Science.gov

Sample records for producing coking heat

  1. Method and apparatus for producing active coke

    SciTech Connect

    Wolfrum, E.

    1980-12-30

    At least a portion of coke produced in a hearth-type furnace is fed into an activation reactor, and at least a portion of the waste gas from the hearth-type furnace is fed to the activation reactor to act as a heating gas and/or an activation gas for the coke feed. Hot waste gas from the activation reactor is passed to a waste-heat boiler. Active coke which has at least partially lost its adsorption capacity may be fed into the furnace in mixture with the coal or alone, or it may be fed directly into the activation reactor for re-activation of the coke.

  2. Effects of preheating and highly heat-conductive brick on coke quality

    SciTech Connect

    Fukuda, K.; Arima, T.

    1995-12-31

    In replacing the coke ovens available currently, the introduction of a combined technique of a preheated coal charging method (preheating temperature:175 C) and the use of highly heat-conductive brick is under examination for raising the productivity of coke ovens. With such background, a study of the effects of this combined technique on the coke quality, especially the coke size was conducted. The experimental results revealed that the primary size of coke produced by the combined technique is noticeably larger than that of the coke made from wet coal and after five revolutions of drum (equivalent to mechanical impact given at a time of dropping from coke oven chamber to wharf), the coke size reduces even compared with an ordinary coke. This may be due to the fact that the coke produced by the combined technique includes a lot of fissures inside the coke lump.

  3. Heat treatment of exchangers to remove coke

    SciTech Connect

    Turner, J.D.

    1990-02-20

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  4. Process for producing shaft furnace cokes

    SciTech Connect

    Nishioka, K.; Sunami, Y.

    1981-06-09

    An impregnated carbonaceous material which can be mixed with basic coal to form a mixture which, once roasted, forms an effective shaft furnace coke. The impregnated carbonaceous material is formed by finely crushing an inert carbonaceous material such as powdered coke, coal gasification char, coal liquifaction residue coal, oil coke, and semi-dry-distilled char, and mixing and impregnating the crushed carbonaceous material with an aromatic pitch such as coal tar, coal tar pitch, asphalt, and pitch obtained by heat-treating or solvent extracting an asphalt. The mixing is conducted at a temperature above the aromatic pitch melting point. The impregnated carbonaceous material contains preferably 50 to 95 parts by weight of crushed inert carbonaceous material and 5 to 50 parts by weight aromatic pitch.

  5. Process for the recovery of coke oven waste heat

    SciTech Connect

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1981-01-20

    This invention is directed to a process for making coke and recovering the heat therefrom for preheating the firing gas to the coke oven. The process involves the use of the coke oven firing gas to extract the sensible heat from the hot coke from the coking oven to both preheat the firing gas for the coke oven and cool the hot coke. Significant economies are achieved in the two-fold function of coke production and heat recovery in accordance with the method disclosed.

  6. Experience in the study of coke battery heating conditions

    SciTech Connect

    Zernii, G.G.; Leibovich, R.E.; Nepomnyashchii, A.A.; Sulimova, E.I.; Robul, L.A.; Kardashova, E.F.; Starobinskii, N.L.

    1982-01-01

    A discussion of the distribution of coke oven gas to the heating flues of the heating wall was presented. The effects of the variation in the density of the charge on the resulting quality of the coke were also discussed. It was concluded that the heat flow should be distributed along the heating wall with consideration not only of the conical nature of the oven, but also the difference in the bulk density of the charge with length and height of the oven. This permitted an improvement on the quality of the coke and a decrease in the consumption of heating gas for charge heating.

  7. Supercritical convection, critical heat flux, and coking characteristics of propane

    NASA Technical Reports Server (NTRS)

    Rousar, D. C.; Gross, R. S.; Boyd, W. C.

    1984-01-01

    The heat transfer characteristics of propane at subcritical and supercritical pressure were experimentally evaluated using electrically heated Monel K-500 tubes. A design correlation for supercritical heat transfer coefficient was established using the approach previously applied to supercritical oxygen. Flow oscillations were observed and the onset of these oscillations at supercritical pressures was correlated with wall-to-bulk temperature ratio and velocity. The critical heat flux measured at subcritical pressure was correlated with the product of velocity and subcooling. Long duration tests at fixed heat flux conditions were conducted to evaluate coking on the coolant side tube wall and coking rates comparable to RP-1 were observed.

  8. Preparation of modified semi-coke by microwave heating and adsorption kinetics of methylene blue.

    PubMed

    Wang, Xin; Peng, Jin-Hui; Duan, Xin-Hui; Srinivasakannan, Chandrasekar

    2013-01-01

    Preparation of modified semi-coke has been achieved, using phosphoric acid as the modifying agent, by microwave heating from virgin semi-coke. Process optimization using a Central Composite Design (CCD) design of Response Surface Methodology (RSM) technique for the preparation of modifies semi-coke is presented in this paper. The optimum conditions for producing modified semi-coke were: concentration of phosphoric acid 2.04, heating time 20 minutes and temperature 587 degrees C, with the optimum iodine of 862 mg/g and yield of 47.48%. The textural characteristics of modified semi-coke were analyzed using scanning electron microscopy (SEM) and nitrogen adsorption isotherm. The BET surface area of modified semi-coke was estimated to be 989.60 m2/g, with the pore volume of 0.74 cm3/g and a pore diameter of 3.009 nm, with micro-pore volume contributing to 62.44%. The Methylene Blue monolayer adsorption capacity was found to be mg/g at K. The adsorption capacity of the modified semi-coke highlights its suitability for liquid phase adsorption application with a potential usage in waste water treatment. PMID:24779145

  9. Method for recovering and utilizing heat of coke-oven gas

    SciTech Connect

    Kunioka, K.; Nishio, H.; Okuyama, Y.; Shimotsuma, T.

    1981-06-02

    A method is described for recovering and utilizing heat of coke- oven gas is eliminated. Through heat exchange with a high-temperature coke-oven gas generated from a coke oven battery and containing vaporized coal tar, vaporized low boiling point substances and dust. By drying and preheating a blended raw material coal fine to be charged into coking ovens of said coke oven battery, and causing most of said coal tar contained in said coke-oven gas to condense and deposit onto the particle surfaces of said coal fine. During the process of said heat exchange, sensible heat and condensation heat of said coke-oven gas and substances contained therein are recovered and utilized, and at the same time, most of the contained coal tar from said coke-oven gas.

  10. Influence of heating rate on quality of needle coke in calcining

    SciTech Connect

    Akhmetov, M.M.; Karpinskaya, N.M.; Shipkov, N.N.

    1984-05-01

    This article examines the calcination of raw coke in hearth and chamber furnaces. Three coke samples with identical degrees of calcining were taken from each furnace. The heating rate was calculated from measurements of the coke temperature as it moved in the furnace under conditions of a stable and characteristic calcining regime. The coke temperature was measured by means of a chromel-alumel thermocouple. Electric resistivity and carbon and hydrogen contents are practically identical for the cokes calcined in the hearth and chamber furnaces. The difference between the quality indexes of the cokes is attributed to the difference in the heating rates. The results indicate that a major disadvantage of the hearth furnace is its high heating rate. It is suggested that the hearth furnace should not be used in calcining cokes that must meet rigid quality requirements.

  11. Occupational exposure to carbon/coke fibers in plants that produce green or calcined petroleum coke and potential health effects: 2. Fiber concentrations.

    PubMed

    Maxim, L Daniel; Galvin, Jennifer B; Niebo, Ron; Segrave, Alan M; Kampa, Otto A; Utell, Mark J

    2006-01-01

    We monitored exposure to various fibers among workers in eight plants operated by ConocoPhillips that produce green or calcined petroleum coke. Carbon/coke and other fibers, including calcium silicate, cellulose, gypsum, and iron silicate, were found in occupational samples. Carbon/coke fibers were found in bulk samples of calcined petroleum coke, the probable source of these fibers in occupational samples. Time-weighted average (TWA) total fiber concentrations were approximately lognormally distributed; 90% were < or = 0.1 f/ml. Although consistently low, TWA total fiber concentrations varied with plant, job (tasks), and type of coke. This was expected given the substantial differences in plant configuration, technology, and workplace practices among refineries and carbon plants. Carbon/coke fibers (identified and measured using transmission electron microscopy [TEM]) were found at all plants producing all types of calcined coke and not detected at any plant producing only green coke. Approximately 98% of all carbon/coke TWAs were < or = 0.1 f/ml. Analysis of task length average (TLA) data by various statistical techniques indicates that the average carbon/coke TLA is certainly < or = 0.05 f/ml and probably < 0.03 f/ml. PMID:16326398

  12. Process for calcining coke

    SciTech Connect

    Komi, N.; Noguchi, K.

    1981-05-05

    A process is described for calcining green coke in at least three heating stages, which comprises preheating the green coke in the first stage, preliminarily calcining the coke in the second stage, cooling the coke; and calcining the coke in the third stage, volatile matter from the second stage being burned during the third stage. The product coke is suitable for preparing graphite electrodes.

  13. Improvement on heating efficiency of fuel in coke oven at CSC

    SciTech Connect

    Hong, M.T.; Chen, C.W.; Shen, J.F.; Hsiao, C.H.; Hsieh, D.L.; Chung, K.A.

    1996-12-31

    A heat input management of coke oven, consisting of two subsystems respectively for setting proper coking time, diagnosing thermal state of coke oven in horizontal and longitudinal direction, was developed. It aimed to control the average oven temperature to the suitable level and to diminish the deviations of temperature between each heating walls. In subsystem 1, the measured flue temperature was corrected by a reversed cooling curve and compared with an ideal transversal profile. A precise thermal state of battery heating was therefore induced. In subsystem 2, with the measurement of gas temperature at ascending pipe, a coking completion table composed of production ratio, coal moisture and flue temperature was established for setting the target flue temperature. Since this coke oven combustion management system was adopted, the remarkable heating improvement has been achieved, for an example at Phase III, the average temperature of coke oven was decreased from 1,262 C to 1,240 C, the fuel was thus saved, the wall temperature was more even and the coke qualities were also improved.

  14. Research on coke-oven heating technology and the properties of coke as a blast-furnace fuel. [UKhIN

    SciTech Connect

    Vasil'ev, Yu.S.; Semisalov, L.P.

    1980-01-01

    A fundamentally novel coke-oven system was designed at Giprokoks (underjet, with bottom gas and air regulation) on the basis of data from model experiments. In particular, when batteries of 41.6 m/sup 3/ coke ovens were developed, the results of model tests led to major modifications to the original designs for the regenerator zones, sloping ducts and flues. UKhIN investigations on hot and hydraulic models, using modern mathematical procedures and computers, were used to study the details of heat exchange and gas flow in the regenerator packings under coke ovens. Criterial equations were derived for the coefficients of heat transfer by convection and of hydraulic resistance, covering the specific features of regenerator performance in coke-oven heating systems. Much useful information for the advance of coke-oven technology has been obtained from laboratory, pilot and fullscale plant studies of the thermal properties of coals and blends. Investigations (including blast-furnace trials) in connection with the commercial adoption of dry coke cooling established that during its soaking in the storage chamber the coke undergoes changes in molecular structure, to an extent dependent on the time and temperature. Recommendations based on this research significantly improve the coke strength properties and extended the range of usable coal supplies. Traditionally, the Institute is greatly interested in the problem of coke yields, which has now become very urgent in connection with the use of higher proportions of grade G and other coals with high volatile matters. Detailed studies have been made of the effects of various processing factors on the yields of saleable and metallurgical coke.

  15. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect

    Battle, E.T.; Chen, K.L. |

    1997-12-31

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  16. Process for producing blast furnace grade coke, a distillable product and fuel gases from a heavy, high sulfur, crude oil

    SciTech Connect

    Boyer, L.D.; Sooter, M.C.; Theodore, F.W.; Wasson, G.E.

    1983-06-14

    A process for producing a distillable hydrocarbonaceous stream, fuel gases and blast furnace grade coke from a heavy, high sulfur, crude oil by producing delayed coke from at least a portion of the crude oil; crushing at least a portion of the coke to provide a finely divided coke feedstock to a briquetting operation where the finely divided coke is briquetted using crude oil or topped crude oil as a binder to produce briquettes of a size from about 3/4 inch to about 3 inches with the resulting briquettes being passed to a high temperature vertical calciner where the solids are desulfurized to produce a strong blast furnace grade coke. The distillable stream and fuel gas stream are recovered from the delayed coking operation, the vertical calciner and optionally a crude oil topping operation. In some instances coke particles in the size range from about 3/4 inch to about 3 inches may be passed directly to the calciner without crushing and briquetting. However, it is preferred to crush and briquette substantially all of the coke.

  17. Considerations concerning the physical heat-recovery of raw coke-oven gas in an industrial pilot-station

    SciTech Connect

    Paunescu, L.; Gaba, A.

    1998-12-31

    The paper presents the conception and realization obtained by the research team at the Metallurgical Researches Institute in an industrial pilot-station on the field of the physical heat-recovery of raw coke-oven gas.

  18. Coke oven gas injection to blast furnaces

    SciTech Connect

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  19. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect

    Leeder, W.R.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  20. Coke calcination levels and aluminum anode quality

    SciTech Connect

    Dreyer, C.; Samanos, B.; Vogt, F.

    1996-10-01

    The calcination temperature of petroleum coke for aluminum anode applications has been generally increased during the past 10 years. This change by coke suppliers has often been done at the request of anode manufacturers (smelters) who seek special quality requirements for the calcined coke. Such an increase in calcining temperatures not only affects coke properties, but also has an effect on calciner operations and may have some unexpected effects on anode quality. One high and one low sulfur coke were calcined industrially at two different levels. The four individual calcined cokes were characterized. Then laboratory scale anodes were produced with each individual calcined coke. These all-coke anodes were first evaluated for optimum pitch content. Then the anodes were baked over a range of temperatures (920 to 1,260 C) in order to evaluate the influence of this heat treatment on anode properties. The results show the influence of calcining temperature on coke properties and anode properties, including the most important influence of the anode baking level.

  1. Structure degradation of 25Cr35Ni heat-resistant tube associated with surface coking and internal carburization

    SciTech Connect

    Wu, X.Q.; Yang, Y.S.; Zhan, Q.; Hu, Z.Q.

    1998-10-01

    Microstructures of 25Cr35Ni heat-resistant cracking tube after service were investigated and degradation mechanism of tube material was discussed. Results reveal that three distinguished zones, that is, internal oxide, carbide free, and internally carburized zones, will gradually develop in the inner wall of a cracking tube during service. Carbide free and internally carburized zones are formed primarily in relation to the periodic spalling and regeneration of surface oxide scale, and diffusion velocity of carbon and carbide forming elements in matrix and the solubility limit of carbon in alloy. The formation and growth of filament coke can aggravate structure degradation of the inner wall of the cracking tube, while deposition of lamellar and spheroidal coke may slow structure degradation to some extent. Surface coking and decoking cycles strongly aggravate the structure degradation of tube material and damage the service life of the cracking tube.

  2. Demand for superpremium needle cokes on upswing

    SciTech Connect

    Acciarri, J.A.; Stockman, G.H. )

    1989-12-01

    The authors discuss how recent supply shortages of super-premium quality needle cokes, plus the expectation of increased shortfalls in the future, indicate that refiners should consider upgrading their operations to fill these demands. Calcined, super-premium needle cokes are currently selling for as much as $550/metric ton, fob producer, and increasing demand will continue the upward push of the past year. Needle coke, in its calcined form, is the major raw material in the manufacture of graphite electrodes. Used in steelmaking, graphite electrodes are the electrical conductors that supply the heat source, through arcing electrode column tips, to electric arc steel furnaces. Needle coke is commercially available in three grades - super premium, premium, and intermediate. Super premium is used to produce electrodes for the most severe electric arc furnace steelmaking applications, premium for electrodes destined to less severe operations, and intermediate for even less critical needs.

  3. A new technology for producing hydrogen and adjustable ratio syngas from coke oven gas

    SciTech Connect

    Jun Shen; Zhi-zhong Wang; Huai-wang Yang; Run-sheng Yao

    2007-12-15

    About 15 billion Nm{sup 3} coke oven gas (COG) is emitted into the air in Shanxi Province in China as air pollutants. It is also a waste of precious chemical resources. In this study, COG was purified respectively by four methods including refrigeration, fiberglass, silica gel, and molecular sieve. Purified COG was separated by a prism membrane into two gas products. One consists mainly of H{sub 2} ({gt}90 vol %) and the other is rich in CH{sub 4} ({gt}60 vol %) with their exact compositions to vary with the membrane separation pressure and outlet gas flow ratio. The gas rich in CH{sub 4} was partially oxidized with oxygen in a high-temperature fixed-bed quartz reactor charged with coke particles of 10 mm size. At 1200-1300{sup o}C, a CH{sub 4} conversion of {gt}99% could be obtained. The H{sub 2}/CO ratio in the synthesis product gas can be adjusted in the range 0.3-1.4, very favorable for further C1 synthesis. 10 refs., 17 figs., 1t ab.

  4. Advanced processes for metallurgical coke. Appendices

    SciTech Connect

    Straus, R.W.; Carsey, J.N.; von Bismarck, G.; Fujishima, C.

    1980-12-01

    Material collected in a survey of German coking plants (some in German, some in English) is presented: Ancit hot briquetting (including blast furnace tests), by-products of Ancit process, coal preparation, high volatile coking coals, preheating, briquetting blending, compacting and preheating, short coking time, wet charges, temperature control and heat consumption, supplies of coke, Solmer coke oven complex at Fos-sur-Mer, etc. (LTN)

  5. Structure of metallurgical coke

    SciTech Connect

    Shapiro, F.L.; Makarov, G.N.; Sidogin, V.P.; Kovalenko, V.P.

    1984-01-01

    Obtaining carboniferous coke satisfying the requirements of the metallurgical production processes constitutes a complicated problem determined by correctness in selecting a technological coking process and selecting the starting coals. Changes in coal charge composition, method, and systems of coking show a considerable effect on the properties of the metallurgical coke. Moreover, each technological process in which coke is used gives rise to quite well-defined requirements as regards its physicochemical properties. The general property of the carboniferous materials, on which their technological properties depend, is the reactive capability, which, in turn, depends to a large extent on the structure (macro-, micro-, and fine structure), the degree of order in the structure, the presence and sizes of crystals, and the extent of development of the system. Therefore, the structure can and must be one of the basic criteria of evaluating the quality when producing and using a specific metallurgical fuel and a reducing agent. A method of complex microscopic analysis of a carboniferous substance of carboniferous coke, iron and chemical etching methods, and optical and electronic (transmission and scanning) microscopy were used to study the structure of metallurgical coke produced by the Dnepropetrovsk Coking Plant. Coke belonging to 7 size-classes was studied microscopically: > 80, 80-60, 60-40, 40-25, 25-10, < 10, and 25-8 mm. The first size classes constitute the principal production of the plant, while the 25-8 mm class is produced to increase the quality of coke supplied to the ferroalloy plants. 5 references, 4 figures, 1 table.

  6. New process for coke-oven gas desulfurization

    SciTech Connect

    Currey, J.H.

    1995-10-01

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  7. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  8. Advanced processes for metallurgical coke. Appendices

    SciTech Connect

    Straus, R.W.; Carsey, J.N.; von Bismarck, G.; Fujishima, C.

    1980-12-01

    Material collected in a survey of German coking plants is presented (some in German; some in English): heat recovery in coke ovens and in coke cooling (both dry and wet methods); use of recovered heat to preheat charge, stamping techniques, blending coals, binders, briquetting, etc. (LTN)

  9. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect

    Michael Volk; Keith Wisecarver

    2003-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  10. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect

    Michael Volk; Keith Wisecarver

    2004-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  11. Method for calcining delayed coke

    SciTech Connect

    Smith, J.H.

    1981-02-17

    Delayed petroleum coke is calcined in an internally-fired vertical shaft kiln. A downwardly-moving bed of green coke is preheated in the top of the kiln by rising combustion gases, then heat soaked at calcining temperatures in the intermediate section of the kiln, and finally cooled by recycle gas moving upwardly from the lower part of the kiln. Partially cooled calcined coke is recovered from the bottom of the kiln.

  12. Process for converting coal into liquid fuel and metallurgical coke

    DOEpatents

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  13. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998

    SciTech Connect

    1998-08-15

    The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

  14. Trends in the automation of coke production

    SciTech Connect

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov

    2009-07-15

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  15. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti

    2009-03-15

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  16. 24 CFR 3280.707 - Heat producing appliances.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 5 2010-04-01 2010-04-01 false Heat producing appliances. 3280.707... Systems § 3280.707 Heat producing appliances. (a) Heat-producing appliances and vents, roof jacks and...) Fuel-burning heat-producing appliances and refrigeration appliances, except ranges and ovens, shall...

  17. Process and apparatus for the dry cooling of coke

    SciTech Connect

    Flockenhaus, C.; Breidenbach, D.; Galow, M.; Hackler, E.; Meckel, J.; Smieskol, S.; Wagener, D.

    1983-10-04

    A process and apparatus for the dry cooling of coke involves the provision of a vessel having therein first and second zones in full communication with each other. Hot coke from a coking operation is introduced into the first zone and is passed through the first and second zones. Raw coke oven gas from the coking operation is introduced into the first zone, thereby reducing the temperature of the coke, while cleaning the raw coke oven gas to form cleaned coke oven gas. The cleaned coke oven gas is removed from the first zone, cooled, and then directly or indirectly utilized as a heat carrier gas introduced into the second zone to therein further reduce the temperature of the coke. The thereby further cooled coke is removed from the second zone.

  18. Characterization of PAHs within PM 10 fraction for ashes from coke production, iron smelt, heating station and power plant stacks in Liaoning Province, China

    NASA Astrophysics Data System (ADS)

    Kong, Shaofei; Shi, Jianwu; Lu, Bing; Qiu, Weiguang; Zhang, Baosheng; Peng, Yue; Zhang, Bowen; Bai, Zhipeng

    2011-07-01

    Polycyclic aromatic hydrocarbons within PM 10 fraction of ashes from two coke production plants, one iron smelt plant, one heating station and one power plant were analyzed with GC-MS technique in 2009. The sum of 17 selected PAHs varied from 290.20 to 7055.72 μg/g and the amounts of carcinogenic PAHs were between 140.33 and 3345.46 μg/g. The most toxic ash was from the coke production plants and then from the iron smelt plant, coal-fired power plant and heating station according to BaP-based toxic equivalent factor (BaPeq) and BaP-based equivalent carcinogenic power (BaPE). PAHs profile of the iron smelt ash was significantly different from others with coefficient of divergence value higher than 0.40. Indicatory PAHs for coke production plants, heating station and coal-fired power plant were mainly 3-ring species such as Acy, Fl and Ace. While for iron smelt plant, they were Chr and BbF. Diagnostic ratios including Ant/(Ant + Phe), Flu/(Flu + Pyr), BaA/Chr, BbF/BkF, Ind/BghiP, IND/(IND + BghiP), BaP/BghiP, BaP/COR, Pyr/BaP, BaA/(BaA + Chr), BaA/BaP and BaP/(BaP + Chr) were calculated which were mostly different from other stacks for the iron smelt plant.

  19. Six meter coke battery renovation at Great Lakes Division, National Steel Corporation

    SciTech Connect

    Sperner, F.A.; Kalinowsky, R.P. )

    1993-01-01

    In 1990, National Steel Corporation initiated the renovation of its No. 5 Battery Facility to reduce Great Lakes Division dependency on outside coke sources by producing enough coke to meet 60% of Great Lakes Division needs. The renovation of the No. 5 Coke Battery and associated By-Product Plant required work in the Battery, Oven Machinery, Coal Handling, Coke Handling and By-Product Plants No. 3 and No. 2. The paper briefly describes the scope of the renovations, then describes the equipment, modifications made, and results of modifications for the following: coal handling system, oven battery (heating, structural design, and process control), oven machinery (U-tube car, pusher machine, on spot door machine, hood car, and quench car), coke handling, and by-products plant (tar and liquor system, primary cooling, exhausters and tar precipitators, secondary gas cooling/ammonia scrubbing, light oil system, waste water treatment and benzene emission controls, and computerized control system).

  20. Developing an accelerated test of coking tendencies of alternative fuels

    SciTech Connect

    Clevenger, M.D.; Bagby, M.O.; Schwab, A.W.; Goering, C.E.; Savage, L.D.

    1988-07-01

    Burning vegetable oils in direct-injected diesel engines leads to nozzle and combustion chamber coking and eventually to engine damage. Because typical durability tests to detect coking tendencies of fuels are expensive, a one-cylinder diesel engine was instrumented and automated to enable external detection of engine coking in only 5 h. The heat release pattern revealed shifts to later burning as coke accumulated in the engine, but exhaust emissions showed little correlation with coke accumulation.

  1. Coking and gasification process

    DOEpatents

    Billimoria, Rustom M.; Tao, Frank F.

    1986-01-01

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  2. High coking value pitch

    DOEpatents

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  3. Numerical modeling of the aerodynamics, heat exchange, and combustion of a polydisperse ensemble of coke-ash particles in ascending axisymmetric two-phase flow

    SciTech Connect

    B.B. Rokhman

    2009-07-15

    A two-dimensional stationary model of motion, heat and mass exchange, and chemical reaction of polydisperse coke and ash particles in ascending gas-suspension flow has been constructed with allowance for the turbulent and pseudo turbulent mechanisms of transfer in the dispersed phase. The system of equations that describes motion and heat transfer in the solid phase has been closed at the level of the equations for the second moments of velocity and temperature pulsations, whereas the momentum equations of the carrying medium have been closed using the equation for turbulent gas energy, which allows for the influence of the particles and heterogeneous reactions.

  4. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction

  5. Selecting the optimum coke pushing sequence

    SciTech Connect

    V.T. Krivoshein; A.V. Makarov

    2007-01-15

    The sequence of pushing coke ovens is one of the most important aspects of battery operation. The sequence must satisfy a number of technical and process conditions: (1) achieve maximum heating-wall life by avoiding destructive expansion pressure in freshly charged ovens and during pushing of the finished coke; (2) ensure uniform brickwork temperature and prevent overheating by compensating for the high thermal flux in freshly charged ovens due to accumulated heat in adjacent ovens that are in the second half of the coking cycle; (3) ensure the most favorable working conditions and safety for operating personnel; (4) provide additional opportunities for repair personnel to perform various types of work, such as replacing coke-machine rails, without interrupting coal production; (5) perform the maximum number of coke-machine operations simultaneously: pushing, charging, and cleaning doors, frames, and standpipe elbows; and (6) reduce electricity consumption by minimizing idle travel of coke machines.

  6. Emission and profile characteristic of volatile organic compounds emitted from coke production, iron smelt, heating station and power plant in Liaoning Province, China.

    PubMed

    Shi, Jianwu; Deng, Hao; Bai, Zhipeng; Kong, Shaofei; Wang, Xiuyan; Hao, Jiming; Han, Xinyu; Ning, Ping

    2015-05-15

    107 kinds of C₂-C₁₂ volatile organic compound (VOC) mass concentrations and profiles for four types of coal-fired stationary sources in Liaoning Province were studied by a dilution sampling system and GC-MS analysis method, which are of significant importance with regard to VOC emissions in northeast of China. The results showed that there were some differences among these VOC source profiles. The total mass concentrations of analyzed 107 VOC species varied from 10,917 to 19,652 μg m(-3). Halogenated hydrocarbons exhibited higher mass percentages for the VOC source profiles of iron smelt (48.8%) and coke production plant (37.7%). Aromatic hydrocarbons were the most abundant in heating station plant (69.1%). Ketones, alcohols and acetates held 45.0% of total VOCs in thermal power plant. For non-methane hydrocarbons (NMHCs), which are demanded for photochemical assessment in the USA, toluene and n-hexane were the most abundant species in the iron smelt, coke production and thermal power plant, with the mass percentages of 64.8%, 52.7% and 38.6%, respectively. Trimethylbenzene, n-propylbenzene and o,m-ethyltoluene approximately accounted for 70.0% in heating station plant. NMHCs emitted from coke production, iron smelt, heating station and power plant listed above presented different chemical reactivities. The average OH loss rate of NMHCs from heating station, was 4 to 5.6 times higher than that of NMHCs from iron smelt, coke production and power plant, which implies that VOCs emitted from heating station in northeast of China should be controlled firstly to avoid photochemical ozone pollution and protect human health. There are significant variations in the ratios of benzene/toluene and m, p-xylene/ethylbenzene of these coal-fired source profiles. The representativeness of the coal-fired sources studied and the VOC samples collected should be more closely examined. The accuracy of VOC source profiles related to coal-fired processes is highly dependent on

  7. Determination of electrical resistivity of dry coke beds

    SciTech Connect

    Eidem, P.A.; Tangstad, M.; Bakken, J.A.

    2008-02-15

    The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

  8. Method for producing micro heat panels

    NASA Technical Reports Server (NTRS)

    Camarda, Charles J. (Inventor); Peterson, George P. (Inventor); Rummler, Donald R. (Inventor)

    1997-01-01

    Flat or curved micro heat pipe panels are fabricated by arranging essentially parallel filaments in the shape of the desired panel. The configuration of the filaments corresponds to the desired configuration of the tubes that will constitute the heat pipes. A thermally conductive material is then deposited on and around the filaments to fill in the desired shape of the panel. The filaments are then removed, leaving tubular passageways of the desired configuration and surface texture in the material. The tubes are then filled with a working fluid and sealed. Composite micro heat pipe laminates are formed by layering individual micro heat pipe panels and bonding them to each other to form a single structure. The layering sequence of the micro heat pipe panels can be tailored to transport heat preferentially in specific directions as desired for a particular application.

  9. Method for producing heat-resistant semi-inorganic compounds

    NASA Technical Reports Server (NTRS)

    Yajima, S.; Okamura, K.; Shishido, T.; Hasegawa, Y.

    1983-01-01

    The method for producing a heat resistant, semi-inorganic compound is discussed. Five examples in which various alcohols, phenols, and aromatic carbonic acids are used to test heat resistance and solubility are provided.

  10. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  11. Glycerol citrate polyesters produced through microwave heating

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The influence of various heating methods without catalysis to prepare copolyesters from citric acid:glycerol blends were studied. In the presence of short term microwave treatments, i.e., 60 sec at 1200 W, blends of glycerol and citric acid invariably formed solid amorphous copolyesters. Fourier tra...

  12. Coking quality and caking properties of western Canadian coals

    SciTech Connect

    Mourits, F.M.; Price, J.T.; Gransden, J.F.; Leeder, W.R.

    1997-12-31

    Methods exist for predicting coke strength from the caking (thermal rheological) or petrographic properties of a metallurgical coal. These methods, which were derived for Carboniferous coals, frequently indicate that western Canadian Cretaceous coals would not make high quality coke yet both types of coals can produce excellent coke suitable for iron blast furnaces. This paper will discuss why western Canadian metallurgical coals exhibit lower thermal rheological values and how to predict the strength of the coke produced from them.

  13. Power systems utilizing the heat of produced formation fluid

    DOEpatents

    Lambirth, Gene Richard

    2011-01-11

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method includes treating a hydrocarbon containing formation. The method may include providing heat to the formation; producing heated fluid from the formation; and generating electricity from at least a portion of the heated fluid using a Kalina cycle.

  14. Progress toward the Hercules coke-to-methanol plant

    SciTech Connect

    Galloway, T.R.; Chiramoute, J.; Pack, G.E.; Patterson, J.

    1983-08-01

    A progress report is given on the Hercules coke-to-methanol plant. The plant gasifies petroleum coke in a fluidized bed to produce syngas for the methanol plant already on site and fuel gas for a combined cycle. The plant will produce 24,000 gallons of chemical grade methanol per day and will cogenerate electricity at about 10 MWe. The coke that is used as the raw feed stock is from a local refinery's fluid coker unit and is sized at minus 6 mm (0.25 inches) and has a heating value of 31 MJ/kg (14,700 Btu/lb). The coke, which is 90% carbon, is relatively unreactive, but can be economically gasified with a catalyst using TOSCO's coke gasification process at 650-850/sup 0/ C (1200-1500/sup 0/ F). This process is unique in that a catalyst reduces the gasification temperature which in turn lowers the oxygen requirements. This lower temperature prevents a slagging ash problem, so typical in other gasification processes. The process also uses less steam than other non-catalytic fluid-bed gasification processes. The capital cost of the plant is 24.2 million dollars and the operating cost is 5.24 million dollars per year. Low interest (8.8%) State of California loans for methanol production are used as well as the alcohol tax credit. The energy cost was found to be around $5/MMBtu for a 20 cent/gal tax credit and a coke feed at $20/ton.

  15. Coke dust enhances coke plant wastewater treatment.

    PubMed

    Burmistrz, Piotr; Rozwadowski, Andrzej; Burmistrz, Michał; Karcz, Aleksander

    2014-12-01

    Coke plant wastewater contain many toxic pollutants. Despite physico-chemical and biological treatment this specific type of wastewater has a significant impact on environment and human health. This article presents results of research on industrial adsorptive coke plant wastewater treatment. As a sorbent the coke dust, dozen times less expensive than pulverized activated carbon, was used. Treatment was conducted in three scenarios: adsorptive after full treatment with coke dust at 15 g L(-1), biological treatment enhanced with coke dust at 0.3-0.5 g L(-1) and addition of coke dust at 0.3 g L(-1) prior to the biological treatment. The enhanced biological treatment proved the most effective. It allowed additional removal of 147-178 mg COD kg(-1) of coke dust. PMID:25113994

  16. Compositions produced using an in situ heat treatment process

    DOEpatents

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  17. Innovative Clean Coal Technology Program: Coke oven gas cleaning demonstration project, Bethlehem Steel Corporation Sparrows Point Plant, Baltimore County, Maryland: Environmental Assessment

    SciTech Connect

    Not Available

    1989-12-01

    This Assessment has been prepared by the US Department of Energy (DOE) to evaluate environmental issues associated with a project that will be cost-shared by DOE and private industry under the Innovative Clean Coal Technology Program. The proposed action is a coke oven gas cleaning technology demonstration project proposed to be installed and operated at the Bethlehem Steel Corporation, Sparrows Point Plant, in Baltimore County, Maryland. Alternatives to the proposed action, which include no action, delayed action, and the use of alternate sites or technologies, are discussed. Three basic steel manufacturing operations are carried out at the Sparrows Point Plant: (1) pyrolytic conversion of coal to coke (carbon) in coke ovens; (2) combination of coke, iron ore, and limestone in a blast furnace to produce iron; and (3) refinement of iron to steel in oxygen or open-hearth furnaces. The Coke Works at the plant consists of three operational coke batteries and two Coal Chemicals plants. Bituminous coal is heated in a coke oven in the absence of air to remove its volatile components. About 70% of the coal feed is converted to coke; the remaining 30% consists of by-product gases and vapors. These by-product gases are treated in the Coal Chemicals plants to recover usable and marketable products, including coke oven gas, which is used to fuel the ovens and furnaces within the plant. The analysis concluded that no significant, environmental impacts would result from the proposed project. 12 refs., 11 figs., 10 tabs.

  18. HEAT TRANSFER AND TRITIUM PRODUCING SYSTEM

    DOEpatents

    Johnson, E.F.

    1962-06-01

    This invention related to a circulating lithium-containing blanket system in a neution source hav'ing a magnetic field associated therewith. The blanket serves simultaneously and efficiently as a heat transfer mediunm and as a source of tritium. The blanket is composed of a lithium-6-enriched fused salt selected from the group consisting of lithium nitrite, lithium nitrate, a mixture of said salts, a mixture of each of said salts with lithium oxide, and a mixture of said salts with each other and with lithium oxide. The moderator, which is contained within the blanket in a separate conduit, can be water. A stellarator is one of the neutron sources which can be used in this invention. (AEC)

  19. Modern outline for a recuperator coke oven

    SciTech Connect

    Flockenhaus, C.; Proetzl, M.; Rohde, W.

    1983-01-01

    This paper describes the design of a demonstration plant, and the results obtained in this, for the testing of Didier Engineering's 2-stage recuperative system. The two stages are: (I) partial recuperation using a metallic heat exchanger and making special use of radiation; (II) direct heat exchange between coke oven waste gas and coking coal for thermal treatment making special use of convection. It is concluded that this type of oven meets the requirements for economic production of coke in chamber-type ovens even after the year 2000. 4 references.

  20. Compositions produced using an in situ heat treatment process

    SciTech Connect

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Henh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2009-10-20

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  1. Prospects for use of lean coking coal from the Kuznetsk coalfield for coking

    SciTech Connect

    Sulimov, G.I.; Agafonov, A.A.; Ol'shanetskii, L.G.

    1983-06-01

    Coals suitable for opencast working in the southern Kuzbass form a transitional stage between low-volatile caking and lean coal and have been incorporated satisfactorily in layer coking charges together with conventional coking coal. Strength tests showed a reasonably strong metallurgical product. Two collieries in particular offered promising coals with a narrow range of vitrinite contents and varying only in rank. These have been blended with a fat coal from Pechora to produce an exceptional metallurgical coke.

  2. Zone control of lean gas underfiring for coke ovens

    SciTech Connect

    Corbman, P.; Faber, P.V.

    1982-02-09

    A coke oven battery is disclosed of the type that is underfired with coke oven gas. A system of horizontal bus flues and valve controls is provided for controlling the supply of lean gas fuel, such as blast furnace gas or any other lean gas, selectively to the gas flues in heating zones of the coke oven chamber walls and the recirculation of waste gas therefrom, so as to achieve the optimum fuel consumption under varying bulk density conditions of the coal mass in the coke oven chamber from the coke side to the pusher side.

  3. Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride

    SciTech Connect

    Sotowa, Chiaki; Korai, Yozo; Mochida, Isao

    1995-12-31

    Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

  4. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel

  5. Cocaine (Coke, Crack) Facts

    MedlinePlus

    ... That People Abuse » Cocaine (Coke, Crack) Facts Cocaine (Coke, Crack) Facts Listen Cocaine is a white ... Version Download "My life was built around getting cocaine and getting high." Stacey is recovering from her ...

  6. Method of operating horizontal coke oven batteries

    SciTech Connect

    Strobel, M.; Thiersch, F.B.

    1981-09-22

    A horizontal coke oven battery construction in which a pusher is mounted to extend into the batteries from one side and push coke out of the batteries on the opposite side, comprises a plurality of coke oven batteries disposed in a row. A first waste gas flue extends along the pusher side of the batteries and a second waste gas flue extends along the coke side. A stack flue at one end of the batteries is connected to the first and second waste gas flues. The construction includes means for directing the heating gases into each oven battery during operation so that, in respect to the pusher and coke size, approximately one-half of the batteries is heated by upward burning and the other half is heated by downward burning. For example, all odd numbered batteries may be heated in the same direction and all even numbered batteries heated in the same direction. The invention also comprises a two-section regenerative heating system having reversing winches wherein the heating on one-half or approximately one-half of the oven chambers is equipped for upward burning and the heating of the other half is equipped with downward burning. Between the two halves, a center head maybe be provided, or only one reversing winch may be provided at the end of the battery.

  7. Possibilities of coke manufacture in nonpollutant conditions

    SciTech Connect

    Barca, F.; Panaitescu, C.; Vidrighin, C.; Peleanu, I.; Albastroiu, P.

    1994-12-31

    The paper presents some possibilities to obtain coke briquettes from anthracite, using as binders petroleum pitch, wheat flour, cement, plaster, ashes from power-plants dried from the electrofilters. Specific thermal post-treatment were proposed for each case, such as: oxidation or heating at low temperatures (under 300 C). As a result the authors obtained coke briquettes to be used in small equipment, with no pollutant pyrogenetic treatment.

  8. Radiative heat transport instability in a laser produced inhomogeneous plasma

    SciTech Connect

    Bychenkov, V. Yu.; Rozmus, W.

    2015-08-15

    A laser produced high-Z plasma in which an energy balance is achieved due to radiation emission and radiative heat transfer supports ion acoustic instability. A linear dispersion relation is derived, and instability is compared to the radiation cooling instability [R. G. Evans, Plasma Phys. Controlled Fusion 27, 751 (1985)]. Under conditions of indirect drive fusion experiments, the driving term for the instability is the radiative heat flux and, in particular, the density dependence of the radiative heat conductivity. A specific example of thermal Bremsstrahlung radiation source has been considered. This instability may lead to plasma jet formation and anisotropic x-ray generation, thus affecting inertial confinement fusion related experiments.

  9. Method for producing heat treated composite nuclear fuel containers

    SciTech Connect

    Rosenbaum, H.S.

    1993-06-29

    A method is described for producing composite constructed nuclear fuel containers for service in water cooled nuclear fission reactors comprising a tubular zirconium alloy casing having a protective lining of a zirconium metal covering the inside surface of the zirconium alloy tubular casing and being metallurgically bonded thereto, consisting essentially of the steps of: heat treating a large diameter zirconium alloy tube comprising a beta-quench treatment of heating the zirconium alloy to a temperature sufficient to recrystallize the zirconium alloy to its beta phase of at least about 970 C and then rapidly cooling the thus heated and recrystallized zirconium alloy tube stock, heat treating a large diameter zirconium metal hollow liner stock comprising a beta-quench treatment of heating the zirconium metal to a temperature sufficient to recrystallize the zirconium metal to its beta phase of at least about 900 C and then rapidly cooling the thus heated and recrystallized zirconium metal hollow liner stock, assembling the heat treated zirconium alloy tube stock and heat treated lining stock with the hollow zirconium metal lining stock inserted inclose fitting contact within the tube stock, metallurgically bonding the tube and liner stocks providing a composite tubular stock unit with the tube stock surrounding the lining stock, and reducing the circumference of the assembled composite tubular stock unit down to a size suitable for service as a lined tubular container for nuclear fuel in a series of progressive reductions in circumference applied in sequence.

  10. Carcinogen assessment of coke oven emissions. Final report

    SciTech Connect

    Not Available

    1984-02-01

    Coke oven workers in Allegheny County, Pennsylvania and at 10 non-Allegheny County coke plants in the United States and Canada were found to be at an excess risk of mortality from cancer of all sites and from cancer of the lungs, bronchus, trachea, kidney, and prostate. An important finding of this study was the dose-response found by both length of exposure and intensity of exposure (top or side of the ovens) for mortality from cancer of the lungs, bronchus, and trachea. A study of Japanese coke oven workers also found them to be at an excess risk of lung cancer mortality. British studies of cancer mortality in coke oven workers have generally been negative, but there were weaknesses in these studies. Coke oven emissions produce positive results in mutagenicity studies. Coal tar, a condensate of coke oven emissions, and various constituents of coke oven emissions have been found to be positive in both mutagenicity and animal carcinogenicity studies.

  11. 24 CFR 3280.707 - Heat producing appliances.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ...) Fuel-burning heat-producing appliances and refrigeration appliances, except ranges and ovens, shall be... appliance manufacturer's instructions. (d) Performance efficiency. (1) All automatic electric storage water... of Household Automatic Electric Storage Type Water Heaters, ANSI C72.1-1972. (2) All gas and...

  12. 24 CFR 3280.707 - Heat producing appliances.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ...) Fuel-burning heat-producing appliances and refrigeration appliances, except ranges and ovens, shall be... appliance manufacturer's instructions. (d) Performance efficiency. (1) All automatic electric storage water... of Household Automatic Electric Storage Type Water Heaters, ANSI C72.1-1972. (2) All gas and...

  13. 24 CFR 3280.707 - Heat producing appliances.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Utilization Efficiency of not less than that specified in 10 CFR part 430, Energy Conservation Program for... CFR part 430, Energy Conservation Program for Consumer Products: Energy Conservation Standards for... 24 Housing and Urban Development 5 2014-04-01 2014-04-01 false Heat producing appliances....

  14. Graphitized needle cokes and natural graphites for lithium intercalation

    SciTech Connect

    Tran, T.D.; Spellman, L.M.; Pekala, R.W.; Goldberger, W.M.; Kinoshita, K.

    1996-05-10

    This paper examined effects of heat treatment and milling (before or after heat treatment) on the (electrochemical) intercalating ability of needle petroleum coke; natural graphite particles are included for comparison. 1 tab, 4 figs, 7 refs.

  15. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and

  16. Heat production in an Archean crustal profile and implications for heat flow and mobilization of heat-producing elements

    NASA Technical Reports Server (NTRS)

    Ashwal, L. D.; Morgan, P.; Kelley, S. A.; Percival, J. A.

    1987-01-01

    Concentrations of heat producing elements (Th, U, and K) in 58 samples representative of the main lithologies in a 100-km transect of the Superior Province of the Canadian Shield have been obtained. The relatively large variation in heat production found among the silicic plutonic rocks is shown to correlate with modal abundances of accessory minerals, and these variations are interpreted as premetamorphic. The present data suggest fundamental differences in crustal radioactivity distributions between granitic and more mafic terrains, and indicate that a previously determined apparently linear heat flow-heat production relationship for the Kapuskasing area does not relate to the distribution of heat production with depth.

  17. [Preliminary investigation on emission of PCDD/Fs and DL-PCBs through flue gas from coke plants in China].

    PubMed

    Sun, Peng-Cheng; Li, Xiao-Lu; Cheng, Gang; Lu, Yong; Wu, Chang-Min; Wu, Chang-Min; Luo, Jin-Hong

    2014-07-01

    According to the Stockholm Convention, polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs) are classified into unintentionally produced persistent organic pollutants (UP-POPs), and named dioxins. Coke production as a thermal process contains organic matters, metal and chlorine, is considered to be a potential source of dioxins. Intensive studies on the emission of dioxins from coking industry are still very scarce. In order to estimate the emission properties of dioxins through coke production, isotope dilution HRGC/HRMS technique was used to determine the concentration of dioxins through flue gas during heating of coal. Three results were obtained. First, total toxic equivalents at each stationary emission source were in the range of 3.9-30.0 pg x m(-3) (at WHO-TEQ) for dioxins which was lower than other thermal processes such as municipal solid waste incineration. Second, higher chlorinated PCDD/Fs were the dominant congeners. Third, emissions of dioxins were dependent on coking pattern. Stamping coking and higher coking chamber may lead to lower emission. PMID:25244832

  18. Method and apparatus for controlling crossflow in a double collector main coke oven battery

    SciTech Connect

    Bauer, E.G.

    1986-07-08

    A method is described of controlling the crossflow of gases given off by a coal mass during the production of coke in a coke oven having a coke side collector main and a pusher side collector main comprising the steps of: (a) determining the temperature difference between the temperature in the coke side standpipe and the temperature in the pusher side standpipe, (b) determining the temperature difference between the temperature in the freespace adjacent the coke side of the coke oven and the temperature in the freespace adjacent the pusher side of the coke oven, (c) determining the temperature difference between the temperature of the heating wall of the coke oven adjacent the coke side of the coke oven and the temperature of the heating wall of the coke oven adjacent the pusher side of the coke oven, and (d) opening the coke side standpipe control valve and gooseneck damper and the pusher side standpipe control valve and gooseneck damper, if they are not in the open position, if the temperature difference of step (b) is substantially the same as the temperature difference of step (c) and the temperature difference of step (a) is greater than about 50/sup 0/F in order to control crossflow.

  19. Analysis of laser-produces jets from locally heated targets

    NASA Astrophysics Data System (ADS)

    Schmitz, Holger; Robinson, Alex

    2015-11-01

    Recent simulations showed that it might be possible to produce a jet by locally heating a foil target with a high intensity laser, so as to produce a single blast wave which then drives jet formation. In contrast to many earlier experimental setups, the jets in this configuration are formed by a two stage process similar to that thought to be responsible for jets from young stellar objects. As the blast wave expands into the ambient medium it creates an inverse conical density structure. This inverse cone focuses the flow into a conically converging flow which then turns into a narrow jet. The realisation of this two step process in an experiment could make it possible to study the formation of stellar jets in the laboratory. We present new results investigating the criteria that lead to the creation of the inverse conical structure and the subsequent jet formation. The localised heating necessary for driving the jet is achieved by guiding the electrons in self generated magnetic fields at resistivity gradients. We present simulations demonstrating the geometries that lead to the localised heating suitable for jet formation. This work is funded by the European Research Council, grant STRUCMAGFAST (ERC-StG-2012).

  20. Reduction of phosphorus and alkali levels in coking coals

    SciTech Connect

    Hoare, I.C.; Waugh, A.B.

