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Sample records for su3-flavor chiral perturbation

  1. Chiral Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Tiburzi, Brian C.

    The era of high-precision lattice QCD has led to synergy between lattice computations and phenomenological input from chiral perturbation theory. We provide an introduction to chiral perturbation theory with a bent towards understanding properties of the nucleon and other low-lying baryons. Four main topics are the basis for this chapter. We begin with a discussion of broken symmetries and the procedure to construct the chiral Lagrangian. The second topic concerns specialized applications of chiral perturbation theory tailored to lattice QCD, such as partial quenching, lattice discretization, and finite-volume effects. We describe inclusion of the nucleon in chiral perturbation theory using a heavy-fermion Euclidean action. Issues of convergence are taken up as our final topic. We consider expansions in powers of the strange-quark mass, and the appearance of unphysical singularities in the heavy-particle formulation. Our aim is to guide lattice practitioners in understanding the predictions chiral perturbation theory makes for baryons, and show how the lattice will play a role in testing the rigor of the chiral expansion at physical values of the quark masses.

  2. Baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Scherer, S.

    2012-03-01

    We provide a short introduction to the one-nucleon sector of chiral perturbation theory and address the issue of power counting and renormalization. We discuss the infrared regularization and the extended on-mass-shell scheme. Both allow for the inclusion of further degrees of freedom beyond pions and nucleons and the application to higher-loop calculations. As applications we consider the chiral expansion of the nucleon mass to order Script O(q6) and the inclusion of vector and axial-vector mesons in the calculation of nucleon form factors. Finally, we address the complex-mass scheme for describing unstable particles in effective field theory.

  3. Chiral perturbation theory with nucleons

    SciTech Connect

    Meissner, U.G.

    1991-09-01

    I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, {pi}N scattering and the {sigma}-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon.

  4. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    DOE PAGESBeta

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the ordermore » we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.« less

  5. Lattice calculation of SU(3) flavor breaking ratios in B0-B¯0 mixing

    NASA Astrophysics Data System (ADS)

    Gadiyak, Valeriya; Loktik, Oleg

    2005-12-01

    We present an unquenched lattice calculation for the SU(3) flavor breaking ratios of the heavy-light decay constants and the ΔB=2 matrix elements. The calculation was performed on 163×32 lattices with two dynamical flavors of domain-wall quarks and inverse lattice spacing 1/a=1.69(5)GeV. Heavy quarks were implemented using an improved lattice formulation of the static approximation. In the infinite heavy-quark mass limit we obtain fBs/fBd=1.29(4)(6), BBs/BBd=1.06(6)(4), ξ=1.33(8)(8) where the first error is statistical and the second systematic.

  6. Strong decays of charmed baryons in heavy hadron chiral perturbation theory: An update

    NASA Astrophysics Data System (ADS)

    Cheng, Hai-Yang; Chua, Chun-Khiang

    2015-10-01

    We first give a brief overview of the charmed baryon spectroscopy and discuss their possible structure and spin-parity assignments in the quark model. With the new Belle measurement of the widths of Σc(2455 ) and Σc(2520 ) and the recent CDF measurement of the strong decays of Λc(2595 ) and Λc(2625 ), we give updated coupling constants in heavy hadron chiral perturbation theory. We find g2=0.56 5-0.024+0.011 for P -wave transitions between s -wave and s -wave baryons, and h2, one of the couplings responsible for S -wave transitions between s -wave and p -wave baryons, is extracted from Λc(2595 )+→Λc+π π to be 0.63 ±0.07 . It is substantially enhanced compared to the old value of order 0.437. With the help from the quark model, two of the couplings h10 and h11 responsible for D -wave transitions between s -wave and p -wave baryons are determined from Σc(2880 ) decays. There is a tension for the coupling h2 as its value extracted from Λc(2595 )+→Λc+ππ will imply Ξc(2790 )0→Ξc'π and Ξc(2815 )+→Ξc*π rates slightly above the current limits. It is conceivable that SU(3) flavor symmetry breaking can help account for the discrepancy.

  7. Partially Quenched Chiral Perturbation Theory to NNLO

    SciTech Connect

    Laehde, Timo; Bijnens, Johan; Danielsson, Niclas

    2006-07-11

    This paper summarizes the recent calculations of the masses and decay constants of the pseudoscalar mesons at the two-loop level, or NNLO, in Partially Quenched Chiral Perturbation theory (PQ{chi}PT). Possible applications include chiral extrapolations of Lattice QCD, as well as the determination of the low-energy constants (LEC:s) of QCD.

  8. Staggered heavy baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Bailey, Jon A.

    2008-03-01

    Although taste violations significantly affect the results of staggered calculations of pseudoscalar and heavy-light mesonic quantities, those entering staggered calculations of baryonic quantities have not been quantified. Here I develop staggered chiral perturbation theory in the light-quark baryon sector by mapping the Symanzik action into heavy baryon chiral perturbation theory. For 2+1 dynamical quark flavors, the masses of flavor-symmetric nucleons are calculated to third order in partially quenched and fully dynamical staggered chiral perturbation theory. To this order the expansion includes the leading chiral logarithms, which come from loops with virtual decuplet-like states, as well as terms of O(mπ3), which come from loops with virtual octet-like states. Taste violations enter through the meson propagators in loops and tree-level terms of O(a2). The pattern of taste symmetry breaking and the resulting degeneracies and mixings are discussed in detail. The resulting chiral forms are appropriate to lattice results obtained with operators already in use and could be used to study the restoration of taste symmetry in the continuum limit. I assume that the fourth root of the fermion determinant can be incorporated in staggered chiral perturbation theory using the replica method.

  9. Tests of Chiral Perturbation Theory with COMPASS

    SciTech Connect

    Friedrich, Jan

    2010-12-28

    The COMPASS experiment at CERN studies with high precision pion-photon induced reactions on nuclear targets via the Primakoff effect. This offers the possibility to test chiral perturbation theory (ChPT) in various channels: Pion Compton scattering allows to clarify the longstanding question of the pion polarisabilities, single neutral pion production is related to the chiral anomaly, and for the two-pion production cross sections exist as yet untested ChPT predictions.

  10. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    SciTech Connect

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.

  11. CP violation in , B 0 → K +π- decays and tests for SU(3) flavor symmetry predictions

    NASA Astrophysics Data System (ADS)

    He, Xiao-Gang; Li, Siao-Fong; Lin, Hsiu-Hsien

    2013-08-01

    The LHCb collaboration has recently measured the first direct CP violation in decays with a rate asymmetry given by 0 .27 ± 0 .04( stat) ± 0 .01( syst). At the same time they also made the most precise measurement for ACP ( B0 → K +π-) = -0 .080 ± 0 .007( stat) ± 0 .003( syst). These data confirm the predicted relation, , in the standard model with SU(3) flavor symmetry. We discuss possible modifications due to SU(3) breaking effects to this relation. There are several other similar relations in B decays. Using current available data we study whether relevant relations hold in B 0 and to PP and PV decays. Here P and V indicate pesudoscalar and vector mesons in the flavor octet representations.

  12. Applications of partially quenched chiral perturbation theory

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1998-05-01

    Partially quenched theories are theories in which the valence- and sea-quark masses are different. In this paper we calculate the nonanalytic one-loop corrections of some physical quantities: the chiral condensate, weak decay constants, Goldstone boson masses, B{sub K}, and the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude, using partially quenched chiral perturbation theory. Our results for weak decay constants and masses agree with, and generalize, results of previous work by Sharpe. We compare B{sub K} and the K{sup +} decay amplitude with their real-world values in some examples. For the latter quantity, two other systematic effects that plague lattice computations, namely, finite-volume effects and unphysical values of the quark masses and pion external momenta, are also considered. We find that typical one-loop corrections can be substantial. {copyright} {ital 1998} {ital The American Physical Society}

  13. Tests of Chiral perturbation theory with COMPASS

    NASA Astrophysics Data System (ADS)

    Friedrich, Jan M.

    2014-06-01

    The COMPASS experiment at CERN accesses pion-photon reactions via the Primakoff effect., where high-energetic pions react with the quasi-real photon field surrounding the target nuclei. When a single real photon is produced, pion Compton scattering is accessed and from the measured cross-section shape, the pion polarisability is determined. The COMPASS measurement is in contradiction to the earlier dedicated measurements, and rather in agreement with the theoretical expectation from ChPT. In the same experimental data taking, reactions with neutral and charged pions in the final state are measured and analyzed in the context of chiral perturbation theory.

  14. The baryon vector current in the combined chiral and 1/Nc expansions

    SciTech Connect

    Flores-Mendieta, Ruben; Goity, Jose L

    2014-12-01

    The baryon vector current is computed at one-loop order in large-Nc baryon chiral perturbation theory, where Nc is the number of colors. Loop graphs with octet and decuplet intermediate states are systematically incorporated into the analysis and the effects of the decuplet-octet mass difference and SU(3) flavor symmetry breaking are accounted for. There are large-Nc cancellations between different one-loop graphs as a consequence of the large-Nc spin-flavor symmetry of QCD baryons. The results are compared against the available experimental data through several fits in order to extract information about the unknown parameters. The large-Nc baryon chiral perturbation theory predictions are in very good agreement both with the expectations from the 1/Nc expansion and with the experimental data. The effect of SU(3) flavor symmetry breaking for the |Delta S|=1 vector current form factors f1(0) results in a reduction by a few percent with respect to the corresponding SU(3) symmetric values.

  15. One-loop chiral perturbation theory with two fermion representations

    NASA Astrophysics Data System (ADS)

    DeGrand, Thomas; Golterman, Maarten; Neil, Ethan T.; Shamir, Yigal

    2016-07-01

    We develop chiral perturbation theory for chirally broken theories with fermions in two different representations of the gauge group. Any such theory has a nonanomalous singlet U (1 )A symmetry, yielding an additional Nambu-Goldstone boson when spontaneously broken. We calculate the next-to-leading order corrections for the pseudoscalar masses and decay constants, which include the singlet Nambu-Goldstone boson, as well as for the two condensates. The results can be generalized to more than two representations.

  16. Chiral perturbation theory with tensor sources

    SciTech Connect

    Cata, Oscar; Cata, Oscar; Mateu, Vicent

    2007-05-21

    We construct the most general chirally-invariant Lagrangian for mesons in the presence of external sources coupled to the tensor current \\bar psi sigma_mu nu psi. In order to have only even terms in the chiral expansion, we consider the new source of O(p2). With this choice, we build the even-parity effective Lagrangian up to the p6-order (NLO). While there are only 4 new terms at the p4-order, at p6-order we find 78 terms for n_f=2 and 113 terms for n_f=3. We provide a detailed discussion on the different mechanisms that ensure that our final set of operators is complete and non-redundant. We also examine the odd-parity sector, to conclude that the first operators appear at the p8-order (NNLO).

  17. Chiral perturbation theory for the Wilson lattice action

    SciTech Connect

    Rupak, Gautam; Shoresh, Noam

    2002-01-25

    The authors extend chiral perturbation theory to include linear dependence on the lattice spacing a for the Wilson action. The perturbation theory is written as a double expansion in the small quark mass m{sub q} and lattice spacing a. They present formulae for the mass and decay constant of a flavor-non-singlet meson in this scheme to order a and m{sub q}{sup 2}. The extension to the partially quenched theory is also described.

  18. Staggered chiral perturbation theory in the two-flavor case

    SciTech Connect

    Du Xining

    2010-07-01

    I study two-flavor staggered chiral perturbation theory in the light pseudoscalar sector. The pion mass and decay constant are calculated through next-to-leading order in the partially-quenched case. In the limit where the strange quark mass is large compared to the light quark masses and the taste splittings, I show that the SU(2) staggered chiral theory emerges from the SU(3) staggered chiral theory, as expected. Explicit relations between SU(2) and SU(3) low energy constants and taste-violating parameters are given. The results are useful for SU(2) chiral fits to asqtad data and allow one to incorporate effects from varying strange quark masses.

  19. Electroproduction of pions at threshold in chiral perturbation theory

    SciTech Connect

    Lee, T.S.H.; Bernard, V.; Kaiser, N.; Meissner, U.G.

    1995-08-01

    The electroproduction of pions off protons close to threshold is studied within the framework of baryon chiral perturbation theory. The approach is based on the fundamental QCD property that at low energies the strong interactions are dictated by the spontaneously broken chiral symmetry. The calculation was done up to the 1-loop level by carrying out order-by-order renormalization procedures. A thorough study of the low-energy theorems related to electroproduction of pions was carried out. Our study showed how the axial radius of the nucleon can be related to the S-wave multipoles E{sub 0+}{sup (-)} and L{sub 0+}{sup (-)}.

  20. Including the {delta}(1232) resonance in baryon chiral perturbation theory

    SciTech Connect

    Hacker, C.; Wies, N.; Scherer, S.; Gegelia, J.

    2005-11-01

    Baryon chiral perturbation theory with explicit {delta}(1232) degrees of freedom is considered. The most general interactions of pions, nucleons, and {delta} consistent with all underlying symmetries as well as with the constraint structure of higher-spin fields are constructed. By use of the extended on-mass-shell renormalization scheme, a manifestly Lorentz-invariant effective-field theory with a systematic power counting is obtained. As applications, we discuss the mass of the nucleon, the pion-nucleon {sigma} term, and the pole of the {delta} propagator.

  1. Improving the ultraviolet behavior in baryon chiral perturbation theory

    SciTech Connect

    Djukanovic, D.; Schindler, M.R.; Scherer, S.; Gegelia, J.

    2005-08-15

    We introduce a new formulation of baryon chiral perturbation theory which improves the ultraviolet behavior of propagators and can be interpreted as a smooth cutoff regularization scheme. It is equivalent to the standard approach, preserves all symmetries, and therefore satisfies the Ward identities. Our formulation is equally well defined in the vacuum, one-nucleon, and few-nucleon sectors of the theory. The equations (Bethe-Salpeter, Lippmann-Schwinger, etc.) for the scattering amplitudes of the few-nucleon sector are free of divergences in the new approach. Unlike the usual cutoff regularization, our 'cutoffs' are parameters of the Lagrangian and do not have to be removed.

  2. Chiral perturbation theory and off-shell electromagnetic form factors

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S.

    1995-05-10

    The off-shell electromagnetic vertex of pions and kaons is calculated to {ital O}({ital p}{sup 4}) in the momentum expansion within the framework of chiral perturbation theory to one loop. The formalism of Gasser and Leutwyler is extended to accommodate the most general form for off-shell Green`s functions in the pseudoscalar meson sector. To that end we identify the structures at {ital O}({ital p}{sup 4}) which were initially removed by using the equation of motion of the lowest-order lagrangian. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  3. Virtual Compton scattering off the nucleon in chiral perturbation theory

    SciTech Connect

    Hemmert, T.R.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-03-01

    We investigate the spin-independent part of the virtual Compton scattering (VCS) amplitude off the nucleon within the framework of chiral perturbation theory. We perform a consistent calculation to third order in external momenta according to Weinberg`s power counting. With this calculation we can determine the second- and fourth-order structure-dependent coefficients of the general low-energy expansion of the spin-averaged VCS amplitude based on gauge invariance, crossing symmetry, and the discrete symmetries. We discuss the kinematical regime to which our calculation can be applied and compare our expansion with the multipole expansion by Guichon, Liu, and Thomas. We establish the connection of our calculation with the generalized polarizabilities of the nucleon where it is possible. {copyright} {ital 1997} {ital The American Physical Society}

  4. A quenched study of the Schroedinger functional with chirally rotated boundary conditions: non-perturbative tuning

    SciTech Connect

    Gonzalez-Lopez, Jennifer; Jansen, Karl; Renner, Dru B.; Shindler, Andrea

    2013-02-01

    The use of chirally rotated boundary conditions provides a formulation of the Schroedinger functional that is compatible with automatic O(a) improvement of Wilson fermions up to O(a) boundary contributions. The elimination of bulk O(a) effects requires the non-perturbative tuning of the critical mass and one additional boundary counterterm. We present the results of such a tuning in a quenched setup for several values of the renormalized gauge coupling, from perturbative to non-perturbative regimes, and for a range of lattice spacings. We also check that the correct boundary conditions and symmetries are restored in the continuum limit.

  5. Even- and Odd-Parity Charmed Meson Masses in Heavy Hadron Chiral Perturbation Theory

    SciTech Connect

    Thomas Mehen; Roxanne Springer

    2005-03-01

    We derive mass formulae for the ground state, J{sup P} = 0{sup -} and 1{sup -}, and first excited even-parity, J{sup P} = 0{sup +} and 1{sup +}, charmed mesons including one loop chiral corrections and {Omicron}(1/m{sub c}) counterterms in heavy hadron chiral perturbation theory. We show a variety of fits to the current data. We find that certain parameter relations in the parity doubling model are not renormalized at one loop, providing a natural explanation for the equality of the hyperfine splittings of ground state and excited doublets.

  6. Comparison of the extended linear {sigma} model and chiral perturbation theory

    SciTech Connect

    Alvarez, W.P.; Kubodera, K.; Myhrer, F.

    2005-09-01

    The pion-nucleon-scattering amplitudes are calculated in tree approximation with the use of the extended linear sigma model (ELSM) as well as heavy-baryon chiral perturbation theory (HB{chi}PT), and the nonrelativistic forms of the ELSM results are compared with those of HB{chi}PT. We find that the amplitudes obtained in ELSM do not agree with those derived from the more fundamental effective approach, HB{chi}PT.

  7. Nucleon-to-{delta} axial transition form factors in relativistic baryon chiral perturbation theory

    SciTech Connect

    Geng, L. S.; Camalich, J. Martin; Alvarez-Ruso, L.; Vacas, M. J. Vicente

    2008-07-01

    We report a theoretical study of the axial nucleon-to-delta (1232) (N{yields}{delta}) transition form factors up to one-loop order in relativistic baryon chiral perturbation theory. We adopt a formalism in which the {delta} couplings obey the spin-3/2 gauge symmetry and, therefore, decouple the unphysical spin-1/2 fields. We compare the results with phenomenological form factors obtained from neutrino bubble-chamber data and in quark models.

  8. Pseudoscalar meson mass to two loops in three-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.; Danielsson, Niclas

    2004-12-01

    This paper presents a first study of the pseudoscalar meson masses to two loops, or next-to-next-to-leading order, within the supersymmetric formulation of partially quenched chiral perturbation theory (PQ{chi}PT). The expression for the pseudoscalar meson mass in the case of three valence and three sea quarks with equal masses, but different from each other, is given to O(p{sup 6}), along with a numerical analysis.

  9. Rare decay {eta}{r_arrow}{pi}{pi}{gamma}{gamma} in chiral perturbation theory

    SciTech Connect

    Knoechlein, G.; Scherer, S.; Drechsel, D.

    1996-04-01

    We investigate the rare radiative {eta} decay modes {eta}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma}{gamma} and {eta}{r_arrow}{pi}{sup 0}{pi}{sup 0}{gamma}{gamma} within the framework of chiral perturbation theory at {ital O}({ital p}{sup 4}). We present photon spectra and partial decay rates for both processes as well as a Dalitz contour plot for the charged decay. {copyright} {ital 1996 The American Physical Society.}

  10. Consistency tests of Ampcalculator and chiral amplitudes in SU(3) Chiral Perturbation Theory: A tutorial-based approach

    NASA Astrophysics Data System (ADS)

    Ananthanarayan, B.; Das, Diganta; Sentitemsu Imsong, I.

    2012-10-01

    Ampcalculator (AMPC) is a Mathematica © based program that was made publicly available some time ago by Unterdorfer and Ecker. It enables the user to compute several processes at one loop (upto O( p 4) in SU(3) chiral perturbation theory. They include computing matrix elements and form factors for strong and non-leptonic weak processes with at most six external states. It was used to compute some novel processes and was tested against well-known results by the original authors. Here we present the results of several thorough checks of the package. Exhaustive checks performed by the original authors are not publicly available, and hence the present effort. Some new results are obtained from the software especially in the kaon odd-intrinsic parity non-leptonic decay sector involving the coupling G 27. Another illustrative set of amplitudes at tree level we provide is in the context of τ-decays with several mesons including quark mass effects, of use to the BELLE experiment. All eight meson-meson scattering amplitudes have been checked. The Kaon-Compton amplitude has been checked and a minor error in the published results has been pointed out. This exercise is a tutorial-based one, wherein several input and output notebooks are also being made available as ancillary files on the arXiv. Some of the additional notebooks we provide contain explicit expressions that we have used for comparison with established results. The purpose is to encourage users to apply the software to suit their specific needs. An automatic amplitude generator of this type can provide error-free outputs that could be used as inputs for further simplification, and in varied scenarios such as applications of chiral perturbation theory at finite temperature, density and volume. This can also be used by students as a learning aid in low-energy hadron dynamics.

  11. Pion-nucleon scattering in covariant baryon chiral perturbation theory with explicit Delta resonances

    NASA Astrophysics Data System (ADS)

    Yao, De-Liang; Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A. M.; Gegelia, J.; Krebs, H.; Meißner, Ulf-G.

    2016-05-01

    We present the results of a third order calculation of the pion-nucleon scattering amplitude in a chiral effective field theory with pions, nucleons and delta resonances as explicit degrees of freedom. We work in a manifestly Lorentz invariant formulation of baryon chiral perturbation theory using dimensional regularization and the extended on-mass-shell renormalization scheme. In the delta resonance sector, the on mass-shell renormalization is realized as a complex-mass scheme. By fitting the low-energy constants of the effective Lagrangian to the S- and P -partial waves a satisfactory description of the phase shifts from the analysis of the Roy-Steiner equations is obtained. We predict the phase shifts for the D and F waves and compare them with the results of the analysis of the George Washington University group. The threshold parameters are calculated both in the delta-less and delta-full cases. Based on the determined low-energy constants, we discuss the pion-nucleon sigma term. Additionally, in order to determine the strangeness content of the nucleon, we calculate the octet baryon masses in the presence of decuplet resonances up to next-to-next-to-leading order in SU(3) baryon chiral perturbation theory. The octet baryon sigma terms are predicted as a byproduct of this calculation.

  12. Nonfactorization of four-quark condensates at low energies within chiral perturbation theory

    SciTech Connect

    Gomez Nicola, A.; Pelaez, J. R.; Ruiz de Elvira, J.

    2010-10-01

    Four-quark correlators and the factorization hypothesis are analyzed in the meson sector within chiral perturbation theory. We define the four-quark condensate as lim{sub x{yields}0}, which is equivalent to other definitions commonly used in the literature. Factorization of the four-quark condensate holds to leading and next to leading order. However, at next to next to leading order, a term with a nontrivial space-time dependence in the four-quark correlator yields a divergent four-quark condensate, whereas the two-quark condensate and the scalar susceptibility are finite. Such a nonfactorization term vanishes only in the chiral limit. We also comment on how factorization still holds in the large N{sub c} limit, provided such a limit is taken before renormalization.

  13. The width of the Roper resonance in baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Gegelia, Jambul; Meißner, Ulf-G.; Yao, De-Liang

    2016-09-01

    We calculate the width of the Roper resonance at next-to-leading order in a systematic expansion of baryon chiral perturbation theory with pions, nucleons, and the delta and Roper resonances as dynamical degrees of freedom. Three unknown low-energy constants contribute up to the given order. One of them can be fixed by reproducing the empirical value for the width of the Roper decay into a pion and a nucleon. Assuming that the remaining two couplings of the Roper interaction take values equal to those of the nucleon, the result for the width of the Roper decaying into a nucleon and two pions is consistent with the experimental value.

  14. Three-flavor partially quenched chiral perturbation theory at NNLO for meson masses and decay constants

    SciTech Connect

    Bijnens, Johan; Danielsson, Niclas; Laehde, Timo A.

    2006-04-01

    We discuss partially quenched chiral perturbation theory (PQ{chi}PT) and possible fitting strategies to lattice QCD data at next-to-next-to-leading order (NNLO) in the mesonic sector. We also present a complete calculation of the masses of the charged pseudoscalar mesons, in the supersymmetric formulation of PQ{chi}PT. Explicit analytical results are given for up to three nondegenerate sea-quark flavors, along with the previously unpublished expression for the pseudoscalar meson decay constant for three nondegenerate sea-quark flavors. The numerical analysis in this paper demonstrates that the corrections at NNLO are sizable, as expected from earlier work.

  15. Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2008-06-15

    Recent attempts to determine the pion polarizability by dispersion relations yield values that disagree with the predictions of chiral perturbation theory. These dispersion relations are based on specific forms for the absorptive part of the Compton amplitudes. The analytic properties of these forms are examined, and the strong enhancement of intermediate-meson contributions is shown to be connected with spurious singularities. If the basic requirements of dispersion relations are taken into account, the results of dispersion theory and effective field theory are not inconsistent.

  16. Elastic pion-nucleon scattering in chiral perturbation theory: A fresh look

    NASA Astrophysics Data System (ADS)

    Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A.; Krebs, H.; Meißner, Ulf-G.

    2016-07-01

    Elastic pion-nucleon scattering is analyzed in the framework of chiral perturbation theory up to fourth order within the heavy-baryon expansion and a covariant approach based on an extended on-mass-shell renormalization scheme. We discuss in detail the renormalization of the various low-energy constants and provide explicit expressions for the relevant β functions and the finite subtractions of the power-counting breaking terms within the covariant formulation. To estimate the theoretical uncertainty from the truncation of the chiral expansion, we employ an approach which has been successfully applied in the most recent analysis of the nuclear forces. This allows us to reliably extract the relevant low-energy constants from the available scattering data at low energy. The obtained results provide clear evidence that the breakdown scale of the chiral expansion for this reaction is related to the Δ resonance. The explicit inclusion of the leading contributions of the Δ isobar is demonstrated to substantially increase the range of applicability of the effective field theory. The resulting predictions for the phase shifts are in an excellent agreement with the predictions from the recent Roy-Steiner-equation analysis of pion-nucleon scattering.

  17. Renormalization of the low-energy constants of chiral perturbation theory from loops with dynamical vector mesons

    NASA Astrophysics Data System (ADS)

    Terschlüsen, Carla; Leupold, Stefan

    2016-07-01

    Starting from a relativistic Lagrangian for pseudoscalar Goldstone bosons and vector mesons in the antisymmetric tensor representation, a one-loop calculation is performed to pin down the divergent structures that appear for the effective low-energy action at chiral orders Q2 and Q4 . The corresponding renormalization-scale dependencies of all low-energy constants up to chiral order Q4 are determined. Calculations are carried out for both the pseudoscalar octet and the pseudoscalar nonet, the latter in the framework of chiral perturbation theory in the limit of a large number of colors.

  18. A Lattice Non-Perturbative Definition of an SO(10) Chiral Gauge Theory and Its Induced Standard Model

    NASA Astrophysics Data System (ADS)

    Wen, Xiao-Gang

    2013-11-01

    The standard model is a chiral gauge theory where the gauge fields couple to the right-hand and the left-hand fermions differently. The standard model is defined perturbatively and describes all elementary particles (except gravitons) very well. However, for a long time, we do not know if we can have a non-perturbative definition of the standard model as a Hamiltonian quantum mechanical theory. Here we propose a way to give a modified standard model (with 48 two-component Weyl fermions) a non-perturbative definition by embedding the modified standard model into an SO (10) chiral gauge theory. We show that the SO (10) chiral gauge theory can be put on a lattice (a 3D spatial lattice with a continuous time) if we allow fermions to interact. Such a non-perturbatively defined standard model is a Hamiltonian quantum theory with a finite-dimensional Hilbert space for a finite space volume. More generally, using the defining connection between gauge anomalies and the symmetry-protected topological orders, one can show that any truly anomaly-free chiral gauge theory can be non-perturbatively defined by putting it on a lattice in the same dimension.

  19. K{yields}{pi} and K{yields}0 in 2+1 flavor partially quenched chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, J.; Li, S.; Lin, M. F.

    2008-11-01

    We calculate results for K{yields}{pi} and K{yields}0 matrix elements to next-to-leading order in 2+1 flavor partially quenched chiral perturbation theory. Results are presented for both the {delta}I=1/2 and 3/2 channels, for chiral operators corresponding to current-current, gluonic penguin, and electroweak penguin 4-quark operators. These formulas are useful for studying the chiral behavior of currently available 2+1 flavor lattice QCD results, from which the low-energy constants of the chiral effective theory can be determined. The low-energy constants of these matrix elements are necessary for an understanding of the {delta}I=1/2 rule, and for calculations of {epsilon}{sup '}/{epsilon} using current lattice QCD simulations.

  20. Nuclear-matter equation of state with consistent two- and three-body perturbative chiral interactions

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2014-04-01

    We compute the energy per particle of infinite symmetric nuclear matter from chiral NLO3 (next-to-next-to-next-to-leading order) two-body potentials plus NLO2 three-body forces. The low-energy constants of the chiral three-nucleon force that cannot be constrained by two-body observables are fitted to reproduce the triton binding energy and the H3-He3 Gamow-Teller transition matrix element. In this way, the saturation properties of nuclear matter are reproduced in a parameter-free approach. The equation of state is computed up to third order in many-body perturbation theory, with special emphasis on the role of the third-order particle-hole diagram. The dependence of these results on the cutoff scale and regulator function is studied. We find that the inclusion of three-nucleon forces consistent with the applied two-nucleon interaction leads to a reduced dependence on the choice of the regulator only for lower values of the cutoff.

  1. Equation of state of imbalanced cold matter from chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Carignano, Stefano; Mammarella, Andrea; Mannarelli, Massimo

    2016-03-01

    We study the thermodynamic properties of matter at vanishing temperature for nonextreme values of the isospin chemical potential and of the strange quark chemical potential. From the leading-order pressure obtained by maximizing the static chiral Lagrangian density, we derive a simple expression for the equation of state in the pion condensed phase and in the kaon condensed phase. We find an analytical expression for the maximum of the ratio between the energy density and the Stefan-Boltzmann energy density and for the isospin chemical potential at the peak, both in good agreement with lattice simulations of quantum chromodynamics. We speculate on the location of the crossover from the Bose-Einstein condensate state to the Bardeen-Cooper-Schrieffer state by a simple analysis of the thermodynamic properties of the system. For μI≳2 mπ, the leading-order chiral perturbation theory breaks down; for example, it underestimates the energy density of the system and leads to a wrong asymptotic behavior.

