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Sample records for resonance scattering spectral

  1. [Immune resonance scattering spectral analysis of fenvalerate].

    PubMed

    Ma, Wen-Sheng; Wang, Su-Mei; Jiang, Zhi-Liang

    2009-01-01

    , 80 microg x mL(-1) HSA, 80 microg x mL(-1) Fe3+, 80 microg x mL(-1) Mg2+, 160 microg x mL(-1) Ca2+, and 160 microg x mL(-1) glucose. The results indicated that this RSS assay has good selectivity. This immune resonance scattering spectral assay was applied to the determination of Fen in waste water samples with satisfactory results. The recovery was in the range of 92.91%-101.25%, and the relative standard deviation was in the range of 1.71%-4.80%. PMID:19385242

  2. A new resonance Rayleigh scattering spectral method for determination of O3 with victoria blue B

    NASA Astrophysics Data System (ADS)

    Wen, Guiqing; Yang, Duo; Jiang, Zhiliang

    2014-01-01

    Ozone (O3) could be absorbed by boric acid-potassium iodide (BKI) absorbent solution to produce tri-iodine ion (I3-) that react with victoria blue B (VBB) to form the associated particle (VBB-I3)n and exhibited a strong resonance Rayleigh scattering (RRS) peak at 722 nm. Under the chosen conditions, the RRS peak intensity was linear with O3 concentration in the range of 0.2-50 μmol/L, with a linear regression equation of ΔI722 = 17.9c - 45.4 and detection limit of 0.057 μmol/L. Accordingly, a simple, rapid and sensitive RRS spectral method was set up for determination of trace O3 in air, with satisfactory results.

  3. Hydride generation-resonance Rayleigh scattering and SERS spectral determination of trace Bi.

    PubMed

    Liang, Xiaojing; Wen, Guiqing; Liu, Qingye; Liang, Aihui; Jiang, Zhiliang

    2016-09-01

    In acidic solutions, Bi(III) was reduced by NaBH4 to form BiH3 gas. Using I3(-)graphene oxide (GO) as absorption solution, the BiH3 gas reacted with I3(-) to form I(-) that resulted in the I3(-) concentration decreasing. In the absence of BiH3, the I3(-) concentration was high, and as receptors it was closed to the surfaces of GO which was as donors. Then the surface plasmon resonance Rayleigh scattering (RRS) energy of GO transfers to I3(-) heavily, and results in the RRS quenching severely. With the increase of the Bi(III) concentration, the receptors and the RRS energy transfer (RRS-ET) decreased, so the RRS intensity enhanced linearly at 370nm. The RRS intensity was linear to the Bi(III) concentration in 0.05-5.5μmol/L, with a detection limit of 4ng/mL Bi. A new RRS-ET spectral method was developed for the determination of trace Bi(III). Using I3(-) as the absorption solution, silver nanorod (AgNR) as sol substrate and Vitoria blue B (VBB) as molecular probe, a SERS method was developed for detection of Bi. PMID:27214274

  4. Hydride generation-resonance Rayleigh scattering and SERS spectral determination of trace Bi

    NASA Astrophysics Data System (ADS)

    Liang, Xiaojing; Wen, Guiqing; Liu, Qingye; Liang, Aihui; Jiang, Zhiliang

    2016-09-01

    In acidic solutions, Bi(III) was reduced by NaBH4 to form BiH3 gas. Using I3- graphene oxide (GO) as absorption solution, the BiH3 gas reacted with I3- to form I- that resulted in the I3- concentration decreasing. In the absence of BiH3, the I3- concentration was high, and as receptors it was closed to the surfaces of GO which was as donors. Then the surface plasmon resonance Rayleigh scattering (RRS) energy of GO transfers to I3- heavily, and results in the RRS quenching severely. With the increase of the Bi(III) concentration, the receptors and the RRS energy transfer (RRS-ET) decreased, so the RRS intensity enhanced linearly at 370 nm. The RRS intensity was linear to the Bi(III) concentration in 0.05-5.5 μmol/L, with a detection limit of 4 ng/mL Bi. A new RRS-ET spectral method was developed for the determination of trace Bi(III). Using I3- as the absorption solution, silver nanorod (AgNR) as sol substrate and Vitoria blue B (VBB) as molecular probe, a SERS method was developed for detection of Bi.

  5. Spectral diagnostic of a microflare. Evidences of resonant scattering in C IV 1548 Å, 1550 Å lines

    NASA Astrophysics Data System (ADS)

    Gontikakis, C.; Winebarger, A. R.; Patsourakos, S.

    2013-02-01

    Aims: We study a microflare, classified as a GOES-A1 after background subtraction, which was observed in active region NOAA 8541 on May 15, 1999. Methods: We used TRACE filtergrams to study the morphology and time evolution. SUMER spectral lines were used to diagnose the chromospheric plasma (Si ii 1533 Å), transition region plasma (C iv 1548, 1550 Å), and coronal plasma (Ne viii 770 Å). Results: In the 171 Å and 195 Å filtergrams, we measure apparent mass motions along two small loops that compose the microflare from the eastern toward the western footpoints. In SUMER, the microflare is detected as a small (47 Mm2), bright area at the western footpoints of the TRACE loops. The spectral profiles recorded over the bright area are complex. The Si ii 1533 Å line is self-reversed owing to opacity, and the coronal Ne viii line profile is composed of two Gaussian components, one of them systematically redshifted. The C iv 1548 Å and 1550 Å profiles are badly distorted because of the temporary depression of the detector local gain caused by the very high count rates reached in the flaring region and we can only confirm the presence of strong blueshifts of ≃ -200 km s-1. Few, unaffected C iv profiles show two spectral components. In the northern part of the bright area, all SUMER spectral lines have at least one blueshifted spectral component. In the southern region of the bright area the spectral lines are redshifted. Adjacent to the microflare we measure, for the first time on the solar disk, an intensity ratio of the 1548 Å line to 1550 Å line with values of three to four, indicating that resonance scattering prevails in the lines formation. Moreover, the scattering region is found to be cospatial to a solar pore. Conclusions: The blueshifts in the footpoints of the microflare and the apparent mass motions observed with TRACE can be explained by a gentle chromospheric evaporation triggered by the microflare. The redshifted spectral components can be

  6. Optical spectral singularities as threshold resonances

    SciTech Connect

    Mostafazadeh, Ali

    2011-04-15

    Spectral singularities are among generic mathematical features of complex scattering potentials. Physically they correspond to scattering states that behave like zero-width resonances. For a simple optical system, we show that a spectral singularity appears whenever the gain coefficient coincides with its threshold value and other parameters of the system are selected properly. We explore a concrete realization of spectral singularities for a typical semiconductor gain medium and propose a method of constructing a tunable laser that operates at threshold gain.

  7. Comparison of temporal and spectral scattering methods using acoustically large breast models derived from magnetic resonance images

    PubMed Central

    Hesford, Andrew J.; Tillett, Jason C.; Astheimer, Jeffrey P.; Waag, Robert C.

    2014-01-01

    Accurate and efficient modeling of ultrasound propagation through realistic tissue models is important to many aspects of clinical ultrasound imaging. Simplified problems with known solutions are often used to study and validate numerical methods. Greater confidence in a time-domain k-space method and a frequency-domain fast multipole method is established in this paper by analyzing results for realistic models of the human breast. Models of breast tissue were produced by segmenting magnetic resonance images of ex vivo specimens into seven distinct tissue types. After confirming with histologic analysis by pathologists that the model structures mimicked in vivo breast, the tissue types were mapped to variations in sound speed and acoustic absorption. Calculations of acoustic scattering by the resulting model were performed on massively parallel supercomputer clusters using parallel implementations of the k-space method and the fast multipole method. The efficient use of these resources was confirmed by parallel efficiency and scalability studies using large-scale, realistic tissue models. Comparisons between the temporal and spectral results were performed in representative planes by Fourier transforming the temporal results. An RMS field error less than 3% throughout the model volume confirms the accuracy of the methods for modeling ultrasound propagation through human breast. PMID:25096103

  8. Comparison of temporal and spectral scattering methods using acoustically large breast models derived from magnetic resonance images.

    PubMed

    Hesford, Andrew J; Tillett, Jason C; Astheimer, Jeffrey P; Waag, Robert C

    2014-08-01

    Accurate and efficient modeling of ultrasound propagation through realistic tissue models is important to many aspects of clinical ultrasound imaging. Simplified problems with known solutions are often used to study and validate numerical methods. Greater confidence in a time-domain k-space method and a frequency-domain fast multipole method is established in this paper by analyzing results for realistic models of the human breast. Models of breast tissue were produced by segmenting magnetic resonance images of ex vivo specimens into seven distinct tissue types. After confirming with histologic analysis by pathologists that the model structures mimicked in vivo breast, the tissue types were mapped to variations in sound speed and acoustic absorption. Calculations of acoustic scattering by the resulting model were performed on massively parallel supercomputer clusters using parallel implementations of the k-space method and the fast multipole method. The efficient use of these resources was confirmed by parallel efficiency and scalability studies using large-scale, realistic tissue models. Comparisons between the temporal and spectral results were performed in representative planes by Fourier transforming the temporal results. An RMS field error less than 3% throughout the model volume confirms the accuracy of the methods for modeling ultrasound propagation through human breast. PMID:25096103

  9. The fluorescence and resonance Rayleigh scattering spectral study and analytical application of cerium (IV) and cefoperazone system

    NASA Astrophysics Data System (ADS)

    Yuan, Yusheng; Fu, Shenghui; Xu, Qianying; Yang, Jidong; Hu, Xiaoli; Liu, Shaopu

    2016-06-01

    In weak acidic medium of pH 3.5-5.6, Ce(IV) can be reduced by cefoperazone (CPZ) to be Ce(III), which further combined with CPZ to form complex Ce(OH)3CPZ. This complex not only has higher fluorescence than Ce(III), but also results in significant increase of resonance Rayleigh scattering (RRS), second order scattering (SOS) and frequency doubling scattering (FDS). The wavelengths of maximum fluorescence exciting and emission are located at 356 nm/349 nm, while the maximum wavelengths of RRS, SOS and FDS are at 312 nm, 550 nm and 390 nm, respectively. The intensity of fluorescence and scattering are all linear with the concentration of CPZ in certain conditions. The detection limit of most sensitive RRS method for CPZ is 2.1 ng mL- 1. The optimum conditions for detecting CPZ using RRS method are investigated. The effect of co-existing substances shows that the method has excellent selectivity, especially since other cephalosporins don't have similar reactions. Therefore, it can be achieved to determine CPZ in cephalosporins selectively. The paper also focuses on the reaction mechanism, the consistent and contracture of the resultant. The reasons for enhanced intensity are presumed in the meantime.

  10. The fluorescence and resonance Rayleigh scattering spectral study and analytical application of cerium (IV) and cefoperazone system.

    PubMed

    Yuan, Yusheng; Fu, Shenghui; Xu, Qianying; Yang, Jidong; Hu, Xiaoli; Liu, Shaopu

    2016-06-01

    In weak acidic medium of pH3.5-5.6, Ce(IV) can be reduced by cefoperazone (CPZ) to be Ce(III), which further combined with CPZ to form complex Ce(OH)3CPZ. This complex not only has higher fluorescence than Ce(III), but also results in significant increase of resonance Rayleigh scattering (RRS), second order scattering (SOS) and frequency doubling scattering (FDS). The wavelengths of maximum fluorescence exciting and emission are located at 356 nm/349 nm, while the maximum wavelengths of RRS, SOS and FDS are at 312 nm, 550 nm and 390 nm, respectively. The intensity of fluorescence and scattering are all linear with the concentration of CPZ in certain conditions. The detection limit of most sensitive RRS method for CPZ is 2.1 ng mL(-1). The optimum conditions for detecting CPZ using RRS method are investigated. The effect of co-existing substances shows that the method has excellent selectivity, especially since other cephalosporins don't have similar reactions. Therefore, it can be achieved to determine CPZ in cephalosporins selectively. The paper also focuses on the reaction mechanism, the consistent and contracture of the resultant. The reasons for enhanced intensity are presumed in the meantime. PMID:26994317

  11. Resonance scattering spectral detection of trace ATP based on label-free aptamer reaction and nanogold catalysis.

    PubMed

    Liang, Aihui; Ouyang, Huixiang; Jiang, Zhiliang

    2011-11-01

    Double-stranded DNA (dsDNA) cannot protect gold nanoparticles (AuNPs) in the presence of NaCl, and dsDNA interacted with adenosine triphosphate (ATP) to form stable G-quartet and a single-stranded DNA (DNA 2) that can protect AuNPs. The unprotected AuNPs were aggregated to AuNP aggregations (AuNPA) that exhibited a resonance scattering (RS) peak at 590 nm. The RS intensity at 590 nm decreased linearly when the ATP concentration increased in the range of 6.6-110 nM. The catalysis of AuNP-DNA 2 was stronger than that of the AuNPA on the glucose-Cu(II) particle reaction, and the product appeared as an RS peak at 620 nm. When the ATP concentration was increased, the AuNP-DNA 2 increased, and the RS intensity at 620 nm increased linearly. The increased RS intensity (ΔI(620 nm)) was linear to ATP concentration in the range of 2.2-220 nM, with a regression equation of ΔI(620 nm) = 0.709C + 7.7, and a detection limit of 0.5 nM. Hereby, a new RS method of ATP detection was set up with high sensitivity and selectivity. PMID:21912797

  12. Nanoparticles assembled by aptamers and crystal violet for arsenic(iii) detection in aqueous solution based on a resonance Rayleigh scattering spectral assay

    NASA Astrophysics Data System (ADS)

    Wu, Yuangen; Zhan, Shenshan; Xing, Haibo; He, Lan; Xu, Lurong; Zhou, Pei

    2012-10-01

    Aptamer-assembled nanomaterials have captured much attention from the field of analytical chemistry in recent years. Although they have been regarded as a promising tool for heavy metal monitoring, report involving aptamer-based biosensors for arsenic detection are rare. Herein we developed a highly sensitive and selective aptamer biosensor for As(iii) detection based on a Resonance Rayleigh Scattering (RRS) spectral assay. Prior to As(iii) detection, we firstly assembled a variety of nanoparticles with different sizes via controlling the concentration of arsenic-binding aptamers in crystal violet (CV) solutions. The results of photon correlation spectroscopy (PCS) and scanning probe microscope (SPM) testified that the introduction of As(iii) had indeed changed the size of nanoparticles, which caused a great variation in the RRS intensity at 310 nm. In the presence of 100 ppb As(iii), a maximum decline in the ratio of RRS intensity was achieved for large nanoparticles assembled from 200 nM of aptamers and CV molecules, where the average size of nanoparticles had decreased from 273 nm to 168 nm. In the case of small nanoparticles, the maximum increase ratio of the RRS intensity was obtained when the concentration of aptamer was over 600 nM. Combined with an RRS spectral assay, an effective biosensor has been developed for As(iii) detection, using the above large and small nanoparticles as the target recognition element. The present biosensor has a detection limit as low as 0.2 ppb, a dynamic range from 0.1 ppb to 200 ppb, and high selectivity over other metal ions. Such an efficient biosensor will play an important role in environmental detection.

  13. Resonant Raman Scattering in Antiferromagnets

    NASA Astrophysics Data System (ADS)

    Chubukov, Andrey V.; Morr, Dirk K.

    1996-03-01

    Two-magnon Raman scattering provides important information about electronic correlations in the insulating parent compounds of high-Tc materials. Recent experiments have shown a strong dependence of the Raman signal in B_1g geometry on the frequency of the incoming photon. We present a detailed numerical study of the diagram which was previously identified(A.V. Chubukov and D.M. Frenkel, Phys. Rev. B 52), 9760 (1995) as the most relevant in the resonant regime. We found two maxima of the two-magnon peak hight at transferred frequencies of ω ≈ 3J and ω ≈ 8J. These results agree with recent experiments by Blumberg(G. Blumberg et al.), preprint et al. on Sr_2CuO_2Cl_2. Furthermore, we study how the two-magnon profile depends on a quasiparticle damping and a hopping between next-nearest neighbors. We also study resonance scattering in other scattering geometries, in particular, A_1g scattering.

  14. Resonant Raman scattering in antiferromagnets

    NASA Astrophysics Data System (ADS)

    Morr, Dirk K.; Chubukov, Andrey V.

    1997-10-01

    Two-magnon Raman scattering provides important information about electronic correlations in the insulating parent compounds of high-Tc materials. Recent experiments have shown a strong dependence of the Raman signal in B1g geometry on the frequency of the incoming photon. We present an analytical and numerical study of the Raman intensity in the resonant regime. It has been previously argued by Chubukov and Frenkel that the most relevant contribution to the Raman vertex at resonance is given by the triple resonance diagram. We derive an expression for the Raman intensity in which we simultaneously include the enhancement due to the triple resonance and a final-state interaction. We compute the two-magnon peak height (TMPH) as a function of incident frequency and find two maxima at ω(1)res~2Δ+3J and ω(2)res~2Δ+8J. We argue that the high-frequency maximum is cut only by a quasiparticle damping, while the low-frequency maximum has a finite amplitude even in the absence of damping. We also obtain an evolution of the Raman profile from an asymmetric form around ω(1)res to a symmetric form around ω(2)res. We further show that the TMPH depends on the fermionic quasiparticle damping, the next-nearest-neighbor hopping term t', and the corrections to the interaction vertex between light and the fermionic current. We discuss our results in the context of recent experiments by Blumberg et al. on Sr2CuO2Cl2 and YBa2Cu3O6.1 and Rübhausen et al. on PrBa2Cu3O7 and show that the triple resonance theory yields a qualitative and to some extent also quantitative understanding of the experimental data.

  15. Cascades of Fano resonances in Mie scattering

    NASA Astrophysics Data System (ADS)

    Rybin, M. V.; Sinev, I. S.; Samusev, K. B.; Limonov, M. F.

    2014-03-01

    The interference nature of resonant Mie scattering, which is described within the Fano model, has been demonstrated. The interference is caused by interaction of an incident electromagnetic wave with reemitted waves that correspond to eigenmodes of a scattering particle. Mie scattering due to the interference can be represented in the form of cascades of resonance lines of different shapes, each of which is described by the classical Fano formula. The effect is observed in resonant light scattering by an arbitrary body of revolution and discussed in detail using the example of scattering by an infinite homogeneous dielectric cylinder.

  16. Resonant Raman scattering in nanoscale pentacene films

    NASA Astrophysics Data System (ADS)

    He, Rui; Dujovne, Irene; Chen, Liwei; Miao, Qian; Hirjibehedin, Cyrus F.; Pinczuk, Aron; Nuckolls, Colin; Kloc, Christian; Ron, Arza

    2004-02-01

    Resonant Raman scattering intensities from nanoscale films of pentacene display large resonant enhancements that enable observation of vibrational modes in monolayer cluster films. The resonant enhancements occur when the outgoing photon energy overlaps the free exciton optical transitions observed in luminescence. The results point to the significant potential of resonant Raman methods in the characterization of nanoscale structures of organic molecular semiconductors.

  17. Spectral correlation of wideband target resonances

    NASA Astrophysics Data System (ADS)

    Sabio, Vincent

    1995-07-01

    The potential for automatic target recognition (ATR) processing of foliage-penetrating (FOPEN) synthetic-aperture radar (SAR) imagery requires very high bandwidth occupancies to achieve sufficient range resolution for the ATR task. The U.S. Army Research Laboratory (ARL) ultra-wideband (UWB) FOPEN SAR -- with greater than 95 percent bandwidth occupancy -- provides a suitable testbed for evaluation of resonance-based ATR approaches. Current resonance-extraction techniques (e.g., SEM) typically have poor performance in the presence of noise, and are often computationally intensive. Recently developed at ARL, the `spectral correlation method' uses linear transforms -- such as Fourier and wavelets -- to resolve resonant components; these transforms are generally quite fast, and have straightforward implementations. Creating a synthetic version of the ringdown and projecting onto the desired transform basis provides a set of expected spectral coefficients (the `spectral template'). The spectral template is correlated with the spectral coefficients acquired from the projection of the focused image data onto the same basis function set; the correlation coefficient is then passed through a simple threshold detector. This yields a fast, efficient scheme for recognition of target resonance effects in UWB imagery. Recent advances in this area include a reduction in false-alarm rate by two orders of magnitude, a reduction in processing time by three orders of magnitude, and recognition of a tactical target.

  18. Resonances in pi-K scattering

    SciTech Connect

    Wilson, David J.

    2014-06-23

    We have obtained clear signals of resonances in coupled-channel pi K - eta K scattering. Using distillation and a large basis of operators we are able to extract a precise spectrum of energy levels using the variational method. These energies are analysed using inelastic extensions of the Luescher method to obtain scattering amplitudes that clearly describe S, P and D wave resonances, corresponding to the physical K_0^*(1430), the K^*(892) and the K_2^*(1430).

  19. Alpha resonant scattering for astrophysical reaction studies

    SciTech Connect

    Yamaguchi, H.; Kahl, D.; Nakao, T.; Wakabayashi, Y.; Kubano, S.; Hashimoto, T.; Hayakawa, S.; Kawabata, T.; Iwasa, N.; Teranishi, T.; Kwon, Y. K.; Binh, D. N.; Khiem, L. H.; Duy, N. G.

    2014-05-02

    Several alpha-induced astrophysical reactions have been studied at CRIB (CNS Radioactive Ion Beam separator), which is a low-energy RI beam separator at Center for Nuclear Study (CNS) of the University of Tokyo. One of the methods to study them is the α resonant scattering using the thick-target method in inverse kinematics. Among the recent studies at CRIB, the measurement of {sup 7}Be+α resonant scattering is discussed. Based on the result of the experiment, we evaluated the contributions of high-lying resonances for the {sup 7}Be(α,γ) reaction, and proposed a new cluster band in {sup 11}C.

  20. Alpha resonant scattering for astrophysical reaction studies

    NASA Astrophysics Data System (ADS)

    Yamaguchi, H.; Kahl, D.; Nakao, T.; Wakabayashi, Y.; Kubano, S.; Hashimoto, T.; Hayakawa, S.; Kawabata, T.; Iwasa, N.; Teranishi, T.; Kwon, Y. K.; Binh, D. N.; Khiem, L. H.; Duy, N. G.

    2014-05-01

    Several alpha-induced astrophysical reactions have been studied at CRIB (CNS Radioactive Ion Beam separator), which is a low-energy RI beam separator at Center for Nuclear Study (CNS) of the University of Tokyo. One of the methods to study them is the α resonant scattering using the thick-target method in inverse kinematics. Among the recent studies at CRIB, the measurement of 7Be+α resonant scattering is discussed. Based on the result of the experiment, we evaluated the contributions of high-lying resonances for the 7Be(α,γ) reaction, and proposed a new cluster band in 11C.

  1. Resonant Compton scattering and gamma-ray burst continuum spectra

    NASA Technical Reports Server (NTRS)

    Baring, M. G.

    1995-01-01

    The Thomson limit of resonant inverse Compton scattering in the strong magnetic fields of neutron stars is considered as a mechanism for producing gamma-ray burst continuum spectra. Photon production spectra and electron cooling rates are presented using the full magnetic Thomson cross-section. Model emission spectra are obtained as self-consistent solutions of a set of photon and electron kinetic equations, displaying spectral breaks and other structure at gamma-ray energies.

  2. Spectral correlation of wideband target resonances

    NASA Astrophysics Data System (ADS)

    Sabio, Vincent

    1996-06-01

    The US Army Research Laboratory (ARL), working with the University of Maryland Department of Electrical Engineering, recently developed a novel method for efficient recognition of resonances in imagery from ARL's ultra-wideband (UWB) SAR instrumentation system, currently being used in foliage- and ground-penetration studies. The recognition technique uses linear transforms (Fourier, wavelets, etc.) to provide a basis for the design of spectrally matched filters. Implementation of the technique is very straightforward: an expectation of the target ringdown is projected onto a transform basis set, yielding a set of spectral coefficients (the 'spectral template'). UWB SAR image data are projected onto the same basis set, yielding a second vector of coefficients (the 'spectral image'). A simple correlation coefficient is generated from the two vectors, providing a measure of co-linearity of the spectral template and the spectral image: higher correlation values indicate greater co-linearity. Exceeding a correlation threshold results in a target implemented--a single 32-megabyte bipolar SAR image can be processed in less than five minutes. Initial spectral-correlation efforts focused on canonical targets and the results have been widely reported. Current studies are focusing on tactical targets, such as CUCVs. Early results on CUCVs have shown that sa single resonance-based template can be sued effectively in the recognition of tactical targets. Ongoing studies have demonstrated a substantial reduction in the false-alarm rate over results reported previously. These results, as well as improvements in the recognitions-processing stage, are reported in this paper.

  3. Scattering Resonances in the Simplest Chemical Reaction

    NASA Astrophysics Data System (ADS)

    Fernandez-Alonso, Felix; Zare, Richard N.

    2002-10-01

    Recent studies of state-resolved angular distributions show the participation of reactive scattering resonances in the simplest chemical reaction. This review is intended for those who wish to learn about the state-of-the-art in the study of the H + H2 reaction family that has made this breakthrough possible. This review is also intended for those who wish to gain insight into the nature of reactive scattering resonances. Following a tour across several fields of physics and chemistry where the concept of resonance has been crucial for the understanding of new phenomena, we offer an operational definition and taxonomy of reactive scattering resonances. We introduce simple intuitive models to illustrate each resonance type. We focus next on the last decade of H + H2 reaction dynamics. Emphasis is placed on the various experimental approaches that have been applied to the search for resonance behavior in the H + H2 reaction family. We conclude by sketching the road ahead in the study of H + H2 reactive scattering resonances.

  4. Hadron scattering and resonances in QCD

    NASA Astrophysics Data System (ADS)

    Dudek, Jozef J.

    2016-05-01

    I describe how hadron-hadron scattering amplitudes are related to the eigenstates of QCD in a finite cubic volume. The discrete spectrum of such eigenstates can be determined from correlation functions computed using lattice QCD, and the corresponding scattering amplitudes extracted. I review results from the Hadron Spectrum Collaboration who have used these finite volume methods to study ππ elastic scattering, including the ρ resonance, as well as coupled-channel π >K, ηK scattering. Ongoing calculations are advertised and the outlook for finite volume approaches is presented.

  5. Submarine UXO Detection Using Resonance Scattering Sonar

    NASA Astrophysics Data System (ADS)

    Gritto, R.; Korneev, V. A.; Johnson, L. R.

    2010-12-01

    Resonance scattered waves from a dataset collected in a pond setting were utilized to detect and characterize unexploded ordnance (UXO) located proud off the bottom sediments. Furthermore, it was investigated whether UXO can be characterized by their size and filler velocities and whether medium velocities can be derived from the field data. Analysis of the field data was supported by numerical modeling. It was found that resonance scattered waves were present in all numerical data and in the field cases of a proud sphere and a buried cylinder. In all other cases of proud UXO the field data revealed frequency dependent scattered waves that were part of the direct reflected waves. Imaging UXO with monochromatic data produces surprisingly good results considering that in most investigated cases a small fraction of the data with very low amplitudes were used in comparison to data typically used for Kirchhoff migration or SAS imaging. The images derived from resonance scattered waves were generated by data obtained from narrow passbands throughout the whole frequency spectrum such that different parts of the UXO can be illumination separately. Range resolution is reduced when imaging is done with monochromatic signals. However, the image resolution can be dramatically improved by adding data from different azimuth as was demonstrated for the cases of a proud sphere and bomb. A suite of results ranging from numerical calculations to field data will be presented to show how the properties of resonance scattering can be utilized to detect, locate and characterize an UXO in littoral environments.

  6. Pygmy Resonances Probed with Electron Scattering

    SciTech Connect

    Bertulani, Carlos A

    2007-05-01

    Pygmy resonances in light nuclei excited in electron scattering are discussed. These collective modes will be explored in future electron-ion colliders such as ELISe/FAIR (spokesperson: Haik Simon - GSI). Response functions for direct breakup are explored with few-body and hydrodynamical models, including the dependence upon final-state interactions.

  7. Anomalous and resonance small angle scattering: Revision

    SciTech Connect

    Epperson, J.E.; Thiyagarajan, P.

    1987-11-01

    Significant changes in the small angle scattered intensity can be induced by making measurements with radiation close to an absorption edge of an appropriate atomic species contained in the sample. These changes can be related quantitatively to the real and imaginary anomalous dispersion terms for the scattering factor (x-rays) or scattering length (neutrons). The physics inherent in these anomalous dispersion terms is first discussed before considering how they enter the relevant scattering theory. Two major areas of anomalous scattering research have emerged; macromolecules in solution and unmixing of metallic alloys. Research in each area is reviewed, illustrating both the feasibility and potential of these techniques. All the experimental results reported to date have been obtained with x-rays. However, it is pointed out that the formalism is the same for the analogue experiment with neutrons, and a number of suitable isotopes exist which exhibit resonance in an accessible range of energy. Potential applications of resonance small angle neutron scatterings are discussed. 54 refs., 8 figs., 1 tab.

  8. Anomalous and resonance small angle scattering

    SciTech Connect

    Epperson, J.E.; Thiyagarajan, P.

    1987-11-01

    Significant changes in the small angle scattered intensity can be induced by making measurements with radiation close to an absorption edge of an appropriate atomic species contained in the sample. These changes can be related quantitatively to the real and imaginary anomalous dispersion terms for the scattering factor (x-rays) or scattering length (neutrons). The physics inherent in these anomalous dispersion terms is first discussed before considering how they enter the relevant scattering theory. Two major areas of anomalous scattering research have emerged; macromolecules in solution and unmixing of metallic alloys. Research in each area is reviewed, illustrating both the feasibility and potential of these techniques. All the experimental results reported to date have been obtained with x-rays. However, it is pointed out that the formalism is the same or the analogue experiment with neutrons, and a number of suitable isotopes exist which exhibit resonance in an accessible range of energy. Potential applications of resonance small-angle neutron scatterings are discussed. 8 figs.

  9. Spectral polarimetric light-scattering by particulate media: 1. Theory of spectral Vector Radiative Transfer

    NASA Astrophysics Data System (ADS)

    Ceolato, Romain; Riviere, Nicolas

    2016-07-01

    Spectral polarimetric light-scattering by particulate media has recently attracted growing interests for various applications due to the production of directional broadband light sources. Here the spectral polarimetric light-scattering signatures of particulate media are simulated using a numerical model based on the spectral Vector Radiative Transfer Equation (VRTE). A microphysical analysis is conducted to understand the dependence of the light-scattering signatures upon the microphysical parameters of particles. We reveal that depolarization from multiple scattering results in remarkable spectral and directional features, which are simulated by our model over a wide spectral range from visible to near-infrared. We propose to use these features to improve the inversion of the scattering problem in the fields of remote sensing, astrophysics, material science, or biomedical.

  10. Proton resonance scattering of 7Be

    NASA Astrophysics Data System (ADS)

    Yamaguchi, H.; Saito, A.; He, J. J.; Wakabayashi, Y.; Amadio, G.; Fujikawa, H.; Kubono, S.; Khiem, L. H.; Kwon, Y. K.; Niikura, M.; Teranishi, T.; Nishimura, S.; Togano, Y.; Iwasa, N.; Inafuku, K.

    2006-07-01

    We have studied the proton resonance scattering of 7Be by using a pure 7Be beam produced at CRIB (CNS Radioactive Ion Beam separator; CNS stands for Center of Nuclear Study, University of Tokyo). The excitation function of 8B was measured up to the excitation energy of 6.8 MeV, with the thick-target method. The excited states of 8B higher than 3.5 MeV were not known by the past experiments. This proton elastic scattering is also of importance in relation with the 7Be(p,γ)8B reaction, which is a key reaction in the standard solar model.

  11. Effective Spectral Function for Neutrino Quasielastic Scattering Event Generators

    NASA Astrophysics Data System (ADS)

    Coopersmith, Brian; Bodek, Arie; Christy, M. Eric

    2014-03-01

    The spectral functions that are used in modeling of quasi elastic scattering in neutrino event generators such as GENIE, NEUT, NUANCE and NUWRO event generators include (Global) Fermi gas, local Fermi gas, Bodek-Ritche Fermi gas with high momentum tail, and the Benhar Fantoni spectral function. We find that these spectral functions do not agree with the prediction of ψ' superscaling functions that are extracted from electron quasi elastic scattering data on nuclear targets. It is known that spectral functions do not fully describe quasi elastic scattering because they only model the initial state. Final state interactions distort the shape of the quasi elastic peak, reduce the cross section at the peak and increase the cross section at the tail of the distribution for large energy transfer to final state nucleons. We show that an ``effective spectral function'' can be constructed to reliably reproduce the kinematic distributions predicted by the ψ' super scaling formalism.