    1995-12-31

    A number of coals, though exhibiting desirable coking properties, can have undesirable levels of alkalis and phosphorus. All the phosphorus in the coal will report to the coke, eventually to the iron and thence to the steel, with adverse effects on its metallurgical properties. Alkalis have damaging effects on the blast furnace operation and can be responsible for loss of heat, loss of production, efficiency loss and reduced furnace life. Buyers of coking coal commonly specify such parameters as phosphorus in coal and alkalis in ash, with penalties and rejection over certain limits. With the introduction of new direct reduction technologies such as COREX and HISMELT, and others such as PCI, it is anticipated that coal producers will have even tighter phosphorus and alkali specifications imposed on their products. Phosphorus is predominantly inorganic in origin occurring in a wide variety of minerals in coal, but its main source is apatite. It can be found mainly in the lower density fractions of the coal and intimately bound, so that conventional physical beneficiation techniques are relatively ineffective. CSIRO has developed a cost effective, selective chemical demineralization treatment, which can be applied to the problem of high alkali, high phosphorus coals. This particular technique makes use of unrefined organic acid, which also has the advantage of being low in cost and environmentally benign. In this paper, the effectiveness of acid demineralization of a number of coals is discussed, within the context of their phosphorus and alkali distributions throughout various size/density fractions.

  1. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect

    Jin, H.G.; Sun, S.; Han, W.; Gao, L.

    2009-09-15

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  2. Effect of bulk density of coking coal on swelling pressure.

    PubMed

    Bai, Jinfeng; Yang, Chunwang; Zhao, Zhenning; Zhong, Xiangyun; Zhang, Yaru; Xu, Jun; Xi, Bai; Liu, Hongchun

    2013-12-01

    Coking coals are the important raw materials for the iron and steel industries and play an important role on its sustainable development, especially on the stamp-charging coke making with the characteristics of increasing the bulk density. There is a significance on the reasonable usage of the coking coal resource with the reduced production cost, improved efficiency of the economy to develop the stamp-charging coke making technology. Important effects of the density of coking coal on the coking and caking properties were investigated. In the article, the maximum values of swelling pressure and variation of Laowan gas coal and Xinjian 1/3 coking coal, Longhu fat coal and Didao coking coal, which were mined at Shenyang and Qitaihe respectively, were investigated under different bulk densities during the coking. The results showed that when the values of density increased from 0.85 ton/m(3) to 1.05 ton/m(3), for the Laowan gas coal, swelling pressure variation and even the maximum value changed slightly. The swelling pressure was 3.63 KPa when the density was improved to 1.05 ton/m(3); for the Xinjian 1/3 coking coal, the values of swelling pressure changed significantly and the maximum values was 82.88 KPa with the density improved to 1.05 when the coal was heated to 600°C. The coke porosity, which was investigated by automatic microphotometer, decreased from 47.4% to 33.1% with the increasing of the density from 0.85 ton/m(3) to 1.05 ton/m(3), and the decreased value was 14.3%. Meanwhile, the pore structures of four cokes were characterized by an optical microscope. PMID:25078833

  3. Mechanisms of coke formation and fouling in thermal cracking

    SciTech Connect

    Lott, R.K.; Rangwala, H.A.; Hsi, C.

    1995-12-31

    When heavy oil is cracked to produce distillate, coking of the reacting liquid is, in general, preceded by formation of a new, highly viscous liquid phase, rich in coke precursors. Results from pilot-scale experiments using feedstocks from Gudao (China) reported here show that inert-gas stripping of light distillates from the reacting liquid strongly inhibits coking and possibly the partition of precursors into the new phase. Heavy oil, rich in asphaltene, is often reported to have a high coking propensity. This paper provides experimental evidence to show that the asphaltene concentration is not the most critical factor in the coking propensity of heavy oil. Autoclave tests show that the liquid product could contain more than 40% of asphaltene, and yield only 60% of the coke produced by similar tests in which the liquid product contains less than 20% asphaltene. The solubility of asphaltene in the reaction liquid is the most crucial factor affecting coke yield. It controls the coking mechanisms and the fouling tendency of the resulting coke.

  4. Formed coke production with recovery of medium btu gas

    SciTech Connect

    Saller, E.

    1981-09-08

    In the fluidized carbonization and calcination of coal to form a reactive coal calcinate for admixture with bituminous binder for briquetting, curing, and coking to produce form coke, there is improvement in recovering medium Btu gases in the overheads by using as the fluidizing medium oxygen diluted with steam or carbon dioxide and removing the steam or carbon dioxide from the overheads.

  5. Recycling of hazardous waste materials in the coking process.

    PubMed

    Alvarez, R; Barriocanal, C; Díez, M A; Cimadevilla, J L G; Casal, M D; Canga, C S

    2004-03-01

    Every year the coking industry produces a significant amount of tarry and other wastes in byproducts plants. For the most part these wastes have not been put to any practical use. In addition, an integrated factory produces several waste oils which differ in composition and quantity, e.g., wastes from the steel rolling-mill process. In this work, the possibility of using such waste materials as binders in a partial briquetting process for metallurgical coke production is explored. By means of this coking procedure, a strong metallurgical coke not inferior in quality to coke from conventional coal blends is produced at pilot and semi-industrial scales. The use of such wastes, some of which are classified as hazardous materials, will avoid the need for dumping, thereby contributing to the protection of the environment as well as reducing the costs related to waste disposal. PMID:15046368

  6. Method for removal of furfural coke from metal surfaces

    SciTech Connect

    Turner, J.D.

    1990-02-27

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  7. Upgrading coke strength by a coal-blend-compaction process

    SciTech Connect

    Fun, F.; Brayton, W.E.; Shoenberger, R.W.

    1981-01-01

    In the continuing effort to upgrade the strength of coke made from available coal blends, US Steel is developing coal-blend compaction as an alternative method to coal preheating. In this process the coal blend is compacted to produce relatively weak compacted materials, which are subsequently degraded into controlled size fractions of intimately integrated particles of the multicomponent coal blend. The degraded blend particles are charged into conventional coke ovens for coking. Coal-blend-compaction tests conducted in the laboratory with coals from the Appalachian basin showed substantial improvement in coke strength. The encouraging laboratory results dictated a commerical scale test at US Steel's Gary Works. This plant test, in which more than 200 tons of coal blend was used, further confirmed the improvement in coke strength by the coal-blend-compaction process. Potential benefits of the process include (1) retrospective adaptation to existing coke batteries, (2) improved strength of coke from regular coal blends, (3) maintenance of same or higher coke strength with poor coal blends, and (4) economics that are competitive with or better than those of coal preheating. Continuing developments are being investigated in a compaction pilot plant and commercial coke ovens at US Steel's Clairton Works, mainly to establish engineering criteria and optimal controls for large-scale installations. 9 figures, 2 tables.

  8. Numerical and experimental analyses of the radiant heat flux produced by quartz heating systems

    NASA Technical Reports Server (NTRS)

    Turner, Travis L.; Ash, Robert L.

    1994-01-01

    A method is developed for predicting the radiant heat flux distribution produced by tungsten filament, tubular fused-quartz envelope heating systems with reflectors. The method is an application of Monte Carlo simulation, which takes the form of a random walk or ray tracing scheme. The method is applied to four systems of increasing complexity, including a single lamp without a reflector, a single lamp with a Hat reflector, a single lamp with a parabolic reflector, and up to six lamps in a six-lamp contoured-reflector heating unit. The application of the Monte Carlo method to the simulation of the thermal radiation generated by these systems is discussed. The procedures for numerical implementation are also presented. Experiments were conducted to study these quartz heating systems and to acquire measurements of the corresponding empirical heat flux distributions for correlation with analysis. The experiments were conducted such that several complicating factors could be isolated and studied sequentially. Comparisons of the experimental results with analysis are presented and discussed. Good agreement between the experimental and simulated results was obtained in all cases. This study shows that this method can be used to analyze very complicated quartz heating systems and can account for factors such as spectral properties, specular reflection from curved surfaces, source enhancement due to reflectors and/or adjacent sources, and interaction with a participating medium in a straightforward manner.

  9. Effects of Annealing on Microstructure and Microstrength of Metallurgical Coke

    NASA Astrophysics Data System (ADS)

    Xing, Xing; Zhang, Guangqing; Rogers, Harold; Zulli, Paul; Ostrovski, Oleg

    2013-12-01

    Two metallurgical cokes were heat treated at 1673 K to 2273 K (1400 °C to 2000 °C) in a nitrogen atmosphere. The effect of heat treatment on the microstructure and microstrength of metallurgical cokes was characterized using X-ray diffraction, Raman spectroscopy, and ultra-microindentation. In the process of heat treatment, the microstructure of the metallurgical cokes transformed toward the graphite structure. Raman spectroscopy of reactive maceral-derived component (RMDC) and inert maceral-derived component (IMDC) indicated that the graphitisation degree of the RMDC was slightly lower than that of the IMDC in the original cokes; however graphitisation of the RMDC progressed faster than that of the IMDC during annealing, and became significantly higher after annealing at 2273 K (2000 °C). The microstrength of cokes was significantly degraded in the process of heat treatment. The microstrength of the RMDC was lower, and of its deterioration caused by heat treatment was more severe than IMDC. The degradation of the microstrength of cokes was attributed to their increased graphitisation degree during the heat treatment.

  10. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich

    2009-07-15

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  11. Met coke world summit 2005

    SciTech Connect

    2005-07-01

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  12. 24 CFR 3280.707 - Heat producing appliances.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... (Continued) OFFICE OF ASSISTANT SECRETARY FOR HOUSING-FEDERAL HOUSING COMMISSIONER, DEPARTMENT OF HOUSING AND... with a comfort heating system. (i) When a manufactured home is manufactured to contain a heating... oil burning comfort heating appliances shall have a flue loss of not more than 25 percent, and...

  13. Thickness Optimization for Petroleum Coke in Microwave Dehydrating Based on the Analysis of Dynamic Absorption Efficiency

    NASA Astrophysics Data System (ADS)

    Shang, Xiaobiao; Chen, Junruo; Peng, Jinhui; Chen, Hua; Zhang, Weifeng; Guo, Shenghui; Chen, Guo

    2015-07-01

    An analytical approach is proposed to optimize the thickness of petroleum coke for achieving maximum microwave power absorption in microwave heating based on analysis of reflection loss (RL). The microwave RL of the petroleum coke layer was studied over the moisture content range of 1%-5% at 20 °C and the petroleum coke (10% moisture content) in the temperature range of 20 to 100 °C at 2.45 GHz. The results show that RL depends sensitively on the thickness of the petroleum coke and the absorption peak shifts towards a larger thickness as the moisture content of the petroleum coke increases. There exists a matching thickness corresponding to the maximum microwave absorption, the maximum absorbing peak decreases when the thickness of petroleum coke exceeds the matching thickness. We also show that the absorption peak is found to move towards a smaller thickness region with increasing petroleum coke temperature.

  14. Micro heat pipe panels and method for producing same

    NASA Technical Reports Server (NTRS)

    Camarda, Charles J. (Inventor); Peterson, George P. (Inventor); Rummler, Donald R. (Inventor)

    1996-01-01

    Flat or curved micro heat pipe panels are fabricated by arranging essentially parallel filaments in the shape of the desired panel. The configuration of the filaments corresponds to the desired configuration of the tubes that will constitute the heat pipes. A thermally conductive material is then deposited on and around the filaments to fill in the desired shape of the panel. The filaments are then removed, leaving tubular passageways of the desired configuration and surface texture in the material. The tubes are then filled with a working fluid and sealed. Composite micro heat pipe laminates are formed by layering individual micro heat pipe panels and bonding them to each other to form a single structure. The layering sequence of the micro heat pipe panels can be tailored to transport heat preferentially in specific directions as desired for a particular application.

  15. Coke oven emissions

    Integrated Risk Information System (IRIS)

    Coke oven emissions ; CASRN NA Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogenic Effects

  16. Coke pushing emission control system

    SciTech Connect

    Kwasnoski, D.; Symons, C.

    1980-07-08

    A method is described for controlling coke oven emissions comprising the steps of: (A) aligning a one-spot, open-top coke quenching car with the coke oven, (B) providing a coke guide from the coke oven to the car, (C) positioning a fume hood over the car, with the fume hood having a length about equal to the length of the car, (D) pushing hot coke from the coke oven through the coke guide and into the car, (E) withdrawing gases from the fume hood during step (D) and passing said gases to gas cleaning equipment at a gas flowrate of between about 1000 and about 3500 scfmd per ton of coke pushed under step (D), and (F) substantially upon completion of step (E) moving the car from under the fume hood to a quenching station with the hot coke in the car exposed to the atmosphere and without further withdrawal of gases from the hot coke to the gas cleaning equipment.

  17. Briquetting of coke fines for phosphorus production

    SciTech Connect

    Shpaizer, E.E.; Klimova, L.K.; Mel'nik, A.P.; Egorov, A.A.

    1988-07-20

    Large amounts of coke wastes have accumulated in phosphorus factories. For use as a carbonaceous reducing agent in phosphorus production this waste material should be agglomerated to the required size with satisfactory strength, with minimal consumption of energy and materials. The dependence of briquet strength on a number of important physicochemical factors is described by an equation obtained by least-squares computer analysis of experimental data. Addition of finely ground quartzite to the mixture raises the thermal stability of the briquets. The activation energy and order of overall interaction of phosphoric acid and the ash components of coke, E = 24.8 kJ/mole and n = 0.98, were found by the method of nonisothermal kinetics. Their results show that the reactions leading to increase of briquet strength occur at temperatures from 520 to 670 K, i.e., below the ignition point of coke. Therefore the briquets may be heat-treated in an oxidizing medium; this greatly simplifies the practical process of agglomeration of coke fines.

  18. Non-coke smelting reduction of iron ores: Process modelling

    NASA Astrophysics Data System (ADS)

    Pichestapong, Pipat

    The scarcity of coking coals and the high cost entailed in minimizing the emissions from the coke-making process as well as the relative inflexibility of large production capacity of the conventional blast-furnace ironmaking are the main reasons for the development of non-coke smelting reduction processes with the economical and ecological compatibility. The main objectives of the alternative processes development are to use ordinary coals directly, extend the range of usable raw materials, and allow the operation at a small scale. While most of smelting reduction processes are still in various stages of development, only the COREX ironmaking has successfully reached the industrial application with its first 300000 tpa plant operated in Pretoria, South Africa. The COREX process is composed of two main reactors: the vertical shaft furnace for the gaseous reduction of iron ore to sponge iron, and the melter-gasifier for the gasification of coal and smelting of iron. The gasification process generates the reducing gas mixture (CO and Hsb2) for use in the reduction furnace and also produces heat for smelting of the direct reduced iron. In the present work, the operating data of the COREX process are studied and process material and energy balances are prepared. The coal consumption rate of the COREX process is found higher than the coke consumption rate of the conventional process; however, the total energy consumption for the COREX process compares well with that of the blast furnace. The COREX process also generates surplus gas of high heating value which is suitable for many applications. A reduction model employing the diffusion-limited mass-transfer coupled with virtual equilibrium at core-interface is developed to determine the reduction of iron oxide pellets. The rate of oxygen-transfer between the solid and gas phases is computed by combining the Stefan-Maxwell multi-component diffusion formalism with the iterative equilibrium constant method. The computed

  19. Organic pollution removal from coke plant wastewater using coking coal.

    PubMed

    Gao, Lihui; Li, Shulei; Wang, Yongtian; Sun, Hao

    2015-01-01

    Coke plant wastewater (CPW) is an intractable chemical wastewater, and it contains many toxic pollutants. This article presents the results of research on a semi-industrial adsorption method of coking wastewater treatment. As a sorbent, the coking coal (CC) was a dozen times less expensive than active carbon. The treatment was conducted within two scenarios, as follows: (1) adsorption after biological treatment of CPW with CC at 40 g L(-1); the chemical oxygen demand (COD) removal was 75.66%, and the concentration was reduced from 178.99 to 43.56 mg L(-1); (2) given an adsorption by CC of 250 g L(-1) prior to the biological treatment of CPW, the eliminations of COD and phenol were 58.08% and 67.12%, respectively. The CC that adsorbed organic pollution and was returned to the coking system might have no effect on both coke oven gas and coke. PMID:26114284

  20. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin

    2009-07-15

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  1. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  2. Coke oven door seal

    SciTech Connect

    Hendrych, G.

    1984-01-17

    A coke oven door seal in which a leaf spring is fixed to the inner end of a continuous concave seating structure which is peripherally mounted on the door frame. A terminally convex ridge structure extends endwise from the door jamb to flex the leaf spring sufficiently so as to form a continuous gas tight seal around the door. The leaf spring is flexed by the ridge by an amount that is greater than the deflection which would result only from the application of pressure on the leaf spring by coke oven gases. The leaf spring is also flexed by an amount that is less than the amount which would surpass its elastic limit. In an alternate embodiment, the leaf spring and seat structure are mounted on the door jamb while the ridge is mounted on the door frame.

  3. Electricity-producing heating apparatus utilizing a turbine generator in a semi-closed brayton cycle

    DOEpatents

    Labinov, Solomon D.; Christian, Jeffrey E.

    2003-10-07

    The present invention provides apparatus and methods for producing both heat and electrical energy by burning fuels in a stove or boiler using a novel arrangement of a surface heat exchanger and microturbine-powered generator and novel surface heat exchanger. The equipment is particularly suited for use in rural and relatively undeveloped areas, especially in cold regions and highlands.

  4. [Health risk assessment of coke oven PAHs emissions].

    PubMed

    Bo, Xin; Wang, Gang; Wen, Rou; Zhao, Chun-Li; Wu, Tie; Li, Shi-Bei

    2014-07-01

    Polycyclic aromatic hydrocarbons (PAHs) produced by coke oven are with strong toxicity and carcinogenicity. Taken typical coke oven of iron and steel enterprises as the case study, the dispersion and migration of 13 kinds of PAHs emitted from coke oven were analyzed using AERMOD dispersion model, the carcinogenic and non-carcinogenic risks at the receptors within the modeling domain were evaluated using BREEZE Risk Analyst and the Human Health Risk Assessment Protocol for Hazardous Waste Combustion (HHRAP) was followed, the health risks caused by PAHs emission from coke oven were quantitatively evaluated. The results indicated that attention should be paid to the non-carcinogenic risk of naphthalene emission (the maximum value was 0.97). The carcinogenic risks of each single pollutant were all below 1.0E-06, while the maximum value of total carcinogenic risk was 2.65E-06, which may have some influence on the health of local residents. PMID:25244863

  5. Damage Diagnosis for High Temperature Coke-oven Chamber Walls

    NASA Astrophysics Data System (ADS)

    Sugiura, Masato; Sakaida, Michitaka; Fujikake, Yohichi; Irie, Keisuke

    Metallurgical coke is needed as reducing reagent and energy source in blast furnaces. Most of coke ovens in Japan have been working over 30 years and have become gradually decrepit. A coke oven consists of many coking chambers, and each chamber is 6 m high, 16 m long and 0.4m wide. Uneven damage at the chamber-wall surface such as brick erosion and carbon deposition disturbs production because the coke is pushed horizontally when discharged from the chamber. To diagnose the chamber wall which is constantly sustained at a high temperature, we have developed a water-cooling heat-resistance probe. Line scan cameras mounted in the probe obtain thermal images of the entire chamber-wall surfaces with high resolution. In addition, to measure topographical information of the wall, a laser light-section method combined with line-scan-camera imaging has been considered. It is emphasized that the diagnosis probe works under enormously severe conditions, such as at a temperature of over 1000°C and inside a width of only 0.4m. Clarifying the appearance of chamber-wall damages in operating aged coke ovens, we proposed the index relating unevenness of a chamber-wall surface to pushing load. The index is utilized for the guidance enabling effective repairs of damaged oven walls.

  6. Coke from coal and petroleum

    DOEpatents

    Wynne, Jr., Francis E.; Lopez, Jaime; Zaborowsky, Edward J.

    1981-01-01

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  7. Characterization of coal- and petroleum-derived binder pitches and the interaction of pitch/coke mixtures in pre-baked carbon anodes

    NASA Astrophysics Data System (ADS)

    Suriyapraphadilok, Uthaiporn

    Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder. During the manufacturing of carbon anodes, coal tar pitch is mixed with calcined petroleum coke. The mix of binder, filler and some additives is heated to about 50°C above the softening point of the pitch, typically 160°C. This temperature is sufficient to enable the pitch to wet the coke particles. The mix is then either extruded, vibrated, or pressed to form a green anode. The binding between coke and pitch is very important to the anode properties. There are different binder pitches used in this work, which were standard coal tar pitch (SCTP-2), petroleum pitch (PP-1), gasification pitch (GP-115), coal-extract pitch (WVU-5), and co-coking pitches (HTCCP and OXCCP). Petroleum pitch is a residue produced from heat-treatment and distillation of petroleum fractions. Production of coal-extract pitch involves a prehydrogenation of coal followed by extraction using a dipolar solvent. Gasification pitches are distilled by-product tars produced from the coal gasification process. Co-coking pitch was developed in this work and was obtained from the liquid distillate of co-coking process of coal and heavy petroleum residue. Understanding of composition and structures of pitches from different sources and processes would lead to greater understanding of the binding properties of pitch in carbon anodes and was one of the main focuses in this study. Characterization of pitches by using different techniques including gas chromatography/mass spectrometry (GC/MS), high performance liquid chromatography (HPLC), matrix-assisted laser desorption ionization/mass spectrometry (MALDI/MS), 1H and 13C solution-state nuclear magnetic resonance (NMR), and 13C solid-state NMR yield important chemistry and structural information. The binding, or in other words the interactions in the pitch/coke mixture, is another interest in this

  8. Some physicochemical properties of petroleum pyrolysis cokes

    SciTech Connect

    Cherednik, E.M.; Butyrin, G.M.; Ibraev, S.O.; Shipkov, N.N.; Volchkova, N.I.

    1986-08-01

    The objective of the present work was to investigate the structure and reactivity of cokes and fillers from petroleum. The tests were carried out with KNPS and KNPE petroleum pyrolysis cokes, KZI needle coke obtained on a delayed coking unit, and coke obtained from KO oxidized petroleum residue. The original cokes were subjected to a preliminary thermal treatment in an inert atmosphere and the calcined samples were then used to determine the reactivity, the ash content, the specific surface, the content of impurities, the porosity, and xray characteristics. The presented data show that suppression of the catalytic effect of the impurities by impreganation with manganese phosphate is effective for cokes with low TTT.

  9. Re-examining the pitch/coke wetting and penetration test

    NASA Astrophysics Data System (ADS)

    Cao, Jinan; Buckley, Alan N.; Tomsett, Alan

    2002-02-01

    To produce structurally soundcarbon anodes for use in aluminum smelting, a strong bond between filler and binder coke is necessary. Bond strength results from mechanical interlocking and adhesion of the binder coke to the filler coke. Critical for creating such bonds is the ability of the pitch to wet the coke surface and penetrate the coke porosity during mixing and forming. Wettability is normally assessed from the pitch behavior during the initial stages of a penetration test. In the test, the observed contact angle between a pitch droplet and a bed of fine coke particles is recorded as the temperature is increased. The temperature at which this contact angle becomes 90° is referred to as the wetting temperature of the pitch. The penetration test may be useful to identify pitch and coke combinations that are unlikely to produce baked anodes of acceptable quality with standard paste preparation conditions. It does not, however, provide a measure of the true wettability of a coke by a pitch. The isothermal penetration experiments reported here demonstrate that the observed contact angle of a pitch against a coke bed changes continuously from >90° to <90°, even to 0‡, at a temperature much lower than the wetting temperature derived from the penetration test. The requirements for the measurement of a true contact angle and the difference between the concepts of adhesion and wetting are discussed.

  10. Process for producing an activated carbon adsorbent with integral heat transfer apparatus

    NASA Technical Reports Server (NTRS)

    Jones, Jack A. (Inventor); Yavrouian, Andre H. (Inventor)

    1996-01-01

    A process for producing an integral adsorbent-heat exchanger apparatus useful in ammonia refrigerant heat pump systems. In one embodiment, the process wets an activated carbon particles-solvent mixture with a binder-solvent mixture, presses the binder wetted activated carbon mixture on a metal tube surface and thereafter pyrolyzes the mixture to form a bonded activated carbon matrix adjoined to the tube surface. The integral apparatus can be easily and inexpensively produced by the process in large quantities.

  11. New coke-sorting system at OAO Koks

    SciTech Connect

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov

    2009-05-15

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  12. Evaluation of fly ash from co-combustion of coal and petroleum coke for use in concrete

    SciTech Connect

    Scott, A.N.; Thomas, M.D.A.

    2007-01-15

    An investigation of fly ash (FA) produced from various blends of coal and petroleum coke (pet coke) fired at Belledune Generating Station, New Brunswick, Canada, was conducted to establish its performance relative to FA derived from coal-only combustion and its compliance with CSA A3000. The FA samples were beneficiated by an electrostatic separation process to produce samples for testing with a range of loss-on-ignition (LOI) values. The results of these studies indicate that the combustion of pet coke results in very little inorganic residue (for example, typically less than 0.5% ash) and the main impact on FA resulting from the co-combustion of coal and up to 25% pet coke is an increase in the unburned carbon content and LOI values. The testing of FA after beneficiation indicates that FA produced from fuels with up to 25% pet coke performs as good as FA produced from the same coal without pet coke.

  13. Heat Treatment Devices and Method of Operation Thereof to Produce Dual Microstructure Superalloys Disks

    NASA Technical Reports Server (NTRS)

    Gayda, John (Inventor); Gabb, Timothy P. (Inventor); Kantzos, Peter T. (Inventor)

    2003-01-01

    A heat treatment assembly and heat treatment methods are disclosed for producing different microstructures in the bore and rim portions of nickel-based superalloy disks, particu- larly suited for gas turbine applications. The heat treatment assembly is capable of being removed from the furnace and disassembled to allow rapid fan or oil quenching of the disk. For solutioning heat treatments of the disk, temperatures higher than that of this solvus temperature of the disk are used to produce coarse grains in the rim of each disk so as to give maximum creep and dwell crack resistance at the rim service temperature. At the same time, solution temperature lower than the solvus temperature of the disk are provided to produce fine grain in the bore of the disk so as to give maximum strength and low cycle fatigue resistance.

  14. Production of blast furnace coke via novel briquetting system

    SciTech Connect

    Theodore, F.W.; Wasson, G.E.

    1982-12-07

    A method of making high strength coke briquettes suitable for use as blast furnace coke comprising, (A) providing coal, (B) heating the coal at a temperature at or above the softening point of the coal to form partially carbonized char, (C) cooling the partially carbonized char below the softening point of the coal, (D) mixing the cooled partially carbonized char and tar to form a mixture of tar and partially carbonized char, (E) briquetting the mixture of tar and partially carbonized char to form briquettes of tar and partially carbonized char, (F) calcinating the briquettes to form high strength briquettes.

  15. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  16. Attempts to prevent injector coking with sunflower oil by engine modifications and fuel additives

    SciTech Connect

    van der Walt, A.N.; Hugo, F.J.C.

    1982-01-01

    The effect of injector tip temperature on coking propencity when sunflower oil is used as a fuel for direct injection engines, was tested. Partial retraction of the injector, the addition of a heat shield to the injector and cooling the injector with water was tried. Also, injector temperature was increased by reducing heat transferred to the cylinder head and preheating the sunflower oil. None of these measures could prevent coking of the injector tip. Coating the injector tip with Teflon and increasing the back leakage rate was also tried without success. Only a few of many additives tested, showed some promise of being able to prevent coking. 5 figures, 1 table.

  17. Conductivity heating a subterranean oil shale to create permeability and subsequently produce oil

    SciTech Connect

    Van Meurs, P.; DeRouffignac, E.P.; Vinegar, H.J.; Lucid, M.F.

    1989-12-12

    This patent describes an improvement in a process in which oil is produced from a subterranean oil shale deposit by extending at least one each of heat-injecting and fluid-producing wells into the deposit, establishing a heat-conductive fluid-impermeable barrier between the interior of each heat-injecting well and the adjacent deposit, and then heating the interior of each heat-injecting well at a temperature sufficient to conductively heat oil shale kerogen and cause pyrolysis products to form fractures within the oil shale deposit through which the pyrolysis products are displaced into at least one production well. The improvement is for enhancing the uniformity of the heat fronts moving through the oil shale deposit. Also described is a process for exploiting a target oil shale interval, by progressively expanding a heated treatment zone band from about a geometric center of the target oil shale interval outward, such that the formation or extension of vertical fractures from the heated treatment zone band to the periphery of the target oil shale interval is minimized.

  18. Vented coke oven door apparatus

    SciTech Connect

    Brown, H. B.; Gerding, C. C.

    1980-08-12

    A vented coke oven door includes a door frame having a vertical face surface carrying a plug assembly having a central vertical internal opening to conduct coke oven gas generated at the bottom of a coal charge in a coke oven chamber. The plug assembly includes a plurality of u-shaped refractory plug segments arranged in an end-to-end aligned relation with leg sections of each u-shaped segment extending horizontally into an abutting relation with the face surface of the door frame. Each leg section carries either an embedded hooked end or a t-shaped head of a threaded fastener which is supported by the door frame so that the leg sections are unrestrained against movement toward and away from each other in response to a thermal gradient across the wall thickness of the refractory plug segment. A backing plug plate is fitted into a recess in the leg sections of each plug segment to provide a closure wall to the u-shaped configuration of the segments and forms the vertical passageway for conducting coke oven gas. The backing plug plate has an exposed layer of cast refractory overlying a layer of insulation used to protect the door frame. A seal strip extends about the outer periphery of the door frame to prevent emission of coke oven gas from the coking chamber.

  19. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOEpatents

    Roes, Augustinus Wilhelmus Maria; Mo, Weijian; Muylle, Michel Serge Marie; Mandema, Remco Hugo; Nair, Vijay

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  20. Influence of the conditions of carbonizing pitches on some properties of the cokes

    SciTech Connect

    Cherednik, E.M.; Butyrin, G.M.; Zimina, L.A.

    1983-01-01

    The porous structures, specific surfaces, and reactivities in relation to CO/sub 2/ of cokes of different natures - petroleum cokes and cokes from hard-coal pitch - on their carbonization and subsequent heat treatment in the bulk and in thin films have been studied. A substantial difference has been found in the reactivities and specific surfaces of the cokes according to the conditions of carbonization of the pitches, which is connected with the formation of a considerable microporosity on the carbonization of pitches in thin film, while the laws of the formation of the porous structures of cokes with equivalent radii of the pores r /SUB eq/ greater than 7 nm are identical in the carbonization of pitches under different conditions.

  1. In-situ heat system stimulates paraffinic crude producers in Gulf of Mexico

    SciTech Connect

    Ashton, J.P.; Kirspel, L.J.; Nguyen, H.T.; Credeur, D.J.

    1986-01-01

    A thermal stimulation process that generates downhole heat is presently being used to stimulate oil wells in the Gulf of Mexico. The crude produced from these shallow wells is highly paraffinic. Previous attempts to stimulate these wells with paraffin solvents and acid systems have been unsuccessful. The in situ heat process has yielded tenfold production rate increases and payout times of less than one week.

  2. In-situ heat system stimulates paraffinic-crude producers in Gulf of Mexico

    SciTech Connect

    Ashton, J.P.; Nguyen, H.T.; Credeur, D.J.; Kirspel, L.J.

    1989-05-01

    A thermal stimulation process that generates downhole heat currently is being used to stimulate oil wells in the Gulf of Mexico. The crude produced from these shallow wells is highly paraffinic. Previous attempts to stimulate these wells with paraffin solvents and acid systems have been unsuccessful. The in-situ heat process has yielded 10-fold production rate increases and payout times of less than 1 week.

  3. Heating apparatus and method and device for producing the heating apparatus

    SciTech Connect

    Eriksson, L.; Polteg, A.

    1986-12-16

    This patent describes a heating apparatus of the tiled stove-type having a return chamber section, a stove section providing a hearth, and a foot section. The stove section is formed by placing individual building blocks in alternate horizontal courses arranged such that the vertical joints between blocks in one course are staggered with relation to the vertical joints between blocks in adjoining courses. The improvement described here comprises: blocks for erecting the sections of the heating apparatus including: blocks for the stove section having cut-out portions to provide a central up flue gas passage extending from the hearth, two vertical down flue gas passages situated outside the central passage and two further vertical up flow gas passages also situated outside the central passage. The two down flue gas passages and the two further up flue gas passages are interconnected at their lower ends in a hearth plane, a return block for the return chamber section having cutout portions providing a return chamber interconnecting the upper ends of the central up flue gas passage and the two down flue gas passages for returning flue gasses to the stove section, the blocks for the stove section including a plurality of rear blocks for forming the upper part of the stove section. The rear blocks are successively horizontally thickened to provide a portion of the central flue gas passage inclined forwardly course to course in an upward direction for deflecting the central flue gas path towards the front part of the stove section and into the return chamber, and blocks for the return chamber section having cut-out portions to interconnect the two up flue gas passages in the return chamber section for leading the flue gasses out to a chimney stack.

  4. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report Number 3, November 1, 1998--February 1, 1999

    SciTech Connect

    1999-02-15

    The focus of work during this reporting period was the construction of an automated probe that will be used to measure the thickness of coke deposits in thermal cracking furnaces. A discovery was made during the last reporting period, which indicated that a conventional NDE broadband transducer could be used in conjunction with a sacrificial standoff composed of a fusible alloy to efficiently couple the transducer to a rough surface operating at high temperature. A probe was constructed that incorporates the recent discovery and initial testing of the probe is now underway. Successful development of the coke detector will provide industry with the only available method for on-line measurement of coke deposits. The coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem.

  5. 46 CFR 148.04-15 - Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture). 148.04-15 Section 148.04-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... Requirements for Certain Material § 148.04-15 Petroleum coke, uncalcined; petroleum coke, uncalcined...

  6. Zinc Accumulation and Behavior in Tuyere Coke

    NASA Astrophysics Data System (ADS)

    Li, Kejiang; Zhang, Jianliang; Liu, Zhengjian; Wang, Tianqiu; Ning, Xiaojun; Zhong, Jianbo; Xu, Runsheng; Wang, Guangwei; Ren, Shan; Yang, Tianjun

    2014-10-01

    A case study of zinc oxide, which represents the first report on the occurrence, crystalline features, formation mechanism, and influence of this mineral in tuyere coke, was conducted in this study. A number of zinc oxides, some of which were in hexagonal wurtzite habit, were observed to distribute mainly in coke pores, cracks, surfaces, and around coke minerals. The accumulation of zinc in tuyere coke may enhance the degradation of coke and increase the generation and accumulation of coke fine in a blast furnace, which would cause bad effect on blast furnace operation. Investigations into zinc behavior in tuyere coke can be important for further interpretations of coke degradation in the high temperature zone of a blast furnace.

  7. The Evolution of Structural Order as a Measure of Thermal History of Coke in the Blast Furnace

    NASA Astrophysics Data System (ADS)

    Lundgren, Maria; Khanna, Rita; Ökvist, Lena Sundqvist; Sahajwalla, Veena; Björkman, Bo

    2014-04-01

    Investigations were carried out on cokes heat treated in the laboratory and on cokes extracted from the experimental blast furnace (EBF) raceway and hearth. X-ray diffraction (XRD) measurements were performed to investigate changes in structural order ( L c), chemical transformations in coke ash along with comparative thermodynamic equilibrium studies and the influence of melt. Three data processing approaches were used to compute L c values as a function of temperature and time and linear correlations were established between L c and heat treatment temperatures during laboratory investigations. These were used to estimate temperatures experienced by coke in various regions of EBF and estimated raceway temperatures were seen to follow the profile of combustion peak. The MgAl2O4 spinel was observed in coke submerged in slag during laboratory studies and in cokes found further into the raceway. Coke in contact with hot metal showed XRD peaks corresponding to presence of Fe3Si. The intensity of SiO2 peak in coke ash was seen to decrease with increasing temperature and disappeared at around 1770 K (1500 °C) due to the formation of SiC. This study has shown that the evolution of structural order and chemical transformations in coke could be used to estimate its thermal history in blast furnaces.

  8. Effects of atamp-charging coke making on strength and high temperature thermal properties of coke.

    PubMed

    Zhang, Yaru; Bai, Jinfeng; Xu, Jun; Zhong, Xiangyun; Zhao, Zhenning; Liu, Hongchun

    2013-12-01

    The stamp-charging coke making process has some advantages of improving the operation environment, decreasing fugitive emission, higher gas collection efficiency as well as less environmental pollution. This article describes the different structure strength and high temperature thermal properties of 4 different types of coke manufactured using a conventional coking process and the stamp-charging coke making process. The 4 kinds of cokes were prepared from the mixture of five feed coals blended by the petrography blending method. The results showed that the structure strength indices of coke prepared using the stamp-charging coke method increase sharply. In contrast with conventional coking process, the stamp-charging process improved the coke strength after reaction but had little impact on the coke reactivity index. PMID:25078828

  9. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla

    2009-07-15

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  10. Technological developments in Japanese coke-making from 1950 to the 1980s -- Memories of an old researcher

    SciTech Connect

    Miyazu, Takashi

    1994-12-31

    The author will give a brief history of the technological developments in Japanese coke-making from 1950 to the 1980s. This period may be divided as follows: (a) The Mythological Age (1950--1960) when Japan imported US heavy coking coals such as Itmann, Keystone, etc. It was believed by coke plant engineers that good metallurgical coke could not be produced without such coals, because the blending of these coals with Japanese low rank high fluidity coals yielded unbelievably excellent coke. Their feeling for such US coals was so strong as to approach a kind of religious fervor. (b) The Groping Age (1960--1970) when Japan had a few means to research coke making, such as analytical data, Gieseler Plastometer and test coking ovens. Therefore, most of the studies were repeated ``trial and error``. (c) The Take-off Age (1970--1980s) when Japan introduced the very useful weapon for research into coal and coke -- ``Petrographic Studies``. It is no exaggeration to say that the application of petrographic studies was the most important factor in the technological developments of coke-making in Japan during this period. The blending design using many kinds of coal was able to achieve the minimization of the coke cost at that time, and it would have been impossible but for the studies.

  11. Solid fossil-fuel recovery by electrical induction heating in situ - A proposal

    NASA Astrophysics Data System (ADS)

    Fisher, S.

    1980-04-01

    A technique, termed electrical induction heating, is proposed for in situ processes of energy production from solid fossil fuels, such as bitumen production from underground distillation of oil sand; oil by underground distillation of oil shale; petroleum from heavy oil by underground mobilization of heavy oil, from either residues of conventional liquid petroleum deposits or new deposits of viscous oil; methane and coal tar from lignite and coal deposits by underground distillation of coal; and generation of electricity by surface combustion of low calorific-value gas from underground coke gasification by combustion of the organic residue left from the underground distillation of coal by induction heating. A method of surface distillation of mined coking coal by induction heating to produce coke, methane, and coal tar is also proposed.

  12. Lipolytic Changes in Fermented Sausages Produced with Turkey Meat: Effects of Starter Culture and Heat Treatment

    PubMed Central

    Kolsarici, Nuray; Candoğan, Kezban

    2014-01-01

    In this study, the effects of two different commercial starter culture mixes and processing methodologies (traditional and heat process) on the lipolytic changes of fermented sausages manufactured with turkey meat were evaluated during processing stages and storage. Free fatty acid (FFA) value increased with fermentation and during storage over 120 d in all fermented sausage groups produced with both processing methodologies (p<0.05). After drying stage, free fatty acid values of traditional style and heat processed fermented sausages were between 10.54-13.01% and 6.56-8.49%, respectively. Thiobarbituric acid (TBA) values of traditionally processed fermented sausages were between 0.220-0.450 mg·kg-1, and TBA values of heat processed fermented sausages were in a range of 0.405-0.795 mg·kg-1. Oleic and linoleic acids were predominant fatty acids in all fermented sausages. It was seen that fermented sausage groups produced with starter culture had lower TBA and FFA values in comparison with the control groups, and heat application inhibited the lipase enzyme activity and had an improving effect on lipid oxidation. As a result of these effects, heat processed fermented sausages had lower FFA and higher TBA values than the traditionally processed groups. PMID:26760744

  13. Monte Carlo simulation of the radiant field produced by a multiple-lamp quartz heating system

    NASA Technical Reports Server (NTRS)

    Turner, Travis L.

    1991-01-01

    A method is developed for predicting the radiant heat flux distribution produced by a reflected bank of tungsten-filament tubular-quartz radiant heaters. The method is correlated with experimental results from two cases, one consisting of a single lamp and a flat reflector and the other consisting of a single lamp and a parabolic reflector. The simulation methodology, computer implementation, and experimental procedures are discussed. Analytical refinements necessary for comparison with experiment are discussed and applied to a multilamp, common reflector heating system.

  14. SiC/C nanocable structure produced in silicon carbide by arc plasma heating

    NASA Astrophysics Data System (ADS)

    Nayak, B. B.

    2012-01-01

    Defect-free and long SiC/C nanocables have been produced by heating SiC powder at 3000°C by employing dc arc plasma (Ar) in a specially designed configuration of graphite arc. Microstructural characterizations of the heat-treated powder carried out by TEM, HRTEM, SAED, EDS, and micro Raman spectroscopy showed the nanocables to consist of a SiC shell/sheath stuffed with wire type solid C core. A possible mechanism is discussed to explain the cable-type growth.

  15. Direct evidence of strongly inhomogeneous energy deposition in target heating with laser-produced ion beams.

    PubMed

    Brambrink, E; Schlegel, T; Malka, G; Amthor, K U; Aléonard, M M; Claverie, G; Gerbaux, M; Gobet, F; Hannachi, F; Méot, V; Morel, P; Nicolai, P; Scheurer, J N; Tarisien, M; Tikhonchuk, V; Audebert, P

    2007-06-01

    We report on strong nonuniformities in target heating with intense, laser-produced proton beams. The observed inhomogeneity in energy deposition can strongly perturb equation of state (EOS) measurements with laser-accelerated ions which are planned in several laboratories. Interferometric measurements of the target expansion show different expansion velocities on the front and rear surfaces, indicating a strong difference in local temperature. The nonuniformity indicates at an additional heating mechanism, which seems to originate from electrons in the keV range. PMID:17677318

  16. Heating dynamics and extreme ultraviolet radiation emission of laser-produced Sn plasmas

    SciTech Connect

    Yuspeh, S.; Sequoia, K. L.; Tao, Y.; Tillack, M. S.; Burdt, R. A.; Najmabadi, F.

    2010-06-28

    The impact of 1.064 mum laser absorption depth on the heating and in-band (2% bandwidth) 13.5 nm extreme ultraviolet emissions in Sn plasmas is investigated experimentally and numerically. In-band emission lasting longer than the laser pulse and separation between the laser absorption and in-band emission region are observed. Maximum efficiency is achieved by additional heating of the core of the plasma to allow the optimal temperature to expand to a lower and more optically thin density. This leads to higher temperature plasma that emits less in-band light as compared to CO{sub 2} produced plasma sources for the same application.

  17. Coke from small-diameter tubes analyzed

    SciTech Connect

    Albright, L.F.

    1988-08-29

    The mechanism for coke deposit formation and the nature of the coke itself can vary with the design of the ethylene furnace tube bank. In this article, coke deposits from furnaces with small-diameter pyrolysis tubes are examined. The samples were taken from four furnaces of identical design (Plant B). As in both the first and second installments of the series, the coke deposits were examined using a scanning electron microscope (SEM) and an energy dispersive X-ray analyzer (EDAX). The deposits from the small-diameter tubes are compared with the coke deposits from the furnace discussed in earlier articles. Analysis of the coke in both sets of samples are then used to offer recommendations for improved decoking procedures, operating procedures, better feed selection, and better selection of the metallurgy used in furnace tubes, to extend the operating time of the furnace tubes by reducing the amount and type of coke build up.

  18. Fuel gas main replacement at Acme Steel's coke plant

    SciTech Connect

    Trevino, O. . Chicago Coke Plant)

    1994-09-01

    ACME Steel's Chicago coke plant consists of two 4-meter, 50-oven Wilputte underjet coke-oven batteries. These batteries were constructed in 1956--1957. The use of blast furnace gas was discontinued in the late 1960's. In 1977--1978, the oven walls in both batteries were reconstructed. Reconstruction of the underfire system was limited to rebuilding the coke-oven gas reversing cocks and meter in orifices. By the early 1980's, the 24-in. diameter underfire fuel gas mains of both batteries developed leaks at the Dresser expansion joints. These leaks were a result of pipe loss due to corrosion. Leaks also developed along the bottoms and sides of both mains. A method is described that permitted pushing temperatures to be maintained during replacement of underfire fuel gas mains. Each of Acme's two, 50-oven, 4-metric Wilputte coke-oven, gas-fired batteries were heated by converting 10-in. diameter decarbonizing air mains into temporary fuel gas mains. Replacement was made one battery at a time, with the temporary 10-in. mains in service for five to eight weeks.

  19. Identification and removal of polycyclic aromatic hydrocarbons in wastewater treatment processes from coke production plants.

    PubMed

    Zhang, Wanhui; Wei, Chaohai; Yan, Bo; Feng, Chunhua; Zhao, Guobao; Lin, Chong; Yuan, Mengyang; Wu, Chaofei; Ren, Yuan; Hu, Yun

    2013-09-01

    Identification and removal of polycyclic aromatic hydrocarbons (PAHs) were investigated at two coke plants located in Shaoguan, Guangdong Province of China. Samples of raw coking wastewaters and wastewaters from subunits of a coke production plant were analyzed using gas chromatography-mass spectrometry (GC/MS) to provide a detailed chemical characterization of PAHs. The identification and characterization of PAH isomers was based on a positive match of mass spectral data of sample peaks with those for PAH isomers in mass spectra databases with electron impact ionization mass spectra and retention times of internal reference compounds. In total, 270 PAH compounds including numerous nitrogen, oxygen, and sulfur heteroatomic derivatives were positively identified for the first time. Quantitative analysis of target PAHs revealed that total PAH concentrations in coking wastewaters were in the range of 98.5 ± 8.9 to 216 ± 20.2 μg/L, with 3-4-ring PAHs as dominant compounds. Calculation of daily PAH output from four plant subunits indicated that PAHs in the coking wastewater came mainly from ammonia stripping wastewater. Coking wastewater treatment processes played an important role in removing PAHs in coking wastewater, successfully removing 92 % of the target compounds. However, 69 weakly polar compounds, including PAH isomers, were still discharged in the final effluent, producing 8.8 ± 2.7 to 31.9 ± 6.8 g/day of PAHs with potential toxicity to environmental waters. The study of coking wastewater herein proposed can be used to better predict improvement of coke production facilities and treatment conditions according to the identification and removal of PAHs in the coke plant as well as to assess risks associated with continuous discharge of these contaminants to receiving waters. PMID:23589270

  20. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  1. Integrated coke, asphalt and jet fuel production process and apparatus

    DOEpatents

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  2. KRESS INDIRECT DRY COOLING SYSTEM, BETHLEHEM STEEL'S COKE PLANT DEMONSTRATION AT SPARROWS POINT, MARYLAND - VOLUME 2. APPENDICES G-N

    EPA Science Inventory

    The report evaluates the Kress Indirect Dry Cooling (KIDC) process, an innovative system for handling and cooling coke produced from a slot-type by-product coke oven battery. The report is based on the test work and demonstration of the system at Bethlehem Steel Corporation's Sp...

  3. KRESS INDIRECT DRY COOLING SYSTEM - BETHLEHEM STEEL'S COKE PLANT DEMONSTRATION AT SPARROWS POINT, MARYLAND - VOLUME 2. APPENDICES G-N

    EPA Science Inventory

    The report evaluates the Kress Indirect Dry Cooling (KIDC) process, an innovative system for handling and cooling coke produced from a slot-type by-product coke oven battery. he report is based on the test work and demonstration of the system at Bethlehem Steel Corporation's Spar...

  4. Coke-oven by-product modifications at National Steel's Great Lakes Div

    SciTech Connect

    Kalinowsky, R.P. . Great Lakes Division); Platts, M. )

    1994-10-01

    The rebuilt by-products plant, and coal and coke material handling facilities began operation in Nov. 1992. Coal handling facilities were reused with repairs and modifications, such as new vibrating bin bottoms, bin blasters and variable-speed belts with weigh scales for an accurate coal blend. Coke handling consists of two new fixed-blade rack and pinion drive coke plows, new conveyors and screening station. The by-products plant processes 48 million cu ft of coke-oven gas per day through two rehabilitated primary coolers, one of two rehabilitated exhausters, two new tar precipitators in parallel, two new ammonia scrubbers with secondary cooling in series and two rehabilitated light oil scrubbers in series. Environmental facilities include ammonia stills, catalytic ammonia destruction reactors with waste heat boilers and complete gas blanketing for benzene control. All facilities are PLC and DCS controlled with data trending capability. The by-product plant met all performance guarantees without any problems.