  2. Mass spectra of heavy-light mesons in heavy hadron chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Alhakami, Mohammad H.

    2016-05-01

    We study the masses of the low-lying charm and bottom mesons within the framework of heavy hadron chiral perturbation theory (HHChPT). We work to third order in the chiral expansion, where meson loops contribute. In contrast to previous approaches, we use physical meson masses in evaluating these loops. This ensures that their imaginary parts are consistent with the observed widths of the D mesons. The lowest odd- and even-parity, strange and nonstrange charm mesons provide enough constraints to determine only certain linear combinations of the low-energy constants in the effective Lagrangian. We comment on how lattice QCD could provide further information to disentangle these constants. Then, we use the results from the charm sector to predict the spectrum of odd and even parity of the bottom mesons. The predicted masses from our theory are in good agreement with experimentally measured masses for the case of the odd-parity sector. For the even-parity sector, the B -meson states have not yet been observed; thus, our results provide useful information for experimentalists investigating such states. The near degeneracy of nonstrange and strange scalar B mesons is confirmed in our predictions using HHChPT. We show why previous approaches of using HHChPT in studying the mass degeneracy in the scalar states of charm and bottom meson sectors gave unsatisfactory results.

  3. Off-shell electromagnetic form factors of pions and kaons in chiral perturbation theory

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S. )

    1994-07-01

    The off-shell electromagnetic vertex of a (pseudo)scalar particle contains, in general, two form factors [ital F] and [ital G] which depend, in addition to the squared momentum transfer, on the invariant masses associated with the initial and final legs of the vertex. Chiral perturbation theory to one loop is used to calculate the off-shell form factors of pions and kaons. The formalism of Gasser and Leutwyler, which was previously used to calculate the on-shell limit of the form factor [ital F], is extended to accommodate the most general form for off-shell Green's functions in the pseudoscalar meson sector. We find that chiral symmetry predicts that the form factors [ital F] of the charged pions and kaons go off-shell in the same way, i.e., the off-shell slope at the real photon point is given by the same new phenomenological constant [beta][sub 1]. Furthermore, it is shown that at order [ital p][sup 4] the form factor [ital F] of the [ital K][sup 0] does not show any off-shell dependence. The form factors [ital G] are all related to the form factors [ital F] in the correct fashion as required by the Ward-Takahashi identity. Numerical results for different off-shell kinematics are presented.

  4. Chirality of tensor perturbations for complex values of the Immirzi parameter

    NASA Astrophysics Data System (ADS)

    Bethke, Laura; Magueijo, João

    2012-03-01

    In this communication, we generalize previous work on tensor perturbations in a de Sitter background in terms of Ashtekar variables to cover all complex values of the Immirzi parameter γ (previous work was restricted to imaginary γ). Particular attention is paid to the case of real γ. Following the same approach as in the imaginary case, we can obtain physical graviton states by invoking reality and torsion-free conditions. The Hamiltonian in terms of graviton states has the same form whether γ has a real part or not; however, changes occur for the vacuum energy and fluctuations. Specifically, we observe a γ-dependent chiral asymmetry in the vacuum fluctuations only if γ has an imaginary part. Ordering prescriptions also change this asymmetry. We thus present a measurable result for CMB polarization experiments that could shed light on the workings of quantum gravity.

  5. Heavy-baryon chiral perturbation theory approach to thermal neutron capture on {sup 3}He

    SciTech Connect

    Lazauskas, Rimantas; Park, Tae-Sun

    2011-03-15

    The cross section for radiative thermal neutron capture on {sup 3}He ({sup 3}He+n{yields}{sup 4}He+{gamma}; known as the hen reaction) is calculated based on heavy-baryon chiral perturbation theory. The relevant M1 operators are derived up to next-to-next-to-next-to-leading order (N{sup 3}LO). The initial and final nuclear wave functions are obtained from the rigorous Faddeev-Yakubovski equations for five sets of realistic nuclear interactions. Up to N{sup 3}LO, the M1 operators contain two low-energy constants, which appear as the coefficients of nonderivative two-nucleon contact terms. After determining these two constants using the experimental values of the magnetic moments of the triton and {sup 3}He, we carry out a parameter-free calculation of the hen cross section. The results are in good agreement with the data.

  6. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Kao, C.-W.; Pasquini, Barbara; Vanderhaeghen, Marc

    2004-12-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering at O(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low-energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the virtual Compton scattering amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double-polarization experiments which allow one to access these spin-flip GPs of the nucleon.

  7. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Chung-Wen Kao; Barbara Pasquini; Marc Vanderhaeghen

    2004-08-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering (VCS) at {Omicron}(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the VCS amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double polarization experiments which allow to access these spin-flip GPs of the nucleon.

  8. Reply to 'Comment on 'Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory''

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2010-02-15

    We show that the alleged discrepancies between chiral perturbation theory (ChPT) and dispersion theory, reported for the polarizability of the pion by Fil'kov and Kashevarov [Phys. Rev. C 72, 035211 (2005)], result from applying dispersion theory to nonanalytic functions.

  9. Twisted mass chiral perturbation theory at next-to-leading order

    NASA Astrophysics Data System (ADS)

    Sharpe, Stephen R.; Wu, Jackson M.

    2005-04-01

    We study the properties of pions in twisted mass lattice QCD (with two degenerate flavors) using chiral perturbation theory (χPT). We work to next-to-leading order (NLO) in a power-counting scheme in which mq˜aΛ2QCD, with mq the physical quark mass and a the lattice spacing. We argue that automatic O(a) improvement of physical quantities at maximal twist, which has been demonstrated in general if mq≫aΛ2QCD, holds even if mq˜aΛ2QCD, as long as one uses an appropriate nonperturbative definition of the twist angle, with the caveat that we have shown this only through NLO in our chiral expansion. We demonstrate this with explicit calculations, for arbitrary twist angle, of all pionic quantities that involve no more than a single pion in the initial and final states: masses, decay constants, form factors, and condensates, as well as the differences between alternate definitions of twist angle. We also calculate the axial and pseudoscalar form factors of the pion, quantities which violate flavor and parity, and which vanish in the continuum limit. These are of interest because they are not automatically O(a) improved at maximal twist. They allow a determination of the unknown low-energy constants introduced by discretization errors, and provide tests of the accuracy of χPT at NLO. We extend our results into the regime where mq˜a2Λ3QCD, and argue in favor of a recent proposal that automatic O(a) improvement at maximal twist remains valid in this regime.

  10. Chiral Perturbation Theory, the 1/N_c expansion and Regge behavior determine the structure of the lightest scalar meson

    SciTech Connect

    Pelaez, J. R.; Michael R. Pennington; de Elvira, J. Ruiz; Wilson, D. J.

    2011-11-01

    The leading 1/N{sub c} behavior of Unitarized Chiral Perturbation Theory distinguishes the nature of the {rho} and the {sigma}. At one loop order the {rho} is a {bar q}q meson, while the {sigma} is not. However, semi-local duality between resonances and Regge behaviour cannot be satisfied for larger N{sub c}, if such a distinction holds. While the {sigma} at N{sub c}= 3 is inevitably dominated by its di-pion component, Unitarised Chiral Perturbation Theory beyond one loop order reveals that as N{sub c} increases above 6-8, the {sigma} has a sub-dominant {bar q}q fraction up at 1.2 GeV. Remarkably this ensures semi-local duality is fulfilled for the range of N{sub c} {approx}< 15-30, where the unitarization procedure adopted applies.

  11. Nuclear structure with accurate chiral perturbation theory nucleon-nucleon potential: Application to 6Li and 10B

    SciTech Connect

    Navratil, P; Caurier, E

    2003-10-14

    The authors calculate properties of A = 6 system using the accurate charge-dependent nucleon-nucleon (NN) potential at fourth order of chiral perturbation theory. By application of the ab initio no-core shell model (NCSM) and a variational calculation in the harmonic oscillator basis with basis size up to 16 {h_bar}{Omega} they obtain the {sup 6}Li binding energy of 28.5(5) MeV and a converged excitation spectrum. Also, they calculate properties of {sup 10}B using the same NN potential in a basis space of up to 8 {h_bar}{Omega}. The results are consistent with results obtained by standard accurate NN potentials and demonstrate a deficiency of Hamiltonians consisting of only two-body terms. At this order of chiral perturbation theory three-body terms appear. It is expected that inclusion of such terms in the Hamiltonian will improve agreement with experiment.

  12. Weak solution of the non-perturbative renormalization group equation to describe dynamical chiral symmetry breaking

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Kumamoto, Shin-Ichiro; Sato, Daisuke

    2014-04-01

    We analyze dynamical chiral symmetry breaking (Dχ SB) in the Nambu-Jona-Lasinio model by using the non-perturbative renormalization group equation. The equation takes the form of a two-dimensional partial differential equation for the multi-fermion effective interactions V(x,t) where x is the bar {ψ }ψ operator and t is the logarithm of the renormalization scale. The Dχ SB occurs due to the quantum corrections, which means it emerges at some finite tc while integrating the equation with respect to t. At t_c some singularities suddenly appear in V which is compulsory in the spontaneous symmetry breakdown. Therefore there is no solution of the equation beyond tc. We newly introduce the notion of a weak solution to get the global solution including the infrared limit t rArr ∞ and investigate its properties. The obtained weak solution is global and unique, and it perfectly describes the physically correct vacuum even in the case of the first order phase transition appearing in a finite-density medium. The key logic of deduction is that the weak solution we defined automatically convexifies the effective potential when treating the singularities.

  13. Muon capture by a proton in heavy baryon chiral perturbation theory

    SciTech Connect

    Fearing, H.W.; Lewis, R.; Mobed, N.; Scherer, S.

    1997-08-01

    The matrix element for muon capture by a proton is calculated to O(p{sup 3}) within heavy baryon chiral perturbation theory using the new O(p{sup 3}) Lagrangian of Ecker and Moj{hacek z}i{hacek s}. External nucleon fields are renormalized using the appropriate definition of the wave function renormalization factor Z{sub N}. Our expression for Z{sub N} differs somewhat from that found in the existing literature, but is the one which is consistent with the Lagrangian we use and the one which ensures, within our approach, the nonrenormalization of the vector coupling as required by the conserved vector current. Expressions for the standard muon capture form factors are derived and compared to experimental data and we determine three of the coefficients of the Ecker-Moj{hacek z}i{hacek s} Lagrangian, namely, b{sub 7}, b{sub 19}, and b{sub 23}. {copyright} {ital 1997} {ital The American Physical Society}

  14. Field transformations and the classical equation of motion in chiral perturbation theory

    SciTech Connect

    Scherer, S.; Fearing, H.W.

    1995-12-01

    The construction of effective Lagrangians commonly involves the application of the ``classical equation of motion`` to eliminate redundant structures and thus generate the minimal number of independent terms. We investigate this procedure in the framework of chiral perturbation theory with particular emphasis on the new features which appear at {ital O}({ital p}{sup 6}). The use of the ``classical equation of motion`` is interpreted in terms of field transformations. Such an interpretation is crucial if one wants to bring a given Lagrangian into a canonical form with a minimal number of terms. We emphasize that the application of field transformations leads to a modification of the coefficients of higher-order terms as well as eliminating structures, or what is equivalent, expressing certain structures in terms of already known different structures. This will become relevant once one considers the problem of expressing in canonical form a model effective interaction containing terms beyond next-to-leading order, i.e., beyond {ital O}({ital p}{sup 4}). In such circumstances the naive application of the clasical equation of motion to simply drop terms, as is commonly done at lowest order, leads to subtle errors, which we discuss.

  15. The Kaon B-parameter in mixed action chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2006-09-01

    We calculate the kaon B-parameter, B{sub K}, in chiral perturbation theory for a partially quenched, mixed action theory with Ginsparg-Wilson valence quarks and staggered sea quarks. We find that the resulting expression is similar to that in the continuum, and in fact has only two additional unknown parameters. At one-loop order, taste-symmetry violations in the staggered sea sector only contribute to flavor-disconnected diagrams by generating an {Omicron}(a{sup 2}) shift to the masses of taste-singlet sea-sea mesons. Lattice discretization errors also give rise to an analytic term which shifts the tree-level value of B{sub K} by an amount of {Omicron}(a{sup 2}). This term, however, is not strictly due to taste-breaking, and is therefore also present in the expression for B{sub K} for pure G-W lattice fermions. We also present a numerical study of the mixed B{sub K} expression in order to demonstrate that both discretization errors and finite volume effects are small and under control on the MILC improved staggered lattices.

  16. Decay constants of pseudoscalar mesons to two loops in three-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.

    2005-05-01

    This paper presents a first study of the decay constants of the charged, or flavor-off-diagonal, pseudoscalar mesons to two loops for three flavors of sea quarks, in partially quenched chiral perturbation theory (PQ{chi}PT). Explicit analytical expressions up to O(p{sup 6}) in the momentum expansion are given. The calculations have been performed within the supersymmetric formulation of PQ{chi}PT. We also present some numerical results to indicate the size of the corrections.

  17. Doubly heavy baryons and quark-diquark symmetry in quenched and partially quenched chiral perturbation theory

    SciTech Connect

    Thomas Mehen; Brian C. Tiburzi

    2006-07-17

    We extend the chiral Lagrangian with heavy quark-diquark symmetry to quenched and partially quenched theories. These theories are used to derive formulae for the chiral extrapolation of masses and hyperfine splittings of doubly heavy baryons in lattice QCD simulations. A quark-diquark symmetry prediction for the hyperfine splittings of heavy mesons and doubly heavy baryons is rather insensitive to chiral corrections in both quenched and partially quenched QCD. Extrapolation formulae for the doubly heavy baryon electromagnetic transition moments are also determined for the partially quenched theory.

  18. Masses and decay constants of pseudoscalar mesons to two loops in two-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.

    2005-10-01

    This paper presents a first study of the masses and decay constants of the charged, or flavor-off-diagonal, pseudoscalar mesons to two loops for two flavors of sea-quarks, in Partially Quenched Chiral Perturbation Theory (PQ{chi}PT). Explicit analytical expressions up to O(p{sup 6}) in the momentum expansion are given. The calculations have been performed within the supersymmetric formulation of PQ{chi}PT. A numerical analysis is done to indicate the size of the corrections.

  19. Chiral perturbation theory for staggered sea quarks and Ginsparg-Wilson valence quarks

    SciTech Connect

    Baer, Oliver; Bernard, Claude; Rupak, Gautam; Shoresh, Noam

    2005-09-01

    We study lattice QCD with staggered sea and Ginsparg-Wilson valence quarks. The Symanzik effective action for this mixed lattice theory, including the lattice spacing contributions of O(a{sup 2}), is derived. Using this effective theory we construct the leading-order chiral Lagrangian. The masses and decay constants of pseudoscalars containing two Ginsparg-Wilson valence quarks are computed at one-loop order.

  20. B -> d* l nu and b -> d l nu form-factors in staggered chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2005-12-01

    We calculate the B {yields} D and B {yields} D* form factors at zero recoil in Staggered Chiral Perturbation Theory. We consider heavy-light mesons in which only the light (u, d, or s) quark is staggered; current lattice simulations generally use a highly improved action such as the Fermilab or NRQCD action for the heavy (b or c) quark. We work to lowest order in the heavy quark expansion and to next-to-leading order in the chiral expansion. We present results for a partially quenched theory with three sea quarks in which there are no mass degeneracies (the ''1+1+1'' theory) and for a partially quenched theory in which the u and d sea quark masses are equal (the ''2+1'' theory). We also present results for full (2+1) QCD, along with a numerical estimate of the size of staggered discretization errors. Finally, we calculate the finite volume corrections to the form factors and estimate their numerical size in current lattice simulations.

  1. Low energy constants of S U (2 ) partially quenched chiral perturbation theory from Nf=2 +1 domain wall QCD

    NASA Astrophysics Data System (ADS)

    Boyle, P. A.; Christ, N. H.; Garron, N.; Jung, C.; Jüttner, A.; Kelly, C.; Mawhinney, R. D.; McGlynn, G.; Murphy, D. J.; Ohta, S.; Portelli, A.; Sachrajda, C. T.

    2016-03-01

    We have performed fits of the pseudoscalar masses and decay constants, from a variety of the RBC-UKQCD Collaboration's domain wall fermion ensembles, to S U (2 ) partially quenched chiral perturbation theory at next-to-leading order (NLO) and next-to-next-to-leading order (NNLO). We report values for nine NLO and eight linearly independent combinations of NNLO partially quenched low-energy constants, which we compare to other lattice and phenomenological determinations. We discuss the size of successive terms in the chiral expansion and use our large set of low-energy constants to make predictions for mass splittings due to QCD isospin-breaking effects and the S-wave π π scattering lengths. We conclude that, for the range of pseudoscalar masses explored in this work, 115 MeV ≲mPS≲430 MeV , the NNLO S U (2 ) expansion is quite robust and can fit lattice data with percent-scale accuracy.

  2. Neutral pion threshold production at Q(2) = 0.05 GeV(2)/c(2) and chiral perturbation theory.

    PubMed

    Merkel, H; Bartsch, P; Baumann, D; Bermuth, J; Bernstein, A M; Bohinc, K; Böhm, R; Clawiter, N; Derber, S; Ding, M; Distler, M O; Ewald, I; Friedrich, J M; Friedrich, J; Jennewein, P; Kahrau, M; Kohl, M; Krygier, K W; Kuss, M; Liesenfeld, A; Merle, P; Miskimen, R A; Müller, U; Neuhausen, R; Pavan, M M; Pospischil, Th; Potokar, M; Rosner, G; Schmieden, H; Seimetz, M; Sirca, S; Wagner, A; Walcher, Th; Weis, M

    2002-01-01

    New data are presented on the p(e,e'p)pi(0) reaction at threshold at a four-momentum transfer of Q(2) = 0.05 GeV(2)/c(2). The data were taken with the three-spectrometer setup of the A1 Collaboration at the Mainz Microtron MAMI. The complete center of mass solid angle was covered up to a center of mass energy of 4 MeV above threshold. Combined with measurements at three different values of the virtual photon polarization epsilon, the structure functions sigma(T), sigma(L), sigma(TT), and sigma(TL) are determined. The results are compared with calculations in heavy baryon chiral perturbation theory and with a phenomenological model. The measured cross section is significantly smaller than both predictions. PMID:11800938

  3. Axial, induced pseudoscalar, and pion-nucleon form factors in manifestly Lorentz-invariant chiral perturbation theory

    SciTech Connect

    Schindler, M. R.; Fuchs, T.; Scherer, S.; Gegelia, J.

    2007-02-15

    We calculate the nucleon form factors G{sub A} and G{sub P} of the isovector axial-vector current and the pion-nucleon form factor G{sub {pi}}{sub N} in manifestly Lorentz-invariant baryon chiral perturbation theory up to and including order O(p{sup 4}). In addition to the standard treatment including the nucleon and pions, we also consider the axial-vector meson a{sub 1} as an explicit degree of freedom. This is achieved by using the reformulated infrared renormalization scheme. We find that the inclusion of the axial-vector meson effectively results in one additional low-energy coupling constant that we determine by a fit to the data for G{sub A}. The inclusion of the axial-vector meson results in an improved description of the experimental data for G{sub A}, while the contribution to G{sub P} is small.

  4. Higher moments of nucleon spin structure functions in heavy baryon chiral perturbation theory and in a resonance model

    SciTech Connect

    C. Kao; D. Drechsel; S. Kamalov; M. Vanderhaeghen

    2003-11-01

    The third moment d{sub 2} of the twist-3 part of the nucleon spin structure function g{sub 2} is generalized to arbitrary momentum transfer Q{sup 2} and is evaluated in heavy baryon chiral perturbation theory (HBChPT) up to order {Omicron}(p{sup 4}) and in a unitary isobar model (MAID). We show how to link d{sub 2} as well as higher moments of the nucleon spin structure functions g{sub 1} and g{sub 2} to nucleon spin polarizabilities. We compare our results with the most recent experimental data, and find a good description of these available data within the unitary isobar model. We proceed to extract the twist-4 matrix element f{sub 2} which appears in the 1/Q{sup 2} suppressed term in the twist expansion of the spin structure function g{sub 1} for proton and neutron.

  5. Weak Solution Method of the Non-Perturbative Renormalization Group Equation to Describe Dynamical Chiral Symmetry Breaking and its Application to Beyond the Ladder Analysis in QCD

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Sato, Daisuke

    The method of non-perturbative renormalization group (NPRG) is applied to the analysis of dynamical chiral symmetry breaking (DχSB) in QCD. We show that the DχSB solution of the NPRG flow equation can be obtained without the bosonization. The solution, having the singular point, can be authorized as the weak solution of partial differential equation, and can be easily evaluated using the method of the characteristic curve. Also we show that our non-ladder extended approximation improves almost perfectly the gauge dependence of the chiral condensates.

  6. Extension of the chiral perturbation theory meson Lagrangian to order {ital p}{sup 6}

    SciTech Connect

    Fearing, H.W.; Scherer, S.

    1996-01-01

    We have constructed the most general chirally invariant Lagrangian {ital scrL}{sub 6} for the meson sector at order {ital p}{sup 6}. The result provides an extension of the standard Gasser-Leutwyler Lagrangian {ital scrL}{sub 4} to one higher order, including as well all the odd intrinsic parity terms in the Lagrangian. The most difficult part of the construction was developing a systematic strategy so as to get all of the independent terms and eliminate the redundant ones in an efficient way. The claim to have obtained the most general Lagrangian relies on this systematic construction and on the elimination of redundant quantities using relations of which we are aware, rather than on a general formal proof of either completeness or independence. The {open_quote}{open_quote}equation-of-motion{close_quote}{close_quote} terms, which are redundant in the sense that they can be transformed away via field transformations, are separated out explicitly. The resulting Lagrangian has been separated into groupings of terms contributing to increasingly more complicated processes, so that one does not have to deal with the full result when calculating {ital p}{sup 6} contributions to simple processes. {copyright} {ital 1995 The American Physical Society.}

  7. Study of K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} in chiral perturbation theory

    SciTech Connect

    Tsuji, K.; Sato, T.

    2008-03-01

    K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} decay rates are studied up to the next-to-leading order (O{sup (4)}) in chiral perturbation theory. It is found that the O{sup (4)} terms appreciably modify the shape of the invariant mass distribution of leptons (M{sub 3e{nu}}) and the energy spectrum of neutrinos.

  8. Proton polarisability contribution to the Lamb shift in muonic hydrogen at fourth order in chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    McGovern, Judith

    2013-04-01

    The recent determination of the proton charge radius from the Lamb shift in muonic hydrogen [1] gives a value that differs by many standard deviations from the CODATA value [2] and from the results of recent electron scattering experiments [3]. In the theoretical calculations [4], the least-well-determined contribution is the ``proton polarisability'' contribution. This is the part of the two-photon exchange which involves proton excitations. The dominant effect can be determined via dispersion relations from the proton structure functions, but a subtraction term remains [5,6]. This subtraction term is the amplitude T1(0,Q^2) for forward, zero-energy, doubly-virtual Compton scattering, which we calculate in heavy-baryon chiral perturbation theory, to fourth order in the chiral expansion and with the leading contribution of the γNδ form factor. This provides a model-independent expression for the amplitude in the low-momentum region, which is the dominant one for its contribution to the Lamb shift, and allows us to significantly reduce the theoretical uncertainty in the latter [7].[4pt] [1] R. Pohl et al., Nature 466, 213 (2010).[0pt] [2] P. J. Mohr, B. N. Taylor and D. B. Newell, Rev. Mod. Phys. 80, 633 (2008) [arXiv:0801.0028].[0pt] [3] J. C. Bernauer et al. (A1 Collaboration), Phys. Rev. Lett. 105, 242001 (2010) [arXiv:1007.5076].[0pt] [4] U. D. Jentschura, Ann. Phys. 326, 500 (2011) [arXiv:1011.5275]; E. Borie, Ann. Phys. 327, 733 (2012) [arXiv:1103.1772].[0pt] [5] K. Pachucki, Phys. Rev. A 60, 3593 (1999) [arXiv:physics/9906002].[0pt] [6] C. E. Carlson and M. Vanderhaeghen, Phys. Rev. A 84, 020102 (2011) [arXiv:1101.5965]; also [arXiv:1109.3779].[0pt] [7] M. C. Birse and J. A. McGovern, Eur. Phys. J. A48, 120 (2012) [arXiv:1206.3030].

  9. Chiral perturbation theory for K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay in the continuum and on the lattice

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1997-09-01

    In this paper we use one-loop chiral perturbation theory in order to compare lattice computations of the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude with the experimental value. This makes it possible to investigate three systematic effects that plague lattice computations: quenching, finite-volume effects, and the fact that lattice computations have been done at unphysical values of the quark masses and pion external momenta (only this latter effect shows up at the tree level). We apply our results to the most recent lattice computation and find that all three effects are substantial. We conclude that one-loop corrections in chiral perturbation theory help in explaining the discrepancy between lattice results and the real-world value. We also reexamine B{sub K}, which is closely related to the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude by chiral symmetry. {copyright} {ital 1997} {ital The American Physical Society}

  10. Up to N{sup 3}LO heavy-baryon chiral perturbation theory calculation for the M1 properties of three-nucleon systems

    SciTech Connect

    Song, Young-Ho; Lazauskas, Rimantas; Park, Tae-Sun

    2009-06-15

    M1 properties, comprising magnetic moments and radiative capture of thermal neutron observables, are studied in two- and three-nucleon systems. We use meson exchange current derived up to N{sup 3}LO using heavy baryon chiral perturbation theory a la Weinberg. Calculations have been performed for several qualitatively different realistic nuclear Hamiltonians, which permits us to analyze model dependence of our results. Our results are found to be strongly correlated with the effective range parameters such as binding energies and the scattering lengths. Taking into account such correlations, the results are in good agreement with the experimental data with small model dependence.

  11. Determination of SU(2) chiral perturbation theory low energy constants from a precise description of pion-pion scattering threshold parameters

    NASA Astrophysics Data System (ADS)

    Nebreda, J.; Peláez, J. R.; Ríos, G.

    2013-09-01

    We determine the values of the one- and two-loop low energy constants appearing in the SU(2) Chiral Perturbation Theory calculation of pion-pion scattering. For this we use a recent and precise sum rule determination of some scattering lengths and slopes that appear in the effective range expansion. In addition we provide sum rules for these coefficients up to third order in the expansion. Our results when using only the scattering lengths and slopes of the S, P, D, and F waves are consistent with previous determinations but seem to require higher order contributions if they are to accommodate the third order coefficients of the effective range expansion.

  12. Introduction to chiral symmetry

    SciTech Connect

    Koch, V.

    1996-01-08

    These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented.

  13. Nucleon electromagnetic form factors from lattice QCD using 2+1 flavor domain wall fermions on fine lattices and chiral perturbation theory

    SciTech Connect

    Syritsyn, S. N.; Bratt, J. D.; Lin, M. F.; Meyer, H. B.; Negele, J. W.; Pochinsky, A. V.; Procura, M.; Engelhardt, M.; Haegler, Ph.; Hemmert, T. R.; Schroers, W.

    2010-02-01

    We present a high-statistics calculation of nucleon electromagnetic form factors in N{sub f}=2+1 lattice QCD using domain wall quarks on fine lattices, to attain a new level of precision in systematic and statistical errors. Our calculations use 32{sup 3}x64 lattices with lattice spacing a=0.084 fm for pion masses of 297, 355, and 403 MeV, and we perform an overdetermined analysis using on the order of 3600 to 7000 measurements to calculate nucleon electric and magnetic form factors up to Q{sup 2{approx_equal}}1.05 GeV{sup 2}. Results are shown to be consistent with those obtained using valence domain wall quarks with improved staggered sea quarks, and using coarse domain wall lattices. We determine the isovector Dirac radius r{sub 1}{sup v}, Pauli radius r{sub 2}{sup v} and anomalous magnetic moment {kappa}{sub v}. We also determine connected contributions to the corresponding isoscalar observables. We extrapolate these observables to the physical pion mass using two different formulations of two-flavor chiral effective field theory at one loop: the heavy baryon small scale expansion and covariant baryon chiral perturbation theory. The isovector results and the connected contributions to the isoscalar results are compared with experiment, and the need for calculations at smaller pion masses is discussed.

  14. f{sub 0}(600),{kappa}(800), {rho}(770) and K*(892), quark mass dependence from unitarized SU(3) Chiral Perturbation Theory

    SciTech Connect

    Nebreda, J.; Pelaez, J. R.

    2010-08-05

    We study the strange and non-strange quark mass dependence of the parameters of the f{sub 0}(600),{kappa}(800), {rho}(770) and K*(892) resonances generated from elastic meson-meson scattering using unitarized one-loop Chiral Perturbation Theory. We fit simultaneously all experimental scattering data up to 0.8-1 GeV together with lattice results on decay constants and scattering lengths up to a pion mass of 440 MeV. Then, the strange and non-strange quark masses are varied from the chiral limit up to values of interest for lattice studies. In these amplitudes, the mass and width of the {rho}(770) and K*(892) present a similar and smooth quark mass dependence. In contrast, both scalars present a similar non-analyticity at high quark masses. Nevertheless the f{sub 0}(600) dependence on both quark masses is stronger than for the {kappa}(800) and the vectors. We also confirm the lattice assumption of quark mass independence of the vector two-meson coupling that, in contrast, is violated for scalars.

