Sample records for radioactive salt waste

  1. Recycling of LiCl-KCl eutectic based salt wastes containing radioactive rare earth oxychlorides or oxides

    NASA Astrophysics Data System (ADS)

    Eun, H. C.; Cho, Y. Z.; Son, S. M.; Lee, T. K.; Yang, H. C.; Kim, I. T.; Lee, H. S.

    2012-01-01

    Recycling of LiCl-KCl eutectic salt wastes containing radioactive rare earth oxychlorides or oxides was studied to recover renewable salts from the salt wastes and to minimize the radioactive wastes by using a vacuum distillation method. Vaporization of the LiCl-KCl eutectic salt was effective above 900 °C and at 5 Torr. The condensations of the vaporized salt were largely dependent on temperature gradient. Based on these results, a recycling system of the salt wastes as a closed loop type was developed to obtain a high efficiency of the salt recovery condition. In this system, it was confirmed that renewable salt was recovered at more than 99 wt.% from the salt wastes, and the changes in temperature and pressure in the system could be utilized to understand the present condition of the system operation.

  2. Characteristics of solidified products containing radioactive molten salt waste.

    PubMed

    Park, Hwan-Seo; Kim, In-Tae; Cho, Yong-Zun; Eun, Hee-Chul; Kim, Joon-Hyung

    2007-11-01

    The molten salt waste from a pyroprocess to recover uranium and transuranic elements is one of the problematic radioactive wastes to be solidified into a durable wasteform for its final disposal. By using a novel method, named as the GRSS (gel-route stabilization/solidification) method, a molten salt waste was treated to produce a unique wasteform. A borosilicate glass as a chemical binder dissolves the silicate compounds in the gel products to produce one amorphous phase while most of the phosphates are encapsulated by the vitrified phase. Also, Cs in the gel product is preferentially situated in the silicate phase, and it is vitrified into a glassy phase after a heat treatment. The Sr-containing phase is mainly phosphate compounds and encapsulated by the glassy phase. These phenomena could be identified by the static and dynamic leaching test that revealed a high leach resistance of radionuclides. The leach rates were about 10(-3) - 10(-2) g/m2 x day for Cs and 10(-4) - 10(-3) g/m2 x day for Sr, and the leached fractions of them were predicted to be 0.89% and 0.39% at 900 days, respectively. This paper describes the characteristics of a unique wasteform containing a molten salt waste and provides important information on a newly developed immobilization technology for salt wastes, the GRSS method.

  3. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOEpatents

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  4. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOEpatents

    Lewis, Michele A.; Johnson, Terry R.

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  5. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. Amore » three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.« less

  6. Development of iron phosphate ceramic waste form to immobilize radioactive waste solution

    NASA Astrophysics Data System (ADS)

    Choi, Jongkwon; Um, Wooyong; Choung, Sungwook

    2014-09-01

    The objective of this research was to develop an iron phosphate ceramic (IPC) waste form using converter slag obtained as a by-product of the steel industry as a source of iron instead of conventional iron oxide. Both synthetic off-gas scrubber solution containing technetium-99 (or Re as a surrogate) and LiCl-KCl eutectic salt, a final waste solution from pyrochemical processing of spent nuclear fuel, were used as radioactive waste streams. The IPC waste form was characterized for compressive strength, reduction capacity, chemical durability, and contaminant leachability. Compressive strengths of the IPC waste form prepared with different types of waste solutions were 16 MPa and 19 MPa for LiCl-KCl eutectic salt and the off-gas scrubber simulant, respectively, which meet the minimum compressive strength of 3.45 MPa (500 psi) for waste forms to be accepted into the radioactive waste repository. The reduction capacity of converter slag, a main dry ingredient used to prepare the IPC waste form, was 4136 meq/kg by the Ce(IV) method, which is much higher than those of the conventional Fe oxides used for the IPC waste form and the blast furnace slag materials. Average leachability indexes of Tc, Li, and K for the IPC waste form were higher than 6.0, and the IPC waste form demonstrated stable durability even after 63-day leaching. In addition, the Toxicity Characteristic Leach Procedure measurements of converter slag and the IPC waste form with LiCl-KCl eutectic salt met the universal treatment standard of the leachability limit for metals regulated by the Resource Conservation and Recovery Act. This study confirms the possibility of development of the IPC waste form using converter slag, showing its immobilization capability for radionuclides in both LiCl-KCl eutectic salt and off-gas scrubber solutions with significant cost savings.

  7. Development of iron phosphate ceramic waste form to immobilize radioactive waste solution

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Choi, Jongkwon; Um, Wooyong; Choung, Sungwook

    The objective of this research was to develop an iron phosphate ceramic (IPC) waste form using converter slag obtained as a by-product of the steel industry as a source of iron instead of conventional iron oxide. Both synthetic off-gas scrubber solution containing technetium-99 (or Re as a surrogate) and LiCl-KCl eutectic salt, a final waste solution from pyrochemical processing of spent nuclear fuel, were used as radioactive waste streams. The IPC waste form was characterized for compressive strength, reduction capacity, chemical durability, and contaminant leachability. Compressive strengths of the IPC waste form prepared with different types of waste solutions weremore » 16 MPa and 19 MPa for LiCl-KCl eutectic salt and the off-gas scrubber simulant, respectively, which meet the minimum compressive strength of 3.45 MPa (500 psi) for waste forms to be accepted into the radioactive waste repository. The reduction capacity of converter slag, a main dry ingredient used to prepare the IPC waste form, was 4,136 meq/kg by the Ce(IV) method, which is much higher than those of the conventional Fe oxides used for the IPC waste form and the blast furnace slag materials. Average leachability indexes of Tc, Li, and K for the IPC waste form were higher than 6.0, and the IPC waste form demonstrated stable durability even after 63-day leaching. In addition, the Toxicity Characteristic Leach Procedure measurements of converter slag and the IPC waste form with LiCl-KCl eutectic salt met the universal treatment standard of the leachability limit for metals regulated by the Resource Conservation and Recovery Act. This study confirms the possibility of development of the IPC waste form using converter slag, showing its immobilization capability for radionuclides in both LiCl-KCl eutectic salt and off-gas scrubber solutions with significant cost savings.« less

  8. Method to synthesize dense crystallized sodalite pellet for immobilizing halide salt radioactive waste

    DOEpatents

    Koyama, Tadafumi

    1994-01-01

    A method for immobilizing waste chloride salts containing radionuclides such as cesium and strontium and hazardous materials such as barium. A sodalite intermediate is prepared by mixing appropriate amounts of silica, alumina and sodium hydroxide with respect to sodalite and heating the mixture to form the sodalite intermediate and water. Heating is continued to drive off the water to form a water-free intermediate. The water-free intermediate is mixed with either waste salt or waste salt which has been contacted with zeolite to concentrate the radionuclides and hazardous material. The waste salt-intermediate mixture is then compacted and heated under conditions of heat and pressure to form sodalite with the waste salt, radionuclides and hazardous material trapped within the sodalite cage structure. This provides a final product having excellent leach resistant capabilities.

  9. Method to synthesize dense crystallized sodalite pellet for immobilizing halide salt radioactive waste

    DOEpatents

    Koyama, Tadafumi.

    1994-08-23

    A method is described for immobilizing waste chloride salts containing radionuclides such as cesium and strontium and hazardous materials such as barium. A sodalite intermediate is prepared by mixing appropriate amounts of silica, alumina and sodium hydroxide with respect to sodalite and heating the mixture to form the sodalite intermediate and water. Heating is continued to drive off the water to form a water-free intermediate. The water-free intermediate is mixed with either waste salt or waste salt which has been contacted with zeolite to concentrate the radionuclides and hazardous material. The waste salt-intermediate mixture is then compacted and heated under conditions of heat and pressure to form sodalite with the waste salt, radionuclides and hazardous material trapped within the sodalite cage structure. This provides a final product having excellent leach resistant capabilities.

  10. Method to synthesize dense crystallized sodalite pellet for immobilizing halide salt radioactive waste

    DOEpatents

    Koyama, T.

    1992-01-01

    This report describes a method for immobilizing waste chloride salts containing radionuclides such as cesium and strontium and hazardous materials such as barium. A sodalite intermediate is prepared by mixing appropriate amounts of silica, alumina and sodium hydroxide with respect to sodalite and heating the mixture to form the sodalite intermediate and water. Heating is continued to drive off the water to form a water-free intermediate. The water-free intermediate is mixed with either waste salt or waste salt which has been contacted with zeolite to concentrate the radionuclides and hazardous material. The waste salt-intermediate mixture is then compacted and heated under conditions of heat and pressure to form sodalite with the waste salt, radionuclides and hazardous material trapped within the sodalite cage structure. This provides a final product having excellent leach resistant capabilities.

  11. Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products

    DOEpatents

    Barney, Gary S.; Brownell, Lloyd E.

    1977-01-01

    A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

  12. Radioactive waste isolation in salt: special advisory report on the status of the Office of Nuclear Waste Isolation's plans for repository performance assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ditmars, J.D.; Walbridge, E.W.; Rote, D.M.

    1983-10-01

    Repository performance assessment is analysis that identifies events and processes that might affect a repository system for isolation of radioactive waste, examines their effects on barriers to waste migration, and estimates the probabilities of their occurrence and their consequences. In 1983 Battelle Memorial Institute's Office of Nuclear Waste Isolation (ONWI) prepared two plans - one for performance assessment for a waste repository in salt and one for verification and validation of performance assessment technology. At the request of the US Department of Energy's Salt Repository Project Office (SRPO), Argonne National Laboratory reviewed those plans and prepared this report to advisemore » SRPO of specific areas where ONWI's plans for performance assessment might be improved. This report presents a framework for repository performance assessment that clearly identifies the relationships among the disposal problems, the processes underlying the problems, the tools for assessment (computer codes), and the data. In particular, the relationships among important processes and 26 model codes available to ONWI are indicated. A common suggestion for computer code verification and validation is the need for specific and unambiguous documentation of the results of performance assessment activities. A major portion of this report consists of status summaries of 27 model codes indicated as potentially useful by ONWI. The code summaries focus on three main areas: (1) the code's purpose, capabilities, and limitations; (2) status of the elements of documentation and review essential for code verification and validation; and (3) proposed application of the code for performance assessment of salt repository systems. 15 references, 6 figures, 4 tables.« less

  13. Role of Brine Chemistry and Sorption in Potential Long-Term Storage of Radioactive Waste in Geologic Salt Formations: Experimental Evaluation of Sorption Parameters

    NASA Astrophysics Data System (ADS)

    Dittrich, T. M.; Emerson, H. P.; Michael, D. P.; Reed, D. T.

    2016-12-01

    Bedded geologic salt formations have been shown to have many favorable properties for the disposal of radioactive waste (i.e., reducing conditions, fracture healing). Performance assessment (PA) modeling for a 10,000 year period for the Waste Isolation Pilot Plant (WIPP) near Carlsbad, NM have predicted an extremely low risk of radioactive material reaching the surrounding environment after the 100 year period required for creep to seal the waste panels and access shafts. Human intrusion caused by drilling operations for oil and gas exploration is the main pathway of concern for environmental release of radioactive material due to pressurized brine pockets located within the salt formation below the repository. Our work focuses on the long-term capability of salt repositories and the associated geologic media to safely isolate stored radioactive waste from the surrounding environment, even in the event of a human intrusion scenario such as a direct brine release (DBR) due to a drilling operation intersecting a brine pocket. In particular, we are revisiting the degree of conservatism in the estimated sorption partition coefficients (Kds) used in the PA model based on complementary batch and column experimental methods (Dittrich and Reimus, 2016). The main focus of this work is to investigate the role of ionic strength, solution chemistry, and oxidation state (III-VI) in actinide sorption to dolomite rock. Based on redox conditions and solution chemistry expected in the WIPP, possible actinide species include Pu(III), Pu(IV), U(IV), U(VI), Np(IV), Np(V), Am(III), and Th(IV). We will present (1) a conceptual overview of Kd use in the PA model, (2) background and evolution of the Kd ranges used, and (3) results from batch and column experiments and model predictions for Kds with WIPP-relevant geologic media. We will also briefly discuss the challenges of upscaling from lab experiments to field scale predictions, the presence of ligands (e.g., acetate, citrate, EDTA

  14. Effects of Heat Generation on Nuclear Waste Disposal in Salt

    NASA Astrophysics Data System (ADS)

    Clayton, D. J.

    2008-12-01

    Disposal of nuclear waste in salt is an established technology, as evidenced by the successful operations of the Waste Isolation Pilot Plant (WIPP) since 1999. The WIPP is located in bedded salt in southeastern New Mexico and is a deep underground facility for transuranic (TRU) nuclear waste disposal. There are many advantages for placing radioactive wastes in a geologic bedded-salt environment. One desirable mechanical characteristic of salt is that it flows plastically with time ("creeps"). The rate of salt creep is a strong function of temperature and stress differences. Higher temperatures and deviatoric stresses increase the creep rate. As the salt creeps, induced fractures may be closed and eventually healed, which then effectively seals the waste in place. With a backfill of crushed salt emplaced around the waste, the salt creep can cause the crushed salt to reconsolidate and heal to a state similar to intact salt, serving as an efficient seal. Experiments in the WIPP were conducted to investigate the effects of heat generation on the important phenomena and processes in and around the repository (Munson et al. 1987; 1990; 1992a; 1992b). Brine migration towards the heaters was induced from the thermal gradient, while salt creep rates showed an exponential dependence on temperature. The project "Backfill and Material Behavior in Underground Salt Repositories, Phase II" (BAMBUS II) studied the crushed salt backfill and material behavior with heat generation at the Asse mine located near Remlingen, Germany (Bechthold et al. 2004). Increased salt creep rates and significant reconsolidation of the crushed salt were observed at the termination of the experiment. Using the data provided from both projects, exploratory modeling of the thermal-mechanical response of salt has been conducted with varying thermal loading and waste spacing. Increased thermal loading and decreased waste spacing drive the system to higher temperatures, while both factors are desired to

  15. Radioactive Wastes.

    PubMed

    Choudri, B S; Charabi, Yassine; Baawain, Mahad; Ahmed, Mushtaque

    2017-10-01

    Papers reviewed herein present a general overview of radioactive waste related activities around the world in 2016. The current reveiw include studies related to safety assessments, decommission and decontamination of nuclear facilities, fusion facilities, transportation. Further, the review highlights on management solutions for the final disposal of low and high level radioactive wastes (LLW and HLW), interim storage and final disposal options for spent fuel (SF), and tritiated wastes, with a focus on environmental impacts due to the mobility of radionuclides in ecosystem, water and soil alongwith other progress made in the management of radioactive wastes.

  16. Treatment of radioactive waste salt by using synthetic silica-based phosphate composite for de-chlorination and solidification

    NASA Astrophysics Data System (ADS)

    Cho, In-Hak; Park, Hwan-Seo; Lee, Ki-Rak; Choi, Jung-Hun; Kim, In-Tae; Hur, Jin Mok; Lee, Young-Seak

    2017-09-01

    In the radioactive waste management, waste salts as metal chloride generated from a pyrochemical process to recover uranium and transuranic elements are one of problematic wastes due to their intrinsic properties such as high volatility and low compatibility with conventional glasses. This study reports a method to stabilize and solidify LiCl waste via de-chlorination using a synthetic composite, U-SAP (SiO2-Al2O3-B2O3-Fe2O3-P2O5) prepared by a sol-gel process. The composite was reacted with alkali metal elements to produce some metal aluminosilicates, aluminophosphates or orthophosphate as a crystalline or amorphous compound. Different from the original SAP (SiO2-Al2O3-P2O5), the reaction product of U-SAP could be successfully fabricated as a monolithic wasteform without a glassy binder at a proper reaction/consolidation condition. From the results of the FE-SEM, FT-IR and MAS-NMR analysis, it could be inferred that the Si-rich phase and P-rich phase as a glassy grains would be distributed in tens of nm scale, where alkali metal elements would be chemically interacted with Si-rich or P-rich region in the virgin U-SAP composite and its products was vitrified into a silicate or phosphate glass after a heat-treatment at 1150 °C. The PCT-A (Product Consistency Test, ASTM-1208) revealed that the mass loss of Cs and Sr in the U-SAP wasteform had a range of 10-3∼10-1 g/m2 and the leach-resistance of the U-SAP wasteform was comparable to other conventional wasteforms. From the U-SAP method, LiCl waste salt was effectively stabilized and solidified with high waste loading and good leach-resistance.

  17. Radioactive Wastes. Revised.

    ERIC Educational Resources Information Center

    Fox, Charles H.

    This publication is one of a series of information booklets for the general public published by the United States Atomic Energy Commission. This booklet deals with the handling, processing and disposal of radioactive wastes. Among the topics discussed are: The Nature of Radioactive Wastes; Waste Management; and Research and Development. There are…

  18. Waste minimization for commercial radioactive materials users generating low-level radioactive waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fischer, D.K.; Gitt, M.; Williams, G.A.

    1991-07-01

    The objective of this document is to provide a resource for all states and compact regions interested in promoting the minimization of low-level radioactive waste (LLW). This project was initiated by the Commonwealth of Massachusetts, and Massachusetts waste streams have been used as examples; however, the methods of analysis presented here are applicable to similar waste streams generated elsewhere. This document is a guide for states/compact regions to use in developing a system to evaluate and prioritize various waste minimization techniques in order to encourage individual radioactive materials users (LLW generators) to consider these techniques in their own independent evaluations.more » This review discusses the application of specific waste minimization techniques to waste streams characteristic of three categories of radioactive materials users: (1) industrial operations using radioactive materials in the manufacture of commercial products, (2) health care institutions, including hospitals and clinics, and (3) educational and research institutions. Massachusetts waste stream characterization data from key radioactive materials users in each category are used to illustrate the applicability of various minimization techniques. The utility group is not included because extensive information specific to this category of LLW generators is available in the literature.« less

  19. Molten salt oxidation of organic hazardous waste with high salt content.

    PubMed

    Lin, Chengqian; Chi, Yong; Jin, Yuqi; Jiang, Xuguang; Buekens, Alfons; Zhang, Qi; Chen, Jian

    2018-02-01

    Organic hazardous waste often contains some salt, owing to the widespread use of alkali salts during industrial manufacturing processes. These salts cause complications during the treatment of this type of waste. Molten salt oxidation is a flameless, robust thermal process, with inherent capability of destroying the organic constituents of wastes, while retaining the inorganic ingredients in the molten salt. In the present study, molten salt oxidation is employed for treating a typical organic hazardous waste with a high content of alkali salts. The hazardous waste derives from the production of thiotriazinone. Molten salt oxidation experiments have been conducted using a lab-scale molten salt oxidation reactor, and the emissions of CO, NO, SO 2 , HCl and dioxins are studied. Impacts are investigated from the composition of the molten salts, the types of feeding tube, the temperature of molten carbonates and the air factor. Results show that the waste can be oxidised effectively in a molten salt bath. Temperature of molten carbonates plays the most important role. With the temperature rising from 600 °C to 750 °C, the oxidation efficiency increases from 91.1% to 98.3%. Compared with the temperature, air factor has but a minor effect, as well as the composition of the molten salts and the type of feeding tube. The molten carbonates retain chlorine with an efficiency higher than 99.9% and the emissions of dioxins are below 8 pg TEQ g -1 sample. The present study shows that molten salt oxidation is a promising alternative for the disposal of organic hazardous wastes containing a high salt content.

  20. Method for solidification of radioactive and other hazardous waste

    DOEpatents

    Anshits, Alexander G.; Vereshchagina, Tatiana A.; Voskresenskaya, Elena N.; Kostin, Eduard M.; Pavlov, Vyacheslav F.; Revenko, Yurii A.; Tretyakov, Alexander A.; Sharonova, Olga M.; Aloy, Albert S.; Sapozhnikova, Natalia V.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2002-01-01

    Solidification of liquid radioactive waste, and other hazardous wastes, is accomplished by the method of the invention by incorporating the waste into a porous glass crystalline molded block. The porous block is first loaded with the liquid waste and then dehydrated and exposed to thermal treatment at 50-1,000.degree. C. The porous glass crystalline molded block consists of glass crystalline hollow microspheres separated from fly ash (cenospheres), resulting from incineration of fossil plant coals. In a preferred embodiment, the porous glass crystalline blocks are formed from perforated cenospheres of grain size -400+50, wherein the selected cenospheres are consolidated into the porous molded block with a binder, such as liquid silicate glass. The porous blocks are then subjected to repeated cycles of saturating with liquid waste, and drying, and after the last cycle the blocks are subjected to calcination to transform the dried salts to more stable oxides. Radioactive liquid waste can be further stabilized in the porous blocks by coating the internal surface of the block with metal oxides prior to adding the liquid waste, and by coating the outside of the block with a low-melting glass or a ceramic after the waste is loaded into the block.

  1. Process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOEpatents

    Colombo, Peter; Kalb, Paul D.; Heiser, III, John H.

    1997-11-14

    The present invention provides a method for encapsulating and stabilizing radioactive, hazardous and mixed wastes in a modified sulfur cement composition. The waste may be incinerator fly ash or bottom ash including radioactive contaminants, toxic metal salts and other wastes commonly found in refuse. The process may use glass fibers mixed into the composition to improve the tensile strength and a low concentration of anhydrous sodium sulfide to reduce toxic metal solubility. The present invention preferably includes a method for encapsulating radioactive, hazardous and mixed wastes by combining substantially anhydrous wastes, molten modified sulfur cement, preferably glass fibers, as well as anhydrous sodium sulfide or calcium hydroxide or sodium hydroxide in a heated double-planetary orbital mixer. The modified sulfur cement is preheated to about 135.degree..+-.5.degree. C., then the remaining substantially dry components are added and mixed to homogeneity. The homogeneous molten mixture is poured or extruded into a suitable mold. The mold is allowed to cool, while the mixture hardens, thereby immobilizing and encapsulating the contaminants present in the ash.

  2. Radioactive Waste.

    ERIC Educational Resources Information Center

    Blaylock, B. G.

    1978-01-01

    Presents a literature review of radioactive waste disposal, covering publications of 1976-77. Some of the studies included are: (1) high-level and long-lived wastes, and (2) release and burial of low-level wastes. A list of 42 references is also presented. (HM)

  3. Method for calcining radioactive wastes

    DOEpatents

    Bjorklund, William J.; McElroy, Jack L.; Mendel, John E.

    1979-01-01

    This invention relates to a method for the preparation of radioactive wastes in a low leachability form by calcining the radioactive waste on a fluidized bed of glass frit, removing the calcined waste to melter to form a homogeneous melt of the glass and the calcined waste, and then solidifying the melt to encapsulate the radioactive calcine in a glass matrix.

  4. [Investigation of radioactivity measurement of medical radioactive waste].

    PubMed

    Koizumi, Kiyoshi; Masuda, Kazutaka; Kusakabe, Kiyoko; Kinoshita, Fujimi; Kobayashi, Kazumi; Yamamoto, Tetsuo; Kanaya, Shinichi; Kida, Tetsuo; Yanagisawa, Masamichi; Iwanaga, Tetsuo; Ikebuchi, Hideharu; Kusama, Keiji; Namiki, Nobuo; Okuma, Hiroshi; Fujimura, Yoko; Horikoshi, Akiko; Tanaka, Mamoru

    2004-11-01

    To explore the possibility of which medical radioactive wastes could be disposed as general wastes after keeping them a certain period of time and confirming that their radioactivity reach a background level (BGL), we made a survey of these wastes in several nuclear medicine facilities. The radioactive wastes were collected for one week, packed in a box according to its half-life, and measured its radioactivity by scintillation survey meter with time. Some wastes could reach a BGL within 10 times of half-life, but 19% of the short half-life group (group 1) including 99mTc and 123I, and 8% of the middle half-life group (group 2) including 67Ga, (111)In, and 201Tl did not reach a BGL within 20 times of half-life. A reason for delaying the time of reaching a BGL might be partially attributed to high initial radiation dose rate or heavy package weight. However, mixing with the nuclides of longer half-life was estimated to be the biggest factor affecting this result. When disposing medical radioactive wastes as general wastes, it is necessary to avoid mixing with radionuclide of longer half-life and confirm that it reaches a BGL by actual measurement.

  5. Waste minimization for commercial radioactive materials users generating low-level radioactive waste. Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fischer, D.K.; Gitt, M.; Williams, G.A.

    1991-07-01

    The objective of this document is to provide a resource for all states and compact regions interested in promoting the minimization of low-level radioactive waste (LLW). This project was initiated by the Commonwealth of Massachusetts, and Massachusetts waste streams have been used as examples; however, the methods of analysis presented here are applicable to similar waste streams generated elsewhere. This document is a guide for states/compact regions to use in developing a system to evaluate and prioritize various waste minimization techniques in order to encourage individual radioactive materials users (LLW generators) to consider these techniques in their own independent evaluations.more » This review discusses the application of specific waste minimization techniques to waste streams characteristic of three categories of radioactive materials users: (1) industrial operations using radioactive materials in the manufacture of commercial products, (2) health care institutions, including hospitals and clinics, and (3) educational and research institutions. Massachusetts waste stream characterization data from key radioactive materials users in each category are used to illustrate the applicability of various minimization techniques. The utility group is not included because extensive information specific to this category of LLW generators is available in the literature.« less

  6. ASSESSMENT OF RADIOACTIVE AND NON-RADIOACTIVE CONTAMINANTS FOUND IN LOW LEVEL RADIOACTIVE WASTE STREAMS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    R.H. Little, P.R. Maul, J.S.S. Penfoldag

    2003-02-27

    This paper describes and presents the findings from two studies undertaken for the European Commission to assess the long-term impact upon the environment and human health of non-radioactive contaminants found in various low level radioactive waste streams. The initial study investigated the application of safety assessment approaches developed for radioactive contaminants to the assessment of nonradioactive contaminants in low level radioactive waste. It demonstrated how disposal limits could be derived for a range of non-radioactive contaminants and generic disposal facilities. The follow-up study used the same approach but undertook more detailed, disposal system specific calculations, assessing the impacts of bothmore » the non-radioactive and radioactive contaminants. The calculations undertaken indicated that it is prudent to consider non-radioactive, as well as radioactive contaminants, when assessing the impacts of low level radioactive waste disposal. For some waste streams with relatively low concentrations of radionuclides, the potential post-closure disposal impacts from non-radioactive contaminants can be comparable with the potential radiological impacts. For such waste streams there is therefore an added incentive to explore options for recycling the materials involved wherever possible.« less

  7. Radioactive waste material melter apparatus

    DOEpatents

    Newman, D.F.; Ross, W.A.

    1990-04-24

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.

  8. Radioactive waste material melter apparatus

    DOEpatents

    Newman, Darrell F.; Ross, Wayne A.

    1990-01-01

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.

  9. [Microbiological Aspects of Radioactive Waste Storage].

    PubMed

    Safonov, A V; Gorbunova, O A; German, K E; Zakharova, E V; Tregubova, V E; Ershov, B G; Nazina, T N

    2015-01-01

    The article gives information about the microorganisms inhabiting in surface storages of solid radioactive waste and deep disposal sites of liquid radioactive waste. It was shown that intensification of microbial processes can lead to significant changes in the chemical composition and physical state of the radioactive waste. It was concluded that the biogeochemical processes can have both a positive effect on the safety of radioactive waste storages (immobilization of RW macrocomponents, a decreased migration ability of radionuclides) and a negative one (biogenic gas production in subterranean formations and destruction of cement matrix).

  10. Risk-informed radioactive waste classification and reclassification.

    PubMed

    Croff, Allen G

    2006-11-01

    Radioactive waste classification systems have been developed to allow wastes having similar hazards to be grouped for purposes of storage, treatment, packaging, transportation, and/or disposal. As recommended in the National Council on Radiation Protection and Measurements' Report No. 139, Risk-Based Classification of Radioactive and Hazardous Chemical Wastes, a preferred classification system would be based primarily on the health risks to the public that arise from waste disposal and secondarily on other attributes such as the near-term practicalities of managing a waste, i.e., the waste classification system would be risk informed. The current U.S. radioactive waste classification system is not risk informed because key definitions--especially that of high-level waste--are based on the source of the waste instead of its inherent characteristics related to risk. A second important reason for concluding the existing U.S. radioactive waste classification system is not risk informed is there are no general principles or provisions for exempting materials from being classified as radioactive waste which would then allow management without regard to its radioactivity. This paper elaborates the current system for classifying and reclassifying radioactive wastes in the United States, analyzes the extent to which the system is risk informed and the ramifications of its not being so, and provides observations on potential future direction of efforts to address shortcomings in the U.S. radioactive waste classification system as of 2004.

  11. Radioactive Waste Management in A Hospital

    PubMed Central

    Khan, Shoukat; Syed, AT; Ahmad, Reyaz; Rather, Tanveer A.; Ajaz, M; Jan, FA

    2010-01-01

    Most of the tertiary care hospitals use radioisotopes for diagnostic and therapeutic applications. Safe disposal of the radioactive waste is a vital component of the overall management of the hospital waste. An important objective in radioactive waste management is to ensure that the radiation exposure to an individual (Public, Radiation worker, Patient) and the environment does not exceed the prescribed safe limits. Disposal of Radioactive waste in public domain is undertaken in accordance with the Atomic Energy (Safe disposal of radioactive waste) rules of 1987 promulgated by the Indian Central Government Atomic Energy Act 1962. Any prospective plan of a hospital that intends using radioisotopes for diagnostic and therapeutic procedures needs to have sufficient infrastructural and manpower resources to keep its ambient radiation levels within specified safe limits. Regular monitoring of hospital area and radiation workers is mandatory to assess the quality of radiation safety. Records should be maintained to identify the quality and quantity of radioactive waste generated and the mode of its disposal. Radiation Safety officer plays a key role in the waste disposal operations. PMID:21475524

  12. Radioactive waste management in a hospital.

    PubMed

    Khan, Shoukat; Syed, At; Ahmad, Reyaz; Rather, Tanveer A; Ajaz, M; Jan, Fa

    2010-01-01

    Most of the tertiary care hospitals use radioisotopes for diagnostic and therapeutic applications. Safe disposal of the radioactive waste is a vital component of the overall management of the hospital waste. An important objective in radioactive waste management is to ensure that the radiation exposure to an individual (Public, Radiation worker, Patient) and the environment does not exceed the prescribed safe limits. Disposal of Radioactive waste in public domain is undertaken in accordance with the Atomic Energy (Safe disposal of radioactive waste) rules of 1987 promulgated by the Indian Central Government Atomic Energy Act 1962. Any prospective plan of a hospital that intends using radioisotopes for diagnostic and therapeutic procedures needs to have sufficient infrastructural and manpower resources to keep its ambient radiation levels within specified safe limits. Regular monitoring of hospital area and radiation workers is mandatory to assess the quality of radiation safety. Records should be maintained to identify the quality and quantity of radioactive waste generated and the mode of its disposal. Radiation Safety officer plays a key role in the waste disposal operations.

  13. Projected Salt Waste Production from a Commercial Pyroprocessing Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Michael F.

    Pyroprocessing of used nuclear fuel inevitably produces salt waste from electrorefining and/or oxide reduction unit operations. Various process design characteristics can affect the actual mass of such waste produced. This paper examines both oxide and metal fuel treatment, estimates the amount of salt waste generated, and assesses potential benefit of process options to mitigate the generation of salt waste. For reference purposes, a facility is considered in which 100 MT/year of fuel is processed. Salt waste estimates range from 8 to 20 MT/year from considering numerous scenarios. It appears that some benefit may be derived from advanced processes for separatingmore » fission products from molten salt waste, but the degree of improvement is limited. Waste form production is also considered but appears to be economically unfavorable. Direct disposal of salt into a salt basin type repository is found to be the most promising with respect to minimizing the impact of waste generation on the economic feasibility and sustainability of pyroprocessing.« less

  14. Considerations of the Differences between Bedded and Domal Salt Pertaining to Disposal of Heat-Generating Nuclear Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hansen, Francis D.; Kuhlman, Kristopher L.; Sobolik, Steven R.

    Salt formations hold promise for eternal removal of nuclear waste from our biosphere. Germany and the United States have ample salt formations for this purpose, ranging from flat-bedded formations to geologically mature dome structures. As both nations revisit nuclear waste disposal options, the choice between bedded, domal, or intermediate pillow formations is once again a contemporary issue. For decades, favorable attributes of salt as a disposal medium have been extoled and evaluated, carefully and thoroughly. Yet, a sense of discovery continues as science and engineering interrogate naturally heterogeneous systems. Salt formations are impermeable to fluids. Excavation-induced fractures heal as sealmore » systems are placed or natural closure progresses toward equilibrium. Engineering required for nuclear waste disposal gains from mining and storage industries, as humans have been mining salt for millennia. This great intellectual warehouse has been honed and distilled, but not perfected, for all nuances of nuclear waste disposal. Nonetheless, nations are able and have already produced suitable license applications for radioactive waste disposal in salt. A remaining conundrum is site location. Salt formations provide isolation and geotechnical barriers reestablish impermeability after waste is placed in the geology. Between excavation and closure, physical, mechanical, thermal, chemical, and hydrological processes ensue. Positive attributes for isolation in salt have many commonalities independent of the geologic setting. In some cases, specific details of the environment will affect the disposal concept and thereby define interaction of features, events and processes, while simultaneously influencing scenario development. Here we identify and discuss high-level differences and similarities of bedded and domal salt formations. Positive geologic and engineering attributes for disposal purposes are more common among salt formations than are significant

  15. Considerations of the Differences between Bedded and Domal Salt Pertaining to Disposal of Heat-Generating Nuclear Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hansen, Francis D.; Kuhlman, Kristopher L.; Sobolik, Steven R.

    Salt formations hold promise for eternal removal of nuclear waste from our biosphere. Germany and the United States have ample salt formations for this purpose, ranging from flat-bedded formations to geologically mature dome structures. As both nations revisit nuclear waste disposal options, the choice between bedded, domal, or intermediate pillow formations is once again a contemporary issue. For decades, favorable attributes of salt as a disposal medium have been extoled and evaluated, carefully and thoroughly. Yet, a sense of discovery continues as science and engineering interrogate naturally heterogeneous systems. Salt formations are impermeable to fluids. Excavation-induced fractures heal as sealmore » systems are placed or natural closure progresses toward equilibrium. Engineering required for nuclear waste disposal gains from mining and storage industries, as humans have been mining salt for millennia. This great intellectual warehouse has been honed and distilled, but not perfected, for all nuances of nuclear waste disposal. Nonetheless, nations are able and have already produced suitable license applications for radioactive waste disposal in salt. A remaining conundrum is site location. Salt formations provide isolation, and geotechnical barriers reestablish impermeability after waste is placed in the geology. Between excavation and closure, physical, mechanical, thermal, chemical, and hydrological processes ensue. Positive attributes for isolation in salt have many commonalities independent of the geologic setting. In some cases, specific details of the environment will affect the disposal concept and thereby define interaction of features, events and processes, while simultaneously influencing scenario development. Here we identify and discuss high-level differences and similarities of bedded and domal salt formations. Positive geologic and engineering attributes for disposal purposes are more common among salt formations than are significant

  16. Radioactive waste management and practice in Bangladesh

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mollah, A.S.; Rahman, M.M.

    1993-12-31

    A large amount of low- and medium-level radioactive wastes are being generated in different parts of Bangladesh. The solid wastes are being collected in steel containers and liquid wastes are collected in plastic carboys and drums. Gaseous Ar-41 is discharged into the atmosphere through the 25 m height stack under controlled conditions after proper monitoring. The solid radioactive wastes collected are approximately 5 m{sup 3} (1988--1992) with gross beta-gamma surface dose rates from 0.30 {micro}Sv/h to 250 {micro}Sv/h. The liquid radioactive wastes are approximately 200 liters (1988--1992) with gross-beta-gamma surface dose rates from 0.30 {micro}Sv/h to 1 mSv/h. The solidmore » and liquid wastes presently being collected are mostly short lived and low level and safely stored according to international safety codes of practice. Radioactive waste packages collected during the 5-yrs study totaled 16, representing a collective volume of {approximately} 7.5 m{sup 3}. The problem of management of radioactive waste in Bangladesh is not so serious at present because the wastes arising are small now. A computerized data base has been developed to document inventory of all radioactive waste arising in the country. The current practices of collection, handling, safe storage and management of the radioactive wastes are reported in this paper.« less

  17. Radioactive waste disposal package

    DOEpatents

    Lampe, Robert F.

    1986-11-04

    A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

  18. Radioactive waste disposal package

    DOEpatents

    Lampe, Robert F.

    1986-01-01

    A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

  19. Evaluation of Terrorist Interest in Radioactive Wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McFee, J.N.; Langsted, J.M.; Young, M.E.

    2006-07-01

    Since September 11, 2001, intelligence gathered from Al Qaeda training camps in Afghanistan, and the ensuing terrorist activities, indicates nuclear material security concerns are valid. This paper reviews available information on sealed radioactive sources thought to be of interest to terrorists, and then examines typical wastes generated during environmental management activities to compare their comparative 'attractiveness' for terrorist diversion. Sealed radioactive sources have been evaluated in numerous studies to assess their security and attractiveness for use as a terrorist weapon. The studies conclude that tens of thousands of curies in sealed radioactive sources are available for potential use in amore » terrorist attack. This risk is mitigated by international efforts to find lost and abandoned sources and bring them under adequate security. However, radioactive waste has not received the same level of scrutiny to ensure security. This paper summarizes the activity and nature of radioactive sources potentially available to international terrorists. The paper then estimates radiation doses from use of radioactive sources as well as typical environmental restoration or decontamination and decommissioning wastes in a radioactive dispersal device (RDD) attack. These calculated doses indicate that radioactive wastes are, as expected, much less of a health risk than radioactive sources. The difference in radiation doses from wastes used in an RDD are four to nine orders of magnitude less than from sealed sources. We then review the International Atomic Energy Agency (IAEA) definition of 'dangerous source' in an adjusted comparison to common radioactive waste shipments generated in environmental management activities. The highest waste dispersion was found to meet only category 1-3.2 of the five step IAEA scale. A category '3' source by the IAEA standard 'is extremely unlikely, to cause injury to a person in the immediate vicinity'. The obvious conclusion of

  20. Radioactive waste storage issues

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kunz, Daniel E.

    1994-08-15

    In the United States we generate greater than 500 million tons of toxic waste per year which pose a threat to human health and the environment. Some of the most toxic of these wastes are those that are radioactively contaminated. This thesis explores the need for permanent disposal facilities to isolate radioactive waste materials that are being stored temporarily, and therefore potentially unsafely, at generating facilities. Because of current controversies involving the interstate transfer of toxic waste, more states are restricting the flow of wastes into - their borders with the resultant outcome of requiring the management (storage and disposal)more » of wastes generated solely within a state`s boundary to remain there. The purpose of this project is to study nuclear waste storage issues and public perceptions of this important matter. Temporary storage at generating facilities is a cause for safety concerns and underscores, the need for the opening of permanent disposal sites. Political controversies and public concern are forcing states to look within their own borders to find solutions to this difficult problem. Permanent disposal or retrievable storage for radioactive waste may become a necessity in the near future in Colorado. Suitable areas that could support - a nuclear storage/disposal site need to be explored to make certain the health, safety and environment of our citizens now, and that of future generations, will be protected.« less

  1. Molten salt oxidation: a versatile and promising technology for the destruction of organic-containing wastes.

    PubMed

    Yao, Zhitong; Li, Jinhui; Zhao, Xiangyang

    2011-08-01

    Molten salt oxidation (MSO), a robust thermal but non-flame process, has the inherent capability of destroying organic constituents in wastes, while retaining inorganic and radioactive materials in situ. It has been considered as an alternative to incineration and may be a solution to many waste disposal problems. The present review first describes the history and development of MSO, as well as design and engineering details, and then focuses on reaction mechanisms and its potential applications in various wastes, including hazardous wastes, medical wastes, mixed wastes, and energetic materials. Finally, the current status of and prospects for the MSO process and directions for future research are considered. Copyright © 2011 Elsevier Ltd. All rights reserved.

  2. 40 CFR 227.30 - High-level radioactive waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false High-level radioactive waste. 227.30 Section 227.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING...-level radioactive waste. High-level radioactive waste means the aqueous waste resulting from the...

  3. Fludrocortisone therapy in cerebral salt wasting.

    PubMed

    Taplin, Craig E; Cowell, Christopher T; Silink, Martin; Ambler, Geoffrey R

    2006-12-01

    Cerebral salt wasting is an increasingly recognized condition in pediatrics and is characterized by inappropriate natriuresis and volume contraction in the presence of cerebral pathology. Diagnosis can be difficult and therapy challenging. A few single case reports of the successful use of fludrocortisone exist. We report 4 patients with cerebral salt wasting, all of whom presented with hyponatremia in the presence of known intracerebral pathology. All had clinically significant hyponatremia, and 3 had hyponatremic seizures. Two of the patients also satisfied clinical criteria for diabetes insipidus. They all were treated with regimens using increased sodium and fluid administration but experienced ongoing salt wasting. Fludrocortisone was instituted in all 4 patients and in 3 resulted in rapid improvement in net sodium balance, enabling the weaning of hypertonic fluids and stabilization of serum electrolytes. In 3 patients, fludrocortisone treatment was complicated by hypokalemia, and in 1 patient by hypertension, which necessitated a dose reduction or brief cessation of therapy. Duration of therapy was 4 to 125 days. Cerebral salt wasting presents considerable management challenges; however, fludrocortisone therapy can be an effective adjunct to treatment.

  4. Reconsolidated Salt as a Geotechnical Barrier

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hansen, Francis D.; Gadbury, Casey

    Salt as a geologic medium has several attributes favorable to long-term isolation of waste placed in mined openings. Salt formations are largely impermeable and induced fractures heal as stress returns to equilibrium. Permanent isolation also depends upon the ability to construct geotechnical barriers that achieve nearly the same high-performance characteristics attributed to the native salt formation. Salt repository seal concepts often include elements of reconstituted granular salt. As a specific case in point, the Waste Isolation Pilot Plant recently received regulatory approval to change the disposal panel closure design from an engineered barrier constructed of a salt-based concrete to onemore » that employs simple run-of-mine salt and temporary bulkheads for isolation from ventilation. The Waste Isolation Pilot Plant is a radioactive waste disposal repository for defense-related transuranic elements mined from the Permian evaporite salt beds in southeast New Mexico. Its approved shaft seal design incorporates barrier components comprising salt-based concrete, bentonite, and substantial depths of crushed salt compacted to enhance reconsolidation. This paper will focus on crushed salt behavior when applied as drift closures to isolate disposal rooms during operations. Scientific aspects of salt reconsolidation have been studied extensively. The technical basis for geotechnical barrier performance has been strengthened by recent experimental findings and analogue comparisons. The panel closure change was accompanied by recognition that granular salt will return to a physical state similar to the halite surrounding it. Use of run-of-mine salt ensures physical and chemical compatibility with the repository environment and simplifies ongoing disposal operations. Our current knowledge and expected outcome of research can be assimilated with lessons learned to put forward designs and operational concepts for the next generation of salt repositories. Mined salt

  5. The safe disposal of radioactive wastes

    PubMed Central

    Kenny, A. W.

    1956-01-01

    A comprehensive review is given of the principles and problems involved in the safe disposal of radioactive wastes. The first part is devoted to a study of the basic facts of radioactivity and of nuclear fission, the characteristics of radioisotopes, the effects of ionizing radiations, and the maximum permissible levels of radioactivity for workers and for the general public. In the second part, the author describes the different types of radioactive waste—reactor wastes and wastes arising from the use of radioisotopes in hospitals and in industry—and discusses the application of the maximum permissible levels of radioactivity to their disposal and treatment, illustrating his discussion with an account of the methods practised at the principal atomic energy establishments. PMID:13374534

  6. Low-Activity Radioactive Wastes

    EPA Pesticide Factsheets

    In 2003 EPA published an Advance Notice of Proposed Rulemaking (ANPR) to collect public comment on alternatives for disposal of waste containing low concentrations of radioactive material ('low-activity' waste).

  7. High-Level Radioactive Waste.

    ERIC Educational Resources Information Center

    Hayden, Howard C.

    1995-01-01

    Presents a method to calculate the amount of high-level radioactive waste by taking into consideration the following factors: the fission process that yields the waste, identification of the waste, the energy required to run a 1-GWe plant for one year, and the uranium mass required to produce that energy. Briefly discusses waste disposal and…

  8. SELF SINTERING OF RADIOACTIVE WASTES

    DOEpatents

    McVay, T.N.; Johnson, J.R.; Struxness, E.G.; Morgan, K.Z.

    1959-12-29

    A method is described for disposal of radioactive liquid waste materials. The wastes are mixed with clays and fluxes to form a ceramic slip and disposed in a thermally insulated container in a layer. The temperature of the layer rises due to conversion of the energy of radioactivity to heat boillng off the liquid to fomn a dry mass. The dry mass is then covered with thermal insulation, and the mass is self-sintered into a leach-resistant ceramic cake by further conversion of the energy of radioactivity to heat.

  9. Stabilization/solidification of radioactive salt waste by using xSiO2-yAl2O3-zP2O5 (SAP) material at molten salt state.

    PubMed

    Park, Hwan-Seo; Kim, In-Tae; Cho, Yong-Zun; Eun, Hee-Chul; Lee, Han-Soo

    2008-12-15

    The molten salt waste from the pyroprocess is one of the problematic wastes to directly apply a conventional process such as vitrification or ceramization. This study suggested a novel method using a reactive material for metal chlorides at a molten temperature of salt waste, and then converting them into manageable product at a high temperature. The inorganic composite, SAP (SiO2-Al2O3-P2O5), synthesized by a conventional sol-gel process has three or four distinctive domains that are bonded sequentially, Si-O-Si-O-A-O-P-O-P. The P-rich phase in the SAP composite is unstable for producing a series of reactive sites when in contact with a molten LiCl salt. After the reaction, metal aluminosilicate, metal aluminophosphate, metal phosphates and gaseous chlorines are generated. From this process, the volatile salt waste is stabilized and it is possible to apply a high temperature process. The reaction products were fabricated successfully by using a borosilicate glass with an arbitrary composition as a chemical binder. There was a low possibility for the valorization of radionuclides up to 1200 degrees C, based on the result of the thermo gravimetric analysis. The Cs and Sr leach rates by the PCT-A method were about 1 x 10(-3) g/(m2 day). For the final disposal of the problematic salt waste, this approach suggested the design concept of an effective stabilizer for metal chlorides and revealed the chemical route to the fabrication of monolithic wasteform by using a composite as an example. Using this method, we could obtain a higher disposal efficiency and lower waste volume, compared with the present immobilization methods.

  10. Boron removal in radioactive liquid waste by forward osmosis membrane

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Doo Seong Hwang; Hei Min Choi; Kune Woo Lee

    2013-07-01

    This study investigated the treatment of boric acid contained in liquid radioactive waste using a forward osmosis membrane. The boron permeation through the membrane depends on the type of membrane, membrane orientation, pH of the feed solution, salt and boron concentration in the feed solution, and osmotic pressure of the draw solution. The boron flux begins to decline from pH 7 and increases with an increase of the osmotic driving force. The boron flux decreases slightly with the salt concentration, but is not heavily influenced by a low salt concentration. The boron flux increases linearly with the concentration of boron.more » No element except for boron was permeated through the FO membrane in the multi-component system. The maximum boron flux is obtained in an active layer facing a draw solution orientation of the CTA-ES membrane under conditions of less than pH 7 and high osmotic pressure. (authors)« less

  11. Permanent Disposal of Nuclear Waste in Salt

    NASA Astrophysics Data System (ADS)

    Hansen, F. D.

    2016-12-01

    Salt formations hold promise for eternal removal of nuclear waste from our biosphere. Germany and the United States have ample salt formations for this purpose, ranging from flat-bedded formations to geologically mature dome structures. Both nations are revisiting nuclear waste disposal options, accompanied by extensive collaboration on applied salt repository research, design, and operation. Salt formations provide isolation while geotechnical barriers reestablish impermeability after waste is placed in the geology. Between excavation and closure, physical, mechanical, thermal, chemical, and hydrological processes ensue. Salt response over a range of stress and temperature has been characterized for decades. Research practices employ refined test techniques and controls, which improve parameter assessment for features of the constitutive models. Extraordinary computational capabilities require exacting understanding of laboratory measurements and objective interpretation of modeling results. A repository for heat-generative nuclear waste provides an engineering challenge beyond common experience. Long-term evolution of the underground setting is precluded from direct observation or measurement. Therefore, analogues and modeling predictions are necessary to establish enduring safety functions. A strong case for granular salt reconsolidation and a focused research agenda support salt repository concepts that include safety-by-design. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Author: F. D. Hansen, Sandia National Laboratories

  12. An analysis of the technical status of high level radioactive waste and spent fuel management systems

    NASA Technical Reports Server (NTRS)

    English, T.; Miller, C.; Bullard, E.; Campbell, R.; Chockie, A.; Divita, E.; Douthitt, C.; Edelson, E.; Lees, L.

    1977-01-01

    The technical status of the old U.S. mailine program for high level radioactive nuclear waste management, and the newly-developing program for disposal of unreprocessed spent fuel was assessed. The method of long term containment for both of these waste forms is considered to be deep geologic isolation in bedded salt. Each major component of both waste management systems is analyzed in terms of its scientific feasibility, technical achievability and engineering achievability. The resulting matrix leads to a systematic identification of major unresolved technical or scientific questions and/or gaps in these programs.

  13. Landsat investigations of the northern Paradox basin, Utah and Colorado: implications for radioactive waste emplacement

    USGS Publications Warehouse

    Friedman, Jules D.; Simpson, Shirley L.

    1978-01-01

    The first stages of a remote-sensing project on the Paradox basin, part of the USGS (U.S. Geological Survey) radioactive waste-emplacement program, consisted of a review and selection of the best available satellite scanner images to use in geomorphologic and tectonic investigations of the region. High-quality Landsat images in several spectral bands (E-2260-17124 and E-5165-17030), taken under low sun angle October 9 and 10, 1975, were processed via computer for planimetric rectification, histogram analysis, linear transformation of radiance values, and edge enhancement. A lineament map of the northern Paradox basin was subsequently compiled at 1:400,000 using the enhanced Landsat base. Numerous previously unmapped northeast-trending lineaments between the Green River and Yellowcat dome; confirmatory detail on the structural control of major segments of the Colorado, Gunnison, and Dolores Rivers; and new evidence for late Phanerozoic reactivation of Precambrian basement structures are among the new contributions to the tectonics of the region. Lineament trends appear to be compatible with the postulated Colorado lineament zone, with geophysical potential-field anomalies, and with a northeast-trending basement fault pattern. Combined Landsat, geologic, and geophysical field evidence for this interpretation includes the sinuousity of the composite Salt Valley anticline, the transection of the Moab-Spanish Valley anticline on its southeastern end by northeast-striking faults, and possible transection (?) of the Moab diapir. Similarly, northeast-trending lineaments in Cottonwood Canyon and elsewhere are interpreted as manifestations of structures associated with northeasterly trends in the magnetic and gravity fields of the La Sal Mountains region. Other long northwesterly lineaments near the western termination of the Ryan Creek fault zone. may be associated with the fault zone separating the Uncompahgre horst uplift from the Paradox basin. Implications of the

  14. Delivery system for molten salt oxidation of solid waste

    DOEpatents

    Brummond, William A.; Squire, Dwight V.; Robinson, Jeffrey A.; House, Palmer A.

    2002-01-01

    The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

  15. Performance Assessment of a Generic Repository in Bedded Salt for DOE-Managed Nuclear Waste

    NASA Astrophysics Data System (ADS)

    Stein, E. R.; Sevougian, S. D.; Hammond, G. E.; Frederick, J. M.; Mariner, P. E.

    2016-12-01

    A mined repository in salt is one of the concepts under consideration for disposal of DOE-managed defense-related spent nuclear fuel (SNF) and high level waste (HLW). Bedded salt is a favorable medium for disposal of nuclear waste due to its low permeability, high thermal conductivity, and ability to self-heal. Sandia's Generic Disposal System Analysis framework is used to assess the ability of a generic repository in bedded salt to isolate radionuclides from the biosphere. The performance assessment considers multiple waste types of varying thermal load and radionuclide inventory, the engineered barrier system comprising the waste packages, backfill, and emplacement drifts, and the natural barrier system formed by a bedded salt deposit and the overlying sedimentary sequence (including an aquifer). The model simulates disposal of nearly the entire inventory of DOE-managed, defense-related SNF (excluding Naval SNF) and HLW in a half-symmetry domain containing approximately 6 million grid cells. Grid refinement captures the detail of 25,200 individual waste packages in 180 disposal panels, associated access halls, and 4 shafts connecting the land surface to the repository. Equations describing coupled heat and fluid flow and reactive transport are solved numerically with PFLOTRAN, a massively parallel flow and transport code. Simulated processes include heat conduction and convection, waste package failure, waste form dissolution, radioactive decay and ingrowth, sorption, solubility limits, advection, dispersion, and diffusion. Simulations are run to 1 million years, and radionuclide concentrations are observed within an aquifer at a point approximately 4 kilometers downgradient of the repository. The software package DAKOTA is used to sample likely ranges of input parameters including waste form dissolution rates and properties of engineered and natural materials in order to quantify uncertainty in predicted concentrations and sensitivity to input parameters. Sandia

  16. Roadmap for disposal of Electrorefiner Salt as Transuranic Waste.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rechard, Robert P.; Trone, Janis R.; Kalinina, Elena Arkadievna

    The experimental breeder reactor (EBR-II) used fuel with a layer of sodium surrounding the uranium-zirconium fuel to improve heat transfer. Disposing of EBR-II fuel in a geologic repository without treatment is not prudent because of the potentially energetic reaction of the sodium with water. In 2000, the US Department of Energy (DOE) decided to treat the sodium-bonded fuel with an electrorefiner (ER), which produces metallic uranium product, a metallic waste, mostly from the cladding, and the salt waste in the ER, which contains most of the actinides and fission products. Two waste forms were proposed for disposal in a minedmore » repository; the metallic waste, which was to be cast into ingots, and the ER salt waste, which was to be further treated to produce a ceramic waste form. However, alternative disposal pathways for metallic and salt waste streams may reduce the complexity. For example, performance assessments show that geologic repositories can easily accommodate the ER salt waste without treating it to form a ceramic waste form. Because EBR-II was used for atomic energy defense activities, the treated waste likely meets the definition of transuranic waste. Hence, disposal at the Waste Isolation Pilot Plant (WIPP) in southern New Mexico, may be feasible. This report reviews the direct disposal pathway for ER salt waste and describes eleven tasks necessary for implementing disposal at WIPP, provided space is available, DOE decides to use this alternative disposal pathway in an updated environmental impact statement, and the State of New Mexico grants permission.« less

  17. Suitability of Palestine salt dome, Anderson Co. , Texas for disposal of high-level radioactive waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Patchick, P.F.

    1980-01-01

    The suitability of Palestine salt dome, in Anderson County, Texas, is in serious doubt for a repository to isolate high-level nuclear waste because of abandoned salt brining operations. The random geographic and spatial occurrence of 15 collapse sinks over the dome may prevent safe construction of the necessary surface installations for a repository. The dissolution of salt between the caprock and dome, from at least 15 brine wells up to 500 feet deep, may permit increased rates of salt dissolution long into future geologic time. The subsurface dissolution is occurring at a rate difficult, if not impossible, to assess ormore » to calculate. It cannot be shown that this dissolution rate is insignificant to the integrity of a future repository or to ancillary features. The most recent significant collapse was 36 feet in diameter and took place in 1972. The other collapses ranged from 27 to 105 feet in diameter and from 1.5 to more than 15 feet in depth. ONWI recommends that this dome be removed from consideration as a candidate site.« less

  18. Radioactive Waste Management in Non-Nuclear Countries - 13070

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kubelka, Dragan; Trifunovic, Dejan

    2013-07-01

    This paper challenges internationally accepted concepts of dissemination of responsibilities between all stakeholders involved in national radioactive waste management infrastructure in the countries without nuclear power program. Mainly it concerns countries classified as class A and potentially B countries according to International Atomic Energy Agency. It will be shown that in such countries long term sustainability of national radioactive waste management infrastructure is very sensitive issue that can be addressed by involving regulatory body in more active way in the infrastructure. In that way countries can mitigate possible consequences on the very sensitive open market of radioactive waste management services,more » comprised mainly of radioactive waste generators, operators of end-life management facilities and regulatory body. (authors)« less

  19. Hanford Site annual dangerous waste report: Volume 2, Generator dangerous waste report, radioactive mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1994-12-31

    This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, waste number, waste designation, weight, and waste designation.

