factory and field applied coatings, tiles, modified bitumen cap sheets, and asphalt shingles₋and reproduced in 3 days the CRRC's 3-year aged values of solar reflectance. In conclusion, this accelerated aging method can be used to speed the evaluation and rating of new cool roofing materials.

  1. Sulfur‐Limonene Polysulfide: A Material Synthesized Entirely from Industrial By‐Products and Its Use in Removing Toxic Metals from Water and Soil

    PubMed Central

    Crockett, Michael P.; Evans, Austin M.; Worthington, Max J. H.; Albuquerque, Inês S.; Slattery, Ashley D.; Gibson, Christopher T.; Campbell, Jonathan A.; Lewis, David A.; Bernardes, Gonçalo J. L.

    2015-01-01

    Abstract A polysulfide material was synthesized by the direct reaction of sulfur and d‐limonene, by‐products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur‐limonene polysulfide resulted in a color change. These properties motivate application in next‐generation environmental remediation and mercury sensing. PMID:26481099

  2. Microbial clogging of saturated soils and aquifer materials: Evaluation of mathematical models

    SciTech Connect

    Vandevivere, P.; Baveye, P.; Sanchez de Lozada, D.

    1995-09-01

    Bacterial reductions of the saturated hydraulic conductivity of natural porous media appear to be caused by a wide range of mechanisms, few of which have been carefully studied. Nevertheless, a number of mathematical models have been developed in recent years to describe the microbial clogging process, based on the assumption that bacterial cells form impermeable biofilms uniformly covering pore walls. In the present study, two independent sets of experimental data available in the literature are used to test the existing bioclogging models. To broaden the scope of the assessment, an additional model, initially developed to describe the deep filtration of suspended colloids, is also included in the comparisons. Analysis of the experimental data reveals a clear relationship between the texture of a porous medium and the ability of a given level of biomass to reduce its saturated hydraulic conductivity at equal biomass, clogging is much more pronounced in fine-textured materials than in coarse-textured ones. In addition, the results of the model comparisons suggest that none of the existing models can predict satisfactorily the saturated hydraulic conductivity reductions observed in fine sands, whereas they fare somewhat better in coarser materials. It is argued that this inadequacy of existing models is due to the continuous biofilm assumption on which they are founded. Indeed, a simplistic model that assumes the biomass to be distributed as plugs instead of as continuous biofilms produces quantitatively much improved predictions of the saturated hydraulic conductivity reductions. Reference is made to the consequences of this observation in terms of future research. 50 refs., 4 figs.

  3. Verification of the Classification and Diagnostic system of Russian soils (2004) on the materials of a collection of soil monoliths from the V.V. Dokuchaev Central Soil Museum

    NASA Astrophysics Data System (ADS)

    Aparin, B. F.; Gerasimova, M. I.; Lebedeva, I. I.; Sukhacheva, E. I.; Tonkonogov, V. D.

    2007-05-01

    The first in the world collection of soil monoliths from the Dokuchaev Central Soil Museum (St. Petersburg) was examined in order to test and verify the new substantive-genetic classification system of Russian soils. This work made it possible to introduce a number of refinements in the second edition of the Russian soil classification system (2004). These refinements included the addition of new diagnostic horizons and features and the specification of their definitions. The analysis of the museum collection of soils has definite advantages, as it allows one to work with soils from different geographic regions simultaneously, to consider morphological features of soils under standard conditions, to use analytical soil data, and to analyze different names (i.e., interpretations of the genesis) given to the same soils. At the same time, a critical analysis of the collection creates necessary prerequisites for a comparative analysis of soils from different regions of Russia with the national reference soil base, which is important in order to reveal the real pedogenetic diversity and improve the information base on soil resources in Russia.

  4. Soils and the soil cover of the arkaim reserve (Steppe Zone of the Trans-Ural Region)

    NASA Astrophysics Data System (ADS)

    Prikhod'ko, V. E.; Ivanov, I. V.; Manakhov, D. V.; Manakhova, E. V.

    2012-08-01

    Soils of the Arkaim Reserve in the area around a unique settlement-fortress of the Bronze Age in Chelyabinsk oblast have been studied. These soils are generally typical of the entire Trans-Ural Plateau. The soil properties are characterized in detail on the basis of factual data on 170 soil pits and four soil catenas. The soil cover of the reserve is specified into six geomorphic groups: (a) denudational surfaces of the low mountains, (b) accumulative-denudational surfaces of the low mountains, (c) denudational-accumulative plain surfaces, (d) lacustrine-alluvial plain surfaces, (e) floodplain surfaces, and (f) slopes and bottoms of the local ravines and hollows. Chernozems occupy about 50% of the reserve; solonetzes and saline soils, 32%; meadow chernozems, 7%; and forest soils, 1%. The soils of the reserve are relatively thin; they have a distinct tonguing of the humus horizon and are often saline and solonetzic. The latter properties are inherited from the parent materials and are preserved in the soils for a long time under the conditions of a dry continental climate. The genetic features of the soils differ in dependence on the composition and age of the parent materials. With respect to the thickness of the soil profiles and the reserves of soil humus, the soils can be arranged into the following lithogenic sequence: the soils developed from the eluvium of igneous rocks-redeposited kaolin clay-montmorillonite-hydromica nonsaline and saline loams and clays. The content of Corg in the upper 20 cm varies from 2.5 to 5.6%, and the reserves of Corg in the layers of 0-0.5 and 0-1.0 m reach 57-265 and 234-375 t/ha, respectively. The soils of pastures subjected to overgrazing occupy two-thirds of the reserve. Their humus content is 10-16% higher in comparison with that in the analogous plowed soils. Another characteristic feature of the humus in the soils of the pastures is its enrichment in the labile fraction (28-40% of Corg).

  5. [Analysis of XRD spectral characteristics of soil clay mineral in two typical cultivated soils].

    PubMed

    Zhang, Zhi-Dan; Luo, Xiang-Li; Jiang, Hai-Chao; Li, Qiao; Shen, Cong-Ying; Liu, Hang; Zhou, Ya-Juan; Zhao, Lan-Po; Wang, Ji-Hong

    2014-07-01

    The present paper took black soil and chernozem, the typical cultivated soil in major grain producing area of Northeast, as the study object, and determinated the soil particle composition characteristics of two cultivated soils under the same climate and location. Then XRD was used to study the composition and difference of clay mineral in two kinds of soil and the evolutionary mechanism was explored. The results showed that the two kinds of soil particles were composed mainly of the sand, followed by clay and silt. When the particle accumulation rate reached 50%, the central particle size was in the 15-130 microm interval. Except for black soil profile of Shengli Xiang, the content of clay showed converse sequence to the central particle in two soils. Clay accumulated under upper layer (18.82%) in black soil profile while under caliche layer (17.41%) in chernozem profile. Clay content was the least in parent material horizon except in black profile of Quanyanling. Analysis of clay XRD atlas showed that the difference lied in not only the strength of diffraction peak, but also in the mineral composition. The main contents of black soil and chernozem were both 2 : 1 clay, the composition of black soil was smectite/illite mixed layer-illite-vermiculite and that of chernozem was S/I mixture-illite-montmorillonite, and both of them contained little kaolinite, chlorite, quartz and other primary mineral. This paper used XRD to determine the characteristics of clay minerals comprehensively, and analyzed two kinds of typical cultivated soil comparatively, and it was a new perspective of soil minerals study. PMID:25269317

  6. Total parenting.

    PubMed

    Smith, Richard

    2010-01-01

    In this essay, Richard Smith observes that being a parent, like so much else in our late-modern world, is required to become ever more efficient and effective, and is increasingly monitored by the agencies of the state, often with good reason given the many recorded instances of child abuse and cruelty. However, Smith goes on to argue, this begins to cast being a parent as a matter of "parenting," a technological deployment of skills and techniques, with the loss of older, more spontaneous and intuitive relations between parents and children. Smith examines this phenomenon further through a discussion of how it is captured to some extent in Hannah Arendt's notion of "natality" and how it is illuminated by Charles Dickens in his classic novel, Dombey and Son. PMID:20662172

  7. About soil cover heterogeneity of agricultural research stations' experimental fields

    NASA Astrophysics Data System (ADS)

    Rannik, Kaire; Kõlli, Raimo; Kukk, Liia

    2013-04-01

    Depending on local pedo-ecological conditions (topography, (geo) diversity of soil parent material, meteorological conditions) the patterns of soil cover and plant cover determined by soils are very diverse. Formed in the course of soil-plant mutual relationship, the natural ecosystems are always influenced to certain extent by the other local soil forming conditions or they are site specific. The agricultural land use or the formation of agro-ecosystems depends foremost on the suitability of soils for the cultivation of feed and food crops. As a rule, the most fertile or the best soils of the area, which do not present any or present as little as possible constraints for agricultural land use, are selected for this purpose. Compared with conventional field soils, the requirements for the experimental fields' soil cover quality are much higher. Experimental area soils and soil cover composition should correspond to local pedo-ecological conditions and, in addition to that, represent the soil types dominating in the region, whereas the fields should be as homogeneous as possible. The soil cover heterogeneity of seven arable land blocks of three research stations (Jõgeva, Kuusiku and Olustvere) was studied 1) by examining the large scale (1:10 000) digital soil map (available via the internet), and 2) by field researches using the transect method. The stages of soils litho-genetic and moisture heterogeneities were estimated by using the Estonian normal soils matrix, however, the heterogeneity of top- and subsoil texture by using the soil texture matrix. The quality and variability of experimental fields' soils humus status, was studied more thoroughly from the aspect of humus concentration (g kg-1), humus cover thickness (cm) and humus stocks (Mg ha-1). The soil cover of Jõgeva experimental area, which presents an accumulative drumlin landscape (formed during the last glacial period), consist from loamy Luvisols and associated to this Cambisols. In Kuusiku area

  8. Effects of land use and geological factors on the spatial variability of soil carbon and nitrogen in the Konya Basin, Turkey

    NASA Astrophysics Data System (ADS)

    Mayes, M. T.; Marin-Spiotta, E.; Ozdogan, M.; Clayton, M.

    2012-12-01

    The landscape-scale (10s-100s km2) spatial variability of soil properties such as carbon and nitrogen stocks is poorly known in many regions worldwide, especially in semi-arid landscapes with millenial histories of intense land use activities. Characterizing patterns and understanding processes that affect such variability is important for basic research on land use impacts for soils and ecosystems, such as modeling regional-scale ecosystem biogeochemical balances and greenhouse gas emissions, as well as applied research for precision agriculture, soil erosion control, water conservation and carbon accounting. Here, we use geostatistical analyses to study patterns of spatial variability in total carbon (TC), organic carbon (SOC), and total nitrogen (TN) stocks in soils (0-25 cm) of the Konya Basin, Turkey. We hypothesized that land use will have a stronger effect on SOC variability, which will be more tightly linked with vegetation and human management, while parent material will be a more important predictor of TC variability in these arid soils with high carbonate content. We collected a total of 560 samples from 35 sites distributed across three soil parent materials and three classes of land use (agriculture, grazing lands and orchards), using multi-temporal analyses of Landsat data to map land cover and geographic information systems (GIS) to aid selection of field sites. Building on previous research that found parent materials strongly control TC, TN and SOC, we tested whether soil parent materials or land-use practices more strongly explain patterns of spatial variability of soil properties at nested scales, including within field-site (within 35 1-ha field sites) and landscape scales (across 35 sites). Initial results show that spatial patterns of total carbon (TC) are strongly affected by soil parent materials and field sites at landscape scales. Forthcoming analyses will analyze patterns in TN and SOC. Our analyses, which test effects of geological

  9. A Brief History of Soil Mapping and Classification in the USA

    NASA Astrophysics Data System (ADS)

    Brevik, Eric C.; Hartemink, Alfred E.

    2014-05-01

    Soil maps show the distribution of soils across an area but also depict soil science theory and ideas on soil formation and classification at the time the maps were created. The national soil mapping program in the USA was established in 1899. The first nation-wide soil map was published by M. Whitney in 1909 and showed soil provinces that were largely based on geology. In 1912, G.N. Coffey published the first country-wide map based on soil properties. The map showed 5 broad soil units that used parent material, color and drainage as diagnostic criteria. The 1913 national map was produced by C.F. Marbut, H.H. Bennett, J.E. Lapham, and M.H. Lapham and showed broad physiographic units that were further subdivided into soil series, soil classes and soil types. In 1935, Marbut drafted a series of maps based on soil properties, but these maps were replaced as official U.S. soil maps in 1938 with the work of M. Baldwin, C.E. Kellogg, and J. Thorp. A series of soil maps similar to modern USA maps appeared in the 1960s with the 7th Approximation followed by revisions with the 1975 and 1999 editions of Soil Taxonomy. This review has shown that soil maps in the United States produced since the early 1900s moved initially from a geologic-based concept to a pedologic concept of soils. Later changes were from property-based systems to process-based, and then back to property-based. The information in this presentation is based on Brevik and Hartemink (2013). Brevik, E.C., and A.E. Hartemink. 2013. Soil Maps of the United States of America. Soil Science Society of America Journal 77:1117-1132. doi:10.2136/sssaj2012.0390.

  10. A new model for humic materials and their interactions with hydrophobic organic chemicals in soil-water or sediment-water systems

    USGS Publications Warehouse

    Wershaw, R. L.

    1986-01-01

    A generalized model of humic materials in soils and sediments, which is consistent with their observed properties, is presented. This model provides a means of understanding the interaction of hydrophobic pollutants with humic materials. In this model, it is proposed that the humic materials in soils and sediments consist of a number of different oligomers and simple compounds which result from the partial degradation of plant remains. These degradation products are stabilized by incorporation into humic aggregates bound together by weak bonding mechanisms, such as hydrogen bonding, pi bonding, and hydrophobic interactions. The resulting structures are similar to micelles or membranes, in which the interiors of the structures are hydrophobic and the exteriors are hydrophilic. Hydrophobic compounds will partition into the hydrophobic interiors of the humic micelles or "membrane-like" structures. ?? 1986.

  11. A new approach of mapping soils in the Alps - Challenges of deriving soil information and creating soil maps for sustainable land use. An example from South Tyrol (Italy)

    NASA Astrophysics Data System (ADS)

    Baruck, Jasmin; Gruber, Fabian E.; Geitner, Clemens

    2015-04-01

    Nowadays sustainable land use management is gaining importance because intensive land use leads to increasing soil degradation. Especially in mountainous regions like the Alps sustainable land use management is important, as topography limits land use. Therefore, a database containing detailed information of soil characteristics is required. However, information of soil properties is far from being comprehensive. The project "ReBo - Terrain classification based on airborne laser scanning data to support soil mapping in the Alps", founded by the Autonomous Province of Bolzano, aims at developing a methodical framework of how to obtain soil data. The approach combines geomorphometric analysis and soil mapping to generate modern soil maps at medium-scale in a time and cost efficient way. In this study the open source GRASS GIS extension module r.geomorphon (Jasciewicz and Stepinski, 2013) is used to derive topographically homogeneous landform units out of high resolution DTMs on scale 1:5.000. Furthermore, for terrain segmentation and classification we additionally use medium-scale data sets (geology, parent material, land use etc.). As the Alps are characterized by a great variety of topography, parent material, wide range of moisture regimes etc. getting reliable soil data is difficult. Additionally, geomorphic activity (debris flow, landslide etc.) leads to natural disturbances. Thus, soil properties are highly diverse and largely scale dependent. Furthermore, getting soil information of anthropogenically influenced soils is an added challenge. Due to intensive cultivation techniques the natural link between the soil forming factors is often repealed. In South Tyrol we find the largest pome producing area in Europe. Normally, the annual precipitation is not enough for intensive orcharding. Thus, irrigation strategies are in use. However, as knowledge about the small scaled heterogeneous soil properties is mostly lacking, overwatering and modifications of the

  12. Molybdenum isotope fractionation in soils: Influence of redox conditions, organic matter, and atmospheric inputs

    NASA Astrophysics Data System (ADS)

    Siebert, C.; Pett-Ridge, J. C.; Opfergelt, S.; Guicharnaud, R. A.; Halliday, A. N.; Burton, K. W.

    2015-08-01

    Molybdenum isotope fractionation accompanying soil development is studied across three pedogenic gradients encompassing a range of controlling factors. These factors include variable redox conditions, organic matter content, Fe and Mn oxy(hydr)oxide content, mineral composition, degree of weathering, pH, type and amount of atmospheric inputs, age, climate, and underlying rock type. Soil profiles from the island of Maui (Hawaii) along a precipitation gradient ranging from 850 to 5050 mm mean annual precipitation show a decrease in average soil δ98Mo from -0.04 ± 0.11‰ at the driest, most oxic site, which is indistinguishable from the basalt parent material (-0.09 ± 0.08‰), to -0.33 ± 0.10‰ at the wettest, most reducing site. A suite of 6 Icelandic soils display a broad trend with heavier δ98Mo values (up to +1.50 ± 0.09‰) in soil horizons that are more weathered and have higher organic matter content. Selective extractions of Mo from different soil components indicate that the association with organic matter and silicate or Ti-oxide residue dominates retention of Mo in these soils, with adsorption on Fe and Mn oxy(hydr)oxides playing a lesser role. Across all basaltic soils, δ98Mo values are lighter in soils that exhibit the most net Mo loss relative to the parent material, and δ98Mo values are heavier in soils that exhibit net Mo gains. A well-drained regolith profile in the Luquillo Mountains of Puerto Rico developed on quartz diorite shows heavier δ98Mo values than the parent material (up to +0.71 ± 0.10‰ with an integrated profile average of +0.28 ± 0.10‰) in soil and shallower saprolite, despite overall moderate loss of 28% of Mo relative to the bedrock. However, the deeper saprolite is unfractionated from bedrock (-0.01 ± 0.10‰, quartz diorite bedrock) indicating that rock weathering dissolution processes and secondary clay formation do not fractionate Mo isotopes. Our data suggest that the Mo mass balance and isotope composition of

  13. Parental Distancing Strategies and Children's Fantasy Play.

    ERIC Educational Resources Information Center

    Perlmutter, Jane C.; Pellegrini, Anthony D.

    Effects of age and gender of preschool children and sex of parent on parental teaching strategies in a fantasy play situation were examined. Relations of parental strategies to children's fantasy play were assessed. Play sessions were held in a small playroom equipped with materials which facilitated dramatic production. The linguistic strategies…

  14. Magnetic Properties of Different-Aged Chernozemic Soils

    NASA Astrophysics Data System (ADS)

    Fattakhova, Leysan; Shinkarev, Alexandr; Kosareva, Lina; Nourgaliev, Danis; Shinkarev, Aleksey; Kondrashina, Yuliya

    2016-04-01

    We investigated the magnetic properties and degree of mineral weathering in profiles of different-aged chernozemic soils derived from a uniform parent material. In this work, layer samples of virgin leached chernozem and chernozemic soils formed on the mound of archaeological earthy monument were used. The characterization of the magnetic properties was carried out on the data of the magnetometry and differential thermomagnetic analysis. The evaluation of the weathering degree was carried out on a loss on ignition, cation exchange capacity and X-ray phase analysis on the data of the original soil samples and samples of the heavy fraction of minerals. It was found that the magnetic susceptibility enhancement in humus profiles of newly formed chernozemic soils lagged significantly behind the organic matter content enhancement. This phenomenon is associated with differences in kinetic parameters of humus formation and structural and compositional transformation of the parent material. It is not enough time of 800-900 years to form a relatively "mature" magnetic profile. These findings are well consistent with the chemical kinetic model (Boyle et al., 2010) linking the formation of the soils magnetic susceptibility with the weathering of primary Fe silicate minerals. Different-aged chernozemic soils are at the first stage of formation of a magnetic profile when it is occur an active production of secondary ferrimagnetic minerals from Fe2+ released by primary minerals.

  15. On the origin of superparamagnetic minerals of tropical soils and their impact on landmine detection

    NASA Astrophysics Data System (ADS)

    Igel, Jan; Preetz, Holger; Altfelder, Sven

    2010-05-01

    Magnetic susceptibility of soils is mainly determined by their content of ferrimagnetic minerals whereas titanomagnetite, magnetite and maghemite being the most important ones. Titanomagnetite and magnetite are of magmatic origin, i.e. they crystallise during cooling of iron-rich magma and are part of many igneous rocks. Maghemite and sometimes magnetite are of pedogenic origin. They develop by crystallisation of dissolved iron during soil forming processes. Ferrimagnetic minerals that are smaller than some tens of nanometres are superparamagnetic (SP) and show frequency dependent susceptibility. SP minerals crystallise if magma cools down rapidly (e.g. volcanic magmas, glasses and ashes) and are frequently formed during pedogenesis. In order to investigate the origin and formation of SP minerals in tropical soils, we analyse magnetic properties of 594 samples from the entire tropics comprising the whole range of weathering states from unweathered rock to highly weathered soil. Tropical soils are subject to intense chemical weathering and are rich in ferrimagnetic and in particular SP minerals. The process leading to a high content of these minerals is either residual enrichment due to their weathering resistance or neo-formation. In this study we focus on the frequency dependent susceptibility (absolute and relative) of the samples and classify it according to the parent material and alteration. We observe that • within each parent-material group, rock material shows in general lower susceptibility and absolute frequency dependence than soil material • ultrabasic and basic/intermediate rocks and soils developed from these rocks show high absolute frequency dependent susceptibility and, in contrast, acid rocks and sediments show lower absolute frequency dependence • absolute frequency dependence increases from unweathered rock to weathered rock, and from subsoil to topsoil material within every group of parent material • relative frequency dependence rises

  16. MICHIGAN SOIL VAPOR EXTRACTION REMEDIATION (MISER) MODEL: A COMPUTER PROGRAM TO MODEL SOIL VAPORT EXTRACTION AND BIOVENTING OF ORGANIC MATERIALS IN UNSATURATED GEOLO-GICAL MATERIAL (EPA/600/SR-97/099)

    EPA Science Inventory

    Soil vapor extraction (SVE) and bioventing (BV) are proven strategies for remediation of unsaturated zone soils. Mathematical models are powerful tools that can be used to integrate and quantify the interaction of physical, chemical, and biological processes occurring in field sc...