  12. Ultrafast Imaging using Spectral Resonance Modulation

    PubMed Central

    Huang, Eric; Ma, Qian; Liu, Zhaowei

    2016-01-01

    CCD cameras are ubiquitous in research labs, industry, and hospitals for a huge variety of applications, but there are many dynamic processes in nature that unfold too quickly to be captured. Although tradeoffs can be made between exposure time, sensitivity, and area of interest, ultimately the speed limit of a CCD camera is constrained by the electronic readout rate of the sensors. One potential way to improve the imaging speed is with compressive sensing (CS), a technique that allows for a reduction in the number of measurements needed to record an image. However, most CS imaging methods require spatial light modulators (SLMs), which are subject to mechanical speed limitations. Here, we demonstrate an etalon array based SLM without any moving elements that is unconstrained by either mechanical or electronic speed limitations. This novel spectral resonance modulator (SRM) shows great potential in an ultrafast compressive single pixel camera. PMID:27122101

  13. Ultrafast Imaging using Spectral Resonance Modulation

    NASA Astrophysics Data System (ADS)

    Huang, Eric; Ma, Qian; Liu, Zhaowei

    2016-04-01

    CCD cameras are ubiquitous in research labs, industry, and hospitals for a huge variety of applications, but there are many dynamic processes in nature that unfold too quickly to be captured. Although tradeoffs can be made between exposure time, sensitivity, and area of interest, ultimately the speed limit of a CCD camera is constrained by the electronic readout rate of the sensors. One potential way to improve the imaging speed is with compressive sensing (CS), a technique that allows for a reduction in the number of measurements needed to record an image. However, most CS imaging methods require spatial light modulators (SLMs), which are subject to mechanical speed limitations. Here, we demonstrate an etalon array based SLM without any moving elements that is unconstrained by either mechanical or electronic speed limitations. This novel spectral resonance modulator (SRM) shows great potential in an ultrafast compressive single pixel camera.

  14. Ultrafast Imaging using Spectral Resonance Modulation.

    PubMed

    Huang, Eric; Ma, Qian; Liu, Zhaowei

    2016-01-01

    CCD cameras are ubiquitous in research labs, industry, and hospitals for a huge variety of applications, but there are many dynamic processes in nature that unfold too quickly to be captured. Although tradeoffs can be made between exposure time, sensitivity, and area of interest, ultimately the speed limit of a CCD camera is constrained by the electronic readout rate of the sensors. One potential way to improve the imaging speed is with compressive sensing (CS), a technique that allows for a reduction in the number of measurements needed to record an image. However, most CS imaging methods require spatial light modulators (SLMs), which are subject to mechanical speed limitations. Here, we demonstrate an etalon array based SLM without any moving elements that is unconstrained by either mechanical or electronic speed limitations. This novel spectral resonance modulator (SRM) shows great potential in an ultrafast compressive single pixel camera. PMID:27122101

  15. Calculation of polarization and anisotropy of resonant and fluorescent scattering. [in planetary atmospheres

    NASA Technical Reports Server (NTRS)

    Chamberlain, Joseph W.

    1990-01-01

    Formulas are derived for the swift calculation of the angular intensity distribution and the degree of polarization associated with the resonant and fluorescent scattering of radiation by atoms which occurs in the rarefied upper atmospheres of planets during sunlit airglow phenomena. Attention is given to spectral lines with hyperfine structure, which are indicative of nuclear spin processes. The method employed involves summations over Zeeman components, allowing an evaluation of polarization through the addition of underlying simple resonant and fluorescent scattering channels.

  16. Effective spectral function for quasielastic scattering on nuclei

    NASA Astrophysics Data System (ADS)

    Bodek, A.; Christy, M. E.; Coopersmith, B.

    2014-10-01

    Spectral functions that are used in neutrino event generators to model quasielastic (QE) scattering from nuclear targets include Fermi gas, Local Thomas Fermi gas (LTF), Bodek-Ritchie Fermi gas with high momentum tail, and the Benhar-Fantoni two dimensional spectral function. We find that the $\

  17. Spectral dependence of fluorescence near plasmon resonant metal nanoparticles

    NASA Astrophysics Data System (ADS)

    Chen, Yeechi

    The optical properties of fluorophores are significantly modified when placed within the near field (0--100 nm) of plasmon resonant metal nanostructures, due to the competition between increased decay rates and "hotspots" of concentrated electric fields. The decay rates and effective electric field intensities are highly dependent on the relative position of dye and metal and the overlap between plasmon resonance and dye absorption and emission. Understanding these dependencies can greatly improve the performance of biosensing and nanophotonic devices. In this dissertation, the fluorescence intensity of organic dyes and CdSe quantum dots near single metal nanoparticles is studied as a function of the local surface plasmon resonance (LSPR) of the nanoparticle. Single metal nanoparticles have narrow, well-defined, intense local surface plasmon resonances that are tunable across the visible spectrum by changes in size and shape. First, we show that organic dyes can be self-assembled on single silver nanoprisms into known configurations by the hybridization of thiolated DNA oligomers. We correlate the fluorescence intensity of the dyes to the LSPR of the individual nanoprism to which they are attached. For each of three different organic dyes, we observe a strong correlation between the fluorescence intensity of the dye and the degree of spectral overlap with the plasmon resonance of the nanoparticle. On average, we observe the brightest fluorescence from dyes attached to metal nanoparticles that have a LSPR scattering peak 40--120 meV higher in energy than the emission peak of the fluorophore. Second, the plasmon-enhanced fluorescence from CdSe/CdS/CdZnS/ZnS core/shell quantum dots is studied near a variety of silver and gold nanoparticles. With single-particle scattering spectroscopy, the localized surface plasmon resonance spectra of single metal nanoparticles is correlated with the photoluminescence excitation (PLE) spectra of the nearby quantum dots. The PLE

  18. Study of resonance light scattering for remote optical probing

    NASA Technical Reports Server (NTRS)

    Penney, C. M.; Morey, W. W.; St. Peters, R. L.; Silverstein, S. D.; Lapp, M.; White, D. R.

    1973-01-01

    Enhanced scattering and fluorescence processes in the visible and UV were investigated which will enable improved remote measurements of gas properties. The theoretical relationship between scattering and fluorescence from an isolated molecule in the approach to resonance is examined through analysis of the time dependence of re-emitted light following excitation of pulsed incident light. Quantitative estimates are developed for the relative and absolute intensities of fluorescence and resonance scattering. New results are obtained for depolarization of scattering excited by light at wavelengths within a dissociative continuum. The experimental work was performed in two separate facilities. One of these utilizes argon and krypton lasers, single moded by a tilted etalon, and a 3/4 meter double monochromator. This facility was used to determine properties of the re-emission from NO2, I2 and O3 excited by visible light. The second facility involves a narrow-line dye laser, and a 3/4 meter single monochromator. The dye laser produces pulsed light with 5 nsec pulse duration and 0.005 nm spectral width.

  19. Scattering of core-shell nanowires with the interference of electric and magnetic resonances.

    PubMed

    Liu, Wei; Miroshnichenko, Andrey E; Oulton, Rupert F; Neshev, Dragomir N; Hess, Ortwin; Kivshar, Yuri S

    2013-07-15

    We study the scattering of normally incident waves by core-shell nanowires, which support both electric and magnetic resonances. Within such nanowires, for p-polarized incident waves, each electric resonance corresponds to two degenerate scattering channels while the magnetic resonance corresponds to only one channel. Consequently, when the electric dipole (ED) and magnetic dipole (MD) are tuned to overlap spectrally, the magnitude of the ED is twice that of the magnetic one, leading to a pair of angles of vanishing scattering. We further demonstrate that the scattering features of nanowires are polarization dependent, and vanishing scattering angles also can be induced by Fano resonances due to the interference of higher-order electric modes with the broad MD mode. PMID:23939129

  20. Resonance effects in neutron scattering lengths

    SciTech Connect

    Lynn, J.E.

    1989-06-01

    The nature of neutron scattering lengths is described and the nuclear effects giving rise to their variation is discussed. Some examples of the shortcomings of the available nuclear data base, particularly for heavy nuclei, are given. Methods are presented for improving this data base, in particular for obtaining the energy variation of the complex coherent scattering length from long to sub-/angstrom/ wave lengths from the available sources of slow neutron cross section data. Examples of this information are given for several of the rare earth nuclides. Some examples of the effect of resonances in neutron reflection and diffraction are discussed. This report documents a seminar given at Argonne National Laboratory in March 1989. 18 refs., 18 figs.

  1. Resonant electromagnetic scattering in anisotropic layered media

    SciTech Connect

    Shipman, Stephen P.; Welters, Aaron T.

    2013-10-15

    The resonant excitation of an electromagnetic guided mode of a slab structure by exterior radiation results in anomalous scattering behavior, including sharp energy-transmission anomalies and field amplification around the frequency of the slab mode. In the case of a periodically layered ambient medium, anisotropy serves to couple the slab mode to radiation. Exact expressions for scattering phenomena are proved by analyzing a pole of the full scattering matrix as it moves off the real frequency axis into the lower half complex plane under a detuning of the wavevector parallel to the slab. The real pole is the frequency of a perfect (infinite Q) guided mode, which becomes lossy as the frequency gains an imaginary part. This work extends results of Shipman and Venakides to evanescent source fields and two-dimensional parallel wavevector and demonstrates by example how the latter allows one to control independently the width and central frequency of a resonance by varying the angle of incidence of the source field. The analysis relies on two nondegeneracy conditions of the complex dispersion relation for slab modes (relating poles of the scattering matrix to wavevector), which were assumed in previous works and are proved in this work for layered media. One of them asserts that the dispersion relation near the wavevector κ and frequency ω of a perfect guided mode is the zero set of a simple eigenvalue ℓ(κ, ω), and the other relates ∂ℓ/∂ω to the total energy of the mode, thereby implying that this derivative is nonzero.

  2. Fano resonances in scattering: an alternative perspective

    NASA Astrophysics Data System (ADS)

    Schwarz, Lukas; Cartarius, Holger; Wunner, Günter; Heiss, Walter Dieter; Main, Jörg

    2015-08-01

    In a previous paper it has been shown that the interference of the first and second order pole of the Green's function at an exceptional point, as well as the interference of the first order poles in the vicinity of the exceptional point, gives rise to asymmetric scattering cross section profiles. In the present paper we demonstrate that these line profiles are indeed well described by the Beutler-Fano formula, and thus are genuine Fano resonances. Also further away from the exceptional points excellent agreement can be found by introducing energy dependent Fano parameters.

  3. Angle- and Spectral-Dependent Light Scattering from Plasmonic Nanocups

    SciTech Connect

    King, Nicholas S.; Li, Yang; Ayala-Orozco, Ciceron; Brannan, Travis; Nordlander, Peter; Halas, Naomi J.

    2011-09-27

    As optical frequency nanoantennas, reduced-symmetry plasmonic nanoparticles have light-scattering properties that depend strongly on geometry, orientation, and variations in dielectric environment. Here we investigate how these factors influence the spectral and angular dependence of light scattered by Au nanocups. A simple dielectric substrate causes the axial, electric dipole mode of the nanocup to deviate substantially from its characteristic cos² θ free space scattering profile, while the transverse, magnetic dipole mode remains remarkably insensitive to the presence of the substrate. Nanoscale irregularities of the nanocup rim and the local substrate permittivity have a surprisingly large effect on the spectral- and angle-dependent light-scattering properties of these structures.

  4. Fast calculation of object infrared spectral scattering based on CUDA

    NASA Astrophysics Data System (ADS)

    Li, Liang-chao; Niu, Wu-bin; Wu, Zhen-sen

    2010-11-01

    Computational unified device architecture (CUDA) is used for paralleling the spectral scattering calculation from non-Lambertian object of sky and earth background irradiation. The bidirectional reflectance distribution function (BRDF) of five parameter model is utilized in object surface element scattering calculation. The calculation process is partitioned into many threads running in GPU kernel and each thread computes a visible surface element infrared spectral scattering intensity in a specific incident direction, all visible surface elements' intensity are weighted and averaged to obtain the object surface scattering intensity. The comparison of results of the CPU calculation and CUDA parallel calculation of a cylinder shows that the CUDA parallel calculation speed improves more than two hundred times in meeting the accuracy, with a high engineering value.

  5. Scattering of the Field of an Open Quasi-Optical Microwave Resonator on Microwire with Inhomogeneities

    NASA Astrophysics Data System (ADS)

    Dorofeev, I. O.; Dunaevskii, G. E.; Larin, V. S.

    2015-12-01

    The effect of inhomogeneities of the glass-coated cast microwires on the spectral characteristics of the fundamental modes of an open-cavity microwave resonator in the frequency range from 8.2 to 15.5 GHz is experimentally determined. It is shown that the observed inhomogeneities act as local scatterers that have resonance properties. Quantitative data on scattering of the field of the open resonator by such inhomogeneities allow the conclusion on their significant influence on the properties of the composite containing a heterogeneous microwire to be drawn.

  6. Scattering of electromagnetic pulses by metal nanospheres in the vicinity of a Fano-like resonance

    NASA Astrophysics Data System (ADS)

    Astapenko, V. A.; Svita, S. Yu.

    2015-06-01

    In the work, radiation scattering by metal nanospheres in a dielectric matrix in case of ultrashort and long electromagnetic pulses is studied theoretically. Spectral efficiencies of backward and forward scattering by silver nanospheres in glass are calculated with the use of experimental data on the dielectric permittivity of silver. The presence of Fano-like resonances in spectral dependences of scattering efficiency caused by interference of dipole and quadrupole scatterings is shown. Backward and forward scattering of ultrashort pulses is calculated and analyzed. The obtained dependences of the total probability of scattering (during all time of the action of a pulse) on pulse duration demonstrate an essential distinction between an ultrashort case and a long pulse limit.

  7. Oxygen depth profiling by nuclear resonant scattering

    SciTech Connect

    Gibson, G. T.; Sheu, W. J.; Glass, G. A.; Wang, Y. Q.

    1999-06-10

    Nuclear resonance scattering (NRS) {sup 16}O({alpha},{alpha}){sup 16}O at 3.045 MeV ({gamma}=10 keV) has been used for oxygen depth profiling in various thin oxide films. There are two ways by which the oxygen concentration versus depth profile can be obtained from the experimental data: energy spectrum simulation or yield distribution analysis. Energy spectrum simulation is done using the standard RBS software/Rutherford Universal Manipulation Program (RUMP) where only one spectrum is usually needed from the measurement. Yield distribution analysis is accomplished by using a custom developed software/Resonance Analysis Program (RAP) and involves a series of spectra obtained by stepping up the beam energy above the resonance energy. This article aims at comparing the fundamentals of both methods and also discussing their advantages and disadvantages in terms of the data acquisition and the post data analysis. A thermally grown thick SiO{sub 2} film and a thin titanium oxide film grown by corona point discharge were examined.

  8. Oxygen depth profiling by nuclear resonant scattering

    SciTech Connect

    Gibson, G.T.; Sheu, W.J.; Glass, G.A. Wang, Y.Q.

    1999-06-01

    Nuclear resonance scattering (NRS) {sup 16}O({alpha},{alpha}){sup 16}O at 3.045 MeV ({Gamma}=10&hthinsp;keV) has been used for oxygen depth profiling in various thin oxide films. There are two ways by which the oxygen concentration versus depth profile can be obtained from the experimental data: energy spectrum simulation or yield distribution analysis. Energy spectrum simulation is done using the standard RBS software/Rutherford Universal Manipulation Program (RUMP) where only one spectrum is usually needed from the measurement. Yield distribution analysis is accomplished by using a custom developed software/Resonance Analysis Program (RAP) and involves a series of spectra obtained by stepping up the beam energy above the resonance energy. This article aims at comparing the fundamentals of both methods and also discussing their advantages and disadvantages in terms of the data acquisition and the post data analysis. A thermally grown thick SiO{sub 2} film and a thin titanium oxide film grown by corona point discharge were examined. {copyright} {ital 1999 American Institute of Physics.}

  9. Fano resonance generated by magnetic scatterer in micro metal slit

    NASA Astrophysics Data System (ADS)

    Zhou, Yun-Song; Wang, Pei-Jie; Wang, Hai; Feng, Sheng-Fei

    2014-09-01

    A micro metal slit/magnetic scatterer structure is proposed to generate electromagnetic Fano resonance. The magnetic scatterer is formed by infinite long split cylinder resonator array. The analytical transmissivity formulas are deduced from Maxwell electromagnetic theory and the Fano resonance transmission is achieved by the theoretical calculations. The enhancement of environment refractive index leads to an ultrasensitive and linear red shift of resonance peak in the THz range.

  10. Effective Spectral Function for Quasielastic Scattering on Nuclei

    NASA Astrophysics Data System (ADS)

    Bodek, Arie; Christy, M. Eric; Coopersmith, Brian

    2014-09-01

    Spectral functions that are used in neutrino event generators (such as GENIE, NEUT, NUANCE, NUWRO, and GiBUU) to model quasielastic (QE) scattering from nuclear targets include Fermi gas, Local Thomas Fermi gas (LTF), Bodek-Ritche Fermi gas with high momentum tail, and the Benhar Fantoni two dimensional spectral function. We find that the predictions of these spectral functions for the dσ/dν distribution of QE events are in disagreement with the prediction of the Φ ' superscaling function which is extracted from fits to quasielastic electron scattering data on nuclear targets. It is known that spectral functions do not fully describe quasielastic scattering because they only model the initial state. Final state interactions distort the shape of dσ/dν, reduce the cross section at the peak and increase the cross section at the tails of the distribution. We show that the kinematic distributions predicted by the Φ ' superscaling formalism can be well described with a modified effective spectral function (EFS).

  11. Physics of Cyclotron Resonance Scattering Features

    NASA Astrophysics Data System (ADS)

    Sschoenherr, Gabriele; Schwarm, Fritz-Walter; Falkner, Sebastian; Dauser, Thomas; Pottschmidt, Katja; Kretschmar, Peter; Klochkov, Dmitry; Ferrigno, Carlo; Britton Hemphill, Paul; Wilms, Joern

    2016-04-01

    Cyclotron resonant scattering features (short: cyclotron lines) are sensitive tracers of the physics of the accretion columns and mounds of X-ray pulsars. They form by interaction of X-ray photons with magnetically quantized electrons in the accreted plasma close to the neutron star. Such lines have been observed as absorption-like features for about 20 X-ray pulsars. Their energies provide a direct measure of the magnetic field strength in the line-forming region. By detailed modelling of the lines and of their parameter dependencies we can further decipher the physical conditions in the accretion column. For instance the fact that the complex scattering cross sections have a strong angle-dependence relates the phase-resolved cyclotron line shapes to parameters that constrain the systems’ still poorly understood geometry. Modelling the physics of cyclotron lines to a degree that allows for detailed and solid comparison to data therefore provides a unique access also to a better understanding of the overall picture of magnetically accreting neutron star systems.

  12. Forward-scattered light: Spectral broadening and temporal coherence

    NASA Astrophysics Data System (ADS)

    Swanson, N. L.; van Winkle, D. H.

    1997-06-01

    Fabry-Pérot spectroscopy was used to observe a spectral broadening of 1.3+/-0.2 MHz in laser light forward scattered through a colloidal solution. Light from a single-mode argon-ion laser was collected after scattering through water to which measured amounts of diatomaceous earth or 0.08-μm-diam polystyrene spheres were successively added. The broadening is attributed to coupling between fluctuations in particle concentration and spontaneous thermal fluctuations. Though spontaneous fluctuations exist in all pure fluids, they are very weak in water. However, the presence of the particles induces temperature gradients in the fluid, which in turn induce fluctuations in particle concentration.

  13. Mie scattering as a cascade of Fano resonances.

    PubMed

    Rybin, Mikhail V; Samusev, Kirill B; Sinev, Ivan S; Semouchkin, George; Semouchkina, Elena; Kivshar, Yuri S; Limonov, Mikhail F

    2013-12-01

    We reveal that the resonant Mie scattering by high-index dielectric nanoparticles can be presented through cascades of Fano resonances. We employ the exact solution of Maxwell's equations and demonstrate that the Lorenz-Mie coefficients of the Mie problem can be expressed generically as infinite series of Fano functions as they describe interference between the background radiation originated from an incident wave and narrow-spectrum Mie scattering modes that lead to Fano resonances. PMID:24514559

  14. Calculation of Thomson scattering spectral fits for interpenetrating flows

    SciTech Connect

    Swadling, G. F. Lebedev, S. V. Burdiak, G. C.; Suttle, L.; Patankar, S.; Smith, R. A.; Bennett, M.; Suzuki-Vidal, F.; Harvey-Thompson, A. J.; Rozmus, W.; Hall, G. N.; Yuan, J.

    2014-12-15

    Collective mode optical Thomson scattering has been used to investigate the interactions of radially convergent ablation flows in Tungsten wire arrays. These experiments were carried out at the Magpie pulsed power facility at Imperial College, London. Analysis of the scattered spectra has provided direct evidence of ablation stream interpenetration on the array axis, and has also revealed a previously unobserved axial deflection of the ablation streams towards the anode as they approach the axis. It is has been suggested that this deflection is caused by the presence of a static magnetic field, advected with the ablation streams, stagnated and accrued around the axis. Analysis of the Thomson scattering spectra involved the calculation and fitting of the multi-component, non-relativistic, Maxwellian spectral density function S (k, ω). The method used to calculate the fits of the data are discussed in detail.

  15. Scatter-based magnetic resonance elastography

    NASA Astrophysics Data System (ADS)

    Papazoglou, Sebastian; Xu, Chao; Hamhaber, Uwe; Siebert, Eberhard; Bohner, Georg; Klingebiel, Randolf; Braun, Jürgen; Sack, Ingolf

    2009-04-01

    Elasticity is a sensitive measure of the microstructural constitution of soft biological tissues and increasingly used in diagnostic imaging. Magnetic resonance elastography (MRE) uniquely allows in vivo measurement of the shear elasticity of brain tissue. However, the spatial resolution of MRE is inherently limited as the transformation of shear wave patterns into elasticity maps requires the solution of inverse problems. Therefore, an MRE method is introduced that avoids inversion and instead exploits shear wave scattering at elastic interfaces between anatomical regions of different shear compliance. This compliance-weighted imaging (CWI) method can be used to evaluate the mechanical consistency of cerebral lesions or to measure relative stiffness differences between anatomical subregions of the brain. It is demonstrated that CWI-MRE is sensitive enough to reveal significant elasticity variations within inner brain parenchyma: the caudate nucleus (head) was stiffer than the lentiform nucleus and the thalamus by factors of 1.3 ± 0.1 and 1.7 ± 0.2, respectively (P < 0.001). CWI-MRE provides a unique method for characterizing brain tissue by identifying local stiffness variations.

  16. Resonant scattering of surface plasmon polaritons by dressed quantum dots

    SciTech Connect

    Huang, Danhong; Cardimona, Dave; Easter, Michelle; Gumbs, Godfrey; Maradudin, A. A.; Lin, Shawn-Yu; Zhang, Xiang

    2014-06-23

    The resonant scattering of surface plasmon-polariton waves (SPP) by embedded semiconductor quantum dots above the dielectric/metal interface is explored in the strong-coupling regime. In contrast to non-resonant scattering by a localized dielectric surface defect, a strong resonant peak in the spectrum of the scattered field is predicted that is accompanied by two side valleys. The peak height depends nonlinearly on the amplitude of SPP waves, reflecting the feedback dynamics from a photon-dressed electron-hole plasma inside the quantum dots. This unique behavior in the scattered field peak strength is correlated with the occurrence of a resonant dip in the absorption spectrum of SPP waves due to the interband photon-dressing effect. Our result on the scattering of SPP waves may be experimentally observable and applied to spatially selective illumination and imaging of individual molecules.

  17. Light scattering by a finite obstacle and fano resonances.

    PubMed

    Tribelsky, Michael I; Flach, Sergej; Miroshnichenko, Andrey E; Gorbach, Andrey V; Kivshar, Yuri S

    2008-02-01

    The conditions for observing Fano resonances at elastic light scattering by a single finite-size obstacle are discussed. General arguments are illustrated by consideration of the scattering by a small (relative to the incident light wavelength) spherical obstacle based upon the exact Mie solution of the diffraction problem. The most attention is paid to recently discovered anomalous scattering. An exactly solvable one-dimentional discrete model with nonlocal coupling for simulating diffraction in wave scattering in systems with reduced spatial dimensionality is also introduced and analyzed. Deep connections between the resonances in the continuous and discrete systems are revealed. PMID:18352275

  18. Quantitative evaluation of blinking in surface enhanced resonance Raman scattering and fluorescence by electromagnetic mechanism

    NASA Astrophysics Data System (ADS)

    Itoh, Tamitake; Iga, Mitsuhiro; Tamaru, Hiroharu; Yoshida, Ken-ichi; Biju, Vasudevanpillai; Ishikawa, Mitsuru

    2012-01-01

    We analyze blinking in surface enhanced resonance Raman scattering (SERRS) and surface enhanced fluorescence (SEF) of rhodamine 6G molecules as intensity and spectral instability by electromagnetic (EM) mechanism. We find that irradiation of intense NIR laser pulses induces blinking in SERRS and SEF. Thanks to the finding, we systematically analyze SERRS and SEF from stable to unstable using single Ag nanoparticle (NP) dimers. The analysis reveals two physical insights into blinking as follows. (1) The intensity instability is inversely proportional to the enhancement factors of decay rate of molecules. The estimation using the proportionality suggests that separation of the molecules from Ag NP surfaces is several angstroms. (2) The spectral instability is induced by blueshifts in EM enhancement factors, which have spectral shapes similar to the plasmon resonance. This analysis provides us with a quantitative picture for intensity and spectral instability in SERRS and SEF within the framework of EM mechanism.

  19. Impact of polydispersity on multipolar resonant scattering in emulsions.

    PubMed

    Mascaro, Benoit; Brunet, Thomas; Poncelet, Olivier; Aristégui, Christophe; Raffy, Simon; Mondain-Monval, Olivier; Leng, Jacques

    2013-04-01

    The influence of size polydispersity on the resonant acoustic properties of dilute emulsions, made of fluorinated-oil droplets, is quantitatively investigated. Ultrasound attenuation and dispersion measurements on various samples with controlled size polydispersities, ranging from 1% to 13%, are found to be in excellent agreement with predictions based on the independent scattering approximation. By relating the particle-size distribution of the synthesized emulsions to the quality factor of the predicted multipolar resonances, the number of observable acoustic resonances is shown to be imposed by the sample polydispersity. These results are briefly discussed into the context of metamaterials for which scattering resonances are central to their effective properties. PMID:23556570

  20. Resonance formation in low energy electron scattering from uracil

    NASA Astrophysics Data System (ADS)

    Mašín, Zdeněk; Gorfinkiel, Jimena D.

    2014-05-01

    We present detailed ab initio results for resonance formation in low energy electron scattering from uracil obtained with the R-matrix method. We identify a larger number of resonances than any previous theoretical study. Most of these resonances have core-excited shape character and appear to be associated to the ring structure of the molecule. Their link to DEA spectra and to the resonances present in electron scattering from pyrimidine are discussed. Contribution to the Topical Issue "Electron and Positron Induced Processes", edited by Michael Brunger, Radu Campeanu, Masamitsu Hoshino, Oddur Ingólfsson, Paulo Limão-Vieira, Nigel Mason, Yasuyuki Nagashima and Hajime Tanuma.

  1. Spectral separation of optical spin based on antisymmetric Fano resonances

    PubMed Central

    Piao, Xianji; Yu, Sunkyu; Hong, Jiho; Park, Namkyoo

    2015-01-01

    We propose a route to the spectral separation of optical spin angular momentum based on spin-dependent Fano resonances with antisymmetric spectral profiles. By developing a spin-form coupled mode theory for chiral materials, the origin of antisymmetric Fano spectra is clarified in terms of the opposite temporal phase shift for each spin, which is the result of counter-rotating spin eigenvectors. An analytical expression of a spin-density Fano parameter is derived to enable quantitative analysis of the Fano-induced spin separation in the spectral domain. As an application, we demonstrate optical spin switching utilizing the extreme spectral sensitivity of the spin-density reversal. Our result paves a path toward the conservative spectral separation of spins without any need of the magneto-optical effect or circular dichroism, achieving excellent purity in spin density superior to conventional approaches based on circular dichroism. PMID:26561372

  2. The spectral shift between near- and far-field resonances of optical nano-antennas.

    PubMed

    Menzel, Christoph; Hebestreit, Erik; Mühlig, Stefan; Rockstuhl, Carsten; Burger, Sven; Lederer, Falk; Pertsch, Thomas

    2014-04-21

    Within the past several years a tremendous progress regarding optical nano-antennas could be witnessed. It is one purpose of optical nano-antennas to resonantly enhance light-matter interactions at the nanoscale, e.g. the interaction of an external illumination with molecules. In this specific, but in almost all schemes that take advantage of resonantly enhanced electromagnetic fields in the vicinity of nano-antennas, the precise knowledge of the spectral position of resonances is of paramount importance to fully exploit their beneficial effects. Thus far, however, many nano-antennas were only optimized with respect to their far-field characteristics, i.e. in terms of their scattering or extinction cross sections. Although being an emerging feature in many numerical simulations, it was only recently fully appreciated that there exists a subtle but very important difference in the spectral position of resonances in the near-and the far-field. With the purpose to quantify this shift, Zuloaga et al. suggested a Lorentzian model to estimate the resonance shift. Here, we devise on fully analytical grounds a strategy to predict the resonance in the near-field directly from that in the far-field and disclose that the issue is involved and multifaceted, in general. We outline the limitations of our theory if more sophisticated optical nano-antennas are considered where higher order multipolar contributions and higher order antenna resonances become increasingly important. Both aspects are highlighted by numerically studying relevant nano-antennas. PMID:24787879

  3. Resonant Compton Scattering in Highly-Magnetized Pulsars

    NASA Astrophysics Data System (ADS)

    Wadiasingh, Zorawar

    Soft gamma repeaters and anomalous X-ray pulsars are subset of slow-rotating neutron stars, known as magnetars, that have extremely high inferred surface magnetic fields, of the order 100-1000 TeraGauss. Hard, non-thermal and pulsed persistent X-ray emission extending between 10 keV and 230 keV has been seen in a number of magnetars by RXTE, INTEGRAL, and Suzaku. In this thesis, the author considers inner magnetospheric models of such persistent hard X-ray emission where resonant Compton upscattering of soft thermal photons is anticipated to be the most efficient radiative process. This high efficiency is due to the relative proximity of the surface thermal photons, and also because the scattering becomes resonant at the cyclotron frequency. At the cyclotron resonance, the effective cross section exceeds the classical Thomson one by over two orders of magnitude, thereby enhancing the efficiency of continuum production and cooling of relativistic electrons. In this thesis, a new Sokolov and Ternov formulation of the QED Compton scattering cross section for strong magnetic fields is employed in electron cooling and emission spectra calculations. This formalism is formally correct for treating spin-dependent effects and decay rates that are important at the cyclotron resonance. The author presents electron cooling rates at arbitrary interaction points in a magnetosphere using the QED cross sections. The QED effects reduce the rates below high-field extrapolations of older magnetic Thomson results. The author also computes angle-dependent upscattering model spectra, formed using collisional integrals, for uncooled monoenergetic relativistic electrons injected in inner regions of pulsar magnetospheres. These spectra are integrated over closed field lines and obtained for different observing perspectives. The spectral cut-off energies are critically dependent on the observer viewing angles and electron Lorentz factor. It is found that electrons with energies less than

  4. Strong WW scattering chiral lagrangians, unitarity and resonances

    SciTech Connect

    Pelaez, J.R.

    1996-08-01

    Chiral lagrangians provide a model independent description of the strongly interacting symmetry breaking sector. In this work, first we review the LHC sensitivity to the chiral parameters (in the hardest case of non-resonant low-energy WW scattering). Later we show how to reproduce or predict the resonance spectrum by means of dispersion theory and the inverse amplitude method. We present a parameter space scan that covers many different strong WW scattering scenarios.

  5. Aircraft Engine Noise Scattering - A Discontinuous Spectral Element Approach

    NASA Technical Reports Server (NTRS)

    Stanescu, D.; Hussaini, M. Y.; Farassat, F.

    2002-01-01

    The paper presents a time-domain method for computation of sound radiation from aircraft engine sources to the far-field. The effects of nonuniform flow around the aircraft and scattering of sound by fuselage and wings are accounted for in the formulation. Our approach is based on the discretization of the inviscid flow equations through a collocation form of the Discontinuous Galerkin spectral element method. An isoparametric representation of the underlying geometry is used in order to take full advantage of the spectral accuracy of the method. Largescale computations are made possible by a parallel implementation based on message passing. Results obtained for radiation from an axisymmetric nacelle alone are compared with those obtained when the same nacelle is installed in a generic con.guration, with and without a wing.

