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Sample records for picosecond infrared studies

  1. Laser-induced reactions in a deep UV resist system: Studied with picosecond infrared spectroscopy

    SciTech Connect

    Lippert, T.; Koskelo, A.; Stoutland, P.O.

    1995-12-31

    One of the most technologically important uses of organic photochemistry is in the imaging industry where radiation-sensitive organic monomers and polymers are used in photoresists. A widely-used class of compounds for imaging applications are diazoketones; these compounds undergo a photoinduced Wolff rearrangement to form a ketene intermediate which subsequently hydrolyses to a base-soluble, carboxylic acid. Another use of organic molecules in polymer matrices is for dopant induced ablation of polymers. As part of a program to develop diagnostics for laser driven reactions in polymer matrices, we have investigated the photoinduced decomposition of 5-diazo-2,2-dimethyl-1,3-dioxane-4,6-dione (5-diazo Meldrum`s acid, DM) in a PMMA matrix using picosecond infrared spectroscopy. In particular, irradiation of DM with a 60 ps 266 nm laser pulse results in immediate bleaching of the diazo infrared band ({nu} = 2172 cm{sup -1}). Similarly, a new band appears within our instrument response at 2161 cm{sup -1} (FWHM = 29 cm{sup -1}) and is stable to greater than 6 ns.; we assign this band to the ketene photoproduct of the Wolff rearrangement. Using deconvolution techniques we estimate a limit for its rate of formation of {tau} < 20 ps. The linear dependence of the absorbance change with the pump power (266 nm) even above the threshold of ablation suggest that material ejection take place after 6ns.

  2. Picosecond infrared study of intramolecular energy transfer in [(phen)(CO){sub 3}Re{sup I}(NC)Ru{sup II}(CN)(bpy){sub 2}]{sup +}

    SciTech Connect

    Dyer, R.B.; Peterson, K.A.; Gordon, K.C.; Woodruff, W.H.; Schoonover, J.R.; Meyer, T.J.; Bignozzi, C.A.

    1992-03-01

    The dynamics and mechanism of intramolecular energy transfer in [(phen)(CO){sub 3}Re{sup I}(NC)Ru{sup II}(CN)(bpy){sub 2}]+ following metal-to-ligand charge transfer excitation have been studied using picosecond infrared spectroscopy.

  3. Picosecond infrared study of intramolecular energy transfer in ((phen)(CO) sub 3 Re sup I (NC)Ru sup II (CN)(bpy) sub 2 ) sup +

    SciTech Connect

    Dyer, R.B.; Peterson, K.A.; Gordon, K.C.; Woodruff, W.H. ); Schoonover, J.R.; Meyer, T.J. . Dept. of Chemistry); Bignozzi, C.A. )

    1992-01-01

    The dynamics and mechanism of intramolecular energy transfer in ((phen)(CO){sub 3}Re{sup I}(NC)Ru{sup II}(CN)(bpy){sub 2})+ following metal-to-ligand charge transfer excitation have been studied using picosecond infrared spectroscopy.

  4. Picosecond melting of peptide nanotubes using an infrared laser: a nonequilibrium simulation study.

    PubMed

    Hoang Viet, Man; Truong, Phan Minh; Derreumaux, Philippe; Li, Mai Suan; Roland, Christopher; Sagui, Celeste; Nguyen, Phuong H

    2015-11-01

    Self-assembled functional peptide biomaterials are emerging with a wide range of envisioned applications in the field of nanotechnology. Currently, methods and tools have been developed to control and manipulate as well as to explore new properties of self-assembled structures. However, considerably fewer studies are being devoted to developing efficient methods to degrade or recycle such extremely stable biomaterials. With this in mind, here we suggest a theoretical framework, inspired by the recent developed mid-infrared free-electron laser pulse technology, to dissociate peptide nanotubes. Adopting a diphenylalanine channel as a prototypical example, we find that the primary step in the dissociation process occurs due to the strong resonance between the carboxylate bond vibrations of the diphenylalanine peptides and the tuned laser frequencies. The effects of laser irradiation are determined by a balance between tube formation and dissociation. Our work shows a proof of concept and should provide a motivation for future experimental developments with the final aim to open a new and efficient way to cleave or to recycle bio-inspired materials. PMID:26437688

  5. Picosecond dissociation of amyloid fibrils with infrared laser: A nonequilibrium simulation study

    SciTech Connect

    Hoang Viet, Man; Roland, Christopher Sagui, Celeste; Derreumaux, Philippe; Nguyen, Phuong H.; Li, Mai Suan

    2015-10-21

    Recently, mid-infrared free-electron laser technology has been developed to dissociate amyloid fibrils. Here, we present a theoretical framework for this type of experiment based on laser-induced nonequilibrium all-atom molecular dynamics simulations. We show that the fibril is destroyed due to the strong resonance between its amide I vibrational modes and the laser field. The effects of laser irradiation are determined by a balance between fibril formation and dissociation. While the overall rearrangements of the fibril finish over short time scales, the interaction between the peptides and the solvent continues over much longer times indicating that the waters play an important role in the dissociation process. Our results thus provide new insights into amyloid fibril dissociation by laser techniques and open up new venues to investigate the complex phenomena associated with amyloidogenesis.

  6. Picosecond dissociation of amyloid fibrils with infrared laser: A nonequilibrium simulation study

    NASA Astrophysics Data System (ADS)

    Hoang Viet, Man; Derreumaux, Philippe; Li, Mai Suan; Roland, Christopher; Sagui, Celeste; Nguyen, Phuong H.

    2015-10-01

    Recently, mid-infrared free-electron laser technology has been developed to dissociate amyloid fibrils. Here, we present a theoretical framework for this type of experiment based on laser-induced nonequilibrium all-atom molecular dynamics simulations. We show that the fibril is destroyed due to the strong resonance between its amide I vibrational modes and the laser field. The effects of laser irradiation are determined by a balance between fibril formation and dissociation. While the overall rearrangements of the fibril finish over short time scales, the interaction between the peptides and the solvent continues over much longer times indicating that the waters play an important role in the dissociation process. Our results thus provide new insights into amyloid fibril dissociation by laser techniques and open up new venues to investigate the complex phenomena associated with amyloidogenesis.

  7. Vibrational Energy Relaxation of Benzene Dimer Studied by Picosecond Time-Resolved Infrared-Ultraviolet Pump-Probe Spectroscopy

    NASA Astrophysics Data System (ADS)

    Kusaka, R.; Ebata, T.

    2010-06-01

    The benzene dimer is excited to the CH stretching vibrational levels by a picosecond IR pulse, and the time evolution of the population of the pumped and redistributed levels are probed by (1+1)REMPI with a picosecond UV pulse. In order to accomplish IR excitation localized in the site of the T-shaped dimer, two dimer isotopomers [(1) Top=C_6H_6, Stem=C_6D_6, (2) Top=C_6D_6, Stem=C_6H_6] are used. From the time profiles of the pumped and the relaxed levels, the rate constants of intracluster vibrational redistribution (ICVR) at each site and subsequent vibrational predissociation (VP) are discussed.

  8. Applications of infrared free electron lasers in picosecond and nonlinear spectroscopy

    NASA Astrophysics Data System (ADS)

    Fann, W. S.; Benson, S. V.; Madey, J. M. J.; Etemad, S.; Baker, G. L.; Rothberg, L.; Roberson, M.; Austin, R. H.

    1990-10-01

    In this paper we describe two different types of spectroscopic experiments that exploit the characteristics of the infrared FEL, Mark III, for studies of condensed matter: - the spectrum of χ(3)(-3ω; ω, ω, ω) in polyacetylene: an application of the free electron laser in nonlinear optical spectroscopy, and - a dynamical test of Davydov-like solitons in acetanilide using a picosecond free electron laser. These two studies highlight the unique contributions FELs can make to condensed-matter spectroscopy.

  9. A New Technology for Applanation Free Corneal Trephination: The Picosecond Infrared Laser (PIRL)

    PubMed Central

    Linke, Stephan J.; Frings, Andreas; Ren, Ling; Gomolka, Amadeus; Schumacher, Udo; Reimer, Rudolph; Hansen, Nils-Owe; Jowett, Nathan; Richard, Gisbert; Miller, R. J. Dwayne

    2015-01-01

    The impact of using a Femtosecond laser on final functional results of penetrating keratoplasty is low. The corneal incisions presented here result from laser ablations with ultrafast desorption by impulsive vibrational excitation (DIVE). The results of the current study are based on the first proof-of-principle experiments using a mobile, newly introduced picosecond infrared laser system, and indicate that wavelengths in the mid-infrared range centered at 3 μm are efficient for obtaining applanation-free deep cuts on porcine corneas. PMID:25781907

  10. Picosecond pulsed infrared laser tuned to amide I band dissociates polyglutamine fibrils in cells.

    PubMed

    Kawasaki, Takayasu; Ohori, Gaku; Chiba, Tomoyuki; Tsukiyama, Koichi; Nakamura, Kazuhiro

    2016-09-01

    Amyloid fibrils are causal substances for serious neurodegenerative disorders and amyloidosis. Among them, polyglutamine fibrils seen in multiple polyglutamine diseases are toxic to neurons. Although much efforts have been made to explore the treatments of polyglutamine diseases, there are no effective drugs to block progression of the diseases. We recently found that a free electron laser (FEL), which has an oscillation wavelength at the amide I band (C = O stretch vibration mode) and picosecond pulse width, was effective for conversion of the fibril forms of insulin, lysozyme, and calcitonin peptide into their monomer forms. However, it is not known if that is also the case in polyglutamine fibrils in cells. We found in this study that the fibril-specific β-sheet conformation of polyglutamine peptide was converted into nonfibril form, as evidenced by the infrared microscopy and scanning-electron microscopy after the irradiation tuned to 6.08 μm. Furthermore, irradiation at this wavelength also changed polyglutamine fibrils to their nonfibril state in cultured cells, as shown by infrared mapping image of protein secondary structure. Notably, infrared thermography analysis showed that temperature increase of the cells during the irradiation was within 1 K, excluding thermal damage of cells. These results indicate that the picosecond pulsed infrared laser can safely reduce amyloid fibril structure to the nonfibril form even in cells. PMID:27342599

  11. Picosecond infrared laser (PIRL): an ideal phonomicrosurgical laser?

    PubMed

    Hess, Markus; Hildebrandt, Michael Dominik; Müller, Frank; Kruber, Sebastian; Kroetz, Peter; Schumacher, Udo; Reimer, Rudolph; Kammal, Michael; Püschel, Klaus; Wöllmer, Wolfgang; Miller, Dwayne

    2013-11-01

    A comparison of tissue cutting effects in excised cadaver human vocal folds after incisions with three different instruments [scalpel, CO2 laser and the picosecond infrared laser-(PIRL)] was performed. In total, 15 larynges were taken from human cadavers shortly after death. After deep freezing and thawing for the experiment, the vocal folds suspended in the hemilarynx were incised. Histology and environmental scanning electron microscopy (ESEM) analyses were performed. Damage zones after cold instrument cuts ranged from 51 to 135 μm, as compared to 9-28 μm after cutting with the PIRL. It was shown that PIRL incision had smaller zones of tissue coagulation and tissue destruction, when compared with scalpel and CO2 laser cuts. The PIRL technology provides an (almost) atraumatic laser, which offers a quantum jump towards realistic 'micro'-phonosurgery on a factual cellular dimension, almost entirely avoiding coagulation, carbonization, or other ways of major tissue destruction in the vicinity of the intervention area. Although not available for clinical use yet, the new technique appears promising for future clinical applications, so that technical and methodological characteristics as well as tissue experiments seem worthwhile to be communicated at this stage of development. PMID:23708442

  12. Picosecond Optical Studies of Solids.

    NASA Astrophysics Data System (ADS)

    Broomfield, Seth Emlyn

    Available from UMI in association with The British Library. Requires signed TDF. Hot carrier relaxation is studied in the alloy semiconductor Ga_{rm 1-x} Al_{rm x}As by analysis of time-resolved luminescence at 4K. Photoexcited carrier densities in the range 10^{16 } to 10^{18}cm ^{-3} were created by 5ps laser pulses in alloys with x values ranging from 0 to 0.36. Carrier temperature cooling curves are discussed in terms of emission and absorption of non-equilibrium phonons by carriers, intervalley scattering of electrons and alloy disorder effects. Energy relaxation within a band of localised exciton states is studied in Ga_{rm 1 -x}Al_{rm x} As by analysis of time-resolved photoluminescence at 4K with a photoexcited carrier density of 10 ^{14}cm^{-3 }. It is found that the width of the band of localised states increases with the degree of alloy disorder as x ranges from 0 to 0.36. A form for the density of localised states is obtained. The intersite exciton overlap is estimated. Photoluminescence of the semiconductor gallium selenide is measured for carrier densities below 3 times 10^{18}cm ^{-3} at 2K. Biexcitons are identified by analysis of the photoluminescence at high densities. This is confirmed by induced optical absorption experiments. It is shown that biexciton dissociation by interaction with low-energy optical phonons occurs as the lattice temperature is increased. The group velocity of excitonic polaritons is obtained from measurements of the time-of-flight of 5ps optical pulses across a 1mum thick layer of gallium arsenide at 4K. The group velocity has a minimum value of 4 times 10 ^5ms^{-1} at the transverse exciton energy, and has a dependence on photon energy which agrees well with a model describing spatial dispersion of polaritons.

  13. Time-resolved fluorescence polarization spectroscopy of visible and near infrared dyes in picosecond dynamics

    NASA Astrophysics Data System (ADS)

    Pu, Yang; Alfano, Robert R.

    2015-03-01

    Near-infrared (NIR) dyes absorb and emit light within the range from 700 to 900 nm have several benefits in biological studies for one- and/or two-photon excitation for deeper penetration of tissues. These molecules undergo vibrational and rotational motion in the relaxation of the excited electronic states, Due to the less than ideal anisotropy behavior of NIR dyes stemming from the fluorophores elongated structures and short fluorescence lifetime in picosecond range, no significant efforts have been made to recognize the theory of these dyes in time-resolved polarization dynamics. In this study, the depolarization of the fluorescence due to emission from rotational deactivation in solution will be measured with the excitation of a linearly polarized femtosecond laser pulse and a streak camera. The theory, experiment and application of the ultrafast fluorescence polarization dynamics and anisotropy are illustrated with examples of two of the most important medical based dyes. One is NIR dye, namely Indocyanine Green (ICG) and is compared with Fluorescein which is in visible range with much longer lifetime. A set of first-order linear differential equations was developed to model fluorescence polarization dynamics of NIR dye in picosecond range. Using this model, the important parameters of ultrafast polarization spectroscopy were identified: risetime, initial time, fluorescence lifetime, and rotation times.

  14. Mitotic spindle studied using picosecond laser scissors

    NASA Astrophysics Data System (ADS)

    Baker, N. M.; Botvinick, E. L.; Shi, Linda; Berns, M. B.; Wu, George

    2006-08-01

    In previous studies we have shown that the second harmonic 532 nm, from a picosecond frequency doubled Nd:YAG laser, can cleanly and selectively disrupt spindle fiber microtubules in live cells (Botvinick et al 2004, Biophys. J. 87:4303-4212). In the present study we have ablated different locations and amounts of the metaphase mitotic spindle, and followed the cells in order to observe the fate of the irradiated spindle and the ability of the cell to continue through mitosis. Cells of the rat kangaroo line (PTK2) were stably transfected by ECFP-tubulin and, using fluorescent microscopy and the automated RoboLase microscope, (Botvinick and Berns, 2005, Micros. Res. Tech. 68:65-74) brightly fluorescent individual cells in metaphase were irradiated with 0.2447 nJ/micropulse corresponding to an irradiance of 1.4496*10^7 J/(ps*cm^2) . Upon irradiation the exposed part of the mitotic spindle immediately lost fluorescence and the following events were observed in the cells over time: (1) immediate contraction of the spindle pole towards the cut, (2) recovery of connection between pole and cut microtubule, (3) completion of mitosis. This system should be very useful in studying internal cellular dynamics of the mitotic spindle.

  15. Reduction of thermocoagulative injury via use of a picosecond infrared laser (PIRL) in laryngeal tissues.

    PubMed

    Böttcher, Arne; Kucher, Stanislav; Knecht, Rainald; Jowett, Nathan; Krötz, Peter; Reimer, Rudolph; Schumacher, Udo; Anders, Sven; Münscher, Adrian; Dalchow, Carsten V; Miller, R J Dwayne

    2015-04-01

    The carbon dioxide (CO2) laser is routinely used in glottic microsurgery for the treatment of benign and malignant disease, despite significant collateral thermal damage secondary to photothermal vaporization without thermal confinement. Subsequent tissue response to thermal injury involves excess collagen deposition resulting in scarring and functional impairment. To minimize collateral thermal injury, short-pulse laser systems such as the microsecond pulsed erbium:yttrium-aluminium-garnet (Er:YAG) laser and picosecond infrared laser (PIRL) have been developed. This study compares incisions made in ex vivo human laryngeal tissues by CO2 and Er:YAG lasers versus PIRL using light microscopy, environmental scanning electron microscopy (ESEM), and infrared thermography (IRT). In comparison to the CO2 and Er:YAG lasers, PIRL incisions showed significantly decreased mean epithelial (59.70 µm) and subepithelial (22.15 µm) damage zones (p < 0.05). Cutting gaps were significantly narrower for PIRL (133.70 µm) compared to Er:YAG and CO2 lasers (p < 0.05), which were more than 5 times larger. ESEM revealed intact collagen fibers along PIRL cutting edges without obvious carbonization, in comparison to diffuse carbonization and tissue melting seen for CO2 and Er:YAG laser incisions. IRT demonstrated median temperature rise of 4.1 K in PIRL vocal fold incisions, significantly less than for Er:YAG laser cuts (171.85 K; p < 0.001). This study has shown increased cutting precision and reduced lateral thermal damage zones for PIRL ablation in comparison to conventional CO2 and Er:YAG lasers in human glottis and supraglottic tissues. PMID:25575843

  16. Size Dependent Ultrafast Cooling of Water Droplets in Microemulsions by Picosecond Infrared Spectroscopy

    NASA Astrophysics Data System (ADS)

    Seifert, G.; Patzlaff, T.; Graener, H.

    2002-04-01

    The ultrafast thermal relaxation of reversed micelles in n-octane/AOT/water (where AOT denotes sodium di-2-ethylhexyl sulfosuccinate) microemulsions was investigated by time-resolved infrared pump-probe spectroscopy. This picosecond cooling process can be described in terms of heat diffusion, demonstrating a new method to determine the nanometer radii of the water droplets. The reverse micelles are stable against transient temperatures far above the equilibrium stability range. The amphiphilic interface layer (AOT) seems to provide an efficient heat contact between the water and the nonpolar solvent.

  17. Octave-spanning infrared supercontinuum generation in robust chalcogenide nanotapers using picosecond pulses.

    PubMed

    Shabahang, Soroush; Marquez, Michael P; Tao, Guangming; Piracha, Mohammad U; Nguyen, Dat; Delfyett, Peter J; Abouraddy, Ayman F

    2012-11-15

    We report on infrared supercontinuum generation extending over more than one octave of bandwidth, from 850 nm to 2.35 μm, produced in a single spatial mode from a robust, compact, composite chalcogenide glass nanotaper. A picosecond laser at 1.55 μm pumps a high-index-contrast, all-solid nanotaper that strongly confines the field to a 480 nm diameter core, while a thermally compatible built-in polymer jacket lends the nanotaper mechanical stability. PMID:23164864

  18. Ambient Mass Spectrometry Imaging with Picosecond Infrared Laser Ablation Electrospray Ionization (PIR-LAESI).

    PubMed

    Zou, Jing; Talbot, Francis; Tata, Alessandra; Ermini, Leonardo; Franjic, Kresimir; Ventura, Manuela; Zheng, Jinzi; Ginsberg, Howard; Post, Martin; Ifa, Demian R; Jaffray, David; Miller, R J Dwayne; Zarrine-Afsar, Arash

    2015-12-15

    A picosecond infrared laser (PIRL) is capable of cutting through biological tissues in the absence of significant thermal damage. As such, PIRL is a standalone surgical scalpel with the added bonus of minimal postoperative scar tissue formation. In this work, a tandem of PIRL ablation with electrospray ionization (PIR-LAESI) mass spectrometry is demonstrated and characterized for tissue molecular imaging, with a limit of detection in the range of 100 nM for reserpine or better than 5 nM for verapamil in aqueous solution. We characterized PIRL crater size using agar films containing Rhodamine. PIR-LAESI offers a 20-30 μm vertical resolution (∼3 μm removal per pulse) and a lateral resolution of ∼100 μm. We were able to detect 25 fmol of Rhodamine in agar ablation experiments. PIR-LAESI was used to map the distribution of endogenous methoxykaempferol glucoronide in zebra plant (Aphelandra squarrosa) leaves producing a localization map that is corroborated by the literature. PIR-LAESI was further used to image the distribution inside mouse kidneys of gadoteridol, an exogenous magnetic resonance contrast agent intravenously injected. Parallel mass spectrometry imaging (MSI) using desorption electrospray ionization (DESI) and matrix assisted laser desorption ionization (MALDI) were performed to corroborate PIR-LAESI images of the exogenous agent. We further show that PIR-LAESI is capable of desorption ionization of proteins as well as phospholipids. This comparative study illustrates that PIR-LAESI is an ion source for ambient mass spectrometry applications. As such, a future PIRL scalpel combined with secondary ionization such as ESI and mass spectrometry has the potential to provide molecular feedback to guide PIRL surgery. PMID:26561279

  19. Fiber laser pumped high power mid-infrared laser with picosecond pulse bunch output.

    PubMed

    Wei, Kaihua; Chen, Tao; Jiang, Peipei; Yang, Dingzhong; Wu, Bo; Shen, Yonghang

    2013-10-21

    We report a novel quasi-synchronously pumped PPMgLN-based high power mid-infrared (MIR) laser with picosecond pulse bunch output. The pump laser is a linearly polarized MOPA structured all fiberized Yb fiber laser with picosecond pulse bunch output. The output from a mode-locked seed fiber laser was directed to pass through a FBG reflector via a circulator to narrow the pulse duration from 800 ps to less than 50 ps and the spectral FWHM from 9 nm to 0.15 nm. The narrowed pulses were further directed to pass through a novel pulse multiplier through which each pulse was made to become a pulse bunch composing of 13 sub-pulses with pulse to pulse time interval of 1.26 ns. The pulses were then amplified via two stage Yb fiber amplifiers to obtain a linearly polarized high average power output up to 85 W, which were then directed to pass through an isolator and to pump a PPMgLN-based optical parametric oscillator via quasi-synchronization pump scheme for ps pulse bunch MIR output. High MIR output with average power up to 4 W was obtained at 3.45 micron showing the feasibility of such pump scheme for ps pulse bunch MIR output. PMID:24150378

  20. Picosecond-time-resolved studies of nonradiative relaxation in ruby and alexandrite

    SciTech Connect

    Gayen, S.K.; Wang, W.B.; Petricevic, V.; Alfano, R.R.

    1985-01-01

    Dynamics of the nonradiative transitions between the /sup 4/T/sub 2/ pump band and the /sup 2/E storage level of the Cr/sup 3 +/ ion in ruby and alexandrite crystals is studied using the picosecond excite-and-probe absorption technique. A 527-nm picosecond pulse excites the /sup 4/T/sub 2/ state of the Cr/sup 3 +/ ion, and an infrared picosecond probe pulse monitors the subsequent growth and decay of population in the excited states as a function of pump-probe delay. An upper limit of 7 ps is determined for the nonradiative lifetime of the /sup 4/T/sub 2/ state in ruby. A vibrational relaxation time of 25 ps for the /sup 4/T/sub 2/ band in alexandrite is estimated. The time to attain thermal equilibrium population between the /sup 2/E and /sup 4/T/sub 2/ levels of alexandrite following excitation of /sup 4/T/sub 2/ band is estimated to be approx. 100 ps.

  1. Peak power tunable mid-infrared oscillator pumped by a high power picosecond pulsed fiber amplifier with bunch output

    NASA Astrophysics Data System (ADS)

    Wei, Kaihua; Guo, Yan; Lai, Xiaomin; Fan, Shanhui

    2016-07-01

    A high power mid-infrared optical parametric oscillator (OPO) with picosecond pulse bunch output is experimentally demonstrated. The pump source was a high power master oscillation power amplifier (MOPA) picosecond pulsed fiber amplifier. The seed of the MOPA was a gain-switched distributed Bragg reflector (DBR) laser diode (LD) with picosecond pulse operation at a high repetition rate. The seed laser was amplified to 50 W by two-stage pre-amplifiers and a large mode area (LMA) Yb fiber based power-amplifier. A fiber-pigtailed acousto-optic modulator with the first order diffraction transmission was inserted into the second pre-amplifier to form a picosecond pulse bunch train and to change the peak power simultaneously. The power-amplified pulse bunches were focused to pump a wavelength-tunable OPO for emitting high power mid-infrared laser. By adjusting the OPO cavity length, the maximum average idler powers obtained at 3.1, 3.3 and 3.5 μm were 7, 6.6 and 6.4 W respectively.

  2. Picosecond electron-optic diagnostics in laser studies

    NASA Astrophysics Data System (ADS)

    Prokhorov, A. M.

    The papers included in this volume provide an overview of research aimed at the development of methods and instrumentation for ultrahigh-speed electron-optic detection and of their applications in laser physics, laser fusion, fiber-optic communication, picosecond spectroscopy, and photobiology. Topics discussed include the physics of a picosecond electron-optic converter, the aberration theory for cathode lenses, picosecond and subpicosecond laser sources, and a beam deflection system for a subpicosecond electron-optic converter.

  3. Nanosurgery with near-infrared 12-femtosecond and picosecond laser pulses

    NASA Astrophysics Data System (ADS)

    Uchugonova, Aisada; Zhang, Huijing; Lemke, Cornelius; König, Karsten

    2011-03-01

    Laser-assisted surgery based on multiphoton absorption of NIR laser light has great potential for high precision surgery at various depths within the cells and tissues. Clinical applications include refractive surgery (fs-LASIK). The non-contact laser method also supports contamination-free cell nanosurgery. Here we apply femtosecond laser scanning microscopes for sub-100 nm surgery of human cells and metaphase chromosomes. A mode-locked 85 MHz Ti:Sapphire laser with an M-shaped ultrabroad band spectrum (maxima: 770 nm/830 nm) with an in situ pulse duration at the target ranging from 12 femtoseconds up to 3 picoseconds was employed. The effects of laser nanoprocessing in cells and chromosomes have been quantified by atomic force microscopy (AFM) and electron microscopy. These studies demonstrate the potential of extreme ultrashort femtosecond laser pulses at low mean milliwatt powers for sub-100 nm surgery.

  4. Retinal threshold studies for nanosecond and picosecond visible laser pulses

    NASA Astrophysics Data System (ADS)

    Roach, William P.; DiCarlo, Cheryl D.; Noojin, Gary D.; Stolarski, David J.; Amnotte, Rodney E.; Smith, Audrey B.; Rogers, Mark E.; Cain, Clarence P.

    1995-05-01

    Threshold measurements for Minimum Visible Lesions (MVL) at the retina are reported for 60 picoseconds (ps) and 4 nanoseconds (ns), single laser pulses in rhesus monkey eyes using a visible wavelength of 532 nanometers (nm) from a doubled Nd:YAG laser. The 50% probability for damage (ED50) dosages are calculated for 1 hour and 24 hour post exposures using 95% fiducial limits. For both pulsewidths, the threshold values calculated by probit analysis decrease between the 1 hour and 24 hour ophthalmoscopic evaluations. The ED50 value determined for the 60 ps pulsewidth was less than half the value at 4 ns (0.43 (mu) J/60 ps vs. 0.90 (mu) J/4 ns at 24 hours) for both readings. Of the 136 exposures for pulse energies ranging from 0.03 to 5.0 (mu) J no hemorrhagic lesions were produced for either pulsewidth studied. However, at 6.6 (mu) J one intraretinal hemorrhagic lesion was observed for 60 ps. The slope of the probit curve was higher for 60 ps when compared with the 4 ns value (3.03 at 60 ps vs. 2.68 at 4 ns). MVL threshold doses calculated are comparable with those reported in the literature. However, the 4 ns MVL values is less than one order of magnitude (a factor 4.7) above the Maximum Permissible Exposure (MPE) level as defined by the 'American National Standard For The Safe Use Of Lasers', ANSI Z136.1-19932. We present the current MVL data as it compares with previous data obtained for picosecond and femtosecond laser pulse thresholds and provide a preliminary assessment of how the ANSI MPE standard might be amended.

  5. Studies on laser material processing with nanosecond and sub-nanosecond and picosecond and sub-picosecond pulses

    NASA Astrophysics Data System (ADS)

    Zhang, Jie; Tao, Sha; Wang, Brian; Zhao, Jay

    2016-03-01

    In this paper, laser ablation of widely used metal (Al, Cu. stainless-steel), semiconductor (Si), transparent material (glass, sapphire), ceramic (Al2O3, AlN) and polymer (PI, PMMA) in industry were systematically studied with pulse width from nanosecond (5-100ns), picosecond (6-10ps) to sub-picosecond (0.8-0.95ps). A critical damage zone (CDZ) of up to 100um with ns laser, <=50um with ps laser, and <=20um with sub-ps laser, respectively was observed as a criteria of selecting the laser pulse width. The effects of laser processing parameters on speed and efficiency were also investigated. This is to explore how to provide industry users the best laser solution for device micro-fabrication with best price. Our studies of cutting and drilling with ns, ps, and sub-ps lasers indicate that it is feasible to achieve user accepted quality and speed with cost-effective and reliable laser by optimizing processing conditions.

  6. Low-noise, high-brightness, tunable source of picosecond pulsed light in the near-infrared and visible.

    PubMed

    Mosley, Peter J; Bateman, Samuel A; Lavoute, Laure; Wadsworth, William J

    2011-12-01

    We have built a flexible source of picosecond pulsed light in both the near-infrared and visible spectral regions. A photonic crystal fiber (PCF) was pumped with a pulsed 1064 nm fiber laser to generate four-wave mixing (FWM) sidebands at 947 nm and 1213 nm. This process was seeded at the idler wavelength with a tunable diode laser to limit the spectral width of the sidebands to less than 0.5 nm. Subsequently the idler was mixed efficiently with the residual pump in a nonlinear crystal to yield their sum frequency at 567 nm. All three outputs were tunable by adjusting the seed wavelength and all had very low pulse-to-pulse amplitude noise. This technique could be extended to different wavelength ranges by selecting different seed lasers and PCF. PMID:22273925

  7. Far-field infrared super-resolution microscopy using picosecond time-resolved transient fluorescence detected IR spectroscopy

    NASA Astrophysics Data System (ADS)

    Sakai, Makoto; Kawashima, Yasutake; Takeda, Akihiro; Ohmori, Tsutomu; Fujii, Masaaki

    2007-05-01

    A new far-field infrared super-resolution microscopy combining laser fluorescence microscope and picosecond time-resolved transient fluorescence detected IR (TFD-IR) spectroscopy is proposed. TFD-IR spectroscopy is a kind of IR-visible/UV double resonance spectroscopy, and detects IR transitions by the transient fluorescence due to electronic transition originating from vibrationally excited level populated by IR light. IR images of rhodamine-6G solution and of fluorescent beads were clearly observed by monitoring the transient fluorescence. Super-resolution twice higher than the diffraction limit for IR light was achieved. The IR spectrum due to the transient fluorescence was also measured from spatial domains smaller than the diffraction limit.

  8. Picosecond flash spectroscopic studies on ultraviolet stabilizers and stabilized polymers

    NASA Technical Reports Server (NTRS)

    Scott, G. W.

    1982-01-01

    Spectroscopic and excited state decay kinetics are reported for monomeric and polymeric forms of ultraviolet stabilizers in the 2-(2'-hydroxyphenyl)-benzotriazole and 2-hydroxybenzophenone classes. For some of these molecules in various solvents at room temperature, (1) ground state absorption spectra, (2) emission spectra, (3) picosecond time-resolved transient absorption spectra, (4) ground state absorption recovery kinetics, (5) emission kinetics, and (6) transient absorption kinetics are reported. In the solid state at low temperatures, emission spectra and their temperature dependent kinetics up to approximately 200K as well as, in one case, the 12K excitation spectra of the observed dual emission are also reported.

  9. Millijoule-level picosecond mid-infrared optical parametric amplifier based on MgO-doped periodically poled lithium niobate.

    PubMed

    Xu, Hongyan; Yang, Feng; Chen, Ying; Liu, Ke; Du, Shifeng; Zong, Nan; Yang, Jing; Bo, Yong; Peng, Qinjun; Zhang, Jingyuan; Cui, Dafu; Xu, Zuyan

    2015-03-20

    A millijoule-level high pulse energy picosecond (ps) mid-infrared (MIR) optical parametric amplifier (OPA) at 3.9 μm based on large-aperture MgO-doped periodically poled lithium niobate (MgO:PPLN) crystal was demonstrated for the first time, to the best of our knowledge. The MIR OPA was pumped by a 30 ps 1064 nm Nd:YAG laser at 10 Hz and injected by an energy-adjustable near-infrared seed based on a barium boron oxide (BBO) optical parametric generator/optical parametric amplifier (OPG/OPA) with double-pass geometry. Output energy of 1.14 mJ at 3.9 μm has been obtained at pump energy of 15.2 mJ. Furthermore, the performance of MIR OPG in MgO:PPLN was also investigated for comparing with the seeded OPA. PMID:25968539

  10. High-precision micro-through-hole array in quartz glass machined by infrared picosecond laser

    NASA Astrophysics Data System (ADS)

    Ji, Lingfei; Hu, Yan; Li, Jian; Wang, Wenhao; Jiang, Yijian

    2015-11-01

    Circle and triangle micro-through-hole arrays without cracks, chips, and debris were machined in 0.3-mm-thick quartz glass by picosecond laser (wavelength = 1064 nm, pulse width ~12 ps) in air ambient. The diameter of each circle through-hole was 550 μm, and the side length of each triangle hole is 500 μm; 30 μm spacing between the adjacent hole edges and the smooth machined surface with R a = 0.8 μm roughness depicted the high precision of the high-density micro-through-hole arrays. The fundamental properties of the ps laser processing of quartz glass were investigated. The laser ablation threshold fluence of the quartz glass was determined as 3.49 J/cm2. Based on the fundamental investigation, a quantitative design of the cutting path for micro-machining of the through-holes with various geometries in quartz glass was developed. The work presents a more practical ps laser micro-machining technique for micro-through-hole arrays in glass-like materials for industrial application due to the precise quality, flexibility in geometries, ease of manipulation, and large-scale application.

  11. Fiber laser pumped burst-mode operated picosecond mid-infrared laser

    NASA Astrophysics Data System (ADS)

    Wei, Kai-Hua; Jiang, Pei-Pei; Wu, Bo; Chen, Tao; Shen, Yong-Hang

    2015-02-01

    We demonstrate a compact periodically poled MgO-doped lithium niobate (MgO:PPLN)-based optical parametric oscillator (OPO) quasi-synchronously pumped by a fiber laser system with burst-mode operation. The pump source is a peak-power-selectable pulse-multiplied picosecond Yb fiber laser. The chirped pulses from a figure of eight-cavity mode-locked fiber laser seed are narrowed to a duration of less than 50 ps using an FBG reflector and a circulator. The narrowed pulses are directed to pass through a pulse multiplier and to form pulse bunches, each of which is composed of 13 sub-pulses. The obtained pulse bunches are amplified by two-stage fiber pre-amplifiers: one-stage is core-pumped and the other is cladding-pumped. A fiberized acousto-optic modulator is inserted to control the pulse repetition rate (PRR) of the pulse bunches before they are power-amplified in the final amplifier stage with a large mode area (LMA) PM Yb-doped fiber. The maximum average powers from the final amplifier are 85 W, 60 W, and 45 W, respectively, corresponding to the PRR of 2.72 MHz, 1.36 MHz, and 0.68 MHz. The amplified pulses are directed to pump an MgO:PPLN-based optical parametric oscillator (OPO). A maximum peak power at 3.45 μm is obtained approximately to be 8.4 kW. Detailed performance characteristics are presented. Project supported by the National Natural Science Foundation of China (Grant No. 61078015) and the National Basic Research Program of China (Grant No. 2011CB311803).

  12. Picosecond infrared laser-induced all-atom nonequilibrium molecular dynamics simulation of dissociation of viruses.

    PubMed

    Hoang Man, Viet; Van-Oanh, Nguyen-Thi; Derreumaux, Philippe; Li, Mai Suan; Roland, Christopher; Sagui, Celeste; Nguyen, Phuong H

    2016-04-28

    Since the discovery of the plant pathogen tobacco mosaic virus as the first viral entity in the late 1800s, viruses traditionally have been mainly thought of as pathogens for disease-resistances. However, viruses have recently been exploited as nanoplatforms with applications in biomedicine and materials science. To this aim, a large majority of current methods and tools have been developed to improve the physical stability of viral particles, which may be critical to the extreme physical or chemical conditions that viruses may encounter during purification, fabrication processes, storage and use. However, considerably fewer studies are devoted to developing efficient methods to degrade or recycle such enhanced stability biomaterials. With this in mind, we carry out all-atom nonequilibrium molecular dynamics simulation, inspired by the recently developed mid-infrared free-electron laser pulse technology, to dissociate viruses. Adopting the poliovirus as a representative example, we find that the primary step in the dissociation process is due to the strong resonance between the amide I vibrational modes of the virus and the tuned laser frequencies. This process is determined by a balance between the formation and dissociation of the protein shell, reflecting the highly plasticity of the virus. Furthermore, our method should provide a feasible approach to simulate viruses, which is otherwise too expensive for conventional equilibrium all-atom simulations of such very large systems. Our work shows a proof of concept which may open a new, efficient way to cleave or to recycle virus-based materials, provide an extremely valuable tool for elucidating mechanical aspects of viruses, and may well play an important role in future fighting against virus-related diseases. PMID:27071540

  13. Widely tunable parametric generation of picosecond visible and mid-infrared radiation in optical fibers

    NASA Astrophysics Data System (ADS)

    Giree, Achut; Jauregui, Cesar; Limpert, Jens; Tünnermann, Andreas

    2013-03-01

    Parametric generation in an endlessly single-mode photonic crystal fiber can be a simple and efficient way to generate tunable visible and mid-infrared radiation. In this manuscript we report on a visible light source that is tunable from 628nm to 661nm with up to 25% conversion efficiency. This was obtained by tuning the parametric pump from 1030nm to 1055nm in a 1.6m long LMA-10 PM photonic crystal fiber. At the same time, the source generates mid-infrared radiation that can be tuned from ~2.65μm to ~2.9μm. A further increase of the tunable range of both the visible and midinfrared is possible simply by extending the pump tuning range.

  14. Study of solvation dynamics in the interior of staphylococcal nuclease (SNase) using picosecond-resolved emission spectra of tryptophan

    NASA Astrophysics Data System (ADS)

    Gao, Guangyu; Li, Yu; Wang, Wei; Men, Jing; Zhong, Dongping; Wang, ShuFeng; Gong, Qihuang

    2014-09-01

    We report here our study on ultrafast spectral dynamics in the interior of SNase using picosecond-resolved emission spectra of tryptophan through site-directed mutagenesis. By probing the solvation dynamics in the nucleotide binding pocket and the Ca2+ binding pocket as well as in the interior of hydrophobic core, two robust relaxation time scales on a few picoseconds and on tens of picoseconds have been observed. Both two time scales are strongly correlated with local structural and chemical properties of protein. These distinct differences in solvation dynamics reflect the intimate relationship between the dynamic structures and the functions of enzyme.

  15. Infrared Detection with High Transition Temperature Bolometers and Response of Niobium Tunnel Junctions to Picosecond Voltage Pulses.

    NASA Astrophysics Data System (ADS)

    Verghese, Simon

    1993-01-01

    Oxide superconductors with high critical temperature T_{rm c} make sensitive thermometers for several types of infrared bolometers. We built composite bolometers with rm YBa_2Cu _3O_{7-delta} thermometers on sapphire substrates which have higher sensitivity than competing thermal detectors which operate at temperatures above 77 K. A 1 x 1 mm bolometer with gold black serving as the radiation absorber has useful sensitivity for wavelengths 20-100 mum. A 3 x 3 mm bolometer with a bismuth film as the absorber operates from 20-100 mum. High-T_{ rm c} bolometers which are fabricated with micromachining techniques on membranes of Si or Si _3N_4 have potential application to large-format arrays which are used for infrared imaging. Thermal isolation is achieved by suspending the membrane on two thin legs of the membrane material. A nonisothermal high-T_{ rm c} bolometer can be fabricated on a membrane of yttria-stabilized zirconia (YSZ) which is in thermal contact with the heat sink along the perimeter of the membrane. A thermal analysis indicates that the YSZ membrane bolometer can have improved sensitivity compared to the sapphire bolometer for spectrometer applications. The quasiparticle tunneling current in a superconductor -insulator-superconductor (SIS) junction is highly nonlinear in the applied voltage. If an SIS junction is excited with photons of energy hbaromega, where hbaromega/e is larger than the width of the nonlinearity in the I-V curve, the response of the quasiparticle current is retarded and depends strongly on omega. We have made the first measurement of the linear response of the quasiparticle current in a Nb/AlO_{rm x} /Nb junction over a broad bandwidth from 75-200 GHz. We used picosecond pulses of millimeter wave radiation which were generated by illuminating a photoconductive switch with a mode-locked laser. The data are in agreement with the theory of linear photon-assisted tunneling. Nonlinear measurements made with these pulses may provide

  16. Toward picosecond time-resolved X-ray absorption studies of interfacial photochemistry

    NASA Astrophysics Data System (ADS)

    Gessner, Oliver; Mahl, Johannes; Neppl, Stefan

    2016-05-01

    We report on the progress toward developing a novel picosecond time-resolved transient X-ray absorption spectroscopy (TRXAS) capability for time-domain studies of interfacial photochemistry. The technique is based on the combination of a high repetition rate picosecond laser system with a time-resolved X-ray fluorescent yield setup that may be used for the study of radiation sensitive materials and X-ray spectroscopy compatible photoelectrochemical (PEC) cells. The mobile system is currently deployed at the Advanced Light Source (ALS) and may be used in all operating modes (two-bunch and multi-bunch) of the synchrotron. The use of a time-stamping technique enables the simultaneous recording of TRXAS spectra with delays between the exciting laser pulses and the probing X-ray pulses spanning picosecond to nanosecond temporal scales. First results are discussed that demonstrate the viability of the method to study photoinduced dynamics in transition metal-oxide semiconductor (SC) samples under high vacuum conditions and at SC-liquid electrolyte interfaces during photoelectrochemical water splitting. Opportunities and challenges are outlined to capture crucial short-lived intermediates of photochemical processes with the technique. This work was supported by the Department of Energy Office of Science Early Career Research Program.

  17. Picosecond infrared spectroscopy as probe for photochemical or thermal reactions in solid matrices

    SciTech Connect

    Lippert, T.; Funk, D.J.; Strauss, C.E.M.; Stoutland, P.O.

    1998-08-01

    Spectroscopy in the mid-IR on timescales from pico to milliseconds has been developed for the study of laser-material interactions over broad timescales. To reach these timescales the authors have employed two configurations: (1) for the ps to ns timescale a one and a two stage difference frequency mixing setup is employed, (2) for the longer timescale, CW mid-IR laser diodes have been used. In general, they excite the sample with one pulse at 1064/266/355 nm and probe some time later in the mid IR (2900--800 cm{sup {minus}1}). In the case of photochemical reaction, they excite the sample directly in the UV. Alternatively, they initiate thermal reactions by pumping a heater dye at 1.064 {micro}m, which quickly converts the photon energy into heat. The potential of this technique to study reactions in the solid state was demonstrated for a photochemically induced (266 nm) reaction (Wolff rearrangement of a {alpha}-diazo-ketone to {alpha}-keto-ketene) in a polymer matrix. Thermal initiation resulted in a similar reaction. The position, amplitude and width of the product bands changed, they believe due to additional side reactions and temperature effects.

  18. Picosecond dynamics of reactions in the liquid phase: studies of iodine photodissociation and development of new laser techniques

    SciTech Connect

    Berg, M.A.

    1985-09-01

    Iodine photodissociation and recombination was studied as a model for processes common to chemical reaction in the liquid phase. Picosecond transient absorption measurements from 1000 to 295 nm were used to monitor the dynamics in a variety of solvents. Most of the atoms which undergo geminate recombination were found to do so in less than or equal to 15 ps, in agreement with the results of existing molecular dynamics simulations. Vibrational relaxation times vary from approx.15 ps near the middle of the ground state well to approx.150 ps for complete relaxation to v = 0. The prediction of strong resonant vibrational energy transfer to chlorinated methane solvents was not supported, but some evidence for this mechanism was found for alkane solvents. Current theory is unable to explain the large variation (65 to 2700 ps) of the excited A'-state lifetime in various solvents. The 10-Hz amplified, synchronously-pumped dye laser which was used in these studies is described and characterized. SERS (Stimulated Electronic Raman Scattering) and difference frequency mixing were used in the generation of the infrared and far-infrared, respectively. 54 refs., 38 figs., 3 tabs. (WRF)

  19. Picosecond Laser Studies of Third-Order Nonlinear Optical Properties in Organic Polymers

    NASA Astrophysics Data System (ADS)

    Cao, Xiaofan

    This dissertation makes the following theoretical and experimental contributions to the understanding of organic nonlinear optical materials in general, and of the nonlinear optical properties of polyquinoxaline (PQL) ladder polymers and metal-phthalocyanines doped in polycarbonate thin films in particular. (1) We developed a new model of the third-order nonlinear polarization density which has both "fast" (compared to 10psec, such as from electronic or lattice excitations) nonlinearity and "slow" (acoustic and thermal) components. This model enables a more accurate analysis than was possible previously of the different nonlinear optical processes seen in the picosecond laser studies of nonlinear optical properties of organic materials than was possible previously. (2) We interpreted our own picosecond four wave mixing measurements in ten polymers (in the PQL family) in terms of the new model parameters. (3) We have performed picosecond four-wave mixing measurement at 1064, (580-640), and 532 nm in Cr-phthalocyanine doped polycarbonate thin films. Our study supports the excitonic picture proposed by Ho et al.^{104 } (4) We observed for the first time a two -photon absorption state in Cr-Phthalocyanine near 0.5 eV. The two photon absorption coefficients which we determined by three independent methods agree well. (5) We showed that measuring the decay of ultrasonic waves induced by picosecond pulses is a superior way to measure acoustic velocity, acoustic damping, acousto-optic coupling constants, and thermal conductivity of materials. With this we studied the anomalous frequency dependence of sound damping in glasses and polymers. We propose a model for the diffusion of lattice "voids" in amorphous materials that accounts for some aspects of the anomalous ultrasonic sound damping. (6) We measured third harmonic generation in several PQL polymers and in a Cr-phthalocyanine doped polymer. Differences in four-wave mixing measurement were compared for five metal

  20. Electrolytes Ageing in Lithium-ion Batteries: A Mechanistic Study from Picosecond to Long Timescales.

    PubMed

    Ortiz, Daniel; Jiménez Gordon, Isabel; Baltaze, Jean-Pierre; Hernandez-Alba, Oscar; Legand, Solène; Dauvois, Vincent; Si Larbi, Gregory; Schmidhammer, Uli; Marignier, Jean-Louis; Martin, Jean-Frédéric; Belloni, Jacqueline; Mostafavi, Mehran; Le Caër, Sophie

    2015-11-01

    The ageing phenomena occurring in various diethyl carbonate/LiPF6 solutions are studied using gamma and pulse radiolysis as a tool to generate similar species as the ones occurring in electrolysis of Li-ion batteries (LIBs). According to picosecond pulse radiolysis experiments, the reaction of the electron with (Li(+), PF6(-)) is ultrafast, leading to the formation of fluoride anions that can then precipitate into LiF(s). Moreover, direct radiation-matter interaction with the salt produces reactive fluorine atoms forming HF(g) and C2H5F(g). The strong Lewis acid PF5 is also formed. This species then forms various R(1)R(2)R(3) P=O molecules, where R is mainly -F, -OH, and -OC2H5. Substitution reactions take place and oligomers are slowly formed. Similar results were obtained in the ageing of an electrochemical cell filled with the same model solution. This study demonstrates that radiolysis enables a description of the reactivity in LIBs from the picosecond timescale until a few days. PMID:26212854

  1. Picosecond nonlinear optical studies of gold nanoparticles synthesised using coriander leaves (Coriandrum sativum)

    NASA Astrophysics Data System (ADS)

    Venugopal Rao, S.

    2011-07-01

    The results are presented from the experimental picosecond nonlinear optical (NLO) studies of gold nanoparticles synthesised using coriander leaf (Coriandrum sativum) extract. Nanoparticles with an average size of ∼30 nm (distribution of 5-70 nm) were synthesised according to the procedure reported by Narayanan et al. [Mater. Lett. 2008, 62, 4588-4591]. NLO studies were carried out using the Z-scan technique using 2 ps pulses near 800 nm. Open-aperture data suggested saturation absorption as the nonlinear absorption mechanism, whereas closed-aperture data suggested a positive nonlinearity. The magnitude of third-order nonlinearity was estimated to be (3.3 ± 0.6) × 10-13 esu. A solvent contribution to the nonlinearity was also identified and estimated. A comparison is attempted with some recently reported NLO studies of similar gold nanostructures.

  2. Study of self-focusing and self-phase-modulation in the picosecond-time regime.

    NASA Technical Reports Server (NTRS)

    Reintjes, J.; Carman, R. L.; Shimizu, F.

    1973-01-01

    Study of the propagation of a single picosecond pulse of a mode-locked Nd-glass laser in CS2 nitrobenzene and toluene by observations of the birefringence and spectral changes in self-focused laser light. Multiple second-harmonic probing beams are used for birefringence measurements in a single IR pulse in various portions of the active cell. The orientational Kerr effect is found to be the prime factor of induced birefringence in nitrobenzene and toluene. The results for CS2 are also consistent with this mechanism and show that the duration of an IR pulse in the focal volume is less than that of the incident pulse. The properties of beams which are focused within the cell by an external lens are also investigated.

  3. A theoretical study of the stress relaxation in HMX on the picosecond time scale

    NASA Astrophysics Data System (ADS)

    Long, Yao; Chen, Jun

    2015-12-01

    The stress relaxation model of β-HMX on the picosecond time scale is studied by a theoretical approach. The relaxation of normal stress is contributed by lattice vibration, and the relaxation of shear stress is contributed by molecular rotation. Based on this model, the energy dissipation rule of the elastic wave and the profile of the shock wave are investigated. We find at low frequency the dissipation rate of the elastic wave is proportional to the power function of frequency, and under high speed shock loading the width of the stress relaxation zone is less than 0.3 μm there is a pressure peak with a height of 14 GPa near the wave front.

  4. Mid-infrared picosecond pump-dump-probe and pump-repump-probe experiments to resolve a ground-state intermediate in cyanobacterial phytochrome Cph1.

    PubMed

    van Wilderen, Luuk J G W; Clark, Ian P; Towrie, Michael; van Thor, Jasper J

    2009-12-24

    Multipulse picosecond mid-infrared spectroscopy has been used to study photochemical reactions of the cyanobacterial phytochrome photoreceptor Cph1. Different photophysical schemes have been discussed in the literature to describe the pathways after photoexcitation, particularly, to identify reaction phases that are linked to photoisomerisation and electronic decay in the 1566-1772 cm(-1) region that probes C=C and C=O stretching modes of the tetrapyrrole chromophore. Here, multipulse spectroscopy is employed, where, compared to conventional visible pump-mid-infrared probe spectroscopy, an additional visible pulse is incorporated that interacts with populations that are evolving on the excited- and ground-state potential energy surfaces. The time delays between the pump and the dump pulse are chosen such that the dump pulse interacts with different phases in the reaction process. The pump and dump pulses are at the same wavelength, 640 nm, and are resonant with the Pr ground state as well as with the excited state and intermediates. Because the dump pulse additionally pumps the remaining, partially recovered, and partially oriented ground-state population, theory is developed for estimating the fraction of excited-state molecules. The calculations take into account the model-dependent ground-state recovery fraction, the angular dependence of the population transfer resulting from the finite bleach that occurs with linearly polarized intense femtosecond optical excitation, and the partially oriented population for the dump field. Distinct differences between the results from the experiments that use a 1 or a 14 ps dump time favor a branching evolution from S1 to an excited state or reconfigured chromophore and to a newly identified ground-state intermediate (GSI). Optical dumping at 1 ps shows the instantaneous induced absorption of a delocalized C=C stretching mode at 1608 cm(-1), where the increased cross section is associated with the electronic ground

  5. Infrared detection with high-[Tc] bolometers and response of Nb tunnel junctions to picosecond voltage pulses

    SciTech Connect

    Verghese, S.

    1993-05-01

    Oxide superconductors with high critical temperature [Tc] make sensitive thermometers for several types of infrared bolometers. The authors built composite bolometers with YBa[sub 2]Cu[sub 3]O[sub 7[minus][delta

  6. Single water solvation dynamics in the 4-aminobenzonitrile-water cluster cation revealed by picosecond time-resolved infrared spectroscopy.

    PubMed

    Miyazaki, Mitsuhiko; Nakamura, Takashi; Wohlgemuth, Matthias; Mitrić, Roland; Dopfer, Otto; Fujii, Masaaki

    2015-11-28

    The dynamics of a solvent is important for many chemical and biological processes. Here, the migration dynamics of a single water molecule is triggered by the photoionization of the 4-aminobenzonitrile-water (4ABN-W) cluster and monitored in real time by picosecond time-resolved IR (ps TRIR) spectroscopy. In the neutral cluster, water is hydrogen-bonded to the CN group. When this CN-bound cluster is selectively ionized with an excess energy of 1238 cm(-1), water migrates with a lifetime of τ = 17 ps from the CN to the NH2 group, forming a more stable 4ABN(+)-W(NH) isomer with a yield of unity. By decreasing the ionization excess energy, the yield of the CN → NH2 reaction is reduced. The relatively slow migration in comparison to the ionization-induced solvent dynamics in the related acetanilide-water cluster cation (τ = 5 ps) is discussed in terms of the internal excess energy after photoionization and the shape of the potential energy surface. PMID:26490096

  7. Optical tomography of human skin with subcellular spatial and picosecond time resolution using intense near infrared femtosecond laser pulses

    NASA Astrophysics Data System (ADS)

    Koenig, Karsten; Wollina, Uwe; Riemann, Iris; Peukert, Christiane; Halbhuber, Karl-Juergen; Konrad, Helga; Fischer, Peter; Fuenfstueck, Veronika; Fischer, Tobias W.; Elsner, Peter

    2002-06-01

    We describe the novel high resolution imaging tool DermaInspect 100 for non-invasive diagnosis of dermatological disorders based on multiphoton autofluorescence imaging (MAI)and second harmonic generation. Femtosecond laser pulses in the spectral range of 750 nm to 850 nm have been used to image in vitro and in vivo human skin with subcellular spatial and picosecond temporal resolution. The non-linear induced autofluorescence originates mainly from naturally endogenous fluorophores/protein structures like NAD(P)H, flavins, keratin, collagen, elastin, porphyrins and melanin. Second harmonic generation was observed in the stratum corneum and in the dermis. The system with a wavelength-tunable compact 80 MHz Ti:sapphire laser, a scan module with galvo scan mirrors, piezoelectric objective positioner, fast photon detector and time-resolved single photon counting unit was used to perform optical sectioning and 3D autofluorescence lifetime imaging (t-mapping). In addition, a modified femtosecond laser scanning microscope was involved in autofluorescence measurements. Tissues of patients with psoriasis, nevi, dermatitis, basalioma and melanoma have been investigated. Individual cells and skin structures could be clearly visualized. Intracellular components and connective tissue structures could be further characterized by tuning the excitation wavelength in the range of 750 nm to 850 nm and by calculation of mean fluorescence lifetimes per pixel and of particular regions of interest. The novel non-invasive imaging system provides 4D (x,y,z,t) optical biopsies with subcellular resolution and offers the possibility to introduce a further optical diagnostic method in dermatology.

  8. Photooxidation and photoaquation of iron hexacyanide in aqueous solution: A picosecond X-ray absorption study.

    PubMed

    Reinhard, M; Penfold, T J; Lima, F A; Rittmann, J; Rittmann-Frank, M H; Abela, R; Tavernelli, I; Rothlisberger, U; Milne, C J; Chergui, M

    2014-03-01

    We present a picosecond Fe K-edge absorption study of photoexcited ferrous and ferric hexacyanide in water under 355 and 266 nm excitation. Following 355 nm excitation, the transient spectra for the ferrous and ferric complexes exhibit a red shift of the edge reflecting an increased electron density at the Fe atom. For the former, an enhanced pre-edge transition is also observed. These observations are attributed to the aquated [Fe(CN)5OH2](3-) species, based on quantum chemical calculations which also provide structural parameters. Upon 266 nm excitation of the ferric complex, a transient reminiscent of the aquated species is observed (appearance of a pre-edge feature and red shift of the edge) but it is different from that obtained under 355 nm excitation. This points to a new reaction channel occurring through an intermediate state lying between these two excitation energies. Finally, 266 nm excitation of the ferrous species is dominated by the photooxidation channel with formation of the ferric complex as main photoproduct. However, we observe an additional minor photoproduct, which is identical to the 266 nm generated photoproduct of the ferric species, suggesting that under our experimental conditions, the pump pulse photooxidises the ferrous complex and re-excites the primary ferric photoproduct. PMID:26798775

  9. [Study of cancer cells fluorescence lifetime based on picosecond time resolution].

    PubMed

    Chen, Bi-Fang; Liu, Tian-Fu

    2006-08-01

    The object of the present study was the ultrafast photodynamic processes of hematoporphyrin derivative (HPD) for diagnosis and therapy of cancer. Time-resolved fluorescence spectra of cancerous and normal cells were measured using an ultrashort pulse laser spectral technique and picosecond time-correlated single-photon counting system. The fast part of cancerous and normal cells fluorescence decay was approximately 150 and 300 ps, the fluorescence peak intensity of cancerous and normal cells decayed about 10% and 55% in 12 hour, the lifetime of cancerous and normal cells was about 824 and 1 798 ps by calculating date of fluorescence decay, and HPD stay time was about 17 and 6 days in the cancerous and normal cells sample respectively. The data show that cancerous cells were greatly intimate with HPD. The results obtained can be used as an important basis for the diagnosis of cancer based on ultrashort pulse laser spectral technique. The results will contribute to feebleness ultrafast fluorescence of biology sample for real time measurement. PMID:17058959

  10. Picosecond kinetic absorption and fluorescence studies of bovine rhodopsin with a fixed 11-ene.

    PubMed Central

    Buchert, J; Stefancic, V; Doukas, A G; Alfano, R R; Callender, R H; Pande, J; Akita, H; Balogh-Nair, V; Nakanishi, K

    1983-01-01

    A synthetic retinal having a fixed 11-cis geometry has been used to prepare a nonbleachable analogue of bovine rhodopsin. Marked differences in the picosecond absorption and fluorescence behavior of this analogue at room temperature, compared with that of natural rhodopsin, were observed. This not only indicates that the 11-cis to trans isomerization of the retinal moiety is the crucial primary event in the photolysis of rhodopsin, but also it establishes that this isomerization must occur on the picosecond time scale or faster. PMID:6626668

  11. Fluorescence and picosecond laser photolysis studies on the deactivation processes of excited hydrogen bonding systems

    NASA Astrophysics Data System (ADS)

    Ikeda, Noriaka; Okada, Tadashi; Mataga, Noboru

    1980-01-01

    The fluorescence quenching reaction of 2-naphthylamine and 1-pyrenol due to hydrogen bonding interaction with pyndine has been investigated Absorption spectra due to the state formed by charge transfer from excited naphthylamine to hydrogen bonded pyridine have been observed by means of picosecond laser photolysis.

  12. Study on third-order nonlinear optical properties of 4-methylsulfanyl chalcone derivatives using picosecond pulses

    SciTech Connect

    D'silva, E.D.; Podagatlapalli, G. Krishna; Venugopal Rao, S.; Dharmaprakash, S.M.

    2012-11-15

    Graphical abstract: Photograph and schematic representation of Z-scan experimental setup used to investigate third order nonlinear properties of the chalcone materials. Highlights: ► Br and NO{sub 2} substituted chalcone derivatives were exposed to picosecond laser pulses. ► Third-order nonlinear optical (NLO) properties were investigated. ► Compounds show promising third-order and optical limiting properties. ► These materials found suitable for electrical and optical applications. -- Abstract: In this paper we present results from the experimental study of third-order nonlinear optical (NLO) properties of three molecules of Br and NO{sub 2} substituted chalcone derivatives namely (2E)-1-(4-bromophenyl)-3-[4(methylsulfanyl)phenyl]prop-2-en-1-one (4Br4MSP), (2E)-1-(3-bromophenyl)-3-[4-(methylsulfanyl) phenyl]prop-2-en-1-one (3Br4MSP) and (2E)-3[4(methylsulfanyl) phenyl]-1-(4-nitrophenyl)prop-2-en-1-one (4N4MSP). The NLO properties have been investigated by Z-scan technique using 2 ps laser pulses at 800 nm. The nonlinear refractive indices, nonlinear absorption coefficient, and the magnitude of third-order susceptibility have been determined. The values obtained are of the order of 10{sup −7} cm{sup 2}/GW, 10{sup −3} cm/GW and 10{sup −14} esu respectively. The molecular second hyperpolarizability for the chalcone derivatives is of the order of 10{sup −32} esu. The coupling factor, excited state cross section, ground state cross section etc. were determined. The optical limiting (OL) property was studied. The results suggest that the nonlinear properties investigated for present chalcones are comparable with some of the reported chalcone derivatives and can be desirable for NLO applications.

  13. Infrared detection with high-{Tc} bolometers and response of Nb tunnel junctions to picosecond voltage pulses

    SciTech Connect

    Verghese, S.

    1993-05-01

    Oxide superconductors with high critical temperature {Tc} make sensitive thermometers for several types of infrared bolometers. The authors built composite bolometers with YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} thermometers on sapphire substrates which have higher sensitivity than competing thermal detectors which operate at temperatures above 77 K. A 1 x 1 mm bolometer with gold black serving as the radiation absorber has useful sensitivity for wavelengths 20--100 {mu}m. A 3 x 3 mm bolometer with a bismuth film as the absorber operates from 20--100 {mu}m. High-{Tc} bolometers which are fabricated with micromachining techniques on membranes of Si or Si{sub 3}N{sub 4} have potential application to large-format arrays which are used for infrared imaging. A nonisothermal high-{Tc} bolometer can be fabricated on a membrane of yttria-stabilized zirconia (YSZ) which is in thermal contact with the heat sink along the perimeter of the membrane. A thermal analysis indicates that the YSZ membrane bolometer can have improved sensitivity compared to the sapphire bolometer for spectrometer applications. The quasiparticle tunneling current in a superconductor-insulator-superconductor (SIS) junction is highly nonlinear in the applied voltage. The authors have made the first measurement of the linear response of the quasiparticle current in a Nb/AlO{sub x}/Nb junction over a broad bandwidth from 75--200 GHz. Nonlinear measurements made with these pulses may provide information about the quasiparticle lifetime. Preliminary data from such measurements are presented.

  14. Photoionization-induced π↔ H site switching dynamics in phenol(+)-Rg (Rg = Ar, Kr) dimers probed by picosecond time-resolved infrared spectroscopy.

    PubMed

    Miyazaki, Mitsuhiko; Sakata, Yuri; Schütz, Markus; Dopfer, Otto; Fujii, Masaaki

    2016-09-21

    The ionization-induced π↔ H site switching reaction in phenol(+)-Rg (PhOH(+)-Rg) dimers with Rg = Ar and Kr is traced in real time by picosecond time-resolved infrared (ps-TRIR) spectroscopy. The ps-TRIR spectra show the prompt appearance of the non-vanishing free OH stretching band upon resonant photoionization of the π-bound neutral clusters, and the delayed appearance of the hydrogen-bonded (H-bonded) OH stretching band. This result directly proves that the Rg ligand switches from the π-bound site on the aromatic ring to the H-bonded site at the OH group by ionization. The subsequent H →π back reaction converges the dimer to a π↔ H equilibrium. This result is in sharp contrast to the single-step π→ H forward reaction in the PhOH(+)-Ar2 trimer with 100% yield. The reaction mechanism and yield strongly depend on intracluster vibrational energy redistribution. A classical rate equation analysis for the time evolutions of the band intensities of the two vibrations results in similar estimates for the time constants of the π→ H forward reaction of τ+ = 122 and 73 ps and the H →π back reaction of τ- = 155 and 188 ps for PhOH(+)-Ar and PhOH(+)-Kr, respectively. The one order of magnitude slower time constant in comparison to the PhOH(+)-Ar2 trimer (τ+ = 7 ps) is attributed to the decrease in density of states due to the absence of the second Ar in the dimer. The similar time constants for both PhOH(+)-Rg dimers are well rationalized by a classical interpretation based on the comparable potential energy surfaces, reaction pathways, and density of states arising from their similar intermolecular vibrational frequencies. PMID:27550720

  15. High power mid-infrared supercontinuum generation in a single-mode ZBLAN fiber pumped by amplified picosecond pulses at 2 μm

    NASA Astrophysics Data System (ADS)

    Liu, Kun; Liu, Jiang; Shi, Hongxing; Tan, Fangzhou; Jiang, Yijian; Wang, Pu

    2015-03-01

    We report high power all fiber mid-infrared (mid-IR) supercontinuum (SC) generation in a single-mode ZBLAN (ZrF4- BaF2-LaF3-AlF3-NaF) fiber with up to 21.8 W average output power from 1.9 to beyond 3.8 μm pumped by amplified picosecond pulses from a master oscillator power amplifier (MOPA) based on small-core single-mode thulium-doped fiber (TDF) with injected seed pulse width of 24 ps and repetition of 93.6 MHz at 1963 nm. The optical-optical conversion efficiency from the 793 nm pump laser of the last stage thulium-doped fiber amplifier (TDFA) to mid-IR SC output is 17%. It is, to the best of our knowledge, the highest average power mid-IR SC generation in a ZBLAN fiber to date. In addition, a noise-like fiber oscillator based on a nonlinear loop mirror (NOLM) with wavepacket width of ~1.4 ns and repetition rate of 3.36 MHz at 1966 nm is also used as a seed of the MOPA for mid-IR SC generation in the ZBLAN fiber. At last, a mid-IR SC from 1.9 to beyond 3.6 μm with average output power of 14.3W, which is limited by injected noise-like pulses power, is generated. The optical-optical conversion efficiency from the 793 nm pump laser of the last stage TDFA to mid-IR SC output is 14.9%. This proves the amplified noise-like pulses are also appropriate for high power mid-IR SC generation in the ZBLAN fiber.

  16. Homogenization of tissues via picosecond-infrared laser (PIRL) ablation: Giving a closer view on the in-vivo composition of protein species as compared to mechanical homogenization

    PubMed Central

    Kwiatkowski, M.; Wurlitzer, M.; Krutilin, A.; Kiani, P.; Nimer, R.; Omidi, M.; Mannaa, A.; Bussmann, T.; Bartkowiak, K.; Kruber, S.; Uschold, S.; Steffen, P.; Lübberstedt, J.; Küpker, N.; Petersen, H.; Knecht, R.; Hansen, N.O.; Zarrine-Afsar, A.; Robertson, W.D.; Miller, R.J.D.; Schlüter, H.

    2016-01-01

    Posttranslational modifications and proteolytic processing regulate almost all physiological processes. Dysregulation can potentially result in pathologic protein species causing diseases. Thus, tissue species proteomes of diseased individuals provide diagnostic information. Since the composition of tissue proteomes can rapidly change during tissue homogenization by the action of enzymes released from their compartments, disease specific protein species patterns can vanish. Recently, we described a novel, ultrafast and soft method for cold vaporization of tissue via desorption by impulsive vibrational excitation (DIVE) using a picosecond-infrared-laser (PIRL). Given that DIVE extraction may provide improved access to the original composition of protein species in tissues, we compared the proteome composition of tissue protein homogenates after DIVE homogenization with conventional homogenizations. A higher number of intact protein species was observed in DIVE homogenates. Due to the ultrafast transfer of proteins from tissues via gas phase into frozen condensates of the aerosols, intact protein species were exposed to a lesser extent to enzymatic degradation reactions compared with conventional protein extraction. In addition, total yield of the number of proteins is higher in DIVE homogenates, because they are very homogenous and contain almost no insoluble particles, allowing direct analysis with subsequent analytical methods without the necessity of centrifugation. Biological significance Enzymatic protein modifications during tissue homogenization are responsible for changes of the in-vivo protein species composition. Cold vaporization of tissues by PIRL-DIVE is comparable with taking a snapshot at the time of the laser irradiation of the dynamic changes that occur continuously under in-vivo conditions. At that time point all biomolecules are transferred into an aerosol, which is immediately frozen. PMID:26778141

  17. Infrared sky noise study

    NASA Technical Reports Server (NTRS)

    Westphal, J. A.

    1972-01-01

    The hardware and techniques to measure and compare sky noise at several sites were studied, and a device was developed that would maximize its output and minimize its output for modulation. The instrument and its functions are described. The nature of sky emissions and the fluctuation, gaseous sources of sky noise, and aerosol sources are discussed. It is concluded that sky noise really exists, and the spatial distribution of the sky noise sources are such that observed noise values are linear functions of chopping stroke.