  17. Assessing Fungal Population in Soil Planted with Cry1Ac and CPTI Transgenic Cotton and Its Conventional Parental Line Using 18S and ITS rDNA Sequences over Four Seasons.

    PubMed

    Qi, Xiemin; Liu, Biao; Song, Qinxin; Zou, Bingjie; Bu, Ying; Wu, Haiping; Ding, Li; Zhou, Guohua

    2016-01-01

    Long-term growth of genetically modified plants (GMPs) has raised concerns regarding their ecological effects. Here, FLX-pyrosequencing of region I (18S) and region II (ITS1, 5.8S, and ITS2) rDNA was used to characterize fungal communities in soil samples after 10-year monoculture of one representative transgenic cotton line (TC-10) and 15-year plantation of various transgenic cotton cultivars (TC-15mix) over four seasons. Soil fungal communities in the rhizosphere of non-transgenic control (CC) were also compared. No notable differences were observed in soil fertility variables among CC, TC-10, and TC-15mix. Within seasons, the different estimations were statistically indistinguishable. There were 411 and 2 067 fungal operational taxonomic units in the two regions, respectively. More than 75% of fungal taxa were stable in both CC and TC except for individual taxa with significantly different abundance between TC and CC. Statistical analysis revealed no significant differences between CC and TC-10, while discrimination of separating TC-15mix from CC and TC-10 with 37.86% explained variance in PCoA and a significant difference of Shannon indexes between TC-10 and TC-15mix were observed in region II. As TC-15mix planted with a mixture of transgenic cottons (Zhongmian-29, 30, and 33B) for over 5 years, different genetic modifications may introduce variations in fungal diversity. Further clarification is necessary by detecting the fungal dynamic changes in sites planted in monoculture of various transgenic cottons. Overall, we conclude that monoculture of one representative transgenic cotton cultivar may have no effect on fungal diversity compared with conventional cotton. Furthermore, the choice of amplified region and methodology has potential to affect the outcome of the comparison between GM-crop and its parental line. PMID:27462344

  18. Assessing Fungal Population in Soil Planted with Cry1Ac and CPTI Transgenic Cotton and Its Conventional Parental Line Using 18S and ITS rDNA Sequences over Four Seasons

    PubMed Central

    Qi, Xiemin; Liu, Biao; Song, Qinxin; Zou, Bingjie; Bu, Ying; Wu, Haiping; Ding, Li; Zhou, Guohua

    2016-01-01

    Long-term growth of genetically modified plants (GMPs) has raised concerns regarding their ecological effects. Here, FLX-pyrosequencing of region I (18S) and region II (ITS1, 5.8S, and ITS2) rDNA was used to characterize fungal communities in soil samples after 10-year monoculture of one representative transgenic cotton line (TC-10) and 15-year plantation of various transgenic cotton cultivars (TC-15mix) over four seasons. Soil fungal communities in the rhizosphere of non-transgenic control (CC) were also compared. No notable differences were observed in soil fertility variables among CC, TC-10, and TC-15mix. Within seasons, the different estimations were statistically indistinguishable. There were 411 and 2 067 fungal operational taxonomic units in the two regions, respectively. More than 75% of fungal taxa were stable in both CC and TC except for individual taxa with significantly different abundance between TC and CC. Statistical analysis revealed no significant differences between CC and TC-10, while discrimination of separating TC-15mix from CC and TC-10 with 37.86% explained variance in PCoA and a significant difference of Shannon indexes between TC-10 and TC-15mix were observed in region II. As TC-15mix planted with a mixture of transgenic cottons (Zhongmian-29, 30, and 33B) for over 5 years, different genetic modifications may introduce variations in fungal diversity. Further clarification is necessary by detecting the fungal dynamic changes in sites planted in monoculture of various transgenic cottons. Overall, we conclude that monoculture of one representative transgenic cotton cultivar may have no effect on fungal diversity compared with conventional cotton. Furthermore, the choice of amplified region and methodology has potential to affect the outcome of the comparison between GM-crop and its parental line. PMID:27462344

  19. Acidification of forest soil in Russia: From 1893 to present

    USGS Publications Warehouse

    Lapenis, A.G.; Lawrence, G.B.; Andreev, A.A.; Bobrov, A.A.; Torn, M.S.; Harden, J.W.

    2004-01-01

    It is commonly believed that fine-textured soils developed on carbonate parent material are well buffered from possible acidification. There are no data, however, that document resistance of such soils to acidic deposition exposure on a timescale longer than 30-40 years. In this paper, we report on directly testing the long-term buffering capacity of nineteenth century forest soils developed on calcareous silt loam. In a chemical analysis comparing archived soils with modern soils collected from the same locations ???100 years later, we found varying degrees of forest-soil acidification in the taiga and forest steppe regions. Land-use history, increases in precipitation, and acidic deposition were contributing factors in acidification. The acidification of forest soil was documented through decreases in soil pH and changes in concentrations of exchangeable calcium and aluminum, which corresponded with changes in communities of soil microfauna. Although acidification was found at all three analyzed locations, the trends in soil chemistry were most pronounced where the highest loading of acidic deposition had taken place. Copyright 2004 by the American Geophysical Union.

  20. Acidification of forest soil in Russia: From 1893 to present

    SciTech Connect

    Lapenis, A.G.; Lawrence, G.B.; Andreev, A.A.; Bobrov, A.A.; Torn, M.S.; Harden, J.W.

    2003-01-02

    It is commonly believed that fine-textured soils developed on carbonate parent material are well buffered from possible acidification. There are no data, however, that document resistance of such soils to acidic deposition exposure on a timescale longer than 30-40 years. In this paper, we report on directly testing the long-term buffering capacity of nineteenth century forest soils developed on calcareous silt loam. In a chemical analysis comparing archived soils with modern soils collected from the same locations similar to 100 years later, we found varying degrees of forest-soil acidification in the taiga and forest steppe regions. Land-use history, increases in precipitation, and acidic deposition were contributing factors in acidification. The acidification of forest soil was documented through decreases in soil pH and changes in concentrations of exchangeable calcium and aluminum, which corresponded with changes in communities of soil microfauna. Although acidification was found at all three analyzed locations, the trends in soil chemistry were most pronounced where the highest loading of acidic deposition had taken place.

  1. Changes in soil CO2 efflux of organic calcaric soils due to disturbance by wind

    NASA Astrophysics Data System (ADS)

    Mayer, M.; Katzensteiner, K.

    2012-04-01

    Disturbances such as windthrow or insect infestations are supposed to have a significant influence on the soil carbon balance of affected forests. Increasing soil temperatures and changes in the soil moisture regime, caused by the removed tree layer, are expected to change soil CO2 efflux, also known as soil respiration. Beside an anticipated stimulation of the carbon mineralization, the main part of root allocated CO2 is offset due to the blown down trees. On mountain forest sites of the Northern Limestone Alps, where highly active organic soils above calcareous parent material are characteristic (Folic Histosols and Rendzic Leptosols), an increase of the mineralization rate of carbon may contribute to enormous humus losses. Serious site degradation can be the consequence, especially on south exposed slopes where extreme climatic conditions occur. The present study tries to give insights to disturbance induced changes in temporal and spatial behaviour of soil respiration for a montane mountain forest located in the Northern Limestone Alps of Upper Austria. Soil respiration, soil temperature and volumetric water content were measured on two windthrow areas (blow down dates were 2007 and 2009 respectively) as well as in an adjacent mature mixed forest during the vegetation periods of 2010 and 2011. Soil respiration in both years was mainly driven by soil temperature, which explained up to 90 % of the concerning temporal variation. Volumetric water content had a significant influence as additional temporal driver. After removing the temperature trend, significant differences in basal soil respiration rates were found for the disturbance area and the forest stand. Inter seasonal declines in soil respiration were ascertained for the mature stand as well as for the recent windthrow. Particular decreases are related to drought stress in summer 2011 and a proceeded decomposition of labile soil carbon components at the windthrow site. An interaction between soil type and

  2. Visualizing Soil Landscapes on Mobile Devices

    NASA Astrophysics Data System (ADS)

    Schulze, Darrell; Lindbo, David

    2016-04-01

    The Integrating Spatial Educational Experiences (Isee) project utilizes the most detailed US soil survey data to create thematic maps of soil properties that are then combined with a highly optimized hillshade basemap for display. The Isee app, currently available for the iPad platform from the Apple App Store, allows the cached maps to be zoomed and panned quickly to any location down to a scale of 1:18,000. Maps currently available for the states of Indiana, Illinois, Kentucky, Ohio, Texas, West Virginia, and Wisconsin include, Dominant Soil Parent Materials, Natural Soil Drainage Classes, Limiting Layers, Surface Soil Colors, and Acid Subsoils. Other thematic maps will be added in the future. The ability to zoom, pan, and change maps quickly allows the user to see and understand soil landscape relationships that are not often apparent using static maps, while the ability to access the maps conveniently in the field allows the user to see how soil landscape features on the maps appear in the field.

  3. Novel approach for quantitatively estimating element retention and material balances in soil profiles of recharge basins used for wastewater reclamation.

    PubMed

    Eshel, Gil; Lin, Chunye; Banin, Amos

    2015-01-01

    We investigated changes in element content and distribution in soil profiles in a study designed to monitor the geochemical changes accruing in soil due to long-term secondary effluent recharge, and its impact on the sustainability of the Soil Aquifer Treatment (SAT) system. Since the initial elemental contents of the soils at the studied site were not available, we reconstructed them using scandium (Sc) as a conservative tracer. By using this approach, we were able to produce a mass-balance for 18 elements and evaluate the geochemical changes resulting from 19 years of effluent recharge. This approach also provides a better understanding of the role of soils as an adsorption filter for the heavy metals contained in the effluent. The soil mass balance suggests 19 years of effluent recharge cause for a significant enrichment in Cu, Cr, Ni, Zn, Mg, K, Na, S and P contents in the upper 4m of the soil profile. Combining the elements lode record during the 19 years suggest that Cr, Ni, and P inputs may not reach the groundwater (20 m deep), whereas the other elements may. Conversely, we found that 58, 60, and 30% of the initial content of Mn, Ca and Co respectively leached from the upper 2-m of the soil profile. These high percentages of Mn and Ca depletion from the basin soils may reduce the soil's ability to buffer decreases in redox potential pe and pH, respectively, which could initiate a reduction in the soil's holding capacity for heavy metals. PMID:25300016

  4. Analysis and assessment on heavy metal sources in the coastal soils developed from alluvial deposits using multivariate statistical methods.

    PubMed

    Li, Jinling; He, Ming; Han, Wei; Gu, Yifan

    2009-05-30

    An investigation on heavy metal sources, i.e., Cu, Zn, Ni, Pb, Cr, and Cd in the coastal soils of Shanghai, China, was conducted using multivariate statistical methods (principal component analysis, clustering analysis, and correlation analysis). All the results of the multivariate analysis showed that: (i) Cu, Ni, Pb, and Cd had anthropogenic sources (e.g., overuse of chemical fertilizers and pesticides, industrial and municipal discharges, animal wastes, sewage irrigation, etc.); (ii) Zn and Cr were associated with parent materials and therefore had natural sources (e.g., the weathering process of parent materials and subsequent pedo-genesis due to the alluvial deposits). The effect of heavy metals in the soils was greatly affected by soil formation, atmospheric deposition, and human activities. These findings provided essential information on the possible sources of heavy metals, which would contribute to the monitoring and assessment process of agricultural soils in worldwide regions. PMID:18976857

  5. Soil morphology of canopy and intercanopy sites in a pinon-Juniper woodland

    SciTech Connect

    Davenport, D.W.; Wilcox, B.P.; Breshear, D.D.

    1996-11-01

    Pinon-juniper woodlands in the semiarid western USA have expanded as much as fivefold during the last 150 yr, often accompanied by losses of understory vegetation and increasing soil erosion. We conducted this study to determine the differences in soil morphology between canopy and intercanopy locations within a pinon (Pinus edulis Engelm.)-juniper [Juniperus monosperma (Engelm.) Sarg.] woodland with uniform parent material, topography, and climate. The woodland studied, located near Los Alamos, NM, has a mean tree age of 135 yr. We examined soil morphology by augering 135 profiles in a square grid pattern and comparing soils under pinon and juniper canopies with intercanopy soils. Only two of the 17 morphological properties compared showed significant differences. The B horizons make up a slightly greater proportion of total profile thickness in intercanopy soils, and there are higher percentages of coarse fragments in the lower portions of canopy soil profiles. Canopy soils have lower mean pH and higher mean organic C than intercanopy soils. Regression analysis showed that most soil properties did not closely correspond with tree size, but total soil thickness and B horizon thickness are significantly greater under the largest pinon trees, and soil reaction is lower under the largest juniper trees. Our findings suggest that during the period in which pinon-juniper woodlands have been expanding, the trees have had only minor effects on soil morphology. 36 refs., 4 figs., 4 tabs.

  6. GEMAS - Soil geochemistry and health implications

    NASA Astrophysics Data System (ADS)

    Ernstsen, Vibeke; Ladenberger, Anna; Wragg, Joanna; Gulan, Aleksandra

    2014-05-01

    The GEMAS Project resulted in a large coherent data set displaying baseline levels of elements in agricultural and grazing land soil, which has a wide variety of applications. Medical geology is an emerging new discipline providing a link between geoscience and medicine by interpreting natural geological factors in relation to human and animal health and their geographical distribution. Medical geology shows not only problems related to harmful health effects of natural geological materials and processes, but also deals with their beneficial aspects. Since the GEMAS project demonstrates the importance of geological factors in geochemical patterns in European soil, this data set can be used in improving our understanding of how the geological processes may affect human health in Europe. The main potential health problems are related to deficiency of nutrients in soil and toxic effects of potentially harmful elements. Deficiency in macro- (e.g., K, Fe, Mg, P) and micro-nutrients (e.g., Se, Zn, Cl) can be responsible for a reduction in crop productivity and certain health issues for livestock and humans. On the other hand, bioavailability of crucial elements depends on soil parameters, e.g., pH; namely, low pH in soil (in northern Europe) makes more micronutrients bioavailable, with the exception of Mo, P and Ca. Rocks underlying the soil layer have a major impact on soil composition, and soil parent material can be a main source of toxic metals, for instance, soil developed on black shale (e.g., Oslo region) shows potentially toxic levels of metals, such as As, Cd, U, Zn and Pb. High content of organic matter is another factor amplifying the toxic levels of metals in soil. Several important topics with health implications can be then addressed using the GEMAS data set, namely, soil properties and element bioavailability, arsenic toxicity, selenium deficiency, potential health effects of liming, uranium in European soil, influence of recent and historical volcanic

  7. Soil Response to Global Change: Soil Process Domains and Pedogenic Thresholds (Invited)

    NASA Astrophysics Data System (ADS)

    Chadwick, O.; Kramer, M. G.; Chorover, J.

    2013-12-01

    The capacity of soil to withstand perturbations, whether driven by climate, land use change, or spread of invasive species, depends on its chemical composition and physical state. The dynamic interplay between stable, well buffered soil process domains and thresholds in soil state and function is a strong determinant of soil response to forcing from global change. In terrestrial ecosystems, edaphic responses are often mediated by availability of water and its flux into and through soils. Water influences soil processes in several ways: it supports biological production, hence proton-donor, electron-donor and complexing-ligand production; it determines the advective removal of dissolution products, and it can promote anoxia that leads microorganisms to utilize alternative electron acceptors. As a consequence climate patterns strongly influence global distribution of soil, although within region variability is governed by other factors such as landscape age, parent material and human land use. By contrast, soil properties can vary greatly among climate regions, variation which is guided by the functioning of a suite of chemical processes that tend to maintain chemical status quo. This soil 'buffering' involves acid-base reactions as minerals weather and oxidation-reduction reactions that are driven by microbial respiration. At the planetary scale, soil pH provides a reasonable indicator of process domains and varies from about 3.5 to10, globally, although most soils lie between about 4.5 and 8.5. Those that are above 7.5 are strongly buffered by the carbonate system, those that are characterized by neutral pH (7.5-6) are buffered by release of non-hydrolyzing cations from primary minerals and colloid surfaces, and those that are <6 are buffered by hydrolytic aluminum on colloidal surfaces. Alkali and alkaline (with the exception of limestone parent material) soils are usually associated with arid and semiarid conditions, neutral pH soils with young soils in both dry

  8. Games in an Introductory Soil Science Course: A Novel Approach for Increasing Student Involvement with Course Material

    ERIC Educational Resources Information Center

    Sulzman, Elizabeth W.

    2004-01-01

    An optional 1-credit recitation course was developed to supplement a traditionally taught 4-credit lecture-plus-laboratory course in soil science at Oregon State University. Popular, competitive games that would be familiar to students were revised to be "soils-based" and were employed in the recitation class. These games were seen as a potential…

  9. Decontamination of soils and materials containing medium-fired PuO{sub 2} using inhibited fluorides with polymer filtration technology

    SciTech Connect

    Temer, D.J.; Villarreal, R.; Smith, B.F.

    1997-10-01

    The decontamination of soils and/or materials from medium-fired plutonium oxide (PuO{sub 2}) with an effective and efficient decontamination agent that will not significantly dissolve the matrix requires a new and innovative technology. After testing several decontamination agents and solutions for dissolution of medium-fired PuO{sub 2}, the most successful decontamination solutions were fluoride compounds, which were effective in breaking the Pu-oxide bond but would not extensively dissolve soil constituents and other materials. The fluoride compounds, tetra fluoboric acid (HBF{sub 4}) and hydrofluorosilicic acid (H{sub 2}F{sub 6}Si), were effective in dissolving medium-fired PuO{sub 2}, and did not seem to have the potential to dissolve the matrix. In both compounds, the fluoride atom is attached to a boron or silicon atom that inhibits the reactivity of the fluoride towards other compounds or materials containing atoms less attracted to the fluoride atom in an acid solution. Because of this inhibition of the reactivity of the fluoride ion, these compounds are termed inhibited fluoride compounds or agents. Both inhibited fluorides studied effectively dissolved medium-fired PuO{sub 2} but exhibited a tendency to not attack stainless steel or soil. The basis for selecting inhibited fluorides was confirmed during leaching tests of medium-fired PuO{sub 2} spiked into soil taken from the Idaho National Engineering Laboratory (INEL). When dissolved in dilute HNO{sub 3}, HCl, or HBr, both inhibited fluoride compounds were effective at solubilizing the medium-fired PuO{sub 2} from spiked INEL soil.

  10. Diffusion and Leaching Behavior of Radionuclides in Category 3 Waste Encasement Concrete and Soil Fill Material – Summary Report

    SciTech Connect

    Mattigod, Shas V.; Wellman, Dawn M.; Bovaird, Chase C.; Parker, Kent E.; Clayton, Libby N.; Powers, Laura; Recknagle, Kurtis P.; Wood, Marcus I.