  6. Low-Intensity Nonlinear Spectral Effects in Compton Scattering

    SciTech Connect

    Hartemann, F V; Albert, F; Siders, C W; Barty, C P

    2010-02-23

    Nonlinear effects are known to occur in Compton scattering light sources, when the laser normalized 4-potential, A = e{radical}-A{sub {mu}}A{sup {mu}}/m{sub 0}c approaches unity. In this letter, it is shown that nonlinear spectral features can appear at arbitrarily low values of A, if the fractional bandwidth of the laser pulse, {Delta}{phi}{sup -1}, is sufficiently small to satisfy A{sup 2} {Delta}{phi} {approx_equal} 1. A three dimensional analysis, based on a local plane-wave, slow-varying envelope approximation, enables the study of these effects for realistic interactions between an electron beam and a laser pulse, and their influence on high-precision Compton scattering light sources.

  7. Angular and spectral light scattering from complex multidielectric coatings

    NASA Astrophysics Data System (ADS)

    Grèzes-Besset, Catherine; Torricini, Didier; Krol, Hélène; Zerrad, Myriam; Lequime, Michel; Amra, Claude

    2011-09-01

    Due to the improvement of deposition technologies and polishing techniques, light scattering has been considerably reduced in optical coatings these last decades, with the result of high quality dense optical filters with minimal losses. However such improvements coupled with modern monitoring techniques have also allowed designing and producing more complex coatings with layer numbers exceeding several hundred in some situations. Within this framework light scattering must again be revisited and analysed in detail, including global loss levels together with angular and spectral analysis. This paper is devoted to the optical balance of sophisticated components for Earth Observation, where the same scene is observed simultaneously in several adjacent wavebands. Self-blocking multilayer stacks are involved to eliminate out-of band harmonics in the instrument but the filter performances are degraded due to an increase of cross talk originating from light scattering. To address this problem we use the theories of light scattering from surface roughness and bulk heterogeneity, which allows to quantity cross-talk levels and choose more adequate filters. A special emphasis is given to the case of hyperspectral filters assemblies located in the focal plane for image filtering.

  8. Anisotropic resonant scattering from polymer photonic crystals.

    PubMed

    Haines, Andrew I; Finlayson, Chris E; Snoswell, David R E; Spahn, Peter; Hellmann, G Peter; Baumberg, Jeremy J

    2012-11-20

    Hyperspectral goniometry reveals anisotropic scattering which dominates the visual appearance of self-assembled polymer opals. The technique allows reconstruction of the reciprocal-space of nanostructures, and indicates that chain defects formed during shear-ordering are responsible for the anisotropy in these samples. Enhanced scattering with improving order is shown to arise from increased effective refractive index contrast, while broadband background scatter is suppressed by absorptive dopants. PMID:22915079

  9. Resonant inelastic x-ray scattering from molecules and atoms

    SciTech Connect

    Arp, U.; Deslattes, R.D.; Miyano, K.E.; Southworth, S.H.

    1995-12-31

    X-ray fluorescence spectroscopy is one of the most powerful methods for the understanding of the electronic structure of matter. We report here on fluorescence experiments in the 2 to 6 keV photon energy range using tunable synchrotron radiation and the resulting experimental programs on resonant inelastic scattering in atoms and on polarization measurements in resonant molecular excitations.

  10. Resonance scattering by fish schools: A comparison of two models.

    PubMed

    Raveau, M; Feuillade, C

    2016-01-01

    The effective medium method is used to investigate resonance scattering from schools of fish with gas-filled swim bladders, as a function of frequency and azimuth. Calculations are also performed with a coupled differential equation model, which incorporates both multiple scattering between fish and wave interference interactions of their scattered fields [Feuillade, Nero, and Love, J. Acoust. Soc. Am. 99, 196-208 (1996)]. A theoretical comparison of the models for idealized spherical schools shows good agreement over the entire resonance region in the forward direction, where interference interactions have a minimal effect. Good agreement is also seen in back scattering at low frequencies, where the wavelength λ≥4s, and s is the average nearest neighbor fish separation. If λ<4s, the models diverge in back scattering, and the effective medium method fails. This can be critically important when migrations of schools to deeper water cause the collective resonance frequency to increase. Multiple scattering interactions are negligible when |4πnf(b)(2)/k|⪅0.01, where n is the fish number density, f(b) is the individual fish scattering amplitude, and k=2π/λ. A comparison with forward scattering data shows very good agreement for both models, and indicates a method for estimating fish abundance. For back scattering data, the effective medium method diverges strongly when λ<4s. PMID:26827014

  11. Resonant light scattering of a laser frequency comb by a quantum dot

    NASA Astrophysics Data System (ADS)

    Konthasinghe, K.; Peiris, M.; Muller, A.

    2014-08-01

    We investigate the spectral and temporal properties of light scattered near resonantly by a single quantum dot when the incident laser field is a frequency comb consisting of a superposition of monochromatic waves equidistant in frequency. Such fields encompass those generated by, e.g., a periodically pulsed laser. A general theoretical treatment for the calculation of first- and second-order correlation functions is given which takes account of spectral diffusion through a slowly varying detuning from resonance, permitting accurate comparison with experiments. We explore the two distinct regimes in which the frequency-comb separation is either larger or smaller than the radiative decay rate. We verify the validity of our calculations by a comparison with experimental data for the case of a bichromatic field and discuss the manifestation of phase coherence between the incoming field and the scattered single-photon wave packet.

  12. Scalar-Pseudoscalar scattering and pseudoscalar resonances

    SciTech Connect

    Albaladejo, M.; Oller, J. A.; Roca, L.

    2011-05-23

    The interactions between the f{sub 0}(980) and a{sub 0}(980) scalar resonances and the lightest pseudoscalar mesons are studied. We first obtain the interacting kernels, without including any ad hoc free parameter, because the lightest scalar resonances are dynamically generated. These kernels are unitarized, giving the final amplitudes, which generate pseudoscalar resonances, associated with the K(1460), {pi}(1300), {pi}(1800), {eta}(1475) and X(1835). We also consider the exotic channels with I = 3/2 and I{sup G} = 1{sup +} quantum numbers. The former could be also resonant in agreement with a previous prediction.

  13. Time-dependent resonant scattering: an analytical approach.

    PubMed

    Lecomte, J M; Kirrander, Adam; Jungen, Ch

    2013-10-28

    A time-dependent description is given of a scattering process involving a single resonance embedded in a set of flat continua. An analytical approach is presented which starts from an incident free particle wave packet and yields the Breit-Wigner cross-section formula at infinite times. We show that at intermediate times the so-called Wigner-Weisskopf approximation is equivalent to a scattering process involving a contact potential. Applications in cold-atom scattering and resonance enhanced desorption of molecules are discussed. PMID:24182008

  14. Time-dependent resonant scattering: An analytical approach

    NASA Astrophysics Data System (ADS)

    Lecomte, J. M.; Kirrander, Adam; Jungen, Ch.

    2013-10-01

    A time-dependent description is given of a scattering process involving a single resonance embedded in a set of flat continua. An analytical approach is presented which starts from an incident free particle wave packet and yields the Breit-Wigner cross-section formula at infinite times. We show that at intermediate times the so-called Wigner-Weisskopf approximation is equivalent to a scattering process involving a contact potential. Applications in cold-atom scattering and resonance enhanced desorption of molecules are discussed.

  15. Multiple fano resonances in spatially compact and spectrally efficient spoof surface plasmon resonators with composite textures.

    PubMed

    Qin, F F; Xiao, J J; Zhang, Q; Liang, W G

    2016-01-01

    Spoof surface plasmons derive their properties from structure resonance rather than from electronic resonance, enabling an extremely high degree of freedom for tuning and modulating different resonances. Here, a composite resonator based on multiscale textured metal surface of different grooves is presented, and spoof localized surface plasmons (LSPs) are shown to emerge and interact coherently. Each band of the spoof LSPs resembles those generated by the homogenously textured surface with the corresponding groove. By adjusting the geometry and filling medium of each substructure in the composite system, we find that the multipole resonant modes sustained by one substructure can couple with those in the other, giving rise to multi-band Fano resonances. Such multiple-Fano resonance structures are spatially more compact while spectrally more comprehensive than usual spoof structures. They can be used for unique resonant devices such as microwave antennas and metasurfaces. PMID:26696158

  16. Novel Trapping and Scattering of Light in Resonant Nanophotonic Structures

    NASA Astrophysics Data System (ADS)

    Hsu, Chia Wei

    Nanophotonic structures provide unique ways to control light and alter its behaviors in ways not possible in macroscopic structures. In this thesis, we explore novel behaviors of light created by nanophotonic structures, with a common theme on resonance effects. The first half of the thesis focuses on a peculiar type of electromagnetic resonance, where the resonance lifetime diverges to infinity. These states, called bound states in the continuum, remain localized in space even though their frequency lie within a continuum of extended modes. We find such states in photonic crystal slabs and the surface of bulk photonic crystals. We show the conditions necessary for them to exist, and provide the first experimental observation of these unusual states. We also show that these states have a topological nature, with conserved and quantized topological charges that govern their generation, evolution, and annihilation. The second half of the thesis concerns light scattering from resonant nanophotonic structures, where resonances can enhance or suppress scattering at particular wavelengths and angles. We show that multiple resonances in one nanostructure and in the same multipole channel generally lead to a scattering dark state where the structure becomes transparent. Based on the coherent interference from multiple scatterers, we show there are geometries that can achieve a sharp structural color where the hue, saturation, and brightness are all viewing-angle independent. We also invent a new type of transparent display based on wavelength-selective light scattering from nanostructures.

  17. Resonating Rays in Light Ion Scattering from AN Optical Potential.

    NASA Astrophysics Data System (ADS)

    Stoyanov, Basil John

    Recent experimental investigations reveal that resonances of composite ion-ion systems are a general phenomenon in light- and heavy-ion scattering. The experimentally observed phenomenon known as the anomalous large-angle scattering (ALAS) of alpha-particle from certain isotopes, such as (alpha)-('40)Ca, manifests itself in the form of successive peaks in the back-scattering excitation function. Earlier theoretical studies were mainly concentrated either on the surface-wave or geometrical-wave description of these phenomena, whereas the pont of view taken here, which is based on the results of physical acoustics, is that the ion-ion scattering amplitude contains both the surface-wave and the geometrical-wave contributions. Therefore a comprehensive approach would be to investigate both of these contributions simultaneously. This is achieved in the present work through a decomposition, by applying the Sommerfeld-Watson and Imai transformations, of the scattering amplitude into its ingredients and by analyzing both the resulting geometrical rays and the surface waves in terms of resonances. This procedure generates a precise mathematical description of resonance processes in ion scattering (via the S-function poles) and at the same time leads in a semi -classical framework to their thorough physical interpretation (via the generalized Bohr-Sommerfeld quantization condition). The existence of resonances in both the geometrical and surface waves emerges from such a description, and is exemplified by numerical calculations for (alpha)-('40)Ca elastic scattering.

  18. Tailoring dielectric resonator geometries for directional scattering and Huygens' metasurfaces

    NASA Astrophysics Data System (ADS)

    Campione, Salvatore; Basilio, Lorena I.; Warne, Larry K.; Sinclair, Michael B.

    2015-02-01

    In this paper we describe a methodology for tailoring the design of metamaterial dielectric resonators, which represent a promising path toward low-loss metamaterials at optical frequencies. We first describe a procedure to decompose the far field scattered by subwavelength resonators in terms of multipolar field components, providing explicit expressions for the multipolar far fields. We apply this formulation to confirm that an isolated high-permittivity cube resonator possesses frequency separated electric and magnetic dipole resonances, as well as a magnetic quadrupole resonance in close proximity to the electric dipole resonance. We then introduce multiple dielectric gaps to the resonator geometry in a manner suggested by perturbation theory, and demonstrate the ability to overlap the electric and magnetic dipole resonances, thereby enabling directional scattering by satisfying the first Kerker condition. We further demonstrate the ability to push the quadrupole resonance away from the degenerate dipole resonances to achieve local behavior. These properties are confirmed through the multipolar expansion and show that the use of geometries suggested by perturbation theory is a viable route to achieve purely dipole resonances for metamaterial applications such as wave-front manipulation with Huygens' metasurfaces. Our results are fully scalable across any frequency bands where high-permittivity dielectric materials are available, including microwave, THz, and infrared frequencies.

  19. High Spectral Resolution Lidar Measurements of Multiple Scattering

    NASA Technical Reports Server (NTRS)

    Eloranta, E. W.; Piironen, P.

    1996-01-01

    The University of Wisconsin High Spectral Resolution Lidar (HSRL) provides unambiguous measurements of backscatter cross section, backscatter phase function, depolarization, and optical depth. This is accomplished by dividing the lidar return into separate particulate and molecular contributions. The molecular return is then used as a calibration target. We have modified the HSRL to use an I2 molecular absorption filter to separate aerosol and molecular signals. This allows measurement in dense clouds. Useful profiles extend above the cloud base until the two way optical depth reaches values between 5 and 6; beyond this, photon counting errors become large. In order to observe multiple scattering, the HSRL includes a channel which records the combined aerosol and molecular lidar return simultaneously with the spectrometer channel measurements of optical properties. This paper describes HSRL multiple scattering measurements from both water and ice clouds. These include signal strengths and depolarizations as a function of receiver field of view. All observations include profiles of extinction and backscatter cross sections. Measurements are also compared to predictions of a multiple scattering model based on small angle approximations.

  20. Plasmonic piezoelectric nanomechanical resonator for spectrally selective infrared sensing.

    PubMed

    Hui, Yu; Gomez-Diaz, Juan Sebastian; Qian, Zhenyun; Alù, Andrea; Rinaldi, Matteo

    2016-01-01

    Ultrathin plasmonic metasurfaces have proven their ability to control and manipulate light at unprecedented levels, leading to exciting optical functionalities and applications. Although to date metasurfaces have mainly been investigated from an electromagnetic perspective, their ultrathin nature may also provide novel and useful mechanical properties. Here we propose a thin piezoelectric plasmonic metasurface forming the resonant body of a nanomechanical resonator with simultaneously tailored optical and electromechanical properties. We experimentally demonstrate that it is possible to achieve high thermomechanical coupling between electromagnetic and mechanical resonances in a single ultrathin piezoelectric nanoplate. The combination of nanoplasmonic and piezoelectric resonances allows the proposed device to selectively detect long-wavelength infrared radiation with unprecedented electromechanical performance and thermal capabilities. These attributes lead to the demonstration of a fast, high-resolution, uncooled infrared detector with ∼80% absorption for an optimized spectral bandwidth centered around 8.8 μm. PMID:27080018

  1. Plasmonic piezoelectric nanomechanical resonator for spectrally selective infrared sensing

    NASA Astrophysics Data System (ADS)

    Hui, Yu; Gomez-Diaz, Juan Sebastian; Qian, Zhenyun; Alù, Andrea; Rinaldi, Matteo

    2016-04-01

    Ultrathin plasmonic metasurfaces have proven their ability to control and manipulate light at unprecedented levels, leading to exciting optical functionalities and applications. Although to date metasurfaces have mainly been investigated from an electromagnetic perspective, their ultrathin nature may also provide novel and useful mechanical properties. Here we propose a thin piezoelectric plasmonic metasurface forming the resonant body of a nanomechanical resonator with simultaneously tailored optical and electromechanical properties. We experimentally demonstrate that it is possible to achieve high thermomechanical coupling between electromagnetic and mechanical resonances in a single ultrathin piezoelectric nanoplate. The combination of nanoplasmonic and piezoelectric resonances allows the proposed device to selectively detect long-wavelength infrared radiation with unprecedented electromechanical performance and thermal capabilities. These attributes lead to the demonstration of a fast, high-resolution, uncooled infrared detector with ~80% absorption for an optimized spectral bandwidth centered around 8.8 μm.

  2. Plasmonic piezoelectric nanomechanical resonator for spectrally selective infrared sensing

    PubMed Central

    Hui, Yu; Gomez-Diaz, Juan Sebastian; Qian, Zhenyun; Alù, Andrea; Rinaldi, Matteo

    2016-01-01

    Ultrathin plasmonic metasurfaces have proven their ability to control and manipulate light at unprecedented levels, leading to exciting optical functionalities and applications. Although to date metasurfaces have mainly been investigated from an electromagnetic perspective, their ultrathin nature may also provide novel and useful mechanical properties. Here we propose a thin piezoelectric plasmonic metasurface forming the resonant body of a nanomechanical resonator with simultaneously tailored optical and electromechanical properties. We experimentally demonstrate that it is possible to achieve high thermomechanical coupling between electromagnetic and mechanical resonances in a single ultrathin piezoelectric nanoplate. The combination of nanoplasmonic and piezoelectric resonances allows the proposed device to selectively detect long-wavelength infrared radiation with unprecedented electromechanical performance and thermal capabilities. These attributes lead to the demonstration of a fast, high-resolution, uncooled infrared detector with ∼80% absorption for an optimized spectral bandwidth centered around 8.8 μm. PMID:27080018

  3. Anisotropic Elastic Resonance Scattering model for the Neutron Transport equation

    SciTech Connect

    Mohamed Ouisloumen; Abderrafi M. Ougouag; Shadi Z. Ghrayeb

    2014-11-24

    The resonance scattering transfer cross-section has been reformulated to account for anisotropic scattering in the center-of-mass of the neutron-nucleus system. The main innovation over previous implementations is the relaxation of the ubiquitous assumption of isotropic scattering in the center-of-mass and the actual effective use of scattering angle distributions from evaluated nuclear data files in the computation of the angular moments of the resonant scattering kernels. The formulas for the high order anisotropic moments in the laboratory system are also derived. A multi-group numerical formulation is derived and implemented into a module incorporated within the NJOY nuclear data processing code. An ultra-fine energy mesh cross section library was generated using these new theoretical models and then was used for fuel assembly calculations with the PARAGON lattice physics code. The results obtained indicate a strong effect of this new model on reactivity, multi-group fluxes and isotopic inventory during depletion.

  4. Electron- and neutrino-nucleus scattering from the quasielastic to the resonance region

    SciTech Connect

    Leitner, T.; Buss, O.; Mosel, U.; Alvarez-Ruso, L.

    2009-03-15

    We present a model for electron and neutrino scattering off nucleons and nuclei focusing on the quasielastic and resonance region. The lepton-nucleon reaction is described within a relativistic formalism that includes, besides quasielastic scattering, the excitation of 13 N* and {delta} resonances and a nonresonant single-pion background. Recent electron scattering data are used for the state-of-the-art parametrizations of the vector form factors; the axial couplings are determined via partial conservation of the axial current and, in the case of the {delta} resonance, the axial form factor is refitted using neutrino-scattering data. Scattering off nuclei is treated within the Giessen Boltzmann-Uehling-Uhlenbeck framework (GiBUU), which takes into account various nuclear effects: the local density approximation for the nuclear ground state, mean-field potentials, and in-medium spectral functions. Results for inclusive scattering off oxygen are presented and, in the case of electron-induced reactions, compared with experimental data and other models.

  5. Biochemical component identification by light scattering techniques in whispering gallery mode optical resonance based sensor

    NASA Astrophysics Data System (ADS)

    Saetchnikov, Vladimir A.; Tcherniavskaia, Elina A.; Saetchnikov, Anton V.; Schweiger, Gustav; Ostendorf, Andreas

    2014-03-01

    Experimental data on detection and identification of variety of biochemical agents, such as proteins (albumin, interferon, C reactive protein), microelements (Na+, Ca+), antibiotic of different generations, in both single and multi component solutions under varied in wide range concentration are represented. Analysis has been performed on the light scattering parameters of whispering gallery mode (WGM) optical resonance based sensor with dielectric microspheres from glass and PMMA as sensitive elements fixed by spin - coating techniques in adhesive layer on the surface of substrate or directly on the coupling element. Sensitive layer was integrated into developed fluidic cell with a digital syringe. Light from tuneable laser strict focusing on and scattered by the single microsphere was detected by a CMOS camera. The image was filtered for noise reduction and integrated on two coordinates for evaluation of integrated energy of a measured signal. As the entrance data following signal parameters were used: relative (to a free spectral range) spectral shift of frequency of WGM optical resonance in microsphere and relative efficiency of WGM excitation obtained within a free spectral range which depended on both type and concentration of investigated agents. Multiplexing on parameters and components has been realized using spatial and spectral parameters of scattered by microsphere light with developed data processing. Biochemical component classification and identification of agents under investigation has been performed by network analysis techniques based on probabilistic network and multilayer perceptron. Developed approach is demonstrated to be applicable both for single agent and for multi component biochemical analysis.

  6. Scattering of universal fermionic clusters in the resonating group method

    NASA Astrophysics Data System (ADS)

    Naidon, Pascal; Endo, Shimpei; García-García, Antonio M.

    2016-02-01

    Mixtures of polarized fermions of two different masses can form weakly bound clusters, such as dimers and trimers, that are universally described by the scattering length between the heavy and light fermions. We use the resonating group method to investigate the low-energy scattering processes involving dimers or trimers. The method reproduces approximately the known particle–dimer and dimer–dimer scattering lengths. We use it to estimate the trimer–trimer scattering length, which is presently unknown, and find it to be positive.

  7. Acoustic swimbladder resonance spectroscopy: Fundamentals in scattering theory

    NASA Astrophysics Data System (ADS)

    Francis, David T. I.; Foote, Kenneth G.

    2003-04-01

    A history of the physics of acoustic resonance is given. The primary, low-frequency, resonant scattering model for air bubbles in water [Minnaert (1933)] is reviewed. Subsequent applications to swimbladdered fish, including models by Andreeva (1964), Love (1978), and Feuillade and Nero (1998), among others, are developed. Reference is made to exemplary measurements of backscattering by Holliday (1972) and Loevik and Hovem (1979), and of forward scattering, or absorption, by Weston (1967) and Diachok (2000), among others. High-frequency resonances are also described, with presentation of both analytical and numerical results for the immersed air bubble. Comparison of these validates the numerical, boundary-element method (BEM). The BEM allows high-frequency resonances to be studied for swimbladders of realistic shapes under pressure and for typical wave-number-swimbladder length products of order 10-40. Implications of high-frequency swimbladder resonance for auditory function in fish are mentioned. [Work supported by ONR.

  8. Dissociation of chloromethanes upon resonant σ* excitation studied by x-ray scattering

    NASA Astrophysics Data System (ADS)

    Bohinc, R.; Žitnik, M.; Bučar, K.; Kavčič, M.; Journel, L.; Guillemin, R.; Marchenko, T.; Simon, M.; Cao, W.

    2013-10-01

    The dissociation process following the Cl K-shell excitation to σ* resonances is studied by high resolution spectroscopy of resonant elastic and inelastic x-ray scattering on CH3Cl, CH2Cl2, CHCl3, and CCl4 molecules. Calculations employing the transition potential and Delta-Kohn-Sham DFT approach are in good agreement with the measured total fluorescence yield and show the presence of a second quasidegenerate group of states with σ* character above the lowest σ* unoccupied molecular orbital for molecules with more than one Cl atom. A bandwidth narrowing and a nonlinear dispersion behavior is extracted from the Kα spectral maps for both σ* resonances. The fitted data indicate that the widths of the Franck-Condon distributions for the first and second σ* resonances are comparable for all the molecules under study. In addition, an asymmetric broadening of the emission peaks is observed for resonant elastic x-ray scattering with zero detuning on both σ* resonances. This is attributed to the fast dissociation, transferring about 0.15 of the scattering probability into higher vibrational modes.

  9. Dissociation of chloromethanes upon resonant σ{sup *} excitation studied by x-ray scattering

    SciTech Connect

    Bohinc, R.; Bučar, K.; Kavčič, M.; Žitnik, M.; Journel, L.; Guillemin, R.; Marchenko, T.; Simon, M.; Cao, W.

    2013-10-07

    The dissociation process following the Cl K-shell excitation to σ{sup *} resonances is studied by high resolution spectroscopy of resonant elastic and inelastic x-ray scattering on CH{sub 3}Cl, CH{sub 2}Cl{sub 2}, CHCl{sub 3}, and CCl{sub 4} molecules. Calculations employing the transition potential and Delta-Kohn-Sham DFT approach are in good agreement with the measured total fluorescence yield and show the presence of a second quasidegenerate group of states with σ{sup *} character above the lowest σ{sup *} unoccupied molecular orbital for molecules with more than one Cl atom. A bandwidth narrowing and a nonlinear dispersion behavior is extracted from the Kα spectral maps for both σ{sup *} resonances. The fitted data indicate that the widths of the Franck-Condon distributions for the first and second σ{sup *} resonances are comparable for all the molecules under study. In addition, an asymmetric broadening of the emission peaks is observed for resonant elastic x-ray scattering with zero detuning on both σ{sup *} resonances. This is attributed to the fast dissociation, transferring about 0.15 of the scattering probability into higher vibrational modes.

  10. Fano resonance scatterings in waveguides with impedance boundary conditions.

    PubMed

    Xiong, Lei; Bi, Wenping; Aurégan, Yves

    2016-02-01

    The resonance scattering theory is used to study the sound propagation in a waveguide with a portion of its wall lined by a locally reacting material. The objective is to understand the effects of the mode coupling in the lined portion on the transmission. It is shown that a zero in the transmission is present when a real resonance frequency of the open system, i.e., the lined portion of the waveguide that is coupled to the two semi-infinite rigid ducts, is equal to the incident frequency. This transmission zero occurs as a Fano resonance-due to the excitation of a trapped mode in the open system. The trapped mode is formed by the interferences of two neighbored modes with complex resonance frequencies. It is also linked to the avoided crossing of eigenvalues of these two modes that occurs near an exceptional point (a subject that has attracted much attention in recent years in different physical domains). The real and complex resonance frequencies of the open system are determined by an equivalent eigenvalue problem of matrix Heff, which describes the eigenvalue problem defined in the finite lined portion (scattering region). With the aid of the eigenvalues and eigenfunctions of matrix Heff, the usual acoustic resonance scattering formula can be extended to describe the coupling effects between the scattering region and the rigid parts of the waveguide. PMID:26936558

  11. Resonant response of electromagnetic scattering from ellipsoid

    NASA Astrophysics Data System (ADS)

    Gavriloaia, Mihai-Bogdan; Vizireanu, Constantin-Radu; Neamtu, Catalin; Preda, Radu; Achimescu, Emanuel; Halunga, Simona

    2015-02-01

    Modern radars must provide in a very short time: existence, mobility and shape of objects evolving in airspace. Evaluation of the object shapes through active research by using synthetic aperture radar is limited in time, resolution, and cost. A new way of processing non-stationary signals is presented in this article. Signals are obtained from the reflection of the electromagnetic field by objects with complex shape when they are irradiated with linear frequency modulated signals. The amplitude of reflected signal is variable on the radio-impulse duration depending on object shape, causing a certain electromagnetic signature. This phenomenon is caused by specific electromagnetic resonance. The reflected signal has maximum amplitude when the frequency of the incident wave is the same with the resonant frequency of the investigated object. The structure of an radar target can be decomposed into simple geometric shapes such as spheres, ellipsoids, prisms, and so on. Using resonant effect that ensures pattern recognition is exemplified by an object with an aerodynamic profile accepted in many component elements of the aircraft, namely - an ellipsoid. It is a geometric shape used extensively in aviation, because it has a very low aerodynamic resistance. The resonant response of ellipsoid is evaluated in a decade frequency band, but the pattern recognition of this shape is enough for an octave band. The resonant response is assessed for cross polarization of incident electromagnetic field, as well. As a result, the radio-impulse shape can be used in a data base for pattern recognition.

  12. Resonant soft X-ray scattering on protein solutions

    NASA Astrophysics Data System (ADS)

    Ye, Dan; Le, Thinh; Wang, Cheng; Zwart, Peter; Gomez, Esther; Gomez, Enrique

    Protein structure is crucial for biological function, such that characterizing protein folding and packing is important for the design of therapeutics and enzymes. We propose resonant soft X-ray scattering (RSOXS) as an approach to study proteins and other biological assemblies in solution. Calculations of the scattering contrast suggest that soft X-ray scattering is more sensitive than hard X-ray scattering, because of contrast generated at the absorption edges of constituent elements such as carbon, nitrogen and oxygen. We have examined the structure of bovine serum albumin (BSA) in solution by RSOXS. We find that by varying incident X-ray energies, we are able to achieve higher scattering contrast near the absorption edge. From our RSOXS scattering result we are able to reconstruct the structure of BSA in 3D. These RSOXS results also agree with hard X-ray experiments, including crystallographic data. Our study demonstrates the potential of RSOXS for studying protein structure in solution.

  13. Polaron hopping in olivine phosphates studied by nuclear resonant scattering

    NASA Astrophysics Data System (ADS)

    Tracy, Sally June

    Valence fluctuations of Fe2+ and Fe3+ were studied in a solid solution of LixFePO4 by nuclear resonant forward scattering of synchrotron x rays while the sample was heated in a diamond-anvil pressure cell. The spectra acquired at different temperatures and pressures were analyzed for the frequencies of valence changes using the Blume-Tjon model of a system with a fluctuating Hamiltonian. These frequencies were analyzed to obtain activation energies and an activation volume for polaron hopping. There was a large suppression of hopping frequency with pressure, giving an anomalously large activation volume. This large, positive value is typical of ion diffusion, which indicates correlated motions of polarons, and Li+ ions that alter the dynamics of both. In a parallel study of NaxFePO4, the interplay between sodium ordering and electron mobility was investigated using a combination of synchrotron x-ray diffraction and nuclear resonant scattering. Conventional Mossbauer spectra were collected while the sample was heated in a resistive furnace. An analysis of the temperature evolution of the spectral shapes was used to identify the onset of fast electron hopping and determine the polaron hopping rate. Synchrotron x-ray diffraction measurements were carried out in the same temperature range. Reitveld analysis of the diffraction patterns was used to determine the temperature of sodium redistribution on the lattice. The diffraction analysis also provides new information about the phase stability of the system. The temperature evolution of the iron site occupancies from the Mossbauer measurements, combined with the synchrotron diffraction results give strong evidence for a relationship between the onset of fast electron dynamics and the redistribution of sodium in the lattice. Measurements of activation barriers for polaron hopping gave fundamental insights about the correlation between electronic carriers and mobile ions. This work established that polaron-ion interactions

  14. Model of resonance scattering of composite particles

    SciTech Connect

    Kuperin, Yu.A.; Makarov, K.A.; Pavlov, B.S.

    1987-04-01

    A model of binary reactions in a system of particles having a nontrivial internal structure is constructed by the theory of extensions of a nonrelativistic Hamiltonian with the addition of a space of internal degrees of freedom. The model is used to describe hadron-hadron scattering at low and intermediate energies.

  15. ARTICLES: Stimulated Raman scattering in resonant nonequilibrium media

    NASA Astrophysics Data System (ADS)

    Khasanov, O. Kh

    1980-12-01

    An analysis is made of the propagation of a short coherent optical pulse in a three-level resonant medium with an essentially nonequidistant spectrum as a function of the degree of preexcitation of the medium. It is found that in addition to self-induced transparency and resonance scattering, stimulated Raman scattering (Stokes or anti-Stokes) should be observed under certain spatial phase-matching conditions. The area theorem is formulated for all radiation components. An analysis is made of the case of propagation of a resonant electromagnetic pulse of frequency ω in a system of three-level atoms having an equidistant spectrum. Under conditions of preexcitation of the medium at the frequency 2ω by longitudinal acoustic pulses, a scattered transverse acoustic wave at the frequency ω may be observed.

  16. A spectrally accurate algorithm for electromagnetic scattering in three dimensions

    NASA Astrophysics Data System (ADS)

    Ganesh, M.; Hawkins, S.

    2006-09-01

    In this work we develop, implement and analyze a high-order spectrally accurate algorithm for computation of the echo area, and monostatic and bistatic radar cross-section (RCS) of a three dimensional perfectly conducting obstacle through simulation of the time-harmonic electromagnetic waves scattered by the conductor. Our scheme is based on a modified boundary integral formulation (of the Maxwell equations) that is tolerant to basis functions that are not tangential on the conductor surface. We test our algorithm with extensive computational experiments using a variety of three dimensional perfect conductors described in spherical coordinates, including benchmark radar targets such as the metallic NASA almond and ogive. The monostatic RCS measurements for non-convex conductors require hundreds of incident waves (boundary conditions). We demonstrate that the monostatic RCS of small (to medium) sized conductors can be computed using over one thousand incident waves within a few minutes (to a few hours) of CPU time. We compare our results with those obtained using method of moments based industrial standard three dimensional electromagnetic codes CARLOS, CICERO, FE-IE, FERM, and FISC. Finally, we prove the spectrally accurate convergence of our algorithm for computing the surface current, far-field, and RCS values of a class of conductors described globally in spherical coordinates.