  20. The radioactive waste management policy and practice in the Czech Republic

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kucerka, M.

    1996-12-31

    In recent period, the new Czech Atomic Law is in the final stage of preparation, and the author expects that Parliament of the Czech Republic will approve it in the first half of the year 1996. Partly the law deals with new distribution of responsibilities among bodies involved in utilization of nuclear energy and ionizing radiation, the state and local authorities. The new provisions include also radioactive waste management activities. These provisions clarify the relations between radioactive waste generators and state, and define explicitly duties of waste generators. One of the most important duties is to cover all expenses formore » radioactive waste management now and in the future, including radioactive waste disposal and decommissioning of nuclear facilities. The law establishes radioactive waste management and decommissioning funds and the new, on waste generators independent radioactive waste management organization, controlled by state, to ensure the safety of inhabitants and the environment, and a optimization of expenses. Parallel to the preparation of the law, the Ministry of Industry and Trade prepares drafts of a statute of the radioactive waste management organization and its control board, and of the methodology and rules of management the radioactive waste fund. First drafts of these documents are expected to be complete in January 1996. The paper will describe recent practice and policy of the radioactive waste management including uranium mining and milling tailings, amounts of waste and its activities, economical background, and safety. A special attention will be paid to description of expected changes in connection with the new Atomic Law and expected steps and time schedule of reorganization of the radioactive waste management structure in the Czech Republic.« less

  1. Apparatus and method for radioactive waste screening

    DOEpatents

    Akers, Douglas W.; Roybal, Lyle G.; Salomon, Hopi; Williams, Charles Leroy

    2012-09-04

    An apparatus and method relating to screening radioactive waste are disclosed for ensuring that at least one calculated parameter for the measurement data of a sample falls within a range between an upper limit and a lower limit prior to the sample being packaged for disposal. The apparatus includes a radiation detector configured for detecting radioactivity and radionuclide content of the of the sample of radioactive waste and generating measurement data in response thereto, and a collimator including at least one aperture to direct a field of view of the radiation detector. The method includes measuring a radioactive content of a sample, and calculating one or more parameters from the radioactive content of the sample.

  2. A reactive distillation process for the treatment of LiCl-KCl eutectic waste salt containing rare earth chlorides

    NASA Astrophysics Data System (ADS)

    Eun, H. C.; Choi, J. H.; Kim, N. Y.; Lee, T. K.; Han, S. Y.; Lee, K. R.; Park, H. S.; Ahn, D. H.

    2016-11-01

    The pyrochemical process, which recovers useful resources (U/TRU metals) from used nuclear fuel using an electrochemical method, generates LiCl-KCl eutectic waste salt containing radioactive rare earth chlorides (RECl3). It is necessary to develop a simple process for the treatment of LiCl-KCl eutectic waste salt in a hot-cell facility. For this reason, a reactive distillation process using a chemical agent was achieved as a method to separate rare earths from the LiCl-KCl waste salt. Before conducting the reactive distillation, thermodynamic equilibrium behaviors of the reactions between rare earth (Nd, La, Ce, Pr) chlorides and the chemical agent (K2CO3) were predicted using software. The addition of the chemical agent was determined to separate the rare earth chlorides into an oxide form using these equilibrium results. In the reactive distillation test, the rare earth chlorides in LiCl-KCl eutectic salt were decontaminated at a decontamination factor (DF) of more than 5000, and were mainly converted into oxide (Nd2O3, CeO2, La2O3, Pr2O3) or oxychloride (LaOCl, PrOCl) forms. The LiCl-KCl was purified into a form with a very low concentration (<1 ppm) for the rare earth chlorides.

  3. Resistance of class C fly ash belite cement to simulated sodium sulphate radioactive liquid waste attack.

    PubMed

    Guerrero, A; Goñi, S; Allegro, V R

    2009-01-30

    The resistance of class C fly ash belite cement (FABC-2-W) to concentrated sodium sulphate salts associated with low level wastes (LLW) and medium level wastes (MLW) is discussed. This study was carried out according to the Koch and Steinegger methodology by testing the flexural strength of mortars immersed in simulated radioactive liquid waste rich in sulphate (48,000 ppm) and demineralised water (used as a reference), at 20 degrees C and 40 degrees C over a period of 180 days. The reaction mechanisms of sulphate ion with the mortar was carried out through a microstructure study, which included the use of Scanning electron microscopy (SEM), porosity and pore-size distribution and X-ray diffraction (XRD). The results showed that the FABC mortar was stable against simulated sulphate radioactive liquid waste (SSRLW) attack at the two chosen temperatures. The enhancement of mechanical properties was a result of the formation of non-expansive ettringite inside the pores and an alkaline activation of the hydraulic activity of cement promoted by the ingress of sulphate. Accordingly, the microstructure was strongly refined.

  4. Crystallization of rhenium salts in a simulated low-activity waste borosilicate glass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riley, Brian J.; McCloy, John S.; Goel, Ashutosh

    2013-04-01

    This study presents a new method for looking at the solubility of volatile species in simulated low-activity waste glass. The present study looking at rhenium salts is also applicable to real applications involving radioactive technetium salts. In this synthesis method, oxide glass powder is mixed with the volatiles species, vacuum-sealed in a fused quartz ampoule, and then heat-treated under vacuum in a furnace. This technique restricts the volatile species to the headspace above the melt but still within the sealed ampoule, thus maximizing the volatile concentration in contact with the glass. Various techniques were used to measure the solubility ofmore » rhenium in glass and include energy dispersive spectroscopy, wavelength dispersive spectroscopy, laser ablation inductively-coupled plasma mass spectroscopy, and inductively-coupled plasma optical emission spectroscopy. The Re-solubility in this glass was determined to be ~3004 parts per million Re atoms. Above this concentration, the salts separated out of the melt as inclusions and as a low viscosity molten salt phase on top of the melt observed during and after cooling. This salt phase was analyzed with X-ray diffraction, scanning electron microscopy as well as some of the other aforementioned techniques and identified to be composed of alkali perrhenate and alkali sulfate.« less

  5. Distillation and condensation of LiCl-KCl eutectic salts for a separation of pure salts from salt wastes from an electrorefining process

    NASA Astrophysics Data System (ADS)

    Eun, Hee Chul; Yang, Hee Chul; Lee, Han Soo; Kim, In Tae

    2009-12-01

    Salt separation and recovery from the salt wastes generated from a pyrochemical process is necessary to minimize the high-level waste volumes and to stabilize a final waste form. In this study, the thermal behavior of the LiCl-KCl eutectic salts containing rare earth oxychlorides or oxides was investigated during a vacuum distillation and condensation process. LiCl was more easily vaporized than the other salts (KCl and LiCl-KCl eutectic salt). Vaporization characteristics of LiCl-KCl eutectic salts were similar to that of KCl. The temperature to obtain the vaporization flux (0.1 g min -1 cm -2) was decreased by much as 150 °C by a reduction of the ambient pressure from 5 Torr to 0.5 Torr. Condensation behavior of the salt vapors was different with the ambient pressure. Almost all of the salt vapors were condensed and were formed into salt lumps during a salt distillation at the ambient pressure of 0.5 Torr and they were collected in the condensed salt storage. However, fine salt particles were formed when the salt distillation was performed at 10 Torr and it is difficult for them to be recovered. Therefore, it is thought that a salt vacuum distillation and condensation should be performed to recover almost all of the vaporized salts at a pressure below 0.5 Torr.

  6. The potential for using slags activated with near neutral salts as immobilisation matrices for nuclear wastes containing reactive metals

    NASA Astrophysics Data System (ADS)

    Bai, Y.; Collier, N. C.; Milestone, N. B.; Yang, C. H.

    2011-06-01

    The UK currently uses composite blends of Portland cement and other inorganic cementitious material such as blastfurnace slag and pulverised fuel ash to encapsulate or immobilise intermediate and low level radioactive wastes. Typically levels up 9:1 blast furnace slag:Portland cement or 4:1 pulverised fuel ash:Portland cement are used. Whilst these systems offer many advantages, their high pH causes corrosion of various metallic intermediate level radioactive wastes. To address this issue, lower pH/weakly alkaline cementitious systems have to be explored. While the blast furnace slag:Portland cement system is referred to as a composite cement system, the underlying reaction is actually an indirect activation of the slag hydration by the calcium hydroxide generated by the cement hydration, and by the alkali ions and gypsum present in the cement. However, the slag also can be activated directly with activators, creating a system known as alkali-activated slag. Whilst these activators used are usually strongly alkaline, weakly alkaline and near neutral salts can also be used. In this paper, the potential for using weakly alkaline and near neutral salts to activate slag in this manner is reviewed and discussed, with particular emphasis placed on the immobilisation of reactive metallic nuclear wastes.

  7. Subseabed storage of radioactive waste

    NASA Astrophysics Data System (ADS)

    Bell, Peter M.

    The subject of the storage of nuclear wastes products incites emotional responses from the public, and thus the U.S. Subseabed Disposal Program will have to make a good case for waste storage beneath the ocean floor. The facts attendant, however, describe circumstances necessitating cool-headed analysis to achieve a solution to the growing nuclear waste problem. Emotion aside, a good case indeed is being made for safe disposal beneath the ocean floor.The problems of nuclear waste storage are acute. A year ago, U.S. military weapons production had accumulated over seventy-five million gallons of high-level radioactive liquid waste; solid wastes, such as spent nuclear fuel rods from reactors, amounted to more than 12,000 tons. These wastes are corrosive and will release heat for 1000 years or more. The wastes will remain dangerously radioactive for a period of 10,000 years. There are advantages in storing the wastes on land, in special underground repositories, or on the surface. These include the accessibility to monitor the waste and the possibility of taking action should a container rupture occur, and thus the major efforts to determine suitable disposal at this time are focused on land-based storage. New efforts, not to be confused with ocean dumping practices of the past, are demonstrating that waste containers isolated in the clays and sediments of the ocean floor may be superior (Environ. Sci. Tech., 16, 28A-37A 1982).

  8. Hanford Site annual dangerous waste report: Volume 4, Waste Management Facility report, Radioactive mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1994-12-31

    This report contains information on radioactive mixed wastes at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, handling method and containment vessel, waste number, waste designation and amount of waste.

  9. Public attitudes about radioactive waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bisconti, A.S.

    Public attitudes about radioactive waste are changeable. That is my conclusion from eight years of social science research which I have directed on this topic. The fact that public attitudes about radioactive waste are changeable is well-known to the hands-on practitioners who have opportunities to talk with the public and respond to their concerns-practitioners like Ginger King, who is sharing the podium with me today. The public`s changeability and open-mindedness are frequently overlooked in studies that focus narrowly on fear and dread. Such studies give the impression that the outlook for waste disposal solutions is dismal. I believe that impressionmore » is misleading, and I`d like to share research findings with you today that give a broader perspective.« less

  10. Canister arrangement for storing radioactive waste

    DOEpatents

    Lorenzo, D.K.; Van Cleve, J.E. Jr.

    1980-04-23

    The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

  11. Canister arrangement for storing radioactive waste

    DOEpatents

    Lorenzo, Donald K.; Van Cleve, Jr., John E.

    1982-01-01

    The subject invention relates to a canister arrangement for jointly storing high level radioactive chemical waste and metallic waste resulting from the reprocessing of nuclear reactor fuel elements. A cylindrical steel canister is provided with an elongated centrally disposed billet of the metallic waste and the chemical waste in vitreous form is disposed in the annulus surrounding the billet.

  12. NRC Monitoring of Salt Waste Disposal at the Savannah River Site - 13147

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pinkston, Karen E.; Ridge, A. Christianne; Alexander, George W.

    2013-07-01

    As part of monitoring required under Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 (NDAA), the NRC staff reviewed an updated DOE performance assessment (PA) for salt waste disposal at the Saltstone Disposal Facility (SDF). The NRC staff concluded that it has reasonable assurance that waste disposal at the SDF meets the 10 CFR 61 performance objectives for protection of individuals against intrusion (chap.61.42), protection of individuals during operations (chap.61.43), and site stability (chap.61.44). However, based on its evaluation of DOE's results and independent sensitivity analyses conducted with DOE's models, the NRC staffmore » concluded that it did not have reasonable assurance that DOE's disposal activities at the SDF meet the performance objective for protection of the general population from releases of radioactivity (chap.61.41) evaluated at a dose limit of 0.25 mSv/yr (25 mrem/yr) total effective dose equivalent (TEDE). NRC staff also concluded that the potential dose to a member of the public is expected to be limited (i.e., is expected to be similar to or less than the public dose limit in chap.20.1301 of 1 mSv/yr [100 mrem/yr] TEDE) and is expected to occur many years after site closure. The NRC staff used risk insights gained from review of the SDF PA, its experience monitoring DOE disposal actions at the SDF over the last 5 years, as well as independent analysis and modeling to identify factors that are important to assessing whether DOE's disposal actions meet the performance objectives. Many of these factors are similar to factors identified in the NRC staff's 2005 review of salt waste disposal at the SDF. Key areas of interest continue to be waste form and disposal unit degradation, the effectiveness of infiltration and erosion controls, and estimation of the radiological inventory. Based on these factors, NRC is revising its plan for monitoring salt waste disposal at the SDF in coordination with

  13. Leveraging Radioactive Waste Disposal at WIPP for Science

    NASA Astrophysics Data System (ADS)

    Rempe, N. T.

    2008-12-01

    Salt mines are radiologically much quieter than other underground environments because of ultra-low concentrations of natural radionuclides (U, Th, and K) in the host rock; therefore, the Waste Isolation Pilot Plant (WIPP), a government-owned, 655m deep geologic repository that disposes of radioactive waste in thick salt near Carlsbad, New Mexico, has for the last 15 years hosted highly radiation-sensitive experiments. Incidentally, Nature started her own low background experiment 250ma ago, preserving viable bacteria, cellulose, and DNA in WIPP salt. The Department of Energy continues to make areas of the WIPP underground available for experiments, freely offering its infrastructure and access to this unique environment. Even before WIPP started disposing of waste in 1999, the Room-Q alcove (25m x 10m x 4m) housed a succession of small experiments. They included development and calibration of neutral-current detectors by Los Alamos National Laboratory (LANL) for the Sudbury Neutrino Observatory, a proof-of-concept by Ohio State University of a flavor-sensitive neutrino detector for supernovae, and research by LANL on small solid- state dark matter detectors. Two currently active experiments support the search for neutrino-less double beta decay as a tool to better define the nature and mass of the neutrino. That these delicate experiments are conducted in close vicinity to, but not at all affected by, megacuries of radioactive waste reinforces the safety argument for the repository. Since 2003, the Majorana collaboration is developing and testing various detector designs inside a custom- built clean room in the Room-Q alcove. Already low natural background readings are reduced further by segmenting the germanium detectors, which spatially and temporally discriminates background radiation. The collaboration also demonstrated safe copper electro-forming underground, which minimizes cosmogenic background in detector assemblies. The largest currently used experimental

  14. Radioactive Liquid Waste Treatment Facility: Environmental Information Document

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Haagenstad, H.T.; Gonzales, G.; Suazo, I.L.

    1993-11-01

    At Los Alamos National Laboratory (LANL), the treatment of radioactive liquid waste is an integral function of the LANL mission: to assure U.S. military deterrence capability through nuclear weapons technology. As part of this mission, LANL conducts nuclear materials research and development (R&D) activities. These activities generate radioactive liquid waste that must be handled in a manner to ensure protection of workers, the public, and the environment. Radioactive liquid waste currently generated at LANL is treated at the Radioactive Liquid Waste Treatment Facility (RLWTF), located at Technical Area (TA)-50. The RLWTF is 30 years old and nearing the end ofmore » its useful design life. The facility was designed at a time when environmental requirements, as well as more effective treatment technologies, were not inherent in engineering design criteria. The evolution of engineering design criteria has resulted in the older technology becoming less effective in treating radioactive liquid wastestreams in accordance with current National Pollutant Discharge Elimination System (NPDES) and Department of Energy (DOE) regulatory requirements. Therefore, to support ongoing R&D programs pertinent to its mission, LANL is in need of capabilities to efficiently treat radioactive liquid waste onsite or to transport the waste off site for treatment and/or disposal. The purpose of the EID is to provide the technical baseline information for subsequent preparation of an Environmental Impact Statement (EIS) for the RLWTF. This EID addresses the proposed action and alternatives for meeting the purpose and need for agency action.« less

  15. Safe disposal of radionuclides in low-level radioactive-waste repository sites; Low-level radioactive-waste disposal workshop, U.S. Geological Survey, July 11-16, 1987, Big Bear Lake, Calif., Proceedings

    USGS Publications Warehouse

    Bedinger, Marion S.; Stevens, Peter R.

    1990-01-01

    In the United States, low-level radioactive waste is disposed by shallow-land burial. Low-level radioactive waste generated by non-Federal facilities has been buried at six commercially operated sites; low-level radioactive waste generated by Federal facilities has been buried at eight major and several minor Federally operated sites (fig. 1). Generally, low-level radioactive waste is somewhat imprecisely defined as waste that does not fit the definition of high-level radioactive waste and does not exceed 100 nCi/g in the concentration of transuranic elements. Most low-level radioactive waste generated by non-Federal facilities is generated at nuclear powerplants; the remainder is generated primarily at research laboratories, hospitals, industrial facilities, and universities. On the basis of half lives and concentrations of radionuclides in low-level radioactive waste, the hazard associated with burial of such waste generally lasts for about 500 years. Studies made at several of the commercially and Federally operated low-level radioactive-waste repository sites indicate that some of these sites have not provided containment of waste nor the expected protection of the environment.

  16. 40 CFR 147.3005 - Radioactive waste injection wells.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Radioactive waste injection wells. 147.3005 Section 147.3005 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER... the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3005 Radioactive waste injection...

  17. 40 CFR 147.3005 - Radioactive waste injection wells.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Radioactive waste injection wells. 147... PROGRAMS (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3005 Radioactive waste injection...

  18. 40 CFR 147.3005 - Radioactive waste injection wells.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Radioactive waste injection wells. 147... PROGRAMS (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3005 Radioactive waste injection...

  19. 40 CFR 147.3005 - Radioactive waste injection wells.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Radioactive waste injection wells. 147... PROGRAMS (CONTINUED) STATE, TRIBAL, AND EPA-ADMINISTERED UNDERGROUND INJECTION CONTROL PROGRAMS Lands of the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3005 Radioactive waste injection...

  20. Radioactive waste disposal in the marine environment

    NASA Astrophysics Data System (ADS)

    Anderson, D. R.

    In order to find the optimal solution to waste disposal problems, it is necessary to make comparisons between disposal media. It has become obvious to many within the scientific community that the single medium approach leads to over protection of one medium at the expense of the others. Cross media comparisons are being conducted in the Department of Energy ocean disposal programs for several radioactive wastes. Investigations in three areas address model development, comparisons of laboratory tests with field results and predictions, and research needs in marine disposal of radioactive waste. Tabulated data are included on composition of liquid high level waste and concentration of some natural radionuclides in the sea.

  1. 10 CFR 72.108 - Spent fuel, high-level radioactive waste, or reactor-related greater than Class C waste...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Spent fuel, high-level radioactive waste, or reactor... RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE Siting Evaluation Factors § 72.108 Spent fuel, high-level radioactive waste, or reactor-related greater than Class C waste transportation. The...

  2. 10 CFR 72.108 - Spent fuel, high-level radioactive waste, or reactor-related greater than Class C waste...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Spent fuel, high-level radioactive waste, or reactor... RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE Siting Evaluation Factors § 72.108 Spent fuel, high-level radioactive waste, or reactor-related greater than Class C waste transportation. The...

  3. Transporting Radioactive Waste: An Engineering Activity. Grades 5-12.

    ERIC Educational Resources Information Center

    HAZWRAP, The Hazardous Waste Remedial Actions Program.

    This brochure contains an engineering activity for upper elementary, middle school, and high school students that examines the transportation of radioactive waste. The activity is designed to inform students about the existence of radioactive waste and its transportation to disposal sites. Students experiment with methods to contain the waste and…

  4. Alternative methods of salt disposal at the seven salt sites for a nuclear waste repository

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1987-02-01

    This study discusses the various alternative salt management techniques for the disposal of excess mined salt at seven potentially acceptable nuclear waste repository sites: Deaf Smith and Swisher Counties, Texas; Richton and Cypress Creek Domes, Mississippi; Vacherie Dome, Louisiana; and Davis and Lavender Canyons, Utah. Because the repository development involves the underground excavation of corridors and waste emplacement rooms, in either bedded or domed salt formations, excess salt will be mined and must be disposed of offsite. The salt disposal alternatives examined for all the sites include commercial use, ocean disposal, deep well injection, landfill disposal, and underground mine disposal.more » These alternatives (and other site-specific disposal methods) are reviewed, using estimated amounts of excavated, backfilled, and excess salt. Methods of transporting the excess salt are discussed, along with possible impacts of each disposal method and potential regulatory requirements. A preferred method of disposal is recommended for each potentially acceptable repository site. 14 refs., 5 tabs.« less

  5. Immobilization of organic radioactive and non-radioactive liquid waste in a composite matrix

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Galkin, Anatoliy; Gelis, Artem V.; Castiglioni, Andrew J.

    A method for immobilizing liquid radioactive waste is provided, the method having the steps of mixing waste with polymer to form a non-liquid waste; contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to cause the polymer, waste, and filler to irreversibly bind in a solid phase, and compressing the solid phase into a monolith. The invention also provides a method for immobilizing liquid radioactive waste containing tritium, the method having the steps of mixing liquid waste with polymer to convert the liquid waste to a non-liquid waste, contacting the non-liquid waste with amore » solidifying agent to create a mixture, heating the mixture to form homogeneous, chemically stable solid phase, and compressing the chemically stable solid phase into a final waste form, wherein the polymer comprises approximately a 9:1 weight ratio mixture of styrene block co-polymers and cross linked co-polymers of acrylamides.« less

  6. Radioactive Waste Management and Nuclear Facility Decommissioning Progress in Iraq - 13216

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Al-Musawi, Fouad; Shamsaldin, Emad S.; Jasim, Hadi

    2013-07-01

    Management of Iraq's radioactive wastes and decommissioning of Iraq's former nuclear facilities are the responsibility of Iraq's Ministry of Science and Technology (MoST). The majority of Iraq's former nuclear facilities are in the Al-Tuwaitha Nuclear Research Center located a few kilometers from the edge of Baghdad. These facilities include bombed and partially destroyed research reactors, a fuel fabrication facility and radioisotope production facilities. Within these facilities are large numbers of silos, approximately 30 process or waste storage tanks and thousands of drums of uncharacterised radioactive waste. There are also former nuclear facilities/sites that are outside of Al-Tuwaitha and these includemore » the former uranium processing and waste storage facility at Jesira, the dump site near Adaya, the former centrifuge facility at Rashdiya and the former enrichment plant at Tarmiya. In 2005, Iraq lacked the infrastructure needed to decommission its nuclear facilities and manage its radioactive wastes. The lack of infrastructure included: (1) the lack of an organization responsible for decommissioning and radioactive waste management, (2) the lack of a storage facility for radioactive wastes, (3) the lack of professionals with experience in decommissioning and modern waste management practices, (4) the lack of laws and regulations governing decommissioning or radioactive waste management, (5) ongoing security concerns, and (6) limited availability of electricity and internet. Since its creation eight years ago, the MoST has worked with the international community and developed an organizational structure, trained staff, and made great progress in managing radioactive wastes and decommissioning Iraq's former nuclear facilities. This progress has been made, despite the very difficult implementing conditions in Iraq. Within MoST, the Radioactive Waste Treatment and Management Directorate (RWTMD) is responsible for waste management and the Iraqi

  7. Radioactive waste material disposal

    DOEpatents

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

    1995-10-24

    The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide. 3 figs.

  8. Radioactive waste material disposal

    DOEpatents

    Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

    1995-01-01

    The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide.

  9. Karlsruhe Database for Radioactive Wastes (KADABRA) - Accounting and Management System for Radioactive Waste Treatment - 12275

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Himmerkus, Felix; Rittmeyer, Cornelia

    2012-07-01

    The data management system KADABRA was designed according to the purposes of the Cen-tral Decontamination Department (HDB) of the Wiederaufarbeitungsanlage Karlsruhe Rueckbau- und Entsorgungs-GmbH (WAK GmbH), which is specialized in the treatment and conditioning of radioactive waste. The layout considers the major treatment processes of the HDB as well as regulatory and legal requirements. KADABRA is designed as an SAG ADABAS application on IBM system Z mainframe. The main function of the system is the data management of all processes related to treatment, transfer and storage of radioactive material within HDB. KADABRA records the relevant data concerning radioactive residues, interimmore » products and waste products as well as the production parameters relevant for final disposal. Analytical data from the laboratory and non destructive assay systems, that describe the chemical and radiological properties of residues, production batches, interim products as well as final waste products, can be linked to the respective dataset for documentation and declaration. The system enables the operator to trace the radioactive material through processing and storage. Information on the actual sta-tus of the material as well as radiological data and storage position can be gained immediately on request. A variety of programs accessed to the database allow the generation of individual reports on periodic or special request. KADABRA offers a high security standard and is constantly adapted to the recent requirements of the organization. (authors)« less

  10. 77 FR 20077 - Request for a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-03

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Export Radioactive Waste Pursuant to 10 CFR..., 2012, radioactive waste tons of or disposal by a February 16, 2012, XW019, in the form of ash radioactive waste licensed facility 11005986. and non-conforming as contaminated in Mexico. material. ash and...

  11. Integrating natural and social sciences to inspire public confidence in radioactive waste policy case study - Committee on radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Usher, Sam

    2007-07-01

    Integrating Natural and Social Sciences to Inspire Public Confidence in Radioactive Waste Policy Case Study: Committee on Radioactive Waste Management Implementing effective long-term radioactive waste management policy is challenging, and both UK and international experience is littered with policy and programme failures. Policy must not only be underpinned by sound science and technical rationale, it must also inspire the confidence of the public and other stakeholders. However, in today's modern society, communities will not simply accept the word of scientists for setting policy based purely on technical grounds. This is particularly so in areas where there are significant social andmore » ethical issues, such as radioactive waste disposal. To develop and implement effective policy, governments, waste owners and implementing bodies must develop processes which effectively integrate both complex technical and scientific issues, with equally challenging social and ethical concerns. These integrating processes must marry often intricate technical issues with broad public and stakeholder engagement programmes, in programmes which can expect the highest levels of public scrutiny, and must invariably be delivered within challenging time and budget constraints. This paper considers a model for how such integrating processes can be delivered. The paper reviews, as a case study, how such challenges were overcome by the Committee on Radioactive Waste Management (CoRWM), which, in July 2006, made recommendations to the UK government for the establishment of a long-term radioactive waste policy. Its recommendations were underpinned by sound science, but also engendered public confidence through undertaking the largest and most significant deliberative public and stakeholder engagement programme on a complex policy issue in the UK. Effective decision-making was enabled through the integration of both proven and bespoke methodologies, including Multi-criteria Decision

  12. Kansas State Briefing Book on low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-07-01

    The Kansas State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Kansas. The profile is the result of a survey of radioactive material licensees in Kansas. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developedmore » through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may affect waste management practices in Kansas.« less

  13. 10 CFR 72.128 - Criteria for spent fuel, high-level radioactive waste, reactor-related greater than Class C waste...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ..., reactor-related greater than Class C waste, and other radioactive waste storage and handling. 72.128... STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE General Design Criteria § 72.128 Criteria for spent fuel, high-level radioactive waste, reactor...

  14. 10 CFR 72.128 - Criteria for spent fuel, high-level radioactive waste, reactor-related greater than Class C waste...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ..., reactor-related greater than Class C waste, and other radioactive waste storage and handling. 72.128... STORAGE OF SPENT NUCLEAR FUEL, HIGH-LEVEL RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE General Design Criteria § 72.128 Criteria for spent fuel, high-level radioactive waste, reactor...

  15. Low-level radioactive waste management handbook series: Low-level radioactive waste management in medical and biomedical research institutions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1987-03-01

    Development of this handbook began in 1982 at the request of the Radhealth Branch of the California Department of Health Services. California Assembly Bill 1513 directed the DHS to ''evaluate the technical and economic feasibility of (1) reducing the volume, reactivity, and chemical and radioactive hazard of (low-level radioactive) waste and (2) substituting nonradioactive or short-lived radioactive materials for those radionuclides which require long-term isolation from the environment. A contract awarded to the University of California at Irvine-UCI (California Std. Agreement 79902), to develop a document focusing on methods for decreasing low-level radioactive waste (LLW) generation in institutions was amore » result of that directive. In early 1985, the US Department of Energy, through EG and G Idaho, Inc., contracted with UCI to expand, update, and revise the California text for national release.« less

  16. Cerebral salt-wasting syndrome due to hemorrhagic brain infarction: a case report.

    PubMed

    Tanaka, Tomotaka; Uno, Hisakazu; Miyashita, Kotaro; Nagatsuka, Kazuyuki

    2014-07-23

    Cerebral salt-wasting syndrome is a condition featuring hyponatremia and dehydration caused by head injury, operation on the brain, subarachnoid hemorrhage, brain tumor and so on. However, there are a few reports of cerebral salt-wasting syndrome caused by cerebral infarction. We describe a patient with cerebral infarction who developed cerebral salt-wasting syndrome in the course of hemorrhagic transformation. A 79-year-old Japanese woman with hypertension and arrhythmia was admitted to our hospital for mild consciousness disturbance, conjugate deviation to right, left unilateral spatial neglect and left hemiparesis. Magnetic resonance imaging revealed a broad ischemic change in right middle cerebral arterial territory. She was diagnosed as cardiogenic cerebral embolism because atrial fibrillation was detected on electrocardiogram on admission. She showed hyponatremia accompanied by polyuria complicated at the same time with the development of hemorrhagic transformation on day 14 after admission. Based on her hypovolemic hyponatremia, she was evaluated as not having syndrome of inappropriate secretion of antidiuretic hormone but cerebral salt-wasting syndrome. She fortunately recovered with proper fluid replacement and electrolyte management. This is a rare case of cerebral infarction and cerebral salt-wasting syndrome in the course of hemorrhagic transformation. It may be difficult to distinguish cerebral salt-wasting syndrome from syndrome of inappropriate antidiuretic hormone, however, an accurate assessment is needed to reveal the diagnosis of cerebral salt-wasting syndrome because the recommended fluid management is opposite in the two conditions.

  17. Pump station for radioactive waste water

    DOEpatents

    Whitton, John P.; Klos, Dean M.; Carrara, Danny T.; Minno, John J.

    2003-11-18

    A pump station for transferring radioactive particle containing waste water, includes: (a.) an enclosed sump having a vertically elongated right frusto conical wall surface and a bottom surface and (b.) a submersible volute centrifugal pump having a horizontally rotating impeller and a volute exterior surface. The sump interior surface, the bottom surface and the volute exterior surface are made of stainless steel having a 30 Ra or finer surface finish. A 15 Ra finish has been found to be most cost effective. The pump station is used for transferring waste water, without accumulation of radioactive fines.

  18. Maine State Briefing Book on low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-08-01

    The Maine State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and Federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Maine. The profile is the result of a survey of radioactive material licensees in Maine. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested partices including industry, government, the media, and interest groups. The assessment was developedmore » through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant goverment agencies and activities, all of which may impact management practices in Maine.« less

  19. Final repository for Denmark's low- and intermediate level radioactive waste

    NASA Astrophysics Data System (ADS)

    Nilsson, B.; Gravesen, P.; Petersen, S. S.; Binderup, M.

    2012-12-01

    Bertel Nilsson*, Peter Gravesen, Stig A. Schack Petersen, Merete Binderup Geological Survey of Denmark and Greenland (GEUS), Øster Voldgade 10, 1350 Copenhagen, Denmark, * email address bn@geus.dk The Danish Parliament decided in 2003 that the temporal disposal of the low- and intermediate level radioactive waste at the nuclear facilities at Risø should find another location for a final repository. The Danish radioactive waste must be stored on Danish land territory (exclusive Greenland) and must hold the entire existing radioactive waste, consisting of the waste from the decommissioning of the nuclear facilities at Risø, and the radioactive waste produced in Denmark from hospitals, universities and industry. The radioactive waste is estimated to a total amount of up to 10,000 m3. The Geological Survey of Denmark and Greenland, GEUS, is responsible for the geological studies of suitable areas for the repository. The task has been to locate and recognize non-fractured Quaternary and Tertiary clays or Precambrian bedrocks with low permeability which can isolate the radioactive waste from the surroundings the coming more than 300 years. Twenty two potential areas have been located and sequential reduced to the most favorable two to three locations taking into consideration geology, hydrogeology, nature protection and climate change conditions. Further detailed environmental and geology investigations will be undertaken at the two to three potential localities in 2013 to 2015. This study together with a study of safe transport of the radioactive waste and an investigation of appropriate repository concepts in relation to geology and safety analyses will constitute the basis upon which the final decision by the Danish Parliament on repository concept and repository location. The final repository is planned to be established and in operation at the earliest 2020.

  20. High-Level Radioactive Waste: Safe Storage and Ultimate Disposal.

    ERIC Educational Resources Information Center

    Dukert, Joseph M.

    Described are problems and techniques for safe disposal of radioactive waste. Degrees of radioactivity, temporary storage, and long-term permanent storage are discussed. Included are diagrams of estimated waste volumes to the year 2000 and of an artist's conception of a permanent underground disposal facility. (SL)

  1. An industry perspective on commercial radioactive waste disposal conditions and trends.

    PubMed

    Romano, Stephen A

    2006-11-01

    The United States is presently served by Class-A, -B and -C low-level radioactive waste and naturally-occurring and accelerator-produced radioactive material disposal sites in Washington and South Carolina; a Class-A and mixed waste disposal site in Utah that also accepts naturally-occurring radioactive material; and hazardous and solid waste facilities and uranium mill tailings sites that accept certain radioactive materials on a site-specific basis. The Washington site only accepts low-level radioactive waste from 11 western states due to interstate Compact restrictions on waste importation. The South Carolina site will be subject to geographic service area restrictions beginning 1 July 2008, after which only three states will have continued access. The Utah site dominates the commercial Class-A and mixed waste disposal market due to generally lower state fees than apply in South Carolina. To expand existing commercial services, an existing hazardous waste site in western Texas is seeking a Class-A, -B and -C and mixed waste disposal license. With that exception, no new Compact facilities are proposed. This fluid, uncertain situation has inspired national level rulemaking initiatives and policy studies, as well as alternative disposal practices for certain low-activity materials.

  2. Mississippi State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    The Mississippi State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state an federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Mississippi. The profile is the result of a survey of NRC licensees in Mississippi. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developed throughmore » personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Mississippi.« less

  3. Wyoming State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Wyoming State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Wyoming. The profile is the result of a survey of NRC licensees in Wyoming. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developed throughmore » personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Wyoming.« less

  4. Massachusetts State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-03-12

    The Massachusetts State Briefing Book is one of a series of State briefing books on low-level radioactive waste management practices. It has been prepared to assist State and Federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Massachusetts. The profile is the result of a survey of NRC licensees in Massachusetts. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developed throughmore » personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Massachusetts.« less

  5. Ohio State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Ohio State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Ohio. The profile is the result of a survey of NRC licensees in Ohio. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developed throughmore » personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Ohio.« less

  6. Management of low-level radioactive waste in Israel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shabtai, B.; Brenner, S.; Ne`eman, E.

    1995-12-31

    Radioactive materials are used extensively in Israel in many areas and applications for medicine, industry, agriculture, research and development and others. Israel`s primary concern in waste management is population safety and environmental protection. The Ministry of The Environment (MOE), in cooperation with the Israeli Atomic Energy Commission (IAEC), supervise over the disposal system, and ensure an effective control. The MOE is responsible for the granting of permits to users of radioactive elements in about 300 plants and institutes, with about 2,200 installations. The MOE operates a computerized database management system (DBMS) on radioactive materials, with data on licensing, import andmore » distribution, waste disposal and transportation. Supervision over the disposal of LLRW has deepened recently, and periodic reports, based on the number of drums containing LLRW, which were transferred from all institutes in Israel to the NRWDS, were prepared. Draft regulations on the disposal of LLRW from institutes of research and education, hospitals, medical laboratories and other, have been recently prepared. These regulations include instructions on the disposal of solid and liquid LLRW as well as radioactive gases and vapors. As a general rule, no LLRW of any sort will be disposed of through the ordinary waste system or general sewage. However, in some extraordinary cases, residues of liquid LLRW are allowed to be disposed in this manner, if the requirements for disposal are satisfied. There are some conditions, in which solid LLRW might be treated as a conventional waste, as well as for safe emission of radioactive gases and aerosols. In light of these considerations, a new and more specific approach to radiation protection organizations and management of low-level radioactive waste problems, supervision and optimization is presented.« less

  7. Radioactive waste processing apparatus

    DOEpatents

    Nelson, Robert E.; Ziegler, Anton A.; Serino, David F.; Basnar, Paul J.

    1987-01-01

    Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container.

  8. Vermont State Briefing Book on low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-07-01

    The Vermont State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Vermont. The profile is the result of a survey of Nuclear Regulatory Commission licensees in Vermont. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment wasmore » developed through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may affect waste management practices in Vermont.« less

  9. 77 FR 52073 - Request To Amend a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-28

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to..., 2012, July 31, 2012, XW012/ radioactive total of 5,500 materials and/or 02, 11005699. waste including tons or about radioactive various 1,000 tons waste that is materials (e.g., metal, 4,000 attributed to...

  10. Midwest Interstate Low-Level Radioactive Waste Commission annual report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1988-08-01

    In 1980, Congress passed the Low-Level Radioactive Waste Policy Act. This Act provided for a new approach to the disposal of low-level radioactive waste. It assigned each state responsibility for the disposal of low-level radioactive waste generated within its borders, and it authorized states to enter into compacts for the purpose of operating regional disposal facilities. It also authorized compacts to restrict the use of regional disposal facilities to only member states. To meet their obligations under the Act, Indiana, Iowa, Michigan, Minnesota, Missouri, Ohio and Wisconsin formed the Midwest Interstate Low-Level Radioactive Waste Compact. The Compact was ratified bymore » each of the state legislatures and by Congress. The Compact established the Midwest Interstate Low-Level Radioactive Waste Commission, composed on one representative appointed by the Governor or Legislature of each member state. Article 3 of the compact requires that the Commission prepare an annual report regarding the activities and actions of the Commission. It also requires that the annual report be distributed to the Governors and legislative leaders in the member states. The Commission's Bylaw Article 12 requires the annual report to cover the preceding fiscal year, and to be distributed in August of each year. The Bylaw also requires that an annual audit, prepared by a certified public accountant, be included as part of the annual report. 3 figs.« less

  11. Method for solidifying liquid radioactive wastes

    DOEpatents

    Berreth, Julius R.

    1976-01-01

    The quantity of nitrous oxides produced during the solidification of liquid radioactive wastes containing nitrates and nitrites can be substantially reduced by the addition to the wastes of a stoichiometric amount of urea which, upon heating, destroys the nitrates and nitrites, liberating nontoxic N.sub.2, CO.sub.2 and NH.sub.3.

  12. Guide to radioactive waste management literature

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Houser, B.L.; Holoway, C.F.; Madewell, D.G.

    Increased public concern about radioactive waste management has called attention to this aspect of the nuclear fuel cycle. Socio-economic planning and technical development are being undertaken to assure that such wastes will be managed safely. This Guide to Radioactive Waste Management Literature has been compiled to serve scientists, engineers, administrators, legislators, and private citizens by directing them to sources of information on various aspects of the subject. References were selected from about 6000 documents on waste management in the computerized information centers in Oak Ridge. The documents were selected, examined, indexed, and abstracted between 1966-1976 by several knowledgeable indexers, principallymore » at the Nuclear Safety Information Center. The selected references were further indexed and classified into 12 categories. Each category is discussed in enough detail to give some understandng of present technology in various phases of waste management and some appreciation of the attendant issues and problems. The bibliographic part of this guide exists in computerized form in the Health Physics Information System and is available through the Oak Ridge Information Center Complex for searching from remote terminals.« less

  13. ONDRAF/NIRAS and high-level radioactive waste management in Belgium

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Decamps, F.

    1993-12-31

    The National Agency for Radioactive Waste and Enriched Fissile Materials, ONDRAF/NIRAS, is a public body with legal personality in charge of managing all radioactive waste on Belgian territory, regardless of its origin and source. It is also entrusted with tasks related to the management of enriched fissile materials, plutonium containing materials and used or unused nuclear fuel, and with certain aspects of the dismantling of closed down nuclear facilities. High-level radioactive waste management comprises essentially and for the time being the storage of high-level liquid waste produced by the former EUROCHEMIC reprocessing plant and of high-level and very high-level heatmore » producing waste resulting from the reprocessing in France of Belgian spent fuel, as well as research and development (R and D) with regard to geological disposal in clay of this waste type.« less

  14. Assessment of public perception of radioactive waste management in Korea.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Trone, Janis R.; Cho, SeongKyung; Whang, Jooho

    2011-11-01

    The essential characteristics of the issue of radioactive waste management can be conceptualized as complex, with a variety of facets and uncertainty. These characteristics tend to cause people to perceive the issue of radioactive waste management as a 'risk'. This study was initiated in response to a desire to understand the perceptions of risk that the Korean public holds towards radioactive waste and the relevant policies and policy-making processes. The study further attempts to identify the factors influencing risk perceptions and the relationships between risk perception and social acceptance.

  15. Gamma-ray spectrometry method used for radioactive waste drums characterization for final disposal at National Repository for Low and Intermediate Radioactive Waste--Baita, Romania.

    PubMed

    Done, L; Tugulan, L C; Dragolici, F; Alexandru, C

    2014-05-01

    The Radioactive Waste Management Department from IFIN-HH, Bucharest, performs the conditioning of the institutional radioactive waste in concrete matrix, in 200 l drums with concrete shield, for final disposal at DNDR - Baita, Bihor county, in an old exhausted uranium mine. This paper presents a gamma-ray spectrometry method for the characterization of the radioactive waste drums' radionuclides content, for final disposal. In order to study the accuracy of the method, a similar concrete matrix with Portland cement in a 200 l drum was used. © 2013 The Authors. Published by Elsevier Ltd All rights reserved.

  16. 76 FR 53980 - Request for a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-30

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Import Radioactive Waste Pursuant to 10 CFR... Hitachi Nuclear Energy, LLC. Radioactive waste Up to 210 Cobalt- Recycling, China August 1, 2011, August 5, consisting of 60 sealed forensic testing 2011, IW030. used Cobalt-60 sources. or storage and radioactive...

  17. The Spanish General Radioactive Waste Management Plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Espejo, J.M.; Abreu, A.

    This paper mainly describes the strategies, the necessary actions and the technical solutions to be developed by ENRESA in the short, medium and long term, aimed at ensuring the adequate management of radioactive waste, the dismantling and decommissioning of nuclear and radioactive facilities and other activities, including economic and financial measures required to carry them out. Starting with the Spanish administrative organization in this field, which identifies the different agents involved and their roles, and after referring to the waste generation, the activities to be performed in the areas of LILW, SF and HLW management, decommissioning of installations and othersmore » are summarized. Finally, the future management costs are estimated and the financing system currently in force is explained. The so-called Sixth General Radioactive Waste Plan (6. GRWP), approved by the Spanish Government, is the 'master document' of reference where all the above mentioned issues are contemplated. In summary: The 6. GRWP includes the strategies and actions to be performed by Enresa in the coming years. The document, revised by the Government and subject to a process of public information, underlines the fact that Spain possesses an excellent infrastructure for the safe and efficient management of radioactive waste, from the administrative, technical and economic-financial points of view. From the administrative point of view there is an organisation, supported by ample legislative developments, that contemplates and governs the main responsibilities of the parties involved in the process (Government, CSN, ENRESA and waste producers). As regards the technical aspect, the experience accumulated to date by Enresa is particularly significant, as are the technologies now available in the field of management and for dismantling processes. As regards the economic-financial basis, a system is in place that guarantees the financing of radioactive waste management costs. This

  18. Method for acid oxidation of radioactive, hazardous, and mixed organic waste materials

    DOEpatents

    Pierce, Robert A.; Smith, James R.; Ramsey, William G.; Cicero-Herman, Connie A.; Bickford, Dennis F.

    1999-01-01

    The present invention is directed to a process for reducing the volume of low level radioactive and mixed waste to enable the waste to be more economically stored in a suitable repository, and for placing the waste into a form suitable for permanent disposal. The invention involves a process for preparing radioactive, hazardous, or mixed waste for storage by contacting the waste starting material containing at least one organic carbon-containing compound and at least one radioactive or hazardous waste component with nitric acid and phosphoric acid simultaneously at a contacting temperature in the range of about 140.degree. C. to about 210 .degree. C. for a period of time sufficient to oxidize at least a portion of the organic carbon-containing compound to gaseous products, thereby producing a residual concentrated waste product containing substantially all of said radioactive or inorganic hazardous waste component; and immobilizing the residual concentrated waste product in a solid phosphate-based ceramic or glass form.

  19. Molten salt destruction of energetic waste materials

    DOEpatents

    Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

    1995-07-18

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

  20. Molten salt destruction of energetic waste materials

    DOEpatents

    Brummond, William A.; Upadhye, Ravindra S.; Pruneda, Cesar O.

    1995-01-01

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

  1. Natural diatomite process for removal of radioactivity from liquid waste.

    PubMed

    Osmanlioglu, Ahmet Erdal

    2007-01-01

    Diatomite has a number of unique physical properties and has found diversified industrial utilization. The filtration characteristics are particularly significant in the purification of liquids. The purpose of this study was to test natural diatomaceous earth (diatomite) as an alternative material that could be used for removal of radioactivity from liquid waste. A pilot-scale column-type device was designed. Natural diatomite samples were ground, sieved and prepared to use as sorption media. In this study, real waste liquid was used as radioactive liquid having special conditions. The liquid waste contained three radionuclides (Cs-137, Cs-134 and Co-60). Following the treatment by diatomite, the radioactivity of liquid waste was reduced from the initial 2.60 Bq/ml to less than 0.40 Bq/ml. The results of this study show that most of the radioactivity was removed from the solution by processing with diatomite.

  2. Radioactive Waste Management Complex low-level waste radiological performance assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maheras, S.J.; Rood, A.S.; Magnuson, S.O.

    This report documents the projected radiological dose impacts associated with the disposal of radioactive low-level waste at the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. This radiological performance assessment was conducted to evaluate compliance with applicable radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the public and the environment. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the public via air, groundwater, and food chain pathways. Projections of doses were made for both offsitemore » receptors and individuals inadvertently intruding onto the site after closure. In addition, uncertainty and sensitivity analyses were performed. The results of the analyses indicate compliance with established radiological criteria and provide reasonable assurance that public health and safety will be protected.« less

  3. A Preliminary Performance Assessment for Salt Disposal of High-Level Nuclear Waste - 12173

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Joon H.; Clayton, Daniel; Jove-Colon, Carlos

    2012-07-01

    A salt repository is one of the four geologic media currently under study by the U.S. DOE Office of Nuclear Energy to support the development of a long-term strategy for geologic disposal of commercial used nuclear fuel (UNF) and high-level radioactive waste (HLW). The immediate goal of the generic salt repository study is to develop the necessary modeling tools to evaluate and improve the understanding of the repository system response and processes relevant to long-term disposal of UNF and HLW in a salt formation. The current phase of this study considers representative geologic settings and features adopted from previous studiesmore » for salt repository sites. For the reference scenario, the brine flow rates in the repository and underlying interbeds are very low, and transport of radionuclides in the transport pathways is dominated by diffusion and greatly retarded by sorption on the interbed filling materials. I-129 is the dominant annual dose contributor at the hypothetical accessible environment, but the calculated mean annual dose is negligibly small. For the human intrusion (or disturbed) scenario, the mean mass release rate and mean annual dose histories are very different from those for the reference scenario. Actinides including Pu-239, Pu-242 and Np-237 are major annual dose contributors, and the calculated peak mean annual dose is acceptably low. A performance assessment model for a generic salt repository has been developed incorporating, where applicable, representative geologic settings and features adopted from literature data for salt repository sites. The conceptual model and scenario for radionuclide release and transport from a salt repository were developed utilizing literature data. The salt GDS model was developed in a probabilistic analysis framework. The preliminary performance analysis for demonstration of model capability is for an isothermal condition at the ambient temperature for the near field. The capability demonstration

  4. Foaming in simulated radioactive waste.

    PubMed

    Bindal, S K; Nikolov, A D; Wasan, D T; Lambert, D P; Koopman, D C

    2001-10-01

    Radioactive waste treatment process usually involves concentration of radionuclides before waste can be immobilized by storing it in stable solid form. Foaming is observed at various stages of waste processing like SRAT (sludge receipt and adjustment tank) and melter operations. This kind of foaming greatly limits the process efficiency. The foam encountered can be characterized as a three-phase foam that incorporates finely divided solids (colloidal particles). The solid particles stabilize foaminess in two ways: by adsorption of biphilic particles at the surfaces of foam lamella and by layering of particles trapped inside the foam lamella. During bubble generation and rise, solid particles organize themselves into a layered structure due to confinement inside the foam lamella, and this structure provides a barrier against the coalescence of the bubbles, thereby causing foaming. Our novel capillary force balance apparatus was used to examine the particle-particle interactions, which affect particle layer formation in the foam lamella. Moreover, foaminess shows a maximum with increasing solid particle concentration. To explain the maximum in foaminess, a study was carried out on the simulated sludge, a non-radioactive simulant of the radioactive waste sludge at SRS, to identify the parameters that affect the foaming in a system characterized by the absence of surface-active agents. This three-phase foam does not show any foam stability unlike surfactant-stabilized foam. The parameters investigated were solid particle concentration, heating flux, and electrolyte concentration. The maximum in foaminess was found to be a net result of two countereffects that arise due to particle-particle interactions: structural stabilization and depletion destabilization. It was found that higher electrolyte concentration causes a reduction in foaminess and leads to a smaller bubble size. Higher heating fluxes lead to greater foaminess due to an increased rate of foam lamella

  5. Geohydrology of the northern Louisiana salt-dome basin pertinent to the storage of radioactive wastes; a progress report

    USGS Publications Warehouse

    Hosman, R.L.

    1978-01-01

    Salt domes in northern Louisiana are being considered as possible storage sites for nuclear wastes. The domes are in an area that received regional sedimentation through early Tertiary (Eocene) time with lesser amounts of Quaternary deposits. The Cretaceous-Tertiary accumulation is a few thousand feet thick; the major sands are regional aquifers that extend far beyond the boundaries of the salt-dome basin. Because of multiple aquifers, structural deformation, and variations in the hydraulic characteristics of cap rock, the ground-water hydrology around a salt dome may be highly complex. The Sparta Sand is the most productive and heavily used regional aquifer. It is either penetrated by or overlies most of the domes. A fluid entering the Sparta flow system would move toward one of the pumping centers, all at or near municipalities that pump from the Sparta. Movement could be toward surface drainage where local geologic and hydrologic conditions permit leakage to the surface or to a surficial aquifer. (Woodard-USGS)

  6. 78 FR 53793 - Request To Amend a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-30

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Import Radioactive Waste Pursuant to... (Class A total of 5,500 ``Foreign Suppliers.'' No IW022/04 radioactive tons of low- other changes to the existing 11005700 waste). level waste). license which authorizes the import of low-level waste for...

  7. Geochemical Aspects of Radioactive Waste Disposal

    NASA Astrophysics Data System (ADS)

    Moody, Judith B.

    1984-04-01

    The author's stated purpose in writing this book is to summarize the large number of government-sponsored research reports on the geochemical aspects of high-level nuclear waste isolation. Although this book has a 1984 publication date, the majority of the cited documents were published before 1982. Unfortunately, passage of the Nuclear Waste Policy Act (NWPA) of 1982 and its signing into law by President Reagan (January 1983) [U.S. Congress, 1983] has significantly altered the U.S. Department of Energy (DOE) Civilian Radioactive Waste Management (CRWM) Program. Therefore this book does not accurately reflect the present U.S. program in geologic disposal of high-level nuclear waste. For example, chapter 2, “Radioactive Waste Management,” is almost 3 years out of date in a field that is changing rapidly (see U.S. DOE [1984a] for the current status of the CRWM Program). Additionally, the source material, which forms the input for this book, is chiefly grey literature, i.e., the referenced documents may or may not have undergone peer review and therefore do not represent the technical judgment of the scientific community. Also, this book only presents a selective sampling of information because the literature cited does not include a representative selection of the widespread available literature on this topic.

  8. Waste Determination Equivalency - 12172

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Freeman, Rebecca D.

    2012-07-01

    The Savannah River Site (SRS) is a Department of Energy (DOE) facility encompassing approximately 800 square kilometers near Aiken, South Carolina which began operations in the 1950's with the mission to produce nuclear materials. The SRS contains fifty-one tanks (2 stabilized, 49 yet to be closed) distributed between two liquid radioactive waste storage facilities at SRS containing carbon steel underground tanks with storage capacities ranging from 2,800,000 to 4,900,000 liters. Treatment of the liquid waste from these tanks is essential both to closing older tanks and to maintaining space needed to treat the waste that is eventually vitrified or disposedmore » of onsite. Section 3116 of the Ronald W. Reagan National Defense Authorization Act of Fiscal Year 2005 (NDAA) provides the Secretary of Energy, in consultation with the Nuclear Regulatory Commission (NRC), a methodology to determine that certain waste resulting from prior reprocessing of spent nuclear fuel are not high-level radioactive waste if it can be demonstrated that the waste meets the criteria set forth in Section 3116(a) of the NDAA. The Secretary of Energy, in consultation with the NRC, signed a determination in January 2006, pursuant to Section 3116(a) of the NDAA, for salt waste disposal at the SRS Saltstone Disposal Facility. This determination is based, in part, on the Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site and supporting references, a document that describes the planned methods of liquid waste treatment and the resulting waste streams. The document provides descriptions of the proposed methods for processing salt waste, dividing them into 'Interim Salt Processing' and later processing through the Salt Waste Processing Facility (SWPF). Interim Salt Processing is separated into Deliquification, Dissolution, and Adjustment (DDA) and Actinide Removal Process/Caustic Side Solvent Extraction Unit (ARP/MCU). The Waste Determination was signed by the

  9. Geohydrologic aspects for siting and design of low-level radioactive-waste disposal

    USGS Publications Warehouse

    Bedinger, M.S.