    2011-08-31

    One of the methods being considered for safely disposing of Category 3 low-level radioactive wastes is to encase the waste in concrete. Such concrete encasement would contain and isolate the waste packages from the hydrologic environment and would act as an intrusion barrier. The current plan for waste isolation consists of stacking low-level waste packages on a trench floor, surrounding the stacks with reinforced steel, and encasing these packages in concrete. These concrete-encased waste stacks are expected to vary in size with maximum dimensions of 6.4 m long, 2.7 m wide, and 4 m high. The waste stacks are expected to have a surrounding minimum thickness of 15 cm of concrete encasement. These concrete-encased waste packages are expected to withstand environmental exposure (solar radiation, temperature variations, and precipitation) until an interim soil cover or permanent closure cover is installed, and to remain largely intact thereafter. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The mobilized radionuclides may escape from the encased concrete by mass flow and/or diffusion and move into the surrounding subsurface environment. Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. The retardation factors for radionuclides contained in the waste packages can be determined from measurements of diffusion coefficients for these contaminants through concrete and fill material. Some of the mobilization scenarios include (1) potential leaching of waste form before permanent closure cover is installed; (2) after the cover installation, long-term diffusion of radionuclides from concrete waste form into surrounding fill material; (3) diffusion of radionuclides from contaminated soils into adjoining concrete encasement and clean fill material. Additionally, the rate of

  11. Soil-restoration rate and initial soil formation trends on example of anthropogenically affected soils of opencast mine in Kursk region, Russian Federation

    NASA Astrophysics Data System (ADS)

    Pigareva, Tatiana

    2015-04-01

    The mining industry is one of the main factors which anthropogenically change the environment. Mining process results in removing of the rocks and mechanical changes of considerable amounts of ground. One of the main results of mining arising of antropic ecosystems as well as increasing of the new created soils total area is technosols. The main factor controlling the soil formation in postmining environment is the quality of spoiled materials. Initial soil formation has been investigated on spoils of the largest iron ore extraction complex in Russia - Mikhailovsky mining and concentration complex which is situated in Kursk region, Russia. Investigated soils are presented by monogenetic weak developed soils of different age (10-15-20 years). Young soils are formed on the loess parent materials (20 year-old soil), or on a mix of sand and clay overburdens (15 and 10-year-old soils). Anthropogenically affected soils are characterized by well-developed humus horizon which is gradually replaced by weakly changed soil-building rocks (profile type A-C for 10-, 15-years old soils, and A-AC-C for 20 years old soils). Gray-humus soils are characterized by presence of diagnostic humus horizon gradually replaced by soil-building rock. The maximum intensity of humus accumulation has been determined in a semi-hydromorphic 10-year-old soil developed on the mixed heaps which is connected with features of water-air conditions complicating mineralization of plant remnants. 20-year-old soil on loess is characterized by rather high rate of organic substances accumulation between all the automorphous soils. It was shown that one of the most effective restoration ways for anthropogenically affected soils is a biological reclamation. Since overburdens once appeared on a day surface are overgrown badly in the first years, they are subject to influence of water and wind erosion. Our researchers have found out that permanent grasses are able to grow quickly; they accumulate a considerable

  12. Organic carbon stocks and sequestration rates of forest soils in Germany.

    PubMed

    Grüneberg, Erik; Ziche, Daniel; Wellbrock, Nicole

    2014-08-01

    The National Forest Soil Inventory (NFSI) provides the Greenhouse Gas Reporting in Germany with a quantitative assessment of organic carbon (C) stocks and changes in forest soils. Carbon stocks of the organic layer and the mineral topsoil (30 cm) were estimated on the basis of ca. 1.800 plots sampled from 1987 to 1992 and resampled from 2006 to 2008 on a nationwide grid of 8 × 8 km. Organic layer C stock estimates were attributed to surveyed forest stands and CORINE land cover data. Mineral soil C stock estimates were linked with the distribution of dominant soil types according to the Soil Map of Germany (1 : 1 000 000) and subsequently related to the forest area. It appears that the C pool of the organic layer was largely depending on tree species and parent material, whereas the C pool of the mineral soil varied among soil groups. We identified the organic layer C pool as stable although C was significantly sequestered under coniferous forest at lowland sites. The mineral soils, however, sequestered 0.41 Mg C ha(-1) yr(-1) . Carbon pool changes were supposed to depend on stand age and forest transformation as well as an enhanced biomass input. Carbon stock changes were clearly attributed to parent material and soil groups as sandy soils sequestered higher amounts of C, whereas clayey and calcareous soils showed small gains and in some cases even losses of soil C. We further showed that the largest part of the overall sample variance was not explained by fine-earth stock variances, rather by the C concentrations variance. The applied uncertainty analyses in this study link the variability of strata with measurement errors. In accordance to other studies for Central Europe, the results showed that the applied method enabled a reliable nationwide quantification of the soil C pool development for a certain period. PMID:24616061

  13. Fractionation of Volatile Elements by Heating of Solid Allende: Implications for the Source Material of Earth, Moon, and the Eucrite Parent Body

    NASA Astrophysics Data System (ADS)

    Jochum, K. P.; Palme, H.

    1993-07-01

    . Nearly-CI-chondritic Sn/Pb ratios are observed in Allende and other carbonaceous chondrites. Evaporation from a solid leads to a severe increase in this ratio. Similarly, Rb/Cs ratios (about 12) are approximately CI-like in all groups of carbonaceous chondrites, perhaps reflecting the inability of nebular processes to fractionate these ratios. In contrast, terrestrial, lunar, and eucritic rocks have much higher Rb/Cs ratios [5]. As volatile loss from molten magmas is excluded [2], their low Cs contents must be characteristic of the parent material. This may exclude carbonaceous chondrites as source materials of eucrites, the Earth, and the Moon. The low Cs in planetary precursor materials may have been produced by secondary heating of small fragments of solid matter at subsolidus temperatures before final accretion. Equilibrated chondrites also show high Rb/Cs ratios, perhaps indicating mobilization of Cs at metamorphic temperatures. References: [1] Palme H. et al. (1988) in Meteorites and the Early Solar System, 436-461, Univ. of Arizona. [2] Humayan M. and Clayton R. N. (1993) LPSC XXIV, 685-686. [3] Davis A. M. et al. (1990) Nature, 347, 655-658. [4] Wulf A. V. and Palme H. (1991) LPSC XXII, 1527-1528. [5] McDonough W. F. et al. (1992) GCA, 56, 1001-1012. Figure 1 appears here in the hard copy.

  14. Soil CO2 constrain and distinction of root respiration and microbial activity by soil CO2 and CH4 profile

    NASA Astrophysics Data System (ADS)

    Ji, S.; Breecker, D.; Nie, J.

    2015-12-01

    Profiles of soil pore space CO2 and CH4 concentrations are rarely reported, especially from the same soils, yet are important for a number of applications. First, quantifying the component of respired CO2 in the soil pore spaces improves paleosol-based paleo-atmospheric CO2 estimates. Second, profiles can be used to estimate the average depth of biological activity (e.g. respiration and CH4 oxidation). Third, CH4 profiles, by identifying microbial activity, may help distinguish root/rhizosphere respiration from microbial decomposition. Here, we report soil CO2 and CH4 profiles measured at the Semi-Arid Climate Observatory and Laboratory (SACOL) on the Chinese Loess Plateau (CLP) at Lanzhou University, Gansu, China. Soil parent material on the site is mainly Quaternary aeolian loess and classifies as an Entisol. Soil respired CO2 (S(z) = soil CO2 - atmospheric CO2) is the most uncertain variable required to reconstruct ancient atmospheric CO2 concentrations from paleosol carbonates. Our direct soil pore space CO2 measurements show that S(z) values varied from ~100ppmV during the spring to ~2200ppmV during the summer. S(z) average 390 ± 30ppmV during May before the summer monsoon begins when soil temperature is increasing, soil water content is at a minimum and pedogenic carbonate may be forming. This value lies in the range of S(z) values previously estimated for surface Inceptisols (300 ± 100ppmV, Breecker 2013) and is lower than Pleistocene CLP paleosols (Da et al.,2015) in similar parent material. Our direct measurements of soil pore space CO2 thus support these previous independent S(z) estimates. We also investigate the average depth of CH4 oxidation and soil respiration, which range from 3-10cm and at least 20cm, respectively, using the shapes of soil gas profiles. Fitting observed soil CO2 and CH4 profiles with a production-diffusion model show that the average depth of CH4 oxidation was always at least 10 cm shallower than the average depth of respiration

  15. "Lou soil", a fertile anthropogenic soil with thousands of years of cultivating history

    NASA Astrophysics Data System (ADS)

    Zhou, J.; Liang, B.; Yan, J.; Zhao, W.

    2012-12-01

    Chinese farmers have a very long history of using manures in their fields. Owing to the long-term addition of manures, an anthropogenic layer was formed on the top of original soil profile (drab soil) in Guanzhong Plains on the south edge of the Loess Plateau, North China. This soil is named the Manural Loessial soil (or Lou soil, "Lou" means the different stories of a building in Chinese). The depth of anthropogenic layer is in range of about 30 to 100 cm depth, which has a close relationship with the soil productivity. This fertile agricultural soil has sustained the agriculture in the region for millenniums. We had determined the organic carbon (SOC) in 7 soil profiles, and found that the depths of anthropogenic layer of were in range of 40 to 71 cm (averaging 59 cm). And the anthropogenic layer became shallower as the profile was far from the village due to less manure application. The organic C stocks in this layer accounted for 69% of organic C stocks in 0-100 cm soil profiles. Organic C stocks in Lou soil was higher than that in the newly cultivated soil developed from loess parent materials. Our 30-day incubation experiment found that addition of synthetic N fertilizer significantly increased the decomposition of SOC in the soils. However, The decomposition rate of SOC in the soil added with manure and inorganic fertilizers for 18-yr (MNPK soil) was significantly lower than in the soils added without fertilizer or inorganic fertilizers (NF soil, and NPK soils). The half-life of the organic C in MNPK soils was also slower than the NF soil, and NPK soil. It indicates that long-term combined application of manure and inorganic fertilizers improves the stabilization of soil organic C. Long-term cultivation has not only increased organic C stocks, but also stabilization of organic C in soil profile. It provides us a unique sample to study the mechanism of accumulation and stabilization of organic C in soil to balance agricultural production and C sequestration

  16. Lunar Soil Particle Separator

    NASA Technical Reports Server (NTRS)

    Berggren, Mark

    2010-01-01

    The Lunar Soil Particle Separator (LSPS) beneficiates soil prior to in situ resource utilization (ISRU). It can improve ISRU oxygen yield by boosting the concentration of ilmenite, or other iron-oxide-bearing materials found in lunar soils, which can substantially reduce hydrogen reduction reactor size, as well as drastically decreasing the power input required for soil heating

  17. Materialism.

    PubMed

    Melnyk, Andrew

    2012-05-01

    Materialism is nearly universally assumed by cognitive scientists. Intuitively, materialism says that a person's mental states are nothing over and above his or her material states, while dualism denies this. Philosophers have introduced concepts (e.g., realization and supervenience) to assist in formulating the theses of materialism and dualism with more precision, and distinguished among importantly different versions of each view (e.g., eliminative materialism, substance dualism, and emergentism). They have also clarified the logic of arguments that use empirical findings to support materialism. Finally, they have devised various objections to materialism, objections that therefore serve also as arguments for dualism. These objections typically center around two features of mental states that materialism has had trouble in accommodating. The first feature is intentionality, the property of representing, or being about, objects, properties, and states of affairs external to the mental states. The second feature is phenomenal consciousness, the property possessed by many mental states of there being something it is like for the subject of the mental state to be in that mental state. WIREs Cogn Sci 2012, 3:281-292. doi: 10.1002/wcs.1174 For further resources related to this article, please visit the WIREs website. PMID:26301463

  18. Trace element analysis of soil type collected from the Manjung and central Perak

    NASA Astrophysics Data System (ADS)

    Azman, Muhammad Azfar; Hamzah, Suhaimi; Rahman, Shamsiah Abdul; Elias, Md Suhaimi; Abdullah, Nazaratul Ashifa; Hashim, Azian; Shukor, Shakirah Abd; Kamaruddin, Ahmad Hasnulhadi Che

    2015-04-01

    Trace elements in soils primarily originated from their parent materials. Parents' material is the underlying geological material that has been undergone different types of chemical weathering and leaching processes. Soil trace elements concentrations may be increases as a result of continuous input from various human activities, including power generation, agriculture, mining and manufacturing. This paper describes the Neutron Activation Analysis (NAA) method used for the determination of trace elements concentrations in part per million (ppm) present in the terrestrial environment soil in Perak. The data may indicate any contamination of trace elements contributed from human activities in the area. The enrichment factors were used to check if there any contamination due to the human activities (power plants, agricultural, mining, etc.) otherwise the values would serve as a baseline data for future study. The samples were collected from 27 locations of different soil series in the area at two different depths: the top soil (0-15cm) and the sub soil (15-30cm). The collected soil samples were air dried at 60°C and passed through 2 µm sieve. Instrumental Neutron Activation Analysis (NAA) has been used for the determination of trace elements. Samples were activated in the Nuclear Malaysia TRIGA Mark II reactor followed by gamma spectrometric analysis. By activating the stable elements in the samples, the elements can be determined from the intensities of gamma energies emitted by the respected radionuclides.

  19. Knowledge translation of the HELPinKIDS clinical practice guideline for managing childhood vaccination pain: usability and knowledge uptake of educational materials directed to new parents

    PubMed Central

    2013-01-01

    Background Although numerous evidence-based and feasible interventions are available to treat pain from childhood vaccine injections, evidence indicates that children are not benefitting from this knowledge. Unrelieved vaccination pain puts children at risk for significant long-term harms including the development of needle fears and subsequent health care avoidance behaviours. Parents report that while they want to mitigate vaccination pain in their children, they lack knowledge about how to do so. An evidence-based clinical practice guideline for managing vaccination pain was recently developed in order to address this knowledge-to-care gap. Educational tools (pamphlet and video) for parents were included to facilitate knowledge transfer at the point of care. The objectives of this study were to evaluate usability and effectiveness in terms of knowledge acquisition from the pamphlet and video in parents of newly born infants. Methods Mixed methods design. Following heuristic usability evaluation of the pamphlet and video, parents of newborn infants reviewed revised versions of both tools and participated in individual and group interviews and individual knowledge testing. The knowledge test comprised of 10 true/false questions about the effectiveness of various pain management interventions, and was administered at three time points: at baseline, after review of the pamphlet, and after review of the video. Results Three overarching themes were identified from the interviews regarding usability of these educational tools: receptivity to learning, accessibility to information, and validity of information. Parents’ performance on the knowledge test improved (p≤0.001) from the baseline phase to after review of the pamphlet, and again from the pamphlet review phase to after review of the video. Conclusions Using a robust testing process, we demonstrated usability and conceptual knowledge acquisition from a parent-directed educational pamphlet and video about

  20. New elements in teaching soil-landscape relationships

    NASA Astrophysics Data System (ADS)

    Sonneveld, M. P. W.

    2012-04-01

    A landscape is an area whose character is the result of the action and interaction of natural and/or human factors. Landscapes are fundamental spatial units for soil scientists working in the fields of soil survey and soil geography. For these scientists but also for those who use their products (e.g. maps), interrelations between geology, geomorphology, soil formation and derived soil patterns in relation to land use are keys to the understanding of landscape functions. Many of these relations have been documented in aging soil survey reports but these are often difficult to access. As a result, important and unique soil-landscape phenomena remain hidden for other environmental scientists or the general public. In the Netherlands, efforts have been undertaken to aggregate information from soil survey reports and recent scientific insights into a new book with the aim to teach students the basic elements in soil-landscape research and to provide insights into valuable earth phenomena that are in need of preservation and/or careful management. New elements include amongst others: - State-of-the-art graphics to show how basic soil forming factors such as climate (change), parent material and time are interrelated. - Detailed catenas for specific soil-landscape systems, showing the relations between geomorphology and soil genesis. - Combining traditional soil maps with high-resolution DEM data to make soil-landscape relations more explicit. - Indicating the extent and impacts of land use change using maps of land use history. With this approach, current insights into natural patterns of geodiversity and pedodiversity are documented and available as a resource for education but also for policy makers working in the fields of geoheritage.

  1. Soil Ecology of Coccidioides immitis at Amerindian Middens in California

    PubMed Central

    Lacy, George H.; Swatek, Frank E.

    1974-01-01

    Outbreaks of coccidioidomycosis and isolation of Coccidioides immitis have been reported from Amerindian middens. This study was undertaken to determine the most important ecological component(s) for the occurrence of C. immitis at archeological sites. Soils from 10 former Indian villages with no prior history of coccidioidal infection were collected and cultured. The physicochemical properties of the midden soils were compared with nonmidden soils and positive soils. The following theories for the sporadic distribution of the pathogen in the soil of the Lower Sonoran Life Zone were considered: (i) the Larrea tridentata (creosote bush) association, (ii) the preference for saline soils, (iii) isolation near rodent burrows, and (iv) animals as possible agents of dispersal. Results showed that a high percentage of the midden soils contained C. immitis, whereas none of the adjacent, nonmidden soils yielded the fungus. Physicochemical analyses revealed that the dark color and alkaline pH of the midden soils were due to past organic contamination. Repeated isolations were made from soils with low to moderate alkalinity. Alkalinity and sandy texture were consistent features of all soils in this study. However, the lack of any reports of nonsandy infested soils possibly indicates that the sandy texture and alkalinity may be factors in the distribution of this fungus. The organic content, soil parent material, and color were not important in the soil ecology. L. tridentata was not significant in the macroflora at the infested sites surveyed. Samples collected without reference to rodent burrows yielded a high percentage of recoveries. Animals, although not the major natural reservoir, cannot be ignored as possible factors in the ecology of C. immitis. Images PMID:4856715

  2. Evaluating SoilGen2 as a tool for projecting soil evolution induced by global change.

    PubMed

    Keyvanshokouhi, Saba; Cornu, Sophie; Samouëlian, Anatja; Finke, Peter

    2016-11-15

    To protect soils against threats, it is necessary to predict the consequences of human activities and global change on their evolution on a ten to hundred year time scale. Mechanistic modelling of soil evolution is then a useful tool. We analysed the ability of the SoilGen model to be used for projections of soil characteristics associated to various soil threats: vertical distributions of <2μm fraction, organic carbon content (OC), bulk density and pH. This analysis took the form of a functional sensitivity analysis in which we varied the initial conditions (parent material properties) and boundary conditions (co-evolution of precipitation and temperature; type and amount of fertilization and tillage as well as duration of agriculture). The simulated scenario variants comprised anthroposequences in Luvisols at two sites with one default scenario, six variants for initial conditions and 12 variants for boundary conditions. The variants reflect the uncertainties to our knowledge of parent material properties or reconstructed boundary conditions. We demonstrated a sensitivity of the model to climate and agricultural practices for all properties. We also conclude that final model results are not significantly affected by the uncertainties of boundary conditions for long simulations runs, although influenced by uncertainties on initial conditions. The best results were for organic carbon, although improvements can be reached through calibration or by incorporating a dynamic vegetation growth module in SoilGen. Results were poor for bulk density due to a fixed-volume assumption in the model, which is not easily modified. The <2μm fraction depth patterns are reasonable but the process of clay new formation needs to be added to obtain the belly shape of the Bt horizon. After calibration for organic carbon under agriculture, the model is suitable for producing soil projections due to global change. PMID:27470670

  3. Soil Organic Carbon Stocks in Depositional Landscapes of Bavaria

    NASA Astrophysics Data System (ADS)

    Kriegs, Stefanie; Schwindt, Daniel; Völkel, Jörg; Kögel-Knabner, Ingrid

    2016-04-01

    Erosion leads to redistribution and accumulation of soil organic matter (SOM) within agricultural landscapes. These fluvic and colluvic deposits are characterized by a highly diverse vertical structure and can contain high amounts of soil organic carbon (SOC) over the whole soil profile. Depositional landscapes are therefore not only productive sites for agricultural use but also influence carbon dynamics which is of great interest with regard on the recent climate change debate. The aim of our study is to elucidate the spatial distribution of organic carbon stocks, as well as its depth function and the role of these landscapes as a reservoir for SOM. Therefore we compare two representative depositional landscapes in Bavaria composed of different parent materials (carbonate vs. granitic). We hypothesize that the soils associated with different depositional processes (fluvial vs. colluvial) differ in SOC contents and stocks, also because of different hydromorphic regimes in fluvic versus colluvic soil profiles. Sampling sites are located in the Alpine Foreland (quaternary moraines with carbonatic parent material) and the foothills of the Bavarian Forest (Granite with Loess) with the main soil types Fluvisols, Gleysols and Luvisols. At both sites we sampled twelve soil profiles up to 150 cm depth, six in the floodplain and six along a vertical slope transect. We took undisturbed soil samples from each horizon and analyzed them for bulk density, total Carbon (OC and IC) and total Nitrogen (N) concentrations. This approach allows to calculate total OC contents and OC stocks and to investigate vertical and horizontal distribution of OC stocks. It will also reveal differences in OC stocks due to the location of the soil profile in fluvic or colluvic deposition scenarios.

