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Last update: August 15, 2014.
1

Progress toward uranium scrap recycling via EBCHR.  

National Technical Information Service (NTIS)

A 250 kW electron beam cold hearth refining (EBCHR) melt furnace at Lawrence Livermore National Laboratory (LLNL) has been in operation for over a year producing 5.5 in.-diameter ingots of various uranium alloys. Production of in-specification uranium-6%-...

R. H. McKoon

1994-01-01

2

Fernald scrap metal recycling and beneficial reuse  

Microsoft Academic Search

The Fernald site, formerly the Feed Materials Production Facility, produced uranium metal products to meet defense production requirements for the Department of Energy from 1953 to 1989. In this report is is described how the Fernald scrap metal project has demonstrated that contractor capabilities can be used successfully to recycle large quantities of Department of Energy scrap metal. The project

G. P. Motl; D. D. Burns

1993-01-01

3

Scrap tire recycling  

SciTech Connect

As the automobile tire technology has grown and met the need for safer and more durable tires, stronger reinforcement and more chemically resistant rubber compounds have made recycling tires more difficult. In an effort to resolve this problem, techniques and equipment were developed to grind tires into small pieces, and new markets were sought to utilize the crumb rubber product streams from ground tires. Industrial combustion processes were modified to accept scrap tires as fuel. These efforts have been beneficial, steadily increasing the percentage of scrap tires recycled to about 10% in 1985, and reaching 72% in 1995. By the end of 1997, fully 100% of tires generated in the U.S. are expected to be recycled.

Lula, J.W.; Bohnert, G.W.

1997-03-01

4

Recycling industries: Booming with scrap growth  

Microsoft Academic Search

The rise of consolidation in the scrap metal recycling industry trails, but parallels, the larger waste hauling industry, according to one of the leading scrap metal processors in the US. Recycling Industries (Englewood, CO) has been extremely active in acquiring new businesses since it received a $220 million capital loan last December. The company`s facilities number about 56 in 12

Malloy

1998-01-01

5

Management of scrap computer recycling in Taiwan.  

PubMed

It is estimated that approximately 300,000 scrap personal computers are generated each year in Taiwan [S.-L. Chang, A Study on the Scrap Computer Treatment Cost, Environment Protection Administration of Taiwan, December 1998 (in Chinese)]. The disposal of such a huge number of scrap computers presents a difficult task for the island due to the scarcity of landfills and incineration facilities available locally. Also, the hazardous materials contained (i.e., phosphor coatings of cathode ray tubes (CRTs), batteries, polychlorinated biphenyl capacitors, mercury-containing parts, liquid crystal display, high-lead content CRT funnel glass, and plastic containing flame-retardant bromine, etc.) in the scrap computers may seriously pollute the environment if they are not properly disposed of. Therefore, the EPA of Taiwan declared scrap personal computers the producer's recycling responsibility as of July 1997. Under this decree, the manufacturers, importers and sellers of personal computers have to properly recover and recycle the scrapped computers which they originally sell. On June 1, 1998, a producer responsibility recycling program for scrap computers was officially implemented in Taiwan. Under this program, consumers can bring their unwanted personal computers to the designated collection points and receive reward money. Currently, only six computer items are mandated to be recycled in this recycling program. They are notebooks, monitors, hard disks, power supplies, printed circuit boards and main frame shells. This article outlines the current scrap computer recycling system in Taiwan. PMID:10751692

Lee, C H; Chang, S L; Wang, K M; Wen, L C

2000-04-28

6

A recycling process for dezincing steel scrap  

SciTech Connect

In response to the several-fold increase in consumption of galvanized steel in the last decade and the problems associated with refurnacing larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is electrowon as dendritic powder. The process is effective for zinc, lead, aluminum, and cadmium removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested for batch treatment of 1,000 tons of mostly baled scrap. A pilot plant to continuously treat loose scrap is under construction. Use of degalvanized steel scrap decreases raw materials and environmental compliance costs to steel- and iron-makers, may enable integrated steel producers to recycle furnace dusts to the sinter plant, and may enable EAF production of flat products without use of DRI or pig iron. Recycling the components of galvanized steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap.

Dudek, F.J.; Daniels, E.J. (Argonne National Lab., IL (United States)); Morgan, W.A.; Kellner, A.W.; Harrison, J. (Metal Recovery Industries, Inc., Hamilton, ON (Canada))

1992-01-01

7

A recycling process for dezincing steel scrap  

SciTech Connect

In response to the several-fold increase in consumption of galvanized steel in the last decade and the problems associated with refurnacing larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is electrowon as dendritic powder. The process is effective for zinc, lead, aluminum, and cadmium removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested for batch treatment of 1,000 tons of mostly baled scrap. A pilot plant to continuously treat loose scrap is under construction. Use of degalvanized steel scrap decreases raw materials and environmental compliance costs to steel- and iron-makers, may enable integrated steel producers to recycle furnace dusts to the sinter plant, and may enable EAF production of flat products without use of DRI or pig iron. Recycling the components of galvanized steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap.

Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Morgan, W.A.; Kellner, A.W.; Harrison, J. [Metal Recovery Industries, Inc., Hamilton, ON (Canada)

1992-08-01

8

Recycling zinc by dezincing steel scrap  

SciTech Connect

In response to the worldwide increase in consumption of galvanized steel for automobiles in the last fifteen years, and the increased cost of environmental compliance associated with remelting larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is recovered electrolytically as dendritic powder. The designed ferrous scrap is rinsed and used directly. The process is effective for zinc, lead, and aluminum removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested in Hamilton, Ontario for batch treatment of 900 tonnes of mostly baled scrap. A pilot plant in East Chicago, Indiana has designed in a continuous process mode 900 tonnes of loose stamping plant scrap; this scrap typically has residual zinc below 0.1% and sodium dragout below 0.001%. This paper reviews pilot plant performance and the economics of recycling galvanized steel and recovering zinc using a caustic process.

Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Morgan, W.A. [Metal Recovery Industries, Inc., East Chicago, IN (United States)

1995-06-01

9

High Value Scrap Tire Recycle  

SciTech Connect

The objectives of this project were to further develop and scale-up a novel technology for reuse of scrap tire rubber, to identify and develop end uses for the technology (products), and to characterize the technology's energy savings and environmental impact.

Bauman, B. D.

2003-02-01

10

Evaluation of radioactive scrap metal recycling  

SciTech Connect

This report evaluates the human health risks and environmental and socio-political impacts of options for recycling radioactive scrap metal (RSM) or disposing of and replacing it. Argonne National Laboratory (ANL) is assisting the US Department of Energy (DOE), Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, in assessing the implications of RSM management alternatives. This study is intended to support the DOE contribution to a study of metal recycling being conducted by the Task Group on Recycling and Reuse of the Organization for Economic Cooperation and Development. The focus is on evaluating the justification for the practice of recycling RSM, and the case of iron and steel scrap is used as an example in assessing the impacts. To conduct the evaluation, a considerable set of data was compiled and developed. Much of this information is included in this document to provide a source book of information.

Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

1995-12-01

11

Evaluation of radioactive scrap metal recycling  

Microsoft Academic Search

This report evaluates the human health risks and environmental and socio-political impacts of options for recycling radioactive scrap metal (RSM) or disposing of and replacing it. Argonne National Laboratory (ANL) is assisting the US Department of Energy (DOE), Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, in assessing the implications of RSM management alternatives. This study is

L. A. Nieves; S. Y. Chen; E. J. Kohout; B. Nabelssi; R. W. Tilbrook; S. E. Wilson

1995-01-01

12

Chemical recycling of scrap composites  

NASA Technical Reports Server (NTRS)

There are no well-developed technologies for recycling composite materials other than grinding to produce fillers. New approaches are needed to reclaim these valuable resources. Chemical or tertiary recycling, conversion of polymers into low molecular weight hydrocarbons for reuse as chemicals or fuels, is emerging as the most practical means for obtaining value from waste plastics and composites. Adherent Technologies is exploring a low-temperature catalytic process for recycling plastics and composites. Laboratory results show that all types of plastics, thermosets as well as thermoplastics, can be converted in high yields to valuable hydrocarbon products. This novel catalytic process runs at 200 C, conversion times are rapid, the process is closed and, thus, nonpolluting, and no highly toxic gas or liquid products have been observed so no negative environmental impact will result from its implementation. Tests on reclamation of composite materials show that epoxy, imide, and engineering thermoplastic matrices can be converted to low molecular weight hydrocarbons leaving behind the reinforcing fibers for reuse as composite reinforcements in secondary, lower-performance applications. Chemical recycling is also a means to dispose of sensitive or classified organic materials without incineration and provides a means to eliminate or reduce mixed hazardous wastes containing organic materials.

Allred, Ronald E.; Salas, Richard M.

1994-01-01

13

Recycling metal scrap. (Latest citations from the EI COMPENDEX*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning the methods and equipment for recycling metal and steel scrap. Citations discuss automatic scrap recycling, scrap metal reprocessing, contaminated metal scrap, and mass-produced building materials from scrap. The design and evaluation of recycling processes in automotive, aircraft, beverage, electronics, and milling industries are examined. (Contains 250 citations and includes a subject term index and title list.)

NONE

1995-03-01

14

Considerations in recycling contaminated scrap metal and rubble  

Microsoft Academic Search

Management options for the Department of Energy's increasing amounts of contaminated scrap metal and rubble include reuse as is, disposal, and recycling. Recycling, with its promise of resource recovery, virgin materials conservation, and land disposal minimization, emerges as a preferred management technique. Implementing a cost effective recycling program requires resolution of several issues including: establishing release limits for contaminants, controlling

A. F. Kluk; E. K. Hocking

1992-01-01

15

Considerations in recycling contaminated scrap metal and rubble  

Microsoft Academic Search

Management options for the Department of Energy`s increasing amounts of contaminated scrap metal and rubble include reuse as is, disposal, and recycling. Recycling, with its promise of resource recovery, virgin materials conservation, and land disposal minimization, emerges as a preferred management technique. Implementing a cost effective recycling program requires resolution of several issues including: establishing release limits for contaminants, controlling

A. F. Kluk; E. K. Hocking

1992-01-01

16

Upgrading nonferrous metal scrap for recycling purposes  

Microsoft Academic Search

Reusing materials in the post-consumer phase of a product is very important; however, it is often difficult to separate the metals, resulting in a scrap that is high in impurities and limited in application. To prevent the mixing of scrap, separation at the source is required. Recently, several techniques for separating nonferrous metals have become available, including eddy-current separation to

Gerrit H. Nijhof; Peter C. Rem

1999-01-01

17

Recycling metal scrap. (Latest citations from the EI Compendex*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning the methods and equipment for recycling metal and steel scrap. Citations discuss automatic scrap recycling, scrap metal reprocessing, contaminated metal scrap, and mass-produced building materials from scrap. The design and evaluation of recycling processes in automotive, aircraft, beverage, electronics, and milling industries are examined. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-11-01

18

Upgrading nonferrous metal scrap for recycling purposes  

Microsoft Academic Search

Reusing materials in the post-consumer phase of a product is very important; however, it is often difficult to separate the\\u000a metals, resulting in a scrap that is high in impurities and limited in application. To prevent the mixing of scrap, separation\\u000a at the source is required. Recently, several techniques for separating nonferrous metals have become available, including\\u000a eddy-current separation to

Gerrit H. Nijhof; Peter C. Rem

1999-01-01

19

Recycling process for dezincing steel scrap.  

National Technical Information Service (NTIS)

In response to the several-fold increase in consumption of galvanized steel in the last decade and the problems associated with refurnacing larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zin...

F. J. Dudek E. J. Daniels W. A. Morgan A. W. Kellner J. Harrison

1992-01-01

20

Metal recycling from scrap and waste materials  

Microsoft Academic Search

Out of a total U.K. consumption of 2.5 million tonnes per annum of nonferrous metals, as much as 33% is recovered from scrap. The structure of the industry which makes this important contribution to the economy is briefly outlined, and the technology is described by which the various nonferrous metals are recovered in reusable form from waste materials. Data on

A. W. Fletcher

1976-01-01

21

Assessment of recycling or disposal alternatives for radioactive scrap metal  

SciTech Connect

The US Department of Energy, Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, is participating with the Organization for Economic Cooperation and Development in providing analytical support for evaluation of management alternatives for radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing environmental and societal implications of recycling and/or disposal process alternatives. This effort includes development of inventory estimates for contaminated metals; investigation of scrap metal market structure, processes, and trends; assessment of radiological and nonradiological effects of recycling; and investigation of social and political factors that are likely to either facilitate or constrain recycling opportunities. In addition, the option of scrap metal disposal is being assessed, especially with regard to the environmental and health impacts of replacing these metals if they are withdrawn from use. This paper focuses on the radiological risk assessment and dose estimate sensitivity analysis. A {open_quotes}tiered{close_quotes} concept for release categories, with and without use restrictions, is being developed. Within the tiers, different release limits may be indicated for specific groupings of radionuclides. Depending on the spectrum of radionuclides that are present and the level of residual activity after decontamination and/or smelting, the scrap may be released for unrestricted public use or for specified public uses, or it may be recycled within the nuclear industry. The conservatism of baseline dose estimates is examined, and both more realistic parameter values and protective measures for workers are suggested.

Murphie, W.E.; Lilly, M.J. III [US Dept. of Energy, Oak Ridge, TN (United States); Nieves, L.A.; Chen, S.Y. [Argonne National Lab., IL (United States)

1993-11-01

22

Assessment of recycling or disposal alternatives for radioactive scrap metal  

Microsoft Academic Search

The US Department of Energy, Office of Environmental Restoration and Waste Management, is participating with the Organization for Economic Cooperation and Development (OECD) is an evaluation of management alternatives for radioactive scarp metals. For this purpose, Argonne National Laboratory is assessing alternatives for radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing environmental and societal implications of recycling

W. E. Murphie; M. J. Lilly; L. A. Nieves; S. Y. Chen

1993-01-01

23

Innovative technologies for recycling contaminated concrete and scrap metal  

Microsoft Academic Search

Decontamination and decommissioning of US DOE`s surplus facilities will generate enormous quantities of concrete and scrap metal. A solicitation was issued, seeking innovative technologies for recycling and reusing these materials. Eight proposals were selected for award. If successfully developed, these technologies will enable DOE to clean its facilities by 2019.

S. J. Bossart; J. Moore

1993-01-01

24

Assessment of recycling or disposal alternatives for radioactive scrap metal  

Microsoft Academic Search

The US Department of Energy, Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, is participating with the Organization for Economic Cooperation and Development in providing analytical support for evaluation of management alternatives for radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing environmental and societal implications of recycling and\\/or disposal process alternatives. This effort includes

W. E. Murphie; M. J. Lilly; L. A. Nieves; S. Y. Chen

1993-01-01

25

Investigating the recycling of nickel hydride battery scrap  

NASA Astrophysics Data System (ADS)

New nickel hydride alloys have been developed to replace the cadmium-containing negative electrodes of nickel-cadmium batteries. The new, cadmium free alloys promise enhanced electrochemical properties as well as reduced environmental toxicity. Rechargeable batteries using nickel hydride electrodes are strong candidates for electric vehicle applications. The U.S. Bureau of Mines is investigating hydrometallurgical technology that separates and recovers purified metallic components present in nickel hydride battery scrap. A preliminary investigation of acid dissolution and metal recovery techniques using whole batteries and electrode rolls has shown potential options that will allow the successful recycling of much of the battery fabrication scrap.

Lyman, Jane W.; Palmer, Glenn R.

1993-05-01

26

Recycling metal scrap. (Latest citations from the EI compendex*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning the processes, techniques, and benefits of recycling metal scrap. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries is considered. Analyses of the current global scrap metal recycling trends are included. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-11-01

27

Feasibility analysis of recycling radioactive scrap steel  

SciTech Connect

The purpose of this study is to: (1) establish a conceptual design that integrates commercial steel mill technology with radioactive scrap metal (RSM) processing to produce carbon and stainless steel sheet and plate at a grade suitable for fabricating into radioactive waste containers; (2) determine the economic feasibility of building a micro-mill in the Western US to process 30,000 tons of RSM per year from both DOE and the nuclear utilities; and (3) provide recommendations for implementation. For purposes of defining the project, it is divided into phases: economic feasibility and conceptual design; preliminary design; detail design; construction; and operation. This study comprises the bulk of Phase 1. It is divided into four sections. Section 1 provides the reader with a complete overview extracting pertinent data, recommendations and conclusions from the remainder of the report. Section 2 defines the variables that impact the design requirements. These data form the baseline to create a preliminary conceptual design that is technically sound, economically viable, and capitalizes on economies of scale. Priorities governing the design activities are: (1) minimizing worker exposure to radionuclide hazards, (2) maximizing worker safety, (3) minimizing environmental contamination, (4) minimizing secondary wastes, and (5) establishing engineering controls to insure that the plant will be granted a license in the state selected for operation. Section 3 provides details of the preliminary conceptual design that was selected. The cost of project construction is estimated and the personnel needed to support the steel-making operation and radiological and environmental control are identified. Section 4 identifies the operational costs and supports the economic feasibility analysis. A detailed discussion of the resulting conclusions and recommendations is included in this section.

Nichols, F. [Manufacturing Sciences Corp., Woodland, WA (United States); Balhiser, B. [MSE, Inc., Butte, MT (United States); Cignetti, N. [Cignetti Associates, North Canton, OH (United States)] [and others

1995-09-01

28

Exothermic Reactions Leading to Unexpected Meltdown of Scrap Uranium--Aluminum Cermet Cores During Outgassing.  

National Technical Information Service (NTIS)

During routine outgassing of scrap uranium-aluminum cermet cores, unexpected exothermic reactions released sufficient energy to melt nine cores. In the subsequent investigation, compounds in the scrap uranium were identified, the history of the material w...

L. W. Gray W. J. Kerrigan

1978-01-01

29

UTILIZATION OF SCRAP PREPREG WASTES AS A REINFORCEMENT IN A WHOLLY RECYCLED PLASTIC - PHASE I  

EPA Science Inventory

Foster-Miller proposes to utilize scrap prepreg waste as a reinforcement in recycled polyethylene. By reinforcing recycled plastics such as polyethylene with scrap prepreg and suitable binders, an economical useful product can be obtained. At the same time, this innovation ...

30

Assessment of recycling or disposal alternatives for radioactive scrap metal  

SciTech Connect

The US Department of Energy, Office of Environmental Restoration and Waste Management, is participating with the Organization for Economic Cooperation and Development (OECD) is an evaluation of management alternatives for radioactive scarp metals. For this purpose, Argonne National Laboratory is assessing alternatives for radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing environmental and societal implications of recycling and/or disposal process alternatives (with metal replacement). Findings will be presented in a report from the OECD Task Group. This paper focuses on the radiological risk assessment and dose estimate sensitivity analysis. A ``tiered`` concept for release categories, with and without use restrictions, is being developed. Within the tiers, different release limits may be indicated for specific groupings of radionuclides. Depending on the spectrum of radionuclides that are present and the level of residual activity after decontamination and/or smelting, the scrap may be released for unrestricted public use or for specified public uses, or it may be recycled within the nuclear industry. The conversatism of baseline dose estimates is examined, and both more realistic parameter values and protective measures for workers are suggested.

Murphie, W.E.; Lilly, M.J. III [USDOE Assistant Secretary for Environmental Restoration and Waste Management, Washington, DC (United States). Office of Environmental Restoration; Nieves, L.A.; Chen, S.Y. [Argonne National Lab., IL (United States)

1993-10-01

31

Recycling metal scrap. June 1970-January 1990 (A Bibliography from the COMPENDEX database). Report for June 1970-January 1990  

SciTech Connect

This bibliography contains citations concerning the processes, techniques, and benefits of recycling metal scrap. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries is considered. Analyses of the current global scrap metal recycling trends are included. (This updated bibliography contains 362 citations, 21 of which are new entries to the previous edition.)

Not Available

1990-03-01

32

Recycling metal scrap. June 1970-April 1989 (Citations from the COMPENDEX data base). Report for June 1970-April 1989  

SciTech Connect

This bibliography contains citations concerning the processes, techniques, and benefits of recycling metal scrap. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries are considered. Analysis of the current global scrap metal recycling trends are included. (This updated bibliography contains 341 citations, 63 of which are new entries to the previous edition.)

Not Available

1989-05-01

33

Guidance for the Identification and Control of Safety and Health Hazards in Metal Scrap Recycling.  

National Technical Information Service (NTIS)

Anyone who works in the metal scrap recycling industry- employers, employees, safety professionals, and industrial hygienists-should read this publication. This guide can help you identify and manage the hazards associated with exposure to various metals ...

2008-01-01

34

Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-04-01

35

Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains a minimum of 88 citations and includes a subject term index and title list.)

NONE

1995-01-01

36

Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-02-01

37

Recycling plastic scrap: Injection molding. (Latest citations from the Rubber and Plastics Research Association database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of scrap plastic produced in the injection molding process. Plastic pellets made from scrap, that are used in the injection molding process, are also discussed. Recycling equipment and automated recycling systems are described. The reuse of plastic scrap culled from junk automobiles and packaging materials is discussed, and waste byproducts from polyurethane production are described. (Contains a minimum of 80 citations and includes a subject term index and title list.)

Not Available

1994-05-01

38

Health risk and impact evaluation for recycling of radioactive scrap metal  

Microsoft Academic Search

The DoE, Office of Environmental Restoration and Waste Management, is participating with the Organization for Economic Cooperation and Development in providing analytical support for developing international standards for recycling of radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing health, environmental and societal implications of recycling and\\/or disposal process alternatives. This effort includes development of international inventory estimates

L. A. Nieves; S. Y. Chen; W. E. Murphie; M. J. Lilly

1994-01-01

39

The recycling of standard quality wrought aluminum alloys from low-grade contaminated scrap  

NASA Astrophysics Data System (ADS)

In recent decades an increasingly large fraction of the world’s wrought aluminum alloys supply has come from the aluminum scrap recovered from industrial waste and discarded post-consumer items. However, replacing even a minor part of primary aluminum in wrought alloys with recycled counterpart originated from lower grades of scrap (typically scrap contaminated with various non-metallic impurities) without influencing the quality of the allay is very demanding from a metallurgical point of view. This article discusses the two approaches for achieving the requested chemical composition of wrought alloys made from recycled aluminum: (i) before melting, by combining the appropriate qualities and quantities of scrap, primary aluminum, and the alloying elements and (ii) during melting, by diluting impurity content with primary aluminum to the needed level and adding, at the same time, the necessary amount of alloying elements for achieving their standard concentration in diluted melts.

Kevorkjjan, Varužan

2010-08-01

40

A NOVEL RECYCLING PROCESS OF TITANIUM METAL SCRAPS BY USING CHLORIDE WASTES  

Microsoft Academic Search

A novel process of recycling titanium metal scraps by utilizing chloride wastes (e.g., FeClx and AlCl3) that are obtained as by-products in the Kroll process or any other chlorination process has been investigated in this study. This is important from the viewpoint of the increase in titanium metal scraps and chloride wastes in the future. Thermodynamic analyses and some primary

Haiyan Zheng; Toru H. Okabe

41

RESRAD-RECYCLE : a computer model for analyzing radiation exposures resulting from recycling radioactively contaminated scrap metals or reusing ratioactively surface-contaminated materials and equipment  

Microsoft Academic Search

RESRAD-RECYCLE is a computer code designed by Argonne National Laboratory (ANL) to be used in making decisions about the disposition of radioactively contaminated materials and scrap metals. It implements a pathway analysis methodology to evaluate potential radiation exposures resulting from the recycling of contaminated scrap metals and the reuse of surface-contaminated materials and equipment. For modeling purposes, it divides the

Jing-Jy Cheng; Bassel Kassas; Charley Yu; John Arnish; Dave LePoire; Shih-Yew Chen; W. A. Williams; A. Wallo; H. Peterson

2004-01-01

42

Scrap tire recycling: Promising high value applications. Final report  

SciTech Connect

Surface modification of scrap tire rubber (rubber particles treated with chlorine gas) show promise for ameliorating the scrap tire problem (the treated rubber can be used as a component in high- performance, expensive polymer systems). The process has been proven in Phase I. Phase II covers market/applications, process development (Forberg-design mixer reactor was chosen), plant design, capital cost estimate, economics environmental/safety/health, and energy impact. Almost of the small amount of chlorine is consumed. The capital costs for a rubber particle treatment facility are attractive, being at least two orders of magnitude less than that of facilities for making new polymer materials. Large volume markets using treated rubber are needed. The amount of scrap rubber available is small compared to the polymers available for replacement. 7 tabs, 16 figs.

Bauman, B.D.; Leskovyansky, P.J.; Drela, H.

1993-11-01

43

SOLUBILITY CHARACTERIZATION OF AIRBORNE URANIUM FROM A URANIUM RECYCLING PLANT  

Microsoft Academic Search

Solubility profiles of uranium dusts in a uranium r ecycling plant were determined by performing in vitro solubility tests on breathing zone air samples con ducted in all process areas of the processing plant. The recycling plant produces hig h density shields, closed end tubes that are punch and formed from uranium sheet metal, and high-fired uranium oxide which is

Robert Metzger; Leslie Cole

2004-01-01

44

INEL metal recycle radioactive scrap metal survey report  

Microsoft Academic Search

DOE requested that inventory and characterization of radioactive scrap metal (RSM) be conducted across the DOE complex. Past studies have estimated the metal available from unsubstantiated sources. In meetings held in FY-1993, with seven DOE sites represented and several DOE-HQ personnel present, INEL personnel discovered that these numbers were not reliable and that large stockpiles did not exist. INEL proposed

Funk

1994-01-01

45

Recycling of gamma titanium aluminide scrap from investment casting operations  

Microsoft Academic Search

In investment casting processes for TiAl alloys, a substantial amount of the original raw material does not end-up as a final product but is instead solidified in runners and feeders of the casting system or as a skull in the crucible. Because of the high prices for the virgin alloys, there is a strong interest in remelting this scrap. This

J. Reitz; C. Lochbichler; B. Friedrich

2011-01-01

46

Recycling of metal scraps—a positive concept leading to augmentation of reserve base  

Microsoft Academic Search

Recycling gives the industry a means to create treasure out of trash. Recycling of used metals in the form of scrap or secondary\\u000a articles has assumed significance, especially in developing countries like India where reprocessing to recover metal is needed\\u000a to meet the raw material deficit as well as conservation of minerals. For India, where labour is cheap, the metal

Pradeep Kumar Jain

47

Contamination of soil and plant by recycling of scrap plastics. [Ipomoea aquatica  

Microsoft Academic Search

The present study concerns a small factory engaged in the recycling of scrap plastics by removing metals from plated surfaces with acid. The rinsing water was discharged into an old fish pond, eventually causing fish-kills in a number of nearby fish ponds and affecting vegetable cultivations in field on the downhill side of the factory through runoff. Ten sites were

V. W. D. Chui; G. Y. S. Chan; Y. H. Cheung; M. H. Wong

1988-01-01

48

Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap.  

National Technical Information Service (NTIS)

Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mec...

A. C. Powell

2012-01-01

49

Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap  

SciTech Connect

Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

Adam C. Powell, IV

2012-07-19

50

Approach and issues toward development of risk-based release standards for radioactive scrap metal recycle and reuse  

Microsoft Academic Search

The decontamination and decommissioning of nuclear facilities is expected to generate large amounts of slightly radioactive scrap metal (RSM). It is likely that some of these materials will be suitable for recycling and reuse. The amount of scrap steel from DOE facilities, for instance, is estimated to be more than one million tons (Hertzler 1993). However, under current practice and

S. Y. Chen; L. A. Nieves; B. K. Nabelssi; D. J. LePoire

1994-01-01

51

ISASMELT™ for the Recycling of E-Scrap and Copper in the U.S. Case Study Example of a New Compact Recycling Plant  

NASA Astrophysics Data System (ADS)

As living standards around the world improve and metal consumption increases, extracting raw materials will likely become more challenging in the future. Although already part of the general metal supply stream, metal recycling has to increase if we are to build a more sustainable society. With the recent widespread adoption of a range of consumer and industrial electronics, the recycling of the so-called electronic scrap ("e-scrap") has also increased in importance. One of the leading technologies for the recycling of e-scrap and copper scrap is the ISASMELT™ Top Submerged Lance technology. This article describes new opportunities for the U.S. recycling industry to yield full value from collected, sorted, and separated waste metals, in particular, e-scrap and lower grade copper scrap by the use of ISASMELT™ technology. The article includes the description of a case study example of a regional, compact ISASMELT™ plant in the United States treating a blend of e-scrap and copper scrap, having a total feed capacity of 75000 t/year of feed. Plants of higher or lower capacity are also discussed.

Alvear Flores, Gerardo R. F.; Nikolic, Stanko; Mackey, Phillip J.

2014-03-01

52

ISASMELT™ for the Recycling of E-Scrap and Copper in the U.S. Case Study Example of a New Compact Recycling Plant  

NASA Astrophysics Data System (ADS)

As living standards around the world improve and metal consumption increases, extracting raw materials will likely become more challenging in the future. Although already part of the general metal supply stream, metal recycling has to increase if we are to build a more sustainable society. With the recent widespread adoption of a range of consumer and industrial electronics, the recycling of the so-called electronic scrap ("e-scrap") has also increased in importance. One of the leading technologies for the recycling of e-scrap and copper scrap is the ISASMELT™ Top Submerged Lance technology. This article describes new opportunities for the U.S. recycling industry to yield full value from collected, sorted, and separated waste metals, in particular, e-scrap and lower grade copper scrap by the use of ISASMELT™ technology. The article includes the description of a case study example of a regional, compact ISASMELT™ plant in the United States treating a blend of e-scrap and copper scrap, having a total feed capacity of 75000 t/year of feed. Plants of higher or lower capacity are also discussed.

Alvear Flores, Gerardo R. F.; Nikolic, Stanko; Mackey, Phillip J.

2014-05-01

53

Health risk and impact evaluation for recycling of radioactive scrap metal  

SciTech Connect

The DoE, Office of Environmental Restoration and Waste Management, is participating with the Organization for Economic Cooperation and Development in providing analytical support for developing international standards for recycling of radioactive scrap metals. For this purpose, Argonne National Laboratory is assessing health, environmental and societal implications of recycling and/or disposal process alternatives. This effort includes development of international inventory estimates for contaminated metals; investigation of international scrap metal markets; assessment of radiological and non-radiological human health risks; impacts on environmental quality and resources; and investigation of social and political factors. The RSM disposal option is being assessed with regard to the environmental and health impacts of replacing the metals if they are withdrawn from use. Impact estimates are developed for steel as an illustrative example because steel comprises a major portion of the scrap metal inventory. Current and potential sources of RSM include nuclear power plants, fuel cycle and weapons production facilities, industrial and medical facilities and equipment, and petroleum and phosphate rock extraction equipment. Millions of metric tons (t) of scrap iron and steel, stainless steel, and copper, as well as lesser quantities of aluminum, nickel, lead, and zirconium, are likely to become available in the future as these facilities are withdrawn from service.

Nieves, L.A.; Chen, S.Y. [Argonne National Lab., IL (United States); Murphie, W.E.; Lilly, M.J. III [USDOE, Washington, DC (United States)

1994-03-01

54

Collection and recycling of electronic scrap: a worldwide overview and comparison with the Brazilian situation.  

PubMed

Recycling and the related issue of sustainable development are increasing in importance around the world. In Brazil, the new National Policy on Solid Wastes has prompted discussion on the future of electronic waste (e-waste). Over the last 10 years, different e-waste collection systems and recycling processes have been applied globally. This paper presents the systems used in different countries and compares the world situation to the current Brazilian reality. To establish a recycling process, it is necessary to organize efficient collection management. The main difficulty associated with the implementation of e-waste recycling processes in Brazil is the collection system, as its efficiency depends not only on the education and cooperation of the people but also on cooperation among industrial waste generators, distributors and the government. Over half a million waste pickers have been reported in Brazil and they are responsible for the success of metal scrap collection in the country. The country also has close to 2400 companies and cooperatives involved in recycling and scrap trading. On the other hand, the collection and recycling of e-waste is still incipient because e-wastes are not seen as valuable in the informal sector. The Brazilian challenge is therefore to organize a system of e-waste management including the informal sector without neglecting environmentally sound management principles. PMID:22552043

de Oliveira, Camila Reis; Bernardes, Andréa Moura; Gerbase, Annelise Engel

2012-08-01

55

Solubility characterization of airborne uranium from a uranium recycling plant.  

PubMed

Solubility profiles of uranium dusts in a uranium recycling plant were determined by performing in vitro solubility tests on breathing zone air samples conducted in all process areas of the processing plant. The recycling plant produces high density shields, closed end tubes that are punched and formed from uranium sheet metal, and high-fired uranium oxide, which is used as a catalyst. The recycled uranium is cut and melted in a vacuum furnace, and part of the molten uranium is poured into molds for further processing. Air samples were taken in process areas under normal working conditions. The dissolution rate of the uranium in a simulant solution of extracellular airway lining fluid (Gamble's solution) was then determined over the next 28 d. Airborne uranium in the oxide section of the plant was found to be highly insoluble with 99% of the uranium having a dissolution half time in excess of 100 d. The solubility of the airborne uranium in other areas of the facility was only slightly more soluble with over 90% of the airborne uranium having dissolution half times in excess of 90 d. PMID:15194928

Metzger, Robert; Cole, Leslie

2004-07-01

56

Fernald scrap metal and recycling and beneficial reuse  

Microsoft Academic Search

The Fernald plant, formerly known as the Feed Materials Production Facility, is located on a 1050-acre site 17 miles northwest of downtown Cincinnati, Ohio. Site construction was initiated in 1951 to fabricate uranium metal to meet defense production requirements of the U.S. Department of Energy (DOE). In October 1990, the DOE transferred management responsibility for the site from its Defense

Motl

1993-01-01

57

Cryogenic grinding: an efficient method for recycling scrap rubber  

SciTech Connect

Cryogenic grinding represents an opportunity for expanding recycling capabilities to a broad range of compounds. Many materials that can be reduced to a powder by conventional coarse grinding can be reduced more efficiently by using a super-cold agent such as liquid nitrogen at -320/sup 0/F to embrittle plastic or rubber polymers before grinding. In addition, cryogenic grinding makes possible the size reduction of many materials that cannot be ground by conventional ambient grinding methods. Some experiences of cryogenic grinding in practice at United Tire and Rubber company, Limited, headquartered in Rexdale, Ontario, are noted. A schematic of such a system is shown.

Not Available

1980-06-01

58

Toxicity tests of soil contaminated by recycling of scrap plastics  

SciTech Connect

The present investigation studied the toxicity of soil contaminated by untreated discharge from a factory that recycles used plastics. The nearby agricultural areas and freshwater fish ponds were polluted with high concentrations of Cu, Ni, and Mn. Water extracts from the contaminated soil retarded root growth of Brassica chinensis (Chinese white cabbage) and Cynodon dactylon (Bermuda grass) where their seeds were obtained commercially. The contaminated populations of C. dactylon, Panicum repen (panic grass), and Imperata cylindrica (wooly grass) were able to withstand higher concentrations of Cu, Ni, and Mn, especially C. dactylon, when compared with their uncontaminated counterparts.

Wong, M.H.; Chui, V.W. (Hong Kong Baptist College, Kowloon (Hong Kong))

1990-03-01

59

Recycling of aluminium scrap for secondary Al-Si alloys.  

PubMed

An increasing amount of recycled aluminium is going into the production of aluminium alloy used for automotive applications. In these applications, it is necessary to control and remove alloy impurities and inclusions. Cleaning and fluxing processes are widely used during processing of the alloys for removal of inclusions, hydrogen and excess of magnesium. These processes use salt fluxes based in the system NaCl-KCl, injection of chlorine or mixture of chlorine with an inert gas. The new systems include a graphite wand and a circulation device to force convection in the melt and permit the bubbling and dispersion of reactive and cleaning agents. This paper discusses the recycling of aluminium alloys in rotary and reverberatory industrial furnaces. It focuses on the removal of magnesium during the melting process. In rotary furnaces, the magnesium lost is mainly due to the oxidation process at high temperatures. The magnesium removal is carried out by the reaction between chlorine and magnesium, with its efficiency associated to kinetic factors such as concentration of magnesium, mixing, and temperature. These factors are also related to emissions generated during the demagging process. Improvements in the metallic yield can be reached in rotary furnaces if the process starts with a proper salt, with limits of addition, and avoiding long holding times. To improve throughput in reverberatories, start the charging with high magnesium content material and inject chlorine gas if the molten metal is at the right temperature. Removal of magnesium through modern technologies can be efficiently performed to prevent environmental problems. PMID:20837560

Velasco, Eulogio; Nino, Jose

2011-07-01

60

Recycling plastic scrap: injection molding. January 1973-August 1988 (Citations from the Rubber and Plastics Research Association data base). Report for January 1973-August 1988  

SciTech Connect

This bibliography contains citations concerning the recycling of scrap plastic produced in the injection-molding process. Plastic pellets made from scrap that are used in the injection-molding process are also discussed. Recycling equipment and automated recycling systems are described. Ways to utilize plastic scrap from used cars, packaging materials, and waste from polyurethane production are presented. (This updated bibliography contains 102 citations, 13 of which are new entries to the previous edition.)

Not Available

1988-08-01

61

Resrad-recycle: a computer model for analyzing radiation exposures resulting from recycling radioactively contaminated scrap metals or reusing radioactively surface-contaminated materials and equipment.  

PubMed

RESRAD-RECYCLE is a computer code designed by Argonne National Laboratory (ANL) to be used in making decisions about the disposition of radioactively contaminated materials and scrap metals. It implements a pathway analysis methodology to evaluate potential radiation exposures resulting from the recycling of contaminated scrap metals and the reuse of surface-contaminated materials and equipment. For modeling purposes, it divides the entire metal recycling process into six steps: (1) scrap delivery, (2) scrap melting, (3) ingot delivery, (4) product fabrication, (5) product distribution, and (6) use of finished product. RESRAD-RECYCLE considers the reuse of surface-contaminated materials in their original forms. It contains representative exposure scenarios for each recycling step and the reuse process; users can also specify scenarios if desired. The model calculates individual and collective population doses for workers involved in the recycling process and for the public using the finished products. The results are then used to derive clearance levels for the contaminated materials on the basis of input dose restrictions. The model accounts for radiological decay and ingrowth, dilution and partitioning during melting, and distribution of refined metal in the various finished products, as well as the varying densities and geometries of the radiation sources during the recycling process. A complete material balance in terms of mass and radioactivity during the recycling process can also be implemented. In an international validation study, the radiation doses calculated by RESRAD-RECYCLE were shown to agree fairly well with actual measurement data. PMID:15551790

Cheng, Jing-Jy; Kassas, Bassel; Yu, Charley; Amish, John; LePoire, Dave; Chen, Shih-Yew; Williams, W A; Wallo, A; Peterson, H

2004-11-01

62

RESRAD-RECYCLE : a computer model for analyzing radiation exposures resulting from recycling radioactively contaminated scrap metals or reusing ratioactively surface-contaminated materials and equipment.  

SciTech Connect

RESRAD-RECYCLE is a computer code designed by Argonne National Laboratory (ANL) to be used in making decisions about the disposition of radioactively contaminated materials and scrap metals. It implements a pathway analysis methodology to evaluate potential radiation exposures resulting from the recycling of contaminated scrap metals and the reuse of surface-contaminated materials and equipment. For modeling purposes, it divides the entire metal recycling process into six steps: (1) scrap delivery, (2) scrap melting, (3) ingot delivery, (4) product fabrication, (5) product distribution, and (6) use of finished product. RESRAD-RECYCLE considers the reuse of surface-contaminated materials in their original forms. It contains representative exposure scenarios for each recycling step and the reuse process; users can also specify scenarios if desired. The model calculates individual and collective population doses for workers involved in the recycling process and for the public using the finished products. The results are then used to derive clearance levels for the contaminated materials on the basis of input dose restrictions. The model accounts for radiological decay and ingrowth, dilution and partitioning during melting, and distribution of refined metal in the various finished products, as well as the varying densities and geometries of the radiation sources during the recycling process. A complete material balance in terms of mass and radioactivity during the recycling process can also be implemented. In an international validation study, the radiation doses calculated by RESRAD-RECYCLE were shown to agree fairly well with actual measurement data.

Cheng, J. J.; Kassas, B.; Yu, C.; Arnish, J. J.; LePoire, D.; Chen, S.-Y.; Williams, W. A.; Wallo, A.; Peterson, H.; Environmental Assessment; DOE; Univ. of Texas

2004-11-01

63

Looking North at Uranium recovery Recycle Tanks in Red Room ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking North at Uranium recovery Recycle Tanks in Red Room in Recycle Recovery Building - Hematite Fuel Fabrication Facility, Recycle Recovery Building, 3300 State Road P, Festus, Jefferson County, MO

64

Securing the metal recycling chain for the steel industry by detecting orphan radioactive sources in scrap metal  

NASA Astrophysics Data System (ADS)

Experimental tests are reported for the detection of the heavy metal shielding of orphan sources hidden inside scrap metal by using a recently developed muon tomography system. Shielded sources do not trigger alarm in radiation portal commonly employed at the entrance of steel industry using scrap metal. Future systems integrating radiation portals with muon tomography inspection gates will substantially reduce the possibility of accidental melting of radioactive sources securing the use of recycled metal.

Pesente, S.; Vanini, S.; Benettoni, M.; Bonomi, G.; Calvini, P.; Checchia, P.; Conti, E.; Gonella, F.; Nebbia, G.; Squarcia, S.; Viesti, G.; Zenoni, A.; Zumerle, G.

2010-08-01

65

Securing the metal recycling chain for the steel industry by detecting orphan radioactive sources in scrap metal  

SciTech Connect

Experimental tests are reported for the detection of the heavy metal shielding of orphan sources hidden inside scrap metal by using a recently developed muon tomography system. Shielded sources do not trigger alarm in radiation portal commonly employed at the entrance of steel industry using scrap metal. Future systems integrating radiation portals with muon tomography inspection gates will substantially reduce the possibility of accidental melting of radioactive sources securing the use of recycled metal.

