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Sample records for pb isotope geochemistry

  1. Sr, Nd, Pb Isotope geochemistry and magma evolution of the potassic volcanic rocks, Wudalianchi, Northeast China

    USGS Publications Warehouse

    Junwen, W.; Guanghong, X.; Tatsumoto, M.; Basu, A.R.

    1989-01-01

    Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in eastern China. Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolution. They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.87Sr /86 Sr is higher and143Nd/144Nd is lower than the undifferentiated global values. In comparison to continental potash volcanic rocks, Pb isotopes are apparently lower. These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material. The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition. ?? 1989 Institute of Geochemistry, Chinese Academy of Sciences.

  2. Eocene Kashmar granitoids (NE Iran): Petrogenetic constraints from U-Pb zircon geochronology and isotope geochemistry

    NASA Astrophysics Data System (ADS)

    Shafaii Moghadam, Hadi; Li, Xian-Hua; Ling, Xiao-Xiao; Santos, Jose F.; Stern, Robert J.; Li, Qiu-Li; Ghorbani, Ghasem

    2015-02-01

    Kashmar granitoids outcrop for ~ 100 km along the south flank of the Sabzevar ophiolite (NE Iran) and consist of granodiorite and monzogranite along with subordinate quartz monzonite, syenogranite and aplitic dikes. These granitoids intruded Early to Middle Eocene high-K volcanic rocks and can spatially be grouped into eastern and western granitoids. Five samples of granite have identical zircon U-Pb ages of ca. 40-41 Ma. The granitoids have quite high K2O (~ 1.3-5.3 wt.%) and Na2O (~ 1.1-4.6 wt.%) with SiO2 ranging between ~ 62 and 77 wt.%. They are metaluminous to peraluminous, calc-alkaline and I-type in composition. Their chondrite-normalized REE patterns are characterized by LREE enrichment and show slight negative Eu anomalies. Kashmar granitoids have low whole rock εNd (- 0.43 to - 2.3), zircon εHf values (- 1.9 to + 7.2), and somewhat elevated δ18O (+ 6.1 to + 8.7‰) in the range of I-type granites. The Kashmar granitoids show Early Neoproterozoic zircon second-stage Hf and bulk rock Nd model ages at ca. 500-1000 Ma (associated with ca. 640 Ma old inherited zircons). Bulk rock Nd-Sr isotopic modeling suggests that 10-20% assimilation of Cadomian lower crust by juvenile mantle melts and then fractional crystallization (AFC process) can explain the Sr-Nd isotopic compositions of Kashmar granitoids. Kashmar granitoids are products of crustal assimilation by mantle melts associated with extension above the subducting Neotethyan Ocean slab beneath SW Eurasia. Similar subduction-related extension was responsible for the flare-up of Eocene-Oligocene magmatism across Iran, associated with core complex formation in central Iran.

  3. Isotopic geochemistry and cosmochemistry

    NASA Astrophysics Data System (ADS)

    Shchukoliukov, Iu. A.

    The book includes recent information on isotope geology, geochemistry, and cosmochemistry, discussed at a recent Soviet-Japanese symposium (at Irkutsk, USSR). Attention is given to numerical modeling of geochronometric systems, a classification of noble-gas components in the earth's interior, the feasibility of using ion microprobe for local isotope analysis of zircons for the purpose of deriving the early history of the earth (on the example of the Novopavlovsk complex from the Ukranian shield), a geological and geochronological study of the Ganalski complex of Kamchatka, and strontium isotopes as a criterion of the nature of acid melts (i.e., mantle- or crust-related). Other papers are on the geochronology and geology of Siberian kimberlites, the nature of sulfur from effusive rocks of the Kamchatka-Kuril-Japan island arc, mass-spectrometric studies of volatile components in exocontact rocks of alkaline-basic intrusions, and an analytical method for stable-isotope analysis in ultrasmall amounts of CO2 and its application to studies of the microscale isotopic zoning in calcite and graphite crystals in marble.

  4. Peri-Amazonian provenance of the Proto-Pelagonian basement (Greece), from zircon U-Pb geochronology and Lu-Hf isotopic geochemistry

    NASA Astrophysics Data System (ADS)

    Zlatkin, Olga; Avigad, Dov; Gerdes, Axel

    2014-01-01

    The basement of the Pelagonian zone of the Hellenides, in the Eastern Mediterranean realm, has been shaped by mid-Neoproterozoic (700 Ma) and Variscan (300 Ma) igneous activities. In the present study, detrital zircon U-Pb geochronology and Lu-Hf isotope geochemistry of ca. 700 Ma-aged granites and of pre-700 Ma metasediments from the Pelagonian zone allow a genuine perspective into the provenance and origin of this terrane which hosts one of the oldest sedimentary sequences known in SE Europe. Pelagonian crustal vestiges comprising 700 Ma granitoids and their hosting metasediments are termed here "Proto-Pelagonian".

  5. Petrogenesis of the Late Triassic volcanic rocks in the Southern Yidun arc, SW China: Constraints from the geochronology, geochemistry, and Sr-Nd-Pb-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Leng, Cheng-Biao; Huang, Qiu-Yue; Zhang, Xing-Chun; Wang, Shou-Xu; Zhong, Hong; Hu, Rui-Zhong; Bi, Xian-Wu; Zhu, Jing-Jing; Wang, Xin-Song

    2014-03-01

    Studies on zircon ages, petrology, major and trace element geochemistry, and Sr-Nd-Hf-Pb isotopic geochemistry of intermediate volcanic rocks from the Southern Yidun arc, Sanjiang-Tethyan Orogenic Belt, SW China have been undertaken in this paper. They are used to discuss the petrogenesis of these rocks and to constrain the tectonic setting and evolution of the Yidun arc. These intermediate volcanic rocks were erupted at ca. 220 Ma (U-Pb zircon ages). Trachyandesite is the dominant lithology among these volcanic rocks, and is mainly composed of hornblende and plagioclase, with minor clinopyroxene and biotite. A hornblende geobarometer suggests that the stagnation of magma in the lower crust, where plagioclase crystallization was suppressed while hornblende crystallized, giving rise to high Sr/Y ratios that are one of the distinguishing features of adakites, after the primary magma originated from the lithospheric mantle wedge. Steeply right-inclined Rare Earth Element (REE) pattern combined with high La/Yb ratios suggests adakitic affinity of these volcanic rocks, implying that slab-melt from the subducting oceanic crust is a necessary component in the primary magma. Besides, trace element geochemistry and isotopic geochemistry also indicate that partial melting of pelagic sediments in the subduction zone and noticeable contamination with the lower crust were involved in the evolution of parental magma of these volcanic rocks. Based on previous work on the Northern Yidun arc and this study, we propose that the subduction was initiated in the Northern Yidun arc and extended to the southern part and that the Northern Yidun arc is an island arc while the Southern Yidun arc represents a continental arc, probably caused by the existence of the Zhongza Massif, that was invoked to be derived from Yangtze Block, as a possible basement of the Southern Yidun arc.

  6. U-Pb geochronology, geochemistry, and H-O-S-Pb isotopic compositions of the Leqingla and Xin'gaguo skarn Pb-Zn polymetallic deposits, Tibet, China

    NASA Astrophysics Data System (ADS)

    Wang, Liqiang; Cheng, Wenbin; Tang, Juxing; Kang, Haoran; Zhang, Yan; Li, Zhuang

    2016-01-01

    The Leqingla and Xin'gaguo deposits are two representative skarn Pb-Zn polymetallic deposits of the Gangdese Pb-Zn polymetallic belt, Tibet, China. LA-ICP-MS zircon U-Pb dating of the mineralization-related biotite granites from both the Leqingla and Xin'gaguo deposits yielded weighted mean ages of 60.8 Ma and 56.5 Ma, respectively, which can be inferred as their mineralization ages. The Leqingla biotite granite is characterized by high Al2O3, total Fe, Na2O, and low K2O. In comparison, the Xin'gaguo biotite granite is characterized by relative higher K2O but lower Al2O3, total Fe, and Na2O. Geochemical and mineralogical characteristics indicate that the Leqingla and Xin'gaguo biotite granites are calc-alkaline I-type granite and High K calc-alkaline I-type granite, respectively. Both the Leqingla and Xin'gaguo biotite granites are enrichment in LREE and LILEs and depletion in HFSEs, and they were formed at the India-Asia collision stage. δ18O and δD values for the Leqingla and Xin'gaguo deposits are -8.8‰ to 5.3‰ and -140.4‰ to -90.1‰, -4.5‰ to 7.0‰ and -117.3‰ to -81.0‰, respectively, indicating magma fluids mixed with meteoric water in ore-forming fluids. δ34S values (-11.6‰ to -0.3‰) of ore sulfides from the Leqingla deposit show characteristics of biogenetic sulfur isotope compositions, suggesting sulfur for the Leqingla deposit were sourced from wall rocks of the Mengla and Luobadui Formation, which are rich in organic materials. δ34S values of ore sulfides from the Xin'gaguo deposits show bimodal distribution (-5.0‰ to -1.6‰ and 1.6-2.1‰), indicating sulfur in the Xin'gaguo deposit were derived from both wall rocks and magma. In the Leqingla deposit, most ore sulfides have the similar Pb isotopic compositions with that of the mineralization-related biotite granite, suggesting the biotite granite supplied most of the ore-forming metals. Pb isotopic compositions of ore sulfides and Hf isotopic compositions of biotite granite show

  7. Magmatic processes at Popocatepetl volcano, Mexico: petrology, geochemistry and Sr-Nd-Pb isotopes

    NASA Astrophysics Data System (ADS)

    Schaaf, P.; Stimac, J.; Siebe, C.; Mac¡as, J.

    2003-12-01

    crystallization, recycling, assimilation, and degassing in relatively evolved magma chambers. The 1996 and 1997 dome eruptions confirm that dacitic magma currently resides beneath Popo and is episodically recharged by more mafic magma, fostering eruption and excess degassing. Two-oxide thermometry and the presence of FeCu sulfide globules confirm that these magmas erupted at T = 930§C and fO2 = -10.2 log, below anhydrite stability. 87Sr/86Sr, e-Nd and 206Pb/204Pb ratios are between 0.70365 and 0.70463, +6.4 and +3.0, and 18.618 and 18.781, respectively. Andesitic to dacitic rocks of Popo formed by mafic recharge, fractionation, and mixing of dacitic to basaltic magmas in mature crustal chambers. Plagioclase accumulation and recycling related to protracted fractionation and assimilation of earlier emplaced magmas and their wallrocks was also important.

  8. Major element, REE, and Pb, Nd and Sr isotopic geochemistry of Cenozoic volcanic rocks of eastern China: implications for their origin from suboceanic-type mantle reservoirs

    USGS Publications Warehouse

    Basu, A.R.; Wang, Junwen; Huang, Wankang; Xie, Guanghong; Tatsumoto, M.

    1991-01-01

    Major- and rare-earth-element (REE) concentrations and UThPb, SmNd, and RbSr isotope systematics are reported for Cenozoic volcanic rocks from northeastern and eastern China. These volcanic rocks, characteristically lacking the calc-alkaline suite of orogenic belts, were emplaced in a rift system which formed in response to the subduction of the western Pacific plate beneath the eastern Asiatic continental margin. The rocks sampled range from basanite and alkali olivine basalt, through olivine tholeiite and quartz tholeiite, to potassic basalts, alkali trachytes, pantellerite, and limburgite. These rock suites represent the volcanic centers of Datong, Hanobar, Kuandian, Changbaishan and Wudalianchi in northeastern China, and Mingxi in the Fujian Province of eastern China. The major-element and REE geochemistry is characteristic of each volcanic suite broadly evolving through cogenetic magmatic processes. Some of the outstanding features of the isotopic correlation arrays are as follows: (1) NdSr shows an anticorrelation within the field of ocean island basalts, extending from the MORB end-member to an enriched, time-averaged high Rb Sr and Nd Sr end-member (EM1), (2) SrPb also shows an anticorrelation, similar to that of Hawaiian and walvis Ridge basalts, (3) NdPb shows a positive correlation, and (4) the 207Pb 204Pb vs 206Pb 204Pb plot shows linear arrays parallel to the general trend (NHRL) for MORB on both sides of the geochron, although in the 208Pb 204Pb vs 206Pb 204Pb plot the linear array is significantly displaced above the NHRL in a pattern similar to that of the oceanic island basalts that show the Dupal signatures. In all isotope correlation patterns, the data arrays define two different mantle components-a MORB-like component and an enriched mantle component. The isotopic data presented here clearly demonstrate the existence of Dupal compositions in the sources of the continental volcanic rocks of eastern China. We suggest that the subcontinental mantle

  9. Major, trace element and isotope geochemistry (Sr-Nd-Pb) of interplinian magmas from Mt. Somma-Vesuvius (Southern Italy)

    USGS Publications Warehouse

    Somma, R.; Ayuso, R.A.; de Vivo, B.; Rolandi, G.

    2001-01-01

    Major, trace element and isotopic (Sr, Nd, Pb) data are reported for representative samples of interplinian (Protohistoric, Ancient Historic and Medieval Formations) activity of Mt. Somma-Vesuvius volcano during the last 3500 years. Tephra and lavas exhibit significant major, trace element and isotopic variations. Integration of these data with those obtained by previous studies on the older Somma suites and on the latest activity, allows to better trace a complete petrological and geochemical evolution of the Mt. Somma-Vesuvius magmatism. Three main groups of rocks are recognized. A first group is older than 12.000 yrs, and includes effusive-explosive activity of Mt. Somma. The second group (8000-2700 yrs B.P.) includes the products emitted by the Ottaviano (8000 yrs. B.P.) and Avellino (3550 yrs B.P.) plinian eruptions and the interplinian activity associated with the Protohistoric Formation. Ancient Historic Formation (79-472 A.D.), Medieval Formation (472-1139 A.D.) and Recent interplinian activity (1631-1944 A.D.) belong to the third group of activity (79-1944 A.D.). The three groups of rocks display distinct positive trends of alkalis vs. silica, which become increasingly steeper with age. In the first group there is an increase in silica and alkalis with time, whereas an opposite tendency is observed in the two younger groups. Systematic variations are also evident among the incompatible (Pb, Zr, Hf, Ta, Th, U, Nb, Rb, Cs, Ba) and compatible elements (Sr, Co, Cr). REE document variable degrees of fractionation, with recent activity displaying higher La/Yb ratios than Medieval and Ancient Historic products with the same degree of evolution. N-MORB normalized multi-element diagrams for interplinian rocks show enrichment in Rb, Th, Nb, Zr and Sm (> *10 N-MORB). Sr isotope ratios are variable, with Protohistoric rocks displaying 87Sr/86Sr= 0.70711-0.70810, Ancient Historic 87Sr/86Sr=0.70665-0.70729, and Medieval 87Sr/86Sr=0.70685-0.70803. Neodymium isotopic

  10. Geology, isotope geochemistry and geochronology of the Jinshachang carbonate-hosted Pb-Zn deposit, southwest China

    NASA Astrophysics Data System (ADS)

    Zhou, Jia-Xi; Bai, Jun-Hao; Huang, Zhi-Long; Zhu, Dan; Yan, Zai-Fei; Lv, Zhi-Cheng

    2015-02-01

    The Jinshachang Pb-Zn deposit, an exceptionally radiogenic Pb-enriched sulfide deposit, hosted by dolostone of the Upper Sinian (Neoproterozoic) Dengying Formation and the Lower Cambrian Meishucun Formation, is located in the western Yangtze Block, about 300 km northeast of Kunming city in southwest China. Ore bodies in this deposit are dominated by strata-bound type and steeply dipping vein type. Primary ores in these two types are composed of sphalerite, galena, fluorite, barite and quartz with massive, banded, veined and disseminated structures. Twenty-seven ore bodies in the Jinshachang deposit host 4.6 million tons of sulfide ores at average grades of 4.07 wt.% Pb and 5.03 wt.% Zn. Quartz separates from the sulfide ores have δDH2O values ranging from -137‰ to -86.2‰ with an average of -114‰ (n = 7), lower than those of magmatic, metamorphic and meteoric water, suggesting a contribution of organic water. δ34SCDT values of ninety-one sulfide separates range from +1.1‰ to +13.4‰ with an average of +5.7‰, lower than those of evaporites (δ34SCDT = +15‰ to +35‰) in the Cambrian to Triassic sedimentary strata in NE Yunnan province. δ34SCDT values of eight barite separates range from +32‰ to +35‰ (average +34‰), within the range of evaporites. These data suggest that S2- in the hydrothermal fluids derived from evaporites by thermo-chemical sulfate reduction (TSR), whereas SO42- directly originated from the evaporites. Six sulfide separates have highly radiogenic 206Pb/204Pb ratios ranging from 20.74 to 21.18 (average 20.92), 207Pb/204Pb ratios ranging from 15.85 to 15.89 (average 15.87), and 208Pb/204Pb ratios ranging from 40.89 to 41.42 (average 41.16). The Pb isotopes of the sulfides plot above the upper crust Pb average evolution curve and overlap the Cambrian sedimentary rocks, but are different from the Sinian dolostone. This indicates a crustal source of Pb most likely derived from the Cambrian sedimentary rocks. The initial 87Sr/86Sr

  11. Sources of granite magmatism in the Embu Terrane (Ribeira Belt, Brazil): Neoproterozoic crust recycling constrained by elemental and isotope (Sr-Nd-Pb) geochemistry

    NASA Astrophysics Data System (ADS)

    Alves, Adriana; Janasi, Valdecir de Assis; Campos Neto, Mario da Costa

    2016-07-01

    Whole rock elemental and Sr-Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810-580 Ma), and is dominated by crust-derived relatively low-T (850-750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNdt (-8 to -10) and highest mg# (30-40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96-1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595-580 Ma) plutons have a spread of compositions from biotite granites with SiO2 as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO2). εNdT are characteristically negative (-12 to -18), with corresponding Nd TDM indicating sources with Paleoproterozoic mean crustal ages (2.0-2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNdt, highest 87Sr/86Srt (0.714-0.717) and lowest 208Pb/206Pb and 207Pb/206Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd-Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The

  12. Sr and Pb isotopic geochemistry of feldspars and implications for the growth of megacrysts in plutonic settings.

    NASA Astrophysics Data System (ADS)

    Munnikhuis, J.; Glazner, A. F.; Coleman, D. S.; Mills, R. D.

    2015-12-01

    Why megacrystic textures develop in silicic igneous rocks is still unknown. One hypothesis is that these crystals nucleate early in a magma chamber with a high liquid content. A supportive observation of this hypothesis is areas in plutons with high concentrations of megacrysts suggesting flow sorting. Another group of hypotheses suggest megacrystic textures form during protracted late-stage coarsening in a low-melt, interlocked matrix due to either thermal oscillations from incremental pluton emplacement, or Ostwald ripening. Isotopic analyses of large, euhedral K-feldspar megacrysts from the Cretaceous intrusive suites of the Sierra Nevada batholith (SNB) provide new insight into their origin. Megacrysts from the SNB reach the decimeter scale, are Or rich (85-90%), are perthitic, and host mineral inclusions of nearly all phases in the host rock. In-situ micro-drilling of transects, from core to rim, of the alkali feldspars provides material for Sr and Pb isotopic analyses by thermal ionization mass spectrometry (TIMS). Preliminary 87Sr/86Sr(i) isotopic data from samples from the Cathedral Peak Granodiorite, of the Tuolumne Intrusive Suite range from 0.706337 to 0.706452 (~1.6ɛSr) near the cores, whereas a sawtooth pattern with larger variability, 0.706179 to 0.706533 (~5ɛSr), occurs nears the rims. We interpret these preliminary data to indicate that the late portion of growth (i.e. crystal rim) was dominated by either cannibalism of small K-feldspar crystals with isotopic variability, or by addition of isotopically diverse late components to the magma. By comparing the Sr and Pb isotopic stratigraphy of megacrysts from a variety of rock matrices and different granitoids in the SNB isotopic trends can be evaluated to determine if crystals sizes are dependent on disequilibrium processes or grow at a steady state.

  13. Uranium-Lead Zircon Ages and Sr, Nd, and Pb Isotope Geochemistry of Selected Plutonic Rocks from Western Idaho

    USGS Publications Warehouse

    Unruh, Daniel M.; Lund, Karen; Kuntz, Mel A.; Snee, Lawrence W.

    2008-01-01

    Across the Salmon River suture in western Idaho, where allochthonous Permian to Cretaceous oceanic rocks are juxtaposed against Proterozoic North American rocks, a wide variety of plutonic rocks are exposed. Available data indicate much variation in composition, source, and structural state of these plutons. The plutonic rocks were long described as the western border zone of the Cretaceous Idaho batholith but limited pre-existing age data indicate more complicated origins. Because the affinity and age of the plutonic rocks cannot be reliably determined from field relations, TIMS U-Pb dating in conjunction with Sr, Nd, and Pb isotopic studies of selected plutons across the suture in western Idaho were undertaken. The data indicate three general groups of plutons including (1) those that intruded the island arc terranes during the Triassic and Jurassic, those that intruded near the western edge of oceanic rocks along the suture in the Early Cretaceous, and the plutons of the Idaho batholith that intruded Proterozoic North American rocks in the Late Cretaceous. Plutons that intruded Proterozoic North American rocks commonly include xenocrystic zircons and in several cases, ages could not be determined. The least radiogenic Sr and most radiogenic Nd are found among the Blue Mountains superterrane island arc samples. Suture-zone plutons have isotopic characteristics that span the range between Idaho batholith and island arc samples but mostly follow island arc signatures. Plutons of the Idaho batholith have the most radiogenic initial Pb and Sr ratios and the least radiogenic Nd of the samples analyzed.

  14. Petrology and Sr-Nd-Pb isotope geochemistry of Late Cretaceous continental rift ignimbrites, Kap Washington peninsula, North Greenland

    NASA Astrophysics Data System (ADS)

    Thorarinsson, Sigurjon B.; Holm, Paul M.; Duprat, Helene I.; Tegner, Christian

    2012-03-01

    The Late Cretaceous-Palaeocene (71-61 Ma) Kap Washington Group (KWG) volcanic sequence is exposed at the north coast of Greenland. The sequence is bimodal and was erupted in a continental rift setting during the opening of the Arctic Ocean. The succession exposed on the Kap Washington peninsula, which forms the bulk of the KWG sequence (> 5 km thick), has been sampled along four traverses with a combined stratigraphic thickness of ca. 1500 m. The sampled sequence is dominated by silicic ignimbrites (69-79 wt.% SiO2) showing geochemical features typical of ferroan, A-type granitoids. The ignimbrites range from sparsely phyric, mildly peraluminous compositions [ASI = Al2O3/(CaO + Na2O + K2O) = 1.05-1.20] to feldspar + quartz ± sodic amphibole ± Fe-Ti oxide phyric peralkaline compositions [PI = (Na2O + K2O)/Al2O3 = 1.00-1.40]. The peraluminous ignimbrites appear to overlie the peralkaline ignimbrites, although stratigraphy is complicated by faulting. Fiamme imbrication indicates that both types were erupted from a vent area located north of the Kap Washington peninsula. The peralkaline ignimbrites have Sr-Nd-Pb isotopic compositions which overlap with the compositions of KWG basalts, indicating a dominantly basaltic source. The more peralkaline compositions were generated by up to ca. 50% fractional crystallisation of alkali feldspar-quartz-dominated assemblages from mildly peralkaline parental magmas, themselves probably derived by fractionation of trachytic magmas. The peraluminous ignimbrites have slightly negative ɛNd(i) and more radiogenic 207Pb/204Pbi and 208Pb/204Pbi. Modelling indicates that they are not cogenetic with the peralkaline ignimbrites and they are inferred to have originated by partial melting of hybridised mafic crust. Petrographic evidence suggests that magma mixing was an important process and variations in Nd-Pb isotopes and trace element ratios indicate mixing between peralkaline and peraluminous magma batches.

  15. Zircon U-Pb dating, geochemistry and Sr-Nd-Pb-Hf-O isotopes for the Nan'getan granodiorites and mafic microgranular enclaves in the East Kunlun Orogen: Record of closure of the Paleo-Tethys

    NASA Astrophysics Data System (ADS)

    Xia, Rui; Wang, Changming; Qing, Min; Li, Wenliang; Carranza, Emmanuel John M.; Guo, Xiaodong; Ge, Liangsheng; Zeng, Guanzhong

    2015-10-01

    The East Kunlun Orogen in the Northern Qinghai-Tibet Plateau is an ideal region to investigate the geodynamic processes of magmatism related to the closure of the Paleo-Tethys Ocean. Here, we report petrology, zircon U-Pb geochronology, whole-rock geochemistry and multiple isotope data from granodiorites and the associated dioritic enclaves in a dominant Nan'getan granitoid in the East Kunlun Orogen. Zircon U-Pb ages indicate that the host granodiorites and dioritic enclaves were synchronously emplaced at ~ 243 Ma. The granodiorites are medium- to high-K calc-alkaline, metaluminous (A/CNK = 0.93-0.98), with high Al2O3 content (15.28%-16.10%), Mg# (47-49), very low Sr/Y ratios (127-217), high abundances of incompatible elements (Y = 3.87-8.36 ppm, Nb = 3.04-5.71 ppm, Th = 3.04-5.71 ppm), low (87Sr/86Sr)i (0.7050-0.7079), negative whole-rock εNd(t) (- 8.2 to - 5.8), (206Pb/204Pb) 243Ma of 18.520 to 18.772, (207Pb/204Pb) 243Ma of 15.611 to 15.650, (208Pb/204Pb) 243Ma of 38.227 to 38.528, δ18OSMOW = 6.8‰-9.1‰, εHf(t) of - 1.2 to + 2.4. The dioritic enclaves (SiO2 = 51.08%-56.29%) have Mg# values of 48-51, with negative Eu anomalies (δEu = 0.59-0.79), low (87Sr/86Sr)i (0.7058-0.7080), negative whole-rock εNd(t) (- 8.2 to - 5.8), (206Pb/204Pb) 243Ma of 18.376 to 18.809, (207Pb/204Pb)243Ma of 15.606 to 15.661, (208Pb/204Pb)243Ma of 38.244 to 38.540, δ18OSMOW = 5.6‰-10.0‰, εHf(t) of - 3.5 to + 1.7. These isotopic features of arc-type rocks from the East Kunlun suggest that the parental magmas of the Nan'getan granodiorites and the dioritic enclaves originated from an enriched lithospheric mantle. The Nan'getan granitoids might have recorded the northward subduction of the Paleo-Tethys ocean lithosphere following the initial collision of the Bayan Har-Songpan Ganzi-East Kunlun terrane and the closure of the Paleo-Tethys Ocean at ~ 243 Ma.

  16. High-spatial-resolution isotope geochemistry of monazite (U-Pb & Sm-Nd) and zircon (U-Pb & Lu-Hf) in the Old Woman and North Piute Mountains, Mojave Desert, California

    NASA Astrophysics Data System (ADS)

    Phillips, Stacy E.; Hanchar, John M.; Miller, Calvin F.; Fisher, Christopher M.; Lancaster, Penny J.; Darling, James R.

    2014-05-01

    Recent improvements in analytical capabilities allow us to reveal details of magmatic processes at an increasingly finer spatial and temporal scale. In situ analyses of the isotopic and trace element composition of accessory minerals at the sub-grain scale have proven to be effective tools for solving a wide range of geological problems. This study presents new data on accessory minerals including monazite & zircon, examined by in situ LA-ICP-MS and Laser Ablation Split Stream (LASS) techniques, analyzing multiple isotopic systems (U-Pb + Sm-Nd, and U-Pb + Lu-Hf in monazite and zircon, respectively) in order to track geochemical changes over time through a magmatic system. The late Cretaceous granitoids of the Old Woman Mountains in the Mojave Desert, California, provide an excellent opportunity to apply these analytical techniques. The peraluminous granites of the Sweetwater Wash, Painted Rock, and North Piute plutons represent different depths of the magmatic system, and are well understood in terms of field relations and whole-rock geochemistry. A preliminary study on the Sweetwater Wash monazites (Fisher et al., in preparation) has revealed significant inter-grain isotopic heterogeneity in the ɛNd composition of the source region (~1700 Ma); however, the U-Pb ages show an isotopic resetting during emplacement at ~75 Ma. This decoupling of U-Pb and Sm-Nd isotopic systems is suggested by Fisher et al. to be due to recrystallisation and/or dissolution-reprecipitation of monazite. If grain boundary diffusion of Pb overrides the more kinetically limited volume diffusion, then the U-Pb systematics will be reset while Sm and Nd remain immobile in the monazite structure as essential structural components of the lattice. This new data will allow the further investigation of these preliminary results, providing new insights into the observed isotopic disequilibrium, with the LASS technique accurately linking the multiple isotopic systems. This will provide important

  17. The Paleozoic Ozbak-Kuh carbonate-hosted Pb-Zn deposit of East Central Iran: Isotope (C, O, S, Pb) geochemistry and ore genesis

    NASA Astrophysics Data System (ADS)

    Ehya, Farhad

    2014-02-01

    Lead and zinc mineralization occurs in dolostones of the Middle Devonian Sibzar Formation at Ozbak-Kuh, which is located 150 km north of Tabas city in East Central Iran. The ore is composed of galena, sphalerite and calcite, with subordinate dolomite and bitumen. Wall-rock alterations include carbonate recrystallization and dolomitization. Microscopic studies reveal that the host rock is replaced by galena and sphalerite. The Pb-Zn mineralization is epigenetic and stratabound. The δ13C values of hydrothermal calcite samples fall in the narrow range between -0.3‰ and 0.8‰. The δ18O values in calcite display a wider range, between -14.5‰ and -11.9‰. The δ13C and δ18O values overlap with the oxygen and carbon isotopic compositions of Paleozoic seawater, indicating the possible important participation of Paleozoic seawater in the ore-forming fluid. The δ18O signature corresponds to a spread in temperature of about 70 °C in the ore-bearing fluid. The δ13C values indicate that the organic materials within the host rocks did not contribute significantly in the hydrothermal fluid. The δ34S values of galena and sphalerite samples occupy the ranges of 12.2‰-16.0‰ and 12.1-16.8‰, respectively. These values reveal that the seawater sulfate is the most probable source of sulfur. The reduced sulfur was most likely supplied through thermochemical sulfate reduction. The sulfur isotope ratios of co-precipitated sphalerite-galena pairs suggest that deposition of the sulfide minerals took place under chemical disequilibrium conditions. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of the galena samples represent average values of 18.08, 15.66, and 38.50, respectively. These ratios indicate that galena Pb likely originated from an orogenic source in which supracrustal rocks with high 238U/204Pb and 232Th/204Pb ratios are dominant. The average lead isotope model age portrays Cambrian age. This model age is not coeval with the host rocks, which are of middle

  18. Detrital zircon U-Pb geochronology, Hf isotopes and geochemistry constraints on crustal growth and Mesozoic tectonics of southeastern China

    NASA Astrophysics Data System (ADS)

    Meng, Lifeng; Li, Zheng-Xiang; Chen, Hanlin; Li, Xian-Hua; Zhu, Chen

    2015-06-01

    In situ U-Pb geochronological, Hf isotopic and REE geochemical analyses of detrital zircons from Mesozoic sandstones in central Jiangxi and east Hunan of the South China Block (SCB) are used to provide not only information about crustal evolution process, but more importantly new constraints on sedimentary provenances as well as Mesozoic basin evolutions in central SCB. A total of 417 concordant zircon analyses define five U-Pb age populations at ca. 2.6-2.3 Ga, ca. 2.0-1.7 Ga, ca. 1.0-0.7 Ga, ca. 500-400 Ma and ca. 300-200 Ma. Integrated analyses of zircon U-Pb ages and Hf isotopes of detrital zircons reveal five episodes of juvenile continental crust growth: ca. 2.5 Ga, ca. 1.7 Ga, ca. 850 Ma, ca. 440 Ma and ca. 230 Ma, with all but the ca. 2.5 Ga episode likely represent that of the SCB. None of the three samples from T3-J1 strata showed strong ca. 1850 Ma and ca. 230 Ma peaks suggesting that the T3-J1 sediments probably sourced from the Yangtze Block. In contrast, stronger peaks of ca. 1850 Ma and ca. 250-230 Ma in post-J1 strata relative to that of T3-J1 strata suggest a dominantly local Cathaysian provenance. In addition, the distinct low εHf(T) values for zircons of ca. 430 Ma from T3-J1 strata in comparison with higher εHf(T) values for that from post-J1 strata also support aforementioned viewpoint. Such sharp changes between the pre-J1 and post-J1 strata coincide with the remarkable change in regional palaeogeography from a broad shallow marine basin in the Late Triassic-Early Jurassic time to a basin-and-range-style province in the Middle Jurassic. The characteristics and time evolution of detrital zircons from the studied area are consistent with the flat-slab subduction model which involves the development of a broad sag basin during the T3-J1 time, and a rapid regional uplift in the Cathaysia Block caused by the reinitiating of normal subduction along the coastal region at ca. 190 Ma.

  19. U-Pb Dating, whole rock and Sr-Nd-Pb-O isotope geochemistry of collisional magmatism in the CACC: Çiçekdaǧ igneous complex (ÇIC)

    NASA Astrophysics Data System (ADS)

    Deniz, Kiymet; Kagan Kadioglu, Yusuf; Stuart, Finlay; Ellam, Rob; Boyce, Adrian; Condon, Daniel

    2015-04-01

    these intrusive rocks have experienced fractional crystallisation coupled with crustal assimilation. The calcalkaline and alkaline series show enrichment in LILE and LREE relative to HFSE and HREE. These rocks have moderate 208Pb/204Pb (38.87-39.16) and 207Pb/204Pb (15.62-15.71) and high 206Pb/204Pb (18.76-18.81). Both trace element and Pb isotope data indicate enriched mantle source (EM-II). Mafic alkaline rocks differed with their low 206Pb/204Pb (17.55-17.62). These rocks are derived from subduction modified lithospheric mantle. The geochemistry and Sr-Nd-O isotope data of ophiolitic rocks and late alkaline dykes are very similar. Both of them have flat REE pattern, high 87Sr/86Sr and 143Nd/144Nd, low δ18O values (1.9-4.0), moderate 208Pb/204Pb (38.81-38.97, 38.51-38.91) and 207Pb/204Pb (15.62-15.70, 15.54-15.69) and high 206Pb/204Pb (18.37-18.77, 18.39-18.73). All data indicate heterogeneous mantle source. Trace element ratio diagrams suggest depleted mantle source and subduction enrichment for late alkaline dykes. Dy versus Dy/Yb diagram and calculated partial melting curves suggest 20-25% degree of partial melting of amphibole-phlogopite bearing spinel lherzolitic mantle sources. Ba/Rb versus Rb/Sr diagram indicate the presence of amphibole in the mantle source of ophiolitic rocks and phlogopite for the late alkaline dykes. U-Pb dating of zircon yielded crystallization ages of 73.74±0.027-73.78±0.046 and 73.78±0.071 for calcalkaline series and alkaline series, respectively. Both series are coexistence and may have coevally been confined from same sources.

  20. Provenance and paleogeography of the Late Cretaceous Mengyejing Formation, Simao Basin, southeastern Tibetan Plateau: Whole-rock geochemistry, U-Pb geochronology, and Hf isotopic constraints

    NASA Astrophysics Data System (ADS)

    Wang, Licheng; Liu, Chenglin; Gao, Xiang; Zhang, Hua

    2014-05-01

    The Late Cretaceous Mengyejing Formation, which contains the only pre-Quaternary potash salt deposit in the Simao Basin, southeastern Tibet, is thought to be genetically related to the Maha Sarakham Formation in the Khorat Basin. The provenance and paleogeography of these two basins have been under debate, although little diagnostic evidence has been previously published. A combined analysis of whole rock geochemistry, zircon U-Pb chronology, and Hf isotopic compositions was performed to characterize the provenance of the Mengyejing Formation. These formation's sandstones are characterized by moderate chemical index of alteration (CIA) values. These values, together with plots of the Th/U-Th ratios, suggest that certain samples have undergone moderate weathering and sedimentary recycling. The major and trace elements (La/Th-Hf, Th/Sc-Zr/Sc, Eu/Eu*-Th/Sc, TiO2-Fe2O3T + MgO, Al2O3/SiO2-Fe2O3T + MgO, K2O/Na2O-SiO2) indicate that the sedimentary sources were felsic rocks from an active continental margin or continental arc with a minor amount of recycled sediment from a passive continental margin. The Mengyejing Formation contains detrital zircons primarily with U-Pb ages of 2.45-2.57 Ga, 1.8-1.9 Ga, 740-880 Ma, 410-470 Ma, and 215-300 Ma. The results reveal that the pre-Devonian zircons are derived from the recycled sediments of the Yangtze block originating in the Qinling Orogenic Belt, and they share this provenance with the coeval sediments in the Khorat Basin. The magmatic rocks of the Ailaoshan and Lincang areas are responsible for supplying the Devonian to Triassic detrital zircons. These provenance data combined with published paleocurrent results suggest that the Simao Basin was situated on the western margin of the Khorat Basin during the Late Cretaceous. The basins were connected when marine incursion occurred. We propose that pre-Devonian materials from the southwestern Sichuan Basin first supplied detritus to the Simao Basin and subsequently to the Khorat

  1. Isotope (Sr, Nd, Pb, O) and trace-element geochemistry of volcanics from the Erta'Ale range (Ethiopia)

    NASA Astrophysics Data System (ADS)

    Barrat, J. A.; Fourcade, S.; Jahn, B. M.; Cheminée, J. L.; Capdevila, R.

    1998-01-01

    The Erta'Ale range is the most important axial volcanic chain of the Afar region. The petrographic diversity of lavas erupted in this area is very important, ranging from magnesian transitional basalts to rhyolites. The variation in isotopic compositions and incompatible element ratios in the basalts (e.g., ɛNd = +4.5 to +7.5, ( {La}/{Yb}) n = 2.5 to 11) demonstrates the heterogeneous character for their mantle sources. Such heterogeneity can be interpreted by the participation of two mantle reservoirs: a depleted MORB and a HIMU OIB-type sources. These reservoirs are indistinguishable from those recently identified in the southern part of the Red Sea region. The isotopic data indicate that the contribution of continental sialic components is not significant in the petrogenesis of the volcanic rocks. Our data further suggest that the crust beneath the Erta'Ale volcanic range is not a thinned (Pan-african?) sialic crust, but could be gabbroic in nature. The acid volcanics have originated mostly through fractional crystallisation of basaltic magmas as revealed from major- and trace-element data and from the relatively homogeneous Sr and Nd isotopic ratios. However, the δ18O variation in the acid lavas suggests an important contribution from a low δ18O component in the petrogenesis of some low δ 18O acid lavas.

  2. Oxygen isotope geochemistry of zircon

    NASA Astrophysics Data System (ADS)

    Valley, John W.; Chiarenzelli, Jeffrey R.; McLelland, James M.

    1994-09-01

    The high-temperature and small sample size of an I.R. laser system has allowed the first detailed study of oxygen isotope ratios in zircon. Low-magnetism zircons that have grown during metamorphism in the Adirondack Mts., N.Y. preserve primary delta (O-18) values and low magnetism igneous zircons are likewise primary, showing no significant affect due to subsequent granulite facies metamorphism. The measured fractionation between zircon and garnet is delta (Gt-Zrc) = 0.0 + or - 0.2/mil (1(sigma)) for most low-magnetism zircons in meta-igneous rocks. The consistency of this value indicates equilibration at temperatures of 700 - 1100 C and little or no change in the equilibrium fractionation over this temperature range. In contrast, detrital low-magnetism zircons in quartzite preserve igneous compositions, up to 4/mil out of equilibrium with host quartz, in spite of granulite facies metamorphism. The oxygen isotope composition of zircon can be linked to U-Pb ages and can `see through' metamorphism, providing a new tool for deciphering complex igneous, metamorphic and hydrothermal histories. Zircons separated by magnetic susceptibility show a consistent correlation. Low-magnetism zircons have the lowest uranium contents, the most concordant U-Pb isotopic compositions, and primary delta (O-18) values. In contrast, high-magnetism zircons are up to 2/mil lower in delta (O-18) than low-magnetism zircons from the same rock. The resetting of oxygen isotope ratios in high-magnetism zircons is caused by radiation damage which creates microfractures and enhances isotopic exchange. Zircons from the metamorphosed anorthosite-mangerite-charnocite-granite (AMCG) suite of adirondacks have previously been dated (1125-1157 Ma) and classified as igneous, metamorphic or disturbed based on their physical and U-Pb isotopic characteristics. Low-magnetism zircons from the AMCG suite have high, nearly constant values of delta (O-18) that average 8.1 + or - 0.4/mil(1 sigma) for samples

  3. Late Neoproterozoic magmatism in South Qinling, Central China: Geochemistry, zircon U-Pb-Lu-Hf isotopes and tectonic implications

    NASA Astrophysics Data System (ADS)

    Wang, Ruirui; Xu, Zhiqin; Santosh, M.; Yao, Yuan; Gao, Li'e.; Liu, Chunhua

    2016-06-01

    The Neoproterozoic tectonic evolution of the northern margin of the Yangtze Block in South China remains debated. In this study, we present results from LA-ICP-MS zircon U-Pb geochronology on a suite of intermediate-felsic rocks in South Qinling, Central China which show a mean age of ca. 630 Ma. The zircon εHf(t) values of these rocks mostly range from + 0.44 to + 14.78. Geochemically, the granites and syenite show high total alkali contents, with enrichment in LREE, LILE (Rb, Ba, and K), and HFSE (Th, U, Nb, Ta, Zr, and Hf), and depletion in Sr, P, and Ti, similar to the features of A-type granites. The meta-diorite shows high Na2O, with depletion in Eu, Ti, and LILE (Sr, Rb, Ba, and K), and enrichment in HFSE (Th, U, Nb, Ta, Zr, and Hf). The geochemical features are consistent with formation of the intermediate-felsic suite through fractionation from underplated basaltic magma that originated from sub-continental lithospheric mantle metasomatized by asthenosphere-derived oceanic-island-basalt-like (OIB-like) melts, coupled with minor crustal contamination. We correlate the ca. 630 Ma magmatism with a back-arc rift setting that probably developed in relation to slab tearing during continued slab rollback.

  4. Zircon-apatite U-Pb geochronology, zircon Hf isotope composition and geochemistry of granite batholith in the northern Mexico: Implications for Tectonomagmatic evolution of southern Cordillera.

    NASA Astrophysics Data System (ADS)

    Mahar, M. A.; Goodell, P.

    2015-12-01

    We present the zircon-apatite U-Pb ages and zircon Hf isotope composition of the granite batholith exposed at the western boundary of Chihuahua. Granidiorite samples were analyzed from both, north and south of the Rio El Fuerte and Sinforosa Lineament. Based on previous studies, the WWN-EES trending Sinforosa Lineament is proposed as the manifestation of a terrane boundary between Seri in the north and Tahue terrane in the south. Zircon U-Pb data indicate that the magmatism spans a time period of 36 Ma from 89 to 53 Ma to the north of the Sinforosa Lineament while granodiorites in the south of the Sinforosa Lineament are dated at 59 Ma. The U-Pb apatite ages are variable in the north of the Sinforosa Lineament and range from 86-51 Ma. These apatite dates are 1-28 Ma younger than the corresponding zircon U-Pb crystallization ages. This indicates variable cooling rates and moderate to shallow emplacement. In contrast, in the south of the Sinforosa Lineament, the U-Pb apatite ages (64-59 Ma) are indistinguishable from the zircon U-Pb age (59 Ma), indicating rapid cooling and shallow emplacement. Zircon morphology and U-Pb dating revealed the absence of inherited component in the zircon ages, as no inheritance of any age has been observed. Most of the northwestern Mexico is underlain by Precambrian-Paleozoic-Jurassic basement. However, in the study area, U-Pb dating does not support the involvement of the older basement in generating the granite magmas. The weighted mean initial ɛHf (t) isotope composition of granodiorites on both sides of the Sinforosa Lineament varies from +2 to +5. However, Hf isotope composition in the south of the Sinforosa Lineament is more heterogeneous and relatively evolved with weighted Mean ɛHf (t) = +1.45. The Hf isotope composition is consistent with the previously reported near bulk silicate Sr-Nd isotope values. We suggest that the magmatic rocks in this region are not derived from melting of a felsic older crust beneath the batholith

  5. Geochemistry, Sr-Nd-Pb isotopes and geochronology of amphibole- and mica-bearing lamprophyres in northwestern Iran: Implications for mantle wedge heterogeneity in a palaeo-subduction zone

    NASA Astrophysics Data System (ADS)

    Aghazadeh, Mehraj; Prelević, Dejan; Badrzadeh, Zahra; Braschi, Eleonora; van den Bogaard, Paul; Conticelli, Sandro

    2015-02-01

    Lamprophyres of different age showing distinctive mineralogy, geochemistry and isotopic ratios are exposed in northwestern Iran. They can be divided into Late Cretaceous sannaite, Late Oligocene-Early Miocene camptonite (amphibole-bearing) and Late Miocene minette (mica-bearing) and spessartite (amphibole-bearing) lamprophyres. Sannaites have high-Ti amphibole along with high-Ti and Al clinopyroxene, and they are characterised by homogeneous enrichment in incompatible trace elements with troughs at Pb. Spessartites have hornblende and low-Al and Ti clinopyroxene, and they are characterised by enriched incompatible trace element pattern with depletions of Nb, Ta, Pb, and Ti with respect to large ion lithophile elements. Minettes have high-Ti and Al brown mica and low-Al and Ti clinopyroxene, and similar to spessartite, are characterised by fractionation of high field strength elements with respect to large ion lithophile elements, with troughs at Nb, Ta, and Ti and a peak at Pb. Minettes show high initial 87Sr/86Sr values up to 0.70760 and low initial 143Nd/144Nd down to 0.512463 with a negative correlation, consistent with the trace element distribution related with an enriched mantle source modified after sediment recycling during subduction and continental collision. Cretaceous sannaites and Early Miocene spessartites show low initial 87Sr/86Sr approaching 0.70447 and high 143Nd/144Nd values up to 0.512667, which are consistent with a depleted within-plate mantle source. Minette and spessartite lamprophyres show high initial 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values, whereas sannaites have lower, but variable, initial 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values with respect to those of calc-alkaline lamprophyres. Minettes originated by partial melting of a metasomatised lithospheric mantle following siliciclastic sediment recycling by subduction. In contrast, sannaites were generated from the partial melting of a similar lithospheric mantle that was

  6. Mesozoic magmatism and timing of epigenetic Pb-Zn-Ag mineralization in the western Fortymile mining district, east-central Alaska: Zircon U-Pb geochronology, whole-rock geochemistry, and Pb isotopes

    USGS Publications Warehouse

    Dusel-Bacon, Cynthia; Aleinkoff, J.N.; Day, W.C.; Mortensen, J.K.

    2015-01-01

    Epigenetic Pb-Zn-Ag ± Cu prospects in the western Fortymile district are spatially associated with splays of the northeast-trending Kechumstuk sinistral-normal fault zone and with ca. 68-66 Ma felsic intrusions and dikes. The similarity between Pb isotope compositions of feldspars from the Late Cretaceous igneous bodies and sulfides from the epithermal prospects suggests a Late Cretaceous age for most of the mineralization. Fluid flow along the faults undoubtedly played a major role in mineralization. We interpret displacement on the northeast-trending faults to be a far-field effect of dextral translation along Late Cretaceous plate-scale boundaries and faults that were roughly parallel to the subsequently developed Denali and Tintina fault systems, which currently bound the region.

  7. Origin of the granites and related Sn and Pb-Zn polymetallic ore deposits in the Pengshan district, Jiangxi Province, South China: constraints from geochronology, geochemistry, mineral chemistry, and Sr-Nd-Hf-Pb-S isotopes

    NASA Astrophysics Data System (ADS)

    Xu, Bin; Jiang, Shao-Yong; Luo, Lan; Zhao, Kui-Dong; Ma, Liang

    2016-05-01

    The Pengshan Sn and Pb-Zn polymetallic deposits are located in the south margin of the Jiujiang-Ruichang (Jiurui) district of the Middle-Lower Yangtze River Metallogenic Belt in South China. Four large deposits include Huangjinwa, Zengjialong, Jianfengpo, and Zhangshiba, the former three are Sn-dominant deposits which occur as stratiform orebodies in the contact zones of the Pengshan granites and within the country rock strata, whereas Zhangshiba consists of stratiform Pb-Zn orebodies within the Precambrian metasedimentary strata. In this study, we present results on zircon U-Pb ages, major and trace elements, and mineral chemistry as well as Sr-Nd-Hf isotope data of the granites, Pb and S isotopes of both the Sn-dominant and Pb-Zn dominant deposits, and U-Pb dating of cassiterite from the Pengshan district. SHRIMP and LA-ICP-MS zircon U-Pb dating shows that the Pengshan granites were emplaced in the Early Cretaceous (129-128 Ma), which is in good agreement with the U-Pb dating (130-128 Ma) of cassiterite from the Jianfengpo Sn deposit. The Pengshan granites consist mainly of weakly peraluminous highly fractionated I-type affinity granitic rocks. Detailed elemental and isotopic data suggest that the granites formed by partial melting of Mesoproterozoic metamorphic basement materials with minor input of mantle-derived melts. The mineral chemistry of biotite demonstrates that the Pengshan granitic magma had a low oxygen fugacity, thereby precluding the tin dominantly partitioning into the rock-forming silicate minerals and favoring accumulation in the exsolved residual liquid during magma crystallization stages. Sulfur isotopes show a relatively heavy sulfur isotopic composition from 5.8 to 17.6 ‰, and no difference for sulfur isotopes between the Sn deposits (5.8-13.4 ‰, Huangjinwa, Zengjialong, Jianfengpo) and the Pb-Zn deposit (mostly 7.1-13.0 ‰, except for one 17.6 ‰, Zhangshiba). The sulfur isotope data of pyrite from the host sedimentary rocks show

  8. Elemental and Sr Nd Pb isotopic geochemistry of Late Paleozoic volcanic rocks beneath the Junggar basin, NW China: Implications for the formation and evolution of the basin basement

    NASA Astrophysics Data System (ADS)

    Zheng, Jianping; Sun, Min; Zhao, Guochun; Robinson, Paul T.; Wang, Fangzheng

    2007-03-01

    The basement beneath the Junggar basin has been interpreted either as a micro-continent of Precambrian age or as a fragment of Paleozoic oceanic crust. Elemental and Sr-Nd-Pb isotopic compositions and zircon Pb-Pb ages of volcanic rocks from drill cores through the paleo-weathered crust show that the basement is composed mainly of late Paleozoic volcanic rock with minor shale and tuff. The volcanic rocks are mostly subalkaline with some minor low-K rocks in the western Kexia area. Some alkaline lavas occur in the central Luliang uplift and northeastern Wulungu depression. The lavas range in composition from basalts to rhyolites and fractional crystallization played an important role in magma evolution. Except for a few samples from Kexia, the basalts have low La/Nb (<1.4), typical for oceanic crust derived from asthenospheric melts. Zircon Pb-Pb ages indicate that the Kexia andesite, with a volcanic arc affinity, formed in the early Carboniferous (345 Ma), whereas the Luliang rhyolite and the Wucaiwan dacite, with syn-collisional to within-plate affinities, formed in the early Devonian (395 and 405 Ma, respectively). Positive ɛNd( t) values (up to +7.4) and low initial 87Sr/ 86Sr isotopic ratios of the intermediate-silicic rocks suggest that the entire Junggar terrain may be underlain by oceanic crust, an interpretation consistent with the juvenile isotopic signatures of many granitoid plutons in other parts of the Central Asia Orogenic Belt. Variation in zircon ages for the silicic rocks, different Ba, P, Ti, Nb or Th anomalies in the mafic rocks, and variable Nb/Y and La/Nb ratios across the basin, suggest that the basement is compositionally heterogeneous. The heterogeneity is believed to reflect amalgamation of different oceanic blocks representing either different evolution stages within a single terrane or possibly derivation from different terranes.

  9. Zircon U-Pb ages, geochemistry, and Sr-Nd-Pb-Hf isotopes of the Nuri intrusive rocks in the Gangdese area, southern Tibet: Constraints on timing, petrogenesis, and tectonic transformation

    NASA Astrophysics Data System (ADS)

    Chen, Lei; Qin, Ke-Zhang; Li, Guang-Ming; Li, Jin-Xiang; Xiao, Bo; Zhao, Jun-Xing; Fan, Xin

    2015-01-01

    Abundant magmatic rocks of various ages are exposed in Gangdese, southern Tibet. These rocks play an important role in understanding the tectonic transformation from the subduction of Neo-Tethyan oceanic crust to the collision of the Indian and Asian continents. Based on zircon U-Pb ages, geochemistry, and Sr-Nd-Pb-Hf isotopic data of the Late Cretaceous to early Oligocene (~ 96-30 Ma) intrusive rocks in the Nuri Cu-W-Mo deposit, we discuss the Late Cretaceous to early Oligocene tectonic transformation of the region and the origin of Oligocene Cu-W-Mo mineralization in southern Gangdese. The Nuri intrusive rocks represent three magmatic episodes: 96-91, 56-52, and 33-30 Ma. The 96-91 and 56-52 Ma rocks have relatively low (87Sr/86Sr)i (0.7041 to 0.7060), and high εNd(t) (+ 3.1 to + 3.5) and εHf(t) values (+ 3.7 to + 15); the 33-30 Ma rocks have relatively high (87Sr/86Sr)i (0.7061 to 0.7063) and Pb isotopes, and low εNd(t) (- 3.8 to - 1.8) and εHf(t) values (+ 0.6 to + 10.1). The three stages of intrusive rocks have geochemical characteristics that are similar to those of coeval rocks in Gangdese. The 96-91 and 33-30 Ma rocks are adakitic, whereas the 56-52 Ma rocks have characteristics of arc calc-alkaline magmatic rocks. The 96-91 Ma rocks were produced by the partial melting of Neo-Tethyan basaltic oceanic crust and minor sediments, whereas the 56-52 Ma rocks were generated by the partial melting of juvenile crust and the 33-30 Ma rocks were formed by the melting of Indian plate lower crust contaminated with overlying mantle materials. On the basis of the regional tectonic and magmatic characteristics, we suggest that Neo-Tethyan oceanic slab subduction and slab roll-back occurred from ~ 100 to 65 Ma, collision between the Indian and Asian continents occurred at 65 to 40 Ma, Neo-Tethyan oceanic slab break-off took place at ~ 50 Ma, and the Indian continent subducted northwards beneath the Asian continent at ~ 30 Ma. From the Late Cretaceous (96-91 Ma) to

  10. Whole-Rock Geochemistry and Zircon U-Pb Isotopes of the Late Cretaceous Granitoids of the Eastern Taurus (turkey): Implications for Petrogenesis and Geodynamic Setting

    NASA Astrophysics Data System (ADS)

    Beyarslan, Melahat; Lin, Yu-Chin; Chung, Sun-Lin; Feyzi Bingol, Ahmet; Yildirim, Esra

    2015-04-01

    The granitoid plutons out crop largely in the Eastern Taurus, in Turkey. New data, including a combination of field relation, U-Pb zircon geochronology and rock geochemistry on the granitoids in the Eastern Taurus of the Tethyan orogen in Turkey, come from four plutons ( Pertek, Baskil, Göksun and Şifrin). Pertek, Baskil and Göksun plutons consist mainly of diorite, quartz-diorites, tonalite, granodiorites and granites of I-type, with minor monzonite, the Şifrin pluton consists of syenogranite, syenite, monzogranite, monzonite. U-Pb zircon geochronology of four samples of diorite and granite from Pertek and Baskil plutons indicate ages of 86±2 - 79 ± 1Ma. U-Pb zircon geochronology of four samples from the Şifrin granitoid yield ages 77±1-72±1 Ma. Considering these ages, emplacement of the plutons took place during Late Cretaceous (Santonian-Campanian), from 86 to 72 Ma. Although the SiO2 of rocks forming granitoids varies in wide range ( 46.792- 74.092 wt%), they show arc and syn-collision geochemical affinity, with enrichment of LILE (K, Rb, Sr and Ba) and depletion of HFSE (Nb, Ta and Ti) and P. Geochemical data indice that the diorite, tonalite and granodiorite are low-K tholeiite, monzodiorite, monzogranite, granite and K-granite are calc-alkaline and high-K calc-alkaline and monzonite, syenomonzonite and syenite of Şifrin pluton and some samples of the Pertek pluton are shoshonitic. The Eastern Taurus granitoids would be formed by partial melting of possible juvenile arc-derived rocks during subduction of the South Branch of the Neo-Tethyan oceanic crust and subsequent arc-continent collision.

  11. Zircon U-Pb dating, geochemistry and Sr-Nd-Pb-Hf isotopes of the Wajilitag alkali mafic dikes, and associated diorite and syenitic rocks: Implications for magmatic evolution of the Tarim large igneous province

    NASA Astrophysics Data System (ADS)

    Zou, Si-Yuan; Li, Zi-Long; Song, Biao; Ernst, Richard E.; Li, Yin-Qi; Ren, Zhong-Yuan; Yang, Shu-Feng; Chen, Han-Lin; Xu, Yi-Gang; Song, Xie-Yan

    2015-01-01

    The Early Permian Tarim large igneous province (Tarim LIP) consists mainly of basaltic lavas, mafic-ultramafic intrusions including dikes and, syenite bodies in the Tarim Basin, NW China. A major unit of the Tarim LIP, the Wajilitag intrusive complex, consists of olivine pyroxenite, clinopyroxenite and gabbro units (from bottom to top), diorite and syenite rocks occurred in the upper part of the complex and alkali mafic dikes intrude the clinopyroxenite phase. Here we report the zircon U-Pb age and Hf isotopes, geochemical characteristics and Sr-Nd-Pb isotopic data of the alkali mafic dikes, and diorite, aegirine-nepheline syenite and syenite porphyry units in the Wajilitag intrusive complex. Zircons from the diorite and alkali mafic rocks yield concordant crystallization ages of 275.2 ± 1.2 Ma and 281.4 ± 1.7 Ma, respectively. The diorite and syenitic rocks in Wajilitag area have a narrow range of SiO2 contents (51.9-57.3 wt.%), and are enriched in total alkalis (Na2O + K2O = 8.3-14.3 wt.%), among which the aegirine-nepheline syenite and syenite porphyry have the geochemical affinity of A-type granites. The alkali mafic rocks and syenitic rocks have high Al2O3 (19.4-21.1 wt.%), Zr, Hf, Ba contents, total rare earth element abundances and LREE/HREE ratios and low Mg# value, K, P and Ti contents. Diorites have lower Al2O3 contents, total REE abundances and LREE/HREE ratios and higher Mg# values than the alkali mafic rocks and syenitic rocks. The diorites and syenitic rocks have low initial 87Sr/86Sr ratios (0.7034-0.7046), and high εNd(t) values (0.1-4.1) and zircon εHf(t) values (- 0.9-4.4). All the diorites and syenitic rocks show the 206Pb/204Pb ratios ranging of 18.0-19.5, 207Pb/204Pb of 15.4-15.6 and 208Pb/204Pb of 38.0-39.9. Sr-Nd isotopic ratios indicate a FOZO-like mantle source for the diorite and syenitic rocks, similar to that of the mafic-ultramafic rocks in the Wajilitag complex. In contrast, zircon Hf isotopes of basalt and syenite elsewhere in the

  12. Carbon isotope geochemistry and geobiology

    NASA Technical Reports Server (NTRS)

    Desmarais, D.

    1985-01-01

    Carbon isotope fractionation values were used to understand the history of the biosphere. For example, plankton analyses confirmed that marine extinctions at the end of the Cretaceous period were indeed severe (see Hsu's article in Sundquist and Broeker, 1984). Variations in the isotopic compositions of carbonates and evaporitic sulfates during the Paleozoic reflect the relative abundances of euxinic (anoxic) marine environments and organic deposits from terrestrial flora. The carbon isotopic composition of Precambrian sediments suggest that the enzyme ribulose bisphosphate carboxylase has existed for perhaps 3.5 billion years.

  13. Detrital zircon U-Pb geochronology, Lu-Hf isotopes and REE geochemistry constrains on the provenance and tectonic setting of Indochina Block in the Paleozoic

    NASA Astrophysics Data System (ADS)

    Wang, Ce; Liang, Xinquan; Foster, David A.; Fu, Jiangang; Jiang, Ying; Dong, Chaoge; Zhou, Yun; Wen, Shunv; Van Quynh, Phan

    2016-05-01

    In situ U-Pb geochronology, Lu-Hf isotopes and REE geochemical analyses of detrital zircons from Cambrian-Devonian sandstones in the Truong Son Belt, central Vietnam, are used to provide the information of provenance and tectonic evolution of the Indochina Block. The combined detrital zircon age spectra of all of the samples ranges from 3699 Ma to 443 Ma and shows with dominant age peaks at ca. 445 Ma and 964 Ma, along with a number of age populations at 618-532 Ma, 1160-1076 Ma, 1454 Ma, 1728 Ma and 2516 Ma. The zircon age populations are similar to those from time equivalent sedimentary sequences in continental blocks disintegrated from the East Gondwana during the Phanerozoic. The younger zircon grains with age peaks at ca. 445 Ma were apparently derived from middle Ordovician-Silurian igneous and metamorphic rocks in Indochina. Zircons with ages older than about 600 Ma were derived from other Gondwana terrains or recycled from the Precambrian basement of the Indochina Block. Similarities in the detrital zircon U-Pb ages suggest that Paleozoic strata in the Indochina, Yangtze, Cathaysia and Tethyan Himalayas has similar provenance. This is consistent with other geological constrains indicating that the Indochina Block was located close to Tethyan Himalaya, northern margin of the India, and northwestern Australia in Gondwana.

  14. A-type granites from the Pan-African orogenic belt in south-western Chad constrained using geochemistry, Sr-Nd isotopes and U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Isseini, Moussa; André-Mayer, Anne-Sylvie; Vanderhaeghe, Olivier; Barbey, Pierre; Deloule, Etienne

    2012-11-01

    The Zabili granitic pluton (SW Chad) exposed in the Mayo Kebbi massif is dominated by a coarse-grained hornblende biotite granite grading into a fine-grained biotite granite along its southern margin. Petrologic (micrographic intergrowth of quartz and alkali feldspars, granophyric microstructures, the presence of fluorite and bastnaesite as accessory minerals) and geochemical data (high silica, alkalis and Fe/Mg, depletions in CaO, MgO, TiO2; high Ga, Nb, Zr, Ga/Al, REE, depletions in Ba, Sr, Eu and compatible elements) indicate that this pluton consists of A-type granites crystallized from hot (apatite and zircon saturation temperatures ranging from 744 °C to 923 °C), extremely differentiated magmas. U-Pb zircon geochronology indicates that the magmas crystallized at 567 ± 10 Ma and reveals the presence of older Neoproterozoic xenocrystic zircons at 668 ± 5 Ma in both facies. Within the fine-grained biotite granite, discordant zircons with U-Pb and Pb-Pb ages ranging from Neoproterozoic to Archaean are also reported. The 668 ± 5 Ma old zircons are considered to derive from country-rocks while discordant zircons, characterized by angular shapes, internal fractures and inherited cores, are likely to represent multi-sources detrital crystals that have recorded at least one metamorphic event. Old pre-Neoproterozoic zircons are reported for the first time for rocks of the Mayo Kebbi massif and they attest to the contribution of an old basement (likely to be the Eastern Nigeria basement and/or the Congo craton) involved in a collisional event with a juvenile Neoproterozoic crust prior to the emplacement of the Zabili granitic pluton. Initial ɛNd values calculated for the Zabili pluton range from + 2.6 to + 7.0, the highest value recorded by one sample from the coarse-grained hornblende-biotite granite being close to the one of the depleted mantle at 570 Ma (ɛNd = + 7.4). Combining geochronology, Nd isotopes composition and geochemical modeling, leads us to

  15. Paleoproterozoic crustal evolution in the East Sarmatian Orogen: Petrology, geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of andesites from the Voronezh massif, Western Russia

    NASA Astrophysics Data System (ADS)

    Terentiev, R. A.; Savko, K. A.; Santosh, M.

    2016-03-01

    Andesites and related plutonic rocks are major contributors to continental growth and provide insights into the interaction between the mantle and crust. Paleoproterozoic volcanic rocks are important components of the East Sarmatian Orogen (ESO) belonging to the East European Craton, although their petrogenesis and tectonic setting remain controversial. Here we present petrology, mineral chemistry, bulk chemistry, Sr-Nd isotopes, and zircon U-Pb geochronological data from andesites and related rocks in the Losevo and Vorontsovka blocks of the ESO. Clinopyroxene phenocrysts in the andesites are depleted in LREE, and enriched in HFSE (Th, Nb, Zr, Hf, Ti) and LILE (Ba, Sr). Based on the chemistry of pyroxenes and whole rocks, as well as Fe-Ti oxides, we estimate a temperature range of 1179 to 1262 °C, pressures of 11.3 to 13.0 kbar, H2O content of 1-5 wt.%, and oxygen fu gacity close to the MH buffer for the melts of the Kalach graben (KG) and the Baygora area (BA) andesites. Our zircon U-Pb geochronological data indicate new zircon growth during the middle Paleoproterozoic as displayed by weighted mean 207Pb/206Pb ages of 2047 ± 17 Ma and 2040 ± 16 Ma for andesite and dacite-porphyry of the BA, and 2050 ± 16 Ma from high-Mg basaltic andesite of the KG. The andesites and related rocks of the KG and BA are characterized by high magnesium contents (Mg # up to 0.68). All these volcanic rocks are depleted in LREE and HFSE, and display negative Nb and Ti anomalies relative to primitive mantle. The high-Mg bulk composition, and the presence of clinopyroxene phenocrysts suggests that the parent melts of the KG and BA suite were in equilibrium with the mantle rocks. The rocks show positive εNd(T) values and low initial 87Sr/86Sr, suggesting that the magmas were mostly derived from metasomatized mantle source. The geochemical differences between the two andesite types are attributed to: the predominance of fractional crystallization, and minor role of contamination in the

  16. Isotope geochemistry in 1990s

    SciTech Connect

    Billo, S.M.

    1995-12-31

    The intense interest in radioactive minerals as a source of atomic energy, and their application in searching for ore deposits and also in gamma-ray and neutron logging oil wells, have opened new vistas in every science. Many minerals containing elements of high atomic weight are radioactive, and emit a radiation which affects a photographic plate and may be detected by means of a sensitive phosphorescent screen. Most of the elements as found in nature are a mixture of isotopes. isotopes are atoms of one element which have different masses. Uranium, thorium, potassium, and rubidium isotopes are also used to date minerals and rocks. Organic materials that have been in equilibrium with CO{sub 2}-photosynthetic cycle during the past 50,000 years are dated by carbon-14 method. The stable isotopes of H{sub 2}, C, N{sub 2}, O{sub 2}, and S are intimately associated with the atmosphere, hydrosphere, and lithosphere and are used in probing water resources.

  17. Zircon U-Pb age, Hf isotopic compositions and geochemistry of the Silurian Fengdingshan I-type granite Pluton and Taoyuan mafic-felsic Complex at the southeastern margin of the Yangtze Block

    NASA Astrophysics Data System (ADS)

    Zhong, Yufang; Ma, Changqian; Zhang, Chao; Wang, Shiming; She, Zhenbing; Liu, Lei; Xu, Haijin

    2013-09-01

    This work presents an integrated study of zircon U-Pb ages and Hf isotope along with whole-rock geochemistry on Silurian Fengdingshan I-type granites and Taoyuan mafic-felsic intrusive Complex located at the southeastern margin of the Yangtze Block, filling in a gap in understanding of Paleozoic I-type granites and mafic-intermediate igneous rocks in the eastern South China Craton (SCC). The Fengdingshan granite and Taoyuan hornblende gabbro are dated at 436 ± 5 Ma and 409 ± 2 Ma, respectively. The Fengdingshan granites display characteristics of calc-alkaline I-type granite with high initial 87Sr/86Sr ratios of 0.7093-0.7127, low ɛNd(t) values ranging from -5.6 to -5.4 and corresponding Nd model ages (T2DM) of 1.6 Ga. Their zircon grains have ɛHf(t) values ranging from -2.7 to 2.6 and model ages of 951-1164 Ma. The Taoyuan mafic rocks exhibit typical arc-like geochemistry, with enrichment in Rb, Th, U and Pb and depletion in Nb, Ta. They have initial 87Sr/86Sr ratios of 0.7053-0.7058, ɛNd(t) values of 0.2-1.6 and corresponding T2DM of 1.0-1.1 Ga. Their zircon grains have ɛHf(t) values ranging from 3.2 to 6.1 and model ages of 774-911 Ma. Diorite and granodiorite from the Taoyuan Complex have initial 87Sr/86Sr ratios of 0.7065-0.7117, ɛNd(t) values from -5.7 to -1.9 and Nd model ages of 1.3-1.6 Ga. The petrographic and geochemical characteristics indicate that the Fengdingshan granites probably formed by reworking of Neoproterozoic basalts with very little of juvenile mantle-derived magma. The Taoyuan Complex formed by magma mixing and mingling, in which the mafic member originated from a metasomatized lithospheric mantle. Both the Fengdingshan and Taoyuan Plutons formed in a post-orogenic collapse stage in an intracontinental tectonic regime. Besides the Paleozoic Fengdingshan granites and Taoyuan hornblende gabbro, other Neoproterozoic and Indosinian igneous rocks located along the southeastern and western margin of the Yangtze Block also exhibit decoupled

  18. Late Triassic intrusive complex in the Jidong region, Jiamusi-Khanka Block, NE China: Geochemistry, zircon U-Pb ages, Lu-Hf isotopes, and implications for magma mingling and mixing

    NASA Astrophysics Data System (ADS)

    Yang, Hao; Ge, Wen-chun; Zhao, Guo-chun; Dong, Yu; Xu, Wen-liang; Ji, Zheng; Yu, Jie-jiang

    2015-05-01

    Whole-rock major and trace element geochemistry together with zircon U-Pb ages and Lu-Hf isotope compositions are reported for a Late Triassic intrusive complex in the Jidong region, Jiamusi-Khanka Block, NE China. Zircon U-Pb dating yields ages between 211 and 208 Ma for enclaves of microgranular diorite and quartz diorite, and between 211 and 209 Ma for the host granitoids. These ages correlate with a previously established intensive Late Triassic magmatic event along the eastern Asian margin. Field observations, together with petrographic features, geochemistry, and zircon Hf isotope data, preclude simple crystal fractionation or restite unmixing as a genetic link for the various rock types within the intrusive complex. The syenogranite suite has high SiO2 (75.5-76.3 wt.%) and low MgO (0.15-0.19 wt.%), and yields enriched LILE and LREE patterns. Most of the zircons in the syenogranites have two-stage model ages of 766 and 1461 Ma, together with positive εHf(t) values of + 0.6 to + 9.1. These results indicate that the granitoid magmas were generated by partial melting of Meso- to Neoproterozoic lower crust. The gabbro suite has a restricted range of SiO2 (46.1-51.9 wt.%) together with high Mg# values (49-70) and high concentrations of Ni, Co, and Cr. Zircons from two diorite samples have single-stage Hf model ages of 557-787 Ma and εHf(t) values of + 1.9 to + 8.3 that are consistent with the coeval gabbros previously studied in the Jidong region. These features, together with the observation that all the gabbros are enriched in LREE and LILE, suggest that the mafic magmas were derived from melting of depleted Neoproterozoic lithospheric mantle that had been metasomatized by slab-derived fluids. It is concluded that the dominant igneous suites within the Late Triassic intrusive complex formed by mingling/mixing of felsic and mafic magmas. The geochemical data, combined with regional geological investigations, indicate that the Late Triassic intrusive complex

  19. Cryogenian alkaline magmatism in the Southern Granulite Terrane, India: Petrology, geochemistry, zircon U-Pb ages and Lu-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Santosh, M.; Yang, Qiong-Yan; Ram Mohan, M.; Tsunogae, T.; Shaji, E.; Satyanarayanan, M.

    2014-11-01

    The Southern Granulite Terrane (SGT) in India preserves the records of the formation and recycling of continental crust from Mesoarchean through Paleoproterozoic to Neoproterozoic and Cambrian, involving multiple subduction-accretion-collision associated with major orogenic cycles. A chain of unmetamorphosed and undeformed alkaline magmatic intrusions occurs along the northern margin of the SGT aligned along paleo-suture zones. Here we investigate two representative plutons from this suite, the Angadimogar syenite (AM) and the Peralimala alkali granite (PM) through field, petrological, geochemical, zircon U-Pb and Lu-Hf studies. Magma mixing and mingling textures and mineral assemblages typical of alkaline rocks are displayed by these plutons. The whole-rock major and trace element data characterize their alkaline nature. In trace element discrimination diagrams, the AM rocks straddle between the VAG (volcanic-arc granites) and WPG (within plate granites) fields with most of the samples confined to the VAG field, whereas the PM rocks are essentially confined to the WPG field. The diversity in some of the geochemical features between the two plutons is interpreted to be the reflection of source heterogeneities. Most zircon grains from the AM and PM plutons display oscillatory zoning typical of magmatic crystallization although some grains, particularly those from the PM pluton, show core-rim structures with dark patchy zoned cores surrounded by irregular thin rims resulting from fluid alteration. The weighted mean 206Pb/238U ages of the magmatic zircons from three samples of the AM syenite are in the range of 781.8 ± 3.8 Ma to 798 ± 3.6 Ma and those from two samples of the PM alkali granite yield ages of 797.5 ± 3.7 Ma and 799 ± 6.2 Ma. A mafic magmatic enclave from the AM pluton shows weighted mean 206Pb/238U age of 795 ± 3.3 Ma. The AM and PM plutons also carry rare xeneocrystic zircons which define upper intercept concordia ages of 3293 ± 13 Ma and 2530

  20. U-Pb-Nd-Hf isotope geochemistry of the Mesoproterozoic A-type granites in Mannefallknausane, western Dronning Maud Land, Antarctica

    NASA Astrophysics Data System (ADS)

    Ramo, O. T.; Kurhila, M.; Luttinen, A. V.; Andersen, T.

    2009-12-01

    The bedrock of western Dronning Maud Land, Antarctica records several stages of anorogenic magmatism. The Grenvillean-age metamorphic basement gneisses of Heimefrontfjella and Mannefallknausane were intruded by mafic dikes (Bauer et al., 2003) and A-type granite plutons (Jacobs, 1991) at circa 1 Ga. A 590 Ma suite of mafic dikes manifests a subsequent episode of Proterozoic anorogenic magmatism (Bauer et al., 2003). Jurassic (180 Ma) continental flood basalts (CFBs), their intrusive equivalents, and associated alkaline mafic rocks represent the third and youngest episode of anorogenic magmatism (Luttinen et al., 1998; Romu and Luttinen, 2007). The crystalline bedrock in western Dronning Maud Land is composed of the Archean Grunehogna craton and the Mesoproterozoic Maud mobile belt. About 100 km south of Archean-Proterozoic transition, in the Proterozoic realm, nunataks of Mannefallknausane (74.5oS, 15oW) are dominated by Precambrian granitoid rocks and rare paragneisses. Three principal granites can be identified: a white, garnet-bearing K-feldspar-megacrystic biotite granite; a red biotite-hornblende±clinopyroxene granite with or without plagioclase-mantled K-feldspar-megacrysts (rapakivi texture); and a dark green porphyritic charnockite with orthopyroxene and hornblende. The presence of rapakivi texture, the mode of occurrence, and geochemical composition of the granites of Mannefallknausane imply A typology. For two varieties of the red granite (wiborgite and pyterlite), our new U-Pb data imply crystallization ages of 1073 ± 6 Ma and 1084 ± 8 Ma, respectively. These are compatible with a U-Pb zircon upper intercept age of 1073 ± 8 Ma of the charnockite (Arndt et al., 1991). The initial Nd isotope composition of these rocks is relatively radiogenic [epsilon-Nd (1075 Ma) value of the biotite granite -0.5; red granite +0.3, +0.5; charnockite +1.4], as is that of a country-rock gneiss from the surrounding bedrock (+1.0). Initial zircon epsilon-Hf values of the

  1. Trace element and Sr-Nd-Pb isotope geochemistry of Rungwe Volcanic Province, Tanzania: Implications for a superplume source for East Africa Rift magmatism

    NASA Astrophysics Data System (ADS)

    Castillo, Paterno; Hilton, David; Halldórsson, Sæmundur

    2014-09-01

    The recently discovered high, plume-like 3He/4He ratios at Rungwe Volcanic Province (RVP) in southern Tanzania, similar to those at the Main Ethiopian Rift in Ethiopia, strongly suggest that magmatism associated with continental rifting along the entire East African Rift System (EARS) has a deep mantle contribution (Hilton et al., 2011). New trace element and Sr-Nd-Pb isotopic data for high 3He/4He lavas and tephras from RVP can be explained by binary mixing relationships involving Early Proterozoic (+/- Archaean) lithospheric mantle, present beneath the southern EARS, and a volatile-rich carbonatitic plume with a limited range of compositions and best represented by recent Nyiragongo lavas from the Virunga Volcanic Province also in the Western Rift. Other lavas from the Western Rift and from the southern Kenya Rift can also be explained through mixing between the same endmember components. In contrast, lavas from the northern Kenya and Main Ethiopian rifts can be explained through variable mixing between the same mantle plume material and the Middle to Late Proterozoic lithospheric mantle, present beneath the northern EARS. Thus, we propose that the bulk of EARS magmatism is sourced from mixing among three endmember sources: Early Proterozoic (+/- Archaean) lithospheric mantle, Middle to Late Proterozoic lithospheric mantle and a volatile-rich carbonatitic plume with a limited range of compositions. We propose further that the African Superplume, a large, seismically anomalous feature originating in the lower mantle beneath southern Africa, influences magmatism throughout eastern Africa with magmatism at RVP and Main Ethiopian Rift representing two different heads of a single mantle plume source. This is consistent with a single mantle plume origin of the coupled He-Ne isotopic signatures of mantle-derived xenoliths and/or lavas from all segments of the EARS (Halldorsson et al., 2014).

  2. Petrogenesis of the Yaochong granite and Mo deposit, Western Dabie orogen, eastern-central China: Constraints from zircon U-Pb and molybdenite Re-Os ages, whole-rock geochemistry and Sr-Nd-Pb-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Chen, Wei; Xu, Zhaowen; Qiu, Wenhong; Li, Chao; Yu, Yang; Wang, Hao; Su, Yang

    2015-05-01

    The Dabie orogen is among the most famous continent-continent collisional orogenic belts in the world, and is characterized by intensive post-collisional extension, magmatism and Mo mineralization. However, the genetic links between the mineralization and the geodynamic evolution of the orogen remain unresolved. In this paper, the Yaochong Mo deposit and its associated granitic stocks were investigated to elucidate this issue. Our new zircon U-Pb ages yielded an Early Cretaceous age (133.3 ± 1.3 Ma) for the Yaochong granite, and our molybdenite Re-Os dating gave a similar age (135 ± 1 Ma) for the Mo deposit. The Yaochong stock is characterized by high silica and alkali but low Mg, Fe and Ca. It is enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs: Rb, K, Th and U), but strongly depleted in heavy REEs, and high field strength elements (HFSEs: Nb, Ta, Ti and Y). The Yaochong granite has initial 87Sr/86Sr ratios of 0.7087-0.7096, and Pb isotopic ratios of (206Pb/204Pb)i = 16.599-16.704, (207Pb/204Pb)i = 15.170-15.618 and (208Pb/204Pb)i = 36.376-38.248. The granite has εNd(t) of -18.0 to -16.3 and εHf(t) values of -26.5 to -20.0. All these data indicate that the Yaochong granite is a high-K calc-alkaline fractionated I-type granite, and may have originated from partial melting of the thickened Yangtze continental crust. The Mo ores also show low radiogenic Pb isotopes similar to the Yaochong stock. Medium Re content in molybdenite (21.8-74.8 ppm) also suggests that the ore-forming materials were derived from the thickened lower crust with possibly minor mixing with the mantle. Similar to the Eastern Dabie orogen, the thickened crust beneath the Western Dabie orogen may also have experienced tectonic collapse, which may have exerted fundamental geodynamic controls on the two-stage Mo mineralization in the region.

  3. Zircon U-Pb geochronology, geochemistry, and Sr-Nd-Hf isotopes of granitoids in the Yulekenhalasu copper ore district, northern Junggar, China: Petrogenesis and tectonic implications

    NASA Astrophysics Data System (ADS)

    Yang, Fuquan; Chai, Fengmei; Zhang, Zhixin; Geng, Xinxia; Li, Qiang

    2014-03-01

    The Yulekenhalasu porphyry copper deposit is located in the Kalaxiange'er metallogenic belt in northern Junggar, China. We present the results from zircon U-Pb geochronology, and geochemical and Sr-Nd-Hf isotope analyses of the granitoids associated with the ore deposits with a view to constrain their petrogenesis and tectonic setting. The granitoids consist of quartz diorite, diorite porphyry, porphyritic monzonite, and quartz porphyry, emplaced at 382, 379, 375-374, and 348 Ma, respectively, which span Late Devonian to early Carboniferous ages. The ore-bearing intrusion is mainly diorite porphyry, with subordinate porphyritic monzonite. The Late Devonian intrusions are characterized by SiO2 contents of 54.5-64.79 wt.%, Na2O contents of 3.82-8.24 wt.%, enrichment in Na, light rare-earth elements (LREEs), and large ion lithophile elements. They also display relative depletion in Y, Ba, P, Nb, Ta, and Ti, and weak negative Eu anomalies (δEu = 0.6-0.87). The early Carboniferous quartz porphyry is characterized by high SiO2 content (72.26-73.35 wt.%), enrichment in LREEs, K, and Sr, and relative depletion in Y (10.82-12.52 ppm) and Yb (1.06-1.15 ppm). The Late Devonian and early Carboniferous granitoids are characterized by positive ɛNd(t) values (5.2-10.1, one sample at - 1.9), positive ɛHf(t) values (7.46-18.45), low (87Sr/86Sr)i values (0.70363-0.70476), and young crustal residence ages. These data indicate that the sources of the granitoids were mainly mantle-derived juvenile rocks. Geochemical and Nd-Sr-Hf isotopic data demonstrate that the Late Devonian granitoids formed in an oceanic island arc, and they were formed from different sources, among which the mineralized diorite porphyry might have originated from a mixed slab-derived and mantle wedge melt source. The early Carboniferous quartz porphyry was likely emplaced in a mature island arc environment, and was probably derived from juvenile crust.

  4. Paleocene and Early Eocene volcanic ash layers in the Schlieren Flysch, Switzerland: U-Pb dating and Hf-isotopes of zircons, pumice geochemistry and origin

    NASA Astrophysics Data System (ADS)

    Koch, Simone; Winkler, Wilfried; Von Quadt, Albrecht; Ulmer, Peter

    2015-11-01

    Thin mm to cm thick bentonite layers of Paleocene to Early Eocene age in the Tonsteinschichten of the Schlieren Flysch represent volcanic ash layers. Heavy mineral analysis of the layers indicates basic to acidic volcanic sources. U/Pb dating of single zircon crystals of a Paleocene layer (WW1948) by LA-ICP-MS points to an eruption at 59.87 ± 0.41 Ma, whereas ID-TIMS shows an eruption age of 60.96 ± 0.07 Ma. Taking into account the external precision of LA-ICP-MS analyses of 1-2% both ages are overlapping and indicate an apparent minimal durations of zircon crystallization of 350 ka. Hf-isotope analysis of the same zircon crystals reveals the hybrid character of the source magma. The geochemical composition of the pumice grains of all bentonite layers is strongly affected by alteration. Nevertheless, the original character of the volcanic source can be evaluated. The Paleocene ashes (Lower Tonsteinschichten, LT) show a more fractionated multi-element pattern than the ashes of Early Eocene (Upper Tonsteinschichten, UT). The LT ash series are of rhyodacite to dacite character whereas the UT ashes fall in the field of alkali basalts. Both ash series seem to originate from a within-plate volcanic setting according to their trace element concentrations. Geochemical and temporary counterparts can be found in ash layers from Anthering (Austria) and the Danish Basin. As proposed for those ashes, volcanism connected to the opening of the North Atlantic might be the source as well for the ashes in the Schlieren Flysch. By comparison of the composition of rocks from the British Paleogene Igneous Province BPIP and the Schlieren Flysch ashes many correlations can be drawn which supports the suggestion of a North Atlantic origin of the Alpine ashes.