  4. Perceived Parenting

    ERIC Educational Resources Information Center

    Wouters, Sofie; Doumen, Sarah; Germeijs, Veerle; Colpin, Hilde; Verschueren, Karine

    2013-01-01

    Contingent self-esteem (i.e., the degree to which one's self-esteem is dependent on meeting particular conditions) has been shown to predict a wide range of psychosocial and academic problems. This study extends previous research on contingent self-esteem by examining the predictive role of perceived parenting dimensions in a sample of early…

  5. Parental Monitoring

    ERIC Educational Resources Information Center

    Shillington, Audrey M.; Lehman, Stephanie; Clapp, John; Hovell, Melbourne; Sipan, Carol; Blumberg, Elaine

    2005-01-01

    Adolescence is a developmental period during which many youth experiment with risk practices. This paper examined the association of parental monitoring with a range of alcohol and other drug (AOD) use behaviors among high-risk youth, while controlling for other demographic and environmental variables previously found to be associated with AOD…

  6. Total Parenting

    ERIC Educational Resources Information Center

    Smith, Richard

    2010-01-01

    In this essay, Richard Smith observes that being a parent, like so much else in our late-modern world, is required to become ever more efficient and effective, and is increasingly monitored by the agencies of the state, often with good reason given the many recorded instances of child abuse and cruelty. However, Smith goes on to argue, this begins…

  7. Constructive Parenting.

    ERIC Educational Resources Information Center

    Goldberg, Sally

    This book turns important research and theory into essential, easy-to-follow guidelines for new parents and child care providers to help them focus on the critical first 3 years of life to build a strong foundation for the future. All the key areas of child development are covered, including self-esteem, and cognitive, motor and social…

  8. Homicidal parents.

    PubMed

    Bourget, D; Bradford, J M

    1990-04-01

    This paper describes a series of 13 cases of parents who have killed their children. A review of the literature suggests that child murder is infrequent and committed in most instances by the parents. Most attention has been directed to the universal phenomenon of child abuse. The killing of a child in our culture is viewed much more seriously than the killing of a newborn infant, legally defined as infanticide. Only a few authors have reported on the former, and their studies tend to demonstrate that a higher proportion of these crimes are perpetrated by mothers. Homicidal behaviour in parents may also be associated with common forms of psychiatric disorders and may manifest as the extended suicide phenomenon (homicide reported with major depressive illness). Attributes of both parents and the children are also significant factors to be considered. In a retrospective study the relevant demographic and clinical data of a series of 13 cases are reviewed. The diagnostic classification using DSM-III-R is discussed in detail. A higher incidence of maternal perpetrators was found and is consistent with previous studies. Exposure to a variety of psychosocial stresses appears to have been a major factor. Similarly the suicidal history and behaviour of the subjects is significant. Affective disorder appears to be an important diagnostic category. Finally, the role of psychiatric and other social agencies is considered in relation to the murder of children. A better understanding of this phenomenon is indicated in order to help us deal with families at risk. PMID:2340456

  9. National Soil Information System in Turkey

    NASA Astrophysics Data System (ADS)

    Emrah Erdogan, Hakki; Sahin, Mehmet; Sahin, Yuksel

    2013-04-01

    Land consolidation (LC) represents complexity if management, legal, economic and technical procedures realized in order to adjust the land structure according to actual human preferences and needs. It includes changes in ownership rights to land and other real estate property, exchange of parcels among owners, changes in parcel borders, parcel size and shape, joining and dividing of parcels, changes in land use, construction works as roads, bridges, water changes etc.. Since the subject of LC is agricultural lands, the quality of consolidation depends on the quality of soil data. General Directorate of Agrarian Reform (GDAR) is the responsible institution on land consolidation whole of Turkey. Under GDAR, National Soil Information System (NSIS) has been build up with base soil data in relevant scale (1:5000). NSIS contain detailed information on soil chemical and physical properties, current land use, parent material, land capability class, Storie Index Values. SI were used on land consolidation, land use planning and farm development services. LCC was used for land distribution, rental land; define of village settlement, consolidation, expropriation, reconstruction, reclamation, non-agricultural usage. LCC were also specified to subclasses in four different limited factors as i) flow and erosion risk ii) requirement of drainage and soil moisture iii) Limits of soil tillage and root (shallow soils, low water retention capacity, stony, salty .etc) iv) climatic limits. In this study, digital soil survey and mapping project located in Yumurtalik, Adana is presented as an example of NSIS data structure. The project cover an area of 45709 ha that include crop lands as an area of 28528 ha and other land use (urban, roads..etc) as an area of 17181 ha. Soil profiles were described in 45 different points and totally 1279 soil samples were collected in field study and the check bore hole were made in 3170 points.

  10. Lateral diversity of regolith and soils under a mountain slope - implications for interpretation of hillslope materials and processes, Central Sudetes, SW Poland

    NASA Astrophysics Data System (ADS)

    Migoń, Piotr; Kacprzak, Andrzej

    2014-09-01

    A recent forestry road cut on the slopes of Mt Wysoka (Sudetes Mountains, Central Europe) exposed a 1.6 km-long, nearly continuous outcrop of hillslope regolith. The regolith is divided into two main parts. The lower one is made of disintegrated tuff, while the upper part, from less than 1 m to at least 3 m thick, includes five different lithological types which combine to form recurring layered vertical sequences of cover materials. This upper part is markedly transformed by pedogenesis. The main aims of the paper are to examine and explain vertical and lateral diversity of these cover materials and to review the findings in the context of their origin and age. Methods included field regolith mapping and soil research followed by basic laboratory analyses of soil properties, including particle size distribution, pH and organic carbon content. Topmost fine-grained and coarse open-work surface materials have been subject to some, although limited downslope transport, while the underlying layers, although lithologically different, are interpreted as mainly products of bedrock weathering and pedogenic alterations, with minimal downslope movement. Slope corrugation into shallow hollows, indistinct spurs and long sections of planar slope exerts an effect on hillslope materials and soil-forming processes via pathways of groundwater circulation. Open-work structures are mainly products of preferential eluviation. Periglacial inheritance in the regolith is uncertain and these layered materials should not be interpreted as indicators of changing environmental conditions in the late Pleistocene. Regional models of hillslope covers do not fit the complexity of regolith present on Mt Wysoka. Generalizations about hillslope materials are better avoided if a limited number of outcrops is investigated.

  11. Influence of perennial plants on chemical properties of arid calcareous soils in Iran

    SciTech Connect

    Karimian, N.; Razmi, K. )

    1990-10-01

    The authors conducted a study in Bajgah to determine the influence of perennial plants on some selected properties of soils formed on the highly calcareous parent material. The major plant genera were determined to be Agropyron, Artemisia, Astragalus, Dianthus, Eryngium, Peganum, Polygonum, Stipa, and Thymus. Tops of plants genera were found to be significantly different in ash, N, P, K, Ca, Mg, Na, Mn, Zn, and Cu; the concentration of Fe was not significantly different. The authors found the plants to differ significantly in their influence on soil properties. Peganum caused an accumulation of organic matter (OM) as high as 7% in the soil, in an environment where the soils typically contain less than 1% OM. Soil concentrations of P, K, Mn, Zn, and Cu were also found to vary significantly beneath different plant genera. They suggest these differences in OM accumulation were caused by plant litter. Concentration of Fe in the soils formed beneath different plant genera was statistically unchanged.

  12. Conserving Soil. Revised.

    ERIC Educational Resources Information Center

    Soil Conservation Service (USDA), Washington, DC.

    This book of enrichment materials is an interdisciplinary study of soil designed for students in grades 6-9. The materials are presented in three units. Unit 1 contains eight activities in which students investigate soil science and study the social impact of soil by examining the history of land use by local Native Americans. Unit 2 contains 10…

  13. Adolescents' and Parents' Conceptions of Parental Authority

    ERIC Educational Resources Information Center

    Smetana, Judith G.

    1988-01-01

    Children ranging from fifth to twelfth grade, and their parents, were presented with items pertaining to family transgressions and asked to judge the legitimacy of parental jurisdiction, justify its wrongness or permissibility, and assess its contingency on parental authority. (PCB)

  14. Stuffing Carbon Away: Mechanisms of Carbon Sequestration in Soils

    SciTech Connect

    Reimer, P J; Masiello, C A; Southon, J R; Trumbore, S E; Harden, J W; White, A F; Chadwick, O A; Torn, M S

    2003-01-24

    Soils offer the potential to sequester large quantities of carbon from the atmosphere for decades to millennia and so may ameliorate the anthropogenic influence of fossil fuel release. However changes in climate can drastically affect the soil's ability to store carbon through changes mineralogy on time scales of human interest. It is essential to understand the major controls on soil carbon dynamics before we attempt to manage sequestration to control atmospheric CO{sub 2} buildup. Models of the terrestrial carbon cycle often use clay content to parameterize soil carbon turnover. Evidence from volcanic soils suggests that soil mineralogy is a major control on a soil's ability to store carbon, because different types of minerals have widely varying abilities to physically and chemically isolate soil organic matter from decomposition, however volcanic soils represent only a small percentage of the earth's soils. The relationship between precipitation and soil carbon storage is also complex and poorly constrained. Significantly, precipitation changes predicted as a result of atmospheric CO{sub 2} doubling include increased rainfall throughout California. We utilized {sup 14}C, {delta}{sup 13}C, and the total organic carbon, iron, and aluminum contents to address the question of the importance of mineralogy and climate on carbon storage in soils formed on a globally representative parent material. The California coastal terraces, formed over the last 500 thousand years as a result of tectonic uplift and sea level change, provide a natural laboratory to examine the effect of mineralogy and climate on carbon storage. We have focused on two terraces sequences, one near Eureka and one near Santa Cruz. Within each set of terraces only soil mineral development varies; all other variables are constant (rainfall, plant systems, and soil parent material, and land management). Annual precipitation at Eureka is twice that at Santa Cruz, allowing us to examine its role in the

  15. Soil development over millennial timescales - a comparison of soil chronosequences of different climates and lithologies

    NASA Astrophysics Data System (ADS)

    Sauer, D.; Schülli-Maurer, I.; Wagner, S.; Scarciglia, F.; Sperstad, R.; Svendgård-Stokke, S.; Sørensen, R.; Schellmann, G.

    2015-07-01

    This paper reports soil development over time in different climates, on time-scales ranging from a few thousand to several hundred thousand years. Changes in soil properties over time, underlying soil-forming processes and their rates are presented. The paper is based on six soil chronosequences, i.e. sequences of soils of different age that are supposed to have developed under the similar conditions with regard to climate, vegetation and other living organisms, relief and parent material. The six soil chronosequences are from humid-temperate, Mediterranean and semi-arid climates. They are compared with regard to soil thickness increase, changes in soil pH, formation of pedogenic iron oxides (expressed as Fed/Fet ratios), clay formation, dust influx (both reflected in clay/silt ratios), and silicate weathering and leaching of base cations(expressed as (Ca+Mg+K+Na)/Al molar ratios) over time. This comparison reveals that the increase of solum thickness with time can be best described by logarithmic equations in all three types of climates. Fed/Fet ratios (proportion of pedogeniciron Fed compared to total iron Fet) reflects the transformation of iron in primary minerals into pedogeniciron. This ratio usually increases with time, except for regions, where the influx of dust (having low Fed/Fet ratios) prevails over the process of pedogeniciron oxide formation, which is the case in the Patagonian chronosequences. Dust influx has also a substantial influence on the time courses of clay/silt ratios and on element indices of silicate weathering. Using the example of a 730 kasoil chronosequence from southern Italy, the fact that soils of long chronosequences inevitably experienced major environmental changes is demonstrated, and, consequentially a modified definition of requirements for soil chronosequences is suggested. Moreover, pedogenic thresholds, feedback systems and progressive versus regressive processes identified in the soil chronosequences are discussed.

  16. Geochemistry of the Paleocene-Eocene and Miocene-Pliocene clayey materials of the eastern part of the Wouri River (Douala sub-basin, Cameroon): Influence of parent rocks

    NASA Astrophysics Data System (ADS)

    Ngon Ngon, G. F.; Mbog, M. B.; Etame, J.; Ntamak-Nida, M. J.; Logmo, E. O.; Gerard, M.; Yongue-Fouateu, R.; Bilong, P.

    2014-03-01

    Major and trace element concentrations of clay deposits of the Missole II and Bomkoul respectively from the Paleocene-Eocene N'Kapa Formation and the Miocene-Pliocene-Matanda-Wouri Formation in the eastern part of the Wouri River in the Douala sub-basin of Cameroon have been investigated to identify the parent rocks. To carry out this study, X-ray diffraction, inductively coupled plasma-atomic emission spectrometry (ICP/AES) and inductively coupled plasma-mass spectrometry (ICP/MS) were performed to determine respectively the mineralogical and chemical data of Missole II and Bomkoul clayey materials. Clay sediments are essentially kaolinitic and illitic, and kaolinitic and smectitic respectively in both sites. They are generally siliceous, aluminous with small iron and bases (MgO, CaO, Na2O, and K2O) contents. Samples of Missole II profiles are more siliceous than those from the Bomkoul grey and dark grey clayey materials. Clayey materials have high Chemical Index of Alteration (CIA = 80-99.34) which suggests that they are strongly weathered under humid tropical climate before and after their deposition in the coastal plain. The value of Eu/Eu* (0.48-0.61), La/Sc (2.15-20.50), Th/Sc (0.74-2.25), Th/Co (1.08-8.33), and Cr/Th (5.24-13.55) ratios support essentially a silicic or felsic parent rocks. Total REE concentrations reflect the variations in their grain-size fractions. Chondrite-normalised REE patterns with LREE enrichment, flat HREE, and negative Eu anomaly are attributed essentially to silicic or felsic parent rocks like those from weathered materials developed from the gneisses around the coastal plain in the littoral part of Cameroon (Noa Tang et al., 2012), main characteristic of Paleocene-Eocene and Miocene-Pliocene clay sediments of Missole II and Bomkoul areas.

  17. Can Low Water/Rock Hydrothermal Alteration of Impact Materials Explain the Rock Component of the Martian Soil?

    NASA Technical Reports Server (NTRS)

    Nelson, M. J.; Newsom, H. E.

    2003-01-01

    The martian regolith is a globally homogenized product of chemical and aeolian weathering processes. The soil is thought to consist of a rock component, with lesser amounts of mobile elements (Ca, Na, and K) than a presumed protolith, and a salt or mobile element component enriched in sulfur and chlorine. In this study we consider the contributions of hydrothermal processes to the origin of the rock component of the martian soil.

  18. Parent Discussion Manual: Parent/Child Home Stimulation. The Marshalltown Project. Revised July 1975.

    ERIC Educational Resources Information Center

    Marshall-Poweshiek Joint County School System, Marshalltown, IA. Dept. of Special Education.

    Intended for parents, the manual is for a 12 week parent education course on the mental stimulation of young handicapped children. Major objectives of the course are helping the child feel positively about himself and helping the child develop his intellectual abilities. Material reinforcements are offered parents who meet criteria for attendance,…

  19. Mercury content of Illinois soils

    USGS Publications Warehouse

    Dreher, G.B.; Follmer, L.R.

    2004-01-01

    For a survey of Illinois soils, 101 cores had been collected and analyzed to determine the current and background elemental compositions of Illinois soils. Mercury and other elements were determined in six samples per core, including a surface sample from each core. The mean mercury content in the surface samples was 33 ?? 20 ??g/kg soil, and the background content was 20 ?? 9 ??g/kg. The most probable sources of mercury in these soils were the parent material, and wet and dry deposition of Hg0 and Hg2+ derived from coal-burning power plants, other industrial plants, and medical and municipal waste incinerators. Mercury-bearing sewage sludge or other fertilizers applied to agricultural fields could have been the local sources of mercury. Although the mercury content correlated with organic carbon content or clay content in individual cores, when all the data were considered, there was no strong correlation between mercury and either the organic carbon or the clay-size content.

  20. Spatial variability of available soil microelements in an ecological functional zone of Beijing.

    PubMed

    Ye, Huichun; Shen, Chongyang; Huang, Yuanfang; Huang, Wenjiang; Zhang, Shiwen; Jia, Xiaohong

    2015-02-01

    Understanding the spatial variability of soil microelements and its influencing factors is of importance for a number of applications such as scientifically formulated fertilizer and environmental protection. This study used descriptive statistics and geostatistics to investigate the spatial variability of available soil Fe, Mn, Cu, and Zn contents in agricultural topsoil (0-20 cm) in an ecological functional zone located at Yanqing County, Beijing, China. Kriging method was applied to map the spatial patterns of available soil Fe, Mn, Cu, and Zn contents. Results showed that the available soil Cu had a widest spatial correlation distance (e.g., 9.6 km), which for available soil Fe, Mn, and Zn were only 1.29, 2.58, and 0.99 km, respectively. The values of C 0/sill for available soil Fe and Zn were 0.12 and 0.11, respectively, demonstrating that the spatial heterogeneity was mainly due to structural factors. The available soil Mn and Cu had the larger values of C 0/sill (i.e., 0.50 and 0.44 for Mn and Cu, respectively), which showed a medium spatial correlation. Mapping of the spatial patterns of the four microelements showed that the decrease trend of available soil Fe and Mn were from northeast to southwest across the study area. The highest amount of available soil Cu was distributed in the middle of the study area surrounding urban region which presented as a "single island". The highest amount of available soil Zn was mainly distributed in the north and south of the study area. One-way analysis of variance for the influencing factors showed that the lithology of parental materials, soil organic matter, and pH were important factors affecting spatial variability of the available microelements. The topography only had a significant influence on the spatial variability of available soil Fe and Mn contents, parental materials, and the land use types had little influence on the spatial variability. PMID:25619696

  1. Fine-resolution multiscale mapping of clay minerals in Australian soils measured with near infrared spectra

    NASA Astrophysics Data System (ADS)

    Viscarra Rossel, R. A.

    2011-12-01

    Clay minerals are the most reactive inorganic components of soils. They help to determine soil properties and largely govern their behaviors and functions. Clay minerals also play important roles in biogeochemical cycling and interact with the environment to affect geomorphic processes such as weathering, erosion and deposition. This paper provides new spatially explicit clay mineralogy information for Australia that will help to improve our understanding of soils and their role in the functioning of landscapes and ecosystems. I measured the abundances of kaolinite, illite and smectite in Australian soils using near infrared (NIR) spectroscopy. Using a model-tree algorithm, I built rule-based models for each mineral at two depths (0-20 cm, 60-80 cm) as a function of predictors that represent the soil-forming factors (climate, parent material, relief, vegetation and time), their processes and the scales at which they vary. The results show that climate, parent material and soil type exert the largest influence on the abundance and spatial distribution of the clay minerals; relief and vegetation have more local effects. I digitally mapped each mineral on a 3 arc-second grid. The maps show the relative abundances and distributions of kaolinite, illite and smectite in Australian soils. Kaolinite occurs in a range of climates but dominates in deeply weathered soils, in soils of higher landscapes and in regions with more rain. Illite is present in varied landscapes and may be representative of colder, more arid climates, but may also be present in warmer and wetter soil environments. Smectite is often an authigenic mineral, formed from the weathering of basalt, but it also occurs on sediments and calcareous substrates. It occurs predominantly in drier climates and in landscapes with low relief. These new clay mineral maps fill a significant gap in the availability of soil mineralogical information. They provide data to for example, assist with research into soil

  2. Soil moisture: Some fundamentals. [agriculture - soil mechanics

    NASA Technical Reports Server (NTRS)

    Milstead, B. W.

    1975-01-01

    A brief tutorial on soil moisture, as it applies to agriculture, is presented. Information was taken from books and papers considered freshman college level material, and is an attempt to briefly present the basic concept of soil moisture and a minimal understanding of how water interacts with soil.

  3. The Soil Is Alive!

    ERIC Educational Resources Information Center

    Science and Children, 1989

    1989-01-01

    Describes activities which demonstrate the abundance of organisms living underground. Provides outlined directions, lists of materials, and a soil ecosystem transparency for delving into the properties of soil. (RT)

  4. Many Parents?

    NASA Astrophysics Data System (ADS)

    Maseng, Torleiv; Moxnes, John F.

    2015-06-01

    In all living species at most, two parents are needed in order to make an offspring. In this paper, we assume that N parents are needed, and we calculate the optimum N in terms of fitness using a simple probabilistic approach. The probability of finding an attractive partner is set to P. The probability that this partner gives increased fitness is set to 1- R. We show that the best number of partners is N = 2 for any value of R as long as 1/2 < P < 2/3. For P < 1/2, the most beneficial is N = 1 partner. As P increases, there exists an optimum number of partners N > 2.

  5. The Process of Parenting.

    ERIC Educational Resources Information Center

    Brooks, Jane B.

    Written to help couples prepare for parenthood and to improve the effectiveness of parents, this book provides extensive guidelines and background information for accomplishing the basic tasks of parenting. Chapter One depicts parenting as a process, delineates parents' tasks and describes how parents learn to be parents. Based on Erikson's theory…

  6. Effects of aqueous extract of soil-like substrate made from three different materials on seed germination and seedling growth of rice

    NASA Astrophysics Data System (ADS)

    Shao, Lingzhi; Fu, Yuming; Fu, Wenting; Yan, Min; Li, Leyuan; Liu, Hong

    2014-03-01

    Biologically processing rice and wheat straws into soil-like substrate (SLS) and then reusing them in plant cultivation system to achieve waste recycle is very crucially important in Bioregenerative life support system (BLSS). However, rice is a plant with strong allelopathic potential. It is not clear yet that what kinds of raw materials can be processed into proper SLS to grow rice in BLSS. Therefore, in this study, the aqueous extract of SLS made from three different materials including rice straw, wheat straw and rice-wheat straw mixture was utilized to investigate its effects on the seed germination and seedling growth of rice. The gradients of the extract concentrations (soil:water) were 1:3, 1:5, 1:9, and 1:15 with deionized water used as control. The effects of different types of SLS on seed germination and seedling vitality of rice were confirmed by analyzing the germination rate, seedling length, root length, the fresh weight and other indicants. In addition, based on the analysis towards pH, organic matter composition and other factors of the SLS as well as the chlorophyll, hormone content of rice, and the mechanism of the inhibition was speculated in order to explore the preventive methods of the phenomenon. Finally, the feasibility of cultivating rice on SLSs made from the raw materials mentioned above was evaluated and wheat raw was determined as the most appropriate material for growing rice.