  18. Picosecond lasers: the next generation of short-pulsed lasers.

    PubMed

    Freedman, Joshua R; Kaufman, Joely; Metelitsa, Andrea I; Green, Jeremy B

    2014-12-01

    Selective photothermolysis, first discussed in the context of targeted microsurgery in 1983, proposed that the optimal parameters for specific thermal damage rely critically on the duration over which energy is delivered to the tissue. At that time, nonspecific thermal damage had been an intrinsic limitation of all commercially available lasers, despite efforts to mitigate this by a variety of compensatory cooling mechanisms. Fifteen years later, experimental picosecond lasers were first reported in the dermatological literature to demonstrate greater efficacy over their nanosecond predecessors in the context of targeted destruction of tattoo ink. Within the last 4 years, more than a decade after those experiments, the first commercially available cutaneous picosecond laser unit became available (Cynosure, Westford, Massachusetts), and several pilot studies have demonstrated its utility in tattoo removal. An experimental picosecond infrared laser has also recently demonstrated a nonthermal tissue ablative capability in soft tissue, bone, and dentin. In this article, we review the published data pertaining to dermatology on picosecond lasers from their initial reports to the present as well as discuss forthcoming technology. PMID:25830248

  19. Picosecond and nanosecond studies of the photoreduction of benzophenone by N,N-diethylaniline and triethylamine

    SciTech Connect

    Devadoss, C.; Fessenden, R.W. )

    1991-09-19

    The photoreduction of benzophenone by N,N-diethylaniline and triethylamine has been examined in a number of solvents by both nano- and picosecond laser photolysis. With diethylaniline, electron transfer is the primary step and the spectrum of the ion pair has been detected even in nonpolar solvents such as benzene and cyclohexane. Rapid proton transfer then takes place to form a high yield of the ketyl radical. The lifetime of the ion pair in benzene is about 900 ps. In acetonitrile, the ion pair dissociated into individual ions which then decay by back electron transfer and proton transfer. A spectral shift to the red occurs over 100 ps as the contact ion pair dissociated. In acidic alcohols such as methanol and trifluoroethanol, proton transfer from the alcohol occurs to produce the ketyl radical. In the case of triethylamine, no distinct absorption band for benzophenone anion was seen in picosecond experiments but difference spectra, which removed much of the spectrum of benzophenone triplet, clearly showed some contribution from the anion. For this compound, it is likely that electron transfer occurs first followed by very fast proton transfer.

  20. UV photolysis of nitromethane studied by sub-picosecond time-resolved CARS experiments

    SciTech Connect

    Rajchenbach, C.; Jonusauskas, G.; Rulliere, C.

    1996-04-01

    Using sub-picosecond CARS experiment we observed direct photolysis of liquid nitromethane after pulse excitation at 299 nm. We measured the dynamics behavior under excitation of three main ground state Raman lines: the {nu} (CN) mode at 917 cm{sup -1}, the {nu}s(NO2) and {delta}s(CH3) modes near 1400 cm{sup -1} and the {nu}s(CH3) mode at 2968 cm{sup -1}. From the evolution of these modes we deduced that the excited state disappears with a lifetime of 1.1{+-}0.3 ps and we measured a photolysis quantum yield at 299 nm of 24%{+-}5%. Important and fast non-radiative desexcitation channel from excited to ground states has been observed.

  1. Picosecond vibrational cooling in mixed molecular crystals studied with a new coherent raman scattering technique

    NASA Astrophysics Data System (ADS)

    Chang, Ta-Chau; Dlott, Dana D.

    1988-05-01

    We demonstrate the pump-induced coherent Stokes Raman scattering (CSRS) technique by measuring vibrational cooling in low temperature crystals of pentacene in naphthalene following excitation of a vibration 747 cm -1 above the S 1 origin. Using picosecond photon echoes and a two-color pump-probe technique, we find that the initial state decays in 33 ps, and reappears at the origin 25 ps later. We show that pump-induced CSRS simultaneously measures the decay from the initial state and reappearance at the origin. This technique has many of the advantages of conventional coherent Raman (e.g. intense coherent signals), but is a direct measure of the population dynamics in the initial and final states.

  2. Picosecond ultrasonic study of surface acoustic waves on titanium nitride nanostructures

    SciTech Connect

    Bjornsson, M. M.; Connolly, A. B.; Mahat, S.; Rachmilowitz, B. E.; Daly, B. C.; Antonelli, G. A.; Myers, A.; Singh, K. J.; Yoo, H. J.; King, S. W.

    2015-03-07

    We have measured surface acoustic waves on nanostructured TiN wires overlaid on multiple thin films on a silicon substrate using the ultrafast pump-probe technique known as picosecond ultrasonics. We find a prominent oscillation in the range of 11–54 GHz for samples with varying pitch ranging from 420 nm down to 168 nm. We find that the observed oscillation increases monotonically in frequency with decrease in pitch, but that the increase is not linear. By comparing our data to two-dimensional mechanical simulations of the nanostructures, we find that the type of surface oscillation to which we are sensitive changes depending on the pitch of the sample. Surface waves on substrates that are loaded by thin films can take multiple forms, including Rayleigh-like waves, Sezawa waves, and radiative (leaky) surface waves. We describe evidence for detection of modes that display characteristics of these three surface wave types.

  3. Picosecond Chemical and Biological Events.

    ERIC Educational Resources Information Center

    Rentzepis, P. M.

    1978-01-01

    Describes a currently used picosecond spectroscopy system capable of reliably recording picosecond events. Two areas of picosecond research are discussed: one concerns the interaction of electrons in fluids; the second, the primary events in vision. (Author/HM)

  4. Picosecond study of energy transfer between rhodamine 6G and 3,3'-diethylthiacarbocyanine iodide in the premicellar region: förster mechanism with increased local concentration

    NASA Astrophysics Data System (ADS)

    Sato, Hiroyasu; Kusumoto, Yoshihumi; Nakashima, Nobuaki; Yoshihara, Keitaro

    1980-04-01

    The mechanism of enhancement in the energy transfer between rhodamine 6G and 3,3'-diethylthiacarbocyanine iodide by sodium lauryl sulfate in the premicellar region was studied by a picosecond laser technique. The Forster mechanism with an increased local concentration suggesting dye-rich induced micelle formation was concluded from the shape of the decay curve.

  5. An investigation into the photochemistry of, and the electrochemically induced CO-loss from, [(CO)5MC(OMe)Me](M = Cr or W) using low-temperature matrix isolation, picosecond infrared spectroscopy, cyclic voltammetry, and time-dependent density functional theory.

    PubMed

    McMahon, Suzanne; Amirjalayer, Saeed; Buma, Wybren J; Halpin, Yvonne; Long, Conor; Rooney, A Denise; Woutersen, Sander; Pryce, Mary T

    2015-09-21

    The photophysics and photochemistry of [(CO)5MC(OMe)Me] (M = Cr or W) were investigated using picosecond time-resolved infrared spectroscopy (M = Cr or W), low-temperature matrix isolation techniques (M = Cr), and time-dependent density functional calculations (M = Cr or W). These studies provide unambiguous evidence for the photochemical formation of a long-lived, 18-electron metallaketene species capable of acting as a synthetically useful intermediate. For the Cr complex, an intermediate metallacyclopropanone singlet excited state was detected on the reaction path to the metallaketene species. This metallacyclopropanone excited state species has a lifetime of less than 100 ps and a characteristic bridging carbonyl band at 1770 cm(-1). The tungsten ketene species was also detected but in contrast to the chromium system, this forms directly from a low-lying triplet excited state. The electrochemical release of CO showed a greater efficiency for the chromium complex when compared to the tungsten. PMID:26089130

  6. Transient picosecond studies of singlet fission in PDTP-DFBT low band gap polymer

    NASA Astrophysics Data System (ADS)

    Huynh, Uyen; Vardeny, Valy; Li, Gang; Yang, Yang

    2014-03-01

    We measured picoseconds transient mid-IR photoinduced absorption (PA) spectra in PDTP-DFBT low band-gap polymer. With 800 nm pumping the PA spectrum at t =0 in pristine film and isolated polymer chain in polystyrene shows two prominent PA bands: PA1 at 0.4eV and Pa2 at 0.8eV. PA1 is assigned to absorption from singlet excitons (transition from 1Bu to mAg) , whereas PA2 is due to a state of triplet-pair, which is formed via singlet fission in the sub-ps time domain. We found that PA2 lifetime strongly depends on the excitation intensity, showing non linear recombination process in both pristine film and in polystyrene. We also found that the triplet-pair recombines with no trace of fusion back to the singlet exciton; we thus conclude that singlet fission is an exothermic process in this polymer. We therefore do not find any magnetic field effect on the transient dynamics of the triplet-pair within our experimental sensitivity (0.2%). Supported by DOE and NSF-MRSEC.

  7. Picosecond spectroscopic studies of energy transfer in phycobiliproteins and model dye systems

    SciTech Connect

    Switalski, S.C.

    1987-02-01

    Energy transfer was investigated in the ..cap alpha beta.. monomer and separated ..cap alpha.. and ..beta.. subunits of C-phycocyanin from Anabaena variabilis and Anacystis nidulans, using steady-state and picosecond spectroscopy. Fluorescence excitation polarization spectra were consistent with a sensitizing (s) - fluorescing (f) model using a Forster energy transfer mechanism. The rise in polarization across the absorption band towards longer wavelength for the ..beta.. subunit and the ..cap alpha beta.. monomer was attributed to energy transfer among the three chromophores in the ..cap alpha beta.. monomer and between the 2 chromophores in the ..beta.. subunit. The constant polarization of the ..cap alpha.. subunit, with one chromophore, is consistent with a lack of any possibility of energy transfer. Fluorescence emission maxima were at 640 nm for the ..cap alpha beta.. monomer and the separated subunits of Anabaena variabilis, and 645 nm for the ..beta.. subunit, 640 nm for the ..cap alpha.. subunit, and 644 nm for ..cap alpha beta.. monomer of Anacystis nidulans. We have shown that the labels s and f are not consistent with all the steady-state spectroscopic results. 171 refs., 32 figs., 15 tabs.

  8. Picosecond optoelectronic devices

    SciTech Connect

    Lee, C.L.

    1984-01-01

    Ever since the invention of picosecond lasers, scientists and electronic engineers have been dreaming of inventing electronic devices that can record in real time the physical and electronic events that take place on picosecond time scales. With the exception of the expensive streak camera, this dream has been largely unfullfilled. Today, a real-time oscilloscope with picosecond time resolution is still not available. To fill the need for even better time resolution, researchers have turned to optical pulses and thus a hybrid technology has emerged-picosecond optoelectronics. This technology, based on bulk photoconductors, has had a slow start. However, because of the simplicity, scaleability, and jitterfree nature of the devices, the technology has recently experienced a rapid growth. This volume reviews the major developments in the field of picosecond optoelectronics over the past decade.

  9. The interplay of protein and solvent picosecond dynamics: Experimental and theoretical studies

    NASA Astrophysics Data System (ADS)

    He, Yunfen

    Terahertz gap is located between microwaves and infrared. THz-TDS is based on the generation of subpicosecond terahertz pulses using ultrashort laser pulses with pulse durations of a few femtoseconds. From the spectroscopic point of view terahertz radiation excites the low frequency vibrations of molecules. Terahertz spectroscopy provides a new way to study protein dynamics in this critical frequency range. The strong temperature dependence of molecular flexibility near 200 K for proteins and polynucleotides hydrated above 30% by weight, dynamical transition, is one of the most significant phenomena of biomolecular dynamics. Measurements of the dynamical transition were performed for native, fully denatured and unstructured polypeptides using THz-TDS. The results reveal that the dynamical transition is independent of either tertiary or secondary structure. The transition are also found for shorter chain alanine peptides down to penta-alanine, which indicates that a quantitative predictive theory for the temperature dependence lies in the understanding of the interaction of the side chains of the poly peptide or poly nucleotide with the biological water. The far infrared vibrational modes can be calculated using harmonic or anharmonic normal mode analysis, and the resulting Density of States (DOS) strongly resembles the measured absorbance. A large contrast in the terahertz dielectric response between oxidized and reduced cytochrome c has lready been observed experimentally. This large contrast has been associated with a change in the collective structural motions that related to protein flexibility. Molecular simulation results from quasiharmonic analysis and dipole-dipole correlation analysis are compared with the measurements to determine the relative contribution of correlated motions and diffusive motions to the measured dielectric response. The measured hydration dependence is reproduced by hydration dependence of quasiharmonic normal modes, but these modes

  10. Infrared-infrared double resonance study of methyl alcohol

    NASA Astrophysics Data System (ADS)

    Goulding, R. R. J.; Mukhopadhyay, I.; Lees, R. M.

    1992-09-01

    In this work we carried out an infrared-infrared (IR-IR) double resonance (DR) study of methyl alcohol using a CO 2 laser and a lead salt diode laser, in order to confirm previously proposed far-infrared (FIR) laser assignments for the 9P(34) and 9P(16) CO 2 laser lines. For the 9P(34) CO 2 laser line it is confirmed that the pump radiation excites the torsionally excited Q(125, 9) transition of methyl alcohol in agreement with the assignments proposed earlier. From the study it was noticed that due to the pump radiation, transitions which are not connected by dipole selection rules either to the lower or upper pumped level were also affected. Thus it appears that four-level IR-IR DR experiments are unlikely to provide useful information for transition assignments. The diode laser study was coupled with a recent spectroscopic study using a high resolution Fourier transform spectrometer to detect and identify hot band and perturbation allowed transitions in CH 3OH.

  11. Charge recombination reactions in photoexcited C[sub 60]-amine complexes studied by picosecond pump probe spectroscopy

    SciTech Connect

    Ghosh, H.N.; Pal, H.; Sapre, A.V.; Mittal, J.P. )

    1993-12-15

    Photoexcitation of complexes between fullerence C[sub 60] and organic amines in benzene solutions is known to result in charge separation (CS) and subsequent charge recombination (CR) reactions, which lead to varying yields of fullerence triplet formation. Picosecond flash photolysis studies are carried out on C[sub 60]-diphenylamine (DPA), C[sub 60]-triethylamine (TEA), C[sub 60]-diazabicyclooctane (DABCO), and C[sub 60]-triphenylamine (TPA) systems to find out mechanistic details of the triplet formation on CR by inducing heavy atom and polarity effects by using suitable solvents. It is found that in the case of C[sub 60]-DPA, C[sub 60]-TEA, and C[sub 60]-DABCO systems proton transfer from the amine cation to the C[sub 60] anion in the ion pair state dominates, leading to poor triplet yields, which improve in heavy atom containing solvents. In TPA, proton transfer is not possible and hence fullerene triplet yields are high. Increase of solvent polarity for this system results in decreased C[sub 60] triplet yields with a consequent increase in the ion dissociation yield. A suitable reaction scheme is proposed to explain the results obtained. 34 refs., 5 figs., 2 tabs.

  12. PLEIADES: a picosecond Compton scattering x-ray source for advanced backlighting and time-resolved material studies

    SciTech Connect

    Gibson, D J; Anderson, S G; Barty, C P; Betts, S M; Booth, R; Brown, W J; Crane, J K; Cross, R R; Fittinghoff, D N; Hartemann, F V; Kuba, J; Le Sage, G P; Tremaine, A M; Springer, P T; Rosenzweig, J B

    2003-10-20

    The PLEIADES (Picosecond Laser-Electron Inter-Action for the Dynamical Evaluation of Structures) facility has produced first light at 70 keV. This milestone offers a new opportunity to develop laser-driven, compact, tunable x-ray sources for critical applications such as diagnostics for the National Ignition Facility and time-resolved material studies. The electron beam was focused to 50 {micro}m rms, at 57 MeV, with 260 C of charge, a relative energy spread of 0.2%, and a normalized emittance of 5 mm mrad horizontally and 13 mm mrad vertically. The scattered 820-nm laser pulse had an energy of 180 mJ and a duration of 54 fs. Initial x-rays were captured with a cooled charge-coupled device using a Cesium Iodide scintillator; the peak photon energy was approximately 78 keV, with a total x-ray flux of 1.3 x 10{sup 6} photons/shot, and the observed angular distribution found to agree very well with three-dimensional codes. Simple K-edge radiography of a tantalum foil showed good agreement with the theoretical divergence-angle dependence of the x-ray energy. Optimization of the x-ray dose is currently underway, with the goal of reaching 10{sup 8} photons per shot and a peak brightness approaching 10{sup 20} photons/mm{sup 2}/mrad{sup 2}/s/0.1%bandwidth.

  13. Laser-driven phase transitions in aqueous colloidal gold nanoparticles under high pressure: picosecond pump-probe study.

    PubMed

    Hashimoto, Shuichi; Katayama, Tetsuro; Setoura, Kenji; Strasser, Michael; Uwada, Takayuki; Miyasaka, Hiroshi

    2016-02-14

    Pump-probe transient extinction spectroscopy was used to analyze 355 nm picosecond laser heating-induced phenomena in 60 nm-diameter aqueous gold nanoparticles (AuNPs) under a high pressure of 60 MPa. Kinetic spectroscopy revealed that a supercritical layer surrounding the AuNP nucleated with a lifetime of approximately 1 ns during its dynamic expansion and decay for a fluence of 19.6 mJ cm(-2). Moreover, in the post-mortem transmission electron micrographs we observed a number of fragments, a small percentage of size-reduced cores, and erupted particles among the intact particles after 60 shots, suggesting that evaporation occurred under laser illumination. The particle temperature calculation indicated that evaporation begins with a liquid droplet AuNP surrounded by a supercritical layer at temperatures below the boiling point of gold. By applying high pressure, we obtained a clear picture of the evaporation event, which was not possible at ambient pressure because bubble formation caused particle temperatures to rise uncontrollably. In this study, we shed light on the critical role of the supercritical layer formed around the AuNP under high pressure during laser-induced evaporation. PMID:26812175

  14. Broadly tunable picosecond ir source

    DOEpatents

    Campillo, A.J.; Hyer, R.C.; Shapiro, S.L.

    1980-04-23

    A picosecond traveling-wave parametric device capable of controlled spectral bandwidth and wavelength in the infrared is reported. Intense 1.064 ..mu..m picosecond pulses (1) pass through a 4.5 cm long LiNbO/sub 3/ optical parametric oscillator crystal (2) set at its degeneracy angle. A broad band emerges, and a simple grating (3) and mirror (4) arrangement is used to inject a selected narrow-band into a 2 cm long LiNbO/sub 3/ optical parametric amplifier crystal (5) along a second pump line. Typical input energies at 1.064 ..mu..m along both pump lines are 6 to 8 mJ for the oscillator and 10 mJ for the amplifier. This yields 1 mJ of tunable output in the range 1.98 to 2.38 ..mu..m which when down-converted in a 1 cm long CdSe crystal mixer (6) gives 2 ..mu..J of tunable radiation over the 14.8 to 18.5 ..mu..m region. The bandwidth and wavelength of both the 2 and 16 ..mu..m radiation output are controlled solely by the diffraction grating.

  15. Broadly tunable picosecond IR source

    DOEpatents

    Campillo, Anthony J.; Hyer, Ronald C.; Shapiro, Stanley J.

    1982-01-01

    A picosecond traveling-wave parametric device capable of controlled spectral bandwidth and wavelength in the infrared is reported. Intense 1.064 .mu.m picosecond pulses (1) pass through a 4.5 cm long LiNbO.sub.3 optical parametric oscillator crystal (2) set at its degeneracy angle. A broad band emerges, and a simple grating (3) and mirror (4) arrangement is used to inject a selected narrow-band into a 2 cm long LiNbO.sub.3 optical parametric amplifier crystal (5) along a second pump line. Typical input energies at 1.064 .mu.m along both pump lines are 6-8 mJ for the oscillator and 10 mJ for the amplifier. This yields 1 mJ of tunable output in the range 1.98 to 2.38 .mu.m which when down-converted in a 1 cm long CdSe crystal mixer (6) gives 2 .mu.J of tunable radiation over the 14.8 to 18.5 .mu.m region. The bandwidth and wavelength of both the 2 and 16 .mu.m radiation output are controlled solely by the diffraction grating.

  16. Electron thermalization and trapping rates in pure and doped alkali and alkaline-earth iodide crystals studied by picosecond optical absorption

    NASA Astrophysics Data System (ADS)

    Ucer, K. B.; Bizarri, G.; Burger, A.; Gektin, A.; Trefilova, L.; Williams, R. T.

    2014-04-01

    Although light continues to be emitted from insulating crystals used as scintillators over a period of nanoseconds to microseconds after stopping of an energetic particle, much of what determines the nonlinearity of response goes on in the first picoseconds. On this time scale, free carriers and excitons are at high density near the track core and thus are subject to nonlinear quenching. The hot (free) electrons eventually cool to low enough energy that trapping on holes, dopants, or defects can commence. In the track environment, spatial distributions of trapped carriers determined on the picosecond time scale can influence the proportionality between light yield and the initial particle energy throughout the whole light pulse. Picosecond spectroscopy of optical absorption induced by a short pulse of above-gap excitation provides a useful window on what occurs during the crucial early evolution of excited populations. The laser excitation can be tuned to excite carriers that are initially very hot (˜3 eV) relative to the band edges, or that are almost thermalized (˜0.1 eV excess energy) at the outset. Undoped and doped samples of NaI:Tl(0%, 0.1%), CsI:Tl(0%, 0.01%, 0.04%, 0.3%), and SrI2:Eu(0%, 0.2%, 0.5%, 3%) are studied in this work.

  17. Picosecond Imaging Circuit Analysis

    NASA Astrophysics Data System (ADS)

    Kash, Jeffrey A.

    1998-03-01

    With ever-increasing complexity, probing the internal operation of a silicon IC becomes more challenging. Present methods of internal probing are becoming obsolete. We have discovered that a very weak picosecond pulse of light is emitted by each FET in a CMOS circuit whenever the circuit changes logic state. This pulsed emission can be simultaneously imaged and time resolved, using a technique we have named Picosecond Imaging Circuit Analysis (PICA). With a suitable imaging detector, PICA allows time resolved measurement on thousands of devices simultaneously. Computer videos made from measurements on real IC's will be shown. These videos, along with a more quantitative evaluation of the light emission, permit the complete operation of an IC to be measured in a non-invasive way with picosecond time resolution.

  18. A high accuracy femto-/picosecond laser damage test facility dedicated to the study of optical thin films

    SciTech Connect

    Mangote, B.; Gallais, L.; Zerrad, M.; Lemarchand, F.; Gao, L. H.; Commandre, M.; Lequime, M.

    2012-01-15

    A laser damage test facility delivering pulses from 100 fs to 3 ps and designed to operate at 1030 nm is presented. The different details of its implementation and performances are given. The originality of this system relies the online damage detection system based on Nomarski microscopy and the use of a non-conventional energy detection method based on the utilization of a cooled CCD that offers the possibility to obtain the laser induced damage threshold (LIDT) with high accuracy. Applications of this instrument to study thin films under laser irradiation are presented. Particularly the deterministic behavior of the sub-picosecond damage is investigated in the case of fused silica and oxide films. It is demonstrated that the transition of 0-1 damage probability is very sharp and the LIDT is perfectly deterministic at few hundreds of femtoseconds. The damage process in dielectric materials being the results of electronic processes, specific information such as the material bandgap is needed for the interpretation of results and applications of scaling laws. A review of the different approaches for the estimation of the absorption gap of optical dielectric coatings is conducted and the results given by the different methods are compared and discussed. The LIDT and gap of several oxide materials are then measured with the presented instrument: Al{sub 2}O{sub 3}, Nb{sub 2}O{sub 5}, HfO{sub 2}, SiO{sub 2}, Ta{sub 2}O{sub 5}, and ZrO{sub 2}. The obtained relation between the LIDT and gap at 1030 nm confirms the linear evolution of the threshold with the bandgap that exists at 800 nm, and our work expands the number of tested materials.

  19. CO photodissociation dynamics in cytochrome P450BM3 studied by subpicosecond visible and mid-infrared spectroscopy.

    PubMed

    Rupenyan, Alisa; Commandeur, Jan; Groot, Marie Louise

    2009-07-01

    Cytochrome P450BM3 is a bacterial enzyme with a heme cofactor that binds small diatomic ligands. Here we report the first study of carbon monoxide (CO) photodissociation and rebinding in ferrous P450BM3 on an ultrafast time scale. We monitored dissociation of carbon monoxide upon Soret band excitation using visible and infrared femtosecond spectroscopy between 100 fs and 4 ns. The dynamics of the ferric P450 was probed for reference in the visible spectral region. In the photodissociated ferrous P450-CO complex, the vibrational hot deligated ground state is populated in 0.2 ps and relaxes on a picosecond time scale. The onset of geminate recombination of CO with the heme is observed on a nanosecond time scale. In the mid-infrared spectral region, the bleached absorption due to the bound C=O stretch vibration is constant on the picosecond to 1 ns time scale, indicating that the photodissociation yield is 100% and that rebinding occurs after 1 ns. In the infrared absorption difference spectra, we additionally resolve two small bands of dissociated CO molecules at 2092 and 2114 cm(-1). This indicates that the escape of photolyzed CO to solvent and the geminate recombination are preceded by transient docking within the protein in a manner similar to that of globins. The bands partially decay with a time constant of 1 ps, possibly due to a relaxation of the protein around the CO docking site, allowing for greater orientational freedom of the CO molecules. PMID:19492790

  20. Picosecond beam monitor

    DOEpatents

    Schutt, D.W.; Beck, G.O.

    1974-01-01

    The current in the beam of a particle accelerator is monitored with picosecond resolution by causing the beam to impinge upon the center conductor of a coaxial line, generating a pulse of electromagnetic energy in response thereto. This pulse is detected by means such as a sampling oscilloscope. (Official Gazette)

  1. Experimental study of the excitation of rhodium isomer in a plasma produced by a picosecond laser pulse

    SciTech Connect

    Afonin, V. I.; Kakshin, A. G.; Mazunin, A. V.

    2010-03-15

    Estimates and first experimental results on the excitation of a long-lived isomer state (E{sub m} = 39.756 keV, J{sup p} = 9/2{sup -}, and T{sub 1/2} = 56.114 min) of Rh{sup 103} nuclei under the action of X radiation in a hot solid-state-density rhodium plasma produced by a picosecond laser pulse in the SOKOL-P laser facility are presented.

  2. Studies on linear, nonlinear optical and excited state dynamics of silicon nanoparticles prepared by picosecond laser ablation

    NASA Astrophysics Data System (ADS)

    Hamad, Syed; Krishna Podagatlapalli, G.; Mounika, R.; Nageswara Rao, S. V. S.; Pathak, A. P.; Venugopal Rao, S.

    2015-12-01

    We report results from our studies on the fabrication and characterization of silicon (Si) nanoparticles (NPs) and nanostructures (NSs) achieved through the ablation of Si target in four different liquids using ˜2 picosecond (ps) pulses. The consequence of using different liquid media on the ablation of Si target was investigated by studying the surface morphology along with material composition of Si based NPs. The recorded mean sizes of these NPs were ˜9.5 nm, ˜37 nm, ˜45 nm and ˜42 nm obtained in acetone, water, dichloromethane (DCM) and chloroform, respectively. The generated NPs were characterized by selected area electron diffraction (SAED), high resolution transmission microscopy (HRTEM), Raman spectroscopic techniques and Photoluminescence (PL) studies. SAED, HRTEM and Raman spectroscopy data confirmed that the material composition was Si NPs in acetone, Si/SiO2 NPs in water, Si-C NPs in DCM and Si-C NPs in chloroform and all of them were confirmed to be polycrystalline in nature. Surface morphological information of the fabricated Si substrates was obtained using the field emission scanning electron microscopic (FESEM) technique. FESEM data revealed the formation of laser induced periodic surface structures (LIPSS) for the case of ablation in acetone and water while random NSs were observed for the case of ablation in DCM and chloroform. Femtosecond (fs) nonlinear optical properties and excited state dynamics of these colloidal Si NPs were investigated using the Z-scan and pump-probe techniques with ˜150 fs (100 MHz) and ˜70 fs (1 kHz) laser pulses, respectively. The fs pump-probe data obtained at 600 nm consisted of single and double exponential decays which were tentatively assigned to electron-electron collisional relaxation (<1 ps) and non-radiative transitions (>1 ps). Large third order optical nonlinearities (˜10-14 e.s.u.) for these colloids have been estimated from Z-scan data at an excitation wavelength of 680 nm suggesting that the

  3. Studies on linear, nonlinear optical and excited state dynamics of silicon nanoparticles prepared by picosecond laser ablation

    SciTech Connect

    Hamad, Syed; Nageswara Rao, S. V. S.; Pathak, A. P.; Krishna Podagatlapalli, G.; Mounika, R.; Venugopal Rao, S. E-mail: soma-venu@uohyd.ac.in

    2015-12-15

    We report results from our studies on the fabrication and characterization of silicon (Si) nanoparticles (NPs) and nanostructures (NSs) achieved through the ablation of Si target in four different liquids using ∼2 picosecond (ps) pulses. The consequence of using different liquid media on the ablation of Si target was investigated by studying the surface morphology along with material composition of Si based NPs. The recorded mean sizes of these NPs were ∼9.5 nm, ∼37 nm, ∼45 nm and ∼42 nm obtained in acetone, water, dichloromethane (DCM) and chloroform, respectively. The generated NPs were characterized by selected area electron diffraction (SAED), high resolution transmission microscopy (HRTEM), Raman spectroscopic techniques and Photoluminescence (PL) studies. SAED, HRTEM and Raman spectroscopy data confirmed that the material composition was Si NPs in acetone, Si/SiO{sub 2} NPs in water, Si-C NPs in DCM and Si-C NPs in chloroform and all of them were confirmed to be polycrystalline in nature. Surface morphological information of the fabricated Si substrates was obtained using the field emission scanning electron microscopic (FESEM) technique. FESEM data revealed the formation of laser induced periodic surface structures (LIPSS) for the case of ablation in acetone and water while random NSs were observed for the case of ablation in DCM and chloroform. Femtosecond (fs) nonlinear optical properties and excited state dynamics of these colloidal Si NPs were investigated using the Z-scan and pump-probe techniques with ∼150 fs (100 MHz) and ∼70 fs (1 kHz) laser pulses, respectively. The fs pump-probe data obtained at 600 nm consisted of single and double exponential decays which were tentatively assigned to electron-electron collisional relaxation (<1 ps) and non-radiative transitions (>1 ps). Large third order optical nonlinearities (∼10{sup −14} e.s.u.) for these colloids have been estimated from Z-scan data at an excitation wavelength of 680 nm

  4. Picosecond diffuse reflectance and transmission laser flash photolysis study of various triaryl-2-pyrazolines

    NASA Astrophysics Data System (ADS)

    Kelly, G. P.; Leicester, P. A.; Wilkinson, F.; Worrall, D. R.; Ferreira, L. F. Vieira; Chittock, R.; Toner, W.

    In this study the first ever reported application of diffuse reflectance laser flash photolysis for the observation of sub-nanosecond transient absorption decays is presented. The compounds studied are various triaryl-2-pyrazolines, both as microcrytals and contained within polycarbonate films. The microcrystalline samples were studied using pump—probe laser flash photolysis in diffuse reflectance mode and the observed transient absorption decay could be fitted using a biexponential model with, in the case of 1, 5-diphenyl-3-styryl-2-pyrazoline, lifetimes of 1.6 × 10 -10 and 1.3 × 10 -9s for the first and second decay components, respectively. This model could also be used to fit the decay kinetics obtained from transmission pump—probe laser flash photolysis experiments conducted upon polycarbonate films containing this same compound, the lifetimes in this instance being 5.5 × 10 -12 and 1.7 × 10 -10s for the first and second decay components, respectively. In addition, a study of the quenching of the pyrazoline excited states in a polycarbonate matrix by disulphone magenta was undertaken. In this case it was necessary to modify the second term of the biexponential model with a term to allow for Förster type long range energy transfer, the Förster critical transfer distance being determined as 25 Å. This biexponential model is rationalized as initial excitation being to the S2 state, the first decay component being relaxation to the S1 state and the second component decay of the S1 state to the ground state, by radiative and non-radiative relaxation and, when DSM is present, long range energy transfer to this energy acceptor.

  5. Development and study of picosecond start and trigger detector for high-energy heavy ion experiments

    NASA Astrophysics Data System (ADS)

    Yurevich, V. I.

    2015-07-01

    Two modular Cherenkov detectors based on MCP-PMTs XP85012 are developed for study Au+Au collisions in future experiments with beams of Nuclotron and collider NICA at JINR, Dubna. The detector arrays register high-energy photons and relativistic charged particles with aim of fast triggering the collisions and generation of start signal with time resolution better then 50 ps for TOF detector. The MC simulation showed the trigger efficiency of 100% for impact parameter range b<10 fm. The best time resolution for single detector channel σt≈21 ps was obtained with DRS4 digitizer in TOF measurements with a deuteron beam.

  6. INFRARED STUDIES OF EPSILON AURIGAE IN ECLIPSE

    SciTech Connect

    Stencel, Robert E.; Kloppenborg, Brian K.; Wall, Randall E.; Hopkins, Jeffrey L.; Howell, Steve B.; Hoard, D. W.; Rayner, John; Bus, Schelte; Tokunaga, Alan; Sitko, Michael L.; Bradford, Suellen; Russell, Ray W.; Lynch, David K.; Hammel, Heidi; Whitney, Barbara; Orton, Glenn; Yanamandra-Fisher, Padma; Hora, Joseph L.; Hinz, Philip; Hoffmann, William; and others

    2011-11-15

    We report here on a series of medium resolution spectro-photometric observations of the enigmatic long period eclipsing binary epsilon Aurigae, during its eclipse interval of 2009-2011, using near-infrared spectra obtained with SpeX on the Infrared Telescope Facility (IRTF), mid-infrared spectra obtained with BASS on AOES and IRTF, MIRSI on IRTF, and MIRAC4 on the MMT, along with mid-infrared photometry using MIRSI on IRTF and MIRAC4 on the MMT, plus 1995-2000 timeframe published photometry and data obtained with Denver's TNTCAM2 at WIRO. The goals of these observations included: (1) comparing eclipse depths with prior eclipse data, (2) confirming the re-appearance of CO absorption bands at and after mid-eclipse, associated with sublimation in the disk, (3) seeking evidence for any mid-infrared solid state spectral features from particles in the disk, and (4) providing evidence that the externally irradiated disk has azimuthal temperature differences. IR eclipse depths appear similar to those observed during the most recent (1983) eclipse, although evidence for post-mid-eclipse disk temperature increase is present, due to F star heated portions of the disk coming into view. Molecular CO absorption returned 57 days after nominal mid-eclipse, but was not detected at mid-eclipse plus 34 days, narrowing the association with differentially heated sub-regions in the disk. Transient He I 10830A absorption was detected at mid-eclipse, persisting for at least 90 days thereafter, providing a diagnostic for the hot central region. The lack of solid-state features in Spitzer Infrared Spectrograph, BASS, and MIRAC spectra to date suggests the dominance of large particles (micron-sized) in the disk. Based on these observations, mid-infrared studies out of eclipse can directly monitor and map the disk thermal changes, and better constrain disk opacity and thermal conductivity.

  7. Ultrafast protein dynamics of hemoglobin as studied by picosecond time-resolved resonance Raman spectroscopy

    NASA Astrophysics Data System (ADS)

    Mizutani, Yasuhisa; Nagai, Masako

    2012-03-01

    Time-resolved resonance Raman spectroscopy on human adult hemoglobin (HbA) following ligand photolysis revealed that the frequency of the iron-histidine stretching [ν(Fe-His)] mode exhibited a 2-cm-1 downshift with a time constant of about 300 ps, suggesting a structural change in the heme pocket following the ligand photolysis. Low-frequency heme modes suggested that the primary metastable form of HbA has a more disordered orientation of propionates and a less strained environment than the deoxy form. The latter fact is consistent with the experimental observation that the ν(Fe-His) frequency of the metastable form is higher than the deoxy form. The present study shows that HbA adopts a metastable structure within the instrument response time and remains little changed in the subnanosecond to nanosecond time regime. Characteristics of the primary protein response of HbA based on the comparison of the results of HbA with those of the isolated chains and myoglobin are discussed.

  8. Ab Initio Study of Hot Carriers in the First Picosecond after Sunlight Absorption in Silicon

    NASA Astrophysics Data System (ADS)

    Bernardi, Marco; Vigil-Fowler, Derek; Lischner, Johannes; Neaton, Jeffrey B.; Louie, Steven G.

    2014-06-01

    Hot carrier thermalization is a major source of efficiency loss in solar cells. Because of the subpicosecond time scale and complex physics involved, a microscopic characterization of hot carriers is challenging even for the simplest materials. We develop and apply an ab initio approach based on density functional theory and many-body perturbation theory to investigate hot carriers in semiconductors. Our calculations include electron-electron and electron-phonon interactions, and require no experimental input other than the structure of the material. We apply our approach to study the relaxation time and mean free path of hot carriers in Si, and map the band and k dependence of these quantities. We demonstrate that a hot carrier distribution characteristic of Si under solar illumination thermalizes within 350 fs, in excellent agreement with pump-probe experiments. Our work sheds light on the subpicosecond time scale after sunlight absorption in Si, and constitutes a first step towards ab initio quantification of hot carrier dynamics in materials.

  9. Study of surface relief gratings on azo organometallic films in picosecond regime.

    PubMed

    Luc, J; Bouchouit, K; Czaplicki, R; Fillaut, J-L; Sahraoui, B

    2008-09-29

    Materials for optical data storage and optical information processing must exhibit good holographic properties. Many materials for these applications have been already proposed. Here we describe a grating inscription process characterized by short inscription time and long-time stability. A series of ruthenium-acetylide organometallic complexes containing an azobenzene fragment were synthesized. Photo-induced gratings were produced by short pulse (16 ps, 532 nm) laser irradiation. The surface relief gratings formed at the same time were observed by atomic force microscope. In this work, we highlight the short inscription times brought into play as well as the good temporal stability of these gratings stored at room temperature. We study the influence of the polarization states and the light intensity of writing beams on the dynamics of the surface relief gratings formation and we compare these results with those of a known representative of azobenzene derivative (Disperse Red 1). Lastly, we show that it is possible to write two-dimensional surface relief gratings. PMID:18825202

  10. Mariner Jupiter/Saturn infrared instrument study

    NASA Technical Reports Server (NTRS)

    1972-01-01

    The Mariner Jupiter/Saturn infrared instrumentation conceptual design study was conducted to determine the physical and operational characteristics of the instruments needed to satisfy the experiment science requirements. The design of the instruments is based on using as many proven concepts as possible. Many design features are taken from current developments such as the Mariner, Pioneer 10, Viking Orbiter radiometers, and Nimbus D spectrometer. Calibration techniques and error analysis for the instrument system are discussed.

  11. Picosecond Spin Caloritronics

    NASA Astrophysics Data System (ADS)

    Cahill, David G.

    The coupling of spin and heat, i.e., spin caloritronics, gives rise to new physical phenomena in nanoscale spin devices and new ways to manipulate local magnetization. Our work in this field takes advantage of recent advances in the measurement and understanding of heat transport at the nanoscale using ultrafast lasers. We use a picosecond duration pump laser pulses as a source of heat and picosecond duration probe laser pulses to detect changes in temperature, spin accumulation, and spin transfer torque using a combination of time-domain thermoreflectance and time-resolved magneto-optic Kerr effect Our pump-probe optical methods enable us to change the temperature of ferromagnetic layers on a picosecond time-scale and generate enormous heat fluxes on the order of 100 GW m-2 that persist for ~ 30 ps. Thermally-driven ultrafast demagnetization of a perpendicular ferromagnet leads to spin accumulation in a normal metal and spin transfer torque in an in-plane ferromagnet. The data are well described by models of spin generation and transport based on differences and gradients of thermodynamic parameters. The spin-dependent Seebeck effect of a perpendicular ferromagnetic layer converts a heat current into spin current, which in turn can be used to exert a spin transfer torque (STT) on a second ferromagnetic layer with in-plane magnetization. Using a [Co,Ni] multilayer as the source of spin, an energy fluence of ~ 4 J m-2 creates thermal STT sufficient to induce ~ 1 % tilting of the magnetization of a 2 nm-thick CoFeB layer.

  12. The first terawatt picosecond CO{sub 2} laser for advanced accelerator studies at the Brookhaven ATF

    SciTech Connect

    Pogorelsky, I.V.; Ben-Zvi, I.; Skaritka, J.

    1996-10-01

    The first terawatt picosecond C0{sub 2} laser system is under development at the Brookhaven Accelerator Test Facility. Presently operational 1 Joule 100-ps ATF laser will be upgraded with a 10 atm amplifier capable of delivery {approximately} 15 Joules of laser energy in a 3 ps pulse. We describe the design of the x-ray preionized 10 atm amplifier of a 10 liter active volume energized by a 1 MV, 200 kA transverse electric discharge. The amplifier, equipped with internal optics, permits the accommodation of a regenerative stage and a multi-pass booster in a relatively compact single discharge volume. The ATF terawatt C0{sub 2} laser shall become operational in 1997 to serve for laser acceleration, x-ray generation and other strong-field physics experiments.

  13. [Study on photographing experiment of infrared detector].

    PubMed

    Wang, De-Jiang; Zhang, Tao

    2011-01-01

    Infrared detectors are widely used in multi spectral remote sensing systems, and in order to verify photographing principles of infrared time delay integration (TDI) detector, and make preparations for future research, a verification system for infrared TDI camera is proposed in the present paper. Experimental methods are explained thoroughly and two major factors which affect image quality are analyzed. First, the causes of image motion and their effects on the quality of image are studied, and a novel architecture using high precision DC-speed machine is presented, then the relationship between velocity of precision turntable and detectors line transfer frequency is determined by Kalman algorithm. Second, four focusing means are analyzed and compared, and video signal amplitude method is selected according to practical application. Finally, a genuine demo system is established in national supervision and test center for optics mechanics quality. 5.3, 6.4 and 9.2 mm drones are chosen for testing. Experimental results indicate that the obtained drone is vivid, and camera's resolution achieves 11.3 lines per mm, which satisfies preliminary aims. PMID:21428103

  14. Functionalization of manganite nanoparticles and their interaction with biologically relevant small ligands: Picosecond time-resolved FRET studies

    NASA Astrophysics Data System (ADS)

    Giri, Anupam; Makhal, Abhinandan; Ghosh, Barnali; Raychaudhuri, A. K.; Pal, Samir Kumar

    2010-12-01

    We report molecular functionalization of the promising manganite nanoparticles La0.67Sr0.33MnO3 (LSMO) for their solubilization in aqueous environments. The functionalization of individual NPs with the biocompatible citrate ligand, as confirmed by Fourier transform infrared (FTIR) spectroscopy, reveals that citrates are covalently attached to the surface of the NPs. UV-VIS spectroscopic studies on the citrate functionalized NPs reveals an optical band in the visible region. Uniform size selectivity (2.6 nm) of the functionalization process is confirmed from high resolution transmission electron microscope (HRTEM). In the present study we have used the optical band of the functionalized NPs to monitor their interaction with other biologically important ligands. Förster resonance energy transfer (FRET) of a covalently attached probe4-nitrophenylanthranilate (NPA) with the capped NPs confirm the attachment of the NPA ligands to the surface functional group (-OH) of the citrate ligand. The FRET of a DNA base mimic, 2-aminopurine (2AP), with the NPs confirms the surface adsorption of 2AP. Our study may find relevance in the study of the interaction of individual manganite NPs with drug/ligand molecules.We report molecular functionalization of the promising manganite nanoparticles La0.67Sr0.33MnO3 (LSMO) for their solubilization in aqueous environments. The functionalization of individual NPs with the biocompatible citrate ligand, as confirmed by Fourier transform infrared (FTIR) spectroscopy, reveals that citrates are covalently attached to the surface of the NPs. UV-VIS spectroscopic studies on the citrate functionalized NPs reveals an optical band in the visible region. Uniform size selectivity (2.6 nm) of the functionalization process is confirmed from high resolution transmission electron microscope (HRTEM). In the present study we have used the optical band of the functionalized NPs to monitor their interaction with other biologically important ligands. F

  15. Picosecond x-ray science.

    SciTech Connect

    Landahl, E.; Reis, D.; Wang, J.; Young, L.

    2006-01-01

    The report discusses the exciting times for short pulse X-rays and the current users of the technology in the United States. Tracking nuclear motions with X-rays transcends scientific disciplines and includes Biology, Materials Science, Condensed Matter and Chemistry. 1 picosecond accesses many phenomena previously hidden at 100ps. Synchrotron advantage over laser plasma and LCLS is that it's easily tunable. There is a large and diverse user community of this technology that is growing rapidly. A working group is being formed to implement 'fast track' Phases 1 and 2 which includes tunable, polarized, monochromatic, focused X-rays; variable pulse length (1 to 100ps) and 1 kHz, 10{sup 9} X-rays/s with 1% bandwidth. ERL would be a major advance for ultrafast time-resolved studies.

  16. Infrared signature studies of aerospace vehicles

    NASA Astrophysics Data System (ADS)

    Mahulikar, Shripad P.; Sonawane, Hemant R.; Arvind Rao, G.

    2007-10-01

    Infrared (IR) emissions from aircraft are used to detect, track, and lock-on to the target. MAN Portable Air Defence Systems (MANPADS) have emerged as a major cause of aircraft and helicopter loss. Therefore, IR signature studies are important to counter this threat for survivability enhancement, and are an important aspect of stealth technology. This paper reviews contemporary developments in this discipline, with particular emphasis on IR signature prediction from aerospace vehicles. The role of atmosphere in IR signature analysis, and relation between IR signature level and target susceptibility are illustrated. Also, IR signature suppression systems and countermeasure techniques are discussed, to highlight their effectiveness and implications in terms of penalties.

  17. Infrared

    NASA Astrophysics Data System (ADS)

    Vollmer, M.

    2013-11-01

    underlying physics. There are now at least six different disciplines that deal with infrared radiation in one form or another, and in one or several different spectral portions of the whole IR range. These are spectroscopy, astronomy, thermal imaging, detector and source development and metrology, as well the field of optical data transmission. Scientists working in these fields range from chemists and astronomers through to physicists and even photographers. This issue presents examples from some of these fields. All the papers—though some of them deal with fundamental or applied research—include interesting elements that make them directly applicable to university-level teaching at the graduate or postgraduate level. Source (e.g. quantum cascade lasers) and detector development (e.g. multispectral sensors), as well as metrology issues and optical data transmission, are omitted since they belong to fundamental research journals. Using a more-or-less arbitrary order according to wavelength range, the issue starts with a paper on the physics of near-infrared photography using consumer product cameras in the spectral range from 800 nm to 1.1 µm [1]. It is followed by a series of three papers dealing with IR imaging in spectral ranges from 3 to 14 µm [2-4]. One of them deals with laboratory courses that may help to characterize the IR camera response [2], the second discusses potential applications for nondestructive testing techniques [3] and the third gives an example of how IR thermal imaging may be used to understand cloud cover of the Earth [4], which is the prerequisite for successful climate modelling. The next two papers cover the vast field of IR spectroscopy [5, 6]. The first of these deals with Fourier transform infrared spectroscopy in the spectral range from 2.5 to 25 µm, studying e.g. ro-vibrational excitations in gases or optical phonon interactions within solids [5]. The second deals mostly with the spectroscopy of liquids such as biofuels and special

  18. Numerical study of the influence of picosecond laser spot size on ablated depth and threshold fluence of metal

    NASA Astrophysics Data System (ADS)

    Zhang, Yiming; Lauer, Benjamin; Neuenschwander, Beat; Romano, Valerio

    2016-03-01

    Picosecond laser systems have been widely used in industrial microprocessing applications since they are a cost-effective tool to achieve high throughput. To better understand the ablation process, firstly the dependence of the ablation depth and the threshold fluence on the laser spot size were determined experimentally by performing ablation with a 10ps pulsed laser system. Further, a 2D axisymmetric model was established to demonstrate the possible mechanism of the phenomena. Three sets of spot radii, namely 15.5μm, 31.5μm and 49.6μm, respectively with equal laser peak fluences ranging from 0.6J/cm2 to 4.5J/cm2 were applied on copper. It was found that the laser ablation depth increases while the threshold fluence decreases with decreasing spot size at identical peak fluence. A 2D axisymmetric thermomechanical model was developed to qualitatively illustrate the mechanism behind these phenomena. The numerical results of the position where the tensile stress exceed to ultimate tensile strength (UTS) of copper show the same trend as the experimental ones. The longitudinal tensile stress was seen to play a more crucial role than the radial tensile/compressive stress on laser ablation process. The impact of the thermal stress on the ablation depth and threshold fluence is derived from the lattice temperature gradient along the surface of the material, leading to spallation and possible modifications of the mechanical properties already at lower laser peak fluences. This is elucidated numerically and analytically. The deviation of the experimental results from the simulation might be attributed to the fact that this simulation model is static. Nevertheless, at low laser fluences, this static approach can provide good explanations of the cold ablation with ultrashort pulsed laser. The limitation of this model is also illustrated.

  19. New format presentation for infrared spectral emittance data. Infrared spectrometry studies, phase 5

    NASA Technical Reports Server (NTRS)

    Lyon, R. J. P.; Green, A. A.

    1972-01-01

    Methods for infrared radiance measurements from geological materials were studied for airborne use over terrains with minimal vegetation. The tasks of the investigation were: (1) calculation of emittance ratios, (2) comparison of IR spectral emittance data with K-band scatterometer data over Pisgah Crater, and (3) standard infrared spectral file. Published papers reporting the research are included.

  20. Vibrational frequency fluctuation of ions in aqueous solutions studied by three-pulse infrared photon echo method.

    PubMed

    Ohta, Kaoru; Tayama, Jumpei; Saito, Shinji; Tominaga, Keisuke

    2012-11-20

    In liquid water, hydrogen bonds form three-dimensional network structures, which have been modeled in various molecular dynamics simulations. Locally, the hydrogen bonds continuously form and break, and the network structure continuously fluctuates. In aqueous solutions, the water molecules perturb the solute molecules, resulting in fluctuations of the electronic and vibrational states. These thermal fluctuations are fundamental to understanding the activation processes in chemical reactions and the function of biopolymers. In this Account, we review studies of the vibrational frequency fluctuations of solute molecules in aqueous solutions using three-pulse infrared photon echo experiments. For comparison, we also briefly describe dynamic fluorescence Stokes shift experiments for investigating solvation dynamics in water. The Stokes shift technique gives a response function, which describes the energy relaxation in the nonequilibrium state and corresponds to the transition energy fluctuation of the electronic state at thermal equilibrium in linear response theorem. The dielectric response of water in the megahertz to terahertz frequency region is a key physical quantity for understanding both of these frequency fluctuations because of the influence of electrostatic interactions between the solute and solvent. We focus on the temperature dependence of the three experiments to discuss the molecular mechanisms of both the frequency fluctuations in aqueous solutions. We used a biexponential function with sub-picosecond and picosecond time constants to characterize the time-correlation functions of both the vibrational and electronic frequency fluctuations. We focus on the slower component, with time constants of 1-2 ps for both the frequency fluctuations at room temperature. However, the temperature dependence and isotope effect for the time constants differ for these two types of fluctuations. The dielectric interactions generally describe the solvation dynamics of

  1. Picosecond x-ray measurements from 100 eV to 30 keV

    SciTech Connect

    Attwood, D.T.; Kauffman, R.L.; Stradling, G.L.

    1980-10-15

    Picosecond x-ray measurements relevant to the Livermore Laser Fusion Program are reviewed. Resolved to 15 picoseconds, streak camera detection capabilities extend from 100 eV to higher than 30 keV, with synchronous capabilities in the visible, near infrared, and ultraviolet. Capabilities include automated data retrieval using charge coupled devices (CCD's), absolute x-ray intensity levels, novel cathodes, x-ray mirror/reflector combinations, and a variety of x-ray imaging devices.

  2. Infrared and Submilllimeter Studies of Dense Cores

    NASA Astrophysics Data System (ADS)

    Bourke, Tyler L.

    2014-07-01

    Dense Cores are the birthplace of stars, and so understanding their structure and evolution is key to understanding star formation. Information on the density, temperature, and motions within cores are needed to describe these properties, and are obtained through continuum and line observations at far infrared and submm/mm wavelengths. Recent observations of dust emission with Herschel and molecular line observations with single-dish telescopes and interferometers provide the wavelength coverage and resolution to finally map core properties without appealing to spherical simplifications. Although large scale Herschel observations reveal numerous filaments in molecular clouds which are well described by cylindrical geometries, cores are still modeled as spherical entities. A few examples of other core geometries exist in the literature, and the wealth of new data on cloud filaments demand that non-spherical models receive more attention in future studies. This talk will examine the evidence for non-spherical cores and their connection to the filaments from which they form.

  3. Picosecond photoconductivity of natural and CVD diamonds

    NASA Astrophysics Data System (ADS)

    Garnov, Serge V.; Pimenov, Sergej M.; Ralchenko, Victor G.; Klimentov, Sergei M.; Konov, Vitali I.; Korotoushenko, K. G.; Obraztsova, E. D.; Plotnikova, S. P.; Sagatelyan, D. M.; Holly, Sandor

    1995-07-01

    Photoexcitation and recombination of nonequilibrium charge carriers in both natural gemstone diamonds and CVD (chemical vapor deposition) polycrystalline diamond films in UV spectrum regions have been investigated. Transient picosecond photoconductivity technique applied permitted to conduct measurements with the time resolution better than 200 picoseconds and to register a charge carrier concentration value as low as 1020 - 1013 cm-3. The dependencies of photocurrent amplitude as a function of incident laser radiation intensity in the range from 103 to 1010 W/cm2 have been obtained. Charge carrier lifetimes had been measured and charge carrier drift mobility were estimated. It is shown that the electronic properties of high quality thick CVD diamond films are comparable to those of the most perfect natural type IIa crystals. Investigation of Raman and luminescence spectra of diamonds have been performed along with scanning electron microscopy studies to characterize bulk and surface structure of tested specimens.

  4. Infrared Imaging System for Studying Brain Function

    NASA Technical Reports Server (NTRS)

    Mintz, Frederick; Mintz, Frederick; Gunapala, Sarath

    2007-01-01

    A proposed special-purpose infrared imaging system would be a compact, portable, less-expensive alternative to functional magnetic resonance imaging (fMRI) systems heretofore used to study brain function. Whereas a typical fMRI system fills a large room, and must be magnetically isolated, this system would fit into a bicycle helmet. The system would include an assembly that would be mounted inside the padding in a modified bicycle helmet or other suitable headgear. The assembly would include newly designed infrared photodetectors and data-acquisition circuits on integrated-circuit chips on low-thermal-conductivity supports in evacuated housings (see figure) arranged in multiple rows and columns that would define image coordinates. Each housing would be spring-loaded against the wearer s head. The chips would be cooled by a small Stirling Engine mounted contiguous to, but thermally isolated from, the portions of the assembly in thermal contact with the wearer s head. Flexible wires or cables for transmitting data from the aforementioned chips would be routed to an integrated, multichannel transmitter and thence through the top of the assembly to a patch antenna on the outside of the helmet. The multiple streams of data from the infrared-detector chips would be sent to a remote site, where they would be processed, by software, into a three-dimensional display of evoked potentials that would represent firing neuronal bundles and thereby indicate locations of neuronal activity associated with mental or physical activity. The 3D images will be analogous to current fMRI images. The data would also be made available, in real-time, for comparison with data in local or internationally accessible relational databases that already exist in universities and research centers. Hence, this system could be used in research on, and for the diagnosis of response from the wearer s brain to physiological, psychological, and environmental changes in real time. The images would also be

  5. Infrared laboratory studies of synthetic planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Williams, D.

    1973-01-01

    Previous research dealing with telluric gases is briefly reviewed. Current research concerning absorption-line broadening, and particulate constituents of planetary atmospheres are discussed. Two articles are included: optical constants of liquid ammonia in the infrared, and broadening of infrared absorption lines at reduced temperatures for nitrous oxide.

  6. Parametric instabilities in picosecond time scales

    SciTech Connect

    Baldis, H.A.; Rozmus, W.; Labaune, C.; Mounaix, Ph.; Pesme, D.; Baton, S.; Tikhonchuk, V.T.

    1993-03-01

    The coupling of intense laser light with plasmas is a rich field of plasma physics, with many applications. Among these are inertial confinement fusion (ICF), x-ray lasers, particle acceleration, and x-ray sources. Parametric instabilities have been studied for many years because of their importance to ICF; with laser pulses with duration of approximately a nanosecond, and laser intensities in the range 10{sup 14}--10{sup 15}W/cm{sup 2} these instabilities are of crucial concern because of a number of detrimental effects. Although the laser pulse duration of interest for these studies are relatively long, it has been evident in the past years that to reach an understanding of these instabilities requires their characterization and analysis in picosecond time scales. At the laser intensities of interest, the growth rate for stimulated Brillouin scattering (SBS) is of the order of picoseconds, and of an order of magnitude shorter for stimulated Raman scattering (SRS). In this paper the authors discuss SBS and SRS in the context of their evolution in picosecond time scales. They describe the fundamental concepts associated with their growth and saturation, and recent work on the nonlinear treatment required for the modeling of these instabilities at high laser intensities.

  7. Picosecond time-resolved emission studies. I. Real-time measurements of solvent-solute interactions. II. Kinetics of energy flow in a photosynthetic antenna system. [4-aminophthalimide

    SciTech Connect

    Yeh, S.W.

    1985-11-01

    Using a picosecond fluorimeter, the dynamics of solvation of electronically excited 4-aminophthalimide in a variety of solvents is measured. The solvation process is manifested by a time-dependent red shift in the emission spectrum in certain solvents. This red shift is time-resolved using a streak camera system. The time constant of the relaxation is found to correlate strongly with the longitudinal dielectric relaxation rate of the solvent. The correlation holds for changes in solvent, for isotopic substitution of a solvent, and for changes in temperature. Never before have direct measurements of excited-state solvation dynamics been shown to correlate with dielectric relaxation over such a wide range of experimental conditions. Emission from certain photosynthetic antenna complexes, phycobilisomes, and from the building blocks of phycobilisomes, phycobiliproteins, has also been studied using the streak camera system. Both the rising and filling portions of the time-resolved emission profiles of the fluorescing chromophores in these structures are studied. The rates of energy transfer between structural domains of the antenna complex and within the isolated biliprotein complexes are deduced from these studies. Comparison of emission profiles from a series of structurally distinct phycobilisomes isolated from three related strains of cyanobacteria have provided new insights into the correlation of the energy transfer function and macromolecular structure in these light-harvesting antenna systems. 133 refs., 58 figs., 14 tabs.

  8. Ultraviolet and infrared correlation studies in Orion

    NASA Astrophysics Data System (ADS)

    Bose, Lakshmi S.; Sujatha, N. V.; Narayanankutty, K.

    We have studied the variation of diffuse ultraviolet (UV) radiation in the northern part of the Orion constellation using a set of eight areas of the GALEX All-Sky Imaging Survey in the far and near UV. Different components of diffuse UV radiation, like dust scattered emission and H2 fluorescence, were quantified and separated after removing the point sources and the foreground emission in each of the fields. Then the dependence of the individual UV components on the infrared 100 μ m dust emission was studied. We did not find any positive correlation between the diffuse-UV and IR-100 micron intensities, probably due to the high optical depth of the region or the entire dust column not contributing to the diffuse UV radiation. However, in the far UV we noticed the presence of an excess emission in addition to the dust scattered radiation, which is clearly absent in the near UV. This excess emission, identified as the H2 fluorescence, is produced by the Trapezium stars in the surrounding molecular clouds. We also compare our results with those of previous studies in the region, based on Far Ultraviolet Spectroscopic Explorer (FUSE) observations.

  9. Infrared Thermographic Study of Laser Ignition

    SciTech Connect

    Mohler, Jonathan H.; Chow, Charles T. S.

    1986-07-01

    Pyrotechnic ignition has been studied in the past by making a limited number of discrete temperature-time observations during ignition. Present-day infrared scanning techniques make it possible to record thermal profiles, during ignition, with high spacial and temporal resolution. Data thus obtained can be used with existing theory to characterize pyrotechnic materials and to develop more precise kinetic models of the ignition process. Ignition has been studied theoretically and experimentally using various thermal methods. It has been shown that the whole process can, ideally, be divided into two stages. In the first stage, the sample pellet behaves like an inert body heated by an external heat source. The second stage is governed by the chemical reaction in the heated volume produced during the first stage. High speed thermographic recording of the temperature distribution in the test sample during laser ignition makes it possible to calculate the heat content at any instant. Thus, one can actually observe laser heating and the onset of self-sustained combustion in the pellet. The experimental apparatus used to make these observations is described. The temperature distributions recorded are shown to be in good agreement with those predicted by heat transfer theory. Heat content values calculated from the observed temperature distributions are used to calculate thermal and kinetic parameters for several samples. These values are found to be in reasonable agreement with theory.

  10. [Infrared and Raman spectra study on Tianhuang].

    PubMed

    Liu, Yun-gui; Chen, Tao

    2012-08-01

    The Tianhuang stones, from Shoushan in China, were studied by using X-ray powder diffractometry (XRD), infrared (IR) spectroscopy and Raman spectroscopy to obtain the spectra characterization. Wave numbers 3621, 3629 and 3631 cm(-1) in the IR spectra and 3626, 3627 and 3632 cm(-1) in the Raman spectra are the characteristic peaks of dickitic Tianhuang, nacritic Tianhuang and illitic Tianhuang, respectively. Raman spectra assigned to OH are in good agreement with the IR results at 3550 -3750 cm(-1). Dickitic Tianhuang includes ordered dickite and disordered dickite. Compared with ordered dickite, the band assigned to OH3 of disordered dickite shifts to low-frequency by 8 cm(-1) and the relative intensity becomes stronger. The disorder structure may relate to the high level of Fe. The IR absorption spectra of nacritic Tianhuang superimposes strong peaks of dickite, indicating that IR absorption bands of dickite are stronger than that of nacrite at 3550-3750 cm(-1). The main mineral composition of illitic Tianhuang is 2M(1), while illite Tianhuang contains a small amount of 1M. All these characters provide a theoretical basis for the scientific identification of Tianhuang. PMID:23156769

  11. Raman and infrared spectroscopic study of turquoise minerals.

    PubMed

    Čejka, Jiří; Sejkora, Jiří; Macek, Ivo; Malíková, Radana; Wang, Lina; Scholz, Ricardo; Xi, Yunfei; Frost, Ray L

    2015-10-01

    Raman and infrared spectra of three well-defined turquoise samples, CuAl6(PO4)4(OH)8·4H2O, from Lavender Pit, Bisbee, Cochise county, Arizona; Kouroudaiko mine, Faleme river, Senegal and Lynch Station, Virginia were studied, interpreted and compared. Observed Raman and infrared bands were assigned to the stretching and bending vibrations of phosphate tetrahedra, water molecules and hydroxyl ions. Approximate O-H⋯O hydrogen bond lengths were inferred from the Raman and infrared spectra. No Raman and infrared bands attributable to the stretching and bending vibrations of (PO3OH)(2-) units were observed. PMID:25956330

  12. Raman and infrared spectroscopic study of turquoise minerals

    NASA Astrophysics Data System (ADS)

    Čejka, Jiří; Sejkora, Jiří; Macek, Ivo; Malíková, Radana; Wang, Lina; Scholz, Ricardo; Xi, Yunfei; Frost, Ray L.

    2015-10-01

    Raman and infrared spectra of three well-defined turquoise samples, CuAl6(PO4)4(OH)8·4H2O, from Lavender Pit, Bisbee, Cochise county, Arizona; Kouroudaiko mine, Faleme river, Senegal and Lynch Station, Virginia were studied, interpreted and compared. Observed Raman and infrared bands were assigned to the stretching and bending vibrations of phosphate tetrahedra, water molecules and hydroxyl ions. Approximate O-H⋯O hydrogen bond lengths were inferred from the Raman and infrared spectra. No Raman and infrared bands attributable to the stretching and bending vibrations of (PO3OH)2- units were observed.

  13. Optothermal response of plasmonic nanofocusing lens under picosecond laser irradiation

    NASA Astrophysics Data System (ADS)

    Du, Z.; Chen, C.; Traverso, L.; Xu, X.; Pan, L.; Chao, I.-H.; Lavine, A. S.

    2014-03-01

    This work studied the optothermal response of plasmonic nanofocusing structures under picosecond pulsed laser irradiation. The surface plasmon polariton is simulated to calculate the optical energy dissipation as the Joule heating source and the thermal transport process is studied using a two temperature model (TTM). At the picosecond time scale that we are interested in, the Fourier heat equation is used to study the electron thermal transport and the hyperbolic heat equation is used to study the lattice thermal transport. For comparison, the single temperature model (STM) is also studied. The difference between TTM and STM indicates that TTM provides more accurate estimates in the picosecond time scale and the STM results are only reliable when the local electron and lattice temperature difference is negligible.

  14. Preparation of water soluble L-arginine capped CdSe/ZnS QDs and their interaction with synthetic DNA: Picosecond-resolved FRET study

    SciTech Connect

    Giri, Anupam; Goswami, Nirmal; Lemmens, Peter; Pal, Samir Kumar

    2012-08-15

    Graphical abstract: Förster resonance energy transfer (FRET) studies on the interaction of water soluble arginine-capped CdSe/ZnS QDs with ethidium bromide (EB) labeled synthetic dodecamer DNA. Highlights: ► We have solubilized CdSe/ZnS QD in water replacing their TOPO ligand by L-arginine. ► We have studied arginine@QD–DNA interaction using FRET technique. ► Arginine@QDs act as energy donor and ethidium bromide-DNA acts as energy acceptor. ► We have applied a kinetic model to understand the kinetics of energy transfer. ► Circular dichroism studies revealed negligible perturbation in the DNA B-form in the arg@QD-DNA complex. -- Abstract: We have exchanged TOPO (trioctylphosphine oxide) ligand of CdSe/ZnS core/shell quantum dots (QDs) with an amino acid L-arginine (Arg) at the toluene/water interface and eventually rendered the QDs from toluene to aqueous phase. We have studied the interaction of the water soluble Arg-capped QDs (energy donor) with ethidium (EB) labeled synthetic dodecamer DNA (energy acceptor) using picoseconds resolved Förster resonance energy transfer (FRET) technique. Furthermore, we have applied a model developed by M. Tachiya to understand the kinetics of energy transfer and the distribution of acceptor (EB-DNA) molecules around the donor QDs. Circular dichroism (CD) studies revealed a negligible perturbation in the native B-form structure of the DNA upon interaction with Arg-capped QDs. The melting and the rehybridization pathways of the DNA attached to the QDs have been monitored by the CD which reveals hydrogen bonding is the associative mechanism for interaction between Arg-capped QDs and DNA.

  15. REMOTE FOURIER TRANSFORM INFRARED AIR POLLUTION STUDIES

    EPA Science Inventory

    A commercial Fourier transform infrared interferometer system has been installed in a van and used to make longpath absorption and single-ended emission measurements of gaseous pollutant concentrations at a variety of pollutant sources. The interferometer system is described and ...

  16. Ultrasensitive coherent Raman technique with picosecond lasers

    SciTech Connect

    Schauer, M.W.; Pellin, M.J.; Biwer, B.M.; Gruen, D.M.

    1987-02-16

    The use of picosecond, Q-switched lasers and advanced polarization schemes has led to the development of a coherent Raman technique with the sensitivity of coherent anti-Stokes Raman spectroscopy experiments but without the troublesome phase-matching requirements. Experiments in dilute solutions of benzene indicate a limit of sensitivity for the current apparatus of 2.5 x 10/sup -4/ M in two minutes of signal averaging over 150 cm/sup -1/. Possible applications to the in situ study of passive films and thin films on transparent media are discussed.

  17. Infrared spectroscopy study of irradiated PVDF

    SciTech Connect

    Chappa, Veronica; Grosso, Mariela del; Garcia Bermudez, Gerardo; Behar, Moni

    2007-10-26

    The effects induced by 1 MeV/amu ion irradiations were compared to those induced by 4-12 MeV/amu irradiations. Structural analysis with infrared spectroscopy (FTIR) was carried out on PVDF irradiated using C and He beams with different fluences. From these spectra it was observed, as a function of fluence, an overall destruction of the polymer, amorphization of the crystalline regions and the creation of in-chain unsaturations. The track dimensions were determined using a previously developed Monte Carlo simulation code and these results were compared to a semiempirical model.

  18. Molecular collision processes in the presence of picosecond laser pulses

    NASA Technical Reports Server (NTRS)

    Lee, H. W.; George, T. F.

    1979-01-01

    Radiative transitions in molecular collision processes taking place in the presence of picosecond pulses are studied within a semiclassical formalism. An expression for adiabatic potential surfaces in the electronic-field representation is obtained, which directly leads to the evaluation of transition probabilities. Calculations with a Landau-Zener-type model indicate that picosecond pulses can be much more effective in inducing transitions than a single long pulse of the same intensity and the same total energy, if the intensity is sufficiently high that the perturbation treatment is not valid.

  19. Spectral coherence in all-normal dispersion supercontinuum in presence of Raman scattering and direct seeding from sub-picosecond pump.

    PubMed

    Klimczak, Mariusz; Soboń, Grzegorz; Abramski, Krzysztof; Buczyński, Ryszard

    2014-12-29

    Intensity stability and wavelength correlations of near-infrared supercontinuum generation are studied in all-normal flattened dispersion, all-solid soft glass photonic crystal fiber. We use dispersive Fourier transformation method to measure shot-to-shot resolved spectra under pumping from a sub-picosecond, fiber-based chirped pulse amplification (CPA) system. For the first time to our knowledge, we demonstrate how unconverted radiation from pump, propagating in the photonic cladding of the fiber, improves the measured degree of coherence in the spectrum and influences its wavelength correlation by seeding of multiple four-wave-mixing / Raman scattering components. The presented results suggest a convenient and simple way of stabilizing of shot-to-shot coherence in sub-picosecond fiber laser pumped, normal-dispersion supercontinuum sources by direct, pump-related seeding. PMID:25607134

  20. Ultrafast energy transfer to liquid water by sub-picosecond high-intensity terahertz pulses: an ab initio molecular dynamics study.