Pesente, S.; Benettoni, M.; Checchia, P.; Conti, E.; Gonella, F.; Nebbia, G. [INFN Sezione di Padova, via Marzolo 8, 35131 Padova Italy (Italy); Vanini, S.; Viesti, G.; Zumerle, G. [INFN Sezione di Padova, via Marzolo 8, 35131 Padova Italy (Italy); University of Padova and INFN Sezione di Padova, via Marzolo 8, 35131 Padova Italy (Italy); Bonomi, G.; Zenoni, A. [University of Brescia, via Branze 38, 25123 Brescia and INFN Sezione di Pavia, via Bassi 6, 27100 Pavia (Italy); Calvini, P.; Squarcia, S. [University of Genova and INFN Sezione di Genova, via Dodecaneso 33, 16146 Genova (Italy)

2010-08-04

66

Refining technology for the recycling of stainless steel radioactive scrap metals, FY 94 bi-annual report  

Microsoft Academic Search

The research addressed under this project is the recycling of metallic nuclear-related by-product materials under the direction of Westinghouse Idaho Nuclear Company (WINCO). The program addresses the recycling of radioactive scrap metals (RSM) for beneficial re-use within the DOE complex; in particular, this program addresses the recycling of stainless steel RSM. It is anticipated that various stainless steel components under

R. E. Mizia; D. G. Atteridge; J. Buckentin; J. Carter; H. L. Davis; J. H. Devletian; M. R. Scholl; R. B. Turpin; S. L. Webster

1994-01-01

67

Recovery of uranium from (U,Gd)O 2 nuclear fuel scrap using dissolution and precipitation in carbonate media  

Microsoft Academic Search

This work studied a process to recover uranium from contaminated (U,Gd)O2 scraps generated from nuclear fuel fabrication processes by using the dissolution of (U,Gd)O2 scraps in a carbonate with H2O2 and the precipitation of the dissolved uranium as UO4. The dissolution characteristics of uranium, Gd, and impurity metal oxides were tested, and the behaviors of UO4 precipitation and Gd solubility

Kwang-Wook Kim; Jun-Taek Hyun; Eil-Hee Lee; Geun-Il Park; Kune-Woo Lee; Myung-June Yoo; Kee-Chan Song; Jei-Kwon Moon

2011-01-01

68

Scrap metal recovery process  

Microsoft Academic Search

A method is disclosed for recycling aluminum scrap containing thermal barrier material comprising the steps of comminuting the scrap to short pieces of a predetermined length, conveying the comminuted aluminum scrap to a storage hopper, continuously feeding comminuted aluminum scrap product to an indirect-fired rotary kiln, heating the scrap to a predetermined temperature for a sufficient amount of time to

1983-01-01

69

Recycling radioactive scrap metal by producing concrete shielding with steel granules  

SciTech Connect

Siempelkamp foundry at Krefeld, Germany, developed a method for recycling radioactively contaminated steel from nuclear installations. The material is melted and used for producing shielding plates, containers, etc., on a cast-iron basis. Because the percentage of stainless steel has recently increased significantly, problems in the production of high-quality cast iron components have also grown. The metallurgy, the contents of nickel and chromium especially, does not allow for the recycling of stainless steel in a percentage to make this process economical. In Germany, the state of the art is to use shielded concrete containers for the transport of low active waste; this concrete is produced by using hematite as an additive for increasing shielding efficiency. The plan was to produce steel granules from radioactive scrap metal as a substitute for hematite in shielding concrete.

Sappok, M. [Siempelkamp Giesserei GmbH, Krefeld (Germany)

1996-12-31

70

Environmental risk related to specific processes during scrap computer recycling and disposal.  

PubMed

The purpose of this work was to achieve a better understanding of the generation of toxic chemicals related to specific processes in scrap computer recycling and disposal, such as thermal recycling of printed circuit boards (PCBs) and the landfilling or dumping of cathode ray tubes (CRTs). Tube furnace pyrolysis was carried out to simulate different thermal treatment conditions for the identification of the by-products and potential environmental risk from thermal recycling ofPCBs. The Toxicity Characteristic Leaching Procedure (TCLP) and a column test were used to study the leaching characteristics of lead from waste CRT glass, which is one of the most important environmental concerns arising from the disposal of e-waste. The results indicate that more attention should be paid to the benzene series when recycling PCBs under thermal conditions, especially for workers without any personal protection equipment. The impact of immersion on the leaching of lead from CRT leaded glass was more effective than the impact of washing only by acid rain. Thus when waste leaded glass has to be stored for some reason, the storage facility should be dry. PMID:23437653

Li, Jinhui; Shi, Pixing; Shan, Hongshan; Xie, Yijun

2012-12-01

71

Advanced technologies for decontamination and conversion of scrap metals  

Microsoft Academic Search

Recycle of radioactive scrap metals (RSM) from decommissioning of DOE uranium enrichment and nuclear weapons manufacturing facilities is mandatory to recapture the value of these metals and avoid the high cost of disposal by burial. The scrap metals conversion project detailed below focuses on the contaminated nickel associated with the gaseous diffusion plants. Stainless steel can be produced in MSC`s

T. R. Muth; J. Moore; D. Olson; B. Mishra

1994-01-01

72

Fatality Assessment and Control Evaluation (FACE) Report for New Jersey: Crane Failure Kills Worker at Scrap Metal Recycling Yard.  

National Technical Information Service (NTIS)

A crane boom at a scrap metal recycling yard collapsed onto a 41-year-old male worker as a result of a structural failure within the crane, resulting in the worker's death. Three other workers were injured during this incident, which occurred at approxima...

2009-01-01

73

Physical upgrading of scrap from Ni-Cd batteries. A first step toward an integrated metal-recycling process  

Microsoft Academic Search

This paper deals with the initial stages of an integrated, metal-recycling process for Ni-Cd batteries (potable, sealed type), that is with the dismantling of spent cells and the physical processing of their resulting scrap. The experiments herein are focused on the performance of a customised shredder and granulometric analysis as to the ability of optimising the waste stream prior to

L. I. C. Barros; C. Guimaraes; F. Margarido; A. M. G. Pacheco

1999-01-01

74

[Health risk assessment in the metal scrap recycle: the case of Brescia].  

PubMed

The recycle of metal scraps is one of the most important industrial activity of Brescia: almost 40% of the metal scraps produced in Italy are reprocessed in this Province. The melting process currently used produces air emissions containing dioxins, PCB and other pollutants which are dispersed in the atmosphere giving a contribution to the general environment pollution. This contribution has been and is being extensively studied in terms of air concentration and soil deposition but, because of its complexity and the difficulty to gather the necessary data, very little investigation has been made up to now on its impact on the health of workers and population. The difficulties are overcome by RAMET, a research Consortium established and financed by the main 24 metallurgical and siderurgical companies of Brescia, which can take advantage of the availability of the production facilities of its shareholders as pilot plants and has access to their database and experience. Starting from this unique favourable condition and in collaboration with the University of Brescia, RAMET is working on a research project having as main objective the assessment of the POPs dose adsorbed and the relevant consequences on workers and public health. The general scheme and organization of this project are given in this paper together with the outlines and the results of the main activities already completed or in progress. PMID:23213800

Corsaro, G B; Gabusi, V; Pilisi, A

2012-01-01

75

Recycle of contaminated scrap metal, Volume 2. Semi-annual report, September 1993--January 1996  

SciTech Connect

Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; and establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume II contains: Task 1.4, optimization of the vitreous phase for stabilization of radioactive species; Task 1.5, experimental testing of Resource Conservation and Recovery Act (RCRA) wastes; and Task 1.6, conceptual design of a CEP facility.

NONE

1996-07-01

76

Recycle of contaminated scrap metal, Volume 1. Semi-annual report, September 1993--January 1996  

SciTech Connect

Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume I covers: executive summary; task 1.1 design CEP system; Task 1.2 experimental test plan; Task 1.3 experimental testing.

NONE

1996-07-01

77

Contamination of soil and plant by recycling of scrap plastics. [Ipomoea aquatica  

SciTech Connect

The present study concerns a small factory engaged in the recycling of scrap plastics by removing metals from plated surfaces with acid. The rinsing water was discharged into an old fish pond, eventually causing fish-kills in a number of nearby fish ponds and affecting vegetable cultivations in field on the downhill side of the factory through runoff. Ten sites were chosen to sample both the vegetation and soil for metal determination by inductively coupled plasma emission spectrophotometry. Nine sites showed various degrees of contamination and the remaining one was unaffected and used as a control. The most polluted site (F8) contained 385 mg/kg Ni and 194 mg/kgCu (total contents in soil), compared with the control site (F101) which contained 12 and 9 mg/kg of Ni and Cu, respectively. It was also noted that the metal uptake by the water spinach, Ipomoea aquatica, was significantly correlated to the contents of exchangeable metals (extracted by 1M ammonium acetate in the soil). Several grass species thriving in the polluted areas also had high concentrations of Ni and Cu, as well as other metal such as Mn, Al and Pb in their tissues.

Chui, V.W.D.; Chan, G.Y.S.; Cheung, Y.H.; Wong, M.H. (Hong Kong Baptist College, Kowloon)

1988-01-01

78

Recycle of scrap plutonium-238 oxide fuel to support future radioisotope applications  

SciTech Connect

The Nuclear Materials Technology (NMT) Division of Los Alamos National Laboratory has initiated a development program to recover and purify plutonium-238 oxide from impure feed sources in a glove box environment. A glove box line has been designed and a chemistry flowsheet developed to perform this recovery task at large scale. The initial demonstration effort focused on purification of {sup 238}PuO{sub 2} fuel by HNO{sub 3}/HF dissolution, followed by plutonium(III) oxalate precipitation and calcination to an oxide. Decontamination factors for most impurities of concern in the fuel were very good, producing {sup 238}PuO{sub 2} fuel significantly better in purity than specified by General Purpose Heat Source (GPHS) fuel powder specifications. The results are encouraging for recycle of relatively impure plutonium-238 oxide and scrap residue items into fuel for useful applications. A sufficient quantity of purified {sup 238}PuO{sub 2} fuel was recovered from the process to allow fabrication of a GPHS unit for testing. The high specific activity of plutonium-238 magnifies the consequences and concerns of radioactive waste generation. This work places an emphasis on development of waste minimization technologies to complement the aqueous processing operation. Results from experiments allowing more time for neutralized solutions of plutonium-238 to precipitate resulted in decontamination to about 1 millicurie/L. Combining ultrafiltration treatment with addition of a water-soluble polymer designed to coordinate Pu, allowed solutions to be decontaminated to about 1 microcurie/L. Efforts continue to develop a capability for efficient, safe, cost-effective, and environmentally acceptable methods to recover and purify {sup 238}PuO{sub 2} fuel.

Schulte, L.D.; Espinoza, J.M.; Ramsey, K.B.; Rinehart, G.H.; Silver, G.L.; Purdy, G.M.; Jarvinen, G.D.

1997-11-01

79

Benefits of recycling galvanized steel scrap for recovery of high-quality steel and zinc metal  

SciTech Connect

Argonne National Laboratory (ANL) and Metal Recovery Industries, Inc. (MRII), in cost-sharing collaboration, have developed an electrolytic process to separate and recover steel and zinc from galvanized steel scrap. This work has been supported by the US DOE. An assessment of available dezinc technology was begun in 1987 which (1) screened process concepts for separating and recovering zinc and steel from galvanized ferrous scrap, (2) selected electrochemical stripping in hot caustic as the most promising process, (3) evaluated the technical and economic feasibility of the selected process on the basis of fundamental electrochemical studies, (4) experimentally verified the technical and economic feasibility of the process in a phased evaluation from bench-scale controlled experiments through batch tests of actual scrap up to six ton lots, and (5) concluded that the process has technical and economic merit and requires larger- scale evaluation in a continuous mode as the final phase of process development. This work has attracted worldwide interest. Preliminary economic analysis indicates that the cost of the recovered ferrous scrap would be about $150/ton (at a base cost of $110/ton for galvanized scrap), including credit for the co-product zinc. Concentrations of zinc, lead, cadmium and other coating constituents on loose scrap are reduced by a minimum of 98%, with zinc, in particular, reduced to below 0.1%. Removal efficiencies on baled scrap with bulk densities between 60 and 245 pounds per cubic foot range from 80 to 90%. About 1000 tons of galvanized scrap bales have been treated in batch operation at MRII in Hamilton, Ontario. A pilot plant for continuous treatment of 40 ton/day of loose scrap is being built by MRII in East Chicago, Indiana, with operation starting in early 1992. 9 refs.

Dudek, F.J.; Daniels, E.J. (Argonne National Lab., IL (United States)); Morgan, W.A. (Metal Recovery Industries, Inc., Hamilton, ON (Canada))

1991-11-04

80

Recovery of uranium from (U,Gd)O 2 nuclear fuel scrap using dissolution and precipitation in carbonate media  

NASA Astrophysics Data System (ADS)

This work studied a process to recover uranium from contaminated (U,Gd)O 2 scraps generated from nuclear fuel fabrication processes by using the dissolution of (U,Gd)O 2 scraps in a carbonate with H 2O 2 and the precipitation of the dissolved uranium as UO 4. The dissolution characteristics of uranium, Gd, and impurity metal oxides were tested, and the behaviors of UO 4 precipitation and Gd solubility were evaluated with changes of the pH of the solution. A little Gd was entrained in the UO 4 precipitate to contaminate the uranium precipitate. Below a pH of 3, the uranium dissolved in the form of uranyl peroxo-carbonato complex ions in the carbonate solution was precipitated as UO 4 with a high precipitation yield, and the Gd had a very high solubility. Using these characteristics, the Gd-contaminated UO 4 could be purified using dissolution in a 1-M HNO 3 solution with heating and re-precipitation upon addition of H 2O 2 to the solution. Finally, an environmentally friendly and economical process to recover pure uranium from contaminated (U,Gd)O 2 scraps was suggested.

Kim, Kwang-Wook; Hyun, Jun-Taek; Lee, Eil-Hee; Park, Geun-Il; Lee, Kune-Woo; Yoo, Myung-June; Song, Kee-Chan; Moon, Jei-Kwon

2011-11-01

81

UTILIZATION OF SCRAP PREPREG WASTES AS A REINFORCEMENT IN A WHOLLY RECYCLED PLASTIC - PHASE II  

EPA Science Inventory

Foster-Miller is proposing to combine Municipal Solid Waste (MSW) commingled plastics with a high performance reinforcement (scrap prepreg) to form a durable and cost competitive wood substitute with superior moisture, rodent and insect resistance. This proposed technology ...

82

Quality- and dilution losses in the recycling of ferrous materials from end-of-life passenger cars: input-output analysis under explicit consideration of scrap quality.  

PubMed

Metals can in theory be infinitely recycled in a closed-loop without any degradation in quality. In reality, however, open-loop recycling is more typical for metal scrap recovered from end-of-life (EoL) products because mixing of different metal species results in scrap quality that no longer matches the originals. Further losses occur when meeting the quality requirement of the target product requires dilution of the secondary material by adding high purity materials. Standard LCA usually does not address these losses. This paper presents a novel approach to quantifying quality- and dilution losses, by means of hybrid input-output analysis. We focus on the losses associated with the recycling of ferrous materials from end-of-life vehicle (ELV) due to the mixing of copper, a typical contaminant in steel recycling. Given the quality of scrap in terms of copper density, the model determines the ratio by which scrap needs to be diluted in an electric arc furnace (EAF), and the amount of demand for EAF steel including those quantities needed for dilution. Application to a high-resolution Japanese IO table supplemented with data on ferrous materials including different grades of scrap indicates that a nationwide avoidance of these losses could result in a significant reduction of CO(2) emissions. PMID:22876977

Nakamura, Shinichiro; Kondo, Yasushi; Matsubae, Kazuyo; Nakajima, Kenichi; Tasaki, Tomohiro; Nagasaka, Tetsuya

2012-09-01

83

A study on the recycling of scrap integrated circuits by leaching.  

PubMed

In order to minimize the problem of pollution and to conserve limited natural resources, a method to recover the valuable metals such as gold, silver and copper) present in the scrap integrated circuits (ICs) was developed in the present study. Roasting, grinding, screening, magnetic separation, melting and leaching were adopted to investigate the efficiency of recovery of gold, silver and copper from scrap ICs. The collected scrap IC samples were roasted at 850 °C to destroy their plastic resin sealing material, followed by screening and magnetic separation to separate the metals from the resin residue. The non-ferrous materials (0.840 mm) were mainly composed of copper and could be melted into a copper alloy. Non-ferrous materials containing gold (860.05 ppm), silver (1323.12 ppm) and copper (37259.7 ppm) (size less than 50 mesh) were recovered 100% by a leaching process and thiourea was used as a leaching reagent. PMID:20837559

Lee, Ching-Hwa; Tang, Li-Wen; Popuri, Srinivasa R

2011-07-01

84

Usage of Organic Wastes in the Electric Arc Furnace for Iron Scrap Recycling  

Microsoft Academic Search

Organic wastes are used in several metallurgical processes as a substitute for fuel and as a feedstock for carbon. The use automotive shredder residue on behalf of organic wastes as a substitute for electric energy in the refining of steel scrap in an electric arc furnace is discussed. A feasibility study is presented, investigating the various possibilities to utilize organic

Johannes Karl Fink

85

Fernald's dilemma: Recycle the radioactively contaminated scrap metal, or bury it?  

Microsoft Academic Search

During the past 5 years, a number of US Department of Energy (DOE) funded efforts have demonstrated the technical efficacy of converting various forms of radioactive scrap metal (RSM) into useable products. From the development of accelerator shielding blocks, to the construction of low level waste containers, technology has been applied to this fabrication process in a safe and stakeholder

Katherine L. Yuracko; Stanton W. Hadley; Robert D. Perlack; Rafael G. Rivera; T. Randall Curlee

1997-01-01

86

Optimization of a microbial fuel cell for wastewater treatment using recycled scrap metals as a cost-effective cathode material.  

PubMed

Microbial fuel cell (MFC) for wastewater treatment is still hindered by the prohibitive cost of cathode material, especially when platinum is used to catalyze oxygen reduction. In this study, recycled scrap metals could be used efficiently as cathode material in a specially-designed MFC. In terms of raw power, the scrap metals ranked as follows: W/Co > Cu/Ni > Inconel 718 > carpenter alloy; however, in terms of cost and long term stability, Inconel 718 was the preferred choice. Treatment performance--assessed on real and synthetic wastewater--was considerably improved either by filling the anode compartment with carbon granules or by operating the MFC in full-loop mode. The latter option allowed reaching 99.7% acetate removal while generating a maximum power of 36 W m(-3) at an acetate concentration of 2535 mg L(-1). Under these conditions, the energy produced by the system averaged 0.1 kWh m(-3) of wastewater treated. PMID:23138054

Lefebvre, Olivier; Tan, Zi; Shen, Yujia; Ng, How Y

2013-01-01

87

A preliminary investigation of unintentional POP emissions from thermal wire reclamation at industrial scrap metal recycling parks in China.  

PubMed

Thermal wire reclamation is considered to be a potential source of unintentional persistent organic pollutants (unintentional POPs). In this study, unintentional POP concentrations, including PCDD/Fs, dioxin like PCBs (dl-PCBs), polychlorinated naphthalenes (PCNs), hexachlorobenzene (HxCBz) and pentachlorobenzene (PeCBz), were quantified in flue gas and residual ash emissions from thermal wire reclamation at scrap metal dismantling parks in Zhejiang Province, China. The total average TEQ emissions of the investigated unintentional POPs from flue gas and residual ash in two typical scrap metal recycling plants ranged from 13.1 to 48.3ngTEQNm(-3) and 0.08 to 2.8ngTEQg(-1), respectively. The dominant PCDD/F congeners were OCDD, 1,2,3,4,6,7,8-HpCDD, OCDF and 1,2,3,4,6,7,8-HpCDF, while PCB-126 and PCB-169 were the main contributors to the toxicity of the dl-PCBs. There were clear differences in the distribution dl-PCBs congeners contributing to the TEQ concentrations in the flue gas samples from the two plants. The PCN TEQs were dominated by PCN-66/67 and PCN-73. Although thermal wire reclamation in incinerators has been proposed as an alternative to open burning, there are still considerable environmental risks associated with regulated incinerators, and unintentional POP emissions from thermal wire reclamation sites need to be controlled by local government agencies. PMID:22436338

Nie, Zhiqiang; Zheng, Minghui; Liu, Guorui; Liu, Wenbin; Lv, Pu; Zhang, Bing; Su, Guijin; Gao, Lirong; Xiao, Ke

2012-05-15

88

A life cycle decision methodology for recycle of radioactive scrap metal  

Microsoft Academic Search

During the past five years, a number of U.S. Department of Energy (DOE) funded efforts have demonstrated the technical efficacy\\u000a of converting various forms of radioactive scrap metal (RSM) into useable products. While health and safety and other technical\\u000a issues have been addressed, the question remains: do the benefits of fabricating products from RSM outweigh the costs? This\\u000a paper presents

Katherine L. Yuracko; Stanton W. Hadley; Robert D. Perlack; Rafael G. Rivera; T. Randall Curlee

1997-01-01

89

Structural insulated panels produced from recycled expanded-polystyrene (EPS) foam scrap. Final report  

SciTech Connect

This report documents a research project undertaken to assess the feasibility of using scrap reground expanded polystyrene (EPS) in the manufacture of structural insulated panels (SIPs) in order to save material costs and reduct the amount of EPS waste products to be disposed. The report documents the manufacturing and testing process and concludes that there was relatively little difference in the thermal and structural characteristics under normal loading conditions of the panels tested with varying amount of regrind (from 10% - 25%) and those made with 100% virgin beads. The report recommends that additional test be undertaken, but suggests that, based on the test results, reground EPS can be successfully used in the cores of SIPs in amounts up to 25%.

Grinnell, A.

1996-11-01

90

Recycling radioactive scrap metal by producing concrete shielding with steel granules  

Microsoft Academic Search

Siempelkamp foundry at Krefeld, Germany, developed a method for recycling radioactively contaminated steel from nuclear installations. The material is melted and used for producing shielding plates, containers, etc., on a cast-iron basis. Because the percentage of stainless steel has recently increased significantly, problems in the production of high-quality cast iron components have also grown. The metallurgy, the contents of nickel

Sappok

1996-01-01

91

Structural insulated panels produced from recycled Expanded-Polystrene (EPS) foam scrap. Final report  

SciTech Connect

This report documents a research project undertaken to assess the feasibility of using scrap reground expanded polystyrene (EPS) in the manufacture of structural insulated panels (SIPs) in order to save material costs and reduce the amount of EPS waste products to be disposed. The project team, managed by Steven Winter Associates, Inc., a Norwalk, Connecticut-based building systems research and consulting firm included: Thermal Foams, Inc., a Buffalo-based manufacturer of EPS products; BASF Corp., the world`s largest producer of EPS beads; Oak Ridge National Laboratory, which performed thermal tests (ASTM C-518); RADCO, Inc. which performed material properties tests: density (ASTM C-303), flexural strength (ASTM C-203), tensile strength (ASTM D-1623), and transverse load test of SIPs panels (ASTM E-72). The report documents the manufacturing and testing process and concludes that there was relatively little difference in the thermal and structural characteristics under normal loading conditions of the panels tested with varying amount of regrind (from 10% - 25%) and those made with 100% virgin beads. The report recommends that additional tests be undertaken, but suggests that, based on the test results, reground EPS can be successfully used in the cores of SIPs in amounts up to 25%.

Grinnell, A.

1996-11-01

92

Scrap tires  

SciTech Connect

Scrap tires, one small part of the country's massive solid waste problem, are causing a disproportional headache. A city the size of Newark, N.J., for example, can pay up to $700,000 a year just to bury its waste tires, assuming it can find landfills to accept them. Many landfills no longer do, and in some areas, it is actually illegal. So stockpiles of scrap tires mount up and illegal dumping runs rampant. Scrap tires represent less than 1 percent of the nation's total solid waste. While we generate approximately a ton of solid waste per year per person, or 250,000,000 tons, we generate only one 20-pound tire per person, or 2,500,000 tons. Despite this small percentage, these tires present a special disposal/reuse challenge because of their size, shape, and physicochemical nature. Classified as a special waste, they are not generally collected with household waste by municipal authorities. Notwithstanding the unique disposal/reuse challenges of scrap tires, it must be stressed that a tire is essentially a petrochemical product than can be reused, can be a source of recoverable petrochemicals, or can be used as a fuel with a higher Btu value than coal. Thus what appears as a waste disposal challenge is also a resource recovery opportunity. Unfortunately, at present, only 30 percent of the country's scrap tires are being reclaimed or recycled. In terms of options, there are three viable areas in which to approach the waste tire problem: whole tire applications; physically processed tire applications; and physicochemical processes.

Not Available

1988-12-01

93

Utilization of magnetic and electrostatic separation in the recycling of printed circuit boards scrap.  

PubMed

The progress of the technology is directly related to the growth of production and consumption of electrical/electronics equipment, especially of personal computers. This type of equipment has a relatively short average lifetime, 2-3 years. The amount of defective or obsolete equipment has been increasing substantially; consequently its disposition and/or recycling should be studied. In this work, printed circuit boards, which are used in personal computers, were studied in order to recover the metals in the circuit boards through mechanical processing, such as crushing, screening, as well as magnetic and electrostatic separation. The results obtained demonstrate the feasibility of using these processes to separate metal fractions from polymers and ceramics, and that it is possible to obtain a fraction concentrated in metals containing more than 50% on average of copper, 24% of tin and 8% of lead. PMID:15681180

Veit, H M; Diehl, T R; Salami, A P; Rodrigues, J S; Bernardes, A M; Tenório, J A S

2005-01-01

94

Securing the metal recycling chain for the steel industry by detecting orphan radioactive sources in scrap metal  

Microsoft Academic Search

Experimental tests are reported for the detection of the heavy metal shielding of orphan sources hidden inside scrap metal by using a recently developed muon tomography system. Shielded sources do not trigger alarm in radiation portal commonly employed at the entrance of steel industry using scrap metal. Future systems integrating radiation portals with muon tomography inspection gates will substantially reduce

S. Pesente; S. Vanini; M. Benettoni; G. Bonomi; P. Calvini; P. Checchia; E. Conti; F. Gonella; G. Nebbia; S. Squarcia; G. Viesti; A. Zenoni; G. Zumerle

2010-01-01

95

SCRAP TIRE RECYCLING: CONVINCING BUSINESSES TO INTEGRATE INEXPENSIVE, CUTTING-EDGE TECHNOLOGY TO CONVERT TIRES INTO VARIOUS CONSTRUCTION MATERIALS  

EPA Science Inventory

Scrap tires cause serious environmental pollution and health problems. Although worldwide figures are imprecise, it is known that one-fourth of the 283 million tires scrapped in the United States were landfilled last year. Hundreds of millions more tires ar...

96

Idaho National Engineering and Environmental Laboratory Site Report on the Production and Use of Recycled Uranium  

Microsoft Academic Search

Recent allegations regarding radiation exposure to radionuclides present in recycled uranium sent to the gaseous diffusion plants prompted the Department of Energy to undertake a system-wide study of recycled uranium. Of particular interest, were the flowpaths from site to site operations and facilities in which exposure to plutonium, neptunium and technetium could occur, and to the workers that could receive

L. C. Lewis; D. C. Barg; C. L. Bendixsen; J. P. Henscheid; D. R. Wenzel; B. L. Denning

2000-01-01

97

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

Microsoft Academic Search

A method is described for treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material

T. W. Ellis; F. A. Schmidt

1995-01-01

98

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

Microsoft Academic Search

Method of treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant

Timothy W. Ellis; Frederick A. Schmidt

1995-01-01

99

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

DOEpatents

A method is described for treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation. 2 figs.

Ellis, T.W.; Schmidt, F.A.

1995-08-01

100

Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction  

DOEpatents

Method of treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation.

Ellis, Timothy W. (Ames, IA); Schmidt, Frederick A. (Ames, IA)

1995-08-01

101

FEASIBILITY STUDY OF DUPOLY TO RECYCLE DEPLETED URANIUM.  

SciTech Connect

DUPoly, depleted uranium (DU) powder microencapsulated in a low-density polyethylene binder, has been demonstrated as an innovative and efficient recycle product, a very durable high density material with significant commercial appeal. DUPoly was successfully prepared using uranium tetrafluoride (UF{sub 4}) ''green salt'' obtained from Fluor Daniel-Fernald, a U.S. Department of Energy reprocessing facility near Cincinnati, Ohio. Samples containing up to 90 wt% UF{sub 4} were produced using a single screw plastics extruder, with sample densities of up to 3.97 {+-} 0.08 g/cm{sup 3} measured. Compressive strength of as-prepared samples (50-90 wt% UF4 ) ranged from 1682 {+-} 116 psi (11.6 {+-} 0.8 MPa) to 3145 {+-} 57 psi (21.7 {+-} 0.4 MPa). Water immersion testing for a period of 90 days produced no visible degradation of the samples. Leach rates were low, ranging from 0.02 % (2.74 x 10{sup {minus}6} gm/gm/d) for 50 wt% UF{sub 4} samples to 0.72 % (7.98 x 10{sup {minus}5} gm/gm/d) for 90 wt% samples. Sample strength was not compromised by water immersion. DUPoly samples containing uranium trioxide (UO{sub 3}), a DU reprocessing byproduct material stockpiled at the Savannah River Site, were gamma irradiated to 1 x 10{sup 9} rad with no visible deterioration. Compressive strength increased significantly, however: up to 200% for samples with 90 wt% UO{sub 3}. Correspondingly, percent deformation (strain) at failure was decreased for all samples. Gamma attenuation data on UO{sub 3} DUPoly samples yielded mass attenuation coefficients greater than those for lead. Neutron removal coefficients were calculated and shown to correlate well with wt% of DU. Unlike gamma attenuation, both hydrogenous and nonhydrogenous materials interact to attenuate neutrons.

ADAMS,J.W.; LAGERAAEN,P.R.; KALB,P.D.; RUTENKROGER,S.P.

1998-02-01

102

Evolution of isotopic composition of reprocessed uranium during the multiple recycling in light water reactors with natural uranium feed  

SciTech Connect

A complex approach based on the consistent modeling of neutron-physics processes and processes of cascade separation of isotopes is applied for analyzing physical problems of the multiple usage of reprocessed uranium in the fuel cycle of light water reactors. A number of scenarios of multiple recycling of reprocessed uranium in light water reactors are considered. In the process, an excess absorption of neutrons by the {sup 236}U isotope is compensated by re-enrichment in the {sup 235}U isotope. Specific consumptions of natural uranium for re-enrichment of the reprocessed uranium depending on the content of the {sup 232}U isotope are obtained.

Smirnov, A. Yu., E-mail: a.y.smirnoff@rambler.ru; Sulaberidze, G. A. [National Research Nuclear University MEPhI (Russian Federation); Alekseev, P. N.; Dudnikov, A. A.; Nevinitsa, V. A., E-mail: neva@dhtp.kiae.ru; Proselkov, V. N.; Chibinyaev, A. V. [Russian Research Centre Kurchatov Institute (Russian Federation)

2012-12-15

103

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2010 CFR

...not apply to the routine recycling of baghouse bags or other...Restricted metallic scrap . For the production...presence of mercury in scrap from end-of-life vehicles...Option for specialty metal scrap. You must certify...

2012-07-01

104

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2010 CFR

...not apply to the routine recycling of baghouse bags or other...Restricted metallic scrap . For the production...presence of mercury in scrap from end-of-life vehicles...Option for specialty metal scrap. You must certify...

2009-07-01

105

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2010 CFR

...not apply to the routine recycling of baghouse bags or other...Restricted metallic scrap . For the production...presence of mercury in scrap from end-of-life vehicles...Option for specialty metal scrap. You must certify...

2010-07-01

106

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2010 CFR

...not apply to the routine recycling of baghouse bags or other...Restricted metallic scrap . For the production...presence of mercury in scrap from end-of-life vehicles...Option for specialty metal scrap. You must certify...

2011-07-01

107

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2010 CFR

...not apply to the routine recycling of baghouse bags or other...Restricted metallic scrap . For the production...presence of mercury in scrap from end-of-life vehicles...Option for specialty metal scrap. You must certify...

2008-07-01

108

Idaho National Engineering and Environmental Laboratory Site Report on the Production and Use of Recycled Uranium  

SciTech Connect

Recent allegations regarding radiation exposure to radionuclides present in recycled uranium sent to the gaseous diffusion plants prompted the Department of Energy to undertake a system-wide study of recycled uranium. Of particular interest, were the flowpaths from site to site operations and facilities in which exposure to plutonium, neptunium and technetium could occur, and to the workers that could receive a significant radiation dose from handling recycled uranium. The Idaho National Engineering and Environmental Laboratory site report is primarily concerned with two locations. Recycled uranium was produced at the Idaho Chemical Processing Plant where highly enriched uranium was recovered from spent fuel. The other facility is the Specific Manufacturing Facility (SMC) where recycled, depleted uranium is manufactured into shapes for use by their customer. The SMC is a manufacturing facility that uses depleted uranium metal as a raw material that is then rolled and cut into shapes. There are no chemical processes that might concentrate any of the radioactive contaminant species. Recyclable depleted uranium from the SMC facility is sent to a private metallurgical facility for recasting. Analyses on the recast billets indicate that there is no change in the concentrations of transuranics as a result of the recasting process. The Idaho Chemical Processing Plant was built to recover high-enriched uranium from spent nuclear fuel from test reactors. The facility processed diverse types of fuel which required uniquely different fuel dissolution processes. The dissolved fuel was passed through three cycles of solvent extraction which resulted in a concentrated uranyl nitrate product. For the first half of the operating period, the uranium was shipped as the concentrated solution. For the second half of the operating period the uranium solution was thermally converted to granular, uranium trioxide solids. The dose reconstruction project has evaluated work exposure and exposure to the public as the result of normal operations and accidents that occurred at the INEEL. As a result of these studies, the maximum effective dose equivalent from site activities did not exceed seventeen percent of the natural background in Eastern Idaho. There was no year in which the radiation dose to the public exceeded the applicable limits for that year. Worker exposure to recycled uranium was minimized by engineering features that reduced the possibility of direct exposure.

L. C. Lewis; D. C. Barg; C. L. Bendixsen; J. P. Henscheid; D. R. Wenzel; B. L. Denning

2000-09-01

109

Recovery and recycling of post-consumer waste materials. Part 2. Target wastes (glass beverage bottles, plastics, scrap metal and steel cans, end-of-life tyres, batteries and household hazardous waste)  

Microsoft Academic Search

The first part of the review paper dealt with general information and covered the specific sectors of paper\\/cardboard and aluminium cans. The present Part 2 should be read in conjunction with Part 1 and assesses the recovery and recycling of additional post-consumer waste sectors, i.e. glass beverage bottles, plastics, scrap metal and steel cans, end-of-life tyres, batteries and household hazardous

Jan Baeyens; Anke Brems; Raf Dewil

2010-01-01

110

EFFECT ON REAGENT CONSUMPTION OF RECYCLING SOLUTIONS IN THE WEAK ACID LEACHING OF A URANIUM ORE  

Microsoft Academic Search

An investgation was carried out to study the possibility of redacing the ; acid requirements in the leaching of uranium ores at controlled pH, by recycling ; a portion of the leach liquor as make-up solution with fresh ore. The work was ; carried out on a laboratory scale on a siliceous ore. Ore fineness, and quantity ; of oxidizing

V. M. McNamara; W. A. Gow

1958-01-01

111

Scrap tire utilization via surface modification  

SciTech Connect

Air Products and Chemicals, Inc. is developing a novel approach to reusing scrap tire rubber, which will be described in this presentation. In addition to consuming scrap tires, this technology represents a new approach to material engineering. Furthermore, this method of rubber recycle is most efficient in terms of energy recovery. 4 figs.

Bauman, B.D. (Air Products and Chemicals, Inc., Allentown, PA (USA))

1990-01-01

112

Utilization of Scrap Thermosets Using Pyrolysis  

Microsoft Academic Search

Plastics are widely used materials, and their application increases considerably every year. Therefore, appropriate waste management policy should be used in relation to utilization\\/recycling of scrap plastic components. Currently, there are no clear utilization options for such scrap thermosetting materials, and landfill is the most commonly used method of their removal. However, it should be underlined that, in various products,

R. Sekula; S. Leszczynski

2008-01-01

113

Recycling  

NSDL National Science Digital Library

You will be learning all about recycling and asking questions as you learn more about recycling. Afterward, you will be making recycling bins that we will use in our classroom. Click on each of the different links and research about recycling. Find out what recycling is, what can be recycled, and why we should recycle. As you find information, add it to the "describing wheel" that is given to you by Ms. Pollak. Answer the main question: What is recycling? Come ...

sgp0002

2010-03-27

114

[Recycle of contaminated scrap metal]: Task 1.3.2, Bulk solids feed system. Topical report, October 1993-- January 1996  

SciTech Connect

A critical requirement in DOE`s efforts to recycle, reuse, and dispose of materials from its decontamination and decommissioning activities is the design of a robust system to process a wide variety of bulk solid feeds. The capability to process bulk solids will increase the range of materials and broaden the application of Catalytic Extraction Processing (CEP). The term bulk solids refers to materials that are more economically fed into the top of a molten metal bath than by submerged injection through a tuyere. Molten Metal Technology, Inc. (MMT) has characterized CEP`s ability to process bulk solid feed materials and has achieved significant growth in the size of bulk solid particles compatible with Catalytic Extraction Processing. Parametric experimental studies using various feed materials representative of the components of various DOE waste streams have validated design models which establish the reactor operating range as a function of feed material, mass flow rate, and particle size. MMT is investigating the use of a slurry system for bulk solid addition as it is the most efficient means for injecting soils, sludges, and similar physical forms into a catalytic processing unit. MMT is continuing to evaluate condensed phase product removal systems and alternative energy addition sources to enhance the operating efficiency of bulk solids CEP units. A condensed phase product removal system capable of on-demand product removal has been successfully demonstrated. MMT is also investigating the use of a plasma arc torch to provide supplemental heating during bulk solids processing. This comprehensive approach to bulk solids processing is expected to further improve overall process efficiency prior to the deployment of CEP for the recycle, reuse, and disposal of materials from DOE decontamination and decommissioning Activities.

NONE

1996-07-01

115

Sensitivity of scrap metal prices to global economic conditions  

Microsoft Academic Search

The scrap metal industry is part of the broader recycling industry that involves the collection,separation and processing of materials for manufacture into raw materials or new products. The demand for scrap metal is a derived demand – based on the demand for steel because scrap metal is an input to steel production. Steel demand in turn is based on demand

Phillip Chindamo

2011-01-01

116

Feasibility study of a portable smelter for scrap metals  

Microsoft Academic Search

The use of a portable smelter to process uranium-contaminated scrap metals was studied. Objectives were to convert scrap metal located at many diverse sites into a form which would be suitable for unlicensed sale and reduce the problems associated with storing the scrap. The Foundry Design Company study indicated the portable smelter concept was feasible from an equipment and transportation

Cavendish

1976-01-01

117

Recycling.  

ERIC Educational Resources Information Center

Discusses the range of benefits resulting from recycling efforts and projects. Presents information and data related to the recycling of metals, cans, paper, fans, and plastics. Suggestions for motivating and involving youth in recycling programs are also offered. (ML)

Sinker, Barbara

1986-01-01

118

Recycling Of Uranium- And Plutonium-Contaminated Metals From Decommissioning Of The Hanau Fuel Fabrication Plant  

SciTech Connect

Decommissioning of a nuclear facility comprises not only actual dismantling but also, above all, management of the resulting residual materials and waste. Siemens Decommissioning Projects (DP) in Hanau has been involved in this task since 1995 when the decision was taken to decommission and dismantle the Hanau Fuel Fabrication Plant. Due to the decommissioning, large amounts of contaminated steel scrap have to be managed. The contamination of this metal scrap can be found almost exclusively in the form of surface contamination. Various decontamination technologies are involved, as there are blasting and wiping. Often these methods are not sufficient to meet the free release limits. In these cases, SIEMENS has decided to melt the scrap at Siempelkamp's melting plant. The plant is licensed according to the German Radiation Protection Ordinance Section 7 (issue of 20.07.2001). The furnace is a medium frequency induction type with a load capacity of 3.2 t and a throughput of 2 t/h for steel melting. For safety reasons, the furnace is widely operated by remote handling. A highly efficient filter system of cyclone, bag filter and HEPA-filter in two lines retains the dust and aerosol activity from the off-gas system. The slag is solidified at the surface of the melt and gripped before pouring the liquid iron into a chill. Since 1989, in total 15,000 t have been molten in the plant, 2,000 t of them having been contaminated steel scrap from the decommissioning of fuel fabrication plants. Decontamination factors could be achieved between 80 and 100 by the high affinity of the uranium to the slag former. The activity is transferred to the slag up to nearly 100 %. Samples taken from metal, slag and dust are analyzed by gamma measurements of the 186 keV line of U235 and the 1001 keV line of Pa234m for U238. All produced ingots showed a remaining activity less than 1 Bq/g and could be released for industrial reuse.

Kluth, T.; Quade, U.; Lederbrink, F. W.

2003-02-26

119

Recycling  

NSDL National Science Digital Library

What objects can be recycled? 1. Click on link. Watch video. Recycle Guy Video 2. Click on link. Watch video. Talking Trash Video 3. Click on link. Watch video. Recycling At School Video 4. Click on link. Play game. Star Fall Recycling Game 5. Click on link. Play game. National Geographic Recycling Game 6. Click on link. Ask Ms. Owens how to do it. Things We Recycle Chart 7. Please see Miss Owens for instructions on the following ...

2011-04-07

120

The credit analysis of recycling beryllium and uranium in BeO-UO2 nuclear fuel  

Microsoft Academic Search

This study quantifies the credits of beryllium and uranium which are used as the raw materials for BeO-UO2 nuclear fuel by analyzing the influence of their credits on the nuclear fuel cycle cost was analyzed, where the credit was defined as the value of raw materials recovered from spent fuel and the raw materials that were re-cycled. The credits of

Sungki Kim; Wonil Ko; W. Zhou; Shripad T. Revankar; Yanghon Chung; Sungsig Bang

2012-01-01

121

Characterization of Microwave-Devulcanized Composites of Ground SBR Scraps  

Microsoft Academic Search

The recycling of waste rubber has considerable significance in terms of environmental protection and energy conservation. Considering that most of the relevant literature is concerned with tire recycling, the objective of this study is to develop and characterize styrene-butadiene rubber composites containing only industrial rubber scraps devulcanized by microwave. The styrene-butadiene rubber extruded profile scraps were collected and ground under

Aline Zanchet; Larissa N. Carli; Marcelo Giovanela; Janaina S. Crespo; Carlos H. Scuracchio; Regina C. R. Nunes

2009-01-01

122

Railroading Scrap  

ERIC Educational Resources Information Center

This article focuses on the environmental benefits of recycling mainly iron and steel, as well as the current status of such recycling processes. It also examines some of the economic constraints working against recycling, and offers suggestions for correcting the problem. (Author/MA)

Kakela, Peter

1975-01-01

123

Recycle  

SciTech Connect

;Contents: The Problem; What`s In Our Trash; Where Does Trash Go; Where Does Our Trash Go; The Solution; What Is Recycling; Why Should We Recycle; A National Goal of 25%; What Can We Recycle; What Do We Do With Our Recyclables.