    1989-01-01

    The objective for siting and design of low-level radioactive-waste repository sites is to isolate the waste from the biosphere until the waste no longer poses an unacceptable hazard as a result of radioactive decay. Low-level radioactive waste commonly is isolated at shallow depths with various engineered features to stabilize the waste and to reduce its dissolution and transport by ground water. The unsaturated zone generally is preferred for isolating the waste. Low-level radioactive waste may need to be isolated for 300 to 500 years. Maintenance and monitoring of the repository site are required by Federal regulations for only the first 100 years. Therefore, geohydrology of the repository site needs to provide natural isolation of the waste for the hazardous period following maintenance of the site. Engineering design of the repository needs to be compatible with the natural geohydrologic conditions at the site. Studies at existing commercial and Federal waste-disposal sites provide information on the problems encountered and the basis for establishing siting guidelines for improved isolation of radioactive waste, engineering design of repository structures, and surveillance needs to assess the effectiveness of the repositories and to provide early warning of problems that may require remedial action.Climate directly affects the hydrology of a site and probably is the most important single factor that affects the suitability of a site for shallow-land burial of low-level radioactive waste. Humid and subhumid regions are not well suited for shallow isolation of low-level radioactive waste in the unsaturated zone; arid regions with zero to small infiltration from precipitation, great depths to the water table, and long flow paths to natural discharge areas are naturally well suited to isolation of the waste. The unsaturated zone is preferred for isolation of low-level radioactive waste. The guiding rationale is to minimize contact of water with the waste and to

  10. Management of radioactive waste in Belgium: ONDRAF/NIRAS and Belgoprocess as major actors of the waste acceptance system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zaelen, Gunter van; Verheyen, Annick

    2007-07-01

    The management of radioactive waste in Belgium is undertaken by the national agency for radioactive waste and enriched fissile materials, ONDRAF/NIRAS, and its industrial partner Belgoprocess. ONDRAF/NIRAS has set up a management system designed to guarantee that the general public and the environment are protected against the potential hazards arising from radioactive waste. Belgoprocess is a private company, founded in 1984 and located in Dessel, Belgium. It is a subsidiary of ONDRAF/NIRAS and its activities focus on the safe processing and storage of radioactive waste. The management system of ONDRAF/NIRAS includes two aspects: a) an integrated system and b) anmore » acceptance system. The integrated system covers all aspects of management ranging from the origin of waste to its transport, processing, interim storage and long-term management. The safety of radioactive waste management not only depends on the quality of the design and construction of the processing, temporary storage or disposal infrastructure, but also on the quality of the waste accepted by ONDRAF/NIRAS. In order to be manage d safely, both in the short and the long term, the waste transferred to ONDRAF/NIRAS must meet certain specific requirements. To that end, ONDRAF/NIRAS has developed an acceptance system. (authors)« less

  11. Engineering Options Assessment Report. Nitrate Salt Waste Stream Processing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anast, Kurt Roy

    2015-11-13

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 above-ground UNS, and 79 candidate below-ground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation.more » Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.« less

  12. Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anast, Kurt Roy

    2015-11-18

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 aboveground UNS, and 79 candidate belowground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation.more » Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.« less

  13. New Jersey State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The New Jersey state Briefing Book is one of a series of State briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in New Jersey. The profile is the result of a survey of NRC licensees in New Jersey. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessmentmore » was developed through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in New Jersey.« less

  14. North Carolina State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The North Carolina State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in North Carolina. The profile is the result of a survey of NRC licensees in North Carolina. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessmentmore » was developed through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in North Carolina.« less

  15. Puerto Rico State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Puerto Rico State Briefing Book is one of a series of state briefing books on low-level radioactive waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Puerto Rico. The profile is the result of a survey of NRC licensees in Puerto Rico. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessmentmore » was developed through personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Puerto Rico.« less

  16. Texas State Briefing Book for low-level radioactive waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-08-01

    The Texas State Briefing Book is one of a series of state briefing books on low-level radioactivee waste management practices. It has been prepared to assist state and federal agency officials in planning for safe low-level radioactive waste disposal. The report contains a profile of low-level radioactive waste generators in Texas. The profile is the result of a survey of NRC licensees in Texas. The briefing book also contains a comprehensive assessment of low-level radioactive waste management issues and concerns as defined by all major interested parties including industry, government, the media, and interest groups. The assessment was developed throughmore » personal communications with representatives of interested parties, and through a review of media sources. Lastly, the briefing book provides demographic and socioeconomic data and a discussion of relevant government agencies and activities, all of which may impact waste management practices in Texas.« less

  17. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM 2008

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B.; Waltz, R.

    2009-06-11

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2008 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report.

  18. Radioactive waste management in Poland status and strategy for the future

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wlodarski, J.

    1995-12-01

    Site selection for a new radioactive waste repository in Poland has been started. The repository will contain low- and intermediate-level radioactive wastes and spent fuel. Superficial, shallow underground and deep underground disposal options were considered; 39 potential sites have been selected. Issues to be resolved regarding waste management in Poland are also outlined in this paper.

  19. Radioactive waste management complex low-level waste radiological composite analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McCarthy, J.M.; Becker, B.H.; Magnuson, S.O.

    1998-05-01

    The composite analysis estimates the projected cumulative impacts to future members of the public from the disposal of low-level radioactive waste (LLW) at the Idaho National Engineering and Environmental Laboratory (INEEL) Radioactive Waste Management Complex (RWMC) and all other sources of radioactive contamination at the INEEL that could interact with the LLW disposal facility to affect the radiological dose. Based upon the composite analysis evaluation, waste buried in the Subsurface Disposal Area (SDA) at the RWMC is the only source at the INEEL that will significantly interact with the LLW facility. The source term used in the composite analysis consistsmore » of all historical SDA subsurface disposals of radionuclides as well as the authorized LLW subsurface disposal inventory and projected LLW subsurface disposal inventory. Exposure scenarios evaluated in the composite analysis include all the all-pathways and groundwater protection scenarios. The projected dose of 58 mrem/yr exceeds the composite analysis guidance dose constraint of 30 mrem/yr; therefore, an options analysis was conducted to determine the feasibility of reducing the projected annual dose. Three options for creating such a reduction were considered: (1) lowering infiltration of precipitation through the waste by providing a better cover, (2) maintaining control over the RWMC and portions of the INEEL indefinitely, and (3) extending the period of institutional control beyond the 100 years assumed in the composite analysis. Of the three options investigated, maintaining control over the RWMC and a small part of the present INEEL appears to be feasible and cost effective.« less

  20. Journey to the Nevada Test Site Radioactive Waste Management Complex

    ScienceCinema

    None

    2018-01-16

    Journey to the Nevada Test Site Radioactive Waste Management Complex begins with a global to regional perspective regarding the location of low-level and mixed low-level waste disposal at the Nevada Test Site. For decades, the Nevada National Security Site (NNSS) has served as a vital disposal resource in the nation-wide cleanup of former nuclear research and testing facilities. State-of-the-art waste management sites at the NNSS offer a safe, permanent disposal option for U.S. Department of Energy/U.S. Department of Defense facilities generating cleanup-related radioactive waste.

  1. Uncertainty quantification applied to the radiological characterization of radioactive waste.

    PubMed

    Zaffora, B; Magistris, M; Saporta, G; Chevalier, J-P

    2017-09-01

    This paper describes the process adopted at the European Organization for Nuclear Research (CERN) to quantify uncertainties affecting the characterization of very-low-level radioactive waste. Radioactive waste is a by-product of the operation of high-energy particle accelerators. Radioactive waste must be characterized to ensure its safe disposal in final repositories. Characterizing radioactive waste means establishing the list of radionuclides together with their activities. The estimated activity levels are compared to the limits given by the national authority of the waste disposal. The quantification of the uncertainty affecting the concentration of the radionuclides is therefore essential to estimate the acceptability of the waste in the final repository but also to control the sorting, volume reduction and packaging phases of the characterization process. The characterization method consists of estimating the activity of produced radionuclides either by experimental methods or statistical approaches. The uncertainties are estimated using classical statistical methods and uncertainty propagation. A mixed multivariate random vector is built to generate random input parameters for the activity calculations. The random vector is a robust tool to account for the unknown radiological history of legacy waste. This analytical technique is also particularly useful to generate random chemical compositions of materials when the trace element concentrations are not available or cannot be measured. The methodology was validated using a waste population of legacy copper activated at CERN. The methodology introduced here represents a first approach for the uncertainty quantification (UQ) of the characterization process of waste produced at particle accelerators. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. 78 FR 9746 - Request To Amend a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-11

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to... radioactive disposition. Amend which was imported mixed waste) in to: 1) add four from Canada under NRC a....; docket No. country Diversified Scientific Class A radioactive Up to a maximum Return of non- Canada...

  3. Thermal-gradient migration of brine inclusions in salt crystals

    NASA Astrophysics Data System (ADS)

    Yagnik, S. K.

    1982-09-01

    High level nuclear waste disposal in a geologic repository was proposed. Natural salt deposits which are considered contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms which is undesirable. In this work, thermal gradient migration of both all liquid and gas liquid inclusions was experimentally studied in synthetic single crystals of NaCl and KCl using a hot stage attachment to an optical microscope which was capable of imposing temperature gradients and axial compressive loads on the crystals. The migration velocities of the inclusion shape and size are discussed.

  4. Radioactive waste management in France and international cooperation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Marque, Y.

    1991-01-01

    Long-term industrial management of radioactive waste in France is carried out by the Agence Nationale pour la gestion des Dechets Radioactifs. (ANDRA), which is a public body responsible mainly for siting, design, construction, and operation of the disposal facilities for every kind of radioactive waste produced in the country. Furthermore, ANDRA has to define and control the required quality of waste packages delivered for disposal. As far as disposal is concerned, it is customary in France to classify waste in two main categories. The first category includes all the so-called short-lived low-level waste (LLW) containing mainly radioactive substances have waste that contains a significant amount of long-lived substances such as transuranic nuclides. Throughout the world, public acceptance is at present the main issue in the siting of a disposal facility. Development of international cooperation is desirable in order to present a consistent international policy, whatever technical options may be chosen according to local considerations and possibilities. It can also be very fruitful to have bilateral collaboration where approaches in the two countries seem to be similar. International cooperation is already a matter of fact within the framework of international organizations such as the International Atomic Energy Agency, the Organization for Economic Cooperation and Development, and the Commission of European Communities.« less

  5. 78 FR 53793 - Request To Amend a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-30

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to... total of 5,500 ``Ultimate Foreign XW012/04 radioactive tons of low- Consignee(s).'' No other 11005699 waste). level waste). changes to the existing license which authorizes the export of non-conforming...

  6. Pyrolytic conversion of plastic and rubber waste to hydrocarbons with basic salt catalysts

    DOEpatents

    Wingfield, Jr., Robert C.; Braslaw, Jacob; Gealer, Roy L.

    1985-01-01

    The invention relates to a process for improving the pyrolytic conversion of waste selected from rubber and plastic to low molecular weight olefinic materials by employing basis salt catalysts in the waste mixture. The salts comprise alkali or alkaline earth compounds, particularly sodium carbonate, in an amount of greater than about 1 weight percent based on the waste feed.

  7. Combined central diabetes insipidus and cerebral salt wasting syndrome in children.

    PubMed

    Lin, Jainn-Jim; Lin, Kuang-Lin; Hsia, Shao-Hsuan; Wu, Chang-Teng; Wang, Huei-Shyong

    2009-02-01

    Central diabetes insipidus, a common consequence of acute central nervous system injury, causes hypernatremia; cerebral salt wasting syndrome can cause hyponatremia. The two conditions occurring simultaneous are rarely described in pediatric patients. Pediatric cases of combined diabetes insipidus and cerebral salt wasting after acute central nervous system injury between January 2000 and December 2007 were retrospectively reviewed, and clinical characteristics were systemically assessed. Sixteen patients, aged 3 months to 18 years, met study criteria: 11 girls and 5 boys. The most common etiologies were severe central nervous system infection (n = 7, 44%) and hypoxic-ischemic event (n = 4, 25%). In 15 patients, diabetes insipidus was diagnosed during the first 3 days after acute central nervous system injury. Onset of cerebral salt wasting syndrome occurred 2-8 days after the onset of diabetes insipidus. In terms of outcome, 13 patients died (81%) and 3 survived under vegetative status (19%). Central diabetes insipidus and cerebral salt wasting syndrome may occur after acute central nervous system injury. A combination of both may impede accurate diagnosis. Proper differential diagnoses are critical, because the treatment strategy for each entity is different.

  8. NCRP Program Area Committee 5: Environmental Radiation and Radioactive Waste Issues

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, S. Y.; Napier, Bruce

    Program Area Committee 5 of the National Council on Radiation Protection and Measurements (NCRP) focuses its activities on environmental radiation and radioactive waste issues. Historically this Committee addressed emerging issues of the nation pertaining to radioactivity or radiation in the environment or radioactive waste issues due either to natural origins or to manmade activities. The Committee continues to identify such issues in the future.

  9. Candidate waste forms for immobilisation of waste chloride salt from pyroprocessing of spent nuclear fuel

    NASA Astrophysics Data System (ADS)

    Vance, E. R.; Davis, J.; Olufson, K.; Chironi, I.; Karatchevtseva, I.; Farnan, I.

    2012-01-01

    Sodalite/glass bodies prepared by hot isostatic pressing (HIPing) at ˜850 °C/100 MPa are candidates for immobilising fission product-bearing waste KCl-LiCl pyroprocessing salts. To study the capacity of sodalite to structurally incorporate such pyroprocessing salts, K, Li, Cs, Sr, Ba and La were individually targeted for substitution in a Na site in sodalite (Na vacancies targeted as charge compensators for alkaline and rare earths) and studied by X-ray diffraction and scanning electron microscopy after sintering in the range of 800-1000 °C. K and Li appeared to enter the sodalite, but Cs, Sr and Ba formed aluminosilicate phases and La formed an oxyapatite phase. However these non-sodalite phases have reasonable resistance to water leaching. Pure chlorapatite gives superior leach resistance to sodalite, and alkalis, alkaline and rare earth ions are generally known to enter chlorapatite, but attempts to incorporate simulated waste salt formulations into HIPed chlorapatite-based preparations or to substitute Cs alone into the structure of Ca-based chlorapatite were not successful on the basis of scanning electron microscopy. The materials exhibited severe water leachability, mainly in regard to Cs release. Attempts to substitute Cs into Ba- and Sr-based chlorapatites also did not look encouraging. Consequently the use of apatite alone to retain fission product-bearing waste pyroprocessing salts from electrolytic nuclear fuel reprocessing is problematical, but chlorapatite glass-ceramics may be feasible, albeit with reduced waste loadings. Spodiosite, Ca 2(PO 4)Cl, does not appear to be suitable for incorporation of Cl-bearing waste containing fission products.

  10. Actinide removal from spent salts

    DOEpatents

    Hsu, Peter C.; von Holtz, Erica H.; Hipple, David L.; Summers, Leslie J.; Adamson, Martyn G.

    2002-01-01

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  11. [Problems of safety regulation under radioactive waste management in Russia].

    PubMed

    Monastyrskaia, S G; Kochetkov, O A; Barchukov, V G; Kuznetsova, L I

    2012-01-01

    Analysis of the requirements of Federal Law N 190 "About radioactive waste management and incorporation of changes into some legislative acts of the Russian Federation", as well as normative-legislative documents actual and planned to be published related to provision of radiation protection of the workers and the public have been done. Problems of safety regulation raised due to different approaches of Rospotrebnadzor, FMBA of Russia, Rostekhnadzor and Minprirody with respect to classification and categorization of the radioactive wastes, disposal, exemption from regulatory control, etc. have been discussed in the paper. Proposals regarding improvement of the system of safety regulation under radioactive waste management and of cooperation of various regulatory bodies have been formulated.

  12. (Low-level radioactive waste management techniques)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Van Hoesen, S.D.; Kennerly, J.M.; Williams, L.C.

    1988-08-08

    The US team consisting of representatives of Oak Ridge National Laboratory (ORNL), Savannah River plant (SRP), Idaho National Engineering Laboratory (INEL), and the Department of Energy, Oak Ridge Operations participated in a training program on French low-level radioactive waste (LLW) management techniques. Training in the rigorous waste characterization, acceptance and certification procedures required in France was provided at Agence Nationale pour les Gestion des Dechets Radioactif (ANDRA) offices in Paris.

  13. West Valley demonstration project: Alternative processes for solidifying the high-level wastes

    NASA Astrophysics Data System (ADS)

    Holton, L. K.; Larson, D. E.; Partain, W. L.; Treat, R. L.

    1981-10-01

    Two pretreatment approaches and several waste form processes for radioactive wastes were selected for evaluation. The two waste treatment approaches were the salt/sludge separation process and the combined waste process. Both terminal and interim waste form processes were studied.

  14. 78 FR 26812 - Request To Amend a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-08

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to...; XW012/03; 11005699. A radioactive total of 5,500 Energy of Canada waste). tons of low- Limited facilities as level waste). ``Ultimate Foreign Consignee(s).'' No other changes to the existing license which...

  15. 78 FR 26813 - Request To Amend a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-08

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Import Radioactive Waste Pursuant to..., 2013, April 23, material (Class to a maximum the licensee name 2013, IW022/03, 11005700. A radioactive total of 5,500 from ``Perma-Fix waste). tons of low- Environmental level waste). Services, Inc.'' to...

  16. Current situation and future plans in radioactive waste management in Mexico

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lopez, H.; Jimenez, M.

    1992-01-01

    A brief introduction is offered in this document in order to explain the importance which is given in Mexico to the safe management of radioactive wastes. The Secretaria de Energia, Minas e Industria Paraestatal is the organization responsible for this issue. Also, a brief historical background is offered so as to understand the evolution of these activities since they were originated. This background allows us to describe the present situation, which consists in a substantial change in the volume of produced radioactive wastes; in other words, before the present situation only the, nuclear wastes from the application of radioisotopes weremore » generated whereas currently, with the starting of commercial operation of the first unit of Laguna Verde Nuclear Power Plant (LVNPP), large volumes of industrial radioactive wastes are being generated. A mention is given as well of the acquired experience during more than 20 years of waste management and of the technologies which have been applied or practiced in the use and disposal of such wastes. Finally, some general trends in relation to the future planning are indicated, which essentially consist in the siting and characterization of a site so as to, design and construct a permanent disposal facility in order to dispose the operational radioactive wastes from LVNPP.« less

  17. 77 FR 25760 - Low-Level Radioactive Waste Management and Volume Reduction

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-01

    ... NUCLEAR REGULATORY COMMISSION [NRC-2011-0183] Low-Level Radioactive Waste Management and Volume.... Nuclear Regulatory Commission (NRC or the Commission) is revising its 1981 Policy Statement on Low-Level..., the NRC staff issued SECY-10-0043, ``Blending of Low-Level Radioactive Waste'' (ADAMS Accession No...

  18. Solidification of radioactive waste resins using cement mixed with organic material

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Laili, Zalina, E-mail: liena@nm.gov.my; Waste and Environmental Technology Division, Malaysian Nuclear Agency; Yasir, Muhamad Samudi

    2015-04-29

    Solidification of radioactive waste resins using cement mixed with organic material i.e. biochar is described in this paper. Different percentage of biochar (0%, 5%, 8%, 11%, 14% and 18%) was investigated in this study. The characteristics such as compressive strength and leaching behavior were examined in order to evaluate the performance of solidified radioactive waste resins. The results showed that the amount of biochar affect the compressive strength of the solidified resins. Based on the data obtained for the leaching experiments performed, only one formulation showed the leached of Cs-134 from the solidified radioactive waste resins.

  19. Utilization of coal fly ash in solidification of liquid radioactive waste from research reactor.

    PubMed

    Osmanlioglu, Ahmet Erdal

    2014-05-01

    In this study, the potential utilization of fly ash was investigated as an additive in solidification process of radioactive waste sludge from research reactor. Coal formations include various percentages of natural radioactive elements; therefore, coal fly ash includes various levels of radioactivity. For this reason, fly ashes have to be evaluated for potential environmental implications in case of further usage in any construction material. But for use in solidification of radioactive sludge, the radiological effects of fly ash are in the range of radioactive waste management limits. The results show that fly ash has a strong fixing capacity for radioactive isotopes. Specimens with addition of 5-15% fly ash to concrete was observed to be sufficient to achieve the target compressive strength of 20 MPa required for near-surface disposal. An optimum mixture comprising 15% fly ash, 35% cement, and 50% radioactive waste sludge could provide the solidification required for long-term storage and disposal. The codisposal of radioactive fly ash with radioactive sludge by solidification decreases the usage of cement in solidification process. By this method, radioactive fly ash can become a valuable additive instead of industrial waste. This study supports the utilization of fly ash in industry and the solidification of radioactive waste in the nuclear industry.

  20. IONSIV(R) IE-911 Performance in Savannah River Site Radioactive Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Walker, D.D.

    2001-06-04

    This report describes cesium sorption from high-level radioactive waste solutions onto IONSIV(R) IE-911 at ambient temperature. Researchers characterized six radioactive waste samples from five high-level waste tanks in the Savannah River Site tank farm, diluted the wastes to 5.6 M Na+, and made equilibrium and kinetic measurements of cesium sorption. The equilibrium measurements were compared to ZAM (Zheng, Anthony, and Martin) model predictions. The kinetic measurements were compared to simulant solutions whose column performance has been measured.

  1. Operational Strategies for Low-Level Radioactive Waste Disposal Site in Egypt - 13513

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mohamed, Yasser T.

    The ultimate aims of treatment and conditioning is to prepare waste for disposal by ensuring that the waste will meet the waste acceptance criteria of a disposal facility. Hence the purpose of low-level waste disposal is to isolate the waste from both people and the environment. The radioactive particles in low-level waste emit the same types of radiation that everyone receives from nature. Most low-level waste fades away to natural background levels of radioactivity in months or years. Virtually all of it diminishes to natural levels in less than 300 years. In Egypt, The Hot Laboratories and Waste Management Centermore » has been established since 1983, as a waste management facility for LLW and ILW and the disposal site licensed for preoperational in 2005. The site accepts the low level waste generated on site and off site and unwanted radioactive sealed sources with half-life less than 30 years for disposal and all types of sources for interim storage prior to the final disposal. Operational requirements at the low-level (LLRW) disposal site are listed in the National Center for Nuclear Safety and Radiation Control NCNSRC guidelines. Additional procedures are listed in the Low-Level Radioactive Waste Disposal Facility Standards Manual. The following describes the current operations at the LLRW disposal site. (authors)« less

  2. Radioactive waste disposal fees-Methodology for calculation

    NASA Astrophysics Data System (ADS)

    Bemš, Július; Králík, Tomáš; Kubančák, Ján; Vašíček, Jiří; Starý, Oldřich

    2014-11-01

    This paper summarizes the methodological approach used for calculation of fee for low- and intermediate-level radioactive waste disposal and for spent fuel disposal. The methodology itself is based on simulation of cash flows related to the operation of system for waste disposal. The paper includes demonstration of methodology application on the conditions of the Czech Republic.

  3. 77 FR 73054 - Application for a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-07

    ... NUCLEAR REGULATORY COMMISSION Application for a License To Export Radioactive Waste Pursuant to 10 CFR 110.70(b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear..., October 25, 2012, XW020, radioactive 1178 pounds disposal by the 11006061. waste in the (approximately...

  4. 76 FR 56489 - Request for a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-13

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Export Radioactive Waste Pursuant to 10 CFR... quantity End use country Duratek Services, Inc., August Class A radioactive Radionuclide Non-conforming Canada. 17, 2011, August 18, 2011, waste in the form reallocation: materials XW010/02, 11005620. of...

  5. 75 FR 74107 - Request for a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-30

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Import Radioactive Waste Pursuant to 10 CFR 110.70(b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear.... EnergySolutions, August 27, Radioactive waste 1,000 tons Incineration for Germany. 2010, November 3, 2010...

  6. 77 FR 20078 - Request for a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-03

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Import Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear.... docket No. Perma-Fix Northwest Richland, Radioactive waste Up to 500 tons of Thermal Mexico. Inc...

  7. 75 FR 68840 - Request for a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-09

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Import Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear.... Oregon Specialty Metals......... Radioactive Waste 186,000 kilograms Return of U.S. Canada August 30...

  8. Granite disposal of U.S. high-level radioactive waste.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Freeze, Geoffrey A.; Mariner, Paul E.; Lee, Joon H.

    This report evaluates the feasibility of disposing U.S. high-level radioactive waste in granite several hundred meters below the surface of the earth. The U.S. has many granite formations with positive attributes for permanent disposal. Similar crystalline formations have been extensively studied by international programs, two of which, in Sweden and Finland, are the host rocks of submitted or imminent repository license applications. This report is enabled by the advanced work of the international community to establish functional and operational requirements for disposal of a range of waste forms in granite media. In this report we develop scoping performance analyses, basedmore » on the applicable features, events, and processes (FEPs) identified by international investigators, to support generic conclusions regarding post-closure safety. Unlike the safety analyses for disposal in salt, shale/clay, or deep boreholes, the safety analysis for a mined granite repository depends largely on waste package preservation. In crystalline rock, waste packages are preserved by the high mechanical stability of the excavations, the diffusive barrier of the buffer, and favorable chemical conditions. The buffer is preserved by low groundwater fluxes, favorable chemical conditions, backfill, and the rigid confines of the host rock. An added advantage of a mined granite repository is that waste packages would be fairly easy to retrieve, should retrievability be an important objective. The results of the safety analyses performed in this study are consistent with the results of comprehensive safety assessments performed for sites in Sweden, Finland, and Canada. They indicate that a granite repository would satisfy established safety criteria and suggest that a small number of FEPs would largely control the release and transport of radionuclides. In the event the U.S. decides to pursue a potential repository in granite, a detailed evaluation of these FEPs would be needed to

  9. Recent Improvement Of The Institutional Radioactive Waste Management System In Slovenia

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sueiae, S.; Fabjan, M.; Hrastar, U.

    2008-07-01

    The task of managing institutional radioactive waste was assigned to the Slovenian National Agency for Radwaste Management by the Governmental Decree of May 1999. This task ranges from the collection of waste at users' premises to the storage in the Central Storage Facility in (CSF) and afterwards to the planned Low and Intermediate Level Waste (LILW) repository. By this Decree ARAO also became the operator of the CSF. The CSF has been in operation since 1986. Recent improvements of the institutional radioactive waste management system in Slovenia are presented in this paper. ARAO has been working on the reestablishment ofmore » institutional radioactive waste management since 1999. The Agency has managed to prepare the most important documents and carry out the basic activities required by the legislation to assure a safe and environmentally acceptable management of the institutional radioactive waste. With the aim to achieve a better organized operational system, ARAO took the advantage of the European Union Transition Facility (EU TF) financing support and applied for the project named 'Improvement of the management of institutional radioactive waste in Slovenia via the design and implementation of an Information Business System'. Through a public invitation for tenders one of the Slovenian largest software company gained the contract. Two international radwaste experts from Belgium were part of their project team. The optimization of the operational system has been carried out in 2007. The project was executed in ten months and it was divided into two phases. The first phase of the project was related with the detection of weaknesses and implementation of the necessary improvements in the current ARAO operational system. With the evaluation of the existing system, possible improvements were identified. In the second phase of the project the software system Information Business System (IBS) was developed and implemented by the group of IT experts. As a

  10. PROCESSING OF RADIOACTIVE WASTE

    DOEpatents

    Johnson, B.M. Jr.; Barton, G.B.

    1961-11-14

    A process for treating radioactive waste solutions prior to disposal is described. A water-soluble phosphate, borate, and/or silicate is added. The solution is sprayed with steam into a space heated from 325 to 400 deg C whereby a powder is formed. The powder is melted and calcined at from 800 to 1000 deg C. Water vapor and gaseous products are separated from the glass formed. (AEC)

  11. Radioactive Waste Management and Environmental Contamination Issues at the Chernobyl Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Napier, Bruce A.; Schmieman, Eric A.; Voitsekhovitch, Oleg V.

    2007-11-01

    The destruction of the Unit 4 reactor at the Chernobyl Nuclear Power Plant resulted in the generation of radioactive contamination and radioactive waste at the site and in the surrounding area (referred to as the Exclusion Zone). In the course of remediation activities, large volumes of radioactive waste were generated and placed in temporary near surface waste-storage and disposal facilities. Trench and landfill type facilities were created from 1986 to 1987 in the Chernobyl Exclusion Zone at distances 0.5 to 15 km from the NPP site. This large number of facilities was established without proper design documentation, engineered barriers, ormore » hydrogeological investigations and they do not meet contemporary waste-safety requirements. Immediately following the accident, a Shelter was constructed over the destroyed reactor; in addition to uncertainties in stability at the time of its construction, structural elements of the Shelter have degraded as a result of corrosion. The main potential hazard of the Shelter is a possible collapse of its top structures and release of radioactive dust into the environment. A New Safe Confinement (NSC) with a 100-years service life is planned to be built as a cover over the existing Shelter as a longer-term solution. The construction of the NSC will enable the dismantlement of the current Shelter, removal of highly radioactive, fuel-containing materials from Unit 4, and eventual decommissioning of the damaged reactor. More radioactive waste will be generated during NSC construction, possible Shelter dismantling, removal of fuel containing materials, and decommissioning of Unit 4. The future development of the Exclusion Zone depends on the future strategy for converting Unit 4 into an ecologically safe system, i.e., the development of the NSC, the dismantlement of the current Shelter, removal of fuel containing material, and eventual decommissioning of the accident site. To date, a broadly accepted strategy for radioactive

  12. Radioactive waste processing apparatus

    DOEpatents

    Nelson, R.E.; Ziegler, A.A.; Serino, D.F.; Basnar, P.J.

    1985-08-30

    Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container. The chamber may be formed by placing a removable extension over the top of the container. The extension communicates with the apparatus so that such vapors are contained within the container, extension and solution feed apparatus. A portion of the chamber includes coolant which condenses the vapors. The resulting condensate is returned to the container by the force of gravity.

  13. Disposal of low-level radioactive waste. Impact on the medical profession

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brill, D.R.; Allen, E.W.; Lutzker, L.G.

    1985-11-01

    During 1985, low-level radioactive waste disposal has become a critical concern. The issue has been forced by the threatened closure of the three commercial disposal sites. The medical community has used radioactive isotopes for decades in nuclear medicine, radiation therapy, radioimmunoassay, and biomedical research. Loss of disposal capacity for radioactive wastes generated by these activities, by the suppliers of radioisotopes, and by pharmaceutical companies will have a profound impact on the medical profession.

  14. 75 FR 74104 - Request for a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-30

    ... NUCLEAR REGULATORY COMMISSION Request for a License To Export Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear..., August 27, Radioactive waste Not to exceed Return to two Germany. 2010, November 3, 2010, XW018...

  15. 75 FR 27842 - Request for a License to Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-18

    ... NUCLEAR REGULATORY COMMISSION Request for a License to Export Radioactive Waste Pursuant to 10 CFR... Duratek Services, Inc. (a Class A Approximately 680 Storage or Canada. subsidiary of radioactive pounds (53 cubic disposal by the EnergySolutions), April 19, waste in the feet) of dry original 2010, April...

  16. An overview of radioactive waste disposal procedures of a nuclear medicine department.

    PubMed

    Ravichandran, R; Binukumar, J P; Sreeram, Rajan; Arunkumar, L S

    2011-04-01

    Radioactive wastes from hospitals form one of the various types of urban wastes, which are managed in developed countries in a safe and organized way. In countries where growth of nuclear medicine services are envisaged, implementations of existing regulatory policies and guidelines in hospitals in terms of handling of radioactive materials used in the treatment of patients need a good model. To address this issue, a brief description of the methods is presented. A designed prototype waste storage trolley is found to be of great help in decaying the I-131 solid wastes from wards before releasing to waste treatment plant of the city. Two delay tanks with collection time of about 2 months and delay time of 2 months alternately result in 6 releases of urine toilet effluents to the sewage treatment plant (STP) of the hospital annually. Samples of effluents collected at releasing time documented radioactive releases of I-131 much below recommended levels of bi-monthly release. External counting of samples showed good statistical correlation with calculated values. An overview of safe procedures for radioactive waste disposal is presented.

  17. Glasses for immobilization of low- and intermediate-level radioactive waste

    NASA Astrophysics Data System (ADS)

    Laverov, N. P.; Omel'yanenko, B. I.; Yudintsev, S. V.; Stefanovsky, S. V.; Nikonov, B. S.

    2013-03-01

    Reprocessing of spent nuclear fuel (SNF) for recovery of fissionable elements is a precondition of long-term development of nuclear energetics. Solution of this problem is hindered by the production of a great amount of liquid waste; 99% of its volume is low- and intermediate-level radioactive waste (LILW). The volume of high-level radioactive waste (HLW), which is characterized by high heat release, does not exceed a fraction of a percent. Solubility of glasses at an elevated temperature makes them unfit for immobilization of HLW, the insulation of which is ensured only by mineral-like matrices. At the same time, glasses are a perfect matrix for LILW, which are distinguished by low heat release. The solubility of borosilicate glass at a low temperature is so low that even a glass with relatively low resistance enables them to retain safety of under-ground LILW depositories without additional engineering barriers. The optimal technology of liquid confinement is their concentration and immobilization in borosilicate glasses, which are disposed in shallow-seated geological repositories. The vitrification of 1 m3 liquid LILW with a salt concentration of ˜300 kg/m3 leaves behind only 0.2 m3 waste, that is, 4-6 times less than by bitumen impregnation and 10 times less than by cementation. Environmental and economic advantages of LILW vitrification result from (1) low solubility of the vitrified LILW in natural water; (2) significant reduction of LILW volume; (3) possibility to dispose the vitrified waste without additional engineering barriers under shallow conditions and in diverse geological media; (4) the strength of glass makes its transportation and storage possible; and finally (5) reliable longterm safety of repositories. When the composition of the glass matrix for LILW is being chosen, attention should be paid to the factors that ensure high technological and economic efficiency of vitrification. The study of vitrified LILW from the Kursk nuclear power plant

  18. Injector nozzle for molten salt destruction of energetic waste materials

    DOEpatents

    Brummond, William A.; Upadhye, Ravindra S.

    1996-01-01

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

  19. Injector nozzle for molten salt destruction of energetic waste materials

    DOEpatents

    Brummond, W.A.; Upadhye, R.S.

    1996-02-13

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath. 2 figs.

  20. Method for storing radioactive combustible waste

    DOEpatents

    Godbee, H.W.; Lovelace, R.C.

    1973-10-01

    A method is described for preventing pressure buildup in sealed containers which contain radioactively contaminated combustible waste material by adding an oxide getter material to the container so as to chemically bind sorbed water and combustion product gases. (Official Gazette)

  1. [Nationwide survey on radioactive waste management related to positron emission tomography in Japan].

    PubMed

    Nagaoka, Hiroaki; Watanabe, Hiroshi; Yamaguchi, Ichiro; Fujibuchi, Toshioh; Kida, Tetsuo; Tanaka, Shinji

    2009-12-20

    A clearance system for medical radioactive solid waste has not yet been implemented in Japan. Since 2004 new regulations have allowed institutions using positron emission tomography(PET)to handle totally decayed radioactive waste as non-radioactive waste after decay-in-storage. It was expected that this new regulation would mediate the installation of clearance systems in Japan. In order to assess the current situation of radiation safety management in PET institutions, we conducted a nationwide survey. The study design was a cross-sectional descriptive study conducted by questionnaire. The subjects of this survey were all the PET institutions in Japan. Among 224 institutes, 128 institutes are equipped with cyclotrons and 96 institutes are not. The number of returned questionnaires was 138. Among institutes that are using delivered radiopharmaceuticals, 80% treat their waste as non-radioactive according to the new regulation. The impact of new regulations for reducing radioactive waste in PET institutes without a cyclotron was estimated at about $400 thousand per year. The main concern of medical institutes was assessment of the contamination caused by by-products of radioactive nuclides generated in target water during the operation of a cyclotron. It was thought that a rational rule based on scientific risk management should be established because these by-products of radioactive nuclides are negligible for radiation safety. New regulation has had a good influence on medical PET institutes, and it is expected that a clearance system for medical radioactive waste will be introduced in the near future, following these recent experiences in PET institutes.

  2. Sintered bentonite ceramics for the immobilization of cesium- and strontium-bearing radioactive waste

    NASA Astrophysics Data System (ADS)

    Ortega, Luis Humberto

    The Advanced Fuel Cycle Initiative (AFCI) is a Department of Energy (DOE) program, that has been investigating technologies to improve fuel cycle sustainability and proliferation resistance. One of the program's goals is to reduce the amount of radioactive waste requiring repository disposal. Cesium and strontium are two primary heat sources during the first 300 years of spent nuclear fuel's decay, specifically isotopes Cs-137 and Sr-90. Removal of these isotopes from spent nuclear fuel will reduce the activity of the bulk spent fuel, reducing the heat given off by the waste. Once the cesium and strontium are separated from the bulk of the spent nuclear fuel, the isotopes must be immobilized. This study is focused on a method to immobilize a cesium- and strontium-bearing radioactive liquid waste stream. While there are various schemes to remove these isotopes from spent fuel, this study has focused on a nitric acid based liquid waste. The waste liquid was mixed with the bentonite, dried then sintered. To be effective sintering temperatures from 1100 to 1200°C were required, and waste concentrations must be at least 25 wt%. The product is a leach resistant ceramic solid with the waste elements embedded within alumino-silicates and a silicon rich phase. The cesium is primarily incorporated into pollucite and the strontium into a monoclinic feldspar. The simulated waste was prepared from nitrate salts of stable ions. These ions were limited to cesium, strontium, barium and rubidium. Barium and rubidium will be co-extracted during separation due to similar chemical properties to cesium and strontium. The waste liquid was added to the bentonite clay incrementally with drying steps between each addition. The dry powder was pressed and then sintered at various temperatures. The maximum loading tested is 32 wt. percent waste, which refers to 13.9 wt. percent cesium, 12.2 wt. percent barium, 4.1 wt. percent strontium, and 2.0 wt. percent rubidium. Lower loadings of waste

  3. 1st Quarter Transportation Report FY2017: Waste Shipments To and From the Nevada National Security Site (NNSS), Radioactive Waste Management Complex

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gregory, Louis

    This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of waste shipments to the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. This report summarizes the 1st quarter of fiscal year (FY) 2017 low-level radioactive waste (LLW), mixed low-level radioactive waste (MLLW) and classified non-radioactive (CNR) shipments. There were no shipments sent for offsite treatment from a NNSS facility and returned to the NNSS this quarter of FY2017.

  4. HIGH TEMPERATURE TREATMENT OF INTERMEDIATE-LEVEL RADIOACTIVE WASTES - SIA RADON EXPERIENCE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sobolev, I.A.; Dmitriev, S.A.; Lifanov, F.A.

    2003-02-27

    This review describes high temperature methods of low- and intermediate-level radioactive waste (LILW) treatment currently used at SIA Radon. Solid and liquid organic and mixed organic and inorganic wastes are subjected to plasma heating in a shaft furnace with formation of stable leach resistant slag suitable for disposal in near-surface repositories. Liquid inorganic radioactive waste is vitrified in a cold crucible based plant with borosilicate glass productivity up to 75 kg/h. Radioactive silts from settlers are heat-treated at 500-700 0C in electric furnace forming cake following by cake crushing, charging into 200 L barrels and soaking with cement grout. Variousmore » thermochemical technologies for decontamination of metallic, asphalt, and concrete surfaces, treatment of organic wastes (spent ion-exchange resins, polymers, medical and biological wastes), batch vitrification of incinerator ashes, calcines, spent inorganic sorbents, contaminated soil, treatment of carbon containing 14C nuclide, reactor graphite, lubricants have been developed and implemented.« less

  5. NCRP Program Area Committee 5: Environmental Radiation and Radioactive Waste Issues.

    PubMed

    Chen, S Y; Napier, Bruce

    2016-02-01

    Program Area Committee 5 of the National Council on Radiation Protection and Measurements (NCRP) focuses its activities on environmental radiation and radioactive waste issues. The Committee completed a number of reports in these subject areas, most recently NCRP Report No. 175, Decision Making for Late-Phase Recovery from Major Nuclear or Radiological Incidents. Historically this Committee addressed emerging issues of the nation pertaining to radioactivity or radiation in the environment or radioactive waste issues due either to natural origins or to manmade activities.

  6. Alternative Electrochemical Salt Waste Forms, Summary of FY11-FY12 Results

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riley, Brian J.; Mccloy, John S.; Crum, Jarrod V.

    2014-01-17

    The Fuel Cycle Research and Development Program, sponsored by the U.S. Department of Energy Office of Nuclear Energy, is currently investigating alternative waste forms for wastes generated from nuclear fuel processing. One such waste results from an electrochemical separations process, called the “Echem” process. The Echem process utilizes a molten KCl-LiCl salt to dissolve the fuel. This process results in a spent salt containing alkali, alkaline earth, lanthanide halides and small quantities of actinide halides, where the primary halide is chloride with a minor iodide fraction. Pacific Northwest National Laboratory (PNNL) is concurrently investigating two candidate waste forms for themore » Echem spent-salt: high-halide minerals (i.e., sodalite and cancrinite) and tellurite (TeO2)-based glasses. Both of these candidates showed promise in fiscal year (FY) 2009 and FY2010 with a simplified nonradioactive simulant of the Echem waste. Further testing was performed on these waste forms in FY2011 and FY2012 to assess the possibility of their use in a sustainable fuel cycle. This report summarizes the combined results from FY2011 and FY2012 efforts.« less

  7. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jantzen, C.; Crawford, C.; Cozzi, A.

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in themore » time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates

  8. High-level radioactive waste management alternatives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1974-05-01

    A summary of a comprehensive overview study of potential alternatives for long-term management of high-level radioactive waste is presented. The concepts studied included disposal in geologic formations, disposal in seabeds, disposal in ice caps, disposal into space, and elimination by transmutation. (TFD)

  9. Long-Term Modeling of Coupled Processes in a Generic Salt Repository for Heat-Generating Nuclear Waste: Analysis of the Impacts of Halite Solubility Constraints

    NASA Astrophysics Data System (ADS)

    Blanco Martin, L.; Rutqvist, J.; Battistelli, A.; Birkholzer, J. T.

    2015-12-01

    Rock salt is a potential medium for the underground disposal of nuclear waste because it has several assets, such as its ability to creep and heal fractures and its water and gas tightness in the undisturbed state. In this research, we focus on disposal of heat-generating nuclear waste and we consider a generic salt repository with in-drift emplacement of waste packages and crushed salt backfill. As the natural salt creeps, the crushed salt backfill gets progressively compacted and an engineered barrier system is subsequently created [1]. The safety requirements for such a repository impose that long time scales be considered, during which the integrity of the natural and engineered barriers have to be demonstrated. In order to evaluate this long-term integrity, we perform numerical modeling based on state-of-the-art knowledge. Here, we analyze the impacts of halite dissolution and precipitation within the backfill and the host rock. For this purpose, we use an enhanced equation-of-state module of TOUGH2 that properly includes temperature-dependent solubility constraints [2]. We perform coupled thermal-hydraulic-mechanical modeling and we investigate the influence of the mentioned impacts. The TOUGH-FLAC simulator, adapted for large strains and creep, is used [3]. In order to quantify the importance of salt dissolution and precipitation on the effective porosity, permeability, pore pressure, temperature and stress field, we compare numerical results that include or disregard fluids of variable salinity. The sensitivity of the results to some parameters, such as the initial saturation within the backfill, is also addressed. References: [1] Bechthold, W. et al. Backfilling and Sealing of Underground Repositories for Radioactive Waste in Salt (BAMBUS II Project). Report EUR20621 EN: European Atomic Energy Community, 2004. [2] Battistelli A. Improving the treatment of saline brines in EWASG for the simulation of hydrothermal systems. Proceedings, TOUGH Symposium 2012

  10. Technical Aspects Regarding the Management of Radioactive Waste from Decommissioning of Nuclear Facilities

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dragolici, F.; Turcanu, C. N.; Rotarescu, G.

    2003-02-25

    The proper application of the nuclear techniques and technologies in Romania started in 1957, once with the commissioning of the Research Reactor VVR-S from IFIN-HH-Magurele. During the last 45 years, appear thousands of nuclear application units with extremely diverse profiles (research, biology, medicine, education, agriculture, transport, all types of industry) which used different nuclear facilities containing radioactive sources and generating a great variety of radioactive waste during the decommissioning after the operation lifetime is accomplished. A new aspect appears by the planning of VVR-S Research Reactor decommissioning which will be a new source of radioactive waste generated by decontamination, disassemblingmore » and demolition activities. By construction and exploitation of the Radioactive Waste Treatment Plant (STDR)--Magurele and the National Repository for Low and Intermediate Radioactive Waste (DNDR)--Baita, Bihor county, in Romania was solved the management of radioactive wastes arising from operation and decommissioning of small nuclear facilities, being assured the protection of the people and environment. The present paper makes a review of the present technical status of the Romanian waste management facilities, especially raising on treatment capabilities of ''problem'' wastes such as Ra-266, Pu-238, Am-241 Co-60, Co-57, Sr-90, Cs-137 sealed sources from industrial, research and medical applications. Also, contain a preliminary estimation of quantities and types of wastes, which would result during the decommissioning project of the VVR-S Research Reactor from IFIN-HH giving attention to some special category of wastes like aluminum, graphite and equipment, components and structures that became radioactive through neutron activation. After analyzing the technical and scientific potential of STDR and DNDR to handle big amounts of wastes resulting from the decommissioning of VVR-S Research Reactor and small nuclear facilities, the

  11. An overview of radioactive waste disposal procedures of a nuclear medicine department

    PubMed Central

    Ravichandran, R.; Binukumar, J. P.; Sreeram, Rajan; Arunkumar, L. S.

    2011-01-01

    Radioactive wastes from hospitals form one of the various types of urban wastes, which are managed in developed countries in a safe and organized way. In countries where growth of nuclear medicine services are envisaged, implementations of existing regulatory policies and guidelines in hospitals in terms of handling of radioactive materials used in the treatment of patients need a good model. To address this issue, a brief description of the methods is presented. A designed prototype waste storage trolley is found to be of great help in decaying the I-131 solid wastes from wards before releasing to waste treatment plant of the city. Two delay tanks with collection time of about 2 months and delay time of 2 months alternately result in 6 releases of urine toilet effluents to the sewage treatment plant (STP) of the hospital annually. Samples of effluents collected at releasing time documented radioactive releases of I-131 much below recommended levels of bi-monthly release. External counting of samples showed good statistical correlation with calculated values. An overview of safe procedures for radioactive waste disposal is presented. PMID:21731225

  12. Analysis of local acceptance of a radioactive waste disposal facility.

    PubMed

    Chung, Ji Bum; Kim, Hong-Kew; Rho, Sam Kew

    2008-08-01

    Like many other countries in the world, Korea has struggled to site a facility for radioactive waste for almost 30 years because of the strong opposition from local residents. Finally, in 2005, Gyeongju was established as the first Korean site for a radioactive waste facility. The objectives of this research are to verify Gyeongju citizens' average level of risk perception of a radioactive waste disposal facility as compared to other risks, and to explore the best model for predicting respondents' acceptance level using variables related to cost-benefit, risk perception, and political process. For this purpose, a survey is conducted among Gyeongju residents, the results of which are as follows. First, the local residents' risk perception of an accident in a radioactive waste disposal facility is ranked seventh among a total of 13 risks, which implies that nuclear-related risk is not perceived very highly by Gyeongju residents; however, its characteristics are still somewhat negative. Second, the comparative regression analyses show that the cost-benefit and political process models are more suitable for explaining the respondents' level of acceptance than the risk perception model. This may be the result of the current economic depression in Gyeongju, residents' familiarity with the nuclear industry, or cultural characteristics of risk tolerance.

  13. 78 FR 9747 - Request To Amend A License To Import; Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-11

    ... NUCLEAR REGULATORY COMMISSION Request To Amend A License To Import; Radioactive Waste Pursuant to... Country from application no.; docket no. Diversified Scientific Class A radioactive Up to 378,000 Volume reduction...... Canada Services, Inc.; January 10, mixed waste kilograms. Amend to: (1) add four 2013...

  14. Radioactive waste management treatments: A selection for the Italian scenario

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Locatelli, G.; Mancini, M.; Sardini, M.

    2012-07-01

    The increased attention for radioactive waste management is one of the most peculiar aspects of the nuclear sector considering both reactors and not power sources. The aim of this paper is to present the state-of-art of treatments for radioactive waste management all over the world in order to derive guidelines for the radioactive waste management in the Italian scenario. Starting with an overview on the international situation, it analyses the different sources, amounts, treatments, social and economic impacts looking at countries with different industrial backgrounds, energetic policies, geography and population. It lists all these treatments and selects the most reasonablemore » according to technical, economic and social criteria. In particular, a double scenario is discussed (to be considered in case of few quantities of nuclear waste): the use of regional, centralized, off site processing facilities, which accept waste from many nuclear plants, and the use of mobile systems, which can be transported among multiple nuclear sites for processing campaigns. At the end the treatments suitable for the Italian scenario are presented providing simplified work-flows and guidelines. (authors)« less

  15. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crawford, C.; Burket, P.; Cozzi, A.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in themore » time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline

  16. Radioactive and mixed waste - risk as a basis for waste classification. Symposium proceedings No. 2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    The management of risks from radioactive and chemical materials has been a major environmental concern in the United states for the past two or three decades. Risk management of these materials encompasses the remediation of past disposal practices as well as development of appropriate strategies and controls for current and future operations. This symposium is concerned primarily with low-level radioactive wastes and mixed wastes. Individual reports were processed separately for the Department of Energy databases.

  17. Applications Where Snap is BPM for Radioactive Waste Assay

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miller, T.J.

    2008-07-01

    Historically, the Atomic Weapons Establishment (AWE) at Aldermaston in the United Kingdom (UK), has used a variety of assay techniques to measure the radioactive content of a diverse range of waste packages from decommissioning, operational and legacy sources. The regulator, the Environment Agency in the UK, places conditions and limits on AWE through an authorisation within the Radioactive Substances Act (RSA93). The conditions and limits require Best Practical Means (BPM) measurements to be used to demonstrate compliance with the authorisation. Hence, the assay technique employed needs to achieve a balance between risk of exposure, environmental considerations, technological considerations, health andmore » safety considerations and cost effectiveness, without being grossly disproportionate in terms of money, time or trouble. Recently published work has concluded that the Spectral Non-destructive Assay Platform (SNAP) assay system is BPM for Depleted Uranium (DU) waste assay at AWE (1) and low level plutonium in soft drummed waste, HEPA filters and soils (2-4). The purpose of this paper is to highlight other applications where SNAP represents BPM for radioactive waste assay. This has been done by intercomparison studies of SNAP with other assay techniques, such as Segmented Gamma Scanner (SGS) and Passive Neutron Coincidence Counter (PNCC). It has been concluded that, for a large range of waste packages encountered at AWE, SNAP is BPM. (author)« less

  18. Radioactive waste disposal implications of extending Part IIA of the Environmental Protection Act to cover radioactively contaminated land.

    PubMed

    Nancarrow, D J; White, M M

    2004-03-01

    A short study has been carried out of the potential radioactive waste disposal issues associated with the proposed extension of Part IIA of the Environmental Protection Act 1990 to include radioactively contaminated land, where there is no other suitable existing legislation. It was found that there is likely to be an availability problem with respect to disposal at landfills of the radioactive wastes arising from remediation. This is expected to be principally wastes of high volume and low activity (categorised as low level waste (LLW) and very low level waste (VLLW)). The availability problem results from a lack of applications by landfill operators for authorisation to accept LLW wastes for disposal. This is apparently due to perceived adverse publicity associated with the consultation process for authorisation coupled with uncertainty over future liabilities. Disposal of waste as VLLW is limited both by questions over volumes that may be acceptable and, more fundamentally, by the likely alpha activity of wastes (originating from radium and thorium operations). Authorised on-site disposal has had little attention in policy and guidance in recent years, but may have a part to play, especially if considered commercially attractive. Disposal at BNFL's near surface disposal facility for LLW at Drigg is limited to wastes for which there are no practical alternative disposal options (and preference has been given to operational type wastes). Therefore, wastes from the radioactively contaminated land (RCL) regime are not obviously attractive for disposal to Drigg. Illustrative calculations have been performed based on possible volumes and activities of RCL arisings (and assuming Drigg's future volumetric disposal capacity is 950,000 m3). These suggest that wastes arising from implementing the RCL regime, if all disposed to Drigg, would not represent a significant fraction of the volumetric capacity of Drigg, but could have a significant impact on the radiological

  19. Discussions about safety criteria and guidelines for radioactive waste management.

    PubMed

    Yamamoto, Masafumi

    2011-07-01

    In Japan, the clearance levels for uranium-bearing waste have been established by the Nuclear Safety Commission (NSC). The criteria for uranium-bearing waste disposal are also necessary; however, the NSC has not concluded the discussion on this subject. Meanwhile, the General Administrative Group of the Radiation Council has concluded the revision of its former recommendation 'Regulatory exemption dose for radioactive solid waste disposal', the dose criteria after the institutional control period for a repository. The Standardization Committee on Radiation Protection in the Japan Health Physics Society (The Committee) also has developed the relevant safety criteria and guidelines for existing exposure situations, which are potentially applicable to uranium-bearing waste disposal. A new working group established by The Committee was initially aimed at developing criteria and guidelines specifically for uranium-bearing waste disposal; however, the aim has been shifted to broader criteria applicable to any radioactive wastes.

  20. [Current status on storage, processing and risk communication of medical radioactive waste in Japan].

    PubMed

    Watanabe, Hiroshi; Yamaguchi, Ichiro; Kida, Tetsuo; Hiraki, Hitoshi; Fujibuchi, Toshioh; Maehara, Yoshiaki; Tsukamoto, Atsuko; Koizumi, Mitsue; Kimura, Yumi; Horitsugi, Genki

    2013-03-01

    Decay-in-storage for radioactive waste including that of nuclear medicine has not been implemented in Japan. Therefore, all medical radioactive waste is collected and stored at the Japan Radioisotope Association Takizawa laboratory, even if the radioactivity has already decayed out. To clarify the current situation between Takizawa village and Takizawa laboratory, we investigated the radiation management status and risk communication activities at the laboratory via a questionnaire and site visiting survey in June 2010. Takizawa laboratory continues to maintain an interactive relationship with local residents. As a result, Takizawa village permitted the acceptance of new medical radioactive waste containing Sr-89 and Y-90. However, the village did not accept any non-medical radioactive waste such as waste from research laboratories. To implement decay-in-storage in Japan, it is important to obtain agreement with all stakeholders. We must continue to exert sincere efforts to acquire the trust of all stakeholders.

  1. Flowsheets and source terms for radioactive waste projections

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Forsberg, C.W.

    1985-03-01

    Flowsheets and source terms used to generate radioactive waste projections in the Integrated Data Base (IDB) Program are given. Volumes of each waste type generated per unit product throughput have been determined for the following facilities: uranium mining, UF/sub 6/ conversion, uranium enrichment, fuel fabrication, boiling-water reactors (BWRs), pressurized-water reactors (PWRs), and fuel reprocessing. Source terms for DOE/defense wastes have been developed. Expected wastes from typical decommissioning operations for each facility type have been determined. All wastes are also characterized by isotopic composition at time of generation and by general chemical composition. 70 references, 21 figures, 53 tables.

  2. Feasibility of space disposal of radioactive nuclear waste. 2: Technical summary

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The feasibility of transporting radioactive waste produced in the process of generating electricity in nuclear powerplants into space for ultimate disposal was investigated at the request of the AEC as a NASA in-house effort. The investigation is part of a broad AEC study of methods for long-term storage or disposal of radioactive waste. The results of the study indicate that transporting specific radioactive wastes, particularly the actinides with very long half-lives, into space using the space shuttle/tug as the launch system, appears feasible from the engineering and safety viewpoints. The space transportation costs for ejecting the actinides out of the solar system would represent less than a 5-percent increase in the average consumer's electric bill.