  15. Nucleon and Delta axial-vector couplings in 1/N{sub c}-Baryon Chiral Perturbation Theory

    SciTech Connect

    Goity, Jose Luis; Calle Cordon, Alvaro

    2013-08-01

    In this contribution, baryon axial-vector couplings are studied in the framework of the combined 1/N{sub c} and chiral expansions. This framework is implemented on the basis of the emergent spin-flavor symmetry in baryons at large N{sub c} and HBChPT, and linking both expansions ({xi}-expansion), where 1/N{sub c} is taken to be a quantity order p. The study is carried out including one-loop contributions, which corresponds to order xi to the third for baryon masses and order {xi} square for the axial couplings.

  16. Chiral corrections to the scalar form factor in B{sub q}{yields}D{sub q} transitions

    SciTech Connect

    Eeg, Jan O.; Fajfer, Svjetlana; Kamenik, Jernej F.

    2008-10-01

    We consider chiral loop corrections to the scalar form factor in B{sub q}{yields}D{sub q}l{nu} decays. First we consider chiral corrections to the 1/m{sub Q} suppressed operators and then we propose a procedure for the extraction of the relevant form factor using lattice QCD results. In particular, the extraction of a B*{yields}D* matrix element on the lattice can be used to determine all the necessary 1/m{sub Q} suppressed contributions to the scalar form factor in B{yields}D transitions. In the case of (B{sub s}{yields}D{sub s})/(B{yields}D) decay rate ratios we speculate that effects of kinematics and chiral corrections tend to cancel for the scalar form factor contributions. In particular the 1/m{sub Q} suppression of chiral corrections is compensated by the potentially large SU(3) flavor symmetry breaking corrections. The calculated corrections are relevant for the precise determination of possible new physics effects in B{sub q}{yields}D{sub q}l{nu} decays.

  17. Lattice extraction of K{yields}{pi}{pi} amplitudes to next-to-leading order in partially quenched and in full chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Soni, Amarjit

    2005-01-01

    We show that it is possible to construct {epsilon}{sup '}/{epsilon} to next-to-leading order (NLO) using partially quenched chiral perturbation theory (PQChPT) from amplitudes that are computable on the lattice. We demonstrate that none of the needed amplitudes require 3-momentum on the lattice for either the full theory or the partially quenched theory; nondegenerate quark masses suffice. Furthermore, we find that the electro-weak penguin ({delta}I=3/2 and 1/2) contributions to {epsilon}{sup '}/{epsilon} in PQChPT can be determined to NLO using only degenerate (m{sub K}=m{sub {pi}}) K{yields}{pi} computations without momentum insertion. Issues pertaining to power divergent contributions, originating from mixing with lower dimensional operators, are addressed. Direct calculations of K{yields}{pi}{pi} at unphysical kinematics are plagued with enhanced finite volume effects in the (partially) quenched theory, but in simulations when the sea quark mass is equal to the up and down quark mass the enhanced finite volume effects vanish to NLO in PQChPT. In embedding the QCD penguin left-right operator onto PQChPT an ambiguity arises, as first emphasized by Golterman and Pallante. With one version [the 'PQS' (patially quenched singlet)] of the QCD penguin, the inputs needed from the lattice for constructing K{yields}{pi}{pi} at NLO in PQChPT coincide with those needed for the full theory. Explicit expressions for the finite logarithms emerging from our NLO analysis to the above amplitudes also are given.

  18. The covariant chiral ring

    NASA Astrophysics Data System (ADS)

    Bourget, Antoine; Troost, Jan

    2016-03-01

    We construct a covariant generating function for the spectrum of chiral primaries of symmetric orbifold conformal field theories with N = (4 , 4) supersymmetry in two dimensions. For seed target spaces K3 and T 4, the generating functions capture the SO(21) and SO(5) representation theoretic content of the chiral ring respectively. Via string dualities, we relate the transformation properties of the chiral ring under these isometries of the moduli space to the Lorentz covariance of perturbative string partition functions in flat space.

  19. Extraction of {gamma} from charmless hadronic B {yields} PP decays using SU(3) flavor symmetry

    SciTech Connect

    Suprun, Denis A.

    2006-07-11

    The decays of B mesons to a pair of charmless pseudoscalar mesons (PP decays) have been analyzed within the framework of flavor SU(3) symmetry and quark-diagrammatic topological approach. Flavor symmetry breaking is taken into account in tree (T) amplitudes through ratios of decay constants fK and f{pi}; exact SU(3) is assumed elsewhere. Acceptable fits to B {yields} PP branching ratios and CP asymmetries are obtained with tree, color-suppressed and QCD penguin amplitudes. Singlet penguin amplitude was introduced to describe decay amplitudes of the modes with {eta} and {eta}' mesons in the final state. Electroweak penguin amplitudes were expressed in terms of the corresponding tree-level diagrams. Values of the weak phase {gamma} were found to be consistent with the current indirect bounds from other analyses of CKM parameters.

  20. Complete leading order analysis in Chiral Perturbation Theory of the decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sub +}l{sub {minus}}{gamma}

    SciTech Connect

    J. L. Goity; Longzhe Zhang

    1997-02-01

    The decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} are studied at the leading order p{sup 6} in Chiral Perturbation Theory. One-loop contributions stemming from the odd intrinsic parity {vert_bar}{Delta}S{vert_bar}=1 effective Lagrangian of order p{sup 4} are included and shown to be of possible relevance. They affect the decay K{sub L}{r_arrow}{gamma}{gamma} adding to the usual pole terms a piece free of counterterm uncertainties. In the case of the K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} decays the dependence of the form factor on the dilepton invariant mass requires a counterterm. The form factor may receive a sizeable contribution from chiral logarithms. Including considerations from the K{sub L}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma} direct emission amplitude, the authors obtain two consistent scenarios. In one scenario the long distance contributions from the one-loop terms are important, while in the other they are marginal. In both cases the counterterm is shown to be significant.

  1. A lattice formulation of chiral gauge theories

    SciTech Connect

    Bodwin, G.T.

    1996-08-01

    We present a method for implementing gauge theories of chiral fermions on the lattice. Discussed topics include: the lattice as a UV regulator, a chiral QED model, modification of the fermion determinant, large gauge-field momenta, and a non-perturbative problem.

  2. Chiral squaring

    NASA Astrophysics Data System (ADS)

    Nagy, S.

    2016-07-01

    We construct the states and symmetries of N = 4 super-Yang-Mills by tensoring two N = 1 chiral multiplets and introducing two extra SUSY generators. This allows us to write the maximal N = 8 supergravity as four copies of the chiral multiplet. We extend this to higher dimensions and discuss applications to scattering amplitudes.

  3. Chiral superconductors.

    PubMed

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed. PMID:27088452

  4. Chiral superconductors

    NASA Astrophysics Data System (ADS)

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.

  5. Isotopic chirality

    SciTech Connect

    Floss, H.G.

    1994-12-01

    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  6. Chiral nucleon-nucleon forces in nuclear structure calculations

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Gargano, A.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2016-05-01

    Realistic nuclear potentials, derived within chiral perturbation theory, are a major breakthrough in modern nuclear structure theory, since they provide a direct link between nuclear physics and its underlying theory, namely the QCD. As a matter of fact, chiral potentials are tailored on the low-energy regime of nuclear structure physics, and chiral perturbation theory provides on the same footing two-nucleon forces as well as many-body ones. This feature fits well with modern advances in ab-initio methods and realistic shell-model. Here, we will review recent nuclear structure calculations, based on realistic chiral potentials, for both finite nuclei and infinite nuclear matter.

  7. Punctuated Chirality

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life’s homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average.

  8. Punctuated chirality.

    PubMed

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average. PMID:18841492

  9. Prebiotic chirality

    NASA Astrophysics Data System (ADS)

    Mekki-Berrada, Ali

    Bringing closer phospholipids each other on a bilayer of liposome, causes their rotation around their fatty acids axis, generating a force which brings closer the two sheets of the bilayer. In this theoretical study I show that for getting the greater cohesion of the liposome, by these forces, the serine in the hydrophilic head must have a L chirality. In the case where the hydrophilic head is absent amino acids with L chirality could contribute to this cohesion by taking the place of L-serine. Some coenzymes having a configuration similar to ethanolamine may also contribute. This is the case of pyridoxamine, thiamine and tetrahydrofolic acid. The grouping of amino acids of L chirality and pyridoxamine on the wall could initialize the prebiotic metabolism of these L amino acids only. This would explain the origin of the homo-chirality of amino acids in living world. Furthermore I show that in the hydrophilic head, the esterification of glycerol-phosphate by two fatty acids go through the positioning of dihydroxyacetone-phosphate and L-glyceraldehyde-3-phosphate, but not of D-glyceraldehyde-3-phosphate, prior their hydrogenation to glycerol-3- phosphate. The accumulation of D-glyceraldehyde-3-phosphate in the cytoplasm displace the thermodynamic equilibria towards the synthesis of D-dATP from D-glyceraldehyde-3-phosphate, acetaldehyde and prebiotic adenine, a reaction which does not require a coenzyme in the biotic metabolism. D-dATP and thiamine, more prebiotic metabolism of L-amino acids on the wall, would initialize D-pentoses phosphate and D-nucleotides pathways from the reaction of D-glyceraldehyde-3-phosphate + dihydroxyacetone-phosphate + prebiotic nucleic bases. The exhaustion of the prebiotic glyceraldehyde (racemic) and the nascent biotic metabolism dominated by D-glyceraldehyde-3-phosphate, would explain the origin of homo-chirality of sugars in living world. References: http://en.wikiversity.org/wiki/Prebiotic_chirality

  10. Quenched QED in the chiral limit. [QED (quantum electrodynamics)

    SciTech Connect

    Vandermark, S.W.

    1993-01-01

    The main goal in this project has been to understand, through analytical methods, whether there could be a continuum limit for QED. This possibility is motivated by recent lattice simulations on quenched QED which apparently exhibit a chiral phase transition at strong coupling in the chiral limit. Another goal is to develop a novel perturbation expansion which may also be usefully applied to other theories. The author begins with the general expression for the chiral order parameter, ([bar [psi

  11. Light Nuclei and HyperNuclei from Quantum Chromodynamics in the Limit of SU(3) Flavor Symmetry

    SciTech Connect

    Beane, S R; Cohen, S D; Detmold, W; Lin, H W; Luu, T C; Orginos, K; Parreno, A; Savage, M J; Walker-Loud, A

    2013-02-01

    The binding energies of a range of nuclei and hypernuclei with atomic number A <= 4 and strangeness |s| <= 2, including the deuteron, di-neutron, H-dibaryon, {sup 3}He, {sub {Lambda}}{sup 3}He, {sub {Lambda}}{sup 4}He, and {sub {Lambda}{Lambda}}{sup 4}He, are calculated in the limit of flavor-SU(3) symmetry at the physical strange quark mass with quantum chromodynamics (without electromagnetic interactions). The nuclear states are extracted from Lattice QCD calculations performed with n{sub f}=3 dynamical light quarks using an isotropic clover discretization of the quark-action in three lattice volumes of spatial extent L ~ 3.4 fm, 4.5 fm and 6.7 fm, and with a single lattice spacing b ~ 0.145 fm.

  12. An investigation of meson spectroscopy on isotropic clover lattices at the SU(3) flavor-symmetric point

    SciTech Connect

    Richards, David G.; Orginos, Konstantinos

    2014-06-23

    We present an investigation of the excited meson spectrum at the N_f= 3 point obtained on isotropic clover lattices with a plaquette Wilson gauge action, and a NP-improved clover fermion action, at a lattice spacing of a \\simeq 0.08 fm, and compare with corresponding calculations on an anisotropic lattice at fine temporal lattice spacing but a spatial lattice spacing of a_s \\simeq 0.125 fm. The methodology adopted follows that employed in the calculation of the spectrum on anisotropic lattices, and we test the efficacy of that approach for isotropic lattices. In particular, we explore the extent to which rotational symmetry for predominantly single-hadron states is realized. By comparison of the energy levels with that obtained using the anisotropic lattice, we obtain an indication of discretization uncertainties in the single-hadron spectrum.

  13. Renormalization of NN Interaction with Relativistic Chiral Two Pion Exchange

    SciTech Connect

    Higa, R; Valderrama, M Pavon; Arriola, E Ruiz

    2007-06-14

    The renormalization of the NN interaction with the Chiral Two Pion Exchange Potential computed using relativistic baryon chiral perturbation theory is considered. The short distance singularity reduces the number of counter-terms to about a half as those in the heavy-baryon expansion. Phase shifts and deuteron properties are evaluated and a general overall agreement is observed.

  14. Chiral streamers

    SciTech Connect

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya

    2015-10-15

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  15. Chiral streamers

    NASA Astrophysics Data System (ADS)

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya Ken

    2015-10-01

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  16. Chiral Dynamics 2006

    NASA Astrophysics Data System (ADS)

    Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry

    2007-10-01

    pt. A. Plenary session. Opening remarks: experimental tests of chiral symmetry breaking / A. M. Bernstein. [Double pie symbols] scattering / H. Leutwyler. Chiral effective field theory in a [Triangle]-resonance region / V. Pascalutsa. Some recent developments in chiral perturbation theory / Ulf-G. Mei ner. Chiral extrapolation and nucleon structure from the lattice / R.D. Young. Recent results from HAPPEX / R. Michaels. Chiral symmetries and low energy searches for new physics / M.J. Ramsey-Musolf. Kaon physics: recent experimental progress / M. Moulson. Status of the Cabibbo angle / V. Cirigliano. Lattice QCD and nucleon spin structure / J.W. Negele. Spin sum rules and polarizabilities: results from Jefferson lab / J-P Chen. Compton scattering and nucleon polarisabilities / Judith A. McGovern. Virtual compton scattering at MIT-bates / R. Miskimen. Physics results from the BLAST detector at the BATES accelerator / R.P. Redwine. The [Pie sympbol]NN system, recent progress / C. Hanhart. Application of chiral nuclear forces to light nuclei / A. Nogga. New results on few-body experiments at low energy / Y. Nagai. Few-body lattice calculations / M.J. Savage. Research opportunities at the upgraded HI?S facility / H.R. Weller -- pt. B. Goldstone boson dynamics. Working group summary: Goldstone Boson dynamics / G. Colangelo and S. Giovannella. Recent results on radiative Kaon decays from NA48 and NA48/2 / S.G. López. Cusps in K-->3 [Pie symbol] decays / B. Kubis. Recent KTeV results on radiative Kaon decays / M.C. Ronquest. The [Double pie symbols] scattering amplitude / J.R. Peláez. Determination of the Regge parameters in the [Double pie symbols] scattering amplitude / I. Caprini. e+e- Hadronic cross section measurement at DA[symbol]NE with the KLOE detector / P. Beltrame. Measurement of the form factors of e+e- -->2([Pie symbol]+[Pie symbol]-), pp and the resonant parameters of the heavy charmonia at BES / H. Hu. Measurement of e+e- multihadronic cross section below 4

  17. Nuclear electromagnetic charge and current operators in Chiral EFT

    SciTech Connect

    Girlanda, Luca; Marcucci, Laura Elisa; Pastore, Saori; Piarulli, Maria; Schiavilla, Rocco; Viviani, Michele

    2013-08-01

    We describe our method for deriving the nuclear electromagnetic charge and current operators in chiral perturbation theory, based on time-ordered perturbation theory. We then discuss possible strategies for fixing the relevant low-energy constants, from the magnetic moments of the deuteron and of the trinucleons, and from the radiative np capture cross sections, and identify a scheme which, partly relying on {Delta} resonance saturation, leads to a reasonable pattern of convergence of the chiral expansion.

  18. Spontaneous Planar Chiral Symmetry Breaking in Cells

    NASA Astrophysics Data System (ADS)

    Hadidjojo, Jeremy; Lubensky, David

    Recent progress in animal development has highlighted the central role played by planar cell polarity (PCP) in epithelial tissue morphogenesis. Through PCP, cells have the ability to collectively polarize in the plane of the epithelium by localizing morphogenetic proteins along a certain axis. This allows direction-dependent modulation of tissue mechanical properties that can translate into the formation of complex, non-rotationally invariant shapes. Recent experimental observations[1] show that cells, in addition to being planar-polarized, can also spontaneously develop planar chirality, perhaps in the effort of making yet more complex shapes that are reflection non-invariant. In this talk we will present our work in characterizing general mechanisms that can lead to spontaneous chiral symmetry breaking in cells. We decompose interfacial concentration of polarity proteins in a hexagonal cell packing into irreducible representations. We find that in the case of polar concentration distributions, a chiral state can only be reached from a secondary instability after the cells are polarized. However in the case of nematic distributions, we show that a finite-amplitude (subcritical, or ``first-order'') nematic transition can send the system from disorder directly to a chiral state. In addition, we find that perturbing the system by stretching the hexagonal packing enables direct (supercritical, or ``second-order'') chiral transition in the nematic case. Finally, we do a Landau expansion to study competition between stretch-induced chirality and the tendency towards a non-chiral state in packings that have retained the full 6-fold symmetry.

  19. Chiral mirrors

    SciTech Connect

    Plum, Eric; Zheludev, Nikolay I.

    2015-06-01

    Mirrors are used in telescopes, microscopes, photo cameras, lasers, satellite dishes, and everywhere else, where redirection of electromagnetic radiation is required making them arguably the most important optical component. While conventional isotropic mirrors will reflect linear polarizations without change, the handedness of circularly polarized waves is reversed upon reflection. Here, we demonstrate a type of mirror reflecting one circular polarization without changing its handedness, while absorbing the other. The polarization-preserving mirror consists of a planar metasurface with a subwavelength pattern that cannot be superimposed with its mirror image without being lifted out of its plane, and a conventional mirror spaced by a fraction of the wavelength from the metasurface. Such mirrors enable circularly polarized lasers and Fabry-Pérot cavities with enhanced tunability, gyroscopic applications, polarization-sensitive detectors of electromagnetic waves, and can be used to enhance spectroscopies of chiral media.

  20. Nuclear chiral dynamics and thermodynamics

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Kaiser, Norbert; Weise, Wolfram

    2013-11-01

    This presentation reviews an approach to nuclear many-body systems based on the spontaneously broken chiral symmetry of low-energy QCD. In the low-energy limit, for energies and momenta small compared to a characteristic symmetry breaking scale of order 1 GeV, QCD is realized as an effective field theory of Goldstone bosons (pions) coupled to heavy fermionic sources (nucleons). Nuclear forces at long and intermediate distance scales result from a systematic hierarchy of one- and two-pion exchange processes in combination with Pauli blocking effects in the nuclear medium. Short distance dynamics, not resolved at the wavelengths corresponding to typical nuclear Fermi momenta, are introduced as contact interactions between nucleons. Apart from a set of low-energy constants associated with these contact terms, the parameters of this theory are entirely determined by pion properties and low-energy pion-nucleon scattering observables. This framework (in-medium chiral perturbation theory) can provide a realistic description of both isospin-symmetric nuclear matter and neutron matter, with emphasis on the isospin-dependence determined by the underlying chiral NN interaction. The importance of three-body forces is emphasized, and the role of explicit Δ(1232)-isobar degrees of freedom is investigated in detail. Nuclear chiral thermodynamics is developed and a calculation of the nuclear phase diagram is performed. This includes a successful description of the first-order phase transition from a nuclear Fermi liquid to an interacting Fermi gas and the coexistence of these phases below a critical temperature Tc. Density functional methods for finite nuclei based on this approach are also discussed. Effective interactions, their density dependence and connections to Landau Fermi liquid theory are outlined. Finally, the density and temperature dependences of the chiral (quark) condensate are investigated.

  1. Long-range interactions between chiral molecules

    SciTech Connect

    Salam, A.

    2015-01-22

    Results of molecular quantum electrodynamics calculations of discriminatory interactions between two chiral molecules undergoing resonance energy transfer, van der Waals dispersion, and optical binding are presented. A characteristic feature of the theory is that the radiation field is quantized with signals consequently propagating between centres at the speed of light. In order to correctly describe optically active chromophores, it is necessary to include magnetic as well as electric dipole coupling terms in the time-dependent perturbation theory computations. Recent work investigating the effect of an absorptive and dispersive chiral medium on the rate of migration of energy will also be discussed.

  2. Chiral logarithms in the massless limit tamed.

    PubMed

    Kivel, Nikolai; Polyakov, Maxim V; Vladimirov, Alexei

    2008-12-31

    We derive nonlinear recursion relations for the leading chiral logarithms (LLs) in massless theories. These relations not only provide a very efficient method of computation of LLs (e.g., the 33-loop contribution is calculated in a dozen of seconds on a PC) but also equip us with a powerful tool for the summation of the LLs. Our method is not limited to chiral perturbation theory only; it is pertinent to any nonrenormalizable effective field theory such as, for instance, the theory of critical phenomena, low-energy quantum gravity, etc. PMID:19437635

  3. Chirality of Viral Capsids

    NASA Astrophysics Data System (ADS)

    Dharmavaram, Sanjay; Xie, Fangming; Bruinsma, Robijn; Klug, William; Rudnick, Joseph

    Most icosahedral viruses are classified by their T-number which identifies their capsid in terms of the number of capsomers and their relative arrangement. Certain T-numbers (T = 7 for instance) are inherently chiral (with no reflection planes) while others (e.g. T = 1) are achiral. We present a Landau-Brazovskii (LB) theory for weak crystallization in which a scalar order parameter that measures density of capsid proteins successfully predicts the various observed T-numbers and their respective chiralities. We find that chiral capsids gain stability by spontaneously breaking symmetry from an unstable chiral state. The inherently achiral LB-free energy does not preferentially select a particular chiral state from its mirror reflection. Based on the physical observation that proteins are inherently chiral molecules with directional interactions, we propose a new chiral term to the LB energy as a possible selection mechanism for chirality.

  4. Chiral logarithms in quenched QCD

    SciTech Connect

    Y. Chen; S. J. Dong; T. Draper; I. Horvath; F. X. Lee; K. F. Liu; N. Mathur; and J. B. Zhang

    2004-08-01

    The quenched chiral logarithms are examined on a 163x28 lattice with Iwasaki gauge action and overlap fermions. The pion decay constant fpi is used to set the lattice spacing, a = 0.200(3) fm. With pion mass as low as {approx}180 MeV, we see the quenched chiral logarithms clearly in mpi2/m and fP, the pseudoscalar decay constant. The authors analyze the data to determine how low the pion mass needs to be in order for the quenched one-loop chiral perturbation theory (chiPT) to apply. With the constrained curve-fitting method, they are able to extract the quenched chiral logarithmic parameter delta together with other low-energy parameters. Only for mpi<=300 MeV do we obtain a consistent and stable fit with a constant delta which they determine to be 0.24(3)(4) (at the chiral scale Lambdachi = 0.8 GeV). By comparing to the 123x28 lattice, they estimate the finite volume effect to be about 2.7% for the smallest pion mass. They also fitted the pion mass to the form for the re-summed cactus diagrams and found that its applicable region is extended farther than the range for the one-loop formula, perhaps up to mpi {approx}500-600 MeV. The scale independent delta is determined to be 0.20(3) in this case. The authors study the quenched non-analytic terms in the nucleon mass and find that the coefficient C1/2 in the nucleon mass is consistent with the prediction of one-loop chiPT. They also obtain the low energy constant L5 from fpi. They conclude from this study that it is imperative to cover only the range of data with the pion mass less than {approx}300 MeV in order to examine the chiral behavior of the hadron masses and decay constants in quenched QCD and match them with quenched one-loop chiPT.

  5. Pion Photo- and Electroproduction and the Chiral MAID Interface

    NASA Astrophysics Data System (ADS)

    Hilt, Marius; Lehnhart, Björn C.; Scherer, Stefan; Tiator, Lothar

    We discuss the extended on-mass-shell scheme for manifestly Lorentz-invariant baryon chiral perturbation theory. We present a calculation of pion photo- and electroproduction up to and including order q4. The low-energy constants have been fixed by fitting experimental data in all available reaction channels. Our results can be accessed via a web interface, the so-called chiral MAID (http://www.kph.uni-mainz.de/MAID/chiralmaid/).

  6. Chirality in nonlinear optics.

    PubMed

    Haupert, Levi M; Simpson, Garth J

    2009-01-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made approximately 50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity. PMID:19046125

  7. Chirality in Nonlinear Optics

    NASA Astrophysics Data System (ADS)

    Haupert, Levi M.; Simpson, Garth J.

    2009-05-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made ˜50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity.

  8. Chiral symmetry and chiral-symmetry breaking

    SciTech Connect

    Peskin, M.E.

    1982-12-01

    These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed. (WHK)

  9. Chiral corrections to the anomalous 2. gamma. decays of. pi. sup 0 ,. eta. and. eta. prime

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  10. PERTURBING LIGNIFICATION

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Perturbing lignification is possible in multiple and diverse ways. Without obvious growth/development phenotypes, transgenic angiosperms can have lignin levels reduced to half the normal level, can have compositions ranging from very high-guaiacyl/low-syringyl to almost totally syringyl, and can eve...

  11. Planar plasmonic chiral nanostructures.

    PubMed

    Zu, Shuai; Bao, Yanjun; Fang, Zheyu

    2016-02-21

    A strong chiral optical response induced at a plasmonic Fano resonance in a planar Au heptamer nanostructure was experimentally and theoretically demonstrated. The scattering spectra show the characteristic narrow-band feature of Fano resonances for both left and right circular polarized lights, with a chiral response reaching 30% at the Fano resonance. Specifically, we systematically investigate the chiral response of planar heptamers with gradually changing the inter-particle rotation angles and separation distance. The chiral spectral characteristics clearly depend on the strength of Fano resonances and the associated near-field optical distributions. Finite element method simulations together with a multipole expansion method demonstrate that the enhanced chirality is caused by the excitation of magnetic quadrupolar and electric toroidal dipolar modes. Our work provides an effective method for the design of 2D nanostructures with a strong chiral response. PMID:26818746

  12. Axially chiral BODIPYs.

    PubMed

    Lerrick, Reinner I; Winstanley, Thomas P L; Haggerty, Karen; Wills, Corinne; Clegg, William; Harrington, Ross W; Bultinck, Patrick; Herrebout, Wouter; Benniston, Andrew C; Hall, Michael J

    2014-05-11

    The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations. PMID:24676233

  13. Chiral atomically thin films

    NASA Astrophysics Data System (ADS)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm–1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  14. Chiral atomically thin films.

    PubMed

    Kim, Cheol-Joo; Sánchez-Castillo, A; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm(-1)) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra. PMID:26900756

  15. Cosmological Perturbations

    NASA Astrophysics Data System (ADS)

    Lesgourges, J.

    2013-08-01

    We present a self-contained summary of the theory of linear cosmological perturbations. We emphasize the effect of the six parameters of the minimal cosmological model, first, on the spectrum of Cosmic Microwave Background temperature anisotropies, and second, on the linear matter power spectrum. We briefly review at the end the possible impact of a few non-minimal dark matter and dark energy models.

  16. Chiral geometry in multiple chiral doublet bands

    NASA Astrophysics Data System (ADS)

    Zhang, Hao; Chen, Qibo

    2016-02-01

    The chiral geometry of multiple chiral doublet bands with identical configuration is discussed for different triaxial deformation parameters γ in the particle rotor model with . The energy spectra, electromagnetic transition probabilities B(M1) and B(E2), angular momenta, and K-distributions are studied. It is demonstrated that the chirality still remains not only in the yrast and yrare bands, but also in the two higher excited bands when γ deviates from 30°. The chiral geometry relies significantly on γ, and the chiral geometry of the two higher excited partner bands is not as good as that of the yrast and yrare doublet bands. Supported by Plan Project of Beijing College Students’ Scientific Research and Entrepreneurial Action, Major State 973 Program of China (2013CB834400), National Natural Science Foundation of China (11175002, 11335002, 11375015, 11461141002), National Fund for Fostering Talents of Basic Science (NFFTBS) (J1103206), Research Fund for Doctoral Program of Higher Education (20110001110087) and China Postdoctoral Science Foundation (2015M580007)

  17. Chiral Drugs: An Overview

    PubMed Central

    Nguyen, Lien Ai; He, Hua; Pham-Huy, Chuong

    2006-01-01

    About more than half of the drugs currently in use are chiral compounds and near 90% of the last ones are marketed as racemates consisting of an equimolar mixture of two enantiomers. Although they have the same chemical structure, most isomers of chiral drugs exhibit marked differences in biological activities such as pharmacology, toxicology, pharmacokinetics, metabolism etc. Some mechanisms of these properties are also explained. Therefore, it is important to promote the chiral separation and analysis of racemic drugs in pharmaceutical industry as well as in clinic in order to eliminate the unwanted isomer from the preparation and to find an optimal treatment and a right therapeutic control for the patient. In this article, we review the nomenclature, pharmacology, toxicology, pharmacokinetics, metabolism etc of some usual chiral drugs as well as their mechanisms. Different techniques used for the chiral separation in pharmaceutical industry as well as in clinical analyses are also examined. PMID:23674971

  18. Chiral corrections to the hyperon vector form factors

    NASA Astrophysics Data System (ADS)

    Villadoro, Giovanni

    2006-07-01

    We present a complete calculation of the SU(3)-breaking corrections to the hyperon vector form factors up to O(p4) in heavy baryon chiral perturbation theory. Because of the Ademollo-Gatto theorem, at this order the results do not depend on unknown low energy constants and allow to test the convergence of the chiral expansion. We complete and correct previous calculations and find that O(p3) and O(1/M0) corrections are important. We also study the inclusion of the decuplet degrees of freedom, showing that in this case the perturbative expansion is jeopardized. These results raise doubts on the reliability of the chiral expansion for hyperons.

  19. Chiral Extrapolation of Lattice Data for Heavy Meson Hyperfine Splittings

    SciTech Connect

    X.-H. Guo; P.C. Tandy; A.W. Thomas

    2006-03-01

    We investigate the chiral extrapolation of the lattice data for the light-heavy meson hyperfine splittings D*-D and B*-B to the physical region for the light quark mass. The chiral loop corrections providing non-analytic behavior in m{sub {pi}} are consistent with chiral perturbation theory for heavy mesons. Since chiral loop corrections tend to decrease the already too low splittings obtained from linear extrapolation, we investigate two models to guide the form of the analytic background behavior: the constituent quark potential model, and the covariant model of QCD based on the ladder-rainbow truncation of the Dyson-Schwinger equations. The extrapolated hyperfine splittings remain clearly below the experimental values even allowing for the model dependence in the description of the analytic background.