    PubMed

    Mishra, Pankaj Kr; Vendrell, Oriol; Santra, Robin

    2013-12-16

    Sub-picosecond heating of bulk water is accomplished by ultrashort and intense THz pulses which are able to transfer a large amount of energy to the liquid. The energy transferred corresponds to a temperature jump of about 600 K. Liquid water becomes a structureless and hot gas-like system still at the density of the liquid, in which the hydrogen-bonding structure has been washed out. PMID:24155137

  1. Infrared micro-spectroscopic studies of epithelial cells

    PubMed Central

    Romeo, Melissa; Mohlenhoff, Brian; Jennings, Michael; Diem, Max

    2009-01-01

    We report results from a study of human and canine mucosal cells, investigated by infrared micro-spectroscopy, and analyzed by methods of multivariate statistics. We demonstrate that the infrared spectra of individual cells are sensitive to the stage of maturation, and that a distinction between healthy and diseased cells will be possible. Since this report is written for an audience not familiar with infrared micro-spectroscopy, a short introduction into this field is presented along with a summary of principal component analysis. PMID:16797481

  2. Case study: using infrared technology for evidentiary purposes

    NASA Astrophysics Data System (ADS)

    Jolivet, Noel D.; Hansen, Joel; Miller, John Lester; Beniga, Rico; Austria, Rich

    2014-06-01

    Infrared technology and imaging systems are already used extensively by the law enforcement (LE) community, typically to gain a tactical advantage or obtain immediate situational awareness. As the use of infrared technology becomes more affordable and widespread, LE is finding new ways to use it and leverage the results in the courtroom as evidence. A case study will be presented where infrared imagery was used to support the Portland Police Bureau (PPB) in prosecuting an individual for a crime where a conviction might not have been assured without said imagery. Tests conducted at FLIR Systems, combined with expert witness testimony by a FLIR employee, helped a jury understand the significance of a key piece of infrared evidence, resulting in a conviction of the criminal. This case was the first Federal case of its kind where infrared imagery was used forensically as evidence and, as such, established precedence. Prior to this, infrared imagery has been offered and debated in court only as to whether it constitutes a legal search. Courtroom observations and lessons learned from this trial have shown that both industry and LE can do a better job of making the prosecution's cases stronger utilizing infrared technology and thus taking criminals off the street.

  3. An Infrared Study of the Juggler Nebula

    NASA Technical Reports Server (NTRS)

    Holbrook, J. C.; Temi, P.; Rank, D.; Bregman, J.

    1996-01-01

    This work is an examination of the infrared reflection nebula surrounding a protostellar source, IRS 1, in the CRL 2136 region at 2.2, 3.08, and 3.45 micron. The greatest absorption due to water ice occurs within 5 arcsec (10,000 AU, D = 2000 pc) of IRS 1. The water ice absorption decreases with increasing radius from IRS 1. This Tau(sub ice) structure suggests that the water ice is primarily associated with IRS 1. The flux from IRS 1 has a (2.2) - (3.45) color of 5, much redder than the nebula. The color structure combined with the Tau(sub ice) structure suggests the presence of an icy-dusty disk around IRS 1 orientated NE to SW. Radio CO maps presented by Kastner et al. reveal a molecular outflow orientated perpendicular to the disk. The south and east reflection lobes line the conical cavity created by the blueshifted molecular outflow.

  4. Fourier transform infrared spectroscopic study of truffles

    NASA Astrophysics Data System (ADS)

    Zhao, Dezhang; Liu, Gang; Song, Dingshan; Liu, Jian-hong; Zhou, Yilan; Ou, Jiaming; Sun, Shizhong

    2006-01-01

    Truffles are rare wild growing edible mushrooms belonging to Ascomycetes. In this paper, Fourier transform infrared (FTIR) spectroscopy was used to obtain vibrational spectra of truffles. The results show that the mushrooms exhibit characteristic spectra. The two strongest absorption bands appear at about 1077cm -1 and 1040 cm -1, which were described as C-O stretching in carbohydrate. The vibrational spectra indicate that the main compositions of the truffles are polysaccharide and protein. According to the characteristics bands and absorption ratios of spectra, different species of truffles can be discriminated. It is also found the great changes between moldy and healthy truffles, which the major differences are observed in the bands of protein. In addition, FTIR spectral differences are observed between the same species of truffles from different producing areas. It is showed that the FTIR spectroscopic method is valuable tool for rapid and nondestructive analysis of truffles prior to any extraction method used.

  5. Wavelength conversion through soliton self-frequency shift in tellurite microstructured fiber with picosecond pump pulse

    NASA Astrophysics Data System (ADS)

    Bi, Wanjun; Li, Xia; Xing, Zhaojun; Zhou, Qinling; Fang, Yongzheng; Gao, Weiqing; Xiong, Liangming; Hu, Lili; Liao, Meisong

    2016-01-01

    Wavelength conversion to the wavelength range that is not covered by commercially available lasers could be accomplished through the soliton self-frequency shift (SSFS) effect. In this study, the phenomenon of SSFS pumped by a picosecond-order pulse in a tellurite microstructured fiber is investigated both theoretically and experimentally. The balance between the dispersion and the nonlinearity achieved by a 1958 nm pump laser induces a distinct SSFS effect. Attributed to the large spectral distance between the pump pulse and the fiber zero-dispersion wavelength, the SSFS is not cancelled due to energy shedding from the soliton to the dispersive wave. Details about the physical mechanisms behind this phenomenon and the variations of the wavelength shift, the conversion efficiency are revealed based on numerical simulations. Owing to the large soliton number N, the pulse width of the first split fundamental soliton is approximately 40 fs, producing a pulse compression factor of ˜38, much higher than that pumped by a femtosecond pulse. Experiments were also conducted to confirm the validity of the simulation results. By varying the pump power, a continuous soliton shift from 1990 nm to 2264 nm was generated. The generation of SSFS in tellurite microstructured fibers with picosecond pump pulse can provide a new approach for wavelength conversion in the mid-infrared range and could be useful in medical and some other areas.

  6. 3-Picolyl Azide Adenine Dinucleotide as a Probe of Femtosecond to Picosecond Enzyme Dynamics

    PubMed Central

    Dutta, Samrat; Li, Yun-Liang; Rock, William; Houtman, Jon C. D.; Kohen, Amnon; Cheatum, Christopher M.

    2012-01-01

    Functionally relevant femtosecond to picosecond dynamics in enzyme active sites can be difficult to measure because of a lack of spectroscopic probes that can be located in the active site without altering the behavior of the enzyme. We have developed a new NAD+ analog 3-Picolyl Azide Adenine Dinucleotide (PAAD+), which has the potential to be a general spectroscopic probe for NAD-dependent enzymes. This analog is stable and binds in the active site of a typical NAD-dependent enzyme formate dehydrogenase (FDH) with similar characteristics to natural NAD+. It has an isolated infrared transition with high molar absorptivity that makes it suitable for observing enzyme dynamics using 2D IR spectroscopy. 2D IR experiments show that in aqueous solution, the analog undergoes complete spectral diffusion within hundreds of femtoseconds consistent with the water hydrogen bonding dynamics that would be expected. When bound to FDH in a binary complex, it shows picosecond fluctuations and a large static offset, consistent with previous studies of the binary complexes of this enzyme. These results show that PAAD+ is an excellent probe of local dynamics and that it should be a general tool for probing the dynamics of a wide range of NAD-dependent enzymes. PMID:22126535

  7. Vibrational dephasing in molecular mixed crystals: A picosecond time domain CARS study of pentacene in naphthalene and benzoic acid

    NASA Astrophysics Data System (ADS)

    Duppen, Koos; Weitekamp, D. P.; Wiersma, Douwe A.

    1983-12-01

    Multiresonant time-domain coherent anti-Stokes Raman scattering (CARS) experiments have been employed in a study of the decay of vibrational coherences of pentacene doped into naphthalene and benzoic acid. In all cases, the CARS decay is found to be exponential, which indicates that the electronic and vibronic inhomogeneities in this system are strongly correlated. The temperature dependence of vibrational dephasing shows no effect of coupling to the lowest-frequency librational mode of pentacene that is known to dominate electronic dephasing. This surprising result can be understood on basis of a dephasing model where rapid coherence exchange exists between a cold vibrational transition and a corresponding near-resonant librationally hot one. For the 767 cm-1 vibrational transition, oscillations of the CARS signal as a function of delay are shown to arise from interference at the detector with a nearby naphthalene host signal. An inconsistency with a previously reported spontaneous Raman study is resolved by showing that the signal observed there is actually site-selected fluorescence.

  8. The effect of picosecond laser pulses on redox-dependent processes in mice red blood cells studied in vivo

    NASA Astrophysics Data System (ADS)

    Voronova, Olga; Gening, Tatyana; Abakumova, Tatyana; Sysolyatin, Aleksey; Zolotovskiy, Igor; Antoneeva, Inna; Ostatochnikov, Vladimir; Gening, Snezhanna

    2014-02-01

    The study highlights the effect of different modes of in vivo laser irradiation of mice using a PFL8LA laser with λ = 1560 nm, pulse duration of 1,4•10-12 s, peak power of 3,72•103 W and average output power of 20•10-3 W on the lipid peroxidation parameters: conjugated dienes, ketodienes and conjugated trienes, malondialdehyde, Schiff bases and the activity of antioxidant enzymes - catalase, glutathione -S-transferase and superoxide dismutase in erythrocytes and plasma of mice. Two groups of mice received a total dose of 3.8 J/cm2 per group, but the 1st group was irradiated only once, while the 2nd - four times. Significant differences in the parameters of the 1st and 2nd groups indicate different effects of the irradiation modes on redox-dependent processes in red blood cells of mice.

  9. Picosecond laser studies of V-T processes in gases and electronic excitation transport in disordered systems

    SciTech Connect

    Hedstrom, J.F.

    1987-06-01

    SVL fluorescence spectroscopy was used to study intramolecular energy transfer from the 0/sup 0/ level of aniline induced by collisions with CO/sub 2/. Time-correlated photon counting was used to measure concentration dependent fluorescence depolarization for rhodamine 6G in glycerol. Fluorescence decays from these viscous solutions provide data for analyzing the three-dimensional, three-body excitation transport theory developed by Gochanour, Andersen and Fayer for disordered systems. The two-dimensional, two-body excitation theory developed by Loring and Fayer was also examined using time-resolved fluorescence depolarization techniques. The samples, made up of submonolayers of rhodamine 3B adsorbed onto optically flat fused silica yield fluorescence profiles which agree well with profiles developed from the theory for reduced surface coverages up to approx.0.4. At higher coverages, excitation trapping by rhodamine 3B aggregates truncates the depolarization process, yielding apparent reduced coverages which are appreciably lower than the true coverages.

  10. Picosecond coherent anti-Stokes Raman scattering (CARS) study of vibrational dephasing of carbon disulfide and benzene in solution

    NASA Technical Reports Server (NTRS)

    Perry, Joseph W.; Woodward, Anne M.; Stephenson, John C.

    1986-01-01

    The vibrational dephasing of the 656/cm mode (nu1, a1g) of CS2 and the 991/cm mode (nu2, a1g) of benzene have been studied as a function of concentration in mixtures with a number of solvents using a ps time-resolved CARS technique. This technique employs two tunable synchronously-pumped mode-locked dye lasers in a stimulated Raman pump, coherent anti-Stokes Raman probe time-resolved experiment. Results are obtained for CS2 in carbon tetrachloride, benzene, nitrobenzene, and ethanol and for benzene nu2 in CS2. The dephasing rates of CS2 nu1 increase on dilution with the polar solvents and decrease or remain constant on dilution with the nonpolar solvents. The CS2/benzene solutions show a contrasting behavior, with the CS2 nu1 dephasing rate being nearly independent of concentration whereas the benzene nu2 dephasing rate decreases on dilution. These results are compared to theoretical models for vibrational dephasing of polyatomic molecules in solution.

  11. Picosecond surface restricted transient grating studies of carrier reaction dynamics at n -GaAs(100) interfaces

    SciTech Connect

    Gomez-Jahn, L.A.; Miller, R.J.D. )

    1992-03-01

    The surface restricted transient grating technique has been found to be sensitive to the Fermi level pinning surface states at the atomic interface of the native oxide layer of (100) GaAs. The sensitivity to these states is better than 10{sup {minus}4} of a monolayer. The grating signal associated with the surface states is eliminated by photoinduced removal of the oxide layer and hole transfer to Se{sup {minus}2} ions adsorbed to the surface. These results support the assignment of the signal to electronic factors associated with surface state species. The use of space charge field focusing of hole carriers to the surface has enabled a discrimination of the hole carrier reaction dynamics from those of the electron at the surface. {ital In} {ital situ} studies of interfacial hole transfer to Se{sup {minus}2} ions present at liquid junctions found the hole transfer time to be less than 30 ps. The selective quenching of the hole carrier through interfacial charge transfer has found that the hole carrier contributes to the optical dispersion in the 1 {mu} region to approximately the same extent as the electron.

  12. Incubation and nanostructure formation on n- and p-type Si(1 0 0) and Si(1 1 1) at various doping levels induced by sub-nanojoule femto- and picosecond near-infrared laser pulses

    NASA Astrophysics Data System (ADS)

    Schüle, M.; Afshar, M.; Feili, D.; Seidel, H.; König, K.; Straub, M.

    2014-09-01

    N- and p-doped Si(1 0 0) and Si(1 1 1) surfaces with dopant concentrations of 2 × 1014-1 × 1019 cm-3 were irradiated by tightly focused 85-MHz repetition rate Ti:sapphire laser light (central wavelength 800 nm, bandwidth 120 nm) at pulse durations of 12 fs to 1.6 ps. Dependent on pulse peak intensity and exposure time nanorifts, ripples of period 130 nm as well as sponge-like randomly nanoporous surface structures were generated with water immersion and, thereafter, laid bare by etching off aggregated oxide nanoparticles. The same structure types emerged in air or water with transform-limited 100-fs pulses. At a pulse length of 12 fs pronounced incubation occurred with incubation coefficients S = 0.66-0.85, whereas incubation was diminished for picosecond pulses (S > 0.95). The ablation threshold strongly rose with dopant concentration. At similar doping level it was higher for n-type than for p-type samples and for Si(1 0 0) compared to Si(1 1 1) surfaces. These observations are attributed to laser-induced defect states in the bandgap which participate in photoexcitation, deactivation of dopants by complex formation, and different densities of interface states at the boundary with the ultrathin native silicon dioxide surface layer. The threshold increase with pulse length revealed predominant single-photon excitation as well as multiphoton absorption.

  13. The Jefferson Lab Sub-picosecond X-ray Program

    NASA Astrophysics Data System (ADS)

    Boyce, J. R.; Benson, S. V.; Bohn, C. L.; Douglas, D. R.; Dylla, H. F.; Gubeli, J. F.; Happek, U.; Jordan, K.; Krafft, G. A.; Neil, G. R.; Piot, P.; Shinn, M. D.; Williams, G. P.

    2003-08-01

    The kW-class infrared (IR) Free Electron Laser (FEL) at Jefferson Lab had the capability of producing intracavity Thomson scattering of the IR off the electron beam thus producing high average flux, sub-picosecond x-rays. We have measured these x-rays and demonstrated the energy tuneability range from 3.5 keV to 18 keV. The corresponding flux and brightness has been estimated and will be discussed. This year, 2002, the FEL was disassembled and has been reconfigured to produce 10 kW average power IR. We present the estimated x-ray capabilities for the new FEL and discuss potential applications.

  14. Infrared Spectroscopic Studies with the Stratospheric Observatory for Infrared Astronomy (sofia)

    NASA Astrophysics Data System (ADS)

    Gehrz, R. D.; Becklin, E. E.

    2011-06-01

    The joint U.S. and German Stratospheric Observatory for Infrared Astronomy (SOFIA) will be a premier facility for studying the physics and chemistry of the interstellar medium and the stellar evolution process for many decades. SOFIA's first-generation instrument complement includes broadband imagers, moderate resolution spectrographs capable of resolving broad features due to dust and large molecules, and high resolution spectrometers suitable for kinematic studies of molecular and atomic gas lines at km/s resolution. SOFIA spectroscopic science applications will be discussed, with special emphasis on investigations related to infrared spectroscopy of astrophysical gas, grains, and ices. First light images and early science results related to these topics will be presented.

  15. An infrared study of dust in Type IIn supernovae

    NASA Astrophysics Data System (ADS)

    Fox, Ori Dosovitz

    2010-11-01

    Given their high sensitivity to warm dust, infrared observations serve as important probes of supernovae and the surrounding supernova environment. Warm dust can trace progenitor mass loss rates, circumstellar interaction, and dust formation in the supernova environment, ultimately contributing to a broader understanding of stellar evolution, supernova explosion mechanics, and the origin of dust in the universe. The Type IIn supernova subclass, named for the "narrow" emission lines, tends to exhibit late-time infrared emission from warm dust more often than other subclasses. These supernovae, however, are particularly rare, consisting of only ˜2--3% of all core-collapse events. With only a handful of Type IIn observations at infrared wavelengths, the nature of the Type IIn environments and progenitors remain relatively unknown. This thesis presents an infrared study of Type IIn supernovae, beginning with a case study of SN 2005ip. A combination of Spitzer/IRS and IRAC, APO/TripleSpec, and FanCam data constrain the dust mass, temperature, and luminosity, identify the origin and heating mechanism of the warm dust, and characterize the progenitor system. Expanding on this work, a warm Spitzer/IRAC mission surveys the coordinates of 68 Type IIn supernovae within 250 Mpc from the past ten years. The detection of late-time emission from nine targets (>10%) nearly doubles the database of existing mid-infrared observations of Type IIn events. Pre-exisiting dust produced by massive progenitor eruptions (i.e., luminous blue variables) and heated by an infrared echo likely dominates the observed mid-infraraed flux. Finally, a characterization of the next generation of near-infrared detectors identifies several non-ideal noise sources and calibrations procedures. The resulting improvement in detector sensitivity paves the way for the next generation of transient observations as they trend towards cooler objects and higher redshifts.

  16. Picosecond lasers for tattoo removal: a systematic review.

    PubMed

    Reiter, Ofer; Atzmony, Lihi; Akerman, Lehavit; Levi, Assi; Kershenovich, Ruben; Lapidoth, Moshe; Mimouni, Daniel

    2016-09-01

    Given that the pigment particles in tattoos have a relaxation time of <10 ns, picosecond lasers would be expected to be more effective than nanosecond lasers in tattoo removal. To systematically review the evidence regarding the effectiveness and safety of picosecond lasers for tattoo removal, Pubmed, Cochrane Central Register of Controlled Trials (CENTRAL), ClinicalTrials.gov, and reference lists were searched for relevant trials. The primary outcome was >70 % clearance of tattoo pigment. Secondary outcomes were 90-100 % clearance of tattoo pigment, number of laser sessions required, and adverse effects. Eight trials were included, six with human participants (160 participants) and 2 with animal models. Seven of the eight trials explored the usage of either 755, 758, 795, 1064, or 1064/532-nm picosecond lasers for black and blue ink tattoos. In the human trials, 69-100 % of tattoos showed over 70 % clearance of pigment after 1-10 laser treatments. Reported side effects included pain, hyperpigmentation and hypopigmentation, blister formation and transient erythema, edema, and pinpoint bleeding. Included articles varied in type of laser investigated, mostly non-comparative studies and with a medium to high risk of bias. There is sparse evidence that picosecond lasers are more effective than their nanosecond counterparts for mainly black and blue ink tattoo removal, with minor side effects. PMID:27311768

  17. Astronomical polarization studies at radio and infrared wavelengths. Part 2: Far infrared polarization of dust clouds

    NASA Technical Reports Server (NTRS)

    Dennison, B. K.

    1976-01-01

    Far infrared polarization of dust clouds is examined. The recently observed 10 micron polarization of the Orion Nebula and the Galactic Center suggests that far infrared polarization may be found in these objects. Estimates are made of the degree of far infrared polarization that may exist in the Orion Nebula. An attempt to observe far infrared polarization from the Orion Nebula was carried out.

  18. Picosecond dynamics of free carrier populations, space- charge fields, and photorefractive nonlinearities in zincblende semiconductors

    NASA Astrophysics Data System (ADS)

    Stark, Thomas Spencer

    Generally, nonlinear optics studies investigate optically-induced changes in refraction or absorption, and their application to spectroscopy or device fabrication. The photorefractive effect is a nonlinear optical effect that occurs in solids, where transport of an optically-induced free-carrier population results in an internal space-charge field, which produces an index change via the linear electrooptic effect. The photorefractive effect has been widely studied for a variety of materials and device applications, mainly because it allows large index changes to be generated with laser beams having only a few milliwatts of average power. Compound semiconductors are important photorefractive materials because they offer a near-infrared optical response, and because their carrier transport properties allow the index change to be generated quickly and efficiently. While many researchers have attempted to measure the fundamental temporal dynamics of the photorefractive effect in semiconductors using continuous-wave, nanosecond- and picosecond-pulsed laser beams, these investigations have been unsuccessful. However, studies with this goal are of clear relevance because they provide information about the fundamental physical processes that produce this effect, as well as the material's speed and efficiency limitations for device applications. In this dissertation, for the first time, we time-resolve the temporal dynamics of the photorefractive nonlinearities in two zincblende semiconductors, semi- insulating GaAs and undoped CdTe. While CdTe offers a lattice-match to the infrared material HgxCd1-xTe, semi-insulating GaAs has been widely used in optoelectronic and high- speed electronic applications. We use a novel transient- grating experimental method that allows picosecond temporal resolution and high sensitivity. Our results provide a clear and detailed picture of the picosecond photorefractive response of both materials, showing nonlinearities due to hot

  19. Studying infrared light therapy for treating Alzheimer's disease

    NASA Astrophysics Data System (ADS)

    Han, Mengmeng; Wang, Qiyan; Zeng, Yuhui; Meng, Qingqiang; Zhang, Jun; Wei, Xunbin

    2016-03-01

    Alzheimer's disease (AD) is an extensive neurodegenerative disease. It is generally believed that there are some connections between AD and amyloid protein plaques in the brain. AD is a chronic disease that usually starts slowly and gets worse over time. The typical symptoms are memory loss, language disorders, mood swings and behavioral issues. Gradual losses of somatic functions eventually lead patients to death. Currently, the main therapeutic method is pharmacotherapy, which may temporarily reduce symptoms, but has many side effects. No current treatment can reverse AD's deterioration. Infrared (IR) light therapy has been studied in a range of single and multiple irradiation protocols in previous studies and was found beneficial for neuropathology. In our research, we have verified the effect of infrared light on AD through Alzheimer's disease mouse model. This transgenic mouse model is made by co-injecting two vectors encoding mutant amyloid precursor protein (APP) and mutant presenilin-1 (PSEN1). We designed an experimental apparatus for treating mice, which primarily includes a therapeutic box and a LED array, which emits infrared light. After the treatment, we assessed the effects of infrared light by testing cognitive performance of the mice in Morris water maze. Our results show that infra-red therapy is able to improve cognitive performance in the mouse model. It might provide a novel and safe way to treat Alzheimer's disease.

  20. Laboratory infrared studies of molecules of atmospheric and astrophysical interest

    NASA Technical Reports Server (NTRS)

    Rao, N. N.

    1982-01-01

    Nineteen reprints on the molecular species are compiled. Much of the work was done by using the Doppler-limited resolution provided by diode lasers. The diode laser was used as a source to a grating spectrometer which has been used earlier for high resolution studies. This technique provided many advantages. Wherever possible, the studies have been directed to intensity determinations of infrared bands.

  1. Picosecond spectroscopic studies of equilibrium structural fluctuations of native and partially unfolded states of Zinc II-substituted and metal-free cytochromes C

    NASA Astrophysics Data System (ADS)

    Tripathy, Jagnyaseni

    Picosecond time-resolved fluorescence spectroscopy was employed to characterize the equilibrium and non-equilibrium protein structural fluctuations in Zn II-substituted (ZnCytc) and metal-free (fbCytc) cytochromes c using dynamic fluorescence Stokes shift (FSS) and fluorescence anisotropy (FA) measurements. The intrinsic porphyrin chromophore is used as the probe for the structural fluctuations of the surrounding protein and solvent. The FSS experiments examine how the time scales detected from the dynamic solvation of a chromoprotein report changes in the character of motion. ZnCytc and fbCytc serve as limited, single-chromophore models for photosynthetic reaction center and light-harvesting proteins. The dynamic solvation of redox and light-harvesting chromophores in photosynthesis plays an important role in the quantum efficiency of electron transfer and energy transfer performed by these systems, respectively. The FSS response function of fbCytc in water is biexponential over the 100-ps--50-ns regime and the two time constants are 1.4 ns and 9.1 ns. ZnCytc under similar solution conditions shows a biexponential FSS response but with time constants of 0.2 ns and 1.5 ns. The two correlation times from the FSS response function correspond to motions of the hydrophobic core and the solvent-contact layer, respectively. Both FSS correlation times were lengthened and the solvation reorganization energy was reduced from 43 cm-1 to 33 cm-1 in the presence of 50% (v/v) glycerol. A Brownian diffusion model with thermally activated barrier crossings on the protein-folding energy landscape is used to interpret these results. The conclusion is that the mean-squared deviations of the fluctuations exhibited by fbCytc are perhaps a factor of ten larger than those in ZnCytc, which is consistent with the suggestion that fbCytc assumes a dynamic, partially unfolded structure with some of the characteristics of a molten globule. The nature of the motion associated with the

  2. Tunable Far Infrared Studies in Support of Stratospheric Measurements

    NASA Technical Reports Server (NTRS)

    Chance Kelly; Park, K.; Nolt, I. G.; Evenson, K. M.

    1998-01-01

    The research performed during this reporting period has been a collaboration between institutions including the Smithsonian Astrophysical Observatory, the National Institute of Standards and Technology, the University of Oregon, and the NASA Langley Research Center. The program has included fully line-resolved measurements of submillimeter and far infrared spectroscopic line parameters (pressure broadening coefficients and their temperature dependences, and fine positions) for the analysis of field measurements of stratospheric constituents, far infrared database improvements, and studies for improved satellite measurements of the Earth's atmosphere. This research program is designed to enable the full utilization of spectra obtained in far infrared/submillimeter field measurements, such as FIRS-2, FILOS, IBEX, SLS, EosMLS, and proposed NASA and European Space Agency measurements of ClO and OH (e.g., PIRAMHYD) for the retrieval of accurate stratospheric altitude profiles of key trace gases involved in ozone layer photochemistry.

  3. Homogeneity study of ointment dosage forms by infrared imaging spectroscopy.

    PubMed

    Carneiro, Renato Lajarim; Poppi, Ronei Jesus

    2012-01-25

    Ointment dosage forms are semi-solid preparations intended for local or transdermal delivery of active substances usually for application to the skin and it is important that they present a homogeneous appearance. In this work, a study of the homogeneity of a tacrolimus ointment dosage form was performed using infrared imaging spectroscopy coupled with principal component analysis (PCA) and multivariate curve resolution with alternating least squares (MCR-ALS) to interpret the imaging data. Optical visible microscopy images indicated possible phase separation in the ointment and, based on the results presented by distribution concentration maps from infrared imaging, it was possible to conclude that, in fact, there was phase separation incorporated in the ointment. Thus, infrared imaging spectroscopy associated to PCA and MCR-ALS is demonstrated to be a powerful tool for the development process of ointment dosage forms. PMID:22018891

  4. Infrared Heterodyne Spectroscopy and its Unique Application to Planetary Studies

    NASA Technical Reports Server (NTRS)

    Kostiuk, Theodore

    2009-01-01

    Since the early 1970's the infrared heterodyne technique has evolved into a powerful tool for the study of molecular constituents, temperatures, and dynamics in planetary atmospheres. Its extremely high spectral resolution (Lambda/(Delta)Lambda/>10(exp 6)) and highly accurate frequency measurement (to 1 part in 10(exp 8)) enabled the detection of nonthermal/natural lasing phenomena on Mars and Venus; direct measurements of winds on Venus, Mars, and Titan; study of mid-infrared aurorae on Jupiter; direct measurement of species abundances on Mars (ozone, isotopic CO2), hydrocarbons on Jupiter, Saturn., Neptune, and Titan, and stratospheric composition in the Earth's stratosphere (O3, CIO, N2O, CO2 ....). Fully resolved emission and absorption line shapes measured by this method enabled the unambiguous retrieval of molecular abundances and local temperatures and thermal structure in regions not probed by other techniques. The mesosphere of Mars and thermosphere of Venus are uniquely probed by infrared heterodyne spectroscopy. Results of these studies tested and constrained photochemical and dynamical theoretical models describing the phenomena measured. The infrared heterodyne technique will be described. Highlights in its evolution to today's instrumentation and resultant discoveries will be presented, including work at Goddard Space Flight Center and the University of Koln. Resultant work will include studies supporting NASA and ESA space missions and collaborations between instrumental and theoretical groups.

  5. Social Perception in Infancy: A Near Infrared Spectroscopy Study

    ERIC Educational Resources Information Center

    Lloyd-Fox, Sarah; Blasi, Anna; Volein, Agnes; Everdell, Nick; Elwell, Claire E.; Johnson, Mark H.

    2009-01-01

    The capacity to engage and communicate in a social world is one of the defining characteristics of the human species. While the network of regions that compose the social brain have been the subject of extensive research in adults, there are limited techniques available for monitoring young infants. This study used near infrared spectroscopy to…

  6. Picosecond DPSS laser technology for OPCPA pumping

    NASA Astrophysics Data System (ADS)

    Vaupel, Andreas; Bodnar, Nathan; Webb, Benjamin; Shah, Lawrence; Richardson, Martin

    2014-02-01

    We present the design and challenges of a diode-pumped solid-state (DPSS) system to amplify picosecond pulses to high pulse energies and high average powers. We discuss our implemented solutions to mitigate thermal effects and present the obtained performance of the picosecond pulse amplification at the multi-10-MW level. Our here presented picosecond DPSS laser is well suited for pumping an optical parametric chirped-pulse amplification (OPCPA) system. Several laser technologies have been employed to pump OPCPA systems and we show how our DPSS system compares in performance to the other approaches.

  7. Infrared Study of Fullerene Planetary Nebulae

    NASA Astrophysics Data System (ADS)

    García-Hernández, D. A.; Villaver, E.; García-Lario, P.; Acosta-Pulido, J. A.; Manchado, A.; Stanghellini, L.; Shaw, R. A.; Cataldo, F.

    2012-12-01

    We present a study of 16 planetary nebulae (PNe) where fullerenes have been detected in their Spitzer Space Telescope spectra. This large sample of objects offers a unique opportunity to test conditions of fullerene formation and survival under different metallicity environments because we are analyzing five sources in our own Galaxy, four in the Large Magellanic Cloud (LMC), and seven in the Small Magellanic Cloud (SMC). Among the 16 PNe studied, we present the first detection of C60 (and possibly also C70) fullerenes in the PN M 1-60 as well as of the unusual ~6.6, 9.8, and 20 μm features (attributed to possible planar C24) in the PN K 3-54. Although selection effects in the original samples of PNe observed with Spitzer may play a potentially significant role in the statistics, we find that the detection rate of fullerenes in C-rich PNe increases with decreasing metallicity (~5% in the Galaxy, ~20% in the LMC, and ~44% in the SMC) and we interpret this as a possible consequence of the limited dust processing occurring in Magellanic Cloud (MC) PNe. CLOUDY photoionization modeling matches the observed IR fluxes with central stars that display a rather narrow range in effective temperature (~30,000-45,000 K), suggesting a common evolutionary status of the objects and similar fullerene formation conditions. Furthermore, the data suggest that fullerene PNe likely evolve from low-mass progenitors and are usually of low excitation. We do not find a metallicity dependence on the estimated fullerene abundances. The observed C60 intensity ratios in the Galactic sources confirm our previous finding in the MCs that the fullerene emission is not excited by the UV radiation from the central star. CLOUDY models also show that line- and wind-blanketed model atmospheres can explain many of the observed [Ne III]/[Ne II] ratios using photoionization, suggesting that possibly the UV radiation from the central star, and not shocks, is triggering the decomposition of the

  8. INFRARED STUDY OF FULLERENE PLANETARY NEBULAE

    SciTech Connect

    Garcia-Hernandez, D. A.; Acosta-Pulido, J. A.; Manchado, A.; Garcia-Lario, P.; Stanghellini, L.; Shaw, R. A.; Cataldo, F. E-mail: amt@iac.es E-mail: Pedro.Garcia-Lario@sciops.esa.int E-mail: letizia@noao.edu

    2012-12-01

    We present a study of 16 planetary nebulae (PNe) where fullerenes have been detected in their Spitzer Space Telescope spectra. This large sample of objects offers a unique opportunity to test conditions of fullerene formation and survival under different metallicity environments because we are analyzing five sources in our own Galaxy, four in the Large Magellanic Cloud (LMC), and seven in the Small Magellanic Cloud (SMC). Among the 16 PNe studied, we present the first detection of C{sub 60} (and possibly also C{sub 70}) fullerenes in the PN M 1-60 as well as of the unusual {approx}6.6, 9.8, and 20 {mu}m features (attributed to possible planar C{sub 24}) in the PN K 3-54. Although selection effects in the original samples of PNe observed with Spitzer may play a potentially significant role in the statistics, we find that the detection rate of fullerenes in C-rich PNe increases with decreasing metallicity ({approx}5% in the Galaxy, {approx}20% in the LMC, and {approx}44% in the SMC) and we interpret this as a possible consequence of the limited dust processing occurring in Magellanic Cloud (MC) PNe. CLOUDY photoionization modeling matches the observed IR fluxes with central stars that display a rather narrow range in effective temperature ({approx}30,000-45,000 K), suggesting a common evolutionary status of the objects and similar fullerene formation conditions. Furthermore, the data suggest that fullerene PNe likely evolve from low-mass progenitors and are usually of low excitation. We do not find a metallicity dependence on the estimated fullerene abundances. The observed C{sub 60} intensity ratios in the Galactic sources confirm our previous finding in the MCs that the fullerene emission is not excited by the UV radiation from the central star. CLOUDY models also show that line- and wind-blanketed model atmospheres can explain many of the observed [Ne III]/[Ne II] ratios using photoionization, suggesting that possibly the UV radiation from the central star, and

  9. Metal nanofilms studied with infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Fahsold, Gerhard; Priebe, Andreas; Pucci, Annemarie; Otto, Andreas

    2006-03-01

    Metal films with thickness in the nanometer range are optically transparent. In the IR range their transmittance may show both the Drude-type behaviour of coalesced islands and the tail of the plasmon absorption of single islands. Therefore, IR transmittance spectroscopy is a sensitive tool for in-situ studies of metal-film growth on insulating substrates and of the film conductivity. With IR transmittance spectroscopy the in-plane film conductivity and its correlation to the film-growth process can be determined without electrical contacts. Adsorbate induced changes can be observed well. Their analysis may give insight into the adsorbate-metal bonding. Depending on the film's roughness the IR lines of adsorbate-vibration modes may be strongly modified because of their interaction with electronic excitations of the film. The atomic roughness of cold-condensed metal films produces additional IR activity: strong IR activity of Raman lines of centrosymmetric adsorbate molecules is observed in those cases where the adsorbate has states close to the Fermi level.

  10. Infrared laboratory studies of synthetic planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Williams, D.

    1972-01-01

    The initial stages of the research were involved with a test of Burch's law of multiplicative transmittance for mixed absorbing gases when their lines are broadened by H2 and He, which are constituents of the atmospheres of the major planets. The broadening of individual lines in the CO fundamental by various gases was investigated. Line strength and half-width for individual CO lines were studied as a function of temperature. Measurements of total band absorptance as a function of absorber thickness and total effective pressure were made at various temperatures for bands of CO and N2O. Attempts were made to develop a phenomenological theory of line broadening that would account for the phenomena observed for the CO fundamental and those reported for more highly polar gases. Laboratory measurements of nitric acid vapor absorptance were compared with balloon measurements in arriving at an estimate of the quantity of nitric acid vapor present in the earth's atmosphere in the region of the ozone layer.

  11. Study of Heat Transfer Dynamics from Gold Nanorods to the Environment via Time-Resolved Infrared Spectroscopy.

    PubMed

    Nguyen, Son C; Zhang, Qiao; Manthiram, Karthish; Ye, Xingchen; Lomont, Justin P; Harris, Charles B; Weller, Horst; Alivisatos, A Paul

    2016-02-23

    Studying the local solvent surrounding nanoparticles is important to understanding the energy exchange dynamics between the particles and their environment, and there is a need for spectroscopic methods that can dynamically probe the solvent region that is in nearby contact with the nanoparticles. In this work, we demonstrate the use of time-resolved infrared spectroscopy to track changes in a vibrational mode of local water on the time scale of hundreds of picoseconds, revealing the dynamics of heat transfer from gold nanorods to the local water environment. We applied this probe to a prototypical plasmonic photothermal system consisting of organic CTAB bilayer capped gold nanorods, as well as gold nanorods coated with varying thicknesses of inorganic mesoporous-silica. The heat transfer time constant of CTAB capped gold nanorods is about 350 ps and becomes faster with higher laser excitation power, eventually generating bubbles due to superheating in the local solvent. Silica coating of the nanorods slows down the heat transfer and suppresses the formation of superheated bubbles. PMID:26840805

  12. Fundamentals of picosecond laser ultrasonics.

    PubMed

    Matsuda, Osamu; Larciprete, Maria Cristina; Li Voti, Roberto; Wright, Oliver B

    2015-02-01

    The aim of this article is to provide an introduction to picosecond laser ultrasonics, a means by which gigahertz-terahertz ultrasonic waves can be generated and detected by ultrashort light pulses. This method can be used to characterize materials with nanometer spatial resolution. With reference to key experiments, we first review the theoretical background for normal-incidence optical detection of longitudinal acoustic waves in opaque single-layer isotropic thin films. The theory is extended to handle isotropic multilayer samples, and is again compared to experiment. We then review applications to anisotropic samples, including oblique-incidence optical probing, and treat the generation and detection of shear waves. Solids including metals and semiconductors are mainly discussed, although liquids are briefly mentioned. PMID:24998119

  13. Timing high-speed microprocessor circuits using picosecond imaging circuit analysis

    NASA Astrophysics Data System (ADS)

    Steen, Steven E.; McManus, Moyra K.; Manzer, Dennis G.

    2001-04-01

    IBM Research has developed a time resolved imaging technique, Picosecond Imaging Circuit Analysis (PICA), which uses single photon events to analyze signals in modern microprocessors on a picosecond time scale. This paper will describe the experimental setup as well as the data management software. A case study of a particularly hard debug problem on a state of the art microprocessor will demonstrate the application of the PICA method.

  14. Comprehensive Infrared Study of Tetryl, Dinitrotoluene, and Trinitrotoluene Compounds.

    PubMed

    Puiu, Adriana; Giubileo, Gianfranco; Cesaro, Stella Nunziante; Bencivenni, Luigi

    2015-12-01

    The present work describes an experimental and theoretical study of energetic materials used for detecting explosives in order to prevent terrorist actions, as well as for de-mining projects. Particular attention was devoted to examining the infrared absorption spectroscopy of classic explosives in order to create a useful mobile apparatus for on-field detection of explosives. This paper reports the vibrational absorption spectra of tetryl, dinitrotoluene, and trinitrotoluene molecules approached using two different spectroscopic techniques, Fourier transform infrared spectroscopy (FT-IR) and laser photoacoustic spectroscopy (LPAS). Diffuse reflectance Fourier transform infrared spectra of all samples were analyzed in a very wide spectral range (400-7500 cm(-1)) showing for the first time the existence of weak absorption bands attributable to overtones or combination bands, while laser photoacoustic spectroscopy spectra have been investigated in the fingerprint region of organic compounds that share the CO2 laser emission range (~920-1100 cm(-1)). The Fourier transform infrared spectra of both matrix isolated dinitrotoluenes have been also investigated. The theoretical treatment of tetryl is reported for the first time. PMID:26555761

  15. Conceptual design study for Infrared Limb Experiment (IRLE)

    NASA Technical Reports Server (NTRS)

    Baker, Doran J.; Ulwick, Jim; Esplin, Roy; Batty, J. C.; Ware, Gene; Tew, Craig

    1989-01-01

    The phase A engineering design study for the Infrared Limb Experiment (IRLE) instrument, the infrared portion of the Mesosphere-Lower Thermosphere Explorer (MELTER) satellite payload is given. The IRLE instrument is a satellite instrument, based on the heritage of the Limb Infrared Monitor of the Stratosphere (LIMS) program, that will make global measurements of O3, CO2, NO, NO2, H2O, and OH from earth limb emissions. These measurements will be used to provide improved understanding of the photochemistry, radiation, dynamics, energetics, and transport phenomena in the lower thermosphere, mesosphere, and stratosphere. The IRLE instrument is the infrared portion of the MELTER satellite payload. MELTER is being proposed to NASA Goddard by a consortium consisting of the University of Michigan, University of Colorado and NASA Langley. It is proposed that the Space Dynamics Laboratory at Utah State University (SDL/USU) build the IRLE instrument for NASA Langley. MELTER is scheduled for launch in November 1994 into a sun-synchronous, 650-km circular orbit with an inclination angle of 97.8 deg and an ascending node at 3:00 p.m. local time.

  16. Snow studies using thermal infrared observations from earth satellites

    NASA Technical Reports Server (NTRS)

    Barnes, J. C.

    1972-01-01

    The application of satellite high resolution infrared data was studied for mapping snow cover. The study has two objectives: (1) to determine whether existing radiometers onboard the Nimbus and ITOS satellites can provide hydrologically useful snow information, and (2) to develop analysis techniques applicable to future IR sensor systems on earth satellites. The IR measurements are being analyzed in conjunction with concurrent satellite photographs and conventional snow cover data.

  17. Environmental Affects on Surfactin Studied Using Multidimensional Infrared Spectroscopy

    NASA Astrophysics Data System (ADS)

    Nite, Jacob; Krummel, Amber

    2014-03-01

    Surfactin, a cyclic lipopeptide produced by Bacillus subtilis, is a pore forming toxin that has been studied in the literature extensively. It is known to exist in two different conformations, S1 and S2, which are thought to relate to surfactin's pore forming ability. The vibrational characteristics of surfactin have been studied using linear infrared spectroscopy as well as two-dimensional infrared spectroscopy in different environments. The environments probed were specifically chosen to mimic surfactin in an aqueous environment as well as a lipid membrane environment. The vibrational spectra were interpreted using transitional dipole coupling to relate the coupling evident in the data to the structural conformers obtained from NMR data. These measurements have been used to link the structural characteristics of surfactin to different solvent environments to gain insight into surfactin's pore forming ability mechanisms. Colorado State University. Maciel Fellowship.

  18. Infrared Structural Biology: Detect Functionally Important Structural Motions of Proteins

    NASA Astrophysics Data System (ADS)

    Xie, Aihua

    Proteins are dynamic. Lack of dynamic structures of proteins hampers our understanding of protein functions. Infrared structural biology (IRSB) is an emerging technology. There are several advantages of IRSB for mechanistic studies of proteins: (1) its excellent dynamic range (detecting structural motions from picoseconds to >= seconds); (2) its high structural sensitivity (detect tiny but functionally important structural motions such as proton transfer and changes in hydrogen bonding interaction); (3) its ability to detect different structural motions simultaneously. Successful development of infrared structural biology demands not only new experimental techniques (from infrared technologies to chemical synthesis and cell biology), but also new data processing (how to translate infrared signals into quantitative structural information of proteins). These topics will be discussed as well as examples of how to use IRSB to study structure-function relationship of proteins. This work was supported by NSF DBI1338097 and OCAST HR10-078.

  19. [Study on spectral emission characteristics of infrared lamps].

    PubMed

    Wang, J; Chen, Z; Gu, B; Luo, Y; Wang, T

    1999-04-01

    The spectral characteristics at wavelength ranges of 0.35-0.85 microm and 1.72-16.7 microm (5800-600 cm(-1)) for both domestic and imported infrared lamps used in scientific research, industry, medical service, home electrical appliance etc. have heen studied and compared. This paper has provided the theoreical and experimental bases for their applications and improvement in designs, technology of manufacture, quality and performance. PMID:15819000

  20. Infrared spectroscopic study of sputtered tungsten oxide films

    SciTech Connect

    Paul, J.L.; Lassegues, J.C. )

    1993-10-01

    Recent infrared and Raman spectroscopic studies of various tungsten oxide films concluded either the formation of W=O terminal bonds or the transformation of such bonds into W-OH groups upon proton insertion. The infrared transmission and reflection spectra of bleached and colored sputtered films were reinvestigated in order to resolve the previous contradictory interpretations and for better insight into the mechanism of electrochromism at the molecular level. The new results confirm the first interpretation and allow us to show that H[sup +] or Li[sup +] insertion creates shorter ([approximately]1.7[angstrom]) and longer ([approximately]2 [angstrom]) W-O bonds around the W[sup 5+] centers. These results are in agreement with the concepts of small polaron and of intervalence charge transfer mechanism. They illustrate the local lattice distortion around a W[sup 5+] site. Aging of the initial films has also been followed and characterized by H/D in situ isotopic exchange.

  1. Study of oral cavity lesions by infrared spectroscopy.

    PubMed

    Giorgini, E; Conti, C; Rocchetti, R; Rubini, C; Sabbatini, S; Librando, V; Tosi, G

    2016-01-01

    Fourier transform infrared (FTIR) microspectroscopy is considered a useful tool in the biomedical field, for analysing in situ and at cellular level, very small areas of tissues and cells, with minimal sample preparation and without the use of stains or probes. This spectroscopic technique has been successfully applied to analyse biological samples from patients affected by tumoral pathologies, with particular attention to oral cavity lesions. In this study, we describe the application of FTIR microspectroscopy to characterize and discriminate the most recurrent benign and malignant diseases of oral cavity compartment. Infrared maps were acquired on tissues affected by the following pathologies: squamous cell carcinoma, adenoid cystic carcinoma, polymorphous low-grade adenocarcinoma, squamous dysplasia, keratocystic odontogenic tumor, radicular cyst, residual cyst, unicystic ameloblastoma, and ameloblastic fibroma, together with healthy tissue samples (used as control group). The epithelial and connective components of all samples were distinguished and submitted to multivariate analysis. The results were in agreement with histological suggestions. PMID:27049108

  2. Picosecond optical vortex pulse illumination forms a monocrystalline silicon needle

    NASA Astrophysics Data System (ADS)

    Takahashi, Fuyuto; Miyamoto, Katsuhiko; Hidai, Hirofumi; Yamane, Keisaku; Morita, Ryuji; Omatsu, Takashige

    2016-02-01

    The formation of a monocrystalline silicon needle by picosecond optical vortex pulse illumination was demonstrated for the first time in this study. The dynamics of this silicon needle formation was further revealed by employing an ultrahigh-speed camera. The melted silicon was collected through picosecond pulse deposition to the dark core of the optical vortex, forming the silicon needle on a submicrosecond time scale. The needle was composed of monocrystalline silicon with the same lattice index (100) as that of the silicon substrate, and had a height of approximately 14 μm and a thickness of approximately 3 μm. Overlaid vortex pulses allowed the needle to be shaped with a height of approximately 40 μm without any changes to the crystalline properties. Such a monocrystalline silicon needle can be applied to devices in many fields, such as core-shell structures for silicon photonics and photovoltaic devices as well as nano- or microelectromechanical systems.

  3. One- and two-dimensional infrared spectroscopic studies of solution-phase homogeneous catalysis and spin-forbidden reactions

    SciTech Connect

    Sawyer, Karma Rae

    2008-12-01

    Understanding chemical reactions requires the knowledge of the elementary steps of breaking and making bonds, and often a variety of experimental techniques are needed to achieve this goal. The initial steps occur on the femto- through picosecond time-scales, requiring the use of ultrafast spectroscopic methods, while the rate-limiting steps often occur more slowly, requiring alternative techniques. Ultrafast one and two-dimensional infrared and step-scan FTIR spectroscopies are used to investigate the photochemical reactions of four organometallic complexes. The analysis leads to a detailed understanding of mechanisms that are general in nature and may be applicable to a variety of reactions.

  4. Thermal Infrared Studies of Chloride Salts; Implications for Mars

    NASA Astrophysics Data System (ADS)

    Baldridge, A. M.; Osterloo, M. M.; Christensen, P. R.

    2007-12-01

    Morphological and spectral evidence supporting the past occurrence of widespread water on the surface of Mars continues to build. Furthermore, geochemical footprints of water are especially compelling. As a past reservoir of water receded, it would have left behind evaporitic chemistries specific to Martian water-rock interactions (e.g. chlorides, sulfates and phyllosilicates). To understand the extent and abundance of past water, the detection of such minerals is key. In support of both orbital and in situ thermal infrared (TIR) observations, we have examined the TIR behavior of chloride minerals. In the thermal infrared, most minerals are identified based on characteristic absorption features. However, chloride detection is particularly challenging because these minerals are transparent over much of the infrared and therefore their identification must be based on the effect that they have on the spectra of coexisting materials. Additionally, the transparent nature of chlorides results in greybody (non-unit emissivity) behavior and consequently the standard calibration techniques to convert from radiance to emissivity produces a slope in the spectra. Here we discuss laboratory spectral studies including emission, reflectance, and transmission spectra of a suite of chloride minerals and mixtures. These studies are then used to interpret a spectrally distinct deposit identified with 2001 Odyssey Thermal Emission Imaging System (THEMIS) data in the low albedo, mid-to-low latitude, southern highlands of Mars which correspond to mid- late Noachian aged terrains and early Hesperian aged ridged plains units.

  5. Femtosecond-picosecond laser photolysis studies on the dynamics of excited charge-transfer complexes: Aromatic hydrocarbon-acid anhydride, -tetracyanoethylene, and -tetracyanoquinodimethane systems in acetonitrile solutions

    SciTech Connect

    Asahi, Tsuyoshi; Mataga, Noboru )

    1991-03-07

    Formation processes of contact ion pairs (CIP) from the excited Franck-Condon (FC) state of charge-transfer (CT) complexes of aromatic hydrocarbons with acid anhydride as well as cyano compound acceptors in acetonitrile solution and charge recombination (CR) rates (k{sub CR}{sup CIP}) of produced CIP states have been investigated by femtosecond and picosecond laser phototlysis and time-resolved absorption spectral measurements covering a wide range of free energy gap-{Delta}G{degree}{sub ip} between the ion pair and the ground state. It has been confirmed that the CIP formation becomes faster and k{sub CR}{sup CIP} of the produced CIP increases with increase of the strengths of the electron donor (D) and acceptor (A) in the complex, i.e., with decrease of the {minus}{Delta}G{degree}{sub ip} value. This peculiar energy gap dependence of k{sub CR}{sup CIP}, quite different from the bell-shaped one observed in the case of the solvent-separated ion pairs (SSIP) or loose ion pairs (LIP) formed by encounter between fluorescer and quencher in the fluoresence quenching reaction, has been interpreted by assuming the change of electronic and geometrical structures of CIP depending on the strengths of D and A.

  6. Picosecond and nanosecond studies of the photoreduction of benzophenone by 1,4-diazabicyclo(2. 2. 2)octane: Characterization of the transient

    SciTech Connect

    Devadoss, C.; Fessenden, R.W. )

    1990-05-31

    The transient that is produced in the quenching of triplet benzophenone by 1,4-diazabicyclo(2.2.2)octane (DABCO) has been examined by use of nano- and picosecond laser photolysis. The initial step in all solvents, both polar and nonpolar, is electron transfer to form a triplet contact ion pair. In nonpolar solvents, the ion pair remains in this form until it decays. For polar solvents, the spectra change somewhat over the first 100 ps showing that the solvation changes and the ion pair becomes solvent separated. The lifetime of the ion pair varies greatly with the solvent. In saturated hydrocarbons it is about 80 ps. Nonpolar solvents with either {pi} electrons or a lone pair of electrons stabilize the ion pair on the nanosecond to microsecond time scale. A small amount of alcohol in benzene also stabilizes the ion pair by hydrogen bonding. A shift in the peak position with time toward the blue accompanies the formation of hydrogen bonds in this case.

  7. Sub-Picosecond Injection of Electrons from Excited [Ru (2,2'-bipy-4,4'-dicarboxy)2(SCN)2] into TiO2 Using Transient Mid-Infrared Spectroscopy

    SciTech Connect

    Ellingson, R. J.; Asbury, J. B.; Ferrere, S.; Ghosh, H. N.; Sprague, J. R.; Lian, T.; Nozik, A. J.

    1999-05-04

    We have used femtosecond pump-probe spectroscopy to time resolve the injection of electrons into nanocrystalline TiO2 film electrodes under ambient conditions following photoexcitation of the adsorbed dye, [Ru(4,4'-dicarboxy-2,2'-bipyridine)2(NCS)2] (N3). Pumping at one of the metal-to-ligand charge transfer adsorption peaks and probing the absorption of electrons injected into the TiO2 conduction band at 1.52 {micro}m and in the range of 4.1 to 7.0 {micro}m, we have directly observed the arrival of the injected electrons. Our measurements indicate an instrument-limited {approx}50-fs upper limit on the electron injection time under ambient conditions in air. We have compared the infrared transient absorption for noninjecting (blank) systems consisting of N3 in ethanol and N3 adsorbed to films of nanocrystalline Al2O3 and ZrO2, and found no indication of electron injection at probe wavelengths in the mid-IR (4.1 to 7.0 {micro}m). At 1.52 {micro}m interferences exist in the observed transient adsorption signal for the blanks.

  8. Studies of planetary boundary layer by infrared thermal imagery

    SciTech Connect

    Albina, Bogdan; Dimitriu, Dan Gheorghe Gurlui, Silviu Octavian; Cazacu, Marius Mihai; Timofte, Adrian

    2014-11-24

    The IR camera is a relatively novel device for remote sensing of atmospheric thermal processes from the Planetary Boundary Layer (PBL) based on measurements of the infrared radiation. Infrared radiation is energy radiated by the motion of atoms and molecules on the surface of aerosols, when their temperature is more than absolute zero. The IR camera measures directly the intensity of radiation emitted by aerosols which is converted by an imaging sensor into an electric signal, resulting a thermal image. Every image pixel that corresponds to a specific radiance is pre-processed to identify the brightness temperature. The thermal infrared imaging radiometer used in this study, NicAir, is a precision radiometer developed by Prata et al. The device was calibrated for the temperature range of 270–320 K and using a calibration table along with image processing software, important information about variations in temperature can be extracted from acquired IR images. The PBL is the lowest layer of the troposphere where the atmosphere interacts with the ground surfaces. The importance of PBL lies in the fact that it provides a finite but varying volume in which pollutants can disperse. The aim of this paper is to analyze the PBL altitude and thickness variations over Iasi region using the IR imaging camera as well as its behavior from day to night and thermal processes occurring in PBL.

  9. Studies of dust grain properties in infrared reflection nebulae.

    PubMed

    Pendleton, Y J; Tielens, A G; Werner, M W

    1990-01-20

    We have developed a model for reflection nebulae around luminous infrared sources embedded in dense dust clouds. The aim of this study is to determine the sizes of the scattering grains. In our analysis, we have adopted an MRN-like power-law size distribution (Mathis, Rumpl, and Nordsieck) of graphite and silicate grains, but other current dust models would give results which were substantially the same. In the optically thin limit, the intensity of the scattered light is proportional to the dust column density, while in the optically thick limit, it reflects the grain albedo. The results show that the shape of the infrared spectrum is the result of a combination of the scattering properties of the dust, the spectrum of the illuminating source, and foreground extinction, while geometry plays a minor role. Comparison of our model results with infrared observations of the reflection nebula surrounding OMC-2/IRS 1 shows that either a grain size distribution like that found in the diffuse interstellar medium, or one consisting of larger grains, can explain the observed shape of the spectrum. However, the absolute intensity level of the scattered light, as well as the observed polarization, requires large grains (approximately 5000 angstroms). By adding water ice mantles to the silicate and graphite cores, we have modeled the 3.08 micrometers ice band feature, which has been observed in the spectra of several infrared reflection nebulae. We show that this ice band arises naturally in optically thick reflection nebulae containing ice-coated grains. We show that the shape of the ice band is diagnostic of the presence of large grains, as previously suggested by Knacke and McCorkle. Comparison with observations of the BN/KL reflection nebula in the OMC-1 cloud shows that large ice grains (approximately 5000 angstroms) contribute substantially to the scattered light. PMID:11538693

  10. Photoluminescence Study of Long Wavelength Superlattice Infrared Detectors

    NASA Technical Reports Server (NTRS)

    Hoglund, Linda; Khoshakhlagh, Arezou; Soibel, Alexander; Ting, David Z.; Hill, Cory J.; Keo, Sam; Gunapala, Sarath D.

    2011-01-01

    In this paper, the relation between the photoluminescence (PL) intensity and the PL peak wavelength was studied. A linear decrease of the PL intensity with increasing cut-off wavelength of long wavelength infrared CBIRDs was observed at 77 K and the trend remained unchanged in the temperature range 10 - 77 K. This relation between the PL intensity and the peak wavelength can be favorably used for comparison of the optical quality of samples with different PL peak wavelengths. A strong increase of the width of the PL spectrum in the studied temperature interval was observed, which was attributed to thermal broadening.

  11. Shaping pulses using frequency conversion with a modulated picosecond free electron laser

    SciTech Connect

    Hooper, B.A.; Madey, J.M.J.

    1995-12-31

    Computer simulations and experiments indicate that we can shape the infrared picosecond pulses of the Mark III FEL in amplitude, frequency, and phase. Strongly modulated fundamental and second harmonic pulses have been generated by operating the Mark III FEL in the regime of strong sideband growth. In this paper, we present the results of simulations and experiments for second harmonic generation with fundamental inputs from 2 to 3 {mu}m.

  12. Observation of coherent undulator radiation from sub-picosecond electron pulses

    SciTech Connect

    Bocek, D.; Hernandez, M.; Kung, P.; Lihn, Hung-chi; Settakorn, C.; Wiedemann, H.

    1995-09-01

    The generation and observation of high power, coherent, far-infrared undulator radiation from sub-picosecond electron bunches at the SUNSHINE facility is reported. Coherent undulator radiation tunable from 50 to 200 microns wavelength is demonstrated. Measurements of the energy (up to 1.7 mJ per 1 microsecs macropulse), frequency spectrum, and spatial distribution of the radiation are reported. Apparent exponential growth of the radiated energy as a function of undulator length is observed.

  13. Infrared Imaging, Spectroscopic, and Photometric Studies of Comets

    NASA Technical Reports Server (NTRS)

    Gehrz, Robert D.

    1997-01-01

    We have continued our program of infrared (IR) photometric, imaging, spectroscopic, and polarimetric temporal observations of comets to study the properties of comet dust and comet nuclei. During the first two years we digitized our IR data base on P/Halley and other recent comets to facilitate further analysis and comparison with other data bases, and found compelling evidence for the emission of a burst of small grains from P/Halley's nucleus at perihelion. We reported imaging and photometric observations of Comets Austin 1990 V and Swift-Tuttle 1992. The Swift-Tuttle 1992t observations included IR photometry, several 7-14 micron long-slit spectra of the coma and a time-sequence of more than 150 10 micron broadband images of the coma. An analysis of near-IR images of the inner coma of P/Halley obtained on three consecutive nights in 1986 March showed sunwardjets. We completed our analysis of IR imaging spectrosco-photometric data on comets. We also obtained observations of Comets Hyakutake 1996 B2 and Hale/Bopp 1995 01. We obtained infrared imaging, photometric, spectroscopic and polarimetric temporal observations of bright comets using a network of five telescopes, with emphasis on simultaneous observations of comets at many wavelengths with different instruments. Our program offers several unique advantages: 1) rapid observational response to new comets with dedicated infrared telescopes; 2) observations within a few degrees of the sun when comets are near perihelion and 3) access to advanced infrared array imagers and spectrometers. In particular, reduction, analysis, publication and archiving of our Jupiter/sl-9 and Comet Hyakutake infrared data received special emphasis. Instrumentation development included installation of the latest version of the innovative FORTH telescope control and a data acquisition system that enables us to control three telescopes remotely by telephone from anywhere in the world for comet observations in broad daylight. We have

  14. Lidar receivers for picosecond remote sensing

    NASA Technical Reports Server (NTRS)

    Stoyanov, D. V.; Dreischuh, T. N.

    1992-01-01

    The lidars of picosecond resolution are an attractive tool for remote probing of some highly dynamic objects like sea subsurface waters, small-scale turbulences in the atmosphere, etc. The picosecond lasers are suitable illuminating sources, but the main restrictions are due to the lack of proper receiving methods, combining the both high temporal and amplitude resolution, good sensitivity, short integration time, and wide dynamic range. The methods for short pulse measurements are not suitable for picosecond lidars, operating at low level, with highly dynamic signals. The streak-cameras are of high cost, lower sensitivity, and lower dynamic range (approximately 10(exp 3)). Because of the background, the single quantum regime in photomultipliers (PMT) is ineffective. The sampling of highly dynamic optical signals with resolution less than or equal to 1ns is a serious problem, limiting the application of the high speed PMT-MCP (microchannel plate) in the picosecond lidar systems. The goal of this work is to describe the use of a new photodetection technique which combines the picosecond resolution with the high amplitude resolution, dynamic range, and sensitivity.

  15. Picosecond time-resolved fluorescence studies on excitation energy transfer in a histidine 117 mutant of the D2 protein of photosystem II in Synechocystis 6803.

    PubMed

    Vasil'ev, S; Bruce, D

    2000-11-21

    The role of the peripheral reaction center chlorophyll a molecule associated with His117 of the D2 polypeptide in photosystem II was investigated in Synechocystis sp. PCC 6803 using a combination of steady state, pump-probe, and picosecond time-resolved fluorescence spectroscopy. Data were obtained from intact cells and isolated thylakoid membranes of a control mutant and a D2-H117T mutant, both of which lacked photosystem I. Excitation energy transfer and trapping were investigated by analyzing the data with a kinetic model that used an exact numerical solution of the Pauli master equation, taking into account available photosystem II spectral and structural information. The results of our kinetic analysis revealed the observed difference in excited-state dynamics between the H117T mutant and the control to be consistent with a retardation of the rate of excitation energy transfer from the peripheral chlorophyll of D2 (Chl at His117) to the electron-transfer pigments and an increase of the rate constant for charge recombination in the H117T mutant. The kinetic model was able to account for the experimentally observed changes in absorption cross section and fluorescence decay kinetics between the control and mutant by invoking changes in only these two rate constants. The results rule out quenching of excitation by a chlorophyll cation radical as a mechanism responsible for the lower efficiency of excitation energy utilization in the H117T mutant. Our work also demonstrates the importance of the chlorophyll associated with His117 of the D2 protein for excitation energy transfer to the PSII electron-transfer pigments and for the effective stabilization of the primary radical pair. PMID:11087370

  16. Experimental study of infrared filaments under different initial conditions

    NASA Astrophysics Data System (ADS)

    Mirell, Daniel Joseph

    In 1964, four years after the first working laser was constructed, long skinny damage tracks and fluorescence trails were seen inside of certain transparent media that were excited by intense light pulses [1]. What was so remarkable about these features was the narrowness of the spatial profile and their long propagation length in the beam in concert with the very high intensity of the light that would be necessary to produce them. A purely linear model of light propagation through such media was insufficient to explain the results of these experiments and hence a new area of nonlinear optics, latex coined filamentation (to describe the length, slimness, and intensity of the light field), was born. Filament studies begin with a medium that has a nonlinear index of refraction, n¯2, that interacts with an intense beam of light so as to cause it to self-focus. The n¯2 of liquid and solid transparent media is much higher than the n¯ 2 of gases and therefore a much higher intensity of laser source would need to be invented to begin the study of filaments in air. With the advent of the Ti-Sapphire Kerr-lens modelocked laser [2], working in combination with the development of the chirped pulse amplifier system in the mid-1990's, light intensities sufficient to produce filaments in air was realized. Since that time much experimental and theoretical work has been done to better understand some of the additional complexities that arise specifically in the filamentation of light in air using several different wavelengths (UV to IR) and pulsewidths (femto- to pico-seconds). Many theoretical models exist each with a different emphasis on the various physical mechanisms that may produce the features experimentally observed in filaments. The experimental work has sought to give the theoretician better data on some of the properties of filaments such as the: (a) spatial and temporal structure of the beam and of the produced plasma (that arises due to the high intensity light

  17. Infrared absorption study of neutron-transmutation-doped germanium

    NASA Technical Reports Server (NTRS)

    Park, I. S.; Haller, E. E.

    1988-01-01

    Using high-resolution far-infrared Fourier transform absorption spectroscopy and Hall effect measurements, the evolution of the shallow acceptor and donor impurity levels in germanium during and after the neutron transmutation doping process was studied. The results show unambiguously that the gallium acceptor level concentration equals the concentration of transmutated Ge-70 atoms during the whole process indicating that neither recoil during transmutation nor gallium-defect complex formation play significant roles. The arsenic donor levels appear at full concentration only after annealing for 1 h at 450 C. It is shown that this is due to donor-radiation-defect complex formation. Again, recoil does not play a significant role.

  18. Infrared study of γ irradiated fluoride optical fibers

    NASA Astrophysics Data System (ADS)

    Abgrall, A.; Poulain, M.; Boisde, G.; Cardin, V.; Maze, G.

    1986-05-01

    In order to develop infrared optical fiber systems in nuclear media, studies are made to know the behavior on line of fluoride glass optical fibers under irradiation. the increase of induced loss and the influence of the dose rate are given at 2.4 microns. Cycles of rela-xation at room temperature and y ray exposure allows an important bleaching and an unaffected kinetic of losses. Characterization of defects created by y radiation on bulk of ZBLA glass is carried out by means of electron spin resonance (ESR). A linear kinetic of ESR signal with dose is observed and possible models for defects are discussed.

  19. Study on detecting CFRP composites using pulsed infrared thermography

    NASA Astrophysics Data System (ADS)

    Huo, Yan; Li, Hui-Juan; Zhao, Yue-Jin; Zhang, Cun-Lin

    2011-08-01

    Composite sandwich structure has been widely used in aerospace due to its lightweight, high stiffness and strength. The quality of the structure is crucial to durability and structural integrity of the rehabilitated the structure, Delaminations, debonding and water ingressing to honeycomb are typical defects in the structure. Defects in the structure will influence the quality of product. Pulse thermography has been an effective NDE method in recent ten years. The technique uses pulse to excite the specimen, because the presence of subsurface defects reduce the diffusion rate, then temperature difference between defect area and sound area will be measured by an infrared camera. Subsurface defects become visible with time delays, it is a non-contact, quickly inspection method. Pulsed infrared thermography has been widely used in aerospace and mechanical manufacture industry because it can offer non-contact, quickly and visual examinations of defects. It is a meaningful research topic to study on quantitative testing with the structure rapidly and non-destructively. Sandwich composites with aluminum facesheet and aluminum honeycomb cores are chosen as study objectives. Some back-drilled holes with different sizes and depths in the specimen are used to simulate delaminations between plies in the strcuture .The paper presents a method for defining the boundaries, quantitatively estimating the sizes of the flaws in the CFRP using pulsed infrared thermography. Processing captured data using splinefitting, measuring the size of the defects by calculating the pixels numbers that exceed the detection threshold and computing areas of defects by binary image. Compared with the designed sizes and areas having defects, the results show that the method offers more than 90% accuracies with reference to the sizes of artificial flaws embedded in the CFRP sheet. The experimental results demonstrate the feasibility of using detection threshold to inspect the CFRP sheet. The curve of

  20. Analysis of Picosecond Pulsed Laser Melted Graphite

    DOE R&D Accomplishments Database

    Steinbeck, J.; Braunstein, G.; Speck, J.; Dresselhaus, M. S.; Huang, C. Y.; Malvezzi, A. M.; Bloembergen, N.

    1986-12-01

    A Raman microprobe and high resolution TEM have been used to analyze the resolidified region of liquid carbon generated by picosecond pulse laser radiation. From the relative intensities of the zone center Raman-allowed mode for graphite at 1582 cm{sup -1} and the disorder-induced mode at 1360 cm{sup -1}, the average graphite crystallite size in the resolidified region is determined as a function of position. By comparison with Rutherford backscattering spectra and Raman spectra from nanosecond pulsed laser melting experiments, the disorder depth for picosecond pulsed laser melted graphite is determined as a function of irradiating energy density. Comparisons of TEM micrographs for nanosecond and picosecond pulsed laser melting experiments show that the structure of the laser disordered regions in graphite are similar and exhibit similar behavior with increasing laser pulse fluence.

  1. Diode-pumped solid state laser sources of picosecond UV pulses for photobiology

    NASA Astrophysics Data System (ADS)

    Roisse, Eric; Louradour, Frederic; Couderc, Vincent; Barthelemy, Alain; Gaignet, M.; Balembois, Francois; Georges, Patrick M.; Brun, Alain

    1998-05-01

    We realized three different configurations for the production of picoseconds pulses in the UV by a diode-pumped solid-state laser. The first one is based on a diode-pumped Cr:LiSAF oscillator delivering tunable picosecond pulses in the near infrared. A Ti:Sapphire regenerative amplifier increased IR pulses energy up to 4.5 (mu) J. After doubling and tripling in two LBO crystals, we obtained pulses with an energy up to 0.14 (mu) J tunable between 273 and 286 nm. In the second scheme, based on a modelocked Nd:YAG laser, the SHG (KTP) and SFG (LBO) crystals are both inserted inside the cavity. The laser operated in a Q-switched mode-locked regime and produced 1.2 mW of UV average power in pulse of 60 picoseconds duration and 4 W peak power. In the last architecture, we used a resonant enhancement with a ring- cavity. We obtained 54% conversion efficiency in the green for picoseconds pulses at 1064 nm at 100 MHz rep. rate. A special arrangement was implemented for compensation of the birefringence and walk-off of the KTP crystal in the resonant cavity. Conversion to UV in the same cavity is in progress.

  2. The Stanford Picosecond FEL Center

    SciTech Connect

    Schwettman, H.A.; Smith, T.I.; Swent, R.L.

    1995-12-31

    In the past two years, FELs have decisively passed the threshold of scientific productivity. There are now six FEL facilities in the United States and Europe, each delivering more than 2000 hours of FEL beam time per year. at the present time approximately 100 papers are published each in referred journals describing optics experiments performed with FELs. Despite the recent success there are important challenges the FEL facilities must address. At Stanford these challenges include: (1) Providing sufficient experimental time at reasonable cost: At Stanford we provide 2000 hours of experimental time per year at a cost of approximately $500 per hour: We are now studying options for markedly increasing experimental time and decreasing cost per hour. (2) Competing effectively with conventional lasers in the mid-IR: Despite the NRC report we do not intend to concede the mid-IR to conventional lasers. FELs are capable of providing optical beams of exceptional quality and stability, and they can also be remarkable flexible devices. Improvements in our superconducting linac driver and our optical beam conditioning systems will dramatically enhance our FEL experimental capabilities. (3) making the transition from first generation to second generation experiments: Important pump-probe and photon echo experiments have been performed at Stanford and others are feasible using present capabilities. None-the-less we are now investing substantial experimental time to improving signal-to-noise and developing other optical cababilities. (4) Extending operation to the far-infrared where the FEL is unique inits capabilities: {open_quotes}FIREFLY{close_quotes} will extend our FEL capabilities to 100 microns. We are now seeking funds for optical instrumentation. (5) Creating and maintaining a good environment for graduate students.