  5. Geochemistry and zircon U-Pb-Hf isotopes of the granitoids of Baolidao and Halatu plutons in Sonidzuoqi area, Inner Mongolia: Implications for petrogenesis and geodynamic setting

    NASA Astrophysics Data System (ADS)

    Hu, Chuansheng; Li, Wenbo; Xu, Cheng; Zhong, Richen; Zhu, Feng

    2015-01-01

    The Baolidao and Halatu plutons are located in the Northern Orogenic Belt (NOB) in Sonidzuoqi area of Inner Mongolia, which has an important significance for the tectonic evolution of Xing-Meng Orogenic Belt (XMOB). The two plutons have been intensively studied but the conclusions are still controversial. Combined with the previous study, this paper gives new geological data about the two correlative plutons for gaining a better understanding of their petrogenesis and the geodynamic setting. The Baolidao granitoids contain two different series, calc-alkaline series mainly formed in the Ordovician and high K calc-alkaline series mainly formed in the Carboniferous. The Halatu granites are formed in the Triassic and belong to high-K calc-alkaline series. This study got the zircon U-Pb ages of 316-322 Ma for the Baolidao granitoids and 233 ± 2 Ma for the Halatu syenogranites, respectively. In the tectonic discrimination diagrams, they mainly fall into the area of post-orogenic granites (POG). Hf isotopic analyses for the Baolidao granitoids (Sample BLD-1 and 3) shows εHf (t) = 3.0-14.0, with two-stage Hf model age (TDM2) of 436-1138 Ma. The Halatu syenogranite (Sample HLT-1) also shows a depleted εHf (t) = 3.8-8.2, with TDM2 of 741-1024 Ma, suggesting the major involvement of juvenile crustal components. The various εHf values of the Carboniferous Baolidao and Triassic Halatu granitoids indicates a hybrid magma source of juvenile material with old crustal component, and the εHf (t) values decrease from the Carboniferous to Triassic, suggesting the increasing proportion of old continental material during this period. Combined with the regional geology, the Carboniferous Baolidao granitoids are possibly not arc rocks, but originated from the post-collisional setting. The Triassic Halatu granites were formed in the subsequently extensional environment.

  6. Geochemistry and detrital zircon U-Pb and Hf isotopes of the paragneiss suite from the Quanji massif, SE Tarim Craton: Implications for Paleoproterozoic tectonics in NW China

    NASA Astrophysics Data System (ADS)

    Zhang, Lu; Wang, Qinyan; Chen, Nengsong; Sun, Min; Santosh, M.; Ba, Jin

    2014-12-01

    The Delingha paragneiss suite in the Quanji massif, southeastern Tarim Craton, is composed of mica schist, paragneiss, leptynite and quartzite, similar to the 'khondalite suites' described from elsewhere in the world. The mica schist is rich in Al2O3 (up to ∼26 wt%) and contains graphite and diagnostic minerals including sillimanite and garnet, with metamorphism under amphibolite-facies to locally granulite-facies conditions as manifested by association with amphibolite and granulite. The detrital zircon U-Pb ages and geochemical data indicate that the protolith materials of the Delingha paragneiss suite were mainly sourced from 2.20 to 2.45 Ga granites, felsic volcanic rocks and TTG, and were deposited at 2.17-1.92 Ga. The detrital zircon Hf and whole-rock Nd isotopes document important crustal growth at ∼2.5-2.7 Ga. The detrital zircon age spectra, the whole rock Nd and zircon Hf model ages, the low-maturity of the protolith, and short-distance transportation suggest that the detritus were derived from the underlying Delingha Complex and the lower Dakendaban sub-Group. The timing of magmatic activities in the source region, the depositional age and metamorphic histories of the Delingha paragneiss suite are all comparable to those recorded in the khondalite belt along northern margin of the Ordos Block in the North China Craton. Our study shows that the 2.2-2.45 Ga magmatic rocks were generated in arc or active continental margin settings, suggesting a prolonged subduction and accretion history prior to final amalgamation (∼2.5-1.8 Ga) to form the unified North China Craton and the assembly of the Tarim Craton in NW China.

  7. Provenance and tectonic setting of Proterozoic metasedimentary sequences of the São Roque Domain, Ribeira Fold Belt, Brazil: a combination of whole-rock geochemistry, Sm-Nd isotopic systematics and detrital zircon U-Pb geochronology

    NASA Astrophysics Data System (ADS)

    Henrique Pinto, Renato; Janasi, Valdecir de A.; Barnes, Sarah-Jane; Borges Carvalho, Bruna; Tassinari, Colombo C. G.; Basei, Miguel A. S.

    2014-05-01

    The Proterozoic São Roque Group (Ribeira Fold Belt, southeast Brazil) is a metasedimentary sequence deposited in a marine environment consisting of proximal metasandstones and meta-felspathic wackes with some volcanic layers (Boturuna Formation) and more distal metawackes and metamudstones (Piragibu Formation). A combination of zircon provenance studies in metasandstones (textural and trace-element analysis and U-Pb geochronology) and whole-rock major and trace-element geochemistry and Sm-Nd isotopic systematics in metamudstones was used to understand the provenance and tectonic significance of this sequence, and their implications to the evolution of the Precambrian crust in the region. Whole-rock geochemistry indicates that the sources are largely granitic (as indicated for instance by the LREE-rich moderately fractionated REE patterns and subtle negative Eu anomalies) with some mafic contribution (responsible for higher contents of Fe2O3, MgO, V, and Cr) and were subject to moderate weathering (CIA - 60 to 82). The trace element signatures in detrital zircons indicate that most of them are derived from plagioclase-rich felsic rocks, as indicated by strong positive Ce anomalies, high (Lu/Sm)N ratios, low U/Yb, and a concave-down shape of the intermediate REE in chondrite-normalized plots. A significant proportion of the zircon crystals show rounded cores with growth zoning truncated and overgrown by a thin rim that has dark color in cathodoluminescence images. These overgrowths are chemically distinct, being enriched in trace elements, especially the LREE, and were dated at 584±47 Ma, reflecting the regional Neoproterozoic metamorphism. Sm-Nd isotope data for Piragibu Formation metamudstones show four main groups of Nd TDM ages at ca. 1.9 Ga, 2.1 Ga, 2.4 Ga and 3.0 Ga. The younger ages define an upper limit for the deposition of the unit, and reflect greater contributions from sources younger than the >2.1 Ga basement. The oldest Nd TDM age (3.0 Ga) is similar

  8. A list of references on lead isotope geochemistry through 1966

    USGS Publications Warehouse

    Doe, Bruce R.

    1968-01-01

    This bibliography was constructed to be as complete as possible for terminal papetrs containing new data relative to the geochmical applications of Common lead U-Th-Pb isotopic dating PbPb210, Pb212, Pb214 No effort was made for completeness of: Annual report, Yearbooks, etc. Review papers although many are included. Abstract and these are omitted.

  9. Zircon U-Pb age, Hf isotope and geochemistry of Carboniferous intrusions from the Langshan area, Inner Mongolia: Petrogenesis and tectonic implications

    NASA Astrophysics Data System (ADS)

    Liu, Min; Zhang, Da; Xiong, Guangqiang; Zhao, Hongtao; Di, Yongjun; Wang, Zhong; Zhou, Zhiguang

    2016-04-01

    Late Paleozoic was a critical period for the tectonic evolution of the northern margin of the Alxa-North China craton, but the evolutionary history is not well constrained. The Carboniferous intrusions in the Langshan area in the western part of the northern margin of the Alxa-North China craton are mainly composed of tonalite, quartz diorite, olivine gabbro and pyroxene peridotite. Zircon LA-ICP-MS U-Pb dating indicates that the Langshan Carboniferous intrusions were emplaced at ca. 338-324 Ma. The quartz diorites are characterized by high amounts of compatible trace elements (Cr, Ni and V) and high Mg# values, which may suggest a significant mantle source. The positive Pb and negative Nb-Ta-Ti anomalies, the variable εHf(t) (-6.9 to 2.0) values and the old Hf model ages (1218-1783 Ma) imply some involvement of ancient continental materials in its petrogenesis. The tonalite has relatively high Sr/Y ratios, low Mg#, Yb and Y contents, features of adakite-like rocks, negative εHf(t) values (-9.8 to -0.1) and older Hf model ages (1344-1953 Ma), which suggest significant involvement of ancient crust materials and mantle-derived basaltic component in its petrogenesis. The high Mg# values, high Cr and Ni contents, and low Zr and Hf contents of the mafic-ultramafic rocks show evidence of a mantle source, and the relatively low zircon εHf(t) values (-5.9 to 3.2) might point to an enriched mantle. The trace element characteristics indicate the influence of subducted sediments and slab-derived fluids. In the tectonic discrimination diagrams, all the rocks plot in subduction-related environment, such as volcanic arc and continental arc. Considering the regional geology, we suggest that the Carboniferous intrusions in the Langshan area were likely emplaced during the late stage of the southward subduction of the Paleo-Asian Ocean plate, which formed a continental arc along the northern margin of the Alxa-North China craton.

  10. Geochemistry, zircon U-Pb ages and Hf isotopes of the Paleozoic volcanic rocks in the northwestern Chinese Altai: Petrogenesis and tectonic implications

    NASA Astrophysics Data System (ADS)

    Wang, Yujing; Yuan, Chao; Long, Xiaoping; Sun, Min; Xiao, Wenjiao; Zhao, Guochun; Cai, Keda; Jiang, Yingde

    2011-10-01

    Paleozoic intermediate-acidic volcanic rocks exposed in the northwestern Chinese Altai mainly consist of two different lithologic suites: rhyolite suite (RS) and dacite-rhyolite suite (DRS), which were both assigned to the late Ordovician Dongxileke Formation. Zircon U-Pb dating results demonstrate that the RS suite was formed in the late Ordovician (443 ± 2 and 445 ± 2 Ma), while the DRS suite yielded much younger ages (411 ± 4 Ma) that are consistent with the early Devonian Kangbutiebao Formation of the Chinese Altai. Zircons from the two suites all have high ɛHf( t) values (mostly +2 to +9), indicating a source dominated by juvenile crustal materials. Rhyolites from the two suites are strongly peraluminous and have high SiO 2 (70.53-76.94 wt.%) and ɛNd( t) values between -1.7 and -0.6, similar to those of the Paleozoic granitoids (>300 Ma) but higher than the Early Paleozoic Habahe sediments, suggesting an origin by partial melting of a juvenile crustal source dominated by meta-igneous rocks. Dacite samples from the DRS suite possess high SiO 2 contents (64.71-67.77 wt.%) and Mg # values (˜52). They have ɛNd( t) values similar to those of the Habahe sediments, which, in combination with their relative high Th/Yb (>3.5) and low Ba/La (<40) ratios, suggests the dacite was originated from sediment-derived melts modified by depleted mantle peridotite. The Mg-rich dacite formed in a critical period (around 410 Ma), during which voluminous granitic intrusions and rhyolite were produced. Extensive partial melting of subducting sediments in the early Devonian is in agreement with a high geothermal gradient in the Chinese Altai. A hot subduction regime is proposed to interpret the early Devonian tectonic evolution of the Chinese Altai.

  11. The provenance of Archean clastic metasediments in the Narryer Gneiss Complex, western Australia: Trace element geochemistry, Nd isotopes, and U-Pb ages for detrital zircons

    SciTech Connect

    Maas, R. Curtin Univ., Perth ); McCulloch, M.T. )

    1991-07-01

    Clastic metasedimentary rocks of mid-Archean age from the Mt. Narryer and Jack Hills metasedimentary belts have REE patterns resembling those of mid- to late-Archean pelitic-quartzitic cratonic sequences elsewhere, and post-Archean continental rocks in general. Detrital zircons in the metasediments range in age from ca. 3,000 to 3,700 Ma. This indicates a provenance from mature cratonic sources controlled by K-rich granitic rocks. Additional minor sediment sources were identified as older, mainly chemical sedimentary sequences, ultramafic rocks, and felsic rocks characterized by low HREE contents, perhaps of tonalitic affinity. Differences between sedimentary REE patterns and those in the surrounding 3.73-3.0 Ga orthogneiss terrain, and between detrital zircon ages and the age distribution in the gneisses, suggest that the present association of the metasedimentary belts with the orthogneiss terrain is of tectonic origin. The occurrence of detrital zircons with U-Pb ages > 4 Ga in certain quartzites and conglomerates of the Jack Hills and Mt. Narryer metasedimentary sequences indicates a further, most likely granitic, source. {epsilon}{sub Nd}(T{sub Dep}) values in Jack Hills metasediments vary widely (+5 to {minus}12) but have a smaller range in the Mt. Narryer belt ({minus}5 to {minus}9). The lowest {epsilon}{sub Nd} values of both sequences are interpreted to reflect the presence of detritus derived from 4.1-4.2 Ga old LREE-enriched continental crust in proportions considerably larger ({ge} 10%) than estimated previously from the abundance of pre-4 Ga detrital zircons ({approx}3%). This would imply the former existence of significant volumes of pre-4 Ga continental crust in the provenance of the Mt. Narryer and Jack Hills metasediments.

  12. Petrology and Sr-Nd-Pb-He isotope geochemistry of postspreading lavas on fossil spreading axes off Baja California Sur, Mexico

    NASA Astrophysics Data System (ADS)

    Tian, Liyan; Castillo, Paterno R.; Lonsdale, Peter F.; Hahm, Doshik; Hilton, David R.

    2011-02-01

    Postspreading volcanism has built large seamounts and volcanic ridges along the short axes of a highly segmented part of the East Pacific Rise crest that ceased spreading at the end of the middle Miocene, offshore Baja California Sur, Mexico. Lava samples from Rosa Seamount, the largest volcano, are predominantly alkalic basalts, mugearites, and benmoreites. This lavas series was generated through fractional crystallization and is compositionally similar to the moderately alkalic lava series in many oceanic islands. Samples from volcanic ridges at three adjacent failed spreading axes include mildly alkalic, transitional, and tholeiitic basalts and differentiated trachyandesites and andesite. The subtle but distinct petrologic and isotopic differences among the four sites may be due to differences in the degree of partial melting of a common, heterogeneous source. Postspreading lavas from these four abandoned axes off Baja California Sur together with those from other fossil spreading axes and from seamount volcanoes that grew on the East Pacific Rise flanks define a compositional continuum ranging from normal mid-ocean ridge basalt (NMORB)-like to ocean island basalt (OIB)-like. We propose that the compositional spectrum of these intraplate volcanic lavas is due to different degrees of partial melting of the compositionally heterogeneous suboceanic mantle in the eastern Pacific. A large degree of partial melting of this heterogeneous mantle during vigorous mantle upwelling at an active spreading center produces NMORB melts, whereas a lesser degree of partial melting during weak mantle upwelling following cessation of spreading produces OIB-like melts. The latter melts have a low (<8 RA) 3He/4He signature indicating their formation is different from that of OIBs from major "hot spot" volcanoes in the Pacific with high 3He/4He ratios, such as Hawaii and Galapagos.

  13. Late Paleoproterozoic charnockite suite within post-collisional setting from the North China Craton: Petrology, geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Yang, Qiong-Yan; Santosh, M.; Rajesh, H. M.; Tsunogae, T.

    2014-11-01

    Charnockites (pyroxene-bearing granitoids) of magmatic origin in diverse tectonic settings and ranging in age from Mesoarchean to Cretaceous constitute important components of the continental crust. Here we report charnockites displaying both magnesian and ferroan compositions associated with gabbros from an AMCG (anorthosite-mangerite-charnockite-granite) suite in the North China Craton. The orthopyroxene in the magnesian charnockite is characterized by moderate XMg of 0.63-0.65 (Wo1-2En62-63Fs35-36), and low Al2O3 content of 0.59-0.71 wt.%. The magnesian charnockites show medium- to high-K contents, and high Mg# (~ 47-69) similar to that of gabbros, whereas the Mg# of the ferroan charnockites is low (~ 6-28). The ferroan charnockites are alkali-calcic to alkalic, and weakly peralkaline to metaluminous, whereas the magnesian charnockites are calcic to calc-alkalic, and metaluminous. Although magnesian charnockites are in general considered to have formed in subduction setting, the medium- to high-K contents, high Mg# values with a wide range, and the highly negative εHf values of the zircons in these rocks (- 8. 4 to - 13.6), suggest inheritance of the arc signature from the melting of ancient arc-related crustal material. The ferroan charnockites show tholeiitic affinity and define a common differentiation trend with the gabbroic anorthosites and likely represent fractionated end-members with or without crustal interaction in a post-collisional rift setting. We present U-Pb age data from zircon grains on seven samples including two ferroan charnockites, three magnesian charnockites, one gabbroic enclave in magnesian charnockite and one gabbroic anorthosite which show emplacement ages of 1748.8 ± 6.4 Ma, 1747.1 ± 9.5 Ma, 1756.4 ± 7.3 Ma, 1756.7 ± 9.2 Ma, 1731 ± 17 Ma, 1731.6 ± 8.2 Ma and 1746.5 ± 7.3 Ma respectively. The negative εHf values (- 1.2 to - 13.6) of zircon grains from these rocks and the older crustal model ages ranging from Mesoarchean to

  14. Geochemistry, zircon U-Pb ages and Sr-Nd-Hf isotopes of an Ordovician appinitic pluton in the East Kunlun orogen: New evidence for Proto-Tethyan subduction

    NASA Astrophysics Data System (ADS)

    Xiong, Fuhao; Ma, Changqian; Wu, Liang; Jiang, Hong'an; Liu, Bin

    2015-11-01

    Appinite is commonly derived from a mantle source in subduction zones and thus holds a key to constrain the tectonic evolution of ancient orogens. This study presents chronological, mineralogical and geochemical data for one appinitic pluton from the south Tethyan suture zone in the East Kunlun orogen, Northern Tibetan Plateau. The pluton is predominantly composed of hornblende-rich mafic appinites, with minor amounts of granodiorite. Zircon U-Pb age of the granodiorite (466 Ma) is identical to the mafic appinites (447-450 Ma). The mafic appinites are commonly hornblende diorites, which comprise large amounts of magnesio-hornblende [Mg/(Fe + Mg) = 0.61-0.68] and andesine (An43-54). The hornblende diorites have low contents of SiO2 (48.62-54.95 wt.%), high contents of total FeO (7.90-12.84 wt.%) and MgO (4.32-11.89 wt.%) and moderate values of Mg# [Mg# = molar 100 ∗ Mg/(Mg + Fe); 49-69]. Their geochemistry displays: slight enrichment of light rare earth elements ((La/Yb)N = 1.89-6.84) and flat heavy rare earth elements ((Ga/Yb)N = 1.49-2.22); enrichment in large ion lithophile elements and depletion in high field strength elements; less-enriched isotopic compositions with initial 87Sr/86Sr ratios of 0.70536-0.70617, εNd(t) of 0.79-3.02 and zircon εHf(t) of 8.73-12.82. The associated granodiorites comprise plagioclase (45-50 vol.%, An = 26-39), quartz (15-20 vol.%), K-feldspar (5-10 vol.%), ferrohornblende [2-5 vol.%, (Mg/(Fe + Mg) = 0.45-0.49] and epidote (1-5 vol.%). The epidotes have pistacite components ranging from 23 to 28. The granodiorites exhibit calc-alkaline character, and have rare earth and trace element patterns similar to the hornblende diorites. The geochemical compositions and simulations suggest that the parental magma of the mafic appinites was generated by partial melting of one depleted mantle source which was metasomatised by subducted sediment-derived felsic melts (ca. 20-25%). Fractional crystallization of clinopyroxene, hornblende

  15. Pb isotopes and toxic metals in floodplain and stream sediments from the Volturno river basin, Italy

    USGS Publications Warehouse

    DeVivo, B.; Somma, R.; Ayuso, R.A.; Calderoni, G.; Lima, A.; Pagliuca, S.; Sava, A.

    2001-01-01

    We present results of a stratigraphic and environmental geochemistry study of the eastern sector of the Volturno river basin (Italy) using stream sediment and floodplain drill core samples. The cores, dated back to 7,000 years B.P., have been used to evaluate background (baseline) values. Pb isotopic compositions and toxic metal abundances have been determined to discriminate natural versus anthropogenic sources. The Pb isotopic compositions of the stream sediments overlap the values of Pb in petrol. The results from both stream sediment and drill core samples plot along a mixing line between the field that characterizes the volcanic rocks outcropping in the area (the natural component) and the Pb isotopic composition of petrol used in western Europe. Results suggest a prevalent contribution of the natural component for the Pb in the drill core samples and a prevailing anthropogenic component for the Pb isotopic compositions in the active stream sediments samples.

  16. Magma mixing origin for the post-collisional adakitic monzogranite of the Triassic Yangba pluton, Northwestern margin of the South China block: geochemistry, Sr-Nd isotopic, zircon U-Pb dating and Hf isotopic evidences

    NASA Astrophysics Data System (ADS)

    Qin, Jiang-Feng; Lai, Shao-Cong; Diwu, Chun-Rong; Ju, Yin-Juan; Li, Yong-Fei

    2010-03-01

    Petrogenesis of high Mg# adakitic rocks in intracontinental settings is still a matter of debate. This paper reports major and trace element, whole-rock Sr-Nd isotope, zircon U-Pb and Hf isotope data for a suite of adakitic monzogranite and its mafic microgranular enclaves (MMEs) at Yangba in the northwestern margin of the South China Block. These geochemical data suggest that magma mixing between felsic adakitic magma derived from thickened lower continental crust and mafic magma derived from subcontinental lithospheric mantle (SCLM) may account for the origin of high Mg# adakitic rocks in the intracontinental setting. The host monzogranite and MMEs from the Yangba pluton have zircon U-Pb ages of 207 ± 2 and 208 ± 2 Ma, respectively. The MMEs show igneous textures and contain abundant acicular apatite that suggests quenching process. Their trace element and evolved Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.707069-0.707138, and ɛNd( t) = -6.5] indicate an origin from SCLM. Some zircon grains from the MMEs have positive ɛHf( t) values of 2.3-8.2 with single-stage Hf model ages of 531-764 Ma. Thus, the MMEs would be derived from partial melts of the Neoproterozoic SCLM that formed during rift magmatism in response to breakup of supercontinent Rodinia, and experience subsequent fractional crystallization and magma mixing process. The host monzogranite exhibits typical geochemical characteristics of adakite, i.e., high La/Yb and Sr/Y ratios, low contents of Y (9.5-14.5 ppm) and Yb, no significant Eu anomalies (Eu/Eu* = 0.81-0.90), suggesting that garnet was stable in their source during partial melting. Its evolved Sr-Nd isotopic compositions [(87Sr/86Sr)i = 0.7041-0.7061, and ɛNd( t) = -3.1 to -4.3] and high contents of K2O (3.22-3.84%) and Th (13.7-19.0 ppm) clearly indicate an origin from the continental crust. In addition, its high Mg# (51-55), Cr and Ni contents may result from mixing with the SCLM-derived mafic magma. Most of the zircon grains from the

  17. Zircon U-Pb age, Lu-Hf isotope, mineral chemistry and geochemistry of Sundamalai peralkaline pluton from the Salem Block, southern India: Implications for Cryogenian adakite-like magmatism in an aborted-rift

    NASA Astrophysics Data System (ADS)

    Renjith, M. L.; Santosh, M.; Li, Tang; Satyanarayanan, M.; Korakoppa, M. M.; Tsunogae, T.; Subba Rao, D. V.; Kesav Krishna, A.; Nirmal Charan, S.

    2016-01-01

    The Sundamalai peralkaline pluton is one among the Cryogenian alkaline plutons occurring in the Dharmapuri Rift Zone (DRZ) of the Salem Block in the Southern Granulite Terrane (SGT) of India. Here we present zircon U-Pb age and Lu-Hf isotopic composition, mineral chemistry and geochemistry of the pluton to explore the petrogenesis and geodynamic implications. Systematic modal variation of orthoclase, Na-plagioclase, Ca-amphibole (ferro-edenite and hastingsite) and quartz developed quartz-monzonite and granite litho units in the Sundamalai pluton. Thermometry based on amphibole-plagioclase pair suggests that the pluton was emplaced and solidified at around 4.6 kbar pressure with crystallization of the major phases between 748 and 661 °C. Estimated saturation temperature of zircon (712-698 °C) is also well within this range. However, apatite saturation occurred at higher temperatures between 835 and 870 °C, in contrast with monazite saturation (718-613 °C) that continued up to the late stage of crystallization. Estimated oxygen fugacity values (log fO2: -14 to -17) indicate high oxidation state for the magma that stabilized titanite and magnetite. The magmatic zircons from Sundamalai pluton yielded a weighted mean 206Pb/238U age of 832.6 ± 3.2 Ma. Geochemically, the Sundamalai rocks are high-K to shoshonitic, persodic (Na2O/K2O ratio > 1), silica-saturated (SiO2:65-72 wt.%), and peralkaline in composition (aluminum saturation index, ASI < 1; Alkalinity index, AI < 0). The initial magma was mildly metaluminous which evolved to strongly peralkaline as result of fractional crystallization (plagioclase effect) controlled differentiation between quartz-monzonite and granite. Both rock types have high content of Na2O (5.1-6.3 wt.%), Ba (350-2589 ppm) and Sr (264-1036 ppm); low content of Y (8.7-17 ppm) and Yb (0.96-1.69 ppm); elevated ratios of La/Yb (11-46) and Sr/Y (46-69) and are depleted in Ti, with a positive Sr anomaly suggesting an adakite-like composition and

  18. High precision Pb, Sr, and Nd isotope geochemistry of alkalic early Kilauea magmas from the submarine Hilina bench region, and the nature of the Hilina/Kea mantle component

    NASA Astrophysics Data System (ADS)

    Kimura, J.; Sisson, T. W.; Nakano, N.; Coombs, M. L.; Lipman, P. W.

    2004-12-01

    Submarine lavas recovered from the Hilina bench region, offshore Kilauea, Hawaii Island provide information on ancient Kilauea volcano and the geochemical components of the Hawaiian hotspot. Alkalic lavas, including nephelinite, basanite, hawaiite, and alkali basalt, dominate the earliest stage of Kilauea magmatism. Transitional basalt pillow lavas are an intermediate phase, preceding development of the voluminous tholeiitic subaerial shield and submarine Puna Ridge. Most alkalic through transitional lavas are quite uniform in Sr-Nd-Pb isotopes, supporting the interpretation that variable extent partial melting of a relatively homogeneous source was responsible for much of the geochemical diversity of early Kilauea magmas (Sisson et al., 2002). These samples are among the highest 206Pb/204Pb known from the Hawaii islands and may represent melts from a distinct geochemical and isotopic endmember involved in the generation of most Hawaiian tholeiites. This endmember is similar to the postulated literature Kea component, but we propose it should be renamed Hilina, to avoid confusion with the geographically defined Kea-trend volcanoes. Isotopic compositions of some shield-stage Kilauea tholeiites overlap the Hilina endmember but most deviate far into the interior of the isotopic field defined by magmas from other Hawaiian volcanoes, reflecting the introduction of melt contributions from both _gKoolau_h (high 87Sr/86Sr, low 206Pb/204Pb) and depleted (low 87Sr/86Sr, intermediate 206Pb/204Pb) source materials. This shift in isotopic character from nearly uniform, endmember, and alkalic, to diverse and tholeiitic corresponds with the major increase in Kilauea_fs magmatic productivity. Two popular geodynamic models can account for these relations: (1) The upwelling mantle source could be concentrically zoned in both chemical/isotopic composition, and in speed/extent of upwelling, with Hilina (and Loihi) components situated in the weakly ascending margins and the Koolau

  19. Zircon U-Pb age and Sr-Nd-Hf-O isotope geochemistry of the Paleocene-Eocene igneous rocks in western Gangdese: Evidence for the timing of Neo-Tethyan slab breakoff

    NASA Astrophysics Data System (ADS)

    Wang, Rui; Richards, Jeremy P.; Hou, Zeng-qian; An, Fang; Creaser, Robert A.

    2015-05-01

    Northward Neo-Tethyan oceanic lithosphere subduction beneath southern Tibet in the Mesozoic-Early Cenozoic produced continental arc magmas in the ~ 1600 km-long Gangdese belt. The most voluminous magmatism occurred in the Paleocene-Eocene, and is characterized by extensive I-type calc-alkaline to high-K calc-alkaline Linzizong volcanic rocks, and coeval plutons. These rocks have been extensively studied in the eastern Gangdese belt (east of ∼ 89°E), but few data exist from the western Gangdese belt. New data for eleven samples of these rocks, combined with existing data from the literature, show that they are similar to the eastern Gangdese belt rocks, with relative depletions in Nb, Ta, P, and Ti, and enrichments in Rb, Ba, Th, U, K, Pb, Zr, and Hf on a primitive mantle-normalized trace element diagrams, typical of continental arc-related igneous rocks. However, compared to the east, western Gangdese igneous rocks range to higher K2O contents (up to 6.1 wt.%), higher (87Sr/86Sr)i ratios (up to 0.7151), and lower εNdi values (down to - 8.1), suggesting that an evolved crustal source was involved in arc magmatism. The Gangdese arc magmatism lasted to ~ 80 Ma, and has a gap or quiescent period afterwards. Starting at ~ 69 Ma, the arc magmatism initiated and shifted southward from ~ 30.5°N to ~ 29.5°N in southern Tibet with an abrupt change of India-Asia convergence rate. The magmas through the whole Gangdese belt at ~ 69-53 Ma are characterized by intermediate εNdi values (- 0.6 to + 4.0), positive εHfi values (+ 3.8 to + 7.1), intermediate δ18O values (+ 5.0‰ to + 6.5‰), and low Th/Y and La/Yb ratios (< 20). These magmas were likely derived from the mantle with crustal contamination by MASH process in response to Neo-Tethyan slab rollback as proposed by previous studies. The Sr-Nd-Hf-O isotopic compositions of Linzizong volcanic rocks and coeval intrusions are relatively homogeneous during ~ 69-53 Ma, but show a wide range at ~ 53-50 Ma. Zircon

  20. Characterizing Pb mobilization from upland soils to streams using (206)Pb/(207)Pb isotopic ratios.

    PubMed

    Dawson, Julian J C; Tetzlaff, Doerthe; Carey, Anne-Marie; Raab, Andrea; Soulsby, Chris; Killham, Kenneth; Meharg, Andrew A

    2010-01-01

    Anthropogenically deposited lead (Pb) binds efficiently to soil organic matter, which can be mobilized through hydrologically mediated mechanisms, with implications for ecological and potable quality of receiving waters. Lead isotopic ((206)Pb/(207)Pb) ratios change down peat profiles as a consequence of long-term temporal variation in depositional sources, each with distinctive isotopic signatures. This study characterizes differential Pb transport mechanisms from deposition to streams at two small catchments with contrasting soil types in upland Wales, U.K., by determining Pb concentrations and (206)Pb/(207)Pb ratios from soil core profiles, interstitial pore waters, and stream water. Hydrological characteristics of soils are instrumental in determining the location in soil profiles of exported Pb and hence concentration and (206)Pb/(207)Pb ratios in surface waters. The highest Pb concentrations from near-surface soils are mobilized, concomitant with high dissolved organic carbon (DOC) exports, from hydrologically responsive peat soils with preferential shallow subsurface flows, leading to increased Pb concentrations in stream water and isotopic signatures more closely resembling recently deposited Pb. In more minerogenic soils, percolation of water allows Pb, bound to DOC, to be retained in mineral horizons and combined with other groundwater sources, resulting in Pb being transported from throughout the profile with a more geogenic isotopic signature. This study shows that (206)Pb/(207)Pb ratios can enhance our understanding of the provenances and transport mechanisms of Pb and potentially organic matter within upland soils. PMID:19954181

  1. Source, evolution and emplacement of Permian Tarim Basalts: Evidence from U-Pb dating, Sr-Nd-Pb-Hf isotope systematics and whole rock geochemistry of basalts from the Keping area, Xinjiang Uygur Autonomous region, northwest China

    NASA Astrophysics Data System (ADS)

    Zhang, Dayu; Zhou, Taofa; Yuan, Feng; Jowitt, Simon M.; Fan, Yu; Liu, Shuai

    2012-04-01

    Permian basalts distribute at least 250,000 km2, and underlie the southwest Tarim Basin in Xinjiang Uygur Autonomous region, northwest China. This vast accumulation of basalt is the main part of the Tarim Large Igneous Province (LIP). The basaltic units in the Lower Permian Kupukuziman and Kaipaizileike Formations in the Keping area, Tarim Basin; were the best exposure of the Permian basalt sequence in the basin. LA-ICP-MS U-Pb dating of zircon from the basal basaltic unit in the section gives an age of 291.9 ± 2.2 Ma (MSWD = 0.30, n = 17); this age, combined with previously published geochronological data, indicates that the basalts in the Tarim Basin were emplaced between 292 Ma and 272 Ma, with about 90% of the basalts being emplaced between 292 and 287 Ma. Basalts from the Keping area have high FeOT (10.8-18.6 wt.%), low Mg#s (0.26-0.60), and exhibit primitive mantle normalized patterns with positive Pb, P and Ti but negative Zr, Y and Ta anomalies. The basalts from both formations have similar 206Pb/204Pb (18.192-18.934), 207Pb/204Pb (15.555-15.598) and 208Pb/204Pb (38.643-38.793) ratios. The basalts also have high ɛSr(t) (45.7-62.1), low ɛNd(t) (-3.6 to -2.2) and low zircon ɛHf(t) (-4.84 to -0.65) values. These characteristics are typical of alkali basalts and suggest that the basalts within the Tarim Basin were derived from an OIB-type mantle source and interacted with enriched mantle (EMI-type) before emplacement. Rare earth element systematics indicate that the parental melts for the basalts were high-degree partial melts derived from garnet lherzolite mantle at the base of the lithosphere. Prior to emplacement, the Tarim Permian Basalts (TPB) underwent fractional crystallization and assimilated crustal material; the basalts were finally emplaced during crustal extension in an intra-plate setting. The wide distribution, deep source and high degree partial melting of the TPB was consistent with a mantle plume origin. The TPB and other coeval igneous

  2. K-Ar ages and Pb, Sr isotopic characteristics of Cenozoic volcanic rocks in Shandong Province, China

    USGS Publications Warehouse

    Daogong, C.; Zicheng, P.; Lanphere, M.A.; Zartman, R.E.

    1985-01-01

    28 samples of Cenozoic volcanic rocks collected from Shandong Province have been dated by K-Ar method. They are mainly Neogene with an age range of 4-19 m. y. The basalts from Linqu and Yishui in west Shandong Province are Miocene and those from Penglai and Qixia in east Shandong Province are Miocene and Pliocene in age. The basalts from Wudi in north Shandong Province are Middle-Early Pleistocene in age. In each area the duration of volcanic eruption was estimated at about 2-3 m. y. Pb and Sr isotopic compositions and U, Th, Pb, Rb, Sr, and major elements in most of the samples were determined. The isotopic compositions are:206Pb/204Pb-16.92-18.48,207Pb/204Pb-15.30-15.59,208Pb/204Pb-37.83-38.54, and (87Sr/86Sr)i-0.70327-0.70632. There are some positive or negative linear correlations between206Pb/204Pb and207Pb/204Pb, Pb isotopes and Pb content, Pb isotopes and Sr isotopes, and Sr isotopes and other elements. The basaltic rocks from east and west Shandong Province have somewhat differences in isotopic composition and element content. The basalts probably are products of multi-stage evolution of the mantle. They have preserved the primary features of the source, although they were influenced, to some extent, by the contamination of crustal materials. ?? 1985 Institute of Geochemistry, Chinese Academy of Sciences.

  3. H, O, Sr, Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions, New Mexico, and relations between evolution of a continental magmatic center and modifications of the lithosphere

    USGS Publications Warehouse

    Johnson, C.M.; Lipman, P.W.; Czamanske, G.K.

    1990-01-01

    Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5-19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary ??18O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in 18O. Initial 87Sr/86Sr ratios (0.705 to 0.708), ??18O values (-2 to-7), and 206Pb/204Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (???26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial 87Sr/86Sr and 206Pb/204Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial 87Sr/86Sr and 206Pb/204Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (???25 Ma) and Rio Hondo (???21 Ma) plutons have relatively homogeneous initial 87Sr/86Sr and 206Pb/204Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. ??18O values for

  4. Pb isotopic heterogeneity in basaltic phenocrysts

    SciTech Connect

    Bryce, Julia G.; DePaolo, Donald J.

    2002-06-01

    The Pb isotopic compositions of phenocrystic phases in young basaltic lavas have been investigated using the Getty-DePaolo method (Getty S. J. and DePaolo D. J. [1995] Quaternary geochronology by the U-Th-Pb method. Geochim. Cosmochim. Acta 59, 3267 3272), which allows for the resolution of small isotopic differences. Phenocryst, matrix, and whole rock analyses were made on samples from the 17 Myr-old Imnaha basalts of the Columbia River Group, a zero-age MORB from the Mid-Atlantic Ridge, and a ca. 260 kyr-old tholeiite from Mount Etna. Plagioclase feldspar phenocrysts have low-(U, Th)/Pb, and in each sample the plagioclase has significantly lower 206Pb/207Pb and 208Pb/207Pb values than whole rock, matrix, and magnetite-rich separates. The Pb isotopic contrast between plagioclase and matrix/whole rock is found in three samples with varying grain sizes (0.5 2 cm for the Imnaha basalt and MORB and <1 mm for the Etna sample) from different tectonic settings, suggesting that these results are not unique. The isotopic contrasts are only slightly smaller in magnitude than the variations exhibited by whole rock samples from the region. The Imnaha basalts also have Sr isotopic heterogeneity evident only in plagioclase phenocrysts, but the MORB and Etna lavas do not. The isotopic heterogeneities reflect magma mixing, and indicate that isotopically diverse magmas were mixed together just prior to eruption. The results reinforce indications from melt inclusion studies that magma source region isotopic heterogeneities have large amplitudes at short length scales, and that the isotopic variations imparted to the magmas are not entirely homogenized during segregation and transport processes.

  5. Contrasted crustal sources as defined by whole-rock and Sr-Nd-Pb isotope geochemistry of neoproterozoic early post-collisional granitic magmatism within the Southern Brazilian Shear Belt, Camboriú, Brazil

    NASA Astrophysics Data System (ADS)

    Florisbal, Luana Moreira; de Assis Janasi, Valdecir; de Fátima Bitencourt, Maria; Stoll Nardi, Lauro Valentim; Heaman, Larry M.

    2012-11-01

    The early phase of post-collisional granitic magmatism in the Camboriú region, south Brazil, is represented by the porphyritic biotite ± hornblende Rio Pequeno Granite (RPG; 630-620 Ma) and the younger (˜610 Ma), equigranular, biotite ± muscovite Serra dos Macacos Granite (SMG). The two granite types share some geochemical characteristics, but the more felsic SMG constitutes a distinctive group not related to RPG by simple fractionation processes, as indicated by its lower FeOt, TiO2, K2O/Na2O and higher Zr Al2O3, Na2O, Ba and Sr when compared to RPG of similar SiO2 range. Sr-Nd-Pb isotopes require different sources. The SMG derives from old crustal sources, possibly related to the Paleoproterozoic protoliths of the Camboriú Complex, as indicated by strongly negative ɛNdt (-23 to -24) and unradiogenic Pb (e.g., 206Pb/204Pb = 16.0-16.3; 207Pb/204Pb = 15.3-15.4) and confirmed by previous LA-MC-ICPMS data showing dominant zircon inheritance of Archean to Paleoproterozoic age. In contrast, the RPG shows less negative ɛNdt (-12 to -15) and a distinctive zircon inheritance pattern with no traces of post-1.6 Ga sources. This is indicative of younger sources whose significance in the regional context is still unclear; some contribution of mantle-derived magmas is indicated by coeval mafic dykes and may account for some of the geochemical and isotopic characteristics of the least differentiated varieties of the RPG. The transcurrent tectonics seems to have played an essential role in the generation of mantle-derived magmas despite their emplacement within a low-strain zone. It may have facilitated their interaction with crustal melts which seem to be to a large extent the products of reworking of Paleoproterozoic orthogneisses from the Camboriú Complex.

  6. Pb Isotopes Track Asian Pollution in California

    NASA Astrophysics Data System (ADS)

    Ewing, S. A.; Christensen, J. N.; Brown, S. T.; Vancuren, R. A.; Cliff, S. S.; Depaolo, D. J.

    2008-12-01

    The transport of Asian pollution to North America has broad implications for global climate models and regional air quality regulation. In the western US, rising atmospheric Pb levels have been evident since the mid-1990s despite the phase-out of leaded gasoline. We use Pb isotopes to fingerprint the trans-Pacific component of atmospheric pollution in California. We measured Pb isotopes in airborne particles collected at two sites west (Mt. Tamalpais) and east (Chabot Observatory, Oakland Hills) of the San Francisco Bay Area, from winter 2007 through late spring 2008. We also analyzed archived springtime samples from inland sites throughout central California. Wintertime values of 206Pb/207Pb vs. 208Pb/207Pb at Chabot Observatory form a linear array that is consistent with published data for San Francisco Bay waters, whereas published values for Chinese cities and loess fall along a separate and distinct array for that region, consistent with our analysis of samples collected at Hefei, China in 2002. Between March and May 2008, the Tamalpais and Chabot samples diverge from the California regional array toward the Chinese array. About half of the central California samples also show a strong Asian influence. We quantify the divergence of values from the regional California array as Δ208Pb = (208Pb/207Pb)expected - (208Pb/207Pb) )observed, where (208Pb/207Pb)expected is derived from a linear fit to the wintertime samples at Chabot Observatory. These Δ208Pb values increase between winter and spring at both Mt. Tamapais and Chabot Observatory, and are higher at Mt. Tamalpais, despite lower Pb concentrations at that site. They indicate that up to 80% of the Pb in the Tamalpais samples, and up to 40% of the Pb in the Chabot Observatory samples, reflect trans-Pacific transport. The lower proportion in the Chabot samples -- where there is often more Pb -- indicates dilution by local urban sources. Our data provide conclusive evidence of Asian air pollution reaching

  7. Boron-isotope geochemistry. Doctoral thesis

    SciTech Connect

    Spivack, A.J.

    1986-01-01

    An investigation of the major aspects of the boron-isotope geochemical cycle was carried out. Particular emphasis was directed at developing a reproducible, high-precision method for the determination of boron isotope ratios in geologic materials and determining the processes that influence the boron-isotope composition of seawater. A method for the determination of the isotopic composition of boron by thermal ionization mass spectrometry of Cs/sub 2/B/sub 4/O/sub 7/ is described. Samples analyzed for boron content and isotopic composition included: seawater, unaltered mid-ocean ridge basalts (MORB), altered MORB (dredge and core samples), serpentinized periodotites, marine sediments, marine sedimentary pore waters, hydrothermally altered sediments, oceanic hydrothermal solutions, rainwater, river water and suspended sediments, island arc volcanics and a soil profile.

  8. Reliability of stable Pb isotopes to identify Pb sources and verifying biological fractionation of Pb isotopes in goats and chickens.

    PubMed

    Nakata, Hokuto; Nakayama, Shouta M M; Yabe, John; Liazambi, Allan; Mizukawa, Hazuki; Darwish, Wageh Sobhy; Ikenaka, Yoshinori; Ishizuka, Mayumi

    2016-01-01

    Stable Pb isotope ratios (Pb-IRs) have been recognized as an efficient tool for identifying sources. This study carried out at Kabwe mining area, Zambia, to elucidate the presence or absence of Pb isotope fractionation in goat and chicken, to evaluate the reliability of identifying Pb pollution sources via analysis of Pb-IRs, and to assess whether a threshold for blood Pb levels (Pb-B) for biological fractionation was present. The variation of Pb-IRs in goat decreased with an increase in Pb-B and were fixed at certain values close to those of the dominant source of Pb exposure at Pb-B > 5 μg/dL. However, chickens did not show a clear relationship for Pb-IRs against Pb-B, or a fractionation threshold. Given these, the biological fractionation of Pb isotopes should not occur in chickens but in goats, and the threshold for triggering biological fractionation is at around 5 μg/dL of Pb-B in goats. PMID:26549754

  9. B, Sr and Pb isotope geochemistry of high-pressure Alpine metaperidotites monitors fluid-mediated element recycling during serpentinite dehydration in subduction mélange (Cima di Gagnone, Swiss Central Alps)

    NASA Astrophysics Data System (ADS)

    Cannaò, E.; Agostini, S.; Scambelluri, M.; Tonarini, S.; Godard, M.

    2015-08-01

    Tectonic mixing of slab- and mantle-derived materials at the interface between converging plates highly enhances fluid-mediated mass transfer from the slab to the overlying mantle. Subduction mélanges can provide information about the interaction among different slices accreted at plate interface domains, with implications on the tectonic and geochemical evolution of the plate-interface itself. At Cima di Gagnone, pelitic schists and gneiss enclose chlorite harzburgite and garnet peridotite lenses, like in subduction mélanges located in-between downgoing slabs and overlying mantle. These peridotites host MORB-type eclogite and metarodingite, and derive from dehydration of serpentinized mantle protoliths. Their enrichment in fluid-mobile B, As, Sb, U, Th is the result of an early-stage oceanic serpentinization, followed by interaction with host metasediments during subduction burial. Here we define the element exchange process in the Gagnone mélange by means of the B, Sr and Pb isotope analysis of its main lithologies (ultramafic, mafic rocks and paragneiss). The 87Sr/86Sr and 206Pb/204Pb ratios of ultramafic rocks (0.7090-0.7124 and 18.292-18.837, respectively) show enrichments in radiogenic Sr and Pb after exchange with the host paraschist (up to 0.7287 87Sr/86Sr; 18.751 206Pb/204Pb). The δ11B values of peridotites (down to -10‰) point to a combined effect of (1) 11B release to deserpentinization fluids (serpentinized protoliths likely had positive δ11B and lower radiogenic Sr, Pb), and of (2) exchange with fluids from the surrounding metasediments. The whole Gagnone rock-suite is finally overprinted by retrograde fluids that essentially bring to an increase in radiogenic Pb (about 19.0 206Pb/204Pb) and to values of 0.710 87Sr/86Sr and of -10‰ δ11B. The recognition of different stages of interaction between mantle rocks and sedimentary/crustal reservoirs allows us to define the geochemical effects related to the early coupling of such rocks along the

  10. Infrared spectroscopy and hydrogen isotope geochemistry of hydrous silicate glasses

    SciTech Connect

    Epstein, S.; Stolper, E.

    1992-01-01

    The focus of this project is the combined appication of infrared spectroscopy and stable isotope geochemistry to the study of hydrogen-bearing species dissolved in silicate melts and glasses. We are conducting laboratory experiments aimed at determining the fractionation of D and H between melt species (OH and H{sub 2}O) and hydrous vapor and the diffusivities of these species in glasses and melts. Knowledge of these parameters is critical to understanding the behavior of hydrogen isotopes during igneous processes and hydrothermal processes. These results also could be valuable in application of glass technology to development of nuclear waste disposal strategies.

  11. Infrared Spectroscopy and Stable Isotope Geochemistry of Hydrous Silicate Glasses

    SciTech Connect

    Stolper, Edward

    2007-03-05

    The focus of this DOE-funded project has been the study of volatile components in magmas and the atmosphere. Over the twenty-one year period of this project, we have used experimental petrology and stable isotope geochemistry to study the behavior and properties of volatile components dissolved in silicate minerals and melts and glasses. More recently, we have also studied the concentration and isotopic composition of CO2 in the atmosphere, especially in relation to air quality issues in the Los Angeles basin.

  12. Magnesium isotope geochemistry in arc volcanism

    PubMed Central

    Teng, Fang-Zhen; Hu, Yan

    2016-01-01

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ26Mg of the Martinique Island lavas varies from −0.25 to −0.10, in contrast to the narrow range that characterizes the mantle (−0.25 ± 0.04, 2 SD). These high δ26Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid−mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration. PMID:27303032

  13. Magnesium isotope geochemistry in arc volcanism.

    PubMed

    Teng, Fang-Zhen; Hu, Yan; Chauvel, Catherine

    2016-06-28

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ(26)Mg of the Martinique Island lavas varies from -0.25 to -0.10, in contrast to the narrow range that characterizes the mantle (-0.25 ± 0.04, 2 SD). These high δ(26)Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid-mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration. PMID:27303032

  14. Magnesium isotope geochemistry in arc volcanism

    NASA Astrophysics Data System (ADS)

    Teng, Fang-Zhen; Hu, Yan; Chauvel, Catherine

    2016-06-01

    Incorporation of subducted slab in arc volcanism plays an important role in producing the geochemical and isotopic variations in arc lavas. The mechanism and process by which the slab materials are incorporated, however, are still uncertain. Here, we report, to our knowledge, the first set of Mg isotopic data for a suite of arc lava samples from Martinique Island in the Lesser Antilles arc, which displays one of the most extreme geochemical and isotopic ranges, although the origin of this variability is still highly debated. We find the δ26Mg of the Martinique Island lavas varies from ‑0.25 to ‑0.10, in contrast to the narrow range that characterizes the mantle (‑0.25 ± 0.04, 2 SD). These high δ26Mg values suggest the incorporation of isotopically heavy Mg from the subducted slab. The large contrast in MgO content between peridotite, basalt, and sediment makes direct mixing between sediment and peridotite, or assimilation by arc crust sediment, unlikely to be the main mechanism to modify Mg isotopes. Instead, the heavy Mg isotopic signature of the Martinique arc lavas requires that the overall composition of the mantle wedge is buffered and modified by the preferential addition of heavy Mg isotopes from fluids released from the altered subducted slab during fluid‑mantle interaction. This, in turn, suggests transfer of a large amount of fluid-mobile elements from the subducting slab to the mantle wedge and makes Mg isotopes an excellent tracer of deep fluid migration.

  15. Beryllium isotope geochemistry in tropical river basins

    SciTech Connect

    Brown, E.T.; Edmond, J.M. ); Raisbeck, G.M.; Bourles, D.L.; Yiou, F. ); Measures, C.I. )

    1992-04-01

    The distributions of beryllium-9 and beryllium-10 in rivers within the Orinoco and Amazon basins have been examined to extend the understanding of their geochemical cycles and to develop their use both in geochronometry, and in studying erosional processes. Analyses of {sup 9}Be in dissolved and suspended material from rivers with a wide range of chemical compositions indicate that its geochemistry is primarily controlled by two major factors: (1) its abundance in the rocks of the watershed and (2) the extent of its adsorption onto particle surfaces. The relative importance of these parameters in individual rivers is determined by the extent of interaction with flood-plain sediments and the riverine pH. This understanding of {sup 9}Be geochemistry forms a basis for examination of the geochemical cycling of {sup 10}Be. In rivers which are dominated by interaction with sediments, the riverine concentration of dissolved {sup 10}Be is far lower than that in the incoming rainwater, indicating that a substantial proportion of it is retained within the soils of the basin or is adsorbed onto riverine particles. However, in acidic rivers in which the stable dissolved Be concentration is determined by the Be level in the rocks of the drainage basin, dissolved {sup 10}Be has essentially the same concentration as in precipitation. These observations imply that the soil column in such regions must be saturated with respect to {sup 10}Be, and that the ratio of the inventory to the flux does not represent an age, as may be the case in temperate latitudes, but rather a residence time.

  16. Isotope geochemistry of caliche developed on basalt

    NASA Astrophysics Data System (ADS)

    Knauth, L. Paul; Brilli, Mauro; Klonowski, Stan

    2003-01-01

    Enormous variations in oxygen and carbon isotopes occur in caliche developed on < 3 Ma basalts in 3 volcanic fields in Arizona, significantly extending the range of δ 18O and δ 13C observed in terrestrial caliche. Within each volcanic field, δ 18O is broadly co-variant with δ 13C and increases as δ 13C increases. The most 18O and 13C enriched samples are for subaerial calcite developed on pinnacles, knobs, and flow lobes that protrude above tephra and soil. The most 18O and 13C depleted samples are for pedogenic carbonate developed in soil atmospheres. The pedogenic caliche has δ 18O fixed by normal precipitation in local meteoric waters at ambient temperatures and has low δ 13C characteristic of microbial soil CO 2. Subaerial caliche has formed from 18O-rich evapoconcentrated meteoric waters that dried out on surfaces after local rains. The associated 13C enrichment is due either to removal of 12C by photosynthesizers in the evaporating drops or to kinetic isotope effects associated with evaporation. Caliche on basalt lava flows thus initially forms with the isotopic signature of evaporation and is subsequently over-layered during burial by calcite carrying the isotopic signature of the soil environment. The large change in carbon isotope composition in subsequent soil calcite defines an isotopic biosignature that should have developed in martian examples if Mars had a "warm, wet" early period and photosynthesizing microbes were present in the early soils. The approach can be similarly applied to terrestrial Precambrian paleocaliche in the search for the earliest record of life on land. Large variations reported for δ 18O of carbonate in Martian meteorite ALH84001 do not necessarily require high temperatures, playa lakes, or flood runoff if the carbonate is an example of altered martian caliche.

  17. Oxygen and hydrogen isotope geochemistry of zeolites

    NASA Technical Reports Server (NTRS)

    Karlsson, Haraldur R.; Clayton, Robert N.

    1990-01-01

    Oxygen and hydrogen isotope ratios for natural samples of the zeolites analcime, chabazite, clinoptilolite, laumontite, mordenite, and natrolite have been obtained. The zeolite samples were classified into sedimentary, hydrothermal, and igneous groups. The ratios for each species of zeolite are reported. The results are used to discuss the origin of channel water, the role of zeolites in water-rock interaction, and the possibility that a calibrated zeolite could be used as a low-temperature geothermometer.

  18. Small scale inhomogeneity in the mantle source of the Cape Verde hotspot is probably related to plume complexity: implications from Sr, Nd and high precision Pb isotopes and geochemistry

    NASA Astrophysics Data System (ADS)

    Holm, P. M.; Sørensen, R. V.

    2009-04-01

    The volcanic rocks of one of the major islands of the Cape Verde hotspot have been investigated in order to test mantle plume models. From the centre of the Cape Verde Rise an array of islands trend west, the northern HIMU-type Cape Verde Islands. Of these, São Nicolau (SN) is the easternmost and Santo Antão the westernmost. Sixty samples of primitive (MgO = 9-14 wt%) basanitic composition from SN that represent the four volcanic stages of the 9 - 0.1 Ma evolution of the island have been analysed for Sr, Nd and high precision Pb isotopic composition. Pb ranges to a less radiogenic composition than on SA [1] and has lower 8/4 than the rocks of the southern EM1-type Cape Verde islands. Most SN lavas have a young HIMU character with negative 7/4. The most radiogenic Pb at SN is less thorogenic than Pb at SA. Temporal variation is also evident: An intermediate age group of samples have particularly low La/Nb = 0.4 - 0.5 and the least LREE-enrichment for SN. The youngest group of rocks has the lowest Zr/Nb = 2.5 - 3.0 and the most unradiogenic Sr and radiogenic Nd in the archipelago. At least four of the mantle source components for the SN magmas are different from any found in the SA magmas. High precision Pb data allow identification of parallel trends for northern SN and the southern island Santiago, which therefore must have unrelated source components. For the northern Cape Verde islands source compositions vary from E to W as well as with time. This cannot be explained by stationary enriched lithosphere components. The derivation of melts from a complex plume source is modelled. [1] Holm P.M., Wilson J.R., Christensen B.P., Hansen S.L., Hein K.M., Mortensen A.K., Pedersen R., Plesner S., and Runge M.K. (2006) JPetrol 47, 145-189.

  19. Crust-mantle interaction in the central North China Craton during the Mesozoic: Evidence from zircon U-Pb chronology, Hf isotope and geochemistry of syenitic-monzonitic intrusions from Shanxi province

    NASA Astrophysics Data System (ADS)

    Ying, Ji-Feng; Zhang, Hong-Fu; Tang, Yan-Jie

    2011-07-01

    In-situ zircon U-Pb ages, Hf isotopic compositions and whole rock geochemical and Sr-Nd isotopic compositions are presented for three Mesozoic syenitic-monzonitic intrusions from Shanxi province, central North China Craton. Zircons from these intrusions all show core-rim structures in that the oscillatory rims recorded their intrusive ages, whereas the cores are interpreted as xenocrysts. The U-Pb age data reveal that the northernmost Dishuiyan monzonite was emplaced at 241 Ma, while the Huyanshan and Erfengshan syenitic-monzonitic complexes were emplaced at 130 Ma and 128-134 Ma, respectively. The Dishuiyan monzonite is petrologically and geochemically uniform, it shows LREE enrichment and HFSE depletion and exhibits enriched Sr and Nd isotopic compositions with (87Sr/86Sr)i = 0.7065 and εNd(t) = - 8.3--7.9. The zircon rims in the Dishuiyan monzonite show highly varied Hf isotopic compositions with εHf(t) = - 27.8--6.4. The varied Hf isotopic compositions and enriched Sr-Nd isotopic compositions, together with the ubiquitous xenocrystic zircon cores, suggest the Dishuiyan monzonite was produced by the mixing of melts from enriched lithospheric mantle and lower crust. The monzonite and syenite from the Huyanshan complexes exhibit different geochemical features. The εNd(t) values of syenite, which are higher than those of monzonite resemble the enriched lithospheric mantle, and together with the absence of zircon in the syenite, we propose that it was originated by partial melting of enriched lithospheric mantle. Monzonites from Huyanshan and Erfengshan share similar petrological and geochemical characteristics, being enriched in LREE and depleted in HFSE, and they show low εNd(t) values between - 18.2 and - 13.9. Similar to zircon rims in the Dishuiyan monzonite, those in the Huyanshan and Erfengshan monzonites also exhibit highly varied Hf isotopic compositions. The consistent ages between the xenocrystic zircons in monzonites and the lower crustal basement

  20. Zircon U-Pb ages, Hf isotopes and geochemistry of the schists, gneisses and granites in Delbar Metamorphic-Igneous Complex, SE of Shahrood (Iran): Implications for Neoproterozoic geodynamic evolutions of Central Iran

    NASA Astrophysics Data System (ADS)

    Balaghi Einalou, Maryam; Sadeghian, Mahmoud; Zhai, Minggou; Ghasemi, Habibollah; Mohajjel, Mohammad

    2014-10-01

    The Delbar Metamorphic-Igneous Complex (DMIC) consists of the medium to high-grade metamorphic rocks and granites - leucogranites is located in the Biarjmand region, in Central Iran. U-Pb dating of the gneisses yielded the ages of 546 ± 3.7-547 ± 6.8 Ma similar to the crystallization ages of leucogranites (541 ± 4.7-547 ± 11 Ma) are consistent to the Late Ediacaran-Early Cambrian ages of Cadomian magmatic arc (∼545 Ma). The 206Pb/238U ages of the detrital zircons from the mica-schists sample are from 551 ± 5.1-549 ± 5.1 Ma. The youngest ages of the meta-pelitic protolith have 10 Ma age intervals compared to the granites emplacement age, which indicates rapid Late Precambrian crustal recycling involving erosion, burial, metamorphism to partial melting of the continental crust in less than ca. 10 Ma. These rapid crustal evolutions were related to the final collision and amalgamation of Gondwana, the Rheic Ocean clouser and coeval paleotethys opening at the end of the Avalonian-Cadomian orogeny. The studied granites are similar to the volcanic arc granitoids and originated from the crustal source in an active continental margin based on the geochemical characteristics and Hf isotopes data. Exhumation of the DMIC Complex, is marked by deposition of Lower Jurassic conglomerates contains pebbles of basement rocks. These rocks were interrupted by mafic swarms dikes that have generated in a back arc extensional setting related to the Neotethys subduction under the Central Iran at the 152 ± 35 Ma (Middle-Late Jurassic) based on the U-Pb apatite dating.

  1. Metal stable isotope signatures as tracers in environmental geochemistry.

    PubMed

    Wiederhold, Jan G

    2015-03-01

    The biogeochemical cycling of metals in natural systems is often accompanied by stable isotope fractionation which can now be measured due to recent analytical advances. In consequence, a new research field has emerged over the last two decades, complementing the traditional stable isotope systems (H, C, O, N, S) with many more elements across the periodic table (Li, B, Mg, Si, Cl, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn, Ge, Se, Br, Sr, Mo, Ag, Cd, Sn, Sb, Te, Ba, W, Pt, Hg, Tl, U) which are being explored and potentially applicable as novel geochemical tracers. This review presents the application of metal stable isotopes as source and process tracers in environmental studies, in particular by using mixing and Rayleigh model approaches. The most important concepts of mass-dependent and mass-independent metal stable isotope fractionation are introduced, and the extent of natural isotopic variations for different elements is compared. A particular focus lies on a discussion of processes (redox transformations, complexation, sorption, precipitation, dissolution, evaporation, diffusion, biological cycling) which are able to induce metal stable isotope fractionation in environmental systems. Additionally, the usefulness and limitations of metal stable isotope signatures as tracers in environmental geochemistry are discussed and future perspectives presented. PMID:25640608

  2. LA-ICP-MS zircon U-Pb dating, trace element and Hf isotope geochemistry of the Heyu granite batholith, eastern Qinling, central China: Implications for Mesozoic tectono-magmatic evolution

    NASA Astrophysics Data System (ADS)

    Li, Nuo; Chen, Yan-Jing; Pirajno, Franco; Gong, Hu-Jun; Mao, Shi-Dong; Ni, Zhi-Yong

    2012-06-01

    Mesozoic granitoids are widespread in the southern margin of the North China Craton, and of particular geological interests because of their indication for lithospheric evolution and close association with porphyry Mo mineralization. In this contribution, in situ LA-ICP-MS U-Pb, Hf isotope and trace element analyses of zircon crystals have been combined to constrain the emplacement time and petrogenesis of the Heyu granitic batholith which hosts the Yuchiling porphyry Mo system, Henan Province, China. As inferred from field investigations, the concentrically zoned Heyu batholith mainly consists of four texturally distinguishable phases, and displays a pattern of monotonically decreasing U-Pb age from 143.0 ± 1.6 Ma for Phase 1, through 138.4 ± 1.5 Ma for Phase 2, through to ca. 135 Ma for Phase 3, and to 133.6 ± 1.3 Ma for the Mo-mineralized Yuchiling granite porphyry (Phase 4). The ɛHf(t) values (- 27.7 to - 3.4) and the two stage Hf model ages (1403 to 2924 Ma) of zircon grains, together with the ages of local strata, suggest that the magmas forming the Heyu batholith were dominantly sourced from the crust, with input of a mantle component. The higher Ce/Ce* ratios of the zircon crystals in the mineralized Yuchiling porphyry compared to those in the Mo-barren phases suggests that fluids exsolved from oxidic magmas might be more favorable for Mo enrichment. A regional synthesis suggests that intensive lithospheric thinning in the southern margin of the North China Craton should not be earlier than 130 Ma.

  3. 40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

    USGS Publications Warehouse

    Cosca, Michael A.; Thompson, Ren A.; Lee, John P.; Turner, Kenzie J.; Neymark, Leonid A.; Premo, Wayne R.

    2014-01-01

    Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been

  4. Early Cretaceous arc volcanic suite in Cebu Island, Central Philippines and its implications on paleo-Pacific plate subduction: Constraints from geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Deng, Jianghong; Yang, Xiaoyong; Zhang, Zhao-Feng; Santosh, M.

    2015-08-01

    The Philippine island arc system is a collage of amalgamated terranes of oceanic, continental and island arc affinities. Here we investigate a volcanic suite in Cebu Island of central Philippines, including basalt, diabase dike, basaltic pyroclastic rock and porphyritic andesite. LA-ICP-MS U-Pb geochronology of zircon grains from the porphyritic andesite and pyroclastic rock yielded ages of 126 ± 3 Ma and 119 ± 2 Ma, respectively, indicating an Early Cretaceous age. The age distribution of the detrital zircons from river sand in the area displays a peak at ca. 118 Ma, close to the age of the pyroclastic rock. The early Cretaceous volcanic rocks in the central Philippines were previously regarded as parts of ophiolite complexes by most investigators, whereas the Cebu volcanics are distinct from these, and display calc-alkaline affinity and island arc setting, characterized by high LREE/HREE ratios and low HFSE contents. These features are similar to the Early Cretaceous arc basalts in the Amami Plateau and east Halmahera in the northernmost and southernmost West Philippine Basin respectively. Zircon Hf isotopes of the pyroclastic rocks show depleted nature similar to those of the Amami Plateau basalts, implying the subducted Pacific-type MORB as probable source. Zircon Hf isotopes of the porphyritic andesite show slight enrichment relative to that of the pyroclastic rocks and MORB, indicating subducted sediments as a minor end-member in the source. The Hf isotopic compositions of the volcanic rocks are also reflected in the detrital zircons from the river sands. We propose that the volcanic rocks of Cebu Island were derived from partial melting of sub-arc mantle wedge which was metasomatized by dehydration of subducted oceanic crust together with minor pelagic sediments. Within the tectonic environment of Southeast Asia during Early Cretaceous, the volcanic rocks in Cebu Island can be correlated to the subduction of paleo-Pacific plate. The Early Cretaceous

  5. Zircon U-Pb age and Sr-Nd-Hf isotope geochemistry of Permian granodiorite and associated gabbro in the Songliao Block, NE China and implications for growth of juvenile crust

    NASA Astrophysics Data System (ADS)

    Liu, Shen; Hu, Ruizhong; Gao, Shan; Feng, Caixia; Feng, Guangying; Coulson, Ian M.; Li, Cai; Wang, Tao; Qi, Youqiang

    2010-02-01

    Post-orogenic granitic and associated mafic rocks from northeastern (NE) China consist of granodiorite and gabbro intrusions. We report here upon new U-Pb zircon ages, geochemical data and Sr-Nd-Hf isotopic data for these rocks. LA-ICP-MS U-Pb zircon analysis yields an age of 262.8 ± 1.0 Ma for the granitic rocks, and a uniform age of 262.1 ± 0.7 Ma for the gabbro. Most of the granitic and mafic rocks are characterised by low K 2O + Na 2O, and pertain to the subalkaline series in the total alkali-silica diagram. The granodiorite samples show low ( 87Sr/ 86Sr) i ranging from 0.700 to 0.705, positive ɛNd( t) values from +0.3 to +0.8, and large variation in ɛHf( t) values of between - 4.0 and +2.5, indicating that both newly underplated basalt (70-80%) and ancient lower crustal sources (20-30%) contributed to their origin. Furthermore, positive ɛHf( t) values with two-stage model ages ( TDM2) of 1123-1260 Ma, together with Nd model ages (960-1000 Ma), suggest an important episode of crustal growth during the Meso-Neoproterozoic beneath the Songliao Block. In contrast, the investigated gabbro is characterised by relatively high ( 87Sr/ 86Sr) i ratios (0.707-0.708), negative ɛNd( t) (- 5.9 to - 5.3) and ɛHf( t) values (- 5.0 to - 2.3), implying that this was derived from an enriched mantle source. The geochemical data indicate that the granitic magmas underwent separation of clinopyroxene, hornblende, K-feldspar, plagioclase, Ti-bearing phases (e.g., rutile, ilmenite, titanite), apatite and zircon during their evolution. Whereas the gabbro is characterised by low MgO (2.92-3.92 wt.%), Mg# (35-41) and compatible elements content, such as Cr (10-68 ppm), Co (16-31 ppm) and Ni (5.7-33 ppm), features of a more evolved mafic magma. There is no evidence that the granitic and mafic rocks were affected by crustal contamination during emplacement. Our interpretation is that the two coeval intrusive suites were both formed in a post-orogenic extensional setting, related to

  6. Timing and sources of granite magmatism in the Ribeira Belt, SE Brazil: Insights from zircon in situ U–Pb dating and Hf isotope geochemistry in granites from the São Roque Domain

    NASA Astrophysics Data System (ADS)

    Janasi, Valdecir de Assis; Andrade, Sandra; Vasconcellos, Antonio Carlos B. C.; Henrique-Pinto, Renato; Ulbrich, Horstpeter H. G. J.

    2016-07-01

    Eight new in situ U-Pb zircon age determinations by SHRIMP and LA-MC-ICPMS reveal that the main granitic magmatism in the São Roque Domain, which is largely dominated by metaluminous high-K calc-alkaline monzogranites with subordinate peraluminous leucogranites, occurred between 604 ± 3 and 590 ± 4 Ma. This small temporal range is ca. 20-30 Ma younger than previously admitted based on U-Pb TIMS dates from literature, some of which obtained in the same occurrences now dated. The observed discrepancy seems related to the presence of small Paleoproterozoic inherited cores in part of the zircon populations used for TIMS multigrain dating, which could also respond for the unusually high (up to 10 Ma) uncertainty associated with most of these dates. The younger age range now identified for the São Roque granite magmatism has important implications for the evolution of the Ribeira Fold Belt. Whilst previously admitted ages ca. 620-630 Ma substantiated correlations with the widespread and intensely foliated high-K calc-alkaline granitoid rocks of the neighbor Socorro-Guaxupé Nappe (potentially associated with an accretionary continental margin), the ∼600-590 Ma interval seems more consistent with a late deformation tectonic setting. Strongly negative εHf(t) characterize the magmatic zircons from the São Roque Domain granites. An eastward increase from -22 in the São Roque Granite to -11 in the Cantareira Granite and neighboring stocks suggests an across-domain shift in granite sources. Such eastward younging of sources, also indicated by Sm-Nd isotope data from granites and supracrustal sequences in neighboring domains, is suggestive that some of the first-order limits and discontinuities in this belt are not defined by the strike-slip fault systems traditionally taken to separate distinct domains. Although the negative εHf(t) and εNd(t) indicate sources with long crustal residence for all studied granite plutons, the observed range is more radiogenic than the

  7. Zircon U-Pb dating, trace element and Sr-Nd-Hf isotope geochemistry of Paleozoic granites in the Miao'ershan-Yuechengling batholith, South China: Implication for petrogenesis and tectonic-magmatic evolution

    NASA Astrophysics Data System (ADS)

    Zhao, Kui-Dong; Jiang, Shao-Yong; Sun, Tao; Chen, Wei-Feng; Ling, Hong-Fei; Chen, Pei-Rong

    2013-09-01

    The Miao'ershan-Yuechengling batholith (MYB) is one of the largest granitic batholiths in South China. At least five individual phases have been identified for the Paleozoic granites in the MYB. SHRIMP and LA-ICP-MS zircon U-Pb dating results imply that these granites were emplaced at 435 ± 4 Ma, 427 ± 3 Ma, 417 ± 6 Ma, 404 ± 6 Ma and 382 ± 2 Ma, respectively. The ages gradually decreased from the southeast to the northwest, implying that the MYB was incrementally emplaced from the southeast to the northwest lasting from early Silurian to late Devonian. Most granites are metaluminous to weakly peraluminous, and contain low P2O5 contents (<0.15%). These granites show enrichment of Rb, Th, U and depletion of Ba, Sr, Eu, Ti. They show relatively high (87Sr/86Sr)i ratios (>0.715), low ɛNd(t) values (-8.9 to -6.7), and low zircon ɛHf(t) values (-9.5 to -4.0). These geochemical and isotopic characteristics indicate that these granites may have formed from partial melting of Paleoproterozoic basement rocks. Slight geochemical differences between different phases can be interpreted as resulting from partial melting of heterogeneous sources or different proportion mixing of meta-igneous and meta-sedimentary rocks. Zircon Hf isotope model ages vary from 1.77 to 1.93 Ga, with an average value of 1.84 ± 0.07 Ga. These data indicate that crust growth in this region took place mainly during the Paleoproterozoic (ca. 1.84 Ga), and the basement in the MYB should belong to the Cathaysia Block. The formation of the Paleozoic granites in the MYB was suggested to be related to the late orogenic magmatism of the Wuyi-Yunkai orogeny. Thus, the late orogenic magmatism in the northwestern part of the Wuyi-Yunkai orogeny must have lasted until ca. 381 Ma and took place also to the east of the Anhua-Luocheng Fault.

  8. Geochemistry, zircon U-Pb and Lu-Hf isotopes of an Early Cretaceous intrusive suite in northeastern Jiangxi Province, South China Block: Implications for petrogenesis, crust/mantle interactions and geodynamic processes

    NASA Astrophysics Data System (ADS)

    Deng, Zhengbin; Liu, Shuwen; Zhang, Lifei; Wang, Zongqi; Wang, Wei; Yang, Pengtao; Luo, Ping; Guo, Boran

    2014-07-01

    The Early Cretaceous Tieshan intrusive suite, in northeastern Jiangxi Province along the northern margin of the Eastern Cathaysia Block, is composed of diabase porphyrites, monzodiorites, syenite porphyries, quartz monzonites, monzogranites and granite porphyries. LA-ICPMS zircon U-Pb isotopic analyses reveal that this intrusive complex was emplaced between 142 Ma and 117 Ma. The ~ 135 Ma diabase porphyrites, monzodiorites, and syenite porphyries are characterized by low to moderate SiO2 and MgO contents, with high K2O and total alkaline contents. These rocks exhibit slightly to strongly fractionated REE patterns and upper crust-like multi-element patterns with depletions of Nb, Ta and Ti, and show strongly negative εHf (t) values of - 9.0 to - 11.8. All these patterns are identical to those of the Caiyuan syenites, Huangtuling gabbros in the east, and Lengshuikeng trachyandesites and quartz syenites in the west. These geochemical and zircon Lu-Hf isotopic features indicate that their magmatic precursors were generated by 0.2%-2% partial melting of a phlogopite-bearing enriched subcontinental lithospheric mantle source that was metasomatized by sediments. The ~ 117 Ma quartz monzonite has slightly higher εHf (t) values (- 5.6 to - 8.7) like those of the Honggong syenites, indicating an interaction between the asthenosphere and the lithosphere. The ~ 142-134 Ma granite porphyries and monzogranites are characterized by high SiO2 levels but low concentrations of refractory elements, and show enrichment of LREEs and LILEs, with variable negative anomalies of Nb, Ta, Ti, Sr, P and Ba in multi-element diagrams normalized by primitive mantle. The monzogranite exhibits strongly negative εHf (t) values of - 10.5 to - 13.3 and TDM2 (Hf) values of 1849-2023 Ma, and the granite porphyries display relatively wide εHf (t) values of - 7.2 to - 13.4 and TDM2 (Hf) values of 1645-2043 Ma, indicating that these monzogranites and granite porphyries are highly fractionated granites

  9. Geochemistry, U–Pb geochronology, Sm–Nd and O isotopes of ca. 50 Ma long Ediacaran High-K Syn-Collisional Magmatism in the Pernambuco Alagoas Domain, Borborema Province, NE Brazil

    NASA Astrophysics Data System (ADS)

    Francisco da Silva Filho, Adejardo; de Pinho Guimarães, Ignez; Santos, Lucilene; Armstrong, Richard; Van Schmus, William Randall

    2016-07-01

    The Pernambuco Alagoas (PEAL) domain shows the major occurrence of granitic batholiths of the Borborema Province, NE Brazil, with Archean to Neoproterozoic range of Nd TDM model ages, giving clues on the role of granites during the Brasiliano orogeny. SHRIMP U/Pb zircon geochronological data for seven granitic intrusions of the PEAL domain divide the studied granitoids into three groups: 1) early-to syn-collision granitoids with crystallization ages ca. 635 Ma (Serra do Catú pluton), 2) syn-collision granitoids with crystallization ages 610-618 Ma (Santana do Ipanema, Água Branca, Mata Grande and Correntes plutons) and 3) late-to post-collision granitoids with ages of ca. 590 Ma (Águas Belas, and Cachoeirinha plutons). The intrusions of group 1 and 2, except the Mata Grande and Correntes plutons, show Nd TDM model ages ranging from 1.2 to 1.5 Ga, while the granitoids from group 3, and Mata Grande Pluton and Correntes plutons have Nd TDM model ages ranging from 1.7 to 2.2 Ga. The studied granitoids with ages <600 Ma are high-K, calc-alkaline, shoshonitic and those with ages <600 Ma are transitional high-K calc-alkaline to alkaline. The volcanic arc signatures associated with the Paleoproterozoic Nd TDM model ages are interpreted as inherited from the source rocks. The oldest ages and lower Nd TDM model ages are recorded from granitoids intruded in the southwest part of the PEAL domain, suggesting that these intrusions are associated with slab-tearing during convergence between the PEAL and the Sergipano domains. Zircon oxygen isotopic data in some of the studied plutons, together with the available Nd isotopic data suggest that the Brasiliano orogeny strongly reworked older crust, of either Paleoproterozoic or Tonian ages. The studied granitoids are coeval with calc-alkaline granitoids of the Transversal Zone and Sergipano domains and rare high-K calc-alkaline granitoids from the Transversal Zone domain. Such large volumes of high-K granitoids with

  10. Eocene Granitic Magmatism in NW Anatolia (Turkey) revisited: New implications from comparative zircon SHRIMP U-Pb and 40Ar-39Ar geochronology and isotope geochemistry on magma genesis and emplacement

    NASA Astrophysics Data System (ADS)

    Altunkaynak, Şafak; Sunal, Gürsel; Aldanmaz, Ercan; Genç, Can Ş.; Dilek, Yıldırım; Furnes, Harald; Foland, Kenneth A.; Yang, Jingsui; Yıldız, Merve

    2012-12-01

    During the Eocene, the northern Neo-Tethys suture zone and immediately adjacent areas in NW Turkey were loci of emplacement of a number of granitoid plutons with age relations and geochemical signatures indicative of magma generation in association with plate convergence. Discrete granitoid plutons of Eocene age in this region are exposed mainly in two distinct belts within and north of the northern Neo-Tethys suture zone. We report new SHRIMP U-Pb zircon and 40Ar/39Ar geochronology along with Sr-Nd isotope data from the granitoids in order to constrain their melt source(s), cooling history, and tectono-magmatic evolution with respect to the Early Cenozoic collisional tectonics of the region. Ranging in composition from diorite to granite, the plutons are largely represented by medium- to high-K calc-alkaline, I-type granites accompanied by minor amounts of shoshonitic rocks with syenite compositions and mafic microgranular enclaves in some of the plutons. In terms of trace element systematics the granitoids and the associated enclaves from the entire Eocene suite display close similarities to magmas from subduction-related or active continental margin settings, characterized by significant enrichment in LILE/HFSE relative to MORB. The rocks display significantly heterogeneous distributions of radiogenic isotopes with 87Sr/86Sr and 143Nd/144Nd ranging from 0.705824 to 0.708363 and from 0.512384 to 0.512718 respectively, suggesting multi-component melt interaction in their genesis. The granitoids from the southern and northern belts yielded zircon SHRIMP U-Pb ages of 52.8 ± 1.8 to 45.41 ± 0.34 Ma and 47.02 ± 0.82 to 36.79 ± 0.67 Ma, respectively, indicating overlapping emplacement ages, with some relatively younger ages from the northern belt. 40Ar/39Ar dating of biotite and hornblende also yielded similarly overlapping cooling ages (51.8 ± 0.1 to 44.9 ± 0.2 Ma and 45.3 ± 0.1 to 36.0 ± 0.1 Ma, respectively). Our combined geochronological data from the co

  11. Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments

    NASA Astrophysics Data System (ADS)

    Ning-jing, Hu; Peng, Huang; Hui, Zhang; Ai-mei, Zhu; Ji-hua, Liu; Jun, Zhang; Lian-hua, He

    2015-10-01

    To investigate the source of Pb within Bohai Bay, Pb concentrations and Pb isotopic compositions (204Pb, 206Pb, 207Pb, and 208Pb) of surface sediments in this area were determined. The Pb concentration in this bay varied widely from 6.9 to 39.2 μg/g (average: 21.8±7.8 μg/g), and the Pb isotopic compositions ranged from 0.8338 to 0.8864 (average: 2.0997±0.0180) for 208Pb/206Pb and from 2.0797 to 2.1531 (average: 0.8477±0.0135) for 207Pb/206Pb, presenting in three distinct clusters. The Pb isotopic ratios of sediments from the northeastern (NE zone) and northwestern (NW zone) coastal areas were significantly influenced by anthropogenic sources such as coal combustion and automobile emission. In sediments from the central and southern Bohai Bay (C-S zone); however, Pb mainly originated from the Yellow River catchment, as a result of lithogenic sediment (from rock weathering) accumulation. The Pb isotopic ratios further indicate that, apart from riverine inputs, the neighboring large-scale ports and aerosols significantly contributed to the anthropogenic Pb contained in these sediments. Pb contamination in the Haihe and Luanhe river mouths as well as in the regions near ports is also suggested from anthropogenic enrichment factors. As cities and ports continue to develop around Bohai Bay, a long-term extensive sewage monitoring program is highly recommended.

  12. Calcium Isotope Geochemistry: Research Horizons and Nanoscale Fractionation Processes

    SciTech Connect

    Yang, W; Simon, J I; DePaolo, D J; Watkins, J M; Richter, F M; Fantle, M S; Ryerson, F J; Ewing, S A; Turchyn, A V; Owens, T L

    2008-10-28

    Interest in studies of calcium isotope variations in nature continues to increase. Investigations span human biology, plants and soils, oceanography and paleoclimate, early solar system processes, aqueous geochemistry, and silicate liquid structure. Variations in the 44Ca/40Ca ratio are generally small, about 5 {per_thousand}, but gradual small improvements in analytical capability now yield 0.05 to 0.1 {per_thousand} resolution. The field is still plagued by a lack of universal standards for isotope ratios and data representation, but these are secondary issues. Traditional isotopic systems have been based in equilibrium thermodynamics, which can explain the magnitude and sign of observed mass-dependent fractionation behavior. For Ca isotopes this is not the case. There is still no reliable way to estimate the equilibrium free energy associated with isotopic exchange between most phases of interest. Experiments are difficult to interpret because it is almost impossible to precipitate minerals from aqueous solution at equilibrium at low temperature. Some studies suggest that, for example, there is no equilibrium isotopic fractionation between calcite and dissolved aqueous Ca. There is good evidence that most Ca isotopic fractionation is caused by kinetic effects. The details of the controlling processes are still missing, and without this mechanistic understanding it is difficult to fully understand the implications of natural isotopic variations. Recent work on dissolved Ca, calcite, and sulfates in both laboratory and natural settings is shedding light on where the fractionation may arise. There is emerging evidence for mass dependent fractionation associated with aqueous diffusion, but probably the primary source of the effects is in the details of precipitation of minerals from solution. This makes the fractionation potentially dependent on a number of factors, including solution composition and mineral growth rate. The next challenge is to develop appropriate

  13. Isotopic and noble gas geochemistry in geothermal research

    SciTech Connect

    Kennedy, B.M.; DePaolo, D.J.

    1997-12-31

    The objective of this program is to provide, through isotopic analyses of fluids, fluid inclusions, and rocks and minerals coupled with improved methods for geochemical data analysis, needed information regarding sources of geothermal heat and fluids, the spatial distribution of fluid types, subsurface flow, water-rock reaction paths and rates, and the temporal evolution of geothermal systems. Isotopic studies of geothermal fluids have previously been limited to the light stable isotopes of H, C, and O. However, other isotopic systems such as the noble gases (He, Ne, Ar, Kr and Xe) and reactive elements (e.g. B, N, S, Sr and Pb) are complementary and may even be more important in some geothermal systems. The chemistry and isotopic composition of a fluid moving through the crust will change in space and time in response to varying chemical and physical parameters or by mixing with additional fluids. The chemically inert noble gases often see through these variations, making them excellent tracers for heat and fluid sources. Whereas, the isotopic compositions of reactive elements are useful tools in characterizing water-rock interaction and modeling the movement of fluids through a geothermal reservoir.

  14. Isotope geochemistry and fluid inclusion study of skarns from Vesuvius

    USGS Publications Warehouse

    Gilg, H.A.; Lima, A.; Somma, R.; Belkin, H.E.; de Vivo, B.; Ayuso, R.A.