NONE

1988-10-01

124

Contaminated nickel scrap processing  

SciTech Connect

The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.

1994-12-01

125

PWR core design, neutronics evaluation and fuel cycle analysis for thorium-uranium breeding recycle  

SciTech Connect

This paper was focused on core design, neutronics evaluation and fuel cycle analysis for Thorium-Uranium Breeding Recycle in current PWRs, without any major change to the fuel lattice and the core internals, but substituting the UOX pellet with Thorium-based pellet. The fuel cycle analysis indicates that Thorium-Uranium Breeding Recycle is technically feasible in current PWRs. A 4-loop, 193-assembly PWR core utilizing 17 x 17 fuel assemblies (FAs) was taken as the model core. Two mixed cores were investigated respectively loaded with mixed reactor grade Plutonium-Thorium (PuThOX) FAs and mixed reactor grade {sup 233}U-Thorium (U{sub 3}ThOX) FAs on the basis of reference full Uranium oxide (UOX) equilibrium-cycle core. The UOX/PuThOX mixed core consists of 121 UOX FAs and 72 PuThOX FAs. The reactor grade {sup 233}U extracted from burnt PuThOX fuel was used to fabrication of U{sub 3}ThOX for starting Thorium-. Uranium breeding recycle. In UOX/U{sub 3}ThOX mixed core, the well designed U{sub 3}ThOX FAs with 1.94 w/o fissile uranium (mainly {sup 233}U) were located on the periphery of core as a blanket region. U{sub 3}ThOX FAs remained in-core for 6 cycles with the discharged burnup achieving 28 GWD/tHM. Compared with initially loading, the fissile material inventory in U{sub 3}ThOX fuel has increased by 7% via 1-year cooling after discharge. 157 UOX fuel assemblies were located in the inner of UOX/U{sub 3}ThOX mixed core refueling with 64 FAs at each cycle. The designed UOX/PuThOX and UOX/U{sub 3}ThOX mixed core satisfied related nuclear design criteria. The full core performance analyses have shown that mixed core with PuThOX loading has similar impacts as MOX on several neutronic characteristic parameters, such as reduced differential boron worth, higher critical boron concentration, more negative moderator temperature coefficient, reduced control rod worth, reduced shutdown margin, etc.; while mixed core with U{sub 3}ThOX loading on the periphery of core has no visible impacts on neutronic characteristics compared with reference full UOX core. The fuel cycle analysis has shown that {sup 233}U mono-recycling with U{sub 3}ThOX fuel could save 13% of natural uranium resource compared with UOX once through fuel cycle, slightly more than that of Plutonium single-recycling with MOX fuel. If {sup 233}U multi-recycling with U{sub 3}ThOX fuel is implemented, more natural uranium resource would be saved. (authors)

Bi, G.; Liu, C.; Si, S. [Shanghai Nuclear Engineering Research and Design Inst., No. 29, Hongcao Road, Shanghai, 200233 (China)

2012-07-01

126

Homologation and functionalization of carbon monoxide by a recyclable uranium complex  

PubMed Central

Carbon monoxide (CO) is in principle an excellent resource from which to produce industrial hydrocarbon feedstocks as alternatives to crude oil; however, CO has proven remarkably resistant to selective homologation, and the few complexes that can effect this transformation cannot be recycled because liberation of the homologated product destroys the complexes or they are substitutionally inert. Here, we show that under mild conditions a simple triamidoamine uranium(III) complex can reductively homologate CO and be recycled for reuse. Following treatment with organosilyl halides, bis(organosiloxy)acetylenes, which readily convert to furanones, are produced, and this was confirmed by the use of isotopically 13C-labeled CO. The precursor to the triamido uranium(III) complex is formed concomitantly. These findings establish that, under appropriate conditions, uranium(III) can mediate a complete synthetic cycle for the homologation of CO to higher derivatives. This work may prove useful in spurring wider efforts in CO homologation, and the simplicity of this system suggests that catalytic CO functionalization may soon be within reach.

Gardner, Benedict M.; Stewart, John C.; Davis, Adrienne L.; McMaster, Jonathan; Lewis, William; Blake, Alexander J.; Liddle, Stephen T.

2012-01-01

127

Homologation and functionalization of carbon monoxide by a recyclable uranium complex.  

PubMed

Carbon monoxide (CO) is in principle an excellent resource from which to produce industrial hydrocarbon feedstocks as alternatives to crude oil; however, CO has proven remarkably resistant to selective homologation, and the few complexes that can effect this transformation cannot be recycled because liberation of the homologated product destroys the complexes or they are substitutionally inert. Here, we show that under mild conditions a simple triamidoamine uranium(III) complex can reductively homologate CO and be recycled for reuse. Following treatment with organosilyl halides, bis(organosiloxy)acetylenes, which readily convert to furanones, are produced, and this was confirmed by the use of isotopically (13)C-labeled CO. The precursor to the triamido uranium(III) complex is formed concomitantly. These findings establish that, under appropriate conditions, uranium(III) can mediate a complete synthetic cycle for the homologation of CO to higher derivatives. This work may prove useful in spurring wider efforts in CO homologation, and the simplicity of this system suggests that catalytic CO functionalization may soon be within reach. PMID:22652572

Gardner, Benedict M; Stewart, John C; Davis, Adrienne L; McMaster, Jonathan; Lewis, William; Blake, Alexander J; Liddle, Stephen T

2012-06-12

128

WINCO Metal Recycle annual report, FY 1993  

Microsoft Academic Search

This report is a summary of the first year progress of the WINCO Metal Recycle Program. Efforts were directed towards assessment of radioactive scrap metal inventories, economics and concepts for recycling, technology development, and transfer of technology to the private sector. Seven DOE laboratories worked together to develop a means for characterizing scrap metal. Radioactive scrap metal generation rates were

Bechtold

1993-01-01

129

Membrane Purification Cell for Aluminum Recycling  

Microsoft Academic Search

Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent.

David DeYoung; James Wiswall; Cong Wang

2011-01-01

130

Catalytic extraction processing of contaminated scrap metal  

Microsoft Academic Search

The contract was conceived to establish the commercial capability of Catalytic Extraction Processing (CEP) to treat contaminated scrap metal in the DOE inventory. In so doing, Molten Metal Technology, Inc. (MMT), pursued the following objectives: demonstration of the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal can be converted to high-grade, ferrous and non-ferrous alloys which

T. P. Griffin; J. E. Johnston

1994-01-01

131

Recycling polyurethanes  

SciTech Connect

This article reports on the PolyUrethane Recycle and Recovery Council`s continuing evaluation of the technical and commercial viability of polyurethane recovery and recycling technologies. In North America, 240,000 tonnes of post-industrial and 16,000 tonnes of post-consumer polyurethane foam was recycled into carpet rebound underlay and other applications in 1993. Demand was so great in North America that 60,000 t of primarily post-industrial scarp was imported from Europe and the Far East. Polyurethane from the seats of the 9 million vehicles scrapped each year could yield 82,000 t of flexible post-consumer foam scrap: instrument and door panels could yield another 10,000 t of semi-flexible scrap.

NONE

1995-08-01

132

Comparative analysis of thorium and uranium fuel for transuranic recycle in a sodium cooled Fast Reactor  

SciTech Connect

The present paper compares the reactor physics and transmutation performance of sodium-cooled Fast Reactors (FRs) for TRansUranic (TRU) burning with thorium (Th) or uranium (U) as fertile materials. The 1000 MWt Toshiba-Westinghouse Advanced Recycling Reactor (ARR) conceptual core has been used as benchmark for the comparison. Both burner and breakeven configurations sustained or started with a TRU supply, and assuming full actinide homogeneous recycle strategy, have been developed. State-of-the-art core physics tools have been employed to establish fuel inventory and reactor physics performances for equilibrium and transition cycles. Results show that Th fosters large improvements in the reactivity coefficients associated with coolant expansion and voiding, which enhances safety margins and, for a burner design, can be traded for maximizing the TRU burning rate. A trade-off of Th compared to U is the significantly larger fuel inventory required to achieve a breakeven design, which entails additional blankets at the detriment of core compactness as well as fuel manufacturing and separation requirements. The gamma field generated by the progeny of U-232 in the U bred from Th challenges fuel handling and manufacturing, but in case of full recycle, the high contents of Am and Cm in the transmutation fuel impose remote fuel operations regardless of the presence of U-232.

C. Fiorina; N. E. Stauff; F. Franceschini; M. T. Wenner; A. Stanculescu; T. K. Kim; A. Cammi; M. E. Ricotti; R. N. Hill; T. A. Taiwo; M. Salvatores

2013-12-01

133

Characterization of shredded television scrap and implications for materials recovery.  

PubMed

Characterization of TV scrap was carried out by using a variety of methods, such as chemical analysis, particle size and shape analysis, liberation degree analysis, thermogravimetric analysis, sink-float test, and IR spectrometry. A comparison of TV scrap, personal computer scrap, and printed circuit board scrap shows that the content of non-ferrous metals and precious metals in TV scrap is much lower than that in personal computer scrap or printed circuit board scrap. It is expected that recycling of TV scrap will not be cost-effective by utilizing conventional manual disassembly. The result of particle shape analysis indicates that the non-ferrous metal particles in TV scrap formed as a variety of shapes; it is much more heterogeneous than that of plastics and printed circuit boards. Furthermore, the separability of TV scrap using density-based techniques was evaluated by the sink-float test. The result demonstrates that a high recovery of copper could be obtained by using an effective gravity separation process. Identification of plastics shows that the major plastic in TV scrap is high impact polystyrene. Gravity separation of plastics may encounter some challenges in separation of plastics from TV scrap because of specific density variations. PMID:16624540

Cui, Jirang; Forssberg, Eric

2007-01-01

134

28 CFR 25.56 - Responsibilities of junk yards and salvage yards and auto recyclers.  

Code of Federal Regulations, 2012 CFR

...requirements. (h) Scrap metal processors and shredders...receive automobiles for recycling where the condition...ascertained, however, scrap metal processors and shredders...on this inspection, scrap metal processors and...

2013-07-01

135

Recycling  

NASA Astrophysics Data System (ADS)

Recycling systems are classified into those employing typically three methods, and the progress of each method is described. In mechanical recycling, powders of phenolic materials are recovered via a mechanical process and reused as fillers or additives in virgin materials. The effects to flowability, curability, and mechanical properties of the materials are explained. In feedstock recycling, monomers, oligomers, or oils are recovered via chemical processes and reused as feedstock. Pyrolysis, solvolysis or hydrolysis, and supercritical or subcritical fluid technology will also be introduced. When using a subcritical fluid of phenol, the recycled material maintains excellent properties similar to the virgin material, and a demonstration plant has been constructed to carry out mass production development. In energy recovery, wastes of phenolic materials are used as an alternative solid fuel to coal because they are combustible and have good calorific value. Industrial wastes of these have been in practical use in a cement plant. Finally, it is suggested that the best recycling method should be selected according to the purpose or situation, because every recycling method has both strengths and weaknesses. Therefore, quantitative and objective evaluation methods in recycling are desirable and should be established.

Goto, Junya; Santorelli, Michael

136

Does Quality Matter in the Iron and Scrap Trade?  

Microsoft Academic Search

This paper sheds light on the iron and steel (IS) scrap trade to examine how economic development affects the quality demanded of recyclable resource. A simple model is presented that show a mechanism of how scrap quality impacts the direction of trade due to comparative advantage. We find that economic development in both importing and exporting countries has a positive

Etsuyo Michida; Cemal Atici; Michikazu Kojima

2011-01-01

137

Marshall Space Flight Center solid waste characterization and recycling improvement study: General office and laboratory waste, scrap metal, office and flight surplus  

Microsoft Academic Search

The primary objectives of the study were to characterize the solid waste stream for MSFC facilities in Huntsville, Alabama, and to evaluate their present recycling program. The purpose of the study was to determine if improvements could be made in terms of increasing quantities of the present commodities collected, adding more recyclables to the program, and streamlining or improving operational

Michael H. Eley; Lavonne Crews; Ben Johnston; David Lee; James Colebaugh

1995-01-01

138

Marshall Space Flight Center solid waste characterization and recycling improvement study: General office and laboratory waste, scrap metal, office and flight surplus  

NASA Technical Reports Server (NTRS)

The primary objectives of the study were to characterize the solid waste stream for MSFC facilities in Huntsville, Alabama, and to evaluate their present recycling program. The purpose of the study was to determine if improvements could be made in terms of increasing quantities of the present commodities collected, adding more recyclables to the program, and streamlining or improving operational efficiency. In conducting the study, various elements were implemented. These included sampling and sorting representative samples of the waste stream; visually inspecting each refuse bin, recycle bin, and roll-off; interviewing employees and recycling coordinators of other companies; touring local material recycling facilities; contacting experts in the field; and performing a literature search.

Eley, Michael H.; Crews, Lavonne; Johnston, Ben; Lee, David; Colebaugh, James

1995-01-01

139

Recycled Uranium Mass Balance Project Y-12 National Security Complex Site Report  

SciTech Connect

This report has been prepared to summarize the findings of the Y-12 National Security Complex (Y-12 Complex) Mass Balance Project and to support preparation of associated U. S. Department of Energy (DOE) site reports. The project was conducted in support of DOE efforts to assess the potential for health and environmental issues resulting from the presence of transuranic (TRU) elements and fission products in recycled uranium (RU) processed by DOE and its predecessor agencies. The United States government used uranium in fission reactors to produce plutonium and tritium for nuclear weapons production. Because uranium was considered scarce relative to demand when these operations began almost 50 years ago, the spent fuel from U.S. fission reactors was processed to recover uranium for recycling. The estimated mass balance for highly enriched RU, which is of most concern for worker exposure and is the primary focus of this project, is summarized in a table. A discrepancy in the mass balance between receipts and shipments (plus inventory and waste) reflects an inability to precisely distinguish between RU and non-RU shipments and receipts involving the Y-12 Complex and Savannah River. Shipments of fresh fuel (non-RU) and sweetener (also non-RU) were made from the Y-12 Complex to Savannah River along with RU shipments. The only way to distinguish between these RU and non-RU streams using available records is by enrichment level. Shipments of {le}90% enrichment were assumed to be RU. Shipments of >90% enrichment were assumed to be non-RU fresh fuel or sweetener. This methodology using enrichment level to distinguish between RU and non-RU results in good estimates of RU flows that are reasonably consistent with Savannah River estimates. Although this is the best available means of distinguishing RU streams, this method does leave a difference of approximately 17.3 MTU between receipts and shipments. Slightly depleted RU streams received by the Y-12 Complex from ORGDP and PGDP are believed to have been returned to the shipping site or disposed of as waste on the Oak Ridge Reservation. No evidence of Y-12 Complex processing of this material was identified in the historical records reviewed by the Project Team.

NONE

2000-12-01

140

INEEL Lead Recycling in a Moratorium Environment  

Microsoft Academic Search

Since 1999, the Idaho National Engineering and Environmental Laboratory (INEEL) Lead Project successfully recycled over 700,000 pounds of excess INEEL lead to the private sector. On February 14, 2000, the Secretary of Energy, Bill Richardson, formalized the January 12, 2000, moratorium on recycling radioactive scrap metal that prevented the unrestricted release of recycled scrap metals to the private sector. This

K. E. Kooda; K. Galloway; C. W. McCray; D. W. Aitken

2003-01-01

141

Limits of Metal Recycling  

Microsoft Academic Search

This work points out different limits for the metal recycling of aluminium, copper and zinc. Being the most important parameter of the recycling activities of every metal, the scrap availability is focused on by the discussion. Knowing the availability of secondary raw materials in an existing system, the respective recycled metal content of production can be determined. However, this varies

Georg Rombach; RWTH Aachen

142

Gold recycling in the United States in 1998  

USGS Publications Warehouse

In 1998, 175 metric tons (t) of refined gold was recovered by U.S. refiners from old and new scrap. The overall recycling rate was 29 percent when scrap consumption was compared with apparent domestic supply. Sources of old scrap includes discarded jewelry, dental materials, plating solutions, and electronic equipment. A very high old scrap recycling efficiency of 96 percent was reached in 1998, the supply of old scrap peaked, gold prices were at an 18-year low, and substantial amounts of old scrap were exported. U.S. net exports of old scrap had a gold content of 28 t.

Amey, Earle B.

2001-01-01

143

Iron and steel recycling in the United States in 1998  

USGS Publications Warehouse

Consumption of iron and steel scrap and the health of the scrap industry depend directly on the health of the steelmaking industry. The United States, as well as most of the world, is expected to consume increasing amounts of scrap as a steadily increasing population demands more steel products. World resources of scrap should be sufficient for the foreseeable future. An estimated 75 million metric tons (Mt) of scrap was generated during 1998 in the United States, and 35 Mt of old scrap and 18 Mt of new scrap was consumed. The recycling efficiency was calculated to be 52%, and the recycling rate was found to be 41%. (See appendix for definitions.)

Fenton, Michael D.

2001-01-01

144

A Practical Recycling Project . . .  

ERIC Educational Resources Information Center

Descirbes a school district's recycling program of aluminum lunch trays that are collected after their use. The trays are used as scrap metal in industrial education workshop and used for sand castings. (PS)

Durant, Raymond H.; Mikuska, James M.

1973-01-01

145

Grinding and Characterization of Scrap Rubbers Powders  

Microsoft Academic Search

SBR and EPDM extruded profile scraps are ground under ambient conditions for further utilization in recycling and reclaiming processes. The obtained powders (SBR-r and EPDM-r, respectively) are physically, thermally, and chemically characterized and the results are analyzed as for its suitability for reuse methods. It is possible to obtain powdered SBR and EPDM rubber with irregular shape and high surface

Tatiana Weber; Aline Zanchet; Rosmary N. Brandalise; Janaina S. Crespo; Regina C. R. Nunes

2008-01-01

146

Cobalt recycling in the United States in 1998  

USGS Publications Warehouse

This report is one of a series of reports on metals recycling. It defines and quantifies the 1998 flow of cobalt-bearing materials in the United States, from imports and stock releases through consumption and disposition, with particular emphasis on the recycling of industrial scrap (new scrap) and used products (old scrap). Because of cobalt?s many and diverse uses, numerous types of scrap were available for recycling by a wide variety of processes. In 1998, an estimated 32 percent of U.S. cobalt supply was derived from scrap. The ratio of cobalt consumed from new scrap to that from old scrap was estimated to be 50:50. Of all the cobalt in old scrap available for recycling, an estimated 68 percent was either consumed in the United States or exported to be recycled.

Shedd, Kim B.

2002-01-01

147

Tungsten recycling in the United States in 2000  

USGS Publications Warehouse

This report, which is one of a series of reports on metals recycling, defines and quantifies the flow of tungsten-bearing materials in the United States from imports and stock releases through consumption and disposition in 2000, with particular emphasis on the recycling of industrial scrap (new scrap) and used products (old scrap). Because of tungsten's many diverse uses, numerous types of scrap were available for recycling by a wide variety of processes. In 2000, an estimated 46 percent of U.S. tungsten supply was derived from scrap. The ratio of tungsten consumed from new scrap to that consumed from old scrap was estimated to be 20:80. Of all the tungsten in old scrap available for recycling, an estimated 66 percent was either consumed in the United States or exported to be recycled.

Shedd, Kim B.

2011-01-01

148

Feasibility of re-melting NORM-contaminated scrap metal  

SciTech Connect

Naturally occurring radioactive materials (NORM) sometimes accumulate inside pieces of equipment associated with oil and gas production and processing activities. Typically, the NORM accumulates when radium that is present in solution in produced water precipitates out in scale and sludge deposits. Scrap equipment containing residual quantities of these NORM-bearing scales and sludges can present a waste management problem if the radium concentrations exceed regulatory limits or activate the alarms on radiation screening devices installed at most scrap metal recycling facilities. Although NORM-contaminated scrap metal currently is not disposed of by re-melting, this form of recycling could present a viable disposition option for this waste stream. Studies indicate that re-melting NORM-contaminated scrap metal is a viable recycling option from a risk-based perspective. However, a myriad of economic, regulatory, and policy issues have caused the recyclers to turn away virtually all radioactive scrap metal. Until these issues can be resolved, re-melting of the petroleum industry's NORM-impacted scrap metal is unlikely to be a widespread practice. This paper summarizes the issues associated with re-melting radioactive scrap so that the petroleum industry and its regulators will understand the obstacles. This paper was prepared as part of a report being prepared by the Interstate Oil and Gas Compact Commission's NORM Subcommittee.

Winters, S. J.; Smith, K. P.

1999-10-26

149

Aluminum recycling in the United States in 2000  

USGS Publications Warehouse

As one of a series of reports on metals recycling, this report discusses the flow of aluminum from production through its uses with particular emphasis on the recycling of industrial scrap (new scrap) and used products (old scrap) in 2000. This materials flow study includes a description of aluminum supply and demand factors for the United States to illustrate the extent of aluminum recycling and to identify recycling trends. Understanding the system of materials flow from source to ultimate disposition can assist in improving the management of natural resources in a manner that is compatible with sound environmental practices. In 2000, the old scrap recycling efficiency for aluminum was estimated to be 42 percent. Almost 60 percent of the aluminum that was recycled in 2000 came from new scrap, and the recycling rate was estimated to be 36 percent. The principal source of old scrap was recycled aluminum beverage cans.

Plunkert, Patricia A.

2006-01-01

150

Analysis of disposition alternatives for radioactively contaminated scrap metal  

SciTech Connect

Millions of tonnes of slightly radioactive, scrap iron and steel, stainless steel, and copper are likely to become available as nuclear and other facilities and equipment are withdrawn from service. Disposition of this material is an international policy issue under consideration currently. The major alternatives for managing this material are to either develop a regulatory process for decontamination and recycling that will safeguard human health or to dispose of the scrap and replace the metal stocks. To evaluate the alternatives, we estimate quantities of scrap arising from nuclear power plant decommissioning, evaluate potential price impacts of recycling on regional markets, and assess the health and environmental impacts of the management alternatives. We conclude that decontaminating and recycling the scrap is the superior alternative.

Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

1997-01-01

151

Recovery of scrap iron metal value using biogenerated ferric iron.  

PubMed

The utility of employing biogenerated ferric iron as an oxidant for the recycling of scrap metal has been demonstrated using continuously growing cells of the extremophilic organism Acidithiobacillus ferrooxidans. A ferric iron rich (70 mol%) lixiviant resulting from bioreactor based growth of A. ferrooxidans readily solubilized target scrap metal with the resultant generation of a leachate containing elevated ferrous iron levels and solubilized copper previously resident in the scrap metal. Recovery of the copper value was easily accomplished via a cementation reaction and the clarified leachate containing a replenished level of ferrous iron as growth substrate was shown to support the growth of A. ferrooxidans and be fully recyclable. The described process for scrap metal recycling and copper recovery was shown to be efficient and economically attractive. Additionally, the utility of employing the E(h) of the growth medium as a means for monitoring fluctuations in cell density in cultures of A. ferrooxidans is demonstrated. PMID:16440341

Ballor, Nicholas R; Nesbitt, Carl C; Lueking, Donald R

2006-04-20

152

Advances in plastic recycling. Volume 1: Recycling of polyurethanes  

SciTech Connect

``Recycling of Polyurethanes'', the first volume in the Advances in Plastics Recycling series, is focused on the physical and chemical recycling of polyurethanes, with attention given to energy conversion. A compilation of the present ongoing studies on recycling of urethane and, in general, isocyanate-based polymers, the focus is on thermosetting urethane polymers. Contents include: Recycling of Polyurethane Plastics in the European Automotive Industry; Present State of Polyurethane Recycling in Europe; Processing Overview of Bonded Polyurethane Foam; Mechanical Recycling of Polyurethane Scrap; Ecostream{trademark}--A Technology Beyond Recycling; Recycling of Flexible polyurethane Foam; General purpose Adhesives Prepared from Chemically Recycled Waste Rigid Polyurethane Foams; and Utilization of Isocyanate Binders in Recycling of Scrap Automotive Headliners.

Frisch, K.C.; Klempner, D.; Prentice, G.

1999-07-01

153

Converting Garbage to Gold: Recycling Our Materials.  

ERIC Educational Resources Information Center

Recycling conserves energy, fights pollution and inflation, creates jobs, and improves the outlook for the future of materials. But converting a throwaway society to recycling will depend on finding good markets for waste paper and scrap metals. (RM)

Chandler, William U.

1984-01-01

154

Melting standardized aluminum scrap: A mass balance model for europe  

NASA Astrophysics Data System (ADS)

Although individual aluminum recycling companies have good knowledge of scrap in terms of its characteristic metal yield during melting, an overall view of this industry is still missing. An aluminum mass balance for the aluminum recycling industry in the European Union member states from 1995 to 2004 (EU-15) has been carried out. The objective was to increase the transparency of the complex recycling system and to determine how resource-conservative the industry is when melting aluminum scrap. Results show that in 2002, about 7 million tonnes of purchased, tolled, and internal scrap—with a metal content of 94%—were recycled in the EU-15. By comparing the net metal input to the final product, the study finds a very respectable metal recovery rate of 98%.

Boin, U. M. J.; Bertram, M.

2005-08-01

155

Germanium recycling in the United States in 2000  

USGS Publications Warehouse

This report describes the recycling flow of germanium in the United States in 2000, as well as other germanium material flow streams. Germanium was recycled mostly from new scrap that was generated during the manufacture of germanium-containing fiber optic cables and from new and old scrap products of germanium-containing infrared imaging devices. In 2000, about 11.5 metric tons of germanium was recycled, about 40 percent of which was derived from old scrap. The germanium recycling rate was estimated to be 50 percent, and germanium scrap recycling efficiency, 76 percent.

Jorgenson, John D.

2006-01-01

156

Advanced technologies for decontamination and conversion of scrap metal  

Microsoft Academic Search

In October 1993, Manufacturing Sciences Corporation was awarded DOE contract DE-AC21-93MC30170 to develop and test recycling of radioactive scrap metal (RSM) to high value and intermediate and final product forms. This work was conducted to help solve the problems associated with decontamination and reuse of the diffusion plant barrier nickel and other radioactively contaminated scrap metals present in the diffusion

V. MacNair; T. Muth; K. Shasteen; A. Liby; G. Hradil; B. Mishra

1996-01-01

157

Recycling galvanized steel: Operating experience and benefits  

SciTech Connect

In response to the increase in consumption of galvanized steel for automobiles in the last decade and the problems associated with remelting larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is recovered electrolytically as dendritic powder. The dezinced ferrous scrap is rinsed and used directly. The process is effective for zinc, lead, and aluminum removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested for batch treatment of 900 tonnes of mostly baled scrap. A pilot plant to continuously treat loose scrap, with a design capacity of 48,000 tonnes annually, has been in operation in East Chicago, Indiana since early in 1993. The first 450 t of scrap degalvanized in the pilot plant have residual zinc below 0.01% and sodium dragout below 0.01%. Use of degalvanized steel scrap decreases raw materials, environmental compliance, and opportunity costs to steel- and iron-makers. Availability of clean degalvanized scrap may enable integrated steel producers to recycle furnace dusts to the sinter plant and EAF shops to produce flat products without use of high quality scrap alternatives such as DRI, pig iron, or iron carbide. Recycling the components of galvanized steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap. The quantities of zinc available by the year 2000 from prompt and obsolete automotive scrap win approach 25% of zinc consumed in the major automotive production centers of the world. Zinc recycling from galvanized steel scrap, either before or after scrap melting, will have to be implemented.

Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Morgan, W.A. [Metal Recovery Industries, Inc., East Chicago, IN (United States)

1993-08-01

158

An industry response to recycle 2000  

Microsoft Academic Search

The US DOE is expected to issue a policy early this year articulating DOE`s position on the recycle of DOE radioactive scrap metal. In anticipation of this `Recycle 2000` initiative, the nuclear industry has formed a new trade association called the Association of Radioactive Metal Recyclers (ARMR). This article describes the Recycle 2000 initiative, provides some background on the ARMR

G. P. Motl; V. Loiselle

1996-01-01

159

Development and characterization of composites with ground elastomeric vulcanized scraps as filler  

Microsoft Academic Search

Mechanical recycling of vulcanized rubber scraps is a low-cost alternative in the search for the recovery of this kind of industrial solid waste. The aim of this study is to incorporate styrene–butadiene rubber (SBR) industrial scraps into a base formulation of SBR used in the fabrication process of extruded profiles. Rheometric, mechanical and morphological characteristics of this base formulation with

Larissa N. Carli; Rosiana Boniatti; Cláudia E. Teixeira; Regina C. R. Nunes; Janaina S. Crespo

2009-01-01

160

Process for removing and detoxifying cadmium from scrap metal including mixed waste  

Microsoft Academic Search

Cadmium-bearing scrap from nuclear applications, such as neutron shielding and reactor control and safety rods, must usually be handled as mixed waste since it is radioactive and the cadmium in it is both leachable and highly toxic. Removing the cadmium from this scrap, and converting it to a nonleachable and minimally radioactive form, would greatly simplify disposal or recycling. A

Kronberg

1994-01-01

161

Gold Recycling in the United States in 1998.  

National Technical Information Service (NTIS)

In 1998, 175 metric tons (t) of refined gold was recovered by U.S. refiners from old and new scrap. The overall recycling rate was 29 percent when scrap consumption was compared with apparent domestic supply. Sources of old scrap included discarded jewelr...

E. B. Amey

1998-01-01

162

THE CONTROL OF URANIUM FIRES  

Microsoft Academic Search

Fires have occurred in the production, storing, handling and shipping of uranium powder and turnings. Batches of uranium powder, swarf and solid scrap have been ignited to observe fire temperatures and combustion rates and materials and methods to suppress or extinguish uranium fires investigated. The effect on various metals in contact with burning uranium has also been examined. The uranium

1952-01-01

163

Beryllium Recycling in the United States in 2000  

USGS Publications Warehouse

This report describes the flow of beryllium in the United States in 2000 with emphasis on the extent to which beryllium was either recycled or reused. Beryllium was recycled mostly from new scrap that was generated during the manufacture of beryllium-related components. In 2000, about 35 metric tons of beryllium was either recycled or reused, about 14 percent of which was derived from old scrap. The beryllium recycling rate was calculated to be about 10 percent, and beryllium scrap recycling efficiency, about 7 percent.

Cunningham, Larry D.

2003-01-01

164

Beryllium recycling in the United States in 2000  

USGS Publications Warehouse

This report describes the flow of beryllium in the United States in 2000 with emphasis on the extent to which beryllium was either recycled or reused. Beryllium was recycled mostly from new scrap that was generated during the manufacture of beryllium-related components. In 2000, about 35 metric tons of beryllium was either recycled or reused, about 14 percent of which was derived from old scrap. The beryllium recycling rate was calculated to be about 10 percent, and beryllium scrap recycling efficiency, about 7 percent.

Cunningham, Larry D.

2004-01-01

165

Advanced technologies for decontamination and conversion of scrap metal  

Microsoft Academic Search

The Department of Energy (DOE) accumulated large quantities of radioactive scrap metal (RSM) through historic maintenance activities. The Decontamination and Decommissioning (D&D) of major sites formerly engaged in production of nuclear materials and manufacture of nuclear weapons will generate additional quantities of RSM, as much as 3 million tons of such metal according to a recent study. The recycling of

T. R. Muth; K. E. Shasteen; A. L. Liby

1995-01-01

166

ADVANCED TECHNOLOGIES FOR DECONTAMINATION AND CONVERSION OF SCRAP METAL  

Microsoft Academic Search

The Department of Energy (DOE) confronts the major responsibility of decommissioni ng most of the U.S. Nuclear Complex, which also includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for cleanup of

Jagdish Malhotra

2000-01-01

167

Radiological Assessment of Releasing Scrap Metal from Nuclear Facilities  

Microsoft Academic Search

Large quantities of scrap metal are generated during the extensive worldwide decontamination and decommissioning of nuclear facilities and, to a lesser extent, during the normal operations of these facilities. To evaluate the radiological impacts of releasing potentially contaminated metals to the general environment, the U.S. Environmental Protection Agency (EPA) performed an exhaustive analysis of the release and recycling of carbon

N. Naraine; C. Conklin; R. Anigstein

2000-01-01

168

Scrap Metal Sorting with Colour Vision and Inductive Sensor Array  

Microsoft Academic Search

This paper presents a novel automatic scrap metal sorting system which employs a colour vision based optical sensing system and an inductive sensor array. The operation of the system is verified in a real metal recycling plant. The long period test results indicate that 80 % purity can be achieved when the feeding conveyor speed is limited below 1,5 m\\/s.

Matti Kutila; Jouko Viitanen; Antero Vattulainen

2005-01-01

169

Analysis of disposition alternatives for radioactively contaminated scrap metal  

Microsoft Academic Search

Millions of tonnes of slightly radioactive, scrap iron and steel, stainless steel, and copper are likely to become available as nuclear and other facilities and equipment are withdrawn from service. Disposition of this material is an international policy issue under consideration currently. The major alternatives for managing this material are to either develop a regulatory process for decontamination and recycling

L. A. Nieves; S. Y. Chen; E. J. Kohout; B. Nabelssi; R. W. Tilbrook; S. E. Wilson

1997-01-01

170

Risk and impact tradeoffs in radioactive scrap metal management  

Microsoft Academic Search

Two management alternatives for radioactive scrap metal were evaluated: (1) recycling and reuse, and (2) disposal and replacement. The human health risks, environmental impacts, and sociopolitical issues potentially associated with these alternatives were assessed in an international context. For each alternative, the health risks from workplace and transportation accidents are greater in magnitude than the risks from potential exposure to

L. A. Nieves; S. Y. Chen

1995-01-01

171

Analysis of disposition alternatives for radioactively contaminated scrap metal  

Microsoft Academic Search

Millions of tons of slightly radioactive scrap iron and steel, stainless steel, and copper are likely to become available as nuclear and other facilities and equipment are withdrawn from service. Disposition of this material is an international policy issue under consideration currently. The major alternatives for managing this material are either to develop a regulatory process for decontamination and recycling

L. A. Nieves; S. Y. Chen; E. J. Kohout; B. Nabelssi; R. W. Tilbrook; S. E. Wilson

1998-01-01

172

Advanced technologies for decomtamination and conversion of scrap metal  

Microsoft Academic Search

The Department of Energy (DOE) faces the task of decommissioning much of the vast US weapons complex. One challenge of this effort includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for

Valerie MacNair; Steve Sarten; Thomas Muth; Brajendra Mishra

1999-01-01

173

Recycled Coarse Aggregate Produced by Pulsed Discharge in Water  

NASA Astrophysics Data System (ADS)

In Japan, the recycling ratio of concrete scraps has been kept over 98 % after the Law for the Recycling of Construction Materials was enforced in 2000. In the present, most of concrete scraps were recycled as the Lower Subbase Course Material. On the other hand, it is predicted to be difficult to keep this higher recycling ratio in the near future because concrete scraps increase rapidly and would reach to over 3 times of present situation in 2010. In addition, the demand of concrete scraps as the Lower Subbase Course Material has been decreased. Therefore, new way to reuse concrete scraps must be developed. Concrete scraps normally consist of 70 % of coarse aggregate, 19 % of water and 11 % of cement. To obtain the higher recycling ratio, the higher recycling ratio of coarse aggregate is desired. In this paper, a new method for recycling coarse aggregate from concrete scraps has been developed and demonstrated. The system includes a Marx generator and a point to hemisphere mesh electrode immersed in water. In the demonstration, the test piece of concrete scrap was located between the electrodes and was treated by the pulsed discharge. After discharge treatment of test piece, the recycling coarse aggregates were evaluated under JIS and TS and had enough quality for utilization as the coarse aggregate.

Namihira, Takao; Shigeishi, Mitsuhiro; Nakashima, Kazuyuki; Murakami, Akira; Kuroki, Kaori; Kiyan, Tsuyoshi; Tomoda, Yuichi; Sakugawa, Takashi; Katsuki, Sunao; Akiyama, Hidenori; Ohtsu, Masayasu

174

Lead decontamination and recycling under RCRA regulatory implications  

Microsoft Academic Search

Radioactively contamination lead is a significant scrap metal recycling opportunity for the Department of Energy (DOE) facilities. Unfortunately, the regulatory maze to determine exactly how to manage scrap metal before it goes to the market may deter facilities from pursuing this opportunity. This paper presents an analysis of the regulatory issues, provides some management guidelines and identifies recycling and reuse

S. Moore-Mayne; M. Romero; H. Grover; S. L. Harnett

1996-01-01

175

Energy use patterns for metal recycling. Information circular  

Microsoft Academic Search

Data were collected on energy requirements to recycle prompt industrial and obsolete scrap for nine metal commodities: iron and steel, aluminum, copper, zinc, lead, stainless steel, titanium, tin, and nickel and nickel alloys. Major process routes for recycling were considered, starting from the first collection point through scrap preparation, transportation, smelting and\\/or refining to the molten metal, ingot, or other

C. L. Kusik; C. B. Kenahan

1978-01-01

176

Using Established Regulations to Recycle Contaminated Metals  

Microsoft Academic Search

DOE restoration projects require acceptable standards for processing volumetrically contaminated metals: ⢠NRC has no regulations addressing recycling of scrap metal containing residual volumetric radioactivity. ⢠DOE is currently restricting outside radioactive scrap metal sales; however, previous Fernald and Ohio State clean-ups have released metals with measurable levels of radioactivity into the open market. ⢠Public sensitivity to the subject

Loewen; Eric Paul

2000-01-01

177

Nickel recycling in the United States in 2004  

USGS Publications Warehouse

As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the flow of nickel from production through distribution and use, with particular emphasis on the recycling of industrial scrap (new scrap) and used products (old scrap) in 2004. This materials flow study includes a description of nickel supply and demand for the United States to illustrate the extent of nickel recycling and to identify recycling trends. Understanding how materials flow from a source through disposition can aid in improving the management of natural resource delivery systems. In 2004, the old scrap recycling efficiency for nickel was estimated to be 56.2 percent. In 2004, nickel scrap consumption in the United States was as follows: new scrap containing 13,000 metric tons (t) of nickel (produced during the manufacture of products), 12 percent; and old scrap containing 95,000 t of nickel (articles discarded after serving a useful purpose), 88 percent. The recycling rate for nickel in 2004 was 40.9 percent, and the percentage of nickel in products attributed to nickel recovered from nickel-containing scrap was 51.6 percent. Furthermore, U.S. nickel scrap theoretically generated in 2004 had the following distribution: scrap to landfills, 24 percent; recovered and used scrap, 50 percent; and unaccounted for scrap, 26 percent. Of the 50 percent of old scrap generated in the United States that was recovered and then used in 2004, about one-third was exported and two-thirds was consumed in the domestic production of nickel-containing products.

Goonan, Thomas G.

2009-01-01

178

Radiological Assessment of Releasing Scrap Metal from Nuclear Facilities  

SciTech Connect

Large quantities of scrap metal are generated during the extensive worldwide decontamination and decommissioning of nuclear facilities and, to a lesser extent, during the normal operations of these facilities. To evaluate the radiological impacts of releasing potentially contaminated metals to the general environment, the U.S. Environmental Protection Agency (EPA) performed an exhaustive analysis of the release and recycling of carbon steel scrap. Further assessments were performed of the clearance and recycling of aluminum and copper scrap. The aim of the analyses was to calculate the annual dose and the lifetime risk of cancer to the reasonably maximally exposed (RME) individual, normalized to the specific activity of a given radioactive contaminant in the scrap, from 1 yr of exposure. These results, presented as a set of tables that list the normalized doses and risks to the RME individual for each of 40 radionuclides that are potential contaminants of the three metals, can be used to assess the potential health effects of releasing scrap with a given level of contamination. This report describes the analysis and gives a summary of the results.

N. Naraine; C. Conklin; R. Anigstein

2000-06-04

179

The concept of the use of recycled uranium for increasing the degree of security of export deliveries of fuel for light-water reactors  

NASA Astrophysics Data System (ADS)

The present paper deals with investigation of the possibilities for reducing the risk of proliferation of fissionable materials by means of increasing the degree of protection of fresh fuel intended for light-water reactors against unsanctioned use in the case of withdrawal of a recipient country of deliveries from IAEA safeguards. It is shown that the use of recycled uranium for manufacturing export nuclear fuel makes transfer of nuclear material removed from the fuel assemblies for weapons purposes difficult because of the presence of isotope 232U, whose content increases when one attempts to enrich uranium extracted from fresh fuel. In combination with restricted access to technologies for isotope separation by means of establishing international centers for uranium enrichment, this technical measure can significantly reduce the risk of proliferation associated with export deliveries of fuel made of low-enriched uranium. The assessment of a maximum level of contamination of nuclear material being transferred by isotope 232U for the given isotope composition of the initial fuel is obtained. The concept of further investigations of the degree of security of export deliveries of fuel assemblies with recycled uranium intended for light-water reactors is suggested.

Alekseev, P. N.; Ivanov, E. A.; Nevinitsa, V. A.; Ponomarev-Stepnoi, N. N.; Rumyantsev, A. N.; Shmelev, V. M.; Borisevich, V. D.; Smirnov, A. Yu.; Sulaberidze, G. A.

2010-12-01

180

Management of MSW in Spain and recovery of packaging steel scrap.  

PubMed

Packaging steel is more advantageously recovered and recycled than other packaging material due to its magnetic properties. The steel used for packaging is of high quality, and post-consumer waste therefore produces high-grade ferrous scrap. Recycling is thus an important issue for reducing raw material consumption, including iron ore, coal and energy. Household refuse management consists of collection/disposal, transport, and processing and treatment - incineration and composting being the most widely used methods in Spain. Total Spanish MSW production exceeds 21 million tons per year, of which 28.1% and 6.2% are treated in compost and incineration plants, respectively. This paper presents a comprehensive study of incineration and compost plants in Spain, including a review of the different processes and technologies employed and the characteristics and quality of the recovered ferrous scrap. Of the total amount of packaging steel scrap recovered from MSW, 38% comes from compost plants and 14% from incineration plants. Ferrous scrap from incineration plants presents a high degree of chemical alteration as a consequence of the thermal process to which the MSW is subjected, particularly the conditions in which the slag is cooled, and accordingly its quality diminishes. Fragmentation and magnetic separation processes produce an enhancement of the scrap quality. Ferrous scrap from compost plants has a high tin content, which negatively affects its recycling. Cleaning and detinning processes are required prior to recycling. PMID:17161595

Tayibi, Hanan; Peña, Carmen; López, Félix A; López-Delgado, Aurora

2007-01-01

181

The steel scrap age.  

