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Sample records for rf-driven negative hydrogen

  1. Plasma And Beam Homogeneity Of The RF-Driven Negative Hydrogen Ion Source For ITER NBI

    SciTech Connect

    Fantz, U.; Franzen, P.; Kraus, W.; Wuenderlich, D.; Gutser, R.; Berger, M.

    2009-03-12

    The neutral beam injection (NBI) system of ITER is based on a large RF driven negative hydrogen ion source. For good beam transmission ITER requires a beam homogeneity of better than 10%. The plasma uniformity and the correlation with the beam homogeneity are being investigated at the prototype ion sources at IPP. Detailed studies are carried out at the long pulse test facility MANITU with a source of roughly 1/8 of the ITER source size. The plasma homogeneity close to plasma grid is measured by optical emission spectroscopy and by fixed Langmuir probes working in the ion saturation region. The beam homogeneity is measured with a spatially resolved H{sub {alpha}} Doppler-shifted beam spectroscopy system. The plasma top-to-bottom symmetry improves with increasing RF power and increasing bias voltage which is applied to suppress the co-extracted electron current. The symmetry is better in deuterium than in hydrogen. The boundary layer near the plasma grid determines the plasma symmetry. At high ion currents with a low amount of co-extracted electrons the plasma is symmetrical and the beam homogeneity is typically 5-10%(RMS). The size scaling and the influence of the magnetic field strength of the filter field created by a plasma grid current is studied at the test facility RADI (roughly a 1/2 size ITER source) at ITER relevant RF power levels. In volume operation in deuterium (non-cesiated source), the plasma illumination of the grid is satisfying.

  2. Operation of RF driven negative ion source in a pure-hydrogen mode

    NASA Astrophysics Data System (ADS)

    Abdrashitov, G.; Belchenko, Yu.; Ivanov, A. A.; Gusev, I.; Senkov, D.; Sanin, A.; Shikhovtsev, I.; Sotnikov, O.; Kondakov, A.

    2015-04-01

    The production of negative hydrogen ions in the radio-frequency driven long-pulsed source with external antenna is studied. RF drivers with various geometry of external antenna, Faraday shield and magnets at the rear flange were examined. H- beam extraction through the single emission aperture was performed in the source pure-hydrogen mode with no external seed of alkali additives. H- beam with ion emission current density up to 5 mA/cm2 and energy up to 75 keV was regularly obtained in the 1 s pulses of the pure-hydrogen mode. The regular temporal increase of H- ion production due to deposition of impurities on the plasma grid surface was recorded. The H- emission current density increased up to 9 mA/cm2 in this case.

  3. Operation of RF driven negative ion source in a pure-hydrogen mode

    SciTech Connect

    Abdrashitov, G.; Belchenko, Yu. Gusev, I.; Senkov, D.; Sanin, A.; Shikhovtsev, I.; Kondakov, A.; Ivanov, A. A.; Sotnikov, O.

    2015-04-08

    The production of negative hydrogen ions in the radio-frequency driven long-pulsed source with external antenna is studied. RF drivers with various geometry of external antenna, Faraday shield and magnets at the rear flange were examined. H- beam extraction through the single emission aperture was performed in the source pure-hydrogen mode with no external seed of alkali additives. H- beam with ion emission current density up to 5 mA/cm{sup 2} and energy up to 75 keV was regularly obtained in the 1 s pulses of the pure-hydrogen mode. The regular temporal increase of H- ion production due to deposition of impurities on the plasma grid surface was recorded. The H- emission current density increased up to 9 mA/cm{sup 2} in this case.

  4. Simulation of cesium injection and distribution in rf-driven ion sources for negative hydrogen ion generation

    SciTech Connect

    Gutser, R.; Wuenderlich, D.; Fantz, U.

    2010-02-15

    Cesium seeded sources for surface generated negative hydrogen ions are major components of neutral beam injection systems in future large-scale fusion experiments such as ITER. Stability and delivered current density depend highly on the cesium conditions during plasma-on and plasma-off phases of the ion source. The Monte Carlo code CSFLOW3D was used to study the transport of neutral and ionic cesium in both phases. Homogeneous and intense flows were obtained from two cesium sources in the expansion region of the ion source and from a dispenser array, which is located 10 cm in front of the converter surface.

  5. Efficient cesiation in RF driven surface plasma negative ion source

    NASA Astrophysics Data System (ADS)

    Belchenko, Yu.; Ivanov, A.; Konstantinov, S.; Sanin, A.; Sotnikov, O.

    2016-02-01

    Experiments on hydrogen negative ions production in the large radio-frequency negative ion source with cesium seed are described. The system of directed cesium deposition to the plasma grid periphery was used. The small cesium seed (˜0.5 G) provides an enhanced H- production during a 2 month long experimental cycle. The gradual increase of negative ion yield during the long-term source runs was observed after cesium addition to the source. The degraded H- production was recorded after air filling to the source or after the cesium washing away from the driver and plasma chamber walls. The following source conditioning by beam shots produces the gradual recovery of H- yield to the high value. The effect of H- yield recovery after cesium coverage passivation by air fill was studied. The concept of cesium coverage replenishment and of H- yield recovery due to sputtering of cesium from the deteriorated layers is discussed.

  6. Efficient cesiation in RF driven surface plasma negative ion source.

    PubMed

    Belchenko, Yu; Ivanov, A; Konstantinov, S; Sanin, A; Sotnikov, O

    2016-02-01

    Experiments on hydrogen negative ions production in the large radio-frequency negative ion source with cesium seed are described. The system of directed cesium deposition to the plasma grid periphery was used. The small cesium seed (∼0.5 G) provides an enhanced H(-) production during a 2 month long experimental cycle. The gradual increase of negative ion yield during the long-term source runs was observed after cesium addition to the source. The degraded H(-) production was recorded after air filling to the source or after the cesium washing away from the driver and plasma chamber walls. The following source conditioning by beam shots produces the gradual recovery of H(-) yield to the high value. The effect of H(-) yield recovery after cesium coverage passivation by air fill was studied. The concept of cesium coverage replenishment and of H(-) yield recovery due to sputtering of cesium from the deteriorated layers is discussed. PMID:26932015

  7. Optical emission spectroscopy at the large RF driven negative ion test facility ELISE: Instrumental setup and first results

    SciTech Connect

    Wünderlich, D.; Fantz, U.; Franzen, P.; Riedl, R.; Bonomo, F.

    2013-09-15

    One of the main topics to be investigated at the recently launched large (A{sub source}= 1.0 × 0.9 m{sup 2}) ITER relevant RF driven negative ion test facility ELISE (Extraction from a Large Ion Source Experiment) is the connection between the homogeneity of the plasma parameters close to the extraction system and the homogeneity of the extracted negative hydrogen ion beam. While several diagnostics techniques are available for measuring the beam homogeneity, the plasma parameters are determined by optical emission spectroscopy (OES) solely. First OES measurements close to the extraction system show that without magnetic filter field the vertical profile of the plasma emission is more or less symmetric, with maxima of the emission representing the projection of the plasma generation volumes, and a distinct minimum in between. The profile changes with the strength of the magnetic filter field but under all circumstances the plasma emission in ELISE is much more homogeneous compared to the smaller IPP prototype sources. Planned after this successful demonstration of the ELISE OES system is to combine OES with tomography in order to determine locally resolved values for the plasma parameters.

  8. Optical emission spectroscopy at the large RF driven negative ion test facility ELISE: Instrumental setup and first results

    NASA Astrophysics Data System (ADS)

    Wünderlich, D.; Fantz, U.; Franzen, P.; Riedl, R.; Bonomo, F.

    2013-09-01

    One of the main topics to be investigated at the recently launched large (Asource = 1.0 × 0.9 m2) ITER relevant RF driven negative ion test facility ELISE (Extraction from a Large Ion Source Experiment) is the connection between the homogeneity of the plasma parameters close to the extraction system and the homogeneity of the extracted negative hydrogen ion beam. While several diagnostics techniques are available for measuring the beam homogeneity, the plasma parameters are determined by optical emission spectroscopy (OES) solely. First OES measurements close to the extraction system show that without magnetic filter field the vertical profile of the plasma emission is more or less symmetric, with maxima of the emission representing the projection of the plasma generation volumes, and a distinct minimum in between. The profile changes with the strength of the magnetic filter field but under all circumstances the plasma emission in ELISE is much more homogeneous compared to the smaller IPP prototype sources. Planned after this successful demonstration of the ELISE OES system is to combine OES with tomography in order to determine locally resolved values for the plasma parameters.

  9. Operation of a cw rf driven ion source with hydrogen and deuterium gas{sup a}

    SciTech Connect

    Melnychuk, S.T.; Debiak, T.W.; Sredniawski, J.J.

    1996-04-01

    We will describe the operation of a cw rf driven multicusp ion source designed for extraction of high current hydrogen and deuterium beams. The source is driven at 2 MHz by a 2.5 turn induction antenna immersed in the plasma. Bare stainless-steel and porcelain-coated Cu antennas have been used. The plasma load is matched to the rf generator by a variable tap {ital N}:1 transformer isolated to 46 kV, and an LC network on the secondary. With H{sub 2} gas the source can be operated at pressures between 5 and 60 mT with power reflection coefficients {lt}0.01. The extracted ion current density with a porcelain-coated antenna is approximately given by 35 mA/cm{sup 2}/kW with an 80 G dipole filter field for input powers from 3.5 to 6.6 kW. The current density remained constant for operation with a 6 and an 8 mm aperture. The source has been operated for 260 h at 3.6 kW with a single-porcelain-coated antenna. Mass spectrometer measurements of the extracted beam at this power show a species mix for H{sup +}:H{sup +}{sub 2}:H{sup +}{sub 3}:OH{sup +} of 0.49: 0.04: 0.42: 0.04. The calculated beam divergence using the IGUN code is compared with the measured divergence from an electrostatic sweep emittance scanner designed for high-power cw beam diagnostics. Phase space measurements at 40 kV and 23 mA beam current result in a normalized rms emittance of 0.09 {pi}mmmrad. {copyright} {ital 1996 American Institute of Physics.}

  10. Operation of a cw rf driven ion source with hydrogen and deuterium gas (abstract){sup a}

    SciTech Connect

    Melnychuk, S.T.; Debiak, T.W.; Sredniawski, J.J.

    1996-03-01

    We will describe the operation of a cw rf driven multicusp ion source designed for extraction of high current hydrogen and deuterium beams. The source is driven at 2 MHz by a 2.5 turn induction antenna immersed in the plasma. Bare stainless-steel and porcelain-coated Cu antennas have been used. The plasma load is matched to the rf generator by a variable tap {ital N}:1 transformer isolated to 46 kV, and an LC network on the secondary. With H{sub 2} gas the source can be operated at pressures between 5 and 60 mT with power reflection coefficients {lt}0.01. The extracted ion current density with a porcelain-coated antenna is approximately given by 35 mA/cm{sup 2}/kW with an 80 G dipole filter field for input powers from 3.5 to 6.6 kW. The current density remained constant for operation with a 6 and an 8 mm aperture. The source has been operated for 260 h at 3.6 kW with a single-porcelain-coated antenna. Mass spectrometer measurements of the extracted beam at this power show a species mix for H{sup +}:H{sup +}{sub 2}:H{sup +}{sub 3}:OH{sup +} of 0.49: 0.04: 0.42: 0.04. The calculated beam divergence using the IGUN code is compared with the measured divergence from an electrostatic sweep emittance scanner designed for high-power cw beam diagnostics. Phase space measurements at 40 kV and 23 mA beam current result in a normalized rms emittance of 0.09 {pi}mmmrad. {copyright} {ital 1996 American Institute of Physics.}

  11. Effect of plasma grid bias on extracted currents in the RF driven surface-plasma negative ion source.

    PubMed

    Belchenko, Yu; Ivanov, A; Sanin, A; Sotnikov, O; Shikhovtsev, I

    2016-02-01

    Extraction of negative ions from the large inductively driven surface-plasma negative ion source was studied. The dependencies of the extracted currents vs plasma grid (PG) bias potential were measured for two modifications of radio-frequency driver with and without Faraday screen, for different hydrogen feeds and for different levels of cesium conditioning. The maximal PG current was independent of driver modification and it was lower in the case of inhibited cesium. The maximal extracted negative ion current depends on the potential difference between the near-PG plasma and the PG bias potentials, while the absolute value of plasma potential in the driver and in the PG area is less important for the negative ion production. The last conclusion confirms the main mechanism of negative ion production through the surface conversion of fast atoms. PMID:26932001

  12. Effect of plasma grid bias on extracted currents in the RF driven surface-plasma negative ion source

    NASA Astrophysics Data System (ADS)

    Belchenko, Yu.; Ivanov, A.; Sanin, A.; Sotnikov, O.; Shikhovtsev, I.

    2016-02-01

    Extraction of negative ions from the large inductively driven surface-plasma negative ion source was studied. The dependencies of the extracted currents vs plasma grid (PG) bias potential were measured for two modifications of radio-frequency driver with and without Faraday screen, for different hydrogen feeds and for different levels of cesium conditioning. The maximal PG current was independent of driver modification and it was lower in the case of inhibited cesium. The maximal extracted negative ion current depends on the potential difference between the near-PG plasma and the PG bias potentials, while the absolute value of plasma potential in the driver and in the PG area is less important for the negative ion production. The last conclusion confirms the main mechanism of negative ion production through the surface conversion of fast atoms.

  13. rf-driven ion sources for industrial applications (invited) (abstract)

    SciTech Connect

    Leung, Ka-Ngo

    2008-02-15

    The Plasma and Ion Source Technology Group at the Lawrence Berkeley National Laboratory have been developing rf-driven ion sources for the last two decades. These sources are being used to generate both positive and negative ion beams. Some of these sources are operating in particle accelerators such as the Spallation Neutron Source (SNS) at Oak Ridge, while others are being employed in various industrial ion beam systems. There are four areas where the rf-driven ion sources are commonly used in industry. (1) In semiconductor manufacturing, rf-driven sources have found important applications in plasma etching, ion beam implantation, and ion beam lithography. (2) In material analysis and surface modification, miniature rf-ion sources can be found in focused ion beam systems. They can provide ion beams of essentially any element in the Periodic Table. The newly developed combined rf ion-electron beam unit improves greatly the performance of the secondary ion mass spectrometry tool. (3) For neutron production, rf ion source is a major component of compact, high flux D-D, D-T, or T-T neutron generators. These neutron sources are now being employed in boron neutron capture therapy (BNCT) as well as in neutron imaging and material interrogation. (4) Large area rf-driven ion source will be used in an industrial design neutral beam diagnostic system for probing fusion plasmas. Such sources can be easily scaled to provide large ion beam current for future fusion reactor applications.

  14. Status of the RF-driven H- ion source for J-PARC linac

    NASA Astrophysics Data System (ADS)

    Oguri, H.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Asano, H.; Ueno, A.; Shibata, T.

    2016-02-01

    For the upgrade of the Japan Proton Accelerator Research Complex linac beam current, a cesiated RF-driven negative hydrogen ion source was installed during the 2014 summer shutdown period, with subsequent operations commencing on September 29, 2014. The ion source has been successfully operating with a beam current and duty factor of 33 mA and 1.25% (500 μs and 25 Hz), respectively. The result of recent beam operation has demonstrated that the ion source is capable of continuous operation for approximately 1100 h. The spark rate at the beam extractor was observed to be at a frequency of less than once a day, which is an acceptable level for user operation. Although an antenna failure occurred during operation on October 26, 2014, no subsequent serious issues have occurred since then.

  15. Status of the RF-driven H⁻ ion source for J-PARC linac.

    PubMed

    Oguri, H; Ohkoshi, K; Ikegami, K; Takagi, A; Asano, H; Ueno, A; Shibata, T

    2016-02-01

    For the upgrade of the Japan Proton Accelerator Research Complex linac beam current, a cesiated RF-driven negative hydrogen ion source was installed during the 2014 summer shutdown period, with subsequent operations commencing on September 29, 2014. The ion source has been successfully operating with a beam current and duty factor of 33 mA and 1.25% (500 μs and 25 Hz), respectively. The result of recent beam operation has demonstrated that the ion source is capable of continuous operation for approximately 1100 h. The spark rate at the beam extractor was observed to be at a frequency of less than once a day, which is an acceptable level for user operation. Although an antenna failure occurred during operation on October 26, 2014, no subsequent serious issues have occurred since then. PMID:26932020

  16. Mini RF-driven ion source for focused ion beam system

    SciTech Connect

    Jiang, X.; Ji, Q.; Chang, A.; Leung, K.N.

    2002-08-02

    Mini RF-driven ion sources with 1.2 cm and 1.5 cm inner chamber diameter have been developed at Lawrence Berkeley National Laboratory. Several gas species have been tested including argon, krypton and hydrogen. These mini ion sources operate in inductively coupled mode and are capable of generating high current density ion beams at tens of watts. Since the plasma potential is relatively low in the plasma chamber, these mini ion sources can function reliably without any perceptible sputtering damage. The mini RF-driven ion sources will be combined with electrostatic focusing columns, and are capable of producing nano focused ion beams for micro machining and semiconductor fabrications.

  17. RF Driven Multicusp H- Ion Source

    SciTech Connect

    Leung, K.N.; DeVries, G.J.; DiVergilio, W.F.; Hamm, R.W.; Hauck, C.A.; Kunkel, W.B.; McDonald, D.S.; Williams, M.D.

    1990-06-01

    An rf driven multicusp source capable of generating 1-ms H{sup -} beam pulses with a repetition rate as high as 150 Hz has been developed. This source can be operated with a filament or other types of starter. There is almost no lifetime limitation and a clean plasma can be maintained for a long period of operation. It is demonstrated that rf power as high as 25 kW could be coupled inductively to the plasma via a glass-coated copper-coil antenna. The extracted H{sup -} current density achieved is about 200 mA/cm{sup 2}.

  18. Negative hydrogen ion production mechanisms

    SciTech Connect

    Bacal, M.; Wada, M.

    2015-06-15

    Negative hydrogen/deuterium ions can be formed by processes occurring in the plasma volume and on surfaces facing the plasma. The principal mechanisms leading to the formation of these negative ions are dissociative electron attachment to ro-vibrationally excited hydrogen/deuterium molecules when the reaction takes place in the plasma volume, and the direct electron transfer from the low work function metal surface to the hydrogen/deuterium atoms when formation occurs on the surface. The existing theoretical models and reported experimental results on these two mechanisms are summarized. Performance of the negative hydrogen/deuterium ion sources that emerged from studies of these mechanisms is reviewed. Contemporary negative ion sources do not have negative ion production electrodes of original surface type sources but are operated with caesium with their structures nearly identical to volume production type sources. Reasons for enhanced negative ion current due to caesium addition to these sources are discussed.

  19. rf-driven ion sources for industrial applications (invited) (abstract)a)

    NASA Astrophysics Data System (ADS)

    Leung, Ka-Ngo

    2008-02-01

    The Plasma and Ion Source Technology Group at the Lawrence Berkeley National Laboratory have been developing rf-driven ion sources for the last two decades. These sources are being used to generate both positive and negative ion beams. Some of these sources are operating in particle accelerators such as the Spallation Neutron Source (SNS) at Oak Ridge, while others are being employed in various industrial ion beam systems. There are four areas where the rf-driven ion sources are commonly used in industry. (1) In semiconductor manufacturing, rf-driven sources have found important applications in plasma etching, ion beam implantation, and ion beam lithography. (2) In material analysis and surface modification, miniature rf-ion sources can be found in focused ion beam systems. They can provide ion beams of essentially any element in the Periodic Table. The newly developed combined rf ion-electron beam unit improves greatly the performance of the secondary ion mass spectrometry tool. (3) For neutron production, rf ion source is a major component of compact, high flux D-D, D-T, or T-T neutron generators. These neutron sources are now being employed in boron neutron capture therapy (BNCT) as well as in neutron imaging and material interrogation. (4) Large area rf-driven ion source will be used in an industrial design neutral beam diagnostic system for probing fusion plasmas. Such sources can be easily scaled to provide large ion beam current for future fusion reactor applications.

  20. Size scaling of negative hydrogen ion sources for fusion

    NASA Astrophysics Data System (ADS)

    Fantz, U.; Franzen, P.; Kraus, W.; Schiesko, L.; Wimmer, C.; Wünderlich, D.

    2015-04-01

    The RF-driven negative hydrogen ion source (H-, D-) for the international fusion experiment ITER has a width of 0.9 m and a height of 1.9 m and is based on a ⅛ scale prototype source being in operation at the IPP test facilities BATMAN and MANITU for many years. Among the challenges to meet the required parameters in a caesiated source at a source pressure of 0.3 Pa or less is the challenge in size scaling of a factor of eight. As an intermediate step a ½ scale ITER source went into operation at the IPP test facility ELISE with the first plasma in February 2013. The experience and results gained so far at ELISE allowed a size scaling study from the prototype source towards the ITER relevant size at ELISE, in which operational issues, physical aspects and the source performance is addressed, highlighting differences as well as similarities. The most ITER relevant results are: low pressure operation down to 0.2 Pa is possible without problems; the magnetic filter field created by a current in the plasma grid is sufficient to reduce the electron temperature below the target value of 1 eV and to reduce together with the bias applied between the differently shaped bias plate and the plasma grid the amount of co-extracted electrons. An asymmetry of the co-extracted electron currents in the two grid segments is measured, varying strongly with filter field and bias. Contrary to the prototype source, a dedicated plasma drift in vertical direction is not observed. As in the prototype source, the performance in deuterium is limited by the amount of co-extracted electrons in short as well as in long pulse operation. Caesium conditioning is much harder in deuterium than in hydrogen for which fast and reproducible conditioning is achieved. First estimates reveal a caesium consumption comparable to the one in the prototype source despite the large size.

  1. Long pulse H- beam extraction with a rf driven ion source on a high power level.

    PubMed

    Kraus, W; Fantz, U; Franzen, P

    2010-02-01

    IPP Garching is investigating the applicability of rf driven negative ion sources for the neutral beam injection of International Thermonuclear Experimental Reactor. The setup of the tested source was improved to enable long pulses up to 100 kW rf power. The efficiency of negative ion production decreases at high power. The extracted H(-) currents as well as the symmetry of the plasma density close to the plasma grid and of the beam divergence depend on the magnetic filter field. The pulse duration is limited by the increase in coextracted electrons, which depends on the rf power and the caesium conditions on the plasma grid. PMID:20192417

  2. Tunable negative Poisson's ratio in hydrogenated graphene.

    PubMed

    Jiang, Jin-Wu; Chang, Tienchong; Guo, Xingming

    2016-09-21

    We perform molecular dynamics simulations to investigate the effect of hydrogenation on the Poisson's ratio of graphene. It is found that the value of the Poisson's ratio of graphene can be effectively tuned from positive to negative by varying the percentage of hydrogenation. Specifically, the Poisson's ratio decreases with an increase in the percentage of hydrogenation, and reaches a minimum value of -0.04 when the percentage of hydrogenation is about 50%. The Poisson's ratio starts to increase upon a further increase of the percentage of hydrogenation. The appearance of a minimum negative Poisson's ratio in the hydrogenated graphene is attributed to the suppression of the hydrogenation-induced ripples during the stretching of graphene. Our results demonstrate that hydrogenation is a valuable approach for tuning the Poisson's ratio from positive to negative in graphene. PMID:27536878

  3. Size scaling of negative hydrogen ion sources for fusion

    SciTech Connect

    Fantz, U. Franzen, P.; Kraus, W.; Schiesko, L.; Wimmer, C.; Wünderlich, D.

    2015-04-08

    The RF-driven negative hydrogen ion source (H{sup −}, D{sup −}) for the international fusion experiment ITER has a width of 0.9 m and a height of 1.9 m and is based on a ⅛ scale prototype source being in operation at the IPP test facilities BATMAN and MANITU for many years. Among the challenges to meet the required parameters in a caesiated source at a source pressure of 0.3 Pa or less is the challenge in size scaling of a factor of eight. As an intermediate step a ½ scale ITER source went into operation at the IPP test facility ELISE with the first plasma in February 2013. The experience and results gained so far at ELISE allowed a size scaling study from the prototype source towards the ITER relevant size at ELISE, in which operational issues, physical aspects and the source performance is addressed, highlighting differences as well as similarities. The most ITER relevant results are: low pressure operation down to 0.2 Pa is possible without problems; the magnetic filter field created by a current in the plasma grid is sufficient to reduce the electron temperature below the target value of 1 eV and to reduce together with the bias applied between the differently shaped bias plate and the plasma grid the amount of co-extracted electrons. An asymmetry of the co-extracted electron currents in the two grid segments is measured, varying strongly with filter field and bias. Contrary to the prototype source, a dedicated plasma drift in vertical direction is not observed. As in the prototype source, the performance in deuterium is limited by the amount of co-extracted electrons in short as well as in long pulse operation. Caesium conditioning is much harder in deuterium than in hydrogen for which fast and reproducible conditioning is achieved. First estimates reveal a caesium consumption comparable to the one in the prototype source despite the large size.

  4. An advanced negative hydrogen ion source.

    PubMed

    Goncharov, Alexey A; Dobrovolsky, Andrey N; Goretskii, Victor P

    2016-02-01

    The results of investigation of emission productivity of negative particles source with cesiated combined discharge are presented. A cylindrical beam of negative hydrogen ions with density about 2 A/cm(2) in low noise mode on source emission aperture is obtained. The total beam current values are up to 200 mA for negative hydrogen ions and up to 1.5 A for all negative particles with high divergence after source. The source has simple design and can produce stable discharge with low level of oscillation. PMID:26931996

  5. Ground state of the hydrogen negative ion

    NASA Astrophysics Data System (ADS)

    Obreshkov, Boyan

    2009-03-01

    Based on recently developed variational many-body Schr"odinger equation for electrons with Coulomb interactions [1], we provide first numerical results for the ground state electron structure of the hydrogen negative ion. It is shown that Fermi-Teller promotion effect together with non-adiabatic screening effects due to the Pauli's exclusion principle are responsible for the weak binding of the anion. The calculated ionization potential J=-1/2 - 2 λ+ <1/r12> of the hydrogen negative ion is compared with the experiment, where λ is the mean binding energy per one electron in the ground state.[0pt] [1] B. D. Obreshkov , Phys. Rev. A 78, 032503 (2008).

  6. Above-threshold ionization of negative hydrogen

    NASA Astrophysics Data System (ADS)

    Nikolopoulos, L. A. A.; Lambropoulos, P.

    1997-10-01

    We present detailed calculations for two-and three-photon above-threshold ionization of the negative hydrogen ion. In addition to calculated values for partial wave amplitudes and phase shifts pertaining to recent experimental results [Xin Miao Zhao et al., Phys. Rev. Lett. 78, 1656 (1997)], we also address the question of the asymmetry of photoelectron angular distributions in ionization under elliptically polarized radiation, which has been studied experimentally in other negative ions [C. Blondel and C. Delsart, Laser Phys. 3, 3 (1993); Nucl. Instrum. Methods Phys. Res. B 79, 156 (1993); F. Dulieu, C. Blondel, and C. Delsart, J. Phys. B 28, 3861 (1995)].

  7. Negative hydrogen ion yields at plasma grid surface in a negative hydrogen ion source

    SciTech Connect

    Wada, M.; Kenmotsu, T.; Sasao, M.

    2015-04-08

    Negative hydrogen (H{sup −}) ion yield from the plasma grid due to incident hydrogen ions and neutrals has been evaluated with the surface collision cascade model, ACAT (Atomic Collision in Amorphous Target) coupled to a negative surface ionization models. Dependence of negative ion fractions upon the velocity component normal to the surface largely affect the calculation results of the final energy and angular distributions of the H{sup −} ions. The influence is particularly large for H{sup −} ions desorbed from the surface due to less than several eV hydrogen particle implact. The present calculation predicts that H{sup −} ion yield can be maximized by setting the incident angle of hydrogen ions and neutrals to be 65 degree. The Cs thickness on the plasma grid should also affect the yields and mean energies of surface produced H{sup −} ions by back scattering and ion induced desorption processes.

  8. Compression effects in inductively coupled, high-power radio-frequency discharges for negative hydrogen ion production

    NASA Astrophysics Data System (ADS)

    Wilhelm, Rolf

    2003-02-01

    In the paper we present a simplified model description of inductively coupled plasma discharges operating at a rather high radio-frequency (rf) power. In this case the induced high plasma currents can cause periodic compressions over a substantial radial distance. Such conditions are obviously given in rf driven 1 MHz/150 kW plasma sources developed at the Institute for Plasma Physics Garching for negative (hydrogen) ion production in future neutral beam injection (NBI) systems for nuclear fusion research, such as the 1 MeV/50 MW NBI system for the International Thermonuclear Experimental Reactor [T. Inoue, R. Hemsworth, V. Kulygin, and Y. Okumura, Fusion Eng. Design 55, 291 (2001)]. The given model describes quite well the compression and other features of the discharge. The results include the Ohmic power input (i.e., electron heating), the resulting density build-up, and—as a new feature—periodical plasma compressions, leading to a direct energy input also into the plasma ions. The model also explains the strange effect of small argon admixtures, which improve the negative ion yield in rf sources by a factor of up to 2-3 (but which have no effect in conventional dc arc sources). With the calculated dependencies from external parameters (e.g., rf-power and frequency, gas pressure, ion mass or the specific geometry), the modeling may help for the further optimization of the rf source.

  9. Negative ion extraction from hydrogen plasma bulk

    SciTech Connect

    Oudini, N.; Taccogna, F.; Minelli, P.

    2013-10-15

    A two-dimensional particle-in-cell/Monte Carlo collision model has been developed and used to study low electronegative magnetized hydrogen plasma. A configuration characterized by four electrodes is used: the left electrode is biased at V{sub l} = −100 V, the right electrode is grounded, while the upper and lower transversal electrodes are biased at an intermediate voltage V{sub ud} between 0 and −100 V. A constant and homogeneous magnetic field is applied parallel to the lateral (left/right) electrodes. It is shown that in the magnetized case, the bulk plasma potential is close to the transversal electrodes bias inducing then a reversed sheath in front of the right electrode. The potential drop within the reversed sheath is controlled by the transversal electrodes bias allowing extraction of negative ions with a significant reduction of co-extracted electron current. Furthermore, introducing plasma electrodes, between the transversal electrodes and the right electrode, biased with a voltage just above the plasma bulk potential, increases the negative ion extracted current and decreases significantly the co-extracted electron current. The physical mechanism on basis of this phenomenon has been discussed.

  10. Production of negative hydrogen ions on metal grids

    SciTech Connect

    Oohara, W.; Maetani, Y.; Takeda, Takashi; Takeda, Toshiaki; Yokoyama, H.; Kawata, K.

    2015-03-15

    Negative hydrogen ions are produced on a nickel grid with positive-ion irradiation. In order to investigate the production mechanism, a copper grid without the chemisorption of hydrogen atoms and positive helium ions without negative ionization are used for comparison. Positive hydrogen ions reflected on the metal surface obtain two electrons from the surface and become negatively ionized. It is found that the production yield of negative ions by desorption ionization of chemisorbed hydrogen atoms seems to be small, and the production is a minor mechanism.

  11. Particle balance in long duration RF driven plasmas on QUEST

    NASA Astrophysics Data System (ADS)

    Hanada, K.; Zushi, H.; Yoshida, N.; Yugami, N.; Honda, T.; Hasegawa, M.; Mishra, K.; Kuzmin, A.; Nakamura, K.; Fujisawa, A.; Idei, H.; Nagashima, Y.; Watanabe, O.; Onchi, T.; Watanabe, H.; Tokunaga, K.; Higashijima, A.; Kawasaki, S.; Nakashima, H.; Takase, Y.; Fukuyama, A.; Mitarai, O.; Peng, Y. K. M.

    2015-08-01

    Global particle balance in non-inductive long-duration plasma on QUEST has been investigated. Approximately 70% of the fuel hydrogen (H) was retained in the wall and then was almost exhausted just after the discharge. The global recycling ratio (Rg), defined as the ratio of the evacuated H2 flux to that injected, was found to gradually increase during discharges and subsequently rose rapidly. To study the growth of Rg, the thermal desorption spectra after deuterium implantation in a specimen exposed to QUEST plasma was analyzed with a model which includes reflection, diffusion, solution, recombination, trapping, and plasma-induced desorption in the re-deposition layer. The model reconstructs the growth of Rg during a long-duration plasma and indicates solution plays a dominant role in the growth.

  12. Hydrogen Plasmas for Negative Ion Production

    SciTech Connect

    Pagano, D.; Gorse, C.; Capitelli, M.

    2005-05-16

    We have improved a zero-dimensional model, built to simulate the operating conditions in the excitation ('driver') region of a multicusp ion source optimized for negative ion production of great interest in thermonuclear applications. The new approach to couple heavy particle and electron kinetics is discussed.

  13. Study on space charge compensation in negative hydrogen ion beam

    NASA Astrophysics Data System (ADS)

    Zhang, A. L.; Peng, S. X.; Ren, H. T.; Zhang, T.; Zhang, J. F.; Xu, Y.; Guo, Z. Y.; Chen, J. E.

    2016-02-01

    Negative hydrogen ion beam can be compensated by the trapping of ions into the beam potential. When the beam propagates through a neutral gas, these ions arise due to gas ionization by the beam ions. However, the high neutral gas pressure may cause serious negative hydrogen ion beam loss, while low neutral gas pressure may lead to ion-ion instability and decompensation. To better understand the space charge compensation processes within a negative hydrogen beam, experimental study and numerical simulation were carried out at Peking University (PKU). The simulation code for negative hydrogen ion beam is improved from a 2D particle-in-cell-Monte Carlo collision code which has been successfully applied to H+ beam compensated with Ar gas. Impacts among ions, electrons, and neutral gases in negative hydrogen beam compensation processes are carefully treated. The results of the beam simulations were compared with current and emittance measurements of an H- beam from a 2.45 GHz microwave driven H- ion source in PKU. Compensation gas was injected directly into the beam transport region to modify the space charge compensation degree. The experimental results were in good agreement with the simulation results.

  14. Study on space charge compensation in negative hydrogen ion beam.

    PubMed

    Zhang, A L; Peng, S X; Ren, H T; Zhang, T; Zhang, J F; Xu, Y; Guo, Z Y; Chen, J E

    2016-02-01

    Negative hydrogen ion beam can be compensated by the trapping of ions into the beam potential. When the beam propagates through a neutral gas, these ions arise due to gas ionization by the beam ions. However, the high neutral gas pressure may cause serious negative hydrogen ion beam loss, while low neutral gas pressure may lead to ion-ion instability and decompensation. To better understand the space charge compensation processes within a negative hydrogen beam, experimental study and numerical simulation were carried out at Peking University (PKU). The simulation code for negative hydrogen ion beam is improved from a 2D particle-in-cell-Monte Carlo collision code which has been successfully applied to H(+) beam compensated with Ar gas. Impacts among ions, electrons, and neutral gases in negative hydrogen beam compensation processes are carefully treated. The results of the beam simulations were compared with current and emittance measurements of an H(-) beam from a 2.45 GHz microwave driven H(-) ion source in PKU. Compensation gas was injected directly into the beam transport region to modify the space charge compensation degree. The experimental results were in good agreement with the simulation results. PMID:26932087

  15. Linac4 low energy beam measurements with negative hydrogen ions

    SciTech Connect

    Scrivens, R. Bellodi, G.; Crettiez, O.; Dimov, V.; Gerard, D.; Granemann Souza, E.; Guida, R.; Hansen, J.; Lallement, J.-B.; Lettry, J.; Lombardi, A.; Midttun, Ø.; Pasquino, C.; Raich, U.; Riffaud, B.; Roncarolo, F.; Valerio-Lizarraga, C. A.; Wallner, J.; Yarmohammadi Satri, M.; Zickler, T.

    2014-02-15

    Linac4, a 160 MeV normal-conducting H{sup −} linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ (Radiofrequency Quadrupole) has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H{sup −} beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  16. The mobility of negative charges in liquid hydrogen

    NASA Astrophysics Data System (ADS)

    Lerner, P. B.; Sokolov, I. M.

    1994-06-01

    There is a great difference in behavior of e- in liquid hydrogen and helium despite the fact that the adopted theories of the mobility are quite similar. Recently, Levchenko and Mezhov-Deglin (Journal of Low Temperature Physics, 89, 457 (1992)) reported large discrepancies of the mobility of the electrons in liquid hydrogen from estimates based on the theory that the electrons are trapped in bubbles forming atomlike structures (“bubblonium”). They properly suggested that these deviations are related to the existence in liquid hydrogen of another, metastable type of negative charge carrier. The subject of the current paper is the physical explanation of the existence of two types of carriers in liquid hydrogen. We attribute the second type of carriers to the cluster ion H - ( H 2 ) x , which is created by the formation of solid hydrogen around a bound state of a hydride ion. We provide estimates for the radius and the kinetics of degradation of the “snowball” formed around the H - ion on the basis of energy diagrams for a hydride ion submerged in liquid hydrogen.

  17. Production of intense negative hydrogen beams with polarized nuclei by selective neutralization of cold negative ions

    DOEpatents

    Hershcovitch, A.

    1984-02-13

    A process for selectively neutralizing H/sup -/ ions in a magnetic field to produce an intense negative hydrogen ion beam with spin polarized protons. Characteristic features of the process include providing a multi-ampere beam of H/sup -/ ions that are

  18. Fine-tuning to minimize emittances of J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Asano, H.; Oguri, H.

    2016-02-01

    The Japan Proton Accelerator Research Complex (J-PARC) cesiated RF-driven H- ion source has been successfully operated for about one year. By the world's brightest level beam, the J-PARC design beam power of 1 MW was successfully demonstrated. In order to minimize the transverse emittances, the rod-filter-field (RFF) was optimized by changing the triple-gap-lengths of each of pairing five piece rod-filter-magnets. The larger emittance degradation seems to be caused by impurity-gases than the RFF. The smaller beam-hole-diameter of the extraction electrode caused the more than expected improvements on not only the emittances but also the peak beam intensity.

  19. Fine-tuning to minimize emittances of J-PARC RF-driven H⁻ ion source.

    PubMed

    Ueno, A; Ohkoshi, K; Ikegami, K; Takagi, A; Asano, H; Oguri, H

    2016-02-01

    The Japan Proton Accelerator Research Complex (J-PARC) cesiated RF-driven H(-) ion source has been successfully operated for about one year. By the world's brightest level beam, the J-PARC design beam power of 1 MW was successfully demonstrated. In order to minimize the transverse emittances, the rod-filter-field (RFF) was optimized by changing the triple-gap-lengths of each of pairing five piece rod-filter-magnets. The larger emittance degradation seems to be caused by impurity-gases than the RFF. The smaller beam-hole-diameter of the extraction electrode caused the more than expected improvements on not only the emittances but also the peak beam intensity. PMID:26932012

  20. Deactivating bacteria with RF Driven Hollow Slot Microplasmas in Open Air at Atmospheric Pressure

    NASA Astrophysics Data System (ADS)

    Yu, Zengqi; Pruden, Amy; Sharma, Ashish; Collins, George

    2003-10-01

    A hollow slot discharge operating in open air at atmospheric pressure has demonstrated its ability to deactivate bacterial growth on nearby surfaces exposed to the RF driven plasma. The cold plasma exits from a hollow slot with a width of 0.2 mm and variable length of 1-35 cm. An internal electrode was powered by 13.56 MHz radio-frequency power at a voltage below 200 V. External electrically grounded slots face the work piece. The plasma plume extends millimeters to centimeter beyond the hollow slot toward the work piece to be irradiated. Argon-Oxygen gas mixtures, at 33 liters per minute flow, were passed through the electrodes and the downstream plasma was employed for the process, with treatment exposure time varied from 0.06 to 0.18 seconds. Bacterial cultures were fixed to 0.22 micron cellulose filter membranes and passed under the plasma at a controlled rate at a distance of about 5-10 millimeters from the grounded slot electrode. Preliminary studies on the effectiveness of the plasma for sterilization were carried out on E. coli. Cultures were grown overnight on the membranes after exposure and the resulting colony forming units (cfu) were determined in treated and untreated groups. In the plasma treated group, a 98.2% kill rate was observed with the lowest exposure time, and increased to 99.8% when the exposure time was tripled. These studies clearly demonstrate the ability of the RF-driven hollow slot atmospheric plasma to inhibit bacterial growth on surfaces.

  1. Rod-filter-field optimization of the J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-01

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second-stage requirements of an H- ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H- ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). Although rod-filter-field (RFF) is indispensable and one of the most beam performance dominative parameters for the RF-driven H- ion source with the internal-antenna, the procedure to optimize it is not established. In order to optimize the RFF and establish the procedure, the beam performances of the J-PARC source with various types of rod-filter-magnets (RFMs) were measured. By changing RFM's gap length and gap number inside of the region projecting the antenna inner-diameter along the beam axis, the dependence of the H- ion beam intensity on the net 2MHz-RF power was optimized. Furthermore, the fine-tuning of RFM's cross-section (magnetmotive force) was indispensable for easy operation with the temperature (TPE) of the plasma electrode (PE) lower than 70°C, which minimizes the transverse emittances. The 5% reduction of RFM's cross-section decreased the time-constant to recover the cesium effects after an slightly excessive cesiation on the PE from several 10 minutes to several minutes for TPE around 60°C.

  2. Negative hydrogen ion source for TOKAMAK neutral beam injector (invited)

    NASA Astrophysics Data System (ADS)

    Okumura, Y.; Fujiwara, Y.; Kashiwagi, M.; Kitagawa, T.; Miyamoto, K.; Morishita, T.; Hanada, M.; Takayanagi, T.; Taniguchi, M.; Watanabe, K.

    2000-02-01

    Intense negative ion source producing multimegawatt hydrogen/deuterium negative ion beams has been developed for the neutral beam injector (NBI) in TOKAMAK thermonuclear fusion machines. Negative ions are produced in a cesium seeded multi-cusp plasma generator via volume and surface processes, and accelerated with a multistage electrostatic accelerator. The negative ion source for JT-60U has produced 18.5 A/360 keV (6.7 MW) H- and 14.3 A/380 keV (5.4 MW) D- ion beams at average current densities of 11 mA/cm2 (H-) and 8.5 mA/cm2 (D-). A high energy negative ion source has been developed for the next generation TOKAMAK such as the International Thermonuclear Experimental Reactor (ITER). The source has demonstrated to accelerate negative ions up to 1 MeV, the energy required for ITER. Higher negative ion current density of more than 20 mA/cm2 was obtained in the ITER concept sources. It was confirmed that the consumption rate of cesium is small enough to operate the source for a half year in ITER-NBI without maintenance.

  3. Negative hydrogen ion production in a helicon plasma source

    SciTech Connect

    Santoso, J. Corr, C. S.; Manoharan, R.; O'Byrne, S.

    2015-09-15

    In order to develop very high energy (>1 MeV) neutral beam injection systems for applications, such as plasma heating in fusion devices, it is necessary first to develop high throughput negative ion sources. For the ITER reference source, this will be realised using caesiated inductively coupled plasma devices, containing either hydrogen or deuterium discharges, operated with high rf input powers (up to 90 kW per driver). It has been suggested that due to their high power coupling efficiency, helicon devices may be able to reduce power requirements and potentially obviate the need for caesiation due to the high plasma densities achievable. Here, we present measurements of negative ion densities in a hydrogen discharge produced by a helicon device, with externally applied DC magnetic fields ranging from 0 to 8.5 mT at 5 and 10 mTorr fill pressures. These measurements were taken in the magnetised plasma interaction experiment at the Australian National University and were performed using the probe-based laser photodetachment technique, modified for the use in the afterglow of the plasma discharge. A peak in the electron density is observed at ∼3 mT and is correlated with changes in the rf power transfer efficiency. With increasing magnetic field, an increase in the negative ion fraction from 0.04 to 0.10 and negative ion densities from 8 × 10{sup 14 }m{sup −3} to 7 × 10{sup 15 }m{sup −3} is observed. It is also shown that the negative ion densities can be increased by a factor of 8 with the application of an external DC magnetic field.

  4. Hydrogen atom temperature measured with wavelength-modulated laser absorption spectroscopy in large scale filament arc negative hydrogen ion source

    SciTech Connect

    Nakano, H. Goto, M.; Tsumori, K.; Kisaki, M.; Ikeda, K.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.; Nishiyama, S.; Sasaki, K.

    2015-04-08

    The velocity distribution function of hydrogen atoms is one of the useful parameters to understand particle dynamics from negative hydrogen production to extraction in a negative hydrogen ion source. Hydrogen atom temperature is one of the indicators of the velocity distribution function. To find a feasibility of hydrogen atom temperature measurement in large scale filament arc negative hydrogen ion source for fusion, a model calculation of wavelength-modulated laser absorption spectroscopy of the hydrogen Balmer alpha line was performed. By utilizing a wide range tunable diode laser, we successfully obtained the hydrogen atom temperature of ∼3000 K in the vicinity of the plasma grid electrode. The hydrogen atom temperature increases as well as the arc power, and becomes constant after decreasing with the filling of hydrogen gas pressure.

  5. A future, intense source of negative hydrogen ions

    NASA Technical Reports Server (NTRS)

    Siefken, Hugh; Stein, Charles

    1994-01-01

    By directly heating lithium hydride in a vacuum, up to 18 micro-A/sq cm of negative hydrogen has been obtained from the crystal lattice. The amount of ion current extracted and analyzed is closely related to the temperature of the sample and to the rate at which the temperature is changed. The ion current appears to be emission limited and saturates with extraction voltage. For a fixed extraction voltage, the ion current could be maximized by placing a grid between the sample surface and the extraction electrode. Electrons accompanying the negative ions were removed by a magnetic trap. A Wein velocity filter was designed and built to provide definitive mass analysis of the extracted ion species. This technique when applied to other alkali hydrides may produce even higher intensity beams possessing low values of emittance.

  6. Emittance measurements for optimum operation of the J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-01

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second stage requirements of an H- ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H- ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). The transverse emittances of the source were measured with various conditions to find out the optimum operation conditions minimizing the horizontal and vertical rms normalized emittances. The transverse emittances were most effectively reduced by operating the source with the plasma electrode temperature lower than 70°C. The optimum value of the cesium (Cs) density around the beam hole of the plasma electrode seems to be proportional to the plasma electrode temperature. The fine control of the Cs density is indispensable, since the emittances seem to increase proportionally to the excessiveness of the Cs density. Furthermore, the source should be operated with the Cs density beyond a threshold value, since the plasma meniscus shape and the ellipse parameters of the transverse emittances seem to be changed step-function-likely on the threshold Cs value.

  7. A new hybrid scheme for simulations of highly collisional RF-driven plasmas

    NASA Astrophysics Data System (ADS)

    Eremin, Denis; Hemke, Torben; Mussenbrock, Thomas

    2016-02-01

    This work describes a new 1D hybrid approach for modeling atmospheric pressure discharges featuring complex chemistry. In this approach electrons are described fully kinetically using particle-in-cell/Monte-Carlo (PIC/MCC) scheme, whereas the heavy species are modeled within a fluid description. Validity of the popular drift-diffusion approximation is verified against a ‘full’ fluid model accounting for the ion inertia and a fully kinetic PIC/MCC code for ions as well as electrons. The fluid models require knowledge of the momentum exchange frequency and dependence of the ion mobilities on the electric field when the ions are in equilibrium with the latter. To this end an auxiliary Monte-Carlo scheme is constructed. It is demonstrated that the drift-diffusion approximation can overestimate ion transport in simulations of RF-driven discharges with heavy ion species operated in the γ mode at the atmospheric pressure or in all discharge simulations for lower pressures. This can lead to exaggerated plasma densities and incorrect profiles provided by the drift-diffusion models. Therefore, the hybrid code version featuring the full ion fluid model should be favored against the more popular drift-diffusion model, noting that the suggested numerical scheme for the former model implies only a small additional computational cost.

  8. Development of a novel radio-frequency negative hydrogen ion source in conically converging configuration.

    PubMed

    Jung, B K; Dang, J J; An, Y H; Chung, K J; Hwang, Y S

    2014-02-01

    Volume-produced negative ion source still requires enhancement of current density with lower input RF (radio-frequency) power in lower operating pressure for various applications. To confirm recent observation of efficient negative ion production with a short cylindrical chamber with smaller effective plasma size, the RF-driven transformer-coupled plasma H(-) ion source at Seoul National University is modified by adopting a newly designed quartz RF window to reduce the chamber length. Experiments with the reduced chamber length show a few times enhancement of H(-) ion beam current compared to that extracted from the previous chamber design, which is consistent with the measured H(-) ion population. Nevertheless, decrease in H(-) ion beam current observed in low pressure regime below ∼5 mTorr owing to insufficient filtering of high energy electrons in the extraction region needs to be resolved to address the usefulness of electron temperature control by the change of geometrical configuration of the discharge chamber. A new discharge chamber with conically converging configuration has been developed, in which the chamber diameter decreases as approaching to the extraction region away from the planar RF antenna such that stronger filter magnetic field can be utilized to prohibit high energy electrons from transporting to the extraction region. First experimental results for the H(-) ion beam extraction with this configuration show that higher magnetic filter field makes peak negative beam currents happen in lower operating pressure. However, overall decrease in H(-) ion beam current due to the change of chamber geometry still requires further study of geometrical effect on particle transport and optimization of magnetic field in this novel configuration. PMID:24593552

  9. Experimental studies of the Negative Ion of Hydrogen. Final Report

    SciTech Connect

    Bryant, Howard C.

    1999-06-30

    This document presents an overview of the results of the DOE'S support of experimental research into the structure and interactions of the negative ion of hydrogen conducted by the Department of Physics and Astronomy of the University of New Mexico at the Los Alamos National Laboratory. The work involves many collaborations with scientists from both institutions, as well as others. Although official DOE support for this work began in 1977, the experiment that led to it was done in 1971, near the time the 800 MeV linear accelerator at Los Alamos (LAMPF) first came on line. Until the mid nineties, the work was performed using the relativistic beam at LAMFF. The most recent results were obtained using the 35 keV injector beam for the Ground Test Accelerator at Los Alamos. A list of all published results from this work is presented.

  10. Cavity Ring-Down System for Density Measurement of Negative Hydrogen Ion on Negative Ion Source

    SciTech Connect

    Nakano, Haruhisa; Tsumori, Katsuyoshi; Nagaoka, Kenichi; Shibuya, Masayuki; Kisaki, Masashi; Ikeda, Katsunori; Osakabe, Masaki; Kaneko, Osamu; Asano, Eiji; Kondo, Tomoki; Sato, Mamoru; Komada, Seiji; Sekiguchi, Haruo; Takeiri, Yasuhiko; Fantz, Ursel

    2011-09-26

    A Cavity Ring-Down (CRD) system was applied to measure the density of negative hydrogen ion (H{sup -}) in vicinity of extraction surface in the H{sup -} source for the development of neutral beam injector on Large Helical Device (LHD). The density measurement with sampling time of 50 ms was carried out. The measured density with the CRD system is relatively good agreement with the density evaluated from extracted beam-current with applying a similar relation of positive ion sources. In cesium seeded into ion-source plasma, the linearity between an arc power of the discharge and the measured density with the CRD system was observed. Additionally, the measured density was proportional to the extracted beam current. These characteristics indicate the CRD system worked well for H{sup -} density measurement in the region of H{sup -} and extraction.

  11. Perfectly matched pulsed 2MHz RF network and CW 30MHz RF matching network for the J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Namekawa, Y.; Yamazaki, S.; Ohkoshi, K.; Koizumi, I.; Ikegami, K.; Takagi, A.; Oguri, H.