  20. Generalized Polarizabilities and the Chiral Structure of the Nucleon

    SciTech Connect

    Hemmert, T.R.; Knoechlein, G.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-07-01

    We present results of the first chiral perturbation theory calculation for the generalized polarizabilities of the nucleon and discuss the response functions in virtual Compton scattering to be measured in the scheduled electron scattering experiments. {copyright} {ital 1997} {ital The American Physical Society}

  1. Pion scattering poles and chiral symmetry restoration

    SciTech Connect

    Fernandez-Fraile, D.; Nicola, A. Gomez; Herruzo, E. T.

    2007-10-15

    Using unitarized chiral perturbation theory methods, we perform a detailed analysis of the {pi}{pi} scattering poles f{sub 0}(600) and {rho}(770) behavior when medium effects such as temperature or density drive the system towards chiral symmetry restoration. In the analysis of real poles below threshold, we show that it is crucial to extend properly the unitarized amplitudes so that they match the perturbative Adler zeros. Our results do not show threshold enhancement effects at finite temperature in the f{sub 0}(600) channel, which remains as a pole of broad nature. We also implement T=0 finite-density effects related to chiral symmetry restoration, by varying the pole position with the pion decay constant. Although this approach takes into account only a limited class of contributions, we reproduce the expected finite-density restoration behavior, which drives the poles towards the real axis, producing threshold enhancement and {pi}{pi} bound states. We compare our results with several model approaches and discuss the experimental consequences, both in relativistic heavy ion collisions and in {pi}{yields}{pi}{pi} and {gamma}{yields}{pi}{pi} reactions in nuclei.

  2. Kagome antiferromagnet: a chiral topological spin liquid?

    PubMed

    Messio, Laura; Bernu, Bernard; Lhuillier, Claire

    2012-05-18

    Inspired by the recent discovery of a new instability towards a chiral phase of the classical Heisenberg model on the kagome lattice, we propose a specific chiral spin liquid that reconciles different, well-established results concerning both the classical and quantum models. This proposal is analyzed in an extended mean-field Schwinger boson framework encompassing time reversal symmetry breaking phases, which allows both a classical and a quantum phase description. At low temperatures, we find that quantum fluctuations favor this chiral phase, which is stable against small perturbations of second- and third-neighbor interactions. For spin-1/2, this phase may be, beyond the mean field, a chiral gapped spin liquid. Such a phase is consistent with the density matrix renormalization group results of Yan et al. [Science 332, 1173 (2011)]. Mysterious features of the low-lying excitations of exact diagonalization spectra also find an explanation in this framework. Moreover, thermal fluctuations compete with quantum ones and induce a transition from this flux phase to a planar zero flux phase at a nonzero value of the renormalized temperature (T/S2), reconciling these results with those obtained for the classical system. PMID:23003183

  3. Applications of chiral symmetry

    SciTech Connect

    Pisarski, R.D.

    1995-03-01

    The author discusses several topics in the applications of chiral symmetry at nonzero temperature. First, where does the rho go? The answer: up. The restoration of chiral symmetry at a temperature T{sub {chi}} implies that the {rho} and a{sub 1} vector mesons are degenerate in mass. In a gauged linear sigma model the {rho} mass increases with temperature, m{sub {rho}}(T{sub {chi}}) > m{sub {rho}}(0). The author conjectures that at T{sub {chi}} the thermal {rho} - a{sub 1}, peak is relatively high, at about {approximately}1 GeV, with a width approximately that at zero temperature (up to standard kinematic factors). The {omega} meson also increases in mass, nearly degenerate with the {rho}, but its width grows dramatically with temperature, increasing to at least {approximately}100 MeV by T{sub {chi}}. The author also stresses how utterly remarkable the principle of vector meson dominance is, when viewed from the modern perspective of the renormalization group. Secondly, he discusses the possible appearance of disoriented chiral condensates from {open_quotes}quenched{close_quotes} heavy ion collisions. It appears difficult to obtain large domains of disoriented chiral condensates in the standard two flavor model. This leads to the last topic, which is the phase diagram for QCD with three flavors, and its proximity to the chiral critical point. QCD may be very near this chiral critical point, and one might thereby generated large domains of disoriented chiral condensates.

  4. Chirality control in oligothiophene through chiral wrapping.

    PubMed

    Sanji, Takanobu; Kato, Nobu; Tanaka, Masato

    2006-01-19

    [structure: see text] Mixing oligothiophenes and polysaccharides, such as amylose and schizophyllan, affords novel inclusion complexes, in which oligothiophene guests adopt twisted conformation in the chiral channel created by left- or right-handed helical wrapping with the polysaccharide host polymers, leading to optical activity. PMID:16408883

  5. Synthesis of Chiral Cyclopentenones.

    PubMed

    Simeonov, Svilen P; Nunes, João P M; Guerra, Krassimira; Kurteva, Vanya B; Afonso, Carlos A M

    2016-05-25

    The cyclopentenone unit is a very powerful synthon for the synthesis of a variety of bioactive target molecules. This is due to the broad diversity of chemical modifications available for the enone structural motif. In particular, chiral cyclopentenones are important precursors in the asymmetric synthesis of target chiral molecules. This Review provides an overview of reported methods for enantioselective and asymmetric syntheses of cyclopentenones, including chemical and enzymatic resolution, asymmetric synthesis via Pauson-Khand reaction, Nazarov cyclization and organocatalyzed reactions, asymmetric functionalization of the existing cyclopentenone unit, and functionalization of chiral building blocks. PMID:27101336

  6. Chiral extrapolations in 2+1 flavor domain wall fermion simulations

    NASA Astrophysics Data System (ADS)

    Lin, Meifeng

    2006-12-01

    Simulations with 2+1 flavors of domain wall fermions provide us with the opportunity to compare the lattice data directly to the predictions of continuum chiral perturbation theory, up to correc- tions from the residual chiral symmetry breaking, mres , and O(a) lattice artefacts, which are rela- tively small for domain wall fermions. We present preliminary results for the pseudoscalar meson masses and decay constants from partially quenched simulations and examine the next-to-leading order chiral extrapolations at small quark masses. The simulations were carried out on two lattice volumes : 163 × 32 and 243 × 64, with the lattice spacing fixed at about 0.1 fm. The subtleties of the chiral fits are discussed. We also explore the roles of mres and O(a) terms in the NLO chiral expansions and their effects on the chiral extrapolations for the pseudoscalar masses and decay constants.

  7. Criteria of backscattering in chiral one-way photonic crystals

    NASA Astrophysics Data System (ADS)

    Cheng, Pi-Ju; Chang, Shu-Wei

    2016-03-01

    Optical isolators are important devices in photonic circuits. To reduce the unwanted reflection in a robust manner, several setups have been realized using nonreciprocal schemes. In this study, we show that the propagating modes in a strongly-guided chiral photonic crystal (no breaking of the reciprocity) are not backscattering-immune even though they are indeed insensitive to many types of scatters. Without the protection from the nonreciprocity, the backscattering occurs under certain circumstances. We present a perturbative method to calculate the backscattering of chiral photonic crystals in the presence of chiral/achiral scatters. The model is, essentially, a simplified analogy to the first-order Born approximation. Under reasonable assumptions based on the behaviors of chiral photonic modes, we obtained the expression of reflection coefficients which provides criteria for the prominent backscattering in such chiral structures. Numerical examinations using the finite-element method were also performed and the results agree well with the theoretical prediction. From both our theory and numerical calculations, we find that the amount of backscattering critically depends on the symmetry of scatter cross sections. Strong reflection takes place when the azimuthal Fourier components of scatter cross sections have an order l of 2. Chiral scatters without these Fourier components would not efficiently reflect the chiral photonic modes. In addition, for these chiral propagating modes, disturbances at the most significant parts of field profiles do not necessarily result in the most effective backscattering. The observation also reveals what types of scatters or defects should be avoided in one-way applications of chiral structures in order to minimize the backscattering.

  8. Spintronics: Chiral damping

    PubMed Central

    Kim, Kyoung-Whan; Lee, Hyun-Woo

    2016-01-01

    The analysis of the magnetic domain wall motion in a nanostructured magnetic system with strong spin-orbit coupling shows that the energy dissipation can be chiral when the inversion symmetry is broken. PMID:26906956

  9. Nonlinear chiral transport phenomena

    NASA Astrophysics Data System (ADS)

    Chen, Jiunn-Wei; Ishii, Takeaki; Pu, Shi; Yamamoto, Naoki

    2016-06-01

    We study the nonlinear responses of relativistic chiral matter to the external fields such as the electric field E , gradients of temperature and chemical potential, ∇T and ∇μ . Using the kinetic theory with Berry curvature corrections under the relaxation time approximation, we compute the transport coefficients of possible new electric currents that are forbidden in usual chirally symmetric matter but are allowed in chirally asymmetric matter by parity. In particular, we find a new type of electric current proportional to ∇μ ×E due to the interplay between the effects of the Berry curvature and collisions. We also derive an analog of the "Wiedemann-Franz" law specific for anomalous nonlinear transport in relativistic chiral matter.

  10. Kaon Thresholds and Two-Flavor Chiral Expansions for Hyperons

    SciTech Connect

    Fu-Jiun Jiang, Brian C. Tiburzi, Andre Walker-Loud

    2011-01-01

    Two-flavor chiral expansions provide a useful perturbative framework to study hadron properties. Such expansions should exhibit marked improvement over the conventional three-flavor chiral expansion. Although one can theoretically formulate two-flavor theories for the various hyperon multiplets, the nearness of kaon thresholds can seriously undermine the effectiveness of the perturbative expansion in practice. We investigate the importance of virtual kaon thresholds on hyperon properties, specifically their masses and isovector axial charges. Using a three-flavor expansion that includes SU(3) breaking effects, we uncover the underlying expansion parameter governing the description of virtual kaon thresholds. For spin-half hyperons, this expansion parameter is quite small. Consequently virtual kaon contributions are well described in the two-flavor theory by terms analytic in the pion mass-squared. For spin three-half hyperons, however, one is closer to the kaon production threshold, and the expansion parameter is not as small. Breakdown of SU(2) chiral perturbation theory is shown to arise from a pole in the expansion parameter associated with the kaon threshold. Estimating higher-order corrections to the expansion parameter is necessary to ascertain whether the two-flavor theory of spin three-half hyperons remains perturbative. We find that, despite higher-order corrections, there is a useful perturbative expansion for the masses and isovector axial charges of both spin-half and spin three-half hyperons.

  11. Chiral plasma instabilities.

    PubMed

    Akamatsu, Yukinao; Yamamoto, Naoki

    2013-08-01

    We study the collective modes in relativistic electromagnetic or quark-gluon plasmas with an asymmetry between left- and right-handed chiral fermions, based on the recently formulated kinetic theory with Berry curvature corrections. We find that there exists an unstable mode, signaling the presence of a plasma instability. We argue the fate of this "chiral plasma instability" including the effect of collisions, and briefly discuss its relevance in heavy ion collisions and compact stars. PMID:23952387

  12. Chiral corrections to the anomalous 2{gamma} decays of {pi}{sup 0}, {eta} and {eta}{prime}

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  13. Perturbative fragmentation

    SciTech Connect

    Kopeliovich, B. Z.; Pirner, H.-J.; Potashnikova, I. K.; Schmidt, Ivan; Tarasov, A. V.

    2008-03-01

    The Berger model of perturbative fragmentation of quarks to pions is improved by providing an absolute normalization and keeping all terms in a (1-z) expansion, which makes the calculation valid at all values of fractional pion momentum z. We also replace the nonrelativistic wave function of a loosely bound pion by the more realistic procedure of projecting to the light-cone pion wave function, which in turn is taken from well known models. The full calculation does not confirm the (1-z){sup 2} behavior of the fragmentation function (FF) predicted in [E. L. Berger, Z. Phys. C 4, 289 (1980); Phys. Lett. 89B, 241 (1980] for z>0.5, and only works at very large z>0.95, where it is in reasonable agreement with phenomenological FFs. Otherwise, we observe quite a different z-dependence which grossly underestimates data at smaller z. The disagreement is reduced after the addition of pions from decays of light vector mesons, but still remains considerable. The process dependent higher twist terms are also calculated exactly and found to be important at large z and/or p{sub T}.

  14. Spontaneous chiral symmetry breaking by hydromagnetic buoyancy

    NASA Astrophysics Data System (ADS)

    Chatterjee, Piyali; Mitra, Dhrubaditya; Brandenburg, Axel; Rheinhardt, Matthias

    2011-08-01

    Evidence for the parity-breaking nature of the magnetic buoyancy instability in a stably stratified gas is reported. In the absence of rotation, no helicity is produced, but the nonhelical state is found to be unstable to small helical perturbations during the development of the instability. The parity-breaking nature of this magnetohydrodynamic instability appears to be the first of its kind and has properties similar to those in chiral symmetry breaking in biochemistry. Applications to the production of mean fields in galaxy clusters are discussed.

  15. Circular Dichroism in the Photoionization of Nanoparticles from Chiral Compounds

    SciTech Connect

    Paul, J.; Doerzbach, A.; Siegmann, K.

    1997-10-01

    The dichroism in photoemission from chiral molecules is observed for the first time. Particles consisting of chiral molecules are suspended in air and irradiated alternately with right and left circularly polarized uv light. We found a polarization dependence in the total photoelectric current. The asymmetries observed are of the order of 10{sup {minus}2} to 10{sup {minus}3} , as expected from perturbation theory, and reverse their sign when the handedness of the molecules is changed. {copyright} {ital 1997} {ital The American Physical Society}

  16. Nuclear axial currents in chiral effective field theory

    DOE PAGESBeta

    Baroni, Alessandro; Girlanda, Luca; Pastore, Saori; Schiavilla, Rocco; Viviani, Michele

    2016-01-11

    Two-nucleon axial charge and current operators are derived in chiral effective field theory up to one loop. The derivation is based on time-ordered perturbation theory and accounts for cancellations between the contributions of irreducible diagrams and the contributions owing to nonstatic corrections from energy denominators of reducible diagrams. Ultraviolet divergencies associated with the loop corrections are isolated in dimensional regularization. The resulting axial current is finite and conserved in the chiral limit, while the axial charge requires renormalization. As a result, a complete set of contact terms for the axial charge up to the relevant order in the power countingmore » is constructed.« less

  17. Chiral Graphene Quantum Dots.

    PubMed

    Suzuki, Nozomu; Wang, Yichun; Elvati, Paolo; Qu, Zhi-Bei; Kim, Kyoungwon; Jiang, Shuang; Baumeister, Elizabeth; Lee, Jaewook; Yeom, Bongjun; Bahng, Joong Hwan; Lee, Jaebeom; Violi, Angela; Kotov, Nicholas A

    2016-02-23

    Chiral nanostructures from metals and semiconductors attract wide interest as components for polarization-enabled optoelectronic devices. Similarly to other fields of nanotechnology, graphene-based materials can greatly enrich physical and chemical phenomena associated with optical and electronic properties of chiral nanostructures and facilitate their applications in biology as well as other areas. Here, we report that covalent attachment of l/d-cysteine moieties to the edges of graphene quantum dots (GQDs) leads to their helical buckling due to chiral interactions at the "crowded" edges. Circular dichroism (CD) spectra of the GQDs revealed bands at ca. 210-220 and 250-265 nm that changed their signs for different chirality of the cysteine edge ligands. The high-energy chiroptical peaks at 210-220 nm correspond to the hybridized molecular orbitals involving the chiral center of amino acids and atoms of graphene edges. Diverse experimental and modeling data, including density functional theory calculations of CD spectra with probabilistic distribution of GQD isomers, indicate that the band at 250-265 nm originates from the three-dimensional twisting of the graphene sheet and can be attributed to the chiral excitonic transitions. The positive and negative low-energy CD bands correspond to the left and right helicity of GQDs, respectively. Exposure of liver HepG2 cells to L/D-GQDs reveals their general biocompatibility and a noticeable difference in the toxicity of the stereoisomers. Molecular dynamics simulations demonstrated that d-GQDs have a stronger tendency to accumulate within the cellular membrane than L-GQDs. Emergence of nanoscale chirality in GQDs decorated with biomolecules is expected to be a general stereochemical phenomenon for flexible sheets of nanomaterials. PMID:26743467

  18. Non-Perturbative Field Theories.

    NASA Astrophysics Data System (ADS)

    Stephenson, David

    Available from UMI in association with The British Library. Requires signed TDF. Some non-perturbative aspects of field theories are studied by applying lattice gauge theory techniques. The low-lying hadronic mass spectrum is calculated numerically using quenched lattice quantum chromodynamics. The results of large numerical simulations performed on a distributed array processor are presented and analysed. Particular emphasis is stressed upon the understanding of systematic and statistical errors in the calculation. In addition, the pion decay constant and the chiral condensate are evaluated. An attempt is made to relate the numerical findings to the experimentally measured quantities. A pioneering attempt to understand Yukawa couplings is discussed. A toy Fermion-Higgs system is studied numerically on a transputer array. Dynamical fermions are included in the investigation of the behavior of the system over a wide range of Yukawa couplings. A phase diagram is found for the model which shows evidence of spontaneous chiral symmetry breaking transitions. Extensions of the model are discussed together some speculations concerning the behaviour of Yukawa couplings in general. The possibility of using the lattice as a model for space-time is investigated by studying the propagation of particles on a fractal lattice. In addition, the use of truncated fractals as novel regulators is studied numerically in the hope that the problem of fermion doubling will be alleviated.

  19. Chiral quirkonium decays

    NASA Astrophysics Data System (ADS)

    Fok, R.; Kribs, Graham D.

    2011-08-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N)ic infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between “chiral quirkonia” versus “vectorlike quirkonia” are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, tt¯, tb¯/bt¯, and γH, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and Wγ, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  20. Chiral Quirkonium Decays

    SciTech Connect

    Fok, R.; Kribs, Graham D.; /Fermilab

    2011-06-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N){sub ic} infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between 'chiral quirkonia' versus 'vectorlike quirkonia' are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, t{bar t}, t{bar b}/b{bar t}, and {gamma}H, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and W{gamma}, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  1. Spontaneous chirality in simple systems

    PubMed

    Pickett; Gross; Okuyama

    2000-10-23

    Two simple examples of spontaneous chiral symmetry breaking are presented. The first is close-packed cylindrically confined spheres. As the cylinder diameter is varied, one obtains a variety of chiral phases. The second example involves unconfined dipolar particles with an isotropic attraction, which also exhibits chiral ground states. We speculate that a dilute magnetorheological fluid film, with the addition of smaller particles to provide an attractive entropic interaction, will exhibit a chiral columnar ground state. PMID:11030973

  2. The chiral phase transition and the role of vacuum fluctuations

    NASA Astrophysics Data System (ADS)

    Khan, Rashid; Andersen, Jens O.; Kyllingstad, Lars T.; Khan, Majid

    2016-03-01

    We apply optimized perturbation theory to the quark-meson model at finite temperature T and quark chemical potential μ. The effective potential is calculated to one loop both in the chiral limit and at the physical point and used to study the chiral dynamics of two-flavor QCD. The critical temperature and the order of the phase transition depend heavily on whether or not one includes the bosonic and fermionic vacuum fluctuations in the effective potential. A full one-loop calculation in the chiral limit predicts a first-order transition for all values of μ. At the physical point, one finds a crossover in the whole μ-T plane.

  3. Vibrational evidence for chiral recognition phenomena in vacuo

    NASA Astrophysics Data System (ADS)

    Suhm, Martin A.

    2007-06-01

    Molecules and molecular conformations which cannot be superimposed on their mirror image are chiral. Chirality or handedness plays an important role throughout the life sciences. When two molecules interact, they can sense their relative handedness, giving rise to spectroscopic signatures of chiral recognition. This is often mediated by hydrogen bonds, most versatile and directional intermolecular interactions. If the distinction between the homo- and heteroconfigurational pairs of molecules is large enough, chiral discrimination, i.e. differences in abundance may occur. The contact between two flexible, transiently chiral molecules may induce a matching of their handedness, i.e. chirality synchronization. Such phenomena are best studied at low temperatures in vacuum isolation, without perturbing interactions [1]. Structural information on the isolated molecular complexes can be obtained by rotational spectroscopy [2], if there is a sufficient dipole moment. Vibrational spectroscopy [3] provides a more universal, but also more coarse-grained access to these phenomena. Our group has reported the first spectroscopic example of chiral recognition between constitutionally identical molecules in the gas phase [4]. We have found a case of chiral discrimination in tetrameric aggregates of methyl lactate, where the relative configuration controls the hydrogen bond topology [5]. In the case of alcohols, we have observed different degrees of chirality synchronization up to a quantitative chirality matching in dimers of trifluoroethanol [6]. These discoveries became possible through the use of a powerful combination of FTIR spectroscopy and high-throughput, pulsed supersonic nozzle expansions into large vacuum chambers [7]. The isolated and elementary character of the investigated molecular assemblies is favourable for quantum chemical treatments [8]. Valuable benchmarks for the modeling of more complex chiral recognition phenomena are thus established. [1] A. Al-Rabaa, E. Br

  4. Contesting the paradigm of chirality

    NASA Astrophysics Data System (ADS)

    Efrati, Efi

    2012-02-01

    In 1893 Lord Kelvin coined the term chirality, and stated what is to become the elementary paradigm of chirality: 'I call any geometrical figure, or any group of points, chiral, and say it has chirality, if its image in a plane mirror , ideally realized cannot be brought to coincide with itself'. While the notion of chirality has greatly advanced our understanding of the structures of molecules and crystals, it has been shown to be inconsistent with every pseudo-scalar quantification. In this talk I will present a tabletop demonstration of a chiral structure which is constructed through the achiral summation of identical elementary units which are symmetric under reflection. The seeming contradiction to the definition of chirality is reconciled by proposing an alternative definition, relying on the physicist interpretation of the right hand rule.

  5. Chiral dynamics in the γ → p → pπ0 reaction

    NASA Astrophysics Data System (ADS)

    Hiller Blin, A. N.; Ledwig, T.; Vicente Vacas, M. J.

    2015-07-01

    We investigate the neutral pion photoproduction on the proton near threshold in covariant chiral perturbation theory with the explicit inclusion of Δ degrees of freedom. This channel is specially sensitive to chiral dynamics and the advent of very precise data from the Mainz microtron has shown the limits of the convergence of the chiral series for both the heavy baryon and the covariant approaches. We show that the inclusion of the Δ resonance substantially improves the convergence leading to a good agreement with data for a wider range of energies.

  6. Determination of the chiral condensate from QCD Dirac spectrum on the lattice

    SciTech Connect

    Fukaya, H.; Onogi, T.; Aoki, S.; Chiu, T. W.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.

    2011-04-01

    We calculate the chiral condensate of QCD with 2, 2+1, and 3 flavors of sea quarks. Lattice QCD simulations are performed employing dynamical overlap fermions with up- and down-quark masses covering a range between 3 and 100 MeV. On L{approx}1.8-1.9 fm lattices at a lattice spacing {approx}0.11 fm, we calculate the eigenvalue spectrum of the overlap-Dirac operator. By matching the lattice data with the analytical prediction from chiral perturbation theory at the next-to-leading order, the chiral condensate in the massless limit of up and down quarks is determined.

  7. Staggered fermions and chiral symmetry breaking in transverse lattice regulated QED

    SciTech Connect

    Griffin, P.A.

    1992-07-01

    Staggered fermions are constructed for the transverse lattice regularization scheme. The weak perturbation theory of transverse lattice non-compact QED is developed in light-cone gauge, and we argue that for fixed lattice spacing this theory is ultraviolet finite, order by order in perturbation theory. However, by calculating the anomalous scaling dimension of the link fields, we find that the interaction Hamiltonian becomes non-renormalizable for g{sup 2}(a) > 4{pi}, where g(a) is the bare (lattice) QED coupling constant. We conjecture that this is the critical point of the chiral symmetry breaking phase transition in QED. Non-perturbative chiral symmetry breaking is then studied in the strong coupling limit. The discrete remnant of chiral symmetry that remains on the lattice is spontaneously broken, and the ground state to lowest order in the strong coupling expansion corresponds to the classical ground state of the two-dimensional spin one-half Heisenberg antiferromagnet.

  8. Intrinsic transverse momentum and dynamical chiral symmetry breaking

    SciTech Connect

    Christian Weiss, Peter Schweitzer, Mark Strikman

    2013-01-01

    We study the effect of QCD vacuum structure on the intrinsic transverse momentum distribution of partons in the nucleon at a low scale. The dynamical breaking of chiral symmetry is caused by non-perturbative interactions at distances of the order rho ~ 0.2 - 0.3 fm, much smaller than the typical nucleon size R ~ 1 fm, resulting in a two-scale picture of nucleon structure. Using an effective dynamical model based on chiral constituent quark degrees of freedom and the 1/N_c expansion (chiral quark-soliton model), we calculate the transverse momentum distribution of quarks and antiquarks at a low scale. The distribution of valence quarks is localized at p_T ~ 1/R. The distribution of flavor-singlet unpolarized sea quarks exhibits a power-like tail extending up to the chiral-symmetry-breaking scale 1/{rho}. A similar tail is present in the flavor-nonsinglet polarized sea. These features are model-independent and represent the imprint of the QCD vacuum on the nucleon's partonic structure. At the level of the nucleon's light-cone wave function, we show that sea quarks partly exist in correlated pairs of transverse size {rho} << R, analogous to short-range NN correlations in nuclei. We discuss the implications of our findings for the transverse momentum distributions in hard scattering processes (semi-inclusive DIS, Drell-Yan pair production) and possible experimental tests of the non-perturbative parton correlations induced by QCD vacuum structure.

  9. Chiral symmetry restoration and scalar-pseudoscalar partners in QCD

    NASA Astrophysics Data System (ADS)

    Gómez Nicola, A.; Ruiz de Elvira, J.; Torres Andrés, R.

    2013-10-01

    We describe scalar-pseudoscalar partner degeneration at the QCD chiral transition in terms of the dominant low-energy physical states for the light quark sector. First, we obtain within model-independent one-loop chiral perturbation theory that the QCD pseudoscalar susceptibility is proportional to the quark condensate at low T. Next, we show that this chiral-restoring behavior for χP is compatible with recent lattice results for screening masses and gives rise to degeneration between the scalar and pseudoscalar susceptibilities (χS,χP) around the transition point, consistently with an O(4)-like current restoration pattern. This scenario is clearly confirmed by lattice data when we compare χS(T) with the quark condensate, expected to scale as χP(T). Finally, we show that saturating χS with the σ/f0(500) broad resonance observed in pion scattering and including its finite temperature dependence, allows us to describe the peak structure of χS(T) in lattice data and the associated critical temperature. This is carried out within a unitarized chiral perturbation theory scheme which generates the resonant state dynamically and is also consistent with partner degeneration.

  10. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD.

    PubMed

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-19

    We show that there exists a special compactification of QCD on R^{3}×S^{1} in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation m_{π}^{2}f_{π}^{2}=-m_{q}⟨q[over ¯]q⟩. Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S^{1}, and yield strong support for adiabatic continuity between the small-S^{1} and large-S^{1} regimes. We also find concrete microscopic connections between N=1 and N=2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics. PMID:27588843

  11. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD

    NASA Astrophysics Data System (ADS)

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-01

    We show that there exists a special compactification of QCD on R3×S1 in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation mπ2fπ2=-mq⟨q ¯ q ⟩ . Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S1, and yield strong support for adiabatic continuity between the small-S1 and large-S1 regimes. We also find concrete microscopic connections between N =1 and N =2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics.

  12. Chiral EFT based nuclear forces: achievements and challenges

    NASA Astrophysics Data System (ADS)

    Machleidt, R.; Sammarruca, F.

    2016-08-01

    During the past two decades, chiral effective field theory has become a popular tool to derive nuclear forces from first principles. Two-nucleon interactions have been worked out up to sixth order of chiral perturbation theory and three-nucleon forces up to fifth order. Applications of some of these forces have been conducted in nuclear few- and many-body systems—with a certain degree of success. But in spite of these achievements, we are still faced with great challenges. Among them is the issue of a proper uncertainty quantification of predictions obtained when applying these forces in ab initio calculations of nuclear structure and reactions. A related problem is the order by order convergence of the chiral expansion. We start this review with a pedagogical introduction and then present the current status of the field of chiral nuclear forces. This is followed by a discussion of representative examples for the application of chiral two- and three-body forces in the nuclear many-body system including convergence issues.

  13. Computer-based analytical simulations of chiral hadronic processes

    NASA Astrophysics Data System (ADS)

    Aleksejevs, A.; Butler, M.

    2010-03-01

    The availability of computational modeling tools for subatomic physics (Form, FeynArts, FormCalc and FeynCalc) has made it possible to perform sophisticated calculations in perturbative quantum field theory. We have adapted these packages in order to apply them to the effective chiral field theory of hadronic interactions. A detailed description of this computational hadronic model is presented here, along with sample calculations.

  14. Chiral electron-chiral target scattering

    SciTech Connect

    Trantham, K.W.; Gay, T.J. Johnston, M.E.

    1996-05-01

    It is possible to have an electronic counterpart to the well known effect of optical circular dichroism: electron circular dichroism (ECD) is the preferential scattering of longitudinally polarized electrons by a chiral target. Resulting essentially from a difference in total scattering cross section for different incident electron helicities, this {open_quotes}parity-violating{close_quotes} effect is allowed by symmetry because the scattering target is handed. The authors have searched for ECD in camphor by measuring the transmitted intensity of electrons with positive (negative) helicity I{sub +({minus})} through a gas cell containing stereoisomers of camphor vapor and constructing the asymmetry A = (I{sub +} {minus} I{sub {minus}}). Within their sensitivity (2x10{sup {minus}4}) the authors were not able to detect ECD at the energies investigated (10 eV). Prospects for future investigations, particularly in light of the recent positive results measured in Muenster, will be discussed.