PubMed

Steel production accounts for 25% of industrial carbon emissions. Long-term forecasts of steel demand and scrap supply are needed to develop strategies for how the steel industry could respond to industrialization and urbanization in the developing world while simultaneously reducing its environmental impact, and in particular, its carbon footprint. We developed a dynamic stock model to estimate future final demand for steel and the available scrap for 10 world regions. Based on evidence from developed countries, we assumed that per capita in-use stocks will saturate eventually. We determined the response of the entire steel cycle to stock saturation, in particular the future split between primary and secondary steel production. During the 21st century, steel demand may peak in the developed world, China, the Middle East, Latin America, and India. As China completes its industrialization, global primary steel production may peak between 2020 and 2030 and decline thereafter. We developed a capacity model to show how extensive trade of finished steel could prolong the lifetime of the Chinese steelmaking assets. Secondary steel production will more than double by 2050, and it may surpass primary production between 2050 and 2060: the late 21st century can become the steel scrap age. PMID:23442209

Pauliuk, Stefan; Milford, Rachel L; Müller, Daniel B; Allwood, Julian M

2013-04-01

182

Chromium Recycling in the United States in 1998  

USGS Publications Warehouse

The purpose of this report is to illustrate the extent to which chromium was recycled in the United States in 1998 and to identify chromium-recycling trends. The major use of chromium was in the metallurgical industry to make stainless steel; substantially less chromium was used in the refractory and chemical industries. In this study, the only chromium recycling reported was that which was a part of stainless steel scrap reuse. In 1998, 20 percent of the U.S. apparent consumption of chromium was secondary (from recycling); the remaining 80 percent was based on net chromium commodity imports and stock adjustments. Chromite ore was not mined in the United States in 1998. In 1998, 75,300 metric tons (t) of chromium contained in old scrap was consumed in the United States; it was valued at $66.4 million. Old scrap generated contained 132,000 t of chromium. The old scrap recycling efficiency was 87 percent, and the recycling rate was 20 percent. About 18,000 t of chromium in old scrap was unrecovered. New scrap consumed contained 28,600 t of chromium, which yielded a new-to-old-scrap ratio of 28:72. U.S. chromium-bearing stainless steel scrap net exports were valued at $154 million and were estimated to have contained 41,000 t of chromium.

Papp, John F.

2001-01-01

183

Manganese recycling in the United States in 1998  

USGS Publications Warehouse

This report describes the flow and processing of manganese within the U.S. economy in 1998 with emphasis on the extent to which manganese is recycled. Manganese was used mostly as an alloying agent in alloys in which it was a minor component. Manganese was recycled mostly within scrap of iron and steel. A small amount was recycled within aluminum used beverage cans. Very little manganese was recycled from materials being recovered specifically for their manganese content. For the United States in 1998, 218,000 metric tons of manganese was estimated to have been recycled from old scrap, of which 96% was from iron and steel scrap. Efficiency of recycling was estimated as 53% and recycling rate as 37%. Metallurgical loss of manganese was estimated to be about 1.7 times that recycled. This loss was mostly into slags from iron and steel production, from which recovery of manganese has yet to be shown economically feasible.

Jones, Thomas S.

2001-01-01

184

Aluminium recycling and environmental issues of salt slag treatment.  

PubMed

Environmental friendly recycling is the trend toward total recycling of aluminium metal. In the secondary aluminium industry, due to the complexity of compositions and contaminants in the various types of aluminium scraps, an understanding of the behavior of different scraps during melting is crucial in the recycling process. Salt slags are the byproducts of the secondary aluminium industry, which should be recycled and processed in a proper way by taking the environmental impact into consideration. This article provides qualitative assessment on 10 different commercial aluminium scraps for their relative recyclability via well-designed and controlled laboratory experiments. It confirms that more nonmetallic contaminants, smaller size, and higher ratio of surface area to body volume generally lead to a lower metal recovery. Recycling the scraps with lower recyclability normally generates more salt slags. High slag viscosity leads to more fine aluminum metal entrapped in the salt slag and thus increases the load of salt slag recycling. It was found that viscosity of the salt flux is increased with the amount of entrapped nonmetallic components, which affect the settling of heavier materials. In addition, the slag samples from the melting tests were leached and analyzed to evaluate the behavior of carbon containing scrap. The elevated carbon content in the scrap resulted in more carbide formation in salt slags and thus more methane generation in salt slag recycling with a higher environmental impact. PMID:16194908

Xiao, Yanping; Reuter, Markus A; Boin, Udo

2005-01-01

185

Proceedings of the waste recycling workshop  

SciTech Connect

Recorded are seventeen talks from five sessions at the workshop. FERMCO`s recycling program, state of the art recycling technology, and an integrated demonstration of deactivation, decommissioning and decommissioning are presented in the plenary session. In the concrete session, decontamination and recycling are discussed. In the transite session, regulations are considered along with recycling and decontamination. In the metals session, radioactive scrap metals are emphasized. And in the regulatory considerations and liabilities session, DOE and EPA viewpoints are discussed. (GHH)

Bailey, R.E.; Thomas, A.F.; Ries, M.A. [eds.] [Ohio State Univ., Columbus, OH (United States)] [eds.; Ohio State Univ., Columbus, OH (United States)

1993-12-31

186

Scrap metal management issues associated with naturally occurring radioactive material  

SciTech Connect

Certain industrial processes sometimes generate waste by-products that contain naturally occurring radioactive material (NORM) at elevated concentrations. Some industries, including the water treatment, geothermal energy, and petroleum industries, generate scrap metal that may be contaminated with NORM wastes. Of these three industries, the petroleum industry probably generates the largest quantity of NORM-contaminated equipment, conservatively estimated at 170,000 tons per year. Equipment may become contaminated when NORM-containing scale or sludge accumulates inside water-handling equipment. The primary radionuclides of concern in these NORM wastes are radium-226 and radium-228. NORM-contaminated equipment generated by the petroleum industry currently is managed several ways. Some equipment is routinely decontaminated for reuse; other equipment becomes scrap metal and may be disposed of by burial at a licensed landfill, encapsulation inside the wellbore of an abandoned well, or shipment overseas for smelting. In view of the increased regulatory activities addressing NORM, the economic burden of managing NORM-contaminated wastes, including radioactive scrap metal, is likely to continue to grow. Efforts to develop a cost-effective strategy for managing radioactive scrap metal should focus on identifying the least expensive disposition options that provide adequate protection of human health and the environment. Specifically, efforts should focus on better characterizing the quantity of radioactive scrap available for recycle or reuse, the radioactivity concentration levels, and the potential risks associated with different disposal options.

Smith, K.P.; Blunt, D.L.

1995-08-01

187

Detinning of Tin Plate Scrap.  

National Technical Information Service (NTIS)

A method is described for preparing and detinning tinplate scrap in an alkaline bath at an electrolyte temperature of 90 C. Tin particles can also be removed from unlacquered tinplate scrap at short processing times. As compared to the margin amount obtai...

R. Becker H. Kammereck

1984-01-01

188

Advanced technologies for decontamination and conversion of scrap metal  

SciTech Connect

The Department of Energy (DOE) accumulated large quantities of radioactive scrap metal (RSM) through historic maintenance activities. The Decontamination and Decommissioning (D&D) of major sites formerly engaged in production of nuclear materials and manufacture of nuclear weapons will generate additional quantities of RSM, as much as 3 million tons of such metal according to a recent study. The recycling of RSM is quickly becoming appreciated as a key strategy in DOE`s cleanup of contaminated sites and facilities.

Muth, T.R.; Shasteen, K.E.; Liby, A.L. [and others

1995-12-01

189

Potential radiation dose to man from recycle of metals reclaimed from a decommissioned nuclear power plant  

Microsoft Academic Search

A generic methodology is presented for estimating potential radiation doses to man from recycling radioactively contaminated scrap metals that may be reclaimed from decommissioned nuclear facilities. The heart of the methodology is a set of tables of radionuclide-specific, radiation-dose factors that may be used to estimate doses to individuals and population groups from recycling any radioactively contaminated scrap metal. The

F. R. ODonnell; S. J. Cotter; D. C. Kocher; E. L. Etnier; A. P. Watson

1978-01-01

190

Columbium (niobium) recycling in the United States in 1998  

USGS Publications Warehouse

This report describes the flow of columbium in the United States in 1998 with emphasis on the extent to which columbium (niobium) was recycled/reused. Columbium was mostly recycled from products of columbium-bearing steels and superalloys; little was recovered from products specifically for their columbium content. In 1998, about 1,800 metric tons of columbium was recycled/reused, with about 55% derived from old scrap. The columbium recycling rate was calculated to be 22%, and columbium scrap recycling efficiency, 50%.

Cunningham, Larry D.

2001-01-01

191

Platinum recycling in the United States in 1998  

USGS Publications Warehouse

In the United States, catalytic converters are the major source of secondary platinum for recycling. Other sources of platinum scrap include reforming and chemical process catalysts. The glass industry is a small but significant source of platinum scrap. In North America, it has been estimated that in 1998 more than 20,000 kilograms per year of platinum-group metals from automobile catalysts were available for recycling. In 1998, an estimated 7,690 kilograms of platinum were recycled in the United States. U.S. recycling efficiency was calculated to have been 76 percent in 1998; the recycling rate was estimated at 16 percent.

Hilliard, Henry E.

2001-01-01

192

Improving metal returns and eco-efficiency in electronics recycling  

Microsoft Academic Search

Abstract—The efficient recovery of precious and special metals from electronic scrap has significant benefits - economically, environmentally, but also under a resource conservation aspect. The yields of these metals could be substantially improved by higher collection rates, less scrap exports to regions with insuffi- cient recycling structures, and by interface optimisation, as pointed out in this document. Keywords - electronic

Christian Hagelüken; Ag Umicore; Kg Co

193

Radioactive scrap metal decontamination technology assessment report  

SciTech Connect

Within the DOE complex there exists a tremendous quantity of radioactive scrap metal. As an example, it is estimated that within the gaseous diffusion plants there exists in excess of 700,000 tons of contaminated stainless steel. At present, valuable material is being disposed of when it could be converted into a high quality product. Liquid metal processing represents a true recycling opportunity for this material. By applying the primary production processes towards the material`s decontamination and re-use, the value of the strategic resource is maintained while drastically reducing the volume of material in need of burial. Potential processes for the liquid metal decontamination of radioactively contaminated metal are discussed and contrasted. Opportunities and technology development issues are identified and discussed. The processes compared are: surface decontamination; size reduction, packaging and burial; melting technologies; electric arc melting; plasma arc centrifugal treatment; air induction melting; vacuum induction melting; and vacuum induction melting and electroslag remelting.

Buckentin, J.M.; Damkroger, B.K.; Schlienger, M.E. [Sandia National Labs., Albuquerque, NM (United States). Liquid Metal Processing Lab.

1996-04-01

194

Assuring the continued recycling of light metals in end-of-life vehicles: A global perspective  

NASA Astrophysics Data System (ADS)

This article reviews issues and technologies in recycling, both current and future, with a focus on end-of-life vehicles (ELVs) and their increasing light material content. Discussion includes the issues involved in designing for recycling, the existing global scrap recycling system, and interactions between different types of recyclables and different sections of the global market. A review follows of current scrap recycling technologies and compares the vehicle recycling regulations in the United States, European Union, and Japan. Finally, opinions are presented on useful, and some not so useful, global and local recycling regulations and initiatives.

Gesing, Adam

2004-08-01

195

Copper Recycling in the United States in 2004  

USGS Publications Warehouse

As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the flow of copper from production through distribution and use, with particular emphasis on the recycling of industrial scrap (new scrap1) and used products (old scrap) in the year 2004. This materials flow study includes a description of copper supply and demand for the United States to illustrate the extent of copper recycling and to identify recycling trends. Understanding how materials flow from a source through disposition can aid in improving the management of natural resource delivery systems. In 2004, the U.S. refined copper supply was 2.53 million metric tons (Mt) of refined unalloyed copper. With adjustment for refined copper exports of 127,000 metric tons (t) of copper, the net U.S. refined copper supply was 2.14 Mt of copper. With this net supply and a consumer inventory decrease of 9,000 t of refined copper, 2.42 Mt of refined copper was consumed by U.S. semifabricators (brass mills, wire rod mills, ingot makers, and foundries and others) in 2004. In addition to the 2.42 Mt of refined copper consumed in 2004, U.S. copper semifabricators consumed 853,000 t of copper contained in recycled scrap. Furthermore, 61,000 t of copper contained in scrap was consumed by noncopper alloy makers, for example, steelmakers and aluminum alloy makers. Old scrap recycling efficiency for copper was estimated to be 43 percent of theoretical old scrap supply, the recycling rate for copper was 30 percent of apparent supply, and the new-scrap-to-old-scrap ratio for U.S. copper product production was 3.2 (76:24).

Goonan, Thomas G.

2009-01-01

196

Automobile shredder residue: Process developments for recovery of recyclable constituents.  

National Technical Information Service (NTIS)

The objectives of this paper are threefold: (1) to briefly outline the structure of the automobile shredder industry as a supplier of ferrous scrap, (2) to review the previous research that has been conducted for recycling automobile shredder residue (ASR...

E. J. Daniels B. J. Jody P. V. Bonsignore E. L. Shoemaker

1990-01-01

197

Characterization of Scrap Materials for Mass Detonating Energetic Materials - Final Report, Project CU1194  

SciTech Connect

Military test and training ranges generate scrap materials from targets and ordnance debris. These materials are routinely removed from the range for recycling; however, energetic material residues in this range scrap has presented a significant safety hazard to operations personnel and damaged recycling equipment. The Strategic Environmental Research and Development Program (SERDP) sought proof of concept evaluations for monitoring technologies to identify energetic residues among range scrap. Sandia National Laboratories teamed with Nomadics, Inc. to evaluate the Nomadics FIDO vapor sensor for application to this problem. Laboratory tests were completed that determined the vapor-sensing threshold to be 10 to 20 ppt for TNT and 150 to 200 ppt for DNT. Field tests with the FIDO demonstrated the proof of concept that energetic material residues can be identified with vapor sensing in enclosed scrap bins. Items such as low order detonation debris, demolition block granules, and unused 81-mm mortars were detected quickly and with minimum effort. Conceptual designs for field-screening scrap for energetic material residues include handheld vapor sensing systems, batch scrap sensing systems, continuous conveyor sensing systems and a hot gas decontamination verification system.

PHELAN, JAMES M.; BARNETT, JAMES L.; FISCHER, MARK; HOLLAND, RYAN

2002-03-01

198

Advanced technologies for decontamination and conversion of scrap metal  

SciTech Connect

In October 1993, Manufacturing Sciences Corporation was awarded DOE contract DE-AC21-93MC30170 to develop and test recycling of radioactive scrap metal (RSM) to high value and intermediate and final product forms. This work was conducted to help solve the problems associated with decontamination and reuse of the diffusion plant barrier nickel and other radioactively contaminated scrap metals present in the diffusion plants. Options available for disposition of the nickel include decontamination and subsequent release or recycled product manufacture for restricted end use. Both of these options are evaluated during the course of this research effort. work during phase I of this project successfully demonstrated the ability to make stainless steel from barrier nickel feed. This paved the way for restricted end use products made from stainless steel. Also, after repeated trials and studies, the inducto-slag nickel decontamination process was eliminated as a suitable alternative. Electro-refining appeared to be a promising technology for decontamination of the diffusion plant barrier material. Goals for phase II included conducting experiments to facilitate the development of an electro-refining process to separate technetium from nickel. In parallel with those activities, phase II efforts were to include the development of the necessary processes to make useful products from radioactive scrap metal. Nickel from the diffusion plants as well as stainless steel and carbon steel could be used as feed material for these products.

MacNair, V.; Muth, T.; Shasteen, K.; Liby, A.; Hradil, G.; Mishra, B.

1996-12-31

199

Process for recovering niobium from uranium-niobium alloys  

DOEpatents

Niobium is recovered from scrap uranium-niobium alloy by melting the scrap with tin, solidifying the billet thus formed, heating the billet to combine niobium with tin therein, placing the billet in hydrochloric acid to dissolve the uranium and leave an insoluble residue of niobium stannide, then separating the niobium stannide from the acid.

Wallace, Steven A. (Knoxville, TN); Creech, Edward T. (Oak Ridge, TN); Northcutt, Walter G. (Oak Ridge, TN)

1983-01-01

200

Process for recovering niobium from uranium-niobium alloys  

DOEpatents

Niobium is recovered from scrap uranium-niobium alloy by melting the scrap with tin, solidifying the billet thus formed, heating the billet to combine niobium with tin therein, placing the billet in hydrochloric acid to dissolve the uranium and form a precipitate of niobium stannide, then separating the precipitate from the acid.

Wallace, S.A.; Creech, E.T.; Northcutt, W.G.

1982-09-27

201

Decontamination and reuse of ORGDP aluminum scrap  

SciTech Connect

The Gaseous Diffusion Plants, or GDPs, have significant amounts of a number of metals, including nickel, aluminum, copper, and steel. Aluminum was used extensively throughout the GDPs because of its excellent strength to weight ratios and good resistance to corrosion by UF{sub 6}. This report is concerned with the recycle of aluminum stator and rotor blades from axial compressors. Most of the stator and rotor blades were made from 214-X aluminum casting alloy. Used compressor blades were contaminated with uranium both as a result of surface contamination and as an accumulation held in surface-connected voids inside of the blades. A variety of GDP studies were performed to evaluate the amounts of uranium retained in the blades; the volume, area, and location of voids in the blades; and connections between surface defects and voids. Based on experimental data on deposition, uranium content of the blades is 0.3%, or roughly 200 times the value expected from blade surface area. However, this value does correlate with estimated internal surface area and with lengthy deposition times. Based on a literature search, it appears that gaseous decontamination or melt refining using fluxes specific for uranium removal have the potential for removing internal contamination from aluminum blades. A melt refining process was used to recycle blades during the 1950s and 1960s. The process removed roughly one-third of the uranium from the blades. Blade cast from recycled aluminum appeared to perform as well as blades from virgin material. New melt refining and gaseous decontamination processes have been shown to provide substantially better decontamination of pure aluminum. If these techniques can be successfully adapted to treat aluminum 214-X alloy, internal and, possibly, external reuse of aluminum alloys may be possible.

Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Wilson, D.F.

1996-12-01

202

Cadmium Recycling in the United States in 2000  

USGS Publications Warehouse

Recycling of cadmium is a young and growing industry that has been influenced by environmental concerns and regulatory constraints. Domestic recycling of cadmium began in 1989 as a byproduct of processing of spent nickel-cadmium batteries. In 1995, International Metals Reclamation Co. Inc. expanded its operations by building a dedicated cadmium recycling plant. In 2000, an estimated 13 percent of cadmium consumption in the United States was sourced from recycled cadmium, which is derived mainly from old scrap or, to lesser degree, new scrap. The easiest forms of old scrap to recycle are small spent nickel-cadmium batteries followed by flue dust generated during recycling of galvanized steel and small amounts of alloys that contain cadmium. Most of new scrap is generated during manufacturing processes, such as nickel-cadmium battery production. All other uses of cadmium are in low concentrations and, therefore, difficult to recycle. Consequently, much of this cadmium is dissipated and lost. The amount of cadmium in scrap that was unrecovered in 2000 was estimated to be 2,030 t, and an estimated 285 t was recovered. Recycling efficiency was estimated to be about 15 percent.

Plachy, Jozef

2003-01-01

203

Cadmium recycling in the United States in 2000  

USGS Publications Warehouse

Recycling of cadmium is a young and growing industry that has been influenced by environmental concerns and regulatory constraints. Domestic recycling of cadmium began in 1989 as a byproduct of processing of spent nickel-cadmium batteries. In 1995, International Metals Reclamation Co. Inc. expanded its operations by building a dedicated cadmium recycling plant. In 2000, an estimated 13 percent of cadmium consumption in the United States was sourced from recycled cadmium, which is derived mainly from old scrap or, to lesser degree, new scrap. The easiest forms of old scrap to recycle are small spent nickel-cadmium batteries followed by flue dust generated during recycling of galvanized steel and small amounts of alloys that contain cadmium. Most of new scrap is generated during manufacturing processes, such as nickel-cadmium battery production. All other uses of cadmium are in low concentrations and, therefore, difficult to recycle. Consequently, much of this cadmium is dissipated and lost. The amount of cadmium in scrap that was unrecovered in 2000 was estimated to be 2,030 metric tons, and an estimated 285 tons was recovered. Recycling efficiency was estimated to be about 15 percent.

Plachy, Jozef

2003-01-01

204

Method for converting uranium oxides to uranium metal  

DOEpatents

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixtures is then cooled to a temperature less than -100/sup 0/C in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, W.K.

1987-01-01

205

Method for converting uranium oxides to uranium metal  

DOEpatents

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, Walter K. (Norris, TN) [Norris, TN

1988-01-01

206

Managing the disposition of potentially radioactive scrap metal.  

PubMed

In 2002, the National Council on Radiation Protection and Measurements (NCRP) issued Report No. 141, Managing Potentially Radioactive Scrap Metal. The report evaluates management policy and related issues regarding scrap metal generated in regulated facilities that have been under radiological control or have radiological concerns. It has been estimated that more than 9 million metric tons of scrap metal of all types that have been associated with the production or use of radioactive materials will be generated during the coming decades at various facilities across the United States. Currently, disposition of such metal has encountered particular obstacles, primarily because of the lack of a consistent disposition policy, systematic regulatory provisions, and, above all, public understanding. Without clarity in the regulatory passage, much of the scrap metal, including metal that has not been contaminated, could be mischaracterized as low-level radioactive waste, resulting in a costly disposition operation. NCRP Report No. 141 identifies this general category of metal as "potentially radioactive scrap metal" (PRSM) and discusses the viable disposition options for facilitating its management. Because much of the PRSM has been found to contain very low residual radioactivity or even none at all, one consideration is to release such metal outside of the radiological control framework. This would require the development and implementation of a set of strict release standards in the United States that would necessarily be risk-based and supported by a comprehensive management scheme. Developing a policy of this kind, however, would entail the resolution of many issues, not the least of which would be public acceptance, including that of the metal industry, of the possible recycling of PRSM in the general commerce. PMID:17033456

Chen, S Y

2006-11-01

207

Uranium  

SciTech Connect

The two important oxidation states for uranium in natural environments are 4+ and 6+. Compounds containing quadrivalent uranium are insoluble in mildly acidic to alkaline conditions; whereas, those containing the linearly uranyl moiety (O=U=O)2+, are highly soluble and mobile. In solution, UO22+ forms soluble complexes with carbonate, oxalate, and hydroxide; UO22+ is also highly susceptible to adsorption either by organic matter, Fe oxyhydroxides, or precipitation with various anions, such as silicate, vanadate, arsenate, and phosphate. In ground water systems U(VI) is reduced to U(IV) if an effective reductant is present, such as H2S. Other reducing agents may be fossil plants, methane, and transported humic material. Uranium minerals display an extraordinary range structural and chemical variability, resulting from the different chemical conditions under which U minerals are formed.

Grenthe, Ingmar; Buck, Edgar C.; Drozdynski, J.; Fujino, T.; Albrecht-Schmitt, Thomas; Wolf, Steven F.

2006-07-31

208

Managing potentially radioactive scrap metal  

SciTech Connect

The National Council on Radiation Protection and Measurements published NCRP Report No. 141 on November 19, 2002. Contract DE-FG02-98CH10945 provided the sole support for this report titled ''Managing Potentially Radioactive Scrap Metal.'' Some preliminary work supported by the U.S. Environmental Protection Agency that led to an NCRP Letter Report provided some background information for this work. NCRP Report No. 141 provides recommendations on the methodologies and techniques available to the United States for disposing of radioactive, contaminated scrap metals.

None

2002-11-19

209

Recycling light metals from end-of-life vehicle  

NASA Astrophysics Data System (ADS)

The amount of aluminum used in cars and light trucks is growing steadily. However, without new developments in aluminum recycling technologies, sheet from automotive aluminum could eventually flood all current markets for recycled aluminum. This article summarizes the use of light metals and different alloys in transportation applications, the current auto recycling system, and new developments in the sorting of light metals by the metal recycling industry and by Huron Valley Steel Corporation, the world’s largest non-ferrous scrap sorter.

Gesing, A.; Wolanski, R.

2001-11-01

210

Neptunium - Uranium - Plutonium CoExtraction in TBP-based Solvent Extraction Processes for Spent Nuclear Fuel Recycling  

Microsoft Academic Search

The US, through the Global Nuclear Energy Partnership, is currently engaged in efforts aimed at closing the nuclear fuel cycle. Neptunium behavior is important to understand for transuranic recycling because of its complex oxidation chemistry. The Pacific Northwest National Laboratory is investigating neptunium oxidation chemistry in the context of the PUREX process. Neptunium extraction in the PUREX process relies on

S. T. Arm; J. Abrefah; G. J. Lumetta; S. I. Sinkov

2007-01-01

211

Chemical Reclamation of Scrap Rubber.  

National Technical Information Service (NTIS)

A conceptual, commercial-scale plant design was formulated for processing 22,500 t/yr of scrap rubber tires to hydrocarbon fuel gases, oils, petrochemicals (principally ethylene and aromatic liquids), and carbon black. The process is based upon molten sal...

G. C. Frazier S. M. Chan O. L. Culberson J. J. Perona J. W. Larsen

1984-01-01

212

Test der Uranrueckfuehrung im Kernkraftwerk Obrigheim. Abschlussbericht. (Test of recycled uranium in the Obrigheim NPP. Final report).  

National Technical Information Service (NTIS)

Operasting performance and isotopic composition were analyzed for UO(sub 2)-fuel from enriched reprocessed uranium (ERU) by performing post-irradiation examinations at burnups of up to 46 GWd/t(U). The examinations confirm a similar operating performance ...

W. Goll D. Porsch F. Schlemmer D. Jorde U. Braun

1990-01-01

213

Magnesium recycling in the United States in 1998  

USGS Publications Warehouse

As concern for the environment has grown in recent years, the importance of recycling has become more evident. The more materials that are recycled, the fewer natural resources will be consumed and the fewer waste products will end up in landfills, the water, and the air. As one of a series of reports on metals recycling, this report discusses the 1998 flow of magnesium in the United States from extraction through its uses with particular emphasis on recycling. In 1998, the recycling efficiency for magnesium was estimated to be 33 percent--almost 60 percent of the magnesium that was recycled came from new scrap, primarily waste from die-casting operations. The principal source of old scrap was recycled aluminum beverage cans.

Kramer, Deborah A.

2002-01-01

214

Magnesium recycling in the United States in 1998  

USGS Publications Warehouse

As concern for the environment has grown in recent years, the importance of recycling has become more evident. The more materials that are recycled, the fewer natural resources will be consumed and the fewer waste products will end up in landfills, in the water, and in the air. As one of a series of reports on metals recycling, this report discusses the 1998 flow of magnesium from extraction through its uses with particular emphasis on recycling. In 1998, the recycling rate for magnesium was estimated to be 33 percent?almost 60 percent of the magnesium that was recycled came from new scrap, primarily waste from diecasting operations. The principal source of old scrap was recycled aluminum beverage cans.

Kramer, Deborah A.

2001-01-01

215

Radiochronological Age of a Uranium Metal Sample from an Abandoned Facility  

SciTech Connect

A piece of scrap uranium metal bar buried in the dirt floor of an old, abandoned metal rolling mill was analyzed using multi-collector inductively coupled plasma mass spectroscopy (MC-ICP-MS). The mill rolled uranium rods in the 1940s and 1950s. Samples of the contaminated dirt in which the bar was buried were also analyzed. The isotopic composition of uranium in the bar and dirt samples were both the same as natural uranium, though a few samples of dirt also contained recycled uranium; likely a result of contamination with other material rolled at the mill. The time elapsed since the uranium metal bar was last purified can be determined by the in-growth of the isotope {sup 230}Th from the decay of {sup 234}U, assuming that only uranium isotopes were present in the bar after purification. The age of the metal bar was determined to be 61 years at the time of this analysis and corresponds to a purification date of July 1950 {+-} 1.5 years.

Meyers, L A; Williams, R W; Glover, S E; LaMont, S P; Stalcup, A M; Spitz, H B

2012-03-16

216

Effective Technology for Recycling Metal. Proceedings of Two Special Workshops.  

ERIC Educational Resources Information Center

The National Association of Secondary Material Industries (NASMI) and the Bureau of Mines have cooperated to sponsor two technically-oriented workshops related to the role of metals recycling and air pollution control technology. The proceedings of these workshops, "Effective Technology and Research for Scrap Metal Recycling" and "Air Pollution…

National Association of Secondary Material Industries, Inc., New York, NY.

217

A Fundamental Metric for Metal Recycling Applied to Coated Magnesium  

Microsoft Academic Search

A fundamental metric for the assessment of the recyclability and, hence, the sustainability of coated magnesium scrap is presented; this metric combines kinetics and thermodynamics. The recycling process, consisting of thermal decoating and remelting, was studied by thermogravimetry and differential thermal analysis (TG\\/DTA) experiments and thermodynamic simulations. Decoating phenomena are interpreted using kinetic analysis, applying existing reaction models. The derived

C. E. M. Meskers; M. A. Reuter; U. Boin; A. Kvithyld

2008-01-01

218

Recycling light metals: Optimal thermal de-coating  

NASA Astrophysics Data System (ADS)

Thermal de-coating of painted and lacquered scrap is one of the new innovations developed for aluminum recycling. If implemented in all recycling and optimized as suggested in this article, recovery would be improved with considerable economic impact. Generally, contaminated scrap is difficult to recycle. Direct re-melting of coated scrap results in the generation of gaseous emissions, with increased metal oxidation, contamination, and salt flux usage. By thermal de-coating of the scrap these problems are avoided. Thermal de-coating followed by remelting of aluminum scrap is now common practice, while painted magnesium scrap is not currently de-coated and recycled. This article presents observations during heating of the contaminated light metals together with the mass loss, evolved gases, and residue after de-coating in order to give a general description of the de-coating process. It is argued that the main behavior during de-coating may be described as two distinct regimes—scission and combustion—regardless of metal substrate and coating. Monitoring the combustion regime should assure optimum de-coating.

Kvithyld, Anne; Meskers, C. E. M.; Gaal, Sean; Reuter, Markus; Engh, Thorvald Abel

2008-08-01

219

Scrap metals industry perspective on radioactive materials.  

PubMed

With more than 80 reported/confirmed accidental melts worldwide since 1983 and still counting, potential contamination by radioactive materials remains as a major concern among recycled scrap and steel companies. Some of these events were catastrophic and have cost the industry millions of dollars in business and, at the same time, resulted in declining consumer confidence. It is also known that more events with confirmed radioactive contamination have occurred that involve mining of old steel slag and skull dumps. Consequently, the steel industry has since undergone massive changes that incurred unprecedented expenses through the installation of radiation monitoring systems in hopes of preventing another accidental melt. Despite such extraordinary efforts, accidental melts continue to occur and plague the industry. One recent reported/confirmed event occurred in the Republic of China in 2004, causing the usual lengthy shutdown for expensive decontamination efforts before the steel mill could resume operations. With this perspective in mind, the metal industry has a long-standing opposition to the release of radioactive materials of any kind to commerce for fear of contamination and the potential consequences. PMID:17033460

Turner, Ray

2006-11-01

220

Advanced technologies for decomtamination and conversion of scrap metal  

SciTech Connect

The Department of Energy (DOE) faces the task of decommissioning much of the vast US weapons complex. One challenge of this effort includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for cleanup of contaminated sites and facilities. Recycling helps to offset the cost of decommissioning and saves valuable space in the waste disposal facilities. It also reduces the amount of environmental effects associated with mining new metals. Work on this project is geared toward finding decontamination and/or recycling alternatives for the RSM contained in the decommissioned gaseous diffusion plants including approximately 40,000 tons of nickel. The nickel is contaminated with Technetium-99, and is difficult to remove using traditional decontamination technologies. The project, titled ``Advanced Technologies for Decontamination and Conversion of Scrap Metal'' was proposed as a four phase project. Phase 1 and 2 are complete and Phase 3 will complete May 31, 1999. Stainless steel made from contaminated nickel barrier was successfully produced in Phase 1. An economic evaluation was performed and a market study of potential products from the recycled metal was completed. Inducto-slag refining, after extensive testing, was eliminated as an alternative to remove technetium contamination from nickel. Phase 2 included successful lab scale and pilot scale demonstrations of electrorefining to separate technetium from nickel. This effort included a survey of available technologies to detect technetium in volumetrically contaminated metals. A new process to make sanitary drums from RSM was developed and implemented. Phase 3 included a full scale demonstration of electrorefining, an evaluation of electro-refining alternatives including direct dissolution, melting of nickel into anodes, a laser cutting demonstration, an investigation of commercial markets for RSM, and refinement of methods to quantify isotopic elements.

Valerie MacNair; Steve Sarten; Thomas Muth; Brajendra Mishra

1999-05-27

221

Removal of copper from ferrous scrap  

DOEpatents

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Blander, Milton (12833 S. 82nd Ct., Palos Park, IL 60464); Sinha, Shome N. (5748 Drexel, 2A, Chicago, IL 60637)

1990-01-01

222

Removal of copper from ferrous scrap  

DOEpatents

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Blander, M.; Sinha, S.N.

1987-07-30

223

Removal of copper from ferrous scrap  

DOEpatents

A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

Blander, M.; Sinha, S.N.

1990-05-15

224

A review of the UK metals recycling industry.  

PubMed

This paper reviews the volatile nature of the price of recycled metals over the past decade and examines legislative and fiscal drivers that have affected the industry. Results from this study have shown that the UK scrap metals markets are presently seeing some of the lowest scrap prices for nearly a decade for both ferrous and non-ferrous metals, in many cases halving in value in less than a year. Scrap metals and other recycled materials prices were high in 1994-96, which have since fallen back to more traditional low levels. World recessions and the steady decline of the UK manufacturing and engineering sectors have effected prices. With tougher new Government legislation, such as the Climate Change Levy and the proposed End of Life Vehicles Directive, small and medium sized scrap merchants are finding it increasingly difficult to compete. PMID:12498482

Emery, Andrew; Williams, Keith P; Griffiths, Anthony J

2002-10-01

225

Recycle Experience of Dismantled Cask Handling Crane by Surface Removal Sampling at Kori No. 1.  

National Technical Information Service (NTIS)

The Kori No.1, which began operation in 1978, replaced its cask handling crane in 2000. To prove the safety of recycling and reuse of crane scrap, a particular calculation method for surface contamination was used. Because surface radioactive contaminatio...

K. D. Kim C. Y. Baeg J. K. Son H. S. Kim J. H. Ha M. J. Song

2002-01-01

226

Recycling of wood–plastic composites prepared from poly(vinyl chloride) and wood flour  

Microsoft Academic Search

This study emphasizes on closed-loop recycling of wood plastic composite (WPC) which consists of two parts. The first part concentrates on re-processing industrial scrap of WPC profiles and its mixture with freshfeed. The ratio of WPC scrap:freshfeed at 30:70 was found to be the most appropriate. The second part involves recycling the WPC profiles up to seven passes. Reductions of

Nawadon Petchwattana; Sirijutaratana Covavisaruch; Jakkid Sanetuntikul

227

What do we know about metal recycling rates?  

USGS Publications Warehouse

The recycling of metals is widely viewed as a fruitful sustainability strategy, but little information is available on the degree to which recycling is actually taking place. This article provides an overview on the current knowledge of recycling rates for 60 metals. We propose various recycling metrics, discuss relevant aspects of recycling processes, and present current estimates on global end-of-life recycling rates (EOL-RR; i.e., the percentage of a metal in discards that is actually recycled), recycled content (RC), and old scrap ratios (OSRs; i.e., the share of old scrap in the total scrap flow). Because of increases in metal use over time and long metal in-use lifetimes, many RC values are low and will remain so for the foreseeable future. Because of relatively low efficiencies in the collection and processing of most discarded products, inherent limitations in recycling processes, and the fact that primary material is often relatively abundant and low-cost (which thereby keeps down the price of scrap), many EOL-RRs are very low: Only for 18 metals (silver, aluminum, gold, cobalt, chromium, copper, iron, manganese, niobium, nickel, lead, palladium, platinum, rhenium, rhodium, tin, titanium, and zinc) is the EOL-RR above 50% at present. Only for niobium, lead, and ruthenium is the RC above 50%, although 16 metals are in the 25% to 50% range. Thirteen metals have an OSR greater than 50%. These estimates may be used in considerations of whether recycling efficiencies can be improved; which metric could best encourage improved effectiveness in recycling; and an improved understanding of the dependence of recycling on economics, technology, and other factors. ?? 2011 by Yale University.

Graedel, T. E.; Allwood, J.; Birat, J. -P.; Buchert, M.; Hageluken, C.; Reck, B. K.; Sibley, S. F.; Sonnemann, G.

2011-01-01

228

Comparisons of four categories of waste recycling in China's paper industry based on physical input-output life-cycle assessment model  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Using crop straws and wood wastes for paper production should be promoted. Black-Right-Pointing-Pointer Bagasse and textile waste recycling should be properly limited. Black-Right-Pointing-Pointer Imports of scrap paper should be encouraged. Black-Right-Pointing-Pointer Sensitivity analysis, uncertainties and policy implications are discussed. - Abstract: Waste recycling for paper production is an important component of waste management. This study constructs a physical input-output life-cycle assessment (PIO-LCA) model. The PIO-LCA model is used to investigate environmental impacts of four categories of waste recycling in China's paper industry: crop straws, bagasse, textile wastes and scrap paper. Crop straw recycling and wood utilization for paper production have small total intensity of environmental impacts. Moreover, environmental impacts reduction of crop straw recycling and wood utilization benefits the most from technology development. Thus, using crop straws and wood (including wood wastes) for paper production should be promoted. Technology development has small effects on environmental impacts reduction of bagasse recycling, textile waste recycling and scrap paper recycling. In addition, bagasse recycling and textile waste recycling have big total intensity of environmental impacts. Thus, the development of bagasse recycling and textile waste recycling should be properly limited. Other pathways for reusing bagasse and textile wastes should be explored and evaluated. Moreover, imports of scrap paper should be encouraged to reduce large indirect impacts of scrap paper recycling on domestic environment.

Liang Sai [School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084 (China); Zhang, Tianzhu, E-mail: zhangtz@mail.tsinghua.edu.cn [School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084 (China); Xu Yijian [School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084 (China); China Academy of Urban Planning and Design, Beijing 100037 (China)

2012-03-15

229

PYROLYSIS AND COMBUSTION OF SCRAP TIRE  

Microsoft Academic Search

In this paper a literature review of both pyrolysis and combustion processes of scrap tires is presented. The work reports, the characteristics of materials, methods, effect of various process parameters, kinetic modelling applied to the pyrolysis and combustion of tires, characteristics of the products and emissions. From the published works results that scrap tire rubber consists of about 60 wt.%

M. Juma; Z. Kore?ová; J. Annus

230

Kinetic modeling of pyrolysis of scrap tires  

Microsoft Academic Search

The disposal of used tires is a major environmental problem. With increasing interest on recovery of wastes, pyrolysis is considered as an alternative process for recovering some of the value in scrap tires. An accurate kinetic model is required to predict product yields during thermal or catalytic pyrolysis of scrap tires. Pyrolysis products contain a variety of hydrocarbons over a

Golshan Mazloom; Fatola Farhadi; Farhad Khorasheh

2009-01-01

231

The Pyrolysis of Scrap Tire with Lignite  

Microsoft Academic Search

Mustafa Kemal Pasa lignite obtained from the Mustafa Kemal Pasa region of Bursa, Turkey was subjected to pyrolysis with scrap tires. Effects of the pyrolysis conditions, such as temperature, weight percent of the scrap tires in the blends, and synergism on the results, was investigated. Tars obtained at the end of pyrolysis were characterized by Fourier transform infrared spectroscopy and

P. Acar; A. Sina?; Z. Misirlio?lu; M. Canel

2011-01-01

232

Evaluation for mulching use of Japanese cedar wooden chips made from scrapped housing timber  

NASA Astrophysics Data System (ADS)

Wooden timber from scrapped housing is not sufficiently recycled. Since timber made from Japanese cedar has been used in Towada, Aomori Prefecture for housing construction, we investigated the mulching method of Japanese cedar wooden chips made from scrapped housing timber. The main recycled chip diameter was comprised of two classes: 4.76 to 10 mm and 10 to 19 mm. They contained negligible amounts of heavy metals. By using 10 cm thick mulching chips, the growth of weeds was controlled due to a shading effect. It also contributed to making soil temperature and moisture stable, which are preferable for tree plantations at parks, orchards, and roadsides. Therefore, we concluded that Japanese cedar wooden chips are available for mulching when they were applied with a 10 cm mulching chips.

Okada, Hiroki; Baba, Mitsuhisa; Suzuki, Yoshiko; Sugiura, Toshihiro; Kobayashi, Hiroshi

233

From Trash to Treasure: Recycling Scrap Metal into Steel  

ERIC Educational Resources Information Center

Trash is having a global impact not only on land, but at sea--making its way into the ocean and creating large islands of floating debris. One such island is The Great Pacific Trash Patch, which is located in the North Pacific and is made up of floating trash and debris that is spread out in an area as much as one and a half times the size of the…

Cantu, Diana

2011-01-01

234

Using Established Regulations to Recycle Contaminated Metals  

SciTech Connect

DOE restoration projects require acceptable standards for processing volumetrically contaminated metals: • NRC has no regulations addressing recycling of scrap metal containing residual volumetric radioactivity. • DOE is currently restricting outside radioactive scrap metal sales; however, previous Fernald and Ohio State clean-ups have released metals with measurable levels of radioactivity into the open market. • Public sensitivity to the subject of non-governmental disposal of materials with residual radioactivity was heightened with the Below Regulatory Concern (BRC) issue. There are no clear guidelines for free release of volumetrically contaminated material.