  3. Infrared Study of Galaxies in the Zone of Avoidance

    NASA Astrophysics Data System (ADS)

    Arrieta, Andres; Lebron, M. E.; Pantoja, C.

    2014-01-01

    The Zone of Avoidance (ZoA) is a region of the sky in which extinction at optical wavelengths is very high due to the gas and dust of the Milky Way (e.g. Kraan-Korteweg et al. 2000, A&ARv, 10, 211). This region is bounded by low latitudes in the galactic coordinate system. A visual inspection of optical or infrared images and HI surveys are still the best ways to identify new galaxy candidates in the ZoA. Many all sky surveys at long wavelengths have been completed and are available through public databases (e.g. WISE, SDSS) allowing their use in other research projects. In this poster we present the results of an infrared study of a small region in the anti-center ZoA taking advantage of IRSA/IPAC archive data. We searched for infrared emission for a sample of 86 galaxies studied in HI by Pantoja et al. (1994, AJ, 108, 92). The WISE space telescope archived data at 3.4, 4.6, 12μm and 22μm was used. Composed images using the 3.4, 4.6 and 12μm bands are presented together with single images of the 22 μm band. Most of the galaxies detected in HI by Pantoja et al. (1994) are bright at 12 and 22μm, indicating the presence of hot dust. This is expected from galaxies with a lot of gas, dust and star formation. On the other hand, most of the 56 galaxies without HI emission are brighter at 3.4 and 4.6μm and had no emission in the 22μm band. These characteristics may be linked to small amount of gas and dust. This research has made use of the NASA/IPAC Infrared Science Archive, which is operated by the Jet Propulsion Laboratory, California Institute of Technology, under contract with the National Aeronautics and Space Administration. We gratefully acknowledge the support from the Fundación Comunitaria de Puerto Rico for this project.

  4. Picosecond photoresponse in van der Waals heterostructures.

    PubMed

    Massicotte, M; Schmidt, P; Vialla, F; Schädler, K G; Reserbat-Plantey, A; Watanabe, K; Taniguchi, T; Tielrooij, K J; Koppens, F H L

    2016-01-01

    Two-dimensional crystals such as graphene and transition-metal dichalcogenides demonstrate a range of unique and complementary optoelectronic properties. Assembling different two-dimensional materials in vertical heterostructures enables the combination of these properties in one device, thus creating multifunctional optoelectronic systems with superior performance. Here, we demonstrate that graphene/WSe2/graphene heterostructures ally the high photodetection efficiency of transition-metal dichalcogenides with a picosecond photoresponse comparable to that of graphene, thereby optimizing both speed and efficiency in a single photodetector. We follow the extraction of photoexcited carriers in these devices using time-resolved photocurrent measurements and demonstrate a photoresponse time as short as 5.5 ps, which we tune by applying a bias and by varying the transition-metal dichalcogenide layer thickness. Our study provides direct insight into the physical processes governing the detection speed and quantum efficiency of these van der Waals heterostuctures, such as out-of-plane carrier drift and recombination. The observation and understanding of ultrafast and efficient photodetection demonstrate the potential of hybrid transition-metal dichalcogenide-based heterostructures as a platform for future optoelectronic devices. PMID:26436565

  5. Dielectric breakdown induced by picosecond laser pulses

    NASA Technical Reports Server (NTRS)

    Smith, W. L.; Bechtel, J. H.; Bloembergen, N.

    1976-01-01

    The damage thresholds of transparent optical materials were investigated. Single picosecond pulses at 1.06 microns, 0.53 microns and 0.35 microns were obtained from a mode locked Nd-YAG oscillator-amplifier-frequency multiplier system. The pulses were Gaussian in space and time and permitted the determination of breakdown thresholds with a reproducibility of 15%. It was shown that the breakdown thresholds are characteristic of the bulk material, which included nine alkali halides, five different laser host materials, KDP, quartz, sapphire and calcium fluoride. The extension of the damage data to the ultraviolet is significant, because some indication was obtained that two- and three-photon absorption processes begin to play a role in determining the threshold. Throughout the visible region of the spectrum the threshold is still an increasing function of frequency, indicating that avalanche ionization is the dominant factor in determining the breakdown threshold. This was confirmed by a detailed study of the damage morphology with a high resolution microscope just above the threshold. The influence of self focusing is discussed, and evidence for beam distortion below the power threshold for complete self focusing is presented, confirming the theory of Marburger.

  6. Picosecond photoresponse in van der Waals heterostructures

    NASA Astrophysics Data System (ADS)

    Massicotte, M.; Schmidt, P.; Vialla, F.; Schädler, K. G.; Reserbat-Plantey, A.; Watanabe, K.; Taniguchi, T.; Tielrooij, K. J.; Koppens, F. H. L.

    2016-01-01

    Two-dimensional crystals such as graphene and transition-metal dichalcogenides demonstrate a range of unique and complementary optoelectronic properties. Assembling different two-dimensional materials in vertical heterostructures enables the combination of these properties in one device, thus creating multifunctional optoelectronic systems with superior performance. Here, we demonstrate that graphene/WSe2/graphene heterostructures ally the high photodetection efficiency of transition-metal dichalcogenides with a picosecond photoresponse comparable to that of graphene, thereby optimizing both speed and efficiency in a single photodetector. We follow the extraction of photoexcited carriers in these devices using time-resolved photocurrent measurements and demonstrate a photoresponse time as short as 5.5 ps, which we tune by applying a bias and by varying the transition-metal dichalcogenide layer thickness. Our study provides direct insight into the physical processes governing the detection speed and quantum efficiency of these van der Waals heterostuctures, such as out-of-plane carrier drift and recombination. The observation and understanding of ultrafast and efficient photodetection demonstrate the potential of hybrid transition-metal dichalcogenide-based heterostructures as a platform for future optoelectronic devices.

  7. Optical Studies on Antimonide Superlattice Infrared Detector Material

    NASA Technical Reports Server (NTRS)

    Hoglund, Linda; Soibel, Alexander; Hill, Cory J.; Ting, David Z.; Khoshakhlagh, Arezou; Liao, Anna; Keo, Sam; Lee, Michael C.; Nguyen, Jean; Mumolo, Jason M.; Gunapala, Sarath D.

    2010-01-01

    In this study the material quality and optical properties of type II InAs/GaSb superlattices are investigated using transmission and photoluminescence (PL) spectroscopy. The influence of the material quality on the intensity of the luminescence and on the electrical properties of the detectors is studied and a good correlation between the photodetector current-voltage (IV) characteristics and the PL intensity is observed. Studies of the temperature dependence of the PL reveal that Shockley-Read-Hall processes are limiting the minority carrier lifetime in both the mid-IR wavelength and the long-IR wavelength detector material studied. These results demonstrate that PL spectroscopy is a valuable tool for optimization of infrared detectors.

  8. Picosecond lasers with the dynamical operation control

    NASA Astrophysics Data System (ADS)

    Mikheev, N. G.; Morozov, V. B.; Olenin, A. N.; Yakovlev, D. V.

    2016-04-01

    Numerical model for simulation of generation process in advanced pulse-periodic high-peak-power picosecond diode-pumped Nd:YAG and Nd:YLF lasers has been developed. The model adequately describes picosecond pulse formation governed by active and passive mode-locking, negative feedback and adjustable loss level in the oscillator cavity. Optical jitter of output pulses attributed to laser generation development from spontaneous noise level was evaluated using statistical analysis of calculation results. In the presented laser scheme, minimal jitter value on the level ~40 ps was estimated.

  9. Study on laser and infrared attenuation performance of carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Liu, Xiang-cui; Liu, Qing-hai; Dai, Meng-yan; Cheng, Xiang; Fang, Guo-feng; Zhang, Tong; Liu, Haifeng

    2014-11-01

    In recent years, the weapon systems of laser and infrared (IR) imaging guidance have been widely used in modern warfare because of their high precision and strong anti-interference. However, military smoke, a rapid and effective passive jamming method, can effectively counteract the attack of precision-guided weapons by their scattering and absorbing effects. The traditional smoke has good visible light (0.4-0.76μm) obscurant performance, but hardly any effects to other electromagnetic wave bands while the weapon systems of laser and IR imaging guidance usually work in broad band, including the near-infrared (1-3μm), middle-infrared (3-5μm), far-infrared (8-14μm), and so on. Accordingly, exploiting new effective obscurant materials has attracted tremendous interest worldwide nowadays. As is known, the nano-structured materials have lots of unique properties comparing with the traditional materials suggesting that they might be the perfect alternatives to solve the problems above. Carbon nanotubes (CNTs) are well-ordered, all-carbon hollow graphitic nano-structured materials with a high aspect ratio, lengths from several hundred nanometers to several millimeters. CNTs possess many unique intrinsic physical-chemical properties and are investigated in many areas reported by the previous studies. However, no application research about CNTs in smoke technology field is reported yet. In this paper, the attenuation performances of CNTs smoke to laser and IR were assessed in 20m3 smoke chamber. The testing wavebands employed in experiments are 1.06μm and 10.6μm laser, 3-5μm and 8-14μm IR radiation. The main parameters were obtained included the attenuation rate, transmission rate, mass extinction coefficient, etc. The experimental results suggest that CNTs smoke exhibits excellent attenuation ability to the broadband IR radiation. Their mass extinction coefficients are all above 1m2·g-1. Nevertheless, the mass extinction coefficients vary with the sampling time

  10. Tunable Infrared Laser Instruments for Airborne Atmospheric Studies

    NASA Technical Reports Server (NTRS)

    Fried, A.; Diskin, G.; Weibring, P.; Richter, D.; Walega, J. G.; Sachse, G.; Slate, T.; Rana, M.; Podolske, J.

    2008-01-01

    Tunable infrared laser-based instruments on airborne platforms have provided invaluable contributions to atmospheric studies over the past several decades. This paper presents an overview of some recent studies and developments using this approach that were presented at the 2007 Field Laser Applications in Industry and Research (FLAIR, http://www.inoa.it/flair/) conference in Florence, Italy. The present overview only covers select in situ absorption-based instruments that were presented in the airborne session at this conference. In no case are comprehensive details presented. These details can be found in the numerous references given. Additional approaches based upon cavity-enhanced and photoacoustic measurements, which are also making invaluable contributions in airborne atmospheric studies, are not discussed in this brief overview.

  11. Long life feasibility study for the shuttle infrared telescope facility

    NASA Technical Reports Server (NTRS)

    1985-01-01

    A study was conducted to assess the feasibility of designing an Infrared Telescope of the 1 meter class which would operate effectively as a Shuttleborne, 14-day Spacelab payload and then be adapted with little modification to work as a 6 month Space station or free flyer payload. The optics configuration and requirements from a previous study were used without modification. In addition, an enhancement to 2 year mission lengths was studied. The cryogenic system selected was a hybrid design with an internal solid Hydrogen tank at 8 Kelvin and an internal superfluid tank at 2K. In addition to the cryogenic design, a detailed look at secondary mirror actuators for chopping, focus and decenter was conducted and analysis and cryo test reported.

  12. The molecular structure of chloritoid: A mid-infrared and near-infrared spectroscopic study

    NASA Astrophysics Data System (ADS)

    Li, Kuo; Liu, Qinfu; Cheng, Hongfei; Deng, Yutao; Frost, Ray L.

    2015-06-01

    The mineral chloritoid collected from the argillite in the bottom of Yaopo Formation of Western Beijing was characterized by mid-infrared (MIR) and near-infrared (NIR) spectroscopy. The MIR spectra showed all fundamental vibrations including the hydroxyl units, basic aluminosilicate framework and the influence of iron on the chloritoid structure. The NIR spectrum of the chloritoid showed combination (ν + δ)OH bands with the fundamental stretching (ν) and bending (δ) vibrations. Based on the chemical component data and the analysis result from the MIR and NIR spectra, the crystal structure of chloritoid from western hills of Beijing, China, can be illustrated. Therefore, the application of the technique across the entire infrared region is expected to become more routine and extend its usefulness, and the reproducibility of measurement and richness of qualitative information should be simultaneously considered for proper selection of a spectroscopic method for the unit cell structural analysis.

  13. The molecular structure of chloritoid: a mid-infrared and near-infrared spectroscopic study.

    PubMed

    Li, Kuo; Liu, Qinfu; Cheng, Hongfei; Deng, Yutao; Frost, Ray L

    2015-06-15

    The mineral chloritoid collected from the argillite in the bottom of Yaopo Formation of Western Beijing was characterized by mid-infrared (MIR) and near-infrared (NIR) spectroscopy. The MIR spectra showed all fundamental vibrations including the hydroxyl units, basic aluminosilicate framework and the influence of iron on the chloritoid structure. The NIR spectrum of the chloritoid showed combination (ν+δ)OH bands with the fundamental stretching (ν) and bending (δ) vibrations. Based on the chemical component data and the analysis result from the MIR and NIR spectra, the crystal structure of chloritoid from western hills of Beijing, China, can be illustrated. Therefore, the application of the technique across the entire infrared region is expected to become more routine and extend its usefulness, and the reproducibility of measurement and richness of qualitative information should be simultaneously considered for proper selection of a spectroscopic method for the unit cell structural analysis. PMID:25828887

  14. Tunable Far Infrared Studies in Support of Stratospheric Measurements

    NASA Technical Reports Server (NTRS)

    Chance, Kelly V.; Park, K.; Nolt, I. G.; Evenson, K. M.

    2001-01-01

    This report summarizes research done under NASA Grant NAG5-4653. The research performed under this grant has been a collaboration between institutions including the Smithsonian Astrophysical Observatory, the National Institute of Standards and Technology, the University of Oregon, and the NASA Langley Research Center. The program has included fully line-resolved measurements of submillimeter and far infrared spectroscopic line parameters (pressure broadening coefficients and their temperature dependences, and line positions) for the analysis of field measurements of stratospheric constituents, far infrared database improvements, and studies for improved satellite measurements of the Earth's atmosphere. This research program is designed to enable the full utilization of spectra obtained in far infrared/submillimeter field measurements, such as FIRS-2, FILOS, IBEX, SLS, EosMLS, and proposed European Space Agency measurements of OH (e.g., PIRAMHYD and SFINX) for the retrieval of accurate stratospheric altitude profiles of key trace gases involved in ozone layer photochemistry. For the analysis of the spectra obtained in the stratosphere from far infrared measurements it is necessary to have accurate values of the molecular parameters (line positions, strengths, and pressure broadening coefficients) for the measured molecules and for possible interfering species. Knowledge of line positions is in increasingly good shape, with some notable exceptions. The increase in position information includes research that has been performed in the present program of research on HO2, H2O, H2O2, O3, HCl, HF, HBr, HI, CO, OH, and ClO. Examples where further line position studies are necessary include hot band and minor isotopomer lines of some of the major trace species (H2O, O3) and normal lines of some triatomic and larger molecules (NO2). Knowledge of strengths is in generally good shape, since most of the lines are from electric dipole transitions whose intensities are well

  15. Infrared Investigations.

    ERIC Educational Resources Information Center

    Lascours, Jean; Albe, Virginie

    2001-01-01

    Describes a series of simple and nontraditional experiments that enable students to discover the properties of infrared radiation by studying the propagation, reflection, diffusion, and refraction of infrared. The experiments rely on two modules, an infrared transmitter and an infrared receiver. (SAH)

  16. Infrared Studies of Optically Pumped Simple Conjugated Polymers.

    NASA Astrophysics Data System (ADS)

    Schaffer, Howard E.

    This dissertation presents the results of a series of infrared spectroscopic studies of optically pumped simple conjugated polymers. It had previously been shown that photoexcitation of the simplest of these polymers, trans -polyacetylene, produced infrared absorptions characteristic of solitons, which are self-localized defects that arise as solutions to the model Hamiltonian proposed by Su, Schrieffer and Heeger (SSH). Upon this foundation, four lines of research to study conjugated polymers were pursued. One, a highly sensitive repetition of the previous measurements for carefully isomerized samples of both (CH) _{x} and its deuterated analogue, (CD)_{x}, have allowed the observation of very weak absorptions, previously unobserved. The frequencies and intensities of these absorptions agree with those predicted by recent calculations, based on the SSH model, to be due to a third bound mode of the soliton defect. Two, comparison of the photoinduced absorption spectra of a series of samples of Shirakawa, Durham, and Naarman type polyacetylene samples has demonstrated the dependence of both frequencies and relative oscillator strengths of the infrared peaks upon sample preparation. The amplitude mode formalism, combined with the results of other experiments, allows these data to provide a connection between spectroscopy of excited states and sample morphology. Three, more complicated polymers have been studied. The four largest peaks characteristic of photogenerated bipolarons in polythiophene have similar interpretation to the stronger peaks in polyacetylene; smaller features have been interpreted similarly to the weak absorptions described in the previous paragraph. Absorptions at lower energy have been assigned as due to vibrations of the rings of polythiophene which are not related to the Peierls-type electron-phonon coupling described by SSH. Preliminary data on the newer polymer polyisothianaphthene is also presented. And, four, the inconclusive results of a

  17. Study of near infrared technology for intracranial hematoma detection

    NASA Astrophysics Data System (ADS)

    Zhang, Quan; Ma, Hong Y.; Nioka, Shoko; Chance, Britton

    2000-04-01

    Although intracranial hematoma detection only requires the continuous wave technique of near infrared spectroscopy (NIRS), previous studies have shown that there are still some problems in obtaining very accurate, reliable hematoma detection. Several of the most important limitations of NIR technology for hematoma detection such as the dynamic range of detection, hair absorption, optical contact, layered structure of the head, and depth of detection are reported in this article. A pulsed light source of variable intensity was designed and studied in order to overcome hair absorption and to increase the dynamic range and depth of detection. An adaptive elastic optical probe was made to improve the optical contact and decrease contact noise. A new microcontroller operated portable hematoma detector was developed. Due to the layered structure of the human head, simulation on a layered medium was analyzed experimentally. Model inhomogeneity tests and animal hematoma tests showed the effectiveness of the improved hematoma detector for intracranial hematoma detection.

  18. Complexation dynamics of CH3SCN and Li(+) in acetonitrile studied by two-dimensional infrared spectroscopy.

    PubMed

    Kwon, YoungAh; Park, Sungnam

    2015-10-01

    Ion-molecule complexation dynamics were studied with CH3SCN and Li(+) in acetonitrile by vibrationally probing the nitrile stretching vibration of CH3SCN. The nitrile stretching vibration of CH3SCN has a long lifetime (T1 = ∼90 ps) and its frequency is significantly blue-shifted when CH3SCN is bound with Li(+) ions to form a CH3SCNLi(+) complex in acetonitrile. Such spectral properties enable us to distinguish free CH3SCN and the CH3SCNLi(+) complex in solutions and measure their dynamics occurring on hundred picosecond timescales. For the complexation between CH3SCN and Li(+) in acetonitrile, the change in enthalpy (ΔH = -7.17 kJ mol(-1)) and the change in entropy (ΔS = -34.4 J K(-1) mol(-1)) were determined by temperature-dependent FTIR experiments. Polarization-controlled infrared pump-probe (IR PP) spectroscopy was used to measure the population decay and orientational dynamics of free CH3SCN and the CH3SCNLi(+) complex. Especially, the orientational relaxation of the CH3SCNLi(+) complex was found to be almost 3 times slower than those of free CH3SCN because Li(+) ions strongly interact with the neighboring solvents. Most importantly, the complexation dynamics of CH3SCN and Li(+) in acetonitrile were successfully measured in real time by 2DIR spectroscopy for the first time and the dissociation and association time constants were directly determined by using the two-species exchange kinetic model. Our experimental results provide a comprehensive overview of the ion-molecule complexation dynamics in solutions occurring under thermal equilibrium conditions. PMID:26323322

  19. Picosecond Spectroscopy of Reactive Intermediates: Generation and Dynamics of Arylmethyl Ions and Radicals in Solution.

    NASA Astrophysics Data System (ADS)

    Schmidt, Jeffrey Allan

    A detailed experimental description is presented of a practical and relatively inexpensive approach for two simultaneous and independent types of picosecond spectroscopic measurements. Two data collection subsystems, (1) a picosecond pump-probe transient absorption/emission spectrometer and (2) a streak camera system for time-dependent measurements of absorption and emission, were developed as independent subsystems within an integrated system based on a single mode-locked Nd:YAG laser which concurrently supplies each subsystem with picosecond pulses. Considerations concerning electrical and optical interfacing between the two subsystems are discussed. With these two subsystems, picosecond-pulsed photolyses of diphenylmethyl chloride, diphenylmethyl bromide, triphenylmethyl chloride, triphenylmethyl bromide, and triphenylacetyl chloride in acetonitrile, methylene chloride, and cyclohexane were studied. The dependence of the yields of radicals and ions are discussed with respect to the nature of the starting compound and the solvent. Ion-pair dynamics were monitored with subsystems 1 and 2. Microscopic rate constants for the collapse of the contact ion pair (CIP), separation of the CIP, and reformation of the CIP from the separated ions were calculated. The photophysics and photochemistry of the triphenylmethyl radical generated from triphenylmethyl chloride, and triphenylacetyl chloride, and tert-butyl triphenylperacetate in solution were studied by means of a unique three-pulse picosecond transient absorption technique. The emission lifetime of the excited triphenylmethyl radical was measured as a function of solvent polarity with subsystem 2. These data were collectively used to gain an understanding of the electronically excited triphenylmethyl radical.

  20. Development of rike techniques using picosecond lasers

    SciTech Connect

    Schauer, M.W.; Pellin, M.J.; Biwer, B.M.; Gruen, D.M.

    1987-09-25

    The sensitivity of the Raman-induced Kerr effect is greatly enhanced through the use of picosecond lasers. Experiments in dilute solutions of benzene indicate that sensitivity at the monolayer level is achievable. Applications to transparent media, to fluorescing samples, and to in situ measurements of electrode surfaces are discussed.

  1. Ultrasensitive coherent Raman technique with picosecond lasers

    SciTech Connect

    Schauer, M.W.; Pellin, M.J.; Biwer, B.M.; Gruen, D.M.

    1986-01-01

    The sensitivity of the Raman-induced Kerr effect is greatly enhanced through the use of picosecond lasers. Experiments in dilute solutions of benzene indicate that sensitivity at the monolayer level is achievable. Applications to transparent media, to fluorescing samples, and to in situ measurements of electrode surfaces are discussed.

  2. [Study on the inclusion compound of avermectin by infrared spectroscopy].

    PubMed

    Shen, Wen; Zhang, Guang-Hua; Guo, Ning; Li, Yun-Tao

    2014-05-01

    This study was designed to investigate the formation and effect of inclusion complex of Avermectin-beta-cyclodextrin based on the accommodation property of beta-cyclodextrin's molecular cavity. The inclusion complex of Averrnectin-beta-cyclodextrin was prepared using saturated solution method and high performance liquid chromatography (HPLC) was employed to determine its entraping efficiency. The formation of Avermectin-beta-cyclodextrin inclusion complex was also demonstrated by infrared spectroscopy(IR). The change of chemical structure produced by photocatalysis of Abamectin was analyzed and the effect of inclusion complex to strengthen the photolysis stability of Abamectin's chemical structure was studied. The results show that the entraping efficiency of the inclusion complex was 40. 5%. The IR analysis presents that the intermolecular hydrogen bond was formed in the Avermectin-beta-cyclodextrin inclusion complex, indicating the composition effect was different from physical mixture. The lactones structure of Avermectin Bla can be photodecomposed and disrupted. After decomposition, the infrared stretching vibration peak of C-O-C structure disappeared and the lactone bond was significantly broken. The lactones structure of avermectin Bla was covered by the inclusion molecular loci in beta-cyclodextrin after the formation of avermectin-beta-cyclodextrin inclusion complex, providing a good photophobic protection for C-O-C structure in the macrocyclic lactone structure of avermectin Bla and improving the photostability of avermectin Bla molecule. The innovation of this study is that the structure and the characters of the prepared avermectin-beta-cyclodextrin inclusion complex were analyzed using spectrum methods. This inclusion complex is expected to be the ideal intermediate in the construction of protective controlled release formulation of avermectin. PMID:25095407

  3. Raman and infrared spectroscopic study of kamphaugite-(Y)

    NASA Astrophysics Data System (ADS)

    Frost, Ray L.; López, Andrés; Scholz, Ricardo

    2015-05-01

    We have studied the carbonate mineral kamphaugite-(Y)(CaY(CO3)2(OH)·H2O), a mineral which contains yttrium and specific rare earth elements. Chemical analysis shows the presence of Ca, Y and C. Back scattering SEM appears to indicate a single pure phase. The vibrational spectroscopy of kamphaugite-(Y) was obtained using a combination of Raman and infrared spectroscopy. Two distinct Raman bands observed at 1078 and 1088 cm-1 provide evidence for the non-equivalence of the carbonate anion in the kamphaugite-(Y) structure. Such a concept is supported by the number of bands assigned to the carbonate antisymmetric stretching mode. Multiple bands in the ν4 region offers further support for the non-equivalence of carbonate anions in the structure. Vibrational spectroscopy enables aspects of the structure of the mineral kamphaugite-(Y) to be assessed.

  4. Infrared spectrometric study of acid-degradable glasses.

    PubMed

    De Maeyer, E A P; Verbeeck, R M H; Vercruysse, C W J

    2002-08-01

    The composition of glasses used in glass-ionomer cements affects their leaching behavior and hence the properties of the cement. The aim of this study was to correlate the composition and leaching behavior of these glasses with their infrared absorption characteristics. The wavenumber of the absorption band of the Si-O asymmetric stretching vibration shifts to a higher value with decreasing content of mono- and bivalent cations in the glass. This effect can be ascribed to the influence of these extraneous ions on the glass network order and connectivity. Preferential leaching of these ions induces an increase of asymmetric stretching vibration and a general modification of the band profile. The results can be correlated with the x-ray diffraction characteristics of the glass. PMID:12147746

  5. Infrared spectroscopy of molecules with nanorod arrays: a numerical study.

    PubMed

    Tardieu, Clément; Vincent, Grégory; Haïdar, Riad; Collin, Stéphane

    2016-04-15

    Nanorod arrays with diameters much smaller than the wavelength exhibit sharp resonances with strong electric-field enhancement and angular dependence. They are investigated for enhanced infrared spectroscopy of molecular bonds. The molecule 3-cyanopropyldimethylchlorosilane (CS) is taken as a reference, and its complex permittivity is determined experimentally in the 3-5 μm wavelength range. When grafted on silicon nitride nanorods, we show numerically that its weak absorption bands due to chemical bond vibrations can be enhanced by several orders of magnitude compared with unstructured thin film. We propose a figure of merit (FoM) to assess the performance of this spectroscopic scheme, and we study the impact of the nanorod cross section on the FoM. PMID:27082334

  6. Study of surfaces using near infrared optical fiber spectrometry

    NASA Technical Reports Server (NTRS)

    Workman, G. L.; Arendale, W. A.; Hughes, C.

    1995-01-01

    The measurement and control of cleanliness for critical surfaces during manufacturing and in service provides a unique challenge for fulfillment of environmentally benign operations. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This presentation will provide an introduction to the use of optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. Correlation of the Near Infrared (NIR) spectroscopic results with Optical Stimulated Electron Emission (OSEE) and ellipsometry will also be presented.

  7. Ultrafast infrared studies of complex ligand rearrangements in solution

    SciTech Connect

    Payne, Christine K.

    2003-05-31

    The complete description of a chemical reaction in solution depends upon an understanding of the reactive molecule as well as its interactions with the surrounding solvent molecules. Using ultrafast infrared spectroscopy it is possible to observe both the solute-solvent interactions and the rearrangement steps which determine the overall course of a chemical reaction. The topics addressed in these studies focus on reaction mechanisms which require the rearrangement of complex ligands and the spectroscopic techniques necessary for the determination of these mechanisms. Ligand rearrangement is studied by considering two different reaction mechanisms for which the rearrangement of a complex ligand constitutes the most important step of the reaction. The first system concerns the rearrangement of a cyclopentadienyl ring as the response of an organometallic complex to a loss of electron density. This mechanism, commonly referred to as ''ring slip'', is frequently cited to explain reaction mechanisms. However, the ring slipped intermediate is too short-lived to be observed using conventional methods. Using a combination of ultrafast infrared spectroscopy and electronic structure calculations it has been shown that the intermediate exists, but does not form an eighteen-electron intermediate as suggested by traditional molecular orbital models. The second example examines the initial steps of alkyne polymerization. Group 6 (Cr, Mo, W) pentacarbonyl species are generated photolytically and used to catalyze the polymerization of unsaturated hydrocarbons through a series of coordination and rearrangement steps. Observing this reaction on the femto- to millisecond timescale indicates that the initial coordination of an alkyne solvent molecule to the metal center results in a stable intermediate that does not rearrange to form the polymer precursor. This suggests that polymerization requires the dissociation of additional carbonyl ligands before rearrangement can occur. Overall

  8. Space-Based Thermal Infrared Studies of Asteroids

    NASA Astrophysics Data System (ADS)

    Mainzer, A.; Usui, F.; Trilling, D. E.

    Large-area surveys operating at mid-infrared wavelengths have proven to be a valuable means of discovering and characterizing minor planets. Through the use of radiometric models, it is possible to derive physical properties such as diameters, albedos, and thermal inertia for large numbers of objects. Modern detector array technology has resulted in a significant improvement in spatial resolution and sensitivity compared with previous generations of spacebased infrared telescopes, giving rise to a commensurate increase in the number of objects that have been observed at these wavelengths. Spacebased infrared surveys of asteroids therefore offer an effective method of rapidly gathering information about the orbital and physical properties of small-body populations. The AKARI, Wide-field Infrared Survey Explorer (WISE)/ Near- Earth Object Wide-field Infrared Survey Explorer (NEOWISE), Spitzer Space Telescope, and Herschel Space Observatory missions have significantly increased the number of minor planets with well-determined diameters and albedos.

  9. Crosstalk study of near infrared InGaAs detectors

    NASA Astrophysics Data System (ADS)

    Li, Xue; Tang, Hengjing; Li, Tao; Fan, Cui; Shao, Xiumei; Li, Jianwei; Wei, Jun; Gong, Haimei

    2016-05-01

    Crosstalk characteristics of high density FPA detectors attract widespread attention in the application of electro-optical systems. Crosstalk characteristics of near-infrared (NIR) InGaAs photodiodes and focal plane arrays (FPAs) were studied in this paper. The mesa type detector was investigated by using laser beam induced current technique (LBIC) to measure the absorption outside the designed photosensitive area, and the results show that the excess absorption enlarges the crosstalk of the adjacent pixels. The structure optimization using the effective absorption layer between the pixels can effectively reduce the crosstalk to 2.5%. The major crosstalk components of the optimization photodiode come from the electronic signal caused by carrier lateral diffusion. For the planar type detectors, test structures were used to compare the crosstalk of different structures, and the guard ring structure shows good suppression of the crosstalk. Then the back-illuminated 32x32 InGaAs photodiodes with 30μm pitch were designed, and LBIC was used to measure its lateral diffusion of the effective carriers and fill factor of photosensitive area. The results indicate that the fill factor of detectors can reach up to 98% when the diffusion region is optimized, and the minimum response exists between two neighborhood pixels. Based on these crosstalk measurement results and optimizing structure designs, the linear InGaAs photodiodes were designed and thus the InGaAs FPA assembly was fabricated. The assembly shows higher electro-optical performance and good improvement on crosstalk. The assembly was applied in infrared imaging system and modulation transfer function (MTF) of FPA assembly was calculated to be above 0.50. The clear image based on FPA assembly was obtained.

  10. Humidity-dependent dynamic infrared linear dichroism study of a poly(ester urethane)

    NASA Astrophysics Data System (ADS)

    Schoonover, Jon R.; Steckle, Warren P., Jr.; Cox, Jonathan D.; Johnston, Cliff T.; Wang, Yanqia; Gillikin, Angela M.; Palmer, Richard A.

    2007-05-01

    Fourier transform infrared techniques, infrared difference spectroscopy and dynamic infrared linear dichroism (DIRLD), have been utilized to explore the effects of humidity and water absorption on a poly(ester urethane). An environmental infrared microbalance cell was used to measure the infrared spectra as a function of humidity and accompanying weight change for the absorption-desorption processes. The infrared difference data indicate that exposure to humidity affects the hydrogen-bonding interactions in the polymer. Dynamic infrared linear dichroism studies in tensile deformation mode as a function of humidity demonstrate how changes in water content affect the orientational response of functional groups. Complex behavior as a function of humidity for functional groups involved in hydrogen bonding indicates that water absorbed by the polymer affects the micro-environments near these functional groups.

  11. Humidity-dependent dynamic infrared linear dichroism study of a poly(ester urethane).

    PubMed

    Schoonover, Jon R; Steckle, Warren P; Cox, Jonathan D; Johnston, Cliff T; Wang, Yanqia; Gillikin, Angela M; Palmer, Richard A

    2007-05-01

    Fourier transform infrared techniques, infrared difference spectroscopy and dynamic infrared linear dichroism (DIRLD), have been utilized to explore the effects of humidity and water absorption on a poly(ester urethane). An environmental infrared microbalance cell was used to measure the infrared spectra as a function of humidity and accompanying weight change for the absorption-desorption processes. The infrared difference data indicate that exposure to humidity affects the hydrogen-bonding interactions in the polymer. Dynamic infrared linear dichroism studies in tensile deformation mode as a function of humidity demonstrate how changes in water content affect the orientational response of functional groups. Complex behavior as a function of humidity for functional groups involved in hydrogen bonding indicates that water absorbed by the polymer affects the micro-environments near these functional groups. PMID:16950649

  12. An investigation on the hole quality during picosecond laser helical drilling of stainless steel 304

    NASA Astrophysics Data System (ADS)

    Zhang, Hongyu; Di, Jianke; Zhou, Ming; Yan, Yu; Wang, Rong

    2015-05-01

    Precision drilling with ultra-short pulse lasers (e.g., picosecond and femtosecond) has been advocated to significantly improve the quality of the micro-holes with reduced recast layer thickness and no heat-affected zone. However, a combination of high-power picosecond laser with helical drilling strategy in laser drilling has rarely been reported in previous studies. In the present study, a series of micro-holes with circular, triangular, rectangular, and rhombic shapes (diameter 0.6 mm) were manufactured on stainless steel 304 using a newly developed laser drilling system which incorporated a picosecond laser and a high-speed laser beam rotation apparatus into a five-axis positioning platform. The quality of the helical drilled holes, e.g., recast layer, micro-crack, circularity, and conicity, were evaluated using an optical microscope, an optical interferometer, and a scanning electron microscope. In addition, the microstructure of the samples was investigated following etching treatment. It was demonstrated that the entrance ends, the exit ends, and the side walls of the micro-holes were quite smooth without accumulation of spattering material and formation of recast layer and micro-crack. No tapering phenomenon was observed, and the circularity of the holes was fairly good. There was no distinctive difference with regard to the microstructure between the edges of the holes and the bulk material. Picosecond laser helical drilling can be an effective technique for manufacturing of micro-holes with very high quality. The development of high-power picosecond laser would promote picosecond laser drilling to be more industrial relevance in the future.

  13. Laser ablation of CFRP using picosecond laser pulses at different wavelengths from UV to IR

    NASA Astrophysics Data System (ADS)

    Wolynski, Alexander; Herrmann, Thomas; Mucha, Patrick; Haloui, Hatim; L'huillier, Johannes

    Laser processing of carbon fibre reinforced plastics (CFRP) has a great industrial relevance for high performance structural parts in airplanes, machine tools and cars. Through-holes drilled by nanosecond laser pulses show thermal induced molten layers and voids. Recently, picosecond lasers have demonstrated the ability to drill high-efficient and high-quality rivet through-holes. In this paper a high-power picosecond laser system operating at different wavelengths (355 nm, 532 nm and 1064 nm) has been used for CFRP ablation experiments to study the influence of different laser parameters in terms of machining quality and processing time.

  14. GIRL: German Infrared Laboratory. Telescope study, phase B

    NASA Technical Reports Server (NTRS)

    Schlegelmilch, R.; Zeiss, C.

    1981-01-01

    The construction and mounting of mirrors for an infrared telescope are described. Tests conducted to determine the thermal and stress characteristics of various types of mounting for main and collection mirrors are also discussed.

  15. Towards microfluidic reactors for in situ synchrotron infrared studies

    NASA Astrophysics Data System (ADS)

    Silverwood, I. P.; Al-Rifai, N.; Cao, E.; Nelson, D. J.; Chutia, A.; Wells, P. P.; Nolan, S. P.; Frogley, M. D.; Cinque, G.; Gavriilidis, A.; Catlow, C. R. A.

    2016-02-01

    Anodically bonded etched silicon microfluidic devices that allow infrared spectroscopic measurement of solutions are reported. These extend spatially well-resolved in situ infrared measurement to higher temperatures and pressures than previously reported, making them useful for effectively time-resolved measurement of realistic catalytic processes. A data processing technique necessary for the mitigation of interference fringes caused by multiple reflections of the probe beam is also described.

  16. Radiometric Study of Soil Profiles in the Infrared Band

    NASA Astrophysics Data System (ADS)

    Ponomareva, T. V.; Ponomarev, E. I.

    2016-02-01

    The applicability of radiometric survey of soil profiles in the infrared range for the analysis of soil physical properties was studied. Radiometric data were obtained for different dates of the growing season for a number of soil profiles. The specificity of temperature profiles of texture-differentiated soils (Luvisols and Retisols) as related to weather conditions of the growing season was examined. The correlation analysis showed a close relationship between the air and surface soil temperatures and between the radiometric and thermodynamic soil temperatures in the upper 10 cm. In the studied profiles, the gradient of radiometric temperatures reached 0.5-0.8°C/cm in the humus horizons and sharply decreased at the depth of more than 15-20 cm. The gradient analysis of radiometric images made it possible to outline the boundaries of soil horizons. For the texture-differentiated soils, the most distinct boundaries were established between the gray-humus AY horizon and the underlying eluvial EL horizon in podzolic soils and between the AY horizon and the underlying humus-eluvial AEL horizon in gray soils.

  17. Double regenerative amplification of picosecond pulses

    NASA Astrophysics Data System (ADS)

    Bai, Zhen-ao; Chen, Li-yuan; Bai, Zhen-xu; Chen, Meng; Li, Gang

    2012-04-01

    An double Nd:YAG regenerative amplification picosecond pulse laser is demonstrated under the semiconductor saturable absorption mirror(SESAM) mode-locking technology and regenerative amplification technology, using BBO crystal as PC electro-optic crystal. The laser obtained is 20.71ps pulse width at 10 KHz repetition rate, and the energy power is up to 4W which is much larger than the system without pre-amplification. This result will lay a foundation for the following amplification.

  18. High Power Picosecond Laser Pulse Recirculation

    SciTech Connect

    Shverdin, M Y; Jovanovic, I; Semenov, V A; Betts, S M; Brown, C; Gibson, D J; Shuttlesworth, R M; Hartemann, F V; Siders, C W; Barty, C P

    2010-04-12

    We demonstrate a nonlinear crystal-based short pulse recirculation cavity for trapping the second harmonic of an incident high power laser pulse. This scheme aims to increase the efficiency and flux of Compton-scattering based light sources. We demonstrate up to 36x average power enhancement of frequency doubled sub-millijoule picosecond pulses, and 17x average power enhancement of 177 mJ, 10 ps, 10 Hz pulses.

  19. A picosecond high pressure gas switch

    SciTech Connect

    Cravey, W.R.; Poulsen, P.P.; Pincosy, P.A.

    1992-06-01

    Work is being done to develop a high pressure gas switch (HPGS) with picosecond risetimes for UWB applications. Pulse risetimes on the order of 200 picoseconds have been observed at 1 kHz prf and 1 atmosphere. Calculations show that switching closure times on the order of tens of picoseconds can be achieved at high pressures and higher electric fields. A voltage hold-off of 1 MV/cm has been measured at 10 atmospheres and several MV/cm appears possible with the HPGS. With these high electric field levels, energy storage of tens of Joules in a reasonably sized package is achievable. Initial HPGS performance has been characterized on the WASP pulse generator at LLNL. A detailed description of the switch used for initial testing is given. Switch recovery times of 1-ms have been measured at 1 atmosphere. Data on the switching uniformity, voltage hold-off recovery, and pulse repeatability, is presented. In addition, a physics switch model is described and results are compared with lab data.

  20. Infrared thermometry study of nanofluid pool boiling phenomena

    PubMed Central

    2011-01-01

    Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (<0.1 vol.%). In addition to macroscopic parameters like the average heat transfer coefficient and critical heat flux [CHF] value, more fundamental parameters such as the bubble departure diameter and frequency, growth and wait times, and nucleation site density [NSD] were directly measured for a thin, resistively heated, indium-tin-oxide surface deposited onto a sapphire substrate. Consistent with other nanofluid studies, the nanoparticles caused deterioration in the nucleate boiling heat transfer (by as much as 50%) and an increase in the CHF (by as much as 100%). The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement. PMID:21711754

  1. Infrared thermometry study of nanofluid pool boiling phenomena.

    PubMed

    Gerardi, Craig; Buongiorno, Jacopo; Hu, Lin-Wen; McKrell, Thomas

    2011-01-01

    Infrared thermometry was used to obtain first-of-a-kind, time- and space-resolved data for pool boiling phenomena in water-based nanofluids with diamond and silica nanoparticles at low concentration (<0.1 vol.%). In addition to macroscopic parameters like the average heat transfer coefficient and critical heat flux [CHF] value, more fundamental parameters such as the bubble departure diameter and frequency, growth and wait times, and nucleation site density [NSD] were directly measured for a thin, resistively heated, indium-tin-oxide surface deposited onto a sapphire substrate. Consistent with other nanofluid studies, the nanoparticles caused deterioration in the nucleate boiling heat transfer (by as much as 50%) and an increase in the CHF (by as much as 100%). The bubble departure frequency and NSD were found to be lower in nanofluids compared with water for the same wall superheat. Furthermore, it was found that a porous layer of nanoparticles built up on the heater surface during nucleate boiling, which improved surface wettability compared with the water-boiled surfaces. Using the prevalent nucleate boiling models, it was possible to correlate this improved surface wettability to the experimentally observed reductions in the bubble departure frequency, NSD, and ultimately to the deterioration in the nucleate boiling heat transfer and the CHF enhancement. PMID:21711754

  2. Infrared thermography based studies on mobile phone induced heating

    NASA Astrophysics Data System (ADS)

    Lahiri, B. B.; Bagavathiappan, S.; Soumya, C.; Jayakumar, T.; Philip, John

    2015-07-01

    Here, we report the skin temperature rise due to the absorption of radio frequency (RF) energy from three handheld mobile phones using infrared thermography technique. Experiments are performed under two different conditions, viz. when the mobile phones are placed in soft touch with the skin surface and away from the skin surface. Additionally, the temperature rise of mobile phones during charging, operation and simultaneous charging and talking are monitored under different exposure conditions. It is observed that the temperature of the cheek and ear regions monotonically increased with time during the usage of mobile phones and the magnitude of the temperature rise is higher for the mobile phone with higher specific absorption rate. The increase in skin temperature is higher when the mobile phones are in contact with the skin surface due to the combined effect of absorption of RF electromagnetic power and conductive heat transfer. The increase in the skin temperature in non-contact mode is found to be within the safety limit of 1 °C. The measured temperature rise is in good agreement with theoretical predictions. The empirical equation obtained from the temperature rise on the cheek region of the subjects correlates well with the specific absorption rate of the mobile phones. Our study suggests that the use of mobile phones in non-contact mode can significantly lower the skin temperature rise during its use and hence, is safer compared to the contact mode.

  3. Design study of a laser-cooled infrared sensor

    NASA Astrophysics Data System (ADS)

    Hehlen, Markus P.; Boncher, William L.; Love, Steven P.

    2015-03-01

    The performance of a solid-state optical refrigerator is the result of a complex interplay of numerous optical and thermal parameters. We present a first preliminary study of an optical cryocooler using ray-tracing techniques. A numerical optimization identified a non-resonant cavity with astigmatism. This geometry offered more efficient pump absorption by the YLF:10%Yb laser-cooling crystal compared to non-resonant cavities without astigmatism that have been pursued experimentally so far. Ray tracing simulations indicate that ~80% of the incident pump light can absorbed for temperatures down to ~100 K. Calculations of heat loads, cooling power, and net payload heat lift are presented. They show that it is possible to cool a payload to a range of 90-100 K while producing a net payload heat lift of 80 mW and 300 mW when pumping a YLF:10%Yb crystal with 20 W and 50 W at 1020 nm, respectively. This performance is suited to cool HgCdTe infrared detectors that are used for sensing in the 8-12 μm atmospheric window. While the detector noise would be ~6× greater at 100 K than at 77 K, the laser refrigerator would introduce no vibrations and thus eliminate sources of microphonic noise that are limiting the performance of current systems.

  4. Population Studies of Quasars in Infrared and X-Ray Light

    NASA Astrophysics Data System (ADS)

    George, Joseph; Singal, Jack

    2016-01-01

    We present newly assembled multiwavelength datasets for studying the luminosity evolution, density evolution, and luminosity functions of quasars in infrared and X-ray light, as well as preliminary results for these parameters in infrared. We use infrared and X-ray data from NASA's Wide-Field Infrared Survey Explorer Chandra X-ray satellites respectively, in combination with optically identified quasars from the Sloan Digital Sky Survey. We present results for the infrared population parameters, including luminosity evolution which suggests that quasars have evolved more slowly in infrared than in other bands. We also demonstrate new techniques for recovering the intrinsic luminosity-luminosity correlations in datasets with different wavebands in the presence of artificial correlations introduced by survey limits and similar redshift evolutions.

  5. An Infrared Laboratory for the Study of Planetary Materials (IRIS): First Results of Impact Rock Studies

    NASA Astrophysics Data System (ADS)

    Morlok, A.; Ahmedi, M.; Hiesinger, H.

    2013-09-01

    We present the results of a study about the mid-infrared reflect ance properties of impact rocks from the zördlinger Ries impact crater. Spectra from separated components of suevite, melt glass, devitrified glass and matrix show a high degree of similarity, reflecting the high abundance of amorphous materials.

  6. Prospects for Chemical Evolution Studies in the Infrared

    NASA Astrophysics Data System (ADS)

    Thatte, Niranjan; Genzel, Reinhard

    Near infrared instrumentation at 4 and 8 meter class telescopes has grown rapidly in the past few years with the advent of 10242 and 20482 detector arrays. We present a brief review of high resolution spectroscopic capabilities available world-wide, with an eye on new developments, e.g. spatially resolved spectroscopy offered by integral field instruments. Observing at near-infrared wavelengths has its own quirks. We discuss observing strategies to get past the limits of high background (including both thermal background and background due to OH sky emission lines), variations in atmospheric transmission, and detector constraints. Special attention is given to the subject of OH suppression/avoidance, which can significantly increase the sensitivity in the J, H and short K windows. This is especially important for (fainter) high redshift targets, where the rest frame visible diagnostic lines are shifted into the near infrared.

  7. Airfoil transition and separation studies using an infrared imaging system

    NASA Technical Reports Server (NTRS)

    Gartenberg, Ehud; Roberts, A. S., Jr.

    1991-01-01

    An infrared imaging system was used to detect the thermal signature of boundary-layer flow regimes on a NACA 0012 airfoil from zero angle of attack up to separation. The boundary-layer transition from laminar to turbulent flow and the onset of separation could be seen on the airfoil thermograms. The findings were compared against the behavior of aluminum foil tufts observable both visually and with the infrared imaging system. This arrangement offers the option of using the infrared imaging system both for flow regime detection through surface thermography and flow visualization by the aluminum foil tufts. Ultimately the surface temperature changes due to variation in the angle of attack of a lifting surface provide a means for interpretation of the boundary-layer flow regimes.

  8. IN SITU INFRARED STUDY OF CATALYTIC DECOMPOSITION OF NO

    SciTech Connect

    KHALID ALMUSAITEER; RAM KRISHNAMURTHY; STEVEN S.C. CHUANG

    1998-08-18

    The growing concerns for the environment and increasingly stringent standards for NO emission have presented a major challenge to control NO emissions from electric utility plants and automobiles. Catalytic decomposition of NO is the most attractive approach for the control of NO emission for its simplicity. Successful development of an effective catalyst for NO decomposition will greatly decrease the equipment and operation cost of NO control. Due to lack of understanding of the mechanism of NO decomposition, efforts on the search of an effective catalyst have been unsuccessful. Scientific development of an effective catalyst requires fundamental understanding of the nature of active site, the rate-limiting step, and an approach to prolong the life of the catalyst. Research is proposed to study the reactivity of adsorbates for the direct NO decomposition and to investigate the feasibility of two novel approaches for improving catalyst activity and resistance to sintering. The first approach is the use of silanation to stabilize metal crystallites and supports for Cu-ZSM-5 and promoted Pt catalysts; the second is utilization of oxygen spillover and desorption to enhance NO decomposition activity. An innovative infrared reactor system will be used to observe and determine the dynamic behavior and the reactivity of adsorbates during NO decomposition, oxygen spillover, and silanation. A series of experiments including X-ray diffraction, temperature programmed desorption, temperature programmed reaction, X-ray photoelectron spectroscopy will be used to characterized the catalysts. The information obtained from this study will provide a scientific basis for developing an effective catalyst for the NO decomposition under practical flue gas conditions.

  9. In Situ Infrared Study of Catalytic Decomposition of NO

    SciTech Connect

    Cher-Dip Tan; Steven S.C. Chuang

    1997-07-17

    The growing concerns for the environment and increasingly stringent standards for NO emission have presented a major challenge to control NO emmissions from electric utility plants and automobiles. Catalytic decomposition of NO is the most attractive approach for the control of NO emission for its simplicity. Successful development of an effective catalyst for NO decomposition will greatly decrease the equipment and operation cost of NO control. Due to lack of understanding of the mechanism of NO decomposition, efforts on the search of an effective catalyst have been unsuccesful. Scientific development of an effective catalyst requires fundamental understanding of the nature of active site, the rate-limiting step, and an approach to prolong the life of the catalyst. Research is proposed to study the reactivity of adsorbates for the direct NO decomposition and to investigate the feasibility of two novel approaches for improving catalyst activity and resistance to sintering. The first approach is the use of silanation to stabilize metal crystallites and supports for Cu-ZSM-5 and promoted Pt catalysts; the second is utilization of oxygen spillover and desorption to enhance NO decomposition activity. An innovative infrared reactor system will be used to observe and determine the dynamic behavior and the reactivity of adsorbates during NO decomposition, oxygen spillover, and silanation. A series of experiments including X-ray diffraction, temperature programmed desorption, temperature programmed reaction, X-ray photoelectron spectroscopy will be used to characterized the catalysts. The information obtained from this study will provide a scientific basis for developing an effective catalyst for the NO decomposition under practical flue gas conditions.

  10. Acidic properties of sulfated zirconia: An infrared spectroscopic study

    SciTech Connect

    Babou, F.; Coudurier, G.; Vedrine, J.C.

    1995-04-01

    Sulfated zirconia with S content of 2 wt.% equivalent to complete coverage of its surface was studied by infrared spectroscopy. At least four sulfated species were identified and exhibited an important and reversible sensitivity to water. These equilibria were demonstrated to exist by the study of adsorption of incremental amounts of water. D{sub 2}O and H{sub 2}{sup 18}O isotopically enriched water molecules were used to assist interpretation of IR spectra. To characterize acidity features, the probe molecules butane, CO, and H{sub 2}O (as weak bases) or pyridine (as a strong base) were adsorbed. Two Lewis acid sites (L{sub 1} and L{sub 2}) were observed and one Bronsted site (B) related to the zirconia support (L{sub 1}) and the sulfated species (L{sub 2}, B). They were evidenced by pyridine adsorption which was shown to partly displace adsorbed sulfate species. With the help of previous theoretical calculations using an ab initio method and representing the zirconia surface by a mononuclear zirconium complex, it is emphasized that the sulfated zirconia can be visualized as a H{sub 2}SO{sub 4} compound grafted onto the surface of zirconia in a way which makes it very sensitive to water but in a reversible way. Its acidity is similar to that of sulfuric acid but it is not really superacidic. Comparison with other oxides leads us to suggest that the cationic charge borne by the metallic cation is of prime importance for the acidity strength. The role of water on the acidic and catalytic properties for n-butane isomerization reaction is emphasized. 33 refs., 11 figs., 2 tabs.

  11. An infrared and luminescence study of tritiated amorphous silicon

    SciTech Connect

    Sidhu, L.S.; Kosteski, T.; Kherani, N.P.; Gaspari, F.; Zukotynski, S.; Shmayda, W.

    1997-07-01

    Tritium has been incorporated into amorphous silicon. Infrared spectroscopy shows new infrared vibration modes due to silicon-tritium (Si-T) bonds in the amorphous silicon network. Si-T vibration frequencies are related to Si-H vibration frequencies by simple mass relationships. Inelastic collisions of {beta} particles, produced as a result of tritium decay, with the amorphous silicon network results in the generation of electron-hole pairs. Radiative recombination of these carriers is observed. Dangling bonds associated with the tritium decay reduce luminescence efficiency.

  12. Cirrus microphysics and infrared radiative transfer: A case study

    NASA Technical Reports Server (NTRS)

    Ackerman, Thomas P.; Heymsfield, Andrew J.; Valero, Francisco P. J.; Kinne, Stefan

    1988-01-01

    Coincident measurements of cirrus cloud microphysical properties such as particle size distribution and particle shape and morphology, and measurements of infrared intensity and flux were made. Data was acquired nearly simultaneously in space and time by a KingAir in cloud and by an ER-2 at an altitude of 19 km. Upwelling infrared intensities and fluxes measured from the ER-2 and observations of cloud particle size distributions and particle phase and morphology made from the KingAir are discussed. Broad-band flux measurements were available both in and below the cirrus layer from the KingAir.

  13. Probing carrier dynamics in nanostructures by picosecond cathodoluminescence.

    PubMed

    Merano, M; Sonderegger, S; Crottini, A; Collin, S; Renucci, P; Pelucchi, E; Malko, A; Baier, M H; Kapon, E; Deveaud, B; Ganière, J-D

    2005-11-24

    Picosecond and femtosecond spectroscopy allow the detailed study of carrier dynamics in nanostructured materials. In such experiments, a laser pulse normally excites several nanostructures at once. However, spectroscopic information may also be acquired using pulses from an electron beam in a modern electron microscope, exploiting a phenomenon called cathodoluminescence. This approach offers several advantages. The multimode imaging capabilities of the electron microscope enable the correlation of optical properties (via cathodoluminescence) with surface morphology (secondary electron mode) at the nanometre scale. The broad energy range of the electrons can excite wide-bandgap materials, such as diamond- or gallium-nitride-based structures that are not easily excited by conventional optical means. But perhaps most intriguingly, the small beam can probe a single selected nanostructure. Here we apply an original time-resolved cathodoluminescence set-up to describe carrier dynamics within single gallium-arsenide-based pyramidal nanostructures with a time resolution of 10 picoseconds and a spatial resolution of 50 nanometres. The behaviour of such charge carriers could be useful for evaluating elementary components in quantum computers, optical quantum gates or single photon sources for quantum cryptography. PMID:16306988

  14. Picosecond and femtosecond laser ablation of hard tissues

    NASA Astrophysics Data System (ADS)

    Serafetinides, Alexander A.; Makropoulou, Mersini I.; Kar, Ajoy K.; Khabbaz, Marouan

    1996-12-01

    In this study, the interaction of picosecond and femtosecond pulsed laser radiation with human dental tissue was investigated experimentally, as this unexplored field is expected to be a potential alternative in powerful laser processing of biomedical structures. Dentin ablation rate experiments were performed by using teeth sections of different thickness. Dental tissue samples were irradiated in air with i) a regenerative amplifier laser at 1064 nm, pulse duration 110 ps, ii) the second harmonic laser at 532 nm, pulse duration 100 ps, and iii) a picosecond tunable dye amplifier at 595 nm, pulse width 800 fs. In all the experiments the pulse repetition rate was 10 Hz. The ablation rate per pulse at different energy fluence settings was calculated by measuring the time needed for the perforation of the whole dental sample thickness. Short laser pulses can confine thermal energy within the optical zone, which maximizes photothermal and photomechanical mechanisms of interaction. Tissue ablation rates were found to be comparable to or better than other nanosecond lasers, and left smooth surfaces, free of thermal damage.

  15. Picosecond optical vortex pulse illumination forms a monocrystalline silicon needle

    PubMed Central

    Takahashi, Fuyuto; Miyamoto, Katsuhiko; Hidai, Hirofumi; Yamane, Keisaku; Morita, Ryuji; Omatsu, Takashige

    2016-01-01

    The formation of a monocrystalline silicon needle by picosecond optical vortex pulse illumination was demonstrated for the first time in this study. The dynamics of this silicon needle formation was further revealed by employing an ultrahigh-speed camera. The melted silicon was collected through picosecond pulse deposition to the dark core of the optical vortex, forming the silicon needle on a submicrosecond time scale. The needle was composed of monocrystalline silicon with the same lattice index (100) as that of the silicon substrate, and had a height of approximately 14 μm and a thickness of approximately 3 μm. Overlaid vortex pulses allowed the needle to be shaped with a height of approximately 40 μm without any changes to the crystalline properties. Such a monocrystalline silicon needle can be applied to devices in many fields, such as core–shell structures for silicon photonics and photovoltaic devices as well as nano- or microelectromechanical systems. PMID:26907639

  16. Picosecond optical vortex pulse illumination forms a monocrystalline silicon needle.

    PubMed

    Takahashi, Fuyuto; Miyamoto, Katsuhiko; Hidai, Hirofumi; Yamane, Keisaku; Morita, Ryuji; Omatsu, Takashige

    2016-01-01

    The formation of a monocrystalline silicon needle by picosecond optical vortex pulse illumination was demonstrated for the first time in this study. The dynamics of this silicon needle formation was further revealed by employing an ultrahigh-speed camera. The melted silicon was collected through picosecond pulse deposition to the dark core of the optical vortex, forming the silicon needle on a submicrosecond time scale. The needle was composed of monocrystalline silicon with the same lattice index (100) as that of the silicon substrate, and had a height of approximately 14 μm and a thickness of approximately 3 μm. Overlaid vortex pulses allowed the needle to be shaped with a height of approximately 40 μm without any changes to the crystalline properties. Such a monocrystalline silicon needle can be applied to devices in many fields, such as core-shell structures for silicon photonics and photovoltaic devices as well as nano- or microelectromechanical systems. PMID:26907639

  17. Study on Senna alata and its different extracts by Fourier transform infrared spectroscopy and two-dimensional correlation infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Adiana, M. A.; Mazura, M. P.

    2011-04-01

    Senna alata L. commonly known as candle bush belongs to the family of Fabaceae and the plant has been reported to possess anti-inflammatory, analgesic, laxative and antiplatelet-aggregating activity. In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional infrared correlation spectroscopy (2D-IR) to study the main constituents of S. alata and its different extracts (extracted by hexane, dichloromethane, ethyl acetate and methanol in turn). The findings indicated that FT-IR and 2D-IR can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can identify the main chemical constituents in medicinal materials and their extracts, but also compare the components differences among similar samples. In a conclusion, FT-IR spectroscopy combined with 2D correlation analysis provides a powerful method for the quality control of traditional medicines.

  18. Amplitude and polarization instability of picosecond light pulses exciting a semiconductor optical resonator.

    PubMed

    Markarov, V A; Pershin, S M; Podshivalov, A A; Zadoian, R S; Zheludev, N I

    1983-11-01

    The first results of our study of nonlinear shift, distortion of form, and destruction of picosecond light pulses interacting with a nonlinear Fabry-Perot resonator in a strongly nonstationary regime are reported. Polarization instability of the light pulse transmitted through a nonlinear resonator has been observed. PMID:19718182

  19. Infrared laser sealing of porcine tissues: preliminary in vivo studies

    NASA Astrophysics Data System (ADS)

    Cilip, Christopher M.; Hutchens, Thomas C.; Kerr, Duane; Latimer, Cassandra; Rosenbury, Sarah B.; Giglio, Nicholas C.; Schweinsberger, Gino R.; Perkins, William C.; Wilson, Christopher R.; Ward, Arlen; Nau, William H.; Fried, Nathaniel M.

    2015-02-01

    We are exploring infrared (IR) lasers as an alternative energy modality to radiofrequency (RF) and ultrasonic (US) devices intended to provide rapid surgical hemostasis with minimal collateral zones of thermal damage and tissue necrosis. Previously, a 1470-nm IR laser sealed and cut ex vivo porcine renal arteries of 1-8 mm in 2 s, yielding burst pressures < 1200 mmHg (compared to normal systolic blood pressure of 120 mmHg) and thermal coagulation zones < 3 mm (including the seal). This preliminary study describes in vivo testing of a laser probe in a porcine model. A prototype, fiber optic based handheld probe with vessel/tissue clasping mechanism was tested on blood vessels < 6 mm diameter using incident 1470-nm laser power of 35 W for 1-5 s. The probe was evaluated for hemostasis after sealing isolated and bundled vasculature of abdomen and hind leg, as well as liver and lung parenchyma. Sealed vessel samples were collected for histological analysis of lateral thermal damage. Hemostasis was achieved in 57 of 73 seals (78%). The probe consistently sealed vasculature in small bowel mesentery, mesometrium, and gastro splenic and epiploic regions. Seal performance was less consistent on hind leg vasculature including saphenous arteries and bundles and femoral and iliac arteries. Collagen denaturation averaged 1.6 mm in 8 samples excised for histologic examination. A handheld laser probe sealed porcine vessels in vivo. With further improvements in probe design and laser parameter optimization, IR lasers may provide an alternative to RF and US vessel sealing devices.

  20. A Satellite Infrared Technique for Diurnal Rainfall Variability Studies

    NASA Technical Reports Server (NTRS)

    Anagnostou, Emmanouil

    1998-01-01

    Reliable information on the distribution of precipitation at high temporal resolution (infrared (IR) brightness temperatures from geostationary platforms have a weak physical connection to precipitation, however, their high sampling frequency makes them attractive in studying the temporal evolution of cloudiness and convection. On the other hand, microwave-based (MW) observations from lower sampling-frequency polar-orbiting platforms can provide a better physical connection to precipitating hydrometeors. A recent invention in rainfall estimation from a combination of these two sensors involves adjustment of IR estimates using co-existing MW-based precipitation data on a monthly basis. These techniques use the MW data to remove systematic errors in IR rain estimates, while retaining the high sampling frequency of IR observations (approximately every 15-30 minutes). Perhaps of even greater importance to climate and hydrometeorological applications is the separation of mesoscale convective systems into a portion of rain associated with deep convection (hereafter called convective precipitation), and to precipitation falling from more widespread anvil clouds. This current work focuses on estimation of tropical convective and stratiform rainfall. We attempt to answer fundamental questions, such as : is estimation of convective and stratiform precipitation from IR feasible? If so, how accurate can this be? What is the scale dependence of the IR algorithm's performance? To address these questions, quantitative comparisons are performed between coincident IR- and MW-based instantaneous rainfall estimates at the MW 85 Ghz resolution (-12.5 km). Our data set spans a three-month period (January to March, 1996) of MW and IR observations over northern South America (15N-15S and 35W-80W), which includes the Amazon river basin.

  1. Studies of Arctic Middle Atmosphere Chemistry using Infrared Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Lindenmaier, Rodica

    The objective of this Ph.D. project is to investigate Arctic middle atmosphere chemistry using solar infrared absorption spectroscopy. These measurements were made at the Polar Environment Atmospheric Research Laboratory (PEARL) at Eureka, Nunavut, which is operated by the Canadian Network for the Detection of Atmospheric Change (CANDAC). This research is part of the CANDAC/PEARL Arctic Middle Atmosphere Chemistry theme and aims to improve our understanding of the processes controlling the stratospheric ozone budget using measurements of the concentrations of stratospheric constituents. The instrument, a Bruker IFS 125HR Fourier transform infrared (FTIR) spectrometer, has been specifically designed for high-resolution measurements over a broad spectral range and has been used to measure reactive species, source gases, reservoirs, and dynamical tracers at PEARL since August 2006. The first part of this research focuses on the optimization of ozone retrievals, for which 22 microwindows were studied and compared. The spectral region from 1000 to 1005 cm-1 was found to be the most sensitive in both the stratosphere and troposphere, giving the highest number of independent pieces of information and the smallest total error for retrievals at Eureka. Similar studies were performed in coordination with the Network for the Detection of Atmospheric Composition Change for nine other species, with the goal of improving and harmonizing the retrieval parameters among all Infrared Working Group sites. Previous satellite validation exercises have identified the highly variable polar conditions of the spring period to be a challenge. In this work, comparisons between the 125HR and ACE-FTS (Atmospheric Chemistry Experiment-Fourier transform spectrometer) from 2007 to 2010 have been used to develop strict criteria that allow the ground and satellite-based instruments to be confidently compared. After applying these criteria, the differences between the two instruments were generally

  2. Study of Banana Dehydration Using Sequential Infrared Radiation and Freeze-Drying

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The drying and quality characteristics of banana slices processed with a sequential infrared radiation and freeze-drying (SIRFD) method were investigated. To study the drying characteristics of bananas during the infrared (IR) and hot air predehydration, Cavendish bananas slices with 5 mm thickness...

  3. Structural and bonding environments derived from infrared spectroscopic studies

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Infrared spectroscopy, generally in the form of FTIR, has been used to characterize the organic matter in animal manure and relevant materials or fractions. The FT-IR spectra of most manure samples resemble the Type III spectra of humic substances with strong aliphatic characters. However, the absor...

  4. Using infrared thermography to study freezing in plants

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Factors that determine when and to what extent a plant will freeze are complex. While thermocouples have served as the main method of monitoring the freezing process in plants, infrared thermography offers distinct advantages, and the use of this latter technology has provided new insights on the p...

  5. Infrared Studies of Epsilon Aurigae in Eclipse 2010

    NASA Astrophysics Data System (ADS)

    Stencel, Robert E.; Kloppenborg, B.; Wall, R.; Howell, S.; Hoard, D.; Rayner, J.; Bus, S.; Tokunaga, A.; Sitko, M.; Russell, R.; Lynch, D.; Brafford, S.; Hammel, H.; Whitney, B.; Orton, G.; Yanamandra-Fisher, P.; Hora, J.; Hoffman, W.; Skemer, A.

    2011-01-01

    We report a series of observations of the enigmatic long period eclipsing binary epsilon Aurigae during its eclipse interval 2009-2011, using near-infrared spectra & photometry obtained with SpeX/IRTF, Spitzer/IRAC, mid-infrared data with BASS on IRTF & AEOS, MIRSI on IRTF and MIRAC4 on MMT, along with MIRSI on IRTF and MIRAC4 on MMT & Denver's TNTCAM2 at WIRO, and an Optec SSP-4 J&H photometer at Mt.Evans Observatory. The objective of these observations include: (1) confirm the appearance of CO absorption bands at and after mid-eclipse, due to the dark disk, and (2) seek evidence for any mid-infrared solid state spectral features from particles in the disk, seen during different portions of total eclipse. The results to date show that the infrared eclipse is less deep than the optical one, and the implied disk temperature has begun to increase from 550K toward 1100K as eclipse progresses past midpoint and heated portions of the disk come into view. Material properties of the disk are consistent with large particles. This work was supported in part by the bequest of William Herschel Womble in support of astronomy at the University of Denver, by NSF grant 1016678 and JPL RSA 1414715 to the University of Denver, by NASA ADP grant NNX09AC73G to the University of Cincinnati, by The Aerospace Corporation's Independent Research and Development Program.

  6. Infrared generation and wave-mixing studies in cesium

    SciTech Connect

    Christian, W.; Stockdale, J.A.D.; Dodhy, A.; Compton, R.N.

    1985-01-01

    A Nd-YAG pumped dye laser and heat pipe has been used to investigate stimulated infrared production, wave mixing, and ionization in cesium vapor near the one-photon resonant 7P/sub 1/2,3/2/ fine structure states.

  7. Fourier Transform Infrared Spectroscopic Studies Of Wheat In The Mid Infrared

    NASA Astrophysics Data System (ADS)

    Olinger, Jill M.; Griffiths, Peter R.

    1989-12-01

    Official grain standards of the United States state that wheat may be divided into seven classes which are: Durum, Red Durum, Hard Red Spring, Hard Red Winter, Soft Red Winter, White, and Mixed.1 Most end uses of wheat involve converting the grain into flour through one of a variety of grinding methods. The quality of wheat-based products is often very dependent upon the type or class of wheat which was used to make the flour. Pasta products, for example, are made almost exclusively from the flour of durum wheats, which are the hardest of the wheats listed above. The highest quality breads are produced using flour from wheats classed as hard, whereas cakes, cookies and pastries are considered best when flour from wheats classed as soft are used. It is obvious then that the capability of determining the class of a particular wheat, especially with respect to hardness, is of economic importance to growers, processors, and merchants of wheat and wheat products. Hardness has been measured in many different ways 2-5 but, as of yet, no one method has become the method of choice. This paper reports on the use of principal components analysis (PCA) of mid infrared diffuse reflectance (DR) spectra of diluted ground wheats to aid in the classification of those wheats with respect to their hardness. The theory and mathematics involved in a principal component analysis have been described elsewhere.9

  8. Dynamical test of Davydov-type solitons in acetanilide using a picosecond free-electron laser

    NASA Astrophysics Data System (ADS)

    Fann, Wunshain; Rothberg, Lewis; Roberson, Mark; Benson, Steve; Madey, John; Etemad, Shahab; Austin, Robert

    1990-01-01

    Picosecond infrared excitation experiments on acetanilide, an α-helix protein analog, indicate that the anomalous 1650-cm-1 band which appears on cooling of acetanilide crystals persists for at least several microseconds following rapid pulsed heating. The ground-state recovery time is 15+/-5 psec, consistent with a conventional mode strongly coupled to the phonon bath. We therefore suggest that the unusual temperature-dependent spectroscopy of acetanilide can be accounted for by slightly nondegenerate hydrogen atom configurations in the crystal.