  7. Thermal performance of soils and backfills in horizontal ground coupled heat pump system applications. Final report

    SciTech Connect

    1998-04-01

    The goal of this research was to address the appropriateness of different soils, in an unsaturated state, for placement adjacent to the buried heat exchanger for GSHP systems. Soils for the study were selected based on an analysis of common soil parent materials that exist in the US in conjunction with the current EPRI soil thermal classification system. Six soils were chosen (Cecil (clay), Fordville (sand), Kranzburg (loam), Moody (silt), Sharpsburg (silt) and Vienna (sandy loam)) which provided at least one soil in each of the EPRI classifications. Initial laboratory studies were concentrated on determination of basic physical, water holding and thermal properties of each soil. Each soil was evaluated for ability to sustain thermal contact conductance under thermal loading, and comparison of the results allowed the soils to be ranked, best to worst. Additional laboratory studies were performed on each soil to rate the long-term thermal performance of each relative to potential for drying adjacent to the heat exchanger along with reduction in heat transfer rate due to soil drying. Tests were conducted over a range of initial water contents and densities that would be common for each soil. Results were used to verify a theoretical analysis of the thermal stability of each soil, based on texture, and to rank each soil according to thermal performance under extended thermal load. Results of the thermal conductivity tests, the thermal contact conductance tests and the thermal performance tests were utilized to propose a thermal performance index (TPI) for soils based on texture. The final soil ranking were then expressed relative to the EPRI soil thermal classification system which identified clay as best, followed by loam, sandy loam, silt, and sand.

  8. Use of 13C labeling to assess carbon partitioning in transgenic and nontransgenic (parental) rice and their rhizosphere soil microbial communities.

    PubMed

    Wu, Wei Xiang; Liu, Wei; Lu, Hao Hao; Chen, Ying Xu; Medha, Devare; Janice, Thies

    2009-01-01

    Photosynthetic assimilation of CO2 is a primary source of carbon in soil and root exudates and can influence the community dynamics of rhizosphere organisms. Thus, if carbon partitioning is affected in transgenic crops, rhizosphere microbial communities may also be affected. In this study, the temporal effects of gene transformation on carbon partitioning in rice and rhizosphere microbial communities were investigated under greenhouse conditions using the 13C pulse-chase labeling method and phospholipid fatty acid (PLFA) analysis. The 13C contents in leaves of transgenic (Bt) and nontransgenic (Ck) rice were significantly different at the seedling, booting and heading stages. There were no detectable differences in 13C distribution in rice roots and rhizosphere microorganisms at any point during rice development. Although a significantly lower amount of Gram-positive bacterial PLFAs and a higher amount of Gram-negative bacterial PLFAs were observed in Bt rice rhizosphere as compared with Ck at all plant development stages, there were no significant differences in the amount of individual 13C-PLFA between Bt and Ck rhizospheres at any growing stage. These findings indicate that the insertion of cry1Ab and marker genes into rice had no persistent or adverse effect on the photosynthate distribution in rice or the microbial community composition in its rhizosphere. PMID:19049503

  9. Magnetic and Geochemical Properties of Andic Soils from the Massif Central, France

    NASA Astrophysics Data System (ADS)

    Grison, H.; Petrovsky, E.; Dlouha, S.; Kapicka, A.

    2014-12-01

    -mineralogy along the soil profiles. Influence of the weathering processes on all the measured parameters is discussed. Soil genesis is influenced by several factors, where the moisture is more important than the age of the parent material. Acknowledgement: This study was supported by Czech Science Foundation through grant No 13-10775S.

  10. Soil magnetic properties in Bulgaria at a national scale-Challenges and benefits

    NASA Astrophysics Data System (ADS)

    Jordanova, Neli; Jordanova, Diana; Petrov, Petar

    2016-02-01

    Establishing topsoil magnetic database at a national scale provides important information for soil classification, evaluation of soil drainage, indirect estimation of the total soil carbon and initial planning in precision agriculture. The Bulgarian database consists of 511 topsoil samples from the upper 20 cm of natural unpolluted soils. Samples have been characterized by detailed magnetic measurements, including mass-specific magnetic susceptibility, frequency dependent magnetic susceptibility, anhysteretic remanence, isothermal remanence and their ratios, hysteresis parameters and ratios, as well as soil reaction (pH). Histograms of the measured parameters per soil type and for the whole database show specific peculiarities and dependence from various parameters. Statistical factor analysis revealed that 87% from the total variance can be explained by four factors. The main factor is dominated by the contribution from concentration-dependent magnetic parameters, second one reflects the role of fine-grained pedogenic magnetic fraction, the third one is determined by the properties of the parent material, fourth one is governed by the internal structural peculiarities of the magnetic particles. The results from cluster analysis reveal the role of soil type and geology for the observed magnetic characteristics. The results emphasize the major role of geology (parent material) for the magnetic signature of topsoil samples on a national scale using sampling density of 1 sample/200 km2. Spatial interpolation of different magnetic parameters using modelled experimental variograms and kriging algorithm highlight lateral peculiarities in the concentration and grain size of the strongly magnetic iron oxides in the topsoils. Additional geochemical data for selected set of samples and meteorological information reveal the role of climate characteristics (mean annual temperature and precipitation) on the formation and development of the strongly magnetic pedogenic fraction

  11. Worldwide organic soil carbon and nitrogen data

    SciTech Connect

    Zinke, P.J.; Stangenberger, A.G.; Post, W.M.; Emanuel, W.R.; Olson, J.S.

    1984-05-01

    A compilation of soil carbon and nitrogen storage data for more than 3500 soil profiles from under natural vegetation or relatively undisturbed sites is presented in this report. A summary table of the carbon and nitrogen storage in a pedon of surface cubic meter for each soil profile, as well as location, elevation, climate, parent material, and vegetation information, are presented. The data were used to determine average carbon and nitrogen storage on land surfaces of the world. Calculations were also made of storage related to climatic classifications, ecosystem clasifications, and latitudinal increments from the equator to 75/sup 0/. Carbon (kg.m/sup -3/) varies from 2 in hot dry climates, through 10 in many cold dry or seasonally moist (warm or hot) climates, to more than 30 in wet alpine or subpolar climates. Nitrogen storage, an order of magnitude smaller than carbon storage in soils, shows broad parallels but exceeds 1600 g.m/sup -3/ for subtropical/tropical premontane or lower montane soils, as well as alpine or subpolar wet soils. Such limiting conditions, defined by a balance of income and loss rates for mature soil profiles, also explain much of the variation among major ecosystem complexes whose soils are partly disturbed, incompletely recovered, or imperfectly known regarding their maturity and stability. Classifying profiles into Holdridge life zones and using appropriate life zone areas, we estimate 1309 x 10/sup 15/ g carbon and 92 x 10/sup 15/ g nitrogen in the world's soils. Alternatively, using average organic carbon and nitrogen densities from one degree latitude bands multiplied by the earth's surface area in the respective bands, we arrive at 1728 x 10/sup 15/ g of carbon and 117 x 10/sup 15/ g of nitrogen. Inadequacies that lead to the disparate estimates are discussed. 123 references, 5 figures, 7 tables.

  12. Parenting Styles and Beliefs about Parental Authority.

    ERIC Educational Resources Information Center

    Smetana, Judith G.

    1994-01-01

    Suggests that models of parenting style, such as Baumrind's popular model, are insensitive to variations in parenting resulting from characteristics of the different situations in which the parenting is expressed. Argues that considering parenting in context adds greater specificity to the model and enhances the potential for predicting child…

  13. 2000 years of paddy soil development - gain and loss of soil carbon

    NASA Astrophysics Data System (ADS)

    Koelbl, A.; Kalbitz, K.; Fiedler, S.; Braeuer, T.; Grootes, P. M.; Cao, Z.; Jahn, R.; Vogelsang, V.; Wissing, L.; Koegel-Knabner, I.

    2010-12-01

    The long-term impact of lowland rice growing on C stocks in soils was evaluated in the coastal region of subtropical China. During the past 2000 years new farmland was created through consecutive land reclamation by protective dikes, providing a unique chronosequence of soil formation under agricultural use. Parts of the land were used for paddy rice, other parts for a variety of non-irrigated crops, allowing study of the C dynamics of paddy soil development in direct comparison to soils not used for lowland rice cultivation (non-paddy). Beside one soil profile at the mudflat, which represents the parent material, soil profiles of the chronosequence were sampled by horizon in triplicate, ranging from 50 to 2000 years of paddy soil use and from 50 to 700 year old non-paddy soils. All samples were analysed for 14C concentrations and for bulk density, total C (TC) as well as organic C (OC) and inorganic C (IC) concentrations, and the corresponding stocks were calculated. In addition, topsoils were subjected to a physical fractionation procedure to evaluate changes of OC saturation in particle size fractions during soil development. In the first 300 years, rice cultivation did not significantly change TC stocks of the soils compared to that of non-paddy soils. The fast decalcification in paddy soils was compensated by a similar gain of OC in the topsoil. Higher 14C concentrations indicate the original C of the sediment in paddy topsoils was replaced faster by recently photosynthesized C than in non-paddy topsoils. OC accumulation in paddy topsoils appears to be complete after 300 years. High increases of OC in paddy topsoils may be due to high OC inputs associated with retarded decomposition during flooding of paddy fields. After 300 years, the decalcification in paddy soils was not compensated anymore by further enrichment of OC in the topsoil. In addition, the paddy soils lost OC in the subsoil. The dense plough pan decreases OC transport from the paddy topsoil into

  14. Major element composition of glasses in three Apollo 15 soils.

    NASA Technical Reports Server (NTRS)

    Reid, A. M.; Warner, J.; Ridley, W. I.; Brown, R. W.

    1972-01-01

    Approximately 180 glasses in each of three Apollo 15 soils have been analyzed for nine elements. Cluster analysis techniques allow the recognition of preferred glass compositions that are equated with parent rock compositions. Green glass rich in Fe and Mg, poor in Al and Ti may be derived from deep-seated pyroxenitic material now present at the Apennine Front. Fra Mauro basalt (KREEP) is most abundant in the LM soil and is tentatively identified as ray material from the Aristillus-Autolycus area. Highland basalt (anorthositic gabbro), believed to be derived from the lunar highlands, has the same composition as at other landing sites, but is less abundant. The Apennine Front is probably not true highland material but may contain a substantial amount of material with the composition of Fra Mauro basalt, but lacking the high-K content.

  15. Rehabilitation materials from surface- coal mines in western USA. I. Chemical characteristics of spoil and replaced cover-soil.

    USGS Publications Warehouse

    Severson, R.C.; Gough, L.P.

    1983-01-01

    A range of at least one order of magnitude was observed for DTPA-extractable Cd, Cu, Fe, Mn, Ni, Pb and Zn and organic matter content of samples of spoil and cover-soil from eleven western USA surface-coal mines. The observed pH of these samples ranged from 3.9 to 8.9; however, most samples were near-neutral to alkaline in reaction. Most constituent levels were found to be below proposed guidelines for maximum permissible levels in mine soil. -from Authors

  16. Ambient trace element background concentrations in soils and their use in risk assessment.

    PubMed

    Díez, M; Simón, M; Martín, F; Dorronsoro, C; García, I; Van Gestel, C A M

    2009-08-01

    The definition of ambient background concentrations (ABCs) is used in this study to assess the potential environmental risk of trace elements in soils and parent materials from Granada, Spain. Two different layers of soil (0-20 and 20-40 cm) and parent material samples were collected at 93 sites. From cumulative frequency distribution curves, ABCs for As, Co, Cu, Cr, Ni, Pb and Zn were estimated at 3.5-20, 7-23, 13-25.6, 29-66, 7-20, 15-36, and 5.5-76 mg kg(-1), respectively. Tukey box-plots were used to discriminate different concentration classes and identify potentially contaminated sites. Weakly-weathered soils (Entisols) over carbonate materials showed the lowest background contents, the most developed soils (Alfisols) over metamorphic rocks the highest ones. Outliers were mainly found near a former iron mine where arsenic concentrations were by far exceeding the corresponding regional ABC. These soils were however, not toxic to Escherichia coli and Vibrio fischeri. The prediction of site-specific ABCs together with bioavailability and toxicity assessment is a valuable tool for giving further insight into the risk of trace elements in soils. PMID:19473692

  17. Amount of organic matter required to induce sulfate reduction in sulfuric material after re-flooding is affected by soil nitrate concentration.

    PubMed

    Yuan, Chaolei; Mosley, Luke M; Fitzpatrick, Rob; Marschner, Petra

    2015-03-15

    Acid sulfate soils (ASS) with sulfuric material can be remediated through microbial sulfate reduction stimulated by adding organic matter (OM) and increasing the soil pH to >4.5, but the effectiveness of this treatment is influenced by soil properties. Two experiments were conducted using ASS with sulfuric material. In the first experiment with four ASS, OM (finely ground mature wheat straw) was added at 2-6% (w/w) and the pH adjusted to 5.5. After 36 weeks under flooded conditions, the concentration of reduced inorganic sulfur (RIS) and pore water pH were greater in all treatments with added OM than in the control without OM addition. The RIS concentration increased with OM addition rate. The increase in RIS concentration between 4% and 6% OM was significant but smaller than that between 2% and 4%, suggesting other factors limited sulfate reduction. In the second experiment, the effect of nitrate addition on sulfate reduction at different OM addition rates was investigated in one ASS. Organic matter was added at 2 and 4% and nitrate at 0, 100, and 200 mg nitrate-N kg(-1). After 2 weeks under flooded conditions, soil pH and the concentration of FeS measured as acid volatile sulfur (AVS) were lower with nitrate added at both OM addition rates. At a given nitrate addition rate, pH and AVS concentration were higher at 4% OM than at 2%. It can be concluded that sulfate reduction in ASS at pH 5.5 can be limited by low OM availability and high nitrate concentrations. Further, the inhibitory effect of nitrate can be overcome by high OM addition rates. PMID:25600239

  18. Employment of a novel magnetically multifunctional purifying material for determination of toxic highly chlorinated polychlorinated biphenyls at trace levels in soil samples.

    PubMed

    Zhang, Jiabin; Pan, Muyun; Gan, Ning; Cao, Yuting; Wu, Dazhen

    2014-10-17

    In this study, we developed a magnetically multifunctional purifying material for efficient removal of matrix interferences, especially certain organochlorine pesticide (DDT, DDE, and DDD), during the determination of toxic highly chlorinated polychlorinated biphenyls (PCBs) at trace levels in soil samples. The multifunctional adsorbent (CMCD-NH2-MNPs) was prepared by grafting carboxymethyl-β-cyclodextrin on the surface of amino-functionalized magnetite (Fe3O4) nanoparticles. CMCD-NH2-MNPs has stronger host-guest complexation with DDT, DDE, and DDD, but the same adsorbent shows weaker adsorption ability toward highly chlorinated PCBs (from tetra- to octa-chlorinated PCBs) owing to their steric hindrance effect. Based on this principle, a simple and rapid gas chromatography-mass spectrometry (GC-MS) method was developed for six indicator PCBs (PCB28, PCB52, PCB101, PCB138, PCB153, and PCB180) in soil. Comparative studies were conducted to determine the clean-up efficiency of the following three techniques: (i) Oasis-HLB, (ii) multi-layer silica column, and (iii) dSPE employing CMCD-NH2-MNPs. The results indicate that CMCD-NH2-MNPs as the purification material can easily and effectively remove DDT, DDE, and DDD in soil samples within a short duration of time. The recoveries for highly chlorinated PCBs were in the range of 85.4-102.2%, with RSDs varying between 1.0 and 6.5%. The proposed method was verified as one of the most effective clean-up procedures for the analysis of highly chlorinated PCBs in real soil samples. PMID:25240650

  19. Derivation of residual radioactive material guidelines for uranium in soil at the Former Associate Aircraft Tool and Manufacturing Company Site, Fairfield, Ohio

    SciTech Connect

    Faillace, E.R.; Nimmagadda, M.; Yu, C.

    1995-01-01

    Residual radioactive material guidelines for uranium in soil were derived for the former Associate Aircraft Tool and Manufacturing Company site in Fairfield, Ohio. This site has been identified for remedial action under the U.S. Department of Energy`s (DOE`s) Formerly Utilized Sites Remedial Action Program (FUSRAP). Single-nuclide and total-uranium guidelines were derived on the basis of the requirement that, after remedial action, the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the site should not exceed (1) 30 mrem/yr for the current-use and likely future-use scenarios or (2) 100 mrem/yr for less likely future-use scenarios. The DOE residual radioactive material (RESRAD) computer code, which implements the methodology described in the DOE manual for establishing residual radioactive material guidelines, was used in this evaluation.

  20. Unlocking the biogeochemical black box: What drives microbial response to climate forcing in semi-arid soils?

    NASA Astrophysics Data System (ADS)

    Moravec, B. G.; McLain, J. E.; Lohse, K. A.

    2009-12-01

    Microbial mediated cycling of carbon (C) and nitrogen (N) and their loss from soils are closely linked to soil moisture and temperature. Yet, it is unclear how microbial communities will respond to climatic forcing (namely increased inter-annual precipitation variability and severe drought) and to what extent parent material controls these responses. We used Real Time Polymerase Chain Reaction (RT-PCR) and C utilization assays to determine the relative abundance and diversity of microbial populations during pre-, mid- and post-monsoon time intervals at four sites along a steep elevation gradient (temperature and precipitation range of >10°C and >50 cm, respectively) in the Santa Catalina Mountains, AZ. Contrasting parent materials (schist and granite) were paired at elevations. RT-PCR results showed large increases of bacterial and fungal biomarkers at high elevations with the onset of precipitation (pre- to mid- monsoon conditions) (as much as 824%). In contrast, bacteria biomarkers did not change at low elevation granite site as a result of the onset of precipitation whereas fungal biomarkers increased by 177% at this site. Both bacteria and fungal biomarkers increased substantially at low elevation schist sites with the onset of precipitation. Finally, C utilization assays indicated that high elevation sites had a relatively high diversity of C utilization compared to low elevation soils. We hypothesize that increased bacterial and fungal abundance in low elevation schist-derived soils relative to granite soils after the onset of monsoon rains may be a function of soil texture, with higher clay content in schist soils leading to higher soil moisture availability. Alternatively, differences in microbial responses may be due to higher C availability in schist soils compared to granite soils. Higher C utilization diversity as well as similar bacteria and fungal biomarker responses found at high elevation sites (both granite and schist soils) in response to

  1. Use of Geochemical Indices in Environmental Assessment of Soil; the Predictable and the Predictably Unpredictable

    NASA Astrophysics Data System (ADS)

    Mikkonen, Hannah; Clarke, Bradley; van de Graaff, Robert; Reichman, Suzie

    2016-04-01

    Geochemical correlations between common contaminants (Pb, Ni, As, Cr, Co and Zn) and earth metals, Fe and Mn, have been recommended as empirical tools to estimate "background" concentrations of metals in soil. A limited number of studies indicate that geochemical ratios between Pb, Ni, As, Cr, Co, V and Zn with scavenger metals Fe or Mn, are consistent between soils collected from different regions (Hamon et al. 2004, Myers and Thorbjornsen 2004). These studies have resulted in the incorporation of geochemical indices into Australian guidance, for derivation of ecological investigation levels for Ni, Cr, Cu and Zn. However, little research has been undertaken to assess the variation of geochemical patterns between soils derived from different parent materials or different weathering environments. A survey of background soils derived from four different parent materials, across Victoria, Australia, was undertaken, comprising collection of samples (n=640) from the surface (0 to 0.1 m) and sub-surface (0.3 to 0.6 m). Soil samples were collected from urban and rural areas of low disturbance, away from point sources of contamination. Samples were analysed for metals/metalloids and soil physical and chemical properties. Statistical review of results included regression and multivariate analysis. The results of the soil survey were compared against geochemical relationships reported within Australia and internationally. Compilation of results from this study and international data sets, indicates that geochemical relationships for metals Cr and V (in the format of log[Cr] = alog[Fe] +c) are predictable, not only between soils derived from different parent materials, but also between soils of different continents. Conversely, relationships between Zn and Fe, Pb and Fe, Cu and Fe, Co and Mn are variable, particularly within soils derived from alluvial sediments, which may have undergone periods of reducing conditions, resulting in dissociation from metal oxides. Broad

  2. Cave-soils, the soils forming underneath the surface

    NASA Astrophysics Data System (ADS)

    Dobos, Endre; Bertóti, Diána; Kovács, Károly; Vadnai, Péter

    2015-04-01

    , or possibly with the Mollic or Rhodic qualifiers. Despite the relatively small number of analysed and reference samples during the mineralogical examinations, we can say that clear trends could be observed in the cave sediments. Due to the present and historical heterogeneity of the catchment area, it is difficult to associate the samples with surface soils. It could be established, however, that approximately half of the minerals in the cave soils are quartz, with ratios of 38-73% depending on the texture. Smectite-vermiculite associations were dominant in the clay mineral fraction, making up 80-90% of the whole fraction in seven of the eight samples. The only exception was the Mexikó-2 sample, where relatively fresh, unweathered, unleached illite-muscovite is mixed with intensively weathered kaolinite. The explanation for this probably comes from the different origin of the parent materials deposited on each other, either over time or during sampling. This theory needs to be confirmed by further detailed analysis. The work has been supported by "Kútfő" TÁMOP-4.2.2.-A11/1/KONV-2012-0049 project and HUSK/1001/2.1.2/0058 cross-border project. Keywords: cave sediments, soil, WRB, soil contamination, soil formation

  3. Soil development as limiting factor for shrub expansion in southwestern Greenland

    NASA Astrophysics Data System (ADS)

    Caviezel, Chatrina; Hunziker, Matthias; Zoller, Oliver; Wüthrich, Christoph; Kuhn, Nikolaus J.