  3. The Use of Induction Melting for the Treatment of Metal Radioactive Waste - 13088

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zherebtsov, Alexander; Pastushkov, Vladimir; Poluektov, Pavel

    2013-07-01

    The aim of the work is to assess the efficacy of induction melting metal for recycling radioactive waste in order to reduce the volume of solid radioactive waste to be disposed of, and utilization of the metal. (authors)

  4. Low-level radioactive waste technology: a selected, annotated bibliography

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fore, C.S.; Vaughan, N.D.; Hyder, L.K.

    1980-10-01

    This annotated bibliography of 447 references contains scientific, technical, economic, and regulatory information relevant to low-level radioactive waste technology. The bibliography focuses on environmental transport, disposal site, and waste treatment studies. The publication covers both domestic and foreign literature for the period 1952 to 1979. Major chapters selected are Chemical and Physical Aspects; Container Design and Performance; Disposal Site; Environmental Transport; General Studies and Reviews; Geology, Hydrology and Site Resources; Regulatory and Economic Aspects; Transportation Technology; Waste Production; and Waste Treatment. Specialized data fields have been incorporated into the data file to improve the ease and accuracy of locating pertinentmore » references. Specific radionuclides for which data are presented are listed in the Measured Radionuclides field, and specific parameters which affect the migration of these radionuclides are presented in the Measured Parameters field. In addition, each document referenced in this bibliography has been assigned a relevance number to facilitate sorting the documents according to their pertinence to low-level radioactive waste technology. The documents are rated 1, 2, 3, or 4, with 1 indicating direct applicability to low-level radioactive waste technology and 4 indicating that a considerable amount of interpretation is required for the information presented to be applied. The references within each chapter are arranged alphabetically by leading author, corporate affiliation, or title of the document. Indexes are provide for (1) author(s), (2) keywords, (3) subject category, (4) title, (5) geographic location, (6) measured parameters, (7) measured radionuclides, and (8) publication description.« less

  5. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOEpatents

    Tsai, S.P.

    1997-07-08

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

  6. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOEpatents

    Tsai, Shih-Perng

    1997-01-01

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

  7. Immobilization of LiCl-Li 2 O pyroprocessing salt wastes in chlorosodalite using glass-bonded hydrothermal and salt-occlusion methods

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riley, Brian J.; Peterson, Jacob A.; Kroll, Jared O.

    In this study, salt occlusion and hydrothermal processes were used to make chlorosodalite through reaction with a high-LiCl salt simulating a waste stream following pyrochemical treatment of oxide-based used nuclear fuel. Some products were reacted with glass binders to increase chlorosodalite yield through alkali ion exchange and aide in densification. Hydrothermal processes included reaction of the salt simulant in an acid digestion vessel with either zeolite 4A or sodium aluminate and colloidal silica. Chlorosodalite yields in the crystalline products were nearly complete in the glass-bonded materials at values of 100 mass% for the salt-occlusion method, up to 99.0 mass% formore » the hydrothermal synthesis with zeolite 4A, and up to 96 mass% for the hydrothermal synthesis with sodium aluminate and colloidal silica. These results show promise for using chemically stable chlorosodalite to immobilize oxide reduction salt wastes.« less

  8. Immobilization of LiCl-Li2O pyroprocessing salt wastes in chlorosodalite using glass-bonded hydrothermal and salt-occlusion methods

    NASA Astrophysics Data System (ADS)

    Riley, Brian J.; Peterson, Jacob A.; Kroll, Jared O.; Frank, Steven M.

    2018-04-01

    In this study, hydrothermal and salt-occlusion processes were used to make chlorosodalite through reactions with a high-LiCl salt simulating a waste stream generated from pyrochemical treatment of oxide-based used nuclear fuel. Some products were reacted with glass binders to increase chlorosodalite yield through alkali ion exchange and to aid in densification. Hydrothermal processes included reaction of the salt simulant in an autoclave with either zeolite 4A or sodium aluminate and colloidal silica. Chlorosodalite yields in the crystalline products were nearly complete in the glass-bonded materials at values of 100 mass% for the salt-occlusion method, up to 99.0 mass% for the hydrothermal synthesis with zeolite 4A, and up to 96 mass% for the hydrothermal synthesis with sodium aluminate and colloidal silica. These results show promise for using chemically stable chlorosodalite to immobilize oxide reduction salt wastes.

  9. Public involvement on closure of Asse II radioactive waste repository in Germany

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kallenbach-Herbert, Beate

    2013-07-01

    From 1967 to 1978, about 125,800 barrels of low- and intermediate level waste were disposed of - nominally for research purposes - in the former 'Asse' salt mine which had before been used for the production of potash for many years. Since 1988 an inflow of brine is being observed which will cause dangers of flooding and of a collapse due to salt weakening and dissolution if it should increase. Since several years the closure of the Asse repository is planned with the objective to prevent the flooding and collapse of the mine and the release of radioactive substances tomore » the biosphere. The first concept that was presented by the former operator, however, seemed completely unacceptable to regional representatives from politics and NGOs. Their activities against these plans made the project a top issue on the political agenda from the federal to the local level. The paper traces the main reasons which lead to the severe safety problems in the past as well as relevant changes in the governance system today. A focus is put on the process for public involvement in which the Citizens' Advisory Group 'A2B' forms the core measure. Its structure and framework, experience and results, expectations from inside and outside perspectives are presented. Furthermore the question is tackled how far this process can serve as an example for a participatory approach in a siting process for a geological repository for high active waste which can be expected to be highly contested in the affected regions. (authors)« less

  10. [The main directions of improving the system of state accounting and control of radioactive substances and radioactive waste products].

    PubMed

    2012-01-01

    This paper describes a modification of the basic directions of state accounting and control of radioactive substances and radioactive waste products, whose implementation will significantly improve the efficiency of its operation at the regional level. Selected areas are designed to improve accounting and control system for the submission of the enterprises established by the reporting forms, the quality of the information contained in them, as well as structures of information and process for collecting, analyzing and data processing concerning radioactive substances and waste products.

  11. The Management of the Radioactive Waste Generated by Cernavoda NPP, Romania, an Example of International Cooperation - 13449

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barariu, Gheorghe

    2013-07-01

    The design criteria and constraints for the development of the management strategy for radioactive waste generated from operating and decommissioning of CANDU Nuclear Units from Cernavoda NPP in Romania, present many specific aspects. The main characteristics of CANDU type waste are its high concentrations of tritium and radiocarbon. Also, the existing management strategy for radioactive waste at Cernavoda NPP provides no treatment or conditioning for radioactive waste disposal. These characteristics embodied a challenging effort, in order to select a proper strategy for radioactive waste management at present, when Romania is an EU member and a signatory country of the Jointmore » Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management. The helping of advanced countries in radioactive waste management, directly or into the frame of the international organizations, like IAEA, become solve the aforementioned challenges at adequate level. (authors)« less

  12. RADIOACTIVE WASTE MANAGEMENT IN THE CHERNOBYL EXCLUSION ZONE - 25 YEARS SINCE THE CHERNOBYL NUCLEAR POWER PLANT ACCIDENT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Farfan, E.; Jannik, T.

    2011-10-01

    Radioactive waste management is an important component of the Chernobyl Nuclear Power Plant accident mitigation and remediation activities of the so-called Chernobyl Exclusion Zone. This article describes the localization and characteristics of the radioactive waste present in the Chernobyl Exclusion Zone and summarizes the pathways and strategy for handling the radioactive waste related problems in Ukraine and the Chernobyl Exclusion Zone, and in particular, the pathways and strategies stipulated by the National Radioactive Waste Management Program. The brief overview of the radioactive waste issues in the ChEZ presented in this article demonstrates that management of radioactive waste resulting from amore » beyond-designbasis accident at a nuclear power plant becomes the most challenging and the costliest effort during the mitigation and remediation activities. The costs of these activities are so high that the provision of radioactive waste final disposal facilities compliant with existing radiation safety requirements becomes an intolerable burden for the current generation of a single country, Ukraine. The nuclear accident at the Fukushima-1 NPP strongly indicates that accidents at nuclear sites may occur in any, even in a most technologically advanced country, and the Chernobyl experience shows that the scope of the radioactive waste management activities associated with the mitigation of such accidents may exceed the capabilities of a single country. Development of a special international program for broad international cooperation in accident related radioactive waste management activities is required to handle these issues. It would also be reasonable to consider establishment of a dedicated international fund for mitigation of accidents at nuclear sites, specifically, for handling radioactive waste problems in the ChEZ. The experience of handling Chernobyl radioactive waste management issues, including large volumes of radioactive soils and complex

  13. Lessons Learned from Radioactive Waste Storage and Disposal Facilities

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Esh, David W.; Bradford, Anna H.

    2008-01-15

    The safety of radioactive waste disposal facilities and the decommissioning of complex sites may be predicated on the performance of engineered and natural barriers. For assessing the safety of a waste disposal facility or a decommissioned site, a performance assessment or similar analysis is often completed. The analysis is typically based on a site conceptual model that is developed from site characterization information, observations, and, in many cases, expert judgment. Because waste disposal facilities are sited, constructed, monitored, and maintained, a fair amount of data has been generated at a variety of sites in a variety of natural systems. Thismore » paper provides select examples of lessons learned from the observations developed from the monitoring of various radioactive waste facilities (storage and disposal), and discusses the implications for modeling of future waste disposal facilities that are yet to be constructed or for the development of dose assessments for the release of decommissioning sites. Monitoring has been and continues to be performed at a variety of different facilities for the disposal of radioactive waste. These include facilities for the disposal of commercial low-level waste (LLW), reprocessing wastes, and uranium mill tailings. Many of the lessons learned and problems encountered provide a unique opportunity to improve future designs of waste disposal facilities, to improve dose modeling for decommissioning sites, and to be proactive in identifying future problems. Typically, an initial conceptual model was developed and the siting and design of the disposal facility was based on the conceptual model. After facility construction and operation, monitoring data was collected and evaluated. In many cases the monitoring data did not comport with the original site conceptual model, leading to additional investigation and changes to the site conceptual model and modifications to the design of the facility. The following cases are

  14. Improved low-level radioactive waste management practices for hospitals and research institutions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1983-07-01

    This report provides a general overview and a compendium of source material on low-level radioactive waste management practices in the institutional sector. Institutional sector refers to hospitals, universities, clinics, and research facilities that use radioactive materials in scientific research and the practice of medicine, and the manufacturers of radiopharmaceuticals and radiography devices. This report provides information on effective waste management practices for institutional waste to state policymakers, regulatory agency officials, and waste generators. It is not intended to be a handbook for actual waste management, but rather a sourcebook of general information, as well as a survey of the moremore » detailed analysis.« less

  15. [Investigation of actual condition of management and disposal of medical radioactive waste in Korea].

    PubMed

    Watanabe, Hiroshi; Nagaoka, Hiroaki; Yamaguchi, Ichiro; Horiuchi, Shoji; Imoto, Atsushi

    2009-07-20

    In order to realize the rational management and disposal of radioactive waste like DIS or its clearance as performed in Europe, North America, and Japan, we investigated the situation of medical radioactive waste in Korea and its enforcement. We visited three major Korean facilities in May 2008 and confirmed details of the procedure being used by administering a questionnaire after our visit. From the results, we were able to verify that the governmental agency had established regulations for the clearance of radioactive waste as self-disposal based on the clearance level of IAEA in Korea and that the medical facilities performed suitable management and disposal of radioactive waste based on the regulations and superintendence of a radiation safety officer. The type of nuclear medicine was almost the same as that in Japan, and the half-life of all radiopharmaceuticals was 60 days or less. While performing regulatory adjustment concerning the rational management and disposal of radioactive waste in Korea for reference also in this country, it is important to provide an enforcement procedure with quality assurance in the regulations.

  16. Treatment Study Plan for Nitrate Salt Waste Remediation Revision 1.0

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Juarez, Catherine L.; Funk, David John; Vigil-Holterman, Luciana R.

    2016-03-07

    The two stabilization treatment methods that are to be examined for their effectiveness in the treatment of both the unremediated and remediated nitrate salt wastes include (1) the addition of zeolite and (2) cementation. Zeolite addition is proposed based on the results of several studies and analyses that specifically examined the effectiveness of this process for deactivating nitrate salts. Cementation is also being assessed because of its prevalence as an immobilization method used for similar wastes at numerous facilities around the DOE complex, including at Los Alamos. The results of this Treatment Study Plan will be used to provide themore » basis for a Resource Conservation and Recovery Act (RCRA) permit modification request of the LANL Hazardous Waste Facility Permit for approval by the New Mexico Environment Department-Hazardous Waste Bureau (NMED-HWB) of the proposed treatment process and the associated facilities.« less

  17. Radioactive waste management in the Chernobyl exclusion zone: 25 years since the Chernobyl nuclear power plant accident.

    PubMed

    Oskolkov, Boris Y; Bondarkov, Mikhail D; Zinkevich, Lubov I; Proskura, Nikolai I; Farfán, Eduardo B; Jannik, G Timothy

    2011-10-01

    Radioactive waste management is an important component of the Chernobyl Nuclear Power Plant accident mitigation and remediation activities in the so-called Chernobyl Exclusion Zone. This article describes the localization and characteristics of the radioactive waste present in the Chernobyl Exclusion Zone and summarizes the pathways and strategy for handling the radioactive waste-related problems in Ukraine and the Chernobyl Exclusion Zone and, in particular, the pathways and strategies stipulated by the National Radioactive Waste Management Program.

  18. 76 FR 58543 - Draft Policy Statement on Volume Reduction and Low-Level Radioactive Waste Management

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-21

    ...-Level Radioactive Waste Management AGENCY: Nuclear Regulatory Commission. ACTION: Reopening of comment... for public comment a draft Policy Statement on Volume Reduction and Low-Level Radioactive Waste Management that updates the 1981 Policy Statement on Low-Level Waste Volume Reduction. The revised Policy...

  19. An Improvement to Low-Level Radioactive Waste Vitrification Processes.

    DTIC Science & Technology

    1986-05-01

    waste stream. 3 9 Sodium and Potassium tetraphenyl borates are both cited in the literature as having high cesium selectivity. 23󈧝󈧫 The thermal... Ferrate (II) Impregnated Zeolite for Cesium Removal from Radioactive Waste," Nuc. Tech., 58, p.242, ANS, La Grange Park, Illinois, (1982T. 29. F.V

  20. Rare Earth Electrochemical Property Measurements and Phase Diagram Development in a Complex Molten Salt Mixture for Molten Salt Recycle

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Jinsuo; Guo, Shaoqiang

    Pyroprocessing is a promising alternative for the reprocessing of used nuclear fuel (UNF) that uses electrochemical methods. Compared to the hydrometallurgical reprocessing method, pyroprocessing has many advantages such as reduced volume of radioactive waste, simple waste processing, ability to treat refractory material, and compatibility with fast reactor fuel recycle. The key steps of the process are the electro-refining of the spent metallic fuel in the LiCl-KCl eutectic salt, which can be integrated with an electrolytic reduction step for the reprocessing of spent oxide fuels.

  1. Commentary: Radioactive Wastes and Damage to Marine Communities

    ERIC Educational Resources Information Center

    Wallace, Bruce

    1974-01-01

    Discusses the effects of radioactive wastes on marine communities, with particular reference to the fitness of populations and the need for field and laboratory studies to provide evidence of ecological change. (JR)

  2. Radioactive waste management: review on clearance levels and acceptance criteria legislation, requirements and standards.

    PubMed

    Maringer, F J; Suráň, J; Kovář, P; Chauvenet, B; Peyres, V; García-Toraño, E; Cozzella, M L; De Felice, P; Vodenik, B; Hult, M; Rosengård, U; Merimaa, M; Szücs, L; Jeffery, C; Dean, J C J; Tymiński, Z; Arnold, D; Hinca, R; Mirescu, G

    2013-11-01

    In 2011 the joint research project Metrology for Radioactive Waste Management (MetroRWM)(1) of the European Metrology Research Programme (EMRP) started with a total duration of three years. Within this project, new metrological resources for the assessment of radioactive waste, including their calibration with new reference materials traceable to national standards will be developed. This paper gives a review on national, European and international strategies as basis for science-based metrological requirements in clearance and acceptance of radioactive waste. © 2013 Elsevier Ltd. All rights reserved.

  3. Protein removal from waste brines generated during ham salting through acidification and centrifugation.

    PubMed

    Gutiérrez-Martínez, Maria del Rosario; Muñoz-Guerrero, Hernán; Alcaína-Miranda, Maria Isabel; Barat, José Manuel

    2014-03-01

    The salting step in food processes implies the production of large quantities of waste brines, having high organic load, high conductivity, and other pollutants with high oxygen demand. Direct disposal of the residual brine implies salinization of soil and eutrophication of water. Since most of the organic load of the waste brines comes from proteins leaked from the salted product, precipitation of dissolved proteins by acidification and removal by centrifugation is an operation to be used in waste brine cleaning. The aim of this study is optimizing the conditions for carrying out the separation of proteins from waste brines generated in the pork ham salting operation, by studying the influence of pH, centrifugal force, and centrifugation time. Models for determining the removal of proteins depending on the pH, centrifugal force, and time were obtained. The results showed a high efficacy of the proposed treatment for removing proteins, suggesting that this method could be used for waste brine protein removal. The best pH value to be used in an industrial process seems to be 3, while the obtained results indicate that almost 90% of the proteins from the brine can be removed by acidification followed by centrifugation. A further protein removal from the brine should have to be achieved using filtrating techniques, which efficiency could be highly improved as a consequence of the previous treatment through acidification and centrifugation. Waste brines from meat salting have high organic load and electrical conductivity. Proteins can be removed from the waste brine by acidification and centrifugation. The total protein removal can be up to 90% of the initial content of the waste brine. Protein removal is highly dependent on pH, centrifugation rate, and time. © 2014 Institute of Food Technologists®

  4. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.

    amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive

  5. Brine flow in heated geologic salt.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuhlman, Kristopher L.; Malama, Bwalya

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes governing equations, which can be used to predict brine flow. These equations are valid under a wide varietymore » of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.« less

  6. Industrial Technology of Decontamination of Liquid Radioactive Waste in SUE MosSIA 'Radon' - 12371

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Adamovich, Dmitry V.; Neveykin, Petr P.; Karlin, Yuri V.

    SUE MosSIA 'RADON' - this enterprise was created more than 50 years ago, which deals with the recycling of radioactive waste and conditioning of spent sources of radiation in stationary and mobile systems in the own factory and operating organizations. Here is represented the experience SUE MosSIA 'Radon' in the field of the management with liquid radioactive waste. It's shown, that the activity of SUE MosSIA 'RADON' is developing in three directions - improvement of technical facilities for treatment of radioactive waters into SUE MosSIA 'RADON' development of mobile equipment for the decontamination of radioactive waters in other organizations, developmentmore » of new technologies for decontamination of liquid radioactive wastes as part of various domestic Russian and international projects including those related to the operation of nuclear power and nuclear submarines. SUE MosSIA 'RADON' has processed more than 270 thousand m{sup 3} of radioactive water, at that more than 7000 m{sup 3} in other organizations for more than 50 years. It is shown that a number of directions, particularly, the development of mobile modular units for decontamination of liquid radioactive waste, SUE MosSIA 'RADON' is a leader in the world. (authors)« less

  7. Real-time alpha monitoring of a radioactive liquid waste stream at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Johnson, J.D.; Whitley, C.R.; Rawool-Sullivan, M.

    1995-12-31

    This poster display concerns the development, installation, and testing of a real-time radioactive liquid waste monitor at Los Alamos National Laboratory (LANL). The detector system was designed for the LANL Radioactive Liquid Waste Treatment Facility so that influent to the plant could be monitored in real time. By knowing the activity of the influent, plant operators can better monitor treatment, better segregate waste (potentially), and monitor the regulatory compliance of users of the LANL Radioactive Liquid Waste Collection System. The detector system uses long-range alpha detection technology, which is a nonintrusive method of characterization that determines alpha activity on themore » liquid surface by measuring the ionization of ambient air. Extensive testing has been performed to ensure long-term use with a minimal amount of maintenance. The final design was a simple cost-effective alpha monitor that could be modified for monitoring influent waste streams at various points in the LANL Radioactive Liquid Waste Collection System.« less

  8. Radioactive liquid wastes discharged to ground in the 200 Areas during 1976

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mirabella, J.E.

    An overall summary is presented giving the radioactive liquid wastes discharged to ground during 1976 and since startup (for both total and decayed depositions) within the Production and Waste Management Division control zone (200 Area plateau). Overall summaries are also presented for 200 East Area and for 200 West Area. The data contain an estimate of the radioactivity discharged to individual ponds, cribs and specific retention sites within the Production and Waste Management Division during 1976 and from startup through December 31, 1976; an estimate of the decayed activities from startup through 1976; the location and reference drawings of eachmore » disposal site; and the usage dates of each disposal site. The estimates for the radioactivity discharged and for decayed activities dicharged from startup through December 31, 1976 are based upon Item 4 of the Bibliography. The volume of liquid discharged to the ponds also includes major nonradioactive streams. The wastes discharged during 1976 to each active disposal site are detailed on a month-to-month basis, along with the monthly maximum concentration and average concentration data. An estimate of the radioactivity discharged to each active site along with the remaining decayed activities is given.« less

  9. On the importance of coupled THM processes to predict the long-term response of a generic salt repository for high-level nuclear waste

    NASA Astrophysics Data System (ADS)

    Blanco Martin, L.; Rutqvist, J.; Birkholzer, J. T.

    2013-12-01

    has been introduced and validated. The time-dependent geomechanical response of salt is determined using the Lux/Wolters constitutive model, developed at Clausthal University of Technology (Germany). References: [1] R. Wolters, and K.-H. Lux. Evaluation of Rock Salt Barriers with Respect to Tightness: Influence of Thermomechanical Damage, Fluid Infiltration and Sealing/Healing. Proceedings of the 7th International Conference on the Mechanical Behavior of Salt (SaltMech7). Paris: Balkema, Rotterdam (2012). [2] W. Bechthold et al., Backfilling and Sealing of Underground Repositories for Radioactive Waste in Salt (BAMBUS Project), European Atomic Energy Community, Report EUR19124 EN (1999). [3] J. Kim, E.L Sonnenthal and J. Rutqvist, 'Formulation and sequential numerical algorithms of coupled fluid/heat flow and geomechanics for multiple porosity materials', Int. J. Numer. Meth. Engng., 92, 425 (2012). [4] J. Rutqvist. Status of the TOUGH-FLAC simulator and recent applications related to coupled fluid flow and crustal deformations. Computational Geosciences, 37, 739-750 (2011).

  10. Radioactive waste from decommissioning of fast reactors (through the example of BN-800)

    NASA Astrophysics Data System (ADS)

    Rybin, A. A.; Momot, O. A.

    2017-01-01

    Estimation of volume of radioactive waste from operating and decommissioning of fast reactors is introduced. Preliminary estimation has shown that the volume of RW from decommissioning of BN-800 is amounted to 63,000 cu. m. Comparison of the amount of liquid radioactive waste derived from operation of different reactor types is performed. Approximate costs of all wastes disposal for complete decommissioning of BN-800 reactor are estimated amounting up to approx. 145 million.

  11. Annual Radioactive Waste Tank Inspection Program 1994

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McNatt, F.G. Sr.

    1995-04-01

    Aqueous radioactive wastes from Savannah River Site (SRS) separations processes are contained in large underground carbon steel tanks. Inspections made during 1994 to evaluate these vessels and evaluations based on data accrued by inspections made since the tanks were constructed are the subject of this report.

  12. Options Assessment Report: Treatment of Nitrate Salt Waste at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-12-17

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognizes that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and that a modification to the LANL Hazardous Waste Facility Permitmore » is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL’s preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.« less

  13. Radioactive wastes in biological research institutions (in French)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kirchmann, R.

    1973-01-01

    The different radioelements used in the Belgian Biological Research Laboratories and the activities used are indicated. The types of utilization of / sup 3/H, /sup 14/C, /sup 32/P, /sup 125/I, /sup 131/I, /sup 85/Sr, and /sup 226/ Ra are given. The handling procedures for contaminated wastes of these radionuclides are described. The release of radioactive waste by all the laboratories which were investigated is estimated. (auth)

  14. 10 CFR 51.62 - Environmental report-land disposal of radioactive waste licensed under 10 CFR part 61.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 2 2013-01-01 2013-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...

  15. 10 CFR 51.62 - Environmental report-land disposal of radioactive waste licensed under 10 CFR part 61.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...

  16. 10 CFR 51.62 - Environmental report-land disposal of radioactive waste licensed under 10 CFR part 61.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 2 2014-01-01 2014-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...

  17. 10 CFR 51.62 - Environmental report-land disposal of radioactive waste licensed under 10 CFR part 61.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 2 2012-01-01 2012-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...

  18. 10 CFR 51.62 - Environmental report-land disposal of radioactive waste licensed under 10 CFR part 61.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...

  19. Solidification Technologies for Radioactive and Chemical Liquid Waste Treatment - Final CRADA Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Castiglioni, Andrew J.; Gelis, Artem V.

    This project, organized under DOE/NNSA's Global Initiatives for Proliferation Prevention program, joined Russian and DOE scientists in developing more effective solidification and storage technologies for liquid radioactive waste. Several patent applications were filed by the Russian scientists (Russia only) and in 2012, the technology developed was approved by Russia's Federal State Unitary Enterprise RADON for application throughout Russia in cleaning up and disposing of radioactive waste.

  20. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOEpatents

    Kalb, Paul D.; Colombo, Peter

    1999-07-20

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  1. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOEpatents

    Kalb, Paul D.; Colombo, Peter

    1998-03-24

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  2. Composition and process for the encapsulation and stabilization of radioactive hazardous and mixed wastes

    DOEpatents

    Kalb, P.D.; Colombo, P.

    1997-07-15

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a ``clean`` polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  3. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOEpatents

    Kalb, P.D.; Colombo, P.

    1998-03-24

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a ``clean`` polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  4. Composition and process for the encapsulation and stabilization of radioactive hazardous and mixed wastes

    DOEpatents

    Kalb, Paul D.; Colombo, Peter

    1997-01-01

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogenous molten matrix. The molten matrix may be directed in a "clean" polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment.

  5. Composition and process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

    DOEpatents

    Kalb, P.D.; Colombo, P.

    1999-07-20

    The present invention provides a composition and process for disposal of radioactive, hazardous and mixed wastes. The present invention preferably includes a process for multibarrier encapsulation of radioactive, hazardous and mixed wastes by combining substantially simultaneously dry waste powder, a non-biodegradable thermoplastic polymer and an anhydrous additive in an extruder to form a homogeneous molten matrix. The molten matrix may be directed in a clean'' polyethylene liner, allowed to cool, thus forming a monolithic waste form which provides a multibarrier to the dispersion of wastes into the environment. 2 figs.

  6. 25 CFR 170.903 - Who notifies tribes of the transport of radioactive waste?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Who notifies tribes of the transport of radioactive waste? 170.903 Section 170.903 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER... § 170.903 Who notifies tribes of the transport of radioactive waste? The Department of Energy (DOE) has...

  7. 25 CFR 170.903 - Who notifies tribes of the transport of radioactive waste?

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 1 2011-04-01 2011-04-01 false Who notifies tribes of the transport of radioactive waste? 170.903 Section 170.903 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER... § 170.903 Who notifies tribes of the transport of radioactive waste? The Department of Energy (DOE) has...

  8. Development of a universal solvent for the decontamination of acidic liquid radioactive wastes

    NASA Astrophysics Data System (ADS)

    Todd, T. A.; Brewer, K. N.; Law, J. D.; Wood, D. J.; Herbest, R. S.; Romanovskiy, V. N.; Esimantovskiy, V. M.; Smirnov, I. V.; Babain, V. A.

    1999-01-01

    A teritiary solvent containing chlorinated cobalt dicarbollide, polyethylene glycol and diphenylcarbamoylmethylphosphine oxide was evaluated in different non-nitroaromatic diluents for the separation of cesium, strontium, actinides and rare earth elements from acidic liquid radioactive waste. Decontamination factors of >95% for Cs, 99.7% for Sr, and 99.99% for actinides were achieved in four successive batch contacts using actual radioactive waste. Pilot plant testing in centrifugal contactors using simulated wastes, has demonstrated removal of >99% of all targeted ions.

  9. Assessment of lead tellurite glass for immobilizing electrochemical salt wastes from used nuclear fuel reprocessing

    NASA Astrophysics Data System (ADS)

    Riley, Brian J.; Kroll, Jared O.; Peterson, Jacob A.; Pierce, David A.; Ebert, William L.; Williams, Benjamin D.; Snyder, Michelle M. V.; Frank, Steven M.; George, Jaime L.; Kruska, Karen

    2017-11-01

    This paper provides an overview of research evaluating the use of lead tellurite glass as a waste form for salt wastes from electrochemical reprocessing of used nuclear fuel. The efficacy of using lead tellurite glass to immobilize three different salt compositions was evaluated: a LiCl-Li2O oxide reduction salt containing fission products from oxide fuel, a LiCl-KCl eutectic salt containing fission products from metallic fuel, and SrCl2. Physical and chemical properties of glasses made with these salts were characterized with X-ray diffraction, bulk density measurements, differential thermal analysis, chemical durability tests, scanning and transmission electron microscopies, and energy-dispersive X-ray spectroscopy. These glasses were found to accommodate high salt concentrations and have high densities, but further development is needed to improve chemical durability.

  10. Processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  11. Processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1998-05-12

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  12. Base of fresh ground water, northern Louisiana Salt-Dome Basin and vicinity, northern Louisiana and southern Arkansas

    USGS Publications Warehouse

    Ryals, G.N.

    1980-01-01

    The National Waste Terminal Storage Program is an effort by the U.S. Department of Energy to locate and develop sites for disposal or storage of commercially produced radioactive wastes. As part of this program, salt domes in the northern Louisiana salt-dome basin are being studied to determine their suitability as repositories. Part of the U.S. Geological Survey 's participation in the program has been to describe the regional geohydrology of the northern Louisiana salt-dome basin. A map based on a compilation of published data and the interpretation of electrical logs shows the altitude of the base of freshwater in aquifers in the northern Louisiana salt-dome basin. (USGS)

  13. Iraq liquid radioactive waste tanks maintenance and monitoring program plan.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dennis, Matthew L.; Cochran, John Russell; Sol Shamsaldin, Emad

    2011-10-01

    The purpose of this report is to develop a project management plan for maintaining and monitoring liquid radioactive waste tanks at Iraq's Al-Tuwaitha Nuclear Research Center. Based on information from several sources, the Al-Tuwaitha site has approximately 30 waste tanks that contain varying amounts of liquid or sludge radioactive waste. All of the tanks have been non-operational for over 20 years and most have limited characterization. The program plan embodied in this document provides guidance on conducting radiological surveys, posting radiation control areas and controlling access, performing tank hazard assessments to remove debris and gain access, and conducting routine tankmore » inspections. This program plan provides general advice on how to sample and characterize tank contents, and how to prioritize tanks for soil sampling and borehole monitoring.« less

  14. A Challenge for Radioactive Waste Management: Memory Preservation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Charton, P.; Ouzounian, G.

    2008-07-01

    ANDRA, the French National Radioactive Waste Management Agency, is responsible for managing all radioactive waste in France over the long term. In the case of short-lived waste for which disposal facilities have a life expectancy of a few centuries, the Agency has set up a system for preserving the memory of those sites. Based on the historical analysis on a comparable timescale and on an appraisal of information-conservation means, a series of regulatory as well as technical provisions was made in order to ensure that sound information be transmitted to future generations. Requirements associated to the provisions deal mostly withmore » legibility and a clear understanding of the information that must be decrypted and understood at least during the lifetime of the facilities (i.e., a few centuries). It must therefore be preserved throughout the same period. Responses to the requirements will be presented notably on various information-recording media, together with the information-diffusion strategy to the different authorities and structures within French society. A concrete illustration of the achievements made so far is the Centre de la Manche Disposal Facility, which was closed down in 1994 and is currently in its post-closure monitoring phase since 2003. In the case of deep geological repositories for long-lived radioactive waste, preserving memory takes a different aspect. First of all, timescales are much longer and are counted in hundreds of thousands of years. It is therefore much more difficult to consider how to maintain the richness of the information over such time periods than it is for short-lived waste. Both the nature and the form of the information to be transmitted must be revised. It would be risky indeed to base memory preservation over the long term on similar mechanisms beyond 1,000 years. Based on the heritage of a much more ancient history, we must seek to find appropriate means in order to develop surface markers and even more to ensure

  15. Topic I: Induced changes in hydrology at low-level radioactive waste repository sites: A section in Safe disposal of radionuclides in low-level radioactive-waste repository sites; Low-level radioactive-waste disposal workshop, U.S. Geological Survey, July 11-16, 1987, Big Bear Lake, Calif., Proceedings (Circular 1036)

    USGS Publications Warehouse

    Prudic, David E.; Dennehy, Kevin F.; Bedinger, Marion S.; Stevens, Peter R.

    1990-01-01

    Engineering practices, including the excavation of trenches, placement of waste, nature of waste forms, backfilling procedures and materials, and trench-cover construction and materials at low-level radioactive-waste repository sites greatly affect the geohydrology of the sites. Engineering practices are dominant factors in eventual stability and isolation of the waste. The papers presented relating to Topic I were discussions of the hydrogeologic setting at existing low-level radioactive-waste repository sites and changes in the hydrology induced by site operations. Papers summarizing detailed studies presented at this workshop include those at sites near Sheffield, Ill.; Oak Ridge National Laboratory, Tenn.; West Valley, N.Y.; Maxey Flats, Ky.; Barnwell, S.C.; and Beatty, Nev. 

  16. Radioactive Waste Characterization Strategies; Comparisons Between AK/PK, Dose to Curie Modeling, Gamma Spectroscopy, and Laboratory Analysis Methods- 12194

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singledecker, Steven J.; Jones, Scotty W.; Dorries, Alison M.

    2012-07-01

    In the coming fiscal years of potentially declining budgets, Department of Energy facilities such as the Los Alamos National Laboratory (LANL) will be looking to reduce the cost of radioactive waste characterization, management, and disposal processes. At the core of this cost reduction process will be choosing the most cost effective, efficient, and accurate methods of radioactive waste characterization. Central to every radioactive waste management program is an effective and accurate waste characterization program. Choosing between methods can determine what is classified as low level radioactive waste (LLRW), transuranic waste (TRU), waste that can be disposed of under an Authorizedmore » Release Limit (ARL), industrial waste, and waste that can be disposed of in municipal landfills. The cost benefits of an accurate radioactive waste characterization program cannot be overstated. In addition, inaccurate radioactive waste characterization of radioactive waste can result in the incorrect classification of radioactive waste leading to higher disposal costs, Department of Transportation (DOT) violations, Notice of Violations (NOVs) from Federal and State regulatory agencies, waste rejection from disposal facilities, loss of operational capabilities, and loss of disposal options. Any one of these events could result in the program that mischaracterized the waste losing its ability to perform it primary operational mission. Generators that produce radioactive waste have four characterization strategies at their disposal: - Acceptable Knowledge/Process Knowledge (AK/PK); - Indirect characterization using a software application or other dose to curie methodologies; - Non-Destructive Analysis (NDA) tools such as gamma spectroscopy; - Direct sampling (e.g. grab samples or Surface Contaminated Object smears) and laboratory analytical; Each method has specific advantages and disadvantages. This paper will evaluate each method detailing those advantages and disadvantages

  17. Integrated data base report--1996: US spent nuclear fuel and radioactive waste inventories, projections, and characteristics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1997-12-01

    The Integrated Data Base Program has compiled historic data on inventories and characteristics of both commercial and U.S. Department of Energy (DOE) spent nuclear fuel (SNF) and commercial and U.S. government-owned radioactive wastes. Inventories of most of these materials are reported as of the end of fiscal year (FY) 1996, which is September 30, 1996. Commercial SNF and commercial uranium mill tailings inventories are reported on an end-of-calendar year (CY) basis. All SNF and radioactive waste data reported are based on the most reliable information available from government sources, the open literature, technical reports, and direct contacts. The information forecastedmore » is consistent with the latest DOE/Energy Information Administration (EIA) projections of U.S. commercial nuclear power growth and the expected DOE-related and private industrial and institutional activities. The radioactive materials considered, on a chapter-by-chapter basis, are SNF, high-level waste, transuranic waste, low-level waste, uranium mill tailings, DOE Environmental Restoration Program contaminated environmental media, naturally occurring and accelerator-produced radioactive material, and mixed (hazardous and radioactive) low-level waste. For most of these categories, current and projected inventories are given through FY 2030, and the radioactivity and thermal power are calculated based on reported or estimated isotopic compositions.« less

  18. A review and overview of nuclear waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Murray, R.L.

    1984-12-31

    An understanding of the status and issues in the management of radioactive wastes is based on technical information on radioactivity, radiation, biological hazard of radiation exposure, radiation standards, and methods of protection. The fission process gives rise to radioactive fission products and neutron bombardment gives activation products. Radioactive wastes are classified according to source: defense, commercial, industrial, and institutional; and according to physical features: uranium mill tailings, high-level, transuranic, and low-level. The nuclear fuel cycle, which contributes a large fraction of annual radioactive waste, starts with uranium ore, includes nuclear reactor use for electrical power generation, and ends with ultimatemore » disposal of residues. The relation of spent fuel storage and reprocessing is governed by technical, economic, and political considerations. Waste has been successfully solidified in glass and other forms and choices of the containers for the waste form are available. Methods of disposal of high-level waste that have been investigated are transmutation by neutron bombardment, shipment to Antartica, deep-hole insertion, subseabed placement, transfer by rocket to an orbit in space, and disposal in a mined cavity. The latter is the favored method. The choices of host geological media are salt, basalt, tuff, and granite.« less

  19. Assessment of lead tellurite glass for immobilizing electrochemical salt wastes from used nuclear fuel reprocessing

    DOE PAGES

    Riley, Brian J.; Kroll, Jared O.; Peterson, Jacob A.; ...

    2017-08-30

    Here, this paper provides an overview of research evaluating the use of lead tellurite glass as a waste form for salt wastes from electrochemical reprocessing of used nuclear fuel. The efficacy of using lead tellurite glass to immobilize three different salt compositions was evaluated: a LiCl-Li 2O oxide reduction salt containing fission products from oxide fuel, a LiCl-KCl eutectic salt containing fission products from metallic fuel, and SrCl 2. Physical and chemical properties of glasses made with these salts were characterized with X-ray diffraction, bulk density measurements, differential thermal analysis, chemical durability tests, scanning and transmission electron microscopies, and energy-dispersivemore » X-ray spectroscopy. These glasses were found to accommodate high salt concentrations and have high densities, but further development is needed to improve chemical durability.« less

  20. Biochemical process of low level radioactive liquid simulation waste containing detergent

    NASA Astrophysics Data System (ADS)

    Kundari, Noor Anis; Putra, Sugili; Mukaromah, Umi

    2015-12-01

    Research of biochemical process of low level radioactive liquid waste containing detergent has been done. Thse organic liquid wastes are generated in nuclear facilities such as from laundry. The wastes that are cotegorized as hazard and poison materials are also radioactive. It must be treated properly by detoxification of the hazard and decontamination of the radionuclides to ensure that the disposal of the waste meets the requirement of standard quality of water. This research was intended to determine decontamination factor and separation efficiensies, its kinetics law, and to produce a supernatant that ensured the environmental quality standard. The radioactive element in the waste was thorium with activity of 5.10-5 Ci/m3. The radioactive liquid waste which were generated in simulation plant contains detergents that was further processed by aerobic biochemical process using SGB 103 bacteria in a batch reactor equipped with aerators. Two different concentration of samples were processed and analyzed for 212 hours and 183 hours respectively at a room temperature. The product of this process is a liquid phase called as supernatant and solid phase material called sludge. The chemical oxygen demand (COD), biological oxygen demand (BOD), suspended solid (SS), and its alpha activity were analyzed. The results show that the decontamination factor and the separation efficiency of the lower concentration samples are higher compared to the samples with high concentration. Regarding the decontamination factor, the result for 212 hours processing of waste with detergent concentration of 1.496 g/L was 3.496 times, whereas at the detergent concentration of 0.748 g/L was 15.305 times for 183 hours processing. In case of the separation efficiency, the results for both samples were 71.396% and 93.465% respectively. The Bacterial growth kinetics equation follow Monod's model and the decreasing of COD and BOD were first order with the rate constant of 0.01 hour-1.

  1. Biochemical process of low level radioactive liquid simulation waste containing detergent

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kundari, Noor Anis, E-mail: nooranis@batan.go.id; Putra, Sugili; Mukaromah, Umi

    Research of biochemical process of low level radioactive liquid waste containing detergent has been done. Thse organic liquid wastes are generated in nuclear facilities such as from laundry. The wastes that are cotegorized as hazard and poison materials are also radioactive. It must be treated properly by detoxification of the hazard and decontamination of the radionuclides to ensure that the disposal of the waste meets the requirement of standard quality of water. This research was intended to determine decontamination factor and separation efficiensies, its kinetics law, and to produce a supernatant that ensured the environmental quality standard. The radioactive elementmore » in the waste was thorium with activity of 5.10{sup −5} Ci/m{sup 3}. The radioactive liquid waste which were generated in simulation plant contains detergents that was further processed by aerobic biochemical process using SGB 103 bacteria in a batch reactor equipped with aerators. Two different concentration of samples were processed and analyzed for 212 hours and 183 hours respectively at a room temperature. The product of this process is a liquid phase called as supernatant and solid phase material called sludge. The chemical oxygen demand (COD), biological oxygen demand (BOD), suspended solid (SS), and its alpha activity were analyzed. The results show that the decontamination factor and the separation efficiency of the lower concentration samples are higher compared to the samples with high concentration. Regarding the decontamination factor, the result for 212 hours processing of waste with detergent concentration of 1.496 g/L was 3.496 times, whereas at the detergent concentration of 0.748 g/L was 15.305 times for 183 hours processing. In case of the separation efficiency, the results for both samples were 71.396% and 93.465% respectively. The Bacterial growth kinetics equation follow Monod’s model and the decreasing of COD and BOD were first order with the rate constant of

  2. 76 FR 56490 - Request for a License To Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-13

    ... No., docket No. Duratek Services, Inc., August Class A radioactive Radionuclide For recycle and Canada. 17, 2011, August 18, 2011, waste in the form reallocation: beneficial reuse IW017/02, 11005621. of radioactively Amend to: to the greatest contaminated (1) Reduce the possible extent, materials...

  3. Improving radioactive waste management: an overview of the Environmental Protection Agency's low-activity waste effort.

    PubMed

    Schultheisz, Daniel J; Czyscinski, Kenneth S; Klinger, Adam D

    2006-11-01

    Radioactive waste disposal in the United States is marked by a fragmented regulatory system, with requirements that often focus on the origin or statutory definition of the waste, rather than the hazard of the material in question. It may be possible to enhance public protection by moving toward a system that provides disposal options appropriate for the hazard presented by the waste in question. This paper summarizes aspects of an approach focusing on the potential use, with appropriate conditions, of Resource Conservation and Recovery Act Subtitle-C hazardous waste landfills for disposal of "low-activity" wastes and public comments on the suggested approach.

  4. Hazards Associated with Legacy Nitrate Salt Waste Drums Managed under the Container Isolation Plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Funk, David John; Clark, David Lewis

    At present, there are 29 drums of nitrate waste salts (oxidizers with potentially acidic liquid bearing RCRA characteristics D001 and D002) that are awaiting processing, specifically to eliminate these characteristics and to allow for ultimate disposition at WIPP. As a result of the Feb. 14th, 2014 drum breach at WIPP, and the subsequent identification of the breached drum as a product ofLANL TRU waste disposition on May 15th, 2014, these 29 containers were moved into the Perrnacon in Dome 231 at TA-54 Area G, as part of the New Mexico Environment Department (NMED) approved container isolation plan. The plan ismore » designed to mitigate hazards associated with the nitrate salt bearing waste stream. The purpose of this document is to articulate the hazards associated with un-remediated nitrate salts while in storage at LANL. These hazards are distinctly different from the Swheat-remediated nitrate salt bearing drums, and this document is intended to support the request to remove the un-remediated drums from management under the container isolation plan. Plans to remediate and/or treat both of these waste types are being developed separately, and are beyond the scope of this document.« less

  5. Corrosion of radioactive waste tanks containing washed sludge and precipitates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bickford, D.F.; Congdon, J.W.; Oblath, S.B.

    1988-05-01

    At the US Department of Energy (DOE) Savannah River Plant, the corrosion of carbon steel storage tanks containing alkaline, high-level radioactive waste is controlled by specification of limits on waste composition and temperature. Laboratory tests, conducted to determine minimum corrosion inhibitor levels, indicated pitting of carbon steel near the waterline for proposed storage conditions. In situ electrochemical measurements of full-scale radioactive process demonstrations were conducted to assess the validity of laboratory tests. The in situ results are compared to those of laboratory tests, with particular regard given to simulated solution composition. Transition metal hydroxide sludge contains strong passivating species formore » carbon steel. Washed precipitate contains organic species that lower solution pH and tend to reduce passivating films, requiring higher inhibitor concentrations than the 0.01 M nitrite required for reactor fuel reprocessing wastes.« less

  6. Solvent for the simultaneous recovery of radionuclides from liquid radioactive wastes

    DOEpatents

    Romanovskiy, Valeriy Nicholiavich; Smirnov, Igor V.; Babain, Vasiliy A.; Todd, Terry A.; Brewer, Ken N.

    2002-01-01

    The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

  7. Biodegradation of the alkaline cellulose degradation products generated during radioactive waste disposal.

    PubMed

    Rout, Simon P; Radford, Jessica; Laws, Andrew P; Sweeney, Francis; Elmekawy, Ahmed; Gillie, Lisa J; Humphreys, Paul N

    2014-01-01

    The anoxic, alkaline hydrolysis of cellulosic materials generates a range of cellulose degradation products (CDP) including α and β forms of isosaccharinic acid (ISA) and is expected to occur in radioactive waste disposal sites receiving intermediate level radioactive wastes. The generation of ISA's is of particular relevance to the disposal of these wastes since they are able to form complexes with radioelements such as Pu enhancing their migration. This study demonstrates that microbial communities present in near-surface anoxic sediments are able to degrade CDP including both forms of ISA via iron reduction, sulphate reduction and methanogenesis, without any prior exposure to these substrates. No significant difference (n = 6, p = 0.118) in α and β ISA degradation rates were seen under either iron reducing, sulphate reducing or methanogenic conditions, giving an overall mean degradation rate of 4.7 × 10(-2) hr(-1) (SE ± 2.9 × 10(-3)). These results suggest that a radioactive waste disposal site is likely to be colonised by organisms able to degrade CDP and associated ISA's during the construction and operational phase of the facility.

  8. Radioactive waste handling and disposal at King Faisal Specialist Hospital and Research Centre.

    PubMed

    Al-Haj, Abdalla N; Lobriguito, Aida M; Al Anazi, Ibrahim

    2012-08-01

    King Faisal Specialist Hospital & Research Centre (KFSHRC) is the largest specialized medical center in Saudi Arabia. It performs highly specialized diagnostic imaging procedures with the use of various radionuclides required by sophisticated dual imaging systems. As a leading institution in cancer research, KFSHRC uses both long-lived and short-lived radionuclides. KFSHRC established the first cyclotron facility in the Middle East, which solved the in-house high demand for radionuclides and the difficulty in importing them. As both user and producer of high standard radiopharmaceuticals, KFSHRC generates large volumes of low and high level radioactive wastes. An old and small radioactive facility that was used for storage of radioactive waste was replaced with a bigger warehouse provided with facilities that will reduce radiation exposure of the staff, members of the public, and of the environment in the framework of "as low as reasonably achievable." The experiences and the effectiveness of the radiation protection program on handling and storage of radioactive wastes are presented.

  9. Use of petrophysical data for siting of deep geological repository of radioactive waste

    NASA Astrophysics Data System (ADS)

    Petrenko, Liliana; Shestopalov, Vyacheslav

    2017-11-01

    The paper is devoted to analyzing the petrophysical properties and petrographical characteristics of Volyn region with the view to choosing the least permeable and so the most suitable geological formation for the radioactive waste disposal. On a basis of the petrophysical estimations of the granitoids properties the argumentation of permeability has been developed for the petrotypes of Volyn region. Also method of classification of the petrotypes with their relative rate of suitability for radioactive waste disposal was developed. As a result of studying the perspectives were shown of the zhytomyr and korosten types of the granitoids as host rock for the radioactive waste disposal. According to the results of investigations performed by Swedish researchers a comparative analysis of rocks based on the age of formation, composition, structural features and some petrophysical properties of granitoids as host rocks for repository of radioactive waste was performed. Detail comparison the data of the granitoids of the Forsmark site in Sweden and the data of the granitoids of the Volyn megablock can be one of the next steps in researching the host rocks for the development of the RW disposal system in Ukraine.

  10. GIVE THE PUBLIC SOMETHING, SOMETHING MORE INTERESTING THAN RADIOACTIVE WASTE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Codee, Hans D.K.

    2003-02-27

    In the Netherlands the policy to manage radioactive waste is somewhat different from that in other countries, although the practical outcome is not much different. Long-term, i.e. at least 100 years, storage in above ground engineered structures of all waste types is the first element in the Dutch policy. Second element, but equally important, is that deep geologic disposal is foreseen after the storage period. This policy was brought out in the early eighties and was communicated to the public as a practical, logical and feasible management system for the Dutch situation. Strong opposition existed at that time to deepmore » disposal in salt domes in the Netherlands. Above ground storage at principle was not rejected because the need to do something was obvious. Volunteers for a long term storage site did not automatically emerge. A site selection procedure was followed and resulted in the present site at Vlissingen-Oost. The waste management organization, COVRA, was not really welcomed here , but was tolerated. In the nineties facilities for low and medium level waste were erected and commissioned. In the design of the facilities much attention was given to emotional factors. The first ten operational years were needed to gain trust from the local population. Impeccable conduct and behavior was necessary as well as honesty and full openness to the public Now, after some ten years, the COVRA facilities are accepted. And a new phase is entered with the commissioning of the storage facility for high level waste, the HABOG facility. A visit to that facility will not be very spectacular, activities take place only during loading and unloading. Furthermore it is a facility for waste, so unwanted material will be brought into the community. In order to give the public something more interesting the building itself is transformed into a piece of art and in the inside a special work of art will be displayed. Together with that the attitude of the company will change. We

  11. Radioactive Waste Conditioning, Immobilisation, And Encapsulation Processes And Technologies: Overview And Advances (Chapter 7)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jantzen, Carol M.; Lee, William E.; Ojovan, Michael I.

    The main immobilization technologies that are available commercially and have been demonstrated to be viable are cementation, bituminization, and vitrification. Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either alkali borosilicate glass or alkali aluminophosphate glass. The exact compositions of nuclear waste glasses are tailored for easy preparation and melting, avoidance of glass-in-glass phase separation, avoidance of uncontrolled crystallization, and acceptable chemical durability, e.g., leach resistance. Glass has also been used to stabilize a variety of lowmore » level wastes (LLW) and mixed (radioactive and hazardous) low level wastes (MLLW) from other sources such as fuel rod cladding/decladding processes, chemical separations, radioactive sources, radioactive mill tailings, contaminated soils, medical research applications, and other commercial processes. The sources of radioactive waste generation are captured in other chapters in this book regarding the individual practices in various countries (legacy wastes, currently generated wastes, and future waste generation). Future waste generation is primarily driven by interest in sources of clean energy and this has led to an increased interest in advanced nuclear power production. The development of advanced wasteforms is a necessary component of the new nuclear power plant (NPP) flowsheets. Therefore, advanced nuclear wasteforms are being designed for robust disposal strategies. A brief summary is given of existing and advanced wasteforms: glass, glass-ceramics, glass composite materials (GCM’s), and crystalline ceramic (mineral) wasteforms that chemically incorporate radionuclides and hazardous species atomically in their structure. Cementitious, geopolymer, bitumen, and other encapsulant wasteforms and composites that atomically bond and

  12. System for handling and storing radioactive waste

    DOEpatents

    Anderson, J.K.; Lindemann, P.E.

    1982-07-19

    A system and method are claimed for handling and storing spent reactor fuel and other solid radioactive waste, including canisters to contain the elements of solid waste, storage racks to hold a plurality of such canisters, storage bays to store these racks in isolation by means of shielded doors in the bays. This system also includes means for remotely positioning the racks in the bays and an access tunnel within which the remotely operated means is located to position a rack in a selected bay. The modular type of these bays will facilitate the construction of additional bays and access tunnel extension.

  13. System for handling and storing radioactive waste

    DOEpatents

    Anderson, John K.; Lindemann, Paul E.

    1984-01-01

    A system and method for handling and storing spent reactor fuel and other solid radioactive waste, including canisters to contain the elements of solid waste, storage racks to hold a plurality of such canisters, storage bays to store these racks in isolation by means of shielded doors in the bays. This system also includes means for remotely positioning the racks in the bays and an access tunnel within which the remotely operated means is located to position a rack in a selected bay. The modular type of these bays will facilitate the construction of additional bays and access tunnel extension.

  14. Radiological protection from radioactive waste management in existing exposure situations resulting from a nuclear accident.

    PubMed

    Sugiyama, Daisuke; Hattori, Takatoshi

    2013-01-01

    In environmental remediation after nuclear accidents, radioactive wastes have to be appropriately managed in existing exposure situations with contamination resulting from the emission of radionuclides by such accidents. In this paper, a framework of radiation protection from radioactive waste management in existing exposure situations for application to the practical and reasonable waste management in contaminated areas, referring to related ICRP recommendations was proposed. In the proposed concept, intermediate reference levels for waste management are adopted gradually according to the progress of the reduction in the existing ambient dose in the environment on the basis of the principles of justification and optimisation by taking into account the practicability of the management of radioactive waste and environmental remediation. It is essential to include the participation of relevant stakeholders living in existing exposure situations in the selection of reference levels for the existing ambient dose and waste management.

  15. Radiological protection from radioactive waste management in existing exposure situations resulting from a nuclear accident

    PubMed Central

    Sugiyama, Daisuke; Hattori, Takatoshi

    2013-01-01

    In environmental remediation after nuclear accidents, radioactive wastes have to be appropriately managed in existing exposure situations with contamination resulting from the emission of radionuclides by such accidents. In this paper, a framework of radiation protection from radioactive waste management in existing exposure situations for application to the practical and reasonable waste management in contaminated areas, referring to related ICRP recommendations was proposed. In the proposed concept, intermediate reference levels for waste management are adopted gradually according to the progress of the reduction in the existing ambient dose in the environment on the basis of the principles of justification and optimisation by taking into account the practicability of the management of radioactive waste and environmental remediation. It is essential to include the participation of relevant stakeholders living in existing exposure situations in the selection of reference levels for the existing ambient dose and waste management. PMID:22719047

  16. Source term evaluation model for high-level radioactive waste repository with decay chain build-up.

    PubMed

    Chopra, Manish; Sunny, Faby; Oza, R B

    2016-09-18

    A source term model based on two-component leach flux concept is developed for a high-level radioactive waste repository. The long-lived radionuclides associated with high-level waste may give rise to the build-up of activity because of radioactive decay chains. The ingrowths of progeny are incorporated in the model using Bateman decay chain build-up equations. The model is applied to different radionuclides present in the high-level radioactive waste, which form a part of decay chains (4n to 4n + 3 series), and the activity of the parent and daughter radionuclides leaching out of the waste matrix is estimated. Two cases are considered: one when only parent is present initially in the waste and another where daughters are also initially present in the waste matrix. The incorporation of in situ production of daughter radionuclides in the source is important to carry out realistic estimates. It is shown that the inclusion of decay chain build-up is essential to avoid underestimation of the radiological impact assessment of the repository. The model can be a useful tool for evaluating the source term of the radionuclide transport models used for the radiological impact assessment of high-level radioactive waste repositories.