  15. Chiral Biomarkers in Meteorites

    NASA Technical Reports Server (NTRS)

    Hoover, Richard B.

    2010-01-01

    The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be

  16. A Chiral Granular Gas

    NASA Astrophysics Data System (ADS)

    Tsai, J.-C.; Ye, Fangfu; Rodriguez, Juan; Gollub, J. P.; Lubensky, T. C.

    2005-05-01

    Inspired by rattleback toys, we created small chiral wires that rotate in a preferred direction on a vertically oscillating platform and quantified their motion with experiment and simulation. We demonstrate experimentally that angular momentum of rotation about particle centers of mass is converted to collective angular momentum of center-of-mass motion in a granular gas of these wires, and we introduce a continuum model that explains our observations.

  17. A chiral granular gas.

    PubMed

    Tsai, J-C; Ye, Fangfu; Rodriguez, Juan; Gollub, J P; Lubensky, T C

    2005-06-01

    Inspired by rattleback toys, we created small chiral wires that rotate in a preferred direction on a vertically oscillating platform and quantified their motion with experiment and simulation. We demonstrate experimentally that angular momentum of rotation about particle centers of mass is converted to collective angular momentum of center-of-mass motion in a granular gas of these wires, and we introduce a continuum model that explains our observations. PMID:16090323

  18. Chiral symmetry and pentaquarks

    SciTech Connect

    Dmitri Diakonov

    2004-07-01

    Spontaneous chiral symmetry breaking, mesons and baryons are illustrated in the language of the Dirac theory. Various forces acting between quarks inside baryons are discussed. I explain why the naive quark models typically overestimate pentaquark masses by some 500 MeV and why in the fully relativistic approach to baryons pentaquarks turn out to be light. I discuss briefly why it can be easier to produce pentaquarks at low than at high energies.

  19. Chirality and protein folding

    NASA Astrophysics Data System (ADS)

    Kwiecinska, Joanna I.; Cieplak, Marek

    2005-05-01

    There are several simple criteria of folding to a native state in model proteins. One of them involves crossing of a threshold value of the root mean square deviation distance away from the native state. Another checks whether all native contacts are established, i.e. whether the interacting amino acids come closer than some characteristic distance. We use Go-like models of proteins and show that such simple criteria may prompt one to declare folding even though fragments of the resulting conformations have a wrong sense of chirality. We propose that a better condition of folding should augment the simple criteria with the requirement that most of the local values of the chirality should be nearly native. The kinetic discrepancy between the simple and compound criteria can be substantially reduced in the Go-like models by providing the Hamiltonian with a term which favours native values of the local chirality. We study the effects of this term as a function of its amplitude and compare it to other models such as ones with side groups and ones with angle-dependent potentials.

  20. Chirality and equilibrium biopolymer bundles.

    PubMed

    Grason, Gregory M; Bruinsma, Robijn F

    2007-08-31

    We use continuum theory to show that chirality is a key thermodynamic control parameter for the aggregation of biopolymers: chirality produces a stable disperse phase of hexagonal bundles under moderately poor solvent conditions, as has been observed in in vitro studies of F actin [O. Pelletier et al., Phys. Rev. Lett. 91, 148102 (2003)]. The large characteristic radius of these chiral bundles is not determined by a mysterious long-range molecular interaction but by in-plane shear elastic stresses generated by the interplay between a chiral torque and an unusual, but universal, nonlinear gauge term in the strain tensor of ordered chains that is imposed by rotational invariance. PMID:17931038

  1. Chiral drag force

    NASA Astrophysics Data System (ADS)

    Rajagopal, Krishna; Sadofyev, Andrey V.

    2015-10-01

    We provide a holographic evaluation of novel contributions to the drag force acting on a heavy quark moving through strongly interacting plasma. The new contributions are chiral in the sense that they act in opposite directions in plasmas containing an excess of left- or right-handed quarks. The new contributions are proportional to the coefficient of the axial anomaly, and in this sense also are chiral. These new contributions to the drag force act either parallel to or antiparallel to an external magnetic field or to the vorticity of the fluid plasma. In all these respects, these contributions to the drag force felt by a heavy quark are analogous to the chiral magnetic effect (CME) on light quarks. However, the new contribution to the drag force is independent of the electric charge of the heavy quark and is the same for heavy quarks and antiquarks, meaning that these novel effects do not in fact contribute to the CME current. We show that although the chiral drag force can be non-vanishing for heavy quarks that are at rest in the local fluid rest frame, it does vanish for heavy quarks that are at rest in a suitably chosen frame. In this frame, the heavy quark at rest sees counterpropagating momentum and charge currents, both proportional to the axial anomaly coefficient, but feels no drag force. This provides strong concrete evidence for the absence of dissipation in chiral transport, something that has been predicted previously via consideration of symmetries. Along the way to our principal results, we provide a general calculation of the corrections to the drag force due to the presence of gradients in the flowing fluid in the presence of a nonzero chemical potential. We close with a consequence of our result that is at least in principle observable in heavy ion collisions, namely an anticorrelation between the direction of the CME current for light quarks in a given event and the direction of the kick given to the momentum of all the heavy quarks and

  2. Optical activity of chirally distorted nanocrystals

    NASA Astrophysics Data System (ADS)

    Tepliakov, Nikita V.; Baimuratov, Anvar S.; Baranov, Alexander V.; Fedorov, Anatoly V.; Rukhlenko, Ivan D.

    2016-05-01

    We develop a general theory of optical activity of semiconductor nanocrystals whose chirality is induced by a small perturbation of their otherwise achiral electronic subsystems. The optical activity is described using the quantum-mechanical expressions for the rotatory strengths and dissymmetry factors introduced by Rosenfeld. We show that the rotatory strengths of optically active transitions are decomposed on electric dipole and magnetic dipole contributions, which correspond to the electric dipole and magnetic dipole transitions between the unperturbed quantum states. Remarkably, while the two kinds of rotatory strengths are of the same order of magnitude, the corresponding dissymmetry factors can differ by a factor of 105. By maximizing the dissymmetry of magnetic dipole absorption one can significantly enhance the enantioselectivity in the interaction of semiconductor nanocrystals with circularly polarized light. This feature may advance chiral and analytical methods, which will benefit biophysics, chemistry, and pharmaceutical science. The developed theory is illustrated by an example of intraband transitions inside a semiconductor nanocuboid, whose rotatory strengths and dissymmetry factors are calculated analytically.

  3. Forming disoriented chiral condensates through fluctuations

    SciTech Connect

    Rischke, D.H.

    1998-10-01

    Using the influence functional formalism, classical equations of motion for the O(N) model are derived in the presence of a heat bath, in both the symmetric phase as well as the phase of spontaneously broken symmetry. The heat bath leads to dissipation and fluctuation terms in the classical equations of motion, which are explicitly computed to lowest order in perturbation theory. In the broken phase these terms are found to be large for the {sigma} field, even at zero temperature, due to the decay process {sigma}{r_arrow}{pi}{pi}, while they are small for the {pi} fields at temperatures below T{sub c}{approx_equal}160 MeV. It is shown that in large volumes the presence of dissipation and fluctuations suppresses the formation of disoriented chiral condensates (DCC{close_quote}s). In small volumes, however, fluctuations become sufficiently large to induce the formation of DCC{close_quote}s even if chiral symmetry has not been restored in the initial stage of the system{close_quote}s evolution. {copyright} {ital 1998} {ital The American Physical Society}

  4. Chiral vacuum fluctuations in quantum gravity

    NASA Astrophysics Data System (ADS)

    Bethke, Laura; Magueijo, João

    2012-05-01

    In this paper we investigate cosmological tensor modes in terms of the Ashtekar variables of loop quantum gravity, for complex values of the Immirzi parameter. While, on-shell, the classical Hamiltonian reduces to the usual expression found in cosmological perturbation theory, the quantum Hamiltonian displays significant differences. We can find a physical Fourier space Hamiltonian in terms of graviton creation and annihilation operators, after selecting out the non-physical modes through the inner product which itself is determined by the reality conditions. We are left with the usual graviton modes but with a chiral asymmetry in the the vacuum energy and fluctuations. The latter depends on γ (in particular it vanishes for purely real γ) and on the ordering of the 2-point function. Such an effect would leave a distinctive imprint in the polarisation of the cosmic microwave background, thus finally engaging quantum gravity in meaningful experimental test.

  5. Hypernuclei and in-medium chiral dynamics

    NASA Astrophysics Data System (ADS)

    Finelli, P.

    2008-04-01

    A recently introduced relativistic nuclear energy density functional, constrained by features of low-energy QCD, is extended to describe the structure of hypernuclei. The density-dependent mean field and the spin-orbit potential of a Λ-hyperon in a nucleus, are consistently calculated using the SU(3) extension of in-medium chiral perturbation theory. The leading long-range ΛN interaction arises from kaon-exchange and 2π-exchange with a Σ-hyperon in the intermediate state. Scalar and vector mean fields, originating from in-medium changes of the quark condensates, produce a sizeable short-range spin-orbit interaction. The model, when applied to oxygen as a test case, provides a natural explanation for the smallness of the effective Λ spin-orbit potential: an almost complete cancellation between the background contributions (scalar and vector) and the long-range terms generated by two-pion exchange.

  6. Chiral plaquette polaron theory of cuprate superconductivity

    NASA Astrophysics Data System (ADS)

    Tahir-Kheli, Jamil; Goddard, William A., III

    2007-07-01

    separation distance from (π/a,π/a) given by δQ≈(2π/a)x , where x is the doping. When the perturbed x2-y2 band energy in mean field is included, incommensurability along the Cu-O bond direction is favored. A resistivity ˜Tμ+1 arises when the polaron energy separation density is of the form ˜Δμ due to Coulomb scattering of the x2-y2 band with polarons. A uniform density leads to linear resistivity. The coupling of the x2-y2 band to the undoped Cud9 spins leads to the angle-resolved photoemission pseudogap and its qualitative doping and temperature dependence. The chiral plaquette polaron leads to an explanation of the evolution of the bilayer splitting in Bi-2212.

  7. Chiral Crystallization of Ethylenediamine Sulfate

    ERIC Educational Resources Information Center

    Koby, Lawrence; Ningappa, Jyothi B.; Dakesssian, Maria; Cuccia, Louis A.

    2005-01-01

    The optimal conditions for the crystallization of achiral ethylenediamine sulfate into large chiral crystals that are ideal for polarimetry studies and observation using Polaroid sheets are presented. This experiment is an ideal undergraduate experiment, which clearly demonstrates the chiral crystallization of an achiral molecule.

  8. CHIRAL POLLUTANTS: OCCURRENCE AND SIGNIFICANCE

    EPA Science Inventory

    This task involves process research to determine the environmental occurrence and fate of enantiomers of selected chiral pesticides, PCBs and other chiral pollutants with an emphasis on currently-used modern pesticides expected to have short to intermediate environmental half-liv...

  9. CHIRAL PESTICIDES: OCCURRENCE AND SIGNIFICANCE

    EPA Science Inventory

    Like amino acids, certain pesticides exist in "left-handed" and "right-handed" (chiral) forms. Commercially available chiral pesticides are produced as racemic mixtures in which the ratio of the two forms (or enantiomers) is 1:1. Enantiomers have the same ...

  10. Mass-Selective Chiral Analysis.

    PubMed

    Boesl, Ulrich; Kartouzian, Aras

    2016-06-12

    Three ways of realizing mass-selective chiral analysis are reviewed. The first is based on the formation of diastereomers that are of homo- and hetero- type with respect to the enantiomers of involved chiral molecules. This way is quite well-established with numerous applications. The other two ways are more recent developments, both based on circular dichroism (CD). In one, conventional or nonlinear electronic CD is linked to mass spectrometry (MS) by resonance-enhanced multiphoton ionization. The other is based on CD in the angular distribution of photoelectrons, which is measured in combination with MS via photoion photoelectron coincidence. Among the many important applications of mass-selective chiral analysis, this review focuses on its use as an analytical tool for the development of heterogeneous enantioselective chemical catalysis. There exist other approaches to combine chiral analysis and mass-selective detection, such as chiral chromatography MS, which are not discussed here. PMID:27070181

  11. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo F.; Karas, Andrew S.; Schultz, Benjamin A.; Engel, Michael; Glotzer, Sharon C.

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams.

  12. Mass-Selective Chiral Analysis

    NASA Astrophysics Data System (ADS)

    Boesl, Ulrich; Kartouzian, Aras

    2016-06-01

    Three ways of realizing mass-selective chiral analysis are reviewed. The first is based on the formation of diastereomers that are of homo- and hetero- type with respect to the enantiomers of involved chiral molecules. This way is quite well-established with numerous applications. The other two ways are more recent developments, both based on circular dichroism (CD). In one, conventional or nonlinear electronic CD is linked to mass spectrometry (MS) by resonance-enhanced multiphoton ionization. The other is based on CD in the angular distribution of photoelectrons, which is measured in combination with MS via photoion photoelectron coincidence. Among the many important applications of mass-selective chiral analysis, this review focuses on its use as an analytical tool for the development of heterogeneous enantioselective chemical catalysis. There exist other approaches to combine chiral analysis and mass-selective detection, such as chiral chromatography MS, which are not discussed here.

  13. Controlling Chirality of Entropic Crystals.

    PubMed

    Damasceno, Pablo F; Karas, Andrew S; Schultz, Benjamin A; Engel, Michael; Glotzer, Sharon C

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. PMID:26550757

  14. Density perturbation theory

    SciTech Connect

    Palenik, Mark C.; Dunlap, Brett I.

    2015-07-28

    Despite the fundamental importance of electron density in density functional theory, perturbations are still usually dealt with using Hartree-Fock-like orbital equations known as coupled-perturbed Kohn-Sham (CPKS). As an alternative, we develop a perturbation theory that solves for the perturbed density directly, removing the need for CPKS. This replaces CPKS with a true Hohenberg-Kohn density perturbation theory. In CPKS, the perturbed density is found in the basis of products of occupied and virtual orbitals, which becomes ever more over-complete as the size of the orbital basis set increases. In our method, the perturbation to the density is expanded in terms of a series of density basis functions and found directly. It is possible to solve for the density in such a way that it makes the total energy stationary even if the density basis is incomplete.

  15. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Friedrich, Jan Michael

    2016-01-01

    With the COMPASS experiment at CERN, pion-photon reactions are investigated via the Primakoff effect, implying that high-energetic pions react with the quasi-real photon field surrounding the target nuclei. The production of a single hard photon in such a pion scattering at lowest momentum transfer to the nucleus is related to pion Compton scattering. From the measured cross-section shape, the pion polarisability is determined. The COMPASS measurement is in contradiction to the earlier dedicated measurements, and rather in agreement with the theoretical expectation from chiral perturbation theory. In the same data taking, reactions with neutral and charged pions in the final state are measured and analyzed. At low energy in the pion-photon centre-of-momentum system, these reactions are governed by chiral dynamics and contain information relevant for chiral perturbation theory. At higher energies, resonances are produced and their radiative coupling is investigated.

  16. Chiral symmetry and effective field theories for hadronic, nuclear and stellar matter

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Rho, Mannque; Weise, Wolfram

    2016-03-01

    Chiral symmetry, first entering in nuclear physics in the 1970s for which Gerry Brown played a seminal role, has led to a stunningly successful framework for describing strongly-correlated nuclear dynamics both in finite and infinite systems. We review how the early, germinal idea conceived with the soft-pion theorems in the pre-QCD era has evolved into a highly predictive theoretical framework for nuclear physics, aptly assessed by Steven Weinberg: "it (chiral effective field theory) allows one to show in a fairly convincing way that what they (nuclear physicists) have been doing all along... is the correct first step in a consistent approximation scheme". Our review recounts both how the theory presently fares in confronting Nature and how one can understand its extremely intricate workings in terms of the multifaceted aspects of chiral symmetry, namely, chiral perturbation theory, skyrmions, Landau Fermi-liquid theory, the Cheshire cat phenomenon, and hidden local and mended symmetries.

  17. Visualizing the chiral anomaly in Dirac and Weyl semimetals with photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Behrends, Jan; Grushin, Adolfo G.; Ojanen, Teemu; Bardarson, Jens H.

    2016-02-01

    Quantum anomalies are the breaking of a classical symmetry by quantum fluctuations. They dictate how physical systems of diverse nature, ranging from fundamental particles to crystalline materials, respond topologically to external perturbations, insensitive to local details. The anomaly paradigm was triggered by the discovery of the chiral anomaly that contributes to the decay of pions into photons and influences the motion of superfluid vortices in 3He-A. In the solid state, it also fundamentally affects the properties of topological Weyl and Dirac semimetals, recently realized experimentally. In this work we propose that the most identifying consequence of the chiral anomaly, the charge density imbalance between fermions of different chirality induced by nonorthogonal electric and magnetic fields, can be directly observed in these materials with the existing technology of photoemission spectroscopy. With angle resolution, the chiral anomaly is identified by a characteristic note-shaped pattern of the emission spectra, originating from the imbalanced occupation of the bulk states and a previously unreported momentum dependent energy shift of the surface state Fermi arcs. We further demonstrate that the chiral anomaly likewise leaves an imprint in angle averaged emission spectra, facilitating its experimental detection. Thereby, our work provides essential theoretical input to foster the direct visualization of the chiral anomaly in condensed matter, in contrast to transport properties, such as negative magnetoresistance, which can also be obtained in the absence of a chiral anomaly.

  18. Off-equilibrium photon production during the chiral phase transition

    SciTech Connect

    Michler, Frank; Hees, Hendrik van; Dietrich, Dennis D.; Leupold, Stefan; Greiner, Carsten

    2013-09-15

    In the early stage of ultrarelativistic heavy-ion collisions chiral symmetry is restored temporarily. During this so-called chiral phase transition, the quark masses change from their constituent to their bare values. This mass shift leads to the spontaneous non-perturbative creation of quark–antiquark pairs, which effectively contributes to the formation of the quark–gluon plasma. We investigate the photon production induced by this creation process. We provide an approach that eliminates possible unphysical contributions from the vacuum polarization and renders the resulting photon spectra integrable in the ultraviolet domain. The off-equilibrium photon numbers are of quadratic order in the perturbative coupling constants while a thermal production is only of quartic order. Quantitatively, we find, however, that for the most physical mass-shift scenarios and for photon momenta larger than 1 GeV the off-equilibrium processes contribute less photons than the thermal processes. -- Highlights: •We investigate first-order photon emission arising from the chiral mass shift. •We provide an ansatz eliminating possible unphysical vacuum contributions. •Our ansatz leads to photon spectra being integrable in the ultraviolet domain.

  19. Microscopically constrained mean-field models from chiral nuclear thermodynamics

    NASA Astrophysics Data System (ADS)

    Rrapaj, Ermal; Roggero, Alessandro; Holt, Jeremy W.

    2016-06-01

    We explore the use of mean-field models to approximate microscopic nuclear equations of state derived from chiral effective field theory across the densities and temperatures relevant for simulating astrophysical phenomena such as core-collapse supernovae and binary neutron star mergers. We consider both relativistic mean-field theory with scalar and vector meson exchange as well as energy density functionals based on Skyrme phenomenology and compare to thermodynamic equations of state derived from chiral two- and three-nucleon forces in many-body perturbation theory. Quantum Monte Carlo simulations of symmetric nuclear matter and pure neutron matter are used to determine the density regimes in which perturbation theory with chiral nuclear forces is valid. Within the theoretical uncertainties associated with the many-body methods, we find that select mean-field models describe well microscopic nuclear thermodynamics. As an additional consistency requirement, we study as well the single-particle properties of nucleons in a hot/dense environment, which affect e.g., charged-current weak reactions in neutron-rich matter. The identified mean-field models can be used across a larger range of densities and temperatures in astrophysical simulations than more computationally expensive microscopic models.

  20. Chiral current generation in QED by longitudinal photons

    NASA Astrophysics Data System (ADS)

    Acosta Avalo, J. L.; Pérez Rojas, H.

    2016-08-01

    We report the generation of a pseudovector electric current having imbalanced chirality in an electron-positron strongly magnetized gas in QED. It propagates along the external applied magnetic field B as a chiral magnetic effect in QED. It is triggered by a perturbative electric field parallel to B, associated to a pseudovector longitudinal mode propagating along B. An electromagnetic chemical potential was introduced, but our results remain valid even when it vanishes. A nonzero fermion mass was assumed, which is usually considered vanishing in the literature. In the quantum field theory formalism at finite temperature and density, an anomaly relation for the axial current was found for a medium of massive fermions. It bears some analogy to the Adler-Bell-Jackiw anomaly. From the expression for the chiral current in terms of the photon self-energy tensor in a medium, it is obtained that electrons and positrons scattered by longitudinal photons (inside the light cone) contribute to the chiral current, as well as the to pair creation due to longitudinal photons (out of light cone). In the static limit, an electric pseudovector current is obtained in the lowest Landau level.

  1. Chiral fiber optical isolator

    NASA Astrophysics Data System (ADS)

    Kopp, Victor I.; Zhang, Guoyin; Zhang, Sheng; Genack, Azriel Z.; Neugroschl, Dan

    2009-02-01

    We propose an in-fiber chiral optical isolator based on chiral fiber polarizer technology and calculate its performance by incorporating the magnetic field into the scattering matrix. The design will be implemented in a special preform, which is passed through a miniature heat zone as it is drawn and twisted. The birefringence of the fiber is controlled by adjusted the diameter of a dual-core optical fiber. By adjusting the twist, the fiber can convert linear to circular polarization and reject one component of circular polarization. In the novel central portion of the isolator, the fiber diameter is large. The effective birefringence of the circular central core with high Verdet constant embedded in an outer core of slightly smaller index of refraction is small. The central potion is a non-reciprocal polarization converter which passes forward traveling left circularly polarized (LCP) light as LCP, while converting backward propagating LCP to right circularly polarized (RCP) light. Both polarizations of light traveling backwards are scattered out of the isolator. Since it is an all-glass structure, we anticipate that the isolator will be able to handle several watts of power and will be environmentally robust.

  2. Chiral quantum dot based materials

    NASA Astrophysics Data System (ADS)

    Govan, Joseph; Loudon, Alexander; Baranov, Alexander V.; Fedorov, Anatoly V.; Gun'ko, Yurii

    2014-05-01

    Recently, the use of stereospecific chiral stabilising molecules has also opened another avenue of interest in the area of quantum dot (QD) research. The main goal of our research is to develop new types of technologically important quantum dot materials containing chiral defects, study their properties and explore their applications. The utilisation of chiral penicillamine stabilisers allowed the preparation of new water soluble white emitting CdS quantum nanostructures which demonstrated circular dichroism in the band-edge region of the spectrum. It was also demonstrated that all three types of QDs (D-, L-, and Rac penicillamine stabilised) show very broad emission bands between 400 and 700 nm due to defects or trap states on the surfaces of the nanocrystals. In this work the chiral CdS based quantum nanostructures have also been doped by copper metal ions and new chiral penicilamine stabilized CuS nanoparticles have been prepared and investigated. It was found that copper doping had a strong effect at low levels in the synthesis of chiral CdS nanostructures. We expect that this research will open new horizons in the chemistry of chiral nanomaterials and their application in biotechnology, sensing and asymmetric synthesis.

  3. Automated Lattice Perturbation Theory

    SciTech Connect

    Monahan, Christopher

    2014-11-01

    I review recent developments in automated lattice perturbation theory. Starting with an overview of lattice perturbation theory, I focus on the three automation packages currently "on the market": HiPPy/HPsrc, Pastor and PhySyCAl. I highlight some recent applications of these methods, particularly in B physics. In the final section I briefly discuss the related, but distinct, approach of numerical stochastic perturbation theory.

  4. Chiral Bosonic Phases on the Haldane Honeycomb Lattice

    NASA Astrophysics Data System (ADS)

    Vasic, Ivana; Petrescu, Alexandru; Le Hur, Karyn; Hofstetter, Walter; Collaboration Collaboration

    2015-03-01

    Motivated by its recent realization in an ultracold atom experiment, we investigate the honeycomb lattice tight-binding model introduced by Haldane, for bosons with local interactions at the average filling of one boson per site. We uncover in the ground state phase diagram three phases: a uniform superfluid (SF), a chiral superfluid (CSF) and a plaquette Mott insulator with local current loops (PMI). Nearest-neighbor and next-nearest neighbor currents distinguish CSF from SF, and the phase transition between them is first order. We apply bosonic dynamical mean field theory and exact diagonalization to obtain the zero temperature phase diagram, complementing numerics with calculations of excitation spectra in strong and weak coupling perturbation theory. Furthermore, we explore the possibility of chiral Mott insulating phases at the average filling of one boson every two sites. The characteristic density fluctuations, current correlation functions, and excitation spectra are measurable in ultracold atom experiments.

  5. Amino Acids and Chirality

    NASA Technical Reports Server (NTRS)

    Cook, Jamie E.

    2012-01-01

    Amino acids are among the most heavily studied organic compound class in carbonaceous chondrites. The abundance, distributions, enantiomeric compositions, and stable isotopic ratios of amino acids have been determined in carbonaceous chondrites fi'om a range of classes and petrographic types, with interesting correlations observed between these properties and the class and typc of the chondritcs. In particular, isomeric distributions appear to correlate with parent bodies (chondrite class). In addition, certain chiral amino acids are found in enantiomeric excess in some chondrites. The delivery of these enantiomeric excesses to the early Earth may have contributed to the origin of the homochirality that is central to life on Earth today. This talk will explore the amino acids in carbonaceous chondritcs and their relevance to the origin of life.

  6. Chiral Bosonization of Superconformal Ghosts

    NASA Technical Reports Server (NTRS)

    Shi, Deheng; Shen, Yang; Liu, Jinling; Xiong, Yongjian

    1996-01-01

    We explain the difference of the Hilbert space of the superconformal ghosts (beta,gamma) system from that of its bosonized fields phi and chi. We calculate the chiral correlation functions of phi, chi fields by inserting appropriate projectors.

  7. Life's chirality from prebiotic environments

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Walker, Sara Imari

    2012-10-01

    A key open question in the study of life is the origin of biomolecular homochirality: almost every life-form on Earth has exclusively levorotary amino acids and dextrorotary sugars. Will the same handedness be preferred if life is found elsewhere? We review some of the pertinent literature and discuss recent results suggesting that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events. In one scenario, autocatalytic prebiotic reactions undergo stochastic fluctuations due to environmental disturbances, in a mechanism reminiscent of evolutionary punctuated equilibrium: short-lived destructive events may lead to long-term enantiomeric excess. In another, chiral-selective polymerization reaction rates influenced by environmental effects lead to substantial chiral excess even in the absence of autocatalysis. Applying these arguments to other potentially life-bearing platforms has implications to the search for extraterrestrial life: we predict that a statistically representative sampling of extraterrestrial stereochemistry will be racemic (chirally neutral) on average.

  8. Critical dimensions for chiral bosons

    SciTech Connect

    Mezincescu, L.; Nepomechie, R.I.

    1988-05-15

    We give the Lagrangian formulation of a Bose model in 1+1 dimensions which describes a free chiral Lie-algebra-valued current. This model is a non-Abelian generalization of the chiral scalar model of Siegel. Both the Abelian and non-Abelian actions have a gauge invariance, which becomes anomalous when the models are quantized. The condition that this anomaly be canceled coincides with the string no-ghost condition.

  9. Frame independent cosmological perturbations

    SciTech Connect

    Prokopec, Tomislav; Weenink, Jan E-mail: j.g.weenink@uu.nl

    2013-09-01

    We compute the third order gauge invariant action for scalar-graviton interactions in the Jordan frame. We demonstrate that the gauge invariant action for scalar and tensor perturbations on one physical hypersurface only differs from that on another physical hypersurface via terms proportional to the equation of motion and boundary terms, such that the evolution of non-Gaussianity may be called unique. Moreover, we demonstrate that the gauge invariant curvature perturbation and graviton on uniform field hypersurfaces in the Jordan frame are equal to their counterparts in the Einstein frame. These frame independent perturbations are therefore particularly useful in relating results in different frames at the perturbative level. On the other hand, the field perturbation and graviton on uniform curvature hypersurfaces in the Jordan and Einstein frame are non-linearly related, as are their corresponding actions and n-point functions.

  10. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    PubMed Central

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-01-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application. PMID:27401541

  11. Correlation between structures of chiral polymers and their efficiency for chiral resolution by crystallization.

    PubMed

    Menahem, Tali; Pravda, Martin; Mastai, Yitzhak

    2009-10-01

    In this work, we describe the correlation between chiral polymer structures, particularly alpha-helical and random coil conformations, and their efficiency as chiral resolving agents in crystallization processes. A set of chiral block copolymers based on polyethylene oxide with chiral glutamic acid oligopeptide segments (PEG(113)-b-(+)-(S)-Glu(20)) were synthesized and employed as additives in the crystallization of rac-threonine. CD spectroscopy demonstrates that structures of chiral polymers could be switched between a helical and a disordered random coil by pH. The effect of these polymers at different conformations on the crystallization kinetics, crystal morphology, and chiral resolution of rac-threonine is reported. Our study demonstrates that only chiral polymers with alpha-helical conformations of the chiral segment are effective as additives for chiral resolution throughout crystallization. Overall, our results provide useful guidelines for the selection and design of chiral polymer additives that will act efficiently for chiral resolution by crystallization. PMID:19455618

  12. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    NASA Astrophysics Data System (ADS)

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-07-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application.

  13. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation.

    PubMed

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-01-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application. PMID:27401541

  14. Peripheral NN scattering from subtractive renormalization of chiral interactions

    SciTech Connect

    Batista, E. F.; Szpigel, S.; Timóteo, V. S.