    2014-05-01

    Southern Greenland currently experiences an increase in summer temperatures and a prolonged growing season (Masson-Delmotte et al. 2012), resulting in an increased shrub cover at the boreal - tundra border ecotone (Normand et al. 2013). These findings suggest the beginning of a greener Greenland in which tundra vegetation is transformed to a boreal woody flora. However, vegetation at borderline ecotones is influenced by further ecologic factors than just temperature. In this study, the ecologic conditions at a selection of sites along an elevation gradient near Igaliku in southern Greenland were examined to identify potential factors limiting the expansion of woody vegetation apart from temperature. The sites differ in elevation, topography, shrub density and soil parent material. The three study sites comprise i) well established birch shrubs growing between 50 and 180 m a.s.l., where the parent material origins from the Julianehab granite (Brooks 2012); ii) extended shrub patches at about 250 m a.s.l., where the parent material consists of Gardar Sandstones and Lavas (Brooks 2012) and iii) restricted shrub patches at an elevation of 250 m a.s.l., where the soil parent material originates from the Gardar intrusions (Brooks 2012). The extent of the shrub areas, topography and soil moisture were mapped, additionally soil samples were analyzed for C-and N-content, texture including coarse fraction and pH and used as soil development indicators. Our results show that the topographic setting regulates the existence or absence of soil while the soil parent material is an important limiting factor for soil moisture. According to these findings, we suggest that a high proportion of areas where temperature increase would allow the increase of shrub cover is not suitable for a woody flora. Brooks, Kent. 2012. "A Tale of Two Intrusions—where Familiar Rock Names No Longer Suffice." Geology Today 28 (1): 13-19. doi:10.1111/j.1365-2451.2012.00815.x. Masson-Delmotte, V., D

  4. Rock and Soil Types at Pathfinder Landing Site

    NASA Technical Reports Server (NTRS)

    1997-01-01

    Type areas of rocks and soils. (A) Dark rock type and bright soil type: Shown is the dark rock Barnacle Bill. Reflectance spectra typical of fresh basalt and APXS spectra indicating more silica-rich basaltic andesite compositions characterize this type. These rocks are typically the small boulders and intermediate-sized cobbles at the Pathfinder site. The bright soil type is very common and in this case comprises Barnacle Bill's wind tail and much of the surround soil area. This soil has a high reflectance and a strongly reddened spectrum indicative of oxidized ferric minerals. (B) Bright rock type: Shown is the bright rock Wedge. Reflectance spectra typical of weathered basalt and APXS spectra indicating basaltic compositions characterize this type. These rocks are typically larger than 1 meter in diameter and many display morphologies indicating flood deposition. (C) Pink rock type: Shown is the pink rock Scooby Doo. APXS and reflectance spectra indicate a composition and optical characteristics similar to the drift soil. However, the morphology of the pink rock type indicates a cemented or rocklike structure. This material may be a chemically cemented hardpan that underlies much of the Pathfinder site. (D) Dark soil type: The dark soil type is typically found on the windward sides of rocks or in rock-free areas like Photometry Flats (shown here) where the bright soil has been striped away by aeolian action or in open areas. Other locations include the Mermaid Dune. (E) Disturbed soil type: The darkening of disturbed soil relative to its parent material, bright soil, as a result of changes in soil texture and compaction caused by movement of the rover and retraction of the lander airbag. (F) Lamb-like soil type: This soil type shows reflectance and spectral characteristics intermediate between the bright and dark soils. Its distinguishing feature is a weak spectral absorption near 900 nanometers not seen in either the bright or dark soils.

    NOTE: original

  5. Soil organic matter stocks in Bavaria as driven by land use, soil type, topography and climate change

    NASA Astrophysics Data System (ADS)

    Kühnel, Anna; Wiesmeier, Martin; Spörlein, Peter; Schilling, Bernd; Kögel-Knabner, Ingrid

    2016-04-01

    Climate change will have profound impacts on organic matter stocks and thus on the functionality of soils. The predicted rising temperatures in Bavaria might lead to an increased decomposition and release of soil carbon into the atmosphere, which would deteriorate a number of important soil functions. Information about the effect of rising temperatures on soils is however scarce. In this study, a comprehensive data set of 1459 soil profiles completely sampled down to the parent material or at least to a depth of 1 m was used to predict SOC stocks for the state of Bavaria separately for top- and subsoils. As potential predictor parameters for SOC storage, we used pedogenetic, topographic and environmental parameters for different random forest models. Our objectives were to identify main drivers of SOC storage in top- and subsoils and to predict the current total SOC storage of Bavaria. In order to identify how organic carbon stocks in soils has already changed over the last 30 years, we used soil data from about 120 long term observation sites with constant management practices. The long term observation sites are homogeneously distributed over Bavaria and comprise forest, grassland and agricultural systems. These sites have been established in the middle of the 80's and have been re-sampled approximately every 10 years. This data set gives us the unique possibility to investigate the effect of rising temperatures on the organic matter storage of soils under different land uses.

  6. Pedological and geological relationships with soil lichen and moss distribution in the eastern Mojave Desert, CA, USA

    USGS Publications Warehouse

    Belnap, Jayne; Miller, David M.; Bedford, David R.; Phillips, Susan L.

    2014-01-01

    Biological soil crusts (biocrusts) are ubiquitous in drylands globally. Lichens and mosses are essential biocrust components and provide a variety of ecosystem services, making their conservation and management of interest. Accordingly, understanding what factors are correlated with their distribution is important to land managers. We hypothesized that cover would be related to geologic and pedologic factors. We sampled 32 sites throughout the eastern Mojave Desert, stratifying by parent material and the age of the geomorphic surfaces. The cover of lichens and mosses on ‘available ground’ (L + Mav; available ground excludes ground covered by rocks or plant stems) was higher on limestone and quartzite-derived soils than granite-derived soils. Cover was also higher on moderately younger-aged geomorphic surfaces (Qya2, Qya3, Qya4) and cutbanks than on very young (Qya1), older-aged surfaces (Qia1, Qia2), or soils associated with coppice mounds or animal burrowing under Larrea tridentata. When all sites and parent materials were combined, soil texture was the most important factor predicting the occurrence of L + Mav, with cover positively associated with higher silt, very fine sand, and fine sand fractions and negatively associated with the very coarse sand fraction. When parent materials were examined separately, nutrients such as available potassium, iron, and calcium became the most important predictors of L + Mav cover.

  7. A history of Soil Survey in England and Wales

    NASA Astrophysics Data System (ADS)

    Hallett, S.; Deeks, L.

    2012-04-01

    Early soil mapping in Britain was dominated, as in the USA, by soil texture with maps dating back to the early 1900's identifying surface texture and parent rock materials. Only in the 1920's did Dokuchaev's work in Russia involving soil morphology and the development of the soil profile start to gain popularity, drawing in the influence of climate and topography on pedogenesis. Intentions to create a formal body at this time responsible for soil survey were not implemented and progress remained slow. However, in 1939 definite steps were taken to address this and the soil survey was created. In 1947, its activities were transferred from Bangor to the research branch of the Rothamsted experimental station in Hertfordshire under Professor G.W. Robinson. Soon after, a number of regional offices were also established to act as a link with the National Agricultural Advisory Service. At this time a Pedology Department was established at Rothamsted, focussing on petrological, X-ray, spectrographic and chemical analyses. Although not a Rothamsted Department itself, the Survey did fall under the 'Lawes Agricultural Trust'. A Soil Survey Research Advisory Board was also formed to act as a liaison with the Agricultural Field Council. In Scotland by contrast, soil survey activities became centred on the Macaulay Institute in Aberdeen. Developments in the survey of British soils were accompanied in parallel by the development of soil classification systems. In 1930 a Soils Correlation Committee had been formed to ensure consistency in methods and naming of soil series and to ensure the classification was applied uniformly. In England and Wales the zonal system adopted was similar to that used in the USA, where soil series were named after the location where they were first described. American soil scientists such as Veitch and Lee provided stimulus to the development of mapping methods. In Scotland a differing classification was adopted, being similar to that used in Canada

  8. Determination of traces of Mo in soils and geological materials by solvent extraction of the molybdenum-thiocyanate complex and atomic absorption.

    PubMed

    Kim, C H; Owens, C M; Smythe, L E

    1974-06-01

    Comprehensive studies of the extraction of the molybdenum-thiocyanate complex with methyl isobutyl ketone have resulted in an improved method for the determination of traces of molybdenum in soils and geological materials by atomic-absorption spectroscopy. The method is applicable in the range 1-500 ppm Mo, with 1-g samples, giving relative standard deviations not exceeding about 8% at a level of 1 ppm. The limit of detection is 0.1 ppm. There are few interferences, and large quantities of iron are without effect. PMID:18961481

  9. The occurrence, sources and spatial characteristics of soil salt and assessment of soil salinization risk in Yanqi basin, northwest China.

    PubMed

    Zhaoyong, Zhang; Abuduwaili, Jilili; Yimit, Hamid

    2014-01-01

    In order to evaluate the soil salinization risk of the oases in arid land of northwest China, we chose a typical oasis-the Yanqi basin as the research area. Then, we collected soil samples from the area and made comprehensive assessment for soil salinization risk in this area. The result showed that: (1) In all soil samples, high variation was found for the amount of Ca2+ and K+, while the other soil salt properties had moderate levels of variation. (2) The land use types and the soil parent material had a significant influence on the amount of salt ions within the soil. (3) Principle component (PC) analysis determined that all the salt ion values, potential of hydrogen (pHs) and ECs fell into four PCs. Among them, PC1 (C1-, Na+, SO4(2-), EC, and pH) and PC2 (Ca2+, K+, Mg2+and total amount of salts) are considered to be mainly influenced by artificial sources, while PC3 and PC4 (CO3(-) and HCO3(2-)) are mainly influenced by natural sources. (4) From a geo-statistical point of view, it was ascertained that the pH and soil salt ions, such as Ca2+, Mg2+ and HCO3(-), had a strong spatial dependency. Meanwhile, Na+ and Cl- had only a weak spatial dependency in the soil. (5) Soil salinization indicators suggested that the entire area had a low risk of soil salinization, where the risk was mainly due to anthropogenic activities and climate variation. This study can be considered an early warning of soil salinization and alkalization in the Yanqi basin. It can also provide a reference for environmental protection policies and rational utilization of land resources in the arid region of Xinjiang, northwest China, as well as for other oases of arid regions in the world. PMID:25211240

  10. The Occurrence, Sources and Spatial Characteristics of Soil Salt and Assessment of Soil Salinization Risk in Yanqi Basin, Northwest China

    PubMed Central

    Zhaoyong, Zhang; Abuduwaili, Jilili; Yimit, Hamid

    2014-01-01

    In order to evaluate the soil salinization risk of the oases in arid land of northwest China, we chose a typical oasis-the Yanqi basin as the research area. Then, we collected soil samples from the area and made comprehensive assessment for soil salinization risk in this area. The result showed that: (1) In all soil samples, high variation was found for the amount of Ca2+ and K+, while the other soil salt properties had moderate levels of variation. (2) The land use types and the soil parent material had a significant influence on the amount of salt ions within the soil. (3) Principle component (PC) analysis determined that all the salt ion values, potential of hydrogen (pHs) and ECs fell into four PCs. Among them, PC1 (C1-, Na+, SO42-, EC, and pH) and PC2 (Ca2+, K+, Mg2+and total amount of salts) are considered to be mainly influenced by artificial sources, while PC3 and PC4 (CO3- and HCO32-) are mainly influenced by natural sources. (4) From a geo-statistical point of view, it was ascertained that the pH and soil salt ions, such as Ca2+, Mg2+ and HCO3-, had a strong spatial dependency. Meanwhile, Na+ and Cl- had only a weak spatial dependency in the soil. (5) Soil salinization indicators suggested that the entire area had a low risk of soil salinization, where the risk was mainly due to anthropogenic activities and climate variation. This study can be considered an early warning of soil salinization and alkalization in the Yanqi basin. It can also provide a reference for environmental protection policies and rational utilization of land resources in the arid region of Xinjiang, northwest China, as well as for other oases of arid regions in the world. PMID:25211240

  11. Relevant magnetic and soil parameters as potential indicators of soil conservation status of Mediterranean agroecosystems

    NASA Astrophysics Data System (ADS)

    Quijano, Laura; Chaparro, Marcos A. E.; Marié, Débora C.; Gaspar, Leticia; Navas, Ana

    2014-09-01

    The main sources of magnetic minerals in soils unaffected by anthropogenic pollution are iron oxides and hydroxides derived from parent materials through soil formation processes. Soil magnetic minerals can be used as indicators of environmental factors including soil forming processes, degree of pedogenesis, weathering processes and biological activities. In this study measurements of magnetic susceptibility are used to detect the presence and the concentration of soil magnetic minerals in topsoil and bulk samples in a small cultivated field, which forms a hydrological unit that can be considered to be representative of the rainfed agroecosystems of Mediterranean mountain environments. Additional magnetic studies such as isothermal remanent magnetization (IRM), anhysteretic remanent magnetization (ARM) and thermomagnetic measurements are used to identify and characterize the magnetic mineralogy of soil minerals. The objectives were to analyse the spatial variability of the magnetic parameters to assess whether topographic factors, soil redistribution processes, and soil properties such as soil texture, organic matter and carbonate contents analysed in this study, are related to the spatial distribution pattern of magnetic properties. The medians of mass specific magnetic susceptibility at low frequency (χlf) were 36.0 and 31.1 × 10-8 m3 kg-1 in bulk and topsoil samples respectively. High correlation coefficients were found between the χlf in topsoil and bulk core samples (r = 0.951, p < 0.01). In addition, volumetric magnetic susceptibility was measured in situ in the field (κis) and values varied from 13.3 to 64.0 × 10-5 SI. High correlation coefficients were found between χlf in topsoil measured in the laboratory and volumetric magnetic susceptibility field measurements (r = 0.894, p < 0.01). The results obtained from magnetic studies such as IRM, ARM and thermomagnetic measurements show the presence of magnetite, which is the predominant magnetic carrier

  12. Quantifying soil and critical zone variability in a forested catchment through digital soil mapping

    NASA Astrophysics Data System (ADS)

    Holleran, M.; Levi, M.; Rasmussen, C.

    2015-01-01

    Quantifying catchment-scale soil property variation yields insights into critical zone evolution and function. The objective of this study was to quantify and predict the spatial distribution of soil properties within a high-elevation forested catchment in southern Arizona, USA, using a combined set of digital soil mapping (DSM) and sampling design techniques to quantify catchment-scale soil spatial variability that would inform interpretation of soil-forming processes. The study focused on a 6 ha catchment on granitic parent materials under mixed-conifer forest, with a mean elevation of 2400 m a.s.l, mean annual temperature of 10 °C, and mean annual precipitation of ~ 85 cm yr-1. The sample design was developed using a unique combination of iterative principal component analysis (iPCA) of environmental covariates derived from remotely sensed imagery and topography, and a conditioned Latin hypercube sampling (cLHS) scheme. Samples were collected by genetic horizon from 24 soil profiles excavated to the depth of refusal and characterized for soil mineral assemblage, geochemical composition, and general soil physical and chemical properties. Soil properties were extrapolated across the entire catchment using a combination of least-squares linear regression between soil properties and selected environmental covariates, and spatial interpolation or regression residual using inverse distance weighting (IDW). Model results indicated that convergent portions of the landscape contained deeper soils, higher clay and carbon content, and greater Na mass loss relative to adjacent slopes and divergent ridgelines. The results of this study indicated that (i) the coupled application of iPCA and cLHS produced a sampling scheme that captured the greater part of catchment-scale soil variability; (ii) application of relatively simple regression models and IDW interpolation of residuals described well the variance in measured soil properties and predicted spatial correlation of soil

  13. Exploring the multiplicity of soil-human interactions: organic carbon content, agro-forest landscapes and the Italian local communities.

    PubMed

    Salvati, Luca; Barone, Pier Matteo; Ferrara, Carlotta

    2015-05-01

    Topsoil organic carbon (TOC) and soil organic carbon (SOC) are fundamental in the carbon cycle influencing soil functions and attributes. Many factors have effects on soil carbon content such as climate, parent material, land topography and the human action including agriculture, which sometimes caused a severe loss in soil carbon content. This has resulted in a significant differentiation in TOC or SOC at the continental scale due to the different territorial and socioeconomic conditions. The present study proposes an exploratory data analysis assessing the relationship between the spatial distribution of soil organic carbon and selected socioeconomic attributes at the local scale in Italy with the aim to provide differentiated responses for a more sustainable use of land. A strengths, weaknesses, opportunities and threats (SWOT) analysis contributed to understand the effectiveness of local communities responses for an adequate comprehension of the role of soil as carbon sink. PMID:25903408

  14. Parental Influences on Adolescent Adjustment: Parenting Styles Versus Parenting Practices

    ERIC Educational Resources Information Center

    Lee, Sang Min; Daniels, M. Harry; Kissinger, Daniel B.

    2006-01-01

    The study identified distinct patterns of parental practices that differentially influence adolescent behavior using the National Educational Longitudinal Survey (NELS:88) database. Following Brenner and Fox's research model (1999), the cluster analysis was used to classify the four types of parental practices. The clusters of parenting practices…

  15. A statistical approach for validating eSOTER and digital soil maps in front of traditional soil maps

    NASA Astrophysics Data System (ADS)

    Bock, Michael; Baritz, Rainer; Köthe, Rüdiger; Melms, Stephan; Günther, Susann

    2015-04-01

    During the European research project eSOTER, three different Digital Soil Maps (DSM) were developed for the pilot area Chemnitz 1:250,000 (FP7 eSOTER project, grant agreement nr. 211578). The core task of the project was to revise the SOTER method for the interpretation of soil and terrain data. It was one of the working hypothesis that eSOTER does not only provide terrain data with typical soil profiles, but that the new products actually perform like a conceptual soil map. The three eSOTER maps for the pilot area considerably differed in spatial representation and content of soil classes. In this study we compare the three eSOTER maps against existing reconnaissance soil maps keeping in mind that traditional soil maps have many subjective issues and intended bias regarding the overestimation and emphasize of certain features. Hence, a true validation of the proper representation of modeled soil maps is hardly possible; rather a statistical comparison between modeled and empirical approaches is possible. If eSOTER data represent conceptual soil maps, then different eSOTER, DSM and conventional maps from various sources and different regions could be harmonized towards consistent new data sets for large areas including the whole European continent. One of the eSOTER maps has been developed closely to the traditional SOTER method: terrain classification data (derived from SRTM DEM) were combined with lithology data (re-interpreted geological map); the corresponding terrain units were then extended with soil information: a very dense regional soil profile data set was used to define soil mapping units based on a statistical grouping of terrain units. The second map is a pure DSM map using continuous terrain parameters instead of terrain classification; radiospectrometric data were used to supplement parent material information from geology maps. The classification method Random Forest was used. The third approach predicts soil diagnostic properties based on

  16. Parents Make a Difference.

    ERIC Educational Resources Information Center

    Institute for Responsive Education, Boston, MA.

    This handbook discusses the following types of parent involvement in education: (1) decision-making; (2) parents as educators; (3) advocacy; (4) school support; and (5) parent education and support. The benefits of parent involvement are outlined. Examples from New York City's 1987-88 Parent Involvement Program (PIP) demonstrate that parent…

  17. Parenting and Video Games

    ERIC Educational Resources Information Center

    Steinkuehler, Constance

    2016-01-01

    There is a terrific disconnect between parenting advice related to media and the realities of contemporary parenting. We condone enrichment parenting and condemn the use of "digital babysitters," admonishing parents who exceed the two-hour screen time limitation even when, all the while, no one is listening. Parents are not merely blasé…

  18. Genetic features of soils in the basin of Lake Kotokel, the Transbaikal region

    NASA Astrophysics Data System (ADS)

    Balsanova, L. D.; Gyninova, V. B.; Tsybikdorzhiev, Ts. Ts.; Gonchikov, B.-M. N.; Shakhmatova, E. Yu.

    2014-07-01

    The diversity of the soils and the specific features of the pedogenesis in the basin of Lake Kotokel have been studied. The specificity of the pedogenesis and soil cover patterns in the lake basin are controlled by the altitudinal zonation, the diversity of parent materials, and the influence of air masses from Lake Baikal. Gray metamorphic soils and raw-humus burozems developed under taiga vegetation in the mountains predominate in the basin of Lake Kotokel. The coastal landscapes and river valleys are occupied by swampy and meadow alluvial soils. The genetic features of the major soils have been characterized on the basis of field descriptions, laboratory data, and special macro- and micromorphological studies.