    2013-02-01

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) 2nd stage requirements of an H- ion beam current of 60mA within normalized emittances of 1.5πmmṡmrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of more than 50days, a cesiated RF-driven H- ion source using a internal-antenna developed at the Spallation Neutron Source (SNS) was developed. As similar as the SNS ion source, the 60kW pulsed 2MHz-RF and 200W CW 30MHz-RF systems are used in order to produce pulsed high-temperature 2MHz-RF plasma and CW low-temperature 30MHz-RF plasma. Each matching network for each system is composed of two vacuum variable condensers (VVCs). In order to supply pulsed 60kW-2MHz-RF power from the power supply (PS) on the ground level, a one-turn isolation transformer using FINEMET cores is installed between the PS and the J-PARC ion source. By comprehending the matching networks with the LTspice IV simulations and high- and low- power experiments and setting the parameters properly, the pulsed 2MHz-RF power up to 46 kW is successfully input to the hydrogen plasma without any misfire and with almost no reflected power.

  12. Production of intense negative hydrogen beams with polarized nuclei by selective neutralization of negative ions

    DOEpatents

    Hershcovitch, Ady

    1987-01-01

    A process for selectively neutralizing H.sup.- ions in a magnetic field to produce an intense negative hydrogen ion beam with spin polarized protons. Characteristic features of the process include providing a multi-ampere beam of H.sup.- ions that are intersected by a beam of laser light. Photodetachment is effected in a uniform magnetic field that is provided around the beam of H.sup.- ions to spin polarize the H.sup.- ions and produce first and second populations or groups of ions, having their respective proton spin aligned either with the magnetic field or opposite to it. The intersecting beam of laser light is directed to selectively neutralize a majority of the ions in only one population, or given spin polarized group of H.sup.- ions, without neutralizing the ions in the other group thereby forming a population of H.sup.- ions each of which has its proton spin down, and a second group or population of H.sup.o atoms having proton spin up. Finally, the two groups of ions are separated from each other by magnetically bending the group of H.sup.- ions away from the group of neutralized ions, thereby to form an intense H.sup.- ion beam that is directed toward a predetermined objective.

  13. Vibrational States of Hydrogen Molecules in One Third LHD Negative Ion Source

    SciTech Connect

    Nishiura, M.; Tsumori, K.; Matsumoto, Y.; Wada, M.; Inoue, T.

    2011-09-26

    The effect of the cesium on hydrogen negative ions is discussed using the vacuum ultraviolet emissions (VUV) from vibrational states of hydrogen molecules. The VUV spectrum from 90 to 165 nm is related to the H{sup -} production from the dissociative attachment of electrons to hydrogen molecules. The VUV spectra in hydrogen plasmas are measured in the extraction region of a negative ion source for neutral beam injector. Under the pure hydrogen discharge, the cesium vapor is introduced into the ion source to enhance the hydrogen negative ion density. When the same arc power of {approx}99 kW is applied in both with and without cesium admixture cases, the ratio of the observed VUV spectrum without to with cesium is not changed clearly. Therefore the production process of H{sup -} related to the wall/electrode surface would be enhanced rather than the volume production process.

  14. Production of intense beams of polarized negative hydrogen ions by double charge exchange in alkali vapour

    NASA Astrophysics Data System (ADS)

    Gruëbler, W.; Schmelzbach, P. A.

    1983-07-01

    The intensity of the polarized negative hydrogen ion beam of the ETHZ atomic beam polarized ion source has been substantially improved by a new double charge exchange device. Increasing the diameter of the charge exchange canal to 1.4 cm results in a beam output of the source of 6 μA of polarized negative hydrogen ions. Further improvements of the charge exchanger are proposed and discussed. With an updated design of the atomic beam apparatus, beams of 0.5 mA polarized negative hydrogen ions may be obtained from such a source.

  15. An RF driven H{sup {minus}} source and a low energy beam injection system for RFQ operation

    SciTech Connect

    Leung, K.N.; Bachman, D.A.; Chan, C.F.; McDonald, D.S.

    1992-12-31

    An RF driven H{sup {minus}} source has been developed at LBL for use in the Superconducting Super Collider (SSC). To date, an H{sup {minus}} current of {approx}40 mA can be obtained from a 5.6-cm-diam aperture with the source operated at a pressure of about 12 m Torr and 50 kW of RF power. In order to match the accelerated H{sup {minus}} beam into the SSC RFQ, a low-energy H{sup {minus}} injection system has been designed. This injector produces an outgoing H{sup {minus}} beam free of electron contamination, with small radius, large convergent angle and small projectional emittance.

  16. Pre-conditioning procedure suitable for internal-RF-antenna of J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Asano, H.; Oguri, H.

    2016-02-01

    The Japan Proton Accelerator Research Complex (J-PARC) cesiated RF-driven H- ion source has been successfully operated for about 1 yr. By the world brightest level beam, the J-PARC design beam power of 1 MW was successfully demonstrated. Although no internal-RF-antenna failure, except for the once caused by an excess cesium due to a misoperation, occurred in the operation, many antennas failed in pre-conditionings for the first hundred days. The antenna failure rate was drastically decreased by using an antenna with coating thicker than a standard value and the pre-conditioning procedure repeating 15 min 25 kW RF-power operation and impurity-gas evacuation a few times, before the full power (50 kW) operation.

  17. Pre-conditioning procedure suitable for internal-RF-antenna of J-PARC RF-driven H⁻ ion source.

    PubMed

    Ueno, A; Ohkoshi, K; Ikegami, K; Takagi, A; Asano, H; Oguri, H

    2016-02-01

    The Japan Proton Accelerator Research Complex (J-PARC) cesiated RF-driven H(-) ion source has been successfully operated for about 1 yr. By the world brightest level beam, the J-PARC design beam power of 1 MW was successfully demonstrated. Although no internal-RF-antenna failure, except for the once caused by an excess cesium due to a misoperation, occurred in the operation, many antennas failed in pre-conditionings for the first hundred days. The antenna failure rate was drastically decreased by using an antenna with coating thicker than a standard value and the pre-conditioning procedure repeating 15 min 25 kW RF-power operation and impurity-gas evacuation a few times, before the full power (50 kW) operation. PMID:26932011

  18. Rod-filter-field optimization of the J-PARC RF-driven H{sup −} ion source

    SciTech Connect

    Ueno, A. Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-08

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second-stage requirements of an H{sup −} ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H{sup −} ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). Although rod-filter-field (RFF) is indispensable and one of the most beam performance dominative parameters for the RF-driven H{sup −} ion source with the internal-antenna, the procedure to optimize it is not established. In order to optimize the RFF and establish the procedure, the beam performances of the J-PARC source with various types of rod-filter-magnets (RFMs) were measured. By changing RFM’s gap length and gap number inside of the region projecting the antenna inner-diameter along the beam axis, the dependence of the H{sup −} ion beam intensity on the net 2MHz-RF power was optimized. Furthermore, the fine-tuning of RFM’s cross-section (magnetmotive force) was indispensable for easy operation with the temperature (T{sub PE}) of the plasma electrode (PE) lower than 70°C, which minimizes the transverse emittances. The 5% reduction of RFM’s cross-section decreased the time-constant to recover the cesium effects after an slightly excessive cesiation on the PE from several 10 minutes to several minutes for T{sub PE} around 60°C.

  19. RF-driven Proton Source with a Back-streaming Electron Dump

    SciTech Connect

    Ji, Q.; Sy, A.; Kwan, J.W.

    2009-09-20

    This article describes an RF ion source with a back-streaming electron dump. A quartz tube, brazed to a metal plug at one end, is fused in the center of a flat quartz plate. RF power (at 13.6 MHz) is coupled to generate hydrogen plasma using a planar external antenna bonded to the window. Bonding the water-cooled rf antenna to the quartz window significantly lowers its temperature. The water-cooled metal plug serves as the backstreaming electron dump. At 1800W, the current density of extracted hydrogen ions reaches approximately 125 mA/cm{sup 2}.

  20. Cavity Ringdown Technique for negative-hydrogen-ion measurement in ion source for neutral beam injector

    NASA Astrophysics Data System (ADS)

    Nakano, H.; Tsumori, K.; Shibuya, M.; Geng, S.; Kisaki, M.; Ikeda, K.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.

    2016-03-01

    The Cavity Ringdown Technique (CRD) is applied for negative hydrogen ion (H-) density measurement in H- source for the neutral beam injector. The CRD is one of the laser absorption techniques. Nd:YAG pulse laser was utilized for negative-hydrogen-ion photodetachment. The H- density related to extracted H- beam was successfully observed by a fixed position CRD. A two-dimensional movable CRD has been developed to measure the H- density profile. Measured profiles were consistent with expected profiles from the H- production area in pure hydrogen and cesium seeded plasmas. By applying absorption saturation in the optical cavity, negative hydrogen ion temperature was evaluated and was confirmed as being a similar value measured with other diagnostics.

  1. Laser photodetachment diagnostics of a 1/3-size negative hydrogen ion source for NBI

    SciTech Connect

    Geng, S.; Tsumori, K.; Nakano, H.; Kisaki, M.; Ikeda, K.; Takeiri, Y.; Osakabe, M.; Nagaoka, K.; Kaneko, O.

    2015-04-08

    To investigate the flows of charged particles in front of the plasma grid (PG) in a negative hydrogen ion source, the information of the local densities of electrons and negative hydrogen ions (H-) are necessary. For this purpose, the laser photodetachment is applied for pure hydrogen plasmas and Cs-seeded plasma in a 1/3-size negative hydrogen ion source in NIFS-NBI test stand. The H- density obtained by photodetachment is calibrated by the results from cavity ring-down (CRD). The pressure dependence and PG bias dependence of the local H- density are presented and discussed. The results show that H- density increases significantly by seeding Cs into the plasma. In Cs-seeded plasma, relativity exists between the H- ion density and plasma potential.

  2. Effects of discharge chamber length on the negative ion generation in volume-produced negative hydrogen ion source

    SciTech Connect

    Chung, Kyoung-Jae; Jung, Bong-Ki; An, YoungHwa; Dang, Jeong-Jeung; Hwang, Y. S.

    2014-02-15

    In a volume-produced negative hydrogen ion source, control of electron temperature is essential due to its close correlation with the generation of highly vibrationally excited hydrogen molecules in the heating region as well as the generation of negative hydrogen ions by dissociative attachment in the extraction region. In this study, geometric effects of the cylindrical discharge chamber on negative ion generation via electron temperature changes are investigated in two discharge chambers with different lengths of 7.5 cm and 11 cm. Measurements with a radio-frequency-compensated Langmuir probe show that the electron temperature in the heating region is significantly increased by reducing the length of the discharge chamber due to the reduced effective plasma size. A particle balance model which is modified to consider the effects of discharge chamber configuration on the plasma parameters explains the variation of the electron temperature with the chamber geometry and gas pressure quite well. Accordingly, H{sup −} ion density measurement with laser photo-detachment in the short chamber shows a few times increase compared to the longer one at the same heating power depending on gas pressure. However, the increase drops significantly as operating gas pressure decreases, indicating increased electron temperatures in the extraction region degrade dissociative attachment significantly especially in the low pressure regime. It is concluded that the increase of electron temperature by adjusting the discharge chamber geometry is efficient to increase H{sup −} ion production as long as low electron temperatures are maintained in the extraction region in volume-produced negative hydrogen ion sources.

  3. Effects of discharge chamber length on the negative ion generation in volume-produced negative hydrogen ion source.

    PubMed

    Chung, Kyoung-Jae; Jung, Bong-Ki; An, YoungHwa; Dang, Jeong-Jeung; Hwang, Y S

    2014-02-01

    In a volume-produced negative hydrogen ion source, control of electron temperature is essential due to its close correlation with the generation of highly vibrationally excited hydrogen molecules in the heating region as well as the generation of negative hydrogen ions by dissociative attachment in the extraction region. In this study, geometric effects of the cylindrical discharge chamber on negative ion generation via electron temperature changes are investigated in two discharge chambers with different lengths of 7.5 cm and 11 cm. Measurements with a radio-frequency-compensated Langmuir probe show that the electron temperature in the heating region is significantly increased by reducing the length of the discharge chamber due to the reduced effective plasma size. A particle balance model which is modified to consider the effects of discharge chamber configuration on the plasma parameters explains the variation of the electron temperature with the chamber geometry and gas pressure quite well. Accordingly, H(-) ion density measurement with laser photo-detachment in the short chamber shows a few times increase compared to the longer one at the same heating power depending on gas pressure. However, the increase drops significantly as operating gas pressure decreases, indicating increased electron temperatures in the extraction region degrade dissociative attachment significantly especially in the low pressure regime. It is concluded that the increase of electron temperature by adjusting the discharge chamber geometry is efficient to increase H(-) ion production as long as low electron temperatures are maintained in the extraction region in volume-produced negative hydrogen ion sources. PMID:24593559

  4. Development of a volume production type hydrogen negative ion source by using sheet plasma

    NASA Astrophysics Data System (ADS)

    Matsumoto, Satoki; Iijima, Takaaki; Tonegawa, Akira; Sato, Kohnosuke; Kawamura, Kazutaka

    2014-10-01

    Stationary production of negative ions are important to play an essential role in Neutral beam injection (NBI). Cesium seeded Surface-production of negative ion sources are used for NBI. However, Cesium seeded surface- production of negative ion sources are not desirable from the point of view of operating steady state ion sources. We carried out the development of negative ion sources by volume-production in hydrogen sheet plasma. Production of hydrogen negative ions through volume processes needs both high energy electron region and low energy electron region. The sheet plasma is suitable for the production of negative ions, because the electron temperature in the central region of the plasma as high as 10-15 eV, whereas in the periphery of the plasma, a low temperature of a few eV of obtained. The hydrogen negative ions density were detected using an omegatron mass analyzer, while the electron density and temperature were measured using a Langmuir probe. Negative ions current extracted from the grid are measured by Faraday-cup.

  5. Development of cesium-free negative hydrogen ion source by using sheet plasma

    NASA Astrophysics Data System (ADS)

    Hase, Takuya; Iijima, Takaaki; Tanaka, Yuta; Takimoto, Tosikio; Tonegawa, Akira; Sato, Kohnosuke; Kawamura, Kazutaka

    2015-09-01

    We demonstrated the production of hydrogen negative ions in cesium-free discharge by using the magnetized sheet plasma. Plasma crossed with a vertical gas flow system and extracting H- beams from the sheet plasma. Under a secondary hydrogen gas entering the hydrogen plasma, the peak position of the hydrogen plasma is localized in the periphery of the sheet plasma. The maximum negative ion beam is successfully extracted using grids located in the periphery of the sheet plasma. The extraction current density is about 8 mA/cm2 at extraction voltage is 2 kV and discharge current of 30 A. The extraction negative ion current density is saturated at the extraction voltage is 2 kV for the limit of the negative ion density in the periphery region of the sheet plasma. On the other hand, the extraction current is saturated (3 mA/cm2) with increasing extraction voltage and the negative ions are not detected without the secondary gas flow (0 sccm). This curve depends on the electrons present. Therefore, it is considered that the negative ion current against the extraction current is around 60% from the ratio of the extraction current and the extraction electron current.

  6. Emittance measurements for optimum operation of the J-PARC RF-driven H{sup −} ion source

    SciTech Connect

    Ueno, A. Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-08

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second stage requirements of an H{sup −} ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H{sup −} ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). The transverse emittances of the source were measured with various conditions to find out the optimum operation conditions minimizing the horizontal and vertical rms normalized emittances. The transverse emittances were most effectively reduced by operating the source with the plasma electrode temperature lower than 70°C. The optimum value of the cesium (Cs) density around the beam hole of the plasma electrode seems to be proportional to the plasma electrode temperature. The fine control of the Cs density is indispensable, since the emittances seem to increase proportionally to the excessiveness of the Cs density. Furthermore, the source should be operated with the Cs density beyond a threshold value, since the plasma meniscus shape and the ellipse parameters of the transverse emittances seem to be changed step-function-likely on the threshold Cs value.

  7. Optimum plasma grid bias for a negative hydrogen ion source operation with Cs

    NASA Astrophysics Data System (ADS)

    Bacal, Marthe; Sasao, Mamiko; Wada, Motoi; McAdams, Roy

    2016-02-01

    The functions of a biased plasma grid of a negative hydrogen (H-) ion source for both pure volume and Cs seeded operations are reexamined. Proper control of the plasma grid bias in pure volume sources yields: enhancement of the extracted negative ion current, reduction of the co-extracted electron current, flattening of the spatial distribution of plasma potential across the filter magnetic field, change in recycling from hydrogen atomic/molecular ions to atomic/molecular neutrals, and enhanced concentration of H- ions near the plasma grid. These functions are maintained in the sources seeded with Cs with additional direct emission of negative ions under positive ion and neutral hydrogen bombardment onto the plasma electrode.

  8. Design and Start-to-End Simulation of an X-Band RF Driven Hard X-Ray FEL with LCLS Injector

    SciTech Connect

    Sun, Yipeng; /SLAC

    2012-08-20

    In this note, it is briefly discussed the accelerator design and start-to-end 3D macro particles simulation (using ELEGANT and GENESIS) of an X-band RF driven hard X-ray FEL with LCLS injector. A preliminary design and LiTrack 1D simulation studies were presented before in an older publication [1]. In numerical simulations this X-band RF driven hard X-ray FEL achieves/exceeds LCLS-like performance in a much shorter overall length of 350 m, compared with 1200 m in the LCLS case. One key feature of this design is that it may achieve a higher final beam current of 5 kA plus a uniform energy profile, mainly due to the employment of stronger longitudinal wake fields in the last X-band RF linac [2].

  9. Effect of nickel grid parameters on production of negative hydrogen ions

    SciTech Connect

    Oohara, W.; Yokoyama, H.; Takeda, Toshiaki; Maetani, Y.; Takeda, Takashi; Kawata, K.

    2014-06-15

    Negative hydrogen ions are produced by plasma-assisted catalytic ionization using a nickel grid. When positive ions passing through the grid are decelerated by an electric field, the extraction current density of passing positive ions is sharply reduced by neutralization and negative ionization of the ions. This phenomenon is found to depend on the specific surface area of the grid and the current density.

  10. Measurement of Gas Temperature in Negative Hydrogen Ion Source by Wavelength-Modulated Laser Absorption Spectroscopy

    NASA Astrophysics Data System (ADS)

    Nishiyama, S.; Sasaki, K.; Nakano, H.; Goto, M.; Kisaki, M.; Tsumori, K.; NIFS-NBI Team

    2014-10-01

    Measurement of the energy distribution of hydrogen atom is important and essential to understand the production mechanism of its negative ion (H-) in cesium-seeded negative ion sources. In this work, we evaluated the temperature of atomic hydrogen in the large-scale arc-discharge negative hydrogen ion source in NIFS by wavelength-modulated laser absorption spectroscopy. The laser beam was passed through the adjacent region to the grid electrode for extracting negative ions. The frequency of the laser was scanned slowly over the whole range of the Doppler width (100 GHz in 1s). A sinusoidal frequency modulation at 600 Hz with a width of 30 GHz was superposed onto the slow modulation. The transmitted laser was detected using a photodiode, and its second harmonic component of the sinusoidal modulation was amplified using a lock-in amplifier. The obtained spectrum was in good agreement with an expected spectrum of the Doppler-broadened Balmer- α line. The estimated temperature of atomic hydrogen was approximately 3000 K. The absorption increased with the arc-discharge power, while the temperature was roughly independent of the power. This work is supported by the NIFS Collaboration Research Program NIFS13KLER021.

  11. Maintenance and operation procedure, and feedback controls of the J-PARC RF-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-01

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second stage requirements of an H- ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H- ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). The maintenance and operation procedure to minimize the plasma chamber (PCH) replacement time on the beam line, which is very important to maximize the J-PARC beam time especially for an antenna failure, is presented in this paper. The PCH preserved by filling argon (Ar) gas inside after pre-conditioning including pre-cesiation to produce the required beam at a test-stand successfully produced the required beam on the beam line with slight addition of cesium (Cs). The methods of the feedback controls of a 2MHz-RF-matching, an H- ion beam intensity and the addition of Cs are also presented. The RF-matching feedback by using two vacuum variable capacitors (VVCs) and RF-frequency shift produced the almost perfect matching with negligibly small reflected RF-power. The H- ion beam intensity was controlled within errors of ±0.1mA by the RF-power feedback. The amount of Cs was also controlled by remotely opening a Cs-valve to keep the RF-power lower than a settled value.

  12. Roles of a plasma grid in a negative hydrogen ion source

    NASA Astrophysics Data System (ADS)

    Bacal, M.; Sasao, M.; Wada, M.; McAdams, R.

    2015-04-01

    The plasma grid is electrically biased with respect to other parts of source chamber wall in both volume sources and sources seeded with alkali metals. The roles of the plasma grid in these two kinds of sources will be described. The main functions of the plasma grid in volume sources are: optimizing the extracted negative ion current, reducing the co-extracted electron current, controlling the axial plasma potential profile, recycling the hydrogen atoms to molecules, concentrating the negative ions near its surface and, when biased positive, depleting the electron population near its surface. These functions are maintained in the sources seeded with alkali metals. However an additional function appears in the Cs seeded sources, namely direct emission of negative ions under positive ion and neutral hydrogen bombardment.

  13. Roles of a plasma grid in a negative hydrogen ion source

    SciTech Connect

    Bacal, M.; Sasao, M.; Wada, M.; McAdams, R.

    2015-04-08

    The plasma grid is electrically biased with respect to other parts of source chamber wall in both volume sources and sources seeded with alkali metals. The roles of the plasma grid in these two kinds of sources will be described. The main functions of the plasma grid in volume sources are: optimizing the extracted negative ion current, reducing the co-extracted electron current, controlling the axial plasma potential profile, recycling the hydrogen atoms to molecules, concentrating the negative ions near its surface and, when biased positive, depleting the electron population near its surface. These functions are maintained in the sources seeded with alkali metals. However an additional function appears in the Cs seeded sources, namely direct emission of negative ions under positive ion and neutral hydrogen bombardment.

  14. Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

    NASA Astrophysics Data System (ADS)

    Rauner, D.; Kurutz, U.; Fantz, U.

    2015-04-01

    As the negative hydrogen ion density nH- is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H- is measured directly, however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H- is produced in the plasma volume, laser photodetachment is applied as the standard method to measure nH-. The additional application of CRDS provides the possibility to directly obtain absolute values of nH-, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H- production and destruction processes. The modelled densities are adapted to the absolute measurements of nH- via CRDS, allowing to identify collisions of H- with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H- in the plasma volume at HOMER. Furthermore, the characteristic peak of nH- observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as ne determines the volume production rate via dissociative electron attachment to vibrationally excited hydrogen molecules.

  15. Experimental Evaluation of a Negative Ion Source for a Heavy Ion Fusion Negative Ion Driver

    SciTech Connect

    Grisham, L. R.; Hahto, S. K.; Hahto, S. T.; Kwan, J. W.; Leung, K. N.

    2004-06-16

    Negative halogen ions have recently been proposed as a possible alternative to positive ions for heavy ion fusion drivers because electron accumulation would not be a problem in the accelerator, and if desired, the beams could be photo-detached to neutrals. To test the ability to make suitable quality beams, an experiment was conducted at Lawrence Berkeley National Laboratory using chlorine in an RF-driven ion source. Without introducing any cesium (which is required to enhance negative ion production in hydrogen ion sources) a negative chlorine current density of 45 mA/cm{sup 2} was obtained under the same conditions that gave 57 45 mA/cm{sup 2} of positive chlorine, suggesting the presence of nearly as many negative ions as positive ions in the plasma near the extraction plane. The negative ion spectrum was 99.5% atomic chlorine ions, with only 0.5% molecular chlorine, and essentially no impurities. Although this experiment did not incorporate the type of electron suppression technology that i s used in negative hydrogen beam extraction, the ratio of co-extracted electrons to Cl{sup -} was as low as 7 to 1, many times lower than the ratio of their mobilities, suggesting that few electrons are present in the near-extractor plasma. This, along with the near-equivalence of the positive and negative ion currents, suggests that the plasma in this region was mostly an ion-ion plasma. The negative chlorine current density was relatively insensitive to pressure, and scaled linearly with RF power. If this linear scaling continues to hold at higher RF powers, it should permit current densities of 100 45 mA/cm{sup 2}, sufficient for present heavy ion fusion injector concepts. The effective ion temperatures of the positive and negative ions appeared to be similar and relatively low for a plasma source.

  16. Experimental evaluation of a negative ion source for a heavy ionfusion negative ion driver

    SciTech Connect

    Grisham, L.R.; Hahto, S.K.; Hahto, S.T.; Kwan, J.W.; Leung, K.N.

    2005-01-18

    Negative halogen ions have recently been proposed as a possible alternative to positive ions for heavy ion fusion drivers because electron accumulation would not be a problem in the accelerator, and if desired, the beams could be photodetached to neutrals [1,2,3]. To test the ability to make suitable quality beams, an experiment was conducted at Lawrence Berkeley National Laboratory using chlorine in an RF-driven ion source. Without introducing any cesium (which is required to enhance negative ion production in hydrogen ion sources) a negative chlorine current density of 45 mA/cm{sup 2} was obtained under the same conditions that gave 57 mA/cm{sup 2} of positive chlorine, suggesting the presence of nearly as many negative ions as positive ions in the plasma near the extraction plane. The negative ion spectrum was 99.5% atomic chlorine ions, with only 0.5% molecular chlorine, and essentially no impurities. Although this experiment did not incorporate the type of electron suppression technology that is used in negative hydrogen beam extraction, the ratio of co-extracted electrons to Cl{sup -} was as low as 7 to 1, many times lower than the ratio of their mobilities, suggesting that few electrons are present in the near-extractor plasma. This, along with the near-equivalence of the positive and negative ion currents, suggests that the plasma in this region was mostly an ion-ion plasma. The negative chlorine current density was relatively insensitive to pressure, and scaled linearly with RF power. If this linear scaling continues to hold at higher RF powers, it should permit current densities of 100 mA/cm{sup 2}, sufficient for present heavy ion fusion injector concepts. The effective ion temperatures of the positive and negative ions appeared to be similar and relatively low for a plasma source.

  17. Ways to improve the efficiency and reliability of radio frequency driven negative ion sources for fusion

    SciTech Connect

    Kraus, W.; Briefi, S.; Fantz, U.; Gutmann, P.; Doerfler, J.

    2014-02-15

    Large RF driven negative hydrogen ion sources are being developed at IPP Garching for the future neutral beam injection system of ITER. The overall power efficiency of these sources is low, because for the RF power supply self-excited generators are utilized and the plasma is generated in small cylindrical sources (“drivers”) and expands into the source main volume. At IPP experiments to reduce the primary power and the RF power required for the plasma production are performed in two ways: The oscillator generator of the prototype source has been replaced by a transistorized RF transmitter and two alternative driver concepts, a spiral coil, in which the field is concentrated by ferrites, which omits the losses by plasma expansion and a helicon source are being tested.

  18. Magnetic ordering temperature of nanocrystalline Gd: enhancement of magnetic interactions via hydrogenation-induced "negative" pressure.

    PubMed

    Tereshina, E A; Khmelevskyi, S; Politova, G; Kaminskaya, T; Drulis, H; Tereshina, I S

    2016-01-01

    Gadolinium is a nearly ideal soft-magnetic material. However, one cannot take advantage of its properties at temperatures higher than the room temperature where Gd loses the ferromagnetic ordering. By using high-purity bulk samples with grains ~200 nm in size, we present proof-of-concept measurements of an increased Curie point (TC) and spontaneous magnetization in Gd due to hydrogenation. From first-principles we explain increase of TC in pure Gd due to the addition of hydrogen. We show that the interplay of the characteristic features in the electronic structure of the conduction band at the Fermi level in the high-temperature paramagnetic phase of Gd and "negative" pressure exerted by hydrogen are responsible for the observed effect. PMID:26931775

  19. Hydrogen evolution at the negative electrode of the all-vanadium redox flow batteries

    NASA Astrophysics Data System (ADS)

    Sun, Che-Nan; Delnick, Frank M.; Baggetto, Loïc; Veith, Gabriel M.; Zawodzinski, Thomas A.

    2014-02-01

    This work demonstrates a quantitative method to determine the hydrogen evolution rate occurring at the negative carbon electrode of the all vanadium redox flow battery (VRFB). Two carbon papers examined by buoyancy measurements yield distinct hydrogen formation rates (0.170 and 0.005 μmol min-1 g-1). The carbon papers have been characterized using electron microscopy, nitrogen gas adsorption, capacitance measurement by electrochemical impedance spectroscopy (EIS), and X-ray photoelectron spectroscopy (XPS). We find that the specific electrochemical surface area (ECSA) of the carbon material has a strong influence on the hydrogen generation rate. This is discussed in light of the use of high surface area material to obtain high reaction rates in the VRFB.

  20. The First Observation of Intra Beam Stripping of Negative Hydrogen in a Superconducting Linear Accelerator

    SciTech Connect

    Aleksandrov, Alexander V; Plum, Michael A; Shishlo, Andrei P; Galambos, John D

    2012-01-01

    We report on an experiment in which a negative hydrogen ions beam in the Spallation Neutron Source (SNS) linear accelerator was replaced with a beam of protons with similar size and dynamics. Beam loss in the superconducting part of the SNS accelerator was at least an order of magnitude lower for the proton beam. Also beam loss has a stronger dependence on intensity with H- than with proton beams. These measurements verify a recent theoretical explanation of unexpected beam losses in the SNS superconducting linear accelerator based on an intra beam stripping mechanism for negative hydrogen ions. An identification of the new physics mechanism for beam loss is important for the design of new high current linear ion accelerators and the performance improvement of existing machines

  1. First Observation of Intrabeam Stripping of Negative Hydrogen in a Superconducting Linear Accelerator

    NASA Astrophysics Data System (ADS)

    Shishlo, A.; Galambos, J.; Aleksandrov, A.; Lebedev, V.; Plum, M.

    2012-03-01

    We report on an experiment in which a negative hydrogen ion beam in the Spallation Neutron Source (SNS) linear accelerator was replaced with a beam of protons with similar size and dynamics. Fractional beam loss in the superconducting part of the SNS accelerator was measured to be at least 2×10-5 for the H- beam, and it was an order of magnitude lower for the protons. Also beam loss has a stronger dependence on intensity with H- than with proton beams. These measurements verify a recent theoretical explanation of unexpected beam losses in the SNS superconducting linear accelerator based on an intrabeam stripping mechanism for negative hydrogen ions. This previously unidentified mechanism for beam loss is important for the design of new high current linear ion accelerators and the performance improvement of existing machines.

  2. Cesium dynamics in long pulse operation of negative hydrogen ion sources for fusiona)

    NASA Astrophysics Data System (ADS)

    Fantz, U.; Wimmer, C.

    2012-02-01

    Large scale negative hydrogen ion sources operating stable for 1 h (cw mode) are required for the neutral beam heating system of the fusion experiment ITER. The formation of negative hydrogen ions relies on the surface effect for which cesium is evaporated into the source. In order to monitor the cesium dynamics the laser absorption spectroscopy technique is applied to the long pulse test facility MANITU. In the vacuum phase, without plasma operation the evaporation of cesium and the built-up of the cesium in the source are measured. Typical neutral cesium densities are 1015 m-3. During plasma operation and after the plasma phase a high cesium dynamics is observed, showing also depletion of cesium during long pulses with low cesium amount. The co-extracted electron current decreases with the cesium amount to a certain level whereas the ion current indicates an optimum density range.

  3. Cesium dynamics in long pulse operation of negative hydrogen ion sources for fusion

    SciTech Connect

    Fantz, U.; Wimmer, C.

    2012-02-15

    Large scale negative hydrogen ion sources operating stable for 1 h (cw mode) are required for the neutral beam heating system of the fusion experiment ITER. The formation of negative hydrogen ions relies on the surface effect for which cesium is evaporated into the source. In order to monitor the cesium dynamics the laser absorption spectroscopy technique is applied to the long pulse test facility MANITU. In the vacuum phase, without plasma operation the evaporation of cesium and the built-up of the cesium in the source are measured. Typical neutral cesium densities are 10{sup 15} m{sup -3}. During plasma operation and after the plasma phase a high cesium dynamics is observed, showing also depletion of cesium during long pulses with low cesium amount. The co-extracted electron current decreases with the cesium amount to a certain level whereas the ion current indicates an optimum density range.

  4. Development of spectrally selective imaging system for negative hydrogen ion source

    SciTech Connect

    Ikeda, K. Nakano, H.; Tsumori, K.; Kisaki, M.; Nagaoka, K.; Osakabe, M.; Takeiri, Y.; Kaneko, O.

    2014-02-15

    A spectrally selective imaging system has been developed to obtain a distribution of H{sub α} emissions at the extraction region in a hydrogen negative ion source. The diagnostic system consisted of an aspherical lens, optical filters, a fiber image conduit, and a charge coupled device detector was installed on the 1/3-scaled hydrogen negative ion source in the National Institute for Fusion Science. The center of sight line passes beside the plasma grid (PG) surface with the distance of 11 mm, and the viewing angle has coverage 35 mm from the PG surface. Two dimensional H{sub α} distribution in the range up to 20 mm from the PG surface was clearly observed. The reduction area for H{sub α} emission caused by beam extraction was widely distributed in the extraction region near the PG surface.

  5. Research progress on ionic plasmas generated in an intense hydrogen negative ion source

    SciTech Connect

    Takeiri, Y. Tsumori, K.; Nagaoka, K.; Kaneko, O.; Ikeda, K.; Nakano, H.; Kisaki, M.; Tokuzawa, T.; Osakabe, M.; Kondo, T.; Sato, M.; Shibuya, M.; Komada, S.; Sekiguchi, H.; Geng, S.

    2015-04-08

    Characteristics of ionic plasmas, observed in a high-density hydrogen negative ion source, are investigated with a multi-diagnostics system. The ionic plasma, which consists of hydrogen positive- and negative-ions with a significantly low-density of electrons, is generated in the ion extraction region, from which the negative ions are extracted through the plasma grid. The negative ion density, i.e., the ionic plasma density, as high as the order of 1×10{sup 17}m{sup −3}, is measured with cavity ring-down spectroscopy, while the electron density is lower than 1×10{sup 16}m{sup −3}, which is confirmed with millimeter-wave interferometer. Reduction of the negative ion density is observed at the negative ion extraction, and at that time the electron flow into the ionic plasma region is observed to conserve the charge neutrality. Distribution of the plasma potential is measured in the extraction region in the direction normal to the plasma grid surface with a Langmuir probe, and the results suggest that the sheath is formed at the plasma boundary to the plasma grid to which the bias voltage is applied. The beam extraction should drive the negative ion transport in the ionic plasma across the sheath formed on the extraction surface. Larger reduction of the negative ions at the beam extraction is observed in a region above the extraction aperture on the plasma grid, which is confirmed with 2D image measurement of the Hα emission and cavity ring-down spectroscopy. The electron distribution is also measured near the plasma grid surface. These various properties observed in the ionic plasma are discussed.

  6. Negative hydrogen ion beam extraction from an AC heated cathode driven Bernas-type ion source

    NASA Astrophysics Data System (ADS)

    Okano, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

    2015-04-01

    A plasma grid structure was installed to a Bernas-type ion source used for ion implantation equipment. A negative hydrogen (H-) ion beam was extracted by an AC driven ion source by adjusting the bias to the plasma grid. The extracted electron current was reduced by positively biasing the plasma grid, while an optimum plasma grid bias voltage for negative ion beam extraction was found to be positive 3 V with respect to the arc chamber. Source operations with AC cathode heating show extraction characteristics almost identical to that with DC cathode heating, except a minute increase in H- current at higher frequency of cathode heating current.

  7. A collisional radiative model of hydrogen plasmas developed for diagnostic purposes of negative ion sources

    NASA Astrophysics Data System (ADS)

    Iordanova, Snejana; Paunska, Tsvetelina

    2016-02-01

    A collisional radiative model of low-pressure hydrogen plasmas is elaborated and applied in optical emission spectroscopy diagnostics of a single element of a matrix source of negative hydrogen ions. The model accounts for the main processes determining both the population densities of the first ten states of the hydrogen atom and the densities of the positive hydrogen ions H+, H2+, and H3+. In the calculations, the electron density and electron temperature are varied whereas the atomic and molecular temperatures are included as experimentally obtained external parameters. The ratio of the Hα to Hβ line intensities is calculated from the numerical results for the excited state population densities, obtained as a solution of the set of the steady-state rate balance equations. The comparison of measured and theoretically obtained ratios of line intensities yields the values of the electron density and temperature as well as of the degree of dissociation, i.e., of the parameters which have a crucial role for the volume production of the negative ions.

  8. Doubly excited states of the hydrogen negative ion and helium atom in astrophysical plasmas

    SciTech Connect

    Jiang Pinghui; Kar, Sabyasachi; Zhou, Y.

    2013-01-15

    The nonthermal effects on the doubly excited resonance states of the hydrogen negative ion and helium atom are investigated in Lorentzian astrophysical plasma environments using highly correlated Hylleraas-type wave functions in the framework of the stabilization method. Resonance parameters (resonance position and width) are reported for the first time as functions of the spectral index and plasma parameter. The screening effects are more pronounced in the stronger screening region.

  9. First experiments with Cs doped Mo as surface converter for negative hydrogen ion sources

    SciTech Connect

    Schiesko, L. Hopf, C.; Höschen, T.; Meisl, G.; Encke, O.; Heinemann, B.; Fantz, U.; Cartry, G.; Amsalem, P.; Achkasov, K.

    2015-08-21

    A study was conducted on the properties of molybdenum implanted with caesium as an approach to reduce the Cs consumption of negative hydrogen ion sources based on evaporated Cs. The depth profiles of the implanted Cs were simulated by SDTrimSP and experimentally determined by X-ray photoelectron spectroscopy depth profiling. In particular, one year after implantation, the depth profiles showed no signs of Cs diffusion into the molybdenum, suggesting long term stability of the implanted Cs atoms. The H{sup −} surface generation mechanisms on the implanted samples in hydrogen plasma were investigated, and the stability of the H{sup −} yield during four hours low power hydrogen plasma discharges was demonstrated. An estimation of the work function reduction (−0.8 eV) by the Cs implantation was performed, and a comparison of the relative negative ion yields between the implanted samples and highly oriented pyrolitic graphite showed that the Cs doped Mo negative ion yield was larger.

  10. Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

    SciTech Connect

    Rauner, D.; Kurutz, U.; Fantz, U.

    2015-04-08

    As the negative hydrogen ion density n{sub H{sup −}} is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H{sup −} is measured directly, however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H{sup −} is produced in the plasma volume, laser photodetachment is applied as the standard method to measure n{sub H{sup −}}. The additional application of CRDS provides the possibility to directly obtain absolute values of n{sub H{sup −}}, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H{sup −} production and destruction processes. The modelled densities are adapted to the absolute measurements of n{sub H{sup −}} via CRDS, allowing to identify collisions of H{sup −} with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H{sup −} in the plasma volume at HOMER. Furthermore, the characteristic peak of n{sub H{sup −}} observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as n{sub e} determines

  11. Formation of silicon hydride using hyperthermal negative hydrogen ions (H -) extracted from an argon-seeded hydrogen sheet plasma source

    NASA Astrophysics Data System (ADS)

    Fernandez, Marcedon S.; Blantocas, Gene Q.; Ramos, Henry J.

    2008-12-01

    An E × B probe (a modified Wien filter) is constructed to function both as a mass spectrometer and ion implanter. The device, given the acronym EXBII selects negative hydrogen ions (H -) from a premixed 10% argon-seeded hydrogen sheet plasma. With a vacuum background of 1.0 × 10 -6 Torr, H - extraction ensues at a total gas feed of 1.8 mTorr, 0.5 A plasma discharge. The EXBII is positioned 3 cm distance from the sheet core as this is the region densely populated by cold electrons ( Te ˜ 2 eV, Ne ˜ 3.4 × 10 11 cm -3) best suited for H - formation. The extracted H - ions of flux density ˜0.26 A/m 2 are segregated, accelerated to hyperthermal range (<100 eV) and subsequently deposited into a palladium-coated 1.1 × 1.1 cm 2, n-type Si (1 0 0) substrate held at the rear end of the EXBII, placed in lieu of its Faraday cup. The palladium membrane plays the role of a catalyst initiating the reaction between Si atoms and H - ions simultaneously capping the sample from oxidation and other undesirable adsorbents. AFM and FTIR characterization tests confirm the formation of SiH 2. Absorbance peaks between 900-970 cm -1 (bending modes) and 2050-2260 cm -1 (stretching modes) are observed in the FTIR spectra of the processed samples. It is found that varying hydrogen exposure time results in the shifting of wavenumbers which may be interpreted as changes in the frequencies of vibration for SiH 2. These are manifestations of chemical changes accompanying alterations in the force constant of the molecule. The sample with longer exposure time exhibits an additional peak at 2036 cm -1 which are hydrides of nano-crystalline silicon.

  12. Triple Guest Occupancy and Negative Compressibility in Hydrogen-Loaded β-Hydroquinone Clathrate.

    PubMed

    Rozsa, Viktor F; Strobel, Timothy A

    2014-06-01

    The molecular interactions and structural behavior of a previously unexplored clathrate system, hydrogen-loaded β-hydroquinone (β-HQ+H2), were investigated under high pressure with synchrotron X-ray diffraction and Raman/infrared spectroscopies. The β-HQ+H2 system exhibits coupling of two independently rare phenomena: multiple occupancy and negative compressibility. The number of H2 molecules per cavity increases from one to three, causing unit cell volume increase by way of unique crystallographic interstitial guest positioning. We anticipate these occupancy-derived trends may be general to a range of inclusion compounds and may aid the chemical and crystallographic design of both high-occupancy hydrogen storage clathrates and novel, variable-composition materials with tunable mechanical properties. PMID:26273868

  13. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions

    SciTech Connect

    Valerio-Lizarraga, Cristhian A.; Lallement, Jean-Baptiste; Lettry, Jacques; Scrivens, Richard; Leon-Monzon, Ildefonso; Midttun, Øystein

    2014-02-15

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H{sup −} beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  14. Extraction of negative hydrogen ions from a compact 14 GHz microwave ion source

    SciTech Connect

    Wada, M.; Kasuya, T.; Nishida, T.; Kenmotsu, T.; Maeno, S.; Nishiura, M.; Shinto, K.; Yamaoka, H.

    2012-02-15

    A pair of permanent magnets has formed enough intensity to realize electron cyclotron resonance condition for a 14 GHz microwave in a 2 cm diameter 9 cm long alumina discharge chamber. A three-electrode extraction system assembled in a magnetic shielding has formed a stable beam of negative hydrogen ions (H{sup -}) in a direction perpendicular to the magnetic field. The measured H{sup -} current density was about 1 mA/cm{sup 2} with only 50 W of discharge power, but the beam intensity had shown saturation against further increase in microwave power. The beam current decreased monotonically against increasing pressure.

  15. Negative hydrogen ion beam extraction from an AC heated cathode driven Bernas-type ion source

    SciTech Connect

    Okano, Y.; Miyamoto, N.; Kasuya, T.; Wada, M.

    2015-04-08

    A plasma grid structure was installed to a Bernas-type ion source used for ion implantation equipment. A negative hydrogen (H{sup −}) ion beam was extracted by an AC driven ion source by adjusting the bias to the plasma grid. The extracted electron current was reduced by positively biasing the plasma grid, while an optimum plasma grid bias voltage for negative ion beam extraction was found to be positive 3 V with respect to the arc chamber. Source operations with AC cathode heating show extraction characteristics almost identical to that with DC cathode heating, except a minute increase in H{sup −} current at higher frequency of cathode heating current.

  16. Plasma transfer process in hydrogen negative ions source based on reflective discharge

    SciTech Connect

    Goretsky, V.P.; Ryabtsev, A.V.; Soloshenko, I.A.; Tarasenko, A.F.; Schedrin, A.I.

    1996-07-01

    The results of theoretical and experimental studies of stationary volume source of hydrogen negative ions based on reflective discharge are presented in the report. Measurements of plasma parameters and emission characteristics are accomplished, and the optimization of ion source geometry is provided. The best parameters of ion beam extracted from the source across a magnetic field are the following: current 40 mA, current density 80 mA/cm{sup 2}, emittance along a magnetic field 3{center_dot}10{sup {minus}5} cm{center_dot}rad, emittance across a magnetic field 1{center_dot}10{sup {minus}5} cm{center_dot}rad. The calculation of beam basic properties is performed by numeric solving of Boltzman equation for electrons, balance equations for more than 300 elementary processes in gas discharge plasma, and equations of ions and electrons motion. Calculated dependencies of hydrogen negative ions current density in a plane of emission slit on the gas pressure and the discharge current are found to be in a good agreement with the experimental data. {copyright} {ital 1996 American Institute of Physics.}

  17. Behavior of Negative Hydrogen Ion and its Beam by Bias and Beam Extraction Voltages

    NASA Astrophysics Data System (ADS)

    Nakano, Haruhisa; Tsumori, Katsuyoshi; Kisaki, Masashi; Ikeda, Katsunori; Geng, Shaofei; Nagaoka, Kenichi; Osakabe, Masaki; Takeiri, Yasuhiko; Kaneko, Osamu; Serianni, Gianluigi; Agostinetti, Piero; Sartori, Emanuele; Brombin, Matteo; Wimmer, Christian

    2015-09-01

    Negative hydrogen ion (H-) dynamics from production to beam extraction in H- source for fusion have not been enough understood in cesium-seeded negative-hydrogen-ion sources. This dynamics understanding contributes constructions of higher performance ion sources. The H- is produced on and emitted from plasma grid electrode (PG) which is boundary electrode between source plasma and beam. The H- density in the vicinity of the PG decreased with bias voltage (between PG and arc chamber) by suppression of H- emission and/or yield. The H- density decrement was observed in H- beam extraction phase and penetrated to 30 mm depth from PG. The depth and H- beam current decreased with bias voltage. One of the possibilities which explain it is extracted H- coming from space in the vicinity of the PG. An object made of ceramic was inserted above the PG aperture. The H- beam intensity decreased if the object was set 9 mm from PG. This does not conflict with the possibility. This work is supported by NIFS Research Programs NIFS13ULRR008 and NIFS13ULRR702, and JSPS KAKENHI Grant Numbers 25800307 and 25249134.

  18. Multiplying probe for accurate power measurements on an RF driven atmospheric pressure plasma jet applied to the COST reference microplasma jet

    NASA Astrophysics Data System (ADS)

    Beijer, P. A. C.; Sobota, A.; van Veldhuizen, E. M.; Kroesen, G. M. W.

    2016-03-01

    In this paper a new multiplying probe for measuring the power dissipated in a miniature capacitively coupled, RF driven, atmospheric pressure plasma jet (μAPPJ—COST Reference Microplasma Jet—COST RMJ) is presented. The approach aims for substantially higher accuracy than provided by traditionally applied methods using bi-directional power meters or commercially available voltage and current probes in conjunction with digitizing oscilloscopes. The probe is placed on a miniature PCB and designed to minimize losses, influence of unknown elements, crosstalk and variations in temperature. The probe is designed to measure powers of the order of magnitude of 0.1-10 W. It is estimated that it measures power with less than 2% deviation from the real value in the tested power range. The design was applied to measure power dissipated in COST-RMJ running in helium with a small addition of oxygen.

  19. A Negative Hydrogen-Ion Source for SNS Using a Helicon Plasma Generator

    SciTech Connect

    Goulding, R. H.; Welton, R. F.; Baity, F. W.; Crisp, D. W.; Fadnek, A.; Kang, Y.; Murray, S. N.; Sparks, D. O.; Stockli, M. P.

    2007-09-28

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory is a world-class facility for materials research based on neutron scattering. It consists of a negative hydrogen (H-) ion source, linear accelerator, proton accumulator ring, and liquid Hg target. A power upgrade is planned for the device, which will require significant improvements in the negative ion source, including the production of H-beam currents of 70-95 mA ({approx}2xthe present SNS source value), with a pulse length of 1 ms and duty factor of {approx}7%. No H-sources currently in existence meet these combined requirements. A proof-of-principle experiment is being constructed in which the rf inductive plasma generator in the present source is replaced by a helicon plasma generator. This is expected to produce a factor of three or better increase in the maximum source plasma density at a reduced rf power level, resulting in significantly increased negative ion current with reduced heat removal requirements.

  20. A Negative Hydrogen-Ion Source for SNS Using a Helicon Plasma Generator

    SciTech Connect

    Goulding, Richard Howell; Welton, Robert F; Baity Jr, F Wallace; Crisp, Danny W; Fadnek, Andy; Kang, Yoon W; Murray Jr, S N; Sparks, Dennis O; Stockli, Martin P

    2007-01-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Labo ratory is a world-class facility for materials research based on neutron scattering. It consists of a negative hydrogen (H-) ion source, linear accelerator, proton accumulator ring, and liquid Hg target. A power up grade is planned for the device, which will require significant improvements in the negative ion source, including the production of H- beam currents of 70-95 mA (~2 the present SNS source value), with a pulse length of 1 ms and duty factor of ~ 7%. No H- sources currently in existence meet these combined requirements. A proof-of-principle experiment is being constructed in which the rf inductive plasma generator in the present source is replaced by a helicon plasma generator. This is expected to produce a factor of three or better in crease in the maximum source plasma density at a reduced rf power level, resulting in significantly increased negative ion current with reduced heat removal requirements.

  1. A collisional radiative model for caesium and its application to an RF source for negative hydrogen ions

    SciTech Connect

    Wünderlich, D. Wimmer, C.; Friedl, R.

    2015-04-08

    A collisional radiative (CR) model for caesium atoms in low-temperature, low-pressure hydrogen-caesium plasmas is introduced. This model includes the caesium ground state, 14 excited states, the singly charged caesium ion and the negative hydrogen ion. The reaction probabilities needed as input are based on data from the literature, using some scaling and extrapolations. Additionally, new cross sections for electron collision ionization and three-body recombination have been calculated. The relevance of mutual neutralization of positive caesium ions and negative hydrogen ions is highlighted: depending on the densities of the involved particle species, this excitation channel can have a significant influence on the population densities of excited states in the caesium atom. This strong influence is successfully verified by optical emission spectroscopy measurements performed at the IPP prototype negative hydrogen ion source for ITER NBI. As a consequence, population models for caesium in electronegative low-temperature, low-pressure hydrogen-caesium plasmas need to take into account the mutual neutralization process. The present CR model is an example for such models and represents an important prerequisite for deducing the total caesium density in surface production based negative hydrogen ion sources.

  2. Over-the-barrier electron detachment in the hydrogen negative ion

    NASA Astrophysics Data System (ADS)

    Milošević, M. Z.; Simonović, N. S.

    2016-09-01

    The electron detachment from the hydrogen negative ion in strong fields is studied using the two-electron and different single-electron models within the quasistatic approximation. Special attention is payed to over-the-barrier regime where the Stark saddle is suppressed below the lowest energy level. It is demonstrated that the single-electron description of the lowest state of the ion, that is a good approximation for weak fields, fails in this and partially in the tunnelling regime. The exact lowest state energies and detachment rates for the ion at different strengths of the applied field are determined by solving the eigenvalue problem of the full two-electron Hamiltonian. A simple formula for the rate, which is valid in both regimes, is determined by fitting the exact data to the expression estimated using single-electron descriptions.

  3. Capture of negative muons by hydrogen atoms at low collision energies

    SciTech Connect

    Sakimoto, Kazuhiro

    2010-01-15

    A rigorous quantum mechanical calculation is carried out for negative muon capture by atomic hydrogen (mu{sup -}+H->mu{sup -}p+e) by using the R-matrix method. The total and final-state selected capture cross sections are calculated at low collision energies ranging from 0.001 to 1 eV. The total capture cross section can, on average, be explained in terms of a previously obtained empirical formula [K. Sakimoto, Phys. Rev. A 66, 032506 (2002)]. However, the present result exhibits additional undulation and cusp structures, which stem from quantum phenomena. The muons are predominantly captured into the highest energetically possible state of mu{sup -}p in the present energy region. However, the mu{sup -}p products having high angular momenta cannot be formed unless the collision energy becomes high.