    2001-01-01

    We present new mineral chemistry, fluid inclusion, stable carbon and oxygen, as well as Pb, Sr, and Nd isotope data of Ca-Mg-silicate-rich ejecta (skarns) and associated cognate and xenolithic nodules from the Mt. Somma-Vesuvius volcanic complex, Italy. The typically zoned skarn ejecta consist mainly of diopsidic and hedenbergitic, sometimes "fassaitic" clinopyroxene, Mg-rich and Ti-poor phlogopite, F-bearing vesuvianite, wollastonite, gehlenite, meionite, forsterite, clinohumite, anorthite and Mg-poor calcite with accessory apatite, spinell, magnetite, perovskite, baddeleyite, and various REE-, U-, Th-, Zr- and Ti-rich minerals. Four major types of fluid inclusions were observed in wollastonite, vesuvianite, gehlenite, clinopyroxene and calcite: a) primary silicate melt inclusions (THOM = 1000-1050??C), b) CO2 ?? H2S-rich fluid inclusions (THOM = 20-31.3??C into the vapor phase), c) multiphase aqueous brine inclusions (THOM = 720-820??C) with mainly sylvite and halite daughter minerals, and d) complex chloride-carbonate-sulfate-fluoride-silicate-bearing saline-melt inclusions (THOM = 870-890??C). The last inclusion type shows evidence for immiscibility between several fluids (silicate melt - aqueous chloride-rich liquid - carbonate/sulfate melt?) during heating and cooling below 870??C. There is no evidence for fluid circulation below 700??C and participation of externally derived meteoric fluids in skarn formation. Skarns have considerably variable 206Pb/204Pb (19.047-19.202), 207Pb/204Pb (15.655-15.670), and 208Pb/204Pb (38.915-39.069) and relatively low 143Nd/144Nd (0.51211-0.51244) ratios. The carbon and oxygen isotope compositions of skarn calcites (??13CV-PDB = -5.4 to -1.1???; ??18OV-SMOW = 11.7 to 16.4???) indicate formation from a 18O- and 13C-enriched fluid. The isotope composition of skarns and the presence of silicate melt inclusion-bearing wollastonite nodules suggests assimilation of carbonate wall rocks by the alkaline magma at moderate depths (< 5

  15. Low-Al and high-Al trondhjemites in the Huai'an Complex, North China Craton: Geochemistry, zircon U-Pb and Hf isotopes, and implications for Neoarchean crustal growth and remelting

    NASA Astrophysics Data System (ADS)

    Zhang, Hua-Feng; Zhai, Ming-Guo; Santosh, M.; Li, Sheng-Rong

    2012-04-01

    Voluminous tonalite-trondhjemite-granodiorite (TTG) magmas were emplaced in the Huai'an Complex of North China Craton (NCC) during the Neoarchean. Here we present the geochemical characteristics of these rocks and identify low-Al (LAl) and high-Al (HAl) types of trondhjemites within the TTG suite. The LAl group displays high silica (SiO2 = 77-80 wt.%), and low Al2O3 contents (11.06-11.89 wt.%), a strongly peraluminous (A/CNK = 1.16 and 1.19) composition and enrichment in HREE (LaN/YbN = 4 and 5, GdN/YbN = 0.35 and 0.9). Their low Rb (13 and 28 ppm), Th (0.3 and 7.0 ppm), relatively high Na2O/K2O values (3.6 and 4.1) and MgO (0.63 and 0.68 wt.%) with moderately high Mg# (36 and 53), suggest crystallization from a primitive source. The HAl group is characterized by relatively low SiO2 (67.22-71.57 wt.%) and high Al2O3 contents (16.35-16.41 wt.%) with trace element contents and distribution patterns closely comparable to those of Archean high-Al TTGs. Our geochemical data do not favor a direct genetic link between the LAl and HAl trondhjemite groups. The zircon U-Pb data reveal that the LAl and HAl groups represent coeval intrusions at ca. 2.55-2.5 Ga. In situ analysis of Hf isotopes in the zircons (ɛHf = +5.6 to +10, and TDM = 2462-2595 Ma), together with the geochemical features of the low-Al trondhjemites suggest that they were generated under relatively low pressure (<8 kbar), through low degree partial melting of a newly accreted amphibolitic crust. Taking into consideration the contemporaneous (2.55-2.50 Ga) high-Al TTGs widely exposed in the Huai'an Complex, we suggest that the low-Al trondhjemites were formed by intraplating of mantle-derived magmas, and the coeval high-Al TTGs were produced by partial melting of a thickened lower crust, triggered by underplating. Our study attests to a major episode of Neoarchean crustal growth in the NCC, and remelting induced by underplating and intraplating of mantle-derived magmas.

  16. Calculation of uncertainties of U-Pb isotope data

    USGS Publications Warehouse

    Ludwig, K. R.

    1980-01-01

    Equations are derived for the estimation of errors and error correlations for various types of U-Pb isotope data, taking into account ion-beam instabilities, run-to-run variability in mass-discrimination, uncertainties in Pb and U concentrations, and uncertainties in initial-Pb and blank-Pb amount and isotopic composition. Equations are also given for the calculation of concordia intercept errors. ?? 1980.

  17. SPATIAL Short Courses Build Expertise and Community in Isotope Geochemistry

    NASA Astrophysics Data System (ADS)

    Riggs, E. M.; Bowen, G. J.

    2015-12-01

    The SPATIAL short course at the University of Utah is designed for graduate students and professionals in the earth and environmental sciences from around the globe. An integral part of the broader, NSF-funded Inter-university Training for Continental-scale Ecology (ITCE) project, the course is an intensive two-week field, classroom and laboratory experience with internationally-known researchers as instructors. The course focuses on stable isotope geochemistry coupled with spatial analysis techniques. Participants do not typically know each other or this research community well upon entering. One of the stated goals of the overall project is to build a community of practice around these techniques. This design is common in many professional fields, but is not often applied at the graduate level nor formally assessed in the earth sciences. Paired pre- and post-tests were administered before the start and after the close of the short courses over 3 years. The survey is a set of instruments adapted from social-cognitive psychology measuring changes in identity and community with other items to measure content knowledge outcomes. We see a subtle, consistent convergence of identities between large-scale isotope geochemistry and participants' research areas. Results also show that the course generates an increase in understanding about stable isotopes' use and application. The data show the SPATIAL course is very effective at bringing students together socially with each other and with faculty to create an environment that fosters community and scientific cooperation. Semi-structured pre-and post- interviews were conducted to understand the program elements that generated gains in learning and community. Participants were selected based on initial responses on the pre-survey to capture the range of initial conditions for the group. Qualitative analysis shows that the major factors for participants were 1) ready access to researchers in an informal setting during the

  18. Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments

    NASA Astrophysics Data System (ADS)

    Hu, Ningjing; Huang, Peng

    2016-04-01

    Anthropogenic Pb input into Bohai Bay, China: Evidence from stable Pb isotopic compositions in sediments Hu Ning-jinga, Huang Pengb,, Liu Ji-huaa, a First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China b Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China To investigate the source of Pb within Bohai Bay, Pb concentrations and Pb isotopic compositions (204Pb, 206Pb, 207Pb, and 208Pb) of surface sediments in this area were determined. The Pb concentration in this bay varied widely from 6.9 to 39.2 μg/g (average: 21.8 ± 7.8 μg/g), and the Pb isotopic compositions ranged from 0.8338 to 0.8864 (average: 2.0997 ± 0.0180) for 208Pb/206Pb and from 2.0797 to 2.1531 (average: 0.8477 ± 0.0135) for 207Pb/206Pb, presenting in three distinct clusters. The Pb isotopic ratios of sediments from the northeastern (NE zone) and northwestern (NW zone) coastal areas were significantly influenced by anthropogenic sources such as coal combustion and automobile emission. In sediments from the central and southern Bohai Bay (C-S zone); however, Pb mainly originated from the Yellow River catchment, as a result of lithogenic sediment (from rock weathering) accumulation. The Pb isotopic ratios further indicate that, apart from riverine inputs, the neighboring large-scale ports and aerosols significantly contributed to the anthropogenic Pb contained in these sediments. Pb contamination in the Haihe and Luanhe river mouths as well as in the regions near ports is also suggested from anthropogenic enrichment factors. As cities and ports continue to develop around Bohai Bay, a long-term extensive sewage monitoring program is highly recommended.

  19. Pb Isotopic Evolution of Koolau Volcano (Oahu, Hawaii)

    NASA Astrophysics Data System (ADS)

    Fekiacova, Z.; Abouchami, W.

    2003-12-01

    High precision Pb isotopes in Hawaiian shield lavas have revealed the existence of source heterogeneities between volcanoes, as well as within a single volcano during its temporal evolution, e.g. Mauna Kea [1, 2]. The Koolau Scientific Drilling Project (KSDP) was initiated in order to evaluate the long-term evolution of Koolau volcano (Oahu), whose subaerial Makapuu stage lavas define the isotopically enriched endmember of Hawaiian shield lavas. We report Pb triple spike data on KSDP main shield-stage lavas (depth range: 304-632 mbsl) and post-erosional Honolulu volcanics. KSDP lavas show a small range of Pb isotopic compositions (206Pb/204Pb=18.02-18.15; 207Pb/204Pb=15.44-15.46; 208Pb/204Pb=37.82-37.87). Pb isotope ratios increase with depth until ˜450 m and then decrease again to a depth of 616 m. Superimposed on this "bell" trend, 206Pb/204Pb ratios oscillate at depth intervals of ˜10m. The Honolulu volcanics display, at a given 206Pb/204Pb ratio, similar 207Pb/204Pb but lower 208Pb/204Pb ratios than KSDP lavas. In 208Pb/204Pb-206Pb/204Pb space, KSDP and Honolulu lavas define two distinct linear arrays which converge at the radiogenic end. However, in 207Pb/204Pb-206Pb/204Pb space, KSDP and Honolulu lavas form a single array, with Honolulu lying at the radiogenic end of the array. While KSDP lavas have more radiogenic Pb isotopic compositions than Makapuu stage lavas [1], they show close resemblance to Nuuanu 1 and Nuuanu 2 landslide blocks [3]. The distinct Pb isotopic features of subaerial, main-shield and post-erosional lavas reflect compositional source changes during the growth of Koolau volcano. The mixing lines defined by KSDP and Honolulu lavas in 208Pb-206Pb space require the presence of three distinct Pb isotopic components. While the enriched "Koolau" component is predominantly sampled during the subaerial stage, its contribution during the main shield building stage has been waxing and waning. The radiogenic Pb endmember common to Honolulu and KSDP

  20. Vapor Pressure Isotope Effects and the Stable Isotope Geochemistry of the Martian Surface

    NASA Astrophysics Data System (ADS)

    Eiler, J. M.

    2002-12-01

    The stable isotope geochemistry of light elements (H, C, N, O and S) is a tool in the search for evidence of life on bodies other than the earth for several reasons: the elements in question are used by all known or easily imagined life forms; several mass spectrometric and spectroscopic methods for measuring their isotopic compositions exist and are appropriate for in situ analysis on other planets; it is known that 'vital effects' generate large (percent) isotopic fractionations; and studies of extant and former life on earth provide models for interpreting such data. However, the evidence stable isotope geochemistry provides is generally interpretable as a signature for life only in the context of a rich understanding of isotopic variations produced by non biological processes in the same environments. Several candidates in the search for extra-terrestrial life (Mars and the Jovian satellites) are bodies having volatile-element geochemical cycles that operate at lower temperatures than the earth's surface and involve phase-changes that do not occur on the earth (e.g., condensation/sublimation of CO2). We review new experimental data (both recently published and unpublished) describing isotopic fractionations accompanying phase changes of CO2, H2O below 240 K, NH3 and CO, compile them with previous data to derive general principles of low-temperature stable isotope fractionations, and discuss their significance for the stable isotope geochemistry of the surface of Mars. One example of the issues constrained by these data (the Martian CO2 cycle) is discussed here. The Martian surface is strongly influenced by condensation/sublimation and adsorption/desorption of CO2. The isotopic consequences of these processes are an attractive goal for in situ observations of atmosphere, ice and/or adsorbed gas because they provide a record of Martian atmospheric dynamics and atmosphere-surface interactions over a range of time-scales. Furthermore, these isotopic signals

  1. Final report of the key comparison CCQM-K98: Pb isotope amount ratios in bronze

    NASA Astrophysics Data System (ADS)

    Vogl, Jochen; Yim, Yong-Hyeon; Lee, Kyoung-Seok; Goenaga-Infante, Heidi; Malinowskiy, Dmitriy; Ren, Tongxiang; Wang, Jun; Vocke, Robert D., Jr.; Murphy, Karen; Nonose, Naoko; Rienitz, Olaf; Noordmann, Janine; Näykki, Teemu; Sara-Aho, Timo; Ari, Betül; Cankur, Oktay

    2014-01-01

    Isotope amount ratios are proving useful in an ever increasing array of applications that range from studies unravelling transport processes, to pinpointing the provenance of specific samples as well as trace element quantification by using isotope dilution mass spectrometry (IDMS). These expanding applications encompass fields as diverse as archaeology, food chemistry, forensic science, geochemistry, medicine and metrology. However, to be effective tools, the isotope ratio data must be reliable and traceable to enable the comparability of measurement results. The importance of traceability and comparability in isotope ratio analysis has already been recognized by the Inorganic Analysis Working Group (IAWG) within the CCQM. While the requirements for isotope ratio accuracy and precision in the case of IDMS are generally quite modest, 'absolute' Pb isotope ratio measurements for geochemical applications as well as forensic provenance studies require Pb isotope ratio measurements of the highest quality. To support present and future CMCs on isotope ratio determinations, a key comparison was urgently needed and therefore initiated at the IAWG meeting in Paris in April 2011. The analytical task within such a comparison was decided to be the measurement of Pb isotope amount ratios in water and bronze. Measuring Pb isotope amount ratios in an aqueous Pb solution tested the ability of analysts to correct for any instrumental effects on the measured ratios, while the measurement of Pb isotope amount ratios in a metal matrix sample provided a real world test of the whole chemical and instrumental procedure. A suitable bronze material with a Pb mass fraction between 10 and 100 mg•kg-1 and a high purity solution of Pb with a mass fraction of approximately 100 mg•kg-1 was available at the pilot laboratory (BAM), both offering a natural-like Pb isotopic composition. The mandatory measurands, the isotope amount ratios n(206Pb)/n(204Pb), n(207Pb)/n(204Pb) and n(208Pb)/n(204Pb

  2. Geochemistry of beryllium isotopes: Applications in geochronometry. Doctoral thesis

    SciTech Connect

    Brown, E.T.

    1990-01-01

    The cosmogenic radioisotope beryllium-10 (half-life= 1.5 Myr) has been determined in suites of samples from tropical river systems and from areas of the oceans influenced by input from the continents, and also within the mineral lattices of quartz grains from Antarctic moraines. These data have been used to investigate the geochemistry of 10Be and apply that knowledge to development of geochronometric techniques. Beryllium-10 is primarily produced by neutron-induced spallation of 14N and 16O in the atmosphere; its flux to the Earth's surface at low latitude was examined through measurements in tropical rainfall. Distributions of 10Be and 9Be (the stable isotope) in dissolved and particulate phases in tropical rivers were used, in conjunction with major ion data, to delineate the geochemical cycle of Be in these river systems. The present work applies in situ cosmogenic production to the examination of the deposition history of moraines of varying ages in Antarctica. It also yields estimates of 10Be and 26Al production rates: 6.4(+5.9-1.5) at/g yr and 42(+20-6) at/g yr at sea level and high geomagnetic latitude.

  3. Nuclear Volume Effects in Equilibrium Stable Isotope Fractionations of Hg, Tl and Pb Isotope Systems

    NASA Astrophysics Data System (ADS)

    Yang, S.; Liu, Y.

    2014-12-01

    Many evidences showed that heavy isotope systems could be significantly fractionated as the consequence of the nuclear volume effect (NVE) or so-called nuclear field shift effect. Here we investigate NVEs of Hg, Tl and Pb isotope systems by using quantum chemistry computational methods with careful evaluation on quantum relativistic effects via the Dirac's formalism of full-electron wavefunction. Our results generally agree with previous studies but with noticeable differences in many cases. With the unique NVE driving force, equilibrium 202Hg/198Hg and 205Tl/203Tl isotopes can be fractionated up to 3.94‰ and 2.78‰ at 0℃, respectively, showing potentially large equilibrium isotope fractionations can be expected for future studies of these two isotope systems. Moreover, the NVE causes large mass-independent fractionations (MIF) for odd-mass isotopes (e.g., ∆199NVHg and ∆201NVHg) and small MIFs for even-mass isotopes (e.g., ∆200NVHg). For Pb isotope system, NVEs induce isotope fractionations up to 1.62‰ (207Pb/206Pb) and 4.06‰ (208Pb/206Pb) at 0℃. However, contributions from classical mass-dependent driving force are small, about 0.1-0.5‰ for 207Pb/206Pb and 0.2-0.9‰ for 208Pb/206Pb. We find that Pb4+-bearing species can be significantly enriched heavy isotopes than Pb2+-bearing species. Comparing to Pb0, Pb2+-bearing species even enrich lighter Pb isotopes. A very strange and interesting thing is that the beta value of Pb2+-bearing species can be smaller than the unity (1.000). Similar thing has been found on Tl+-bearing species. This is an impossible and unexplained situation if only based on classical mass-dependent isotope fractionation theory (e.g., Bigeleisen-Mayer equation). The consequence is that the different direction of beta values of Pb2+-bearing species will let the Pb isotope fractionation even larger when they fractionate with Pb4+-bearing species. Moreover, NVEs also cause mass-independent fractionation (MIF) of odd 207Pb

  4. The Pb isotopic compositions of lower crustal xenoliths and the evolution of lower crustal Pb

    NASA Astrophysics Data System (ADS)

    Rudnick, Roberta L.; Goldstein, Steven L.

    1990-05-01

    Pb isotopic compositions for three suites of well-characterized granulite facies xenoliths from a diversity of crustal settings (the Chudleigh and McBride volcanic provinces, Queensland, Australia and the Eifel volcanics, West Germany) are presented here. All three suites plot to the right of the 4.57 Ga geochron, similar to the published Pb results of other mafic granulite xenoliths. Correlations between Sr, Nd and Pb isotopes in the three suites measured here point to an origin by mixing of mantle-derived basaltic magmas with lower crust at the time of basaltic underplating (i.e., < 100 Ma for Chudleigh, ˜ 300 Ma for McBride, ˜ 450 Ma for Eifel). Because the Pb concentration of the continental crust is much greater than that of mantle-derived basaltic magmas, the Pb isotopic compositions of the magmas are shifted dramatically by the mixing, allowing delineation of the isotopic characteristics of the lower crust. In all three cases, this lower crust had radiogenic Pb and Sr isotopic compositions and unradiogenic Nd isotopic compositions, yielding Proterozoic Nd model ages. Such radiogenic lower crust contrasts markedly with the Pb isotopic characteristics of most Precambrian granulite facies terrains. Whereas the Nd isotopes reflect the average age of crust formation, the Pb isotopic characteristics of the lower crust appear to be a function of the tectonothermal age of the crust: unradiogenic Pb can only develop in regions which have remained stable for long time periods (e.g., cratons), whereas in areas where orogenies have occurred subsequent to crustal formation, the Pb isotopic composition of the lower crust is "rejuvenated" through mixing with radiogenic Pb from upper crust and mantle-derived magmas. Thus, after orogeny, the Pb isotopic composition of the lower crust resembles that of the upper crust. On the basis of this proposed orogenic age-Pb isotope correlation, we estimate the Pb isotopic composition of the lower crust using the data for granulite

  5. Archean Pb Isotope Evolution: Implications for the Early Earth.

    NASA Astrophysics Data System (ADS)

    Vervoort, J. D.; Thorpe, R.; Albarede, F.; Blichert-Toft, J.

    2008-12-01

    The U-Pb isotope system provides us with a powerful tool for understanding the chemical evolution of the Earth. Pb isotopes in Archean rocks, however, have not been widely utilized because U mobility makes initial Pb isotope ratios from old silicate rocks difficult, if not impossible, to determine. Galenas in syngenetic volcanogenic massive sulfide (VMS) deposits, however, provide snapshots of initial Pb ratios because their Pb isotopic composition is time invariant at their formation (U/Pb=0). The Pb isotopic record from galenas from rocks of all age have been utilized for over 70 years to answer a wide range of scientific problems beginning with Al Nier's pioneering work analyzing Pb isotopes in the 1930's but are no longer widely used by the isotopic community because they have been produced by older TIMS techniques. We have begun a re-examination of Archean Pb by an extensive analysis of over 100 galena samples from Archean VMS deposits throughout the Superior and Slave Provinces in Canada as well as from other VMS deposits in Finland, South Africa and Western Australia. The goal of this work is to provide modern, high precision measurements and update an old, but venerable, Pb isotopic data set. We feel these data provide important constraints on not only the Pb isotopic evolution of the Earth, but planetary differentiation and recycling processes operating in the first 2 b.y. of Earth's history. Our analytical techniques include dissolving the Pb sulfide minerals, purifying them with ion chromatography, and analyzing them using MC-ICPMS at both Washington State University (Neptune) and Ecole Normale Superieure in Lyon, France (Nu). All Pb solutions are doped with Tl in order to correct for mass fractionation. In this abstract we report preliminary galena Pb isotope data from 6 VMS deposits in the Abitibi greenstone belt: Chibougamu, Matagami, Noranda, Normetal, Timmins, and Val d"Or. These deposits are all approximately 2.7 Ga in age but in detail vary from 2

  6. Pb isotopes in drinking water: a new strategy for detection of low Pb sources

    EPA Science Inventory

    Source detection of low concentrations of Pb in water, for instance less than 15 µg L-1, may require a new methodology as the tolerances of Pb in drinking water are further reduced. It appears that the isotope properties of Pb may aid discrimination among natural sources and anth...

  7. Geochemistry.

    ERIC Educational Resources Information Center

    Fyfe, William S.

    1979-01-01

    Techniques in geochemistry continue to improve in sensitivity and scope. The exciting areas of geochemistry still include the classical fields of the origin of the elements and objects in space, but environmental crisis problems are important as well. (Author/BB)

  8. U-Th-Pb isotopic systematics of lunar norite 78235

    NASA Technical Reports Server (NTRS)

    Premo, W. R.; Tatsumoto, M.

    1991-01-01

    A pristine high-Mg noritic cumulate thought to be relict deep-seated lunar crust is studied with an eye to obtaining evidence of initial Pb isotopic composition and U/Pb ratios of early lunar magma sources and possibly of a primary magma ocean. A leaching procedure was conducted on polymineralic separates to assure the removal of secondary Pb components. The Pb from leached separates do not form a linear trend on the Pb-Pb diagram, indicating open-system behavior either from mixtures of Pb or postcrystallization disturbances. Calculated initial Pb compositions and corresponding U-238/Pb-204 (mu) values are presented, with the assumption of reasonably precise radiometric ages from the literature for norite 78236. The results obtained support the contention that high-Mg suite rocks are coeval with the ferroan anorthosites, both being produced during the earliest stages of lunar evolution.

  9. Zircon U-Pb geochronology, and elemental and Sr-Nd-Hf-O isotopic geochemistry of post-collisional rhyolite in the Chiang Khong area, NW Thailand and implications for the melting of juvenile crust

    NASA Astrophysics Data System (ADS)

    Qian, Xin; Wang, Yuejun; Feng, Qinglai; Zi, Jian-Wei; Zhang, Yuzhi; Chonglakmani, Chongpan

    2016-06-01

    Volcanic rocks are widely exposed within the Chiang Khong-Lampang-Tak igneous zone in NW Thailand. A representative rhyolite sample from the Chiang Khong area yielded a zircon U-Pb age of 230.7 ± 1.1 Ma (n = 20, MSWD = 0.98). The Chiang Khong rhyolites are characterized by low TiO2 (0.29-0.62 wt%) and MgO (0.04-0.82 wt%) with A/CNK values of 0.95-1.06 (one outlier at 1.47), and can be classified as highly fractionated I-type rhyolites. They are enriched in LILEs and LREEs, and depleted in HFSEs. Two representative samples have 87Sr/86Sr (i) ratios of 0.70497 and 0.70527, and the ɛNd (t) values fall at +1.1 and +1.3, respectively. ɛHf (t) and δ18O in zircon are between +4.7 to +12.0 and 5.3 to 5.9 ‰, respectively. Our geochemical data suggest that the Chiang Khong rhyolites formed by partial melting of juvenile mafic lower crust in a post-collisional setting. Deep crustal anatexis was probably induced by upwelling asthenospheric mantle, shortly after slab detachment subsequent to closure of the Paleo-Tethys.

  10. Zircon U-Pb age and Sr-Nd-Hf isotope geochemistry of the Ganluogou dioritic complex in the northern Triassic Yidun arc belt, Eastern Tibetan Plateau: Implications for the closure of the Garzê-Litang Ocean

    NASA Astrophysics Data System (ADS)

    Wu, Tao; Xiao, Long; Wilde, Simon A.; Ma, Chang-Qian; Li, Zi-Long; Sun, Yi; Zhan, Qiong-Yao

    2016-04-01

    The Triassic Yidun arc belt (YAB) lies between the Jinshajiang suture zone to the west and the Garzê-Litang suture zone to the east, Eastern Tibetan Plateau. To study the YAB can not only help us to better understand the evolutionary history of the Garzê-Litang Ocean but can also provide some important information to constrain the evolution of the eastern Paleo-Tethys. In this paper, the geochronological and geochemical data of the Ganluogou dioritic complex were systematically investigated in order to decipher the geodynamic setting of the complex and to further determine the final closure time of the Garzê-Litang Ocean. The Ganluogou dioritic complex is located in the northern part of the YAB. It consists of ferrodiorite, diorite and a mixing zone between them and is the largest intermediate-mafic pluton in the YAB. The ferrodiorites were emplaced at 213 ± 2 Ma have low SiO2 and high Fe2O3* contents, whereas the diorites formed at 209 ± 2 Ma and have relatively higher SiO2, Na2O + K2O, Th, U, Zr, and Hf contents, but lower Al2O3, MgO, CaO, Co, and Sr contents than the ferrodiorites. Relative to the primitive mantle both the ferrodiorites and diorites are depleted in Nb and Ta. However, the ferrodiorites exhibit strong depletion in Zr and Hf, whereas the diorites contain relatively higher Th and U contents without negative Zr and Hf anomalies. Both rock-types have similar chondrite-normalized rare earth element patterns with (La/Yb)N ratios = 4.4 to 18.2, and show weak Eu anomalies, with Eu/Eu* of 0.47 to 1. They both show narrow ranges in Sr-Nd-Hf isotopic compositions. However, the ferrodiorites contain lower initial 87Sr/86Sr ratios (0.7052-0.7057) and relatively higher εNd(t) values (- 3.8 to - 2.4) than the diorites, which record values of 0.7062-0.7066 and - 5.5 to - 5.7, respectively. For the zircon Hf isotopic composition, the ferrodiorites also exhibit higher 176Hf/177Hf ratios (0.282738-0.282804) and more depleted εHf(t) values (3.4-5.6) than

  11. Origin of the Ediacaran Porongos Group, Dom Feliciano Belt, southern Brazilian Shield, with emphasis on whole rock and detrital zircon geochemistry and U-Pb, Lu-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Pertille, Juliana; Hartmann, Léo Afraneo; Philipp, Ruy Paulo; Petry, Thales Sebben; de Carvalho Lana, Cristiano

    2015-12-01

    The Porongos Group is the major component of a fold and thrust belt located in the central portion of the Dom Feliciano Belt in the Sul-Riograndense Shield, Brazil. In this paper, the variations in composition of sediments and the depositional time are presented. Major and trace elements indicate that Porongos Group is composed mostly of immature sediments derived from intermediate felsic sources with minor contribution from mature recycled sources. U-Pb SHRIMP ages for a chlorite schist (sample 300) exhibit a proeminent population of 570-800 Ma, subordinate population of 1800-2250 Ma and minor population of 1200 Ma, whereas for a schist (sample 198) the main population is 1050-1500 and minor populations are 2040-2300 and 580-800 Ma. The ɛHf values of Neoproterozoic grains indicate variable degrees of crustal reworking (ɛHf = -18 to -4) with three main TDM model ages (2.2, 1.8, 1.5 Ga). The Paleoproterozoic grains include a few Archean (3.2-2.5 Ga) TDM ages. The trace elements of all analyzed detrital zircon grains reflect continental crust origin. According to the data set, the sediments of the Porongos Group were derived from locally eroded granitic rocks of the Dom Feliciano Belt and from the uplifted Paleoproterozoic basement (La Plata Craton). Further analytical signal and total magnetic field maps delimit regionally the shape and extension of the Porongos fold and thrust belt and includes the Capané region. We conclude that the duration of Porongos Group basin filling probably lasted from 650 to 570 Ma in a foreland tectonic setting of the Dom Feliciano Belt.

  12. Geochemistry

    ERIC Educational Resources Information Center

    Ailin-Pyzik, Iris B.; Sommer, Sheldon E.

    1977-01-01

    Enumerates some of the research findings in geochemistry during the last year, including X-ray analysis of the Mars surface, trace analysis of fresh and esterarine waters, and analysis of marine sedements. (MLH)

  13. A new method fingerprinting magmatic processes using combined U/Pb ID-TIMS geochronology and accessory mineral geochemistry

    NASA Astrophysics Data System (ADS)

    Schoene, B.; Schaltegger, U.; Latkoczy, C.; Günther, D.

    2009-12-01

    Zircon is commonly used as a recorder of magmatic processes because of its utility in geochronology and ability to retain primary growth information at prolonged magmatic conditions. Recent applications of U-Pb ID-TIMS geochronology have shown that precision on dates of single zircons are often far smaller than the time-scales of magmatic systems. The result is that dates on such grains record various processes occurring over an interval of time during the production, mobilisation, and emplacement of magmas. Combining age information with geochemical data from the same zircons has proved a useful tool, but thus far has been restricted to low-precision in situ dating techniques. Furthermore, these techniques have been unable to combine age data with trace element geochemistry on the same volume of zircon. We have developed a new technique that combines high-precision ID-TIMS dating with geochemical characterization on the exact same material. U and Pb are commonly separated from the other chemical constituents by ion exchange chemistry during sample preparation. We retain this fraction and analyse it using solution nebulization ICP-SFMS with matrix-matched external liquid calibration. We measured elements such as Zr, Hf, Y, Sc, and the REE, which are present in solution at between 10 and >105 ppt; Hf isotopes are subsequently measured on the same solution. Data obtained using this approach allow us to distinguish between models for melt generation, transport, and assembly of the ca. 40 Ma composite mafic to felsic Re di Castello pluton, Adamello batholith, northern Italy. Coupled with age uncertainties on single zircons as low as 10,000 years, zircon geochemistry preserves a rich record of fractional crystallization, crustal assimilation and magma mixing over timescales of <20,000 to >400,000 years. These data can also be used to distinguish between auto-, xeno-, and antecrystic zircon. Combined with field observation and U-Pb sphene thermochronology, we show that

  14. Dynamics of the Galapagos hotspot from helium isotope geochemistry

    SciTech Connect

    Kurz, M.D.; Geist, D.

    1999-12-01

    The authors have measured the isotopes of He, Sr, Nd and Pb in a number of lava flows from the Galapagos Archipelago; the main goal is to use magmatic helium as a tracer of plume influence in the western volcanoes. Because the Galapagos lava flows are so well preserved, it is also possible to measure surface exposure ages using in situ cosmic-ray-produced {sup 3}He. The exposure ages range from {lt}0.1 to 580 Ka, are consistent with other chronological constrains, and provide the first direct dating of these lava flows. The new age data demonstrate the utility of the technique in this important age range and show that the western Galapagos volcanoes have been erupting distance compositions simultaneously for the last {approximately}10 Ka. The magmatic {sup 3}He/{sup 4}He ratios range from 6.0 to 27 times atmospheric (R{sub a}), with the highest values found on the islands of Isabella (16.8 R{sub a} for Vulcan Sierra Negra) and Fernandina (23 to 27 R{sub a}). Values from Santa Cruz are close to typical mid-ocean ridge basalt values (MORB, of {approximately}9 R{sub 2}) and Pinta has a {sup 3}He/{sup 4}He ratio lower than MORB (6.9 R{sub a}). These data confirm that the plume is centered beneath Fernandina which is the most active volcano in the archipelago and is at the leading edge of plate motion. The data are consistent with previous isotopic studies, confirming extensive contributions from depleted asthenospheric or lithospheric mantle sources, especially to the central islands. The most striking aspect of the helium isotopic data is that the {sup 3}He/{sup 4}He ratios decrease systematically in all directions from Fernandina. This spatial variability is assumed to reflect the contribution of the purest plume component to Fernandina magmatism, and shows that helium is a sensitive indicator of plume influence. The highest {sup 3}He/{sup 4}He ratios are found in volcanoes with lowest Na{sub 2}O(8) and FeO(8), which may relate to source composition as well as degree

  15. Pb isotopes in surficial pelagic sediments from the North Atlantic

    NASA Technical Reports Server (NTRS)

    Hamelin, B.; Grousset, F.; Sholkovitz, E. R.

    1990-01-01

    The concentration of Pb and its isotopic composition were measured in samples from the surface of sea-water sediments obtained from the northeastern Atlantic, the Sargasso Sea, and the U.S. continental shelf, with the purpose of investigating changes in Pb sources due to the anthropogenic perturbation that took place in modern times. It was found that the anthropogenic Pb input to marine sediments due to the increase of Pb contamination over the ocean during the last century could be identified in all these samples. However, samples from eastern and western Atlantic had very different Pb isotopic profiles, each reflecting the character of anthropogenic Pb emissions from the European and U.S. industries, respectively.

  16. The Pb isotopic evolution of the Martian mantle constrained by initial Pb in Martian meteorites

    NASA Astrophysics Data System (ADS)

    Bellucci, J. J.; Nemchin, A. A.; Whitehouse, M. J.; Snape, J. F.; Bland, P.; Benedix, G. K.

    2015-12-01

    The Pb isotopic compositions of maskelynite and pyroxene grains were measured in ALH84001 and three enriched shergottites (Zagami, Roberts Massif 04262, and Larkman Nunatuk 12011) by secondary ion mass spectrometry. A maskelynite-pyroxene isochron for ALH84001 defines a crystallization age of 4089 ± 73 Ma (2σ). The initial Pb isotopic composition of each meteorite was measured in multiple maskelynite grains. ALH84001 has the least radiogenic initial Pb isotopic composition of any Martian meteorite measured to date (i.e., 206Pb/204Pb = 10.07 ± 0.17, 2σ). Assuming an age of reservoir formation for ALH84001 and the enriched shergottites of 4513 Ma, a two-stage Pb isotopic model has been constructed. This model links ALH84001 and the enriched shergottites by their similar μ value (238U/204Pb) of 4.1-4.6 from 4.51 Ga to 4.1 Ga and 0.17 Ga, respectively. The model employed here is dependent on a chondritic μ value (~1.2) from 4567 to 4513 Ma, which implies that core segregation had little to no effect on the μ value(s) of the Martian mantle. The proposed Pb isotopic model here can be used to calculate ages that are in agreement with Rb-Sr, Lu-Hf, and Sm-Nd ages previously determined in the meteorites and confirm the young (~170 Ma) ages of the enriched shergottites and ancient, >4 Ga, age of ALH84001.

  17. Isotopic equilibration between dissolved and suspended particulate lead in the Atlantic Ocean - Evidence from Pb-210 and stable Pb isotopes

    NASA Technical Reports Server (NTRS)

    Sherrell, Robert M.; Boyle, Edward A.; Hamelin, Bruno

    1992-01-01

    Vertical profiles of, on one hand, the stable Pb isotopic composition, and on the other, the ratio of total Pb to Pb-210 in suspended particles, are noted to closely track contemporaneous depth variations in these ratios for dissolved Pb throughout the upper 2 km of the Sargasso Sea near Bermuda. A simple flux model suggests that the effect of deep ocean scavenging processes on the flux and isotopic composition of Pb sinking on large particles was minor throughout the preanthropogenic, and most of the anthropogenic era: but it has become more important as surface inputs decrease to preleaded gasoline levels, perhaps exceeding the contribution of surface-derived Pb flux in the next decade.

  18. U-Pb isotopic systematics of ferroan anorthosite 60025

    NASA Technical Reports Server (NTRS)

    Premo, W. R.; Tatsumoto, M.

    1993-01-01

    Preliminary U-Pb isotopic data from separates of ferroan anorthosite 60025 confirm its antiquity at approximately 4.42 Ga. Three Pb-Pb isochron ages involving different sets of mineral separates vary by only 20 million years, but indicate derivation of the sets from isotopically distinct magma sources. If this anorthosite was a monomict cumulate product formed during the Moon's early primary differentiation stage, then residual liquids of crystallizing magmas were evolving isotopically, even at the cm-scale, over the duration of the crystallization period. Another explanation is that this sample is simply a polymict breccia and that the Pb isotopic results are a result of subsequent mechanical mixing of mineral assemblages from various cumulate piles formed coevally at approximately 4.42 Ga from isotopically distinct magma sources. In our ongoing search for early lunar Pb isotopic compositions, we have analyzed Apollo 16 anorthosites 67075 and 62337 and Apollo 17 high-Mg suite cumulates (troctolite 76535, norite 78235, and dunite 72415). The U-Pb isotopic systematics have been better behaved in the high-Mg suite rocks than in the anorthosites that have shown evidence of mineral assemblages of mixed parentage. Our aim in analyzing anorthosite 60025 was to avoid or minimize this problem as it had been considered essentially monomict, although recent work has shown that not only is 60025 polymict, but shows textual evidence of at least two episodes of deformation. Of five splits studied by James, Lindstrom and McGee, the four mineral splits appeared monomict, whereas the whole-rock split was considered polymict. Previous isotopic work indicate that this anorthosite was quite primitive, a claim that was apparently confirmed by the U-Pb isotopic age of 4.51 +/- .01 Ga on three plagioclase separates. However, a Sm-Nd internal isochron age of 4.44 +/- 0.02 Ga was determined using plagioclase, olivine, and mafic mineral separates, creating some doubt about the anorthosite

  19. Pb isotopes in surficial pelagic sediments from the North Atlantic

    SciTech Connect

    Hamelin, B.; Grousset, F. ); Sholkovitz, E.R. )

    1990-01-01

    The authors measured Pb isotopic composition and concentration in sediment samples close to the sea water interface in 6 box-cores from the NE Atlantic, 2 box-cores from the Sargasso Sea, and one from the US continental shelf. The anthropogenic Pb input to marine sediments due to the increase of Pb contamination over the ocean during the last century can be identified in all these cores. In the eastern part of the Atlantic, i.e., in regions under aeolian influence from Europe, Pb pollution can be recognized using its distinctive unradiogenic composition, clearly different from the upper-crustal values commonly found in pre-Holocene sediments. In contrast, Pb pollution in regions influenced by North American sources can be identified only in detailed concentration profiles because the American Pb pollution has an isotopic composition much closer to that of the natural detrital Pb input coming from weathering of the continental crust. Pb excess inventories are in good agreement with fluxes estimated from sediment-trap data and with the time record of Pb-contamination increase given by analyses in coral growth bands. Inventories of Pb contamination to the sediments of the Mud Patch (American shelf) are tenfold higher (84 {mu}g/cm{sup 2}) than those to Hatteras and Bermuda abyssal plains (4.3 and 2.8 {mu}g/cm{sup 2}).

  20. Geochemistry

    SciTech Connect

    Foster, N.H.; Beaumont, E.A.

    1988-01-01

    Papers in this text are part of a reprint series designed to be useful to those involved in petroleum exploration and development. The authors divide the topic of geochemistry into four sections: (1) petroleum formation,(2) source rock evaluation, (3) migration, and (4) surface geochemistry. Petroleum formation contains papers that discuss accumulation and preservation of organic matter, conversion to kerogen, conversion to petroleum, and effects that different types of kerogen have on the types of petroleum generated. The section on source rocks contain papers that review methods for estimating total organic content of source rocks, potential amount of petroleum they can expel, and quantity of petroleum expelled from these source rocks.Migration deals with mechanisms for expulsion and migration of petroleum from source rocks and in carrier beds. The section on surface geochemistry discusses the problems associated with using geochemical methods in exploration.

  1. Reconstruction of historical atmospheric Pb using Dutch urban lake sediments: a Pb isotope study.

    PubMed

    Walraven, N; van Os, B J H; Klaver, G Th; Middelburg, J J; Davies, G R

    2014-06-15

    Lake sediments provide a record of atmospheric Pb deposition and changes in Pb isotope composition. To our knowledge, such an approach has not previously been performed in The Netherlands or linked to national air monitoring data. Results are presented for Pb content and isotope composition of (137)Cs dated lake sediments from 2 Dutch urban lakes. Between 1942 and 2002A.D. anthropogenic atmospheric Pb deposition rates in the two lakes varied from 12±2 to 69±16μgcm(-2)year(-1). The rise and fall of leaded gasoline is clearly reflected in the reconstructed atmospheric Pb deposition rates. After the ban on leaded gasoline, late 1970s/early 1980s, atmospheric Pb deposition rates decreased rapidly in the two urban lakes and the relative contributions of other anthropogenic Pb sources - incinerator ash (industrial Pb) and coal/galena - increased sharply. Atmospheric Pb deposition rates inferred from the lake record a clear relationship with nearby measured annual mean air Pb concentrations. Based on this relationship it was estimated that air Pb concentrations between 1942 and 2002A.D. varied between 5 and 293ng/m(3). PMID:24705301

  2. Pb isotopic evidence for early Archaean crust in South Greenland

    NASA Astrophysics Data System (ADS)

    Taylor, P. N.; Kalsbeek, F.

    The results of an isotopic remote sensing study focussed on delineating the extent of Early Archean crust north and south of the Nuuk area and in south Greenland is presented. Contamination of the Late Archean Nuk gneisses and equivalents by unradiogenic Pb uniquely characteristic of Amitsoq gneiss was detected as far south as Sermilik about 70 km south of Nuuk and only as far north as the mouth of Godthabsfjord. This study was extended to the southern part of the Archean craton and the adjoining Early Proterozoic Ketilidian orogenic belt where the Pb isotopes suggest several episodes of reworking of older uranium depleted continental crust. The technique of using the Pb isotope character of younger felsic rocks, in this case Late Archean and Early Proterozoic gneisses and granites to sense the age and isotopic character of older components, is a particularly powerful tool for reconstructing the evolutionary growth and development of continental crust.

  3. Pb isotopic evidence for early Archaean crust in South Greenland

    NASA Technical Reports Server (NTRS)

    Taylor, P. N.; Kalsbeek, F.

    1986-01-01

    The results of an isotopic remote sensing study focussed on delineating the extent of Early Archean crust north and south of the Nuuk area and in south Greenland is presented. Contamination of the Late Archean Nuk gneisses and equivalents by unradiogenic Pb uniquely characteristic of Amitsoq gneiss was detected as far south as Sermilik about 70 km south of Nuuk and only as far north as the mouth of Godthabsfjord. This study was extended to the southern part of the Archean craton and the adjoining Early Proterozoic Ketilidian orogenic belt where the Pb isotopes suggest several episodes of reworking of older uranium depleted continental crust. The technique of using the Pb isotope character of younger felsic rocks, in this case Late Archean and Early Proterozoic gneisses and granites to sense the age and isotopic character of older components, is a particularly powerful tool for reconstructing the evolutionary growth and development of continental crust.

  4. β- decay of the neutron-rich isotope 215Pb

    NASA Astrophysics Data System (ADS)

    De Witte, H.; Eeckhaudt, S.; Andreyev, A. N.; Borzov, I. N.; Cederkäll, J.; De Smet, A.; Fedorov, D. V.; Fedoseyev, V. N.; Franchoo, S.; Górska, M.; Grawe, H.; Huber, G.; Huyse, M.; Janas, Z.; Köster, U.; Kurcewicz, W.; Kurpeta, J.; Płochocki, A.; Van de Vel, K.; Van Duppen, P.; Weissman, L.

    2013-06-01

    This Brief Report reports on the first observation of the β--delayed γ decay of 215Pb, feeding states in 215Bi. The 215Pb beam was produced using resonant laser ionization and mass separated at the ISOLDE-CERN on-line mass separator. This ensured clean identification of the γ rays as belonging to the decay of 215Pb or its β-decay daughters. A half-life of 147(12) s was measured for the 215Pb β decay and a level scheme for the daughter nucleus 215Bi is proposed, resulting in an extended systematics of the excited states of the neutron-rich Bi isotopes.

  5. Sr-Nd-Pb isotope variability across and along the Ecuadorian volcanic arc

    NASA Astrophysics Data System (ADS)

    Ancellin, Marie-Anne; Samaniego, Pablo; Vlastélic, Ivan; Nauret, François; Gannoun, Mouhcine; Hidalgo, Silvana

    2016-04-01

    the 2 cordilleras and of the inter-andean valley plot at the junction of the two trends. These new data confirm previous observations made with the trace element and Sr-Nd systematics that suggested marked differences between the two cordilleras ([1], [3], [4]), and allow us to go forward distinguishing the back-arc. In addition, we are able to test the influence of Carnegie ridge on magma geochemistry, which is still debated. Altogether, Sr-Nd-Pb isotope variations require three different magmatic sources: (1) an unradiogenic component, represented by back-arc magmas, which may correspond to the mantle source; (2) an upper crustal radiogenic component, expressed in Eastern cordillera magmas and (3) a third component (low 87Sr/86Sr, radiogenic Nd-Pb isotopes), represented by some Western Cordillera magmas, which could either be an unradiogenic, immature oceanic basement or a slab influence. [1] Hidalgo et al., Lithos 132-133 (2012), 180-192 [2] Samaniego et al., Contrib. Mineral. Petrol. 160 (2010), 239-260 [3] Chiaradia et al., Contrib. Mineral. Petrol. 158 (2009), 563-588 [4] Schiano et al., Contrib. Mineral. Petrol. 160 (2010), 297-312

  6. Impact of anthropogenic Pb and ocean circulation on the recent distribution of Pb isotopes in the Indian Ocean

    NASA Astrophysics Data System (ADS)

    Lee, Jong-Mi; Boyle, Edward A.; Gamo, Toshitaka; Obata, Hajime; Norisuye, Kazuhiro; Echegoyen, Yolanda

    2015-12-01

    Pb and Pb isotope ratios in the modern ocean have been altered significantly by anthropogenic Pb inputs over the past century. Most studies of anthropogenic Pb in the ocean have focused on the North Atlantic and North Pacific Oceans, and the impact of anthropogenic Pb inputs to the Indian Ocean and processes controlling the distribution of Pb in the Indian Ocean are poorly known. This study presents the Pb and Pb isotopic composition (206Pb/207Pb, 208Pb/207Pb) of 11 deep stations from the Indian Ocean Japanese GEOTRACES cruise (KH-09-5), from the Bay of Bengal and Arabian Sea to the Southern Ocean (62°S). The Pb isotope ratios of the Indian Ocean range 1.140-1.190 for 206Pb/207Pb and 2.417-2.468 for 208Pb/207Pb, with lower ratios appearing in the shallow waters of the northern Indian Ocean and higher ratios appearing in the deep layers of the Southern Ocean. This result agrees with a previous study on Pb concentrations (Echegoyen et al., 2014) showing that the Indian Ocean, particularly its northern part, is largely perturbed by anthropogenic Pb inputs. 206Pb/207Pb and 208Pb/207Pb of the Indian sector Southern Ocean are still lower than natural Pb, showing this region was also affected by anthropogenic Pb. Anomalously low or high 206Pb/207Pb and 208Pb/207Pb were observed in the thermocline and shallow waters of the southern Indian Ocean and the Arabian Sea, which are ascribed to water mass distribution (e.g., Subantarctic Mode Water) and evolving Pb isotope ratios of this region as dominant anthropogenic Pb sources change. 206Pb/207Pb and 208Pb/207Pb in the Bay of Bengal are higher than those in the Arabian Sea, which might be the result of the anthropogenic Pb inputs from different provenance or seawater exchanging Pb isotopes with natural particles derived from rivers and/or sediments at the basin boundaries.

  7. Radioactive halos and ion microprobe measurement of Pb isotope ratios

    NASA Technical Reports Server (NTRS)

    Gentry, R. V.

    1974-01-01

    This investigation was to obtain, if possible, the Pb isotope ratios of both lunar and meteoritic troilite grains by utilizing ion microprobe techniques. Such direct in situ measurement of Pb isotope ratios would eliminate contamination problems inherent in wet chemistry separation procedures, and conceivably determine whether lunar troilite grains were of meteoritic origin. For comparison purposes two samples of meteoritic troilite were selected (one from Canyon Diablo) for analysis along with two very small lunar troilite grains (approximately 50-100 microns). It was concluded that the ion microprobe as presently operating, does not permit the in situ measurement of Pb isotope ratios in lunar or meteoritic troilite. On the basis of these experiments no conclusions could be drawn as to the origin of the lunar troilite grains.

  8. Chemical weathering of granitic rock: experiments and Pb-Li isotopes tracing

    NASA Astrophysics Data System (ADS)

    Millot, R.; Négrel, P.

    2011-12-01

    In a recent study (Négrel et al. 2010, Chem. Geol. Vol. 274) focusing on the lead geochemistry and Pb-isotope ratios of groundwaters along a small (53 km2) endoreic granitic catchment in India (Masheshwaram, Andhra Pradesh), we have shown that most of the lead in the groundwaters is of geogenic origin. Combining a weathering model and field observations, we were able to define a two-step weathering process that includes a control on the Pb-isotope ratios by accessory phases and by the main minerals from the granite in a second step of weathering. In order to go further and to better characterize water/rock interactions, we performed laboratory experiments with the two main granite bedrocks from this site. The aim of the present work is to better constrain the processes of water/rock interactions both in terms of source (dissolution of different primary minerals) and extent of weathering, by measuring Pb isotope signatures in addition with Li isotope signatures. Laboratory experiments consisted in measuring the evolution through time of major and trace elements, as well as Pb and Li isotopic compositions of a rainwater solution in equilibrium with a granite powder. Experiments were carried out at 25°C with a solution/powder mass ratio of 10 considering 15 mL of reference solution TMRAIN-95 and 1.5 g of powdered granite placed in screw-top Teflon° PFA beakers. The beakers were kept in a temperature-controlled oven, which temperature was maintained within 5% of target temperature over the total duration of the experiments. Aliquots of the solution (after filtration at 0.2 μm) in contact with the granite powder were periodically sampled (from weeks up to 2 years) and analyzed for lead and lithium isotopic compositions. The results show that a radiogenic contribution of lead is observed during the experiments, in agreement with the field observations, and that the light lithium isotope (6Li) is preferentially retained during uptake of Li into secondary minerals. The

  9. Pb - Isotopes and Pulses of the Deccan Plume

    NASA Astrophysics Data System (ADS)

    Basu, A. R.; Yannopoulos, A. S.

    2015-12-01

    Mantle plumes are generally implicated for flood basalt generation in both continental and oceanic environments by impact of large plume heads beneath or within the lithosphere. The Deccan and Siberian flood basalt eruptions, synchronous with the Cretaceous-Paleogene and end-Permian extinctions, respectively, continue to fascinate geoscientists in search for the "kill-mechanisms" by impacts, volcanisms or both. Recently, Richards et al. (2015) proposed that bulk of the Deccan eruption was triggered by the Chicxulub impact. We showed (Basu et al., 1993) that early (68.5 Ma) and late (65 Ma) alkalic pulses of the Deccan were before and after the impact event at 66 Ma. Here, we focus on an extensive volcano-stratigraphic study of Pb isotopic systematics of 69 basaltic samples from 3 subgroups and 12 formations of the Deccan, each sampled from bottom to top along the stratigraphic section, covering the 3km thick 12 Deccan formations. Pb is sensitive to crustal contamination of mantle plume-derived magmas as both the upper and lower mantle are low in Pb (0.02 - 0.15 ppm) compared to ~ 4 ppm in continental crust. The lower Deccan formations of Kalsubai and Lonavala have initial 206Pb/204Pb with a widely varying range (16.543 - 22.823) indicating continental crustal contamination. In contrast, the upper formations of the Wai subgroup show a narrow range of 16.883 to 18.956, reflecting the plume signature. In addition, the 206Pb/204Pb and 207Pb/204Pb data of the Kalsubai subgroup lavas give an isochron age of 2603±140 Ma (single-stage, µ = 8). The Wai subgroup shows a narrow and restricted Pb isotopic range plotting closer to the Geochron. We interpret these data to infer that the basement rocks of the Deccan, the Archean Indian craton, were assimilated by the upwelling melt, ultimately clearing the conduit passages for the lavas sourced from direct melting of the plume head.

  10. Temporal trends of pollution Pb and other metals in east-central Baffin Island inferred from lake sediment geochemistry.

    PubMed

    Michelutti, Neal; Simonetti, Antonio; Briner, Jason P; Funder, Svend; Creaser, Robert A; Wolfe, Alexander P

    2009-10-15

    Concentrations and stable isotope ratios of lead (Pb) from lake sediments were used to quantify temporal patterns of anthropogenic Pb pollution in the Clyde River region of Baffin Island, Arctic Canada. Surface sediments from eight lakes on eastern Baffin Island and one from northern-most Greenland, spanning a gradient of 20 degrees latitude, showed great variability with respect to Pb concentration and stable isotopic Pb ratios, with little apparent latitudinal trend. To constrain the temporal evolution of regional Pb pollution, a well-dated core from one of the sites, Lake CF8 on east-central Baffin Island, was analyzed geochemically at high stratigraphic resolution. A pronounced decrease in the (206)Pb/(207)Pb ratio occurs in sediments deposited between 1923 and the mid-1970s, likely reflecting alkyl-Pb additives derived from the combustion of fossil fuels at a global scale. A two-component mixing model indicates that 17-26% of the Pb in the labile fraction of sediments deposited in Lake CF8 between 2001 and 2005 is from anthropogenic input. A Pb-Pb co-isotopic plot ((206)Pb/(207)Pb vs.(208)Pb/(206)Pb ratios) of the Lake CF8 time series data indicates multiple possible sources of industrial Pb pollution. Despite widespread reductions in industrial Pb emissions since the 1970s, there is no evidence for attendant reductions of pollution Pb at Lake CF8. Enhanced scavenging from increased primary production as well as changing precipitation rates as climate warms may represent important factors that modulate Pb deposition to Lake CF8, and Arctic lakes elsewhere. PMID:19665172

  11. Accurate electron affinity of Pb and isotope shifts of binding energies of Pb(.).

    PubMed

    Chen, Xiaolin; Ning, Chuangang

    2016-08-28

    Lead (Pb) was the last element of the group IVA whose electron affinity had a low accuracy around 10 meV before the present work. This was due to the generic threshold photodetachment measurement that cannot extent well below 0.5 eV due to the light source limitation. In the present work, the electron affinity of Pb was determined to be 2877.33(13) cm(-1) or 0.356 743(16) eV for the isotope m = 208. The accuracy was improved by a factor of 500 with respect to the previous laser photodetachment electron spectroscopy. Moreover, remarkable isotope shifts of the binding energy of Pb(-) 6p(3) (4)S3/2 - Pb 6p(2) (3)P2 were observed for m = 206, 207, and 208. PMID:27586918

  12. A list of references on lead isotope geochemistry, 1967-1969 (with an addendum to the list through 1966)

    USGS Publications Warehouse

    Doe, Bruce R.

    1971-01-01

    This bibliography was constructed to be as complete as possible for terminal papers containing new data relative to the geochemical applications of: Common lead U-The-Pb isotopic dating PbPb210, Pb212, Pb214 No effort was made for completeness of: Annual reports, Yearbooks, etc. Review papers although many are included. Abstracts and theses are omitted.

  13. U-Pb geochronology and geochemistry of Zahedan and Shah Kuh plutons, southeast Iran: Implication for closure of the South Sistan suture zone

    NASA Astrophysics Data System (ADS)

    Mohammadi, Ali; Burg, Jean-Pierre; Bouilhol, Pierre; Ruh, Jonas

    2016-04-01

    We present U-Pb zircon crystallization ages combined with major and trace element analyses, Sr-Nd isotopes and zircon in-situ Hf isotope analyses of intermediate to granitic intrusions along the southern segment of the N-S trending Sistan suture zone in eastern Iran. The Zahedan and Shah-Kuh Eocene plutons consist in a series of granite-granodiorite-rhyolite with U-Pb zircon ages of 40.5-44.3 Ma and ca. 28.9-30.9 Ma. Isotope geochemistry and modeling suggest that 40.5-44.3 Ma plutons represent melts derived from the turbidites of the surrounding accretionary wedge. Melting of the wedge was induced by the intrusion of mantle magmas, with subsequent interaction between mantle- and turbiditic melts being responsible for the wide range of compositions. Most of the 28.9-30.9 Ma magmas were generated from mantle melting, with assimilation of the surrounding turbidites. The rare setting of within-wedge intrusions is attributed to mantle upwelling reaching wedge sediments at the inception of delamination processes, which signal the end of subduction-related deformational and thermal events in the Sistan suture zone.

  14. USE OF STABLE ISOTOPES IN ENVIRONMENTAL AND FORENSIC GEOCHEMISTRY STUDIES

    EPA Science Inventory

    Stable carbon and hydrogen isotopes have been used for many decades in the petroleum industry, but the development of combined gas chromatography-isotope ratio mass spectrometry (GCIRMS) has led to a virtual explosion in application of this technique not only in petroleum explora...

  15. LA-ICP MS zircon dating, whole-rock and Sr-Nd-Pb-O isotope geochemistry of the Camiboğazı pluton, Eastern Pontides, NE Turkey: Implications for lithospheric mantle and lower crustal sources in arc-related I-type magmatism

    NASA Astrophysics Data System (ADS)

    Kaygusuz, Abdullah; Arslan, Mehmet; Siebel, Wolfgang; Sipahi, Ferkan; İlbeyli, Nurdane; Temizel, İrfan

    2014-04-01

    Late Cretaceous I-type plutons are widespread in the Eastern Pontides, NE Turkey. The studied Camiboğazı pluton is a composite pluton consisting of diorite, tonalite, monzodiorite, monzonite, quartz monzonite, granite, and mafic microgranular enclaves (MMEs). Laser ablation ICP-MS U-Pb dating of zircon yielded crystallization ages of 76.21 ± 0.79 Ma, 75.65 ± 0.50 Ma, 75.04 ± 0.83 Ma, and 74.73 ± 0.86 Ma for diorite, monzodiorite, monzonite, and granite, respectively. The rocks of the pluton have I-type, high-K to shoshonitic and metaluminous character, displaying whole-rock geochemical features of arc-related granites. They are enriched in large-ion lithophile and light rare-earth elements, and depleted in high-field-strength elements. Major element variations can be attributed to fractionation of plagioclase, clinopyroxene, hornblende, and Fe-Ti oxides. The rocks show considerable variation in 87Sr/86Sr(i) (0.70498 to 0.70622), ɛNd(i) (- 2.79 to - 0.36), δ18O values (+ 6.3 to + 11.4) and Nd model ages (TDM) (0.81 Ga to 1.26 Ga). Besides, they have (206Pb/204Pb) = 18.44-19.09, (207Pb/204Pb) = 15.64-15.69, and (208Pb/204Pb) = 38.37-38.89. Although isotope signatures of the mafic microgranular enclaves (MMEs) (87Sr/86Sr(i) = 0.70551 to 0.70622; ɛNd(i) = - 2.9 to - 1.23; δ18O = + 8.3 to + 9.7) are largely similar to the host rocks, MMEs are characterized by relatively high Mg-numbers (32-36), low contents of SiO2 (52-56 wt.%) and low ASI (0.7-0.9). Estimated crystallization temperatures for the rocks of the pluton range from 735 ± 58 °C to 844 ± 24 °C and a shallow intrusion depth (< 10 km) is estimated from Al-in-hornblende thermobarometry. Whole-rock geochemical and isotopic data suggest magma generation by dehydration melting of an amphibolite-type lower crustal component with additional input of a subcontinental lithospheric mantle component. Furthermore, Sr-Nd isotope mixing model reveals ~ 30% to 40% lower crustal magma contribution to the mantle

  16. ISOTOPIC EVALUATION OF PB OCCURRENCES IN THE RIVERINE ECOSYSTEMS OF THE KANKAKEE WATERSHED, ILLINOIS-INDIANA.

    EPA Science Inventory

    Environmental background levels of Pb were measured in ponds, river waters, sediments, suspended sediments, rocks, and air particulates within the Kankakee watershed during the period of 1995 to 1999. Stable isotopic Pb distinguised airborne Pb and its incorporation into riverin...

  17. Stable isotope geochemistry of East African waters. [Abstract only

    SciTech Connect

    Sayer, M.D.; Cerling, T.E.; Bowman, J.R.

    1983-03-01

    Lakes and Rivers in East Africa have varied stable isotopic compositions. Lakes exhibit enriched delta13-C values (-2 to +5%), while their inflowing rivers show depleted values (-15 to -8%). Hot springs and standing pools of water have intermediate values. Some small lakes are extremely variable in delta18-0 or deltaD (+2 to +8% and +20 to +40%, respectively for Lake Naivasha), whereas larger lakes are relatively constant for long periods of time (+5.6 to 6.1 and +36 to 40, respectively for Lake Turkana). Isotopic values are unrelated to salinity for comparison between lakes. Stable isotopes also reveal the sources of hot spring discharges: the Kapedo hot springs probably originate from Maralel and not from Lake Baringo as local legend has it; the hot springs north of Lake Naivasha are of meteoric origin while those to the south of Lake Naivasha have similar isotopic compositions to Lake Naivasha.

  18. Infrared spectroscopy and hydrogen isotope geochemistry of hydrous silicate glasses. Progress report

    SciTech Connect

    Epstein, S.; Stolper, E.

    1992-03-01

    The focus of this project is the combined appication of infrared spectroscopy and stable isotope geochemistry to the study of hydrogen-bearing species dissolved in silicate melts and glasses. We are conducting laboratory experiments aimed at determining the fractionation of D and H between melt species (OH and H{sub 2}O) and hydrous vapor and the diffusivities of these species in glasses and melts. Knowledge of these parameters is critical to understanding the behavior of hydrogen isotopes during igneous processes and hydrothermal processes. These results also could be valuable in application of glass technology to development of nuclear waste disposal strategies.

  19. Clumped isotope geochemistry of mid-Cretaceous (Barremian-Aptian) rudist shells: paleoclimatic and paleoenvironmental implications

    NASA Astrophysics Data System (ADS)

    Huck, S.; Steuber, T.; Bernasconi, S.; Weissert, H.

    2012-04-01

    The Cretaceous period is generally considered to have been a time of climate warmth, but there is an ongoing dispute about the existence of Cretaceous cool episodes - including the short-termed installation of polar ice caps. The Late Barremian-Early Aptian represents a Cretaceous key interval in terms of paleoclimate and paleoceanography, as it provides evidence for (i) a cooler climate (Pucéat et al., 2003) and (ii) a considerable seasonality of sea surface temperatures (SSTs) at low latitudes (Steuber et al., 2005). The timing and significance of these cool episodes, however, are not well constrained. Recently published TEX86 data, in contrast to oxygen isotope paleotemperature estimates, now are in support of a climate scenario with equable hot (~30° C) tropical SSTs from the Early Cretaceous onwards. The aim of this project is to reconstruct the evolution of Barremian-Aptian sea-surface temperatures (SSTs) in the tropical Tethyan realm by use of a combined geochemical approach including oxygen isotope analysis and carbonate clumped-isotope thermometry. Paleotemperature proxies are based on the isotope geochemistry of low-Mg calcite of pristine rudist bivalve shells (Toucasia, Requienia) collected from different carbonate platform settings, including the Provence platform in SE France and the Adriatic Carbonate platform in Croatia. Carbonate clumped-isotope geochemistry deals with the state of ordering of rare isotopes in molecules, in particular with their tendency to form bonds with other rare isotopes (13C-18O) rather than with the most abundant ones. Carbonate clumped-isotope thermometry has been shown to allow for reconstructing (i) the temperature of carbonate mineral formation and calculating (ii) the isotopic composition of the water from which carbonate minerals were formed (by using the δ18O of the analysed carbonate sample). Our approach seeks to provide insights into possible biases in temperature estimates of different paleothermometers

  20. A study of REE and Pb, Sr and Nd isotopes in garnet-lherzolite xenoliths from Mingxi, Fujian Province

    USGS Publications Warehouse

    Wankang, H.; Junwen, W.; Basu, A.R.; Tatsumoto, M.

    1993-01-01

    The REE and Pb, Sr, Nd isotopes in three xenoliths from limburgite and scoria-breccias, including spinel-lherzolite, spinel-garnet-lherzolite and phlogopite-gamet-lherzolite, were analysed. The REE contents of the xenoliths are 1.3 to 3.3 times those of the chondrites with their REE patterns characterized by weak LREE depletion. The143Nd/144Nd values of whole rocks and minerals range from 0.51306 to 0.51345 with ??Nd=+ 8.2- +15.8,206Pb/204 Pb < 18.673, and207Pb/204Pb < 15.574. All this goes to show that the upper mantle in Mingxi at the depth of 67-82 km is a depleted mantle of MORB type, with87Sr/86 Sr ratios 0.70237-0.70390. In Nd-Sr diagram the data points of whole rocks are all out of the mantle array, implying that the xenoliths from Mingxi have more radiogenic Sr isotopes than those of the mantle array. ?? 1993 Institute of Geochemistry, Chinese Academy of Sciences.

  1. Isotope geochemistry of the Amazon Basin: A reconnaissance

    NASA Astrophysics Data System (ADS)

    Longinelli, A.; Edmond, J. M.

    1983-04-01

    On the transects of the Amazon River made by the Alpha Helix in 1976 and 1977, an extensive suite of samples was collected for isotopic analyses. The water isotopes (18O/16O, D/H) were determined in atmospheric water vapour and in river, rain, and leaf waters. 13C/12C ratios were measured in the dissolved and atmospheric CO2. Determinations were made of 34S/32S and oxygen isotopes in dissolved sulphate. The effect of `continentality' on the water isotopes is minor reflecting the large scale recycling by evapotranspiration from the huge area of forest within the basin. Variations in the isotopic abundances between 1976 (June-July, dry season) and 1977 (May-June, end of wet season) are consistent with the changes in meteorological conditions. The isotopic composition of the CO2, both atmospheric and dissolved, is dominated by biological effects. In 1976 the dissolved CO2 showed downstream variations from -14‰ at Iquitos in Peru to -22‰ in the lower reaches. In 1977, no systematic trend was apparent, the data ranging around -19‰. The values for atmospheric CO2 decrease inland from marine values at the mouth to around -15‰ at Manaus. During the dry season (1976) the values in the interior, western basin were homogeneous at -20‰. In the wet season there were considerable variations reflecting atmospheric instabilities with the average value being about -13‰. The sulphur isotopic composition of the dissolved sulphate is remarkably uniform at around 7‰. In 1977 the 18O values in the sulphate decreased systematically downstream from 8‰ in Peru to 3‰ at the mouth, consistent with a progressive, redox-mediated exchange with water and dissolved oxygen. In 1977 the values increased to over 11‰, apparently indicating exchange with a highly fractionated reservoir of dissolved oxygen perhaps in the semireducing environment of the flood plain lakes.

  2. Geological, rare earth elemental and isotopic constraints on the origin of the Banbanqiao Zn-Pb deposit, southwest China

    NASA Astrophysics Data System (ADS)

    Li, Bo; Zhou, Jia-Xi; Huang, Zhi-Long; Yan, Zai-Fei; Bao, Guang-Ping; Sun, Hai-Rui

    2015-11-01

    elemental and isotopic data suggest that the REE, C and S in the ore-forming fluids of the Banbanqiao deposit were mainly originated from the carbonate host rocks, while the Pb and O were primarily derived from radiogenic Pb- and 18O-depleted sources, which are most likely to be the underlying Proterozoic basement rocks. Studies on the geology, rare earth elements and isotope geochemistry indicate that the Banbanqiao deposit is a carbonate-hosted, stratiform, anticline-controlled, epigenetic and high grade Zn-Pb deposit formed by elemental compositions of mixed origin, and is a typical SYG-type deposit in the western Yangtze Block, southwest China.

  3. Oxygen isotope geochemistry of The Geysers reservoir rocks, California

    SciTech Connect

    Gunderson, Richard P.; Moore, Joseph N.

    1994-01-20

    Whole-rock oxygen isotopic compositions of Late Mesozoic graywacke, the dominant host rock at The Geysers, record evidence of a large liquid-dominated hydrothermal system that extended beyond the limits of the present steam reservoir. The graywackes show vertical and lateral isotopic variations that resulted from gradients in temperature, permeability, and fluid composition during this early liquid-dominated system. All of these effects are interpreted to have resulted from the emplacement of the granitic "felsite" intrusion 1-2 million years ago. The {delta}{sup 18}O values of the graywacke are strongly zoned around a northwest-southeast trending low located near the center of and similar in shape to the present steam system. Vertical isotopic gradients show a close relationship to the felsite intrusion. The {delta}{sup 18}O values of the graywacke decrease from approximately 15 per mil near the surface to 4-7 per mil 300 to 600 m above the intrusive contact. The {delta}{sup 18}O values then increase downward to 8-10 per mil at the felsite contact, thereafter remaining nearly constant within the intrusion itself. The large downward decrease in {delta}{sup 18}O values are interpreted to be controlled by variations in temperature during the intrusive event, ranging from 150{degree}C near the surface to about 425{degree}C near the intrusive contact. The upswing in {delta}{sup 18}O values near the intrusive contact appears to have been caused by lower rock permeability and/or heavier fluid isotopic composition there. Lateral variations in the isotopic distributions suggests that the effects of temperature were further modified by variations in rock permeability and/or fluid-isotopic composition. Time-integrated water:rock ratios are thought to have been highest within the central isotopic low where the greatest isotopic depletions are observed. We suggest that this region of the field was an area of high permeability within the main upflow zone of the liquid

  4. Identifying Nutrient Sources to Lake Erie Using Isotope Geochemistry

    NASA Astrophysics Data System (ADS)

    Elsbury, K.; Paytan, A.

    2006-12-01

    Large areas of Lake Erie's hypolimnon continue to undergo seasonally hypoxic conditions, despite extensive efforts over the past 30 years to reduce phosphorus loads from known sources. The oxygen isotopic composition of dissolved phosphate found in lake waters can be used to identify the nutrient source or sources responsible for rising phosphate concentrations contributing to eutrophication and hypoxia. Isotope data from the West and Central Basins of Lake Erie and from seven key tributaries collected during August of 2005, June of 2006, and October of 2006 give a seasonal overview of phosphate sources to Lake Erie.

  5. A Pb isotopic resolution to the Martian meteorite age paradox

    NASA Astrophysics Data System (ADS)

    Bellucci, J. J.; Nemchin, A. A.; Whitehouse, M. J.; Snape, J. F.; Kielman, R. B.; Bland, P. A.; Benedix, G. K.

    2016-01-01

    Determining the chronology and quantifying various geochemical reservoirs on planetary bodies is fundamental to understanding planetary accretion, differentiation, and global mass transfer. The Pb isotope compositions of individual minerals in the Martian meteorite Chassigny have been measured by Secondary Ion Mass Spectrometry (SIMS). These measurements indicate that Chassigny has mixed with a Martian reservoir that evolved with a long-term 238U/204Pb (μ) value ˜ two times higher than those inferred from studies of all other Martian meteorites except 4.428 Ga clasts in NWA7533. Any significant mixing between this and an unradiogenic reservoir produces ambiguous trends in Pb isotope variation diagrams. The trend defined by our new Chassigny data can be used to calculate a crystallization age for Chassigny of 4.526 ± 0.027 Ga (2σ) that is clearly in error as it conflicts with all other isotope systems, which yield a widely accepted age of 1.39 Ga. Similar, trends have also been observed in the Shergottites and have been used to calculate a >4 Ga age or, alternatively, attributed to terrestrial contamination. Our new Chassigny data, however, argue that the radiogenic component is Martian, mixing occurred on the surface of Mars, and is therefore likely present in virtually every Martian meteorite. The presence of this radiogenic reservoir on Mars resolves the paradox between Pb isotope data and all other radiogenic isotope systems in Martian meteorites. Importantly, Chassigny and the Shergottites are likely derived from the northern hemisphere of Mars, while NWA 7533 originated from the Southern hemisphere, implying that the U-rich reservoir, which most likely represents some form of crust, must be widespread. The significant age difference between SNC meteorites and NWA 7533 is also consistent with an absence of tectonic recycling throughout Martian history.

  6. Geochemistry

    ERIC Educational Resources Information Center

    Brett, Robin; Hanshaw, Bruce B.

    1978-01-01

    The past year has seen the development of certain fields of geochemical research including Nd-Sm isotope studies of meteorites and ancient terrestrial rocks; the use of the consortium approach of assembling a multidisciplined team to tackle a problem; and the handling and analysis of small quantities of materials. (Author/MA)

  7. Isotope geochemistry of the Amazon Basin: A reconnaissance

    SciTech Connect

    Longinelli, A.; Edmond, J.M.

    1983-04-20

    On the transects of the Amazon River made by the Alpha Helix in 1976 and 1977, an extensive suite of samples was collected for isotopic analyses. The water isotopes (/sup 18/O//sup 16/O, D/H) were determined in atmospheric water vapour and in river, rain, and leaf waters. /sup 13/C//sup 12/C ratios were measured in the dissolved and atmospheric CO/sub 2/. Determinations were made of /sup 34/S//sup 32/S and oxygen isotopes in dissolved sulphate. The effect of 'continentality' on the water isotopes is minor reflecting the large scale recycling by evapotranspiration from the huge area of forest within the basin. Variations in the isotopic abundances between 1976 (June--July, dry season) and 1977 (May--June, end of wet season) are consistent with the changes in meteorological conditions. The isotopic composition of the CO/sub 2/, both atmospheric and dissolved, is dominated by biological effects. In 1976 the dissolved CO/sub 2/ showed downstream variations from -14X at Iquitos in Peru to -22X in the lower reaches. In 1977, no systematic trend was apparent, the data ranging around -19X. The values for atmospheric CO/sub 2/ decrease inland from marine values at the mouth to around -15X at Manaus. During the dry season (1976) the values in the interior, western basin were homogeneous at -20X. In the wet season there were considerable variations reflecting atmospheric instabilities with the average value being about -13X. The sulphur isotopic composition of the dissolved sulphate is remarkably uniform at around 7X. In 1977 the /sup 18/O values in the sulphate decreased systematically downstream from 8X in Peru to 3X at the mouth, consistent with a progressive redox-mediated exchange with water and dissolved oxygen. In 1977 the values increased to over 11X, apparently indicating exchange with a highly fractionated reservoir of dissolved oxygen perhaps in the semireducing environment of the flood plain lakes.

  8. New Carbonate Standard Reference Materials for Boron Isotope Geochemistry

    NASA Astrophysics Data System (ADS)

    Stewart, J.; Christopher, S. J.; Day, R. D.

    2015-12-01

    The isotopic composition of boron (δ11B) in marine carbonates is well established as a proxy for past ocean pH. Yet, before palaeoceanographic interpretation can be made, rigorous assessment of analytical uncertainty of δ11B data is required; particularly in light of recent interlaboratory comparison studies that reported significant measurement disagreement between laboratories [1]. Well characterised boron standard reference materials (SRMs) in a carbonate matrix are needed to assess the accuracy and precision of carbonate δ11B measurements throughout the entire procedural chemistry; from sample cleaning, to ionic separation of boron from the carbonate matrix, and final δ11B measurement by multi-collector inductively coupled plasma mass spectrometry. To date only two carbonate reference materials exist that have been value-assigned by the boron isotope measurement community [2]; JCp-1 (porites coral) and JCt-1 (Giant Clam) [3]. The National Institute of Standards and Technology (NIST) will supplement these existing standards with new solution based inorganic carbonate boron SRMs that replicate typical foraminiferal and coral B/Ca ratios and δ11B values. These new SRMs will not only ensure quality control of full procedural chemistry between laboratories, but have the added benefits of being both in abundant supply and free from any restrictions associated with shipment of biogenic samples derived from protected species. Here we present in-house δ11B measurements of these new boron carbonate SRM solutions. These preliminary data will feed into an interlaboratory comparison study to establish certified values for these new NIST SRMs. 1. Foster, G.L., et al., Chemical Geology, 2013. 358(0): p. 1-14. 2. Gutjahr, M., et al., Boron Isotope Intercomparison Project (BIIP): Development of a new carbonate standard for stable isotopic analyses. Geophysical Research Abstracts, EGU General Assembly 2014, 2014. 16(EGU2014-5028-1). 3. Inoue, M., et al., Geostandards and

  9. Iron isotope geochemistry in the Antarctic cryptoendolithic microbial ecosystem

    NASA Astrophysics Data System (ADS)

    Sun, H.

    2002-05-01

    The stable isotope composition of iron is a potentially powerful tracer of biogeochemical cycles because iron is ubiquitous, it is required by all organisms, and it is resistant to alterations during diagenesis. Here we report evidence of biological iron isotope fractionation in the weathering process of sandstone in McMurdo Dry Valleys, Antarctica, caused by the cryptoendolithic lichen-dominated microbial community that live below the rock surface. The fungi secrete oxalic acid, which under the sunlight reduces and dissolves the iron in the colonized zone. The mobilized iron diffuses to the rock surface and the rock interior below the organisms where it is re-oxidized. This leaching process is shown to prefer lighter isotopes of iron, leaving the colonized layer enriched in del 56Fe by as much 0.8 per mil. Had endolithic microorganisms occurred on Mars as commonly believed, they might have left similar iron biosignatures, well preserved in rocks because of the absence of subsequent aqueous activities.

  10. Long-Term Performance of Pb Isotopic Analysis by TIMS with 202Pb-205Pb Double Spike

    NASA Astrophysics Data System (ADS)

    Amelin, Y.; Connelly, J. N.

    2008-05-01

    The 202Pb-205Pb-233U-235U spike (Pb DS), prepared at the Geological Survey of Canada in 2005 [1], and the 202Pb-205Pb-235U spike, prepared at the Department of Geosciences, University of Oslo [2], have been used for more than two years. Both spikes are routinely used for TIMS analysis of Pb with internal fractionation correction for U-Pb dating of various rocks and minerals, including dating perovskite [2] and meteorites and their components [1, 4-7]. A few hundred standard and sample Pb DS analyses were acquired with these two spikes using Triton TI mass spectrometers at the Geological Survey of Canada, US Geological Survey and the Australian National University, a Finnigan-MAT 261 mass spectrometer at The University of Texas at Austin and a Finnigan-MAT 262 mass spectrometer at the University of Oslo. All analyses were performed using high efficiency silicic acid emitter [8] and a static multicollector mode if the samples were sufficiently large to produce an ion beam greater than ca. 2-5×10-14 A on 206Pb and 207Pb. These data allow us to evaluate long - term performance of the Pb DS procedure for sub-nanogram samples of Pb. The performance of this procedure is evaluated on the basis of the long-term reproducibility of analyses of isotopic standards, and from improving quality of linear fits in Pb-Pb isochron diagrams (and, hence, improved precision of ages) compared to the same data reduced using external normalization. The data for 0.3 ng loads of SRM-981, analyzed with the batches of samples in 2006 and 2007 at the GSC, yield the mean 204Pb/206Pb of 0.05904±0.00013 (0.226% 2σ), #207Pb/206Pb of 0.91483±0.00018 (0.020% 2σ)), and 208Pb/206Pb of 2.16771±0.00054 (0.025% 2σ)). These values and errors are similar to those reported in [1] for the loads of the same size, and to the values obtained for similar loads at the USGS and at ANU over shorter periods of time. The precision and reproducibility of sample analysis and standard analyses is similar, and

  11. Dynamic variability of dissolved Pb and Pb isotope composition from the U.S. North Atlantic GEOTRACES transect

    NASA Astrophysics Data System (ADS)

    Noble, Abigail E.; Echegoyen-Sanz, Yolanda; Boyle, Edward A.; Ohnemus, Daniel C.; Lam, Phoebe J.; Kayser, Rick; Reuer, Matt; Wu, Jingfeng; Smethie, William

    2015-06-01

    This study presents dissolved Pb concentration and isotopic composition distributions from GEOTRACES GA03, the U.S. North Atlantic Transect. Pb in the ocean is primarily derived from anthropogenic sources and Pb fluxes into the North Atlantic Ocean have been steadily decreasing following the phase-out of alkyl leaded gasoline usage in North America and Europe between 1975 and 1995. A compilation of dissolved Pb profiles from three stations occupied repeatedly during the last three decades reveals a dramatic decrease in concentrations within the surface layers and the thermocline maxima, although elevated concentrations greater than 60 pmol/kg are still observed in the center of the North Atlantic gyre where ventilation timescales are longer than at the western boundary. The evolution of stable Pb isotopes at these stations shows a shift from dominantly North American-like composition in surface waters in the early 1980s towards a more European-like composition in later years. The most recent shallow signatures at the Bermuda Atlantic Time Series station (BATS) show an even more recent trend returning to higher 206Pb/207Pb ratios after the completed phase-out of leaded gasoline in Europe, presumably because recently deposited Pb is more strongly influenced by industrial and incineration Pb than by residual alkyl leaded gasoline utilization. In surface waters, trends toward a more prominent European influence are also found in the middle of the basin and toward the European coast, coincident with higher concentrations of surface dissolved Pb. Scavenging of anthropogenic Pb is observed within the TAG hydrothermal plume, and it is unclear if there is any significant contribution to deep water by basaltic Pb leached by hydrothermal fluids. In the upper water column, many stations along the transect show Pb concentration maxima at ~100 m depth, coincident with a low 206Pb/207Pb isotopic signature that is typical of European emission sources. Although Pb ores from the

  12. Sulfur isotope and porewater geochemistry of Florida escarpment seep sediments

    USGS Publications Warehouse

    Chanton, J.P.; Martens, C.S.; Paull, C.K.; Coston, J.A.

    1993-01-01

    Distributions of porewater constituents, SO4=, NH4+, Cl-, ???CO2, and H2S, solid phase iron, and sulfur concentrations, and the sulfur isotopic composition of dissolved and solid phases were investigated in sediments from abyssal seeps at the base of the Florida escarpment. Despite the apparent similarity of seep sediment porewater chemistry to that of typical marine sediments undergoing early diagenesis, relationships between chemical distributions and isotopic measurements revealed that the distribution of pore fluid constituents was dominated by processes occurring within the platform rather than by in situ microbial processes. Ammonium and sulfate concentrations were linearly correlated with chloride concentrations, indicating that variations in porewater chemistry were controlled by the admixture of seawater and a sulfate depleted brine with a chlorinity of 27.5 ?? 1.9%. and 2.2 ?? 1.3 mM ammonium concentration. At sites dominated by seepage, dissolved sulfate isotopic composition remained near seawater values despite depletion in porewater concentrations. Porewater ???CO2 concentrations were found to be elevated relative to seawater, but not to the extent predicted from the observed sulfate depletion. Sediment solid phase sulfur was predominantly pyrite, at concentrations as high as 20% S by weight. In contrast to typical marine deposits, pyrite concentrations were not related to the quantity of sedimentary organic matter. Pyrite ??34S values ranged from -29%. to + 21%. (CDT). However, only positive ??34S values were observed at sites associated with high pyrite concentrations. Isotopically heavy pyrite was observed at sites with porewater sulfate of seawater-like isotopic composition. Isotopically light pyrite was associated with sites where porewater sulfate exhibited ??34S values greater than those in seawater, indicating the activity of in situ microbial sulfate reduction. Thus, dual sulfide sources are suggested to explain the range in sediment pyrite

  13. Coupled U-Pb isotopic studies and synchrotron x-ray microbeam analysis of geologic systems

    NASA Astrophysics Data System (ADS)

    Lanzirotti, A.; Sutton, S.; Rasbury, T.; Becker, M.; Hanson, G. N.