  17. Polarization of photons scattered by electrons in any spectral distribution

    SciTech Connect

    Chang, Zhe; Lin, Hai-Nan; Jiang, Yunguo

    2014-01-01

    On the basis of the quantum electrodynamics, we present a generic formalism of the polarization for beamed monochromatic photons scattered by electrons in any spectral distribution. The formulae reduce to the components of the Fano matrix when electrons are at rest. We mainly investigate the polarization in three scenarios, i.e., electrons at rest, isotropic electrons with a power-law spectrum, and thermal electrons. If the incident beam is polarized, the polarization is reduced significantly by isotropic electrons at large viewing angles; the degree of polarization caused by thermal electrons is about half of that caused by power-law electrons. If the incident bean is unpolarized, soft γ-rays can lead to about 15% polarization at viewing angles around π/4. For isotropic electrons, one remarkable feature is that the polarization as a function of the incident photon energy always peaks roughly at 1 MeV; this is valid for both the thermal and power-law cases. This feature can be used to distinguish the model of the inverse Compton scattering from that of the synchrotron radiation.

  18. Resonance-spacing tuning over whole free spectral range in a single microring resonator

    NASA Astrophysics Data System (ADS)

    Gao, Ge; Yuan, Shuai; Li, Danping; Xia, Jinsong

    2016-03-01

    In this paper, we present a single microring resonator structure formed by incorporating a reflectivity-tunable loop mirror for the tuning of resonance spacing. Based on the optical mode-splitting in the resonator structure, spacing between two adjacent resonances can be tuned from zero to one whole free spectral range (FSR) by controlling the coupling strength between the two counter-propagating degenerate modes in the microring resonator. In experiment, by integrating metallic microheater, the resonance-spacing tuning over the whole FSR (1.17 nm) is achieved within 9.82 mW heating power dissipation. The device is expected to have potential applications in reconfigurable optical filtering and microwave photonics.

  19. Laser-induced resonant structure in electron-atom scattering

    NASA Astrophysics Data System (ADS)

    Flegel, A. V.; Frolov, M. V.; Manakov, N. L.; Starace, Anthony F.

    2009-11-01

    Orders of magnitude increases are predicted in the cross sections for electron-atom scattering accompanied by absorption or emission of n laser photons for incident electron energies at which the electron, by emitting μ laser photons, can be captured by the atom to form a negative ion. Resonance enhancements are most significant in the plateau region (n gg μ) of the scattered electron spectrum, whose shape is predicted to replicate that of the ion's (n + μ)-photon detachment spectrum.

  20. Probing Nanoscale Pentacene Films by Resonant Raman Scattering

    NASA Astrophysics Data System (ADS)

    He, Rui; Dujovne, Irene; Chen, Liwei; Miao, Qian; Hirjibehedin, Cyrus F.; Pinczuk, Aron; Nuckolls, Colin; Kloc, Christian; Blanchet, Graciela B.

    2005-06-01

    Resonant enhancements of Raman scattering intensities offer the sensitivity required to study nanoscale pentacene films that reach into monolayer thickness. In the results reported here structural characterization of ultra-thin layers and of their fundamental optical properties are investigated by resonant Raman scattering from intra-molecular and inter-molecular vibrations. In this work Raman methods emerge as ideal tools for the study of physics and characterization of ultra-thin nanoscale films of molecular organic materials fabricated on diverse substrates of current and future devices.

  1. Resonant Raman scattering from silicon nanoparticles enhanced by magnetic response.

    PubMed

    Dmitriev, Pavel A; Baranov, Denis G; Milichko, Valentin A; Makarov, Sergey V; Mukhin, Ivan S; Samusev, Anton K; Krasnok, Alexander E; Belov, Pavel A; Kivshar, Yuri S

    2016-05-01

    Enhancement of optical response with high-index dielectric nanoparticles is attributed to the excitation of their Mie-type magnetic and electric resonances. Here we study Raman scattering from crystalline silicon nanoparticles and reveal that magnetic dipole modes have a much stronger effect on the scattering than electric modes of the same order. We demonstrate experimentally a 140-fold enhancement of the Raman signal from individual silicon spherical nanoparticles at the magnetic dipole resonance. Our results confirm the importance of the optically-induced magnetic response of subwavelength dielectric nanoparticles for enhancing light-matter interactions. PMID:27113352

  2. High-order momentum modes by resonant superradiant scattering

    SciTech Connect

    Zhou Xiaoji; Fu Jiageng; Chen Xuzong

    2009-12-15

    The spatial and time evolutions of superradiant scattering are studied theoretically for a weak pump beam with different frequency components traveling along the long axis of an elongated Bose-Einstein condensate. Resulting from the analysis for mode competition between the different resonant channels and the local depletion of the spatial distribution in the superradiant Rayleigh scattering, a method of getting a large number of high-order forward modes by resonant frequency components of the pump beam is provided, which is beneficial to a lager momentum transfer in atom manipulation for the atom interferometry and atomic optics.

  3. Resonant Raman scattering background in XRF spectra of binary samples

    NASA Astrophysics Data System (ADS)

    Sánchez, Héctor Jorge; Leani, Juan José

    2015-02-01

    In x-ray fluorescence analysis, spectra present singular characteristics produced by the different scattering processes. When atoms are irradiated with incident energy lower and close to an absorption edge, scattering peaks appear due to an inelastic process known as resonant Raman scattering. In this work we present theoretical calculations of the resonant Raman scattering contributions to the background of x-ray fluorescence spectra of binary samples of current technological or biological interest. On one hand, a binary alloy of Fe with traces of Mn (Mn: 0.01%, Fe: 99.99%) was studied because of its importance in the stainless steels industries. On the second hand a pure sample of Ti with V traces (Ti: 99%, V: 1%) was analyzed due to the current relevance in medical applications. In order to perform the calculations the Shiraiwa and Fujino's model was used to calculate characteristic intensities and scattering interactions. This model makes certain assumptions and approximations to achieve the calculations, especially in the case of the geometrical conditions and the incident and take-off beams. For the binary sample studied in this work and the considered experimental conditions, the calculations show that the resonant Raman scattering background is significant under the fluorescent peak, affects the symmetry of the peaks and, depending on the concentrations, overcomes the enhancements contributions (secondary fluorescence).

  4. Resonances in low-energy positron-alkali scattering

    NASA Technical Reports Server (NTRS)

    Horbatsch, M.; Ward, S. J.; Mceachran, R. P.; Stauffer, A. D.

    1990-01-01

    Close-coupling calculations were performed with up to five target states at energies in the excitation threshold region for positron scattering from Li, Na and K. Resonances were discovered in the L = 0, 1 and 2 channels in the vicinity of the atomic excitation thresholds. The widths of these resonances vary between 0.2 and 130 MeV. Evidence was found for the existence of positron-alkali bound states in all cases.

  5. Resonantly enhanced Bragg-scattering spectroscopy of an atomic transition

    NASA Astrophysics Data System (ADS)

    Yang, Xudong; Qiao, Cuifang; Li, Chuanliang; Chen, Fenghua

    2016-07-01

    A novel resonantly enhanced Bragg-scattering (REBS) spectroscopy from a population difference grating (PDG) is reported. The PDG is formed by a standing-wave (SW) pump field, which periodically modulates the space population distributions of two levels in the 87Rb D1 line. Then, a probe beam, having identical frequency and orthogonal polarization with the SW pump field, is Bragg-scattered by the PDG. The research achievement shows that the Bragg-scattered light is strongest at an atomic transition, and forms an REBS spectrum with a high signal-to-noise ratio and sub-natural linewidth. The observed REBS can be applied in precise frequency measurements.

  6. Transparent displays enabled by resonant nanoparticle scattering

    NASA Astrophysics Data System (ADS)

    Hsu, Chia Wei; Zhen, Bo; Qiu, Wenjun; Shapira, Ofer; Delacy, Brendan G.; Joannopoulos, John D.; Soljačić, Marin

    2014-01-01

    The ability to display graphics and texts on a transparent screen can enable many useful applications. Here we create a transparent display by projecting monochromatic images onto a transparent medium embedded with nanoparticles that selectively scatter light at the projected wavelength. We describe the optimal design of such nanoparticles, and experimentally demonstrate this concept with a blue-color transparent display made of silver nanoparticles in a polymer matrix. This approach has attractive features including simplicity, wide viewing angle, scalability to large sizes and low cost.

  7. Near-resonance-Rayleigh scattering measurement on a resonant laser-driven barium plasma

    SciTech Connect

    Nee, T.A.

    1985-06-01

    Near-resonance-Rayleigh scattering is used as a space-time-resolved density probe on a resonant laser-driven barium plasma. Feasibility of this technique was investigated. Comparison to other methods such as absorption technique is made and found to be consistent.

  8. Raman Scattering at Resonant or Near-Resonant Conditions: A Generalized Short-Time Approximation

    NASA Astrophysics Data System (ADS)

    Mohammed, Abdelsalam; Sun, Yu-Ping; Miao, Quan; Ågren, Hans; Gel'mukhanov, Faris

    2012-02-01

    We investigate the dynamics of resonant Raman scattering in the course of the frequency detuning. The dephasing in the time domain makes the scattering fast when the photon energy is tuned from the absorption resonance. This makes frequency detuning to act as a camera shutter with a regulated scattering duration and provides a practical tool of controlling the scattering time in ordinary stationary measurements. The theory is applied to resonant Raman spectra of a couple of few-mode model systems and to trans-1,3,5-hexatriene and guanine-cytosine (G-C) Watson-Crick base pairs (DNA) molecules. Besides some particular physical effects, the regime of fast scattering leads to a simplification of the spectrum as well as to the scattering theory itself. Strong overtones appear in the Raman spectra when the photon frequency is tuned in the resonant region, while in the mode of fast scattering, the overtones are gradually quenched when the photon frequency is tuned more than one vibrational quantum below the first absorption resonance. The detuning from the resonant region thus leads to a strong purification of the Raman spectrum from the contamination by higher overtones and soft modes and purifies the spectrum also in terms of avoidance of dissociation and interfering fluorescence decay of the resonant state. This makes frequency detuning a very useful practical tool in the analysis of the resonant Raman spectra of complex systems and considerably improves the prospects for using the Raman effect for detection of foreign substances at ultra-low concentrations.

  9. Resonant Raman scattering from silicon nanoparticles enhanced by magnetic response

    NASA Astrophysics Data System (ADS)

    Dmitriev, Pavel A.; Baranov, Denis G.; Milichko, Valentin A.; Makarov, Sergey V.; Mukhin, Ivan S.; Samusev, Anton K.; Krasnok, Alexander E.; Belov, Pavel A.; Kivshar, Yuri S.

    2016-05-01

    Enhancement of optical response with high-index dielectric nanoparticles is attributed to the excitation of their Mie-type magnetic and electric resonances. Here we study Raman scattering from crystalline silicon nanoparticles and reveal that magnetic dipole modes have a much stronger effect on the scattering than electric modes of the same order. We demonstrate experimentally a 140-fold enhancement of the Raman signal from individual silicon spherical nanoparticles at the magnetic dipole resonance. Our results confirm the importance of the optically-induced magnetic response of subwavelength dielectric nanoparticles for enhancing light-matter interactions.Enhancement of optical response with high-index dielectric nanoparticles is attributed to the excitation of their Mie-type magnetic and electric resonances. Here we study Raman scattering from crystalline silicon nanoparticles and reveal that magnetic dipole modes have a much stronger effect on the scattering than electric modes of the same order. We demonstrate experimentally a 140-fold enhancement of the Raman signal from individual silicon spherical nanoparticles at the magnetic dipole resonance. Our results confirm the importance of the optically-induced magnetic response of subwavelength dielectric nanoparticles for enhancing light-matter interactions. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr07965a

  10. Optically resonant magneto-electric cubic nanoantennas for ultra-directional light scattering

    SciTech Connect

    Sikdar, Debabrata Premaratne, Malin; Cheng, Wenlong

    2015-02-28

    Cubic dielectric nanoparticles are promising candidates for futuristic low-loss, ultra-compact, nanophotonic applications owing to their larger optical coefficients, greater packing density, and relative ease of fabrication as compared to spherical nanoparticles; besides possessing negligible heating at nanoscale in contrast to their metallic counterparts. Here, we present the first theoretical demonstration of azimuthally symmetric, ultra-directional Kerker's-type scattering of simple dielectric nanocubes in visible and near-infrared regions via simultaneous excitation and interference of optically induced electric- and magnetic-resonances up to quadrupolar modes. Unidirectional forward-scattering by individual nanocubes is observed at the first generalized-Kerker's condition for backward-scattering suppression, having equal electric- and magnetic-dipolar responses. Both directionality and magnitude of these unidirectional-scattering patterns get enhanced where matching electric- and magnetic-quadrupolar responses spectrally overlap. While preserving azimuthal-symmetry and backscattering suppression, a nanocube homodimer provides further directionality improvement for increasing interparticle gap, but with reduced main-lobe magnitude due to emergence of side-scattering lobes from diffraction-grating effect. We thoroughly investigate the influence of interparticle gap on scattering patterns and propose optimal range of gap for minimizing side-scattering lobes. Besides suppressing undesired side-lobes, significant enhancement in scattering magnitude and directionality is attained with increasing number of nanocubes forming a linear chain. Optimal directionality, i.e., the narrowest main-scattering lobe, is found at the wavelength of interfering quadrupolar resonances; whereas the largest main-lobe magnitude is observed at the wavelength satisfying the first Kerker's condition. These unique optical properties of dielectric nanocubes thus can revolutionize their

  11. Optically resonant magneto-electric cubic nanoantennas for ultra-directional light scattering

    NASA Astrophysics Data System (ADS)

    Sikdar, Debabrata; Cheng, Wenlong; Premaratne, Malin

    2015-02-01

    Cubic dielectric nanoparticles are promising candidates for futuristic low-loss, ultra-compact, nanophotonic applications owing to their larger optical coefficients, greater packing density, and relative ease of fabrication as compared to spherical nanoparticles; besides possessing negligible heating at nanoscale in contrast to their metallic counterparts. Here, we present the first theoretical demonstration of azimuthally symmetric, ultra-directional Kerker's-type scattering of simple dielectric nanocubes in visible and near-infrared regions via simultaneous excitation and interference of optically induced electric- and magnetic-resonances up to quadrupolar modes. Unidirectional forward-scattering by individual nanocubes is observed at the first generalized-Kerker's condition for backward-scattering suppression, having equal electric- and magnetic-dipolar responses. Both directionality and magnitude of these unidirectional-scattering patterns get enhanced where matching electric- and magnetic-quadrupolar responses spectrally overlap. While preserving azimuthal-symmetry and backscattering suppression, a nanocube homodimer provides further directionality improvement for increasing interparticle gap, but with reduced main-lobe magnitude due to emergence of side-scattering lobes from diffraction-grating effect. We thoroughly investigate the influence of interparticle gap on scattering patterns and propose optimal range of gap for minimizing side-scattering lobes. Besides suppressing undesired side-lobes, significant enhancement in scattering magnitude and directionality is attained with increasing number of nanocubes forming a linear chain. Optimal directionality, i.e., the narrowest main-scattering lobe, is found at the wavelength of interfering quadrupolar resonances; whereas the largest main-lobe magnitude is observed at the wavelength satisfying the first Kerker's condition. These unique optical properties of dielectric nanocubes thus can revolutionize their

  12. Polarized line formation by resonance scattering. II. Conservative case.

    NASA Astrophysics Data System (ADS)

    Ivanov, V. V.; Grachev, S. I.; Loskutov, V. M.

    1997-05-01

    We consider multiple resonance scattering with complete frequency redistribution (CFR) in a semi-infinite conservative atmosphere (photon destruction probability ɛ_I_=0) with the sources at infinite depth. The polarization arising in resonance scattering is completely accounted for. The problem we consider is the resonance-scattering counterpart of the Chandrasekhar-Sobolev problem of Rayleigh scattering in the conservative atmosphere. The numerical data on the matrix source function S(τ) in the atmosphere with conservative dipole resonance scattering (the depolarization parameter W=1) are presented; we assume Doppler profile. The source matrix is found by a non-iterative numerical solution of the matrix Wiener-Hopf integral equation with the matrix {LAMBDA}-operator. Depth dependence of the elements of the source matrix S(τ) is discussed. Some unexpected peculiarities are revealed in the behavior of its polarization terms. The matrix I(z) which is the generalization of the Chandrasekhar H-function to the case of polarized resonance scattering is found by the iterative solution of the Chandrasekhar-type nonlinear matrix integral equation. We present high-accuracy (5 s.f.) numerical data on I(z) for dipole conservative scattering with the Doppler profile. The center-to-limb variation of the degree of polarization in the core of a Doppler broadened resonance line is found. In conservative case, the limiting limb polarization δ_0_ in the core of such a line is 9.4430% (for W=1). The dependence of δ_0_ on the depolarization parameter W is found. Simple interpolation formula, δ_0_=(9.443-38.05sqrt(ɛ)_I_)%, is suggested for the limb polarization of the radiation emerging from an isothermal nearly conservative atmosphere (ɛ_I_<<1, W=1). The data on I(z) are used to find the polarization line profiles and to trace their center-to-limb variation. The asymptotic expansions of S(τ) for τ-{infinity} (deep layers) and of I(z) for z-{infinity} (line wings) are found

  13. Scattering estimation from digital breast tomosynthesis guiding near infrared spectral tomographic reconstruction

    NASA Astrophysics Data System (ADS)

    Michaelsen, Kelly E.; Krishnaswamy, Venkataramanan; Pogue, Brian W.; Poplack, Steven P.; Paulsen, Keith D.

    2013-03-01

    X-ray image pixel intensity and optical scattering are compared for 11 normal subjects to assess the feasibility of using X-ray imaging as a surrogate for optical scattering in NIR spectral tomography. Digital breast tomosynthesis exams, as well as twenty single point reflectance measurements of optical breast scattering are compared for a wide variety of breast sizes and densities to determine if scattering can be accurately predicted based on x-ray attenuation. If implemented, x-ray based scattering estimation will decrease exam time and cost as well as simplify the design of a newly developed integrated near infrared spectral tomography and digital breast tomosynthesis imaging system.

  14. Angular and spectrally resolved investigations of yeast cells by light scattering microscopy and goniometric measurements

    NASA Astrophysics Data System (ADS)

    Stark, Julian; Müller, Dennis; Nothelfer, Steffen; Kienle, Alwin

    2015-07-01

    Spectrally and angular resolved light scattering from yeast cells was studied with a scattering microscope and a goniometer. Different cell models were investigated with help of analytical solutions of Maxwell's equations. It was found that extraction of precise morphological and optical cellular properties from the measured scattering patterns and phase functions requires more sophisticated cell models than standard Mie theory.

  15. Widely tunable two-colour seeded free-electron laser source for resonant-pump resonant-probe magnetic scattering.

    PubMed

    Ferrari, Eugenio; Spezzani, Carlo; Fortuna, Franck; Delaunay, Renaud; Vidal, Franck; Nikolov, Ivaylo; Cinquegrana, Paolo; Diviacco, Bruno; Gauthier, David; Penco, Giuseppe; Ribič, Primož Rebernik; Roussel, Eleonore; Trovò, Marco; Moussy, Jean-Baptiste; Pincelli, Tommaso; Lounis, Lounès; Manfredda, Michele; Pedersoli, Emanuele; Capotondi, Flavio; Svetina, Cristian; Mahne, Nicola; Zangrando, Marco; Raimondi, Lorenzo; Demidovich, Alexander; Giannessi, Luca; De Ninno, Giovanni; Danailov, Miltcho Boyanov; Allaria, Enrico; Sacchi, Maurizio

    2016-01-01

    The advent of free-electron laser (FEL) sources delivering two synchronized pulses of different wavelengths (or colours) has made available a whole range of novel pump-probe experiments. This communication describes a major step forward using a new configuration of the FERMI FEL-seeded source to deliver two pulses with different wavelengths, each tunable independently over a broad spectral range with adjustable time delay. The FEL scheme makes use of two seed laser beams of different wavelengths and of a split radiator section to generate two extreme ultraviolet pulses from distinct portions of the same electron bunch. The tunability range of this new two-colour source meets the requirements of double-resonant FEL pump/FEL probe time-resolved studies. We demonstrate its performance in a proof-of-principle magnetic scattering experiment in Fe-Ni compounds, by tuning the FEL wavelengths to the Fe and Ni 3p resonances. PMID:26757813

  16. Widely tunable two-colour seeded free-electron laser source for resonant-pump resonant-probe magnetic scattering

    NASA Astrophysics Data System (ADS)

    Ferrari, Eugenio; Spezzani, Carlo; Fortuna, Franck; Delaunay, Renaud; Vidal, Franck; Nikolov, Ivaylo; Cinquegrana, Paolo; Diviacco, Bruno; Gauthier, David; Penco, Giuseppe; Ribič, Primož Rebernik; Roussel, Eleonore; Trovò, Marco; Moussy, Jean-Baptiste; Pincelli, Tommaso; Lounis, Lounès; Manfredda, Michele; Pedersoli, Emanuele; Capotondi, Flavio; Svetina, Cristian; Mahne, Nicola; Zangrando, Marco; Raimondi, Lorenzo; Demidovich, Alexander; Giannessi, Luca; de Ninno, Giovanni; Danailov, Miltcho Boyanov; Allaria, Enrico; Sacchi, Maurizio

    2016-01-01

    The advent of free-electron laser (FEL) sources delivering two synchronized pulses of different wavelengths (or colours) has made available a whole range of novel pump-probe experiments. This communication describes a major step forward using a new configuration of the FERMI FEL-seeded source to deliver two pulses with different wavelengths, each tunable independently over a broad spectral range with adjustable time delay. The FEL scheme makes use of two seed laser beams of different wavelengths and of a split radiator section to generate two extreme ultraviolet pulses from distinct portions of the same electron bunch. The tunability range of this new two-colour source meets the requirements of double-resonant FEL pump/FEL probe time-resolved studies. We demonstrate its performance in a proof-of-principle magnetic scattering experiment in Fe-Ni compounds, by tuning the FEL wavelengths to the Fe and Ni 3p resonances.

  17. Widely tunable two-colour seeded free-electron laser source for resonant-pump resonant-probe magnetic scattering

    PubMed Central

    Ferrari, Eugenio; Spezzani, Carlo; Fortuna, Franck; Delaunay, Renaud; Vidal, Franck; Nikolov, Ivaylo; Cinquegrana, Paolo; Diviacco, Bruno; Gauthier, David; Penco, Giuseppe; Ribič, Primož Rebernik; Roussel, Eleonore; Trovò, Marco; Moussy, Jean-Baptiste; Pincelli, Tommaso; Lounis, Lounès; Manfredda, Michele; Pedersoli, Emanuele; Capotondi, Flavio; Svetina, Cristian; Mahne, Nicola; Zangrando, Marco; Raimondi, Lorenzo; Demidovich, Alexander; Giannessi, Luca; De Ninno, Giovanni; Danailov, Miltcho Boyanov; Allaria, Enrico; Sacchi, Maurizio

    2016-01-01

    The advent of free-electron laser (FEL) sources delivering two synchronized pulses of different wavelengths (or colours) has made available a whole range of novel pump–probe experiments. This communication describes a major step forward using a new configuration of the FERMI FEL-seeded source to deliver two pulses with different wavelengths, each tunable independently over a broad spectral range with adjustable time delay. The FEL scheme makes use of two seed laser beams of different wavelengths and of a split radiator section to generate two extreme ultraviolet pulses from distinct portions of the same electron bunch. The tunability range of this new two-colour source meets the requirements of double-resonant FEL pump/FEL probe time-resolved studies. We demonstrate its performance in a proof-of-principle magnetic scattering experiment in Fe–Ni compounds, by tuning the FEL wavelengths to the Fe and Ni 3p resonances. PMID:26757813

  18. Scattering resonances in slow NH3-He collisions

    NASA Astrophysics Data System (ADS)

    Gubbels, Koos B.; van de Meerakker, Sebastiaan Y. T.; Groenenboom, Gerrit C.; Meijer, Gerard; van der Avoird, Ad

    2012-02-01

    We theoretically study slow collisions of NH3 molecules with He atoms, where we focus in particular on the observation of scattering resonances. We calculate state-to-state integral and differential cross sections for collision energies ranging from 10-4 cm-1 to 130 cm-1, using fully converged quantum close-coupling calculations. To describe the interaction between the NH3 molecules and the He atoms, we present a four-dimensional potential energy surface, based on an accurate fit of 4180 ab initio points. Prior to collision, we consider the ammonia molecules to be in their antisymmetric umbrella state with angular momentum j = 1 and projection k = 1, which is a suitable state for Stark deceleration. We find pronounced shape and Feshbach resonances, especially for inelastic collisions into the symmetric umbrella state with j = k = 1. We analyze the observed resonant structures in detail by looking at scattering wavefunctions, phase shifts, and lifetimes. Finally, we discuss the prospects for observing the predicted scattering resonances in future crossed molecular beam experiments with a Stark-decelerated NH3 beam.

  19. Resonant inverse Compton scattering by secondary pulsar plasma

    NASA Astrophysics Data System (ADS)

    Lyubarskii, Yu. E.; Petrova, S. A.

    Neutron stars are known to be rather hot, the temterature scaling a few times 105K. Thermal X-ray photons emitted by the star surface suffer inverse Compton scattering off the particles of pulsar plasma. In the presence of a strong magnetic field the scattering cross-section is essentially enhanced if the photon energy in the particle rest frame equals the cyclotron energy. At typical pulsar conditions the photons near the maximum of the neutron star black-body spectrum are resonantly scattered by the particles with the Lorentz-factors γ ~102 - 103. So resonant inverse Compton scattering is the most efficient for the secondary plasma particles, being an essential energy-loss mechanism in a wide range of pulsar parameters. For the resonant character of the scattering the energy loss depends essentially on the initial particle energy. Since the distribution function of the secondary plasma is broad (γ ~10 - 104), it evolves essentially. The particles with the Lorentz-factors ~102 - 103 are substantially decelerated forming a sharp peak at low energies. The particles at the wings of the initial distribution are not decelerated at all. Thus, the resultant distribution function of the secondary plasma becomes two-humped giving rise to the two-stream instability. The growth rate for the instability is found to be sufficiently high at typical conditions. So the two-stream instability develops readily and leads to an essential increase of plasma oscillations which are likely to be transformed into radio emission. The resonantly upscattered photons are found to gain energies of 1-10 MeV, so that they form an additional component in pulsar gamma-ray spectrum. The corresponding gamma-ray flux is estimated as well.

  20. Resonant magnetic scattering of polarized soft x rays

    SciTech Connect

    Sacchi, M.; Hague, C.F.; Gullikson, E.M.; Underwood, J.

    1997-04-01

    Magnetic effects on X-ray scattering (Bragg diffraction, specular reflectivity or diffuse scattering) are a well known phenomenon, and they also represent a powerful tool for investigating magnetic materials since it was shown that they are strongly enhanced when the photon energy is tuned across an absorption edge (resonant process). The resonant enhancement of the magnetic scattering has mainly been investigated at high photon energies, in order to match the Bragg law for the typical lattice spacings of crystals. In the soft X-ray range, even larger effects are expected, working for instance at the 2p edges of transition metals of the first row or at the 3d edges of rare earths (300-1500 eV), but the corresponding long wavelengths prevent the use of single crystals. Two approaches have been recently adopted in this energy range: (i) the study of the Bragg diffraction from artificial structures of appropriate 2d spacing; (ii) the analysis of the specular reflectivity, which contains analogous information but has no constraints related to the lattice spacing. Both approaches have their own specific advantages: for instance, working under Bragg conditions provides information about the (magnetic) periodicity in ordered structures, while resonant reflectivity can easily be related to electronic properties and absorption spectra. An important aspect common to all the resonant X-ray scattering techniques is the element selectivity inherent to the fact of working at a specific absorption edge: under these conditions, X-ray scattering becomes in fact a spectroscopy. Results are presented for films of iron and cobalt.

  1. Resonant Soft X-ray Scattering for Soft Materials

    NASA Astrophysics Data System (ADS)

    Wang, Cheng; Young, Athony; Hexemer, Alexander; Padmore, Howard

    2015-03-01

    Over the past a few years, we have developed Resonant Soft X-ray Scattering (RSoXS) and constructed the first dedicated resonant soft x-ray scattering beamline at the Advanced Light Source, LBNL. RSoXS combines soft x-ray spectroscopy with x-ray scattering thus offers statistical information for 3D chemical morphology over a large length scale range from nanometers to micrometers. Its unique chemical sensitivity, large accessible size scale, molecular bond orientation sensitivity with polarized x-rays and high coherence have shown great potential for chemical/morphological structure characterization for many classes of materials. Some recent development of in-situ soft x-ray scattering with in-vacuum sample environment will be discussed. In order to study sciences in naturally occurring conditions, we need to overcome the sample limitations set by the low penetration depth of soft x-rays and requirement of high vacuum. Adapting to the evolving environmental cell designs utilized increasingly in the Electron Microscopy community, customized designed liquid/gas environmental cells will enable soft x-ray scattering experiments on biological, electro-chemical, self-assembly, and hierarchical functional systems in both static and dynamic fashion. Recent RSoXS results on organic electronics, block copolymer thin films, and membrane structure will be presented.

  2. Parallel Spectral Acquisition with an Ion Cyclotron Resonance Cell Array.

    PubMed

    Park, Sung-Gun; Anderson, Gordon A; Navare, Arti T; Bruce, James E

    2016-01-19

    Mass measurement accuracy is a critical analytical figure-of-merit in most areas of mass spectrometry application. However, the time required for acquisition of high-resolution, high mass accuracy data limits many applications and is an aspect under continual pressure for development. Current efforts target implementation of higher electrostatic and magnetic fields because ion oscillatory frequencies increase linearly with field strength. As such, the time required for spectral acquisition of a given resolving power and mass accuracy decreases linearly with increasing fields. Mass spectrometer developments to include multiple high-resolution detectors that can be operated in parallel could further decrease the acquisition time by a factor of n, the number of detectors. Efforts described here resulted in development of an instrument with a set of Fourier transform ion cyclotron resonance (ICR) cells as detectors that constitute the first MS array capable of parallel high-resolution spectral acquisition. ICR cell array systems consisting of three or five cells were constructed with printed circuit boards and installed within a single superconducting magnet and vacuum system. Independent ion populations were injected and trapped within each cell in the array. Upon filling the array, all ions in all cells were simultaneously excited and ICR signals from each cell were independently amplified and recorded in parallel. Presented here are the initial results of successful parallel spectral acquisition, parallel mass spectrometry (MS) and MS/MS measurements, and parallel high-resolution acquisition with the MS array system. PMID:26669509

  3. Resonance electronic Raman scattering in rare earth crystals

    SciTech Connect

    Williams, G.M.

    1988-11-10

    The intensities of Raman scattering transitions between electronic energy levels of trivalent rare earth ions doped into transparent crystals were measured and compared to theory. A particle emphasis was placed on the examination of the effect of intermediate state resonances on the Raman scattering intensities. Two specific systems were studied: Ce/sup 3 +/(4f/sup 1/) in single crystals of LuPO/sub 4/ and Er/sup 3 +/(4f/sup 11/) in single crystals of ErPO/sub 4/. 134 refs., 92 figs., 33 tabs.

  4. Resonant enhancement of Raman scattering in metamaterials with hybrid electromagnetic and plasmonic resonances

    NASA Astrophysics Data System (ADS)

    Guddala, Sriram; Narayana Rao, D.; Ramakrishna, S. Anantha

    2016-06-01

    A tri-layer metamaterial perfect absorber of light, consisting of (Al/ZnS/Al) films with the top aluminum layer patterned as an array of circular disk nanoantennas, is investigated for resonantly enhancing Raman scattering from C60 fullerene molecules deposited on the metamaterial. The metamaterial is designed to have resonant bands due to plasmonic and electromagnetic resonances at the Raman pump frequency (725 nm) as well as Stokes emission bands. The Raman scattering from C60 on the metamaterial with resonantly matched bands is measured to be enhanced by an order of magnitude more than C60 on metamaterials with off-resonant absorption bands peaking at 1090 nm. The Raman pump is significantly enhanced due to the resonance with a propagating surface plasmon band, while the highly impedance-matched electromagnetic resonance is expected to couple out the Raman emission efficiently. The nature and hybridization of the plasmonic and electromagnetic resonances to form compound resonances are investigated by numerical simulations.

  5. Effective-range approximations for resonant scattering of cold atoms

    NASA Astrophysics Data System (ADS)

    Blackley, Caroline L.; Julienne, Paul S.; Hutson, Jeremy M.