  5. Causes of {open_quotes}undercut{close_quotes} development in coke-oven brickwork

    SciTech Connect

    Krivoshein, V.T.

    1992-12-31

    By no means the least important fault that can develop in coke-oven refractories, and which lowers the productivity and shortens the life of coke-oven batteries is the development of so-called {open_quotes}undercuts,{close_quotes} whereby longitudinal fissures of variable depth and length appear in the first one or two rows of bricks form the floor. On the other hand, large-scale undercutting only develops in individual batteries, and many coking plant workers employed in the servicing and upkeep of the coke ovens are unfamiliar with the problem. No convincing explanation has yet been forthcoming, and consequently no effective measures have been laid down for its prevention. The first large-scale outbreak of undercutting in this country occurred in 1956-1957, in No. 1-4 batteries (side heating) at the Kuznetsk and Magnitogorsk II & SW-plants. 2 refs., 3 tabs.

  6. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  7. Heat shock decreases the embryonic quality of frozen-thawed bovine blastocysts produced in vitro

    PubMed Central

    MORI, Miyuki; HAYASHI, Takeshi; ISOZAKI, Yoshihiro; TAKENOUCHI, Naoki; SAKATANI, Miki

    2015-01-01

    In this study, the effect of heat shock on frozen-thawed blastocysts was evaluated using in vitro-produced (IVP) bovine embryos. In experiment 1, the effects of 6 h of heat shock at 41.0 C on fresh blastocysts were evaluated. HSPA1A expression as a reflection of stress was increased by heat shock (P < 0.05), but the expressions of the quality markers IFNT and POU5F1 were not affected. In experiment 2, frozen-thawed blastocysts were incubated at 38.5 C for 6 h (cryo-con) or exposed to heat shock at 41.0 C for 6 h (cryo-HS). Then, blastocysts were cultured at 38.5 C until 48 h after thawing (both conditions). Cryo-HS blastocysts exhibited a decreased recovery rate: HSPA1A expression was dramatically increased compared with that in fresh or cryo-con blastocysts at 6 h, and IFNT expression was decreased compared with that in cryo-con blastocysts at 6 h (both P < 0.05). Cryo-con blastocysts at 6 h also exhibited higher HSPA1A expression than fresh blastocysts (P < 0.05). At 48 h after thawing, the number of hatched blastocysts and blastocyst diameter were lower in cryo-HS blastocysts (P < 0.05). Cryo-con blastocysts showed lower POU5F1 levels at 48 h than fresh, cryo-con or cryo-HS blastocysts at 6 h (P < 0.05), but their POU5F1 levels were not different from those of cryo-HS blastocysts at 48 h. These results indicated that application of heat shock to frozen-thawed blastocysts was highly damaging. The increase in damage by the interaction of freezing-thawing and heat shock might be one reason for the low conception rate in frozen-thawed embryo transfer in summer. PMID:26096768

  8. Net Shape Fins for Compact Heat Exchanger Produced by Cold Spray

    NASA Astrophysics Data System (ADS)

    Cormier, Yannick; Dupuis, Philippe; Jodoin, Bertrand; Corbeil, Antoine

    2013-10-01

    This work explores the manufacturability of pyramidal fin arrays produced using the cold spray process. Near-net shaped pyramidal fin arrays of various sizes and fin densities were manufactured using masks made of commercially available steel wire mesh. The feedstock powders used to produce the fins are characterized using scanning electron microscopy. Obstruction of the masks was investigated. The standoff distances between the substrate, mesh, and nozzle were empirically determined. Fin array characterization was performed using digital microscopy. The fin arrays' heat transfer performance was assessed experimentally for a range of Reynolds number relevant to the application sought. The fins produced using the cold spray process outperform traditional straight (rectangular) fins at the same fin density and it is hypothesized that this is due to increased fluid mixing and turbulence.

  9. Selection of equipment for coke processing

    SciTech Connect

    Pokhodenko, N.T.; Kuznetsov, V.A.; Nurlygayanova, V.M.; Petrunina, O.A.

    1984-07-01

    This article shows how the design and selection of equipment for the crushing, transportation, and storage of petroleum coke is dependent on the physicomechanical properties of the coke. The mechanical properties of petroleum coke depend on its total porosity, which is determined from true and apparent densities. Topics considered include screen composition, bulk density, the degree of compaction, coefficients of internal and external friction, segregation, and the angle of repose. A vibrating platform operating at 350 cycles per minute was used to investigate the dynamics of compaction of coke fractions during rail transport. It is emphasized that the physical properties of coke as a free-flowing material are of paramount importance in designing the processing and transportation systems and storage facilities for coking and calcining units.

  10. Application of quality improvement techniques to meet coke battery environmental regulations

    SciTech Connect

    Lively, D.L.

    1993-01-01

    Citizens Gas and Coke Utility operates three coke oven batteries, producing both foundry coke and blast furnace coke, under the trade name Indianapolis Coke. Active participation in the regulation negotiation process by the Vice President of Indianapolis Coke allowed the company to accurately anticipate the environmental regulations, long before they were set in law. Several improvements were put into motion that helps them meet the new environmental regulations. Better trained operators with new job positions dedicated solely to environmental compliance, an extensive environmental training program, and two innovations, a portable oven door milling and cleaning machine and three new computer applications are the result of team efforts. The focus of this paper is development of the computer applications designed to enhance three areas of environmental compliance. The three areas addressed by the applications are documentation and information deployment, problem solving, and resource allocation. Through quality improvement techniques and team oriented problem solving, new approaches to environmental data collection and analysis have helped Indianapolis Coke meet the ever tightening environmental regulations.

  11. Equation of state studies of warm dense matter samples heated by laser produced proton beams

    NASA Astrophysics Data System (ADS)

    Hoarty, D. J.; Guymer, T.; James, S. F.; Gumbrell, E.; Brown, C. R. D.; Hill, M.; Morton, J.; Doyle, H.

    2012-03-01

    Heating of matter by proton beams produced by short pulse, laser-solid target interaction has been demonstrated over the last ten years by a number of workers. In the work described in this paper heating by a pulse of laser produced protons has been combined with high-resolution soft x-ray radiography to record the expansion of thin wire targets. Analysis of the radiographs yields material properties in the warm dense matter regime. These measurements imply initial temperatures in the experimental samples over a range from 14 eV up to 40 eV; the sample densities varied from solid to a tenth solid density. Assuming an adiabatic expansion after the initial proton heating phase isentropes of the aluminium sample material were inferred and compared to tabulated data from the SESAME equation of state library. The proton spectrum was also measured using calibrated magnetic spectrometers and radiochromic film. The accuracy of the technique used to infer material data is discussed along with possible future development.

  12. K2CO3 catalysis on the reactivity of top charged coke and stamp charged coke

    NASA Astrophysics Data System (ADS)

    Pang, Qing-hai; Zhang, Jian-liang; Qi, Cheng-lin; Ma, Chao; Kong, De-wen; Mao, Rui

    2013-01-01

    The catalysis of K2CO3 on the reactivity of top charged coke and stamp charged coke from Pansteel in China was studied. The coke reaction index of the stamp charged coke was 1%-2% higher than that of the top charged coke. Under the catalysis of K2CO3, the coke reaction index of both cokes approximately increased by 4%, 6%, 10% and 6% at 900, 1000, 1100 and 1200°C, respectively. The reactivity of the K-enriched stamp charged coke was 1%-2% higher than that of the K-enriched top charged coke below 1100°C. However, only negligible differences were found in the temperature zone between 1100 and 1200°C. Scanning electron microscopy images illustrated that pores in the top charged coke were smaller and equally distributed, while relatively more big pores exist non-homogenously in stamp charged coke. Due to the different processes in production, the stamp charged coke was more porous and most of the pores tended to be applanate. Cracks were observed in the microstructure of the stamp charged coke during the carbon solution reaction, implying the inferior quality of the stamp charged coke to the top charged coke at high temperature. Diffusion of K during the carbon solution reaction was studied by the energy dispersive spectrometry. It is found that K gradually spreads into the center of lumpy coke with the rising of temperature and is equally distributed on the edges of pores at 1200°C. Besides, oxidation reactions of functional groups become faster with the catalysis of K.content

  13. Life Cycle Analysis of High Quality Recycled Aggregate Produced byHeating and Rubbing Method

    NASA Astrophysics Data System (ADS)

    Shima, Hirokazu; Matsuhashi, Ryuji; Yoshida, Yoshikuni; Tateyashiki, Hisashi

    Most of demolished concrete is recycled as road subbase, but its generation is expected to increase rapidly and exceed the demand of road subbase in a near future. To promote the recycling of concrete, the technology to produce high quality recycled aggregate by the heating and rubbing method has been developed. In this method, demolished concrete is heated up to about 300°C in a heater to make cement paste brittle with its dehydration. The heated concrete is then rubbed in two mills to recover the recycled aggregate, while the paste is removed from the surface of aggregate and collected as cement fine powder. In this method, much energy is consumed to heat and rub concrete; however, the cement fine powder is utilized for a soil stabilizer and cement raw materials, so that the environmental load is reduced in cement manufacturing. The life cycle analysis of the recycled aggregate is carried out to evaluate this technology. As a result, the life cycle CO2 is a negative value because the deduction of CO2 emission in cement manufacturing by the powder is much large. This technology is proved to be very effective to reduce CO2.

  14. EXTERIOR VIEW, BEE HIVE COKE OVEN DOOR. Pratt Coal ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR VIEW, BEE HIVE COKE OVEN DOOR. - Pratt Coal & Coke Company, Pratt Mines, Coke Ovens & Railroad, Bounded by First Street, Avenue G, Third Place, Birmingham Southern Railroad, Birmingham, Jefferson County, AL

  15. Coke workers' exposure to volatile organic compounds in northern China: a case study in Shanxi Province.

    PubMed

    He, Qiusheng; Yan, Yulong; Zhang, Yanli; Wang, Xinming; Wang, Yuhang

    2015-06-01

    China is the largest coke producer and exporter in the world, and it has been a major concern that large populations of coke workers are exposed to the associated air pollutants such as volatile organic compounds (VOCs). This study aimed to preliminarily quantify the potential exposure to VOCs emitted from two representative coking plants and assess the potential health risks. Air samples from various stages of coking were collected from the topside of coke ovens and various plant areas and then analyzed for benzene, toluene, ethylbenzene, and xylene (BTEX). The time-weighted average (TWA) concentrations were used to quantify the coke oven emission (COE). The TWA concentrations for benzene were 705.6 and 290.4 μg m(-3) in plant A and plant B, respectively, which showed a higher exposure level than those reported in other countries. COE varied on the topside of coke ovens during charging and pushing processes, from 268.3 to 1197.7 μg m(-3) in plant A and 85.4-489.7 μg m(-3) in plant B. Our results indicate that benzene exposure from the diffusion of tar distillation also exerts significant health risks and thus should also be concerned. Charging and pushing activities accounted for nearly 70 % of benzene dose at the topside, and the benzene exposure risks to the coke oven workers in China were higher than those reported by US EPA. Compared to the reported emission sources, the weight-based ratios of average benzene to toluene, ethylbenzene, and xylene in different COE air samples showed unique characteristic profiles. Based on the B/T ratios from this work and from literatures on several major cities in northern China, it was evident that COE contributes significantly to the severe pollution of VOCs in the air of northern China. Future more rigorous studies are warranted to characterize VOC emission profiles in the stack gas of the coking processes in China. PMID:25975238

  16. Mixture for producing fracture-resistant, fiber-reinforced ceramic material by microwave heating

    DOEpatents

    Meek, T.T.; Blake, R.D.

    1985-04-03

    A fracture-resistant, fiber-reinforced ceramic substrate is produced by a method which involves preparing a ceramic precursor mixture comprising glass material, a coupling agent, and resilient fibers, and then exposing the mixture to microwave energy. The microwave field orients the fibers in the resulting ceramic material in a desired pattern wherein heat later generated in or on the substrate can be dissipated in a desired geometric pattern parallel to the fiber pattern. Additionally, the shunt capacitance of the fracture-resistant, fiber-reinforced ceramic substrate is lower which provides for a quicker transit time for electronic pulses in any conducting pathway etched into the ceramic substrate.

  17. Mixture for producing fracture-resistant, fiber-reinforced ceramic material by microwave heating

    DOEpatents

    Meek, T.T.; Blake, R.D.

    1987-09-22

    A fracture-resistant, fiber-reinforced ceramic substrate is produced by a method which involves preparing a ceramic precursor mixture comprising glass material, a coupling agent, and resilient fibers, and then exposing the mixture to microwave energy. The microwave field orients the fibers in the resulting ceramic material in a desired pattern wherein heat later generated in or on the substrate can be dissipated in a desired geometric pattern parallel to the fiber pattern. Additionally, the shunt capacitance of the fracture-resistant, fiber-reinforced ceramic substrate is lower which provides for a quicker transit time for electronic pulses in any conducting pathway etched into the ceramic substrate. 2 figs.

  18. Mixture for producing fracture-resistant, fiber-reinforced ceramic material by microwave heating

    DOEpatents

    Meek, Thomas T.; Blake, Rodger D.

    1987-01-01

    A fracture-resistant, fiber-reinforced ceramic substrate is produced by a method which involves preparing a ceramic precursor mixture comprising glass material, a coupling agent, and resilient fibers, and then exposing the mixture to microwave energy. The microwave field orients the fibers in the resulting ceramic material in a desired pattern wherein heat later generated in or on the substrate can be dissipated in a desired geometric pattern parallel to the fiber pattern. Additionally, the shunt capacitance of the fracture-resistant, fiber-reinforced ceramic substrate is lower which provides for a quicker transit time for electronic pulses in any conducting pathway etched into the ceramic substrate.

  19. Copyrolysis of coal with coke-oven gas

    SciTech Connect

    Liao, H.; Li, B.; Sun, C.

    1997-12-31

    To improve the economy of the hydropyrolysis process by reducing hydrogen cost, it has been suggested to use cheaper hydrogen-rich gas (such as coke-oven gas) instead of pure hydrogen. Pyrolysis of Chinese Xianfeng lignite has been carried out with real coke-oven gas (COG) as reactive gases at 0.1--5 MPa and the final temperature of 650 C with heating rate of 5--25 C/min in an 10 g fixed-bed reactor. The effects of pressure on product yields under COG were investigated in detail and compared with coal pyrolysis with hydrogen at the same conditions. The results indicate that it is possible to use COG instead of pure hydrogen in hydropyrolysis. To optimize the yields of the valuable chemicals, the experimental conditions must be adjusted.

  20. Antifouling agents for prevention of unwanted coke formation in reactors

    SciTech Connect

    Urban, P.; Stolfa, F.

    1987-03-03

    A method is described to prevent fouling of equipment used in high temperature coke producing petroleum reactions comprising the addition of an alcoholic aqueous mixture of an antifoulant comprising a phthalocyanine compound to a hydrocarbon feedstock at reaction conditions. The addition comprises the steps of: (a) sonicating a mixture of a phthalocyanine compound with water to form an aqueous dispersion of the phthalocyanine; (b) adding an alcohol to the aqueous dispersion to form an alcoholic aqueous dispersion of the phthalocyanine compound; and, (c) adding the alcoholic aqueous dispersion of the phthalocyanine compound to the hydrocarbon feedstock in an amount sufficient to reduce fouling of equipment employed during the high temperature coke producing petroleum reaction.

  1. New designs in the reconstruction of coke-sorting systems

    SciTech Connect

    A.S. Larin; V.V. Demenko; V.L. Voitanik

    2009-07-15

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  2. Beam heated linear theta-pinch device for producing hot plasmas

    DOEpatents

    Bohachevsky, Ihor O.

    1981-01-01

    A device for producing hot plasmas comprising a single turn theta-pinch coil, a fast discharge capacitor bank connected to the coil, a fuel element disposed along the center axis of the coil, a predetermined gas disposed within the theta-pinch coil, and a high power photon, electron or ion beam generator concentrically aligned to the theta-pinch coil. Discharge of the capacitor bank generates a cylindrical plasma sheath within the theta-pinch coil which heats the outer layer of the fuel element to form a fuel element plasma layer. The beam deposits energy in either the cylindrical plasma sheath or the fuel element plasma layer to assist the implosion of the fuel element to produce a hot plasma.

  3. Regeneration of coked catalysts: The effect of aging upon the characteristics of the coke deposits

    SciTech Connect

    Royo, C.; Ibarra, J.V.; Monzon, A.; Santamaria, J. . Dept. de Ingenieria Quimica y Tecnologias del Medio Ambiente)

    1994-11-01

    The effect of aging in nitrogen upon the regeneration characteristics of the coke deposits on chromia-alumina catalysts has been investigated. To this end, the coked catalysts have been subjected to various treatments in nitrogen, and the chemical composition and reactivity of the deposits have been investigated. The results show that the process of aging in nitrogen gives rise to significant changes in both the composition and reactivity of the coke deposits, due to the stripping of the coke fractions with a higher volatility. This obviously has important consequences upon the subsequent regeneration, which are also discussed and tested in regeneration experiments using coked catalyst of different ages.

  4. [Environmental and health impacts of wood combustion to produce heat and power].

    PubMed

    Valerio, Federico

    2012-01-01

    Toxic chemicals such as benzene, polycyclic aromatic hydrocarbons, dioxins, and ultra fine particles were found in the smoke produced by wood combustion. Emission factors confirm that, to produce the same energy amount, many more pollutants are emitted by wood than by natural gas. Biomass burning produces a relevant deterioration of air quality inside and outside houses, notably due to emissions of fine and ultra fine dust (PM10, PM2.5) according to reviewed studies. Important improvements in emission quality are obtained with the use of more efficient household heating systems, both in developed and in developing countries. Numerous studies have assessed the possible health effects produced by wood smoke, providing sufficient evidence that the indoor exposure to wood smoke, even in developed countries, can have adverse effects on human health. In 2010 IARC classified wood smoke as a possible human carcinogen. In Europe, electricity generation from biomass combustion is increasing (12% each year) thanks to incentives provided to reduce greenhouse gas emissions and use of fossil fuels.Today adequate studies to assess the environmental and health effects of emissions from power plants fuelled by solid biomasses are still needed. PMID:22418798

  5. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  6. CARCINOGEN ASSESSMENT OF COKE OVEN EMISSIONS

    EPA Science Inventory

    Coke oven workers in Allegheny County, Pennsylvania and at 10 non-Allegheny County coke plants in the United States and Canada were found to be at an excess risk of mortality from cancer of all sites and from cancer of the lungs, bronchus, trachea, kidney, and prostate. An import...

  7. Methane heat transfer investigation

    NASA Technical Reports Server (NTRS)

    1984-01-01

    Future high chamber pressure LOX/hydrocarbon booster engines require copper base alloy main combustion chamber coolant channels similar to the SSME to provide adequate cooling and reusable engine life. Therefore, it is of vital importance to evaluate the heat transfer characteristics and coking thresholds for LNG (94% methane) cooling, with a copper base alloy material adjacent to he fuel coolant. High pressure methane cooling and coking characteristics recently evaluated at Rocketdyne using stainless steel heated tubes at methane bulk temperatures and coolant wall temperatures typical of advanced engine operation except at lower heat fluxes as limited by the tube material. As expected, there was no coking observed. However, coking evaluations need be conducted with a copper base surface exposed to the methane coolant at higher heat fluxes approaching those of future high chamber pressure engines.

  8. Methane heat transfer investigation

    NASA Technical Reports Server (NTRS)

    Cook, R. T.

    1984-01-01

    Future high chamber pressure LOX/hydrocarbon booster engines require copper-base alloy main combustion chamber coolant channels similar to the SSME to provide adequate cooling and resuable engine life. Therefore, it is of vital importance to evaluate the heat transfer characteristics and coking thresholds for LNG (94% methane) cooling, with a copper-base alloy material adjacent to the fuel coolant. High-pressure methane cooling and coking characteristics were recently evaluated using stainless-steel heated tubes at methane bulk temperatures and coolant wall temperatures typical of advanced engine operation except at lower heat fluxes as limited by the tube material. As expected, there was no coking observed. However, coking evaluations need be conducted with a copper-base surface exposed to the methane coolant at higher heat fluxes approaching those of future high chamber pressure engines.

  9. Integration of Thermoelectric Generators and Wood Stove to Produce Heat, Hot Water, and Electrical Power

    NASA Astrophysics Data System (ADS)

    Goudarzi, A. M.; Mazandarani, P.; Panahi, R.; Behsaz, H.; Rezania, A.; Rosendahl, L. A.

    2013-07-01

    Traditional fire stoves are characterized by low efficiency. In this experimental study, the combustion chamber of the stove is augmented by two devices. An electric fan can increase the air-to-fuel ratio in order to increase the system's efficiency and decrease air pollution by providing complete combustion of wood. In addition, thermoelectric generators (TEGs) produce power that can be used to satisfy all basic needs. In this study, a water-based cooling system is designed to increase the efficiency of the TEGs and also produce hot water for residential use. Through a range of tests, an average of 7.9 W was achieved by a commercial TEG with substrate area of 56 mm × 56 mm, which can produce 14.7 W output power at the maximum matched load. The total power generated by the stove is 166 W. Also, in this study a reasonable ratio of fuel to time is described for residential use. The presented prototype is designed to fulfill the basic needs of domestic electricity, hot water, and essential heat for warming the room and cooking.

  10. Ammonium nitrogen removal from coking wastewater by chemical precipitation recycle technology.

    PubMed

    Zhang, Tao; Ding, Lili; Ren, Hongqiang; Xiong, Xiang

    2009-12-01

    Ammonium nitrogen removal from wastewater has been of considerable concern for several decades. In the present research, we examined chemical precipitation recycle technology (CPRT) for ammonium nitrogen removal from coking wastewater. The pyrolysate resulting from magnesium ammonium phosphate (MAP) pyrogenation in sodium hydroxide (NaOH) solution was recycled for ammonium nitrogen removal from coking wastewater. The objective of this study was to investigate the conditions for MAP pyrogenation and to characterize of MAP pyrolysate for its feasibility in recycling. Furthermore, MAP pyrolysate was characterized by scanning electron microscope (FESEM), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FTIR) as well as X-ray diffraction (XRD). The MAP pyrolysate could be produced at the optimal condition of a hydroxyl (OH(-)) to ammonium molar ratio of 2:1, a heating temperature of 110 degrees C, and a heating time of 3h. Surface characterization analysis indicated that the main component of the pyrolysate was amorphous magnesium sodium phosphate (MgNaPO(4)). The pyrolysate could be recycled as a magnesium and phosphate source at an optimum pH of 9.5. When the recycle times were increased, the ammonium nitrogen removal ratio gradually decreased if the pyrolysate was used without supplementation. When the recycle times were increased, the ammonium nitrogen removal efficiency was not decreased if the added pyrolysate was supplemented with MgCl(2).6H(2)O plus Na(2)HPO(4).12H(2)O during treatment. A high ammonium nitrogen removal ratio was obtained by using pre-formed MAP as seeding material. PMID:19850316

  11. ELM simulation experiments using transient heat and particle load produced by a magnetized coaxial plasma gun

    NASA Astrophysics Data System (ADS)

    Shoda, K.; Sakuma, I.; Iwamoto, D.; Kikuchi, Y.; Fukumoto, N.; Nagata, M.

    2011-10-01

    It is considered that thermal transient events such as type I edge-localized modes (ELMs) and disruptions will limit the lifetime of plasma-facing components (PFCs) in ITER. It is predicted that the heat load onto the PFCs during type I ELMs in ITER is 0.2-2MJ/m2 with pulse length of ~0.1-1ms. We have investigated interaction between transient heat and particle load and the PFCs by using a magnetized coaxial plasma gun (MCPG) at University of Hyogo. In the experiment, a pulsed plasma with duration of ~0.5ms, incident ion energy of ~30eV, and surface absorbed energy density of ~0.3-0.7MJ/m2 was produced by the MCPG. However, no melting occurred on a tungsten surface exposed to a single plasma pulse of ~0.7MJ/m2, while cracks clearly appeared at the edge part of the W surface. Thus, we have recently started to improve the performance of the MCPG in order to investigate melt layer dynamics of a tungsten surface such as vapor cloud formation. In the modified MCPG, the capacitor bank energy for the plasma discharge is increased from 24.5 kJ to 144 kJ. In the preliminary experiments, the plasmoid with duration of ~0.6 ms, incident ion energy of ~ 40 eV, and the surface absorbed energy density of ~2 MJ/m2 was successfully produced at the gun voltage of 6 kV.

  12. Coking partially briquetted coal charge under industrial conditions

    SciTech Connect

    Sukhorukov, V.I.; Bezdvernyi, G.N.; Kopeliovich, L.V.; Mishchikhin, V.G.; Berkutov, A.N.; Stepanov, Y.; Abramicheva, A.I.; Topchii, M.P.

    1982-01-01

    The partial briquetting of low grade coals ordinarily unsuitable for coking, has been found to allow use of these materials in the coking process under industrial conditions, with an improvement in coke quality. Coke oven capacity is increased. The binder used is medium temperature coal tar.

  13. Method of hot-briquetting mixtures of coal and coke

    SciTech Connect

    Kleisa, K.; Langhoff, J.; Lehmann, J.; Makrutzki, D.; Nashan, G.

    1980-07-08

    In a method of making briquettes in which coke and coking coal are admixed to form a briquetting mixture having a temperature in the range between about 400 to 500/sup 0/C, the improvement is described wherein the coke temperature is adjusted, prior to mixing of the coke with the coking coal, to a temperature level which will, upon mixing of the coke with the coking coal, result in the mixture having a temperature with +-5% of a predetermined briquetting temperature lying within said range.

  14. Method of charging coke ovens with coal

    SciTech Connect

    Azimov, A.A.; Davydenko, V.M.; Dorfman, G.A.; Gromov, N.F.; Kulakov, N.K.; Likhogub, E.P.; Marapulets, G.N.; Minasov, A.N.; Shestakov, V.A.; Silka, A.N.

    1982-11-23

    A method is claimed for charging coke ovens with coal by: passage of coal through charging holes and simultaneously withdrawing gases evolving from the coal charge through the middle charging holes thereof; holding the coal charge over a period of time sufficient for a coal-charging machine to deliver a next batch of said coal charge for charging the next successive coke oven; completely charging said coke oven while simultaneously charging the next successive coke oven through its extreme charging holes; withdrawing through said middle charging holes of said coke oven being completely charged, said coke-oven gases; and introducing a gas inert to said cokeoven gas in an amount of 15-20% of the total amount of the cokeoven gas being withdrawn. There is also provided a coal-charging machine for carrying out this method comprising a frame with undercarriages, hoppers for containing the coal charge, the number of hoppers corresponding to the number of the charging holes of the coke oven, coal feed devices disposed in the upper portion of the hoppers.

  15. Process for producing fluid fuel from coal

    DOEpatents

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  16. Process for utilizing the waste heat content of condensate and/or vapor produced in the manufacture of sugar

    SciTech Connect

    Huber, H.; Schiweck, H.

    1981-09-22

    A process is provided for utilizing the waste heat content of condensate and/or vapor produced in the manufacture of sugar in which thin juice is cooled, subjected to one or more stages of flash evaporation to concentrate and further cool the juice, after which it is heated with condensate and/or vapor produced elsewhere in the sugar manufacturing process and with incoming thin juice thereby heating the outgoing juice to substantially its original temperature and providing the cooling of the incoming thin juice. In another embodiment completely purified thin juice is concentrated in a multiple effect evaporating plant wherein the vapor produced in the final evaporator is compressed and is returned selectively to one of the preceding evaporators of the evaporating plant for use in heating the juice.

  17. Spotlight on the microbes that produce heat shock protein 90-targeting antibiotics

    PubMed Central

    Piper, Peter W.; Millson, Stefan H.

    2012-01-01

    Heat shock protein 90 (Hsp90) is a promising cancer drug target as a molecular chaperone critical for stabilization and activation of several of the oncoproteins that drive cancer progression. Its actions depend upon its essential ATPase, an activity fortuitously inhibited with a very high degree of selectivity by natural antibiotics: notably the actinomycete-derived benzoquinone ansamycins (e.g. geldanamycin) and certain fungal-derived resorcyclic acid lactones (e.g. radicicol). The molecular interactions made by these antibiotics when bound within the ADP/ATP-binding site of Hsp90 have served as templates for the development of several synthetic Hsp90 inhibitor drugs. Much attention now focuses on the clinical trials of these drugs. However, because microbes have evolved antibiotics to target Hsp90, it is probable that they often exploit Hsp90 inhibition when interacting with each other and with plants. Fungi known to produce Hsp90 inhibitors include mycoparasitic, as well as plant-pathogenic, endophytic and mycorrhizal species. The Hsp90 chaperone may, therefore, be a prominent target in establishing a number of mycoparasitic (interfungal), fungal pathogen–plant and symbiotic fungus–plant relationships. Furthermore the Hsp90 family proteins of the microbes that produce Hsp90 inhibitor antibiotics are able to reveal how drug resistance can arise by amino acid changes in the highly conserved ADP/ATP-binding site of Hsp90. PMID:23271830

  18. A viable process for producing hydrogen synfuel using nuclear fusion heat

    NASA Astrophysics Data System (ADS)

    Galloway, T. R.; Brown, L. C.

    Analytical and costing analyses of a thermochemical water splitting plant powered by a tandem mirror fusion reactor are presented. Design criteria indicated directing high quality steam to the chemical plant, where no liquid metal coolants would be used. Minimal pumping distances for high pressure He, multiple barriers between the neutron-activated blanket and the hydrogen product, and modular construction where possible are necessary. A He-Brayton topping cycle, coupled to a steam-Rankine bottoming cycle are selected. Slightly over 1111 MWt and about 720 MWe could be produced by the plant if all low grade waste heat is directed to the Rankine cycle. SO3 is used with water for the splitting process, then recombined. H2 is siphoned off as a fuel and O2 is delivered to a coal reforming plant. A 30 yr plant life is projected, operating at a 70% thermal efficiency for the splitting process and producing H2 at $10-12/GJ. The plant is expected to become economically viable in the year 2030 if debt financing is available at 12.25% per year.

  19. Heteroatom incorporated coke for electrochemical cell electrode

    DOEpatents

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  20. Heteroatom incorporated coke for electrochemical cell electrode

    DOEpatents

    Lewis, Irwin Charles; Greinke, Ronald Alfred

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  1. 16. Coke 'fines' bin at Furnace D. After delivery to ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    16. Coke 'fines' bin at Furnace D. After delivery to the trestle bins, the coke was screened and the coke 'fines' or breeze, were transported by conveyor to the coke fines bins where it was collected and leaded into dump trucks. The coke fines were then sold for fuel to a sinter plant in Lorain, Ohio. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  2. Improving effectiveness of coke oven patching

    SciTech Connect

    Withrow, J.A.; McCollum, H.R.

    1982-01-01

    An effective patching program is essential to protect the battery against severe damage which would result from air, foul gas, and fuel gas leaks; and to keep it in operating condition for a reasonable life span. In addition to that basic purpose of patching, other areas such as heating efficiency, coke quality, and emissions performance can benefit from an effective program. Clairton Works and US Steel Research have made improvements in the patching program in several broad categories: equipment used for application of patching material, the patching material itself, and practices used in administration of the patching program. The equipment changes include a pusher machine ram-mounted roof patching unit and a new type of patching buggy for use with materials which tend to settle or cake. New materials have been formulated which develop a ceramic bond on the oven refractories and provide superior adherance. Battery Temperature Profiles, Charging Surveys, and Stack Observation Reports are used on a regular basis to identify critical areas for patching beyond those which can be identified by operating personnel on an incidental basis. This paper reviews each of these improvements in Clairton's patching program in terms of the equipment, materials, and practices per se and also discusses the results of implementing these changes.

  3. Reduced coking of fuel nozzles

    SciTech Connect

    Mancini, A.A.; Sager, J.W.; Kobish, T.R.

    1989-01-17

    This patent describes a fuel nozzle useful for a gas turbine engine and having a nozzle face, the combination of fuel supply means on the nozzle, the fuel supply means including an annular fuel discharge body converging in a downstream direction toward a longitudinal central axis of the nozzle and terminating in a downstream fuel discharge orifice substantially on the central axis for discharging fuel from the orifice for mixing with air downstream of the nozzle face, air supply means on the nozzle for discharging air from the nozzle face, and means on the nozzle around the fuel discharge body cooperating with the air supply means for controllably discharging sufficient air flow with locally reduced swirl strength over the fuel discharge body to establish a recirculation zone spaced away from the nozzle face downstream thereof a sufficient distance to substantially reduce coking on the nozzle face.

  4. Human health risk characterization of petroleum coke calcining facility emissions.

    PubMed

    Singh, Davinderjit; Johnson, Giffe T; Harbison, Raymond D

    2015-12-01

    Calcining processes including handling and storage of raw petroleum coke may result in Particulate Matter (PM) and gaseous emissions. Concerns have been raised over the potential association between particulate and aerosol pollution and adverse respiratory health effects including decrements in lung function. This risk characterization evaluated the exposure concentrations of ambient air pollutants including PM10 and gaseous pollutants from a petroleum coke calciner facility. The ambient air pollutant levels were collected through monitors installed at multiple locations in the vicinity of the facility. The measured and modeled particulate levels in ambient air from the calciner facility were compared to standards protective of public health. The results indicated that exposure levels were, on occasions at sites farther from the facility, higher than the public health limit of 150 μg/m(3) 24-h average for PM10. However, the carbon fraction demonstrated that the contribution from the calciner facility was de minimis. Exposure levels of the modeled SO2, CO, NOx and PM10 concentrations were also below public health air quality standards. These results demonstrate that emissions from calcining processes involving petroleum coke, at facilities that are well controlled, are below regulatory standards and are not expected to produce a public health risk. PMID:26520182

  5. KRESS INDIRECT DRY COOLING SYSTEM, BETHLEHEM STEEL'S COKE PLANT DEMONSTRATION AT SPARROWS POINT, MARYLAND - VOLUME 1. TECHNICAL REPORT AND APPENDICES A-F

    EPA Science Inventory

    The report evaluates the Kress Indirect Dry Cooling (KIDC) process, an innovative system for handling and cooling coke produced from a slot-type by-product coke oven battery. he report is based on the test work and demonstration of the system at Bethlehem Steel Corporation's Spar...

  6. KRESS INDIRECT DRY COOLING SYSTEM - BETHLEHEM STEEL'S COKE PLANT DEMONSTRATION AT SPARROWS POINT, MARYLAND - VOLUME 1. TECHNICAL REPORT AND APPENDICES A-F

    EPA Science Inventory

    The report evaluates the Kress Indirect Dry Cooling (KIDC) process, an innovative system for handling and cooling coke produced from a slot-type by-product coke oven battery. he report is based on the test work and demonstration of the system at Bethlehem Steel Corporation's Spar...

  7. [Study on co-pyrolysis of coking-coal, plastic and dust].

    PubMed

    Zhao, Rongfang; Ye, Shufeng; Xie, Yusheng; Chen, Yunfa

    2003-09-01

    The co-pyrolysis processes of different proportions of coking-coal, plastic, metallurgical dust (MD) were investigated using thermal analyzer (Setaram Labsys) under a neutral atmosphere of N2 at the sweep rate of 30 mL/min, the linear heating rate and the final pyrolysis temperature were 5 degrees C/min and 1000 degrees C respectively in this study. The experimental results indicated that both the pyrolysis process of coking-coal and that of plastic were radical mechanism. In other word, within the relatively lower temperature range, a large amount of radicals were generated during their pyrolysis processes and stabilized through the intra-radical rearrangement reactions or inter-radical combination reactions. This means that sulfur containing in coal and plastic tends to formed gaseous sulfides, such as H2S, COS, CS2, etc. When co-existing with MD, these sulfides will react with metal oxides containing in MD to form metal sulfide with high stability and the cleaner coke oven gas (COG) were obtained. Within higher temperature interval of 500 degrees C-1000 degrees C, some of the gaseous products after pyrolysis (e.g. H2, CO and C) reinforce the reduction atmosphere that the coking reaction system needs and accelerate the reduction of metal oxides in MD and gasification of metal, which were conductive to the effective removal of sulfur in coke. Therefore, it is definitely feasible to adding waste plastic and MD into coking-coal to remove the sulfur in COG and coke simultaneously. PMID:14719256

  8. Ultraviolet Raman spectroscopy of catalysts: Adsorption and coke formation in zeolites and vibrational spectra of supported metal oxides

    NASA Astrophysics Data System (ADS)

    Chua, Yek Tann

    2001-10-01

    The primary goal of this dissertation is to study the physicochemical and catalytic properties of zeolites and supported metal oxide catalysts using UV Raman spectroscopy. In order to reduce the thermal degradation and possible photodecomposition of adsorbates by UV radiation, we have developed a novel fluidized bed method for measuring the UV Raman spectra of catalysts and adsorbates. The UV Raman spectra of various organic compounds adsorbed in zeolites H-USY and H-ZSM-5 are recorded. When measurements are performed on stationary and spinning samples, the Raman spectra show the presence of coke, a typical end product of heat and photochemistry. In contrast, the Raman peaks of the unreacted adsorbates dominate the spectra measured using the fluidized bed method. These results indicate that the fluidized bed technique is a good method for measuring UV Raman spectra of catalysts and adsorbates. The formation of coke in the methanol-to-gasoline conversion over zeolite H-ZSM-5 causes deactivation of the catalyst. To gain insight into the formation of coke, we have studied this reaction using UV Raman spectroscopy. The Raman spectral changes suggest coke is produced from conjugated olefins via cyclopentadiene intermediates. Aromatic compounds in gasoline may also be produced from cyclopentadienes. The adsorbate-induced structural changes of zeolites may alter the molecular sieving characteristics of these materials which ultimately affect their performance as catalysts and adsorbents. We have quantified the adsorbate-induced structural changes of zeolite H-RHO using UV Raman spectroscopy. The Raman spectra of the zeolite after the adsorption of water, methanol or acetonitrile are consistent with an increase in the average T-O-T angle of the zeolite of 5-8°. The adsorption of ammonia, on the other hand, decreases the average T-O-T angle by 5°. Because of certain advantages of UV Raman spectroscopy over visible Raman spectroscopy, recently there is a strong interest in

  9. New and revised standards for coke production

    SciTech Connect

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval

    2009-07-15

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  10. Special analyses reveal coke-deposit structure

    SciTech Connect

    Albright, L.F.

    1988-08-01

    A scanning electron microscope (SEM) and an energy dispersive X-ray analyzer (EDAX) have been used to obtain information that clarifies the three mechanisms of coke formation in ethylene furnaces, and to analyze the metal condition at the exit of furnace. The results can be used to examine furnace operations and develop improved ethylene plant practices. In this first of four articles on the analyses of coke and metal samples, the coking mechanisms and coke deposits in a section of tube from an actual ethylene furnace (Furnace A) from a plant on the Texas Gulf Coast are discussed. The second articles in the series will analyze the condition of the tube metal in the same furnace. To show how coke deposition and metal condition dependent on the operating parameters of an ethylene furnace, the third article in the series will show the coke deposition in a Texas Gulf Coast furnace tube (Furnace B) that operated at shorter residence time. The fourth article discusses the metal condition in that furnace. Some recommendations, based on the analyses and findings, are offered in the fourth article that could help extend the life of ethylene furnace tubes, and also improve overall ethylene plant operations.

  11. Commercial cokes and graphites as anode materials for lithium-ion cells

    SciTech Connect

    Derwin, D.J.; Kinoshita, K.; Tran, T.D.; Zaleski, P.

    1998-07-01

    Several types of carbonaceous materials from Superior Graphite Co. were investigated for lithium ion intercalation. These commercially available cokes, graphitized cokes and graphites have a wide range of physical and chemical properties. The coke materials were investigated in propylene carbonate based electrolytes and the graphitic materials were studied in ethylene carbonate/dimethyl solutions to prevent exfoliation. The reversible capacities of disordered cokes are below 230 mAh/g and those for many highly ordered synthetic (artificial) and natural graphites approached 372 mAh/g (LiC{sub 6}). The irreversible capacity losses vary between 15 to as much as 200% of reversible capacities for various types of carbon. Heat treated cokes with the average particle size of 10 microns showed marked improvements in reversible capacity for lithium intercalation. The electrochemical characteristics are correlated with data obtained from scanning electron microscopy (SEM), high resolution transmission electron microscopy (TEM), X-ray diffraction (XRD) and BET surface are analysis. The electrochemical performance, availability, cost and manufacturability of these commercial carbons will be discussed.

  12. Commercial cokes and graphites as anode materials for lithium - ion cells

    SciTech Connect

    Derwin, D J; Kinoshita, K; Tran, T D; Zaleski, P

    2000-10-26

    Several types of carbonaceous materials from Superior Graphite Co. were investigated for lithium ion intercalation. These commercially available cokes, graphitized cokes and graphites have a wide range of physical and chemical properties. The coke materials were investigated in propylene carbonate based electrolytes and the graphitic materials were studied in ethylene carbonate/dimethyl solutions to prevent exfoliation. The reversible capacities of disordered cokes are below 230 mAh/g and those for many highly ordered synthetic (artificial) and natural graphites approached 372 mAh/g (LiC{sub 6}). The irreversible capacity losses vary between 15 to as much as 200% of reversible capacities for various types of carbon. Heat treated cokes with the average particle size of 10 microns showed marked improvements in reversible capacity for lithium intercalation. The electrochemical characteristics are correlated with data obtained from scanning electron microscopy (SEM), high resolution transmission electron microscopy (TEM), X-ray diffraction (XRD) and BET surface area analysis. The electrochemical performance, availability, cost and manufacturability of these commercial carbons will be discussed.

  13. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect

    T.F. Trembach; A.G. Klimenko

    2009-07-15

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  14. Application of NMR techniques for studying coking of FCC catalysts

    SciTech Connect

    Bonardet, J.J.; Barrage, M.C.; Fraissard, J.

    1995-12-31

    NMR occupies an important place in the study of the deactivation of zeolites by coking. Indeed, association of the resonances of several nuclei has shown that it is possible to investigate: the nature of the, carbonaceous; deposits; under certain conditions, the coke content; the mode of zeolite deactivation; the exact location of the internal coke and the evolution of its distribution with the coke content, the presence of carbonaceous; residues at the crystallite surface; the effect of zeolite structure and the nature of the reactant on coking and regeneration. It also reveals the role of extra framework aluminium species and that of certain lattice Al atoms in the coking process.

  15. H2-producing bacterial communities from a heat-treated soil inoculum.

    PubMed

    Iyer, Prabha; Bruns, Mary Ann; Zhang, Husen; Van Ginkel, Steve; Logan, Bruce E

    2004-12-01

    Hydrogen gas (approximately 60% H(2)) was produced in a continuous flow bioreactor inoculated with heat-treated soil, and fed synthetic wastewater containing glucose (9.5 g l(-1)). The pH in the bioreactor was maintained at 5.5 to inhibit consumption of H(2) by methanogens. The objective of this study was to characterize bacterial communities in the reactor operated under two different hydraulic retention times (HRTs of 30-h and 10-h) and temperatures (30 degrees C and 37 degrees C). At 30-h HRT, the H(2) production rate was 80 ml h(-1) and yield was 0.91 mol H(2)/mol glucose. At 10-h HRT, the H(2) production rate was more than 5 times higher at 436 ml h(-1), and yield was 1.61 mol H(2)/mol glucose. Samples were removed from the reactor under steady-state conditions for PCR-based detection of bacterial populations by ribosomal intergenic spacer analysis (RISA). Populations detected at 30-h HRT were more diverse than at 10-h HRT and included representatives of Bacillaceae, Clostridiaceae, and Enterobacteriaceae. At 10-h HRT, only Clostridiaceae were detected. When the temperature of the 10-h HRT reactor was increased from 30 degrees C to 37 degrees C, the steady-state H(2) production rate increased slightly to 463 ml h(-1) and yield was 1.8 mol H(2)/mol glucose. Compared to 30 degrees C, RISA fingerprints at 37 degrees C from the 10-h HRT bioreactor exhibited a clear shift from populations related to Clostridium acidisoli (subcluster Ic) to populations related to Clostridium acetobutylicum (subcluster Ib). PMID:15558274

  16. Estimating concentrations of heat producing elements in the crust near the Sudbury Neutrino Observatory, Ontario, Canada

    NASA Astrophysics Data System (ADS)

    Phaneuf, Catherine; Mareschal, Jean-Claude

    2014-05-01

    Because the concentrations of uranium and thorium in the crust must be determined precisely for the future geoneutrino observations planned at the Sudbury Neutrino Observatory, we investigate whether airborne radiometric surveys can be used to constrain crustal radioactivity. The regional airborne surveys cover a wide area with high spatial resolution (< 250 m), but are only sensitive to a very thin (25 cm) surficial layer. We calculate crustal heat production in the Sudbury region from airborne radiometric surveys and compare with measurements on outcrop and core samples, and with heat flow data. The concentrations of uranium, thorium, and potassium from radiometric surveys are correlated with geology, but heat production estimates are lower than values from rock samples. The radiometric surveys give a mean heat production of 0.8 ± 0.6 (σ) μW m- 3 for more than 176,000 values. The outcrop samples collected along a transect in the Superior Province yield an average heat production of 2.9 ± 2.4 (σ) μW m- 3 and core samples from drill holes yield an average of 2.5 ± 0.8 (σ) μW m- 3. The high heat production in the rock samples is consistent with surface heat flux measurements near Sudbury with a mean value that is 12 mW m- 2 higher than the average Canadian Shield. The study shows that airborne aeromagnetic surveys give useful information on lateral variations in surface heat production but are unlikely to provide the reliable values of heat production needed to calculate the crustal geoneutrino flux. Crustal heat production will be best calculated from heat flux data complemented by heat production measurements on rock samples. The high mean heat production in Sudbury Igneous Complex samples (≈ 1.5 μW m- 3) suggests that the main source of the melt sheet was the very radioactive upper crust of the Superior Province or that the melt sheet was extremely enriched relative to a lower crustal source.