    2001-12-01

    Analytical advances in thermal ionization mass spectrometry now allow for precise measurement of U and Pb abundance and Pb isotopic composition in minerals where U and Pb may only amount to a few picograms by weight. High precision analysis at such low levels means that a much wider variety of mineral species can be considered as potentially useful U-Pb geochronometers. However, evaluating the potential use of these minerals for high-precision dating requires understanding the environmental and crystal chemistry of the U and Pb being analyzed in these minerals. Advances in the production of microfocused synchrotron x-ray beams allow more unambiguous evaluation of uranium partitioning and speciation in these geochemical systems. The microbeam capabilities of these instruments, such as the X26A beamline at the NSLS, allow for near simultaneous evaluation of major and trace elements using synchrotron XRF, elemental speciation and coordination using x-ray absorption spectroscopy (XANES and EXAFS), and mineralogy using micro-XRD at resolutions of 10 microns or less. Additionally, the synchrotron hard x-ray microprobe allows for non-destructive analysis of the same hand specimens or thin sections from which samples are separated for isotopic analysis with a detection sensitivity often of 1 ppm or better. Some examples illustrate how these combined studies can help characterize the U and Pb geochemistry of the host environments in which these minerals formed. Andradite garnets from the Grand Canyon Supergroup (1178+/-26 Ma) are shown to be compositionally homogeneous in U abundance (10-25 ppm), with U as a 4+ species. Fossilized Jurassic fish coprolites from the Shuttle Meadow Fm. (ca. 200 Ma) show that although they are dominated by apatite the highest U abundance is consistent with adsorption onto organic C at the time of sedimentation. Examples of U analyzed from a number of terrestrial carbonates shows that U can be incorporated as both 4+ and 6+ species and may also

  14. Srsbnd Ndsbnd Pb isotopic compositions of Early Cretaceous granitoids from the Dabie orogen: Constraints on the recycled lower continental crust

    NASA Astrophysics Data System (ADS)

    He, Yongsheng; Li, Shuguang; Hoefs, Jochen; Kleinhanns, Ilka C.

    2013-01-01

    In order to characterize the recycled lower continental crust (LCC) in the Dabie orogen, 17 Early Cretaceous low-Mg adakitic (LMA) and 9 normal (non-adakitic) granitoids have been investigated for Srsbnd Ndsbnd Pb isotopes. Combined with literature data, LMA have low ƐNd(t) (- 27.8 to - 14.7) and 206Pb/204Pb(i) (15.69-17.16) and low to moderately high 87Sr/86Sr(i) (0.7066 to 0.7087) ratios. Normal granitoids yield isotope ratios similar to adakitic rocks, except a few with 87Sr/86Sr (i) up to 0.7105. Dabie LMA define a linear trend parallel to the North Hemisphere Reference Line (NHRL) in a 208Pb/204Pb(i)- 206Pb/204Pb(i) diagram. For a given 206Pb/204Pb(i), the 208Pb/204Pb(i) or ∆8/4 (152-217) of Dabie LMA are close to the majority of UHP gneisses and the Neoproterozoic mafic rocks from the northern margin of the South China Block (SCB), but significantly higher than adakitic rocks from the North China Block (∆8/4 < 150). Considering the commonly present Neoproterozoic inherited zircons, we suggest that the LMA in the Dabie orogen are derived from a thickened LCC that could be dominantly composed of ancient SCB lower crust. The Srsbnd Ndsbnd Pb isotopic composition of LMA are similar to those of Post-Collisional Mafic Igneous rocks (PCMI) from the Dabie orogen, but different to exhumed UHP rocks. The Srsbnd Ndsbnd Pb isotopic system of the mantle source of the PCMI could be enriched in components dominantly from delaminated LCC of the Dabie orogen instead of deeply subducted continental crust, which is in contrast to O- and C-isotope data by [Zhao, Z.F., Zheng, Y.F., Wei, C.S., Wu, Y.B., Chen, F.K., and Jahn, B.M., 2005. Zircon Usbnd Pb age, element and Csbnd O isotope geochemistry of post-collisional mafic-ultramafic rocks from the Dabie orogen in east-central China. Lithos 83(1-2), 1-28; Dai, L.Q., Zhao, Z.F., Zheng, Y.F., Li, Q.L., Yang, Y.H., and Dai, M.N., 2011. Zircon Hfsbnd O isotope evidence for crust-mantle interaction during continental deep

  15. Biogeochemistry of a mesotrophic lake and it's carbon isotope geochemistry

    NASA Astrophysics Data System (ADS)

    Cheng, S.; Ehresman, W.; Sadurski, S. E.

    2010-12-01

    Crystal Lake, located in west-central Ohio, is the main lake of a series of 4 interconnected lakes. The location and orientation indicate that they are most likely moulin-induced glacial lakes. Crystal Lake is about 5 hectares (12.5 acres). The maximum depth and mean depth are about 11.9 meters and 3.8 meters, respectively. As a result of this high depth-to-surface area ratio, it creates a strong thermal stratification during warm season. The lake was classified as eutrophic lake. However, the water quality has improved in the past decades. The chlorophyll in the epillimnion and upper metalimlion is about 4 μg/l and the Secchi disk depth is about 3.0 meters (10 feet). It is therefore reclassified as mesotrophic lake. Dissolved oxygen maximum (15.6 ppm) and pH peak (8.6) existed at 4.1 meter on August 16, 2010. At around 7.3 meter, where redox potential reading shows a sudden change from oxidizing to reducing , a ~half meter layer of dense purple sulfur bacteria coincides with turbidity, chlorophyll, and sulfate maxima. The chemical depth profiles are a result of thermal stratification, oxygenic photosynthesis by algae, non-oxygenic photosynthesis by purple sulfur bacteria, and respiration in the hypolimnion. Precipitation of calcium carbonate in the epilimnion and metalimnion is coupled by it’s dissolution in the hypolimnion. The purpose of the current project is to present extensive background study to form the framework for quantifying the carbon isotope evolution with multiple reaction pathways. Carbon isotope composition of dissolved inorganic carbon is being analyzed. Wigley-Plummer-Pearson mass transfer model will be used for the quantification of carbon isotope reaction pathways.

  16. Lithium isotope geochemistry and origin of Canadian shield brines.

    PubMed

    Bottomley, D J; Chan, L H; Katz, A; Starinsky, A; Clark, I D

    2003-01-01

    Hypersaline calcium/chloride shield brines are ubiquitous in Canada and areas of northern Europe. The major questions relating to these fluids are the origin of the solutes and the concentration mechanism that led to their extreme salinity. Many chemical and isotopic tracers are used to solve these questions. For example, lithium isotope systematics have been used recently to support a marine origin for the Yellowknife shield brine (Northwest Territories). While having important chemical similarities to the Yellowknife brine, shield brines from the Sudbury/Elliot Lake (Ontario) and Thompson/Snow Lake (Manitoba) regions, which are the focus of this study, exhibit contrasting lithium behavior. Brine from the Sudbury Victor mine has lithium concentrations that closely follow the sea water lithium-bromine concentration trajectory, as well as delta6Li values of approximately -28/1000. This indicates that the lithium in this brine is predominantly marine in origin with a relatively minor component of crustal lithium leached from the host rocks. In contrast, the Thompson/Snow Lake brine has anomalously low lithium concentrations, indicating that it has largely been removed from solution by alteration minerals. Furthermore, brine and nonbrine mine waters at the Thompson mine have large delta6Li variations of approximately 30/1000, which primarily reflects mixing between deep brine with delta6Li of -35 +/- 2/1000 and near surface mine water that has derived higher delta6Li values through interactions with their host rocks. The contrary behavior of lithium in these two brines shows that, in systems where it has behaved conservatively, lithium isotopes can distinguish brines derived from marine sources. PMID:14649868

  17. Mafic dykes intrusive into Pre-Cambrian rocks of the São Luís cratonic fragment and Gurupi Belt (Parnaíba Province), north-northeastern Brazil: Geochemistry, Sr-Nd-Pb-O isotopes, 40Ar/39Ar geochronology, and relationships to CAMP magmatism

    NASA Astrophysics Data System (ADS)

    Klein, Evandro L.; Angélica, Rômulo S.; Harris, Chris; Jourdan, Fred; Babinski, Marly

    2013-07-01

    Dykes of diabase and microgabbro intruded into Pre-Cambrian rocks of the São Luís cratonic fragment and Gurupi Belt, which are tectonic and erosive windows of the Parnaíba Basin in north-northeastern Brazil. Ar-Ar ages were determined, and major, trace element, and Nd-Sr-Pb-O isotopic compositions of these dykes were measured to provide insights into their age, and into the nature of their mantle sources and petrogenetic processes. The data have also been used to compare the chemical and isotopic signatures of the dykes with those of the Central Atlantic Magmatic Province (CAMP). Four chemical groups of mafic dykes have been identified. These comprise two subtypes of high-Ti rocks (i) HTi-1 (TiO2 < 2.3 wt.%; SiO2 > 47 wt.%), (ii) HTi-2 (TiO2 > 2.7 wt.%; SiO2 > 47 wt.%), in addition to (iii) evolved high-Ti (TiO2 > 4 wt.%; SiO2 of ~ 46 wt.%) and (iv) low-Si (TiO2 > 2.2 wt.%; SiO2 < 45 wt.%) rocks. 40Ar/39Ar geochronology of plagioclase returned ages of 201 ± 4 Ma and 193 ± 10 Ma for the HTi-2 subtype, and of 201 ± 2 Ma and 207 ± 9 Ma for the evolved high-Ti group. The HTi-1 and low-Si groups presented highly disturbed age spectra, and did not allow the definition of their emplacement ages. The Argon data indicate an age > 200 Ma for the low-Si group and are dubious with respect to the age of theHTi-1 subtype, if coeval with (i.e., ~ 200 Ma), or older than, the HTi-2 and evolved high-Ti types. All groups present δ18O values of pyroxene that are compatible with uncontaminated mantle-derived magmas. The HTi-1 subtype (average 143Nd/144Nd200 = 0.512644; 87Sr/86Sr200 = 0.7035; 206Pb/204Pb of 17.86) shows the less enriched and less fractionated (more primitive) trace element distribution of all groups. The HTi-2 subtype shows enriched trace element pattern and depleted Nd-Sr signature (143Nd/144Nd200 = 0.512610; 87Sr/86Sr200 = 0.7037) and average 206Pb/204Pb ratios of 17.23. The evolved high-Ti chemical group shows average ratios of 143Nd/144Nd200 = 0.512558, 87Sr

  18. Oxygen isotope geochemistry of back-arc lavas

    NASA Astrophysics Data System (ADS)

    Bonifacie, M.; Eiler, J. M.; Stolper, E. M.; Langmuir, C. H.

    2007-12-01

    Oxygen isotope ratios of arc-related magmas can constrain the amount and nature of slab-derived components contributing to their mantle sources because: (i) most geological solids and fluids contain similar concentration of oxygen; and (ii) possible slab components (fluids, melts or rocks from sedimentary, mafic or ultramafic parts of the lithosphere) differ from one another in δ18O values and these distinctive oxygen-isotope compositions can be preserved in deeply subducted materials. Previous laser fluorination oxygen isotope data on back-arc basin basalts (BABB) show slightly but consistently elevated δ18O values (from 5.5 to 6.1 ‰ [1-3]) with respect to mid-ocean ridge basalts or MORB (δ18O = 5.5 ± 0.2 ‰ [4]). The subtle elevations in δ18O characteristic of BABB are generally associated with 'enriched' radiogenic isotope compositions (e.g., high 87Sr/86Sr) and high apparent degrees of melting of their peridotitic sources that may reflect fluxed melting of the mantle by fluids and/or hydrous melts released from subducted oceanic lithosphere [1-3]. These trends could be used to precisely define the sources and amounts of slab- derived components delivered to the back arc mantle. However, two issues demand that this problem be better constrained through further studies. First, the subtle difference in δ18O between MORB and BABB involves comparison of data generated in different laboratories that may not share common standardization; this difference must be demonstrated within a single laboratory using a common set of standards. Second, the trends of δ18O vs. other geochemical indices observed in BABB lavas are based on samples from several relatively small and unrelated suites of lavas. These trends must be documented through study of one or more relatively large and diverse suites of closely related lavas. We are performing new laser-fluorination oxygen isotope measurements of a comprehensive suite of fresh back-arc glasses collected along the Eastern

  19. Oxygen isotopic composition and U-Pb discordance in zircon

    USGS Publications Warehouse

    Booth, A.L.; Kolodny, Y.; Chamberlain, C.P.; McWilliams, M.; Schmitt, A.K.; Wooden, J.

    2005-01-01

    We have investigated U-Pb discordance and oxygen isotopic composition of zircon using high-spatial resolution ??18O measurement by ion microprobe. ??18O in both concordant and discordant zircon grains provides an indication of the relationship between fluid interaction and discordance. Our results suggest that three characteristics of zircon are interrelated: (1) U-Pb systematics and concomitant age discordance, (2) ??18O and the water-rock interactions implied therein, and (3) zircon texture, as revealed by cathodoluminescence and BSE imaging. A key observation is that U-Pb-disturbed zircons are often also variably depleted in 18O, but the relationship between discordance and ??18O is not systematic. ??18O values of discordant zircons are generally lighter but irregular in their distribution. Textural differences between zircon grains can be correlated with both U-Pb discordance and ??18O. Discordant grains exhibit either a recrystallized, fractured, or strongly zoned CL texture, and are characteristic of 18O depletion. We interpret this to be a result of metamictization, leading to destruction of the zircon lattice and an increased susceptibility to lead loss. Conversely, grains that are concordant have less-expressed zoning and a smoother CL texture and are enriched in 18O. From this it is apparent that various stages of water-rock interaction, as evidenced by systematic variations in ??18O, leave their imprint on both the texture and U-Pb systematics of zircon. Copyright ?? 2005 Elsevier Ltd.

  20. Integrated modelling of enhanced in situ biodenitrification in a fractured aquifer: biogeochemistry and isotope geochemistry

    NASA Astrophysics Data System (ADS)

    Rodríguez-Escales, Paula; Folch, Albert; van Breukelen, Boris M.; Vidal-Gavilan, Georgina; Soler, Albert

    2014-05-01

    Enhanced in-situ biodenitrification is a feasible technology to recovery groundwater polluted by nitrates and achieves drinking water standards. Under optimum conditions, nitrate is reduced by autochthonous bacteria trough different reactions until arrive to harmless dinitrogen gas. Isotopic fractionation monitoring in field applications allows knowing the exact degree and the real scope of this technology. Using the Rayleigh equation the change in the isotope ratio of the nitrate molecule (δ15N-NO3-, δ18O-NO3-) is related to the fraction of molecules remaining as a result of biodenitrification. However, Rayleigh application at field scale is sometimes limited due to other processes involved during groundwater flow such as dispersion or adsorption and geological media heterogeneities that interferes in concentration values. Then, include isotope fractionation processes in reactive transport models is a useful tool to interpret and predict data from in-situ biodenitrification. We developed a reactive transport model of enhanced in situ application at field scale in a fractured aquifer that considers biogeochemical processes as well as isotope fractionation to enable better monitoring and management of this technology. Processes considered were: microbiological- exogenous and endogenous nitrate and sulfate respiration coupled with microbial growth and decay, geochemical reactions (precipitation of calcite) and isotopic fractionation (δ15N-NO3-; δ18O- NO3- and carbon isotope network). The 2-D simulations at field scale were developed using PHAST code. Modeling of nitrate isotope geochemistry has allowed determining the extent of biodenitrification in model domain. We have quantified which is the importance in decreasing of nitrate concentrations due to biodegradation (percentage of biodegradation, 'B%') and due to dilution process (percentage of dilution, 'D%'). On the other hand, the stable carbon isotope geochemistry has been modeled. We have considered the

  1. The Zoo of Mantle Components Seen Through the Lens of Stable Isotope Geochemistry

    NASA Astrophysics Data System (ADS)

    Eiler, J. M.

    2005-12-01

    Solid earth geochemistry has imposed order on the radiogenic isotope diversity exhibited by basalts and mantle rocks, but struggles to determine when this diversity reflects crustal recycling vs. intra-mantle differentiation. Stable isotope geochemistry can help make such distinctions because surface processes lead to large isotopic variations whereas mantle processes are imagined not to. Subducted components of the sources of arc lavas lead to obvious 'signals' in isotopic compositions of H, Li, B, and O, suggesting similar signals should identify subducted components in MORB and intraplate lavas. The reality is a hash of positive, negative and enigmatic results: 18O-enrichments are clearly associated with the 'EM'-type ocean-island-basalts, re-enforcing long-held hypotheses that these lavas sample sources rich in recycled sediment and/or upper oceanic crust. Similar observations suggest recycled crust contributes to 'background' geochemical variations in the sources of normal MORBs. On the other hand, the ocean-island-basalt end member often associated with the largest amounts of subducted crust ('HIMU') is essentially invariant and normal in oxygen isotope composition, lending weight to heretical hypotheses that this component is a consequence of intramantle differentiation. The Li and H isotope systems are proving to have much in common: Subducted materials are 7Li and D enriched relative to the mantle and subduction-zone metamorphism likely drives some deeply subducted rocks to very 7Li and D-depleted compositions. Despite this great diversity in subducted components, Li and H isotopic compositions of most MORBs and intraplate lavas vary little. The exceptions, while real, would not have been predicted based on their radiogenic and O isotope and trace element compositions. Mantle xenoliths exhibit highly variable Li and H isotope compositions, including values lower in 7Li and D than any fresh basalt. While both of these isotopic systems suffer from the

  2. Mineralogy and stable isotope geochemistry of hydrothermally altered oceanic rocks

    USGS Publications Warehouse

    Stakes, D.S.; O'Neil, J.R.

    1982-01-01

    Mineralogical and isotopic variations observed in altered glassy and crystalline rocks from the East Pacific Rise and the Mid-Atlantic Ridge provide information about the temperatures of alteration and seawater/rock ratios for various hydrothermal regimes within the oceanic crust. A systematic increase in alteration temperature is evident for the glassy rocks in the sequence: (1) nontronite and celadonite vesicle fillings (35??C), (2) saponite-rich pillow breccias (130-170??C), (3) calcite-rich greenstone breccias and epidote-rich greenstone (200-350??C). These results include the highest temperatures thus far reported for saponite formation. The "seawater-dominated" hydrothermal alteration process that formed the saponite-rich pillow breccias is characterized by high water/rock ratios (>50:1), low to moderate temperatures, a seawater origin of most of the carbon in vein calcites (??13 C ??? 0) and the predominance of Fe-rich saponite and calcite as secondary phases. Greenstones (chlorite-quartz-epidote) and greenstone breccias (chlorite-quartz-albite-calcite) are altered in a "rock-dominated" system with lower water/rock ratios (50:1 to < 1:1), higher temperatures, and vein calcites with carbon that is principally of magmatic origin (??13 C ??? -4). The crystalline rocks (diabase, gabrro, and metagabbro) are affected to varying degrees by pervasive high-temperature seawater interactions that commence soon after solidification, producing varying proportions of fine-grained secondary minerals including talc, smectite, chlorite, vermiculite, actinolite, and sodic plagioclase. Hydrothermal solutions, derived from alteration of the crystalline rocks, are of the appropriate temperature and isotopic composition to alter the overlying glassy rocks to the observed mineralogies as well as being the source of metal-rich deposits associated with the oceanic spreading centers. ?? 1982.

  3. Discrimination of the Cigarettes Geographical Origin by DRC-ICP-MS Measurements of Pb Isotope Compositions

    NASA Astrophysics Data System (ADS)

    Guo, W.; Hu, S.; Jin, L.

    2014-12-01

    Trace Pb are taken up with the same isotopic ratios as is present in the source soil, and the isotopic composition of Pb could used to reflect these sources and provide powerful indicators of the geographic origin of agriculture products derived from vegetative matter. We developed a simple and high throughput method, which based on DRC-ICP-MS for determination of Pb isotope ratios for discriminating the geographic origin of cigarettes. After acid digestion procedure, the cigarette digested solutions were directly analyzed by ICP-QMS with a DRC pressurized by the non-reactive gas Ne. In the DRC, Ne molecules collision with Pb ions and improves Pb isotope ratios precision 3-fold, which may be due to the collisional dampling smoothes out the ion beam fluctuations. Under the optimum DRC rejection parameter Q (RPq = 0.45), the main matrix components (K, Na, Ca, Mg, Al, Fe etc.) originating from cigarettes were filtered out. Mass discrimination of 208Pb/206Pb ratio in Ne DRC mode increased 0.3% compared to the standard mode, the mass bias due to the in-cell Ne gas collision can be accurately corrected by NIST 981 Pb isotope standard. This method was verified by a tobacco reference material CTV-OTL-2. Results of 208Pb/206Pb and 207Pb/206Pb were 2.0848 ± 0.0028 (2δ) and 0.8452 ± 0.0011 (2δ) for CTA-VTL-2, which were agreed with the literature values (208Pb/206Pb = 2.0884 ± 0.0090 and 207Pb/206Pb = 0.8442 ± 0.0032). The precision of Pb isotope ratios (208Pb/206Pb and 207Pb/206Pb) for the cigarette samples are ranged from 0.01 to 0.08% (N = 5). It has sufficient precision to discriminate 91 different brand cigarettes originated from four different geographic regions (Shown in Fig).

  4. Petrogenesis and origin of modern Ethiopian rift basalts: Constraints from isotope and trace element geochemistry

    NASA Astrophysics Data System (ADS)

    Ayalew, D.; Jung, S.; Romer, R. L.; Kersten, F.; Pfänder, J. A.; Garbe-Schönberg, D.

    2016-08-01

    The source of continental rift-related basalts and their relation to rifting processes is a continuous matter of debate. We present major and trace element and Sr, Nd, Hf and Pb isotope data for axial rift basalts from eight volcanic centres (Ayelu, Hertali, Dofan, Fantale, Kone, Bosetti and Gedemsa, from NE to SW) in Afar and Main Ethiopian Rift (MER) to assess their source regions and their genetic relationships. These lavas have geochemical characteristics, i.e., a peak at Ba, Nb and troughs at K and Rb in primitive mantle-normalised multielement diagrams, which are consistent with predominant melting of an amphibole-bearing lithospheric mantle. However, the isotopic compositions for these lavas are heterogeneous (87Sr/86Sr = 0.70354-0.70431, 143Nd/144Nd = 0.51280-0.51294, 176Hf/177Hf = 0.28301-0.28315, 206Pb/204Pb = 18.48-19.31, 207Pb/204Pb = 15.53-15.62, 208Pb/204Pb = 38.61-39.06) and require various mantle reservoirs with distinctive isotopic signatures. The range of isotopic compositions requires the involvement of three distinct source components from the asthenospheric and veined lithospheric mantle. Progressive rifting leads to lithosperic thinning and upwelling of hot asthenospheric mantle, which induces melting of the veined lithospheric mantle. The trace element characteristics of the lavas are dominated by the vein material, which has a higher trace element content than the surrounding mantle. The isotopic composition of the vein material, however, is not very different from the ambient mantle, giving rise of apparent uncoupling of trace element and isotope constraints for the melt source. The uprising basaltic liquids in part inherit a lithospheric trace element signature, while their isotopic compositions are mostly unaffected due to short residence times within the lithosphere in context with progressive rifting and lithospheric thinning. Thus, the geochemical and isotope data are consistent with a multi-component source prevailing beneath the Afar

  5. The Distribution and Behaviour of Pb-U-Th and Pb Isotopes in Mantle Minerals.

    NASA Astrophysics Data System (ADS)

    Cenki-Tok, B.; Burton, K. W.; Parkinson, I. J.; Mokadem, F.; Harvey, J.; Charlier, B. L.

    2005-12-01

    The chemistry of mantle derived basalts is largely controlled by elemental partitioning between melt and mantle minerals. For the Re-Os isotope system, parent and daughter elements may be strongly decoupled between oxide and sulphide, both in sub-continental and sub-oceanic mantle [1]. Both natural and experimental studies indicate that Th and U are mostly located in silicates. In contrast sulphide dominates the Pb budget in the same rocks [2]. This raises the possibility that Th, U and Pb may also be strongly decoupled in the mantle. 207Pb-204Pb double spike (DS) and TIMS methods have been used to measure the distribution and partitioning behaviour of Pb between silicate phases and sulphide in mantle xenoliths from Kilbourne Hole and San Carlos, USA and Lashaine, Tanzania. Calibration of the DS yields results for SRM 981 that are in good agreement with published values within analytical error [3, 4, 5]. Preliminary Pb results on a garnet lherzolite from Tanzania indicate that, similar to what is observed in the 187Re-187Os system, included sulphides preserve much older age information than the silicate phases yielding model ages close to 3 Ga and < 1 Ga, respectively. These results indicate that the Pb isotope signature generated by the melting of mantle rocks depends on fertility, degree of melting and the release or retention of less radiogenic Pb from included sulphide in the source. The differential behaviour of Th, U and Pb in mantle rocks may, at least in part, play a role in the decoupling of those elements in MORB. References: [1] Burton, K.W., Schiano, P., Birck, J.L. & Allegre, C.J. (1999). Earth. Plan. Sci. Let., 172, 311-322. [2] Meijer, A., Kwon, T.T., Tilton, G.R. (1990). J. Geoph. Res., 95, 433-448. [3] Galer, S.J.G. & Abouchami, W., (1998). Min. Mag. 62A, 491-492. [4] Thirwall, M.F. (2000). Chem. Geol., 163, 299-322. [5] Baker, J., Peate, D., Waight, T. & Meysen, C. (2004). Chem. Geol., 211, 275-303.

  6. Pb isotope record over one century in snow from Victoria Land, Antarctica

    NASA Astrophysics Data System (ADS)

    Van de Velde, K.; Vallelonga, P.; Candelone, J.-P.; Rosman, K. J. R.; Gaspari, V.; Cozzi, G.; Barbante, C.; Udisti, R.; Cescon, P.; Boutron, C. F.

    2005-03-01

    Pb and Ba concentrations and Pb isotopic compositions are reported for firn core and snow pit samples from Victoria Land, Antarctica, dating from 1872 AD to 1994 AD. From variations in Pb/Ba ratios and Pb isotopic compositions, two periods of major Pb enhancements were identified, from 1891 to 1908 AD and from 1948 to 1994 AD. The earlier pollution event is attributed to Pb emissions from non-ferrous metal production and coal combustion in the Southern Hemisphere and is in excellent agreement with coincident pollution inputs reported in firn/ice cores from two other regions of Antarctica, at Coats Land and Law Dome. Using Pb isotopic systematics, it was calculated that ˜50% of Pb deposited in Victoria Land in 1897 originated from anthropogenic emission sources. The more recent period of Pb enhancements, from 1948 to 1994 AD, corresponds to the introduction and widespread use of gasoline alkyl Pb additives in automobiles in the Southern Hemisphere, with anthropogenic Pb inputs averaging 60% of total Pb but with large uncertainty. Intra- and inter-annual variations in Pb concentrations and isotopic compositions were evaluated in snow pits samples corresponding to the period 1991-1994. Substantial variations in Pb/Ba and 206Pb/ 207Pb ratios were detected but the absence of a regular seasonal pattern for these parameters suggests that the transport and deposition of aerosols to the Antarctic ice sheet are complex and vary from year to year.

  7. Metal(loid) distribution and Pb isotopic signatures in the urban environment of Athens, Greece.

    PubMed

    Kelepertzis, Efstratios; Komárek, Michael; Argyraki, Ariadne; Šillerová, Hana

    2016-06-01

    Lead concentrations and isotopic compositions of contaminated urban soils and house dusts from Athens, Greece, have been determined to identify possible sources of Pb contamination and examine relationships between these two environmental media. Different soil particle sizes (<2000 μm, <200 μm, <100 μm, <70 μm, <32 μm) and chemical fractions (total, EDTA-extractable and acetic acid-extractable (HAc)) were analyzed for their Pb content and isotopic composition. Metal(loid)s (Pb, Zn, Cu, As, Ni, Cr, Mn, Fe) are significantly enriched in the finest fraction. The Pb isotopic compositions were similar for the different soil particle size fractions and different chemical extractions. The HAc extraction proved to be a useful procedure for tracing anthropogenic Pb in urban soil. The range of (206)Pb/(207)Pb ratios (1.140-1.180) in Athens soil suggests that the Pb content represents an accumulated mixture of Pb deposited from past vehicular emissions and local natural sources. The contribution of anthropogenic Pb to total soil Pb ranged from 36% to 95%. The Pb isotopic composition of vacuum house dusts ((206)Pb/(207)Pb = 1.1.38-1.167) from Athens residents is mostly comparable to that of urban soil suggesting that exterior soil particles are transferred into homes. As a result, anthropogenic Pb in house dust from Athens urban environment principally originated from soil particles containing Pb from automobile emissions (former use of leaded gasoline). PMID:26946177

  8. Pb, Sr, and Nd isotopes in basalts and sulfides from the Juan de Fuca Ridge

    NASA Technical Reports Server (NTRS)

    Hegner, E.; Tatsumoto, M.

    1987-01-01

    Isotopic Pb, Sr, and Nd data were collected by the Alvin submersible from seven basalt glasses in the southern Juan de Fuca Ridge (JFR), giving similar ratios for Pb-206/Pb-204 of about 18.45, for Pb-207/Pb-204 of about 15.47, for Pb-208/Pb-204 of about 37.81, for Sr-87/Sr-86 of about 0.70249, and for Nd-143/Nd-144 of about 0.51315. Data suggest that the basalts are all cogenetic, and that four of the samples are also comagmatic. It is concluded that isotopic data for the JFR and seamount basalts provide additional support for the mantle blob cluster model (Allegre et al., 1984), suggesting the involvement of multiple components in the genesis of ridge basalts, and including an unusual end-member that has nonradiogenic Sr and variable Pb-206/Pb-204 isotopic compositions.

  9. A Pb Isotope Window Into the Geodynamics of the Archean Mantle

    NASA Astrophysics Data System (ADS)

    Vervoort, J. D.

    2004-05-01

    The U-Pb isotope system provides us with a powerful tool for attacking problems of the chemical evolution of the Earth. Pb isotopes in Archean rocks, however, have not been widely utilized because the mobility of U makes initial Pb isotope ratios from old silicate rocks difficult if not impossible to determine. Galenas in syngenetic volcanogenic massive sulfide (VMS) deposits, however, provide us with snapshots into initial Pb ratios in these rocks because their Pb isotopic composition is time invariant (U/Pb=0) and is also buffered against disturbances by their high Pb concentrations. Initial Pb isotopic compositions determined from galenas of VMS deposits from the 2.7 Ga Abitibi greenstone belt define a highly linear Pb/Pb isotope array (207Pb/204Pb vs. 206Pb/204Pb), nearly coincident with the 2.7 Ga geochron, whose slope corresponds to an age of ~4.4 Ga. The Abitibi array has a large range of 207Pb/204Pb, remarkably the same magnitude as modern MORB, but 206Pb/204Pb variations only one-tenth as large as MORB. The U/Pb variations that produced these Pb isotopic relationships could only have been created early in the Earth's history when more radiogenic 207Pb was produced than 206Pb. The Pb isotopic variations also require that evolution of Pb took place in a system that was nearly closed between 4.4 and 2.7 Ga. The Abitibi crust that hosts these VMS deposits is widely characterized by depleted Nd and Hf isotopic compositions, consistent with a the Abitibi being a dominantly juvenile addition from depleted mantle at 2.7 Ga with little evidence of contributions from older crust. In contrast, the Pb isotopic composition of 2.7 Ga VMS galenas from Archean cratons where older crust is known to occur (e.g., Slave) have Pb isotopic compositions displaced toward higher 206Pb/204Pb, clearly indicating the contribution of pre-2.7 Ga crust in their genesis. The simple observation is that there is Pb isotopic evidence for older crust where it is known to exist today and this

  10. A century long sedimentary record of anthropogenic lead (Pb), Pb isotopes and other trace metals in Singapore.

    PubMed

    Chen, Mengli; Boyle, Edward A; Switzer, Adam D; Gouramanis, Chris

    2016-06-01

    Reconstructing the history of metal deposition in Singapore lake sediments contributes to understanding the anthropogenic and natural metal deposition in the data-sparse Southeast Asia. To this end, we present a sedimentary record of Pb, Pb isotopes and eleven other metals (Ag, As, Ba, Cd, Co, Cr, Cu, Ni, Tl, U and Zn) from a well-dated sediment core collected near the depocenter of MacRitchie Reservoir in central Singapore. Before the 1900s, the sedimentary Pb concentration was less than 2 mg/kg for both soil and sediment, with a corresponding (206)Pb/(207)Pb of ∼1.20. The Pb concentration increased to 55 mg/kg in the 1990s, and correspondingly the (206)Pb/(207)Pb decreased to less than 1.14. The (206)Pb/(207)Pb in the core top sediment is concordant with the (206)Pb/(207)Pb signal of aerosols in Singapore and other Southeast Asian cities, suggesting that Pb in the reservoir sediment was mainly from atmospheric deposition. Using the Pb concentration in the topmost layer of sediment, the estimated atmospheric Pb flux in Singapore today is ∼1.6 × 10(-2) g/m(2) yr. The concentrations of eleven other metals preserved in the sediment were also determined. A principal component analysis showed that most of the metals exhibit an increasing trend towards 1990s with a local concentration peak in the mid-20(th) century. PMID:26967352

  11. Combining stable isotope isotope geochemistry and carbonic anhydrase activity to trace vital effect in carbonate precipitation experiments

    NASA Astrophysics Data System (ADS)

    Thaler, C.; Ader, M.; Menez, B.; Guyot, F. J.

    2013-12-01

    Carbonates precipitated by skeleton-forming eukaryotic organisms are often characterized by non-equilibrium isotopic signatures. This specificity is referred to as the "vital effect" and can be used as an isotopic evidence to trace life. Combining stable isotope geochemistry and enzymology (using the enzyme carbonic anhydrase) we aim to demonstrate that prokaryotes are also able to precipitate carbonate with a non-equilibrium d18OCaCO3. Indeed, if in an biomineralization experiment carbonates are precipitated with a vital effect, the addition of carbonic anhydrase should drive the system to isotope equilibrium, And provide a comparison point to estimate the vital effect range. This protocol allowed us to identify a -20‰ vital effect for the d18O of carbonates precipitated by Sporosarcina pasteurii, a bacterial model of carbonatogen metabolisms. This approach is thus a powerfull tool for the understanding of microbe carbonatogen activity and will probably bring new insights into the understanding of bacterial activity in subsurface and during diagenesis.

  12. Estimation of groundwater velocities from Yucca Flat to the Amargosa Desert using geochemistry and environmental isotopes

    SciTech Connect

    Hershey, R.L.; Acheampong, S.Y.

    1997-06-01

    Geochemical and isotopic data from groundwater sampling locations can be used to estimate groundwater flow velocities for independent comparison to velocities calculated by other methods. The objective of this study was to calculate groundwater flow velocities using geochemistry and environmental isotopes from the southern end of Yucca Flat to the Amargosa Desert, considering mixing of different groundwater inputs from sources each and southeast of the Nevada Test Site (NTS). The approach used to accomplish the objective of this study consisted of five steps: (1) reviewing and selecting locations where carbon isotopic groundwater analyses, reliable ionic analysis, and well completion information are available; (2) calculating chemical speciation with the computer code WATEQ4F (Ball and Nordstrom, 1991) to determine the saturation state of mineral phases for each ground water location; (3) grouping wells into reasonable flowpaths and mixing scenarios from different groundwater sources; (4) using the computer code NETPATH (Plummer et al., 1991) to simulate mixing and the possible chemical reactions along the flowpath, and to calculate the changes in carbon-13/carbon-12 isotopic ratios ({delta}{sup 13}C) as a result of these reactions; and (5) using carbon-14 ({sup 14}C) data to calculate velocity.

  13. Trace Metals, Rare Earths, Carbon and Pb Isotopes as Proxies of Environmental Catastrophe at the Permian - Triassic Boundary in Spiti Himalayas, India

    NASA Astrophysics Data System (ADS)

    Ghosh, N.; Basu, A. R.; Garzione, C. N.; Ghatak, A.; Bhargava, O. N.; Shukla, U. K.; Ahluwalia, A. D.

    2015-12-01

    Himalayan sediments from Spiti Valley, India preserve geochemical signatures of the Permian - Triassic (P-Tr) mass extinction in the Neo-Tethys Ocean. We integrate new sedimentological and fossil record with high-resolution geochemical-isotopic data from Spiti that reveals an ecological catastrophe of global proportions. Trace elements of U, Th, Nb, Ta, Zr, Hf, the rare earths (REE) and carbon, oxygen and lead isotopes measured across the P-Tr boundary in Spiti are used as proxies for evaluating abrupt changes in this continental shelf environment. δ13Corg excursions of 2.4‰ and 3.1‰ in Atargu and Guling P-Tr sections in Spiti Valley are associated with an abrupt fall of biological productivity while δ13Ccarb and δ18Ocarb record of these sediments shows effects of diagenesis. Here, the P-Tr boundary is compositionally distinct from the underlying Late Permian gray shales, as a partly gypsiferous ferruginous layer that allows additional geochemical-isotopic investigation of sedimentary sources. Conspicuous Ce - Eu anomalies in the light REE-enriched Late Permian shales reflect the source composition of the adjacent Panjal Trap basalts of Kashmir. An abrupt change of this source to continental crust is revealed by Nb - Ta and Zr - Hf anomalies at the P-Tr ferruginous layer and continuing through the overlying Early Triassic carbonate rocks. Pb concentration and isotope ratios of 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb identify changes in the sedimentary element flux, distinguishing the Late Permian shales from the distinct siliciclastic continental crustal signature in the Early Triassic carbonates. These geochemical-isotopic constraints on the sedimentary geochemistry of one of the most critical transitions in geological record establish the utility of multi-proxy datasets for paleoenvironmental reconstructions.

  14. Strontium isotope characterization and major ion geochemistry of karst water flow, Shentou, northern China

    NASA Astrophysics Data System (ADS)

    Wang, Yanxin; Guo, Qinghai; Su, Chunli; Ma, Teng

    2006-09-01

    SummaryKarst water is the most important source of water supply for Shanxi province, northern China. The Shentou springs are representative of the 19 major karst springs at Shanxi. The total area of the Shentou karst water system is 5316 km 2, the Middle Ordovician limestone being its major karst aquifer. In this study, data about the strontium isotope geochemistry and major ion hydrochemistry were analyzed to understand the flow patterns and hydrogeochemical processes of karst water at Shentou. The contour map of TDS value of karst water and that of Sr concentration are similar, showing the general tendency of increase from the northern, western and southern boundary to the discharge area. The average values of 87Sr/ 86Sr ratios of karst water decrease from recharge (0.7107) to discharge area (0.7102), evolving towards those of limestone hostrocks. Comparison of 87Sr/ 86Sr ratios with Sr content suggests that isotopic compositions of some karst water samples from the recharge and flow through area should be the result of interaction between aquifer limestone matrix and strontium-poor recharge waters of meteoric origin. However, for samples from the discharge area that are plotted above the mixing line, mixing with groundwater in the Quaternary aquifers with high 87Sr/ 86Sr ratios may be another factor controlling Sr isotope chemistry. Two major groundwater flow paths were discerned from hydrogeological and geochemical data. Along both flow paths, the 87Sr/ 86Sr ratios of karst water show a general tendency of decrease. Geochemical modeling of the major ion geochemistry of karst water using PHREEQC also indicates that the chemistry of springs should be affected by the incorporation of groundwater in Quaternary aquifer. The effect of the mixing action on the spring hydrochemistry in flow path 1 is more remarkable than that in flow path 2, according to different mixing ratios in both paths (30% in flow path 1 and 5% in flow path 2).

  15. Dust in Antarctica: the perspective from Pb isotopes

    NASA Astrophysics Data System (ADS)

    Vallelonga, P. T.

    2013-12-01

    The timing and variability of glacial-interglacial dust fluxes to the central East Antarctic plateau have been well defined from the detailed EPICA Dome C and Vostok ice core records. Within this broad structure, several interesting and analytically demanding questions have developed around the sources, transport mechanisms and distribution of deposition of Antarctic dust. During the glacial maxima, the dominance of dust from southern South America is clearly demonstrated by several proxies. The provenance of dust during the interglacials and relatively non-dusty periods of each glacial is still actively debated. These periods are significant in that they comprise approximately 80% of the duration and 30% of total dust emission during each complete glacial-interglacial cycle. Lead (Pb) isotopes have been successfully employed to study the late-Holocene development of industrial emissions in the Southern Hemisphere, with this technique consequently applied to paleofluxes of Antarctic Pb. Emphasis will be given to the interpretation of isotopic data and new findings from the EPICA Dome C and Vostok ice cores.

  16. The Use of Lead Isotope and Rare Earth Element Geochemistry for Forensic Geographic Provenancing

    NASA Astrophysics Data System (ADS)

    Carey, A.; Darrah, T.; Harrold, Z.; Prutsman-Pfeiffer, J.; Poreda, R.

    2008-12-01

    Lead isotope and rare earth element composition of modern human bones are analyzed to explore their utility for geographical provenancing. DNA analysis is the standard for identification of individuals. DNA analysis requires a DNA match for comparison. Thus, DNA analysis is of limited use in cases involving unknown remains. Trace elements are incorporated into bones and teeth during biomineralization, recording the characteristics of an individual's geochemical environment. Teeth form during adolescence, recording the geochemical environment of an individual's youth. Bones remodel throughout an individual's lifetime. Bones consist of two types of bone tissue (cortical and trabecular) that remodel at different rates, recording the geochemical environment at the time of biomineralization. Cortical bone tissue, forming the outer surface of bones, is dense, hard tissue that remodels in 25-30 yrs. Conversely, trabecular bone tissue, the inner cavity of bones, is low density, porous and remodels in 2-5 years. Thus, analyzing teeth and both bone tissues allows for the development of a geographical time line capable of tracking immigration patterns through time instead of only an individual's youth. Geochemical isotopic techniques (Sr, O, C, N) have been used for geographical provenancing in physical anthropology. The isotopic values of Sr, C, O, N are predominantly a function of soil compositions in areas where food is grown or water is consumed. Application of these provenancing techniques has become difficult as an individual's diet may reflect the isotopic composition of foods obtained at the local grocer as opposed to local soil compositions. Thus, we explore the use of REEs and Pb isotopes for geographical provenancing. Pb and REEs are likely more reliable indicators of modern geographical location as their composition are high in bio-available sources such as local soils, atmospheric aerosols, and dust as opposed to Sr, C, O, N that are controlled by food and

  17. Solubility, diffusivity, and isotopic exchange rate of hydrogen isotopes in Li-Pb

    SciTech Connect

    Maeda, Y.; Edao, Y.; Yamaguchi, S.; Fukada, S.

    2008-07-15

    The diffusion, solution and permeation coefficients of hydrogen isotopes in liquid Li-Pb which is a candidate liquid blanket material for fusion reactors were determined in the temperature range 573-973 K using an unsteady permeation method. Each coefficients was correlated to temperature as follows: D{sub Li-Pb} = 1.8 x 10{sup -8} exp(-11590/RT) [m{sup 2}/s] (1) K{sub Li-Pb} = 2.1x10{sup -6} exp(-18700/RT) [1/Pa{sup 0.5}] (2) P{sub Li-Pb} = 1.8x10{sup -9} exp(-30290/RT) [mol/msPa{sup 0.5}] (3) The hydrogen permeation flux depends on the square root of pressure at 773-973 K. Although the power of pressure declined below 0.4 when temperature was below 673 K, the effects of surface resistance were neglected above 673 K. The hydrogen solubility in liquid Li-Pb was found to correlate with a Sievert's constant. We calculated a height-equivalent to theoretical-plate of a gas-liquid countercurrent extraction tower for tritium recovery rates in liquid Li-Pb to be H{sub L}= 7.0x10{sup -2} [m] (4). (authors)

  18. Chemical and isotopical characterisation of atmospheric pollution from urban and rural environments of the Rhine Valley (PCBs, trace elements and Sr-, Nd- and Pb- isotope determinations)

    NASA Astrophysics Data System (ADS)

    Guéguen, F.; Stille, P.; Millet, M.; Dietze, V.; Gieré, R.

    2010-05-01

    from traffic and the principal industrial activities. UCC normalized trace element distribution patterns of aerosols and tree bark are very similar. 206Pb/207Pb and 208Pb/207Pb isotope ratios of today's PM vary within a small range and are very similar to those of steel plant, waste incinerator and thermal power plant emissions. Older aerosols (collected 1995, before leaded petrol was phased out), have significantly lower Pb isotope ratios pointing to the impact of leaded gasoline at that time. Tree bark monitoring covers a 10-y history of Pb emissions. Combining Pb isotope ratios with 87Sr/86Sr and 143Nd/144Nd allows for a much better discrimination between the different anthropogenic emissions and might be suitable for source apportionments. PCBs concentrations of tree bark or PAS samples are generally correlated with trace element contents determined on the same material. PAS/tree bark PCBs ratio allows distinguishing between current or past contamination. 1Lahd Geagea, M., Stille, P., Gauthier-Lafaye, F., Perrone, Th., Aubert, D. 2008. Baseline determination of the atmospheric Pb, Sr and Nd isotopic compositions in the Rhine valley, Vosges mountains (France) and the Central Swiss Alps. Applied Geochemistry, 23, 1703-1714.

  19. Pb, Sr, Nd and Hf isotopic evidence of multiple sources for Oahu, Hawaii basalts

    NASA Technical Reports Server (NTRS)

    Stille, P.; Unruh, D. M.; Tatsumoto, M.

    1983-01-01

    Pb, Sr, Nd and Hf isotopic compositions of Oahu volcanics indicate that the three principal volcanic series on Oahu Koolau, Honolulu and Waianae - were derived from isotopically distinct sources. Honolulu and Waianae basalts plot on the Nd-Pb-Sr 'mantle plane' whereas Koolau data plot distinctly below the plane.

  20. Anorogenic nature of magmatism in the Northern Baikal volcanic belt: Evidence from geochemical, geochronological (U-Pb), and isotopic (Pb, Nd) data

    USGS Publications Warehouse

    Neymark, L.A.; Larin, A.M.; Nemchin, A.A.; Ovchinnikova, G.V.; Rytsk, E. Yu

    1998-01-01

    The Northern Baikal volcanic belt has an age of 1.82-1.87 Ga and extends along the boundary between the Siberian Platform and the Baikal foldbelt. The volcanic belt is composed of volcanics of the Akitkan Group and granitic rocks of the Irel and Primorsk complexes. The geochemistry of the rocks points to the intraplate anorogenic nature of the belt. U-Pb zircon dating of the Chuya granitoids revealed that they are older (2020-2060 Ma) than the Northern Baikal volcanic belt and, thus, cannot be regarded as its component. Data on the Pb isotopic system of feldspars from the granitoids confirm the contemporaneity of all volcanic rocks of the belt except the volcanics of the upper portion of the Akitkan Group (Chaya Formation). Our data suggest its possibly younger (???1.3 Ga) age. The isotopic Nd and Pb compositions of the acid volcanic rocks provide evidence of the heterogeneity of their crustal protoliths. The volcanics of the Malaya Kosa Formation have ??Nd(T) = -6.1, ??2 = 9.36, and were most probably produced with the participation of the U-depleted lower continental crust of Archean age. Other rocks of the complex show ??Nd(T) from -0.1 to -2.4, ??2 = 9.78, and could have been formed by the recycling of the juvenile crust. The depletion of the Malaya Kosa volcanics in most LILEs and HFSEs compared with other acid igneous rocks of the belt possibly reflects compositional differences between the Late Archean and Early Proterozoic crustal sources. The basaltic rocks of the Malaya Kosa Formation (??Nd varies from -4.6 to -5.4) were produced by either the melting of the enriched lithospheric mantle or the contamination of derivatives of the depleted mantle by Early Archean lower crustal rocks, which are not exposed within the area. Copyright ?? 1998 by MAEe Cyrillic signK Hay??a/Interperiodica Publishing.

  1. Pb isotopic ratios in airborne PM 10 of an iron/metal industrial complex area and nearby residential areas: Implications for ambient sources of Pb pollution

    NASA Astrophysics Data System (ADS)

    Lee, Heon-Chul; Kim, Mo-Keun; Jo, Wan-Kuen

    2011-03-01

    This study examined four stable isotopic compositions of Pb in the PM10 (204Pb, 206Pb, 207Pb and 208Pb) along with the ambient Pb concentrations in two residences relative to their proximity to an iron and metal industrial complex (IMIC) as well as an industrial site located within the boundary of the IMIC. In addition, eight potential emission sources were investigated for stable isotopic compositions of Pb. The wintertime Pb isotopic ratios for 208Pb/206Pb for ambient samples of an industrial sampling site (ISS) were closer to those of the residential ambient air concentrations measured at closer proximity to the IMIC (RA1) compared to another residential area located further away (RA2). This finding suggests that the ambient Pb sources were more similar between RA1 and the ISS than between RA2 and the ISS. In contrast, the summertime Pb isotopic ratios for the ambient samples of the ISS were not similar to those for RA1, which in turn were similar to those for RA2. During the summer, it is suggested that motor vehicle emissions appear to be a potential source of Pb in the two residential areas. For the ISS, neither 207Pb/206Pb nor 208Pb/206Pb ratios showed a clear seasonal pattern. However for the ambient samples of the two residential areas, both the 207Pb/206Pb and 208Pb/206Pb ratios exhibited a seasonal pattern, with relatively higher mean 207Pb/206Pb and 208Pb/206Pb ratios during the summer season. It was further confirmed that the ambient Pb concentrations were significantly higher at the ISS than those for RA1, which in turn were significantly higher than those for RA2. At all three sampling sites, high enrichment factor values (≥ 475) were found for Pb.

  2. Evidence of a connection between the Atlantic and Mediterranean during the Messinian Salinity Crisis from Pb and Nd isotopes

    NASA Astrophysics Data System (ADS)

    Modestou, Sevasti; Gutjahr, Marcus; Fietzke, Jan; Rodés, Ángel; Frank, Martin; Bolhão Muiños, Susana; Ellam, Rob; Flecker, Rachel

    2014-05-01

    Prior to the opening of the Gibraltar Strait at 5.33 Ma, the Betic (southern Spain) and Rifian (northern Morocco) marine palaeocorridors linked the Mediterranean to the Atlantic. Although the central regions of these corridors have been heavily eroded due to uplift, evidence published to date indicates that both closed before the onset of the Messinian Salinity Crisis (MSC; 5.97 to 5.33 Ma [1, 2]). However, pre-MSC corridor closure presents a paradox, as the volume of halite deposited within the Mediterranean basin requires several times the volume of seawater contained in the basin itself. In this regard, radiogenic isotopes such as Sr, Pb, and Nd can provide key information about the timing of exchange through the Betic and Rifian palaeogateways. Due to the resolvable isotopic difference in Nd isotope signatures of outgoing Mediterranean and incoming Atlantic water masses, demonstrated both for the present day as well as the past environment, this isotope system can be used to identify exchange between these two water bodies. Although less well constrained to date, the Pb isotope system can be used in a similar manner due to its short residence time in seawater and interbasin variability. A high resolution Pb isotope record extracted using laser ablation from ferromanganese crust 3514-6 (recovered from the Lion Seamount, NE Atlantic, water depth 690-940 m) indicates a relatively constant Pb isotope signature before, during and after the MSC period. The previously published [3] Nd isotope record of crust 3514-6 corroborates that the crust was deposited in a current distinct from NE Atlantic Deep water or Antarctic Intermediate Water, the principal currents in the region of the Lion Seamount. The combined Pb and Nd isotope evolution suggests that Mediterranean Outflow Water (MOW) was continuously advected into the NE Atlantic during and after the MSC. Furthermore, preliminary Nd isotope records from Late Miocene sediments collected in the Sorbas Basin, Spain

  3. Common Pb isotope mapping of UHP metamorphic zones in Dabie orogen, Central China: Implication for Pb isotopic structure of subducted continental crust

    NASA Astrophysics Data System (ADS)

    Shen, Ji; Wang, Ying; Li, Shu-Guang

    2014-10-01

    We report Pb isotopic compositions for feldspars separated from 57 orthogneisses and 2 paragneisses from three exhumed UHPM slices representing the North Dabie zone, the Central Dabie zone and the South Dabie zone of the Dabie orogen, central-east China. The feldspars from the gneisses were recrystallized during Triassic continental subduction and UHP metamorphism. Precursors of the orthogneisses are products of Neoproterozoic bimodal magmatic events, those in north Dabie zone emplaced into the lower crust and those in central and south Dabie zones into middle or upper crust, respectively. On a 207Pb/204Pb vs. 206Pb/204Pb diagram, almost all orthogneisses data lie to the left of the 0.23 Ga paleogeochron and plot along the model mantle evolution curve with the major portion of the data plotting below it. On a 208Pb/204Pb vs. 206Pb/204Pb diagram the most of data of north Dabie zone extend in elongate arrays along the lower crustal curve and others extend between the lower crustal curve to near the mantle evolution curve for the plumbotectonics model. This pattern demonstrates that the Pb isotopic evolution of the feldspars essentially ended at 0.23 Ga and the orthogneiss protoliths were principally dominated by reworking of ancient lower crust with some addition of juvenile mantle in the Neoproterozoic rifting tectonic zone. According to geological evolution history of the locally Dabie orogen, a four-stage Pb isotope evolution model including a long time evolution between 2.0 and 0.8 Ga with a lower crust type U/Pb ratio (μ = 5-6) suggests that magmatic emplacement levels of the protoliths of the orthogneisses in the Dabie orogen at 0.8 Ga also play an important role in the Pb evolution of the exhumed UHPM slices, corresponding to their respective Pb characters at ca. 0.8-0.23 Ga. For example, north Dabie zone requires low μ values (3.4-9.6), while central and south Dabie zones require high μ values (10.9-17.2). On the other hand, Pb isotopic mixing between

  4. Isotopic composition of Pb and Th in interplinian volcanics from Somma-Vesuvius volcano, Italy

    USGS Publications Warehouse

    Cortini, M.; Ayuso, R.A.; de Vivo, B.; Holden, P.; Somma, R.

    2004-01-01

    We present a detailed isotopic study of volcanic rocks emitted from Somma-Vesuvius volcano during three periods of interplinian activity: "Protohistoric" (3550 y B.P. to 79 A.D.), "Ancient Historic" (79 to 472 A.D.) and "Medieval" (472 to 1631 A.D.). Pb isotopic compositions of two acid leached fractions and whole rock residues of 37 whole rock samples (determined by Somma et al., 2001) show that each of the three interplinian periods is distinguished by small, systematic, and unique uranogenic and thorogenic Pb isotopic trends. This key and novel feature is compatible with the notion that the Pb isotopic data reflect small-scale source heterogeneity operating over relatively short periods of time. From this representative group of samples, a selected set of nine whole rocks were analysed for Th isotopes. 232Th/238U ratios in the source can be obtained independently from Pb and from Th isotopes. Those obtained from Pb isotopes represent source ratios, time-integrated over the whole age of the Earth; they range from 3.9 to 4.1. 232Th/238U obtained from Th isotopes are those of the present source. They are lower, and cluster around 3.5; this difference probably indicates recent U enrichment of the present source. The behaviour of Pb, as inferred by its isotopic ratios, is quite distinct from that of Sr and Nd isotopes: Pb isotope variations are not correlated to Sr or Nd isotope variations. The isotopic contrast is compatible with the idea that the isotopes were decoupled during magmatic production, evolution, and ascent through the crust. Thus, the Pb isotopes do not reflect the effects of the same processes as in the case of the Sr and Nd isotopes, or, as we also favor, they do not necessarily reflect the same source contributions into the magmas. Moreover, the Pb isotopic evolution of the interplinian rocks chiefly reflects mixing, driven by processes that are superimposed on, and independent of, other source contributions that determine the isotopic compositions

  5. U-Pb geochronology and geochemistry of Eocene and Oligocene plutons in southeast Iran: Implication for closure of the South Sistan Suture Zone

    NASA Astrophysics Data System (ADS)

    Burg, Jean-Pierre; Mohammadi, Ali; Ruh, Jonas; Bouilhol, Pierre

    2016-04-01

    The N-S trending Sistan Suture Zone in eastern Iran is a splay of the Tethys sutures. It represents an oceanic embayment that separated the Central Iran from the Afghan continental blocks. Structural, tectonic and petrological/geochemical evidence define eastward subduction beneath the Afghan continental block of the Sistan inlet of the Mesozoic Tethys Ocean. Mapping of the area allowed reaching and sampling intermediate to granitic intrusions stretched along the southern segment of this collisional suture zone. U-Pb zircon crystallization ages combined with major and trace element analyses, dated the series of granite-granodiorite-rhyolite at ca 40.5-44.3 Ma and ca 28.9-30.9 Ma. Isotopic geochemistry, including Sr-Nd isotopes and Hf isotope analyses, and petrological modelling suggest that the 40.5-44.3 Ma plutons crystallized from melts largely derived from the turbidites of the host accretionary wedge. Melting of the deep wedge was induced by the intrusion of mantle magmas interacting with the crustal turbiditic melts, which is responsible for the wide range of compositions. Most of the 28.9-30.9 Ma magmas were generated from mantle melting, with assimilation of the surrounding turbidites. The rare setting of within-wedge intrusions is attributed to mantle upwelling reaching wedge sediments at the inception of delamination processes, which sign the end of subduction-related deformational and thermal events in the Sistan Suture Zone. Numerical modelling of subduction - magma production - intrusion and melting of wedge sediments further constrains this collisional to post-collisional scenario.

  6. Hf-Nd Isotopic and Trace-Element Geochemistry of Global Subducting Sediments

    NASA Astrophysics Data System (ADS)

    Vervoort, J. D.; Plank, T.; Patchett, P. J.

    2001-12-01

    Ferromanganese nodules, crusts, and associated metalliferous clays have long been known to have anomalously high Lu/Hf ratios and highly radiogenic Hf relative to Nd (Patchett et al., 1984; White et al., 1986). These oceanic sediments are some of the few terrestrial materials where Hf and Nd isotopes deviate from the crust-mantle array. This distinctive isotopic signature, therefore, has the potential to trace the fate of oceanic sediments through the subduction zone and into the mantle. It has recently been suggested, for example, that pelagic sediments can be detected in some Hawaiian basalts (Blichert-Toft et al., 1999) and in volcanic rocks from the Luzon arc (Marini et al., 2000) based on their Hf-Nd isotopic compositions. The weak link in this approach, however, is that we do not know, in any quantitative way, how widespread this anomalous signature is in oceanic sediments, what compositions are responsible for this signature, or how volumetrically important these compositions are in terms of the total sediment flux into subduction zones and the mantle. Most marine sediments analyzed thus far have been collected on or near the ocean floor and constitute an incomplete and unrepresentative inventory of the sediment column bound for the subduction zone. There is some reason to suspect that much of the sediment flux is not particularly anomalous, either in terms of Lu/Hf ratios or Hf and Nd isotopic compositions. The most dominant sediment types entering many subduction zones (terrigenous and other continentally derived sediments), have normal Lu/Hf ratios and Hf-Nd isotopic compositions that are indistinguishable from the crust-mantle array. An examination is needed of the Hf-Nd isotopic composition of oceanic sediments, the major and trace-element geochemistry of global sediment flux, how such compositions may relate to Hf-Nd isotopic behavior, and potential Lu/Hf and Nd/Hf fractionation in subduction zones. In addition, the origin of the high Lu/Hf and

  7. Zircon U-Pb-Hf isotopes, bulk-rock geochemistry and petrogenesis of Middle to Late Triassic I-type granitoids in the Xing'an Block, northeast China: Implications for early Mesozoic tectonic evolution of the central Great Xing'an Range

    NASA Astrophysics Data System (ADS)

    Yang, Hao; Ge, Wen-chun; Yu, Qian; Ji, Zheng; Liu, Xi-wen; Zhang, Yan-long; Tian, De-xin

    2016-04-01

    We report zircon U-Pb age data, Hf isotopes, and bulk-rock geochemical data for the Middle to Late Triassic granitoids in the Taerqi-Chabaqi-Kutihe region within the Xing'an Block of the central Great Xing'an Range, northeast China. Euhedral to subhedral zircon grains were extracted from the nine representative granitoids. These zircons exhibit oscillatory zoning typical of a magmatic origin. The zircon U-Pb determinations on the monzogranite, syenogranite and quartz diorite samples yielded ages between 244 Ma and 206 Ma, which essentially suggests that the magmatism in the Xing'an Block occurred during the Middle to Late Triassic period. Geochemically, these granitoids have SiO2 = 62.97-76.31 wt%, A/CNK = 1.03-1.51, and K2O/Na2O = 0.40-2.39, we infer that they belong to high-K calc-alkaline series and are peraluminous I-type granites in nature. The major and trace element systematics indicate that these granitoids have different origins. Among them, the 244 Ma syenogranite of Taerqi and the 230-206 Ma monzogranite and syenogranite of Kutihe were probably generated from partial melting of pre-existing juvenile arc-type rocks in a relatively shallow crustal level. The 210 Ma quartz diorite of Chabaqi likely originated from the hybridization between a depleted mantle component and the juvenile subducted oceanic crustal materials that were buried to depths of the middle to lower continental crust. The 212 Ma monzogranite and syenogranite of Kutihe were probably generated from the partial melting of miscellaneous lower crustal materials at high pressure conditions. By combining these new data with regional geological data, we conclude that the early Mesozoic evolution of the central Great Xing'an Range was governed by two superimposed tectonic regimes, i.e., (1) post-orogenic extension due to slab break-off after the closure of the Paleo-Asian oceanic basin along the Hegenshan-Heihe suture belt, and (2) back-arc extension associated with the southward subduction of

  8. Heavy Metals Pollution and Pb Isotopic Signatures in Surface Sediments Collected from Bohai Bay, North China

    PubMed Central

    Gao, Bo; Lu, Jin; Hao, Hong; Yin, Shuhua; Yu, Xiao; Wang, Qiwen; Sun, Ke

    2014-01-01

    To investigate the characteristics and potential sources of heavy metals pollution, surface sediments collected from Bohai Bay, North China, were analyzed for the selected metals (Cd, Cr, Cu, Ni, Pb, and Zn). The Geoaccumulation Index was used to assess the level of heavy metal pollution. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 0.15, 79.73, 28.70, 36.56, 25.63, and 72.83 mg/kg, respectively. The mean concentrations of the studied metals were slightly higher than the background values. However, the heavy metals concentrations in surface sediments in Bohai Bay were below the other important bays or estuaries in China. The assessment by Geoaccumulation Index indicated that Cr, Zn, and Cd were classified as “the unpolluted” level, while Ni, Cu, and Pb were ranked as “unpolluted to moderately polluted” level. The order of pollution level of heavy metals was: Pb > Ni > Cu > Cr > Zn > Cd. The Pb isotopic ratios in surface sediments varied from 1.159 to 1.185 for 206Pb/207Pb and from 2.456 to 2.482 for 208Pb/207Pb. Compared with Pb isotopic radios in other sources, Pb contaminations in the surface sediments of Bohai Bay may be controlled by the mix process of coal combustion, aerosol particles deposition, and natural sources. PMID:24982926

  9. Heavy metals pollution and pb isotopic signatures in surface sediments collected from Bohai Bay, North China.

    PubMed

    Gao, Bo; Lu, Jin; Hao, Hong; Yin, Shuhua; Yu, Xiao; Wang, Qiwen; Sun, Ke

    2014-01-01

    To investigate the characteristics and potential sources of heavy metals pollution, surface sediments collected from Bohai Bay, North China, were analyzed for the selected metals (Cd, Cr, Cu, Ni, Pb, and Zn). The Geoaccumulation Index was used to assess the level of heavy metal pollution. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 0.15, 79.73, 28.70, 36.56, 25.63, and 72.83 mg/kg, respectively. The mean concentrations of the studied metals were slightly higher than the background values. However, the heavy metals concentrations in surface sediments in Bohai Bay were below the other important bays or estuaries in China. The assessment by Geoaccumulation Index indicated that Cr, Zn, and Cd were classified as "the unpolluted" level, while Ni, Cu, and Pb were ranked as "unpolluted to moderately polluted" level. The order of pollution level of heavy metals was: Pb > Ni > Cu > Cr > Zn > Cd. The Pb isotopic ratios in surface sediments varied from 1.159 to 1.185 for (206)Pb/(207)Pb and from 2.456 to 2.482 for (208)Pb/(207)Pb. Compared with Pb isotopic radios in other sources, Pb contaminations in the surface sediments of Bohai Bay may be controlled by the mix process of coal combustion, aerosol particles deposition, and natural sources. PMID:24982926

  10. Pb isotopic constraints on the formation of the Dikulushi Cu-Pb-Zn-Ag mineralisation, Kundelungu Plateau (Democratic Republic of Congo)

    NASA Astrophysics Data System (ADS)

    Haest, Maarten; Schneider, Jens; Cloquet, Christophe; Latruwe, Kris; Vanhaecke, Frank; Muchez, Philippe

    2010-04-01

    Base metal-Ag mineralisation at Dikulushi and in other deposits on the Kundelungu Plateau (Democratic Republic of Congo) developed during two episodes. Subeconomic Cu-Pb-Zn-Fe polysulphide ores were generated during the Lufilian Orogeny (c. 520 Ma ago) in a set of E-W- and NE-SW-oriented faults. Their lead has a relatively unradiogenic and internally inhomogeneous isotopic composition (206Pb/204Pb = 18.07-18.49), most likely generated by mixing of Pb from isotopically heterogeneous clastic sources. These sulphides were remobilised and enriched after the Lufilian Orogeny, along reactivated and newly formed NE-SW-oriented faults into a chalcocite-dominated Cu-Ag mineralisation of high economic interest. The chalcocite samples contain only trace amounts of lead and show mostly radiogenic Pb isotope signatures that fall along a linear trend in the 207Pb/204Pb vs. 206Pb/204Pb diagram (206Pb/204Pb = 18.66-23.65; 207Pb/204Pb = 15.72-16.02). These anomalous characteristics reflect a two-stage evolution involving admixture of both radiogenic lead and uranium during a young fluid event possibly c. 100 Ma ago. The Pb isotope systematics of local host rocks to mineralisation also indicate some comparable young disturbance of their U-Th-Pb systems, related to the same event. They could have provided Pb with sufficiently radiogenic compositions that was added to less radiogenic Pb remobilised from precursor Cu-Pb-Zn-Fe polysulphides, whereas the U most likely originated from external sources. Local metal sources are also suggested by the 208Pb/204Pb-206Pb/204Pb systematics of combined ore and rock lead, which indicate a pronounced and diversified lithological control of the immediate host rocks on the chalcocite-dominated Cu-Ag ores. The Pb isotope systematics of polysulphide mineralisation on the Kundelungu Plateau clearly record a diachronous evolution.

  11. Oxygen isotope geochemistry of the amphiboles: Isotope effects of cation substitutions in minerals

    SciTech Connect

    Kohn, M.J.; Valley, J.W.

    1998-06-01

    The occurrence of coexisting amphiboles in rocks and the likelihood of concurrent isotope closure allows equilibrium oxygen isotope fractionations among the amphiboles to be recovered from natural samples. Oxygen isotope analyses of mineral separates using laser fluorination show that coexisting amphiboles increasingly partition {sup 18}O in the order: hornblende {much_lt} gedrite < cummingtonite {le} anthophyllite. The observed fractionations at {approximately}575 C are: {Delta}(Ged-Hbl) = 0.8%, {Delta}(Cum-Hbl) = 0.9, {Delta}(Cum-Ged) = 0.2, {Delta}(Ath-Ged) = 0.3, and {Delta}(Ath-Hbl) > 0.9. Previously published data for hornblende, actinolite, glaucophane, and garnet show that {Delta}(Act-Hbl) {approximately} 0.2, {Delta}(Gin-Grt) {much_gt} 1, and {Delta}(Hbl-Grt) {approximately} 0. Thus, glaucophane strongly partitions {sup 18}O relative to the calcic amphiboles. The fractionation between two amphiboles of arbitrary composition can be predicted from the known fractionations for mica endmembers, pyroxene endmembers, and exchange components. Applications of the exchange component method reproduce measured amphibole fractionations to within {+-}0.1 to {+-}0.2%, whereas other predictive methods cause misfit for typical metamorphic hornblende of {ge}0.5% at 575 C. Although the isotope effects of cation exchanges may be small at high-T, they magnify dramatically for minerals formed in surficial, diagenetic, and low-T metamorphic environments. Different composition clays are predicted to have equilibrium {delta}{sup 18}O differences of 2--9%. If the isotope fractionation can be determined for one mineral endmember, then calibrated exchanges allow accurate prediction of the isotope fractionations for intermediate compositions of most ortho-, ring-, chain-, and sheet-silicates.

  12. The isotope systematics of a juvenile intraplate volcano: Pb, Nd, and Sr isotope ratios of basalts from Loihi Seamount, Hawaii

    USGS Publications Warehouse

    Staudigel, H.; Zindler, A.; Hart, S.R.; Leslie, T.; Chen, C.-Y.; Clague, D.

    1984-01-01

    Sr, Nd, and Pb isotope ratios for a representative suite of 15 basanites, alkali basalts, transitional basalts and tholeiites from Loihi Seamount, Hawaii, display unusually large variations for a single volcano, but lie within known ranges for Hawaiian basalts. Nd isotope ratios in alkali basalts show the largest relative variation (0.51291-0.51305), and include the nearly constant tholeiite value ( ??? 0.51297). Pb isotope ratios show similarly large ranges for tholeiites and alkali basalts and continue Tatsumoto's [31] "Loa" trend towards higher 206Pb 204Pb ratios, resulting in a substantial overlap with the "Kea" trend. 206Pb 204Pb ratios for Loihi and other volcanoes along the Loa and Kea trends [31] are observed to correlate with the age of the underlying lithosphere suggesting lithosphere involvement in the formation of Hawaiian tholeiites. Loihi lavas display no correlation of Nd, Sr, or Pb isotope ratios with major element compositions or eruptive age, in contrast with observations of some other Hawaiian volcanoes [38]. Isotope data for Loihi, as well as average values for Hawaiian volcanoes, are not adequately explained by previously proposed two-end-member models; new models for the origin and the development of Hawaiian volcanoes must include mixing of at least three geochemically distinct source regions and allow for the involvement of heterogeneous oceanic lithosphere. ?? 1984.

  13. Assessment of dissolved Pb concentration and isotopic composition in surface waters of the modern global ocean

    NASA Astrophysics Data System (ADS)

    Pinedo-Gonzalez, P.; West, A. J.; Sanudo-Wilhelmy, S. A.

    2015-12-01

    Lead (Pb) produced by human activities, mainly from leaded gasoline combustion and high-temperature industries, dominates Pb in our present-day oceans. Previous studies have shown that surface ocean Pb concentrations and isotope ratios have varied in time and space, reflecting the changes in the amount of inputs and sources of anthropogenic Pb. However, data on surface ocean Pb is quite limited, especially for some basins like the Indian Ocean. In the present study, Pb concentrations and stable isotopes (208, 207, and 206) have been analyzed in surface water samples (3m depth) collected during the Malaspina Circumnavigation Expedition, 2010. Our results are compared with data from the literature to i) evaluate the changing status of metal contamination in surface waters of the global ocean over the last 30 years, and ii) propose potential sources of modern Pb to the oceans. Our results show that Pb concentrations in surface waters of the North Atlantic Ocean have decreased ~ 40% since 1975, attributable to the phase-out of leaded gasoline in North America. This result is corroborated by stable Pb isotope measurements. Furthermore, the isotopic gradient observed in surface waters of the studied transects in the north tropical and subtropical Atlantic Ocean can be attributed to simple mixing of European and African aerosols and Saharan Holocene loess. Results from an understudied transect in the Southern Indian Ocean give an indication of the source region of Pb delivered to this region. Although comparison with literature data is limited, mixing of Australian ores and African and Australian coals could potentially explain the measured Pb isotope composition. This study provides an opportunity to build on the work of previous oceanographic campaigns, enabling us to assess the impact of anthropogenic Pb inputs to the ocean and the relative importance of various Pb sources, providing new insights into the transport and fate of Pb in the oceans.

  14. A "Tail" Of Two Mines: Determining The Sources Of Lead In Mine Waters Using Pb Isotopes

    NASA Astrophysics Data System (ADS)

    Cousens, B. L.; Allen, D. M.; Lepitre, M. E.; Mortensen, J. K.; Gabites, J. E.; Nugent, M.; Fortin, D.

    2004-12-01

    Acid mine drainage can be a significant environmental problem in regions where mine tailings are exposed to surface water and shallow groundwater flow. Whereas high metal concentrations in surface waters and groundwaters indicate that metals are being mobilized, these data do not uniquely identify the source of the contamination. The isotopic composition of Pb in mine waters is a superb tracer of Pb sources, because the isotopic composition of ore Pb is usually significantly different from that of host rocks, other surficial deposits, and aerosols. We have investigated metal mobility at two abandoned Pb-Zn mines in different geological settings: the sediment-hosted Sullivan Mine in southeastern British Columbia, and the New Calumet Mine of western Quebec that is hosted in metamorphic rocks of the Grenville Province. Ores from both mines have homogeneous Pb isotopic compositions that are much less radiogenic than surrounding host rocks. At Sullivan, the Pb isotopic compositions of water samples define a mixing line between Sullivan ore and at least one other more radiogenic end-member. Water samples with high Pb concentrations (0.002 to 0.3 mg/L) generally are acidic and have Pb isotope ratios equal to Sullivan ore, whereas waters with low Pb contents have near-neutral pH and have variably more radiogenic Pb isotope ratios. Thus not all the waters collected in the study area originate from Sullivan ore or mining operations, as previously thought. The dominant source of ore Pb in mine waters are the waste rock dumps. Based on their isotopic compositions, host shales or aerosols from the local Pb smelter are potential sources of non-Sullivan ore Pb; local glacial tills are an unlikely source due to their heterogeneous Pb isotopic composition. Similarly, at the New Calumet mine, water samples collected in direct contact with either ore at the surface or tailings have high Pb concentrations (up to 0.02 mg/L) and Pb isotope ratios equal to New Calumet Pb-Zn ore. However

  15. Pb isotopic study on soils from Domizio-Flegreo Littoral area, Napoli, Italy

    NASA Astrophysics Data System (ADS)

    Grezzi, G.; Ayuso, R. A.; Lima, A.; Albanese, S.; de Vivo, B.

    2009-04-01

    The Domizio - Flegreo Littoral area, together with the Agro Aversano area, are part of a Site of National Interest for pollution assessment. This area is located along the north coastal zone of the Campania region (Italy) and has an extension of about 855 Km2. We analyzed soils for heavy metal content in order to study and discriminate the impact of natural and anthropogenic sources. We collected 292 soil surface samples (5-15 cm depth) and produced maps showing the distribution of heavy metals in the soils. On the basis of the geographic distribution of heavy metals, 9 soil profiles were also collected for detailed examination (1 meter from surface). From each soil profile, we collected 10 soil samples (1/10 cm) in the urban and suburban areas of the littoral area. Also, we collected 8 groundwater samples likely associated with the soils. Pb isotope compositions of these soils and waters help to constrain the impact of anthropogenic and natural components on the soil profiles. Possible anthropogenic end-members include pesticides used in the area. Lead isotope compositions of soils known to contain anomalously high values of heavy metals were measured in order to determine the sources of the Pb and, by inference, sources of other metals that are likely to share similar geochemical behaviour in the surface environment (e.g., As). Acid-leach compositions of the soils represent Pb that is adsorbed to mineral surfaces, whereas residue compositions may reflect bedrock. Labile Pb (acid-leach fractions) from the soils shows a range in compositions of 207Pb/206Pb = 0.8275 to 0.8486, and 208Pb/206Pb = 2.0488 to 2.0873. The isotope values vary and decrease with depth. The Pb isotope ratios obtained on groundwater samples range from about 207Pb/206Pb = 0.8516 to 0.8636, 208Pb/206Pb = 2.0706 to 2.1064. The Pb isotope ratios in the soil profiles and groundwater are generally consistent with multiple sources that include anthropogenic Pb. Surface soil samples from Giugliano

  16. Trace Element and Pb Isotope Constraints on Dynamic Evolution of Earth Reservoirs

    NASA Astrophysics Data System (ADS)

    Collerson, K.; Kamber, B.

    2001-12-01

    Advances in interpretation of Pb isotope systematics provide constraints for modelling Earth evolution. Such improved understanding of Pb isotope systematics has coincided with advances in techniques for accurate Pb isotope ratio measurement by MC-ICPMS. Continental growth since 3.75 Ga has occurred at convergent margins via dehydration of subducted slabs and supra-subduction zone melting. Nb is preferentially retained in slabs relative to U and Th, which are lost to escaping fluids. Over time, the depleted upper mantle (DM) lost U and Th relative to Nb. Thus Nb/Th and Nb/U of UM mirror amount of continental crust present. Because Nb, Th and U are similarly incompatible during MORB melting, temporal Nb-Th-U systematics of mantle can be reconstructed from uncontaminated, depleted-mantle derived rocks1. Excellent agreement exists between crustal growth curve based on Nb/Th and those based on Pb isotope systematics2 and geophysics 3. Temporal variation of Nb/U reflects crustal extraction until 2 Ga. It then reflects preferential U recycling into DM, constraining timing of preservation of a pandemic oxygenated atmosphere. Increase in atmospheric O2 explains the second Pb paradox and refines understanding of DM evolution. Key to understanding mantle Pb isotope evolution is the realization that DM has highly dynamic U/Pb and Th/U ratios relative to undegassed lower mantle (LM). Thus, so-called OIB EM-1 reservoir could reflect LM4. Pb data for Phanerozoic and Proterozoic Gp 2 kimberlites from South Africa plot in thorogenic and uranogenic Pb space consistent with a LM source [4]. Mineralogically, chemically and isotopically different Gp 1 kimberlites, which are readily discernable in plots of PM normalized Ta/U and Nb/Th have very radiogenic 206Pb/204Pb and 208Pb/204Pb but relatively unradiogenic 207Pb/204Pb, compositions identical to HIMU OIB's. We have suggested in [4] that the HIMU isotopic composition can be derived from EM-1 during a transient <100 Ma stage of strong

  17. Pb isotopes in anorthositic breccias 67075 and 62237 - A search for primitive lunar lead

    NASA Technical Reports Server (NTRS)

    Premo, W. R.; Tatsumoto, M.; Wang, J.-W.

    1989-01-01

    The lunar Pb isotopic evolution is explored based on an investigation of the U-Th-Pb systematics of the primitive Apollo 16 anorthositic breccias 76075 and 62237. The isotope data for acid-leached residues from 67075 lie within or on a triangle formed by plagioclase, opaques, and a pyroxen-olivine mixture, and the isotope data for 62237 lie within or on a triangle formed by plagioclase, olivine, and pyroxene. The results suggest that the moon had high first-stage values for the Pb evolution equations from the onset.

  18. Detrital zircon geochronology and Nd isotope geochemistry of an early Paleozoic succession in Korea:

    NASA Astrophysics Data System (ADS)

    Lee, Yong Il; Choi, Taejin; Lim, Hyoun Soo; Orihashi, Yuji

    2015-04-01

    This study reports the results of an analysis of U-Pb ages of detrital zircons and Nd isotope compositions from the well-established lower Paleozoic platform succession developed on the Precambrian gneiss and metasedimentary rocks in South Korea. The three stratigraphic units in the basal part of the succession are the Jangsan, Myeonsan, and Myobong Formations. The unfossiliferous Jangsan (white­to­pink quartz sandstone) and Myeonsan (dark-gray ilmenite-rich sandstone/shale) Formations are in fault contact and are generally considered to be coeval (Early Cambrian). Both formations are also generally considered to be conformably overlain by the dark­ gray, fossiliferous, fine-grained Myobong Formation (late Early-early Middle Cambrian). We here report U-Pb ages of detrital zircons and Nd isotopic data from the Jangsan, Myeonsan, and Myobong Formations. The Jangsan and Myeonsan Formations provide Archean-Paleoproterozoic U-Pb ages, but the former is characterized by Archean Sm-Nd model ages and the latter by late Paleoproterozoic Sm-Nd model ages, which is indicative of a significant change in provenance. This suggests that the Jangsan Formation predates the Myeonsan Formation. The Myobong Formation provides dominantly Meso- to Neoproterozoic U-Pb ages and Sm-Nd model ages that are slightly younger than those of the Myeonsan Formation. Contrary to the conventional wisdom, the combined evidence of unconformable contact and marked changes in zircon U-Pb ages and Nd isotopic compositions suggests that the Myobong Formation overlies the Jangsan and Myeonsan Formations unconformably. Considering the metamorphic age of the immediately underlying Precambrian basement metasediments (0.8 to 0.9 Ga), this stratigraphic relationship strongly suggests that the Jangsan Formation may be Neoproterozoic in age and that the Myeonsan Formation may be latest Neoproterozoic to Early Cambrian and calls for reevaluation of Precambrian-Paleozoic history of the Korean Peninsula. The

  19. Climate forcing of the Pb isotope record of terrigenous input into the Equatorial Atlantic

    NASA Astrophysics Data System (ADS)

    Abouchami, W.; Zabel, M.

    2003-08-01

    Pb isotopic compositions of bulk sediment cores from the Tropical Atlantic are used here to infer variations in the provenance of terrigenous input to the Tropical Atlantic during Pleistocene climate cycles. The 200-ka high precision (2σ∼100 ppm) Pb isotope records of the Ceará Rise (Western Atlantic) and Sierra Leone Rise (Eastern Atlantic) cores show a clear glacial-interglacial cyclicity, reflected by alternating unradiogenic Pb and radiogenic Pb in both cores. The glacial-interglacial Pb isotopic contrast is also observed in Pb-Pb space and can be explained in terms of binary mixing - variations along the mixing lines reflecting changes in the relative proportions of the glacial (unradiogenic) and interglacial (radiogenic) Pb source(s). The Pleistocene Pb isotopic variability of the terrigenous input to the Ceará Rise can be linked to changes in the weathering styles in the Amazon Basin and, as a result, in the Amazon river discharge. These changes are reflected by a greater contribution from the highlands (Andes) Pb source during glacial times, and strengthening of the lowlands (Shield) Pb source during interglacials. On the other hand, Pb isotopic variations in the Sierra Leone Rise core indicate increased Pb inputs from the Saharan dust plume during glacial times, in agreement with the wind patterns over Africa. Furthermore, this result bears some implications on the cause of the enhanced glacial terrigenous fluxes to the Tropical Atlantic, which we infer to be due to increase in winter wind transport rather than glacial hyperaridity. The cyclicity of the Ceará Rise and Sierra Leone Rise Pb isotopic records together with changes in the proportions of mixing sources throughout the last 200 ka monitor changes in the hydrological cycle over South America and the wind systems over Africa, respectively, both of which are linked to the seasonal latitudinal migration of the Intertropical Convergence Zone. The correlation found between Pb isotope cycles and

  20. Pb isotopic signatures of the atmosphere of the São Paulo city Brazil

    NASA Astrophysics Data System (ADS)

    Babinski, M.; Aily, C.; Ruiz, I. R.; Sato, K.

    2003-05-01

    Lead isotopic compositions of the atmosphere of the São Paulo city, Brazil, were determined from particulate matter (PM{10}) collected on teflon filters, and rainwater samples at the São Paulo University for the period between Auguste 1999 and September/2000. The PM{10} ^{207}Pb/^{206}Pb ratios range from 0.786 to 0.875, and ^{208}Pb/^{206}Pb from 1.934 to 2.119, defining an array on the Pb diagram. Lead concentrations range from 3.02 to 254.52 ng/m^3. Rainwater samples displayed the same isotopic ratios measured on PM{10} collected the same day, thus indicating that aerosols are scavenged by rain. Analyses of possible pollutants sources such as gasoline and ethanol, soot from vehicle exhaust pipes, and particulate material from industrial emissions, collected on fiberglass filters, mostly yielded isotopic compositions falling into an interval defined by 84% of the PM{10} samples (^{207}Pb/^{206}Pb = 0.840-0.870). However, 15% of the PM{10} samples are more radiogenic, indicating a significant, unidentified radiogenic source (^{207}Pb/^{206}Pb < 0.780), evident mainly in samples collected during weekends and from November/1999 to April/2000. We suggest that most of the anthropogenic Pb found in the São Paulo atmosphere comes from industrial emissions, since the amount of Pb present in vehicular fuels is negligible.