Loewen, Eric Paul

2000-09-01

235

Closed loop recycling of lead/acid batteries  

NASA Astrophysics Data System (ADS)

The traditional lead/acid battery is a recycleable product, irrespective whether it is of an automotive, traction or standby design. The product benefits from the traditional lead metallurgy that has been developed for both primary (mines) and secondary (recycling) smelting. Secondary smelting accounts for 60% of total lead production in Europe, and this market lead the most effectively metal. In secondary smelters, scrapped batteries are crushed and smelted. The polypropylene from the boxes is recycled to produce secondary plastic for battery, automotive, or other miscellaneous uses. The lead metal is refined to be re-used in the battery industry. The acid is retreated. Recycling requires a collection network. The lead/acid battery benefits from the traditional collection network that has been established for scrap-iron and non-ferrous metal scrap. In Western Europe, the recycling rate for scrapped batteries is estimated to be 80 to 90%. All participants in the battery recycling loop agree that the process must be a clean cycle for it to be credible. The collection organization is improving the quality of storage and transportation, especially with regard to the acid that can only be neutralized in correctly-controlled facilities, generally located at the smelters. The smelters themselves tend, through local regulations, to run at the optimum level of protection of the environment.

Bied-Charreton, B.

236

Predictions of scenarios for the consumption of scrap metal in ferrous metallurgy  

Microsoft Academic Search

This article analyzes the development of a method for using secondary sources of iron in ferrous metallurgy and examines the\\u000a main models that have been created in the EC nations and Japan in recent decades to optimize the recycling of dormant scrap.\\u000a Various national and regional models now exist to describe the production and consumption of steel products. Optimizing the

O. V. Golubev; A. S. Korotchenko; P. I. Chernousov

2011-01-01

237

Guidance document for multi-facility recycle\\/reuse\\/free release of metals from radiological control areas  

Microsoft Academic Search

Approximately 15% of the Low Level Waste (LLW) produced at Los Alamos consists of scrap metal equipment and materials. The majority of this material is produced by decommissioning and modification of existing facilities. To address this waste stream, Los Alamos has developed a scrap metal recycling program that is operated by the Environmental Stewardship Office to minimize the amount of

S. Gogol; T. Starke

1997-01-01

238

Public Health Assessment for Scorpio Recycling, Incorporated Candelaria Ward, Toa Baja Municipality, Puerto Rico, EPA Facility ID: PRD987376662.  

National Technical Information Service (NTIS)

The Scorpio Recycling, Inc. (SRI) site is an active scrap metal yard located on State Road No. 2, Candelaria Ward, Toa Baja, and Puerto Rico. Part of the property was previously used as a battery salvage area where batteries were dismantled for scrap. SRI...

2004-01-01

239

Modeling of Alternative Compositions of Recycled Wrought Aluminum Alloys  

NASA Astrophysics Data System (ADS)

Nowadays, a significant part of postconsumed wrought aluminum scrap is still used for the production of comparatively cheaper cast alloys, in that way losing an important part of the potential added value. The share of postconsumed scrap in wrought aluminum alloys could be increased either by sorting to fractions with the required chemical composition and/or by broadening the standard compositional tolerance limits of alloying elements. The first solution requires hand or automatic sorting of postconsumed scrap as alloys or groups of alloys to the degree of separation sufficient to enable the blending of standard compositions of wrought alloys; the second solution is much more radical, predicting changes in the existing standards for wrought aluminum alloys toward nonstandard alloys but yet having properties acceptable for customers. In this case, the degree of separation of incoming postconsumed scrap required is much less demanding. The model presented in this work enables the design of optimal (standard and nonstandard recycling-friendly) compositions and properties of wrought aluminum alloys with significantly increased amounts of postconsumed scrap. The following two routes were modeled in detail: (I) the blending of standard and nonstandard compositions of wrought aluminum alloys starting from postconsumed aluminum scrap sorted to various degrees simulated by the model and (II) changing the initial standard composition of wrought aluminum alloys to nonstandard "recycling-friendly" ones, with broader concentration tolerance limits of alloying elements and without influencing the selected alloy properties, specified in advance. The applied algorithms were found to be very useful in the industrial design of both procedures: (I) the computation of the required chemical composition of the scrap streams obtained by sorting (or, in other words, the postconsumed scrap sorting level), necessary for achieving the standard wrought alloy composition and (II) the transformation of standard to nonstandard (recycling-friendly) compositions with the key alloy properties (e.g., tensile strength and elongation) remaining the same.

Kevorkijan, Varužan

2013-08-01

240

Recycling, Inc.  

ERIC Educational Resources Information Center

Suggestions for creating a successful office recycling system are enumerated from start up plans to waste reduction and paper recycling. Contact information for recycling equipment, potential buyers of recycled materials, recycled products for purchase, and ideas for promotion and education of staff are included. (MCO)

Martin, Amy

1992-01-01

241

Recycling: General studies. (Latest citations from the NTIS Bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning the processes, techniques, and benefits of recycling. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Also included are citations on recycling of waste paper fibers and rubber wastes for the production of new products. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries are considered. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1994-11-01

242

Recycling: General studies. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning the processes, techniques, and benefits of recycling. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Also included are citations on recycling of waste paper fibers and rubber wastes for the production of new products. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries are considered. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-12-01

243

Recycling: General studies. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning the processes, techniques, and benefits of recycling. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Also included are citations on recycling of waste paper fibers and rubber wastes for the production of new products. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries are considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1995-12-01

244

Recycling asphalt pavements. January 1975-January 1990 (a Bibliography from the COMPENDEX data base). Report for January 1975-January 1990  

SciTech Connect

This bibliography contains citations concerning the recycling of asphalt-containing pavement materials. Articles include examples of recycling asphalt pavements; performance testing of recycled paving; methods including cold in-place, cold off-site, and hot-mix recycling; additives in recycled pavement for better performance; use of scrap roofing asphalt in conjunction with recycled paving; economics of recycling; process design; and process variables. Recycling of other materials is considered in related bibliographies. (Contains 130 citations fully indexed and including a title list.)

Not Available

1990-03-01

245

AIR EMISSIONS FROM SCRAP TIRE COMBUSTION  

EPA Science Inventory

The report discusses air emissions from two types of scrap tire combustion: uncontrolled and controlled. Uncontrolled sources are open tire fires, which produce many unhealthful products of incomplete combustion and release them directly into the atmosphere. Controlled combustion...

246

Plutonium scrap multiplicity counter operation manual  

Microsoft Academic Search

This manual describes the design features and performance and operating characteristics for the plutonium scrap multiplicity counter (PSMC). It counts neutron multiplicities to quantitatively assay plutonium in many forms, including impure scrap and waste. Monte Carlo neutronic calculations were used to design the high-efficiency (55%) detector using eighty ³He tubes in a high-density polyethylene body. The new multiplicity shift-register electronics

H. O. Menlove; J. Baca; M. S. Krick; K. E. Kroncke; D. G. Langner

1993-01-01

247

Plutonium scrap multiplicity counter operation manual  

Microsoft Academic Search

This manual describes the design features and performance and operating characteristics for the plutonium scrap multiplicity counter (PSMC). It counts neutron multiplicities to quantitatively assay plutonium in many forms, including impure scrap and waste. Monte Carlo neutronic calculations were used to design the high-efficiency (55%) detector using eighty [sup 3]He tubes in a high-density polyethylene body. The new multiplicity shift-register

H. O. Menlove; J. Baca; M. S. Krick; K. E. Kroncke; D. G. Langner

1993-01-01

248

Responsible recycling  

SciTech Connect

The issues that affect the recycling of lead-acid batteries and the challenges that this issue brings to both the lead industry and to the battery manufacturers are covered. Topics include the lead market (its size and structure), the economic constraints on the recycling system, recycling rates for batteries, the technology of recycling, and future considerations.

Pugh, A. (Britannia Refined Metals, Northfleet (United Kingdom))

1993-05-01

249

Carbon reduction in uranium alloys utilizing hafnium additions  

Microsoft Academic Search

With increasing environmental concerns regarding the handling and storage of uranium waste, recycling previously used material is becoming exceedingly more important. Carbon is one of the primary trace impurities that builds up in uranium with repeated use. The goal of this study is to reduce carbon in recycled uranium during the casting process to carbon levels associated with virgin uranium

G. Mackiewicz-Ludtka; W. C. Pullen; C. A. Henderson; W. Chu; M. W. Wendel

1990-01-01

250

Titanium recycling in the United States in 2004, chap. Y of Sibley, S.F., ed., Flow studies for recycling metal commodities in the United States  

USGS Publications Warehouse

As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the titanium metal fraction of the titanium economy, which generates and uses titanium metal scrap in its operations. Data for 2004 were selected to demonstrate the titanium flows associated with these operations. This report includes a description of titanium metal supply and demand in the United States to illustrate the extent of titanium recycling and to identify recycling trends. In 2004, U.S. apparent consumption of titanium metal (contained in various titanium-bearing products) was 45,000 metric tons (t) of titanium, which was distributed as follows: 25,000 t of titanium recovered as new scrap, 9,000 t of titanium as titanium metal and titanium alloy products delivered to the U.S. titanium products reservoir, 7,000 t of titanium consumed by steelmaking and other industries, and 4,000 t of titanium contained in unwrought and wrought products exported. Titanium recycling is concentrated within the titanium metals sector of the total titanium market. The titanium market is otherwise dominated by pigment (titanium oxide) products, which generate dissipative losses instead of recyclable scrap. In 2004, scrap (predominantly new scrap) was the source of roughly 54 percent of the titanium metal content of U.S.-produced titanium metal products.

Goonan, Thomas G.

2010-01-01

251

THE ROLE OF HYDROMETALLURGY IN THE RECYCLING OF ZINC, COPPER AND LEAD  

Microsoft Academic Search

Metals recycling remains an important industrial activity for both economic and environmental reasons, and the role of hydrometallurgical processing in the recycling of zinc, copper and lead is discussed. Hydrometallurgical processes are being developed to leach zinc from galvanized steel scrap prior to remelting, and both alkaline and acid leaching technologies are being evaluated to eliminate zinc from electric arc

252

The DOE`s radioactively contaminated metal recycling: The policy and its implementation  

Microsoft Academic Search

Millions of tons of potentially recoverable materials have accumulated over the years at U.S. DOE sites and facilities now undergrowing environmental restoration. These materials include thousands of tones of scrap metals, both radioactively contaminated and not. This article discusses the DOE`s policy on contaminated metal recycling and its implementation in the following topic areas: the recycling policy concept; an innovative

S. Warren; E. Rizkalla

1997-01-01

253

End-of-life vehicle recycling : state of the art of resource recovery from shredder residue  

Microsoft Academic Search

Each year, more than 25 million vehicles reach the end of their service life throughout the world, and this number is rising rapidly because the number of vehicles on the roads is rapidly increasing. In the United States, more than 95% of the 10-15 million scrapped vehicles annually enter a comprehensive recycling infrastructure that includes auto parts recyclers\\/dismantlers, remanufacturers, and

B. J. Jody; E. J. Daniels; C. M. Duranceau; J. A. Pomykala; J. S. Spangenberger

2011-01-01

254

Recycled materials in asphalt pavements. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of asphalt pavement materials, and the use of other recycled materials to manufacture asphalt pavement. Articles discuss methods used for recycling bituminous pavement including hot-mix and cold-mix. Materials used to improve recycled pavement, and recycled materials used in asphalt pavement include latexes, rubber scrap such as tires, glass shards, concretes, dusts, waste oils, roofing wastes, sulfur, and metal refining sludges. Testing and evaluation of recycled pavements both in laboratories and in test cases are considered. (Contains a minimum of 160 citations and includes a subject term index and title list.)

Not Available

1994-05-01

255

A Fundamental Metric for Metal Recycling Applied to Coated Magnesium  

Microsoft Academic Search

A fundamental metric for the assessment of the recyclability and, hence, the sustainability of coated magnesium scrap is presented;\\u000a this metric combines kinetics and thermodynamics. The recycling process, consisting of thermal decoating and remelting, was\\u000a studied by thermogravimetry and differential thermal analysis (TG\\/DTA) experiments and thermodynamic simulations. Decoating\\u000a phenomena are interpreted using kinetic analysis, applying existing reaction models. The derived

C. E. M. Meskers; M. A. Reuter; U. Boin; A. Kvithyld

2008-01-01

256

Automobile shredder residue: Process developments for recovery of recyclable constituents  

SciTech Connect

The objectives of this paper are threefold: (1) to briefly outline the structure of the automobile shredder industry as a supplier of ferrous scrap, (2) to review the previous research that has been conducted for recycling automobile shredder residue (ASR), and (3) to present the results and implications of the research being conducted at ANL on the development of a process for the selective recovery and recycling of the thermoplastics content of ASR. 15 refs., 5 figs.

Daniels, E.J.; Jody, B.J.; Bonsignore, P.V.; Shoemaker, E.L.

1990-01-01

257

World War II and the birth of modern recycling  

SciTech Connect

The concept of reusing waste materials had been around for many decades before the war, but few municipalities collected recyclables in an organized, controlled fashion. Though today`s thriving recycling industry seems brand new, its roots run far deeper to a time when both industry and citizens were called upon to help save the world. With so many goods rationed during World War II, hundreds of collectors would buy scrap metal and textiles and resell them back to mills.

Woods, R.; Peterson, C.

1995-04-01

258

Improving metal returns and eco-efficiency in electronics recycling - a holistic approach for interface optimisation between pre-processing and integrated metals smelting and refining  

Microsoft Academic Search

The efficient recovery of precious and special metals from electronic scrap has significant benefits - economically, environmentally, but also under a resource conservation aspect. The yields of these metals could be substantially improved by higher collection rates, less scrap exports to regions with insufficient recycling structures, and by interface optimisation, as pointed out in this document

Christian Hagelüken

2006-01-01

259

Uranium and Thorium  

ERIC Educational Resources Information Center

The results of President Carter's policy on non-proliferation of nuclear weapons are expected to slow the growth rate in energy consumption, put the development of the breeder reactor in question, halt plans to reprocess and recycle uranium and plutonium, and expand facilities to supply enriched uranium. (Author/MA)

Finch, Warren I.

1978-01-01

260

Silver Recycling in the United States in 2000  

USGS Publications Warehouse

In 2000, the global silver supply deficit (the difference between mine and scrap supply and silver demand) was more than 3,000 metric tons. U.S. silver demand for photographic applications alone was nearly equal to annual U.S. silver production. Until 1968, the U.S. silver deficit was filled by withdrawals from the U.S. Treasury reserves. In 2000, the deficit was filled by destocking, imports, and recycling. Photographic wastes, spent catalysts, and electronic scrap are the major sources of materials for silver recycling. Nearly 1,800 tons of silver contained in these materials were available for recycling in 2000. Other recyclable silver-bearing materials include dental alloys, jewelry, and silverware. In 2000, an estimated 1,700 tons of silver were recovered from secondary sources in the United States. The U.S. recycling efficiency for old scrap was calculated to have been 97 percent in 2000; the recycling rate was estimated to be 32 percent.

Hilliard, Henry E.

2003-01-01

261

Silver recycling in the United States in 2000  

USGS Publications Warehouse

In 2000, the global silver supply deficit (the difference between mine and scrap supply and silver demand) was more than 3,000 metric tons. U.S. silver demand for photographic applications alone was nearly equal to annual U.S. silver production. Until 1968, the U.S. silver deficit was filled by withdrawals from the U.S. Treasury reserves. In 2000, the deficit was filled by destocking, imports, and recycling. Photographic wastes, spent catalysts, and electronic scrap are the major sources of materials for silver recycling. Nearly 1,800 metric tons of silver contained in these materials were available for recycling in 2000. Other recyclable silver-bearing materials include dental alloys, jewelry, and silverware. In 2000, an estimated 1,700 tons of silver were recovered from secondary sources in the United States. The U.S. recycling efficiency for old scrap was calculated to have been 97 percent in 2000; the recycling rate was estimated to be 32 percent.

Hilliard, Henry E.

2003-01-01

262

Metal recycling experience at Los Alamos National Laboratory. Reuse, release, and recycle of metals from radiological control areas``  

Microsoft Academic Search

Approximately 15% of the Low-Level Waste (LLW) produced at Los Alamos consists of scrap metal equipment and materials. The majority of this material is produced by decommissioning and the modification of existing facilities. To reduce this waste stream, Department of Energy Headquarters, EM-77 Office, sponsored the Reuse, Recycle, and Release of Metals from Radiological Control Areas High Return on Investment

Gogol

1997-01-01

263

Recycling: General studies. January 1987-November 1991 (Citations from the NTIS Data-Base). Rept. for Jan 87-Nov 91  

SciTech Connect

The bibliography contains citations concerning the processes, techniques, and benefits of recycling. The recycling processes for aluminum, chromium, nickel, cobalt, lead, copper, and precious metals scrap are discussed. Also included are citations on recycling of waste paper fibers and rubber wastes for the production of new products. Recycling in the jewelry, electronics, milling, beverage, automotive, and aircraft industries are considered. (Contains 177 citations with title list and subject index.)

Not Available

1991-10-01

264

Comparing urban solid waste recycling from the viewpoint of urban metabolism based on physical input-output model: A case of Suzhou in China  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Impacts of solid waste recycling on Suzhou's urban metabolism in 2015 are analyzed. Black-Right-Pointing-Pointer Sludge recycling for biogas is regarded as an accepted method. Black-Right-Pointing-Pointer Technical levels of reusing scrap tires and food wastes should be improved. Black-Right-Pointing-Pointer Other fly ash utilization methods should be exploited. Black-Right-Pointing-Pointer Secondary wastes from reusing food wastes and sludge should be concerned. - Abstract: Investigating impacts of urban solid waste recycling on urban metabolism contributes to sustainable urban solid waste management and urban sustainability. Using a physical input-output model and scenario analysis, urban metabolism of Suzhou in 2015 is predicted and impacts of four categories of solid waste recycling on urban metabolism are illustrated: scrap tire recycling, food waste recycling, fly ash recycling and sludge recycling. Sludge recycling has positive effects on reducing all material flows. Thus, sludge recycling for biogas is regarded as an accepted method. Moreover, technical levels of scrap tire recycling and food waste recycling should be improved to produce positive effects on reducing more material flows. Fly ash recycling for cement production has negative effects on reducing all material flows except solid wastes. Thus, other fly ash utilization methods should be exploited. In addition, the utilization and treatment of secondary wastes from food waste recycling and sludge recycling should be concerned.

Liang Sai, E-mail: liangsai09@gmail.com [School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084 (China); Zhang Tianzhu, E-mail: zhangtz@mail.tsinghua.edu.cn [School of Environment, State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084 (China)

2012-01-15

265

Price and volatility transmission between primary and scrap metal markets  

Microsoft Academic Search

The relationship between primary and scrap prices has been hypothesized for the most part as unidirectional, characterized by spillovers from primary to scrap prices. The purpose of this study is to evaluate empirically the dynamic interactions between primary and scrap metal prices through multivariate time series methods. In addition, the study expands the investigation at the level of volatility transmission,

Irene M. Xiarchos; Jerald J. Fletcher

2009-01-01

266

Recycle City  

NSDL National Science Digital Library

Recycle City contains an interactive city map that demonstrates how residents of every section of the city, formerly Dumptown, have recycled, reduced, and reused waste to turn their town around. There is a Dumptown Game with a Control Center to monitor displays while Dumptown changes as waste reduction programs are put in place. Students can create their own Recycle City scavenger hunt or go to the Activities area and see other ways to put Recycle City to use to help protect the environment.

1997-01-01

267

Hanford recycling.  

National Technical Information Service (NTIS)

This paper is a study of the past and present recycling efforts on the Hanford site and options for future improvements in the recycling program. Until 1996, recycling goals were voluntarily set by the waste generators: this year, DOE has imposed goals fo...

I. M. Leonard

1996-01-01

268

RECYCLING TODAY  

NSDL National Science Digital Library

We have probably heard of recycling but what is it really and why is it so improtant to do? Please answer the questions below as well as visiting the different websites to explore what recycling really is. Form groups of 4 and explore the following websites as well as answer the questions which follow. The first website is of Recycle City where you will be exploring the City and how they recycle. Recyle City Why Recycling is Important Now please answer the following questions on paper. 1. What are the 3 R's? Explain in further ...

Smith, Miss

2010-12-03

269

Radioactive scrap metal decontamination technology assessment report.  

National Technical Information Service (NTIS)

Within the DOE complex there exists a tremendous quantity of radioactive scrap metal. As an example, it is estimated that within the gaseous diffusion plants there exists in excess of 700,000 tons of contaminated stainless steel. At present, valuable mate...

J. M. Buckentin B. K. Damkroger M. E. Schlienger

1996-01-01

270

Selenium Recycling in the United States in 2004  

USGS Publications Warehouse

The vast majority of selenium consumption in the United States is in dissipative uses, such as alloys, animal feeds, fertilizers, glass decolorizer, and pigments. The nondissipative use as a photoreceptor for xerographic copiers is declining. As a result of a lack of a substantial supply of selenium-containing scrap, there are no longer selenium recycling facilities in the United States. Selenium-containing materials collected for recycling, primarily selenium-containing photocopier drums, are exported for processing in other countries. Of the estimated 350 metric tons (t) of selenium products that went to the U.S. market in 2004, an estimated 300 t went to dissipative uses. An estimated 4 t was recovered from old scrap and exported for recycling.

George, Micheal W.; Wagner, Lorie A.

2009-01-01

271

Recycling plastics and polymeric wastes. October 1976-November 1989 (Citations from the COMPENDEX data base). Report for October 1976-November 1989  

SciTech Connect

This bibliography contains citations concerning the recycling and uses of plastic and polymeric scraps and wastes. Topics include communition or grinding of scrap, degradation by heat or chemical reaction, compatibility of various plastics with one another, sorting problems, physical properties of reprocessed materials, economics, public awareness, waste minimization, waste re-use, and foreign experience in plastics recycling. New products made from recycled materials, and products expressly made to be recyclable are also discussed. (Contains 347 citations fully indexed and including a title list.)

Not Available

1989-12-01

272

White goods recycling in the United States: Economic and technical issues in recovering, reclaiming, and reusing nonmetallic materials  

Microsoft Academic Search

Obsolete white goods (appliances such as refrigerators, freezers, washers, dryers, ranges, dishwashers, water heaters, dehumidifiers, and air conditioners) contain significant quantities of recyclable materials, but because of economic and environmental concerns, only limited quantities of these scrap materials are currently being recycled. Appliances are manufactured from a mix of materials, such as metals, polymers, foam, and fiberglass; metals represent more

D. E. Karvelas; B. J. Jody; E. J. Daniels

1995-01-01

273

Validation of the RESRAD-RECYCLE computer code.  

SciTech Connect

The RESRAD-RECYCLE computer code was developed by Argonne National Laboratory under the sponsorship of the U.S. Department of Energy. It was designed to analyze potential radiation exposures resulting from the reuse and recycling of radioactively contaminated scrap metal and equipment. It was one of two codes selected in an international model validation study concerning recycling of radioactively contaminated metals. In the validation study, dose measurements at various stages of melting a spent nuclear fuel rack at Studsvik RadWaste AB, Sweden, were collected and compared with modeling results. The comparison shows that the RESRAD-RECYCLE results agree fairly well with the measurement data. Among the scenarios considered, dose results and measurement data agree within a factor of 6. Discrepancies may be explained by the geometrical limitation of the RESRAD-RECYCLE's external exposure model, the dynamic nature of the recycling activities, and inaccuracy in the input parameter values used in dose calculations.

Cheng, J.-J.; Yu, C.; Williams, W. A.; Murphie, W.

2002-02-01

274

Process for continuous production of metallic uranium and uranium alloys  

DOEpatents

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO.sub.3), or any other substantially stable uranium oxide, to form the uranium dioxide (UO.sub.2). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl.sub.4), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation.

Hayden, Jr., Howard W. (Oakridge, TN); Horton, James A. (Livermore, CA); Elliott, Guy R. B. (Los Alamos, NM)

1995-01-01

275

Process for continuous production of metallic uranium and uranium alloys  

DOEpatents

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO{sub 3}), or any other substantially stable uranium oxide, to form the uranium dioxide (UO{sub 2}). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl{sub 4}), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation. 4 figs.

Hayden, H.W. Jr.; Horton, J.A.; Elliott, G.R.B.

1995-06-06

276

Transportable calorimeter measurements of highly enriched uranium  

Microsoft Academic Search

A sensitive calorimeter has been combined with a small temperature-controlled water bath to compose a transportable system that is capable of measuring multikilogram quantities of highly enriched uranium (HEU). The sample chamber size, 5 in. in diameter by 10 in. high, is large enough to hold sufficient HEU metal or high-grade scrap to provide a measurable thermal signal. Calorimetric measurements

C. Rudy; D. S. Bracken; P. Staples; L. Carrillo

1997-01-01

277

End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.  

SciTech Connect

Each year, more than 50 million vehicles reach the end of their service life throughout the world. More than 95% of these vehicles enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, about 75% of automotive materials are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobiles, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials (about 25% of the weight of the vehicle)--commonly called shredder residue--is disposed of in landfills. Over the past 10 to 15 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles (ELVs), including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has focused on developing technology to recover materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lighter-weight materials--primarily polymers and polymer composites--will be used in manufacturing these vehicles. These materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems at end-of-life. Argonne National Laboratory (Argonne), in cooperation with the Vehicle Recycling Partnership (VRP) and the American Plastics Council (APC), is working to develop technology for recycling materials from shredder residue. Several other organizations worldwide are also working on developing technology for recycling shredder residue. Without a commercially viable shredder industry, our nation may face greater environmental challenges and a decreased supply of quality scrap and be forced to turn to primary ores for the production of finished metals. This document presents a review of the state of the art in shredder residue recycling. Available technologies and emerging technologies for the recycling of materials from shredder residue are discussed.

Jody, B. J.; Daniels, E. J.; Energy Systems

2007-03-21

278

Reductive denitrification of nitrate by scrap iron filings*  

PubMed Central

Reduction of nitrate by zero-valent iron is a highly exergonic reaction that has long been known to occur. Use of scrap iron filings (SIF) as the PRB (Permeable Reactive Barrier) material can be used to recycle certain by-products, and identify cheaper replacements for expensive conventional PRB materials, especially pure metallic iron. The feasibility of reductive denitrification of nitrate by SIF was studied by batch experiments. Operational parameters such as pH value, SIF dosage and initial concentration of nitrate were investigated. The removal efficiency of nitrate reached 80% under the conditions of pH of 2.5, nitrate initial concentration of 45 mg/L and SIF dosage of 100 g/L within 4 h. Results indicated that nitrate removal is inversely related to pH. Low pH value condition favors for the nitrate transformation. Different from the results of others who studied nitrate reduction using iron powder, we found that there was a lag time before nitrate reduction occurs, even at low pH. Finally, the possible mechanism of nitrate reduction by Fe0 is discussed.

Hao, Zhi-wei; Xu, Xin-hua; Wang, Da-hui

2005-01-01

279

Chemical reclamation of scrap rubber. Final report  

SciTech Connect

A conceptual, commercial-scale plant design was formulated for processing 22,500 t/yr of scrap rubber tires to hydrocarbon fuel gases, oils, petrochemicals (principally ethylene and aromatic liquids), and carbon black. The process is based upon molten salt (zinc chloride) pyrolysis of the rubber, and pyrolysis data obtained in a bench-scale flow apparatus. An economic assessment of the plant was made in terms of late 1979 dollars, for ranges in scrap tire costs and prices for the principal products: carbon black and the fuel gases and oil. Profitability at these 1979 costs and prices is somewhat modest by chemical processing industry standards for new processes, but any increases in energy and carbon black prices would cause favorable changes in this assessment.

Frazier, G.C.; Chan, S.M.; Culberson, O.L.; Perona, J.J.; Larsen, J.W.

1984-01-01

280

Overview of flow studies for recycling metal commodities in the United States  

USGS Publications Warehouse

Metal supply consists of primary material from a mining operation and secondary material, which is composed of new and old scrap. Recycling, which is the use of secondary material, can contribute significantly to metal production, sometimes accounting for more than 50 percent of raw material supply. From 2001 to 2011, U.S. Geological Survey (USGS) scientists studied 26 metals to ascertain the status and magnitude of their recycling industries. The results were published in chapters A-Z of USGS Circular 1196, entitled, "Flow Studies for Recycling Metal Commodities in the United States." These metals were aluminum (chapter W), antimony (Q), beryllium (P), cadmium (O), chromium (C), cobalt (M), columbium (niobium) (I), copper (X), germanium (V), gold (A), iron and steel (G), lead (F), magnesium (E), manganese (H), mercury (U), molybdenum (L), nickel (Z), platinum (B), selenium (T), silver (N), tantalum (J), tin (K), titanium (Y), tungsten (R), vanadium (S), and zinc (D). Each metal commodity was assigned to a single year: chapters A-M have recycling data for 1998; chapters N-R and U-W have data for 2000, and chapters S, T, and X-Z have data for 2004. This 27th chapter of Circular 1196 is called AA; it includes salient data from each study described in chapters A-Z, along with an analysis of overall trends of metals recycling in the United States during 1998 through 2004 and additional up-to-date reviews of selected metal recycling industries from 1991 through 2008. In the United States for these metals in 1998, 2000, and 2004 (each metal commodity assigned to a single year), 84 million metric tons (Mt) of old scrap was generated. Unrecovered old scrap totaled 43 Mt (about 51 percent of old scrap generated, OSG), old scrap consumed was 38 Mt (about 45 percent of OSG), and net old scrap exports were 3.3 Mt (about 4 percent of OSG). Therefore, there was significant potential for increased recovery from scrap. The total old scrap supply was 88 Mt, and the overall new-to-old-scrap ratio was 36:64. On a weighted-average basis, the recycling rate overall for these metals was 40 percent, and the estimated efficiency of recovery was 63 percent. New scrap consumed was 21 Mt. The United States was a net exporter of most scrap metals, and the net exports of 3.3 Mt were valued at $2 billion in constant 1998 dollars. Metals show a wide range of recycling rates, recycling efficiency, and new-to-old-scrap ratios. Recycling rates cluster in the range from 15 to 45 percent, whereas efficiencies are fairly evenly distributed over a range from 7 to 97 percent.

Sibley, Scott F.

2011-01-01

281

Process for removing cadmium from scrap metal  

DOEpatents

A process for the recovery of a metal, in particular, cadmium contained in scrap, in a stable form. The process comprises the steps of mixing the cadmium-containing scrap with an ammonium carbonate solution, preferably at least a stoichiometric amount of ammonium carbonate, and/or free ammonia, and an oxidizing agent to form a first mixture so that the cadmium will react with the ammonium carbonate to form a water-soluble ammine complex; evaporating the first mixture so that ammine complex dissociates from the first mixture leaving carbonate ions to react with the cadmium and form a second mixture that includes cadmium carbonate; optionally adding water to the second mixture to form a third mixture; adjusting the pH of the third mixture to the acid range whereby the cadmium carbonate will dissolve; and adding at least a stoichiometric amount of sulfide, preferably in the form of hydrogen sulfide or an aqueous ammonium sulfide solution, to the third mixture to precipitate cadmium sulfide. This mixture of sulfide is then preferably digested by heating to facilitate precipitation of large particles of cadmium sulfide. The scrap may be divided by shredding or breaking up to expose additional surface area. Finally, the precipitated cadmium sulfide can be mixed with glass formers and vitrified for permanent disposal.

Kronberg, James W. (Aiken, SC)

1995-01-01

282

Process for removing cadmium from scrap metal  

DOEpatents

A process is described for the recovery of a metal, in particular, cadmium contained in scrap, in a stable form. The process comprises the steps of mixing the cadmium-containing scrap with an ammonium carbonate solution, preferably at least a stoichiometric amount of ammonium carbonate, and/or free ammonia, and an oxidizing agent to form a first mixture so that the cadmium will react with the ammonium carbonate to form a water-soluble ammine complex; evaporating the first mixture so that ammine complex dissociates from the first mixture leaving carbonate ions to react with the cadmium and form a second mixture that includes cadmium carbonate; optionally adding water to the second mixture to form a third mixture; adjusting the pH of the third mixture to the acid range whereby the cadmium carbonate will dissolve; and adding at least a stoichiometric amount of sulfide, preferably in the form of hydrogen sulfide or an aqueous ammonium sulfide solution, to the third mixture to precipitate cadmium sulfide. This mixture of sulfide is then preferably digested by heating to facilitate precipitation of large particles of cadmium sulfide. The scrap may be divided by shredding or breaking up to expose additional surface area. Finally, the precipitated cadmium sulfide can be mixed with glass formers and vitrified for permanent disposal. 2 figures.

Kronberg, J.W.

1995-04-11

283

Process for removing cadmium from scrap metal  

DOEpatents

A process for the recovery of a metal, in particular, cadmium contained in scrap, in a stable form. The process comprises the steps of mixing the cadmium-containing scrap with an ammonium carbonate solution, preferably at least a stoichiometric amount of ammonium carbonate, and/or free ammonia, and an oxidizing agent to form a first mixture so that the cadmium will react with the ammonium carbonate to form a water-soluble ammine complex; evaporating the first mixture so that ammine complex dissociates from the first mixture leaving carbonate ions to react with the cadmium and form a second mixture that includes cadmium carbonate; optionally adding water to the second mixture to form a third mixture; adjusting the pH of the third mixture to the acid range whereby the cadmium carbonate will dissolve; and adding at least a stoichiometric amount of sulfide, preferably in the form of hydrogen sulfide or an aqueous ammonium sulfide solution, to the third mixture to precipitate cadmium sulfide. This mixture of sulfide is then preferably digested by heating to facilitate precipitation of large particles of cadmium sulfide. The scrap may be divided by shredding or breaking up to exposure additional surface area. Finally, the precipitated cadmium sulfide can be mixed with glass formers and vitrified for permanent disposal.

Kronberg, J.W.

1994-01-01

284

Recycling production designs: the value of coordination and flexibility in aluminum recycling operations  

NASA Astrophysics Data System (ADS)

The growing motivation for aluminum recycling has prompted interest in recycling alternative and more challenging secondary materials. The nature of these alternative secondary materials necessitates the development of an intermediate recycling facility that can reprocess the secondary materials into a liquid product Two downstream aluminum remelters will incorporate the liquid products into their aluminum alloy production schedules. Energy and environmental benefits result from delivering the products as liquid but coordination challenges persist because of the energy cost to maintain the liquid. Further coordination challenges result from the necessity to establish a long term recycling production plan in the presence of long term downstream aluminum remelter production uncertainty and inherent variation in the daily order schedule of the downstream aluminum remelters. In this context a fundamental question arises, considering the metallurgical complexities of dross reprocessing, what is the value of operating a coordinated set of by-product reprocessing plants and remelting cast houses? A methodology is presented to calculate the optimal recycling center production parameters including 1) the number of recycled products, 2) the volume of recycled products, 3) allocation of recycled materials across recycled products, 4) allocation of recycled products across finished alloys, 4) the level of flexibility for the recycling center to operate. The methods implemented include, 1) an optimization model to describe the long term operations of the recycling center, 2) an uncertainty simulation tool, 3) a simulation optimization method, 4) a dynamic simulation tool with four embedded daily production optimization models of varying degrees of flexibility. This methodology is used to quantify the performance of several recycling center production designs of varying levels of coordination and flexibility. This analysis allowed the identification of the optimal recycling center production design based on maximizing liquid recycled product incorporation and minimizing cast sows. The long term production optimization model was used to evaluate the theoretical viability of the proposed two stage scrap and aluminum dross reprocessing operation including the impact of reducing coordination on model performance. Reducing the coordination between the recycling center and downstream remelters by reducing the number of recycled products from ten to five resulted in only 1.3% less secondary materials incorporated into downstream production. The dynamic simulation tool was used to evaluate the performance of the calculated recycling center production plan when resolved on a daily timeframe for varying levels of operational flexibility. The dynamic simulation revealed the optimal performance corresponded to the fixed recipe with flexible production daily optimization model formulation. Calculating recycled product characteristics using the proposed simulation optimization method increased profitability in cases of uncertain downstream remelter production and expensive aluminum dross and post-consumed secondary materials. (Copies available exclusively from MIT Libraries, libraries.mit.edu/docs - docs@mit.edu)

Brommer, Tracey H.

285

Membrane Purification Cell for Aluminum Recycling  

SciTech Connect

Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent. Eliminating the need for using primary aluminum as a diluent would dramatically reduce energy requirements, decrease carbon dioxide emissions, and increase scrap utilization in recycling. Electrorefining can be used to extract pure aluminum from mixed scrap. Some example applications include producing primary grade aluminum from specific scrap streams such as consumer packaging and mixed alloy saw chips, and recycling multi-alloy products such as brazing sheet. Electrorefining can also be used to extract valuable alloying elements such as Li from Al-Li mixed scrap. This project was aimed at developing an electrorefining process for purifying aluminum to reduce energy consumption and emissions by 75% compared to conventional technology. An electrolytic molten aluminum purification process, utilizing a horizontal membrane cell anode, was designed, constructed, operated and validated. The electrorefining technology could also be used to produce ultra-high purity aluminum for advanced materials applications. The technical objectives for this project were to: - Validate the membrane cell concept with a lab-scale electrorefining cell; - Determine if previously identified voltage increase issue for chloride electrolytes holds for a fluoride-based electrolyte system; - Assess the probability that voltage change issues can be solved; and - Conduct a market and economic analysis to assess commercial feasibility. The process was tested using three different binary alloy compositions (Al-2.0 wt.% Cu, Al-4.7 wt.% Si, Al-0.6 wt.% Fe) and a brazing sheet scrap composition (Al-2.8 wt.% Si-0.7 wt.% Fe-0.8 wt.% Mn),. Purification factors (defined as the initial impurity concentration divided by the final impurity concentration) of greater than 20 were achieved for silicon, iron, copper, and manganese. Cell performance was measured using its current and voltage characteristics and composition analysis of the anode, cathode, and electrolytes. The various cells were autopsied as part of the study. Three electrolyte systems tested were: LiCl-10 wt. % AlCl3, LiCl-10 wt. % AlCl3-5 wt.% AlF3 and LiF-10 wt.% AlF3. An extended four-day run with the LiCl-10 wt.% AlCl3-5 wt.% AlF3 electrolyte system was stable for the entire duration of the experiment, running at energy requirements about one third of the Hoopes and the conventional Hall-Heroult process. Three different anode membranes were investigated with respect to their purification performance and survivability: a woven graphite cloth with 0.05 cm nominal thickness & > 90 % porosity, a drilled rigid membrane with nominal porosity of 33%, and another drilled rigid graphite membrane with increased thickness. The latter rigid drilled graphite was selected as the most promising membrane design. The economic viability of the membrane cell to purify scrap is sensitive to primary & scrap aluminum prices, and the cost of electricity. In particular, it is sensitive to the differential between scrap and primary aluminum price which is highly variable and dependent on the scrap source. In order to be economically viable, any scrap post-processing technology in the U.S. market must have a total operating cost well below the scrap price differential of $0.20-$0.40 per lb to the London Metal Exchange (LME), a margin of 65%-85% of the LME price. The cost to operate the membrane cell is estimated to be < $0.24/lb of purified aluminum. The energy cost is estimated to be $0.05/lb of purified aluminum with the remaining costs being repair and maintenance, electrolyte, labor, taxes and depreciation. The bench-scale work on membrane purification cell process has demonstrated technological advantages and subs

David DeYoung; James Wiswall; Cong Wang

2011-11-29

286

Benefit/Cost Analysis of Plutonium Recycle Options in the United States.  

National Technical Information Service (NTIS)

Predictable effects of the recycle of plutonium and uranium recovered from spent LWR fuels were assessed in a final environmental statement (GESMO). Five alternative dispositions of LWR-produced plutonium ranging from prompt recycle of recovered plutonium...

H. Lowenberg J. B. Burnham F. Fisher W. H. Ray

1977-01-01

287

Looking Northwest at Uranium Dryers Along North Side of Green ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking Northwest at Uranium Dryers Along North Side of Green Room in Recycle Recovery Building - Hematite Fuel Fabrication Facility, Recycle Recovery Building, 3300 State Road P, Festus, Jefferson County, MO

288

Ferrous scrap preheating system: Phase 3, Final report  

SciTech Connect

Utilizing electric arc smelters for making steel has allowed many smaller manufacturers to compete with large integrated mills. The electric arc furnace melts scrap to produce steel. The subject of this report is a Scrap Preheater that heats and cleans the arc furnace scrap using its own low cost natural gas energy supply. Scrap preheating can increase the capacity of a given arc furnace and reduce the operating costs. In addition it reduces the air emissions and allows utilization of lower cost scrap. The program was divided into three phases and was to culminate with an operating prototype at a demonstration host site steel mill. A host site agreement was executed and critical components were tested. The prototype scrap preheater was completely designed. It was sized to preheat 30 tons of scrap in a scrap bucket in 30 minutes. Energy is supplied by a rich fume reactor that completely oxidizes organics from the scrap and auxiliary natural gas. There were several delays and changes in the project that resulted in the host site requesting to withdraw from the program. Extensive efforts were made to secure a replacement host site. However, when another host could not be found, the project was terminated.

NONE

1996-05-13

289

The recycle value of fuel discharged from light water reactors  

SciTech Connect

The recycle value of the fuel discharged from light water reactors has been determined from the viewpoint of recycle in pressurized water reactors. It is concluded that no economic advantage can be gained unless both uranium and plutonium are recycled and only if the reprocessing cost remains below $366/kg. A value based on initial substitution method has also been calculated for plutonium having different concentrations of fissile and fertile isotopes. It has been estimated that under the self-generated recycle option, the neutronic worth of recycled plutonium is reduced to -- 70% of the worth of no-cycle plutonium in 3 to 4 recycles and decreases very slowly after that.

Mirza, N.M.; Parvez, A.

1987-08-01

290

41 CFR 109-27.5107 - Recovery of silver from used hypo solution and scrap film.  

Code of Federal Regulations, 2013 CFR

...Recovery of silver from used hypo solution and scrap film. 109-27.5107...Recovery of silver from used hypo solution and scrap film. The requirements...recovery of silver from used hypo solution and scrap film are contained...

2013-07-01

291

The role of automobiles for the future of aluminum recycling.  