  9. Observational Studies of Protoplanetary Disks at Mid-Infrared Wavelengths

    NASA Astrophysics Data System (ADS)

    Li, Dan; Telesco, Charles; Wright, Christopher; Packham, Christopher; Marinas, Naibi

    2013-07-01

    We have used mid-infrared cameras on 8-to-10 m class telescopes to study the properties of young circumstellar disks. During the initial phases of this program we examined a large sample of mid-IR images of standard stars delivered by T-ReCS at Gemini South to evaluate its on-sky performance as characterized by, for example the angular resolution, the PSF shape, and the PSF temporal stability, properties that are most relevant to our high-angular resolution study of disks. With this information we developed an Interactive Data Language (IDL) package of routines optimized for reducing the data and correcting for image defects commonly seen in ground-based mid-IR data. We obtained, reduced, and analyzed mid-IR images and spectra of several Herbig Ae/Be disks (including HD 259431, MWC 1080, VV Ser) and the debris disk (β Pic), and derived their physical properties by means of radiative transfer modeling or spectroscopic decomposition and analyses. These results are highlighted here. During this study, we also helped commission CanariCam, a new mid-IR facility instrument built by the University of Florida for the 10.4 m Gran Telescopio Canarias (GTC) on La Palma, Canary Islands, Spain. CanariCam is an imager with spectroscopic, polarimetric, and coronagraphic capabilities, with the dual-beam polarimetry being a unique mode introduced with CanariCam for the first time to a 10 m telescope at mid-IR wavelengths. It is well known that measurements of polarization, originating from aligned dust grains in the disks and their environments, have the potential to shed light on the morphologies of the magnetic fields in these regions, information that is critical to understanding how stars and planets form. We have obtained polarimetric data of several Herbig Ae/Be disks and YSOs, and the data reduction and analyses are in process. We present preliminary results here. This poster is based upon work supported by the NSF under grant AST-0903672 and AST-0908624 awarded to C.M.T.

  10. Stimulated light forces using picosecond laser pulses

    NASA Astrophysics Data System (ADS)

    Bloch, Immanuel; Goepfert, A.; Haubrich, D.; Lison, F.; Schuetze, R.; Wynands, Robert; Meschede, Dieter

    1997-05-01

    Using the stimulated force exerted by counterpropagating picosecond laser pulses from a mode-locked Ti:Sapphire laser we were able to focus a beam of laser-cooled cesium atoms along one dimension to about 57% of its original width in the detection zone. The force profile was measured outside and inside the overlap region of the pulses and found to be in agreement with an earlier theoretical prediction. A brief theoretical account of the interaction of atoms with pulsed laser light based on the optical Bloch equations is given.

  11. Raman and infrared studies of synthetic Maya Blue pigment

    NASA Astrophysics Data System (ADS)

    Reza, Layra; Manciu, Felicia; Ramirez, Alejandra; Chianelli, Russell

    2008-10-01

    A fascinating aspect of Maya pigments is that despite the environmentally harsh humidity and high temperatures they resist fading and they have unprecedented stability. In this investigation, we address the question of how organic dye binds to inorganic palygorskite to form a pigment similar to Maya Blue. We also address how such binding might be affected by varying the proportion of dye relative to that of the mineral, and by varying the length of heating time used in preparation of the pigment. Our analysis by Raman and infrared absorption spectroscopies proves the partial elimination of the selection rules for the centrosymmetric indigo, and shows the disappearance of the indigo N-H bonding, as the organic molecules incorporate into palygorskite material. Infrared data confirm the loss of zeolitic water and a partial removal of structural water after the heating process. Evidence of bonding between palygorskite and indigo through oxygen is revealed by both spectroscopic measurements.

  12. Joint microwave and infrared studies for soil moisture determination

    NASA Technical Reports Server (NTRS)

    Njoku, E. G.; Schieldge, J. P.; Kahle, A. B. (Principal Investigator)

    1980-01-01

    The feasibility of using a combined microwave-thermal infrared system to determine soil moisture content is addressed. Of particular concern are bare soils. The theoretical basis for microwave emission from soils and the transport of heat and moisture in soils is presented. Also, a description is given of the results of two field experiments held during vernal months in the San Joaquin Valley of California.

  13. Spitzer and DIRBE Studies of the Infrared Background

    NASA Astrophysics Data System (ADS)

    Werner, Michael; Gorjian, Varoujan; Hauser, Michael; Wright, Edward; Arendt, Rick; Chary, Ranga-Ram; Levenson, Louis

    2011-05-01

    The extragalactic background light (EBL), defined as the sky surface brightness of all radiation arising from outside the Milky Way, carries in the 1-5um region the imprint of the nearby Universe, of red-shifted light from the first galaxies, and of any possible pre-galactic contributions. The DIRBE instrument on the COBE satellite has measured the total sky brightness, the Cosmic Infrared Background (CIRB), over the entire sky at 3.6um. The CIRB is the sum of the zodiacal light, galactic starlight, radiation from the ISM, and the EBL. Although the determinations of the EBL are presently limited by uncertainties in the zodiacal light model, experiments now under way can reduce those uncertainties. This Spitzer proposal prepares for that reduction by eliminating other uncertainties. We will use Spitzer to determine the point source components of CIRB at 3.6um, the wavelength of the minimum in the bright foreground from interplanetary dust. We will measure essentially all of the stellar contribution, and more than 80% of the integrated light from resolved galaxies; this can be extrapolated using other Spitzer data to determine IGL. The ultimate objective of this type of study is to search for a currently unknown diffuse component of EBL, DEBL. Symbolically, DEBL = EBL-IGL. In this program, we will execute the following steps aimed at reducing the uncertainties in DEBL once the zodiacal uncertainty in CIRB is minimized and a correction for ISM emission is applied: 1. Cross calibrating DIRBE and Spitzer so that EBL and IGL are on the same flux scale; 2. Reducing the uncertainties in EBL by measuring stars as faint as 19th mag at 3.6um. 3. Determining EBL and IGL at six widely separated positions so that the isotropy - and hence the cosmological significance - of any detection of DEBL can be assessed. We emphasize that this important investigation can be carried out only with Spitzer, and this scientific opportunity is perishable due to Spitzer's finite lifetime.

  14. High Efficiency Near Infrared Spectrometer for Zodiacal Light Spectral Study

    NASA Technical Reports Server (NTRS)

    Kutyrea, A. S.

    2008-01-01

    We are developing a near infrared spectrometer for measuring solar absorption lines in the zodiacal light in the near infrared region. R. Reynolds at el. (2004, ApJ 61 2, 1206) demonstrated that observing single Fraunhofer line can be a powerful tool for extracting zodiacal light parameters based on their measurements of the profile of the Mg I lneat 5 184 A. We are extending this technique to the near infrared with the primary goal of measuring the absolute intensity of the zodiacal light. This measurement will provide the crucial information needed to accurately subtract zodiacal emission from the DIRBE measurements to get a much higher quality measurement of the extragalactic IR background. The instrument design is based on a dual Fabry-Perot interferometer with a narrow band filter. Its double etalon design allows to achieve high spectral contrast to reject the bright out of band telluric OH emission. High spectral contrast is absolutely necessary to achieve detection limits needed to accurately measure the intensity of the absorption line. We present the design, estimated performance of the instrument with the expected results of the observing program.

  15. Study on the characteristics of different infrared transmission in atmospheric turbulence

    NASA Astrophysics Data System (ADS)

    Wang, Zhe; Wang, Jing-yuan; Xu, Zhi-yong; Chang, Shuai; Zhao, Ji-yong; Chen, Yi-wang; Wang, Rong; Wei, Yi-mei

    2015-10-01

    It is known theoretically that the long wavelength infrared has better performance when transmitting in atmospheric turbulence. In order to evaluate the influence of the atmospheric turbulence quantificationally, the characteristics of different infrareds transmission in atmospheric turbulence are simulated and studied. A series of time relevant phase screens of atmospheric turbulence are simulated based on Fourier transform method proposed by McGlamery. Wind speed and direction are introduced in the meantime. Wavefront distortion, image spot dancing and spreading, receive loss of different wavelengths (0.85μm, 3.6μm, 10.6μm) are simulated respectively and compared to each other. The results show that the performances of long wavelength infrared (10.6μm) are the best, mid wavelength infrared (3.6μm) takes the second place and short wavelength infrared (0.85μm) is the worst.

  16. Key technique study and application of infrared thermography in hypersonic wind tunnel

    NASA Astrophysics Data System (ADS)

    LI, Ming; Yang, Yan-guang; Li, Zhi-hui; Zhu, Zhi-wei; Zhou, Jia-sui

    2014-11-01

    The solutions to some key techniques using infrared thermographic technique in hypersonic wind tunnel, such as temperature measurement under great measurement angle, the corresponding relation between model spatial coordinates and the ones in infrared map, the measurement uncertainty analysis of the test data etc., are studied. The typical results in the hypersonic wind tunnel test are presented, including the comparison of the transfer rates on a thin skin flat plate model with a wedge measured with infrared thermography and thermocouple, the experimental study heating effect on the flat plate model impinged by plume flow and the aerodynamic heating on the lift model.

  17. Picosecond Ultrasonic Measurement of Liquids

    NASA Astrophysics Data System (ADS)

    Msall, Madeleine; Wright, Oliver; Matsuda, Osamu

    2007-03-01

    We study acoustic waves launched using a 400 fs blue pulse (407.5 nm) from a Ti:sapphire laser, focused on a SiO2/GaAs interface (r ˜ 25 μm, fluence <15 μJ/cm^2). Because of the asymmetry of the (114) GaAs, thermoelastic and piezoelastic processes generate quasishear and quasilongitudinal acoustic pulses that propagate in both materials. Pulse echoes in the thin (0.2 μm) SiO2 layer cause a variation in optical reflectivity at the interface. In thicker layers, including the GaAs substrate and liquid layers on top of the SiO2 surface, variations in the bulk optical reflectivity caused by the pulses can also be detected if the layer is transparent to the probe wavelength (407 or 815 nm). We look at the pulse propagation in water, ethylene glycol and glycerine. We measure a longitudinal sound velocity for glycerine of 2800 m/s, 32% larger than low frequency values, giving evidence of considerable elastic stiffening. Our pulses have central frequencies ˜50 GHz. A more modest 4.6% increase in the longitudinal sound velocity for water (1552 m/s) is also observed. In spite of this notable stiffening, no shear waves were observed in any of the liquids studied, indicating that propagation is still within the hydrodynamic regime.

  18. Picosecond Time-Resolved Ir-Uv Pump-Probe Spectroscopic Study on Vibrational Energy Relaxation of Benzene Dimer and Trimer in the CH Stretching Region

    NASA Astrophysics Data System (ADS)

    Kusaka, Ryoji; Inokuchi, Yoshiya; Ebata, Takayuki

    2012-06-01

    Vibrational energy relaxation (VER) in the CH stretching region of benzene dimer (Bz_2) and trimer (Bz_3) has been studied by IR-UV pump-probe spectroscopy in supersonic beams. Firstly, we investigated isotope-substituted hd heterodimer, where h=C_6H_6 and d=_6D_6, because the Stem and Top sites in the hd dimer can be site-selectively excited, different from hh homodimer. The two h(stem)d(top) and h(top)d(stem) isomers show remarkable difference in the lifetimes of intracluster vibrational energy redistribution (IVR). In the transient UV spectra, we observed a broad electronic transition due to the bath modes. The time evolutions of the bath modes can be described by a three step VER model involving IVR and vibrational predissociation (VP). This model was also confirmed by the observed rise profile of the Bz fragment. Secondly, we investigated hh homodimer. The hh homodimer shows the stepwise VER process with time constants similar to those of the hd dimer, suggesting a very weak excitation-exchange coupling of the vibrations between the two sites of the hh dimer. Finally, we found that Bz_3 also exhibits the stepwise VER process, though each step is faster than Bz_2.

  19. Picosecond High Pressure Gas Switch experiment

    SciTech Connect

    Cravey, W.R.; Freytag, E.K.; Goerz, D.A.; Poulsen, P.; Pincosy, P.A.

    1993-08-01

    A high Pressure Gas Switch has been developed and tested at LLNL. Risetimes on the order of 200 picoseconds have been observed at 1 kHz prf and 1 atmosphere pressures. Calculations show that switching closure times on the order of tens of picoseconds can be achieved at higher pressures and electric fields. A voltage hold-off of 1 MV/cm has been measured at 10 atmospheres and several MV/cm appears possible with the HPGS. With such high electric field levels, energy storage of tens of Joules in a reasonably sized package is achievable. Initial HPGS performance has been characterized using the WASP pulse generator at LLNL. A detailed description of the switch used for initial testing is given. Switch recovery times of 1-ms have been measured at 1 atmosphere. Data on the switching uniformity, voltage hold-off recovery, and pulse repeatability, is presented. In addition, a physics switch model is described and results are compared with experimental data. Modifications made to the WASP HV pulser in order to drive the HPGS will also be discussed. Recovery times of less than 1 ms were recorded without gas flow in the switch chambers. Low pressure synthetic air was used as the switch dielectric. Longer recovery times were required when it was necessary to over-voltage the switch.

  20. Picosecond laser ablation of porcine sclera

    NASA Astrophysics Data System (ADS)

    Góra, Wojciech S.; Harvey, Eleanor M.; Dhillon, Baljean; Parson, Simon H.; Maier, Robert R. J.; Hand, Duncan P.; Shephard, Jonathan D.

    2013-03-01

    Lasers have been shown to be successful in certain medical procedures and they have been identified as potentially making a major contribution to the development of minimally invasive procedures. However, the uptake is not as widespread and there is scope for many other applications where laser devices may offer a significant advantage in comparison to the traditional surgical tools. The purpose of this research is to assess the potential of using a picosecond laser for minimally invasive laser sclerostomy. Experiments were carried out on porcine scleral samples due to the comparable properties to human tissue. Samples were prepared with a 5mm diameter trephine and were stored in lactated Ringer's solution. After laser machining, the samples were fixed in 3% glutaraldehyde, then dried and investigated under SEM. The laser used in the experiments is an industrial picosecond TRUMPF TruMicro laser operating at a wavelength of 1030nm, pulse length of 6ps, repetition rate of 1 kHz and a focused spot diameter of 30μm. The laser beam was scanned across the samples with the use of a galvanometer scan head and various ablation patterns were investigated. Processing parameters (pulse energy, spot and line separation) which allow for the most efficient laser ablation of scleral tissue without introducing any collateral damage were investigated. The potential to create various shapes, such as linear incisions, square cavities and circular cavities was demonstrated.

  1. Monolithic millimeter-wave and picosecond electronic technologies

    SciTech Connect

    Talley, W.K.; Luhmann, N.C.

    1996-03-12

    Theoretical and experimental studies into monolithic millimeter-wave and picosecond electronic technologies have been undertaken as a collaborative project between the Lawrence Livermore National Laboratory (LLNL) and the University of California Department of Applied Science Coherent Millimeter-Wave Group under the auspices of the Laboratory Directed Research and Development Program at LLNL. The work involves the design and fabrication of monolithic frequency multiplier, beam control, and imaging arrays for millimeter-wave imaging and radar, as well as the development of high speed nonlinear transmission lines for ultra-wideband radar imaging, time domain materials characterization and magnetic fusion plasma applications. In addition, the Coherent Millimeter-Wave Group is involved in the fabrication of a state-of-the-art X-band ({approximately}8-11 GHz) RF photoinjector source aimed at producing psec high brightness electron bunches for advanced accelerator and coherent radiation generation studies.

  2. Infrared study of transitional disks in Ophiuchus with Herschel

    NASA Astrophysics Data System (ADS)

    Rebollido, Isabel; Merín, Bruno; Ribas, Álvaro; Bustamante, Ignacio; Bouy, Hervé; Riviere-Marichalar, Pablo; Prusti, Timo; Pilbratt, Göran L.; André, Philippe; Ábrahám, Péter

    2015-09-01

    Context. Observations of nearby star-forming regions with the Herschel Space Observatory complement our view of the protoplanetary disks in Ophiuchus with information about the outer disks. Aims: The main goal of this project is to provide new far-infrared fluxes for the known disks in the core region of Ophiuchus and to identify potential transitional disks using data from Herschel. Methods: We obtained PACS and SPIRE photometry of previously spectroscopically confirmed young stellar objects (YSO) in the region and analysed their spectral energy distributions. Results: From an initial sample of 261 objects with spectral types in Ophiuchus, we detect 49 disks in at least one Herschel band. We provide new far-infrared fluxes for these objects. One of them is clearly a new transitional disk candidate. Conclusions: The data from Herschel Space Observatory provides fluxes that complement previous infrared data and that we use to identify a new transitional disk candidate. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Final reduced Herschel maps are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/581/A30Appendix A is available in electronic form at http://www.aanda.orgAll tables are also available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/581/A30

  3. Optical and Near Infrared Study of the Cepheus E Outflow, a Very Low Excitation Object

    NASA Technical Reports Server (NTRS)

    Noreiga-Crespo, A.; Ayala, S.; Garnavich, P.; Curiel, S.; Raga, A.; Bohm, K.; Raymond, J.

    2000-01-01

    In this study, we explore the link between the physical properties of the outflow as determined from optical imaging and spectroscopy, and compare these results with those obtained from observations in the near infrared.

  4. An infrared imaging study of galaxies in the local universe

    NASA Technical Reports Server (NTRS)

    Grauer, Albert D.; Rieke, Marcia J.; Mcleod, Kim K.

    1995-01-01

    This poster was a preliminary report on a survey of galaxies in the local universe at J and K using a NICMOS3 256 x 256 infrared photometric camera attached to the 61 inch telescope on Mt. Bigelow. Deep images are being obtained for a representative sample of galaxies in the Uppsala General Catalogue. Structural and color parameters are determined for a wide variety of galactic types. These data should prove to be valuable in characterizing stellar populations within disks and bulges, determining if IR-active galaxies have unusual global as well as- nuclear properties, and understanding the effects of evolution and redshift dimming in distant galaxies.

  5. Design study for Thermal Infrared Multispectral Scanner (TIMS)

    NASA Technical Reports Server (NTRS)

    Stanich, C. G.; Osterwisch, F. G.; Szeles, D. M.; Houtman, W. H.

    1981-01-01

    The feasibility of dividing the 8-12 micrometer thermal infrared wavelength region into six spectral bands by an airborne line scanner system was investigated. By combining an existing scanner design with a 6 band spectrometer, a system for the remote sensing of Earth resources was developed. The elements in the spectrometer include an off axis reflective collimator, a reflective diffraction grating, a triplet germanium imaging lens, a photoconductive mercury cadmium telluride sensor array, and the mechanical assembly to hold these parts and maintain their optical alignment across a broad temperature range. The existing scanner design was modified to accept the new spectrometer and two field filling thermal reference sources.

  6. Development of near infrared spectrometer for gem materials study

    NASA Astrophysics Data System (ADS)

    Jindata, W.; Meesiri, W.; Wongkokua, W.

    2015-07-01

    Most of gem materials can be characterized by infrared absorption spectroscopy. Normally, mid infrared absorption technique has been applied for investigating fundamental vibrational modes. However, for some gem materials, such as tourmaline, NIR is a better choice due to differentiation. Most commercial NIR spectrometers employ complicated dispersive grating or Fourier transform techniques. In this work, we developed a filter type NIR spectrometer with the availability of high efficiency and low-cost narrow bandpass NIR interference filters to be taught in a physics laboratory. The instrument was designed for transmission-mode configuration. A 50W halogen lamp was used as NIR source. There were fourteen NIR filters mounted on a rotatory wheel for wavelength selection ranging from 1000-1650 nm with steps of 50 nm. A 1.0 mm diameter of InGaAs photodiode was used as the detector for the spectrometer. Hence, transparent gem materials can be used as samples for experiment. Student can learn vibrational absorption spectroscopy as well as Beer-Lambert law from the development of this instrument.

  7. Picosecond Acoustic Measurement of Anisotropic Properties of Thin Films

    SciTech Connect

    Perton, M.; Rossignol, C.; Chigarev, N.; Audoin, B.

    2007-03-21

    Properties of thin metallic films have been studied extensively by means of laser-picosecond ultrasonics. Generation of longitudinal and shear waves via thermoelastic mechanism and large source has been only demonstrated for waves vectors along the normal to the interface. However, such measurements cannot provide complete information about elastic properties of films. As it has been already shown for nanosecond ultrasonics, the knowledge of group or phase velocities in several directions for sources with small lateral size allows determining the stiffness tensor coefficients of a sample. The experimental set-up was prepared to obtain the thinnest size for the source to achieve acoustic diffraction. The identification of the stiffness tensor components, based on the inversion of the bulk waves phase velocities, is applied to signals simulated and experimentally recorded for a material with hexagonal properties. First estimation of stiffness tensor coefficients for thin metallic film 2.1 {mu}m has been performed.

  8. Infrared Spectroscopy and Catalysis Research: Infrared spectra of adsorbed molecules provide important information in the study of catalysis.

    PubMed

    Eischens, R P

    1964-10-23

    The examples discussed here represent only a small part of the published work relating to infrared spectra of adsorbed molecules. The publications in this field indicate that infrared spectroscopy is being used for surface chemistry research in about 50 laboratories throughout the world. This effort is mainly devoted to problems related to catalysis, and in this field infrared spectroscopy is the most widely used physical tool for surface chemistry studies. The general acceptance of infrared spectroscopy is primarily due to the fact that it provides information which is pertinent to the understanding of surface reactions on an atomic scale. During the last decade significant progress has also been made in the classical chemical techniques of catalysis study and in utilization of physical tools which depend on phenomena of magnetism, conductivity, low-energy electron diffraction, and electron emission. Probably the most important progress has been in the field of inorganic chemistry, where dramatic advances have been made in knowledge of metal coordination compounds. Such knowledge is vital to the understanding of catalysis on metal surfaces. I believe this progress has produced an attitude of sophisticated optimism among catalysis researchers with regard to eventual understanding of heterogeneous catalysis. This attitude is closely related to the realization that there is no "secret of catalysis" which places catalytic action beyond the limits of ordinary chemical knowledge (22). This view implies that the chemical aspects of heterogeneous catalysis are not unique and that the use of solid catalysts merely provides a highly effective exposure of catalytic atoms and facilitates separation of the products from the catalyst. Many capable catalysis researchers believe that studies of homogeneous catalysis provide the most direct route for the study of heterogeneous catalysis. Obviously homogeneous reactions catalyzed by compounds containing only one or two metal atoms

  9. The influence of surface passivation on electronic energy relaxation dynamics of CdSe and CdSe/CdS nanocrystals studied using visible and near infrared transient absorption spectroscopy.

    PubMed

    Yi, Chongyue; Knappenberger, Kenneth L

    2015-03-19

    Charge carrier relaxation dynamics of electronically excited CdSe and CdSe/CdS core/shell nanocrystals (NCs) were studied using femtosecond time-resolved transient absorption spectroscopy, employing both visible and near-infrared (NIR) probe laser pulses. Following 400 nm excitation, the combination of visible and NIR laser probe pulses were used to determine the influence of surface passivation on electronic relaxation dynamics for nanocrystals overcoated with either organic ligands or inorganic semiconductors. In particular, low-energy NIR photons were used to isolate transient absorption signals due to either electron and hole intraband transitions. Four relaxation components were detected for CdSe NCs passivated by organic molecules: (1) picosecond hole relaxation; (2) electron deep trapping; (3) electron surface trapping; and (4) exciton radiative recombination. Based on TA data collected over a broad energy range, electron deep trapping at Se(2-) sites was suppressed for CdSe NCs passivated by inorganic (CdS) semiconducting materials. By comparing the time-dependent transient absorption data of a series of CdSe/CdS NCs with different shell thicknesses, evidence for the transition from Type-I to quasi Type-II NCs was obtained. These data illustrate the sensitivity of femtosecond time-resolved transient absorption measurements carried out over visible and near infrared probe energies for determining the influence of nanocrystal structure on electronic relaxation dynamics. PMID:25761249

  10. Water dynamics in salt solutions studied with ultrafast two-dimensional infrared (2D IR) vibrational echo spectroscopy.

    PubMed

    Fayer, Michael D; Moilanen, David E; Wong, Daryl; Rosenfeld, Daniel E; Fenn, Emily E; Park, Sungnam

    2009-09-15

    Water is ubiquitous in nature, but it exists as pure water infrequently. From the ocean to biology, water molecules interact with a wide variety of dissolved species. Many of these species are charged. In the ocean, water interacts with dissolved salts. In biological systems, water interacts with dissolved salts as well as charged amino acids, the zwitterionic head groups of membranes, and other biological groups that carry charges. Water plays a central role in a vast number of chemical processes because of its dynamic hydrogen-bond network. A water molecule can form up to four hydrogen bonds in an approximately tetrahedral arrangement. These hydrogen bonds are continually being broken, and new bonds are being formed on a picosecond time scale. The ability of the hydrogen-bond network of water to rapidly reconfigure enables water to accommodate and facilitate chemical processes. Therefore, the influence of charged species on water hydrogen-bond dynamics is important. Recent advances in ultrafast coherent infrared spectroscopy have greatly expanded our understanding of water dynamics. Two-dimensional infrared (2D IR) vibrational echo spectroscopy is providing new observables that yield direct information on the fast dynamics of molecules in their ground electronic state under thermal equilibrium conditions. The 2D IR vibrational echoes are akin to 2D nuclear magnetic resonance (NMR) but operate on time scales that are many orders of magnitude shorter. In a 2D IR vibrational echo experiment (see the Conspectus figure), three IR pulses are tuned to the vibrational frequency of interest, which in this case is the frequency of the hydroxyl stretching mode of water. The first two pulses "label" the initial molecular structures by their vibrational frequencies. The system evolves between pulses two and three, and the third pulse stimulates the emission of the vibrational echo pulse, which is the signal. The vibrational echo pulse is heterodyne, detected by combining it

  11. THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): A SOUNDING ROCKET PAYLOAD TO STUDY THE NEAR INFRARED EXTRAGALACTIC BACKGROUND LIGHT

    SciTech Connect

    Zemcov, M.; Bock, J.; Hristov, V.; Levenson, L. R.; Mason, P.; Arai, T.; Matsumoto, T.; Matsuura, S.; Tsumura, K.; Wada, T.; Battle, J.; Cooray, A.; Keating, B.; Renbarger, T.; Kim, M. G.; Lee, D. H.; Nam, U. W.; Sullivan, I.; Suzuki, K.

    2013-08-15

    The Cosmic Infrared Background Experiment (CIBER) is a suite of four instruments designed to study the near infrared (IR) background light from above the Earth's atmosphere. The instrument package comprises two imaging telescopes designed to characterize spatial anisotropy in the extragalactic IR background caused by cosmological structure during the epoch of reionization, a low resolution spectrometer to measure the absolute spectrum of the extragalactic IR background, and a narrow band spectrometer optimized to measure the absolute brightness of the zodiacal light foreground. In this paper we describe the design and characterization of the CIBER payload. The detailed mechanical, cryogenic, and electrical design of the system are presented, including all system components common to the four instruments. We present the methods and equipment used to characterize the instruments before and after flight, and give a detailed description of CIBER's flight profile and configurations. CIBER is designed to be recoverable and has flown four times, with modifications to the payload having been informed by analysis of the first flight data. All four instruments performed to specifications during the subsequent flights, and the scientific data from these flights are currently being analyzed.

  12. Near-infrared studies of embedded star clusters

    NASA Astrophysics Data System (ADS)

    Park, Chan

    The Fan Mountain Near-Infrared Camera, FanCam, features an 8.7'x8.7' field of view on a 1024x1024 Teledyne Imaging Sensors HAWAII-1 detector array. The instrument mounts at the f/15.5 focus of the 31 inch telescope. Its seeing-limited optical design, optimized for the JHK atmospheric bands, includes a field stop at the telescope focus, a doublet collimator, two 8-position filterwheels straddling a Lyot stop, and a doublet reimager. The 0.51''pixel-1 plate scale leads to a slightly oversampled point spread function for the typical seeing of 1.5''. The entire optical train is encased in a cryogenic dewar cooled by a closed-loop cooling system. Chapter 2 describes the camera design and some early results of camera performance test. Long term near-infrared, J, H, and Ks, photometric monitoring of the embedded cluster NGC 1333 is presented in Chapter 3. We employ the Stetson variability index and reduced chi 2 to identify variable objects. Color-magnitude and color-color diagrams demonstrate that NGC 1333 is extremely young and highly extincted. Light curves in all three bands are well correlated. The spatial distribution of variable stars shows a strong correlation with the peak of the extinction map while non-variable stars are evenly spread over the whole field of view. Spitzer-2MASS-identified IR excess YSOs and Chandra X-ray sources were compared with our variable stars. A total of 25 previously-unknown member candidates are presented, with 15 objects in the mass range of brown dwarfs. The IMF and mass distribution of the cluster are presented. We discuss the implication of Ks vs. H--Ks color-magnitude diagram slope statistics in view of the evolutionary sequence of young star-forming embedded clusters. Another long term near-infrared, J, H, and Ks, photometric monitoring performed with FanCam for the embedded cluster NGC 7129 is presented in Chapter 4.

  13. Picosecond-nanosecond laser photolysis studies on the photochemical reaction of excited benzophenone with 1,4-diazabicyclo[2.2.2]octane in acetonitrile solution: proton abstraction of the free benzophenone anion radical from the ground state amine

    NASA Astrophysics Data System (ADS)

    Miyasaka, Hiroshi; Morita, Kazuhiro; Kamada, Kenji; Mataga, Noboru

    1991-04-01

    Picosecond and nanosecond dynamics of the ion pair produced by the electron transfer reaction between the triplet state benzophenone ( 3BP*) and 1,4-diazabicyclo[2.2.2]octane (DABCO) was investigated by means of transient absorption spectroscopy and laser-induced photoconductivity measurement. It has been revealed that the solvated free anion radical of BP, produced by the rapid ionic dissociation of the ion pair within 2 ns, abstracts proton from the neutral DABCO giving benzophenone ketyl radical, competing with the charge recombination reaction at encounter with DABCO +, decomposition and/or impurity scavenging processes.

  14. Infrared imaging and tufts studies of boundary layer flow regimes on a NACA 0012 airfoil

    NASA Technical Reports Server (NTRS)

    Gartenberg, Ehud; Roberts, A. Sidney, Jr.; Mcree, Griffith J.

    1989-01-01

    A study of boundary-layer flow regimes on a NACA 0012 airfoil from zero angle of attack up to separation is presented. The boundary-layer transition from the laminar to the turbulent regime and the onset of the separation were detected by surface thermography of the airfoil performed with an infrared imaging system. The findings were compared with observations of aluminum-foil tufts visible with the infrared imaging system. This arrangement allows the infrared imaging system to assume the dual role of flow regime detection through surface thermography and flow visualization through the observation of the aluminum-foil tufts. Ultimately the temperature history on an uncontaminated surface could provide an interpretation of the state of boundary-layer flow. Separation studies performed on the NACA 0012 airfoil showed that aluminum foil tufts can be observed with infrared imaging systems.

  15. A rheumatoid arthritis study by Fourier transform infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Carvalho, Carolina S.; Silva, Ana Carla A.; Santos, Tatiano J. P. S.; Martin, Airton A.; dos Santos Fernandes, Ana Célia; Andrade, Luís E.; Raniero, Leandro

    2012-01-01

    Rheumatoid arthritis is a systemic inflammatory disease of unknown causes and a new methods to identify it in early stages are needed. The main purpose of this work is the biochemical differentiation of sera between normal and RA patients, through the establishment of a statistical method that can be appropriately used for serological analysis. The human sera from 39 healthy donors and 39 rheumatics donors were collected and analyzed by Fourier Transform Infrared Spectroscopy. The results show significant spectral variations with p<0.05 in regions corresponding to protein, lipids and immunoglobulins. The technique of latex particles, coated with human IgG and monoclonal anti-CRP by indirect agglutination known as FR and CRP, was performed to confirm possible false-negative results within the groups, facilitating the statistical interpretation and validation of the technique.

  16. Study of a middle-wavelength infrared athermalized optical system

    NASA Astrophysics Data System (ADS)

    Gao, Hong-Yun; Xiong, Tao; Li, Sheng-Hui

    2008-09-01

    For cooled 320 × 240 detector with staring focal plane array, a novel middle infrared athermal optical system is presented. The system is composed of 5 spherical lenses. The materials of lenses are silicon and germanium. The optical parameters and modulation transfer function (MTF) are investigated. The system has the diffraction limited image quality and stable image plane from -30 °C to 70 °C. The characteristic parameters of the system are as follows: f/number of 4, cold shield efficiency of 100%, spectrum region of 3.7 4.8 μm and transmissivity of 80%. The system has the merits of simple structure, low price, and it is easy to machining.

  17. Comparative study of infrared techniques for fast biogeochemical sediment analyses

    NASA Astrophysics Data System (ADS)

    Hahn, A.; RoséN, P.; Kliem, P.; Ohlendorf, C.; Zolitschka, B.

    2011-10-01

    Analysis of sediment samples in the visible to mid infrared (IR) region requires small amounts of sample material and enables rapid and cost efficient geochemical analysis of mineral and organic sediment components. Here we use geochemical properties (total organic and inorganic carbon, biogenic silica, total nitrogen) from the ICDP deep drilling project PASADO to compare three different IR spectroscopy techniques: Diffuse Reflectance Fourier Transform IR Spectrometry (DRIFTS), Attenuated Total Reflectance Fourier Transform IR Spectroscopy (ATR-FTIRS) and Visible Near IR Spectroscopy (VNIRS). ATR-FTIRS and VNIRS are more rapid techniques compared to DRIFTS. Results show that calibration models developed using DRIFTS are most robust (correlation coefficient: R = 0.92 for TIC, R = 0.84 for BSi, R = 0.97 for TOC, R = 0.95 for TN). However, good statistical performance was also obtained by using ATR-FTIRS and VNIRS. When time and costs are limiting factors, these tools may be given preference for rapid biogeochemical screening.

  18. Infrared and optical spectroscopy study of UHMWPE polymers

    NASA Astrophysics Data System (ADS)

    Wolf, M. S.; Morvan, J. N.; Dordevic, S. V.; Stojilovic, N.

    2009-03-01

    Ultra-High Molecular Weight Polyethylene (UHMWPE) is very often the material of choice for the bearing surfaces of most hip and knee implants primarily due to its low friction combined with good toughness and abrasion resistance. We investigate optical properties of biomedical-grade UHMWPE GUR 1020 powders and sheets using infrared and UV-vis spectroscopy and compare results with those from industrial grade samples. In addition, we use X-ray diffraction spectroscopy to monitor the changes in crystal structure of these polymers as a function of temperature. Finally, we deliberately oxidize and subsequently characterize these materials since the oxidation of UHMWPE bio- implants is believed to be responsible for their failure in vivo.

  19. Raman and Infrared Absorption Study of Indigoid-based Pigments

    NASA Astrophysics Data System (ADS)

    Manciu, Felicia; Durrer, William; Reza, Layra; Ramirez, Alejandra; Chianelli, Russell

    2009-04-01

    A fascinating aspect of Maya pigments is that despite the environmentally harsh humidity and high temperatures they resist fading and they have unprecedented stability. In this investigation, we address the question of how organic dye binds to inorganic palygorskite to form pigments. Our analysis by Raman and infrared absorption spectroscopies proves that different processes are taking place for the indigo-palygorskite system as compared with the thioindigo-palygorskite complex. While partial elimination of the selection rules for the centrosymmetric indigo and disappearance of the indigo N-H bonding, with conversion to dehydroindigo, is observed for the first compound, the latter shows no evident structure modification. The interaction between indigo and palygorskite is likely through oxygen and nitrogen. Only oxygen plays this role for the thioindigo-palygorskite complex.

  20. Study of dual-channel infrared spectroradiometer systems

    NASA Technical Reports Server (NTRS)

    Wrubel, J. A.

    1973-01-01

    A dual channel infrared spectroradiometer system was installed at a high altitude facility where spectral data were obtained from F2/H2, FLOX/CH4, FLOX/B2H6, OF2/CH4, and OF2/B2H6 propellant combinations. A good HF emission spectra was obtained for tests with the OF2B2H6 propellant combination. Subsequently, data were obtained on the LOX/GH2 propellant combination at sea level and altitude conditions that were inconsistent because the calculation of plume properties led to physically unrealistic results. The inconsistencies resulted from measurement accuracy not being within the narrow limits required by the data reduction scheme. Although the anticipated program results were not obtained, the data gathered are useful for guiding future experimental efforts and formulations of less sensitive analytical models.

  1. High-intensity coherent FIR radiation from sub-picosecond electron bunches

    SciTech Connect

    Kung, P.H.; Lihn, Hung-chi; Wiedemann, H.; Bocek, D.

    1994-01-01

    A facility to generate high-intensity, ultra-short pulses of broad-band far-infrared radiation has been assembled and tested at Stanford. The device uses sub-picosecond relativistic electron bunches to generate coherent radiation through transition or synchrotron radiation in the far-infrared (FIR) regime between millimeter waves and wavelengths of about 100 {mu}m and less. Experimental results show a peak radiation power of greater than 0.33 MW within a micro-bunch and an average FIR radiation power of 4 mW. The average bunch length of 2856 micro-bunches within a 1 {mu}sec macro-pulse is estimated to be about 480 sec. Simulations experimental setup and results will be discussed.

  2. Infrared cameras are potential traceable "fixed points" for future thermometry studies.

    PubMed

    Yap Kannan, R; Keresztes, K; Hussain, S; Coats, T J; Bown, M J

    2015-01-01

    The National physical laboratory (NPL) requires "fixed points" whose temperatures have been established by the International Temperature Scale of 1990 (ITS 90) be used for device calibration. In practice, "near" blackbody radiators together with the standard platinum resistance thermometer is accepted as a standard. The aim of this study was to report the correlation and limits of agreement (LOA) of the thermal infrared camera and non-contact infrared temporal thermometer against each other and the "near" blackbody radiator. Temperature readings from an infrared thermography camera (FLIR T650sc) and a non-contact infrared temporal thermometer (Hubdic FS-700) were compared to a near blackbody (Hyperion R blackbody model 982) at 0.5 °C increments between 20-40 °C. At each increment, blackbody cavity temperature was confirmed with the platinum resistance thermometer. Measurements were taken initially with the thermal infrared camera followed by the infrared thermometer, with each device mounted in turn on a stand at a fixed distance of 20 cm and 5 cm from the blackbody aperture, respectively. The platinum thermometer under-estimated the blackbody temperature by 0.015 °C (95% LOA: -0.08 °C to 0.05 °C), in contrast to the thermal infrared camera and infrared thermometer which over-estimated the blackbody temperature by 0.16 °C (95% LOA: 0.03 °C to 0.28 °C) and 0.75 °C (95% LOA: -0.30 °C to 1.79 °C), respectively. Infrared thermometer over-estimates thermal infrared camera measurements by 0.6 °C (95% LOA: -0.46 °C to 1.65 °C). In conclusion, the thermal infrared camera is a potential temperature reference "fixed point" that could substitute mercury thermometers. However, further repeatability and reproducibility studies will be required with different models of thermal infrared cameras. PMID:26468981

  3. Tunable far infrared studies of molecular parameters in support of stratospheric measurements

    NASA Technical Reports Server (NTRS)

    Chance, Kelly V.; Evenson, K. M.; Park, K.; Radostitz, J. V.; Jennings, D. A.; Nolt, I. G.; Vanek, M. D.

    1991-01-01

    Lab studies were made in support of far infrared spectroscopy of the stratosphere using the Tunable Far InfraRed (TuFIR) method of ultrahigh resolution spectroscopy and, more recently, spectroscopic and retrieval calculations performed in support of satellite-based atmospheric measurement programs: the Global Ozone Monitoring Experiment (GOME), and the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY).

  4. Timing characteristics of Large Area Picosecond Photodetectors

    NASA Astrophysics Data System (ADS)

    Adams, B. W.; Elagin, A.; Frisch, H. J.; Obaid, R.; Oberla, E.; Vostrikov, A.; Wagner, R. G.; Wang, J.; Wetstein, M.

    2015-09-01

    The LAPPD Collaboration was formed to develop ultrafast large-area imaging photodetectors based on new methods for fabricating microchannel plates (MCPs). In this paper we characterize the time response using a pulsed, sub-picosecond laser. We observe single-photoelectron time resolutions of a 20 cm × 20 cm MCP consistently below 70 ps, spatial resolutions of roughly 500 μm, and median gains higher than 107. The RMS measured at one particular point on an LAPPD detector is 58 ps, with ± 1σ of 47 ps. The differential time resolution between the signal reaching the two ends of the delay line anode is measured to be 5.1 ps for large signals, with an asymptotic limit falling below 2 ps as noise-over-signal approaches zero.

  5. Timing Characteristics of Large Area Picosecond Photodetectors

    SciTech Connect

    Adams, Bernhard W.; Elagin, Andrey L.; Frisch, H.; Obaid, Razib; Oberla, E; Vostrikov, Alexander; Wagner, Robert G.; Wang, Jingbo; Wetstein, Matthew J.; Northrop, R

    2015-09-21

    The LAPPD Collaboration was formed to develop ultralast large-area imaging photodetectors based on new methods for fabricating microchannel plates (MCPs). In this paper we characterize the time response using a pulsed, sub picosecond laser. We observe single photoelectron time resolutions of a 20 cm x 20 cm MCP consistently below 70 ps, spatial resolutions of roughly 500 pm, and median gains higher than 10(7). The RMS measured at one particular point on an LAPPD detector is 58 ps, with in of 47 ps. The differential time resolution between the signal reaching the two ends of the delay line anode is measured to be 5.1 ps for large signals, with an asymptotic limit falling below 2 ps as noise-over-signal approaches zero.

  6. Development of a mid-infrared laser for study of infrared countermeasures techniques

    NASA Astrophysics Data System (ADS)

    Bekman, H. H. P. T.; van den Heuvel, J. C.; van Putten, F. J. M.; Schleijpen, Ric

    2004-12-01

    Countermeasures against heat seeking missiles require access to efficient laser sources, which should emit wavelengths at band I, II and IV. Efficient diode pumped solid-state lasers, combined with efficient non-linear wavelength shifters, allow the development of practical tuneable mid-IR countermeasure sources. The paper describes the requirements and the development of a tabletop laser source for study of DIRCM techniques. Jamming laser systems must be able of creating pulse sequences in the frequency range between 100 Hz and 10,000 Hz, including the capability to mix and sweep the jam frequency. A Nd:YVO4 pump laser with maximum pump power of 3 Watt and pulse length of 10 ns, and a maximum modulation frequency of 100 kHz was selected. A linear single resonant OPO cavity with 30 mm long, 1mm thick PPLN crystals was build. With the tabletop laser system we were able to generate wavelengths from 1.5 to 4 micron. In band I, at 2 micron we can generate between 400-550 mW, and in band II, from 3-4 micron we can generate 130-160 mW laser jam power. The beam quality (M2) is approximately 2.5. The power efficiency for the idler was 8.8%, while the slope power efficiency was 15%. Jam patterns are generated by use of an acousto-optic modulator.

  7. Patterning of ITO with picosecond lasers

    NASA Astrophysics Data System (ADS)

    Račiukaitis, Gediminas; Brikas, Marijus; Gedvilas, Mindaugas; Darčianovas, Gediminas

    2007-02-01

    Indium-tin oxide (ITO) is the main material for making transparent electrodes in electronic devices and flat panel displays. Laser-direct-write technology has been widely used for patterning ITO. The well defined edges and good electrical isolation at a short separation are required for the modern OLED and RFID devices of high packing density. High repetition rate lasers with a short, picosecond pulse width offer new possibilities for high efficiency structuring of transparent conductors on glass and other substrates. The results of patterning the ITO film on glass with picosecond lasers at various wavelengths are presented. Laser radiation initiated ablation of the material, forming trenches in ITO. Profile of the trenches was analyzed with a phase contrast optical microscope, a stylus type profiler, SEM and AFM. Clean removal of the ITO layer was achieved with the 266 nm radiation when laser fluence was above the threshold at 0.20 J/cm2, while for the 355 nm radiation the threshold was higher, above 0.46 J/cm2. The glass substrate was damaged in the area where the fluence was higher than 1.55 J/cm2. The 532 nm radiation allowed getting well defined trenches, but a lot of residues in the form of dust were generated on the surface. UV radiation at the 266 nm provided the widest working window for ITO ablation without damage of the substrate. Use of UV laser radiation with fluences close to the ablation threshold made it possible to minimize surface contamination and the recast ridge formation during the process.

  8. 39.1 μJ picosecond ultraviolet pulses at 355 nm with 1 MHz repeat rate.

    PubMed

    Zhu, Peng; Li, Daijun; Liu, Qingyong; Chen, Jun; Fu, Shaojun; Shi, Peng; Du, Keming; Loosen, Peter

    2013-11-15

    Based on our reliable high-power picosecond laser source with high beam qualities, we designed a compact and efficient third harmonic generation scheme by cascading a frequency doubling and a sum frequency generation using LBO as the nonlinear material. A maximum output of 39.1 W with a repeat rate of 1 MHz at 355 nm was obtained, which implied a pulse energy of 39.1 μJ, which was the highest picosecond UV pulse energy with an all-solid-state setup so far. The total conversion efficiency from infrared to UV was up to 46%. And the output UV has excellent beam qualities with an M-square factor less than 1.1. PMID:24322114

  9. A new photometric study of Herbig Ae/Be stars in the infrared

    NASA Astrophysics Data System (ADS)

    Chen, P. S.; Shan, H. G.; Zhang, P.

    2016-04-01

    In this paper we collected almost all HAeBe stars known so far (253 sources in total) to photometrically study their infrared properties. The 2MASS, WISE, IRAS and AKARI data are employed to make analyses. It is shown from several two-color diagrams that from 1 μm to 60 μm infrared radiations from circumstellar disks with the power law distribution play a very important role for infrared excesses which are much larger than that for ordinary Be stars. In the WISE two-color diagram, (W2-W3) vs. (W1-W2), some sources show thermal emissions probably due to dust surrounded and enhanced PAH features at 3.3 and 11.3 μm. In the wavelength longer than 60 μm infrared radiations are not so influenced by the circumstellar disk, but mainly from the ISM surrounded.

  10. A study of infrared spectroscopy de-noising based on LMS adaptive filter

    NASA Astrophysics Data System (ADS)

    Mo, Jia-qing; Lv, Xiao-yi; Yu, Xiao

    2015-12-01

    Infrared spectroscopy has been widely used, but which often contains a lot of noise, so the spectral characteristic of the sample is seriously affected. Therefore the de-noising is very important in the spectrum analysis and processing. In the study of infrared spectroscopy, the least mean square (LMS) adaptive filter was applied in the field firstly. LMS adaptive filter algorithm can reserve the detail and envelope of the effective signal when the method was applied to infrared spectroscopy of breast cancer which signal-to-noise ratio (SNR) is lower than 10 dB, contrast and analysis the result with result of wavelet transform and ensemble empirical mode decomposition (EEMD). The three evaluation standards (SNR, root mean square error (RMSE) and the correlation coefficient (ρ)) fully proved de-noising advantages of LMS adaptive filter in infrared spectroscopy of breast cancer.

  11. A Thermal Infrared Radiation Parameterization for Atmospheric Studies

    NASA Technical Reports Server (NTRS)

    Chou, Ming-Dah; Suarez, Max J.; Liang, Xin-Zhong; Yan, Michael M.-H.; Cote, Charles (Technical Monitor)

    2001-01-01

    This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

  12. Infrared spectrometry studies: Spectral digital data acquisition system (1971 version)

    NASA Technical Reports Server (NTRS)

    Lu, L.; Lyon, R. J. P.

    1971-01-01

    The construction of the Stanford Spectral Digital Data Acquisition System is described. The objective of the system is to record both the spectral distribution of incoming radiation from the rock samples measured by the spectroradiometer (Exotech Model 10-34 Circular Variable Filter Infrared Spectroradiometer) together with other weather information. This system is designed for both laboratory and field measurement programs. The multichannel inputs (8 channels) of the system are as follows: Ch 1 the Spectro-radiometer, Ch 2 the radiometer (PRT-5), and Ch 3 to Ch 8 for the weather information. The system records data from channel 1 and channel 2 alternately for 48 times, before a fast sweep across the six weather channels, to form a single scan in the scan counter. The operation is illustrated in a block diagram, and the theory of operation is described. The outputs are written on a 7-track magnetic tape with IBM compatible form. The format of the tape and the playback computer programs are included. The micro-pac digital modules and a CIPHER model 70 tape recorder (Cipher Data Products) are used. One of the major characteristics of this system is that it is externally clocked by the spectroradiometer instead of taking data at intervals of various wavelengths by using internal-clocking.

  13. Thermal oscillations in rat kidneys: an infrared imaging study

    PubMed Central

    Gorbach, Alexander M.; Wang, Hengliang; Elster, Eric

    2008-01-01

    A high-resolution infrared (IR) camera was used to assess rhythmicity in localized renal blood flow, including the extent of regions containing nephrons with spontaneous oscillations in their individual blood flow. The IR imaging was able to follow changes in rat renal perfusion during baseline conditions, during occlusion of the main renal artery and during the administration of either saline or papaverine. Concurrent recordings were made of tubular pressure in superficial nephrons. Spontaneous vascular oscillations centred around 0.02–0.05 Hz and approximately 0.01 Hz could be detected reproducibly by IR imaging. Their spectral characteristics and their response to papaverine were in line with tubular pressure measurements. The intensity of and synchrony between thermal signals from different local areas of the kidney may allow, after surgical exposure, non-invasive imaging of functional clusters involved in renal cortical blood flow. Through visualization of the spatial extent of thermal oscillations, IR imaging holds promise in assessing kidney autoregulatory mechanisms. PMID:18650199

  14. Studying hot exozodiacal dust with near-infrared interferometry

    NASA Astrophysics Data System (ADS)

    Absil, Olivier; Defrère, Denis; Le Bouquin, Jean-Baptiste; Mollier, Benjamin; Augereau, Jean-Charles; Coudé du Foresto, Vincent; Di Folco, Emmanuel; Ertel, Steve; ten Brummelaar, Theo

    2012-07-01

    Since our first detection of a resolved near-infrared emission around the main sequence star Vega, which we identified as the signature of hot dust grains close to the sublimation limit, we have been systematically searching for similar signatures around a magnitude-limited sample of nearby main sequence stars with the FLUOR instrument at the CHARA array. About 40 targets with spectral types ranging from A to K have been observed within the last 6 years, leading to first statistical trends on the occurence of the bright exozodi phenomenon as a function of spectral type. Our target sample is balanced between stars known to harbour cold dust populations from space-based missions (e.g., Spitzer, Herschel) and stars without cold dust, so that the occurence of abundant hot dust can also be correlated with the presence of large reservoirs of cold planetesimals. In this paper, we present preliminary conclusions from the CHARA/FLUOR survey. We also discuss the first results obtained in 2011/2012 with the new PIONIER visiting instrument at the VLTI, which is now used to extend our survey sample to the Southern hemisphere and to fainter targets. A first measurement of the exozodi/star flux ratio as a function of wavelength within the H band is presented, thanks to the low spectral resolution capability of PIONIER. Finally, we also briefly discuss our plans for extending the survey to fainter targets in the Northern hemisphere with an upgraded version of the FLUOR beam combiner.

  15. Raman and infrared spectroscopic study of boussingaultite and nickelboussingaultite

    NASA Astrophysics Data System (ADS)

    Culka, Adam; Jehlička, Jan; Němec, Ivan

    2009-08-01

    The Raman and infrared spectra of two secondary sulphate minerals, boussingaultite [(NH 4) 2Mg(SO 4) 2·6H 2O] and nickelboussingaultite [(NH 4) 2Ni,Mg(SO 4) 2·6H 2O] have been collected. Two bands observed at 983 and 990 cm -1 were attributed to the ν1(SO 42-) symmetric stretching vibration. The bands at 1133, 1096 and 1063 cm -1 in boussingaultite spectra and bands at 1149, 1093 and 1063 cm -1 in nickelboussingaultite spectra were attributed to the ν3(SO 42-) antisymmetric stretching vibration. The splitting of the ν4(SO 42-) bending vibration produced bands at 625 and 615 cm -1 in the boussingaultite spectra and 652, 624 and 602 cm -1 in the nickelboussingaultite spectra. Similarly, in the case of the ν2(SO 4) bending vibration, the bands were observed at 454 cm -1 in the boussingaultite spectra and 482, 457 and 440 cm -1 in the nickelboussingaultite spectra. The splitting of bands is the result of lowered symmetry of sulphate ions and possibly a result of substitution of Mg ions by Ni ions in nickelboussingaultite. The bands in the NH 4+ bending vibration region were observed at 1705 and 1678 cm -1 ( ν2), 1460 and 1438 cm -1 ( ν4) for the mineral boussingaultite. In the high wavenumber region the bands arising from the OH (bands above 3000 cm -1) and the NH 4+ (2940, 2918 and 2845 cm -1) stretching vibrations were identified.

  16. Far-Infrared Studies of Strongly Correlated Electron Systems

    NASA Astrophysics Data System (ADS)

    George, Anita

    1995-01-01

    Results of far-infrared and IR reflection measurements of Y_{1-x}Pr_ {x}Ba_2Cu _3O_{7-delta} , U_{1-x}Th _{x}NiSn and FeSi are presented. The experiments were performed over a spectral range of 10 -3000 cm^{-1} and a temperature range of 10-300 K using the technique of fast Fourier transform spectroscopy. The films of the Y_{1 -x}Pr_{x}Ba _2Cu_3O _{7-delta} series were grown using a laser ablation technique and included both superconducting and insulating samples. A number of phonon modes were identified in the reflectance spectrum of these compounds. The optical measurements did not show evidence of a BCS gap in the superconducting compounds but were consistent with the resistivity behavior of the samples. The results of the reflectance measurements on U_{1-x}Th_ {x}NiSn alloys are consistent with the semiconducting-to-metallic transition observed in these materials. Four phonon lines were observed in the reflectance spectra at all temperatures. In addition, a temperature and frequency dependent mode was observed at low frequencies. From the conductivity calculations a decrease in the oscillator strength was observed at low temperatures suggesting a partial destruction of the semiconducting gap. The reflectance measurements of FeSi were performed over the spectral range of 10-700 cm^{ -1}. The reflectance shows an unusual temperature dependence between 129 and 95 K, a range where the resistivity shows very little change. This suggests that a new phenomenon might be occurring in this temperature range. Two phonon modes were identified in the conductivity spectra at 200 and 325 cm^{-1}.

  17. Study of jamming of the frequency modulation infrared seekers

    NASA Astrophysics Data System (ADS)

    Qian, Fang; Guo, Jin; Shao, Jun-feng; Wang, Ting-feng

    2013-09-01

    The threat of the IR guidance missile is a direct consequence of extensive proliferation of the airborne IR countermeasure. The aim of a countermeasure system is to inject false information into a sensor system to create confusion. Many optical seekers have a single detector that is used to sense the position of its victim in its field of view. A seeker has a spinning reticle in the focal plane of the optical system that collects energy from the thermal scene and focuses it on to the detector. In this paper, the principle of the conical-scan FM reticle is analyzed. Then the effect that different amplitude or frequency modulated mid-infrared laser pulse acts on the reticle system is simulated. When the ratio of jamming energy to target radiation (repression) gradually increases, the azimuth error and the misalignment angle error become larger. The results show that simply increasing the intensity of the jamming light achieves little, but it increases the received signal strength of the FM reticle system ,so that the target will be more easily exposed. A slow variation of amplitude will warp the azimuth information received by the seeker, but the target can't be completely out of the missile tracking. If the repression and the jamming frequency change at the same time, the jamming effects can be more obvious. When the jamming signal's angular frequency is twice as large as the carrier frequency of the reticle system, the seeker will can't receive an accurate signal and the jamming can be achieved. The jamming mechanism of the conical-scan FM IR seeker is described and it is helpful to the airborne IR countermeasure system.

  18. Fiber-laser-based, green-pumped, picosecond optical parametric oscillator using fan-out grating PPKTP.

    PubMed

    Chaitanya Kumar, S; Parsa, S; Ebrahim-Zadeh, M

    2016-01-01

    We report a stable, Yb-fiber-laser-based, green-pumped, picosecond optical parametric oscillator (OPO) for the near-infrared based on periodically poled potassium titanyl phosphate (PPKTP) nonlinear crystal, using fan-out grating design and operating near room temperature. The OPO is continuously tunable across 726-955 nm in the signal and 1201-1998 nm in the idler, resulting in a total signal plus idler wavelength coverage of 1026 nm by grating tuning at a fixed temperature. The device generates up to 580 mW of average power in the signal at 765 nm and 300 mW in the idler at 1338 nm, with an overall extraction efficiency of up to 52% and a pump depletion >76%. The extracted signal at 765 nm and idler at 1746 nm exhibit excellent passive power stability better than 0.5% and 0.8% rms, respectively, over 1 h with good beam quality in TEM00 mode profile. The output signal pulses have a Gaussian temporal duration of 13.2 ps, with a FWHM spectral bandwidth of 3.4 nm at 79.5 MHz repetition rate. Power scaling limitations of the OPO due to the material properties of PPKTP are studied. PMID:26696156

  19. Multiplex picosecond coherent Stokes raman spectroscopy of pentacene doped in naphthalene

    NASA Astrophysics Data System (ADS)

    Chang, Ta-Chau; Liu, Tie-Yue; Wu, Hsing-Mei; Li, Hung-Wen

    1992-09-01

    We present a study of the multiplex picosecond CSRS experiments of the mixed crystals of pentacene doped in naphthalene. By this method we are able to measure vibrational decay times from different species simultaneously. The shorter decay time measured for the 1385 cm -1 mode of naphthalene while increasing the concentration of pentacene and tuning the pump frequency near the absorption transition may be interpreted by the model of impurity perturbed domains.

  20. Quantum-chemical and picosecond investigations of excited states of thioindigoid dyes

    SciTech Connect

    Fabian, Yu.; Krysanov, S.A.; Alfimov, M.V.

    1987-11-01

    The thioindigoid dyes are convenient objects for studying reverse trans-cis photoisomerization. This is due to the extensive use of nanosecond photolysis. In this work, in order to interpret some new absorption bands, the authors compare the results of quantum-chemical and picosecond investigations of solutions of the trans isomers of thioindigo and a perinaphthothioindigoid dye. A double-beam optical system, which makes it possible to record the kinetics of the variation of the induced absorption in the range from several picoseconds to 5 nsec, was used for the real-time scanning of the continuum instead of an echelon. The spectroscopic properties of the thioindigoid chromophore can be understood in the framework of standard calculations by the Pariser-Parr-Pople method.

  1. Amplification of picosecond pulses in a 140-GHz gyrotron-traveling wave tube.

    PubMed

    Kim, H J; Nanni, E A; Shapiro, M A; Sirigiri, J R; Woskov, P P; Temkin, R J

    2010-09-24

    An experimental study of picosecond pulse amplification in a gyrotron-traveling wave tube (gyro-TWT) has been carried out. The gyro-TWT operates with 30 dB of small signal gain near 140 GHz in the HE₀₆ mode of a confocal waveguide. Picosecond pulses show broadening and transit time delay due to two distinct effects: the frequency dependence of the group velocity near cutoff and gain narrowing by the finite gain bandwidth of 1.2 GHz. Experimental results taken over a wide range of parameters show good agreement with a theoretical model in the small signal gain regime. These results show that in order to limit the pulse broadening effect in gyrotron amplifiers, it is crucial to both choose an operating frequency at least several percent above the cutoff of the waveguide circuit and operate at the center of the gain spectrum with sufficient gain bandwidth. PMID:21230783

  2. Picosecond laser-induced breakdown at 5321 and 5347 A - Observation of frequency-dependent behavior

    NASA Technical Reports Server (NTRS)

    Smith, W. L.; Bechtel, J. H.; Bloembergen, N.

    1977-01-01

    A study is presented of picosecond laser-induced breakdown at 3547 and 5321 A of several materials. The thresholds obtained for breakdown at 5321 A are compared to previous results obtained at 1.064 microns using the same laser system. This comparison illustrates the transition of bulk laser-induced breakdown as it becomes increasingly frequency dependent. UV picosecond pulses are obtained by mixing 5321 A and 1.064 micron pulses in a KH2PO4 crystal. Upper and lower bounds on the 3547 A breakdown threshold are defined, although some effects of walk-off distortion and self-focusing are observed. The results are discussed with reference to models for the intrinsic processes involved in the breakdown, i.e., avalanche and multiphoton ionization.

  3. Amplification of Picosecond Pulses in a 140-GHz Gyrotron-Traveling Wave Tube

    PubMed Central

    Kim, H. J.; Nanni, E. A.; Shapiro, M. A.; Sirigiri, J. R.; Woskov, P. P.; Temkin, R. J.

    2011-01-01

    An experimental study of picosecond pulse amplification in a gyrotron-traveling wave tube (gyro-TWT) has been carried out. The gyro-TWT operates with 30 dB of small signal gain near 140 GHz in the HE06 mode of a confocal waveguide. Picosecond pulses show broadening and transit time delay due to two distinct effects: the frequency dependence of the group velocity near cutoff and gain narrowing by the finite gain bandwidth of 1.2 GHz. Experimental results taken over a wide range of parameters show good agreement with a theoretical model in the small signal gain regime. These results show that in order to limit the pulse broadening effect in gyrotron amplifiers, it is crucial to both choose an operating frequency at least several percent above the cutoff of the waveguide circuit and operate at the center of the gain spectrum with sufficient gain bandwidth. PMID:21230783

  4. Analyzing integrated circuits at work with a picosecond time-gated imager.

    PubMed

    Comelli, D; D'Andrea, C; Valentini, G; Cubeddu, R; Casiraghi, R; Cantarelli, D

    2005-12-12

    A system based on a picosecond time-gated image intensifier is proposed for non-contact testing of CMOS circuits. The apparatus allows one to record the temporal evolution of the luminescence emitted during transistor switching as a function of the position inside the chip. The system is characterized by an intrinsic parallelism in the spatial dimensions. This feature is noticeable for studying wide sections of complex circuits, like microprocessors and random access memories, where multiple electrical events occur simultaneously. Experiments on a CMOS inverter chain and on a static memory have been carried out, in order to demonstrate the applicability of a picosecond time-gated imager to circuit analysis. PMID:19503220

  5. Synthesis, characterization and infrared emissivity study of polyurethane/TiO 2 nanocomposites

    NASA Astrophysics Data System (ADS)

    Chen, Jing; Zhou, Yuming; Nan, Qiuli; Sun, Yanqing; Ye, Xiaoyun; Wang, Zhiqiang

    2007-09-01

    In this study, polyurethane/titania (PU/TiO 2) nanocomposites were prepared in ultrasonic process and characterized by fourier transform IR spectroscopy (FT-IR), powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and infrared emissivity analysis. The TEM and SEM results indicated that the nanoparticles were dispersed homogeneously in PU matrix on nanoscale. TGA-DSC confirmed that the heat stability of the composite was improved. Infrared emissivity study showed that the nanocomposite possessed lower emissivity value than those values of pure polymer and nanoparticles.

  6. Optically active substituted polyacetylene@carbon nanotube hybrids: Preparation, characterization and infrared emissivity property study

    SciTech Connect

    Bu, Xiaohai; Zhou, Yuming Zhang, Tao; Wang, Yongjuan; Zhang, Zewu; He, Man

    2014-08-15

    Optically active substituted polyacetylene@multiwalled carbon nanotubes (SPA@MWCNTs) nanohybrids were fabricated by wrapping helical SPA copolymers onto the surface of modified nanotubes through ester bonding linkage. SPA copolymer based on chiral phenylalanine and serine was pre-polymerized by a rhodium zwitterion catalyst in THF, and evidently proved to possess strong optical activity and adopt a predominately one-handed helical conformation. Various characterizations including Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and transmission electron microscopy (TEM) demonstrated that the SPA had been covalently grafted onto the nanotubes without destroying their original graphite structure. The wrapped SPA was found to exhibit an enhancement in thermal stability and still maintained considerable optical activity after grafting. The infrared emissivity property of the nanohybrids at 8–14 μm was investigated in addition. The results indicated that the SPA@MWCNTs hybrid matrix could possess a much lower infrared emissivity value (ε=0.707) than raw MWCNTs, which might be due to synergistic effect of the unique helical conformation of optically active SPA and strengthened interfacial interaction between the organic polymers and inorganic nanoparticles. - Graphical abstract: Optically active SPA@MWCNTs nanohybrids with low infrared emissivity. - Highlights: • Synthesis of optically active SPA copolymer derived from serine and phenylalanine. • Preparation and characterization of optically active SPA@MWCNTs nanohybrids. • Application study of the SPA@MWCNTs nanohybrids (ε=0.707) in lowering the infrared emissivity.

  7. Laser surface texturing of cast iron steel: dramatic edge burr reduction and high speed process optimisation for industrial production using DPSS picosecond lasers

    NASA Astrophysics Data System (ADS)

    Bruneel, David; Kearsley, Andrew; Karnakis, Dimitris

    2015-07-01

    In this work we present picosecond DPSS laser surface texturing optimisation of automotive grade cast iron steel. This application attracts great interest, particularly in the automotive industry, to reduce friction between moving piston parts in car engines, in order to decrease fuel consumption. This is accomplished by partially covering with swallow microgrooves the inner surface of a piston liner and is currently a production process adopting much longer pulse (microsecond) DPSS lasers. Lubricated interface conditions of moving parts require from the laser process to produce a very strictly controlled surface topography around the laser formed grooves, whose edge burr height must be lower than 100 nm. To achieve such a strict tolerance, laser machining of cast iron steel was investigated using an infrared DPSS picosecond laser (10ps duration) with an output power of 16W and a repetition rate of 200 kHz. The ultrashort laser is believed to provide a much better thermal management of the etching process. All studies presented here were performed on flat samples in ambient air but the process is transferrable to cylindrical geometry engine liners. We will show that reducing significantly the edge burr below an acceptable limit for lubricated engine production is possible using such lasers and remarkably the process window lies at very high irradiated fluences much higher that the single pulse ablation threshold. This detailed experimental work highlights the close relationship between the optimised laser irradiation conditions as well as the process strategy with the final size of the undesirable edge burrs. The optimised process conditions are compatible with an industrial production process and show the potential for removing extra post)processing steps (honing, etc) of cylinder liners on the manufacturing line saving time and cost.

  8. Comparative Study Using Different Infrared Zones of the Solventless Activation of Organic Reactions

    PubMed Central

    Córdova, María Olivia Noguez; Flores Ramírez, Carlos I.; Bejarano, Benjamín Velasco; Arroyo Razo, Gabriel A.; Pérez Flores, Francisco J.; Tellez, Vladimir Carranza; Ruvalcaba, René Miranda

    2011-01-01

    In this work, the results of a study comparing the use of irradiation from different regions of the infrared spectrum for the promotion of several organic reactions, are presented and discussed. This use of eco-conditions provides a green approach to chemical synthesis. A set of ten different organic reactions were evaluated, including the Knoevenagel, Hantzsch, Biginelli and Meldrum reactions. It is important to highlight the use of a commercial device that produces infrared irradiation in the near infrared region and its distribution by convection providing heating uniformity, significantly reducing reaction times, achieving good yields and proceeding in the absence of solvent. It is also worth noting that a variety of different reactions may be performed at the same time. Finally, the products obtained were identified using TLC, together with corresponding MS-data, complementarily in comparison of NMR 1H and 13C data with literature information. PMID:22272092

  9. An infrared study of the NGC 1977 H II region/molecular cloud interface

    NASA Technical Reports Server (NTRS)

    Makinen, P.; Harvey, P. M.; Wilking, B. A.; Evans, N. J., II

    1985-01-01

    The results of an infrared study of the H II region NGC 1977 and the adjacent dense molecular cloud are reported. Extensive far-infrared maps with 45 arcsec resolution allow the spatial structure of the dust temperature and optical depth variations across the ionization front to be delineated. Analysis of the dust energetics indicates that the only significant energy source is the B1 V star HD 37018 which ionizes the H II region. This result, together with a favorable geometry, provides a good opportunity to determine the ratio of ultraviolet absorption efficiency to far-infrared emission efficiency, 790 + 460 or - 180. Analysis of the gas energetics indicates that collisions with warm dust grains can explain the observed gas temperatures.

  10. Tree Canopy Characterization for EO-1 Reflective and Thermal Infrared Validation Studies: Rochester, New York

    NASA Technical Reports Server (NTRS)

    Ballard, Jerrell R., Jr.; Smith, James A.

    2002-01-01

    The tree canopy characterization presented herein provided ground and tree canopy data for different types of tree canopies in support of EO-1 reflective and thermal infrared validation studies. These characterization efforts during August and September of 2001 included stem and trunk location surveys, tree structure geometry measurements, meteorology, and leaf area index (LAI) measurements. Measurements were also collected on thermal and reflective spectral properties of leaves, tree bark, leaf litter, soil, and grass. The data presented in this report were used to generate synthetic reflective and thermal infrared scenes and images that were used for the EO-1 Validation Program. The data also were used to evaluate whether the EO-1 ALI reflective channels can be combined with the Landsat-7 ETM+ thermal infrared channel to estimate canopy temperature, and also test the effects of separating the thermal and reflective measurements in time resulting from satellite formation flying.

  11. POLARIZED RADIO SOURCES: A STUDY OF LUMINOSITY, REDSHIFT, AND INFRARED COLORS

    SciTech Connect

    Banfield, Julie K.; George, Samuel J.; Taylor, A. Russ; Stil, Jeroen M.; Kothes, Roland; Scott, Douglas

    2011-05-20

    The Dominion Radio Astrophysical Observatory Deep Field polarization study has been matched with the Spitzer Wide-Area Infrared Extragalactic Survey of the European Large Area Infrared Space Observatory Survey North 1 field. We have used Very Large Array observations with a total intensity rms of 87 {mu}Jy beam{sup -1} to match SWIRE counterparts to the radio sources. Infrared color analysis of our radio sample shows that the majority of polarized sources are elliptical galaxies with an embedded active galactic nucleus. Using available redshift catalogs, we found 429 radio sources of which 69 are polarized with redshifts in the range of 0.04 < z < 3.2. We find no correlation between redshift and percentage polarization for our sample. However, for polarized radio sources, we find a weak correlation between increasing percentage polarization and decreasing luminosity.