  17. Coking wastewater increases micronucleus frequency in mouse in vivo via oxidative stress.

    PubMed

    Zhu, Na; Li, Hongyan; Li, Guangke; Sang, Nan

    2013-10-01

    Coking wastewater has caused serious health risk in coal-producing areas of China, however its toxic effects have not been well understood. The genotoxicity induced by coking wastewater on mice in vivo and its possible oxidative mechanisms were investigated via observing the induction of micronuclei in polychromatic erythrocytes of mouse bone marrow, and subsequently determining the antioxidative enzyme activities (superoxide dismutase Cu, Zn-SOD, Se-dependent glutathione peroxidase, and catalase), thiobarbituric acid reactive substance contents and protein carbonyl levels in brains and livers of mice. Results showed that the tested coking wastewater caused a significant increase of micronucleus frequencies in a concentration-dependent manner. Also, the sample increased lipid peroxidation and protein oxidation levels, which was accompanied by changes in antioxidative status. Interestingly, pre-treatment with an antioxidant (vitamin C) led to a statistical reduction in the micronucleus frequency caused by coking wastewater. This implies that coking wastewater induces evident genetic damage in mammalian cells, and exposure to polluted areas might pose a potential genotoxic risk to human beings; in the process, oxidative stress played a crucial role. PMID:24494500

  18. Highly coke-resistant ni nanoparticle catalysts with minimal sintering in dry reforming of methane.

    PubMed

    Han, Joung Woo; Kim, Chanyeon; Park, Jun Seong; Lee, Hyunjoo

    2014-02-01

    Nickel catalysts are typically used for hydrogen production by reforming reactions. Reforming methane with carbon dioxide, called dry reforming of methane (DRM), is a good way to produce hydrogen or syngas (a mixture of hydrogen and carbon monoxide) from two notable greenhouse gases. However, Ni catalysts used for DRM suffer from severe coke deposition. It has been known that small Ni nanoparticles are advantageous to reduce coke formation, but the high reaction temperature of DRM (800 °C) inevitably induces aggregation of the nanoparticles, leading to severe coke formation and degraded activity. Here, we develop highly coke-resistant Ni catalysts by immobilizing premade Ni nanoparticles of 5.2 nm in size onto functionalized silica supports, and then coating the Ni/SiO2 catalyst with silica overlayers. The silica overlayers enable the transfer of reactants and products while preventing aggregation of the Ni nanoparticles. The silica-coated Ni catalysts operate stably for 170 h without any degradation in activity. No carbon deposition was observed by temperature programmed oxidation (TPO), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy. The Ni catalysts without silica coating show severe sintering after DRM reaction, and the formation of filamentous carbon was observed. The coke-resistant Ni catalyst is potentially useful in various hydrocarbon transformations. PMID:24402833

  19. VIEW LOOKING NORTHEAST SHOWING TIPPLE FOR LOADING COKED COAL INTO ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING NORTHEAST SHOWING TIPPLE FOR LOADING COKED COAL INTO RAILROAD CARS (FRONT), COAL STORAGE BIN AND TIPPLE FOR COAL TO BE CHARGED IN FURNACES (BACK) - Alverton Coke Works, State Route 981, Alverton, Westmoreland County, PA

  20. 1. GENERAL VIEW OF COKE WORKS LOOKING WEST, SHOWING OVENS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. GENERAL VIEW OF COKE WORKS LOOKING WEST, SHOWING OVENS IN FOREGROUND, LARRY CAR TIPPLE TO THE RIGHT, AND COAL TIPPLE IN CENTERGROUND - Lucernemines Coke Works, 0.2 mile East of Lucerne, Lucerne Mines, Indiana County, PA

  1. 2. Left to right: coke ovens, wharf with belt conveyor, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. Left to right: coke ovens, wharf with belt conveyor, coal bunker, coke stack, brick quencher, gas holder, view framed by bracing for overhead conveyor. Looking south/southeast - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  2. GENERAL OVERVIEW, LOOKING NORTH FROM COKE OVEN SITE, HEIGHT C. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL OVERVIEW, LOOKING NORTH FROM COKE OVEN SITE, HEIGHT C. 20 FEET. - Pratt Coal & Coke Company, Pratt Mines, Tailings Pile, Bounded by First Street, Avenue G, Third Place, Birmingham Southern Railroad, Birmingham, Jefferson County, AL

  3. GENERAL OVERVIEW, LOOKING NORTH FROM BEE HIVE COKE OVEN SITE. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL OVERVIEW, LOOKING NORTH FROM BEE HIVE COKE OVEN SITE. - Pratt Coal & Coke Company, Pratt Mines, Tailings Pile, Bounded by First Street, Avenue G, Third Place, Birmingham Southern Railroad, Birmingham, Jefferson County, AL

  4. VIEW OF EIGHT COKE OVENS ON EAST SIDE OF TOWN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW OF EIGHT COKE OVENS ON EAST SIDE OF TOWN OF ALVERTON, CONSTRUCTED OF YELLOW REFRACTORY BRICK. "WOODLAND M2" AND "BENEZETT - Alverton Coke Works, State Route 981, Alverton, Westmoreland County, PA

  5. 2. GENERAL VIEW LOOKING NORTHEAST, SHOWING COKE MACHINE (CENTER), INTERMEDIATE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. GENERAL VIEW LOOKING NORTHEAST, SHOWING COKE MACHINE (CENTER), INTERMEDIATE TIPPLE (RIGHT), AND OVENS - Shoaf Mine & Coke Works, East side of Shoaf, off Township Route 472, Shoaf, Fayette County, PA

  6. Development of coke strength after reaction (CSR) at Dofasco

    SciTech Connect

    T.W. Todoschuk; J.P. Price; J.F. Gransden

    2004-03-01

    In order to prevent coke degradation without detrimentally affecting blast furnace service life, Dofasco initiated a project to improve coke strength after reaction. The results of the program and Dofasco's prediction model are presented. 9 refs., 12 figs., 9 tabs.

  7. 23. Brick coke quencher, brick stack, metal stack to right, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    23. Brick coke quencher, brick stack, metal stack to right, coke gas pipe to left; in background, BOF building, limestone piles, Levy's Slag Dump. Looking north/northwest - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  8. METALLURGICAL COKE INDUSTRY PARTICULATE EMISSIONS: SOURCE CATEGORY REPORT

    EPA Science Inventory

    The report gives results of a study to develop particulate emission factors based on cutoff size for inhalable particles for the metallurgical coke industry. After a review of available information characterizing particulate emissions from metallurgical coke plants, the data were...

  9. APPLICABILITY OF COKE PLANT CONTROL TECHNOLOGIES TO COAL CONVERSION

    EPA Science Inventory

    The report gives results of comparisons of process and waste stream characteristics from the Byproduct coke over process with selected gasification and liquefaction processes. It includes recommendations regarding control technologies for air, water, and solid wastes. Coke oven c...

  10. 61. INTERIOR VIEW OF THE COKE DRYER BUILDING, LOOKING AT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    61. INTERIOR VIEW OF THE COKE DRYER BUILDING, LOOKING AT FIRE BOXES AND SILOS FOR COKE DRYERS. APRIL 22, 1919. - United States Nitrate Plant No. 2, Reservation Road, Muscle Shoals, Muscle Shoals, Colbert County, AL

  11. Electrical conduction phenomena in coked industrial reforming catalysts

    SciTech Connect

    Daveau, S.; Bonanos, N.

    1997-02-01

    Industrial Pt/Al{sub 2}O{sub 3} reforming catalysts containing up to 26 wt% of carbon have been studied by admittance spectroscopy. Spectra obtained on heating in nitrogen in the range 200--500 C displayed low frequency relaxations, which were interpreted in terms of a network of carbon islands linked by surface ionic conduction. During subsequent cooling, these features disappeared, suggesting that they were generated by dissociation of strongly bound water. Isothermal ac measurements in nitrogen showed that the conductance was determined by the carbon content. Similar measurements made in dilute oxygen showed that the conductance decreased with burn-off of carbon. Analysis of gases evolved on heating revealed aqueous and chloride species, originating from acid sites on the catalyst support. The results suggest that electrical techniques could be used to characterize coked reforming catalysts.

  12. Simulations of ionospheric turbulence produced by HF heating near the upper hybrid layer

    NASA Astrophysics Data System (ADS)

    Najmi, A.; Eliasson, B.; Shao, X.; Milikh, G. M.; Papadopoulos, K.

    2016-06-01

    Heating of the ionosphere by high-frequency (HF), ordinary (O) mode electromagnetic waves can excite magnetic field-aligned density striations, associated with upper and lower hybrid turbulence and electron heating. We have used Vlasov simulations in one spatial and two velocity dimensions to study the induced turbulence in the presence of striations when the O-mode pump is mode converted to large-amplitude upper hybrid oscillations trapped in a striation. Parametric processes give rise to upper and lower hybrid turbulence, as well as to large amplitude, short wavelength electron Bernstein waves. The latter excite stochastic electron heating when their amplitudes exceed a threshold for stochasticity, leading to a rapid increase of the electron temperature by several thousands of kelvin. The results have relevance for high-latitude heating experiments.

  13. Technical and economic assessment of producing hydrogen by reforming syngas from the Battelle indirectly heated biomass gasifier

    SciTech Connect

    Mann, M.K.

    1995-08-01

    The technical and economic feasibility of producing hydrogen from biomass by means of indirectly heated gasification and steam reforming was studied. A detailed process model was developed in ASPEN Plus{trademark} to perform material and energy balances. The results of this simulation were used to size and cost major pieces of equipment from which the determination of the necessary selling price of hydrogen was made. A sensitivity analysis was conducted on the process to study hydrogen price as a function of biomass feedstock cost and hydrogen production efficiency. The gasification system used for this study was the Battelle Columbus Laboratory (BCL) indirectly heated gasifier. The heat necessary for the endothermic gasification reactions is supplied by circulating sand from a char combustor to the gasification vessel. Hydrogen production was accomplished by steam reforming the product synthesis gas (syngas) in a process based on that used for natural gas reforming. Three process configurations were studied. Scheme 1 is the full reforming process, with a primary reformer similar to a process furnace, followed by a high temperature shift reactor and a low temperature shift reactor. Scheme 2 uses only the primary reformer, and Scheme 3 uses the primary reformer and the high temperature shift reactor. A pressure swing adsorption (PSA) system is used in all three schemes to produce a hydrogen product pure enough to be used in fuel cells. Steam is produced through detailed heat integration and is intended to be sold as a by-product.

  14. Preventing the overcharging of coke ovens

    SciTech Connect

    Price, C. A.

    1981-05-19

    A metod is described for preventing the overcharging of coal into a coke oven system in which preheated coal is transported from a storage container to the coke ovens by means of a substantially enclosed continuous conveyor system filled with inert gas. A portion of inert gas within the enclosed conveyor system is carried along with the coal into the coke oven itself. During filling of the oven, this inert gas is carried up and out of the oven standpipes. When the oven becomes filled, however, the standpipe escape route becomes blocked resulting in a rapid pressure buildup within the system. This rapid pressure build-up is utilized to generate a signal to stop further filling of the oven. The instant method may be employed as a primary regulating system, but is more preferably employed as a back-up to conventional sensor probes used for regulating the level of coal.

  15. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  16. Coke formation in the thermal cracking of hydrocarbons. 4: Modeling of coke formation in naphtha cracking

    SciTech Connect

    Reyniers, G.C.; Froment, G.F. . Lab. voor Petrochemische Techniek); Kopinke, F.D.; Zimmermann, G. . Abteilung Hochtemperaturreaktionen am Inst. fuer Technische Chemie)

    1994-11-01

    An extensive experimental program has been carried out in a pilot unit for the thermal cracking of hydrocarbons. On the basis of the experimental information and the insight in the mechanisms for coke formation in pyrolysis reactors, a mathematical model describing the coke formation has been derived. This model has been incorporated in the existing simulation tools at the Laboratorium voor Petrochemische Techniek, and the run length of an industrial naphtha cracking furnace has been accurately simulated. In this way the coking model has been validated.

  17. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  18. Analyses of alternate skirt attachments to coke drums

    SciTech Connect

    Antalffy, L.P.; Baxter, J.E.; Malek, D.W.; Bardia, K.L.; Taagepera, J.

    1995-12-31

    One of the most sensitive areas to cracking in coke drums is the skirt to shell attachment joint. The severe thermal cycling from drum heat up and quenching together with the cycling pressure stresses in the drum acting on the skirt geometry will cause large stress intensity concentrations at the skirt to shell junction. This paper investigates four types of skirt attachments to a coke drum, namely: the conventional fillet weld attachment to the drum cone; a fillet weld attachment to the outside of the vessel shell; a modified design where the skirt is attached by an externally blended weld build up with an internally radiused backing weld; and a design where the skirt is attached to the drum shell by an integral contour machined plate in which the skirt attachment stub is machined. In each case, the thermal gradient and the subsequent thermal stress intensity in the skirt are determined. A comparison of the total stress intensities in each joint is provided to evaluate the comparative advantages of each design. A determination is also made on the effects of slotting in the skirt to alleviate the total stress intensity level in the skirt.

  19. Heat transfer enhancement due to a longitudinal vortex produced by a single winglet in a pipe

    SciTech Connect

    Oyakawa, Kenyu; Senaha, Izuru; Ishikawa, Shuji; Hokama, Mashashige

    1999-07-01

    Longitudinal vortices were artificially generated by a single winglet vortex generator in a pipe. The purpose of this study is to analyze the motion of longitudinal vortices and their effects on heat transfer enhancement. The flow pattern was visualized by means of both fluorescein and rhodamine B as traces in a water flow. The main vortex was moved spirally along the circumference and the behavior of the other vortices was observed. Streamwise and circumferential heat transfer coefficients on the wall, wall static pressure, and velocity distribution in an overall cross section were also measured for the air flow in a range of Reynolds numbers from 18,800 to 62,400. The distributions of the streamwise heat transfer coefficient had a periodic pattern, and the peaks in the distribution were circumferentially moved due to the spiral motion of the main vortex. Lastly, the relationships between the iso-velocity distribution, wall static pressure, and heat transfer characteristics was shown. In the process of forming the vortex behind the winglet vortex generator, behaviors of both the main vortex and the corner vortex were observed as streak lines. The vortex being raised along the end of the winglet, and the vortex ring being rolled up to the main vortex were newly observed. Both patterns of the streamwise velocity on a cross-section and the static pressure on the wall show good correspondences to phenomena of the main vortex spirally flowing downstream. The increased ratio of the heat transfer is similar to that of the friction factor based on the shear stress on the wall surface of the pipe. The quantitative analogy between the heat transfer and the shear stress is confirmed except for some regions, where the effects of the down-wash or blow-away of the secondary flows is caused due to the main vortex.

  20. Cyclic process for producing methane from carbon monoxide with heat removal

    DOEpatents

    Frost, Albert C.; Yang, Chang-lee

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  1. Cyclic process for producing methane in a tubular reactor with effective heat removal

    DOEpatents

    Frost, Albert C.; Yang, Chang-Lee

    1986-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  2. [Emission and source characterization of monoaromatic hydrocarbons from coke production].

    PubMed

    He, Qiu-Sheng; Wang, Xin-Ming; Sheng, Guo-Ying; Fu, Jia-Mo

    2005-09-01

    Monoaromatic hydrocarbons (MAHs) from indigenous and industrial coking processes are studied in Shanxi province. They are sampled on the top of coke ovens and in the chimneys using stainless steel canister and determined by GC/MSD after preconcentration with liquid nitrogen. Benzene, toluene and xylene are the main components among MAHs emitted from coking processes. Benzene and the total MAHs concentrations were as high as 3421.0 microg/m3 and 4 865.9 microg/m3 in the air from indigenous coking, 548.7 microg/m3 and 1 054.8 microg/m3 in the oventop air from industrial coking, and 1 376.4 microg/m3 and 1 819.4 microg/m3 in stack gas from industrial coking, respectively. The MAHs concentrations vary greatly during the indigenous coking process, which in the prophase (from firing to 10 days) is obviously higher than in the anaphase (10 days to quenching the coke). In industrial coking the MAHs in the oventop air are highest when charging the coal and next when transferring the hot coke, but in stack gas they are highest when charging coal and lowest when transferring the coke. Benzene, toluene, ethylbenzene and xylene (BTEX) in industrial coking samples show good linearity, indicating that MAHs in industrial coking might come predominantly from coal pyrolysis; but BTEX distribute dispersedly in indigenous coking samples, indicating that its emission might be affected by many factors. In all samples BTEX ratios especially high B/E ratio, is unique among MAHs sources, and might be helpful to characterize pollution from coking. PMID:16366463

  3. Bactericidal Effect of Selected Antidiarrhoeal Medicinal Plants on Intracellular Heat-Stable Enterotoxin-Producing Escherichia coli

    PubMed Central

    Birdi, Tannaz J.; Brijesh, S.; Daswani, Poonam G.

    2014-01-01

    Diarrhoeal diseases due to enterotoxigenic Escherichia coli continue to be a cause of global concern. Medicinal plants have been gaining popularity as promising antidiarrhoeal agents. In the present study, four antidiarrhoeal plants, viz. Aegle marmelos, Cyperus rotundus, Psidium guajava and Zingiber officinale were screened against a heat-stable toxin-producing enterotoxigenic E. coli strain. Decoctions of these plants were studied for their effect on intracellular killing of the bacterial strain using murine monocytic cell line, J774. [3H] thymidine release assay was used to evaluate the apoptotic/necrotic effect. All plants at concentrations <1% enhanced intracellular killing of the bacteria by J774 cells. However, at higher concentrations, the decoctions induced apoptosis in J774 cells. The study demonstrates that these plants could control diarrhoea caused by heat-stable toxin-producing enterotoxigenic E. coli through their immunomodulatory effect. PMID:25035535

  4. Sodium nitrate containing mixture for producing ceramic-glass-ceramic seal by microwave heating

    DOEpatents

    Blake, R.D.; Meek, T.T.

    1984-10-10

    A mixture for, and method of using such a mixture, for producing a ceramic-glass-ceramic seal by the use of microwave energy are disclosed, wherein the mixture comprises a glass sealing material, a coupling agent, and an oxidizer. The seal produced exhibits greater strength due to its different microstructure. Sodium nitrate is the most preferred oxidizer.

  5. Method for producing ceramic-glass-ceramic seals by microwave heating

    DOEpatents

    Blake, Rodger D.; Meek, Thomas T.

    1986-01-01

    Method for producing a ceramic-glass-ceramic seal by the use of microwave energy, and a sealing mixture which comprises a glass sealing material, a coupling agent, and an oxidizer. The seal produced exhibits greater strength due to its different microstructure. Sodium nitrate is the most preferred oxidizer.

  6. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect

    T.F. Trembach; E.N. Lanina

    2009-07-15

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  7. Method for producing H.sub.2 using a rotating drum reactor with a pulse jet heat source

    DOEpatents

    Paulson, Leland E.

    1990-01-01

    A method of producing hydrogen by an endothermic steam-carbon reaction using a rotating drum reactor and a pulse jet combustor. The pulse jet combustor uses coal dust as a fuel to provide reaction temperatures of 1300.degree. to 1400.degree. F. Low-rank coal, water, limestone and catalyst are fed into the drum reactor where they are heated, tumbled and reacted. Part of the reaction product from the rotating drum reactor is hydrogen which can be utilized in suitable devices.

  8. Novel carbon-rich additives preparation by degradative solvent extraction of biomass wastes for coke-making.

    PubMed

    Zhu, Xianqing; Li, Xian; Xiao, Li; Zhang, Xiaoyong; Tong, Shan; Wu, Chao; Ashida, Ryuichi; Liu, Wenqiang; Miura, Kouichi; Yao, Hong

    2016-05-01

    In this work, two extracts (Soluble and Deposit) were produced by degradative solvent extraction of biomass wastes from 250 to 350°C. The feasibilities of using Soluble and Deposit as additives for coke-making were investigated for the first time. The Soluble and Deposit, having significantly higher carbon content, lower oxygen content and extremely lower ash content than raw biomasses. All Solubles and most of Deposits can melt completely at the temperature ranged from 80 to 120°C and 140 to 180°C, respectively. The additions of Soluble or Deposit into the coke-making coal significantly improved their thermoplastic properties with as high as 9°C increase of the plastic range. Furthermore, the addition of Deposit or Soluble also markedly enhanced the coke quality through increasing coke strength after reaction (CSR) and reducing coke reactivity index (CRI). Therefore, the Soluble and Deposit were proved to be good additives for coke-making. PMID:26871958

  9. Prediction of the quality of coke obtained from vacuum residues by using spectroscopy infrared FTIR-ART

    NASA Astrophysics Data System (ADS)

    León, A. Y.; Rodríguez, N. A.; Mejía, E.; Cabanzo, R.

    2016-02-01

    According to the trend of the heavy crudes and high demand of fuels, it is projected a considerable increase in the production of vacuum residues. With the purpose of taking advantage of these loads, the refineries have been improving conversion processes for the production of better quality distillates. However, as increasing the severity conditions and the species content of resins and asphaltenes high concentrations of coke are obtained. To provide an insight into the quality and cokes properties, in this study fifty (50) coke samples obtained from vacuum residues processed under conditions of thermal cracking and hydroconversion were selected. Each coke was analysed in detail with properties such as fixed carbon, volatile material, ash, and calorific value. Subsequently, a characterization methodology was developed to predict the properties of cokes, by using partial least squares regression, and infrared spectroscopy (FTIR-ATR) in the spectral range from 4000 to 500cm-1. The models obtained by chemometrics allowed to predict the quality of the coke produced from vacuum residues with reliable responses in short periods of time.

  10. Characterization of heat transport dynamics in laser-produced plasmas using collective Thomson scattering: Simulation and proposed experiment

    SciTech Connect

    Cameron, S.M.; Camacho, J.F.

    1995-12-01

    The authors propose an experiment in which the collective Thomson scattering lineshape obtained from ion acoustic waves is used to infer the spatial structure of local heat transport parameters and collisionality in a laser-produced plasma. The peak-height asymmetry in the ion acoustic wave spectrum will be used in conjunction with a recently developed model describing the effects of collisional and Landau damping contributions on the low-frequency electron density fluctuation spectrum to extract the relative electron drift velocity. This drift arises from temperature gradients in the plasma. The local heat flux, which is proportional to the drift, can then be estimated, and the electron thermal conductivity will be inferred from the relationship between the calculated heat flux and the experimentally determined temperature gradient. Damping of the entropy wave component at zero mode frequency is shown to be an estimate of the ion thermal conductivity, and its visibility is a direct measure of the ion-ion mean free path. The authors also propose to measure thermal transport parameters under dynamic conditions in which the plasma is heated impulsively by a laser beam on a fast ({approximately}50 ps) time scale. This technique will enable the authors to study heat transport in the presence of the large temperature gradients that are generated by this local heating mechanism. Deviations of the inferred local thermal conductivity from its Spitzer-Haerm value can be used to study the transition to the nonlocal heat transport regime. The authors have constructed a simple numerical model of this proposed experiment and present the results of a simulation. 41 refs., 9 figs.

  11. Water protection in coke-plant design

    SciTech Connect

    G.I. Alekseev

    2009-07-15

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  12. 77 FR 32998 - Foundry Coke From China

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-04

    ... The Commission instituted this review on December 1, 2011 (76 FR 74810) and determined on March 5, 2012 that it would conduct an expedited review (77 FR 15123, March 14, 2012). The Commission... COMMISSION Foundry Coke From China Determination On the basis of the record \\1\\ developed in the subject...

  13. Cancer mortality among coke oven workers.

    PubMed Central

    Redmond, C K

    1983-01-01

    The OSHA standard for coke oven emissions, which went into effect in January 1977, sets a permissible exposure limit to coke oven emissions of 150 micrograms/m3 benzene-soluble fraction of total particulate matter (BSFTPM). Review of the epidemiologic evidence for the standard indicates an excess relative risk for lung cancer as high as 16-fold in topside coke oven workers with 15 years of exposure or more. There is also evidence for a consistent dose-response relationship in lung cancer mortality when duration and location of employment at the coke ovens are considered. Dose-response models fitted to these same data indicate that, while excess risks may still occur under the OSHA standard, the predicted levels of increased relative risk would be about 30-50% if a linear dose-response model is assumed and 3-7% if a quadratic model is assumed. Lung cancer mortality data for other steelworkers suggest the predicted excess risk has probably been somewhat overestimated, but lack of information on important confounding factors limits further dose-response analysis. PMID:6653539

  14. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  15. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process.

    PubMed

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-01-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration. PMID:27270486

  16. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

    NASA Astrophysics Data System (ADS)

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-06-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration.

  17. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

    PubMed Central

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-01-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration. PMID:27270486

  18. Supersonic Heat Wave Propagation in Laser-Produced Underdense Plasma for Efficient X-Ray Generation

    SciTech Connect

    Tanabe, M; Nishimura, H; Fujioka, S; Nagai, K; Iwamae, A; Ohnishi, N; Fournier, K B; Girard, F; Primout, M; Villette, B; Tobin, M; Mima, K

    2008-06-12

    We have observed supersonic heat wave propagation in a low-density aerogel target ({rho} {approx} 3.2 mg/cc) irradiated at the intensity of 4 x 10{sup 14} W/cm{sup 2}. The heat wave propagation was measured with a time-resolved x-ray imaging diagnostics, and the results were compared with simulations made with the two-dimensional radiation-hydrodynamic code, RAICHO. Propagation velocity of the ionization front gradually decreased as the wave propagates into the target. The reason of decrease is due to increase of laser absorption region as the front propagates and interplay of hydrodynamic motion and reflection of laser propagation. These features are well reported with the simulation.

  19. Coking coals of Mongolia: Distribution and resources

    NASA Astrophysics Data System (ADS)

    Erdenetsogt, Bat-Orshikh; Jargal, Luvsanchultem

    2016-04-01

    The coal deposits of Mongolia tend to become younger from west to east and can be subdivided into two provinces, twelve basins, and three areas. Main controlling factor of coal rank is the age of coal bearing sequences. Western Mongolian coal-bearing province contains mostly high rank bituminous coal in strata from Late Carboniferous. The basins in southern Mongolia and the western part of central Mongolia have low rank bituminous coal in strata from the Permian. The northern and central Mongolian basins contain mainly Jurassic subbituminous coal, whereas the Eastern Mongolian province has Lower Cretaceous lignite. Mongolian known coking coal reserves are located in western, southern and northern Mongolia and related to Carboniferous, Permian and Jurassic sequences, respectively. Pennsylvanian Nuurstkhotgor coal deposit is located in northwestern Mongolia (in Western Mongolian coal-bearing province). The coals have 1-7.5 crucible swelling number (CSN) and 0-86 G-index. Vitrinite reflectance value (Rmax in oil) varies from 0.7% to 1.2% and sulfur content is low, ranging from 0.3% to 0.6% with an average of 0.4%. Coal reserve is estimated to be 1.0 billion ton, of which half is coking coal. Upper Permian Khurengol deposit is situated in western Mongolia (in Western Mongolian coal-bearing province). CSN and G-index of coal are 8-9 and 54-99, respectively. The coals have Rmax of 1.1 to 1.7% (average 1.4%) and sulfur content of 0.2 to 0.6% (average 0.4%). Coking coal reserve of the deposit is estimated to be 340 million ton. Upper Permian Tavantolgoi, the largest coking coal deposit, lies in southern Mongolia (in South Gobi coal-bearing basin). The coals have CSN of 1 to 7.5 and Rmax of 0.7% to 1.2%. Sulfur content is low, ranging from 0.5% to 0.9%. Coal reserve is estimated to be 6.0 billion ton, of which 2.0 billion ton is accounted as coking coal. Lower-Middle Jurassic Ovoot coal is located in northern Mongolia (in Orkhon-Selenge coal-bearing area). This is one of

  20. Microstructured silver surfaces produced by freeze casting for enhanced phase change heat transfer

    NASA Astrophysics Data System (ADS)

    Gouws, G. J.; Shortt, N.

    2015-12-01

    Microporous silver surface layers were formed on copper substrates by means of a modified freeze casting method. The structure of such layers is the result of the templating action of the ice crystals and layers were found to contain a hierarchical porous structure. Three different pore morphologies were present in the microstructure with pore sizes ranging from approximately 0.5 to 200 μm. The application of these surface structures was found to considerably enhance the heat flux during the nucleate phase of pool boiling, with heat fluxes up to five times higher from a microporous surface compared to a bare copper substrate. Bubble formation and departure was found to be significantly different on the two types of surfaces, with smaller bubbles formed with a high density on the microporous surface. The enhancement in heat flux by these structures is most likely due to the combined effect of an increased surface area with high thermal conductivity, an increase in nucleation sites for bubble formation as well as effective wicking from micropores to sustain bubble growth and departure.

  1. Single Chain Variable Fragments Produced in Escherichia coli against Heat-Labile and Heat-Stable Toxins from Enterotoxigenic E. coli

    PubMed Central

    Andrade, Fernanda B.; Nepomuceno, Roberto; Silva, Anderson; Munhoz, Danielle D.; Yamamoto, Bruno B.; Luz, Daniela; Abreu, Patrícia A. E.; Horton, Denise S. P. Q.; Elias, Waldir P.; Ramos, Oscar H. P.; Piazza, Roxane M. F.

    2015-01-01

    Background Diarrhea is a prevalent pathological condition frequently associated to the colonization of the small intestine by enterotoxigenic Escherichia coli (ETEC) strains, known to be endemic in developing countries. These strains can produce two enterotoxins associated with the manifestation of clinical symptoms that can be used to detect these pathogens. Although several detection tests have been developed, minimally equipped laboratories are still in need of simple and cost-effective methods. With the aim to contribute to the development of such diagnostic approaches, we describe here two mouse hybridoma-derived single chain fragment variable (scFv) that were produced in E. coli against enterotoxins of ETEC strains. Methods and Findings Recombinant scFv were developed against ETEC heat-labile toxin (LT) and heat-stable toxin (ST), from previously isolated hybridoma clones. This work reports their design, construction, molecular and functional characterization against LT and ST toxins. Both antibody fragments were able to recognize the cell-interacting toxins by immunofluorescence, the purified toxins by ELISA and also LT-, ST- and LT/ST-producing ETEC strains. Conclusion The developed recombinant scFvs against LT and ST constitute promising starting point for simple and cost-effective ETEC diagnosis. PMID:26154103

  2. Method for determining the end of devolatilizing in a coke oven and adjusting the coke cycle based thereon

    SciTech Connect

    Bauer, E.G.

    1986-02-04

    This patent describes a process for manufacturing coke in a by-product coke oven battery. Each oven is operated over a coking cycle; each coking cycle having an aim total coke cycle time defined by a charging time and an aim push time. The aim push time has a permitted plus or minus deviation. Between the charging time and aim push time there is: (1) a devolatilizing period of estimated length, and (2) a coke soaking period immediately following the devolatilizing period. The method of determining the end of the devolatilizing period consists of: (a) in a first coking cycle, during a devolatilizing period, obtaining liquid catch condensed volatiles specimens from gas samples withdrawn from within the coke oven; (1) determining a reference light-transmitting value of the catch specimens for the devolatilizing period; (b) in a second coking cycle, as the coking cycle approaches an estimated end of the devolatilizing period, obtaining liquid catch specimens having condensed volatiles from gas samples withdrawn from within the coke oven; and (1) determining when an individual light-transmitting value of one of the specimens varies by a pre-selected amount from the reference light-transmitting value.

  3. Measurement of soil bacterial colony temperatures and isolation of a high heat-producing bacterium

    PubMed Central

    2013-01-01

    Background The cellular temperatures of microorganisms are considered to be the same as those of their surroundings because the cellular volume is too small to maintain a cellular temperature that is different from the ambient temperature. However, by forming a colony or a biofilm, microorganisms may be able to maintain a cellular temperature that is different from the ambient temperature. In this study, we measured the temperatures of bacterial colonies isolated from soils using an infrared imager and investigated the thermogenesis by a bacterium that increases its colony temperature. Results The temperatures of some colonies were higher or lower than that of the surrounding medium. A bacterial isolate with the highest colony temperature was identified as Pseudomonas putida. This bacterial isolate had an increased colony temperature when it grew at a temperature suboptimal for its growth. Measurements of heat production using a microcalorimeter showed that the temperature of this extraordinary, microcalorimetrically determined thermogenesis corresponded with the thermographically observed increase in bacterial colony temperature. When investigating the effects of the energy source on this thermal behavior, we found that heat production by this bacterium increased without additional biomass production at a temperature suboptimal for its growth. Conclusions We found that heat production by bacteria affected the bacterial colony temperature and that a bacterium identified as Pseudomonas putida could maintain a cellular temperature different from the ambient temperature, particularly at a sub-optimal growth temperature. The bacterial isolate P. putida KT1401 increased its colony temperature by an energy-spilling reaction when the incubation temperature limited its growth. PMID:23497132

  4. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect

    1998-09-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  5. An engineered method for the repair of coke oven batteries

    SciTech Connect

    Dohle, H.; Ehmke, R.

    1996-12-31

    Improved sales figures in steel making industry and the consequently higher demand for blast furnace coke more recently not only led to a lot of new plant construction projects but also to a vivid growth in repair projects. Sales problems experienced in the past combined with the reluctant attitude to invest in new battery construction projects exerted a negative influence on the age structure of coke plants worldwide. In the US, for example, 58% of the steel companies` coke ovens and 72% of the merchant coke ovens are over 20 years old. The structural status and thus the service life expectancy of a coke oven battery surely do not alone depend on the coke oven battery`s age, but in particular on its total coke production and on the operating and maintenance practice of its operators. More stringent pollution control codes and regulations call for optimum maintenance, particularly for older coke oven plants, considering both technical and economic aspects. The target is to maintain the operability of coke ovens for a lot more years by implementing the best suitable maintenance and repair methods. On condition that appropriate maintenance and repair methods are initiated in time and with care and diligence, the service life of a coke oven battery can be prolonged substantially. A selection of repair and modernization programs developed by TSOA is described and explained.

  6. Mutualistic fungal endophytes produce phytohormones and organic acids that promote japonica rice plant growth under prolonged heat stress*

    PubMed Central

    Waqas, Muhammad; Khan, Abdul Latif; Shahzad, Raheem; Ullah, Ihsan; Khan, Abdur Rahim; Lee, In-Jung

    2015-01-01

    This study identifies the potential role in heat-stress mitigation of phytohormones and other secondary metabolites produced by the endophytic fungus Paecilomyces formosus LWL1 in japonica rice cultivar Dongjin. The japonica rice was grown in controlled chamber conditions with and without P. formosus LWL1 under no stress (NS) and prolonged heat stress (HS) conditions. Endophytic association under NS and HS conditions significantly improved plant growth attributes, such as plant height, fresh weight, dry weight, and chlorophyll content. Furthermore, P. formosus LWL1 protected the rice plants from HS compared with controls, indicated by the lower endogenous level of stress-signaling compounds such as abscisic acid (25.71%) and jasmonic acid (34.57%) and the increase in total protein content (18.76%–33.22%). Such fungal endophytes may be helpful for sustainable crop production under high environmental temperatures. PMID:26642184

  7. DIARRHEA OUTBREAK IN PERNAMBUCO, BRAZIL, ASSOCIATED WITH A HEAT-STABLE CYTOTOXIC ENTEROTOXIN PRODUCED BY Aeromonas caviae

    PubMed Central

    LOPES, Ana Carolina Amaral; MARTINS, Luciano Moura; GATTI, Maria Silvia Viccari; FALAVINA DOS REIS, Cristhiane Moura; HOFER, Ernesto; YANO, Tomomasa

    2015-01-01

    SUMMARY In the present study enterotoxic and cytotoxic activities of twenty Aeromonas caviaestrains were examined. They originated from fecal specimens of patients with acute diarrhea during an outbreak in Brazil in 2004. Culture supernatants of fourteen strains (70%) caused fluid accumulation in rabbit ileal intestinal loops and in suckling mice assays, and also showed a cytotoxic activity in Vero and Caco-2 cells. The enterotoxic and cytotoxic factors were heat-stable after culture supernatants treatment at 100 ºC. The results revealed that A. caviaestrains produce a putative diarrheagenic virulence factor, a heat-stable cytotoxic enterotoxin that could be linked to the diarrhea outbreak that took place in Brazil. PMID:26422161

  8. Isochoric heating of reduced mass targets by ultra-intense laser produced relativistic electrons

    SciTech Connect

    Neumayer, P; Lee, H J; Offerman, D; Shipton, E; Kemp, A; Kritcher, A L; Doppner, T; Back, C A; Glenzer, S H

    2009-02-04

    We present measurements of the chlorine K-alpha emission from reduced mass targets, irradiated with ultra-high intensity laser pulses. Chlorinated plastic targets with diameters down to 50 micrometers and mass of a few 10{sup -8} g were irradiated with up to 7 J of laser energy focused to intensities of several 10{sup 19} W/cm{sup 2}. The conversion of laser energy to K-alpha radiation is measured, as well as high resolution spectra that allow observation of line shifts, indicating isochoric heating of the target up to 18 eV. A zero-dimensional 2-temperature equilibration model, combined with electron impact K-shell ionization and post processed spectra from collisional radiative calculations reproduces the observed K-alpha yields and line shifts, and shows the importance of target expansion due to the hot electron pressure.

  9. Impurity Ions in a Plasma Produced by Electron Cyclotron Resonance Heating

    NASA Astrophysics Data System (ADS)

    Yonesu, Akira; Komori, Akio; Kawai, Yoshinobu

    1988-08-01

    The mechanism of the generation of impurity ions is experimentally evidenced in an electron cyclotron resonance (ECR) plasma produced with a copper Lisitano coil. It is shown that neutral copper particles are sputtered from the Lisitano coil by argon ions and are ionized by the collisions with electrons. The argon ions are accelerated by the ion sheath formed on the Lisitano coil surface, so that the plasma space potential plays an important role in producing the impurities. The impurity flux calculated by using plasma parameters and the sputtering yield of copper is found to be consistent with the observed value. The production of a pure ECR plasma is also attempted with an aluminum Lisitano coil which has a smaller sputtering yield than that of the copper Lisitano coil.

  10. Effect of Filling Type and Heating Method on Prevalence of Listeria species and Listeria monocytogenes in Dumplings Produced in Poland.

    PubMed

    Szymczak, Barbara; Dąbrowski, Waldemar

    2015-05-01

    The count of Listeria monocytogenes was determined, before and after heat treatment, in 200 samples of dumplings of 9 brands and with different types of stuffing. Analyses were conducted according to ISO 11290-1 standard and with real-time PCR method. The highest count of L. monocytogenes was found in meat dumplings (10(2) to 10(4) CFU/g), whereas products with white cheese-potato stuffing and vegetable-mushroom stuffing contained significantly less Listeria, 20 to 80 and 5 to 32 CFU/g, respectively. In cooled meat dumplings the extent of contamination depended significantly on the producer. In addition, a significant (P < 0.05) correlation was determined between contamination level and meat content in the stuffing (rho = 0.418), especially in stuffing containing pork meat (0.464), contrary to beef-containing stuffing (0.284). Heating dumplings in boiling water for 2 min completely eliminated L. monocytogenes in meat dumplings. In contrast, the microwave heating applied for 2 min at 600 W only reduced the count of L. monocytogenes by 1 to 2 logs. Hence, the microwave heating failed to reduce the risk of infection with this pathogen below the level permissible in the EU regulation, especially in the most contaminated samples. In this case, the efficacy of microwave heating was significantly (P < 0.05) affected by the initial count of L. monocytogenes (rho = 0.626), then by meat content in the stuffing (0.476), and to the lowest extent--by the type of meat (0.415 to 0.425). However, no Listeria sp. and L. monocytogenes were isolated from cooked dumplings with fruits (strawberries or blueberries). PMID:25847074

  11. Regeneration performance and carbon consumption of semi-coke and activated coke for SO₂ and NO removal.

    PubMed

    Ding, Song; Li, Yuran; Zhu, Tingyu; Guo, Yangyang

    2015-08-01

    To decrease the operating cost of flue gas purification technologies based on carbon-based materials, the adsorption and regeneration performance of low-price semi-coke and activated coke were compared for SO2 and NO removal in a simulated flue gas. The functional groups of the two adsorbents before and after regeneration were characterized by a Fourier transform infrared (FTIR) spectrometer, and were quantitatively assessed using temperature programmed desorption (TPD) coupled with FTIR and acid-base titration. The results show that semi-coke had higher adsorption capacity (16.2% for SO2 and 38.6% for NO) than activated coke because of its higher content of basic functional groups and lactones. After regeneration, the adsorption performance of semi-coke decreased because the number of active functional groups decreased and the micropores increased. Semi-coke had better regeneration performance than activated coke. Semi-coke had a larger SO2 recovery of 7.2% and smaller carbon consumption of 12% compared to activated coke. The semi-coke carbon-based adsorbent could be regenerated at lower temperatures to depress the carbon consumption, because the SO2 recovery was only reduced a small amount. PMID:26257344

  12. Semi-coke briquettes: towards reducing emissions of primary PM2.5, particulate carbon, and carbon monoxide from household coal combustion in China

    PubMed Central

    Li, Qing; Li, Xinghua; Jiang, Jingkun; Duan, Lei; Ge, Su; Zhang, Qi; Deng, Jianguo; Wang, Shuxiao; Hao, Jiming

    2016-01-01

    Direct household use of unprocessed raw coals for cooking and heating without any air pollution control device has caused serious indoor and outdoor environment problems by emitting particulate matter (PM) and gaseous pollutants. This study examined household emission reduction by switching from unprocessed bituminous and anthracite coals to processed semi-coke briquettes. Two typical stoves were used to test emission characteristics when burning 20 raw coal samples commonly used in residential heating activities and 15 semi-coke briquette samples which were made from bituminous coals by industrial carbonization treatment. The carbonization treatment removes volatile compounds from raw coals which are the major precursors for PM formation and carbon emission. The average emission factors of primary PM2.5, elemental carbon, organic carbon, and carbon monoxide for the tested semi-coke briquettes are much lower than those of the tested raw coals. Based on the current coal consumption data in China, switching to semi-coke briquettes can reduce average emission factors of these species by about 92%, 98%, 91%, and 34%, respectively. Additionally, semi-coke briquette has relatively lower price and higher burnout ratio. The replacement of raw coals with semi-coke briquettes is a feasible path to reduce pollution emissions from household activities. PMID:26782059

  13. Semi-coke briquettes: towards reducing emissions of primary PM2.5, particulate carbon, and carbon monoxide from household coal combustion in China

    NASA Astrophysics Data System (ADS)

    Li, Qing; Li, Xinghua; Jiang, Jingkun; Duan, Lei; Ge, Su; Zhang, Qi; Deng, Jianguo; Wang, Shuxiao; Hao, Jiming

    2016-01-01

    Direct household use of unprocessed raw coals for cooking and heating without any air pollution control device has caused serious indoor and outdoor environment problems by emitting particulate matter (PM) and gaseous pollutants. This study examined household emission reduction by switching from unprocessed bituminous and anthracite coals to processed semi-coke briquettes. Two typical stoves were used to test emission characteristics when burning 20 raw coal samples commonly used in residential heating activities and 15 semi-coke briquette samples which were made from bituminous coals by industrial carbonization treatment. The carbonization treatment removes volatile compounds from raw coals which are the major precursors for PM formation and carbon emission. The average emission factors of primary PM2.5, elemental carbon, organic carbon, and carbon monoxide for the tested semi-coke briquettes are much lower than those of the tested raw coals. Based on the current coal consumption data in China, switching to semi-coke briquettes can reduce average emission factors of these species by about 92%, 98%, 91%, and 34%, respectively. Additionally, semi-coke briquette has relatively lower price and higher burnout ratio. The replacement of raw coals with semi-coke briquettes is a feasible path to reduce pollution emissions from household activities.

  14. A Real-Time Mathematical Model for the Two-Dimensional Temperature Field of Petroleum Coke Calcination in Vertical Shaft Calciner

    NASA Astrophysics Data System (ADS)

    Xiao, Jin; Huang, Jindi; Zhong, Qifan; Li, Fachuang; Zhang, Hongliang; Li, Jie

    2016-02-01

    A real-time mathematical model for the two-dimensional temperature field of petroleum coke calcination in vertical shaft calciner was developed based on computational fluid dynamics. In the modeling process, the petroleum coke discharging process was described by the solid viscous flow, the dynamic heat flux boundary condition was adopted to specify the heat transfer between the flue wall and the gas in the flue, and the Arrhenius equation was used to characterize the pyrolysis process of petroleum coke. The model was validated with both measurement data and data from the literature. The effects of discharge rate per pot, volatile content of green coke, and excess air coefficient on the temperature field of the vertical shaft calciner were investigated with the use of the developed model. The following reasonable operating conditions were obtained: the discharge rate per pot should be less than 90 kg/h, the volatile content of green coke should be in the range of 9-11%, and the excess air coefficient should be in the range of 1.10-1.20. In this work, the governing equations were discretized by using the finite volume method, and the discrete linear equations were solved by using sparse matrix package UMFPACK. The model calculating process takes about less than 15 s. Therefore, the model is beneficial in realizing real-time online temperature detection of petroleum coke calcination in a vertical shaft calciner.

  15. Semi-coke briquettes: towards reducing emissions of primary PM2.5, particulate carbon, and carbon monoxide from household coal combustion in China.

    PubMed

    Li, Qing; Li, Xinghua; Jiang, Jingkun; Duan, Lei; Ge, Su; Zhang, Qi; Deng, Jianguo; Wang, Shuxiao; Hao, Jiming

    2016-01-01

    Direct household use of unprocessed raw coals for cooking and heating without any air pollution control device has caused serious indoor and outdoor environment problems by emitting particulate matter (PM) and gaseous pollutants. This study examined household emission reduction by switching from unprocessed bituminous and anthracite coals to processed semi-coke briquettes. Two typical stoves were used to test emission characteristics when burning 20 raw coal samples commonly used in residential heating activities and 15 semi-coke briquette samples which were made from bituminous coals by industrial carbonization treatment. The carbonization treatment removes volatile compounds from raw coals which are the major precursors for PM formation and carbon emission. The average emission factors of primary PM2.5, elemental carbon, organic carbon, and carbon monoxide for the tested semi-coke briquettes are much lower than those of the tested raw coals. Based on the current coal consumption data in China, switching to semi-coke briquettes can reduce average emission factors of these species by about 92%, 98%, 91%, and 34%, respectively. Additionally, semi-coke briquette has relatively lower price and higher burnout ratio. The replacement of raw coals with semi-coke briquettes is a feasible path to reduce pollution emissions from household activities. PMID:26782059

  16. Feasibility of meltcasing strontium fluoride to produce high-density heat sources

    SciTech Connect

    Wheelwright, E.J.; Montgomery, D.R.

    1985-02-01

    A modest proof-of-principle effort has been conducted to investigate melt casting as a process for compacting SrF/sub 2/ to near theoretical density. A nonradioactive SrF/sub 2/ mixture, similar in chemical composition and method of prepartion to SrF/sub 2/ encapsulated at the Hanford Waste Encapsulation and Storage Facility (WESF) was used for the test evaluations. Hard, dimensionally stable, monolithic ingots that are >98% of theoretical density have been produced. Significant chemical purification from Al, Fe, Cr, Ni, Na and Zr has been demonstrated.

  17. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  18. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  19. Mutagenicity and aromatic amine content of fumes from heated cooking oils produced in Taiwan.

    PubMed

    Chiang, T A; Pei-Fen, W; Ying, L S; Wang, L F; Ko, Y C

    1999-01-01

    According to toxicological studies, there are several unidentified mutagens derived from cooking oil fumes appearing in kitchens of Chinese homes where women daily prepare food. Data are limited to an analysis of aromatic amines from cooking oil fumes, which are known to be carcinogenic for bladder cancer. Fume samples from three different commercial cooking oils frequently used in Taiwan were collected and analysed for mutagenicity in the Salmonella/microsome assay. Aromatic amines were extracted from the samples and identified by HPLC and confirmed by gas chromatography/mass spectrometry (GC/MS). Extracts from three cooking oil fumes were found to be mutagenic in the presence of S-9 mix. All samples contained 2-naphthylamine (2-NA) and 4-aminobiphenyl (4-ABP). Concentrations of 2-NA and 4-ABP were 31.5 and 35.7 microg/m3 in fumes from sunflower oil, 31.9 and 26.4 mg/m3 in vegetable oil, and 48.3 and 23.3 microg/m3 in refined-lard oil, respectively. Mutagenicities of the three cooking oil condensates were significantly reduced (P<0.05) by adding the antioxidant catechin (CAT) into the oils before heating. Significant difference existed between the amounts of aromatic amines with and without adding CAT (P<0.05). These results indicate that exposure to cooking oil fumes in Taiwan might be an important but controllable risk factor in the aetiology of bladder cancer. PMID:10227736

  20. Transient liquid-crystal technique used to produce high-resolution convective heat-transfer-coefficient maps

    NASA Astrophysics Data System (ADS)

    Hippensteele, Steven A.; Poinsatte, Philip E.

    1993-08-01

    In this transient technique the preheated isothermal model wall simulates the classic one-dimensional, semi-infinite wall heat transfer conduction problem. By knowing the temperature of the air flowing through the model, the initial temperature of the model wall, and the surface cooling rate measured at any location with time (using the fast-response liquid-crystal patterns recorded on video tape), the heat transfer coefficient can be calculated for the color isothermal pattern produced. Although the test was run transiently, the heat transfer coefficients are for the steady-state case. The upstream thermal boundary condition was considered to be isothermal. This transient liquid-crystal heat-transfer technique was used in a transient air tunnel in which a square-inlet, 3-to-1 exit transition duct was placed. The duct was preheated prior to allowing room temperature air to be suddenly drawn through it. The resulting isothermal contours on the duct surfaces were revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record was made of the temperature and time data for all points on the duct surfaces during each test. The duct surfaces were uniformly heated using two heating systems: the first was an automatic temperature-controlled heater blanket completely surrounding the test duct like an oven, and the second was an internal hot-air loop through the inside of the test duct. The hot-air loop path was confined inside the test duct by insulated heat dams located at the inlet and exit ends of the test duct. A recirculating fan moved hot air into the duct inlet, through the duct, out of the duct exit, through the oven, and back to the duct inlet. The temperature nonuniformity of the test duct model wall was held very small. Test results are reported for two inlet Reynolds numbers of 200,000 and 1,150,000 (based on the square-inlet hydraulic diameter) and two free-stream turbulence

  1. Transient liquid-crystal technique used to produce high-resolution convective heat-transfer-coefficient maps

    NASA Technical Reports Server (NTRS)

    Hippensteele, Steven A.; Poinsatte, Philip E.