  17. Treatment of radioactive liquid waste by sorption on natural zeolite in Turkey.

    PubMed

    Osmanlioglu, Ahmet Erdal

    2006-09-01

    Liquid radioactive waste has been generated from the use of radioactive materials in industrial applications, research and medicine in Turkey. Natural zeolites (clinoptilolite) have been studied for the removal of several key radionuclides ((137)Cs, (60)Co, (90)Sr and (110m)Ag) from liquid radioactive waste. The aim of the present study is to investigate effectiveness of zeolite treatment on decontamination factor (DF) in a combined process (chemical precipitation and adsorption) at the laboratory tests and scale up to the waste treatment plant. In this study, sorption and precipitation techniques were adapted to decontamination of liquid low level waste (LLW). Effective decontamination was achieved when sorbents are used during the chemical precipitation. Natural zeolite samples were taken from different zeolite formations in Turkey. Comparison of the ion-exchange properties of zeolite minerals from different formations shows that Gordes clinoptilolite was the most suitable natural sorbent for radionuclides under dynamic treatment conditions and as an additive for chemical precipitation process. Clinoptilolite were shown to have a high selectivity for (137)Cs and (110m)Ag as sorbent. In the absence of potassium ions, native clinoptilolite removed (60)Co and (90)Sr very effectively from the liquid waste. In the end of this liquid waste treatment, decontamination factor was provided as 430 by using 0.5 mm clinoptilolite at 30 degrees C.

  18. Bituminization of radioactive wastes: safety studies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Arod, J.

    1982-01-01

    The bitumen embedding of low- and medium-level radioactive wastes has reached the industrial stage. Bituminization plants are operating satisfactorily in France and throughout the world. However, bituminization presents certain risks due to the nature of bitumens themselves. These risks must be taken into account. This paper specifies those risks and presents the results of leachability tests performed in accordance with the International Atomic Energy Agency proposed standard on coated concentrates, on chemical coprecipitation sludges with and without addition of heavy solvents such as TBP and TLA, and on ion exchange resins. The results show that the leaching rates in demineralizedmore » water are on the order of 10/sup -6/ to 10/sup -8/ for cesium 137, 10/sup -5/ to 10/sup -7/ for strontium-90, 10/sup -5/ to 10/sup -6/ for ruthemium-106, 10/sup -5/ to 10/sup -6/ for cobalt-60, 10/sup -5/ to 10/sup -6/ for total gamma activity, and 10/sup -5/ to 10/sup -8/ for the plutonium-238, the plutonium-239, and the americium 241 alpha emitters. Even if this conditioning is not perfect, the storage of low- and medium-level radioactive wastes is made possible with adequate safety and at a reasonable cost.« less

  19. System for chemically digesting low level radioactive, solid waste material

    DOEpatents

    Cowan, Richard G.; Blasewitz, Albert G.

    1982-01-01

    An improved method and system for chemically digesting low level radioactive, solid waste material having a high through-put. The solid waste material is added to an annular vessel (10) substantially filled with concentrated sulfuric acid. Concentrated nitric acid or nitrogen dioxide is added to the sulfuric acid within the annular vessel while the sulfuric acid is reacting with the solid waste. The solid waste is mixed within the sulfuric acid so that the solid waste is substantilly fully immersed during the reaction. The off gas from the reaction and the products slurry residue is removed from the vessel during the reaction.

  20. 10 CFR 72.108 - Spent fuel, high-level radioactive waste, or reactor-related greater than Class C waste...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... RADIOACTIVE WASTE, AND REACTOR-RELATED GREATER THAN CLASS C WASTE Siting Evaluation Factors § 72.108 Spent... proposed ISFSI or MRS must be evaluated with respect to the potential impact on the environment of the...

  1. Method for utilizing decay heat from radioactive nuclear wastes

    DOEpatents

    Busey, H.M.

    1974-10-14

    Management of radioactive heat-producing waste material while safely utilizing the heat thereof is accomplished by encapsulating the wastes after a cooling period, transporting the capsules to a facility including a plurality of vertically disposed storage tubes, lowering the capsules as they arrive at the facility into the storage tubes, cooling the storage tubes by circulating a gas thereover, employing the so heated gas to obtain an economically beneficial result, and continually adding waste capsules to the facility as they arrive thereat over a substantial period of time.

  2. Spent fuel and high-level radioactive waste transportation report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educatedmore » layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages sew be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.« less

  3. Spent fuel and high-level radioactive waste transportation report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educatedmore » layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.« less

  4. Spent Fuel and High-Level Radioactive Waste Transportation Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by SSEB in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or nomore » background in nuclear waste Issues. In addition. this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.« less

  5. Environmental assessment, finding of no significant impact, and response to comments. Radioactive waste storage

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    The Department of Energy`s (DOE) Rocky Flats Environmental Technology Site (the Site), formerly known as the Rocky Flats Plant, has generated radioactive, hazardous, and mixed waste (waste with both radioactive and hazardous constituents) since it began operations in 1952. Such wastes were the byproducts of the Site`s original mission to produce nuclear weapons components. Since 1989, when weapons component production ceased, waste has been generated as a result of the Site`s new mission of environmental restoration and deactivation, decontamination and decommissioning (D&D) of buildings. It is anticipated that the existing onsite waste storage capacity, which meets the criteria for low-levelmore » waste (LL), low-level mixed waste (LLM), transuranic (TRU) waste, and TRU mixed waste (TRUM) would be completely filled in early 1997. At that time, either waste generating activities must cease, waste must be shipped offsite, or new waste storage capacity must be developed.« less

  6. Innovative Process for Comprehensive Treatment of Liquid Radioactive Waste - 12551

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Penzin, R.A.; Sarychev, G.A.

    those containing hardness salts, resulted in generation of LRW concentrate 300-600 g/l. The method is based on utilization of supersonic ejector for intensification of thermal physic processes and performance of evaporation in brine recycling mode. All proposed technological solutions are totally based on patented Russian developments. Proposed work will allow to construct modular plants, which will be totally prepared for efficient purification of any types of liquid radioactive wastes from radionuclides in case of force majeure. According to proposed scheme concentration level of cesium radionuclides in safe-for-storage form will make up not less than 5000. With respect to purification from cesium radionuclides of liquid radioactive wastes stored at NPP 'Fukushima' about 10 t of inorganic sorbents, loaded in 160 protective filter-containers, will be required for solving this problem. The amount of secondary wastes will be reduced approximately in 5 times in comparison with traditional schemes, applied in purification of secondary LRW of Fukushima-1 by Areva (France) and Kurion (USA) companies. All units of modular plants will be constructed and manufactured as totally automated, providing their twenty-four-hour safe operation. Modular design will ensure efficiency and let optimize the costs of secondary LRW treatment. In order to ensure off-line operation in emergency conditions the plant should be equipped with auxiliary modules: energy and ventilation ones. Under normal conditions these modules can be stored in 'mothballed' condition at special warehouses under the authority of federal bodies. It will be reasonable to choose required transport facilities, the most suitable for transportation of modules to target destination beforehand, using vessel classification list.« less

  7. Disposal of Radioactive Waste at Hanford Creates Problems

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1978

    1978-01-01

    Radioactive storage tanks at the Hanford facility have developed leaks. The situation is presently considered safe, but serious. A report from the National Academy of Science has recommended that the wastes be converted to stable solids and stored at another site on the Hanford Reservation. (Author/MA)

  8. Radioactive Waste...The Problem and Some Possible Solutions

    ERIC Educational Resources Information Center

    Olivier, Jean-Pierre

    1977-01-01

    Nuclear safety is a highly technical and controversial subject that has caused much heated debate and political concern. This article examines the problems involved in managing radioactive wastes and the techniques now used. Potential solutions are suggested and the need for international cooperation is stressed. (Author/MA)

  9. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM- 2007

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B; Ruel Waltz, R

    2008-06-05

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. The 2007 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. A very small amount of material had seeped from Tank 12 from a previously identified leaksite. The material observed had dried on the tank wall and did not reach the annulus floor. A total of 5945 photographs were made and 1221 visual and video inspections were performed during 2007. Additionally, ultrasonic testing was performed on four Waste Tanksmore » (15, 36, 37 and 38) in accordance with approved inspection plans that met the requirements of WSRC-TR-2002- 00061, Revision 2 'In-Service Inspection Program for High Level Waste Tanks'. The Ultrasonic Testing (UT) In-Service Inspections (ISI) are documented in a separate report that is prepared by the ISI programmatic Level III UT Analyst. Tanks 15, 36, 37 and 38 are documented in 'Tank Inspection NDE Results for Fiscal Year 2007'; WSRC-TR-2007-00064.« less

  10. Feasibility of Space Disposal of Radioactive Nuclear Waste. 1: Executive Summary

    NASA Technical Reports Server (NTRS)

    1973-01-01

    This NASA study, performed at the request of the AEC, concludes that transporting radioactive waste (primarily long-lived isotopes) into space is feasible. Tentative solutions are presented for technical problems involving safe packaging. Launch systems (existing and planned), trajectories, potential hazards, and various destinations were evaluated. Solar system escape is possible and would have the advantage of ultimate removal of the radioactive waste from man's environment. Transportation costs would be low (comparable to less than a 5 percent increase in the cost of electricity) even though more than 100 space shuttle launches per year would be required by the year 2000.

  11. Removal of radioactive and other hazardous material from fluid waste

    DOEpatents

    Tranter, Troy J [Idaho Falls, ID; Knecht, Dieter A [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Burchfield, Larry A [W. Richland, WA; Anshits, Alexander G [Krasnoyarsk, RU; Vereshchagina, Tatiana [Krasnoyarsk, RU; Tretyakov, Alexander A [Zheleznogorsk, RU; Aloy, Albert S [St. Petersburg, RU; Sapozhnikova, Natalia V [St. Petersburg, RU

    2006-10-03

    Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.

  12. Hydrogeologic factors in the selection of shallow land burial sites for the disposal of low-level radioactive waste

    USGS Publications Warehouse

    Fischer, John N.

    1986-01-01

    In the United States, low-level radioactive waste is disposed of by shallow land burial. Commercial low-level radioactive waste has been buried at six sites, and low-level radioactive waste generated by the Federal Government has been buried at nine major and several minor sites. Several existing low-level radioactive waste sites have not provided expected protection of the environment. These shortcomings are related, at least in part, to an inadequate understanding of site hydrogeology at the time the sites were selected. To better understand the natural systems and the effect of hydrogeologic factors on long-term site performance, the U.S. Geological Survey has conducted investigations at five of the six commercial low-level radioactive waste sites and at three Federal sites. These studies, combined with those of other Federal and State agencies, have identified and confirmed important hydrogeologic factors in the effective disposal of low-level radioactive waste by shallow land burial. These factors include precipitation, surface drainage, topography, site stability, geology, thickness of the host soil-rock horizon, soil and sediment permeability, soil and water chemistry, and depth to the water table.

  13. Waste Isolation Pilot Plant Salt Decontamination Testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Demmer, Ricky Lynn; Reese, Stephen Joseph

    2015-03-01

    On February 14, 2014, americium and plutonium contamination was released in the Waste Isolation Pilot Plant (WIPP) salt caverns. Several practical, easily deployable methods of decontaminating WIPP salt, using a surrogate contaminant and americium (241Am), were developed and tested. The effectiveness of the methods is evaluated qualitatively, and to the extent practical, quantitatively. Of the methods tested (dry brushing, vacuum cleaning, water washing, mechanical grinding, strippable coatings, and fixative barriers), the most practical seems to be water washing. Effectiveness is very high, and water washing is easy and rapid to deploy. The amount of wastewater produced (~2 L/m2) would bemore » substantial and may not be easy to manage, but the method is the clear winner from a usability perspective. Removable surface contamination levels (smear results) from water washed coupons found no residual removable contamination. Thus, whatever contamination is left is likely adhered to (or trapped within) the salt. The other option that shows promise is the use of a fixative barrier. Bartlett Nuclear, Inc.’s Polymeric Barrier System proved the most durable of the coatings tested. The coatings were not tested for contaminant entrapment, only for coating integrity and durability.« less

  14. Proceedings of the 7th US/German Workshop on Salt Repository Research, Design, and Operation.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hansen, Francis D.; Steininger, Walter; Bollingerfehr, Willhelm

    The 7th US/German Workshop on Salt Repository Research, Design, and Operation was held in Washington, DC on September 7-9, 2016. Over fifty participants representing governmental agencies, internationally recognized salt research groups, universities, and private companies helped advance the technical basis for salt disposal of radioactive waste. Representatives from several United States federal agencies were able to attend, including the Department of Energy´s Office of Environmental Management and Office of Nuclear Energy, the Environmental Protection Agency, the Nuclear Regulatory Commission, and the Nuclear Waste Technical Review Board. A similar representation from the German ministries showcased the covenant established in a Memorandummore » of Understanding executed between the United States and Germany in 2011. The US/German workshops´ results and activities also contribute significantly to the Nuclear Energy Agency Salt Club repository research agenda.« less

  15. Bonded carbon or ceramic fiber composite filter vent for radioactive waste

    DOEpatents

    Brassell, Gilbert W.; Brugger, Ronald P.

    1985-02-19

    Carbon bonded carbon fiber composites as well as ceramic or carbon bonded ceramic fiber composites are very useful as filters which can separate particulate matter from gas streams entraining the same. These filters have particular application to the filtering of radioactive particles, e.g., they can act as vents for containers of radioactive waste material.

  16. Radiation safety requirements for radioactive waste management in the framework of a quality management system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Salgado, M.M.; Benitez, J.C.; Pernas, R.

    2007-07-01

    The Center for Radiation Protection and Hygiene (CPHR) is the institution responsible for the management of radioactive wastes generated from nuclear applications in medicine, industry and research in Cuba. Radioactive Waste Management Service is provided at a national level and it includes the collection and transportation of radioactive wastes to the Centralized Waste Management Facilities, where they are characterized, segregated, treated, conditioned and stored. A Quality Management System, according to the ISO 9001 Standard has been implemented for the RWM Service at CPHR. The Management System includes the radiation safety requirements established for RWM in national regulations and in themore » Licence's conditions. The role of the Regulatory Body and the Radiation Protection Officer in the Quality Management System, the authorization of practices, training and personal qualification, record keeping, inspections of the Regulatory Body and internal inspection of the Radiation Protection Officer, among other aspects, are described in this paper. The Quality Management System has shown to be an efficient tool to demonstrate that adequate measures are in place to ensure the safety in radioactive waste management activities and their continual improvement. (authors)« less

  17. Special Analysis for the Disposal of the INL Waste Associated with the Unirradiated Light Water Breeder Reactor (LWBR) Waste Stream at the Area 5 Radioactive Waste Management Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shott, Gregory

    This special analysis (SA) evaluates whether the Idaho National Laboratory (INL) Waste Associated with the Unirradiated Light Water Breeder Reactor (LWBR) waste stream (INEL167203QR1, Revision 0) is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the INL Waste Associated with the Unirradiated LWBR waste meets all U.S. Department of Energy (DOE) Manual DOE M 435.1-1, “Radioactive Waste Management Manual,” Chapter IV, Section P performance objectives (DOE 1999). The INL Waste Associated with the Unirradiated LWBR waste stream is recommended for acceptance with the conditionmore » that the total uranium-233 ( 233U) inventory be limited to 2.7E13 Bq (7.2E2 Ci).« less

  18. Characterization of Class A low-level radioactive waste 1986--1990. Volume 6: Appendices G--J

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dehmel, J.C.; Loomis, D.; Mauro, J.

    1994-01-01

    Under contract to the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, the firms of S. Cohen & Associates, Inc. (SC&A) and Eastern Research Group (ERG) have compiled a report that describes the physical, chemical, and radiological properties of Class-A low-level radioactive waste. The report also presents information characterizing various methods and facilities used to treat and dispose non-radioactive waste. A database management program was developed for use in accessing, sorting, analyzing, and displaying the electronic data provided by EG&G. The program was used to present and aggregate data characterizing the radiological, physical, and chemical properties of the wastemore » from descriptions contained in shipping manifests. The data thus retrieved are summarized in tables, histograms, and cumulative distribution curves presenting radionuclide concentration distributions in Class-A waste as a function of waste streams, by category of waste generators, and regions of the United States. The report also provides information characterizing methods and facilities used to treat and dispose non-radioactive waste, including industrial, municipal, and hazardous waste regulated under Subparts C and D of the Resource Conservation and Recovery Act (RCRA). The information includes a list of disposal options, the geographical locations of the processing and disposal facilities, and a description of the characteristics of such processing and disposal facilities. Volume 1 contains the Executive Summary, Volume 2 presents the Class-A waste database, Volume 3 presents the information characterizing non-radioactive waste management practices and facilities, and Volumes 4 through 7 contain Appendices A through P with supporting information.« less

  19. Ceramization of low and intermediate level radioactive wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fiquet, O.; Berson, X.

    1993-12-31

    A ceramic conditioning is studied for a large variety of low and intermediate level wastes. These wastes arise from several waste streams coming from all process steps of the fuel cycle. The physical properties of ceramics can advantageously be used for radioactive waste immobilization. Their chemical durability can offer a barrier against external aggression. More over, some minerals have possible host sites in their crystal structure for heavy elements which can confer the best immobilization mechanism. The general route for development studies is described giving compositions and process choices. Investigations have been conducted on clay materials and on the processmore » parameters which condition the final product properties. Two practical examples are described concerning chemical precipitation sludge resulting from liquid waste treatment and chamot used as a fluidized bed in a graphite incinerator. Important process parameters are put in evidence and the possibility of a pilot plant development is briefly mentioned. Results of investigations are promising to define a new route of conditioning.« less

  20. Engineering Deinococcus geothermalis for Bioremediation of High-Temperature Radioactive Waste Environments

    PubMed Central

    Brim, Hassan; Venkateswaran, Amudhan; Kostandarithes, Heather M.; Fredrickson, James K.; Daly, Michael J.

    2003-01-01

    Deinococcus geothermalis is an extremely radiation-resistant thermophilic bacterium closely related to the mesophile Deinococcus radiodurans, which is being engineered for in situ bioremediation of radioactive wastes. We report that D. geothermalis is transformable with plasmids designed for D. radiodurans and have generated a Hg(II)-resistant D. geothermalis strain capable of reducing Hg(II) at elevated temperatures and in the presence of 50 Gy/h. Additionally, D. geothermalis is capable of reducing Fe(III)-nitrilotriacetic acid, U(VI), and Cr(VI). These characteristics support the prospective development of this thermophilic radiophile for bioremediation of radioactive mixed waste environments with temperatures as high as 55°C. PMID:12902245

  1. Method of encapsulating solid radioactive waste material for storage

    DOEpatents

    Bunnell, Lee Roy; Bates, J. Lambert

    1976-01-01

    High-level radioactive wastes are encapsulated in vitreous carbon for long-term storage by mixing the wastes as finely divided solids with a suitable resin, formed into an appropriate shape and cured. The cured resin is carbonized by heating under a vacuum to form vitreous carbon. The vitreous carbon shapes may be further protected for storage by encasement in a canister containing a low melting temperature matrix material such as aluminum to increase impact resistance and improve heat dissipation.

  2. 78 FR 7818 - Request To Amend a License To Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-04

    ... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear... Recipient country application no.; docket No. Eastern Technologies, Inc.; Class A radioactive The total...

  3. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS)more » feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.« less

  4. Salt deposits in Los Medanos area, Eddy and Lea counties, New Mexico

    USGS Publications Warehouse

    Jones, C.L.; with sections on Ground water hydrology, Cooley; and Surficial Geology, Bachman

    1973-01-01

    The salt deposits of Los Medanos area, in Eddy and Lea Counties, southeastern New Mexico, are being considered for possible use as a receptacle for radioactive wastes in a pilot-plant repository. The salt deposits of the area. are in three evaporite formations: the Castile, Salado, and Rustler Formations, in ascending order. The three formations are dominantly anhydrite and rock salt, but some gypsum, potassium ores, carbonate rock, and fine-grained clastic rocks are present. They have combined thicknesses of slightly more than 4,000 feet, of which roughly one-half belongs to the Salado. Both the Castile and the Rustler are-richer in anhydrite-and poorer in rock salt-than the Salado, and they provide this salt-rich formation with considerable Protection from any fluids which might be present in underlying or overlying rocks. The Salado Formation contains many thick seams of rock salt at moderate depths below the surface. The rock salt has a substantial cover of well-consolidated rocks, and it is very little deformed structurally. Certain geological details essential for Waste-storage purposes are unknown or poorly known, and additional study involving drilling is required to identify seams of rock salt suitable for storage purposes and to establish critical details of their chemistry, stratigraphy, and structure.

  5. Schematic designs for penetration seals for a reference repository in bedded salt

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kelsall, P.C.; Case, J.B.; Meyer, D.

    1982-11-01

    The isolation of radioactive wastes in geologic repositories requires that man-made penetrations such as shafts, tunnels, or boreholes are adequately sealed. This report describes schematic seal designs for a repository in bedded salt referenced to the straitigraphy of southeastern New Mexico. The designs are presented for extensive peer review and will be updated as site-specific conceptual designs when a site for a repository in salt has been selected. The principal material used in the seal system is crushed salt obtained from excavating the repository. It is anticipated that crushed salt will consolidate as the repository rooms creep close to themore » degree that mechanical and hydrologic properties will eventually match those of undisturbed, intact salt. For southeastern New Mexico salt, analyses indicate that this process will require approximately 1000 years for a seal located at the base of one of the repository shafts (where there is little increase in temperature due to waste emplacement) and approximately 400 years for a seal located in an access tunnel within the repository. Bulkheads composed of contrete or salt bricks are also included in the seal system as components which will have low permeability during the period required for salt consolidation.« less

  6. Seismic-refraction survey to the top of salt in the north end of the Salt Valley Anticline, Grand County, Utah

    USGS Publications Warehouse

    Ackermann, Hans D.

    1979-01-01

    A seismic-refraction survey, consisting of three lines about 2700, 2760, and 5460 meters long, was made at the north end of the Salt Valley anticline of the Paradox Basin in eastern Utah. The target was the crest of a diapiric salt mass and the overlying, deformed caprock. The interpretations reveal an undulating salt surface with as much as 80 meters of relief. The minimum depth of about 165 meters is near the location of three holes drilled by the U.S. Department of Energy for the purpose of evaluating the Salt Valley anticline as a potential site for radioactive waste storages Caprock properties were difficult to estimate because the contorted nature of these beds invalidated a geologic interpretation in terms of velocity layers. However, laterally varying velocities of the critically refracted rays throughout the area suggest differences in the gross physical properties of the caprock.

  7. FERRATE TREATMENT FOR REMOVING CHROMIUM FROM HIGH-LEVEL RADIOACTIVE TANK WASTE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sylvester, Paul; Rutherford, Andy; Gonzalez-Martin, Anuncia

    2000-12-01

    A method has been developed for removing chromium from alkaline high-level radioactive tank waste. Removing chromium from these wastes is critical in reducing the volume of waste requiring expensive immobilization and deep geologic disposition. The method developed is based on the oxidation of insoluble chromium(III) compounds to soluble chromate using ferrate. The tests conducted with a simulated Hanford tank sludge indicate that the chromium removal with ferrate is more efficient at 5 M NaOH than at 3 M NaOH. Chromium removal increases with increasing Fe(VI)/Cr(III) molar ratio, but the chromium removal tends to level out for Fe(VI)/Cr(III) greater than 10.more » Increasing temperature leads to better chromium removal, but higher temperatures also led to more rapid ferrate decomposition. Tests with radioactive Hanford tank waste generally confirmed the simulant results. In all cases examined, ferrate enhanced the chromium removal, with a typical removal of around 60-70% of the total chromium present in the washed sludge solids. The ferrate leachate solutions did not contain significant concentrations of transuranic elements, so these solutions could be handled as low-activity waste.« less

  8. Development of characterization protocol for mixed liquid radioactive waste classification

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zakaria, Norasalwa, E-mail: norasalwa@nuclearmalaysia.gov.my; Wafa, Syed Asraf; Wo, Yii Mei

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as ‘problematic’ waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this studymore » is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.« less

  9. The safety improvement of Romanian radioactive waste facilities as an example for human and environmental protection

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barariu, Gheorghe

    2013-07-01

    According to IAEA classification, Romania with two nuclear research centres, with 2 Nuclear Power Units in operation at Cernavoda Town and with 2 new Units envisaged to be in operation soon, can be considered as a country with an average nuclear activity. In Romania there was an extensive interest in management of radioactive wastes generated by the use of nuclear technology in industry and research. Using the most advanced technologies in the mentioned time periods, Romania successfully accomplished to solve all management issues related to radioactive wastes being addressed all safety concerns. Every step of nuclear activity development was accompaniedmore » by the suitable waste management facilities. So that, in order to improve the existing treatment and disposal capacities for institutional waste, the existing Radioactive Waste Treatment Facility (STDR) and the National Repository Radioactive Wastes (DNDR) at Baita, Bihor, will be improved to actual requirements on the occasion of VVR-S Research Reactor decommissioning. This activity is in development into the frame of a National funded project related to disposal galleries filling improvement and repository closure for DNDR Baita, Bihor. All improvements will be approved by Environmental Protection Authority and Regulatory Body, being a guaranty of human and environmental protection. Also, in accordance with national specific and international policies and taking into account decommissioning activities related to the present operating NPPs, all necessary measures were considered in order to avoid unnecessary generation of radioactive wastes, to minimize, as much as possible, waste production and accumulation and the necessity to develop optimum solutions for a new repository with the assurance of improved nuclear safety. (authors)« less

  10. Subsurface geology of a potential waste emplacement site, Salt Valley Anticline, Grand County, Utah

    USGS Publications Warehouse

    Hite, R.J.

    1977-01-01

    The Salt Valley anticline, which is located about 32 km northeast of Moab, Utah, is perhaps one of the most favorable waste emplacement sites in the Paradox basin. The site, which includes about 7.8 km 2, is highly accessible and is adjacent to a railroad. The anticline is one of a series of northwest-trending salt anticlines lying along the northeast edge of the Paradox basin. These anticlines are cored by evaporites of the Paradox Member of the Hermosa Formation of Middle Pennsylvanian age. The central core of the Salt Valley anticline forms a ridgelike mass of evaporites that has an estimated amplitude of 3,600 m. The evaporite core consists of about 87 percent halite rock, which includes some potash deposits; the remainder is black shale, silty dolomite, and anhydrite. The latter three lithologies are referred to as 'marker beds.' Using geophysical logs from drill holes on the anticline, it is possible to demonstrate that the marker beds are complexly folded and faulted. Available data concerning the geothermal gradient and heatflow at the site indicate that heat from emplaced wastes should be rapidly dissipated. Potentially exploitable resources of potash and petroleum are present at Salt Valley. Development of these resources may conflict with use of the site for waste emplacement.

  11. Double knockout of carbonic anhydrase II (CAII) and Na(+)-Cl(-) cotransporter (NCC) causes salt wasting and volume depletion.

    PubMed

    Xu, Jie; Barone, Sharon; Brooks, Mary-Beth; Soleimani, Manoocher

    2013-01-01

    The thiazide-sensitive Na(+)-Cl(-) cotransporter NCC and the Cl(-)/HCO3(-)exchanger pendrin are expressed on apical membranes of distal cortical nephron segments and mediate salt absorption, with pendrin working in tandem with the epithelial Na(+) channel (ENaC) and the Na(+)-dependent chloride/bicarbonate exchanger (NDCBE), whereas NCC is working by itself. A recent study showed that NCC and pendrin compensate for loss of each other under basal conditions, therefore masking the role that each plays in salt reabsorption. Carbonic anhydrase II (CAII, CA2 or CAR2) plays an important role in acid-base transport and salt reabsorption in the proximal convoluted tubule and acid-base transport in the collecting duct. Animals with CAII deletion show remodeling of intercalated cells along with the downregulation of pendrin. NCC KO mice on the other hand show significant upregulation of pendrin and ENaC. Neither model shows any significant salt wasting under baseline conditions. We hypothesized that the up-regulation of pendrin is essential for the prevention of salt wasting in NCC KO mice. To test this hypothesis, we generated NCC/CAII double KO (dKO) mice by crossing mice with single deletion of NCC and CAII. The NCC/CAII dKO mice displayed significant downregulation of pendrin, along with polyuria and salt wasting. As a result, the dKO mice developed volume depletion, which was associated with the inability to concentrate urine. We conclude that the upregulation of pendrin is essential for the prevention of salt and water wasting in NCC deficient animals and its downregulation or inactivation will result in salt wasting, impaired water conservation and volume depletion in the setting of NCC inactivation or inhibition. © 2014 S. Karger AG, Basel.

  12. 40 CFR 147.3005 - Radioactive waste injection wells.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Radioactive waste injection wells. 147... wells. Notwithstanding §§ 144.24 and 146.51(b) of this chapter, owners and operators of wells used to... permitting requirements pertaining to Class I wells in parts 124, 144 and 146 of this chapter, as modified...

  13. Waste Handling and Emplacement Options for Disposal of Radioactive Waste in Deep Boreholes.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cochran, John R.; Hardin, Ernest

    2015-11-01

    Traditional methods cannot be used to handle and emplace radioactive wastes in boreholes up to 16,400 feet (5 km) deep for disposal. This paper describes three systems that can be used for handling and emplacing waste packages in deep borehole: (1) a 2011 reference design that is based on a previous study by Woodward–Clyde in 1983 in which waste packages are assembled into “strings” and lowered using drill pipe; (2) an updated version of the 2011 reference design; and (3) a new concept in which individual waste packages would be lowered to depth using a wireline. Emplacement on coiled tubingmore » was also considered, but not developed in detail. The systems described here are currently designed for U.S. Department of Energy-owned high-level waste (HLW) including the Cesium- 137/Strontium-90 capsules from the Hanford Facility and bulk granular HLW from fuel processing in Idaho.« less

  14. Thirteenth annual U.S. DOE low-level radioactive waste management conference: Proceedings

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1991-12-31

    The 40 papers in this document comprise the proceedings of the Department of Energy`s Thirteenth Annual Low-Level Radioactive Waste Management Conference that was held in Atlanta, Georgia, on November 19--21, 1991. General subjects addressed during the conference included: disposal facility design; greater-than-class C low-level waste; public acceptance considerations; waste certification; site characterization; performance assessment; licensing and documentation; emerging low-level waste technologies; waste minimization; mixed waste; tracking and transportation; storage; and regulatory changes. Papers have been processed separately for inclusion on the data base.

  15. Characterizations of the radioactive waste by the remotely-controlled collimated spectrometric system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stepanov, Vyacheslav E.; Potapov, Victor N.; Smirnov, Sergey V.

    Decontamination and decommissioning of the research reactors MR (Testing Reactor) and RFT (Reactor of Physics and Technology) has recently been initiated in the National Research Center (NRC) 'Kurchatov institute', Moscow. In the building, neighboring to the reactor, the storage of HLRW is located. The storage is made of monolithic concrete in which steel cells depth 4 m are located. In cells of storage the HLRW packed into cases are placed. These the radioactive waste are also subject to export on long storage in the specialized organization. For characterization of the radioactive waste in cases the remote-controlled collimated spectrometer system wasmore » used. The system consists of a spectrometric collimated gamma-ray detector, a color video camera and a control unit, mounted on a rotator, which are mounted on a tripod with the host computer. For determination of specific activity of radionuclides in cases, it is developed programs of calculation of coefficients of proportionality of specific activity to the corresponding speeds of the account in peaks of full absorption at single specific activity of radionuclides in cases. For determination of these coefficients the mathematical model of spectrometer system based on the Monte-Carlo method was used. Dependences of calibration coefficients for various radionuclides from distance between the detector and a case at various values of the radioactive waste density in cases are given. Measurements of specific activity in cases are taken and are discussed. By results of measurements decisions on the appeal of the radioactive waste being in cases are made. (authors)« less

  16. AMS measurements of 14C and 129I in seawater around radioactive waste dump sites

    NASA Astrophysics Data System (ADS)

    Povinec, P. P.; Oregioni, B.; Jull, A. J. T.; Kieser, W. E.; Zhao, X.-L.

    2000-10-01

    According to a recent IAEA compilation of inventories of radioactive wastes dumped in the world ocean, a total of 85 PBq of radioactive wastes were dumped, in the Atlantic (45 PBq), the Pacific (1.4 PBq) and the Arctic (38 PBq) Oceans and their marginal seas between 1946 and 1993, mostly in the form of low-level wastes. 3H, and 14C formed an important part of the beta-activity of these dumped wastes. Because of its long half-life, 14C will be the main constituent in possible leakages from the wastes in the future. On the other hand, 14C and 129I are important radioactive tracers which have been artificially introduced into the oceans. Small amounts of 14C and 129I can be easily measured by accelerator mass spectrometry (AMS) on mg-size samples of carbon and iodine extracted from 500 ml seawater samples. The high analytical sensitivity enables one therefore to find even trace amounts of 14C and 129I which could be released from radioactive wastes, and to compare the measured levels with the global distribution of these radionuclides. The IAEAs Marine Environment Laboratory (IAEA-MEL) has been engaged in an assessment program related to radioactive waste dumping in the oceans since 1992 and has participated in several expeditions to the Atlantic, Arctic, Indian and Pacific Oceans to sample seawater, biota and sediment for radiological assessment studies. In the present paper, we report on methods of 14C and 129I measurements in seawater by AMS and present data on the NE Atlantic, the Arctic and the NW Pacific Ocean dumping sites. A small increase of 14C was observed at the NE Atlantic dumping site.

  17. International Surveillance Mechanism for Sea Dumping of Radioactive Waste

    ERIC Educational Resources Information Center

    OECD Observer, 1977

    1977-01-01

    The OECD consultation and surveillance mechanism is discussed in detail in this article. Four phases are identified and examined: (1) Notification, (2) Consultation, (3) Supervision, (4) Post-operation. This system is designed to provide the safest possible conditions for sea dumping of radioactive wastes. (MA)

  18. Incineration of European non-nuclear radioactive waste in the USA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moloney, B. P.; Ferguson, D.; Stephenson, B.

    2013-07-01

    Incineration of dry low level radioactive waste from nuclear stations is a well established process achieving high volume reduction factors to minimise disposal costs and to stabilise residues for disposal. Incineration has also been applied successfully in many European Union member countries to wastes arising from use of radionuclides in medicine, nonnuclear research and industry. However, some nations have preferred to accumulate wastes over many years in decay stores to reduce the radioactive burden at point of processing. After decay and sorting the waste, they then require a safe, industrial scale and affordable processing solution for the large volumes accumulated.more » This paper reports the regulatory, logistical and technical issues encountered in a programme delivered for Eckert and Ziegler Nuclitec to incinerate safely 100 te of waste collected originally from German research, hospital and industrial centres, applying for the first time a 'burn and return' process model for European waste in the US. The EnergySolutions incinerators at Bear Creek, Oak Ridge, Tennessee, USA routinely incinerate waste arising from the non-nuclear user community. To address the requirement from Germany, EnergySolutions had to run a dedicated campaign to reduce cross-contamination with non-German radionuclides to the practical minimum. The waste itself had to be sampled in a carefully controlled programme to ensure the exacting standards of Bear Creek's license and US emissions laws were maintained. Innovation was required in packaging of the waste to minimise transportation costs, including sea freight. The incineration was inspected on behalf of the German regulator (the BfS) to ensure suitability for return to Germany and disposal. This first 'burn and return' programme has safely completed the incineration phase in February and the arising ash will be returned to Germany presently. The paper reports the main findings and lessons learned on this first of its kind

  19. Method of storing radioactive wastes using modified tobermorite

    DOEpatents

    Komarneni, Sridhar; Roy, Della M.

    1985-01-01

    A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatable with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

  20. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM 2010

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B.; Waltz, R.

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2010 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report. The 2010 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. All inspections scheduled per SRR-LWE-2009-00138, HLW Tank Farm Inspection Plan for 2010, were completed. Ultrasonic measurements (UT) performed in 2010 met the requirements of C-ESG-00006, In-Service Inspection Program for Highmore » Level Waste Tanks, Rev. 3, and WSRC-TR-2002-00061, Rev.6. UT inspections were performed on Tanks 30, 31 and 32 and the findings are documented in SRNL-STI-2010-00533, Tank Inspection NDE Results for Fiscal Year 2010, Waste Tanks 30, 31 and 32. A total of 5824 photographs were made and 1087 visual and video inspections were performed during 2010. Ten new leaksites at Tank 5 were identified in 2010. The locations of these leaksites are documented in C-ESR-G-00003, SRS High Level Waste Tank Leaksite Information, Rev.5. Ten leaksites at Tank 5 were documented during tank wall/annulus cleaning activities. None of these new leaksites resulted in a release to the environment. The leaksites were documented during wall cleaning activities and the waste nodules associated with the leaksites were washed away. Previously documented leaksites were reactivated at Tank 12 during waste removal activities.« less

  1. Novel waste printed circuit board recycling process with molten salt.

    PubMed

    Riedewald, Frank; Sousa-Gallagher, Maria

    2015-01-01

    The objective of the method was to prove the concept of a novel waste PCBs recycling process which uses inert, stable molten salts as the direct heat transfer fluid and, simultaneously, uses this molten salt to separate the metal products in either liquid (solder, zinc, tin, lead, etc.) or solid (copper, gold, steel, palladium, etc.) form at the operating temperatures of 450-470 °C. The PCB recovery reactor is essentially a U-shaped reactor with the molten salt providing a continuous fluid, allowing molten salt access from different depths for metal recovery. A laboratory scale batch reactor was constructed using 316L as suitable construction material. For safety reasons, the inert, stable LiCl-KCl molten salts were used as direct heat transfer fluid. Recovered materials were washed with hot water to remove residual salt before metal recovery assessment. The impact of this work was to show metal separation using molten salts in one single unit, by using this novel reactor methodology. •The reactor is a U-shaped reactor filled with a continuous liquid with a sloped bottom representing a novel reactor concept.•This method uses large PCB pieces instead of shredded PCBs as the reactor volume is 2.2 L.•The treated PCBs can be removed via leg B while the process is on-going.

  2. Novel waste printed circuit board recycling process with molten salt

    PubMed Central

    Riedewald, Frank; Sousa-Gallagher, Maria

    2015-01-01

    The objective of the method was to prove the concept of a novel waste PCBs recycling process which uses inert, stable molten salts as the direct heat transfer fluid and, simultaneously, uses this molten salt to separate the metal products in either liquid (solder, zinc, tin, lead, etc.) or solid (copper, gold, steel, palladium, etc.) form at the operating temperatures of 450–470 °C. The PCB recovery reactor is essentially a U-shaped reactor with the molten salt providing a continuous fluid, allowing molten salt access from different depths for metal recovery. A laboratory scale batch reactor was constructed using 316L as suitable construction material. For safety reasons, the inert, stable LiCl–KCl molten salts were used as direct heat transfer fluid. Recovered materials were washed with hot water to remove residual salt before metal recovery assessment. The impact of this work was to show metal separation using molten salts in one single unit, by using this novel reactor methodology. • The reactor is a U-shaped reactor filled with a continuous liquid with a sloped bottom representing a novel reactor concept. • This method uses large PCB pieces instead of shredded PCBs as the reactor volume is 2.2 L. • The treated PCBs can be removed via leg B while the process is on-going. PMID:26150977

  3. US/German Collaboration in Salt Repository Research, Design and Operation - 13243

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Steininger, Walter; Hansen, Frank; Biurrun, Enrique

    2013-07-01

    Recent developments in the US and Germany [1-3] have precipitated renewed efforts in salt repository investigations and related studies. Both the German rock salt repository activities and the US waste management programs currently face challenges that may adversely affect their respective current and future state-of-the-art core capabilities in rock salt repository science and technology. The research agenda being pursued by our respective countries leverages collective efforts for the benefit of both programs. The topics addressed by the US/German salt repository collaborations align well with the findings and recommendations summarized in the January 2012 US Blue Ribbon Commission on America's Nuclearmore » Future (BRC) report [4] and are consistent with the aspirations of the key topics of the Strategic Research Agenda of the Implementing Geological Disposal of Radioactive Waste Technology Platform (IGD-TP) [5]. Against this background, a revival of joint efforts in salt repository investigations after some years of hibernation has been undertaken to leverage collective efforts in salt repository research, design, operations, and related issues for the benefit of respective programs and to form a basis for providing an attractive, cost-effective insurance against the premature loss of virtually irreplaceable scientific expertise and institutional memory. (authors)« less

  4. 76 FR 47613 - Board Meeting: September 13-14, 2011-Salt Lake City, UT; the U.S. Nuclear Waste Technical Review...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-05

    ... NUCLEAR WASTE TECHNICAL REVIEW BOARD Board Meeting: September 13-14, 2011--Salt Lake City, UT; the U.S. Nuclear Waste Technical Review Board Will Meet To Discuss DOE Plans for Used Fuel Disposition R... Amendments Act of 1987, the U.S. Nuclear Waste Technical Review Board will hold a public meeting in Salt Lake...

  5. Geohydrology of the Keechi, Mount Sylvan, Oakwood, and Palestine salt domes in the northeast Texas salt-dome basin

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Carr, J.E.; Halasz, S.J.; Peters, H.B.

    1980-01-01

    The salt within these domes has penetrated as much as 20,000 feet of Mesozoic and Cenozoic strata, and presently extends to within 120 to 800 feet of the land surface. The salt penetrates or closely underlies major freshwater and salinewater aquifers within the basin. To provide a safe repository for radioactive wastes within one or more of these domes, a thorough understanding of the geohydrology needs to be obtained, and the hydrologic stability of the domes needs to be established for the expected life of the storage facility. Dissolution may exist at all four candidate salt domes, possibly through contactmore » with Cretaceous or Tertiary aquifers, or through fault systems in the vicinity of the domes. Strata overlying and surrounding Palestine and Keechi Salt Domes have been arched into steeply-dipping folds that are complexly faulted. Similar conditions exist at Oakwood and Mount Sylvan Domes, except that the Tertiary strata have been only moderately disturbed. Additional problems concerning the hydrologic stability of Oakwood and Palestine Salt Domes have resulted from the disposal of oil-field salinewater in the cap rock at the Oakwood Dome and previous solution mining of salt at the Palestine Dome.« less

  6. Joint Assessment of Renewable Energy and Water Desalination Research Center (REWDC) Program Capabilities and Facilities In Radioactive Waste Management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bissani, M; Fischer, R; Kidd, S

    2006-04-03

    The primary goal of this visit was to perform a joint assessment of the Renewable Energy and Water Desalination Center's (REWDC) program in radioactive waste management. The visit represented the fourth technical and scientific interaction with Libya under the DOE/NNSA Sister Laboratory Arrangement. Specific topics addressed during the visit focused on Action Sheet P-05-5, ''Radioactive Waste Management''. The Team, comprised of Mo Bissani (Team Lead), Robert Fischer, Scott Kidd, and Jim Merrigan, consulted with REWDC management and staff. The team collected information, discussed particulars of the technical collaboration and toured the Tajura facility. The tour included the waste treatment facility,more » waste storage/disposal facility, research reactor facility, hot cells and analytical labs. The assessment team conducted the first phase of Task A for Action Sheet 5, which involved a joint assessment of the Radioactive Waste Management Program. The assessment included review of the facilities dedicated to the management of radioactive waste at the Tourja site, the waste management practices, proposed projects for the facility and potential impacts on waste generation and management.« less

  7. 1st Quarter Transportation Report FY 2015: Radioactive Waste Shipments to and from the Nevada National Security Site (NNSS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gregory, Louis

    2015-02-20

    This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of radioactive waste shipments to and from the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. There were no shipments sent for offsite treatment and returned to the NNSS this quarter. This report summarizes the 1st quarter of Fiscal Year (FY) 2015 low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW) shipments. Tabular summaries are provided which include the following: Sources of and carriers for LLW and MLLW shipments tomore » and from the NNSS; Number and external volume of LLW and MLLW shipments; Highway routes used by carriers; and Incident/accident data applicable to LLW and MLLW shipments. In this report shipments are accounted for upon arrival at the NNSS, while disposal volumes are accounted for upon waste burial. The disposal volumes presented in this report include minor volumes of non-radioactive classified waste/material that were approved for disposal (non-radioactive classified or nonradioactive classified hazardous). Volume reports showing cubic feet generated using the Low-Level Waste Information System may vary slightly due to rounding conventions for volumetric conversions from cubic meters to cubic feet.« less

  8. 4th Quarter Transportation Report FY 2014: Radioactive Waste Shipments to and from the Nevada National Security Site (NNSS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gregory, Louis

    2014-12-02

    This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of radioactive waste shipments to and from the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. There were no shipments sent for offsite treatment and returned to the NNSS this quarter. There was one shipment of two drums sent for offsite treatment and disposal. This report summarizes the 4th quarter of Fiscal Year (FY) 2014 low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW) shipments. This report also includes annualmore » summaries for FY 2014.« less

  9. Investigations of the unsaturated zone at two radioactive waste disposal sites in Lithuania.

    PubMed

    Skuratovič, Žana; Mažeika, Jonas; Petrošius, Rimantas; Martma, Tõnu

    2016-01-01

    The unsaturated zone is an important part of the water cycle, governed by many hydrological and hydrogeological factors and processes and provide water and nutrients to the terrestrial ecosystem. Besides, the soils of the unsaturated zone are regarded as the first natural barrier to a large extent and are able to limit the spread of contaminants depending on their properties. The unsaturated zone provides a linkage between atmospheric moisture, groundwater, and seepage of groundwater to streams, lakes, or other surface water bodies. The major difference between water flow in saturated and unsaturated soils is that the hydraulic conductivity, which is conventionally assumed to be a constant in saturated soils, is a function of the degree of saturation or matrix suction in the unsaturated soils. In Lithuania, low and intermediate level radioactive wastes generated from medicine, industry and research were accumulated at the Maisiagala radioactive waste repository. Short-lived low and intermediate levels radioactive waste, generated during the operation of the Ignalina Nuclear Power Plant (INPP) and arising after the INPP decommissioning will be disposed of in the near surface repository close to the INPP (Stabatiske site). Extensive data sets of the hydraulic properties and water content attributed to unsaturated zone soil profiles of the two radioactive waste disposal sites have been collected and summarized. Globally widespread radionuclide tritium ((3)H) and stable isotope ratio ((18)O/(16)O and (2)H/(1)H) distribution features were determined in precipitation, unsaturated zone soil moisture profiles and groundwater.

  10. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM - 2011

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B.; Waltz, R.

    2012-06-21

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2011 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report. The 2011 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. All inspections scheduled per SRR-LWE-2011-00026, HLW Tank Farm Inspection Plan for 2011, were completed. Ultrasonic measurements (UT) performed in 2011 met the requirements of C-ESR-G-00006, In-Service Inspection Program for Highmore » Level Waste Tanks, Rev. 3, and WSRC-TR-2002-00061, Rev.6. UT inspections were performed on Tanks 25, 26 and 34 and the findings are documented in SRNL-STI-2011-00495, Tank Inspection NDE Results for Fiscal Year 2011, Waste Tanks 25, 26, 34 and 41. A total of 5813 photographs were made and 835 visual and video inspections were performed during 2011. A potential leaksite was discovered at Tank 4 during routine annual inspections performed in 2011. The new crack, which is above the allowable fill level, resulted in no release to the environment or tank annulus. The location of the crack is documented in C-ESR-G-00003, SRS High Level Waste Tank Leaksite Information, Rev.6.« less

  11. Radioactive waste disposal via electric propulsion

    NASA Technical Reports Server (NTRS)

    Burns, R. E.

    1975-01-01

    It is shown that space transportation is a feasible method of removal of radioactive wastes from the biosphere. The high decay heat of the isotopes powers a thermionic generator which provides electrical power for ion thrust engines. The massive shields (used to protect ground and flight personnel) are removed in orbit for subsequent reuse; the metallic fuel provides a shield for the avionics that guides the orbital stage to solar system escape. Performance calculations indicate that 4000 kg. of actinides may be removed per Shuttle flight. Subsidiary problems - such as cooling during ascent - are discussed.

  12. Ferrate treatment for removing chromium from high-level radioactive tank waste.

    PubMed

    Sylvester, P; Rutherford, L A; Gonzalez-Martin, A; Kim, J; Rapko, B M; Lumetta, G J

    2001-01-01

    A method has been developed for removing chromium from alkaline high-level radioactive tank waste. Removing chromium from these wastes is critical in reducing the volume of waste requiring expensive immobilization and deep geologic disposition. The method developed is based on the oxidation of insoluble chromium(III) compounds to soluble chromate using ferrate. This method could be generally applicable to removing chromium from chromium-contaminated solids, when coupled with a subsequent reduction of the separated chromate back to chromium(III). The tests conducted with a simulated Hanford tank sludge indicate that the chromium removal with ferrate is more efficient at 5 M NaOH than at 3 M NaOH. Chromium removal increases with increasing Fe(VI)/Cr(II) molar ratio, but the chromium removal tends to level out for Fe(VI)/ Cr(III) greaterthan 10. Increasingtemperature leadsto better chromium removal, but higher temperatures also led to more rapid ferrate decomposition. Tests with radioactive Hanford tank waste generally confirmed the simulant results. In all cases examined, ferrate enhanced the chromium removal, with a typical removal of around 60-70% of the total chromium present in the washed sludge solids. The ferrate leachate solutions did not contain significant concentrations of transuranic elements, so these solutions could be disposed as low-activity waste.

  13. Prompt gamma neutron activation analysis of toxic elements in radioactive waste packages.

    PubMed

    Ma, J-L; Carasco, C; Perot, B; Mauerhofer, E; Kettler, J; Havenith, A

    2012-07-01

    The French Alternative Energies and Atomic Energy Commission (CEA) and National Radioactive Waste Management Agency (ANDRA) are conducting an R&D program to improve the characterization of long-lived and medium activity (LL-MA) radioactive waste packages. In particular, the amount of toxic elements present in radioactive waste packages must be assessed before they can be accepted in repository facilities in order to avoid pollution of underground water reserves. To this aim, the Nuclear Measurement Laboratory of CEA-Cadarache has started to study the performances of Prompt Gamma Neutron Activation Analysis (PGNAA) for elements showing large capture cross sections such as mercury, cadmium, boron, and chromium. This paper reports a comparison between Monte Carlo calculations performed with the MCNPX computer code using the ENDF/B-VII.0 library and experimental gamma rays measured in the REGAIN PGNAA cell with small samples of nickel, lead, cadmium, arsenic, antimony, chromium, magnesium, zinc, boron, and lithium to verify the validity of a numerical model and gamma-ray production data. The measurement of a ∼20kg test sample of concrete containing toxic elements has also been performed, in collaboration with Forschungszentrum Jülich, to validate the model in view of future performance studies for dense and large LL-MA waste packages. Copyright © 2012 Elsevier Ltd. All rights reserved.

  14. Final Report - "Foaming and Antifoaming and Gas Entrainment in Radioactive Waste Pretreatment and Immobilization Processes"

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wasan, Darsh T.

    2007-10-09

    The Savannah River Site (SRS) and Hanford site are in the process of stabilizing millions of gallons of radioactive waste slurries remaining from production of nuclear materials for the Department of Energy (DOE). The Defense Waste Processing Facility (DWPF) at SRS is currently vitrifying the waste in borosilicate glass, while the facilities at the Hanford site are in the construction phase. Both processes utilize slurry-fed joule-heated melters to vitrify the waste slurries. The DWPF has experienced difficulty during operations. The cause of the operational problems has been attributed to foaming, gas entrainment and the rheological properties of the process slurries.more » The rheological properties of the waste slurries limit the total solids content that can be processed by the remote equipment during the pretreatment and meter feed processes. Highly viscous material can lead to air entrainment during agitation and difficulties with pump operations. Excessive foaming in waste evaporators can cause carryover of radionuclides and non-radioactive waste to the condensate system. Experimental and theoretical investigations of the surface phenomena, suspension rheology and bubble generation of interactions that lead to foaming and air entrainment problems in the DOE High Level and Low Activity Radioactive Waste separation and immobilization processes were pursued under this project. The first major task accomplished in the grant proposal involved development of a theoretical model of the phenomenon of foaming in a three-phase gas-liquid-solid slurry system. This work was presented in a recently completed Ph.D. thesis (9). The second major task involved the investigation of the inter-particle interaction and microstructure formation in a model slurry by the batch sedimentation method. Both experiments and modeling studies were carried out. The results were presented in a recently completed Ph.D. thesis. The third task involved the use of laser confocal microscopy to

  15. Monte Carlo simulations of radioactive waste encapsulated by bisphenol-A polycarbonate and effect of bismuth-III oxide filler material

    NASA Astrophysics Data System (ADS)

    Özdemir, Tonguç

    2017-06-01

    Radioactive waste generated from the nuclear industry and non-power applications should carefully be treated, conditioned and disposed according to the regulations set by the competent authority(ies). Bisphenol-a polycarbonate (BPA-PC), a very widely used polymer, might be considered as a potential candidate material for low level radioactive waste encapsulation. In this work, the dose rate distribution in the radioactive waste drum (containing radioactive waste and the BPA-PC polymer matrix) was determined using Monte Carlo simulations. Moreover, the change of mechanical properties of BPA-PC was estimated and their variation within the waste drum was determined for the periods of 15, 30 and 300 years after disposal to the final disposal site. The change of the dose rate within the waste drum with different contents of bismuth-III oxide were also simulated. It was concluded that addition of bismuth-III oxide filler decreases the dose delivered to the polymeric matrix due to photoelectric effect.

  16. Equipment evaluation for low density polyethylene encapsulated nitrate salt waste at the Rocky Flats Plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yamada, W.I.; Faucette, A.M.; Jantzen, R.C.

    1993-08-30

    Mixed wastes at the Rocky Flats Plant (RFP) are subject to regulation by the Resource Conservation and Recovery Act (RCRA). Polymer solidification is being developed as a final treatment technology for several of these mixed wastes, including nitrate salts. Encapsulation nitrate salts with low density polyethylene (LDPE) has been the preliminary focus of the RFP polymer solidification effort. Literature reviews, industry surveys, and lab-scale and pilot-scale tests have been conducted to evaluate several options for encapsulating nitrate salts with LDPE. Most of the effort has focused on identifying compatible drying and extrusion technologies. Other processing options, specifically meltration and non-heatedmore » compounding machines, were also investigated. The best approach appears to be pretreatment of the nitrate salt waste brine in either a vertical or horizontal thin film evaporator followed by compounding of the dried waste with LDPE in an intermeshing, co-rotating, twin-screw extruder. Additional pilot-scale tests planned for the fall of 1993 should further support this recommendation. Preliminary evaluation work indicates that meltration is not possible at atmospheric pressure with the LDPE (Chevron PE-1409) provided by RFP. However, meltration should be possible at atmospheric pressure using another LDPE formulation with altered physical and rheological properties: Lower molecular weight and lower viscosity (Epoline C-15). Contract modifications are now in process to allow a follow-on pilot scale demonstration. Questions regarding changed safety and physical properties of the resultant LDPE waste form due to use of the Epoline C-15 will be addressed. No additional work with non-heated mixer compounder machines is planned at this time.« less

  17. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jantzen, Carol; Herman, Connie; Crawford, Charles

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable tomore » glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.« less

  18. Considerations Related To Human Intrusion In The Context Of Disposal Of Radioactive Waste-The IAEA HIDRA Project

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Seitz, Roger; Kumano, Yumiko; Bailey, Lucy

    2014-01-09

    The principal approaches for management of radioactive waste are commonly termed ‘delay and decay’, ‘concentrate and contain’ and ‘dilute and disperse’. Containing the waste and isolating it from the human environment, by burying it, is considered to increase safety and is generally accepted as the preferred approach for managing radioactive waste. However, this approach results in concentrated sources of radioactive waste contained in one location, which can pose hazards should the facility be disrupted by human action in the future. The International Commission on Radiological Protection (ICRP), International Atomic Energy Agency (IAEA), and Organization for Economic Cooperation and Development/Nuclear Energymore » Agency (OECD/NEA) agree that some form of inadvertent human intrusion (HI) needs to be considered to address the potential consequences in the case of loss of institutional control and loss of memory of the disposal facility. Requirements are reflected in national regulations governing radioactive waste disposal. However, in practice, these requirements are often different from country to country, which is then reflected in the actual implementation of HI as part of a safety case. The IAEA project on HI in the context of Disposal of RadioActive waste (HIDRA) has been started to identify potential areas for improved consistency in consideration of HI. The expected outcome is to provide recommendations on how to address human actions in the safety case in the future, and how the safety case may be used to demonstrate robustness and optimize siting, design and waste acceptance criteria within the context of a safety case.« less

  19. 77 FR 40817 - Low-Level Radioactive Waste Regulatory Management Issues

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-11

    ...-2011-0012] RIN-3150-AI92 Low-Level Radioactive Waste Regulatory Management Issues AGENCY: Nuclear... Materials and Environmental Management Programs, U.S. Nuclear Regulatory Commission, Washington, DC 20555... State Materials and Environmental Management Programs, U.S. Nuclear Regulatory Commission, Washington...