  12. Analytical estimation of solid angle subtended by complex well-resolved surfaces for infrared detection studies.

    PubMed

    Mahulikar, Shripad P; Potnuru, Santosh K; Kolhe, Pankaj S

    2007-08-01

    The solid angle (Omega) subtended by the hot power-plant surfaces of a typical fighter aircraft, on the detector of an infrared (IR) guided missile, is analytically obtained. The use of the parallel rays projection method simplifies the incorporation of the effect of the optical blocking by engine surfaces, on Omega-subtended. This methodology enables the evaluation of the relative contribution of the IR signature from well-resolved distributed sources, and is important for imaging infrared detection studies. The complex 3D surface of a rear fuselage is projected onto an equivalent planar area normal to the viewing aspect, which would give the same Omega-subtended. PMID:17676106

  13. Lattice dynamical study of Raman and infrared modes in Mg2SiO4

    NASA Astrophysics Data System (ADS)

    Kaur, Harleen; Jindal, Ruby; Sinha, M. M.

    2016-05-01

    Vibrational studies on Raman and infrared active phonons in orthorhombic phase for Mg2SiO4 have been made by applying a short range force constant model. The lattice dynamical calculations were carried out by Wilson's GF matrix method by normal coordinate analysis of Mg2SiO4 having space group Pbnm in orthorhombic phase. The calculations have been made with fifteen stretching and eleven bending force constants. The calculated values of Raman and infrared phonons are in good agreement with the experimental results. The contribution of each force constant towards the zone centre phonons has been determined in terms of potential energy distribution.

  14. Headspace analysis gas-phase infrared spectroscopy: a study of xanthate decomposition on mineral surfaces

    NASA Astrophysics Data System (ADS)

    Vreugdenhil, Andrew J.; Brienne, Stephane H. R.; Markwell, Ross D.; Butler, Ian S.; Finch, James A.

    1997-03-01

    The O-ethyldithiocarbonate (ethyl xanthate, CH 3CH 2OCS -2) anion is a widely used reagent in mineral processing for the separation of sulphide minerals by froth flotation. Ethyl xanthate interacts with mineral powders to produce a hydrophobic layer on the mineral surface. A novel infrared technique, headspace analysis gas-phase infrared spectroscopy (HAGIS) has been used to study the in situ thermal decomposition products of ethyl xanthate on mineral surfaces. These products include CS 2, COS, CO 2, CH 4, SO 2, and higher molecular weight alkyl-containing species. Decomposition pathways have been proposed with some information determined from 2H- and 13C-isotope labelling experiments.

  15. Detection of nonlinear picosecond acoustic pulses by time-resolved Brillouin scattering

    SciTech Connect

    Gusev, Vitalyi E.

    2014-08-14

    In time-resolved Brillouin scattering (also called picosecond ultrasonic interferometry), the time evolution of the spatial Fourier component of an optically excited acoustic strain distribution is monitored. The wave number is determined by the momentum conservation in photon-phonon interaction. For linear acoustic waves propagating in a homogeneous medium, the detected time-domain signal of the optical probe transient reflectivity shows a sinusoidal oscillation at a constant frequency known as the Brillouin frequency. This oscillation is a result of heterodyning the constant reflection from the sample surface with the Brillouin-scattered field. Here, we present an analytical theory for the nonlinear reshaping of a propagating, finite amplitude picosecond acoustic pulse, which results in a time-dependence of the observed frequency. In particular, we examine the conditions under which this information can be used to study the time-evolution of the weak-shock front speed. Depending on the initial strain pulse parameters and the time interval of its nonlinear transformation, our theory predicts the detected frequency to either be monotonically decreasing or oscillating in time. We support these theoretical predictions by comparison with available experimental data. In general, we find that picosecond ultrasonic interferometry of nonlinear acoustic pulses provides access to the nonlinear acoustic properties of a medium spanning most of the GHz frequency range.

  16. GRANULAR ACTIVATED CARBON ADSORPTION AND INFRARED REACTIVATION: A CASE STUDY

    EPA Science Inventory

    A study evaluated the effectiveness and cost of removing trace organic contaminants and surrogates from drinking water by granular activated carbon (GAC) adsorption. The effect of multiple reactivations of spent GAC was also evaluated. Results indicated that reactivated GAC eff...

  17. A feasibility study: California Department of Forestry and Fire Protection utilization of infrared technologies for wildland fire suppression and management

    NASA Technical Reports Server (NTRS)

    Nichols, J. D.; Britten, R. A.; Parks, G. S.; Voss, J. M.

    1990-01-01

    NASA's JPL has completed a feasibility study using infrared technologies for wildland fire suppression and management. The study surveyed user needs, examined available technologies, matched the user needs with technologies, and defined an integrated infrared wildland fire mapping concept system configuration. System component trade-offs were presented for evaluation in the concept system configuration. The economic benefits of using infrared technologies in fire suppression and management were examined. Follow-on concept system configuration development and implementation were proposed.

  18. Fabrication of broadband antireflective black metal surfaces with ultra-light-trapping structures by picosecond laser texturing and chemical fluorination

    NASA Astrophysics Data System (ADS)

    Zheng, Buxiang; Wang, Wenjun; Jiang, Gedong; Mei, Xuesong

    2016-06-01

    A hybrid method consisting of ultrafast laser-assisted texturing and chemical fluorination treatment was applied for efficiently enhancing the surface broadband antireflection to fabricate black titanium alloy surface with ultra-light-trapping micro-nanostructure. Based on the theoretical analysis of surface antireflective principle of micro-nanostructures and fluoride film, the ultra-light-trapping micro-nanostructures have been processed using a picosecond pulsed ultrafast laser on titanium alloy surfaces. Then fluorination treatment has been performed by using fluoroalkyl silane solution. According to X-ray diffraction phase analysis of the surface compositions and measurement of the surface reflectance using spectrophotometer, the broadband antireflective properties of titanium alloy surface with micro-nano structural characteristics were investigated before and after fluorination treatment. The results show that the surface morphology of micro-nanostructures processed by picosecond laser has significant effects on the antireflection of light waves to reduce the surface reflectance, which can be further reduced using chemical fluorination treatment. The high antireflection of over 98 % in a broad spectral range from ultraviolet to infrared on the surface of metal material has been achieved for the surface structures, and the broadband antireflective black metal surfaces with an extremely low reflectance of ultra-light-trapping structures have been obtained in the wavelength range from ultraviolet-visible to near-infrared, middle-wave infrared. The average reflectance of microgroove groups structured surface reaches as low as 2.43 % over a broad wavelength range from 200 to 2600 nm. It indicates that the hybrid method comprising of picosecond laser texturing and chemical fluorination can effectively induce the broadband antireflective black metal surface. This method has a potential application for fabricating antireflective surface used to improve the

  19. The Laser-assisted photoelectric effect of He, Ne, Ar and Xe in intense extreme ultraviolet and infrared laser fields

    NASA Astrophysics Data System (ADS)

    Hayden, P.; Dardis, J.; Hough, P.; Richardson, V.; Kennedy, E. T.; Costello, J. T.; Düsterer, S.; Redlin, H.; Feldhaus, J.; Li, W. B.; Cubaynes, D.; Meyer, M.

    2016-02-01

    In this paper, we report results on two-colour above-threshold ionisation, where extreme ultraviolet pulses of femtosecond duration were synchronised to intense infrared laser pulses of picosecond duration, in order to study the laser-assisted photoelectric effect of atomic helium, neon, krypton and xenon which leads to the appearance of characteristic sidebands in the photoelectron spectra. The observed trends are found to be well described by a simple model based on the soft-photon approximation, at least for the relatively low optical intensities of up to ? employed in these early experiments.

  20. FDTD/TDSE study of surface-enhanced infrared absorption by metal nanoparticles.

    SciTech Connect

    Chang, S.-H.; Schatz, G. C.; Gray, S. K.; Chemistry; Northwestern Univ.; National Cheng-Kung Univ.

    2006-01-01

    We study surface-enhanced infrared absorption, including multiphoton processes, due to the excitation of surface plasmons on metal nanoparticles. The time-dependent Schroedinger equation and finite-difference time-domain method are self-consistently coupled to treat the problem.

  1. Do Infants Recognize the Arcimboldo Images as Faces? Behavioral and Near-Infrared Spectroscopic Study

    ERIC Educational Resources Information Center

    Kobayashi, Megumi; Otsuka, Yumiko; Nakato, Emi; Kanazawa, So; Yamaguchi, Masami K.; Kakigi, Ryusuke

    2012-01-01

    Arcimboldo images induce the perception of faces when shown upright despite the fact that only nonfacial objects such as vegetables and fruits are painted. In the current study, we examined whether infants recognize a face in the Arcimboldo images by using the preferential looking technique and near-infrared spectroscopy (NIRS). In the first…

  2. Infrared study of N-butylbenzamide - aromatic donor systems

    NASA Astrophysics Data System (ADS)

    Nikolić, A. D.; Perišić-Janjić, N.; Kobilarov, N. L.; Petrović, S. D.

    1984-03-01

    This paper is a part of an extensive study devoted to the behaviour of N-substituted amides in solutions (ref.1,2). N-n-butylbenzamide (NnBBA), N-iso-butylbenzamide (NiBBA) and N-tert-butylbenzamide (NtBBA) have been studied in CCl 4 - aromatic hydrocarbon (benzene and toluene) solutions by means of IR spectra, using NH fundamental stretching vibration region. Also, NtBBA systems have been examined by UV spectroscopy. On the other hand, NnBBA systems were subjected to gas chromatographic measurements. 1:1 hydrogen bonded complex formation between amide and the aromatic hydrocarbons is considered on the basis of the obtained results.

  3. Alignment and Polarization Sensitivity Study for the Cassini-Composite InfraRed Spectrometer (CIRS) Far InfraRed (FIR) Interferometer

    NASA Technical Reports Server (NTRS)

    Crooke, Julie A.; Hagopian, John G.

    1998-01-01

    The Composite InfraRed Spectrometer (CIRS) instrument flying on the Cassini spacecraft to Saturn is a cryogenic spectrometer with far-infrared (FIR) and mid-infrared (MIR) channels. The CIRS FIR channel is a polarizing interferometer that contains three polarizing grid components. These components are an input polarizer, a polarizing beamsplitter, and an output polarizer/analyzer. They consist of a 1.5 micron thick mylar substrate with 2 gm wide copper wires, with 2 gm spacing (4 micron pitch) photolithographically deposited on the substrate. This paper details the polarization sensitivity studies performed on the output polarizer/analyzer, and the alignment sensitivity studies performed on the input polarizer and beamsplitter components in the FIR interferometer.

  4. Numerical study on the influence of aluminum on infrared radiation signature of exhaust plume

    NASA Astrophysics Data System (ADS)

    Zhang, Wei; Ye, Qing-qing; Li, Shi-peng; Wang, Ning-fei

    2013-09-01

    The infrared radiation signature of exhaust plume from solid propellant rockets has been widely mentioned for its important realistic meaning. The content of aluminum powder in the propellants is a key factor that affects the infrared radiation signature of the plume. The related studies are mostly on the conical nozzles. In this paper, the influence of aluminum on the flow field of plume, temperature distribution, and the infrared radiation characteristics were numerically studied with an object of 3D quadrate nozzle. Firstly, the gas phase flow field and gas-solid multi phase flow filed of the exhaust plume were calculated using CFD method. The result indicates that the Al203 particles have significant effect on the flow field of plume. Secondly, the radiation transfer equation was solved by using a discrete coordinate method. The spectral radiation intensity from 1000-2400 cm-1 was obtained. To study the infrared radiation characteristics of exhaust plume, an exceptional quadrate nozzle was employed and much attention was paid to the influences of Al203 particles in solid propellants. The results could dedicate the design of the divert control motor in such hypervelocity interceptors or missiles, or be of certain meaning to the improvement of ingredients of solid propellants.

  5. Advanced far infrared detector and double donor studies in Ge

    SciTech Connect

    Olsen, C.S.

    1994-12-01

    This has application to astronomy and astrophysics. Selenium in Ge has been studied with a doping technique which limits complex formation. Only one ionization level has been found to correspond to selenium, which presumably occupies a substitutional site. This level is extremely unstable and its concentration decreases after annealing at 400C. Future work is planned to anneal the fast neutron damage before much selenium has formed in the {sup 74/76}Ge samples. It is expected that the observed selenium level can be better characterized and the missing selenium level is more likely to be discovered if other defects are removed before {sup 77}Se formation.

  6. Shuttle infrared telescope facility (SIRTF) preliminary design study

    NASA Technical Reports Server (NTRS)

    1976-01-01

    An overall picture of the SIRTF system is first presented, including the telescope, focal plane instruments, cryogen supply, shuttle and spacelab support subsystems, mechanical and data interfaces with the vehicles, ground support equipment, and system requirements. The optical, mechanical, and thermal characteristics of the telescope are then evaluated, followed by a description of the SIRTF internal stabilization subsystem and its interface with the IPS. Expected performance in the shuttle environment is considered. Tradeoff studies are described, including the Gregorian versus the Cassegrain telescope, aperture diameter tradeoff, a CCD versus an image dissector for the star tracker, the large ambient telescope versus the SIRTF, and a dedicated gimbal versus the IPS. Operations from integration through launch and recovery are also discussed and cost estimates for the program are presented.

  7. Time-resolved infrared studies of protein conformational dynamics

    SciTech Connect

    Woodruff, W.H.; Causgrove, T.P.; Dyer, R.B.; Callender, R.H.

    1994-12-01

    We have demonstrated that TRIR in the amide I region gives structural information regarding protein conformational changes in realtime, both on processes involved in the development of the functional structure (protein folding) and on protein structural changes that accompany the functional dynamics of the native structure. Assignment of many of the amide I peaks to specific amide or sidechain structures will require much additional effort. Specifically, the congestion and complexity of the protein vibrational spectra dictate that isotope studies are an absolute requirement for more than a qualitative notion of the structural interpretation of these measurements. It is clear, however, that enormous potential exists for elucidating structural relaxation dynamics and energetics with a high degree of structural specificity using this approach.

  8. Conformational isomerism of pyridoxal. Infrared matrix isolation and theoretical studies

    NASA Astrophysics Data System (ADS)

    Kwiatek, Anna; Mielke, Zofia

    2015-01-01

    A combined matrix isolation FTIR and theoretical DFT/B3LYP/6-311++G(2p,2d) study of pyridoxal was performed. The calculations resulted in five stable PLHB conformers stabilized by intramolecular Osbnd H⋯O bonding between phenolic OH and carbonyl Cdbnd O groups and another thirteen conformers in which OH or/and aldehyde groups are rotated by 180° around CO or/and CC bonds leading, respectively, to formation of PLO, PLA and PLOA conformers. The analysis of the spectra of the as-deposited matrix indicated that two most stable PLHB1 and PLHB2 conformers with intramolecular hydrogen bond are present in the matrix. The exposure of the PL/Ar matrix to mercury lamp radiation (λ > 345 nm) induced conformational change of PLHB isomers to PLOA ones.

  9. Infrared laser heating for studies of cellulose degradation

    SciTech Connect

    Jackson, J.P.; Arthurs, E.; Schwalbe, L.A.; Sega, R.M.; Windish, D.; Long, W.H.; Stappaerts, E.A.

    1988-09-15

    We describe a new technique for studying thermally induced chemical transformations in cellulose. The apparatus consists of a carbon dioxide laser for heating, an IR thermometer, and an optical reflectance spectrometer for tracking the progressive discoloration of the sample. To illustrate the technique, we present measurements from a single piece of sample linen along five isotherms in the 200--290/sup 0/C range. We derive an algebraic expression for the reflectivity of the sample as a function of the areal concentrations of the chromophoric states produced at temperature. The results are then explained in terms of first-order chemical rate theory and a four-step model. From the measurements we derive the activation energies, Arrhenius constants, and reflectivities of the chromophoric states.

  10. Conformational isomerism of pyridoxal. Infrared matrix isolation and theoretical studies.

    PubMed

    Kwiatek, Anna; Mielke, Zofia

    2015-01-25

    A combined matrix isolation FTIR and theoretical DFT/B3LYP/6-311++G(2p,2d) study of pyridoxal was performed. The calculations resulted in five stable PLHB conformers stabilized by intramolecular O-H⋯O bonding between phenolic OH and carbonyl C=O groups and another thirteen conformers in which OH or/and aldehyde groups are rotated by 180° around CO or/and CC bonds leading, respectively, to formation of PLO, PLA and PLOA conformers. The analysis of the spectra of the as-deposited matrix indicated that two most stable PLHB1 and PLHB2 conformers with intramolecular hydrogen bond are present in the matrix. The exposure of the PL/Ar matrix to mercury lamp radiation (λ>345 nm) induced conformational change of PLHB isomers to PLOA ones. PMID:25173527

  11. Mariner Jupiter/Saturn 1977 infrared interferometer spectrometer (MJS' 77) design study

    NASA Technical Reports Server (NTRS)

    1974-01-01

    A design study of the Infrared Interferometer Spectrometer and Radiometer (IRIS) instrument for the Mariner Jupiter/Saturn 1977 mission was conducted. The objective of the study was to investigate a number a potential problem areas identified in previous studies and to develop the instrument system designs along the lines providing for the optimum performance obtainable with the allowable budgets. The considerations for the optical design, mechanical design, and electronic design are examined.

  12. Studying soil properties using visible and near infrared spectral analysis

    NASA Astrophysics Data System (ADS)

    Moretti, S.; Garfagnoli, F.; Innocenti, L.; Chiarantini, L.

    2009-04-01

    This research is carried out inside the DIGISOIL Project, whose purposes are the integration and improvement of in situ and proximal measurement technologies, for the assessment of soil properties and soil degradation indicators, going form the sensing technologies to their integration and their application in digital soil mapping. The study area is located in the Virginio river basin, about 30 km south of Firenze, in the Chianti area, where soils with agricultural suitability have a high economic value connected to the production of internationally famous wines and olive oils. The most common soil threats, such as erosion and landslide, may determine huge economic losses, which must be considered in farming management practices. This basin has a length of about 23 km for a basin area of around 60,3 Km2. Geological formations outcropping in the area are Pliocene to Pleistocene marine and lacustrine sediments in beds with almost horizontal bedding. Vineyards, olive groves and annual crops are the main types of land use. A typical Mediterranean climate prevails with a dry summer followed by intense and sometimes prolonged rainfall in autumn, decreasing in winter. In this study, three types of VNIR and SWIR techniques, operating at different scales and in different environments (laboratory spectroscopy, portable field spectroscopy) are integrated to rapidly quantify various soil characteristics, in order to acquire data for assessing the risk of occurrence for typically agricultural practice-related soil threats (swelling, compaction, erosion, landslides, organic matter decline, ect.) and to collect ground data in order to build up a spectral library to be used in image analysis from air-borne and satellite sensors. Difficulties encountered in imaging spectroscopy, such as influence of measurements conditions, atmospheric attenuation, scene dependency and sampling representation are investigated and mathematical pre-treatments, using proper algorithms, are applied and

  13. Far infrared, near infrared, and radio molecular line studies of HFE 2, HFE 3, and FJM 6

    NASA Technical Reports Server (NTRS)

    Fischer, J.; Cassar, L.; Righini-Cohen, G.; Simon, M.

    1979-01-01

    Far-infrared, near-infrared, and radio molecular-line observations of the regions of HFE 2, HFE 3, and FJM 6 are described. At positions of high molecular column density nearest to the reported positions of these sources, their infrared emission cannot be confirmed at upper bounds below those of the original detection. Near-infrared observations of the FJM 6 region (which includes the Bok globule Barnard 361) reveal a number of stellar sources, most of which are behind the molecular cloud and are reddened by it. Visual extinction through B 361 estimated by star counts yields A sub V/N(/C-13/O) = 3.7 + or - 1.6) x 10 to the -16th mag sq cm. The gas temperature and the upper bound on the dust temperature in the FJM 6 region are consistent with cosmic-ray heating of the cloud, while the values of these parameters for the clouds in the HFE 2 and HFE 3 regions do not appear consistent with either cosmic-ray or radiative heating.

  14. A study of the large-scale infrared emission from a selected dark cloud

    NASA Technical Reports Server (NTRS)

    Young, Erick T.

    1993-01-01

    An investigation of the infrared emission energetics and embedded population in the rho Ophiuchi dark cloud is summarized. With a distance of approximately 140 pc, the rho Ophiuchi cloud is one of the closest regions of recent star formation. It is also one of the best studied such regions with numerous observations at all wavelengths. The Infrared Astronomy Satellite (IRAS) data of the cloud provided a new glimpse of the overall structure of the cloud. In particular, the interaction of radiation from the Sco-Oph OB Association on the external heating of the cloud was very evident on Skyflux and Survey CO-Add images produced by IRAS. The infrared survey also revealed a number of new embedded sources in the cloud which have subsequently been observed from the ground. In earlier study, the overall energies of the cloud using the IRAS data was explored. The main conclusions of that work were: (1) the overall luminosity of the cloud is well explained by the emission of the known B-stars, HD 147889, SR-3, and S1, along with a 15 percent contribution from the external radiation field; (2) the dust physical temperatures were significantly lower than the observed CO gas temperatures; and (3) dust grains are heated to only 10 percent to 20 percent of the total depth into the cloud. This analysis was extended by drawing on data from large-scale CO maps of Loren (1989) and from near-infrared surveys of the embedded population.

  15. An HST surface photometric study of ultraluminous infrared galaxies

    NASA Astrophysics Data System (ADS)

    Zheng, Z.; Wu, H.; Mao, S.; Xia, X.-Y.; Deng, Z.-G.; Zou, Z.-L.

    1999-09-01

    We study the surface photometry for 13 single-nucleus ultraluminous IRAS galaxies (ULIRGs), selected from a parent sample of 58 galaxies obtained in a Hubble Space Telescope I-band snapshot survey. These galaxies can be classified into two classes using a quantitative chi (2) criterion based on whether their surface brightness profiles are well fitted by the R(1) / 4 law. The surface brightness profiles of all four galaxies in the first class are well fitted by the R(1) / 4 law. Their isophotes are all disky at R <~ 1 h(-1) kpc, consistent with the molecular disks/rings found in nearby ULIRGs from CO observations. For the nine class II objects, their surface brightness profiles are less well fitted by the R(1) / 4 law. Qualitatively, the class II objects can be further divided into two sub-classes (IIa and IIb) based on their photometric behaviors. The four galaxies in class IIa have a bright nucleus, an inner R(1) / 4 component and an outer extension. Remarkably all these four galaxies are Seyfert 1 galaxies with luminosities in the quasar regime and with relatively narrow permitted and strong FeII emission lines. The remaining five galaxies in Class IIb have surface brightness profiles deviating to various degrees from the R(1) / 4 law, including one galaxy that is well fitted by an exponential law. In contrast to class IIa, spectral classifications of galaxies in class IIb are mostly HII regions or LINERs. We also present new spectroscopic observations for some of these galaxies. We establish the redshift of IR 09427+1929 to be 0.284, instead of 0.149 as adopted in the literature. Our analyzes support the idea that mergings of disk galaxies produce elliptical or S0 galaxies. These observations also suggest that the formation of QSOs may be an integral part of elliptical galaxy formation (at low redshifts). This research was based on observations obtained with the NASA/ESA Hubble Space Telescope through the Space Telescope Science Institute, which is operated by

  16. Transmission of holographic 3D images using infrared transmitter(II): on a study of transmission of holographic 3D images using infrared transmitter safe to medical equipment

    NASA Astrophysics Data System (ADS)

    Takano, Kunihiko; Muto, Kenji; Tian, Lan; Sato, Koki

    2007-09-01

    An infrared transmitting technique for 3D holographic images is studied. It seems to be very effective as a transmitting technique for 3D holographic images in the places where electric wave is prohibited to be used for transmission. In this paper, we first explain our infrared transmitting system for holograms and a display system for the presentation of holographic 3D images reconstructed from the received signal. Next, we make a report on the results obtained by infrared transmission of CGH and a comparison of the real and the reconstructed 3D images in our system. As this result, it is found that reconstructed holographic 3D images do not suffer a large deterioration in the quality and highly contrasted ones can be presented.

  17. High power industrial picosecond laser from IR to UV

    NASA Astrophysics Data System (ADS)

    Saby, Julien; Sangla, Damien; Pierrot, Simonette; Deslandes, Pierre; Salin, François

    2013-02-01

    Many industrial applications such as glass cutting, ceramic micro-machining or photovoltaic processes require high average and high peak power Picosecond pulses. The main limitation for the expansion of the picosecond market is the cost of high power picosecond laser sources, which is due to the complexity of the architecture used for picosecond pulse amplification, and the difficulty to keep an excellent beam quality at high average power. Amplification with fibers is a good technology to achieve high power in picosecond regime but, because of its tight confinement over long distances, light undergoes dramatic non linearities while propagating in fibers. One way to avoid strong non linearities is to increase fiber's mode area. Nineteen missing holes fibers offering core diameter larger than 80μm have been used over the past few years [1-3] but it has been shown that mode instabilities occur at approximately 100W average output power in these fibers [4]. Recently a new fiber design has been introduced, in which HOMs are delocalized from the core to the clad, preventing from HOMs amplification [5]. In these so-called Large Pitch Fibers, threshold for mode instabilities is increased to 294W offering robust single-mode operation below this power level [6]. We have demonstrated a high power-high efficiency industrial picosecond source using single-mode Large Pitch rod-type fibers doped with Ytterbium. Large Pitch Rod type fibers can offer a unique combination of single-mode output with a very large mode area from 40 μm up to 100μm and very high gain. This enables to directly amplify a low power-low energy Mode Locked Fiber laser with a simple amplification architecture, achieving very high power together with singlemode output independent of power level or repetition rate.

  18. Deuteration Effect Study on the Vibrational Dynamics of Phenol and Phenol-Water Complex by Picosecond Time-Resolved Ir-Uv Pump-Probe Spectroscopy in a Supersonic Molecular Beam

    NASA Astrophysics Data System (ADS)

    Miyazaki, Yasunori; Inokuchi, Yoshiya; Ebata, Takayuki

    2012-06-01

    The vibrational energy relaxations of the OH and OD stretch of phenol-d_0 and phenol-d_0-(H_2O) complex and phenol-d_1 and phenol-d_1-(D_2O) complex, respectively, are investigated by picosecond IR-UV pump-probe spectroscopy. The key to understand their dynamic is well-suited to a two-step Tier model. For phenol-d_0, an energy flow is described by the intramolecularVR steps: "OH stretching level" → "doorway state" → "bath state". The intramolecularVR lifetime of phenol-d_0 is obtained to be 14 ps. On the other hand, the OD stretching vibration of phenol-d_1 exhibits quantum beats, followed by the intramolecularVR with a lifetime of 90 ps. In contrast, for the phenol-water complex, the intramolecularVR lifetime of OH(OD) stretch becomes 4.3 ps(12 ps) and an energy flow is described by the intramolecular and intermolecular processes, which lead to VP (vibratinal predisocciation). Although the energy difference is 1000 cm-1, no remarkable change of intermolecularVR and VP lifetimes is found in the hydrogen-bonded phenol-water complexes.

  19. An All-Optical Picosecond Switch in Polydiacetylene

    NASA Technical Reports Server (NTRS)

    Abdeldayem, Hossin; Frazier, Donald O.; Paley, Mark S.

    2002-01-01

    Polydiacetylene derivative of 2-methyl-4-nitroaniline (PDAMNA) showed a picosecond switching property. This phenomenon was demonstrated by wave guiding a cw He-Ne laser collinearly with a mode-locked picosecond Nd:YAG laser at 532 nm through a hollow fiber coated on the inside with a thin film of PDAMNA. The z-scan investigations of PDAMNA thin film revealed that the PDAMNA system is a three level system and the switching is caused by excited state absorption of the He-Ne beam.

  20. Synchronization of sub-picosecond electron and laser pulses

    SciTech Connect

    Rosenzweig, J. B.; Le Sage, G. P.

    1999-07-12

    Sub-picosecond laser-electron synchronization is required to take full advantage of the experimental possibilities arising from the marriage of modern high intensity lasers and high brightness electron beams in the same laboratory. Two particular scenarios stand out in this regard, injection of ultra-short electron pulses in short wavelength laser-driven plasma accelerators, and Compton scattering of laser photons from short electron pulses. Both of these applications demand synchronization, which is sub-picosecond, with tens of femtosecond synchronization implied for next generation experiments. The design of a microwave timing modulator system is now being investigated in more detail.

  1. Synchronization of sub-picosecond electron and laser pulses

    SciTech Connect

    Rosenzweig, J.B.; Le Sage, G.P.

    1999-07-01

    Sub-picosecond laser-electron synchronization is required to take full advantage of the experimental possibilities arising from the marriage of modern high intensity lasers and high brightness electron beams in the same laboratory. Two particular scenarios stand out in this regard, injection of ultra-short electron pulses in short wavelength laser-driven plasma accelerators, and Compton scattering of laser photons from short electron pulses. Both of these applications demand synchronization, which is sub-picosecond, with tens of femtosecond synchronization implied for next generation experiments. The design of a microwave timing modulator system is now being investigated in more detail. (AIP) {copyright} {ital 1999 American Institute of Physics.}

  2. Picosecond intersubband hole relaxation in p-type quantum wells

    SciTech Connect

    Xu, Z.; Fauchet, P.M.; Rella, C.W.; Schwettman, H.A.

    1995-12-31

    We report the first direct measurement of the relaxation time of holes in p-type quantum wells using tunable, subpicosecond mid-infrared laser pulses in a pump-probe arrangement. The QW layers consisted of 50 In{sub 0.5}Ga{sub 0.5}As/Al{sub 0.5}Ga{sub 0.5}As periods. The In{sub 0.5}Ga{sub 0.5}As well was 4 nm wide and the Al{sub 0.5}Ga{sub 0.5}As barrier was 8 nm wide. The dopant concentration was 10{sup 19} CM{sup -3} which corresponds to a sheet density of 1.2 x 10{sup 13} CM{sup -2}. The room temperature IR spectrum showed a 50 meV wide absorption peak at 5.25 {mu}m (220 meV). This energy agrees with the calculated n=1 heavy hole to n=1 light hole transition energy of 240 meV (150 meV for strain and 90 meV for confinement). The large absorption width results from hole-hole scattering and the difference in dispersion relations between the two subbands. The equal-wavelength pump-probe transmission measurements were performed using the Stanford free electron laser (FEL). The FEL pulses were tuned between 4 and 6 {mu} m and their duration was less than 1 ps. The measurements were performed as a function of temperature, pump wavelength and intensity (from 0.3 to 10 GW/cm{sup 2}). In all our experiments, we find an increase of transmission (decrease of absorption or bleaching) following photopumping, which recovers as a single exponential with a time constant (relaxation time) of the order of 1 picosecond. The maximum change in transmission is linear with pump 2 intensity below 1 GW/cm{sup 2} and saturates to {approximately}3% with a saturation intensity I{sub sat} of 3 GW/cm{sup 2}. As the saturation regime is entered, the relaxation time increases from 0.8 ps to 1.8 ps. This relaxation time depends on the temperature T: it increases from 0.8 ps to 1.3 ps as T decreases from 300 K to 77 K. Finally, when we tune the laser through the absorption band, the magnitude of the signal changes but its temporal behavior does not change, within the accuracy of the measurements.

  3. [Study on estimation of deserts soil total phosphorus content from thermal-infrared emissivity].

    PubMed

    Hou, Yan-jun; Tiyip, Tashpolat; Zhang, Fei; Sawut, Mamat; Nurmemet, Ilyas

    2015-02-01

    Soil phosphorus provides nutrient elements for plants, is one of important parameters for evaluating soil quality. The traditional method for soil total phosphorus content (STPC) measurement is not effective and time-consuming. However, remote sensing (RS) enables us to determine STPC in a fast and efficient way. Studies on the estimation of STPC in near-infrared spectroscopy have been developed by scholars, but model accuracy is still poor due to the low absorption coefficient and unclear absorption peak of soil phosphorus in near-infrared. In order to solve the deficiency which thermal-infrared emissivity estimate desert soil total phosphorus content, and could improve precision of estimation deserts soil total phosphorus. In this paper, characteristics of soil thermal-infrared emissivity are analyzed on the basis of laboratory processing and spectral measurement of deserts soil samples from the eastern Junggar Basin. Furthermore, thermal-infrared emissivity based RS models for STPC estimation are established and accuracy assessed. Results show that: when STPC is higher than 0.200 g x kg(-1), the thermal-infrared emissivity increases with the increase of STPC on the wavelength between 8.00 microm and 13 microm, and the emissivity is more sensitive to STPC on the wavelength between 9.00 and 9.6 microm; the estimate mode based on multiple stepwise regression was could not to estimate deserts soil total phosphorus content from thermal-infrared emissivity because the estimation effects of them were poor. The estimation accuracy of model based on partial least squares regression is higher than the model based on multiple stepwise regression. However, the accuracy of second-order differential estimation model based on partial least square regression is higher than based on multiple stepwise regression; The first differential of continuous remove estimation model based on partial least squares regression is the best model with R2 of correction and verification are up to

  4. Process analytical technology case study part I: feasibility studies for quantitative near-infrared method development.

    PubMed

    Cogdill, Robert P; Anderson, Carl A; Delgado-Lopez, Miriam; Molseed, David; Chisholm, Robert; Bolton, Raymond; Herkert, Thorsten; Afnán, Ali M; Drennen, James K

    2005-01-01

    This article is the first of a series of articles detailing the development of near-infrared (NIR) methods for solid-dosage form analysis. Experiments were conducted at the Duquesne University Center for Pharmaceutical Technology to qualify the capabilities of instrumentation and sample handling systems, evaluate the potential effect of one source of a process signature on calibration development, and compare the utility of reflection and transmission data collection methods. A database of 572 production-scale sample spectra was used to evaluate the interbatch spectral variability of samples produced under routine manufacturing conditions. A second database of 540 spectra from samples produced under various compression conditions was analyzed to determine the feasibility of pooling spectral data acquired from samples produced at diverse scales. Instrument qualification tests were performed, and appropriate limits for instrument performance were established. To evaluate the repeatability of the sample positioning system, multiple measurements of a single tablet were collected. With the application of appropriate spectral preprocessing techniques, sample repositioning error was found to be insignificant with respect to NIR analyses of product quality attributes. Sample shielding was demonstrated to be unnecessary for transmission analyses. A process signature was identified in the reflection data. Additional tests demonstrated that the process signature was largely orthogonal to spectral variation because of hardness. Principal component analysis of the compression sample set data demonstrated the potential for quantitative model development. For the data sets studied, reflection analysis was demonstrated to be more robust than transmission analysis. PMID:16353986

  5. Ultrafast supercontinuum fiber-laser based pump-probe scanning magneto-optical Kerr effect microscope for the investigation of electron spin dynamics in semiconductors at cryogenic temperatures with picosecond time and micrometer spatial resolution

    SciTech Connect

    Henn, T.; Kiessling, T. Ossau, W.; Molenkamp, L. W.; Biermann, K.; Santos, P. V.

    2013-12-15

    We describe a two-color pump-probe scanning magneto-optical Kerr effect microscope which we have developed to investigate electron spin phenomena in semiconductors at cryogenic temperatures with picosecond time and micrometer spatial resolution. The key innovation of our microscope is the usage of an ultrafast “white light” supercontinuum fiber-laser source which provides access to the whole visible and near-infrared spectral range. Our Kerr microscope allows for the independent selection of the excitation and detection energy while avoiding the necessity to synchronize the pulse trains of two separate picosecond laser systems. The ability to independently tune the pump and probe wavelength enables the investigation of the influence of excitation energy on the optically induced electron spin dynamics in semiconductors. We demonstrate picosecond real-space imaging of the diffusive expansion of optically excited electron spin packets in a (110) GaAs quantum well sample to illustrate the capabilities of the instrument.

  6. Initial Technology Assessment for the Large UV-Optical-Infrared (LUVOIR) Mission Concept Study

    NASA Technical Reports Server (NTRS)

    Bolcar, Matthew R.; Feinberg, Lee D.; France, Kevin; Rauscher, Bernard J.; Redding, David; Schiminovich, David

    2016-01-01

    The NASA Astrophysics Divisions 30-Year Roadmap prioritized a future large-aperture space telescope operating in the ultra-violet-optical-infrared wavelength regime. The Association of Universities for Research in Astronomy envisioned a similar observatory, the High Definition Space Telescope. And a multi-institution group also studied the Advanced Technology Large Aperture Space Telescope. In all three cases, a broad science case is outlined, combining general astrophysics with the search for bio-signatures via direct-imaging and spectroscopic characterization of habitable exo-planets. We present an initial technology assessment that enables such an observatory that is currently being studied for the 2020 Decadal Survey by the Large UV-Optical Infrared (LUVOIR) surveyor Science and Technology Definition Team. We present here the technology prioritization for the 2016 technology cycle and define the required technology capabilities and current state-of-the-art performance. Current, planned, and recommended technology development efforts are also reported.

  7. Local excitation and interference of surface phonon polaritons studied by near-field infrared microscopy.

    PubMed

    Huber, A J; Ocelic, N; Hillenbrand, R

    2008-03-01

    We demonstrate that mid-infrared surface phonon polariton excitation, propagation and interference can be studied by scattering-type near-field optical microscopy (s-SNOM). In our experiments we image surface phonon polaritons (SPPs) propagating on flat SiC crystals. They are excited by weakly focused illumination of single or closely spaced metal disks we fabricated on the SiC surface by conventional photolithography. SPP imaging is performed by pseudo-heterodyne interferometric detection of infrared light scattered by the metal tip of our s-SNOM. The pseudo-heterodyne technique simultaneously yields optical amplitude and phase images which allows us to measure the SPP wave vector--including its sign--and the propagation length and further to study SPP interference. High resolution imaging of SPPs could be applied to investigate for example SPP focusing or heat transfer by SPPs in low dimensional nanostructures. PMID:18331484

  8. Stimulated infrared thermography applied to differentiate scar tissue from peri-scar tissue: a preliminary study.

    PubMed

    Riquet, Damien; Houel, Nicolas; Bodnar, Jean-Luc

    2016-08-01

    Every human injury leads to a scar formation. The healing process leads to the formation of new tissue: the scar, which is different from the original tissue. This process is influenced by mechanical strength and the local vasculature is modified. The purpose of this study is to show that there are various temperatures between the scar and the peri-scar area associated with the healing process that can be estimated using the thermal infrared camera. In the study, 12 scars were stimulated by cold. Several changes of temperature were observed between scar and peri-scar area for 10 min. Scars appeared significantly colder with a Wilcoxon test (p = 0.01). Results showed that stimulated infrared thermography can be used to monitor the temperature difference between the scar and peri-scar tissue. PMID:27270169

  9. Initial Technology Assessment for the Large-Aperture UV-Optical-Infrared (LUVOIR) Mission Concept Study

    NASA Technical Reports Server (NTRS)

    Bolcar, Matthew R.; Feinberg, Lee; France, Kevin; Rauscher, Bernard J.; Redding, David; Schiminovich, David

    2016-01-01

    The NASA Astrophysics Division's 30-Year Roadmap prioritized a future large-aperture space telescope operating in the ultra-violet/optical/infrared wavelength regime. The Association of Universities for Research in Astronomy envisioned a similar observatory, the High Definition Space Telescope. And a multi-institution group also studied the Advanced Technology Large Aperture Space Telescope. In all three cases, a broad science case is outlined, combining general astrophysics with the search for biosignatures via direct-imaging and spectroscopic characterization of habitable exoplanets. We present an initial technology assessment that enables such an observatory that is currently being studied for the 2020 Decadal Survey by the Large UV/Optical/Infrared (LUVOIR) surveyor Science and Technology Definition Team. We present here the technology prioritization for the 2016 technology cycle and define the required technology capabilities and current state-of-the-art performance. Current, planned, and recommended technology development efforts are also reported.

  10. Study on probability of detection for fatigue cracks in sonic infrared imaging

    NASA Astrophysics Data System (ADS)

    Zhu, Jun-zhen; Zhang, Chao-sheng; Feng, Fu-zhou; Min, Qing-xu; Xu, Chao

    2016-07-01

    Detection reliability of sonic infrared imaging is one of the increasingly important aspects for out of lab applications. And for the detection reliability evaluation, probability of detection (POD) for different defects under given test conditions has been successfully used as an accepted quantitative measurement. In this study, we test a set of C45 ferritic steel plates with artificial fatigue cracks. Experimental results show that the crack heating response increases with the increasing crack length, and the relationship between the logarithmic form of heat response signal and the crack length appears to be linear. Based on the above statistic characteristics, the linear regression analysis and the Wald method are adopted to estimate the POD function and its confidence interval. The study aims to provide a quantitative evaluation method for detection reliability in sonic infrared imaging.

  11. Study of optical techniques for the Ames unitary wind tunnel. Part 5: Infrared imagery

    NASA Technical Reports Server (NTRS)

    Lee, George

    1992-01-01

    A survey of infrared thermography for aerodynamics was made. Particular attention was paid to boundary layer transition detection. IR thermography flow visualization of 2-D and 3-D separation was surveyed. Heat transfer measurements and surface temperature measurements were also covered. Comparisons of several commercial IR cameras were made. The use of a recently purchased IR camera in the Ames Unitary Plan Wind Tunnels was studied. Optical access for these facilities and the methods to scan typical models was investigated.

  12. Infrared laser photolysis - A new tool for the study of prebiotic chemistry

    NASA Technical Reports Server (NTRS)

    Davis, D. D.; Smith, G. R.; Guillory, W. A.

    1980-01-01

    Infrared laser induced dielectric breakdown and multiphoton absorption experiments on CH4/NH3 'atmospheres' are described. It is found that HCN, a central intermediate in prebiotic chemistry, is a principal product. This, combined with the fact that dielectric breakdown appears to have much in common with ordinary electric sparks, suggests that the laser could be a useful tool in studies of prebiotic chemistry. Several possible experiments in this vein are suggested.

  13. Micro-Raman and infrared studies of multiferroic TbMn₂O₅.

    PubMed

    Mansouri, S; Jandl, S; Roberge, B; Balli, M; Dimitrov, D Z; Orlita, M; Faugeras, C

    2016-02-10

    We have studied the Raman and infrared spectral response of TbMn2O5 under an applied magnetic field parallel to the easy magnetic a-axis at 4.2 K. Strong spin-lattice coupling in TbMn2O5 is evidenced by a frequency shift of Raman and infrared phonons as a function of magnetic field compared to the phonon response of BiMn2O5 that remains unaffected. The magnetic field behavior of the highest frequency phonons retraces the polarization switching in TbMn2O5 and shows an important frequency softening below 3 T that is modulated by the J 3 and J 4 exchange parameters. The role of the Tb(3+) spin alignment with H is interpreted in terms of a local lattice striction and the contribution of the charge transfer mechanism to the magnetoelectric process is evaluated. PMID:26790102

  14. The Rho Ophiuchi cloud young stellar population - Results of a near-infrared study

    NASA Technical Reports Server (NTRS)

    Greene, Thomas P.; Young, Erick T.

    1991-01-01

    An imaging survey of 1.4 sq pc of the Rho Ophiuchi dark cloud in the J, H, and K near-infrared photometric bands was conducted. Approximately 332 of the 481 detected sources are associated with the cloud, and 30 percent of these have near-infrared excesses, indicative of disks or circumstellar material surrounding these young stellar objects (YSOs). The K-band luminosity function is significantly different in different regions of the survey area, suggesting that YSOs in these regions have different ages or mass functions. The entire survey area has a high star formation efficiency of about 23 percent. Finally, many newly detected sources provide a relatively large, uniformly sensitive sample of objects for study at longer wavelengths to better determine true source luminosities and evolutionary lifetimes.

  15. Fourier transform infrared synchrotron ellipsometry for studying the anisotropy of small organic samples.

    PubMed

    Hinrichs, K; Gensch, M; Röseler, A; Korte, E H; Sahre, K; Eichhorn, K J; Esser, N; Schade, U

    2003-10-01

    An experimental setup for polarization-dependent and spectroscopic ellipsometric measurements was developed that utilizes the brilliance of synchrotron infrared radiation at the electron storage ring at BESSY II for investigations of small samples and sample areas. During commissioning of the beamline and the experimental setup, a 1 mm2 piece of a well-characterized polyimide film was studied to show the benefits of Fourier transform infrared (FT-IR) synchrotron ellipsometry. The band shapes are interpreted with respect to the anisotropic distribution of transition dipole moments within the film. In comparison to a globar source, the signal intensity has been improved by more than one order of magnitude for this example. PMID:14639753

  16. Photodynamic inactivation of microorganisms which cause pulmonary diseases with infrared light: an in vitro study

    NASA Astrophysics Data System (ADS)

    Leite, Ilaiáli S.; Geralde, Mariana C.; Salina, Ana C.; Medeiros, Alexandra I.; Kurachi, Cristina; Bagnato, Vanderlei S.; Inada, Natalia M.

    2014-03-01

    Lower respiratory infections are among the leading causes of death worldwide. In this study, it was evaluated the interaction of indocyanine green, a photosensitizer activated by infrared light, with alveolar macrophages and the effectiveness of the photodynamic therapy using this compound against Streptococcus pneumoniae . Initial experiments analyzed indocyanine green toxicity to alveolar macrophages in the dark with different drug concentrations and incubation times, and macrophage viability was obtained with the MTT method. The average of the results showed viability values below 90% for the two highest concentrations. Experiments with Streptococcus pneumoniae showed photodynamic inactivation with 10 μM indocyanine green solution. Further experiments with the bacteria in co-culture with AM will be conducted verifying the photodynamic inactivation effectiveness of the tested drug concentrations and incubation periods using infrared light.

  17. Micro-Raman and infrared studies of multiferroic TbMn2O5

    NASA Astrophysics Data System (ADS)

    Mansouri, S.; Jandl, S.; Roberge, B.; Balli, M.; Dimitrov, D. Z.; Orlita, M.; Faugeras, C.

    2016-02-01

    We have studied the Raman and infrared spectral response of TbMn2O5 under an applied magnetic field parallel to the easy magnetic a-axis at 4.2 K. Strong spin-lattice coupling in TbMn2O5 is evidenced by a frequency shift of Raman and infrared phonons as a function of magnetic field compared to the phonon response of BiMn2O5 that remains unaffected. The magnetic field behavior of the highest frequency phonons retraces the polarization switching in TbMn2O5 and shows an important frequency softening below 3 T that is modulated by the J 3 and J 4 exchange parameters. The role of the Tb3+ spin alignment with H is interpreted in terms of a local lattice striction and the contribution of the charge transfer mechanism to the magnetoelectric process is evaluated.

  18. Infrared absorption study of hydrogen incorporation in thick nanocrystalline diamond films

    SciTech Connect

    Tang, C.J.; Neves, A.J.; Carmo, M.C.

    2005-05-30

    We present an infrared (IR) optical absorbance study of hydrogen incorporation in nanocrystalline diamond films. The thick nanocrystalline diamond films were synthesized by microwave plasma-assisted chemical vapor deposition and a high growth rate about 3.0 {mu}m/h was achieved. The morphology, phase quality, and hydrogen incorporation were assessed by means of scanning electron microscopy, Raman spectroscopy, and Fourier-transform infrared spectroscopy (FTIR). Large amount of hydrogen bonded to nanocrystalline diamond is clearly evidenced by the huge CH stretching band in the FTIR spectrum. The mechanism of hydrogen incorporation is discussed in light of the growth mechanism of nanocrystalline diamond. This suggests the potential of nanocrystalline diamond for IR electro-optical device applications.

  19. Study of wavefront error and polarization of a side mounted infrared window

    NASA Astrophysics Data System (ADS)

    Liu, Jiaguo; Li, Lin; Hu, Xinqi; Yu, Xin

    2008-03-01

    The wavefront error and polarization of a side mounted infrared window made of ZnS are studied. The Infrared windows suffer from temperature gradient and stress during their launch process. Generally, the gradient in temperature changes the refractive index of the material whereas stress produces deformation and birefringence. In this paper, a thermal finite element analysis (FEA) of an IR window is presented. For this purpose, we employed an FEA program Ansys to obtain the time-varying temperature field. The deformation and stress of the window are derived from a structural FEA with the aerodynamic force and the temperature field previously obtained as being the loads. The deformation, temperature field, stress field, ray tracing and Jones Calculus are used to calculate the wavefront error and the change of polarization state.

  20. Optical Design Trade Study for the Wide Field Infrared Survey Telescope [WFIRST

    NASA Technical Reports Server (NTRS)

    Content, David A.; Goullioud, R.; Lehan, John P.; Mentzell, John E.

    2011-01-01

    The Wide Field Infrared Survey Telescope (WFIRST) mission concept was ranked first in new space astrophysics mission by the Astro2010 Decadal Survey incorporating the Joint Dark Energy Mission (JDEM)-Omega payload concept and multiple science white papers. This mission is based on a space telescope at L2 studying exoplanets [via gravitational microlensing], probing dark energy, and surveying the near infrared sky. Since the release of NWNH, the WFIRST project has been working with the WFIRST science definition team (SDT) to refine mission and payload concepts. We present the driving requirements. The current interim reference mission point design, based on the use of a 1.3m unobscured aperture three mirror anastigmat form, with focal imaging and slitless spectroscopy science channels, is consistent with the requirements, requires no technology development, and out performs the JDEM-Omega design.

  1. The thermotropic behavior of dipalmitoyl phosphatidylcholine bilayers. A Fourier transform infrared study of specifically labeled lipids.

    PubMed Central

    Cameron, D G; Casal, H L; Mantsch, H H; Boulanger, Y; Smith, I C

    1981-01-01

    Fourier transform infrared spectroscopy has been used to study the thermotropic behavior of hydrated multibilayers of specifically deuterated derivatives of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine. It is shown that throughout the gel phase there is little or no conformational disorder introduced into the acyl chains. The pretransition effect is greatest in the central segments of the acyl chains, demonstrating that the interchain interactions are more pronounced in this region than in the center of the bilayer and suggesting the presence, in the gel phase, of a "plateau" in the strength of the interchain interactions. As the temperature is reduced, the rate of rotation of the terminal methyl group decreases steadily; below 0 degree C the conformation is rigid on the infrared time scale. PMID:6894878

  2. A study of the large-scale infrared emission from a selected dark cloud

    NASA Technical Reports Server (NTRS)

    Young, Erick T.

    1990-01-01

    An investigation of the infrared emission energetics and embedded population in the rho Ophiuchi dark cloud is summarized. With a distance of approximately 140 pc, the rho Ophiuchi cloud is one of the closest regions of recent star formation. It is also one of the best studied such regions with numerous observations at all wavelengths. The IRAS data of the cloud provided a new glimpse of the overall structure of the cloud. In particular, the interaction of radiation from the Sco-Oph OB Association on the external heating of the cloud was very evident on Skyflux and Survey Co-Add images produced by IRAS. The infrared survey also revealed a number of new embedded sources in the cloud which have subsequently been observed from the ground. An earlier study explored the overall energetics of the cloud using the IRAS data. The main conclusions of that work were: (1) the overall luminosity of the cloud is well explained by the emission of the known B-stars, HD 147889, SR-3, and S1, along with a 15 percent contribution from the external radiation field; (2) the dust physical temperatures were significantly lower than the observed CO gas temperatures; and (3) dust grains are heated to only 10 percent to 20 percent of the total depth into the cloud. This analysis is extended by drawing on data from large-scale CO maps and from near-infrared surveys of the embedded population.

  3. Atmosphere and climate studies of Mars using the Mars Observer pressure modulator infrared radiometer

    NASA Technical Reports Server (NTRS)

    Mccleese, D. J.; Haskins, R. D.; Schofield, J. T.; Zurek, R. W.; Leovy, C. B.; Paige, D. A.; Taylor, F. W.

    1992-01-01

    Studies of the climate and atmosphere of Mars are limited at present by a lack of meteorological data having systematic global coverage with good horizontal and vertical resolution. The Mars Observer spacecraft in a low, nearly circular, polar orbit will provide an excellent platform for acquiring the data needed to advance significantly our understanding of the Martian atmosphere and its remarkable variability. The Mars Observer pressure modulator infrared radiometer (PMIRR) is a nine-channel limb and nadir scanning atmospheric sounder which will observe the atmosphere of Mars globally from 0 to 80 km for a full Martian year. PMIRR employs narrow-band radiometric channels and two pressure modulation cells to measure atmospheric and surface emission in the thermal infrared. PMIRR infrared and visible measurements will be combined to determine the radiative balance of the polar regions, where a sizeable fraction of the global atmospheric mass annually condenses onto and sublimes from the surface. Derived meteorological fields, including diabatic heating and cooling and the vertical variation of horizontal winds, are computed from the globally mapped fields retrieved from PMIRR data.

  4. OLBERS: An Interplanetary Probe to Study Visible and Infrared Diffuse Backgrounds

    NASA Astrophysics Data System (ADS)

    Désert, F.-X.

    1995-10-01

    The visible extragalactic background (though as yet undetected) is insufficient to explain the abundance of heavy elements in galaxies: either there should be some diffuse extragalactic light in the near infrared (from 1 to 10 μm) and/or in the far infrared (≥100 μm) if dust has reprocessed the star light. We propose a new space mission to be dedicated to the search and mapping of primordial stellar light from the visible to the mid-infrared (20 μm). In this spectrum range, detectors have reached such a sensitivity that the mission should aim at being (source) photon noise limited, and not any longer background photon noise limited. For that purpose, a small passively cooled telescope with large format CCDs and CIDs could be sent beyond the zodiacal dust cloud (which is absent beyond a solar distance of about 3 AU). In that case, the only remaining foregrounds before reaching the extragalactic background, is due to the Milky Way integrated emission from stars and the diffuse galactic light due to scattering and emission by interstellar dust, which are all unavoidable. Maps of the extragalactic light could be obtained at the arcminute resolution with high signal to noise ratio. This mission is the next logical step after IRAS, COBE and ISO for the study of extragalactic IR backgrounds. It has been proposed as a possible medium-sized mission for the post-horizon 2000 ESA program that could be a piggy back of a planetary mission.

  5. Conformations of 1,1-diethoxyethane: A matrix isolation infrared and ab initio study

    NASA Astrophysics Data System (ADS)

    Venkatesan, V.; Viswanathan, K. S.

    2011-03-01

    Conformations of 1,1-diethoxyethane (DEE) were studied using matrix isolation infrared spectroscopy. Infrared features of the lowest energy, G∓G±(tt) conformer and the first higher energy, TG-(tt) conformer of matrix-isolated DEE were observed for the first time. The experiments were supported by ab initio computations performed at the HF and B3LYP levels, using a 6-31++G** basis set. The computed vibrational wavenumbers at the B3LYP/6-31++G** level for the G∓G±(tt) and TG-(tt) conformers, were found to agree well with the experimentally observed features, leading to a definitive assignment of the infrared features of these conformers of DEE. At the B3LYP/6-31++G** level, the energy of TG-(tt) conformer was found to be 0.42 kcal/mol above the ground state G∓G±(tt) conformer. AIM calculations were also performed to understand the role of intramolecular Csbnd H⋯O interaction in the conformational preferences in DEE.

  6. The application of infrared synchrotron radiation to the study of interfacial vibrational modes

    SciTech Connect

    Hirschmugl, C.J.; Williams, G.P.

    1992-12-31

    Synchrotron radiation provides an extremely bright broad-band source in the infrared which is ideally suited to the study of surface and interface vibrational modes in the range 50--3,000 cm{sup {minus}1}. Thus it covers the important range of molecule-substrate interactions, as well as overlapping with the more easily accessible near-ir region where molecular internal modes are found. Compared to standard broadband infrared sources such as globars, not only is it 1,000 times brighter, but its emittance matches the phase-space of the electrochemical cell leading to full utilization of this brightness advantage. In addition, the source is more stable even than water-cooled globars in vacuum for both short-term and long-term fluctuations. The authors summarize the properties of synchrotron radiation in the infrared, in particular pointing out the distinct differences between this and the x-ray region. They use experimental data in discussing important issues of signal to noise and address the unique problems and advantages of the synchrotron source. Thus they emphasize the important considerations necessary for developing new facilities. This analysis then leads to a discussion of phase-space matching to electrochemical cells, and to other surfaces in vacuum. Finally they show several examples of the application of infrared synchrotron radiation to surface vibrational spectroscopy. The examples are for metal crystal surfaces in ultra-high vacuum and include CO/Cu(100) and (111) and CO/K/Cu(100). The experiments show how the stability of the synchrotron source allows subtle changes in the background to be observed in addition to the discrete vibrational modes. These changes are due to electronic states induced by the adsorbate. In some cases the authors have seen interferences between these and the discrete vibrational modes, leading to a breakdown of the dipole selection rules, and the observation of additional modes.

  7. The application of infrared synchrotron radiation to the study of interfacial vibrational modes

    SciTech Connect

    Hirschmugl, C.J.; Williams, G.P.

    1992-01-01

    Synchrotron radiation provides an extremely bright broad-band source in the infrared which is ideally suited to the study of surface and interface vibrational modes in the range 50--3,000 cm[sup [minus]1]. Thus it covers the important range of molecule-substrate interactions, as well as overlapping with the more easily accessible near-ir region where molecular internal modes are found. Compared to standard broadband infrared sources such as globars, not only is it 1,000 times brighter, but its emittance matches the phase-space of the electrochemical cell leading to full utilization of this brightness advantage. In addition, the source is more stable even than water-cooled globars in vacuum for both short-term and long-term fluctuations. The authors summarize the properties of synchrotron radiation in the infrared, in particular pointing out the distinct differences between this and the x-ray region. They use experimental data in discussing important issues of signal to noise and address the unique problems and advantages of the synchrotron source. Thus they emphasize the important considerations necessary for developing new facilities. This analysis then leads to a discussion of phase-space matching to electrochemical cells, and to other surfaces in vacuum. Finally they show several examples of the application of infrared synchrotron radiation to surface vibrational spectroscopy. The examples are for metal crystal surfaces in ultra-high vacuum and include CO/Cu(100) and (111) and CO/K/Cu(100). The experiments show how the stability of the synchrotron source allows subtle changes in the background to be observed in addition to the discrete vibrational modes. These changes are due to electronic states induced by the adsorbate. In some cases the authors have seen interferences between these and the discrete vibrational modes, leading to a breakdown of the dipole selection rules, and the observation of additional modes.

  8. Mapping Glacial Weathering Processes with Thermal Infrared Remote Sensing: A Case Study at Robertson Glacier, Canada

    NASA Astrophysics Data System (ADS)

    Rutledge, A. M.; Christensen, P. R.; Shock, E.; Canovas, P. A., III

    2014-12-01

    Geologic weathering processes in cold environments, especially subglacial chemical processes acting on rock and sediment, are not well characterized due to the difficulty of accessing these environments. Glacial weathering of geologic materials contributes to the solute flux in meltwater and provides a potential source of energy to chemotrophic microbes, and is thus an important component to understand. In this study, we use Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data to map the extent of glacial weathering in the front range of the Canadian Rockies using remotely detected infrared spectra. We ground-truth our observations using laboratory infrared spectroscopy, x-ray diffraction, and geochemical analyses of field samples. The major goals of the project are to quantify weathering inputs to the glacial energy budget, and to link in situ sampling with remote sensing capabilities. Robertson Glacier, Alberta, Canada is an excellent field site for this technique as it is easily accessible and its retreating stage allows sampling of fresh subglacial and englacial sediments. Infrared imagery of the region was collected with the ASTER satellite instrument. At that same time, samples of glacially altered rock and sediments were collected on a downstream transect of the glacier and outwash plain. Infrared laboratory spectroscopy and x-ray diffraction were used to determine the composition and abundance of minerals present. Geochemical data were also collected at each location, and ice and water samples were analyzed for major and minor elements. Our initial conclusion is that the majority of the weathering seems to be occurring at the glacier-rock interface rather than in the outwash stream. Results from both laboratory and ASTER data indicate the presence of leached weathering rinds. A general trend of decreasing carbonate abundances with elevation (i.e. residence time in ice) is observed, which is consistent with increasing calcium ion

  9. Structural study of photodegraded acrylic-coated lime wood using Fourier transform infrared and two-dimensional infrared correlation spectroscopy.

    PubMed

    Popescu, Carmen-Mihaela; Simionescu, Bogdan C

    2013-06-01

    The weathering of acrylic films and acrylic-coated lime wood (Tillia cordata Mill.) were examined using Fourier transform infrared (FT-IR) and two-dimensional infrared correlation spectroscopy. The obtained results showed chemical changes induced by exposure to weathering conditions, in both films and coated wood. The observed spectral changes of the acrylic films refer to the absorption band assigned to the C-O stretching, which progressively decreases with increasing exposure time. In the spectra of treated wood samples the main signal indicating the advance of oxidation during the photodegradation exposure is the gradual increase and broadening of the band in the carbonyl region. This is due to the formation of the non-hydrogen bonded aliphatic carboxylic acids and γ-lactone structures in the acrylic resin and of the nonconjugated ketones, carboxyl groups, and lactones in wood. As a consequence, the increase of the 1734 cm(-1) band is due to the degradation of lignin from wood surface. These observations are also supported by the decreased intensities of the bands at 1598 and 1505 cm(-1), assigned to C=C of aromatic skeletal (lignin). The relative intensity of the characteristic aromatic lignin band at 1505 cm(-1) decreases up to 25% of its original value after weathering, being less than half of the value obtained for uncoated wood. Two-dimensional infrared (2D IR) correlation spectroscopy was used to identify the sequence of the modifications of the different stretching vibrations bands under the weathering conditions, the method allowing the prediction of the order of degradation reactions. The acrylic resin degradation starts with the formation of radicals by abstraction of the tertiary hydrogen atoms of the methyl acrylate units and the α-CH3 groups from the ethyl methacrylate units. The subsequent decomposition and oxidation led to the formation of alcohol groups, hydroperoxides, ketones, and/or carboxylic acid groups. The 2D IR correlation spectra of

  10. Analysis of biological tissues using scanning near-field infrared microspectroscopy

    NASA Astrophysics Data System (ADS)

    Jeung, Andrew G.; Erramilli, Shyamsunder; Hong, Mi K.; Huie, Phil; Smith, Todd I.

    1997-10-01

    Infrared absorption microspectroscopy is a useful technique to analyze biological tissues, as it can rapidly and non- destructively provide quantitative information about the molecular composition of tissue on a small spatial scale. At the Stanford Picosecond Free Electron Laser Center, a Scanning Near-field Infrared Microscope (SNIM) with the Free Electron Laser (FEL) as its illumination source has been used for in situ microspectroscopic characterization of constituents in human atherosclerotic tissue. The system consists of a Near-field Scanning Optical Microscope utilizing a tapered chalcogenide fiber as the scanning probe. The Stanford mid-infrared FEL provides high power infrared radiation that can be easily coupled into the chalcogenide fiber and whose wavelength is continuously tunable from 3 to 15 micrometers. With the FEL, the SNIM can acquire an image at a single wavelength of a 200 micrometer square region with 2 micrometer spatial resolution in under 30 minutes. It can also obtain infrared spectra at sub- wavelength resolution. The SNIM was used to examine unstained, frozen microtone sections of human atherosclerotic lesions. Spectra from localized regions in the sample were taken and analyzed to determine the distribution of various protein, lipid, and mineral constituents among the tissue microstructures. These findings were compared with results obtained by polarization microscopy and traditional histological staining techniques. The molecular information obtained in these studies can potentially lead to a greater understanding of atherosclerosis. Moreover, they demonstrate the usefulness of SNIM towards micrometer-scale vibrational microspectroscopy.

  11. Laser-induced damage threshold of silicon in millisecond, nanosecond, and picosecond regimes

    SciTech Connect

    Wang, X.; Shen, Z. H.; Lu, J.; Ni, X. W.

    2010-08-15

    Millisecond, nanosecond, and picosecond laser pulse induced damage thresholds on single-crystal are investigated in this study. The thresholds of laser-induced damage on silicon are calculated theoretically for three pulse widths based on the thermal damage model. An axisymmetric mathematical model is established for the transient temperature field of the silicon. Experiments are performed to test the damage thresholds of silicon at various pulse widths. The results indicate that the damage thresholds obviously increase with the increasing of laser pulse width. Additionally, the experimental results agree well with theoretical calculations and numerical simulation results.

  12. Pulsed picosecond KGW:Nd3+ laser based on the Sagnac interferometer

    NASA Astrophysics Data System (ADS)

    Grabovski, Vitaly V.; Prokhorenko, Valentin I.; Yatskiv, Dmytro Y.

    1995-04-01

    Energetic, statistical, and temporal characteristics of a pico-second KGW:Nd laser based on the Sagnac interferometer are studied. All experiments are provided in comparison with the traditional linear cavity. The effect of stimulated Raman scattering suppression in such a specific cavity was found. Stimulated Raman scattering in KGW dumped all output parameters in the laser with a linear cavity. A new cavity scheme can solve such problems and provide for good output handling. It is shown that output pulse duration is larger in the proposed scheme compared with a linear cavity but other characteristics are much better.

  13. Si nanostructures grown by picosecond high repetition rate pulsed laser deposition

    NASA Astrophysics Data System (ADS)

    Pervolaraki, M.; Komninou, Ph.; Kioseoglou, J.; Athanasopoulos, G. I.; Giapintzakis, J.

    2013-08-01

    One-step growth of n-doped Si nanostructures by picosecond ultra fast pulsed laser deposition at 1064 nm is reported for the first time. The structure and morphology of the Si nanostructures were characterized by X-ray diffraction, scanning electron microscopy and atomic force microscopy. Transmission electron microscopy studies revealed that the shape of the Si nanostructures depends on the ambient argon pressure. Fibrous networks, cauliflower formations and Si rectangular crystals grew when argon pressure of 300 Pa, 30 Pa and vacuum (10-3 Pa) conditions were used, respectively. In addition, the electrical resistance of the vacuum made material was investigated.

  14. Picosecond laser-driven terahertz radiation from large scale preplasmas of solid targets

    NASA Astrophysics Data System (ADS)

    Liao, G. Q.; Li, Y. T.; Li, C.; Su, L. N.; Zheng, Y.; Liu, M.; Dunn, J.; Nilsen, J.; Hunter, J.; Wang, W. M.; Sheng, Z. M.; Zhang, J.

    2016-05-01

    The terahertz (THz) radiation from the front of solid targets with a large-scale preplasma irradiated by relativistic picosecond laser pulses has been studied. The THz radiation measured at the specular direction nonlinearly increases with laser energy and an optimal plasma density scalelength is observed. Particle-in-cell simulations indicate that the radiation can be attributed to the model of mode conversion. While the THz radiation near the target normal direction is saturated with laser energy and plasma scalelength. Unlike the radiation in the specular direction’ the transient current formed at the plasma-vacuum interface could be responsible for the radiation near the target normal.

  15. Picosecond laser cutting and drilling of thin flex glass

    NASA Astrophysics Data System (ADS)

    Wlodarczyk, Krystian L.; Brunton, Adam; Rumsby, Phil; Hand, Duncan P.

    2016-03-01

    We investigate the feasibility of cutting and drilling thin flex glass (TFG) substrates using a picosecond laser operating at wavelengths of 1030 nm, 515 nm and 343 nm. 50 μm and 100 μm thick AF32®Eco Thin Glass (Schott AG) sheets are used. The laser processing parameters such as the wavelength, pulse energy, pulse repetition frequency, scan speed and the number of laser passes which are necessary to perform through a cut or to drill a borehole in the TFG substrate are studied in detail. Our results show that the highest effective cutting speeds (220 mm/s for a 50 μm thick TFG substrate and 74 mm/s for a 100 μm thick TFG substrate) are obtained with the 1030 nm wavelength, whereas the 343 nm wavelength provides the best quality cuts. The 515 nm wavelength, meanwhile, can be used to provide relatively good laser cut quality with heat affected zones (HAZ) of <25 μm for 50 μm TFG and <40 μm for 100 μm TFG with cutting speeds of 100 mm/s and 28.5 mm/s, respectively. The 343 nm and 515 nm wavelengths can also be used for drilling micro-holes (with inlet diameters of ⩽75 μm) in the 100 μm TFG substrate with speeds of up to 2 holes per second (using 343 nm) and 8 holes per second (using 515 nm). Optical microscope and SEM images of the cuts and micro-holes are presented.

  16. Field and laboratory studies of Fourier transform infrared spectroscopy in continuous emissions monitoring applications

    NASA Astrophysics Data System (ADS)

    Plummer, Grant M.

    1991-04-01

    Entropy Environmentalists, Inc. has performed a number of field and laboratory studies using a FTIR spectrometer for the analysis of gas phase samples and sample streams. The field studies, undertaken in conjunction with the U.S. Environmental Protection Agency (EPA), included several weeks of continuous monitoring at a hazardous waste incinerator, a sewage sludge incinerator, and a coal-fired boiler. Results of the analyses of both cold and hot samples, using several types of infrared absorption cells, will be discussed and compared to the results of other continuous monitoring systems.

  17. Mapping Soil Surface Macropores Using Infrared Thermography: An Exploratory Laboratory Study

    PubMed Central

    de Lima, João L. M. P.; Abrantes, João R. C. B.; Silva, Valdemir P.; de Lima, M. Isabel P.; Montenegro, Abelardo A. A.

    2014-01-01

    Macropores and water flow in soils and substrates are complex and are related to topics like preferential flow, nonequilibrium flow, and dual-continuum. Hence, the quantification of the number of macropores and the determination of their geometry are expected to provide a better understanding on the effects of pores on the soil's physical and hydraulic properties. This exploratory study aimed at evaluating the potential of using infrared thermography for mapping macroporosity at the soil surface and estimating the number and size of such macropores. The presented technique was applied to a small scale study (laboratory soil flume). PMID:25371915

  18. A temperature dependent infrared absorption study of strong hydrogen bonds in bis(glycinium)oxalate

    NASA Astrophysics Data System (ADS)

    Bhatt, Himal; Deo, M. N.; Murli, C.; Vishwakarma, S. R.; Chitra, R.; Sharma, Surinder M.

    2016-05-01

    We report infrared absorption studies on Bis(glycinium)oxalate, an organic complex of the simplest amino acid Glycine, under varying temperatures in the range 77 - 350 K. The measurements have been carried out in the spectral range 400 - 4000 cm-1 and the strongest O-H---O hydrogen bond, which plays a vital role in the structural stabilization, has been studied. Subtle changes in widths of modes and temperature dependent frequency variations have been observed near 250 K. The hydrogen bonding network remains stable in the entire temperature range. This is in contrast to its reported high pressure behavior.