    1993-01-01

    In this transient technique the preheated isothermal model wall simulates the classic one-dimensional, semi-infinite wall heat transfer conduction problem. By knowing the temperature of the air flowing through the model, the initial temperature of the model wall, and the surface cooling rate measured at any location with time (using the fast-response liquid-crystal patterns recorded on video tape), the heat transfer coefficient can be calculated for the color isothermal pattern produced. Although the test was run transiently, the heat transfer coefficients are for the steady-state case. The upstream thermal boundary condition was considered to be isothermal. This transient liquid-crystal heat-transfer technique was used in a transient air tunnel in which a square-inlet, 3-to-1 exit transition duct was placed. The duct was preheated prior to allowing room temperature air to be suddenly drawn through it. The resulting isothermal contours on the duct surfaces were revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record was made of the temperature and time data for all points on the duct surfaces during each test. The duct surfaces were uniformly heated using two heating systems: the first was an automatic temperature-controlled heater blanket completely surrounding the test duct like an oven, and the second was an internal hot-air loop through the inside of the test duct. The hot-air loop path was confined inside the test duct by insulated heat dams located at the inlet and exit ends of the test duct. A recirculating fan moved hot air into the duct inlet, through the duct, out of the duct exit, through the oven, and back to the duct inlet. The temperature nonuniformity of the test duct model wall was held very small. Test results are reported for two inlet Reynolds numbers of 200,000 and 1,150,000 (based on the square-inlet hydraulic diameter) and two free-stream turbulence

  2. Coking rates in a laboratory pyrolysis furnace: Liquid petroleum feedstocks

    SciTech Connect

    Leftin, H.P.; Newsome, D.S.

    1987-05-01

    Integral rates of coking for 14 feedstocks (light naphtha to vacuum gas oil) and mixtures of these were determined in a laboratory pyrolysis furnace between 815 and 943/sup 0/C and between 70 and 340 ms. These can be ranked as severe coking (S.C) and low coking (L.C.) feedstocks and are characterized by production of filamentous and amorphous (encapsulating) coke, respectively. Admixture of a L.C. feedstock in greater than a critical minimum amount of a S.C. feedstock imparts a natural inhibition on the coking rate of the S.C. feedstock, so that the coking rate of the mixture mimics that of the L.C. component.

  3. Laser Ultrasonic Furnace Tube Coke Monitor

    SciTech Connect

    1999-02-15

    This reports summarizes the technical progress achieved during the third quarter of the ERIP project entitled, ''Laser Ultrasonic Furnace Tube Coke Monitor.'' The focus of work during this reporting period was the construction of an automated probe that will be used to measure the thickness of coke deposits in thermal cracking furnaces. A discovery was made during the last reporting period, which indicated that a conventional NDE broadband transducer could be used in conjunction with a sacrificial standoff composed of a fusible alloy to efficiently couple the transducer to a rough surface operating at high temperature. A probe was constructed that incorporates the recent discovery and initial testing of the probe is now underway. Because of other project commitments, the manpower available to allocate to the coke detector project was limited during the most recent quarter. As a result, the project is somewhat behind the original schedule. However, project expenditures are consistent with the project progress to date. The total program budget is $98,670 and the current project expenditures are approximately $24,000. The original contract budget period ends on April 30, 1999. We intend to request a six-month no-cost extension to the contract so that we may complete the project objectives.

  4. Microbiology of coke-plant activated sludge

    SciTech Connect

    Owens, J.R.

    1983-01-01

    The biological treatment of coke-plant wastewater represents the most economical means of detoxification and contaminant removal, but little is known about the microbial ecology of this system. Research was therefore undertaken to determine the kinds of microorganisms that survive and function in this environment and to examine the growth patterns that influence treatment efficiency. The microbial flora of coke-plant activated sludge is predominated by populations of aerobic gram negative rods. The principle genera identified were Pseudomonas, Alcaligenes, Flavobacterium and Acinetobacter. The genera Bacillus, Nocardia and Micrococcus were also present at low levels. A single type of rotifer was present along with various protozoans. The ability of microorganisms in coke wastewater to grow on various organic compounds as their sole source of carbon and energy is more restrictive when compared with that of isolates obtained from activated sludge processes treating municipal wastes. The phenol degrading bacteria can be maintained in a continuous culture system with a hydraulic retention time (HRT) of as long as 14 days. Under conditions of increasing HRT the average cell size decreased and the number of cells per milliter increased. As the HRT increased cell yields decreased. At long HRT's (7 to 14 days) cell yields remained constant.

  5. Toxicological assessment of green petroleum coke.

    PubMed

    McKee, Richard H; Herron, Deborah; Beatty, Patrick; Podhasky, Paula; Hoffman, Gary M; Swigert, James; Lee, Carol; Wong, Diana

    2014-01-01

    Green petroleum coke is primarily inorganic carbon with some entrained volatile hydrocarbon material. As part of the petroleum industry response to the high production volume challenge program, the potential for reproductive effects was assessed in a subchronic toxicity/reproductive toxicity screening test in rats (OECD 421). The repeated-dose portion of the study provided evidence for dust accumulation and inflammatory responses in rats exposed to 100 and 300 mg/m(3) but there were no effects at 30 mg/m(3). In the reproductive toxicity screen, the frequency of successful matings was reduced in the high exposure group (300 mg/m(3)) and was not significantly different from control values but was outside the historical experience of the laboratory. The postnatal observations (external macroscopic examination, body weight, and survival) did not indicate any treatment-related differences. Additional tests conducted to assess the potential hazards to aquatic (fish, invertebrates, and algae) and soil dwelling organisms (earthworms and vascular plants) showed few effects at the maximum loading rates of 1000 mg coke/L in aquatic studies and 1000 mg coke/kg soil in terrestrial studies. The only statistically significant finding was an inhibition of algal growth measured as either biomass or growth rate. PMID:24179031

  6. Inhibition of Cronobacter sakazakii by heat labile bacteriocins produced by probiotic LAB isolated from healthy infants.

    PubMed

    Awaisheh, Saddam S; Al-Nabulsi, Anas A; Osaili, Tareq M; Ibrahim, Salam; Holley, Richard

    2013-09-01

    Cronobacter sakazakii is an opportunistic pathogen that can cause bacteremia, meningitis, and necrotizing enterocolitis, most often in neonates with case-fatality rates that may reach 80%. The antimicrobial activity of lactic acid bacteria against a wide range of foodborne pathogens is well-established in different types of food products. The objective of the current study was to investigate the antibacterial activity of Lactobacillus acidophilus and L. casei isolated from feces of healthy infants against different strains of C. sakazakii in agar and a rehydrated infant milk formula (RIMF) model. The inhibition zones of C. sakazakii around L. acidophilus or L. casei ranged from 22 to 32 mm on eMan Rogosa Sharpe (MRS) agar under aerobic conditions, while a slight reduction in antibacterial activity was noted on modified MRS (0.2% glucose) under anaerobic conditions. It was observed that pH-neutralized cell-free supernatant (CFS) of L. acidophilus or L. casei was inhibitory against tested C. sakazakii strains. The inhibition zones of neutralized CFS were lower than the antibacterial activities of live cultures. The antibacterial activity of CFS was abolished when CFS from L. acidophilus or L. casei was heated at 60 or 80 °C for either 10 min or 2 h, or treated with trypsin or pepsin. This was considered strong evidence that the inhibition was due to the production of bacteriocins by L. casei and L. acidophilus. Both the CFS and active growing cells of L. casei and L. acidophilus were able to reduce the viability of C. sakazakii in the RIMF model. The results may extend the use of natural antimicrobials instead of conventional preservation methods to improve the safety of RIMF. PMID:23924352

  7. Glycoprotein receptors for a heat-stable enterotoxin (STh) produced by enterotoxigenic Escherichia coli.

    PubMed Central

    Hirayama, T; Wada, A; Iwata, N; Takasaki, S; Shimonishi, Y; Takeda, Y

    1992-01-01

    Glycoprotein receptors for heat-stable enterotoxin STh of enterotoxigenic Escherichia coli in the rat intestinal cell membrane were identified and characterized. Incubation of rat intestinal cell membranes with radioiodinated N-5-azidonitrobenzoyl-STh[5-19] (125I-ANB-STh[5-19]) followed by photolysis resulted in specific radiolabeling of two distinct proteins with M(r)s of 200,000 (designated STR-200A and STR-200B). STR-200A was found to be composed of two molecules of a protein with an M(r) of 70,000 (70-kDa protein), whereas STR-200B was composed of two different protein molecules with M(r)s of 53,000 (53-kDa protein) and 77,000 (77-kDa protein). These proteins showed no guanylate cyclase activity. The 70-kDa protein was labeled most with 125I-ANB-STh[5-19], suggesting that STR-200A is the main receptor protein in the rat intestinal cell membrane. The carbohydrate moieties of STR-200A and STR-200B were examined by enzymatic deglycosylation. The 70-kDa protein of STR-200A was found to contain N-linked high-mannose-type and/or hybrid-type oligosaccharides, and results suggested that it possesses at least three N glycosylation sites. The 53-kDa protein of STR-200B was found to have an N-linked complex-type oligosaccharide side chain. The deglycosylated 70-kDa protein retained activity for binding to STh, suggesting that the carbohydrate moieties of these receptor proteins are not important for binding with STh. Images PMID:1328055

  8. Method for producing a secondary lithium cell comprising a heat-sensitive protective mechanism

    SciTech Connect

    Ullrich, Matthias; Bechtold, Dieter; Rabenstein, Heinrich; Brohm, Thomas

    2003-01-01

    A method for producing a secondary lithium cell which has at least one lithium-cycling negative electrode, at least one lithium-intercalating positive electrode, at least one separator disposed between the positive and the negative electrode, and a nonaqueous lithium ion-conducting electrolyte. The method is carried out by the electrodes and/or the separator being coated, by means of electrostatic powder coating, with wax particles which are insoluble in the electrolyte and have a melting temperature of from about 50 to about 150 .degree. C. and a mean particle size of from about 6 to about 20 .mu.m, the amount of wax being between about 0.5 and about 2.5 mg/cm.sup.2 of electrode area.

  9. Non-Spitzer heat flow in a steadily ablating laser-produced plasma

    SciTech Connect

    Bell, A.R.

    1985-06-01

    Electron energy transport in a laser-produced ablating plasma is modeled by the Vlasov--Fokker--Planck equation for electrons and the fluid equations for cold ions. These equations are solved using approximations which maintain good accuracy but allow faster computational solution than was previously possible. It is found that the spatial profiles for temperature and density in planar geometry differ very little from those calculated from the Spitzer conductivity. At high laser intensities, the plasma flow diverges as it flows away from the solid target and the effects of nonplanar flow are important. This is modeled by the adoption of spherical geometry, and it is found that the Spitzer conductivity breaks down and the temperature and density profiles differ significantly from those calculated using the Spitzer conductivity.

  10. "Decoking" of a "coked" zeolite catalyst in a glow discharge.

    PubMed

    Khan, M A; Al-Jalal, A A; Bakhtiari, I A

    2003-09-01

    "Decoking" of a "coked" zeolite catalyst in a glow discharge in oxygen is investigated. The "decoking" process involves reactions of atomic oxygen (O atoms) with "coke" and yields gases such as CO, CO(2) as well as other gaseous products that could be easily pumped out. Three different modes of discharge were investigated including a static mode, a flowing-gas mode, and a periodic-purge mode where the oxygen and other gaseous products of the discharge were replaced by fresh O(2)gas after short but regular intervals of time. In some cases, additional heating was also used to provide base temperatures of the order of 100 degrees C to facilitate penetration of oxygen atoms into the inner layers and cages of the zeolite catalyst. This paper presents some results of spectroscopic analytical techniques used to monitor the atomization of oxygen, oxidation of "coke", and to confirm the process of "decoking". More specifically, radiation emission on the 3 s (5)S- 3p (5)P transitions of O around 777.2-777.5 nm were selected for monitoring the atomization of O(2). On the other hand, X-ray photo-electron spectroscopy (XPS) was used to determine the amount of residual carbon and extent of "decoking". Furthermore, evolution of CO and CO(2) gases as a function of time was systematically monitored in real time. For CO, the 451.1 nm band head belonging to the B(1) Sigma - A(1) Pi bands of the Angstrom system of the CO spectrum was used, while for CO(2), the band head at 353.4 nm belonging to the CO(2)(+) spectrum was used. The rates of evolution of CO and CO(2) were related to the rate of "decoking" of the catalyst. It is noted that in the periodic-purge mode, about 63% of the total yield of CO from a given sample of the catalyst appears in the first 3-min exposure to discharge whereas it takes up to 15 min to remove nearly 94% of the removable carbon under our experimental conditions. PMID:12861433

  11. The effects of petroleum coke properties on carbon anode quality

    SciTech Connect

    Belitskus, D. ); Danka, D.J. )

    1988-11-01

    Comprehensive bench-scale testing of the effects of calcined coke on the properties of prebaked anodes for aluminum smelting cells has revealed correlations between coke and anode properties. Extensive measurements of the physical properties of coke as well as impurities, determinations of performance-indicative anode properties, and correlation by regression analyses provided statistically significant relationships which can generally be explained in terms of reasonable chemical and physical interactions.

  12. AERIAL OVERVIEW, LOOKING WEST, WITH BEE HIVE COKE OVENS IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    AERIAL OVERVIEW, LOOKING WEST, WITH BEE HIVE COKE OVENS IN FORESTED OVERGROWTH (BOTTOM LEFT), COKE TAILINGS PILE (BOTTOM RIGHT THROUGH CENTER TOP LEFT), FORMER BIRMINGHAM SOUTHERN RAILWAY SHOPS BUILDING (TOP RIGHT). CONVICT CEMETERY IS JUST WEST OF THE TAILINGS PILE (TOP LEFT IN THIS PHOTOGRAPH). - Pratt Coal & Coke Company, Pratt Mines, Convict Cemetery, Bounded by First Street, Avenue G, Third Place & Birmingham Southern Railroad, Birmingham, Jefferson County, AL

  13. Method for characterizing the coking tendencies of baseoils and additive-treated oils

    SciTech Connect

    Dickakian, G.B.

    1989-07-18

    This patent describes a method of characterizing the coking tendency of baseoil. The method consists the steps of: (a) subjecting the baseoil to conditions which accelerate asphaltene coke precursor formation in the baseoil, and (b) characterizing the coking tendency of the baseoil by determining (i) the onset and progression of asphaltene coke precursor formation as a function of time or (ii) the progression of asphaltene coke precursor formation as a function of time, wherein a faster onset of asphaltene coke precursor formation and a higher rate of asphaltene coke precursor formation or a higher rate of asphaltene coke precursor formation indicates a higher coking tendency of the baseoil than a slower onset of asphaltene coke precursor formation and a lower rate of asphaltene coke precursor formation or a lower rate of asphaltene coke precursor formation.

  14. 76 FR 77020 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Coke Oven...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-09

    ... Information Collection Activities; Submission for OMB Review; Comment Request; Coke Oven Emissions ACTION... Administration (OSHA) sponsored information collection request (ICR) titled, ``Coke Oven Emissions,'' to the...: The purpose of Coke Oven Emissions Standard and its information collection requirements, codified...

  15. Machinability of Austempered Ductile Iron (ADI) Produced by Integrated Green Technology of Continuous Casting-Heat Treatment Processes

    SciTech Connect

    Meena, A.; El Mansori, M.; Ghidossi, P.

    2011-01-17

    This study presents the novel processing technique known as continuous casting-heat treatment processes to produce Austempered Ductile Iron (ADI) which is a new class of ductile iron. ADI is characterized by improved mechanical properties but has low machinability as compared to other cast irons and steel of similar strength. The novel technique is developed by the integration of casting (in die casting) and heat treatment processes in foundry to save cost energy and time. Specimens just after casting were austenitized at 930 deg. C for 90 min and then austempered in fluidized bed at 380 deg. C for 90 and 120 min. Hence, the effect of austempering time on the morphology of retained austenite and mechanical properties of the material were examined and compared with conventionally produced ADI. Drilling tests were then carried out to evaluate the machinability of ADI in terms of cutting forces, chip micro-hardness, chip morphology and surface roughness. The mechanical properties of ADI austempered for 120 min have found to be better as compare to the ADI austempered for 90 min.

  16. Machinability of Austempered Ductile Iron (ADI) Produced by Integrated Green Technology of Continuous Casting-Heat Treatment Processes

    NASA Astrophysics Data System (ADS)

    Meena, A.; El Mansori, M.; Ghidossi, P.

    2011-01-01

    This study presents the novel processing technique known as continuous casting-heat treatment processes to produce Austempered Ductile Iron (ADI) which is a new class of ductile iron. ADI is characterized by improved mechanical properties but has low machinability as compared to other cast irons and steel of similar strength. The novel technique is developed by the integration of casting (in die casting) and heat treatment processes in foundry to save cost energy and time. Specimens just after casting were austenitized at 930° C for 90 min and then austempered in fluidized bed at 380° C for 90 and 120 min. Hence, the effect of austempering time on the morphology of retained austenite and mechanical properties of the material were examined and compared with conventionally produced ADI. Drilling tests were then carried out to evaluate the machinability of ADI in terms of cutting forces, chip micro-hardness, chip morphology and surface roughness. The mechanical properties of ADI austempered for 120 min have found to be better as compare to the ADI austempered for 90 min.

  17. Methods of steam coals usage for coke production

    SciTech Connect

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.

    1998-04-01

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40 % by weight. There are some coal deposits in Kuznetskii basin which have big resources of the coals with low caking tendency. The low caking properties of such coals limit of its application in coking process. At the same time the usage of low caking coals for the coke production would allow to broad up the feedstock for coke production. Preliminary tests, carried out in COAL-C`s lab shown some differences in coal properties in dependence on the size distribution. That is why the separation of well caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way of low caking coals application in coke industry is briquettes production from such coals. This method is been known for a very loner time acro. It may be divided into two possible directions of briquettes using. First is a direct coking of briquettes from the low caking coals. Another way is briquettes adding to coal blend in defined proportion and its combined coking. The possibility of application of coal benefication methods mentioned above was investigated in present work.

  18. The methods of steam coals usage for coke production

    SciTech Connect

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  19. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect

    Galbreath, K.C.

    1998-07-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  20. Visualization of coke state in hydraulic decoking process

    NASA Astrophysics Data System (ADS)

    Guo, Qian; Tong, Xinglin; Deng, Chengwei; Zhang, Cui; Huang, Di; Chen, Liang; Xiong, Jiaguo

    2016-05-01

    The relationship model of the sound signal and the coke state can be established through multiple test and comparison of the noise signal and the coke operation. By collecting data, we summarize the main frequency power fluctuation range of the sound signal in kinds of state, and extract the nearest 5 decision results for reference. The weighted value of each result according to the update time has gradually increased. On the basis of that, we developed visualization software, real-time reflect out coke coking tower state. Animation refresh rate is second level, and the vertical height can be accurate to 0.1m.

  1. Competitive reactions of organophosphorus radicals on coke surfaces.

    PubMed

    Catak, Saron; Hemelsoet, Karen; Hermosilla, Laura; Waroquier, Michel; Van Speybroeck, Veronique

    2011-10-17

    The efficacy of organophosphorus radicals as anticoking agents was subjected to a computational study in which a representative set of radicals derived from industrially relevant organophosphorus additives was used to explore competitive reaction pathways on the graphene-like coke surface formed during thermal cracking. The aim was to investigate the nature of the competing reactions of different organophosphorus radicals on coke surfaces, and elucidate their mode of attack and inhibiting effect on the forming coke layer by use of contemporary computational methods. Density functional calculations on benzene and a larger polyaromatic hydrocarbon, namely, ovalene, showed that organophosphorus radicals have a high propensity to add to the periphery of the coke surface, inhibiting methyl radical induced hydrogen abstraction, which is known to be a key step in coke growth. Low addition barriers reported for a phosphatidyl radical suggest competitive aptitude against coke formation. Moreover, organophosphorus additives bearing aromatic substituents, which were shown to interact with the coke surface through dispersive π-π stacking interactions, are suggested to play a nontrivial role in hindering further stacking among coke surfaces. This may be the underlying rationale behind experimental observation of softer coke in the presence of organophosphorus radicals. The ultimate goal is to provide information that will be useful in building single-event microkinetic models. This study presents pertinent information on potential reactions that could be taken up in these models. PMID:21956815

  2. A heat treatment procedure to produce fine-grained lamellar microstructures in a P/M titanium aluminide alloy

    NASA Astrophysics Data System (ADS)

    Au, Peter

    A process for fabricating advanced aerospace titanium aluminide alloys starting from metal powders (the hot isostatically consolidated P/M process) is presented in this thesis. This process does not suffer the difficulties of chemical inhomogeneities and coarse grain structure of castings. In addition heat treatments which take advantage of the refined structure of HIP processed materials are developed to achieve microstructure control and subsequent mechanical property control. It is shown that a better "property balance" is possible after the heat treatment of HIP consolidated materials than it is with alternative processing. It is well understood that the standard microstructures (near-gamma, duplex, nearly lamellar, and fully lamellar) do not have the balanced mechanical properties (tensile, yield, creep and fatigue strength, ductility and fracture toughness) necessary for optimal performance in aero engine and automotive applications. In this work a fine-grained fully lamellar (FGFL) microstructure is developed for property control and in particular for achieving a much improved property balance. A heat treatment procedure for this purpose which consists of cyclic processing in the alpha transus temperature region to achieve an FGFL structure with grain sizes in the range of 50 mum to 150 mum is presented. Compared with conventional duplex structured materials, the minimum creep rate is an order of magnitude lower with only a 10% loss in tensile yield strength. Moreover, a three-fold increase in tensile elongation is possible by converting to an FGFL structure with only a 30% loss in minimum creep rate. These are attractive trade-offs when considering the use of these alloys for aerospace purposes. A thorough literature review of the mechanisms of formation of standard microstructures and their deformation under mechanical loading is contained in the thesis. In addition, conventional techniques to produce FGFL microstructures in wrought and cast materials are

  3. Distributed control system at National Steel's Great Lakes Div. rehabilitated coke battery

    SciTech Connect

    Oliphant, M.A.; Gambert, G. . Great Lakes Division)

    1994-10-01

    The Great Lakes' No. 5 coke-oven battery and by-products plant was recently rehabilitated and substantially modified. The battery consists of 85 ovens with a design coke production level of 890,000 tons/year. It includes a complex heating system, reversing system, quench station, emissions controls and oven machinery to control the charging and pushing of the ovens. The by-products plant handles 48 million cu ft of gas per day, utilizing two primary gas coolers, two exhausters, two electrostatic tar precipitators, secondary gas cooler, ammonia scrubbers, stills and destruction plant, waste heat boilers, boiler water treatment plant, gas blanketing system, gas boosters, water cooling tower, wet surface air cooler and a phenol extraction plant located a quarter mile away. A completely integrated distributed control system has greatly facilitated the operation of a complicated process such as the rehabilitated coke-oven battery and by-products plant. Manpower requirements are reduced, with more information being generated automatically. Operators spend much less time walking the plant and considerably more time monitoring the process. Training of operating and maintenance people was time consuming but once completed, the operation became much easier and less costly to control.

  4. Characteristics of Catalytic Gasification of Natural Coke with H2O in a Fluidized Bed

    NASA Astrophysics Data System (ADS)

    Lin, L. S.; Zhao, C. S.; Wang, S.; Zhu, G.; Xiang, W. G.

    The experimental investigation on gasification characteristics of natural coke from Peicheng, Jiangsu with steam were conducted in a fluidized bed gasifier setup. The effects of several parameters, in terms of the catalyst type, the catalyst mixed manner and the dosage of catalyst over coke on the yield, the components, the heating value of fuel gas and the carbon conversion rate were examined. Results indicate that the fluidized bed gasification technology could overcome the shortcomings of natural coke. Ca-, Fe- and Cu-based nitrates could improve the gasification reaction effectively with a little difference, they could be listed in a descending sequence as follows: Cu-based>Fe-based>Ca-based according to their catalytic effect. The influences of Fe/Ca ratio and Cu/Ca ratio on gasification are similar, gas yield, carbon conversion rate and gas heating value per hour increase as Fe/Ca ratio or Cu/Ca ratio increases, but all of them go up first and then drop with decrease in Fe/Cu ratio. When the dosage of Ca-, Fe- and Cu-based nitrates mixed with the ratio of Ca/Fe/Cu= 10/35/55 is 3%, the best catalytic effect is achieved.

  5. Sprites produced by quasi-electrostatic heating and ionization in the lower ionosphere

    NASA Astrophysics Data System (ADS)

    Pasko, V. P.; Inan, U. S.; Bell, T. F.; Taranenko, Y. N.

    1997-03-01

    Quasi-electrostatic (QE) fields that temporarily exist at high altitudes following the sudden removal (e.g., by a lightning discharge) of thundercloud charge at low altitudes lead to ambient electron heating (up to ~5eV average energy), ionization of neutrals, and excitation of optical emissions in the mesosphere/lower ionosphere. Model calculations predict the possibility of significant (several orders of magnitude) modification of the lower ionospheric conductivity in the form of depletions of electron density due to dissociative attachment to O2 molecules and/or in the form of enhancements of electron density due to breakdown ionization. Results indicate that the optical emission intensities of the 1st positive band of N2 corresponding to fast (~1ms) removal of 100-300 C of thundercloud charge from 10 km altitude are in good agreement with observations of the upper part (``head'' and ``hair'' [Sentman et al., 1995]) of the sprites. The typical region of brightest optical emission has horizontal and vertical dimensions ~10km, centered at altitudes 70 km and is interpreted as the head of the sprite. The model also shows the formation of low intensity glow (``hair'') above this region due to the excitation of optical emissions at altitudes ~85km during ~500μs at the initial stage of the lightning discharge. Comparison of the optical emission intensities of the 1st and 2nd positive bands of N2, Meinel and 1st negative bands of N2+, and 1st negative band of O2+ demonstrates that the 1st positive band of N2 is the dominating optical emission in the altitude range around ~70km, which accounts for the observed red color of sprites, in excellent agreement with recent spectroscopic observations of sprites. Results indicate that the optical emission levels are predominantly defined by the lightning discharge duration and the conductivity properties of the atmosphere/lower ionosphere (i.e., relaxation time of electric field in the conducting medium). The model demonstrates

  6. Characterization of Cu{sub 6}Sn{sub 5} intermetallic powders produced by water atomization and powder heat treatment

    SciTech Connect

    Tongsri, Ruangdaj; Yotkaew, Thanyaporn; Krataitong, Rungtip; Wila, Pongsak; Sir-on, Autcharaporn; Muthitamongkol, Pennapa; Tosangthum, Nattaya

    2013-12-15

    Since the Cu{sub 6}Sn{sub 5} intermetallic shows its importance in industrial applications, the Cu{sub 6}Sn{sub 5} intermetallic-containing powders, produced by a powder processing route with a high production rate, were characterized. The route consisted of water atomization of an alloy melt (Cu–61 wt.% Sn) and subsequent heat treatment of the water-atomized powders. Characterization of the water-atomized powders and their heated forms was conducted by using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Fine water-atomized powder microstructures consisted of primary hexagonal η-Cu{sub 6.25}Sn{sub 5} dendrites coexisting with interdendritic η-Cu{sub 6.25}Sn{sub 5} + β-Sn eutectic. Solidification of fine melt droplets was governed by surface nucleation and growth of the primary hexagonal η-Cu{sub 6.25}Sn{sub 5} dendrites followed by η-Cu{sub 6.25}Sn{sub 5} + β-Sn eutectic solidification of the remnant liquid. In coarse melt droplets, nucleation and growth of primary ε-Cu{sub 3}Sn dendrites were followed by peritectic reaction (ε-Cu{sub 3}Sn + liquid → η-Cu{sub 6.25}Sn{sub 5}) or direct crystallization of η-Cu{sub 6.25}Sn{sub 5} phase from the undercooled melt. Finally, the η-Cu{sub 6.25}Sn{sub 5} + β-Sn eutectic solidification of the remnant liquid occurred. Heating of the water-atomized powders at different temperatures resulted in microstructural homogenization. The water-atomized powders with mixed phases were transformed to powders with single monoclinic ή-Cu{sub 6}Sn{sub 5} phase. - Highlights: • The Cu{sub 6}Sn{sub 5} intermetallic powder production route was proposed. • Single phase Cu{sub 6}Sn{sub 5} powders could be by water atomization and heating. • Water-atomized Cu–Sn powders contained mixed Cu–Sn phases. • Solidification and heat treatment of water-atomized Cu–Sn powders are explained.

  7. Tried and True: Using Diet Coke and Mentos to Teach Scientific Inquiry

    ERIC Educational Resources Information Center

    Murray, Tracey Arnold

    2011-01-01

    Adding mint Mentos candy to a two-liter bottle of Diet Coke produces a fountain of soda foam that can reach 3 m high. A demonstration such as this can get a "Wow" out of most audiences, usually followed by a "Do it again!"--but can it be used to teach anything? The answer is a definite "Yes," and what follows is a guided inquiry activity that…

  8. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect

    T.F. Trembach; A.G. Klimenko

    2009-07-15

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  9. Core-shell biopolymer nanoparticles produced by electrostatic deposition of beet pectin onto heat-denatured beta-lactoglobulin aggregates.

    PubMed

    Santipanichwong, R; Suphantharika, M; Weiss, J; McClements, D J

    2008-08-01

    The purpose of this study was to produce and characterize core-shell biopolymer particles based on electrostatic deposition of an anionic polysaccharide (beet pectin) onto amphoteric protein aggregates (heat-denatured beta-lactoglobulin [beta-lg]). Initially, the optimum conditions for forming stable protein particles were established by thermal treatment (80 degrees C for 15 min) of 0.5 wt% beta-lg solutions at different pH values (3 to 7). After heating, stable submicron-sized (d=100 to 300 nm) protein aggregates could be formed in the pH range from 5.6 to 6. Core-shell biopolymer particles were formed by mixing a suspension of protein aggregates (formed by heating at pH 5.8) with a beet pectin solution at pH 7 and then adjusting the pH to values where the beet pectin is adsorbed (< pH 6). The impact of pH (3 to 7) and salt concentration (0 to 250 mM NaCl) on the properties of the core-shell biopolymer particles formed was then established. The biopolymer particles were stable to aggregation from pH 4 to 6, but aggregated at lower pH values because they had a relatively small -potential. The biopolymer particles remained intact and stable to aggregation up to 250 mM NaCl at pH 4, indicating that they had good salt stability. The core-shell biopolymer particles prepared in this study may be useful for encapsulation and delivery of bioactive food components or as substitutes for lipid droplets. PMID:19241582

  10. Combustion of petroleum coke dust as a partial substitute for natural gas and oil in the alumina trihydrate calcination process

    SciTech Connect

    Desgroseillers, B.; Perron, J.; Laurin, P.; Menard, O.; Martin, J.

    1996-10-01

    In the Saguenay region, Alcan operates two coke calcination rotary kilns to supply with calcined coke its prebaked anode and Soderberg paste smelters. The annual production is approximately 220,000 t of calcined coke. For the last few years, the unwanted emissions of under calcined coke dust (UCCD) emitted from the kilns along with the hot gas reaches approximately 16,000 t per year. A maximum of 6,000 t of UCCD are recycled in fabrication processes. In the search of new possibilities to recycle and sell the remaining 10,000 t the possibility of using this UCCD as a heating source ion other processes has emerged, particularly for the calcination of alumina trihydrate. A feasibility study on the combustion as well as a plant trial showed the benefits of burning this UCCD in two 60 t/h capacity calcination units. In fact, appreciable savings in natural gas or oil, as well as increased energetic efficiency (gain of 6%) were observed in the calcination units. Furthermore, the impact on quality of the metallurgical alumina is negligible. These results can be explained partly by the use of a solid combustible which presents longer combustion time compared to natural gas. The combustion zones are therefore extended, favoring the heat transfer to the solid during calcination.

  11. Multifunctional resistive-heating and color-changing monofilaments produced by a single-step coaxial melt-spinning process.

    PubMed

    Laforgue, Alexis; Rouget, Geoffroy; Dubost, Sylvain; Champagne, Michel F; Robitaille, Lucie

    2012-06-27

    Multifunctional coaxial monofilaments were successfully produced by melt-spinning several polymer composites in a single-step. The external layer of the monofilaments was a thermochromic composite having a color-transition at 40 °C (above the ambient temperature) in order to avoid control interferences by the external temperature. The core layer of the monofilaments was a conductive polymer nanocomposite whose resistive heating properties were used to control the monofilament's temperature and therefore its color using electrical current. The careful selection of the materials and adequate formulation allowed to obtain a trilayer structure with enhanced compatibility between the layers. The mechanical properties of the monofilaments were improved by a solid-state stretching step while also decreasing their diameter. A 64 cm(2) prototype fabric was woven to characterize the resistive-heating and color-changing properties of the monofilaments. Exceptional thermal output levels were reached, with a temperature rising up to over 100 °C at voltages above 110 V. The reversible color change properties were also successfully demonstrated. PMID:22650496

  12. Numerical modeling of radiation physics in kinetic plasmas [IV] - Isochoric heating by intense X-ray laser-produced photoelectrons

    NASA Astrophysics Data System (ADS)

    Royle, Ryan; Sentoku, Yasuhiko

    2014-10-01

    An intense, hard X-ray laser such as an XFEL is an attractive light source since it can directly heat solid matter isochorically to a temperature of millions of degrees on a time scale of a few tens of femtoseconds, which is much shorter than the plasma expansion time scale. The X-ray laser interaction with carbon, aluminum, silicon, and copper is studied with a particle-in-cell code that solves the photoionization and X-ray transport self-consistently. Photoionization is the dominant absorption mechanism and non-thermal photoelectrons are produced with energy near the X-ray photon energy. The photoelectrons' stopping range is a few microns and they are quickly thermalized in tens of femtoseconds. As a result, a hot plasma column is formed behind the laser pulse with a temperature of more than 100,000 kelvin (>10 eV) and energy density greater than 1011 J/m3. The heating depth and temperature depend on the material and are also controllable by changing the photon energy of the incident laser light.

  13. 29 CFR 1910.1029 - Coke oven emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 6 2012-07-01 2012-07-01 false Coke oven emissions. 1910.1029 Section 1910.1029 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR (CONTINUED) OCCUPATIONAL SAFETY AND HEALTH STANDARDS (CONTINUED) Toxic and Hazardous Substances § 1910.1029 Coke oven emissions. (a) Scope...

  14. "Fishing" of heteropolyacids into carbonaceous seine via coking.

    PubMed

    Sushkevich, Vitaly L; Ivanova, Irina I; Lancelot, Christine; Moldovan, Simona; Ersen, Ovidiu; Ordomsky, Vitaly V

    2015-12-14

    The carbon encapsulated tungstophosphoric acid was synthesized by the controlled coking during gas phase reaction of formaldehyde with isobutene. The as-made material showed unique stability toward leaching in the aqueous phase due to localization of HPA clusters inside the porous coke matrix with high activity in the esterification reaction. PMID:26451706

  15. Clairton B battery: new technology in coke production

    SciTech Connect

    DiCola, R.F.; McCollum, H.R.

    1983-08-01

    A new 800,000 ton/year, 75-oven coke battery has been constructed at US Steels' Clairton plant. The 6 m ovens have a computerized feed-forward underfiring control system, a unique coke pushing sequence and a fully-automated single-position catch car, as well as optical targets for positioning the charging car and pushing and door machines.

  16. SAMPLING AND ANALYSIS OF COKE-OVEN DOOR EMISSIONS

    EPA Science Inventory

    The report gives results of extensive tests of selected fractions of samples of emissions generated by leakage from a coke oven door during a 16-hour coking cycle. The tests included: particulate emissions determination; trace metal analyses; gas analyses; organic analyses by IR ...

  17. Analytical methods used in a study of coke oven effluent.

    PubMed

    Schulte, K A; Larsen, D J; Hornung, R W; Crable, J V

    1975-02-01

    In a coke oven study conducted by NIOSH, selected chemical analyses of airborne particulates, vapors, and metals in the emissions from five coke ovens were done. Eight sampling procedures and seven analytical techniques were used to analyze samples collected for the study. Six of the analytical methods used are discussed. PMID:1146677

  18. Comparison of the tribological properties of fluorinated cokes and graphites

    NASA Technical Reports Server (NTRS)

    Fusaro, Robert L.

    1988-01-01

    The friction, wear, endurance life, and surface morphology of rubbed (burnished) fluorinated graphite and fluorinated coke materials were studied. Two different coke powders, a graphitic carbon powder, and a graphite powder were fluorinated and then tribologically investigated. In addition, one of the coke powders was reduced in size before fluorinating to evaluate the effect of a finer particle size on the tribological properties. For comparison, graphite and coke powders which were not fluorinated were also tribologically evaluated. Elemental analysis by emission spectroscopy was performed on each sample to determine the impurity content and X-ray diffraction analysis was performed to determine the crystallinity. Coke was found to have very little lubricating ability, but fluorinated coke did possess good lubricating properties. However, the fluorinated graphite and fluorinated graphitic carbon (which gave equivalent results) gave superior results to those obtained with the fluorinated cokes. No tribological benefit was found for using small versus a larger particle size of coke, at least when evaluated as a rubbed film.

  19. Comparison of the tribological properties of fluorinated cokes and graphites

    NASA Technical Reports Server (NTRS)

    Fusaro, Robert L.

    1987-01-01

    The friction, wear, endurance life, and surface morphology of rubbed (burnished) fluorinated graphite and fluorinated coke materials were studied. Two different coke powders, a graphitic carbon powder, and a graphite powder were fluorinated and then tribologically investigated. In addition, one of the coke powders was reduced in size before fluorinating to evaluate the effect of a finer particle size on the tribological properties. For comparison, graphite and coke powders which were not fluorinated were also tribologically evaluated. Elemental analysis by emission spectroscopy was performed on each sample to determine the impurity content and X-ray diffraction analysis was performed to determine the crystallinity. Coke was found to have very little lubricating ability, but fluorinated coke did possess good lubricating properties. However, the fluorinated graphite and fluorinated graphitic carbon (which gave equivalent results) gave superior results to those obtained with the fluorinated cokes. No tribological benefit was found for using small versus a larger particle size of coke, at least when evaluated as a rubbed film.

  20. CARCINOGEN ASSESSMENT OF COKE OVEN EMISSIONS (REVISED DRAFT)

    EPA Science Inventory

    Coke oven workers in Allegheny County, Pennsylvania and at 10 non-Allegheny County coke plants in the United States and Canada were found to be at an excess risk of mortality from cancer of all sites and from cancer of the lungs, bronchus, and trachea, kidney, and prostate. An im...

  1. Heat treatment of welded joints of steel 0.3С-1Cr-1Si produced by high-power fiber lasers

    NASA Astrophysics Data System (ADS)

    Kuryntsev, S. V.; Gilmutdinov, A. Kh.

    2015-11-01

    The effect of heat treatment on the welded joints of steel grade 0.3С-1Cr-1Si produced by 30 kW power fiber lasers was investigated in the paper. The speed of the welding process was 20 mm/s. Heat treatment was carried out on two levels, quenching with subsequent middle tempering and high tempering. The samples were examined before and after heat treatment, macro- and microstructure were studied using SEM, UTS, three points bent test, microhardness. The effect of heat treatment was significant: it allowed reduction of the weld hardness of considerably and enhancement of its ductility.

  2. Effect of physical disturbance on the structure of needle coke

    NASA Astrophysics Data System (ADS)

    Zhao, Shi-Gui; Wang, Bao-Cheng; Sun, Quan

    2010-10-01

    Through different preparation technology, this paper reports that the needle coke is prepared with coal-tar pitch under the effect of magnetic field and ultrasonic cavitation. It studies the effect of physical disturbance on the structure of needle coke. The structure of needle coke is characterized by scanning electron microscope and x-ray diffractometer, and the influence mechanism is analysed. Results showed that the structure and property of needle coke could be effectively improved by magnetic field and ultrasonic cavitations, such as degree of order, degree of graphitization and crystallization. Comparatively speaking, the effect of magnetic field was greater. The graphitization degree of needle coke prepared under the effect of magnetic field is up to 45.35%.

  3. Coke Deposition and Smoke Formation in Turbojet Engines

    NASA Technical Reports Server (NTRS)

    Hibbard, R. R.; Wear, J. D.

    1956-01-01

    In the early development of jet engines, it was occasionally found that excessive amounts of coke or other carbonaceous deposits were formed in the combustion chamber. Sometimes a considerable amount of smoke was noted in the-exhaust gases. Excessive coke deposits may adversely affect jet-engine performance in several ways. The formation of excessive amounts of coke on or just downstream of a fuel nozzle (figs. 116(a) and (b)) changes the fuel-spray pattern and possibly affects combustor life and performance. Similar effects on performance can result from the deposition of coke on primary-air entry ports (fig. 116(c)). Sea-level or altitude starting may be impaired by the deposition of coke on spark-plug electrodes (fig. 116(b)), deposits either grounding the electrodes completely or causing the spark to occur at positions other than the intended gap. For some time it was thought that large deposits of coke in turbojet combustion chambers (fig. 116(a)) might break away and damage turbine blades; however, experience has indicated that for metal blades this problem is insignificant. (Cermet turbine blades may be damaged by loose coke deposits.) Finally, the deposition of coke may cause high-temperature areas, which promote liner warping and cracking (fig. 116(d)) from excessive temperature gradients and variations in thermal-expansion rates. Smoke in the exhaust gases does not generally impair engine performance but may be undesirable from a tactical or a nuisance standpoint. Appendix B of reference 1 and references 2 to 4 present data obtained from full-scale engines operated on test stands and from flight tests that indicate some effects on performance caused by coke deposits and smoke. Some information about the mechanism of coke formation is given in reference 5 and chapter IX. The data indicate that (1) high-boiling fuel residuals and partly polymerized products may be mixed with a large amount of smoke formed in the gas phase to account for the consistency

  4. Evaluation of co-cokes from bituminous coal with vacuum resid or decant oil, and evaluation of anthracites, as precursors to graphite

    NASA Astrophysics Data System (ADS)

    Nyathi, Mhlwazi S.

    2011-12-01

    Graphite is utilized as a neutron moderator and structural component in some nuclear reactor designs. During the reactor operaction the structure of graphite is damaged by collision with fast neutrons. Graphite's resistance to this damage determines its lifetime in the reactor. On neutron irradiation, isotropic or near-isotropic graphite experiences less structural damage than anisotropic graphite. The degree of anisotropy in a graphite artifact is dependent on the structure of its precursor coke. Currently, there exist concerns over a short supply of traditional precursor coke, primarily due to a steadily increasing price of petroleum. The main goal of this study was to study the anisotropic and isotropic properties of graphitized co-cokes and anthracites as a way of investigating the possibility of synthesizing isotropic or near-isotropic graphite from co-cokes and anthracites. Demonstrating the ability to form isotropic or near-isotropic graphite would mean that co-cokes and anthracites have a potential use as filler material in the synthesis of nuclear graphite. The approach used to control the co-coke structure was to vary the reaction conditions. Co-cokes were produced by coking 4:1 blends of vacuum resid/coal and decant oil/coal at temperatures of 465 and 500 °C for reaction times of 12 and 18 hours under autogenous pressure. Co-cokes obtained were calcined at 1420 °C and graphitized at 3000 °C for 24 hours. Optical microscopy, X-ray diffraction, temperature-programmed oxidation and Raman spectroscopy were used to characterize the products. It was found that higher reaction temperature (500 °C) or shorter reaction time (12 hours) leads to an increase in co-coke structural disorder and an increase in the amount of mosaic carbon at the expense of textural components that are necessary for the formation of anisotropic structure, namely, domains and flow domains. Characterization of graphitized co-cokes showed that the quality, as expressed by the degree of

  5. Influence of Alumina Addition to Aluminum Fins for Compact Heat Exchangers Produced by Cold Spray Additive Manufacturing

    NASA Astrophysics Data System (ADS)

    Farjam, Aslan; Cormier, Yannick; Dupuis, Philippe; Jodoin, Bertrand; Corbeil, Antoine

    2015-10-01

    In this work, aluminum and aluminum-alumina powder mixtures were used to produce pyramidal fin arrays on aluminum substrates using cold spray as an additive manufacturing process. Using aluminum-alumina mixtures instead of pure aluminum powder could be seen as a cost-effective measure, preventing nozzle clogging or the need to use expensive polymer nozzles that wear out rapidly during cold spray. The fin geometries that were produced were observed using a 3D digital microscope to determine the flow passages width and fins' geometric details. Heat transfer and pressure drop tests were carried out using different ranges of appropriate Reynolds numbers for the sought commercial application to compare each fin array and determine the effect of alumina content. It was found that the presence of alumina reduces the fins' performance when compared to pure aluminum fins but that they were still outperforming traditional fins. Numerical simulations were performed to model the fin arrays and were used to predict the pressure loss in the fin array and compare these results with experimental values. The numerical model opens up new avenues in predicting different applicable operating conditions and other possible fin shapes using the same fin composition, instead of performing costly and time-consuming experiments.

  6. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W.

    1996-02-01

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  7. Effect of paste humidity on kinetics of carbothermal reduction of extruded barite and coke mixture

    NASA Astrophysics Data System (ADS)

    Salem, A.; Jamshidi, S.

    2012-08-01

    The effect of the moisture content of barite-coke paste on the kinetics of carbothermal reduction was investigated to understand the role of extrusion technique on this type of solid-gas reaction. The pastes were formulated using the typical natural barite and coke powders normally used in the industrial scale. 0.65 wt.% carboxyl methyl cellulose and different amounts of distilled water, ranging 24.3-34.4% were added to the mixed powders. The obtained pastes were then shaped by a laboratory extruder. The extrusion process was assessed by determining the total porosity of dry samples. The samples in the form of disc were isothermally heated at different temperatures in the range of 800-950 °C and the conversion of barite into barium sulfide was measured by the iodometry. The reduction data were analyzed by a modified kinetic model and the frequency factor and activation energy were calculated to evaluate the reduction mechanism. It was found that the moisture content of the paste significantly affects the active site density due to increasing contact surface area between coke and barite particles.

  8. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect

    Pettrey, J.O.; Greene, D.E. )

    1993-01-01

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  9. Uncertainty Analysis on Heat Transfer Correlations for RP-1 Fuel in Copper Tubing

    NASA Technical Reports Server (NTRS)

    Driscoll, E. A.; Landrum, D. B.

    2004-01-01

    NASA is studying kerosene (RP-1) for application in Next Generation Launch Technology (NGLT). Accurate heat transfer correlations in narrow passages at high temperatures and pressures are needed. Hydrocarbon fuels, such as RP-1, produce carbon deposition (coke) along the inside of tube walls when heated to high temperatures. A series of tests to measure the heat transfer using RP-1 fuel and examine the coking were performed in NASA Glenn Research Center's Heated Tube Facility. The facility models regenerative cooling by flowing room temperature RP-1 through resistively heated copper tubing. A Regression analysis is performed on the data to determine the heat transfer correlation for Nusselt number as a function of Reynolds and Prandtl numbers. Each measurement and calculation is analyzed to identify sources of uncertainty, including RP-1 property variations. Monte Carlo simulation is used to determine how each uncertainty source propagates through the regression and an overall uncertainty in predicted heat transfer coefficient. The implications of these uncertainties on engine design and ways to minimize existing uncertainties are discussed.

  10. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Alternative standards for coke oven... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for coke oven doors equipped with sheds. (a) The owner or operator of a new or existing coke oven...

  11. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Alternative standards for coke oven... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for coke oven doors equipped with sheds. (a) The owner or operator of a new or existing coke oven...

  12. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Alternative standards for coke oven... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for coke oven doors equipped with sheds. (a) The owner or operator of a new or existing coke oven...

  13. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Alternative standards for coke oven... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for coke oven doors equipped with sheds. (a) The owner or operator of a new or existing coke oven...

  14. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Alternative standards for coke oven... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for coke oven doors equipped with sheds. (a) The owner or operator of a new or existing coke oven...

  15. Coke mineral transformations in the experimental blast furnace

    SciTech Connect

    Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla

    2008-09-15

    Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

  16. Variation in coke properties within the blast-furnace shop

    SciTech Connect

    E.N. Stepanov; I.I. Mel'nikov; V.P. Gridasov; A.A. Stepanova

    2009-04-15

    In active production at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), samples of melt materials were taken during shutdown and during planned repairs at furnaces 1 and 8. In particular, coke was taken from the tuyere zone at different distances from the tuyere tip. The mass of the point samples was 2-15 kg, depending on the sampling zone. The material extracted from each zone underwent magnetic separation and screening by size class. The resulting coke sample was averaged out and divided into parts: one for determining the granulometric composition and mechanical strength; and the other for technical analysis and determination of the physicochemical properties of the coke.