  1. Geochemistry of /sup 210/Pb in the southeastern, US estuarine system

    SciTech Connect

    Storti, F.W.

    1980-11-01

    This study was an attempt to determine the geochemical behavior of /sup 210/Pb in southeastern salt marsh estuaries. As a part of this study the /sup 210/Pb dating technique was applied to natural and anthropogenic deposits of the region. /sup 210/Pb activity of sediment and water from the Georgia coastal area was measured by alpha spectroscopy. The effects of grain size and carbon content of the sediment on /sup 210/Pb concentrations was evaluated and the activity of /sup 210/Pb in dissolved and particulate phases of rivers was measured as a function of salinity. Ages and sedimentation rates of sedimentary deposits were also determined for some deposits. /sup 210/Pb activity in dissolved and particulate phases of rivers showed no clear trends as functions of salinity. River particulate activities were three to four times higher than dissolved activities. The relationship between /sup 210/Pb activity in salt marsh sediments and grain size was highly significant. Direct application of the /sup 210/Pb method to date and determine sedimentation rates of natural and anthropogenic deposits was partially successful. The anthropogenic deposits, however, had to be dated on the basis of normalizing /sup 210/Pb activities to grain size (% silt and clay) and carbon content (% carbon).

  2. Isotope and trace element geochemistry of lamprophyres and syenites from different areas of South-Chuya complex, SE Altai.

    NASA Astrophysics Data System (ADS)

    Vasyukova, Elena

    2016-04-01

    Major and trace elements and radiogenic isotope data are reported for lamprophyres and syenites of South-Chuya complex associated with ore districts in South East of Gornyi Altai, Russia. Dikes of lamprophyres form big area, elongated from north-west to south-east. Within the area of complex dikes distribute irregularly accompanied the fault zones. Lamprophyres of three largest areas, named Aktash, South Chuya and Yustyd were characterized in terms of geology, petro- and geochemistry, isotopic composition. Some of the lamprophyres judging by the high mg'>60 reveal mantle signatures. They reveal round TRE patterns typical of the primitive low degree partial melts but with the negative Nb- Ta anomalies. The others with the lower mg' suggest their differentiation and contamination in crust material. They reveal slightly lower level of TRE and lower troughs of all HFSE. All dikes had intruded in the period of 250-235 Ma, have similar mineralogical, petro- and geochemistry characteristics which were the reasons for unite all of them in one complex. On the most of geochemistry diagrams dikes from 3 areas form their own, but intersected clusters. But on the isotopic diagrams (Sm/Nd and Rb/Sr systems) they show the principle dissimilarity between dikes from various areas. Yustyd lamprophyres initial isotopic characteristics are close to the BSE. The south-chuya rocks isotopic compositions are more enriched by 87Sr/86Sr and have negative ɛNd (-2.84..-4.05). Contamination by the lower crust material suggested at the early stage during the formation of the lamprophyres. Bu the Yustyd lamprophyres were contaminated also during the ascend by the upper crust. Two competitive hypotheses n the isotopic composition are dicussed: 1) different sources or 2) different proportions between the material from the same sources, which ensemble generate the parental magma for the rocks.

  3. Progress integrating ID-TIMS U-Pb geochronology with accessory mineral geochemistry: towards better accuracy and higher precision time

    NASA Astrophysics Data System (ADS)

    Schoene, B.; Samperton, K. M.; Crowley, J. L.; Cottle, J. M.

    2012-12-01

    It is increasingly common that hand samples of plutonic and volcanic rocks contain zircon with dates that span between zero and >100 ka. This recognition comes from the increased application of U-series geochronology on young volcanic rocks and the increased precision to better than 0.1% on single zircons by the U-Pb ID-TIMS method. It has thus become more difficult to interpret such complicated datasets in terms of ashbed eruption or magma emplacement, which are critical constraints for geochronologic applications ranging from biotic evolution and the stratigraphic record to magmatic and metamorphic processes in orogenic belts. It is important, therefore, to develop methods that aid in interpreting which minerals, if any, date the targeted process. One promising tactic is to better integrate accessory mineral geochemistry with high-precision ID-TIMS U-Pb geochronology. These dual constraints can 1) identify cogenetic populations of minerals, and 2) record magmatic or metamorphic fluid evolution through time. Goal (1) has been widely sought with in situ geochronology and geochemical analysis but is limited by low-precision dates. Recent work has attempted to bridge this gap by retrieving the typically discarded elution from ion exchange chemistry that precedes ID-TIMS U-Pb geochronology and analyzing it by ICP-MS (U-Pb TIMS-TEA). The result integrates geochemistry and high-precision geochronology from the exact same volume of material. The limitation of this method is the relatively coarse spatial resolution compared to in situ techniques, and thus averages potentially complicated trace element profiles through single minerals or mineral fragments. In continued work, we test the effect of this on zircon by beginning with CL imaging to reveal internal zonation and growth histories. This is followed by in situ LA-ICPMS trace element transects of imaged grains to reveal internal geochemical zonation. The same grains are then removed from grain-mount, fragmented, and

  4. The combined application of organic sulphur and isotope geochemistry to assess multiple sources of palaeobiochemicals with identical carbon skeletons

    NASA Technical Reports Server (NTRS)

    Kohnen, M. E.; Schouten, S.; Sinninghe Damste, J. S.; de Leeuw, J. W.; Merrit, D.; Hayes, J. M.

    1992-01-01

    Five immature sediments from a Messinian evaporitic basin, representing one evaporitic cycle, were studied using molecular organic sulphur and isotope geochemistry. It is shown that a specific carbon skeleton which is present in different "modes of occurrence" ("free" hydrocarbon, alkylthiophene, alkylthiolane, alkyldithiane, alkylthiane, and sulphur-bound in macromolecules) may have different biosynthetic precursors which are possibly derived from different biota. It is demonstrated that the mode of occurrence and the carbon isotopic composition of a sedimentary lipid can be used to "reconstruct" its biochemical precursor. This novel approach of recognition of the suite of palaeobiochemicals present during the time of deposition allows for identification of the biological sources with an unprecedented specificity.

  5. Pb isotopes in sulfides from mid-ocean ridge hydrothermal sites

    SciTech Connect

    LeHuray, A.P.; Church, S.E.; Koski, R.A.; Bouse, R.M.

    1988-04-01

    The authors report Pb isotope ratios of sulfides deposited at seven recently active mid-ocean ridge (MOR) hydrothermal vents. Sulfides from three sediment-starved sites on the Juan de Fuca Ridge contain Pb with isotope ratios identical to their local basaltic sources. Lead in two deposits from the sediment-covered Escanaba Trough, Gorda Ridge, is derived from the sediments and does not appear to contain any basaltic component. There is a range of isotope ratios in a Guaymas Basin deposit, consistent with a mixture of sediment and MOR basalt Pb. Lead in a Galapagos deposit differs slightly from known Galapagos basalt Pb isotope values. The faithful record of Pb isotope signatures of local sources in MOR sulfides indicates that isotope ratios from ancient analogues ca be used as accurate reflections of ancient oceanic crustal values in ophiolite-hosted deposits and continental crustal averages in sediment-hosted deposits. The preservation of primary ophiolitic or continental crustal Pb isotope signatures in ancient MOR sulfides provides a powerful tool for investigation of crustal evolution and for fingerprinting ancient terranes.

  6. Provenance and sedimentary environments of the Proterozoic São Roque Group, SE-Brazil: Contributions from petrography, geochemistry and Sm-Nd isotopic systematics of metasedimentary rocks

    NASA Astrophysics Data System (ADS)

    Henrique-Pinto, R.; Janasi, V. A.; Tassinari, C. C. G.; Carvalho, B. B.; Cioffi, C. R.; Stríkis, N. M.

    2015-11-01

    The Proterozoic metasedimentary sequences exposed in the São Roque Domain (Apiaí Terrane, Ribeira Belt, southeast Brazil) consist of metasandstones and meta-felspathic wackes with some volcanic layers of within-plate geochemical signature (Boturuna Formation), a passive margin turbidite sequence of metawackes and metamudstones (Piragibu Formation), and volcano-sedimentary sequences with MORB-like basalts (Serra do Itaberaba Group; Pirapora do Bom Jesus Formation). A combination of zircon provenance studies in metasandstones, whole-rock geochemistry and Sm-Nd isotopic systematics in metamudstones was used to understand the provenance and tectonic significance of these sequences, and their implications to the evolution of the Precambrian crust in the region. Whole-rock geochemistry of metamudstones, dominantly from the Piragibu Formation, points to largely granitic sources (as indicated for instance by LREE-rich moderately fractionated REE patterns and subtle negative Eu anomalies) with some mafic contribution (responding for higher contents of Fe2O3, MgO, V, and Cr) and were subject to moderate weathering (CIA - 51 to 85). Sm-Nd isotope data show three main peaks of Nd TDM ages at ca. 1.9, 2.1 and 2.4 Ga; the younger ages define an upper limit for the deposition of the unit, and reflect greater contributions from sources younger than the >2.1 Ga basement. The coincident age peaks of Nd TDM and U-Pb detrital zircons at 2.1-2.2 Ga and 2.4-2.5 Ga, combined with the possible presence of a small amount of zircons derived from mafic (gabbroid) sources with the same ages, as indicated by a parallel LA-ICPMS U-Pb dating study in metapsammites, are suggestive that these were major periods of crustal growth in the sources involving not only crust recycling but also some juvenile addition. A derivation from similar older Proterozoic sources deposited in a passive margin basin is consistent with the main sedimentary sequences in the São Roque Domain being broadly coeval and

  7. Coupling Meteorology, Metal Concentrations, and Pb Isotopes for Source Attribution in Archived Precipitation Samples

    EPA Science Inventory

    A technique that couples lead (Pb) isotopes and multi-element concentrations with meteorological analysis was used to assess source contributions to precipitation samples at the Bondville, Illinois USA National Trends Network (NTN) site. Precipitation samples collected over a 16 ...

  8. Basalt Pb isotope analysis and the prehistoric settlement of Polynesia.

    PubMed

    Weisler, M I; Woodhead, J D

    1995-03-14

    The prehistoric settlement of the Pacific Ocean has intrigued scholars and stimulated anthropological debate for the past two centuries. Colonized over a few millennia during the mid to late Holocene, the islands of the Pacific--displaying a wide diversity of geological and biotic variability--provided the stage for endless "natural experiments" in human adaptation. Crucial to understanding the evolution and transformation of island societies is documenting the relative degree of interisland contacts after island colonization. In the western Pacific, ideal materials for archaeologically documenting interisland contact--obsidian, pottery, and shell ornaments--are absent or of limited geographic distribution in Polynesia. Consequently, archaeologists have relied increasingly on fine-grained basalt artifacts as a means for documenting colonization routes and subsequent interisland contacts. Routinely used x-ray fluorescence characterization of oceanic island basalt has some problems for discriminating source rocks and artifacts in provenance studies. The variation in trace and major element abundances is largely controlled by near-surface magma-chamber processes and is broadly similar between most oceanic islands. We demonstrate that Pb isotope analysis accurately discriminates rock source and is an excellent technique for charting the scale, frequency, and temporal span of imported fine-grained basalt artifacts found throughout Polynesia. The technique adds another tool for addressing evolutionary models of interaction, isolation, and cultural divergence in the eastern Pacific. PMID:7892194

  9. Climate Forcing on the Sedimentary Pb Isotope Record of the Equatorial Atlantic

    NASA Astrophysics Data System (ADS)

    Abouchami, W.; Zabel, M.

    2001-12-01

    The forcing mechanism for the radiogenic isotopes variations recorded in marine sediments over the past few million years remains debatable and a causal link between isotope tracers and climate is difficult to ascertain. We report evidence for a climate control on Pb sources to the Equatorial Atlantic using high precision Pb triple spike data (Galer, 1999) on two sediments cores covering the last six Marine Isotope Stages ( ~200 ka). Core GeoB1523-1 (3° 49,9'N, 41° 37.3'W, 3292m) is located on the Ceará Rise (West Atlantic) close to the Amazon mouth and core GeoB2910-1 (4° 50.7'N, 21° 03.2'W, 2703m) on the Sierra Leone Rise (East Atlantic) on the downwind trajectory of the boreal winter Saharan dust plume. These cores are ideally situated for monitoring climate-related Pb isotopic variations, since they have been shown to record past variations in terrigenous fluxes in response to Earth's orbital changes (Zabel et al., 1999; Rühlemann et al., 2001). Pb isotope data were obtained on bulk sediments which, given the two orders of magnitude difference in Pb contents of detritus ( ~10ppm) and carbonate (1-10ppb), will essentially reflect the composition of the terrigenous fraction. Pb isotope ratios display periodic fluctuations over the last ~200 ka in both cores and are quite distinct in the two basins. The east Atlantic core exhibits higher 207Pb/204Pb and 208Pb/204Pb but lower 206Pb/204Pb than the west Atlantic core. The Pb isotope signal is cyclical and closely follows the \\delta 18O record, interglacial periods being systematically more radiogenic than glacial periods. This pattern is observed in both cores, although changes in the western Atlantic seem to lead those in the eastern Atlantic. In Pb isotope space, the west Atlantic data form a unique Pb isotope array that is quite distinct from the east Atlantic where two trends are found. This clearly demonstrates that the Pb sources feeding the two basins are different. Furthermore, the persistence of a

  10. Reactive transport modelling of biogeochemical processes and carbon isotope geochemistry inside a landfill leachate plume

    NASA Astrophysics Data System (ADS)

    van Breukelen, Boris M.; Griffioen, Jasper; Röling, Wilfred F. M.; van Verseveld, Henk W.

    2004-06-01

    The biogeochemical processes governing leachate attenuation inside a landfill leachate plume (Banisveld, the Netherlands) were revealed and quantified using the 1D reactive transport model PHREEQC-2. Biodegradation of dissolved organic carbon (DOC) was simulated assuming first-order oxidation of two DOC fractions with different reactivity, and was coupled to reductive dissolution of iron oxide. The following secondary geochemical processes were required in the model to match observations: kinetic precipitation of calcite and siderite, cation exchange, proton buffering and degassing. Rate constants for DOC oxidation and carbonate mineral precipitation were determined, and other model parameters were optimized using the nonlinear optimization program PEST by means of matching hydrochemical observations closely (pH, DIC, DOC, Na, K, Ca, Mg, NH 4, Fe(II), SO 4, Cl, CH 4, saturation index of calcite and siderite). The modelling demonstrated the relevance and impact of various secondary geochemical processes on leachate plume evolution. Concomitant precipitation of siderite masked the act of iron reduction. Cation exchange resulted in release of Fe(II) from the pristine anaerobic aquifer to the leachate. Degassing, triggered by elevated CO 2 pressures caused by carbonate precipitation and proton buffering at the front of the plume, explained the observed downstream decrease in methane concentration. Simulation of the carbon isotope geochemistry independently supported the proposed reaction network.

  11. Reactive transport modelling of biogeochemical processes and carbon isotope geochemistry inside a landfill leachate plume.

    PubMed

    van Breukelen, Boris M; Griffioen, Jasper; Röling, Wilfred F M; van Verseveld, Henk W

    2004-06-01

    The biogeochemical processes governing leachate attenuation inside a landfill leachate plume (Banisveld, the Netherlands) were revealed and quantified using the 1D reactive transport model PHREEQC-2. Biodegradation of dissolved organic carbon (DOC) was simulated assuming first-order oxidation of two DOC fractions with different reactivity, and was coupled to reductive dissolution of iron oxide. The following secondary geochemical processes were required in the model to match observations: kinetic precipitation of calcite and siderite, cation exchange, proton buffering and degassing. Rate constants for DOC oxidation and carbonate mineral precipitation were determined, and other model parameters were optimized using the nonlinear optimization program PEST by means of matching hydrochemical observations closely (pH, DIC, DOC, Na, K, Ca, Mg, NH4, Fe(II), SO4, Cl, CH4, saturation index of calcite and siderite). The modelling demonstrated the relevance and impact of various secondary geochemical processes on leachate plume evolution. Concomitant precipitation of siderite masked the act of iron reduction. Cation exchange resulted in release of Fe(II) from the pristine anaerobic aquifer to the leachate. Degassing, triggered by elevated CO2 pressures caused by carbonate precipitation and proton buffering at the front of the plume, explained the observed downstream decrease in methane concentration. Simulation of the carbon isotope geochemistry independently supported the proposed reaction network. PMID:15134877

  12. The growth of the continental crust: Constraints from radiogenic isotope geochemistry

    NASA Technical Reports Server (NTRS)

    Taylor, Paul N.

    1988-01-01

    Most models for evolution of continental crust are expressed in the form of a diagram illustrating the cumulative crustal mass (normalized relative to the present crustal mass) as a function of time. Thus, geochronological data inevitably play a major role in either constructing or testing crustal growth models. For all models, determining the start-time for effective crustal accretion is of vital importance. To this end, the continuing search for, and reliable characterization of, the most ancient crustal rock-units remains a worthy enterprise. Another important role for geochronology and radiogenic isotope geochemistry is to assess the status of major geological events as period either of new crust generation or of reworking of earlier formed continental crust. For age characterization of major geological provinces, using the critieria outined, the mass (or volume) of crust surviving to the present day should be determinable as a function of crust formation age. More recent developments, however, appear to set severe limitations on recycling of crust, at least by the process of sediment subduction. In modeling crustal growth without recycling, valuable constaints on growth rate variations through time can be provided if variations in the average age of the continental crust can be monitored through geological history. The question of the average age of the exposed continental crust was addressed by determining Sm-Nd crustal residence model ages (T-CR) for fine-grained sediment loads of many of the world's major rivers.

  13. A routine high-precision method for Lu-Hf isotope geochemistry and chronology

    USGS Publications Warehouse

    Patchett, P.J.; Tatsumoto, M.

    1981-01-01

    A method for chemical separation of Lu and Hf from rock, meteorite and mineral samples is described, together with a much improved mass spectrometric running technique for Hf. This allows (i) geo- and cosmochronology using the176Lu???176Hf+??- decay scheme, and (ii) geochemical studies of planetary processes in the earth and moon. Chemical yields for the three-stage ion-exchange column procedure average 90% for Hf. Chemical blanks are <0.2 ng for Lu and Hf. From 1 ??g of Hf, a total ion current of 0.5??10-11 Ampere can be maintained for 3-5 h, yielding 0.01-0.03% precision on the ratio176Hf/177Hf. Normalisation to179Hf/177Hf=0.7325 is used. Extensive results for the Johnson Matthey Hf standard JMC 475 are presented, and this sample is urged as an international mass spectrometric standard; suitable aliquots, prepared from a single batch of JMC 475, are available from Denver. Lu-Hf analyses of the standard rocks BCR-1 and JB-1 are given. The potential of the Lu-Hf method in isotope geochemistry is assessed. ?? 1980 Springer-Verlag.

  14. The lead (Pb) isotope signature, behaviour and fate of traffic-related lead pollution in roadside soils in The Netherlands.

    PubMed

    Walraven, N; van Os, B J H; Klaver, G Th; Middelburg, J J; Davies, G R

    2014-02-15

    In this study the origin, behaviour and fate of anthropogenic Pb in sandy roadside soils were assessed by measuring soil characteristics, Pb isotope composition and content. In 1991 and 2003 samples were taken at different depth intervals at approximately 8 and 75 m from two highways in The Netherlands. The Pb isotope composition of the litter layer ((206)Pb/(207)Pb=1.12-1.14) differs from the deeper soil samples ((206)Pb/(207)Pb=1.20-1.21). Based on a mixing model it is concluded that the samples contain two Pb sources: natural Pb and anthropogenic Pb, the latter mainly derived from gasoline. (206)Pb/(207)Pb ratios demonstrate that the roadside soils were polluted to a depth of ~15 cm. Within this depth interval, anthropogenic Pb content is associated with organic matter. Although Pb pollution only reached a depth of ~15 cm, this does not mean that the topsoils retain all anthropogenic Pb. Due to the low pH and negligible binding capacity of soils at depths >15 cm, anthropogenic Pb migrated towards groundwater after reaching depths of >15 cm. The Pb isotope composition of the groundwater ((206)Pb/(207)Pb=1.135-1.185) establishes that groundwater is polluted with anthropogenic Pb. The contribution of anthropogenic Pb to the groundwater varies between ~30 and 100%. Based on the difference in soil Pb content and Pb isotope compositions over a period of 12 years, downward Pb migration is calculated to vary from 72 ± 95 to 324 ± 279 mg m(-2)y(-1). Assuming that the downward Pb flux is constant over time, it is calculated that 35-90% of the atmospherically delivered Pb has migrated to the groundwater. PMID:24342096

  15. Isotopic signatures for natural versus anthropogenic Pb in high-altitude Mt. Everest ice cores during the past 800 years.

    PubMed

    Lee, Khanghyun; Hur, Soon Do; Hou, Shugui; Burn-Nunes, Laurie J; Hong, Sungmin; Barbante, Carlo; Boutron, Claude F; Rosman, Kevin J R

    2011-12-15

    A long-term record, extending back 800 years (1205 to 2002 AD), of the Pb isotopic composition ((206)Pb/(207)Pb and (208)Pb/(207)Pb) as well as Pb concentrations from high altitude Mt. Everest ice cores has the potential to identify sources and source regions affecting natural and anthropogenic Pb deposition in central Asia. The results show that the regional natural background Pb isotope signature (~1.20 for (206)Pb/(207)Pb and ~2.50 for (208)Pb/(207)Pb) in the central Himalayas was dominated by mineral dust over the last ~750 years from 1205 to 1960s, mostly originating from local sources with occasional contributions of long-range transported dust probably from Sahara desert and northwestern India. Since the 1970s, the Pb isotope ratios are characterized by a continuous decline toward less radiogenic ratios with the least mean ratios of 1.178 for (206)Pb/(207)Pb and 2.471 for (208)Pb/(207)Pb in the period 1990-1996. The depression of the (206)Pb/(207)Pb and (208)Pb/(207)Pb values during the corresponding periods is most likely due to an increasing influence of less radiogenic Pb of anthropogenic origin mainly from leaded gasoline used in South Asia (India as well as possibly Bangladesh and Nepal). From 1997 to 2002, isotopic composition tends to show a shift to slightly more radiogenic signature. This is likely attributed to reducing Pb emissions from leaded gasoline in source regions, coinciding with the nationwide reduction of Pb in gasoline and subsequent phase-out of leaded gasoline in South Asia since 1997. An interesting feature is the relatively high levels of Pb concentrations and enrichment factors (EF) between 1997 and 2002. Although the reason for this feature remains uncertain, it would be probably linked with an increasing influence of anthropogenic Pb emitted from other sources such as fossil fuel combustion and non-ferrous metal production. PMID:22047738

  16. Geochemistry of the Ediacaran-Early Cambrian transition in Central Iberia: Tectonic setting and isotopic sources

    NASA Astrophysics Data System (ADS)

    Fuenlabrada, José Manuel; Pieren, Agustín P.; Díez Fernández, Rubén; Sánchez Martínez, Sonia; Arenas, Ricardo

    2016-06-01

    A complete Ediacaran-Early Cambrian stratigraphic transition can be observed in the southern part of the Central Iberian Zone (Iberian Massif). Two different stratigraphic units, underlying Ordovician series, display geochemical and Sm-Nd isotopic features in agreement with an evolving geodynamic setting. Pusa Shales (Early Cambrian) rest unconformably on greywackes of the Lower Alcudian Formation (Late Ediacaran). Both sequences present minor compositional variations for major and trace element contents and similar REE patterns, close to those of PAAS (Post Archean Australian Shale). Trace element contents and element ratios suggest mixed sources, with intermediate to felsic igneous contributions for both units. Tectonic setting discrimination diagrams for the Ediacaran greywackes indicate that these turbiditic series were deposited in a sedimentary basin associated with a mature active margin (volcanic arc). However, the compositions of the Cambrian shales fit better with a more stable context, a back-arc or retro-arc setting. εNd(T) and TDM ages are compatible with dominance of a similar cratonic source for both sequences, probably the West Africa Craton. εNd565 values for the Ediacaran greywackes (- 3.0 to - 1.4) along with TDM ages (1256-1334 Ma) imply a significant contribution of juvenile material, probably derived from the erosion of the volcanic arc. However, εNd530 values in the Cambrian shales (- 5.2 to - 4.0) together with older TDM ages (1444-1657 Ma), suggest a higher contribution of cratonic isotopic sources, probably derived from erosion of the adjacent mainland. Coeval with the progressive cessation of arc volcanism along the peri-Gondwanan realm during the Cambrian, there was a period of more tectonic stability and increasing arrival of sediments from cratonic areas. The geochemistry of the Ediacaran-Cambrian transition in Central Iberia documents a tectonic switch in the periphery of Gondwana, from an active margin to a more stable context

  17. Mass-dependent and -independent fractionation of isotopes in Ni and Pb chelate complex formation reactions

    NASA Astrophysics Data System (ADS)

    Nomura, Masao; Kudo, Takashi; Adachi, Atsuhiko; Aida, Masao; Fujii, Yasuhiko

    2013-11-01

    Mass independent fractionation (MIF) has been a very interesting topic in the field of inorganic isotope chemistry, in particular, geo- and cosmo- chemistry. In the present work, we studied the isotope fractionation of Ni(II) and Pb(II) ions in complex formation with chelating reagent EDTA. To obtain clear results on the mass dependence of the isotope fractionation, we have conducted long-distance ion exchange chromatography of Ni(II) and Pb(II), using chelate complex reagent EDTA. The results apparently show that the isotope fractionation in Ni complex formation system is governed by the mass dependent rule. On the other hand the isotope fractionation in the Pb complex system is governed by the mass independent rule or the nuclear volume effect.

  18. Mass-dependent and -independent fractionation of isotopes in Ni and Pb chelate complex formation reactions

    SciTech Connect

    Nomura, Masao; Kudo, Takashi; Adachi, Atsuhiko; Aida, Masao; Fujii, Yasuhiko

    2013-11-13

    Mass independent fractionation (MIF) has been a very interesting topic in the field of inorganic isotope chemistry, in particular, geo- and cosmo- chemistry. In the present work, we studied the isotope fractionation of Ni(II) and Pb(II) ions in complex formation with chelating reagent EDTA. To obtain clear results on the mass dependence of the isotope fractionation, we have conducted long-distance ion exchange chromatography of Ni(II) and Pb(II), using chelate complex reagent EDTA. The results apparently show that the isotope fractionation in Ni complex formation system is governed by the mass dependent rule. On the other hand the isotope fractionation in the Pb complex system is governed by the mass independent rule or the nuclear volume effect.

  19. Pb, Sr, and Nd isotopes in basalts and sulfides from the Juan de Fuca Ridge

    SciTech Connect

    Hegner, E.; Tatsumoto, M.

    1987-10-10

    Pb, Sr, Nd isotopes of seven basalt glasses collected by the submersible Alvin from the southern Juan de Fuca Ridge (SJFR) are almost identical (/sup 206/Pb//sup 204/Pbapprox.18.45, /sup 207/Pb//sup 204/Pbapprox.15.47, /sup 208/Pb//sup 204/Pbapprox.37.81, /sup 87/Sr//sup 86/Srapprox.0.70249, /sup 143/Nd//sup 144/Ndapprox.0.51315). Whereas all basalts appear cogenetic, four of the samples have uniform abundances of U, Th, Rb, Nd, Sm, Pb, and Sr, indicating that they are also comagmatic. Two basalt glasses dredged previously at the SJFR have similar isotopic compositions but higher concentrations of U, Th, and Pb. The /sup 206/Pb//sup 204/Pb ratios are intermediate between generally less radiogenic ridge basalts from south of the Juan de Fuca Ridge (JFR) and often more radiogenic basalts from the northern JFR and NE Pacific seamounts. Sr and Nd isotopic compositions closely resemble data of other ridge basalts from the northernmost East Pacific Rise and are intermediate between isotopically more diverse seamount basalts produced nearby.

  20. Tracing of industrial aerosol sources in an urban environment using Pb, Sr, and Nd isotopes.

    PubMed

    Geagea, Majdi Lahd; Stille, Peter; Gauthier-Lafaye, François; Millet, Maurice

    2008-02-01

    A comprehensive Pb-Sr-Nd isotope tracer study of atmospheric trace metal pollution has been performed in the urban environment of Strasbourg-Kehl. Filter dust of the principal pollutant sources (waste incinerators, thermal power plant and steel plant) and soot of car and ship exhausts have been analyzed. In addition tree barks (as biomonitors) and PM10 have been analyzed to trace and determine the distribution of the pollution in the environment. The industrial sources have highly variable epsilonNd values (-9.7 and -12.5 for incinerators and -17.5 for steel plant). Much higher epsilonNd values have been found for soot of car exhausts (-6 and -6.9). These high values make the Nd isotope system a powerful tool for the discrimination of traffic emissions but especially for the identification of diesel derived particles in the urban environment. The 206Pb/207Pb isotope ratios of gasoline are low (1.089) compared to diesel soot (1.159). The 26Pb/207Pb ratios of 1.151-1.152 for the steel plant and 1.152 for the solid waste incinerator are close to the Pb isotope ratio of diesel. The 87Sr/ 8Sr isotope ratios of the principal industrial sources vary significantly: 0.7095 for the domestic solid waste incinerator, 0.709 for the steel plant, and 0.7087 for car exhaust soot. PM10 aerosols collected in the urban center of Strasbourg show the influence of the pollutant sources at 3-7 km distance from the center. Most of the aerosols Pb isotopic compositions suggest Pb admixtures from at least three sources: a natural background and in function of the wind direction the domestic waste incinerator (S-wind) or the steel plant and the chemical waste incinerator (NE-wind). The traffic contribution can only be estimated with help of Nd isotopes. Therefore the clear identification of different pollutant sources in the urban environment is only possible by combining the three different isotope systems and is based on the fact that significant differences exist between the Pb, Sr, and

  1. RECONSTRUCTING LAURENTIDE ICE SHEET MELTWATER GEOCHEMISTRY USING COMBINED STABLE ISOTOPE AND LASER ABLATION TRACE ELEMENT ANALYSES

    NASA Astrophysics Data System (ADS)

    Vetter, L.; Spero, H. J.; Eggins, S. M.; Flower, B. P.; Williams, C. C.

    2009-12-01

    Little is known about the oxygen isotope evolution of Northern hemisphere ice sheets during past glacial cycles, with the exception of results from models and calculations based on whole ocean δ18O change. Reconstructing changes in the δ18Owater of the global ocean assumes a homogeneous δ18O value for contributions from Northern hemisphere ice sheets with a mass balance contribution from the Southern hemisphere. Because oceanic δ18Ow forms a crucial baseline for deconvolving the combined signal of temperature and hydrologic changes recorded in foraminiferal calcite, constraints on the contributions of melting ice sheets form a fundamental component of reconstructions of global ocean δ18Ow changes on glacial timescales. Here we present a novel geochemical technique to compute the oxygen isotopic composition of Laurentide Ice Sheet (LIS) meltwater flowing into the Gulf of Mexico during periods of rapid ice sheet melting. The technique combines data from different types of geochemical analyses on individual shells of the planktonic foraminifera Orbulina universa to compute meltwater geochemistry, using laser ablation ICP-MS to measure Mg/Ca (a temperature proxy) and Ba/Ca (a salinity proxy) and isotope ratio mass spectrometry to measure δ18O (a temperature and δ18Owater proxy) on remaining shell material. O. universa has a very large temperature and salinity tolerance (9-30°C; 23-45 psu) and broad depth habitat (0-80 m), so an assemblage of individual shells from a single core interval records a range of water conditions. We have selected deglacial meltwater intervals from core MD02-2550 (26.95°N, 91.35°W, 2245 m water depth), collected from the anoxic Orca Basin in the Gulf of Mexico, for a proof of concept demonstration. From each interval, we combine measurements of Mg/Ca, Ba/Ca, and δ18O on 30-100 individual O. universa. The δ18O from each shell reflects the combined influence of temperature and δ18Owater, where this latter value is a function of

  2. Production and in vivo imaging of (203)Pb as a surrogate isotope for in vivo (212)Pb internal absorbed dose studies.

    PubMed

    Máthé, Domokos; Szigeti, Krisztián; Hegedűs, Nikolett; Horváth, Ildikó; Veres, Dániel S; Kovács, Béla; Szűcs, Zoltán

    2016-08-01

    (212)Pb is a clinically relevant therapeutic alpha emitter isotope. A surrogate, (203)Pb, if prepared with sufficiently high specific activity could be used to estimate (212)Pb in vivo absorbed doses. An improved production procedure of (203)Pb with a simple, new separation method and high specific radioactivity for imaging is reported. We determined the in-vivo biodistribution of (203)Pb in mice by SPECT/CT. This highlights application possibilities of (203)Pb for further in vivo and clinical uses (radiolabeled (212)Pb-peptide co-injection, dosimetry calculation). PMID:27156049

  3. Elucidating the construction of the Austurhorn Intrusion, SE Iceland, using zircon elemental and isotopic geochemistry and geochronology

    NASA Astrophysics Data System (ADS)

    Padilla, A. J.; Miller, C. F.; Carley, T. L.; Economos, R. C.; Schmitt, A. K.; Fisher, C. M.; Hanchar, J. M.; Bindeman, I. N.; Wooden, J. L.; Sigmarsson, O.

    2013-12-01

    The Austurhorn Intrusive Complex (AIC) in SE Iceland comprises large bodies of granophyre, gabbro, and a mafic-felsic composite zone (MFCZ) that exemplifies mafic-felsic interactions common in Icelandic silicic systems. However, despite being one of Iceland's best-studied intrusions (Blake 1966; Furman et al 1992a,b; Thorarinsson & Tegner 2009), few studies have included detailed analyses of zircon, a mineral widely recognized as a valuable tracer of the history and evolution of its parental magma(s). In this study, we employ in-situ zircon elemental and isotopic (hafnium and oxygen) geochemistry, as well as U-Pb geochronology, as tools for elucidating the complex construction and magmatic evolution of Austurhorn's MFCZ. The elemental compositions of AIC zircons form a broad but coherent array partly overlapping with the zircon geochemical signature for Icelandic silicic volcanic rocks (Carley et al 2011). With some exceptions (see below), Hf concentrations are low (less than 10,000 ppm), typical of Icelandic zircon, and Ti concentrations range from 6 to 25 ppm (Ti-in-zircon temps. 730-870°C). Their δ18O values are generally well-constrained at +2.5 to +4 ‰, consistent with other Icelandic magmatic zircon (Bindeman et al 2012) and preserving evidence for partial melting of hydrothermally-altered crust as the source of silicic magmas within the Austurhorn system. Epsilon-Hf values cluster tightly at +13×1 ɛ-units, suggesting a single source for the different units of the MFCZ. The notable exceptions to the trends described above are zircons from a high-silica granophyre displaying CL-dark zones and convoluted zoning. These fall well outside the AIC geochemical arrays, primarily distinguished by high Hf (up to 24,000 ppm) and lower Ti (down to 2 ppm), far higher Hf and lower Ti than any other analyzed Icelandic zircon, and extremely low δ18O values (down to -6 ‰). We interpret these to reflect multiple episodes of partial melting and melt extraction of the

  4. Pb isotope constaints on the extent of crustal recycling into a steady state mantle

    NASA Technical Reports Server (NTRS)

    Galer, S. J. G.; Goldstein, S. L.; Onions, R. K.

    1988-01-01

    Isotopic and geochemical evidence was discussed against recycling of continental crust into the mantle. Element ratios such as Sm/Nd, Th/Sc, and U/Pb in sedimentary masses have remained relatively constant throughout Earth history, and this can only be reconciled with steady state recycling models if new crustal materials added from the mantle have had similar ratios. Such recycling models would also require shorter processing times for U, Th, and Pb through the mantle than are geodynamically reasonable. Models favoring subduction of pelagic sediments as the only recycling mechanism fail to account for the Pb isotopic signature of the mantle. Recycling of bulk crust with Pb isotopic compositions similar to those expected for primitive mantle would be permissable with available data, but there appear to be no plausible tectonic mechanisms to carry this out.

  5. Sr, Nd, and Pb isotopic character of Tertiary basalts from southwest Poland

    NASA Astrophysics Data System (ADS)

    Blusztajn, Jerzy; Hart, Stanley R.

    1989-10-01

    Tertiary basaltic volcanics from southwest Poland which form the eastern part of the Central European Volcanic Province (CEVP) have been studied for Sr, Nd, and Pb isotopic compositions. 87Sr/86Sr ratios range from 0.70317 to 0.70369, 143Nd/144Nd ratios range from 0.51285 to 0.51302 and Pb isotopic compositions range from 19.42 to 19.94 for 206Pb/204Pb. These data indicate the influence of three end-member mantle components DMM, HIMU and EM. An analysis of all isotopic results from the CEVP leads to the conclusion that basalts from SW Poland have the most depleted character. We propose a model whereby the depleted source mantle for the CEVP interacted with enriched components (EM). The western part of the CEVP was enriched on a larger scale than the eastern part, probably due to the influence of the Rhine Graben rift.

  6. Origin of the Honolulu Volcanics Series (Oahu, Hawaii) From High Precision Pb Isotope Data

    NASA Astrophysics Data System (ADS)

    Fekiacova, Z.; Abouchami, W.; Galer, S. J.; Garcia, M. O.

    2005-12-01

    The origin and sources of rejuvenated volcanism in Hawaii has been long debated with the depleted isotopic features commonly attributed to assimilation of the 110 Ma-old Pacific oceanic lithosphere underlying Hawaii. Alternatively, it has been recently suggested that this depleted component is a long-lived feature intrinsic to the Hawaiian plume [1, 2]. Here, we report triple-spike Pb isotope data on lavas erupted from the different evolutionary stages of Koolau volcano, including the rejuvenated Honolulu Volcanics Series (HVS), the main shield stage lavas, sampled by the Koolau Scientific Drilling Project (KSDP) and late-shield Makapuu subaerial lavas [3]. These data demonstrate the existence of compositional source variations throughout the evolution of the volcano. In addition, we obtained new Pb isotope data on basalts from ODP Site 843, located 225 km southwest of Honolulu which sampled 110 Ma-old Pacific crust. If these data are representative of the local oceanic crust and mantle, then the Hawaiian Pacific lithosphere is not a viable source component for the rejuvenated Honolulu Volcanics. Despite a narrow range in Pb isotope ratios, both the KSDP and HVS lavas define linear isotope arrays in Pb isotope space. While the two arrays have distinct slopes in 208Pb-206Pb space, suggesting the involvement of at least three Pb components, the two datasets overlap in 207Pb-206Pb space due to the extremely limited variation (< 1per mil) in 207Pb/204Pb ratios. By comparison, ODP site 843 basalts have significantly more radiogenic Pb isotopic compositions and form a linear Pb isotope array distinct from that of the HVS, although lying within the field of present-day EPR MORB [4]. Thus, there appears to be no major differences in the Pb isotopic character of ''old'' vs. ''young'' Pacific MORB. We infer that three distinct Pb components were involved in the source of Koolau: (1) an EM-type component, corresponding to the so-called ''Koolau component'', predominantly

  7. Using Pb isotopes in surface media to distinguish anthropogenic sources from undercover uranium sources

    NASA Astrophysics Data System (ADS)

    Kyser, Kurt; Lahusen, Larry; Drever, Garth; Dunn, Colin; Leduc, Evelyne; Chipley, Don

    2015-09-01

    The response in elemental concentrations and Pb isotopes in various surface media from the Cigar West unconformity-type uranium deposit located at a depth of 450 m were measured to ascertain if element migration from the deposit can be detected at the surface. The media included clay-size fractions separated from the A2, B and C soil horizons, and tree cores and twigs from black spruce (Picea mariana) and jack pine (Pinus banksiana) trees. Lead isotopes were used to trace any effect on the surface media from the deposit at depth because the 207Pb/206Pb ratios in the ore are < 0.1, whereas the background values in the basin are > 0.7 and modern anthropogenic Pb from aerosols are near 0.9. The tree cores record their lowest and therefore most radiogenic 207Pb/206Pb ratios of < 0.7 near the surface projection of the deposit and associated structures, particularly in tree rings that predate any exploration and drilling activity in the area. The median 207Pb/206Pb ratios increase in the order C, B soil horizon clays, tree cores, A2 soil clays and twigs because of the increasing contribution of common Pb with high ratios from anthropogenic sources that affect the shallowest media the most. Although this anthropogenic Pb as well as that from the background dominates the composition of all media at the surface and the contribution from the deposit at depth is diminished toward the surface, ore-related Pb is still present as a few percent of the composition of pathfinder elements and Pb isotopes.

  8. Evidencing the Impact of Coastal Contaminated Sediments on Mussels Through Pb Stable Isotopes Composition.

    PubMed

    Dang, Duc Huy; Schäfer, Jörg; Brach-Papa, Christophe; Lenoble, Véronique; Durrieu, Gaël; Dutruch, Lionel; Chiffoleau, Jean-Francois; Gonzalez, Jean-Louis; Blanc, Gérard; Mullot, Jean-Ulrich; Mounier, Stéphane; Garnier, Cédric

    2015-10-01

    Heavily contaminated sediments are a serious concern for ecosystem quality, especially in coastal areas, where vulnerability is high due to intense anthropogenic pressure. Surface sediments (54 stations), 50 cm interface cores (five specific stations), river particles, coal and bulk Pb plate from past French Navy activities, seawater and mussels were collected in Toulon Bay (NW Mediterranean Sea). Lead content and Pb stable isotope composition have evidenced the direct impact of sediment pollution stock on both the water column quality and the living organisms, through the specific Pb isotopic signature in these considered compartments. The history of pollution events including past and present contaminant dispersion in Toulon Bay were also demonstrated by historical records of Pb content and Pb isotope ratios in sediment profiles. The sediment resuspension events, as simulated by batch experiments, could be a major factor contributing to the high Pb mobility in the considered ecosystem. A survey of Pb concentrations in surface seawater at 40 stations has revealed poor seawater quality, affecting both the dissolved fraction and suspended particles and points to marina/harbors as additional diffuse sources of dissolved Pb. PMID:26348385

  9. Pb-isotope systematics of a fossil hydrothermal system from the Troodos ophiolite, Cyprus: Evidence for a polyphased alteration history

    NASA Astrophysics Data System (ADS)

    Booij, Ernst; Bettison-Varga, Lori; Farthing, Dori; Staudigel, Hubert

    2000-10-01

    Pb-isotopic ratios have been determined on massive sulphides from the Troodos ophiolite and their inferred source rocks: epidosites and greenschist altered dikes. The latter have distinctly higher Pb-isotope ratios than the sulphides. The high 207Pb/ 204Pb ratios for the whole rocks indicate the involvement of an old (sedimentary) Pb-component. Extensive leaching of three epidosite samples shows that the radiogenic Pb can be removed and the resulting trend for the leached samples is consistent with a Pb-Pb age of ˜95 Ma for these rocks. Inferred initial Pb isotope ratios are similar to those of the sulphides (this study) and fresh glasses from the Akaki Canyon in Cyprus. Therefore the Pb incorporated in the massive sulphides may originate from these greenschist facies hydrothermally altered rocks. The isotopic composition of the leachate Pb points toward a sedimentary origin. Calculation of the Pb-isotopic ratios for 90 Ma old "average" Troodos sediment shows that the "foreign" Pb in the epidosites may very well be derived from this source. This Pb probably does not reside within the mineral lattices of these metamorphic rocks, but rather is adsorbed on mineral surfaces or is present in microscopic particulate matter that may have been filtered from the circulating seawater. Unmodified seawater is considered an unlikely Pb source because of the extremely small dissolved Pb contents of seawater. Furthermore, no seawater or sedimentary signature is evident in the sulphides. Several models of Pb transport from different sources into these rocks may be envisaged, such as dissolution of Miocene evaporites and brine formation, equilibration of pore waters to the Pb isotope ratios of host sediments, and direct infiltration of deep sea particulate matter from the nepheloid layer. With the limited amount of data presently available it is impossible to critically determine the most likely processes of Pb transport.

  10. Inorganic geochemistry data from Lake El'gygytgyn sediments: marine isotope stages 6-11

    NASA Astrophysics Data System (ADS)

    Minyuk, P. S.; Borkhodoev, V. Y.; Wennrich, V.

    2014-03-01

    Geochemical analyses were performed on sediments recovered by deep drilling at Lake El'gygytgyn in central Chukotka, northeastern Russia (67°30' N; 172°05' E). Major and rare element concentrations were determined using X-ray fluorescence spectroscopy (XRF) on the < 250 μm fraction from 617 samples dated to ca. 440 and 125 ka, which approximates marine isotope stages (MIS) 11 to 6. The inorganic geochemistry indicates significant variations in elemental composition between glaciations and interglaciations. Interglacial sediments are characterized by high contents of SiO2, Na2O, CaO, K2O, and Sr and are depleted in Al2O3, Fe2O3, TiO2, and MgO. An extreme SiO2 enrichment during MIS 11.3 and 9.3 was caused by an enhanced flux of biogenic silica (BSi). The geochemical structure of MIS 11 shows similar characteristics as seen in MIS 11 records from Lake Baikal (southeastern Siberia) and Antarctic ice cores, thereby arguing for the influence of global forcings on these records. High sediment content of TiO2, Fe2O3, MgO, Al2O3, LOI, Ni, Cr, and Zr typifies glacial stages, with the most marked increases during MIS 7.4 and 6.6. Reducing conditions during glacial times are indicated by peaks in the Fe2O3 content and coinciding low Fe2O3/MnO ratios. This conclusion also is supported by P2O5 and MnO enrichment, indicating an increased abundance of authigenic, fine-grained vivianite. Elemental ratios (CIA, CIW, PIA, and Rb/Sr) indicate that glacial sediments are depleted in mobile elements, like Na, Ca, K and Sr. This depletion was caused by changes in the sedimentation regime and thus reflects environmental changes.

  11. Magnesian anorthosites from the western highlands of the Moon: Isotope geochemistry and petrogenesis

    NASA Technical Reports Server (NTRS)

    Snyder, Gregory A.; Taylor, Lawrence A.; Halliday, Alex N.

    1993-01-01

    Breccias from the Apollo 14 landing site have provided a wealth of information on the genesis of the lunar highlands. Various pristine rock-types have been discovered in relative abundance including rare ferroan anorthosites and alkali-suite and magnesian-suite rocks. Mineral-chemical and radiogenic isotopic data are reported here for a newly discovered Mg-suite anorthosite from Apollo 14, sample 14303,347. Meyer et al. reported U-Pb zircon analyses of Mg-suite highlands rocks from the western limb of the Moon. We have compiled these ages and generated a weighted average age of 4211 = 6 Ma; some 200 Ma younger than ferroan anorthosites. Utilizing this age for Mg-anorthosite 14303,347, our data results in an initial epsilon(sub Nd) value of -1.0 and initial Sr-87/Sr-86 of 0.69915. Based on trace-element, isotopic, and mineral-chemical data, the western highlands Mg-suite is interpreted to be crustal precipitates of a picritic magma, which assimilated KREEPy trapped liquid from upper-mantle cumulates during its transport to the crust.

  12. Deciphering The Sources Of Cenozoic Volcanism In Central Mongolia Using Trace Element And Isotope Geochemistry

    NASA Astrophysics Data System (ADS)

    Hunt, A. C.; Parkinson, I. J.; Harris, N.; Rogers, N. W.; Barry, T.; Yondon, M.

    2009-12-01

    One of the largest regions of Cenozoic intra-plate volcanism stretches across central Asia from the Baikal Rift in Siberia, through central Mongolia to China. In Mongolia this is expressed as numerous small-volume alkali-basaltic cones and lavas, erupted since ca. 30 Ma. Currently, accepted models of melt generation for intraplate magmatism, such as mantle plumes, lithospheric extension and convective removal of the lithosphere, are difficult to reconcile with some aspects of volcanism and tectonics in this region. A suite of basalts erupted across an area of Cenozoic uplift in central Mongolia, known as the Hangai Dome, has been analysed for trace elements and Sr-Nd-Pb isotopes. New Pb isotope data were collected by double spike MC-ICP-MS at the Open University and have a long-term 2σ reproducibility better than 175 ppm for NBS 981. These data suggest progressive mixing between two distinct source regions in the genesis of the Hangai basalts. Older basalts, previously dated at 5.91 ± 0.02 Ma (Barry et al., 2003), are derived from a component with an asthenospheric signature similar to depleted Indian MORB. Younger basalts are increasingly mixed with a component with lower Pb and Sr ratios and an enriched trace element signature, which is similar in composition to some lamproites erupted in the western USA (Mirnejad and Bell, 2006). This represents a transition from asthenospheric to lithospheric melting through time. Furthermore, studies on mantle xenoliths from across the Hangai Dome indicate an elevated geotherm under the centre of the dome and significantly cooler conditions at its margins, interpreted to be the result of mantle upwellling (Harris et al., in review). Further numerical modelling will assess the relative contributions from lithospheric and asthenospheric sources in the genesis of these basalts, and contribute to understanding this enigmatic volcanic region. Barry, T. L., Saunders, A. D., Kempton, P. D., Windley, B.F., Pringle, M.S., Dorjnamjaa

  13. Genesis of the Bangbule Pb-Zn-Cu polymetallic deposit in Tibet, western China: Evidence from zircon U-Pb geochronology and S-Pb isotopes

    NASA Astrophysics Data System (ADS)

    Kan, Tian; Zheng, Youye; Gao, Shunbao

    2016-04-01

    The Banbule Pb-Zn-Cu skarn deposit is located in the Longger-Gongbujiangda volcanic magma arc in the Gangdese-Nyainqentanglha Plate. It is the only lead-zinc polymetallic deposit discovered in the westernmost Nyainqentanglha metallogenic belt. The measured and indicated resources include 0.9 Mt of Pb+Zn (4.77% Pb and 4.74% Zn, respectively), 6499 t of Cu, and 178 t of Ag (18.75g/t Ag). The orebodies mainly occur as lenses, veins and irregular shapes in the contact zone between the quartz-porphyry and limestone of the Upper Permian Xiala Formation, or in the boundaries between limestone and sandstone. Pb-Zn-Cu mineralization in the Banbule deposit is closely associated with skarns. The ore minerals are dominated by galena, sphalerite, chalcopyrite, bornite, and magnetite, with subordinate pyrite, malachite, and azurite. The gangue minerals are mainly garnet, actinolite, diopside, quartz, and calcite. The ore-related quartz-porphyry displays LA-ICP-MS zircon U-Pb age of 77.31±0.74 Ma. The δ34S values of sulfides define a narrow range of -0.8 to 4.7‰ indicating a magmatic source for the ore-forming materials. Lead isotopic systematics yield 206Pb/204Pb of 18.698 to 18.752, 207Pb/204Pb of 15.696 to 15.760, and 208Pb/204Pb of 39.097 to 39.320. The data points are constrained around the growth curves of upper crust and orogenic belt according to the tectonic discrimination diagrams. The calculated Δβ ‑ Δγ values plot within the magmatic field according to the discrimination diagram of Zhu et al. (1995). The S-Pb isotopic data suggest that Bangbule is a typical skarn deposit, and the Pb-Zn-Cu mineralization is genetically related to the quartz-porphyry in the mining district. The discovery of the Bangbule deposit indicates that there is metallogenic potential in the westernmost Nyainqentanglha belt, which is of great importance for the exploration work in this area.

  14. Common Pb isotopic compositions of the Lima, Arequipa and Toquepala segments in the Coastal batholith, Peru: Implications for magmagenesis

    NASA Astrophysics Data System (ADS)

    Mukasa, Samuel B.

    1986-05-01

    Common-Pb isotopic compositions for 65 feldspar samples from the 188-37-Ma old gabbroic to monzogranitic plutons of the Peruvian Coastal batholith show changes along strike that can be related to variable contamination of mantle-derived magmas by the local Precambrian basement. Results have the following isotopic ranges: 206Pb/204Pb = 17.580-20.803 ; 207Pb/204Pb = 15.555-15.709 ; and 208Pb/204Pb = 38.104-41.177 . With averages of 206Pb /204Pb = 18.630 , 207Pb /204Pb = 15.610 and 208Pb /204Pb = 38.500 , the gabbroic, dioritic and tonalitic plutons north and east of Lima (the Lima segment) have ratios similar to the isotopically homogeneous reservoir identified by Tilton (1979), Tilton and Barreiro (1980), and Barreiro and Stern (1982) for rocks in central and southern Chile. The homogeneous reservoir has been suggested to be "enriched" subcontinental mantle. More siliceous rocks (granodiorites and monzogranites) in the Lima segment have considerably higher ratios ( 206Pb /204Pb = 18.680-20.803 , 207Pb /204Pb = 15.610-15.709 and 208Pb /204Pb = 38.500-41.177 ). Nine of ten monzogranites from the ring dike complexes in the Lima segment define a linear array with a slope of 0.1143 (correlation coefficient = 0.9398) and a Pb isochron age of 1.9 Ga. This isochron age has no simple chronological meaning, although it may represent a component of sedimentary debris, derived from 1.9 Ga crustal materials. Feldspars from plutons in the Arequipa and Toquepala segments south of Lima tend to have low Pb-isotopic ratios ( 206Pb /204Pb = 17.580-18.603 , 207Pb /204Pb = 15.555-15.633 and 208Pb /204Pb = 38.104-38.749 ). The ratios plot between the isotopic signatures of local Precambrian granulites and gneisses and the Chile-type "enriched" subcontinental magmatic reservoir, indicating that these end members were the principal magma sources. The oldest plutonic rocks in the segments (early- to mid-Jurassic) are closest to the Pb-isotopic ratios of the Precambrian basement

  15. Geochemistry, zircon U-Pb dating and Hf isotopies composition of Paleozoic granitoids in Jinchuan, NW China: Constraints on their petrogenesis, source characteristics and tectonic implication

    NASA Astrophysics Data System (ADS)

    Zeng, Renyu; Lai, Jianqing; Mao, Xiancheng; Li, Bin; Ju, Peijiao; Tao, Shilong

    2016-05-01

    Granitoids are widely distributed in Jinchuan at the southwestern margin of the North China plate, which is also an important area of mineral deposits. The research subject of this article are two Paleozoic granitoids, a cataclastic syenogranite and a granodiorite porphyry. This study presents whole rock geochemistry and zircon U-Pb-Hf isotope data for the two granitoids to determine their petrogenesis, source characteristics and tectonic significance. The cataclastic syenogranite is characterized by metaluminous composition with high potassium, and LaN/YbN from 39 to 48. The composition with strong negative Eu anomalies and Zircon saturation temperatures (TZr) from 947 to 1072 °C classify this intrusion as an A-type granite. The granodiorite porphyry is metaluminous with high sodium, sub-alkaline, LaN/YbN ratios from 27 to 32. These I-type intrusions have no Eu anomalies and TZr ranges from 818 to 845 °C. Both the cataclastic syenogranite and granodiorite porphyry show enrichment of LREE and LILE and depletion of HREE and HFSE, except Hf and Zr. Using single zircon LA-ICP-MS U-Pb dating, the emplacement age of the cataclastic syenogranite and granodiorite porphyry are determined at 433.4 ± 3.7 Ma and 361.7 ± 4.6 Ma, respectively. Zircons from the cataclastic syenogranits have uniform negative εHf(t) values (-11 ± 0.5 to -9 ± 0.5), implying the involvement of an old Palaeoproterozoic crustal source in magma genesis. The zircons from the granodiorite porphyry have εHf(t) values that range from -8 ± 1.0 to +10 ± 0.6, suggesting heterogeneous source materials involving both juvenile and ancient crust reworked crustal components. Based on the geological significance of granites at the southwestern margin of the North China plate, the closure of the North Qilian Ocean occurred at ∼444 Ma. Geochemical features suggest that the cataclastic syenogranite and granodiorite porphyry formed in an intraplate extensional and compressional setting, respectively. Hence

  16. Geochemistry and U-Pb zircon geochronology of the pegmatites in Ede area, southwestern Nigeria: A newly discovered oldest Pan African rock in southwestern Nigeria

    NASA Astrophysics Data System (ADS)

    Adetunji, A.; Olarewaju, V. O.; Ocan, O. O.; Ganev, V. Y.; Macheva, L.

    2016-03-01

    Field and petrographic studies, whole rock geochemistry and in-situ LA-ICP-MS geochemical and isotopic U-Pb measurements on zircons have been performed on granitic pegmatites of Ede area, southwestern Nigeria with a view to characterize them, determining their mineralization potentials, petrogenetic attributes and emplacement age. The pegmatites are hosted by migmatite gneiss complex, biotite-muscovite schist and associated quartzite. The textural and mineralogical characteristics of these pegmatites indicate the occurrence of two main varieties, namely, muscovite pegmatite and garnet pegmatite. Of less importance are inclusions and pods of graphic granite, quartz-microcline aplitic and pegmatitic bodies. At the present level of erosion, the parent igneous rocks of the pegmatites are not exposed. The two dominant pegmatite varieties show slightly different chemical peculiarities but similar peraluminous character. The average K/Rb ratios of 165 and 163, respectively, for muscovite and garnet pegmatites combined with other trace element compositions are indicative of affinity to muscovite class of pegmatite which are generally not promising for rare elements mineralization. However, the unusually high concentration of bismuth in the zircons indicates Bi mineralization in the area which can either be in the pegmatites or host rocks. The Nb/Ta ratios for both muscovite and garnet pegmatites range from 0.7 to 15.2 and 1.0 to 14.8, respectively. These Nb/Ta ratios and Eu anomalies are statistically similar for both pegmatites. These probably indicate the pegmatites crystallized from a common source but separated into crystallization paths that produced different pegmatite varieties through liquid-liquid immiscibity mechanism. In-situ measurements of REE, P, Y, Nb, Hf, Ta, Bi, Th and U of individual zircon grains show the existence of two chemically and texturally different domains which are indicative of alteration that may be due to interface-coupled dissolution

  17. Cretaceous seamounts along the continent ocean transition of the Iberian margin: U Pb ages and Pb Sr Hf isotopes

    NASA Astrophysics Data System (ADS)

    Merle, Renaud; Schärer, Urs; Girardeau, Jacques; Cornen, Guy

    2006-10-01

    To elucidate the age and origin of seamounts in the eastern North Atlantic, 54 titanite and 10 zircon fractions were dated by the U-Pb chronometer, and initial Pb, Sr, and Hf isotope ratios were measured in feldspars and zircon, respectively. Rocks analyzed are essentially trachy-andesites and trachytes dredged during the "Tore Madeira" cruise of the Atalante in 2001. The ages reveal different pulses of alkaline magmatism occurring at 104.4 ± 1.4 (2 σ) Ma and 102.8 ± 0.7 Ma on the Sponge Bob seamount, at 96.3 ± 1.0 Ma on Ashton seamount, at 92.3 ± 3.8 Ma on the Gago Coutinho seamount, at 89.3 ± 2.3 Ma and 86.5 ± 3.4 Ma on the Jo Sister volcanic complex, and at 88.3 ± 3.3 Ma, 88.2 ± 3.9, and 80.5 ± 0.9 Ma on the Tore locality. No space-time correlation is observed for alkaline volcanism in the northern section of the Tore-Madeira Rise, which occurred 20-30 m.y. after opening of the eastern North Atlantic. Initial isotope signatures are: 19.139-19.620 for 206Pb/ 204Pb, 15.544-15.828 for 207Pb/ 204Pb, 38.750-39.936 for 208Pb/ 204Pb, 0.70231-0.70340 for 87Sr/ 86Sr, and +6.9 to +12.9 for initial epsilon Hf. These signatures are different from Atlantic MORB, the Madeira Archipelago and the Azores, but they lie in the field of worldwide OIB. The Cretaceous seamounts therefore seem to be generated by melts from a OIB-type source that interact with continental lithospheric mantle lying formerly beneath Iberia and presently within the ocean-continent transition zone. Inheritance in zircon and high 207Pb of initial Pb substantiate the presence of very minor amounts of continental material in the lithospheric mantle. A long-lived thermal anomaly is the most plausible explanation for alkaline magmatism since 104 Ma and it could well be that the same anomaly is still the driving force for tertiary and quaternary alkaline magmatism in the eastern North Atlantic region. This hypothesis is agreement with the plate-tectonic position of the region since Cretaceous time

  18. Reconstruction of historical lead contamination and sources in Lake Hailing, Eastern China: a Pb isotope study.

    PubMed

    Zhang, Rui; Guan, Minglei; Shu, Yujie; Shen, Liya; Chen, Xixi; Zhang, Fan; Li, Tiegang; Jiang, Tingchen

    2016-05-01

    The history records of lead and its stable isotopic ratios were determined in a sediment core to receive anthropogenic impacts on the Lake Hailing in eastern China. The sediment core was dated based on (210)Pb, (137)Cs, and (239+240)Pu. The historical changes of Pb/Al and Pb isotope ratios showed increasing trend upward throughout the core, suggesting changes in energy usage and correlating closely with the experience of a rapid economic and industrial development of the catchment, Linyi City, in eastern China. Based on the mixing end member model of Pb isotope ratios, coal combustion emission dominated anthropogenic Pb sources in the half part of the century contributing 13 to 43 % of total Pb in sediment. Moreover, contributions of chemical and organic fertilizer were 1-13 and 5-14 %, respectively. In contrast, the contribution of leaded gasoline was low than 8 %. The results indicated that historical records of Pb contamination predominantly sourced from coal combustion and chemical and organic fertilizer in the catchment. In addition, an increase of coal combustion source and fertilizers was found throughout the sediment core, whereas the contribution of leaded gasoline had declined after 2000s, which is attributed to the phaseout of leaded gasoline in China. PMID:26832874

  19. Isotope and trace element geochemistry of sediments from the Barbados Ridge-Demerara Plain region, Atlantic Ocean

    NASA Astrophysics Data System (ADS)

    White, William M.; Dupré, Bernard; Vidal, Philippe

    1985-09-01

    Twenty-four piston core sediment samples and 13 sediments and 3 basalts from DSDP Leg 78 Site 543 were analyzed for Sr, Nd and Pb isotopic compositions. The results show sediment with highly radiogenic Pb 206Pb /204Pb up to 19.8) and rather radiogenic Sr and unradiogenic Nd has been deposited in the region since the Cretaceous. The source of this sediment is probably the Archean Guiana Highland, which is drained by the Orinoco River. Pb and Sr isotopic compositions and sediment thickness decrease and 143Nd /144Nd increases northward due to a decrease in turbiditic component. This decrease is partly due to the damming action of basement ridges. Rare earth concentrations in the sediments are somewhat low, due to the abundance of detrital and biogenic components in the sediment and rapid sedimentation rates. Both positive and negative Ce anomalies occur in the surface sediments, but only positive Ce anomalies occur in the Site 543 sediments. It is unlikely that sediment subducted to the source region of Lesser Antilles arc magmas could be the cause of negative Ce anomalies in those magmas. Isotopic compositions of Site 543 basalts show some effect of contamination by seawater-basalt reaction products and sediments. Beyond this, however, they are typical of "normal" depleted MORB.

  20. Age of Alpine Corsica ophiolites revisited: Insights from in situ zircon U-Pb age and O-Hf isotopes

    NASA Astrophysics Data System (ADS)

    Li, Xian-Hua; Faure, Michel; Rossi, Philippe; Lin, Wei; Lahondère, Didier

    2015-04-01

    Knowledge of the age and timing of ophiolite sequences is essential for understanding the mechanisms of plate tectonics. The ophiolites in the Schistes Lustrés and the Upper nappes of Alpine Corsica represent remnants of the Liguria-Piemonte ocean basin that formed as a branch of the Central Atlantic basin during the opening of the Mesozoic Western Alpine Tethys. Despite numerous isotopic and paleontological studies, the age and timing of the ophiolites in the Schistes Lustrés nappe are still controversial. This study presents integrated in situ analyses of zircon U-Pb age and O-Hf isotopic data for ophiolitic gabbros and plagiogranites from three localities in the Schistes Lustrés nappe of Eastern Corsica. Our new results demonstrate that these rocks crystallized synchronously at ~ 159 Ma, approximately 10 m.y. younger than the ophiolites in the Balagne Upper nappe. Zircons from the gabbros and plagiogranites are characterized by highly positive εHf(t) (+ 15.0 to + 15.9) and mantle-like δ18O (5.2-5.4‰) values. Thus, these ophiolitic rocks were cogenetic, and crystallized from magmas produced by partial melting of a depleted, N-MORB type mantle. By contrast, in the Balagne Upper nappe, the ~ 169 Ma ophiolites contain numerous xenocrystic zircons inherited from a continental crust. Our current knowledge of isotopic geochronology and geochemistry supports a paleogeographic reconstruction, in which the earliest ophiolites in the Balagne nappe were emplaced close to a continental margin at ~ 169 Ma, while the N-MORB type ophiolites in the Schistes Lustrés nappe were likely formed approximately 10 m.y. later in the central part of the Liguria-Piemonte oceanic basin. The relative location of the Schistes Lustrés and Balagne Upper nappes with respect to continental margins is discussed.

  1. Isotopic generator for /sup 212/Pb and /sup 212/Bi

    SciTech Connect

    Zucchini, G.L.; Friedman, A.M.

    1982-01-01

    A large potential exists for the use of short lived alpha emitting isotopes for therapeutic purposes. Most prior research has been performed with isotopes such as /sup 211/At which require a cyclotron for production. It obviously would be more convenient to use a long lived isotopic generator system. For this reason, we have undertaken a study of the properties of several such generators, one of which, /sup 228/Th, is described here.

  2. Synthesis, characterization, and evaluation of a novel bifunctional chelating agent for the lead isotopes 203Pb and 212Pb.

    PubMed

    Chappell, L L; Dadachova, E; Milenic, D E; Garmestani, K; Wu, C; Brechbiel, M W

    2000-01-01

    Radioisotopes of Pb(II) have been of some interest in radioimmunotherapy and radioimmunoimaging (RII). However, the absence of a kinetically stable bifunctional chelating agent for Pb(II) has hampered its use for these applications. 203Pb (T(1/2) = 52.02 h) has application potential in RII, with a gamma-emission that is ideal for single photon emission computerized tomography, whereas 212Pb (T(1/2) = 10 h) is a source of highly cytotoxic alpha-particles via its decay to its 212Bi (T(1/2) = 60 min) daughter. The synthesis of the novel bifunctional chelating agent 2-(4-isothiocyanotobenzyl)-1,4,7,10-tetraaza-1,4,7,10-tetra- (2-carbamoyl methyl)-cyclododecane (4-NCS-Bz-TCMC) is reported herein. The Pb[TCMC]2+ complex was less labile to metal ion release than Pb[DOTA]2- at pH 3.5 and below in isotopic exchange experiments. In addition to increased stability to Pb2+ ion release at low pH, the bifunctional TCMC ligand was found to have many other advantages over the bifunctional 1,4,7,10-tetraazacyclodocane-1,4,7,10-tetraacetic acid (DOTA) ligand. These include a shorter and more straightforward synthetic route, a more efficient conjugation reaction to a monoclonal antibody (mAb), with a higher chelate to protein ratio, a higher percent immuroreactivity, and a more efficient radiolabeling reaction of the mAb-ligand conjugate with 203Pb. PMID:10755652

  3. Isotope geochemistry of early Kilauea magmas from the submarine Hilina bench: The nature of the Hilina mantle component

    NASA Astrophysics Data System (ADS)

    Kimura, Jun-Ichi; Sisson, Thomas W.; Nakano, Natsuko; Coombs, Michelle L.; Lipman, Peter W.

    2006-03-01

    Submarine lavas recovered from the Hilina bench region, offshore Kilauea, Hawaii Island provide information on ancient Kilauea volcano and the geochemical components of the Hawaiian hotspot. Alkalic lavas, including nephelinite, basanite, hawaiite, and alkali basalt, dominate the earliest stage of Kilauea magmatism. Transitional basalt pillow lavas are an intermediate phase, preceding development of the voluminous tholeiitic subaerial shield and submarine Puna Ridge. Most alkalic through transitional lavas are quite uniform in Sr-Nd-Pb isotopes, supporting the interpretation that variable extent partial melting of a relatively homogeneous source was responsible for much of the geochemical diversity of early Kilauea magmas ( Sisson et al., 2002). These samples are among the highest 206Pb/ 204Pb known from Hawaii and may represent melts from a distinct geochemical and isotopic end-member involved in the generation of most Hawaiian tholeiites. This end-member is similar to the postulated literature Kea component, but we propose that it should be renamed Hilina, to avoid confusion with the geographically defined Kea-trend volcanoes. Isotopic compositions of some shield-stage Kilauea tholeiites overlap the Hilina end-member but most deviate far into the interior of the isotopic field defined by magmas from other Hawaiian volcanoes, reflecting the introduction of melt contributions from both "Koolau" (high 87Sr/ 86Sr, low 206Pb/ 204Pb) and depleted (low 87Sr/ 86Sr, intermediate 206Pb/ 204Pb) source materials. This shift in isotopic character from nearly uniform, end-member, and alkalic, to diverse and tholeiitic corresponds with the major increase in Kilauea's magmatic productivity. Two popular geodynamic models can account for these relations: (1) The upwelling mantle source could be concentrically zoned in both chemical/isotopic composition, and in speed/extent of upwelling, with Hilina (and Loihi) components situated in the weakly ascending margins and the Koolau

  4. Isotope geochemistry of early Kilauea magmas from the submarine Hilina bench: The nature of the Hilina mantle component

    USGS Publications Warehouse

    Kimura, Jun-Ichi; Sisson, T.W.; Nakano, N.; Coombs, M.L.; Lipman, P.W.

    2006-01-01

    Submarine lavas recovered from the Hilina bench region, offshore Kilauea, Hawaii Island provide information on ancient Kilauea volcano and the geochemical components of the Hawaiian hotspot. Alkalic lavas, including nephelinite, basanite, hawaiite, and alkali basalt, dominate the earliest stage of Kilauea magmatism. Transitional basalt pillow lavas are an intermediate phase, preceding development of the voluminous tholeiitic subaerial shield and submarine Puna Ridge. Most alkalic through transitional lavas are quite uniform in Sr-Nd-Pb isotopes, supporting the interpretation that variable extent partial melting of a relatively homogeneous source was responsible for much of the geochemical diversity of early Kilauea magmas (Sisson et al., 2002). These samples are among the highest 206Pb/204Pb known from Hawaii and may represent melts from a distinct geochemical and isotopic end-member involved in the generation of most Hawaiian tholeiites. This end-member is similar to the postulated literature Kea component, but we propose that it should be renamed Hilina, to avoid confusion with the geographically defined Kea-trend volcanoes. Isotopic compositions of some shield-stage Kilauea tholeiites overlap the Hilina end-member but most deviate far into the interior of the isotopic field defined by magmas from other Hawaiian volcanoes, reflecting the introduction of melt contributions from both "Koolau" (high 87Sr/86Sr, low 206Pb/204Pb) and depleted (low 87Sr/86Sr, intermediate 206Pb/204Pb) source materials. This shift in isotopic character from nearly uniform, end-member, and alkalic, to diverse and tholeiitic corresponds with the major increase in Kilauea's magmatic productivity. Two popular geodynamic models can account for these relations: (1) The upwelling mantle source could be concentrically zoned in both chemical/isotopic composition, and in speed/extent of upwelling, with Hilina (and Loihi) components situated in the weakly ascending margins and the Koolau component

  5. Petrogenesis of Challis volcanics from central and southwestern Idaho - Trace element and Pb isotopic evidence

    NASA Technical Reports Server (NTRS)

    Norman, Marc D.; Mertzman, Stanley A.

    1991-01-01

    An analysis of the lava flows and ash-flow tuffs in Idaho is conducted to determine the composition of the volcanics in terms of major and trace elements and Pb isotopic substances. Al2O3 is found to be low, MgO content is high, and the concentration of K2O is higher or equal to that of Na2O with respect to the lavas of mafic to intermediate composition. Trace elements and element ratios are compatible with the crustal component, and the Pb isotopic compositions suggest a lack of assimilation during crystallization. The evidence does not support the notion of a magma system related to subduction, and the data regarding Pb isotopes and trace elements point to a connection with the lithosphere. A model is proposed for the Challis volcanics in which they resulted from completely melting within the lithosphere and then extending during the late Mesozoic and early Cenozoic compression.

  6. Stable isotope geochemistry of clay minerals from fossil and active hydrothermal systems, southwestern Hokkaido, Japan

    SciTech Connect

    Marumo, Katsumi; Longstaffe, F.J.; Matsubaya, Osamu

    1995-06-01

    Miocene submarine to Quaternary terrestrial volcanism in southwestern Hokkaido, Japan, is associated with hydrothermal clay alteration and mineralization, including Kuroko-type deposits at Kagenosawa (14.2 Ma, Cu > Zn, Pb > Au) and Minamishiraoi (12.5 Ma, Ba > Zn, Pb, Cu), vein-style at Noboribetsu ({le} 1.8 Ma). The {delta}D and {delta}{sup 18}O values of mica (sericite), mica-smectite, chlorite, chlorite-smectite, nacrite, dickite, kaolinite, and smectite were used to deduce the type(s) of hydrothermal fluid at each locality. Calculated compositions for Minamishiraoi and Kagenosawa fluids suggest that seawater was dominant, but some mixing with magmatic water is also indicated, particularly for the polymetallic Kagenosawa deposit. Hydrothermal fluids at Date, Chitose, and the Noboribetsu geothermal area were dominated by meteoric water. The {delta}D and {delta}{sup 18}O values of modern hot-spring waters at Noboribetsu closely parallel fluid compositions calculated for the clay alteration at Date, Chitose, and Noboribetsu. In vacuo TG patterns of other smectitic clays suggested gradual loss of hydroxyl-groups beginning near 200{degrees}C, rather than the more typical distinct separation between interlayer water at <200{degrees}C and hydroxyl-groups at >400{degrees}C. This behaviour constrains the maximum temperature that can be used for in vacuo preheating. Furthermore, shifts to lower {delta}D values (by as much as 19{per_thousand}) were obtained when this smectite was dispersed in low-D water for three weeks, perhaps indicating isotopic exchange. However, with appropriate care, {delta}D values obtained by conventional procedures (including preheating to {le}200{degrees}C) normally reproduced natural compositions of the smectitic clays with acceptable accuracy and precision.

  7. U, Th, and Pb isotopes in hot springs on the Juan de Fuca Ridge

    NASA Technical Reports Server (NTRS)

    Chen, J. H.

    1987-01-01

    Concentrations and isotopic compositions of U, Th, and Pb in three hydrothermal fluids from the Juan de Fuca Ridge were determined from samples obtained by the Alvin submersible. The samples were enriched in Pb and Th relative to deep-sea water, and were deficient in U. No clear relationship with Mg was found, suggesting nonideal mixing between the hot hydrothermal fluids and the cold ambient seawater. Values for U-234/U-238 have a seawater signature, and show a U-234 enrichment relative to the equilibrium value. The Pb isotopic composition has a uniform midocean ridge basalt signature, and it is suggested that Pb in these fluids may represent the best average value of the local oceanic crust.

  8. 210Pb chronology and trace metal geochemistry in the intertidal sediment of Qinjiang River estuary, China

    NASA Astrophysics Data System (ADS)

    Xia, Peng; Meng, Xianwei; Feng, Aiping; Yin, Ping; Wang, Xiangqin; Zhang, Jun

    2012-06-01

    Historical records of metal inputs were studied by using a sediment core collected from a sand-rich mudflat in the Qinjiang River estuary, China. 210Pb chronology was used to reconstruct the fluxes of Hg, Cu, Pb, Zn, Cd, Cr and As to the core site during the last 86 years. Based on the constant initial concentration model, the sedimentation rates are 1.18 cm year-1 in the top 30 cm sandy layer and 0.92 cm year-1 in the muddy bottom layer. To compensate for grain-size and mineralogy effects on metal concentrations, aluminum was used as the normalizing element. The enrichment factors ( EF) indicate that the natural inputs had prevailed up to the early 1980s. After this period, the intensity of human activities has resulted in continual increasing trend of metals towards the surface. Recent sediment samples from the Qinjiang River estuary are found moderately enriched by Cd ( EF>1.5) and slightly enriched by other metals ( EF<1.5). Considering that the drainage area of the Qinjiang River is mostly agricultural land, the increased Cd may be due to the usage of fertilizers and pesticides in agricultural activities and the combustion of fossil fuels.

  9. U-Pb isotope systematics and age of uranium mineralization, Midnite mine, Washington.

    USGS Publications Warehouse

    Ludwig, K. R.; Nash, J.T.; Naeser, C.W.

    1981-01-01

    Uranium ores at the Midnite mine, near Spokane, Washington, occur in phyllites and calcsilicates of the Proterozoic Togo Formation, near the margins of an anomalously uraniferous, porphyritic quartz monzonite of Late Cretaceous age. The present geometry of the ore zones is tabular, with the thickest zones above depressions in the pluton-country rock contact. Analyses of high-grade ores from the mine define a 207 Pb/ 204 Pb- 235 U/ 204 Pb isochron indicating an age of mineralization of 51.0 + or - 0.5 m.y. This age coincides with a time of regional volcanic activity (Sanpoil Volcanics), shallow intrusive activity, erosion, and faulting. U-Th-Pb isotopic ages of zircons from the porphyritic quartz monzonite in the mine indicate an age of about 75 m.y., hence the present orebodies were formed about 24 m.y. after its intrusion. The 51-m.y. time of mineralization probably represents a period of mobilization and redeposition of uranium by supergene ground waters, perhaps aided by mild heating and ground preparation and preserved by a capping of newly accumulated, impermeable volcanic rocks. It seems most likely that the initial concentration of uranium occurred about 75 m.y. ago, probably from relatively mild hydrothermal fluids in the contact-metamorphic aureole of the U-rich porphyritic quartz monzonite.Pitchblende, coffinitc, pyrite, marcasite, and hisingerite are the most common minerals in the uranium-bearing veinlets, with minor sphalerite and chalcopyrite. Coffinitc with associated marcasite is paragenetically later than pitchblende, though textural and isotopic evidence suggests no large difference in the times of pitchblende and colfinite formation.The U-Pb isotope systematics of total ores and of pitchblende-coffinite and pyrite-marcasite separates show that whereas open system behavior for U and Pb is essentially negligible for large (200-500 g) ore samples, Pb migration has occurred on a scale of 1 to 10 mm (out of pitchblende and coffinite and into pyrite

  10. Geochemistry of the Patricia Zn-Pb-Ag Deposit (paguanta, NE Chile)

    NASA Astrophysics Data System (ADS)

    Chinchilla Benavides, D.; Merinero Palomares, R.; Piña García, R.; Ortega Menor, L.; Lunar Hernández, R.

    2013-12-01

    The Patricia Zn-Pb-Ag ore deposit is located within the Paguanta mining project, situated at the northern end of the Andean Oligocene Porphyry Copper Belt of Chile. The sulfide mineralization occurs as W-E oriented veins hosted in volcanic rocks, mainly andesite (pyroclastic, ash and lavas), of Upper Cretaceous to Middle Tertiary age. The ore mineralogy (obtained by EMPA analyses) comprises in order of abundance, pyrite, sphalerite (5.5 - 10.89 wt % Fe, 9.8-19 % molar FeS and 0.52 wt % Cd), galena, arsenopyrite, chalcopyrite and Ag-bearing sulfosalts. The veins show a zoned and banded internal structure with pyrite at the edges and sphalerite in the center. The Ag occurs mostly as Ag-Cu-Sb sulfosalts, in order of abundance: series freibergite - argentotennantite -polybasite and stephanite. Other minor Ag phases such as argentite, pyrargirite and diaphorite were also identified. These Ag phases are typically associated with the base-metal sulfides. Freibergite occurs filling voids within sphalerite, chalcopyrite and at the contact between sphalerite and galena. Polybasite, stephanite, pyrargirite and argentite are mostly in close association with freibergite. In the case of diaphorite, it commonly occurs filling voids between galena crystals or as inclusions within galena. Some minor Ag-bearing sulfosalts are also identified between pyrite crystals. The alteration minerals are dominated by chlorite, illite and kaolinite. The gangue minerals consist of quartz and carbonates identified by XRD as kutnahorite. We obtained linear correlation statistically significant only for Ag, As Au, Cd, Cu, Pb, Sb and Zn and therefore we generated an enhanced scatter plot matrix of these elements. Bulk rock analyses (ICP/MS and XRF) of drill cores show that Ag is strongly and positively correlated with Pb and As, moderately with Cd, Sb, Au and Zn and weakly with Cu, while Au is moderately and positively correlated with Ag, As, Cd, Sb and Zn and weakly with Cu and Pb. These results

  11. Infrared spectroscopy and hydrogen isotope geochemistry of hydrous silicate glasses. Progress report, June 1, 1996--May 31, 1999

    SciTech Connect

    Epstein, S.; Stolper, E.

    1998-06-01

    This DOE-funded project (DE-FG03-ER13445, 6/1/96-5/31/99) emphasizes study of the behavior of volatiles in magmatic systems. The project is explicitly focused on the combined application of IR spectroscopy, experimental petrology, and stable isotope geochemistry to understanding the behavior and properties of the volatile components dissolved in silicate melts and glasses, although in recent years, our emphasis has broadened to include non-volatile aspects of stable isotope geochemistry. Results obtained during the current grant and previous grant periods confirm that when applied to study of well-chosen synthetic and natural systems, the combination of these approaches and techniques can yield insights of general petrological and volcanological value and of practical value to DOE. In particular, the results of our DOE-funded work has led to a deeper understanding of the physical chemistry of silicate melts as well as specific constraints on the thermal and chemical evolution of high-level magmatic systems of the sort being evaluated as potential geothermal and magmathermal energy sources. Moreover, our work has also contributed to understanding the behavior of H-, C-, and O-bearing species in amorphous and crystalline silicates, including the kinetics of their interactions; we believe these results will contribute to efforts to use silicates in the development of nuclear waste disposal strategies.

  12. In-situ Pb Isotope Ratio Measurements in Glasses and Melt Inclusions by LA-SF-ICPMS

    NASA Astrophysics Data System (ADS)

    Jochum, K. P.; Stoll, B.; Herwig, K.; Amini, M.; Abouchami, W.

    2004-12-01

    We have developed a technique to determine Pb isotopes in glass fragments and melt inclusions by laser ablation (LA) - sector field (SF) - ICPMS. The measurements were done with a New Wave UP-213 laser system and an ELEMENT2 ICP mass spectrometer using the electrical scan mode. The geological MPI-DING reference glasses (Jochum et al., 2000), for which TIMS and MC-ICPMS Pb triple spike (TS) data are now available, were used to test our technique. Our LA-SF-ICPMS data for 208Pb/206Pb and 207Pb/206Pb agree with the high-precision Pb data within 0.2 %. Polished 150 μ m thick sections were used for the analysis of melt inclusions from samples of the Hawaii Scientific Drilling Project (HSDP). Inclusions were ablated for 10 - 30 s in single spots (40 - 80 μ m diameter). Each analysis consisted of 100 to 300 measurements of 206Pb, 207Pb and 208Pb. Typical in-run precision (1 RSE) ranged from 0.2 - 0.4 %. These values are similar to those obtained by SIMS (Saal et al., 1998). The 208Pb/206Pb (1.91 - 2.13) and 207Pb/206Pb (0.778 - 0.877) in the melt inclusions show large and systematic variations. The range of variability in Pb isotope ratios is similar to that reported in melt inclusions from Mangaia and Tahaa basalts (Saal et al., 1998). The Pb isotope arrays (in 208Pb/206Pb vs 207Pb/206Pb) can be explained by mixing of at least two end members. Groundmass values are uniform and similar to the whole rock data and plot within the melt inclusion fields. LA-SF-ICPMS has also been applied for determining Pb isotope ratios and trace element concentrations in carefully handpicked 200 - 500 μ m large glass fragments from 19 samples of the submarine section of HSDP-2. Precision of the Pb isotope data was about 0.2 - 0.3 %. Most LA-SF-ICPMS data agree with high-precision TIMS data using aliquots of about 50 mg. Both data sets confirm the temporal Pb isotope variations found in the HSDP-2 core based on the whole-rock TS Pb isotope data (Eisele et al., 2003).