  4. Monitoring Surface Condition of Plasma Grid of a Negative Hydrogen Ion Source

    SciTech Connect

    Wada, M.; Kasuya, T.; Tokushige, S.; Kenmotsu, T.

    2011-09-26

    Surface condition of a plasma grid in a negative hydrogen ion source is controlled so as to maximize the beam current under a discharge operation with introducing Cs into the ion source. Photoelectric current induced by laser beams incident on the plasma grid can produce a signal to monitor the surface condition, but the signal detection can be easily hindered by plasma noise. Reduction in size of a detection electrode embedded in the plasma grid can improve signal-to-noise ratio of the photoelectric current from the electrode. To evaluate the feasibility of monitoring surface condition of a plasma gird by utilizing photoelectric effect, a small experimental setup capable of determining quantum yields of a surface in a cesiated plasma environment is being assembled. Some preliminary test results of the apparatus utilizing oxide cathodes are reported.

  5. Electrical shielding box measurement of the negative hydrogen beam from Penning ion gauge ion source

    NASA Astrophysics Data System (ADS)

    Wang, T.; Yang, Z.; Dong, P.; long, J. D.; He, X. Z.; Wang, X.; Zhang, K. Z.; Zhang, L. W.

    2012-06-01

    The cold-cathode Penning ion gauge (PIG) type ion source has been used for generation of negative hydrogen (H-) ions as the internal ion source of a compact cyclotron. A novel method called electrical shielding box dc beam measurement is described in this paper, and the beam intensity was measured under dc extraction inside an electrical shielding box. The results of the trajectory simulation and dc H- beam extraction measurement were presented. The effect of gas flow rate, magnetic field strength, arc current, and extraction voltage were also discussed. In conclusion, the dc H- beam current of about 4 mA from the PIG ion source with the puller voltage of 40 kV and arc current of 1.31 A was extrapolated from the measurement at low extraction dc voltages.

  6. The negative hydrogen Penning ion gauge ion source for KIRAMS-13 cyclotron

    SciTech Connect

    An, D. H.; Jung, I. S.; Kang, J.; Chang, H. S.; Hong, B. H.; Hong, S.; Lee, M. Y.; Kim, Y.; Yang, T. K.; Chai, J. S.

    2008-02-15

    The cold-cathode-type Penning ion gauge (PIG) ion source for the internal ion source of KIRAMS-13 cyclotron has been used for generation of negative hydrogen ions. The dc H-beam current of 650 {mu}A from the PIG ion source with the Dee voltage of 40 kV and arc current of 1.0 A is extrapolated from the measured dc extraction beam currents at the low extraction dc voltages. The output optimization of PIG ion source in the cyclotron has been carried out by using various chimneys with different sizes of the expansion gap between the plasma boundary and the chimney wall. This paper presents the results of the dc H-extraction measurement and the expansion gap experiment.

  7. 3D self-consistent modeling of a matrix source of negative hydrogen ions.

    PubMed

    Tarnev, Kh; Demerdjiev, A; Shivarova, A; Lishev, St

    2016-02-01

    The paper is in the scope of studies on the rf driving of a matrix source of negative hydrogen ions: a matrix of small radius discharges with planar-coil inductive driving and single aperture extraction from each discharge. The results from a three-dimensional model, in which plasma description is coupled to electrodynamics, confirm former conclusion that a single coil driving of the whole matrix by a zigzag coil with an omega-shaped conductor on the bottom of each discharge tube ensures efficient rf power deposition to the plasma. The latter is due to similarities with the rf driving of a single discharge by a single planar coil, shown by the obtained induced current and spatial distribution of the plasma parameters. Distinctions associated with the coil configuration as a single coil for the whole matrix are also discussed. PMID:26932005

  8. Study on a negative hydrogen ion source with hot cathode arc discharge

    SciTech Connect

    Lin, S. H. Fang, X.; Zhang, H. J.; Qian, C.; Ma, B. H.; Wang, H.; Li, X. X.; Zhang, X. Z.; Sun, L. T.; Zhang, Z. M.; Yuan, P.; Zhao, H. W.

    2014-02-15

    A negative hydrogen (H{sup −}) ion source with hot cathode arc discharge was designed and fabricated as a primary injector for a 10 MeV PET cyclotron at IMP. 1 mA dc H{sup −} beam with ε {sub N,} {sub RMS} = 0.08 π mm mrad was extracted at 25 kV. Halbach hexapole was adopted to confine the plasma. The state of arc discharge, the parameters including filament current, arc current, gas pressure, plasma electrode bias, and the ratio of I{sub e{sup −}}/I{sub H{sup −}} were experimentally studied. The discussion on the result, and opinions to improve the source were given.

  9. Electrical shielding box measurement of the negative hydrogen beam from Penning ion gauge ion source

    SciTech Connect

    Wang, T.; Yang, Z.; Dong, P.; Long, J. D.; He, X. Z.; Zhang, K. Z.; Zhang, L. W.; Wang, X.

    2012-06-15

    The cold-cathode Penning ion gauge (PIG) type ion source has been used for generation of negative hydrogen (H{sup -}) ions as the internal ion source of a compact cyclotron. A novel method called electrical shielding box dc beam measurement is described in this paper, and the beam intensity was measured under dc extraction inside an electrical shielding box. The results of the trajectory simulation and dc H{sup -} beam extraction measurement were presented. The effect of gas flow rate, magnetic field strength, arc current, and extraction voltage were also discussed. In conclusion, the dc H{sup -} beam current of about 4 mA from the PIG ion source with the puller voltage of 40 kV and arc current of 1.31 A was extrapolated from the measurement at low extraction dc voltages.

  10. Negative hydrogen ion beam extracted from a Bernas-type ion source

    SciTech Connect

    Miyamoto, N.; Wada, M.

    2011-09-26

    Negative hydrogen (H{sup -}) ion beam was produced without cesium seeding by a Bernas-type ion source with a coaxial hot cathode. The amount of H{sup -} ion beam current extracted from an original Bernas-type ion source using a hairpin shape filament as a hot cathode was 1 {mu}A with the 0.4 A arc current, while that 300 eV beam energy. In the other hand, H{sup -} ion beam current using the Bernas-type ion source with a coaxial hot cathode reached 4 {mu}A under the same condition. Production efficiency was enhanced by the focused plasma produced by a coaxial hot cathode.

  11. Dependence of beam emittance on plasma electrode temperature and rf-power, and filter-field tuning with center-gapped rod-filter magnets in J-PARC rf-driven H- ion source

    NASA Astrophysics Data System (ADS)

    Ueno, A.; Koizumi, I.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2014-02-01

    The prototype rf-driven H- ion-source with a nickel plated oxygen-free-copper (OFC) plasma chamber, which satisfies the Japan Proton Accelerator Research Complex (J-PARC) 2nd stage requirements of a H- ion beam current of 60 mA within normalized emittances of 1.5 π mm mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500 μs × 25 Hz) and a life-time of more than 50 days, was reported at the 3rd international symposium on negative ions, beams, and sources (NIBS2012). The experimental results of the J-PARC ion source with a plasma chamber made of stainless-steel, instead of nickel plated OFC used in the prototype source, are presented in this paper. By comparing these two sources, the following two important results were acquired. One was that the about 20% lower emittance was produced by the rather low plasma electrode (PE) temperature (TPE) of about 120 °C compared with the typically used TPE of about 200 °C to maximize the beam current for the plasma with the abundant cesium (Cs). The other was that by using the rod-filter magnets with a gap at each center and tuning the gap-lengths, the filter-field was optimized and the rf-power necessary to produce the J-PARC required H- ion beam current was reduced typically 18%. The lower rf-power also decreases the emittances.

  12. Dependence of beam emittance on plasma electrode temperature and rf-power, and filter-field tuning with center-gapped rod-filter magnets in J-PARC rf-driven H{sup −} ion source

    SciTech Connect

    Ueno, A. Koizumi, I.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2014-02-15

    The prototype rf-driven H{sup −} ion-source with a nickel plated oxygen-free-copper (OFC) plasma chamber, which satisfies the Japan Proton Accelerator Research Complex (J-PARC) 2nd stage requirements of a H{sup −} ion beam current of 60 mA within normalized emittances of 1.5 π mm mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500 μs × 25 Hz) and a life-time of more than 50 days, was reported at the 3rd international symposium on negative ions, beams, and sources (NIBS2012). The experimental results of the J-PARC ion source with a plasma chamber made of stainless-steel, instead of nickel plated OFC used in the prototype source, are presented in this paper. By comparing these two sources, the following two important results were acquired. One was that the about 20% lower emittance was produced by the rather low plasma electrode (PE) temperature (T{sub PE}) of about 120 °C compared with the typically used T{sub PE} of about 200 °C to maximize the beam current for the plasma with the abundant cesium (Cs). The other was that by using the rod-filter magnets with a gap at each center and tuning the gap-lengths, the filter-field was optimized and the rf-power necessary to produce the J-PARC required H{sup −} ion beam current was reduced typically 18%. The lower rf-power also decreases the emittances.

  13. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source.

    PubMed

    Kim, June Young; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae; Hwang, Y S

    2016-02-01

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H(-) ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H(-) ion generation in volume-produced negative hydrogen ion sources. PMID:26931999

  14. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    NASA Astrophysics Data System (ADS)

    Kim, June Young; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae; Hwang, Y. S.

    2016-02-01

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H- ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ˜4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H- ion generation in volume-produced negative hydrogen ion sources.

  15. Progress on producing polarized negative hydrogen ions by the ETHZ polarized ion source using the atomic beam method

    NASA Astrophysics Data System (ADS)

    Schmelzbach, P. A.; Grüebler, W.

    1983-03-01

    The progress on the ETHZ polarized negative hydrogen ion source, based on the atomic beam method, is described. Particular improvements have been made in the double charge exchange from positive to negative hydrogen ions. At present the source produces over 100 μA H+ ions, which yields 5-6 μA polarized negative hydrogen ions. These ions have been accelerated, in a EN tandem accelerator. A record current of 2-3 μA of polarized deuterons with 89% polarization could be focused through a 3 mm diameter collimator on a target. Further improvements incorporating presently available techniques are discussed. It is shown that 50-100 μA of polarized H- and D- ions can be produced with this type of source.

  16. Single discharge of the matrix source of negative hydrogen ions: Influence of the neutral particle dynamics

    SciTech Connect

    Paunska, Ts.; Todorov, D. Shivarova, A.; Tarnev, Kh.

    2015-04-08

    The study presents two-dimensional (2D) fluid-plasma-model description of a planar-coil inductively-driven discharge, considered as a single element of a matrix source of volume-produced negative hydrogen ions. Whereas the models developed up to now have been directed towards description of the charged particle behavior in the discharge, including that of the negative ions, this model stresses on the role of the neutral particle dynamics and of the surface processes in the formation of the discharge structure. The latter is discussed based on comparison of results obtained for discharges in a flowing gas and at a constant gas pressure as well as for different values of the coefficient of atom recombination on the walls. The conclusions are that the main plasma parameters – electron density and temperature and plasma potential – determining the gas discharge regime stay stable, regardless of changes in the redistribution of the densities of the neutral particles and of the positive ions. With regards to the volume production of the ions, which requires high density of (vibrationally excited) molecules, the impact on the degree of dissociation of the coefficient of atom recombination on the wall is discussed.

  17. Negative Linear Compressibility in Organic Mineral Ammonium Oxalate Monohydrate with Hydrogen Bonding Wine-Rack Motifs.

    PubMed

    Qiao, Yuancun; Wang, Kai; Yuan, Hongsheng; Yang, Ke; Zou, Bo

    2015-07-16

    Negative linear compressibility (NLC) is a relatively uncommon phenomenon and rarely studied in organic systems. Here we provide the direct evidence of the persistent NLC in organic mineral ammonium oxalate monohydrate under high pressure using synchrotron X-ray powder diffraction, Raman spectroscopy and density functional theory (DFT) calculation. Synchrotron X-ray powder diffraction measurement reveals that ammonium oxalate monohydrate shows both positive and negative linear compressibility along b-axis before 11.5 GPa. The red shift of the external Raman modes and abnormal changes of several selected internal modes in high-pressure Raman spectra further confirmed the NLC. DFT calculations demonstrate that the N-H···O hydrogen bonding "wine-rack" motifs result in the NLC along b-axis in ammonium oxalate monohydrate. We anticipate the high-pressure study of ammonium oxalate monohydrate may represent a promising strategy for accelerating the pace of exploitation and improvement of NLC materials especially in organic systems. PMID:26266859

  18. Studies of negative ions by collision-induced decomposition and hydrogen-deuterium exchange techniques.

    PubMed Central

    Hunt, D F; Sethi, S K; Shabanowitz, J

    1980-01-01

    Development of two new techniques for studying the gas phase chemistry of negative ions is reported. Collision induced dissociation (CID) of (M-1)- ions has been accomplished in a newly constructed triple stage quadrupole mass spectrometer. This instrument was assembled by adding two additional Finnigan quadrupole mass filters to a Finnigan Model 3200 CI mass spectrometer. Generation of (M-1)- ions is accomplished by allowing OH- and sample to react under CI conditions in the ion source. The first quadrupole mass filter, Q1, is then employed to selectively pass the (M-1)- ion into a second quadrupole filter containing argon or neon at 10(-3) torr. On collision with the inert gas the (M-1)- ions dissociate into fragments which are then mass analyzed in the third quadrupole filter, CID spectra of (M-1)- ions from twelve carbonyl compounds are presented in this paper. Ion molecule isotope exchange reactions in the CI ion source can be used to count the number of hydrogen atoms in many different chemical environments. Collisions between sample (M-1)- ions and deuterium-labeled reagent gases (ND3, D2O, EtOD) facilitate incorporation of deuterium into the negative ion if the basicities of the sample and reagent anions are similar. Thus it is possible to selectively incorporate deuterium into many organic samples by controlling the exothermicity of the acid base, ion-molecule chemistry. PMID:7428745

  19. Measurement of the negative hydrogen ions temperature by using an omegatron mass analyzer in the sheet plasma

    NASA Astrophysics Data System (ADS)

    Takimoto, Toshikio; Iijima, Takaaki; Tanaka, Yuta; Hase, Takuya; Tonegawa, Akira; Sato, Kohnosuke; Kawamura, Kazutaka

    2015-09-01

    The production mechanisms of negative ions in hydrogen plasma are not easily understood because of the complex phenomena of atomic and molecular reactions. A mainstream measurement of H- is a laser photodetachment technique. We had measured negative ions using a laser photodetachment technique. Consequently, under a secondary hydrogen gas supply entering into the plasma, the H- is distributed in the periphery of the sheet plasma. In addition, it has been reported that the negative hydrogen ions transport velocity evaluated by the relaxation time of optically released electron current. Nevertheless, this technique a laser photodetachment cannot be used as a mass analyzer. In this paper, we have measured the temperature of the negative hydrogen ions TH- by using an omegatron mass analyzer in the sheet plasma. The TH- is determined by measuring the collection ion currents IH- as a function of the ion repeller voltage VG2 by using an omegatron mass analyzer. From the fitting an exponential region of the measured I-V characteristics curve, TH- is around 1.40 eV at the gas pressure of 0.23 Pa in the periphery region of the sheet plasma.

  20. The study of discharge characteristic of the cold-cathode negative hydrogen PIG-type ion source

    NASA Astrophysics Data System (ADS)

    Yang, Z.; Dong, P.; Long, J. D.; Wang, T.; Lan, C. H.; Peng, Y. F.; Wei, T.; He, X. Z.; Zhang, K. Z.; Shi, J. S.

    2012-09-01

    The cold-cathode Penning ion gage (PIG)-type ion source is designed for the internal ion source of the compact cyclotron. This kind of ion source has been used for generation of the negative hydrogen (H-) ions for many decades. The discharge characteristics of the ion source are investigated systematically for hydrogen operation at different discharge currents, gas flow rates and magnetic fields, respectively. In this paper, optical emission spectroscopy measurement is carried out to diagnose the parameters of the hydrogen plasma in the ion source. The preliminary optimization of the H- formation with the gas flow rates is discussed and analyzed. Current experimental results can provide useful information for the design and operation of the negative ion source.

  1. Characterisation of the properties of a negative hydrogen ion beam by several beam diagnostic techniques

    NASA Astrophysics Data System (ADS)

    Maurizio, R.; Fantz, U.; Bonomo, F.; Serianni, G.

    2016-06-01

    The beam properties of the BATMAN negative ion source, which is the prototype of one module of the source for the ITER neutral beam injection system, are characterised by means of three diagnostic techniques: beam emission spectroscopy (BES), the experimental calorimeter mini-STRIKE and a copper calorimeter. The main beam parameters—beam divergence, homogeneity and top–bottom asymmetries—are studied in different operational scenarios: with different magnetic filter field setups, source settings and with different gases (hydrogen or deuterium). Among all dependences, the influence of the magnetic field configuration on the beam and the evolution of the beam features during some conditioning days are investigated in detail. Data show that the stronger the filter field in the beam region, the higher the beam top–bottom asymmetry—likely a v× B effect. During the conditioning of the source, such vertical beam asymmetry increases as well, suggesting an inhomogeneous H ‑production at the first grid of the extraction system.

  2. Quantification Of Cesium In Negative Hydrogen Ion Sources By Laser Absorption Spectroscopy

    SciTech Connect

    Fantz, U.; Wimmer, Ch.

    2011-09-26

    The use of cesium in negative hydrogen ion sources and the resulting cesium dynamics caused by the evaporation and redistribution in the vacuum and plasma phase makes a reliable and on-line monitoring of the cesium amount in the source highly desirable. For that purpose, a robust and compact laser absorption setup suitable for the ion source environment has been developed utilizing the Cs D{sub 2} resonance line at 852.1 nm. First measurements are taken in a small laboratory plasma chamber with cesium evaporation. A detection limit of {approx_equal}5x10{sup 13} m{sup -3} at a typical path length of 15 cm has been obtained with a dynamic range of more than three orders of magnitude, limited by line saturation at high densities. For on-line monitoring an automatic data analysis is established achieving a temporal resolution of 100 ms. The setup has then been applied to the ITER prototype ion sources developed at IPP. It is been shown that the method is well suited for routine measurements revealing a new insight into the cesium dynamics during source operation and cesium conditioning.

  3. Operation Status of the J-PARC Negative Hydrogen Ion Source

    SciTech Connect

    Oguri, H.; Ikegami, K.; Ohkoshi, K.; Namekawa, Y.; Ueno, A.

    2011-09-26

    A cesium-free negative hydrogen ion source driven with a lanthanum hexaboride (LaB{sub 6}) filament is being operated without any serious trouble for approximately four years in J-PARC. Although the ion source is capable of producing an H{sup -} ion current of more than 30 mA, the current is routinely restricted to approximately 16 mA at present for the stable operation of the RFQ linac which has serious discharge problem from September 2008. The beam run is performed during 1 month cycle, which consisted of a 4-5 weeks beam operation and a few days down-period interval. At the recent beam run, approximately 700 h continuous operation was achieved. At every runs, the beam interruption time due to the ion source failure is a few hours, which correspond to the ion source availability of more than 99%. The R and D work is being performed in parallel with the operation in order to enhance the further beam current. As a result, the H{sup -} ion current of 61 mA with normalized rms emittance of 0.26 {pi}mm.mrad was obtained by adding a cesium seeding system to a J-PARC test ion source which has the almost same structure with the present J-PARC ion source.

  4. Effects of roughness and temperature on low-energy hydrogen positive and negative ion reflection from silicon and carbon surfaces

    SciTech Connect

    Tanaka, N.; Kato, S.; Miyamoto, T.; Wada, M.; Nishiura, M.; Tsumori, K.; Matsumoto, Y.; Kenmotsu, T.; Okamoto, A.; Kitajima, S.; Sasao, M.; Yamaoka, H.

    2014-02-15

    Angle-resolved energy distribution functions of positive and negative hydrogen ions produced from a rough-finished Si surface under 1 keV proton irradiation have been measured. The corresponding distribution from a crystalline surface and a carbon surface are also measured for comparison. Intensities of positive and negative ions from the rough-finished Si are substantially smaller than those from crystalline Si. The angular distributions of these species are broader for rough surface than the crystalline surface. No significant temperature dependence for positive and negative ion intensities is observed for all samples in the temperature range from 300 to 400 K.

  5. Chaos, noise, and tails on the I-V curve steps of rf-driven Josephson junctions

    NASA Astrophysics Data System (ADS)

    Cronemeyer, D. C.; Chi, C. C.; Davidson, A.; Pedersen, N. F.

    1985-03-01

    We report the first experiments and digital and analog simulations which demonstrate the existence of chaotic regions in the I-V curves of dc- and rf-current-biased Josephson junctions. These junctions were formed of crossed Pb strips and were shunted with Au resistors. Chaos appears as negatively going tails on the trailing edges of the rf-induced steps; these tails, which may be as large as 50% of the voltage step width, have not previously been reported. The parameters for the occurrence of these tails center at βc=4, Ω=ω/ωp=0.15, irf=Irf/Ic=1.04, Ic=3×105 A/m2 at 4.2 K. The thermal noise of the shunting resistor was emulated by a Gaussian spectrum. The presence of such noise dramatically alters the substeps, spikes, and bifurcations predicted for zero temperature. With only small amounts of noise, such complexities disappear, and are replaced by a smooth tail on the step accompanied by broadband noise. There is good agreement between the experiments on a real junction, simulations with a phase-locked loop, and numerical calculations with a digital computer.

  6. Design of long pulse/steady state negative hydrogen ion sources for fusion applications

    SciTech Connect

    Prelec, K.

    1980-01-01

    By using parameters of ion sources when operating in a pulsed mode and without cooling (pulse length < 0.1 s), requirements have been determined for a long pulse (several seconds) or steady state operating mode and two sources have been designed and fabricated. First of the two is a penning source, designed for a steady state operation with a cathode power density of 1 kW/cm/sup 2/. For the range of cathode power densities between 0.2 kW/cm/sup 2/ and 1 Kw/cm/sup 2/, nucleated boiling has to be used for heat removal; below 0.2 kW/cm/sup 2/ water flow cooling suffices. Although this source should deliver 0.3 to 0.5 A of H/sup -/ ions in a steady state operation and at full power, the other source, which has a magnetron geometry, is more promising. The latter incorporates two new features compared to first designs, geometrical focusing of fast, primary negative hydrogen ions from the cathode into the extraction slit, and a wider discharge gap in the back of the source. These two changes have resulted in an improvement of the power and gas efficiencies by a factor of 3 to 4 and in a reduction of the cathode power density by an order of magnitude. The source has water cooling for all the electrodes, because maximum power densities will not be higher than 0.2 kW/cm/sup 2/. Very recently a modification of this magnetron source is being considered; it consists of plasma injection into the source from a hollow cathode discharge.

  7. Spatial and temporal evolution of negative ions in a pulsed inductively coupled hydrogen plasma source across a magnetic filter

    NASA Astrophysics Data System (ADS)

    Nulty, Stuart; Corr, Cormac

    2015-09-01

    Low-temperature electronegative plasmas have important applications in high-energy sources for fusion energy, plasma thrusters and materials processing. Neutral beam injection systems and space thruster technology such as the PEGASUS propulsion system rely on efficiently producing extractable negative ions. In this work we investigate the production of hydrogen negative ions in a pulsed inductively coupled plasma across a magnetic filter. The electron energy distribution function, plasma density and electron temperature are determined using an RF compensated Langmuir probe, and time-resolved laser photo-detachment is used to measure the negative ion fraction. The spatial and temporal evolution of these plasma parameters within the plasma source will be presented. Using a pulsed plasma and a magnetic filter, the electron temperature can be efficiently controlled and a higher density of negative ions compared to electrons can be obtained at certain locations within the source.

  8. Maintenance and operation procedure, and feedback controls of the J-PARC RF-driven H{sup −} ion source

    SciTech Connect

    Ueno, A. Ohkoshi, K.; Ikegami, K.; Takagi, A.; Yamazaki, S.; Oguri, H.

    2015-04-08

    In order to satisfy the Japan Proton Accelerator Research Complex (J-PARC) second stage requirements of an H{sup −} ion beam of 60mA within normalized emittances of 1.5πmm•mrad both horizontally and vertically, a flat top beam duty factor of 1.25% (500μs×25Hz) and a life-time of longer than 1month, the J-PARC cesiated RF-driven H{sup −} ion source was developed by using an internal-antenna developed at the Spallation Neutron Source (SNS). The maintenance and operation procedure to minimize the plasma chamber (PCH) replacement time on the beam line, which is very important to maximize the J-PARC beam time especially for an antenna failure, is presented in this paper. The PCH preserved by filling argon (Ar) gas inside after pre-conditioning including pre-cesiation to produce the required beam at a test-stand successfully produced the required beam on the beam line with slight addition of cesium (Cs). The methods of the feedback controls of a 2MHz-RF-matching, an H{sup −} ion beam intensity and the addition of Cs are also presented. The RF-matching feedback by using two vacuum variable capacitors (VVCs) and RF-frequency shift produced the almost perfect matching with negligibly small reflected RF-power. The H{sup −} ion beam intensity was controlled within errors of ±0.1mA by the RF-power feedback. The amount of Cs was also controlled by remotely opening a Cs-valve to keep the RF-power lower than a settled value.

  9. Hydrogen negative-ion surface production on diamond materials in low-pressure H2 plasmas

    NASA Astrophysics Data System (ADS)

    Cartry, Gilles; Achkasov, Kostiantyn; Pardanaud, Cédric; Layet, Jean-Marc; Simonin, Alain; Gicquel, Alix; PIIM Collaboration; IRFM Collaboration; LSPM Collaboration

    2014-10-01

    Negative-ion sources producing H-current density of ~200 A/m2 are required for the heating of the fusion plasma of the international project ITER. The only up-to-date solution to reach such a high H-negative-ion current is the use of cesium (Cs). Deposition of Cs on the negative-ion source walls lowers the material work function and allows for high electron-capture efficiency by incident particles and thus, high negative ion yields. However, severe drawbacks to the use of Cs have been identified and its elimination from the fusion negative-ion sources would be highly valuable. Volume production is not efficient enough at low-pressure to reach the high current required. Therefore, we are working on alternative solutions to produce high yield of H-negative-ions on surfaces in Cs-free H2 plasmas. In this communication, we will detail the methodology employed to study negative-ion surface production. In particular we will describe how the negative-ions are extracted from the plasma, and how we can obtain information on surface production mechanisms from the measurement of the H-energy distribution functions. We will present some results obtained on diamond surfaces and show that diamond is a promising candidate as a negative-ion enhancer material in low-pressure H2 plasmas. EFDA, FR-FCM, ANR, PACA are acknowledged for their support.

  10. Partially hydrogenated and fluorinated graphene: Structure, roughness, and negative thermal expansion

    NASA Astrophysics Data System (ADS)

    Neek-Amal, M.; Peeters, F. M.

    2015-10-01

    The structural properties of partially hydrogenated and fluorinated graphene with different percentages of H/F atoms are investigated using molecular dynamics simulations based on reactive force field (ReaxFF) potentials. We found that the roughness of graphene varies with the percentage (p ) of H or F and in both cases is maximal around p =50 % . Similar results were obtained for partially oxidized graphene. The two-dimensional area size of partially fluorinated and hydrogenated graphene exhibits a local minimum around p =35 % coverage. The lattice thermal contraction in partially functionalized graphene is found to be one order of magnitude larger than that of fully covered graphene. We also show that the armchair structure for graphene oxide (similar to the structure of fully hydrogenated and fluorinated graphene) is unstable. Our results show that the structure of partially functionalized graphene changes nontrivially with the C : H and C : F ratio as well as with temperature.

  11. An unexpected negative influence of light intensity on hydrogen production by dark fermentative bacteria Clostridium beijerinckii.

    PubMed

    Zagrodnik, R; Laniecki, M

    2016-01-01

    The role of light intensity on biohydrogen production from glucose by Clostridium beijerinckii, Clostridium acetobutylicum, and Rhodobacter sphaeroides was studied to evaluate the performance and possible application in co-culture fermentation system. The applied source of light had spectrum similar to the solar radiation. The influence of light intensity on hydrogen production in dark process by C. acetobutylicum was negligible. In contrast, dark fermentation by C. beijerinckii bacteria showed a significant decrease (83%) in produced hydrogen at light intensity of 540W/m(2). Here, the redirection of metabolism from acetic and butyric acid formation towards lactic acid was observed. This not yet reported effect was probably caused by irradiation of these bacteria by light within UVA range, which is an important component of the solar radiation. The excessive illumination with light of intensity higher than 200W/m(2) resulted in decrease in hydrogen production with photofermentative bacteria as well. PMID:26602144

  12. Capacitively Coupled Radio Frequency Discharge Plasmas In Hydrogen: Particle Modeling and Negative Ion Kinetics

    SciTech Connect

    Diomede, P.; Longo, S.; Capitelli, M.

    2005-05-16

    We present a 1D(r)2D(v) particle code for capacitively coupled radio frequency discharge plasmas in hydrogen, which includes a rigorous kinetic modeling of ion transport and several solutions to speed up the convergence. In a test case the effect of surface atom recombination and molecule vibrational deactivation on H- concentration is investigated.

  13. Hydrogen Peroxide Linked to Lysine Oxidase Activity Facilitates Biofilm Differentiation and Dispersal in Several Gram-Negative Bacteria▿

    PubMed Central

    Mai-Prochnow, Anne; Lucas-Elio, Patricia; Egan, Suhelen; Thomas, Torsten; Webb, Jeremy S.; Sanchez-Amat, Antonio; Kjelleberg, Staffan

    2008-01-01

    The marine bacterium Pseudoalteromonas tunicata produces an antibacterial and autolytic protein, AlpP, which causes death of a subpopulation of cells during biofilm formation and mediates differentiation, dispersal, and phenotypic variation among dispersal cells. The AlpP homologue (LodA) in the marine bacterium Marinomonas mediterranea was recently identified as a lysine oxidase which mediates cell death through the production of hydrogen peroxide. Here we show that AlpP in P. tunicata also acts as a lysine oxidase and that the hydrogen peroxide generated is responsible for cell death within microcolonies during biofilm development in both M. mediterranea and P. tunicata. LodA-mediated biofilm cell death is shown to be linked to the generation of phenotypic variation in growth and biofilm formation among M. mediterranea biofilm dispersal cells. Moreover, AlpP homologues also occur in several other gram-negative bacteria from diverse environments. Our results show that subpopulations of cells in microcolonies also die during biofilm formation in two of these organisms, Chromobacterium violaceum and Caulobacter crescentus. In all organisms, hydrogen peroxide was implicated in biofilm cell death, because it could be detected at the same time as the killing occurred, and the addition of catalase significantly reduced biofilm killing. In C. violaceum the AlpP-homologue was clearly linked to biofilm cell death events since an isogenic mutant (CVMUR1) does not undergo biofilm cell death. We propose that biofilm killing through hydrogen peroxide can be linked to AlpP homologue activity and plays an important role in dispersal and colonization across a range of gram-negative bacteria. PMID:18502869

  14. Study of negative hydrogen ion beam optics using the 3D3V PIC model

    NASA Astrophysics Data System (ADS)

    Miyamoto, K.; Nishioka, S.; Goto, I.; Hatayama, A.; Hanada, M.; Kojima, A.

    2015-04-01

    The mechanism of negative ion extraction under real conditions with the complex magnetic field is studied by using the 3D PIC simulation code. The extraction region of the negative ion source for the negative ion based neutral beam injection system in fusion reactors is modelled. It is shown that the E x B drift of electrons is caused by the magnetic filter and the electron suppression magnetic field, and the resultant asymmetry of the plasma meniscus. Furthermore, it is indicated that that the asymmetry of the plasma meniscus results in the asymmetry of negative ion beam profile including the beam halo. It could be demonstrated theoretically that the E x B drift is not significantly weakened by the elastic collisions of the electrons with neutral particles.

  15. Study of negative hydrogen ion beam optics using the 3D3V PIC model

    SciTech Connect

    Miyamoto, K.; Nishioka, S.; Goto, I.; Hatayama, A.; Hanada, M.; Kojima, A.

    2015-04-08

    The mechanism of negative ion extraction under real conditions with the complex magnetic field is studied by using the 3D PIC simulation code. The extraction region of the negative ion source for the negative ion based neutral beam injection system in fusion reactors is modelled. It is shown that the E x B drift of electrons is caused by the magnetic filter and the electron suppression magnetic field, and the resultant asymmetry of the plasma meniscus. Furthermore, it is indicated that that the asymmetry of the plasma meniscus results in the asymmetry of negative ion beam profile including the beam halo. It could be demonstrated theoretically that the E x B drift is not significantly weakened by the elastic collisions of the electrons with neutral particles.

  16. Hydrogen Bonding and Binding of Polybasic Residues with Negatively Charged Mixed Lipid Monolayers

    SciTech Connect

    Lorenz, C.; Feraudo, J.; Travesset, A.

    2008-01-23

    Phosphoinositides, phosphorylated products of phosphatidylinositol, are a family of phospholipids present in tiny amounts (1% or less) in the cytosolic surface of cell membranes, yet they play an astonishingly rich regulatory role, particularly in signaling processes. In this letter, we use molecular dynamics simulations on a model system of mixed lipid monolayers to investigate the interaction of phosphatidylinositol 4,5-bisphosphate (PIP{sub 2}), the most common of the phosphoinositides, with a polybasic peptide consisting of 13 lysines. Our results show that the polybasic peptide sequesters three PIP{sub 2} molecules, forming a complex stabilized by the formation of multiple hydrogen bonds between PIP{sub 2} and the Lys residues. We also show that the polybasic peptide does not sequester other charged phospholipids such as phosphatidylserine because of the inability to form long-lived stable hydrogen bonds.

  17. Tests on the extracted current density of negative hydrogen ions from a single element of the matrix source

    SciTech Connect

    Lishev, St.; Yordanov, D. Shivarova, A.

    2015-04-08

    Concepts for the extraction of volume-produced negative hydrogen ions from a rf matrix source (a matrix of small-radius discharges with a planar-coil inductive driving) are presented and discussed based on experimental results for the current densities of the extracted ions and the co-extracted electrons. The experiment has been carried out in a single discharge of the source: a rf discharge with a radius of 2.25 cm inductively driven by a 3.5-turn planar coil. The length of the discharge tube, the area of the reference electrode inserted in the discharge volume, the discharge modes, the magnetic filter and its position along the discharge length, the position of the permanent magnets for the separation of the co-extracted electrons from the extracted ions in the extraction device and the bias applied to its first electrode are considered as factors influencing the extracted currents of negative ions.

  18. VUV Absorption Spectroscopy of a Penning Surface - Negative Hydrogen Ion Source

    NASA Astrophysics Data System (ADS)

    Pitcher, Eric John

    The demand for energetic, high-current H ^- beams is ever-growing. Because H ^- is efficiently neutralized at high energies, these beams are ideally suited to applications where energetic neutral beams of particles are required to propagate across magnetic fields. Prime examples are neutral-beam heating of magnetic fusion plasmas and directed-energy weapons for ballistic missile defense. Such applications place demanding requirements on sources of H^ - ions, particularly with respect to the parameters of beam current, brightness, quiescence, reliability, and duty-factor. A class of sources that holds great promise for meeting these stringent requirements is the surface-plasma source (SPS), and in particular, the Penning type of SPS. It has long been conjectured that atomic hydrogen plays an important role in both H^- formation and transport in these sources. Understanding the interdependence of atomic hydrogen properties and those of H^ -, and how this relationship might be exploited to improve source performance is the motivation for this research. An overview of SPS's is presented. Previous measurements on the discharge are reviewed. Absorption spectroscopy, the diagnostic technique used to gather all of the data presented here, is discussed. Techniques that may potentially be used to measure the properties of H^ - in the discharge are discussed. The two absorption spectrometers used in this experiment are described. Measurements of ground-state atomic hydrogen density and temperature in a Penning SPS are presented. These measurements are the first of this kind for this type of discharge. An upper limit on the H^- density in the extraction region of the source is measured by the application of a novel diagnostic technique: the hydrogen atom density following H^- photodetachment by a Nd:YAG beam is measured and compared to the equilibrium atomic density. A simple model is derived that describes the dependence of the atomic temperature on the externally

  19. Volume generation of negative ions in high density hydrogen discharges. Revision 1

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.

    1983-11-11

    An optimized tandem two-chamber negative-ion source system is discussed. In the first chamber high energy (E > 20 eV) electron collisions provide for H/sub 2/ vibrational excitation, while in the second chamber negative ions are formed by dissociative attachment. The gas density, electron density, and system scale length are varied as independent parameters. The extracted negative ion current density passes through a maximum as electron and gas densities are varied. This maximum scales inversely with system scale length, R. The optimum extracted current densities occur for electron densities near nR = 10/sup 13/ electrons cm/sup -2/ and for gas densities, N/sub 2/R, in the range 10/sup 14/ to 10/sup 15/ molecules cm/sup -2/. The extracted current densities are sensitive to the atomic concentration in the discharge. The atomic concentration is parametrized by the wall recombination coefficient, ..gamma.., and scale length, R. As ..gamma.. ranges from 0.1 to 1.0 and for system scale lengths of one centimeter, extracted current densities range from 8.0 to 80. mA cm/sup -2/.

  20. Characteristics of Hydrogen Negative Ion Source with FET based RF System

    SciTech Connect

    Ando, A.; Matsuno, T.; Funaoi, T.; Tanaka, N.; Tsumori, K.; Takeiri, Y.

    2011-09-26

    Characteristics of radio frequency (RF) plasma production were investigated using a FET inverter power supply as a RF generator. High density hydrogen plasma was obtained using an external coil wound a cylindrical ceramic tube (driver region) with RF frequency of lower than 0.5 MHz. When an axial magnetic field around 10 mT was applied to the driver region, an electron density increased drastically and attained to over 10{sup 19} m{sup -3} in the driver region. Effect of the axial magnetic field in driver and expansion region was examined. Lower gas pressure operation below 0.5 Pa was possible with higher RF frequency. H{sup -} density in the expansion region was measured by using laser photo-detachment system. It decreased as the axial magnetic field applied, which was caused by the increase of energetic electron from the driver.

  1. Analysis of Discharge Initiation in a RF Hydrogen Negative Ion Source

    SciTech Connect

    Hayami, T.; Yoshinari, S.; Terasaki, R.; Hatayama, A.; Fukano, A.

    2011-09-26

    The maintenance free RF ion source is expected to be one of the most promising candidates for the negative ion sources of plasma heating for fusion reactors. In order to make clear the condition for the discharge initiation of the RF source, we are developing an electromagnetic PIC model. The numerical result shows that a positive potential built-up with respect to the wall. As a result, the electron wall loss decreases and the electron density increases. The positive potential plays a key role for the suppression of wall loss and the electron confinement. The electromagnetic-PIC model developed is useful for the analysis of discharge initiation of the RF source.

  2. Mesic molecular effects in the capture of negative pions stopped in gaseous hydrogen isotopes

    NASA Astrophysics Data System (ADS)

    Aniol, K. A.; Measday, D. F.; Hasinoff, M. D.; Roser, H. W.; Bagheri, A.; Entezami, F.; Virtue, C.; Stadlbauer, J. M.; Horváth, D.; Salomon, M.; Robertson, B. C.

    1983-11-01

    The influence of molecular structure on the nuclear capture probability of stopped negative pions has been observed by comparing the π0 gamma-ray spectrum from π- mesons stopped in HD gas to that from a mixture of equal amounts of H2 plus D2. The fraction of stopped pions that are captured by a proton in the H2+D2 mixture is fH2D2=0.417+/-0.004, while for HD it is fHD=0.338+/-0.008, independent of the gas pressure between 6 and 90 atm. The ratio, fH2D2fHD, of the fractions is 1.23+/-0.03.

  3. Transport properties of bare and hydrogenated zigzag silicene nanoribbons: Negative differential resistances and perfect spin-filtering effects

    SciTech Connect

    Yang, X. F.; Liu, Y. S. Feng, J. F.; Wang, X. F.; Zhang, C. W.; Chi, F.

    2014-09-28

    Ab initio calculations are performed to investigate the spin-polarized transport properties of the bare and hydrogenated zigzag silicene nanoribbons (ZSiNRs). The results show that the ZSiNRs with symmetric (asymmetric) edges prefer the ferromagnetic (antiferromagnetic) as their ground states with the semiconductor properties, while the accordingly antiferromagnetic (ferromagnetic) states exhibit the metallic behaviors. These facts result in a giant magnetoresistance behavior between the ferromagnetic and antiferromagnetic states in the low bias-voltage regime. Moreover, in the ferromagnetic ZSiNRs with asymmetric edges, a perfect spin-filtering effect with 100% positive electric current polarization can be achieved by altering the bias voltage. In addition, we also find that the negative differential resistances prefer the metastable states. The findings here indicate that the asymmetric and symmetric ZSiNRs are promising materials for spintronic applications.

  4. Measurements of Lyman Alpha Radiation from Collisions, 100 EV to 4000EV, of Negative Hydrogen Ions on Various Target Gases and Positive Hydrogen Ions on Xenon

    NASA Astrophysics Data System (ADS)

    Greenland, Glenn Blair

    This study reports measurements of cross sections for the production of Lyman alpha radiation from processes in which an ion is incident on a neutral target gas. Two kinds of processes were measured: the stripping of the extra electron from a negative hydro- gen ion leaving an excited neutral and the capture of an electron by a proton also leaving an excited neutral. In each case, radiation from the 2p state of the neutral hydrogen was detected. The projectile struck the static gas target with a kinetic energy between 100 and 4000 electron volts. The measurements used the ultraviolet absorption properties of molecular oxygen to isolate the Lyman alpha line. Cross sections for emission of Lyman alpha perpendicular to the incident beam were determined. The targets used in the stripping experiments were the atomic gases: helium, neon, argon, krypton and xenon, and the molecular gases: hydrogen, nitrogen and methane. The cross sections are rela- tively flat over the energy range investigated. All are slightly below 10('-16) cm('2) at 1000 eV. Only with the neon target does the cross section fall below 2 x 10('0-17) cm('2) at 100 electron volts. While the data appear to support the modeling of stripping with excitation as a two step process, this modeling may not be valid for excitation above 2p. Only a xenon target was used in the capture experiments. Careful measurements did not substantiate an earlier report of unusual structure('1) in this cross section. ('1)P. J. Martin, Ph.D. Dissertation, Univ. of Nebraska, 1975.

  5. Aharonov-Bohm Effect in the Photodetachment Microscopy of Hydrogen Negative Ions in an Electric Field

    NASA Astrophysics Data System (ADS)

    Wang, Dehua

    2014-09-01

    The Aharonov-Bohm (AB) effect in the photodetachment microscopy of the H- ions in an electric field has been studied on the basis of the semiclassical theory. After the H- ion is irradiated by a laser light, they provide a coherent electron source. When the detached electron is accelerated by a uniform electric field, two trajectories of a detached electron which run from the source to the same point on the detector, will interfere with each other and lead to an interference pattern in the photodetachment microscopy. After the solenoid is electrified beside the H- ion, even though no Lorentz force acts on the electron outside the solenoid, the photodetachment microscopy interference pattern on the detector is changed with the variation in the magnetic flux enclosed by the solenoid. This is caused by the AB effect. Under certain conditions, the interference pattern reaches the macroscopic dimensions and could be observed in a direct AB effect experiment. Our study can provide some predictions for the future experimental study of the AB effect in the photodetachment microscopy of negative ions.

  6. Development of a Negative Hydrogen Ion Source for Spatial Beam Profile Measurement of a High Intensity Positive Ion Beam

    SciTech Connect

    Shinto, Katsuhiro; Wada, Motoi; Nishida, Tomoaki; Demura, Yasuhiro; Sasaki, Daichi; Tsumori, Katsuyoshi; Nishiura, Masaki; Kaneko, Osamu; Kisaki, Masashi; Sasao, Mamiko

    2011-09-26

    We have been developing a negative hydrogen ion (H{sup -} ion) source for a spatial beam profile monitor of a high intensity positive ion beam as a new diagnostic tool. In case of a high intensity continuous-wave (CW) deuteron (D{sup +}) beam for the International Fusion Materials Irradiation Facility (IFMIF), it is difficult to measure the beam qualities in the severe high radiation environment during about one-year cyclic operation period. Conventional techniques are next to unusable for diagnostics in the operation period of about eleven months and for maintenance in the one-month shutdown period. Therefore, we have proposed an active beam probe system by using a negative ion beam and started an experimental study for the proof-of-principle (PoP) of the new spatial beam profile monitoring tool. In this paper, we present the status of development of the H{sup -} ion source as a probe beam source for the PoP experiment.

  7. Global model analysis of negative ion generation in low-pressure inductively coupled hydrogen plasmas with bi-Maxwellian electron energy distributions

    SciTech Connect

    Huh, Sung-Ryul; Kim, Nam-Kyun; Jung, Bong-Ki; Chung, Kyoung-Jae; Hwang, Yong-Seok; Kim, Gon-Ho

    2015-03-15

    A global model was developed to investigate the densities of negative ions and the other species in a low-pressure inductively coupled hydrogen plasma with a bi-Maxwellian electron energy distribution. Compared to a Maxwellian plasma, bi-Maxwellian plasmas have higher populations of low-energy electrons and highly vibrationally excited hydrogen molecules that are generated efficiently by high-energy electrons. This leads to a higher reaction rate of the dissociative electron attachment responsible for negative ion production. The model indicated that the bi-Maxwellian electron energy distribution at low pressures is favorable for the creation of negative ions. In addition, the electron temperature, electron density, and negative ion density calculated using the model were compared with the experimental data. In the low-pressure regime, the model results of the bi-Maxwellian electron energy distributions agreed well quantitatively with the experimental measurements, unlike those of the assumed Maxwellian electron energy distributions that had discrepancies.

  8. Optimization of plasma parameters with magnetic filter field and pressure to maximize H- ion density in a negative hydrogen ion source

    NASA Astrophysics Data System (ADS)

    Cho, Won-Hwi; Dang, Jeong-Jeung; Kim, June Young; Chung, Kyoung-Jae; Hwang, Y. S.

    2016-02-01

    Transverse magnetic filter field as well as operating pressure is considered to be an important control knob to enhance negative hydrogen ion production via plasma parameter optimization in volume-produced negative hydrogen ion sources. Stronger filter field to reduce electron temperature sufficiently in the extraction region is favorable, but generally known to be limited by electron density drop near the extraction region. In this study, unexpected electron density increase instead of density drop is observed in front of the extraction region when the applied transverse filter field increases monotonically toward the extraction aperture. Measurements of plasma parameters with a movable Langmuir probe indicate that the increased electron density may be caused by low energy electron accumulation in the filter region decreasing perpendicular diffusion coefficients across the increasing filter field. Negative hydrogen ion populations are estimated from the measured profiles of electron temperatures and densities and confirmed to be consistent with laser photo-detachment measurements of the H- populations for various filter field strengths and pressures. Enhanced H- population near the extraction region due to the increased low energy electrons in the filter region may be utilized to increase negative hydrogen beam currents by moving the extraction position accordingly. This new finding can be used to design efficient H- sources with an optimal filtering system by maximizing high energy electron filtering while keeping low energy electrons available in the extraction region.

  9. Optimization of plasma parameters with magnetic filter field and pressure to maximize H⁻ ion density in a negative hydrogen ion source.

    PubMed

    Cho, Won-Hwi; Dang, Jeong-Jeung; Kim, June Young; Chung, Kyoung-Jae; Hwang, Y S

    2016-02-01

    Transverse magnetic filter field as well as operating pressure is considered to be an important control knob to enhance negative hydrogen ion production via plasma parameter optimization in volume-produced negative hydrogen ion sources. Stronger filter field to reduce electron temperature sufficiently in the extraction region is favorable, but generally known to be limited by electron density drop near the extraction region. In this study, unexpected electron density increase instead of density drop is observed in front of the extraction region when the applied transverse filter field increases monotonically toward the extraction aperture. Measurements of plasma parameters with a movable Langmuir probe indicate that the increased electron density may be caused by low energy electron accumulation in the filter region decreasing perpendicular diffusion coefficients across the increasing filter field. Negative hydrogen ion populations are estimated from the measured profiles of electron temperatures and densities and confirmed to be consistent with laser photo-detachment measurements of the H(-) populations for various filter field strengths and pressures. Enhanced H(-) population near the extraction region due to the increased low energy electrons in the filter region may be utilized to increase negative hydrogen beam currents by moving the extraction position accordingly. This new finding can be used to design efficient H(-) sources with an optimal filtering system by maximizing high energy electron filtering while keeping low energy electrons available in the extraction region. PMID:26932018

  10. Negative-ion surface production in hydrogen plasmas: Determination of the negative-ion energy and angle distribution function using mass spectrometry

    NASA Astrophysics Data System (ADS)

    Dubois, J. P. J.; Achkasov, K.; Kogut, D.; Ahmad, A.; Layet, J. M.; Simonin, A.; Cartry, G.

    2016-05-01

    This work focuses on the understanding of the production mechanism of negative-ions on surface in low pressure plasmas of H2/D2. The negative ions are produced on a Highly Oriented Pyrolytic Graphite sample negatively biased with respect to plasma potential. The negative ions created under the positive ion bombardment are accelerated towards the plasma, self-extracted, and detected according to their energy and mass by a mass spectrometer placed in front of the sample. The shape of the measured Negative-Ion Energy Distribution Function (NIEDF) strongly differs from the NIEDF of the ions emitted by the sample because of the limited acceptance angle of the mass spectrometer. To get information on the production mechanisms, we propose a method to obtain the distribution functions in energy and angle (NIEADFs) of the negative-ions emitted by the sample. It is based on an a priori determination of the NIEADF and on an a posteriori validation of the choice by comparison of the modelled and experimental NIEDFs.

  11. Endothelial nitric oxide synthase negatively regulates hydrogen peroxide-stimulated AMP-activated protein kinase in endothelial cells.