  17. Characteristics of laboratory-coked resid HDS catalyst

    SciTech Connect

    Baumgart, J. Wang, Y.; Ernst, W.R. )

    1990-12-01

    A sample of commercial residual oil hydrotreating catalyst with a bimodal pore structure was coked to progressively higher levels with styrene at 425{degree}C. Measurements of porosity by mercury intrusion-extrusion porosimetry, nitrogen adsorption-desorption porosimetry, and coronene diffusivity reveal the importance of the pore network to the structure of the coked catalyst. The role played by 'shielded' large pores within the structure is demonstrated. It is proposed that coking first occurs at the junctions between large, shielded pores and narrow connecting pores. The results are discussed in terms of the theoretical predictions of Mann and co-workers.

  18. Universal model of slow pyrolysis technology producing biochar and heat from standard biomass needed for the techno-economic assessment.

    PubMed

    Klinar, Dušan

    2016-04-01

    Biochar as a soil amendment and carbon sink becomes in last period one of the vast, interesting product of slow pyrolysis. Simplest and most used industrial process arrangement is a production of biochar and heat at the same time. Proposed mass and heat balance model consist of heat consumers (heat demand side) and heat generation-supply side. Direct burning of all generated uncondensed volatiles from biomass provides heat. Calculation of the mass and heat balance of both sides reveals the internal distribution of masses and energy inside process streams and units. Thermodynamic calculations verified not only the concept but also numerical range of the results. The comparisons with recent published scientific and vendors data prove its general applicability and reliability. The model opens the possibility for process efficiency innovations. Finally, the model was adapted to give more investors favorable results and support techno-economic assessments entirely. PMID:26851894

  19. Utilization of spent coking plant acid

    SciTech Connect

    Vasil'eva, I.V.; Vasilenko, N.Y.; Mostovaya, V.G.; Tret'yak, N.K.

    1983-01-01

    A feasibility study is described for using spent regenerated sulfuric acid from a coking plant, containing 540-640 g/l H/sub 2/SO/sub 4/, to pickle metals. Results were compared with the performance of a solution of technical sulfuric acid in pickling high-carbon and low-alloy steels. It was found economically feasible to use the spent regenerated acid as the basic pickling solution. The degree of protection of the metal against corrosion is 85%, which can be increased to 98-99% if inhibitors are added to the acid. Only one-fifth as much inhibitor is needed with the regenerated acid as with the technical sulfuric acid.

  20. Thermal processes in the two-stage primary cooling of coke oven gas

    SciTech Connect

    Petrukhno, R.P.; Vasil'ev, Y.S.

    1982-01-01

    An investigation of a two-stage method for the cooling of coke oven gas was presented. The method employed air-cooling in a finned-tube exchanger for primary cooling, and then water cooling in a horizontal tube exchanger. Calculations showed that about 80% of the heat was removed by the air cooler. Also, the cooling water savings was about 70-75% over conventional methods using water only. The two stage concept allowed increased velocity of the gas and decreasing the sealing of the exchanger.

  1. The effect of treatment stages on the coking wastewater hazardous compounds and their toxicity.

    PubMed

    Wei, Xiao-xue; Zhang, Zi-yang; Fan, Qing-lan; Yuan, Xiao-ying; Guo, Dong-sheng

    2012-11-15

    This study investigated the change of hazardous materials in coking wastewater at different treatment stages (anaerobic, anaerobic/aerobic, anaerobic/aerobic/photo degradation, anaerobic/aerobic/ozone oxidation treatment) and the effects of them on the development of maize embryos and the activity of amylase and protease in maize seeds. Moreover the interaction of refractory organic matters in the wastewater at different treatment stages with amylase and protease also were determined in vitro. The results show that the biodegradable and the refractory organic compounds in the wastewater both can affect maize embryo development (germination inhibition rate is 19.3% for biodegradable organic compounds). As the treatment stage preceding, the inhibition effect of coking wastewater on the development of the maize embryo (for germination inhibition rates change from 49.3% to 24.6%) and on enzymatic activity (inhibition rates change from 63.9% to 22.4% for amylase) decreases gradually, but the photo-degradation treatment to anaerobic/aerobic effluent can increase its toxicity. The changes in the ability of the refractory organic compounds to bind with enzyme proteins, combined with the analysis of the organic components by GC/MS, show that in the process of coking wastewater treatment no new toxic chemicals were produced. PMID:23022415

  2. Improved coking resistance of direct ethanol solid oxide fuel cells with a Ni-Sx anode

    NASA Astrophysics Data System (ADS)

    Yan, Ning; Luo, Jing-Li; Chuang, Karl T.

    2014-03-01

    In this study, the coking resistance of anode supported direct ethanol solid oxide fuel cell with a Ni-Sx anode was investigated comparatively with the conventional cell using pure Ni catalyst. The surface catalytic properties of Ni were manipulated via depositing a layer of S atoms. It was confirmed that on the surface of Ni, a combination of S monolayer and elemental S was formed without producing Ni3S2 phase. The developed Ni-Sx cell exhibited a significantly improved coke resistivity in ethanol feed while maintaining an adequately high performance. The S species on Ni enabled the suppression of the coke formation as well as the alleviation of the metal dusting effect of the anode structure. After operating in ethanol fuel for identical period of time at 850 °C, a maximum power density of 400 mW cm-2 was sustained whereas the conventional cell performance decreased to less than 40 mW cm-2 from the original 704 mW cm-2. In an optimized stability test, the Ni-Sx cell operated at 750 °C for more than 22 h until the fuel drained without any degradation.

  3. 14. Battery of coke ovens (DX?) on right, pusher cars ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. Battery of coke ovens (DX?) on right, pusher cars on right, hot gas pipes on left and overhead; pulverized coal bunker is tall, vertical structure on left. looking south - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  4. 2. PANORAMA OF INDUSTRY: (CLOCKWISE FROM LEFT) USSTEEL COKE GAS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. PANORAMA OF INDUSTRY: (CLOCKWISE FROM LEFT) USSTEEL COKE GAS PIPELINE, URR COAL LOADING STATION, CONRAIL PORT PERRY BRIDGE, URR HOT METAL BRIDGE, USSSTEEL EDGAR THOMSON WORKS. - Conrail Port Perry Bridge, Spanning Monongahela River, Elizabeth, Allegheny County, PA

  5. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect

    Giertz, J.; Huhn, F.; Hofherr, K.

    1995-12-01

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  6. Priorities in the design of chemical shops at coke plants

    SciTech Connect

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak

    2009-07-15

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  7. Experimental research on quality features of metallurgical coke

    NASA Astrophysics Data System (ADS)

    Andrei, V.; Constantin, N.

    2015-06-01

    From all the solid fuels, the metallurgical coke is the most used in obtaining iron in the blast furnace. Together with the iron ore, manganese ore and fluxes, it constitutes the basis of raw materials and materials for elaborating pig iron. This paper presents the results of laboratory investigations by the authors to determine the most important quality characteristics of some types of coke used in the blast furnace charge.

  8. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect

    Not Available

    1992-08-24

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  9. Mortality of coke plant workers in The Netherlands.

    PubMed

    Swaen, G M; Slangen, J J; Volovics, A; Hayes, R B; Scheffers, T; Sturmans, F

    1991-02-01

    During the production of coke, large quantities of coke oven gas are emitted. People who work on the top or on the sides of coke ovens are exposed to this oven gas, which contains a range of carcinogenic chemicals. To investigate the cancer risks under these work conditions, a retrospective study was undertaken. In total 11,399 former workers were enrolled in the study. Of these, 5639 had worked in the coke plant for at least six months between 1945 and 1969. The other 5740 had worked in another plant during the same period and formed a non-exposed group for comparison. The study group was followed up until 1984 for mortality. The causes of death were obtained from the Central Bureau of Statistics. Among the coke oven workers significantly higher death rates were found for lung cancer and non-malignant respiratory disease. Mortality in the byproduct section was similar to that expected. Among workers in the tar distillery the rate for lung cancer was higher than expected. The risk for gastric cancer and non-malignant respiratory disease among the workers of the coke shipping department was increased but the SMRs did not reach statistical significance. No data were collected about individual smoking habits or socioeconomic state of the study subjects and the possibility that the risk found could be attributed to these factors cannot be ruled out. It has been stated by other investigators, however, that the effect of not controlling for smoking tends to be modest. PMID:1998607

  10. Bronchitis in men employed in the coke industry

    PubMed Central

    Walker, D. D.; Archibald, R. M.; Attfield, M. D.

    1971-01-01

    Walker, D. D., Archibald, R. M., and Attfield, M. D. (1971).Brit. J. industr. Med.,28, 358-363. Bronchitis in men employed in the coke industry. An epidemiological survey to determine the prevalence of bronchitis in men employed at two of the National Coal Board's coking plants is described. Eight hundred and eighty-one men (91%) of the total working population were examined. A strong association was found between bronchitis prevalence and cigarette smoking (P < 0·001). In addition, men who smoked and who were exposed to high temperatures, dust, and fumes in the environment of the coke-ovens had more bronchitis than men who worked elsewhere in the cokeworks (P < 0·02). Both the presence of bronchitis and employment in the environment of the coke-ovens had significant and independent effects on ventilatory capacity. The combination of cigarette smoking and previous employment in a dusty industry also had a significant effect on ventilatory capacity. The investigation suggests that cigarette smoking, and the combination of smoking and pollution from the coke-ovens and previous occupation, appear to be important factors in the aetiology of bronchitis and reduced ventilatory capacity in men employed in the coke manufacturing industry. PMID:5124835

  11. Mortality of coke plant workers in The Netherlands.

    PubMed Central

    Swaen, G M; Slangen, J J; Volovics, A; Hayes, R B; Scheffers, T; Sturmans, F

    1991-01-01

    During the production of coke, large quantities of coke oven gas are emitted. People who work on the top or on the sides of coke ovens are exposed to this oven gas, which contains a range of carcinogenic chemicals. To investigate the cancer risks under these work conditions, a retrospective study was undertaken. In total 11,399 former workers were enrolled in the study. Of these, 5639 had worked in the coke plant for at least six months between 1945 and 1969. The other 5740 had worked in another plant during the same period and formed a non-exposed group for comparison. The study group was followed up until 1984 for mortality. The causes of death were obtained from the Central Bureau of Statistics. Among the coke oven workers significantly higher death rates were found for lung cancer and non-malignant respiratory disease. Mortality in the byproduct section was similar to that expected. Among workers in the tar distillery the rate for lung cancer was higher than expected. The risk for gastric cancer and non-malignant respiratory disease among the workers of the coke shipping department was increased but the SMRs did not reach statistical significance. No data were collected about individual smoking habits or socioeconomic state of the study subjects and the possibility that the risk found could be attributed to these factors cannot be ruled out. It has been stated by other investigators, however, that the effect of not controlling for smoking tends to be modest. PMID:1998607

  12. Effect of γ-Aminobutyric Acid-producing Lactobacillus Strain on Laying Performance, Egg Quality and Serum Enzyme Activity in Hy-Line Brown Hens under Heat Stress.

    PubMed

    Zhu, Y Z; Cheng, J L; Ren, M; Yin, L; Piao, X S

    2015-07-01

    Heat-stress remains a costly issue for animal production, especially for poultry as they lack sweat glands, and alleviating heat-stress is necessary for ensuring animal production in hot environment. A high γ-aminobutyric acid (GABA)-producer Lactobacillus strain was used to investigate the effect of dietary GABA-producer on laying performance and egg quality in heat-stressed Hy-line brown hens. Hy-Line brown hens (n = 1,164) at 280 days of age were randomly divided into 4 groups based on the amount of freeze-dried GABA-producer added to the basal diet as follows: i) 0 mg/kg, ii) 25 mg/kg, iii) 50 mg/kg, and iv) 100 mg/kg. All hens were subjected to heat-stress treatment through maintaining the temperature and the relative humidity at 28.83±3.85°C and 37% to 53.9%, respectively. During the experiment, laying rate, egg weight and feed intake of hens were recorded daily. At the 30th and 60th day after the start of the experiment, biochemical parameters, enzyme activity and immune activity in serum were measured. Egg production, average egg weight, average daily feed intake, feed conversion ratio and percentage of speckled egg, soft shell egg and misshaped egg were significantly improved (p<0.05) by the increasing supplementation of the dietary GABA-producer. Shape index, eggshell thickness, strength and weight were increased linearly with increasing GABA-producer supplementation. The level of calcium, phosphorus, glucose, total protein and albumin in serum of the hens fed GABA-producing strain supplemented diet was significantly higher (p<0.05) than that of the hens fed the basal diet, whereas cholesterol level was decreased. Compared with the basal diet, GABA-producer strain supplementation increased serum level of glutathione peroxidase (p = 0.009) and superoxide dismutase. In conclusion, GABA-producer played an important role in alleviating heat-stress, the isolated GABA-producer strain might be a potential natural and safe probiotic to use to improve laying

  13. Effect of γ-Aminobutyric Acid-producing Lactobacillus Strain on Laying Performance, Egg Quality and Serum Enzyme Activity in Hy-Line Brown Hens under Heat Stress

    PubMed Central

    Zhu, Y. Z.; Cheng, J. L.; Ren, M.; Yin, L.; Piao, X. S.

    2015-01-01

    Heat-stress remains a costly issue for animal production, especially for poultry as they lack sweat glands, and alleviating heat-stress is necessary for ensuring animal production in hot environment. A high γ-aminobutyric acid (GABA)-producer Lactobacillus strain was used to investigate the effect of dietary GABA-producer on laying performance and egg quality in heat-stressed Hy-line brown hens. Hy-Line brown hens (n = 1,164) at 280 days of age were randomly divided into 4 groups based on the amount of freeze-dried GABA-producer added to the basal diet as follows: i) 0 mg/kg, ii) 25 mg/kg, iii) 50 mg/kg, and iv) 100 mg/kg. All hens were subjected to heat-stress treatment through maintaining the temperature and the relative humidity at 28.83±3.85°C and 37% to 53.9%, respectively. During the experiment, laying rate, egg weight and feed intake of hens were recorded daily. At the 30th and 60th day after the start of the experiment, biochemical parameters, enzyme activity and immune activity in serum were measured. Egg production, average egg weight, average daily feed intake, feed conversion ratio and percentage of speckled egg, soft shell egg and misshaped egg were significantly improved (p<0.05) by the increasing supplementation of the dietary GABA-producer. Shape index, eggshell thickness, strength and weight were increased linearly with increasing GABA-producer supplementation. The level of calcium, phosphorus, glucose, total protein and albumin in serum of the hens fed GABA-producing strain supplemented diet was significantly higher (p<0.05) than that of the hens fed the basal diet, whereas cholesterol level was decreased. Compared with the basal diet, GABA-producer strain supplementation increased serum level of glutathione peroxidase (p = 0.009) and superoxide dismutase. In conclusion, GABA-producer played an important role in alleviating heat-stress, the isolated GABA-producer strain might be a potential natural and safe probiotic to use to improve laying

  14. Innovative coke oven gas cleaning system for retrofit applications. Quarterly technical progress report No. 4, October 1, 1990 to December 31, 1990

    SciTech Connect

    Kwasnoski, D.

    1993-10-22

    Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A subcontractor has been retained to develop a computerized program for operations and maintenance training for the coke oven gas treatment plant. Recent developments in the coke plant operating plans will result in reductions in the rate of production of coke oven gas to be processed in the demonstration project.

  15. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect

    Sutcu, H.; Toroglu, I.; Piskin, S.

    2009-07-01

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  16. Mechanism of Formation and Stabilization of Nanoparticles Produced by Heating Electrostatic Complexes of WPI-Dextran Conjugate and Chondroitin Sulfate.

    PubMed

    Dai, Qingyuan; Zhu, Xiuling; Yu, Jingyang; Karangwa, Eric; Xia, Shuqin; Zhang, Xiaoming; Jia, Chengsheng

    2016-07-13

    Protein conformational changes were demonstrated in biopolymer nanoparticles, and molecular forces were studied to elucidate the formation and stabilization mechanism of biopolymer nanoparticles. The biopolymer nanoparticles were prepared by heating electrostatic complexes of whey protein isolate (WPI)-dextran conjugate (WD) and chondroitin sulfate (ChS) above the denaturation temperature and near the isoelectric point of WPI. The internal characteristics of biopolymer nanoparticles were analyzed by several spectroscopic techniques. Results showed that grafted dextran significantly (p < 0.05) prevented the formation of large aggregates of WD dispersion during heat treatment. However, heat treatment slightly induced the hydrophobicity changes of the microenvironment around fluorophores of WD. ChS electrostatic interaction with WD changed the fluorescence intensity of WD regardless of heat treatment. Far-UV circular dichroism (CD) and attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopies confirmed that glycosylation and ionic polysaccharide did not significantly cause protein conformational changes in WD and ChS (WDC) during heat treatment. In addition, hydrophobic bonds were the major molecular force for the formation and stabilization of biopolymer nanoparticles. However, hydrogen bonds slightly influenced their formation and stabilization. Ionic bonds only promoted the formation of biopolymer nanoparticles, while disulfide bonds partly contributed to their stability. This work will be beneficial to understand protein conformational changes and molecular forces in biopolymer nanoparticles, and to prepare the stable biopolymer nanoparticles from heating electrostatic complexes of native or glycosylated protein and polysaccharide. PMID:27329490

  17. Effect of Heat Treatment on the Microstructure and Mechanical Properties of Stainless Steel 316L Coatings Produced by Cold Spray for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    AL-Mangour, Bandar; Vo, Phuong; Mongrain, Rosaire; Irissou, Eric; Yue, Stephen

    2014-04-01

    In this study, the effects of heat treatment on the microstructure and mechanical properties of cold sprayed stainless steel 316L coatings using N2 and He as propellant gases were investigated. Powder and coating characterizations, including coating microhardness, coating porosity, and XRD phase analysis were performed. It was found that heat treatment reduced porosity, improved inter-particle bonding, and increased ductility. XRD results confirmed that no phase transformation occurred during deposition. Significant increase in UTS and ductility was observed for the annealed specimens obtained with nitrogen propellant, whereas little changes were observed for the helium propellant produced specimen.

  18. Process for producing cracked distillate and hydrogen from heavy oil

    SciTech Connect

    Aizawa, S.; Fujimori, K.; Satomi, Y.; Suzuka, T.

    1980-09-23

    A process is disclosed for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalysts, reducing the laterite or laterote-containing catalyst on which the coke is deposited, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.

  19. Effect of different pH coking wastewater on adsorption of coking coal.

    PubMed

    Gao, Lihui; Li, Shulei; Wang, Yongtian

    2016-01-01

    H2SO4 has an effect on the sorption of organic contaminants by coking coal (CC) in wastewater. This paper focused on the effect of pH on the removal of chemical oxygen demand (COD), phenols and ammonia. UV-vis spectra, Fourier transform infrared spectra, zeta potential and Brunauer, Emmett and Teller (BET) analysis were investigated to characterize the changes of CC properties and coking wastewater (CW) at different pH values. The results showed that the COD and phenol removal efficiencies increased with decreasing pH value, while the ammonia removal efficiency was decreased gradually. A new transmittance band in the region of 340-600 cm(-1) was observed in UV-vis spectra of CW in acidic condition. The absolute value of the zeta potential as the solution was gradually increasing with the increasing of pH value. Surface area and total pore volume of CC which was immersed in acidic solutions measured by BET were much higher than that of raw CC. CC has a greater adsorption capacity to organic pollution in the acidic solution mainly by van der Waals forces and hydrogen bonding. PMID:26877041

  20. Two inhibitors of neutrophil chemotaxis are produced by hyperimmunoglobulin E recurrent infection syndrome mononuclear cells exposed to heat-killed staphylococci.

    PubMed Central

    Donabedian, H; Gallin, J I

    1983-01-01

    Mononuclear cells from normal volunteers and from patients with the hyperimmunoglobulin E recurrent infection syndrome (HIE) were cultured for 18 h with and without opsonized, heat-killed Staphylococcus aureus (OS). The supernatants from normal mononuclear cell cultures without OS revealed no inhibitory activity for neutrophil chemotaxis, whereas those from HIE patients revealed the previously reported 61,000-dalton factor. However, when normal cells were cultured with OS, they produced a proteinaceous, 56 degrees C-stable, 30,000- to 45,000-dalton factor which preferentially inhibited neutrophil versus monocyte chemotaxis. When HIE cells were exposed to OS, they produced the same 30,000- to 45,000-dalton factor as normal cells, as well as the 61,000-dalton factor that they produced spontaneously. Assay of 1,000-fold dilutions of supernatants from cultures of normal mononuclear cells with OS revealed a mean production of 7.8 +/- 5.4% inhibition of chemotaxis, whereas assay of 1,000-fold dilutions of supernatants from cultures of HIE mononuclear cells (spontaneously producing the 61,000-dalton factor) with OS revealed a 26.6 +/- 3.6% inhibition (P less than 0.02). The data indicate that in short-term culture both normal and HIE mononuclear cells produce an inhibitor of neutrophil chemotaxis when exposed to particulate heat-killed staphylococci but that HIE cells produce qualitatively and quantitatively more inhibitory activity. PMID:6343237

  1. Oxidizing Roasting Performances of Coke Fines Bearing Brazilian Specularite Pellets

    NASA Astrophysics Data System (ADS)

    Chun, Tiejun; Zhu, Deqing

    2016-06-01

    Oxidized pellets, consisting of Brazilian specularite fines and coke fines, were prepared by disc pelletizer using bentonite as binder. The roasting process of pellets includes preheating stage and firing stage. The compressive strength of preheated pellets and fired pellets reached the peak value at 1.5% coke fines dosage. During the initial stage of preheating, some original Fe2O3 was reduced to Fe3O4 because of partial reduction atmosphere in pellet. During the later stage of preheating and firing stage, coke fines were burnt out, and the secondary Fe2O3 (new generation Fe2O3) was generated due to the re-oxidization of Fe3O4, which improved the recrystallization of Fe2O3. Compared with the fired pellets without adding coke fines, fired pellets with 1.5% coke fines exhibited the comparable RSI (reduction swelling index) and RDI+3.15 mm (reduction degradation index), and slightly lower RI (reducibility index).

  2. Health survey of former workers in a Norwegian coke plant: Part. 1. Estimation of historical exposures

    PubMed Central

    Romundstad, P. R.; Ronneberg, A.; Leira, H. L.; Bye, T.

    1998-01-01

    OBJECTIVE: To estimate historical exposure levels at a coke plant for all agents considered to be of importance for epidemiological studies of mortality and cancer incidence. METHODS: Time weighted average exposure (8 h TWA) was estimated based on personal measurements for polycyclic aromatic hydrocarbons (PAHs) and carbonaceous particulates. Exposure to quartz was estimated relative to the concentration of carbonaceous particulates. These estimates were adjusted for the use of airstream helmets. Exposure to other agents were estimated qualitatively (asbestos, benzene, and arsenic) or semi-quantitatively (carbon monoxide (CO) and heat) based on measurements and other indicators of exposure. RESULTS: Exposure to PAHs was highest for those who worked at the top of the ovens (300 micrograms/m3) in the period from 1970-6. The estimated PAH exposure was reduced to an average of 65 micrograms/m3 after the introduction of exposure control measures in 1976. The estimates for carbonaceous particulates ranged from 1 to 16 mg/m3, with the highest exposure for workers at the top of the ovens and at the coke screening station. CONCLUSIONS: The exposure of greatest concern in this study is to PAHs, but exposures to carbonaceous particulates and CO may also be of importance. The major limitations of this study are the lack of personal measurements before 1975 and the total lack of measurements for some of the exposed categories of workers. Despite these limitations, we think that this assessment reflects the actual exposures for most of the former employees. The assessment thus provides a reasonable tool for the subsequent epidemiological study and for future epidemiological follow up studies at the coke plant.   PMID:9861184

  3. 75 FR 11936 - USS Clairton Coke Works, Clairton, PA; Notice of Termination of Investigation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-12

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF LABOR Employment and Training Administration USS Clairton Coke Works, Clairton, PA; Notice of Termination of... Coke Works, Clairton, Pennsylvania. The petitioner has requested that the petition be...

  4. Apparatus and method of using a fuel gas regulator for a coke oven battery

    SciTech Connect

    Dickerson, D.M.; Filkes, R.W.

    1985-08-06

    Method and apparatus for the regulation of the flow of fuel gas in the fuel gas supply duct of a heating wall of a coke oven to assure uniform heat distribution in the oven are provided. The regulating means consists of a thin plate having a similar shape to that of a fuel gas supply duct for insertion therein. Pivotally attached to and extending perpendicularly from the outer face of the plate are twin parallel control rods with gage marks inscribed thereon. To effect the regulation of fuel gas flow, the regulating means is inserted into the fuel gas supply duct at an appropriate location and the flow rate is adjusted by pivoting the plate by the manipulation of the adjusting rods.

  5. The mathematical description of the gasification process of woody biomass in installations with a plasma heat source for producing synthesis gas

    NASA Astrophysics Data System (ADS)

    Sadrtdinov, A. R.; Safin, R. G.; Gerasimov, M. K.; Petrov, V. I.; Gilfanov, K. K.

    2016-04-01

    The article presents the scheme of processing of plant biomass in the gasification installation with a plasma heat source to produce synthesis gas suitable for chemical industry. The analyzed physical picture of raw materials' recycling process underlies a mathematical description of the process set out in the form of the basic differential equations with boundary conditions. The received mathematical description allows calculating of the main parameters of equipment for biomass recycling and to determine the optimal modes of its operation.

  6. A phase-separation kinetic model for coke formation

    SciTech Connect

    Wiehe, I.A. . Corporate Research Lab.)

    1993-11-01

    Coke formation during the thermolysis of petroleum residua is postulated to occur by a mechanism that involves the liquid-liquid phase separation of reacted asphaltenes to form a phase that is lean in abstractable hydrogen. This mechanism provides the basis of a model that quantitatively describes the kinetics for the thermolysis of Cold Lake vacuum residuum and its deasphalted oil in an open-tube reactor at 400 C. The previously unreacted asphaltenes were found to be the fraction with the highest rate of thermal reaction but with the least extent of reaction. This not only described the appearance and disappearance of asphaltenes but also quantitatively described the variation in molecular weight and hydrogen content of the asphaltenes with reaction time. Further evidence of the liquid-liquid phase separation was the observation of spherical particles of liquid crystalline coke and the preferential conversion of the most associated asphaltenes to coke.

  7. A phase separation kinetic model for coke formation

    SciTech Connect

    Wiehe, I.A.

    1993-12-31

    Coke formation during the thermolysis of petroleum residua is postulated to occur by a mechanism that involves the liquid-liquid phase separation of reacted asphaltenes to form a phase that is lean in abstractable hydrogen. This mechanism provides the basis of a model the quantitatively describes the kinetics for the thermolysis of Cold Lake vacuum residuum and its deasphalted oil in an open tube reactor at 400{degrees}C. The previously unreacted asphaltenes were found to be the fraction with the highest rate of thermal reaction but with the least extent of reaction. Further evidence of the liquid-liquid phase separation was the observation of spherical particles of liquid crystalline coke and the preferential conversion of the most associated asphaltenes to coke.

  8. Textural changes in metallurgical coke prepared with polyethylene

    NASA Astrophysics Data System (ADS)

    Gornostayev, Stanislav S.; Heino, Jyrki J.; Kokkonen, Tommi M. T.; Makkonen, Hannu T.; Huttunen, Satu M. M.; Fabritius, Timo M. J.

    2014-10-01

    The effect of high-density polyethylene (HDPE) on the textural features of experimental coke was investigated using polarized-light optical microscopy and wavelet-based image analysis. Metallurgical coke samples were prepared in a laboratory-scale furnace with 2.5%, 5.0%, 7.5%, 10.0%, and 12.5% HDPE by mass, and one sample was prepared by 100% coal. The amounts and distribution of textures (isotropic, mosaic and banded) and pores were obtained. The calculations reveal that the addition of HDPE results in a decrease of mosaic texture and an increase of isotropic texture. Ethylene formed from the decomposition of HDPE is considered as a probable reason for the texture modifications. The approach used in this study can be applied to indirect evaluation for the reactivity and strength of coke.

  9. Application of probabilistic event attribution in the summer heat extremes in the western US to emissions traced to major industrial carbon producers

    NASA Astrophysics Data System (ADS)

    Mera, R. J.; Allen, M. R.; Mote, P.; Ekwurzel, B.; Frumhoff, P. C.; Rupp, D. E.

    2015-12-01

    Heat waves in the western US have become progressively more severe due to increasing relative humidity and nighttime temperatures, increasing the health risks of vulnerable portions of the population, including Latino farmworkers in California's Central Valley and other socioeconomically disadvantaged communities. Recent research has shown greenhouse gas emissions doubled the risk of the hottest summer days during the 2000's in the Central Valley, increasing public health risks and costs, and raising the question of which parties are responsible for paying these costs. It has been argued that these costs should not be taken up solely by the general public through taxation, but that additional parties can be considered, including multinational corporations who have extracted and marketed a large proportion of carbon-based fuels. Here, we apply probabilistic event attribution (PEA) to assess the contribution of emissions traced to the world's 90 largest major industrial carbon producers to the severity and frequency of these extreme heat events. Our research uses very large ensembles of regional climate model simulations to calculate fractional attribution of policy-relevant extreme heat variables. We compare a full forcings world with observed greenhouse gases, sea surface temperatures and sea ice extent to a counter-factual world devoid of carbon pollution from major industrial carbon producers. The results show a discernable fraction of record-setting summer temperatures in the western US during the 2000's can be attributed to emissions sourced from major carbon producers.

  10. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of...

  11. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations...

  12. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations...

  13. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of...

  14. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of...

  15. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of...

  16. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations...

  17. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations...

  18. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations...

  19. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of...

  20. [Characterization of PAHs in fly ashes from coke production].

    PubMed

    Mu, Ling; Peng, Lin; Liu, Xiao-Feng; Bai, Hui-Ling; Zhang, Jian-Qiang

    2013-03-01

    In order to investigate the characteristics of polycyclic aromatic hydrocarbons (PAHs) in ashes from coking, PAHs in ashes from three coke production plants were analyzed with GC-MS, and the distribution characteristics of PAHs and potential toxicity risk were discussed. The sum of 16 EPA prior PAHs varied from 8.17 x 10(2) to 5.17 x 10(3) microg x g(-1). PAH contents from the coke oven (stamp charging) with the height of 3.2 m were two times higher than those from the one (top charging) with the height of 6.0 m, and PAHs in ashes from coal charging were significantly higher than those from coke pushing in the same plant. Four-ring and five-ring PAHs were the dominant species in ashes from coking and the sum of them accounted for more than 80.00% of total PAHs. Chrysene (Chr), benzo [a] anthracene (BaA) and benzo [b] fluoranthene (BbF) were abundant in all ash samples. The content of total BaP-based toxic equivalency (BaPeq) ranged from 1.64 x 10(2) to 9.57 x 10(2) microg x g(-1). From the carcinogenic point of view, besides benzo [a] pyrene (BaP), dibenz [a,h] anthracene (DbA) contributed most to the overall toxicity of PAHs, followed by BaA and BbF. BaPeq concentration from coal charging was 5.21-fold higher than that from coke pushing, indicating that different reuse ways should be considered based on their specific toxicity profiles of PAHs. PMID:23745428

  1. The prospects for incineration of municipal solid waste in Russia in order to produce heat and electric power

    NASA Astrophysics Data System (ADS)

    Baskakov, A. P.

    2014-04-01

    The article presents the results of the low-temperature pyrolysis of the main components of municipal solid waste (MSW): wood, products of wood processing (paper, cardboard, fabrics, etc.), various plastics, rubber, as well as of a representative sample of MSW. A waste-to-energy plant is described, at which municipal solid waste is subjected to the pyrolysis, and then pyrolysis products are incinerated in a slagging-bottom furnace. The paper presents an analysis of the operation of a modern waste-to-energy plant equipped with a wet scrubber, with a high-degree recovery of the heat of exhaust gases by means of a heat pump, and with evaporation cooling of glowing slag in a tank filled with water. Chemical treatment of water circulating in the system makes it possible to convert heavy metals and other hazardous substances into the insoluble form and then to remove them.

  2. Mathematical model of non-stationary temperature distribution in the metal body produced by induction heating process

    NASA Astrophysics Data System (ADS)

    Rak, Josef

    2016-03-01

    An induction heating problem can be described by a parabolic differential equation. For this equation, specific Joule looses must be computed. It can be done by solving the Fredholm Integral Equation of the second kind for the eddy current of density. When we use the Nyström method with the singularity subtraction, the computation time is rapidly reduced. This paper shows the method for finding non-stationary temperature distribution in the metal body with illustrative examples.

  3. Influence of Heat Treatment on Structure and Charge Capacity of Sol-Gel Produced TiO2 Films

    NASA Astrophysics Data System (ADS)

    Özdemir, Orhan; Gökdemir, Fatma Pınar; Keskin, Bahadır; Kutlu, Kubilay

    Titanium dioxide thin films were synthesized by sol-gel route from titanium isopropoxide (TIP) with acetic acid. Prior to the heat treatment, the films were amorphous phase. Above 400 °C, phase transition took place from amorphous into anatase phase. Electrochromic properties of each phase indicated reversible coloration upon Li+ ion intercalation in cyclic voltammetric measurements. Nevertheless, both charge capacity and energy band gap of films begun to decrease with increase in annealing temperature due to the crystallization.

  4. Effect of Energetic Trapped Particles Produced by ICRF Wave Heating on Sawtooth Instability in the DIII-D Tokamak

    NASA Astrophysics Data System (ADS)

    Choi, M.; Chan, V. S.; Chu, M. S.; Jeon, Y. M.; Lao, L. L.; Li, G.; Pinsker, R. I.; Ren, Q.; Turnbull, A. D.

    2007-09-01

    We evaluate the accuracy of the Porcelli sawtooth model using more realistic numerical models from the ORBIT-RF and GATO codes in DIII-D fast wave heating experiments. Simulation results confirm that the fast wave-induced energetic trapped particles may stabilize the sawtooth instability. The crucial kinetic stabilizing contribution strongly depends on both the experimentally reconstructed magnetic shear at the q = 1 surface and the calculated poloidal beta of energetic trapped particles inside the q = 1 surface.

  5. Temperament and intuition: a commentary on Feltz and Cokely.

    PubMed

    Nadelhoffer, Thomas; Kvaran, Trevor; Nahmias, Eddy

    2009-03-01

    In this paper, we examine Adam Feltz and Edward Cokely's recent claim that "the personality trait extraversion predicts people's intuitions about the relationship of determinism to free will and moral responsibility" (INSERT REFERENCE). We will first present some criticisms of their work before briefly examining the results of a recent study of our own. We argue that while Feltz and Cokely have their finger on the pulse of an interesting and important issue, they have not established a robust and stable connection between extraversion and compatibilist-friendly intuitions. PMID:19136280

  6. Evaluation of antibacterial and anti-inflammatory activities of less polar ginsenosides produced from polar ginsenosides by heat-transformation.

    PubMed

    Wang, Lijun; Yang, Xiushi; Yu, Xiaona; Yao, Yang; Ren, Guixing

    2013-12-18

    Ginsenosides are the major active constituents in both white and red American ginseng (AG), and their pharmacological effects on central nervous, cardiovascular, and endocrine systems have been well elucidated. However, the anti-Propionibacterium acnes (P. acnes) activity of them is still unknown. In this study, 5 ginsenosides enriched fractions were obtained from the total ginsenosides extract of AG roots (TAG) by resin adsorption and heat-transformation. Resin purification decreased the total polyphenol (TP) content in the fractions. However, heat treatment increased the TP content and induced extensive conversion of the polar ginsenosides (Rg1, Re, Rb1, Rc, Rb2, Rd, and Gyp XVII) to less polar compounds (Rg2, Rg3, Rg6/F4, Rs3, and Rg5/Rk1). Only the heat-treated fraction from 65% methanol elution of the HP-20 column (HPHF) showed antibacterial activity against P. acnes (ATCC11827, MIC, 128 μg/mL; ATCC6919 MIC, 64 μg/mL), S. epidermidis (MIC, 4100 μg/mL) and S. aureus (MIC, 15000 μg/mL). In the anti-inflammatory activity assay, 10 μg/mL of HPHF significantly (P < 0.05) inhibited NO production in LPS-stimulated RAW264.7 cells. These results suggest that less polar ginsenosides enriched fraction HPHF obtained from AG might be useful to develop new types of antibacterial substances and new skin care cosmetics for acne prevention and therapy. PMID:24289140

  7. Long- but not short-term heat acclimation produces an apoptosis-resistant cardiac phenotype: a lesson from heat stress and ischemic/reperfusion insults.

    PubMed

    Assayag, Miri; Gerstenblith, Gary; Stern, Michael D; Horowitz, Michal

    2010-09-01

    Long-term heat acclimation (AC, 30d/34 degrees C) is a phenotypic adaptation leading to increased thermotolerance during heat stress (HS, 2 h 41 degrees C). AC also renders protection against ischemic/reperfusion (I/R, 30' global ischemia/40' reperfusion) insult via cross-tolerance mechanisms. In contrast to the protected AC phenotype, the onset of acclimation (34 degrees C, AC2d) is characterized by cellular perturbations, suggesting increased susceptibility to HS and I/R insults. In this investigation, we tested the hypothesis that apoptosis resistance is part of the AC repertoire and that, at the initial phase of acclimation (AC2d), cytoprotection is impaired. TUNEL staining and caspase 3 levels in HS and I/R insulted hearts affirmed this hypothesis. To examine the role of the mitochondria in life/death decision in AC2d and 30d AC settings vs. control hearts, we studied the Bcl-2 apoptotic cascade and found increased levels of the anti-apoptotic Bcl-X(L) and decreased levels of the pro-apoptotic death promoter Bad in hearts from AC2d and AC animals. In these groups, cytochrome c (cyt c) was elevated in the mitochondria and remained unchanged in the cytosol. This adaptation was insufficient to negate apoptosis in AC2d rats. At this early acclimation phase (and in controls), increased caspase 8 activity confirmed activation of the extrinsic (Fas ligand) apoptosis pathway. In conclusion, the elevated Bcl-X(L)/Bad ratio and decreased cyt c leakage to the cytosol are insufficient to protect the heart and interactions with additional cytoprotective pathways involved in acclimation (elevated HSP70, ROS, and sarcolemmal adaptations to abolish extrinsic apoptosis pathways) are required to induce the apoptosis-resistant AC phenotype. PMID:20221856

  8. Project Title: Small Scale Electrical Power Generation from Heat Co-Produced in Geothermal Fluids: Mining Operation

    SciTech Connect

    Clark, Thomas M; Erlach, Celeste

    2014-12-30

    Demonstrate the technical and economic feasibility of small scale power generation from low temperature co-produced fluids. Phase I is to Develop, Design and Test an economically feasible low temperature ORC solution to generate power from lower temperature co-produced geothermal fluids. Phase II &III are to fabricate, test and site a fully operational demonstrator unit on a gold mine working site and operate, remotely monitor and collect data per the DOE recommended data package for one year.

  9. Solar gasification of coal, activated carbon, coke and coal and biomass mixtures

    NASA Astrophysics Data System (ADS)

    Gregg, D. W.; Taylor, R. W.; Campbell, J. H.; Taylor, J. R.; Cotton, A.

    1980-01-01

    The gasification of subbituminous coal, activated carbon, coke and a mixture of coal and biomass by direct solar irradiation in a solar furnace is investigated. Sunlight concentrated by a 23-kW solar furnace was focused directly on the fuel being gasified in a gravity-fed gasifier through a window in the reactor, and steam or CO2 was passed through the bed to react with the fuel and form a combustible product gas. Experiments performed with coal and steam resulted in the conversion of more than 40% of the sunlight arriving at the reactor focus into chemical fuel, with production rate increasing with solar power and product gas composition and thus gas heating value remaining constant. A typical moisture-free gas composition obtained consists of 54% H2, 25% CO, 16% CO2, 4% CH4 and 1% higher hydrocarbons. Experiments with activated carbon and a uniform mixture of coal and biomass resulted in similar conversion efficiencies but slightly different product gas compositions, while coke showed a lower efficiency. Advantages of solar gasification over conventional oxygen-blown gasifiers are indicated.

  10. Association of HSP70 and genotoxic damage in lymphocytes of workers exposed to coke-oven emission

    PubMed Central

    Xiao, Chengfeng; Chen, Sheng; Li, Jizhao; Hai, Tao; Lu, Qiaofa; Sun, Enling; Wang, Ruibo; Tanguay, Robert M.; Wu, Tangchun

    2002-01-01

    Heat shock proteins (Hsps) have been reported to protect cells, tissues, and organisms against damage from a wide variety of stressful stimuli. Whether they protect against deoxyribonucleic acid (DNA) damage in individuals exposed to environmental stresses and chemical carcinogens is unknown. In the study, we investigated the association between Hsp70 levels (the most abundant mammalian Hsp) and genotoxic damage in lymphocytes of workers exposed to coke-oven emission using Western dot blot and 2 DNA damage assays, the comet assay and the micronucleus test. The data show that there is a significant increase in Hsp70 levels, DNA damage score, and micronucleus rates in lymphocytes of workers exposed to coke-oven emission as compared with the control subjects. Furthermore, there was a significant negative correlation of Hsp70 levels with DNA damage scores in the comet assay (r = −0.663, P < 0.01) and with micronucleus rates (r = −0.461, P < 0.01) in the exposed group. In the control group, there was also a light negative correlation between Hsp70 with DNA damage and micronuclei rate (r = −0.236 and r = 0.242, respectively), but it did not reach a statistically significant level (P > 0.05). Our results show that individuals who had high Hsp70 levels generally showed lower genotoxic damage than others. These results suggest a role of Hsp70 in the protection of DNA from genotoxic damage induced by coke-oven emission. PMID:12653484

  11. Mortality in retired coke oven plant workers.

    PubMed Central

    Chau, N; Bertrand, J P; Mur, J M; Figueredo, A; Patris, A; Moulin, J J; Pham, Q T

    1993-01-01

    A previous study on 536 retired coke oven plant workers in Lorraine Collieries (France) reported an excess of deaths from lung cancer (standardised mortality ratio (SMR) = 251) compared with the French male population. Occupational exposures during working life were retraced for each subject, but the number of deaths during the observation period (1963-82) was small, and smoking habits were known only for dead subjects. In 1988, the cohort was re-examined (182 deaths occurred between 1963 and 1987) and smoking habits were determined for all the subjects. This study confirmed the excess of lung cancer (SMR = 238, p < 0.001). It showed an excess of mortality from all causes (SMR = 141, p < 0.001), overall cancers (SMR = 133, p < 0.05), and cardiovascular diseases (SMR = 133, p < 0.05). A significant excess of deaths was found for subjects who worked near the ovens for all causes (145, p < 0.01), lung cancer (SMR = 252, p < 0.01), colon cancer (SMR = 381, p < 0.05), and cardiovascular diseases (SMR = 155, p < 0.05). A significant excess mortality was also found from all causes (176, p < 0.05) and stomach cancer (SMR = 538, p < 0.01) in subjects who worked in byproducts, from lung cancer (SMR = 433, p < 0.001) in those in the workshops, and from cirrhosis of the liver and alcoholism (SMR = 360, p < 0.01) in those underground; but, due to small numbers, these figures were not robust. An excess of mortality from all causes (SMR = 163, p<001), lung cancer (SMR = 228, p<0.05) and cardiovascular diseases (SMR = 179, p<0.01) was shown also for non-exposed or slightly exposed subjects. The fact that, on the whole, mortality of various exposed groups was similar to that of non-exposed or slightly exposed workers may be explained in part by the selection at hiring and the healthy worker effect. As an increased risk of lung cancer was noted among subjects who worked in the old generations of plant compared with the other workers (although the relative risk was not significant

  12. Genetic damage induced by organic extract of coke oven emissions on human bronchial epithelial cells.

    PubMed

    Zhai, Qingfeng; Duan, Huawei; Wang, Yadong; Huang, Chuanfeng; Niu, Yong; Dai, Yufei; Bin, Ping; Liu, Qingjun; Chen, Wen; Ma, Junxiang; Zheng, Yuxin

    2012-08-01

    Coke oven emissions are known as human carcinogen, which is a complex mixture of polycyclic aromatic hydrocarbon. In this study, we aimed to clarify the mechanism of action of coke oven emissions induced carcinogenesis and to identify biomarkers of early biological effects in a human bronchial epithelial cell line with CYP1A1 activity (HBE-CYP1A1). Particulate matter was collected in the oven area on glass filter, extracted and analyzed by GC/MS. DNA breaks and oxidative damage were evaluated by alkaline and endonucleases (FPG, hOGG1 and ENDO III)-modified comet assays. Cytotoxicity and chromosomal damage were assessed by the cytokinesis-block micronucleus cytome (CBMN-Cyt) assay. The cells were treated with organic extract of coke oven emissions (OE-COE) representing 5, 10, 20, 40μg/mL extract for 24h. We found that there was a dose-effect relationship between the OE-COE and the direct DNA damage presented by tail length, tail intensity and Olive tail moment in the comet assay. The presence of lesion-specific endonucleases in the assays increased DNA migration after OE-COE treatment when compared to those without enzymes, which indicated that OE-COE produced oxidative damage at the level of pyrimidine and purine bases. The dose-dependent increase of micronuclei, nucleoplasmic bridges and nuclear buds in exposed cells was significant, indicating chromosomal and genomic damage induced by OE-COE. Based on the cytotoxic biomarkers in CBMN-Cyt assay, OE-COE may inhibit nuclear division, interfere with apoptosis, or induce cell necrosis. This study indicates that OE-COE exposure can induce DNA breaks/oxidative damage and genomic instability in HBE-CYP1A1 cells. The FPG-comet assay appears more specific for detecting oxidative DNA damage induced by complex mixtures of genotoxic substances. PMID:22522113

  13. Petroleum coke and soft tailings sediment in constructed wetlands may contribute to the uptake of trace metals by algae and aquatic invertebrates.

    PubMed

    Baker, Leanne F; Ciborowski, Jan J H; MacKinnon, Michael D

    2012-01-01

    The fate of trace metals in pore water collected from wetland sediments and organisms exposed to petroleum coke were evaluated within in situ aquatic microcosms. Oil sands operators of Fort McMurray, Alberta, Canada produced 60 million tonnes of petroleum coke by 2008, containing elevated concentrations of sulphur and several trace metals commonly seen in oil sands materials. This material may be included in the construction of reclaimed wetlands. Microcosms were filled with a surface layer of petroleum coke over mine-waste sediments and embedded in a constructed wetland for three years to determine how these materials would affect the metal concentrations in the sediment pore water, colonizing wetland plants and benthic invertebrates. Petroleum coke treatments produced significantly elevated levels of Ni. We also found unexpectedly higher concentrations of metals in "consolidated tailings" waste materials, potentially due to the use of oil sands-produced gypsum, and higher background concentration of elements in the sediment used in the controls. A trend of higher concentrations of V, Ni, La, and Y was present in the tissues of the colonizing macrophytic alga Chara spp. Aeshnid dragonflies may also be accumulating V. These results indicate that the trace metals present in some oil sands waste materials could be taken up by aquatic macro-algae and some wetland invertebrates if these materials are included in reclaimed wetlands. PMID:22119033

  14. Processes forming Gas, Tar, and Coke in Cellulose Gasification from Gas-Phase Reactions of Levoglucosan as Intermediate.

    PubMed

    Fukutome, Asuka; Kawamoto, Haruo; Saka, Shiro

    2015-07-01

    The gas-phase pyrolysis of levoglucosan (LG), the major intermediate species during cellulose gasification, was studied experimentally over the temperature range of 400-900 °C. Gaseous LG did not produce any dehydration products, which include coke, furans, and aromatic substances, although these are characteristic products of the pyrolysis of molten LG. Alternatively, at >500 °C, gaseous LG produced only fragmentation products, such as noncondensable gases and condensable C1 -C3 fragments, as intermediates during noncondensable gas formation. Therefore, it was determined that secondary reactions of gaseous LG can result in the clean (tar- and coke-free) gasification of cellulose. Cooling of the remaining LG in the gas phase caused coke formation by the transition of the LG to the molten state. The molecular mechanisms that govern the gas- and molten-phase reactions of LG are discussed in terms of the acid catalyst effect of intermolecular hydrogen bonding to promote the molten-phase dehydration reactions. PMID:26099988

  15. Heat resistance in extended-spectrum beta-lactamase-producing Escherichia coli may favor environmental survival in a hospital setting.