  19. Ultrafast infrared spectroscopy in photosynthesis.

    PubMed

    Di Donato, Mariangela; Groot, Marie Louise

    2015-01-01

    In recent years visible pump/mid-infrared (IR) probe spectroscopy has established itself as a key technology to unravel structure-function relationships underlying the photo-dynamics of complex molecular systems. In this contribution we review the most important applications of mid-infrared absorption difference spectroscopy with sub-picosecond time-resolution to photosynthetic complexes. Considering several examples, such as energy transfer in photosynthetic antennas and electron transfer in reaction centers and even more intact structures, we show that the acquisition of ultrafast time resolved mid-IR spectra has led to new insights into the photo-dynamics of the considered systems and allows establishing a direct link between dynamics and structure, further strengthened by the possibility of investigating the protein response signal to the energy or electron transfer processes. This article is part of a Special Issue entitled: Vibrational spectroscopies and bioenergetic systems. PMID:24973600

  20. Near-infrared spectroscopy as an auxiliary tool in the study of child development

    PubMed Central

    de Oliveira, Suelen Rosa; Machado, Ana Carolina Cabral de Paula; de Miranda, Débora Marques; Campos, Flávio dos Santos; Ribeiro, Cristina Oliveira; Magalhães, Lívia de Castro; Bouzada, Maria Cândida Ferrarez

    2015-01-01

    OBJECTIVE: To investigate the applicability of Near-Infrared Spectroscopy (NIRS) for cortical hemodynamic assessment tool as an aid in the study of child development. DATA SOURCE: Search was conducted in the PubMed and Lilacs databases using the following keywords: ''psychomotor performance/child development/growth and development/neurodevelopment/spectroscopy/near-infrared'' and their equivalents in Portuguese and Spanish. The review was performed according to criteria established by Cochrane and search was limited to 2003 to 2013. English, Portuguese and Spanish were included in the search. DATA SYNTHESIS: Of the 484 articles, 19 were selected: 17 cross-sectional and two longitudinal studies, published in non-Brazilian journals. The analyzed articles were grouped in functional and non-functional studies of child development. Functional studies addressed the object processing, social skills development, language and cognitive development. Non-functional studies discussed the relationship between cerebral oxygen saturation and neurological outcomes, and the comparison between the cortical hemodynamic response of preterm and term newborns. CONCLUSIONS: NIRS has become an increasingly feasible alternative and a potentially useful technique for studying functional activity of the infant brain. PMID:25862295

  1. Picosecond spectroscopy of vibrational and electronic dynamics in high-pressure molecular solids

    SciTech Connect

    Crowell, R.A. II.

    1992-01-01

    Picosecond time resolved studies of vibrational and electronic dynamics in molecular solids are presented. Several uranyl compounds were selected that had large gaps in their vibrational energy density of states. Picosecond coherent anti-Stokes Raman measurements (psCARS) reveal that at 10 K vibrational relaxation occurs by at least a fifth order anharmonic mechanism. At elevated temperatures vibrational decay proceeds predominantly by a cubic anharmonic upconversion mechanism. The results of psCARS on a low temperature molecular solid in a high pressure diamond anvil cell are presented. For carbon disulfide pressure induced shifts in the phonon frequencies result in the opening up of a new relaxation pathway for the 2[nu][sub 2] mode. This pressure induced relaxation mechanism appears to dominate the dynamics of this mode at pressures greater than 19 kbar. Pressure dependent low temperature psCARS measurements for the [nu][sub 9], [nu][sub 8], and [nu][sub 5] of naphthalene are presented. Pressure induced density of states effects are isolated, allowing direct observations of pressure induced anharmonic coupling effects. The magnitude of the pressure induced anharmonic coupling is highly mode specific. psCARS measurements at low temperature are performed on homogeneous high pressure crystals and on highly strained crystals. Results are analyzed in terms of competition between vibrational relaxation and inhomogeneous dephasing. Changes in vibrational dephasing induced by a large negative pressure change ([minus][Delta]P [ge] 5 kbar) are used to determine the magnitude of inhomogeneous dephasing effects. The strain induced inhomogeneous dephasing is mode specific. Picosecond photon echo measurements on a molecular solid in a high pressure diamond anvil cell at low temperature are presented. Results for the O[sub 1] and O[sub 3] photosites in pentacene doped pterphenyl are presented and discussed in terms of pressure induced changes in the Debye frequency.

  2. Photoconductivity in organic thin films: From picoseconds to seconds after excitation

    NASA Astrophysics Data System (ADS)

    Day, J.; Subramanian, S.; Anthony, J. E.; Lu, Z.; Twieg, R. J.; Ostroverkhova, O.

    2008-06-01

    We present a detailed study, on time scales from picoseconds to seconds, of transient and continuous wave (cw) photoconductivity in solution-grown thin films of functionalized pentacene (Pc), anthradithiophene (ADT), and dicyanomethylenedihydrofuran (DCDHF). In all films, at temperatures of 285-350 K, we observe fast carrier photogeneration and nonthermally activated charge transport on picosecond time scales. At ˜30 ps after photoexcitation at room temperature and at applied electric field of 1.2×104 V/cm, values obtained for the product of mobility and photogeneration efficiency, μη, in ADT-tri-isoproplysilylethynyl-(TIPS)-F, Pc-TIPS, and DCDHF films are ˜0.018-0.025, ˜0.01-0.022, and ˜0.002-0.004 cm2/V s, respectively, depending on the film quality, and are weakly electric field dependent. In functionalized ADT and Pc films, the power-law decay dynamics of the transient photoconductivity is observed, on time scales of up to ˜1 μs after photoexcitation, in the best samples. In contrast, in DCDHF amorphous glass, most of the photogenerated carriers are trapped within ˜200 ps. Transport of photoexcited carriers on longer time scales is probed by cw illumination through an optical chopper, with a variable chopper frequency. In contrast with what is observed on picosecond time scales, charge carriers on millisecond and longer time scales are predominantly localized, and are characterized by a broad distribution of carrier lifetimes. Such carriers make the principal contributions to dc photoconductivity.

  3. The study of a single BGC823 cell using Fourier transform infrared microspectroscopic imaging

    NASA Astrophysics Data System (ADS)

    Wang, Xin; Qi, Zeming; Wang, Shengyi; Liu, Gang; Gao, Helong; Tian, Yangchao

    2011-09-01

    In order to investigate gastric cancer at cellular and sub-cellular level, a single human gastric adenocarcinoma BGC823 cell was studied by an infrared microscope equipped with a focal plane array (FPA) detector. The spectra showed difference between the nucleus and the endoplasmic reticulum (ER) of the BGC823 cell. The peak of v asPO 2- was shifted to a higher wavenumber at the nucleus compared with that at the ER. The height ratios of 2954 cm -1/2922 cm -1 (CH 3/CH 2) and 1088 cm -1/1539 cm -1 (DNA/amide II) of the nucleus were significantly higher than those of the ER. Furthermore, chemical images reveal the intensity distributions of lipids, proteins and DNA of the single BGC823 cell, and the intense absorptions of proteins and DNA were observed in the nuclear region of the cell while the intense absorption of lipids was found in the ER region of the cell. The Fourier transform infrared (FTIR) microspectroscopic imaging result indicates the study of the single gastric cancer cell at sub-cellular level can be beneficial for knowing gastric cancer more which will be of great importance for the study and diagnosis of gastric cancer. The result also suggests that FPA is a useful tool in the study of a single cell and may be a powerful tool for study and diagnosis of gastric cancer.

  4. Infrared fiber optic evanescent wave spectroscopy for the study of diffusion in the human skin

    NASA Astrophysics Data System (ADS)

    Raichlin, Yosef; Goldberg, I.; Brenner, Sarah; Shulzinger, Evgeny; Katzir, Abraham

    2002-03-01

    Fourier Transform Infrared (FTIR) spectroscopic systems make use of Attenuated Total Reflection (ATR) elements for the study of skin in dermatology. FTIR - ATR allows real time and reagent-less analysis of several components, simultaneously. The potential for skin studies is increased by the development of the flexible fiber optic sensor made from infrared transparent polycrystalline silver halide. Segments of fibers can replace the ATR sensing elements inside an FTIR system. Moreover a Fiberoptic Evanescent Wave Spectroscopy (FEWS) can also be used for real time in vivo measurement on skin, in situ. We used FEWS to study the diffusion of UV sunscreen lotions from the outer skin layer into the dermis and epidermis, and used the various absorption bands to differentiate between the behavior of the organic and the water molecules in the lotion. FEWS can be a powerful tool for studying the transport of drugs and cosmetic creams through the skin from the stratum corneum to the dermis and epidermis and for studying the lateral diffusion of various molecules into the skin, in vivo and in real time.

  5. Picosecond kinetics and Sn <-- S1 absorption spectra of retinoids and carotenoids

    NASA Astrophysics Data System (ADS)

    Bondarev, Stanislav L.; Tikhomirov, S. A.; Bachilo, Sergei M.

    1991-05-01

    Light energy absorption, as well as the subsequent photochemical and photophysical processes of cis -+trans isomerisation (vision and bacteriorhodopsin photosynthesis) and energy transfer (photosynthesis in green plants and micro organisms) take place in a pigment-protein complex including polyene chromophors, retinoids and carotenoids. Picosecond and subpicosecond studies of the spectral and kinetic characteristics of these processes are carried out in both complex photoreceptor and photosynthetic ms'2 and model systems with the use of solutions of retinoids and carotenoids.36 The lifetimes of the lower singlet-exited states S (21A; ) ofsome carotenoids in toluene at room temperature have been measured by the method of picosecond photolysis and amount to 8.6+/- 0.5 for all-trans-fl -carotene1 and 5.2 0.6 PS for canthaxanthin.5 /3 -carotene fluorescence at room temperature is practically absent, its yield being less than iO (Ref. 7). /1 -carotene fluorescence at 77 and 4.2 K in isopentane discovered by us8 is characterized by yields of (4+/-2) .iO and (8+/-3) . i0- and lifetimes of(4+/-2) .iO' and (8+/-3) .iO' and is due to the transitions from the higher S(1' B) state. The picosecond transient S -S absorption of/I - carotene in different solvents at 293 K is characterized by spectra in the 550-600 nm range.8 For retinoids, there is one work (Ref. 4) which gives the S, +-Si absorption spectrum of the Schiff base (aldimine) of retinal with amaz 465 mn in n-hexane at 290 K. The duration of transient absorption was 21 5 ps, although the fluorescence kinetics measured in this work (Ref. 4) at 298 K were characterized by two-component decay with r1 = 22 and r2 = 265 ps. The transient picosecond absorption spectra for retinal are absent in the literature and the lifetimes of its singlet-excited state at room temperature, measured by absorption and fluorescence, amount to 20+/-10 Ps in n-hexane3 and 17 Ps in ethanol,'9 respectively.

  6. Carbonate associated with hydroxide sol-gel processing of yttria: An infrared spectroscopic study

    SciTech Connect

    Seaverson, L.M.; Luo, S.Q.; Chien, P.L.; McClelland, J.F.

    1986-05-01

    Yttrium hydroxide gel was dried by five techniques to study their influences on the sintering behavior of yttria. Dried precursors, calcined and sintered oxides, and the initial gel were examined via Fourier transform infrared photoacoustic and/or attenuated total reflection spectroscopies. Carbonate was found to be in unidentate coordination to surface yttrium on both the dried hydroxide precursor and calcined oxide particles. An inverse correlation was found between the normalized surface carbonate concentration (carbonate concentration (wt%)/surface area (m/sup 2//g)) of precursors and calcined oxides and the density of their corresponding sintered bodies. Carbonate affects sintered density during the calcination and sintering steps.

  7. Decomposition of NO studied by infrared emission and CO laser absorption

    NASA Technical Reports Server (NTRS)

    Hanson, R. K.; Flower, W. L.; Monat, J. P.; Kruger, C. H.

    1974-01-01

    A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation was developed and applied in a study of the decomposition kinetics of NO. Simultaneous measurements of infrared emission by NO at 5.3 microns were also made to validate the laser absorption technique. The data were obtained behind incident shocks in NO-N2O-Ar (or Kr) mixtures, with temperatures in the range 2400-4100 K. Rate constants for dominant reactions were inferred from comparisons with computer simulations of the reactive flow.

  8. Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

    NASA Technical Reports Server (NTRS)

    Goldman, A.; Williams, W. J.; Murcray, D. G.

    1974-01-01

    The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

  9. Correlation Study Of Diffenrential Skin Temperatures (DST) For Ovulation Detection Using Infra-Red Thermography

    NASA Astrophysics Data System (ADS)

    Rao, K. H. S.; Shah, A. v.; Ruedi, B.

    1982-11-01

    The importance of ovulation time detection in the Practice of Natural Birth Control (NBC) as a contraceptive tool, and for natural/artificial insemination among women having the problem of in-fertility, is well known. The simple Basal Body Temperature (BBT) method of ovulation detection is so far unreliable. A newly proposed Differential Skin Temperature (DST) method may help minimize disturbing physiological effects and improve reliability. This paper explains preliminary results of a detailed correlative study on the DST method, using Infra-Red Thermography (IRT) imaging, and computer analysis techniques. Results obtained with five healthy, normally menstruating women volunteers will be given.

  10. Thermal Physical, and Infrared Spectroscopic Studies on Glasses Prepared by Microwave Route

    SciTech Connect

    Jagadeesha, N.; Gowda, V. C. Veeranna; Chakradhar, R. P. S.; Reddy, C. Narayana

    2011-07-15

    This paper describes thermal, physical and spectroscopic properties of glasses prepared by a novel micro wave method. These studies exhibited a strong compositional dependent trend and existence of characteristic boro-vanadate groups in these glasses. The scheme of modification of borate and vanadate groups is controlled by Sanderson's electronegativity principle. Analysis of density and glass transition temperatures suggests the presence of characteristic four coordinated borate and diboro - vanadate groups in these glasses. The presence of [BO{sub 4/2}]{sup -} and [B{sub 2}V{sub 2}O{sub 9}]{sup 2-}) groups are confirmed by Infrared Spectroscopy of investigated glasses.

  11. Study of advanced InSb arrays for SIRTF (Space Infrared Telescope Facility)

    NASA Technical Reports Server (NTRS)

    Hoffman, Alan; Feitt, Robert

    1989-01-01

    The Santa Barbara Research Center has completed a study leading to the development of advanced Indium Antimonide detector arrays for the Space Infrared Telescope Facility (SIRTF) Focal Plane Array Detector (FPAD) Subsystem of the Infrared Array Camera (IRAC) Band 1. The overall goal of the study was to perform design tradeoff studies, analysis and research to develop a Direct Readout Integrated Circuit to be hybridized to an advanced, high performance InSb detector array that would satisfy the technical requirements for Band 1 as specified in the IRAC Instrument Requirements Document (IRD), IRAC-202. The overall goal of the study was divided into both a near-term goal and a far-term goal. The near-term goal identifies current technology available that approaches, and in some cases meets the program technological goals as specified in IRAC-202. The far-term goal identifies technology development required to completely achieve SIRTF program goals. Analyses of potential detector materials indicates that InSb presently meets all Band 1 requirements and is considered to be the baseline approach due to technical maturity. The major issue with regard to photovoltaic detectors such as InSb and HgCdTe is to achieve a reduction in detector capacitance.

  12. Recent progress in picosecond pulse generation from semiconductor lasers

    NASA Technical Reports Server (NTRS)

    Auyeung, J. C.; Johnston, A. R.

    1982-01-01

    This paper reviews the recent progress in producing picosecond optical pulses from semiconductor laser diodes. The discussion concentrates on the mode-locking of a semiconductor laser diode in an external resonator. Transform-limited optical pulses ranging from several picoseconds to subpicosecond durations have been observed with active and passive mode-locking. Even though continuing research on the influence of impurities and defects on the mode-locking process is still needed, this technique has good promise for being utilized in fiber-optic communication systems. Alternative methods of direct electrical and optical excitation to produce ultrashort laser pulses are also described. They can generate pulses of similar widths to those obtained by mode-locking. The pulses generated will find applications in laser ranging and detector response measurement.

  13. Studies of fullerene absorption and production using an infrared free-electron laser

    SciTech Connect

    Affatigato, M.; Haglund, R.F.; Ying, Z.C.; Compton, R.N.

    1995-12-31

    Tunable photon sources such as free-electron lasers are potentially valuable tools in spectroscopic studies of fullerenes, a new class of carbon materials with unique cage structures. We have used the infrared free-electron-laser facility at Vanderbilt University to study the infrared absorption of gas-phase fullerene molecules and also to investigate the effects of an infrared laser in the synthesis and crystallization of fullerene materials. In one experiment, fullerene vapor was created in a heat pipe through which the FEL beam was passed; the transmission of the FEL beam relative to a reference detector was measured as a function of wavelength. A large (>10%) absorption of the IR laser was observed when it passed through C{sub 60} vapor at {approximately}800{degrees}C. Due to the broad spectral width of the FEL as well as spectral congestion, no spectral peaks were seen when the laser wavelength was tuned across a T{sub 1u}C{sub 60} IR mode near 7.0 {mu}. However, it is expected that the vibrational features can be resolved experimentally by passing the transmitted beam through a monochromator. In a separate experiment, the FEL beam was focused onto a surface of graphite or graphite/metal mixture target. Various fullerene molecules, including endohedral types, were produced when the soot was recovered from the ablation chamber. The yield of the products was measured to be {approximately}0.4 g/J of the incident laser energy. However, both the yield and the product distribution are virtually, the same as those in experiments using a nanosecond Nd:YAG laser. This suggests that the laser wavelength is not a crucial parameter in making fullerenes by laser ablation. Even when the laser is at resonance with one of the vibrational modes of C{sub 60}, the fullerene production is neither substantially enhanced nor suppressed.

  14. Luminescence studies and infrared emission of erbium-doped calcium zirconate phosphor.

    PubMed

    Tiwari, Neha; Dubey, Vikas

    2016-05-01

    The near-infrared-to-visible upconversion luminescence behaviour of Er(3+) -doped CaZrO3 phosphor is discussed in this manuscript. The phosphor was prepared by a combustion synthesis technique that is suitable for less-time-taking techniques for nanophosphors. The starting materials used for sample preparation were Ca(NO3 )2 .4H2 O, Zr(NO3 )4 and Er(NO3 )2, and urea was used as a fuel. The prepared sample was characterized by X-ray diffraction (XRD). The surface morphology of prepared phosphor was determined by field emission gun scanning electron microscopy (FEGSEM). The functional group analysis was determined by Fourier transform infrared (FTIR) spectroscopy. All prepared phosphors with variable Er(3+) concentrations (0.5-2.5 mol%) were studied by photoluminescence analysis. It was found that the excitation spectra of the prepared phosphor showed a sharp excitation peak centred at 980 nm. The emission spectra with variable Er(3+) concentrations showed strong peaks in the 555 nm and 567 nm range, with a dominant peak at 555 nm due to the ((2) H11/2 ,(4) S3/2 ) transition and a weaker transition at 567 nm associated with 527 nm. Spectrophotometric determination of the peak was evaluated by the Commission Internationale de I'Eclairage (CIE) method These upconverted emissions were attributed to a two-photon process. The excitation wavelength dependence of the upconverted luminescence, together with its time evolution after infrared pulsed excitation, suggested that energy transfer upconversion processes were responsible for the upconversion luminescence. The upconversion mechanisms were studied in detail through laser power dependence. Excited state absorption and energy transfer processes were discussed as possible upconversion mechanisms. The cross-relaxation process in Er(3+) was also investigated. Copyright © 2015 John Wiley & Sons, Ltd. PMID:26456020

  15. Picosecond time-domain electromagnetic scattering from conducting cylinders

    NASA Astrophysics Data System (ADS)

    Robertson, W. M.; Kopcsay, G. V.; Arjavalingam, G.

    1991-12-01

    The microwave scattering properties of conducting cylinders are characterized by measuring their response to picosecond-duration electromagnetic pulses. The ultrafast electromagnetic transients are generated and detected with optoelectronically pulsed antennas. The time-domain response gives physical insight into the scattering process. In addition, Fourier analysis is used to obtain the frequency dependence of the scattered amplitude and phase from 15 to 140 GHz.

  16. Picosecond pulse shaping by spectral phase and amplitude manipulation.

    PubMed

    Heritage, J P; Weiner, A M; Thurston, R N

    1985-12-01

    The temporal profile of ultrashort optical pulses may be tailored by physically manipulating the phase and the amplitude of frequency components that are spatially dispersed within a grating pulse compressor. Arbitrary pulse shapes may be synthesized subject only to the usual restrictions imposed by finite bandwidth and spatial resolution. We demonstrate this technique by generating a burst of evenly spaced picosecond pulses, a pulse doublet with odd field symmetry, and a burst of evenly spaced pulse doublets with odd field symmetry. PMID:19730501

  17. Infrared Thermometers

    ERIC Educational Resources Information Center

    Schaefers, John

    2006-01-01

    An infrared (IR) thermometer lab offers the opportunity to give science students a chance to measure surface temperatures, utilizing off-the-shelf technology. Potential areas of study include astronomy (exoplanets), electromagnetic spectrum, chemistry, evaporation rates, anatomy, crystal formation, and water or liquids. This article presents one…

  18. Combined studies of chemical composition of urine sediments and kidney stones by means of infrared microspectroscopy.

    PubMed

    Tamošaitytė, Sandra; Hendrixson, Vaiva; Želvys, Arūnas; Tyla, Ramūnas; Kučinskienė, Zita A; Jankevičius, Feliksas; Pučetaitė, Milda; Jablonskienė, Valerija; Šablinskas, Valdas

    2013-02-01

    Results of the structural analysis of urinary sediments by means of infrared spectral microscopy are presented. The results are in good agreement with the results of standard optical microscopy in the case of single-component and crystalline urinary sediments. It is found that for noncrystalline or multicomponent sediments, the suggested spectroscopic method is superior to optical microscopy. The chemical structure of sediments of any molecular origin can be elucidated by this spectroscopic method. The method is sensitive enough to identify solid particles of drugs present in urine. Sulfamethoxazole and traces of other medicines are revealed in this study among the other sediments. We also show that a rather good correlation exists between the type of urinary sediments and the renal stones removed from the same patient. Spectroscopic studies of urinary stones and corresponding sediments from 76 patients suffering from renal stone disease reveal that in 73% of cases such correlation exists. This finding is a strong argument for the use of infrared spectral microscopy to prevent kidney stone disease because stones can be found in an early stage of formation by using the nonintrusive spectroscopic investigation of urinary sediments. Some medical recommendations concerning the overdosing of certain pharmaceuticals can also be derived from the spectroscopic studies of urinary sediments. PMID:23429795

  19. Study on dietary fibre by Fourier transform-infrared spectroscopy and chemometric methods.

    PubMed

    Chylińska, Monika; Szymańska-Chargot, Monika; Kruk, Beata; Zdunek, Artur

    2016-04-01

    Fresh fruit is an important part of the diet of people all over the world as a significant source of water, vitamins and natural sugars. Nowadays it is also one of the main sources of dietary fibre. In fruit the dietary fibre is simply cell wall consisting essentially of polysaccharides. The aim of present study was to predict the contents of pectins, cellulose and hemicelluloses by partial least squares regression (PLS) analysis on the basis of Fourier transform-infrared (FT-IR) spectra of fruit cell wall residue. The second purpose was to analyse the composition of dietary fibre from fruit based on FT-IR spectral information in combination with chemometric methods (principle components analysis (PCA) and hierarchical cluster analysis (HCA)). Additionally the contents of polysaccharides in studied fruits were determined by analytical methods. It has been shown that the analysis of infrared spectra and the use of multivariate statistical methods can be useful for studying the composition of dietary fibre. PMID:26593472

  20. Effects of Somatothermal Far-Infrared Ray on Primary Dysmenorrhea: A Pilot Study

    PubMed Central

    Ke, Yu-Min; Ou, Ming-Chiu; Ho, Cheng-Kun; Lin, Yung-Sheng; Liu, Ho-Yen; Chang, Wen-An

    2012-01-01

    The purpose of this study was to assess the beneficial effects of using a far-infrared (FIR) belt on the management of patients with primary dysmenorrhea. This is the first study to determine the efficacy of somatothermal FIR using a parallel-arm randomized sham-controlled and double-blinded design with objective physical evidence and psychometric self-reports. Fifty-one Taiwanese women with primary dysmenorrhea were enrolled in the study. Results indicate that there was an increased abdominal temperature of 0.6°C and a 3.27% increase in abdominal blood flow in the FIR group (wearing FIR belt) compared to those in the control group (wearing sham belt). Verbal rating scale and numeric rating scale scores in the FIR group were both lower than those in the control group. Compared to the blank group (wearing no belt), the average dysmenorrhea pain duration of the FIR group was significantly reduced from 2.5 to 1.8 days, but there was no significant difference in the control group. These results demonstrate that the use of a belt made of far-infrared ceramic materials can reduce primary dysmenorrhea. PMID:23320024

  1. Combined studies of chemical composition of urine sediments and kidney stones by means of infrared microspectroscopy

    NASA Astrophysics Data System (ADS)

    Tamošaitytė, Sandra; Hendrixson, Vaiva; Želvys, Arūnas; Tyla, Ramūnas; Kučinskienė, Zita A.; Jankevičius, Feliksas; Pučetaitė, Milda; Jablonskienė, Valerija; Šablinskas, Valdas

    2013-02-01

    Results of the structural analysis of urinary sediments by means of infrared spectral microscopy are presented. The results are in good agreement with the results of standard optical microscopy in the case of single-component and crystalline urinary sediments. It is found that for noncrystalline or multicomponent sediments, the suggested spectroscopic method is superior to optical microscopy. The chemical structure of sediments of any molecular origin can be elucidated by this spectroscopic method. The method is sensitive enough to identify solid particles of drugs present in urine. Sulfamethoxazole and traces of other medicines are revealed in this study among the other sediments. We also show that a rather good correlation exists between the type of urinary sediments and the renal stones removed from the same patient. Spectroscopic studies of urinary stones and corresponding sediments from 76 patients suffering from renal stone disease reveal that in 73% of cases such correlation exists. This finding is a strong argument for the use of infrared spectral microscopy to prevent kidney stone disease because stones can be found in an early stage of formation by using the nonintrusive spectroscopic investigation of urinary sediments. Some medical recommendations concerning the overdosing of certain pharmaceuticals can also be derived from the spectroscopic studies of urinary sediments.

  2. X-ray production with sub-picosecond laser pulses

    SciTech Connect

    Schappert, G.T.; Cobble, J.A.; Fulton, R.D.; Kyrala, G.A.

    1993-12-31

    The interaction of intense, sub-picosecond laser pulses with solid targets produces intense picosecond x-ray pulses. With focused laser pulses of several 10 {sup 18} W/cm{sup 2}, He-like and H-like line radiation from targets such as aluminum and silicon has been produced. The energy conversion efficiency from the laser pulse energy to the 1--2 keV line x-rays is nearly one percent. The duration of the line x-ray radiation is of the order of ten picoseconds, although this may be an upper estimate because of the temporal resolution of the x-ray streak camera. The spatial extent of the x-ray source region is only slightly larger than the laser focal spot, or about 10 {mu}m in diameter. With these characteristics, such x-ray sources emit an intensity of nearly 10{sup 14} W/cm{sup 2}. Experiments and modeling which led to the above conclusions will be discussed.

  3. Picosecond VUV anti-Stokes Raman laser pumped by a KrF laser

    NASA Astrophysics Data System (ADS)

    Takahashi, Akihiko; Maeda, Mitsuo; Muraoka, Katsunori; Akazaki, Masanori

    1989-02-01

    Generation of picosecond vacuum ultraviolet pulses by anti-Stokes stimulated Raman Scattering (ASRS) in hydrogen gas is reported. A tunable picosecond KrF excimer laser (30 ps FWHM, 12 mJ) is used as a pump source, and a series of anti-Stokes lines up to the 9th order (128.8 nm) is efficiently generated. The transient effects due to the finite decay time of the Raman medium are discussed for the present picosecond ASRS experiment.

  4. [Study on XRD and infrared spectroscopy of nephrites from Xinjiang and Xiuyan, Liaoning].

    PubMed

    Chen, Quan-Li; Bao, De-Qing; Yin, Zuo-Wei

    2013-11-01

    The nephrite species with different colors from Xinjiang and Xiuyan, Liaoning, including gray nephrite, yellow nephrite, white nephrite, jasper and He-Mo nephrite, a special nephrite from Xiuyan, were selected for the present study. The gemological testing method, infrared absorption spectroscopy and X-ray powder diffraction were used to analyze and compare the gemological characteristics of the nephrite with different colors and textures from the above localities, in order to understand the similarities and differences between these nephrites with similar colors but different origin, and provide a theoretical basis for the identification of the nephrite origin. The results show that the nephrites from Xinjiang and Xiuyan, Liaoning province have similar gemological properties. They have similar refractive index of 1.60-1.62 and density of 2.660-3.020 g x cm(-3), and only the density has some differences with different colors. The fluorescence.characteristics are not obvious in these nephrites. The major constituent minerals for these nephrites are tremolite, and small amounts of clay minerals such as chlorite and illite are found in the jasper from Xinjiang. Based on the X-ray powder diffraction analysis on the different types of nephrite from two localities, it was shown that the character of spectra peaks and diffraction intensity of different types of nephrite can reflect the texture of the nephrite and the size of crystalline particles to some extent. The infrared absorption spectra are similar for the nephrites from two localities. The infrared absorption spectrum does not make sense to identify the origin and species of nephrites. PMID:24555399

  5. Determining soil moisture from geosynchronous satellite infrared data - A feasibility study

    NASA Technical Reports Server (NTRS)

    Wetzel, P. J.; Atlas, D.; Woodward, R. H.

    1984-01-01

    Numerical modelling results are reported from a pilot study investigating the feasibility of developing a technique for daily soil moisture measurement throughout the world, based on GOES infrared data. A detailed one-dimensional boundary layer-surface-soil model was used in order to determine which physical parameters observable from GOES are most sensitive to soil moisture, and which are most effected by seasonal changes, atmospheric effects and vegetation cover. The results of the sensitivity test show that the mid-morning differential of surface temperature with respect to absorbed solar radiation is optimally sensitive to soil moisture. A case study comparing model results with GOES infrared data confirms the sensitivity of this parameter to soil moisture and also confirms the applicability of the model to predicting area-averaged surface temperature changes. Model measurements of soil moisture are expected to be most accurate for dry or marginal agricultural areas where drought is common. Sources of error, including the advection of clouds, are examined and methods of minimizing error are discussed.

  6. Trade-off studies of a hyperspectral infrared sounder on a geostationary satellite.

    PubMed

    Wang, Fang; Li, Jun; Schmit, Timothy J; Ackerman, Steven A

    2007-01-10

    Trade-off studies on spectral coverage, signal-to-noise ratio (SNR), and spectral resolution for a hyperspectral infrared (IR) sounder on a geostationary satellite are summarized. The data density method is applied for the vertical resolution analysis, and the rms error between true and retrieved profiles is used to represent the retrieval accuracy. The effects of spectral coverage, SNR, and spectral resolution on vertical resolution and retrieval accuracy are investigated. The advantages of IR and microwave sounder synergy are also demonstrated. When focusing on instrument performance and data processing, the results from this study show that the preferred spectral coverage combines long-wave infrared (LWIR) with the shorter middle-wave IR (SMidW). Using the appropriate spectral coverage, a hyperspectral IR sounder with appropriate SNR can achieve the required science performance (1 km vertical resolution, 1 K temperature, and 10% relative humidity retrieval accuracy). The synergy of microwave and IR sounders can improve the vertical resolution and retrieval accuracy compared to either instrument alone. PMID:17268565

  7. High-resolution infrared studies of perdeutero-spiropentane, C5D8

    NASA Astrophysics Data System (ADS)

    Erickson, B. A.; Ju, X.; Nibler, J. W.; Beaudry, C. M.; Blake, T. A.

    2016-07-01

    Perdeutero-spiropentane (C5D8) has been synthesized, and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational states. Gas phase infrared spectra were recorded at a resolution (0.002 cm-1) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis and/or Fermi resonance interactions for most bands. However a detailed rovibrational analysis of the fundamental ν15 (b2) parallel band proved possible, and a fit of more than 1600 lines yielded a band origin of 1053.84465(10) cm-1 and ground state constants (in units of cm-1): B0 = 0.1120700(9), DJ = 1.51(3) × 10-8, DJK = 3.42(15) × 10-8. We note that the B0 value is significantly less than a value of Ba = 0.1140 cm-1 calculated using structural parameters from an earlier electron diffraction (ED) study, whereas one expects Ba to be lower than B0 because of thermal averaging over higher vibrational levels. A similar discrepancy was noted in an earlier study of C5H8 (Price et al., 2011). The structural and spectroscopic results are in good accord with values computed at the anharmonic level using the B3LYP density functional method with a cc-pVTZ basis set.

  8. Infrared study of new star cluster candidates associated to dusty globules

    NASA Astrophysics Data System (ADS)

    Soto King, P.; Barbá, R.; Roman-Lopes, A.; Jaque, M.; Firpo, V.; Nilo, J. L.; Soto, M.; Minniti, D.

    2014-10-01

    We present results from a study of a sample of small star clusters associated to dusty globules and bright-rimmed clouds that have been observed under ESO/Chile public infrared survey Vista Variables in the Vía Láctea (VVV). In this short communication, we analyse the near-infrared properties of a set of four small clusters candidates associated to dark clouds. This sample of clusters associated to dusty globules are selected from the new VVV stellar cluster candidates developed by members of La Serena VVV Group (Barbá et al. 2014). Firstly, we are producing color-color and color-magnitude diagrams for both, cluster candidates and surrounding areas for comparison through PSF photometry. The cluster positions are determined from the morphology on the images and also from the comparison of the observed luminosity function for the cluster candidates and the surrounding star fields. Now, we are working in the procedures to establish the full sample of clusters to be analyzed and methods for subtraction of the star field contamination. These clusters associated to dusty globules are simple laboratories to study the star formation relatively free of the influence of large star-forming regions and populous clusters, and they will be compared with those clusters associated to bright-rimmed globules, which are influenced by the energetic action of nearby O and B massive stars.

  9. Time resolved infrared studies of C-H bond activation by organometallics

    SciTech Connect

    Asplund, M.C. |

    1998-06-01

    This work describes how step-scan Fourier Transform Infrared spectroscopy and visible and near infrared ultrafast lasers have been applied to the study of the photochemical activation of C-H bonds in organometallic systems, which allow for the selective breaking of C-H bonds in alkanes. The author has established the photochemical mechanism of C-H activation by Tp{sup *}Rh(CO){sub 2}(Tp{sup *} = HB-Pz{sup *}{sub 3}, Pz = 3,5-dimethylpyrazolyl) in alkane solution. The initially formed monocarbonyl forms a weak solvent complex, which undergoes a change in Tp{sup *} ligand connectivity. The final C-H bond breaking step occurs at different time scales depending on the structure of the alkane. In linear solvents, the time scale is <50 ns and cyclic alkanes is {approximately}200 ps. The reactivity of the Tp{sup *}Rh(CO){sub 2} system has also been studied in aromatic solvents. Here the reaction proceeds through two different pathways, with very different time scales. The first proceeds in a manner analogous to alkanes and takes <50 ns. The second proceeds through a Rh-C-C complex, and takes place on a time scale of 1.8 {micro}s.

  10. STUDIES OF THE Be STAR X PERSEI DURING A BRIGHT INFRARED PHASE

    SciTech Connect

    Mathew, Blesson; Banerjee, D. P. K.; Naik, Sachindra; Ashok, N. M.

    2013-06-15

    We present multi-epoch photometric and spectroscopic near-infrared observations of the Be star X Persei in the JHK bands covering the wavelength range 1.08-2.35 {mu}m. Combining results from our earlier studies with the present observations, it is shown that the equivalent widths and line fluxes of the prominent H I and He I lines anti-correlate with the strength of the adjacent continuum. That is, during the span of the observations, the JHK broadband fluxes increase while the emission equivalent width values of the H I and He I lines decrease (the lines under consideration being the Paschen and Brackett lines of hydrogen and the 1.7002 {mu}m and 2.058 {mu}m lines of helium). Such an anti-correlation effect is not commonly observed in Be stars in the optical; in the infrared, this may possibly be the first reported case of such behavior. We examine different mechanisms that could possibly cause it and suggest that it could originate due to a radiatively warped, precessing circumstellar disk. It is also shown that during the course of our studies, X Per evolved to an unprecedented state of high near-IR brightness with J, H, K magnitudes of 5.20, 5.05, and 4.84, respectively.

  11. Development of a sensitive mid-infrared spectrometer for the study of cooled molecular ions

    NASA Astrophysics Data System (ADS)

    Porambo, Michael W.

    The study of molecular ions is relevant to many areas of scientific interest. Mid-infrared laser spectroscopy functions as a useful tool for understanding the role of molecular ions in these areas. To this end, a broadly tunable mid-infrared difference frequency generation noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) system has been developed and characterized through rovibrational spectroscopy of methane. In addition, an attempt was made to use this spectrometer to probe molecular ions focused into an ion beam. Challenges inherent to laboratory molecular ion spectroscopy, such as quantum dilution at high internal temperatures and low ion number density, have been addressed through the development of an instrument that produces rotationally cooled molecular ions coupled to the highly sensitive spectroscopic technique NICE-OHMS. The instrument was first explored as an extension of an ion beam spectrometer by the integration of a continuous supersonic expansion discharge source for the production of the cooled molecular ions. Issues with the implementation led to the re- design of the instrument for spectroscopically probing a supersonic expansion discharge directly with NICE-OHMS. After implementing discharge modulation of the supersonic expansion source, spectra of rotationally cooled H(3/+) and HN(+/2) were acquired. This instrumental development and preliminary spectroscopy has paved the way for a new method for the sensitive spectroscopic study of cooled molecular ions that will aid further insight into these chemical species in many fields.

  12. [The Study on Infrared Spectra of 7-Hydroxycoumarin by Density Functional Theory].

    PubMed

    Jia, Fei-yun; Su, Yu; Ran, Ming; Zhu, Jiang; Zhang, Bo

    2016-01-01

    Infrared spectroscopy is an important source of information for the identification of the compounds structure and it is great significant for biological activity research of natural and organic drug molecules. With the theoretical calculation method is more reasonable and calculation accuracy continues to improve, Theoretical calculate advantage is more obvious in the infrared spectrum simulation and vibration modes attributable identified. And it has important reference value for experimental study of infrared spectral analysis. Using density functional theory, geometry optimizations and frequencies calculation of 7-Hydroxycoumarin were performed at the level of B3LYP/6-311G(d, p), the stable structure and all vibration modes of 7-Hydroxycoumarin were attained. The results show that the infrared absorption peak of 7-hydroxycoumarin is mainly distributed in the several regions in wave number of 3 700-3 500, 3 150-3 000, 1 750-1 400, 1 400-1 000, 1 000-50 cm(-1). In addition to the vibration in a wave number range of 3 700-3 500, 3 150-3 000 cm(-1) is relatively independent, and were attributed to OH stretching vibration and benzene ring CH stretching vibration, the other several vibration regions are more complex, the different degree of spectral peaks is composed of multiple vibration modes. Finally, based on the theoretical analysis of the vibration mode, the vibration modes of 7-Hydroxycoumarin molecule were assigned, and in order to discuss the reliability of theoretical calculation method, the correlation diagram of the main absorption peak of 7-hydroxyl group was drawn from the theoretical value of X axis and the experimental value of Y axis, the correlation between experimental IR data and calculated IR data of 7-Hydroxycoumarin was analyzed through the linear regression method. Results show that they have good correlation, correlation coefficient values "r" equals 0.998 5, and the theory calculation of 7-Hydroxycoumarin IR by density functional theory at

  13. Optical and electrical studies of single walled carbon nanotubes for infrared sensing and photovoltaic applications

    NASA Astrophysics Data System (ADS)

    Omari, Mones A.

    Carbon nanotubes are emerging as highly promising opto-electro-mechanical device components essential for the development of a variety of hybrid opto-electronic, electro-mechanical and bio-medical technologies on the nanoscale and have been a subject of continued research. In particular, single-walled carbon nanotubes are predicted to exhibit strong light absorption induced by photon-assisted electronic transitions, free carrier and plasmonic-based absorption. Single-walled carbon nanotubes have been confirmed to exhibit a strong photoconduction response in the infrared range, which can provide many new opportunities in engineering nano-photovoltaic and optoelectronic devices. At the same time, the use of strong chemical reagents has been long considered as one of the key processing steps for the separation and purification of single-walled carbon nanotube post-synthesis. In this work, optically-induced voltage in carbon nanotube bundles and thin-films configured as two-terminal resistive elements and operating as junctionless photo-cells in the infrared range as well as the time-dependent wet-processing of HiPCo nanotubes in phosphoric acid and its effect on the structural, transport, infrared light absorption, and photoconduction characteristics were studied. As the photo-voltage generated is found to appear only for asymmetric and off-contact illuminations, the effect is explained based on a photo-generated heat flow model. The engineered cell prototypes were found to yield electrical powers of ˜ 30 pW while demonstrating improved conversion efficiency under high-flux illumination. The cell is also shown to act as an uncooled infrared sensor, with its dark-to-photocurrent ratio improving as temperature increases. The wet-processing of HiPCo nanotubes was done for a nominal time intervals of 1, 2 and 3 hours. The treatment was found to be a two-step process that initially results in the removal and partial replacement of most pre-existing C-O, O-H and CHx groups

  14. A Study of Global Cirrus Optical and Microphysical Properties Based on an Efficient Infrared Retrieval Method

    NASA Astrophysics Data System (ADS)

    Li, Y.; Heidinger, A. K.

    2015-12-01

    Current studies of global upper tropospheric cirrus clouds from satellite observations are focused on daytime, primarily due to dependence on solar reflectance in the retrieval technique. Here, utilizing an accurate and efficient infrared based retrieval technique, cirrus cloud optical properties, including cloud optical thickness and effective particle size, are investigated using Aqua MODIS data during both day and night conditions. It is revealed that contrast of averaged day and night properties is small, despite of an apparent distinction in occurrence frequencies. The geographical differences are more pronounced. Seasonal variations, vertical distributions, as well as interrelations with other macrophysical and microphysical properties are also studied. The findings of this study will be useful for developing future cirrus cloud parameterization schemes in climate models.

  15. Rock type mapping with indices defined for multispectral thermal infrared ASTER data: case studies

    NASA Astrophysics Data System (ADS)

    Ninomiya, Yoshiki

    2003-03-01

    ASTER sensor aboard NASA's Terra satellite has the capability of measuring multispectral thermal infrared (TIR) emission from the earth's surface to space. The author proposed indices by the combination of ASTER-TIR bands for detecting quartz and carbonate minerals, and another index to estimate the abundance of bulk SiO2 content in the surface silicate rocks, applied them to the low level ASTER radiance at the sensor data without atmospheric corrections, and showed a potential ability of the indices in a rock type mapping. This paper tries to apply the proposed method into the practical case studies using ASTER-TIR data. The study sites include ophiolitic belt zones in Oman and along Yarlun Zangbo River in Tibet. The applied results are compared with the geology of the study areas. It indicates that the new remote sensing approach proposed here would improve the quality and the cost of the geological mapping in arid and semi-arid regions.

  16. Development and applications of infrared structural biology

    NASA Astrophysics Data System (ADS)

    Kang, Zhouyang

    Aspartic acid (Asp), Glutamic acid (Glu) and Tyrosine (Tyr) often play critical roles at the active sites of proteins. Probing the structural dynamics of functionally important Asp/Glu and Tyr provides crucial information for protein functionality. Time-resolved infrared structural biology offers strong advantages for its high structural sensitivity and broad dynamic range (picosecond to kilosecond). In order to connect the vibrational frequencies to specific structures of COO- groups and phenolic --OH groups, such as the number, type, and geometry of hydrogen bond interactions, we develop two sets of vibrational structural markers (VSM), built on the symmetric and asymmetric stretching frequencies for COO- and C-O stretching and C-O-H bending frequencies for phenolic --OH. Extensive quantum physics (density functional theory) based computational studies, combined with site-specific isotope labeling as well as site-directed mutagenesis, and experimental FTIR data on Asp/Glu in proteins, are used to establish a unique correlation between the vibrations and multiple types of hydrogen bonding interactions. Development of those vibrational structural markers significantly enhances the power of time-resolved infrared structural biology for the study of functionally important structural dynamics of COO- from Asp/Glu and phenolic --OH from Tyr residues in proteins, including rhodopsin for biological signaling, bacteriorhodopsin and PYP for proton transfer, photosystem II for energy transformation, and HIV protease for enzymatic catalysis. Furthermore, this approach can be adopted in the future development of vibrational structural markers for other functionally important amino acid residues in proteins, such as arginine (Arg), histidine (His), and serine (Ser).

  17. Spectroscopic Study of Terahertz Generation in Mid-Infrared Quantum Cascade Lasers

    NASA Astrophysics Data System (ADS)

    Jiang, Yifan; Vijayraghavan, Karun; Jung, Seungyong; Jiang, Aiting; Kim, Jae Hyun; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus C.; Belkin, Mikhail A.

    2016-02-01

    Terahertz quantum cascade laser sources based on intra-cavity difference-frequency generation are currently the only room-temperature mass-producible diode-laser-like emitters of coherent 1-6 THz radiation. Device performance has improved dramatically over the past few years to reach milliwatt-level power output and broad tuning from 1.2 to 5.9 THz, all at room-temperature. Terahertz output in these sources originates from intersubband optical nonlinearity in the laser active region. Here we report the first comprehensive spectroscopic study of the optical nonlinearity and investigate its dependence on the mid-infrared pump frequencies. Our work shows that the terahertz generation efficiency can vary by a factor of 2 or greater depending on the spectral position of the mid-infrared pumps for a fixed THz difference-frequency. We have also measured for the first time the linewidth for transitions between the lower quantum cascade laser states, which is critical for determining terahertz nonlinearity and predicting optical loss in quantum cascade laser waveguides.

  18. THE MILKY WAY PROJECT: A STATISTICAL STUDY OF MASSIVE STAR FORMATION ASSOCIATED WITH INFRARED BUBBLES

    SciTech Connect

    Kendrew, S.; Robitaille, T. P.; Simpson, R.; Lintott, C. J.; Bressert, E.; Povich, M. S.; Sherman, R.; Schawinski, K.; Wolf-Chase, G.

    2012-08-10

    The Milky Way Project citizen science initiative recently increased the number of known infrared bubbles in the inner Galactic plane by an order of magnitude compared to previous studies. We present a detailed statistical analysis of this data set with the Red MSX Source (RMS) catalog of massive young stellar sources to investigate the association of these bubbles with massive star formation. We particularly address the question of massive triggered star formation near infrared bubbles. We find a strong positional correlation of massive young stellar objects (MYSOs) and H II regions with Milky Way Project bubbles at separations of <2 bubble radii. As bubble sizes increase, a statistically significant overdensity of massive young sources emerges in the region of the bubble rims, possibly indicating the occurrence of triggered star formation. Based on numbers of bubble-associated RMS sources, we find that 67% {+-} 3% of MYSOs and (ultra-)compact H II regions appear to be associated with a bubble. We estimate that approximately 22% {+-} 2% of massive young stars may have formed as a result of feedback from expanding H II regions. Using MYSO-bubble correlations, we serendipitously recovered the location of the recently discovered massive cluster Mercer 81, suggesting the potential of such analyses for discovery of heavily extincted distant clusters.

  19. Spectroscopic Study of Terahertz Generation in Mid-Infrared Quantum Cascade Lasers.

    PubMed

    Jiang, Yifan; Vijayraghavan, Karun; Jung, Seungyong; Jiang, Aiting; Kim, Jae Hyun; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus C; Belkin, Mikhail A

    2016-01-01

    Terahertz quantum cascade laser sources based on intra-cavity difference-frequency generation are currently the only room-temperature mass-producible diode-laser-like emitters of coherent 1-6 THz radiation. Device performance has improved dramatically over the past few years to reach milliwatt-level power output and broad tuning from 1.2 to 5.9 THz, all at room-temperature. Terahertz output in these sources originates from intersubband optical nonlinearity in the laser active region. Here we report the first comprehensive spectroscopic study of the optical nonlinearity and investigate its dependence on the mid-infrared pump frequencies. Our work shows that the terahertz generation efficiency can vary by a factor of 2 or greater depending on the spectral position of the mid-infrared pumps for a fixed THz difference-frequency. We have also measured for the first time the linewidth for transitions between the lower quantum cascade laser states, which is critical for determining terahertz nonlinearity and predicting optical loss in quantum cascade laser waveguides. PMID:26879901

  20. Time-resolved infrared absorption studies of the dynamics of radical reactions.

    SciTech Connect

    Macdonald, R. G.

    2008-01-01

    There is very little information available about the dynamics of radical+radical interactions. These processes are important in combustion being chain termination steps as well as generating new molecular species. To study these processes, a new experimental apparatus has been constructed to investigate radical-radical dynamics. The first radical or atomic species is produced with a known concentration in a microwave discharge flow system. The second is produced by pulsed laser photolysis of a suitable photolyte. The time dependence of individual rovibrational states of the product is followed by absorption of a continuous infrared laser. This approach will allow the reaction of interest to be differentiated from other radical reactions occurring simultaneously. The experimental approach is highly versatile, being able to detect a number of molecular species of particular interest to combustion processes such as water, methane, acetylene etc. at the state specific level. State specific infrared absorption coefficients of radicals can be measured in situ allowing for the determination of the absolute concentrations and hence branching ratios for reactions having multiple reaction pathways.

  1. Studying the Diurnal Cycle of Convection Using a TRMM-Calibrated Infrared Rain Algorithm

    NASA Technical Reports Server (NTRS)

    Negri, Andrew J.; Adler, Robert F.; Huffman, George J.; Manyin, Michael

    2004-01-01

    The development of a satellite infrared (IR) technique for estimating convective and stratiform rainfall and its application in studying the diurnal variability of rainfall on a global scale is presented. The Convective-Stratiform Technique (CST), calibrated by coincident, physically retrieved rain rates from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR), is applied over the global tropics. The technique makes use of the IR data from the TRMM Visible/Infrared Scanner (VIRS) before application to global geosynchronous satellite data. The calibrated CST technique has the advantages of high spatial resolution (4 km), filtering of non-raining cirrus clouds, and the stratification of the rainfall into its convective and stratiform components, the last being important for the calculation of vertical profiles of latent heating. The diurnal cycle of rainfall, as well as the division between convective and stratiform rainfall will be presented. The technique is validated using available data sets and compared to other global rainfall products such as Global Precipitation Climatology Project (GPCP) IR product, calibrated with TRMM Microwave Imager (TMI) data. Results from five years of PR data will show the global-tropical partitioning of convective and stratiform rainfall.

  2. Studying the Diurnal Cycle of Convection Using a TRMM-Calibrated Infrared Rain Algorithm

    NASA Technical Reports Server (NTRS)

    Negri, Andrew J.

    2005-01-01

    The development of a satellite infrared (IR) technique for estimating convective and stratiform rainfall and its application in studying the diurnal variability of rainfall on a global scale is presented. The Convective-Stratiform Technique (CST), calibrated by coincident, physically retrieved rain rates from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR), is applied over the global tropics. The technique makes use of the IR data from the TRMM Visible/Infrared Scanner (VIRS) before application to global geosynchronous satellite data. The calibrated CST technique has the advantages of high spatial resolution (4 km), filtering of nonraining cirrus clouds, and the stratification of the rainfall into its convective and stratiform components, the last being important for the calculation of vertical profiles of latent heating. The diurnal cycle of rainfall, as well as the division between convective and Stratiform rainfall will be presented. The technique is validated using available data sets and compared to other global rainfall products such as Global Precipitation Climatology Project (GPCP) IR product, calibrated with TRMM Microwave Imager (TMI) data. Results from five years of PR data will show the global-tropical partitioning of convective and stratiform rainfall.

  3. A Study of Planetary Nebulae using the Faint Object Infrared Camera for the SOFIA Telescope

    NASA Technical Reports Server (NTRS)

    Davis, Jessica

    2012-01-01

    A planetary nebula is formed following an intermediate-mass (1-8 solar M) star's evolution off of the main sequence; it undergoes a phase of mass loss whereby the stellar envelope is ejected and the core is converted into a white dwarf. Planetary nebulae often display complex morphologies such as waists or torii, rings, collimated jet-like outflows, and bipolar symmetry, but exactly how these features form is unclear. To study how the distribution of dust in the interstellar medium affects their morphology, we utilize the Faint Object InfraRed CAmera for the SOFIA Telescope (FORCAST) to obtain well-resolved images of four planetary nebulae--NGC 7027, NGC 6543, M2-9, and the Frosty Leo Nebula--at wavelengths where they radiate most of their energy. We retrieve mid infrared images at wavelengths ranging from 6.3 to 37.1 micron for each of our targets. IDL (Interactive Data Language) is used to perform basic analysis. We select M2-9 to investigate further; analyzing cross sections of the southern lobe reveals a slight limb brightening effect. Modeling the dust distribution within the lobes reveals that the thickness of the lobe walls is higher than anticipated, or rather than surrounding a vacuum surrounds a low density region of tenuous dust. Further analysis of this and other planetary nebulae is needed before drawing more specific conclusions.

  4. Studies on Nephrite and Jadeite Jades by Fourier Transform Infrared (ftir) and Raman Spectroscopic Techniques

    NASA Astrophysics Data System (ADS)

    Tan, T. L.; Ng, L. L.; Lim, L. C.

    2013-10-01

    The mineralogical properties of black nephrite jade from Western Australia are studied by Fourier transform infrared (FTIR) spectroscopy using both transmission and specular reflectance techniques in the 4000-400 cm-1 wavenumber region. The infrared absorption peaks in the 3700-3600 cm-1 region which are due to the O-H stretching mode provides a quantitative analysis of the Fe/(Fe+Mg) ratio in the mineral composition of jade samples. The Fe/(Fe+Mg) percentage in black nephrite is found to be higher than that in green nephrite, but comparable to that of actinolite (iron-rich nephrite). This implies that the mineralogy of black nephrite is closer to actinolite than tremolite. The jade is also characterized using Raman spectroscopy in the 1200-200 cm-1 region. Results from FTIR and Raman spectroscopic data of black nephrite jade are compared with those of green nephrite jade from New Zealand and jadeite jade from Myanmar. Black nephrite appears to have a slightly different chemical composition from green nephrite. Spectra from FTIR and Raman spectroscopic techniques were found to be useful in differentiating black nephrite, green nephrite, and green jadeite jades. Furthermore, data on refractive index, specific gravity, and hardness of black nephrite jade are measured and compared with those of green nephrite and of jadeite jade.

  5. Mid-infrared study of stones from the Sutter's Mill meteorite

    NASA Astrophysics Data System (ADS)

    Nuevo, Michel; Sandford, Scott A.; Flynn, George J.; Wirick, Susan

    2014-11-01

    The Sutter's Mill meteorite fell in northern California on April 22, 2012. Several fragments of the meteorite were recovered, some of them shortly after the fall, others several days later after a heavy rainstorm. In this work, we analyzed several samples of four fragments―SM2, SM12, SM20, and SM30―from the Sutter's Mill meteorite with two infrared (IR) microscopes operating in the 4000-650 cm-1 (2.5-15.4 μm) range. Spectra show absorption features associated with minerals such as olivines, phyllosilicates, carbonates, and possibly pyroxenes, as well as organics. Spectra of specific minerals vary from one particle to another within a given stone, and even within a single particle, indicating a nonuniform mineral composition. Infrared features associated with aliphatic CH2 and CH3 groups associated with organics are also seen in several spectra. However, the presence of organics in the samples studied is not clear because these features overlap with carbonate overtone bands. Finally, other samples collected within days after the rainstorm show evidence for bacterial terrestrial contamination, which indicates how quickly meteorites can be contaminated on such small scales.

  6. Near-Infrared Spectroscopic Study of AA Tau: Water and OH Observations

    NASA Astrophysics Data System (ADS)

    Brown, Logan Ryan; Gibb, Erika

    2014-06-01

    To understand our own solar origins, we must investigate the composition of the protoplanetary disk from which the solar system formed. To infer this, we study analogs to the early solar system called T Tauri stars. These objects are low-mass, pre-main sequence stars surrounded by circumstellar disks of material from which planets are believed to form. We present high-resolution (λ/Δλ˜25,000), near-infrared spectroscopic data from the T Tauri star AA Tau using NIRSPEC at the Keck II telescope, located on Mauna Kea, HI, taken in 2009 and 2010. AA Tau has a close to edge-on geometry, with an inclination of 70° ± 10° (Donati et al. 2010). Objects must have a nearly edge-on inclination for the disk to be sampled via absorption line spectroscopy. We observed strong absorption lines of both water and OH to which a spectroscopic model was fit in order for us to determine column density and rotational temperature. These near-infrared observations complement the work being done with ALMA, allowing us to probe the inner most disk regions and the chemistry contained within while ALMA primarily samples and is most sensitive to the outer disk.

  7. A multispectral study of an extratropical cyclone with Nimbus 3 medium resolution infrared radiometer data

    NASA Technical Reports Server (NTRS)

    Holub, R.; Shenk, W. E.

    1973-01-01

    Four registered channels (0.2 to 4, 6.5 to 7, 10 to 11, and 20 to 23 microns) of the Nimbus 3 Medium Resolution Infrared Radiometer (MRIR) were used to study 24-hr changes in the structure of an extratropical cyclone during a 6-day period in May 1969. Use of a stereographic-horizon map projection insured that the storm was mapped with a single perspective throughout the series and allowed the convenient preparation of 24-hr difference maps of the infrared radiation fields. Single-channel and multispectral analysis techniques were employed to establish the positions and vertical slopes of jetstreams, large cloud systems, and major features of middle and upper tropospheric circulation. Use of these techniques plus the difference maps and continuity of observation allowed the early detection of secondary cyclones developing within the circulation of the primary cyclone. An automated, multispectral cloud-type identification technique was developed, and comparisons that were made with conventional ship reports and with high-resolution visual data from the image dissector camera system showed good agreement.

  8. Spectroscopic Study of Terahertz Generation in Mid-Infrared Quantum Cascade Lasers

    PubMed Central

    Jiang, Yifan; Vijayraghavan, Karun; Jung, Seungyong; Jiang, Aiting; Kim, Jae Hyun; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus C.; Belkin, Mikhail A.

    2016-01-01

    Terahertz quantum cascade laser sources based on intra-cavity difference-frequency generation are currently the only room-temperature mass-producible diode-laser-like emitters of coherent 1–6 THz radiation. Device performance has improved dramatically over the past few years to reach milliwatt-level power output and broad tuning from 1.2 to 5.9 THz, all at room-temperature. Terahertz output in these sources originates from intersubband optical nonlinearity in the laser active region. Here we report the first comprehensive spectroscopic study of the optical nonlinearity and investigate its dependence on the mid-infrared pump frequencies. Our work shows that the terahertz generation efficiency can vary by a factor of 2 or greater depending on the spectral position of the mid-infrared pumps for a fixed THz difference-frequency. We have also measured for the first time the linewidth for transitions between the lower quantum cascade laser states, which is critical for determining terahertz nonlinearity and predicting optical loss in quantum cascade laser waveguides. PMID:26879901

  9. Shadowing the soft x-ray background by infrared cirrus: A study of selected regions

    NASA Technical Reports Server (NTRS)

    Wang, Q. Daniel; Yu, Ka Chun

    1995-01-01

    Using the ROSAT and IRAS data achieves, we studied shadows in the diffuse 0.25 keV background toward infrared cirrus clouds to infer the distribution of the hot interstellar medium (ISM). Surprisingly, we found that anticorrelation between infrared emission from cirrus clouds and background x-ray intensity was present in all five galactic latitude (b approx. greater than 25 deg) fields that we selected. In two fieds, the anticorrelation is more than 30% deep, and shows particularly convincing evidence that they are due to x-ray absorption by the clouds. Assuming an average density for the local x-ray-emitting gas (T approximately 10(exp 6) K), we estimated the minimum distances to the clouds based on our best-fit x-ray intensities originating in front of the clouds. These distances are in the range of 60 to 160 pc. Therefore, we conclude that there are a considerable number of degree-size, x-ray-absorbing gas clouds at approximately 10(exp 2) pc and that large amounts of x-ray-emitting gas exist in regions beyonds these clouds.

  10. An experimental study on infrared drying kinetics of an aqueous adhesive supported by polymer composite

    NASA Astrophysics Data System (ADS)

    Allanic, Nadine; Le Bideau, Pascal; Glouannec, Patrick; Deterre, Rémi

    2016-04-01

    The infrared drying of an aqueous polymer emulsion spread on a thin composite flat film is experimentally studied. The composite film is composed of polyamide fibers supported by a poly(vinyl fluoride) film. The aqueous polymer is an Ethylene Vinyl Acetate emulsion playing the role of adhesive. It is spread over the film with a low thickness, about one hundred micrometers. The aim of this work is to understand the effects of the presence of fibers on the drying of this thin-layer product. With this in mind, a specific laboratory set up composed of a near infrared heater is used in order to get the drying kinetics. First, incident heat fluxes received at the product surface and transmittances of materials (semi-transparent medium) are measured with an ad-hoc heat flux sensor. Then, many experiments are performed with and without fibers. For linking the final moisture content to the fibers thermal and hydric behavior, a microscopic analysis of the dried samples is investigated. This analysis is performed for two thicknesses of polymer corresponding to two covering rates of fibers.

  11. Studies in Above- and Below-Threshold Harmonics in Argon with an Infrared Femtosecond Laser

    NASA Astrophysics Data System (ADS)

    Chew, Andrew; Yin, Yanchun; Li, Jie; Ren, Xiaoming; Cunningham, Eric; Wu, Yi; Chang, Zenghu

    2016-05-01

    We investigate and compare the above- and below-threshold harmonics in Argon gas using our recently-developed 1 kHz, two-cycle (11.4 fs), 3mJ, and carrier-envelope-phase(CEP)-stable laser at 1.6 μm. Such ultraviolet pulses can serve as pump or probe for studying dynamics in atoms and molecules. Unlike high harmonics with photon energy well above the ionization potential, the mechanism for generating harmonics near the ionization threshold is still under intense investigation. Previous work by Chini et al. on below-threshold harmonics was done using a 0.8 μm few-cycle Ti:Sapphire spectrally-broadened source with energy up to 300 μJ. It has been predicted by theory that free-free transitions dominate the below threshold harmonic generation as the laser wavelength increase from near infrared to mid-infrared. We are therefore interested in investigating how using a longer wavelength laser might lead to changes to the behavior of below-threshold harmonics when we vary various parameters. We report the π-periodity CEP dependence and ellipticity dependence of the above- and below-threshold harmonics. This material was based on work supported by National Science Foundation (1068604), Army Research Office (W911NF-14-1-0383), Air Force Office of Scientific Research (FA9550-15-1-0037) and the DARPA PULSE program by a Grant from AMRDEC (W31P4Q1310017).

  12. Analytical study of Yang-Mills theory in the infrared from first principles

    NASA Astrophysics Data System (ADS)

    Siringo, Fabio

    2016-06-01

    Pure Yang-Mills SU(N) theory is studied in the Landau gauge and four dimensional space. While leaving the original Lagrangian unmodified, a double perturbative expansion is devised, based on a massive free-particle propagator. In dimensional regularization, all diverging mass terms cancel exactly in the double expansion, without the need to include mass counterterms that would spoil the symmetry of the Lagrangian. No free parameters are included that were not in the original theory, yielding a fully analytical approach from first principles. The expansion is safe in the infrared and is equivalent to the standard perturbation theory in the UV. At one-loop, explicit analytical expressions are given for the propagators and the running coupling and are found in excellent agreement with the data of lattice simulations. A universal scaling property is predicted for the inverse propagators and shown to be satisfied by the lattice data. Higher loops are found to be negligible in the infrared below 300 MeV where the coupling becomes small and the one-loop approximation is under full control.

  13. Picosecond laser micromachining of nitinol and platinum-iridium alloy for coronary stent applications

    NASA Astrophysics Data System (ADS)

    Muhammad, N.; Whitehead, D.; Boor, A.; Oppenlander, W.; Liu, Z.; Li, L.

    2012-03-01

    The demand for micromachining of coronary stents by means of industrial lasers rises quickly for treating coronary artery diseases, which cause more than one million deaths each year. The most widely used types of laser for stent manufacturing are Nd:YAG laser systems with a wavelength of 1064 nm with pulse lengths of 10-3-10-2 seconds. Considerable post-processing is required to remove heat-affected zones (HAZ), and to improve surface finishes and geometry. Using a third harmonic laser radiation of picosecond laser (6×10-12 s pulse duration) in UV range, the capability of the picosecond laser micromachining of nitinol and platinum-iridium alloy for coronary stent applications are presented. In this study dross-free cut of nitinol and platinum-iridium alloy tubes are demonstrated and topography analysis of the cut surface is carried out. The HAZ characteristics have been investigated by means of microscopic examinations and measurement of micro-hardness distribution near the cut zones.

  14. Diffraction of picosecond bulk longitudinal and shear waves in micron thick films

    NASA Astrophysics Data System (ADS)

    Audoin, B.; Perton, M.; Chigarev, N.; Rossignol, C.

    2008-01-01

    Investigation of thin metallic film properties by means of picosecond ultrasonics [C. Thomsen et al., Phys. Rev. Lett. 53, 989 (1984)] has been under the scope of several studies. Generation of longitudinal and shear waves [T. Pézeril et al., Phys. Rev. B 73, 132301 (2006); O. Matsuda et al., Phys. Rev. Lett. 93, 095501 (2004)] with a wave vector normal to the film free surface has been demonstrated. Such measurements cannot provide complete information about properties of anisotropic films. Extreme focusing of a laser pump beam (≈0.5 μm) on the sample surface has recently allowed us to provide evidence of picosecond acoustic diffraction in thin metallic films (≈1 μm) [C. Rossignol et al., Phys. Rev. Lett. 94, 166106 (2005)]. The resulting longitudinal and shear wavefronts propagate at group velocity through the bulk of the film. To interpret the received signals, source directivity diagrams are calculated taking into account material anisotropy, optical penetration, and laser beam width on the sample surface. It is shown that acoustic diffraction increases with optical penetration, so competing with the increasing of directivity caused by beam width. Reflection with mode conversion at the film-substrate interface is discussed.

  15. Nanoparticles based laser-induced surface structures formation on mesoporous silicon by picosecond laser beam interaction

    NASA Astrophysics Data System (ADS)

    Talbi, A.; Petit, A.; Melhem, A.; Stolz, A.; Boulmer-Leborgne, C.; Gautier, G.; Defforge, T.; Semmar, N.

    2016-06-01

    In this study, laser induced periodic surface structures were formed on mesoporous silicon by irradiation of Nd:YAG picosecond pulsed laser beam at 266 nm wavelength at 1 Hz repetition rate and with 42 ps pulse duration. The effects of laser processing parameters as laser beam fluence and laser pulse number on the formation of ripples were investigated. Scanning electron microscopy and atomic force microscopy were used to image the surface morphologies and the cross section of samples after laser irradiation. At relatively low fluence ∼20 mJ/cm2, ripples with period close to the laser beam wavelength (266 nm) and with an always controlled orientation (perpendicular to the polarization of ps laser beam) appeared after a large laser pulse number of 12,000. It has been found that an initial random distribution of SiOx nanoparticles is periodically structured with an increase of the laser pulse number. Finally, it is experimentally demonstrated that we formed a 100 nm liquid phase under the protusion zones including the pores in the picosecond regime.

  16. Porous microstructures induced by picosecond laser scanning irradiation on stainless steel surface

    NASA Astrophysics Data System (ADS)

    Liu, Bin; Jiang, Gedong; Wang, Wenjun; Mei, Xuesong; Wang, Kedian; Cui, Jianlei; Wang, Jiuhong

    2016-03-01

    A study of porous surfaces having micropores significantly smaller than laser spot on the stainless steel 304L sample surface induced by a picosecond regenerative amplified laser, operating at 1064 nm, is presented. Variations in the interaction regime of picosecond laser pulses with stainless steel surfaces at peak irradiation fluences(Fpk=0.378-4.496 J/cm2) with scanning speeds(v=125-1000 μm/s) and scan line spacings(s=0-50 μm) have been observed and thoroughly investigated. It is observed that interactions within these parameters allows for the generation of well-defined structured surfaces. To investigate the formation mechanism of sub-focus micropores, the influence of key processing parameters has been analyzed using a pre-designed laser pulse scanning layout. Appearances of sub-focus ripples and micropores with the variation of laser peak fluence, scanning speed and scan line spacing have been observed. The dependencies of surface structures on these interaction parameters have been preliminarily verified. With the help of the experimental results obtained, interaction parameters for fabrication of large area homogeneous porous structures with the feature sizes in the range of 3-15 μm are determined.

  17. High-power, fiber-laser-pumped, picosecond optical parametric oscillator based on MgO:sPPLT.

    PubMed

    Kumar, S Chaitanya; Ebrahim-Zadeh, M

    2011-12-19

    We report a stable, high-power, mid-infrared synchronously-pumped optical parametric oscillator (SPOPO) based on MgO:sPPLT, pumped by a 1064 nm, picosecond Yb-fiber laser operating at a repetition rate of 81.1 MHz. The singly resonant SPOPO is tunable over 1531-1642 nm (111 nm) in the near-infrared signal and 3022-3488 nm (466 nm) in the mid-infrared idler, providing a total tuning range of 577 nm. Careful optimization of output coupling results in a signal output power as high as 4.3 W at 1593 nm and a mid-infrared idler power of 2 W at 3204 nm for 13.4 W of pump power at a total extraction efficiency of 47%. The SPOPO can be operated near room temperature, down to 30 °C, and exhibits passive peak-to-peak power stability better than 8.6% at 1568 nm (signal) and 8.2% at 3310 nm (idler) over 13 hours at full power. The output signal pulses have duration of 17.5 ps, with a FWHM spectral bandwidth of 1.4 nm centered at 1568 nm. PMID:22274250

  18. Picosecond pulses compression at 1053-nm center wavelength by using a gas-filled hollow-core fiber compressor

    NASA Astrophysics Data System (ADS)

    Huang, Zhi-Yuan; Wang, Ding; Leng, Yu-Xin; Dai, Ye

    2015-01-01

    We theoretically study the nonlinear compression of picosecond pulses with 10-mJ of input energy at the 1053-nm center wavelength by using a one-meter-long gas-filled hollow-core fiber (HCF) compressor and considering the third-order dispersion (TOD) effect. It is found that when the input pulse is about 1 ps/10 mJ, it can be compressed down to less than 20 fs with a high transmission efficiency. The gas for optimal compression is krypton gas which is filled in a HCF with a 400-μm inner diameter. When the input pulse duration is increased to 5 ps, it can also be compressed down to less than 100 fs efficiently under proper conditions. The results show that the TOD effect has little impact on picosecond pulse compression and the HCF compressor can be applied on compressing picosecond pulses efficiently with a high compression ratio, which will benefit the research of high-field laser physics. Project supported by the National Natural Science Foundation of China (Grant Nos. 11204328, 61221064, 61078037, 11127901, and 11134010), the National Basic Research Program of China (Grant No. 2011CB808101), the Commission of Science and Technology of Shanghai, China (Grant No. 12dz1100700), the Natural Science Foundation of Shanghai, China (Grant No. 13ZR1414800), and the International Science and Technology Cooperation Program of China (Grant No. 2011DFA11300).