    PubMed

    Jin, Benjamin Y; Sartoretto, Juliano L; Gladyshev, Vadim N; Michel, Thomas

    2009-10-13

    Hydrogen peroxide and other reactive oxygen species are intimately involved in endothelial cell signaling. In many cell types, the AMP-activated protein kinase (AMPK) has been implicated in the control of metabolic responses, but the role of endothelial cell redox signaling in the modulation of AMPK remains to be completely defined. We used RNA interference and pharmacological methods to establish that H(2)O(2) is a critical activator of AMPK in cultured bovine aortic endothelial cells (BAECs). H(2)O(2) treatment of BAECs rapidly and significantly increases the phosphorylation of AMPK. The EC(50) for H(2)O(2)-promoted phosphorylation of AMPK is 65 + or - 15 microM, within the physiological range of cellular H(2)O(2) concentrations. The Ca(2+)/calmodulin-dependent protein kinase kinase-beta (CaMKKbeta) inhibitor STO-609 abolishes H(2)O(2)-dependent AMPK activation, whereas eNOS inhibitors enhance AMPK activation. Similarly, siRNA-mediated knockdown of CaMKKbeta abrogates AMPK activation, whereas siRNA-mediated knockdown of eNOS leads to a striking increase in AMPK phosphorylation. Cellular imaging studies using the H(2)O(2) biosensor HyPer show that siRNA-mediated eNOS knockdown leads to a marked increase in intracellular H(2)O(2) generation, which is blocked by PEG-catalase. eNOS(-/-) mice show a marked increase in AMPK phosphorylation in liver and lung compared to wild-type mice. Lung endothelial cells from eNOS(-/-) mice also show a significant increase in AMPK phosphorylation. Taken together, these results establish that CaMKKbeta is critically involved in mediating the phosphorylation of AMPK promoted by H(2)O(2) in endothelial cells, and document that eNOS is an important negative regulator of AMPK phosphorylation and intracellular H(2)O(2) generation in endothelial cells. PMID:19805165

  12. Endothelial nitric oxide synthase negatively regulates hydrogen peroxide-stimulated AMP-activated protein kinase in endothelial cells

    PubMed Central

    Jin, Benjamin Y.; Sartoretto, Juliano L.; Gladyshev, Vadim N.; Michel, Thomas

    2009-01-01

    Hydrogen peroxide and other reactive oxygen species are intimately involved in endothelial cell signaling. In many cell types, the AMP-activated protein kinase (AMPK) has been implicated in the control of metabolic responses, but the role of endothelial cell redox signaling in the modulation of AMPK remains to be completely defined. We used RNA interference and pharmacological methods to establish that H2O2 is a critical activator of AMPK in cultured bovine aortic endothelial cells (BAECs). H2O2 treatment of BAECs rapidly and significantly increases the phosphorylation of AMPK. The EC50 for H2O2-promoted phosphorylation of AMPK is 65 ± 15 μM, within the physiological range of cellular H2O2 concentrations. The Ca2+/calmodulin-dependent protein kinase kinase-β (CaMKKβ) inhibitor STO-609 abolishes H2O2-dependent AMPK activation, whereas eNOS inhibitors enhance AMPK activation. Similarly, siRNA-mediated knockdown of CaMKKβ abrogates AMPK activation, whereas siRNA-mediated knockdown of eNOS leads to a striking increase in AMPK phosphorylation. Cellular imaging studies using the H2O2 biosensor HyPer show that siRNA-mediated eNOS knockdown leads to a marked increase in intracellular H2O2 generation, which is blocked by PEG-catalase. eNOS−/− mice show a marked increase in AMPK phosphorylation in liver and lung compared to wild-type mice. Lung endothelial cells from eNOS−/− mice also show a significant increase in AMPK phosphorylation. Taken together, these results establish that CaMKKβ is critically involved in mediating the phosphorylation of AMPK promoted by H2O2 in endothelial cells, and document that eNOS is an important negative regulator of AMPK phosphorylation and intracellular H2O2 generation in endothelial cells. PMID:19805165

  13. Angle-resolved intensity and energy distributions of positive and negative hydrogen ions released from tungsten surface by molecular hydrogen ion impact

    NASA Astrophysics Data System (ADS)

    Kato, S.; Tanaka, N.; Sasao, M.; Kisaki, M.; Tsumori, K.; Nishiura, M.; Matsumoto, Y.; Kenmotsu, T.; Wada, M.; Yamaoka, H.

    2015-08-01

    Hydrogen ion reflection properties have been investigated following the injection of H+, H2+ and H3+ ions onto a polycrystalline W surface. Angle- and energy-resolved intensity distributions of both scattered H+ and H- ions are measured by a magnetic momentum analyzer. We have detected atomic hydrogen ions reflected from the surface, while molecular hydrogen ions are unobserved within our detection limit. The reflected hydrogen ion energy is approximately less than one-third of the incident beam energy for H3+ ion injection and less than a half of that for H2+ ion injection. Other reflection properties are very similar to those of monoatomic H+ ion injection. Experimental results are compared to the classical trajectory simulations using the ACAT code based on the binary collision approximation.

  14. Negative ion source development for fusion application (invited).

    PubMed

    Takeiri, Yasuhiko

    2010-02-01

    Giant negative ion sources, producing high-current of several tens amps with high energy of several hundreds keV to 1 MeV, are required for a neutral beam injector (NBI) in a fusion device. The giant negative ion sources are cesium-seeded plasma sources, in which the negative ions are produced on the cesium-covered surface. Their characteristic features are discussed with the views of large-volume plasma production, large-area beam acceleration, and high-voltage dc holding. The international thermonuclear experimental reactor NBI employs a 1 MeV-40 A of deuterium negative ion source, and intensive development programs for the rf-driven source plasma production and the multistage electrostatic acceleration are in progress, including the long pulse operation for 3600 s. Present status of the development, as well as the achievements of the giant negative ion sources in the working injectors, is also summarized. PMID:20192420

  15. Negative ion source development for fusion application (invited)

    SciTech Connect

    Takeiri, Yasuhiko

    2010-02-15

    Giant negative ion sources, producing high-current of several tens amps with high energy of several hundreds keV to 1 MeV, are required for a neutral beam injector (NBI) in a fusion device. The giant negative ion sources are cesium-seeded plasma sources, in which the negative ions are produced on the cesium-covered surface. Their characteristic features are discussed with the views of large-volume plasma production, large-area beam acceleration, and high-voltage dc holding. The international thermonuclear experimental reactor NBI employs a 1 MeV-40 A of deuterium negative ion source, and intensive development programs for the rf-driven source plasma production and the multistage electrostatic acceleration are in progress, including the long pulse operation for 3600 s. Present status of the development, as well as the achievements of the giant negative ion sources in the working injectors, is also summarized.

  16. Femtosecond Hydrogen Bond Dynamics of Bulk-like and Bound Water at Positively and Negatively Charged Lipid Interfaces Revealed by 2D HD-VSFG Spectroscopy.

    PubMed

    Singh, Prashant Chandra; Inoue, Ken-Ichi; Nihonyanagi, Satoshi; Yamaguchi, Shoichi; Tahara, Tahei

    2016-08-26

    Interfacial water in the vicinity of lipids plays an important role in many biological processes, such as drug delivery, ion transportation, and lipid fusion. Hence, molecular-level elucidation of the properties of water at lipid interfaces is of the utmost importance. We report the two-dimensional heterodyne-detected vibrational sum frequency generation (2D HD-VSFG) study of the OH stretch of HOD at charged lipid interfaces, which shows that the hydrogen bond dynamics of interfacial water differ drastically, depending on the lipids. The data indicate that the spectral diffusion of the OH stretch at a positively charged lipid interface is dominated by the ultrafast (<∼100 fs) component, followed by the minor sub-picosecond slow dynamics, while the dynamics at a negatively charged lipid interface exhibit sub-picosecond dynamics almost exclusively, implying that fast hydrogen bond fluctuation is prohibited. These results reveal that the ultrafast hydrogen bond dynamics at the positively charged lipid-water interface are attributable to the bulk-like property of interfacial water, whereas the slow dynamics at the negatively charged lipid interface are due to bound water, which is hydrogen-bonded to the hydrophilic head group. PMID:27482947

  17. Recombination and dissociative recombination of H/sub 2//sup +/ and H/sub 3//sup +/ ions on surfaces with application to hydrogen negative ion sources

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.

    1988-12-01

    A four-step model for recombination and dissociative recombination of H/sub 2//sup +/ and H/sub 3//sup +/ ions on metal surfaces is discussed. Vibrationally excited molecules, H/sub 2/(v''), from H/sub 3//sup +/ recombination are produced in a broad spectrum that enhances the excited level distribution. The application of this latter process to hydrogen negative ion discharges is discussed. 5 refs., 3 figs., 1 tab.

  18. On the meniscus formation and the negative hydrogen ion extraction from ITER neutral beam injection relevant ion source

    NASA Astrophysics Data System (ADS)

    Mochalskyy, S.; Wünderlich, D.; Ruf, B.; Fantz, U.; Franzen, P.; Minea, T.

    2014-10-01

    The development of a large area (Asource,ITER = 0.9 × 2 m2) hydrogen negative ion (NI) source constitutes a crucial step in construction of the neutral beam injectors of the international fusion reactor ITER. To understand the plasma behaviour in the boundary layer close to the extraction system the 3D PIC MCC code ONIX is exploited. Direct cross checked analysis of the simulation and experimental results from the ITER-relevant BATMAN source testbed with a smaller area (Asource,BATMAN ≈ 0.32 × 0.59 m2) has been conducted for a low perveance beam, but for a full set of plasma parameters available. ONIX has been partially benchmarked by comparison to the results obtained using the commercial particle tracing code for positive ion extraction KOBRA3D. Very good agreement has been found in terms of meniscus position and its shape for simulations of different plasma densities. The influence of the initial plasma composition on the final meniscus structure was then investigated for NIs. As expected from the Child-Langmuir law, the results show that not only does the extraction potential play a crucial role on the meniscus formation, but also the initial plasma density and its electronegativity. For the given parameters, the calculated meniscus locates a few mm downstream of the plasma grid aperture provoking a direct NI extraction. Most of the surface produced NIs do not reach the plasma bulk, but move directly towards the extraction grid guided by the extraction field. Even for artificially increased electronegativity of the bulk plasma the extracted NI current from this region is low. This observation indicates a high relevance of the direct NI extraction. These calculations show that the extracted NI current from the bulk region is low even if a complete ion-ion plasma is assumed, meaning that direct extraction from surface produced ions should be present in order to obtain sufficiently high extracted NI current density. The calculated extracted currents, both ions

  19. Negative ion-driven associated particle neutron generator

    DOE PAGESBeta

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in eithermore » pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.« less

  20. Negative ion-driven associated particle neutron generator

    SciTech Connect

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2015-10-09

    We describe an associated particle neutron generator that employs a negative ion source to produce high neutron flux from a small source size. Furthermore, negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). Finally, the neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to similar to 108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  1. Negative ion-driven associated particle neutron generator

    NASA Astrophysics Data System (ADS)

    Antolak, A. J.; Leung, K. N.; Morse, D. H.; Donovan, D. C.; Chames, J. M.; Whaley, J. A.; Buchenauer, D. A.; Chen, A. X.; Hausladen, P. A.; Liang, F.

    2016-01-01

    An associated particle neutron generator is described that employs a negative ion source to produce high neutron flux from a small source size. Negative ions produced in an rf-driven plasma source are extracted through a small aperture to form a beam which bombards a positively biased, high voltage target electrode. Electrons co-extracted with the negative ions are removed by a permanent magnet electron filter. The use of negative ions enables high neutron output (100% atomic ion beam), high quality imaging (small neutron source size), and reliable operation (no high voltage breakdowns). The neutron generator can operate in either pulsed or continuous-wave (cw) mode and has been demonstrated to produce 106 D-D n/s (equivalent to ~108 D-T n/s) from a 1 mm-diameter neutron source size to facilitate high fidelity associated particle imaging.

  2. Small radio frequency driven multicusp ion source for positive hydrogen ion beam production

    SciTech Connect

    Perkins, L.T.; Herz, P.R.; Leung, K.N.; Pickard, D.S. )

    1994-04-01

    A compact, 2.5 cm diam rf-driven multicusp ion source has been developed and tested for H[sup +] ion production in pulse mode operation. The source is optimized for atomic hydrogen ion species and extractable current. It is found that hydrogen ion beam current densities in excess of 650 mA/cm[sup 2] can be achieved with H[sup +] species above 80%. The geometry and position of the porcelain-coated copper antenna were found to be of great significance in relation to the efficiency of the ion source.

  3. A spin-Seebeck diode with a negative differential spin-Seebeck effect in a hydrogen-terminated zigzag silicene nanoribbon heterojunction.

    PubMed

    Fu, Hua-Hua; Gu, Lei; Wu, Dan-Dan

    2016-05-14

    The spin-Seebeck effect (SSE), the central topic of spin caloritronics, provides a new direction for future low power consumption technology. To realize device applications of SSE, a spin-Seebeck diode (SSD) with a negative differential SSE is very desirable. To this end, we constructed a spin caloritronics device that was composed of a ferromagnetic double-single-hydrogen-terminated zigzag silicene nanoribbon (ZSiNR-H2-H) and an antiferromagnetic double-double-hydrogen-terminated zigzag silicene nanoribbon (ZSiNR-H2-H2). By using ab initio calculations combined with nonequilibrium Green's function technique, we found that thermally driven spin current through the heterojunction featured the SSD effect and negative differential SSE. The former originates from the asymmetrical thermal-driven conducting electrons and holes, and the latter ascribes to the thermal spin compensation effect. Their physical mechanisms are much different from the previous ones mainly relying on the spin-wave excitations in the interface between metals and magnetic insulators, supporting our study that puts forward a new route to realize the SSD with a negative differential SSE. PMID:27098900

  4. Negative-ion production on carbon materials in hydrogen plasma: influence of the carbon hybridization state and the hydrogen content on H- yield

    NASA Astrophysics Data System (ADS)

    Ahmad, Ahmad; Pardanaud, Cédric; Carrère, Marcel; Layet, Jean-Marc; Gicquel, Alix; Kumar, Pravin; Eon, David; Jaoul, Cédric; Engeln, Richard; Cartry, Gilles

    2014-02-01

    Highly oriented polycrystalline graphite (HOPG), boron-doped diamond (BDD), nanocrystalline diamond, ultra-nanocrystalline diamond and diamond-like carbon surfaces are exposed to low-pressure hydrogen plasma in a 13.56 MHz plasma reactor. Relative yields of surface-produced H- ions due to bombardment of positive ions from the plasma are measured by an energy analyser cum quadrupole mass spectrometer. Irrespective of plasma conditions (0.2 and 2 Pa), HOPG surfaces show the highest yield at room temperature (RT), while at high temperature (HT), the highest yield (˜3-5 times compared to HOPG surface at RT) is observed on BDD surfaces. The shapes of ion distribution functions are compared at RT and HT to demonstrate the mechanism of ion generation at the surface. Raman spectroscopy analyses of the plasma-exposed samples reveal surface modifications influencing H- production yields, while further analyses strongly suggest that the hydrogen content of the material and the sp3/sp2 ratio are the key parameters in driving the surface ionization efficiency of carbon materials under the chosen plasma conditions.

  5. Doppler shift measurement of Balmer-alpha line spectrum emission from a plasma in a negative hydrogen ion source

    SciTech Connect

    Wada, M. Doi, K.; Kisaki, M.; Nakano, H.; Tsumori, K.; Nishiura, M.

    2015-04-08

    Balmer-α light emission from the extraction region of the LHD one-third ion source has shown a characteristic Doppler broadening in the wavelength spectrum detected by a high resolution spectrometer. The spectrum resembles Gaussian distribution near the wavelength of the intensity peak, while it has an additional component of a broader foot. The measured broadening near the wavelength of the intensity peak corresponds to 0.6 eV hydrogen atom temperature. The spectrum exhibits a larger expansion in the blue wing which becomes smaller when the line of sight is tilted toward the driver region from the original observation axis parallel to the plasma grid. A surface collision simulation model predicts the possibility of hydrogen reflection at the plasma grid surface to form a broad Balmer-α light emission spectrum.

  6. Negative ion production by backscattering from alkali-metal surfaces bombarded by ions of hydrogen and deuterium

    SciTech Connect

    Schneider, P.J.

    1980-03-01

    Measurements have been made of the total backscattered D/sup -/ and H/sup -/ yields from thick, clean targets of Cs, Rb, K, Na, and Li, bombarded with H/sub 2//sup +/, H/sub 3//sup +/, D/sub 2//sup +/, and D/sub 3//sup +/ with incident energies from 0.15 to 4.0 keV/nucleus. All of the measurements were made at background pressures less than 10/sup -9/ Torr and the alkali-metal targets were evaporated onto a cold substrate (T = 77K) in situ to assure thick, uncontaminated targets. Measurements of the H/sup -/ yield from various transition metal targets with thin coverages of alkali-metals have also been made as a function of the surface work function. The negative ion yields are discussed in terms of the probabilities of reflection of the incident particles, of formation of the negative ion at the surface and of the survival of the negative ion leaving the surface. For each thick alkali-metal target, the negative ion yield measurements have been used in a least squares fit to determine two parameters in a theoretically derived expression for the negative ion yield. The parameters obtained from a thick Na target have been used to calculate the yield from a Cu target with thin coverage of Na (such that the surface work function is equal to thick Na).

  7. Negative-ion yield in low-pressure radio frequency discharges in hydrogen: Particle modeling and vibrational kinetics

    SciTech Connect

    Diomede, P.; Longo, S.; Capitelli, M.

    2006-03-15

    A theoretical study of the complex interplay between the vibrational kinetics and the plasma dynamics in low-pressure hydrogen plasmas produced by radio frequency discharges is performed. The study is realized by means of a one-dimensional particle model with five species (e, H{sup +}, H{sub 2}{sup +}, H{sub 3}{sup +}, and H{sup -}) while the vibrational/dissociation kinetics is based on a continuum model and the two are self-consistently coupled. In particular, we analyze the influence of pressure.

  8. H{sup -} beam extraction from a cesium seeded field effect transistor based radio frequency negative hydrogen ion source

    SciTech Connect

    Ando, A.; Matsuno, T.; Funaoi, T.; Tanaka, N.; Tsumori, K.; Takeiri, Y.

    2012-02-15

    H{sup -} beam was successfully extracted from a cesium seeded ion source operated using a field effect transistor inverter power supply as a radio frequency (RF) wave source. High density hydrogen plasma more than 10{sup 19} m{sup -3} was obtained using an external type antenna with RF frequency of lower than 0.5 MHz. The source was isolated by an isolation transformer and H{sup -} ion beam was extracted from a single aperture. Acceleration current and extraction current increased with the increase of extraction voltage. Addition of a small amount of cesium vapor into the source enhanced the currents.

  9. Doubly excited {sup 1,3}P{sup e} resonance states of helium and the hydrogen negative ion interacting with Coulomb and screened Coulomb potentials

    SciTech Connect

    Kar, Sabyasachi; Ho, Y. K.

    2011-04-15

    We have investigated the doubly excited {sup 1,3}P{sup e} resonance states of helium and the hydrogen negative ion interacting with Coulomb and screened Coulomb potentials using exponential correlated wave functions. In the pure Coulomb case, calculations have been carried out by using the complex-coordinate rotation and the stabilization method. The {sup 1}P{sup e} resonance states of He below the N= 3, 4, and 5 thresholds of He{sup +}, and the {sup 3}P{sup e} resonance states of He below the N= 3 thresholds of He{sup +}, are reported. The 5p{sup 2} {sup 3}P{sup e} state, which has attracted recent interest, is also reported and discussed. In the screened Coulomb case, we have used the stabilization method to obtain two different series (3pnp and 3dnd) of resonance states below the N= 3 He{sup +} threshold as a function of the screening parameters. Resonance widths for the 3dnd series show some interesting behaviors. The resonance parameters (position and width) for helium and the hydrogen negation ion as functions of the screening parameters are reported.

  10. Negative ion surface production on carbon materials in hydrogen plasma: a thermodesorption analysis of carbon surface states

    NASA Astrophysics Data System (ADS)

    Cartry, Gilles; Achkasov, Kostiantyn; Pardanaud, Cédric; Layet, Jean-Marc; Simonin, Alain; Gicquel, Alix; Saidi, Othmen; Bisson, Régis; Angot, Thierry; PIIM Collaboration; IRFM Collaboration; LSPM Collaboration

    2014-10-01

    Negative ion surface production in plasmas has been studied in the context of fusion where H-surface production in cesium-seeded plasmas is of a primary interest for neutral beam injection devices. Although surface production is much lower in Cs-free plasmas, it may be non-negligible. Indeed it has been observed that significant numbers of H-ions can be created on a graphite surface upon positive ion bombardment in H2 plasmas. Graphite material has been compared to a large variety of diamond layers, in particular poly-crystalline boron-doped and non-doped diamond thin films. It has been shown an enhancement of the negative-ion yield by a factor 5 for diamond materials at high temperature, while the yield continuously decreases for graphite. The difference is due to the different properties of the pristine materials but also to the modifications bring by the plasma to the materials during exposure. In order to study in detail these modifications, plasma exposed samples have been analyzed by Raman spectroscopy and Temperature Programmed Desorption (TPD). These diagnostics helped to trace the surface state changes of the materials and identify the reasons for the elevated negative ion production at high temperature on diamonds.

  11. Preparation of hydrogenated diamond-like carbon films by reactive Ar/CH4 high power impulse magnetron sputtering with negative pulse voltage

    NASA Astrophysics Data System (ADS)

    Kimura, Takashi; Kamata, Hikaru

    2015-09-01

    High power impulse magnetron sputtering (HiPIMS) has been attracted, because sputtered target species are highly ionized. High densities of active species such as radical ions and neutral radicals can be also achieved owing to high density reactive HiPIMS plasmas. We investigate properties of hydrogenated diamond-like carbon films prepared by reactive HiPIMS of Ar/CH4 gas mixture. The properties of the films strongly depend on the plasma compositions and the kinetic energy of the carbon-containing ions which can enter into the films. The film preparation is performed at an average power of 60 W and a repetition frequency of 110 Hz, changing CH4 fraction up to 15%. Total pressure ranges between 0.3 and 2 Pa. The maximum of instantaneous power is about 20-25 kW, and the magnitude of the current is 36 A. A negative pulse voltage is applied to the substrates for about 10 μs after the target voltage changed from about -600 V to 0 V. The structural properties are characterized by Raman spectroscopy and nano-indentation method. Film hardness strongly depends on the magnitude of negative pulse voltage. By adjusting the magnitude of negative voltage, the film hardness ranges between about 10 and 22 GPa. This work is partially supported by JSPS KAKENHI Grant Number 26420230.

  12. Hydrogen negative ion production in a 14 GHz electron cyclotron resonance compact ion source with a cone-shaped magnetic filter.

    PubMed

    Ichikawa, T; Kasuya, T; Kenmotsu, T; Maeno, S; Nishiura, M; Shimozuma, T; Yamaoka, H; Wada, M

    2014-02-01

    The plasma electrode structure of a 14 GHz ECR ion source was modified to enlarge the plasma volume of low electron temperature region. The result shows that the extracted beam current reached about 0.6 mA/cm(2) with about 40 W microwave power. To investigate the correlation between the volume of the low electron temperature region and the H(-) current, a vacuum ultraviolet (VUV) spectrometer had been installed to observe light emission in the VUV wavelength range from the plasma. From the results of the negative ion beam current and that from VUV spectrometry, production rate of vibrationally excited hydrogen molecule seems to be enhanced by increasing the volume of low electron temperature region. PMID:24593572

  13. Development of the front end test stand and vessel for extraction and source plasma analyses negative hydrogen ion sources at the Rutherford Appleton Laboratory

    SciTech Connect

    Lawrie, S. R.; Faircloth, D. C.; Letchford, A. P.; Perkins, M.; Whitehead, M. O.; Wood, T.; Gabor, C.; Back, J.

    2014-02-15

    The ISIS pulsed spallation neutron and muon facility at the Rutherford Appleton Laboratory (RAL) in the UK uses a Penning surface plasma negative hydrogen ion source. Upgrade options for the ISIS accelerator system demand a higher current, lower emittance beam with longer pulse lengths from the injector. The Front End Test Stand is being constructed at RAL to meet the upgrade requirements using a modified ISIS ion source. A new 10% duty cycle 25 kV pulsed extraction power supply has been commissioned and the first meter of 3 MeV radio frequency quadrupole has been delivered. Simultaneously, a Vessel for Extraction and Source Plasma Analyses is under construction in a new laboratory at RAL. The detailed measurements of the plasma and extracted beam characteristics will allow a radical overhaul of the transport optics, potentially yielding a simpler source configuration with greater output and lifetime.

  14. Hydrogen negative ion production in a 14 GHz electron cyclotron resonance compact ion source with a cone-shaped magnetic filter

    SciTech Connect

    Ichikawa, T.; Kasuya, T.; Wada, M.; Kenmotsu, T.; Maeno, S.; Nishiura, M.; Shimozuma, T.; Yamaoka, H.

    2014-02-15

    The plasma electrode structure of a 14 GHz ECR ion source was modified to enlarge the plasma volume of low electron temperature region. The result shows that the extracted beam current reached about 0.6 mA/cm{sup 2} with about 40 W microwave power. To investigate the correlation between the volume of the low electron temperature region and the H{sup −} current, a vacuum ultraviolet (VUV) spectrometer had been installed to observe light emission in the VUV wavelength range from the plasma. From the results of the negative ion beam current and that from VUV spectrometry, production rate of vibrationally excited hydrogen molecule seems to be enhanced by increasing the volume of low electron temperature region.

  15. Negative ion source with external RF antenna

    DOEpatents

    Leung, Ka-Ngo; Hahto, Sami K.; Hahto, Sari T.

    2007-02-13

    A radio frequency (RF) driven plasma ion source has an external RF antenna, i.e. the RF antenna is positioned outside the plasma generating chamber rather than inside. The RF antenna is typically formed of a small diameter metal tube coated with an insulator. An external RF antenna assembly is used to mount the external RF antenna to the ion source. The RF antenna tubing is wound around the external RF antenna assembly to form a coil. The external RF antenna assembly is formed of a material, e.g. quartz, which is essentially transparent to the RF waves. The external RF antenna assembly is attached to and forms a part of the plasma source chamber so that the RF waves emitted by the RF antenna enter into the inside of the plasma chamber and ionize a gas contained therein. The plasma ion source is typically a multi-cusp ion source. A converter can be included in the ion source to produce negative ions.

  16. Influence of electrolyte composition and temperature on behaviour of AB5 hydrogen storage alloy used as negative electrode in Ni-MH batteries

    NASA Astrophysics Data System (ADS)

    Karwowska, Malgorzata; Jaron, Tomasz; Fijalkowski, Karol J.; Leszczynski, Piotr J.; Rogulski, Zbigniew; Czerwinski, Andrzej

    2014-10-01

    The AB5-type metal alloy (Mm-Ni4.1Al0.2Mn0.4Co0.45) has been investigated in different electrolytes (LiOH, NaOH, KOH, RbOH, CsOH). All of the electrochemical measurements have been performed using limited volume electrode technique (LVE). Thickness of the working electrode is nearly equal to the diameter of the grain (ca. 50 μm). Hydrogen diffusion coefficient has been determined using chronoamperometry. Hydrogen diffusion coefficient calculated for 100% state of charge reaches maximum value in KOH (DH = 4.65·10-10 cm2 s-1). We have obtained the highest value of capacity for the electrode in KOH and the lowest - in CsOH. The temperature influence on alloy capacity has been also tested. The alloy has been also characterised with SEM coupled with EDS, TGA/DSC and powder XRD. The unit cell of MmNi4.1Al0.2Mn0.4Co0.45 have been refined in the Cu5.4Yb0.8 structure type (a modified LaNi5 structure); the structure is unaffected by the electrochemical treatment.

  17. Negative mass

    NASA Astrophysics Data System (ADS)

    Hammond, Richard T.

    2015-03-01

    Some physical aspects of negative mass are examined. Several unusual properties, such as the ability of negative mass to penetrate any armor, are analysed. Other surprising effects include the bizarre system of negative mass chasing positive mass, naked singularities and the violation of cosmic censorship, wormholes, and quantum mechanical results as well. In addition, a brief look into the implications for strings is given.

  18. Sensitivity of RF-driven Plasma Filaments to Trace Gases

    NASA Astrophysics Data System (ADS)

    Burin, M. J.; Czarnocki, C. J.; Czarnocki, K.; Zweben, S. J.; Zwicker, A.

    2011-10-01

    Filamentary structures have been observed in many types of plasma discharges in both natural (e.g. lightning) and industrial systems (e.g. dielectric barrier discharges). Recent progress has been made in characterizing these structures, though various aspects of their essential physics remain unclear. A common example of this phenomenon can be found within a toy plasma globe (or plasma ball), wherein a primarily neon gas mixture near atmospheric pressure clearly and aesthetically displays filamentation. Recent work has provided the first characterization of these plasma globe filaments [Campanell et al., Physics of Plasmas 2010], where it was noticed that discharges of pure gases tend not to produce filaments. We have extended this initial work to investigate in greater detail the dependence of trace gases on filamentation within a primarily Neon discharge. Our preliminary results using a custom globe apparatus will be presented, along with some discussion of voltage dependencies. Newly supported by the NSF/DOE Partnership in Basic Plasma Science and Engineering.

  19. Negative Electron Affinity Mechanism for Diamond Surfaces

    NASA Technical Reports Server (NTRS)

    Krainsky, I. L.; Asnin, V. M.

    1998-01-01

    The energy distribution of the secondary electrons for chemical vacuum deposited diamond films with Negative Electron Affinity (NEA) was investigated. It was found that while for completely hydrogenated diamond surfaces the negative electron affinity peak in the energy spectrum of the secondary electrons is present for any energy of the primary electrons, for partially hydrogenated diamond surfaces there is a critical energy above which the peak is present in the spectrum. This critical energy increases sharply when hydrogen coverage of the diamond surface diminishes. This effect was explained by the change of the NEA from the true type for the completely hydrogenated surface to the effective type for the partially hydrogenated surfaces.

  20. Improvements of the magnetic field design for SPIDER and MITICA negative ion beam sources

    SciTech Connect

    Chitarin, G.; Agostinetti, P.; Aprile, D.; Marconato, N.; Veltri, P.

    2015-04-08

    The design of the magnetic field configuration in the SPIDER and MITICA negative ion beam sources has evolved considerably during the past four years. This evolution was driven by three factors: 1) the experimental results of the large RF-driven ion sources at IPP, which have provided valuable indications on the optimal magnetic configurations for reliable RF plasma source operation and for large negative ion current extraction, 2) the comprehensive beam optics and heat load simulations, which showed that the magnetic field configuration in the accelerator is crucial for keeping the heat load due to electrons on the accelerator grids within tolerable limits, without compromising the optics of the negative ion beam in the foreseen operating scenarios, 3) the progress of the detailed mechanical design of the accelerator, which stimulated the evaluation of different solutions for the correction of beamlet deflections of various origin and for beamlet aiming. On this basis, new requirements and solution concepts for the magnetic field configuration in the SPIDER and MITICA beam sources have been progressively introduced and updated until the design converged. The paper presents how these concepts have been integrated into a final design solution based on a horizontal “long-range” field (few mT) in combination with a “local” vertical field of some tens of mT on the acceleration grids.

  1. Improvements of the magnetic field design for SPIDER and MITICA negative ion beam sources

    NASA Astrophysics Data System (ADS)

    Chitarin, G.; Agostinetti, P.; Aprile, D.; Marconato, N.; Veltri, P.

    2015-04-01

    The design of the magnetic field configuration in the SPIDER and MITICA negative ion beam sources has evolved considerably during the past four years. This evolution was driven by three factors: 1) the experimental results of the large RF-driven ion sources at IPP, which have provided valuable indications on the optimal magnetic configurations for reliable RF plasma source operation and for large negative ion current extraction, 2) the comprehensive beam optics and heat load simulations, which showed that the magnetic field configuration in the accelerator is crucial for keeping the heat load due to electrons on the accelerator grids within tolerable limits, without compromising the optics of the negative ion beam in the foreseen operating scenarios, 3) the progress of the detailed mechanical design of the accelerator, which stimulated the evaluation of different solutions for the correction of beamlet deflections of various origin and for beamlet aiming. On this basis, new requirements and solution concepts for the magnetic field configuration in the SPIDER and MITICA beam sources have been progressively introduced and updated until the design converged. The paper presents how these concepts have been integrated into a final design solution based on a horizontal "long-range" field (few mT) in combination with a "local" vertical field of some tens of mT on the acceleration grids.

  2. Cesium in hydrogen negative-ion sources

    SciTech Connect

    Belchenko, Yu.I.; Davydenko, V.I.

    2006-03-15

    Experimental data on the dynamics of cesium particles in the pulsed magnetron and Penning surface-plasma ion sources are presented. Cesium escape from the source emission apertures and the cesium ion current to discharge electrodes was measured. The low value of cesium flux from the source was detected. An intense cesium ion current to the cathode (up to 0.8 A/cm{sup 2}) was measured. The high value of cesium ion current to surface-plasma source cathode confirms the cesium circulation near the cathode.

  3. Negative hydrogen ion sources for accelerators

    SciTech Connect

    Moehs, D.P.; Peters, J.; Sherman, J.; /Los Alamos

    2005-08-01

    A variety of H{sup -} ion sources are in use at accelerator laboratories around the world. A list of these ion sources includes surface plasma sources with magnetron, Penning and surface converter geometries as well as magnetic-multipole volume sources with and without cesium. Just as varied is the means of igniting and maintaining magnetically confined plasmas. Hot and cold cathodes, radio frequency, and microwave power are all in use, as well as electron tandem source ignition. The extraction systems of accelerator H{sup -} ion sources are highly specialized utilizing magnetic and electric fields in their low energy beam transport systems to produce direct current, as well as pulsed and/or chopped beams with a variety of time structures. Within this paper, specific ion sources utilized at accelerator laboratories shall be reviewed along with the physics of surface and volume H{sup -} production in regard to source emittance. Current research trends including aperture modeling, thermal modeling, surface conditioning, and laser diagnostics will also be discussed.

  4. Hydrogen production

    NASA Technical Reports Server (NTRS)

    England, C.; Chirivella, J. E.; Fujita, T.; Jeffe, R. E.; Lawson, D.; Manvi, R.

    1975-01-01

    The state of hydrogen production technology is evaluated. Specific areas discussed include: hydrogen production fossil fuels; coal gasification processes; electrolysis of water; thermochemical production of hydrogen; production of hydrogen by solar energy; and biological production of hydrogen. Supply options are considered along with costs of hydrogen production.

  5. An experimental study of waveguide coupled microwave heating with conventional multicusp negative ion sources

    SciTech Connect

    Komppula, J.; Kalvas, T.; Koivisto, H.; Laulainen, J.; Tarvainen, O.

    2015-04-08

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RF-driven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H{sup −} ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  6. Hydrogen sensor

    DOEpatents

    Duan, Yixiang; Jia, Quanxi; Cao, Wenqing

    2010-11-23

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  7. Hydrogenation apparatus

    DOEpatents

    Friedman, Joseph [Encino, CA; Oberg, Carl L [Canoga Park, CA; Russell, Larry H [Agoura, CA

    1981-01-01

    Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

  8. Hydrogen trapping and the interaction of hydrogen with metals

    NASA Technical Reports Server (NTRS)

    Danford, Merlin D.

    1987-01-01

    A method has been developed for the determination of trapped hydrogen in metal alloys, involving the determination of mobile hydrogen using the electrochemical method and the determination of total hydrogen with the fusion method, the difference in hydrogen concentrations being due to trapped hydrogen. It has been found that hydrogen enters body-centered cubic structures through the grain bodies rather than through the grain boundaries. Hydrogen also diffuses much more rapidly in body-centered cubic structures on charging than in face-centered cubic structures, the hydrogen distribution being more uniform in nature. The energy necessary to cause hydrogen embrittlement is postulated to arise from the changes in crystal lattice energies brought about through interaction of hydrogen with atoms in the metal lattice. The total energy change is more negative for body-centered cubic structures, believed to be the cause of a greater tendency toward hydrogen embrittlement. Finally, the agreement of hydrogen concentrations obtained at 25 C by the electrochemical method with those obtained by the fusion method are taken as a strong indication of the power and validity of the electrochemical method.

  9. Hydrogen Production

    SciTech Connect

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  10. Hydrogenation apparatus

    DOEpatents

    Friedman, J.; Oberg, C. L.; Russell, L. H.

    1981-06-23

    Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

  11. Hydrogen Generator

    NASA Technical Reports Server (NTRS)

    1978-01-01

    Another spinoff from spacecraft fuel cell technology is the portable hydrogen generator shown. Developed by General Electric Company, it is an aid to safer operation of systems that use hydrogen-for example, gas chromatographs, used in laboratory analysis of gases. or flame ionization detectors used as $ollution monitors. The generator eliminates the need for high-pressure hydrogen storage bottles, which can be a safety hazard, in laboratories, hospitals and industrial plants. The unit supplies high-purity hydrogen by means of an electrochemical process which separates the hydrogen and oxygen in distilled water. The oxygen is vented away and the hydrogen gas is stored within the unit for use as needed. GE's Aircraft Equipment Division is producing about 1,000 of the generators annually.

  12. Hydrogen Bibliography

    SciTech Connect

    Not Available

    1991-12-01

    The Hydrogen Bibliography is a compilation of research reports that are the result of research funded over the last fifteen years. In addition, other documents have been added. All cited reports are contained in the National Renewable Energy Laboratory (NREL) Hydrogen Program Library.

  13. Hydrogen energy.

    PubMed

    Edwards, P P; Kuznetsov, V L; David, W I F

    2007-04-15

    The problem of anthropogenically driven climate change and its inextricable link to our global society's present and future energy needs are arguably the greatest challenge facing our planet. Hydrogen is now widely regarded as one key element of a potential energy solution for the twenty-first century, capable of assisting in issues of environmental emissions, sustainability and energy security. Hydrogen has the potential to provide for energy in transportation, distributed heat and power generation and energy storage systems with little or no impact on the environment, both locally and globally. However, any transition from a carbon-based (fossil fuel) energy system to a hydrogen-based economy involves significant scientific, technological and socio-economic barriers. This brief report aims to outline the basis of the growing worldwide interest in hydrogen energy and examines some of the important issues relating to the future development of hydrogen as an energy vector. PMID:17272235

  14. Meningitis - gram-negative

    MedlinePlus

    Gram-negative meningitis ... Acute bacterial meningitis can be caused by Gram-negative bacteria. Meningococcal and H. influenzae meningitis are caused by Gram-negative bacteria and are covered in detail in other articles. This article ...

  15. Cesium injection system for negative ion duoplasmatrons

    DOEpatents

    Kobayashi, Maasaki; Prelec, Krsto; Sluyters, Theodorus J

    1978-01-01

    Longitudinally extending, foraminous cartridge means having a cylindrical side wall forming one flat, circular, tip end surface and an opposite end; an open-ended cavity, and uniformly spaced orifices for venting the cavity through the side wall in the annulus of a plasma ring for uniformly ejecting cesium for coating the flat, circular, surface. To this end, the cavity is filled with a cesium containing substance and attached to a heater in a hollow-discharge duoplasmatron. By coating the flat circular surface with a uniform monolayer of cesium and locating it in an electrical potential well at the end of a hollow-discharge, ion duoplasmatron source of an annular hydrogen plasma ring, the negative hydrogen production from the duoplasmatron is increased. The negative hydrogen is produced on the flat surface of the cartridge and extracted by the electrical potential well along a trajectory coaxial with the axis of the plasma ring.

  16. Atomic wall recombination and volume negative ion production

    SciTech Connect

    Pagano, Damiano; Gorse, Claudine; Capitelli, Mario

    2006-03-15

    The development of a numerical code for the modeling of negative ion sources requires the knowledge of a lot of processes occurring both in the gas phase and at the surface. The present work concerns the effect of surface processes (in particular atomic wall recombination) on the kinetics of production/destruction of negative ions. Especially in the pressure regimes useful to produce negative hydrogen ions for thermonuclear applications, wall processes can strongly affect the negative ion production acting on the vibrational distribution of molecular hydrogen.

  17. Hydrogen Effect against Hydrogen Embrittlement

    NASA Astrophysics Data System (ADS)

    Murakami, Yukitaka; Kanezaki, Toshihiko; Mine, Yoji

    2010-10-01

    The well-known term “hydrogen embrittlement” (HE) expresses undesirable effects due to hydrogen such as loss of ductility, decreased fracture toughness, and degradation of fatigue properties of metals. However, this article shows, surprisingly, that hydrogen can have an effect against HE. A dramatic phenomenon was found in which charging a supersaturated level of hydrogen into specimens of austenitic stainless steels of types 304 and 316L drastically improved the fatigue crack growth resistance, rather than accelerating fatigue crack growth rates. Although this mysterious phenomenon has not previously been observed in the history of HE research, its mechanism can be understood as an interaction between hydrogen and dislocations. Hydrogen can play two roles in terms of dislocation mobility: pinning (or dragging) and enhancement of mobility. Competition between these two roles determines whether the resulting phenomenon is damaging or, unexpectedly, desirable. This finding will, not only be the crucial key factor to elucidate the mechanism of HE, but also be a trigger to review all existing theories on HE in which hydrogen is regarded as a dangerous culprit.

  18. Storing Hydrogen

    SciTech Connect

    Kim, Hyun Jeong; Karkamkar, Abhijeet J.; Autrey, Thomas; Chupas, Peter; Proffen, Thomas E.

    2010-05-31

    Researchers have been studying mesoporous materials for almost two decades with a view to using them as hosts for small molecules and scaffolds for molding organic compounds into new hybrid materials and nanoparticles. Their use as potential storage systems for large quantities of hydrogen has also been mooted. Such systems that might hold large quantities of hydrogen safely and in a very compact volume would have enormous potential for powering fuel cell vehicles, for instance. A sponge-like form of silicon dioxide, the stuff of sand particles and computer chips, can soak up and store other compounds including hydrogen. Studies carried out at the XOR/BESSRC 11-ID-B beamline at the APS have revealed that the nanoscopic properties of the hydrogenrich compound ammonia borane help it store hydrogen more efficiently than usual. The material may have potential for addressing the storage issues associated with a future hydrogen economy. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. Hydrogen program overview

    SciTech Connect

    Gronich, S.

    1997-12-31

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  20. Negative-ion states

    SciTech Connect

    Compton, R.N.

    1982-01-01

    In this brief review, we discuss some of the properties of atomic and molecular negative ions and their excited states. Experiments involving photon reactions with negative ions and polar dissociation are summarized. 116 references, 14 figures.

  1. Volume production of negative ions in the reflex-type ion source

    SciTech Connect

    Jimbo, K.

    1982-06-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion source. The extracted negative hydrogen currents of 9.7 mA (100 mA/cm/sup 2/) for H/sup -/ and of 4.1 mA(42 mA/cm/sup 2/) for D/sup -/ are obtained continuously. The impurity is less than 1%. An isotope effect of negative ion production is observed.

  2. Negative ion generator

    DOEpatents

    Stinnett, R.W.

    1984-05-08

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions. 8 figs.

  3. Negative ion generator

    DOEpatents

    Stinnett, Regan W.

    1984-01-01

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions.

  4. [Negative symptoms: which antipsychotics?].

    PubMed

    Maurel, M; Belzeaux, R; Adida, M; Azorin, J-M

    2015-12-01

    Treating negative symptoms of schizophrenia is a major issue and a challenge for the functional and social prognosis of the disease, to which they are closely linked. First- and second-generation antipsychotics allow a reduction of all negative symptoms. The hope of acting directly on primary negative symptoms with any antipsychotic is not supported by the literature. However, the effectiveness of first- and second-generation antipsychotics is demonstrated on secondary negative symptoms. PMID:26776390

  5. Sentential Negation in English

    ERIC Educational Resources Information Center

    Mowarin, Macaulay

    2009-01-01

    This paper undertakes a detailed analysis of sentential negation in the English language with Chomsky's Government-Binding theory of Transformational Grammar as theoretical model. It distinguishes between constituent and sentential negation in English. The essay identifies the exact position of Negation phrase in an English clause structure. It…

  6. Hydrogen chloride

    Integrated Risk Information System (IRIS)

    Hydrogen chloride ; CASRN 7647 - 01 - 0 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogeni

  7. Hydrogen sulfide

    Integrated Risk Information System (IRIS)

    Hydrogen sulfide ; 7783 - 06 - 4 Human health assessment information on a chemical substance is included in the IRIS database only after a comprehensive review of toxicity data , as outlined in the IRIS assessment development process . Sections I ( Health Hazard Assessments for Noncarcinogenic Effec

  8. Electrochemical Hydrogen Peroxide Generator

    NASA Technical Reports Server (NTRS)

    Tennakoon, Charles L. K.; Singh, Waheguru; Anderson, Kelvin C.

    2010-01-01

    Two-electron reduction of oxygen to produce hydrogen peroxide is a much researched topic. Most of the work has been done in the production of hydrogen peroxide in basic media, in order to address the needs of the pulp and paper industry. However, peroxides under alkaline conditions show poor stabilities and are not useful in disinfection applications. There is a need to design electrocatalysts that are stable and provide good current and energy efficiencies to produce hydrogen peroxide under acidic conditions. The innovation focuses on the in situ generation of hydrogen peroxide using an electrochemical cell having a gas diffusion electrode as the cathode (electrode connected to the negative pole of the power supply) and a platinized titanium anode. The cathode and anode compartments are separated by a readily available cation-exchange membrane (Nafion 117). The anode compartment is fed with deionized water. Generation of oxygen is the anode reaction. Protons from the anode compartment are transferred across the cation-exchange membrane to the cathode compartment by electrostatic attraction towards the negatively charged electrode. The cathode compartment is fed with oxygen. Here, hydrogen peroxide is generated by the reduction of oxygen. Water may also be generated in the cathode. A small amount of water is also transported across the membrane along with hydrated protons transported across the membrane. Generally, each proton is hydrated with 3-5 molecules. The process is unique because hydrogen peroxide is formed as a high-purity aqueous solution. Since there are no hazardous chemicals or liquids used in the process, the disinfection product can be applied directly to water, before entering a water filtration unit to disinfect the incoming water and to prevent the build up of heterotrophic bacteria, for example, in carbon based filters. The competitive advantages of this process are: 1. No consumable chemicals are needed in the process. The only raw materials

  9. Metallic Hydrogen

    NASA Astrophysics Data System (ADS)

    Silvera, Isaac; Zaghoo, Mohamed; Salamat, Ashkan

    2015-03-01

    Hydrogen is the simplest and most abundant element in the Universe. At high pressure it is predicted to transform to a metal with remarkable properties: room temperature superconductivity, a metastable metal at ambient conditions, and a revolutionary rocket propellant. Both theory and experiment have been challenged for almost 80 years to determine its condensed matter phase diagram, in particular the insulator-metal transition. Hydrogen is predicted to dissociate to a liquid atomic metal at multi-megabar pressures and T =0 K, or at megabar pressures and very high temperatures. Thus, its predicted phase diagram has a broad field of liquid metallic hydrogen at high pressure, with temperatures ranging from thousands of degrees to zero Kelvin. In a bench top experiment using static compression in a diamond anvil cell and pulsed laser heating, we have conducted measurements on dense hydrogen in the region of 1.1-1.7 Mbar and up to 2200 K. We observe a first-order phase transition in the liquid phase, as well as sharp changes in optical transmission and reflectivity when this phase is entered. The optical signature is that of a metal. The mapping of the phase line of this transition is in excellent agreement with recent theoretical predictions for the long-sought plasma phase transition to metallic hydrogen. Research supported by the NSF, Grant DMR-1308641, the DOE Stockpile Stewardship Academic Alliance Program, Grant DE-FG52-10NA29656, and NASA Earth and Space Science Fellowship Program, Award NNX14AP17H.

  10. Hydrogen environment embrittlement.

    NASA Technical Reports Server (NTRS)

    Gray, H. R.

    1972-01-01

    Hydrogen embrittlement is classified into three types: internal reversible hydrogen embrittlement, hydrogen reaction embrittlement, and hydrogen environment embrittlement. Characteristics of and materials embrittled by these types of hydrogen embrittlement are discussed. Hydrogen environment embrittlement is reviewed in detail. Factors involved in standardizing test methods for detecting the occurrence of and evaluating the severity of hydrogen environment embrittlement are considered. The effects of test technique, hydrogen pressure, purity, strain rate, stress concentration factor, and test temperature are discussed.

  11. Negative Ion Density Fronts

    SciTech Connect

    Igor Kaganovich

    2000-12-18

    Negative ions tend to stratify in electronegative plasmas with hot electrons (electron temperature Te much larger than ion temperature Ti, Te > Ti ). The boundary separating a plasma containing negative ions, and a plasma, without negative ions, is usually thin, so that the negative ion density falls rapidly to zero-forming a negative ion density front. We review theoretical, experimental and numerical results giving the spatio-temporal evolution of negative ion density fronts during plasma ignition, the steady state, and extinction (afterglow). During plasma ignition, negative ion fronts are the result of the break of smooth plasma density profiles during nonlinear convection. In a steady-state plasma, the fronts are boundary layers with steepening of ion density profiles due to nonlinear convection also. But during plasma extinction, the ion fronts are of a completely different nature. Negative ions diffuse freely in the plasma core (no convection), whereas the negative ion front propagates towards the chamber walls with a nearly constant velocity. The concept of fronts turns out to be very effective in analysis of plasma density profile evolution in strongly non-isothermal plasmas.

  12. Hydrogen scavengers

    SciTech Connect

    Carroll, David W.; Salazar, Kenneth V.; Trkula, Mitchell; Sandoval, Cynthia W.

    2002-01-01

    There has been invented a codeposition process for fabricating hydrogen scavengers. First, a .pi.-bonded allylic organometallic complex is prepared by reacting an allylic transition metal halide with an organic ligand complexed with an alkali metal; and then, in a second step, a vapor of the .pi.-bonded allylic organometallic complex is combined with the vapor of an acetylenic compound, irradiated with UV light, and codeposited on a substrate.

  13. The addiction to negativity.

    PubMed

    Lane, R C; Hull, J W; Foehrenbach, L M

    1991-01-01

    In this paper, we have described a type of resistance that has attracted increasing psychoanalytic attention in recent years. Patients exposed to intense negativity during early life may develop an addiction to negative experience as adolescents and adults, and this may constitute a central organizing feature of their personality. In almost all patients, however, some moments of negativity may be observed. We have traced the developmental origins of an attachment to negativity, drawing especially on psychoanalytic investigations of preoedipal pathology. Manifestations and derivatives of early negativity include anhedonia, attachment to physical pain, fear of success, masochism, deprivation of self and others, and negative voyeurism. In discussing the dynamic functions of negativity, we place particular emphasis on two motives: the patient's desires for revenge against early objects that have been a source of deprivation and frustration; and the defensive function of negativity in helping to express as well as ward off dangerous wishes to merge with the object. Deviant forms of autoerotism are likely to be used by these patients to deal with the reactivation of early experiences of neglect and rejection. When negativity is used as a defense or method of relating to others it can lead to a severe disruption of the psychotherapeutic relationship. We have reviewed suggestions for the management of extreme negativity in treatment. Resolution of the therapist's countertransference reactions, especially induced feelings of frustration, rage, and helplessness, is crucial. Emphasis also has been placed on the patient's desires for revenge against self and object, and the manner in which these may be understood and eventually resolved. Only when patient and therapist begin to investigate the adaptive functions of extreme negativity can this pathological symptom be resolved and the patient's awareness of self and sense of autonomy be enhanced. PMID:1763149

  14. The Evolution of Negation.

    ERIC Educational Resources Information Center

    Croft, William

    1991-01-01

    Discusses a method for extrapolation of diachronic processes from synchronic states, the dynamicization of synchronic typologies, to propose a hitherto unobserved historical source for markers of verbal negation, namely irregular negative existential predicate forms. Explanations are proposed for the occurrence of the attested processes in this…

  15. Learning from Negative Morality.

    ERIC Educational Resources Information Center

    Oser, Fritz K.

    1996-01-01

    Identifies and discusses the elements and applications of learning from negative morality. Negative morality refers to the experience of learning from mistakes thereby creating a body of personal knowledge about "what not to do." This knowledge not only protects individuals but steers them to the right behavior. (MJP)

  16. Hydrogen environment embrittlement

    NASA Technical Reports Server (NTRS)

    Gray, H. R.

    1972-01-01

    Hydrogen embrittlement is classified into three types: internal reversible hydrogen embrittlement, hydrogen reaction embrittlement, and hydrogen environment embrittlement. Characteristics of and materials embrittled by these types of hydrogen embrittlement are discussed. Hydrogen environment embrittlement is reviewed in detail. Factors involved in standardizing test methods for detecting the occurrence of and evaluating the severity of hydrogen environment embrittlement are considered. The effect of test technique, hydrogen pressure, purity, strain rate, stress concentration factor, and test temperature are discussed. Additional research is required to determine whether hydrogen environment embrittlement and internal reversible hydrogen embrittlement are similar or distinct types of embrittlement.

  17. On Negative Mass

    NASA Astrophysics Data System (ADS)

    Belletête, Jonathan; Paranjape, M. B.

    2013-06-01

    The Schwarzschild solution to the matter free, spherically symmetric Einstein equations has one free parameter, the mass. But the mass can be of any sign. What is the meaning of the negative mass solutions? The answer to this question for the case of a pure Schwarzschild negative mass black solution is still elusive, however, in this essay, we will consider negative mass solutions within a Schwarzschild-de Sitter geometry. We show that there exist reasonable configurations of matter, bubbles of distributions of matter, that satisfy the dominant energy condition everywhere, that are nonsingular and well behaved everywhere, but correspond to the negative mass Schwarzschild-de Sitter geometry outside the matter distribution. These negative mass bubbles could occur as the end state of a quantum tunneling transition.