PubMed

To reach required product qualities with lowest costs, aluminum postconsumer scrap is currently recycled using strategies of downgrading and dilution, due to difficulties in refining. These strategies depend on a continuous and fast growth of the bottom reservoir of the aluminum downgrading cascade, which is formed by secondary castings, mainly used in automotive applications. A dynamic material flow model for the global vehicle system was developed to assess the likelihood, timing, and extent of a potential scrap surplus. The results demonstrate that a continuation of the above-mentioned strategies will lead to a nonrecyclable scrap surplus by around 2018 ± 5 if no additional measures are taken. The surplus could grow to reach a level of 0.4-2 kg/cap/yr in 2050, corresponding to a loss of energy saving potential of 43-240 TWh/yr electricity. Various intervention options for avoiding scrap surplus are discussed. Effective strategies need to include an immediate and rapid penetration of dramatically improved scrap sorting technologies for end-of-life vehicles and other aluminum applications. PMID:22816552

Modaresi, Roja; Müller, Daniel B

2012-08-21

292

A Fundamental Metric for Metal Recycling Applied to Coated Magnesium  

NASA Astrophysics Data System (ADS)

A fundamental metric for the assessment of the recyclability and, hence, the sustainability of coated magnesium scrap is presented; this metric combines kinetics and thermodynamics. The recycling process, consisting of thermal decoating and remelting, was studied by thermogravimetry and differential thermal analysis (TG/DTA) experiments and thermodynamic simulations. Decoating phenomena are interpreted using kinetic analysis, applying existing reaction models. The derived kinetic model parameters ln A and E a /( RT p ) are used to characterize the decoating process. The impact of inorganic coating components on remelting is quantified using exergy. Oxidation and entrapment losses, quality losses, and material resource depletion caused by the inorganic components are expressed in exergy units and combined into the single parameter {mathcal{R}} . Based on the results, the coating characteristics favorable for recycling are derived. The obtained metric is a three-dimensional (3 D) combination of ln A, E a /( RT p ), and {mathcal{R}} , which represent the decoating velocity, the ease of decoating, and the impact of coating materials on the remelting process, respectively. The metric, therefore, directly links coating characteristics, coating design, and product design with process technology and recyclability, enabling the ranking of coating alternatives in terms of their respective recyclability. Therefore, the key idea of this article is to use fundamental metallurgical theory to express the recyclability of postconsumer scrap in a unique combination of parameters. This should pave the way for ranking the sustainability of different materials.

Meskers, C. E. M.; Reuter, M. A.; Boin, U.; Kvithyld, A.

2008-06-01

293

Recycled Towers  

NSDL National Science Digital Library

Students learn about material reuse by designing and building the strongest and tallest towers they can, using only recycled materials. They follow design constraints and build their towers to withstand earthquake and high wind simulations.

Integrated Teaching And Learning Program

294

Recycle City  

NSDL National Science Digital Library

Recycling made fun. The Environmental Protection Agency's Recycle City Web site offers students an interactive way to learn how recycling can affect their environment. Users can click any part of the cartoon drawing of the city to learn about that particular building or site and what can be done to decrease waste. The site also contains a more involved exercise called the Dumptown game, where visitors click on City Hall to view various recycling programs and choose the program(s) the city will implement. Once implemented, that activity can be seen taking place in Dumptown. Although the Dumptown exercise may require the help of a teacher to navigate for younger students, both exercises are excellent for K-12 teachers and students.

1997-01-01

295

Ideas: Recycling.  

ERIC Educational Resources Information Center

Presents classroom ideas focusing on connections among mathematics, concern for the environment, and conservation of natural resources, including decomposition, water conservation, packaging materials, use of manufactured cans, and recycling. Includes reproducible student worksheets. (MKR)

Chessin, Debby A.; And Others

1994-01-01

296

Manganese consumption and recycling flow model. Information circular/1995  

SciTech Connect

The report follows the flow of manganese through its metallurgical and chemical applications and highlights areas where significant losses occur owing to downgrading, export, or disposal. The study indicates that materials containing 695,000 short tons (st) of manganese were consumed domestically in 1990. Scrap recovery specifically for manganese recycling was insignificant. However, considerable manganese was recycled through processing operations as a minor component of ferrous and nonferrous scrap and steel slag. The major loss category is manganese lost in steel processing, 323,156 st or 46 pct of the 1990 apparent consumption. Most of this loss reports to steelmaking slags. Recovery from slags is technically feasible, but is not economically feasible.

Gabler, R.C.

1995-04-01

297

Purification of nuclear grade Zr scrap as the high purity dense Zr deposits from Zirlo scrap by electrorefining in LiF-KF-ZrF4 molten fluorides  

NASA Astrophysics Data System (ADS)

Zirconium (Zr) has commonly been used as a cladding material of nuclear fuel. Moreover, it is regarded as the only material that can be used for nuclear fuel cladding because it has the lowest neutron capture cross section of any metal element and because it has high corrosion resistance and size stability. In this study, Hf-free Zr tubes (Zr-1Nb-1Sn-0.1Fe) were used as anode materials and electrorefining was performed in a LiF-KF eutectic 6 wt.% ZrF4 molten fluoride salt system. As a result of electrolysis, Zr scrap metal was recycled into pure Zr with low levels of impurities, and the size and density of the Zr deposit was controlled using applied current density.

Park, Kyoung Tae; Lee, Tae Hyuk; Jo, Nam Chan; Nersisyan, Hayk H.; Chun, Byong Sun; Lee, Hyuk Hee; Lee, Jong Hyeon

2013-05-01

298

Potential Application of Recycled Rubber in Oil Pollution Control  

Microsoft Academic Search

The abundance and indiscriminate disposal of scrap tyres inurban areas in Nigeria create serious health and environmentalproblems. The potential of using rubber recycled from scraptyres as an absorbent in crude oil clean up was investigated.Rubber particles of mesh sizes within the range of 0.15 to2.36 mm were used to absorb crude oil at different temperatures(5 to 40 °C). The rapid

F. A. Aisien; F. K. Hymore; R. O. Ebewele

2003-01-01

299

Potential radioactive scrap metal quantities from nuclear power plants worldwide  

Microsoft Academic Search

Approximately 12 million tons of scrap metals are likely to be generated worldwide during the next 50 years from decommissioning and dismantling nuclear power plants. A large portion of this material will be only slightly contaminated it at all, and, it it is releasable, it would have a scrap value of billions of dollars. Disposition of the metal is complicated

L. A. Nieves; R. W. Tilbrook

1996-01-01

300

91. VIEW NORTHWEST OF SCRAP HOUSE AND CAST HOUSE, BUILDINGS ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

91. VIEW NORTHWEST OF SCRAP HOUSE AND CAST HOUSE, BUILDINGS 101 AND 72; BUILDING 101 IN THE CENTER OF THE PHOTOGRAPH HOUSED SCRAP METAL CLEANING AND PROCESSING FACILITIES; BUILDING 72 AT RIGHT CENTER HOUSED MELTING FURNACES AND CONTINUOUS CASTING MACHINERY - Scovill Brass Works, 59 Mill Street, Waterbury, New Haven County, CT

301

49 CFR 173.218 - Fish meal or fish scrap.  

Code of Federal Regulations, 2013 CFR

...Transportation 2 2013-10-01 2013-10-01 false Fish meal or fish scrap. 173.218 Section 173.218 Transportation...Materials Other Than Class 1 and Class 7 § 173.218 Fish meal or fish scrap. (a) Except as provided in...

2013-10-01

302

46 CFR 148.265 - Fish meal or fish scrap.  

Code of Federal Regulations, 2013 CFR

...Shipping 5 2013-10-01 2013-10-01 false Fish meal or fish scrap. 148.265 Section 148.265 Shipping ...Special Requirements for Certain Materials § 148.265 Fish meal or fish scrap. (a) This part does not...

2013-10-01

303

A Study of Scrap Heating By Burners. Part I: Experiments  

NASA Astrophysics Data System (ADS)

A furnace, approximately 1 m3 in capacity, was built to measure the efficiency of heat transfer from a propane-oxygen burner to different types of industrial steel scrap. Supplementary measurements were undertaken to measure the scrap density, size, and void fraction to insure complete combustion of the propane and to measure the extent of scrap oxidation. Local values of temperature in the scrap bed were measured along with the exit temperature of the off gas. The off gas temperature was a direct measurement of the overall efficiency of heating. It was found that smaller and denser scrap was heated more effectively. Configurations that increased the path length of the gas also increased the efficiency of heating. In Part II, a mathematical model is developed to compare with the measured temperatures.

Mandal, Kamalesh; Irons, Gordon A.

2013-02-01

304

Textile recycling  

SciTech Connect

The most common household textiles include clothing, linens, draperies, carpets, shoes, handbags, and rugs. Old clothing, of course, is the most readily reused and/or recycled residentially generated textile category. State and/or local mandates to recycle a percentage of the waste stream are providing the impetus to add new materials to existing collection programs. Concurrently, the textile industry is aggressively trying to increase its throughput by seeking new sources of material to meet increased world demand for product. As experienced with drop-off programs for traditional materials, a majority of residents will not recycle materials unless the collection programs are convenient, i.e., curbside collection. The tonnage of marketable textiles currently being landfilled provide evidence of this. It is the authors' contention that if textile recycling is made convenient and accessible to every household in a municipality or region, then the waste stream disposed may be reduced in a similar fashion as when traditional recyclables are included in curbside programs.

Jablonowski, E. (Killam Associates, Millburn, NJ (United States)); Carlton, J.

1995-01-01

305

Tire Recycling  

NASA Technical Reports Server (NTRS)

Cryopolymers, Inc. tapped NASA expertise to improve a process for recycling vehicle tires by converting shredded rubber into products that can be used in asphalt road beds, new tires, hoses, and other products. In conjunction with the Southern Technology Applications Center and Stennis Space Center, NASA expertise in cryogenic fuel-handling needed for launch vehicle and spacecraft operations was called upon to improve the recycling concept. Stennis advised Cryopolymers on the type of equipment required, as well as steps to reduce the amount of liquid nitrogen used in the process. They also guided the company to use more efficient ways to control system hardware. It is estimated that more than 300 million tires nationwide are produced per year. Cryopolymers expects to reach a production rate of 5,000 tires recycled per day.

1997-01-01

306

Vanadium recycling in the United States in 2004  

USGS Publications Warehouse

As one of a series of reports that describe the recycling of metal commodities in the United States, this report discusses the flow of vanadium in the U.S. economy in 2004. This report includes a description of vanadium supply and demand in the United States and illustrates the extent of vanadium recycling and recycling trends. In 2004, apparent vanadium consumption, by end use, in the United States was 3,820 metric tons (t) in steelmaking and 232 t in manufacturing, of which 17 t was for the production of superalloys and 215 t was for the production of other alloys, cast iron, catalysts, and chemicals. Vanadium use in steel is almost entirely dissipative because recovery of vanadium from steel scrap is chemically impeded under the oxidizing conditions in steelmaking furnaces. The greatest amount of vanadium recycling is in the superalloy, other-alloy, and catalyst sectors of the vanadium market. Vanadium-bearing catalysts are associated with hydrocarbon recovery and refining in the oil industry. In 2004, 2,850 t of vanadium contained in alloy scrap and spent catalysts was recycled, which amounted to about 44 percent of U.S. domestic production. About 94 percent of vanadium use in the United States was dissipative (3,820 t in steel/4,050 t in steel+fabricated products).

Goonan, Thomas G.

2011-01-01

307

Energy implications of glass-container recycling  

SciTech Connect

This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

1994-03-01

308

Scrap tires: a resource and technology evaluation of tire pyrolysis and other selected alternate technologies  

Microsoft Academic Search

The results of a technical and economic evaluation of scrap tire pyrolysis are presented and some other alternative uses for scrap tires are discussed. A scrap tire, by definition in this report, is one for which there is no economic end use. Information is presented on the scrap tire resource, pyrolysis processes, pyrolysis products (char, oil, and gas), markets for

J. Dodds; W. F. Domenico; D. R. Evans; L. W. Fish; P. L. Lassahn; W. J. Toth

1983-01-01

309

SCRAP BEING FED INTO HARRIS TGS200 BALER. BLOCKS OF COMPACTED ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

SCRAP BEING FED INTO HARRIS TGS-200 BALER. BLOCKS OF COMPACTED SCRAP, CALLED "CABBAGES", ARE MELTED DOWN IN THE CAST SHOP,ALONG WITH RAW METAL AND ALLOYS. BALED SCRAP MELTS MORE RAPIDLY THAN LOOSE SCRAP. - American Brass Foundry, 70 Sayre Street, Buffalo, Erie County, NY

310

Endocytic recycling  

Microsoft Academic Search

After endocytosis, most membrane proteins and lipids return to the cell surface, but some membrane components are delivered to late endosomes or the Golgi. We now understand that the pathways taken by internalized molecules that eventually recycle to the cell surface can be surprisingly complex and can involve a series of sorting events that occur in several organelles. The molecular

Frederick R. Maxfield; Timothy E. McGraw

2004-01-01

311

Recycled soundscapes  

Microsoft Academic Search

An interactive system collects noise from a public place and transforms it into content for a public orchestration: the noise is split in specific sounds which are recomposed through sonic interface in a new soundscape. The SoundCam is the most visible part of the Recycling Soundscapes system. It rotates scanning a public space and gives the possibility to spy and

Karmen Franinovic; Yon Visell

2004-01-01

312

Recycling Philology.  

ERIC Educational Resources Information Center

Proposes that English teachers recycle philology as a field of study. Redefines the shape of philology in view of postmodern theories of signification. Considers concepts of hermeneutics in retheorizing the aims of philology. Shows how such philological investigation might be used in the classroom to study literary texts. (HB)

Knapp, Peggy A.

1993-01-01

313

Integrated steel producers race the recycling clock  

SciTech Connect

When classed as waste, the leftover oxides of blast furnaces and oxygen furnaces must go into landfill. That is an expensive option. Assuming there is space and permission for land disposal, this may be only a temporary solution. Finally, there is an economic incentive to replace some amount of scrap with the iron units in waste. The various factors have brought a concerted recycling push. With increased use of galvanized scrap, a growing portion of the waste is zinc coated. Unlike electric furnace dust, the waste from blast furnaces and oxygen furnaces doesn`t have enough zinc to be classed as hazardous. In theory, repeated cycling will concentrate the zinc but there is uncertainty about what actually happens. There are ways to remove zinc from waste, however, favorable economics have tended to require high concentrations of zinc. New processes and conditions could change the economic equation. The ultimate answer to recycling could be a facility specifically designed for converting waste into usable metal.

McManus, G.J.

1996-01-01

314

Scrap tires: a resource and technology evaluation of tire pyrolysis and other selected alternate technologies  

SciTech Connect

The results of a technical and economic evaluation of scrap tire pyrolysis are presented and some other alternative uses for scrap tires are discussed. A scrap tire, by definition in this report, is one for which there is no economic end use. Information is presented on the scrap tire resource, pyrolysis processes, pyrolysis products (char, oil, and gas), markets for these products, and the economics of tire pyrolysis. A discussion is presented on alternative ideas for using scrap tires as an energy resource.

Dodds, J.; Domenico, W.F.; Evans, D.R.; Fish, L.W.; Lassahn, P.L.; Toth, W.J.

1983-11-01

315

Uranium Metal Dissolution in the Presence of Fluoride and Boron  

Microsoft Academic Search

H-Area Operations is planning to process plutonium-contaminated (Pu-contaminated) uranium metal scrap in its efforts to de-inventory excess nuclear materials. Experimental work was performed with a piece of uranium sheet. The study had four primary objectives. First, gather reaction rate data at a range of processing conditions to compare against reaction rate data reported in earlier studies and recommend a flowsheet

Pierce

2004-01-01

316

Recovery of Uranium from Refractory Ores.  

National Technical Information Service (NTIS)

Uranium is recovered from refractory carbonaceous-sulfidic ores or concentrates by leaching with nitric acid, followed by sorption on an ion exchange resin. In addition, the nitric acid leach solution is regenerated and recycled.

T. G. Carnahan K. P. V. Lei

1977-01-01

317

Method for treating rare earth-transition metal scrap  

DOEpatents

Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a prefused, rare earth fluoride-bearing flux of CaF.sub.2, CaCl.sub.2 or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA); Jones, Lawrence L. (Des Moines, IA)

1992-12-29

318

MANUAL SPOT WELDING STATION IN THE REAR PAN SCRAP REWORK ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

MANUAL SPOT WELDING STATION IN THE REAR PAN SCRAP REWORK AREA FACING S. NORTH END OF HISTORIC PORTION OF ASSEMBLY PLANT, FIRST FLOOR, X7, COLUMN 17. - B Building, 3001 Miller Road, Dearborn, Wayne County, MI

319

19. 1500 CUBIC FEET CAPACITY SCRAP STEEL CHARGING BOX ON ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

19. 1500 CUBIC FEET CAPACITY SCRAP STEEL CHARGING BOX ON THE CHARGING AISLE OF THE BOP SHOP LOOKING NORTHWEST. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

320

Disposal Techniques with Energy Recovery for Scrapped Vehicle Tires.  

National Technical Information Service (NTIS)

The scrap tire disposal problem is serious and widespread. However there are a number of promising management options, especially using the rubber as a supplemental fuel for existing combustors. The most cost-effective approach to dealing with Denver's ti...

T. A. Sladek E. K. Demos

1987-01-01

321

Contaminated scrap metal management on the Oak Ridge Reservation  

SciTech Connect

Large quantities of scrap metal are accumulating at the various Department of Energy (DOE) installations across the country as a result of ongoing DOE programs and missions in concert with present day waste management practices. DOE Oak Ridge alone is presently storing around 500,000 tons of scrap metal. The local generation rate, currently estimated at 1,400 tons/yr, is expected to increase sharply over the next couple of years as numerous environmental restoration and decommissioning programs gain momentum. Projections show that 775,000 tons of scrap metal could be generated at the K-25 Site over the next ten years. The Y-12 Plant and Oak Ridge National Laboratory (ORNL) have similar potentials. The history of scrap metal management at Oak Ridge and future challenges and opportunities are discussed.

Hayden, H.W.; Stephenson, M.J.; Bailey, J.K.; Weir, J.R. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States); Gilbert, W.C. [USDOE Oak Ridge Operations Office, TN (United States)

1993-09-01

322

Method for treating rare earth-transition metal scrap  

DOEpatents

Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a rare earth fluoride-bearing flux of CaF[sub 2], CaCl[sub 2] or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy. 3 figs.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.

1992-12-29

323

Precipitation Recycling  

NASA Technical Reports Server (NTRS)

The water cycle regulates and reflects natural variability in climate at the regional and global scales. Large-scale human activities that involve changes in land cover, such as tropical deforestation, are likely to modify climate through changes in the water cycle. In order to understand, and hopefully be able to predict, the extent of these potential global and regional changes, we need first to understand how the water cycle works. In the past, most of the research in hydrology focused on the land branch of the water cycle, with little attention given to the atmospheric branch. The study of precipitation recycling which is defined as the contribution of local evaporation to local precipitation, aims at understanding hydrologic processes in the atmospheric branch of the water cycle. Simply stated, any study on precipitation recycling is about how the atmospheric branch of the water cycle works, namely, what happens to water vapor molecules after they evaporate from the surface, and where will they precipitate?

Eltahir, Elfatih A. B.; Bras, Rafael L.

1996-01-01

324

Plutonium scrap recovery at Savannah River: Past, present, and vision of the future  

SciTech Connect

As a result of the changing requirement, plus environmental and regulatory commitments, SRP now has essentially completed its paradigm shift. SRP has been transformed from primarily a reprocessor of irradiated uranium targets to primarily a reprocessor of non-specification plutonium. This is the mission which will carry SRP into the 21st Century. Accomplishment of the defined goals for the three-pronged RandD program will achieve several objectives: exploit new processes for recovering low-grade scraps; enhance SRP's position to incorporate pyrochemical processes where they are attractive or beneficial to plant scrap recovery; provide SRL/SRP with a capability to develop compatible aqueous pyrochemical processes; identify material compatibility requirements for the incorporation of pyrochemical processes at SRP; promote development and demonstration of improved NDA instrumentation to accurately measure plutonium holdups in solid residues; identify and implement the technology required for reagent preparation and atmospheric quality control; provide a means to compare economic options for emerging new processes; and as a result, identify process steps which will also put SRP in a position to readily adapt to changing plutonium missions.

Gray, L.W.; Gray, J.H.; Blancett, A.L.; Lower, M.W.; Rudisill, T.S.

1988-01-01

325

Conversion of plutonium scrap and residue to boroilicate glass using the GMODS process  

SciTech Connect

Plutonium scrap and residue represent major national and international concerns because (1) significant environmental, safety, and health (ES&H) problems have been identified with their storage; (2) all plutonium recovered from the black market in Europe has been from this category; (3) storage costs are high; and (4) safeguards are difficult. It is proposed to address these problems by conversion of plutonium scrap and residue to a CRACHIP (CRiticality, Aerosol, and CHemically Inert Plutonium) glass using the Glass Material Oxidation and Dissolution System (GMODS). CRACHIP refers to a set of requirements for plutonium storage forms that minimize ES&H concerns. The concept is several decades old. Conversion of plutonium from complex chemical mixtures and variable geometries into a certified, qualified, homogeneous CRACHIP glass creates a stable chemical form that minimizes ES&H risks, simplifies safeguards and security, provides an easy-to-store form, decreases storage costs, and allows for future disposition options. GMODS is a new process to directly convert metals, ceramics, and amorphous solids to glass; oxidize organics with the residue converted to glass; and convert chlorides to borosilicate glass and a secondary sodium chloride stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium (a plutonium surrogate), Zircaloy, stainless steel, and other materials to glass. GMODS is an enabling technology that creates new options. Conventional glassmaking processes require conversion of feeds to oxide-like forms before final conversion to glass. Such chemical conversion and separation processes are often complex and expensive.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.; Rudolph, J.; Elam, K.R.; Ferrada, J.J.

1995-11-28

326

Properties of concrete containing scrap-tire rubber – an overview  

Microsoft Academic Search

Solid waste management is one of the major environmental concerns in the United States. Over 5 billion tons of non-hazardous solid waste materials are generated in USA each year. Of these, more than 270 million scrap-tires (approximately 3.6 million tons) are generated each year. In addition to this, about 300 million scrap-tires have been stockpiled. Several studies have been carried

Rafat Siddique; Tarun R. Naik

2004-01-01

327

Recovery of lead, tin and indium from alloy wire scrap  

Microsoft Academic Search

Lead, tin and indium were successfully recovered from alloy wire scrap containing these metals by acid\\/alkali leaching. The scrap material was leached with hot HCl–HNO3 solution. Upon cooling down to 10°C, 71.8% of lead initially present was separated as lead chloride. The major part of the remaining lead content (22.9%) was recovered by cementation with indium powder of 1.5 equivalents

M. A. Barakat

1998-01-01

328

Scrap? This Program Grows on It!  

ERIC Educational Resources Information Center

A high school industrial arts program in plastics recycling provided students direct contact with production methods of the plastics industry as well as awareness of governmental functions. Experimentation included fuel cells, paving and construction composites, soil composites, and watercraft flotation. (EA)

Schureman, Robert

1975-01-01

329

Recycling of auto shredder residue.  

PubMed

Currently, about 75% of end-of-life vehicle's (ELV) total weight is recycled in EU countries. The remaining 25%, which is called auto shredder residues (ASR) or auto fluff, is disposed of as landfill because of its complexity. It is a major challenge to reduce this percentage of obsolete cars. The European draft directive states that by the year 2006, only 15% of the vehicle's weight can be disposed of at landfill sites and by 2015, this will be reduced to 5%. The draft directive states that a further 10% can be incinerated. The quantities of shredder fluff are likely to increase in the coming years. This is because of the growing number of cars being scrapped, coupled with the increase in the amount of plastics used in cars. In Sweden, some current projects are focusing on recycling of ASR material. In this paper some different alternatives for using this material are reported. The hypothetical injection of ASR into a blast furnace concentrating on ASR's effect to some blast furnace (BF) parameters has been completed using a blast furnace mass balance model. As a result, in principle, ASR can be used as reducing agent in the BF process if certain conditions are met. The particle size of ASR material must be controlled to ensure optimal gasification of the material in the raceway. Regarding the chemical composition of ASR, the non-ferrous content can affect the pig iron quality, which is difficult to rectify at a later point. The most attractive recycling alternative is to use the products obtained from pyrolysis of ASR in appropriate metallurgical processes. PMID:16600493

Nourreddine, Menad

2007-01-31

330

Computer Recycling  

NSDL National Science Digital Library

Given current rates of computer consumerism and technological advances, one might expect to find a lot of computers out there in the world. What happens to these old computers? This Topic in Depth explores this issue, reviews some options for recycling computers, and provides tips for anyone considering purchasing a refurbished computer. The first article from BBC News (1) reports on research which suggests that "the number of personal computers worldwide is expected to double by 2010 to 1.3 billion machines." The second article from Oasis, a project of the Irish eGovernment initiative, (2) reviews some of the issues surrounding waste from electrical and electronic equipment. This next article from PC World (3) gives some ideas for how to dispose of an old notebook computer. One option, of course, is to donate your notebook, which is discussed in this article from Tech Soup (4). Another resource for information on computer recycling and reuse is this website from CompuMentor (5). Given the current market for computers, many are considering refurbished computers. This article from Vnunet (6 ) explains what a refurbished computer is while the next website provides some tips for buying a refurbished computer (7 ). Finally, this article from About.com reports on the recently introduced National Computer Recycling Act (8).

331

Fluidized-bed combustion of scrap tires: Technical note  

SciTech Connect

An introduction to fluidized-bed combustion (FBC) is presented in Section 2.0. Based on this discussion of its technical development, FBC is then presented as a means of scrap tire disposal. In Section 3.0, scrap tire disposal is reviewed in the categories of (1) physical applications, (2) chemical applications, (3) pyrolysis, and (4) incineration for thermal energy recovery. Scrap tire disposal is reviewed on the basis of (1) environmental acceptability, (2) conservation of resources, (3) impact on existing industries, (4) operational feasibility, and (5) special features. The focus of this report is the fluidized-bed incineration of scrap tires for thermal energy recovery. The factors that affect scrap tire combustion are discussed in Section 4.0. These factors are (1) agitation, (2) temperature, (3) excess air, (4) residence time, (5) feed uniformity, (6) solid waste handling, and (7) pollutants emission control. In reviewing these incineration processes, (1) fuel flexibility, (2) environmental acceptability, (3) combustion efficiency, and (4) operational reliability are discussed. The results from a tire incineration experiment conducted at the Morgantown Energy Technology Center are presented in Section 5.0, and a conceptual fluidized-bed combustor is discussed in Section 6.0. Future considerations in the FBC of scrap tires are discussed in Section 7.0. 8 refs., 6 figs., 6 tabs.

Shang, J.Y.; Mei, J.S.; Notestein, J.E.

1981-10-01

332

Value analysis of neodymium content in shredder feed: toward enabling the feasibility of rare Earth magnet recycling.  

PubMed

In order to facilitate the development of recycling technologies for rare earth magnets from postconsumer products, we present herein an analysis of the neodymium (Nd) content in shredder scrap. This waste stream has been chosen on the basis of current business practices for the recycling of steel, aluminum, and copper from cars and household appliances, which contain significant amounts of rare earth magnets. Using approximations based on literature data, we have calculated the average Nd content in the ferrous shredder product stream to be between 0.13 and 0.29 kg per ton of ferrous scrap. A value analysis considering rare earth metal prices between 2002 and 2013 provides values between $1.32 and $145 per ton of ferrous scrap for this material, if recoverable as pure Nd metal. Furthermore, we present an analysis of the content and value of other rare earths (Pr, Dy, Tb). PMID:24934194

Bandara, H M Dhammika; Darcy, Julia W; Apelian, Diran; Emmert, Marion H

2014-06-17

333

REGULATIONS ON PHOTOVOLTAIC MODULE DISPOSAL AND RECYCLING.  

SciTech Connect

Environmental regulations can have a significant impact on product use, disposal, and recycling. This report summarizes the basic aspects of current federal, state and international regulations which apply to end-of-life photovoltaic (PV) modules and PV manufacturing scrap destined for disposal or recycling. It also discusses proposed regulations for electronics that may set the ground of what is to be expected in this area in the near future. In the US, several states have started programs to support the recycling of electronic equipment, and materials destined for recycling often are excepted from solid waste regulations during the collection, transfer, storage and processing stages. California regulations are described separately because they are different from those of most other states. International agreements on the movement of waste between different countries may pose barriers to cross-border shipments. Currently waste moves freely among country members of the Organization of Economic Cooperation and Development (OECD), and between the US and the four countries with which the US has bilateral agreements. However, it is expected, that the US will adopt the rules of the Basel Convention (an agreement which currently applies to 128 countries but not the US) and that the Convection's waste classification system will influence the current OECD waste-handling system. Some countries adopting the Basel Convention consider end-of-life electronics to be hazardous waste, whereas the OECD countries consider them to be non-hazardous. Also, waste management regulations potentially affecting electronics in Germany and Japan are mentioned in this report.

FTHENAKIS,V.

2001-01-29

334

Influence of void fraction on plutonium recycling in BWR  

NASA Astrophysics Data System (ADS)

The uncertainty of commercial operation of fast breeder reactors (FBR) claims for another solution to the plutonium produced in light water reactors (LWR). As one option, recently, the plutonium recycling in LWR becomes an important consideration. A study on the impact of changing void fraction on plutonium recycling in BWR has been performed. Two types of uranium sources in mixed oxide (MOX) fuel, namely the depleted uranium and the natural uranium have been evaluated. The trend is similar for both MOX fuels that BWR can gain its critical condition for the void fraction of less than 42% and it may be operated in critical condition for the void fraction of 42% and 95%.

Surbakti, R.; Waris, A.; Basar, K.; Permana, S.; Kurniadi, R.

2012-06-01

335

Argonne explains nuclear recycling in 4 minutes  

SciTech Connect

Currently, when using nuclear energy only about five percent of the uranium used in a fuel rod gets fissioned for energy; after that, the rods are taken out of the reactor and put into permanent storage. There is a way, however, to use almost all of the uranium in a fuel rod. Recycling used nuclear fuel could produce hundreds of years of energy from just the uranium we've already mined, all of it carbon-free. Problems with older technology put a halt to recycling used nuclear fuel in the United States, but new techniques developed by scientists at Argonne National Laboratory address many of those issues. For more information, visit http://www.anl.gov/energy/nuclear-energy.

None

2012-01-01

336

Argonne explains nuclear recycling in 4 minutes  

ScienceCinema

Currently, when using nuclear energy only about five percent of the uranium used in a fuel rod gets fissioned for energy; after that, the rods are taken out of the reactor and put into permanent storage. There is a way, however, to use almost all of the uranium in a fuel rod. Recycling used nuclear fuel could produce hundreds of years of energy from just the uranium we've already mined, all of it carbon-free. Problems with older technology put a halt to recycling used nuclear fuel in the United States, but new techniques developed by scientists at Argonne National Laboratory address many of those issues. For more information, visit http://www.anl.gov/energy/nuclear-energy.

None

2013-04-19

337

Green Science: Revisiting Recycling  

ERIC Educational Resources Information Center

Recycling has been around for a long time--people have reused materials and refashioned them into needed items for thousands of years. More recently, war efforts encouraged conservation and reuse of materials, and in the 1970s recycling got its official start when recycling centers were created. Now, curbside recycling programs and recycling…

Palliser, Janna

2011-01-01

338

A Recycled Giraffe  

ERIC Educational Resources Information Center

Chicken wire, cardboard tubes, newspaper, scrap lumber and discontinued fabric samples were among the discarded materials used in the art classes at the Webster Hill Elementary School, West Hartford, Connecticut, to create an eight-foot giraffe. (Author/RK)

Diorio, Lucille

1976-01-01

339

Model institutional infrastructures for recycling of photovoltaic modules  

SciTech Connect

This paper describes model approaches to designing an institutional infrastructure for the recycling of decommissioned photovoltaic modules; more detailed discussion of the information presented in this paper is contained in Reaven et al., (1996)[1]. The alternative approaches are based on experiences in other industries, with other products and materials. In the aluminum, scrap iron, and container glass industries, where recycling is a long-standing, even venerable practice, predominantly private, fully articulated institutional infrastructures exist. Nevertheless, even in these industries, arrangements are constantly evolving in response to regulatory changes, competition, and new technological developments. Institutional infrastructures are less settled for younger large- scale recycling industries that target components of the municipal solid waste (MSW) stream, such as cardboard and newspaper, polyethylene terephthalate (PET) and high-density polyethylene (HDPE) plastics, and textiles. In these industries the economics, markets, and technologies are rapidly changing. Finally, many other industries are developing projects to ensure that their products are recycled (and recyclable) e.g., computers, non-automotive batteries, communications equipment, motor and lubrication oil and oil filters, fluorescent lighting fixtures, automotive plastics and shredder residues, and bulk industrial chemical wastes. The lack of an an adequate recycling infrastructure, attractive end-markets, and clear the economic incentives, can be formidable impediments to a self- sustaining recycling system.

Moscowitz, P.D.; Reaven, J.; Fthenakis, V.M.

1996-07-01

340

Decontaminating and Melt Recycling Tritium Contaminated Stainless Steel  

SciTech Connect

The Westinghouse Savannah River Company, Idaho National Engineering Laboratory, and several university and industrial partners are evaluating recycling radioactively contaminated stainless steel. The goal of this program is to recycle contaminated stainless steel scrap from US Department of Energy national defense facilities. There is a large quantity of stainless steel at the DOE Savannah River Site from retired heavy water moderated Nuclear material production reactors (for example heat exchangers and process water piping), that will be used in pilot studies of potential recycle processes. These parts are contaminated by fission products, activated species, and tritium generated by neutron irradiation of the primary reactor coolant, which is heavy (deuterated) water. This report reviews current understanding of tritium contamination of stainless steel and previous studies of decontaminating tritium exposed stainless steel. It also outlines stainless steel refining methods, and proposes recommendations based on this review.

Clark, E.A.

1995-04-03

341

Environmental effects of the uranium fuel cycle: a review of data for technetium  

Microsoft Academic Search

Sources of potential releases of ⁹⁹Tc to the environment are reviewed for the uranium fuel cycle considering two options: the recycle of spent uranium fuel and no fuel recycling. In the no recycle option, the only source of ⁹⁹Tc release is an extremely small amount associated with airborne emissions from the processing of high-level wastes. With recycling, ⁹⁹Tc releases are

J. E. Till; R. W. Shor; F. O. Hoffman

1984-01-01

342

Screening of halogenated aromatic compounds in some raw material lots for an aluminium recycling plant.  

PubMed

Four samples of scrap raw materials for an aluminium recycling plant were screened for the occurrence of persistent halogenated aromatic compounds. The samples contained waste from handling of electric and electronic plastics, filter dust from electronic crusher, cyclone dust from electronic crusher and light fluff from car shredder. In our screening analyses, brominated flame retardants were observed in all samples. Polybrominated diphenyl ethers (PBDE) were identified in all samples in amounts of 245-67450 ng/g. The major PBDE congeners found were decabromo- and pentabromodiphenyl ethers. 1,1-bis(2,4,6-tribromophenoxy)ethane, hexabromobenzene, ethyl-pentabromobenzene, tetrabromobisphenol-A, pentabromotoluene and dimethyl tetrabromobenzene were observed in all scrap samples. The concentrations of PCBs, PCNs (polychlorinated naphthalenes) and nona- to undecachlorinated terphenyls in some of these scrap samples were remarkably high. PMID:14987867

Sinkkonen, Seija; Paasivirta, Jaakko; Lahtiperä, Mirja; Vattulainen, Antero

2004-05-01

343

Long-term strategies for increased recycling of automotive aluminum and its alloying elements.  

PubMed

Aluminum recycling currently occurs in a cascading fashion, where some alloys, used in a limited number of applications, absorb most of the end-of-life scrap. An expected increase in scrap supply in coming decades necessitates restructuring of the aluminum cycle to open up new recycling paths for alloys and avoid a potential scrap surplus. This paper explores various interventions in end-of-life management and recycling of automotive aluminum, using a dynamic substance flow analysis model of aluminum and its alloying elements with resolution on component and alloy level (vehicle-component-alloy-element model). It was found that increased component dismantling before vehicle shredding can be an effective, so far underestimated, intervention in the medium term, especially if combined with development of safety-relevant components such as wheels from secondary material. In the long term, automatic alloy sorting technologies are most likely required, but could at the same time reduce the need for magnesium removal in refining. Cooperation between the primary and secondary aluminum industries, the automotive industry, and end-of-life vehicle dismantlers is therefore essential to ensure continued recycling of automotive aluminum and its alloying elements. PMID:24655476

Løvik, Amund N; Modaresi, Roja; Müller, Daniel B

2014-04-15

344

The fate of sulfur during rapid pyrolysis of scrap tires.  

PubMed

The fate of sulfur during rapid pyrolysis of scrap tires at temperatures from 673 to 1073K was investigated. Sulfur was predominant in the forms of thiophenic and inorganic sulfides in raw scrap tires. In the pyrolysis process, sulfur in organic forms was unstable and decomposed, leading to the sulfur release into tar and gases. At 673 and 773K, a considerable amount of sulfur was distributed in tar. Temperature increasing from 773 to 973K promoted tar decomposition and facilitated sulfur release into gases. At 1073K, the interactions between volatiles and char stimulated the formation of high-molecular-weight sulfur-containing compounds. After pyrolysis, almost half of the total content of sulfur in raw scrap tires still remained in the char and was mostly in the form of sulfides. Moreover, at temperatures higher than 873K, part of sulfur in the char was immobilized in the sulfates. In the pyrolysis gases, H2S was the main sulfur-containing gas. Increasing temperature stimulated the decomposition of organic polymers in scrap tires and more H2S was formed. Besides H2S, other sulfur-containing gases such as CH3SH, COS and SO2 were produced during the rapid pyrolysis of scrap tires. PMID:24238304

Hu, Hongyun; Fang, Yuan; Liu, Huan; Yu, Ren; Luo, Guangqian; Liu, Wenqiang; Li, Aijun; Yao, Hong

2014-02-01

345

Disposition of Unirradiated Sodium Bonded EBR-II Driver Fuel Elements and HEU Scrap: Work Performed for FY 2007  

SciTech Connect

Specific surplus high enriched uranium (HEU) materials at the Idaho National Laboratory (INL) Materials and Fuels Complex (MFC) will be transferred to a designated off-site receiving facility. The DOE High Enriched Uranium Disposition Program Office (HDPO) will determine which materials, if any, will be prepared and transferred to an off-site facility for processing and eventual fabrication of fuel for nuclear reactors. These surplus HEU materials include approximately 7200 kg unirradiated sodium-bonded EBR-II driver fuel elements, and nearly 800 kg of HEU casting scrap from the process which formed various sodium-bonded fuels (including the EBR-II driver elements). Before the driver fuel can be packaged for shipment, the fuel elements will require removal of the sodium bond. The HEU scrap will also require repackaging in preparation for off-site transport. Preliminary work on this task was authorized by BWXT Y-12 on Nov 6, 2006 and performed in three areas: • Facility Modifications • Safety Documentation • Project Management

Karen A Moore

2007-04-01

346

Recycling: Additional Efforts Could Increase Municipal Recycling.  

National Technical Information Service (NTIS)

Although recycling can generate environmental and economic benefits, the national recycling rate has increased only slightly since 2000, according to the Environmental Protection Agency (EPA). While local governments have the primary role in operating rec...

2006-01-01

347

40 CFR 63.10885 - What are my management practices for metallic scrap and mercury switches?  

Code of Federal Regulations, 2013 CFR

...staff to communicate to suppliers throughout the scrap supply chain the need to promote the removal of mercury switches...staff to communicate to suppliers throughout the scrap supply chain the need to promote the removal or mercury...

2013-07-01

348

40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?  

Code of Federal Regulations, 2013 CFR

...staff to communicate to suppliers throughout the scrap supply chain the need to promote the removal of mercury switches...staff to communicate to suppliers throughout the scrap supply chain the need to promote the removal of mercury...

2013-07-01

349

Component- and Alloy-Specific Modeling for Evaluating Aluminum Recycling Strategies for Vehicles  

NASA Astrophysics Data System (ADS)

Previous studies indicated that the availability of mixed shredded aluminum scrap from end-of-life vehicles (ELV) is likely to surpass the capacity of secondary castings to absorb this type of scrap, which could lead to a scrap surplus unless suitable interventions can be identified and implemented. However, there is a lack of studies analyzing potential solutions to this problem, among others, because of a lack of component- and alloy-specific information in the models. In this study, we developed a dynamic model of aluminum in the global vehicle stock (distinguishing 5 car segments, 14 components, and 7 alloy groups). The forecasts made up to the year 2050 for the demand for vehicle components and alloy groups, for the scrap supply from discarded vehicles, and for the effects of different ELV management options. Furthermore, we used a source-sink diagram to identify alloys that could potentially serve as alternative sinks for the growing scrap supply. Dismantling the relevant components could remove up to two-thirds of the aluminum from the ELV stream. However, the use of these components for alloy-specific recycling is currently limited because of the complex composition of components (mixed material design and applied joining techniques), as well as provisions that practically prevent the production of safety-relevant cast parts from scrap. In addition, dismantling is more difficult for components that are currently penetrating rapidly. Therefore, advanced alloy sorting seems to be a crucial step that needs to be developed over the coming years to avoid a future scrap surplus and prevent negative energy use and emission consequences.

Modaresi, Roja; Løvik, Amund N.; Müller, Daniel B.

2014-03-01

350

Data summary of municipal solid waste management alternatives. Volume 7, Appendix E -- Material recovery/material recycling technologies  

SciTech Connect

The enthusiasm for and commitment to recycling of municipal solid wastes is based on several intuitive benefits: Conservation of landfill capacity; Conservation of non-renewable natural resources and energy sources; Minimization of the perceived potential environmental impacts of MSW combustion and landfilling; Minimization of disposal costs, both directly and through material resale credits. In this discussion, ``recycling`` refers to materials recovered from the waste stream. It excludes scrap materials that are recovered and reused during industrial manufacturing processes and prompt industrial scrap. Materials recycling is an integral part of several solid waste management options. For example, in the preparation of refuse-derived fuel (RDF), ferrous metals are typically removed from the waste stream both before and after shredding. Similarly, composting facilities, often include processes for recovering inert recyclable materials such as ferrous and nonferrous metals, glass, Plastics, and paper. While these two technologies have as their primary objectives the production of RDF and compost, respectively, the demonstrated recovery of recyclables emphasizes the inherent compatibility of recycling with these MSW management strategies. This appendix discusses several technology options with regard to separating recyclables at the source of generation, the methods available for collecting and transporting these materials to a MRF, the market requirements for post-consumer recycled materials, and the process unit operations. Mixed waste MRFs associated with mass bum plants are also presented.

none,

1992-10-01

351

Rare earth-transition metal scrap treatment method  

DOEpatents

Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA); Jones, Lawrence L. (Des Moines, IA); Lincoln, Lanny P. (Woodward, IA)

1992-02-11

352

Scrap Tires: A Resource and Technology Evaluation of Tire Pyrolysis and Other Selected Alternate Technologies.  