  13. Stable isotope geochemistry of clay minerals from fossil and active hydrothermal systems, southwestern Hokkaido, Japan

    NASA Astrophysics Data System (ADS)

    Marumo, Katsumi; Longstaffe, Fred J.; Matsubaya, Osamu

    1995-06-01

    Miocene submarine to Quaternary terrestrial volcanism in southwestern Hokkaido, Japan, is associated with hydrothermal clay alteration and mineralization, including Kuroko-type deposits at Kagenosawa (14.2 Ma, Cu > Zn, Pb > Au) and Minamishiraoi (12.5 Ma, Ba > Zn, Pb, Cu), vein-style mineralization at Date (5.2 Ma, Au-Ag-Cu-Pb-Zn) and Chitose (3.6 Ma, Au-Ag), and geothermal activity at Noboribetsu (≤1.8 Ma). The δD and δ 18O values of mica (sericite), mica-smectite, chlorite, chlorite-smectite, nacrite, dickite, kaolinite, and smectite were used to deduce the type(s) of hydrothermal fluid at each locality. Calculated compositions for Minamishiraoi and Kagenosawa fluids suggest that seawater was dominant, but some mixing with magmatic water is also indicated, particularly for the polymetallic Kagenosawa deposit. Hydrothermal fluids at Date, Chitose, and the Noboribetsu geothermal area were dominated by meteoric water. Minor involvement of magmatic water during mineralization at Date cannot be ruled out, but evolution of local meteoric water along an evaporation trend and/or an 18O-shift due to hydrothermal rock-meteoric water interaction also could have produced appropriate fluid compositions. The δD and δ 18O values of modern hot-spring waters at Noboribetsu closely parallel fluid compositions calculated for the clay alteration at Date, Chitose, and Noboribetsu. Because relatively poor reproducibility was obtained for the δD values of the swelling clays, additional tests were conducted. Stepwise heating showed that, for some smectitic clays, water evolved between 200 and 300°C had anomalously high δD values because of residual interlayer water. This error can be minimized by sufficiently long preheating (in vacuo) at ≤200°C. In vacuo TG patterns of other smectitic clays suggested gradual loss of hydroxyl-groups beginning near 200°C, rather than the more typical distinct separation between interlayer water at <200°C and hydroxyl-groups at > 400

  14. Pb enamel biomarker: Deposition of pre- and postnatal Pb isotope injection in reconstructed time points along rat enamel transect

    SciTech Connect

    Rinderknecht, A.L.; Kleinman, M.T.; Ericson, J.E. . E-mail: jeericso@uci.edu

    2005-10-01

    Exposure to lead (Pb) as well as other heavy metals in the environment is still a matter of public health concern. The development of the enamel biomarker for heavy metal exposure assessment is designed to improve studies of dose-effect relationships to developmental anomalies, particularly embryonic dysfunctions, and to provide a time-specific recount of past exposures. The work presented in this paper demonstrates maternal transfer across the placental barrier of the enriched isotope {sup 206}Pb tracer to the enamel of the rat pup. Likewise, injections of {sup 204}Pb-enriched tracer in the neonate rat resulted in deposition of the tracer in the enamel histology as measured by secondary ion microprobe spectrometry. Through enamel, we were able to observe biological removal and assimilation of prenatal and postnatal tracers, respectively. This research demonstrates that enamel can be used as a biomarker of exposure to Pb and may illustrate the toxicokinetics of incorporating Pb into fetal and neonatal steady-state system processes. The biomarker technique, when completely developed, may be applied to cross-sectional and longitudinal epidemiological research.

  15. Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor Mine, South Africa.

    NASA Technical Reports Server (NTRS)

    Manton, W. I.; Tatsumoto, M.

    1971-01-01

    Five nodules of eclogite, one nodule of garnet peridotite, and one sample of kimberlite from the Roberts Victor Mine in the Orange Free State were analyzed for concentrations of U, Th, Pb, Rb, and Sr, and also isotopic compositions of Pb and Sr. Results are presented and analyzed. They indicate that the Roberts Victor eclogites have been contaminated by lead from the host rock of kimberlite. This finding suggests that stepwise extraction of lead may be a means of obtaining the isotopic composition of the primary lead in kimberlitic eclogites.

  16. The characteristic of Pb isotopic compositions in different chemical fractions in sediments from Three Gorges Reservoir, China.

    PubMed

    Han, Lanfang; Gao, Bo; Wei, Xin; Gao, Li; Xu, Dongyu; Sun, Ke

    2015-11-01

    To explore the distribution and sources of Pb within the Three Gorges Reservoir (TGR), Pb concentrations and isotope ratios were measured in sediment cores collected from one mainstream and three tributaries. The results showed that sediments contained an average of 43.54 mg kg(-1) of Pb, roughly 1.6 times higher than the geochemical background concentration. Mainstream sediments showed higher average Pb concentrations but slightly less (206)Pb/(207)Pb and more radiogenic (207)Pb/(208)Pb ratios than all tributaries. Most Pb occurred in reducible phases, with much less in exchangeable and oxidizable fractions; thus, Fe-Mn oxides may be the major sink of anthropogenic Pb. Bi-plots of (206)Pb/(207)Pb versus Pb content, and of (206)Pb/(207)Pb versus (207)Pb/(208)Pb, indicated that coal combustion was the predominant anthropogenic Pb source for exchangeable, reducible, and oxidizable fractions, while residual Pb mainly occurred naturally. The average percentage of coal consumption contribution was 61.1% for the Pb contamination in sediments in the lower reaches in the TGR region. PMID:26319507

  17. Geochronology, geochemistry and Sr-Nd-Hf isotopes of mafic dikes in the Huicheng Basin: Constraints on intracontinental extension of the Qinling orogen

    NASA Astrophysics Data System (ADS)

    Li, Wei; Dong, Yunpeng; Guo, Anlin; Liu, Xiaoming; Wang, Yuejun; Liu, Wenhang; Yang, Yuanzhen

    2015-05-01

    The diabase dikes intruded the Lower Cretaceous sandstone in the Huicheng Basin are key to understanding the Mesozoic tectonic evolution of the Qinling orogen. LA-ICP-MS zircon U-Pb dating yields a crystallization age of 107 ± 1 Ma for them. The dikes have low contents of SiO2 (42.46-50.16 wt.%), MgO (3.47-5.59 wt.%) with low Mg# of 49-59, and TiO2 (1.35-1.63 wt.%), high TFe2O3 (8.15-9.36 wt.%), Al2O3 (14.75-17.23 wt.%) and K2O (0.87-3.61 wt.%). Their Ni and Cr contents are in range of 16.8-111 and 45.7-315 ppm, respectively. They are significantly enriched in light rare earth elements and large ion lithophile elements (e.g., Cs, Pb and Ba), and depleted in Rb, K, P, and Ti. The dikes show relatively high whole-rock initial 87Sr/86Sr ratios (0.7071-0.7079) and negative εNd (t) values (-1.5 to -4.8) with single-stage Nd model ages of 941-1186 Ma. In addition, they have low zircon εHf (t) values (-8.6 to +3.5) with single-stage Hf model ages of 674-1117 Ma. Both elemental and isotopic geochemistry suggests that the magma of these dikes has undergone significant crystallization fractionation of olivine and pyroxene but weak crustal contamination during magma evolution. They were derived from partial melting of an enriched lithospheric mantle source. Together with regional geological data, these results suggest that the Qinling orogen experienced an intracontinental extension during the late Early Cretaceous.

  18. Geochemistry and isotope geochemistry of the Monfalcone thermal waters (northern Italy): inference on the deep geothermal reservoir

    NASA Astrophysics Data System (ADS)

    Petrini, R.; Italiano, F.; Ponton, M.; Slejko, F. F.; Aviani, U.; Zini, L.

    2013-09-01

    Geochemical investigations were carried out to define the origin of the low- to moderate-temperature thermal waters feeding the Monfalcone springs in northern Italy. Chemical data indicate that waters approach the composition of seawater. Mixing processes with cold low-salinity waters are highlighted. The δ18O and δD values are in the range -5.0 to -6.4 ‰, and -33 to -40 ‰, respectively, suggesting the dilution of the saline reservoir by karst-type freshwaters. A surplus of Ca2+ and Sr2+ ions with respect to a conservative mixing is ascribed to diagenetic reactions of the thermal waters with Cretaceous carbonates at depth. The measured Sr isotopic composition (87Sr/86Sr ratio) ranges between 0.70803 and 0.70814; after correction for the surplus Sr, a 87Sr/86Sr ratio indicating Miocene paleo-seawater is obtained. The dissolved gases indicate long-lasting gas-water interactions with a deep-originated gas phase of crustal origin, dominated by CO2 and marked by a water TDIC isotopic composition in the range -5.9 to-8.8 and helium signature with 0.08 < R/Ra < 0.27, which is a typical range for the crust. A possible scenario for the Monfalcone thermal reservoir consists of Miocene marine paleowaters which infiltrated through the karstic voids formed within the prevalently Cretaceous carbonates during the upper Eocene emersion of the platform, and which were entrapped by the progressive burial by terrigenous sediments.

  19. Pb isotope composition in lichens and aerosols from eastern Sicily: Insights into the regional impact of volcanoes on the environment

    SciTech Connect

    Monna, F. ); Aiuppa, A.; Varrica, D. ); Dongarra, G. CNR, Palermo . Istituto Geochimica dei Fluidi)

    1999-08-01

    A total of 25 lichen thalli of Parmelia conspersa (Ehrh), collected at Vulcano island and at Mt. Etna, during a one-year biogeochemical survey, were analyzed for Pb, br, Al, Sc,[sup 206]Pb/[sup 207]Pb, and [sup 208]Pb/[sup 206]Pb ratios. Lead isotope ratios were also measured on aerosol samples from urban areas and industrial sites of Sicily. The observed [sup 206]Pb/[sup 207]Pb range for urban and industrial aerosols matches the anthropogenic signature. Lichens instead, are closer to the compositional field of [sup 206]Pb rich geogenic sources. This natural input is more evident at Vulcano island than at Mt. Etna, where the anthropogenic activities are considerably more effective. On the basis of lead isotope data, Pb/Br ratios and calculated lead enrichment factors, a natural lead pollution from volcanoes is suggested. Volcanic lead contribution ranges from 10 to 30% at Mt. Etna to 10--80% at Vulcano island.

  20. Lead isotopes and trace metal ratios of aerosols as tracers of Pb pollution sources in Kanpur, India

    NASA Astrophysics Data System (ADS)

    Sen, Indra; Bizimis, Michael; Tripathi, Sachchida; Paul, Debajyoti; Tyagi, Swati; Sengupta, Deep

    2015-04-01

    The anthropogenic flux of Pb in the Earth's surface is almost an order of magnitude higher than its corresponding natural flux [1]. Identifying the sources and pathways of anthropogenic Pb in environment is important because Pb toxicity is known to have adverse effects on human health. Pb pollution sources for America, Europe, and China are well documented. However, sources of atmospheric Pb are unknown in India, particularly after leaded gasoline was phased out in 2000. India has a developing economy with a rapidly emerging automobile and high temperature industry, and anthropogenic Pb emission is expected to rise in the next decade. In this study, we report on the Pb- isotope compositions and trace metal ratios of airborne particulates collected in Kanpur, an industrial city in northern India. The Pb concentration in the airborne particulate matter varies between 14-216 ng/m3, while the other heavy metals vary by factor of 10 or less, e.g. Cd=0.3-3 ng/m3, As=0.4-3.5 ng/m3, Zn=36-161 ng/m3, and Cu=3-22 ng/m3. The 206Pb/207Pb, 208Pb/206Pb, and 208Pb/207Pb vary between 1.112 - 1.129, 2.123-2.141, and 2.409-2.424 respectively, and are highly correlated with each other (R2>0.9). Pb isotopes and trace metal data reveals that coal combustion is the major source of anthropogenic Pb in the atmosphere, with limited contribution from mining and smelting processes. We further conclude that combination of Pb isotope ratios and V/Pb ratios are powerful tracers for Pb source apportionment studies, which is otherwise difficult to differentiate based only on Pb systematics [1] Sen and Peucker-Ehrenbrink (2012), Environ. Sci. Technol.(46), 8601-8609

  1. Monitoring of Pb Contamination in Loire Estuary: Trends, Distribution and Isotopic composition

    NASA Astrophysics Data System (ADS)

    Brach-Papa, Christophe; Chiffoleau, Jean-François; Knoery, Joel; Chouvelon, Tiphaine; Auger, Dominique; Bretaudeau, Jane; Crochet, Sylvette; Rozuel, Emmanuelle; Thomas, Batien; Vasileva, Emilia; Oriani, Anna Maria

    2014-05-01

    The Loire River is one of the largest river systems in Western Europe and constitutes a major continental input to marine environment in the Bay of Biscay. Its catchment area flows through agricultural, industrial areas and through a more and more urbanized estuary. Even if Loire River is not considered as a highly polluted system, some studies identified a Pb contamination of its estuary due to industrial inputs and combustion of leaded gasoline up to the mid 90's. A retrospective study, based on the analysis (Pb contents and isotopic composition) of Mytilus edulis samples collected by the French mussel watch program (RNO/ROCCH) has highlighted this contamination and its trend between 1985-2005 (Couture et al., 2010). This poster will first complete the work initiated by Couture et al. Pb contents and isotopic signatures in mussel samples collected by RNO/ROCCH over the last 10 years will be presented and discussed. Results will be compared to measurements performed on various environmental samples (sediment, biota…) collected in the frame of the environmental monitoring project RS2E started in 2012 by the "Observatoire des Sciences de l'Univers Nantes-Atlantique" (OSUNA). This new data will contribute to a better characterisation of Pb contents and distribution along the Loire Estuary. Moreover, some key samples will be submitted to HR-ICP-MS for Pb isotopic analysis. Discrimination of anthropic Pb sources requires both precise and accurate isotope ratio determination and also high versatility due to the complex matrix, which is typical for marine and estuarine samples. These measurements will contribute to a more accurate definition and characterisation of main actual anthropic Pb sources (urban, agricultural, industrial or atmospheric deposition). Couture R.- M., Chiffoleau J.-F., Auger D., Claisse D., Gobeil C. and Cossa D. (2010) Seasonal and decadal variation in lead sources to eastern north Atlantic mussels. Environ. Sci. Technol. 44, 1211-1216.

  2. Radiogenic Isotopes As Paleoceanographic Tracers in Deep-Sea Corals: Advances in TIMS Measurements of Pb Isotopes and Application to Southern Ocean Corals

    NASA Astrophysics Data System (ADS)

    Wilson, D. J.; van de Flierdt, T.; Bridgestock, L. J.; Paul, M.; Rehkamper, M.; Robinson, L. F.; Adkins, J. F.

    2014-12-01

    Deep-sea corals have emerged as a valuable archive of deep ocean paleoceanographic change, with uranium-series dating providing absolute ages and the potential for centennial resolution. In combination with measurements of radiocarbon, neodymium isotopes and clumped isotopes, this archive has recently been exploited to reconstruct changes in ventilation, water mass sourcing and temperature in relation to millennial climate change. Lead (Pb) isotopes in both corals and seawater have also been used to track anthropogenic inputs through space and time and to trace transport pathways within the oceans. Better understanding of the oceanic Pb cycle is emerging from the GEOTRACES programme. However, while Pb isotopes have been widely used in environmental studies, their full potential as a (pre-anthropogenic) paleoceanographic tracer remains to be exploited. In deep-sea corals, challenges exist from low Pb concentrations in aragonite in comparison to secondary coatings, the potential for contamination, and the efficient elemental separation required for measurement by thermal ionisation mass spectrometry (TIMS). Here we discuss progress in measuring Pb isotopes in coral aragonite using a 207Pb-204Pb double spike on a ThermoFinnigan Triton TIMS. For a 2 ng NIST-981 Pb standard, the long term reproducibility (using 1011 Ω resistors) is ~1000 ppm (2 s.d.) on 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios. We now show that using a new 1012 Ω resistor to measure the small 204Pb beam improves the internal precision on these ratios from ~500 ppm (2 s.e.) to ~250 ppm (2 s.e.) and we envisage a potential improvement in the long term reproducibility as a consequence. We further assess the internal precision and external reproducibility of our method using a BCR-2 rock standard and an in-house coral standard. Preliminary evidence on the application of this method to natural samples is derived from cleaning experiments and replication tests on deep-sea corals from the Southern

  3. Source identification of heavy metal contamination using metal association and Pb isotopes in Ulsan Bay sediments, East Sea, Korea.

    PubMed

    Chae, Jung Sun; Choi, Man Sik; Song, Yun Ho; Um, In Kwon; Kim, Jae Gon

    2014-11-15

    To determine the characteristics of metal pollution sources in Ulsan Bay, East Sea, 39 surface and nine core sediments were collected within the bay and offshore area, and analyzed for metals and stable lead (Pb) isotopes. Most surface sediments (>95% from 48 sites) had high copper (Cu), zinc (Zn), cadmium (Cd), and Pb concentrations that were as much as 1.3 times higher than background values. The primary source of metal contamination came from activities related to nonferrous metal refineries near Onsan Harbor, and the next largest source was from shipbuilding companies located at the mouth of the Taehwa River. Three different anthropogenic sources and background sediments could be identified as end-members using Pb isotopes. Isotopic ratios for the anthropogenic Pb revealed that the sources were imported ores from Australia, Peru, and the United States. In addition, Pb isotopes of anthropogenic Pb discharged from Ulsan Bay toward offshore could be determined. PMID:25148756

  4. Some Pb and Sr isotopic measurements on eclogites from the Roberts Victor mine, South Africa

    USGS Publications Warehouse

    Manton, W.I.; Tatsumoto, M.

    1971-01-01

    Five nodules of eclogite, one nodule of garnet peridotite and one sample of kimberlite from the Roberts Victor mine were analyzed for concentrations of U, Th, Pb, Rb and Sr and isotopic compositions of Pb and Sr. In the eclogites, U content ranges from 0.09 to 0.26 ppm, Th from 0.35 to 1.1 ppm, Pb from 0.79 to 5.5 ppm, Rb from 2.1 to 28 ppm and Sr from 133 to 346 ppm; 206Pb/204Pb ratios range from 14.8 to 18.5, 207Pb/204Pb from 14.9 to 15.7, 208Pb/204Pb from 35.2 to 38.5. The garnet peridotite contains 0.22 ppm U, 0.97 ppm Th, 1.05 ppm Pb, 6.9 ppm Rb and 108 ppm Sr and the kimberlite contains 2.5 ppm U, 30 ppm Th, 37 ppm Pb, 113 ppm Rb and 2040 ppm Sr. The lead in the eclogites has two components, a lead pyroextractable at 1100-1200?? and a non-pyroextractable residual lead. In three of the eclogites, which are to some extent altered, a proportion of the pyroextractable lead may be contaminating lead from the kimberlite, but an altered kyanite eclogite does not appear to be contaminated by this same kimberlite. The pyroextractable lead from a less altered eclogite contains a much larger proportion of 206Pb. Compositions calculated for the residual leads vary greatly. In many of the pyroextraction runs the primary eclogitic phases disappeared and the new phases plagioclase, clinopyroxene and a magnetic iron compound were formed. Why part of the lead should have been retained by these new phases is not understood. ?? 1971.

  5. Trace elements and Pb isotopes in soils and sediments impacted by uranium mining.

    PubMed

    Cuvier, A; Pourcelot, L; Probst, A; Prunier, J; Le Roux, G

    2016-10-01

    The purpose of this study is to evaluate the contamination in As, Ba, Co, Cu, Mn, Ni, Sr, V, Zn and REE, in a high uranium activity (up to 21,000Bq∙kg(-1)) area, downstream of a former uranium mine. Different geochemical proxies like enrichment factor and fractions from a sequential extraction procedure are used to evaluate the level of contamination, the mobility and the availability of the potential contaminants. Pb isotope ratios are determined in the total samples and in the sequential leachates to identify the sources of the contaminants and to determine the mobility of radiogenic Pb in the context of uranium mining. In spite of the large uranium contamination measured in the soils and the sediments (EF≫40), trace element contamination is low to moderate (2Pb enrichment is highlighted, the Pb isotopic signature of the contaminated soils is strongly radiogenic. Measurements performed on the sequential leachates reveal inputs of radiogenic Pb in the most mobile fractions of the contaminated soil. Inputs of low-mobile radiogenic Pb from mining activities may also contribute to the Pb signature recorded in the residual phase of the contaminated samples. We demonstrate that Pb isotopes are efficient tools to trace the origin and the mobility of the contaminants in environments affected by uranium mining. PMID:27220101

  6. Effects of simple acid leaching of crushed and powdered geological materials on high-precision Pb isotope analyses

    NASA Astrophysics Data System (ADS)

    Todd, Erin; Stracke, Andreas; Scherer, Erik E.

    2015-07-01

    We present new results of simple acid leaching experiments on the Pb isotope composition of USGS standard reference material powders and on ocean island basalt whole rock splits and powders. Rock samples were leached with cold 6 N HCl in an ultrasonic bath, then on a hot plate, and washed with ultrapure H2O before sample digestion in HF-HNO3 and chromatographic purification of Pb. Lead isotope analyses were measured by Tl-doped MC-ICPMS. Intrasession and intersession analytical reproducibilities of repeated analyses of both synthetic Pb solutions and Pb from single digests of chemically processed natural samples were generally better than 100 ppm (2 SD). The comparison of leached and unleached samples shows that leaching consistently removes variable amounts of contaminants that differ in Pb isotopic composition for different starting materials. For repeated digests of a single sample, analyses of leached samples reproduce better than those of unleached ones, confirming that leaching effectively removes most of the heterogeneously distributed extraneous Pb. Nevertheless, the external reproducibility of leached samples is still up to an order of magnitude worse than that of Pb solution standards (˜100 ppm). More complex leaching methods employed by earlier studies yield Pb isotope ratios within error of those produced by our method and at similar levels of reproducibility, demonstrating that our simple leaching method is as effective as more complex leaching techniques. Therefore, any Pb isotope heterogeneity among multiple leached digests of samples in excess of the external reproducibility is attributed to inherent isotopic heterogeneity of the sample. The external precision of ˜100 ppm (2 SD) achieved for Pb isotope ratio determination by Tl-doped MC-ICPMS is thus sufficient for most rocks. The full advantage of the most precise Pb isotope analytical methods is only realized in cases where the natural isotopic heterogeneity among samples in a studied suite is

  7. Enhanced Continental Weathering on Antarctica During the Mid Miocene Climatic Optima Based on Pb Isotopes

    NASA Astrophysics Data System (ADS)

    Martin, E. E.; Fenn, C.; Basak, C.

    2012-12-01

    Feedbacks between climate and continental weathering can be monitored over geologic time scales using Pb isotopes preserved in marine sediments. During chemical weathering, radiogenic Pb is preferentially released to the dissolved phase, producing weathering solutions with more radiogenic isotopic values than the parent rock. The offset between the composition of the solution and rock tend to increase with the intensity of incongruent weathering (von Blanckenburg and Nägler, 2001; Harlavan and Erel, 2002). The seawater isotopic signal extracted from Fe-Mn oxides on bulk marine sediments is interpreted to represent the composition of local dissolved weathering inputs. For example, increasing seawater Pb isotopes observed during the most recent deglaciation are believed to reflect enhanced weathering of newly exposed glacial rock flour under warm conditions (Foster and Vance, 2006; Kurzweil et al., 2010). For this study we evaluated Nd and Pb isotopes from both the seawater fraction (extracted from Fe-Mn oxides) and parent rock (the detrital fraction of marine sediment) during the Mid-Miocene Climatic Optimum (MMCO) and subsequent cooling and East Antarctic Ice Sheet (EAIS) expansion (18 to 8 Ma) from Ocean Drilling Program site 744 on Kerguelen Plateau (2300 m; Indian sector) and sites 689 and 690 on Maud Rise (2080 m and 2914 m; Atlantic sector). The absolute value of seawater 206Pb/204Pb and separation between values for seawater and detrital fractions increased during the MMCO, suggesting enhanced weathering in proglacial and deglaciated areas exposed by ice sheet meltback during the warm interval. During the ensuing cooling, seawater values and the offset between the two archives decreased. Similar trends are displayed by 207Pb/204Pb and 208Pb/204Pb, although 207Pb/204Pb detrital values tend to be higher than seawater values. Reconstructions of atmospheric pCO2 in the Miocene have suggested both 1) decoupling between pCO2 and climate with consistently low

  8. The use of Pb, Sr, and Hg isotopes in Great Lakes precipitation as a tool for pollution source attribution.

    PubMed

    Sherman, Laura S; Blum, Joel D; Dvonch, J Timothy; Gratz, Lynne E; Landis, Matthew S

    2015-01-01

    The anthropogenic emission and subsequent deposition of heavy metals including mercury (Hg) and lead (Pb) present human health and environmental concerns. Although it is known that local and regional sources of these metals contribute to deposition in the Great Lakes region, it is difficult to trace emissions from point sources to impacted sites. Recent studies suggest that metal isotope ratios may be useful for distinguishing between and tracing source emissions. We measured Pb, strontium (Sr), and Hg isotope ratios in daily precipitation samples that were collected at seven sites across the Great Lakes region between 2003 and 2007. Lead isotope ratios ((207)Pb/(206)Pb=0.8062 to 0.8554) suggest that Pb deposition was influenced by coal combustion and processing of Mississippi Valley-Type Pb ore deposits. Regional differences in Sr isotope ratios ((87)Sr/(86)Sr=0.70859 to 0.71155) are likely related to coal fly ash and soil dust. Mercury isotope ratios (δ(202)Hg=-1.13 to 0.13‰) also varied among the sites, likely due to regional differences in coal isotopic composition, and fractionation occurring within industrial facilities and in the atmosphere. These data represent the first combined characterization of Pb, Sr, and Hg isotope ratios in precipitation collected across the Great Lakes region. We demonstrate the utility of multiple metal isotope ratios in parallel with traditional trace element multivariate statistical modeling to enable more complete pollution source attribution. PMID:25265397

  9. U-Pb zircon geochronology, Sr-Nd geochemistry, petrogenesis and tectonic setting of Mahoor granitoid rocks (Lut Block, Eastern Iran)

    NASA Astrophysics Data System (ADS)

    Beydokhti, Roohollah Miri; Karimpour, Mohammad Hassan; Mazaheri, Seyed Ahmad; Santos, José Francisco; Klötzli, Urs

    2015-11-01

    The Mahoor Cu-Zn-bearing porphyritic granitoid rocks belong to the Lut Block volcanic-plutonic belt (central Eastern Iran). These granitoid rocks occur mainly as dykes and stocks that intrude into Eocene volcanics and pyroclastic rocks. Petrographically, all the studied intrusives display porphyritic textures with mm-sized phenocrysts, most commonly of plagioclase and hornblende, embedded in a fine-grained groundmass with variable amounts of plagioclase, hornblende, clinopyroxene, quartz and opaque minerals. Hydrothermal alteration affected these granitoid rocks, as revealed by the common occurrence of sericite, chlorite, titanite, epidote and calcite. Chemical classification criteria show that the intrusives may be named as gabbrodiorites, diorites, monzodiorites and tonalites. Major elements geochemistry reveals that all the studied lithologies are typically metaluminous (A/CNK ⩽ 0.9). Magnetic susceptibility (1485 × 10-5 SI) together with mineralogical and geochemical features shows that they belong to magnetite granitoid series (I-type). Trace element patterns normalized to chondrite and primitive mantle are very similar to each other and show enrichments in LREE relative to HREE and in LILE relative to HFSE, as well as negative anomalies of Ta, Nb and Ti. Eu/Eu∗ ratios vary from 0.88 (in the most mafic composition) to 0.65, showing that plagioclase played a role in magma differentiation. LA-MC-ICP-MS U-Pb zircon data from a diorite, yielded similar concordia ages of ca. 31.88 ± 0.2 Ma (Error: 2σ), which corresponds to the Oligocene period. These granitoid rocks have (87Sr/86Sr)i values vary between 0.7055 and 0.7063. In terms of isotopic compositions, while εNdi is between -0.6 and -2.5, suggesting that magmas underwent contamination through being exposed to the continental crust. The whole set of geochemical data agree with the emplacement of the studied intrusions in a magmatic belt above a subduction zone. Primitive magmas should have formed by

  10. Preliminary Report on U-Th-Pb Isotope Systematics of the Olivine-Phyric Shergottite Tissint

    NASA Technical Reports Server (NTRS)

    Moriwaki, R.; Usui, T.; Yokoyama, T.; Simon, J. I.; Jones, J. H.

    2014-01-01

    Geochemical studies of shergottites suggest that their parental magmas reflect mixtures between at least two distinct geochemical source reservoirs, producing correlations between radiogenic isotope compositions, and trace element abundances.. These correlations have been interpreted as indicating the presence of a reduced, incompatible-element- depleted reservoir and an oxidized, incompatible-element-rich reservoir. The former is clearly a depleted mantle source, but there has been a long debate regarding the origin of the enriched reservoir. Two contrasting models have been proposed regarding the location and mixing process of the two geochemical source reservoirs: (1) assimilation of oxidized crust by mantle derived, reduced magmas, or (2) mixing of two distinct mantle reservoirs during melting. The former clearly requires the ancient martian crust to be the enriched source (crustal assimilation), whereas the latter requires a long-lived enriched mantle domain that probably originated from residual melts formed during solidification of a magma ocean (heterogeneous mantle model). This study conducts Pb isotope and U-Th-Pb concentration analyses of the olivine-phyric shergottite Tissint because U-Th-Pb isotope systematics have been intensively used as a powerful radiogenic tracer to characterize old crust/sediment components in mantle- derived, terrestrial oceanic island basalts. The U-Th-Pb analyses are applied to sequential acid leaching fractions obtained from Tissint whole-rock powder in order to search for Pb isotopic source components in Tissint magma. Here we report preliminary results of the U-Th-Pb analyses of acid leachates and a residue, and propose the possibility that Tissint would have experienced minor assimilation of old martian crust.

  11. Helium- and lead-isotope geochemistry of oceanic volcanic rocks from the East Pacific and South Atlantic. Doctoral thesis

    SciTech Connect

    Graham, D.W.

    1987-01-01

    Glassy basalts erupted at young Pacific seamounts and along the mid-ocean ridge in the South Atlantic, and volcanic rocks from the island of St. Helena were studied for He and Pb isotopes. (U+TH)/He ages of seamount alkali basalts were determined from the isotope disequilibrium of (3)He/(4)He between He trapped in vesicles and that dissolved in the glass phase. The method allows alkalic lavas to be dated in the age range of 103 to 106 years. Tholclites at the EPR seamounts have He, Pb, Sr and Nd isotope compositions indistinguishable from MORB, while associated alkali basalts show more radiogenic signatures. The low (3)He/(4)He in the vesicles of alkali basalts (1.2-2.6 RA), their low helium concentrations, and systematic variations with extent of differentiation suggest that magmatic processes influence (3)He/(4)He in these alkalic lavas. Pb-Sr-Nd isotopes at Shimada seamount (17 deg N, 117 deg W) indicate the presence of enriched mantle beneath the East Pacific which resembles that beneath Samoa. Low (3)He/(4)He (4-5 RA) appears to be an inherent characteristic of the component. Much of the South Atlantic ridge axis displays (3)He/(4)He lower than normal MORB, and is apparently contaminated by off-axis hotspots. He-Pb systematics along the ridge suggest that (3)He/(4)He at St. Helena is less than MORB, consistent with values measured by in vacuo crushing of olivine and pyroxene in St. Helena rocks (approx. 5.8 RA).

  12. Large-scale shell-model calculations on the spectroscopy of N <126 Pb isotopes

    NASA Astrophysics Data System (ADS)

    Qi, Chong; Jia, L. Y.; Fu, G. J.

    2016-07-01

    Large-scale shell-model calculations are carried out in the model space including neutron-hole orbitals 2 p1 /2 ,1 f5 /2 ,2 p3 /2 ,0 i13 /2 ,1 f7 /2 , and 0 h9 /2 to study the structure and electromagnetic properties of neutron-deficient Pb isotopes. An optimized effective interaction is used. Good agreement between full shell-model calculations and experimental data is obtained for the spherical states in isotopes Pb-206194. The lighter isotopes are calculated with an importance-truncation approach constructed based on the monopole Hamiltonian. The full shell-model results also agree well with our generalized seniority and nucleon-pair-approximation truncation calculations. The deviations between theory and experiment concerning the excitation energies and electromagnetic properties of low-lying 0+ and 2+ excited states and isomeric states may provide a constraint on our understanding of nuclear deformation and intruder configuration in this region.

  13. Field isotopic study of lead fate and compartmentalization in earthworm-soil-metal particle systems for highly polluted soil near Pb recycling factory.

    PubMed

    Goix, Sylvaine; Mombo, Stéphane; Schreck, Eva; Pierart, Antoine; Lévêque, Thibaut; Deola, Frédéric; Dumat, Camille

    2015-11-01

    Earthworms are important organisms in soil macrofauna and play a key role in soil functionality, and consequently in terrestrial ecotoxicological risk assessments. Because they are frequently observed in soils strongly polluted by metals, the influence of earthworm bioturbation on Pb fate could therefore be studied through the use of Pb isotopes. Total Pb concentrations and isotopic composition ((206)Pb, (207)Pb and (208)Pb) were then measured in earthworms, casts and bulk soils sampled at different distance from a lead recycling factory. Results showed decreasing Pb concentrations with the distance from the factory whatever the considered matrix (bulk soils, earthworm bodies or cast samples) with higher concentrations in bulk soils than in cast samples. The bivariate plot (208)Pb/(206)Pb ratios versus (206)Pb/(207)Pb ratios showed that all samples can be considered as a linear mixing between metallic process particulate matter (PM) and geochemical Pb background. Calculated anthropogenic fraction of Pb varied between approximately 84% and 100%. Based on Pb isotopic signatures, the comparison between casts, earthworms and bulk soils allowed to conclude that earthworms preferentially ingest the anthropogenic lead fraction associated with coarse soil organic matter. Actually, soil organic matter was better correlated with Pb isotopic ratios than with Pb content in soils. The proposed hypothesis is therefore a decrease of soil organic matter turnover due to Pb pollution with consequences on Pb distribution in soils and earthworm exposure. Finally, Pb isotopes analysis constitutes an efficient tool to study the influence of earthworm bioturbation on Pb cycle in polluted soils. PMID:26025429

  14. High-precision Pb Isotopes Reveal Two Small Magma Bodies Beneath the Summit of Kilauea Volcano

    NASA Astrophysics Data System (ADS)

    Pietruszka, A. J.; Heaton, D. E.; Marske, J. P.; Garcia, M. O.

    2013-12-01

    The summit magma storage reservoir of Kilauea Volcano is one of the most important components of the volcano's magmatic plumbing system, but its geometry is poorly known. High-precision Pb isotopic analyses of Kilauea summit lavas (1959-1982) define the minimum number of magma bodies within the summit reservoir and their volumes. The 206Pb/204Pb ratios of these lavas display a temporal decrease due to changes in the composition of the parental magma delivered to the volcano. Analyses of multiple lavas from some individual eruptions reveal small but significant differences in 206Pb/204Pb. The extra-caldera lavas from Aug. 1971 and Jul. 1974 display lower Pb isotope ratios and higher MgO contents (10 wt. %) than the intra-caldera lavas (MgO ~7-8 wt. %) from each eruption. From 1971 to 1982, the 206Pb/204Pb ratios of the lavas define two separate decreasing temporal trends. The intra-caldera lavas from 1971, 1974, 1975, Apr. 1982 and the lower MgO lavas from Sep. 1982 have higher 206Pb/204Pb ratios at a given time (compared to the extra-caldera lavas and the higher MgO lavas from Sep. 1982). These trends require that the intra- and extra-caldera lavas (and the Sep. 1982 lavas) were supplied from two separate, partially isolated magma bodies. Numerous studies (Fiske and Kinoshita, 1969; Klein et al., 1987) have long identified the locus of Kilauea's summit reservoir ~2 km southeast of Halemaumau (HMM) at a depth of ~2-7 km, but more recent investigations have discovered a second magma body located <1 km below the east rim of HMM (Battaglia et al., 2003; Johnson et al., 2010). The association between the vent locations of the extra-caldera lavas near the southeast rim of the caldera and their higher MgO contents suggests that these lavas tapped the deeper magma body. In contrast, the lower MgO intra-caldera lavas were likely derived from the shallow magma body beneath HMM. Residence time modeling based on the Pb isotope ratios of the lavas suggests that the magma volume

  15. Steep REE patterns and enriched Pb isotopes in southern Central American arc magmas: Evidence for forearc subduction erosion?

    NASA Astrophysics Data System (ADS)

    Goss, A. R.; Kay, S. M.

    2006-05-01

    The appearance of adakitic magmas with steep rare earth element (REE) patterns in southern Costa Rica and Panama at ˜4 Ma coincides with the collision of the Cocos Ridge and the inception of slab shallowing along the margin. Distinctly higher 206Pb/204Pb and 208Pb/204Pb ratios in these adakitic lavas than in older Miocene lavas suggest that components enriched in radiogenic Pb also entered the mantle magma source at ˜4 Ma. Published Pb-isotopic data for Central American arc lavas show that a similar radiogenic component is not present in lavas farther north and that maxima in post-Miocene 206Pb/204Pb and 208Pb/204Pb ratios occur in central Costa Rica and western Panama. Cretaceous and early Tertiary ophiolites in the forearc, whose origins have been linked to the Galápagos hot spot, show a similar spatial pattern in Pb isotopic ratios. The incorporation of ophiolitic forearc crust into the mantle wedge by forearc subduction erosion can explain the along-arc spatial and temporal pattern of Pb-isotopic ratios in southern Central American arc lavas. Partial melting of crust removed from the base of the forearc and subjected to high-pressure metamorphism in the subduction channel provides an explanation for the steep adakitic REE patterns in some Costa Rican and Panamanian arc lavas.

  16. Isotopic and trace element geochemistry of alkalic-mafic-ultramafic-carbonatitic complexes and flood basalts in NE India: Origin in a heterogeneous Kerguelen plume

    NASA Astrophysics Data System (ADS)

    Ghatak, Arundhuti; Basu, Asish R.

    2013-08-01

    , nephelinites, sovites, melteigite in the first group and syenites and ijolites in the second. The Nd-Sr-Pb-isotopic and trace element geochemistry of the first group of carbonatitic-ultrabasic rocks are consistent with similar data of the RBST lavas of the present and previous studies, and are modeled as derived from a relatively primitive carbonated garnet peridotite source in the KP. In contrast, the syenites and ijolites of the second group show a wide range of Nd-Sr-Pb isotopic compositions, modeled by low-degree melts of an ancient recycled carbonated eclogite also in the KP. The KP thus reflects heterogeneities in the lower mantle-derived plume with carbonated components yielding ultrabasic melts at greater depths with low-degree melting, followed by rise of the plume at shallower depths causing tholeiitic flood basalt volcanism. Collectively, these data imply a zone of influence of the plate-motion-reconstructed KP head for ˜1000 km around the Bengal Basin, as represented by the widely scattered and diverse rock types of the RBST.

  17. Boron occurrence in halite and boron isotope geochemistry of halite in the Qarhan Salt Lake, western China

    NASA Astrophysics Data System (ADS)

    Fan, QiShun; Ma, YunQi; Cheng, HuaiDe; Wei, HaiCheng; Yuan, Qin; Qin, ZhanJie; Shan, FaShou

    2015-06-01

    Previous studies have investigated boron (B) isotope composition of salt lake brines in the Qaidam Basin, western China. However, the research on B isotope geochemistry of halite from a sediment core in a typical sedimentary basin has been very limited. In this study, a 102-m-long drill core (ISL1A) was recovered from Qarhan Salt Lake in eastern Qaidam Basin. Forty-three halite samples from upper 44.0 m in ISL1A were collected and analyzed for chemical compositions (K+, Na+, Ca2 +, Mg2 +, Cl-, SO42 -, Sr2 + and B3 +) and B isotopes in order to investigate their relationships, and B isotope fractionation between halite and brines in the Qarhan Salt Lake. The results show that: (1) more B3 + and Mg2 + values in halite are low concentrations and more concentrated, and low B3 + concentrations have a strong correlation with low Mg2 + in halite, which imply that they might be the same source; (2) low Mg2 + values in halite from ISL1A have a similar trend with mMg2 + (molarity) of fluid inclusion brines from two sediment cores (east to ISL1A about 50 km) in the study area, suggesting that low B3 + and Mg2 + concentrations should derive from fluid inclusions in halite based on X-ray diffraction results in ISL1A that no borate and small amount of magnesium salts were deposited; (3) δ11B values of halite in ISL1A range from - 0.35 to + 5.84‰, which are in the range of those of river water and brines (- 1.0 to + 9.6‰), and almost overlapped with those of brines (+ 2.9 to + 7.5‰) in the Qarhan Salt Lake. These results suggest that no or minor B isotope fractionation between halite and brine occurred.

  18. Resolving arc processes through detrital zircon U-Pb geochronology and geochemistry: a case study from the southern California Mesozoic convergent margin

    NASA Astrophysics Data System (ADS)

    Johnston, S. M.; Kylander-Clark, A. R.

    2015-12-01

    Detrital zircon geochronology has been widely exploited to establish temporal characteristics in sedimentary source terranes. Detrital zircon geochemistry, however, has been largely overlooked given results from continentally derived igneous zircon that show subtle intersample variation in trace-element concentrations, and which make correlation between detrital zircon and their host terrane difficult. Nevertheless, recent studies suggest systematically variable geochemistry in McCoy Mountain detrital zircons derived from the southern California Mesozoic arc, and our preliminary data from the Peninsular Ranges batholith indicates strong correlations between whole-rock and zircon geochemistry. Here, we present coupled U-Pb geochronology and geochemistry measured by laser ablation split stream ICPMS on detrital zircons from Nacimiento block forearc sediments in Central California to characterize temporal and geochemical trends in the adjacent Mesozoic arc terrane. 1098 grains of Mesozoic age analyzed from 22 samples in the Nacimiento block define three periods of high magmatic flux in the Permian (270-250 Ma), Jurassic (170-140 Ma), and late Cretaceous (115-90 Ma). Zircon from the Permian arc is the least abundant of the three magmatic pulses, although they consistently display elevated Yb/Gd and U/Yb. Jurassic zircons display consistently low U/Yb, variably elevated Yb/Gd, abruptly higher Th/U and LREE from 155-145, and abruptly lower REE concentrations from 145-140 Ma. Zircon from the Cretaceous arc displays gradually increasing U/Yb, Th/U and LREE, with abruptly decreasing Yb/Gd at 95 Ma. The geochemical trends observed in the Nacimiento block detrital zircons of Cretaceous age are strikingly similar to temporal changes in geochemistry known from Cretaceous arc rocks of the Mojave and Peninsular Ranges, and strongly suggest a southern California provenance for Nacimiento block sediments. Furthermore, the similarity of geochemical trends between Cretaceous detrital

  19. U, Th, and Pb isotopes in hot springs on the Juan de Fuca Ridge

    SciTech Connect

    Chen, J.H.

    1987-10-10

    The concentrations and isotopic compositions of U, Th, and Pb in three hydrothermal fluids from the Juan de Fuca Ridge were determined. The samples consisted of 10.2--57.6% of the pure hydrothermal end-members based on Mg contents. The Pb contents of the samples ranged from 34 to 87 ng/g, U from 1.3 to 3.0 ng/g, and Th from 0.2 to 7.7 pg/g. These samples showed large enrichments of Pb and Th relative to deep-sea water and some depletion of U. They did not show coherent relationships with Mg, however, indicating nonideal mixings between the hot hydrothermal fluids and cold ambient seawater. Particles filtered from these hydrothermal fluids contained significant amounts of Th and Pb which may effectively increase the concentration of these elements in the fluids when acidified. The /sup 234/U//sup 238/U values in all samples show a /sup 234/U enrichment relative to the equilibrium value and have a seawater signature. The Pb isotopic composition of the Juan de Fuca hydrothermal fluids resembles that of 21 /sup 0/N East Pacific Rise and has a uniform mid-ocean ridge basalt signature. The hydrothermal systems at oceanic spreading ridges have circulated through a large volume of basalts. Therefore Pb in these fluids may represent the best average value of the local oceanic crust. From the effects of U deposition from seawater to the crust and Pb extraction from rock to the ocean, the U/Pb ratio in the hydrothermally altered oceanic crust may be increased significantly. copyright American Geophysical Union 1987

  20. Analogous intruder behavior near Ni, Sn, and Pb isotopes

    NASA Astrophysics Data System (ADS)

    Liddick, S. N.; Walters, W. B.; Chiara, C. J.; Janssens, R. V. F.; Abromeit, B.; Ayres, A.; Bey, A.; Bingham, C. R.; Carpenter, M. P.; Cartegni, L.; Chen, J.; Crawford, H. L.; Darby, I. G.; Grzywacz, R.; Harker, J.; Hoffman, C. R.; Ilyushkin, S.; Kondev, F. G.; Larson, N.; Madurga, M.; Miller, D.; Padgett, S.; Paulauskas, S. V.; Rajabali, M. M.; Rykaczewski, K.; Seweryniak, D.; Suchyta, S.; Zhu, S.

    2015-08-01

    Near shell closures, the presence of unexpected states at low energies provides a critical test of our understanding of the atomic nucleus. New measurements for the N =42 isotones Co6927 and Cu7129, along with recent data and calculations in the Ni isotopes, establish a full set of complementary, deformed, intruder states astride the closed-shell 28Ni isotopes. Nuclei with a one-proton hole or one-proton particle adjacent to Z =28 were populated in β -decay experiments and in multinucleon transfer reactions. A β -decaying isomer, with a 750(250)-ms half-life, has been identified in 42,27,69Co. It likely has low spin and accompanies the previously established 7 /2- state. Complementary data for the levels of isotonic 42,29,71Cu support the presence of a deformed, Δ J =1 band built on the proton intruder 7 /2- level at 981 keV. These data, together with recent studies of lower-mass Co and Cu isotopes and extensive work near 68Ni, support the view that intruder states based on particle-hole excitations accompany all closed proton shells with Z ≥28 .

  1. A Teaching Exercise to Introduce Stable Isotope Fractionation of Metals into Geochemistry Courses

    ERIC Educational Resources Information Center

    Weiss, Dominik J.; Harris, Caroline; Maher, Kate; Bullen, Thomas

    2013-01-01

    Variations in the isotopic composition of elements have been widely used to study earth's climate, biosphere, and interior, and more recently to track the fate of contaminants. Within the broad range of elements that exhibit measureable isotopic variations, metal stable isotopes are increasingly applied across the biological, geological,…

  2. Do ages of authigenic K-feldspar date the formation of Mississippi valley-type Pb-Zn deposits, central and southeastern United States?: Pb isotopic evidence

    USGS Publications Warehouse

    Aleinikoff, J.N.; Walter, M.; Kunk, M.J.; Hearn, P.P., Jr.

    1993-01-01

    Pb concentrations and isotopic compositions have been determined for authigenic overgrowths and detrital cores of K-feldspar from Cambrian sedimentary rocks in Texas, Tennessee, and Pennsylvania (group 1) and southeastern Missouri (group 2). Overgrowths and cores were separated by abrasion and analyzed separately. The disparity in Pb isotopic ratios of group 1 overgrowths and Pb in nearby Mississippi Valley-type deposits implies that the regional authigenic K-feldspar event was not synchronous with ore deposition in the southeastern United States. In contrast, Pb isotopic ratios from group 2 authigenic K-feldspar are similar to ratios in ores of southeastern Missouri, suggesting a genetic relation in late Paleozoic time. -from Authors

  3. Growth rate of a deep-sea coral using sup 210 Pb and other isotopes

    SciTech Connect

    Druffel, E.R.M.; King, L.I.; Belastock, R.A.; Buesseler, K.O. )

    1990-05-01

    A deep-sea coral was studied to determine its growth rate and to reconstruct time histories of isotope distributions in the deep ocean. The specimen was collected at a depth of 600 m off Little Bahama Banks using the Deep Submergence Vehicle (DSV) Alvin. The growth rate of the calcitic coral trunk was determined using excess {sup 210}Pb measured in concentric bands. Excess {sup 210}Pb was found in the outer half of the coral's radius, and a growth rate of 0.11 {plus minus} 0.02 mm/a is calculated. Assuming a constant growth rate during formation of the entire trunk, an age of 180 {plus minus} 40 a is estimated for the coral. The decrease observed in radiocarbon activities measured on the same bands (Griffin and Druffel, 1989) concurred with the growth rate estimated from excess {sup 210}Pb activity. {sup 239,240}Pu activities measured by mass spectrometry were also detected in the outer two bands of the coral, as expected from the {sup 210}Pb chronology. Stable oxygen and carbon isotopes measured in samples collected by a variety of techniques are positively correlated. This is evidence of a variable kinetic isotope effect most likely caused by variations in the skeletal growth rate. Long-lived corals such as this specimen have the potential for serving as integrators of seawater chemistry in the deep-sea over several century timescales.

  4. Evaluating the provenance of Permian-Triassic and Palaeocene-Eocene ash beds by high precision U-Pb and Lu-Hf isotopic analyses of zircons: linking local sedimentary records to global events

    NASA Astrophysics Data System (ADS)

    Eivind Augland, Lars; Jones, Morgan; Planke, Sverre; Svensen, Henrik; Tegner, Christian

    2016-04-01

    Zircons are a powerful tool in geochronology and isotope geochemistry, as their affinity for U and Hf in the crystal structure and the low initial Pb and Lu allow for precise and accurate dating by U-Pb ID-TIMS and precise and accurate determination of initial Hf isotopic composition by solution MC-ICP-MS analysis. The U-Pb analyses provide accurate chronostratigraphic controls on the sedimentary successions and absolute age frames for the biotic evolution across geological boundaries. Moreover, the analyses of Lu-Hf by solution MC-ICP-MS after Hf-purification column chemistry provide a powerful and robust fingerprinting tool to test the provenance of individual ash beds. Here we focus on ash beds from Permian-Triassic and Palaeocene successions in Svalbard and from the Palaeocene-Eocene Thermal Maximum (PETM) in Fur, Denmark. Used in combination with whole rock geochemistry from the ash layers and the available geochemical and isotopic data from potential source volcanoes, these data are used to evaluate the provenance of the Permian-Triassic and Palaeocene ashes preserved in Svalbard and PETM ashes in Denmark. If explosive eruptions from volcanic centres such as the Siberian Traps and the North Atlantic Igneous Province (NAIP) can be traced to distal basins as ash layers, they provide robust tests of hypotheses of global synchronicity of environmental changes and biotic crises. In addition, the potential correlation of ash layers with source volcanoes will aid in constraining the extent of explosive volcanism in the respective volcanic centres. The new integrated data sets will also contribute to establish new reference sections for the study of these boundary events when combined with stable isotope data and biostratigraphy.

  5. Stable (206Pb, 207Pb, 208Pb) and radioactive (210Pb) lead isotopes in 1 year of growth of Sphagnum moss from four ombrotrophic bogs in southern Germany: Geochemical significance and environmental implications

    NASA Astrophysics Data System (ADS)

    Shotyk, William; Kempter, Heike; Krachler, Michael; Zaccone, Claudio

    2015-08-01

    The surfaces of Sphagnum carpets were marked with plastic mesh and 1 year later the production of plant matter was harvested in four ombrotrophic bogs from two regions of southern Germany: Upper Bavaria (Oberbayern, OB) and the Northern Black Forest (Nordschwarzwald, NBF). Radioactive, 210Pb was determined in solid samples using ultralow background gamma spectrometry while total Pb concentrations and stable isotopes (206Pb, 207Pb, 208Pb) were determined in acid digests using ICP-SMS. Up to 12 samples (40 × 40 cm) were collected per site, and 6-10 sites investigated per bog. The greatest variations within a given sampling site were in the range 212-532 Bq kg-1 for 210Pb activity, whereas 206Pb/207Pb and 208Pb/206Pb varied less than 1%. The median values of all parameters for the sites (6-10 per bog) were not significantly different. The median activities of 210Pb (Bq kg-1) in the mosses collected from the bogs in NBF (HO = 372 ± 56, n = 55; WI = 342 ± 58, n = 93) were slightly less from those in OB (GS = 394 ± 50, n = 55; KL = 425 ± 58, n = 24). However, the mosses in the NBF bogs exhibited much greater productivity (187-202 g m-2 a-1) compared to those of OB (71-91 g m-2 a-1), and this has a profound impact on the accumulation rates of 210Pb (Bq m-2 a-1), with the bogs in the NBF yielding fluxes (HO = 73 ± 30; WI = 65 ± 20) which are twice those of OB (GS = 29 ± 11; KL = 40 ± 13). Using the air concentrations of 210Pb measured at Schauinsland (SIL) in the southern Black Forest and average annual precipitation, the atmospheric fluxes of 210Pb at SIL (340 Bq m-2 a-1) exceeds the corresponding values obtained from the mosses by a factor of five, providing the first quantitative estimate of the net retention efficiency of 210Pb by Sphagnum. When the 210Pb activities of all moss samples are combined (n = 227), a significant decrease with increasing plant production rate is observed; in contrast, total Pb concentrations show the opposite trend. The contrasting

  6. Inherited Pb isotopic records in olivine antecryst-hosted melt inclusions from Hawaiian lavas

    NASA Astrophysics Data System (ADS)

    Sakyi, Patrick Asamoah; Tanaka, Ryoji; Kobayashi, Katsura; Nakamura, Eizo

    2012-10-01

    Dislocation textures of olivine grains and Pb isotopic compositions (207Pb/206Pb and 208Pb/206Pb) of olivine-hosted melt inclusions in basaltic lavas from three Hawaiian volcanoes (Kilauea, Mauna Loa, and Koolau) were examined. More than 70% of the blocky olivine grains in the studied samples have a regular-shaped dislocation texture with their dislocation densities exceeding 106 cm-2, and can be considered as deformed olivine. The size distribution of blocky olivine grains shows that more than 99% of blocky olivines coarser than 1.2 mm are identified as deformed olivine. These deformed olivine grains are identified as antecrysts, which originally crystallized from previous stages of magmatism in the same shield, followed by plastic deformation prior to entrainment in the erupted host magmas. This study revealed that entrainment of mantle-derived crystallization products by younger batches of magma is an important part of the evolution of magnesium-rich Hawaiian magma. Lead isotopic compositions of melt inclusions hosted in the olivine antecrysts provide information of the evolutionary history of Hawaiian volcanoes which could not have been accessed if only whole rock analyses were carried out. Antecryst-hosted melt inclusions in Kilauea and Koolau lavas demonstrate that the source components in the melting region changed during shield formation. In particular, evidence of interaction of plume-derived melts and upper mantle was observed in the earliest stage of Koolau magmatism.

  7. REE, trace elements, Sr, Pb, C, and O isotopes in a zoned skarn ore deposit

    SciTech Connect

    Langmuir, C.; LeHuray, A.; Fairbanks, R.; Meinert, L.

    1985-01-01

    The Groundhog skarn in the Central Mining District, New Mexico, is zoned along its >2km length adjacent to a dike swarm which trends NE toward the Santa Rita porphyry Cu deposit. Isotopes and trace elements in whole rocks and mineral separates from skarn and adjacent carbonate allow the study of the source of the metals and the systematics of trace element behavior in a skarn system. (1) /sup 87/Sr//sup 86/Sr ratios are uniform (.7083 +/- 1) in the carbonate host, but they range up to .714 in hydrothermal calcite and pyx from the skarn, values distinct from both Santa Rita (.706) and carbonate. (2) delta/sup 18/O (SMOW) in carbonate ranges from (+6.3 -+ 23) and is correlated positively with delta/sup 13/C (-5.6-+2.4) and negatively with /sup 87/Sr//sup 86/Sr. Several trace elements also correlate with delta/sup 18/O. (3) Pb isotopes in galenas lie on the regression line for southwestern New Mexico Proterozoic crust. PbS from the skarn closest to Santa Rita has isotope ratios identical to PbS from the Santa Rita pit. (4) Most of the REE are not in gar or pyx. REE abundances are <1X chondrites after HC1 leaches, but in unleached samples can be >20X chondrites. All pyx separates have deep negative Ce and very deep Eu anomalies. Sr isotopes show that neither Santa Rita magma nor carbonate is the sole source of Sr. Pb isotopes are consistent with a Santa Rita source. The Ce anomaly suggests a seawater source for the REE. The data show that many of the metals in the skarn are not derived from the Santa Rita porphyry, and suggest that different elements may be derived from different source rocks.

  8. Nd, Pb, Sr, and O isotopic characterization of Saudi Arabian Shield terranes

    USGS Publications Warehouse

    Stoeser, D.B.; Frost, C.D.

    2006-01-01

    New Nd, Sr and O isotopic data for granitoid rocks of the Saudi Arabian Shield are presented together with published Nd, Pb, Sr and O isotopic data and all available geologic and geochronologic information to re-evaluate the terranes defined for the Saudi Arabian part of the Arabian-Nubian Shield. Three groups of terranes are identified: 1) the western arc terranes, 2) the eastern arc terranes, and 3) the Khida terrane. The Khida terrane is the only terrane composed of pre-Neoproterozoic continental crust. The western arc terranes are of oceanic arc affinity, and have the least radiogenic Pb and Sr and most radiogenic Nd isotopic compositions and some of the lowest ??18O values of any rocks of the Saudi Arabian Shield. Although some previous studies have characterized the eastern arc terranes as of continental affinity, this study shows that they too are composed of Neoproterozoic oceanic arcs, although their sources have slightly elevated 208Pb/204Pb, Nd, Sri, and ??18O values compared to the western arc terranes. These data suggest that either the isotopic composition of the mantle source for the western arc terranes is more depleted than that of the eastern arc terranes or the eastern arc terranes have been mixed with a small amount of cratonic source material, or both. We further elaborate on the Hulayfah-Ad Dafinah fault zone as a major boundary within the Saudi Arabian portion of the East African Orogen. With further study, its northern extension may be shown to pass through what has been defined as the Hail terrane, and its southern extension appears to lie under cover east of the Tathlith-Malahah terrane and extend into Yemen. It may represent the collision zone between East and West Gondwana, and at the very least it is an important suture between groups of arc terranes of contrasting isotopic composition caught between two converging continents.

  9. Pb-concentrations and Pb-isotope ratios in soils collected along an east-west transect across the United States

    USGS Publications Warehouse

    Reimann, Clemens; Smith, David B.; Woodruff, Laurel G.; Flem, Belinda

    2011-01-01

    Analytical results for Pb-concentrations and isotopic ratios from ca. 150 samples of soil A horizon and ca. 145 samples of soil C horizon collected along a 4000-km east–west transect across the USA are presented. Lead concentrations along the transect show: (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for central to eastern USA (Missouri to Maryland) when compared to the western USA (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern USA (1.35 vs. 1.14). Lead isotopes show a distinct trend across the USA, with the highest 206Pb/207Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g., California, median A-horizon: 1.195; C-horizon: 1.216). The soil C-horizon samples show generally higher 206Pb/207Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The 206Pb/207Pb-isotope ratios in the soil A horizon show a correlation with the total feldspar content for the same 2500-km portion of the transect from east-central Colorado to the Atlantic coast that shows steadily increasing precipitation. No such correlation exists in the soil C horizon. The data demonstrate the importance of climate and weathering on both Pb-concentration and 206Pb/207Pb-isotope ratios in soil samples and natural shifts thereof in the soil profile during soil-forming processes.

  10. {alpha} transitions to coexisting 0{sup +} states in Pb and Po isotopes

    SciTech Connect

    Xu Chang; Ren Zhongzhou

    2007-04-15

    The {alpha}-transitions ({delta}l=0) to ground and first excited 0{sup +} states in neutron deficient Pb and Po isotopes are systematically analyzed by the density-dependent cluster model. The magnitude of nuclear deformation of the coexisting 0{sub 1}{sup +} and 0{sub 2}{sup +} states is extracted directly from the experimental {alpha}-decay energies and half-lives. The phenomenon of shape coexistence around the Z=82 shell closure is clearly demonstrated in our present analysis. The obtained deformation values from Rn {yields} Po {yields} Pb decay chains are generally consistent with both the available experimental and theoretical studies.

  11. Isotope Geochemistry of Calcite Coatings and the Thermal History of the Unsaturated Zone at Yucca Mountain, Nevada

    SciTech Connect

    B.D. Marshall; J.F. Whelan

    2000-07-27

    Calcite and opal coatings found on fracture footwalls and lithophysal cavity bottoms in the volcanic section at Yucca Mountain (exposed in a tunnel) contain a record of gradual chemical and isotopic changes that have occurred in the unsaturated zone. The thin (less than 6 cm) coatings are composed primarily of calcite, opal, chalcedony, and quartz. Fluid inclusions in calcite that homogenize at greater than ambient temperatures provide impetus for geochronologic studies in order to determine the thermal history. In the welded Topopah Spring Tuff (12.7 Ma), U-Pb ages of opal and chalcedony layers provide evidence of a long history of deposition throughout the past 10 m.y. However, these ages can constrain the ages of associated calcite layers only in samples with an easily interpretable microstratigraphy. Strontium isotope ratios in calcite increase with microstratigraphic position from the base up to the outermost surface of the coatings. The strontium incorporated in these coatings records the systematic change in pore-water isotopic composition due to water-rock interaction primarily in the overlying nonwelded tuffs. A one-dimensional advection-reaction model simulates strontium isotope ratios measured in pore water extracted from core in three vertical boreholes adjacent to the tunnel. By calculating the strontium isotope compositions of the rocks at various past times, the model predicts a history of the strontium isotope ratios in the water that matches the record in the calcite and therefore provides approximate ages. Oxygen isotope ratios measured in calcite gradually increase with decreasing model strontium age. Assuming that the oxygen isotope ratio of the percolating water was relatively constant, this trend indicates a gradual cooling of the rocks over millions of years, in agreement with thermal modeling of magma beneath the 12-Ma Timber Mountain caldera just north of Yucca Mountain. This model predicts that temperatures significantly exceeding current

  12. Trace element and isotope geochemistry of Cretaceous-Tertiary boundary sediments: identification of extra-terrestrial and volcanic components

    NASA Technical Reports Server (NTRS)

    Margolis, S. V.; Doehne, E. F.

    1988-01-01

    Trace element and stable isotope analyses were performed on a series of sediment samples crossing the Cretaceous-Tertiary (K-T) boundary from critical sections at Aumaya and Sopelano, Spain. The aim is to possibly distinguish extraterrestrial vs. volcanic or authigenic concentration of platinum group and other elements in K-T boundary transitional sediments. These sediments also have been shown to contain evidence for step-wise extinction of several groups of marine invertebrates, associated with negative oxygen and carbon isotope excursions occurring during the last million years of the Cretaceous. These isotope excursions have been interpreted to indicate major changes in ocean thermal regime, circulation, and ecosystems that may be related to multiple events during latest Cretaceous time. Results to date on the petrographic and geochemical analyses of the Late Cretaceous and Early Paleocene sediments indicate that diagenesis has obviously affected the trace element geochemistry and stable isotope compositions at Zumaya. Mineralogical and geochemical analysis of K-T boundary sediments at Zumaya suggest that a substantial fraction of anomalous trace elements in the boundary marl are present in specific mineral phases. Platinum and nickel grains perhaps represent the first direct evidence of siderophile-rich minerals at the boundary. The presence of spinels and Ni-rich particles as inclusions in aluminosilicate spherules from Zumaya suggests an original, non-diagenetic origin for the spherules. Similar spherules from southern Spain (Caravaca), show a strong marine authigenic overprint. This research represents a new approach in trying to directly identify the sedimentary mineral components that are responsible for the trace element concentrations associated with the K-T boundary.

  13. Time-series analysis of ion and isotope geochemistry of selected springs of the Nevada Test Site, Nye County, Nevada

    SciTech Connect

    Lyles, B.F.; Edkins, J.; Jacobson, R.L.; Hess, J.W.

    1990-11-01

    The temporal variations of ion and isotope geochemistry were observed at six selected springs on the Nevada Test Site, Nye County, Nevada and included: Cane, Whiterock, Captain Jack, Topopah, Tippipah, and Oak Springs. The sites were monitored from 1980 to 1982 and the following parameters were measured: temperature, pH, electrical conductance, discharge, cations (Ca{sup 2+}, Mg{sup 2+}. Na{sup +}, K{sup +}), anions Cl{sup {minus}}, SO{sub 4}{sup 2{minus}}. HCO{sub 3}{sup {minus}}, silica, stable isotopes ({delta}{sup 18}O, {delta}D, {delta}{sup 13}C), and radioactive isotopes ({sup 3}H, {sup 14}C). A more detailed study was continued from 1982 to 1988 at Cane and Whiterock Springs. Field microloggers were installed at these sites in 1985 to measure the high frequency response of temperature, electrical conductance, and discharge to local precipitation. Stage fluctuations near the discharge point dissolve minerals/salts as groundwater inundates the mineralized zone immediately above the equilibrium water table. This phenomena was most noticeable at Whiterock Spring and lagged the discharge response by several hours. Stable isotope analysis of precipitation and groundwater suggests a 1.5 to 2 month travel time for meteoric water to migrate from the recharge area to the discharge point. Groundwater age determinations suggest a mean age of approximately 30 years at Whiterock Spring and possibly older at Cane Spring. However, the short travel time and geochemical integrity of recharge pulses suggest that the waters are poorly mixed along the flow paths. 25 refs., 25 figs., 24 tabs.

  14. The geochemistry and isotopic composition of the mafic and intermediate igneous components of the Cape Granite Suite, South Africa

    NASA Astrophysics Data System (ADS)

    Jordaan, L. J.; Scheepers, R.; Barton, E. S.

    1995-07-01

    A number of small outcrops of igneous rocks, gabbroic to granodioritic in composition, occur scattered throughout the western Cape in South Africa. These outcrops, which are mostly intrusive into the Malmesbury metasedimentary sequence, define a small number of medium-sized plutons. A characteristic feature of the larger plutons is their composite nature. Each pluton consists of multiple intrusive phases; a few show extensive hydrothermal alteration. Plutons from Yzerfontein and Mud River, which occur in the Tygerberg terrane, are high-K calcalkaline (K-trans-alkaline) while all plutons from Malmesbury, which occurs in the Swartland terrane, are tholeiitic. The high-K suite correspond to other I-type Cape granites, whereas the tholeiitic Malmesbury plutons may be a precursor of A-type Cape granites in both the Tygerberg and Swartland terranes. Monzonite from the Yzerfontein pluton yielded a UPb age of 519±7 Ma on zircon mineral separates. Rb-Sr isotope data did not yield reliable ages, possibly due to alteration, but yielded distinct initial isotope ratios for the high-K calc-alkaline and the tholeiitic plutons. The δ34S isotope ratios of pyrite range from 1 to 2.7% for Yzerfontein and from 3.6 to 4.6% for Mud River, suggesting a magmatic source for the pyrite. PbPb data on whole rock and pyrite samples imply crustal input into all the original magmas.

  15. Pb isotopes in the Sunda-Banda arc (Indonesia) as tracers of input from slab, sediment and continental crust

    NASA Astrophysics Data System (ADS)

    Elburg, M. A.; van Bergen, M. J.; Foden, J. D.

    2003-04-01

    Pb isotopic arrays in Quaternary volcanics from the Sunda-Banda arc have previously been interpreted as representing mixing between sub-arc mantle and subducted continental material. The mantle component in the non-collisional section of the arc appears to resemble Indian Ocean-type Mid Ocean Ridge basalt (I-MORB). In the eastern portion of the arc, where the Australian continent collides with the arc, the mantle component has been inferred to have Pb isotopic characteristics similar to Indian Ocean Island Basalt (I-OIB). Compilation of existing Pb and He isotope data on the active arc and combination with new Pb data on the inactive section shows that all volcanoes from the collisional section, independent of their depth to the Benioff zone, have high 208Pb/204Pb for their 207Pb/204Pb ratios, characteristic of I-OIB. However, there is no a-priori physical explanation why an OIB-type source would be tapped at the very moment that continental collision sets in. It is more likely that the Pb isotopic arrays in both the collisional and non-collisional section represent mixing of two subducted components. In the collisional section, this would be Australian upper and lower crust; in the non-collisional section, oceanic crust and entrained sediment. Within the non-collisional section, the Quaternary potassic volcanoes on the island of Sumbawa form a Pb isotopic array in a 208Pb/204Pb versus 207Pb/204Pb diagram that lies in between that of the lower-K non-collisional volcanics, and the samples from the collisional section. This contrasts with 2-4 Ma low-K volcanics from the island, that fall within the field for other low-K volcanoes. The sudden change to potassic volcanism with this particular Pb isotopic signature is thought to represent subduction of oceanic crust with more OIB-type characteristics, perhaps similar to material seen near Christmas Island. Samples from Romang, Wetar, Lirang and south Alor within the extinct section of the arc are characterised by

  16. Characteristics of Heavy Metals and Pb Isotopic Composition in Sediments Collected from the Tributaries in Three Gorges Reservoir, China

    PubMed Central

    Gao, Bo; Zhou, Huaidong; Huang, Yong; Wang, Yuchun; Gao, Jijun; Liu, Xiaobo

    2014-01-01

    The concentrations, distribution, accumulation, and potential ecological risk of heavy metals (Cr, Cu, Zn, Ni, As, Pb, Cd, and Hg) in sediments from the Three Gorges Reservoir (TGR) tributaries were determined and studied. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of heavy metals in sediment of TGR tributaries were higher than the local background values of soils and sediments in China. The assessment by Geoaccumulation Index indicated that Cu, Ni, and Hg were at the “slightly polluted” level and Cd was ranked as the “moderately polluted” level in tributary sediments of TGR. The assessment by Potential Ecological Risk Index showed that Hg and Cd were the predominant elements in tributary sediments in TGR. The Pb isotopic ratios in sediments varied from 1.171 to 1.202 for 206Pb/207Pb and from 2.459 to 2.482 for 208Pb/207Pb in TGR. All Pb isotopic ratios in sediments were similar to those from coal combustion, lead ores (the mining activities and smelting process), and cement material, indicating that these anthropogenic inputs may be the main sources for Pb pollution in sediments of TGR tributaries. PMID:24624045

  17. Thermal history and origin of the Tanzanian Craton from Pb isotope thermochronology of feldspars from lower crustal xenoliths

    NASA Astrophysics Data System (ADS)

    Bellucci, Jeremy J.; McDonough, William F.; Rudnick, Roberta L.

    2011-01-01

    Common and radiogenic Pb isotopic compositions of plagioclase and anti-perthitic feldspars from granulite-facies lower crustal xenoliths from the Labait Volcano on the eastern margin of the Tanzanian Craton have been measured via laser ablation MC-ICP-MS. Common Pb in plagioclase and a single stage Pb evolution model indicate that the lower crust of the Tanzanian Craton was extracted from mantle having a 238U/ 204Pb of 8.1 ± 0.3 and a 232Th/ 238U of 4.3 ± 0.1 at 2.71 ± 0.09 Ga (all uncertainties are 2σ). Since 2.4 Ga, some orthoclase domains within anti-perthites have evolved with a maximum 238U/ 204Pb of 6 and 232Th/ 238U of 4.3. The spread in Pb isotopic composition in the anti-perthitic feldspars yields single crystal Pb-Pb isochrons of ˜ 2.4 Ga, within uncertainty of U-Pb zircon ages from the same sample suite. The Pb isotopic heterogeneities imply that these granulites resided at temperatures < 600 °C in the lower crust of the Tanzanian Craton from ca. 2.4 Ga to the present. In concert with the chemistry of surface samples, mantle xenoliths, and lower crustal xenoliths, our data imply that the cratonic lithosphere in Tanzania formed ca. ˜ 2.7 Ga, in a convergent margin setting, and has remained undisturbed since 2.7 Ga.

  18. Characteristics of heavy metals and Pb isotopic composition in sediments collected from the tributaries in three Gorges Reservoir, China.

    PubMed

    Gao, Bo; Zhou, Huaidong; Huang, Yong; Wang, Yuchun; Gao, Jijun; Liu, Xiaobo

    2014-01-01

    The concentrations, distribution, accumulation, and potential ecological risk of heavy metals (Cr, Cu, Zn, Ni, As, Pb, Cd, and Hg) in sediments from the Three Gorges Reservoir (TGR) tributaries were determined and studied. Pb isotopic compositions in sediments were also measured to effectively identify the potential Pb sources. The results showed that the average concentrations of heavy metals in sediment of TGR tributaries were higher than the local background values of soils and sediments in China. The assessment by Geoaccumulation Index indicated that Cu, Ni, and Hg were at the "slightly polluted" level and Cd was ranked as the "moderately polluted" level in tributary sediments of TGR. The assessment by Potential Ecological Risk Index showed that Hg and Cd were the predominant elements in tributary sediments in TGR. The Pb isotopic ratios in sediments varied from 1.171 to 1.202 for (206)Pb/(207)Pb and from 2.459 to 2.482 for (208)Pb/(207)Pb in TGR. All Pb isotopic ratios in sediments were similar to those from coal combustion, lead ores (the mining activities and smelting process), and cement material, indicating that these anthropogenic inputs may be the main sources for Pb pollution in sediments of TGR tributaries. PMID:24624045

  19. Assessing of distribution, mobility and bioavailability of exogenous Pb in agricultural soils using isotopic labeling method coupled with BCR approach.

    PubMed

    Huang, Zhi-Yong; Xie, Hong; Cao, Ying-Lan; Cai, Chao; Zhang, Zhi

    2014-02-15

    The contamination of Pb in agricultural soils is one of the most important ecological problems, which potentially results in serious health risk on human health through food chain. Hence, the fate of exogenous Pb contaminated in agricultural soils is needed to be deeply explored. By spiking soils with the stable enriched isotopes of (206)Pb, the contamination of exogenous Pb(2+) ions in three agricultural soils sampled from the estuary areas of Jiulong River, China was simulated in the present study, and the distribution, mobility and bioavailability of exogenous Pb in the soils were investigated using the isotopic labeling method coupled with a four-stage BCR (European Community Bureau of Reference) sequential extraction procedure. Results showed that about 60-85% of exogenous Pb was found to distribute in reducible fractions, while the exogenous Pb in acid-extractable fractions was less than 1.0%. After planting, the amounts of exogenous Pb presenting in acid-extractable, reducible and oxidizable fractions in rhizospheric soils decreased by 60-66%, in which partial exogenous Pb was assimilated by plants while most of the metal might transfer downward due to daily watering and applying fertilizer. The results show that the isotopic labeling technique coupled with sequential extraction procedures enables us to explore the distribution, mobility and bioavailability of exogenous Pb contaminated in soils, which may be useful for the further soil remediation. PMID:24412626

  20. Evolution of Nd and Pb isotopes in Central Pacific seawater from ferromanganese crusts

    USGS Publications Warehouse

    Ling, H.F.; Burton, K.W.; O'Nions, R. K.; Kamber, B.S.; Von Blanckenburg, F.; Gibb, A.J.; Hein, J.R.

    1997-01-01

    Hydrogenetic ferromanganese crusts incorporate elements from ambient seawater during their growth on seamounts. By analysing Nd, Pb and Be isotope profiles within crusts it is possible to reconstruct seawater tracer histories. Depth profiles of 10Be/9Be ratios in three Pacific ferromanganese crusts have been used to obtain growth rates which are between 1.4 and 3.8 mm/Ma. Nd and Pb isotopes provide intact records of isotopic variations in Pacific seawater over the last 20 Ma or more. There were only small changes in Pb isotope composition in the last 20 Ma. This indicates a constant Pb composition for the erosional sources and suggests further that erosional Nd inputs may have been uniform too. ??ND values vary considerably with time and most probably reflect changes in ocean circulation. The ??ND values of the crusts not only vary as a function of age but also as a function of water depth. From 25 to 0 Ma, crust VA13/2 from 4.8 km water depth has a similar pattern of ??ND variation to the two shallower crusts from 1.8 and 2.3 km, but about 1.0 to 1.5 units more negative. This suggests that ??ND stratification in Pacific seawater, as demonstrated for the present day, has been maintained for at least 20 Ma. Each crust shows a decrease in ??ND from 3-5 Ma to the present, which is interpreted in terms of an increase in the NADW component present in the Pacific. From 10 to 3-5 Ma ago the crusts show an increase in ??ND. This suggests a decreasing role for a deep water source with ??ND less than circum-Pacific sources. In this regard the Panamanian gateway restriction from ???10 Ma with final closure at 3-5 Ma may have played an important role in reducing access of Atlantic-derived Nd to the Pacific.

  1. Cu-Zn-Pb multi isotopic characterization of a small watershed (Loire river basin, France)

    NASA Astrophysics Data System (ADS)

    Desaulty, A. M.; Millot, R.; Perret, S.; Bourrain, X.

    2015-12-01

    Combating metal pollution in surface water is a major environmental, public health and economic issue. Knowledge of the behavior of metals, such as copper (Cu), zinc (Zn) and lead (Pb) in sediments and dissolved load, is a key factor to improve the management of rivers. Recent advances in mass spectrometry related to the development of MC-ICPMS allow to analyze the isotopic composition of these elements, and previous studies show the effectiveness of isotopic analyses to determine the anthropogenic sources of pollution in environment. The goal of this study is to use the Cu-Zn-Pb multi-isotopic signature to track the pollutions in surface water, and to understand the complex processes causing the metals mobilization and transport in environment. More particularly we investigate the mechanisms of distribution between the dissolved load and particulate load, known to play an important role in the transport of metals through river systems. As case study, we chose a small watershed, poorly urbanized in the Loire river basin. Its spring is in a pristine area, while it is only impacted some kilometers further by the releases rich in metals coming from a hospital water treatment plant. First a sampling of these liquid effluents as well as dissolved load and sediment from upstream to downstream was realized and their concentrations and isotopic data were determined. Then to simulate a lot of potential natural and anthropogenic modifications of environmental conditions, we made sequential extraction protocol using various reagents on the sediments. Isotopic analyzes were performed also on the various extracting solutions. Isotopic ratios were measured using a Neptune MC-ICPMS at the BRGM, after a protocol of purification for Zn and Cu. The results showed that, these isotopic systematics reveal important informations about the mechanists of mobilization and transport of metals through river systems. However experiments performed under laboratory conditions will be necessary

  2. Theoretical studies on the alpha decay of 178-220Pb isotopes

    NASA Astrophysics Data System (ADS)

    Santhosh, K. P.; Sukumaran, Indu; Priyanka, B.

    2015-03-01

    The α decay half lives for the isotopes of Pb (Z = 82) nuclei in the range 178 ≤ A ≤ 220 have been studied systematically within the Coulomb and proximity potential model (CPPM) and also within CPPM with modified deformation dependent assault frequency. The half-lives have been evaluated using the experimental Q values. The computed half-lives are compared with the experimental data and also with the existing theoretical models and are found in good agreement. Using our model we could also demonstrate the influence of the neutron shell closure (N = 126) in the alpha decay half lives through the Geiger-Nuttall (GN) plots of ln ⁡ λ vs. ZE - 1 / 2, log10 ⁡T1/2 vs. Q - 1 / 2 and - ln ⁡ P vs. ZQ - 1 / 2. We have also studied the Universal curve of log10 ⁡T1/2 vs. - ln ⁡ P, where all the alpha transitions could be plotted as a single line. The study on the various forms of GN plots, with various variables, enabled us in developing a new, simple relation for the alpha decay half lives of the Pb isotopes and our study also revealed that CPPM and CPPM with the modified assault frequency are appropriate for the alpha decay studies of Pb isotopes and thus can be successfully applied to other alpha emitter nuclides.

  3. Pb Isotopes as an Indicator of the Asian Contribution to Particulate Air Pollution in Urban California

    SciTech Connect

    Ewing, Stephanie A.; Christensen, John N.; Brown, Shaun T.; Vancuren, Richard A.; Cliff, Steven S.; DePaolo, Donald J.

    2010-10-25

    During the last two decades, expanding industrial activity in east Asia has led to increased production of airborne pollutants that can be transported to North America. Previous efforts to detect this trans-Pacific pollution have relied upon remote sensing and remote sample locations. We tested whether Pb isotope ratios in airborne particles can be used to directly evaluate the Asian contribution to airborne particles of anthropogenic origin in western North America, using a time series of samples from a pair of sites upwind and downwind of the San Francisco Bay Area. Our results for airborne Pb at these sites indicate a median value of 29 Asian origin, based on mixing relations between distinct regional sample groups. This trans-Pacific Pb is present in small quantities but serves as a tracer for airborne particles within the growing Asian industrial plume. We then applied this analysis to archived samples from urban sites in central California. Taken together, our results suggest that the analysis of Pb isotopes can reveal the distribution of airborne particles affected by Asian industrial pollution at urban sites in northern California. Under suitable circumstances, this analysis can improve understanding of the global transport of pollution, independent of transport models.

  4. Controls on ostracod valve geochemistry: Part 2. Carbon and oxygen isotope compositions

    NASA Astrophysics Data System (ADS)

    Decrouy, Laurent; Vennemann, Torsten Walter; Ariztegui, Daniel

    2011-11-01

    The stable carbon and oxygen isotope compositions of fossil ostracods are powerful tools to estimate past environmental and climatic conditions. The basis for such interpretations is that the calcite of the valves reflects the isotopic composition of water and its temperature of formation. However, calcite of ostracods is known not to form in isotopic equilibrium with water and different species may have different offsets from inorganic precipitates of calcite formed under the same conditions. To estimate the fractionation during ostracod valve calcification, the oxygen and carbon isotope compositions of 15 species living in Lake Geneva were related to their autoecology and the environmental parameters measured during their growth. The results indicate that: (1) Oxygen isotope fractionation is similar for all species of Candoninae with an enrichment in 18O of more than 3‰ relative to equilibrium values for inorganic calcite. Oxygen isotope fractionation for Cytheroidea is less discriminative relative to the heavy oxygen, with enrichments in 18O for these species of 1.7 to 2.3‰. Oxygen isotope fractionations for Cyprididae are in-between those of Candoninae and Cytheroidea. The difference in oxygen isotope fractionation between ostracods and inorganic calcite has been interpreted as resulting from a vital effect. (2) Comparison with previous work suggests that oxygen isotope fractionation may depend on the total and relative ion content of water. (3) Carbon isotope compositions of ostracod valves are generally in equilibrium with DIC. The specimens' δ 13C values are mainly controlled by seasonal variations in δ 13C DIC of bottom water or variation thereof in sediment pore water. (4) Incomplete valve calcification has an effect on carbon and oxygen isotope compositions of ostracod valves. Preferential incorporation of CO32- at the beginning of valve calcification may explain this effect. (5) Results presented here as well as results from synthetic carbonate

  5. Pyrogenic inputs of anthropogenic Pb and Hg to sediments of the Hood Canal, Washington, in the 20th century: source evidence from stable Pb isotopes and PAH signatures.