  20. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM 2009

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, B.; Waltz, R.

    2010-06-21

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2009 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report. The 2009 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. All inspections scheduled per LWO-LWE-2008-00423, HLW Tank Farm Inspection Plan for 2009, were completed. All Ultrasonic measurements (UT) performed in 2009 met the requirements of C-ESG-00006, In-Service Inspection Program formore » High Level Waste Tanks, Rev. 1, and WSRC-TR-2002-00061, Rev.4. UT inspections were performed on Tank 29 and the findings are documented in SRNL-STI-2009-00559, Tank Inspection NDE Results for Fiscal Year 2009, Waste Tank 29. Post chemical cleaning UT measurements were made in Tank 6 and the results are documented in SRNL-STI-2009-00560, Tank Inspection NDE Results Tank 6, Including Summary of Waste Removal Support Activities in Tanks 5 and 6. A total of 6669 photographs were made and 1276 visual and video inspections were performed during 2009. Twenty-Two new leaksites were identified in 2009. The locations of these leaksites are documented in C-ESR-G-00003, SRS High Level Waste Tank Leaksite Information, Rev.4. Fifteen leaksites at Tank 5 were documented during tank wall/annulus cleaning activities. Five leaksites at Tank 6 were documented during tank wall/annulus cleaning activities. Two new leaksites were identified at Tank 19 during waste removal activities. Previously documented leaksites were reactivated at Tanks 5 and 12 during waste removal activities. Also, a very small amount of additional leakage from a previously identified leaksite at Tank 14 was observed.« less

  1. Electrochemical probing of high-level radioactive waste tanks containing washed sludge and precipitates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bickford, D.F.; Congdon, J.W.; Oblath, S.B.

    1987-01-01

    At the U.S. Department of Energy's Savannah River Plant, corrosion of carbon steel storage tanks containing alkaline, high-level radioactive waste is controlled by specification of limits on waste composition and temperature. Processes for the preparation of waste for final disposal will result in waste with low corrosion inhibitor concentrations and, in some cases, high aromatic organic concentrations, neither of which are characteristic of previous operations. Laboratory tests, conducted to determine minimum corrosion inhibitor levels indicated pitting of carbon steel near the waterline for proposed storage conditions. In situ electrochemical measurements of full-scale radioactive process demonstrations have been conducted to assessmore » the validity of laboratory tests. Probes included pH, Eh (potential relative to a standard hydrogen electrode), tank potential, and alloy coupons. In situ results are compared to those of the laboratory tests, with particular regard given to simulated solution composition.« less

  2. Radiation protection challenges in the management of radioactive waste from high-energy accelerators.

    PubMed

    Ulrici, Luisa; Algoet, Yvon; Bruno, Luca; Magistris, Matteo

    2015-04-01

    The European Laboratory for Particle Physics (CERN) has operated high-energy accelerators for fundamental physics research for nearly 60 y. The side-product of this activity is the radioactive waste, which is mainly generated as a result of preventive and corrective maintenance, upgrading activities and the dismantling of experiments or accelerator facilities. Prior to treatment and disposal, it is common practice to temporarily store radioactive waste on CERN's premises and it is a legal requirement that these storage facilities are safe and secure. Waste treatment typically includes sorting, segregation, volume and size reduction and packaging, which will depend on the type of component, its chemical composition, residual activity and possible surface contamination. At CERN, these activities are performed in a dedicated waste treatment centre under the supervision of the Radiation Protection Group. This paper gives an overview of the radiation protection challenges in the conception of a temporary storage and treatment centre for radioactive waste in an accelerator facility, based on the experience gained at CERN. The CERN approach consists of the classification of waste items into 'families' with similar radiological and physical-chemical properties. This classification allows the use of specific, family-dependent techniques for radiological characterisation and treatment, which are simultaneously efficient and compliant with best practices in radiation protection. The storage was planned on the basis of radiological and other possible hazards such as toxicity, pollution and fire load. Examples are given of technical choices for the treatment and radiological characterisation of selected waste families, which could be of interest to other accelerator facilities. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  3. Development of integrated radioactive waste packaging and conditioning solutions in the UK

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sibley, Peter; Butter, Kevin; Zimmerman, Ian

    2013-07-01

    In order to offer a more cost effective, safer and efficient Intermediate Level Waste (ILW) management service, EnergySolutions EU Ltd. and Gesellschaft fur Nuklear-Service mbH (GNS) have been engaged in the development of integrated radioactive waste retrieval, packaging and conditioning solutions in the UK. Recognising the challenges surrounding regulatory endorsement and on-site implementation in particular, this has resulted in an alternative approach to meeting customer, safety regulator and disposability requirements. By working closely with waste producers and the organisation(s) responsible for endorsing radioactive waste management operations in the UK, our proposed solutions are now being implemented. By combining GNS' off-the-shelf,more » proven Ductile Cast Iron Containers (DCICs) and water removal technologies, with EnergySolutions EU Ltd.'s experience and expertise in waste retrieval, safety case development and disposability submissions, a fully integrated service offering has been developed. This has involved significant effort to overcome technical challenges such as onsite equipment deployment, active commissioning, conditioning success criteria and disposability acceptance. Our experience in developing such integrated solutions has highlighted the importance of working in collaboration with all parties to achieve a successful and viable outcome. Ultimately, the goal is to ensure reliable, safe and effective delivery of waste management solutions. (authors)« less

  4. Bacterial Diversity in Bentonites, Engineered Barrier for Deep Geological Disposal of Radioactive Wastes.

    PubMed

    Lopez-Fernandez, Margarita; Cherkouk, Andrea; Vilchez-Vargas, Ramiro; Jauregui, Ruy; Pieper, Dietmar; Boon, Nico; Sanchez-Castro, Ivan; Merroun, Mohamed L

    2015-11-01

    The long-term disposal of radioactive wastes in a deep geological repository is the accepted international solution for the treatment and management of these special residues. The microbial community of the selected host rocks and engineered barriers for the deep geological repository may affect the performance and the safety of the radioactive waste disposal. In this work, the bacterial population of bentonite formations of Almeria (Spain), selected as a reference material for bentonite-engineered barriers in the disposal of radioactive wastes, was studied. 16S ribosomal RNA (rRNA) gene-based approaches were used to study the bacterial community of the bentonite samples by traditional clone libraries and Illumina sequencing. Using both techniques, the bacterial diversity analysis revealed similar results, with phylotypes belonging to 14 different bacterial phyla: Acidobacteria, Actinobacteria, Armatimonadetes, Bacteroidetes, Chloroflexi, Cyanobacteria, Deinococcus-Thermus, Firmicutes, Gemmatimonadetes, Planctomycetes, Proteobacteria, Nitrospirae, Verrucomicrobia and an unknown phylum. The dominant groups of the community were represented by Proteobacteria and Bacteroidetes. A high diversity was found in three of the studied samples. However, two samples were less diverse and dominated by Betaproteobacteria.

  5. Development of an air flow calorimeter prototype for the measurement of thermal power released by large radioactive waste packages.

    PubMed

    Razouk, R; Beaumont, O; Failleau, G; Hay, B; Plumeri, S

    2018-03-01

    The estimation and control of the thermal power released by the radioactive waste packages are a key parameter in the management of radioactive waste geological repository sites. In the framework of the European project "Metrology for decommissioning nuclear facilities," the French National Agency of Radioactive Waste Management (ANDRA) collaborates with Laboratoire National de Métrologie et D'essais in order to measure the thermal power up to 500 W of typical real size radioactive waste packages (of at least 0.175 m 3 ) with an uncertainty better than 5% by using a measurement method traceable to the international system of units. One of the selected metrological approaches is based on the principles of air flow calorimetry. This paper describes in detail the development of the air flow calorimeter prototype as well as the design of a radioactive waste package simulator used for its calibration. Results obtained from the calibration of the calorimeter and from the determination of thermal powers are presented here with an investigation of the measurement uncertainties.

  6. Development of an air flow calorimeter prototype for the measurement of thermal power released by large radioactive waste packages

    NASA Astrophysics Data System (ADS)

    Razouk, R.; Beaumont, O.; Failleau, G.; Hay, B.; Plumeri, S.

    2018-03-01

    The estimation and control of the thermal power released by the radioactive waste packages are a key parameter in the management of radioactive waste geological repository sites. In the framework of the European project "Metrology for decommissioning nuclear facilities," the French National Agency of Radioactive Waste Management (ANDRA) collaborates with Laboratoire National de Métrologie et D'essais in order to measure the thermal power up to 500 W of typical real size radioactive waste packages (of at least 0.175 m3) with an uncertainty better than 5% by using a measurement method traceable to the international system of units. One of the selected metrological approaches is based on the principles of air flow calorimetry. This paper describes in detail the development of the air flow calorimeter prototype as well as the design of a radioactive waste package simulator used for its calibration. Results obtained from the calibration of the calorimeter and from the determination of thermal powers are presented here with an investigation of the measurement uncertainties.

  7. Successes and Techniques Associated with Teaching the Chemistry of Radioactive Wastes.

    ERIC Educational Resources Information Center

    Williams, Donald H.

    1995-01-01

    Describes a chemistry course that is built around the topic of radioactive waste and encompasses a large number of chemistry concepts including redox, equilibrium, kinetics, nuclear energy, and the periodic chart. (JRH)

  8. Handling Radioactive Waste from the Proton Accelerator Facility at the Paul Scherrer Institut (PSI) - Always Surprising? - 13320

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mueth, Joachim

    The Paul Scherrer Institut (PSI) is the largest national research centre in Switzerland. Its multidisciplinary research is dedicated to a wide field in natural science and technology as well as particle physics. In this context, PSI is operating, amongst others, a large proton accelerator facility since more than 30 years. In two cyclotrons, protons are accelerated to high speeds and then guided along roughly 100 m of beam line to three different target stations to produce secondary particles like mesons and neutrons for experiments and a separately beam line for UCN. The protons induce spallation processes in the target materials,more » and also at other beam loss points along the way, with emission of protons, neutrons, hydrogen, tritium, helium, heavier fragments and fission processes. In particular the produced neutrons, due to their large penetration depth, will then interact also with the surrounding materials. These interactions of radiation with matter lead to activation and partly to contamination of machine components and the surrounding infrastructures. Maintenance, operation and decommissioning of installations generate inevitably substantial amounts of radioactive operational and dismantling waste like targets, magnets, collimators, shielding (concrete, steel) and of course secondary waste. To achieve an optimal waste management strategy for interim storage or final disposal, radioactive waste has to be characterized, sorted and treated. This strategy is based on radiation protection demands, raw waste properties (size, material, etc.), and requirements to reduce the volume of waste, mainly for legal and economical reasons. In addition, the radiological limitations for transportation of the waste packages to a future disposal site have to be taken into account, as well as special regulatory demands. The characterization is a task of the waste producer. The conditioning processes and quality checks for radioactive waste packages are part of an

  9. PROCESSING OF RADIOACTIVE WASTE

    DOEpatents

    Allemann, R.T.; Johnson, B.M. Jr.

    1961-10-31

    A process for concentrating fission-product-containing waste solutions from fuel element processing is described. The process comprises the addition of sugar to the solution, preferably after it is made alkaline; spraying the solution into a heated space whereby a dry powder is formed; heating the powder to at least 220 deg C in the presence of oxygen whereby the powder ignites, the sugar is converted to carbon, and the salts are decomposed by the carbon; melting the powder at between 800 and 900 deg C; and cooling the melt. (AEC) antidiuretic hormone from the blood by the liver. Data are summarized from the following: tracer studies on cardiovascular functions; the determination of serum protein-bound iodine; urinary estrogen excretion in patients with arvanced metastatic mammary carcinoma; the relationship between alheroclerosis aad lipoproteins; the physical chemistry of lipoproteins; and factors that modify the effects of densely ionizing radia

  10. 77 FR 10401 - Low-Level Radioactive Waste Management Issues

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-22

    ... rather than active systems to limit and retard releases to the environment. Development of the 10 CFR... have been a number of developments that have called into question some of the key assumptions made in... radioactive wastes that did not exist at the time 10 CFR Part 61 was promulgated. The developments previously...

  11. Complex electronic waste treatment - An effective process to selectively recover copper with solutions containing different ammonium salts.

    PubMed

    Sun, Z H I; Xiao, Y; Sietsma, J; Agterhuis, H; Yang, Y

    2016-11-01

    Recovery of valuable metals from electronic waste has been highlighted by the EU directives. The difficulties for recycling are induced by the high complexity of such waste. In this research, copper could be selectively recovered using an ammonia-based process, from industrially processed information and communication technology (ICT) waste with high complexity. A detailed understanding on the role of ammonium salt was focused during both stages of leaching copper into a solution and the subsequent step for copper recovery from the solution. By comparing the reactivity of the leaching solution with different ammonium salts, their physiochemical behaviour as well as the leaching efficiency could be identified. The copper recovery rate could reach 95% with ammonium carbonate as the leaching salt. In the stage of copper recovery from the solution, electrodeposition was introduced without an additional solvent extraction step and the electrochemical behaviour of the solution was figured out. With a careful control of the electrodeposition conditions, the current efficiency could be improved to be 80-90% depending on the ammonia salts and high purity copper (99.9wt.%). This research provides basis for improving the recyclability and efficiency of copper recovery from such electronic waste and the whole process design for copper recycling. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. The political science of radioactive waste disposal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jacobi, L.R. Jr.

    1996-06-01

    This paper was first presented at the annual meeting of the HPS in New Orleans in 1984. Twelve years later, the basic lessons learned are still found to be valid. In 1984, the following things were found to be true: A government agency is preferred by the public over a private company to manage radioactive waste. Semantics are important--How you say it is important, but how it is heard is more important. Public information and public relations are very important, but they are the last thing of concern to a scientist. Political constituency is important. Don`t overlook the need formore » someone to be on your side. Don`t forget that the media is part of the political process-they can make you or break you. Peer technical review is important, but so is citizen review. Sociology is an important issue that scientists and technical people often overlook. In summary, despite the political nature of radioactive waste disposal, it is as true today as it was in 1984 that technical facts must be used to reach sound technical conclusions. Only then, separately and openly, should political factors be considered. So, what can be said today that wasn`t said in 1984? Nothing. {open_quotes}It`s deja vu all over again.{close_quotes}« less

  13. Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.

    1999-03-16

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination oaf plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  14. Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials

    DOEpatents

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1999-03-16

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  15. Decommissioning the Romanian Water-Cooled Water-Moderated Research Reactor: New Environmental Perspective on the Management of Radioactive Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barariu, G.; Giumanca, R.

    2006-07-01

    Pre-feasibility and feasibility studies were performed for decommissioning of the water-cooled water-moderated research reactor (WWER) located in Bucharest - Magurele, Romania. Using these studies as a starting point, the preferred safe management strategy for radioactive wastes produced by reactor decommissioning is outlined. The strategy must account for reactor decommissioning, as well as for the rehabilitation of the existing Radioactive Waste Treatment Plant and for the upgrade of the Radioactive Waste Disposal Facility at Baita-Bihor. Furthermore, the final rehabilitation of the laboratories and ecological reconstruction of the grounds need to be provided for, in accordance with national and international regulations. Inmore » accordance with IAEA recommendations at the time, the pre-feasibility study proposed three stages of decommissioning. However, since then new ideas have surfaced with regard to decommissioning. Thus, taking into account the current IAEA ideology, the feasibility study proposes that decommissioning of the WWER be done in one stage to an unrestricted clearance level of the reactor building in an Immediate Dismantling option. Different options and the corresponding derived preferred option for waste management are discussed taking into account safety measures, but also considering technical, logistical and economic factors. For this purpose, possible types of waste created during each decommissioning stage are reviewed. An approximate inventory of each type of radioactive waste is presented. The proposed waste management strategy is selected in accordance with the recommended international basic safety standards identified in the previous phase of the project. The existing Radioactive Waste Treatment Plant (RWTP) from the Horia Hulubei Institute for Nuclear Physics and Engineering (IFIN-HH), which has been in service with no significant upgrade since 1974, will need refurbishing due to deterioration, as well as upgrading in order to

  16. Toxic Substances Control Act (TSCA) Polychlorinated Biphenyl (PCB)/Radioactive Waste Annual Inventory for Calendar Year 2013

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    no author on report

    2014-06-01

    The Toxic Substances Control Act, 40 CFR 761.65(a)(1) provides an exemption from the one year storage time limit for PCB/radioactive waste. PCB/radioactive waste may exceed the one year time limit provided that the provisions at 40 CFR 761.65(a)(2)(ii) and 40 CFR 761.65(a)(2)(iii) are followed. These two subsections require, (ii) "A written record documenting all continuing attempts to secure disposal is maintained until the waste is disposed of" and (iii) "The written record required by subsection (ii) of this section is available for inspection or submission if requested by EPA." EPA Region 10 has requested the Department of Energy (DOE) tomore » submit an inventory of radioactive-contaminated PCB waste in storage at the Idaho National Laboratory (INL) for the previous calendar year. The annual inventory is separated into two parts, INL without Advanced Mixed Waste Treatment Project (AMWTP) (this includes Battelle Energy Alliance, LLC, CH2M-WG Idaho, LLC, and the Naval Reactors Facility), and AMWTP.« less

  17. 3rd Quarter Transportation Report FY 2014: Radioactive Waste Shipments to and from the Nevada National Security Site (NNSS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gregory, Louis

    2014-09-20

    This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of radioactive waste shipments to the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. There were no shipments sent for offsite treatment and returned to the NNSS this quarter. This report summarizes the 3rd quarter of Fiscal Year (FY) 2014 low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW) shipments. This report also includes annual summaries for FY 2014 in Tables 4 and 5. Tabular summaries are provided which includemore » the following: Sources of and carriers for LLW and MLLW shipments to and from the NNSS; Number and external volume of LLW and MLLW shipments; Highway routes used by carriers; and Incident/accident data applicable to LLW and MLLW shipments. In this report shipments are accounted for upon arrival at the NNSS, while disposal volumes are accounted for upon waste burial. The disposal volumes presented in this report do not include minor volumes of non-radioactive materials that were approved for disposal. Volume reports showing cubic feet generated using the Low-Level Waste Information System may vary slightly due to differing rounding conventions.« less

  18. Cesium Sorption/Desorption Experiments with IONSIV(R) IE-911 in Radioactive Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Walker, D.D.

    2001-02-13

    This report describes cesium desorption from IONSIV IE-911 during ambient temperature storage and following temperature increases to 35 and 55 degrees C. This report also describes cesium sorption following return to ambient temperature. The IONSIV IE-911 used in these tests was loaded with cesium from Tank 44F radioactive waste in an ion exchange column test in 1999. Cesium desorbed and resorbed in the presence of Tank 44F waste and simulated waste solutions.

  19. Voluntarism, public engagement and the role of geoscience in radioactive waste management policy-making

    NASA Astrophysics Data System (ADS)

    Bilham, Nic

    2014-05-01

    In the UK, as elsewhere in Europe, there has been a move away from previous 'technocratic' approaches to radioactive waste management (RWM). Policy-makers have recognised that for any RWM programme to succeed, sustained engagement with stakeholders and the public is necessary, and any geological repository must be constructed and operated with the willing support of the community which hosts it. This has opened up RWM policy-making and implementation to a wider range of (often contested) expert inputs, ranging across natural and social sciences, engineering and even ethics. Geoscientists and other technical specialists have found themselves drawn into debates about how various types of expertise should be prioritised, and how they should be integrated with diverse public and stakeholder perspectives. They also have a vital role to play in communicating to the public the need for geological disposal of radioactive waste, and the various aspects of geoscience which will inform the process of implementing this, from identifying potential volunteer host communities, to finding a suitable site, developing the safety case, construction of a repository, emplacement of waste, closure and subsequent monitoring. High-quality geoscience, effectively communicated, will be essential to building and maintaining public confidence throughout the many decades such projects will take. Failure to communicate effectively the relevant geoscience and its central role in the UK's radioactive waste management programme arguably contributed to West Cumbria's January 2013 decision to withdraw from the site selection process, and may discourage other communities from coming forward in future. Across countries needing to deal with their radioactive waste, this unique challenge gives an unprecedented urgency to finding ways to engage and communicate effectively with the public about geoscience.

  20. Guidance for Low-Level Radioactive Waste (LLRW) and Mixed Waste (MW) Treatment and Handling

    DTIC Science & Technology

    1997-06-30

    7-2 7-1 Excavation of Contaminated Soils . . . . . . . . 7-3 7-1 Excavation of Contaminated Sediments...becomes only as radioactive as natural soil . By comparison, many other potential y hazardous, but nonradioactive, chemical wastes like lead, silver...solutions and cleanup materials, engine oils and grease, epoxies and resins, laser dyes, paint residues, photo- graphic materials, soils , asphalts

  1. Numerical analysis of impurity separation from waste salt by investigating the change of concentration at the interface during zone refining process

    NASA Astrophysics Data System (ADS)

    Choi, Ho-Gil; Shim, Moonsoo; Lee, Jong-Hyeon; Yi, Kyung-Woo

    2017-09-01

    The waste salt treatment process is required for the reuse of purified salts, and for the disposal of the fission products contained in waste salt during pyroprocessing. As an alternative to existing fission product separation methods, the horizontal zone refining process is used in this study for the purification of waste salt. In order to evaluate the purification ability of the process, three-dimensional simulation is conducted, considering heat transfer, melt flow, and mass transfer. Impurity distributions and decontamination factors are calculated as a function of the heater traverse rate, by applying a subroutine and the equilibrium segregation coefficient derived from the effective segregation coefficients. For multipass cases, 1d solutions and the effective segregation coefficient obtained from three-dimensional simulation are used. In the present study, the topic is not dealing with crystal growth, but the numerical technique used is nearly the same since the zone refining technique was just introduced in the treatment of waste salt from nuclear power industry because of its merit of simplicity and refining ability. So this study can show a new application of single crystal growth techniques to other fields, by taking advantage of the zone refining multipass possibility. The final goal is to achieve the same high degree of decontamination in the waste salt as in zone freezing (or reverse Bridgman) method.

  2. Ion-exchange material and method of storing radioactive wastes

    DOEpatents

    Komarneni, S.; Roy, D.M.

    1983-10-31

    A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt, and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatible with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

  3. Treatment of low level radioactive liquid waste containing appreciable concentration of TBP degraded products.

    PubMed

    Valsala, T P; Sonavane, M S; Kore, S G; Sonar, N L; De, Vaishali; Raghavendra, Y; Chattopadyaya, S; Dani, U; Kulkarni, Y; Changrani, R D

    2011-11-30

    The acidic and alkaline low level radioactive liquid waste (LLW) generated during the concentration of high level radioactive liquid waste (HLW) prior to vitrification and ion exchange treatment of intermediate level radioactive liquid waste (ILW), respectively are decontaminated by chemical co-precipitation before discharge to the environment. LLW stream generated from the ion exchange treatment of ILW contained high concentrations of carbonates, tributyl phosphate (TBP) degraded products and problematic radio nuclides like (106)Ru and (99)Tc. Presence of TBP degraded products was interfering with the co-precipitation process. In view of this a modified chemical treatment scheme was formulated for the treatment of this waste stream. By mixing the acidic LLW and alkaline LLW, the carbonates in the alkaline LLW were destroyed and the TBP degraded products got separated as a layer at the top of the vessel. By making use of the modified co-precipitation process the effluent stream (1-2 μCi/L) became dischargeable to the environment after appropriate dilution. Based on the lab scale studies about 250 m(3) of LLW was treated in the plant. The higher activity of the TBP degraded products separated was due to short lived (90)Y isotope. The cement waste product prepared using the TBP degraded product was having good chemical durability and compressive strength. Copyright © 2011 Elsevier B.V. All rights reserved.

  4. Internal structure of mushroom-shaped salt diapirs

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1989-01-01

    This book focuses on the dynamics and kinematics of salt diapirs with crestal bulbs shaped like a mushroom, one of the most complex types of diapirs, as interpreted by experimental modeling and from naturally occurring examples. Direct, practical applications of this research include use in the evaluation of salt domes as repositories for radioactive waste, in the exploration and production of salt, potash, and sulfur, and in the search for subtle hydrocarbon traps. The authors conducted 8 centrifuge experiments, which produced more than 100 model diapirs. These experiments were dynamically scaled to U.S. Gulf Coast salt domes, but the qualitativemore » results are also relevant to salt diapirs in other provinces and to granitoid diapirs penetrating metamorphic crust. The centrifuged domes grew under overburdens of constant thickness or under aggrading and prograding overburdens, a new experimental approach. Results indicate that external mushroom structure results from toroidal circulation of buoyant source and immediate cover having similar effective viscosities, whereas internal structure is produced by toroidal circulation confined within the diapir. The internal diapir structure elucidates the mechanics of emplacement and indicates whether an external mushroom shape can be expected and sought by further exploration.« less

  5. Method for the simultaneous recovery of radionuclides from liquid radioactive wastes using a solvent

    DOEpatents

    Romanovskiy, Valeriy Nicholiavich; Smirnov, Igor V.; Babain, Vasiliy A.; Todd, Terry A.; Brewer, Ken N.

    2001-01-01

    The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

  6. Recent developments in the French programme for radioactive waste management planning Act of 28 june 2006

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ouzounian, G.

    2007-07-01

    In 2005, new developments on radioactive-waste management in France were marked mostly by the preparation of the 2006 milestone specified in the act of 30 December 1991. A bill on radioactive waste management has been prepared by the Government at the beginning of 2006 and passed to the French Parliament on 15 June 2006. The Planning Act on the sustainable management of radioactive materials and wastes has been drawn from the results of the 15 years of research performed by ANDRA and the CEA on 'partitioning and transmutation of long-lived radionuclides', 'deep geological disposal' and 'conditioning and long term interimmore » storage'. Major milestones during those two last years are presented, including reviews of the Dossier 2005, official reports, the Public Debate, and finally the Planning Act. (authors)« less

  7. Radioactive Waste Management Complex performance assessment: Draft

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Case, M.J.; Maheras, S.J.; McKenzie-Carter, M.A.

    1990-06-01

    A radiological performance assessment of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory was conducted to demonstrate compliance with appropriate radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the general public. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the general public via air, ground water, and food chain pathways. Projections of doses were made for both offsite receptors and individuals intruding onto the site after closure. In addition, uncertainty analyses were performed. Resultsmore » of calculations made using nominal data indicate that the radiological doses will be below appropriate radiological criteria throughout operations and after closure of the facility. Recommendations were made for future performance assessment calculations.« less

  8. Waste Isolation Pilot Plant Salt Decontamination Testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rick Demmer; Stephen Reese

    2014-09-01

    On February 14, 2014, americium and plutonium contamination was released in the Waste Isolation Pilot Plant (WIPP) salt caverns. At the request of WIPP’s operations contractor, Idaho National Laboratory (INL) personnel developed several methods of decontaminating WIPP salt, using surrogate contaminants and also americium (241Am). The effectiveness of the methods is evaluated qualitatively, and to the extent possible, quantitatively. One of the requirements of this effort was delivering initial results and recommendations within a few weeks. That requirement, in combination with the limited scope of the project, made in-depth analysis impractical in some instances. Of the methods tested (dry brushing,more » vacuum cleaning, water washing, strippable coatings, and mechanical grinding), the most practical seems to be water washing. Effectiveness is very high, and it is very easy and rapid to deploy. The amount of wastewater produced (2 L/m2) would be substantial and may not be easy to manage, but the method is the clear winner from a usability perspective. Removable surface contamination levels (smear results) from the strippable coating and water washing coupons found no residual removable contamination. Thus, whatever is left is likely adhered to (or trapped within) the salt. The other option that shows promise is the use of a fixative barrier. Bartlett Nuclear, Inc.’s Polymeric Barrier System (PBS) proved the most durable of the coatings tested. The coatings were not tested for contaminant entrapment, only for coating integrity and durability.« less

  9. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1986-1990

    USGS Publications Warehouse

    Trask, N.J.; Stevens, P.R.

    1991-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research efforts are categorized according to whether they are related most directly to: (1) high-level wastes, (2) transuranic wastes, (3) low-level and mixed low-level and hazardous wastes, or (4) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, to development of techniques and methods for characterizing disposal sites, and to studies of geologic and hydrologic processes related to the transport and/or retention of waste radionuclides.

  10. Training Activities on Radioactive Waste Management at Moscow SIA -Radon-: Experience, Practice, Theory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Batyukhnova, O.G.; Arustamov, A.E.; Dmitriev, S.A.

    Management of radioactive waste relates to the category of hazardous activities. Hence the requirements to the professional level of managers and personnel working in this industry are very high. Education, training and examination of managers, operators and workers are important elements of assuring safe and efficient operation of radioactive waste management sites. The International Education Training Centre (IETC) at Moscow State Unitary Enterprise Scientific and Industrial Association 'Radon' (SIA 'Radon'), in co-operation with the International Atomic Energy Agency (IAEA), has developed expertise and provided training to waste management personnel for the last 10 years. The paper summarizes the current experiencemore » of the SIA 'Radon' in the organisation and implementation of the IAEA sponsored training and others events and outlines some of strategic educational elements, which IETC will continue to pursue in the coming years. (authors)« less

  11. Leaching of plutonium from a radioactive waste glass by eight groundwaters from the western United States

    USGS Publications Warehouse

    Rees, T.F.; Cleveland, J.M.; Nash, K.L.

    1985-01-01

    The leachability of a radioactive waste glass formulated to Battelle Pacific Northwest Laboratory specification 80-270 has been studied using eight actual groundwaters with a range of chemical compositions as leachants. Waters collected from the Grande Ronde Basalt (Washington State) and from alluvial deposits in the Hualapai Valley (Arizona) were the most effective at removing plutonium from this glass. Leaching was shown to be incongruent; plutonium was removed from the glass more slowly than the overall glass matrix. The results of these experiments indicate the need to study the leachability of actual waste forms using the actual projected groundwaters that are most likely to come into contact with the waste should a radioactive waste repository be breached.

  12. Research of ceramic matrix for a safe immobilization of radioactive sludge waste

    NASA Astrophysics Data System (ADS)

    Dorofeeva, Ludmila; Orekhov, Dmitry

    2018-03-01

    The research and improvement of the existing method for radioactive waste hardening by fixation in a ceramic matrix was carried out. For the samples covered with the sodium silicate and tested after the storage on the air the speed of a radionuclides leaching was determined. The properties of a clay ceramics and the optimum conditions of sintering were defined. The experimental data about the influence of a temperature mode sintering, water quantities, sludge and additives in the samples on their mechanical durability and a water resistance were obtained. The comparative analysis of the conducted research is aimed at improvement of the existing method of the hardening radioactive waste by inclusion in a ceramic matrix and reveals the advantages of the received results over analogs.

  13. Monitoring technologies for ocean disposal of radioactive waste

    NASA Astrophysics Data System (ADS)

    Triplett, M. B.; Solomon, K. A.; Bishop, C. B.; Tyce, R. C.

    1982-01-01

    The feasibility of using carefully selected subseabed locations to permanently isolate high level radioactive wastes at ocean depths greater than 4000 meters is discussed. Disposal at several candidate subseabed areas is being studied because of the long term geologic stability of the sediments, remoteness from human activity, and lack of useful natural resources. While the deep sea environment is remote, it also poses some significant challenges for the technology required to survey and monitor these sites, to identify and pinpoint container leakage should it occur, and to provide the environmental information and data base essential to determining the probable impacts of any such occurrence. Objectives and technical approaches to aid in the selective development of advanced technologies for the future monitoring of nuclear low level and high level waste disposal in the deep seabed are presented. Detailed recommendations for measurement and sampling technology development needed for deep seabed nuclear waste monitoring are also presented.

  14. Radioactive Waste Management, its Global Implication on Societies, and Political Impact

    NASA Astrophysics Data System (ADS)

    Matsui, Kazuaki

    2009-05-01

    Reprocessing plant in Rokkasho, Japan is under commissioning at the end of 2008, and it starts soon to reprocess about 800 Mt of spent fuel per annum, which have been stored at each nuclear power plant sites in Japan. Fission products together with minor actinides separated from uranium and plutonium in the spent fuel contain almost all radioactivity of it and will be vitrified with glass matrix, which then will fill the canisters. The canisters with the high level radioactive waste (HLW) are so hot in both thermal and radiological meanings that they have to be cooled off for decades before bringing out to any destination. Where is the final destination for HLW in Japan, which is located at the rim of the Pacific Ocean with volcanoes? Although geological formation in Japan is not so static and rather active as the other parts of the planet, experts concluded with some intensive studies and researches that there will be a lot of variety of geological formations even in Japan which can host the HLW for so long times of more than million years. Then an organization to implement HLW disposal program was set up and started to campaign for volunteers to accept the survey on geological suitability for HLW disposal. Some local governments wanted to apply, but were crashed down by local and neighbor governments and residents. The above development is not peculiar only to Japan, but generally speaking more or less common for those with radioactive waste programs. This is why the radioactive waste management is not any more science and technology issue but socio-political one. It does not mean further R&D on geological disposal is not any more necessary, but rather we, each of us, should face much more sincerely the societal and political issues caused by the development of the science and technology. Second topic might be how effective partitioning and transformation technology may be to reduce the burden of waste disposal and denature the waste toxicity? The third one might

  15. Principles and Tasks of the New Regulatory System for Radioactive Waste Management in the Russian Federation - 12020

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bolshov, L.A.; Linge, I.I.; Kovalchuk, V.D.

    This year the Federal Law 'On Radioactive Waste management' was adopted in the Russian Federation. The law significantly changes the existing radioactive waste management regulatory system and assigns a lot of new tasks in order to implement new principles and overcome inevitable respective difficulties. Nuclear Safety Institute was largely involved in the process of the development of the law as well as its further co-ordination among the stakeholders, during which some important initial provisions were excluded. In the paper special features of the Russian safety regulation system for radioactive waste management are analyzed. Most significant requirements adopted by the lawmore » as well as tasks and expected difficulties related to its implementation are discussed. (authors)« less

  16. The NEA research and environmental surveillance programme related to sea disposal of low-level radioactive waste

    NASA Astrophysics Data System (ADS)

    Rugger, B.; Templeton, W. L.; Gurbutt, P.

    1983-05-01

    Sea dumping operations of certain types of packaged low and medium level radioactive wastes have been carried out since 1967 in the North-East Atlantic under the auspices of the OECD Nuclear Energy Agency. On the occasion of the 1980 review of the continued suitability of the North-East Atlantic site used for the disposal of radioactive waste, it was recommended that an effort should be made to increase the scientific data base relating to the oceanographic and biological characteristics of the dumping area. In particular, it was suggested that a site specific model of the transfer of radionuclides in the marine environment be developed, which would permit a better assessment of the potential radiation doses to man from the dumping of radioactive waste. To fulfill these objectives a research and environmental surveillance program related to sea disposal of radioactive waste was set up in 1981 with the participation of thirteen Member countries and the International Laboratory for Marine Radioactivity of the IAEA in Monaco. The research program is focused on five research areas which are directly relevant to the preparation of more site specific assessments in the future. They are: model development; physical oceanography; geochemistry; biology; and radiological surveillance. Promising results have already been obtained and more are anticipated in the not too distant future. An interim description of the NEA dumping site has been prepared which provides an excellent data base for this area.

  17. Bench scale experiments for the remediation of Hanford Waste Treatment Plant low activity waste melter off-gas condensate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Taylor-Pashow, Kathryn M.L.; Poirier, Michael; McCabe, Daniel J.

    The Low Activity Waste (LAW) vitrification facility at the Hanford Waste Treatment and Immobilization Plant (WTP) will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The plan for disposition of this stream during baseline operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. The primary reason to recycle this stream is so that the semi-volatile 99Tc isotope eventually becomes incorporated into the glass. This stream also contains non-radioactive salt components that are problematic in the melter,more » so diversion of this stream to another process would eliminate recycling of these salts and would enable simplified operation of the LAW melter and the Pretreatment Facilities. This diversion from recycling this stream within WTP would have the effect of decreasing the LAW vitrification mission duration and quantity of glass waste. The concept being tested here involves removing the 99Tc so that the decontaminated aqueous stream, with the problematic salts, can be disposed elsewhere.« less

  18. Analogues to features and processes of a high-level radioactive waste repository proposed for Yucca Mountain, Nevada

    USGS Publications Warehouse

    Simmons, Ardyth M.; Stuckless, John S.; with a Foreword by Abraham Van Luik, U.S. Department of Energy

    2010-01-01

    Natural analogues are defined for this report as naturally occurring or anthropogenic systems in which processes similar to those expected to occur in a nuclear waste repository are thought to have taken place over time periods of decades to millennia and on spatial scales as much as tens of kilometers. Analogues provide an important temporal and spatial dimension that cannot be tested by laboratory or field-scale experiments. Analogues provide one of the multiple lines of evidence intended to increase confidence in the safe geologic disposal of high-level radioactive waste. Although the work in this report was completed specifically for Yucca Mountain, Nevada, as the proposed geologic repository for high-level radioactive waste under the U.S. Nuclear Waste Policy Act, the applicability of the science, analyses, and interpretations is not limited to a specific site. Natural and anthropogenic analogues have provided and can continue to provide value in understanding features and processes of importance across a wide variety of topics in addressing the challenges of geologic isolation of radioactive waste and also as a contribution to scientific investigations unrelated to waste disposal. Isolation of radioactive waste at a mined geologic repository would be through a combination of natural features and engineered barriers. In this report we examine analogues to many of the various components of the Yucca Mountain system, including the preservation of materials in unsaturated environments, flow of water through unsaturated volcanic tuff, seepage into repository drifts, repository drift stability, stability and alteration of waste forms and components of the engineered barrier system, and transport of radionuclides through unsaturated and saturated rock zones.

  19. Study of extraterrestrial disposal of radioactive wastes. Part 3: Preliminary feasibility screening study of space disposal of the actinide radioactive wastes with 1 percent and 0.1 percent fission product contamination

    NASA Technical Reports Server (NTRS)

    Hyland, R. E.; Wohl, M. L.; Finnegan, P. M.

    1973-01-01

    A preliminary study was conducted of the feasibility of space disposal of the actinide class of radioactive waste material. This waste was assumed to contain 1 and 0.1 percent residual fission products, since it may not be feasible to completely separate the actinides. The actinides are a small fraction of the total waste but they remain radioactive much longer than the other wastes and must be isolated from human encounter for tens of thousands of years. Results indicate that space disposal is promising but more study is required, particularly in the area of safety. The minimum cost of space transportation would increase the consumer electric utility bill by the order of 1 percent for earth escape and 3 percent for solar escape. The waste package in this phase of the study was designed for normal operating conditions only; the design of next phase of the study will include provisions for accident safety. The number of shuttle launches per year required to dispose of all U.S. generated actinide waste with 0.1 percent residual fission products varies between 3 and 15 in 1985 and between 25 and 110 by 2000. The lower values assume earth escape (solar orbit) and the higher values are for escape from the solar system.

  20. 77 FR 52072 - Request To Amend a License to Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-28

    ..., 2012 IW022/ radioactive total of 5,500 beneficial reuse 02 11005700. waste including tons or about and... thermal and non- paper, cloth, activity thermal concrete, material, and treatment. rubber, plastic, 500...

  1. Collective dose estimates by the marine food pathway from liquid radioactive wastes dumped in the Sea of Japan.

    PubMed

    Togawa, O; Povinec, P P; Pettersson, H B

    1999-09-30

    IAEA-MEL has been engaged in an assessment programme related to radioactive waste dumping by the former USSR and other countries in the western North Pacific Ocean and its marginal seas. This paper focuses on the Sea of Japan and on estimation of collective doses from liquid radioactive wastes. The results from the Japanese-Korean-Russian joint expeditions are summarized, and collective doses for the Japanese population by the marine food pathway are estimated from liquid radioactive wastes dumped in the Sea of Japan and compared with those from global fallout and natural radionuclides. The collective effective dose equivalents by the annual intake of marine products caught in each year show a maximum a few years after the disposals. The total dose from all radionuclides reaches a maximum of 0.8 man Sv in 1990. Approximately 90% of the dose derives from 137Cs, most of which is due to consumption of fish. The total dose from liquid radioactive wastes is approximately 5% of that from global fallout, the contribution of which is below 0.1% of that of natural 210Po.

  2. Favorable Decision Upholding Radioactive/Hazardous Mixed Waste Storage Civil Enforcement Policy

    EPA Pesticide Factsheets

    This page contains a copy of the U.S. Court of Appeals (District of Columbia Circuit) decision in Edison Electric Institute, et al. v. EPA, No. 91-1586, which upheld the EPA's August 29, 1991, radioactive/hazardous 'mixed waste' storage civil enforcement policy

  3. I-NERI-2007-004-K, DEVELOPMENT AND CHARACTERIZATION OF NEW HIGH-LEVEL WASTE FORMS FOR ACHIEVING WASTE MINIMIZATION FROM PYROPROCESSING

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S.M. Frank

    Work describe in this report represents the final year activities for the 3-year International Nuclear Energy Research Initiative (I-NERI) project: Development and Characterization of New High-Level Waste Forms for Achieving Waste Minimization from Pyroprocessing. Used electrorefiner salt that contained actinide chlorides and was highly loaded with surrogate fission products was processed into three candidate waste forms. The first waste form, a high-loaded ceramic waste form is a variant to the CWF produced during the treatment of Experimental Breeder Reactor-II used fuel at the Idaho National Laboratory (INL). The two other waste forms were developed by researchers at the Korean Atomicmore » Energy Research Institute (KAERI). These materials are based on a silica-alumina-phosphate matrix and a zinc/titanium oxide matrix. The proposed waste forms, and the processes to fabricate them, were designed to immobilize spent electrorefiner chloride salts containing alkali, alkaline earth, lanthanide, and halide fission products that accumulate in the salt during the processing of used nuclear fuel. This aspect of the I-NERI project was to demonstrate 'hot cell' fabrication and characterization of the proposed waste forms. The outline of the report includes the processing of the spent electrorefiner salt and the fabrication of each of the three waste forms. Also described is the characterization of the waste forms, and chemical durability testing of the material. While waste form fabrication and sample preparation for characterization must be accomplished in a radiological hot cell facility due to hazardous radioactivity levels, smaller quantities of each waste form were removed from the hot cell to perform various analyses. Characterization included density measurement, elemental analysis, x-ray diffraction, scanning electron microscopy and the Product Consistency Test, which is a leaching method to measure chemical durability. Favorable results from this demonstration

  4. Special Analysis: 2016-001 Analysis of the Potential Under-Reporting of Am-241 Inventory for Nitrate Salt Waste at Area G

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chu, Shaoping; Stauffer, Philip H.; Birdsell, Kay Hanson

    The Los Alamos National Laboratory (LANL) generates radioactive waste as a result of various activities. Operational waste is generated from a wide variety of research and development activities including nuclear weapons development, energy production, and medical research. Environmental restoration (ER), and decontamination and decommissioning (D&D) waste is generated as contaminated sites and facilities at LANL undergo cleanup or remediation. The majority of this waste is low-level radioactive waste (LLW) and is disposed of at the Technical Area 54 (TA-54), Area G disposal facility.

  5. Low-Level Radioactive Waste Management in the United States: What Have We Wrought? The Richard S. Hodes, M.D. Honor Lecture Award - 12222

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jacobi, Lawrence R.

    2012-07-01

    In 1979, radioactive waste disposal was an important national issue. State governors were closing the gates on the existing low-level radioactive waste disposal sites and the ultimate disposition of spent fuel was undecided. A few years later, the United States Congress thought they had solved both problems by passing the Low-Level Radioactive Waste Policy Act of 1981, which established a network of regional compacts for low-level radioactive waste disposal, and by passing the Nuclear Waste Policy Act of 1982 to set out how a final resting place for high-level waste would be determined. Upon passage of the acts, State, Regionalmore » and Federal officials went to work. Here we are some 30 years later with little to show for our combined effort. The envisioned national repository for high-level radioactive waste has not materialized. Efforts to develop the Yucca Mountain high-level radioactive waste disposal facility were abandoned after spending $13 billion on the failed project. Recently, the Blue Ribbon Commission on America's Nuclear Future issued its draft report that correctly concludes the existing policy toward high-level nuclear waste is 'all but completely broken down'. A couple of new low-level waste disposal facilities have opened since 1981, but neither were the result of efforts under the act. What the Act has done is interject a system of interstate compacts with a byzantine interstate import and export system to complicate the handling of low-level radioactive waste, with attendant costs. As this paper is being written in the fourth-quarter of 2011, after 30 years of political and bureaucratic turmoil, a new comprehensive low-level waste disposal facility at Andrews Texas is approaching its initial operating date. The Yucca Mountain project might be completed or it might not. The US Nuclear Regulatory Commission is commencing a review of their 1981 volume reduction policy statement. The Department of Energy after 26 years has yet to figure out how

  6. Yucca Mountain, Nevada - A proposed geologic repository for high-level radioactive waste

    USGS Publications Warehouse

    Levich, R.A.; Stuckless, J.S.

    2006-01-01

    Yucca Mountain in Nevada represents the proposed solution to what has been a lengthy national effort to dispose of high-level radioactive waste, waste which must be isolated from the biosphere for tens of thousands of years. This chapter reviews the background of that national effort and includes some discussion of international work in order to provide a more complete framework for the problem of waste disposal. Other chapters provide the regional geologic setting, the geology of the Yucca Mountain site, the tectonics, and climate (past, present, and future). These last two chapters are integral to prediction of long-term waste isolation. ?? 2007 Geological Society of America. All rights reserved.

  7. Radiological risk assessment and biosphere modelling for radioactive waste disposal in Switzerland.

    PubMed

    Brennwald, M S; van Dorp, F

    2009-12-01

    Long-term safety assessments for geological disposal of radioactive waste in Switzerland involve the demonstration that the annual radiation dose to humans due to the potential release of radionuclides from the waste repository into the biosphere will not exceed the regulatory limit of 0.1 mSv. Here, we describe the simple but robust approach used by Nagra (Swiss National Cooperative for the Disposal of Radioactive Waste) to quantify the dose to humans as a result to time-dependent release of radionuclides from the geosphere into the biosphere. The model calculates the concentrations of radionuclides in different terrestrial and aquatic compartments of the surface environment. The fluxes of water and solids within the environment are the drivers for the exchange of radionuclides between these compartments. The calculated radionuclide concentrations in the biosphere are then used to estimate the radiation doses to humans due to various exposure paths (e.g. ingestion of radionuclides via drinking water and food, inhalation of radionuclides, external irradiation from radionuclides in soils). In this paper we also discuss recent new achievements and planned future work.

  8. Modelling the sulfate capacity of simulated radioactive waste borosilicate glasses

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bingham, P. A.; Vaishnav, S.; Forder, S. D.

    2017-02-01

    The capacity of simulated high-level radioactive waste borosilicate glasses to incorporate sulfate has been studied as a function of glass composition. Combined Raman, 57Fe Mössbauer and literature evidence supports the attribution of coordination numbers and oxidation states of constituent cations for the purposes of modelling, and results confirm the validity of correlating sulfate incorporation in multicomponent borosilicate radioactive waste glasses with different models. A strong compositional dependency is observed and this can be described by an inverse linear relationship between incorporated sulfate (mol% SO 4 2-) and total cation field strength index of the glass, Σ(z/a 2), with a highmore » goodness-of-fit (R 2 ≈ 0.950). Similar relationships are also obtained if theoretical optical basicity, Λ th (R 2 ≈ 0.930) or non-bridging oxygen per tetrahedron ratio, NBO/T (R 2 ≈ 0.919), are used. Results support the application of these models, and in particular Σ(z/a 2), as predictive tools to aid the development of new glass compositions with enhanced sulfate capacities.« less

  9. Understanding the toxicity of buried radioactive waste and its impacts.

    PubMed

    Cohen, Bernard L

    2005-10-01

    The oral ingestion toxicities of buried high level radioactive waste from nuclear power plants and of the natural radioactivity in the ground are calculated and expressed as cancer doses, the number of fatal cancers predicted by the linear no-threshold theory if all of the material were fed to people. Unless the size of the U.S. nuclear power industry is greatly expanded, there will probably never be more than 2 trillion cancer doses (CD) in U.S. repositories, as compared with 31 trillion CD in the ground above them. Measurements of the uranium, thorium, and radium in human bodies indicate that the latter cause 500 deaths per year in U.S. The great majority of this material is derived from the top few meters of soil that are penetrated by plant roots. It is concluded that the annual number of U.S. deaths from buried nuclear wastes will be about 1.0 (or less), orders of magnitude less than the number from coal burning electricity generation, the principal competitor of nuclear power.

  10. The Low-Level Radioactive Waste Management Office: Thirty Years of Experience in Canada - 13308

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Benitez, Liliana; Gardiner, Mark J.; Zelmer, Robert L.

    2013-07-01

    This paper reviews thirty years of progress by the Low-Level Radioactive Waste Management Office (LLRWMO) in developing and implementing low-level radioactive waste (LLRW) remediation projects and environmentally safe co-existence strategies. It reports on the present status and the future of the national historic waste program in Canada. There are over two million cubic metres of historic LLRW in Canada. Historic LLRW is broadly defined as LLRW that was managed in the past in a manner that is no longer considered acceptable and for which the original owner cannot reasonably be held accountable. In many cases, the original owner can notmore » be identified or no longer exists. The LLRWMO was established in 1982 as Canada's agent to carry out the responsibilities of the federal government for the management of historic LLRW. The LLRWMO is operated by Atomic Energy of Canada Limited (AECL) through a cost-recovery agreement with Natural Resources Canada (NRCan), the federal department that provides the funding and establishes national policy for radioactive waste management in Canada. The LLRWMO expertise includes project managers, environmental remediation specialists, radiation surveyors, communications staff and administrative support staff. The LLRWMO in providing all aspects of project oversight and implementation contracts additional resources supplementing core staff capacity as project/program demands require. (authors)« less

  11. An optimal method for phosphorylation of rare earth chlorides in LiCl-KCl eutectic based waste salt

    NASA Astrophysics Data System (ADS)

    Eun, H. C.; Kim, J. H.; Cho, Y. Z.; Choi, J. H.; Lee, T. K.; Park, H. S.; Park, G. I.

    2013-11-01

    A study on an optimal method for the phosphorylation of rare earth chlorides in LiCl-KCl eutectic waste salt generated the pyrochemical process of spent nuclear fuel was performed. A reactor with a pitched four blade impeller was designed to create a homogeneous mixing zone in LiCl-KCl eutectic salt. A phosphorylation test of NdCl3 in the salt was carried out by changing the operation conditions (operation temperature, stirring rate, agent injection amount). Based on the results of the test, a proper operation condition (450 °C, 300 rpm, 1 eq. of phosphorylation agent) for over a 0.99 conversion ratio of NdCl3 to NdPO4 was determined. Under this condition, multi-component rare earth (La, Ce, Pr, Nd, Sm, Eu, Gd, Y) chlorides were effectively converted into phosphate forms. It was confirmed that the existing regeneration process of LiCl-KCl eutectic waste salt can be greatly improved and simplified through these phosphorylation test results.

  12. Concrete and cement composites used for radioactive waste deposition.

    PubMed

    Koťátková, Jaroslava; Zatloukal, Jan; Reiterman, Pavel; Kolář, Karel

    2017-11-01

    This review article presents the current state-of-knowledge of the use of cementitious materials for radioactive waste disposal. An overview of radwaste management processes with respect to the classification of the waste type is given. The application of cementitious materials for waste disposal is divided into two main lines: i) as a matrix for direct immobilization of treated waste form; and ii) as an engineered barrier of secondary protection in the form of concrete or grout. In the first part the immobilization mechanisms of the waste by cement hydration products is briefly described and an up-to date knowledge about the performance of different cementitious materials is given, including both traditional cements and alternative binder systems. The advantages, disadvantages as well as gaps in the base of information in relation to individual materials are stated. The following part of the article is aimed at description of multi-barrier systems for intermediate level waste repositories. It provides examples of proposed concepts by countries with advanced waste management programmes. In the paper summary, the good knowledge of the material durability due to its vast experience from civil engineering is highlighted however with the urge for specific approach during design and construction of a repository in terms of stringent safety requirements. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. An experimental study on Sodalite and SAP matrices for immobilization of spent chloride salt waste

    NASA Astrophysics Data System (ADS)

    Giacobbo, Francesca; Da Ros, Mirko; Macerata, Elena; Mariani, Mario; Giola, Marco; De Angelis, Giorgio; Capone, Mauro; Fedeli, Carlo

    2018-02-01

    In the frame of Generation IV reactors a renewed interest in pyro-processing of spent nuclear fuel is underway. Molten chloride salt waste arising from the recovering of uranium and plutonium through pyro-processing is one of the problematic wastes for direct application of vitrification or ceramization. In this work, Sodalite and SAP have been evaluated and compared as potential matrices for confinement of spent chloride salt waste coming from pyro-processing. To this aim Sodalite and SAP were synthesized both in pure form and mixed with different glass matrices, i.e. commercially available glass frit and borosilicate glass. The confining matrices were loaded with mixed chloride salts to study their retention capacities with respect to the elements of interest. The matrices were characterized and leached for contact times up to 150 days at room temperature and at 90 °C. SEM analyses were also performed in order to compare the matrix surface before and after leaching. Leaching results are discussed and compared in terms of normalized releases with similar results reported in literature. According to this comparative study the SAP matrix with glass frit binder resulted in the best matrix among the ones studied, with respect to retention capacities for both matrix and spent fuel elements.

  14. Radioactive nuclear waste stabilization - Aspects of solid-state molecular engineering and applied geochemistry

    NASA Technical Reports Server (NTRS)

    Haggerty, S. E.

    1983-01-01

    Stabilization techniques for the storage of radioactive wastes are surveyed, with emphasis on immobilization in a primary barrier of synthetic rock. The composition, half-life, and thermal-emission characteristics of the wastes are shown to require thermally stable immobilization enduring at least 100,000 years. Glass materials are determined to be incapable of withstanding the expected conditions, average temperatures of 100-500 C for the first 100 years. The geological-time stability of crystalline materials, ceramics or synthetic rocks, is examined in detail by comparing their components with similar naturally occurring minerals, especially those containing the same radioactive elements. The high-temperature environment over the first 100 years is seen as stabilizing, since it can recrystallize radiation-induced metamicts. The synthetic-rock stabilization technique is found to be essentially feasible, and improvements are suggested, including the substitution of nepheline with freudenbergite and priderite for alkaline-waste stabilization, the maintenance of low oxygen fugacity, and the dilution of the synthetic-rock pellets into an inert medium.