    2014-04-01

    Studies of cold atom collisions and few-body interactions often require the energy dependence of the scattering phase shift, which is usually expressed in terms of an effective-range expansion. We use accurate coupled-channel calculations on 6Li, 39K, and 133Cs to explore the behavior of the effective range in the vicinity of both broad and narrow Feshbach resonances. We show that commonly used expressions for the effective range break down dramatically for narrow resonances and near the zero crossings of broad resonances. We present an alternative parametrization of the effective range that is accurate through both the pole and the zero crossing for both broad and narrow resonances. However, the effective-range expansion can still fail at quite low collision energies, particularly around narrow resonances. We demonstrate that an analytical form of an energy and magnetic-field-dependent phase shift, based on multichannel quantum defect theory, gives accurate results for the energy-dependent scattering length.

  6. Spectral Kinetic Simulation of the Ideal Multipole Resonance Probe

    NASA Astrophysics Data System (ADS)

    Gong, Junbo; Wilczek, Sebastian; Szeremley, Daniel; Oberrath, Jens; Eremin, Denis; Dobrygin, Wladislaw; Schilling, Christian; Friedrichs, Michael; Brinkmann, Ralf Peter

    2015-09-01

    The term Active Plasma Resonance Spectroscopy (APRS) denotes a class of diagnostic techniques which utilize the natural ability of plasmas to resonate on or near the electron plasma frequency ωpe: An RF signal in the GHz range is coupled into the plasma via an electric probe; the spectral response of the plasma is recorded, and a mathematical model is used to determine plasma parameters such as the electron density ne or the electron temperature Te. One particular realization of the method is the Multipole Resonance Probe (MRP). The ideal MRP is a geometrically simplified version of that probe; it consists of two dielectrically shielded, hemispherical electrodes to which the RF signal is applied. A particle-based numerical algorithm is described which enables a kinetic simulation of the interaction of the probe with the plasma. Similar to the well-known particle-in-cell (PIC), it contains of two modules, a particle pusher and a field solver. The Poisson solver determines, with the help of a truncated expansion into spherical harmonics, the new electric field at each particle position directly without invoking a numerical grid. The effort of the scheme scales linearly with the ensemble size N.

  7. Spectrally Resolved Magnetic Resonance Imaging of the XenonBiosensor

    SciTech Connect

    Hilty, Christian; Lowery, Thomas; Wemmer, David; Pines, Alexander

    2005-07-15

    Due to its ability to non-invasively record images, as well as elucidate molecular structure, nuclear magnetic resonance is the method of choice for applications as widespread as chemical analysis and medical diagnostics. Its detection threshold is, however, limited by the small polarization of nuclear spins in even the highest available magnetic fields. This limitation can, under certain circumstances, be alleviated by using hyper-polarized substances. Xenon biosensors make use of the sensitivity gain of hyperpolarized xenon to provide magnetic resonance detection capability for a specific low-concentration target. They consist of a cryptophane cage, which binds one xenon atom, and which has been connected via a linker to a targeting moiety such as a ligand or antibody. Recent work has shown the possibility of using the xenon biosensor to detect small amounts of a substance in a heterogeneous environment by NMR. Here, we demonstrate that magnetic resonance (MR) provides the capability to obtain spectrally and spatially resolved images of the distribution of immobilized biosensor, opening the possibility for using the xenon biosensor for targeted imaging.

  8. Time Delay in Neutron-Alpha Resonant Scattering

    SciTech Connect

    Hoop, Bernard; Hale, Gerald M.

    2011-10-24

    Time delay analysis of neutron-alpha resonant scattering cross sections supports characterization of the lowest 3/2{sup +} level in {sup 5}He as fundamentally an n-{alpha} resonance on the second Riemann energy sheet of both n-{alpha} and deuteron-{sup 3}H channels, with an associated shadow pole on a different unphysical sheet that, through its associated zero on the physical sheet, contributes to the large {sup 4}He(n,d){sup 3}H cross section.

  9. Gyro-resonant scattering of radiation belt electrons during the solar minimum by fast magnetosonic waves

    NASA Astrophysics Data System (ADS)

    Shprits, Yuri Y.; Runov, Andrei; Ni, Binbin

    2013-02-01

    In the current study, we perform statistical analysis of the magnetosonic (MS) waves (also often referred to as extremely low frequency (ELF) equatorial noise) in the range between the ion cyclotron frequency and the lower hybrid resonance frequency within 10° of the magnetic equator. Observations were made between 2 and 9 RE using THEMIS Filter Bank (FBK) data. ELF waves with spectral power exceeding 10-6 nT2/Hz are registered in ~3% of all samples in the inner magnetosphere. The survey has shown that, during the solar minimum, the average amplitude of equatorial ELF waves is less than 0.025 nT. Interpreting ELF events as MS waves, we have evaluated the corresponding wave-induced resonant scattering coefficients of radiation belt energetic electrons. We also study the effect of heavy ions on the scattering rates. The analysis reveals that the scattering by magnetosonic waves for various plasma compositions during geomagnetically quiet times is by up to two orders of magnitude slower than was previously reported and cannot significantly contribute to the long-term dynamics of the radiation belts. Computed electron scattering rates by magnetosonic waves extends to higher αeq when the fraction of H+ in the plasma decreases, while the range of pitch angles for which resonance occurs remains relatively insensitive to the plasma composition. While inclusion of multi-ion species into the wave dispersion relation produces noticeable changes in bounce-averaged scattering rates, the average rates are still significantly below typical scattering rates of chorus or hiss waves.

  10. Evidence of scattering effects influenced by plasma flows in C VI 1548 Å, 1550 Å spectral lines emitted from the Sun

    NASA Astrophysics Data System (ADS)

    Gontikakis, C.; Vial, J.-C.

    2016-05-01

    Aims: We search for, and study, individual spectral profiles where the complex shape of the C iv 1548 Å line is different from the shape of the simultaneously recorded C iv 1550 Å line. Such an asymmetry is not expected for line emission resulting from collisional excitation. Therefore we propose an explanation of these observations through the differential effect of velocity fields on resonant scattering. Methods: We analyse spectra recorded with the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) on the Solar and Heliospheric Observatory (SOHO) over active region, NOAA 8541 as well as a second data set on the quiet Sun. We perform Gaussian fits on the individual profiles with two or three Gaussian functions. Moreover, we parameterize the profile asymmetries by calculating the intensity ratios I1548/I1550, from the derived Gaussian functions. We also calculate artificial spectral profiles emitted from two plasma volumes, which have different line of sight motions and where the plasma emission is influenced by resonant scattering. Results: We locate three small regions in NOAA 8541 which have spectral asymmetries. There the profiles have two or three spectral components, with different intensity ratios. Artificial profiles show that two plasma volumes, having distinct velocities relative to the observer, may reproduce the observed profiles, under the influence of resonant scattering. Conclusions: Asymmetric profiles, found in an active region, can be used as a diagnostic for the importance of resonant scattering in transition region plasma.

  11. Resonant inelastic x-ray scattering at the limit of subfemtosecond natural lifetime

    SciTech Connect

    Marchenko, T.; Journel, L.; Marin, T.; Guillemin, R.; Carniato, S.; Simon, M.; Zitnik, M.; Kavcic, M.; Bucar, K.; Mihelic, A.; Hoszowska, J.; Cao, W.

    2011-04-14

    We present measurements of the resonant inelastic x-ray scattering (RIXS) spectra of the CH{sub 3}I molecule in the hard-x-ray region near the iodine L{sub 2} and L{sub 3} absorption edges. We show that dispersive RIXS spectral features that were recognized as a fingerprint of dissociative molecular states can be interpreted in terms of ultrashort natural lifetime of {approx}200 attoseconds in the case of the iodine L-shell core-hole. Our results demonstrate the capacity of the RIXS technique to reveal subtle dynamical effects in molecules with sensitivity to nuclear rearrangement on a subfemtosecond time scale.

  12. Resonant and non-resonant X-ray scattering from C 70

    NASA Astrophysics Data System (ADS)

    Guo, Jinghua; Skytt, Per; Wassdahl, Nial; Nordgren, Joseph; Luo, Yi; Vahtras, Olav; Ågren, Hans

    1995-03-01

    Resonant and non-resonant X-ray scattering spectra of the C 70 molecule are presented and analyzed by ab initio Hartree-Fock calculations using a newly developed formalism for symmetry selective inelastic X-ray scattering. Compared to C 60, a weak excitation energy dependence of the spectra features is observed. The change from 'soccer-ball' (I h) to 'rugby-ball' (D 5h) shapes leads to less symmetry selectivity but larrger polarization selectivity. In contrast to C 60, the RIXS spectrum of C 70 molecule is dense even for narrow-band excitation.

  13. scattering and D meson resonances from lattice QCD

    NASA Astrophysics Data System (ADS)

    Mohler, Daniel; Prelovsek, Sasa; Woloshyn, R. M.

    2013-02-01

    A first exploratory lattice QCD simulation is presented, aimed at extracting the masses and widths of the broad scalar D0*(2400) and the axial D1(2430) charm-light resonances. For that purpose Dπ and D*π scattering are simulated, and the resonance parameters are extracted using a Breit-Wigner fit of the resulting phase shifts. We use a single two-flavor dynamical ensemble with mπ≈266MeV, a≃0.124fm and a rather small volume V=163×32. The resulting D0*(2400) mass is 351±21MeV above the spin average (1)/(4)(mD+3mD*), in agreement with the experimental value of 347±29MeV above. The resulting D0*→Dπ coupling, glat=2.55±0.21GeV, is close to the experimental value gexp⁡≤1.92±0.14GeV, where g parametrizes the width Γ≡g2p*/s. The resonance parameters for the broad D1(2430) are also found close to the experimental values; these are obtained by appealing to the heavy quark limit, where the neighboring resonance D1(2420) is narrow. The calculated I=1/2 scattering lengths are a0=0.81±0.14fm for Dπ and a0=0.81±0.17fm for D*π scattering. The simulation of the scattering in these channels incorporates quark-antiquark as well as multihadron interpolators, and the distillation method is used for contractions. In addition, the ground and several excited charm-light and charmonium states with various JP are calculated using standard quark-antiquark interpolators.

  14. Tunable resonator-based devices for producing variable delays and narrow spectral linewidths

    NASA Technical Reports Server (NTRS)

    Savchenkov, Anatoliy (Inventor); Maleki, Lutfollah (Inventor); Matsko, Andrey B. (Inventor); Ilchenko, Vladimir (Inventor)

    2006-01-01

    Devices with two or more coupled resonators to produce narrow spectral responses due to interference of signals that transmit through the resonators and techniques for operating such devices to achieve certain operating characteristics are described. The devices may be optical devices where optical resonators such as whispering gallery mode resonators may be used. In one implementation, at least one of the coupled optical resonators is a tunable resonator and is tuned to change its resonance frequency to tune the spectral response of the device. The described devices and techniques may be applied in optical filters, optical delays, optical waveform generators, and other applications.

  15. 4 f excitations in Ce Kondo lattices studied by resonant inelastic x-ray scattering

    NASA Astrophysics Data System (ADS)

    Amorese, A.; Dellea, G.; Fanciulli, M.; Seiro, S.; Geibel, C.; Krellner, C.; Makarova, I. P.; Braicovich, L.; Ghiringhelli, G.; Vyalikh, D. V.; Brookes, N. B.; Kummer, K.

    2016-04-01

    The potential of resonant inelastic soft x-ray scattering to measure 4 f crystal electric-field excitation spectra in Ce Kondo lattices has been examined. Spectra have been obtained for several Ce systems and show a well-defined structure determined by crystal-field, spin-orbit, and charge-transfer excitations only. The spectral shapes of the excitation spectra can be well understood in the framework of atomic multiplet calculations. For CeCu2Si2 we found notable disagreement between the inelastic x-ray-scattering spectra and theoretical calculations when using the crystal-field scheme proposed from inelastic neutron scattering. Modified sets of crystal-field parameters yield better agreement. Our results also show that, with the very recent improvements of soft x-ray spectrometers in resolution to below 30 meV at the Ce M4 ,5 edges, resonant inelastic x-ray scattering could be an ideal tool to determine the crystal-field scheme in Ce Kondo lattices and other rare-earth compounds.

  16. Dependence of the spectral diffuse-direct irradiance ratio on aerosol spectral distribution and single scattering albedo

    NASA Astrophysics Data System (ADS)

    Kaskaoutis, D. G.; Kambezidis, H. D.; Dumka, U. C.; Psiloglou, B. E.

    2016-09-01

    This study investigates the modification of the clear-sky spectral diffuse-direct irradiance ratio (DDR) as a function of solar zenith angle (SZA), spectral aerosol optical depth (AOD) and single scattering albedo (SSA). The solar spectrum under various atmospheric conditions is derived with Simple Model of the Atmospheric Radiative Transfer of Sunshine (SMARTS) radiative transfer code, using the urban and continental aerosol models as inputs. The spectral DDR can be simulated with great accuracy by an exponentially decreasing curve, while the aerosol optical properties strongly affect the scattering processes in the atmosphere, thus modifying the DDR especially in the ultraviolet (UV) spectrum. Furthermore, the correlation between spectral DDR and spectral AOD can be represented precisely by an exponential function and can give valuable information about the dominance of specific aerosol types. The influence of aerosols on spectral DDR increases with increasing SZA, while the simulations using the urban aerosol model as input in SMARTS are closer to the measurements taken in the Athens urban environment. The SMARTS simulations are interrelated with spectral measurements and can be used for indirect estimations of SSA. Overall, the current work provides some theoretical approximations and functions that help in understanding the dependence of DDR on astronomical and atmospheric parameters.

  17. Resonance Scattering Mechanisms in Solids and at Solid Surfaces.

    NASA Astrophysics Data System (ADS)

    Gerber, Andrew D.

    1987-09-01

    The concept of resonance electron scattering is applied to two very different solid state systems, one at the surface of a solid and one in the bulk. In part I, the problem of resonance scattering of electrons from molecules adsorbed on a metallic surface is examined. An analysis is made of the factors leading to the broadening and energy shift of the e -N _{2} vibrational excitation cross sections as compared to their gas phase analogues. Two effects are found to be important: the breaking of the molecular symmetry by the surface, and the influence of the metallic image potential. Multiple scattering calculations verify that these mechanisms produce a broadening and energy shift in the range of those seen experimentally. In part II, a new mechanism is formulated for the attenuation of ultrasound in mixed valence metals. The mechanism is based on the coupling of phonons to electrons in localized, atomic-like f-levels. The local nature of the interaction gives rise to a large enhancement over the standard (Pippard) result, especially in the limit of short electron mean free path. The mechanism also produces a 'bump' in the attenuation coefficient as a function of temperature, offering an explanation for the experimentally observed 12 K feature of UPt_{3} . A calculation of the attenuation coefficient for a mixed valence lattice reveals further enhancement and structure caused by coherent absorption at f-levels in many unit cells. The effects of degeneracy and correlation are examined in a calculation of the ultrasound attenuation for a system containing dilute Kondo impurities. The unifying theme of this work is the strong interaction between electrons and vibrational modes resulting from the trapping of electrons in localized resonance states. This mechanism has previously been seen to be of great importance for electron-molecule collisions in the gas phase. In the present work, its importance is demonstrated for scattering processes in solids and at solid surfaces

  18. Scattering of an ultrashort electromagnetic radiation pulse by an atom in a broad spectral range

    SciTech Connect

    Astapenko, V. A.

    2011-02-15

    The scattering of an ultrashort electromagnetic pulse by atomic particles is described using a consistent quantum-mechanical approach taking into account excitation of a target and nondipole electromagnetic interaction, which is valid in a broad spectral range. This approach is applied to the scattering of single- and few-cycle pulses by a multielectron atom and a hydrogen atom. Scattering spectra are obtained for ultrashort pulses of different durations. The relative contribution of 'elastic' scattering of a single-cycle pulse by a hydrogen atom is studied in the high-frequency limit as a function of the carrier frequency and scattering angle.

  19. High spectral resolution lidar to measure optical scattering properties of atmospheric aerosols. I - Theory and instrumentation

    NASA Technical Reports Server (NTRS)

    Shipley, S. T.; Tracy, D. H.; Eloranta, E. W.; Roesler, F. L.; Weinman, J. A.; Trauger, J. T.; Sroga, J. T.

    1983-01-01

    A high spectral resolution lidar technique to measure optical scattering properties of atmospheric aerosols is described. Light backscattered by the atmosphere from a narrowband optically pumped oscillator-amplifier dye laser is separated into its Doppler broadened molecular and elastically scattered aerosol components by a two-channel Fabry-Perot polyetalon interferometer. Aerosol optical properties, such as the backscatter ratio, optical depth, extinction cross section, scattering cross section, and the backscatter phase function, are derived from the two-channel measurements.

  20. Study of the resonant scattering in the Perseus cluster core with ASTRO-H SXS

    NASA Astrophysics Data System (ADS)

    Konami, Saori; Sato, Kosuke; Ohashi, Takaya; Churazov, Eugene; Zhuravleva, Irina; Sunyaev, Rashid

    Resonance lines from cores of galaxy clusters have significant optical depth, as predicted by Gilfanov, Sunyaev & Churazov (1987). We can constrain turbulence velocity from the level of suppression of the resonance lines, providing a good measure of dynamical condition of gas. The Soft X-ray Spectrometer (SXS) onboard ASTRO-H is a high-resolution spectrometer and capable of separating resonance lines from other line components. It is important to estimate the flux contamination due to the point spread function (PSF) of the X-ray telescope ~1.5’. Zhuravleva et al. (2013) constructed spectral models for the Perseus cluster which took into account modifications of line fluxes and shapes due to the resonant scattering effect as well as by radial variations of density, temperature and abundances of heavy elements. Line broadening by small-scale motions were also included. We performed simulation of these models by taking into account the pixel layout of SXS and PSF effect. The suppression of resonance line from H-like Fe will enable us to constrain gas velocities below 300 km/sec.

  1. Spectral reconstruction by scatter analysis for a linear accelerator photon beam.

    PubMed

    Jalbout, Wassim T; Spyrou, Nicholas M

    2006-05-01

    Pre-existing methods for photon beam spectral reconstruction are briefly reviewed. An alternative reconstruction method by scatter analysis for linear accelerators is introduced. The method consists in irradiating a small plastic phantom at standard 100 cm SSD and inferring primary beam energy spectral information based on the measurement with a standard Farmer chamber of scatter around the phantom at several specific scatter angles: a scatter curve is measured which is indicative of the primary spectrum at hand. A Monte Carlo code is used to simulate the scatter measurement set-up and predict the relative magnitude of scatter measurements for mono-energetic primary beams. Based on mono-energetic primary scatter data, measured scatter curves are analysed and the spectrum unfolded as the sum of mono-energetic individual energy bins using the Schiff bremsstrahlung model. The method is applied to an Elekta/SL18 6 MV photon beam. The reconstructed spectrum matches the Monte Carlo calculated spectrum for the same beam within 6.2% (average error when spectra are compared bin by bin). Depth dose values calculated for the reconstructed spectrum agree with physically measured depth dose data to within 1%. Scatter analysis is preliminarily shown to have potential as a practical spectral reconstruction method requiring few measurements under standard 100 cm SSD and feasible in any radiotherapy department using a phantom and a Farmer chamber. PMID:16625037

  2. A resonant scattering formalism for a fluid loaded elastic spherical near a planar boundary

    NASA Astrophysics Data System (ADS)

    Bishop, Garner

    2002-11-01

    Free field scattering from stationary fluid loaded elastic targets is well known and understood in terms of free field resonant scattering theory (RST), that it is given by the superposition of resonant and background components, and that the resonant components can be isolated by subtraction of an appropriate background. Backgrounds for isolating free field resonance spectra are well known. However, RST for scattering from a fluid loaded elastic target near a planar boundary where target scattering is accompanied by target-boundary scattering is less well known. A T-matrix formalism for plane wave scattering from rigid and soft spheres near a planar penetrable boundary is generalized to include a fluid loaded elastic spherical shell and RST is used to replace the free field T-matrix for the elastic shell that occurs within the formalism. It is shown that target-boundary scattering couples resonant and background components, couples modal resonances, and produces super-resonances. A background is introduced and it is shown that while background scattering is suppressed, coupled background and resonant scattering is not. Numerical results demonstrate some of the effects of target boundary scattering on the free field resonant spectrum of the shell as well as the dependence of target-boundary scattering on target.

  3. On the resonance structure in nucleon-nucleon scattering

    NASA Astrophysics Data System (ADS)

    Kloet, W. M.; Tjon, J. A.

    1981-10-01

    A possible explanation of resonance-like structure in 1D 2 and 3F 3 proton-proton phase parameters at medium energy is suggested by the analysis of an exactly soluble coupled channel model. Looping in the Argand plot is mainly due to the nucleon-delta branch cut. This effect is already present in the NΔ box diagram, but is modified by higher order multiple scattering. Poles occur close to the NΔ branch point and originate from left-hand singularities in the unphysical sheet.

  4. Nuclear resonance scattering measurement of human iron stores

    SciTech Connect

    Wielopolski, L.; Ancona, R.C.; Mossey, R.T.; Vaswani, A.N.; Cohn, S.H.

    1985-07-01

    Hepatic iron stores were measured noninvasively in 31 patients (thalassemia, hemodialysis, hemosiderosis, refractory anemia) with suspected iron overload, employing a nuclear resonance scattering (NRS) technique. The thalassemia patients were undergoing desferrioxamine chelation therapy during the NRS measurements. The hemodialysis patients were measured before chelation therapy. Iron levels measured by NRS were in general agreement with those determined in liver biopsies by atomic absorption spectroscopy. In addition, NRS measurements from the thorax of some of these patients suggest that this method may also prove useful for clinical assessment of cardiac iron.

  5. Resonant impulsive-stimulated Raman scattering on malachite green

    SciTech Connect

    Chesnoy, J.; Mokhtari, A.

    1988-10-01

    We have studied in the femtosecond regime the transient dynamics of dichroism (anisotropic absorption), birefringence, and frequency shift induced by an intense femtosecond pump beam in the dye malachite green in solution. Vibrational quantum beats were observed superimposed on the saturated absorption and dispersion signals and quantitatively explained in terms of impulsive-stimulated Raman scattering close to an electronic resonance. The selectivity for observation of the vibrations in the two electronic states is described for the different experimental schemes. We discuss the access to vibrational and electronic dynamics in both ground and excited electronic states and compare the possibilities to those of previous techniques.

  6. Anion Photoelectron Angular Distributions: Electron Scattering Resonances in Photodetachment

    NASA Astrophysics Data System (ADS)

    Mabbs, Richard

    2012-06-01

    To a large degree the photoelectron angular distributions (PAD) of anionic species represent signatures of the bound parent orbital. However, these angular distributions are also influenced by interaction of the outgoing electron with the neutral (atomic, molecular or cluster) residue. The electron kinetic energy evolution (eKE) of the PAD is presented for a number of different species (from molecular to cluster anion), showing the often striking effect of excitation of temporary excited anionic states. These cases highlight the influence of different types of electron-molecule scattering resonances in photodetachment dynamics. Additionally, the possibility of using the eKE evolution of the PAD for structural elucidation is discussed.

  7. Multiphonon resonant Raman scattering in MoS{sub 2}

    SciTech Connect

    Gołasa, K. Grzeszczyk, M.; Wysmołek, A.; Babiński, A.; Leszczyński, P.; Faugeras, C.; Nicolet, A. A. L.; Potemski, M.

    2014-03-03

    Optical emission spectrum of a resonantly (λ = 632.8 nm) excited molybdenum disulfide (MoS{sub 2}) is studied at liquid helium temperature. More than 20 peaks in the energy range spanning up to 1400 cm{sup −1} from the laser line, which are related to multiphonon resonant Raman scattering processes, are observed. The attribution of the observed lines involving basic lattice vibrational modes of MoS{sub 2} and both the longitudinal (LA(M)) and the transverse (TA(M) and/or ZA(M)) acoustic phonons from the vicinity of the high-symmetry M point of the MoS{sub 2} Brillouin zone is proposed.

  8. Resonant electronic Raman scattering: A BCS-like system

    NASA Astrophysics Data System (ADS)

    Rodrigues, Leonarde N.; Arantes, A.; Schüller, C.; Bell, M. J. V.; Anjos, V.

    2016-05-01

    In this paper we investigate the resonant intersubband Raman scattering of two-dimensional electron systems in GaAs-AlGaAs single quantum wells. Self-consistent calculations of the polarized and depolarized Raman cross sections show that the appearance of excitations at the unrenormalized single-particle energy are related to three factors: the extreme resonance regime, the existence of degeneracy in intersubband excitations of the electron gas, and, finally, degeneracy in the interactions between pairs of excitations. It is demonstrated that the physics that governs the problem is similar to the one that gives rise to the formation of the superconducting state in the BCS theory of normal metals. Comparison between experiment and theory shows an excellent agreement.

  9. Noise power spectral density of a fibre scattered-light interferometer with a semiconductor laser source

    SciTech Connect

    Alekseev, A E; Potapov, V T

    2013-10-31

    Spectral characteristics of the noise intensity fluctuations at the output of a scattered-light interferometer, caused by phase fluctuations of semiconductor laser radiation are considered. This kind of noise is one of the main factors limiting sensitivity of interferometric sensors. For the first time, to our knowledge, the expression is obtained for the average noise power spectral density at the interferometer output versus the degree of a light source coherence and length of the scattering segment. Also, the approximate expressions are considered which determine the power spectral density in the low-frequency range (up to 200 kHz) and in the limiting case of extended scattering segments. The expression obtained for the noise power spectral density agrees with experimental normalised power spectra with a high accuracy. (interferometry of radiation)

  10. ON THE FORMATION OF Lyalpha EMISSION FROM RESONANTLY SCATTERED CONTINUUM PHOTONS OF GAMMA-RAY BURST's AFTERGLOW

    SciTech Connect

    Xu Wen; Wu Xiangping

    2010-02-20

    The continuum spectrum of gamma-ray burst's (GRB) afterglow at Lyalpha wavelength is known to be otherwise featureless except for the existence of a pair of smooth damping wings. Resonant scattering of photons with the ambient neutral hydrogen around the GRB may alter this picture. We study the formation and evolution of the spectral imprint of these resonantly scattered photons in the context of GRB's afterglow. Based on an analytic model that includes photons that are scattered only once, as well as a complete treatment of all the scatterings using Monte Carlo simulations, we are able to calculate the spectrum and luminosity of this Lyalpha emission from a very early moment up to a late epoch. We find that the amount, the motion, and the geometry of the neutral hydrogen around the GRB, together with the time behavior of the source are the crucial factors that affect the predicted luminosity and spectral profile. The flux of the Lyalpha emission is found to be mainly contributed by photons that are scattered only once. The flux is of the order 10{sup -4}-10{sup -9} relative to the undecayed maximum flux of the transmitted continuum, making the feature negligible but potentially observable. If not obscured by the host galaxy's damped Lyalpha absorption systems or intergalactic neutral hydrogen, the feature may appear sometime from 1 hr to several years when the directly transmitted light has faded away. This scattered emission feature can be distinguished from Lyalpha photons of other origins by its luminosity evolution and by its gradual narrowing of profile with time. The typical timescale for spectral variance is that of the light crossing time of a hydrogen clump close to the GRB. If observed, the resonant peaks' time-dependent behavior is a scanning probe on the distribution of neutral hydrogen in GRB's immediate neighborhood.

  11. Surface plasmon resonance sensor based on spectral interferometry: numerical analysis.

    PubMed

    Zhang, Yunfang; Li, Hui; Duan, Jingyuan; Shi, Ancun; Liu, Yuliang

    2013-05-10

    In this paper, we introduce a numerical simulation of a phase detecting surface plasmon resonance (SPR) scheme based on spectral interference. Based on the simulation, we propose a method to optimize various aspects of SPR sensors, which enables better performance in both measurement range (MR) and sensitivity. In the simulation, four parameters including the spectrum of the broadband light source, incident angle, Au film thickness, and refractive index of the prism coupler are analyzed. The results show that it is a good solution for better performance to use a warm white broadband (625-800 nm) light source, a divergence angle of the collimated incident light less than 0.02°, and an optimized 48 nm thick Au film when a visible broadband light source is used. If a near-IR light source is used, however, the Au film thickness should be somewhat thinner according the specific spectrum. In addition, a wider MR could be obtained if a prism coupler with higher refractive index is used. With all the parameters appropriately set, the SPR MR could be extended to 0.55 refractive index units while keeping the sensitivity at a level of 10(-8). PMID:23669838

  12. Clenbuterol Assay by Spectral Imaging Surface Plasmon Resonance Biosensor System.

    PubMed

    Wu, Yichuan; Yao, Manwen; Fang, Xiangyi; Yang, Yucong; Cheng, Xiaoli

    2015-11-01

    To prevent illegal use of clenbuterol and for quality control in the food industry, more efficient and reliable methods for clenbuterol detection are needed. In this study, clenbuterol was detected using a spectral imaging surface plasmon resonance sensor system via two inhibition methods: (1) the target site compensation method, in which anti-clenbuterol antibody was immobilized on the sensor chip as a bioprobe and (2) the solution competition method in which a clenbuterol-BSA conjugate was immobilized on the sensor chip as the bioprobe. The detectable clenbuterol concentration ranged between 6.25 and 100 μg/mL for both methods. The clenbuterol limit of detection for the target site compensation method and solution competition method are estimated to be 6.7 and 4.5 μg/mL, respectively. The proposed methods were successfully applied to the detection of clenbuterol molecules and were found to have high specificity and high-throughput and were label free and operationally convenient. PMID:26319570

  13. Scattering and Extinction Torques: How Plasmon Resonances Affect the Orientation Behavior of a Nanorod in Linearly Polarized Light.

    PubMed

    Xu, Xiaohao; Cheng, Chang; Zhang, Yao; Lei, Hongxiang; Li, Baojun

    2016-01-21

    Linearly polarized light can exert an orienting torque on plasmonic nanorods. The torque direction has generally been considered to change when the light wavelength passes through a plasmon longitudinal resonance. Here, we use the Maxwell stress tensor to evaluate this torque in general terms. According to distinct light-matter interaction processes, the total torque is decomposed into scattering and extinction torques. The scattering torque tends to orient plasmonic nanorods parallel to the light polarization, independent of the choice of light wavelength. The direction of the extinction torque is not only closely tied to the excitation of plasmon resonance but also depends on the specific plasmon mode around which the light wavelength is tuned. Our findings show that the conventional wisdom that simply associates the total torque with the plasmon longitudinal resonances needs to be replaced with an understanding based on the different torque components and the details of spectral distribution. PMID:26720710

  14. Scattering-Type Surface-Plasmon-Resonance Biosensors

    NASA Technical Reports Server (NTRS)

    Wang, Yu; Pain, Bedabrata; Cunningham, Thomas; Seshadri, Suresh

    2005-01-01

    Biosensors of a proposed type would exploit scattering of light by surface plasmon resonance (SPR). Related prior biosensors exploit absorption of light by SPR. Relative to the prior SPR biosensors, the proposed SPR biosensors would offer greater sensitivity in some cases, enough sensitivity to detect bioparticles having dimensions as small as nanometers. A surface plasmon wave can be described as a light-induced collective oscillation in electron density at the interface between a metal and a dielectric. At SPR, most incident photons are either absorbed or scattered at the metal/dielectric interface and, consequently, reflected light is greatly attenuated. The resonance wavelength and angle of incidence depend upon the permittivities of the metal and dielectric. An SPR sensor of the type most widely used heretofore includes a gold film coated with a ligand a substance that binds analyte molecules. The gold film is thin enough to support evanescent-wave coupling through its thickness. The change in the effective index of refraction at the surface, and thus the change in the SPR response, increases with the number of bound analyte molecules. The device is illuminated at a fixed wavelength, and the intensity of light reflected from the gold surface opposite the ligand-coated surface is measured as a function of the angle of incidence. From these measurements, the angle of minimum reflection intensity is determined

  15. On the sbottom resonance in dark matter scattering

    SciTech Connect

    Gondolo, Paolo; Scopel, Stefano E-mail: scopel@sogang.ac.kr

    2013-10-01

    A resonance in the neutralino-nucleus elastic scattering cross section is usually purported when the neutralino-sbottom mass difference m{sub b-tilde}−m{sub χ} is equal to the bottom quark mass m{sub b} ∼ 4 GeV. Such a scenario has been discussed as a viable model for light ( ∼ 10 GeV) neutralino dark matter as explanation of possible DAMA and CoGeNT direct detection signals. Here we give physical and analytical arguments showing that the sbottom resonance may actually not be there. In particular, we show analytically that the one-loop gluon-neutralino scattering amplitude has no pole at m{sub b-tilde} = m{sub χ}+m{sub b}, while by analytic continuation to the regime m{sub b-tilde} < m{sub χ}, it develops a pole at m{sub b-tilde} = m{sub χ}−m{sub b}. In the limit of vanishing gluon momenta, this pole corresponds to the only cut of the neutralino self-energy diagram with a quark and a squark running in the loop, when the decay process χ→ Q-tilde +Q becomes kinematically allowed. The pole can be interpreted as the formation of a b-tilde b-bar qqq or b-tilde *bqqq resonant state (where qqq are the nucleon valence quarks), which is however kinematically not accessible if the neutralino is the LSP. Our analysis shows that the common practice of estimating the neutralino-nucleon cross section by introducing an ad-hoc pole at m{sub b-tilde} = m{sub χ}+m{sub b} into the effective four-fermion interaction (also including higher-twist effects) should be discouraged, since it corresponds to adding a spurious pole to the scattering process at the center-of-mass energy (s){sup 1/2} ≅ m{sub χ} ≅ m{sub b-tilde}−m{sub b}. Our considerations can be extended from the specific case of supersymmetry to other similar cases in which the dark matter particle scatters off nucleons through the exchange of a b-flavored state almost degenerate in mass with the dark matter particle, such as for instance in theories with extra dimensions and in other mass-degenerate dark

  16. Controlling the spectral shape of nonlinear Thomson scattering with proper laser chirping

    NASA Astrophysics Data System (ADS)

    Rykovanov, S. G.; Geddes, C. G. R.; Schroeder, C. B.; Esarey, E.; Leemans, W. P.