  18. RF-driven ion source with a back-streaming electron dump

    DOEpatents

    Kwan, Joe; Ji, Qing

    2014-05-20

    A novel ion source is described having an improved lifetime. The ion source, in one embodiment, is a proton source, including an external RF antenna mounted to an RF window. To prevent backstreaming electrons formed in the beam column from striking the RF window, a back streaming electron dump is provided, which in one embodiment is formed of a cylindrical tube, open at one end to the ion source chamber and capped at its other end by a metal plug. The plug, maintained at the same electrical potential as the source, captures these backstreaming electrons, and thus prevents localized heating of the window, which due to said heating, might otherwise cause window damage.

  19. RF driven sulfur lamp having driving electrodes which face each other

    DOEpatents

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  20. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOEpatents

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  1. RF driven sulfur lamp having driving electrodes which face each other

    DOEpatents

    Gabor, George; Orr, Thomas Robert; Greene, Charles Maurice; Crawford, Douglas Gordon; Berman, Samuel Maurice

    1999-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  2. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOEpatents

    Gabor, George; Orr, Thomas Robert; Greene, Charles Maurice; Crawford, Douglas Gordon; Berman, Samuel Maurice

    1998-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  3. The injection of microorganisms into an atmospheric pressure rf-driven microplasma

    NASA Astrophysics Data System (ADS)

    Maguire, P. D.; Mahony, C. M. O.; Diver, D.; Mariotti, D.; Bennet, E.; Potts, H.; McDowell, D. A.

    2013-09-01

    The introduction of living organisms, such as bacteria, into atmospheric pressure microplasmas offers a unique means to study certain physical mechanisms in individual microorganisms and also help understand the impact of macroscopic entities and liquid droplets on plasma characteristics. We present the characterization of an RF-APD operating at 13.56 MHz and containing microorganisms in liquid droplets emitted from a nebulizer, with the spray entrained in a gas flow by a gas shroud and passed into the plasma source. We report successful microorganism injection and transmission through the plasma with stable plasma operation of at least one hour. Diagnostics include RF electrical characterization, optical emission spectrometry and electrostatic deflection to investigate microorganism charging. A close-coupled Impedans Octiv VI probe indicates source efficiencies of 10 to 15%. The introduction of the droplets/microorganisms results in increased plasma conductivity and reduced capacitance, due to their impact on electron density and temperature. An electrical model will be presented based on diagnostic data and deflection studies with input from simulations of charged aerosol diffusion and evaporation. Engineering and Physical Sciences Research Council EP/K006088, EP/K006142.

  4. Application of a pulsed, RF-driven, multicusp source for low energy plasma immersion ion implantation

    SciTech Connect

    Wengrow, A.B.; Leung, K.N.; Perkins, L.T.; Pickard, D.S.; Rickard, M.; Williams, M.D.; Tucker, M.

    1996-06-01

    The multicusp ion source can produce large volumes of uniform, quiescent, high density plasmas. A plasma chamber suited for plasma immersion ion implantation (PIII) was readily made. Conventional PIII pulses the bias voltage applied to the substrate which is immersed in a CW mode plasma. Here, a method by which the plasma itself is pulsed was developed. Typically pulse lengths of 500 {mu}s are used and are much shorter than that of the substrate voltage pulse (5-15 ms). This approach, together with low gas pressures and low bias voltages, permits the constant energy implantation of an entire wafer simultaneously without glow discharge. Results show that this process can yield implant currents of up to 2.5 mA/cm{sup 2}; thus very short implant times can be achieved. Uniformity of the ion flux is also discussed. As this method can be scaled to any dimension, it can be made to handle any size wafer.

  5. Simulations of the GEC rf-driven plasma reactor with He

    SciTech Connect

    Riley, M.E.; Drallos, P.; McGrath, R.

    1992-12-01

    The authors have developed a model of the electronic processes occuring in a He plasma entailing 12 electronic transitions, 5 levels (some composite), and trapped radiative decay of certain states. Along with surface scattering conditions, momentum transfer, charge transfer, and diffusion, these processes are incorporated into a 1D-2V electron Boltzmann equation (BE) code with time evolution alternating between BE and fluid equations (FE) dynamics. The FE electronic rates are obtained periodically from the BE. The ions and neutrals are completely FE. The BE-FE hybrid works well, enabling a study of the plasma and reaction kinetics to near steady state of the actual laboratory system.

  6. ADX: A high Power Density, Advanced RF-Driven Divertor Test Tokamak for PMI studies

    NASA Astrophysics Data System (ADS)

    Whyte, Dennis; ADX Team

    2015-11-01

    The MIT PSFC and collaborators are proposing an advanced divertor experiment, ADX; a divertor test tokamak dedicated to address critical gaps in plasma-material interactions (PMI) science, and the world fusion research program, on the pathway to FNSF/DEMO. Basic ADX design features are motivated and discussed. In order to assess the widest range of advanced divertor concepts, a large fraction (>50%) of the toroidal field volume is purpose-built with innovative magnetic topology control and flexibility for assessing different surfaces, including liquids. ADX features high B-field (>6 Tesla) and high global power density (P/S ~ 1.5 MW/m2) in order to access the full range of parallel heat flux and divertor plasma pressures foreseen for reactors, while simultaneously assessing the effect of highly dissipative divertors on core plasma/pedestal. Various options for efficiently achieving high field are being assessed including the use of Alcator technology (cryogenic cooled copper) and high-temperature superconductors. The experimental platform would also explore advanced lower hybrid current drive and ion-cyclotron range of frequency actuators located at the high-field side; a location which is predicted to greatly reduce the PMI effects on the launcher while minimally perturbing the core plasma. The synergistic effects of high-field launchers with high total B on current and flow drive can thus be studied in reactor-relevant boundary plasmas.

  7. RUI: Structure and Behavior of RF-Driven Plasma Filaments in High-Pressure Gases

    SciTech Connect

    Burin, Michael

    2014-11-18

    The filamentary discharge seen within commercial plasma globes is commonly enjoyed, yet not well understood. We investigate filament properties in a plasma globe using a variable high voltage amplifier. Results from the 3-year grant period and their physics are discussed.

  8. Hydrogen detector

    DOEpatents

    Kanegae, Naomichi; Ikemoto, Ichiro

    1980-01-01

    A hydrogen detector of the type in which the interior of the detector is partitioned by a metal membrane into a fluid section and a vacuum section. Two units of the metal membrane are provided and vacuum pipes are provided independently in connection to the respective units of the metal membrane. One of the vacuum pipes is connected to a vacuum gauge for static equilibrium operation while the other vacuum pipe is connected to an ion pump or a set of an ion pump and a vacuum gauge both designed for dynamic equilibrium operation.

  9. Kriging without negative weights

    SciTech Connect

    Szidarovszky, F.; Baafi, E.Y.; Kim, Y.C.

    1987-08-01

    Under a constant drift, the linear kriging estimator is considered as a weighted average of n available sample values. Kriging weights are determined such that the estimator is unbiased and optimal. To meet these requirements, negative kriging weights are sometimes found. Use of negative weights can produce negative block grades, which makes no practical sense. In some applications, all kriging weights may be required to be nonnegative. In this paper, a derivation of a set of nonlinear equations with the nonnegative constraint is presented. A numerical algorithm also is developed for the solution of the new set of kriging equations.

  10. Negative birefringent polyimide films

    NASA Technical Reports Server (NTRS)

    Harris, Frank W. (Inventor); Cheng, Stephen Z. D. (Inventor)

    1994-01-01

    A negative birefringent film, useful in liquid crystal displays, and a method for controlling the negative birefringence of a polyimide film is disclosed which allows the matching of an application to a targeted amount of birefringence by controlling the degree of in-plane orientation of the polyimide by the selection of functional groups within both the diamine and dianhydride segments of the polyimide which affect the polyimide backbone chain rigidity, linearity, and symmetry. The higher the rigidity, linearity and symmetry of the polyimide backbone, the larger the value of the negative birefringence of the polyimide film.

  11. Evaluation of negative ion distribution changes by image processing diagnostic

    SciTech Connect

    Ikeda, K. Nakano, H.; Tsumori, K.; Kisaki, M.; Nagaoka, K.; Tokuzawa, T.; Osakabe, M.; Takeiri, Y.; Kaneko, O.; Geng, S.

    2015-04-08

    Distributions of hydrogen Balmer-α (H{sub α}) intensity and its reduction behavior close to a plasma grid (PG) surface have been observed by a spectrally selective imaging system in an arc discharge type negative hydrogen ion source in National Institute for Fusion Science. H{sub α} reduction indicates a reduction of negative hydrogen ions because the mutual neutralization process between H{sup +} and H{sup −} ions causes the dominant excitation process for H{sub α} emission in the rich H{sup −} condition such as in ionic plasma. We observed a significant change in H{sub α} reduction distribution due to change in the bias voltage, which is used to suppress the electron influx. Small H{sub α} reduction in higher bias is likely because the production of negative ions is suppressed by the potential difference between the plasma and PG surface.

  12. Negative electrode composition

    DOEpatents

    Kaun, Thomas D.; Chilenskas, Albert A.

    1982-01-01

    A secondary electrochemical cell and a negative electrode composition for use therewith comprising a positive electrode containing an active material of a chalcogen or a transiton metal chalcogenide, a negative electrode containing a lithium-aluminum alloy and an amount of a ternary alloy sufficient to provide at least about 5 percent overcharge capacity relative to a negative electrode solely of the lithium-aluminum alloy, the ternary alloy comprising lithium, aluminum, and iron or cobalt, and an electrolyte containing lithium ions in contact with both of the positive and the negative electrodes. The ternary alloy is present in the electrode in the range of from about 5 percent to about 50 percent by weight of the electrode composition and may include lithium-aluminum-nickel alloy in combination with either the ternary iron or cobalt alloys. A plurality of series connected cells having overcharge capacity can be equalized on the discharge side without expensive electrical equipment.

  13. Logo and Negative Numbers.

    ERIC Educational Resources Information Center

    Strawn, Candace A.

    1998-01-01

    Describes LOGO's turtle graphics capabilities based on a sixth-grade classroom's activities with negative numbers and Logo programming. A sidebar explains LOGO and offers suggestions to teachers for using LOGO effectively. (LRW)

  14. Atomic negative ions

    SciTech Connect

    Brage, T.

    1991-01-01

    We review some of the recent progress in the studies of alkaline-earth, negative ions. Computations of autodetachment rates, electron affinities and transition wavelengths are discussed and some new and improved results are given.

  15. Atomic negative ions

    SciTech Connect

    Brage, T.

    1991-12-31

    We review some of the recent progress in the studies of alkaline-earth, negative ions. Computations of autodetachment rates, electron affinities and transition wavelengths are discussed and some new and improved results are given.

  16. Negative affixes in medical English.

    PubMed

    Dzuganova, B

    2006-01-01

    Many medical terms have negative meaning expressed by means of a negative prefix or suffix. The most frequently used negative prefixes are: a-, dis-, in-, non-, and un-. There is only one negative suffix -less (Ref. 15). PMID:17125069

  17. Mechanochemical hydrogenation of coal

    DOEpatents

    Yang, Ralph T.; Smol, Robert; Farber, Gerald; Naphtali, Leonard M.

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  18. Hydrogen peroxide poisoning

    MedlinePlus

    ... peroxide is used in these products: Hydrogen peroxide Hair bleach Some contact lens cleaners Note: Household hydrogen peroxide ... it contains 97% water and 3% hydrogen peroxide. Hair bleaches are stronger. They usually have a concentration of ...

  19. Negative Halogen Ions for Fusion Applications

    SciTech Connect

    Grisham, L.R.; Kwan, J.W.; Hahto, S.K.; Hahto, S.T.; Leung, K.N.; Westenskow, G.

    2006-01-01

    Over the past quarter century, advances in hydrogen negative ion sources have extended the usable range of hydrogen isotope neutral beams to energies suitable for large magnetically confined fusion devices. Recently, drawing upon this experience, negative halogen ions have been proposed as an alternative to positive ions for heavy ion fusion drivers in inertial confinement fusion, because electron accumulation would be prevented in negative ion beams, and if desired, the beams could be photo-detached to neutrals. This paper reports the results of an experiment comparing the current density and beam emittance of Cl+ and Cl- extracted from substantially ion-ion plasmas with that of Ar+ extracted from an ordinary electron-ion plasma, all using the same source, extractor, and emittance scanner. At similar discharge conditions, the Cl- current was typically 85 – 90% of the positive chlorine current, with an e-/ Cl- ratio as low as seven without grid magnets. The Cl- was as much as 76% of the Ar+ current from a discharge with the same RF drive. The minimum normalized beam emittance and inferred ion temperatures of Cl+, Cl-, and Ar+ were all similar, so the current density and optical quality of Cl- appear as suitable for heavy ion fusion driver applications as a positive noble gas ion of similar mass. Since F, I, and Br should all behave similarly in an ion source, they should also be suitable as driver beams.

  20. Hydrogen Permeation Barrier Coatings

    SciTech Connect

    Henager, Charles H.

    2008-01-01

    Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

  1. Negative pressure wound therapy.

    PubMed

    Thompson, James T; Marks, Malcolm W

    2007-10-01

    Negative pressure wound therapy has become an increasingly important part of wound management. Over the last decade, numerous uses for this method of wound management have been reported, ranging from acute and chronic wounds, to closure of open sternal and abdominal wounds, to assistance with skin grafts. The biophysics behind the success of this treatment largely have focused on increased wound blood flow, increased granulation tissue formation, decreased bacterial counts, and stimulation of wound healing pathways through shear stress mechanisms. The overall success of negative pressure wound therapy has led to a multitude of clinical applications, which are discussed in this article. PMID:17967622

  2. Hydrogen embrittlement in nickel-hydrogen cells

    NASA Technical Reports Server (NTRS)

    Gross, Sidney

    1989-01-01

    It was long known that many strong metals can become weakened and brittle as the result of the accumulation of hydrogen within the metal. When the metal is stretched, it does not show normal ductile properties, but fractures prematurely. This problem can occur as the result of a hydrogen evolution reaction such as corrosion or electroplating, or due to hydrogen in the environment at the metal surface. High strength alloys such as steels are especially susceptible to hydrogen embrittlement. Nickel-hydrogen cells commonly use Inconel 718 alloy for the pressure container, and this also is susceptible to hydrogen embrittlement. Metals differ in their susceptibility to embrittlement. Hydrogen embrittlement in nickel-hydrogen cells is analyzed and the reasons why it may or may not occur are discussed. Although Inconel 718 can display hydrogen embrittlement, experience has not identified any problem with nickel-hydrogen cells. No hydrogen embrittlement problem is expected with the 718 alloy pressure container used in nickel-hydrogen cells.

  3. Extracted current saturation in negative ion sources

    SciTech Connect

    Mochalskyy, S.; Lifschitz, A. F.; Minea, T.

    2012-06-01

    The extraction of negatively charged particles from a negative ion source is one of the crucial issues in the development of the neutral beam injector system for future experimental reactor ITER. Full 3D electrostatic particle-in-cell Monte Carlo collision code - ONIX [S. Mochalskyy et al., Nucl. Fusion 50, 105011 (2010)] - is used to simulate the hydrogen plasma behaviour and the extracted particle features in the vicinity of the plasma grid, both sides of the aperture. It is found that the contribution to the extracted negative ion current of ions born in the volume is small compared with that of ions created at the plasma grid walls. The parametric study with respect to the rate of negative ions released from the walls shows an optimum rate. Beyond this optimum, a double layer builds-up by the negative ion charge density close to the grid aperture surface reducing thus extraction probability, and therefore the extracted current. The effect of the extraction potential and magnetic field magnitudes on the extraction is also discussed. Results are in good agreement with available experimental data.

  4. Charged particle flows in the beam extraction region of a negative ion source for NBI

    NASA Astrophysics Data System (ADS)

    Geng, S.; Tsumori, K.; Nakano, H.; Kisaki, M.; Ikeda, K.; Osakabe, M.; Nagaoka, K.; Takeiri, Y.; Shibuya, M.; Kaneko, O.

    2016-02-01

    Experiments by a four-pin probe and photodetachment technique were carried out to investigate the charged particle flows in the beam extraction region of a negative hydrogen ion source for neutral beam injector. Electron and positive ion flows were obtained from the polar distribution of the probe saturation current. Negative hydrogen ion flow velocity and temperature were obtained by comparing the recovery times of the photodetachment signals at opposite probe tips. Electron and positive ions flows are dominated by crossed field drift and ambipolar diffusion. Negative hydrogen ion temperature is evaluated to be 0.12 eV.

  5. Charged particle flows in the beam extraction region of a negative ion source for NBI.

    PubMed

    Geng, S; Tsumori, K; Nakano, H; Kisaki, M; Ikeda, K; Osakabe, M; Nagaoka, K; Takeiri, Y; Shibuya, M; Kaneko, O

    2016-02-01

    Experiments by a four-pin probe and photodetachment technique were carried out to investigate the charged particle flows in the beam extraction region of a negative hydrogen ion source for neutral beam injector. Electron and positive ion flows were obtained from the polar distribution of the probe saturation current. Negative hydrogen ion flow velocity and temperature were obtained by comparing the recovery times of the photodetachment signals at opposite probe tips. Electron and positive ions flows are dominated by crossed field drift and ambipolar diffusion. Negative hydrogen ion temperature is evaluated to be 0.12 eV. PMID:26931985

  6. The Negative Repetition Effect

    ERIC Educational Resources Information Center

    Mulligan, Neil W.; Peterson, Daniel J.

    2013-01-01

    A fundamental property of human memory is that repetition enhances memory. Peterson and Mulligan (2012) recently documented a surprising "negative repetition effect," in which participants who studied a list of cue-target pairs twice recalled fewer targets than a group who studied the pairs only once. Words within a pair rhymed, and…

  7. [Chemotherapies of negative schizophrenia].

    PubMed

    Petit, M; Dollfus, S

    1991-01-01

    Five years ago, Goldberg claimed that negative symptoms of schizophrenia do respond to neuroleptics. This apparent discovery is, in fact, a very common way of thinking for European schools of psychiatry, specially the French one guided by Delay and Deniker. Initially focused on reserpine and some alerting phenothiazines such as thioproperazine, this opinion has been extended to benzamides in the 1970s. The analysis of the publications devoted to this point indicates that several drugs are actually considered as potent disinhibitors (i.e. active on negative symptoms of schizophrenia): Phenothiazines: As shown in the controlled studies by Itil (1971), Poirier-Littré (1988), fluphenazine and pipotiazine improve the BPRS anergia factor and the SANS score. Butyrophenones: The first description of the "imipramine like" effect of trifluperidol by Janssen (1959) initiated the studies by Gallant (1960), Fox (1963). They compared trifluperidol at low doses versus haloperidol and chlorpromazine at medium and high doses, BPRS anergia factor improved only at low doses. Diphenylbutylpiperidines (DPBP): Meltzer's review (1986) concluded to the efficacy of such drugs on negative symptoms appearing as a specific biochemical relationship effect. A definite analysis about doses leads to a very different interpretation: DPBP low doses and only low doses improved negative symptoms as much as some low doses of phenothiazines. On the opposite, DPBP, phenothiazines and butyrophenones high doses are inefficient.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:1683624

  8. Physical applications of muon catalysis: Muon capture in hydrogen

    NASA Astrophysics Data System (ADS)

    Filchenkov, V. V.

    2016-07-01

    Results of theoretical and experimental research on capture of negative muons in hydrogen are reported with an emphasis on the accompanying phenomenon of muon catalysis in hydrogen and subtleties of the experimental method. A conclusion is drawn that precise determination of the capture rate is important for refining the standard model.

  9. Composition for absorbing hydrogen

    DOEpatents

    Heung, L.K.; Wicks, G.G.; Enz, G.L.

    1995-05-02

    A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  10. An independent hydrogen source

    SciTech Connect

    Kobzenko, G.F.; Chubenko, M.V.; Kobzenko, N.S.; Senkevich, A.I.; Shkola, A.A.

    1985-10-01

    Descriptions are given of the design and operation of an independent hydrogen source used in purifying and storing hydrogen. If LaNi/sub 5/ or TiFe is used as the sorbent, one can store about 500 liter of chemically bound hydrogen in a vessel of 0.9 liter. Molecular purification of the desorbed hydrogen is used. The IHS is a safe hydrogen source, since the hydrogen is trapped in the sorbent in the chemically bound state and in equilibrium with LaNi/sub 5/Hx at room temperature. If necessary, the IHS can serve as a compressor and provide higher hydrogen pressures. The device is compact and transportable.

  11. Composition for absorbing hydrogen

    DOEpatents

    Heung, Leung K.; Wicks, George G.; Enz, Glenn L.

    1995-01-01

    A hydrogen absorbing composition. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  12. Negative refraction and superconductivity

    NASA Astrophysics Data System (ADS)

    Amariti, Antonio; Forcella, Davide; Mariotti, Alberto; Siani, Massimo

    2011-10-01

    We discuss exotic properties of charged hydrodynamical systems, in the broken superconducting phase, probed by electromagnetic waves. Motivated by general arguments from hydrodynamics, we observe that negative refraction, namely the propagation in opposite directions of the phase velocities and of the energy flux, is expected for low enough frequencies. We corroborate this general idea by analyzing a holographic superconductor in the AdS/CFT correspondence, where the response functions can be explicitly computed. We study the dual gravitational theory both in the probe and in the backreacted case. We find that, while in the first case the refractive index is positive at every frequency, in the second case there is negative refraction at low enough frequencies. This is in agreement with hydrodynamic considerations.

  13. Think (Gram) negative!

    PubMed Central

    2010-01-01

    The increasing prevalence of multiresistant Gram-negative bacteria of the Enterobacteriaceae family in Europe is a worrisome phenomenon. Extended spectrum betalactamase-producing Escherichia coli strains are widespread in the community and are frequently imported into the hospital. Of even more concern is the spread of carbapenem-resistant strains of Klebsiella spp. from regions where they are already endemic. Antibiotic use is a main driver of antibiotic resistance, which again increases broad spectrum antibiotic use, resulting in a vicious circle that is difficult to interrupt. The present commentary highlights important findings of a surveillance study of antimicrobial use and resistance in German ICUs over 8 years with a focus on Gram-negative resistance. PMID:20587087

  14. Negative Emissions Technology

    NASA Astrophysics Data System (ADS)

    Day, Danny

    2006-04-01

    Although `negative emissions' of carbon dioxide need not, in principle, involve use of biological processes to draw carbon out of the atmosphere, such `agricultural' sequestration' is the only known way to remove carbon from the atmosphere on time scales comparable to the time scale for anthropogenic increases in carbon emissions. In order to maintain the `negative emissions' the biomass must be used in such a way that the resulting carbon dioxide is separated and permanently sequestered. Two options for sequestration are in the topsoil and via geologic carbon sequestration. The former has multiple benefits, but the latter also is needed. Thus, although geologic carbon sequestration is viewed skeptically by some environmentalists as simply a way to keep using fossil fuels---it may be a key part of reversing accelerating climate forcing if rapid climate change is beginning to occur. I will first review the general approach of agricultural sequestration combined with use of resulting biofuels in a way that permits carbon separation and then geologic sequestration as a negative emissions technology. Then I discuss the process that is the focus of my company---the EPRIDA cycle. If deployed at a sufficiently large scale, it could reverse the increase in CO2 concentrations. I also estimate of benefits --carbon and other---of large scale deployment of negative emissions technologies. For example, using the EPRIDA cycle by planting and soil sequestering carbon in an area abut In 3X the size of Texas would remove the amount of carbon that is being accumulated worldwide each year. In addition to the atmospheric carbon removal, the EPRIDA approach also counters the depletion of carbon in the soil---increasing topsoil and its fertility; reduces the excess nitrogen in the water by eliminating the need for ammonium nitrate fertilizer and reduces fossil fuel reliance by providing biofuel and avoiding natural gas based fertilizer production.

  15. The negative repetition effect.

    PubMed

    Mulligan, Neil W; Peterson, Daniel J

    2013-09-01

    A fundamental property of human memory is that repetition enhances memory. Peterson and Mulligan (2012) recently documented a surprising negative repetition effect, in which participants who studied a list of cue-target pairs twice recalled fewer targets than a group who studied the pairs only once. Words within a pair rhymed, and across pairs, the target words were drawn from a small set of categories. In the repetition condition, the pairs were initially presented in a random order and then presented a 2nd time blocked by the category of the target words. In the single presentation condition, the pairs were presented only in the blocked order. Participants in the former condition recalled fewer target words on a free recall test despite having seen the word pairs twice (the negative repetition effect). This phenomenon is explored in a series of 5 experiments assessing 3 theoretical accounts of the effect. The experiments demonstrate that the negative repetition effect generalizes over multiple encoding conditions (reading and generative encoding), over different memory tests (free and cued recall), and over delay (5 min and 2 days). The results argue against a retrieval account and a levels-of-processing account but are consistent with the item-specific-relational account, the account upon which the effect was initially predicated. PMID:23421508

  16. Hydrogen Embrittlement Understood

    NASA Astrophysics Data System (ADS)

    Robertson, Ian M.; Sofronis, P.; Nagao, A.; Martin, M. L.; Wang, S.; Gross, D. W.; Nygren, K. E.

    2015-06-01

    The connection between hydrogen-enhanced plasticity and the hydrogen-induced fracture mechanism and pathway is established through examination of the evolved microstructural state immediately beneath fracture surfaces including voids, "quasi-cleavage," and intergranular surfaces. This leads to a new understanding of hydrogen embrittlement in which hydrogen-enhanced plasticity processes accelerate the evolution of the microstructure, which establishes not only local high concentrations of hydrogen but also a local stress state. Together, these factors establish the fracture mechanism and pathway.

  17. A Few Facts about Hydrogen [and] Hydrogen Bibliography.

    ERIC Educational Resources Information Center

    Hinds, H. Roger

    Divided into two sections, this publication presents facts about and the characteristics of hydrogen and a bibliography on hydrogen. The first section lists nine facts on what hydrogen is, four on where hydrogen is found, nine on how hydrogen is used, nine on how hydrogen can be used, and 14 on how hydrogen is made. Also included are nine…

  18. Microstructures of negative and positive azeotropes.

    PubMed

    Shephard, J J; Callear, S K; Imberti, S; Evans, J S O; Salzmann, C G

    2016-07-28

    Azeotropes famously impose fundamental restrictions on distillation processes, yet their special thermodynamic properties make them highly desirable for a diverse range of industrial and technological applications. Using neutron diffraction, we investigate the structures of two prototypical azeotropes, the negative acetone-chloroform and the positive benzene-methanol azeotrope. C-HO hydrogen bonding is the dominating interaction in the negative azeotrope but C-ClO halogen bonding contributes as well. Hydrogen-bonded chains of methanol molecules, which are on average longer than in pure methanol, are the defining structural feature of the positive azeotrope illustrating the fundamentally different local mixing in the two kinds of azeotropes. The emerging trend for both azeotropes is that the more volatile components experience the more pronounced structural changes in their local environments as the azeotropes form. The mixing of the acetone-chloroform azeotrope is essentially random above 20 Å, where the running Kirkwood-Buff integrals of our structural model converge closely to the ones expected from thermodynamic data. The benzene-methanol azeotrope on the other hand displays extended methanol-rich regions and consequently the running Kirkwood-Buff integrals oscillate up to at least 60 Å. Our study provides the first experimental insights into the microstructures of azeotropes and a direct link with their thermodynamic properties. Ultimately, this will provide a route for creating tailored molecular environments in azeotropes to improve and fine-tune their performances. PMID:27367534

  19. Hydrogen nanobubble at normal hydrogen electrode

    NASA Astrophysics Data System (ADS)

    Nakabayashi, S.; Shinozaki, R.; Senda, Y.; Yoshikawa, H. Y.

    2013-05-01

    Electrochemically formed hydrogen nanobubbles at a platinum rotating disk electrode (RDE) were detected by re-oxidation charge. The dissolution time course of the hydrogen nanobubbles was measured by AFM tapping topography under open-circuit conditions at stationary platinum and gold single-crystal electrodes. The bubble dissolution at platinum was much faster than that at gold because two types of diffusion, bulk and surface diffusion, proceeded at the platinum surface, whereas surface diffusion was prohibited at the gold electrode. These findings indicated that the electrochemical reaction of normal hydrogen electrode partly proceeded heterogeneously on the three-phase boundary around the hydrogen nanobubble.

  20. Hydrogen energy systems studies

    SciTech Connect

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M.

    1996-10-01

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  1. Correlation of H/sup -/ production and the work function of a surface in a hydrogen plasma

    SciTech Connect

    Wada, M.

    1983-03-01

    Surface-plasma negative hydrogen ion sources are being developed as possible parts for future neutral beam systems. In these ion sources, negative hydrogen ions (H/sup -/) are produced at low work function metal surfaces immersed in hydrogen plasmas. To investigate the correlation between the work function and the H/sup -/ production at the surface with a condition similar to the one in the actual plasma ion source, these two parameters were simultaneously measured in the hydrogen plasma environment.

  2. Polarized negative ions

    SciTech Connect

    Haeberli, W.

    1981-04-01

    This paper presents a survey of methods, commonly in use or under development, to produce beams of polarized negative ions for injection into accelerators. A short summary recalls how the hyperfine interaction is used to obtain nuclear polarization in beams of atoms. Atomic-beam sources for light ions are discussed. If the best presently known techniques are incorporated in all stages of the source, polarized H/sup -/ and D/sup -/ beams in excess of 10 ..mu..A can probably be achieved. Production of polarized ions from fast (keV) beams of polarized atoms is treated separately for atoms in the H(25) excited state (Lamb-Shift source) and atoms in the H(1S) ground state. The negative ion beam from Lamb-Shift sources has reached a plateau just above 1 ..mu..A, but this beam current is adequate for many applications and the somewhat lower beam current is compensated by other desirable characteristics. Sources using fast polarized ground state atoms are in a stage of intense development. The next sections summarize production of polarized heavy ions by the atomic beam method, which is well established, and by optical pumping, which has recently been demonstrated to yield very large nuclear polarization. A short discussion of proposed ion sources for polarized /sup 3/He/sup -/ ions is followed by some concluding remarks.

  3. Concentration of Hydrogen Peroxide

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F. (Inventor)

    2006-01-01

    Methods for concentrating hydrogen peroxide solutions have been described. The methods utilize a polymeric membrane separating a hydrogen peroxide solution from a sweep gas or permeate. The membrane is selective to the permeability of water over the permeability of hydrogen peroxide, thereby facilitating the concentration of the hydrogen peroxide solution through the transport of water through the membrane to the permeate. By utilizing methods in accordance with the invention, hydrogen peroxide solutions of up to 85% by volume or higher may be generated at a point of use without storing substantial quantities of the highly concentrated solutions and without requiring temperatures that would produce explosive mixtures of hydrogen peroxide vapors.

  4. Application of anomalous diffusion in production of negative ions

    NASA Astrophysics Data System (ADS)

    Jimbo, Kouichi

    1984-11-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion sources. When anomalous diffusion in the positive column was found by Hoh and Lehnert [Phys. Fluids 3, 600 (1960)], it was pointed out that the large particle loss produced by anomalous diffusion is compensated for by the larger particle production inside the plasma. In the present experiments anomalous diffusion was artificially encouraged by changing the radial electric field inside the reflex discharge. Apparent encouragement of negative ion current by the increase of the density fluctuation amplitude is observed. Twice as much negative ion current was obtained with the artificial encouragement as without. On the other hand, the larger extracted negative ion current was observed with a lower electron temperature, which is calculated from the anomalous diffusion coefficient derived from a simple nonlinear theory. This result is consistent with Wadehra's calculated results [Appl. Phys. Lett. 35, 917 (1979)].

  5. Application of anomalous diffusion in production of negative ions

    SciTech Connect

    Jimbo, K.

    1984-11-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion sources. When anomalous diffusion in the positive column was found by Hoh and Lehnert (Phys. Fluids 3, 600 (1960)), it was pointed out that the large particle loss produced by anomalous diffusion is compensated for by the larger particle production inside the plasma. In the present experiments anomalous diffusion was artificially encouraged by changing the radial electric field inside the reflex discharge. Apparent encouragement of negative ion current by the increase of the density fluctuation amplitude is observed. Twice as much negative ion current was obtained with the artificial encouragement as without. On the other hand, the larger extracted negative ion current was observed with a lower electron temperature, which is calculated from the anomalous diffusion coefficient derived from a simple nonlinear theory. This result is consistent with Wadehra's calculated results (Appl. Phys. Lett. 35, 917 (1979)).

  6. Negative Entropy of Life

    NASA Astrophysics Data System (ADS)

    Goradia, Shantilal

    2015-10-01

    We modify Newtonian gravity to probabilistic quantum mechanical gravity to derive strong coupling. If this approach is valid, we should be able to extend it to the physical body (life) as follows. Using Boltzmann equation, we get the entropy of the universe (137) as if its reciprocal, the fine structure constant (ALPHA), is the hidden candidate representing the negative entropy of the universe which is indicative of the binary information as its basis (http://www.arXiv.org/pdf/physics0210040v5). Since ALPHA relates to cosmology, it must relate to molecular biology too, with the binary system as the fundamental source of information for the nucleotides of the DNA as implicit in the book by the author: ``Quantum Consciousness - The Road to Reality.'' We debate claims of anthropic principle based on the negligible variation of ALPHA and throw light on thermodynamics. We question constancy of G in multiple ways.

  7. Negative Optical Torque

    NASA Astrophysics Data System (ADS)

    Chen, Jun; Ng, Jack; Ding, Kun; Fung, Kin Hung; Lin, Zhifang; Chan, C. T.

    2014-09-01

    Light carries angular momentum, and as such it can exert torques on material objects. Applications of these opto-mechanical effects were limited initially due to their smallness in magnitude, but later becomes powerful and versatile after the invention of laser. Novel and practical approaches for harvesting light for particle rotation have since been demonstrated, where the structure is always subjected to a positive optical torque along a certain axis if the incident angular momentum has a positive projection on the same axis. We report here an interesting phenomenon of ``negative optical torque'', meaning that incoming photons carrying angular momentum rotate an object in the opposite sense. Surprisingly this can be realized quite straightforwardly in simple planar structures. Field retardation is a necessary condition and discrete rotational symmetry of material object plays an important role. The optimal conditions are explored and explained.

  8. Negative ion source

    DOEpatents

    Leung, K.N.; Ehlers, K.W.

    1982-08-06

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  9. Negative ion source

    DOEpatents

    Leung, K.N.; Ehlers, K.W.

    1984-12-04

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field. 14 figs.

  10. Negative ion source

    DOEpatents

    Leung, Ka-Ngo; Ehlers, Kenneth W.

    1984-01-01

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  11. Negative Optical Torque

    PubMed Central

    Chen, Jun; Ng, Jack; Ding, Kun; Fung, Kin Hung; Lin, Zhifang; Chan, C. T.

    2014-01-01

    Light carries angular momentum, and as such it can exert torques on material objects. Applications of these opto-mechanical effects were limited initially due to their smallness in magnitude, but later becomes powerful and versatile after the invention of laser. Novel and practical approaches for harvesting light for particle rotation have since been demonstrated, where the structure is always subjected to a positive optical torque along a certain axis if the incident angular momentum has a positive projection on the same axis. We report here an interesting phenomenon of “negative optical torque”, meaning that incoming photons carrying angular momentum rotate an object in the opposite sense. Surprisingly this can be realized quite straightforwardly in simple planar structures. Field retardation is a necessary condition and discrete rotational symmetry of material object plays an important role. The optimal conditions are explored and explained. PMID:25226863

  12. Do `negative' temperatures exist?

    NASA Astrophysics Data System (ADS)

    Lavenda, B. H.

    1999-06-01

    A modification of the second law is required for a system with a bounded density of states and not the introduction of a `negative' temperature scale. The ascending and descending branches of the entropy versus energy curve describe particle and hole states, having thermal equations of state that are given by the Fermi and logistic distributions, respectively. Conservation of energy requires isentropic states to be isothermal. The effect of adiabatically reversing the field is entirely mechanical because the only difference between the two states is their energies. The laws of large and small numbers, leading to the normal and Poisson approximations, characterize statistically the states of infinite and zero temperatures, respectively. Since the heat capacity also vanishes in the state of maximum disorder, the third law can be generalized in systems with a bounded density of states: the entropy tends to a constant as the temperature tends to either zero or infinity.

  13. Hydrogen transport membranes

    DOEpatents

    Mundschau, Michael V.

    2005-05-31

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  14. Hydrogen production by Cyanobacteria

    PubMed Central

    Dutta, Debajyoti; De, Debojyoti; Chaudhuri, Surabhi; Bhattacharya, Sanjoy K

    2005-01-01

    The limited fossil fuel prompts the prospecting of various unconventional energy sources to take over the traditional fossil fuel energy source. In this respect the use of hydrogen gas is an attractive alternate source. Attributed by its numerous advantages including those of environmentally clean, efficiency and renew ability, hydrogen gas is considered to be one of the most desired alternate. Cyanobacteria are highly promising microorganism for hydrogen production. In comparison to the traditional ways of hydrogen production (chemical, photoelectrical), Cyanobacterial hydrogen production is commercially viable. This review highlights the basic biology of cynobacterial hydrogen production, strains involved, large-scale hydrogen production and its future prospects. While integrating the existing knowledge and technology, much future improvement and progress is to be done before hydrogen is accepted as a commercial primary energy source. PMID:16371161

  15. Supply options. [hydrogen market

    NASA Technical Reports Server (NTRS)

    1975-01-01

    The use of captive hydrogen (produced and consumed on site) and merchant hydrogen (externally supplied) is considered. A low-merchant-captive ratio market and a high-merchant-captive ratio market are described and compared.

  16. 19. Print from copy negative (original glass plate negative in ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. Print from copy negative (original glass plate negative in Tippecanoe County Historical Society.) Original photo dated May 7, 1893. View north, south side. - Big Four Depot, 10 South Second Street, Lafayette, Tippecanoe County, IN

  17. Hydrogen Technologies Safety Guide

    SciTech Connect

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  18. Solar hydrogen generator

    NASA Technical Reports Server (NTRS)

    Sebacher, D. I.; Sabol, A. P. (Inventor)

    1977-01-01

    An apparatus, using solar energy to manufacture hydrogen by dissociating water molecules into hydrogen and oxygen molecules is described. Solar energy is concentrated on a globe containing water thereby heating the water to its dissociation temperature. The globe is pervious to hydrogen molecules permitting them to pass through the globe while being essentially impervious to oxygen molecules. The hydrogen molecules are collected after passing through the globe and the oxygen molecules are removed from the globe.

  19. Negative Expertise: Comparing Differently Tenured Elder Care Nurses' Negative Knowledge

    ERIC Educational Resources Information Center

    Gartmeier, Martin; Lehtinen, Erno; Gruber, Hans; Heid, Helmut

    2011-01-01

    Negative expertise is conceptualised as the professional's ability to avoid errors during practice due to certain cognitive agencies. In this study, negative knowledge (i.e. knowledge about what is wrong in a certain context and situation) is conceptualised as one such agency. This study compares and investigates the negative knowledge of elder…

  20. Sensitive hydrogen leak detector

    DOEpatents

    Myneni, G.R.

    1999-08-03

    A sensitive hydrogen leak detector system is described which uses passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor. 1 fig.

  1. Flash hydrogenation of coal

    DOEpatents

    Manowitz, Bernard; Steinberg, Meyer; Sheehan, Thomas V.; Winsche, Warren E.; Raseman, Chad J.

    1976-01-01

    A process for the hydrogenation of coal comprising the contacting of powdered coal with hydrogen in a rotating fluidized bed reactor. A rotating fluidized bed reactor suitable for use in this process is also disclosed. The coal residence time in the reactor is limited to less than 5 seconds while the hydrogen contact time is not in excess of 0.2 seconds.

  2. Biological hydrogen photoproduction

    SciTech Connect

    Nemoto, Y.

    1995-09-01

    Following are the major accomplishments of the 6th year`s study of biological hydrogen photoproduction which were supported by DOE/NREL. (1) We have been characterizing a biological hydrogen production system using synchronously growing aerobically nitrogen-fixing unicellular cyanobacterium, Synechococcus sp. Miami BG 043511. So far it was necessary to irradiate the cells to produce hydrogen. Under darkness they did not produce hydrogen. However, we found that, if the cells are incubated with oxygen, they produce hydrogen under the dark. Under 80% argon + 20% oxygen condition, the hydrogen production activity under the dark was about one third of that under the light + argon condition. (2) Also it was necessary so far to incubate the cells under argon atmosphere to produce hydrogen in this system. Argon treatment is very expensive and should be avoided in an actual hydrogen production system. We found that, if the cells are incubated at a high cell density and in a container with minimum headspace, it is not necessary to use argon for the hydrogen production. (3) Calcium ion was found to play an important role in the mechanisms of protection of nitrogenase from external oxygen. This will be a clue to understand the reason why the hydrogen production is so resistant to oxygen in this strain. (4) In this strain, sulfide can be used as electron donor for the hydrogen production. This result shows that waste water can be used for the hydrogen production system using this strain.

  3. Liquid metal hydrogen barriers

    DOEpatents

    Grover, George M.; Frank, Thurman G.; Keddy, Edward S.

    1976-01-01

    Hydrogen barriers which comprise liquid metals in which the solubility of hydrogen is low and which have good thermal conductivities at operating temperatures of interest. Such barriers are useful in nuclear fuel elements containing a metal hydride moderator which has a substantial hydrogen dissociation pressure at reactor operating temperatures.

  4. Sensitive hydrogen leak detector

    DOEpatents

    Myneni, Ganapati Rao

    1999-01-01

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  5. Hydrogen from coal

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Hydrogen production from coal by hydrogasification is described. The process involves the solubilization of coal to form coal liquids, which are hydrogasified to produce synthetic pipeline gas; steam reforming this synthetic gas by a nuclear heat source produces hydrogen. A description is given of the hydrogen plant, its performance, and its effect on the environment.

  6. Purification of Hydrogen

    DOEpatents

    Newton, A S

    1950-12-05

    Disclosed is a process for purifying hydrogen containing various gaseous impurities by passing the hydrogen over a large surface of uranium metal at a temperature above the decomposition temperature of uranium hydride, and below the decomposition temperature of the compounds formed by the combination of the uranium with the impurities in the hydrogen.

  7. In-situ infrared study of silicon in KOH electrolyte: Surface hydrogenation and hydrogen penetration

    NASA Astrophysics Data System (ADS)

    Philipsen, H. G. G.; Ozanam, F.; Allongue, P.; Kelly, J. J.; Chazalviel, J.-N.

    2016-02-01

    The n-Si(111)/6 M KOH electrolyte interface has been investigated by in-situ multiple-internal reflection infrared spectroscopy, at room temperature and at 40 °C. The potential of the Si electrode was stepped successively to positive and negative values with respect to open-circuit potential, leading to surface oxidation and oxide dissolution, respectively. Infrared spectra were recorded together with the interfacial current. Analysis of the infrared spectra indicates that, following the positive potential step, the electronic state of the surface changes from accumulation to inversion and the surface termination changes from a hydrogenated state to an oxidised state. The hydrogenated state is recovered after an induction time following the negative potential step. However, hydrogen penetration into the silicon lattice is then found to take place, as indicated by the appearance of a new SiH band and a strong background absorption of electronic origin. This sub-surface hydrogenation is associated with a slow increase of the interfacial current. This process is found to be especially important at higher temperature and is attributed to the formation of microcracks partially decorated with hydrogen. These results indicate that the chemistry and morphology of a silicon electrode are not stable even in the presence of an applied negative potential.

  8. Coagulase-Negative Staphylococci

    PubMed Central

    Heilmann, Christine; Peters, Georg

    2014-01-01

    SUMMARY The definition of the heterogeneous group of coagulase-negative staphylococci (CoNS) is still based on diagnostic procedures that fulfill the clinical need to differentiate between Staphylococcus aureus and those staphylococci classified historically as being less or nonpathogenic. Due to patient- and procedure-related changes, CoNS now represent one of the major nosocomial pathogens, with S. epidermidis and S. haemolyticus being the most significant species. They account substantially for foreign body-related infections and infections in preterm newborns. While S. saprophyticus has been associated with acute urethritis, S. lugdunensis has a unique status, in some aspects resembling S. aureus in causing infectious endocarditis. In addition to CoNS found as food-associated saprophytes, many other CoNS species colonize the skin and mucous membranes of humans and animals and are less frequently involved in clinically manifested infections. This blurred gradation in terms of pathogenicity is reflected by species- and strain-specific virulence factors and the development of different host-defending strategies. Clearly, CoNS possess fewer virulence properties than S. aureus, with a respectively different disease spectrum. In this regard, host susceptibility is much more important. Therapeutically, CoNS are challenging due to the large proportion of methicillin-resistant strains and increasing numbers of isolates with less susceptibility to glycopeptides. PMID:25278577

  9. Improved negative ion source

    DOEpatents

    Delmore, J.E.

    1984-05-01

    A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reaccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200 to 500/sup 0/C for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

  10. Plasmonics without negative dielectrics

    NASA Astrophysics Data System (ADS)

    Della Giovampaola, Cristian; Engheta, Nader

    2016-05-01

    Plasmonic phenomena are exhibited in light-matter interaction involving materials whose real parts of permittivity functions attain negative values at operating wavelengths. However, such materials usually suffer from dissipative losses, thus limiting the performance of plasmon-based optical devices. Here, we utilize an alternative methodology that mimics a variety of plasmonic phenomena by exploiting the well-known structural dispersion of electromagnetic modes in bounded guided-wave structures filled with only materials with positive permittivity. A key issue in the design of such structures is prevention of mode coupling, which can be achieved by implementing thin metallic wires at proper interfaces. This method, which is more suitable for lower frequencies, allows designers to employ conventional dielectrics and highly conductive metals for which the loss is low at these frequencies, while achieving plasmonic features. We demonstrate, numerically and analytically, that this platform can provide surface plasmon polaritons, local plasmonic resonance, plasmonic cloaking, and epsilon-near-zero-based tunneling using conventional positive-dielectric materials.

  11. Coagulase-negative staphylococci.

    PubMed

    Becker, Karsten; Heilmann, Christine; Peters, Georg

    2014-10-01

    The definition of the heterogeneous group of coagulase-negative staphylococci (CoNS) is still based on diagnostic procedures that fulfill the clinical need to differentiate between Staphylococcus aureus and those staphylococci classified historically as being less or nonpathogenic. Due to patient- and procedure-related changes, CoNS now represent one of the major nosocomial pathogens, with S. epidermidis and S. haemolyticus being the most significant species. They account substantially for foreign body-related infections and infections in preterm newborns. While S. saprophyticus has been associated with acute urethritis, S. lugdunensis has a unique status, in some aspects resembling S. aureus in causing infectious endocarditis. In addition to CoNS found as food-associated saprophytes, many other CoNS species colonize the skin and mucous membranes of humans and animals and are less frequently involved in clinically manifested infections. This blurred gradation in terms of pathogenicity is reflected by species- and strain-specific virulence factors and the development of different host-defending strategies. Clearly, CoNS possess fewer virulence properties than S. aureus, with a respectively different disease spectrum. In this regard, host susceptibility is much more important. Therapeutically, CoNS are challenging due to the large proportion of methicillin-resistant strains and increasing numbers of isolates with less susceptibility to glycopeptides. PMID:25278577

  12. Hydrogen separation process

    DOEpatents

    Mundschau, Michael; Xie, Xiaobing; Evenson, IV, Carl; Grimmer, Paul; Wright, Harold

    2011-05-24

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  13. Negative Pressure Wound Therapy

    PubMed Central

    2006-01-01

    Executive Summary Objective This review was conducted to assess the effectiveness of negative pressure wound therapy. Clinical Need: Target Population and Condition Many wounds are difficult to heal, despite medical and nursing care. They may result from complications of an underlying disease, like diabetes; or from surgery, constant pressure, trauma, or burns. Chronic wounds are more often found in elderly people and in those with immunologic or chronic diseases. Chronic wounds may lead to impaired quality of life and functioning, to amputation, or even to death. The prevalence of chronic ulcers is difficult to ascertain. It varies by condition and complications due to the condition that caused the ulcer. There are, however, some data on condition-specific prevalence rates; for example, of patients with diabetes, 15% are thought to have foot ulcers at some time during their lives. The approximate community care cost of treating leg ulcers in Canada, without reference to cause, has been estimated at upward of $100 million per year. Surgically created wounds can also become chronic, especially if they become infected. For example, the reported incidence of sternal wound infections after median sternotomy is 1% to 5%. Abdominal surgery also creates large open wounds. Because it is sometimes necessary to leave these wounds open and allow them to heal on their own (secondary intention), some may become infected and be difficult to heal. Yet, little is known about the wound healing process, and this makes treating wounds challenging. Many types of interventions are used to treat wounds. Current best practice for the treatment of ulcers and other chronic wounds includes debridement (the removal of dead or contaminated tissue), which can be surgical, mechanical, or chemical; bacterial balance; and moisture balance. Treating the cause, ensuring good nutrition, and preventing primary infection also help wounds to heal. Saline or wet-to-moist dressings are reported as

  14. Nanoplasmonic hydrogen sensing

    NASA Astrophysics Data System (ADS)

    Wadell, Carl; Syrenova, Svetlana; Langhammer, Christoph

    2014-09-01

    In this review we discuss the evolution of surface plasmon resonance and localized surface plasmon resonance based hydrogen sensors. We put particular focus on how they are used to study metal-hydrogen interactions at the nanoscale, both at the ensemble and the single nanoparticle level. Such efforts are motivated by a fundamental interest in understanding the role of nanosizing on metal hydride formation processes. However, nanoplasmonic hydrogen sensors are not only of academic interest but may also find more practical use as all-optical gas detectors in industrial and medical applications, as well in a future hydrogen economy, where hydrogen is used as a carbon free energy carrier.

  15. Safe venting of hydrogen

    SciTech Connect

    Stewart, W.F.; Dewart, J.M.; Edeskuty, F.J.

    1990-01-01

    The disposal of hydrogen is often required in the operation of an experimental facility that contains hydrogen. Whether the vented hydrogen can be discharged to the atmosphere safely depends upon a number of factors such as the flow rate and atmospheric conditions. Calculations have been made that predict the distance a combustible mixture can extend from the point of release under some specified atmospheric conditions. Also the quantity of hydrogen in the combustible cloud is estimated. These results can be helpful in deciding of the hydrogen can be released directly to the atmosphere, or if it must be intentionally ignited. 15 refs., 5 figs., 2 tabs.

  16. Hydrogen ionic plasma generated using Al plasma grid

    NASA Astrophysics Data System (ADS)

    Oohara, W.; Anegawa, N.; Egawa, M.; Kawata, K.; Kamikawa, T.

    2016-08-01

    Negative hydrogen ions are produced in the apertures of a plasma grid made of aluminum under the irradiation of positive ions, generating an ionic plasma consisting of positive and negative ions. The saturation current ratio obtained using a Langmuir probe reflects the existence ratio of electrons and is found to increase in connection with the diffusion of the ionic plasma. The local increment of the current ratio suggests the collapse of negative ions and the replacement of detached electrons.