    2014-11-11

    We apply five subtractions in the Lippman-Schwinger (LS) equation in order to perform a non-perturbative renormalization of chiral N3LO nucleon-nucleon interactions. Here we compute the phase shifts for the uncoupled peripheral waves at renormalization scales between 0.1 fm{sup −1} and 1 fm{sup −1}. In this range, the results are scale invariant and provide an overall good agreement with the Nijmegen partial wave analysis up to at least E{sub lab} = 150 MeV, with a cutoff at Λ = 30 fm{sup −1}.

  15. Ward identities and chiral anomalies for coupled fermionic chains

    NASA Astrophysics Data System (ADS)

    Costa, L. C.; Ferraz, A.; Mastropietro, Vieri

    2013-12-01

    Coupled fermionic chains are usually described by an effective model written in terms of bonding and anti-bonding fermionic fields with linear dispersion in the vicinities of the respective Fermi points. We derive for the first time exact Ward Identities (WI) for this model, proving the existence of chiral anomalies which verify the Adler-Bardeen non-renormalization property. Such WI are expected to play a crucial role in the understanding of the thermodynamic properties of the system. Our results are non-perturbative and are obtained analyzing Grassmann functional integrals by means of constructive quantum field theory methods.

  16. The Perturbed Puma Model

    NASA Astrophysics Data System (ADS)

    Rong, Shu-Jun; Liu, Qiu-Yu

    2012-04-01

    The puma model on the basis of the Lorentz and CPT violation may bring an economical interpretation to the conventional neutrinos oscillation and part of the anomalous oscillations. We study the effect of the perturbation to the puma model. In the case of the first-order perturbation which keeps the (23) interchange symmetry, the mixing matrix element Ue3 is always zero. The nonzero mixing matrix element Ue3 is obtained in the second-order perturbation that breaks the (23) interchange symmetry.

  17. Neutron matter with Quantum Monte Carlo: chiral 3N forces and static response

    NASA Astrophysics Data System (ADS)

    Buraczynski, M.; Gandolfi, S.; Gezerlis, A.; Schwenk, A.; Tews, I.

    2016-03-01

    Neutron matter is related to the physics of neutron stars and that of neutron-rich nuclei. Quantum Monte Carlo (QMC) methods offer a unique way of solving the many-body problem non-perturbatively, providing feedback on features of nuclear interactions and addressing scenarios that are inaccessible to other approaches. In this contribution we go over two recent accomplishments in the theory of neutron matter: a) the fusing of QMC with chiral effective field theory interactions, focusing on local chiral 3N forces, and b) the first attempt to find an ab initio solution to the problem of static response.

  18. Neutron matter with Quantum Monte Carlo: chiral 3N forces and static response

    DOE PAGESBeta

    Buraczynski, M.; Gandolfi, S.; Gezerlis, A.; Schwenk, A.; Tews, I.

    2016-03-01

    Neutron matter is related to the physics of neutron stars and that of neutron-rich nuclei. Moreover, Quantum Monte Carlo (QMC) methods offer a unique way of solving the many-body problem non-perturbatively, providing feedback on features of nuclear interactions and addressing scenarios that are inaccessible to other approaches. Our contribution goes over two recent accomplishments in the theory of neutron matter: a) the fusing of QMC with chiral effective field theory interactions, focusing on local chiral 3N forces, and b) the first attempt to find an ab initio solution to the problem of static response.

  19. Nucleon sigma term and strange quark content from lattice QCD with exact chiral symmetry

    SciTech Connect

    Ohki, H.; Fukaya, H.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Matsufuru, H.; Noaki, J.; Shintani, E.; Onogi, T.

    2008-09-01

    We calculate the nucleon sigma term in two-flavor lattice QCD utilizing the Feynman-Hellman theorem. Both sea and valence quarks are described by the overlap fermion formulation, which preserves exact chiral and flavor symmetries on the lattice. We analyze the lattice data for the nucleon mass using the analytical formulae derived from the baryon chiral perturbation theory. From the data at valence quark mass set different from sea quark mass, we may extract the sea quark contribution to the sigma term, which corresponds to the strange quark content. We find that the strange quark content is much smaller than the previous lattice calculations and phenomenological estimates.

  20. Chiral symmetry in rotating systems

    NASA Astrophysics Data System (ADS)

    Malik, Sham S.

    2015-08-01

    The triaxial rotating system at critical angular momentum I ≥Iband exhibits two enatiomeric (the left- and right-handed) forms. These enatiomers are related to each other through dynamical chiral symmetry. The chiral symmetry in rotating system is defined by an operator χ ˆ =Rˆy (π) T ˆ, which involves the product of two distinct symmetries, namely, continuous and discrete. Therefore, new guidelines are required for testing its commutation with the system Hamiltonian. One of the primary objectives of this study is to lay down these guidelines. Further, the possible impact of chiral symmetry on the geometrical arrangement of angular momentum vectors and investigation of observables unique to nuclear chiral-twins is carried out. In our model, the angular momentum components (J1, J2, J3) occupy three mutually perpendicular axes of triaxial shape and represent a non-planar configuration. At certain threshold energy, the equation of motion in angular momentum develops a second order phase transition and as a result two distinct frames (i.e., the left- and right-handed) are formed. These left- and right-handed states correspond to a double well system and are related to each other through chiral operator. At this critical angular momentum, the centrifugal and Coriolis interactions lower the barrier in the double well system. The tunneling through the double well starts, which subsequently lifts the degeneracy among the rotational states. A detailed analysis of the behavior of rotational energies, spin-staggering, and the electromagnetic transition probabilities of the resulting twin-rotational bands is presented. The ensuing model results exhibit similarities with many observed features of the chiral-twins. An advantage of our formalism is that it is quite simple and it allows us to pinpoint the understanding of physical phenomenon which lead to chiral-twins in rotating systems.

  1. Towards the chiral limit in QCD

    SciTech Connect

    Shailesh Chandrasekharan

    2006-02-28

    Computing hadronic observables by solving QCD from first principles with realistic quark masses is an important challenge in fundamental nuclear and particle physics research. Although lattice QCD provides a rigorous framework for such calculations many difficulties arise. Firstly, there are no good algorithms to solve lattice QCD with realistically light quark masses. Secondly, due to critical slowing down, Monte Carlo algorithms are able to access only small lattice sizes on coarse lattices. Finally, due to sign problems it is almost impossible to study the physics of finite baryon density. Lattice QCD contains roughly three mass scales: the cutoff (or inverse lattice spacing) a{sup -1}, the confinement scale {Lambda}{sub QCD}, and the pion mass m{sub {pi}}. Most conventional Monte Carlo algorithms for QCD become inefficient in two regimes: when {Lambda}{sub QCD} becomes small compared to a{sup -1} and when m{sub {pi}} becomes small compared to {Lambda}{sub QCD}. The former can be largely controlled by perturbation theory thanks to asymptotic freedom. The latter is more difficult since chiral extrapolations are typically non-analytic and can be unreliable if the calculations are not done at sufficiently small quark masses. For this reason it has been difficult to compute quantities close to the chiral limit. The essential goal behind this proposal was to develop a new approach towards understanding QCD and QCD-like theories with sufficiently light quarks. The proposal was based on a novel cluster algorithm discovered in the strong coupling limit with staggered fermions [1]. This algorithm allowed us to explore the physics of exactly massless quarks and as well as light quarks. Thus, the hope was that this discovery would lead to the complete solution of at least a few strongly coupled QCD-like theories. The solution would be far better than those achievable through conventional methods and thus would be able to shed light on the chiral physics from a new

  2. Can a Non-Chiral Object Be Made of Two Identical Chiral Moieties?

    ERIC Educational Resources Information Center

    LeMarechal, Jean Francois

    2008-01-01

    Several pedagogical objects can be used to discuss chirality. Here, we use the cut of an apple to show that the association of identical chiral moieties can form a non-chiral object. Octahedral chirality is used to find situations equivalent to the cut of the apple. (Contains 5 figures.)

  3. Chiral Chlordane Components in Environmental Matrices

    EPA Science Inventory

    Chlordane, a persistent, bioaccumulative and toxic organochlorine pesticide, has been studied for many years. Since the advent of chiral analysis for environmental samples, over 2,400 measurements have been made of various chiral chlordane components. Chlordane enantiomer fractio...

  4. Effects of chirality and surface stresses on the bending and buckling of chiral nanowires

    NASA Astrophysics Data System (ADS)

    Wang, Jian-Shan; Shimada, Takahiro; Wang, Gang-Feng; Kitamura, Takayuki

    2014-01-01

    Due to their superior optical, elastic and electrical properties, chiral nanowires have many applications as sensors, probes, and building blocks of nanoelectromechanical systems. In this paper, we develop a refined Euler-Bernoulli beam model for chiral nanowires with surface effects and material chirality incorporated. This refined model is employed to investigate the bending and buckling of chiral nanowires. It is found that surface effects and material chirality significantly affect the elastic behaviour of chiral nanowires. This study is helpful not only for understanding the size-dependent behaviour of chiral nanowires, but also for characterizing their mechanical properties.

  5. Hydrogen-Regulated Chiral Nanoplasmonics.

    PubMed

    Duan, Xiaoyang; Kamin, Simon; Sterl, Florian; Giessen, Harald; Liu, Na

    2016-02-10

    Chirality is a highly important topic in modern chemistry, given the dramatically different pharmacological effects that enantiomers can have on the body. Chirality of natural molecules can be controlled by reconfiguration of molecular structures through external stimuli. Despite the rapid progress in plasmonics, active regulation of plasmonic chirality, particularly in the visible spectral range, still faces significant challenges. In this Letter, we demonstrate a new class of hybrid plasmonic metamolecules composed of magnesium and gold nanoparticles. The plasmonic chirality from such plasmonic metamolecules can be dynamically controlled by hydrogen in real time without introducing macroscopic structural reconfiguration. We experimentally investigate the switching dynamics of the hydrogen-regulated chiroptical response in the visible spectral range using circular dichroism spectroscopy. In addition, energy dispersive X-ray spectroscopy is used to examine the morphology changes of the magnesium particles through hydrogenation and dehydrogenation processes. Our study can enable plasmonic chiral platforms for a variety of gas detection schemes by exploiting the high sensitivity of circular dichroism spectroscopy. PMID:26745446

  6. Tactoids of chiral liquid crystals

    NASA Astrophysics Data System (ADS)

    Palacio-Betancur, Viviana; Villada-Gil, Stiven; Zhou, Ye; Armas-Pérez, Julio C.; de Pablo, Juan José; Hernández-Ortiz, Juan Pablo

    The phase diagram of chiral liquid crystals confined in ellipsoids is obtained, by following a theoretically informed Monte Carlo relaxation of the tensor alignment field Q. The free energy of the system is described by a functional in the framework of the Landau-de Gennes formalism. This study also includes the effect of anchoring strength, curvature, and chirality of the system. In the low chirality region of the phase diagram we found the twist bipolar (BS) phase and some cholesteric phases such as the radial spherical structure (RSS), twist cylinder (TC) and double twist cylinder (DTC) whose axis of rotation is not necessarily aligned with the major axis of the geometry. For high chirality scenarios, the disclination lines are twisted or bent near the surface preventing the formation of symmetric networks of defects, although an hexagonal pattern is formed on the surface which might serve as open sites for collocation of colloids. By analyzing the free energies of isochoric systems, prolate geometries tend to be more favorable for high chirality and low anchoring conditions. Universidad Nacional de Colombia Ph.D. grant and COLCIENCIAS under the Contract No. 110-165-843-748. CONACYT for Postdoctoral Fellowships Nos. 186166 and 203840.

  7. Chiral Thirring–Wess model

    SciTech Connect

    Rahaman, Anisur

    2015-10-15

    The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson.

  8. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo; Karas, Andrew; Schultz, Benjamin; Engel, Michael; Glotzer, Sharon

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. Work supported by the National Science Foundation, Division of Materials Research Award No. DMR 1120923, U.S. Army Research Office under Grant Award No. W911NF-10-1-0518, and also by the DOD/ASD (R&E) under Award No. N00244-09-1-0062.

  9. Field induced spin chirality and chirality switching in magnetic multilayers

    NASA Astrophysics Data System (ADS)

    Tartakovskaya, Elena V.

    2015-05-01

    The physical origin of the field-induced spin chirality experimentally observed in rare earth multilayers is determined. It is shown that the effect is possible due to the interplay between solid-state exchange interactions (the Ruderman-Kittel-Kasuya-Yosida and the Dsyaloshinsky-Moriya interactions), the external magnetic field and a special confinement of magnetic constituents. The presented model describes a certain temperature dependence of the chirality factor in agreement with experimental data and opens a new way to design nanostructured objects with predicted handedness.

  10. Chiral lattice fermions with correct vacuum polarization and chiral anomaly

    SciTech Connect

    Pryor, C. )

    1991-04-15

    An action for chiral lattice fermions is proposed, which avoids the Nielsen-Ninomiya theorem by virtue of its nonlocality and nonbilinearity. The action is constructed by eliminating the extra fermion modes with a gauge-violating Majorana-type Wilson mass, which is then rendered invariant by an integration over gauge transformations. The free propagator is calculated, and the one-loop vacuum polarization is shown to be identical to that for Wilson fermions, even at nonzero lattice spacing. Also the chiral anomaly is shown to be the same as for Wilson fermions in the continuum limit.

  11. Repulsive Casimir force in chiral metamaterials.

    PubMed

    Zhao, R; Zhou, J; Koschny, Th; Economou, E N; Soukoulis, C M

    2009-09-01

    We demonstrate theoretically that one can obtain repulsive Casimir forces and stable nanolevitations by using chiral metamaterials. By extending the Lifshitz theory to treat chiral metamaterials, we find that a repulsive force and a minimum of the interaction energy possibly exist for strong chirality, under realistic frequency dependencies and correct limiting values (for zero and infinite frequencies) of the permittivity, permeability, and chiral coefficients. PMID:19792309

  12. Chiral order and fluctuations in multi-flavour QCD

    NASA Astrophysics Data System (ADS)

    Descotes-Genon, S.; Girlanda, L.; Stern, J.

    2003-03-01

    Multi-flavour (N_f ge 3) chiral perturbation theory (χPT) may exhibit instabilities due to vacuum fluctuations of sea bar q q pairs. Keeping the fluctuations small would require a very precise fine tuning of the low-energy constants L_4(μ) and L_6(μ) to L_4^{crit}(M_ρ) = - 0.51 \\cdot 10^{-3}, L_6^{crit}(M_ρ) = - 0.26 \\cdot 10^{-3}. A small deviation from these critical values - like the one suggested by the phenomenology of OZI-rule violation in the scalar channel - is amplified by huge numerical factors inducing large effects of vacuum fluctuations. This would lead in particular to a strong Nf dependence of chiral symmetry breaking (χSB) and a suppression of the multi-flavour chiral order parameters. A simple resummation is shown to cure the instability of N_fge 3 χPT, but it modifies the standard expressions of some O( p 2 ) and O( p 4 ) low-energy parameters in terms of observables. On the other hand, for r= m s / m & gt; 15, the two-flavour condensate is not suppressed, due to the contribution induced by massive vacuum bar ss pairs. Thanks to the latter, the standard two-flavour χPT is protected from multi-flavour instabilities and could provide a well-defined expansion scheme in powers of non-strange quark masses.

  13. Power counting regime of chiral effective field theory and beyond.

    SciTech Connect

    Hall, J. M.M.; Leinweber, D. B.; Young, R. D.; Physics; Univ. of Adelaide

    2010-08-10

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  14. Power counting regime of chiral effective field theory and beyond

    SciTech Connect

    Hall, J. M. M.; Leinweber, D. B.; Young, R. D.

    2010-08-01

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  15. Chiral Sensor for Enantiodiscrimination of Varied Acids.

    PubMed

    Huang, Huayin; Bian, Guangling; Zong, Hua; Wang, Yabai; Yang, Shiwei; Yue, Huifeng; Song, Ling; Fan, Hongjun

    2016-06-01

    A chiral thiophosphoroamide 4 derived from (1R,2R)-1,2-diaminocyclohexane is used as a highly effective chiral sensor for the chiral recognition of varied acids via ion-pairing and hydrogen-bonding interactions using (1)H, (19)F and (31)P NMR. PMID:27192021

  16. Chirality and gravitational parity violation.

    PubMed

    Bargueño, Pedro

    2015-06-01

    In this review, parity-violating gravitational potentials are presented as possible sources of both true and false chirality. In particular, whereas phenomenological long-range spin-dependent gravitational potentials contain both truly and falsely chiral terms, it is shown that there are models that extend general relativity including also coupling of fermionic degrees of freedom to gravity in the presence of torsion, which give place to short-range truly chiral interactions similar to that usually considered in molecular physics. Physical mechanisms which give place to gravitational parity violation together with the expected size of the effects and their experimental constraints are discussed. Finally, the possible role of parity-violating gravity in the origin of homochirality and a road map for future research works in quantum chemistry is presented. PMID:25919812

  17. Microwave propagation in chiral metamaterials

    NASA Astrophysics Data System (ADS)

    Prybylski, Aida; Yon, Luis; Noginova, Natalia

    Chiral hyperbolic metamaterials are predicted to show interesting properties associated with possible topological photonic states in these materials, which present new opportunities for light control and manipulation. As prototypes, we consider two metal-dielectric systems designed for microwave range: a twisted wires array, where chirality is associated with shape of metal inclusions, and a rotated layer system, with parallel wires in each layer, and direction of the wires orientation rotated from layer to layer. Systems with different content of metal and layer-to-layer distance were fabricated and studied in the free space propagation experiment. The results were discussed in terms of effective media consideration.

  18. Collisions in Chiral Kinetic Theory.

    PubMed

    Chen, Jing-Yuan; Son, Dam T; Stephanov, Mikhail A

    2015-07-10

    Using a covariant formalism, we construct a chiral kinetic theory Lorentz invariant to order O(ℏ), which includes collisions. We find a new contribution to the particle number current due to the side jumps required by the conservation of angular momentum during collisions. We also find a conserved symmetric stress-energy tensor as well as the H function obeying Boltzmann's H theorem. We demonstrate their use by finding a general equilibrium solution and the values of the anomalous transport coefficients characterizing the chiral vortical effect. PMID:26207458

  19. Mechanical chirality: A chiral catalyst with a ring to it

    NASA Astrophysics Data System (ADS)

    Goldup, Stephen M.

    2016-05-01

    A chiral [2]rotaxane in which the asymmetry is derived from the way in which the two components are mechanically interlocked -- rather than being encoded in the covalent connectivity of the components themselves -- has been shown to act as an enantioselective organocatalyst.

  20. Determination of the Chiral Condensate from (2+1)-Flavor Lattice QCD

    SciTech Connect

    Fukaya, H.; Aoki, S.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.; Onogi, T.

    2010-03-26

    We perform a precise calculation of the chiral condensate in QCD using lattice QCD with 2+1 flavors of dynamical overlap quarks. Up and down quark masses cover a range between 3 and 100 MeV on a 16{sup 3}x48 lattice at a lattice spacing {approx}0.11 fm. At the lightest sea quark mass, the finite volume system on the lattice is in the {epsilon} regime. By matching the low-lying eigenvalue spectrum of the Dirac operator with the prediction of chiral perturbation theory at the next-to-leading order, we determine the chiral condensate in (2+1)-flavor QCD with strange quark mass fixed at its physical value as {Sigma}{sup MS}(2 GeV)=[242(04)((+19/-18)) MeV]{sup 3} where the errors are statistical and systematic, respectively.

  1. Quantum theory of chiral interactions in cholesteric liquid crystals

    NASA Astrophysics Data System (ADS)

    Issaenko, S. A.; Harris, A. B.; Lubensky, T. C.

    1999-07-01

    The effective chiral interaction between molecules arising from long-range quantum interactions between fluctuating charge moments is analyzed in terms of a simple model of chiral molecules. This model is based on the approximations that (a) the dominant excited states of a molecule form a band whose width is small compared to the average energy of excitation above the ground state and (b) biaxial orientational correlation between adjacent molecules can be neglected. Previous treatments of quantum chiral interactions have been based on a multipole expansion of the effective interaction energy within second-order perturbation theory. We consider a system consisting of elongated molecules and, although we invoke the expansion in terms of coordinates transverse to the long axis of constituent molecules, we treat the longitudinal coordinate exactly. Such an approximation is plausible for molecules in real liquid crystals. The macroscopic cholesteric wave vector Q (Q=2π/P, where P is the pitch) is obtained via Q=h/K2, where K2 is the Frank elastic constant for twist and h is the torque field which we calculate from the effective chiral interaction κIJaI×aJ.RIJ, where the unit vector aI specifies the orientation of molecule I and RIJ is the displacement of molecule I relative to molecule J. We identify two distinct physical limits depending on whether one or both of the interacting molecules are excited in the virtual state. When both molecules are excited, we regain the R-8IJ dependence of κIJ on intermolecular separation found previously by Van der Meer et al. [J. Chem. Phys. 65, 3935 (1976)]. The two-molecule, unlike the one-molecule term, can be interpreted in terms of a superposition of pairwise interactions between individual atoms (or local chiral centers) on the two molecules. Contributions to κIJ when one molecule is excited in the virtual state are of order R-7IJ for helical molecules which are assumed not to have a global dipole moment, but whose atoms

  2. Coherent perfect absorption in chiral metamaterials.

    PubMed

    Ye, Yuqian; Hay, Darrick; Shi, Zhimin

    2016-07-15

    We study the coherent perfect absorption (CPA) of a chiral structure and derive analytically the CPA condition for transversely isotropic chiral structures in circular polarization bases. The coherent absorption of such a chiral system is generally polarization dependent and can be tuned by the relative phase between the coherent input beams. To demonstrate our theoretical predictions, a chiral metamaterial absorber operating in the terahertz frequency range is optimized. We numerically demonstrate that a coherent absorption of 99.5% can be achieved. Moreover, we show that an optimized CPA chiral structure can be used as an interferometric control of polarization state of the output beams with constant output intensity. PMID:27420535

  3. Scaling laws in chiral hydrodynamic turbulence

    NASA Astrophysics Data System (ADS)

    Yamamoto, Naoki

    2016-06-01

    We study the turbulent regime of chiral (magneto)hydrodynamics for charged and neutral matter with chirality imbalance. We find that the chiral magnetohydrodynamics for charged plasmas possesses a unique scaling symmetry, only without fluid helicity under the local charge neutrality. We also find a different type of unique scaling symmetry in the chiral hydrodynamics for neutral matter with fluid helicity in the inertial range. We show that these symmetries dictate the self-similar inverse cascade of the magnetic and kinetic energies. Our results imply the possible inverse energy cascade in core-collapse supernovae due to the chiral transport of neutrinos.

  4. Chiral xenobiotics bioaccumulations and environmental health prospectives.

    PubMed

    Hussain, Iqbal; ALOthman, Zeid A; Alwarthan, Abdulrahman A; Sanagi, Mohd Marsin; Ali, Imran

    2015-08-01

    The chiral xenobiotics are very dangerous for all of us due to the different enantioselective toxicities of the enantiomers. Besides, these have different enantioselective bioaccumulations and behaviors in our body and other organisms. It is of urgent need to understand the enantioselective bioaccumulations, toxicities, and the health hazards of the chiral xenobiotics. The present article describes the classification, sources of contamination, distribution, enantioselective bioaccumulation, and the toxicities of the chiral xenobiotics. Besides, the efforts are also made to discuss the prevention and remedial measures of the havoc of the chiral xenobiotics. The challenges of the chiral xenobiotics have also been highlighted. Finally, future prospectives are also discussed. PMID:26148690

  5. Vortex perturbation dynamics

    NASA Technical Reports Server (NTRS)

    Criminale, W. O.; Lasseigne, D. G.; Jackson, T. L.

    1995-01-01

    An initial value approach is used to examine the dynamics of perturbations introduced into a vortex under strain. Both the basic vortex considered and the perturbations are taken as fully three-dimensional. An explicit solution for the time evolution of the vorticity perturbations is given for arbitrary initial vorticity. Analytical solutions for the resulting velocity components are found when the initial vorticity is assumed to be localized. For more general initial vorticity distributions, the velocity components are determined numerically. It is found that the variation in the radial direction of the initial vorticity disturbance is the most important factor influencing the qualitative behavior of the solutions. Transient growth in the magnitude of the velocity components is found to be directly attributable to the compactness of the initial vorticity.

  6. Helical motion of chiral liquid crystal droplets

    NASA Astrophysics Data System (ADS)

    Yamamoto, Takaki; Sano, Masaki

    Artificial swimmers have been intensively studied to understand the mechanism of the locomotion and collective behaviors of cells and microorganisms. Among them, most of the artificial swimmers are designed to move along the straight path. However, in biological systems, chiral dynamics such as circular and helical motion are quite common because of the chirality of their bodies, which are made of chiral biomolecules. To understand the role of the chirality in the physics of microswimmers, we designed chiral artificial swimmers and the theoretical model for the chiral motion. We found that chiral liquid crystal droplets, when dispersed in surfactant solutions, swim in the helical path induced by the Marangoni effect. We will discuss the mechanism of the helical motion with our phenomenological model. This work is supported by Grant-in-Aid for JSPS Fellows (Grant No. 26.9814), and MEXT KAKENHI Grant No. 25103004.

  7. Chirality effect in disordered graphene ribbon junctions

    NASA Astrophysics Data System (ADS)

    Long, Wen

    2012-05-01

    We investigate the influence of edge chirality on the electronic transport in clean or disordered graphene ribbon junctions. By using the tight-binding model and the Landauer-Büttiker formalism, the junction conductance is obtained. In the clean sample, the zero-magnetic-field junction conductance is strongly chirality-dependent in both unipolar and bipolar ribbons, whereas the high-magnetic-field conductance is either chirality-independent in the unipolar or chirality-dependent in the bipolar ribbon. Furthermore, we study the disordered sample in the presence of magnetic field and find that the junction conductance is always chirality-insensitive for both unipolar and bipolar ribbons with adequate disorders. In addition, the disorder-induced conductance plateaus can exist in all chiral bipolar ribbons provided the disorder strength is moderate. These results suggest that we can neglect the effect of edge chirality in fabricating electronic devices based on the magnetotransport in a disordered graphene ribbon.

  8. On the tensorial nature of chirality

    NASA Astrophysics Data System (ADS)

    Efrati, Efi; Irvine, William

    2013-03-01

    Chirality occupies a central role in fields ranging from biological self assembly to the design of optical meta-materials. The definition of chirality, as given by lord Kelvin in 1893, associates handedness with the lack of mirror symmetry. However, the quantification of chirality based on this definition has proven to be an elusive task. The difficulty in quantifying chirality is contrasted by the ease with which one determines the handedness of objects with a well defined axis such as screws and helices. In this talk I will present table-top demonstrations that show that a single object can simultaneously be left handed and right handed when considered from different directions. The orientation dependence of handedness motivates a tensorial quantification of chirality relating directions to rotations. I will give an explicit example of such a tensorial measure of chirality for embedded surfaces, and show how the tensorial nature of chirality can be probed in experiments and exploited as a design principle.

  9. Micropatterning of cells reveals chiral morphogenesis

    PubMed Central

    2013-01-01

    Invariant left-right (LR) patterning or chirality is critical for embryonic development. The loss or reversal of LR asymmetry is often associated with malformations and disease. Although several theories have been proposed, the exact mechanism of the initiation of the LR symmetry has not yet been fully elucidated. Recently, chirality has been detected within single cells as well as multicellular structures using several in vitro approaches. These studies demonstrated the universality of cell chirality, its dependence on cell phenotype, and the role of physical boundaries. In this review, we discuss the theories for developmental LR asymmetry, compare various in vitro cell chirality model systems, and highlight possible roles of cell chirality in stem cell differentiation. We emphasize that the in vitro cell chirality systems have great promise for helping unveil the nature of chiral morphogenesis in development. PMID:23672821

  10. Influence of the Polyakov loop on the chiral phase transition in the two flavor chiral quark model

    NASA Astrophysics Data System (ADS)

    Markó, G.; Szép, Zs.

    2010-09-01

    The SU(2)L×SU(2)R chiral quark model consisting of the (σ,π→) meson multiplet and the constituent quarks propagating on the homogeneous background of a temporal gauge field is solved at finite temperature and quark baryon chemical potential μq using an expansion in the number of flavors Nf, both in the chiral limit and for the physical value of the pion mass. Keeping the fermion propagator at its tree level, several approximations to the pion propagator are investigated. These approximations correspond to different partial resummations of the perturbative series. Comparing their solution with a diagrammatically formulated resummation relying on a strict large-Nf expansion of the perturbative series, one concludes that only when the local part of the approximated pion propagator resums infinitely many orders in 1/Nf of fermionic contributions a sufficiently rapid crossover transition at μq=0 is achieved allowing for the existence of a tricritical point or a critical end point in the μq-T phase diagram. The renormalization and the possibility of determining the counterterms in the resummation provided by a strict large-Nf expansion are investigated.

  11. Baryon and chiral symmetry breaking

    SciTech Connect

    Gorsky, A.; Krikun, A.

    2014-07-23

    We briefly review the generalized Skyrmion model for the baryon recently suggested by us. It takes into account the tower of vector and axial mesons as well as the chiral symmetry breaking. The generalized Skyrmion model provides the qualitative explanation of the Ioffe’s formula for the baryon mass.

  12. Chiral phosphines in nucleophilic organocatalysis

    PubMed Central

    Xiao, Yumei; Sun, Zhanhu

    2014-01-01

    Summary This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols. PMID:25246969

  13. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1994-07-01

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on possible experimental ramifications.

  14. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1995-07-10

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on their possible experimental ramifications. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  15. Non-perturbative aspects of hadron structure in QCD

    SciTech Connect

    Thomas, Anthony W.