    2016-03-01

    Effects of nonlinearity in Thomson scattering of a high intensity laser pulse from electrons are analyzed. Analytic expressions for laser pulse shaping in frequency (chirping) are obtained which control spectrum broadening for high laser pulse intensities. These analytic solutions allow prediction of the spectral form and required laser parameters to avoid broadening. Results of analytical and numerical calculations agree well. The control over the scattered radiation bandwidth allows narrow bandwidth sources to be produced using high scattering intensities, which in turn greatly improves scattering yield for future x- and gamma-ray sources.

  17. SUPERNOVA RESONANCE-SCATTERING LINE PROFILES IN THE ABSENCE OF A PHOTOSPHERE

    SciTech Connect

    Friesen, Brian; Baron, E.; Branch, David; Chen Bin; Parrent, Jerod T.; Thomas, R. C.

    2012-11-15

    In supernova (SN) spectroscopy relatively little attention has been given to the properties of optically thick spectral lines in epochs following the photosphere's recession. Most treatments and analyses of post-photospheric optical spectra of SNe assume that forbidden-line emission comprises most if not all spectral features. However, evidence exists that suggests that some spectra exhibit line profiles formed via optically thick resonance-scattering even months or years after the SN explosion. To explore this possibility, we present a geometrical approach to SN spectrum formation based on the 'Elementary Supernova' model, wherein we investigate the characteristics of resonance-scattering in optically thick lines while replacing the photosphere with a transparent central core emitting non-blackbody continuum radiation, akin to the optical continuum provided by decaying {sup 56}Co formed during the explosion. We develop the mathematical framework necessary for solving the radiative transfer equation under these conditions and calculate spectra for both isolated and blended lines. Our comparisons with analogous results from the Elementary Supernova code SYNOW reveal several marked differences in line formation. Most notably, resonance lines in these conditions form P Cygni-like profiles, but the emission peaks and absorption troughs shift redward and blueward, respectively, from the line's rest wavelength by a significant amount, despite the spherically symmetric distribution of the line optical depth in the ejecta. These properties and others that we find in this work could lead to misidentification of lines or misattribution of properties of line-forming material at post-photospheric times in SN optical spectra.

  18. Experimental evaluation of the twofold electromagnetic enhancement theory of surface-enhanced resonance Raman scattering

    SciTech Connect

    Yoshida, Ken-ichi; Itoh, Tamitake; Biju, Vasudevanpillai; Ishikawa, Mitsuru; Ozaki, Yukihiro

    2009-02-15

    We examined an electromagnetic (EM) theory of surface-enhanced resonance Raman scattering (SERRS) using single Ag nanoaggregates. The SERRS-EM theory is characterized by twofold EM enhancement induced by the coupling of plasmon resonance with both excitation and emission of Raman scattering plus fluorescence. The total emission cross-section spectra of enhanced Raman scattering and enhanced fluorescence were calculated using the following parameters: the spectrum of enhancement factor induced by plasmon resonance, resonance Raman scattering overlapped with fluorescence, and excitation wavelengths. The calculations well agreed with experimental total emission cross-section spectra, thus providing strong indications that the SERRS-EM theory is quantitatively correct.

  19. Determination of the Mechanism for Resonant Scattering in LaMnO{sub 3}

    SciTech Connect

    Shen, Q.; Finkelstein, K.; Elfimov, I.S.; Sawatzky, G.A.; Fanwick, P.; Tokura, Y.; Kimura, T.; Colella, R.

    2006-06-23

    The resonant multiple Bragg x-ray diffraction is used to study the forbidden (104) reflection in LaMnO{sub 3}. Using the interference between the three-beam scattering and resonant scattering we can determine the phase of the resonant scattering. This phase is shown to be consistent with a model in which the resonant scattering is caused by the influence of the Mn-O bond length distortion rather than directly by the orbital ordering on the Mn 4p band structure.

  20. Anomalous Spectral Shift of Near- and Far-Field Plasmonic Resonances in Nanogaps

    PubMed Central

    2016-01-01

    The near-field and far-field spectral response of plasmonic systems are often assumed to be identical, due to the lack of methods that can directly compare and correlate both responses under similar environmental conditions. We develop a widely tunable optical technique to probe the near-field resonances within individual plasmonic nanostructures that can be directly compared to the corresponding far-field response. In tightly coupled nanoparticle-on-mirror constructs with nanometer-sized gaps we find >40 meV blue-shifts of the near-field compared to the dark-field scattering peak, which agrees with full electromagnetic simulations. Using a transformation optics approach, we show such shifts arise from the different spectral interference between different gap modes in the near- and far-field. The control and tuning of near-field and far-field responses demonstrated here is of paramount importance in the design of optical nanostructures for field-enhanced spectroscopy, as well as to control near-field activity monitored through the far-field of nano-optical devices. PMID:27077075

  1. Dark-field spectral imaging microscope for localized surface plasmon resonance-based biosensing

    NASA Astrophysics Data System (ADS)

    Yim, Sang-Youp; Park, Jin-Ho; Kim, Min-Gon

    2015-07-01

    Localized surface plasmon resonance (LSPR) of metal nanoparticles makes red-shift of extinction wavelength with an increase in the refractive index at the surface of the metal nanoparticles. Since biomolecules bound to the metal nanoparticle's surface induce refractive index change, biosensing based on LSPR effect can be possible by monitoring scattering or absorption spectrum changes. Generally, however, conventional method detects ensemble averaged LSPR signal of a huge number of metal nanoparticles. Here, we have constructed a dark-field spectral imaging microscope in order to monitor the scattering spectra of individual metal nanoparticles, simultaneously. Gold nanorod (GNR) and aptamer are employed to detect ochratoxin A (OTA) related to a carcinogenic illness. An aptamer-target binding mechanism promotes wavelength shift of extinction spectra due to refractive index change within sensing volume of GNR by structural change of aptamer. A number of GNRs can be identified in a dark-field LSPR image, simultaneously. A typical spectrum of a GNR exhibits red-shift after target binding of molecules and OTA detection is extended to the very low concentration of 1 pM level.

  2. Carbon nanohorn-based nanofluids: characterization of the spectral scattering albedo

    PubMed Central

    2012-01-01

    The full characterization of the optical properties of nanofluids consisting of single-wall carbon nanohorns of different morphologies in aqueous suspensions is carried out using a novel spectrophotometric technique. Information on the nanofluid scattering and absorption spectral characteristics is obtained by analyzing the data within the single scattering theory and validating the method by comparison with previous monochromatic measurements performed with a different technique. The high absorption coefficient measured joint to the very low scattering albedo opens promising application perspectives for single-wall carbon nanohorn-based fluid or solid suspensions. The proposed approximate approach can be extended also to other low-scattering turbid media. PACS: 78.35.+c Brillouin and Rayleigh scattering, other light scattering; 78.40.Ri absorption and reflection spectra, fullerenes and related materials; 81.05.U- carbon/carbon-based materials; 78.67.Bf optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures, nanocrystals, nanoparticles, and nanoclusters. PMID:22297089

  3. Spectral shape of stimulated Brillouin scattering in crystals

    NASA Astrophysics Data System (ADS)

    Ohno, S.; Sonehara, T.; Tatsu, E.; Koreeda, A.; Saikan, S.

    2015-12-01

    We derived a formula to describe the stimulated Brillouin spectral shape in crystals for various temperatures ranging from room temperature to liquid-helium temperature. We modeled a sample as a one-dimensional system with a finite thickness in which the optically induced phonon propagates, partly interacting with the pump and probe laser beams. When the sample length is shorter than the propagation distance (i.e., the mean free path) of phonons, the spectral shape becomes multipeaked due to the multiple phonon reflections in the sample. Such a situation can be realized in a thin film or a bulk sample at low temperatures. We experimentally measured the Brillouin gain spectra with a multipeak structure in TeO2 and PbMoO4 crystals at low temperatures. We found that these spectra were reproduced by our formula for both the coaxial and off-axis phonon propagations with respect to the laser beams. It was revealed that our formula is very useful in estimating the phonon attenuation coefficient from the observed spectra, which gradually change from Lorentzian shape to a multipeak spectrum with decreasing temperature.

  4. On long-wave sound scattering by a Rankine vortex: Non-resonant and resonant cases

    NASA Astrophysics Data System (ADS)

    Kopiev, Victor F.; Belyaev, Ivan V.

    2010-04-01

    The well-known two-dimensional problem of sound scattering by a Rankine vortex at small Mach number M is considered. Despite its long history, the solutions obtained by many authors still are not free from serious objections. The common approach to the problem consists in the transformation of governing equations to the d'Alembert equation with right-hand part. It was recently shown [I.V. Belyaev, V.F. Kopiev, On the problem formulation of sound scattering by cylindrical vortex, Acoustical Physics 54(5) (2008) 603-614] that due to the slow decay of the mean velocity field at infinity the convective equation with nonuniform coefficients instead of the d'Alembert equation should be considered, and the incident wave should be excited by a point source placed at a large but finite distance from the vortex instead of specifying an incident plane wave (which is not a solution of the governing equations). Here we use the new formulation of Belyaev and Kopiev to obtain the correct solution for the problem of non-resonant sound scattering, to second order in Mach number M. The partial harmonic expansion approach and the method of matched asymptotic expansions are employed. The scattered field in the region far outside the vortex is determined as the solution of the convective wave equation, and van Dyke's matching principle is used to match the fields inside and outside the vortical region. Finally, resonant scattering is also considered; an O( M2) result is found that unifies earlier solutions in the literature. These problems are considered for the first time.

  5. Observation of superconductivity in hydrogen sulfide from nuclear resonant scattering.

    PubMed

    Troyan, Ivan; Gavriliuk, Alexander; Rüffer, Rudolf; Chumakov, Alexander; Mironovich, Anna; Lyubutin, Igor; Perekalin, Dmitry; Drozdov, Alexander P; Eremets, Mikhail I

    2016-03-18

    High-temperature superconductivity remains a focus of experimental and theoretical research. Hydrogen sulfide (H2S) has been reported to be superconducting at high pressures and with a high transition temperature. We report on the direct observation of the expulsion of the magnetic field in H2S compressed to 153 gigapascals. A thin (119)Sn film placed inside the H2S sample was used as a sensor of the magnetic field. The magnetic field on the (119)Sn sensor was monitored by nuclear resonance scattering of synchrotron radiation. Our results demonstrate that an external static magnetic field of about 0.7 tesla is expelled from the volume of (119)Sn foil as a result of the shielding by the H2S sample at temperatures between 4.7 K and approximately 140 K, revealing a superconducting state of H2S. PMID:26989248

  6. Resonant Scattering of Positronium in Collision with CO2

    NASA Astrophysics Data System (ADS)

    Brawley, S. J.; Williams, A. I.; Shipman, M.; Laricchia, G.

    2010-12-01

    The total cross sections of positronium (Ps) scattering from a carbon-dioxide molecule have been measured over the range (7-400) eV incident-Ps energy. For the first time in Ps collisions, a resonantlike structure is observed. For the present target, it occurs around 9.5 eV followed by a broader peak at ˜60eV. Following Brawley et al. [Science 330, 789 (2010)SCIEAS0036-807510.1126/science.1192322] who have observed similarities between the total cross sections of positronium and of electrons incident upon a given target at the same velocity, a corresponding comparison is made for CO2. The comparison suggests that the former peak corresponds to the well-known Πu2 shape resonance which occurs for electrons at an incident velocity of 0.5 a.u. Further features are discussed and theoretical input is sought.

  7. Tuning Mie scattering resonances in soft materials with magnetic fields.

    PubMed

    Brunet, Thomas; Zimny, Kevin; Mascaro, Benoit; Sandre, Olivier; Poncelet, Olivier; Aristégui, Christophe; Mondain-Monval, Olivier

    2013-12-27

    An original approach is proposed here to reversibly tune Mie scattering resonances occurring in random media by means of external low induction magnetic fields. This approach is valid for both electromagnetic and acoustic waves. The experimental demonstration is supported by ultrasound experiments performed on emulsions made of fluorinated ferrofluid spherical droplets dispersed in a Bingham fluid. We show that the electromagnet-induced change of droplet shape into prolate spheroids, with a moderate aspect ratio of 2.5, drastically affects the effective properties of the disordered medium. Its effective acoustic attenuation coefficient is shown to vary by a factor of 5, by controlling both the flux density and orientation of the applied magnetic field. PMID:24483797

  8. Surface origin and control of resonance Raman scattering and surface band gap in indium nitride

    NASA Astrophysics Data System (ADS)

    Alarcón-Lladó, Esther; Brazzini, Tommaso; Ager, Joel W.

    2016-06-01

    Resonance Raman scattering measurements were performed on indium nitride thin films under conditions where the surface electron concentration was controlled by an electrolyte gate. As the surface condition is tuned from electron depletion to accumulation, the spectral feature at the expected position of the (E 1, A 1) longitudinal optical (LO) near 590 cm‑1 shifts to lower frequency. The shift is reversibly controlled with the applied gate potential, which clearly demonstrates the surface origin of this feature. The result is interpreted within the framework of a Martin double resonance, where the surface functions as a planar defect, allowing the scattering of long wavevector phonons. The allowed wavevector range, and hence the frequency, is modulated by the electron accumulation due to band gap narrowing. A surface band gap reduction of over 500 meV is estimated for the conditions of maximum electron accumulation. Under conditions of electron depletion, the full InN bandgap (E g  =  0.65 eV) is expected at the surface. The drastic change in the surface band gap is expected to influence the transport properties of devices which utilize the surface electron accumulation layer.

  9. Polarized line formation by resonance scattering. I. Basic formalism.

    NASA Astrophysics Data System (ADS)

    Ivanov, V. V.; Grachev, S. I.; Loskutov, V. M.

    1997-02-01

    The model two-level problem of non-LTE line formation in homogeneous plane atmospheres is reconsidered with the complete account of polarization arising in resonance scattering. We use the approximation of complete frequency redistribution (CFR) and restrict our discussion to the most important case of axially symmetric radiation fields in semi-infinite atmospheres. The primary sources are assumed to be partially polarized. The problem is reduced to the 2x2 matrix Wiener-Hopf integral equation for the matrix source function S(τ). The matrix kernel K_1_(τ) of the {LAMBDA}-operator appearing in this equation is represented as a continuous superposition of exponentials. As we show in Paper II of the series, this enables one to develop a matrix version of the analytical theory which, on the one hand, is a generalization of the scalar CFR theory and, on the other, is the CFR version of the theory of multiple monochromatic Rayleigh scattering. As a preparatory step for this, we discuss in detail the properties of the kernel matrix K_1_(τ) and the dispersion matrix T(z). The latter is essentially the two-sided Laplace transform of K_1_(τ). We consider the asymptotic behavior of K_1_(τ) and T(z) for large τ and z, respectively. For the particular case of the Doppler profile the complete asymptotic expansions of these matrices are presented. These results are at the base of the theory presented in Paper II of the series.

  10. Tuning of resonance spacing over whole free spectral range based on Autler-Townes splitting in a single microring resonator.

    PubMed

    Gao, Ge; Li, Danping; Zhang, Yong; Yuan, Shuai; Armghan, Ammar; Huang, Qingzhong; Wang, Yi; Yu, Jinzhong; Xia, Jinsong

    2015-10-19

    In this paper, a single microring resonator structure formed by incorporating a reflectivity-tunable loop mirror is demonstrated for the tuning of resonance spacing. Autler-Townes splitting in the resonator is utilized to tune the spacing between two adjacent resonances by controlling the strength of coupling between the two counter-propagating degenerate modes in the microring resonator. A theoretical model based on the transfer matrix method is built to analyze the device. The theoretical analysis indicates that the resonance spacing can be tuned from zero to one free spectral range (FSR). In experiment, by integrating metallic microheater, the tuning of resonance spacing in the range of the whole FSR (1.17 nm) is achieved within 9.82 mW heating power dissipation. The device has potential for applications in reconfigurable optical filtering and microwave photonics. PMID:26480351

  11. Highly sensitive detection of melamine based on gemini surfactant using enhanced resonance Rayleigh scattering signals

    NASA Astrophysics Data System (ADS)

    Wang, Peng; Dong, Jiang Xue; Li, Nian Bing; Luo, Hong Qun

    2013-02-01

    We present here a resonance Rayleigh scattering (RRS) spectrum method for the determination of melamine at the nanogram level using a gemini surfactant (disodium 4-dodecyl-2,4'-oxydibenzenesulfonate, DDOF). It was found that DDOF could react with cationic melamine to form an ion-association complex, which induced the enhancement of RRS intensity and the appearance of a new RRS spectrum in acetate buffer (pH 3.6). The RRS spectral characteristics of the melamine-DDOF system, the optimum conditions of the reaction, and the influencing factors have been investigated. Under optimum conditions, the enhanced RRS intensity was proportional to the concentration of melamine in the range of 0.38-6.30 μg/mL. The method has high sensitivity, and the detection limit for melamine is 8.48 ng/mL. Furthermore, the reaction mechanism and the reasons of RRS enhancement were evaluated.

  12. Resonant Inelastic X-ray Scattering Study of the Electronic Structure of Cu2O

    SciTech Connect

    Hill, J.P.; Kim, Y.-J.; Yamaguchi, H.; Gog, T.; Casa, D.

    2010-05-15

    A resonant inelastic x-ray scattering study of the electronic structure of the semiconductor cuprous oxide, Cu{sub 2}O, is reported. When the incident x-ray energy is tuned to the CuK-absorption edge, large enhancements of the spectral features corresponding to the electronic transitions between the valence band and the conduction band are observed. A feature at 6.5 eV can be well described by an interband transition from occupied states of mostly Cu3d character to unoccupied states with mixed 3d, 4s, and O2p character. In addition, an insulating band gap is observed, and the momentum dependence of the lower bound is measured along the {Gamma}-R direction. This is found to be in good agreement with the valence-band dispersion measured with angle-resolved photoemission spectroscopy.

  13. Controllable emission of a dipolar source coupled with a magneto-dielectric resonant subwavelength scatterer

    PubMed Central

    Rolly, Brice; Geffrin, Jean-Michel; Abdeddaim, Redha; Stout, Brian; Bonod, Nicolas

    2013-01-01

    We demonstrate experimentally and theoretically that a local excitation of a single scatterer of relative dielectric permittivity ε = 6 permits to excite broad dipolar and quadrupolar electric and magnetic resonances that shape the emission pattern in an unprecedented way. By suitably positioning the feed with respect to the sphere at a λ/3 distance, this compact antenna is able to spectrally sort the electromagnetic emission either in the forward or in the backward direction, together with a high gain in directivity. Materials with ε = 6 can be found in the whole spectrum of frequencies promising Mie antennas to become an enabling technology in numbers of applications, ranging from quantum single photon sources to telecommunications. PMID:24165924

  14. Experimental studies on output, spatial, and spectral characteristics of a microdroplet dye laser containing intralipid as a highly scattering medium

    SciTech Connect

    Taniguchi, Hiroshi; Tanosaki, Shinji; Tsujita, Kazuhiro; Inaba, Humio

    1996-11-01

    Lasing characteristics of Rhodamine 6G dye-doped microdroplets containing highly scattering fat emulsion Intralipid-10% are studied experimentally. Noteworthy findings are that well-defined lasing threshold can be observed and one order or more magnitude enhancement of emission intensity with suitable (optimum) conditions of the Intralipid mixing ratio, in comparison with original neat-dye lasing microdroplets. The authors present and discuss the measured results of input-output intensities for different dye concentrations and dye-Intralipid mixing ratios in this high-gain laser dye-soft scatterer system and microscope images of spatial distribution of light emission from both the microdroplets containing neat-dye and dye-Intralipid mixture. It was found that almost no-lasing neat-dye microdroplets, which have either much higher or much lower dye concentration, can achieve lasing by substituting suitably certain amounts of the Intralipid, causing multiple light scattering. Spectral measurements of lasing outputs from the Rhodamine 6G dye-Intralipid microdroplets show the tendency of the disappearance of the well-known mode structures, owing to the morphology-dependent resonances of this microspherical cavity inherent to the neat-dye microdroplets. It is their belief that the present results make this novel method of dye-Intralipid microsystem very attractive for a variety of future applications, including diagnostic tools for highly sensitive detection and identification of small quantity objects and species embedded or hidden in highly scattering media.

  15. Solution of electromagnetic scattering and radiation problems using a spectral domain approach - A review

    NASA Technical Reports Server (NTRS)

    Mittra, R.; Ko, W. L.; Rahmat-Samii, Y.

    1979-01-01

    This paper presents a brief review of some recent developments on the use of the spectral-domain approach for deriving high-frequency solutions to electromagnetics scattering and radiation problems. The spectral approach is not only useful for interpreting the well-known Keller formulas based on the geometrical theory of diffraction (GTD), it can also be employed for verifying the accuracy of GTD and other asymptotic solutions and systematically improving the results when such improvements are needed. The problem of plane wave diffraction by a finite screen or a strip is presented as an example of the application of the spectral-domain approach.

  16. A resonance raman scattering study of vibrational dephasing in the mixed crystal of pentacene in naphthalene

    NASA Astrophysics Data System (ADS)

    de Bree, Philippus; Wiersma, Douwe A.

    1982-04-01

    Resonance Raman scattering is used to investigate vibrational dephasing in the mixed crystal of pentacene in naphthalene. It is shown that, as for the pure electronic transition, uncorrelated resonant phonon scattering processes in the ground and vibrationally excited state induce vibrational dephasing in this system.

  17. Picosecond spectral coherent anti-Stokes Raman scattering imaging with principal component analysis of meibomian glands

    NASA Astrophysics Data System (ADS)

    Lin, Chia-Yu; Suhalim, Jeffrey L.; Nien, Chyong Ly; Miljković, Miloš D.; Diem, Max; Jester, James V.; Potma, Eric. O.

    2011-02-01

    The lipid distribution in the mouse meibomian gland was examined with picosecond spectral anti-Stokes Raman scattering (CARS) imaging. Spectral CARS data sets were generated by imaging specific localized regions of the gland within tissue sections at consecutive Raman shifts in the CH2 stretching vibrational range. Spectral differences between the location specific CARS spectra obtained in the lipid-rich regions of the acinus and the central duct were observed, which were confirmed with a Raman microspectroscopic analysis, and attributed to meibum lipid modifications within the gland. A principal component analysis of the spectral data set reveals changes in the CARS spectrum when transitioning from the acini to the central duct. These results demonstrate the utility of picosecond spectral CARS imaging combined with multivariate analysis for assessing differences in the distribution and composition of lipids in tissues.

  18. Adaptation of the University of Wisconsin High Spectral Resolution Lidar for Polarization and Multiple Scattering Measurements

    NASA Technical Reports Server (NTRS)

    Eloranta, E. W.; Piironen, P. K.

    1996-01-01

    Quantitative lidar measurements of aerosol scattering are hampered by the need for calibrations and the problem of correcting observed backscatter profiles for the effects of attenuation. The University of Wisconsin High Spectral Resolution Lidar (HSRL) addresses these problems by separating molecular scattering contributions from the aerosol scattering; the molecular scattering is then used as a calibration target that is available at each point in the observed profiles. While the HSRl approach has intrinsic advantages over competing techniques, realization of these advantages requires implementation of a technically demanding system which is potentially very sensitive to changes in temperature and mechanical alignments. This paper describes a new implementation of the HSRL in an instrumented van which allows measurements during field experiments. The HSRL was modified to measure depolarization. In addition, both the signal amplitude and depolarization variations with receiver field of view are simultaneously measured. This allows for discrimination of ice clouds from water clouds and observation of multiple scattering contributions to the lidar return.

  19. Optimization of a coded aperture coherent scatter spectral imaging system for medical imaging

    NASA Astrophysics Data System (ADS)

    Greenberg, Joel A.; Lakshmanan, Manu N.; Brady, David J.; Kapadia, Anuj J.

    2015-03-01

    Coherent scatter X-ray imaging is a technique that provides spatially-resolved information about the molecular structure of the material under investigation, yielding material-specific contrast that can aid medical diagnosis and inform treatment. In this study, we demonstrate a coherent-scatter imaging approach based on the use of coded apertures (known as coded aperture coherent scatter spectral imaging1, 2) that enables fast, dose-efficient, high-resolution scatter imaging of biologically-relevant materials. Specifically, we discuss how to optimize a coded aperture coherent scatter imaging system for a particular set of objects and materials, describe and characterize our experimental system, and use the system to demonstrate automated material detection in biological tissue.

  20. Resonances in rotationally inelastic scattering of OH(X2Π) with helium and neon.

    PubMed

    Gubbels, Koos B; Ma, Qianli; Alexander, Millard H; Dagdigian, Paul J; Tanis, Dick; Groenenboom, Gerrit C; van der Avoird, Ad; van de Meerakker, Sebastiaan Y T

    2012-04-14

    We present detailed calculations on resonances in rotationally and spin-orbit inelastic scattering of OH (X(2)Π, j = 3/2, F(1), f) radicals with He and Ne atoms. We calculate new ab initio potential energy surfaces for OH-He, and the cross sections derived from these surfaces compare well with the recent crossed beam scattering experiment of Kirste et al. [Phys. Rev. A 82, 042717 (2010)]. We identify both shape and Feshbach resonances in the integral and differential state-to-state scattering cross sections, and we discuss the prospects for experimentally observing scattering resonances using Stark decelerated beams of OH radicals. PMID:22502519

  1. Ultrasonic Thermometry Inside Tissues Based on High-resolution Detection of Spectral Shifts in Overtones of Scattering Signals

    NASA Astrophysics Data System (ADS)

    Bazán, I.; Ramos, A.; Ramírez, A.; Leija, L.

    Some research results of cooperation works in biomedical engineering, established among current national projects of Mexico and Spain, are resumed. They are related to coordinated activities of three R & D groups, with the aim to achieve high-resolution ultrasonic thermometry into tissue phantoms with internal reflectors of a non-invasive way. Advanced spectral techniques are being used to extract thermal information in echo-signals acquired from biological phantoms with internal structures having a quasi-regular scattering distribution as, for instance, it happens in the liver tissues where a rather regular separation between scatterers has been reported. These techniques can indicate pathologies related to thermal increases due to the presence of disease. Small changes with temperature can be detected in the location of overtones of the fundamental resonance related to the separation of internal reflectors. But, this requires discarding the influence of the echoes noise on the thermal estimation results. A first evaluation of these spectral analysis techniques is performed, using echo-signals acquired from a phantom in the temperature range with medical interest, where the noise influence is shown for different levels of SNR in the echoes, using signals derived of a mathematical model for hepatic tissue echoes, where the average power, signal to noise ratio and inter-arrival time standard deviation, were taken into account. It seems that our high-resolution spectral option could be applied to detect some pathologies in tissues having regular scattering, but new advances must be performed with real tissues, in order to confirm the potential resolution of this approach.

  2. Spectral Absorption and Scattering Properties of Normal and Bruised Apple Tissue

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Knowledge of the spectral absorption and scattering properties of apple tissue, especially bruised tissue, can help us develop an effective method for detecting bruises during postharvest sorting and grading. This research was intended to determine the optical properties of normal and bruised apple ...

  3. Assessing multiple quality attributes of peaches using spectral absorption and scattering properties

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this research was to measure the spectral absorption and reduced scattering coefficients of peaches, using a hyperspectral imaging-based spatially-resolved method, for maturity/quality assessment. A newly developed optical property measuring instrument was used for acquiring hypersp...

  4. Data fusion of visible/near-infrared spectroscopy and spectral scattering for apple quality assessment

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Visible/near-infrared (VNIR) spectroscopy and spectral scattering are based on different sensing principles, and they have shown different abilities for predicting apple fruit firmness and soluble solids content (SSC). Hence the two techniques could work synergistically to improve the quality predic...

  5. Charge-magnetic interference resonant scattering studies of ferromagnetic crystals and thin films

    SciTech Connect

    Haskel, D.; Kravtsov, E.; Choi, Y.; Lang, J.C.; Islam, Z.; Srajer, G.; Jiang, J.S.; Bader, S.D.; Canfield, Paul C.

    2012-06-15

    The element- and site-specificity of X-ray resonant magnetic scattering (XRMS) makes it an ideal tool for furthering our understanding of complex magnetic systems. In the hard X-rays, XRMS is readily applied to most antiferromagnets where the relatively weak resonant magnetic scattering (10 −2–10 −6Ic) is separated in reciprocal space from the stronger, Bragg charge scattered intensity, Ic. In ferro(ferri)magnetic materials, however, such separation does not occur and measurements of resonant magnetic scattering in the presence of strong charge scattering are quite challenging. We discuss the use of charge-magnetic interference resonant scattering for studies of ferromagnetic (FM) crystals and layered films. We review the challenges and opportunities afforded by this approach, particularly when using circularly polarized X-rays.We illustrate current capabilities at the Advanced Photon Source with studies aimed at probing site-specific magnetism in ferromagnetic crystals, and interfacial magnetism in films.

  6. Three-dimensional visualization of objects in scattering medium using integral imaging and spectral analysis

    NASA Astrophysics Data System (ADS)

    Lee, Yeonkyung; Yoo, Hoon

    2016-02-01

    This paper presents a three-dimensional visualization method of 3D objects in a scattering medium. The proposed method employs integral imaging and spectral analysis to improve the visual quality of 3D images. The images observed from 3D objects in the scattering medium such as turbid water suffer from image degradation due to scattering. The main reason is that the observed image signal is very weak compared with the scattering signal. Common image enhancement techniques including histogram equalization and contrast enhancement works improperly to overcome the problem. Thus, integral imaging that enables to integrate the weak signals from multiple images was discussed to improve image quality. In this paper, we apply spectral analysis to an integral imaging system such as the computational integral imaging reconstruction. Also, we introduce a signal model with a visibility parameter to analyze the scattering signal. The proposed method based on spectral analysis efficiently estimates the original signal and it is applied to elemental images. The visibility-enhanced elemental images are then used to reconstruct 3D images using a computational integral imaging reconstruction algorithm. To evaluate the proposed method, we perform the optical experiments for 3D objects in turbid water. The experimental results indicate that the proposed method outperforms the existing methods.

  7. Scattering in remote sensing in the visible and microwave spectral range and in traffic control

    NASA Astrophysics Data System (ADS)

    Böttger, U.; Kühne, R.; Thiessenhusene, K.-U.

    2003-05-01

    The treatment of scattering processes in remote sensing for interpretation of satellite data is demonstrated in the visible and microwave spectral range comparing the two spectral ranges. Analogies and distinctions in the treatment of the scattering processes are shown. Based on this cognition an approach for traffic simulation is outlined. Simulating the traffic of a part of a city, a whole city or a larger area in an acceptable time is one of the tasks in recent traffic research. One possible approach is the areal treatment of the road network. That means that single streets are not resolved but are introduced into simulations only by parameters that correspond to a specific traffic area resistance. The aim of this work is to outline such a possibility using experiences obtained from the theory of radiative transport to simulate scattering processes and applying them to the very complex system of traffic simulation.

  8. Fano resonance and improved sensing performance in a spectral-simplified optofluidic micro-bubble resonator by introducing selective modal losses.