  19. Long-Wave Infrared Functional Brain Imaging in Human: A Pilot Study

    PubMed Central

    Joyal, Christian C; Henry, Mylene

    2013-01-01

    Although some authors suggest to use Long-Wave Infrared (LWIR) sensors to evaluate brain functioning, the link between emissions of LWIR and mental effort is not established. The goal of this pilot study was to determine whether frontal LWIR emissions vary during execution of neuropsychological tasks known to differentially activate the pre-frontal cortex (simple color presentations, induction of the Stroop effect, and a gambling task with real money). Surprisingly, LWIR emissions as measured with bilateral frontal sensors in 47 participants significantly differed between tasks, in the supposed direction (Colorstudy suggests that investigations of convergent validity with other types of brain imaging techniques can be initiated with LWIR imaging. If confirmed, this technique would offer a simple and accessible method to evaluate frontal cortex activation. PMID:23400426

  20. Long-wave infrared functional brain imaging in human: a pilot study.

    PubMed

    Joyal, Christian C; Henry, Mylene

    2013-01-01

    Although some authors suggest to use Long-Wave Infrared (LWIR) sensors to evaluate brain functioning, the link between emissions of LWIR and mental effort is not established. The goal of this pilot study was to determine whether frontal LWIR emissions vary during execution of neuropsychological tasks known to differentially activate the pre-frontal cortex (simple color presentations, induction of the Stroop effect, and a gambling task with real money). Surprisingly, LWIR emissions as measured with bilateral frontal sensors in 47 participants significantly differed between tasks, in the supposed direction (Colorstudy suggests that investigations of convergent validity with other types of brain imaging techniques can be initiated with LWIR imaging. If confirmed, this technique would offer a simple and accessible method to evaluate frontal cortex activation. PMID:23400426

  1. Study of the heat transfer in solids using infrared photothermal radiometry and simulation by COMSOL Multiphysics.

    PubMed

    Suarez, V; Hernández Wong, J; Nogal, U; Calderón, A; Rojas-Trigos, J B; Juárez, A G; Marín, E

    2014-01-01

    It is reported the study of the heat transfer through a homogeneous and isotropic solid exited by square periodic light beam on its front surface. For this, we use the Infrared Photothermal Radiometry in order to obtain the evolution of the temperature difference on the rear surface of three samples, silicon, copper and wood, as a function of the exposure time. Also, we solved the heat transport equation for this problem with the boundary conditions congruent with the physical situation, by means of numerical simulation based in finite element analysis. Our results show a good agreement between the experimental and numerical simulated results, which demonstrate the utility of this methodology for the study of the thermal response of solids. PMID:23684428

  2. Do GSM 900MHz signals affect cerebral blood circulation? A near-infrared spectrophotometry study

    NASA Astrophysics Data System (ADS)

    Wolf, Martin; Haensse, Daniel; Morren, Geert; Froehlich, Juerg

    2006-06-01

    Effects of GSM 900MHz signals (EMF) typical for a handheld mobile phone on the cerebral blood circulation were investigated using near-infrared spectrophotometry (NIRS) in a three armed (12W/kg, 1.2W/kg, sham), double blind, randomized crossover trial in 16 healthy volunteers. During exposure we observed borderline significant short term responses of oxyhemoglobin and deoxyhemoglobin concentration, which correspond to a decrease of cerebral blood flow and volume and were smaller than regular physiological changes. Due to the relatively high number of statistical tests, these responses may be spurious and require further studies. There was no detectable dose-response relation or long term response within 20min. The detection limit was a fraction of the regular physiological changes elicited by functional activation. Compared to previous studies using PET, NIRS provides a much higher time resolution, which allowed investigating the short term effects efficiently, noninvasively, without the use of radioactive tracers and with high sensitivity.

  3. Mid-infrared Molecular Emission Studies from Energetic Materials using Laser-Induced Breakdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Brown, Ei; Hommerich, Uwe; Yang, Clayton; Trivedi, Sudhir; Samuels, Alan; Snyder, Peter

    2011-10-01

    Laser-induced breakdown spectroscopy (LIBS) is a powerful diagnostic tool for detection of trace elements by monitoring the atomic and ionic emission from laser-induced plasmas. The laser-induced plasma was produced by focusing a 30 mJ pulsed Nd:YAG laser (1064 nm) to dissociate, atomize, and ionize target molecules. In this work, LIBS emissions in the mid-infrared (MIR) region were studied for potential applications in chemical, biological, and explosives (CBE) sensing. We report on the observation of MIR emissions from energetic materials (e.g. ammonium compounds) due to laser-induced breakdown processes. All samples showed LIBS-triggered oxygenated breakdown products as well as partially dissociated and recombination molecular species. More detailed results of the performed MIR LIBS studies on the energetic materials will be discussed at the conference.

  4. Wide Field Infra-Red Survey Telescope (WFIRST) 2.4-Meter Mission Study

    NASA Technical Reports Server (NTRS)

    Content, D.; Aaron, K.; Alplanalp, L.; Anderson, K.; Capps, R.; Chang, Z.; Dooley, J.; Egerman, R.; Goullioud, R.; Klein, D.; Kruk, J.; Kuan, G.; Melton, M.; Ruffa, J.; Underhill, M.; Buren, D. Van

    2013-01-01

    The most recent study of the Wide Field Infrared Survey Telescope (WFIRST) mission is based on reuse of an existing 2.4m telescope. This study was commissioned by NASA to examine the potential science return and cost effectiveness of WFIRST by using this significantly larger aperture telescope. We review the science program envisioned by the WFIRST 2012-2013 Science Definition Team (SDT), an overview of the mission concept, and the telescope design and status. Comparisons against the previous 1.3m and reduced cost 1.1m WFIRST design concepts are discussed. A significant departure from past point designs is the option for serviceability and the geostationary orbit location which enables servicing and replacement instrument insertion later during mission life. Other papers at this conference provide more in depth discussion of the wide field instrument and the optional exoplanet imaging coronagraph instrument.

  5. Fourier transform infrared and Raman spectroscopy studies on magnetite/Ag/antibiotic nanocomposites

    NASA Astrophysics Data System (ADS)

    Ivashchenko, Olena; Jurga-Stopa, Justyna; Coy, Emerson; Peplinska, Barbara; Pietralik, Zuzanna; Jurga, Stefan

    2016-02-01

    This article presents a study on the detection of antibiotics in magnetite/Ag/antibiotic nanocomposites using Fourier transform infrared (FTIR) and Raman spectroscopy. Antibiotics with different spectra of antimicrobial activities, including rifampicin, doxycycline, cefotaxime, and ceftriaxone, were studied. Mechanical mixtures of antibiotics and magnetite/Ag nanocomposites, as well as antibiotics and magnetite nanopowder, were investigated in order to identify the origin of FTIR bands. FTIR spectroscopy was found to be an appropriate technique for this task. The spectra of the magnetite/Ag/antibiotic nanocomposites exhibited very weak (for doxycycline, cefotaxime, and ceftriaxone) or even no (for rifampicin) antibiotic bands. This FTIR "invisibility" of antibiotics is ascribed to their adsorbed state. FTIR and Raman measurements show altered Csbnd O, Cdbnd O, and Csbnd S bonds, indicating adsorption of the antibiotic molecules on the magnetite/Ag nanocomposite structure. In addition, a potential mechanism through which antibiotic molecules interact with magnetite/Ag nanoparticle surfaces is proposed.

  6. Thermal and cryogenic design study for space infrared telescope facility (SIRTF)

    NASA Technical Reports Server (NTRS)

    Urbach, A. R.; Kelly, T.; Poley, R.

    1984-01-01

    A study was conducted to determine the ability of an all superfluid helium design to meet the performance requirements of background limited to 200 micrometer, and a two year lifetime for a one meter class free flying infrared observatory. Both a 98 deg and 28.5 deg inclination orbits were examined, and aperture shade designs were developed for both orbits. A unique forebaffle cooling design significantly reduces the sensitivity to aperture heat loads. With certain restrictions on observing modes, the study determined that an all superfluid helium Dewar will meet the temperature and lifetime requirements. A dual cryogen SFHe/SH2 system was also investigated for the 28.5 deg orbit and found to provide a more constant forebaffle temperature but with only a slight improvement in lifetime.

  7. A far-infrared radiative closure study in the Arctic: Application to water vapor

    NASA Astrophysics Data System (ADS)

    Delamere, J. S.; Clough, S. A.; Payne, V. H.; Mlawer, E. J.; Turner, D. D.; Gamache, R. R.

    2010-09-01

    Far-infrared (λ > 15.0 μm) (far-IR) radiative processes provide a large fraction of Earth's outgoing longwave radiation and influence upper tropospheric vertical motion. Water vapor, because of its abundance and strong absorption properties over an extended spectral range, is the primary source of these radiative processes. Historically, the lack of spectrally resolved radiometric instruments and the opacity of the lower atmosphere have precluded extensive studies of far-IR water vapor absorption properties. The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program has organized a series of field experiments, the Radiative Heating in Underexplored Bands Campaigns (RHUBC), to address this deficiency. The first phase of RHUBC took place in 2007 at the ARM North Slope of Alaska Climate Research Facility. Measurements taken before and during this campaign have provided the basis for a clear-sky radiative closure study aimed at reducing key uncertainties associated with far-IR radiative transfer models. Extended-range Atmospheric Emitted Radiance Interferometer infrared radiance observations taken in clear sky conditions were compared against calculations from the Line-By-Line Radiative Transfer Model. The water vapor column amounts used in these calculations were retrieved from 183 GHz radiometer measurements. The uncertainty in these integrated water vapor retrievals is approximately 2%, a notable improvement over past studies. This far-IR radiative closure study resulted in an improvement to the Mlawer-Tobin Clough-Kneiyzs-Davies (MT_CKD) water vapor foreign continuum model and updates to numerous, far-IR water vapor line parameters from their values in the circa 2006 version of the HITRAN molecular line parameter database.

  8. Investigating protein structure and folding with coherent two-dimensional infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Baiz, Carlos; Peng, Chunte; Reppert, Michael; Jones, Kevin; Tokmakoff, Andrei

    2012-02-01

    We present a new technique to quantitatively determine the secondary structure composition of proteins in solution based on ultrafast two-dimensional infrared (2DIR) spectroscopy. The percentage of residues in alpha-helix, beta-sheet, and unstructured conformations is extracted from a principal component analysis of the measured amide-I 2DIR spectra. We benchmark the method against a library of commercially-available proteins by comparing the predicted structure compositions with the x-ray crystal structures. The new technique offers sub-picosecond time resolution, and can be used to study systems that are difficult to study with conventional methods such as gels, intrinsically disordered peptides, fibers, and aggregates. We use the technique to investigate the structural changes and timescales associated with folding and denaturing of small proteins via equilibrium and transient temperature-jump 2DIR spectroscopy.

  9. Emissivity and Anisothermality Studies at the Lunar Poles with Diviner's Far Infrared Channels

    NASA Astrophysics Data System (ADS)

    Aye, K.; Paige, D. A.; Siegler, M. A.; Greenhagen, B. T.

    2013-12-01

    The Diviner Radiometer on the Lunar Reconnaissance Orbiter (LRO) is measuring surface temperatures in 7 different thermal channels, 4 of them in the wavelength area classically defined as far infrared, starting at 13 microns, and ending with the longest wavelength channel at 400 microns. The surface temperatures derived from these thermal infrared measurements at the lunar poles indicate some of the coldest temperatures measured in the solar system of around 20 K. This work aims to disprove the null hypothesis that other effects like wavelength and temperature dependent emissivities are responsible for a reduced radiant exitance and the subsequently low derived surface temperature. To address the wavelength dependency of emissivity we are comparing nighttime temperatures over time (cooling curves) in between the different far infrared channels at selected locations. The locations have to be selected for low rock abundance to minimize anisothermality effects influencing the cooling curves. For this we are applying the method of lunar surface rock abundance using Diviner data as described in Bandfield et al. (2011), that has not been done so far at latitudes poleward of 60°. To avoid the large influence of slopes on the surface temperatures, the main reason for the latitude restriction in Bandfield et al. (2011) we use recent LOLA altimeter data to resolve any slopes that could influence the cooling curve at a chosen location. Having selected a location relatively free of anisothermalities and taking their effect into account, general differences in the cooling curves of the different Diviner wavelengths are interpreted as wavelength-dependent emissivities. To address the potential temperature dependency of emissivity, we are studying how the parameters of a mid-temperature range exponential fit to the cooling curve fit from approx. 250 to 70K, where we do not expect a temperature dependence of emissivity, extends to highest and lowest temperatures at the poles

  10. Study and design of modularized real-time processor for infrared thermal image

    NASA Astrophysics Data System (ADS)

    Chen, Qian; Bai, Lianfa; Fang, Ming

    2001-09-01

    The new-type infrared thermal imaging technology should be a combination of infrared detecting and real-time processing. The intelligence ,modularity, miniature and real-time are the developmental subjects in infrared image processing In this paper, on the basis of the researching in the architecture feature of nowadays digital image processing system, the development. ideas and technology approaches of infrared image real-time processing are described .The new types of structure and technique of infrared thermal image real-time processing--adaptive time-space sequence flow network construction and feature weighting adaptive real-time processing method are presented firstly. According to the infrared image characteristics, the histogram of infrared image and the correlation inside frame or interframe are analyzed in detail, and some image enhancement methods are taken. These thermal image processing theory and algorithm are realized by hardware circuit. In PCB design, additional circuit noise and digital pulse interference are discussed deeply. On the basis of many experiments, the PCB design regulations with anti-interference are established. Finally, the Modularized Infrared Image Real-time Processor is finished with noise suppression and image enhancement. The design and circuit construction of the modularized infrared image real-time processor are given.

  11. Vibrational dynamics of azide-derivatized amino acids studied by nonlinear infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Okuda, Masaki; Ohta, Kaoru; Tominaga, Keisuke

    2015-06-01

    Recently, biomolecules which are labeled by azide or thiocyanate groups in solutions and proteins have been studied to examine microscopic environment around a solute by nonlinear infrared (IR) spectroscopy. In this study, we have performed two-dimensional infrared (2D-IR) spectroscopy to investigate the vibrational frequency fluctuations of two different azide-derivatized amino acids, Ala (N3-Ala) and Pro (N3-Pro), and N3- in water. From the 2D-IR experiments, it was found that the frequency-frequency time correlation function (FFTCF) of solute can be modeled by a delta function plus an exponential function and constant. FFTCF for each probe molecule has a decay component of about 1 ps, and this result suggests that the stretching mode of the covalently bonded azide group is sensitive to the fluctuations of hydrogen bond network system, as found in previous studies of N3- in water. In contrast to FFTCF of N3-, FFTCF of the azide-derivatized amino acids contains static component. This static component may reflect dynamics of water affected by the solutes or the structural fluctuations of the solute itself. We also performed the IR pump-probe measurements for the probe molecules in water in order to investigate vibrational energy relaxation (VER) and reorientational relaxation. It was revealed that the charge fluctuations in the azide group are significant for the VER of this mode in water, reflecting that the VER rate of N3- is faster than those of the azide-derivatized amino acids. While the behaviors of the anisotropy decay of N3-Ala and N3- are similar to each other, the anisotropy decay of N3-Pro contains much slower decaying component. By considering the structural difference around the vibrational probe between N3-Ala and N3-Pro, it is suggested that the structural freedom of the probe molecules can affect the reorientational processes.

  12. Infrared dermal thermography on diabetic feet soles to predict ulcerations: a case study

    NASA Astrophysics Data System (ADS)

    Liu, Chanjuan; van der Heijden, Ferdi; Klein, Marvin E.; van Baal, Jeff G.; Bus, Sicco A.; van Netten, Jaap J.

    2013-03-01

    Diabetic foot ulceration is a major complication for patients with diabetes mellitus. If not adequately treated, these ulcers may lead to foot infection, and ultimately to lower extremity amputation, which imposes a major burden to society and great loss in health-related quality of life for patients. Early identification and subsequent preventive treatment have proven useful to limit the incidence of foot ulcers and lower extremity amputation. Thus, the development of new diagnosis tools has become an attractive option. The ultimate objective of our project is to develop an intelligent telemedicine monitoring system for frequent examination on patients' feet, to timely detect pre-signs of ulceration. Inflammation in diabetic feet can be an early and predictive warning sign for ulceration, and temperature has been proven to be a vicarious marker for inflammation. Studies have indicated that infrared dermal thermography of foot soles can be one of the important parameters for assessing the risk of diabetic foot ulceration. This paper covers the feasibility study of using an infrared camera, FLIR SC305, in our setup, to acquire the spatial thermal distribution on the feet soles. With the obtained thermal images, automated detection through image analysis was performed to identify the abnormal increased/decreased temperature and assess the risk for ulceration. The thermography for feet soles of patients with diagnosed diabetic foot complications were acquired before the ordinary foot examinations. Assessment from clinicians and thermography were compared and follow-up measurements were performed to investigate the prediction. A preliminary case study will be presented, indicating that dermal thermography in our proposed setup can be a screening modality to timely detect pre-signs of ulceration.

  13. The use of near infrared Fourier Transform techniques in the study of surface enhanced Raman spectra

    NASA Astrophysics Data System (ADS)

    Fleischmann, M.; Sockalingum, D.; Musiani, M. M.

    Near infrared Fourier Transform Raman spectroscopy has been used to study the SERS of a number of electrode-solution interfaces. These measurements are illustrated by the following examples: the adsorption of pyridine on Ag, Cu and An surfaces; the adsorption of ferri- and ferrocyanide ions on An electrodes in two different support electrolytes; the behaviour of the corrosion inhibitors benzotriazole and 2-aminopyrimidine at Cu surfaces. Measurements of the DSERS spectra of pyridine at Ag electrodes and of normal Raman spectra of pyridine at Pt electrodes are also reported. The results are also compared with data taken by conventional methods in the visible region and the advantages of this newly developed technique are assessed.

  14. In Situ Infrared Ellipsometry for Protein Adsorption Studies on Ultrathin Smart Polymer Brushes in Aqueous Environment

    DOE PAGESBeta

    Kroning, Annika; Furchner, Andreas; Aulich, Dennis; Bittrich, Eva; Rauch, Sebastian; Uhlmann, Petra; Eichhorn, Klaus-Jochen; Seeber, Michael; Luzinov, Igor; Kilbey, S. Michael; et al

    2015-02-10

    The protein-adsorbing and -repelling properties of various smart nanometer-thin polymer brushes with high potential for biosensing and biomedical applications are studied by in-situ infrared-spectroscopic ellipsometry (IRSE). IRSE as a highly sensitive non-destructive technique allows us to investigate protein adsorption on polymer brushes in aqueous environment in dependence of external stimuli like temperature and pH. These stimuli are, for instance, relevant in switchable mixed brushes containing poly(N-isopropyl acrylamide) and poly(acrylic acid), respectively. We use such brushes as model surfaces for controlling protein adsorption of human serum albumin and human fibrinogen. IRSE can distinguish between polymer-specific vibrational bands, which yield insights intomore » the hydration state of the brushes, and changes in the protein-specific amide bands, which are related to changes of the protein secondary structure.« less

  15. NMR and Infrared Study of Thermal Oxidation of cis-1, 4-Polybutadiene

    NASA Technical Reports Server (NTRS)

    Gemmer, Robert V.; Golub, Morton A.

    1978-01-01

    A study of the microstructural changes occuring in CB during thermal, uncatalyzed oxidation was carried out. Although the oxidation of CB is accompanied by extensive crosslinking with attendant insolubilization, it was found possible to follow the oxidation of solid CB directly with C-13 NMR spectroscopy. The predominant products appearing in the C-13 NMR spectra of oxidized CB are epoxides. The presence of lesser amounts of alcohols, peroxides, and carbonyl structures was adduced from complementary infrared and NMR spectra of soluble extracts obtained from the oxidized, crosslinked CB. This distribution of functional groups contrasts with that previously reported for the autooxidation of 1,4-polyisoprene. The difference was rationalized in terms of the relative stabilities of intermediate radical species involved in the autoxidation of CB and 1,4-polyisoprene.

  16. Infrared Spectral Studies of the Thermally-Driven Chemistry Present on Icy Satellites

    NASA Technical Reports Server (NTRS)

    Loeffler, Mark J.; Hudson, Reggie L.

    2012-01-01

    Remote sensing of Jupiters icy satellites has revealed that even though their surfaces arc composed mostly of water ice, molecules such as SO2, CO2, H2O2. O2, and O3 also are present. On Europa, a high radiation flux is believed to play a role in the formation of many of the minor species detected, and numerous laboratory studies have been devoted to explore this hypothesis. In this presentation we will discuss some of our recent research on another alteration pathway, thermally-driven chemical reactions, which are also important for understanding the chemical evolution of Europa's surface and sub-surface ices. We will focus on the infrared spectra of and reactions between H2O, SO2 and H2O2, at 80 - 130 K.

  17. Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices

    SciTech Connect

    Tanskanen, Hanna; Khriachtchev, Leonid; Raesaenen, Markku; Feldman, Vladimir I.; Sukhov, Fedor F.; Orlov, Aleksei Yu.; Tyurin, Daniil A.

    2005-08-08

    Vinyl radicals produced by annealing-induced reaction of mobilized hydrogen atoms with acetylene molecules in solid noble-gas matrices (Ar, Kr, and Xe) were characterized by Fourier transform infrared and electron paramagnetic resonance (EPR) spectroscopies. The hydrogen atoms were generated from acetylene by UV photolysis or fast electron irradiation. Two vibrational modes of the vinyl radical ({nu}{sub 7} and {nu}{sub 5}) were assigned in IR absorption studies. The assignment is based on data for various isotopic substitutions (D and {sup 13}C) and confirmed by comparison with the EPR measurements and density-functional theory calculations. The data on the {nu}{sub 7} mode is in agreement with previous experimental and theoretical results whereas the {nu}{sub 5} frequency agrees well with the computational data but conflicts with the gas-phase IR emission results.

  18. Opening of an icosahedral boron framework: A combined infrared spectroscopic and computational study

    NASA Astrophysics Data System (ADS)

    Fagiani, Matias R.; Liu Zeonjuk, L.; Esser, Tim K.; Gabel, Detlef; Heine, Thomas; Asmis, Knut R.; Warneke, Jonas

    2015-04-01

    The opening of an icosahderal boron cage in the periodinated closo-dodecaborate B12I122- upon deiodination is studied using cryogenic ion trap vibrational spectroscopy combined with electronic structure calculations. Comparison of simulated vibrational spectra to the infrared photodissociation spectra of messenger-tagged B12I122- and B12In- (n = 7-9) formed by skimmer collision induced dissociation shows that the larger clusters absorb exclusively below 975 cm-1 and hence exhibit quasi-icosahedral B12-cage structures, while the higher energy absorptions in-between 1000 and 1300 cm-1 observed for n = 7 can only be recovered by considering a breakup of the icosahedral cage upon deiodination from n = 8 to n = 7.

  19. Studying brain function with near-infrared spectroscopy concurrently with electroencephalography

    NASA Astrophysics Data System (ADS)

    Tong, Y.; Rooney, E. J.; Bergethon, P. R.; Martin, J. M.; Sassaroli, A.; Ehrenberg, B. L.; Van Toi, Vo; Aggarwal, P.; Ambady, N.; Fantini, S.

    2005-04-01

    Near-infrared spectroscopy (NIRS) has been used for functional brain imaging by employing properly designed source-detector matrices. We demonstrate that by embedding a NIRS source-detector matrix within an electroencephalography (EEG) standard multi-channel cap, we can perform functional brain mapping of hemodynamic response and neuronal response simultaneously. In this study, the P300 endogenous evoked response was generated in human subjects using an auditory odd-ball paradigm while concurrently monitoring the hemodynamic response both spatially and temporally with NIRS. The electrical measurements showed the localization of evoked potential P300, which appeared around 320 ms after the odd-ball stimulus. The NIRS measurements demonstrate a hemodynamic change in the fronto-temporal cortex a few seconds after the appearance of P300.

  20. In Situ Infrared Ellipsometry for Protein Adsorption Studies on Ultrathin Smart Polymer Brushes in Aqueous Environment

    SciTech Connect

    Kroning, Annika; Furchner, Andreas; Aulich, Dennis; Bittrich, Eva; Rauch, Sebastian; Uhlmann, Petra; Eichhorn, Klaus-Jochen; Seeber, Michael; Luzinov, Igor; Kilbey, S. Michael; Lokitz, Bradley S.; Minko, Sergiy; Hinrichs, Karsten

    2015-02-10

    The protein-adsorbing and -repelling properties of various smart nanometer-thin polymer brushes with high potential for biosensing and biomedical applications are studied by in-situ infrared-spectroscopic ellipsometry (IRSE). IRSE as a highly sensitive non-destructive technique allows us to investigate protein adsorption on polymer brushes in aqueous environment in dependence of external stimuli like temperature and pH. These stimuli are, for instance, relevant in switchable mixed brushes containing poly(N-isopropyl acrylamide) and poly(acrylic acid), respectively. We use such brushes as model surfaces for controlling protein adsorption of human serum albumin and human fibrinogen. IRSE can distinguish between polymer-specific vibrational bands, which yield insights into the hydration state of the brushes, and changes in the protein-specific amide bands, which are related to changes of the protein secondary structure.

  1. Hydrogen spill-over on alumina - a study by infrared spectroscopy. Technical report

    SciTech Connect

    Cavanagh, R.R.; Yates, J.T. Jr.

    1980-05-01

    Infrared spectroscopy has been used to monitor the exchange of D2(g) with OH groups chemisorbed on Al2O3. It has been shown that near 300K, the rate of the exchange process is rapid in the presence of supported Rh particles on the Al2O3. A qualitative model for hydrogen 'spillover' is presented in which dissociative adsorption of dihydrogen by the metal is a key step. It is shown that CO chemisorption on the supported Rh leads to a marked reduction in the 'spillover' rate due to site blockage on the Rh. This is consistent with recent studies of behavior of the CO and H coadsorbed on Rh(111).

  2. Infrared spectroscopy study of the sorption of selenium(IV) on natural zeolites

    NASA Astrophysics Data System (ADS)

    Zonkhoeva, E. L.; Sanzhanova, S. S.

    2011-07-01

    The sorption of selenium(IV) ions on single crystals of natural shabazite, analcime, mesolite, stilbite, and on clinoptilolite- and mordenite-containing tuffs in dependence on the concentration and pH of a solution of sodium selenite was studied by infrared spectroscopy. It was assumed that sorption on clinoptilolite and mordenite tuffs from a 0.1 M solution of sodium selenite with pH 9 occurs in the form of selenite and pyroselenite anions forming a hydrogen bond with the zeolite water molecules. It was established that water molecules in analcime, unlike stilbite, shabazite and mesolite, also form hydrogen bonds with the selenite ion in an alkaline medium. No hydrogen bonds are formed in diluted solutions or an acid medium. The partial desilylation and dealumination of zeolites in alkaline and acid media respectively, were observed.

  3. Infrared and density functional theory studies of formic acid hydrate clusters in noble gas matrices

    NASA Astrophysics Data System (ADS)

    Ito, Fumiyuki

    2016-08-01

    Infrared absorption spectra of formic acid hydrate clusters (HCOOH)m(H2O)n have been measured in noble gas matrices (Ar and Kr). The concentration dependence of the spectra and the comparison with a previous experimental study on HCOOH(H2O) and HCOOH(H2O)2 [Geoge et al., Spectrochim. Acta, Part A 60 (2004) 3225] led to the identification of large clusters. Density functional theory calculations at the B3LYP-DCP/6-31+G(2d,2p) level were carried out to determine the anharmonic vibrational properties of the clusters, enabling a consistent assignment of the observed vibrational peaks to specific clusters.

  4. Raman and mid-infrared spectroscopic study of geometrically frustrated hydroxyl cobalt halides at room temperature

    NASA Astrophysics Data System (ADS)

    Liu, Xiao-Dong; Meng, Dong-Dong; Hagihala, Masato; Zheng, Xu-Guang; Guo, Qi-Xin

    2011-07-01

    Mid-infrared absorption and Raman spectra of the geometrically frustrated material series, hydroxyl cobalt halides ß-Co2(OH)3Cl and ß-Co2(OH)3Br, are first, to the best of our knowledge, measured at room temperature, to study the corresponding relationship between their vibrational spectral properties and crystal microstructures. Through the comparative analysis of the four spectra we have categorically assigned the OH-related vibration modes of hydroxyl groups in the trimeric hydrogen bond environment (Co3 ≡OH)3 ... Cl/Br, and tentatively suggested vibration modes of O-Co-O, Co-O and Cl/Br-Co-Cl/Br units. These results can also become the basis for analysing their low-temperature spectral properties, which can help to understand the underlying physics of their exotic geometric frustration phenomena around phase transition temperatures.

  5. [Study on the infrared spectra and raman spectra of steel rusty layer with atmospheric corrosion].

    PubMed

    Yang, Xiao-mei

    2006-12-01

    In the present study two methods, infrared and Raman spectral analyses, were used to measure the rusty layer of samples with atmospheric corrosion from Qingdao. The main component rust phase of the rusty layer was observed, showing that the relative content of the rust phase varies with the change in corrosion time. The main component rust phases of the rusty layer were found to be alpha-Fe2O3 , gamma-FeOOH, alpha-FeOOH, delta-FeOOH and Fe3O4, with the relative content of each rust phase of A3 (1) rusty layer sample exhibiting the following relation: gamma-FeOOH> alpha-FeOOH>delta-FeOOH, and the relative contents of other rusty layer samples were found to follow the relation: gamma-FeOOH> delta-FeOOH>alpha-FeOOH. PMID:17361722

  6. Infrared cross-sections and integrated band intensities of propylene: Temperature-dependent studies

    NASA Astrophysics Data System (ADS)

    Es-sebbar, Et-touhami; Alrefae, Majed; Farooq, Aamir

    2014-01-01

    Propylene, a by-product of biomass burning, thermal cracking of hydrocarbons and incomplete combustion of fossil fuels, is a ubiquitous molecule found in the environment and atmosphere. Accurate infrared (IR) cross-sections and integrated band intensities of propylene are essential for quantitative measurements and atmospheric modeling. We measured absolute IR cross-sections of propylene using Fourier Transform Infrared (FTIR) Spectroscopy over the wavenumber range of 400-6500 cm-1 and at gas temperatures between 296 and 460 K. We recorded these spectra at spectral resolutions ranging from 0.08 to 0.5 cm-1 and measured the integrated band intensities for a number of vibrational bands in certain spectral regions. We then compared the integrated band intensities measured at room temperature with values derived from the National Institute of Standards and Technology (NIST) and the Pacific Northwest National Laboratory (PNNL) databases. Our results agreed well with the results reported in the two databases with a maximum deviation of about 4%. The peak cross-sections for the primary bands decreased by about 20-54% when the temperature increased from 296 to 460 K. Moreover, we determined the integrated band intensities as a function of temperature for certain features in various spectral regions; we found no significant temperature dependence over the range of temperatures considered here. We also studied the effect of temperature on absorption cross-section using a Difference Frequency Generation (DFG) laser system. We compared the DFG results with those obtained from the FTIR study at certain wavenumbers over the 2850-2975 cm-1 range and found a reasonable agreement with less than 10% discrepancy.

  7. Infrared studies of the reaction of methanesulfonic acid with trimethylamine on surfaces.

    PubMed

    Nishino, Noriko; Arquero, Kristine D; Dawson, Matthew L; Finlayson-Pitts, Barbara J

    2014-01-01

    Organosulfur compounds generated from a variety of biological as well as anthropogenic sources are oxidized in air to form sulfuric acid and methanesulfonic acid (MSA). Both of these acids formed initially in the gas phase react with ammonia and amines in air to form and grow new particles, which is important for visibility, human health and climate. A competing sink is deposition on surfaces in the boundary layer. However, relatively little is known about reactions after they deposit on surfaces. We report here diffuse reflectance infrared Fourier transform spectrometry (DRIFTS) studies of the reaction of MSA with trimethylamine (TMA) on a silicon powder at atmospheric pressure in synthetic air and at room temperature, either in the absence or in the presence of water vapor. In both cases, DRIFTS spectra of the product surface species are essentially the same as the transmission spectrum obtained for trimethylaminium methanesulfonate, indicating the formation of the salt on the surface with a lower limit to the reaction probability of γ > 10(-6). To the best of our knowledge, this is the first infrared study to demonstrate this chemistry from the heterogeneous reaction of MSA with an amine on a surface. This heterogeneous chemistry appears to be sufficiently fast that it could impact measurements of gas-phase amines through reactions with surface-adsorbed acids on sampling lines and inlets. It could also represent an additional sink for amines in the boundary layer, especially at night when the gas-phase reactions of amines with OH radical and ozone are minimized. PMID:24304088

  8. Infrared laser thermal fusion of blood vessels: preliminary ex vivo tissue studies

    NASA Astrophysics Data System (ADS)

    Cilip, Christopher M.; Rosenbury, Sarah B.; Giglio, Nicholas; Hutchens, Thomas C.; Schweinsberger, Gino R.; Kerr, Duane; Latimer, Cassandra; Nau, William H.; Fried, Nathaniel M.

    2013-05-01

    Suture ligation of blood vessels during surgery can be time-consuming and skill-intensive. Energy-based, electrosurgical, and ultrasonic devices have recently replaced the use of sutures and mechanical clips (which leave foreign objects in the body) for many surgical procedures, providing rapid hemostasis during surgery. However, these devices have the potential to create an undesirably large collateral zone of thermal damage and tissue necrosis. We explore an alternative energy-based technology, infrared lasers, for rapid and precise thermal coagulation and fusion of the blood vessel walls. Seven near-infrared lasers (808, 980, 1075, 1470, 1550, 1850 to 1880, and 1908 nm) were tested during preliminary tissue studies. Studies were performed using fresh porcine renal vessels, ex vivo, with native diameters of 1 to 6 mm, and vessel walls flattened to a total thickness of 0.4 mm. A linear beam profile was applied normal to the vessel for narrow, full-width thermal coagulation. The laser irradiation time was 5 s. Vessel burst pressure measurements were used to determine seal strength. The 1470 nm laser wavelength demonstrated the capability of sealing a wide range of blood vessels from 1 to 6 mm diameter with burst strengths of 578±154, 530±171, and 426±174 mmHg for small, medium, and large vessel diameters, respectively. Lateral thermal coagulation zones (including the seal) measured 1.0±0.4 mm on vessels sealed at this wavelength. Other laser wavelengths (1550, 1850 to 1880, and 1908 nm) were also capable of sealing vessels, but were limited by lower vessel seal pressures, excessive charring, and/or limited power output preventing treatment of large vessels (>4 mm outer diameter).

  9. Decomposition of soil organic matter by ectomycorrhizal fungi studied by infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Nicolás, César; Tunlid, Anders; Persson, Per

    2015-04-01

    Boreal forests accumulate a fifth of the global soil organic matter (SOM) pool and play an important role in the carbon cycling. Most trees in these boreal forests live in symbiosis with ectomycorrhizal fungi (EMF) that sheath the plant root tips. In the symbiotic relationship, EMF provide nutrients from the soil to plants such as nitrogen and phosphorous, and trees give carbon in return to the fungi. When foraging for these nutrients, EMF use different strategies to explore the soil matrix. Long-distance exploration types grow far into the soil surroundings of the roots, while short-medium distance exploration ones grow close to the root tips. Despite these morphological differences among EMF, there is still little evidence of their functional role in the SOM decomposition. In this study, two ectomycorrhizal fungi Paxillus involutus and Laccaria bicolor, which belong to long and medium-distance smooth exploration types respectively, were grown in axenic cultures on SOM extracted from forest litter. To trigger the fungal decomposing activity, the extracts were supplemented with glucose. Chemical analysis and infrared spectroscopy were used to analyze the organic matter and chemometric tools such as principal component analysis (PCA), two-dimensional (2D) correlation analysis and multivariate curve resolution-alternating least squares (MCR-ALS) analysis were applied to further understand the chemical changes in the SOM. The first principal component of PCA explained 77% of the total variability and separated the treatments based on two infrared spectral regions: polysaccharides (970-1,150 cm-1) and carbonyl region (1,620-1,800 cm-1). Moreover, the 2D correlation analysis showed that the polysaccharides region in both treatments was negatively correlated with the carbonyl region, suggesting the production of oxidized compounds such as ketones during the uptake of glucose. The 2D correlation analysis also revealed that the diminution of intensity in the

  10. Stimulated Raman scattering of picosecond pulses in a YVO4 crystal

    NASA Astrophysics Data System (ADS)

    Zong, N.; Zhang, X. F.; Li, C. M.; Cui, D. F.; Xu, Z. Y.; Zhang, H. J.; Wang, J. Y.

    2008-12-01

    Stimulated Raman scattering (SRS) with a picosecond pulse in YVO4 crystals in a transient state was investigated. The picosecond gain of YVO4 crystals pumped by a 532-nm laser evaluated by means of the threshold was 16.13 cm/GW.

  11. Signal averaging x-ray streak camera with picosecond jitter

    NASA Astrophysics Data System (ADS)

    Maksimchuk, A.; Kim, M.; Workman, J.; Korn, G.; Squier, J.; Du, D.; Umstadter, D.; Mourou, G.; Bouvier, M.

    1996-03-01

    We have developed an averaging picosecond x-ray streak camera using a dc-biased photoconductive switch as a generator of a high-voltage ramp. The streak camera is operated at a sweep speed of up to 8 ps/mm, shot-to-shot jitter is less than ±1 ps. The streak camera has been used to measure the time history of broadband x-ray emission from an ultrashort pulse laser-produced plasma. Accumulation of the streaked x-ray signals significantly improved the signal-to-noise ratio of the data obtained.

  12. Mechanical Properties of Nuclear Fuel Surrogates using Picosecond Laser Ultrasonics

    SciTech Connect

    David Hurley; Marat Khafizov; Farhad Farzbod; Eric Burgett

    2013-05-01

    Detailed understanding between microstructure evolution and mechanical properties is important for designing new high burnup nuclear fuels. In this presentation we discuss the use of picosecond ultrasonics to measure localize changes in mechanical properties of fuel surrogates. We develop measurement techniques that can be applied to investigate heterogeneous elastic properties caused by localize changes in chemistry, grain microstructure caused by recrystallization, and mechanical properties of small samples prepared using focused ion beam sample preparation. Emphasis is placed on understanding the relationship between microstructure and mechanical properties

  13. High-power picosecond fiber source for coherent Raman microscopy

    PubMed Central

    Kieu, Khanh; Saar, Brian G.; Holtom, Gary R.; Xie, X. Sunney; Wise, Frank W.

    2011-01-01

    We report a high-power picosecond fiber pump laser system for coherent Raman microscopy (CRM). The fiber laser system generates 3.5 ps pulses with 6 W average power at 1030 nm. Frequency doubling yields more than 2 W of green light, which can be used to pump an optical parametric oscillator to produce the pump and the Stokes beams for CRM. Detailed performance data on the laser and the various wavelength conversion steps are discussed, together with representative CRM images of fresh animal tissue obtained with the new source. PMID:19571996

  14. Picosecond dynamics of photoexcited carriers in interacting silicon nanocrystals

    NASA Astrophysics Data System (ADS)

    Kořínek, Miroslav; Trojánek, František; Hiller, Daniel; Gutsch, Sebastian; Zacharias, Margit; Kübel, Christian; Malý, Petr

    2016-07-01

    The non-radiative Auger carrier recombination plays an important role in physics and the application of semiconductor nanocrystals. Here we report on the effect of inter-nanocrystal carrier interaction on Auger recombination. We prepared a special set of samples containing silicon nanocrystals embedded in silicon oxide with well-defined geometry. The picosecond carrier recombination rate measured by femtosecond pump and probe technique was found to be strongly dependent on the inter-nanocrystal separation. The observed decrease of the decay rate with nanocrystal separation on the nanometer scale is interpreted in terms of the wave function overlap appearing in the relevant matrix element describing the recombination process.

  15. In Vitro picosecond ultrasonics in a single cell

    NASA Astrophysics Data System (ADS)

    Rossignol, C.; Chigarev, N.; Ducousso, M.; Audoin, B.; Forget, G.; Guillemot, F.; Durrieu, M. C.

    2008-09-01

    Ultrasonics signals at frequencies 5.7±0.1 and 6.8±0.1GHz are measured in two organelles of a single vegetal cell in vitro with a picosecond ultrasonic technique. Using standard values for cell optical index, ultrasound velocities of 1.6±0.1 and 2.0±0.1μm/ns are measured from several signals recorded in the vacuole and in the nucleus of a single Allium cepa cell, respectively. A 1μm lateral and 0.25μm depth resolution is attained.

  16. Picosecond imaging of low-density plasmas by electron deflectometry.

    PubMed

    Centurion, M; Reckenthaeler, P; Krausz, F; Fill, E E

    2009-02-15

    We have imaged optical-field ionized plasmas with electron densities as low as 10(13) cm(-3) on a picosecond timescale using ultrashort electron pulses. Electric fields generated by the separation of charges are imprinted on a 20 keV probe electron pulse and reveal a cloud of electrons expanding away from a positively charged plasma core. Our method allows for a direct measurement of the electron energy required to escape the plasma and the total charge. Simulations reproduce the main features of the experiment and allow determination of the energy of the electrons. PMID:19373367

  17. Picosecond conformational transition and equilibration of a cyclic peptide

    NASA Astrophysics Data System (ADS)

    Bredenbeck, Jens; Helbing, Jan; Sieg, Arne; Schrader, Tobias; Zinth, Wolfgang; Renner, Christian; Behrendt, Raymond; Moroder, Luis; Wachtveitl, Josef; Hamm, Peter

    2003-05-01

    Ultrafast IR spectroscopy is used to monitor the nonequilibrium backbone dynamics of a cyclic peptide in the amide I vibrational range with picosecond time resolution. A conformational change is induced by means of a photoswitch integrated into the peptide backbone. Although the main conformational change of the backbone is completed after only 20 ps, the subsequent equilibration in the new region of conformational space continues for times >16 ns. Relaxation and equilibration processes of the peptide backbone occur on a discrete hierarchy of time scales. Albeit possessing only a few conformational degrees of freedom compared with a protein, the peptide behaves highly nontrivially and provides insights into the complexity of fast protein folding.

  18. Shelf life study of egg albumin in pasteurized and non-pasteurized eggs using visible-near infrared spectroscopy

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A twelve week shelf life study was conducted on the egg albumen from both pasteurized and non-pasteurized shell eggs using visible-near infrared spectroscopy. The goal of the study was to correlate the chemical changes detected in the spectra to the measurement of Haugh units (measure of interior eg...

  19. A Fourier transform infrared spectroscopic study of yeast hexokinase: conformational changes under interaction with substrates and inhibitors

    NASA Astrophysics Data System (ADS)

    Trinquier-Dinet, Murielle; Boisdon, Marie-Thérèse; Perie, Jacques; Willson, Michèle

    1998-02-01

    The infrared (FTIR) spectroscopy study of several complexes of yeast hexokinase with substrates and inhibitors allows the determination of open and closed conformations of the protein. The analysis is based on a correlation between FTIR and X-ray data for one of the inhibitor-enzyme complexes of the study and from that reference, the features of the amide I band hydration component.

  20. Study of Fourier transform infrared spectra of cockroach nervous tissue and chitin

    NASA Astrophysics Data System (ADS)

    Ghadage, Vijay H.; Kulkarni, Gauri R.; Bhoraskar, Sudha V.

    2012-03-01

    Fourier Transform Infrared Spectroscopy (FTIR) is a very sensitive tool which is capable of providing strong insight on structural and functional changes in lipids and proteins induced by laser radiation. In the present work cockroach nervous tissue and chitin from tibia region are irradiated with Nd: YAG laser (λ= 1064 nm, Power =150mW) via fiber optics (Numerical aperture=0.22, diameter = 8 μ). Nd: YAG laser exposure time is varied from 10 sec to 50 sec for nervous tissue and chitin. FTIR (Fourier Transform Infra Red spectra) of cockroach nervous tissue and chitin are compared before and after laser irradiation. The FTIR spectrum of non irradiated cockroach nervous tissue shows clearly the peaks due to O-H (Carboxylic acid), C=O (Amide I), C=C (Aromatic), N=0 (Nitro), C-H (Alkenes), CH (Aromatics). FTIR Spectra of non irradiated cockroach chitin clearly shows O-H (Carboxylic acid), C=O (Carbonyl stretch), C=C (Aromatic), N=O (Nitro), C-O, (anhydrides), C-H (Alkenes stretch) group. FTIR spectra of laser radiated nervous tissue from cockroach tibia and chitin shows significant changes in transmittance for O-H, C=O, C=C, C-H, N=O, C-O and C-H groups. The percentage transmittance increases for O-H, C=C group for exposure time 10sec, 40sec and 50 sec for nervous tissue. The percentage transmittance increases for O-H, C=C group for exposure time 10sec, 20sec, 30sec and 40 sec for chitin. The study shows clearly that FTIR spectroscopy of nervous tissue can reveal the interactions between infrared laser light and nervous tissue.

  1. Matrix isolation infrared spectroscopic study of the vapor species over heated ReO{sub 3}

    SciTech Connect

    Almond, M.J.; Orrin, R.H.; Ogden, J.S.

    1996-02-01

    The vapor phase species over ReO{sub 3} heated in vacuo to approx 400C have been trapped in argon or nitrogen matrices at approx 12 K. The only species within such matrices detected by infrared spectroscopy is Re{sub 2}O{sub 7}. The bands of matrix-isolated Re{sub 2}O{sub 7} have been assigned by comparison with the spectrum of the gaseous compound. Most of the isolated Re{sub 2}O{sub 7} is shown to be in the monomeric form; thus, an infrared absorption at 916.5 cm{sup {minus}1} (N{sub 2} matrix), which had previously been assigned to an aggregate of Re{sub 2}O{sub 7} may, on the basis of annealing experiments, be attributed to the monomer. The solid remaining in the sample tube following heating of the ReO{sub 3} sample consists of ReO{sub 2} in both the monoclinic and orthorhombic crystal forms alongside some unreacted cubic ReO{sub 3} and a small amount of orthorhombic Re{sub 2}O{sub 7}. Thus, it is found that thermal decomposition of ReO{sub 3} in vacuo at 400 C follows the expected disproportionation route. The authors find no spectroscopic evidence for the existence of other species, such as ReO{sub 3} or HReO{sub 4}, in the vapor above heated ReO{sub 3}. This finding is in contrast to the results of earlier mass spectrometric studies that suggested that molecular ReO{sub 3} was present in the vapor together with Re{sub 2}O{sub 7}.

  2. Feasibility study on using an infrared thermometer for evaluation and administration of cryosurgery.

    PubMed

    Yan, Jing-Fu; Wang, Hong-Wu; Liu, Jing; Deng, Zhong-Shan; Rao, Wei; Xiang, Shi-Hai

    2007-01-01

    Successful performance of cryosurgery relies heavily on a quick, efficient, safe and economic imaging way to monitor the surgical advancement and then to evaluate the curative effect. However, there is currently a lack of such an imaging modality. As for the commonly adopted imaging devices such as X-CT, MRI and PET, in addition their high cost and complexity in operation, they often induce additional scathe to the patients due to their potential radiation effects. Besides, in cryosurgery, the most important parameter - temperature - can not be directly detected by these methods. Considering the above factors, infrared thermography (IRT), a rather useful yet often neglected functional imaging technique in clinics, is proposed in this paper as an efficient tool for the quick evaluation and administration of a cryosurgical treatment of tumors. Based on skin surface temperature mapping, the degree of damage to the target tissue site caused by different freezing/heating protocols, as well as the states of blood circulation and metabolic heat generation within the treated region can possibly be identified. Further, through recording the temperature variation feature at the skin surface before and after cryosurgery, IRT would help to quickly evaluate the curative effect, which is very beneficial for later treatment planning. By detecting the surface infrared image and analyzing its digital values, the patient's invisible focus and abnormal physiological states, e.g. inflammations or pneumothorax, often accompanied by cryosurgical output yet difficult to determine via conventional imaging, could also possibly be diagnosed. To test the above concepts, both typical animal and clinical experiments were performed to demonstrate the feasibility and advantages of IRT-guided cryosurgery. This study may help push forward a novel, low-cost and non-contact way for an efficient performance of cryosurgery. PMID:17573622

  3. Study on 512×128 pixels InGaAs near infrared focal plane arrays

    NASA Astrophysics Data System (ADS)

    Li, Xue; Tang, Hengjing; Huang, Songlei; Shao, Xiumei; Li, Tao; Huang, Zhangcheng; Gong, Haimei

    2014-10-01

    It is well known that In0.53Ga0.47As epitaxial material is lattice-matched to InP substrate corresponding to the wavelength from 0.9μm to 1.7μm, which results to high quality material and good device characteristics at room temperature. In order to develop the near infrared multi-spectral imaging, 512×128 pixels InGaAs Near Infrared Focal Plane Arrays (FPAs) were studied. The n-InP/i-InGaAs/n-InP double hereto-structure epitaxial material was grown by MBE. The 512×128 back-illuminated planar InGaAs detector arrays were fabricated, including the improvement of passivation film, by grooving the diffusion masking layer, the P type electrode layer, In bump condition and so on. The photo-sensitive region has the diffusion area of 23×23μm2 and pixel pitch of 30×30μm2 . The 512×128 detector arrays were individually hybridized on readout integrated circuit(ROIC) by Indium bump based on flip-chip process to make focal plane arrays (FPAs). The ROIC is based on a capacitive trans-impedance amplifier with correlated double sampling and integrated while readout (IWR) mode with high readout velocity of every pixel resulting in low readout noise and high frame frequency. The average peak detectivity and the response non-uniformity of the FPAs are 1.63×1012 cmHz1/2/W and 5.9%, respectively. The power dissipation and frame frequency of the FPAs are about 180mW and 400Hz, respectively.

  4. Land surface emissivity from high temporal resolution geostationary infrared imager radiances: Methodology and simulation studies

    NASA Astrophysics Data System (ADS)

    Li, Jun; Li, Zhenglong; Jin, Xin; Schmit, Timothy J.; Zhou, Lihang; Goldberg, Mitchell D.

    2011-01-01

    The time continuity of measurements from the Spinning Enhanced Visible and InfraRed Imager (SEVIRI) on board the Meteosat Second Generation (MSG) Meteosat-8/9 and from the Advanced Baseline Imager (ABI) on board the next generation of Geostationary Operational Environmental Satellite (GOES-R) can be uniquely taken into account for infrared (IR) land surface emissivity (LSE) retrievals. The algorithm is based on the assumption that land surface temperature (LST) is temporally variable while the LSE is temporally invariable within a short period of time, i.e., a few hours. SEVIRI/ABI radiances from multiple time steps can be used to retrieve temporally invariable IR LSE and variable LST. The algorithm theoretical basis is described. Sensitivity studies with simulations show that (1) the algorithm is less sensitive to the first guesses of LST and the 8.7 μm LSE but quite sensitive to the first guesses of the 10.8 and 12 μm LSE, (2) the algorithm is weakly sensitive to the observational noise and radiative transfer calculation uncertainty (in the form of random noise), and (3) except for the 8.7 μm LSE and LST, the algorithm is weakly sensitive to the radiance biases from dust contamination but sensitive to the radiance biases in the 12 μm channel from the radiative transfer calculation. It is emphasized that the radiance biases from dust contamination are very difficult if not impossible to estimate due to the high temporal and spatial variations of the spatial distribution and optical properties of dust aerosol. It is also found that the algorithm is sensitive to the LST weighting functions rather than the sensor's local zenith angle; as long as the LST weighting functions are large enough, the retrieval precision is good.

  5. Amplification of picosecond pulses in F{sub 2}{sup -}:LiF crystals synchronously pumped by picosecond and nanosecond laser pulses

    SciTech Connect

    Basiev, Tasoltan T; Karasik, Aleksandr Ya; Konyushkin, V A; Osiko, Vyacheslav V; Papashvili, A G; Chunaev, D S

    2005-04-30

    A method for amplification of picosecond pulses in F{sub 2}{sup -}:LiF crystals synchronously pumped by picosecond and nanosecond pulses is proposed and demonstrated. Due to two-stage amplification of a train of 22-ps, 1150-nm SRS pulses generated by a PbMoO{sub 4} crystal, a power gain of (2-4)x 10{sup 3} is achieved and single 6-ps, 0.88-mJ pulses are obtained. (lasers)

  6. Picosecond Spectroscopy of Vibrational and Electronic Dynamics in High Pressure Molecular Solids.

    NASA Astrophysics Data System (ADS)

    Crowell, Robert Ashton, II

    Picosecond time resolved studies of vibrational and electronic dynamics in molecular solids are presented. In the first, several uranyl compounds were selected that had large gaps in their vibrational energy density of states. Picosecond coherent anti-Stokes Raman measurements (psCARS) revealed that at 10 K vibrational relaxation occurs by at least a fifth order anharmonic mechanism. However, at elevated temperatures vibrational decay is found to proceed predominantly by a cubic anharmonic upconversion mechanism. In a second study the results of some of the first psCARS on a low temperature molecular solid in a high pressure diamond anvil cell are presented. For carbon disulfide pressure induced shifts in the phonon frequencies result in the opening up of a new relaxation pathway for the 2nu_2 mode. This pressure induced relaxation mechanism appears to dominate the dynamics of this mode at pressures greater than 19 kbar. In the third project pressure dependent low temperature psCARS measurements for the nu_9, nu_8, and nu_5 of naphthalene are presented. Pressure induced density of states effects are isolated, thereby allowing the first direct observations of pressure induced anharmonic coupling effects. The results indicate that the magnitude of the pressure induced anharmonic coupling is highly mode specific. In a fourth study psCARS measurements at low temperature are performed on homogeneous high pressure crystals and on highly strained crystals. Results are analyzed in terms of competition between vibrational relaxation and inhomogeneous dephasing. Changes in vibrational dephasing induced by a large negative pressure change (-Delta P >= 5 kbar) are used to determine the magnitude of inhomogeneous dephasing effects. The strain induced inhomogeneous dephasing is found to be mode specific. Finally the first picosecond photon echo measurements on a molecular solid in a high pressure diamond anvil cell at low temperature are presented. Results for the O _1 and O_3

  7. Neural correlates of spontaneous deception: A functional near-infrared spectroscopy (fNIRS)study.

    PubMed

    Ding, Xiao Pan; Gao, Xiaoqing; Fu, Genyue; Lee, Kang

    2013-03-01

    Deception is commonly seen in everyday social interactions. However, most of the knowledge about the underlying neural mechanism of deception comes from studies where participants were instructed when and how to lie. To study spontaneous deception, we designed a guessing game modeled after Greene and Paxton (2009) "Proceedings of the National Academy of Sciences, 106(30), 12506-12511", in which lying is the only way to achieve the performance level needed to end the game. We recorded neural responses during the game using near-infrared spectroscopy (NIRS). We found that when compared to truth-telling, spontaneous deception, like instructed deception, engenders greater involvement of such prefrontal regions as the left superior frontal gyrus. We also found that the correct-truth trials produced greater neural activities in the left middle frontal gyrus and right superior frontal gyrus than the incorrect-truth trials, suggesting the involvement of the reward system. Furthermore, the present study confirmed the feasibility of using NIRS to study spontaneous deception. PMID:23340482

  8. Femtosecond wavelength-tunable OPCPA system based on picosecond fiber laser seed and picosecond DPSS laser pump.

    PubMed

    Danilevičius, R; Zaukevičius, A; Budriūnas, R; Michailovas, A; Rusteika, N

    2016-07-25

    We present a compact and stable femtosecond wavelength-tunable optical parametric chirped pulse amplification (OPCPA) system. A novel OPCPA front-end was constructed using a multi-channel picosecond all-in-fiber source for seeding DPSS pump laser and white light supercontinuum generation. Broadband chirped pulses were parametrically amplified up to 1 mJ energy and compressed to less than 40 fs duration. Pulse wavelength tunability in the range from 680 nm to 930 nm was experimentally demonstrated. PMID:27464199

  9. Laser damage growth with picosecond pulses.

    PubMed

    Sozet, Martin; Neauport, Jérôme; Lavastre, Eric; Roquin, Nadja; Gallais, Laurent; Lamaignère, Laurent

    2016-05-15

    Laser-induced damage growth has been investigated in the subpicosecond regime at 1030 nm. We have herein studied the growth of damage sites initiated on a high-reflective dielectric coating under subsequent laser irradiations at a constant fluence. We show through an experimental approach that growth can be triggered for fluences as low as 50% of the intrinsic damage threshold of the mirror. Moreover, once growth starts, damage areas increase linearly with the number of laser shots. The behavior of defect-induced damage sites has been observed more extensively, and it appears that their growth probability depends on their initiation fluence. PMID:27176998

  10. Infrared studies of sulfuric acid and its impact on polar and global ozone

    NASA Astrophysics Data System (ADS)

    Iraci, Laura Tracy

    Sulfuric acid aerosols are present throughout the lower stratosphere and play an important role in both polar and global ozone depletion. In the polar regions, stratospheric sulfate aerosols (SSAs) act as nuclei for the growth of polar stratospheric clouds (PSCs). Heterogeneous reactions can occur on these PSCs, leading to chlorine activation and catalytic ozone destruction. This thesis addresses the issue of polar ozone depletion through laboratory studies which examine the nucleation of PSCs on sulfuric acid. In addition, chemistry which occurs directly on sulfate aerosols may impact ozone at midlatitudes, and studies describing one such reaction are presented as well. To study the growth of type I PSCs on sulfuric acid, thin H2SO4 films were exposed to water and nitric acid vapors at stratospheric temperatures. Fourier transform infrared spectroscopy was used to probe the phase of the sulfuric acid and to identify the HNO3/H2O films which condensed. Supercooled liquid sulfuric acid films showed uptake of HNO3 to form ternary solutions, followed by crystallization of nitric acid trihydrate (NAT). When crystalline sulfuric acid tetrahydrate (SAT) films were exposed to nitric acid and water, condensation of a supercooled HNO3/H2O layer was often observed. As predicted by theory, some of the SAT crystal then dissolved, creating a ternary H2SO4/HNO3/H2O solution. From this solution, NAT nearly always crystallized, halting the phase change of sulfuric acid. If a supercooled nitric acid layer did not condense on frozen sulfuric acid, crystalline NAT was not deposited from the gas phase when SNAT/leq41. At significantly higher supersaturations, NAT could be forced to condense on sulfuric acid, regardless of its phase. Calculations of the contact parameter from experimental data indicate that m<0.79 for NAT on SAT, predicting a significant barrier to nucleation of NAT from the gas phase. While PSCs can form only in the cold polar regions of the stratosphere, sulfuric

  11. High-pulse-energy mode-locked picosecond oscillator

    NASA Astrophysics Data System (ADS)

    Chao, Yang; Chen, Meng; Li, Gang

    2014-02-01

    We report on a high-pulse-energy solid-state picosecond Nd:YVO4 oscillator with cavity-dumping. The laser is end-pumped by an 808 nm laser diode and passively mode-locked with a semiconductor saturable absorption mirror (SESAM). In pure cw-mode-locking, this laser produced 2.5 W of average power at a pulse repetition rate of 40 MHz and pulse duration around 12 ps. A cavity dumping technique using an intra-cavity BBO electro-optic crystal to which bidirectional voltage was applied was adopted, effectively improving the cavity-dumping rate. Tunable high repetition rate from 100 kHz to 1 MHz was achieved. With electro-optic cavity dumper working at 1 MHz repetition rate, we achieved average power 594 mW. The laser includes a 5 mm long, a-cut, 0.5% doped Nd:YVO4 crystal with a 5-degree angle at one end face. Laser radiation is coupled out from the crystal end face with a 5-degree angle, without requiring insertion of a thin-film polarizer (TFP), thus simplifying the laser structure. This picosecond laser system has the advantages of compact structure and high stability, providing a good oscillator for regenerative amplifiers.

  12. Structural, photoluminescence and picosecond nonlinear optical effect of In-doped ZnO nanowires

    NASA Astrophysics Data System (ADS)

    Yan, Xiao-Yan; Yao, Cheng-Bao; Li, Jin; Hu, Jun-Yan; Li, Qiang-Hua; Yang, Shou-Bin

    2016-05-01

    In-doped ZnO (IZO) nanowires were grown using the chemical vapour deposition method. The IZO nanowires have been characterized by scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and UV-Visible spectroscopy. The PL results demonstrated a larger band-gap for the IZO nanowires in comparison to the undoped ZnO. Two major emission peaks were observed for the IZO nanowires, one originated from the free exciton recombination (ultraviolet emission) and another possibly related to the deep-level emission (visible emission). Furthermore, the nonlinear optical characteristic of the nanowires was studied using picosecond Z-scan technique. The experimental results show that the two and three-photon absorption coefficient of samples were able to be observed. These studies make the promising potential applications of the samples in the development of multifunctional all-optical devices.

  13. Picosecond Diffraction at the ESRF: How Far Have We Come and Where Are We Going?

    SciTech Connect

    Wulff, Michael; Kong Qingyu; Cammarata, Marco; Lo Russo, Manuela; Anfinrud, Philip; Schotte, Friedrich; Lorenc, Maciej; Ihee, Hyotcherl; Kim, Tae Kyu; Plech, Anton

    2007-01-19

    The realization of solution phase pump-probe diffraction experiments on beamline ID09B is described. The pink beam from a low-K in-vacuum undulator is used to study the structural dynamics of small molecules in solution to 100 picosecond time resolution and at atomic resolution. The X-ray chopper and the associated timing modes of the synchrotron are described. The dissociation of molecular iodine in liquid CCl4 is studied by single pulse diffraction. The data probe not only the iodine structures but also the solvent structure as the latter is thermally excited by the flow of energy from recombining iodine atoms. The low-q part of the diffraction spectra is a sensitive probe of the hydrodynamics of the solvent as a function of time.

  14. Absolute response of Fuji imaging plate detectors to picosecond-electron bunches.

    PubMed

    Zeil, K; Kraft, S D; Jochmann, A; Kroll, F; Jahr, W; Schramm, U; Karsch, L; Pawelke, J; Hidding, B; Pretzler, G

    2010-01-01

    The characterization of the absolute number of electrons generated by laser wakefield acceleration often relies on absolutely calibrated FUJI imaging plates (IP), although their validity in the regime of extreme peak currents is untested. Here, we present an extensive study on the dependence of the sensitivity of BAS-SR and BAS-MS IP to picosecond electron bunches of varying charge of up to 60 pC, performed at the electron accelerator ELBE, making use of about three orders of magnitude of higher peak intensity than in prior studies. We demonstrate that the response of the IPs shows no saturation effect and that the BAS-SR IP sensitivity of 0.0081 photostimulated luminescence per electron number confirms surprisingly well data from previous works. However, the use of the identical readout system and handling procedures turned out to be crucial and, if unnoticed, may be an important error source. PMID:20113093

  15. Absolute response of Fuji imaging plate detectors to picosecond-electron bunches

    SciTech Connect

    Zeil, K.; Kraft, S. D.; Jochmann, A.; Kroll, F.; Jahr, W.; Schramm, U.; Karsch, L.; Pawelke, J.; Hidding, B.; Pretzler, G.

    2010-01-15

    The characterization of the absolute number of electrons generated by laser wakefield acceleration often relies on absolutely calibrated FUJI imaging plates (IP), although their validity in the regime of extreme peak currents is untested. Here, we present an extensive study on the dependence of the sensitivity of BAS-SR and BAS-MS IP to picosecond electron bunches of varying charge of up to 60 pC, performed at the electron accelerator ELBE, making use of about three orders of magnitude of higher peak intensity than in prior studies. We demonstrate that the response of the IPs shows no saturation effect and that the BAS-SR IP sensitivity of 0.0081 photostimulated luminescence per electron number confirms surprisingly well data from previous works. However, the use of the identical readout system and handling procedures turned out to be crucial and, if unnoticed, may be an important error source.

  16. Picosecond dynamics of benzophenone anion solvation

    SciTech Connect

    Lin, Y.; Jonah, C.D. )

    1993-01-14

    The dynamics of benzophenone anion solvation in alcohols are studied by pulse-radiolysis techniques. The solvation process is characterized by the blue shift of the transient absorption spectrum of the anion and is faster for the smaller alcohols. The anion is solvated more slowly than the electron in the same solvent, but the solvation times of both are similar to [tau][sub 2], the solvent dielectric relaxation time. The familiar phenomenological two-state model of solvation was found to be inappropriate for describing the anion solvation process. A multistate process appears to be a more appropriate description. The authors modeled the kinetics of the spectral relaxation. In most cases, nearly quantitative agreement between the calculated and observed spectra is achieved. The characteristic relaxation times for the alcohol solvents around the anions were also reproduced. 50 refs., 8 figs., 3 tabs.

  17. Thermal processing as a means to prepare durable, submicron thickness ionomer films for study by transmission infrared spectroscopy.

    PubMed

    Byun, Chang Kyu; Parker, Tifani; Liang, Chunchao; Kendrick, Ian; Dimakis, Nicholas; Smotkin, Eugene S; Jin, Li-Mei; Zhuang, Dongqing; DesMarteau, Darryl D; Creager, Stephen E; Korzeniewski, Carol

    2012-10-01

    A high temperature solution processing method was adapted to prepare durable, freestanding, submicrometer thickness films for transmission infrared spectroscopy studies of ionomer membrane. The materials retain structural integrity following cleaning and ion-exchange steps in boiling solutions, similar to a commercial fuel cell membrane. Unlike commercial membrane, which typically has thicknesses of >25 μm, the structural properties of the submicrometer thickness materials can be probed in mid-infrared spectral measurements with the use of transmission sampling. Relative to the infrared attenuated total reflection (ATR) technique, transmission measurements can sample ionomer membrane materials more uniformly and suffer less distortion from optical effects. Spectra are reported for thermally processed Nafion and related perfluoroalkyl ionomer materials containing phosphonate and phosphinate moieties substituted for the sulfonate end group on the side chain. Band assignments for complex or unexpected features are aided by density functional theory (DFT) calculations. PMID:22947127

  18. A SPITZER/INFRARED SPECTROGRAPH SPECTRAL STUDY OF A SAMPLE OF GALACTIC CARBON-RICH PROTO-PLANETARY NEBULAE

    SciTech Connect

    Zhang Yong; Kwok Sun; Hrivnak, Bruce J. E-mail: sunkwok@hku.h

    2010-12-10

    Recent infrared spectroscopic observations have shown that proto-planetary nebulae (PPNs) are sites of active synthesis of organic compounds in the late stages of stellar evolution. This paper presents a study of Spitzer/Infrared Spectrograph spectra for a sample of carbon-rich PPNs, all except one of which show the unidentified 21 {mu}m emission feature. The strengths of the aromatic infrared band, 21 {mu}m, and 30 {mu}m features are obtained by decomposition of the spectra. The observed variations in the strengths and peak wavelengths of the features support the model that the newly synthesized organic compounds gradually change from aliphatic to aromatic characteristics as stars evolve from PPNs to planetary nebulae.

  19. Infrared study of the hydrogen bonding site in a poly-functional schiff base: N( sp2) or N( sp)?

    NASA Astrophysics Data System (ADS)

    Laureys, C.; Zeegers-Huyskens, Th.

    1987-05-01

    The hydrogen bond complexes between phenol derivatives and the Schiff base [(diphenylmethylene)amino]-acetonitrile have been studied by infrared spectroscopy in carbon tetrachloride solution. The thermodynamic data and the infrared spectra investigated in the ν OH, ν CN and ν CN region indicate that complex formation occurs at the nitrogen atom of the nitrile function. The hydrogen bonding site is in this case governed by the accessibility of the lone pair which is markedly higher for the N( sp) than the N( sp2) electrons.

  20. Wrist Hypothermia Related to Continuous Work with a Computer Mouse: A Digital Infrared Imaging Pilot Study.

    PubMed

    Reste, Jelena; Zvagule, Tija; Kurjane, Natalja; Martinsone, Zanna; Martinsone, Inese; Seile, Anita; Vanadzins, Ivars

    2015-08-01

    Computer work is characterized by sedentary static workload with low-intensity energy metabolism. The aim of our study was to evaluate the dynamics of skin surface temperature in the hand during prolonged computer mouse work under different ergonomic setups. Digital infrared imaging of the right forearm and wrist was performed during three hours of continuous computer work (measured at the start and every 15 minutes thereafter) in a laboratory with controlled ambient conditions. Four people participated in the study. Three different ergonomic computer mouse setups were tested on three different days (horizontal computer mouse without mouse pad; horizontal computer mouse with mouse pad and padded wrist support; vertical computer mouse without mouse pad). The study revealed a significantly strong negative correlation between the temperature of the dorsal surface of the wrist and time spent working with a computer mouse. Hand skin temperature decreased markedly after one hour of continuous computer mouse work. Vertical computer mouse work preserved more stable and higher temperatures of the wrist (>30 °C), while continuous use of a horizontal mouse for more than two hours caused an extremely low temperature (<28 °C) in distal parts of the hand. The preliminary observational findings indicate the significant effect of the duration and ergonomics of computer mouse work on the development of hand hypothermia. PMID:26262633