  17. Conservatives, liberals, and "the negative".

    PubMed

    Charney, Evan

    2014-06-01

    The authors connect conservatism with aversion to negativity via the tendentious use of the language of threats to characterize conservatism, but not liberalism. Their reliance upon an objective conception of the negative ignores the fact that much of the disagreement between liberals and conservatives is over whether or not one and the same state of affairs is negative or positive. PMID:24970432

  18. Negativity bias and basic values.

    PubMed

    Schwartz, Shalom H

    2014-06-01

    Basic values explain more variance in political attitudes and preferences than other personality and sociodemographic variables. The values most relevant to the political domain are those likely to reflect the degree of negativity bias. Value conflicts that represent negativity bias clarify differences between what worries conservatives and liberals and suggest that relations between ideology and negativity bias are linear. PMID:24970450

  19. Hydrogen storage methods.

    PubMed

    Züttel, Andreas

    2004-04-01

    Hydrogen exhibits the highest heating value per mass of all chemical fuels. Furthermore, hydrogen is regenerative and environmentally friendly. There are two reasons why hydrogen is not the major fuel of today's energy consumption. First of all, hydrogen is just an energy carrier. And, although it is the most abundant element in the universe, it has to be produced, since on earth it only occurs in the form of water and hydrocarbons. This implies that we have to pay for the energy, which results in a difficult economic dilemma because ever since the industrial revolution we have become used to consuming energy for free. The second difficulty with hydrogen as an energy carrier is its low critical temperature of 33 K (i.e. hydrogen is a gas at ambient temperature). For mobile and in many cases also for stationary applications the volumetric and gravimetric density of hydrogen in a storage material is crucial. Hydrogen can be stored using six different methods and phenomena: (1) high-pressure gas cylinders (up to 800 bar), (2) liquid hydrogen in cryogenic tanks (at 21 K), (3) adsorbed hydrogen on materials with a large specific surface area (at T<100 K), (4) absorbed on interstitial sites in a host metal (at ambient pressure and temperature), (5) chemically bonded in covalent and ionic compounds (at ambient pressure), or (6) through oxidation of reactive metals, e.g. Li, Na, Mg, Al, Zn with water. The most common storage systems are high-pressure gas cylinders with a maximum pressure of 20 MPa (200 bar). New lightweight composite cylinders have been developed which are able to withstand pressures up to 80 MPa (800 bar) and therefore the hydrogen gas can reach a volumetric density of 36 kg.m(-3), approximately half as much as in its liquid state. Liquid hydrogen is stored in cryogenic tanks at 21.2 K and ambient pressure. Due to the low critical temperature of hydrogen (33 K), liquid hydrogen can only be stored in open systems. The volumetric density of liquid hydrogen

  20. Transfer of small negative atmospheric ions

    NASA Astrophysics Data System (ADS)

    Maruyama, Toshiro; Katayama, Takashi

    2003-12-01

    The transfer of small negative atmospheric ions in air and from air to water has been studied. The mean lifetime of ions was experimentally obtained from the concentration distribution of ions in a round free jet. It was about 30 s in relative humidity of 63%-75%, indicating that ions generated at one source in a room could not be homogeneously spread throughout the room by conventional convective flow of air. Rapid dissipation of the ions occurs during diffusion in stationary air. However, most of the ions that enter the mouth of a human body reach the lungs, because of the high convective velocity of breathing. The irradiation of ions onto water decreased the electric conductivity of the water. This finding suggests that the transfer of ions into water in a human body breaks the network of H2O molecules and enhances the formation of hydrogen bonds between a biopolymer and water.

  1. Installation of spectrally selective imaging system in RF negative ion source

    NASA Astrophysics Data System (ADS)

    Ikeda, K.; Wünderlich, D.; Fantz, U.; Heinemann, B.; Kisaki, M.; Nagaoka, K.; Nakano, H.; Osakabe, M.; Tsumori, K.; Geng, S.; Kaneko, O.; Takeiri, Y.

    2016-02-01

    A spectrally selective imaging system has been installed in the RF negative ion source in the International Thermonuclear Experimental Reactor-relevant negative ion beam test facility ELISE (Extraction from a Large Ion Source Experiment) to investigate distribution of hydrogen Balmer-α emission (Hα) close to the production surface of hydrogen negative ion. We selected a GigE vision camera coupled with an optical band-path filter, which can be controlled remotely using high speed network connection. A distribution of Hα emission near the bias plate has been clearly observed. The same time trend on Hα intensities measured by the imaging diagnostic and the optical emission spectroscopy is confirmed.

  2. Investigations of negative and positive cesium ion species

    NASA Technical Reports Server (NTRS)

    Chanin, L. M.

    1978-01-01

    A direct test is provided of the hypothesis of negative ion creation at the anode or collector of a diode operating under conditions simulating a cesium thermionic converter. The experimental technique involves using direct ion sampling through the collector electrode with mass analysis using a quadrupole mass analyzer. Similar measurements are undertaken on positive ions extracted through the emitter electrode. Measurements were made on a variety of gases including pure cesium, helium-cesium mixtures and cesium-hydrogen as well as cesium-xenon mixtures. The gas additive was used primarily to aid in understanding the negative ion formation processes. Measurements were conducted using emitter (cathode) temperatures up to about 1000 F. The major negative ion identified through the collector was Cs(-) with minor negative ion peaks tentatively identified as H(-), H2(-), H3(-), He(-) and a mass 66. Positive ions detected were believed to be Cs(+), Cs2(+) and Cs3(+).

  3. Hydrogen Filling Station

    SciTech Connect

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

    2010-02-24

    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen

  4. Hydrogen energy systems studies

    SciTech Connect

    Ogden, J.M.; Steinbugler, M.; Kreutz, T.

    1998-08-01

    In this progress report (covering the period May 1997--May 1998), the authors summarize results from ongoing technical and economic assessments of hydrogen energy systems. Generally, the goal of their research is to illuminate possible pathways leading from present hydrogen markets and technologies toward wide scale use of hydrogen as an energy carrier, highlighting important technologies for RD and D. Over the past year they worked on three projects. From May 1997--November 1997, the authors completed an assessment of hydrogen as a fuel for fuel cell vehicles, as compared to methanol and gasoline. Two other studies were begun in November 1997 and are scheduled for completion in September 1998. The authors are carrying out an assessment of potential supplies and demands for hydrogen energy in the New York City/New Jersey area. The goal of this study is to provide useful data and suggest possible implementation strategies for the New York City/ New Jersey area, as the Hydrogen Program plans demonstrations of hydrogen vehicles and refueling infrastructure. The authors are assessing the implications of CO{sub 2} sequestration for hydrogen energy systems. The goals of this work are (a) to understand the implications of CO{sub 2} sequestration for hydrogen energy system design; (b) to understand the conditions under which CO{sub 2} sequestration might become economically viable; and (c) to understand design issues for future low-CO{sub 2} emitting hydrogen energy systems based on fossil fuels.

  5. Hydrogen interactions with metals

    NASA Technical Reports Server (NTRS)

    Mclellan, R. B.; Harkins, C. G.

    1975-01-01

    Review of the literature on the nature and extent of hydrogen interactions with metals and the role of hydrogen in metal failure. The classification of hydrogen-containing systems is discussed, including such categories as covalent hydrides, volatile hydrides, polymeric hydrides, and transition metal hydride complexes. The use of electronegativity as a correlating parameter in determining hydride type is evaluated. A detailed study is made of the thermodynamics of metal-hydrogen systems, touching upon such aspects as hydrogen solubility, the positions occupied by hydrogen atoms within the solvent metal lattice, the derivation of thermodynamic functions of solid solutions from solubility data, and the construction of statistical models for hydrogen-metal solutions. A number of theories of hydrogen-metal bonding are reviewed, including the rigid-band model, the screened-proton model, and an approach employing the augmented plane wave method to solve the one-electron energy band problem. Finally, the mechanism of hydrogen embrittlement is investigated on the basis of literature data concerning stress effects and the kinetics of hydrogen transport to critical sites.

  6. Ultrafine hydrogen storage powders

    DOEpatents

    Anderson, Iver E.; Ellis, Timothy W.; Pecharsky, Vitalij K.; Ting, Jason; Terpstra, Robert; Bowman, Robert C.; Witham, Charles K.; Fultz, Brent T.; Bugga, Ratnakumar V.

    2000-06-13

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  7. Negative compressibility observed in graphene containing resonant impurities

    SciTech Connect

    Chen, X. L.; Wang, L.; Li, W.; Wang, Y.; He, Y. H.; Wu, Z. F.; Han, Y.; Zhang, M. W.; Xiong, W.; Wang, N.

    2013-05-20

    We observed negative compressibility in monolayer graphene containing resonant impurities under different magnetic fields. Hydrogenous impurities were introduced into graphene by electron beam (e-beam) irradiation. Resonant states located in the energy region of {+-}0.04 eV around the charge neutrality point were probed in e-beam-irradiated graphene capacitors. Theoretical results based on tight-binding and Lifshitz models agreed well with experimental observations of graphene containing a low concentration of resonant impurities. The interaction between resonant states and Landau levels was detected by varying the applied magnetic field. The interaction mechanisms and enhancement of the negative compressibility in disordered graphene are discussed.

  8. Negative compressibility observed in graphene containing resonant impurities

    NASA Astrophysics Data System (ADS)

    Chen, X. L.; Wang, L.; Li, W.; Wang, Y.; He, Y. H.; Wu, Z. F.; Han, Y.; Zhang, M. W.; Xiong, W.; Wang, N.

    2013-05-01

    We observed negative compressibility in monolayer graphene containing resonant impurities under different magnetic fields. Hydrogenous impurities were introduced into graphene by electron beam (e-beam) irradiation. Resonant states located in the energy region of ±0.04 eV around the charge neutrality point were probed in e-beam-irradiated graphene capacitors. Theoretical results based on tight-binding and Lifshitz models agreed well with experimental observations of graphene containing a low concentration of resonant impurities. The interaction between resonant states and Landau levels was detected by varying the applied magnetic field. The interaction mechanisms and enhancement of the negative compressibility in disordered graphene are discussed.

  9. Negative-ion source applications.

    PubMed

    Ishikawa, J

    2008-02-01

    In this paper heavy negative-ion sources which we developed and their applications for materials science are reviewed. Heavy negative ions can be effectively produced by the ejection of a sputtered atom through the optimally cesiated surface of target with a low work function. Then, enough continuous negative-ion currents for materials-science applications can be obtained. We developed several kinds of sputter-type heavy negative-ion sources such as neutral- and ionized-alkaline metal bombardment-type heavy negative-ion source and rf-plasma sputter type. In the case where a negative ion is irradiated on a material surface, surface charging seldom takes place because incoming negative charge of the negative ion is well balanced with outgoing negative charge of the released secondary electron. In the negative-ion implantation into an insulator or insulated conductive material, high precision implantation processing with charge-up free properties can be achieved. Negative-ion implantation technique, therefore, can be applied to the following novel material processing systems: the surface modification of micrometer-sized powders, the nanoparticle formation in an insulator for the quantum devices, and the nerve cell growth manipulation by precise control of the biocompatibility of polymer surface. When a negative ion with low kinetic energy approaches the solid surface, the kinetic energy causes the interatomic bonding (kinetic bonding), and formation of a metastable material is promoted. Carbon films with high constituent of sp(3) bonding, therefore, can be formed by carbon negative-ion beam deposition. PMID:18315249

  10. Enzymatic Hydrogen Production from Starch and Water

    SciTech Connect

    Zhang, Y.-H. Percival; Evans, Barbara R; Mielenz, Jonathan R; Hopkins, Robert C.; Adams, Michael W. W.

    2007-01-01

    A novel enzymatic reaction was conducted for producing hydrogen from starch and water at 30oC. The overall reaction comprised of 13 enzymes, 1 cofactor (NADP+), and phosphate was driven by energy stored in carbohydrate starch according to the overall stoichiometry stoichiometric reaction of C6H10O5 (l) + 7 H2O (l) --> 12 H2 (g) + 6 CO2 (g). It is spontaneous and unidirectional because of negative Gibbs free energy and the removal of gaseous products from the aqueous reaction solution. With technology improvement and integration with fuel cells, this technology would be suitable for mobile applications and also solve the challenges associated with hydrogen storage, distribution, and infrastructure in a hydrogen economy.

  11. Analysis of hydrogen isotope mixtures

    DOEpatents

    Villa-Aleman, Eliel

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  12. Fiber optic hydrogen sensor

    NASA Astrophysics Data System (ADS)

    Jung, Chuck C.; Saaski, Elric W.; McCrae, David A.

    1998-09-01

    This paper describes a novel fiber optic-based hydrogen sensor. The sensor consists of a thin-film etalon, constructed on the distal end of a fiber optic. The exterior mirror of the etalon is palladium or a palladium-alloy, which undergoes an optical change upon exposure to hydrogen. Data is presented on fiber optic sensors constructed with palladium and several alloys of palladium. The linearity of the optical response of these sensors to hydrogen is examined. Etalons made with pure palladium are found to be desirable for sensing low concentrations of hydrogen, or for one-time exposure to high concentrations of hydrogen. Etalons made from palladium alloys are found to be more desirable in applications were repeated cycling in high concentrations of hydrogen occurs.

  13. Hydrogen powered bus

    ScienceCinema

    None

    2013-11-22

    Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

  14. National hydrogen energy roadmap

    SciTech Connect

    None, None

    2002-11-01

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. Based on the results of the government-industry National Hydrogen Energy Roadmap Workshop, held in Washington, DC on April 2-3, 2002, it displays the development of a roadmap for America's clean energy future and outlines the key barriers and needs to achieve the hydrogen vision goals defined in

  15. HYDROGEN ISOTOPE TARGETS

    DOEpatents

    Ashley, R.W.

    1958-08-12

    The design of targets for use in the investigation of nuclear reactions of hydrogen isotopes by bombardment with accelerated particles is described. The target con struction eomprises a backing disc of a metal selected from the group consisting of molybdenunn and tungsten, a eoating of condensed titaniunn on the dise, and a hydrogen isotope selected from the group consisting of deuterium and tritium absorbed in the coatiag. The proeess for preparing these hydrogen isotope targets is described.

  16. Hydrogen rich gas generator

    NASA Technical Reports Server (NTRS)

    Houseman, J. (Inventor)

    1976-01-01

    A process and apparatus is described for producing a hydrogen rich gas by introducing a liquid hydrocarbon fuel in the form of a spray into a partial oxidation region and mixing with a mixture of steam and air that is preheated by indirect heat exchange with the formed hydrogen rich gas, igniting the hydrocarbon fuel spray mixed with the preheated mixture of steam and air within the partial oxidation region to form a hydrogen rich gas.

  17. Hydrogen energy systems studies

    SciTech Connect

    Ogden, J.M.; Steinbugler, M.; Dennis, E.

    1995-09-01

    For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

  18. 24. Duplicate negative of an historic negative. 'AERIAL VIEW OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    24. Duplicate negative of an historic negative. 'AERIAL VIEW OF AREA 'B' HOLSTON ORDNANCE WORKS.' 1944. #OCMH 4-12.2ASAV3 in Super Explosives Program RDX and Its Composition A, B, & C, Record Group No. 319, National Archives, Washington, D.C. - Holston Army Ammunition Plant, RDX-and-Composition-B Manufacturing Line 9, Kingsport, Sullivan County, TN

  19. Hydrogen /Hydride/-air secondary battery

    NASA Technical Reports Server (NTRS)

    Sarradin, J.; Bronoel, G.; Percheron-Guegan, A.; Achard, J. C.

    1979-01-01

    The use of metal hydrides as negative electrodes in a hydrogen-air secondary battery seems promising. However, in an unpressurized cell, more stable hydrides that LaNi5H6 must be selected. Partial substitutions of nickel by aluminium or manganese increase the stability of hydrides. Combined with an air reversible electrode, a specific energy close to 100 Wh/kg can be expected.

  20. HYDROGEN SEPARATION MEMBRANES

    SciTech Connect

    Donald P. McCollor; John P. Kay

    1999-08-01

    A likely membrane for future testing of high-temperature hydrogen separation from a gasification product stream was targeted as an inorganic analog of a dense-metal membrane, where the hydrogen would dissolve into and diffuse through the membrane structure. An amorphous membrane such as zinc sulfide appeared to be promising. Previously, ZnS film coating tests had been performed using an electron-beam vacuum coating instrument, with zinc films successfully applied to glass substrates. The coatings appeared relatively stable in air and in a simple simulated gasification atmosphere at elevated temperature. Because the electron-beam coating instrument suffered irreparable breakdown, several alternative methods were tested in an effort to produce a nitrogen-impermeable, hydrogen-permeable membrane on porous sintered steel substrates. None of the preparation methods proved successful in sealing the porous substrate against nitrogen gas. To provide a nitrogen-impermeable ZnS material to test for hydrogen permeability, two ZnS infrared sample windows were purchased. These relatively thick ''membranes'' did not show measurable permeation of hydrogen, either due to lack of absorption or a negligible permeation rate due to their thickness. To determine if hydrogen was indeed adsorbed, thermogravimetric and differential thermal analyses tests were performed on samples of ZnS powder. A significant uptake of hydrogen gas occurred, corresponding to a maximum of 1 mole H{sub 2} per 1 mole ZnS at a temperature of 175 C. The hydrogen remained in the material at ambient temperature in a hydrogen atmosphere, but approximately 50% would be removed in argon. Reheating in a hydrogen atmosphere resulted in no additional hydrogen uptake. Differential scanning calorimetry indicated that the hydrogen uptake was probably due to the formation of a zinc-sulfur-hydrogen species resulting in the formation of hydrogen sulfide. The zinc sulfide was found to be unstable above approximately 200 C

  1. Optimized hydrogen piston engines

    SciTech Connect

    Smith, J.R.

    1994-05-10

    Hydrogen piston engines can be simultaneously optimized for improved thermal efficiency and for extremely low emissions. Using these engines in constant-speed, constant-load systems such as series hybrid-electric automobiles or home cogeneration systems can result in significantly improved energy efficiency. For the same electrical energy produced, the emissions from such engines can be comparable to those from natural gas-fired steam power plants. These hydrogen-fueled high-efficiency, low-emission (HELE) engines are a mechanical equivalent of hydrogen fuel cells. HELE engines could facilitate the transition to a hydrogen fuel cell economy using near-term technology.

  2. Hydrogen ion microlithography

    DOEpatents

    Tsuo, Y. Simon; Deb, Satyen K.

    1990-01-01

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing.

  3. Hydrogen ion microlithography

    DOEpatents

    Tsuo, Y.S.; Deb, S.K.

    1990-10-02

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing. 6 figs.

  4. Hydrogen Gets Onboard

    SciTech Connect

    Gutowski, Maciej S.; Autrey, Thomas

    2006-03-01

    In this brief review we update progress in research efforts for on-board hydrogen storage for fuel cell powered vehicles. In addition to economic targets, the technological challenges are bounded by volumetric and gravimetric constraints. Specifically, an amoiunt of 4 kg of H2, required to propel a highly fuel efficient automobile for 500 kilometers, must fit into the space of a conventional gasoline tank. The volumetric constraints rule out compressed and liquefied H2 and teach us that hydrogen must be stored as a solid material, either by physi-sorption to high surface area materials or chemically bond (covalent or ionic) to light weight elements. Hydrogen stored on high surface area materials is weakly bound and general requires low temperatures to stabilize the hydrogen. On the other end, hydrogen covalently bound to light metals requires high temperatures to release the hydrogen. One interesting alterative is chemical hydrogen storage (CHS). CHS covers a broad range of materials but is defined as a process whereby the hydrogen is released by a chemical reaction. The reaction could be induced by hydrolysis, a reaction with water, or by thermolysis, heating to moderate temperatures to release hydrogen. The spent material can then be reprocessed or regenerated off-board. Battelle operates the Pacific Northwest National Laboratory for the US Department of Energy.

  5. Sustainable hydrogen production

    SciTech Connect

    Block, D.L.; Linkous, C.; Muradov, N.

    1996-01-01

    This report describes the Sustainable Hydrogen Production research conducted at the Florida Solar Energy Center (FSEC) for the past year. The report presents the work done on the following four tasks: Task 1--production of hydrogen by photovoltaic-powered electrolysis; Task 2--solar photocatalytic hydrogen production from water using a dual-bed photosystem; Task 3--development of solid electrolytes for water electrolysis at intermediate temperatures; and Task 4--production of hydrogen by thermocatalytic cracking of natural gas. For each task, this report presents a summary, introduction/description of project, and results.

  6. Thin film hydrogen sensor

    DOEpatents

    Lauf, Robert J.; Hoffheins, Barbara S.; Fleming, Pamela H.

    1994-01-01

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed.

  7. Hydrogen Safety Knowledge Tools

    SciTech Connect

    Fassbender, Linda L.

    2011-01-31

    With hydrogen gaining acceptance as an energy carrier for fuel cell vehicles and stationary fuel cell applications, a new community of hydrogen users is emerging and continues to grow. With this growth has come the need to spread the word about safe practices for handling, storing, and using hydrogen. Like all energy forms, hydrogen can be used safely through proper procedures and engineering techniques. However, hydrogen involves a degree of risk that must be respected, and the importance of avoiding complacency or haste in the safe conduct and performance of projects involving hydrogen cannot be overstated. To encourage and promote the safe use of hydrogen, Pacific Northwest National Laboratory (PNNL) has developed and continues to enhance two software tools in support of the U.S. Department of Energy's Fuel Cell Technologies Program: the Hydrogen Safety Best Practices online manual (www.H2BestPractices.org) and the Hydrogen Incident Reporting and Lessons Learned database (www.H2Incidents.org).

  8. Negative cooperativity in regulatory enzymes.

    PubMed

    Levitzki, A; Koshland, D E

    1969-04-01

    Negative cooperativity has been observed in CTP synthetase, an allosteric enzyme which contains a regulatory site. Thus, the same enzyme exhibits negative cooperativity for GTP (an effector) and glutamine (a substrate) and positive cooperativity for ATP and UTP (both substrates). In the process of the delineation of these phenomena, diagnostic procedures for negative cooperativity were developed. Application of these procedures to other enzymes indicates that negative cooperativity is a characteristic of many of them. These findings add strong support for the sequential model of subunit interactions which postulates that ligand-induced conformational changes are responsible for regulatory and cooperative phenomena in enzymes. PMID:5256410

  9. Negative ions of polyatomic molecules.

    PubMed Central

    Christophorou, L G

    1980-01-01

    In this paper general concepts relating to, and recent advances in, the study of negative ions of polyatomic molecules area discussed with emphasis on halocarbons. The topics dealt with in the paper are as follows: basic electron attachment processes, modes of electron capture by molecules, short-lived transient negative ions, dissociative electron attachment to ground-state molecules and to "hot" molecules (effects of temperature on electron attachment), parent negative ions, effect of density, nature, and state of the medium on electron attachment, electron attachment to electronically excited molecules, the binding of attached electrons to molecules ("electron affinity"), and the basic and the applied significance of negative-ion studies. PMID:7428744

  10. Intrinsic Negative Mass from Nonlinearity

    NASA Astrophysics Data System (ADS)

    Di Mei, F.; Caramazza, P.; Pierangeli, D.; Di Domenico, G.; Ilan, H.; Agranat, A. J.; Di Porto, P.; DelRe, E.

    2016-04-01

    We propose and provide experimental evidence of a mechanism able to support negative intrinsic effective mass. The idea is to use a shape-sensitive nonlinearity to change the sign of the mass in the leading linear propagation equation. Intrinsic negative-mass dynamics is reported for light beams in a ferroelectric crystal substrate, where the diffusive photorefractive nonlinearity leads to a negative-mass Schrödinger equation. The signature of inverted dynamics is the observation of beams repelled from strongly guiding integrated waveguides irrespective of wavelength and intensity and suggests shape-sensitive nonlinearity as a basic mechanism leading to intrinsic negative mass.

  11. Neurobiological background of negative symptoms.

    PubMed

    Galderisi, Silvana; Merlotti, Eleonora; Mucci, Armida

    2015-10-01

    Studies investigating neurobiological bases of negative symptoms of schizophrenia failed to provide consistent findings, possibly due to the heterogeneity of this psychopathological construct. We tried to review the findings published to date investigating neurobiological abnormalities after reducing the heterogeneity of the negative symptoms construct. The literature in electronic databases as well as citations and major articles are reviewed with respect to the phenomenology, pathology, genetics and neurobiology of schizophrenia. We searched PubMed with the keywords "negative symptoms," "deficit schizophrenia," "persistent negative symptoms," "neurotransmissions," "neuroimaging" and "genetic." Additional articles were identified by manually checking the reference lists of the relevant publications. Publications in English were considered, and unpublished studies, conference abstracts and poster presentations were not included. Structural and functional imaging studies addressed the issue of neurobiological background of negative symptoms from several perspectives (considering them as a unitary construct, focusing on primary and/or persistent negative symptoms and, more recently, clustering them into factors), but produced discrepant findings. The examined studies provided evidence suggesting that even primary and persistent negative symptoms include different psychopathological constructs, probably reflecting the dysfunction of different neurobiological substrates. Furthermore, they suggest that complex alterations in multiple neurotransmitter systems and genetic variants might influence the expression of negative symptoms in schizophrenia. On the whole, the reviewed findings, representing the distillation of a large body of disparate data, suggest that further deconstruction of negative symptomatology into more elementary components is needed to gain insight into underlying neurobiological mechanisms. PMID:25797499

  12. Combination moisture and hydrogen getter

    DOEpatents

    Harrah, L.A.; Mead, K.E.; Smith, H.M.

    1983-09-20

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (1) a solid acetylenic compound and (2) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  13. Combination moisture and hydrogen getter

    DOEpatents

    Not Available

    1982-04-29

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  14. Combination moisture and hydrogen getter

    DOEpatents

    Harrah, Larry A.; Mead, Keith E.; Smith, Henry M.

    1983-01-01

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

  15. Enhancing hydrogen spillover and storage

    DOEpatents

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  16. Enhancing hydrogen spillover and storage

    DOEpatents

    Yang, Ralph T.; Li, Yingwel; Lachawiec, Jr., Anthony J.

    2011-05-31

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  17. Reverse hydrogen spillover on and hydrogenation of supported metal clusters: insights from computational model studies.

    PubMed

    Vayssilov, Georgi N; Petrova, Galina P; Shor, Elena A Ivanova; Nasluzov, Vladimir A; Shor, Alexei M; St Petkov, Petko; Rösch, Notker

    2012-05-01

    "Reverse" spillover of hydrogen from hydroxyl groups of the support onto supported transition metal clusters, forming multiply hydrogenated metal species, is an essential aspect of various catalytic systems which comprise small, highly active transition metal particles on a support with a high surface area. We review and analyze the results of our computational model studies related to reverse hydrogen spillover, interpreting available structural and spectral data for the supported species and examining the relationship between metal-support and metal-hydrogen interactions. On the examples of small clusters of late transition metals, adsorbed in zeolite cavities, we showed with computational model studies that reverse spillover of hydrogen is energetically favorable for late transition metals, except for Au. This preference is crucial for the chemical reactivity of such bifunctional catalytic systems because both functions, of metal species and of acidic sites, are strongly modified, in some cases even suppressed - due to partial oxidation of the metal cluster and the conversion of protons from acidic hydroxyl groups to hydride ligands of the metal moiety. Modeling multiple hydrogen adsorption on metal clusters allowed us to quantify how (i) the support affects the adsorption capacity of the clusters and (ii) structure and oxidation state of the metal moiety changes upon adsorption. In all models of neutral systems we found that the metal atoms are partially positively charged, compensated by a negative charge of the adsorbed hydrogen ligands and of the support. In a case study we demonstrated with calculated thermodynamic parameters how to predict the average hydrogen coverage of the transition metal cluster at a given temperature and hydrogen pressure. PMID:22353996

  18. Muon transfer from hot muonic hydrogen atoms to neon

    SciTech Connect

    Jacot-Guillarmod, R. . Inst. de Physique); Bailey, J.M. ); Beer, G.A.; Knowles, P.E.; Mason, G.R.; Olin, A. ); Beveridge, J.L.; Marshall, G.M.; Brewer, J.H.; Forster, B.M. ); Huber, T.M. ); Kammel, P.; Zmeskal, J.

    1992-01-01

    A negative muon beam has been directed on adjacent solid layers of hydrogen and neon. Three targets differing by their deuterium concentration were investigated. Muonic hydrogen atoms can drift to the neon layer where the muon is immediately transferred. The time structure of the muonic neon X-rays follows the exponential law with a disappearance rate corresponding to the one of [mu][sup [minus]p] atoms in each target. The rates [lambda][sub pp[mu

  19. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOEpatents

    Hindin, Saul G.; Roberts, George W.

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  20. Hydrogenated graphene and hydrogenated silicene: computational insights.

    PubMed

    Nguyen, Manh-Thuong; Phong, Pham Nam; Tuyen, Nguyen Duc

    2015-06-01

    Density functional calculations are performed to study the energetic, structural, and electronic properties of graphene and silicene functionalized with hydrogen. Our calculations predict that H atoms bind much more strongly to silicene than to graphene. The adsorbed H atoms tend to cooperatively stabilize each other leading to a two-dimensional nucleation and growth mechanism. The different structural and electronic modifications induced by H in fully functionalized graphene and silicene (known as graphane and silicane) are also explained. Finally, the electronic properties of defective graphane with multiple hydrogen vacancies are investigated. Engineering the vacancies in graphane offers a way to modify the electronic properties of this material. PMID:25820304

  1. Negation in the Chaamling Language.

    ERIC Educational Resources Information Center

    Rai, Vishnu S.

    This paper examines the different ways of forming negative sentences in the Chaamling language, an indigenous language spoken in the eastern, hilly districts of Nepal. It explains that negation, or negativization, in the Chaamling language is done with the help of affixation. In imperative sentences, the prefix mi- is added to the verb, which is…

  2. Hydrogen Tunneling in Enzymes and Biomimetic Models

    SciTech Connect

    Layfield, Joshua P.; Hammes-Schiffer, Sharon

    2013-12-20

    Hydrogen transfer reactions play an important role throughout chemistry and biology. In general, hydrogen transfer reactions encompass proton and hydride transfer, which are associated with the transfer of a positively or negatively charged species, respectively, and proton-coupled electron transfer (PCET), which corresponds to the net transfer of one electron and one proton in the simplest case. Such PCET reactions can occur by either a sequential mechanism, in which the proton or electron transfers first, or a concerted mechanism, in which the electron and proton transfer in a single kinetic step with no stable intermediate. Furthermore, concerted PCET reactions can be subdivided into hydrogen atom transfer (HAT), which corresponds to the transfer of an electron and proton between the same donor and acceptor (i.e., the transfer of a predominantly neutral species), and electron-proton transfer (EPT), which corresponds to the transfer of an electron and proton between different donors and acceptors, possibly even in different directions. In all of these types of hydrogen transfer reactions, hydrogen tunneling could potentially play a signficant role. The theoretical development portion of this Review was supported by the National Science Foundation under CHE-10-57875. The biological portion of this Review was funded by NIH Grant No. GM056207. The biomimetic portion was supported as part of the Center for Molecular Electro-catalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  3. Hydrogen Tunneling in Enzymes and Biomimetic Models

    SciTech Connect

    Layfield, Joshua P.; Hammes-Schiffer, Sharon

    2014-04-09

    Hydrogen transfer reactions play an important role throughout chemistry and biology. In general, hydrogen transfer reactions encompass proton and hydride transfer, which are associated with the transfer of a positively or negatively charged species, respectively, and proton-coupled electron transfer (PCET), which corresponds to the net transfer of one electron and one proton in the simplest case. Such PCET reactions can occur by either a sequential mechanism, in which the proton or electron transfers first, or a concerted mechanism, in which the electron and proton transfer in a single kinetic step with no stable intermediate. Furthermore, concerted PCET reactions can be subdivided into hydrogen atom transfer (HAT), which corresponds to the transfer of an electron and proton between the same donor and acceptor (i.e., the transfer of a predominantly neutral species), and electron-proton transfer (EPT), which corresponds to the transfer of an electron and proton between different donors and acceptors, possibly even in different directions. In all of these types of hydrogen transfer reactions, hydrogen tunneling could potentially play a significant role. The biomimetic portion was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  4. Effects of partial hydrogenation on electronic transport properties in C60 molecular devices

    NASA Astrophysics Data System (ADS)

    Chen, L. N.; Cao, C.; Wu, X. Z.; Ma, S. S.; Huang, W. R.; Xu, H.

    2012-12-01

    By using nonequilibrium Green's functions in combination with the density-function theory, we investigate electronic transport properties of molecular devices with pristine and partial hydrogenation. The calculated results show that the electronic transport properties of molecular devices can be modulated by partial hydrogenation. Interestingly, our results exhibit negative differential resistance behavior in the case of the imbalance H-adsorption in C60 molecular devices under low bias. However, negative differential resistance behavior cannot be observed in the case of the balance H-adsorption. A mechanism is proposed for the hydrogenation and negative differential resistance behavior.

  5. Membrane for hydrogen recovery from streams containing hydrogen sulfide

    DOEpatents

    Agarwal, Pradeep K.

    2007-01-16

    A membrane for hydrogen recovery from streams containing hydrogen sulfide is provided. The membrane comprises a substrate, a hydrogen permeable first membrane layer deposited on the substrate, and a second membrane layer deposited on the first layer. The second layer contains sulfides of transition metals and positioned on the on a feed side of the hydrogen sulfide stream. The present invention also includes a method for the direct decomposition of hydrogen sulfide to hydrogen and sulfur.

  6. Hydrogen Impurity Defects in Rutile TiO2.

    PubMed

    Mo, Li-Bin; Wang, Yu; Bai, Yang; Xiang, Qing-Yun; Li, Qun; Yao, Wen-Qing; Wang, Jia-Ou; Ibrahim, Kurash; Wang, Huan-Hua; Wan, Cai-Hua; Cao, Jiang-Li

    2015-01-01

    Hydrogen-related defects play crucial roles in determining physical properties of their host oxides. In this work, we report our systematic experimental and theoretical (based on density functional theory) studies of the defect states formed in hydrogenated-rutile TiO2 in gaseous H2 and atomic H. In gas-hydrogenated TiO2, the incorporated hydrogen tends to occupy the oxygen vacancy site and negatively charged. The incorporated hydrogen takes the interstitial position in atom-hydrogenated TiO2, forming a weak O-H bond with the closest oxygen ion, and becomes positive. Both states of hydrogen affect the electronic structure of TiO2 mainly through changes of Ti 3d and O 2p states instead of the direct contributions of hydrogen. The resulted electronic structures of the hydrogenated TiO2 are manifested in modifications of the electrical and optical properties that will be useful for the design of new materials capable for green energy economy. PMID:26627134

  7. Hydrogen Impurity Defects in Rutile TiO2

    PubMed Central

    Mo, Li-Bin; Wang, Yu; Bai, Yang; Xiang, Qing-Yun; Li, Qun; Yao, Wen-Qing; Wang, Jia-Ou; Ibrahim, Kurash; Wang, Huan-Hua; Wan, Cai-Hua; Cao, Jiang-Li

    2015-01-01

    Hydrogen-related defects play crucial roles in determining physical properties of their host oxides. In this work, we report our systematic experimental and theoretical (based on density functional theory) studies of the defect states formed in hydrogenated-rutile TiO2 in gaseous H2 and atomic H. In gas-hydrogenated TiO2, the incorporated hydrogen tends to occupy the oxygen vacancy site and negatively charged. The incorporated hydrogen takes the interstitial position in atom-hydrogenated TiO2, forming a weak O-H bond with the closest oxygen ion, and becomes positive. Both states of hydrogen affect the electronic structure of TiO2 mainly through changes of Ti 3d and O 2p states instead of the direct contributions of hydrogen. The resulted electronic structures of the hydrogenated TiO2 are manifested in modifications of the electrical and optical properties that will be useful for the design of new materials capable for green energy economy. PMID:26627134

  8. Hydrogen Impurity Defects in Rutile TiO2

    NASA Astrophysics Data System (ADS)

    Mo, Li-Bin; Wang, Yu; Bai, Yang; Xiang, Qing-Yun; Li, Qun; Yao, Wen-Qing; Wang, Jia-Ou; Ibrahim, Kurash; Wang, Huan-Hua; Wan, Cai-Hua; Cao, Jiang-Li

    2015-12-01

    Hydrogen-related defects play crucial roles in determining physical properties of their host oxides. In this work, we report our systematic experimental and theoretical (based on density functional theory) studies of the defect states formed in hydrogenated-rutile TiO2 in gaseous H2 and atomic H. In gas-hydrogenated TiO2, the incorporated hydrogen tends to occupy the oxygen vacancy site and negatively charged. The incorporated hydrogen takes the interstitial position in atom-hydrogenated TiO2, forming a weak O-H bond with the closest oxygen ion, and becomes positive. Both states of hydrogen affect the electronic structure of TiO2 mainly through changes of Ti 3d and O 2p states instead of the direct contributions of hydrogen. The resulted electronic structures of the hydrogenated TiO2 are manifested in modifications of the electrical and optical properties that will be useful for the design of new materials capable for green energy economy.

  9. Hydrogen local vibrational modes in compound semiconductors

    SciTech Connect

    McCluskey, M.D.

    1998-12-31

    Local vibrational mode (LVM) spectroscopy of hydrogen and deuterium in GaP, AlSb, ZnSe, and GaN has provided important information about the structures of dopant-hydrogen complexes and their interaction with the host lattice. In GaN:Mg, for example, hydrogen binds to a host nitrogen which is adjacent to the magnesium acceptor. In GaP and ZnSe, it has been demonstrated that the temperature dependent shifts of LVM`s are proportional to the lattice thermal energy, a consequence of the anharmonic coupling of the local mode to acoustical phonons. Large hydrostatic pressures have been applied to semiconductors to probe the vibrational properties of hydrogen-related complexes. In GaAs, the pressure dependent shifts of the {sup 12}C-H and {sup 13}C-H stretch modes have positive curvatures, while the shift of the S-H stretch mode has a negative curvature. This may be related to the fact that in the bond-centered C-H complex, the hydrogen is compressed between the carbon acceptor and one gallium host atom, whereas in the S-H complex, the hydrogen occupies an interstitial position and is not crowded by neighboring atoms. If these trends are general, then hydrostatic pressure may be a powerful tool in determining the position of the hydrogen atom(s) in a complex. In AlSb, pressure was utilized to resolve a mystery as to why the Se-D complex gives rise to one stretch mode peak while the Se-H stretch mode splits into three peaks. This anomalous splitting is explained in terms of a new resonant interaction between the stretch mode and combination modes involving a wag mode harmonic and extended lattice phonons. The interaction gives rise to vibrational modes with both localized and extended components. When the temperature or hydrostatic pressure is varied, the modes exhibit anti-crossing behavior.

  10. Hydrogen evolution reaction catalyst

    DOEpatents

    Subbaraman, Ram; Stamenkovic, Vojislav; Markovic, Nenad; Tripkovic, Dusan

    2016-02-09

    Systems and methods for a hydrogen evolution reaction catalyst are provided. Electrode material includes a plurality of clusters. The electrode exhibits bifunctionality with respect to the hydrogen evolution reaction. The electrode with clusters exhibits improved performance with respect to the intrinsic material of the electrode absent the clusters.

  11. Thick film hydrogen sensor

    DOEpatents

    Hoffheins, Barbara S.; Lauf, Robert J.

    1995-01-01

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  12. Thick film hydrogen sensor

    DOEpatents

    Hoffheins, B.S.; Lauf, R.J.

    1995-09-19

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors. 8 figs.

  13. Towards a Hydrogen Economy

    SciTech Connect

    Sherif, S.A.; Barbir, Frano; Veziroglu, T.N.

    2005-07-01

    From electrolysis and thermolysis to production from biomass, hydrogen production methods are falling into place. So is storage, via all modes of gaseous, liquid, slush, and metal hydride systems. But proponents need to address the perception that hydrogen poses a severe safety risk, since the evidence suggests its risks are of the same order of magnitude as gasoline or natural gas.

  14. Hydrogen permeation through metals

    SciTech Connect

    Huhn, D.K.

    1985-01-01

    The permeation of hydrogen through metals was studied both theoretically and experimentally. Gas phase permeation experiments with nickel, iron, and iron-titanium alloys were done at low temperatures, 270 to 343 K, and high temperatures, 751 to 384 K, with hydrogen pressures ranging from 10/sup 3/ to 10/sup 5/ Pa. Experiments at low temperatures used an electrochemical cell to detect the permeating hydrogen, deuterium, or hydrogen-deuterium flux. At high temperatures a vacuum system equipped with a mass spectrometer measured the permeating hydrogen flux. The permeability and diffusivity of hydrogen through nickel membranes, 10/sup -4/ to 10/sup -5/ m in thickness, was measured in the temperature range of 580 to 270 K. The experimental results did not exhibit postulated surface effects; however, trapping of hydrogen was observed with a trap density of 2.5 x 10/sup 23/ sites/m/sup 3/ and a binding energy of 33 kJ/mole. The permeability of hydrogen through iron-titanium alloys increased with titanium concentration with a maximum increase of approximately 10% for a Fe-3.04 wt% Ti alloy compared to pure iron. High temperature diffusivity measurements showed a small decrease in diffusivity with titanium concentration; therefore, the solubility increased.

  15. Hydrogen in amorphous silicon

    SciTech Connect

    Peercy, P. S.

    1980-01-01

    The structural aspects of amorphous silicon and the role of hydrogen in this structure are reviewed with emphasis on ion implantation studies. In amorphous silicon produced by Si ion implantation of crystalline silicon, the material reconstructs into a metastable amorphous structure which has optical and electrical properties qualitatively similar to the corresponding properties in high-purity evaporated amorphous silicon. Hydrogen studies further indicate that these structures will accomodate less than or equal to 5 at.% hydrogen and this hydrogen is bonded predominantly in a monohydride (SiH/sub 1/) site. Larger hydrogen concentrations than this can be achieved under certain conditions, but the excess hydrogen may be attributed to defects and voids in the material. Similarly, glow discharge or sputter deposited amorphous silicon has more desirable electrical and optical properties when the material is prepared with low hydrogen concentration and monohydride bonding. Results of structural studies and hydrogen incorporation in amorphous silicon were discussed relative to the different models proposed for amorphous silicon.

  16. Hydrogen utilization and alternatives

    NASA Technical Reports Server (NTRS)

    Manvi, R.; Caputo, R.; Fujita, T.

    1975-01-01

    The historical uses of hydrogen are described along with potential new uses which could develop as a result of the diminishing supply of conventional fossil fuels such as natural gas. A perspective view of hydrogen, both as a chemical feedstock and as a fuel, is necessary to understand its relationship to the overall national energy projections. These projections, which show energy usage in terms of use sectors, forms of energy, and sources of energy, do not specifically identify hydrogen as a component of the energy system. By superimposing the traditional roles upon the new opportunities for hydrogen on the energy projections, the role of hydrogen and future projections is developed within the context of the national energy projections. Use, supply, and other factors affecting application are interrelated and are discussed.

  17. Hydrogen Fuel Quality

    SciTech Connect

    Rockward, Tommy

    2012-07-16

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

  18. Challenges in hydrogen storage

    NASA Astrophysics Data System (ADS)

    Schüth, F.

    2009-09-01

    Hydrogen is one possible medium for energy storage and transportation in an era beyond oil. Hydrogen appears to be especially promising in connection with electricity generation in polymer electrolyte membrane (PEM) fuel cells in cars. However, before such technologies can be implemented on a larger scale, satisfactory solutions for on-board storage of hydrogen are required. This is a difficult task due to the low volumetric and gravimetric storage density on a systems level which can be achieved so far. Possibilities include cryogenic storage as liquid hydrogen, high pressure storage at 70 MPa, (cryo)adsorptive storage, or various chemical methods of binding and releasing hydrogen. This survey discusses the different options and the associated advantages and disadvantages.

  19. Hydrogen Peroxide Concentrator

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F.

    2007-01-01

    A relatively simple and economical process and apparatus for concentrating hydrogen peroxide from aqueous solution at the point of use have been invented. The heart of the apparatus is a vessel comprising an outer shell containing tubular membranes made of a polymer that is significantly more permeable by water than by hydrogen peroxide. The aqueous solution of hydrogen peroxide to be concentrated is fed through the interstitial spaces between the tubular membranes. An initially dry sweep gas is pumped through the interiors of the tubular membranes. Water diffuses through the membranes and is carried away as water vapor mixed into the sweep gas. Because of the removal of water, the hydrogen peroxide solution flowing from the vessel at the outlet end is more concentrated than that fed into the vessel at the inlet end. The sweep gas can be air, nitrogen, or any other gas that can be conveniently supplied in dry form and does not react chemically with hydrogen peroxide.

  20. The microstructures and electrochemical performances of La0.6Gd0.2Mg0.2Ni3.0Co0.5-xAlx (x=0-0.5) hydrogen storage alloys as negative electrodes for nickel/metal hydride secondary batteries

    NASA Astrophysics Data System (ADS)

    Li, Rongfeng; Xu, Peizhen; Zhao, Yamin; Wan, Jing; Liu, Xiaofang; Yu, Ronghai

    2014-12-01

    La0.6Gd0.2Mg0.2Ni3.0Co0.5-xAlx (x = 0-0.5) hydrogen storage alloys were prepared by induction melting followed by annealing treatment at 1173 K for 8 h. The effects of substitution Al for Co on the microstructures and electrochemical performances were studied systematically. The structure analyses show that all alloys consist of multiphase structures such as (La, Mg)2Ni7 phase, (La, Mg) Ni3 phase and LaNi5 phase. The abundance of (La, Mg)2Ni7 phase decreases while the abundance of LaNi5 phase and (La, Mg)Ni3 phase increases directly as the Al content increasing. The electrochemical tests show that the maximum discharge capacity of alloy electrodes are almost unchanged when x ≤ 0.2 while the cyclic stability of the alloy electrode are improved significantly after proper amount of Al substitution for Co. The alloy electrode with x = 0.1 exhibits the better balance between discharge capacity and cycling life than any others. Moreover, at the discharge current density of 900 mA g-1, the high rate dischargeability (HRD) of the alloy electrodes decreases with increasing Al substitution and the relative analyses reveal that the charge transfer on alloy surface is more important than the hydrogen diffusion in alloy bulk for the kinetic properties of the alloy electrodes.

  1. Metal-Hydrogen Phase Diagrams in the Vicinity of Melting Temperatures

    SciTech Connect

    Shapovalov, V.I.

    1999-01-06

    Hydrogen-metal interaction phenomena belong to the most exciting challenges of today's physical metallurgy and physics of solids due to the uncommon behavior of hydrogen in condensed media and to the need for understanding hydrogen's strong negative impact on properties of some high-strength steels and.alloys. The paper cites and summarizes research data on fundamental thermodynamic characteristics of hydrogen in some metals that absorb it endothermally at elevated temperatures. For a number of metal-hydrogen systems, information on some phase diagrams previously not available to the English-speaking scientific community is presented.

  2. Three chamber negative ion source

    DOEpatents

    Leung, Ka-Ngo; Ehlers, Kenneth W.; Hiskes, John R.

    1985-01-01

    A negative ion vessel is divided into an excitation chamber, a negative ionization chamber and an extraction chamber by two magnetic filters. Input means introduces neutral molecules into a first chamber where a first electron discharge means vibrationally excites the molecules which migrate to a second chamber. In the second chamber a second electron discharge means ionizes the molecules, producing negative ions which are extracted into or by a third chamber. A first magnetic filter prevents high energy electrons from entering the negative ionization chamber from the excitation chamber. A second magnetic filter prevents high energy electrons from entering the extraction chamber from the negative ionizing chamber. An extraction grid at the end of the negative ion vessel attracts negative ions into the third chamber and accelerates them. Another grid, located adjacent to the extraction grid, carries a small positive voltage in order to inhibit positive ions from migrating into the extraction chamber and contour the plasma potential. Additional electrons can be suppressed from the output flux using ExB forces provided by magnetic field means and the extractor grid electric potential.

  3. Isotropic Negative Thermal Expansion Metamaterials.

    PubMed

    Wu, Lingling; Li, Bo; Zhou, Ji

    2016-07-13

    Negative thermal expansion materials are important and desirable in science and engineering applications. However, natural materials with isotropic negative thermal expansion are rare and usually unsatisfied in performance. Here, we propose a novel method to achieve two- and three-dimensional negative thermal expansion metamaterials via antichiral structures. The two-dimensional metamaterial is constructed with unit cells that combine bimaterial strips and antichiral structures, while the three-dimensional metamaterial is fabricated by a multimaterial 3D printing process. Both experimental and simulation results display isotropic negative thermal expansion property of the samples. The effective coefficient of negative thermal expansion of the proposed models is demonstrated to be dependent on the difference between the thermal expansion coefficient of the component materials, as well as on the circular node radius and the ligament length in the antichiral structures. The measured value of the linear negative thermal expansion coefficient of the three-dimensional sample is among the largest achieved in experiments to date. Our findings provide an easy and practical approach to obtaining materials with tunable negative thermal expansion on any scale. PMID:27333052

  4. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). ItÆs made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  5. Lower body negative pressure device

    NASA Technical Reports Server (NTRS)

    Nolte, R. W.

    1977-01-01

    The Lower Body Negative Pressure Device was used, in the space environment, to stress the astronaut's cardiovascular system, to determine the extent and time course of his cardiovascular deconditioning and to determine whether in-flight data from experiment M092, Lower Body Negative Pressure, would be useful in predicting postflight status of orthostatic tolerance. The lower portion of the subject's body was enclosed in this device for the purpose of applying regulated and controlled negative pressure. A description is given of the device.

  6. Measuring Hydrogen Concentrations in Metals

    NASA Technical Reports Server (NTRS)

    Danford, M. D.

    1985-01-01

    Commercial corrosion-measurement system adapted to electrochemical determination of hydrogen concentrations in metals. New technique based on diffusion of hydrogen through foil specimen of metal. In sample holder, hydrogen produced on one side of foil, either by corrosion reaction or by cathodic current. Hydrogen diffused through foil removed on other side by constant anode potential, which leads to oxidation of hydrogen to water. Anode current is measure of concentration of hydrogen diffusing through foil. System used to study hydrogen uptake, hydrogen elimination by baking, effect of heat treatment, and effect of electroplating on high-strength steels.

  7. Photoelectrochemical hydrogen production

    SciTech Connect

    Rocheleau, R.; Misra, A.; Miller, E.

    1998-08-01

    A significant component of the US DOE Hydrogen Program is the development of a practical technology for the direct production of hydrogen using a renewable source of energy. High efficiency photoelectrochemical systems to produce hydrogen directly from water using sunlight as the energy source represent one of the technologies identified by DOE to meet this mission. Reactor modeling and experiments conducted at UH provide strong evidence that direct solar-to-hydrogen conversion efficiency greater than 10% can be expected using photoelectrodes fabricated from low-cost, multijunction (MJ) amorphous silicon solar cells. Solar-to-hydrogen conversion efficiencies as high as 7.8% have been achieved using a 10.3% efficient MJ amorphous silicon solar cell. Higher efficiency can be expected with the use of higher efficiency solar cells, further improvement of the thin film oxidation and reduction catalysts, and optimization of the solar cell for hydrogen production rather than electricity production. Hydrogen and oxygen catalysts developed under this project are very stable, exhibiting no measurable degradation in KOH after over 13,000 hours of operation. Additional research is needed to fully optimize the transparent, conducting coatings which will be needed for large area integrated arrays. To date, the best protection has been afforded by wide bandgap amorphous silicon carbide films.

  8. Piezoelectric enhancement under negative pressure

    NASA Astrophysics Data System (ADS)

    Kvasov, Alexander; McGilly, Leo J.; Wang, Jin; Shi, Zhiyong; Sandu, Cosmin S.; Sluka, Tomas; Tagantsev, Alexander K.; Setter, Nava

    2016-07-01

    Enhancement of ferroelectric properties, both spontaneous polarization and Curie temperature under negative pressure had been predicted in the past from first principles and recently confirmed experimentally. In contrast, piezoelectric properties are expected to increase by positive pressure, through polarization rotation. Here we investigate the piezoelectric response of the classical PbTiO3, Pb(Zr,Ti)O3 and BaTiO3 perovskite ferroelectrics under negative pressure from first principles and find significant enhancement. Piezoelectric response is then tested experimentally on free-standing PbTiO3 and Pb(Zr,Ti)O3 nanowires under self-sustained negative pressure, confirming the theoretical prediction. Numerical simulations verify that negative pressure in nanowires is the origin of the enhanced electromechanical properties. The results may be useful in the development of highly performing piezoelectrics, including lead-free ones.