    PubMed

    Boll, Erik J; Frimodt-Møller, Jakob; Olesen, Bente; Krogfelt, Karen A; Struve, Carsten

    2016-06-01

    Nosocomial infections caused by extended-spectrum β-lactamase (ESBL)-producing Escherichia coli are a major concern worldwide. There is an urgent need to identify bacterial factors promoting survival and persistence of these organisms in the nosocomial environment. Here, we describe the presence of a gene cluster, containing the Clp ATPase ClpK, within a collection of Danish ESBL-producing E. coli isolates. The cluster conferred thermoprotection upon the isolates, and thus might facilitate survival on medical devices exposed to semi-high temperatures in a hospital setting. PMID:26946311

  16. Effect of Reservoir-Caprock Interface Dip and Circulation of Produced Fluid on CO2-Based Geothermal Heat Extraction from Saline Aquifers

    NASA Astrophysics Data System (ADS)

    Garapati, N.; Randolph, J.; Saar, M. O.

    2014-12-01

    CO2-Plume Geothermal (CPG) energy utilization involves injection of CO2 as a working fluid to extract heat from naturally high permeability geologic units. The injected CO2 forms a large subsurface CO2 plume that absorbs heat from the geothermal reservoir and eventually buoyantly rises to the surface. The CO2 plume can be "tapped" for thermal and/or electric power production in a geothermal power system. In actual systems, the CO2 plume would likely be skewed opposite any likely dip direction of the reservoir-caprock interface. Here, we numerically analyze the characteristics of CO2 plume formation and geothermal heat extraction from geothermal reservoirs with dip. We find that the heat extraction rate and the total amount of heat extracted over time is the same for symmetric and skewed CO2 plume systems when the circular, horizontal production well is arranged according to the CO2 plume distribution around the injection well. We also conduct simulations of CO2 plume formation within a pre-existing groundwater flow field and find that groundwater flow is not capable of skewing the CO2 plume. Furthermore, we investigate the effects of reinjecting small amounts of brine that are produced with the CO2. Brine has a smaller mobility than supercritical CO2 at a given temperature and thus accumulates near the injection well. Such brine accumulation reduces the relative permeability for the CO2 phase, which in turn increases the pore-fluid pressure around the injection well. For this reason, and as injection of two fluid phases is problematic, we recommend removal of any brine from the produced fluid before the cooled CO2 is reinjected into the reservoir. Separated brine may be reinjected into the formation away from the CO2 plume, providing an additional means of controlling and directing the CO2 plume pressure field and flow direction and avoiding the need to treat and dispose of the CO2 near the land surface. In summary, we show that the geothermal heat extraction

  17. Theoretical and experimental foundations for preparing coke for blast-furnace smelting

    SciTech Connect

    A.L. Podkorytov; A.M. Kuznetsov; E.N. Dymchenko; V.P. Padalka; S.L. Yaroshevskii; A.V. Kuzin

    2009-05-15

    This article examines the preparation of coke for blast-furnace smelting by a method that most fully meets the requirements of blast-furnace technology: screening of the -36 mm fraction, the separation of nut coke of the 15-36 mm fraction, and its charging into the furnace in a mixture with the iron-ore-bearing charge components. An analysis is made of trial use of coke of the Premium class on blast furnace No. 5 at the Enakievo Metallurgical Plant. Use of this coke makes it possible to reduce the consumption of skip coke by 3.2-4.1%.

  18. Properties of spent active coke particles analysed via comminution in spouted bed.

    PubMed

    Buczek, Bronislaw

    2013-01-01

    Samples of active coke, fresh and spent after cleaning flue gases from communal waste incinerators, were investigated. The outer layers of both coke particles were separately removed by comminution in a spouted bed. The samples of both active cokes were analysed by means of densities, mercury porosimetry, and adsorption technique. Remaining cores were examined to determine the degree of consumption of coke by the sorption of hazardous emissions (SO2, HCl, and heavy metals) through its bed. Differences in contamination levels within the porous structure of the particles were estimated. The study demonstrated the effectiveness of commercial active coke in the cleaning of flue gases. PMID:24459454

  19. Properties of Spent Active Coke Particles Analysed via Comminution in Spouted Bed

    PubMed Central

    Buczek, Bronislaw

    2013-01-01

    Samples of active coke, fresh and spent after cleaning flue gases from communal waste incinerators, were investigated. The outer layers of both coke particles were separately removed by comminution in a spouted bed. The samples of both active cokes were analysed by means of densities, mercury porosimetry, and adsorption technique. Remaining cores were examined to determine the degree of consumption of coke by the sorption of hazardous emissions (SO2, HCl, and heavy metals) through its bed. Differences in contamination levels within the porous structure of the particles were estimated. The study demonstrated the effectiveness of commercial active coke in the cleaning of flue gases. PMID:24459454

  20. Application research on hydraulic coke cutting monitoring system based on optical fiber sensing technology

    NASA Astrophysics Data System (ADS)

    Zhong, Dong; Tong, Xinglin

    2014-06-01

    With the development of the optical fiber sensing technology, the acoustic emission sensor has become one of the focal research topics. On the basis of studying the traditional hydraulic coke cutting monitoring system, the optical fiber acoustic emission sensor has been applied in the hydraulic coke cutting monitoring system for the first time, researching the monitoring signal of the optical fiber acoustic emission sensor in the system. The actual test results show that using the acoustic emission sensor in the hydraulic coke cutting monitoring system can get the real-time and accurate hydraulic coke cutting state and the effective realization of hydraulic coke cutting automatic monitoring in the Wuhan Branch of Sinopec.

  1. Material Characterization of Austempered Ductile Iron (ADI) Produced by a Sustainable Continuous Casting-Heat Treatment Process

    NASA Astrophysics Data System (ADS)

    Meena, Anil; El Mansori, Mohamed

    2012-12-01

    Selecting a suitable manufacturing process is one way of achieving sustainability of a product by diminishing energy consumption during its production cycle and improving material efficiency. The article attempts to explore the new processing technology for direct manufacturing of lightweight austempered ductile iron (ADI) casting in a permanent mold. The new processing technology is based on the innovative integrated approach toward casting and heat-treatment process. In this technology, the ductile iron samples obtained using the permanent mold are first austenized immediately after solidification process followed by austempering heat treatment in the fluidized bed and then air cooled at room temperature to obtain ADI material. The influence of austempering time on the microstructural characteristics, mechanical properties, and strain-hardening behavior of ADI was studied. Optical microscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) analyses were performed to correlate the mechanical properties with microstructural characteristics. It was observed that the mechanical properties of resulting ADI samples were influenced by the microstructural transformations and varied retained austenite volume fractions obtained due to different austempering time. The results indicate that the strain-hardening behavior of the ADI material is influenced by the carbon content of retained austenite.

  2. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  3. ENVIRONMENTAL ASSESSMENT OF COKE BY-PRODUCT RECOVERY PLANTS

    EPA Science Inventory

    The report gives results of an initial screening study, initiating a multimedia environmental assessment of coke by-product recovery plants in the U.S. The study included both the gathering and analysis of existing data and sampling and analysis at one plant based on EPA's Indust...

  4. Coke quality for blast furnaces with coal-dust fuel

    SciTech Connect

    Y.A. Zolotukhin; N.S. Andreichikov

    2009-07-01

    Recently, plans have been developed for the introduction of pulverized coal injection (PCI) at various Russian metallurgical enterprises. The main incentive for switching to PCI is the recent price rises for Russian natural gas. The paper discusses the quality of coke for PCI into blast furnaces.

  5. Coke Reactivity in Simulated Blast Furnace Shaft Conditions

    NASA Astrophysics Data System (ADS)

    Haapakangas, Juho; Suopajärvi, Hannu; Iljana, Mikko; Kemppainen, Antti; Mattila, Olli; Heikkinen, Eetu-Pekka; Samuelsson, Caisa; Fabritius, Timo

    2016-08-01

    Despite the fact that H2 and H2O are always present in the gas atmosphere of a blast furnace shaft, their role in the solution-loss reactions of coke has not been thoroughly examined. This study focuses on how H2 and H2O affect the reaction behavior and whether a strong correlation can be found between reactivity in the conditions of the CRI test (Coke Reactivity Index) and various simulated blast furnace shaft gas atmospheres. Partial replacement of CO/CO2 with H2/H2O was found to significantly increase the reactivity of all seven coke grades at 1373 K (1100 °C). H2 and H2O, however, did not have a significant effect on the threshold temperature of gasification. The reactivity increasing effect was found to be temperature dependent and clearly at its highest at 1373 K (1100 °C). Mathematical models were used to calculate activation energies for the gasification, which were notably lower for H2O gasification compared to CO2 indicating the higher reactivity of H2O. The reactivity results in gas atmospheres with CO2 as the sole gasifying component did not directly correlate with reactivity results in gases also including H2O, which suggests that the widely used CRI test is not entirely accurate for estimating coke reactivity in the blast furnace.

  6. 29 CFR 1926.1129 - Coke oven emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Coke oven emissions. 1926.1129 Section 1926.1129 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... oven emissions. Note: The requirements applicable to construction work under this section are...

  7. 29 CFR 1926.1129 - Coke oven emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 29 Labor 8 2011-07-01 2011-07-01 false Coke oven emissions. 1926.1129 Section 1926.1129 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR... oven emissions. Note: The requirements applicable to construction work under this section are...

  8. RESIDUAL RISK ASSESSMENTS - RESIDUAL RISK ASSESSMENT FOR COKE OVENS

    EPA Science Inventory

    This source category previously subjected to a technology-based standard will be examined to determine if health or ecological risks are significant enough to warrant further regulation for Coke Ovens. These assesments utilize existing models and data bases to examine the multi-m...

  9. The development of analytical methodologies for characterizing coke oven emissions

    SciTech Connect

    Schreiber, E.M.

    1988-01-01

    Currently, coke oven operators are required by law to monitor worker's exposure to coke oven emissions for coal tar pitch volatiles (CTPV) by measuring the benzene soluble fraction of particulates. However, it is not universally accepted that CTPV are a good measure of health effects. Consequently, better methods for analyzing coke oven emissions that relate to worker's health is needed. Sampling apparatus designed to measure particulates and vapor organics, employing high volume (hi-vol) pumps and personal pumps were field tested. The analytical scheme developed was more efficient in extracting PAHs than the benzene soluble fraction method. Both filter and florisil plugs were extracted with methylene chloride using an ultrasonic bath. The extract volumes were reduced and solvent exchanged with iso-octane in a Kuderna-Danish (KD) apparatus and analyzed by gas chromatography. Qualitative analysis was performed using a gas chromatograph (GC)/flame ionization detector (FID) and GC/mass spectrometer. A total of 68 compounds were identified. Sixteen PAHs selected were selected for quantitative analysis and their concentrations ranged from 0.02 ug/m{sup 3} to 5100 ug/m{sup 3}. The relative concentrations of the PAHs were compared with other processes in which PAHs are emitted, such as paving and roofing operations and were found to be unique enough that finger printing coke oven emissions may be possible.

  10. Using the undersizes of Karaganda coals in coking charges

    SciTech Connect

    Muzychuk, V.D.; Chernyak, Yu.B.; Khegai, U.; Tyrchenkova, L.M.; Vasyuchkov, E.I.; Vlasova, Z.A.

    1984-01-01

    The requirements for coking coals have increased considerably in the Karaganda basin in connection with starting up the Vostochaya Central Concentrating Mill and coal treatment plant No. 2 of the Karaganda Metallurgical Complex, as well as in connection with the increase in the use of Karaganda coking coals which has taken place at the plants in the Ural and Ukraine regions. The problem of expanding the source of raw materials is of current interest due to the involvement of Karaganda coals with a high ash content in the charge. In this connection, undersizes of the fine classes of Karaganda coals presently used to meet energy needs are of considerable interest. This paper discusses how an undersize of types K and K2 Karaganda coals can be used in determined amounts in the coking charges of the Karaganda Metallurgical Complex. When the amount of type KZh coals in a charges is decreased (less than or equal to 50%), the percentage of coal undersizes from the Karaganda mine must be no more than 5% due to their inferior agglutinating power. When the content of type KZh coal is 55% or more, the percentage of coal undersizes from the Karaganda mine can be increased to 7%. Coal undersizes from the 50th Anniversary of the October Revolution mine possess a higher agglutinating power than those from the Karaganda mine. However, it is not advisable to feed them into a coking charge in an amount surpassing 5% at the present time due to the higher ash content.

  11. EVALUATION OF THE POTENTIAL CARCINOGENICITY OF COKE OVEN EMISSIONS

    EPA Science Inventory

    Coke oven emissions are known human carcinogens, classified as weight-of-evidence Group A under the EPA Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1986a). vidence on potential carcinogenicity from animal studies is "Sufficient,". and the evidence rom human studies is "S...

  12. ENVIRONMENTAL ASSESSMENT OF DRY COKE QUENCHING VS. CONTINUOUS WET QUENCHING

    EPA Science Inventory

    The report gives results of an assessment of the multimedia environmental impacts of continuous wet and dry quenching at National Steel's Weirton, West Virginia, Brown's Island coke plant. The report, based primarily on design data, test data from related processes, and engineeri...

  13. 29 CFR 1926.1129 - Coke oven emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 29 Labor 8 2012-07-01 2012-07-01 false Coke oven emissions. 1926.1129 Section 1926.1129 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR (CONTINUED) SAFETY AND HEALTH REGULATIONS FOR CONSTRUCTION Toxic and Hazardous Substances § 1926.1129...

  14. 29 CFR 1926.1129 - Coke oven emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 29 Labor 8 2014-07-01 2014-07-01 false Coke oven emissions. 1926.1129 Section 1926.1129 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR (CONTINUED) SAFETY AND HEALTH REGULATIONS FOR CONSTRUCTION Toxic and Hazardous Substances § 1926.1129...

  15. 29 CFR 1926.1129 - Coke oven emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 29 Labor 8 2013-07-01 2013-07-01 false Coke oven emissions. 1926.1129 Section 1926.1129 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR (CONTINUED) SAFETY AND HEALTH REGULATIONS FOR CONSTRUCTION Toxic and Hazardous Substances § 1926.1129...

  16. 29. Coke oven byproduct building "XX" with ammonia stills; powerhouse ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    29. Coke oven by-product building "XX" with ammonia stills; powerhouse with 8 sisters (stacks) in background; conveyor #20 (with break) on right, pulevrized coal storage bunker on left. Looking north/northwest - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  17. 30. XX byproducts building (containing coke gas compressors at north ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    30. XX by-products building (containing coke gas compressors at north end, ammonia stills in south end), #20 coal conveyor jutting out of top on east side, continuing out west side to bunker. Looking south/southeast - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  18. COKE STORAGE HOPPER LOCATED OUTSIDE THE MALLEABLE FOUNDRY SHOWING LOADING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    COKE STORAGE HOPPER LOCATED OUTSIDE THE MALLEABLE FOUNDRY SHOWING LOADING DEVICE THAT USED A SKIP CAR TO FILL THE HOPPER FROM UNDERGROUND GRAVITY-FED STORAGE AREAS FROM INCOMING RAILROAD CARS. - Stockham Pipe & Fittings Company, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL

  19. Coke Reactivity in Simulated Blast Furnace Shaft Conditions

    NASA Astrophysics Data System (ADS)

    Haapakangas, Juho; Suopajärvi, Hannu; Iljana, Mikko; Kemppainen, Antti; Mattila, Olli; Heikkinen, Eetu-Pekka; Samuelsson, Caisa; Fabritius, Timo

    2016-04-01

    Despite the fact that H2 and H2O are always present in the gas atmosphere of a blast furnace shaft, their role in the solution-loss reactions of coke has not been thoroughly examined. This study focuses on how H2 and H2O affect the reaction behavior and whether a strong correlation can be found between reactivity in the conditions of the CRI test (Coke Reactivity Index) and various simulated blast furnace shaft gas atmospheres. Partial replacement of CO/CO2 with H2/H2O was found to significantly increase the reactivity of all seven coke grades at 1373 K (1100 °C). H2 and H2O, however, did not have a significant effect on the threshold temperature of gasification. The reactivity increasing effect was found to be temperature dependent and clearly at its highest at 1373 K (1100 °C). Mathematical models were used to calculate activation energies for the gasification, which were notably lower for H2O gasification compared to CO2 indicating the higher reactivity of H2O. The reactivity results in gas atmospheres with CO2 as the sole gasifying component did not directly correlate with reactivity results in gases also including H2O, which suggests that the widely used CRI test is not entirely accurate for estimating coke reactivity in the blast furnace.

  20. Advanced oxidation processes with coke plant wastewater treatment.

    PubMed

    Krzywicka, A; Kwarciak-Kozłowska, A

    2014-01-01

    The aim of this study was to determine the most efficient method of coke wastewater treatment. This research examined two processes - advanced oxidation with Fenton and photo-Fenton reaction. It was observed that the use of ultraviolet radiation with Fenton process had a better result in removal of impurities. PMID:24804662

  1. Kinetics of Carbon Dissolution of Coke in Molten Iron

    NASA Astrophysics Data System (ADS)

    Jang, Dongik; Kim, Yumkyum; Shin, Minsoo; Lee, Joonho

    2012-12-01

    The effect of temperature on the dissolution rate of carbon from coke in molten iron was investigated using a sampling technique in the temperature range of 1723 K to 1923 K (1450 °C to 1650 °C). The dissolution rate of carbon from coke in molten iron increased as the temperature increased. At 1923 K (1650 °C), the rate-determining step was the mass transfer of carbon in the boundary layer adjacent to the metal-carbon interface. At 1723 K (1450 °C), the rate-determining step changed from the mass transfer to the interfacial chemical reaction as the reaction proceeded. At 1823 K (1550 °C), both reaction steps affected the apparent reaction rates. Sulfur dissolution did not affect the carbon dissolution rates in molten iron, so it was considered that the sulfur adsorption at the metal/coke interface was not so significant. The apparent activation energy of the carbon dissolution of coke in molten iron was estimated to be 442 kJ/mol.

  2. 19. VIEW OF THE TWO ROWS OF COKE OVENS, LOOKING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. VIEW OF THE TWO ROWS OF COKE OVENS, LOOKING EAST. THE OVENS LIE TO THE EAST OF THE MINE BUILDINGS. BEEHIVE OVENS FORM THE ROW ON THE LEFT OF THE PHOTOGRAPH. THE RECTANGULAR OVENS ARE ON THE RIGHT. - Tower Hill No. 2 Mine, Approximately 0.47 mile Southwest of intersection of Stone Church Road & Township Route 561, Hibbs, Fayette County, PA

  3. CYANIDE REMOVAL FROM COKE MAKING AND BLAST FURNACE WASTE WATERS

    EPA Science Inventory

    The report gives results of a study to determine the feasibility of removing cyanide from coke making and blast furnace waste waters by ion flotation or column precipitate flotation of iron ferrocyanides. Ion flotation was reasonably effective on ferricyanide, but not on cyanide ...

  4. Emission characteristics of heavy metals and their behavior during coking processes.

    PubMed

    Mu, Ling; Peng, Lin; Liu, Xiaofeng; Bai, Huiling; Song, Chongfang; Wang, Ying; Li, Zhen

    2012-06-01

    Besides organic pollutants, coke production generates emissions of toxic heavy metals. However, intensive studies on heavy metal emissions from the coking industry are still very scarce. The current work focuses on assessing the emission characteristics of heavy metals and their behavior during coking. Simultaneous sampling of coal, coke, residues from air pollution control devices (APCD), effluent from coke quenching, and fly ash from different processes before and after APCD has been performed. The total heavy metal concentration in the flue gas from coke pushing (CP) was significantly higher than that from coal charging (CC) and combustion of coke oven gases (CG). Emission factors of heavy metals for CP and CC were 378.692 and 42.783 μg/kg, respectively. During coking, the heavy metals that were contained in the feedstock coal showed different partitioning patterns. For example, Cu, Zn, As, Pb, and Cr were obviously concentrated in the inlet fly ash compared to the coke; among these metals Cu, As, and Cr were concentrated in the outlet fly ash, whereas Zn and Pb were distributed equally between the outlet fly ash and APCD residue. Ni, Co, Cd, Fe, and V were partitioned equally between the inlet fly ash and the coke. Understanding the behavior of heavy metals during coking processes is helpful for the effective control of these heavy metals and the assessment of the potential impact of their emissions on the environment. PMID:22607524

  5. Use of a scale model for coke oven charging practice development

    SciTech Connect

    Case, E.R.; Pendergras, S.T.

    1982-01-01

    A 1/8 scale model coke oven was designed and built for use as a tool to improve coke oven charging practice. Major goals of the program were to increase coke oven productivity and decrease charging emissions. The material used to simulate coal in the model was chosen on the basis of angle of repose. the proper choice of media to simulate the coke oven charge, under a given set of operating conditions, was essential to obtain correspondence between the model and the production oven. Oven profiles were very similar after individual larry car hoppers were dropped and after leveling. Improved coke oven charging practices developed with the coke oven model, in combination with close control by operating personnel, have resulted in increased coke oven charge weights of over 1.0 ton/oven without increased charging emissions.

  6. Formation and catalytic activity of high molecular weight soluble polymers produced by heating amino acids in a modified sea medium

    NASA Astrophysics Data System (ADS)

    Okihana, Hiroyuki

    1982-06-01

    Eighteen protein amino acids with milk casein composition were heated in a modified sea medium. Marigranules were formed in the precipitates and soluble polymers were formed in the supernatant. Time course of the reaction (ultraviolet spectra, the concentration of metal ions, and the concentration of amino acids in the supernatant) were measured. The time course of the formation of the soluble polymers was also studied by Bio-Gel P-2 column. High molecular weight soluble polymers (HMWSP) were separated from low molecular weight ones by dialysis. It was shown that these polymers catalyzed the dehydrogenation of NADH. These polymers also catalyzed the coupled reaction between dehydrogenation of NADH and reduction of resazurin. This coupled reaction was accelerated by the light.

  7. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D.; Dumesic, James A.

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  8. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D.; Dumesic, James A.

    2012-04-10

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  9. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOEpatents

    Cortright, Randy D.; Dumesic, James A.

    2013-04-02

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  10. Advanced treatment of coking wastewater by coagulation and zero-valent iron processes.

    PubMed

    Lai, Peng; Zhao, Hua-zhang; Wang, Chao; Ni, Jin-ren

    2007-08-17

    Advanced treatment of coking wastewater was investigated experimentally with coagulation and zero-valent iron (ZVI) processes. Particular attention was paid to the effect of dosage and pH on the removal of chemical oxygen demand (COD) in the two processes. The results showed that ZVI was more effective than coagulation for advanced treatment of coking wastewater. The jar tests revealed that maximal COD removal efficiency of 27.5-31.8% could be achieved under the optimal condition of coagulation, i.e. 400mg/L of Fe(2)(SO(4))3 as coagulant at pH 3.0-5.0. On the other hand, the COD removal efficiency could be up to 43.6% under the idealized condition of ZVI upon 10 g/L active carbon and 30 g/L iron being dosed at pH 4.0. The mechanisms for COD removal in ZVI were dominated by coagulation, precipitation and oxidation-reduction. ZVI would also enhance the biodegradability of effluent by increasing BOD5/COD from 0.07 to 0.53. Moreover, some ester compounds could be produced in the reaction. Although ZVI was found more efficient than coagulation in eliminating low molecular weight (<2000 Da) compounds in the wastewater, there were still a few residual contaminants which could hardly be eliminated by either of the process. PMID:17267104

  11. Preparation and characterization of bi-metallic nanoparticle catalyst having better anti-coking properties using reverse micelle technique

    NASA Astrophysics Data System (ADS)

    Zacharia, Thomas

    Energy needs are rising on an exponential basis. The mammoth energy sources like coal, natural gas and petroleum are the cause of pollution. The large outcry for an alternate energy source which is environmentally friendly and energy efficient is heard during the past few years. This is where “Clean-Fuel” like hydrogen gained its ground. Hydrogen is mainly produced by steam methane reforming (SMR). An alternate sustainable process which can reduce the cost as well as eliminate the waste products is Tri-reforming. In both these reforming processes nickel is used as catalyst. However as the process goes on the catalyst gets deactivated due to coking on the catalytic surface. This goal of this thesis work was to develop a bi-metallic catalyst which has better anti-coking properties compared to the conventional nickel catalyst. Tin was used to dope nickel. It was found that Ni3Sn complex around a core of Ni is coking resistant compared to pure nickel catalyst. Reverse micelle synthesis of catalyst preparation was used to control the size and shape of catalytic particles. These studies will benefit researches on hydrogen production and catalyst manufactures who work on different bi-metallic combinations.

  12. Mutagenicity studies with urine concentrates from coke plant workers

    SciTech Connect

    Moeller, M.; Dybing, E.

    1980-01-01

    Urine from coke plant workers, collected before and after work, were tested for the content of mutagenic substances in the Salmonella test system. Urine extracts from exposed smokers showed mutagenic activity, whereas urine from exposed nonsmokers did not. The mutagenicity of exposed smoker's urine was not significantly different from that of urine from nonexposed smokers. Mutagenicity of smokers' urine was only evident in the presence of a rat liver metabolic activation system. The addition of beta-glucuronidase did not enhance the mutagenic effect. The facts that coke plant workers are exposed to very high levels of polycyclic aromatic hydrocarbons (PAH) and that there is no observed enhanced mutagenicity of their urine indicate that the mutagenicity observed with urine from smokers is not due to conventional PAH.

  13. New environmental concepts in the chemical and coke industries

    SciTech Connect

    A.Yu. Naletov; V.A. Naletov

    2007-05-15

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  14. The influence of coke source on anode performance

    NASA Astrophysics Data System (ADS)

    Jonville, C.; Thomas, J. C.; Dreyer, C.

    1995-08-01

    The role of anode raw material has long been debated in the aluminum smelting industry. By examining data accumulated from two similar smelting operations of Aluminium Pechiney, this article focuses on the differences in performance of anodes that can be attributed to the raw materials. The results suggest that good anode performance can be obtained for a range of cokes, provided that the operation is well designed and carefully operated.

  15. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  16. Removing particulates from aspiration air during coke dry quenching

    SciTech Connect

    Stefanenko, V.T.; Lysenko, T.v.; Voronkova, T.I.; Gracheva, O.L.

    1983-01-01

    The characteristics of recovery of coke dust are due to the relatively large size of the particles and their highly abrasive nature. The use of wet dust traps is not feasible due to the difficulties arising from the necessity of treating the sludge water. It is feasible to use dry methods of purifying the aspiration air. As dust traps one may recommend type SDK-TsN-33 or SK-TsN-34 conical cyclones, as well as vertical electrofilters.

  17. Composition and method for coke retardant during hydrocarbon processing

    SciTech Connect

    Reid, D.K.

    1988-02-09

    A process is described for inhibiting the formation and deposition of filamentous coke on metallic surfaces in contact with a hydrocarbon having a temperature of 600/sup 0/-1300/sup 0/F which comprises adding to the hydrocarbon a sufficient amount for the purpose of a boron compound selected from the group of boron oxide compounds, boric acid and metal borides, with the proviso that when boric acid is used, it is substantially free of water.

  18. New Surface-Associated Heat-Labile Colonization Factor Antigen (CFA/II) Produced by Enterotoxigenic Escherichia coli of Serogroups O6 and O8

    PubMed Central

    Evans, Dolores G.; Evans, Doyle J.

    1978-01-01

    Enterotoxigenic Escherichia coli (ETEC) belonging to serogroups O6 and O8 do not possess the H-10407-type colonization factor antigen (CFA/I). However, these frequently isolated ETEC were found to possess a second and distinct heat-labile surface-associated colonization factor antigen, termed CFA/II. Whereas CFA/I mediates mannose-resistant hemagglutination of human group A erythrocytes, CFA/II does not. CFA/II mediates mannose-resistant hemagglutination of bovine erythrocytes, and mannose-resistant hemagglutination is rapid only at reduced temperature (4°C). Because CFA/II, like CFA/I, is spontaneously lost by many ETEC isolates in the laboratory, it was possible to produce specific anti-CFA/II serum by preparing antiserum against living cells of a prototype strain (PB-176) and adsorbing this serum with living and heat-treated cells of its CFA/II-negative derivative strain PB-176-P. This serum, which neutralized the colonization factor activity of CFA/II-positive strains in infant rabbits, was employed to confirm the presence of CFA/II on ETEC which exhibited mannose-resistant hemagglutination of bovine but not human erythrocytes. CFA/II, like CFA/I, mediates adherence of the bacteria to the mucosal surface of the small intestine, as demonstrated by indirect immunofluorescence. CFA/II appears to be an important virulence factor for humans since CFA/II-positive ETEC are frequently isolated from diarrhea cases, particularly travelers' diarrhea, in Mexico; these ETEC were not uncommon in a collection of isolates from Bangladesh. The O6:H16 strain of ETEC responsible for an outbreak of diarrhea in the United States was also shown to be CFA/II positive. CFA/I and CFA/II were never found on the same serotypes of ETEC, but 98% of the heat-stable and heat-labile enterotoxin-producing ETEC belonging to the frequently isolated serogroups O6, O8, O15, O25, O63, and O78 were positive for either CFA/I or CFA/II. Images PMID:80383

  19. The History and Future Challenges of Calcined Petroleum Coke Production and Use in Aluminum Smelting

    NASA Astrophysics Data System (ADS)

    Edwards, Les

    2015-02-01

    Calcined petroleum coke is used for the production of carbon anodes in the Hall-Héroult aluminum smelting process due to a combination of low impurity levels, ready availability, and relatively low cost. This article provides a review of the history and use of calcined petroleum coke for anode production and describes the different calcining technologies used by the industry. The article discusses the impact of changes in crude oil quality and refining economics over the last 10 years as well as the impact on green petroleum coke quality and availability. The industry has adapted well to quality changes in recent times, and the blending of different quality cokes by smelters is becoming increasingly important. The world has a plentiful supply of green petroleum coke, but the next wave of aluminum smelting capacity growth will put further pressure on the supply of the higher quality cokes traditionally favored by the industry.

  20. Method and apparatus for processing filling gas from a coke oven battery

    SciTech Connect

    Polenz, J.; Wagner, H.

    1981-08-11

    An improved coke oven battery and an improved method for production of coke and byproducts are provided. The filling gas escaping during the filling of the oven chambers with coal is initially rendered inert by admixing flue gas. Then the resulting gas mixture of filling gas and flue gas is withdrawn via a conduit fed with flushing liquor from the coke oven gas off-take main and is added to the raw coke oven gas after the coke oven gas off-take main. The tar and coal containing flushing liquor coming from the filling gas conduit is fed back to the coke oven gas off-take main after removal of the tar.

  1. An Integrated Model of Coal/Coke Combustion in a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Shen, Y. S.; Guo, B. Y.; Yu, A. B.; Austin, P.; Zulli, P.

    2010-03-01

    A three-dimensional integrated mathematical model of the combustion of pulverized coal and coke is developed. The model is applied to the region of lance-blowpipe-tuyere-raceway-coke bed to simulate the operation of pulverized coal injection in an ironmaking blast furnace. The model integrates two parts: pulverized coal combustion model in the blowpipe-tuyere-raceway-coke bed and the coke combustion model in the coke bed. The model is validated against the measurements in terms of coal burnout and gas composition, respectively. The comprehensive in-furnace phenomena are simulated in the raceway and coke bed, in terms of flow, temperature, gas composition, and coal burning characteristics. In addition, underlying mechanisms for the in-furnace phenomena are analyzed. The model provides a cost-effective tool for understanding and optimizing the in-furnace flow-thermo-chemical characteristics of the PCI process in full-scale blast furnaces.

  2. Influence of metal surface and sulfur addition on coke deposition in the thermal cracking of hydrocarbons

    SciTech Connect

    Reyniers, M.F.S.G.; Froment, G.F.

    1995-03-01

    Coke formation in the thermal cracking of hydrocarbons was studied in a pilot plant unit and in a microreactor with complete mixing of the gas phase, containing a hollow cylinder suspended at the arm of an electrobalance. The morphology of the coke was studied by SEM, while EDX was used to determine the concentration of metals in the coke layer. The influence of the metal surface composition, of it pretreatment, and of the addition of various sulfur compounds on the coking rate and CO production was investigated for condition typical for those in the cracking coil. The CO yield is not a measure of the coking rate. Sulfur compounds are very efficient in reducing the CO yield but promote coke formation.

  3. Wet oxidation of real coke wastewater containing high thiocyanate concentration.

    PubMed

    Oulego, Paula; Collado, Sergio; Garrido, Laura; Laca, Adriana; Rendueles, Manuel; Díaz, Mario

    2014-01-01

    Coke wastewaters, in particular those with high thiocyanate concentrations, represent an important environmental problem because of their very low biodegradability. In this work, the treatment by wet oxidation of real coke wastewaters containing concentrations of thiocyanate above 17 mM has been studied in a 1-L semi-batch reactor at temperatures between 453 and 493 K, with total oxygen pressures in the range of 2.0-8.0 MPa. A positive effect of the matrix of real coke wastewater was observed, resulting in faster thiocyanate degradation than was obtained with synthetic wastewaters. Besides, the effect of oxygen concentration and temperature on thiocyanate wet oxidation was more noticeable in real effluents than in synthetic wastewaters containing only thiocyanate. It was also observed that the degree of mineralization of the matrix organic compounds was higher when the initial thiocyanate concentration increased. Taking into account the experimental data, kinetic models were obtained, and a mechanism implying free radicals was proposed for thiocyanate oxidation in the matrix considered. In all cases, sulphate, carbonates and ammonium were identified as the main reaction products of thiocyanate wet oxidation. PMID:24269931

  4. Improved coke ovens thermal control at Italsider Taranto Works

    SciTech Connect

    Palumbo, L.; Castelli, M.; Gibellieri, E., De Franco, F.; Santis, L.

    1981-01-01

    The right determination of the flue temperatures shifting, according to coke ovens working cycle, has been carried out at Italsider Taranto Works with the cooperation of Centro Sperimentale Metallurgico by using an original method of elaboration and comparison of temperature data collected according to the usual ways by the operators. The results are immediately used for the appropriate control interventions. This technique, after the first experimental application, has been gradually extended to all eleven batteries for a total amount of 485 ovens and it is being used since more than four years. The data are processed out by a 1100 UNIVAC computer to which the access is possible through a remote terminal located in the cokeplant offices. In this way it has been possible to improve the batteries thermal state control with the result of improving considerably the temperatures uniformity both in the transverse and longitudinal axis of the ovens. These positive results had good effects on the stabilization of coke quality, on energy savings and on improvements of working conditions in the coke ovens area. 5 figures, 4 tables.

  5. Copyrolysis of coal and waste plastics under coke-oven gas

    SciTech Connect

    Liao, H.; Li, B.; Zhang, B.

    1998-12-31

    A way for increasing oil and decreasing water (IODW) in copyrolysis of coal with coke-oven gas (COG) by adding waste plastics was suggested and the effects of pressure, heating rate and final temperature on the yields of char, oil and water obtained from copyrolysis of coal and waste plastics under COG were investigated in detail. Copyrolysis of Chinese Xianfeng lignite and waste plastics under COG were carried out in a 10g fixed-bed reactor under pressures of 0.1--3MPa, heating rate from 5--25 K/min and final temperatures of 723--923K. The results indicated that by adding 5% of high-density polyethylene (HDPE), the oil yield increased 4.5% (excluding the oil yield from HDPE pyrolysis) more than that of coal pyrolysis without HDPE, and water decreased about 2.2%. The yields of increased oil and decreased water accounted for 21.2% and 13% of Xianfeng lignite pyrolysis alone, respectively. With increasing pressure and final temperature, the total conversion, oil yields and water increased in varying degrees. Decreasing heating rate is beneficial to improve oil yield and reduce water. Adding waste plastics in copyrolysis of coal with COG not only improves the economic interest but also creates a way for high effective treatment of waste plastics.

  6. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution

    PubMed Central

    Neagu, Dragos; Oh, Tae-Sik; Miller, David N.; Ménard, Hervé; Bukhari, Syed M.; Gamble, Stephen R.; Gorte, Raymond J.; Vohs, John M.; Irvine, John T.S.

    2015-01-01

    Metal particles supported on oxide surfaces are used as catalysts for a wide variety of processes in the chemical and energy conversion industries. For catalytic applications, metal particles are generally formed on an oxide support by physical or chemical deposition, or less commonly by exsolution from it. Although fundamentally different, both methods might be assumed to produce morphologically and functionally similar particles. Here we show that unlike nickel particles deposited on perovskite oxides, exsolved analogues are socketed into the parent perovskite, leading to enhanced stability and a significant decrease in the propensity for hydrocarbon coking, indicative of a stronger metal–oxide interface. In addition, we reveal key surface effects and defect interactions critical for future design of exsolution-based perovskite materials for catalytic and other functionalities. This study provides a new dimension for tailoring particle–substrate interactions in the context of increasing interest for emergent interfacial phenomena. PMID:26360910

  7. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution.

    PubMed

    Neagu, Dragos; Oh, Tae-Sik; Miller, David N; Ménard, Hervé; Bukhari, Syed M; Gamble, Stephen R; Gorte, Raymond J; Vohs, John M; Irvine, John T S

    2015-01-01

    Metal particles supported on oxide surfaces are used as catalysts for a wide variety of processes in the chemical and energy conversion industries. For catalytic applications, metal particles are generally formed on an oxide support by physical or chemical deposition, or less commonly by exsolution from it. Although fundamentally different, both methods might be assumed to produce morphologically and functionally similar particles. Here we show that unlike nickel particles deposited on perovskite oxides, exsolved analogues are socketed into the parent perovskite, leading to enhanced stability and a significant decrease in the propensity for hydrocarbon coking, indicative of a stronger metal-oxide interface. In addition, we reveal key surface effects and defect interactions critical for future design of exsolution-based perovskite materials for catalytic and other functionalities. This study provides a new dimension for tailoring particle-substrate interactions in the context of increasing interest for emergent interfacial phenomena. PMID:26360910

  8. Mössbauer analysis of coal coke samples from Samacá, Boyacá, Colombia

    NASA Astrophysics Data System (ADS)

    Pacheco Serrano, W. A.; Quintão Lima, D.; Fabris, J. D.

    2014-01-01

    Three samples of coke produced from coal from a mine in the municipality of Samacá, department of Boyacá, Colombia, were studied essentially with Mössbauer spectroscopy. The samples were treated with NaOH 5 mol L - 1 in order to increase the proportion of iron oxides, by selectively dissolving silicate minerals and any remaining gibbsite, before the physical analysis. Room temperature Mössbauer data revealed that all samples do contain major proportions (>50 % of the relative subspectral area) of hematite along with (super) paramagnetic species as iron-bearing chemical compounds. The superparamagnetic contribution may be due to very fine grains of iron oxides, including nanometric hematite.

  9. Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution

    NASA Astrophysics Data System (ADS)

    Neagu, Dragos; Oh, Tae-Sik; Miller, David N.; Ménard, Hervé; Bukhari, Syed M.; Gamble, Stephen R.; Gorte, Raymond J.; Vohs, John M.; Irvine, John T. S.

    2015-09-01

    Metal particles supported on oxide surfaces are used as catalysts for a wide variety of processes in the chemical and energy conversion industries. For catalytic applications, metal particles are generally formed on an oxide support by physical or chemical deposition, or less commonly by exsolution from it. Although fundamentally different, both methods might be assumed to produce morphologically and functionally similar particles. Here we show that unlike nickel particles deposited on perovskite oxides, exsolved analogues are socketed into the parent perovskite, leading to enhanced stability and a significant decrease in the propensity for hydrocarbon coking, indicative of a stronger metal-oxide interface. In addition, we reveal key surface effects and defect interactions critical for future design of exsolution-based perovskite materials for catalytic and other functionalities. This study provides a new dimension for tailoring particle-substrate interactions in the context of increasing interest for emergent interfacial phenomena.

  10. Integration of stripping of fines slurry in a coking and gasification process

    DOEpatents

    DeGeorge, Charles W.

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  11. Graphitization of Coke and Its Interaction with Slag in the Hearth of a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Li, Kejiang; Zhang, Jianliang; Liu, Yanxiang; Barati, Mansoor; Liu, Zhengjian; Zhong, Jianbo; Su, Buxin; Wei, Mengfang; Wang, Guangwei; Yang, Tianjun

    2016-04-01

    Coke reaction behavior in the blast furnace hearth has yet to be fully understood due to limited access to the high temperature zone. The graphitization of coke and its interaction with slag in the hearth of blast furnace were investigated with samples obtained from the center of the deadman of a blast furnace during its overhaul period. All hearth coke samples from fines to lumps were confirmed to be highly graphitized, and the graphitization of coke in the high temperature zone was convinced to start from the coke surface and lead to the formation of coke fines. It will be essential to perform further comprehensive investigations on graphite formation and its evolution in a coke as well as its multi-effect on blast furnace performance. The porous hearth cokes were found to be filled up with final slag. Further research is required about the capability of coke to fill final slag and the attack of final slag on the hearth bottom refractories since this might be a new degradation mechanism of refractories located in the hearth bottom.

  12. CO₂ carbonation under aqueous conditions using petroleum coke combustion fly ash.

    PubMed

    González, A; Moreno, N; Navia, R

    2014-12-01

    Fly ash from petroleum coke combustion was evaluated for CO2 capture in aqueous medium. Moreover the carbonation efficiency based on different methodologies and the kinetic parameters of the process were determined. The results show that petroleum coke fly ash achieved a CO2 capture yield of 21% at the experimental conditions of 12 g L(-1), 363°K without stirring. The carbonation efficiency by petroleum coke fly ash based on reactive calcium species was within carbonation efficiencies reported by several authors. In addition, carbonation by petroleum coke fly ash follows a pseudo-second order kinetic model. PMID:25000300

  13. Rapid assessment of bovine spongiform encephalopathy prion inactivation by heat treatment in yellow grease produced in the industrial manufacturing process of meat and bone meals

    PubMed Central

    2013-01-01

    Background Prions, infectious agents associated with transmissible spongiform encephalopathy, are primarily composed of the misfolded and pathogenic form (PrPSc) of the host-encoded prion protein. Because PrPSc retains infectivity after undergoing routine sterilizing processes, the cause of bovine spongiform encephalopathy (BSE) outbreaks are suspected to be feeding cattle meat and bone meals (MBMs) contaminated with the prion. To assess the validity of prion inactivation by heat treatment in yellow grease, which is produced in the industrial manufacturing process of MBMs, we pooled, homogenized, and heat treated the spinal cords of BSE-infected cows under various experimental conditions. Results Prion inactivation was analyzed quantitatively in terms of the infectivity and PrPSc of the treated samples. Following treatment at 140°C for 1 h, infectivity was reduced to 1/35 of that of the untreated samples. Treatment at 180°C for 3 h was required to reduce infectivity. However, PrPSc was detected in all heat-treated samples by using the protein misfolding cyclic amplification (PMCA) technique, which amplifies PrPScin vitro. Quantitative analysis of the inactivation efficiency of BSE PrPSc was possible with the introduction of the PMCA50, which is the dilution ratio of 10% homogenate needed to yield 50% positivity for PrPSc in amplified samples. Conclusions Log PMCA50 exhibited a strong linear correlation with the transmission rate in the bioassay; infectivity was no longer detected when the log PMCA50 of the inoculated sample was reduced to 1.75. The quantitative PMCA assay may be useful for safety evaluation for recycling and effective utilization of MBMs as an organic resource. PMID:23835086

  14. Utilizing coking plant wastes for briquetting of sponge iron. [Magnitogorsk Integrated Iron and Steel Works-USSR

    SciTech Connect

    Letimin, V.N.; Aleksandrov, G.S.; Smetanina, E.K.; Syrovegina, R.I.; Shubin, A.F.; Andreev, L.M.; Anikin, G.Ya.

    1981-01-01

    Of all the carbon-containing coking industry wastes, the one most fully meeting the requirements for briquetting of sponge iron is heavy tar products. These wastes have a good binder capacity, are plentiful, are neutral with regard to sponge iron, and have a relatively low sulfur content. A plant has been modified for the use of the heavy tar products as a binder in the sponge iron briquettes. The capital investment is modest and the briquettes produced are of higher strength and quality than those compacted without a binder. 1 figure, 2 tables.

  15. Mechanical Strength and Failure Characteristics of Cast Mg-9 pctAl-1 pctZn Alloys Produced by a Heated-Mold Continuous Casting Process: Tensile Properties

    NASA Astrophysics Data System (ADS)

    Okayasu, Mitsuhiro; Takeuchi, Shuhei; Ohfuji, Hiroaki

    2014-11-01

    The mechanical properties and failure characteristics of a cast Mg alloy (AZ91: Mg-Al8.9-Zn0.6-Mn0.2) produced by a heated-mold continuous casting process (HMC) are investigated. In a modification of the original HMC process, the cooling of the liquid alloy by direct water spray is carried out in an atmosphere of high-purity argon gas. The HMC-AZ91 alloy exhibits excellent mechanical properties (high strength and high ductility) that are about twice as high as those for the same alloy produced by conventional gravity casting. The increased material strength and ductility of the HMC sample are attributed to nanoscale and microscale microstructural characteristics. The fine grains and tiny spherical eutectic structures ( e.g., Mg17Al12 and Al6Mn) distributed randomly in the matrix of the HMC alloy result in resistance to dislocation movement, leading to high tensile strength. Basal slip on (0001) planes in the relatively organized crystal orientation of the HMC alloy, as well as grain boundary sliding through tiny spherical eutectic structures, results in high ductility. Details of the failure mechanism under static loading in the HMC alloy are also discussed using failure models.

  16. Microwave-assisted ultraviolet digestion of petroleum coke for the simultaneous determination of nickel, vanadium and sulfur by ICP-OES.

    PubMed

    Oliveira, Jussiane S S; Picoloto, Rochele S; Bizzi, Cezar A; Mello, Paola A; Barin, Juliano S; Flores, Erico M M

    2015-11-01

    A method for the simultaneous determination of Ni, V and S in petroleum coke by inductively coupled plasma optical emission spectrometry (ICP-OES) after microwave-assisted ultraviolet digestion (MW-UV) in closed vessels was proposed. Digestion was performed using electrodeless discharge lamps positioned inside quartz vessels and turned on by microwave radiation. The following parameters were evaluated: HNO3 concentration (15 mL of 1, 4, 7, 10 or 14.4 mol L(-1)), volume of H2O2 (30%, 1 or 3 mL), sample mass (100, 250 or 500 mg) and heating time (40 or 60 min) with or without the use of UV lamps. Digestion efficiency was evaluated by the determination of the residual carbon content (RCC) in digests. Using UV lamps lower RCC was obtained and the combination of 4 mol L(-1) HNO3 with 3 mL of H2O2 and 60 min of heating allowed a suitable digestion of up to 500 mg of petroleum coke (RCC< 21%). The agreement with the reference values for Ni, V and S (obtained by digestion of petroleum coke by microwave-induced combustion) and with a certified reference material of petroleum coke was between 96 and 101%. The proposed method was considered as advantageous when compared to American Society for Testing and Materials method because it allowed the simultaneous determination of Ni, V and S with lower limit of detection (0.22, 0.12 and 8.7 µg g(-1) for Ni, V and S, respectively) avoiding the use of concentrated nitric acid and providing digests suitable for routine analysis by ICP-OES. PMID:26452926

  17. Effects of Coke Calcination Level on Pore Structure in Carbon Anodes

    NASA Astrophysics Data System (ADS)

    Fang, Ning; Xue, Jilai; Lang, Guanghui; Bao, Chongai; Gao, Shoulei

    2016-02-01

    Effects of coke calcination levels on pore structure of carbon anodes have been investigated. Bench anodes were prepared by 3 types of cokes with 4 calcination temperatures (800°C, 900°C, 1000°C and 1100°C). The cokes and anodes were characterized using hydrostatic method, air permeability determination, mercury porosimetry, image analysis and confocal microscopy (CSLM). The cokes with different calcination levels are almost the same in LC values (19-20 Å) and real density (1.967-1.985 g/cm3), while the anode containing coke calcined at 900°C has the lowest open porosity and air permeability. Pore size distribution (represented by Anode H sample) can be roughly divided into two ranges: small and medium pores in diameter of 10-400 μm and large pores of 400-580 μm. For the anode containing coke calcined at 800°C, a number of long, narrow pores in the pore size range of 400-580 μm are presented among cokes particles. Formation of these elongated pores may be attributed to coke shrinkages during the anode baking process, which may develop cracking in the anode under cell operations. More small or medium rounded pores with pore size range of 10-400 μm emerge in the anodes with coke calcination temperatures of 900°C, 1000°C and 1100°C, which may be generated due to release of volatiles from the carbon anode during baking. For the anode containing coke calcined at 1100°C, it is found that many rounded pores often closely surround large coke particles, which have potential to form elongated, narrow pores.