    PubMed

    Liao, Jie; Wu, Xiang; Liu, Liying; Xu, Lei

    2016-04-18

    The spectral mode density in optical micro-bubble resonators is reduced by introducing a loss element of UV curable adhesive to selectively suppress the whispering gallery modal resonances. Asymmetric Fano resonant profile appears after spectral simplification, and the sharp slope amplifies the detecting intensity change by 4.3 times when sensing the liquid core refractive index change. PMID:27137294

  9. Spectral editing for in vivo 13C magnetic resonance spectroscopy

    NASA Astrophysics Data System (ADS)

    Xiang, Yun; Shen, Jun

    2012-01-01

    In vivo detection of carboxylic/amide carbons is a promising technique for studying cerebral metabolism and neurotransmission due to the very low RF power required for proton decoupling. In the carboxylic/amide region, however, there is severe spectral overlap between acetate C1 and glutamate C5, complicating studies that use acetate as an astroglia-specific substrate. There are no known in vivo MRS techniques that can spectrally resolve acetate C1 and glutamate C5 singlets. In this study, we propose to spectrally separate acetate C1 and glutamate C5 by a two-step J-editing technique after introducing homonuclear 13C- 13C scalar coupling between carboxylic/amide carbons and aliphatic carbons. By infusing [1,2- 13C 2]acetate instead of [1- 13C]acetate the acetate doublet can be spectrally edited because of the large separation between acetate C2 and glutamate C4 in the aliphatic region. This technique can be applied to studying acetate transport and metabolism in brain in the carboxylic/amide region without spectral interference.

  10. Modeling of Outer Radiation Belt Electron Scattering due to Spatial and Spectral Properties of ULF Waves

    NASA Astrophysics Data System (ADS)

    Tornquist, Mattias

    The research presented in this thesis covers wave-particle interactions for relativistic (0.5-10 MeV) electrons in Earth's outer radiation belt (r = 3-7 RE, or L-shells: L = 3-7) interacting with magnetospheric Pc-5 (ULF) waves. This dissertation focuses on ideal models for short and long term electron energy and radial position scattering caused by interactions with ULF waves. We use test particle simulations to investigate these wave-particle interactions with ideal wave and magnetic dipole fields. We demonstrate that the wave-particle phase can cause various patterns in phase space trajectories, i.e. local acceleration, and that for a global electron population, for all initial conditions accounted for, has a negligible net energy scattering. Working with GSM polar coordinates, the relevant wave field components are EL, Ephi and Bz, where we find that the maximum energy scattering is 3-10 times more effective for Ephi compared to EL in a magnetic dipole field with a realistic dayside compression amplitude. We also evaluate electron interactions with two coexisting waves for a set of small frequency separations and phases, where it is confirmed that multi-resonant transport is possible for overlapping resonances in phase space when the Chirikov criterion is met (stochasticity parameter K = 1). The electron energy scattering enhances with decreasing frequency separation, i.e. increasing K, and is also dependent on the phases of the waves. The global acceleration is non-zero, can be onset in about 1 hour and last for > 4 hours. The adiabatic wave-particle interaction discussed up to this point can be regarded as short-term scattering ( tau ˜ hours ). When the physical problem extends to longer time scales (tau ˜ days ) the process ceases to be adiabatic due to the introduction of stochastic element in the system and becomes a diffusive process. We show that any mode in a broadband spectrum can contribute to the total diffusion rate for a particular drift

  11. Plasmon-resonant Raman spectroscopy in metallic nanoparticles: Surface-enhanced scattering by electronic excitations

    NASA Astrophysics Data System (ADS)

    Carles, R.; Bayle, M.; Benzo, P.; Benassayag, G.; Bonafos, C.; Cacciato, G.; Privitera, V.

    2015-11-01

    Since the discovery of surface-enhanced Raman scattering (SERS) 40 years ago, the origin of the "background" that is systematically observed in SERS spectra has remained questionable. To deeply analyze this phenomenon, plasmon-resonant Raman scattering was recorded under specific experimental conditions on a panel of composite multilayer samples containing noble metal (Ag and Au) nanoparticles. Stokes, anti-Stokes, and wide, including very low, frequency ranges have been explored. The effects of temperature, size (in the nm range), embedding medium (SiO2, Si3N4, or TiO2) or ligands have been successively analyzed. Both lattice (Lamb modes and bulk phonons) and electron (plasmon mode and electron-hole excitations) dynamics have been investigated. This work confirms that in Ag-based nanoplasmonics composite layers, only Raman scattering by single-particle electronic excitations accounts for the background. This latter appears as an intrinsic phenomenon independently of the presence of molecules on the metallic surface. Its spectral shape is well described by revisiting a model developed in the 1990s for analyzing electron scattering in dirty metals, and used later in superconductors. The gs factor, that determines the effective mean-free path of free carriers, is evaluated, gsexpt=0.33 ±0.04 , in good agreement with a recent evaluation based on time-dependent local density approximation gstheor=0.32 . Confinement and interface roughness effects at the nanometer range thus appear crucial to understand and control SERS enhancement and more generally plasmon-enhanced processes on metallic surfaces.

  12. Ultrasharp nonlinear photothermal and photoacoustic resonances and holes beyond the spectral limit

    NASA Astrophysics Data System (ADS)

    Zharov, Vladimir P.

    2011-02-01

    High-resolution nonlinear laser spectroscopy based on absorption saturation, Lamb-dip and spectral hole-burning phenomena has contributed much to basic and applied photonics. Here, a laser spectroscopy based on nonlinear nanobubble-related photothermal and photoacoustic phenomena is presented. It shows ultrasharp resonances and dips up to a few nanometres wide in broad plasmonic spectra of nanoparticles. It also demonstrates narrowing of absorption spectra of dyes and cellular chromophores, as well as an increase in the sensitivity and resolution of the spectral hole-burning technique. This approach can permits the study of nonlinear plasmonics at a level of resolution beyond the spectral limits, the identification of weakly absorbing spectral holes, spectral optimization of photothermal nanotherapy, measurements of tiny red and blue resonance shifts in nanoplasmonic sensors, the use of negative contrast in photoacoustic technique, multispectral imaging and multicolour cytometry.

  13. Ultrasharp nonlinear photothermal and photoacoustic resonances and holes beyond the spectral limit

    PubMed Central

    Zharov, Vladimir P.

    2012-01-01

    High-resolution nonlinear laser spectroscopy based on absorption saturation, Lamb-dip and spectral hole-burning phenomena have contributed much to basic and applied photonics. Here, a laser spectroscopy based on nonlinear photothermal and photoacoustic phenomena is presented. It shows ultrasharp resonances and dips up to a few nanometres wide in broad plasmonic spectra of nanoparticles. It also demonstrates narrowing of absorption spectra of dyes and chromophores, as well as an increase in the sensitivity and resolution of the spectral hole-burning technique. This approach can permit the study of laser-nanoparticle interactions at a level of resolution beyond the spectral limits, identification of weakly absorbing spectral holes, spectral optimization of photothermal nanotherapy, measurements of tiny red and blue plasmon resonance shifts, multispectral imaging and multicolour cytometry. PMID:25558274

  14. A Model of Resonance Scattering on Curved Quantum Wires

    NASA Astrophysics Data System (ADS)

    Exner, Pavel

    A model of electron motion in a curved quantum wire of a finite length 2D attached to a pair of macroscopic electrodes is studied. Regarding the problem as a two-dimensional one, we model the electrodes as halfplanes and the quantum wire as a line segment joining them; it supports a potential which is a combination of a constant transversal-mode energy and an attractive curvature-induced term. We show that the bound states which may be present at an infinite quantum wire turn into resonances and that spectral concentration is valid as D .Translated AbstractEin Modell der Resonanzstreuung auf gekrümmten, dünnen DrähtenDas Modell einer Elektronenbewegung in einem gekrümmten, ultradünnen Draht der Länge 2D, der zwei makroskopische Elektroden verbindet, wird untersucht. Das Modell als zweidimensional betrachtend, nehmen wir die Elektroden als Halbebenen und den Draht als verbindendes Liniensegment. Das Potential ist eine Kombination aus konstanter Transversalmoden-energie und einem anziehenden, von der Krümmung hervorgerufenen Term. Wir zeigen, daß der gebundene Zustand, der im unendlich langen Draht auftreten kann, in Resonanzen übergeht, und die Spektraldichte für D gilt.

  15. Platform for spectrally resolved x-ray scattering from imploding capsules at the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Kraus, D.; Döppner, T.; Kritcher, A. L.; Yi, A.; Boehm, K.; Bachmann, B.; Divol, L.; Fletcher, L. B.; Glenzer, S. H.; Landen, O. L.; Masters, N.; Saunders, A. M.; Weber, C.; Falcone, R. W.; Neumayer, P.

    2016-05-01

    We present a new experimental platform to perform spectrally resolved x-ray scattering measurements of ionization, density and temperature in imploding CH or beryllium capsules at the National Ignition Facility. Scattered x-rays at 9 keV from a zinc He-alpha plasma source at a scattering angle of 120 degrees are highly sensitive to K-shell ionization, while at the same time constraining density and temperature. This platform will allow for x-ray scattering studies of dense plasmas with free electron densities up to 1025 cm-3 giving the possibility to investigate effects of pressure ionization and Pauli blocking on the ablator ionization state right before or shortly after stagnation of the implosion.

  16. Gas temperature and density measurements based on spectrally resolved Rayleigh-Brillouin scattering

    NASA Technical Reports Server (NTRS)

    Seasholtz, Richard G.; Lock, James A.

    1992-01-01

    The use of molecular Rayleigh scattering for measurements of gas density and temperature is evaluated. The technique used is based on the measurement of the spectrum of the scattered light, where both temperature and density are determined from the spectral shape. Planar imaging of Rayleigh scattering from air using a laser light sheet is evaluated for ambient conditions. The Cramer-Rao lower bounds for the shot-noise limited density and temperature measurement uncertainties are calculated for an ideal optical spectrum analyzer and for a planar mirror Fabry-Perot interferometer used in a static, imaging mode. With this technique, a single image of the Rayleigh scattered light can be analyzed to obtain density (or pressure) and temperature. Experimental results are presented for planar measurements taken in a heated air stream.

  17. A fast numerical solution of scattering by a cylinder: Spectral method for the boundary integral equations

    NASA Technical Reports Server (NTRS)

    Hu, Fang Q.

    1994-01-01

    It is known that the exact analytic solutions of wave scattering by a circular cylinder, when they exist, are not in a closed form but in infinite series which converges slowly for high frequency waves. In this paper, we present a fast number solution for the scattering problem in which the boundary integral equations, reformulated from the Helmholtz equation, are solved using a Fourier spectral method. It is shown that the special geometry considered here allows the implementation of the spectral method to be simple and very efficient. The present method differs from previous approaches in that the singularities of the integral kernels are removed and dealt with accurately. The proposed method preserves the spectral accuracy and is shown to have an exponential rate of convergence. Aspects of efficient implementation using FFT are discussed. Moreover, the boundary integral equations of combined single and double-layer representation are used in the present paper. This ensures the uniqueness of the numerical solution for the scattering problem at all frequencies. Although a strongly singular kernel is encountered for the Neumann boundary conditions, we show that the hypersingularity can be handled easily in the spectral method. Numerical examples that demonstrate the validity of the method are also presented.

  18. Fano resonance-induced negative optical scattering force on plasmonic nanoparticles.

    PubMed

    Chen, Huajin; Liu, Shiyang; Zi, Jian; Lin, Zhifang

    2015-02-24

    We demonstrate theoretically that Fano resonance can induce a negative optical scattering force acting on plasmonic nanoparticles in the visible light spectrum when an appropriate manipulating laser beam is adopted. Under the illumination of a zeroth-order Bessel beam, the plasmonic nanoparticle at its Fano resonance exhibits a much stronger forward scattering than backward scattering and consequently leads to a net longitudinal backward optical scattering force, termed Fano resonance-induced negative optical scattering force. The extinction spectra obtained based on the Mie theory show that the Fano resonance arises from the interference of simultaneously excited multipoles, which can be either a broad electric dipole mode and a narrow electric quadrupole mode, or a quadrupole and an octupole mode mediated by the broad electric dipole. Such Fano resonance-induced negative optical scattering force is demonstrated to occur for core-shell, homogeneous, and hollow metallic particles and can therefore be expected to be universal for many other nanostructures exhibiting Fano resonance, adding considerably to the flexibility of optical micromanipulation on the plasmonic nanoparticles. More interestingly, the flexible tunability of the Fano resonance by particle morphology opens up the possibility of tailoring the optical scattering force accordingly, offering an additional degree of freedom to optical selection and sorting of plasmonic nanoparticles. PMID:25635617

  19. Effect of the third π ∗ resonance on the angular distributions for electron-pyrimidine scattering

    NASA Astrophysics Data System (ADS)

    Mašín, Zdeněk; Gorfinkiel, Jimena D.

    2016-07-01

    We present a detailed analysis of the effect of the well known third π∗ resonance on the angular behaviour of the elastic cross section in electron scattering from pyrimidine. This resonance, occurring approximately at 4.7 eV, is of mixed shape and core-excited character. Experimental and theoretical results show the presence of a peak/dip behaviour in this energy range, that is absent for other resonances. Our investigations show that the cause of the peak/dip is an interference of background p-wave to p-wave scattering amplitudes with the amplitudes for resonant scattering. The equivalent resonance in pyrazine shows the same behaviour and the effect is therefore likely to appear in other benzene-like molecules. Contribution to the Topical Issue "Advances in Positron and Electron Scattering", edited by Paulo Limao-Vieira, Gustavo Garcia, E. Krishnakumar, James Sullivan, Hajime Tanuma and Zoran Petrovic.

  20. Molecular structure, spectral constants, and fermi resonances in chlorine nitrate

    NASA Astrophysics Data System (ADS)

    Petkie, Douglas T.; Butler, Rebecca A. H.; Helminger, Paul; De Lucia, Frank C.

    2004-06-01

    Chlorine nitrate has two low-lying vibrational modes that lead to a series of Fermi resonances in the 9 υ97 υ7 family of levels that include the 9 2⇔7 1 and 9 3⇔7 19 1 dyads and the 9 4⇔9 27 1⇔7 2 and 9 5⇔9 37 1⇔9 17 2 triads. These states, along with the ground and 9 1 vibrational states, have been previously analyzed with millimeter and submillimeter wave spectroscopy and provide a substantial body of data for the investigation of these resonances and their impact on calculated spectroscopic constants and structural parameters. Due to fitting indeterminacies, these previous analyses did not include the main Fermi resonance interaction term. Consequently, the fitted rotational constants are linear combinations of the unmixed rotational constants of the basis vibrational states. In this paper, we have calculated the contributions of the Fermi resonances to the observed rotational constants in a model that determines the vibrational-rotational constants, the Fermi term and the mixing between interacting vibrational states, the cubic potential constant ( φ997) that connects interacting levels through a Fermi resonance, and the inertial defects. These results agree with predictions from ab initio and harmonic force field calculations and provide further experimental information for the determination of the fundamental molecular properties of chlorine nitrate.

  1. CRISM-Derived Spectral Scattering Parameters for Surfaces in the Vicinity of Opportunity Mars Rover Traverses

    NASA Astrophysics Data System (ADS)

    Shaw, A.; Arvidson, R. E.; Wolff, M. J.; Seelos, F. P.; Wiseman, S. M.; Cull, S.

    2011-12-01

    CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) data were used to retrieve scattering parameters of surfaces traversed by the Opportunity Mars rover, as well as adjacent areas. Our estimates agree with those retrieved by Johnson et al. [2006] using Opportunity's Panoramic Camera data, and we are able to extend estimates of the Hapke single particle scattering albedo and asymmetry parameter (from the one-term Henyey Greenstein single particle phase function) to a greater spectral resolution and spectral range. This analysis allows us to distinguish between surface units that otherwise look relatively uniform spectrally. This work also provides photometric functions essential for converting spectra to a single viewing geometry which will yield more accurate spectral comparisons. Our method involves simultaneously modeling surface and atmospheric contributions, iterating through surface scattering parameters until a Levenberg-Marquardt least squares best fit is achieved. Retrieved single scattering albedos range from 0.42 to 0.57 (0.5663 - 2.2715 micrometers), and retrieved asymmetry parameters range from -0.27 to -0.17 (moderately backscattering). All surfaces become more backscattering with increasing wavelength. Further, the northern and western portions of Victoria crater's ejecta apron are more backscattering than surrounding regions, indicating a change in physical properties. In images taken when the rover traversed this unit, a surface with small ripples and a dense cover of hematitic spherules is apparent, providing agreement with lab experiments by Johnson et al. [2006] showing increased backscattering with the addition of hematitic spherules. The CRISM-derived scattering parameters also show that bedrock-dominated surfaces are less backscattering than soil-covered surfaces.

  2. Using Single-Scattering Albedo Spectral Curvature to Characterize East Asian Aerosol Mixtures

    NASA Technical Reports Server (NTRS)

    Li, Jing; Carlson, Barbara E.; Lacis, Andrew A.

    2015-01-01

    Spectral dependence of aerosol single-scattering albedo (SSA) has been used to infer aerosol composition. In particular, aerosol mixtures dominated by dust absorption will have monotonically increasing SSA with wavelength while that dominated by black carbon absorption has monotonically decreasing SSA spectra. However, by analyzing SSA measured at four wavelengths, 440, 675, 870, and 1020 nm from the Aerosol Robotic Network data set, we find that the SSA spectra over East Asia are frequently peaked at 675 nm. In these cases, we suggest that SSA spectral curvature, defined as the negative of the second derivative of SSA as a function of wavelength, can provide additional information on the composition of these aerosol mixtures. Aerosol SSA spectral curvatures for East Asia during fall and winter are considerably larger than those found in places primarily dominated by biomass burning or dust aerosols. SSA curvature is found to increase as the SSA magnitude decreases. The curvature increases with coarse mode fraction (CMF) to a CMF value of about 0.4, then slightly decreases or remains constant at larger CMF. Mie calculations further verify that the strongest SSA curvature occurs at approx. 40% dust fraction, with 10% scattering aerosol fraction. The nonmonotonic SSA spectral dependence is likely associated with enhanced absorption in the shortwave by dust, absorption by black carbon at longer wavelengths, and also the flattened absorption optical depth spectral dependence due to the increased particle size.

  3. The spectral energy distribution of the scattered light from dark clouds

    NASA Technical Reports Server (NTRS)

    Mattila, Kalevi; Schnur, G. F. O.

    1989-01-01

    A dark cloud is exposed to the ambient radiation field of integrated starlight in the Galaxy. Scattering of starlight by the dust particles gives rise to a diffuse surface brightness of the dark nebula. The intensity and the spectrum of this diffuse radiation can be used to investigate, e.g., the scattering parameters of the dust, the optical thickness of the cloud, and as a probe of the ambient radiation field at the location of the cloud. An understanding of the scattering process is also a prerequisite for the isolation of broad spectral features due to fluorescence or to any other non-scattering origin of the diffuse light. Model calculations are presented for multiple scattering in a spherical cloud. These calculations show that the different spectral shapes of the observed diffuse light can be reproduced with standard dust parameters. The possibility to use the observed spectrum as a diagnostic tool for analyzing the thickness of the cloud and the dust particle is discussed.

  4. Experimental implementation of coded aperture coherent scatter spectral imaging of cancerous and healthy breast tissue samples

    NASA Astrophysics Data System (ADS)

    Lakshmanan, Manu N.; Greenberg, Joel A.; Samei, Ehsan; Kapadia, Anuj J.

    2015-03-01

    A fast and accurate scatter imaging technique to differentiate cancerous and healthy breast tissue is introduced in this work. Such a technique would have wide-ranging clinical applications from intra-operative margin assessment to breast cancer screening. Coherent Scatter Computed Tomography (CSCT) has been shown to differentiate cancerous from healthy tissue, but the need to raster scan a pencil beam at a series of angles and slices in order to reconstruct 3D images makes it prohibitively time consuming. In this work we apply the coded aperture coherent scatter spectral imaging technique to reconstruct 3D images of breast tissue samples from experimental data taken without the rotation usually required in CSCT. We present our experimental implementation of coded aperture scatter imaging, the reconstructed images of the breast tissue samples and segmentations of the 3D images in order to identify the cancerous and healthy tissue inside of the samples. We find that coded aperture scatter imaging is able to reconstruct images of the samples and identify the distribution of cancerous and healthy tissues (i.e., fibroglandular, adipose, or a mix of the two) inside of them. Coded aperture scatter imaging has the potential to provide scatter images that automatically differentiate cancerous and healthy tissue inside of ex vivo samples within a time on the order of a minute.

  5. Nuclear clusters studied with alpha resonant scatterings using RI beams at CRIB

    NASA Astrophysics Data System (ADS)

    Yamaguchi, H.; Kahl, D.; Nakao, T.; Wakabayashi, Y.; Hashimoto, T.; Hayakawa, S.; Kawabata, T.; Teranishi, T.; Kwon, Y. K.; Binh, D. N.; Khiem, L. H.; Duy, N. N.; Kubono, S.; Suhara, T.; Kanada-En'yo, Y.; Moon, J. Y.; Kim, A.; Iwasa, N.; Lee, P. S.; Chae, K. Y.; Cha, S. M.; Gwak, M. S.; Kim, D. H.; Milman, E.

    2014-12-01

    Alpha resonant scattering is a simple and promising method to study α-cluster structure in nuclei. It has several good features which enable us to perform measurements with short-lived and relatively low-intense RI beams. Several measurements on alpha resonant scattering have been carried out at CRIB (CNS Radioactive Ion Beam separator), which is a low-energy RI beam separator at Center for Nuclear Study (CNS) of the University of Tokyo. Recent α resonant scattering studies at CRIB, using 7Li, 7Be and 10Be beams with a helium gas target, are discussed.

  6. Scattering Problem and Resonances for Three-Body Coulomb Quantum Systems: Parallel Calculations

    NASA Astrophysics Data System (ADS)

    Yarevsky, E.

    2016-02-01

    An approach to the solution of scattering and resonance problems based on splitting the potential into a finite range part and a long range tail part is proposed. The explicit solution to the Schrödinger equation for the long range tail Hamiltonian is used as an incoming wave. This reformulation of the scattering problem makes it suitable for treatment by the exterior complex scaling. The same technique is used to determine resonances of the system. Calculations are performed with the finite element method which allows efficient parallel computations. The approach is illustrated with calculations of the electron resonant scattering on the hydrogen and the helium ion.

  7. Nuclear dynamics in the core-excited state of aqueous ammonia probed by resonant inelastic soft x-ray scattering

    SciTech Connect

    Weinhardt, L.; Weigand, M.; Fuchs, O.; Baer, M.; Blum, M.; Denlinger, J. D.; Yang, W.; Umbach, E.; Heske, C.

    2011-09-01

    The electronic structure of aqueous NH{sub 3} and ND{sub 3} has been investigated using resonant inelastic soft x-ray scattering. Spectral features of different processes involving nuclear dynamics in the core-excited state can be identified. When exciting into the lowest core-excited state, we find a strong isotope effect and clear evidence for ultrafast proton dynamics. Furthermore, a strong vibronic coupling is observed and, in the case of aqueous NH{sub 3}, a vibrational fine structure can be resolved.

  8. Probing the spectral density of the surface electromagnetic fields through scattering of waveguide photons

    PubMed Central

    Chen, Guang-Yin

    2016-01-01

    The spectral density of the metal-surface electromagnetic fields will be strongly modified in the presence of a closely-spaced quantum emitter. In this work, we propose a feasible way to probe the changes of the spectral density through the scattering of the waveguide photon incident on the quantum emitter. The variances of the lineshape in the transmission spectra indicate the coherent interaction between the emitter and the pseudomode resulting from all the surface electromagnetic modes. We further investigate the quantum coherence between the emitter and the pseudomode of the metal-dielectric interface. PMID:26860197

  9. Nonlinear spectral signatures and spatiotemporal behavior of stimulated Raman scattering from single laser speckles.

    PubMed

    Vu, H X; Yin, L; DuBois, D F; Bezzerides, B; Dodd, E S

    2005-12-01

    Simulations are reported of the Thomson scatter spectrum of electrostatic waves (ESWs) excited in single laser hot spots by backward stimulated Raman scattering (BSRS). Under conditions similar those in the recent experiments of Kline et al. [Phys. Rev. Lett. 94, 175003 (2005)], a spectral streak, resulting from the trapping-induced frequency shift of the ESW, is found for high wave-number ESWs, similar to the observations. This shift and parametric frequency matching lead to isolated BSRS pulses. Modes with acoustic dispersion, resulting from the trapping-modified electron velocity distribution, can enhance the frequency range of the streak. PMID:16384390

  10. Structural and dynamical properties of chlorinated hydrocarbons studied with resonant inelastic x-ray scattering.

    PubMed

    Bohinc, R; Žitnik, M; Bučar, K; Kavčič, M; Carniato, S; Journel, L; Guillemin, R; Marchenko, T; Kawerk, E; Simon, M; Cao, W

    2016-04-01

    We present a theoretical and experimental study of resonant inelastic x-ray scattering on a large group of chlorinated hydrocarbons: CH3Cl, CH2Cl2, CHCl3, CCl4, CH3CH2Cl, ClCH2CH2Cl, CH3CHCl2, CH3CCl3, C2H2Cl2-iso, C2H2Cl2-cis, C2H2Cl2-trans, and C6H5Cl. Differences in structural and dynamical properties of the molecules generated by diverse chemical environments are observed in the measured Cl(Kα) spectral maps as well as in the Cl(K) total fluorescence yield spectra. The energy position, relative intensity, and the width of the Franck-Condon distribution of low-lying σ(∗) and π(∗) resonances are extracted by a fitting procedure taking into account the experimental broadening. The theoretical values obtained with the transition potential and Δ Kohn-Sham methods are in good agreement with the experimental parameters indicating subtle differences due to variations in the molecular structure. PMID:27059572

  11. Structural and dynamical properties of chlorinated hydrocarbons studied with resonant inelastic x-ray scattering

    NASA Astrophysics Data System (ADS)

    Bohinc, R.; Žitnik, M.; Bučar, K.; Kavčič, M.; Carniato, S.; Journel, L.; Guillemin, R.; Marchenko, T.; Kawerk, E.; Simon, M.; Cao, W.

    2016-04-01

    We present a theoretical and experimental study of resonant inelastic x-ray scattering on a large group of chlorinated hydrocarbons: CH3Cl, CH2Cl2, CHCl3, CCl4, CH3CH2Cl, ClCH2CH2Cl, CH3CHCl2, CH3CCl3, C2H2Cl2-iso, C2H2Cl2-cis, C2H2Cl2-trans, and C6H5Cl. Differences in structural and dynamical properties of the molecules generated by diverse chemical environments are observed in the measured Cl(Kα) spectral maps as well as in the Cl(K) total fluorescence yield spectra. The energy position, relative intensity, and the width of the Franck-Condon distribution of low-lying σ∗ and π∗ resonances are extracted by a fitting procedure taking into account the experimental broadening. The theoretical values obtained with the transition potential and Δ Kohn-Sham methods are in good agreement with the experimental parameters indicating subtle differences due to variations in the molecular structure.

  12. Voigt spectral profiles in two-photon resonance fluorescence

    SciTech Connect

    Alexanian, Moorad; Bose, Subir K.

    2007-11-15

    A recent work on two-photon fluorescence is extended by considering the pump field to be a coherent state, which represents a laser field operating well above threshold. The dynamical conditions are investigated under which the two-photon spectrum gives rise, in addition to a Lorentzian line shape at the pump frequency, to two Voigt spectral sideband profiles. Additional conditions are found under which the Voigt profile behaves like either a Gaussian or a Lorentzian line shape.

  13. Estimates of the Spectral Aerosol Single Sea Scattering Albedo and Aerosol Radiative Effects during SAFARI 2000

    NASA Technical Reports Server (NTRS)

    Bergstrom, Robert W.; Pilewskie, Peter; Schmid, Beat; Russell, Philip B.

    2003-01-01

    Using measurements of the spectral solar radiative flux and optical depth for 2 days (24 August and 6 September 2000) during the SAFARI 2000 intensive field experiment and a detailed radiative transfer model, we estimate the spectral single scattering albedo of the aerosol layer. The single scattering albedo is similar on the 2 days even though the optical depth for the aerosol layer was quite different. The aerosol single scattering albedo was between 0.85 and 0.90 at 350 nm, decreasing to 0.6 in the near infrared. The magnitude and decrease with wavelength of the single scattering albedo are consistent with the absorption properties of small black carbon particles. We estimate the uncertainty in the single scattering albedo due to the uncertainty in the measured fractional absorption and optical depths. The uncertainty in the single scattering albedo is significantly less on the high-optical-depth day (6 September) than on the low-optical-depth day (24 August). On the high-optical-depth day, the uncertainty in the single scattering albedo is 0.02 in the midvisible whereas on the low-optical-depth day the uncertainty is 0.08 in the midvisible. On both days, the uncertainty becomes larger in the near infrared. We compute the radiative effect of the aerosol by comparing calculations with and without the aerosol. The effect at the top of the atmosphere (TOA) is to cool the atmosphere by 13 W/sq m on 24 August and 17 W/sq m on 6 September. The effect on the downward flux at the surface is a reduction of 57 W/sq m on 24 August and 200 W/sq m on 6 September. The aerosol effect on the downward flux at the surface is in good agreement with the results reported from the Indian Ocean Experiment (INDOEX).

  14. High performance liquid chromatography coupled with resonance Rayleigh scattering for the detection of three fluoroquinolones and mechanism study

    NASA Astrophysics Data System (ADS)

    Zhou, Mingqiong; Peng, Jingdong; He, Rongxing; He, Yuting; Zhang, Jing; Li, Aiping

    2015-02-01

    A reliable and versatile high performance liquid chromatography coupled with resonance Rayleigh scattering method was established for the determination of three fluoroquinolones, including levofloxacin, norfloxacin and enrofloxacin in water sample and human urine sample. In pH 4.4-4.6 Britton-Robinson buffer medium, the fluoroquinolones separated by high performance liquid chromatography could react with erythrosine to form 1:1 ion-association complexes, which could make contributions to the great enhancement of RRS. The resonance Rayleigh scattering signal was recorded at λex = λem = 330 nm. The resonance Rayleigh scattering spectral characteristics of the drugs and the experimental conditions such as pH, detection wavelength, erythrosine concentration, flow rate, the length of reaction tube were studied. Quantum chemistry calculation, Fourier transform infrared spectroscopy and absorption spectroscopy were used to discuss the reaction mechanism. The recoveries of samples added standard ranged from 97.53% to 102.00%, and the relative standard deviation was below 4.64%. The limit of detection (S/N = 3) of 0.05-0.12 μg mL-1 was reached, and the linear regression coefficients were all above 0.999. The proposed method was proved as a simple, low cost and high sensitivity method.

  15. Adaptation of the University of Wisconsin High Spectral Resolution Lidar for Polarization and Multiple Scattering Measurements

    NASA Technical Reports Server (NTRS)

    Eloranta, E. W.; Piironen, P. K.

    1992-01-01

    A new implementation of the High Spectral Resolution Lidar (HSRL) in an instrument van which allows measurements during field experiments is described. The instrument was modified to provide measurements of depolarization. In addition, both the signal amplitude and depolarization variations with receiver field of view are simultaneously measured. These modifications allow discrimination of ice clouds from water clouds and observation of multiple scattering contributions to the lidar return.

  16. ON THE SPECTRAL SHAPE OF RADIATION DUE TO INVERSE COMPTON SCATTERING CLOSE TO THE MAXIMUM CUTOFF

    SciTech Connect

    Lefa, E.; Kelner, S. R.; Aharonian, F. A.

    2012-07-10

    The spectral shape of radiation due to inverse Compton scattering is analyzed in the Thomson and the Klein-Nishina regime for electron distributions with exponential cutoff. We derive analytical, asymptotic expressions for the spectrum close to the maximum cutoff region. We consider monoenergetic, Planckian, and synchrotron photons as target photon fields. These approximations provide a direct link between the distribution of parent electrons and the upscattered spectrum at the cutoff region.

  17. Surface-enhanced resonance hyper-Raman scattering and surface-enhanced resonance Raman scattering of dyes adsorbed on silver electrode and silver colloid: a comparison study

    NASA Astrophysics Data System (ADS)

    Li, Wu-Hu; Li, Xiao-Yuan; Yu, Nai-Teng

    1999-10-01

    Surface-enhanced resonance hyper-Raman scattering (SERHRS) and surface-enhanced resonance Raman scattering (SERRS) of three dyes, rhodamine 6G, crystal violet and basic fuchsin, are studied comparatively on electrochemically roughened silver electrode and silver colloid, respectively. All three dyes show a better SERHRS efficiency on the silver colloid than on the silver electrode, a phenomenon just opposite to what we have recently observed for pyridine and pyrazine [Chem. Phys. Lett. 305 (1999) 303]. These results suggest that the efficiency of SEHRS depends not only on the active surfaces employed (colloidal metals versus roughened electrodes) but also on the types of the adsorbed molecules.