  15. Electrochemical probing of high-level radioactive waste tanks containing washed sludge and precipitates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bickford, D.F.; Congdon, J.W.; Oblath, S.B.

    1986-12-01

    At the US Department of Energy's Savannah River Plant, corrosion of carbon steel storage tanks containing alkaline, high-level radioactive waste is controlled by specification of limits on waste composition and temperature. Processes for the preparation of waste for final disposal will result in waste with low corrosion inhibitor concentrations and, in some cases, high aromatic organic concentrations, neither of which are characteristic of previous operations. Laboratory tests, conducted to determine minimum corrosion inhibitor levels indicated pitting of carbon steel near the waterline for proposed storage conditions. In situ electrochemical measurements of full-scale radioactive process demonstrations have been conducted to assessmore » the validity of laboratory tests. Probes included pH, Eh (potential relative to a standard hydrogen electrode), tank potential, and alloy coupons. In situ results are compared to those of the laboratory tests, with particular regard given to simulated solution composition. Transition metal hydroxide sludge contains strong passivating species for carbon steel. Washed precipitate contains organic species that lower solution pH and tend to reduce passivating films, requiring higher inhibitor concentrations than the 0.01 molar nitrite required for reactor fuel reprocessing wastes. Periodic agitation, to keep the organic phase suspended, or cathodic protection are possible alternatives to higher nitrite inhibitor concentrations.« less

  16. Regulatory control of low level radioactive waste in Taiwan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, T.D.S.; Chiou, Syh-Tsong

    1996-12-31

    The commercial operation of Chinshan Nuclear Power Plant (NPP) Unit One marked the beginning of Taiwan`s nuclear power program. There are now three NPPs, each consisting of two units, in operation. This represents a generating capacity of 5,144 MWe. Nuclear power plants are sharing some 30 percent of electricity supplies in Taiwan. As far as low level radwaste (LLRW) is concerned, Taiwan Power Company (TPC) is the principal producer, contributing more than 90 percent of total volume of waste arising in Taiwan. Small producers, other than nuclear industries, medicine, research institutes, and universities, are responsible for the remaining 10 percent.more » In the paper, the LLRW management policy, organizational scheme, regulatory control over waste treatment, storage, transportation and disposal are addressed. Added to the paper in the last is how this country is managing its Naturally Occurring Radioactive Materials (NORM) waste.« less

  17. 78 FR 45578 - Application For a License to Export Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-29

    ... NUCLEAR REGULATORY COMMISSION Application For a License to Export Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear... requestor or petitioner upon the applicant, the office of the General Counsel, U.S. Nuclear Regulatory...

  18. 78 FR 45579 - Request for a License to Import Radioactive Waste

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-29

    ... NUCLEAR REGULATORY COMMISSION Request for a License to Import Radioactive Waste Pursuant to 10 CFR 110.70 (b) ``Public Notice of Receipt of an Application,'' please take notice that the Nuclear... requestor or petitioner upon the applicant, the office of the General Counsel, U.S. Nuclear Regulatory...

  19. Finite element code FENIA verification and application for 3D modelling of thermal state of radioactive waste deep geological repository

    NASA Astrophysics Data System (ADS)

    Butov, R. A.; Drobyshevsky, N. I.; Moiseenko, E. V.; Tokarev, U. N.

    2017-11-01

    The verification of the FENIA finite element code on some problems and an example of its application are presented in the paper. The code is being developing for 3D modelling of thermal, mechanical and hydrodynamical (THM) problems related to the functioning of deep geological repositories. Verification of the code for two analytical problems has been performed. The first one is point heat source with exponential heat decrease, the second one - linear heat source with similar behavior. Analytical solutions have been obtained by the authors. The problems have been chosen because they reflect the processes influencing the thermal state of deep geological repository of radioactive waste. Verification was performed for several meshes with different resolution. Good convergence between analytical and numerical solutions was achieved. The application of the FENIA code is illustrated by 3D modelling of thermal state of a prototypic deep geological repository of radioactive waste. The repository is designed for disposal of radioactive waste in a rock at depth of several hundred meters with no intention of later retrieval. Vitrified radioactive waste is placed in the containers, which are placed in vertical boreholes. The residual decay heat of radioactive waste leads to containers, engineered safety barriers and host rock heating. Maximum temperatures and corresponding times of their establishment have been determined.

  20. National profile on commercially generated low-level radioactive mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Klein, J.A.; Mrochek, J.E.; Jolley, R.L.

    1992-12-01

    This report details the findings and conclusions drawn from a survey undertaken as part of a joint US Nuclear Regulatory Commission and US Environmental Protection Agency-sponsored project entitled ``National Profile on Commercially Generated Low-Level Radioactive Mixed Waste.`` The overall objective of the work was to compile a national profile on the volumes, characteristics, and treatability of commercially generated low-level mixed waste for 1990 by five major facility categories-academic, industrial, medical, and NRC-/Agreement State-licensed goverment facilities and nuclear utilities. Included in this report are descriptions of the methodology used to collect and collate the data, the procedures used to estimate themore » mixed waste generation rate for commercial facilities in the United States in 1990, and the identification of available treatment technologies to meet applicable EPA treatment standards (40 CFR Part 268) and, if possible, to render the hazardous component of specific mixed waste streams nonhazardous. The report also contains information on existing and potential commercial waste treatment facilities that may provide treatment for specific waste streams identified in the national survey. The report does not include any aspect of the Department of Energy`s (DOES) management of mixed waste and generally does not address wastes from remedial action activities.« less

  1. Study of extraterrestrial disposal of radioactive wastes. Part 1: Space transportation and destination considerations for extraterrestrial disposal of radioactive wastes. [feasibility of using space shuttle

    NASA Technical Reports Server (NTRS)

    Thompson, R. L.; Ramler, J. R.; Stevenson, S. M.

    1974-01-01

    A feasibility study of extraterrestrial disposal of radioactive waste is reported. This report covers the initial work done on only one part of the NASA study, that evaluates and compares possible space destinations and space transportation systems. The currently planned space shuttle was found to be more cost effective than current expendable launch vehicles by about a factor of 2. The space shuttle requires a third stage to perform the waste disposal missions. Depending on the particular mission, this third stage could be either a reusable space tug or an expendable stage such as a Centaur.

  2. Polonium-210 in the environment around a radioactive waste disposal area and phosphate ore processing plant.

    PubMed

    Arthur, W J; Markham, O D

    1984-04-01

    Polonium-210 concentrations were determined for soil, vegetation and small mammal tissues collected at a solid radioactive waste disposal area, near a phosphate ore processing plant and at two rural areas in southeastern Idaho. Polonium concentrations in media sampled near the radioactive waste disposal facility were equal to or less than values from rural area samples, indicating that disposal of solid radioactive waste at the Idaho National Engineering Laboratory Site has not resulted in increased environmental levels of polonium. Concentrations of 210Po in soils, deer mice hide and carcass samples collected near the phosphate processing plant were statistically (P less than or equal to 0.05) greater than the other sampling locations; however, the mean 210Po concentration in soils and small mammal tissues from sampling areas near the phosphate plant were only four and three times greater, respectively, than control values. No statistical (P greater than 0.05) difference was observed for 210Po concentrations in vegetation among any of the sampling locations.

  3. Cesium distribution and phases in proxy experiments on the incineration of radioactively contaminated waste from the Fukushima area.

    PubMed

    Saffarzadeh, Amirhomayoun; Shimaoka, Takayuki; Kakuta, Yoshitada; Kawano, Takashi

    2014-10-01

    After the March 11, 2011 Tohoku earthquake and Fukushima I Nuclear Power Plant accident, incineration was initially adopted as an effective technique for the treatment of post-disaster wastes. Accordingly, considerable amounts of radioactively contaminated residues were immediately generated through incineration. The level of radioactivity associated with radiocesium in the incineration ash residues (bottom ash and fly ash) became significantly high (several thousand to 100,000 Bq/kg) as a result of this treatment. In order to understand the modes of occurrence of radiocesium, bottom ash products were synthesized through combusting of refuse-derived fuel (RDF) with stable Cs salts in a pilot incinerator. Microscopic and microanalytical (SEM-EDX) techniques were applied and the following Cs categories were identified: low and high concentrations in the matrix glass, low-level partitioning into some newly-formed silicate minerals, partitioning into metal-sulfide compounds, and occurring in newly-formed Cs-rich minerals. These categories that are essentially silicate-bound are the most dominant forms in large and medium size bottom ash particles. It is expected that these achievements provide solutions to the immobilization of radiocesium in the incineration ash products contaminated by Fukushima nuclear accident. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Assessment of Options for the Treatment of Nitrate Salt Wastes at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Robinson, Bruce Alan; Funk, David John; Stevens, Patrice Ann

    2016-03-17

    This paper summarizes the methodology used to evaluate options for treatment of the remediated nitrate salt waste containers at Los Alamos National Laboratory. The method selected must enable treatment of the waste drums, which consist of a mixture of complex nitrate salts (oxidizer) improperly mixed with sWheat Scoop®1, an organic kitty litter and absorbent (fuel), in a manner that renders the waste safe, meets the specifications of waste acceptance criteria, and is suitable for transport and final disposal in the Waste Isolation Pilot Plant located in Carlsbad, New Mexico. A Core Remediation Team was responsible for comprehensively reviewing the options,more » ensuring a robust, defensible treatment recommendation. The evaluation process consisted of two steps. First, a prescreening process was conducted to cull the list on the basis for a decision of feasibility of certain potential options with respect to the criteria. Then, the remaining potential options were evaluated and ranked against each of the criteria in a consistent methodology. Numerical scores were established by consensus of the review team. Finally, recommendations were developed based on current information and understanding of the scientific, technical, and regulatory situation. A discussion of the preferred options and documentation of the process used to reach the recommended treatment options are presented.« less

  5. Management of Low-Level Radioactive Waste from Research, Hospitals and Nuclear Medical Centers in Egypt - 13469

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hasan, M.A.; Selim, Y.T.; Lasheen, Y.F.

    2013-07-01

    The application of radioisotopes and radiation sources in medical diagnosis and therapy is an important issue. Physicians can use radioisotopes to diagnose and treat diseases. Methods of treatment, conditioning and management of low level radioactive wastes from the use of radiation sources and radioisotopes in hospitals and nuclear medicine application, are described. Solid Radioactive waste with low-level activity after accumulation, minimization, segregation and measurement, are burned or compressed in a compactor according to the international standards. Conditioned drums are transported to the interim storage site at the Egyptian Atomic Energy Authority (EAEA) represented in Hot Labs and Waste Management Centermore » (HLWMC) for storage and monitoring. (authors)« less

  6. Behavior of radioactive cesium during incineration of radioactively contaminated wastes from decontamination activities in Fukushima.

    PubMed

    Fujiwara, Hiroshi; Kuramochi, Hidetoshi; Nomura, Kazutaka; Maeseto, Tomoharu; Osako, Masahiro

    2017-11-01

    Large volumes of decontamination wastes (DW) generated by off-site decontamination activities in Fukushima Prefecture have been incinerated since 2015. The behavior of radioactive cesium during incineration of DW was investigated at a working incineration plant. The incineration discharged bottom ash (BA) and fly ash (FA) with similar levels of radiocesium, and the leachability of the radiocesium from both types of ash was very low (<1%). These results are significantly different from those obtained for the incineration of contaminated municipal solid waste (CMSW) reported in earlier studies. The source of radiocesium in DW-FA is chiefly small particles derived from DW and DW-BA blown into the flue gas, not the deposition of gaseous synthesized radiocesium compounds on the surfaces of ash particles in the flue gas as observed in CMSW incineration. This source difference causes the behavior of radiocesium during waste incineration to differ between DW and CMSW. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Slovenian Experience with the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stritar, A.

    Slovenia is a relatively small European country with only one operating nuclear power plant, one operating research reactor and one Central Interim Storage for Radioactive Waste from small producers. There are also a uranium mine and mill at Zirovski vrh, both in the decommissioning stage. The Slovenian Government, its public and neighboring countries are most interested in the managing of radioactive waste in the safest possible way by carefully utilizing best practices and existing human and financial resources. In order to achieve this goal the tight connection with the international community in the area of radioactive waste management is essential.more » Slovenia was among those countries involved in the process of preparation of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management (Joint Convention) from the very beginning and was also among first ratifiers. Slovenia had prepared the first report under the Convention and took part in the first Review Meeting in November 2003. The preparation of this report was not regarded only as a fulfillment of obligation toward Joint Convention, but was considered primarily as a kind of self appraisal of the national radioactive management program. Therefore the preparation of the report primarily contributed to the improvements in the field of radioactive waste management and consequently enhanced the safety of our public. For the preparation of the second report for the review meeting in 2006 it was decided to follow the structure of the first report. Only updates were introduced and eventual changes in the area of radioactive waste management were reflected. (authors)« less

  8. Low-level liquid radioactive waste treatment at Murmansk, Russia: Technical design and review of facility upgrade and expansion

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dyer, R.S.; Diamante, J.M.; Duffey, R.B.

    1996-07-01

    The governments of Norway and the US have committed their mutual cooperation and support the Murmansk Shipping Company (MSCo) to expand and upgrade the Low-Level Liquid Radioactive Waste (LLRW) treatment system located at the facilities of the Russian company RTP Atomflot, in Murmansk, Russia. RTP Atomflot provides support services to the Russian icebreaker fleet operated by the MSCo. The objective is to enable Russia to permanently cease disposing of this waste in Arctic waters. The proposed modifications will increase the facility`s capacity from 1,200 m{sup 3} per year to 5,000 m{sup 3} per year, will permit the facility to processmore » high-salt wastes from the Russian Navy`s Northern fleet, and will improve the stabilization and interim storage of the processed wastes. The three countries set up a cooperative review of the evolving design information, conducted by a joint US and Norwegian technical team from April through December, 1995. To ensure that US and Norwegian funds produce a final facility which will meet the objectives, this report documents the design as described by Atomflot and the Russian business organization, ASPECT, both in design documents and orally. During the detailed review process, many questions were generated, and many design details developed which are outlined here. The design is based on the adsorption of radionuclides on selected inorganic resins, and desalination and concentration using electromembranes. The US/Norwegian technical team reviewed the available information and recommended that the construction commence; they also recommended that a monitoring program for facility performance be instituted.« less

  9. Role of Congress in the High Level Radioactive Waste Odyssey: The Wisdom and Will of the Congress - 13096

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vieth, Donald L.; Voegele, Michael D.

    2013-07-01

    Congress has had a dual role with regard to high level radioactive waste, being involved in both its creation and its disposal. A significant amount of time has passed between the creation of the nation's first high level radioactive waste and the present day. The pace of addressing its remediation has been highly irregular. Congress has had to consider the technical, regulatory, and political issues and all have had specific difficulties. It is a true odyssey framed by an imperative and accountability, by a sense of urgency, by an ability or inability to finish the job and by consequences. Congressmore » had set a politically acceptable course by 1982. However, President Obama intervened in the process after he took office in January 2009. Through the efforts of his Administration, by the end of 2012, the US government has no program to dispose of high level radioactive waste and no reasonable prospect of a repository for high level radioactive waste. It is not obvious how the US government program will be reestablished or who will assume responsibility for leadership. The ultimate criteria for judging the consequences are 1) the outcome of the ongoing NRC's Nuclear Waste Confidence Rulemaking and 2) the concomitant permissibility of nuclear energy supplying electricity from operating reactors in the US. (authors)« less

  10. Safety monitoring of the FBG sensor in respect of radioactivity and deformation measurement of a silo structure for radioactive waste disposal

    NASA Astrophysics Data System (ADS)

    Kim, Ki-Soo; Cho, Seong-Kyu

    2015-07-01

    The FBG sensor has globally been commercialized in various fields that is actively applied in Korea as well. Especially it is widely used as a structural monitoring sensor in civil engineering and construction structures due to its advantages including electrical stability, chemical stability and multiplexing. This report aims to introduce safety inspection of the FBG sensor in respect of radioactivity which has been applied to a silo structure for radioactive waste disposal as an example.

  11. 238Pu recovery and salt disposition from the molten salt oxidation process

    NASA Astrophysics Data System (ADS)

    Remerowski, M. L.; Stimmel, Jay J.; Wong, Amy S.; Ramsey, Kevin B.

    2000-07-01

    We have begun designing and optimizing our recovery and recycling processes by experimenting with samples of "spent salt" produced by MSO treatment of surrogate waste in the reaction vessel at the Naval Surface Warfare Center-Indian Head. One salt was produced by treating surrogate waste containing pyrolysis ash spiked with cerium. The other salt contains residues from MSO treatment of materials similar to those used in 238Pu processing, e.g., Tygon tubing, PVC bagout bags, HDPE bottles. Using these two salt samples, we will present results from our investigations.

  12. Microwave applicator for in-drum processing of radioactive waste slurry

    DOEpatents

    White, T.L.

    1994-06-28

    A microwave applicator for processing of radioactive waste slurry uses a waveguide network which splits an input microwave of TE[sub 10] rectangular mode to TE[sub 01] circular mode. A cylindrical body has four openings, each receiving 1/4 of the power input. The waveguide network includes a plurality of splitters to effect the 1/4 divisions of power. 4 figures.

  13. Microwave applicator for in-drum processing of radioactive waste slurry

    DOEpatents

    White, Terry L.

    1994-01-01

    A microwave applicator for processing of radioactive waste slurry uses a waveguide network which splits an input microwave of TE.sub.10 rectangular mode to TE.sub.01 circular mode. A cylindrical body has four openings, each receiving 1/4 of the power input. The waveguide network includes a plurality of splitters to effect the 1/4 divisions of power.

  14. Response of soil microorganisms to radioactive oil waste: results from a leaching experiment

    NASA Astrophysics Data System (ADS)

    Galitskaya, P.; Biktasheva, L.; Saveliev, A.; Ratering, S.; Schnell, S.; Selivanovskaya, S.

    2015-06-01

    Oil wastes produced in large amounts in the processes of oil extraction, refining, and transportation are of great environmental concern because of their mutagenicity, toxicity, high fire hazardousness, and hydrophobicity. About 40% of these wastes contain radionuclides; however, the effects of oil products and radionuclides on soil microorganisms are frequently studied separately. The effects on various microbial parameters of raw waste containing 575 g of total petroleum hydrocarbons (TPH) kg-1 waste, 4.4 of 226Ra, 2.8 of 232Th, and 1.3 kBq kg-1 of 40K and its treated variant (1.6 g kg-1 of TPH, 7.9 of 226Ra, 3.9 of 232Th, and 183 kBq kg-1 of 40K) were examined in a leaching column experiment to separate the effects of hydrocarbons from those of radioactive elements. The raw waste sample (H) was collected from tanks during cleaning and maintenance, and a treated waste sample (R) was obtained from equipment for oil waste treatment. Thermal steam treatment is used in the production yard to reduce the oil content. The disposal of H waste samples on the soil surface led to an increase in the TPH content in soil: it became 3.5, 2.8, and 2.2 times higher in the upper (0-20 cm), middle (20-40 cm), and lower (40-60cm) layers, respectively. Activity concentrations of 226Ra and 232Th increased in soil sampled from both H- and R- columns in comparison to their concentrations in control soil. The activity concentrations of these two elements in samples taken from the upper and middle layers were much higher for the R-column compared to the H-column, despite the fact that the amount of waste added to the columns was equalized with respect to the activity concentrations of radionuclides. The H waste containing both TPH and radionuclides affected the functioning of the soil microbial community, and the effect was more pronounced in the upper layer of the column. Metabolic quotient and cellulase activity were the most sensitive microbial parameters as their levels were changed 5

  15. Impact of Salt Waste Processing Facility Streams on the Nitric-Glycolic Flowsheet in the Chemical Processing Cell

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Martino, C.

    An evaluation of the previous Chemical Processing Cell (CPC) testing was performed to determine whether the planned concurrent operation, or “coupled” operations, of the Defense Waste Processing Facility (DWPF) with the Salt Waste Processing Facility (SWPF) has been adequately covered. Tests with the nitricglycolic acid flowsheet, which were both coupled and uncoupled with salt waste streams, included several tests that required extended boiling times. This report provides the evaluation of previous testing and the testing recommendation requested by Savannah River Remediation. The focus of the evaluation was impact on flammability in CPC vessels (i.e., hydrogen generation rate, SWPF solvent components,more » antifoam degradation products) and processing impacts (i.e., acid window, melter feed target, rheological properties, antifoam requirements, and chemical composition).« less

  16. The French Radioactive Waste Disposal System: Which Discussions for Which Decisions?

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Baillet, J.P.; Ouzounian, G.

    2008-07-01

    Over the last 20 years or so, radioactive-waste management has undergone remarkable developments in France. The Law of 30 December 1991 prescribed that Parliament would convene once again at the end of a 15-year research period. In 2005, the government asked the National Commission on Public Debate to organise a public debate on radioactive-waste management. Hence, for the first time, such an event was held in accordance with a national policy and not on a specific project. The debate took place between 12 September 2005 and 13 January 2006. Although the debate remained mostly a discussion among experts and opposedmore » most frequently pro-nuclear and anti-nuclear activists, it still provided an opportunity to define and clarify challenges. Following the public debate and in the light of the assessment of investigation results, Parliament adopted on 28 June 2006 a new Planning Act on the Management of Radioactive Waste, which applies to all radioactive residues, irrespective of their activity level, and prescribes specific procedures and deadlines, such as the commissioning of a disposal facility for radium-bearing and graphite waste by 2013 and of a deep geological repository for high-level and intermediate-level long-lived waste by 2025. In the latter case, the Planning Act renews the assessment system for Andra's studies and investigations by a committee of experts and by the OPECST over and above the review of the future licence application by the Nuclear Safety Authority. In addition, a new law will set up the reversibility conditions of the repository before the government may grant any authorisation. At the local level, the act reinforces the prerogatives of the Local Information and Oversight Committee, which is responsible for public information and consultation issues; furthermore, it prescribes that a public debate and a public inquiry be held as a prerequisite to the delivery of any authorisation. Hence, ANDRA is taking all necessary means in order

  17. Forensic microanalysis of Manhattan Project legacy radioactive wastes in St. Louis, MO.

    PubMed

    Kaltofen, Marco; Alvarez, Robert; Hixson, Lucas W

    2018-06-01

    Radioactive particulate matter (RPM) in St Louis, MO, area surface soils, house dusts and sediments was examined by scanning electron microscopy with energy dispersive X-ray analysis. Analyses found RPM containing 238 U and decay products (up to 46 wt%), and a distinct second form of RPM containing 230 Th and decay products (up to 15.6 wt%). The SEM-EDS analyses found similar RPM in Manhattan Project-era radioactive wastes and indoor dusts in surrounding homes. Copyright © 2018 Elsevier Ltd. All rights reserved.

  18. Investigation of variable compositions on the removal of technetium from Hanford Waste Treatment Plant low activity waste melter off-gas condensate simulant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Taylor-Pashow, Kathryn M. L.; McCabe, Daniel J.; Pareizs, John M.

    The Low Activity Waste (LAW) vitrification facility at the Hanford Waste Treatment and Immobilization Plant (WTP) will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the offgas system. The plan for disposition of this stream during baseline operations is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. The primary reason to recycle this stream is so that the semi-volatile 99Tc isotope eventually becomes incorporated into the glass. This stream also contains non-radioactive salt components that are problematic in the melter,more » so diversion of this stream to another process would eliminate recycling of these salts and would enable simplified operation of the LAW melter and the Pretreatment Facilities. This diversion from recycling this stream within WTP would have the effect of decreasing the LAW vitrification mission duration and quantity of glass waste. The concept being tested here involves removing the 99Tc so that the decontaminated aqueous stream, with the problematic salts, can be disposed elsewhere.« less

  19. Special Analysis for the Disposal of the Materials and Energy Corporation Sealed Sources at the Area 5 Radioactive Waste Management Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shott, Gregory

    This special analysis (SA) evaluates whether the Materials and Energy Corporation (M&EC) Sealed Source waste stream (PERM000000036, Revision 0) is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the M&EC Sealed Source waste meets all U.S. Department of Energy (DOE) Manual DOE M 435.1-1, “Radioactive Waste Management Manual,” Chapter IV, Section P performance objectives (DOE 1999). The M&EC Sealed Source waste stream is recommended for acceptance without conditions.

  20. Vitrification of radioactive high-level waste by spray calcination and in-can melting

    NASA Astrophysics Data System (ADS)

    Hanson, M. S.; Bjorklund, W. J.

    1980-07-01

    After several nonradioactive test runs, radioactive waste from the processing of 1.5 t of spent, light water reactor fuel was successfully concentrated, dried and converted to a vitreous product. A total of 97 L of waste glass (in two stainless steel canisters) was produced. The spray calcination process coupled to the in-can melting process, as developed at Pacific Northwest Labortory, was used to vitrify the waste. An effluent system consisting of a variety of condensation of scrubbing steps more than adequately decontaminated the process off gas before it was released to the atmosphere.

  1. Marine disposal of radioactive wastes

    NASA Astrophysics Data System (ADS)

    Woodhead, D. S.

    1980-03-01

    In a general sense, the main attraction of the marine environment as a repository for the wastes generated by human activities lies in the degree of dispersion and dilution which is readily attainable. However, the capacity of the oceans to receive wastes without unacceptable consequences is clearly finite and this is even more true of localized marine environments such as estuaries, coastal waters and semi-enclosed seas. Radionuclides have always been present in the marine environment and marine organisms and humans consuming marine foodstuffs have always been exposed, to some degree, to radiation from this source. The hazard associated with ionizing radiations is dependent upon the absorption of energy from the radiation field within some biological entity. Thus any disposal of radioactive wastes into the marine environment has consequences, the acceptability of which must be assessed in terms of the possible resultant increase in radiation exposure of human and aquatic populations. In the United Kingdom the primary consideration has been and remains the safe-guarding of public health. The control procedures are therefore designed to minimize as far as practicable the degree of human exposure within the overall limits recommended as acceptable by the International Commission on Radiological Protection. There are several approaches through which control could be exercised and the strengths and weaknesses of each are considered. In this review the detailed application of the critical path technique to the control of the discharge into the north-east Irish Sea from the fuel reprocessing plant at Windscale is given as a practical example. It will be further demonstrated that when human exposure is controlled in this way no significant risk attaches to the increased radiation exposure experienced by populations of marine organisms in the area.

  2. Technical Basis for the Removal of Unremediated Nitrate Salt Sampling (UNS) to Support LANL Treatment Studies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Funk, David John

    2016-05-05

    The sampling of unremediated nitrate salts (UNS) was originally proposed by the U.S. Department of Energy (DOE) and Los Alamos National Security, LLC (LANS) (collectively, the Permittees) as a means to ensure adequate understanding and characterization of the problematic waste stream created when the Permittees remediated these nitrate salts-bearing waste with an organic absorbent. The proposal to sample the UNS was driven by a lack of understanding with respect to the radioactive contamination release that occurred within the underground repository at the Waste Isolation Pilot Plant (WIPP) in February 14, 2014, as well as recommendations made by a Peer Reviewmore » Team. As discussed, the Permittees believe that current knowledge and understanding of the waste has sufficiently matured such that this additional sampling is not required. Perhaps more importantly, the risk of both chemical and radiological exposure to the workers sampling the UNS drum material is unwarranted. This memo provides the technical justification and rationale for excluding the UNS sampling from the treatment studies.« less

  3. Water, vapour and heat transport in concrete cells for storing radioactive waste

    NASA Astrophysics Data System (ADS)

    Carme Chaparro, M.; W. Saaltink, Maarten

    2016-08-01

    Water is collected from a drain situated at the centre of a concrete cell that stores radioactive waste at 'El Cabril', which is the low and intermediate level radioactive waste disposal facility of Spain. This indicates flow of water within the cell. 2D numerical models have been made in order to reproduce and understand the processes that take place inside the cell. Temperature and relative humidity measured by sensors in the cells and thermo-hydraulic parameters from laboratory test have been used. Results show that this phenomenon is caused by capillary rise from the phreatic level, evaporation and condensation within the cell produced by temperature gradients caused by seasonal temperature fluctuations outside. At the centre of the cell, flow of gas and convection also play a role. Three remedial actions have been studied that may avoid the leakage of water from the drain.

  4. From cerebral salt wasting to diabetes insipidus with adipsia: case report of a child with craniopharyngioma.

    PubMed

    Raghunathan, Veena; Dhaliwal, Maninder Singh; Gupta, Aditya; Jevalikar, Ganesh

    2015-03-01

    Craniopharyngioma is associated with a wide and interesting variety of sodium states both by itself and following surgical resection. These are often challenging to diagnose, especially given their dynamic nature during the perioperative course. We present the case of a boy with craniopharyngioma who had hyponatremia due to cerebral salt wasting preoperatively, developed diabetes insipidus (DI) intraoperatively and proceeded to develop hypernatremia with adipsic DI. Cerebral salt wasting is a rare presenting feature of craniopharyngioma. Postoperative DI can be associated with thirst abnormalities including adipsia due to hypothalamic damage; careful monitoring and a high index of suspicion are required for its detection. Adipsic DI is a difficult condition to manage; hence a conservative surgical approach is suggested.

  5. Prostaglandin-E2 Mediated Increase in Calcium and Phosphate Excretion in a Mouse Model of Distal Nephron Salt Wasting

    PubMed Central

    Soleimani, Manoocher; Barone, Sharon; Xu, Jie; Alshahrani, Saeed; Brooks, Marybeth; McCormack, Francis X.; Smith, Roger D.; Zahedi, Kamyar

    2016-01-01

    Contribution of salt wasting and volume depletion to the pathogenesis of hypercalciuria and hyperphosphaturia is poorly understood. Pendrin/NCC double KO (pendrin/NCC-dKO) mice display severe salt wasting under basal conditions and develop profound volume depletion, prerenal renal failure, and metabolic alkalosis and are growth retarded. Microscopic examination of the kidneys of pendrin/NCC-dKO mice revealed the presence of calcium phosphate deposits in the medullary collecting ducts, along with increased urinary calcium and phosphate excretion. Confirmatory studies revealed decreases in the expression levels of sodium phosphate transporter-2 isoforms a and c, increases in the expression of cytochrome p450 family 4a isotypes 12 a and b, as well as prostaglandin E synthase 1, and cyclooxygenases 1 and 2. Pendrin/NCC-dKO animals also had a significant increase in urinary prostaglandin E2 (PGE-2) and renal content of 20-hydroxyeicosatetraenoic acid (20-HETE) levels. Pendrin/NCC-dKO animals exhibit reduced expression levels of the sodium/potassium/2chloride co-transporter 2 (NKCC2) in their medullary thick ascending limb. Further assessment of the renal expression of NKCC2 isoforms by quantitative real time PCR (qRT-PCR) reveled that compared to WT mice, the expression of NKCC2 isotype F was significantly reduced in pendrin/NCC-dKO mice. Provision of a high salt diet to rectify volume depletion or inhibition of PGE-2 synthesis by indomethacin, but not inhibition of 20-HETE generation by HET0016, significantly improved hypercalciuria and salt wasting in pendrin/NCC dKO mice. Both high salt diet and indomethacin treatment also corrected the alterations in NKCC2 isotype expression in pendrin/NCC-dKO mice. We propose that severe salt wasting and volume depletion, irrespective of the primary originating nephron segment, can secondarily impair the reabsorption of salt and calcium in the thick ascending limb of Henle and/or proximal tubule, and reabsorption of sodium and

  6. Rapid immobilization of simulated radioactive soil waste by microwave sintering.

    PubMed

    Zhang, Shuai; Shu, Xiaoyan; Chen, Shunzhang; Yang, Huimin; Hou, Chenxi; Mao, Xueli; Chi, Fangting; Song, Mianxin; Lu, Xirui

    2017-09-05

    A rapid and efficient method is particularly necessary in the timely disposal of seriously radioactive contaminated soil. In this paper, a series of simulated radioactive soil waste containing different contents of neodymium oxide (3-25wt.%) has been successfully vitrified by microwave sintering at 1300°C for 30min. The microstructures, morphology, element distribution, density and chemical durability of as obtained vitrified forms have been analyzed. The results show that the amorphous structure, homogeneous element distribution, and regular density improvement are well kept, except slight cracks emerge on the magnified surface for the 25wt.% Nd 2 O 3 -containing sample. Moreover, all the vitrified forms exhibit excellent chemical durability, and the leaching rates of Nd are kept as ∼10 -4 -10 -6 g/(m 2 day) within 42days. This demonstrates a potential application of microwave sintering in radioactive contaminated soil disposal. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. Modelling the sulfate capacity of simulated radioactive waste borosilicate glasses

    DOE PAGES

    Bingham, Paul A.; Vaishnav, Shuchi; Forder, Sue D.; ...

    2016-11-10

    In this paper, the capacity of simulated high-level radioactive waste borosilicate glasses to incorporate sulfate has been studied as a function of glass composition. Combined Raman, 57Fe Mössbauer and literature evidence supports the attribution of coordination numbers and oxidation states of constituent cations for the purposes of modelling, and results confirm the validity of correlating sulfate incorporation in multicomponent borosilicate radioactive waste glasses with different models. A strong compositional dependency is observed and this can be described by an inverse linear relationship between incorporated sulfate (mol% SO 4 2-) and total cation field strength index of the glass, Σ(z/a 2),more » with a high goodness-of-fit (R 2 ≈ 0.950). Similar relationships are also obtained if theoretical optical basicity, Λ th (R 2 ≈ 0.930) or non-bridging oxygen per tetrahedron ratio, NBO/T (R 2 ≈ 0.919), are used. Finally, results support the application of these models, and in particular Σ(z/a 2), as predictive tools to aid the development of new glass compositions with enhanced sulfate capacities.« less

  8. SEPARATION OF Cs$sup 137$ FROM HIGH-ACTIVITY RADIOACTIVE WASTE (in Dutch)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1963-01-01

    A process was developed on a laboratory scale to separate Cs/sup 137/ from waste fuels of atomic reactors. The recovery of this powerful and industrially important gamma emitter of 30 years half life is said to be so simple as to make it possible on an industrial scale. It is based on the preferential absorption of Cs by ammonium phosphor-molybdate from the nitric acid solution of the waste material and the subsequent extraction of Cs from its absorber. This method is more practical than other processes which are based upon precipitation and recrystallization of cesium salts. It was successfully testedmore » on waste solutions of very different compositions. (OID)« less

  9. Disposing of High-Level Radioactive Waste in Germany - A Note from the Licensing Authority - 12530

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pick, Thomas Stefan; Bluth, Joachim; Lauenstein, Christof

    Following the national German consensus on the termination of utilisation of nuclear energy in the summer of 2011, the Federal and Laender Governments have declared their intention to work together on a national consensus on the disposal of radioactive waste as well. Projected in the early 1970's the Federal Government had started exploring the possibility to establish a repository for HLW at the Gorleben site in 1977. However, there is still no repository available in Germany today. The delay results mainly from the national conflict over the suitability of the designated Gorleben site, considerably disrupting German society along the crevicemore » that runs between supporters and opponents of nuclear energy. The Gorleben salt dome is situated in Lower Saxony, the German state that also hosts the infamous Asse mine repository for LLW and ILW and the Konrad repository project designated to receive LLW and ILW as well. With the fourth German project, the Morsleben L/ILW repository only 20 km away across the state border, the state of Lower Saxony carries the main load for the disposal of radioactive waste in Germany. After more than 25 years of exploration and a 10 year moratorium the Gorleben project has now reached a cross-road. Current plans for setting up a new site selection procedure in Germany call for the selection and exploration of up to four alternative sites, depending only on suitable geology. In the meantime the discussion is still open on whether the Gorleben project should be terminated in order to pacify the societal conflict or being kept in the selection process on account of its promising geology. The Lower Saxony Ministry for Environment and Climate Protection proposes to follow a twelve-step-program for finding the appropriate site, including the Gorleben site in the process. With its long history of exploration the site is the benchmark that alternative sites will have to compare with. Following the national consensus of 2011 on the

  10. A new approach to characterize very-low-level radioactive waste produced at hadron accelerators.

    PubMed

    Zaffora, Biagio; Magistris, Matteo; Chevalier, Jean-Pierre; Luccioni, Catherine; Saporta, Gilbert; Ulrici, Luisa

    2017-04-01

    Radioactive waste is produced as a consequence of preventive and corrective maintenance during the operation of high-energy particle accelerators or associated dismantling campaigns. Their radiological characterization must be performed to ensure an appropriate disposal in the disposal facilities. The radiological characterization of waste includes the establishment of the list of produced radionuclides, called "radionuclide inventory", and the estimation of their activity. The present paper describes the process adopted at CERN to characterize very-low-level radioactive waste with a focus on activated metals. The characterization method consists of measuring and estimating the activity of produced radionuclides either by experimental methods or statistical and numerical approaches. We adapted the so-called Scaling Factor (SF) and Correlation Factor (CF) techniques to the needs of hadron accelerators, and applied them to very-low-level metallic waste produced at CERN. For each type of metal we calculated the radionuclide inventory and identified the radionuclides that most contribute to hazard factors. The methodology proposed is of general validity, can be extended to other activated materials and can be used for the characterization of waste produced in particle accelerators and research centres, where the activation mechanisms are comparable to the ones occurring at CERN. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Putting Radioactive Wastes on Ice: A Proposal for an International Radionuclide Depository in Antarctica

    ERIC Educational Resources Information Center

    Zeller, E. J.; And Others

    1973-01-01

    Describes need for creating permanent disposal of high-level radioactive wastes accumulating in different countries. Possibilities of establishing facilities for this purpose in Antarctic ice cap are examined. (PS)

  12. Perovskite-Ni composite: a potential route for management of radioactive metallic waste.

    PubMed

    Mahadik, Pooja Sawant; Sengupta, Pranesh; Halder, Rumu; Abraham, G; Dey, G K

    2015-04-28

    Management of nickel - based radioactive metallic wastes is a difficult issue. To arrest the release of hazardous material to the environment it is proposed to develop perovskite coating for the metallic wastes. Polycrystalline BaCe0.8Y0.2O3-δ perovskite with orthorhombic structure has been synthesized by sol-gel route. Crystallographic analyses show, the perovskite belong to orthorhombic Pmcn space group at room temperature, and gets converted to orthorhombic Incn space group at 623K, cubic Pm3m space group (with a=4.434Å) at 1173K and again orthorhombic Pmcn space group at room temperature after cooling. Similar observations have been made from micro-Raman study as well. Microstructural studies of BaCe0.8Y0.2O3-δ-NiO/Ni composites showed absence of any reaction product at the interface. This suggests that both the components (i.e. perovskite and NiO/Ni) of the composite are compatible to each other. Interaction of BaCe0.8Y0.2O3-δ-NiO/Ni composites with simulated barium borosilicate waste glass melt also did not reveal any reaction product at the interfaces. Importantly, uranium from the waste glass melt was found to be partitioned within BaCe0.8Y0.2O3-δ perovskite structure. It is therefore concluded that BaCe0.8Y0.2O3-δ can be considered as a good coating material for management of radioactive Ni based metallic wastes. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Effect of temperature on the durability of class C fly ash belite cement in simulated radioactive liquid waste: synergy of chloride and sulphate ions.

    PubMed

    Guerrero, A; Goñi, S; Allegro, V R

    2009-06-15

    The durability of class C fly ash belite cement (FABC-2-W) in simulated radioactive liquid waste (SRLW) rich in a mixed sodium chloride and sulphate solution is presented here. The effect of the temperature and potential synergic effect of chloride and sulfate ions are discussed. This study has been carried out according to the Koch-Steinegger test, at the temperature of 20 degrees C and 40 degrees C during a period of 180 days. The durability has been evaluated by the changes of the flexural strength of mortar, fabricated with this cement, immersed in a simulated radioactive liquid waste rich in sulfate (0.5M), chloride (0.5M) and sodium (1.5M) ions--catalogued like severely aggressive for the traditional Portland cement--and demineralised water, which was used as reference. The reaction mechanism of sulphate, chloride and sodium ions with the mortar was evaluated by scanning electron microscopy (SEM), porosity and pore-size distribution, and X-ray diffraction (XRD). The results showed that the chloride binding and formation of Friedel's salt was inhibited by the presence of sulphate. Sulphate ion reacts preferentially with the calcium aluminate hydrates forming non-expansive ettringite which precipitated inside the pores; the microstructure was refined and the mechanical properties enhanced. This process was faster and more marked at 40 degrees C.

  14. Conflicting Expertise and Uncertainty: Quality Assurance in High-Level Radioactive Waste Management.

    ERIC Educational Resources Information Center

    Fitzgerald, Michael R.; McCabe, Amy Snyder

    1991-01-01

    Dynamics of a large, expensive, and controversial surface and underground evaluation of a radioactive waste management program at the Yucca Mountain power plant are reviewed. The use of private contractors in the quality assurance study complicates the evaluation. This case study illustrates high stakes evaluation problems. (SLD)

  15. Site characterization for LIL radioactive waste disposal in Romania

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Diaconu, D. R.; Birdsell, K. H.; Witkowski, M. S.

    2001-01-01

    Recent studies in radioactive waste management in Romania have focussed mainly on the disposal of low and intermediate level waste from the operation of the new nuclear power plant at Cernavoda. Following extensive geological, hydrological, seismological, physical and chemical investigations, a disposal site at Saligny has been selected. This paper presents description of the site at Saligny as well as the most important results of the site characterisation. These are reflected in the three-dimensional, stratigraphical representation of the loess and clay layers and in representative parameter values for the main layers. Based on these data, the simulation of the background,more » unsaturated-zone water flow at the Saligny site, calculated by the FEHM code, is in a good agreement with the measured moisture profile.« less

  16. Double knockout of pendrin and Na-Cl cotransporter (NCC) causes severe salt wasting, volume depletion, and renal failure.

    PubMed

    Soleimani, Manoocher; Barone, Sharon; Xu, Jie; Shull, Gary E; Siddiqui, Faraz; Zahedi, Kamyar; Amlal, Hassane

    2012-08-14

    The Na-Cl cotransporter (NCC), which is the target of inhibition by thiazides, is located in close proximity to the chloride-absorbing transporter pendrin in the kidney distal nephron. Single deletion of pendrin or NCC does not cause salt wasting or excessive diuresis under basal conditions, raising the possibility that these transporters are predominantly active during salt depletion or in response to excess aldosterone. We hypothesized that pendrin and NCC compensate for loss of function of the other under basal conditions, thereby masking the role that each plays in salt absorption. To test our hypothesis, we generated pendrin/NCC double knockout (KO) mice by crossing pendrin KO mice with NCC KO mice. Pendrin/NCC double KO mice displayed severe salt wasting and sharp increase in urine output under basal conditions. As a result, animals developed profound volume depletion, renal failure, and metabolic alkalosis without hypokalemia, which were all corrected with salt replacement. We propose that the combined inhibition of pendrin and NCC can provide a strong diuretic regimen without causing hypokalemia for patients with fluid overload, including patients with congestive heart failure, nephrotic syndrome, diuretic resistance, or generalized edema.

  17. Double knockout of pendrin and Na-Cl cotransporter (NCC) causes severe salt wasting, volume depletion, and renal failure

    PubMed Central

    Soleimani, Manoocher; Barone, Sharon; Xu, Jie; Shull, Gary E.; Siddiqui, Faraz; Zahedi, Kamyar; Amlal, Hassane

    2012-01-01

    The Na-Cl cotransporter (NCC), which is the target of inhibition by thiazides, is located in close proximity to the chloride-absorbing transporter pendrin in the kidney distal nephron. Single deletion of pendrin or NCC does not cause salt wasting or excessive diuresis under basal conditions, raising the possibility that these transporters are predominantly active during salt depletion or in response to excess aldosterone. We hypothesized that pendrin and NCC compensate for loss of function of the other under basal conditions, thereby masking the role that each plays in salt absorption. To test our hypothesis, we generated pendrin/NCC double knockout (KO) mice by crossing pendrin KO mice with NCC KO mice. Pendrin/NCC double KO mice displayed severe salt wasting and sharp increase in urine output under basal conditions. As a result, animals developed profound volume depletion, renal failure, and metabolic alkalosis without hypokalemia, which were all corrected with salt replacement. We propose that the combined inhibition of pendrin and NCC can provide a strong diuretic regimen without causing hypokalemia for patients with fluid overload, including patients with congestive heart failure, nephrotic syndrome, diuretic resistance, or generalized edema. PMID:22847418

  18. Inhibiting localized corrosion during storage of dilute SRP wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Oblath, S.B.; Congdon, J.W.

    1986-01-01

    High-level radioactive waste will be incorporated in borosilicate glass in the Defense Waste Processing Facility (DWPF) at the Savannah River Plant (SRP). As part of this process, large volumes of inorganic salt wastes will be decontaminated for disposal as low-level waste. The principal contaminants, /sup 137/Cs and /sup 90/Sr, are removed by treatment with sodium tetraphenylborate and sodium titanate. The resulting solids will be slurried with a dilute salt solution and stored in existing carbon steel tanks for several years prior to processing and disposal. Initial tests indicated a tendency for localized corrosion of the tanks. An investigation, using nonradioactivemore » simulants for the expected solution compositions, identified inhibitors which would protect the steel. Changes in solution compositions over time, due to radiolytic effects, were also accounted for by the simulants. Six inhibitors were identified which would protect the steel tanks. The effects these inhibitors would have on later processing steps in the DWPF were then evaluated. After this process, only sodium nitrite remained as an inhibitor that was both effective and compatible with the DWPF. The use of this inhibitor has been demonstrated on a real waste slurry.« less

  19. Ion exchangers in radioactive waste management: natural Iranian zeolites.

    PubMed

    Nilchi, A; Maalek, B; Khanchi, A; Ghanadi Maragheh, M; Bagheri, A; Savoji, K

    2006-01-01

    Five samples of natural zeolites from different parts of Iran were chosen for this study. In order to characterize and determine their structures, X-ray diffraction and infrared spectrometry were carried out for each sample. The selective absorption properties of each zeolite were found by calculating the distribution coefficient (K(d)) of various simulated wastes which were prepared by spiking the radionuclides with (131)I, (99)Mo, (153)Sm, (140)La and (147)Nd. All the zeolite samples used in this study had extremely high absorption value towards (140)La; clinoptolite from Mianeh and analsite from Ghalehkhargoshi showed good absorption for (147)Nd; clinoptolite from Semnan and clinoptolite from Firozkoh showed high absorption for (153)Sm; mesolite from Arababad Tabas showed good absorption for (99)Mo; and finally mesolite from Arababad Tabas, clinoptolite from Semnan and clinoptolite from Firozkoh could be used to selectively absorb (131)I from the stimulated waste which was prepared. The natural zeolites chosen for these studies show a similar pattern to those synthetic ion exchangers in the literature and in some cases an extremely high selectivity towards certain radioactive elements. Hence the binary separation of radioactive elements could easily be carried out. Furthermore, these zeolites, which are naturally occurring ion exchangers, are viable economically and extremely useful alternatives in this industry.

  20. Treatment of Radioactive Metallic Waste from Operation of Nuclear Power Plants by Melting - The German Way for a Consistent Recycling to Minimize the Quantity of Radioactive Waste from Operation and Dismantling for Disposal - 12016

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wegener, Dirk; Kluth, Thomas

    2012-07-01

    During maintenance of nuclear power plants, and during their decommissioning period, a large quantity of radioactive metallic waste will accrue. On the other hand the capacity for final disposal of radioactive waste in Germany is limited as well as that in the US. That is why all procedures related to this topic should be handled with a maximum of efficiency. The German model of consistent recycling of the radioactive metal scrap within the nuclear industry therefore also offers high capabilities for facilities in the US. The paper gives a compact overview of the impressive results of melting treatment, the currentmore » potential and further developments. Thousands of cubic metres of final disposal capacity have been saved. The highest level of efficiency and safety by combining general surface decontamination by blasting and nuclide specific decontamination by melting associated with the typical effects of homogenization. An established process - nationally and internationally recognized. Excellent connection between economy and ecology. (authors)« less

  1. Species removal from aqueous radioactive waste by deep-bed filtration.

    PubMed

    Dobre, Tănase; Zicman, Laura Ruxandra; Pârvulescu, Oana Cristina; Neacşu, Elena; Ciobanu, Cătălin; Drăgolici, Felicia Nicoleta

    2018-05-26

    Performances of aqueous suspension treatment by deep-bed sand filtration were experimentally studied and simulated. A semiempirical deterministic model and a stochastic model were used to predict the removal of clay particles (20 μm) from diluted suspensions. Model parameters, which were fitted based on experimental data, were linked by multiple linear correlations to the process factors, i.e., sand grain size (0.5 and 0.8 mm), bed depth (0.2 and 0.4 m), clay concentration in the feed suspension (1 and 2 kg p /m 3 ), suspension superficial velocity (0.015 and 0.020 m/s), and operating temperature (25 and 45 °C). These relationships were used to predict the bed radioactivity determined by the deposition of radioactive suspended particles (>50 nm) from low and medium level aqueous radioactive waste. A deterministic model based on mass balance, kinetic, and interface equilibrium equations was developed to predict the multicomponent sorption of 60 Co, 137 Cs, 241 Am, and 3 H radionuclides (0.1-0.3 nm). A removal of 98.7% of radioactive particles was attained by filtering a radioactive wastewater volume of 10 m 3 (0.5 mm sand grain size, 0.3 m bed depth, 0.223 kg p /m 3 suspended solid concentration in the feed suspension, 0.003 m/s suspension superficial velocity, and 25 °C operating temperature). Predicted results revealed that the bed radioactivity determined by the sorption of radionuclides (0.01 kBq/kg b ) was significantly lower than the bed radioactivities caused by the deposition of radioactive particles (0.5-1.8 kBq/kg b ). Copyright © 2018 Elsevier Ltd. All rights reserved.

  2. Technical and design update in the AUBE French low-level radioactive waste disposal facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Marque, Y.

    1989-01-01

    Long-term industrial management of radioactive waste in France is carried out by the Agence Nationale pour la Gestion des Dechets Radioactifs (ANDRA). ANDRA is in charge of design, siting, construction, and operation of disposal centers. The solution selected in France for the disposal of low- and medium-level, short-lived radioactive waste is near-surface disposal in the earth using the principle of multiple barriers, in accordance with national safety rules and regulations, and based on operating experience from the Centre de Stockage de la Manche. Since the center's start-up in 1969, 400,000 m{sup 3} of waste have been disposed of. The Frenchmore » national program for waste management is proceeding with the construction of a second near-surface disposal, which is expected to be operational in 1991. It is located in the department of AUBE (from which its name derives), 100 miles southeast of Paris. The paper describes the criteria for siting and design of the AUBE disposal facility, design of the AUBE facility disposal module, and comparison with North Carolina and Pennsylvania disposal facility designs.« less

  3. Characteristics and Classification of Solid Radioactive Waste From the Front-End of the Uranium Fuel Cycle.

    PubMed

    Liu, Xinhua; Wei, Fangxin; Xu, Chunyan; Liao, Yunxuan; Jiang, Jing

    2015-09-01

    The proper classification of radioactive waste is the basis upon which to define its disposal method. In view of differences between waste containing artificial radionuclides and waste with naturally occurring radionuclides, the scientific definition of the properties of waste arising from the front end of the uranium fuel cycle (UF Waste) is the key to dispose of such waste. This paper is intended to introduce briefly the policy and practice to dispose of such waste in China and some foreign countries, explore how to solve the dilemma facing such waste, analyze in detail the compositions and properties of such waste, and finally put forward a new concept of classifying such waste as waste with naturally occurring radionuclides.

  4. Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel

    DOEpatents

    Herrmann, Steven Douglas

    2014-05-27

    Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

  5. The radioactivity estimation of 14C and 3H in graphite waste samples of the KRR-2.

    PubMed

    Reyoung Kim, Hee

    2013-09-01

    The radioactivity of (14)C and (3)H in graphite samples from the dismantled Korea Research Reactor-2 (the KRR-2) site was analyzed by high-temperature oxidation and liquid scintillation counting, and the graphite waste was suggested to be disposed of as a low-level radioactive waste. The graphite samples were oxidized at a high temperature of 800 °C, and their counting rates were measured by using a liquid scintillation counter (LSC). The combustion ratio of the graphite was about 99% on the sample with a maximum weight of 1g. The recoveries from the combustion furnace were around 100% and 90% in (14)C and (3)H, respectively. The minimum detectable activity was 0.04-0.05 Bq/g for the (14)C and 0.13-0.15 Bq/g for the (3)H at the same background counting time. The activity of (14)C was higher than that of (3)H over all samples with the activity ratios of the (14)C to (3)H, (14)C/(3)H, being between 2.8 and 25. The dose calculation was carried out from its radioactivity analysis results. The dose estimation gave a higher annual dose than the domestic legal limit for a clearance. It was thought that the sampled graphite waste from the dismantled research reactor was not available for reuse or recycling and should be monitored as low-level radioactive waste. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1983, 1984, and 1985

    USGS Publications Warehouse

    Dinwiddie, G.A.; Trask, N.J.

    1986-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research is described according to whether it is related most directly to: (1) high-level and transuranic wastes, (2) low-level wastes, or (3) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, and to studies of regions or environments where waste-disposal sites might be located. A significant part of the activity is concerned with techniques and methods for characterizing disposal sites and studies of geologic and hydrologic processes related to the transport and (or) retention of waste radionuclides.

  7. On-line remote monitoring of radioactive waste repositories

    NASA Astrophysics Data System (ADS)

    Calì, Claudio; Cosentino, Luigi; Litrico, Pietro; Pappalardo, Alfio; Scirè, Carlotta; Scirè, Sergio; Vecchio, Gianfranco; Finocchiaro, Paolo; Alfieri, Severino; Mariani, Annamaria

    2014-12-01

    A low-cost array of modular sensors for online monitoring of radioactive waste was developed at INFN-LNS. We implemented a new kind of gamma counter, based on Silicon PhotoMultipliers and scintillating fibers, that behaves like a cheap scintillating Geiger-Muller counter. It can be placed in shape of a fine grid around each single waste drum in a repository. Front-end electronics and an FPGA-based counting system were developed to handle the field data, also implementing data transmission, a graphical user interface and a data storage system. A test of four sensors in a real radwaste storage site was performed with promising results. Following the tests an agreement was signed between INFN and Sogin for the joint development and installation of a prototype DMNR (Detector Mesh for Nuclear Repository) system inside the Garigliano radwaste repository in Sessa Aurunca (CE, Italy). Such a development is currently under way, with the installation foreseen within 2014.

  8. Uncertainty analysis of the radiological characteristics of radioactive waste using a method based on log-normal distributions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gigase, Yves

    2007-07-01

    Available in abstract form only. Full text of publication follows: The uncertainty on characteristics of radioactive LILW waste packages is difficult to determine and often very large. This results from a lack of knowledge of the constitution of the waste package and of the composition of the radioactive sources inside. To calculate a quantitative estimate of the uncertainty on a characteristic of a waste package one has to combine these various uncertainties. This paper discusses an approach to this problem, based on the use of the log-normal distribution, which is both elegant and easy to use. It can provide asmore » example quantitative estimates of uncertainty intervals that 'make sense'. The purpose is to develop a pragmatic approach that can be integrated into existing characterization methods. In this paper we show how our method can be applied to the scaling factor method. We also explain how it can be used when estimating other more complex characteristics such as the total uncertainty of a collection of waste packages. This method could have applications in radioactive waste management, more in particular in those decision processes where the uncertainty on the amount of activity is considered to be important such as in probability risk assessment or the definition of criteria for acceptance or categorization. (author)« less

  9. Amounts and activity concentrations of radioactive wastes from the cleanup of large areas contaminated in nuclear accidents

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lehto, J.; Ikaeheimonen, T.K.; Salbu, B.