  9. Piezoelectric enhancement under negative pressure.

    PubMed

    Kvasov, Alexander; McGilly, Leo J; Wang, Jin; Shi, Zhiyong; Sandu, Cosmin S; Sluka, Tomas; Tagantsev, Alexander K; Setter, Nava

    2016-01-01

    Enhancement of ferroelectric properties, both spontaneous polarization and Curie temperature under negative pressure had been predicted in the past from first principles and recently confirmed experimentally. In contrast, piezoelectric properties are expected to increase by positive pressure, through polarization rotation. Here we investigate the piezoelectric response of the classical PbTiO3, Pb(Zr,Ti)O3 and BaTiO3 perovskite ferroelectrics under negative pressure from first principles and find significant enhancement. Piezoelectric response is then tested experimentally on free-standing PbTiO3 and Pb(Zr,Ti)O3 nanowires under self-sustained negative pressure, confirming the theoretical prediction. Numerical simulations verify that negative pressure in nanowires is the origin of the enhanced electromechanical properties. The results may be useful in the development of highly performing piezoelectrics, including lead-free ones. PMID:27396411

  10. Chemochromic Hydrogen Leak Detectors

    NASA Technical Reports Server (NTRS)

    Roberson, Luke; Captain, Janine; Williams, Martha; Smith, Trent; Tate, LaNetra; Raissi, Ali; Mohajeri, Nahid; Muradov, Nazim; Bokerman, Gary

    2009-01-01

    At NASA, hydrogen safety is a key concern for space shuttle processing. Leaks of any level must be quickly recognized and addressed due to hydrogen s lower explosion limit. Chemo - chromic devices have been developed to detect hydrogen gas in several embodiments. Because hydrogen is odorless and colorless and poses an explosion hazard, there is an emerging need for sensors to quickly and accurately detect low levels of leaking hydrogen in fuel cells and other advanced energy- generating systems in which hydrogen is used as fuel. The device incorporates a chemo - chromic pigment into a base polymer. The article can reversibly or irreversibly change color upon exposure to hydrogen. The irreversible pigment changes color from a light beige to a dark gray. The sensitivity of the pigment can be tailored to its application by altering its exposure to gas through the incorporation of one or more additives or polymer matrix. Furthermore, through the incorporation of insulating additives, the chemochromic sensor can operate at cryogenic temperatures as low as 78 K. A chemochromic detector of this type can be manufactured into any feasible polymer part including injection molded plastic parts, fiber-spun textiles, or extruded tapes. The detectors are simple, inexpensive, portable, and do not require an external power source. The chemochromic detectors were installed and removed easily at the KSC launch pad without need for special expertise. These detectors may require an external monitor such as the human eye, camera, or electronic detector; however, they could be left in place, unmonitored, and examined later for color change to determine whether there had been exposure to hydrogen. In one type of envisioned application, chemochromic detectors would be fabricated as outer layers (e.g., casings or coatings) on high-pressure hydrogen storage tanks and other components of hydrogen-handling systems to provide visible indications of hydrogen leaks caused by fatigue failures or

  11. Color Changing Hydrogen Sensors

    NASA Technical Reports Server (NTRS)

    Roberson, Luke B.; Williams, Martha; Captain, Janine E.; Mohajeri, Nahid; Raissi, Ali

    2015-01-01

    During the Space Shuttle Program, one of the most hazardous operation that occurred was the loading of liquid hydrogen (LH2) during fueling operations of the spacecraft. Due to hydrogen's low explosive limit, any amount leaked could lead to catastrophic event. Hydrogen's chemical properties make it ideal as a rocket fuel; however, the fuel is deemed unsafe for most commercial use because of the inability to easily detect the gas leaking. The increased use of hydrogen over traditional fossil fuels would reduce greenhouse gases and America's dependency on foreign oil. Therefore a technology that would improve safety at NASA and in the commercial sector while creating a new economic sector would have a huge impact to NASA's mission. The Chemochromic Detector for sensing hydrogen gas leakage is a color-changing detector that is useful in any application where it is important to know not only the presence but also the location of the hydrogen gas leak. This technology utilizes a chemochromicpigment and polymer matrix that can be molded or spun into rigid or pliable shapes useable in variable temperature environments including atmospheres of inert gas, hydrogen gas, or mixtures of gases. A change in color of the detector material indicates where gaseous hydrogen leaks are occurring. The irreversible sensor has a dramatic color change from beige to dark grey and remains dark grey after exposure. A reversible pigment changes from white to blue in the presence of hydrogen and reverts back to white in the presence of oxygen. Both versions of the sensor's pigments were comprised of a mixture of a metal oxide substrate and a hydro-chromic compound (i.e., the compound that changed color in the presence of hydrogen) and immediately notified the operator of the presence of low levels of hydrogen. The detector can be used in a variety of formats including paint, tape, caulking, injection molded parts, textiles and fabrics, composites, and films. This technology brings numerous

  12. Chromatographic hydrogen isotope separation

    DOEpatents

    Aldridge, F.T.

    Intermetallic compounds with the CaCu/sub 5/ type of crystal structure, particularly LaNiCo/sub 4/ and CaNi/sub 5/, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation column. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale multi-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen cn produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  13. Chromatographic hydrogen isotope separation

    DOEpatents

    Aldridge, Frederick T.

    1981-01-01

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  14. Biological hydrogen production

    SciTech Connect

    Benemann, J.R.

    1995-11-01

    Biological hydrogen production can be accomplished by either thermochemical (gasification) conversion of woody biomass and agricultural residues or by microbiological processes that yield hydrogen gas from organic wastes or water. Biomass gasification is a well established technology; however, the synthesis gas produced, a mixture of CO and H{sub 2}, requires a shift reaction to convert the CO to H{sub 2}. Microbiological processes can carry out this reaction more efficiently than conventional catalysts, and may be more appropriate for the relatively small-scale of biomass gasification processes. Development of a microbial shift reaction may be a near-term practical application of microbial hydrogen production.

  15. Extremely weak hydrogen flames

    SciTech Connect

    Lecoustre, V.R.; Sunderland, P.B.; Chao, B.H.; Axelbaum, R.L.

    2010-11-15

    Hydrogen jet diffusion flames were observed near their quenching limits. These involved downward laminar flow of hydrogen from a stainless steel hypodermic tube with an inside diameter of 0.15 mm. Near their quenching limits these flames had hydrogen flow rates of 3.9 and 2.1 {mu}g/s in air and oxygen, respectively. Assuming complete combustion, the associated heat release rates are 0.46 and 0.25 W. To the authors' knowledge, these are the weakest self-sustaining steady flames ever observed. (author)

  16. Factors identified for negative appendicectomies.

    PubMed

    Mirza, M R; Habib, L; Jaleel, F

    2009-07-01

    The study was done, to determine the factors for negative appendicectomies. This prospective descriptive study includes patients managed at four non teaching and a teaching hospital of Karachi from March 2006 to February 2008. One hundred and sixty eight patients underwent appendicectomy during the study period. Details of clinical presentations, investigations, operative findings and histopathology were entered and analyzed. Literature search was aimed to see the negative appendicectomy rate (NAR) in last ten years despite using diagnostic tools (clinical scoring, diagnostic imaging and laparoscopy). In this study a total number of 168 patients under went appendicectomy. Normal appendices were found in 31 patients (negative appendicectomy rate was 18.45%) and associated pathology was seen in 13 patients, an incidental finding of Meckel's diverticulum in 5 patients and no other pathology was seen in 13 patients. The different factors which we identified for negative appendicectomies in our practice were non teaching hospitals where diagnostic scoring system was difficult to apply, female gender, selective use of imaging modality, other pathologies presenting with pain in right lower quadrant (RLQ) and requiring surgical intervention, and non-availability of CT scan and laparoscopy. Despite many advances in diagnostic system, acute appendicitis is still a diagnostic dilemma at times. Although there is no substitute for clinical judgment but in sub groups of patients in whom the possibility of negative appendicectomy is high, diagnostic modalities should be used judiciously to decrease the negative exploration. PMID:19623147

  17. [Negative symptoms and cerebral imaging].

    PubMed

    Kaladjian, A; Belzeaux, R; Adida, M; Azorin, J-M

    2015-12-01

    A number of neuroanatomical and neurofonctional abnormalities have been evidenced by cerebral imaging studies in patients suffering from schizophrenia. Nevertheless, those specifically associated with the negative symptoms of this disease are still insufficiently known. This work is a review of selected studies that have assessed the brain correlates of negative symptoms in schizophrenia. Approaches using structural imaging have highlighted reduction of gray matter density or cortical thickness associated with negative symptoms, which is rather sparsely distributed within the frontal and temporal regions, localized nevertheless more particularly in the frontal medial and orbitofrontal areas, as well as the amygdalo-hippocampic complex. These deficits are concurrent with a loss of integrity of the principal paths of white matter tracts between frontal and limbic regions. On the other hand, neurofonctional abnormalities associated with negative symptoms involve especially the frontal areas and limbic striatum. A disturbed functioning within the fronto-striatal loops, related to a striatal dopaminergic deficit, may represent a potential explanatory hypothesis of the negative symptoms of schizophrenia, as suggested by studies using Positron Emission Tomography on this topic or neuroimaging studies on the effects of antipsychotics. A better identification of the cerebral abnormalities associated with the negative dimension of schizophrenia, with regard to the lateralization of these abnormalities or to their changes during the course of the disease, could offer new therapeutic modalities for the treatment of this dimension which, until now, remains few responsive to conventional pharmacological treatments. PMID:26776387

  18. The columbium-hydrogen system and hydrogen embrittlement of columbium

    NASA Technical Reports Server (NTRS)

    Walter, R. J.

    1970-01-01

    Columbium specimens are charged uniformly with hydrogen allowing accurate measurement of the hydrogen content by a procedure involving the removal of hydrogen from flowing argon at 2000 degrees F. Hydrogen content effects on the ductile-to-transition temperature are determined for temperatures between 200 and 600 degrees F.

  19. Structural investigations of hydrogenated epitaxial graphene grown on 4H-SiC (0001)

    SciTech Connect

    Tokarczyk, M.; Kowalski, G. Stępniewski, R.; Możdżonek, M.; Strupiński, W.; Ciepielewski, P.; Borysiuk, J.

    2013-12-09

    Structural investigations of hydrogenated epitaxial graphene grown on SiC(0001) are presented. It is shown that hydrogen plays a dual role. In addition to contributing to the well-known removal of the buffer layer, it goes between the graphene planes, resulting in an increase of the interlayer spacing to 3.6 Å–3.8 Å. It is explained by the intercalation of molecular hydrogen between carbon planes, which is followed by H{sub 2} dissociation, resulting in negatively charged hydrogen atoms trapped between the graphene layers, with some addition of covalent bonding to carbon atoms. Negatively charged hydrogen may be responsible for p-doping observed in hydrogenated multilayer graphene.

  20. Hydrogen storage compositions

    DOEpatents

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  1. Photoelectrochemical hydrogen production

    SciTech Connect

    Rocheleau, R.E.; Miller, E.; Misra, A.

    1996-10-01

    The large-scale production of hydrogen utilizing energy provided by a renewable source to split water is one of the most ambitious long-term goals of the U.S. Department of Energy`s Hydrogen Program. One promising option to meet this goal is direct photoelectrolysis in which light absorbed by semiconductor-based photoelectrodes produces electrical power internally to split water into hydrogen and oxygen. Under this program, direct solar-to-chemical conversion efficiencies as high as 7.8 % have been demonstrated using low-cost, amorphous-silicon-based photoelectrodes. Detailed loss analysis models indicate that solar-to-chemical conversion greater than 10% can be achieved with amorphous-silicon-based structures optimized for hydrogen production. In this report, the authors describe the continuing progress in the development of thin-film catalytic/protective coatings, results of outdoor testing, and efforts to develop high efficiency, stable prototype systems.

  2. Hydrogen chloride test set

    NASA Technical Reports Server (NTRS)

    Workman, G. L.

    1976-01-01

    Detector uses tertiary amine, which makes reaction fairly specific for relatively small highly polarized hydrogen chloride molecule. Reaction is monitored by any microbalance capable of measuring extremely small mass differences in real time.

  3. Hydrogen in titanium alloys

    SciTech Connect

    Wille, G W; Davis, J W

    1981-04-01

    The titanium alloys that offer properties worthy of consideration for fusion reactors are Ti-6Al-4V, Ti-6Al-2Sn-4Zr-2Mo-Si (Ti-6242S) and Ti-5Al-6Sn-2Zr-1Mo-Si (Ti-5621S). The Ti-6242S and Ti-5621S are being considered because of their high creep resistance at elevated temperatures of 500/sup 0/C. Also, irradiation tests on these alloys have shown irradiation creep properties comparable to 20% cold worked 316 stainless steel. These alloys would be susceptible to slow strain rate embrittlement if sufficient hydrogen concentrations are obtained. Concentrations greater than 250 to 500 wppm hydrogen and temperatures lower than 100 to 150/sup 0/C are approximate threshold conditions for detrimental effects on tensile properties. Indications are that at the elevated temperature - low hydrogen pressure conditions of the reactors, there would be negligible hydrogen embrittlement.

  4. Hydrogen on the rise

    NASA Astrophysics Data System (ADS)

    2016-08-01

    Using hydrogen as an energy carrier has long been discussed as a route to a greener future, and although headway has been less significant than many hoped, recent developments point to tangible progress.

  5. Fiber optic hydrogen sensor

    SciTech Connect

    Butler, M.A.; Sanchez, R.; Dulleck, G.R.

    1996-05-01

    This report covers the development of fiber optic hydrogen and temperature sensors for monitoring dissolved hydrogen gas in transformer oil. The concentration of hydrogen gas is a measure of the corona and spark discharge within the transformer and reflects the state of health of the transformer. Key features of the instrument include use of palladium alloys to enhance hydrogen sensitivity, a microprocessor controlled instrument with RS-232, liquid crystal readout, and 4-20 ma. current loop interfaces. Calibration data for both sensors can be down loaded to the instrument through the RS-232 interface. This project was supported by the Technology Transfer Initiative in collaboration with J. W. Harley, Inc. through the mechanism of a cooperative research and development agreement (CRADA).

  6. Hydrogen-fueled engine

    NASA Technical Reports Server (NTRS)

    Laumann, E. A.; Reynolds, R. K. (Inventor)

    1978-01-01

    A hydrogen-oxygen fueled internal combustion engine is described, which utilizes an inert gas, such as argon, as a working fluid to increase the efficiency of the engine, eliminate pollution, and facilitate operation of a closed cycle energy system. In a system where sunlight or other intermittent energy source is available to separate hydrogen and oxygen from water, the oxygen and inert gas are taken into a diesel engine into which hydrogen is injected and ignited. The exhaust is cooled so that it contains only water and the inert gas. The inert gas in the exhaust is returned to the engine for use with fresh oxygen, while the water in the exhaust is returned to the intermittent energy source for reconversion to hydrogen and oxygen.

  7. Florida Hydrogen Initiative

    SciTech Connect

    Block, David L

    2013-06-30

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring

  8. The Hydrogen Economy

    NASA Astrophysics Data System (ADS)

    Crabtree, George W.; Dresselhaus, Mildred S.; Buchanan, Michelle V.

    2004-12-01

    If the fuel cell is to become the modern steam engine, basic research must provide breakthroughs in understanding, materials, and design to make a hydrogen-based energy system a vibrant and competitive force.

  9. The ENEA F-CUBE Facility: Trends in R.F. driven compact FELs and related diagnostics

    SciTech Connect

    Doria, A.; Gallerano, G.P.; Giovenale, E.

    1995-12-31

    The Frascati FEL Facility F-CUBE (FEL-Compact for User Basic Experiment) currently operates in the mm-wave region providing about 600 hrs of beam time per year to users. This FEL is a low cost compact device intended to be the first step in making the FEL a laboratory tool. It exploits some unique features like short pulses with coherent emission seeding and the dispersion properties of a waveguide resonator at {open_quotes}zero slippage{close_quotes} to provide wide band tunability. The system is presently being upgraded to extend these characteristics into the far infrared. A new NdFeB permanent magnet undulator has been built and magnetic measurements have been performed. FEL tunability in the interval from 400 to 900 pm will be provided by the variation of the undulator gap and of the gap of the planar waveguide in the resonator. Due to the short electron bunch duration coherent spontaneous emission is expected also in this wavelength range. Its effect on the FEL performance will be discussed together with a comparison of different coherent emission mechanisms, like coherent transition radiation (CTR), which can be used as a diagnostic tool.

  10. Numerical simulation of an atmospheric pressure RF-driven plasma needle and heat transfer to adjacent human skin using COMSOL.

    PubMed

    Schröder, Maximilian; Ochoa, Angel; Breitkopf, Cornelia

    2015-01-01

    Plasma medicine is an emerging field where plasma physics is used for therapeutical applications. Temperature is an important factor to take into account with respect to the applications of plasma to biological systems. During the treatment, the tissue temperature could increase to critical values. In this work, a model is presented, which is capable of predicting the skin temperature during a treatment with a radio frequency driven plasma needle. The main gas was helium. To achieve this, a discharge model was coupled to a heat transfer and fluid flow model. The results provide maximum application times for different power depositions in order to avoid reaching critical skin temperatures. PMID:25850416

  11. Characteristics of a RF-Driven Ion Source for a Neutron Generator Used For Associated Particle Imaging

    SciTech Connect

    Wu, Ying; Hurley, John P.; Ji, Qing; Kwan, Joe; Leung, Ka-Ngo

    2008-08-08

    We present recent work on a prototype compact neutron generator for associated particle imaging (API). API uses alpha particles that are produced simultaneously with neutrons in the deuterium-tritium (2D(3T,n)4 alpha) fusion reaction to determine the direction of the neutrons upon exiting the reaction. This method determines the spatial position of each neutron interaction and requires the neutrons to be generated from a small spot in order to achieve high spatial resolution. The ion source for API is designed to produce a focused ion beam with a beam spot diameter of 1-mm or less on the target. We use an axial type neutron generator with a predicted neutron yield of 108 n/s for a 50 muA D/T ion beam current accelerated to 80 kV. The generator utilizes a RF planar spiral antenna at 13.56 MHz to create a highly efficient inductively-coupled plasma at the ion source. Experimental results show that beams with an atomic ion fraction of over 80percent can be obtained while utilizing only 100 watts of RF power in the ion source. A single acceleration gap with a secondary electron suppression electrode is used in the tube. Experimental results, such as the current density, atomic ion fraction, electron temperature, and electron density, from ion source testing will be discussed.

  12. Thermal cracking with hydrogen donor diluent

    SciTech Connect

    Derbyshire, F.; Varghese, P.; Whitehurst, D.D.

    1983-07-26

    An improved hydrogen donor for hydrogen donor diluent cracking is provided by extraction with naphtha from the cracked product and hydrogenation by hydrogen transfer from a lower boiling hydrogen donor such as tetralin.

  13. The hydrogen issue.

    PubMed

    Armaroli, Nicola; Balzani, Vincenzo

    2011-01-17

    Hydrogen is often proposed as the fuel of the future, but the transformation from the present fossil fuel economy to a hydrogen economy will need the solution of numerous complex scientific and technological issues, which will require several decades to be accomplished. Hydrogen is not an alternative fuel, but an energy carrier that has to be produced by using energy, starting from hydrogen-rich compounds. Production from gasoline or natural gas does not offer any advantage over the direct use of such fuels. Production from coal by gasification techniques with capture and sequestration of CO₂ could be an interim solution. Water splitting by artificial photosynthesis, photobiological methods based on algae, and high temperatures obtained by nuclear or concentrated solar power plants are promising approaches, but still far from practical applications. In the next decades, the development of the hydrogen economy will most likely rely on water electrolysis by using enormous amounts of electric power, which in its turn has to be generated. Producing electricity by burning fossil fuels, of course, cannot be a rational solution. Hydroelectric power can give but a very modest contribution. Therefore, it will be necessary to generate large amounts of electric power by nuclear energy of by renewable energies. A hydrogen economy based on nuclear electricity would imply the construction of thousands of fission reactors, thereby magnifying all the problems related to the use of nuclear energy (e.g., safe disposal of radioactive waste, nuclear proliferation, plant decommissioning, uranium shortage). In principle, wind, photovoltaic, and concentrated solar power have the potential to produce enormous amounts of electric power, but, except for wind, such technologies are too underdeveloped and expensive to tackle such a big task in a short period of time. A full development of a hydrogen economy needs also improvement in hydrogen storage, transportation and distribution

  14. Pionic hydrogen and deuterium

    NASA Astrophysics Data System (ADS)

    Gotta, Detlev; Amaro, F. D.; Anagnostopoulos, D. F.; Bühler, P.; Gorke, H.; Covita, D. S.; Fuhrmann, H.; Gruber, A.; Hennebach, M.; Hirtl, A.; Ishiwatari, T.; Indelicato, P.; Le Bigot, E.-O.; Marton, J.; Nekipelov, M.; dos Santos, J. M. F.; Schlesser, S.; Schmid, Ph.; Simons, L. M.; Strauch, Th.; Trassinelli, M.; Veloso, J. F. C. A.; Zmeskal, J.

    The ground-state level shifts and broadenings of the hydrogen isotopes caused by the strong interaction have been redetermined by using a high-resolution crystal spectrometer. An additional measurement of muonic hydrogen reveals properties of the de-excitation cascade of such electrically neutral exotic atoms, in particular Coulomb de-excitation, the understanding of which is essential for the analysis of the hadronic-atom data.

  15. Pionic hydrogen and deuterium

    NASA Astrophysics Data System (ADS)

    Gotta, Detlev; Amaro, F. D.; Anagnostopoulos, D. F.; Bühler, P.; Gorke, H.; Covita, D. S.; Fuhrmann, H.; Gruber, A.; Hennebach, M.; Hirtl, A.; Ishiwatari, T.; Indelicato, P.; Le Bigot, E.-O.; Marton, J.; Nekipelov, M.; dos Santos, J. M. F.; Schlesser, S.; Schmid, Ph.; Simons, L. M.; Strauch, Th.; Trassinelli, M.; Veloso, J. F. C. A.; Zmeskal, J.

    2012-05-01

    The ground-state level shifts and broadenings of the hydrogen isotopes caused by the strong interaction have been redetermined by using a high-resolution crystal spectrometer. An additional measurement of muonic hydrogen reveals properties of the de-excitation cascade of such electrically neutral exotic atoms, in particular Coulomb de-excitation, the understanding of which is essential for the analysis of the hadronic-atom data.

  16. Hydrogen recovery process

    DOEpatents

    Baker, Richard W.; Lokhandwala, Kaaeid A.; He, Zhenjie; Pinnau, Ingo

    2000-01-01

    A treatment process for a hydrogen-containing off-gas stream from a refinery, petrochemical plant or the like. The process includes three separation steps: condensation, membrane separation and hydrocarbon fraction separation. The membrane separation step is characterized in that it is carried out under conditions at which the membrane exhibits a selectivity in favor of methane over hydrogen of at least about 2.5.

  17. Cryogenic hydrogen release research.

    SciTech Connect

    LaFleur, Angela Christine

    2015-12-01

    The objective of this project was to devolop a plan for modifying the Turbulent Combustion Laboratory (TCL) with the necessary infrastructure to produce a cold (near liquid temperature) hydrogen jet. The necessary infrastructure has been specified and laboratory modifications are currently underway. Once complete, experiments from this platform will be used to develop and validate models that inform codes and standards which specify protection criteria for unintended releases from liquid hydrogen storage, transport, and delivery infrastructure.

  18. Lokiarchaeon is hydrogen dependent.

    PubMed

    Sousa, Filipa L; Neukirchen, Sinje; Allen, John F; Lane, Nick; Martin, William F

    2016-01-01

    The nature of the host that acquired the mitochondrion at the eukaryote origin is an important microbial evolutionary issue. Modern phylogenetics indicates that the host was an archaeon. The metagenome sequence of Candidatus Lokiarchaeon has identified it as being the closest relative of the host yet known. Here, we report comparative genomic evidence indicating that Lokiarchaeon is hydrogen dependent, as one theory for the eukaryote origin-the hydrogen hypothesis-predicts for the host lineage. PMID:27572645

  19. Hydrogen-powered flight

    NASA Technical Reports Server (NTRS)

    Smith, Timothy D.

    2005-01-01

    As the Nation moves towards a hydrogen economy the shape of aviation will change dramatically. To accommodate a switch to hydrogen the aircraft designs, propulsion, and power systems will look much different than the systems of today. Hydrogen will enable a number of new aircraft capabilities from high altitude long endurance remotely operated aircraft (HALE ROA) that will fly weeks to months without refueling to clean, zero emissions transport aircraft. Design and development of new hydrogen powered aircraft have a number of challenges which must be addressed before an operational system can become a reality. While the switch to hydrogen will be most outwardly noticeable in the aircraft designs of the future, other significant changes will be occurring in the environment. A switch to hydrogen for aircraft will completely eliminate harmful greenhouse gases such as carbon monoxide (CO), carbon dioxide (CO2), sulfur oxides (SOx), unburnt hydrocarbons and smoke. While these aircraft emissions are a small percentage of the amount produced on a daily basis, their placement in the upper atmosphere make them particularly harmful. Another troublesome gaseous emission from aircraft is nitrogen oxides (NOx) which contribute to ozone depletion in the upper atmosphere. Nitrogen oxide emissions are produced during the combustion process and are primarily a function of combustion temperature and residence time. The introduction of hydrogen to a gas turbine propulsion system will not eliminate NOx emissions; however the wide flammability range will make low NOx producing, lean burning systems feasible. A revolutionary approach to completely eliminating NOx would be to fly all electric aircraft powered by hydrogen air fuel cells. The fuel cells systems would only produce water, which could be captured on board or released in the lower altitudes. Currently fuel cell systems do not have sufficient energy densities for use in large aircraft, but the long term potential of eliminating

  20. Advanced Hydrogen Liquefaction Process

    SciTech Connect

    Schwartz, Joseph; Kromer, Brian; Neu, Ben; Jankowiak, Jerome; Barrett, Philip; Drnevich, Raymond

    2011-09-28

    The project identified and quantified ways to reduce the cost of hydrogen liquefaction, and reduce the cost of hydrogen distribution. The goal was to reduce the power consumption by 20% and then to reduce the capital cost. Optimizing the process, improving process equipment, and improving ortho-para conversion significantly reduced the power consumption of liquefaction, but by less than 20%. Because the efficiency improvement was less than the target, the program was stopped before the capital cost was addressed. These efficiency improvements could provide a benefit to the public to improve the design of future hydrogen liquefiers. The project increased the understanding of hydrogen liquefaction by modeling different processes and thoroughly examining ortho-para separation and conversion. The process modeling provided a benefit to the public because the project incorporated para hydrogen into the process modeling software, so liquefaction processes can be modeled more accurately than using only normal hydrogen. Adding catalyst to the first heat exchanger, a simple method to reduce liquefaction power, was identified, analyzed, and quantified. The demonstrated performance of ortho-para separation is sufficient for at least one identified process concept to show reduced power cost when compared to hydrogen liquefaction processes using conventional ortho-para conversion. The impact of improved ortho-para conversion can be significant because ortho para conversion uses about 20-25% of the total liquefaction power, but performance improvement is necessary to realize a substantial benefit. Most of the energy used in liquefaction is for gas compression. Improvements in hydrogen compression will have a significant impact on overall liquefier efficiency. Improvements to turbines, heat exchangers, and other process equipment will have less impact.

  1. Purdue Hydrogen Systems Laboratory

    SciTech Connect

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

    2011-12-28

    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts

  2. Nickel hydrogen bipolar battery electrode design

    NASA Technical Reports Server (NTRS)

    Puglisi, V. J.; Russell, P.; Verrier, D.; Hall, A.

    1985-01-01

    The preferred approach of the NASA development effort in nickel hydrogen battery design utilizes a bipolar plate stacking arrangement to obtain the required voltage-capacity configuration. In a bipolar stack, component designs must take into account not only the typical design considerations such as voltage, capacity and gas management, but also conductivity to the bipolar (i.e., intercell) plate. The nickel and hydrogen electrode development specifically relevant to bipolar cell operation is discussed. Nickel oxide electrodes, having variable type grids and in thicknesses up to .085 inch are being fabricated and characterized to provide a data base. A selection will be made based upon a system level tradeoff. Negative (hydrpogen) electrodes are being screened to select a high performance electrode which can function as a bipolar electrode. Present nickel hydrogen negative electrodes are not capable of conducting current through their cross-section. An electrode was tested which exhibits low charge and discharge polarization voltages and at the same time is conductive. Test data is presented.

  3. Hydrogen Delivery Technical Team Roadmap

    SciTech Connect

    2013-06-01

    The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen.

  4. Hydrogen Distribution and Delivery Infrastructure

    SciTech Connect

    2008-11-01

    This 2-page fact sheet provides a brief introduction to hydrogen delivery technologies. Intended for a non-technical audience, it explains how hydrogen is transported and delivered today, the challenges to delivering hydrogen for use as a widespread energy carrier, and the research goals for hydrogen delivery.

  5. Nanostructured materials for hydrogen storage

    DOEpatents

    Williamson, Andrew J.; Reboredo, Fernando A.

    2007-12-04

    A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

  6. Electrochemical hydrogen Storage Systems

    SciTech Connect

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the

  7. STME Hydrogen Mixer Study

    NASA Technical Reports Server (NTRS)

    Blumenthal, Rob; Kim, Dongmoon; Bache, George

    1992-01-01

    The hydrogen mixer for the Space Transportation Main Engine is used to mix cold hydrogen bypass flow with warm hydrogen coolant chamber gas, which is then fed to the injectors. It is very important to have a uniform fuel temperature at the injectors in order to minimize mixture ratio problems due to the fuel density variations. In addition, the fuel at the injector has certain total pressure requirements. In order to achieve these objectives, the hydrogen mixer must provide a thoroughly mixed fluid with a minimum pressure loss. The AEROVISC computational fluid dynamics (CFD) code was used to analyze the STME hydrogen mixer, and proved to be an effective tool in optimizing the mixer design. AEROVISC, which solves the Reynolds Stress-Averaged Navier-Stokes equations in primitive variable form, was used to assess the effectiveness of different mixer designs. Through a parametric study of mixer design variables, an optimal design was selected which minimized mixed fuel temperature variation and fuel mixer pressure loss. The use of CFD in the design process of the STME hydrogen mixer was effective in achieving an optimal mixer design while reducing the amount of hardware testing.

  8. Examining hydrogen transitions.

    SciTech Connect

    Plotkin, S. E.; Energy Systems

    2007-03-01

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  9. EDITORIAL: Negative ion based neutral beam injection

    NASA Astrophysics Data System (ADS)

    Hemsworth, R. S.

    2006-06-01

    It is widely recognized that neutral beam injection (NBI), i.e. the injection of high energy, high power, beams of H or D atoms, is a flexible and reliable system that has been the main heating system on a large variety of fusion devices, and NBI has been chosen as one of the three heating schemes of the International Tokomak Reactor (ITER). To date, all the NBI systems but two have been based on the neutralization (in a simple gas target) of positive hydrogen or deuterium ions accelerated to <100 keV/nucleon. Above that energy the neutralization of positive ions falls to unacceptably low values, and higher energy neutral beams have to be created by the neutralization of accelerated negative ions (in a simple gas target), as this remains high (approx60%) up to >1 MeV/nucleon. Unfortunately H- and D- are difficult to create, and the very characteristic that makes them attractive, the ease with which the electron is detached from the ion, means that it is difficult to create high concentrations or fluxes of them, and it is difficult to avoid substantial, collisional, losses in the extraction and acceleration processes. However, there has been impressive progress in negative ion sources and accelerators over the past decade, as demonstrated by the two pioneering, operational, multi-megawatt, negative ion based, NBI systems at LHD (180 keV, H0) and JT-60U (500 keV, D0), both in Japan. Nevertheless, the system proposed for ITER represents a substantial technological challenge as an increase is required in beam energy, to 1 MeV, D0, accelerated ion (D-) current, to 40 A, accelerated current density, 200 A m-2 of D-, and pulse length, to 1 h. At the Fourth IAEA Technical Meeting on Negative Ion Based Neutral Beam Injectors, hosted by the Consorzio RFX, Padova, Italy, 9-11 May 2005, the status of the R&D aimed at the realization of the injectors for ITER was presented. Because of the importance of this development to the success of the ITER project, participants at that

  10. Hydrogen Generation Via Sodium Borohydride

    NASA Astrophysics Data System (ADS)

    Mohring, Richard M.; Wu, Ying

    2003-07-01

    Along with the technological challenges associated with developing fuel cells and hydrogen burning engines, a major issue that must be addressed to ensure the ultimate success of a hydrogen economy is the ability to store and transport hydrogen effectively. Millennium Cell has developed and patented a proprietary system for storing and generating hydrogen gas called Hydrogen on Demand™. The system releases the hydrogen stored in fuel solutions of sodium borohydride as needed through an easily controllable catalytic process. The fuel itself is water-based, rich in hydrogen content, and non-flammable. It can be stored in plastic containers under no pressure. After the hydrogen from the fuel is consumed, the remaining product, sodium metaborate (chemically similar to borax), can be recycled back into fresh fuel. In this paper, an overview of the Hydrogen on Demand™ technology is presented along with data showing the performance characteristics of practical hydrogen generation systems. A brief discussion of sodium borohydride regeneration chemistry is also provided.

  11. Sources of polarized negative ions: progress and prospects

    SciTech Connect

    Haeberli, W.

    1980-01-01

    A summary of recent progress in the art of producing beams of polarized ions is given. In all sources of polarized ions, one first produces (or selects) neutral atoms which are polarized in electron spin. Those types of sources which use a beam of thermal polarized hydrogen atoms are discussed. Progress made in the preparation of the atomic beam and the methods used to convert the neutral atoms to polarized ions is summarized. The second type of source discussed is based on fast (keV) polarized hydrogen atoms. Conversion to negative ions is very simple because one only needs to pass the fast atoms through a suitable charge exchange medium (gas or vapor). However, the production of the polarized atoms is more difficult in this case. The proposal to employ polarized alkali vapor to form a beam of polarized fast H atoms, where the polarized alkali atoms are produced either by an atomic beam apparatus or by optical pumping is discussed. (WHK)

  12. Negative Transportation and Cross-Linguistic Negative Evidence.

    ERIC Educational Resources Information Center

    Soga, Matsuo

    1972-01-01

    This paper considers whether the negative transportation (NT) rule operating in English is operative also in Japanese and whether investigation of the phenomenon in Japanese may provide new insights for English research. The discussion begins with an explanation and examples of the NT rule in English. Japanese cases are then studied, and the…

  13. Experimental investigation of hydrogen peroxide RF plasmas

    NASA Astrophysics Data System (ADS)

    Barni, R.; Decina, A.; Zanini, S.; D'Orazio, A.; Riccardi, C.

    2016-04-01

    This work reports a detailed experimental study of the plasma properties in low pressure RF discharges in hydrogen peroxide and a comparison with argon under the same operating conditions. H2O2 plasmas have been proposed for sterilization purposes. Electrical properties of the discharge were shown to be similar, as for the RF and DC voltages of the driving electrode. Bulk plasma volume remains stable, concentrated in an almost cylindrical region between the two facing electrodes. It was found that the electron temperature is almost uniform across the plasma and independent of the power level. This is higher than in argon discharges: T e  =  4.6  ±  0.9 eV versus T e  =  3.3  ±  1.1 eV. The plasma density increases almost linearly with the power level and a substantial negative ion component has been ruled out in hydrogen peroxide. Dissociation in the plasma gas phase was revealed by atomic hydrogen and hydroxyl radical emission in the discharge spectra. Emission from hydroxyl and atomic oxygen demonstrates that oxidizing radicals are produced by hydrogen peroxide discharges, revealing its usefulness for plasma processing other than sterilization, for instance to increase polymer film surface energy. On the other hand, argon could be considered as a candidate for the sterilization purposes due to the intense production of UV radiation.

  14. Graphene nanopores as negative differential resistance devices

    SciTech Connect

    Qiu, Wanzhi; Nguyen, Phuong Duc; Skafidas, Efstratios

    2015-02-07

    We present graphene nanopores as new negative differential resistance (NDR) devices, and study their quantum transport properties using non-equilibrium Green's function and the density functional tight binding method. The proposed device structure is created on intrinsic armchair-edged graphene nanoribbons with uniform widths, where the central scattering region has a nanopore in the interior, and the two ends of the nanoribbon act naturally as connecting electrodes. We show that nitrogen-passivated scattering regions generally result in pronounced NDR properties, while hydrogen-passivated ones do not. This NDR effect occurs at low bias voltages, below 1 V, and achieves extraordinarily high peak-to-valley current ratio, while still attaining very high peak current densities. In addition, very sharp current peaks in the μA range can occur in the I-V curves, and through varying structural dimensions of the proposed structure multiple NDR regions can be realized. These results suggest that the device has promising potential in applications such as high frequency oscillators, memory devices, and fast switches.

  15. California Hydrogen Infrastructure Project

    SciTech Connect

    Heydorn, Edward C

    2013-03-12

    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a real-world retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation's hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling stations

  16. Theory of hydrogen in semiconductors

    SciTech Connect

    Walle, C.G. van de

    1998-12-31

    This paper treats the subject of hydrogen in semiconductors from various perspectives. First, a brief historical overview is given. Then, some basic principles governing the interaction between hydrogen and semiconductors are outlined. Finally, specific examples will emphasize the impact of hydrogen on technological applications. While the general treatment applies to interactions of hydrogen with any semiconductor, the applications will focus mainly on hydrogen interacting with silicon.

  17. Hydrogen storage and generation system

    DOEpatents

    Dentinger, Paul M.; Crowell, Jeffrey A. W.

    2010-08-24

    A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  18. Negativity Bias in Dangerous Drivers

    PubMed Central

    Chai, Jing; Qu, Weina; Sun, Xianghong; Zhang, Kan; Ge, Yan

    2016-01-01

    The behavioral and cognitive characteristics of dangerous drivers differ significantly from those of safe drivers. However, differences in emotional information processing have seldom been investigated. Previous studies have revealed that drivers with higher anger/anxiety trait scores are more likely to be involved in crashes and that individuals with higher anger traits exhibit stronger negativity biases when processing emotions compared with control groups. However, researchers have not explored the relationship between emotional information processing and driving behavior. In this study, we examined the emotional information processing differences between dangerous drivers and safe drivers. Thirty-eight non-professional drivers were divided into two groups according to the penalty points that they had accrued for traffic violations: 15 drivers with 6 or more points were included in the dangerous driver group, and 23 drivers with 3 or fewer points were included in the safe driver group. The emotional Stroop task was used to measure negativity biases, and both behavioral and electroencephalograph data were recorded. The behavioral results revealed stronger negativity biases in the dangerous drivers than in the safe drivers. The bias score was correlated with self-reported dangerous driving behavior. Drivers with strong negativity biases reported having been involved in mores crashes compared with the less-biased drivers. The event-related potentials (ERPs) revealed that the dangerous drivers exhibited reduced P3 components when responding to negative stimuli, suggesting decreased inhibitory control of information that is task-irrelevant but emotionally salient. The influence of negativity bias provides one possible explanation of the effects of individual differences on dangerous driving behavior and traffic crashes. PMID:26765225

  19. Sigma models with negative curvature

    NASA Astrophysics Data System (ADS)

    Alonso, Rodrigo; Jenkins, Elizabeth E.; Manohar, Aneesh V.

    2016-05-01

    We construct Higgs Effective Field Theory (HEFT) based on the scalar manifold Hn, which is a hyperbolic space of constant negative curvature. The Lagrangian has a non-compact O (n , 1) global symmetry group, but it gives a unitary theory as long as only a compact subgroup of the global symmetry is gauged. Whether the HEFT manifold has positive or negative curvature can be tested by measuring the S-parameter, and the cross sections for longitudinal gauge boson and Higgs boson scattering, since the curvature (including its sign) determines deviations from Standard Model values.

  20. High-energy Physics with Hydrogen Bubble Chambers

    DOE R&D Accomplishments Database

    Alvarez, L. W.

    1958-03-07

    Recent experience with liquid hydrogen bubble chambers of 25 and 40 cm dia. in high-energy physics experiments is discussed. Experiments described are: interactions of K{sup -} mesons with protons, interactions of antiprotons with protons, catalysis of nuclear fusion reactions by muons, and production and decay of hyperons from negative pions. (W.D.M.)

  1. Negative Electron Affinity Effect on the Surface of Chemical Vapor Deposited Diamond Polycrystalline Films

    NASA Technical Reports Server (NTRS)

    Krainsky, I. L.; Asnin, V. M.; Mearini, G. T.; Dayton, J. A., Jr.

    1996-01-01

    Strong negative electron affinity effects have been observed on the surface of as-grown chemical vapor deposited diamond using Secondary Electron Emission. The test samples were randomly oriented and the surface was terminated with hydrogen. The effect appears as an intensive peak in the low energy part of the spectrum of the electron energy distribution and may be described in the model of effective negative electron affinity.

  2. Atomic hydrogen cleaning of semiconductor photocathodes

    SciTech Connect

    Sinclair, C.K.; Poelker, B.M.; Price, J.S.

    1997-06-01

    Negative Electron Affinity (NEA) semiconductor photocathodes are widely used for the production of polarized electron beams, and are also useful for the production of high brightness electron beams which can be modulated at very high frequencies. Preparation of an atomically clean semiconductor surface is an essential step in the fabrication of a NEA photocathode. This cleaning step is difficult for certain semiconductors, such as the very thin materials which produce the highest beam polarization, and those which have tightly bound oxides and carbides. Using a small RF dissociation atomic hydrogen source, the authors have reproducibly cleaned GaAs wafers which have been only degreased prior to installation in vacuum. They have consistently prepared very high quantum efficiency photocathodes following atomic hydrogen cleaning. Details of their apparatus and most recent results are presented.

  3. Advanced nickel hydrogen cell configuration study

    NASA Technical Reports Server (NTRS)

    Adler, E.; Perez, F.

    1983-01-01

    An evaluation of the current nickel hydrogen cell design is presented. The IPV, or the Individual Pressure Vessel, is the state of the art right now. The present design, 3 1/2 inch cell, has a current limit of 50 ampere-hours. The nickel hydrogen cell design is the state of the art. Its size is 3 1/2 inches which limits it to 50 hours. The probable limits of that are probably 160 amphere IPV cell remaining in the passive cooling mode. The IPV stacks is a parallel connection of electrodes. Positive electrodes are connected with leads to the top portion of the stack and negative electrodes are connected with leads and pulled down to the bottom. So it is a combination connection of paralleling series electrostacking--parallel inside each individual stack, and series connected from one stack to the next. It offers, in the analysis, improvements in packaging, cost, energy density, and specific energy.

  4. Negative Geography: Locating Things Elsewhere.

    ERIC Educational Resources Information Center

    Stoddard, Robert H.

    The phenomenon of negative geography--the assertion that any location is better than the one selected--is discussed and ways in which this approach differs from traditional geography methodology are analyzed. Case studies of two citizens' groups which protested the relocation of a city mission and halfway house in their neighborhoods illustrate…

  5. Metastable metallic hydrogen glass

    SciTech Connect

    Nellis, W J

    2001-02-06

    The quest for metallic hydrogen has been going on for over one hundred years. Before hydrogen was first condensed into a liquid in 1898, it was commonly thought that condensed hydrogen would be a metal, like the monatomic alkali metals below hydrogen in the first column of the Periodic Table. Instead, condensed hydrogen turned out to be transparent, like the diatomic insulating halogens in the seventh column of the Periodic Table. Wigner and Huntington predicted in 1935 that solid hydrogen at 0 K would undergo a first-order phase transition from a diatomic to a monatomic crystallographically ordered solid at {approx}25 GPa. This first-order transition would be accompanied by an insulator-metal transition. Though searched for extensively, a first-order transition from an ordered diatomic insulator to a monatomic metal is yet to be observed at pressures up to 120 and 340 GPa using x-ray diffraction and visual inspection, respectively. On the other hand, hydrogen reaches the minimum electrical conductivity of a metal at 140 GPa, 0.6 g/cm{sup 3}, and 3000 K. These conditions were achieved using a shock wave reverberating between two stiff sapphire anvils. The shock wave was generated with a two-stage light-gas gun. This temperature exceeds the calculated melting temperature at 140 GPa by a factor of {approx}2, indicating that this metal is in the disordered fluid phase. The disorder permits hydrogen to become metallic via a Mott transition in the liquid at a much smaller pressure than in the solid, which has an electronic bandgap to the highest pressures reached to date. Thus, by using the finite temperature achieved with shock compression to achieve a disordered melt, metallic hydrogen can be achieved at a much lower pressure in a fluid than in a solid. It is not known how, nor even whether, metallic hydrogen can be quenched from a fluid at high pressures to a disordered solid metallic glass at ambient pressure and temperature. Because metallization occurs by simply

  6. Hydrogen peroxide poisoning.

    PubMed

    Watt, Barbara E; Proudfoot, Alex T; Vale, J Allister

    2004-01-01

    Hydrogen peroxide is an oxidising agent that is used in a number of household products, including general-purpose disinfectants, chlorine-free bleaches, fabric stain removers, contact lens disinfectants and hair dyes, and it is a component of some tooth whitening products. In industry, the principal use of hydrogen peroxide is as a bleaching agent in the manufacture of paper and pulp. Hydrogen peroxide has been employed medicinally for wound irrigation and for the sterilisation of ophthalmic and endoscopic instruments. Hydrogen peroxide causes toxicity via three main mechanisms: corrosive damage, oxygen gas formation and lipid peroxidation. Concentrated hydrogen peroxide is caustic and exposure may result in local tissue damage. Ingestion of concentrated (>35%) hydrogen peroxide can also result in the generation of substantial volumes of oxygen. Where the amount of oxygen evolved exceeds its maximum solubility in blood, venous or arterial gas embolism may occur. The mechanism of CNS damage is thought to be arterial gas embolisation with subsequent brain infarction. Rapid generation of oxygen in closed body cavities can also cause mechanical distension and there is potential for the rupture of the hollow viscus secondary to oxygen liberation. In addition, intravascular foaming following absorption can seriously impede right ventricular output and produce complete loss of cardiac output. Hydrogen peroxide can also exert a direct cytotoxic effect via lipid peroxidation. Ingestion of hydrogen peroxide may cause irritation of the gastrointestinal tract with nausea, vomiting, haematemesis and foaming at the mouth; the foam may obstruct the respiratory tract or result in pulmonary aspiration. Painful gastric distension and belching may be caused by the liberation of large volumes of oxygen in the stomach. Blistering of the mucosae and oropharyngeal burns are common following ingestion of concentrated solutions, and laryngospasm and haemorrhagic gastritis have been

  7. Safe Use of Hydrogen and Hydrogen Systems

    NASA Technical Reports Server (NTRS)

    Maes, Miguel

    2006-01-01

    This is a viewgraph presentation that is a course for teaching the safe use of hydrogen. The objectives of the course are 1. To familiarize the student with H2 safety properties 2. To enable the identification, evaluations and addressing of H2 system hazards 3. To teach: a. Safe practices for, b. Design, c. Materials selection, d. H2 system operation, e. Physical principles and empirical observations on which these safe practices are based, f. How to respond to emergency situations involving H2, g How to visualize safety concepts through in-class exercises, h. Identify numerous parameters important to H2 safety.

  8. Hot Hydrogen Test Facility

    SciTech Connect

    W. David Swank

    2007-02-01

    The core in a nuclear thermal rocket will operate at high temperatures and in hydrogen. One of the important parameters in evaluating the performance of a nuclear thermal rocket is specific impulse, ISp. This quantity is proportional to the square root of the propellant’s absolute temperature and inversely proportional to square root of its molecular weight. Therefore, high temperature hydrogen is a favored propellant of nuclear thermal rocket designers. Previous work has shown that one of the life-limiting phenomena for thermal rocket nuclear cores is mass loss of fuel to flowing hydrogen at high temperatures. The hot hydrogen test facility located at the Idaho National Lab (INL) is designed to test suitability of different core materials in 2500°C hydrogen flowing at 1500 liters per minute. The facility is intended to test non-uranium containing materials and therefore is particularly suited for testing potential cladding and coating materials. In this first installment the facility is described. Automated Data acquisition, flow and temperature control, vessel compatibility with various core geometries and overall capabilities are discussed.

  9. Magnetic liquefier for hydrogen

    SciTech Connect

    1992-12-31

    This document summarizes work done at the Astronautics Technology Center of the Astronautics Corporation of America (ACA) in Phase 1 of a four phase program leading to the development of a magnetic liquefier for hydrogen. The project involves the design, fabrication, installation, and operation of a hydrogen liquefier providing significantly reduced capital and operating costs, compared to present liquefiers. To achieve this goal, magnetic refrigeration, a recently developed, highly efficient refrigeration technology, will be used for the liquefaction process. Phase 1 project tasks included liquefier conceptual design and analysis, preliminary design of promising configurations, design selection, and detailed design of the selected design. Fabrication drawings and vendor specifications for the selected design were completed during detailed design. The design of a subscale, demonstration magnetic hydrogen liquefier represents a significant advance in liquefaction technology. The cost reductions that can be realized in hydrogen liquefaction in both the subscale and, more importantly, in the full-scale device are expected to have considerable impact on the use of liquid hydrogen in transportation, chemical, and electronic industries. The benefits to the nation from this technological advance will continue to have importance well into the 21st century.

  10. Hydrogen Contractors Meeting

    SciTech Connect

    Fitzsimmons, Tim

    2006-05-16

    This volume highlights the scientific content of the 2006 Hydrogen Contractors Meeting sponsored by the Division of Materials Sciences and Engineering (DMS&E) on behalf of the Office of Basic Energy Sciences (BES) of the U. S. Department of Energy (DOE). Hydrogen Contractors Meeting held from May 16-19, 2006 at the Crystal Gateway Marriott Hotel Arlington, Virginia. This meeting is the second in a series of research theme-based Contractors Meetings sponsored by DMS&E held in conjunction with our counterparts in the Office of Energy Efficiency and Renewable Energy (EERE) and the first with the Hydrogen, Fuel Cells and Infrastructure Technologies Program. The focus of this year’s meeting is BES funded fundamental research underpinning advancement of hydrogen storage. The major goals of these research efforts are the development of a fundamental scientific base in terms of new concepts, theories and computational tools; new characterization capabilities; and new materials that could be used or mimicked in advancing capabilities for hydrogen storage.

  11. Hydrogen Optical Fiber Sensors

    SciTech Connect

    Lieberman, Robert A.; Beshay, Manal; Cordero, Steven R.

    2008-07-28

    Optically-based hydrogen sensors promise to deliver an added level of safety as hydrogen and fuel cell technologies enter the mainstream. More importantly, they offer reduced power consumption and lower cost, which are desirable for mass production applications such as automobiles and consumer appliances. This program addressed two of the major challenges previously identified in porous optrode-based optical hydrogen sensors: sensitivity to moisture (ambient humidity), and interference from the oxygen in air. Polymer coatings to inhibit moisture and oxygen were developed in conjunction with newer and novel hydrogen sensing chemistries. The results showed that it is possible to achieve sensitive hydrogen detection and rapid response with minimal interference from oxygen and humidity. As a result of this work, a new and more exciting avenue of investigation was developed: the elimination of the porous optrode and deposition of the sensor chemistry directly into the polymer film. Initial results have been promising, and open up a wider range of potential applications from extended optical fiber sensing networks, to simple plastic "stickers" for use around the home and office.