National Technical Information Service (NTIS)

The results of a technical and economic evaluation of scrap tire pyrolysis are presented and some other alternative uses for scrap tires are discussed. A scrap tire, by definition in this report, is one for which there is no economic end use. Information ...

J. Dodds W. F. Domenico D. R. Evans L. W. Fish P. L. Lassahn

1983-01-01

353

Recycling lead to recover refractory precious metals  

NASA Astrophysics Data System (ADS)

Lead recycling has many benefits. For example, it provides an alternative to virgin lead, thereby avoiding the environmental impacts of primary lead smelting. In addition, as with other secondary metal operations, it consumes less energy at a lower cost than primary production. An emerging process has been evaluated in which these attributes are leveraged to process refractory precious metals ores. Direct cyanidation of refractory gold and silver ore yields poor gold and silver recoveries. In fact, some ores are simply not amenable to direct cyanidation. The process described in this paper consists of smelting lead-bearing material together with argentopyrite concentrate that contains precious metals. Sodium carbonate is used as a fluxing agent and scrap iron is used as a reductant. The reaction product is molten lead bullion enriched with the precious metals. Smelting recoveries of both silver and gold can be as high as 98%.

Parga, J. R.; Muzquiz, G. G.; Valenzuela, J. L.; Ojebuoboh, F. K.

2001-12-01

354

Recycling Improves USA  

Microsoft Academic Search

Changes are occurring in recycling that will improve the United States. There are significant improvements in the economy, environment and the health of Americans due to recycling efforts. Recycling will be shown as a superior option compared to landfill, incineration and virgin material processing. Many Case studies will be discussed that show how communities are making long-term decisions for recycling.

Luke Monroe

355

Analytical laboratories method No. 4011 - radiometric determination of uranium-232 in uranium bearing materials  

SciTech Connect

The method is designed for use on recycled uranium materials and is applicable to materials that will yield at least 100 mg of uranium. Typical analysis time is 24 to 30 hours. U-232 can be measured to a lower limit of detection of 1 ppb (U-235 basis).

Not Available

1987-01-14

356

Retrieval of buried depleted uranium from the T-1 trench  

SciTech Connect

The Trench 1 remediation project will be conducted this year to retrieve depleted uranium and other associated materials from a trench at Rocky Flats Environmental Technology Site. The excavated materials will be segregated and stabilized for shipment. The depleted uranium will be treated at an offsite facility which utilizes a novel approach for waste minimization and disposal through utilization of a combination of uranium recycling and volume efficient uranium stabilization.

Burmeister, M. [Rocky Mountain Remediation Services, Golden, CO (United States); Castaneda, N. [Dept. of Energy, Golden, CO (United States). Rocky Flats Field Office; Greengard, T. [Kaiser-Hill Co., Golden, CO (United States)]|[Science Applications International Corp. (United States); Hull, C. [S.M. Stoller Corp., Boulder, CO (United States); Barbour, D.; Quapp, W.J. [Starmet Corp. (United States)

1998-07-01

357

An econometric model of the U.S. secondary copper industry: Recycling versus disposal  

USGS Publications Warehouse

In this paper, a theoretical model of secondary recovery is developed that integrates microeconomic theories of production and cost with a dynamic model of scrap generation and accumulation. The model equations are estimated for the U.S. secondary copper industry and used to assess the impacts that various policies and future events have on copper recycling rates. The alternatives considered are: subsidies for secondary production, differing energy costs, and varying ore quality in primary production. ?? 1990.

Slade, M. E.

1980-01-01

358

Recycle Experience of Dismantled Cask Handling Crane by Surface Removal Sampling at Kori Unit No.1  

Microsoft Academic Search

The Kori No.1, which began operation in 1978, replaced its cask handling crane in 2000. To prove the safety of recycling and reuse of crane scrap, a particular calculation method for surface contamination was used. Because surface radioactive contamination of steel is limited to a few-microns-thick layer, we can calculate the total(removable and fixed contamination) activity of the sample conservatively

K. D. Kim; C. Y. Baeg; J. K. Son; H. S. Kim; J. A. Ha; M. J. Song

2002-01-01

359

Use of Scrap Rubber in Asphalt Pavement Surfaces.  

National Technical Information Service (NTIS)

Scrap tire rubber was mixed into an asphalt concrete wearing course to study the effect of ice disbonding from the pavement surface under traffic. Rubber contents of 0, 3, 6, and 12% by weight were studied. Initial laboratory ice disbonding test results l...

R. A. Eaton R. J. Roberts R. R. Blackburn

1991-01-01

360

Copper Removal from Molten Ferrous Scrap: A Pilot Plant Study.  

National Technical Information Service (NTIS)

The removal of copper from molten carbon - saturated iron melts by treatment with sodium sulfate compacts has been successfully demonstrated on a pilot-plant scale. Major equipment involved a one-ton arc furnace for melting ferrous scrap and a one and one...

H. V. Makar R. E. Brown

1974-01-01

361

Feasibility of re-melting NORM-contaminated scrap metal  

Microsoft Academic Search

Naturally occurring radioactive materials (NORM) sometimes accumulate inside pieces of equipment associated with oil and gas production and processing activities. Typically, the NORM accumulates when radium that is present in solution in produced water precipitates out in scale and sludge deposits. Scrap equipment containing residual quantities of these NORM-bearing scales and sludges can present a waste management problem if the

S. J. Winters; K. P. Smith

1999-01-01

362

Aromatic chemicals from the catalytic pyrolysis of scrap tyres  

Microsoft Academic Search

Scrap tyres were pyrolysed in a fixed bed reactor and the evolved pyrolysis gases were passed through a secondary catalytic reactor. The main objective was to maximise the concentration of single ring aromatic compounds, which are of known higher commercial value. Three types of zeolite catalyst were examined of different surface acidity and pore size. The influence of catalyst to

Paul T Williams; Alexander J Brindle

2003-01-01

363

BRONZE FOUNDRY SCRAP STORED IN THE BINS TO THE RIGHT ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

BRONZE FOUNDRY SCRAP STORED IN THE BINS TO THE RIGHT ARE LOADED INTO THE BOTTOM DROPPING CHARGE BUCKET IN THE BACKGROUND BEFORE BEING CHARGED INTO ONE OF THE ELECTRIC ARC FURNACES. - Stockham Pipe & Fittings Company, Brass Foundry, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL

364

INTERIOR VIEW, LOOKING NORTH, TOWARDS CUPOLA WHERE SCRAP METAL AND ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

INTERIOR VIEW, LOOKING NORTH, TOWARDS CUPOLA WHERE SCRAP METAL AND OTHER COMPONENTS ARE MELTED TO CREATE DUCTILE IRON. BRIGHT FLASH IN BACKGROUND RESULTS FROM MOLTEN METAL (DUCTILE IRON) BEING POURED FROM CUPOLA INTO TRANSFER LADLE - McWane Cast Iron Pipe Company, Pipe Casting Area, 1201 Vanderbilt Road, Birmingham, Jefferson County, AL

365

Thermodynamic analysis of contamination by alloying elements in aluminum recycling.  

PubMed

In previous studies on the physical chemistry of pyrometallurgical processing of aluminum scrap, only a limited number of thermodynamic parameters, such as the Gibbs free energy change of impurity reactions and the variation of activity of an impurity in molten aluminum, were taken into account. In contrast, in this study we thermodynamically evaluated the quantitative removal limit of impurities during the remelting of aluminum scrap; all relevant parameters, such as the total pressure, the activity coefficient of the target impurity, the temperature, the oxygen partial pressure, and the activity coefficient of oxidation product, were considered. For 45 elements that usually occur in aluminum products, the distribution ratios among the metal, slag, and gas phases in the aluminum remelting process were obtained. Our results show that, except for elements such as Mg and Zn, most of the impurities occurred as troublesome tramp elements that are difficult to remove, and our results also indicate that the extent to which the process parameters such as oxygen partial pressure, temperature, and flux composition can be changed in aluminum production is quite limited compared to that for iron and copper production, owing to aluminum's relatively low melting point and strong affinity for oxygen. Therefore, the control of impurities in the disassembly process and the quality of scrap play important roles in suppressing contamination in aluminum recycling. PMID:20536230

Nakajima, Kenichi; Takeda, Osamu; Miki, Takahiro; Matsubae, Kazuyo; Nakamura, Shinichiro; Nagasaka, Tetsuya

2010-07-15

366

Assessment of potential radiation exposures by uncontrolled recycle or reuse of radioactive scrap metals  

Microsoft Academic Search

With current waste monitoring technology it is reasonable to assume that much of the material designated as low level waste, generated within nuclear facilities, is in fact uncontaminated. A criterion for uncontrolled disposal of low-level radioactive contaminated waste is that the radiation exposure of the public and of each individual caused by this disposal is so low that radiation protection

Sang-Yoon Lee; Kun Jai Lee

1999-01-01

367

Recycle Used Oil on America Recycles Day.  

ERIC Educational Resources Information Center

Explains that motor oils can be reused and recycled. Educates students about environmental hazards and oil management and includes classroom activities. Addresses the National Science Education Standards. (YDS)

White, Boyd W.

2000-01-01

368

Recycled Art: Create Puppets Using Recycled Objects.  

ERIC Educational Resources Information Center

Presents an activity from "Healthy Foods from Healthy Soils" for making puppets using recycled food packaging materials. Includes background information, materials, instructions, literature links, resources, and benchmarks. (NB)

Clearing, 2003

2003-01-01

369

Waste recycling in the textile industry. (Latest citations from World Textile abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of fibrous and other waste materials from textile production. Citations discuss recycled materials such as cellulosic and polymeric wastes, cloth scraps, cottons, wools, and waste dusts for use in fabric products, building materials, thermal insulation, textile-reinforced materials, and geotextiles. Equipment for collecting, sorting, and processing textile wastes is also discussed. Citations concerning heat recovery and effluent treatment in the textile industry are covered in separate bibliographies.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1997-11-01

370

Waste recycling in the textile industry. (Latest citations from World Textile Abstracts database). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of fibrous and other waste materials from textile production. Citations discuss recycled materials such as cellulosic and polymeric wastes, cloth scraps, cottons, wools, and waste dusts for use in fabric products, building materials, thermal insulation, textile-reinforced materials, and geotextiles. Equipment for collecting, sorting, and processing textile wastes is also discussed. Citations concerning heat recovery and effluent treatment in the textile industry are covered in separate bibliographies. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-10-01

371

Waste recycling in the textile industry. (Latest citations from World Textile Abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of fibrous and other waste materials from textile production. Citations discuss recycled materials such as cellulosic and polymeric wastes, cloth scraps, cottons, wools, and waste dusts for use in fabric products, building materials, thermal insulation, textile-reinforced materials, and geotextiles. Equipment for collecting, sorting, and processing textile wastes is also discussed. Citations concerning heat recovery and effluent treatment in the textile industry are covered in separate bibliographies. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-10-01

372

Waste recycling in the textile industry. (Latest citations from World Textile abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of fibrous and other waste materials from textile production. Citations discuss recycled materials such as cellulosic and polymeric wastes, cloth scraps, cottons, wools, and waste dusts for use in fabric products, building materials, thermal insulation, textile-reinforced materials, and geotextiles. Equipment for collecting, sorting, and processing textile wastes is also discussed. Citations concerning heat recovery and effluent treatment in the textile industry are covered in separate bibliographies. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-06-01

373

Waste recycling in the textile industry. (Latest citations from World Textile Abstracts). Published Search  

SciTech Connect

The bibliography contains citations concerning the recycling of fiberous and other waste materials from textile production. The use of recyclable materials such as cellulosic and polymeric wastes, cloth scraps, fiber waste, glass fiber wastes, and waste dusts for use in textile products, insulation, paneling and other building supplies, yarns, roping, and pavement materials are considered. Equipment for collecting, sorting, and processing textile wastes is also discussed. Heat recovery and effluent treatment in the textile industry are referenced in related bibliographies. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1992-07-01

374

Study of Recycled and Virgin Compounded Metal Injection Moulded Feedstock for Stainless Steel 630  

NASA Astrophysics Data System (ADS)

Fine rounded powders preferable for metal injection moulding (MIM) are expensive. This forces MIM makers to recycle green scraps, for example, the runner system and defected green parts. This is particularly necessary for injection moulded small parts where parts are only a small portion of the injection short size. There is very little published data, although recycling feedstock has been practise throughout the industry. This work aims at investigating the effects of recycled stainless steel 630 feedstock content on the density, mechanical properties, dimensional changes and microstructure. Five batches of compounded virgin and recycled feedstock were studies from 0% to 100% recycled feedstock with the increment of 25%. Homogenously compounded feedstock was injected using the same injection condition. Subsequently, green parts were debinded and sintered at 1325°C for 2 hours in argon atmosphere. The results suggest that the green density increases linearly with increasing percentage of recycled feedstock because the polymeric binder was broken down during previous process. However, the sintered density remains nominally constant. As a result, the mechanical properties and microstructure of sintered parts are independent of recycled feedstock content. However, the volumetric and linear shrinkage decreases linearly with the increase in percentage of recycled feedstock. The difference in shrinkage is vital to dimensional control during commercial production. For example, only 4.5% of recycled feedstock can be added to virgin feedstock if a tolerance of ±0.3 mm is required for a 25 mm MIM part.

Manonukul, Anchalee; Likityingwara, Warakij; Rungkiatnawin, Phataraporn; Muenya, Nattapol; Amoranan, Suttha; Kittinantapol, Witoo; Surapunt, Suphachai

375

Interlaboratory comparison program for nondestructive assay of prototype uranium reference materials  

Microsoft Academic Search

The US Department of Energy (DOE), New Brunswick Laboratory (NBS), designed and administered an interlaboratory comparison program based on the measurement of NBL-produced prototype uranium nondestructive assay (NDA) reference materials for scrap and waste. The objectives of the program were to evaluate the reliability of NDA techniques as applied to nuclear safeguards materials control and accountability needs and to investigate

N. M. Trahey; M. M. Smith; A. M. Voeks; J. T. Bracey

1986-01-01

376

Definition of prominent thermal mechanisms associated with the buoyancy-induced transport of hafnium-carbide within a solidifying uranium-hafnium alloy  

Microsoft Academic Search

Environmental concerns over uranium wastes generated interest in using existing uranium stockpiles as feed materials. One obstacle to recycling is accumulation of carbon that can degrade as-cast mechanical properties. A program was begun to develop a casting procedure capable of reducing the C content in components made from recycled uranium to levels comparable with virgin feed stock. Trace amounts of

M. J. Taylor; G. Mackiewicz-Ludtka

1992-01-01

377

The recycling dilemma for advanced materials use: Automobile materials substitution  

SciTech Connect

This paper discusses the difficulties associated with imposing recycling imperatives upon advanced materials development by examining the case of automotive materials substitution and its impacts upon the recyclability of the automobile. Parallels are drawn between today's issues, which focus upon the recyclability of the increasing polymeric fraction in automobile shredder fluff, and the junked automobile problem of the 1960's, when the problem of abandoned automobiles became a part of the environmental and legislative agenda in the US and overseas. In the 1960's, both the source and the resolution of the junk automobile problem arose through a confluence of technological and economic factors, rather than through any set of regulatory influences. The rise of electric arc furnace steelmaking and the development of the automobile shredder were sufficient to virtually eliminate the problem - so much so that today's problems are incorrectly viewed as novelties. Today's automobile recycling problem again derives from technological and economic factors, but regulatory influences have spurred some of them. While there are no lack of technological solutions to the problem of automobile shredder fluff, none of these solutions yet provides scrap processors with the kind of profit opportunity necessary to implement them. In some ways, it is implicit in advanced materials markets that there is little to no demand for recycled forms of these materials, and, in the absence of these markets, there are few reasons to expect that the solution to today's problems will be quite so neat.

Field, F.R. III; Clark, J.P. (Massachusetts Inst. of Tech., Cambridge (United States))

1991-01-01

378

Uranium: Prices, rise, then fall  

SciTech Connect

Uranium prices hit eight-year highs in both market tiers, $16.60/lb U{sub 3}O{sub 8} for non-former Soviet Union (FSU) origin and $15.50 for FSU origin during mid 1996. However, they declined to $14.70 and $13.90, respectively, by the end of the year. Increased uranium prices continue to encourage new production and restarts of production facilities presently on standby. Australia scrapped its {open_quotes}three-mine{close_quotes} policy following the ouster of the Labor party in a March election. The move opens the way for increasing competition with Canada`s low-cost producers. Other events in the industry during 1996 that have current or potential impacts on the market include: approval of legislation outlining the ground rules for privatization of the US Enrichment Corp. (USEC) and the subsequent sales of converted Russian highly enriched uranium (HEU) from its nuclear weapons program, announcement of sales plans for converted US HEU and other surplus material through either the Department of Energy or USEC, and continuation of quotas for uranium from the FSU in the United States and Europe. In Canada, permitting activities continued on the Cigar Lake and McArthur River projects; and construction commenced on the McClean Lake mill.

Pool, T.C.

1997-03-01

379

One million served: Rhode Island`s recycling facility  

SciTech Connect

Rhode Island`s landfill and adjacent materials recovery facility (MRF) in Johnston, both owned by the quasi-public Rhode Island Resource Recovery Corp. (RIRRC, Johnston), serve the entire state. The $12-million recycling facility was built in 1989 next to the state`s sole landfill, the Central Landfill, which accepts only in-state trash. The MRF is operated for RIRRC by New England CRInc. (Hampton, N.H.), a unit of Waste Management, Inc. (WMI, Oak Brook, Ill.). It handles a wide variety of materials, from the usual newspaper, cardboard, and mixed containers to new streams such as wood waste, scrap metal, aseptic packaging (milk and juice boxes), and even textiles. State municipalities are in the process of adding many of these new recyclable streams into their curbside collection programs, all of which feed the facility.

Malloy, M.G.

1997-11-01

380

International Recycling of LLW Metals  

Microsoft Academic Search

Melting of radioactive scrap metal has been successfully practiced for more than 15 years, with approximately 60,000 tons of steel being processed into beneficial reuse applications. This process has converted radioactive scrap metal at a licensed facility into useful products such as shield blocks, security barriers and shield containers. These products are used within the nuclear industry, such as nuclear

T. Eshleman; J. Jansen; Sawada Shinya

2008-01-01

381

Electrolytic method for recovery of lead from scrap batteries: scale-up study using 20-liter multielectrode cell  

SciTech Connect

Prior work at the Bureau of Mines resulted in the successful development of a bench-scale, combination electrorefining-electrowinning method for recycling the lead from scrap batteries using waste fluosilicic acid (H/sub 2/SiF/sub 6/) as electrolyte. This paper describes larger scale experiments. Anodes cast from scrap battery lead were electrorefined in a 20-L multielectrode cell for 3 to 7 days. The anodes, containing 2 to 2.5 pct antimony, were ideal for obtaining firm and adherent slime blankets. Cathode deposits, assaying 99.99 pct Pb, were obtained, with current efficiencies near 99 pct. Sludge leaching was done in 100-L tanks followed by filtering in 61 cm square vacuum pan filters. Lead of greater than 99.99-pct purity was recovered from the filtrate by electrowinning in a 20-L multielectrode cell using insoluble PbO/sub 2/-Ti (lead dioxide-coated titanium) anodes and pure lead cathodes. The fluosilicic acid electrolyte depleted in lead was repeatedly recycled to leach more sludge, and there was no problem with impurity buildup. The amount of PbO/sub 2/ formed on the anodes during electrowinning was less than 1 pct of the total lead deposited on the cathodes, as long as the phosphorus concentration in the electrolyte was greater than 1.3 g/L. Emissions of lead in air were less than 10 ..mu..g/m/sup 3/, well below the proposed OSHA limit of 50 ..mu..g/m/sup 3/.

Lee, A.Y.; Cole, E.R. Jr.; Paulson, D.L.

1984-01-01

382

Recycling Rules: Understanding Recycling and a MRF  

NSDL National Science Digital Library

In this activity, learners simulate the separation techniques that materials recovery facilities (MRFs) use and then design their own series of recycling techniques. Learners identify four ways recyclable materials can be separated and sorted at a MRF: conveyor belts, blowers, flotation, and magnetism.

Keep America Beautiful, Inc.

2010-01-01

383

Newell's metals recycling tradition  

Microsoft Academic Search

Since 1976, Newell Recycling Co., Inc.'s metals recycling facility in Atlanta has been processing everything from aluminum cans to automobiles. It is a full-service metals recycling center, handling both ferrous and non-ferrous metals. Newell Recycling takes metal components and machinery and processes it into usable feedstock for metal smelters and steel mills. The facility is split into five basic processing

Dabaie

1994-01-01

384

Recycling of automotive aluminum  

Microsoft Academic Search

With the global warming of concern, the secondary aluminum stream is becoming an even more important component of aluminum production and is attractive because of its economic and environmental benefits. In this work, recycling of automotive aluminum is reviewed to highlight environmental benefits of aluminum recycling, use of aluminum alloys in automotive applications, automotive recycling process, and new technologies in

Jirang CUI; Hans J. ROVEN

2010-01-01

385

The future of recycling  

Microsoft Academic Search

Recycling in general and metal recycling in particular, many believe, enjoy a very bright future. As resource depletion, environmental concerns, and other factors drive primary production costs up, the relative importance of recycling in supplying the material needs of society will grow. This optimistic view, however, may paint an overly rosy and misleading picture.A large portion of secondary metal production

John E. Tilton

1999-01-01

386

Anthropogenic nickel cycle: insights into use, trade, and recycling.  

PubMed

The anthropogenic nickel cycle for the year 2000 was analyzed using a material flow analysis at multiple levels: 52 countries, territories, or country groups, eight regions, and the planet. Special attention was given to the trade in nickel-containing products at different stages of the cycle. A new circular diagram highlights process connections, the role and potential of recycling, and the relevance of trade at different life stages. The following results were achieved. (1) The nickel cycle is dominated by six countries or territories: USA, China and Hong Kong, Japan, Germany, Taiwan, and South Korea; only China also mines some of its nickel used. (2) Nickel is mostly used in alloyed form in stainless steels (68%). (3) More scrap is used for the production of stainless steels (42%) than for other first uses (11%). (4) Industrial machinery is the largest end use category for nickel (25%), followed by buildings and infrastructure (21%) and transportation (20%). (5) 57% of discarded nickel is recycled within the nickel and stainless steel industries, and 14% is lost to other metal markets where nickel is an unwanted constituent of carbon steel and copper alloy scrap. PMID:18522124

Reck, Barbara K; Müller, Daniel B; Rostkowski, Katherine; Graedel, T E

2008-05-01

387

A method for leaching or dissolving gold from ores or precious metal scrap  

NASA Astrophysics Data System (ADS)

The hydrometallurgical leaching of native gold from gold-bearing ores or the dissolution of gold metal during the recycling of electronic and precious metal scrap is performed every day using hazardous chemicals such as sodium cyanide or aqua regia. These chemicals represent health and safety risks for workers and a serious threat for the environment. However, even if several other reagents are known to dissolve gold at the laboratory scale, none of these are used industrially. Hot mixtures of hydrochloric acid with strong oxidizing compounds are known to generate in-situ nascent chlorine which is capable of dissolving gold efficiently. In this study, the authors investigated the capability of a hot mixture of hydrochloric acid and ground manganese (IV) oxide to dissolve gold metal either under atmospheric or pressurized conditions. The best result was obtained under a pressure of 639 kPa at 90°C with a dissolution rate of 0.250 g·cm-2h-1 and it was compared to that reported in the literature for other industrial reagents.

Geoffroy, Nicolas; Cardarelli, François

2005-08-01

388

Elemental analysis of steel scrap metals and minerals by laser-induced breakdown spectroscopy  

NASA Astrophysics Data System (ADS)

The atomic emission of laser-induced plasma on steel samples has been studied for quantitative elemental analysis. The plasma has been created with 8 ns wide pulses using the second-harmonic from a Q-switched Nd:YAG laser, in air at atmospheric pressure. The plasma emission is detected with temporal resolution, using an Echelle spectrometer of wide spectral range (300-900 nm) combined with an intensified charge coupled device camera. A plasma temperature of 7800 ± 400 K is determined using the Boltzmann plot method, from spectra obtained under optimized experimental conditions. As an example of an industrial application the concentration of copper in scrap metals is studied, which is an important factor to determine the quality of the samples to recycle. Cu concentrations down to 200 ppm can be detected. Another application of the laser-induced plasma spectroscopy method is the measurement of the nickel and copper concentrations in an iron-containing sample of reduced magma from the 1870s expedition to western Greenland by Adolf Erik Nordenskiöld. Different spectral lines of nickel are used for calibration, and their results are compared.

Vieitez, Maria Ofelia; Hedberg, Jonas; Launila, Olli; Berg, Lars-Erik

2005-08-01

389

Wastes from plutonium conversion and scrap recovery operations  

SciTech Connect

This report deals with the handling of defense-related wastes associated with plutonium processing. It first defines the different waste categories along with the techniques used to assess waste content. It then discusses the various treatment approaches used in recovering plutonium from scrap. Next, it addresses the various waste management approaches necessary to handle all wastes. Finally, there is a discussion of some future areas for processing with emphasis on waste reduction. 91 refs., 25 figs., 4 tabs.

Christensen, D.C.; Bowersox, D.F.; McKerley, B.J.; Nance, R.L.

1988-03-01

390

On the pyrolysis kinetics of scrap automotive tires  

Microsoft Academic Search

Pyrolysis kinetics of scrap tires of passenger car and truck have been investigated thermogravimetrically under heating rates of 5, 10, 20 and 30K\\/min and temperature range 373–1273K in nitrogen. The results show that the initial reaction temperatures are 482–521K for the tire of passenger car and 458–511K for truck tire. Both tires exhibit similar behaviors that the initial reaction temperature

J. H. Chen; K. S. Chen; L. Y. Tong

2001-01-01

391

Scrap metal management issues associated with naturally occurring radioactive material  

Microsoft Academic Search

Certain industrial processes sometimes generate waste by-products that contain naturally occurring radioactive material (NORM) at elevated concentrations. Some industries, including the water treatment, geothermal energy, and petroleum industries, generate scrap metal that may be contaminated with NORM wastes. Of these three industries, the petroleum industry probably generates the largest quantity of NORM-contaminated equipment, conservatively estimated at 170,000 tons per year.

K. P. Smith; D. L. Blunt

1995-01-01

392

4. VIEW OF PLUTONIUM CANISTER ON CHAINVEYOR. SCRAP PLUTONIUM WAS ...  

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. VIEW OF PLUTONIUM CANISTER ON CHAINVEYOR. SCRAP PLUTONIUM WAS COLLECTED INTO CANS AT INDIVIDUAL WORKSTATIONS. THE CANS WERE TRANSFERRED VIA THE CHAIN CONVEYOR TO A WORKSTATION IN MODULE C WHERE THE MATERIAL WAS COMPRESSED INTO BRIQUETTES FOR LATER USE. (6/20/93) - Rocky Flats Plant, Plutonium Manufacturing Facility, North-central section of Plant, just south of Building 776/777, Golden, Jefferson County, CO

393

EFFECTOF ISOLATION WALL USING SCRAP TIRE ON GROUND VIBRATION REDUCTION  

NASA Astrophysics Data System (ADS)

Some countermeasure methods against the environmental ground vibration caused by some traffic vibrations have been proposed so far. The authors have developed a new type ground vibration isolation wall using scrap tire, and evaluated its effectiveness on the ground vibration reduction by full scale field tests. In this paper, the authors discussed and examined the effectiveness of the developed countermeasure method by two field tests. The one concerns on the effect of scrap tire as soft material of vibration isolation wall, and the other on the effect of the developed countermeasure method practically applied in a residential area close to monorail traffic. As the results, it was elucidated that the ground vibration of 2-3 dB was reduced in case of two times volume of the soft material, the conversion ratio of the vibration energy of the soft material to the kinetic energy was higher than that of the core material of PHC pile, the vibration acceleration of 0.19 - 1.26 gal was reduced by the developed countermeasure method in case of the monorail traffic, and the vibration reduction measured behind the isolation wall agreed well with the proposed theoretical value, together with confirming the effectiveness of the ground vibration isolation wall using scrap tire as the countermeasure method against the environmental ground vibration.

Kashimoto, Takahiko; Kashimoto, Yusuke; Hayakawa, Kiyoshi; Matsui, Tamotsu; Fujimoto, Hiroaki

394

A rationale for recycling  

NASA Astrophysics Data System (ADS)

The decision as to whether to recycle discarded objects or not has traditionally been made on a simple financial basis. However, over the last few years a popular movement has sprung up which regards recycling as a good in itself, and this movement finds itself at odds with the present financial basis for recycling. In this paper a rationale for recycling is worked out in an attempt to resolve this conflict. It is concluded that the normal market signals do not provide a proper basis for recycling decisions and that this market failure must be corrected by government intervention. However, this intervention should not take the form of uncritical support for recycling. Rather the societal objectives of individual recycling proposals should be identified and the proposal should then be evaluated in terms of whether it would achieve these objectives more effectively than some alternative action.

Evans, David G.

1994-05-01

395

Original Acid Leaching of Indium-Lead-Tin Alloy Wire Scrap  

Microsoft Academic Search

Acid leaching of indium-Iead-tin alloy wire scrap has been studied. An experimental study was excuted to produce leaching liquor for subsequent sepa­ ration of the concerned metals from the scrap material. Two leaching solu­ tions were investigated; hydrochloric acid and hydrochloric-nitric acid oxida­ tion leaching. Parameters affecting leaching processes such as time, temperature, acid concentration and acid: scrap stoichiometric ratio

M. A. Barakat; K. KOIKE

396

Rapid Separation Methods to Characterize Actinides and Metallic Impurities in Plutonium Scrap Materials at SRS  

SciTech Connect

The Nuclear Materials Stabilization and Storage Division at SRS plans to stabilize selected plutonium scrap residue materials for long term storage by dissolution processing and plans to stabilize other plutonium vault materials via high-temperature furnace processing. To support these nuclear material stabilization activities, the SRS Analytical Laboratories Department (ALD) will provide characterization of materials required prior to the dissolution or the high-firing of these materials. Lab renovations to install new analytical instrumentation are underway to support these activities that include glove boxes with simulated-process dissolution and high- pressure microwave dissolution capability. Inductively-coupled plasma atomic emission spectrometry (ICP-AES), inductively- coupled mass spectrometry (ICP-MS) and thermal-ionization mass spectrometry (TIMS) will be used to measure actinide isotopics and metallic impurities. New high-speed actinide separation methods have been developed that will be applied to isotopic characterization of nuclear materials by TIMS and ICP-MS to eliminate isobaric interferences between Pu-238 /U- 238 and Pu-241/Am-241. TEVA Resin, UTEVA Resin, and TRU Resin columns will be used with vacuum-assisted flow rates to minimize TIMS and ICP-MS sample turnaround times. For metallic impurity analysis, rapid column removal methods using UTEVA Resin, AGMP-1 anion resin and AG MP-50 cation resin have also been developed to remove plutonium and uranium matrix interferences prior to ICP-AES and ICP- MS measurements.

Maxwell, S.L. III [Westinghouse Savannah River Company, AIKEN, SC (United States); Jones, V.D.

1998-07-01

397

Sink-float ferrofluid separator applicable to full scale nonferrous scrap separation  

NASA Technical Reports Server (NTRS)

Design and performance of a ferrofluid levitation separator for recovering nonferrous metals from shredded automobiles are reported. The scrap separator uses an electromagnet to generate a region of constant density within a pool of ferrofluid held between the magnetic poles; a saturated kerosene base ferrofluid as able to float all common industrial metals of interest. Conveyors move the scrap into the ferrofluid for separation according to density. Results of scrap mixture separation studies establish the technical feasibility of relatively pure aluminum alloy and zinc alloy fractions from shredded automobile scrap by this ferrofluid levitation process. Economic projections indicate profitable operation for shredders handling more than 300 cars per day.

1973-01-01

398

Methods for increasing the efficiency of heating scrap metal in electric arc furnaces  

NASA Astrophysics Data System (ADS)

The type of heating, which determines heat transfer from an external energy source to a metallic charge, plays a key role in the process of preliminary heating of scrap metal. The type of charge heating during preliminary heating of scrap metal mainly determines the average scrap metal heating temperature and the formation of harmful substances. This article considers the existing types of charge heating in EAF baths and shaft heaters. The types of scrap metal heating that increase the energy efficiency and weaken the ecological problems related to this process in electric furnace steelmaking units are found.

Raile, V.

2013-06-01

399

Guidance document for multi-facility recycle/reuse/free release of metals from radiological control areas  

SciTech Connect

Approximately 15% of the Low Level Waste (LLW) produced at Los Alamos consists of scrap metal equipment and materials. The majority of this material is produced by decommissioning and modification of existing facilities. To address this waste stream, Los Alamos has developed a scrap metal recycling program that is operated by the Environmental Stewardship Office to minimize the amount of LLW metal sent for LLW landfill disposal. Past practice has supported treating all waste metals generated within RCA`s as contaminated. Through the metal recycling project, ESO is encouraging the use of alternatives to LLW disposal. Diverting RSM from waste landfill, disposal protects the environment, reduces the cost of operation, and reduces the cost of maintenance and operation at landfill sites. Waste minimization efforts also results in a twofold economic reward: The RSM has a market value and decontamination reduces the volume and therefore the amount of the radioactive waste to be buried within landfills.

Gogol, S.; Starke, T.

1997-08-15

400

Material control and accountability aspects of safeguards for the USA ²³³U\\/TH fuel recycle plant  

Microsoft Academic Search

Two fuel cycles are considered. The highly enriched uranium (HEU) cycle uses uranium enriched 93% in ²³⁵U as the initial fuel. The medium enriched uranium (MEU) cycle uses uranium with a ²³⁵U enrichment less than 20% as its initial fuel. In both, ²³³U is bred from thorium. The HEU ²³⁵U and the ²³³U of both cycles are recycled. The MEU

J. A. Jr. Carpenter; S. R. McNeany; P. Angelini; N. D. Holder; L. Abraham

1979-01-01

401

Depleted Uranium  

MedlinePLUS

... Military Sexual Trauma Radiation Chemical, Biological, and Radiological Weapons Cold Injury Hearing Impairment Visual Impairment Former Prisoners ... from natural uranium used in nuclear reactors or weapons leaves “depleted” uranium. DU has 40 percent less ...

402

Review of PennDOT Publication 408 for the use of recycled co-product materials: Summary recommendations. Final report  

SciTech Connect

The purpose of this project is to decrease the institutional or perceived institutional barriers for the use of recycled and co-product materials including glass, steel slag, foundry sand, fly ash, shingle tabs, reclaimed Portland cement concrete, and scrap tires in the Pennsylvania Department of Transportation`s (PennDOT) Publications 408, Commonwealth of Pennsylvania Department of Transportation Specifications. This report reviews potential uses of each material, identifies the project that used these materials, and provides direction for future specification development.

Van Tassel, E.L.; Tikalsky, P.J.; Christensen, D.W.

1999-04-30

403

Study of thermal and mechanical properties of virgin and recycled poly(ethylene terephthalate) before and after injection molding  

Microsoft Academic Search

In this study, we compared the thermal properties (glass transition, melting point and crystallinity) and mechanical properties (Young’s modulus, elongation at break and impact strength) of post-consumer poly(ethylene terephthalate) (PET) bottles with those of the virgin resin. We studied two types of scraps of recycled PET: one arising from homogeneous deposits of bottles and the other of heterogeneous deposits soiled

N. Torres; J. J. Robin; B. Boutevin

2000-01-01

404

Definition of prominent thermal mechanisms associated with the buoyancy-induced transport of hafnium-carbide within a solidifying uranium-hafnium alloy.  

National Technical Information Service (NTIS)

Environmental concerns over uranium wastes generated interest in using existing uranium stockpiles as feed materials. One obstacle to recycling is accumulation of carbon that can degrade as-cast mechanical properties. A program was begun to develop a cast...

M. J. Taylor G. Mackiewicz-Ludtka

1992-01-01

405

Enriched Uranium  

NSDL National Science Digital Library

This Wikipedia website provides information about the various concentrations of uranium used for different applications. Topics include a brief description of the grades of uranium and methods of isotope separation. There are also links to other aspects of uranium enrichment and related information. This information lays the foundation for informed discussion about the potential of nuclear energy and the risks of nuclear proliferation.

Wikipedia

406

Factors Influencing Household Recycling Behavior  

Microsoft Academic Search

To investigate factors encouraging or deterring recycling, telephone interviews were used to study recycling behavior, attitudes, and knowledge of 221 randomly selected adults in a suburban city that had begun a citywide curbside recycling program within the past year. Approximately 40% reported participation in the curbside recycling program, and nearly 20% more claimed that their household had been recycling in

Stuart Oskamp; Maura J. Harrington; Todd C. Edwards; Deborah L. Sherwood; Shawn M. Okuda; Deborah C. Swanson

1991-01-01

407

Solids loading evaluation for HB-line scrap recovery filters  

SciTech Connect

The HB-Line Scrap Recovery facility uses wire screen filters to remove solids from plutonium-containing solutions transferred from the slab tank dissolvers. At times, the accumulation of solids is large enough to cause blinding (i.e., pluggage) of the filters. If the solids contain undissolved plutonium, significant accumulation of fissile material could impact operations. To address this potential issue, experiments were performed to define the minimum solids required to completely blind a filter. The solids loading experiments were performed by arranging 25- and 10-{micro}m HB-Line filters in series to simulate the equipment in the scrap recovery process. Separate tests were performed using coarse and fine glass frit and cerium oxide powder suspended in 35 wt% sodium nitrate solution using a small turbine mixer. The solution and solids were transferred from a reservoir through the filter housings by vacuum. In each case, the 25-{micro}m filter blinded first and was full of wet cake. After drying and accounting for the sodium nitrate in the filter cake, the following results were obtained. The results of the solids loading tests demonstrated that at least 800 g of solids accumulated in the filter housing before flow stopped. The actual amount of collected material was dependent upon the physical properties of the solids such as density and particle size. The mass of solids collected by the blinded 25-{micro}m filter increased when successively finer solids were used in the experiments. Based on these results, one should anticipate that filters in the HB-Line Scrap Recovery Facility have the potential to collect similar quantities of material before transfer of solution from the dissolvers is severely impacted.

Crowder, M.L.

2000-08-08

408

Recycling of waste printed circuit boards: a review of current technologies and treatment status in China.  

PubMed

From the use of renewable resources and environmental protection viewpoints, recycling of waste printed circuit boards (PCBs) receives wide concerns as the amounts of scrap PCBs increases dramatically. However, treatment for waste PCBs is a challenge due to the fact that PCBs are diverse and complex in terms of materials and components makeup as well as the original equipment's manufacturing processes. Recycle technology for waste PCBs in China is still immature. Previous studies focused on metals recovery, but resource utilization for nonmetals and further separation of the mixed metals are relatively fewer. Therefore, it is urgent to develop a proper recycle technology for waste PCBs. In this paper, current status of waste PCBs treatment in China was introduced, and several recycle technologies were analyzed. Some advices against the existing problems during recycling process were presented. Based on circular economy concept in China and complete recycling and resource utilization for all materials, a new environmental-friendly integrated recycling process with no pollution and high efficiency for waste PCBs was provided and discussed in detail. PMID:18829162

Huang, Kui; Guo, Jie; Xu, Zhenming

2009-05-30

409

Carbothermic Aluminum Production Using Scrap Aluminum As A Coolant  

DOEpatents

A process for producing aluminum metal by carbothermic reduction of alumina ore. Alumina ore is heated in the presence of carbon at an elevated temperature to produce an aluminum metal body contaminated with about 10-30% by wt. aluminum carbide. Aluminum metal or aluminum alloy scrap then is added to bring the temperature to about 900-1000.degree. C. and precipitate out aluminum carbide. The precipitated aluminum carbide is filtered, decanted, or fluxed with salt to form a molten body having reduced aluminum carbide content.

LaCamera, Alfred F. (Trafford, PA)

2002-11-05

410

Characteristics of the slags produced in the fusion of scrap steel by electric arc furnace  

Microsoft Academic Search

The use of industrial by-products requires knowledge of the characteristics of the materials. This work presents characterization data on slags produced in the fusion of scrap steel by electric arc furnace. It includes the chemical, mineralogical, and microstructural analysis and physical characteristics. Mineralogically, scrap steel from electric arc furnace are a mix of anhydrous calcium silicates and iron composites and

M. P. Luxán; R. Sotolongo; F. Dorrego; E. Herrero

2000-01-01

411

Application of pyrolized carbon black from scrap tires in pavement design (hot mix asphalt)  

Microsoft Academic Search

Various concepts and techniques have been developing for efficient and economical disposal and utilization of scrap tires. One of these is pyrolysis of scrap tires by a cooking process in order to break down the rubber into salable byproducts. Tire pyrolysis yields approximately 25% carbon black (CB) and is named pyrolized carbon black (PCB) in this study. Due to relatively

1995-01-01

412

Evaluation of two different scrap tires as hydrocarbon source by pyrolysis  

Microsoft Academic Search

The main objective of the present study is to investigate the effect of the polymer types in scrap tires on the pyrolysis products. Two different types of scrap tires (passenger car tire, PCT and truck tire, TT) have been pyrolyzed in a fixed bed reactor at the temperatures of 550, 650 and 800°C under N2 atmosphere. Pyrolysis products (gas, oil

Suat Ucar; Selhan Karagoz; Ahmet R. Ozkan; Jale Yanik

2005-01-01

413

Evaluation of products recovered from scrap tires for use as asphalt modifiers  

Microsoft Academic Search

Western Research Institute performed rheological tests and water sensitivity tests on asphalt cements that had been modified with carbonous residues obtained from the pyrolysis of scrap tires and waste motor oil. These tests are part of an ongoing program at the University of Wyoming Chemical Engineering Department to evaluate, as asphalt additives, solid carbonous products recovered from the scrap tire

McKay

1992-01-01

414

Enhanced high-solids anaerobic digestion of waste activated sludge by the addition of scrap iron.  