  19. Volatile element depletion and K-39/K-41 fractionation in lunar soils

    NASA Technical Reports Server (NTRS)

    Church, S. E.; Tilton, G. R.; Wright, J. E.; Lee-Hu, C.-N.

    1976-01-01

    Evidence for selective loss and isotopic fractionation (in the case of K) of volatile elements during formation of agglutinates by micrometeoritic bombardment of lunar soils is presented. Concentrations and isotopic compositions of volatile elements (K, Rb, Pb) and nonvolatile elements (U, Th, Ba, Sr, rare earths) in separates taken from soils 14163, 14259, 15041, 68501, and 71500 are examined. Rayleigh fractionation calculations applied to K-39/K-41 isotopic data indicate ten-fold recycling of bulk soil, to account for observed isotopic anomalies. The lunar soil fines fraction seems to be a site of deposition for volatile or labile Pb produced during agglutination. Local fines (below 75 microns) are viewed as representative of the parent material for agglutinates formed in situ by micrometeoritic impact. Magnetic separation of agglutinates from soil 68501 revealed a bimodal population, with one class comprising welded blocky magnetic glasses.

  20. Assessment of radioactive materials and heavy metals in the surface soil around uranium mining area of Tongliao, China.

    PubMed

    Haribala; Hu, Bitao; Wang, Chengguo; Gerilemandahu; Xu, Xiao; Zhang, Shuai; Bao, Shanhu; Li, Yuhong

    2016-08-01

    Natural and artificial radionuclides and heavy metals in the surface soil of the uranium mining area of Tongliao, China, were measured using gamma spectrometry, flame atomic absorption spectrophotometry, graphite furnace atomic absorption spectrophotometry and microwave dissolution atomic fluorescence spectrometry respectively. The estimated average activity concentrations of (238)U, (232)Th, (226)Ra, (40)K and (137)Cs are 27.53±16.01, 15.89±5.20, 12.64±4.27, 746.84±38.24 and 4.23±4.76Bq/kg respectively. The estimated average absorbed dose rate in the air and annual effective dose rate are 46.58±5.26nGy/h and 57.13±6.45μSv, respectively. The radium equivalent activity, external and internal hazard indices were also calculated and their mean values are within the acceptable limits. The heavy metal concentrations of Pb, Cd, Cu, Zn, Hg and As from the surface soil were measured and their health risks were then determined. Although the content of Cd is much higher than the average background in China, its non-cancer and cancer risk indices are all within the acceptable ranges. These calculated hazard indices to estimate the potential radiological health risk in soil and the dose rate are well below their permissible limit. In addition the correlations between the radioactivity concentrations of the radionuclides and the heavy metals in soil were determined by the Pearson linear coefficient. PMID:27107776

  1. Can hydromorphic conditions accelerate soil development?

    NASA Astrophysics Data System (ADS)

    Ringer, Marianna; Kiss, Klaudia; Horváth-Szabó, Kata; Réka Balázs, Brigitta; Németh, Tibor; Sipos, Péter; Szabó, Máté; Jakab, Gergely; Madarász, Balázs; Szalai, Zoltán

    2016-04-01

    The formation and development of waterlogged (hydromorphic) soils are primarily determined by long-term water saturation. The presence of water in the profile can result increasing speed of soil forming processes including the accumulation of organic matter or other components and mineralogical transformations. Original papers refer more than hundreds of years for this kinds of mineral transformations. We suppose that this process could be more rapid. This study focuses on the mineralogical investigation of a sandy meadow soil (calcic, gleyic Phaeozem ferric, arenic) located in a swampy area in Central Hungary. The starting time of the soil formation is a well documented fact: the parent material deposited during an extremely heavy flood event in the 1960s. Therefore, the studied soil profile is the result of the last half century. Our aim was to explore the degree of mineral phase alteration via soil formation during a half-century under hydromorphic conditions. Routine laboratory measurements (selective dissolution methods for the determination of amorphous and crystalline Fe, and Mn content, X-ray fluorescence spectroscopy measurements for elemental composition determination, X-ray powder diffraction for mineralogical composition, and particle sizing by laser diffraction) were implemented. Morphological and chemical study of carbonate and iron nodules was carried out by electron microprobe. Simple chemical tests (eg. Fe2+ indication by dipiridil test) and morphological observations were performed on the field. Redox potential (Eh) and pH were measured in 20 cm and 40 cm depths by field monitoring station during the vegetation period. Results show that well developed horizons have emerged during fifty years in the studied soil profile. The most intense mineralogical transformations developed in the zone of the heaviest redox oscillation. Soil formation under hydromorphic conditions proceeds at higher speeds contrariwise to the century time scale reported in

  2. Soils developed from alluvial and proluvial deposits in the Gröndalselva River valley in West Spitsbergen

    NASA Astrophysics Data System (ADS)

    Pereverzev, V. N.; Litvinova, T. I.

    2012-05-01

    The genetic characterization of soils developed from alluvial and proluvial deposits in the Gröndalselva River valley (West Spitsbergen) is presented. These soils are compared with analogous soils formed on marine terraces along the coasts of Isfjord and Grönfjord. Gray-humus (soddy) soils with an O-AY-C profile have been described on parent materials of different origins, including alluvial and proluvial sediments. The texture of the soils in the Gröndalselva River valley varies from medium to heavy loam and differs from the texture of the soils on other geomorphic positions in the higher content of fine particles. The soils developed from the alluvial deposits are characterized by their richer mineralogical and chemical composition in comparison with the soils developed from proluvial deposits, marine deposits, and bedrocks. All the deposits are impoverished in CaO. No differentiation of the chemical composition of the soils along the soil profiles has been found in the soils of the coastal areas and the river valley. Some accumulation of oxalate-soluble Al and Fe compounds takes place in the uppermost mineral horizon. The soils of all the geomorphic positions have a high humus content and a high exchange capacity.

  3. Assessment of heavy metal pollution in surface soils and plant material in the post-industrial city of Katowice, Poland.

    PubMed

    Steindor, Karolina A; Franiel, Izabella J; Bierza, Wojciech M; Pawlak, Beata; Palowski, Bernard F

    2016-01-01

    This investigation was undertaken to assess the level of environment pollution by biological monitoring. The leaves and bark of popular ornamental trees Acer pseudoplatanus L. and Acer platanoides L. and soil from the sampling sites were used to perform heavy metals pollution monitoring in urban areas with different pollution sources, as well to investigate the suitability of the leaves and bark as bioindicators of Pb, Zn, Cd and Cu pollution. Plant samples were collected at nine locations classified into three pollution groups based on metal content in the soils. The chosen pollution indices were used to assess the level of contamination according to background values. Soils in the Katowice area are found to be relatively heavily contaminated with Pb, Zn and Cd. Both of the maple tree species did not statistically differ in terms of the investigated elements' concentration in leaves or bark. Only bark samples reflected the pollution level, showing differences between the sampling points, and therefore are recommended for biomonitoring purposes. PMID:26809744

  4. Soil processes and functions across an international network of Critical Zone Observatories: Introduction to experimental methods and initial results

    NASA Astrophysics Data System (ADS)

    Banwart, Steven; Menon, Manoj; Bernasconi, Stefano M.; Bloem, Jaap; Blum, Winfried E. H.; Souza, Danielle Maia de; Davidsdotir, Brynhildur; Duffy, Christopher; Lair, Georg J.; Kram, Pavel; Lamacova, Anna; Lundin, Lars; Nikolaidis, Nikolaos P.; Novak, Martin; Panagos, Panos; Ragnarsdottir, Kristin Vala; Reynolds, Brian; Robinson, David; Rousseva, Svetla; de Ruiter, Peter; van Gaans, Pauline; Weng, Liping; White, Tim; Zhang, Bin

    2012-11-01

    Growth in human population and demand for wealth creates ever-increasing pressure on global soils, leading to soil losses and degradation worldwide. Critical Zone science studies the impact linkages between these pressures, the resulting environmental state of soils, and potential interventions to protect soil and reverse degradation. New research on soil processes is being driven by the scientific hypothesis that soil processes can be described along a life cycle of soil development. This begins with formation of new soil from parent material, development of the soil profile, and potential loss of the developed soil functions and the soil itself under overly intensive anthropogenic land use, thus closing the cycle. Four Critical Zone Observatories in Europe have been selected focusing research at sites that represent key stages along the hypothetical soil life cycle; incipient soil formation, productive use of soil for farming and forestry, and decline of soil due to longstanding intensive agriculture. Initial results from the research show that soil develops important biogeochemical properties on the time scale of decades and that soil carbon and the development of favourable soil structure takes place over similar time scales. A new mathematical model of soil aggregate formation and degradation predicts that set-aside land at the most degraded site studied can develop substantially improved soil structure with the accumulation of soil carbon over a period of several years. Further results demonstrate the rapid dynamics of soil carbon; how quickly it can be lost, and also demonstrate how data from the CZOs can be used to determine parameter values for models at catchment scale. A structure for a new integrated Critical Zone model is proposed that combines process descriptions of carbon and nutrient flows, a simplified description of the soil food web, and reactive transport; all coupled with a dynamic model for soil structure and soil aggregation. This approach

  5. Soil water repellency as a vegetation-driven strategy for soil moisture sequestration in Banksia woodlands (Western Australia)

    NASA Astrophysics Data System (ADS)

    Muñoz-Rojas, Miriam; Jiménez-Morillo, Nicasio T.; González-Pérez, José A.; Zavala, Lorena M.; Stevens, Jason; Jordán, Antonio

    2016-04-01

    Water repellency is a property of some soils that inhibits or delays the rainwater infiltration. When a surface or subsurface soil horizon is water repellent, water is retained for periods of time that vary according to the severity of hydrophobicity, soil moisture and other parameters. Water repellency is caused by hydrophobic organic substances released by plant residues, roots or soil microorganisms. Certain abiotic agents, like fire, can increase the severity of soil water repellency in certain cases. Under water-repellent conditions, water can infiltrate only when the pressure of the water column is high enough or when macropores allow it. These macropores may be formed by galleries excavated by animals, dead roots or gaps between aggregate or rock fragments. Banksia plants have a dimorphic root morphology. Proteoid roots are formed by clusters of densely compacted short lateral rootlets that radiate from the parent root. These clusters spread just some centimeters below the soil surface constituting a thick dense sheet of roots and are known to secrete large amounts of organic acids and phenolics to increase the uptake of P and other minerals. In contrast, the parent root penetrates soil deeply, reaching the water table. Sandy soils below banksia woodlands from Western Australia coastal dunes show a characteristic vertical distribution of water repellency. We observed that the first soil layer (just some millimeters of depth) was formed by a wettable sand particles transported by wind, covering a wettable or subcritically water-repellent subsurface layer (0-20 cm). A second soil layer (20-40 cm) was formed by a severely water-repellent layer with aggregates bulked by dominant banksia proteoid roots. Below this layer, soil water repellency decreased with depth until soil material rendered wettable at depths between 40 and 80 cm under field conditions. It is hypothesized that banksia roots are capable of inducing soil water repellency, causing the occurrence of

  6. The distribution of organic material and its contribution to the micro-topography of particles from wettable and water repellent soils

    NASA Astrophysics Data System (ADS)

    Bryant, Rob; Cheng, Shuying; Doerr, Stefan H.; Wright, Chris J.; Bayer, Julia V.; Williams, Rhodri P.

    2010-05-01

    Organic coatings on mineral particles will mask the physic-chemical properties of the underlying mineral surface. Surface images and force measurements obtained using atomic force microscopy (AFM) provide information about the nature of and variability in surfaces properties at the micro- to nano-scale. As AFM technology and data processing advance it is anticipated that a significant amount of information will be obtained simultaneously from individual contacts made at high frequency in non-contact or tapping mode operation. For present purposes the surfaces of model materials (smooth glass surfaces and acid-washed sand (AWS)) provide an indication of the dependency of the so-called AFM phase image on the topographic image (which is obtained synoptically). Pixel wise correlation of these images reveals how the modulation of an AFM probe is affected when topographic features are encountered. Adsorption of soil-derived humic acid (HA) or lecithin (LE), used here as an example for natural organic material, on these surfaces provides a soft and compliant, albeit partial, covering on the mineral which modifies the topography and the response of an AFM tip as it partially indents the soft regions (which contributes depth to the phase image). This produces a broadening on the data domain in the topographic/phase scatter diagram. Two dimensional classifications of these data, together with those obtained from sand particles drawn from water repellent and wettable soils, suggest that these large adsorbate molecules appear to have little preference to attach to particular topographic features or elevations. It appears that they may effectively remain on the surface at the point of initial contact. If organic adsorbates present a hydrophobic outer surface, then it seems possible that elevated features will not be immune from this and provide scope for a local, albeit, small contribution to the expression of super-hydrophobicity. It is therefore speculated here that the water

  7. Materials

    NASA Technical Reports Server (NTRS)

    Glaessgen, Edward H.; Schoeppner, Gregory A.

    2006-01-01

    NASA Langley Research Center has successfully developed an electron beam freeform fabrication (EBF3) process, a rapid metal deposition process that works efficiently with a variety of weldable alloys. The EBF3 process can be used to build a complex, unitized part in a layer-additive fashion, although the more immediate payoff is for use as a manufacturing process for adding details to components fabricated from simplified castings and forgings or plate products. The EBF3 process produces structural metallic parts with strengths comparable to that of wrought product forms and has been demonstrated on aluminum, titanium, and nickel-based alloys to date. The EBF3 process introduces metal wire feedstock into a molten pool that is created and sustained using a focused electron beam in a vacuum environment. Operation in a vacuum ensures a clean process environment and eliminates the need for a consumable shield gas. Advanced metal manufacturing methods such as EBF3 are being explored for fabrication and repair of aerospace structures, offering potential for improvements in cost, weight, and performance to enhance mission success for aircraft, launch vehicles, and spacecraft. Near-term applications of the EBF3 process are most likely to be implemented for cost reduction and lead time reduction through addition of details onto simplified preforms (casting or forging). This is particularly attractive for components with protruding details that would require a significantly large volume of material to be machined away from an oversized forging, offering significant reductions to the buy-to-fly ratio. Future far-term applications promise improved structural efficiency through reduced weight and improved performance by exploiting the layer-additive nature of the EBF3 process to fabricate tailored unitized structures with functionally graded microstructures and compositions.

  8. Parenting while Being Homeless

    ERIC Educational Resources Information Center

    Swick, Kevin J.; Williams, Reginald; Fields, Evelyn

    2014-01-01

    This article explores the dynamics of parenting while being in a homeless context. The mosaic of stressors involved in this homeless parenting process are explicated and discussed. In addition, resources and strategies that may support parenting are presented and discussed.

  9. Driving Factors of Carbon Distribution in Soils as Determined by z*

    NASA Astrophysics Data System (ADS)

    Mnich, M.; Lawrence, C. R.; Harden, J. W.; Treat, C. C.; Schulz, M. S.

    2015-12-01

    Terrestrial soils store approximately three times the amount of carbon(C) stored in the atmosphere. Understanding the mechanisms resulting in soil organic carbon stabilization is necessary for predicting the fate of this carbon and potential feedbacks to climate change. Here, we explore how soil carbon depth gradients are influenced by factors such as age, parent material, mean annual temperature (MAT) and a modeled moisture/leaching index (LI). Specifically, we calculate a quantitative metric reflecting the depth gradient of organic carbon, z*, described by Rosenbloom et al. 2006, which describes the depth attenuation of C turnover by fitting the %C by depth relationship with an exponential decay function. We compare z* across several soil chronosequences (n=33) spanning a broad array of ecosystems and climates. The compiled chronosequence data were collected from previously published studies and ongoing USGS work. Each sequence consisted of at least two soils spanning a developmental age gradient and each soil included depth resolved carbon concentrations, with at least four different depths sampled in vertical profile. When the soil profile data were integrated across all depths, we found only weak relationships between total C in these profiles with various soil forming factors. Comparing depth resolved concentrations provided an opportunity to determine the significance of depth resolved gradients and particularly the importance of deep soil C. We found a significant positive relationship between z* and age, (R2=0.57, p=4.0*10-13), a significant negative relationship between z* and LI (R2=0.02, p=0.02), a significant relationship between (age x LI) and z* (R2=0.02, p=0.02, a positive relationship between z* and MAT (R2=0.1 p=0.01), and no relationship between z* and general parent material type (felsic, mafic, calcareous ; R2=0.04, p=0.01). These findings aid in determining the drivers of soil carbon storage across sites.

  10. Silicate and carbonate mineral weathering in soil profiles developed on Pleistocene glacial drift (Michigan, USA): Mass balances based on soil water geochemistry

    NASA Astrophysics Data System (ADS)

    Jin, Lixin; Williams, Erika L.; Szramek, Kathryn J.; Walter, Lynn M.; Hamilton, Stephen K.

    2008-02-01

    Geochemistry of soil, soil water, and soil gas was characterized in representative soil profiles of three Michigan watersheds. Because of differences in source regions, parent materials in the Upper Peninsula of Michigan (the Tahquamenon watershed) contain only silicates, while those in the Lower Peninsula (the Cheboygan and the Huron watersheds) have significant mixtures of silicate and carbonate minerals. These differences in soil mineralogy and climate conditions permit us to examine controls on carbonate and silicate mineral weathering rates and to better define the importance of silicate versus carbonate dissolution in the early stage of soil-water cation acquisition. Soil waters of the Tahquamenon watershed are the most dilute; solutes reflect amphibole and plagioclase dissolution along with significant contributions from atmospheric precipitation sources. Soil waters in the Cheboygan and the Huron watersheds begin their evolution as relatively dilute solutions dominated by silicate weathering in shallow carbonate-free soil horizons. Here, silicate dissolution is rapid and reaction rates dominantly are controlled by mineral abundances. In the deeper soil horizons, silicate dissolution slows down and soil-water chemistry is dominated by calcite and dolomite weathering, where solutions reach equilibrium with carbonate minerals within the soil profile. Thus, carbonate weathering intensities are dominantly controlled by annual precipitation, temperature and soil pCO 2. Results of a conceptual model support these field observations, implying that dolomite and calcite are dissolving at a similar rate, and further dissolution of more soluble dolomite after calcite equilibrium produces higher dissolved inorganic carbon concentrations and a Mg 2+/Ca 2+ ratio of 0.4. Mass balance calculations show that overall, silicate minerals and atmospheric inputs generally contribute <10% of Ca 2+ and Mg 2+ in natural waters. Dolomite dissolution appears to be a major process

  11. Parental overprotection revisited.

    PubMed

    Thomasgard, M; Metz, W P

    1993-01-01

    Dimensions of parental overprotection are clarified in a critical review of the research and clinical literature. An indulgent style of parenting is distinguished from an overprotective parent-child relationship. Differential antecedents and outcomes are proposed for each of these forms of parent-child interaction. Measures of protection are reviewed. A new conceptual model of parental overprotection is presented which takes into account child, parent, family, socio-cultural, environmental and resiliency factors. Directions for future research are suggested. PMID:8287694

  12. Single Parent/Homemaker Project Reports.

    ERIC Educational Resources Information Center

    Kentucky State Dept. of Education, Frankfort. Office of Vocational Education.

    Annual reports, project descriptions, and various other materials are provided for 35 projects. Most of the projects focus on homemaking; some are on sex equity. Project titles include: Single Parent/Adult Homemaker Reentry Program (Ashland Community College); Career Awareness Class for the Single Parent and/or Homemaker (Cumberland Valley Health…

  13. Parents with Children--II. Intergenerational Continuities.

    ERIC Educational Resources Information Center

    Quinton, D.; Rutter, M.

    1984-01-01

    Studies families showing parenting difficulties and examines possible origins of those difficulties. Findings demonstrate a strong link between multiple parenting breakdown and markedly disrupted family experiences in childhood. Concludes that explanatory models based exclusively on either personal or material factors are inadequate. (RH)

  14. Preparation for Parenting. Teacher's Instructional Guide.

    ERIC Educational Resources Information Center

    Texas Tech Univ., Lubbock. Home Economics Curriculum Center.

    This instructional guide for a one-half-credit technical laboratory course for grades 10-12 teaches parental responsibilities; child guidance techniques; positive role modeling and parenting practices that promote child development, health, safety, and well-being. Introductory materials consist of a course description; overview of course design;…

  15. Silent play in a loud theatre - soil development in a geomorphically active proglacial area

    NASA Astrophysics Data System (ADS)

    Harlaar, Piet; Temme, Arnaud; Heckmann, Tobias

    2015-04-01

    Proglacial areas are scientifically famous for two sets of processes: first, the tumultuous geomorphic response to glacial retreat including enhanced fluvial activity and mass movements such as debris flows, rock fall and landslides. Second, the slow and somewhat regular development of soil and vegetation. These two sets of processes have usually been studied in isolation: soil development is best observed in wide, flat proglacial areas where not much geomorphic work is done. This has left questions unanswered that relate to the effect of geomorphic disturbance on high mountain soil formation, and vice versa. We attempted to characterize these interactions in the geomorphically active proglacial area of the Gepatsch Ferner in the Kaunertal in Austria. Geomorphic activity in this area is intensively studied in the PROSA project. In our study, several dozen soils were sampled in order to describe soil properties. Sampling locations were selected with Latin Hypercube sampling to best cover the variation in soil-forming factors. Results clearly showed that soil properties were not only a function of age, but also of erosion-deposition amounts and geomorphic regime. In contrast to what is reported in literature, soil pH in very young soils rose before it dropped as soils became older. The early pH rise probably reflects the leaching of pyrite in the parent material.