  12. Hot Hydrogen Test Facility

    SciTech Connect

    Swank, W. David; Carmack, Jon; Werner, James E.; Pink, Robert J.; Haggard, DeLon C.; Johnson, Ryan

    2007-01-30

    The core in a nuclear thermal rocket will operate at high temperatures and in hydrogen. One of the important parameters in evaluating the performance of a nuclear thermal rocket is specific impulse, ISP. This quantity is proportional to the square root of the propellant's absolute temperature and inversely proportional to square root of its molecular weight. Therefore, high temperature hydrogen is a favored propellant of nuclear thermal rocket designers. Previous work has shown that one of the life-limiting phenomena for thermal rocket nuclear cores is mass loss of fuel to flowing hydrogen at high temperatures. The hot hydrogen test facility located at the Idaho National Lab (INL) is designed to test suitability of different core materials in 2500 deg. C hydrogen flowing at 1500 liters per minute. The facility is intended to test low activity uranium containing materials but is also suited for testing cladding and coating materials. In this first installment the facility is described. Automated data acquisition, flow and temperature control, vessel compatibility with various core geometries and overall capabilities are discussed.

  13. Hydrogen-Selective Membrane

    DOEpatents

    Collins, John P.; Way, J. Douglas

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2.s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  14. Hydrogen-selective membrane

    DOEpatents

    Collins, J.P.; Way, J.D.

    1995-09-19

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2}s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  15. Hydrogen-selective membrane

    DOEpatents

    Collins, John P.; Way, J. Douglas

    1997-01-01

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 .mu.m but typically less than about 20 .mu.m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m.sup.2. s at a temperature of greater than about 500.degree. C. and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500.degree. C. and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400.degree. C. and less than about 1000.degree. C. before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process.

  16. Hydrogen-selective membrane

    DOEpatents

    Collins, J.P.; Way, J.D.

    1997-07-29

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2} s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  17. Calibrating the DARHT Electron Spectrometer with Negative Ions

    SciTech Connect

    R. Trainham , A. P. Tipton , and R. R. Bartech

    2005-11-01

    Negative ions of hydrogen and oxygen have been used to calibrate the DARHT electron spectrometer over the momentum range of 2 to 20 MeV/c. The calibration was performed on September 1, 3, and 8, 2004, and it is good to 0.5% absolute, provided that instrument alignment is carefully controlled. The momentum in MeV/c as a function of magnetic field (B in Gauss) and position in the detector plane (X in mm) is: P = (B-6.28)/(108.404-0.1935*X)

  18. Low-energy negative muon interaction with matter

    NASA Astrophysics Data System (ADS)

    Danev, Petar; Adamczak, Andrzej; Bakalov, Dimitar; Mocchiutti, Emiliano; Stoilov, Mihail; Vacchi, Andrea

    2016-03-01

    Using simulated data, obtained with the FLUKA code, we derive empirical regularities about the propagation and stopping of low-energy negative muons in hydrogen and selected solid materials. The results are intended to help the preliminary stages of the set-up design for experimental studies of muon capture and muonic atom spectroscopy. Provided are approximate expressions for the parameters of the the momentum, spatial and angular distribution of the propagating muons. In comparison with the available data on the stopping power and range of muons (with which they agree in the considered energy range) these results have the advantage to also describe the statistical spread of the muon characteristics of interest.

  19. Influence of hydrogen oxidation kinetics on hydrogen environment embrittlement

    NASA Technical Reports Server (NTRS)

    Walter, R. J.; Kendig, M. W.; Meisels, A. P.

    1992-01-01

    Results are presented from experiments performed to determine the roles of hydrogen absorption and hydrogen electron transfer on the susceptibility of Fe- and Ni-base alloys to ambient-temperature hydroen embrittlement. An apparent independence is noted between hydrogen environment embrittlement and internal hydrogen embrittlement. The experiments were performed on Inconel 718, Incoloy 903, and A286. The electrochemical results obtained indicate that Inconel 718 either adsorbs hydrogen more rapidly and/or the electrochemical oxidation of the adsorbed hydrogen occurred more rapidly than in the other two materials.

  20. Experimental investigation of the relation between H- negative ion density and Lyman-α emission intensity in a microwave discharge

    NASA Astrophysics Data System (ADS)

    Aleiferis, S.; Tarvainen, O.; Svarnas, P.; Bacal, M.; Béchu, S.

    2016-03-01

    A new mechanism for producing negative ions in low density and low power hydrogen plasmas was proposed recently. It refers to anion formation due to collisions between hydrogen atoms being in the first excited state. The proposed mechanism was indirectly supported by the quadratic relation observed between the extracted negative ion current and Lyman-α radiation of a filament-driven arc discharge, when borrowed data from the literature were combined. The present work provides experimental data comparing directly the absolute negative ion density and Lyman-α radiation in an ECR-driven hydrogen plasma source. The previously mentioned quadratic relation is not observed in the specific source studied, underlying the difficulty of distinguishing between the proposed mechanism and other negative ion production paths.

  1. Metalinguistic Negation in English and Arabic

    ERIC Educational Resources Information Center

    Nedwick, Kelly M.

    2014-01-01

    Negation is a unique and fascinating property of human language which has been given extensive theoretical and typological treatment. One categorization divides negation use into metalinguistic negation and descriptive negation (Horn, 1985). Descriptive negation (DN) is the truth-functional semantic operator which has received the most attention…

  2. Bis(benzyl­tri­methyl­ammonium) bis­[(4SR,12SR,18RS,26RS)-4,18,26-trihy­droxy-12-oxido-13,17-dioxahepta­cyclo­[14.10.0.03,14.04,12.06,11.018,26.019,24]hexa­cosa-1,3(14),6,8,10,15,19,21,23-nona­ene-5,25-dione] sesquihydrate: dimeric structure formation via [O—H—O]− negative charge-assisted hydrogen bonds (–CAHB) with benzyl­tri­methyl­ammonium counter-ions

    PubMed Central

    Bengiat, Ravell; Gil, Maayan; Klein, Asne; Bogoslavsky, Benny; Cohen, Shmuel; Almog, Joseph

    2016-01-01

    The reaction between bis-ninhydrin resorcinol and benzyl­tri­methyl­ammonium fluoride in ethanol has produced the title compound, 2C10H16N+·2C24H13O8 −·1.5H2O, which contains a unique centrosymmetric supra­molecular dimeric entity, where two deprotonated ligands are held together via two strong and short [O⋯O = 2.4395 (13) Å] [O—H—O]− bonds of the type negative charge-assisted hydrogen bonds (–CAHB). The central aromatic rings of the ligands create parallel-displaced π–π stacking at an inter­planar distance of 3.381 (1) Å, which helps stabilize the dimer. In the crystal, two symmetry-related solvent water mol­ecules with a site occupancy of 0.75 are attached to the carbonyl groups of the dimer by weaker O—H⋯O hydrogen bonds, forming chains along [101]. PMID:27006816

  3. Bis(benzyl-tri-methyl-ammonium) bis-[(4SR,12SR,18RS,26RS)-4,18,26-trihy-droxy-12-oxido-13,17-dioxahepta-cyclo-[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexa-cosa-1,3(14),6,8,10,15,19,21,23-nona-ene-5,25-dione] sesquihydrate: dimeric structure formation via [O-H-O](-) negative charge-assisted hydrogen bonds (-CAHB) with benzyl-tri-methyl-ammonium counter-ions.

    PubMed

    Bengiat, Ravell; Gil, Maayan; Klein, Asne; Bogoslavsky, Benny; Cohen, Shmuel; Almog, Joseph

    2016-03-01

    The reaction between bis-ninhydrin resorcinol and benzyl-tri-methyl-ammonium fluoride in ethanol has produced the title compound, 2C10H16N(+)·2C24H13O8 (-)·1.5H2O, which contains a unique centrosymmetric supra-molecular dimeric entity, where two deprotonated ligands are held together via two strong and short [O⋯O = 2.4395 (13) Å] [O-H-O](-) bonds of the type negative charge-assisted hydrogen bonds (-CAHB). The central aromatic rings of the ligands create parallel-displaced π-π stacking at an inter-planar distance of 3.381 (1) Å, which helps stabilize the dimer. In the crystal, two symmetry-related solvent water mol-ecules with a site occupancy of 0.75 are attached to the carbonyl groups of the dimer by weaker O-H⋯O hydrogen bonds, forming chains along [101]. PMID:27006816

  4. Microbial detection method based on sensing molecular hydrogen

    NASA Technical Reports Server (NTRS)

    Wilkins, J. R.; Stoner, G. E.; Boykin, E. H.

    1974-01-01

    A simple method for detecting bacteria, based on the time of hydrogen evolution, was developed and tested against various members of the Enterobacteriaceae group. The test system consisted of (1) two electrodes, platinum and a reference electrode, (2) a buffer amplifier, and (3) a strip-chart recorder. Hydrogen evolution was measured by an increase in voltage in the negative (cathodic) direction. A linear relationship was established between inoculum size and the time hydrogen was detected (lag period). Lag times ranged from 1 h for 1 million cells/ml to 7 h for 1 cell/ml. For each 10-fold decrease in inoculum, length of the lag period increased 60 to 70 min. Based on the linear relationship between inoculum and lag period, these results indicate the potential application of the hydrogen-sensing method for rapidly detecting coliforms and other gas-producing microorganisms in a variety of clinical, food, and other samples.

  5. Surface production of H(-) ions by hyperthermal hydrogen atoms

    NASA Astrophysics Data System (ADS)

    Lee, Brian S.; Seidl, M.

    1992-12-01

    Hyperthermal atomic hydrogen of energy in the range of 1-10 eV has been produced by electron impact dissociation in a CW 2.45 GHz microwave electron cyclotron resonance discharge using a Lisitano-Coil (Lisitano, 1970). The flux and the energy of the hydrogen atoms have been measured by negative surface ionization of the atoms backscattered from pure and cesiated metal surfaces. A hyperthermal atomic hydrogen flux density equivalent to more than 0.5 A/sq cm and a temperature of about 5 eV has been produced for 420 W discharge power under CW condition. These hydrogen atoms can be directed onto an external converter located outside the discharge. This opens up new possibilities for H(-) ion source design.

  6. Hydrogen production from carbonaceous material

    DOEpatents

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  7. Asymmetric hydrogenations (Nobel lecture).

    PubMed

    Knowles, William S

    2002-06-17

    The start of the development of catalysts for asymmetric hydrogenation was the concept of replacing the triphenylphosphane ligand of the Wilkinson catalyst with a chiral ligand. With the new catalysts, it should be possible to hydrogenate prochiral olefins. Knowles and his co-workers were convinced that the phosphorus atom played a central role in this selectivity, as only chiral phosphorus ligands such as (R,R)-DIPAMP, whose stereogenic center lies directly on the phosphorus atom, lead to high enantiomeric excesses when used as catalysts in asymmetric hydrogenation reactions. This hypothesis was disproven by the development of ligands with chiral carbon backbones. Although the exact mechanism of action of the phosphane ligands is not incontrovertibly determined to this day, they provide a simple entry to a large number of chiral compounds. PMID:19746594

  8. Hydrogen vehicle fueling station

    SciTech Connect

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A.; Prenger, F.C.; Hill, D.D.

    1995-09-01

    The authors describe a hydrogen vehicle fueling station that receives and stores hydrogen in liquid form and dispenses it either as a liquid or compressed gas. The economics that accrue from the favorable weight and volume advantages of liquid hydrogen support this concept both now and probably for some time to come. The model for liquid transfer to a 120-liter vehicle tank shows that transfer times under five minutes are feasible with pump-assisted transfer, or for pressure transfer with subcooling greater than 1 K. The model for compressed gas transfer shows that underfilling of nearly 30% can occur during rapid filling. Cooling the fill gas to 214 K completely eliminates underfilling.

  9. Hydrogen vehicle fueling station

    SciTech Connect

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A.

    1996-12-31

    The authors describe a hydrogen vehicle fueling station that receives and stores hydrogen in liquid form and dispenses it either as a liquid or compressed gas. The economics of distribution that accrue from the favorable weight and volume advantages of liquid hydrogen support this concept both now and for some time to come. The authors model for liquid transfer to a 120 L vehicle tank shows that tank filling times under five minutes are feasible with pump-assisted transfer, or for pressure transfer with subcooling greater than 1 K. The authorsmodel for compressed gas transfer shows that vehicle tank underfilling of nearly 30 percent can occur during rapid refueling. Cooling the fill gas to 214 K completely eliminates the underfilling problem.

  10. Volume production of negative ions in the reflex type ion source

    SciTech Connect

    Jimbo, K.

    1982-01-01

    The production of negative hydrogen ions is investigated in the reflex-type negative ion source. The extracted negative hydrogen currents of 9.7 mA (100 mA/cm/sup 2/) for H/sup -/ and of 4.1 mA (42 mA/cm/sup 2/) for D/sup -/ are obtained continuously. The impurity is less then 1%. An isotope effect of negative ion production is observed. When anomalous diffusion in the positive column was found by Lehnert and Hoh (1960), it was pointed out that the large particle loss produced by anomalous diffusion is compensated by the large particle production inside the plasma, i.e., the plasma tries to maintain itself. The self-sustaining property of the plasma is applied to the reflex-type negative ion source. Anomalous diffusion was artificially encouraged by changing the radial electric field inside the reflex discharge. The apparent encouragement of negative ion diffusion by the increase of density fluctuation amplitude is observed. Twice as much negative ion current was obtained with the artificial encouragement as without. It is found from the quasilinear theory that the inwardly directed radial electric field destabilizes the plasma in the reflex-type ion source. The nonlinear theory based on Yoshikawa method (1962) is extended, and the anomalous diffusion coefficient in a weakly ionized plasma is obtained. The electrostatic sheath trap, which increases the confinement of negative ions in the reflex-type ion source, is also discussed.

  11. Hydrogen: Fueling the Future

    SciTech Connect

    Leisch, Jennifer

    2007-02-27

    As our dependence on foreign oil increases and concerns about global climate change rise, the need to develop sustainable energy technologies is becoming increasingly significant. Worldwide energy consumption is expected to double by the year 2050, as will carbon emissions along with it. This increase in emissions is a product of an ever-increasing demand for energy, and a corresponding rise in the combustion of carbon containing fossil fuels such as coal, petroleum, and natural gas. Undisputable scientific evidence indicates significant changes in the global climate have occurred in recent years. Impacts of climate change and the resulting atmospheric warming are extensive, and know no political or geographic boundaries. These far-reaching effects will be manifested as environmental, economic, socioeconomic, and geopolitical issues. Offsetting the projected increase in fossil energy use with renewable energy production will require large increases in renewable energy systems, as well as the ability to store and transport clean domestic fuels. Storage and transport of electricity generated from intermittent resources such as wind and solar is central to the widespread use of renewable energy technologies. Hydrogen created from water electrolysis is an option for energy storage and transport, and represents a pollution-free source of fuel when generated using renewable electricity. The conversion of chemical to electrical energy using fuel cells provides a high efficiency, carbon-free power source. Hydrogen serves to blur the line between stationary and mobile power applications, as it can be used as both a transportation fuel and for stationary electricity generation, with the possibility of a distributed generation energy infrastructure. Hydrogen and fuel cell technologies will be presented as possible pollution-free solutions to present and future energy concerns. Recent hydrogen-related research at SLAC in hydrogen production, fuel cell catalysis, and hydrogen

  12. Hydrogen vehicle fueling station

    SciTech Connect

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A.

    1995-09-01

    Hydrogen fueling stations are an essential element in the practical application of hydrogen as a vehicle fuel, and a number of issues such as safety, efficiency, design, and operating procedures can only be accurately addressed by a practical demonstration. Regardless of whether the vehicle is powered by an internal combustion engine or fuel cell, or whether the vehicle has a liquid or gaseous fuel tank, the fueling station is a critical technology which is the link between the local storage facility and the vehicle. Because most merchant hydrogen delivered in the US today (and in the near future) is in liquid form due to the overall economics of production and delivery, we believe a practical refueling station should be designed to receive liquid. Systems studies confirm this assumption for stations fueling up to about 300 vehicles. Our fueling station, aimed at refueling fleet vehicles, will receive hydrogen as a liquid and dispense it as either liquid, high pressure gas, or low pressure gas. Thus, it can refuel any of the three types of tanks proposed for hydrogen-powered vehicles -- liquid, gaseous, or hydride. The paper discusses the fueling station design. Results of a numerical model of liquid hydrogen vehicle tank filling, with emphasis on no vent filling, are presented to illustrate the usefulness of the model as a design tool. Results of our vehicle performance model illustrate our thesis that it is too early to judge what the preferred method of on-board vehicle fuel storage will be in practice -- thus our decision to accommodate all three methods.

  13. Hydrogen from biomass: state of the art and research challenges

    SciTech Connect

    Milne, Thomas A; Elam, Carolyn C; Evans, Robert J

    2002-02-01

    The report was prepared for the International Energy Agency (IEA) Agreement on the Production and Utilization of Hydrogen, Task 16, Hydrogen from Carbon-Containing Materials. Hydrogen's share in the energy market is increasing with the implementation of fuel cell systems and the growing demand for zero-emission fuels. Hydrogen production will need to keep pace with this growing market. In the near term, increased production will likely be met by conventional technologies, such as natural gas reforming. In these processes, the carbon is converted to CO2 and released to the atmosphere. However, with the growing concern about global climate change, alternatives to the atmospheric release of CO2 are being investigated. Sequestration of the CO2 is an option that could provide a viable near-term solution. Reducing the demand on fossil resources remains a significant concern for many nations. Renewable-based processes like solar- or wind-driven electrolysis and photobiological water splitting hold great promise for clean hydrogen production; however, advances must still be made before these technologies can be economically competitive. For the near-and mid-term, generating hydrogen from biomass may be the more practical and viable, renewable and potentially carbon-neutral (or even carbon-negative in conjunction with sequestration) option. Recently, the IEA Hydrogen Agreement launched a new task to bring together international experts to investigate some of these near- and mid-term options for producing hydrogen with reduced environmental impacts. This review of the state of the art of hydrogen production from biomass was prepared to facilitate in the planning of work that should be done to achieve the goal of near-term hydrogen energy systems. The relevant technologies that convert biomass to hydrogen, with emphasis on thermochemical routes are described. In evaluating the viability of the conversion routes, each must be put in the context of the availability of

  14. H3O+ tetrahedron induction in large negative linear compressibility

    PubMed Central

    Wang, Hui; Feng, Min; Wang, Yu-Fang; Gu, Zhi-Yuan

    2016-01-01

    Despite the rarity, large negative linear compressibility (NLC) was observed in metal-organic framework material Zn(HO3PC4H8PO3H)∙2H2O (ZAG-4) in experiment. We find a unique NLC mechanism in ZAG-4 based on first-principle calculations. The key component to realize its large NLC is the deformation of H3O+ tetrahedron. With pressure increase, the oxygen apex approaches and then is inserted into the tetrahedron base (hydrogen triangle). The tetrahedron base subsequently expands, which results in the b axis expansion. After that, the oxygen apex penetrates the tetrahedron base and the b axis contracts. The negative and positive linear compressibility is well reproduced by the hexagonal model and ZAG-4 is the first MOFs evolving from non re-entrant to re-entrant hexagon framework with pressure increase. This gives a new approach to explore and design NLC materials. PMID:27184726

  15. H3O+ tetrahedron induction in large negative linear compressibility

    NASA Astrophysics Data System (ADS)

    Wang, Hui; Feng, Min; Wang, Yu-Fang; Gu, Zhi-Yuan

    2016-05-01

    Despite the rarity, large negative linear compressibility (NLC) was observed in metal-organic framework material Zn(HO3PC4H8PO3H)•2H2O (ZAG-4) in experiment. We find a unique NLC mechanism in ZAG-4 based on first-principle calculations. The key component to realize its large NLC is the deformation of H3O+ tetrahedron. With pressure increase, the oxygen apex approaches and then is inserted into the tetrahedron base (hydrogen triangle). The tetrahedron base subsequently expands, which results in the b axis expansion. After that, the oxygen apex penetrates the tetrahedron base and the b axis contracts. The negative and positive linear compressibility is well reproduced by the hexagonal model and ZAG-4 is the first MOFs evolving from non re-entrant to re-entrant hexagon framework with pressure increase. This gives a new approach to explore and design NLC materials.

  16. H3O(+) tetrahedron induction in large negative linear compressibility.

    PubMed

    Wang, Hui; Feng, Min; Wang, Yu-Fang; Gu, Zhi-Yuan

    2016-01-01

    Despite the rarity, large negative linear compressibility (NLC) was observed in metal-organic framework material Zn(HO3PC4H8PO3H)∙2H2O (ZAG-4) in experiment. We find a unique NLC mechanism in ZAG-4 based on first-principle calculations. The key component to realize its large NLC is the deformation of H3O(+) tetrahedron. With pressure increase, the oxygen apex approaches and then is inserted into the tetrahedron base (hydrogen triangle). The tetrahedron base subsequently expands, which results in the b axis expansion. After that, the oxygen apex penetrates the tetrahedron base and the b axis contracts. The negative and positive linear compressibility is well reproduced by the hexagonal model and ZAG-4 is the first MOFs evolving from non re-entrant to re-entrant hexagon framework with pressure increase. This gives a new approach to explore and design NLC materials. PMID:27184726

  17. Hydrogen production from microbial strains

    DOEpatents

    Harwood, Caroline S; Rey, Federico E

    2012-09-18

    The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

  18. Polyhydride complexes for hydrogen storage

    SciTech Connect

    Jensen, C.M.

    1995-09-01

    Polyhydride metal complexes are being developed for application in hydrogen storage. Efforts have focused on developing complexes with improved available hydrogen weight percentages. We have explored the possibility that complexes containing aromatic hydrocarbon ligands could store hydrogen at both the metal center and in the ligands. We have synthesized novel indenyl hydride complexes and explored their reactivity with hydrogen. The reversible hydrogenation of [IrH{sub 3}(PPh{sub 3})({eta}{sup 5}-C{sub 10}H{sub 7})]{sup +} has been achieved. While attempting to prepare {eta}{sup 6}-tetrahydronaphthalene complexes, we discovered that certain polyhydride complexes catalyze both the hydrogenation and dehydrogenation of tetrahydronaphthalene.

  19. Hydrogen environment embrittlement of metals

    NASA Technical Reports Server (NTRS)

    Jewett, R. P.; Walter, R. J.; Chandler, W. T.; Frohmberg, R. P.

    1973-01-01

    Hydrogen environment embrittlement refers to metals stressed while exposed to a hydrogen atmosphere. Tested in air, even after exposure to hydrogen under pressure, this effect is not observed on similar specimens. Much high purity hydrogen is prepared by evaporation of liquid hydrogen, and thus has low levels for potential impurities which could otherwise inhibit or poison the absorbent reactions that are involved. High strength steels and nickel-base allows are rated as showing extreme embrittlement; aluminum alloys and the austenitic stainless steels, as well as copper, have negligible susceptibility to this phenomenon. The cracking that occurs appears to be a surface phenomenon, is unlike that of internal hydrogen embrittlement.

  20. Thin film hydrogen sensor

    DOEpatents

    Cheng, Y.T.; Poli, A.A.; Meltser, M.A.

    1999-03-23

    A thin film hydrogen sensor includes a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end. 5 figs.

  1. NREL's Hydrogen Program

    SciTech Connect

    2011-01-01

    The research and development taking place today at the National Renewable Energy Laboratory (NREL) is paving the way for nature's most plentiful element—hydrogen—to power the next generation. NREL researchers are working to unlock the potential of hydrogen and to advance the fuel cell technologies that will power the automobiles, equipment, and buildings of tomorrow. Hydrogen and fuel cells are a fundamental part of the broader portfolio of renewable technologies that are moving our nation toward its goals of energy independence and sustainability.

  2. Reduced hydrogen cadmium plating

    SciTech Connect

    Hoeller, T.; Ross, L. ); Varma, R. ); Agarwala, V.S. )

    1991-01-01

    This paper demonstrates the advantages of using a periodic reverse pulse plating method, incorporating a fast cathodic pulse which is separated from the subsequent anodic/cathodic pulses by a long rest period in producing silvery cadmium coatings on steel from aqueous fluoroborate electrolyte. Also, the deposition obtained by combination of pulse currents and turbulent electrolyte flow system (forced convection of electrolyte, Re {approximately} 20-25,000) result in a near hydrogen-free electrodeposition of fine- grained cadmium. This is confirmed by the determination of diffusible hydrogen by the electrochemical (Barnach Electrode) method.

  3. Producing Hydrogen With Sunlight

    NASA Technical Reports Server (NTRS)

    Biddle, J. R.; Peterson, D. B.; Fujita, T.

    1987-01-01

    Costs high but reduced by further research. Producing hydrogen fuel on large scale from water by solar energy practical if plant costs reduced, according to study. Sunlight attractive energy source because it is free and because photon energy converts directly to chemical energy when it breaks water molecules into diatomic hydrogen and oxygen. Conversion process low in efficiency and photochemical reactor must be spread over large area, requiring large investment in plant. Economic analysis pertains to generic photochemical processes. Does not delve into details of photochemical reactor design because detailed reactor designs do not exist at this early stage of development.

  4. Hydrogen/bromine cell

    SciTech Connect

    Hohne, K.; Starbeck, G.

    1985-05-28

    Described herein is an energy storage device which utilizes a hydrogen/bromine cell. The cell includes a bromine electrode and a hydrogen electrode. The cell is light weight, resists corrosion caused by bromine or hydrobromic acid and uses both an electrolysis and a fuel cell reaction to store or discharge electrical energy. The cell frame is made of graphite and has a pyrographite coating on at least the portion facing the bromine electrode. This cell is therefore very useful in matching varying energy supplies with varying energy demands and allows for decentralization of energy storage.

  5. Hydrogen rich gas generator

    NASA Technical Reports Server (NTRS)

    Houseman, J.; Rupe, J. H.; Kushida, R. O. (Inventor)

    1976-01-01

    A process and apparatus is described for producing a hydrogen rich gas by injecting air and hydrocarbon fuel at one end of a cylindrically shaped chamber to form a mixture and igniting the mixture to provide hot combustion gases by partial oxidation of the hydrocarbon fuel. The combustion gases move away from the ignition region to another region where water is injected to be turned into steam by the hot combustion gases. The steam which is formed mixes with the hot gases to yield a uniform hot gas whereby a steam reforming reaction with the hydrocarbon fuel takes place to produce a hydrogen rich gas.

  6. Hydrogen peroxide catalytic decomposition

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F. (Inventor)

    2010-01-01

    Nitric oxide in a gaseous stream is converted to nitrogen dioxide using oxidizing species generated through the use of concentrated hydrogen peroxide fed as a monopropellant into a catalyzed thruster assembly. The hydrogen peroxide is preferably stored at stable concentration levels, i.e., approximately 50%-70% by volume, and may be increased in concentration in a continuous process preceding decomposition in the thruster assembly. The exhaust of the thruster assembly, rich in hydroxyl and/or hydroperoxy radicals, may be fed into a stream containing oxidizable components, such as nitric oxide, to facilitate their oxidation.

  7. Electrolytic hydrogen production

    NASA Astrophysics Data System (ADS)

    Ramani, M. P. S.

    In the role of a secondary energy carrier complementary to electricity in a postfossil-fuel era, hydrogen produced by the elecrolytic splitting of water may be obtained by a variety of methods whose technology development status is presently assessed. Nuclear heat can be converted into hydrogen either directly, via thermal splitting of water, or by means of water electrolysis, which can be of the unipolar tank type or the bipolar filter-press type. An evaluation is made of advanced electrolytic techniques involving exotic materials, as well as solid polymer electrolyte electrolysis and high-temperature water-vapor electrolysis.

  8. Thin film hydrogen sensor

    DOEpatents

    Cheng, Yang-Tse; Poli, Andrea A.; Meltser, Mark Alexander

    1999-01-01

    A thin film hydrogen sensor, includes: a substantially flat ceramic substrate with first and second planar sides and a first substrate end opposite a second substrate end; a thin film temperature responsive resistor on the first planar side of the substrate proximate to the first substrate end; a thin film hydrogen responsive metal resistor on the first planar side of the substrate proximate to the fist substrate end and proximate to the temperature responsive resistor; and a heater on the second planar side of the substrate proximate to the first end.

  9. Regional Consumer Hydrogen Demand and Optimal Hydrogen Refueling Station Siting

    SciTech Connect

    Melendez, M.; Milbrandt, A.

    2008-04-01

    Using a GIS approach to spatially analyze key attributes affecting hydrogen market transformation, this study proposes hypothetical hydrogen refueling station locations in select subregions to demonstrate a method for determining station locations based on geographic criteria.

  10. Cosmology with negative absolute temperatures

    NASA Astrophysics Data System (ADS)

    Vieira, J. P. P.; Byrnes, Christian T.; Lewis, Antony

    2016-08-01

    Negative absolute temperatures (NAT) are an exotic thermodynamical consequence of quantum physics which has been known since the 1950's (having been achieved in the lab on a number of occasions). Recently, the work of Braun et al. [1] has rekindled interest in negative temperatures and hinted at a possibility of using NAT systems in the lab as dark energy analogues. This paper goes one step further, looking into the cosmological consequences of the existence of a NAT component in the Universe. NAT-dominated expanding Universes experience a borderline phantom expansion (w < ‑1) with no Big Rip, and their contracting counterparts are forced to bounce after the energy density becomes sufficiently large. Both scenarios might be used to solve horizon and flatness problems analogously to standard inflation and bouncing cosmologies. We discuss the difficulties in obtaining and ending a NAT-dominated epoch, and possible ways of obtaining density perturbations with an acceptable spectrum.

  11. Gram-Negative Flagella Glycosylation

    PubMed Central

    Merino, Susana; Tomás, Juan M.

    2014-01-01

    Protein glycosylation had been considered as an eccentricity of a few bacteria. However, through advances in analytical methods and genome sequencing, it is now established that bacteria possess both N-linked and O-linked glycosylation pathways. Both glycosylation pathways can modify multiple proteins, flagellins from Archaea and Eubacteria being one of these. Flagella O-glycosylation has been demonstrated in many polar flagellins from Gram-negative bacteria and in only the Gram-positive genera Clostridium and Listeria. Furthermore, O-glycosylation has also been demonstrated in a limited number of lateral flagellins. In this work, we revised the current advances in flagellar glycosylation from Gram-negative bacteria, focusing on the structural diversity of glycans, the O-linked pathway and the biological function of flagella glycosylation. PMID:24557579

  12. Negative effects of positive reinforcement

    PubMed Central

    Perone, Michael

    2003-01-01

    Procedures classified as positive reinforcement are generally regarded as more desirable than those classified as aversive—those that involve negative reinforcement or punishment. This is a crude test of the desirability of a procedure to change or maintain behavior. The problems can be identified on the basis of theory, experimental analysis, and consideration of practical cases. Theoretically, the distinction between positive and negative reinforcement has proven difficult (some would say the distinction is untenable). When the distinction is made purely in operational terms, experiments reveal that positive reinforcement has aversive functions. On a practical level, positive reinforcement can lead to deleterious effects, and it is implicated in a range of personal and societal problems. These issues challenge us to identify other criteria for judging behavioral procedures. ImagesFigure 1Figure 2 PMID:22478391

  13. In defense of negative temperature

    NASA Astrophysics Data System (ADS)

    Poulter, J.

    2016-03-01

    This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature, being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs entropies must obey the same thermodynamic consistency relation. Second, the Boltzmann entropy does obey the second law of thermodynamics. Third, there exists an integrating factor of the heat differential with both definitions of entropy.

  14. Low Trans Hydrogenation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Although hydrogenation has been the technology of choice for fat formulation for many years recent concerns over the health and nutrition of trans fatty acids have had a profound effect on the edible oil industry. Since Jan. 1, 2006, TFA has been required on nutrition labels along with saturated an...

  15. Gas controlled hydrogen fermentation.

    PubMed

    Bastidas-Oyanedel, Juan-Rodrigo; Mohd-Zaki, Zuhaida; Zeng, Raymond J; Bernet, Nicolas; Pratt, Steven; Steyer, Jean-Philippe; Batstone, Damien John

    2012-04-01

    Acidogenic fermentation is an anaerobic process of double purpose, while treating organic residues it produces chemical compounds, such as hydrogen, ethanol and organic acids. Therefore, acidogenic fermentation arises as an attractive biotechnology process towards the biorefinery concept. Moreover, this process does not need sterile operating conditions and works under a wide range of pH. Changes of operating conditions produce metabolic shifts, inducing variability on acidogenic product yield. To induce those changes, experiments, based on reactor headspace N(2)-flushing (gas phase), were designed. A major result was the hydrogen yield increase from 1 to 3.25±0.4 ( [Formula: see text] ) at pH 4.5 and N(2)-flushing of 58.4 (L·d(-1)). This yield is close to the theoretical acidogenic value (4 [Formula: see text] ). The mechanisms that explain this increase on hydrogen yield shifts are related to the thermodynamics of three metabolic reactions: lactate hydrogenase, NADH hydrogenase and homoacetogenesis, which are affected by the low hydrogen partial pressures. PMID:22342590

  16. A Simple Hydrogen Electrode

    ERIC Educational Resources Information Center

    Eggen, Per-Odd

    2009-01-01

    This article describes the construction of an inexpensive, robust, and simple hydrogen electrode, as well as the use of this electrode to measure "standard" potentials. In the experiment described here the students can measure the reduction potentials of metal-metal ion pairs directly, without using a secondary reference electrode. Measurements…

  17. Resistive hydrogen sensing element

    DOEpatents

    Lauf, Robert J.

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  18. Liquid Hydrogen: Target, Detector

    SciTech Connect

    Mulholland, G.T.; Harigel, G.G.

    2004-06-23

    In 1952 D. Glaser demonstrated that a radioactive source's radiation could boil 135 deg. C superheated-diethyl ether in a 3-mm O glass vessel and recorded bubble track growth on high-speed film in a 2-cm3 chamber. This Bubble Chamber (BC) promised improved particle track time and spatial resolution and cycling rate. Hildebrand and Nagle, U of Chicago, reported Liquid Hydrogen minimum ionizing particle boiling in August 1953. John Wood created the 3.7-cm O Liquid Hydrogen BC at LBL in January 1954. By 1959 the Lawrence Berkley Laboratory (LBL) Alvarez group's '72-inch' BC had tracks in liquid hydrogen. Within 10 years bubble chamber volumes increased by a factor of a million and spread to every laboratory with a substantial high-energy physics program. The BC, particle accelerators and special separated particle beams created a new era of High Energy Physics (HEP) experimentation. The BC became the largest most complex cryogenic installation at the world's HEP laboratories for decades. The invention and worldwide development, deployment and characteristics of these cryogenic dynamic target/detectors and related hydrogen targets are described.

  19. Hydrogen isotope separation

    DOEpatents

    Bartlit, John R.; Denton, William H.; Sherman, Robert H.

    1982-01-01

    A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

  20. Hydrogen isotope separation

    DOEpatents

    Bartlit, J.R.; Denton, W.H.; Sherman, R.H.

    Disclosed is a system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D/sub 2/, DT, T/sub 2/, and a tritium-free stream of HD for waste disposal.

  1. Hydrogen fuel - Universal energy

    NASA Astrophysics Data System (ADS)

    Prince, A. G.; Burg, J. A.

    The technology for the production, storage, transmission, and consumption of hydrogen as a fuel is surveyed, with the physical and chemical properties of hydrogen examined as they affect its use as a fuel. Sources of hydrogen production are described including synthesis from coal or natural gas, biomass conversion, thermochemical decomposition of water, and electrolysis of water, of these only electrolysis is considered economicially and technologically feasible in the near future. Methods of production of the large quantities of electricity required for the electrolysis of sea water are explored: fossil fuels, hydroelectric plants, nuclear fission, solar energy, wind power, geothermal energy, tidal power, wave motion, electrochemical concentration cells, and finally ocean thermal energy conversion (OTEC). The wind power and OTEC are considered in detail as the most feasible approaches. Techniques for transmission (by railcar or pipeline), storage (as liquid in underwater or underground tanks, as granular metal hydride, or as cryogenic liquid), and consumption (in fuel cells in conventional power plants, for home usage, for industrial furnaces, and for cars and aircraft) are analyzed. The safety problems of hydrogen as a universal fuel are discussed, noting that they are no greater than those for conventional fuels.

  2. Chemochromic Hydrogen Sensors

    NASA Technical Reports Server (NTRS)

    Wiggins, Bryan C.

    2007-01-01

    As fossil fuel supplies decline, hydrogen is quickly becoming an increasingly important fuel source. Currently hydrogen is the prime fuel of today's space vehicles (e.g., Space Shuttle) and featured as a fuel for some prototype vehicles such as the BMW seven series model. Hydrogen is a colorless, odorless gas with a 4% lower explosive limit which makes leak detection a priority. In an effort to support the use of hydrogen, a chemochromic (color changing) sensor was developed that is robust, simple to use, and does not require active operation. It can be made into a thin tape which can be conveniently used for leak detection at flanges, valves, or outlets. Chemochromic sensors can be either reversible or irreversible; however, irreversible chemochromic sensors will be analyzed in this report. The irreversible sensor is useful during hazardous operations when personnel cannot be present. To actively monitor leaks, testing of the irreversible sensor against environmental effects was completed and results indicated this material is suitable for outdoor use in the harsh beachside environment of Kennedy Space Center. The experiments in this report will give additional results to the environmental testing by adding solid rocket booster residue as a variable. The primary motivation for these experiments is to prepare the sensors for the launch pad environment at the Kennedy Space Center. In an effort to simulate the atmosphere at the pads before and after launch, the chemochromic sensors are exposed to solid rocket residue under various conditions.

  3. Hydrogen production from coal

    NASA Technical Reports Server (NTRS)

    1975-01-01

    The gasification reactions necessary for the production of hydrogen from montana subbituminous coal are presented. The coal composition is given. The gasifier types mentioned include: suspension (entrained) combustion; fluidized bed; and moving bed. Each gasification process is described. The steam-iron process, raw and product gas compositions, gasifier feed quantities, and process efficiency evaluations are also included.

  4. Onboard hydrogen generation for automobiles

    NASA Technical Reports Server (NTRS)

    Houseman, J.; Cerini, D. J.

    1976-01-01

    Problems concerning the use of hydrogen as a fuel for motor vehicles are related to the storage of the hydrogen onboard a vehicle. The feasibility is investigated to use an approach based on onboard hydrogen generation as a means to avoid these storage difficulties. Two major chemical processes can be used to produce hydrogen from liquid hydrocarbons and methanol. In steam reforming, the fuel reacts with water on a catalytic surface to produce a mixture of hydrogen and carbon monoxide. In partial oxidation, the fuel reacts with air, either on a catalytic surface or in a flame front, to yield a mixture of hydrogen and carbon monoxide. There are many trade-offs in onboard hydrogen generation, both in the choice of fuels as well as in the choice of a chemical process. Attention is given to these alternatives, the results of some experimental work in this area, and the combustion of various hydrogen-rich gases in an internal combustion engine.

  5. Hydrogen Storage Technical Team Roadmap

    SciTech Connect

    2013-06-01

    The mission of the Hydrogen Storage Technical Team is to accelerate research and innovation that will lead to commercially viable hydrogen-storage technologies that meet the U.S. DRIVE Partnership goals.

  6. Oxidation resistant organic hydrogen getters

    DOEpatents

    Shepodd, Timothy J.; Buffleben, George M.

    2008-09-09

    A composition for removing hydrogen from an atmosphere, comprising a mixture of a polyphenyl ether and a hydrogenation catalyst, preferably a precious metal catalyst, and most preferably Pt. This composition is stable in the presence of oxygen, will not polymerize or degrade upon exposure to temperatures in excess of 200.degree. C., or prolonged exposure to temperatures in the range of 100-300.degree. C. Moreover, these novel hydrogen getter materials can be used to efficiently removing hydrogen from mixtures of hydrogen/inert gas (e.g., He, Ar, N.sub.2), hydrogen/ammonia atmospheres, such as may be encountered in heat exchangers, and hydrogen/carbon dioxide atmospheres. Water vapor and common atmospheric gases have no adverse effect on the ability of these getter materials to absorb hydrogen.

  7. Process for thermochemically producing hydrogen

    DOEpatents

    Bamberger, Carlos E.; Richardson, Donald M.

    1976-01-01

    Hydrogen is produced by the reaction of water with chromium sesquioxide and strontium oxide. The hydrogen producing reaction is combined with other reactions to produce a closed chemical cycle for the thermal decomposition of water.

  8. The Summer of Hydrogen

    NASA Technical Reports Server (NTRS)

    Weber, Philip

    2008-01-01

    Ground crew veterans at Kennedy Space Center still talk about what they call "the summer of hydrogen"-the long, frustrating months in 1990 when the shuttle fleet was grounded by an elusive hydrogen leak that foiled our efforts to fill the orbiter's external fuel tank. Columbia (STS-35) was on Launch Pad A for a scheduled May 30 launch when we discovered the hydrogen leak during - tanking. The external fuel tank is loaded through the orbiter. Liquid hydrogen flows through a 17-inch umbilical between the orbiter and the tank. During fueling, we purge the aft fuselage with gaseous nitrogen to reduce the risk of fire, and we have a leak-detection system in the mobile launch platform, which samples (via tygon tubing) the atmosphere in and around the vehicle, drawing it down to a mass spectrometer that analyzes its composition. When we progressed to the stage of tanking where liquid hydrogen flows through the vehicle, the concentration of hydrogen approached four percent-the limit above which it would be dangerously flammable. We had a leak. We did everything we could think of to find it, and the contractor who supplied the flight hardware was there every day, working alongside us. We did tanking tests, which involved instrumenting the suspected leak sources, and cryo-loaded the external tank to try to isolate precisely where the leak originated. We switched out umbilicals; we replaced the seals between the umbilical and the orbiter. We inspected the seals microscopically and found no flaws. We replaced the recirculation pumps, and we found and replaced a damaged teflon seal in a main propulsion system detent cover, which holds the prevalve-the main valve supplying hydrogen to Space Shuttle Main Engine 3 -in the open position. The seal passed leak tests at ambient temperature but leaked when cryogenic temperatures were applied. We added new leak sensors-up to twenty at a time and tried to be methodical in our placements to narrow down the possible sources of the problem

  9. Cesium Delivery System for Negative Ion Source at IPR

    SciTech Connect

    Bansal, G.; Pandya, K.; Soni, J.; Gahlaut, A.; Parmar, K. G.; Bandyopadhyay, M.; Chakraborty, A.; Singh, M. J.

    2011-09-26

    The technique of surface production of negative ions using cesium, Cs, has been efficiently exploited over the years for producing negative ion beams with increased current densities from negative ion sources used on neutral beam lines. Deposition of Cs on the source walls and the plasma grid lowers the work function and therefore enables a higher yield of H{sup -}, when hydrogen particles (H and/or H{sub x}{sup +}) strike these surfaces.A single driver RF based (100 kW, 1 MHz) negative ion source test bed, ROBIN, is being set up at IPR under a technical collaboration between IPR and IPP, Germany. The optimization of the Cs oven design to be used on this facility as well as multidriver sources is underway. The characterization experiments of such a Cs delivery system with a 1 g Cs inventory have been carried out using surface ionization technique. The experiments have been carried by delivering Cs into a vacuum chamber without plasma. The linear motion of the surface ionization detector, SID, attached with a linear motion feedthrough allows measuring the angular distribution of the Cs coming out of the oven. Based on the experimental results, a Cs oven for ROBIN has been proposed. The Cs oven design and experimental results of the prototype Cs oven are reported and discussed in the paper.

  10. Detroit Commuter Hydrogen Project

    SciTech Connect

    Brooks, Jerry; Prebo, Brendan

    2010-07-31

    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with

  11. Photovoltaic hydrogen production

    SciTech Connect

    Hiser, H.W.; Memory, S.B.; Veziroglu, T.N.; Padin, J.

    1996-10-01

    This is a new project, which started in June 1995, and involves photovoltaic hydrogen production as a fuel production method for the future. In order to increase the hydrogen yield, it was decided to use hybrid solar collectors to generate D.C. electricity, as well as high temperature steam for input to the electrolyzer. In this way, some of the energy needed to dissociate the water is supplied in the form of heat (or low grade energy), to generate steam, which results in a reduction of electrical energy (or high grade energy) needed. As a result, solar to hydrogen conversion efficiency is increased. In the above stated system, the collector location, the collector tracking sub-system (i.e., orientation/rotation), and the steam temperature have been taken as variables. Five locations selected - in order to consider a variety of latitudes, altitudes, cloud coverage and atmospheric conditions - are Atlanta, Denver, Miami, Phoenix and Salt Lake City. Plain PV and hybrid solar collectors for a stationary south facing system and five different collector rotation systems have been analyzed. Steam temperatures have been varied between 200{degrees}C and 1200{degrees}C. During the first year, solar to hydrogen conversion efficiencies have been considered. The results show that higher steam temperatures, 2 dimensional tracking system, higher elevations and dryer climates causes higher conversion efficiencies. Cost effectiveness of the sub-systems and of the overall system will be analyzed during the second year. Also, initial studies will be made of an advanced high efficiency hybrid solar hydrogen production system.

  12. Task D: Hydrogen safety analysis

    SciTech Connect

    Swain, M.R.; Sievert, B.G.; Swain, M.N.

    1996-10-01

    This report covers two topics. The first is a review of codes, standards, regulations, recommendations, certifications, and pamphlets which address safety of gaseous fuels. The second is an experimental investigation of hydrogen flame impingement. Four areas of concern in the conversion of natural gas safety publications to hydrogen safety publications are delineated. Two suggested design criteria for hydrogen vehicle fuel systems are proposed. It is concluded from the experimental work that light weight, low cost, firewalls to resist hydrogen flame impingement are feasible.

  13. Hydrogen Fire Spectroscopy Issues Project

    NASA Technical Reports Server (NTRS)

    Youngquist, Robert C. (Compiler)

    2014-01-01

    The detection of hydrogen fires is important to the aerospace community. The National Aeronautics and Space Administration (NASA) has devoted significant effort to the development, testing, and installation of hydrogen fire detectors based on ultraviolet, near-infrared, mid-infrared, andor far-infrared flame emission bands. Yet, there is no intensity calibrated hydrogen-air flame spectrum over this range in the literature and consequently, it can be difficult to compare the merits of different radiation-based hydrogen fire detectors.

  14. First experiments with the negative ion source NIO1

    NASA Astrophysics Data System (ADS)

    Cavenago, M.; Serianni, G.; De Muri, M.; Agostinetti, P.; Antoni, V.; Baltador, C.; Barbisan, M.; Baseggio, L.; Bigi, M.; Cervaro, V.; Degli Agostini, F.; Fagotti, E.; Kulevoy, T.; Ippolito, N.; Laterza, B.; Minarello, A.; Maniero, M.; Pasqualotto, R.; Petrenko, S.; Poggi, M.; Ravarotto, D.; Recchia, M.; Sartori, E.; Sattin, M.; Sonato, P.; Taccogna, F.; Variale, V.; Veltri, P.; Zaniol, B.; Zanotto, L.; Zucchetti, S.

    2016-02-01

    Neutral Beam Injectors (NBIs), which need to be strongly optimized in the perspective of DEMO reactor, request a thorough understanding of the negative ion source used and of the multi-beamlet optics. A relatively compact radio frequency (rf) ion source, named NIO1 (Negative Ion Optimization 1), with 9 beam apertures for a total H- current of 130 mA, 60 kV acceleration voltage, was installed at Consorzio RFX, including a high voltage deck and an X-ray shield, to provide a test bench for source optimizations for activities in support to the ITER NBI test facility. NIO1 status and plasma experiments both with air and with hydrogen as filling gas are described. Transition from a weak plasma to an inductively coupled plasma is clearly evident for the former gas and may be triggered by rising the rf power (over 0.5 kW) at low pressure (equal or below 2 Pa). Transition in hydrogen plasma requires more rf power (over 1.5 kW).

  15. First experiments with the negative ion source NIO1.

    PubMed

    Cavenago, M; Serianni, G; De Muri, M; Agostinetti, P; Antoni, V; Baltador, C; Barbisan, M; Baseggio, L; Bigi, M; Cervaro, V; Degli Agostini, F; Fagotti, E; Kulevoy, T; Ippolito, N; Laterza, B; Minarello, A; Maniero, M; Pasqualotto, R; Petrenko, S; Poggi, M; Ravarotto, D; Recchia, M; Sartori, E; Sattin, M; Sonato, P; Taccogna, F; Variale, V; Veltri, P; Zaniol, B; Zanotto, L; Zucchetti, S

    2016-02-01

    Neutral Beam Injectors (NBIs), which need to be strongly optimized in the perspective of DEMO reactor, request a thorough understanding of the negative ion source used and of the multi-beamlet optics. A relatively compact radio frequency (rf) ion source, named NIO1 (Negative Ion Optimization 1), with 9 beam apertures for a total H(-) current of 130 mA, 60 kV acceleration voltage, was installed at Consorzio RFX, including a high voltage deck and an X-ray shield, to provide a test bench for source optimizations for activities in support to the ITER NBI test facility. NIO1 status and plasma experiments both with air and with hydrogen as filling gas are described. Transition from a weak plasma to an inductively coupled plasma is clearly evident for the former gas and may be triggered by rising the rf power (over 0.5 kW) at low pressure (equal or below 2 Pa). Transition in hydrogen plasma requires more rf power (over 1.5 kW). PMID:26932048

  16. High-Yield Hydrogen Production from Starch and Water by a Synthetic Enzymatic Pathway

    PubMed Central

    Zhang, Y.-H. Percival; Evans, Barbara R.; Mielenz, Jonathan R.; Hopkins, Robert C.; Adams, Michael W.W.

    2007-01-01

    Background The future hydrogen economy offers a compelling energy vision, but there are four main obstacles: hydrogen production, storage, and distribution, as well as fuel cells. Hydrogen production from inexpensive abundant renewable biomass can produce cheaper hydrogen, decrease reliance on fossil fuels, and achieve zero net greenhouse gas emissions, but current chemical and biological means suffer from low hydrogen yields and/or severe reaction conditions. Methodology/Principal Findings Here we demonstrate a synthetic enzymatic pathway consisting of 13 enzymes for producing hydrogen from starch and water. The stoichiometric reaction is C6H10O5 (l)+7 H2O (l)→12 H2 (g)+6 CO2 (g). The overall process is spontaneous and unidirectional because of a negative Gibbs free energy and separation of the gaseous products with the aqueous reactants. Conclusions Enzymatic hydrogen production from starch and water mediated by 13 enzymes occurred at 30°C as expected, and the hydrogen yields were much higher than the theoretical limit (4 H2/glucose) of anaerobic fermentations. Significance The unique features, such as mild reaction conditions (30°C and atmospheric pressure), high hydrogen yields, likely low production costs ($∼2/kg H2), and a high energy-density carrier starch (14.8 H2-based mass%), provide great potential for mobile applications. With technology improvements and integration with fuel cells, this technology also solves the challenges associated with hydrogen storage, distribution, and infrastructure in the hydrogen economy. PMID:17520015

  17. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOEpatents

    Harkness, John B. L.; Gorski, Anthony J.; Daniels, Edward J.

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  18. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOEpatents

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  19. Magnetic levitation of condensed hydrogen

    NASA Technical Reports Server (NTRS)

    Paine, C. G.; Seidel, G. M.

    1991-01-01

    Liquid and solid molecular hydrogen has been levitated using a pair of small superconducting solenoids. The hydrogen samples, up to 3 mm in dimension, were trapped in a magnetic potential having either a discrete minimum or a minimum in the form of a ring 1 cm in diameter. The hydrogen could be moved about in the magnetic trap by applying an electric field.

  20. Hydrogen as an energy vector

    NASA Technical Reports Server (NTRS)

    Powers, W. D.

    1975-01-01

    The feasibility of utilizing hydrogen as an energy vector is considered, with special attention given to means of hydrogen production. The state-of-the-art in thermochemical processes is reviewed, and criteria for the technical and economic feasibility of large-scale thermochemical water splitting processes are presented. The production of hydrogen from coal and from photolysis of water is discussed.