    PubMed

    Louchouarn, Patrick; Kuo, Li-Jung; Brandenberger, Jill M; Marcantonio, Franco; Garland, Charity; Gill, Gary A; Cullinan, Valerie

    2012-06-01

    Combustion-derived PAHs and stable Pb isotopic signatures ((206)Pb/(207)Pb) in sedimentary records assisted in reconstructing the sources of atmospheric inputs of anthropogenic Pb and Hg to the Hood Canal, Washington. The sediment-focusing corrected peak fluxes of total Pb and Hg (1960-70s) demonstrate that the watershed of Hood Canal has received greater atmospheric inputs of these metals than its mostly rural land use would predict. The tight relationships between the Pb, Hg, and organic markers in the cores indicate that these metals are derived from industrial combustion emissions. Multiple lines of evidence point to the Asarco smelter, located in the Main Basin of Puget Sound, as the major emission source of these metals to the watershed of the Hood Canal. The evidence includes (1) similar PAH isomer ratios in sediment cores from the two basins, (2) the correlations between Pb, Hg, and Cu in sediments and previously studied environmental samples including particulate matter emitted from the Asarco smelter's main stack at the peak of production, and (3) Pb isotope ratios. The natural rate of recovery in Hood Canal since the 1970s, back to preindustrial metal concentrations, was linear and contrasts with recovery rates reported for the Main Basin which slowed post late 1980s. PMID:22541021

  6. Character of the pre-Mesozoic basement along the edge of the western US craton: Pb isotopic evidence from Mesozoic plutonism

    SciTech Connect

    Wooden, J.L.; Kistler, R.W.; Robinson, A.; Tosdal, R.M. ); Wright, J.E. . Dept. of Geology and Geophysics)

    1993-04-01

    The pre-Mesozoic cratonic crust of the western US was a composite of provinces composed mostly of Archean and Early Proterozoic rocks that had been truncated by Late Proterozoic rifting and had some new Paleozoic crust added along the western edge. Mesozoic and younger geologic events greatly obscured this pre-Mesozoic basement along the craton edge. However, the Pb isotopic signatures of Mesozoic plutons provide significant clues to the character of the crust in which they formed or were emplaced because of a strong contrast in Pb concentration between low-Pb, mantle-derived melts and Pb-rich crust. Thus, magmas whether derived from the crust or the mantle with subsequent crustal interaction, will likely have Pb isotopic compositions that reflect those of the crust. In the western US the Pb isotopic compositions of Mesozoic plutonic rocks have strong regional characteristics. Within the Early Proterozoic Mojave crustal province, Mesozoic plutonic rocks have a large range of 206Pb/204Pb ratios that plot above the crustal average, relatively high 207Pb/204Pb ratios that suggest an Archean contribution, and Pb and Sr isotopic compositions that are not correlated and that do not distinguish age groups. At the southern and western edge of this province where some 1.1 Ga rocks are exposed, 208Pb/204Pb ratios lie along the average crust model curve. These data suggest that any individual pluton provides a composite Pb isotopic composition for a discrete vertical section of the crust. Pb isotopic compositions of plutons in the Sierra Nevada and Great Basin are very different from those described above with 206Pb/204Pb ratios starting at 18.6, well-correlated Pb isotopic trends starting below the crustal model but extending to values that require input from the very radiogenic Wyoming province Archean crust, and good correlations between Pb and (1) Sr isotopic compositions and (2) W-E geographic position.

  7. Cenozoic marine geochemistry of thallium deduced from isotopic studies of ferromanganese crusts and pelagic sediments

    USGS Publications Warehouse

    Rehkamper, M.; Frank, M.; Hein, J.R.; Halliday, A.

    2004-01-01

    Cenozoic records of Tl isotope compositions recorded by ferromanganese (Fe-Mn) crusts have been obtained. Such records are of interest because recent growth surfaces of Fe-Mn crusts display a nearly constant Tl isotope fractionation relative to seawater. The time-series data are complemented by results for bulk samples and leachates of various marine sediments. Oxic pelagic sediments and anoxic marine deposits can be distinguished by their Tl isotope compositions. Both pelagic clays and biogenic oozes are typically characterized by ??205Tl greater than +2.5, whereas anoxic sediments have ??205Tl of less than -1.5 (??205Tl is the deviation of the 205Tl/203Tl isotope ratio of a sample from NIST SRM 997 Tl in parts per 104). Leaching experiments indicate that the high ??205Tl values of oxic sediments probably reflect authigenic Fe-Mn oxyhydroxides. Time-resolved Tl isotope compositions were obtained from six Fe-Mn crusts from the Atlantic, Indian, and Pacific oceans and a number of observations indicate that these records were not biased by diagenetic alteration. Over the last 25 Myr, the data do not show isotopic variations that significantly exceed the range of Tl isotope compositions observed for surface layers of Fe-Mn crusts distributed globally (??205 Tl=+12.8??1.2). This indicates that variations in deep-ocean temperature were not recorded by Tl isotopes. The results most likely reflect a constant Tl isotope composition for seawater. The growth layers of three Fe-Mn crusts that are older than 25 Ma show a systematic increase of ??205Tl with decreasing age, from about +6 at 60-50 Ma to about +12 at 25 Ma. These trends are thought to be due to variations in the Tl isotope composition of seawater, which requires that the oceans of the early Cenozoic either had smaller output fluxes or received larger input fluxes of Tl with low ??205Tl. Larger inputs of isotopically light Tl may have been supplied by benthic fluxes from reducing sediments, rivers, and/or volcanic

  8. Heavy metal input to agricultural soils from irrigation with treated wastewater: Insight from Pb isotopes

    NASA Astrophysics Data System (ADS)

    Kloppmann, Wolfram; Cary, Lise; Psarras, Georgios; Surdyk, Nicolas; Chartzoulakis, Kostas; Pettenati, Marie; Maton, Laure

    2010-05-01

    A major objective of the EU FP6 project SAFIR was to overcome certain drawbacks of wastewater reuse through the development of a new irrigation technology combining small-scale modular water treatment plants on farm level and improved irrigation hardware, in the aim to lower the risks related to low quality water and to increase water use efficiency. This innovative technology was tested in several hydro-climatic contexts (Crete, Italy, Serbia, China) on experimental irrigated tomato and potato fields. Here we present the heavy metal variations in soil after medium-term (3 irrigation seasons from 2006-2008) use of treated municipal wastewater with a special focus on lead and lead isotope signatures. The experimental site is located in Chania, Crete. A matrix of plots were irrigated, combining different water qualities (secondary, primary treated wastewater, tap water, partially spiked with heavy metals, going through newly developed tertiary treatment systems) with different irrigation strategies (surface and subsurface drip irrigation combined with full irrigation and partial root drying). In order to assess small scale heavy metal distribution around a drip emitter, Pb isotope tracing was used, combined with selective extraction. The sampling for Pb isotope fingerprinting was performed after the 3rd season of ww-irrigation on a lateral profile from a drip irrigator (half distance between drip lines, i.e. 50cm) and three depth intervals (0-10, 10-20, 20-40 cm). These samples were lixiviated through a 3 step selective extraction procedure giving rise to the bio-accessible, mobile and residual fraction: CaCl2/NaNO3 (bio-accessible fraction), DPTA (mobile fraction), total acid attack (residual fraction). Those samples were analysed for trace elements (including heavy metals) and major inorganic compounds by ICP-MS. The extracted fractions were then analysed by Thermal Ionisation Mass Spectrometry (TIMS) for their lead isotope fingerprints (204Pb, 206Pb, 207Pb, 208Pb

  9. Metasedimentary melting in the formation of charnockite: Petrological and zircon U-Pb-Hf-O isotope evidence from the Darongshan S-type granitic complex in southern China

    NASA Astrophysics Data System (ADS)

    Jiao, Shu-Juan; Li, Xian-Hua; Huang, Hui-Qing; Deng, Xi-Guang

    2015-12-01

    Charnockites are Opx-bearing igneous rocks commonly found in high-grade metamorphic terranes. Despite being volumetrically minor, they show a wide range in both bulk geochemistry and intensive parameters. They form a characteristic component of the AMCG (anorthosite-mangerite-charnockite-granite) suite, but their association with typical S-type granites is less well-known. The Darongshan S-type granitic complex (DSGC) in Guangxi Province, southern China, contains granites varying in mafic silicate mineral assemblages from Bt + Crd (Darongshan suite) to Opx + Grt + Bt + Crd (Jiuzhou suite) and Opx + Crd ± Bt (Taima suite), corresponding to a geochemical transition from magnesian calc-alkalic to ferroan calc-alkalic. However, its genesis, even the accurate age of intrusion, remains highly contentious despite intensive research. In order to understand the genesis of charnockite and its genetic relationship with S-type granite; here, we first determined zircon U-Pb ages of each suite using a SIMS on the basis of a detailed petrological study. Zircon U-Pb ages show that all suites of the complex were emplaced contemporaneously at ca. 249 Ma. Monazite apparent U-Pb ages are indistinguishable from zircon U-Pb ages within analytical error. Further in situ zircon Hf-O isotope analyses reveal that the granitic complex was dominantly derived from reduced melting metasedimentary rocks (δ18Ozircon = ca. 11‰; εHf(t)zircon = ca. - 10; Δlog FMQ ≤ 0; Mn in apatite oxybarometer) with rare material input from the mantle. The variation in δ18O (7.8‰-12.9‰) is more likely a result of hybridization, whereas that in εHf(t) (- 31.9 to - 1.8) is a result of both hybridization and disequilibrium melting. The variation in mineralogy and geochemistry may be interpreted as a result of entrainment of peritectic garnets from biotite-dehydration melting. Nevertheless, heat input from mantle through basaltic intrusion/underplating is considered to play a major role in high

  10. Ion Microprobe U-Pb Dating and Sr Isotope Measurement of Conodont

    NASA Astrophysics Data System (ADS)

    Sano, Y.; Ishida, A.; Kagoshima, T.; Takahata, N.

    2014-12-01

    We have developed a method of in situ ion microprobe U-Pb dating and Sr isotope measurement of biogenic apatite using NanoSIMS. This was applied to a protoconodont, an early Cambrian phosphate microfossil [1]. On a single fragment of a fossil derived from a sedimentary layer in the Meishucunian Yuhucun Formation, southern China [2], 23 spots provide a 238U/206Pb isochron age of 547 ± 43 Ma (2sigma), which is consistent with the depositional age, 536.5 ± 2.5 Ma estimated using zircon U-Pb dating of interbedded tuffs [3]. However, five spots on a small region in the same protoconodont yield an isochron age of 417 ± 74 Ma (2sigma), apparently younger than the formation age. The younger age might be attributable to a later hydrothermal event, perhaps associated with Caledonian orogenic activity recorded in younger zircon with an age of 420-440 Ma [4]. We measured Sr isotopic ratios of the protoconodont by NanoSIMS. In the older domain, 19 spots give the ratio of 0.71032 ± 0.00023 (2sigma), although seven spots on the younger region provide the ratio of 0.70862 ± 0.00045; which is significantly less radiogenic than the older domain. We also measured U-Pb age and Sr isotopes of a Carboniferous conodont derived from the Kinderhookian stage from the Illinois Basin region in North America. 20 spots yield a 238U/206Pb isochron age of 291 ± 56 Ma (2sigma), which is markedly younger than the depositional age of the fossil of 350-363 Ma. On the other hand, 9 spots give a Sr isotopic ratio of 0.70784 ± 0.00030, less radiogenic than the older domain of protoconodont. These data together with other isotopes such as Cl may provide a constraint on the model for chemical evolution of seawater. [1] Sano et al. (2014) J. Asian Earth Sci. 92, 10-17. [2] Condon et al. (2005) Science 308, 95-98. [3] Sawaki et al. (2008) Gondwana Res. 14, 148-158. [4] Guo et al. (2009) Geochem. J. 43, 101-122.

  11. β-decay properties of neutron-deficient Pt, Hg, and Pb isotopes

    SciTech Connect

    Sarriguren, P.; Boillos, J. M.; Moreno, O.; Moya de Guerra, E.

    2015-10-15

    Neutron-deficient isotopes in the lead region are well established examples of the shape coexistence phenomenon in nuclei. In this work, bulk and decay properties, including deformation energy curves, charge mean square radii, Gamow-Teller (GT) strength distributions, and β-decay half-lives, are studied in neutron-deficient Pt, Hg, and Pb isotopes. The nuclear structure involved is described microscopically from deformed quasiparticle random-phase approximation calculations with residual interactions in both particle-hole and particle-particle channels, performed on top of a self-consistent deformed quasiparticle Skyrme Hartree-Fock basis. The sensitivity to deformation of the GT strength distributions in those isotopes is proposed as an additional complementary signature of the nuclear shape. The β-decay half-lives resulting from the GT strength distributions are compared to experiment to demonstrate the ability of the method.

  12. Stable isotope geochemistry of pore waters from the New Jersey shelf - No evidence for Pleistocene melt water

    NASA Astrophysics Data System (ADS)

    van Geldern, Robert; Hayashi, Takeshi; Böttcher, Michael E.; Mottl, Michael J.; Barth, Johannes A. C.; Stadler, Susanne

    2013-04-01

    Ocean Drilling Program, Volume 313, Tokyo, available at: http://publications.iodp.org/proceedings/313/313toc.htm. van Geldern, R., Hayashi, T., Böttcher, M. E., Mottl, M. J., Barth, J. A. C., and Stadler, S., 2013, Stable isotope geochemistry of pore waters and marine sediments from the New Jersey shelf: Methane formation and fluid origin: Geosphere, v. 9, no. 1, p. in press.

  13. Determining provenance of marine metal pollution in French bivalves using Cd, Zn and Pb isotopes

    NASA Astrophysics Data System (ADS)

    Shiel, Alyssa E.; Weis, Dominique; Cossa, Daniel; Orians, Kristin J.

    2013-11-01

    Cadmium, Zn and Pb isotopic compositions (MC-ICP-MS) and elemental concentrations (HR-ICP-MS) have been used to distinguish between natural and anthropogenic sources of these metals in bivalves collected from the coastlines of France (English Channel, Atlantic and Mediterranean coasts). The Cd isotopic signatures (δ114Cd = -1.08‰ to -0.52‰) exhibited by bivalves from the coastlines of France, excluding those from NE France, are within the range of those exhibited by bivalves from the USA East coast (δ114Cd = -1.20‰ to -0.54‰). This indicates the high prevalence of industry, as well as the low natural contributions of Cd from North Atlantic waters in both regions. Thus, the significance of anthropogenic Cd sources is similar. These significant anthropogenic contributions are identified for bivalves with a large range in tissue Cd concentrations. Importantly, French bivalves from the Gironde estuary and Marennes-Oléron basin (regions of historic and modern importance for oyster farming, respectively) exhibited the highest Cd levels of the study. Their Cd isotopic signatures indicate historical smelting emissions remain the primary Cd source despite the cessation of local smelting activities in 1986 and subsequent remedial efforts. No significant variability is observed in the δ66Zn values of the French bivalves (∼0.53‰), with the exception of the much heavier compositions exhibited by oysters from the polluted Gironde estuary (1.19-1.27‰). Lead isotopes do not fractionate during processing like Cd and Zn. They can, therefore, be used to identify emissions from industrial processes and the consumption of unleaded gasoline and diesel fuel as metal sources to French bivalves. Cadmium and Zn isotopes are successfully used here as tracers of anthropogenic processing emissions and are combined with Pb isotope "fingerprinting" techniques to identify metal sources.

  14. Nd and Pb isotope evolution of the Indian Ocean during Termination 1

    NASA Astrophysics Data System (ADS)

    Wilson, D. J.; Piotrowski, A. M.; Galy, A.

    2009-12-01

    Neodymium isotopes in the modern oceans appear to behave as a quasi-conservative tracer for water mass sourcing and mixing. Therefore, temporal changes in water mass geometry can potentially be reconstructed from time series of ɛNd recovered from the authigenic component of marine sediments [1]. We use this approach to investigate glacial to interglacial changes in water mass sources to the deep Indian Ocean, focusing on Termination 1. One important consideration is the reliable recovery of a seawater signal, which we address using coretop and downcore tests on both sediment leachates and foraminifera. In addition, recent studies have suggested that boundary exchange [2] and/or reversible scavenging [3] may be important in controlling the ɛNd distribution in the modern oceans, which could complicate reconstructions of past water mass mixing. We test this using coupled neodymium and lead isotope measurements. Since Pb has a shorter deepwater residence time (50-400 years) than Nd (500-1000 years), its isotopic composition should be more sensitive to local boundary exchange and water mass mixing over shorter path lengths, whereas Nd isotopes respond to longer path length circulation and more distal inputs. Western Indian Ocean sediment core WIND 28K (10°S, 52°E, 4157m depth, [4]) is situated within the deep western boundary current and is therefore well placed to provide a record of deep water inflow. A decrease of around 3 ɛNd units through the deglaciation as well as millennial variability could be interpreted in terms of changing export of North Atlantic Deep Water into the Southern Ocean and hence Indian Ocean, in support of the recent Central Equatorial Indian Ocean ɛNd record [5]. Deglacial changes in the Pb isotope record can be described by two component mixing which might indicate water mass mixing or a change in the continental sources of Pb. We also consider the incongruent weathering mechanism which has been proposed to explain a similar pattern of

  15. Whole-rock Pb and Sm-Nd isotopic constraints on the growth of southeastern Laurentia during Grenvillian orogenesis

    USGS Publications Warehouse

    Fisher, C.M.; Loewy, S.L.; Miller, C.F.; Berquist, P.; Van Schmus, W. R.; Hatcher, R.D., Jr.; Wooden, J.L.; Fullagar, P.D.

    2010-01-01

    The conventional view that the basement of the southern and central Appalachians represents juvenile Mesoproterozoic crust, the final stage of growth of Laurentia prior to Grenville collision, has recently been challenged. New whole-rock Pb and Sm-Nd isotopic data are presented from Meso protero zoic basement in the southern and central Appalachians and the Granite-Rhyolite province, as well as one new U-Pb zircon age from the Granite-Rhyolite province. These data, combined with existing data from Mesoproterozoic terranes throughout southeastern Laurentia, further substantiate recent suggestions that the southern and central Appalachian basement is exotic with respect to Laurentia. Sm-Nd isotopic compositions of most rocks from the southern and central Appalachian basement are consistent with progressive growth through reworking of the adjacent Granite-Rhyolite province. However, Pb isotopic data, including new analyses from important regions not sampled in previous studies, do not correspond with Pb isotopic compositions of any adjacent crust. The most distinct ages and isotopic compositions in the southern and central Appalachian basement come from the Roan Mountain area, eastern Tennessee-western North Carolina. The data set indicates U-Pb zircon ages up to 1.8 Ga for igneous rocks, inherited and detrital zircon ages >2.0 Ga, Sm-Nd depleted mantle model (TDM) ages >2.0 Ga, and the most elevated 207Pb/204Pb observed in southeastern Laurentia. The combined U-Pb geochronologic and Sm-Nd and Pb isotopic data preclude derivation of southern and central Appalachian basement from any nearby crustal material and demonstrate that Grenville age crust in southeastern Laurentia is exotic and probably was transferred during collision and assembly of Rodinia. These new data better define the boundary between the exotic southern and central Appalachian basement and adjacent Laurentian Granite-Rhyolite province. ?? 2010 Geological Society of America.

  16. Microbial sulfur metabolism evidenced from pore fluid isotope geochemistry at Site U1385

    NASA Astrophysics Data System (ADS)

    Turchyn, Alexandra V.; Antler, Gilad; Byrne, David; Miller, Madeline; Hodell, David A.

    2016-06-01

    At Site U1385, drilled during IODP Expedition 339 off the coast of Portugal on the continental slope, high-resolution sulfate concentration measurements in the pore fluids display non-steady-state behavior. At this site there is a zone of sulfate reduction in the uppermost seven meters of sediment, followed by a 38-meter interval where sulfate concentrations do not change, and finally sulfate concentrations are depleted to zero between 45 and 55 meters below seafloor. Below the sulfate minimum zone, there is abundant methane, suggesting that the lower sulfate consumption zone is coupled to anaerobic methane oxidation. We analyze pore water samples from IODP Site U1385 for sulfur and oxygen isotope ratios of dissolved sulfate, as well as the sulfur isotope composition of sedimentary pyrite. The sulfur isotopes in pore fluid sulfate display similar non-steady-state behavior similar to that of the sulfate concentrations, increasing over the uppermost zone of sulfate reduction and again over the lower zone of sulfate-driven anaerobic methane oxidation. The oxygen isotopes in sulfate increase to the 'apparent equilibrium' value in the uppermost zone of sulfate reduction and do not change further. Our calculations support the idea that sulfite to sulfide reduction is the limiting step in microbial sulfate reduction, and that the isotope fractionation expressed in the residual pore water sulfate pool is inversely proportional to the net sulfate reduction rate. The sulfur isotope composition of pyrite acquires one value in the uppermost sediments, which may be overprinted by a second value in the deeper sediments, possibly due to iron release during anaerobic methane oxidation or iron diffusion from a higher zone of bacterial iron reduction. Our results have implications for modeling the sulfur isotope composition of the pyrite burial flux in the global biogeochemical sulfur cycle.

  17. Provenance of sedimentary kaolin deposits in Egypt: Evidences from the Pb, Sr and Nd isotopes

    NASA Astrophysics Data System (ADS)

    Baioumy, Hassan

    2014-12-01

    This work reports, for the first time, the Pb, Sr and Nd isotopes of the clay fractions (<2 μm) from sedimentary kaolin deposits in Egypt of different ages (Carboniferous and lower Cretaceous), localities (Sinai, Red Sea and Aswan), lithologies (flint and plastic) and clay minerals composition (pure kaolinite and mixture of kaolinite, illite and chlorite) to determine their source area compositions and examine the effect of provenance on their isotopic compositions. Measured (present day) and age-corrected Pb isotopes data (100 and 300 My for the Cretaceous and Carboniferous deposits, respectively) are more or less homogeneous in all deposits regardless of their ages, localities, and compositions. This, therefore, suggests that the Pb isotopes cannot be used as a tracer for source area compositions of these kaolin deposits. On the other hand, the studied kaolin deposits show variations in their measured and age-corrected Sr and Nd isotopes regarding to their ages and compositions. The Carboniferous illite-rich kaolin deposits in the Khaboba and Hasbar areas, Sinai have higher measured and age-corrected 87Sr/86Sr ratios (average of 0.715742 and 0.711156 for measured and age-corrected, respectively) compared to the non-illitic Carboniferous deposit at Abu Natash area (average of 0.70772 and 0.70769 for measured and age-corrected, respectively) and the lower Cretaceous deposits in all areas (average of 0.70827 and 0.70821 for measured and age-corrected, respectively). The Carboniferous kaolin deposits in the Khaboba and Hasbar areas also have lower 143Nd/144Nd ratios (average of 0.51206 and 0.51180 for measured and age-corrected, respectively) compared to the Carboniferous Abu Natash deposit (average of 0.51253 and 0.51231 for measured and age-corrected, respectively) as well as the lower Cretaceous deposits in all areas (average of 0.51248 and 0.51239 for measured and age-corrected, respectively). Initial εNd values are negative in the Carboniferous kaolin deposits

  18. Evolution of the Mazatzal province and the timing of the Mazatzal orogeny: Insights from U-Pb geochronology and geochemistry of igneous and metasedimentary rocks in southern New Mexico

    USGS Publications Warehouse

    Amato, J.M.; Boullion, A.O.; Serna, A.M.; Sanders, A.E.; Farmer, G.L.; Gehrels, G.E.; Wooden, J.L.

    2008-01-01

    New U-Pb zircon ages, geochemistry, and Nd isotopic data are presented from three localities in the Paleoproterozoic Mazatzal province of southern New Mexico, United States. These data help in understanding the source regions and tectonic setting of magmatism from 1680 to 1620 Ma, the timing of the Mazatzal orogeny, the nature of postorogenic maginatism, Proterozoic plate tectonics, and provide a link between Mazatzal subblocks in Arizona and northern New Mexico. The data indicate a period from 1680 to 1650 Ma in which juvenile felsic granitoids were formed, and a later event between 1646 and 1633 Ma, when these rocks were deformed together with sedimentary rocks. No evidence of pre-1680 Ma rocks or inherited zircons was observed. The igneous rocks have ENd(t) from -1.2 to +4.3 with most between +2 and +4, suggesting a mantle source or derivation from similar-aged crust. Nd isotope and trace element concentrations are consistent with models for typical are magmatism. Detrital zircon ages from metasedimentary rocks indicate that sedimentation occurred until at least 1646 Ma. Both local and Yavapai province sources contributed to the detritus. All of the samples older than ca. 1650 Ma are deformed, whereas undeformed porphyroblasts were found in the contact aureole of a previously dated 1633 Ma gabbro. Regionally, the Mlazatzal orogeny occurred mainly between 1654 and 1643 Ma, during final accretion of a series of island arcs and intervening basins that may have amalgamated offshore. Rhyolite magmatism in the southern Mazatzal province was coeval with gabbro intrusions at 1633 Ma and this bimodal magmatism may have been related to extensional processes following arc accretion. ?? 2007 Geological Society of America.

  19. Isotope geochemistry and the study of habitability and life on other planets (Invited)

    NASA Astrophysics Data System (ADS)

    Eiler, J.

    2010-12-01

    The question of life on other planets might be solved by a remarkable discovery — a martian coquina, or perhaps a tentacle print on a distant landscape. But, until this happens, evidence for life and, more generally, habitability will use indirect geochemical arguments such as isotope thermometers and biomarkers (molecular, isotopic, and elemental fingerprints of biology)., Understanding this evidence will also demand a quantitative planetary history based on isotopic dating. Laboratory study of samples derived from Mars or other solar-system bodies will be a focus of geochemical investigations aimed at such assessments. Examples of how this will be done can be found in studies of the Precambrian geologic record and Martian meteorites. Debates regarding environmental conditions and biogenicity of minerals and organic matter are common in the study of such materials. These controversies derive from simple but refractory problems with the geochemical principles we employ: Indicators of metabolism can be mimicked by abiologic reactions; paleo-environmental proxies generally require an understanding of related geochemical cycles (e.g., the isotopic budget of water); and, though many organic molecules are unambiguous biomarkers, diagenesis can transform them into compounds that resemble products of abiogenic organic synthesis. If planetary sample return is to produce definitive geochemical constraints on habitability and biology, we will require either luck or a new class of geochemical tools that explicitly address these problems. The spatial distribution of rare isotopes within molecular structures, including ‘clumping’ and position-specific isotope effects, offer new geochemical tools that could provide such solutions. For example, even a simple molecule like acetic acid (C2H4O2) has more than 200 distinct isotopic configurations when spatial distribution of isotopes is considered, and the proportions of these could reflect formation temperature, the nature of

  20. The boron isotope geochemistry of the Kirka borate deposit, western Turkey

    NASA Astrophysics Data System (ADS)

    Palmer, M. R.; Helvaci, C.

    1995-09-01

    We have measured the boron isotope composition of seventeen samples of borate minerals (colemanite, ulexite, and borax) and the 87Sr/ 86Sr ratio in thirteen borate samples from the Kirka borate deposit in western Anatolia, Turkey. These Neogene deposits were formed by evaporation of playa lakes fed by geothermal springs. The δ 11B values range from -14.9% o in colemanite to -1.6% o in borax. To a first approximation the relative differences in the δ 11B values of the borate minerals are consistent with their basic boron atomic configuration, but the magnitude of the boron isotope fractionation between the three minerals precludes their simultaneous precipitation from a brine with the same boron isotope composition and pH. Rather the data are consistent with precipitation of colemanite from a brine with lower pH than that required for ulexite precipitation, which in turn requires a lower pH than is needed for borax precipitation. The boron isotope data also suggest that the borate minerals did not maintain boron isotopic equilibrium with the brine after they precipitated. Rayleigh fractionation models indicate that during borax precipitation the δ 11B value of the brine was slightly heavier than during precipitation of ulexite and colemanite.

  1. Origin of the Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska: Evidence from regional Pb and Sr isotope sources

    USGS Publications Warehouse

    Ayuso, R.A.; Kelley, K.D.; Leach, D.L.; Young, L.E.; Slack, J.F.; Wandless, G.; Lyon, A.M.; Dillingham, J.L.

    2004-01-01

    Pb and Sr isotope data were obtained on the shale-hosted Zn-Pb-Ag Red Dog deposits (Qanaiyaq, Main, Aqqaluk, and Paalaaq), other shale-hosted deposits near Red Dog, and Zn-Pb-Ag sulfide and barite deposits in the western and central Brooks Range. The Red Dog deposits and other shale-hosted Zn-Pb-Ag deposits near Red Dog are hosted in the Mississippian Kuna Formation, which is underlain by a sequence of marine-deltaic clastic rocks of the Upper Devonian to Lower Mississippian Endicott Group. Ag-Pb-Zn vein-breccias are found in the Endicott Group. Galena formed during the main mineralization stages in the Red Dog deposits and from the Anarraaq and Wulik deposits have overlapping Pb isotope compositions in the range 206Pb/204Pb = 18.364 to 18.428, 207Pb/204Pb = 15.553 to 15.621, and 208Pb/204Pb = 38.083 to 38.323. Galena and sphalerite formed during the main ore-forming stages in the Red Dog deposits define a narrow field on standard uranogenic and thorogenic Pb isotope diagrams. Lead in sulfides of the Red Dog district is less radiogenic (238U/204Pb: ?? = 9.51-9.77) than is indicated by the average crustal lead evolution model (?? = 9.74), a difference consistent with a long history of evolution at low ratios of ?? before the Carboniferous. The homogeneous regional isotopic reservoir of Pb may indicate large-scale transport and leaching of minerals with various ?? ratios and Th/Pb ratios. Younger and genetically unrelated fluids did not significantly disturb the isotopic compositions of galena and sphalerite after the main mineralization event in the Red Dog district. Some pyrite shows evidence of minor Pb remobilization. The overall lead isotope homogeneity in the shale-hosted massive sulfide deposits is consistent with three types of control: a homogeneous regional source, mixing of lead during leaching of a thick sedimentary section and fluid transport, or mixing at the site of deposition. Isotopic variability of the hydrothermal fluids, as represented by galena

  2. Lead isotope study of Zn-Pb ore deposits associated with the Basque-Cantabrian basin and Paleozoic basement, Northern Spain

    NASA Astrophysics Data System (ADS)

    Velasco, F.; Pesquera, A.; Herrero, J. M.

    1996-01-01

    A total of forty-three galena samples from syngenetic and epigenetic Pb-Zn mineralizations emplaced in the Lower Cretaceous Basque-Cantabrian basin and Paleozoic basement of the Cinco Villas massif in the western Pyrenees, have been analyzed for Pb-isotopic composition. Galena from sedex mineralizations hosted in Carboniferous clastic rocks in the Cinco Villas massif display an homogeneous lead isotopic signature (206Pb/2044Pb ≈ 18.43, 207Pb/204Pb ≈ 15.66, 208Pb/ 204Pb ≈ 38.69) suggesting a single lead reservoir. These values are slightly more radiogenic than lead from other European Hercynian deposits, possibly reflecting the influence of a more evolved upper crustal source. Underlying Paleozoic sediments are proposed as lead source for the Cinco Villas massif ores. Analyses from twenty-six galena samples from the four strata-bound ore districts hosted in Mesozoic rocks reveal the existence of two populations regarding their lead isotopic composition. Galena from the western Santander districts (e.g., Reocin) is characterized by more radiogenic isotope values (206Pb/204Pb ≈ 18.74, 207Pb/204Pb ≈ 15.67, 208Pb/ 204Pb ≈ 38.73) than those from the central and eastern districts (Troya-Legorreta, Central and Western Vizcaya, 206Pb/204Pb ≈ 18.59, 207Pb/204Pb ≈ 15.66, 208Pb/ 204Pb ≈ 38.73). In all districts, the most likely source for these mineralizations was the thick sequence of Lower Cretaceous clastic sediments. The existence of two separate lead isotopic populations could be the result of regional difference in the composition of the basement rocks and the clastic sediments derived of it or different evolution histories. In both sub-basins, isotopic ratios indicate an increase in crustal influence as the age of the ores decreases.

  3. Sulfur isotope geochemistry of ore and gangue minerals from the Silesian-Cracow Mississippi Valley-type ore district, Poland

    USGS Publications Warehouse

    Leach, D.L.; Vets, J.G.; Gent, C.A.

    1996-01-01

    Studies of the sulfur isotopic composition of ore and gangue minerals from the Silesian-Cracow Zn-Pb district were conducted to gain insights into processes that controlled the location and distribution of the ore deposits. Results of this study show that minerals from the Silesian-Cracow ore district have the largest range of sulfur isotope compositions in sulfides observed from any Mississippi Valley-type ore district in the world. The ??34S values for sulfide minerals range from +38 to -32 per mil for the entire paragenetic sequence but individual stages exhibit smaller ranges. There is a well developed correlation between the sulfur isotope composition and paragenetic stage of ore deposition. The first important ore stage contains mostly positive ??34S values, around 5 per mil. The second stage of ore formation are lower, with a median value of around -5 to -15 per mil, and with some values as low as -32 per mil. Late stage barite contains isotopically heavy sulfur around +32 per mil. The range in sulfur isotope compositions can be explained by contributions of sulfur from a variety of source rocks together with sulfur isotope fractionations produced by the reaction paths for sulfate reduction. Much of the variation in sulfur isotope compositions can be explained by bacterial reduction of sedimentary sulfate and disequilibrium reactions by intermediate-valency sulfur species, especially in the late-stage pyrite and sphalerite. Organic reduction of sulfate and thermal release of sulfur from coals in the Upper Silesian Coal Basin may have been important contributors to sulfur in the ore minerals. The sulfur isotopic data, ore mineral textures, and fluid inclusion data, are consistent with the hypothesis that fluid mixing was the dominant ore forming mechanism. The rather distinct lowering of ?? 34S values in sulfides from stage 2 to stage 3 is believed to reflect some fundamental change in the source of reduced sulfur and/or hydrology of the ore

  4. Ca isotope stratigraphy across the Cenomanian-Turonian OAE 2: Links between volcanism, seawater geochemistry, and the carbonate fractionation factor

    NASA Astrophysics Data System (ADS)

    Du Vivier, Alice D. C.; Jacobson, Andrew D.; Lehn, Gregory O.; Selby, David; Hurtgen, Matthew T.; Sageman, Bradley B.

    2015-04-01

    2CO3- during CO2 uptake. Recent studies utilizing a variety of isotope proxies, e.g., Nd, Os, and Pb, implicate eruption of the Caribbean Large Igneous Province as a likely source of increased CO2. Moreover, integration of C, Ca, and Os isotope data reveals new information about the timing of events during the onset of OAE 2.

  5. Geochemistry Meets Anthropology: the use of Sr Isotopes as Tracers for Ancient Human Migration.

    NASA Astrophysics Data System (ADS)

    Solis, G.; Schaaf, P.; Hernandez, T.; Horn, P.; Manzanilla, L.

    2005-12-01

    Sr isotopes have increasingly become an important tool in archeology and anthropology in determining provenance of humans. By comparing isotopic signatures of human teeth and bone with the soil environment, Sr isotope ratios have been used as tracers identifying living areas. Sr isotope ratios in tooth enamel reflect the source of diet during youth, whereas ratios in dentine and bones come from the food growing in local geologies around the time of death. However, since analytical procedures vary from lab to lab we present here our new technique and how it affects results. We studied 11 teeth and 12 bone samples from the archeological site of Teotihuacan, central Mexico, as well as soil and water from the locality. Mechanical sample preparation of all teeth involved isolation of the enamel layer with the aid of an orthodontical micro-tool. For some enamel samples up to three fractions (two leachates and residue) were obtained for measurement. Thoroughly cleaned bone material underwent no leaching. As an example, 87Sr/86Sr results from a sample with ratios of 0.70477 for bone (which is identical to highland soil), 0.70530 for first leachate, 0.70590 for second leachate, and 0.70668 (mean accuracy +/- 0.00004) for enamel, clearly show enamel contamination by mobile Sr probably from soil. We thus find that repeated cleaning and particularly repeated leaching procedures, including isotopic measurement of the leachates, are critical to differentiate primary from secondary Sr isotope ratios as product of interaction of soil, sediments and water from the substrate where burials took place.

  6. Pb-isotopic systematics of lunar highland rocks (>3.9 Ga): Constraints on early lunar evolution

    USGS Publications Warehouse

    Premo, W.R.; Tatsumoto, M.; Misawa, K.; Nakamuka, N.; Kita, N.I.

    1999-01-01

    The present lead (Pb)-isotopic database of over 200 analyses from nearly 90 samples of non-mare basalt, lunar highland rocks (>3.9 Ga) delineate at least three isotopically distinct signatures that in some combination can be interpreted to characterize the systematics of the entire database. Two are fairly new sets of lunar data and are typical of Pb data from other solar-system objects, describing nearly linear arrays slightly above the 'geochron' values, with 207Pb/206Pb values 500). Although the age and origin of this exotic Pb is not well constrained, it is interpreted to be related to the entrapment of incompatible-element-rich (U, Th) melts within the lunar upper mantle and crust between 4.36 and 4.46 Ga (urKREEP residuum?). The latest discovered Pb signature is found only in lunar meteorites and is characterized by relatively low source ?? values between 10 and 50 at 3.9 Ga. The fact that most lunar crustal rocks (>3.9 Ga) exhibit high 207Pb/206Pb values requires that they were derived from, mixed with, or contaminated by Pb produced from early-formed, high-?? sources. The ubiquity of these U-Pb characteristics in the sample collection is probably an artifact of Apollo and Luna sampling sites, all located on the near side of the Moon, which was deeply excavated during the basin-forming event(s). However, the newest Pb-isotopic data support the idea that the Moon originally had a ?? value of ~8 to 35, slightly elevated from Earth values, and that progressive U-Pb fractionations occurred within the Moon during later stages of differentiation between 4.36 and 4.46 Ga.

  7. A Pb isotope investigation of the Lovozero Agpaitic Nepheline Syenite, Kola Peninsula, Russia

    NASA Astrophysics Data System (ADS)

    Zartman, R. E.; Kogarko, L. N.

    2014-01-01

    For the first time Pb isotope composition was established in Lovozero rocks and raremetal ores, which is important for identifying their sources. The world's largest layered intrusion of agpaitic nepheline syenite-the Lovozero alkaline massif—is located near the center of the Kola Peninsula in Russia. This superlarge complex plutonic body hosts the economically important loparite and eudiallyte deposits [1]. These deposits contain immense resources of REE, Nb, Ta, Zr, and constitute a world class mineral district. The Lovozero massif belongs to the Kola ultramafic alkaline and carbonatitic province (KACP) of Devonian age. Previous bulk rock studies have shown that the initial Sr and Nd isotope ratios of Lovozero rocks plot in the depleted mantle quadrant of Sr-Nd diagrams [2]. More recently, Hf isotope data obtained by Kogarko et al. (3) confirm that the Lovozero and Khibina massifs with ɛHf between 6 and 8 are derived predominantly from a depleted mantle source. It was shown that Sr, Nd, and Hf abundances are significantly elevated in the Kola alkaline rocks, and thus their isotopic compositions are relatively insensitive to minor contamination by the overlying crustal rocks. By contrast, Pb in the KACP rocks is a much more sensitive indicator of a crustal component. In this paper we investigate the lead isotopic signature of all resentative types of Lovozero rocks (Table 1) in order to further characterize their mantle sources. The Lovozero massif consists of four intrusive phases. Rocks of phase I (mostly nepheline syenites) comprise about 5% of the total volume, phase II (urtites, foyaite, lujavrites) forms the main portion of the massif comprising 77% in volume, and phase III (eudialyte lujavrites) contributes about 18%. Country rocks are represented by Devonian effusive rocks and Archean gneisses.

  8. Pb isotopes in sediments of Lake Constance, Central Europe constrain the heavy metal pathways and the pollution history of the catchment, the lake and the regional atmosphere

    SciTech Connect

    Kober, B.; Wessels, M.; Bollhoefer, A.; Mangini

    1999-05-01

    Pb isotope ratios and Pb concentrations of well-dated sediments of Lake Constance, Central Europe have been analyzed using thermal ion mass spectrometry. Sequential extraction studies indicated isotope homogeneity of the leachable Pb components within the investigated layers. Since the middle of the 19th century a significant anthropogenic Pb component appeared in the lake sediments, and rapidly approaches concentration levels similar to that of the geogenic Pb background (20 ppm) at the beginning of the 20th century. Anthropogenic Pb was predominantly transferred to the lake sediments via the atmosphere. Pb sources were coal combustion, industrial ore processing and leaded gasoline. The flux of a fluvial Pb component to the lake sediments, additive to atmospheric Pb deposition, peaked in about 1960. This flux is attributed to (re)mobilization of Pb from polluted parts of the lake catchment, and indicates the change of catchment soils from a pollution sink to a heavy metal source. The strong reduction of anthropogenic Pb in the uppermost lake sediments since the 1960s has been caused by advances of environmental protection. The lake sediments record the changing fluxes and the isotope composition of the deposited aeolian Pb pollution. During the 20th century aeolian Pb fluxes to the lake sediments were in the range of 1--4 {micro}g/cm{sup 2}/a. During peak emission periods of gasoline Pb to the atmosphere (1960--1990) the aerosol Pb isotope composition was rather constant ({sup 206}Pb/{sup 207}Pb: 1.12--1.13) and probably a mixture of Canadian and Australian with Russian and Central European Pb types. Aeolian Pb isotope and Pb flux trends in the lake sediments as a whole agree well with the trends found in Alpine glaciers (Doering et al., 1997a,b) and in ombrotrophic peat bogs of Switzerland (Shotyk et al., 1996). However, different industrial Pb components were deposited in the archives of aeolian pollution during the early 20th century.

  9. Siderophile and chalcophile element abundances in oceanic basalts, Pb isotope evolution and growth of the earth's core

    NASA Technical Reports Server (NTRS)

    Newsom, H. E.; White, W. M.; Jochum, K. P.; Hofmann, A. W.

    1986-01-01

    The hypothesis that the mantle Pb isotope ratios reflect continued extraction of Pb into the earth's core over geologic time is evaluated by studying the depeletion of chalcophile and siderophile elements in the mantle. Oceanic basalt samples are analyzed in order to determine the Pb, Sr, and Nd isotropic compositions and the abundances of siderophile and chalcophile elements and incompatible lithophile elements. The data reveal that there is no systematic variation of siderophile or chalcophile element abundances relative to abundances of lithophile elements and the Pb/Ce ratio of the mantle is constant. It is suggested that the crust formation involves nonmagmatic and magmatic processes.

  10. A review of applications of U-Th-Pb isotope systematics to investigations of uranium source rocks.

    USGS Publications Warehouse

    Stuckless, J.S.

    1987-01-01

    U, Th and Pb concentrations and the isotopic composition of Pb can be used to evaluate crystalline rocks as a source for U in sedimentary deposits. Under favourable geologic circumstances, the technique can yield information on both the timing and the amount of U released to the sedimentary environment. The technique is best suited to the study of Archean rocks that have high U/Pb, a known common Pb composition, and a simple two-stage history. Less ideal rock units can also be evaluated, but conclusions reached for rocks of Phanerozoic age or younger will generally be qualitative at best.-Author

  11. Pb and O isotopic constraints on the source of granitic rocks from Cape Breton Island, Nova Scotia, Canada

    USGS Publications Warehouse

    Ayuso, R.A.; Barr, S.M.; Longstaffe, F.J.

    1996-01-01

    Pb isotopic compositions of leached feldspars from twenty-three plutons in Cape Breton Island can be divided into two groups: anorthosite, syenite, and granite in the Blair River Complex, which have the least radiogenic compositions on the Island, and granitic rocks from terranes (Aspy, Bras d'Or, and Mira) to the south. Pb isotopic data for the Blair River Complex (206Pb/204Pb = 17.399-18.107; 207Pb/204Pb = 15.505-15.560; 208Pb/204Pb = 36.689-37.733) are consistent with an old source region ultimately derived from the mantle and contaminated by sialic crust. Oxygen isotopic compositions of syenite in the Blair River Complex (??18O = +8.0 to +8.5 permil) are slightly higher than anorthosite (+7.0 to +8.3 permil); a Silurian granite in the Blair River Complex has ??18O = +7.5 permil. Cambrian to Devonian plutons in the Aspy, Bras d'Or, and Mira terranes are more radiogenic (206Pb/204Pb = 18.192-18.981; 207Pb/204Pb = 15.574-15.712; 208Pb/ 204Pb =37.815-38.936) than the Blair River Complex and were generated from source regions having a predominant crustal Pb signature (high ??). The ??18O values of granites and granodiorites in the Aspy terrane (+7.5 to +9.2 permil; avg = +8.6 permil) and Bras d'Or (+3.7 to +11.3 permil; avg = +9.4 permil) are also consistent with involvement of sialic crust. Many Late Proterozoic granites from the Mira terrane have anomalously low ??18O values (+0.2 to +5.9 permil), perhaps produced from protoliths that had undergone hydrothermal alteration prior to melting. Paleozoic granitic rocks from the Aspy, Bras d'Or, and Mira terranes cannot be uniquely distinguished on the basis of their Pb and O isotopic compositions. The granitic rocks could have been generated during terrane amalgamation from combinations of unradiogenic (Grenville-like) and more radiogenic (Avalon-like) sources.

  12. Application of Hydrogen Isotope Geochemistry to Volcanology: Recent Perspective on Eruption Dynamics

    SciTech Connect

    Nakamura, M.; Kasai, Y.; Sato, N.; Yoshimura, S.

    2008-02-25

    Degassing of magma is central to understand the dynamics of volcanic eruption. Hydrogen isotopic composition of volcanic rocks reflects degassing processes. The natural obsidian samples in some eruptions typically show a gently and then rapidly decreasing {delta}D trends with decreasing water content; this led to the two-stage degassing model, with closed-system volatile exsolution (batch fractionation of hydrogen isotope) during the explosive phase followed by open-system degassing (Rayleigh fractionation) to produce the low {delta}D value of the dome and flow lavas. However, the relationship between pattern of degassing (and fractionation) and mode of eruption is controversial. Based on the CO{sub 2}/H{sub 2}O ratio of the obsidians, Rust et al. suggested that the analyzed samples with relatively constant {delta}D value and high water content were buffered (re-equilibrated) with vapor of relatively constant isotopic composition, assuming that silicic magma along conduit wall is fragmented and highly permeable. However, the timing and mechanism of the shift to open system degassing (Rayleigh fractionation) has not been clarified. To further constrain the eruption dynamics, experimental study on the hydrogen isotope fractionation during degassing would be helpful, although common noble metals used as sample capsules, including Au, are permeable to hydrogen at magmatic temperature, and even to water molecule in the prolonged run, probably due to the change of grain boundary properties such as thermal grooving.

  13. Oxygen and carbon isotope geochemistry of the Krivoy rog iron formation, Ukranian SSR

    NASA Astrophysics Data System (ADS)

    Perry, E. C.; Ahmad, S. N.

    1981-04-01

    Oxygen and carbon isotope analyses of samples from three mines in the Krivoy Rog iron formation, Ukranian SSR, are reported here. Maximum and minimum quartz-magnetite fractionation values ( Δ QM) and inferred temperature range in degrees centrigrade for each mine are:

  14. Selenium isotope geochemistry: A new approach to characterizing the environmental chemistry of selenium. Final report

    SciTech Connect

    Volpe, A.M.; Esser, B.K.

    1997-02-05

    High levels of selenium in the environment will be a prominent water quality issue in the western United States for many years. Selenium accumulation is linked to increased rates of death and deformity in migratory birds, blind staggers in livestock, and selenosis in humans. In California, agricultural drain waters and oil refinery effluent contribute to high selenium content in the San Joaquin Valley and the San Francisco Bay. The importance of these industries to California`s economy precludes simple abatement, while the complexity of selenium cycling precludes simple remediation. The purpose of this project is to measure variations in the isotopic composition of selenium in water and soil samples caused by natural processes and to show, for the first time, the value of isotopic measurements in characterizing selenium pollution. The research seeks to identify sources of selenium pollution, determine processes in the selenium cycle, and support selenium remediation studies. The project required the successful integration of three components: (1) appropriate sampling a field setting showing Se enrichment and possibly isotopic fractionation, (2) analytical chemical methods for isolating and purifying the various species of Se in waters and sediment, and (3) mass spectroscopic instrumentation for high precision isotope abundance measurements.

  15. Chronology and isotopic geochemistry of apollo 14 basalts and Skaergard Gabbro, Eastern Greenland

    NASA Technical Reports Server (NTRS)

    Dasch, E. J.

    1986-01-01

    Work completed on Apollo 14 basalts has been published. The two dates obtained from these rocks comprised the oldest and two of the three oldest ages (4.1 and 4.3 billion years) known for lunar maria basalts; thus their ages are important in understanding the moon's earliest history. Owing to the antiquity of these rocks, two more fragments have been dated as part of a second ASEE/NASA SFF program. The new ages are 3.95 and 4.12 billion years, thus further establishing and amplifying the earlier results. This work, although perhaps more interesting for its chronologic information, was begun as a test of chemical and petrographic models. Fragments of Apollo basalt were placed into five categories, based on petrologic and chemical, especially rare-earth element, composition. Isotopic studies were begun in an attempt to determine if the five groups of basalts were related by age or initial isotopic composition (isotopic composition of lava at time of extrusion). Although a few of the representatives of the five groups have the same age and/or initial strontium-isotopic composition, within the analtytical uncertainties, most apparently are unrelated. Petrologic implications of these data will be published in an appropriate journal.

  16. Chlorine isotope geochemistry of Icelandic thermal fluids: Implications for geothermal system behavior at divergent plate boundaries

    NASA Astrophysics Data System (ADS)

    Stefánsson, Andri; Barnes, Jaime D.

    2016-09-01

    The chlorine isotope composition of thermal fluids from Iceland were measured in order to evaluate the source of chlorine and possible chlorine isotope fractionation in geothermal systems at divergent plate boundaries. The geothermal systems studied have a wide range of reservoir temperatures from 40 to 437 °C and in-situ pH of 6.15 to 7.15. Chlorine concentrations range from 5.2 to 171 ppm and δ37 Cl values are -0.3 to + 2.1 ‰ (n = 38). The δ37 Cl values of the thermal fluids are interpreted to reflect the source of the chlorine in the fluids. Geothermal processes such as secondary mineral formation, aqueous and vapor speciation and boiling were found to have minimal effects on the δ37 Cl values. However, further work is needed on incorporation of Cl into secondary minerals and its effect on Cl isotope fractionation. Results of isotope geochemical modeling demonstrate that the range of δ37 Cl values documented in the natural thermal fluids can be explained by leaching of the basaltic rocks by meteoric source water under geothermal conditions. Magmatic gas partitioning may also contribute to the source of Cl in some cases. The range of δ37 Cl values of the fluids result mainly from the large range of δ37 Cl values observed for Icelandic basalts, which range from -0.6 to + 1.2 ‰.

  17. Mineralogy and hydrogen isotope geochemistry of clay minerals in the Ohnuma geothermal area, Northeastern Japan

    NASA Astrophysics Data System (ADS)

    Marumo, Katsumi; Nagasawa, Keinosuke; Kuroda, Yoshimasu

    1980-04-01

    Mineralogical and hydrogen isotopic studies have been made on clay minerals occurring in the Ohnuma geothermal area, northeastern Japan. Here, clay minerals such as smectite, kaolinite, dickite, sericite, and chlorite were formed by hydrothermal alteration of Miocene rocks. A chemical equilibrium can be assumed to be attained from the fact that the amount of expandable layer in the interstratified chlorite/smectite decreases and the polytype of sericite changes from 1M to 2M 1 with increasing depth and temperature. The hydrogen isotopic composition (D/H) of the clay minerals is lighter than that of the geothermal and local meteoric waters by about 20-40‰. The hydrogen isotopic fractionation factors α mineral-water are as follows: 0.972-0.985 for kaolinite and dickite, 0.973-0.977 for sericite, and 0.954-0.987 for chlorite. In the temperature range from 100 to 250°C, the hydrogen isotopic fractionation factors between these minerals and water are not sensitive to the temperature. α chlorite-water depends on the kind of octahedrally coordinated cations which lie close to the hydroxyl groups; it becomes large with an increase of Mg content of chlorite.

  18. Sulfur, carbon, hydrogen, and oxygen isotope geochemistry of the Idaho cobalt belt

    USGS Publications Warehouse

    Johnson, Craig A.; Bookstrom, Arthur A.; Slack, John F.

    2012-01-01

    Cobalt-copper ± gold deposits of the Idaho cobalt belt, including the deposits of the Blackbird district, have been analyzed for their sulfur, carbon, hydrogen, and oxygen isotope compositions to improve the understanding of ore formation. Previous genetic hypotheses have ranged widely, linking the ores to the sedimentary or diagenetic history of the host Mesoproterozoic sedimentary rocks, to Mesoproterozoic or Cretaceous magmatism, or to metamorphic shearing. The δ34S values are nearly uniform throughout the Blackbird dis- trict, with a mean value for cobaltite (CoAsS, the main cobalt mineral) of 8.0 ± 0.4‰ (n = 19). The data suggest that (1) sulfur was derived at least partly from sedimentary sources, (2) redox reactions involving sulfur were probably unimportant for ore deposition, and (3) the sulfur was probably transported to sites of ore for- mation as H2S. Hydrogen and oxygen isotope compositions of the ore-forming fluid, which are calculated from analyses of biotite-rich wall rocks and tourmaline, do not uniquely identify the source of the fluid; plausible sources include formation waters, metamorphic waters, and mixtures of magmatic and isotopically heavy meteoric waters. The calculated compositions are a poor match for the modified seawaters that form vol- canogenic massive sulfide (VMS) deposits. Carbon and oxygen isotope compositions of siderite, a mineral that is widespread, although sparse, at Blackbird, suggest formation from mixtures of sedimentary organic carbon and magmatic-metamorphic carbon. The isotopic compositions of calcite in alkaline dike rocks of uncertain age are consistent with a magmatic origin. Several lines of evidence suggest that siderite postdated the emplacement of cobalt and copper, so its significance for the ore-forming event is uncertain. From the stable isotope perspective, the mineral deposits of the Idaho cobalt belt contrast with typical VMS and sedimentary exhalative deposits. They show characteristics of deposit

  19. Hf-Nd-Pb Isotopes in Lavas and Pyroxenites From Kaula Island Reveal a Depleted Component in the Hawaiian Plume

    NASA Astrophysics Data System (ADS)

    Bizimis, M.; Garcia, M. O.; Norman, M. D.; Salters, V. J.

    2008-05-01

    The presence of depleted material within the otherwise isotopically enriched Hawaiian plume has fundamental implications on the source composition and the scales of heterogeneities and mixing in mantle plumes. A depleted plume component has been recognized in the Pb isotope systematics of Oahu rejuvenated stage lavas (the Honolulu Volcanics, or HV) and in the Hf-Nd isotope compositions of garnet pyroxenite xenoliths from Salt Lake Crater (SLC). Also, peridotite xenoliths from SLC with extreme Hf and Os isotope compositions and up to 2 Ga old Re-depletion ages have been interpreted as fragments of an ancient depleted recycled lithosphere that is part of the plume. Here we present the first combined Hf-Nd-Sr-Pd isotope investigation of phonolite and nephelinite lavas and pyroxenite xenoliths from Kaula Island, Hawaii. The location of Kaula some 300km from Oahu and on a cross-trend relation with the main Hawaiian ridge allows to investigate whether this depleted component has been continuously present in the Hawaiian plume the last ~2-3 Ma, or it is only recognized in Oahu. In terms of major and trace element contents, the Kaula nephelinites and pyroxenites generally overlap the compositions of the HV and SLC pyroxenites on Oahu, respectively. The garnet pyroxenites are interpreted as high pressure cumulates near the base of the lithosphere (70-100km), while the spinel pyroxenites possibly come from shallower depths. In Hf-Nd isotope space both Kaula lavas and pyroxenites (data on cpx separates) plot above the Hawaiian tholeiite trend, with relatively radiogenic Hf isotopes (ɛHf = 13.5-21) for a given Nd (ɛNd=7.3-8.3). These compositions do not intersect the Pacific MORB field. The Pb isotopic compositions of the Kaula lavas and pyroxenites, and new Pb data on the SLC pyroxenites (all data collected by high precision MC-ICPMS using the Tl addition technique) extend to lower 206Pb/204Pb (18.09-17.80) and 208Pb/204Pb (37.42-37.76) than previously reported in Hawaiian

  20. Isotope geochemistry of waters affected by acid mine drainage in old labour sites (SE, Spain).

    NASA Astrophysics Data System (ADS)

    Pérez-Sirvent, Carmen; Martinez-Sanchez, Maria Jose; Garcia-Lorenzo, Maria Luz; Agudo, Ines; Hernandez-Cordoba, Manuel; Recio, Clemente

    2015-04-01

    The ore deposits of this zone have iron, lead and zinc as the main metal components. Iron is present in oxides, hydroxides, sulfides, sulfates, carbonates, and silicates; lead and zinc occur in sulfides (galena and sphalerite, respectively), carbonates, sulfates, and lead or zinc-bearing (manganese, iron) oxides. Mining started with the Romans and activity peaked in the second half of the 19th century and throughout the 20th century until the 1980's. From 1940 to 1957, mineral concentration was made by froth flotation and, prior to this, by gravimetric techniques. The mining wastes, or tailings, with a very fine particle size were deposited inland (tailings dams) and, since 1957, huge releases were made in directly the sea coast. The objective of this work was to evaluate processes affecting waters from abandoned mine sites by way of stable isotopic analysis, particularly H and O stable isotopes from water and S and O from dissolved sulfates. Several common chemical and physical processes, such as evaporation, water-rock interaction and mixing could alter water isotopic composition. Evaporation, which causes an enrichment in δD and δ18O in the residual water, is an important process in semiarid areas. The results obtained indicate that, for sites near the coast, waters are meteoric, and marine infiltration only takes place in the deepest layers near the shore or if water remains stagnated in sediments with low permeability. The main source of sulfate was the oxidation of sulfides, resulting in the liberation of acid, sulfate and metals. In order to assess the mechanism responsible for sulfide oxidation, the stoichiometric isotope balance model and the general isotope balance model were tested, suggesting that the oxidation via Fe3+ was predominant in the surface, and controlled by A. ferrooxidans, while at depth, sulfate reduction occurred.

  1. Strontium isotope geochemistry of groundwater in the central part of the Dakota (Great Plains) aquifer, USA

    USGS Publications Warehouse

    Gosselin, D.C.; Harvey, F.E.; Frost, C.; Stotler, R.; Macfarlane, P.A.

    2004-01-01

    The Dakota aquifer of the central and eastern Great Plains of the United States is an important source of water for municipal supplies, irrigation and industrial use. Although the regional flow system can be characterized generally as east to northeasterly from the Rocky Mountains towards the Missouri River, locally the flow systems are hydrologically complex. This study uses Sr isotopic data from groundwater and leached aquifer samples to document the complex subsystems within the Dakota aquifer in Nebraska and Kansas. The interaction of groundwater with the geologic material through which it flows has created spatial patterns in the isotopic measurements that are related to: long-term water-rock interaction, during which varying degrees of isotopic equilibrium between water and rock has been achieved; and the alteration of NaCl fluids by water-rock interaction. Specifically, Sr isotopic data distinguish brines from Kansas and western Nebraska from those in eastern Nebraska: the former are interpreted to reflect interaction with Permian rocks, whereas the latter record interaction with Pennsylvanian rocks. The Sr isotopic composition of groundwater from other parts of Nebraska and Kansas are a function of the dynamic interaction between groundwater and unlithified sediments (e.g., glacial till and loess), followed by interaction with oxidized and unoxidized sediments within the Dakota Formation. This study illustrates the power of combining Sr chemistry with more conventional geochemical data to obtain a more complete understanding of groundwater flow systems within regional aquifer systems where extensive monitoring networks do not exist. ?? 2003 Elsevier Ltd. All rights reserved.

  2. Applications of UThPb isotope systematics to the problems of radioactive waste disposal

    USGS Publications Warehouse

    Stuckless, J.S.

    1986-01-01

    Concentrations of U, Th and Pb, and the isotopic composition of Pb for whole-rock samples of granitoids show: (1) that open-system behavior is nearly universal in the surface and near-surface environment; and (2) that elemental mobility is possible to depths of several hundred meters. Several identified or at least postulated factors that control U and/or Pb mobility include: (1) the mineralogical sites for U and its daughter products; (2) access of groundwater to these sites; (3) the volume of circulating water; and (4) the chemistry of the groundwater. Studies of granitic samples from peralkaline complexes in the Arabian Shield have shown that most samples lost less than 20% of their U during recent exposure to the near-surface environment. Most of the U in these samples appears to be firmly bound in zircons. In contrast, most surface and shallow drill-core samples of the granite of Lankin Dome (Granite Mountains, Wyoming) have lost ??? 70% of their U. Most of the U in these samples is weakly bound in biotite and epidote-family minerals. The granite recovered during the Illinois Deep Drill Hole Project (Stephenson County, Illinois) is mineralogically similar to the granite of Lankin Dome, but this granite lost radiogenic Pb rather than U, probably as a result of exposure to groundwater that had a markedly different chemistry from that in the Granite Mountains. Studies of the Sherman Granite (Wyoming) and the Go??temar Granite (southeastern Sweden) have shown that U and/or Pb mobility is greatest in and near fractured rock. The greater mobility is interpreted to be the result of both a larger water/rock ratio in the fractured rock and exposure to water over an increased surface area (and consequently a greater number of uranium sites). Several types of geochemical and mineralogic data can be used to identify rock-water interaction in granites; however, if rock samples have favorable radiogenic to common Pb ratios, both the amount and approximate timing of U or Pb

  3. Oxygen-isotope geochemistry of quaternary rhyolite from the Mineral Mountains, Utah, USA

    SciTech Connect

    Bowman, J.R.; Evans, S.H. Jr.; Nash, W.P.

    1982-03-01

    Oxygen isotope analyses were made of phenocryst and glass separates from four Quaternary rhyolite flows and domes in the Mineral Mountains, southwest Utah. With the exception of biotite in all samples and alkali feldspar in the rhyolite domes, all minerals appear to be in close oxygen isotope exchange equilibrium. The geothermometry equations proposed by Bottinga and Javoy (1973) and Javoy (1977) for quartz, alkali feldspar and magnetite produce the best agreement with temperature results fom two-feldspar and iron-titanium oxide geothermometry for these rhyolites. If the rhyolites were generated by partial melting in the crust, their whole-rock (glass) delta/sup 18/O values (6.3 to 6.9 permil) are consistent with generation from I-type (Chappell and White, 1974, O'Neil and Chappell, 1977; O'Neil et. al., 1977) sources.

  4. Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols

    NASA Astrophysics Data System (ADS)

    Bindeman, I. N.; Eiler, J. M.; Wing, B. A.; Farquhar, J.

    2007-05-01

    We present analyses of stable isotopic ratios 17O/ 16O, 18O/ 16O, 34S/ 32S, and 33S/ 32S, 36S/ 32S in sulfate leached from volcanic ash of a series of well known, large and small volcanic eruptions. We consider eruptions of Mt. St. Helens (Washington, 1980, ˜1 km 3), Mt. Spurr (Alaska, 1953, <1 km 3), Gjalp (Iceland, 1996, 1998, <1 km 3), Pinatubo (Phillipines, 1991, 10 km 3), Bishop tuff (Long Valley, California, 0.76 Ma, 750 km 3), Lower Bandelier tuff (Toledo Caldera, New Mexico, 1.61 Ma, 600 km 3), and Lava Creek and Huckleberry Ridge tuffs (Yellowstone, Wyoming, 0.64 Ma, 1000 km 3 and 2.04 Ma 2500 km 3, respectively). This list covers much of the diversity of sizes and the character of silicic volcanic eruptions. Particular emphasis is paid to the Lava Creek tuff for which we present wide geographic sample coverage. This global dataset spans a significant range in δ34S, δ18O, and Δ17O of sulfate (29‰, 30‰, and 3.3‰, respectively) with oxygen isotopes recording mass-independent ( Δ17O > 0.2‰) and sulfur isotopes exhibiting mass-dependent behavior. Products of large eruptions account for most of' these isotopic ranges. Sulfate with Δ17O > 0.2‰ is present as 1-10 μm gypsum crystals on distal ash particles and records the isotopic signature of stratospheric photochemical reactions. Sediments that embed ash layers do not contain sulfate or contain little sulfate with Δ17O near 0‰, suggesting that the observed sulfate in ash is of volcanic origin. Mass-dependent fractionation of sulfur isotopic ratios suggests that sulfate-forming reactions did not involve photolysis of SO 2, like that inferred for pre-2.3 Ga sulfates from Archean sediments or Antarctic ice-core sulfate associated with few dated eruptions. Even though the sulfate sulfur isotopic compositions reflect mass-dependent processes, the products of caldera-forming eruptions display a large δ34S range and exhibit fractionation relationships that do not follow the expected equilibrium

  5. Uranium-thorium isotope geochemistry of saline ground waters from central Missouri

    SciTech Connect

    Banner, J.L.; Chen, J.H.; Wasserburg, G.J.

    1989-03-01

    The isotopic and elemental distributions of uranium and thorium were examined in a suite of saline ground waters from central Missouri using mass spectrometric techniques. The waters were sampled from natural springs and artesian wells in Mississippian and Ordovician aquifers and have a wide range in salinity (5 to 26 /per thousand/), deltaD (/minus/108 to /minus/45 /per thousand/), and delta/sup 18/O (/minus/14.7 to /minus/6.5 /per thousand/) values. The suite of samples has a large range in /sup 238/U (50 to 200 x 10/sup /minus/12/g/g) and /sup 232/Th (0.3 to 9.1 x 10/sup /minus/12/g/g) concentrations and extremely high /sup 234/U//sup 238/U activity ratios ranging from 2.15 to 16.0. These isotopic compositions represent pronounced uranium-series disequilibrium compared with the value of modern seawater (1.15) or the equilibrium value (1.00). For such /sup 234/U-enriched waters, /sup 234/U//sup 238/U isotope ratios can be determined with a precision of /+-/ 10 /per thousand/ (2sigma) on 10 mL of sample and less than /+-/5 /per thousand/ on 100 mL. In contrast to the large /sup 234/U enrichments, /sup 230/Th//sup 238/U activity ratios in the ground waters are significantly lower than the equilibrium value. The more saline samples have markedly higher /sup 234/U//sup 238/U activity ratios and lower deltaD and delta/sup 18/O values. Unfiltered and filtered (< 0.1 ..mu..m) aliquots of a saline sample have the same isotopic composition and concentration of uranium, indicating uranium essentially occurs entirely as a dissolved species. The filtered/unfiltered concentration ratio for thorium in this sample is 0.29, demonstrating the predominant association of thorium with particulates.

  6. Implications of formation water movement based on isotopic data and elemental geochemistry, southwestern Ontario

    SciTech Connect

    Frape, S.K.; Dollar, P.; Fritz, P.; Travail, R.A.; McNutt, R.H.; MacQueen, R.W.

    1986-08-01

    Formation waters in Paleozoic sediments analyzed for /sup 2/H, /sup 18/O, /sup 87/Sr//sup 86/Sr, tritium, and major/minor contents show the following. (1) The stable isotope contents are typical for formation brines, but have /sup 18/O and /sup 2/H values that group according to formation age, with waters in Cambrian strata being most depleted; and the most concentrated brines do not compare well to known Michigan basin brines. Many waters are Ca-Na-Cl brines similar to typical Canadian shield brines, although the origin of the various chemical species may be masked by intense rock-water interaction. (2) The /sup 87/Sr//sup 86/Sr values for Cambrian brines range from 0.7095 to 0.7102. In one detailed study, the brine and calcite cement had the same value (0.7095), which is slightly higher than Cambrian seawater (0.7091-0.7092), and indicates that the cement precipitated from the brine during diagenesis. The reservoir rock has a /sup 87/Sr//sup 86/Sr value of 0.7330, indicating little or no water/rock exchange. Sr isotopic values for Ordovician brines range from 0.7095 to 0.7103, which is higher than Ordovician seawater (0.7085). In contrast, the Silurian Salina Formation brines and Silurian seawater values are the same (0.7085-0.7087). Despite an active tectonic history, causing considerable faulting and movement within Paleozoic and Precambrian rock strata, the isotopic results for the Cambrian indicate isotopic equilibrium between brine and cement; therefore, these formation waters have not moved since the calcite formed.

  7. Strong Relationship between Hf-Nd-Pb Isotopes in Atlantic Sediments and the Lesser Antilles arc Composition

    NASA Astrophysics Data System (ADS)

    Carpentier, M.; Chauvel, C.; Mattielli, N.

    2006-12-01

    Geochemical variability of lavas from the Lesser Antilles arc is well established and is characterized by a chemical zoning from north to south along the arc. Lavas from the northern part of the arc have usually less radiogenic and less variable Sr and Pb isotopic compositions than those from the south. Possible explanations include a larger contribution from sediments in the source of the southern islands, and/or a north-south change in the chemical composition of the sediments that are subducted beneath the Lesser Antilles arc We conducted a geochemical study (Nd, Hf and Pb isotopic compositions) of Atlantic sediments coming from two different sites drilled during DSDP Leg 78 (site 543, 15.7N) and DSDP Leg 14 (site 144, 9.5N). At site 543, the sedimentary pile has epsilon Nd values between -14.6 and -11 and epsilon Hf between -10.6 and -1. 206Pb/204Pb ratios vary between 19.1 and 19.5. The sediment pile has an overall strong continental signature suggesting that their source is primarily detrital. This is in agreement with the interpretation of White et al. (1985) who suggested that the dominant source was the Archean Guiana Highland drained by the Orinoco River. Further south, at site 144, the succession consists of chalk ooze, marl and clays, and organic-rich black shales. Samples have epsilon Nd between -18.4 and -10 and epsilon Hf between -20.4 and -5.4 and the Pb isotopic compositions are extremely variable. Chalk ooze, marl and clay have 206Pb/204Pb ratios between 18.8 and 20.0, while the black shales have extremely radiogenic compositions with 206Pb/204Pb between 21.6 and 27.7. These compositions reflect the radioactive decay of authigenic uranium concentrated in organic- rich layers characterized by elevated 238U/204Pb ratios (100 up to 600). The isotopic compositions of sediments from both sites are largely influenced by continental input with Nd and Hf isotopes plotting in the continental domain of the "terrestrial array", but the southern site has more

  8. Isotope Geochemistry of Possible Terrestrial Analogue for Martian Meteorite ALH84001

    NASA Technical Reports Server (NTRS)

    Mojzsis, Stephen J.

    2000-01-01

    We have studied the microdomain oxygen and carbon isotopic compositions by SIMS of complex carbonate rosettes from spinel therzolite xenoliths, hosted by nepheline basanite, from the island of Spitsbergen (Norway). The Quaternary volcanic rocks containing the xenoliths erupted into a high Arctic environment and through relatively thick continental crust containing carbonate rocks. We have attempted to constrain the sources of the carbonates in these rocks by combined O-18/O-16 and C-13/C-12 ratio measurements in 25 micron diameter spots of the carbonate and compare them to previous work based primarily on trace-element distributions. The origin of these carbonates can be interpreted in terms of either contamination by carbonate country rock during ascent of the xenoliths in the host basalt, or more probably by hydrothermal processes after emplacement. The isotopic composition of these carbonates from a combined delta.18O(sub SMOW) and delta.13C(sub PDB) standpoint precludes a primary origin of these minerals from the mantle. Here a description is given of the analysis procedure, standardization of the carbonates, major element compositions of the carbonates measured by electron microprobe, and their correlated C and O isotope compositions as measured by ion microprobe. Since these carbonate rosettes may represent a terrestrial analogue to the carbonate "globules" found in the martian meteorite ALH84001 interpretations for the origin of the features found in the Spitsbergen may be of interest in constraining the origin of these carbonate minerals on Mars.

  9. Ca Isotope Evidence for Changes in the Carbonate Geochemistry of Seawater Across OAE 2

    NASA Astrophysics Data System (ADS)

    Lehn, G. O.; Jacobson, A. D.; Du Vivier, A.; Selby, D. S.; Hurtgen, M.; Sageman, B. B.

    2014-12-01

    We used a new high-precision MC-TIMS method to generate Ca isotope records (δ44/40Ca; 2SD = ± 0.04‰) for three sections spanning OAE 2: central Colorado, USA (Portland #1 core), southeastern France (Pont d'Issole), and Eastbourne, England (Eastbourne Chalk). The Eastbourne Chalk δ44/40Ca values are higher than previously reported but define a similar trend, where δ44/40Ca values increase prior to OAE 2 and then decrease at the onset. The Portland core and the Pont d'Issole section display comparable δ44/40Ca values, which increase by ~0.10 - 0.15‰ immediately at the onset of OAE 2 and then decrease to near-initial values across the event. According to a numerical model of the marine Ca cycle, reasonable changes to the riverine and hydrothermal input fluxes cannot explain the rate and magnitude of the positive isotope excursion. A decrease in the magnitude of the carbonate fractionation factor provides the best explanation for the data. Because a decrease in the fractionation factor corresponds to an increase in the Ca/CO3 ratio of seawater, we tentatively attribute the positive Ca isotope excursion to transient ocean acidification, i.e., a reduction in the concentration of CO3 during CO2 uptake. Other studies implicate eruption of the Caribbean Large Igneous Province as the most likely source of CO2.

  10. Isotopic geochemistry of acid thermal waters and volcanic gases from Zaō volcano in Japan

    NASA Astrophysics Data System (ADS)

    Kiyosu, Yasuhiro; Kurahashi, Makoto

    1984-08-01

    The chemical composition and D/H, {18O }/{16O } and {34S }/{32S } ratios have been determined for the acid hot waters and volcanic gases discharging from Zaō volcano in Japan. The thermal springs in Zaō volcano issue acid sulfate-chloride type waters (Zaō) and acid sulfate type waters (Kamoshika). Gases emitted at Kamoshika fumaroles are rich in CO 2, SO 2 and N 2, exclusive of H 2O. Chloride concentrations and oxygen isotope data indicate that the Zaō thermal waters issue a fluid mixture from an acid thermal reservoir and meteoric waters from shallow aquifers. The waters in the Zaō volcanic system have slight isotopic shifts from the respective local meteoric values. The isotopic evidence indicates that most of the water in the system is meteoric in origin. Sulfates in Zaō acid sulfate-chloride waters with δ34S values of around +15‰, are enriched in 34S compared to Zaō H 2S, while the acid sulfate waters at Kamoshika contain supergene light sulfate ( δ 34S = ˜ + 4‰ ) derived from volcanic sulfur dioxide from the volcanic exhalations. The sulfur species in Zaō acid waters are lighter in δ34S than those of other volcanic areas, reflecting the difference in total pressure.

  11. Carbon isotope geochemistry of the Cretaceous-Tertiary section of the Wasserfallgraben, Lattengebirge, southeast Germany

    NASA Astrophysics Data System (ADS)

    Arneth, J.-D.; Matzigkeit, U.; Boos, A.

    1985-09-01

    Carbonates and organic matter in sediments of the Cretaceous-Tertiary (C/T) section of the Wasserfallgraben, Lattengebirge (Bavaria) have been investigated. All parameters—the carbonate content (C carb), its isotopic composition ( δ 13C carb, δ 18O carb) as well as the organic carbon content (C org), its isotopic composition ( δ 13C org) and the H/C ratio of the sedimentary organic matter—display systematic variations across the C/T boundary which cannot be attributed to a single cause. The boundary zone as a whole is tectonically disturbed and shows significant features of detrital contaminations. Unidirectional shift in δ 13C carb and δ 13C org are observed when directly comparing Maastrichtian (latest Cretaceous) and Danian (earliest Tertiary) sediments. These synchronous isotope displacements towards more negative readings are interpreted to reflect the reduced photosynthetic activity as consequence of the mass extinction at the C/T boundary. The results may have some bearings on other C/T profiles investigated where measurements on the reduced carbon species are still lacking.

  12. Stable isotope geochemistry of acid mine drainage: Experimental oxidation of pyrite

    USGS Publications Warehouse

    Taylor, B.E.; Wheeler, M.C.; Nordstrom, D.K.

    1984-01-01

    Sulfate and water from experiments in which pyrite was oxidized at a pH of 2.0 were analyzed for sulfur and oxygen stable isotopes. Experiments were conducted under both aerobic and anaerobic sterile conditions, as well as under aerobic conditions in the presence of Thiobacillus ferrooxidans, to elucidate the pathways of oxidation. Oxygen isotope fractionation between SO2-4 and H2O varied from +4.0 %. (anaerobic, sterile) to + 18.0 %. (aerobic, with T. ferrooxidans.). The oxygen isotope composition of dissolved oxygen utilized in both chemical and microbially-mediated oxidation was also determined (+11.4 %., by T. ferrooxidans; +18.4 %., chemical). Contributions of water-derived oxygen and dissolved oxygen to the sulfate produced in the oxidation of pyrite could thus be estimated. Water-derived oxygen constituted from 23 to ~ 100 percent of the oxygen in the sulfate produced in the experiments, and this closely approximates the range of contribution in natural acid mine drainage. Oxidation of sulfides in anaerobic, water-saturated environments occurs primarily by chemical oxidation pathways, whereas oxidation of sulfides in well-aerated, unsaturated zone environments occurs dominantly by microbially mediated pathways. ?? 1984.

  13. Isotopic Ag-Cu-Pb record of silver circulation through 16th-18th century Spain.

    PubMed

    Desaulty, Anne-Marie; Telouk, Philippe; Albalat, Emmanuelle; Albarède, Francis

    2011-05-31

    Estimating global fluxes of precious metals is key to understanding early monetary systems. This work adds silver (Ag) to the metals (Pb and Cu) used so far to trace the provenance of coinage through variations in isotopic abundances. Silver, copper, and lead isotopes were measured in 91 coins from the East Mediterranean Antiquity and Roman world, medieval western Europe, 16th-18th century Spain, Mexico, and the Andes and show a great potential for provenance studies. Pre-1492 European silver can be distinguished from Mexican and Andean metal. European silver dominated Spanish coinage until Philip III, but had, 80 y later after the reign of Philip V, been flushed from the monetary mass and replaced by Mexican silver. PMID:21606351

  14. Isotopic Ag–Cu–Pb record of silver circulation through 16th–18th century Spain

    PubMed Central

    Desaulty, Anne-Marie; Telouk, Philippe; Albalat, Emmanuelle; Albarède, Francis

    2011-01-01

    Estimating global fluxes of precious metals is key to understanding early monetary systems. This work adds silver (Ag) to the metals (Pb and Cu) used so far to trace the provenance of coinage through variations in isotopic abundances. Silver, copper, and lead isotopes were measured in 91 coins from the East Mediterranean Antiquity and Roman world, medieval western Europe, 16th–18th century Spain, Mexico, and the Andes and show a great potential for provenance studies. Pre-1492 European silver can be distinguished from Mexican and Andean metal. European silver dominated Spanish coinage until Philip III, but had, 80 y later after the reign of Philip V, been flushed from the monetary mass and replaced by Mexican silver. PMID:21606351

  15. Rare earth element and stable isotope (O, S) geochemistry of barite from the Bijgan deposit, Markazi Province, Iran

    NASA Astrophysics Data System (ADS)

    Ehya, Farhad

    2012-01-01

    tectonic setting, host rock characteristics, REE geochemistry, and oxygen and sulfur isotopic compositions support a submarine hydrothermal origin for the Bijgan barite deposit. At the seafloor, barite deposition occurred where ascending Ba-bearing hydrothermal fluids encountered seawater. Sulfate was derived from the sulfate-bearing marine waters, and, to a lesser extent, by oxidized H2S, which was derived from magmatic hydrothermal fluids.

  16. The Inter-Tropical Convergence Zone: A causal mechanism for Pb isotope cyclicity in Tropical Atlantic sediment cores

    NASA Astrophysics Data System (ADS)

    Abouchami, W.; Zabel, M.

    2003-04-01

    Lead isotopic compositions of bulk sediment cores from the Tropical Atlantic can be used to infer variations in the provenance of terrigenous input to the Tropical Atlantic during Pleistocene climate cycles. Pb isotope data were obtained using the triple spike method (Galer, 1999) on bulk sediments cores and cover the last six Marine Isotope Stages. The 200-ka high precision (2σ ˜100 ppm) Pb isotope records of the Ceará Rise (Western Atlantic, core GeoB1523-1, 3^o49'N, 41^o37'W, 3292 m) and Sierra Leone Rise (Eastern Atlantic, core GeoB2910-1, 4^o50'N, 21^o03'W, 2703 m) cores show a clear glacial-interglacial cyclicity, reflected by alternating unradiogenic Pb and radiogenic Pb. Changes in the relative proportions of the glacial (unradiogenic) and interglacial (radiogenic) Pb source(s) can be explained by changes in the erosional regime (chemical vs. physical) as a function of prevailing climate, combined with different mechanisms of Pb transport to the oceans (predominantly eolian in the Eastern Atlantic vs. riverine in the Western Atlantic). We interpret these regional changes as reflecting shifts in the mean latitude of the Inter-Tropical Convergence Zone that affects the hydrological cycle over South America and the wind systems over Africa. Our results strongly favor an increase in winter wind transport (rather than glacial hyper aridity) as the cause of enhanced glacial terrigenous fluxes observed in the Tropical Atlantic (Ruddiman, 1997). The two Atlantic Pb isotopic records exhibit strong correlations with Pleistocene sea level fluctuations, providing evidence for global teleconnection between tropical records and high latitude climate. Galer, S.J.G. (1999). Optimal double and triple spiking for high precision lead isotopic measurements. Chem. Geol. 154, 255-274. Ruddiman, W. F. (1997). Tropical Atlantic terrigenous fluxes since 25,000 yrs B.P., Mar. Geol., 136, 189-207.

  17. Isotopic composition and concentration of Pb in suspended particulate matter of the Irish Sea reveals distribution and sources.

    PubMed

    Charlesworth, M E; Chenery, S; Mellor, A; Service, M

    2006-01-01

    The isotopic composition and concentration of Pb was measured in suspended particulate matter of the Irish Sea. Aerosol, surficial and pre-industrial sediment was also analysed to provide information on sources terms. Concentrations of Pb in suspended sediments were lower than previously reported which presumably reflects the international effort to reduce Pb inputs to the environment. Lead concentrations were highest in Liverpool Bay and lowest in the western Irish Sea. A significant negative relationship between Pb and salinity suggests that present inputs and the resuspension of relict lead associated with particles in areas significantly affected by freshwater discharges are the predominant sources of Pb to the Irish Sea. The isotopic composition of Pb in the stratified region of the western Irish Sea demonstrates that atmospheric sources are also significant to this region, which is consistent with current knowledge on the hydrography. Pb isotopic ratios show that water entering the Irish Sea through St George's Channel is significantly influenced by anthropogenic inputs prior to additional contamination by direct inputs to the Irish Sea. PMID:16194553

  18. Chlorine isotope geochemistry of hydrothermally altered oceanic crust: Mineralogical controls and experimental constraints

    NASA Astrophysics Data System (ADS)

    Cisneros, M.; Barnes, J.; Jenkins, D. M.; Gardner, J. E.

    2012-12-01

    Chlorine stable isotopes (37Cl and 35Cl) can provide an important fingerprint for geochemical recycling of subducted oceanic lithosphere and fluid-rock interaction due to chlorine's high solubility in aqueous phases. To implement Cl isotopes as a tracer of volatile element recycling, we must constrain the δ37Cl value of potential Cl reservoirs and determine fractionation factors between Cl-bearing phases. δ37Cl and Cl concentrations of hydrothermally altered oceanic crust (AOC) samples from seven IODP/ODP/DSDP drill sites have been measured on bulk rock samples (n = 50). For ease of comparing results, samples are categorized into three lithologies: 1) extrusive lavas, 2) sheeted dikes, and 3) gabbros. Extrusive lava Cl concentrations vary from <0.01 wt% to 0.03 wt% (avg = 95 ppm Cl; n= 20) and δ37Cl values range from -1.4 to +1.0‰ (avg = 0.0 ± 0.6‰). Chlorine concentrations of the sheeted dikes range from < 0.01 wt% to 0.05 wt% (avg = 163 ppm Cl; n = 11) and δ37Cl values of dikes range from - 0.4 to + 1.4‰ (avg = 0.1 ± 0.3‰). Bulk chlorine concentrations of the gabbros range from < 0.01 wt% to 0.09 wt% (avg = 244 ppm Cl; n = 19). δ37Cl values of gabbros range from - 0.6 to + 1.8‰ (avg = 0.6 ± 0.6‰). Three general conclusions can be derived from these AOC bulk rock results: 1) δ37Cl values and Cl concentrations increase with increasing total amphibole content. 2) Based on re-calculations of mass balance equations using updated AOC Cl concentrations (~3 times higher than previous estimates, this study), the total amount of Cl recycled into the mantle is higher than previously estimated. 3) [Cl] and δ37Cl values can provide a crude estimate of metamorphic grade in AOC samples. Amphibole-water Cl isotope fractionation experiments are necessary for quantifying the magnitude of Cl fractionation and to aid in interpreting the range of natural Cl isotope variation. Determination of equilibrium fractionation factors between hydrous minerals and co

  19. Little Ice Age Recorded in Mn/Fe Precipitates by Pb and Nd Isotopes

    NASA Astrophysics Data System (ADS)

    Liebetrau, V.; Eisenhauer, A.; Frei, R.; Bock, B.; Kronz, A.; Hansen, B. T.; Leipe, T.