PubMed

Anaerobic digestion of waste activated sludge usually requires pretreatment procedure to improve the bioavailability of sludge, which involves considerable energy and high expenditures. This study proposes a cost-effective method for enhanced anaerobic digestion of sludge without a pretreatment by directly adding iron into the digester. The results showed that addition of Fe(0) powder could enhance 14.46% methane yield, and Fe scrap (clean scrap) could further enhance methane yield (improving rate 21.28%) because the scrap has better mass transfer efficiency with sludge and liquid than Fe(0) powder. The scrap of Fe with rust (rusty scrap) could induce microbial Fe(III) reduction, which resulted in achieving the highest methane yield (improving rate 29.51%), and the reduction rate of volatile suspended solids (VSS) was also highest (48.27%) among Fe powder, clean scrap and rusty scrap. PCR-DGGE proved that the addition of rusty scrap could enhance diversity of acetobacteria and enrich iron-reducing bacteria to enhance degradation of complex substrates. PMID:24657762

Zhang, Yaobin; Feng, Yinghong; Yu, Qilin; Xu, Zibin; Quan, Xie

2014-05-01

415

Bioleaching of metals from electronic scrap by moderately thermophilic acidophilic bacteria  

Microsoft Academic Search

The present work was aimed at studying the bioleachability of metals from electronic scrap by the selected moderately thermophilic strains of acidophilic chemolithotrophic and acidophilic heterotrophic bacteria. These included Sulfobacillus thermosulfidooxidans and an unidentified acidophilic heterotroph (code A1TSB) isolated from local environments. Among the strategies adapted to obtain enhanced metal leaching rates from electronic scrap, a mixed consortium of the

Sadia Ilyas; Munir A. Anwar; Shahida B. Niazi; M. Afzal Ghauri

2007-01-01

416

Economic Evaluation of an Electrolytic Process To Recover Lead from Scrap Batteries.  

National Technical Information Service (NTIS)

The publication is an economic evaluation of the Bureau of Mines electrolytic process for recovering lead from scrap lead-acid batteries. In this process, scrap batteries are crushed and separated into metal and sludge fractions. The metal fraction is cas...

T. A. Phillips

1986-01-01

417

Solvent recycle/contaminant reduction testing - Phase I, Task 3. Topical progress report, June 1994--December 1994  

SciTech Connect

The Department of Energy (DOE) is now faced with the task of meeting decontamination and decommissioning obligations at numerous facilities by the year 2019. Due to the tremendous volume of material involved, innovative decontamination technologies are being sought that can reduce the volumes of contaminated waste materials and secondary wastes requiring disposal. With sufficient decontamination, some of the material from DOE facilities could be released as scrap into the commercial sector for recycle, thereby reducing the volume of radioactive waste requiring disposal. Although recycling may initially prove to be more costly than current disposal practices, rapidly increasing disposal costs are expected to make recycling more and more cost effective. Additionally, recycling is now perceived as the ethical choice in a world where the consequences of replacing resources and throwing away reusable materials are impacting the well-being of the environment. This report describes the solvent recyle test program for EDTA/ammonium carbonate solvent.

NONE

1995-07-01

418

Chemical decontamination of process equipment using recyclable chelating solvent Phase I. Final report, September 1993--June 1995  

SciTech Connect

The Department of Energy (DOE) is now faced with the task of meeting decontamination and decommissioning obligations at numerous facilities by the year 2019. Due to the tremendous volume of material involved, innovative decontamination technologies are being sought that can reduce the volumes of contaminated waste materials and secondary wastes requiring disposal. With sufficient decontamination, some of the material from DOE facilities could be released as scrap into the commercial sector for recycle, thereby reducing the volume of radioactive waste requiring disposal. Although recycling may initially prove to be more costly than current disposal practices, rapidly increasing disposal costs are expected to make recycling more and more cost effective. Additionally, recycling is now perceived as the ethical choice in a world where the consequences of replacing resources and throwing away reusable materials are impacting the well-being of the environment.

NONE

1995-10-01

419

Recycling Conform Design.  

National Technical Information Service (NTIS)

The flow of materials in a real recycling system can be demonstrated in a simplified manner by a recycling model system. The analysis of this system results in additional new goals and guide lines for design. The guide lines are interpreted by examples sh...

W. Jorden

1984-01-01

420

Is mandated recycling possible  

Microsoft Academic Search

If piles of potentially recyclable materials are accumulated as a result of a mandatory source separation program, what options exist for the community First, it could attempt to market the recyclables through normal commercial channels. Second, the community could attempt to market the materials at lower prices to the consumers, since any contribution above available disposal cost is a profit

Cutler

1988-01-01

421

Partnership: Recycling $/$ Outdoor Education.  

ERIC Educational Resources Information Center

The Ottawa Board of Education (Ontario, Canada) has committed revenues generated by a districtwide recycling program to help fund the MacSkimming Outdoor Education Centre. A partnership between recycling and outdoor education is valuable in developing an environmental ethic among students and in finding new ways to fund outdoor education. (LP)

Weir, Phil

1996-01-01

422

Making Recycled Paper  

NSDL National Science Digital Library

This video and accompanying text describe the three-pronged resource conservation strategy known as "reduce, reuse, and recycle". The video segment, adapted from the television program 'ZOOM', features cast members demonstrating how something that might otherwise be discarded, such as newspaper, can be recycled to create a functional or even beneficial new product. Questions for discussion are also provided.

2005-01-01

423

Reuse, Reduce, Recycle.  

ERIC Educational Resources Information Center

Discussion of recycling paper in law libraries is also applicable to other types of libraries. Results of surveys of law libraries that investigated recycling practices in 1987 and again in 1990 are reported, and suggestions for reducing the amount of paper used and reusing as much as possible are offered. (LRW)

Briscoe, Georgia

1991-01-01

424

Recycling at Camp.  

ERIC Educational Resources Information Center

Outlines a Michigan summer camp's efforts to reduce solid waste disposal by recycling cardboard, tin, glass, aluminum, and plastic milk containers. Points out variables affecting the success of such efforts. Discusses Michigan state funding for the development of recycling programs. (SV)

Cummins, William M.

1988-01-01

425

Wee Recyclers Resources.  

ERIC Educational Resources Information Center

Hands-on activities in this guide are designed to help preschool children (ages 3-5) understand that reducing, reusing, and recycling preserves natural resources and prolongs the life of landfills. Children sort, match and compare recyclable items and learn to separate some items by number and color. The 29 activities are divided into units that…

Wisconsin State Dept. of Natural Resources, Madison.

426

The Fermilab recycler ring  

SciTech Connect

The Fermilab Recycler is a permanent magnet storage ring for the accumulation of antiprotons from the Antiproton Source, and the recovery and cooling of the antiprotons remaining at the end of a Tevatron store. It is an integral part of the Fermilab III luminosity upgrade. The following paper describes the design features, operational and commissioning status of the Recycler Ring.

Martin Hu

2001-07-24

427

AIRCRAFT INDUSTRY WASTEWATER RECYCLING  

EPA Science Inventory

The feasibility of recycling certain categories of water used in the manufacture of airplanes was demonstrated. Water in four categories was continuously recycled in 380-liter (100-gallon) treatment plants; chemical process rinse water, dye-penetrant crack-detection rinse water, ...

428

CHANGING THE LANDSCAPE--LOW-TECH SOLUTIONS TO THE PADUCAH SCRAP METAL REMOVAL PROJECT ARE PROVIDING SAFE, COST-EFFECTIVE REMEDIATION OF CONTAMINATED SCRAP YARDS  

SciTech Connect

Between 1974 and 1983, contaminated equipment was removed from the Paducah Gaseous Diffusion Plant (PGDP) process buildings as part of an enrichment process upgrade program. The upgrades consisted of the dismantlement, removal, and on-site storage of contaminated equipment, cell components, and scrap material (e.g., metal) from the cascade facilities. Scrap metal including other materials (e.g., drums, obsolete equipment) not related to this upgrade program have thus far accumulated in nine contiguous radiologically-contaminated and non-contaminated scrap yards covering 1.05E5 m2 (26 acres) located in the northwestern portion of the PGDP. This paper presents the sequencing of field operations and methods used to achieve the safe removal and disposition of over 47,000 tonnes (53,000 tons) of metal and miscellaneous items contained in these yards. The methods of accomplishment consist of mobilization, performing nuclear criticality safety evaluations, moving scrap metal to ground level, inspection and segregation, sampling and characterization, scrap metal sizing, packaging and disposal, and finally demobilization. Preventing the intermingling of characteristically hazardous and non-hazardous wastes promotes waste minimization, allowing for the metal and materials to be segregated into 13 separate waste streams. Low-tech solutions such as using heavy equipment to retrieve, size, and package scrap materials in conjunction with thorough planning that integrates safe work practices, commitment to teamwork, and incorporating lessons learned ensures that field operations will be conducted efficiently and safely.

Watson, Dan; Eyman, Jeff

2003-02-27

429

Volatilisation and oxidation of aluminium scraps fed into incineration furnaces.  

PubMed

Ferrous and non-ferrous metal scraps are increasingly recovered from municipal solid waste incineration bottom ash and used in the production of secondary steel and aluminium. However, during the incineration process, metal scraps contained in the waste undergo volatilisation and oxidation processes, which determine a loss of their recoverable mass. The present paper evaluates the behaviour of different types of aluminium packaging materials in a full-scale waste to energy plant during standard operation. Their partitioning and oxidation level in the residues of the incineration process are evaluated, together with the amount of potentially recoverable aluminium. About 80% of post-consumer cans, 51% of trays and 27% of foils can be recovered through an advanced treatment of bottom ash combined with a melting process in the saline furnace for the production of secondary aluminium. The residual amount of aluminium concentrates in the fly ash or in the fine fraction of the bottom ash and its recovery is virtually impossible using the current eddy current separation technology. The average oxidation levels of the aluminium in the residues of the incineration process is equal to 9.2% for cans, 17.4% for trays and 58.8% for foils. The differences between the tested packaging materials are related to their thickness, mechanical strength and to the alloy. PMID:22749723

Biganzoli, Laura; Gorla, Leopoldo; Nessi, Simone; Grosso, Mario

2012-12-01

430

Some functional properties of composite material based on scrap tires  

NASA Astrophysics Data System (ADS)

The utilization of scrap tires still obtains a remarkable importance from the aspect of unloading the environment from non-degradable waste [1]. One of the most prospective ways for scrap tires reuse is a production of composite materials [2] This research must be considered as a continuation of previous investigations [3, 4]. It is devoted to the clarification of some functional properties, which are considered important for the view of practical applications, of the composite material. Some functional properties of the material were investigated, for instance, the compressive stress at different extent of deformation of sample (till 67% of initial thickness) (LVS EN 826) [5] and the resistance to UV radiation (modified method based on LVS EN 14836) [6]. Experiments were realized on the purposefully selected samples. The results were evaluated in the correlation with potential changes of Shore C hardness (Shore scale, ISO 7619-1, ISO 868) [7, 8]. The results showed noticeable resistance of the composite material against the mechanical influence and ultraviolet (UV) radiation. The correlation with the composition of the material, activity of binder, definite technological parameters, and the conditions supported during the production, were determined. It was estimated that selected properties and characteristics of the material are strongly dependent from the composition and technological parameters used in production of the composite material, and from the size of rubber crumb. Obtained results show possibility to attain desirable changes in the composite material properties by changing both the composition and technological parameters of examined material.

Plesuma, Renate; Malers, Laimonis

2013-09-01

431

Radiation accident at Mayapuri scrap market, Delhi, 2010.  

PubMed

This article reports the accidental public radiation exposure in a scrap market in Delhi, India, on March 2010. The source, a gamma unit containing Cobalt-60 pencils, was improperly disposed of by a research institution in violation of national regulations for radiation protection and safety of radioactive sources. The unit was sold off to unsuspecting scrap dealers who dismantled the equipment. This event subsequently caused the most severe radiation accident reported in India to date, resulting in seven radiation injuries and one death. The clinical course of five of the patients treated at the All India Institute of Medical Sciences hospital, New Delhi, is summarised in this report. All five patients suffered from the haematological form of the acute radiation syndrome and local cutaneous radiation injury as well. While four patients exposed to doses between 0.6 and 2.8 Gy survived with intensive or supportive treatment, the patient with the highest exposure of 3.1 Gy died due to acute respiratory distress syndrome and multi-organ failure on Day 16 after hospitalisation. The incident highlights the current gaps in the knowledge, infrastructure and legislation in handling radioactive materials. Medical institutions need to formulate individualised triage and management guidelines to immediately respond to future public radiological accidents. PMID:22914329

Dey, A B; Mohanan, Sandeep; Damodaran, Deepak; Soneja, Manish; Jain, Neetu; Mohan, Anant; Vikram, Naval Kishore; Sood, Rita

2012-10-01

432

Purification of {sup 238}PuO{sub 2} scrap for heat source fuel  

SciTech Connect

The Nuclear Materials Technology (NMT) Division of Los Alamos National Laboratory has initiated a development program to recover and purify plutonium-238 oxide from impure feed sources in a glove box environment. A glove box line has been designed and a chemistry flowsheet developed to perform this recovery task at large scale. The initial demonstration effort focused on purification of {sup 238}PuO{sub 2} fuel by HNO{sub 3}/HF dissolution, followed by plutonium(III) oxalate precipitation and calcination to an oxide. Decontamination factors for most impurities of concern in the fuel were very good, producing {sup 238}PuO{sub 2} fuel significantly better in purity than specified by General Purpose Heat Source (GPHS) fuel powder specifications. A sufficient quantity of purified {sup 238}PuO{sub 2} fuel was recovered from the process to allow fabrication of a GPHS unit for testing. The results are encouraging for recycle of relatively impure plutonium-238 oxide and scrap residue items into fuel for useful applications. The high specific activity of plutonium-238 magnifies the consequences and concerns of radioactive waste generation. This work places an emphasis on development of waste minimization technologies to complement the aqueous processing operation. Results from experiments on neutralized solutions of plutonium-238 resulted in decontamination to about 1 millicurie/L. Combining ultrafiltration treatment with addition of a water soluble polymer designed to coordinate Pu, allowed solutions to be decontaminated to about 1 microcurie/L. Efforts continue to develop a capability for efficient, safe, cost effective, and environmentally acceptable methods to recover and purify {sup 238}PuO{sub 2} fuel.

Schulte, L.D.; Purdy, G.M.; Jarvinen, G.D.; Ramsey, K.; Silver, G.L.; Espinoza, J.; Rinehart, G.H.

1997-10-01

433

Recycle Used Oil on America Recycles Day  

NSDL National Science Digital Library

Motor oil doesn't wear out--it just gets dirty. Students and the general public may not know that used oil can be reused or recycled. The fact is, used oil can be re-fined, blended with additives, and used again. When you consider that 1.4 billion gallons

White, Boyd W.

2000-11-01

434

An economic and technical assessment of black-dross and salt-cake-recycling systems for application in the secondary aluminum industry  

SciTech Connect

The secondary aluminum industry annually disposes of large amounts of dross residues and salt cake, which are by-products from the processing of scrap aluminum for reuse. These wastes contain as much as 50% salts and are presently disposed of in conventional landfills. As the costs of landfill space increase and the availability of landfill space decreases, disposal of the residues will increasingly compromise the economics of recycling aluminum. Alternative processes exist by which the major constituents of the various drosses and salt cakes can be recovered for recycling. In this study, we review available recycling technologies and processes relevant to the recycling of black dross and salt cake and discuss new concepts that have the potential to improve the cost-effectiveness of recycling technologies.

Karvelas, D.; Daniels, E.; Jody, B.; Bonsignore, P.

1991-12-01

435

Active Recycling eyes coast-to-coast operations  

SciTech Connect

Active Recycling is a waste processing facility covering more than four acres in a mixed neighborhood in south-central Los Angeles. The recycling center handles more than 16,000 tons per month of household waste, making it more than twice the average size of most existing US materials recovery facilities today. The yard has its own railroad spur, and prepared materials from the recycling center are shipped out daily. Glass, paper, aluminum, and scrap metal are shipped directly to mills for reuse. The materials shipped by rail are dropped off throughout the US, while the rest of the materials go overseas in export containers. The company's sizeable loading dock can load four rail cars and seven 40-foot export containers simultaneously. The center boasts of paying some of the highest prices in the area for glass bottles and jars, polyethylene terephthalate soft drink bottles, and high-density polyethylene containers, cardboard, newspapers, mixed-color and white paper, aluminum, copper, brass, automotive batteries, iron and cast iron, lead, tin, stainless steel, diecast aluminum, aluminum foil and TV dinner trays, radiators, and electric motors.

Paquette, P.

1995-03-01

436

Creating Methane from Plastics: Recycling at a Lunar Outpost  

NASA Technical Reports Server (NTRS)

The high cost of re-supply from Earth demands resources to be utilized to the fullest extent for exploration missions. Recycling is a key technology that maximizes the available resources by converting waste products into useful commodities. One example of this is to convert crew member waste such as plastic packaging, food scraps, and human waste, into fuel. The ability to refuel on the lunar surface would reduce the vehicle mass during launch and provide excess payload capability. The goal of this project is to determine the feasibility of recycling waste into methane on the lunar outpost by performing engineering assessments and lab demonstrations of the technology. The first goal of the project was to determine how recycling could influence lunar exploration. Table I shows an estimation of the typical dried waste stream generated each day for a crew of four. Packaging waste accounts for nearly 86% of the dry waste stream and is a significant source of carbon on the lunar surface. This is important because methane (CH4) can be used as fuel and no other source of carbon is available on the lunar surface. With the initial assessment indicating there is sufficient resources in the waste stream to provide refueling capabilities, the project was designed to examine the conversion of plastics into methane.

Captain, Janine; Santiago, Eddie; Wheeler, Ray; Strayer, RIchard; Garland, Jay; Parrish, Clyde

2010-01-01

437

Dragnet: Nonprofit Computer Recyclers  

NSDL National Science Digital Library

If you have ever wondered what happens to obsolete computers, check out these current awareness Websites. The disposal of computers is classified as hazardous waste, which has become an environmental concern as the number of obsolete computers rises. In fact, the Wisconsin Department of Natural Resources and the State of Massachusetts have banned computer equipment from landfills. Dragnet: Nonprofit Computer Recyclers is an EPA-licensed computer recycling organization that reuses all acceptable components and systems or recycles damaged or unusable components. Rebuilt computer systems are given to "persons with disabilities and persons living in disadvantaged situations."

438

Bioleaching of electronic scrap by mixed culture of moderately thermophilic microorganisms  

NASA Astrophysics Data System (ADS)

A process for the metal recovery from electronic scrap using bacterial leaching was investigated. A mixed culture of moderately thermophilic microorganisms was enriched from acid mine drainages (AMDs) samples collected from several sulphide mines in Romania, and the bioleaching of electronic scrap was conducted both in shake flask and bioreactor. The results show that in the shake flask, the mixture can tolerate 50 g/L scrap after being acclimated to gradually increased concentrations of scrap. The copper extraction increases obviously in bioleaching of scrap with moderately thermophilic microorganisms supplemented with 0.4 g/L yeast extract at 180 r/min, 74% copper can be extracted in the pulp of 50 g/L scrap after 20 d. Compared with copper extractions of mesophilic culture, unacclimated culture and acclimated culture without addition of yeast extract, that of accliniated culture with addition of yeast extract is increased by 53%, 44% and 16%, respectively. In a completely stirred tank reactor, the mass fraction of copper and total iron extraction reach up to 81% and 56%, respectively. The results also indicate that it is necessary to add a large amount of acid to the pulp to extract copper from electronic scrap effectively.

Iv?nu?, D.; ?nu?, R. C., IV; C?lmuc, F.

2010-06-01

439

Minor Actinides Recycling in PWRs  

SciTech Connect

Recycling of minor actinides in current and near future PWR is considered as one of the options of the general waste management strategy. This paper presents the analysis of this option both from the core physics and fuel cycle point of view. A first indicator of the efficiency of different neutron spectra for transmutation purposes is the capture to fission cross sections ratio which is less favourable by a factor between 5 to 10 in PWRs compared to fast reactors. Another indicator presented is the production of high ranking isotopes like Curium, Berkelium or Californium in the thermal or epithermal spectrum conditions of PWR cores by successive neutron captures. The impact of the accumulation of this elements on the fabrication process of such PWR fuels strongly penalizes this option. The main constraint on minor actinides loadings in PWR (or fast reactors) fuels are related to their direct impact (or the impact of their transmutation products) on the reactivity coefficients, the reactivity control means and the core kinetics parameters. The main fuel cycle physical parameters like the neutron source, the alpha decay power, the gamma and neutrons dose rate and the criticality aspects are also affected. Recent neutronic calculations based on a reference core of the Evolutionary Pressurized Reactor (EPR), indicates typical maximum values of 1 % loadings. Different fuel design options for minor actinides transmutation purposes in PWRs are presented: UOX and MOX, homogeneous and heterogeneous assemblies. In this later case, Americium loading is concentrated in specific pins of a standard UOX assembly. Recycling of Neptunium in UOX and MOX fuels was also studied to improve the proliferation resistance of the fuel. The impact on the core physics and penalties on Uranium enrichment were underlined in this case. (authors)

Delpech, M.; Golfier, H. [CEA Saclay 91191 Gif-sur-Yvette (France); Vasile, A.; Varaine, F.; Boucher, L. [CEA Cadarache, 13108 Saint-Paul-lez-Durance Cedex (France); Greneche, D. [AREVA - Tour AREVA - F - 92084 Paris La Defense Cedex (France)

2006-07-01

440

Uranium Pyrophoricity Phenomena and Prediction  

SciTech Connect

We have compiled a topical reference on the phenomena, experiences, experiments, and prediction of uranium pyrophoricity for the Hanford Spent Nuclear Fuel Project (SNFP) with specific applications to SNFP process and situations. The purpose of the compilation is to create a reference to integrate and preserve this knowledge. Decades ago, uranium and zirconium fires were commonplace at Atomic Energy Commission facilities, and good documentation of experiences is surprisingly sparse. Today, these phenomena are important to site remediation and analysis of packaging, transportation, and processing of unirradiated metal scrap and spent nuclear fuel. Our document, bearing the same title as this paper, will soon be available in the Hanford document system [Plys, et al., 2000]. This paper explains general content of our topical reference and provides examples useful throughout the DOE complex. Moreover, the methods described here can be applied to analysis of potentially pyrophoric plutonium, metal, or metal hydride compounds provided that kinetic data are available. A key feature of this paper is a set of straightforward equations and values that are immediately applicable to safety analysis.

DUNCAN, D.R.

2000-04-20

441

Creating Methane from Plastic: Recycling at a Lunar Outpost  

NASA Technical Reports Server (NTRS)

The high cost of re-supply from Earth demands resources to be utilized to the fullest extent for exploration missions. The ability to refuel on the lunar surface would reduce the vehicle mass during launch and provide excess payload capability. Recycling is a key technology that maximizes the available resources by converting waste products into useful commodities. One example of this is to convert crew member waste such as plastic packaging, food scraps, and human waste into fuel. This process thermally degrades plastic in the presence of oxygen producing CO2 and CO. The CO2 and CO are then reacted with hydrogen over catalyst (Sabatier reaction) producing methane. An end-to-end laboratory-scale system has been designed and built to produce methane from plastic, in this case polyethylene. This first generation system yields 12-16% CH4 by weight of plastic used.

Santiago-Maldonado, Edgardo; Captain, Janine; Devor, Robert; Gleaton, Jeremy

2010-01-01

442

Energy Return on Investment from Recycling Nuclear Fuel  

SciTech Connect

This report presents an evaluation of the Energy Return on Investment (EROI) from recycling an initial batch of 800 t/y of used nuclear fuel (UNF) through a Recycle Center under a number of different fuel cycle scenarios. The study assumed that apart from the original 800 t of UNF only depleted uranium was available as a feed. Therefore for each subsequent scenario only fuel that was derived from the previous fuel cycle scenario was considered. The scenarios represent a good cross section of the options available and the results contained in this paper and associated appendices will allow for other fuel cycle options to be considered.

None

2011-08-17

443

The Totem Pole Recycled.  

ERIC Educational Resources Information Center

Presents an activity that integrates science, environmental education, art, and social studies. Students identify and research an endangered species and construct a totem pole depicting the species using a recyclable material. (MDH)

Sewall, Susan Breyer

1991-01-01

444

Reduce, Reuse, Recycle  

NSDL National Science Digital Library

In this media-rich lesson featuring LOOP SCOOPS videos, students consider how the concept of needs vs. wants can help them think about ways to protect Earth's natural resources by reducing, reusing, and recycling materials.

Foundation, Wgbh E.

2010-11-30

445

Making Recycled Paper  

NSDL National Science Digital Library

In this activity on page 11 of the PDF, learners follow simple steps to recycle old newspaper into new paper. Use this activity to introduce conservation as well as the chemistry of cellulose and how paper products are made.

Society, American C.

2011-01-01

446

Kinetics of scrap tyre pyrolysis under vacuum conditions.  

PubMed

Scrap tyre pyrolysis under vacuum is attractive because it allows easier product condensation and control of composition (gas, liquid and solid). With the aim of determining the effect of vacuum on the pyrolysis kinetics, a study has been carried out in thermobalance. Two data analysis methods have been used in the kinetic study: (i) the treatment of experimental data of weight loss and (ii) the deconvolution of DTG (differential thermogravimetry) curve. The former allows for distinguishing the pyrolysis of the three main components (volatile components, natural rubber and styrene-butadiene rubber) according to three successive steps. The latter method identifies the kinetics for the pyrolysis of individual components by means of DTG curve deconvolution. The effect of vacuum in the process is significant. The values of activation energy for the pyrolysis of individual components of easier devolatilization (volatiles and NR) are lower for pyrolysis under vacuum with a reduction of 12K in the reaction starting temperature. The kinetic constant at 503K for devolatilization of volatile additives at 0.25atm is 1.7 times higher than that at 1atm, and that corresponding to styrene-butadiene rubber at 723K is 2.8 times higher. Vacuum enhances the volatilization and internal diffusion of products in the pyrolysis process, which contributes to attenuating the secondary reactions of the repolymerization and carbonization of these products on the surface of the char (carbon black). The higher quality of carbon black is interesting for process viability. The large-scale implementation of this process in continuous mode requires a comparison to be made between the economic advantages of using a vacuum and the energy costs, which will be lower when the technologies used for pyrolysis require a lower ratio between reactor volume and scrap tyre flow rate. PMID:19589669

Lopez, Gartzen; Aguado, Roberto; Olazar, Martín; Arabiourrutia, Miriam; Bilbao, Javier

2009-10-01

447

Waste recycling in the textile industry. July 1983-September 1989 (Citations from World Textile abstracts). Report for July 1983-September 1989  

SciTech Connect

This bibliography contains citations on the recycling of waste-fibrous materials for textile production, and the recycling of textile-waste materials. Topics include use of wastes as raw materials for textile and fabric manufacturing; reuse of waste cloth, scraps, fibers, and polymeric materials from textile manufacturing; and the equipment used to collect, sort, and process textile wastes. Materials considered include cellulosic wastes, polymeric wastes, cloth scraps, fiber waste, glass-fiber wastes, and waste dusts. Applications discussed include textile products, insulation, paneling and other building supplies, yarns, roping, and pavement materials. Heat recovery and effluent treatment in the textile industry are referenced in related published bibliographies. (Contains 242 citations fully indexed and including a title list.)

Not Available

1989-12-01

448

Climate Kids: Recycle This!  

NSDL National Science Digital Library

The site features an online game in which participants keep recyclable items out of the trash by guiding them into proper bins. Accompanying the game is a list of three categories of items that can be recycled, along with the benefits of doing so. This lesson is part of the Climate Kids website, a NASA education resource featuring articles, videos, images and games focused on the science of climate change.

449

Recyclability Index for Automobiles  

Microsoft Academic Search

A rating system was developed to quantify the environmental impacts of light-duty motor vehicles at the end of their life-cycle based on recyclability, toxic material content and ultimate disposal. Each year, 10-11 million vehicles are retired from service in the United States. The vehicle material not recycled is called automotive shredder residue (ASR). About 4.5 to 5 million tons of

Alexander Tsuji; Yarrow Nelson; Andrew Kean; Samuel A. Vigil

2006-01-01

450

Uranium Metal Dissolution in the Presence of Fluoride and Boron  

SciTech Connect

H-Area Operations is planning to process plutonium-contaminated (Pu-contaminated) uranium metal scrap in its efforts to de-inventory excess nuclear materials. Experimental work was performed with a piece of uranium sheet. The study had four primary objectives. First, gather reaction rate data at a range of processing conditions to compare against reaction rate data reported in earlier studies and recommend a flowsheet for H-Canyon and/or for HB-Line. Second, develop new data for calculating hydrogen and total generation rates during uranium metal dissolution. Third, the tests intend to provide data to help demonstrate that the proposed flowsheet does not pose a criticality hazard. Last, use the data to recommend a process flowsheet.

Pierce, R.A.

2004-02-02

451

Recycling of nonmetallics  

USGS Publications Warehouse

The first factor determining recyclability is the composition of the material itself. Metals, for example, can be reused with little or no loss in quality. Paper and rubber, by this criterion, are less recyclable. Each time paper is recycled, some cellulose fibers are broken. Shorter fibers can mean weaker paper of perceived lower quality and value. Vulcanizing is an irreversible chemical process that precludes recycling rubber in its original form. Both materials may be reused in other applications often of lower value than the original one. To be recyclable, the discarded material must have a collection infrastructure at the source of waste generation, at a central collection site, or at curbside. The recovered material must also have a market. If it is priced noncompetitively or no market exists, if it does not meet specifications, or if it requires special technology investments which cannot be recovered through future sales, the recovered material may be stockpiled or discarded rather than recycled. ?? 1996 International Association for Mathematical Geology.

Amey, E. B.; Kelly, T. D.

1996-01-01

452

MaTrace: Tracing the Fate of Materials over Time and Across Products in Open-Loop Recycling.  

PubMed

Even for metals, open-loop recycling is more common than closed-loop recycling due, among other factors, to the degradation of quality in the end-of-life (EoL) phase. Open-loop recycling is subject to loss of functionality of original materials, dissipation in forms that are difficult to recover, and recovered metals might need dilution with primary metals to meet quality requirements. Sustainable management of metal resources calls for the minimization of these losses. Imperative to this is quantitative tracking of the fate of materials across different stages, products, and losses. A new input-output analysis (IO) based model of dynamic material flow analysis (MFA) is presented that can trace the fate of materials over time and across products in open-loop recycling taking explicit consideration of losses and the quality of scrap into account. Application to car steel recovered from EoL vehicles (ELV) showed that after 50 years around 80% of the steel is used in products, mostly buildings and civil engineering (infrastructure), with the rest mostly resided in unrecovered obsolete infrastructure and refinery losses. Sensitivity analysis was conducted to evaluate the effects of changes in product lifespan, and the quality of scrap. PMID:24872019

Nakamura, Shinichiro; Kondo, Yasushi; Kagawa, Shigemi; Matsubae, Kazuyo; Nakajima, Kenichi; Nagasaka, Tetsuya

2014-07-01

453

White goods recycling in the United States: Economic and technical issues in recovering, reclaiming, and reusing nonmetallic materials  

SciTech Connect

Obsolete white goods (appliances such as refrigerators, freezers, washers, dryers, ranges, dishwashers, water heaters, dehumidifiers, and air conditioners) contain significant quantities of recyclable materials, but because of economic and environmental concerns, only limited quantities of these scrap materials are currently being recycled. Appliances are manufactured from a mix of materials, such as metals, polymers, foam, and fiberglass; metals represent more than 75% of the total weight. Appliance recycling is driven primarily by the value of the steel in the appliances. Over the last 15 years, however, the use of polymers in appliance manufacturing has increased substantially at the expense of metals. The shift in the materials composition of appliances may threaten the economics of the use of obsolete appliances as a source for scrap metals. To increase the recycling of white goods, cost-effective and environmentally acceptable technologies must be developed to separate, recover, reclaim, and reuse polymers from discarded appliances. Argonne National Laboratory is currently conducting research, with industry support, to develop cost-effective processes and methods for recovering and reclaiming acrylonitrile butadiene-styrene and High-density polystyrene from discarded appliances. This collaborative research focuses on developing a combination of mechanical/physical and chemical separation methods for recovering and reusing these high-value plastics. In addition, cost-effective methods for improving the performance characteristics of the recovered plastics are being investigated with the goal of recycling these plastics to their original application. In this paper, we examine the technical and economic issues that affect the recycling of white goods and present results of Argonne`s white goods recycling research and development activities.

Karvelas, D.E.; Jody, B.J.; Daniels, E.J.

1995-02-01

454

Electrolytic method for recovery of lead from scrap batteries: scale-up study using 20-liter multielectrode cell. Report of investigations/1984  

SciTech Connect

Anodes cast from scrap battery lead were electrorefined in a 20-L multielectrode cell for 3 to 7 days. The anodes, containing 2 to 2.5 pct antimony, were ideal for obtaining firm and adherent slime blankets. Cathode deposits, assaying 99.99 pct Pb, were obtained, with current efficiencies near 99 pct. Sludge leaching was done in 100-L tanks followed by filtering in 61 cm square vacuum pan filters. Lead of greater than 99.99-pct purity was recovered from the filtrate by electrowinning in a 20-L multielectrode cell using insoluble PbO2-Ti (lead dioxide-coated titanium) anodes and pure lead cathodes. The fluosilicic acid electrolyte depleted in lead was repeatedly recycled to leach more sludge, and there was no problem with impurity buildup.

Lee, A.Y.; Cole, E.R. Jr.; Paulson, D.L.

1984-01-01

455

Bioremediation of uranium contaminated soils and wastes  

SciTech Connect

Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (1) stabilization of uranium and toxic metals with reduction in waste volume and (2) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

Francis, A.J.

1998-12-31

456

Scrap Tire Disposal and Utilization Alternatives: A State-of-the-Art Report.  

National Technical Information Service (NTIS)

A review has been made of the available worldwide literature which describes techniques and equipment used in the disposal of scrap tires. The operational procedures, feasibility, and impact of each alternative technique are discussed, and current and pro...

G. L. Ochs K. V. Coram

1975-01-01

457

Evaluation of products recovered from scrap tires for use as asphalt modifiers.  

National Technical Information Service (NTIS)

Western Research Institute performed rheological tests and water sensitivity tests on asphalt cements that had been modified with carbonous residues obtained from the pyrolysis of scrap tires and waste motor oil. These tests are part of an ongoing program...

J. McKay

1992-01-01

458

Sink-Float Ferrofluid Separator Applicable to Full Scale Nonferrous Scrap Separation.  

National Technical Information Service (NTIS)

Design and performance of a ferrofluid levitation separator for recovering nonferrous metals from shredded automobiles are reported. The scrap separator uses an electromagnet to generate a region of constant density within a pool of ferrofluid held betwee...

1973-01-01

459

Rapid Separation Methods to Characterize Actinides and Metallic Impurities in Plutonium Scrap Materials at SRS.  

National Technical Information Service (NTIS)

The Nuclear Materials Stabilization and Storage Division at SRS plans to stabilize selected plutonium scrap residue materials for long term storage by dissolution processing and plans to stabilize other plutonium vault materials via high-temperature furna...

S. L. Maxwell V. D. Jones

1998-01-01

460

Gold Recovery from Scrap Electronic Solders by Fused-Salt Electrolysis.  

National Technical Information Service (NTIS)

The report discusses a process for recovering gold and refining tin-lead solders from scrap solder discarded by the electronics industry. Contaminated solder can be refined by electrotransport in a molten-salt chloride electrolyte. Refined solder is recov...

E. K. Kleespiex J. P. Bennetts T. A. Henrie

1969-01-01

461

Comparison of instrumental methods used in the determination of uranium, plutonium, and americium  

SciTech Connect

This paper describes the use of Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Mass Spectrometry-Isotopic Dilution (MSID) for the quantitative determination of plutonium and uranium in different types of samples. 2{pi} - alpha counting and high resolution gamma spectrometry for the analysis of americium and plutonium in scrap, residues, and process samples is also described. Comparison of the data obtained by these methods was presented and evaluated. 11 tabs.

Sabau, C.S.

1990-01-01

462

EVALUATION OF FLOWSHEET CHANGES FOR THE HIGHLY ENRICHED URANIUM BLENDDOWN PROGRAM  

Microsoft Academic Search

H Canyon is considering a flowsheet change for Plutonium (Pu) Contaminated Scrap (PuCS) material. The proposed change is to route dissolved PuCS material directly to a uranium (U) storage tank. As a result, the PuCS solution will bypass Head End and First U Cycle, and will be purified by solvent extraction in Second U Cycle. The PuCS solution contains appreciable

M. Crowder; T. Rudisill; J. Laurinat; J. Mickalonis

2007-01-01

463

Recovery of fissile materials from plutonium residues, miscellaneous spent nuclear fuel, and uranium fissile wastes  

SciTech Connect

A new process is proposed that converts complex feeds containing fissile materials into a chemical form that allows the use of existing technologies (such as PUREX and ion exchange) to recover the fissile materials and convert the resultant wastes to glass. Potential feed materials include (1) plutonium scrap and residue, (2) miscellaneous spent nuclear fuel, and (3) uranium fissile wastes. The initial feed materials may contain mixtures of metals, ceramics, amorphous solids, halides, and organics. 14 refs., 4 figs.

Forsberg, C.W.

1997-03-01

464

Optimization of pyrolysis conditions of scrap tires under inert gas atmosphere  

Microsoft Academic Search

A pyrolysis system was designed for the production of activated carbon and other products from scrap tires. The system allows work under inert atmosphere (N2 gas). The pyrolysis experiments were carried out in a fixed-bed batch reactor of (1.25m length and 0.03m o.d.) which was heated by an electric furnace. The feed material used was scrap tires supplied from General

Mahmood M. Barbooti; Thamer J. Mohamed; Alaa A. Hussain; Falak O. Abas

2004-01-01

465

Crosslinking kinetics of SBR composites containing vulcanized ground scraps as filler  

Microsoft Academic Search

The aim of this study was to characterize the cure reaction of styrene–butadiene rubber (SBR) composites containing industrial\\u000a rubber scraps. Different proportions of SBR ground scraps (SBR-r), varying from 10 to 80 parts per hundred of rubber, were\\u000a incorporated into a base formulation of identical composition. Crosslink formation and the kinetics of the cure reaction were\\u000a evaluated through oscillatory disk

Larissa N. Carli; Otávio Bianchi; Raquel S. Mauler; Janaina S. Crespo

466

Upgrading Scrap Tire Derived Oils Using Activated Carbon Supported Metal Catalysts  

Microsoft Academic Search

Scrap tire derived oils were upgraded over metal-loaded activated carbon catalysts and commercial catalyst at different operating conditions. Activated carbon support was prepared from the pyrolytic carbon black from pyrolysis of scrap tires. Activated carbon catalysts contained the metal pairs of Co-Ni, Co-Mo, and Ni-Mo. All metal-loaded activated carbon catalysts showed similar catalytic activity for upgrading process at 350°C under

S. Ucar; S. Karagoz; J. Yanik; M. Yuksel; M. Saglam

2007-01-01

467

Effects of rotating impeller degassing on microstructure and mechanical properties of the A356 scraps  

Microsoft Academic Search

The rotating impeller degassing technique was used for degassing of A356 scrap melt which had been protected and purified with an RE-containing JDN-I flux. Results indicated that the modification of eutectic silicon was faded and the mechanical properties of the alloy became worse after rotating impeller degassing and that the tensile strength and elongation of the scrap A356 alloy which

Hongjun Ni; Baode Sun; Haiyan Jiang; Wenjiang Ding

2003-01-01

468

Protocols for implementing DOE authorized release of radioactive scrap metals  

Microsoft Academic Search

A process to implement the US Department of Energy`s (DOE) policy for authorized release of radioactive materials from DOE facilities is provided in the Draft Handbook for Controlling Release for Reuse or Recycle of Property Containing Residual Radioactive Material, published by DOE in 1997 and distributed to DOE field offices for interim use and implementation. The authorized release of such

S. Y. Chen; J. Arnish; S. Kamboj; L. A. Nieves

1999-01-01

469

A Study of Scrap Heating by Burners: Part II—Numerical Modeling  

NASA Astrophysics Data System (ADS)

A computational fluid dynamics code was developed to model the heating of a bed of porous steel scrap by combustion gases from a burner. The code accounted for nonuniform void fraction in the bed; turbulent, non-Darcian flow, heat transfer from the gas to the scrap; and radiation. The measured bed porosity values were used in the code. Because steel scrap pieces are very irregular in shape and size, the effective particle diameter was fitted to measurements made in a 1-m3 capacity furnace, as reported in part I. It was found that the lower porosity of the scrap was the most beneficial in increasing the efficiency of heat transfer to the scrap bed because the interfacial area is larger. The effect of particle size was much smaller. It was found that the configurations that increased the residence time or path length of the gases increased the efficiency. The measured porosity of the bed approached unity at the walls, so this provided an easy path for the gas to short-circuit the bed, which limited the effectiveness of decreasing the porosity to increase heat-transfer efficiency. Similarly, simulations of nonuniform scrap distributions reduced efficiency of heat transfer due to short circuiting. The implications of the findings for industrial operations are discussed.

Mandal, Kamalesh; Irons, Gordon A.

2013-02-01

470

Process for removing copper in a recoverable form from solid scrap metal  

DOEpatents

A process for removing copper in a recoverable form from a copper/solid ferrous scrap metal mix is disclosed. The process begins by placing a copper/solid ferrous scrap metal mix into a reactor vessel. The atmosphere within the reactor vessel is purged with an inert gas or oxidizing while the reactor vessel is heated in the area of the copper/solid ferrous scrap metal mix to raise the temperature within the reactor vessel to a selected elevated temperature. Air is introduced into the reactor vessel and thereafter hydrogen chloride is introduced into the reactor vessel to obtain a desired air-hydrogen chloride mix. The air-hydrogen chloride mix is operable to form an oxidizing and chloridizing atmosphere which provides a protective oxide coating on the surface of the solid ferrous scrap metal in the mix and simultaneously oxidizes/chloridizes the copper in the mix to convert the copper to a copper monochloride gas for transport away from the solid ferrous scrap metal. After the copper is completely removed from the copper/solid ferrous scrap metal mix, the flows of air and hydrogen chloride are stopped and the copper monochloride gas is collected for conversion to a recoverable copper species.

Hartman, Alan D. (Albany, OR); Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR)

1995-01-01

471