    2012-09-26

    We review recent developments in the understanding of hadron structure in the context of QCD. These developments build on the success of lattice QCD and discoveries in chiral perturbation theory. We focus particularly on tests of QCD through the strangeness content of the nucleon, the investigation of excited states of the nucleon, where lattice QCD, experiment and phenomenology meet. Lastly, we discuss the implications of these developments in hadron structure for our understanding of nuclear structure and the equation of state of dense matter.

  16. Non-perturbative QCD Modeling and Meson Physics

    NASA Astrophysics Data System (ADS)

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-01

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  17. Non-perturbative QCD Modeling and Meson Physics

    SciTech Connect

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-20

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  18. Cosmological perturbations in antigravity

    NASA Astrophysics Data System (ADS)

    Oltean, Marius; Brandenberger, Robert

    2014-10-01

    We compute the evolution of cosmological perturbations in a recently proposed Weyl-symmetric theory of two scalar fields with oppositely signed conformal couplings to Einstein gravity. It is motivated from the minimal conformal extension of the standard model, such that one of these scalar fields is the Higgs while the other is a new particle, the dilaton, introduced to make the Higgs mass conformally symmetric. At the background level, the theory admits novel geodesically complete cyclic cosmological solutions characterized by a brief period of repulsive gravity, or "antigravity," during each successive transition from a big crunch to a big bang. For simplicity, we consider scalar perturbations in the absence of anisotropies, with potential set to zero and without any radiation. We show that despite the necessarily wrong-signed kinetic term of the dilaton in the full action, these perturbations are neither ghostlike nor tachyonic in the limit of strongly repulsive gravity. On this basis, we argue—pending a future analysis of vector and tensor perturbations—that, with respect to perturbative stability, the cosmological solutions of this theory are viable.

  19. Light meson electromagnetic form factors from three-flavor lattice QCD with exact chiral symmetry

    NASA Astrophysics Data System (ADS)

    Aoki, S.; Cossu, G.; Feng, X.; Hashimoto, S.; Kaneko, T.; Noaki, J.; Onogi, T.

    2016-02-01

    We study the chiral behavior of the electromagnetic (EM) form factors of pions and kaons in three-flavor lattice QCD. In order to make a direct comparison of the lattice data with chiral perturbation theory (ChPT), we employ the overlap quark action that has exact chiral symmetry. Gauge ensembles are generated at a lattice spacing of 0.11 fm with four pion masses ranging between Mπ≃290 MeV and 540 MeV and with a strange quark mass ms close to its physical value. We utilize the all-to-all quark propagator technique to calculate the EM form factors with high precision. Their dependence on ms and on the momentum transfer is studied by using the reweighting technique and the twisted boundary conditions for the quark fields, respectively. A detailed comparison with SU(2) and SU(3) ChPT reveals that the next-to-next-to-leading order terms in the chiral expansion are important to describe the chiral behavior of the form factors in the pion mass range studied in this work. We estimate the relevant low-energy constants and the charge radii, and find reasonable agreement with phenomenological and experimental results.

  20. The Relaxation of Twisted Chiral Nematic Liquid Crystals with Side-Chain Polymeric Layer

    NASA Astrophysics Data System (ADS)

    Zhou, Xuan; Zhang, Zhidong

    2013-09-01

    A generalized form of surface dissipation function, for the description of the relative motion of the nematic director with respect to the polymer side chains in twisted chiral nematic samples is proposed, and the relaxation time of such samples are investigated, using the perturbation analysis method proposed by Alexe-Ionescu et al. Our results show that the presence of both the surface dissipation and the polymer side chains increase the relaxation time.

  1. Mean field theory of the linear sigma-model: chiral solitons

    SciTech Connect

    Kahana, S.; Ripka, G.

    1983-01-01

    The mean field theory of the chiral invariant sigma-model is outlined. bound states (solitons) of valence quarks are obtained self-consistently using a hedgehog shape for the pion field. A schematic model for the coupled fermion-boson fields is presented. Renormalization is worked out for the fermion one-loop corrections and numerical results presented for the purely scalar-field case. The interpretation of the baryon number of the perturbed vacuum is considered.

  2. Nucleon structure in the chiral regime with domain wall fermions on an improved staggered sea

    SciTech Connect

    R.G. Edwards; G. Fleming; Ph. Hagler; J.W. Negele; K. Orginos; A.V. Pochinsky; D.B. Renner; D.G. Richards; W. Schroers

    2006-07-23

    Moments of unpolarized, helicity, and transversity distributions, electromagnetic form factors, and generalized form factors of the nucleon are presented from a preliminary analysis of lattice results using pion masses down to 359 MeV. The twist two matrix elements are calculated using a mixed action of domain wall valence quarks and asqtad staggered sea quarks and are renormalized perturbatively. Several observables are extrapolated to the physical limit using chiral perturbation theory. Results are compared with experimental moments of quark distributions and electromagnetic form factors and phenomenologically determined generalized form factors, and the implications on the transverse structure and spin content of the nucleon are discussed.

  3. Chiral sensing by nonchiral tetrapyrroles.

    PubMed

    Labuta, Jan; Hill, Jonathan P; Ishihara, Shinsuke; Hanyková, Lenka; Ariga, Katsuhiko

    2015-03-17

    Enantiomeric excess (ee) is a measure of the purity of an enantiomer of a chiral compound with respect to the presence of the complementary enantiomer. It is an important aspect of chemistry, especially in the fields of pharmaceuticals and asymmetric catalysis. Existing methods for determination of enantiomeric excesses using nuclear magnetic resonance (NMR) spectroscopy mostly rely on special chiral reagents (auxiliaries) that form two or more diastereomeric complexes with a chiral compound. As a result of this, the NMR spectrum of each enantiomer is different, allowing the determination of enantiomeric excess. In this Account, we describe a molecular design process that has allowed us to prepare prochiral solvating agents for NMR determination of ee of a wide variety of analyte types. At the outset of this work, we initially encountered the phenomenon of NMR peak splitting in the oxoporphyrinogen (OxP) host component of a supramolecular host-guest complex, where the extent of the splitting is apparently proportional to the guests' ee. Upon closer examination of the mechanism of action, it was found that several complicating factors, including prototropic tautomerism, macrocyclic inversion (ring-flipping), and 1:2 host-guest stoichiometry, obstruct potential applications of OxP as a chiral solvating agent. By considering the molecular conformation of the OxP host, a saddle-shaped calix[4]pyrrole, we moved to study the tetraphenylporphyrin (TPP) dication since it has a similar form, and it was found that it could also be used to probe ee. However, although TPP does not suffer from disadvantageous tautomeric processes, it is still subject to macrocyclic inversion and has the additional serious disadvantage of operating for ee sensing only at depressed temperatures. The intrinsic disadvantages of the OxP and TPP systems were finally overcome by covalently modifying the OxP chromophore by regioselective N-alkylation at one face of the molecule. This procedure yields a

  4. Liouvillian perturbations of black holes

    NASA Astrophysics Data System (ADS)

    Couch, W. E.; Holder, C. L.

    2007-10-01

    We apply the well-known Kovacic algorithm to find closed form, i.e., Liouvillian solutions, to the differential equations governing perturbations of black holes. Our analysis includes the full gravitational perturbations of Schwarzschild and Kerr, the full gravitational and electromagnetic perturbations of Reissner-Nordstrom, and specialized perturbations of the Kerr-Newman geometry. We also include the extreme geometries. We find all frequencies ω, in terms of black hole parameters and an integer n, which allow Liouvillian perturbations. We display many classes of black hole parameter values and their corresponding Liouvillian perturbations, including new closed-form perturbations of Kerr and Reissner-Nordstrom. We also prove that the only type 1 Liouvillian perturbations of Schwarzschild are the known algebraically special ones and that type 2 Liouvillian solutions do not exist for extreme geometries. In cases where we do not prove the existence or nonexistence of Liouvillian perturbations we obtain sequences of Diophantine equations on which decidability rests.

  5. Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters

    NASA Astrophysics Data System (ADS)

    Katsuno, Hiroyasu; Uwaha, Makio

    2016-01-01

    By grinding crystals in a solution, the chirality of crystal structure (and the molecular chirality for the case of chiral molecules as well) can be converted, and the cause of the phenomenon is attributed to crystal growth with chiral clusters. We show that the recently found chirality conversion with a periodic change of temperature can also be explained by crystal growth with chiral clusters. With the use of a generalized Becker-Döring model, which includes enantio-selective incorporation of small chiral clusters to large solid clusters, the change of cluster distribution and the mass flow between clusters are studied. The chiral clusters act as a reservoir to pump out the minority species to the majority, and the exponential amplification of the enantiomeric excess found in the experiment is reproduced in the numerical calculation.

  6. Aspects of perturbative unitarity

    NASA Astrophysics Data System (ADS)

    Anselmi, Damiano

    2016-07-01

    We reconsider perturbative unitarity in quantum field theory and upgrade several arguments and results. The minimum assumptions that lead to the largest time equation, the cutting equations and the unitarity equation are identified. Using this knowledge and a special gauge, we give a new, simpler proof of perturbative unitarity in gauge theories and generalize it to quantum gravity, in four and higher dimensions. The special gauge interpolates between the Feynman gauge and the Coulomb gauge without double poles. When the Coulomb limit is approached, the unphysical particles drop out of the cuts and the cutting equations are consistently projected onto the physical subspace. The proof does not extend to nonlocal quantum field theories of gauge fields and gravity, whose unitarity remains uncertain.

  7. Topology and perturbation theory

    NASA Astrophysics Data System (ADS)

    Manjavidze, J.

    2000-08-01

    This paper contains description of the fields nonlinear modes successive quantization scheme. It is shown that the path integrals for absorption part of amplitudes are defined on the Dirac (δ-like) functional measure. This permits arbitrary transformation of the functional integral variables. New form of the perturbation theory achieved by mapping the quantum dynamics in the space WG of the (action, angle)-type collective variables. It is shown that the transformed perturbation theory contributions are accumulated exactly on the boundary ∂WG. Abilities of the developed formalism are illustrated by the Coulomb problem. This model is solved in the WC=(angle, angular momentum, Runge-Lentz vector) space and the reason of its exact integrability is emptiness of ∂WC.

  8. Renormalized Lie perturbation theory

    SciTech Connect

    Rosengaus, E.; Dewar, R.L.

    1981-07-01

    A Lie operator method for constructing action-angle transformations continuously connected to the identity is developed for area preserving mappings. By a simple change of variable from action to angular frequency a perturbation expansion is obtained in which the small denominators have been renormalized. The method is shown to lead to the same series as the Lagrangian perturbation method of Greene and Percival, which converges on KAM surfaces. The method is not superconvergent, but yields simple recursion relations which allow automatic algebraic manipulation techniques to be used to develop the series to high order. It is argued that the operator method can be justified by analytically continuing from the complex angular frequency plane onto the real line. The resulting picture is one where preserved primary KAM surfaces are continuously connected to one another.

  9. Intermolecular perturbation theory

    NASA Astrophysics Data System (ADS)

    Hayes, I. C.; Hurst, G. J. B.; Stone, A. J.

    The new intermolecular perturbation theory described in the preceding papers is applied to some van der Waals molecules. HeBe is used as a test case, and the perturbation method converges well at interatomic distances down to about 4 a0, giving results in excellent agreement with supermolecule calculations. ArHF and ArHCl have been studied using large basis sets, and the results agree well with experimental data. The ArHX configuration is favoured over the ArXH configuration mainly because of larger polarization and charge-transfer contributions. In NeH2 the equilibrium geometry is determined by a delicate balance between opposing effects; with a double-zeta-polarization basis the correct configuration is predicted.

  10. Enantioselective recognition at mesoporous chiral metal surfaces

    PubMed Central

    Wattanakit, Chularat; Côme, Yémima Bon Saint; Lapeyre, Veronique; Bopp, Philippe A.; Heim, Matthias; Yadnum, Sudarat; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2014-01-01

    Chirality is widespread in natural systems, and artificial reproduction of chiral recognition is a major scientific challenge, especially owing to various potential applications ranging from catalysis to sensing and separation science. In this context, molecular imprinting is a well-known approach for generating materials with enantioselective properties, and it has been successfully employed using polymers. However, it is particularly difficult to synthesize chiral metal matrices by this method. Here we report the fabrication of a chirally imprinted mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and chiral template molecules. The porous platinum retains a chiral character after removal of the template molecules. A matrix obtained in this way exhibits a large active surface area due to its mesoporosity, and also shows a significant discrimination between two enantiomers, when they are probed using such materials as electrodes. PMID:24548992

  11. Asymmetric synthesis using chiral-encoded metal

    PubMed Central

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-01-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity. PMID:27562028

  12. Molecular chirality: language, history, and significance.

    PubMed

    Gal, Joseph

    2013-01-01

    In this chapter some background material concerning molecular chirality and enantiomerism is presented. First some basic chemical-molecular aspects of chirality are reviewed, after which certain relevant terminology whose use in the literature has been problematic is discussed. Then an overview is provided of some of the early discoveries that laid the foundations of the science of molecular chirality in chemistry and biology, including the discovery of the phenomenon of molecular chirality by L. Pasteur, the proposals for the asymmetric carbon atom by J.H. van 't Hoff and J.A. Lebel, Pasteur's discovery of biological enantioselectivity, the discovery of enantioselectivity at biological receptors by A. Piutti, the studies of enzymatic stereoselectivity by E. Fischer, and the work on enantioselectivity in pharmacology by A. Cushny. Finally, the role of molecular chirality in pharmacotherapy and new-drug development, arguably one of the main driving forces for the current intense interest in the phenomenon of molecular chirality, is discussed. PMID:23666078

  13. Stable Pentaquarks from Strange Chiral Multiplets

    SciTech Connect

    Silas Beane

    2004-12-01

    The assumption of strong diquark correlations in the QCD spectrum suggests flavor multiplets of hadrons that are degenerate in the chiral limit. Generally it would be unnatural for there to be degeneracy in the hadron spectrum that is not protected by a QCD symmetry. Here we show--for pentaquarks constructed from diquarks--that these degeneracies can be naturally protected by the full chiral symmetry of QCD. The resulting chiral multiplet structure recovers the ideally-mixed pentaquark mass spectrum of the diquark model, and interestingly, requires that the axial couplings of the pentaquarks to states outside the degenerate multiplets vanish in the chiral limit. This result suggests that if these hadrons exist, they are stable in the chiral limit and therefore have widths that scale as the fourth power of the kaon mass over the chiral symmetry breaking scale. Natural-size widths are of order a few MeV.

  14. Anomalous Maxwell equations for inhomogeneous chiral plasma

    NASA Astrophysics Data System (ADS)

    Gorbar, E. V.; Shovkovy, I. A.; Vilchinskii, S.; Rudenok, I.; Boyarsky, A.; Ruchayskiy, O.

    2016-05-01

    Using the chiral kinetic theory we derive the electric and chiral current densities in inhomogeneous relativistic plasma. We also derive equations for the electric and chiral chemical potentials that close the Maxwell equations in such a plasma. The analysis is done in the regimes with and without a drift of the plasma as a whole. In addition to the currents present in the homogeneous plasma (Hall current, chiral magnetic, chiral separation, and chiral electric separation effects, as well as Ohm's current) we derive several new terms associated with inhomogeneities of the plasma. Apart from various diffusionlike terms, we find also new dissipationless terms that are independent of relaxation time. Their origin can be traced to the Berry curvature modifications of the kinetic theory.

  15. Asymmetric synthesis using chiral-encoded metal.

    PubMed

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-01-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity. PMID:27562028

  16. Chiral description of massive gravity

    NASA Astrophysics Data System (ADS)

    Alexandrov, Sergei; Krasnov, Kirill; Speziale, Simone

    2013-06-01

    We propose and study a new first order version of the ghost-free massive gravity. Instead of metrics or tetrads, it uses a connection together with Plebanski's chiral 2-forms as fundamental variables, rendering the phase space structure similar to that of SU(2) gauge theories. The chiral description simplifies computations of the constraint algebra, and allows us to perform the complete canonical analysis of the system. In particular, we explicitly compute the secondary constraint and carry out the stabilization procedure, thus proving that in general the theory propagates 7 degrees of freedom, consistently with previous claims. Finally, we point out that the description in terms of 2-forms opens the door to an infinite class of ghost-free massive bi-gravity actions. Our results apply directly to Euclidean signature. The reality conditions to be imposed in the Lorentzian signature appear to be more complicated than in the usual gravity case and are left as an open issue.

  17. Bootstrapping N=2 chiral correlators

    NASA Astrophysics Data System (ADS)

    Lemos, Madalena; Liendo, Pedro

    2016-01-01

    We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.

  18. On chirality of slime mould.

    PubMed

    Dimonte, Alice; Adamatzky, Andrew; Erokhin, Victor; Levin, Michael

    2016-02-01

    Left-right patterning and lateralised behaviour is an ubiquitous aspect of plants and animals. The mechanisms linking cellular chirality to the large-scale asymmetry of multicellular structures are incompletely understood, and it has been suggested that the chirality of living cells is hardwired in their cytoskeleton. We examined the question of biased asymmetry in a unique organism: the slime mould Physarum polycephalum, which is unicellular yet possesses macroscopic, complex structure and behaviour. In laboratory experiment using a T-shape, we found that Physarum turns right in more than 74% of trials. The results are in agreement with previously published studies on asymmetric movement of muscle cells, neutrophils, liver cells and growing neural filaments, and for the first time reveal the presence of consistently-biased laterality in the fungi kingdom. Exact mechanisms of the slime mould's direction preference remain unknown. PMID:26747637

  19. Microfluidic Separation of Chiral Particles

    NASA Astrophysics Data System (ADS)

    Marcos; Fu, Henry; Powers, Thomas; Stocker, Roman

    2008-11-01

    We present a combined theoretical and experimental investigation of the fluid mechanics of a helix exposed to a shear flow. In addition to classic Jeffery orbits, Resistive Force Theory predicts a drift of the helix across streamlines, perpendicular to the shear plane. The direction of the drift is determined by the direction of the shear and the chirality of the helix. We verify this prediction experimentally using microfluidics, by exposing Leptospira biflexa, a non-motile strain of helical-shaped bacteria, to a plane parabolic flow. As the shear in the top and bottom halves of the microchannel has opposite sign, we predict and observe the bacteria in these two regions to drift in opposite directions. The magnitude of the separation is in good quantitative agreement with theory. This setup can be used to separate microscale chiral objects.

  20. On lattice chiral gauge theories

    NASA Technical Reports Server (NTRS)

    Maiani, L.; Rossi, G. C.; Testa, M.

    1991-01-01

    The Smit-Swift-Aoki formulation of a lattice chiral gauge theory is presented. In this formulation the Wilson and other non invariant terms in the action are made gauge invariant by the coupling with a nonlinear auxilary scalar field, omega. It is shown that omega decouples from the physical states only if appropriate parameters are tuned so as to satisfy a set of BRST identities. In addition, explicit ghost fields are necessary to ensure decoupling. These theories can give rise to the correct continuum limit. Similar considerations apply to schemes with mirror fermions. Simpler cases with a global chiral symmetry are discussed and it is shown that the theory becomes free at decoupling. Recent numerical simulations agree with those considerations.

  1. Localizing Perturbations of the Racemic Equilibria Involving Dipicolinate-Derived Lanthanide(III) Complexes.

    PubMed

    Nguyen, Brian T; Ingram, Andrew J; Muller, Gilles

    2016-04-01

    Helical D3 tris(4-amino-2,6-pyridine-dicarboxylate)terbium(III) and europium(III) complexes, which form a racemic equilibrium in aqueous solution, were prepared to study their secondary coordination sphere interactions with chiral amino acids. These interactions were probed using a combination of circularly polarized luminescence (CPL) and 13C NMR spectroscopy. The results indicate that, regardless of the interaction between the chiral molecule and the complex, without an accessible hydrogen-bond donor on the associating molecule, perturbation of the racemic equilibrium cannot occur. A generalized conclusion is established that indicates that the mechanism of chiral recognition by tris(dipicolinate)lanthanide(III) complexes is similar across a variety of analogous ligands. PMID:26935003

  2. ENANTIOMERIC RATIOS OF CHIRAL PCB ATROPISOMERS IN RADIODATED SEDIMENT CORES

    EPA Science Inventory

    Enantiomeric ratios (ERs)) of chiral polychlorinated biphenyl (PCB) atropisomers were quantified in radiodated sediment cores of Lake Hartwell SC, a reservoir heavily impacted by PCBS, to study spatial and temporal changes in chirality. A chiral analysis of cores showed accumulat...

  3. Anomalies and Discrete Chiral Symmetries

    SciTech Connect

    Creutz, M.

    2009-09-07

    The quantum anomaly that breaks the U(1) axial symmetry of massless multi-flavored QCD leaves behind a discrete flavor-singlet chiral invariance. With massive quarks, this residual symmetry has a close connection with the strong CP-violating parameter theta. One result is that if the lightest quarks are degenerate, then a first order transition will occur when theta passes through pi. The resulting framework helps clarify when the rooting prescription for extrapolating in the number of flavors is valid.

  4. Chiral particle separation by a nonchiral microlattice.

    PubMed

    Bogunovic, Lukas; Fliedner, Marc; Eichhorn, Ralf; Wegener, Sonja; Regtmeier, Jan; Anselmetti, Dario; Reimann, Peter

    2012-09-01

    We conceived a model experiment for a continuous separation strategy of chiral molecules (enantiomers) without the need of any chiral selector structure or derivatization agents: Microparticles that only differ by their chirality are shown to migrate along different directions when driven by a steady fluid flow through a square lattice of cylindrical posts. In accordance with our numerical predictions, the transport directions of the enantiomers depend very sensitively on the orientation of the lattice relative to the fluid flow. PMID:23005274

  5. Chiral Particle Separation by a Nonchiral Microlattice

    NASA Astrophysics Data System (ADS)

    Bogunovic, Lukas; Fliedner, Marc; Eichhorn, Ralf; Wegener, Sonja; Regtmeier, Jan; Anselmetti, Dario; Reimann, Peter

    2012-09-01

    We conceived a model experiment for a continuous separation strategy of chiral molecules (enantiomers) without the need of any chiral selector structure or derivatization agents: Microparticles that only differ by their chirality are shown to migrate along different directions when driven by a steady fluid flow through a square lattice of cylindrical posts. In accordance with our numerical predictions, the transport directions of the enantiomers depend very sensitively on the orientation of the lattice relative to the fluid flow.

  6. Chiral anomaly, bosonization, and fractional charge

    SciTech Connect

    Mignaco, J.A.; Monteiro, M.A.R.

    1985-06-15

    We present a method to evaluate the Jacobian of chiral rotations, regulating determinants through the proper-time method and using Seeley's asymptotic expansion. With this method we compute easily the chiral anomaly for ..nu.. = 4,6 dimensions, discuss bosonization of some massless two-dimensional models, and handle the problem of charge fractionization. In addition, we comment on the general validity of Fujikawa's approach to regulate the Jacobian of chiral rotations with non-Hermitian operators.

  7. Objects of Maximum Electromagnetic Chirality

    NASA Astrophysics Data System (ADS)

    Fernandez-Corbaton, Ivan; Fruhnert, Martin; Rockstuhl, Carsten

    2016-07-01

    We introduce a definition of the electromagnetic chirality of an object and show that it has an upper bound. Reciprocal objects attain the upper bound if and only if they are transparent for all the fields of one polarization handedness (helicity). Additionally, electromagnetic duality symmetry, i.e., helicity preservation upon interaction, turns out to be a necessary condition for reciprocal objects to attain the upper bound. We use these results to provide requirements for the design of such extremal objects. The requirements can be formulated as constraints on the polarizability tensors for dipolar objects or on the material constitutive relations for continuous media. We also outline two applications for objects of maximum electromagnetic chirality: a twofold resonantly enhanced and background-free circular dichroism measurement setup, and angle-independent helicity filtering glasses. Finally, we use the theoretically obtained requirements to guide the design of a specific structure, which we then analyze numerically and discuss its performance with respect to maximal electromagnetic chirality.

  8. Chiral plasmons without magnetic field.

    PubMed

    Song, Justin C W; Rudner, Mark S

    2016-04-26

    Plasmons, the collective oscillations of interacting electrons, possess emergent properties that dramatically alter the optical response of metals. We predict the existence of a new class of plasmons-chiral Berry plasmons (CBPs)-for a wide range of 2D metallic systems including gapped Dirac materials. As we show, in these materials the interplay between Berry curvature and electron-electron interactions yields chiral plasmonic modes at zero magnetic field. The CBP modes are confined to system boundaries, even in the absence of topological edge states, with chirality manifested in split energy dispersions for oppositely directed plasmon waves. We unveil a rich CBP phenomenology and propose setups for realizing them, including in anomalous Hall metals and optically pumped 2D Dirac materials. Realization of CBPs will offer a powerful paradigm for magnetic field-free, subwavelength optical nonreciprocity, in the mid-IR to terahertz range, with tunable splittings as large as tens of THz, as well as sensitive all-optical diagnostics of topological bands. PMID:27071090

  9. Chiral plasmons without magnetic field

    NASA Astrophysics Data System (ADS)

    Song, Justin C. W.

    2016-04-01

    Plasmons, the collective oscillations of interacting electrons, possess emergent properties that dramatically alter the optical response of metals. We predict the existence of a new class of plasmons—chiral Berry plasmons (CBPs)—for a wide range of 2D metallic systems including gapped Dirac materials. As we show, in these materials the interplay between Berry curvature and electron–electron interactions yields chiral plasmonic modes at zero magnetic field. The CBP modes are confined to system boundaries, even in the absence of topological edge states, with chirality manifested in split energy dispersions for oppositely directed plasmon waves. We unveil a rich CBP phenomenology and propose setups for realizing them, including in anomalous Hall metals and optically pumped 2D Dirac materials. Realization of CBPs will offer a powerful paradigm for magnetic field-free, subwavelength optical nonreciprocity, in the mid-IR to terahertz range, with tunable splittings as large as tens of THz, as well as sensitive all-optical diagnostics of topological bands.

  10. Sperm Trajectories Form Chiral Ribbons

    PubMed Central

    Su, Ting-Wei; Choi, Inkyum; Feng, Jiawen; Huang, Kalvin; McLeod, Euan; Ozcan, Aydogan

    2013-01-01

    We report the discovery of an entirely new three-dimensional (3D) swimming pattern observed in human and horse sperms. This motion is in the form of ‘chiral ribbons’, where the planar swing of the sperm head occurs on an osculating plane creating in some cases a helical ribbon and in some others a twisted ribbon. The latter, i.e., the twisted ribbon trajectory, also defines a minimal surface, exhibiting zero mean curvature for all the points on its surface. These chiral ribbon swimming patterns cannot be represented or understood by already known patterns of sperms or other micro-swimmers. The discovery of these unique patterns is enabled by holographic on-chip imaging of >33,700 sperm trajectories at >90–140 frames/sec, which revealed that only ~1.7% of human sperms exhibit chiral ribbons, whereas it increases to ~27.3% for horse sperms. These results might shed more light onto the statistics and biophysics of various micro-swimmers' 3D motion. PMID:23588811

  11. Chiral selection on inorganic crystalline surfaces

    NASA Technical Reports Server (NTRS)

    Hazen, Robert M.; Sholl, David S.

    2003-01-01

    From synthetic drugs to biodegradable plastics to the origin of life, the chiral selection of molecules presents both daunting challenges and significant opportunities in materials science. Among the most promising, yet little explored, avenues for chiral molecular discrimination is adsorption on chiral crystalline surfaces - periodic environments that can select, concentrate and possibly even organize molecules into polymers and other macromolecular structures. Here we review experimental and theoretical approaches to chiral selection on inorganic crystalline surfaces - research that is poised to open this new frontier in understanding and exploiting surface-molecule interactions.

  12. Lateral chirality-sorting optical forces

    PubMed Central

    Hayat, Amaury; Mueller, J. P. Balthasar; Capasso, Federico

    2015-01-01

    The transverse component of the spin angular momentum of evanescent waves gives rise to lateral optical forces on chiral particles, which have the unusual property of acting in a direction in which there is neither a field gradient nor wave propagation. Because their direction and strength depends on the chiral polarizability of the particle, they act as chirality-sorting and may offer a mechanism for passive chirality spectroscopy. The absolute strength of the forces also substantially exceeds that of other recently predicted sideways optical forces. PMID:26453555

  13. Chiral Magnetic Effect in Hydrodynamic Approximation

    NASA Astrophysics Data System (ADS)

    Zakharov, Valentin I.

    We review derivations of the chiral magnetic effect (ChME) in hydrodynamic approximation. The reader is assumed to be familiar with the basics of the effect. The main challenge now is to account for the strong interactions between the constituents of the fluid. The main result is that the ChME is not renormalized: in the hydrodynamic approximation it remains the same as for non-interacting chiral fermions moving in an external magnetic field. The key ingredients in the proof are general laws of thermodynamics and the Adler-Bardeen theorem for the chiral anomaly in external electromagnetic fields. The chiral magnetic effect in hydrodynamics represents a macroscopic manifestation of a quantum phenomenon (chiral anomaly). Moreover, one can argue that the current induced by the magnetic field is dissipation free and talk about a kind of "chiral superconductivity". More precise description is a quantum ballistic transport along magnetic field taking place in equilibrium and in absence of a driving force. The basic limitation is the exact chiral limit while temperature—excitingly enough—does not seemingly matter. What is still lacking, is a detailed quantum microscopic picture for the ChME in hydrodynamics. Probably, the chiral currents propagate through lower-dimensional defects, like vortices in superfluid. In case of superfluid, the prediction for the chiral magnetic effect remains unmodified although the emerging dynamical picture differs from the standard one.