  16. Lithological and land-use based assessment of heavy metal pollution in soils surrounding a cement plant in SW Europe.

    PubMed

    Cutillas-Barreiro, Laura; Pérez-Rodríguez, Paula; Gómez-Armesto, Antía; Fernández-Sanjurjo, María José; Álvarez-Rodríguez, Esperanza; Núñez-Delgado, Avelino; Arias-Estévez, Manuel; Nóvoa-Muñoz, Juan Carlos

    2016-08-15

    We study the influence of phasing out a cement plant on the heavy metal (Hg, Pb and Cr) content in the surrounding soils, taking into account factors often neglected, such as contributions due to local lithology or land use. The range of total Hg was 10-144µg kg(-1), reaching up to 41 and 145mgkg(-1) for total contents of Pb and Cr, respectively. Forest soils showed higher concentration of Hg than prairie soils, indicating the importance of land use on the accumulation of volatile heavy metals in soils. In forest soils, total Hg showed a trend to decrease with soil depth, whereas in prairie soils the vertical pattern of heavy metal concentrations was quite homogeneous. In most cases, the distance to the cement plant was not a factor of influence in the soils content of the analyzed heavy metals. Total Pb and Cr contents in soils nearby the cement plant were quite similar to those found in the local lithology, resulting in enrichment factor values (EF's) below 2. This suggests that soil parent material is the main source of these heavy metals in the studied soils, while the contribution of the cement plant to Pb and Cr soil pollution was almost negligible. On the contrary, the soils surrounding the cement plant accumulate a significant amount of Hg, compared to the underlying lithology. This was especially noticeable in forest soils, where Hg EF achieved values up to 36. These results are of relevance, bearing in mind that Hg accumulation in soils may be an issue of environmental concern, particularly in prairie soils, where temporal flooding can favor Hg transformation to highly toxic methyl-Hg. In addition, the concurrence of acid soils and total-Cr concentrations in the range of those considered phytotoxic should be also stressed. PMID:27099999

  17. Resilient Parenting: Overcoming Poor Parental Bonding

    ERIC Educational Resources Information Center

    Travis, Wendy J.; Combs-Orme, Terri

    2007-01-01

    This study identified groups of mothers with varying patterns of adaptive functioning and bonds with their own parents. These patterns were related to mothers' parenting of their own children to understand how some mothers avoid repeating the cycle of poor parenting. Data from 210 new mothers were analyzed before hospital discharge about bonding…

  18. Parent Connection: Enlisting Parents in Career Counselling.

    ERIC Educational Resources Information Center

    Sinacore, Ada L.; Healy, Patricia; Hassan, Sheila

    1999-01-01

    Although the potential impact of parental influence in career development is recognized, attempts to enlist parents in positive ways often appear haphazard, rather than purposeful. Article offers numerous strategies to maximize the positive aspects of parental involvement in children's career development, by offering concrete steps to strengthen…

  19. Parental Involvement to Parental Engagement: A Continuum

    ERIC Educational Resources Information Center

    Goodall, Janet; Montgomery, Caroline

    2014-01-01

    Based on the literature of the field, this article traces a continuum between parental involvement with schools, and parental engagement with children's learning. The article seeks to shed light on an area of confusion; previous research has shown that different stakeholder groups understand "parental engagement" in different ways.…

  20. Chinese Parenting Reconsideration: Parenting Practices in Taiwan.

    ERIC Educational Resources Information Center

    Chen, Fu-mei; Luster, Tom

    This study examined authoritative and authoritarian parenting and specific parenting practices among Chinese mothers with preschoolers. The final sample consisted of 463 mothers with their 3 to 7 year-olds from 11 preschools, in Taiwan. Mothers completed a Chinese translation of the Parenting Behavior Questionnaire that assessed their parenting…

  1. Mineral Occurrence, Translocation, and Weathering in Soils Developed on Four Types of Carbonate and Non-carbonate Alluvial Fan Deposits in Mojave Desert, Southeastern California

    NASA Astrophysics Data System (ADS)

    Deng, Y.; McDonald, E. V.

    2007-12-01

    Soil geomorphology and mineralogy can reveal important clues about Quaternary climate change and geochemical process occurring in desert soils. We investigated (1) the mineral transformation in desert soils developed on four types of alluvial fans (carbonate and non-carbonate) under the same conditions of climate and landscape evolution; and (2) the effects of age, parent materials, and eolian processes on the transformation and translocation of the minerals. Four types of alluvial-fan deposits along the Providence Mountains piedmonts, Mojave Desert, southeastern California, USA were studied: (1) carbonate rocks, primarily limestone and marble (LS), (2) fine-grained rhyodacite and rhyolitic tuff mixed with plutonic and carbonate rocks (VX), (3) fine- to coarse- grained mixed plutonic (PM) rocks, and (4) coarse-grained quartz monzonite (QM). These juxtaposed fan deposits are physically correlated in a small area (about 20 km by 15 km) and experienced the same climatic changes in the late Pleistocene and Holocene. The soils show characteristic mineral compositions of arid/semiarid soils: calcite is present in nearly all of the samples, and a few of the oldest soils contain gypsum and soluble salts. Parent material has profound influence on clay mineral composition of the soils: (1) talc were observed only in soils developed on the volcanic mixture fan deposits, and talc occurs in all horizons; (2) palygorskite occur mainly in the petrocalcic (Bkm) of old soils developed on the LS and VX fan deposits, indicating pedogenic origin; (3) chlorite was observed mainly in soils developed on VX fan deposits (all ages) and on some LS deposits, but it is absent in soils developed on PM and QM fan deposits; and (4) vermiculite was common throughout soils developed on plutonic rock fan deposits. These mineralogical differences suggest that minerals in the soils are primarily inherited from their parent materials and that mineral weathering in this area was weak. Except the

  2. Texture-dependent anaerobic microsites constrain soil carbon oxidation rates

    NASA Astrophysics Data System (ADS)

    Keiluweit, Marco; Fendorf, Scott

    2016-04-01

    Soil texture, which is a product of parent material, climate and other soil forming factors, is a predictor for long-term storage of soil organic carbon (SOC) storage in many soil ecosystems. Positive correlation between texture (particularly clay content) and SOC storage have long been attributed to protective associations between clay minerals and organic compounds that prevent microbial and enzymatic access - a mechanism commonly referred to as 'mineral protection'. Texture therefore acts as the primary proxy for mineral protection in terrestrial ecosystem models used to assess SOC storage and its sensitivity to global change impacts. Here we show that this protective effect of texture is not only due to mineral protection, but also to the formation of anaerobic microsites. Combining micro-scale laboratory experiments with field-scale observations, we find that oxygen diffusion limitations within clay-rich domains create anaerobic microsites within seemingly well-aerated soils, shifting microbial metabolism to less efficient anaerobic SOC oxidation pathways. Kinetic and thermodynamic constraints reduce SOC oxidation rates within these anaerobic microsites by an order of magnitude relative to aerobic rates, and caused the preservation of bioavailable, polymeric and reduced organic compounds. Lifting these metabolic constraints through increased soil aeration (e.g., through changes in precipitation patterns or land use) may stimulate microbial oxidation of this inherently bioavailable SOC pool. Models that attribute the effects of texture merely to 'mineral protection' may therefore underestimate the vulnerability of soil C to global change impacts.

  3. Parenting Workshops on Child Development.

    ERIC Educational Resources Information Center

    Warren-Newport Public Library, Gurnee, IL.

    The parent education materials in this packet are intended for use by professionals, and some paraprofessionals, who work with children from birth through 5 years of age and with their families. Included are guidelines for choosing playthings for children of any age, and lists of suggested toys for children of various ages, and, in particular,…

  4. Social Variations in Perceived Parenting Styles among Norwegian Adolescents.

    PubMed

    Elstad, Jon Ivar; Stefansen, Kari

    2014-01-01

    Previous research has documented the associations between parenting and parenting styles and child and adolescent outcomes. Little is known, however, about the social structuring of parenting in contemporary Nordic welfare states. A possible hypothesis is that socioeconomic variations in parenting styles in present-day Norway will be small because of material affluence, limited income inequality, and an active welfare state. This study examines social variations in parenting as perceived by Norwegian adolescents (N = 1362), with a focus on four parenting style dimensions: responsiveness, demandingness, neglecting, and intrusive. Responsiveness seems to capture major divisions in parenting. Adolescents in families with fewer economic resources experienced their parents as somewhat less responsive, but responsiveness was not related to parents' education. Low parental education was on the other hand associated with perceptions of parents as neglecting and intrusive. Viewing parents as demanding did neither vary with parental education nor with family economy. Substantial variations in parenting styles persist in present-day Norway, and these variations correspond moderately with the families' placement in the social structure. Indicators of parenting and parenting styles may be useful indicators of some aspects of child and adolescent well-being. PMID:25132873

  5. A Reexamination of Amino Acids in Lunar Soils: Implications for the Survival of Exogenous Organic Material During Impact Delivery

    NASA Technical Reports Server (NTRS)

    Brinton, Karen L. F.; Bada, Jeffrey L.

    1996-01-01

    Using a sensitive high performance liquid chromatography technique, we have analyzed both the hot water extract and the acid hydrolyzed hot water extract of lunar soil collected during the Apollo 17 mission. Both free amino acids and those derived from acid labile precursors are present at a level of roughly 15 ppb. Based on the D/L amino acid ratios, the free alanine and aspartic acid observed in the hot water extract can be entirely attributed to terrestrial biogenic contamination. However, in the acid labile fraction, precursors which yield amino acids are apparently present in the lunar soil. The amino acid distribution suggests that the precursor is probably solar wind implanted HCN. We have evaluated our results with regard to the meteoritic input of intact organic compounds to the moon based on an upper limit of less than or equal to 0.3 ppb for alpha-aminoisobutyric acid, a non-protein amino acid which does not generally occur in terrestrial organisms and which is not a major amino acid produced from HCN, but which is a predominant amino acid in many carbonaceous chondrites. We find that the survival of exogenous organic compounds during lunar impact is less than or equal to 0.8%. This result represents an example of minimum organic impact survivability. This is an important first step toward a better understanding of similar processes on Earth and on Mars, and their possible contribution to the budget of prebiotic organic compounds on the primitive Earth.

  6. A reexamination of amino acids in lunar soils: implications for the survival of exogenous organic material during impact delivery.

    PubMed

    Brinton, K L; Bada, J L

    1996-01-01

    Using a sensitive high performance liquid chromatography technique, we have analyzed both the hot water extract and the acid hydrolyzed hot water extract of lunar soil collected during the Apollo 17 mission. Both free amino acids and those derived from acid labile precursors are present at a level of roughly 15 ppb. Based on the D/L amino acid ratios, the free alanine and aspartic acid observed in the hot water extract can be entirely attributed to terrestrial biogenic contamination. However, in the acid labile fraction, precursors which yield amino acids are apparently present in the lunar soil. The amino acid distribution suggests that the precursor is probably solar wind implanted HCN. We have evaluated our results with regard to the meteoritic input of intact organic compounds to the moon based on an upper limit of < or = 0.3 ppb for alpha-aminoisobutyric acid, a non-protein amino acid which does not generally occur in terrestrial organisms and which is not a major amino acid produced from HCN, but which is a predominant amino acid in many carbonaceous chondrites. We find that the survival of exogenous organic compounds during lunar impact is < or = 0.8%. This result represents an example of minimum organic impact survivability. This is an important first step toward a better understanding of similar processes on Earth and on Mars, and their possible contribution to the budget of prebiotic organic compounds on the primitive Earth. PMID:11541128

  7. Using magnetic susceptibility to discriminate between soil moisture regimes in selected loess and loess-like soils in northern Iran

    NASA Astrophysics Data System (ADS)

    Valaee, Morteza; Ayoubi, Shamsollah; Khormali, Farhad; Lu, Sheng Gao; Karimzadeh, Hamid Reza

    2016-04-01

    This study used discriminant analysis to determine the efficacy of magnetic measures for discriminating between four soil moisture regimes in northern Iran. The study area was located on loess deposits and loess-like soils containing similar parent material. Four soil moisture regimes including aridic, xeric, udic, and aquic were selected. A total of 25 soil profiles were drug from each regime and composite soil samples were collected within the moisture control section. A set of magnetic measures including magnetic susceptibility at low (χlf) and high (χhf) frequencies, frequency-dependent magnetic susceptibility (χfd), saturation isothermal remnant magnetization (SIRM), and isothermal remnant magnetization (IRM100 mT, IRM 20 mT) were measured in the laboratory. Dithionite citrate bicarbonate (Fed) and acid oxalate (Feo) contents of all soil samples were also determined. The lowest and highest χlf and χhf were observed in aquic and udic moisture regimes, respectively. A similar trend was obtained for Fed and Fed-Feo. The significant positive correlation between Fed and SIRM (r = 0.60; P < 0.01) suggested the formation of stable single domains (SSD) due to pedogenic processes. The results of discriminant analysis indicated that a combination of magnetic measures could successfully discriminate between the selected moisture regimes in the study area (average accuracy = 80%). It can thus be concluded that magnetic measures could be applied as a powerful indicator for differentiation of soil moisture regimes in the study area.

  8. Landmarks of History of Soil Science in Sri Lanka

    NASA Astrophysics Data System (ADS)

    Mapa, R.

    2012-04-01

    Sri Lanka is a tropical Island in the Southern tip of Indian subcontinent positioned at 50 55' to 90 50' N latitude and 790 42' to 810 53' E longitude surrounded by the Indian Ocean. It is an island 435 km in length and 224 km width consisting of a land are of 6.56 million ha with a population of 20 million. In area wise it is ranked as 118th in the world, where at present ranked as 47 in population wise and ranked 19th in population density. The country was under colonial rule under Portuguese, Dutch and British from 1505 to 1948. The majority of the people in the past and present earn their living from activities based on land, which indicates the important of the soil resource. The objective of this paper is to describe the landmarks of the history of Soil Science to highlight the achievements and failures, which is useful to enrich our present understanding of Sri Lankan soils. The landmarks of the history of Soil Science in Sri Lanka can be divided to three phases namely, the early period (prior to 1956), the middle period (1956 to 1972) and the present period (from 1972 onwards). During the early period, detailed analytical studies of coffee and tea soils were compiled, and these gave mainly information on up-country soils which led to fertilizer recommendations based on field trials. In addition, rice and forest soils were also studied in less detail. The first classification of Sri Lankan soils and a provisional soil map based on parent material was published by Joachim in 1945 which is a major landmark of history of Soil Science in Sri Lanka. In 1959 Ponnamperuma proposed a soil classification system for wetland rice soils. From 1963 to 1968 valuable information on the land resource was collected and documented by aerial resource surveys funded by Canada-Ceylon Colombo plan aid project. This covered 18 major river basins and about 1/4th of Sri Lanka, which resulted in producing excellent soil maps and information of the areas called the Kelani Aruvi Ara

  9. Lead in vegetation, forest floor material, and soils of the spruce-fir zone, Great Smoky Mountains National Park

    SciTech Connect

    Bogle, M.A.; Turner, R.R.

    1983-01-01

    Based on a survey during 1982, lead concentrations in vegetation, litter and soils of the spruce-fir zone of the Great Smoky Mountains National Park are generally less than values reported for similar sites in the northeastern United States and western Europe. As expected, lead concentrations increased with increasing age of spruce and fir foliage, and with increasing degree of decomposition of litter. Fir bole wood was higher in lead than spruce bole wood, but both species were far below acutely phytotoxic levels. Although the results of this study indicated no immediate cause for concern, periodic monitoring of lead and other metals in the spruce-fir zone should be continued to provide early detection of significant changes. 32 references, 1 figure, 4 tables.

  10. Mercury distribution in tropical soil profiles related to origin of mercury and soil processes.

    PubMed

    Grimaldi, Catherine; Grimaldi, Michel; Guedron, Stephane

    2008-08-15

    The aim of the study is to improve our understanding of the vertical and lateral variations in the mercury content [Hg] of tropical soils. In addition to the distance to anthropogenic sources of Hg, the most frequently evoked determining factor is the abundance of Hg-bearing phases. Soil processes (weathering, mass or water transfer) determine the abundance of carrier phases. We assume that soil processes also have a direct impact on the distribution of Hg and that the impact is different according to the lithogenic or atmospheric origin of this element. We compare two types of soil (oxisol and ultisol) in the French Guiana forest, at localities a few tens of metres apart and exhibiting very different Hg contents. We show that vertical profiles of [Hg] are strongly related to the variations of [Hg(atmospheric)], whereas [Hg(lithogenic)] varies little. The penetration of Hg(atmospheric) from the surface deposits is favoured down to a depth of 3 m in the oxisol and limited to the upper horizons of the ultisol because of contrasted hydraulic conductivity between the two soils. Hg is primarily of lithogenic origin in the alteritic horizons of the ultisol. The relative accumulation of Hg(lithogenic) during the progressive weathering of parental material is limited near the soil surface by the disequilibrium of secondary minerals. Remobilization of Hg(atmospheric) or Hg(lithogenic) stored in the soil is a function of the chemical or particulate erosion of Hg-bearing phases, particularly active in the upper horizons of the ultisol, where lateral flow occurs during rain events. The correlations observed between the iron or clay contents and [Hg] can be caused by the affinity of Hg for these carrier phases, but may also reflect the weathering and the transfer processes which affect together the fate of Hg and the mineralogical and chemical composition of the soil. PMID:18495215

  11. A Chance to Parent

    ERIC Educational Resources Information Center

    Yuan, Susan; Brillhart, Lindsay; Lightfoot, Elizabeth

    2012-01-01

    While parents with disabilities may face big challenges, with appropriate supports, many can be great parents. Just like other parents, they do not have to be responsible for every part of childrearing all by themselves. All parents rely on supports to help raise their children, such as day care, carpools, schools, babysitting co-ops, or advice…

  12. Parent Conferences. Beginnings Workshop.

    ERIC Educational Resources Information Center

    Duffy, Roslyn; And Others

    1997-01-01

    Presents six workshop sessions on parent conferences: (1) "Parents' Perspectives on Conferencing" (R. Duffy); (2) "Three Way Conferences" (G. Zeller); (3) "Conferencing with Parents of Infants" (K. Albrecht); (4) "Conferencing with Parents of School-Agers" (L. G. Miller); (5) "Cross Cultural Conferences" (J. Gonzalez-Mena); and (6) "Working with…

  13. Parent Mentor Manual.

    ERIC Educational Resources Information Center

    Voluntary Interdistrict Coordinating Council, St. Louis, MO.

    Legal action opposing school segregation in St. Louis (Missouri) in the 1970s resulted in a plan to facilitate student transfer and transportation. The Parent Mentor Program was established to help parents acquire skills to work effectively with their children's schools. Through the program, parents are put in touch with other parents who are…

  14. Involving Latino Parents.

    ERIC Educational Resources Information Center

    Quezada, Reyes L.; Diaz, Delia M.; Sanchez, Maria

    2003-01-01

    Describes barriers to Latino parent involvement in educational activities, factors to consider when involving Latino parents, and two examples of Latino involvement programs in California: Family Literacy Workshop at James Monroe Elementary School, Madera Unified School District, and Parents Take P.A.R.T. (Parent Assisted Reading Training) at…

  15. Children of Incarcerated Parents.

    ERIC Educational Resources Information Center

    Gabel, Katherine, Ed.; Johnston, Denise, Ed.

    The arrest and imprisonment of a parent is significant trauma for children, and children of incarcerated parents are at high risk for juvenile delinquency. This book for social workers, psychologists, and others who work with children whose parents are incarcerated examines parental incarceration, its impact on children, care and placement of…

  16. Turn Parents into Partners.

    ERIC Educational Resources Information Center

    Bobetsky, Victor V.

    2003-01-01

    Focuses on how music teachers can improve their interaction with parents and involve them in their child's music education. States that teachers should meet with parents early in the year and inform parents about their child's accomplishments. Offers ideas about discipline issues and how parents can become involved in the music program. (CMK)

  17. Parent Interview Schedule.

    ERIC Educational Resources Information Center

    Purdue Univ., Lafayette, IN. Educational Research Center.

    This 116-item interview schedule designed for parents who failed to respond to the Questionnaire for Parents, is individually administered to the mother of the child of elementary school age. It consists of scales measuring 14 parent variables plus a section devoted to demographic variables: (1) parent's achievement aspirations for the child, (2)…

  18. Questionnaire for Parents.

    ERIC Educational Resources Information Center

    Purdue Univ., Lafayette, IN. Educational Research Center.

    The 116-item parent que