    The fallout from a major nuclear accident at a nuclear plant may result in a wide-scale contamination of the environment. Cleanup of contaminated areas is of special importance if these areas are populated or cultivated. All cleanup measures generate high amounts of radioactive waste, which have to be treated and disposed of in a safe manner. Scenarios assessing the amounts and activity concentrations of radioactive wastes for various cleanup measures after severe nuclear accidents have been worked out for urban, forest and agricultural areas. These scenarios are based on contamination levels and ares of contaminated lands from a model accident,more » which simulates a worst case accident at a nuclear power plant. Amounts and activity concentrations of cleanup wastes are not only dependent on the contamination levels and areas of affected lands, but also on the type of deposition, wet or dry, on the time between the deposition and the cleanup work, on the season, at which the deposition took place, and finally on the level of cleanup work. In this study practically all types of cleanup wastes were considered, whether or not the corresponding cleanup measures are cost-effective or justified. All cleanup measures are shown to create large amounts of radioactive wastes, but the amounts, as well as the activity concentrations vary widely from case to case.« less

  10. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOEpatents

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1--6 mole % iron (III) oxide, from about 1--6 mole % aluminum oxide, from about 15--20 mole % sodium oxide or potassium oxide, and from about 30--60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3--6 mole % sodium oxide, from about 20--50 mole % tin oxide, from about 30--70 mole % phosphate, from about 3--6 mole % aluminum oxide, from about 3--8 mole % silicon oxide, from about 0.5--2 mole % iron (III) oxide and from about 3--6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  11. Decision Support System For Management Of Low-Level Radioactive Waste Disposal At The Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shott, G.; Yucel, V.; Desotell, L.

    2006-07-01

    The long-term safety of U.S. Department of Energy (DOE) low-level radioactive disposal facilities is assessed by conducting a performance assessment -- a systematic analysis that compares estimated risks to the public and the environment with performance objectives contained in DOE Manual 435.1-1, Radioactive Waste Management Manual. Before site operations, facilities design features such as final inventory, waste form characteristics, and closure cover design may be uncertain. Site operators need a modeling tool that can be used throughout the operational life of the disposal site to guide decisions regarding the acceptance of problematic waste streams, new disposal cell design, environmental monitoringmore » program design, and final site closure. In response to these needs the National Nuclear Security Administration Nevada Site Office (NNSA/NSO) has developed a decision support system for the Area 5 Radioactive Waste Management Site in Frenchman Flat on the Nevada Test Site. The core of the system is a probabilistic inventory and performance assessment model implemented in the GoldSim{sup R} simulation platform. The modeling platform supports multiple graphic capabilities that allow clear documentation of the model data sources, conceptual model, mathematical implementation, and results. The combined models have the capability to estimate disposal site inventory, contaminant concentrations in environmental media, and radiological doses to members of the public engaged in various activities at multiple locations. The model allows rapid assessment and documentation of the consequences of waste management decisions using the most current site characterization information, radionuclide inventory, and conceptual model. The model is routinely used to provide annual updates of site performance, evaluate the consequences of disposal of new waste streams, develop waste concentration limits, optimize the design of new disposal cells, and assess the adequacy of

  12. A Characteristics-Based Approach to Radioactive Waste Classification in Advanced Nuclear Fuel Cycles

    NASA Astrophysics Data System (ADS)

    Djokic, Denia

    The radioactive waste classification system currently used in the United States primarily relies on a source-based framework. This has lead to numerous issues, such as wastes that are not categorized by their intrinsic risk, or wastes that do not fall under a category within the framework and therefore are without a legal imperative for responsible management. Furthermore, in the possible case that advanced fuel cycles were to be deployed in the United States, the shortcomings of the source-based classification system would be exacerbated: advanced fuel cycles implement processes such as the separation of used nuclear fuel, which introduce new waste streams of varying characteristics. To be able to manage and dispose of these potential new wastes properly, development of a classification system that would assign appropriate level of management to each type of waste based on its physical properties is imperative. This dissertation explores how characteristics from wastes generated from potential future nuclear fuel cycles could be coupled with a characteristics-based classification framework. A static mass flow model developed under the Department of Energy's Fuel Cycle Research & Development program, called the Fuel-cycle Integration and Tradeoffs (FIT) model, was used to calculate the composition of waste streams resulting from different nuclear fuel cycle choices: two modified open fuel cycle cases (recycle in MOX reactor) and two different continuous-recycle fast reactor recycle cases (oxide and metal fuel fast reactors). This analysis focuses on the impact of waste heat load on waste classification practices, although future work could involve coupling waste heat load with metrics of radiotoxicity and longevity. The value of separation of heat-generating fission products and actinides in different fuel cycles and how it could inform long- and short-term disposal management is discussed. It is shown that the benefits of reducing the short-term fission

  13. Radiation resistant concrete for applications in nuclear power and radioactive waste industries

    NASA Astrophysics Data System (ADS)

    Burnham, Steven Robert

    Elemental components of ordinary concrete contain a variety of metals and rare earth elements that are susceptible to neutron activation. This activation occurs by means of radiative capture, a neutron interaction that results in formation of radioisotopes such as Co-60, Eu-152, and Eu-154. Studies have shown that these three radioisotopes are responsible for the residual radioactivity found in nuclear power plant concrete reactor dome and shielding walls. Such concrete is classified as Low Level Radioactive Waste (LLRW) and Very Low Level Waste (VLLW) by International Atomic Energy Agency (IAEA) standards and requires disposal at appropriate disposal sites. There are only three such sites in the USA, and every nuclear power plant will produce at the time of decommissioning approximately 1,500 tonnes of activated concrete classified as LLRW and VLLW. NAVA ALIGA (ancient word for a new stone) is a new concrete mixture developed mainly by research as presented in this thesis. The purpose of NAVA ALIGA is to satisfy IAEA clearance levels if used as a material for reactor dome, spent fuel pool, or radioactive waste canisters. NAVA ALIGA will never be activated above the IAEA clearance level after long-term exposure to neutron radiation when used as a material for reactor dome, spent fuel pool, and radioactive waste canisters. Components of NAVA ALIGA were identified using Instrumental Neutron Activation Analysis (INAA) and Inductively Coupled Plasma Mass Spectrometry (ISP-MS) to determine trace element composition. In addition, it was tested for compressive strength and permeability, important for nuclear infrastructure. The studied mixture had a high water to cement ratio of 0.56, which likely resulted in the high measured permeability, yet the mixture also showed a compressive strength greater than 6 000 psi after 28 days. In addition to this experimental analysis, which goal was to develop a standard approach to define the concrete mixtures in satisfying the IAEA

  14. Special Analysis of Transuranic Waste in Trench T04C at the Area 5 Radioactive Waste Management Site, Nevada Test Site, Nye County, Nevada, Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Greg Shott, Vefa Yucel, Lloyd Desotell

    2008-05-01

    This Special Analysis (SA) was prepared to assess the potential impact of inadvertent disposal of a limited quantity of transuranic (TRU) waste in classified Trench 4 (T04C) within the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS). The Area 5 RWMS is a low-level radioactive waste disposal site in northern Frenchman Flat on the Nevada Test Site (NTS). The Area 5 RWMS is regulated by the U.S. Department of Energy (DOE) under DOE Order 435.1 and DOE Manual (DOE M) 435.1-1. The primary objective of the SA is to evaluate if inadvertent disposal of limitedmore » quantities of TRU waste in a shallow land burial trench at the Area 5 RWMS is in compliance with the existing, approved Disposal Authorization Statement (DAS) issued under DOE M 435.1-1. In addition, supplemental analyses are performed to determine if there is reasonable assurance that the requirements of Title 40, Code of Federal Regulations (CFR), Part 191, Environmental Radiation Protection Standards for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes, can be met. The 40 CFR 191 analyses provide supplemental information regarding the risk to human health and the environment of leaving the TRU waste in T04C. In 1989, waste management personnel reviewing classified materials records discovered that classified materials buried in trench T04C at the Area 5 RWMS contained TRU waste. Subsequent investigations determined that a total of 102 55-gallon drums of TRU waste from Rocky Flats were buried in trench T04C in 1986. The disposal was inadvertent because unclassified records accompanying the shipment indicated that the waste was low-level. The exact location of the TRU waste in T04C was not recorded and is currently unknown. Under DOE M 435.1-1, Chapter IV, Section P.5, low-level waste disposal facilities must obtain a DAS. The DAS specifies conditions that must be met to operate within the radioactive waste management basis

  15. 76 FR 10810 - Public Workshop to Discuss Low-Level Radioactive Waste Management

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-28

    ... the environment. Development of the part 61 regulation in the early 1980s was based on several... there have been a number of developments that have called into question some of the key assumptions...-level radioactive wastes that did not exist at the time part 61 was promulgated. The developments...

  16. Geological problems in radioactive waste isolation - A world wide review

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Witherspoon, P.A.

    1991-06-01

    The problem of isolating radioactive wastes from the biosphere presents specialists in the earth sciences with some of the most complicated problems they have ever encountered. This is especially true for high-level waste (HLW), which must be isolated in the underground and away from the biosphere for thousands of years. The most widely accepted method of doing this is to seal the radioactive materials in metal canisters that are enclosed by a protective sheath and placed underground in a repository that has been carefully constructed in an appropriate rock formation. Much new technology is being developed to solve the problemsmore » that have been raised, and there is a continuing need to publish the results of new developments for the benefit of all concerned. Table 1 presents a summary of the various formations under investigation according to the reports submitted for this world wide review. It can be seen that in those countries that are searching for repository sites, granitic and metamorphic rocks are the prevalent rock type under investigation. Six countries have developed underground research facilities that are currently in use. All of these investigations are in saturated systems below the water table, except the United States project, which is in the unsaturated zone of a fractured tuff.« less

  17. Geologic and hydrologic considerations for various concepts of high-level radioactive waste disposal in conterminous United States

    USGS Publications Warehouse

    Ekren, E.B.; Dinwiddie, G.A.; Mytton, J.W.; Thordarson, William; Weir, J.E.; Hinrichs, E.N.; Schroder, L.J.

    1974-01-01

    The purpose of this investigation is to evaluate and identify which geohydrologic environments in conterminous United States are best suited for various concepts or methods of underground disposal of high-level radioactive wastes and to establish geologic and hydrologic criteria that are pertinent to high-level waste disposal. The unproven methods of disposal include (1) a very deep drill hole (30,000-50,000 ft or 9,140-15,240 m), (2) a matrix of (an array of multiple) drill holes (1,000-20,000 ft or 305-6,100 m), (3) a mined chamber (1,000-10,000 ft or 305-3,050 m), (4) a cavity with separate manmade structures (1,000-10,000 ft or 305-3,050 m), and (5) an exploded cavity (2,000-20,000 ft or 610-6,100 m) o The geohydrologic investigation is made on the presumption that the concepts or methods of disposal are technically feasible. Field and laboratory experiments in the future may demonstrate whether or not any of the methods are practical and safe. All the conclusions drawn are tentative pending experimental confirmation. The investigation focuses principally on the geohydrologic possibilities of several methods of disposal in rocks other than salt. Disposal in mined chambers in salt is currently under field investigation, and this disposal method has been intensely investigated and evaluated by various workers under the sponsorship of the Atomic Energy Commission. Of the various geohydrologic factors that must be considered in the selection of optimum waste-disposal sites, the most important is hydrologic isolation to assure that the wastes will be safely contained within a small radius of the emplacement zone. To achieve this degree of hydrologic isolation, the host rock for the wastes must have very low permeability and the site must be virtually free of faults. In addition, the locality should be in (1) an area of low seismic risk where the possibility of large earthquakes rupturing the emplacement zone is very low, (2) where the possibility- of flooding by

  18. Final report on decommissioning of wells, boreholes, and tiltmeter sites, Gulf Coast Interior Salt Domes of Louisiana

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1989-07-01

    In the late 1970s, test holes were drilled in northern Louisiana in the vicinity of Vacherie and Rayburn`s Salt Domes as part of the Department of Energy`s (DOE) National Waste Terminal Storage (NWTS) (rename the Civilian Radioactive Waste Management (CRWM)) program. The purpose of the program was to evaluate the suitability of salt domes for long term storage or disposal of high-level nuclear waste. The Institute for Environmental Studies at Louisiana State University (IES/LSU) and Law Engineering Testing Company (LETCo) of Marietta, Georgia performed the initial field studies. In 1982, DOE awarded a contract to the Earth Technology Corporation (TETC)more » of Long Beach, California to continue the Gulf Coast Salt Dome studies. In 1986, DOE deferred salt domes from further consideration as repository sites. This report describes test well plugging and site abandonment activities performed by SWEC in accordance with Activity Plan (AP) 1--3, Well Plugging and Site Restoration of Work Sites in Louisiana. The objective of the work outlined in this AP was to return test sites to as near original condition as possible by plugging boreholes, removing equipment, regrading, and seeding. Appendices to this report contain forms required by State of Louisiana, used by SWEC to document decommissioning activities, and pertinent documentation related to lease/access agreements.« less

  19. PIC-container for containment and disposal of low and intermediate level radioactive wastes

    NASA Astrophysics Data System (ADS)

    Araki, K.; Shinji, Y.; Maki, Y.; Ishizaki, K.; Minegishi, K.; Sudoh, G.

    1981-03-01

    Steel fiber reinforced polymer impregnated concrete (SFPIC) was investigated for low and intermediate level radioactive waste containers. The 60 L and 200 L containers were designed as pressure container (without equalizer) for 500 kg/square cm and 700 kg/square cm. Polymerization of impregnated methylmethacrylate monomer was performed by 60 Co-gamma ray radiation and thermal catalytic polymerization respectively. Under the loading of 500 kg/square cm and 700 kg/square cm-outside hydraulic pressure, these containers were kept in their good condition. The observed maximum strains were about .001380 and .003950 at the outside central position of container body for circumferential direction of the 60 L and 200 L container, respectively. The containers were immersed in deionized water for 400 days, nuclides were not leached from the container. The SFPIC container was suitable for containment and disposal of low and intermediate level radioactive wastes.

  20. Multiple criteria approach to site selection of radioactive waste disposal facility in the Republic of Croatia

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schaller, A.; Skanata, D.

    1995-12-31

    Site selection approach to radioactive waste disposal facility, which is under way in Croatia, is presented in the paper. This approach is based on application of certain relevant terrestrial and technical criteria in the site selection process. Basic documentation used for this purpose are regional planning documents prepared by the Regional Planning Institute of Croatia. The basic result of research described in the paper is the proposal of several potential areas which are suitable for siting a radioactive waste repository. All relevant conclusions are based on both data groups -- generic and on-field experienced (measured). Out of a dozen potentialmore » areas, four have been chosen as representative by the authors. The presented comparative analysis was made by means of the VISA II computer code, developed by the V. Belton and SPV Software Products. The code was donated to the APO by the IAEA. The main objective of the paper is to initiate and facilitate further discussions on possible ways of evaluation and comparison of potential areas for sitting of radioactive waste repository in this country, as well as to provide additional contributions to the current site selection process in the Republic of Croatia.« less

  1. The analysis of the program to develop the Nuclear Waste Management System: Allocated requirements for the Office of Civilian Radioactive Waste Management Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Woods, T.W.

    1991-09-01

    This report is volume 3, part B, of the program to satisfy the allocated requirements of the Office of Civilian Radioactive Waste Management Program, in the development of the nuclear waste management system. The report is divided into the following sections: regulatory compliance; external relations; international programs; strategic and contingency planning; contract business management; and administrative services. (CS)

  2. Novel use of geochemical models in evaluating treatment trains for aqueous radioactive waste streams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Abitz, R.J.

    1996-12-31

    Thermodynamic geochemical models have been applied to assess the relative effectiveness of a variety of reagents added to aqueous waste streams for the removal of radioactive elements. Two aqueous waste streams were examined: effluent derived from the processing of uranium ore and irradiated uranium fuel rods. Simulations of the treatment train were performed to estimate the mass of reagents needed per kilogram of solution, identify pH regions corresponding to solubility minimums, and predict the identity and quantity of precipitated solids. Results generated by the simulations include figures that chart the chemical evolution of the waste stream as reagents are addedmore » and summary tables that list mass balances for all reagents and radioactive elements of concern. Model results were used to set initial reagent levels for the treatment trains, minimizing the number of bench-scale tests required to bring the treatment train up to full-scale operation. Additionally, presentation of modeling results at public meetings helps to establish good faith between the federal government, industry, concerned citizens, and media groups. 18 refs., 3 figs., 1 tab.« less

  3. Modeling of the T S D E Heater Test to Investigate Crushed Salt Reconsolidation and Rock Salt Creep for the Underground Disposal of High-Level Nuclear Waste

    NASA Astrophysics Data System (ADS)

    Blanco Martin, L.; Rutqvist, J.; Birkholzer, J. T.; Wolters, R.; Lux, K. H.

    2014-12-01

    Rock salt is a potential medium for the underground disposal of nuclear waste because it has several assets, in particular its water and gas tightness in the undisturbed state, its ability to heal induced fractures and its high thermal conductivity as compared to other shallow-crustal rocks. In addition, the run-of-mine, granular salt, may be used to backfill the mined open spaces. We present simulation results associated with coupled thermal, hydraulic and mechanical processes in the TSDE (Thermal Simulation for Drift Emplacement) experiment, conducted in the Asse salt mine in Germany [1]. During this unique test, conceived to simulate reference repository conditions for spent nuclear fuel, a significant amount of data (temperature, stress changes and displacements, among others) was measured at 20 cross-sections, distributed in two drifts in which a total of six electrical heaters were emplaced. The drifts were subsequently backfilled with crushed salt. This test has been modeled in three-dimensions, using two sequential simulators for flow (mass and heat) and geomechanics, TOUGH-FLAC and FLAC-TOUGH [2]. These simulators have recently been updated to accommodate large strains and time-dependent rheology. The numerical predictions obtained by the two simulators are compared within the framework of an international benchmark exercise, and also with experimental data. Subsequently, a re-calibration of some parameters has been performed. Modeling coupled processes in saliniferous media for nuclear waste disposal is a novel approach, and in this study it has led to the determination of some creep parameters that are very difficult to assess at the laboratory-scale because they require extremely low strain rates. Moreover, the results from the benchmark are very satisfactory and validate the capabilities of the two simulators used to study coupled thermal, mechanical and hydraulic (multi-component, multi-phase) processes relative to the underground disposal of high

  4. Radioactive liquid wastes discharged to ground in the 200 Areas during 1978

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anderson, J. D.; Poremba, B. E.

    1979-03-26

    This document is issued quarterly for the purpose of summarizing the radioactive liquid wastes that have been discharged to the ground in the 200 Areas. In addition to data for 1978, cumulative data since plant startup are presented. Also, in this document is a listing of decayed activity to the various plant sites.

  5. Use of zinc and copper (I) salts to reduce sulfur and nitrogen impurities during the pyrolysis of plastic and rubber waste to hydrocarbons

    DOEpatents

    Wingfield, Jr., Robert C.; Braslaw, Jacob; Gealer, Roy L.

    1984-01-01

    An improvement in a process for the pyrolytic conversion of rubber and plastic waste to hydrocarbon products which results in reduced levels of nitrogen and sulfur impurities in these products. The improvement comprises pyrolyzing the waste in the presence of at least about 1 weight percent of salts, based on the weight of the waste, preferably chloride or carbonate salts, of zinc or copper (I). This invention was made under contract with or subcontract thereunder of the Department of Energy Contract #DE-AC02-78-ER10049.

  6. 40 CFR 268.34 - Waste specific prohibitions-toxicity characteristic metal wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... characteristic wastes from elemental phosphorus processing; radioactive wastes mixed with EPA Hazardous wastes... identified characteristic wastes from elemental phosphorus processing, radioactive waste mixed with D004-D011...

  7. 40 CFR 268.34 - Waste specific prohibitions-toxicity characteristic metal wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... characteristic wastes from elemental phosphorus processing; radioactive wastes mixed with EPA Hazardous wastes... identified characteristic wastes from elemental phosphorus processing, radioactive waste mixed with D004-D011...

  8. Waste Oil Burn-Off in Coast Guard Power Plants - Diesel Piston Ring Wear Study by Radioactive Tracer Techniques

    DOT National Transportation Integrated Search

    1976-07-01

    This report covers the results of a study utilizing a radioactive tracer technique to determine wear effects on the upper compression rings of a two-stroke cycle diesel engine burning mixtures of waste lube oil in fuel oil. The radioactive tracer tec...

  9. Evaluating and planning the radioactive waste options for dismantling the Tokamak Fusion Test Reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rule, K.; Scott, J.; Larson, S.

    1995-12-31

    The Tokamak Fusion Test Reactor (TFTR) is a one-of-a kind tritium fusion research reactor, and is planned to be decommissioned within the next several years. This is the largest fusion reactor in the world and as a result of deuterium-tritum reactions is tritium contaminated and activated from 14 Mev neutrons. This presents many unusual challenges when dismantling, packaging and disposing its components and ancillary systems. Special containers are being designed to accommodate the vacuum vessel, neutral beams, and tritium delivery and processing systems. A team of experienced professionals performed a detailed field study to evaluate the requirements and appropriate methodsmore » for packaging the radioactive materials. This team focused on several current and innovative methods for waste minimization that provides the oppurtunmost cost effective manner to package and dispose of the waste. This study also produces a functional time-phased schedule which conjoins the waste volume, weight, costs and container requirements with the detailed project activity schedule for the entire project scope. This study and project will be the first demonstration of the decommissioning of a tritium fusion test reactor. The radioactive waste disposal aspects of this project are instrumental in demonstrating the viability of a fusion power reactor with regard to its environmental impact and ultimate success.« less

  10. Congenital primary adrenal insufficiency and selective aldosterone defects presenting as salt-wasting in infancy: a single center 10-year experience.

    PubMed

    Bizzarri, Carla; Olivini, Nicole; Pedicelli, Stefania; Marini, Romana; Giannone, Germana; Cambiaso, Paola; Cappa, Marco

    2016-08-02

    Salt-wasting represents a relatively common cause of emergency admission in infants and may result in life-threatening complications. Neonatal kidneys show low glomerular filtration rate and immaturity of the distal nephron leading to reduced ability to concentrate urine. A retrospective chart review was conducted for infants hospitalized in a single Institution from 1(st) January 2006 to 31(st) December 2015. The selection criterion was represented by the referral to the Endocrinology Unit for hyponatremia (serum sodium <130 mEq/L) of suspected endocrine origin at admission. Fifty-one infants were identified. In nine infants (17.6 %) hyponatremia was related to unrecognized chronic gastrointestinal or renal salt losses or reduced sodium intake. In 10 infants (19.6 %) hyponatremia was related to central nervous system diseases. In 19 patients (37.3 %) the final diagnosis was congenital adrenal hyperplasia (CAH). CAH was related to 21-hydroxylase deficiency in 18 patients, and to 3β-Hydroxysteroid dehydrogenase (3βHSD) deficiency in one patient. Thirteen patients (25.5 %) were affected by different non-CAH salt-wasting forms of adrenal origin. Four familial cases of X-linked adrenal hypoplasia congenita due to NROB1 gene mutation were identified. Two unrelated girls showed aldosterone synthase deficiency due to mutation of the CYP11B2 gene. Two unrelated infants were affected by familial glucocorticoid deficiency due to MC2R gene mutations. One girl showed pseudohypoaldosteronism related to mutations of the SCNN1G gene encoding for the epithelial sodium channel. Transient pseudohypoaldosteronism was identified in two patients with renal malformations. In two infants the genetic aetiology was not identified. Emergency management of infants presenting with salt wasting requires correction of water losses and treatment of electrolyte imbalances. Nevertheless, the differential diagnosis may be difficult in emergency settings, and sometimes hospitalized infants

  11. Removal of radioactive contaminants by polymeric microspheres.

    PubMed

    Osmanlioglu, Ahmet Erdal

    2016-11-01

    Radionuclide removal from radioactive liquid waste by adsorption on polymeric microspheres is the latest application of polymers in waste management. Polymeric microspheres have significant immobilization capacity for ionic substances. A laboratory study was carried out by using poly(N-isopropylacrylamide) for encapsulation of radionuclide in the liquid radioactive waste. There are numbers of advantages to use an encapsulation technology in radioactive waste management. Results show that polymerization step of radionuclide increases integrity of solidified waste form. Test results showed that adding the appropriate polymer into the liquid waste at an appropriate pH and temperature level, radionuclide was encapsulated into polymer. This technology may provide barriers between hazardous radioactive ions and the environment. By this method, solidification techniques became easier and safer in nuclear waste management. By using polymer microspheres as dust form, contamination risks were decreased in the nuclear industry and radioactive waste operations.

  12. Final environmental impact statement. Management of commercially generated radioactive waste. Volume 3. Public comments hearing board report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1980-10-01

    This EIS analyzes the significant environmental impacts that could occur if various technologies for management and disposal of high-level and transuranic wastes from commercial nuclear power reactors were to be developed and implemented. This EIS will serve as the environmental input for the decision on which technology, or technologies, will be emphasized in further research and development activities in the commercial waste management program. The action proposed in this EIS is to (1) adopt a national strategy to develop mined geologic repositories for disposal of commercially generated high-level and transuranic radioactive waste (while continuing to examine subseabed and very deepmore » hole disposal as potential backup technologies) and (2) conduct a R and D program to develop such facilities and the necessary technology to ensure the safe long-term containment and isolation of these wastes. The Department has considered in this statement: development of conventionally mined deep geologic repositories for disposal of spent fuel from nuclear power reactors and/or radioactive fuel reprocessing wastes; balanced development of several alternative disposal methods; and no waste disposal action. This volume contains written public comments and hearing board responses and reports offered on the draft statement.« less

  13. Brine Migration in Heated Salt: Lessons Learned from Field Experiments

    NASA Astrophysics Data System (ADS)

    Kuhlman, K. L.; Matteo, E. N.; Mills, M.

    2017-12-01

    We summarize several interesting brine migration related phenomena hinted at in field experiments from field testing related to salt radioactive waste repositories in Germany and the US. Past heater tests in salt have shown 1) thermal-hydrological-mechanical coupling is quite strong during both heating and cooling; 2) chemical composition of brine evolves during heating, and comprises a mix of several water sources; and 3) acid gas (HCl) generation has been observed during past heater tests and may have multiple mechanisms for formation. We present a heated brine migration test design, formulated with these complexities in mind. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc. for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.

  14. EXAFS/XANES studies of plutonium-loaded sodalite/glass waste forms

    NASA Astrophysics Data System (ADS)

    Richmann, Michael K.; Reed, Donald T.; Kropf, A. Jeremy; Aase, Scott B.; Lewis, Michele A.

    2001-09-01

    A sodalite/glass ceramic waste form is being developed to immobilize highly radioactive nuclear wastes in chloride form, as part of an electrochemical cleanup process. Two types of simulated waste forms were studied: where the plutonium was alone in an LiCl/KCl matrix and where simulated fission-product elements were added representative of the electrometallurgical treatment process used to recover uranium from spent nuclear fuel also containing plutonium and a variety of fission products. Extended X-ray absorption fine structure spectroscopy (EXAFS) and X-ray absorption near-edge spectroscopy (XANES) studies were performed to determine the location, oxidation state, and particle size of the plutonium within these waste form samples. Plutonium was found to segregate as plutonium(IV) oxide with a crystallite size of at least 4.8 nm in the non-fission-element case and 1.3 nm with fission elements present. No plutonium was observed within the sodalite in the waste form made from the plutonium-loaded LiCl/KCl eutectic salt. Up to 35% of the plutonium in the waste form made from the plutonium-loaded simulated fission-product salt may be segregated with a heavy-element nearest neighbor other than plutonium or occluded internally within the sodalite lattice.

  15. Environmental analysis Waste Isolation Pilot Plant (WIPP) cost reduction proposals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Waste Isolation Pilot Plant (WIPP) is a research and development facility to demonstrate the safe disposal of radioactive wastes resulting from the defense activities and programs of the United States government. The facility is planned to be developed in bedded salt at the Los Medanos site in southeastern New Mexico. The environmental consequences of contruction and operation of the WIPP facility are documented in ''Final Environmental Impact Statement, Waste Isolation Pilot Plant''. The proposed action addressed by this environmental analysis is to simplify and reduce the scope of the WIPP facility as it is currently designed. The proposed changesmore » to the existing WIPP design are: limit the waste storage rate to 500,000 cubic feet per year; eliminate one shaft and revise the underground ventilation system; eliminate the underground conveyor system; combine the Administration Building, the Underground Personnel Building and the Waste Handling Building office area; simplify the central monitoring system; simplify the security control systems; modify the Waste Handling Building; simplify the storage exhaust system; modify the above ground salt handling logistics; simplify the power system; reduce overall site features; simplify the Warehouse/Shops Building and eliminate the Vehicle Maintenance Building; and allow resource recovery in Control Zone IV.« less

  16. Achievements and Perspectives of the Joint Convention on the Safety of Spent Fuel Management and on the Safety of Radioactive Waste Management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Louvat, D.; Lacoste, A.C.

    The Joint Convention on the Safety of Spent Fuel management and on the Safety of Radioactive Waste Management is the first legal instrument to directly address the safety of spent fuel and radioactive waste management on a global scale. The Joint Convention entered into force in 2001. This paper describes its process and its main achievements to date. The perspectives to establish of a Global Waste Safety Regime based on the Joint Convention are also discussed. (authors)

  17. The characterization and risk assessment of the `Red Forest` radioactive waste burial site at Chernobyl Nuclear Power Plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bungai, D.A.; Skalskij, A.S.; Dzhepo, S.P.

    The `Red Forest` radioactive waste burials created during emergency clean-up activities at Chernobyl Nuclear Power Plant represent a serious source of radioactive contamination of the local ground water system with 9OSr concentration in ground water exceeding the drinking water standard by 3-4 orders of magnitude. In this paper we present results of our hydrogeological and radiological `Red Forest` site characterization studies, which allow us to estimate 9OSr subsurface migration parameters. We use then these parameters to assess long terrain radionuclide transport to groundwater and surface water, and to analyze associated health risks. Our analyses indicate that 9OSr transport via groundmore » water pathway from `Red Forest` burials to the adjacent Pripyat River is relatively insignificant due to slow release of 9OSr from the waste burials (less than 1% of inventory per year) and due to long enough ground water residence time in the subsurface, which allows substantial decay of the radioactive contaminant. Tins result and our previous analyses indicate, that though conditions of radioactive waste storage in burials do not satisfy Ukrainian regulation on radiation protection, health risks caused by radionuclide migration to ground water from `Red Forest` burials do not justify application of expensive countermeasures.« less

  18. Summary Report of Laboratory Testing to Establish the Effectiveness of Proposed Treatment Methods for Unremediated and Remediated Nitrate Salt Waste Streams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anast, Kurt Roy; Funk, David John

    The inadvertent creation of transuranic waste carrying hazardous waste codes D001 and D002 requires the treatment of the material to eliminate the hazardous characteristics and allow its eventual shipment and disposal at the Waste Isolation Pilot Plant (WIPP). This report documents the effectiveness of two treatment methods proposed to stabilize both the unremediated and remediated nitrate salt waste streams (UNS and RNS, respectively). The two technologies include the addition of zeolite (with and without the addition of water as a processing aid) and cementation. Surrogates were developed to evaluate both the solid and liquid fractions expected from parent waste containers,more » and both the solid and liquid fractions were tested. Both technologies are shown to be effective at eliminating the characteristic of ignitability (D001), and the addition of zeolite was determined to be effective at eliminating corrosivity (D002), with the preferred option1 of zeolite addition currently planned for implementation at the Waste Characterization, Reduction, and Repackaging Facility. During the course of this work, we established the need to evaluate and demonstrate the effectiveness of the proposed remedy for debris material, if required. The evaluation determined that Wypalls absorbed with saturated nitrate salt solutions exhibit the ignitability characteristic (all other expected debris is not classified as ignitable). Follow-on studies will be developed to demonstrate the effectiveness of stabilization for ignitable Wypall debris. Finally, liquid surrogates containing saturated nitrate salts did not exhibit the characteristic of ignitability in their pure form (those neutralized with Kolorsafe and mixed with sWheat did exhibit D001). As a result, additional nitrate salt solutions (those exhibiting the oxidizer characteristic) will be tested to demonstrate the effectiveness of the remedy.« less

  19. A Model for Remote Depth Estimation of Buried Radioactive Wastes Using CdZnTe Detector.

    PubMed

    Ukaegbu, Ikechukwu Kevin; Gamage, Kelum A A

    2018-05-18

    This paper presents the results of an attenuation model for remote depth estimation of buried radioactive wastes using a Cadmium Zinc Telluride (CZT) detector. Previous research using an organic liquid scintillator detector system showed that the model is able to estimate the depth of a 329-kBq Cs-137 radioactive source buried up to 12 cm in sand with an average count rate of 100 cps. The results presented in this paper showed that the use of the CZT detector extended the maximum detectable depth of the same radioactive source to 18 cm in sand with a significantly lower average count rate of 14 cps. Furthermore, the model also successfully estimated the depth of a 9-kBq Co-60 source buried up to 3 cm in sand. This confirms that this remote depth estimation method can be used with other radionuclides and wastes with very low activity. Finally, the paper proposes a performance parameter for evaluating radiation detection systems that implement this remote depth estimation method.

  20. A Model for Remote Depth Estimation of Buried Radioactive Wastes Using CdZnTe Detector

    PubMed Central

    2018-01-01

    This paper presents the results of an attenuation model for remote depth estimation of buried radioactive wastes using a Cadmium Zinc Telluride (CZT) detector. Previous research using an organic liquid scintillator detector system showed that the model is able to estimate the depth of a 329-kBq Cs-137 radioactive source buried up to 12 cm in sand with an average count rate of 100 cps. The results presented in this paper showed that the use of the CZT detector extended the maximum detectable depth of the same radioactive source to 18 cm in sand with a significantly lower average count rate of 14 cps. Furthermore, the model also successfully estimated the depth of a 9-kBq Co-60 source buried up to 3 cm in sand. This confirms that this remote depth estimation method can be used with other radionuclides and wastes with very low activity. Finally, the paper proposes a performance parameter for evaluating radiation detection systems that implement this remote depth estimation method. PMID:29783644

  1. Radioactive waste management in France: safety demonstration fundamentals.

    PubMed

    Ouzounian, G; Voinis, S; Boissier, F

    2012-01-01

    The main challenge in development of the safety case for deep geological disposal is associated with the long periods of time over which high- and intermediate-level long-lived wastes remain hazardous. A wide range of events and processes may occur over hundreds of thousands of years. These events and processes are characterised by specific timescales. For example, the timescale for heat generation is much shorter than any geological timescale. Therefore, to reach a high level of reliability in the safety case, it is essential to have a thorough understanding of the sequence of events and processes likely to occur over the lifetime of the repository. It then becomes possible to assess the capability of the repository to fulfil its safety functions. However, due to the long periods of time and the complexity of the events and processes likely to occur, uncertainties related to all processes, data, and models need to be understood and addressed. Assessment is required over the lifetime of the radionuclides contained in the radioactive waste. Copyright © 2012. Published by Elsevier Ltd.

  2. Three multimedia models used at hazardous and radioactive waste sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moskowitz, P.D.; Pardi, R.; Fthenakis, V.M.

    1996-02-01

    Multimedia models are used commonly in the initial phases of the remediation process where technical interest is focused on determining the relative importance of various exposure pathways. This report provides an approach for evaluating and critically reviewing the capabilities of multimedia models. This study focused on three specific models MEPAS Version 3.0, MMSOILS Version 2.2, and PRESTO-EPA-CPG Version 2.0. These models evaluate the transport and fate of contaminants from source to receptor through more than a single pathway. The presence of radioactive and mixed wastes at a site poses special problems. Hence, in this report, restrictions associated with the selectionmore » and application of multimedia models for sites contaminated with radioactive and mixed wastes are highlighted. This report begins with a brief introduction to the concept of multimedia modeling, followed by an overview of the three models. The remaining chapters present more technical discussions of the issues associated with each compartment and their direct application to the specific models. In these analyses, the following components are discussed: source term; air transport; ground water transport; overland flow, runoff, and surface water transport; food chain modeling; exposure assessment; dosimetry/risk assessment; uncertainty; default parameters. The report concludes with a description of evolving updates to the model; these descriptions were provided by the model developers.« less

  3. Final environmental impact statement. Waste Isolation Pilot Plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1980-10-01

    This volume contains the appendices for the Final Environmental Impact Statement for the Waste Isolation Pilot Plant (WIPP). Alternative geologic environs are considered. Salt, crystalline rock, argillaceous rock, and tuff are discussed. Studies on alternate geologic regions for the siting of WIPP are reviewed. President Carter's message to Congress on the management of radioactive wastes and the findings and recommendations of the interagency review group on nuclear waste management are included. Selection criteria for the WIPP site including geologic, hydrologic, tectonic, physicochemical compatability, and socio-economic factors are presented. A description of the waste types and the waste processing procedures aremore » given. Methods used to calculate radiation doses from radionuclide releases during operation are presented. A complete description of the Los Medanos site, including archaeological and historic aspects is included. Environmental monitoring programs and long-term safety analysis program are described. (DMC)« less

  4. Secondary Aluminum Processing Waste: Salt Cake ...

    EPA Pesticide Factsheets

    Thirty-nine salt cake samples were collected from 10 SAP facilities across the U.S. The facilities were identified by the Aluminum Association to cover a wide range of processes. Results suggest that while the percent metal leached from the salt cake was relatively low, the leachable metal content may still pose a contamination concern and potential human and ecological exposure if uncontrollably released to the environment. As a result, salt cake should always be managed at facilities that utilize synthetic liner systems with leachate collection (the salt content of the leachate will increase the hydraulic conductivity of clay liners within a few years of installation). The mineral phase analysis showed that various species of aluminum are present in the salt cake samples with a large degree of variability. The relative abundance of various aluminum species was evaluated but it is noted that the method used is a semi-quantitative method and as a result there is a limitation for the data use. The analysis only showed a few aluminum species present in salt cake which does not exclude the presence of other crystalline species especially in light of the variability observed in the samples. Results presented in this document are of particular importance when trying to understand concerns associated with the disposal of salt cake in MSW landfills. From the end-of-life management perspective, data presented here suggest that salt cake should not be size reduce

  5. Evaluation of the safety of mobile units for the conditioning of radioactive waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Filss, Martin; Wallner, Christian

    2013-07-01

    In Germany mobile units are used to treat and condition radioactive waste. On behalf of the relevant authorities TUV SUD Industrie Service GmbH evaluates their safety. In this paper we outline the general procedure we apply and point out typical results. Generally, a generic safety case evaluates the effects of incidents and accidents and its consequences for the workers and the public. Special care is necessary to define the radioactive inventory, the nuclide composition and the mobility of the radioactive substances. A systems analysis is carried out. Typical aspects to be considered are the handling procedures, the measurement devices andmore » automatic actions. From the various possible malfunctions the critical ones have to be identified. Generally one or only a few scenarios have to be considered in detail. (authors)« less

  6. Final environmental impact statement. Management of commercially generated radioactive waste. Volume 1 of 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1980-10-01

    This EIS analyzes the significant environmental impacts that could occur if various technologies for management and disposal of high-level and transuranic wastes from commercial nuclear power reactors were to be developed and implemented. This EIS will serve as the environmental input for the decision on which technology, or technologies, will be emphasized in further research and development activities in the commercial waste management program. The action proposed in this EIS is to (1) adopt a national strategy to develop mined geologic repositories for disposal of commercially generated high-level and transuranic radioactive waste (while continuing to examine subseabed and very deepmore » hole disposal as potential backup technologies) and (2) conduct a R and D program to develop such facilities and the necessary technology to ensure the safe long-term containment and isolation of these wastes. The Department has considered in this statement: development of conventionally mined deep geologic repositories for disposal of spent fuel from nuclear power reactors and/or radioactive fuel reprocessing wastes; balanced development of several alternative disposal methods; and no waste disposal action. This EIS reflects the public review of and comments offered on the draft statement. Included are descriptions of the characteristics of nuclear waste, the alternative disposal methods under consideration, and potential environmental impacts and costs of implementing these methods. Because of the programmatic nature of this document and the preliminary nature of certain design elements assumed in assessing the environmental consequences of the various alternatives, this study has been based on generic, rather than specific, systems. At such time as specific facilities are identified for particular sites, statements addressing site-specific aspects will be prepared for public review and comment.« less

  7. Low sintering temperature glass waste forms for sequestering radioactive iodine

    DOEpatents

    Nenoff, Tina M.; Krumhansl, James L.; Garino, Terry J.; Ockwig, Nathan W.

    2012-09-11

    Materials and methods of making low-sintering-temperature glass waste forms that sequester radioactive iodine in a strong and durable structure. First, the iodine is captured by an adsorbant, which forms an iodine-loaded material, e.g., AgI, AgI-zeolite, AgI-mordenite, Ag-silica aerogel, ZnI.sub.2, CuI, or Bi.sub.5O.sub.7I. Next, particles of the iodine-loaded material are mixed with powdered frits of low-sintering-temperature glasses (comprising various oxides of Si, B, Bi, Pb, and Zn), and then sintered at a relatively low temperature, ranging from 425.degree. C. to 550.degree. C. The sintering converts the mixed powders into a solid block of a glassy waste form, having low iodine leaching rates. The vitrified glassy waste form can contain as much as 60 wt % AgI. A preferred glass, having a sintering temperature of 500.degree. C. (below the silver iodide sublimation temperature of 500.degree. C.) was identified that contains oxides of boron, bismuth, and zinc, while containing essentially no lead or silicon.

  8. Thermal-gradient migration of brine inclusions in salt crystals. [Synthetic single crystals of NaCl and KCl

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yagnik, S.K.

    1982-09-01

    It has been proposed that high-level nuclear waste be disposed in a geologic repository. Natural-salt deposits, which are being considered for this purpose, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive-decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms which is undesirable. In this work, thermal gradient migration of bothmore » all-liquid and gas-liquid inclusions was experimentally studied in synthetic single crystals of NaCl and KCl using a hot-stage attachment to an optical microscope which was capable of imposing temperature gradients and axial compressive loads on the crystals. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is non-linear.At high axial loads, however, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, three different gas phases (helium, air and argon) were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large angle grain boundaries was observed. 35 figures, 3 tables.« less

  9. ANNULUS CLOSURE TECHNOLOGY DEVELOPMENT INSPECTION/SALT DEPOSIT CLEANING MAGNETIC WALL CRAWLER

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Minichan, R; Russell Eibling, R; James Elder, J

    2008-06-01

    The Liquid Waste Technology Development organization is investigating technologies to support closure of radioactive waste tanks at the Savannah River Site (SRS). Tank closure includes removal of the wastes that have propagated to the tank annulus. Although amounts and types of residual waste materials in the annuli of SRS tanks vary, simple salt deposits are predominant on tanks with known leak sites. This task focused on developing and demonstrating a technology to inspect and spot clean salt deposits from the outer primary tank wall located in the annulus of an SRS Type I tank. The Robotics, Remote and Specialty Equipmentmore » (RRSE) and Materials Science and Technology (MS&T) Sections of the Savannah River National Laboratory (SRNL) collaborated to modify and equip a Force Institute magnetic wall crawler with the tools necessary to demonstrate the inspection and spot cleaning in a mock-up of a Type I tank annulus. A remote control camera arm and cleaning head were developed, fabricated and mounted on the crawler. The crawler was then tested and demonstrated on a salt simulant also developed in this task. The demonstration showed that the camera is capable of being deployed in all specified locations and provided the views needed for the planned inspection. It also showed that the salt simulant readily dissolves with water. The crawler features two different techniques for delivering water to dissolve the salt deposits. Both water spay nozzles were able to dissolve the simulated salt, one is more controllable and the other delivers a larger water volume. The cleaning head also includes a rotary brush to mechanically remove the simulated salt nodules in the event insoluble material is encountered. The rotary brush proved to be effective in removing the salt nodules, although some fine tuning may be required to achieve the best results. This report describes the design process for developing technology to add features to a commercial wall crawler and the

  10. Hydrogen Production in Radioactive Solutions in the Defense Waste Processing Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    CRAWFORD, CHARLES L.

    2004-05-26

    In the radioactive slurries and solutions to be processed in the Defense Waste Processing Facility (DWPF), hydrogen will be produced continuously by radiolysis. This production results from alpha, beta, and gamma rays from decay of radionuclides in the slurries and solutions interacting with the water. More than 1000 research reports have published data concerning this radiolytic production. The results of these studies have been reviewed in a comprehensive monograph. Information about radiolytic hydrogen production from the different process tanks is necessary to determine air purge rates necessary to prevent flammable mixtures from accumulating in the vapor spaces above these tanks.more » Radiolytic hydrogen production rates are usually presented in terms of G values or molecules of hydrogen produced per 100ev of radioactive decay energy absorbed by the slurry or solution. With the G value for hydrogen production, G(H2), for a particular slurry and the concentrations of radioactive species in that slurry, the rate of H2 production for that slurry can be calculated. An earlier investigation estimated that the maximum rate that hydrogen could be produced from the sludge slurry stream to the DWPF is with a G value of 0.45 molecules per 100ev of radioactive decay energy sorbed by the slurry.« less

  11. Low-level radioactive waste management: transitioning to off-site disposal at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dorries, Alison M

    2010-11-09

    Facing the closure of nearly all on-site management and disposal capability for low-level radioactive waste (LLW), Los Alamos National Laboratory (LANL) is making ready to ship the majority of LLW off-site. In order to ship off-site, waste must meet the Treatment, Storage, and Disposal Facility's (TSDF) Waste Acceptance Criteria (WAC). In preparation, LANL's waste management organization must ensure LANL waste generators characterize and package waste compliantly and waste characterization documentation is complete and accurate. Key challenges that must be addressed to successfully make the shift to off-site disposal of LLW include improving the detail, accuracy, and quality of process knowledgemore » (PK) and acceptable knowledge (AK) documentation, training waste generators and waste management staff on the higher standard of data quality and expectations, improved WAC compliance for off-site facilities, and enhanced quality assurance throughout the process. Certification of LANL generators will allow direct off-site shipping of LLW from their facilities.« less

  12. Taipower`s radioactive waste management program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, B.C.C.

    1996-09-01

    Nuclear safety and radioactive waste management are the two major concerns of nuclear power in Taiwan. Recognizing that it is an issue imbued with political and social-economic concerns, Taipower has established an integrated nuclear backend management system and its associated financial and mechanism. For LLW, the Orchid Island storage facility will play an important role in bridging the gap between on-site storage and final disposal of LLW. Also, on-site interim storage of spent fuel for 40 years or longer will provide Taipower with ample time and flexibility to adopt the suitable alternative of direct disposal or reprocessing. In other words,more » by so exercising interim storage option, Taipower will be in a comfortable position to safely and permanently dispose of radwaste without unduly forgoing the opportunities of adopting better technologies or alternatives. Furthermore, Taipower will spare no efforts to communicate with the general public and make her nuclear backend management activities accountable to them.« less

  13. The characterization of radioactive waste: a critical review of techniques implemented or under development at CEA, France

    NASA Astrophysics Data System (ADS)

    Pérot, Bertrand; Jallu, Fanny; Passard, Christian; Gueton, Olivier; Allinei, Pierre-Guy; Loubet, Laurent; Estre, Nicolas; Simon, Eric; Carasco, Cédric; Roure, Christophe; Boucher, Lionel; Lamotte, Hervé; Comte, Jérôme; Bertaux, Maïté; Lyoussi, Abdallah; Fichet, Pascal; Carrel, Frédérick

    2018-03-01

    This review paper describes the destructive and non-destructive measurements implemented or under development at CEA, in view to perform the most complete radioactive waste characterization. First, high-energy photon imaging (radiography, tomography) brings essential information on the waste packages, such as density, position and shape of the waste inside the container and in the possible binder, quality of coating and blocking matrices, presence of internal shields or structures, presence of cracks, voids, or other defects in the container or in the matrix, liquids or other forbidden materials, etc. Radiological assessment is then performed using a series of non-destructive techniques such as gamma-ray spectroscopy, which allows characterizing a wide range of radioactive and nuclear materials, passive neutron coincidence counting and active neutron interrogation with the differential die-away technique, or active photon interrogation with high-energy photons (photofission), to measure nuclear materials. Prompt gamma neutron activation analysis (PGNAA) can also be employed to detect toxic chemicals or elements which can greatly influence the above measurements, such as neutron moderators or absorbers. Digital auto-radiography can also be used to detect alpha and beta contaminated waste. These non-destructive assessments can be completed by gas measurements, to quantify the radioactive and radiolysis gas releases, and by destructive examinations such as coring homogeneous waste packages or cutting the heterogeneous ones, in view to perform visual examination and a series of physical, chemical, and radiochemical analyses on samples. These last allow for instance to check the mechanical and containment properties of the package envelop, or of the waste binder, to measure toxic chemicals, to assess the activity of long-lived radionuclides or pure beta emitters, to determine the isotopic composition of nuclear materials, etc.

  14. An overview of the draft for the amendment of 'nuclear materials and radioactive waste management act'

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Huan Lin; Tai-Wei Lan; Min-Tsang Chang

    2013-07-01

    The 'Nuclear Materials and Radioactive Waste Management Act' (NMRWMA) in Taiwan has been in use since 2002. To promote further administrative efficiency and improve regulatory capacity, an amendment of the act has been initiated by the Atomic Energy Council (AEC). It is now being reviewed by outside experts and related communities so as to include the best understanding of risk management factors. For the future decommissioning challenges of nuclear facilities, the act is also being amended to comply with the regulatory requirements of the decommissioning mandates. Currently the Taiwan government is conducting government reorganization, and AEC will be reformed butmore » will remain as an independent regulatory body. AEC will then be capable of improving the regulatory capacity for facilitating licensing and inspection, ensuring operational safety, environmental protection and public involvement, and giving a more flexible administrative discretion, such as expending the margin of penalty. The amendment is also required to provide a formal legal basis for the Nuclear Backend Fund, and to mandate the waste producers to take responsibility for any final debt repayment. In addition, this amendment promotes measures to prevent accidents or emergencies concerning radioactive materials and facilities and procedures to reduce the impact and effect of any unexpected events. Furthermore, this amendment intends to implement the concept of information transparency and public participation so as to meet the public needs. Finally, radioactive waste final disposal tasks have to be completed by waste producers under the supervision of the AEC. (authors)« less

  15. Electrochemical reduction behavior of simplified simulants of vitrified radioactive waste in molten CaCl2

    NASA Astrophysics Data System (ADS)

    Katasho, Yumi; Yasuda, Kouji; Nohira, Toshiyuki

    2018-05-01

    The electrochemical reduction of two types of simplified simulants of vitrified radioactive waste, simulant 1 (glass component only: SiO2, B2O3, Na2O, Al2O3, CaO, Li2O, and ZnO) and simulant 2 (also containing long-lived fission product oxides, ZrO2, Cs2O, PdO, and SeO2), was investigated in molten CaCl2 at 1103 K. The behavior of each element was predicted from the potential-pO2- diagram constructed from thermodynamic data. After the immersion of simulant 1 into molten CaCl2 without electrolysis, the dissolution of Na, Li, and Cs was confirmed by inductively coupled plasma atomic emission spectrometry and mass spectrometry analysis of the samples. The scanning electron microscopy/energy dispersive X-ray and X-ray diffraction analyses of simulants 1 and 2 electrolyzed at 0.9 V vs. Ca2+/Ca confirmed that most of SiO2 had been reduced to Si. After the electrolysis of simulants 1 and 2, Al, Zr, and Pd remained in the solid phase. In addition, SeO2 was found to remain partially in the solid phase and partially evaporate, although a small quantity dissolved into the molten salt.

  16. Durability of a reinforced concrete designed for the construction of an intermediate-level radioactive waste disposal facility

    NASA Astrophysics Data System (ADS)

    Duffó, G. S.; Arva, E. A.; Schulz, F. M.; Vazquez, D. R.

    2012-01-01

    The National Atomic Energy Commission of the Argentine Republic is developing a nuclear waste disposal management programme that contemplates the design and construction of a facility for the final disposal of intermediate-level radioactive wastes. The repository is based on the use of multiple, independent and redundant barriers. The major components are made in reinforced concrete so, the durability of these structures is an important aspect for the facility integrity. This work presents an investigation performed on a reinforced concrete specifically designed for this purpose, to predict the service life of the intermediate level radioactive waste disposal facility from data obtained with several techniques. Results obtained with corrosion sensors embedded in a concrete prototype are also included. The information obtained will be used for the final design of the facility in order to guarantee a service life more or equal than the foreseen durability for this type of facilities.

  17. Collective doses to man from dumping of radioactive waste in the Arctic Seas.

    PubMed

    Nielsen, S P; Iosjpe, M; Strand, P

    1997-08-25

    A box model for the dispersion of radionuclides in the marine environment covering the Arctic Ocean and the North Atlantic Ocean has been constructed. Collective doses from ingestion pathways have been calculated from unit releases of the radionuclides 3H, 60Co, 63Ni, 90Sr, 129I, 137Cs, 239Pu and 241Am into a fjord on the east coast of NovayaZemlya. The results show that doses for the shorter-lived radionuclides (e.g. 137Cs) are derived mainly from seafood production in the Barents Sea. Doses from the longer-lived radionuclides (e.g. 239Pu) are delivered through marine produce further away from the Arctic Ocean. Collective doses were calculated for two release scenarios, both of which are based on information of the dumping of radioactive waste in the Barents and Kara Seas by the former Soviet Union and on preliminary information from the International Arctic Sea Assessment Programme. A worst-case scenario was assumed according to which all radionuclides in liquid and solid radioactive waste were available for dispersion in the marine environment at the time of dumping. Release of radionuclides from spent nuclear fuel was assumed to take place by direct corrosion of the fuel ignoring the barriers that prevent direct contact between the fuel and the seawater. The second scenario selected assumed that releases of radionuclides from spent nuclear fuel do not occur until after failure of the protective barriers. All other liquid and solid radioactive waste was assumed to be available for dispersion at the time of discharge in both scenarios. The estimated collective dose for the worst-case scenario was about 9 manSv and that for the second scenario was about 3 manSv. In both cases, 137Cs is the radionuclide predicted to dominate the collective doses as well as the peak collective dose rates.

  18. Characterization of radioactive wastes with respect to harmful materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kugel, Karin; Steyer, Stefan; Brennecke, Peter

    In addendum 4 to the license of the German KONRAD repository, which considers mainly radiological aspects, a water law permit was issued in order to prevent the pollution of the near-surface groundwater. The water law permit stipulates limitations for 10 radionuclides and 2 groups of radionuclides as well as mass limitations for 94 substances and materials relevant for water protection issues. Two collateral clauses, i.e. additional requirements imposed by the licensing authority, include demands on the monitoring, registering and balancing of non-radioactive harmful substances and materials /1/. In order to fulfill the requirements of the water law permit the Germanmore » Federal Office for Radiation Protection (BfS) being the operator of the KONRAD repository has developed a concept, which ensures the compliance with all requirements of the water law permit and which provides standardized easy manageable guidance for the waste producers to describe their wastes. On 15 March 2011 the competent water authority, the 'Niedersaechsischer Landesbetrieb fuer Wasserwirtschaft, Kuesten- und Naturschutz' (NLWKN) issued the approval for this concept. Being the most essential part of this concept the procedural method and the developed description of nonradioactive waste package constituents by use of standardized lists of materials and containers is addressed and presented in this paper. The waste producer has to describe his waste package in a standardized way on the base of the lists of materials and containers. For each material in the list a comprehensive description is given comprising the composition, scope of application, quality control measures, thresholds and other data. Each entry in the list has to be approved by NLWKN. The scope of the lists is defined by the waste producers' needs. Using some particular materials as examples, the approval procedure for including materials in the list is described. The procedure of describing the material composition has to

  19. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOEpatents

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1999-03-09

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  20. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOEpatents

    Cao, Hui; Adams, Jay W.; Kalb, Paul D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.