    2002-12-01

    Ferromanganese precipitates of the Baltic Sea can be dated by the 226Raexcess/Ba-method (Liebetrau et al., 2002). Recent investigations have shown that these precipitates may represent perfect archives for the postglacial history of the circum Baltic area. In particular, these precipitates offer the possibility to study short term variations of the Scandinavian shield erosion and climate change during the Little Ice Age. The Nd isotope record of a selected Mn/Fe crust from the Mecklenburg Bay of the Baltic Sea shows a significant change of the ɛ Nd-value from around -13 for ages older than 1100 years AD to approx. -18 around 1600 years AD. This shift can be explained by increased erosion and input of Nd from Archean Scandinavian sources and/or a reduced inflow of North Atlantic water (ɛ Nd = -13) to the Baltic Sea. Comparison with a temperature reconstruction for Fennoscandia (Mann, 2001) documents a close relationship of the ɛ Nd record with temperature variations during the Little Ice Age because negative ɛ Nd-value tend to correlate with lower temperature during the last 1000 years. In contrast, the pattern of 207Pb/206Pb record closely correlates with historically known changes of anthropogenic activities during the industrial revolution and times of enhanced Ag and Pb mining. Nd and Pb are correlated before 1100 AD but are decoupled after at about 1100 years AD. We propose that Pb appears to be more sensitive to anthropogenic activities since about 1100 AD. Liebetrau V., Eisenhauer A., Gussone N., W”rner G., Hansen B.T., and Leipe T., 2002, 226Raexcess/Ba growth rates and U-Th-Ra-Ba systematic of Baltic Mn/Fe crusts, Geochim. Cosmochim. Acta, 66, 73-83 Mann M.E., 2001, The Little Ice Age, in: Encyclopedia of Environmental Global Change

  20. Isotope and elemental geochemistry of Cretaceous fossiliferous concretions (Santana Formation, Brazil)

    NASA Astrophysics Data System (ADS)

    Heimhofer, Ulrich; Meister, Patrick; Bernasconi, Stefano M.; Ariztegui, Daniel; Martill, David M.; Schwark, Lorenz

    2014-05-01

    Exceptional three-dimensional fossil preservation (incl. phosphatization of soft-tissues) within organic carbon-rich mudstones is often associated with the formation of a protective carbonate shell surrounding the fossil specimen. Examples for this type of preservation are the Early Cretaceous fishes, turtles and pterosaurs from the Brazilian Santana Formation. Numerous studies proposed different conceptual models for concretion formation. Having new state-of-the-art geochemical tools at hand we revisited these models for the Santana Formation as an exemplary case. Differential compaction clearly indicates early precipitation of micritic calcite surrounding a central cavity containing the still decomposing fossil. The presence of pyrite forming a circular rim around the fossil and carbonate with negative carbon isotope compositions suggest intense sulphate reduction whereby the production of ammonium from the decay of proteins led to an increased alkalinity, which induced early carbonate precipitation. By means of micro-XRF scanning we found that pyrite is absent from the interior part of the concretions and that total iron content is very low, which indicate absence of sulphate reduction at the center of the concretions and possibly local onset of methanogenesis. We postulate that the central cavity may even have been filled with methane gas that evolved from the decaying animal. Methane diffusing outward was anaerobically oxidized in the surrounding sulphate reduction zone. Carbonate clumped isotopes revealed that micritic calcite formed early, but that these early precipitates are overprinted by two different late diagenetic cements precipitated at elevated temperatures. The occurrence of an outermost "cone-in-cone" calcite rim can be associated with burial showing temperatures of up to 60°C. Strontium-isotope ratios of matrix calcite and cement phases show radiogenic values (0.710416 to 0.712465), which are significantly higher than typical marine Cretaceous

  1. Zircon U-Pb age, geochemical, and Sr-Nd-Pb isotopic constraints on the origin of alkaline intrusions in eastern Shandong Province, China

    NASA Astrophysics Data System (ADS)

    Liu, Shen; Feng, Caixia; Hu, Ruizhong; Gao, Shan; Wang, Tao; Feng, Guangying; Qi, Youqiang; Coulson, Ian M.; Lai, Shaocong

    2013-08-01

    Alkaline intrusions in the eastern Shandong Province consist of quartz monzonite and granite. U-Pb zircon ages, geochemical data, and Sr-Nd-Pb isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon analyses yielded consistent ages ranging from 114.3 ± 0.3 to 122.3 ± 0.4 Ma for six samples of the felsic rocks. The felsic rocks are characterised by a wide range of chemical compositions (SiO2 = 55.14-77.63 wt. %, MgO = 0.09-4.64 wt. %, Fe2O3 = 0.56-7.6 wt. %, CaO = 0.40-5.2 wt. %), light rare earth elements (LREEs) and large ion lithophile elements (LILEs) (i.e., Rb, Pb, U) enrichment, as well as significant rare earth elements (HREEs) and heavy field strength (HFSEs) (Nb, Ta, P and Ti) depletion, various and high (87Sr/86Sr) i ranging from 0.7066 to 0.7087, low ɛ Nd (t) values from -14.1 to -17.1, high neodymium model ages (TDM1 = 1.56-2.38Ga, TDM2 = 2.02-2.25Ga), 206Pb/204Pb = 17.12-17.16, 207Pb/204Pb = 15.44-15.51, and 208Pb/204Pb = 37.55-37.72. The results suggested that these rocks were derived from an enriched crustal source. In addition, the alkaline rocks also evolved as the result of the fractionation of potassium feldspar, plagioclase, +/- ilmenite or rutile and apatite. However, the alkaline rocks were not affected by crustal contamination. Moreover, the generation of the alkaline rocks can be attributed to the structural collapse of the Sulu organic belt due to various processes.

  2. Using size fractionation and Pb isotopes to study Pb transport in the waters of an organic-rich upland catchment.

    PubMed

    Graham, Margaret C; Vinogradoff, Susan I; Chipchase, Alastair J; Dunn, Sarah M; Bacon, Jeffrey R; Farmer, John G

    2006-02-15

    Processes controlling Pb release from a small organic-rich upland catchment in northeast Scotland were investigated via measurement of Pb concentrations and 206Pb/207Pb ratios in rainwater, throughflow, surface flow, and receiving streamwaters under storm and baseflow conditions. For this catchment, the output of Pb via streams was only 2.0 +/- 1.2 kg year(-1) (11.4 +/- 6.8 g ha(-1) year(-1)), much lower than the input of 7.5 +/- 2.0 kg year(-1) (42.6 +/- 11.4 g ha(-1) year(-1)), and so the catchment is still a sink for anthropogenic Pb. Most (68-87%) of the output, however, occurred under storm conditions. Size fractionation revealed that 50-60% was in large particulate form (>25 microm) with a 206Pb/ 207Pb ratio of approximately 1.16, similar to that of the surface soils. Some 30-40% of the storm Pb output was associated with dissolved organic matter in the <0.45 microm fraction and had a lower 206Pb/207Pb ratio of approximately 1.14, close to the value obtained for near-surface throughflow. Future extreme weather conditions such as prolonged dry or wet periods will increase transport of Pb to receiving waters. Although particulate forms could then rapidly be removed under low flow conditions, Pb associated with dissolved organic matter will persist longer in aquatic systems and may also be more bioavailable. PMID:16572783

  3. Geochronology, geochemistry, and Sr-Nd-Hf isotopes of the early Paleozoic igneous rocks in the Duobaoshan area, NE China, and their geological significance

    NASA Astrophysics Data System (ADS)

    Wu, Guang; Chen, Yuchuan; Sun, Fengyue; Liu, Jun; Wang, Guorui; Xu, Bei

    2015-01-01

    The Duobaoshan area of northwestern Heilongjiang Province is the most important copper resource concentration region in NE China. To date, the Duobaoshan superlarge Cu-Mo deposit and the Tongshan large Cu-Mo deposit have been discovered in the Duobaoshan area. Both the deposits are hosted by granodiorites and volcanic rocks. Zircon LA-ICP-MS U-Pb dating indicates that these granodiorites emplaced approximately 479 Ma ago and that those volcanic rocks erupted between 447 and 450 Ma. The early Ordovicain granodiorites belong to the high-K to medium-K calc-alkaline series and are characterized by high Al2O3 and Sr contents, low Yb and Y contents, and relatively low Mg# values and Na2O/K2O ratios, with positive Eu or slight negative Eu anomalies (averaging 1.18). All of these geochemical characters are similar to those of the adakites generated by partial melting of a thickened lower crust in the world. Moreover, the granodiorites have low initial 87Sr/86Sr ratios (varying from 0.703474 to 0.704436), very high zircon εHf(t) and whole-rock εNd(t) values (varying from 13.0 to 16.8 and 5.27 to 5.46, respectively), and young zircon Hf and whole-rock Nd single-stage and two-stage model ages. Taking these geochemical characteristics and Sr-Nd-Hf isotope compositions together, we suggest that the early Ordovician granodiorites in the Duobaoshan area occurred in a post-collision environment and were formed by partial melting of a juvenile thickened lower crust dominated by depleted mantle-derived material. These late Ordovician volcanic rocks, which are composed of basalt, basaltic andesite, and andesite, belong to the tholeiitic or calc-alkaline series. They are generally enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs; e.g., Nb, Ta, Zr, Hf, P, and Ti), consistent with the geochemistry of igneous rocks from island arcs or active continental margins. Compared with the early Ordovician granodiorites, these volcanic rocks

  4. Petrogenesis of Sveconorwegian magmatism in southwest Norway; constraints from zircon U-Pb-Hf-O and whole-rock geochemistry

    NASA Astrophysics Data System (ADS)

    Roberts, Nick M. W.; Slagstad, Trond; Parrish, Randall R.; Norry, Michael J.; Marker, Mogens; Horstwood, Matthew S. A.; Røhr, Torkil

    2013-04-01

    The Sveconorwegian orogen is traditionally interpreted as a Himalayan-scale continental collision, and the eastward continuation of the Grenville Province of Laurentia; however, it has recently been proposed that it represents an accretionary orogen without full-scale continental collision (Slagstad et al., in press). We suggest that magmatism is one of the key constraints to differentiate between different types of orogens; thus, detailed investigation of the timing and petrogenesis of the magmatic record is a requirement for better understanding of the Sveconorwegian orogen as a whole. Here, we present new U-Pb geochronology, zircon Hf-O isotope, and whole-rock geochemical data to constrain the petrogenesis of the early -Sveconorwegian Sirdal Magmatic Belt (SMB). The SMB is a batholithic-scale complex of intrusions that intrudes into most of the Rogaland-Hardangervidda Block in southwest Norway. Current age constraints put emplacement between ~1050 to 1020 Ma. New ages from the Suldal region indicate that the onset of SMB magmatism can be put back to 1070 Ma, which is some 30-50 Myrs prior to high-grade metamorphism. Average initial ɛHf signatures range from ~0 to 4; these overlap with later post-Sveconorwegian granites and with early-/pre-Sveconorwegian ferroan (A-type) granites. Average δ18O signatures range from ~5.7 to 8.7, except for one anomalous granite at ~11.6. The Hf-O signatures are compatible with a mixed mantle-crustal source. Crustal sources may include ~1500 Ma Telemarkian or ~1200 Ma juvenile crust. Hf-O bulk-mixing modelling using a 1500 Ma crustal source indicates >50 % mantle input. Although much further mapping and geochronological work is required, granitic magmatism appears to have persisted throughout much of the ~1100 to 900 Ma period that spans the Sveconorwegian orogen. This magmatism is consistently ferroan (i.e. dry); however, the SMB marks a clear transition to magnesian (i.e. wet) magmatism, with a return to ferroan magmatism at

  5. The geochemistries of 210Po and 210Pb in waters overlying and within the Orca Basin, Gulf of Mexico

    NASA Astrophysics Data System (ADS)

    Todd, James F.; Wong, George T. F.; Reid, David F.

    1986-10-01

    Vertical profiles of dissolved 210Po, 210Pb, and 226Ra were obtained from waters overlying and within the Orca Basin; an anoxic, hypersaline and virtually non-sulfide bearing basin in the Gulf of Mexico. The station had a depth of 2410 m. The seawater-brine interface was located at 2230 m. In oxic waters, near-surface (0-250 m) concentrations of dissolved 210Po and 210Pb ranged from 6 to 8 dpm/100 kg and decreased to about 3 dpm/100 kg at 740 m. Below this depth concentrations remained relatively constant. Near-surface 226Ra concentrations varied from about 7 to 9 dpm/100 kg, and then increased with depth to a relatively uniform deep-water value of approximately 13 dpm/100 kg, in agreement with previously reported data for the Gulf of Mexico. The slight deficiency of 210Pb in the surface waters may result from mixing with inner shelf waters that are enriched in 226Ra. At the seawater-brine interface, sharp maxima were observed in the profiles of 210Po, 210Pb, and 226Ra, where concentrations reached 56.0, 28.3, and 840 dpm/100 kg, respectively. These are among the highest values reported for the marine environment to date. Below the interface, concentrations decreased to about 9, 6, and 210 dpm/100 kg for 210Po, 210Pb, and 226Ra, respectively. These sharp maxima may be caused by a combination of the accumulation of particles in the strong pycnocline, the subsequent dissolution of particulate hydrous Mn and Fe oxides and hydroxides, and the decomposition of biogenic particulate material. The residence time of 210Pb in the brine is about one year, a value similar to that reported for the anoxic waters of the Cariaco Trench even though the concentration of 210Pb in that basin is much lower.

  6. The boron isotope geochemistry of the neogene borate deposits of western Turkey

    NASA Astrophysics Data System (ADS)

    Palmer, M. R.; Helvaci, C.

    1997-08-01

    We have analyzed the boron isotope composition of 80 borate minerals (major minerals: borax, colemanite, and ulexite; minor minerals: veatchite-A, tunellite, kernite, terrugite, probertite, meyer-hofferite, inderite, inyoite, hydroboracite, howlite, and pandermite) from the main deposits (Kirka, Bigadiç, and Emet) and two smaller deposits (Kestelek and Sultançayir) in the western Turkish borate deposits. Forty-three samples were also analysed for their Sr isotope composition. The data span a wide range in δ11B values from -1.6%o to -25.3%o. The δ 11B values of the main borate minerals are largely controlled by their mineralogy and the pH of the brines from which they precipitated. An inverse correlation between the average δ 11B and 87Sr/86Sr ratios of colemanite in the different deposits suggests there is some variation in the sources of boron and Sr to the deposits. Emet has the highest contribution from aluminosilicates and Kirka the highest contribution from Eocene carbonates, with Bigadiç occupying an intermediate position. The δ11B values of the minor borate minerals distinguish between those which are primary precipitates from the original brines (or formed from primary borates without boron loss from the system) and those which formed from alteration of preexisting borate minerals with substantial loss of boron from the system.

  7. Isotope geochemistry of thermal and nonthermal waters in the Valles caldera, Jemez Mountains, northern New Mexico

    SciTech Connect

    Vuataz, F.D.; Goff, F.

    1986-02-10

    Over 100 stable isotope and 45 tritium analyses from thermal and nonthermal waters of the Jemez Mountains region, New Mexico, have been used to define the hydrodynamics of the Valles caldera (Baca) geothermal system and related geothermal fluids of the region. Evaluation of 36 cold meteoric waters yields an equation for the Jemez Mountains meteoric water line of deltaD = 8delta/sup 18/O+12, while further evaluation of nine cold meteoric waters yields an equation relating recharge elevation to deuterium content of E(meters) = -44.9 (deltaD)-1154. Based on the deuterium content of five Baca well waters (223/sup 0/--294/sup 0/C), the average recharge elevation of the Valles geothermal system ranges from 2530 to 2890 m. This range of elevations falls between the elevations of the lowest point of the caldera floor (2400 m) and the summit of the resurgent dome inside the caldera (3430 m). Thus stable isotopes indicate that the caldera depression probably serves as a recharge basin for the deep geothermal system. Although cold spring waters of the Jemez Mountains region consist of meteoric water, tritium analyses show that most of them contain water between 20 and 75 years old.

  8. Organic Geochemistry of the Hamersley Province: Relationships Among Organic Carbon Isotopes, Molecular Fossils, and Lithology

    NASA Technical Reports Server (NTRS)

    Eigenbrode, Jennifer L.

    2012-01-01

    Molecular fossils are particularly valuable ancient biosignatures that can provide key insight about microbial sources and ecology in early Earth studies. In particular, hopanes carrying 2-methyl or 3-methyl substituents are proposed to be derived from cyanobacteria and oxygen-respiring methanotrophs, respectively, based on both their modem occurrences and their Proterozoic and Phanerozoic sedimentary distributions. Steranes are likely from ancestral eukaryotes. The distribution of methylhopanes, steranes, and other biomarkers in 2.72-2.56 billion-year-old rocks from the Hamersley Province, Western Australia show relationships to lithology, facies, and isotopes of macromolecular carbon, and other biomarkers. These observations support biomarker syngenicity and thermal maturity. Moreover, ecological signatures are revealed, including a surprising relationship between isotopic values for bulk macromolecular carbon and the biomarker for methanotrophs. The record suggests that cyanobacteria were likely key organisms of shallow-water microbial ecosystems providing molecular oxygen, fixed carbon, and possibly fixed nitrogen, and methanotrophs were not alone in recycling methane and other C-13-depleted substrates.

  9. Isotope geochemistry of crinoids from Burlington-Keokuk Formations: implications for diagenesis

    SciTech Connect

    Chyi, M.S.; Hanson, G.N.; Meyers, W.J.

    1985-01-01

    Petrographic studies suggest that early calcite cements are present within the intraskeletal pores of crinoids from the Mississippian Burlington-Keokuk Fms. of Illinois, Iowa, and Missouri. Procedures have been developed for analyzing the Sr isotope ratio, Sr and Rb abundances, and C and O isotope values for sample sizes of 2 mg or less. Drilled crinoids have Sr that is more radiogenic (0.70810-0.70845) than Mississippian sea water (0.7076), but generally less radiogenic than whole rock samples (0.7080-0.7089), drilled apatites (0.70880), plucked crinoid grains (0.7085-0.7090), drilled micrite (0.70853-0.71255), or late vug saddle dolomite (0.70967) and calcite (0.70890). Shale layers within the Keokuk Fm. have initial Sr of 0.708 to 0.714. Mass balance considerations suggest that these shales cannot be the primary source of the radiogenic Sr. The variations in C and Sr may reflect various extents of interaction with regional ground waters or brines. The micrite and apatite were apparently more strongly affected by later fluids than were the coexisting calcite cements within the crinoids.

  10. Origin of the ore-forming fluids and metals of the Bangpu porphyry Mo-Cu deposit of Tibet, China: Constraints from He-Ar, H-O, S and Pb isotopes

    NASA Astrophysics Data System (ADS)

    Wang, Liqiang; Tang, Juxing; Cheng, Wenbin; Chen, Wei; Zhang, Zhi; Lin, Xin; Luo, Maocheng; Yang, Chao

    2015-05-01

    The Bangpu porphyry Mo-Cu deposit is a representative Mo-dominated deposit besides the Sharang porphyry Mo deposit in the Gangdese metallogenic belt. The Mo-Cu mineralization has a close relationship with the monzogranite porphyry and diorite porphyrite. We identify three stages during the ore formation: a pre-ore stage, a main-ore stage with Mo-Cu deposited dominantly, and a post-ore stage. In this study, He-Ar, H-O, S and Pb isotopic compositions of the Bangpu deposit were determined. Based on these determinations, integrated isotope geochemistry studies were performed to constrain the possible sources of the ore-forming fluids and metals. The 3He/4He and 40Ar/36Ar ratios of fluid inclusions exhibit a range of 0.12209-0.36370 Ra and 275.6-346.1, respectively. The 4He and 40Ar concentrations vary from 1.51 to 3.57 (10-7 cm3 STP g-1) and 0.49 to 9.31 (10-7 cm3 STP g-1), respectively. He-Ar isotopic compositions suggest dominantly crustal-derived fluid with minor amount of meteoric water in the main ore stage. The δ18Ofluid and δDfluid values vary from -1.3‰ to 3.9‰ and -140.5‰ to -73.7‰, respectively, indicating that magma fluids mixed with meteoric water. The average δ34S value of the sulfides (0.3‰) in the main-ore stage is close to the ore-forming porphyries, indicating a magmatic source. The lead isotopic components of ore sulfides exhibit restricted ranges with 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of 18.450-18.728, 15.602-5.672, and 38.715-39.211, respectively and μ values in the range of and 9.46-9.58, indicating ore-forming metals of primarily an upper crust source with a small amount of mantle materials. Compared to the Bangpu deposit, the ore metals derived from mantle are even greater in the Jiama and Qulong deposits, which leads to Cu being the dominant mineralization in the Jiama and Qulong deposit.

  11. Cenozoic calcretes from the Teruel Graben, Spain: microstructure, stable isotope geochemistry and environmental significance

    NASA Astrophysics Data System (ADS)

    Alonso-Zarza, A. M.; Arenas, C.

    2004-05-01

    In the Teruel Graben (northeast Spain), laminar and nodular calcretes formed in a variety of Cenozoic deposits, ranging in age from Palaeogene to Pleistocene. These calcretes developed in a relatively small area under the influence of the same highlands. Consequently, differences in their microstructure and isotopic composition (C and O) must be related to differences in host rock, climate, vegetation and duration of development. Nine profiles developed in different sedimentary settings, from proximal areas to lacustrine environments, were studied to determine whether the microstructure and stable isotope composition changed during the Cenozoic. These characteristics might be used as indicators of the prevailing climate and vegetation, and reveal any changes that occurred during this time. Most of the laminar calcretes studied are compound profiles that formed on hard substrates (e.g., Jurassic limestones) or coarse detrital deposits (e.g., Palaeogene, Pliocene and Plio-Pleistocene sandstones and conglomerates). These profiles formed in proximal areas of the basin and also in fluvial terraces. Microstructures include biogenic features such as alveolar septal structures, root tubes, calcified root cells and calcified organic filaments. Underside coatings of micrite and fibrous vadose cements are common around gravel clasts. On the other side, spherulites are only preserved at the very top of the youngest calcretes. Nodular calcretes developed on fine detrital substrates (e.g., on Palaeogene, Miocene and Pliocene red mudstones and sandy mudstones of distal alluvial and floodplain environments), and in some places grade vertically into palustrine limestones. The nodules consist of micrite and were elongated vertically, show desiccation cracks and mottling, micritic coatings, some alveolar septal structures, and root traces. Microcodium of type 1 occurs in both laminar and nodular calcretes, but only in those of Palaeogene age, while calcified root cells ( Microcodium

  12. Comprehensive Pb-Sr-Nd-Hf isotopic, trace element, and mineralogical characterization of mafic to ultramafic rock reference materials

    NASA Astrophysics Data System (ADS)

    Fourny, Anaïs.; Weis, Dominique; Scoates, James S.

    2016-03-01

    Controlling the accuracy and precision of geochemical analyses requires the use of characterized reference materials with matrices similar to those of the unknown samples being analyzed. We report a comprehensive Pb-Sr-Nd-Hf isotopic and trace element concentration data set, combined with quantitative phase analysis by XRD Rietveld refinement, for a wide range of mafic to ultramafic rock reference materials analyzed at the Pacific Centre for Isotopic and Geochemical Research, University of British Columbia. The samples include a pyroxenite (NIM-P), five basalts (BHVO-2, BIR-1a, JB-3, BE-N, GSR-3), a diabase (W-2), a dolerite (DNC-1), a norite (NIM-N), and an anorthosite (AN-G); results from a leucogabbro (Stillwater) are also reported. Individual isotopic ratios determined by MC-ICP-MS and TIMS, and multielement analyses by HR-ICP-MS are reported with 4-12 complete analytical duplicates for each sample. The basaltic reference materials have coherent Sr and Nd isotopic ratios with external precision below 50 ppm (2SD) and below 100 ppm for Hf isotopes (except BIR-1a). For Pb isotopic reproducibility, several of the basalts (JB-3, BHVO-2) require acid leaching prior to dissolution. The plutonic reference materials also have coherent Sr and Nd isotopic ratios (<50 ppm), however, obtaining good reproducibility for Pb and Hf isotopic ratios is more challenging for NIM-P, NIM-N, and AN-G due to a variety of factors, including postcrystallization Pb mobility and the presence of accessory zircon. Collectively, these results form a comprehensive new database that can be used by the geochemical community for evaluating the radiogenic isotope and trace element compositions of volcanic and plutonic mafic-ultramafic rocks.

  13. Unraveling the sources of ground level ozone in the Intermountain Western United States using Pb isotopes.

    PubMed

    Christensen, John N; Weiss-Penzias, Peter; Fine, Rebekka; McDade, Charles E; Trzepla, Krystyna; Brown, Shaun T; Gustin, Mae Sexauer

    2015-10-15

    Ozone as an atmospheric pollutant is largely produced by anthropogenic precursors and can significantly impact human and ecosystem health, and climate. The U.S. Environmental Protection Agency has recently proposed lowering the ozone standard from 75 ppbv (MDA8 = Maximum Daily 8-Hour Average) to between 65 and 70 ppbv. This will result in remote areas of the Intermountain West that includes many U.S. National Parks being out of compliance, despite a lack of significant local sources. We used Pb isotope fingerprinting and back-trajectory analysis to distinguish sources of imported ozone to Great Basin National Park in eastern Nevada. During discrete Chinese Pb events (> 1.1 ng/m(3) & > 80% Asian Pb) trans-Pacific transported ozone was 5 ± 5.5 ppbv above 19 year averages for those dates. In contrast, concentrations during regional transport from the Los Angeles and Las Vegas areas were 15 ± 2 ppbv above the long-term averages, and those characterized by high-altitude transport 3 days prior to sampling were 19 ± 4ppbv above. However, over the study period the contribution of trans-Pacific transported ozone increased at a rate of 0.8 ± 0.3 ppbv/year, suggesting that Asian inputs will exceed regional and high altitude sources by 2015-2020. All of these sources will impact regulatory compliance with a new ozone standard, given increasing global background. PMID:25934382

  14. Nitrogen isotope geochemistry of organic matter and minerals during diagenesis and hydrocarbon migration

    NASA Astrophysics Data System (ADS)

    Williams, Lynda B.; Ferrell, Ray E., Jr.; Hutcheon, Ian; Bakel, Allen J.; Walsh, Maud M.; Krouse, H. Roy

    1995-02-01

    The magnitude of isotopic variations between organic and inorganic nitrogen was examined in samples from three stacked hydrocarbon reservoirs in the Fordoche Field (Louisiana Gulf Coast Basin, USA). Measurements were made of δ 15N in kerogen, bitumen, oil, formation water, and fixed-NH 4 extracted from mudstones, nonproductive sandstones, and productive sandstones. Nitrogen isotope fractionation occurs because 14N is released preferentially to 15N from organic molecules during thermal maturation. Released 14N goes into solution, or may be adsorbed by minerals, leaving crude oil enriched in 15N. Diagenetic clay minerals (e.g., illite) commonly form in the temperature range of hydrocarbon generation, and NH 4+ may be fixed in clay interlayers with an isotopic ratio similar to that of the migrating fluids. Results indicate that the influence of organic matter on mineral δ 15N depends on the timing of authigenic mineral formation relative to fluid migration. The average δ 15N of kerogen (3.2 ± 0.3‰) and fixed-NH 4 from mudstones (3.0 ± 1.4) is similar, while bitumen increases from +3.5 to +5.1‰ with depth. In deep reservoir sandstones (>100°C), the δ 15N of crude oil averages +5.2 ± 0.4‰, similar to the δ 15N of bitumen in the proposed source rocks. Formation waters are 14N-enriched with an average δ 15N of -2.2 ± 2.6‰. Fixed-NH 4 δ 15N values lie between that of the oil and water. The average δ 15N of fixed-NH 4 is 3.0 ± 1.2‰ in productive sandstones, and 0.2 ± 2.4‰ innonproductive sandstones. In the shallower reservoir sandstones (<90°C) fixed-NH 4 is apparently not influenced by the presently associated fluids. Productive and nonproductive sandstones have distinctly low average δ 15N values (-1.2 ± 0.8‰), yet crude oil (+11.1 ± 0.3‰) and water (+3.8 ± 0.1‰) have been 15N-enriched by ˜6‰ relative to the deeper reservoirs. This suggests that the present fluids migrated into the reservoir after authigenic illite had formed

  15. Boron, Sr, O, and H isotope geochemistry of groundwaters from Mt. Etna (Sicily) -- Hydrologic implications

    SciTech Connect

    Pennisi, M.; Leeman, W.P.; Tonarini, S.; Pennisi, A.; Nabelek, P.

    2000-03-01

    Combined B, O, H, and Sr isotopic studies of groundwaters from Mt. Etna provide new constraints on their origin and the consequences of fluid-rock interaction within this hydrologic system. Variations in {delta}{sup 18}O ({minus}9.7 to {minus}7.2%) and {delta}D ({minus}62 to {minus}23%) mainly lie along the regional meteoric water line and suggest that most waters originated as local precipitation. However, small shifts in {delta}{sup 18}O, and variable {sup 87}Sr/{sup 86}Sr (0.70355 to 0.70879) and {delta}{sup 11}B ({minus}5.2 to 25.8%) indicate that subsequent interactions occurred between the fluids and local rocks. High B/Cl ratios in all samples seemingly preclude direct involvement of seawater in the hydrologic system despite the proximity to the coast and, in some samples, elevated {sup 87}Sr/{sup 86}Sr and {delta}{sup 11}B. Two general end-member water types are recognized on the basis of their chemistry. These apparently are produced by interactions of local meteoric waters with the dominant reservoir rocks--either basaltic lavas of Etna or the underlying sediments, respectively; high {delta}{sup 11}B in the sediment-hosted end-member points to a significant marine carbonate contribution. Subsequent mixing between these or similar end-members produced a range of intermediate composition groundwaters. Certain anomalous water compositions require the presence locally of a distinct component with high B and moderate {delta}{sup 11}B (ca. 10%) but relatively low {sup 87}/Sr/{sup 86}Sr; an anthropogenic source for this component is plausible. One unusual sample has B and Sr isotopic compositions similar to the other volcanic rock-hosted waters, but anomalously high Cl content that likely reflects local magmatic outgassing near this sampling locality. In general, this study indicates that groundwater B and Sr isotopic compositions are rock-dominated; these data provide useful constraints on the origin and evolution of groundwaters.

  16. Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

    USGS Publications Warehouse

    Komor, S.C.; Valley, J.W.

    1990-01-01

    The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ??18O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5??? at 5760 m depth. In contrast, feldspar ??18O values decrease with depth from near 10 at the surface to 7.1??? at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ??18O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ??18O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100-300?? C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500?? C) exchange between alkali feldspar and fluids. The high

  17. The Estherville mesosiderite: U-Pb, Rb-Sr, and Sm-Nd isotopic study of a polymict breccia

    SciTech Connect

    Brouxel, M.; Tatsumoto, M. )

    1991-04-01

    A systematic U-Pb, Sm-Nd, and Rb-Sr isotopic study shows that the Estherville mesosiderite was formed between 4.56 and 4.43 Ga. Observed isotopic heterogeneity is in agreement with multiple generations of meteoritic impacts described in other mesosiderites. At least part of the Estherville silicate fraction was formed early in solar system history as indicated by the Pb-Pb (4555 {plus minus} 35 Ma), U-Pb (4560 {plus minus} 31 Ma), Rb-Sr (4542 {plus minus} 203 Ma), and Sm-Nd (4533 {plus minus} 94 Ma) ages. Mesosiderites therefore present not only petrological but also geochronological similarities with eucrites. The Pb isotopic composition of the metal phase plots on the same isochron as the silicates, indicating formation and subsequent mixing with silicates early in the history of the solar system. This is consistent with previous observations indicating that iron was reduced during the silicate-magmatic stage, most likely a consequence of mixing with metal. In addition to these more-ancient portions of the Estherville breccia, other parts were formed later as suggested by the Pb-Pb (4422 {plus minus} 50 Ma) and U-Pb (4437 {plus minus} 11 Ma) ages observed in a second group of leaches and residues. This age is similar to some cumulate eucrite ages and may represent the formation of a second mesosiderite component. The Sm-Nd and the Rb-Sr ages obtained on Estherville show large errors that may be a consequence of the mixing between the 4.56 and 4.43 Ga endmembers. Estherville, like most mesosiderites, was affected by a major heating event around 3.5-3.7 Ga as shown by the Ar-Ar ages. This heating event partially disturbed the Rb-Sr isotopic system (Rb-Sr metamorphic ages range between 3.81 and 4.08 Ga).

  18. U-Pb Dating of Carbonates: A Complement to Clumped Isotope Analyses

    NASA Astrophysics Data System (ADS)

    Rasbury, T.; Suarez, M. B.

    2014-12-01

    Carbonates are ubiquitous in nature, forming in a variety of settings at the surface and through burial. The field and petrographic relationships of carbonate phases can often be linked to the depositional setting and burial path(s) that the sedimentary pile has experienced. Clumped isotopes are taking on an important role of testing the temperature of formation of the carbonates, and combined with other approaches such as fluid inclusion analyses offers tremendous potential for testing basin evolution models. However, while the relative ages of carbonates are often fairly easily elucidated, the absolute ages of the events recorded in carbonates are not. U-Pb dating of carbonates offers the best potential for constraining the ages. However, not all fluids have favorable U/Ca ratios. U-Pb dated groundwater carbonates from the Late Triassic New Haven Arkose give an age of 211 +/- 2 Ma, consistent with the known age of deposition. Late bright luminescent calcite from the same formation gives an age of 81+/-11 Ma, constraining the age (both primary and secondary) of carbonate formation. Clumped isotope analyses of primary carbonate phases show somewhat elevated temperatures between 50-60o C, some 30 degrees hotter than other estimates for this Triassic equatorial setting, and are more likely the result of re-ordering of 13C-18O bonds at depth. Apparently the primary calcite, appears to have preserved its depositional U-Pb systematics, however bond re-ordering or recrystallization of these carbonates appear to reflect values closer to thermal equilibrium with the last phase of carbonate formation (bright luminescent calcite, 81 ± 11 Ma). Further work on these samples will target these younger calcites to determine if this later calcite phase records similar temperatures.

  19. Methods for the separation of rhenium, osmium and molybdenum applicable to isotope geochemistry

    USGS Publications Warehouse

    Morgan, J.W.; Golightly, D.W.; Dorrzapf, A.F., Jr.

    1991-01-01

    Effective methods are described for the chemical separation of rhenium, osmium and molybdenum. The methods are based on distillation and anion-exchange chromatography, and have been the basis for rhenium-osmium isotope studies of ore deposits and meteorites. Successful anion-exchange separation of osmium requires both recognition and careful control of the osmium species in solution; thus, distillation of osmium tetroxide from a mixture of sulfuric acid and hydrogen peroxide is preferred to anion-exchange. Distribution coefficients measured for perrhenate in sulfuric acid media are sufficiently high (Kd > 500) for rhenium to be directly loaded onto an ion-exchange column from a distillation residue and subsequently eluted with nitric acid. Polymerization of molybdenum species during elution is prevented by use of a solution that is 1M in hydrochloric acid and 1M in sodium chloride. ?? 1991.

  20. Major, trace element and stable isotope geochemistry of synorogenic breccia bodies, Ellsworth Mountains, Antarctica

    USGS Publications Warehouse

    Craddock, J.P.; McGillion, M.S.; Webers, G.F.

    2007-01-01

    Cambrian carbonates in the Heritage Range of the Ellsworth Mountains, West Antarctica host a series of carbonate-rich breccia bodies that formed contemporaneously with the Permian Gondwanide orogen. The breccia bodies had a three-stage genesis, with the older breccias containing Cambrian limestone (and marble) clasts supported by calcite, whereas the younger breccias are nearly clast-free and composed entirely of matrix calcite. Breccia clasts, calcite matrix and detrital matrix samples were analyzed using x-ray fluorescence (major and trace elements), x-ray diffraction, and stable isotopes (C, O) and suggest that the breccias formed as part of a closed geochemical system, at considerable depth, within the Cambrian limestone host as the Ellsworth Mountains deformed into a fold-and-thrust belt along the margin of Gondwana

  1. Palynology and organic/isotope geochemistry of the Mae Moh Basin, Northern Thailand

    SciTech Connect

    Minh, L.V.; Abrajano, T.; Burden, E.; Winsor, L. ); Ratanasthien, B. )

    1994-07-01

    The Mae Moh basin is one of several Tertiary intermontane basins in northern Thailand, whose evolution has been linked to the collision of the Indian plate with the Eurasian plate since the early Eocene. As in most of these basins, lacustrine/swamp sedimentation in the Mae Moh basin can be broadly divided into an Oligocene to Miocene synrift sequence and a Miocene to Quarternary postrift sequence. The dominance of swamp flora recognized from spore and pollen assemblages (e.g., Polypodiidites usmensis, Verrucatosporites, Cyrtostachys), as well as the abundance of macrophytes and woody debris, indicate overwhelming hot and humid swamp conditions, with lake development restricted to relatively small areas. The distribution of alkanes and their compound-specific carbon isotope compositions are used to further show climatic variations affecting the lake/swamp ecology during the deposition of the synrift sequence.

  2. Compilation of gas geochemistry and isotopic analyses from The Geysers geothermal field: 1978-1991

    USGS Publications Warehouse

    Lowenstern, Jacob B.; Janik, Cathy; Fahlquist, Lynne; Johnson, Linda S.

    1999-01-01

    We present 45 chemical and isotopic analyses from well discharges at The Geysers geothermal field and summarize the most notable geochemical trends. H2 and H2S concentrations are highest in the Southeast Geysers, where steam samples have δD and δ18O values that reflect replenishment by meteoric water. In the Northwest Geysers, samples are enriched in gas/steam, CO2, CH4, and N2/Ar relative to the rest of the field, and contain steam that is elevated in δD and δ18O, most likely due to substantial contributions from Franciscan-derived fluids. The δ13C of CO2, trends in CH4 vs. N2, and abundance of NH3 indicate that the bulk of the non-condensable gases are derived from thermal breakdown of organic materials in Franciscan meta-sediments.

  3. Sr-Nd isotope geochemistry and petrogenesis of the Chah-Shaljami granitoids (Lut Block, Eastern Iran)

    NASA Astrophysics Data System (ADS)

    Arjmandzadeh, R.; Karimpour, M. H.; Mazaheri, S. A.; Santos, J. F.; Medina, J. M.; Homam, S. M.

    2011-05-01

    Chah-Shaljami porphyritic granitoids belong to the Lut Block volcanic-plutonic belt of central eastern Iran. These intrusive rocks are mostly quartz monzonites, granodiorites and diorites. Geochemical evidence reveals that they are co-genetic and that they have features typical of high-K calc-alkaline to shoshonitic rocks from volcanic arc setting. Primitive mantle-normalized trace element spider diagrams display strong enrichment in LILE, such as Rb, Ba, and Cs, and depletion in some HFSE, e.g. Nb, Ti, Y and HREE. Chondrite-normalized plots show a very marked REE fractionation, with significant LREE enrichment (23 ⩾ La N/Yb N ⩾ 14) and the lack of Eu anomaly. Sr/Y and La/Yb ratios of Chah-shaljami intrusives are respectively 20-67 and 21-34, which reveals that, despite their K-rich composition, these rocks also, have some adakitic affinity. Plots on the Sr/Y-Y and La/Yb-Yb diagrams show that the Chah-Shaljami intrusives may be subdivided into two distinct classes. A Rb-Sr age of 33.5 ± 1 Ma, mainly dependent on the Sr isotopic composition of biotite, was obtained in a quartz monzonite sample. Taking into account that this sample was almost unaffected by hydrothermal and meteoric alteration and that cooling was probably fast, the 33-34 Ma date is interpreted as the intrusion age. With the exception of two samples, initial 87Sr/ 86Sr ratios and C̵Nd values are clustered in the restricted ranges of 0.70470-0.70506 and +1.9-+2.7, which fits into a supra-subduction mantle wedge source for the parental melts and indicates that, in general, crustal contribution for magma diversification was not relevant; however, one sample shows higher 87Sr/ 86Sr and lower C̵Nd, revealing that, occasionally, crustal rock assimilation also contributed to geochemical variation; one other sample, strongly affected by hydrothermal alteration, departs from the main group only by higher 87Sr/ 86Sr, suggesting that its alteration involved crustal fluids. Sr and Nd isotope compositions

  4. The geochemistry of uranium and thorium isotopes in the Western Desert of Egypt

    SciTech Connect

    Dabous, A.A.

    1994-11-01

    The concentrations of {sup 238}U, {sup 234}U, {sup 232}Th, and {sup 228}Th have been measured in the groundwaters of the Bahariya and Farafra oases of the Western Desert of Egypt. These waters are characterized by normal amounts of U, but unusually high concentrations of Th. The pattern of variation of the parent isotopes, {sup 238}U and {sup 232}Th, as well as the daughter isotopes, {sup 234}U, {sup 230}Th, and {sup 228}Th, is systematic within and between the two oases. From the unusually consistent distribution of the {sup 234}U/{sup 238}U activity ratios one can conclude that the samples from both oases are representative of a two-component mixing system. One component, characterized by low U content and a high {sup 234}U/{sup 238}U activity ratio, is typical of deep artesian systems and probably represents flowthrough water derived from the Nubian highlands to the south. The second component is characterized by a greater U concentration and a low activity ratio. This signature is hypothesized as being derived by leaching of downward infiltrating water during pluvial times. The source of the U may be the uraniferous phosphate strata that overly the sandstone aquifer in both oasis areas. Higher Th values are associated with the artesian flow component of the mixing system and suggests that Th-bearing minerals may be abundant in the Nubian sandstone aquifer. The distribution of {sup 230}Th and {sup 228}Th in the water samples supports this interpretation.

  5. Radium isotope geochemistry of thermal waters, Yellowstone National Park, Wyoming, USA

    SciTech Connect

    Sturchio, N.C.; Bohlke, J.K.; Markun, F.J. )

    1993-03-01

    Radium isotope activities ([sup 226]Ra, [sup 228]Ra, and [sup 224]Ra), chemical compositions, and sulfur isotope ratios in sulfate were determined for water samples from thermal areas in Yellowstone National Park, Wyoming. Activities of [sup 226]Ra in these waters range from <0.2 to 37.9 dpm/kg. Activity ratios of [sup 228]Ra/[sup 226]Ra range from 0.26 to 14.2, and those of [sup 224]Ra/[sup 228]Ra range from 0.73 to 3.1. Radium concentrations are inversely correlated with aquifer equilibration temperatures (estimated from dissolved silica concentrations), while [Ra/Ba][sub aq] and [sup 228]Ra/[sup 226]Ra activity ratios depend upon U/Ba and Th/U ratios in aquifer rocks. Major controls on Ra concentration in Yellowstone thermal waters are inferred to be (1) barite saturation (at Norris Geyser Basin, Mammoth Hot Springs, and other northern areas) and (2) zeolite-water ion exchange (at Upper Geyser Basin). The data are consistent with a model in which (1) radium and barium are supplied to water by bulk dissolution of aquifer rock, and (2) chemical equilibration of water with rock is rapid relative to the 1602 year half-life of [sup 226]Ra. The [sup 228]Ra/[sup 226]Ra activity ratios of the waters may in some cases reflect surface enrichments of [sup 232]Th and/or may indicate that [alpha]-recoil input of [sup 228]Ra is rapid relative to water-rock chemical equilibration. Activity ratios of [sup 224]Ra/[sup 228]Ra indicate a nearly ubiquitous [sup 224]Ra excess that generally increases with decreasing pH. Near-surface ([le]100 m) thermal water flow velocities at Mammoth Hot Springs are estimated from [sup 224]Ra/[sup 228]Ra variation to be [ge]1 m h[sup [minus]1]. 73 refs., 4 figs., 4 tabs.

  6. New Results on the Palaeobiology of Bears on the Swabian Alb (Chronology, Isotopic Geochemistry and Palaeogenetics)

    NASA Astrophysics Data System (ADS)

    Muenzel, Susanne

    2010-05-01

    Paleogenetic investigations at three geographically close caves in the Ach Valley near Blaubeuren have revealed two different cave bear haplogroups. These two haplogroups correspond to Ursus spelaeus (haplogroup 1) and Ursus ingressus (haplogroup 4) (Rabeder & Hofreiter 2004, Die Höhle 55, 58-77). This genetic variability was first attested for Geißenklösterle and Sirgenstein cave, but the new genetic data attest them also for Hohle Fels. In all three caves Ursus ingressus replaced Ursus spelaeus around 28 000 B.P. The carbon and nitrogen isotopes of the two genetic types do not vary significantly, meaning that there is no dietary difference between them and Ursus spelaeus were in dietary competition with Ursus ingressus in the Ach valley. The radiocarbon dates suggested a sudden replacement (Hofreiter et al. 2007, Current Biology 17(4): R1-R3), which must have been accompanied by local extinction of the older cave bear, according to the dietary competition with the younger bear. The possible reasons for this replacement are not clear yet. Climatic changes are unlikely, since the faunal composition remains the same and the environmental data do not differ significantly. But we cannot exclude human impact on the cave bear population, since a cave bear vertebra with an embedded fragment of a flint projectile was recovered in the Gravettian layer AH IIcf dated to 27 830+150-140 B.P. and gives indisputable proof of the hunting of cave bears. Numerous cut marks proof an ongoing exploitation of this species. In this context, new radiocarbon dates and isotopic results on cave bears and coeval brown bears will help us to refine the possible scenarios of this complex evolutionary and ecological process. These results will be used to test hypotheses of competitive exclusion between the different bear species. This study will exemplify how combining evidence from different approaches can provide invaluable clues about palaeobiology of late Pleistocene large mammals such as

  7. The plumbotectonic model for Pb isotopic systematics among major terrestrial reservoirs-A case for bi-directional transport

    USGS Publications Warehouse

    Zartman, R.E.; Haines, S.M.

    1988-01-01

    Version IV of plumbotectonics expands and refines the original model of Doe and Zartman (1979) and Zartman and Doe (1981) for explaining Pb (Sr, and Nd) isotopic systematics among major terrestrial reservoirs. A case for bi-directional transport among reservoirs is based on the observed isotopic compositions for different tectonic settings, and finds a rationale in the kinetics of plate tectonics. Chemical fractionation and radioactive decay create isotopic differences during periods of isolation of one reservoir from another, whereas dynamic processes allowing mixing between reservoirs tend to reduce these differences. Observed isotopic characteristics reflect a balance between these opposing tendencies and provide constraints on the extent and timing of fractionation and mixing processes. Plumbotectonics does not require interaction with a lower mantle or core reservoir over most of the Earth's lifetime, and, in fact, achieves a material balance consistent with no such exchange of material. Important evidence of the amount and timing of crustal recycling, and of the residence times of mantle heterogeneities lies in the coupled 207Pb 204Pb-206 Pb 204Pb systematics. We believe that examination of the published data base fully supports our contention of significant bi-directional transport of material among terrestrial reservoirs. Plumbotectonics allows us to explore many aspects of reservoir interaction, and to identify parameters that provide meaningful constraints on mantle-crust differentiation. We put forth a compromise fit to many of the model variables in version IV, which can serve as a reference for future work. ?? 1988.

  8. Zircon U-Pb ages, geochemical and Sr-Nd-Pb-Hf isotopic constraints on petrogenesis of the Tarom-Olya pluton, Alborz magmatic belt, NW Iran

    NASA Astrophysics Data System (ADS)

    Nabatian, Ghasem; Jiang, Shao-Yong; Honarmand, Maryam; Neubauer, Franz

    2016-02-01

    A petrological, geochemical and Sr-Nd-Pb isotopic study was carried out on the Tarom-Olya pluton, Iran, in the central part of the Alpine-Himalayan orogenic belt. The pluton is composed of diorite, monzonite, quartz-monzonite and monzogranite, which form part of the Western Alborz magmatic belt. LA-ICP-MS analyses of zircons yield ages from 35.7 ± 0.8 Ma to 37.7 ± 0.5 Ma, interpreted as the ages of crystallization of magmas. Rocks from the pluton have SiO2 contents ranging from 57.0 to 69.9 wt.%, high K2O + Na2O (5.5 to 10.3 wt.%) and K2O/Na2O ratio of 0.9 to 2.0. Geochemical discrimination criteria show I-type and shoshonitic features for the studied rocks. All investigated rocks are enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs), depleted in high-field strength elements (HFSEs), and show weak or insignificant Eu anomalies (Eu/Eu* = 0.57-1.02) in chondrite-normalized trace element patterns. The Tarom-Olya pluton samples also show depletions in Nb, Ta and Ti typical of subduction-related arc magmatic signatures. The samples have relatively low ISr (0.7047-0.7051) and positive εNd(36 Ma) (+ 0.39 to + 2.10) values. The Pb isotopic ratios show a (206Pb/204Pb)i ratio of 18.49-18.67, (207Pb/204Pb)i ratio of 15.58-15.61 and (208Pb/204Pb)i ratio of 38.33-38.77. The εHf(t) values of the Tarom-Olya pluton zircons vary from - 5.9 to + 8.4, with a peak at + 2 to + 4. The depleted mantle Hf model ages for the Tarom-Olya samples are close to 600 Ma. These isotope evidences indicate contribution of juvenile sources in petrogenesis of the Tarom-Olya pluton. Geochemical and isotopic data suggest that the parental magma of the Tarom-Olya pluton was mainly derived from a sub-continental lithospheric mantle source, which was metasomatized by fluids and melts from the subducted Neotethyan slab with a minor crustal contribution. Subsequent hot asthenospheric upwelling and lithospheric extension caused decompression melting in the final stage of

  9. Os, Sr, Nd, and Pb isotope systematics of southern African peridotite xenoliths - Implications for the chemical evolution of subcontinental mantle

    NASA Technical Reports Server (NTRS)

    Walker, R. J.; Carlson, R. W.; Shirey, S. B.; Boyd, F. R.

    1989-01-01

    Isotope analyses of Os, Sr, Nd, and Pb elements were caried out on twelve peridotite xenoliths from the Jagersfontein, Letseng-la-terae, Thaba Patsoa, Mothae, and Premier kimberlites of southern Africa, to investigate the timing and the nature of melt extraction from the continental lithosphere and its relation to the continent formation and stabilization. The distinct Os and Pb isotopic characteristics found in these samples suggested that both the low- and the high-temperature peridotites reside in an ancient stable lithospheric 'keel' to the craton that has been isolated from chemical exchange with the sublithospheric mantle for time periods in excess of 2 Ga.

  10. Exotic crustal components at the northern margin of the Bohemian Massif-Implications from Usbnd Thsbnd Pb and Hf isotopes of zircon from the Saxonian Granulite Massif

    NASA Astrophysics Data System (ADS)

    Sagawe, Anja; Gärtner, Andreas; Linnemann, Ulf; Hofmann, Mandy; Gerdes, Axel

    2016-06-01

    The Saxonian Granulite Massif is located at the northern margin of the Saxo-Thuringian Zone of the peri-Gondwana Bohemian Massif. Eight felsic and mafic granulites were studied with respect to their geochemistry and Usbnd Pb zircon geochronology. The felsic granulites are interpreted to be derived from continental crust of possible granitoid composition. An origin from depleted mantle sources with IAT to MORB composition can be assumed for the mafic granulites. The peak of metamorphism is thought to be timed at about 340 Ma, while several earlier metamorphic events are supposed to have occurred at about 355-360, 370-375, 405, and 450 Ma. They reveal a complex and polyphased geologic evolution of the Saxonian Granulite Massif. Protolith emplacement likely took place at c. 450 and 494 Ma. Hf isotopic data suggest Mesoproterozoic crustal ages at least for parts of the massif. As these crustal ages are exotic for the Bohemian Massif, their origin has to be searched elsewhere. Potential source areas could be Amazonia and Baltica, of which the latter is the one preferred. Furthermore, a composite architecture with at least two components-the felsic granulites with Mesoproterozoic crustal model ages, and the mafic granulites of potential island arc origin-is hypothesised. Their amalgamation to the recent appearance of the Saxonian Granulite Massif is likely bracketed between 375 and 340 Ma.

  11. Timing and tectonic setting of the Sijiaying banded iron deposit in the eastern Hebei province, North China Craton: Constraints from geochemistry and SIMS zircon U-Pb dating

    NASA Astrophysics Data System (ADS)

    Cui, Minli; Zhang, Lianchang; Wu, Huaying; Xu, Yingxia; Li, Wenjun

    2014-11-01

    The North China Craton (NCC), one of the oldest continental blocks in Asia, has a complicated evolutionary history with the age of the old crust up to 3.8 Ga and records the important geological events of the Earth. The Sijiaying BIF, the largest banded iron formation located in eastern Hebei province, in the east part of NCC, records an important thermo-tectonic event; Previous studies focused on the geological description, but the timing and tectonic setting have been unclear so far. The Sijiaying BIF is hosted in Neoarchean metamorphic rocks, which includes biotite-leptynite, hornblende plagioclase-gneiss and biotite plagioclase-gneiss. Using major element contents and ratios of the host rocks, the protoliths of the hornblende plagioclase-gneiss and biotite plagioclase-gneiss are shown to be dacite, whereas those of the biotite-leptynites are sedimentary rocks. Based on geology and geochemistry of the host rocks, we infer that the Sijiaying BIF is an Algoma type deposit. SIMS zircon U-Pb dating shows: igneous zircons from the biotite plagioclase-gneiss and hornblende plagioclase-gneiss have U-Pb ages of 2535 ± 8 Ma and 2543 ± 14 Ma, respectively; zircons from the biotite-leptynite have an age of 2537 ± 13 Ma. We infer that the ages of 2543-2535 Ma represent the time of the Sijiaying BIF. PAAS-normalized REY profiles of the ore samples are characterized by LREE depletion and HREE enrichment, positive La and Eu anomalies and an average Y/Ho weight ratio of 32, indicating a mixture of submarine hydrothermal fluids and deep seawater. REE data was combined with the δ18O analyzed by previous researcher of the ore from individual magnetite bands to infer that the Sijiaying BIF precipitated from hydrothermal fluids discharging on the sea floor. The hornblende plagioclase-gneiss and biotite plagioclase-gneiss that are enriched in LILE and LREE and depleted in high field strength elements (HFSE) Nb, Ta and Ti, have geochemical signatures that are similar to those of

  12. Ten years of elemental atmospheric metal fallout and Pb isotopic composition monitoring using lichens in northeastern France

    NASA Astrophysics Data System (ADS)

    Cloquet, Christophe; Estrade, Nicolas; Carignan, Jean

    2015-09-01

    We report on the chemical and Pb isotopic compositions of epiphytic lichens collected from small tree branches in the urban area of the city of Metz (NE France). Lichens were collected in five different years between 2001 and 2009. The data are first compared year to year in order to document any temporal change and trend in metal atmospheric fallout. The area studied was then subdivided into different zones on the basis of land use (urban, suburban, rural and industrial) in order to determine potential spatial gradients. The median concentrations and enrichment factors (EF, normalized to Al) of Pb and other metals (Cu, Zn, Cd, Ni, Cr, Hg, Fe) in lichens from the urban, suburban, and rural zones show no systematic variation between 2001 and 2008. However, the metal EFs show spatial variation and are generally highest in the urban area and lowest in the rural area. Lichens within the industrial zone (collected in 2009), which is dominated by steel industries, are richest in Al, Fe, Cr, Pb, and Zn. Although the Al concentration is high in these lichens, the EFs for the cited metals are several times higher than those measured in lichens from the other three zones. No significant differences were noted for Hg, Cd, Cu and or Ni. Pb isotopic compositions measured in lichens may be highly variable from year to year and from zone to zone. The variation is primarily interpreted to result from mixing between: (i) Pb added to gasoline (and recycled through re-emission of road dust in the atmosphere); (ii) regional industrial Pb from long-range transportation and/or mixed with urban Pb; and (iii) local industrial Pb. The median isotopic compositions of individual zones are distinct, suggesting variable mixing of these three sources. The annual variations show that 2001 was most affected by gasoline Pb, whereas 2003 and 2006 were more affected by the local steel industry.

  13. Sr-Nd-Pb isotope systematics of the Banda Arc, Indonesia: Combined subduction and assimilation of continental material

    NASA Astrophysics Data System (ADS)

    Vroon, P. Z.; van Bergen, M. J.; White, W. M.; Varekamp, J. C.

    1993-12-01

    We present Sr, Nd, and Pb isotope results and SiO2, Rb, Sr, Sm, Nd, U, Th, and Pb data for six active volcanoes and one extinct volcanic island distributed over the whole length of the Banda Arc. Rock types range from low-K tholeiitic in the NE to high-K calc-alkaline in the SW. The volcanoes in the NE have 'normal' arc signatures, whereas those in the SW have extreme values. Serua, situated in the central part, is the most anomalous volcano with regard to its Sr and Nd isotopic composition but not with regard to Pb isotopes. The inactive island of Romang in the SW overlaps the Serua trends. The volcanoes display variable within-suite ranges in Sr-87/Sr-86 and Nd-143/Nd-144. Large ranges (e.g., at Nila) are consistent with assimilation (10-20%) of carbonate-bearing sediments from the arc crust. Despite the evidence for assimilation, it cannot explain all of the Sr-Nd isotopic trends found, and Banda Arc magmas must have already obtained a 'continental' signature at depth before they reached the arc crust. Within-suit trends of Pb isotopes are virtually absent. We found an extreme range in the volcanics along the arc which coincide with a similar trend in sediments in front of the arc and consider this as strong evidence for the contribution of subducted continent-derived material to magma sources.

  14. Fluid inclusion and isotope geochemistry of the Yangla copper deposit, Yunnan, China

    NASA Astrophysics Data System (ADS)

    Yang, Xi-An; Liu, Jia-Jun; Yang, Long-Bo; Han, Si-Yu; Sun, Xiao-Ming; Wang, Huan

    2014-04-01

    The Yangla copper deposit, with Cu reserves of 1.2 Mt, is located between a series of thrust faults in the Jinshajiang-Lancangjiang-Nujiang region, Yunnan, China, and has been mined since 2007. Fluid inclusion trapping conditions ranged from 1.32 to 2.10 kbar at 373-409 °C. Laser Raman spectroscopy confirms that the vapour phase in these inclusions consists of CO2, CH4, N2 and H2O. The gas phases in the inclusions are H2O and CO2, with minor amounts of N2, O2, CO, CH4, C2H2, C2H4, and C2H6. Within the liquid phase, the main cations are Ca2+ and Na+ while the main anions are SO4 2- and Cl-. The oxygen and hydrogen isotope compositions of the ore-forming fluids (-3.05‰ ≤ δ18OH2O ≤ 2.5‰; -100‰ ≤ δD ≤ -120‰) indicate that they were derived from magma and evolved by mixing with local meteoric water. The δ34S values of sulfides range from -4.20‰ to 1.85‰(average on -0.85‰), supporting a magmatic origin. Five molybdenite samples taken from the copper deposit yield a well-constrained 187Re-187Os isochron age of 232.8 ± 2.4 Ma. Given that the Yangla granodiorite formed between 235.6 ± 1.2 Ma and 234.1 ± 1.2 Ma, the Cu metallogenesis is slightly younger than the crystallization age of the parent magma. A tectonic model that combines hydrothermal fluid flow and isotope compositions is proposed to explain the formation of the Yangla copper deposit. At first, westward subduction of the Jinshajiang Oceanic Plate in the Early Permian resulted in the development of a series of thrust faults. This was accompanied by fractional melting beneath the overriding plate, triggering magma ascent and extensive volcanism. The thrust faults, which were then placed under tension during a change in tectonic mode from compression to extension in the Late Triassic, formed favorable pathways for the magmatic ore-forming fluids. These fluids precipitated copper-sulfides to form the Yangla deposit.

  15. Use of New 1013 Ohm Current Amplifiers in U and Pb Isotope Ratio Analysis by TIMS

    NASA Astrophysics Data System (ADS)

    Bouman, C.; Trinquier, A.; Lloyd, N. S.; Schwieters, J. B.

    2014-12-01

    Faraday cups can potentially be improved by a factor of 10 too. This presentation will focus on the analysis of small Pb and U using TIMS, for geochronology and nuclear forensics. In our setup, all U and Pb isotopes are measured simultaneously on Faraday cups, except 204Pb which is collected on the SEM since the 204Pb is the least abundant and required for common lead correction.

  16. Ion microprobe U-Pb dating and strontium isotope analysis of biogenic apatite

    NASA Astrophysics Data System (ADS)

    Sano, Y.; Toyoshima, K.; Takahata, N.; Shirai, K.

    2012-12-01

    Conodonts are micro-fossils chemically composed of apatite which occurred in the body of one animal. They are guide fossils to show formation ages of sedimentary sequences with the highest resolution [1] and good samples to verify the dating method. We developed the ion microprobe U-Pb dating of apatite [2] and applied the method to a Carboniferous conodont [3] by using a SHRIMP II installed at Department of Earth and Planetary Sciences, Hiroshima University. Recently we have developed the NanoSIMS U-Pb dating method and successfully measured the formation ages of monazite [4] and zircon [5] at Atmosphere and Ocean Research Institute, University of Tokyo. In this work we carried out the NanoSIMS U-Pb dating of biogenic apatite such as conodont. Since the spot size of NanoSIMS is smaller than SHRIMP II, it is easier to have multi-spots on the single fragment of biogenic apatite. Based on the isochron method of U-Pb system, we have calculated the formation ages. They are consistent with those in literature. In order to study the chemical evolution of ocean during the past 600 Million years, strontium isotopes (87Sr/86Sr) of fossil marine carbonate such as coral skeletons and foraminifera tests were measured and compiled [6]. However they are not robust when the age is older than 500Ma, partly due to post-depositional histories. Apatite is more stable and more resistant to the alteration than carbonate [7]. Recently we have developed the method of NanoSIMS strontium isotopic analysis of a fish otolith, which composed of aragonite [8]. In this work we carried out the strontium isotopic analysis of biogenic apatite. The advantage of the ion microprobe technique over the TIMS (thermal ionization mass spectrometer) and MC-ICP-MS (multi-collector inductively coupled argon plasma mass spectrometer) method is preservation of the important textural context and to provide an opportunity for other simultaneous analytical work with high spatial resolution. This is the case for

  17. Atmospheric Pb deposition since the Industrial Revolution recorded by five Swiss peat profiles: Enrichment factors, fluxes, isotopic composition, and sources

    SciTech Connect

    Weiss, D.; Shotyk, W.; Kramers, J.D.; Appleby, P.G.; Cheburkin, A.K.

    1999-05-01

    Atmospheric Pb deposition since the Industrial Revolution was studied in western, central, and southern Switzerland using five rural peat bogs. Similar temporal patterns were found in western and central Switzerland, with two distinct periods of Pb enrichment relative to the natural background: between 1880 and 1920 with enrichments ranging from 40 to 80 times, and between 1960 and 1980 with enrichments ranging from 80 to 100 times. The fluxes also were generally elevated in those time periods: in western Switzerland between 1.16 and 1.55 {micro}g cm{sup {minus}2} y{sup {minus}1} during the second period. Between the Industrial Revolution and 1985, nonradiogenic Pb became increasingly important in all five cores because of the replacement of coal by oil after ca. 1920, the use of Australian Pb in industry, and the extensive combustion of leaded gasoline after 1950. The introduction of unleaded gasoline in 1985 had a pronounced effect on the Pb deposition in all five cores. Enrichments dropped sharply, and the isotopic ratios reverted back toward natural values. The cores from western and central Switzerland showed very similar isotopic trends throughout the time period studied, implying that these sites were influenced contemporaneously by similar pollution sources and atmospheric pathways. Southern Switzerland revealed a different record with respect to the Pb pollution: it was dominated by a single massive Pb enrichment dated between 1930 and 1950.

  18. Quantifying the signature of the industrial revolution from Pb and Cd isotopes in the Susquehanna Shale Hills Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    Ma, L.; Herndon, E.; Jin, L.; Sanchez, D.; Brantley, S. L.

    2013-12-01

    Anthropogenic forcings have dominated metal cycling in many environments. During the period of the industrial revolution, mining and smelting of ores and combustion of fossil fuels released non-negligible amounts of potentially toxic metals such as Pb, Cd, Mn, and Zn into the environment. The extent and fate of these metal depositions in soils during that period however, have not been adequately evaluated. Here, we combine Pb isotopes with Cd isotopes to trace the sources of metal pollutants in a small temperate watershed (Shale Hills) in Pennsylvania. Previous work has shown that Mn additions to soils in central PA was caused by early iron production, as well as coal burning and steel making upwind. Comparison of the Pb and Cd concentrations in the bedrock and soils from this watershed show that Pb and Cd in soils at Shale Hills are best characterized by addition profiles, consistent with atmospheric additions. Three soil profiles at Shale Hills on the same hillslope have very similar anthropogenic Pb inventories. Pb isotope results further reveal that the extensive use of local coals during iron production in early 19th century in Pennsylvania is most likely the anthropogenic Pb source for the surface soils at Shale Hills. Pb concentrations and isotope ratios were used to calculate mass balance and diffusive transport models in soil profiles. The model results further reveal that during the 1850s to 1920s, coal burning in local iron blasting furnaces significantly increased the Pb deposition rates to 8-14 μg cm-2 yr-1, even more than modern Pb deposition rates derived from the use of leaded gasoline in the 1940s to 1980s. Furthermore, Cd has a low boiling point (~760 °C) and easily evaporates and condenses. The evaporation and condensation processes could generate systematic mass-dependent isotope fractionation between Cd in coal burning products and the naturally occurring Cd in the sulfide minerals of coals. This fractionation indicates that Cd isotopes can

  19. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico

    NASA Technical Reports Server (NTRS)

    Des Marais, D. J.; Stallard, M. L.; Nehring, N. L.; Truesdell, A. H.

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330 degrees C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher delta 13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400 degrees C) and higher (600 degrees C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments.

  20. Oxygen isotope geochemistry of the silicic volcanic rocks of the Etendeka-Parana province: Source constraints

    SciTech Connect

    Harris, C.; Milner, S.C.; Armstrong, R.A. ); Whittingham, A.M. )

    1990-11-01

    Oxygen isotope ratios of pyroxene phenocrysts in the silicic volcanic rocks from the Cretaceous Etendeka-Parana flood basalt province (Namibia, South America) are believed to reflect the {delta}{sup 18}O values of the original magmas. The authors recognize a high {delta}{sup 18}O value type ({delta}{sup 18}O pyroxene {approximately} +10{per thousand}) found in the south of both regions, and a low {delta}{sup 18}O value type ({delta}{sup 18}O pyroxene {approximately} +6.5{per thousand}) found in the north. Other differences between thee two rhyolite types include higher concentrations of incompatible elements and lower initial {sup 87}Sr/{sup 86}Sr ratios in the low {delta}{sup 18}O value type. The authors suggest that the regional distribution of rhyolite types reflects differences in source composition, which can best be explained if the sources are lower crustal, Late Proterozoic mobile belt material (high {delta}{sup 18}O) and Archean lower crust (low {delta}{sup 18}O).

  1. Isotopic geochemistry of a mid-Proterozoic evaporite basin: Balmat, New York

    USGS Publications Warehouse

    Whelan, J.F.; Rye, R.O.; De Lorraine, W.; Ohmoto, H.

    1990-01-01

    Lenses of Proterozoic meta-evaporitic anhydrite as much as 60 m thick occur in a 1150 to 1300 Ma Grenville Series marble sequence near Balmat, New York. ??34Sanhy values in the oldest lens average 8.2 permil; progressively younger lenses average 19.6, 27.2, 26.7, and 19.1 permil. The thickest and isotopically heaviest lens displays coincident upsection increases in ??34Sanhy (24.1-30.2 permil) and ??18Oanhy (19.8-22.5 permil) values. These increases and the overall 34S enrichment of the anhydrite indicate that anhydrite precipitation was concurrent with large-scale bacterial sulfate reduction in the depositional basin. The arid climate and high evaporation rates implied by evaporite deposition result in 18O enrichment of the basin waters and the carbonates precipitated from them. The evidence of arid climate and the variability and 34S-enrichment of the anhydrite imply that the Balmat environment was a closed or restricted basin in which evaporation and bacterial sulfate reduction combined to produce a 34S-enriched, sulfate-rich brine. -from Authors

  2. Strontium isotope geochemistry of soil and playa deposits near Yucca Mountain, Nevada

    SciTech Connect

    Marshall, B.D.; Mahan, S.A.

    1994-12-31

    The isotopic composition of strontium contained in the carbonate fractions of soils provides an excellent tracer which can be used to test models for their origin. This paper reports data on surface coatings and cements, eolian sediments, playas and alluvial fan soils which help to constrain a model for formation of the extensive calcretes and fault infilling in the Yucca Mountain region. The playas contain carbonate with a wide range of strontium compositions; further work will be required to fully understand their possible contributions to the pedogenic carbonate system. Soils from an alluvial fan to the west of Yucca Mountain show that only small amounts of strontium are derived from weathering of silicate detritus. However, calcretes from a fan draining a carbonate terrane have strontium compositions dominated locally by the limestone strontium component. Although much evidence points to an eolian source for at least some of the strontium in the pedogenic carbonates near Yucca Mountain, an additional component or past variation of strontium composition in the eolian source is required to model the pedogenic carbonate system.

  3. Isotope geochemistry and modelling of the multi-aquifer system in the eastern part of Lithuania

    NASA Astrophysics Data System (ADS)

    Mokrik, Robert; Juodkazis, Vytautas; Štuopis, Anicetas; Mažeika, Jonas

    2014-06-01

    A steady-state groundwater flow model of three Quaternary intertill aquifers in the eastern part of Lithuania has been compiled. The distinction of separate modelled layers is based on hydraulic and isotope-hydrochemistry data criteria. 3H data were used to estimate the corrected groundwater age and were coupled with a groundwater-flow-dynamics model of the Quaternary aquifer system along a cross-section flow pathway from the Baltic Upland recharge area in eastern Lithuania towards the discharge area in the lowlands near the city of Kaunas in central Lithuania. The bicarbonate content in groundwater (214-462 mg/l) increases downgradient towards the lowland area. The other major constituents and total dissolved solids (TDS) have a trend analogous to the bicarbonate. The 14C activity of dissolved inorganic carbon (DIC) in the groundwater ranges from 41.4 to 85.7 pMC. With aquifer-system depth, active precipitation of aqueous solution takes place by dissolving minerals of calcite and dolomite and leakage of "old" groundwater from lower aquifers; the process is also traced by lower 14C and 3H activities and by more positive δ18O values in lowland areas.

  4. Geochemistry of CI chondrites: Major and trace elements, and Cu and Zn Isotopes

    NASA Astrophysics Data System (ADS)

    Barrat, J. A.; Zanda, B.; Moynier, F.; Bollinger, C.; Liorzou, C.; Bayon, G.

    2012-04-01

    In order to check the heterogeneity of the CI chondrites and determine the average composition of this group of meteorites, we analyzed a series of six large chips (weighing between 0.6 and 1.2 g) of Orgueil prepared from five different stones. In addition, one sample from each of Ivuna and Alais was analyzed. Although the sizes of the chips used in this study were “large”, our results show evidence for minor chemical heterogeneity in Orgueil, particularly for alkali elements and U. After removal of one outlier sample, the spread of the results is considerably reduced. For most of the 46 elements analyzed in this study, the average composition calculated for Orgueil is in very good agreement with previous CI estimates. This average, obtained with a “large” mass of samples, is analytically homogeneous and is suitable for normalization purposes. Finally, the Cu and Zn isotopic ratios are homogeneously distributed within the CI parent body with a spread of less than 100 ppm per atomic mass unit (amu).

  5. Carbon isotope geochemistry of hydrocarbons in the Cerro Prieto geothermal field, Baja California Norte, Mexico

    USGS Publications Warehouse

    Des Marais, D.J.; Stallard, M.L.; Nehring, N.L.; Truesdell, A.H.

    1988-01-01

    Hydrocarbon abundances and stable-isotopic compositions were measured in wells M5, M26, M35 and M102, which represent a range of depths (1270-2000 m) and temperatures (275-330??C) in the field. In order to simulate the production of the geothermal hydrocarbons, gases were collected from the pyrolysis of lignite in the laboratory. This lignite was obtained from a well which sampled rock strata which are identical to those occurring in the field, but which have experienced much lower subsurface temperatures. In both the well and the laboratory observations, high-temperature environments favored higher relative concentrations of methane, ethane and benzene and generally higher ??13C-values in the individual hydrocarbons. The best correlation between the laboratory and well data is obtained when laboratory-produced gases from experiments conducted at lower (400??C) and higher (600??C) temperatures are mixed. This improved correlation suggests that the wells are sampling hydrocarbons produced from a spectrum of depths and temperatures in the sediments. ?? 1988.

  6. Tracing magma mixing in granite genesis: in situ U-Pb dating and Hf-isotope analysis of zircons

    NASA Astrophysics Data System (ADS)

    Yang, Jin-Hui; Wu, Fu-Yuan; Wilde, Simon A.; Xie, Lie-Wen; Yang, Yue-Heng; Liu, Xiao-Ming

    2007-02-01

    In situ zircon U-Pb and Hf-isotopic data have been determined for mafic microgranular enclaves and host granitoids from the Early Cretaceous Gudaoling batholith in the Liaodong Peninsula, NE China, in order to constrain the sources and petrogenesis of granites. The zircon U-Pb age of the enclaves (120 ± 1 Ma) is identical to that of the host monzogranite (120 ± 1 Ma), establishing that the mafic and felsic magmas were coeval. The Hf isotopic composition of the enclaves [ ɛ Hf( t) = +4.5 to -6.2] is distinct from the host monzogranite [ ɛ Hf( t) = -15.1 to -25.4], indicating that both depleted mantle and crustal sources contributed to their origin. The depleted mantle component was not previously revealed by geochemical and Nd and Sr isotopic studies, showing that zircon Hf isotopic data can be a powerful geochemical tracer with the potential to provide unique petrogenetic information. Some wall-rock contamination is indicated by inherited zircons with considerably older U-Pb ages and low initial Hf isotopic compositions. Hafnium isotopic variations in Early Cretaceous zircons rule-out simple crystal-liquid fractionation or restite unmixing as the major genetic link between enclaves and host rocks. Instead, mixing of mantle-derived mafic magmas with crustal-derived felsic magmas, coupled with assimilation of wall rocks, is compatible with the data.

  7. Pb isotopic systematics in dolomitic rocks and their application to geochronology, provenance, and fluid-rock interaction

    SciTech Connect

    Hoff, J.A.

    1992-01-01

    In the Burlington-Keokuk Fms. (Miss.; Iowa-Illinois) the two major dolomite generations (dolomites I and II) exhibit a difference in initial [sup 206]Pb/[sup 204]Pb. This difference is used to constrain the sources of dolomitizing fluids. The composition of dolomite I is consistent with a marine source for Pb, which had an ultimate derivation from rocks uplifted along eastern North America during the Acadian Orogeny. In contrast, dolomite II has a significantly higher [sup 206]Pb/[sup 204]Pb character. Fluid-rock modeling is used to show that dolomite II could have formed by interaction of dolomite I with a saline fluid that had previously interacted with underlying sedimentary units. The Pb isotopic data indicates that this saline fluid did not derive its Pb from the more radiogenic (basement ) sources samples by the ore solutions that precipitated the MVT deposits in the region. Whole-rock dolostones from both the Burlington-Keokuk Fms. and the Wahoo Em. (Penn.; Prudhoe Bay, Alaska) are enriched in U (up to 67 ppm) relative to their constituent dolomites (<2 ppm). The enrichment of U, high [mu]'s ([sup 238]U/[sup 204]Pb), and low k's ([sup 232]Th/[sup 238]U) exhibited by wholerocks from both sequences suggest that U was mobile relative to Th and Pb during diagenesis. The timing of U-enrichment/mobility are constrained using Pb isotopic data. Despite high [mu]'s, Burlington-Keokuk Fms. dolostones are relatively unradiogenic. Calculations require U-enrichment to be relatively recent (i.e., <5 Ma). In contrast, dolostones from the Wahoo Fm. are relatively uranogenic and the spread of isotopic data yields Pb-Pb and U-Pb ages of [approximately]260 Ma. These ages are consistent with U enrichment concurrent with the development of a regional unconformity during the Permian. In both the Burlington-Keokuk and Wahoo Fms., U was probably transported as U(VI) complexes in near surface oxidized waters and enriched in local reducing zones adjacent to exposure surfaces.

  8. Variations in Pb concentrations and Pb-isotope ratios in soils collected along an east-west transect across the United States

    NASA Astrophysics Data System (ADS)

    Smith, David; Woodruff, Laurel; Reimann, Clemens; Flem, Belinda

    2014-05-01

    Soil A-horizon and C-horizon samples were collected along a 4000 km long transect cutting the USA from the west to the east coast. For purposes of site selection, the transect was divided into approximately 40-km segments. For each segment, a 1-km2 target area was selected at random. Soil A- and C-horizon samples were collected at a site within each target area that was most representative of the surrounding landscape. The samples were air-dried at ambient temperature, disaggregated, and sieved through a 2-mm stainless steel screen. The <2-mm material was crushed to <150 µm in a ceramic mill prior to chemical analysis. Lead was analyzed in all the A- and C-horizon samples by inductively coupled plasma-mass spectrometry following a 4-acid digestion. The complete dataset can be found in Smith et al., 2005. Pb-isotope ratio measurements were carried out on 159 soil A-horizon and 137 soil C-horizon samples on an inductively coupled sector field plasma mass spectrometer (SF-ICP-MS; ELEMENT 1, Finnigan MAT) in the laboratory of the Geological Survey of Norway (NGU), following a 7 N HNO3 digestion. Lead concentrations along the transect show (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for the central to eastern U.S. (Missouri to Maryland) when compared to the western U.S. (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern US (1.35 vs. 1.14). Lead isotopes show a distinct trend across the U.S., with the highest 206Pb/207Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g. California, median A-horizon: 1.195; C-horizon:1.216). The soil C-horizon samples show generally higher 206Pb/207Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The 206Pb/207Pb isotope ratios in the soil A horizon show a correlation with the total

  9. Fluid inclusions and isotopic characteristics of the Jiawula Pb-Zn-Ag deposit, Inner Mongolia, China

    NASA Astrophysics Data System (ADS)

    Li, Tiegang; Wu, Guang; Liu, Jun; Hu, Yanqing; Zhang, Yunfu; Luo, Dafeng; Mao, Zhihao

    2015-05-01

    , 207Pb/204Pb, and 208Pb/204Pb values of the ore minerals are in the ranges of 18.319-18.377, 15.499-15.596, and 38.094-38.314, respectively. Initial 87Sr/86Sr ratios of sulfides range from 0.712381 to 0.712770. The data for the S, Pb, and Sr isotopic systems indicate that the ore-forming metals and sulfur came from Mesozoic magma. The Jiawula deposit is a low-sulfidation epithermal Pb-Zn-Ag deposit, and fluid boiling is the dominant mechanism for the deposition of ore-forming materials.

  10. Apatite U-Pb thermochronolgy applied to complex geological settings - insights from geo/thermochronology and geochemistry

    NASA Astrophysics Data System (ADS)

    Paul, Andre; Spikings, Richard; Ulyanov, Alexey; Chew, David

    2016-04-01

    Application of high temperature (>350oC) thermochronology is limited to the U-Pb system of accessory minerals, such as apatite, under the assumption that radiogenic lead is lost to thermally activated volume diffusion into an infinite reservoir. Cochrane et al. (2015) have demonstrated a working example from the northern Andes of South America. Predictions from volume diffusion theory were compared with measured single grain U-Pb date correlated to shortest diffusion radius and in-situ profiles measured by LA-ICP-MS. Results from both techniques were found to be in agreement with predictions from thermally activated, volume diffusion. However, outliers from the ID-TIMS data suggested some complexity, as grains were found to be too young relative to their diffusion radius. Interaction of multiple processes can be responsible for the alteration of apatite U-Pb dates such as: (1) metamorphic (over)growth, (2) fluid aided alteration/recrystallization and (3) metamictization and fracturing of the grain. Further, predictions from volume diffusion rely on the input parameters: (a) diffusivity, (b) activation energy and (c) shortest diffusion radius. Diffusivity and activation energy are potentially influenced by the chemical composition and subsequent changes in crystal structure. Currently there is one value for diffusion parameter and activation energy established for (Durango) apatite (Cherniak et al., 1991). Correlation between diffusivity/activation energy and composition has not been established. We investigate if correlations exist between diffusivity/activation energy and composition by obtaining single grain apatite U-Pb date and chemical compostion and correlating these to their diffusion radius. We test the consistency of apatite closure temperature, by comparing the apatite U-Pb dates with lower temperature thermochronometers such as white mica and K-feldspar Ar/Ar and by petrographic observations. We test if chemical information can be a proxy to identify

  11. Paleoenvironment and the oxygen isotope geochemistry of ironstone of the Upper Ordovician Neda Formation, Wisconsin, USA

    SciTech Connect

    Yapp, C.J. )

    1993-05-01

    Geological evidence suggests that the goethite-dominated, oolitic ironstone of the Upper Ordovician Neda Formation in the north central United States was subaerially weathered in the Late Ordovician. The oxygen isotope ratios of the goethites in the [open quotes]hard[close quotes] and [open quotes]soft[close quotes] ores of this deposit are rather uniform with a [delta][sup 18]O value of about [minus]1.0[per thousand]. This [delta][sup 18]O value indicates the presence of meteoric water at the time of goethite formation and supports the idea that the goethites in hard and soft ores were formed in the same chemical weathering environment 440 million years ago. The [delta][sup 18]O value of accessory phosphate in some soft ore goethite-rich ooids was measured and combined with the goethite [delta][sup 18]O value to calculate a temperature of formation of about 23[degrees]C. The corresponding [delta][sup 18]O value of the ancient water was calculated to have been [minus]7.3[per thousand]. The relatively [open quotes]cool[close quotes] temperature calculated for the low-altitude, tropical site occupied by the Neda ironstone in the Late Ordovician is consistent with published evidence from fossil marine invertebrates for global cooling at that time. The [delta][sup 18]O value of [minus]7.3[per thousand] for the ancient tropical precipitation could indicate intense rainfall of a seasonal (perhaps monsoonal) character. 27 refs., 7 figs., 3 tabs.

  12. Isotopic and trace element geochemistry of lavas from the northern Mariana and southern volcano arcs

    SciTech Connect

    Lin Pingnan.

    1989-01-01

    Samples from submarine volcanoes and islands were analyzed for concentrations of K, Rb, Sr, Ba, REE, {sup 87}Sr/{sup 86}Sr and some selected samples for {sup 143}Nd/{sup 144}Nd. These data show strong variations along the arc, being relatively depleted in the tholeiitic and low-K calc-alkaline volcanoes of the Volcano Arc (VA) and the Mariana Central Island Province (CIP). All of the Mariana Northern Seamount Province (NSP) and Volcano arc Iwo Jima (IJ) are enriched in LIL and LREE, particularly in the northern half, where the lavas have strong shoshonitic affinities. Chemical characteristics of these lavas suggest source- or melt-mixing, with the NSP shoshonites being derived from a LIL- and LREE-enriched OIB-like source or melt, while Mariana CIP and Volcano Arc melts are derived from a depleted MORB-like mangle that has been recharged with K, Rb, Sr and Ba by hydrous fluids. Neodymium and strontium isotopic data reveal {var epsilon}{sub Nd} values ranging from +2.4 to +9.5 and {sup 87}Sr/{sup 86}Sr from 0.70320 to 0.70405. Anomalous trends of {sup 87}Sr/{sup 86}Sr and Ba/La found in some S-NSP lavas suggest that the addition of a sedimentary component may be superimposed on the two component mixing. The lavas from the Mariana and Volcano arcs, therefore, are interpreted as resulting from mixing of at least three components. The bulk of the lavas derive from an OIB-like mantle source (or melt) mixing with various proportions of a metasomatized depleted mantle source (or melt). These hybrid sources may be contaminated with minor amounts of subducted sediment and fluxed by multistage-f