  18. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  19. Industrial test coking of partially compacted charges by the method of briquetting without a binder

    SciTech Connect

    Olfert, A.I.; Taits, E.M.; Semenov, B.M.; Ruban, N.V.; Pavlov, V.V.; Ivanov, A.I.; Kovaleva, N.A.; Kalika, V.G.

    1981-01-01

    As a result of industrial test investigations on the coking of partially compacted charges by the method of briquetting without a binder it was shown that: (1) It is possible in practice to briquette coal charges without a binder to obtain small briquettes weighing about 7-8 g, with density of 1.14 to 1.15 g/cm/sup 3/, sufficiently strong that these briquettes may be used as a component of a coal charge loaded into coke ovens. (2) There ia an increase in the mechanical strength of the coke by the M40 index by 3% and a decrease in the M10 by 1.2% in the box coking of partially compacted industrial coal charge of the Moscow Coke Gas Plant. (3) There is an increase in the yield of the over 40 mm size class coke (by 5 to 10%) with a corresponding decrease in the yield of the finer size classes) depending on the caking capacity in the box coking of partially compacted charges. (4) It is possible to increase (with partial compaction of the charges) the proportion of Kuznetsk poorly-caking coal in the industrial charge of the Moscow Coke Gas Plant to 50 to 60% in comparison to the present 20%.

  20. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect

    G.R. Gainieva; L.D. Nikitin

    2007-07-01

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  1. 77 FR 15123 - Foundry Coke From China; Scheduling of an Expedited Five-Year Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-14

    ... its notice of institution (76 FR 74810, December 1, 2011) of the subject five-year review was adequate... COMMISSION Foundry Coke From China; Scheduling of an Expedited Five-Year Review AGENCY: United States...)) (the Act) to determine whether revocation of the antidumping duty order on foundry coke from...

  2. Interfaces Between Coke, Slag, and Metal in the Tuyere Level of a Blast Furnace

    NASA Astrophysics Data System (ADS)

    Li, Kejiang; Zhang, Jianliang; Liu, Zhengjian; Barati, Mansoor; Zhong, Jianbo; Wei, Mengfang; Wang, Guangwei; Jiao, Kexin; Yang, Tianjun

    2015-04-01

    An in-depth understanding about the reactions in the high-temperature zone of a blast furnace is significant to optimize both the current and future blast furnace process. The interfaces between coke, slag, and metal were observed using scanning electronic microscope with samples obtained from the tuyere level of a blast furnace. Two types of slag phases were identified, one originating from coke ash and the other from the bosh slag. Slag formed by coke ash was seen to cover the coke surface, which may hinder the reaction of coke with both gas and liquid iron. The reduction of FeO from the bosh slag (originated from the primary slag) occurs in the coke/slag interface with the reduced iron forming a metal layer surrounding the coke surface. The reduction of SiO2 occurs both in and outside the coke, and the reduced silicon reacts with iron to form iron silicide if the two species come into contact. Further study is proposed based on the results of this study.

  3. EMISSION TESTING AND EVALUATION OF THE ENCLOSED COKE PUSHING AND QUENCHING SYSTEM

    EPA Science Inventory

    The report describes a coke battery, placed into operation in May 1973 by National Steel's Weirton Steel Division, Weirton, WV. Consisting of 87 ovens, each 6 m tall, the battery includes features to reduce environmental discharges from the coke pushing and quenching operations. ...

  4. 76 FR 74810 - Foundry Coke From China; Institution of a Five-Year Review

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-01

    ..., and F (19 CFR part 207), as most recently amended at 76 FR 61937 (October 6, 2011). \\1\\ No response to... duty order on imports of foundry coke from China (66 FR 48025). Following five-year reviews by Commerce... order on imports of foundry coke from China (72 FR 1214). The Commission is now conducting a...

  5. EMISSION TESTING AND EVALUATION OF FORD/KOPPERS COKE PUSHING CONTROL SYSTEM. VOLUME II. APPENDICES

    EPA Science Inventory

    The report documents a field testing and engineering evaluation of the performance of a retrofitted, mobile-hood, high-energy-scrubber control system, abating coke-side pushing emissions from a 58-oven coke battery. It documents the venturi-scrubber inlet and outlet emission rate...

  6. EMISSION TESTING AND EVALUATION OF FORD/KOPPERS COKE PUSHING CONTROL SYSTEM. VOLUME I. FINAL REPORT

    EPA Science Inventory

    The report documents a field testing and engineering evaluation of the performance of a retrofitted, mobile-hood, high-energy-scrubber control system, abating coke-side pushing emissions from a 58-oven coke battery. It documents the venturi-scrubber inlet and outlet emission rate...

  7. Ground-water resources of Coke County, Texas

    USGS Publications Warehouse

    Wilson, Clyde A.

    1973-01-01

    Coke County, located in semiarid west-central Texas, where large ranches, small farms, and oil production are the main bases of the economy, has a small supply of ground and surface water. Of the approximately 1,900 acre-feet of fresh to moderately saline ground water used in 1968, industry used 880 acre-feet, irrigation used 210 acre-feet, and domestic supply and livestock used 820 acre-feet. All of the water for municipal supply and some of the water for industry is obtained from surface-water reservoirs.

  8. Determining the sulfuric acid fog concentration in coke oven gas

    SciTech Connect

    Zin'kovskaya, S.I.; Okhrimenko, E.L.; Sobko, L.V.

    1982-11-06

    A volumetric method for the analysis of sulfuric acid aerosols at levels of acid greater (25-40 g/m/sup 3/) than those (1 g/m/sup 3/) analyzable by current methods is described. Coke oven gas after acid scrubbing and electrofiltration is passed through a Schott filter (pressure drop 100 mm Hg), the sulfuric acid aerosol being condensed on the filter which is washed with water and the washings filtered with NaOH (0.01 N after electrofilter, 1.0 N after the acid towers) to methyl orange end point. The error is +/- 2%.

  9. Removal of cyanide compounds from coke oven gas

    SciTech Connect

    Sokratova, N.B.; Klimova, V.T.; Starodubtsev, D.S.; Chilikina, G.S.

    1982-01-01

    Bench-scale and pilot plant experiments were conducted on the ozonization of coke oven gas for the removal of cyanide and thiocyanates. Bubbler reactors with capacities of 0.5 dm/sup 3/ and 1.0 m/sup 3/ were used, and the concentrations of CN/sup -/, CNS/sup -/, and NH/sup +/, as well as the ph were determined. The concentration of ozone entering and leaving the reactor were found and used to compute ozone consumption. This method of cyanide removal compared favorably with respect to cost of reagents used to using sodium hypochlorite.

  10. Urinary 1-hydroxypyrene concentrations in coke oven workers

    PubMed Central

    Wu, M. T.; Mao, I. F.; Ho, C. K.; Wypij, D.; Lu, P. L.; Smith, T. J.; Chen, M. L.; Christiani, D. C.

    1998-01-01

    OBJECTIVES: To investigate the relation of individual occupational exposure to total particulates benzene soluble fraction (BSF) of ambient air with urinary 1-hydroxypyrene (1-OHP) concentrations among coke oven workers in Taiwan. METHODS: 80 coke oven workers and 50 referents were monitored individually for the BSF of breathing zone air over three consecutive days. Exposures were categorised as high, medium, or low among coke oven workers based on exposure situations. The high exposure group (n = 18) worked over the oven. The medium and low exposure groups (n = 41 and n = 21) worked at the side of the oven for > 4 hours and < 4 hours a day, respectively. Urine was collected before the shift on the morning of day 1 and after the shift on the afternoon of day 3 to find the change of 1-OHP concentrations across the shift. RESULTS: The median (range) changes of urinary 1-OHP concentrations across the shift for various exposure situations (microgram/g creatinine) were as follows: high 182 (7 to 3168); medium 9 (-8 to 511); low 7 (-6 to 28); and referents 0.2 (-2 to 72). This change of urinary 1-OHP was highly associated with individual occupational exposure to the BSF in air (r = 0.74 and 0.64, p < 0.001). The regression model showed significant effects of individual exposures to the BSF and alcohol consumption on urinary postshift 1-OHP after adjusting for preshift 1-OHP in the total population (n = 130). More exposure to the BSF led to higher postshift 1-OHP (p < 0.001); current drinkers of > 120 g/week had lower urinary postshift 1-OHP than never and former drinkers (p = 0.01). A 10-fold increase in the average BSF in air resulted in about a 2.5-fold increase in postshift 1-OHP among the 80 coke oven workers. CONCLUSION: Urinary 1-OHP concentrations can be used as a good biomarker to assess individual exposure to the BSF in air. Alcohol drinking may modify the toxicokinetic pathway of the BSF; the effects of alcohol should be investigated further in occupational

  11. New additive retards coke formation in ethylene furnace tubes

    SciTech Connect

    Not Available

    1994-05-09

    Adding relatively small amounts of a new additive to the feed stream of a steam cracker can inhibit coke formation on the metal surfaces of processing equipment and increase furnace run time. The additive comprises a variable mixture of four to six inorganic salts in aqueous solution. The components of the additive mixture can be varied, as needed, for processing heavy feed materials such as heavy naphtha and gas oil. The process was first tested at a Korean petrochemical plant and is now operating successfully at a commercial facility in Russia. The results of the Korean trial are presented here.

  12. 76 FR 52350 - Coke Oven Emissions Standard; Extension of the Office of Management and Budget's (OMB) Approval...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-22

    ... Occupational Safety and Health Administration Coke Oven Emissions Standard; Extension of the Office of...) approval of the information collection requirements specified in the Standard on Coke Oven Emissions (29... requirements in the Coke Oven Emissions Standard provide protection for workers from the adverse health...

  13. 40 CFR Appendix A to Subpart L of... - Operating Coke Oven Batteries as of April 1, 1992

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 10 2013-07-01 2013-07-01 false Operating Coke Oven Batteries as of... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries Pt. 63, Subpt. L, App. A Appendix A to Subpart L of Part 63—Operating Coke Oven Batteries as of April 1, 1992 No. Plant Battery 1...

  14. 40 CFR Appendix A to Subpart L of... - Operating Coke Oven Batteries as of April 1, 1992

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 10 2012-07-01 2012-07-01 false Operating Coke Oven Batteries as of... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries Pt. 63, Subpt. L, App. A Appendix A to Subpart L of Part 63—Operating Coke Oven Batteries as of April 1, 1992 No. Plant Battery 1...

  15. 40 CFR Appendix A to Subpart L of... - Operating Coke Oven Batteries as of April 1, 1992

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Operating Coke Oven Batteries as of... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries Pt. 63, Subpt. L, App. A Appendix A to Subpart L of Part 63—Operating Coke Oven Batteries as of April 1, 1992 No. Plant Battery 1...

  16. 40 CFR Appendix A to Subpart L of... - Operating Coke Oven Batteries as of April 1, 1992

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 10 2014-07-01 2014-07-01 false Operating Coke Oven Batteries as of... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries Pt. 63, Subpt. L, App. A Appendix A to Subpart L of Part 63—Operating Coke Oven Batteries as of April 1, 1992 No. Plant Battery 1...

  17. 40 CFR Appendix A to Subpart L of... - Operating Coke Oven Batteries as of April 1, 1992

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Operating Coke Oven Batteries as of... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries Pt. 63, Subpt. L, App. A Appendix A to Subpart L of Part 63—Operating Coke Oven Batteries as of April 1, 1992 No. Plant Battery 1...

  18. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect

    Not Available

    1989-08-01

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  19. Lung cancer mortality and exposure to polycyclic aromatic hydrocarbons in British coke oven workers

    PubMed Central

    2013-01-01

    Background Workers on coke oven plants may be exposed to potentially carcinogenic polycyclic aromatic hydrocarbons (PAHs), particularly during work on the ovens tops. Two cohorts, employees of National Smokeless Fuels (NSF) and the British Steel Corporation (BSC) totalling more than 6,600 British coke plant workers employed in 1967, had been followed up to mid-1987 for mortality. Previous analyses suggested an excess in lung cancer risk of around 25%, or less when compared with Social Class IV (‘partly skilled’). Analyses based on internal comparisons within the cohorts identified statistical associations with estimates of individual exposures, up to the start of follow-up, to benzene-soluble materials (BSM), widely used as a metric for mixtures of PAHs. Some associations were also found with times spent in certain coke ovens jobs with specific exposure scenarios, but results were not consistent across the two cohorts and limitations in the exposure estimates were noted. The present study was designed to reanalyse the existing data on lung cancer mortality, incorporating revised and improved exposure estimates to BSM and to benzo[a]pyrene (B[a]P), including increments during the follow-up and a lag for latency. Methods Mean annual average concentrations of both BSM and B[a]P were estimated by analysis of variance (ANOVA) from concentration measurements at all NSF and six BSC plants, and summarised by job and plant, with a temporal trend (for the BSM only). These were combined with subjects’ work histories, to produce exposure estimates in each year of follow-up, with a 10-year lag to allow for latency. Exposures to BSM and to B[a]P were sufficiently uncorrelated to permit analysis in relation to each variable separately. Lung cancer death risks during the follow-up were analysed in relation to the estimated time-dependent exposures, both continuous and grouped, using Cox regression models, with adjustment for age. Results Changing the exposure estimates

  20. Heights integrated model as instrument for simulation of hydrodynamic, radiation transport, and heat conduction phenomena of laser-produced plasma in EUV applications.

    SciTech Connect

    Sizyuk, V.; Hassanein, A.; Morozov, V.; Sizyuk, T.; Mathematics and Computer Science

    2007-01-16

    The HEIGHTS integrated model has been developed as an instrument for simulation and optimization of laser-produced plasma (LPP) sources relevant to extreme ultraviolet (EUV) lithography. The model combines three general parts: hydrodynamics, radiation transport, and heat conduction. The first part employs a total variation diminishing scheme in the Lax-Friedrich formulation (TVD-LF); the second part, a Monte Carlo model; and the third part, implicit schemes with sparse matrix technology. All model parts consider physical processes in three-dimensional geometry. The influence of a generated magnetic field on laser plasma behavior was estimated, and it was found that this effect could be neglected for laser intensities relevant to EUV (up to {approx}10{sup 12} W/cm{sup 2}). All applied schemes were tested on analytical problems separately. Benchmark modeling of the full EUV source problem with a planar tin target showed good correspondence with experimental and theoretical data. Preliminary results are presented for tin droplet- and planar-target LPP devices. The influence of three-dimensional effects on EUV properties of source is discussed.

  1. Metabolic activation of organic extracts from diesel, coke oven, roofing tar, and cigarette smoke emissions in the Ames assay

    SciTech Connect

    Williams, K.; Lewtas, J.

    1985-01-01

    The role of metabolic activation in the difference between a microbial and mammalian bioassays in the ranking of genotoxic potency of several environmental emissions was investigated. Although the relative potency in the Ames assay correlated well with the relative potency in mammalian cell and mouse skin for a series of automotive emissions (diesel and gasoline), this was not the case for the coke oven, roofing tar, and cigarette smoke condensate (CSC) emissions. The study examined several parameters of the metabolic activation with Salmonella typhimurium TA98 including S9 concentration and a comparison of Aroclor-1254 induced with uninduced S9 from both rat and hamster liver. The diesel-emissions sample was direct acting while the other samples required activation. The standard S9 concentration (approximately 1.25 mg protein/plate) also produced the maximum mutagenic activity. Induced S9s produced higher mutagenic activity than uninduced. The hamster S9 gave significantly higher mutagenic activies than rat S9 for the coke oven and CSC.

  2. Distribution of polycyclic aromatic hydrocarbons in coke plant wastewater.

    PubMed

    Burmistrz, Piotr; Burmistrz, Michał

    2013-01-01

    The subject of examinations presented in this paper is the distribution of polycyclic aromatic hydrocarbons (PAHs) between solid and liquid phases in samples of raw wastewater and wastewater after treatment. The content of 16 PAHs according to the US EPA was determined in the samples of coke plant wastewater from the Zdzieszowice Coke Plant, Poland. The samples contained raw wastewater, wastewater after physico-chemical treatment as well as after biological treatment. The ΣPHA16 content varied between 255.050 μg L(-1) and 311.907 μg L(-1) in raw wastewater and between 0.940 and 4.465 μg L(-1) in wastewater after full treatment. Investigation of the distribution of PAHs showed that 71-84% of these compounds is adsorbed on the surface of suspended solids and 16-29% is dissolved in water. Distribution of individual PAHs and ΣPHA16 between solid phase and liquid phase was described with the use of statistically significant, linear equations. The calculated values of the partitioning coefficient Kp changed from 0.99 to 7.90 for naphthalene in samples containing mineral-organic suspension and acenaphthylene in samples with biological activated sludge, respectively. PMID:24334890

  3. Apparatus for leveling coal in a coke oven chamber

    SciTech Connect

    Spindeler, H.; Wackerbarth, F.

    1985-01-01

    A coal-leveling apparatus includes a leveling rod supported by a pressing machine for movement through a leveling opening into a mushroom-shaped gas-collecting space to level the coal charged in the coking chamber of a coke oven. The leveling rod includes a head element that carries two support members that can move on pivot levers between an operative position wherein the support members are extended from the head element for support by upwardly-inclined wall surfaces in the mushroom-shaped gas-collecting space. In the inoperative position, the support members are retracted toward both sides of the head element. An actuating rod extends through the leveling rod to the head element. In one embodiment, the actuating rod can be moved in opposite directions of its length. An end of each of the first pivot levers is connected to the actuating rod and the opposite ends of the first levers are connected to second pivot levers. The second pivot levers are connected at one end to the head element and carry the support members. The connection between the pivot levers and the actuating rod, in one embodiment, is by a pivot connection, and in another embodiment by rollers that can move along an inclined surface on an end of the actuating rod. In a third embodiment a nut is threadedly engaged with threads on the end portion of the actuating rod to move the levers.

  4. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect

    Not Available

    1992-10-16

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  5. High strength coke oven wall having gas flues therein

    SciTech Connect

    Westbrook, R.W. III.

    1993-07-20

    In a nonrecovery coke oven battery including a plurality of coke ovens constructed in side-by-side relation with adjacent ovens in the battery being separated by a common sidewall having a face exposed in each said adjacent oven, and a plurality of generally rectangular flues formed in and extending generally vertically upward through each said common sidewall in spaced relation to one another, said flues having internal end surfaces generally parallel to said sidewall faces and side surfaces generally perpendicular to said sidewall faces, said sidewall being constructed of refractory brick separated by mortar joints and arranged in alternate odd and even courses with each course of brick including a plurality of groups of brick each cooperating to form a core having a rectangular opening extending there through defining a portion of one of said flues, the improvement is described wherein the refractory brick defining said cores in said even numbered courses comprise bricks of at least two shapes and the bricks defining the cores in the odd number of courses comprises bricks of at least two shapes, and wherein the shapes of the brick forming the core in said odd and in said even courses are different from one another, the refractory brick in each said core being shaped and arranged such that no mortar joint between two adjacent bricks defining any core is contained in a single vertical plane from a flue to the adjacent oven.

  6. Functional group and individual maceral chemistry of high volatile bituminous coals from southern Indiana: Controls on coking

    USGS Publications Warehouse

    Walker, R.; Mastalerz, Maria

    2004-01-01

    The individual maceral chemistries of two Pennsylvanian, high volatile bituminous coals, the Danville Coal Member (Dugger Formation, R o=0.55%) and the Lower Block Coal Member (Brazil Formation, R o=0.56%) of Indiana, were investigated using electron microprobe and Fourier Transform Infrared Spectrometry (FTIR) techniques, with the purpose of understanding differences in their coking behavior. Microprobe results reveal that carbon contents are highest in inertinite and sporinite, followed by desmocollinite and telocollinite. Oxygen and organic nitrogen are most abundant in telocollinite and desmocollinite; sporinite and inertinite contain lesser amounts of these two elements. Organic sulfur contents are highest in sporinite, lowest in inertinite, and intermediate in desmocollinite and telocollinite. Vitrinites within the Danville and Lower Block coals are very similar in elemental composition, while Lower Block inertinites and sporinites have higher carbon, lower oxygen, and sulfur contents which, when combined with the inertinite-and sporinite-rich composition of the Lower Block seam, strongly influences its whole coal chemistry. Fourier transform infrared spectrometry revealed greater aromatic hydrogen in the Lower Block coal, along with higher CH2/CH3 ratios, which suggest that liptinites contribute considerable amounts of long-chain, unbranched aliphatics to the overall kerogen composition of the Lower Block coal. Long-chain, unbranched aliphatics crack at higher temperatures, producing tar and oily byproducts during coking; these may help increase Lower Block plasticity. Electron microprobe and FTIR results indicate that individual maceral chemistries, combined with the maceral composition of the seam, are the primary control of better coking properties of the Lower Block coal. ?? 2003 Elsevier B.V. All rights reserved.

  7. Naphthenic acids speciation and removal during petroleum-coke adsorption and ozonation of oil sands process-affected water.

    PubMed

    Gamal El-Din, Mohamed; Fu, Hongjing; Wang, Nan; Chelme-Ayala, Pamela; Pérez-Estrada, Leonidas; Drzewicz, Przemysław; Martin, Jonathan W; Zubot, Warren; Smith, Daniel W

    2011-11-01

    The Athabasca Oil Sands industry produces large volumes of oil sands process-affected water (OSPW) as a result of bitumen extraction and upgrading processes. Constituents of OSPW include chloride, naphthenic acids (NAs), aromatic hydrocarbons, and trace heavy metals, among other inorganic and organic compounds. To address the environmental issues associated with the recycling and/or safe return of OSPW into the environment, water treatment technologies are required. This study examined, for the first time, the impacts of pretreatment steps, including filtration and petroleum-coke adsorption, on ozonation requirements and performance. The effect of the initial OSPW pH on treatment performance, and the evolution of ozonation and its impact on OSPW toxicity and biodegradability were also examined. The degradation of more than 76% of total acid-extractable organics was achieved using a semi-batch ozonation system at a utilized ozone dose of 150 mg/L. With a utilized ozone dose of 100 mg/L, the treated OSPW became more biodegradable and showed no toxicity towards Vibrio fischeri. Changes in the NA profiles in terms of carbon number and number of rings were observed after ozonation. The filtration of the OSPW did not improve the ozonation performance. Petroleum-coke adsorption was found to be effective in reducing total acid-extractable organics by a 91%, NA content by an 84%, and OSPW toxicity from 4.3 to 1.1 toxicity units. The results of this study indicate that the combination of petroleum-coke adsorption and ozonation is a promising treatment approach to treat OSPW. PMID:21907388

  8. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  9. Annual book of ASTM Standards 2005. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke

    SciTech Connect

    2005-09-15

    The first part covers standards for gaseous fuels. The standard part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrographic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

  10. Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke

    SciTech Connect

    2008-09-15

    The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

  11. Innovative coke oven gas cleaning system for retrofit applications: Environmental Monitoring Program. Volume 3, Appendix sections 8--14: Baseline Sampling Program report

    SciTech Connect

    Stuart, L.M.

    1994-05-27

    This report contains no text. It consists entirely of numerical data: Coke oven wastewater treatment performance; Ammonia still effluents to equalization tank; Stack gas analysis of coke oven batteries; CoaL consumption; Coke production; Supplemental OSHA employee exposure monitoring(hydrocarbons,ammonia, hydrogen sulfide); operating data; chemical products and coke oven gas production.

  12. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect

    Diemer, P.E.; Seyfferth, W.

    1997-12-31

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  13. The release of trace elements in the process of coal coking.

    PubMed

    Konieczyński, Jan; Zajusz-Zubek, Elwira; Jabłońska, Magdalena

    2012-01-01

    In order to assess the penetration of individual trace elements into the air through their release in the coal coking process, it is necessary to determine the loss of these elements by comparing their contents in the charge coal and in coke obtained. The present research covered four coke oven batteries differing in age, technology, and technical equipment. By using mercury analyzer MA-2 and the method of ICP MS As, Be, Cd, Co, Hg, Mn, Ni, Se, Sr, Tl, V, and Zn were determined in samples of charge coal and yielded coke. Basing on the analyses results, the release coefficients of selected elements were determined. Their values ranged from 0.5 to 94%. High volatility of cadmium, mercury, and thallium was confirmed. The tests have shown that although the results refer to the selected case studies, it may be concluded that the air purity is affected by controlled emission occurring when coke oven batteries are fired by crude coke oven gas. Fugitive emission of the trace elements investigated, occurring due to coke oven leaks and openings, is small and, is not a real threat to the environment except mercury. PMID:22666104

  14. Distribution, partition and removal of polycyclic aromatic hydrocarbons (PAHs) during coking wastewater treatment processes.

    PubMed

    Zhang, Wanhui; Wei, Chaohai; An, Guanfeng

    2015-05-01

    In this study, we report the performance of a full-scale conventional activated sludge (A-O1-O2) treatment in eliminating polycyclic aromatic hydrocarbons (PAHs). Both aqueous and solid phases along with the coking wastewater treatment processes were analyzed for the presence of 18 PAHs. It was found that the target compounds occurred widely in raw coking wastewater, treated effluent and sludge samples. In the coking wastewater treatment system, 4-5 ring PAHs were the dominant compounds, while 4 rings PAHs predominated in the sludge samples. Over 98% of the PAH removal was achieved in the coking wastewater treatment plant (WWTP), with the total concentration of PAHs being 21.3 ± 1.9 μg L(-1) in the final effluent. During the coking wastewater treatment processes, the association of the lower molecular weight PAH with suspended solids was generally less than 60%, while the association of higher molecular weight PAHs was greater than 90%. High distribution efficiencies (Kdp and Kds) were found, suggesting that adsorption was the potential removal pathway of PAHs. Finally, the mass balances of PAHs in various stages of the coking WWTP were obtained, and the results indicated that adsorption to sludge was the main removal pathway for PAHs in the coking wastewater treatment processes. PMID:25865172

  15. The Release of Trace Elements in the Process of Coal Coking

    PubMed Central

    Konieczyński, Jan; Zajusz-Zubek, Elwira; Jabłońska, Magdalena

    2012-01-01

    In order to assess the penetration of individual trace elements into the air through their release in the coal coking process, it is necessary to determine the loss of these elements by comparing their contents in the charge coal and in coke obtained. The present research covered four coke oven batteries differing in age, technology, and technical equipment. By using mercury analyzer MA-2 and the method of ICP MS As, Be, Cd, Co, Hg, Mn, Ni, Se, Sr, Tl, V, and Zn were determined in samples of charge coal and yielded coke. Basing on the analyses results, the release coefficients of selected elements were determined. Their values ranged from 0.5 to 94%. High volatility of cadmium, mercury, and thallium was confirmed. The tests have shown that although the results refer to the selected case studies, it may be concluded that the air purity is affected by controlled emission occurring when coke oven batteries are fired by crude coke oven gas. Fugitive emission of the trace elements investigated, occurring due to coke oven leaks and openings, is small and, is not a real threat to the environment except mercury. PMID:22666104

  16. Effect of stripper conditions on the yield and structure of coke derived from n-Hexadecane

    SciTech Connect

    Mohammed, A.A.H.; McGhee, B.J.; Snape, C.E.

    1996-10-01

    In FCC units, coked catalyst first passes to a steam stripper to remove residual volatiles before being transferred to the regenerator. Entrained products which are symptomatic of incomplete stripping can contribute to the overall level of coke and increase its hydrogen content considerably. To determine how the yields and composition coke varies in FCC as a function of stripper conditions, tests have been conducted ill fluidised-bed reactor using n-hexadecane at 500{degrees}C, a commercial FCC catalyst with stripping times up to 120 min. Coke concentrates have been prepared by demineralisation with hydrofluoric and hydrochloric acids. The inherently quantitative single pulse excitation {sup 13}C NMR technique has been used to derive the total, protonated and non-protonated aromatic carbon concentrations for the coke concentrates. Mass spectrometry las also used to characterise the cokes. The initial coke possesses considerable aliphatic character (carbon aromaticity of 0.80), but the removal of volatiles by stripping gives rise to increases in both aromaticity and aromatic ring size.

  17. Activated oil sands fluid coke for electrical double-layer capacitors

    NASA Astrophysics Data System (ADS)

    Zuliani, Jocelyn E.; Kirk, Donald W.; Jia, Charles Q.; Tong, Shitang

    2014-12-01

    Electrochemical capacitors are important energy storage devices that have high power density, rapid charging cycles and are highly cyclable. In this study, activated fluid coke has demonstrated high surface area, improved capacitive properties, and high energy density. Fluid coke is a by-product generated from continuous high temperature bitumen upgrading, resulting in the formation of nearly spherical particles with concentric carbon layers. The residual sulphur impurities in fluid coke may enhance its energy storage performance. The activated coke samples have high specific surface areas, up to 1960 m2 g-1, and show promising capacitive performance, in 4 M KOH electrolyte, with high gravimetric and specific capacitances of 228-257 F g-1 and 13-14 μF cm-2, respectively. These results are comparable to other top performing activated carbon materials [1-3]. The activated fluid coke maintains high performance at fast charging rates, greater than 160 F g-1 at a current density of 7500 mA g-1. Activated fluid coke's high capacitance and promising rate performance are potentially associated with its unique layered, and the moderate sulphur content in the chemical structure. Activated fluid coke is a unique opportunity to use a limited use by-product to generate activated carbon that has a high surface area and promising energy storage properties.

  18. Reflection of a probe pulse and thermal emission of electrons produced by an aluminum film heated by a femtosecond laser pulse

    SciTech Connect

    Bezhanov, S. G.; Ionin, A. A.; Kanavin, A. P.; Kudryashov, S. I.; Makarov, S. V.; Seleznev, L. V.; Sinitsyn, D. V.; Uryupin, S. A.

    2015-06-15

    It is shown that an experimental decrease in the reflection of a probe femtosecond pulse from an aluminum film heated by a higher-power femtosecond pulse can be quantitatively described taking into account the inhomogeneous distribution of the laser pulse field in the film and the evolution of the electron and lattice temperature during absorption of the heating inhomogeneous field. Analysis of the electron temperature evolution on the heated film surface combined with modern concepts about the influence of a surface volume charge on thermal emission gave the relation between the amount of emitted electrons and experimental data on the heating of the aluminum film by the femtosecond pulse.

  19. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert

    2009-05-15

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  20. Variation in toxicity response of Ceriodaphnia dubia to Athabasca oil sands coke leachates.

    PubMed

    Puttaswamy, Naveen; Turcotte, Dominique; Liber, Karsten

    2010-07-01

    Coke from the Athabasca (Alberta, Canada) oil sands operations may someday be integrated into reclamation landscapes. It is hypothesized that the metals associated with the solid coke may leach into the surrounding environment. Therefore, the main objectives of this study were to characterize the toxicity and chemistry of coke leachates collected from two field lysimeters (i.e. shallow lysimeter and deep lysimeter) over a period of 20months, as well as from other oil sands coke storage sites. In addition, a batch renewal leaching of coke was conducted to examine the rate of metals release. Chronic toxicity of key metals (e.g. Al, Mn, Ni and V) found in lysimeter coke leachate was evaluated separately. Toxicity test results revealed that whole coke leachates (100% v/v) were acutely toxic to Ceriodaphnia dubia; the 7-day LC50 values were always <25% v/v coke leachate. The deep lysimeter leachate was generally more toxic than the shallow lysimeter leachate, likely because of significantly higher concentrations of vanadium (V) found in the deep lysimeter leachate at all sampling times. Vanadium concentrations were higher than all other metals found in the leachate from both lysimeters, and in the batch renewal leaching study. Furthermore, V found in leachates collected from other oil sands field sites showed a concentration-response relationship with C. dubia survival. Mass balance calculations indicated that 94-98% of potentially leachable V fraction was still present in the coke from two field lysimeters. Evidence gathered from these assessments, including toxic unit (TU) calculations for the elements of concern, suggests that V was the likely cause of toxicity of the deep lysimeter leachate, whereas in the shallow lysimeter leachate both Ni and V could be responsible for the observed toxicity. PMID:20553931

  1. Color and chlorinated organics removal from pulp mills wastewater using activated petroleum coke.

    PubMed

    Shawwa, A R; Smith, D W; Sego, D C

    2001-03-01

    Delayed petroleum coke, a waste by-product from the oil sand industry, was utilized in the production of activated carbon. The activated carbon was then evaluated for color and chlorinated organics reduction from pulp mill wastewater. The activation of the petroleum coke was evaluated using a fixed bed reactor involving carbonization and activation steps at temperature of 850 degrees C and using steam as the activation medium. The activation results showed that the maximum surface area of the activated coke was achieved at an activation period of 4 h. The maximum surface area occurred at burnoff and water efficiency of 48.5 and 54.3%, respectively. Increasing the activation period to 6 h resulted in a decrease in the surface area. Methylene blue adsorption results indicated that the activation process was successful. Methylene blue adsorbed per 100 g of applied activated coke was 10 times higher than that adsorbed by raw petroleum coke. Adsorption equilibrium results of the bleached wastewater and the activated coke showed that significant color, COD, DOC and AOX removal (> 90%) was achieved when the activated coke dose exceeded 15,000 mg/L. Adsorption isotherms, in terms of COD, DOC, UV and color were developed based on the batch equilibrium data. Based on these isotherms, the amount of activated coke required to achieve certain removal of color and AOX can be predicted. The utilization of the petroleum coke for the production of activated carbon can provide an excellent disposal option for the oil sand industry at the same time would provide a cheap and valuable activated carbon. PMID:11228973

  2. Characterization of the origin and distribution of the minerals and phases in metallurgical cokes

    SciTech Connect

    Sushil Gupta; Maria Dubikova; David French; Veena Sahajwalla

    2007-01-15

    Three industrial metallurgical cokes were examined using X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray analysis (SEM/EDS). The study highlighted the difficulties and implications of identifying the inherent crystalline mineral phases in cokes using XRD such that increasing the ashing temperature led to the formation of anhydrite and destruction of metallic iron: microwave plasma ashing resulted in minimal alteration of the original coke mineralogy apart from the formation of bassanite and possibly jarosite. A preliminary scheme to characterize coke minerals is presented such that, physically, minerals can be classified as fine ({lt}50 {mu}m), coarse (50-100 {mu}m), and agglomerate ({gt}1000 {mu}m); chemically, minerals can be grouped as refractory, semirefractory, and reactive, while on the basis of distribution they can be described as discrete, disseminated, or pore inclusions. Quartz, cristobalite, mullite, and high melting point Al-silicates were found to be the predominant refractory phases while low melting point Al-silicates, e.g., containing high fluxing elements such as K, and Fe were the main semirefractory phases present in all cokes. A variety of iron containing phases including pyrrhotite, troilite, iron oxides, metallic iron, and iron silicates were also invariably present in all cokes while calcium phases were found to occur as sulfide, silicates, and phosphates. In general, iron and calcium phases can be categorized as reactive phases with few exceptions such as oldhamite (CaS). The study highlighted that most of the cokes possess a similar mineralogy, with the main distinction being in their relative abundance, particle size, and nature of distribution in the coke matrix. The study provides a basis to develop a mechanistic understanding of the influence of minerals on coke reactivity and strength at high temperatures. 41 refs., 13 figs., 4 tabs.

  3. HEAT GENERATION

    DOEpatents

    Imhoff, D.H.; Harker, W.H.

    1963-12-01

    Heat is generated by the utilization of high energy neutrons produced as by nuclear reactions between hydrogen isotopes in a blanket zone containing lithium, a neutron moderator, and uranium and/or thorium effective to achieve multtplicatton of the high energy neutron. The rnultiplied and moderated neutrons produced react further with lithium-6 to produce tritium in the blanket. Thermal neutron fissionable materials are also produced and consumed in situ in the blanket zone. The heat produced by the aggregate of the various nuclear reactions is then withdrawn from the blanket zone to be used or otherwise disposed externally. (AEC)

  4. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  5. Fraction of Pt surface covered with coke following hydrogenolysis of hexane

    SciTech Connect

    Rivera-Latas, F.J.; Betta, R.A.D.; Boudart, M. )

    1992-05-01

    This paper reports that following hydrogenolysis of n-hexane on an alumina-supported platinum catalyst, the surface of the metal is covered partially with carbonaceous residues or coke. The fraction of surface platinum not covered with coke has been found to be about one half by four independent techniqu3s: titration of preadsorbed oxygen by dihydrogen, chemisorption of carbon monoxide, infrared spectroscopy of chemisorbed carbon monoxide, and hydrogenation rate of ethylene. The first of these techniques suggests itself as the simplest one for further studies of deactivation by coking of platinum catalysts.

  6. Evaluation of the potential carcinogenicity of coke oven emissions. Final report

    SciTech Connect

    1988-06-01

    Coke oven emissions are known human carcinogens, classified as weight-of-evidence Group A under the EPA Guidelines for Carcinogen Risk Assessment. Evidence on potential carcinogenicity from animal studies is Sufficient, and the evidence from human studies is Sufficient. The potency factor (F) for coke oven emissions are estimated to be 1.53 (mg/kg/day)(-1), placing it in potency group 2 according to the CAG`s methodology for evaluating potential carcinogens. Combining the weight-of-evidence group and the potency group, coke oven emissions are assigned a HIGH hazard ranking.

  7. Organophosphorus compounds as coke inhibitors during naphtha pyrolysis. Effect of benzyl diethyl phosphite and triphenylphosphine sulfide

    SciTech Connect

    Das, P.; Prasad, S.; Kunztu, D.

    1992-09-01

    This paper reports that significant reduction in the rate of coke formation during naphtha pyrolysis was achieved by adding benzyl diethyl phosphite or triphenylphosphine sulfide to the feed. Although the yield of carbon oxides was reduced, there was no effect of these additives on the hydrocarbon yields. Addition of these organophosphorus compounds significantly reduced the concentration of metals, such as iron, nickel, and chromium, incorporated in the coke. A previously proposed model for coke inhibition due to the formation of a passivating metal-phosphorus complex could satisfactorily correlate the data.

  8. Prospects for use of lean caking coal from the Kuznetsk coalfield for coking

    SciTech Connect

    Sulimov, G.I.; Agafonov, A.A.; Ol'shanetskii, L.G.

    1983-01-01

    The coals from the Kuznetsk Coalfield were investigated under laboratory and pilot-plant conditions and compared with coals of various rank from the Anzhero Coalfield. The coals from the South of the Kuzbass have a more favorable petrographic composition than the Anzhero coals; their volatile matter depends on the rank; the caking capacity is low; the plastic layer is not measured, and the swelling index is also low. The lean coal types are coked in charges containing Kuznetsk and Pechora coal. The criterion for evaluation of the coking capacity was the coke mechanical strength indices, obtained during testing in the large grate drum. 1 figure, 4 tables.

  9. Draft Genome Sequences of Two Heat-Resistant Mutant Strains (A52 and B41) of the Photosynthetic Hydrogen-Producing Bacterium Rhodobacter capsulatus.

    PubMed

    Gokce, Abdulmecit; Cakar, Zeynep Petek; Yucel, Meral; Ozcan, Orhan; Sencan, Sevde; Sertdemir, Ibrahim; Erguner, Bekir; Yuceturk, Betul; Sarac, Aydan; Yuksel, Bayram; Ozturk, Yavuz

    2016-01-01

    The draft genome sequences of two heat-resistant mutant strains, A52 and B41, derived from Rhodobacter capsulatus DSM 1710, and with different hydrogen production levels, are reported here. These sequences may help understand the molecular basis of heat resistance and hydrogen production in R. capsulatus. PMID:27284151

  10. Draft Genome Sequences of Two Heat-Resistant Mutant Strains (A52 and B41) of the Photosynthetic Hydrogen-Producing Bacterium Rhodobacter capsulatus

    PubMed Central

    Gokce, Abdulmecit; Cakar, Zeynep Petek; Yucel, Meral; Ozcan, Orhan; Sencan, Sevde; Sertdemir, Ibrahim; Erguner, Bekir; Yuceturk, Betul; Sarac, Aydan; Yuksel, Bayram

    2016-01-01

    The draft genome sequences of two heat-resistant mutant strains, A52 and B41, derived from Rhodobacter capsulatus DSM 1710, and with different hydrogen production levels, are reported here. These sequences may help understand the molecular basis of heat resistance and hydrogen production in R. capsulatus. PMID:27284151

  11. [Pilot-plant testing for flue gas desulfurization and dust removal by activated coke].

    PubMed

    Zhai, Shang-peng; Liu, Jing; Xin, Chang-xia; Tang, Song-song; Zhang, Peng; Xiao, You-guo; Ma, Zheng-fei

    2006-05-01

    A developed flue gas desulfurization and dust removal process with a cross-flow moving bed filled with activated coke (AC) was tested on a pilot scale with the gas treatment capacity of 1000 mg x h(-t). The results show that a easy-operating and stable-running pilot-scale testing equipment can be reached, and under the conditions of testing space velocity, the feed gas temperature of 120 degrees C, SO2 concentrations of 3232-6006 mg x m(-3) and dust concentration of 89.3-1599.7 mg x m(-3), the high efficiency of flue gas desulfurization and dust removal is reached with the purity of dust less than 50 mg x m(-3). In the technology, the spent AC was regenerated by heating, and the SO2 concentration in the desorption gas is about 40.1%, which can be efficiently recovered as a sulfur resource. Favorable economy benefit can be reached by using the process. PMID:16850821

  12. Influence of O2 and H2O on carbothermal reduction of SO2 by oil-sand fluid coke.

    PubMed

    Feng, Wenguo; Jia, Charles Q

    2005-12-15

    To develop a new process for removing high-concentration SO2 from industrial flue gases, the carbothermal reduction of SO2 by oil-sand fluid coke at 700 degrees C was investigated by varying the inlet concentration of either O2 or H2O. Concentrations of O2 and H2O ranged from 0 to 20% and from 0 to 30%, respectively, in a stream of SO2 (18%) with the balance helium. Addition of O2 and H2O was found to enhance SO2 reduction. The enhancement was attributed to the reducing gases, CO and H2, produced by solid-gas reactions between carbon and O2 or H2O. The effects of O2 and H2O on sulfur yield, however, were bifacial: adding O2 and/or H2O increased the sulfur yield when SO2 conversion was incomplete, otherwise, it decreased the sulfur yield through the formation of sulfides such as H2S. The results of a thermodynamic analysis were in a good agreementwith the experimental results, suggesting that gas-solid reactions were slow enough to allow gas-phase equilibrium. This study indicates that carbon, such as oil-sand fluid coke, can be utilized to remove SO2 in flue gases containing O2/H2O and to convert it to elemental sulfur. PMID:16475356

  13. Reduction of gas phase air toxics from combustion and incineration sources using the GE-Mitsui-BG activated coke process

    SciTech Connect

    Olson, D.G.; Tsuji, K.; Shiraishi, I.

    1998-04-01

    The dry desulfurization, denitification and air toxics removal process using activated coke (AC) was originally researched and developed during the 1960`s by Bergbau Forschung (BF), now called Deutsche Montan Technologies. Mitsui Mining Company (MMC) signed a licensing agreement with BF in 1982 to investigate, test and adapt the system to facilities in Japan. Japanese regulations are stricter than in the United States toward SOx/NOx pollutants, as well as flyash emissions from the utility industry, oil refineries and other industries. This process is installed on four coal-fired boilers and Fluidized Catalytic Cracker (FCC) units. These plants were constructed by MMC in Japan and Uhde GmbH in Germany. General Electric Environmental Services, Inc. (GEESI) signed a license agreement in 1992 with MMC and Mitsui and Company, Ltd. of Tokyo. Under this agreement, GEESI will market, design, fabricate and install the Mitsui-BF process for flue gas cleaning applications in North America. MMC also developed a technology to produce AC used in the dry DeSOx/DeNOx/Air Toxics removal process based on their own metallurgical coke manufacturing technology. This paper provides information on the details of MMC`s AC used in the dry DeSOx/DeNOx/Air Toxics removal process and of the DeSOx/DeNOx/Air Toxics removal process itself.

  14. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov

    2009-02-15

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  15. Physical and electrochemical properties of supercapacitor composite electrodes prepared from biomass carbon and carbon from green petroleum coke

    NASA Astrophysics Data System (ADS)

    Awitdrus, Deraman, M.; Talib, I. A.; Farma, R.; Omar, R.; Ishak, M. M.; Taer, E.; Dolah, B. N. M.; Basri, N. H.; Nor, N. S. M.

    2015-04-01

    The green monoliths (GMs) were prepared from the mixtures of pre-carbonized fibers of oil palm empty fruit bunches (or self-adhesive carbon grains (SACG)) and green petroleum coke (GPC) with the mixing ratio of 0, 10, 30, 50 and 70 % GPC, respectively. The GMs were carbonized in N2 environment at 800°C to produce carbon monoliths (CM00, CM10, CM30, CM50 and CM70). The CMs were CO2 activated at 800°C for 1 hour to produced activated carbon monolith electrodes (ACM00, ACM10, ACM30, ACM50 and ACM70). For each percentage of GPC, three duplicate symmetrical supercapacitor cells were fabricated using these activated carbon monolith electrodes respectively, and the capacitive performance amongst the cells was compared and analyzed in order to observe the relationship between the capacitive performance and the physical properties (microstructure and porosity) of the ACMs electrodes containing varying percentage of GPC.

  16. Experimental study on the effects of blast-cap configurations and charge patterns on coke descending in CDQ cooling shaft

    SciTech Connect

    Y.H. Feng; X.X. Zhang; M.L. Wu

    2008-08-15

    The coke descending behavior in a CDQ cooling shaft is studied experimentally by means of a tracing method with a digital camera. For three different blast-caps, the law of coke flow is studied under five conditions of coke charge. The experimental results show that, for the sake of the uniformity of the coke burden descending, a blast-cap with elliptical cross-section is a better choice than that with circular cross-section regardless of high or low placement. A coke charge pattern with a flat top burden surface is preferable to that with peak-valley surface, a double-peak superior to a one-peak. Trajectory and average velocity distribution of coke behavior depend weakly on whether the coke is continuously fed or not as the discharging began. The blast-caps have local effects on the descending coke and hardly affect whether the cokes flow smoothly or not in the case of coke burden with enough depth.

  17. Guide to ASTM test methods for the analysis of coal and coke

    SciTech Connect

    R.A. Kishore Nadkarni

    2008-07-01

    The guide includes brief descriptions of all 56 ASTM test methods that cover the physical, chemical, and spectroscopic analytical techniques to qualitatively and quantitatively identify over 40 chemical and physical properties of coal, coke, their products, and by-products.

  18. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin

    2009-07-15

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  19. Study of ways of reducing coke use at non-integrated metallurgical plants

    SciTech Connect

    S.A. Feshchenko; V.I. Pleshkov; I.N. Shishchuk; A.V. Buev

    2006-03-15

    To reduce the costs of blast-furnace smelting, the Svobodnyi Sokol plant has devised a comprehensive program of organizational-technical measures that include study of ways of reducing coke consumption. To do this, the plant began operating its blast furnaces with schungite when making foundry and conversion pig irons. Using schungite in the charge employed to make foundry iron makes it possible to save a significant (10-15%) amount of coke. The value of the coefficient that characterizes the replacement of coke by schungite varies broadly and can reach 1.0 or more, depending on the grade of iron being made and the furnace operating regime. The same coefficient has a value of 0.57 kg coke/kg schungite when 12-15 kg schungite/ton pig is used to make conversion pig iron.

  20. Fe-Si droplets associated with graphite on blast furnace coke

    NASA Astrophysics Data System (ADS)

    Gornostayev, Stanislav S.; Fabritius, Timo M. J.; Kerkkonen, Olavi; Härkki, Jouko J.

    2012-06-01

    Fe-Si droplets on the surface of blast furnace (BF) coke from 25 to 50 cm at the tuyere level are mostly composed of Fe3Si, which has various shapes (round, elongated, and irregular) and penetration degrees into the BF coke matrix. The shapes and penetration degrees may depend on the saturation of molten iron by silicon during interaction with the coke matrix. The droplets are covered by a tiny shell of carbon. Graphite observed inside the droplets can be divided into two categories: well-formed tabular crystals with relatively large size and flakes with structures similar as those in cast iron. The textures of the droplets reflect composition, interaction with the coke matrix, and cooling conditions.