  18. Electron paramagnetic resonance and optical absorption spectral studies on chalcocite

    NASA Astrophysics Data System (ADS)

    Reddy, S. Lakshmi; Fayazuddin, Md.; Frost, Ray L.; Endo, Tamio

    2007-11-01

    A chalcocite mineral sample of Shaha, Congo is used in the present study. An electron paramagnetic resonance (EPR) study on powdered sample confirms the presence of Mn(II), Fe(III) and Cu(II). Optical absorption spectrum indicates that Fe(III) impurity is present in octahedral structure whereas Cu(II) is present in rhombically distorted octahedral environment. Mid-infrared results are due to water and sulphate fundamentals.

  19. Electron paramagnetic resonance and optical absorption spectral studies on chalcocite.

    PubMed

    Reddy, S Lakshmi; Fayazuddin, Md; Frost, Ray L; Endo, Tamio

    2007-11-01

    A chalcocite mineral sample of Shaha, Congo is used in the present study. An electron paramagnetic resonance (EPR) study on powdered sample confirms the presence of Mn(II), Fe(III) and Cu(II). Optical absorption spectrum indicates that Fe(III) impurity is present in octahedral structure whereas Cu(II) is present in rhombically distorted octahedral environment. Mid-infrared results are due to water and sulphate fundamentals. PMID:17324611

  20. Spectral Tuning of Plasmon Resonance in a Core/Shell (Au)Ag Nanocomposite

    NASA Astrophysics Data System (ADS)

    Panarin, A. Yu.; Abakshonok, A. V.; Agabekov, V. E.; Eryomin, A. N.; Terekhov, S. N.

    2015-01-01

    A bimetallic (Au)Ag nanocomposite with a core/shell structure was synthesized in aqueous solution and a H2O/EtOH mixture (1:1) containing polymers (carboxymethylcellulose, sodium polystyrenesulfonate, polyvinylpyrrolidone, dextran). Its structure and optical properties were characterized. The shape and position of scattering bands of colloidal noble-metal nanoparticles with optical density <0.1 were undistorted by solvent absorption. Scattering spectra had to be corrected for solutions of greater optical density. A method for correcting the resonant lightscattering spectra of Au and (Au)Ag nanoparticles was proposed for a single-beam apparatus. The possibility of surface plasmon resonance tuning for (Au)Ag with a short-wavelength shift of ~150 nm for the absorption band maximum and of ~84 nm for the resonant scattering band was demonstrated by varying the AgNO3 concentration during formation of the silver shell on the gold core.

  1. Collisionless spectral-kinetic Simulation of the Multipole Resonance Probe

    NASA Astrophysics Data System (ADS)

    Dobrygin, Wladislaw; Szeremley, Daniel; Schilling, Christian; Oberrath, Jens; Eremin, Denis; Mussenbrock, Thomas; Brinkmann, Ralf Peter

    2012-10-01

    Plasma resonance spectroscopy is a well established plasma diagnostic method realized in several designs. One of these designs is the multipole resonance probe (MRP). In its idealized - geometrically simplified - version it consists of two dielectrically shielded, hemispherical electrodes to which an RF signal is applied. A numerical tool is under development, which is capable of simulating the dynamics of the plasma surrounding the MRP in electrostatic approximation. In the simulation the potential is separeted in an inner and a vacuum potential. The inner potential is influenced by the charged partilces and is calculated by a specialized Poisson solver. The vacuum potential fulfills Laplace's equetion and consists of the applied voltage of the probe as boundary condition. Both potentials are expanded in spherical harmonics. For a practical particle pusher implementation, the expansion must be appropriately truncated. Compared to a PIC simulation a grid is unnecessary to calculate the force on the particles. This work purpose is a collisionless kinetic simulation, which can be used to investigate kinetic effects on the resonance behavior of the MRP.[4pt] [1] M. Lapke et al., Appl. Phys. Lett. 93, 2008, 051502.

  2. Recent measurements of the spectral backward-scattering coefficient in coastal waters

    NASA Astrophysics Data System (ADS)

    Maffione, Robert A.; Dana, David R.

    1997-02-01

    The backward scattering coefficient bb was measured in various coastal waters with fixed-angle backscattering sensors developed by the authors. Measurements were made at four discrete wavelengths covering the spectral range 440 to 675 nm. A power law spectral dependence of bb due to scattering by particles was investigated of the form bbp((lambda) ) equals bbp ((lambda) 0) ((lambda) 0/(lambda) )(gamma , where the superscript p denotes particle scattering and (lambda) is the wavelength. The exponent (gamma) depends on the particle size distribution and composition of particles. Extensive measurements in Monterey Bay, California, showed that 0.1 spectrally 'flat' waters measured.

  3. Velocity and Temperature Measurement in Supersonic Free Jets Using Spectrally Resolved Rayleigh Scattering

    NASA Technical Reports Server (NTRS)

    Panda, J.; Seasholtz, R. G.

    2004-01-01

    The flow fields of unheated, supersonic free jets from convergent and convergent-divergent nozzles operating at M = 0.99, 1.4, and 1.6 were measured using spectrally resolved Rayleigh scattering technique. The axial component of velocity and temperature data as well as density data obtained from a previous experiment are presented in a systematic way with the goal of producing a database useful for validating computational fluid dynamics codes. The Rayleigh scattering process from air molecules provides a fundamental means of measuring flow properties in a non-intrusive, particle free manner. In the spectrally resolved application, laser light scattered by the air molecules is collected and analyzed using a Fabry-Perot interferometer (FPI). The difference between the incident laser frequency and the peak of the Rayleigh spectrum provides a measure of gas velocity. The temperature is measured from the spectral broadening caused by the random thermal motion and density is measured from the total light intensity. The present point measurement technique uses a CW laser, a scanning FPI and photon counting electronics. The 1 mm long probe volume is moved from point to point to survey the flow fields. Additional arrangements were made to remove particles from the main as well as the entrained flow and to isolate FPI from the high sound and vibration levels produced by the supersonic jets. In general, velocity is measured within +/- 10 m/s accuracy and temperature within +/- 10 K accuracy.

  4. Carbon nanohorn-based nanofluids: characterization of the spectral scattering albedo.

    PubMed

    Mercatelli, Luca; Sani, Elisa; Giannini, Annalisa; Di Ninni, Paola; Martelli, Fabrizio; Zaccanti, Giovanni

    2012-01-01

    The full characterization of the optical properties of nanofluids consisting of single-wall carbon nanohorns of different morphologies in aqueous suspensions is carried out using a novel spectrophotometric technique. Information on the nanofluid scattering and absorption spectral characteristics is obtained by analyzing the data within the single scattering theory and validating the method by comparison with previous monochromatic measurements performed with a different technique. The high absorption coefficient measured joint to the very low scattering albedo opens promising application perspectives for single-wall carbon nanohorn-based fluid or solid suspensions. The proposed approximate approach can be extended also to other low-scattering turbid media.PACS: 78.35.+c Brillouin and Rayleigh scattering, other light scattering; 78.40.Ri absorption and reflection spectra, fullerenes and related materials; 81.05.U- carbon/carbon-based materials; 78.67.Bf optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures, nanocrystals, nanoparticles, and nanoclusters. PMID:22297089

  5. Chemical imaging and microspectroscopy with spectral focusing coherent anti-Stokes Raman scattering.

    PubMed

    Chen, Bi-Chang; Sung, Jiha; Wu, Xiaoxi; Lim, Sang-Hyun

    2011-02-01

    We demonstrate two different coherent anti-Stokes Raman scattering (CARS) microscopy and microspectroscopy methods based on the spectral focusing mechanism. The first method uses strongly chirped broadband pulses from a single Ti:sapphire laser and generates CARS signals at the fingerprint region. Fast modulation of the time delay between the pump and Stokes laser pulses coupled with lock-in signal detection significantly reduces the nonresonant background and produces Raman-like CARS signals with a spectral resolution of 20 cm(-1). The second method generates CARS signals in the CH (carbon-hydrogen) stretching region with IR supercontinuum pulses from a photonic crystal fiber. The spectral resolution of 30 cm(-1) is achieved. Maximum entropy method is used to retrieve a Raman-equivalent CARS spectrum from lipid membranes. Chemical imaging and microspectroscopy are demonstrated with various samples. PMID:21361675

  6. Attometer resolution spectral analysis based on polarization pulling assisted Brillouin scattering merged with heterodyne detection.

    PubMed

    Preussler, Stefan; Schneider, Thomas

    2015-10-01

    Spectral analysis is essential for measuring and monitoring advanced optical communication systems and the characterization of active and passive devices like amplifiers, filters and especially frequency combs. Conventional devices have a limited resolution or tuning range. Therefore, the true spectral shape of the signal remains hidden. In this work, a small part of the signal under test is preselected with help of the polarization pulling effect of stimulated Brillouin scattering where all unwanted spectral components are suppressed. Subsequently, this part is analyzed more deeply through heterodyne detection. Thereby, the local oscillator is generated from a narrow linewidth fiber laser which acts also as pump wave for Brillouin scattering. By scanning the pump wave together with the local oscillator through the signal spectrum, the whole signal is measured. The method is tunable over a broad wavelength range, is not affected by unwanted mixing products and utilizes a conventional narrow bandwidth photo diode. First proof of concept experiments show the measurement of the power spectral density function with a resolution in the attometer or lower kilohertz range at 1550 nm. PMID:26480198

  7. The complex ion structure of warm dense carbon measured by spectrally resolved x-ray scattering

    SciTech Connect

    Kraus, D.; Barbrel, B.; Falcone, R. W.; Vorberger, J.; Helfrich, J.; Frydrych, S.; Ortner, A.; Otten, A.; Roth, F.; Schaumann, G.; Schumacher, D.; Siegenthaler, K.; Wagner, F.; Roth, M.; Gericke, D. O.; Wünsch, K.; Bachmann, B.; Döppner, T.; Bagnoud, V.; Blažević, A.; and others

    2015-05-15

    We present measurements of the complex ion structure of warm dense carbon close to the melting line at pressures around 100 GPa. High-pressure samples were created by laser-driven shock compression of graphite and probed by intense laser-generated x-ray sources with photon energies of 4.75 keV and 4.95 keV. High-efficiency crystal spectrometers allow for spectrally resolving the scattered radiation. Comparing the ratio of elastically and inelastically scattered radiation, we find evidence for a complex bonded liquid that is predicted by ab-initio quantum simulations showing the influence of chemical bonds under these conditions. Using graphite samples of different initial densities we demonstrate the capability of spectrally resolved x-ray scattering to monitor the carbon solid-liquid transition at relatively constant pressure of 150 GPa. Showing first single-pulse scattering spectra from cold graphite of unprecedented quality recorded at the Linac Coherent Light Source, we demonstrate the outstanding possibilities for future high-precision measurements at 4th Generation Light Sources.

  8. Spectral element method-based parabolic equation for EM-scattering problems

    NASA Astrophysics Data System (ADS)

    He, Zi; Fan, Zhen-Hong; Chen, Ru-Shan

    2016-01-01

    The traditional parabolic equation (PE) method is based on the finite difference (FD) scheme. However, the scattering object cannot be well approximated for complex geometries. As a result, a large number of meshes are needed to discretize the complex scattering objects. In this paper, the spectral element method is introduced to better approximate the complex geometry in each transverse plane, while the FD scheme is used along the paraxial direction. This proposed algorithm begins with expanding the reduced scattered fields with the Gauss-Lobatto-Legendre polynomials and testing them by the Galerkin's method in each transverse plane. Then, the calculation can be taken plane by plane along the paraxial direction. Numerical results demonstrate that the accuracy can be improved by the proposed method with larger meshes when compared with the traditional PE method.

  9. Investigation of mixed ionospheric and fround scatter using high spectral content pulse sequences for SuperDARN radars

    NASA Astrophysics Data System (ADS)

    Spaleta, J.; Bristow, W. A.

    2013-12-01

    SuperDARN radars estimate plasma drift velocities from the Doppler shift observed on signals scattered from field-aligned density irregularities. These field-aligned density irregularities are embedded in the ionospheric plasma, and move at the same velocity as background plasma. As a result, the electromagnetic signals scattered from these irregularities are Doppler shifted. The SuperDARN radars routinely observe ionospheric scatter Doppler velocities ranging from zero to thousands of meters per second. The radars determine the Doppler shift of the ionospheric scatter by linear fitting the phase of an auto correlation function derived from the radar pulse sequence. The phase fitting technique employed assumes a single dominant velocity is present in the signal. In addition, the SuperDARN radars can also observe signals scattered from the ground. Once refracted by the ionospheric plasma and bent earthward, the radar pulses eventually reach the ground where they scatter, sending signal back to the radar. This ground-scatter signal is characterized as having a low Doppler shift and low spectral width. The SuperDARN radars are able to use these signal characteristics to discriminate the ground scatter signal from the ionospheric scatter, when regions of ground scatter are isolated from ionospheric scatter returns. The phase fitting assumption of a single dominate target can easily be violated at ranges where ground and ionospheric scatter mix together. Due to the wide elevation angle extent of the SuperDARN radar design, ground and ionospheric scatter from different propagation paths can mix together in the return signal. When this happens, the fitting algorithm attempts to fit to the dominant signal, and if ground scatter dominates, information about the ionospheric scatter at that range can be unresolved. One way to address the mix scatter situation is to use a high spectral content pulse sequence together with a spectral estimation technique. The high spectral

  10. Franck-Condon processes in pentacene monolayers revealed in resonance Raman scattering

    NASA Astrophysics Data System (ADS)

    He, Rui; Tassi, Nancy G.; Blanchet, Graciela B.; Pinczuk, Aron

    2011-03-01

    Franck-Condon processes in pentacene monolayers are revealed in resonance Raman scattering from intramolecular vibrations. The Raman intensities from a totally symmetric vibrational mode display resonance enhancement double peaks when incident or scattered photon energies overlap the free exciton (FE) optical emission. The two resonances are of about equal strength. This remarkable symmetry in the resonance Raman profile suggests that Franck-Condon overlap integrals for the respective vibronic transitions have the same magnitude, which could be explained by the small displacement of potential energy curves along the configuration coordinate upon the FE excitation. The interference between scattering amplitudes in the Raman resonance reveals quantum coherence of the symmetry-split states (Davydov doublet) of the lowest intrinsic singlet exciton in pentacene monolayers.

  11. Evidence for Resonance Scattering in the X-ray Spectrum of Zeta Puppis

    NASA Technical Reports Server (NTRS)

    Leutenegger, Maurice

    2008-01-01

    We present XMM-Newton Reflection Grating Spectrometer observations of pairs of X-ray emission line profiles from the 0 star Zeta Pup that originate from the same He-like ion. The two profiles in each pair have different shapes and cannot both be consistently fit by models assuming the same wind parameters. We show that the differences in profile shape can be accounted for in a model including the effects of resonance scattering, which affects the resonance line in the pair but not the intercombination line. This implies that resonance scattering is also important in single resonance lines, where its effect is difficult to distinguish from a low effective continuum optical depth in the wind. Thus, resonance scattering may help reconcile X-ray line profile shapes with literature mass-loss rates.

  12. The limitations of resonant Compton scattering as a gamma-ray burst model

    NASA Technical Reports Server (NTRS)

    Brainerd, J. J.

    1992-01-01

    Resonant Compton upscattering is commended as a mechanism that produces a hard gamma-ray spectrum while suppressing X-rays. This model, however, has severe physical and observational limitations. Effective X-ray suppression places a lower limit on the electron density; above this limit X-rays scatter multiple times, so the single-scattering approximation of this mechanism is invalid. Multiple scattering produces a spectrum that is much harder than the single-scattering spectrum. As the Thomson optical depth of a power-law electron beam approaches unity, photon spawning commences at a high rate and physically invalidates the underlying electron distribution. The Compton upscattering model is therefore only valid over a narrow range of electron densities. An observational consequence of this model is the absence of the third cyclotron resonance. Resonant scattering produces gamma-rays that propagate nearly along the magnetic field. The resonant cross section of the third harmonic, which is strongly angle dependent, falls below the Compton continuum for these gamma rays. The observation of a third cyclotron resonance in a gamma-ray burst spectrum would eliminate resonant Compton scattering as a gamma-ray burst process.

  13. Resonance light scattering determination of metallothioneins using levofloxacin-palladium complex as a light scattering probe

    NASA Astrophysics Data System (ADS)

    Xue, Jin-Hua; Qian, Qiu-Mei; Wang, Yong-Sheng; Meng, Xia-Ling; Liu, Lu

    2013-02-01

    A novel method of resonance light scattering (RLS) was developed for the analysis of trace metallothioneins (MTs) in human urine. In a CH3COOH-CH3COONa buffer solution of pH 4.5, the formation of a complex between levofloxacin (LEV)-Pd and MTs led to enhance the RLS intensity of the system, and the enhanced RLS intensity at 468 nm was proportional to the concentration of MTs in the range of 0.059-22.4 μg mL-1. The linear regression equation was ΔI = 127.5 ρ (μg mL-1)-88.02 with a correlation coefficient of 0.9992, and the detection limit of 17.8 ng mL-1. The relative standard deviation and the average recovery were 3.8-5.4% (n = 11) and 92.15%, respectively. The proposed method is convenient, reliable and sensitive, and has been used successfully for the determination of trace MTs in human urine samples.

  14. Monte Carlo Code System for Calculation of Multiple Scattering of Neutrons in the Resonance Region.

    Energy Science and Technology Software Center (ESTSC)

    1983-01-25

    Version 00 MCRTOF systematically calculates capture and scattering probabilities for neutrons incident on a material disk, with neutron cross sections calculated from the resonance parameters. Capture, front and rear face scattering, transmission, etc., probabilities are obtained from the average destinations of the incident neutrons.

  15. Spectroscopy of strongly correlated systems: Resonant x-ray scattering without energy resolution in the scattered beam

    NASA Astrophysics Data System (ADS)

    Braicovich, L.; Tagliaferri, A.; Annese, E.; Ghiringhelli, G.; Dallera, C.; Fracassi, F.; Palenzona, A.; Brookes, N. B.

    2007-02-01

    The total emission of photons excited by x rays (90° between incident and detected photons) is measured vs the incident photon energy at the CeM4,5 edges in CeIn3 , CeSnIn2 , CeAl2 , CePd3 , and CeRh2 , and at the NiL2,3 edges in NiO. The results show the signature of a second-order process; these experiments must be interpreted as genuine resonant inelastic scattering (though without energy resolution of the emitted photons) and not as absorption spectroscopy measured by the total fluorescence yield. In Ce compounds, information on bulk hybridization can thus be obtained simply and with high sensitivity. The branching ratio between the different scattering channels is also measured. This approach opens innovative perspectives in resonant inelastic x-ray scattering.

  16. Nuclear magnetic resonance spectral analysis and molecular properties of berberine

    NASA Astrophysics Data System (ADS)

    Huang, Ming-Ju; Lee, Ken S.; Hurley, Sharon J.

    An extensive theoretical study of berberine has been performed at the ab initio HF/6-31G**, HF/6-311G**, and B3LYP/6-311G** levels with and without solvent effects. The optimized structures are compared with X-ray data. We found that the optimized structures with solvent effects are in slightly better agreement with X-ray data than those without solvent effects. The 1H and 13C nuclear magnetic resonance (NMR) chemical shifts of berberine were calculated by using the gauge-independent atomic orbital (GIAO) (with and without solvent effects), CSGT, and IGAIM methods. The calculated chemical shifts were compared with the two-dimensional NMR experimental data. Overall, the calculated chemical shifts show very good agreement with the experimental results. The harmonic vibrational frequencies for berberine were calculated at the B3LYP/6-311G** level.

  17. CARS Spectral Fitting with Multiple Resonant Species using Sparse Libraries

    NASA Technical Reports Server (NTRS)

    Cutler, Andrew D.; Magnotti, Gaetano

    2010-01-01

    The dual pump CARS technique is often used in the study of turbulent flames. Fast and accurate algorithms are needed for fitting dual-pump CARS spectra for temperature and multiple chemical species. This paper describes the development of such an algorithm. The algorithm employs sparse libraries, whose size grows much more slowly with number of species than a conventional library. The method was demonstrated by fitting synthetic "experimental" spectra containing 4 resonant species (N2, O2, H2 and CO2), both with noise and without it, and by fitting experimental spectra from a H2-air flame produced by a Hencken burner. In both studies, weighted least squares fitting of signal, as opposed to least squares fitting signal or square-root signal, was shown to produce the least random error and minimize bias error in the fitted parameters.

  18. Bound and scattering states in harmonic waveguides in the vicinity of free space Feshbach resonances

    NASA Astrophysics Data System (ADS)

    Wang, Gaoren; Giannakeas, Panagiotis; Schmelcher, Peter

    2016-08-01

    The two-body bound and scattering properties in an one-dimensional harmonic waveguide close to free space magnetic Feshbach resonances are investigated based on the local frame transformation approach within a single partial wave approximation. An energy and magnetic field dependent free space phase shift is adopted in the current theoretical framework. For both s- and p-wave interaction, the least bound state in the waveguide dissociates into the continuum at the resonant magnetic field where the effective one-dimensional scattering length {a}{{1D}} diverges. Consequently, the association of atoms into molecules in the waveguide occurs when the magnetic field is swept adiabatically across the pole of {a}{{1D}}. In the vicinity of broad s-wave resonances, the resonant magnetic field is nearly independent on the transverse confining frequency {ω }\\perp of the waveguide. Close to p-wave and narrow s-wave resonances, the resonant magnetic field changes as {ω }\\perp varies.

  19. A recursive method for updating apple firmness prediction models based on spectral scattering images

    NASA Astrophysics Data System (ADS)

    Peng, Yankun; Lu, Renfu

    2007-09-01

    Multispectral scattering is effective for nondestructive prediction of fruit firmness. However, the established prediction models for multispectral scattering are variety specific and may not perform appropriately for fruit harvested from different orchards or at different times. In this research, a recursive least squares method was proposed to update the existing prediction model by adding samples from a new population to assure good performance of the model for predicting fruit from the new population. Multispectral scattering images acquired by a multispectral imaging system from Golden Delicious apples that were harvested at the same time but had different postharvest storage time periods were used to develop the updating method. Radial scattering profiles were described by the modified Lorentzian distribution (MLD) function with four profile parameters for eight wavelengths. Multi-linear regression was performed on MLD parameters to establish prediction models for fruit firmness for each group. The prediction model established in the first group was then updated by using selected samples from the second group, and four different sampling methods were compared and validated with the rest apples. The prediction model corrected by the model-updating method gave good firmness predictions with the correlation coefficient (r) of 0.86 and the standard error of prediction (SEP) of 6.11 N. This model updating method is promising for implementing the spectral scattering technique for real-time prediction of apple fruit firmness.

  20. Resonance and non-resonance effect of continuum states of 6Li on elastic scattering angular distributions

    NASA Astrophysics Data System (ADS)

    Gómez Camacho, A.

    2016-07-01

    CDCC calculations of elastic scattering angular distributions for reactions of the weakly bound projectile 6Li with targets 28Si and 58Ni at energies around the Coulomb barrier are presented. Special emphasis is given to account for the effect of couplings from 6Li resonance states l = 2, J π = 3+, 2+, 1+. Similarly, the effect produced by non-resonant state couplings is studied. The convergent calculations are carried out with global α-target and d-target interactions. The calculated elastic scattering angular distributions are in general in good agreement with the measurements for the systems considered in this work. It is found that the calculations with only resonance states are very similar to that with all couplings (resonance+non-resonance). So, the absence of these states have a strong effect on elastic scattering (non-resonance states calculation). It is shown that the effects increase as the collision energy increases. An interpretation of the strength of the different effects is given in terms of the polarization potentials that emerge from the different couplings.

  1. Double resonance surface enhanced Raman scattering substrates: an intuitive coupled oscillator model.

    PubMed

    Chu, Yizhuo; Wang, Dongxing; Zhu, Wenqi; Crozier, Kenneth B

    2011-08-01

    The strong coupling between localized surface plasmons and surface plasmon polaritons in a double resonance surface enhanced Raman scattering (SERS) substrate is described by a classical coupled oscillator model. The effects of the particle density, the particle size and the SiO2 spacer thickness on the coupling strength are experimentally investigated. We demonstrate that by tuning the geometrical parameters of the double resonance substrate, we can readily control the resonance frequencies and tailor the SERS enhancement spectrum. PMID:21934853

  2. A complex guided spectral transform Lanczos method for studying quantum resonance states

    DOE PAGESBeta

    Yu, Hua-Gen

    2014-12-28

    A complex guided spectral transform Lanczos (cGSTL) algorithm is proposed to compute both bound and resonance states including energies, widths and wavefunctions. The algorithm comprises of two layers of complex-symmetric Lanczos iterations. A short inner layer iteration produces a set of complex formally orthogonal Lanczos (cFOL) polynomials. They are used to span the guided spectral transform function determined by a retarded Green operator. An outer layer iteration is then carried out with the transform function to compute the eigen-pairs of the system. The guided spectral transform function is designed to have the same wavefunctions as the eigenstates of the originalmore » Hamiltonian in the spectral range of interest. Therefore the energies and/or widths of bound or resonance states can be easily computed with their wavefunctions or by using a root-searching method from the guided spectral transform surface. The new cGSTL algorithm is applied to bound and resonance states of HO₂, and compared to previous calculations.« less

  3. A complex guided spectral transform Lanczos method for studying quantum resonance states

    SciTech Connect

    Yu, Hua-Gen

    2014-12-28

    A complex guided spectral transform Lanczos (cGSTL) algorithm is proposed to compute both bound and resonance states including energies, widths and wavefunctions. The algorithm comprises of two layers of complex-symmetric Lanczos iterations. A short inner layer iteration produces a set of complex formally orthogonal Lanczos (cFOL) polynomials. They are used to span the guided spectral transform function determined by a retarded Green operator. An outer layer iteration is then carried out with the transform function to compute the eigen-pairs of the system. The guided spectral transform function is designed to have the same wavefunctions as the eigenstates of the original Hamiltonian in the spectral range of interest. Therefore the energies and/or widths of bound or resonance states can be easily computed with their wavefunctions or by using a root-searching method from the guided spectral transform surface. The new cGSTL algorithm is applied to bound and resonance states of HO₂, and compared to previous calculations.

  4. A complex guided spectral transform Lanczos method for studying quantum resonance states

    SciTech Connect

    Yu, Hua-Gen

    2014-12-28

    A complex guided spectral transform Lanczos (cGSTL) algorithm is proposed to compute both bound and resonance states including energies, widths, and wavefunctions. The algorithm comprises of two layers of complex-symmetric Lanczos iterations. A short inner layer iteration produces a set of complex formally orthogonal Lanczos polynomials. They are used to span the guided spectral transform function determined by a retarded Green operator. An outer layer iteration is then carried out with the transform function to compute the eigen-pairs of the system. The guided spectral transform function is designed to have the same wavefunctions as the eigenstates of the original Hamiltonian in the spectral range of interest. Therefore, the energies and/or widths of bound or resonance states can be easily computed with their wavefunctions or by using a root-searching method from the guided spectral transform surface. The new cGSTL algorithm is applied to bound and resonance states of HO{sub 2}, and compared to previous calculations.

  5. A conservative spectral method for the Boltzmann equation with anisotropic scattering and the grazing collisions limit

    SciTech Connect

    Gamba, Irene M.; Haack, Jeffrey R.

    2014-08-01

    We present the formulation of a conservative spectral method for the Boltzmann collision operator with anisotropic scattering cross-sections. The method is an extension of the conservative spectral method of Gamba and Tharkabhushanam [17,18], which uses the weak form of the collision operator to represent the collisional term as a weighted convolution in Fourier space. The method is tested by computing the collision operator with a suitably cut-off angular cross section and comparing the results with the solution of the Landau equation. We analytically study the convergence rate of the Fourier transformed Boltzmann collision operator in the grazing collisions limit to the Fourier transformed Landau collision operator under the assumption of some regularity and decay conditions of the solution to the Boltzmann equation. Our results show that the angular singularity which corresponds to the Rutherford scattering cross section is the critical singularity for which a grazing collision limit exists for the Boltzmann operator. Additionally, we numerically study the differences between homogeneous solutions of the Boltzmann equation with the Rutherford scattering cross section and an artificial cross section, which give convergence to solutions of the Landau equation at different asymptotic rates. We numerically show the rate of the approximation as well as the consequences for the rate of entropy decay for homogeneous solutions of the Boltzmann equation and Landau equation.

  6. Spectrally resolving and scattering-compensated x-ray luminescence/fluorescence computed tomography

    PubMed Central

    Cong, Wenxiang; Shen, Haiou; Wang, Ge

    2011-01-01

    The nanophosphors, or other similar materials, emit near-infrared (NIR) light upon x-ray excitation. They were designed as optical probes for in vivo visualization and analysis of molecular and cellular targets, pathways, and responses. Based on the previous work on x-ray fluorescence computed tomography (XFCT) and x-ray luminescence computed tomography (XLCT), here we propose a spectrally-resolving and scattering-compensated x-ray luminescence/fluorescence computed tomography (SXLCT or SXFCT) approach to quantify a spatial distribution of nanophosphors (other similar materials or chemical elements) within a biological object. In this paper, the x-ray scattering is taken into account in the reconstruction algorithm. The NIR scattering is described in the diffusion approximation model. Then, x-ray excitations are applied with different spectra, and NIR signals are measured in a spectrally resolving fashion. Finally, a linear relationship is established between the nanophosphor distribution and measured NIR data using the finite element method and inverted using the compressive sensing technique. The numerical simulation results demonstrate the feasibility and merits of the proposed approach. PMID:21721815

  7. Parameter-induced stochastic resonance based on spectral entropy and its application to weak signal detection

    SciTech Connect

    Zhang, Jinjing; Zhang, Tao

    2015-02-15

    The parameter-induced stochastic resonance based on spectral entropy (PSRSE) method is introduced for the detection of a very weak signal in the presence of strong noise. The effect of stochastic resonance on the detection is optimized using parameters obtained in spectral entropy analysis. Upon processing employing the PSRSE method, the amplitude of the weak signal is enhanced and the noise power is reduced, so that the frequency of the signal can be estimated with greater precision through spectral analysis. While the improvement in the signal-to-noise ratio is similar to that obtained using the Duffing oscillator algorithm, the computational cost reduces from O(N{sup 2}) to O(N). The PSRSE approach is applied to the frequency measurement of a weak signal made by a vortex flow meter. The results are compared with those obtained applying the Duffing oscillator algorithm.

  8. Evidence for dibaryon resonances in nucleon-nucleon scattering

    SciTech Connect

    Roberts, J.B.

    1980-01-01

    There has been a revival of interest in the subject of nucleon-nucleon resonances in the past 3 to 4 years, largely generated by experimental results from the polarized beam program at the Argonne ZGS. Evidence from experimental results and phase shift and phenomenological analyses incorporating these results regarding the existence of these resonances is summarized. 20 figures.

  9. Double-confocal resonator for X-ray generation via intracavity Thomson scattering

    SciTech Connect

    Xie, M.

    1995-12-31

    There has been a growing interest in developing compact X-ray sources through Thomson scattering of a laser beam by a relativistic electron beam. For higher X-ray flux it is desirable to have the scattering to occur inside an optical resonator where the laser power is higher. In this paper I propose a double-confocal resonator design optimized for head-on Thomson scattering inside an FEL oscillator and analyze its performance taking into account the diffraction and FEL gain. A double confocal resonator is equivalent to two confocal resonators in series. Such a resonator has several advantages: it couples electron beam through and X-ray out of the cavity with holes on cavity mirrors, thus allowing the system to be compact; it supports the FEL mode with minimal diffraction loss through the holes; it provides a laser focus in the forward direction for a better mode overlap with the electron beam; and it provides a focus at the same location in the backward direction for higher Thomson scattering efficiency; in addition, the mode size at the focal point and hence the Rayleigh range can be adjusted simply through intracavity apertures; furthermore, it gives a large mode size at the mirrors to reduce power loading. Simulations as well as analytical results will be presented. Also other configurations of intracavity Thomson scattering where the double-confocal resonator could be useful will be discussed.

  10. Electromagnetic scattering by harmonically expanding surfaces and related complex resonances

    NASA Astrophysics Data System (ADS)

    Censor, D.

    1985-02-01

    A relativistically exact iterative method is developed for scattering of electromagnetic waves by expanding surfaces. In particular, the problems of the expanding cylinder and sphere are computed. It is shown that expanding scatterers respond to harmonic excitation by radiating nonharmonic waves. These waves involve complex frequencies, which are computed here. The method involves secular terms in t; therefore its validity for harmonic excitation is limited to early times. However, in the case of impulse excitation and transient scattering this problem is automatically resolved by the fact that the signal is exponentially decaying and the secular terms have no large-time effect.