  14. Chiral mass-gap in curved space.

    PubMed

    Flachi, Antonino; Fukushima, Kenji

    2014-08-29

    We discuss a new type of QCD phenomenon induced in curved space. In the QCD vacuum, a mass-gap of Dirac fermions is attributed to the spontaneous breaking of chiral symmetry. If the curvature is positive large, the chiral condensate melts but a chiral invariant mass-gap can still remain, which we name the chiral gap effect in curved space. This leads to decoupling of quark deconfinement which implies a view of black holes surrounded by a first-order QCD phase transition. PMID:25215970

  15. Generation of a Chiral Giant Micelle.

    PubMed

    Ito, Thiago H; Salles, Airton G; Priebe, Jacks P; Miranda, Paulo C M L; Morgon, Nelson H; Danino, Dganit; Mancini, Giovanna; Sabadini, Edvaldo

    2016-08-23

    Over the past few years, chiral supramolecular assemblies have been successfully used for recognition, sensing and enantioselective transformations. Several approaches are available to control chirality of discrete assemblies (e.g., cages and capsules), but few are efficient in assuring chirality for micellar aggregates. Optically active amino acid-derived surfactants are commonly used to generate chiral spherical micelles. To circumvent this limitation, we benefited from the uniaxial growth of spherical micelles into long cylindrical micelles usually called wormlike or giant micelles, upon the addition of cosolutes. This paper describes the unprecedented formation of chiral giant micelles in aqueous solutions of cetyltrimethylammonium bromide (CTAB) upon increasing addition of enantiopure sodium salt of 1,1'-bi-2-naphthol (Na-binaphtholate) as a cosolute. Depending on the concentrations of CTAB and Na-binaphtholate, chiral gel-like systems are obtained. The transition from spherical to giant micellar structures was probed using rheology, cryo-transmission electron microscopy, polarimetry, and electronic circular dichroism (CD). CD can be effectively used to monitor the incorporation of Na-binaphtholate into the micelle palisade as well as to determine its transition to giant micellar structures. Our approach expands the scope for chirality induction in micellar aggregates bringing the possibility to generate "smart" chiral systems and an alternative asymmetric chiral environment to perform enantioselective transformations. PMID:27499127

  16. Inherently Chiral Spider-Like Oligothiophenes.

    PubMed

    Sannicolò, Francesco; Mussini, Patrizia R; Benincori, Tiziana; Martinazzo, Rocco; Arnaboldi, Serena; Appoloni, Giulio; Panigati, Monica; Quartapelle Procopio, Elsa; Marino, Valentina; Cirilli, Roberto; Casolo, Simone; Kutner, Wlodzimierz; Noworyta, Krzysztof; Pietrzyk-Le, Agnieszka; Iskierko, Zofia; Bartold, Katarzyna

    2016-07-25

    The racemate of an inherently chiral "spider-like" octathiophene monomer T83 , in which chirality is generated by torsion in its backbone, was synthesized. The racemate was resolved into configurationally stable antipodes by HPLC on a chiral stationary phase. Electrooxidation of the enantiomers resulted in materials displaying high enantiorecognition ability towards the antipodes of some chiral probes. Moreover, the T83 racemate demonstrated great aptitude to stimulate formation of 3D rigid architectures if used as a cross-linking monomer for molecular imprinting. This feature was exploited to devise a molecularly imprinted polymer-based chemosensor selective for a thymine-adenine oligonucleotide. PMID:27321902

  17. Chiral pattern formation in compact microbial colonies

    NASA Astrophysics Data System (ADS)

    Korolev, Kirill; Bino George, Ashish

    Chirality is ubiquitous in biology from single molecules to entire populations. Yet, we are still lacking a detailed understanding of how chiral patterns emerge from cell competition and growth, even in simple microbial colonies. Although many microbes grow as dense colonies with no apparent chirality, recent experiments with Escherichia coli have demonstrated that internal dynamics in such populations can be in fact chiral. We show that there is a unique way to extend the commonly-used reaction-diffusion models of colony growth to account for the emergent chirality. This new model connects microscopic and macroscopic chirality and explains the origin of logarithmic spirals separating different sub-populations in a colony. We also show that chirality is substantially enhanced by the cooperation among the cells at the expansion frontier. In heterogeneous populations composed of strains with different chiralities and growth rates, our model predicts a very rich set of possible dynamics. For example, different chiralities can result in either sharp boundaries between the strains or promote their intermixing depending on the preferred twisting directions of the strains.

  18. Inherently Chiral Calixarenes: Synthesis, Optical Resolution, Chiral Recognition and Asymmetric Catalysis

    PubMed Central

    Li, Shao-Yong; Xu, Yao-Wei; Liu, Jun-Min; Su, Cheng-Yong

    2011-01-01

    Inherently chiral calixarenes, whose chirality is based on the absence of a planar symmetry or an inversion center in the molecules as a whole through the asymmetric array of several achiral groups upon the three-dimensional calix-skeletons, are challenging and attractive chiral molecules, because of their potential in supramolecular chemistry. The synthesis and optical resolution of all varieties of inherently chiral calixarenes are systematically discussed and classified, and their applications in chiral recognition and asymmetric catalysis are thoroughly illustrated in this review. PMID:21339996

  19. Discrete reductive perturbation technique

    SciTech Connect

    Levi, Decio; Petrera, Matteo

    2006-04-15

    We expand a partial difference equation (P{delta}E) on multiple lattices and obtain the P{delta}E which governs its far field behavior. The perturbative-reductive approach is here performed on well-known nonlinear P{delta}Es, both integrable and nonintegrable. We study the cases of the lattice modified Korteweg-de Vries (mKdV) equation, the Hietarinta equation, the lattice Volterra-Kac-Van Moerbeke equation and a nonintegrable lattice KdV equation. Such reductions allow us to obtain many new P{delta}Es of the nonlinear Schroedinger type.

  20. Chirally-modified metal surfaces: energetics of interaction with chiral molecules.

    PubMed

    Dementyev, Petr; Peter, Matthias; Adamovsky, Sergey; Schauermann, Swetlana

    2015-09-21

    Imparting chirality to non-chiral metal surfaces by adsorption of chiral modifiers is a highly promising route to create effective heterogeneously catalyzed processes for the production of enantiopure pharmaceuticals. One of the major current challenges in heterogeneous chiral catalysis is the fundamental-level understanding of how such chirally-modified surfaces interact with chiral and prochiral molecules to induce their enantioselective transformations. Herein we report the first direct calorimetric measurement of the adsorption energy of chiral molecules onto well-defined chirally-modified surfaces. Two model modifiers 1-(1-naphthyl)ethylamine and 2-methylbutanoic acid were used to impart chirality to Pt(111) and their interaction with propylene oxide was investigated by means of single-crystal adsorption calorimetry. Differential adsorption energies and absolute surface uptakes were obtained for the R- and S-enantiomers of propylene oxide under clean ultrahigh vacuum conditions. Two types of adsorption behavior were observed for different chiral modifiers, pointing to different mechanisms of imparting chirality to metal surfaces. The results are analyzed and discussed in view of previously reported stereoselectivity of adsorption processes. PMID:26256836

  1. Hydrodynamics of Liquids of Chiral Molecules and Suspensions Containing Chiral Particles

    NASA Astrophysics Data System (ADS)

    Andreev, A. V.; Son, D. T.; Spivak, B.

    2010-05-01

    We obtain hydrodynamic equations describing a fluid consisting of chiral molecules or a suspension of chiral particles in a Newtonian fluid. The hydrodynamic velocity and stresses arising in a flowing chiral liquid have components that are forbidden by symmetry in a Newtonian liquid. For example, a chiral liquid in a Poiseuille flow between parallel plates exerts forces on the plates, which are perpendicular to the flow. A generic flow results in spatial separation of particles of different chirality. Thus even a racemic suspension will exhibit chiral properties in a generic flow. A suspension of particles of random shape in a Newtonian liquid is described by equations which are similar to those describing a racemic mixture of chiral particles in a liquid.

  2. Canonical floquet perturbation theory

    NASA Astrophysics Data System (ADS)

    Pohlen, David J.

    1992-12-01

    Classical Floquet theory is examined in order to generate a canonical transformation to modal variables for periodic system. This transformation is considered canonical if the periodic matrix of eigenvectors is symplectic at the initial time. Approaches for symplectic normalization of the eigenvectors had to be examined for each of the different Poincare eigenvalue cases. Particular attention was required in the degenerate case, which depended on the solution of a generalized eigenvector. Transformation techniques to ensure real modal variables and real periodic eigenvectors were also needed. Periodic trajectories in the restricted three-body case were then evaluated using the canonical Floquet solution. The system used for analyses is the Sun-Jupiter system. This system was especially useful since it contained two of the more difficult Poincare eigenvalue cases, the degenerate case and the imaginary eigenvalue case. The perturbation solution to the canonical modal variables was examined using both an expansion of the Hamiltonian and using a representation that was considered exact. Both methods compared quite well for small perturbations to the initial condition. As expected, the expansion solution failed first due to truncation after the third order term of the expansion.

  3. Variational Monte Carlo study of chiral spin liquid in quantum antiferromagnet on the triangular lattice

    NASA Astrophysics Data System (ADS)

    Hu, Wen-Jun; Gong, Shou-Shu; Sheng, D. N.

    2016-08-01

    By using Gutzwiller projected fermionic wave functions and variational Monte Carlo technique, we study the spin-1 /2 Heisenberg model with the first-neighbor (J1), second-neighbor (J2), and additional scalar chiral interaction JχSi.(Sj×Sk) on the triangular lattice. In the nonmagnetic phase of the J1-J2 triangular model with 0.08 ≲J2/J1≲0.16 , recent density-matrix renormalization group (DMRG) studies [Zhu and White, Phys. Rev. B 92, 041105(R) (2015), 10.1103/PhysRevB.92.041105 and Hu, Gong, Zhu, and Sheng, Phys. Rev. B 92, 140403(R) (2015), 10.1103/PhysRevB.92.140403] find a possible gapped spin liquid with the signal of a competition between a chiral and a Z2 spin liquid. Motivated by the DMRG results, we consider the chiral interaction JχSi.(Sj×Sk) as a perturbation for this nonmagnetic phase. We find that with growing Jχ, the gapless U(1) Dirac spin liquid, which has the best variational energy for Jχ=0 , exhibits the energy instability towards a gapped spin liquid with nontrivial magnetic fluxes and nonzero chiral order. We calculate topological Chern number and ground-state degeneracy, both of which identify this flux state as the chiral spin liquid with fractionalized Chern number C =1 /2 and twofold topological degeneracy. Our results indicate a positive direction to stabilize a chiral spin liquid near the nonmagnetic phase of the J1-J2 triangular model.

  4. Reaching the Chiral Limit in Many Flavor Systems

    NASA Astrophysics Data System (ADS)

    Hasenfratz, Anna; Cheng, Anqi; Petropoulos, Gregory; Schaich, David

    We present a brief overview of our recent lattice studies of SU(3) gauge theory with Nf = 8 and 12 fundamental fermions, including some new and yet-unpublished results. To explore relatively unfamiliar systems beyond lattice QCD, we carry out a wide variety of investigations with the goal of synthesizing the results to better understand the non-perturbative dynamics of these systems. All our findings are consistent with conformal infrared dynamics in the 12-flavor system, but with 8 flavors we observe puzzling behavior that requires further investigation. Our new Monte Carlo renormalization group technique exploits the Wilson flow to obtain more direct predictions of a 12-flavor IR fixed point. Studies of Nf = 12 bulk and finite-temperature transitions also indicate IR conformality, while our current results for the 8-flavor phase diagram do not yet provide clear signs of spontaneous chiral symmetry breaking. From the Dirac eigenvalue spectrum we extract the mass anomalous dimension γm, and predict γ*m = 0:32(3) at the 12-flavor fixed point. The Nf = 8 system again shows interesting behavior, with a large anomalous dimension across a wide range of energy scales. We use the eigenvalue density to predict the chiral condensate, and compare this approach with direct and partially-quenched < overline ψ ψ rangle measurements.

  5. Smooth Wilson loops in N=4 non-chiral superspace

    NASA Astrophysics Data System (ADS)

    Beisert, Niklas; Müller, Dennis; Plefka, Jan; Vergu, Cristian

    2015-12-01

    We consider a supersymmetric Wilson loop operator for 4d N = 4 super Yang-Mills theory which is the natural object dual to the AdS 5 × S 5 superstring in the AdS/CFT correspondence. It generalizes the traditional bosonic 1 /2 BPS Maldacena-Wilson loop operator and completes recent constructions in the literature to smooth (non-light-like) loops in the full N=4 non-chiral superspace. This Wilson loop operator enjoys global super-conformal and local kappa-symmetry of which a detailed discussion is given. Moreover, the finiteness of its vacuum expectation value is proven at leading order in perturbation theory. We determine the leading vacuum expectation value for general paths both at the component field level up to quartic order in anti-commuting coordinates and in the full non-chiral superspace in suitable gauges. Finally, we discuss loops built from quadric splines joined in such a way that the path derivatives are continuous at the intersection.

  6. Chiral symmetry breaking and confinement beyond rainbow-ladder truncation

    NASA Astrophysics Data System (ADS)

    Bashir, Adnan; Raya, Alfredo; Sánchez-Madrigal, Saúl

    2011-08-01

    A nonperturbative construction of the 3-point fermion-boson vertex which obeys its Ward-Takahashi or Slavnov-Taylor identity, ensures the massless fermion and boson propagators transform according to their local gauge covariance relations, reproduces perturbation theory in the weak coupling regime and provides a gauge independent description for dynamical chiral symmetry breaking and confinement has been a long-standing goal in physically relevant gauge theories such as quantum electrodynamics (QED) and quantum chromodynamics. In this paper, we demonstrate that the same simple and practical form of the vertex can achieve these objectives not only in 4-dimensional quenched QED but also in its 3-dimensional counterpart. Employing this convenient form of the vertex ansatz into the Schwinger-Dyson equation for the fermion propagator, we observe that it renders the critical coupling in 4-dimensional quenched QED markedly gauge independent in contrast with the bare vertex and improves on the well-known Curtis-Pennington construction. Furthermore, our proposal yields gauge independent order parameters for confinement and dynamical chiral symmetry breaking in 3-dimensional quenched QED.

  7. Precision electromagnetic structure of octet baryons in the chiral regime

    SciTech Connect

    Boinepalli, S.; Leinweber, D. B.; Williams, A. G.; Zanotti, J. M.; Zhang, J. B.

    2006-11-01

    The electromagnetic properties of the baryon octet are calculated in quenched QCD on a 20{sup 3}x40 lattice with a lattice spacing of 0.128 fm using the fat-link irrelevant clover (FLIC) fermion action. FLIC fermions enable simulations to be performed efficiently at pion masses as low as 300 MeV. By combining FLIC fermions with an improved-conserved vector current, we ensure that discretization errors occur only at O(a{sup 2}) while maintaining current conservation. Magnetic moments and electric and magnetic radii are extracted from the electric and magnetic form factors for each individual quark sector. From these, the corresponding baryon properties are constructed. Our results are compared with the predictions of quenched chiral perturbation theory. We detect substantial curvature and environment sensitivity of the quark contributions to electric charge radii and magnetic moments in the low quark-mass region.

  8. Vortex Crystals with Chiral Stripes in Itinerant Magnets

    NASA Astrophysics Data System (ADS)

    Ozawa, Ryo; Hayami, Satoru; Barros, Kipton; Chern, Gia-Wei; Motome, Yukitoshi; Batista, Cristian D.

    Noncoplanar spin textures in itinerant magnets are generating increasing interest because of the associated spin Berry phase, which induces a tremendous effective magnetic field on the itinerant electrons. Such noncoplanar spin textures appear frequently in itinerant magnets, even with vanishingly small spin-orbit coupling. We explore a generic condition for noncoplanar spin ordering, with a focus on ``frustration'' in itinerant magnets, that is characterized by multiple global maxima in the magnetic susceptibility. In a simple square Kondo lattice model, we find that a noncoplanar vortex-antivortex crystal with a one-dimensional modulation of spin scalar chirality becomes stable in a wide range of electron filling fraction. The unexpected result is obtained by careful analyses of higher-order terms in the perturbative expansion in terms of the Kondo exchange coupling and the degree of noncoplanarity, as well as numerical simulation based on the Langevin and stochastic Landau-Lifshitz-Gilbert dynamics with the kernel polynomial method.

  9. Chiral bosonic phases on the Haldane honeycomb lattice

    NASA Astrophysics Data System (ADS)

    Vasić, Ivana; Petrescu, Alexandru; Le Hur, Karyn; Hofstetter, Walter

    2015-03-01

    Recent experiments in ultracold atoms and photonic analogs have reported the implementation of artificial gauge fields in lattice systems, facilitating the realization of topological phases. Motivated by such advances, we investigate the Haldane honeycomb lattice tight-binding model, for bosons with local interactions at the average filling of one boson per site. We analyze the ground-state phase diagram and uncover three distinct phases: a uniform superfluid (SF), a chiral superfluid (CSF), and a plaquette Mott insulator with local current loops (PMI). Nearest-neighbor and next-nearest-neighbor currents distinguish CSF from SF, and the phase transition between them is first order. We apply bosonic dynamical mean-field theory and exact diagonalization to obtain the phase diagram, complementing numerics with calculations of excitation spectra in strong and weak coupling perturbation theory. The characteristic density fluctuations, current correlation functions, and excitation spectra are measurable in ultracold atom experiments.

  10. In-medium chiral SU (3) dynamics and hypernuclear structure

    NASA Astrophysics Data System (ADS)

    Finelli, P.; Kaiser, N.; Vretenar, D.; Weise, W.

    2007-12-01

    A previously introduced relativistic energy density functional, successfully applied to ordinary nuclei, is extended to hypernuclei. The density-dependent mean field and the spin-orbit potential are consistently calculated for a Λ hyperon in the nucleus using the SU (3) extension of in-medium chiral perturbation theory. The leading long range ΛN interaction arises from kaon-exchange and 2π-exchange with Σ hyperon in the intermediate state. Scalar and vector mean fields reflecting in-medium changes of the quark condensates are constrained by QCD sum rules. The model, applied to oxygen as a test case, describes spectroscopic data in good agreement with experiment. In particular, the smallness of the Λ spin-orbit interaction finds a natural explanation in terms of an almost complete cancellation between scalar-vector background contributions and long-range terms generated by two-pion exchange.

  11. Chiral plasmonic nanostructures on achiral nanopillars.

    PubMed

    Yeom, Bongjun; Zhang, Huanan; Zhang, Hui; Park, Jai Il; Kim, Kyoungwon; Govorov, Alexander O; Kotov, Nicholas A

    2013-11-13

    Chirality of plasmonic films can be strongly enhanced by three-dimensional (3D) out-of-plane geometries. The complexity of lithographic methods currently used to produce such structures and other methods utilizing chiral templates impose limitations on spectral windows of chiroptical effects, the size of substrates, and hence, further research on chiral plasmonics. Here we demonstrate 3D chiral plasmonic nanostructures (CPNs) with high optical activity in the visible spectral range based on initially achiral nanopillars from ZnO. We made asymmetric gold nanoshells on the nanopillars by vacuum evaporation at different inclination and rotation angles to achieve controlled symmetry breaking and obtained both left- and right-rotating isomers. The attribution of chiral optical effects to monolithic enantiomers made in this process was confirmed by theoretical calculations based on their geometry established from scanning electron microscope (SEM) images. The chirality of the nanoshells is retained upon the release from the substrate into a stable dispersion. Deviation of the incident angle of light from normal results in increase of polarization rotation and chiral g-factor as high as -0.3. This general approach for preparation of abiological nanoscale chiral materials can be extended to other out-of plane 3D nanostructures. The large area films made on achiral nanopillars are convenient for sensors, optical devices, and catalysis. PMID:24111695

  12. Orientation-Dependent Handedness and Chiral Design

    NASA Astrophysics Data System (ADS)

    Efrati, Efi; Irvine, William T. M.

    2014-01-01

    Chirality occupies a central role in fields ranging from biological self-assembly to the design of optical metamaterials. The definition of chirality, as given by Lord Kelvin, associates chirality with the lack of mirror symmetry: the inability to superpose an object on its mirror image. While this definition has guided the classification of chiral objects for over a century, the quantification of handed phenomena based on this definition has proven elusive, if not impossible, as manifest in the paradox of chiral connectedness. In this work, we put forward a quantification scheme in which the handedness of an object depends on the direction in which it is viewed. While consistent with familiar chiral notions, such as the right-hand rule, this framework allows objects to be simultaneously right and left handed. We demonstrate this orientation dependence in three different systems—a biomimetic elastic bilayer, a chiral propeller, and optical metamaterial—and find quantitative agreement with chirality pseudotensors whose form we explicitly compute. The use of this approach resolves the existing paradoxes and naturally enables the design of handed metamaterials from symmetry principles.

  13. Chiral gravity, log gravity, and extremal CFT

    SciTech Connect

    Maloney, Alexander; Song Wei; Strominger, Andrew

    2010-03-15

    We show that the linearization of all exact solutions of classical chiral gravity around the AdS{sub 3} vacuum have positive energy. Nonchiral and negative-energy solutions of the linearized equations are infrared divergent at second order, and so are removed from the spectrum. In other words, chirality is confined and the equations of motion have linearization instabilities. We prove that the only stationary, axially symmetric solutions of chiral gravity are BTZ black holes, which have positive energy. It is further shown that classical log gravity--the theory with logarithmically relaxed boundary conditions--has finite asymptotic symmetry generators but is not chiral and hence may be dual at the quantum level to a logarithmic conformal field theories (CFT). Moreover we show that log gravity contains chiral gravity within it as a decoupled charge superselection sector. We formally evaluate the Euclidean sum over geometries of chiral gravity and show that it gives precisely the holomorphic extremal CFT partition function. The modular invariance and integrality of the expansion coefficients of this partition function are consistent with the existence of an exact quantum theory of chiral gravity. We argue that the problem of quantizing chiral gravity is the holographic dual of the problem of constructing an extremal CFT, while quantizing log gravity is dual to the problem of constructing a logarithmic extremal CFT.

  14. Chiral THz metamaterial with tunable optical activity

    SciTech Connect

    Zhou, Jiangfeng; Taylor, Antoinette; O' Hara, John; Chowdhury, Roy; Zhao, Rongkuo; Soukoullis, Costas M

    2010-01-01

    Optical activity in chiral metamaterials is demonstrated in simulation and shows actively tunable giant polarization rotation at THz frequencies. Electric current distributions show that pure chirality is achieved by our bi-Iayer chiral metamaterial design. The chirality can be optically controlled by illumination with near-infrared light. Optical activity, occurring in chiral materials such as DNA, sugar and many other bio-molecules, is a phenomenon of great importance to many areas of science including molecular biology, analytical chemistry, optoelectronics and display applications. This phenomenon is well understood at an effective medium level as a magnetic/electric moment excited by the electric/magnetic field of the incident electromagnetic (EM) wave. Usually, natural chiral materials exhibit very weak optical activity e.g. a gyrotropic quartz crystal. The optical activity of chiral metamaterials, however, can be five orders of magnitude stronger. Chiral metamaterials are made of sub-wavelength resonators lacking symmetry planes. The asymmetry allows magnetic moments to be excited by the electric field of the incident EM wave and vice versa. Recently, chiral metamaterials have been demonstrated and lead to prospects in giant optical activity, circular dichroism, negative refraction and reversing the Casmir force. These fascinating optical properties require strong chirality, which may be designed through the microscopic structure of chiral metamaterials. However, these metamaterials have a fixed response function, defined by the geometric structuring, which limits their ability to manipulate EM waves. Active metamaterials realize dynamic control of response functions and have produced many influential applications such as ultra-fast switching devices, frequency and phase modulation and memory devices. Introducing active designs to chiral metamaterials will give additional freedom in controlling the optical activity, and therefore enable dynamic manipulation

  15. A liquid crystalline chirality balance for vapours

    NASA Astrophysics Data System (ADS)

    Ohzono, Takuya; Yamamoto, Takahiro; Fukuda, Jun-Ichi

    2014-04-01

    Chiral discrimination of vapours plays an important role in olfactory perception of biological systems and its realization by artificial sensors has been an intriguing challenge. Here, we report a simple method that tangibly visualizes the chirality of a diverse variety of molecules dissolved from vapours with high sensitivity, by making use of a structural change in a periodic microstructure of a nematic liquid crystal confined in open microchannels. This microstructure is accompanied by a topological line defect of a zigzag form with equal lengths of ‘zig’ and ‘zag.’ We find that a tiny amount of vapour of chiral molecules injected onto the liquid crystal induces the imbalance of ‘zig’ and ‘zag’ depending on its enantiomeric excess within a few seconds. Our liquid-crystal-based ‘chirality balance’ offers a simple, quick and versatile chirality-sensing/-screening method for gas-phase analysis (for example, for odours, environmental chemicals or drugs).

  16. Spontaneous Chiral Symmetry Breaking for Finite Systems.

    PubMed

    Boscheto, Emerson; López-Castillo, Alejandro

    2015-12-01

    Theoretical clues are desirable to help uncover the origin of bio-homochirality in life, as well as the mechanisms for the asymmetric production of functional chiral substances. Here, an open-to-matter reaction network based on a model proposed by Plasson et al. is studied. In the extended model, the statistical fluctuations lead the system to break chiral symmetry autonomously, that is, without any initial enantiomeric excess or external influence. In the stability diagrams, we observe regions of parameter space that correspond to racemic, homochiral, chiral oscillatory, and, to our knowledge, for the first time in a chiral model, chaotic regimes. The dependencies of the final concentrations of chiral substances on the parameters are determined analytically and discussed for both the racemic and homochiral regimes. PMID:26395183

  17. Enantioselective environmental toxicology of chiral pesticides.

    PubMed

    Ye, Jing; Zhao, Meirong; Niu, Lili; Liu, Weiping

    2015-03-16

    The enantioselective environmental toxic effect of chiral pesticides is becoming more important. As the industry develops, increasing numbers of chiral insecticides and herbicides will be introduced into use, potentially posing toxic effects on nontarget living beings. Chiral pesticides, including herbicides such as acylanilides, phenoxypropanoic acids, and imidazolinones, and insecticides such as synthetic pyrethroids, organophosphates, and DDT often behave enantioselectively during agricultural use. These compounds also pose unpredictable enantioselective ecological threats to nontarget living beings and/or humans, affecting the food chain and entire ecosystems. Thus, to investigate the enantioselective toxic effects of chiral insecticides and herbicides is necessary during environmental protection. The environmental toxicology of chiral pesticides, especially the findings obtained from studies conducted in our laboratory during the past 10 years, is reviewed. PMID:25643169

  18. Chiral Extensions of the Mssm

    NASA Astrophysics Data System (ADS)

    Ferretti, Gabriele; Karateev, Denis

    2013-03-01

    We present a class of extensions of the MSSM characterized by a fully chiral field content (no μ-terms) and no baryon or lepton number violating term in the superpotential due to an extra U‧(1) gauge symmetry. The minimal model consists of the usual matter sector with family dependent U‧(1) charges, six Higgs weak doublets, and three singlets required to give masses to the Higgsinos and cancel anomalies. We discuss its main features such as the tree level mass spectrum and the constraints on flavor changing processes.

  19. Chirality and the Quark Model

    SciTech Connect

    Eric S. Swanson; Adam P. Szczepaniak

    2002-06-07

    The relationship of the quark model to the known chiral properties of QCD is a long-standing problem in the interpretation of low energy QCD. In particular, how can the pion be viewed as both a collective Goldstone boson quasiparticle and as a valence quark antiquark bound state? A comparison of the many-body solution of a simplified model of QCD to the constituent quark model demonstrates that the quark model is sufficiently flexible to describe meson hyperfine splitting provided proper renormalization conditions and correct degrees of freedom are employed consistently.

  20. Nuclear forces and chiral theories

    SciTech Connect

    Friar, J.L. |

    1995-09-01

    Recent successes in ab initio calculations of light nuclei (A=2-6) will be reviewed and correlated with the dynamical consequences of chiral symmetry. The tractability of nuclear physics evinced by these results is evidence for that symmetry. The relative importance of three-nucleon forces, four-nucleon forces, multi-pion exchanges, and relativistic corrections will be discussed in the context of effective field theories and dimensional power counting. Isospin violation in the nuclear force will also be discussed in this context.

  1. Flatbands under Correlated Perturbations

    NASA Astrophysics Data System (ADS)

    Bodyfelt, Joshua D.; Leykam, Daniel; Danieli, Carlo; Yu, Xiaoquan; Flach, Sergej

    2014-12-01

    Flatband networks are characterized by the coexistence of dispersive and flatbands. Flatbands (FBs) are generated by compact localized eigenstates (CLSs) with local network symmetries, based on destructive interference. Correlated disorder and quasiperiodic potentials hybridize CLSs without additional renormalization, yet with surprising consequences: (i) states are expelled from the FB energy EFB, (ii) the localization length of eigenstates vanishes as ξ ˜1 /ln (E -EFB) , (iii) the density of states diverges logarithmically (particle-hole symmetry) and algebraically (no particle-hole symmetry), and (iv) mobility edge curves show algebraic singularities at EFB . Our analytical results are based on perturbative expansions of the CLSs and supported by numerical data in one and two lattice dimensions.

  2. Flatbands under correlated perturbations.

    PubMed

    Bodyfelt, Joshua D; Leykam, Daniel; Danieli, Carlo; Yu, Xiaoquan; Flach, Sergej

    2014-12-01

    Flatband networks are characterized by the coexistence of dispersive and flatbands. Flatbands (FBs) are generated by compact localized eigenstates (CLSs) with local network symmetries, based on destructive interference. Correlated disorder and quasiperiodic potentials hybridize CLSs without additional renormalization, yet with surprising consequences: (i) states are expelled from the FB energy E_{FB}, (ii) the localization length of eigenstates vanishes as ξ∼1/ln(E-E_{FB}), (iii) the density of states diverges logarithmically (particle-hole symmetry) and algebraically (no particle-hole symmetry), and (iv) mobility edge curves show algebraic singularities at E_{FB}. Our analytical results are based on perturbative expansions of the CLSs and supported by numerical data in one and two lattice dimensions. PMID:25526142

  3. Discrete Newtonian cosmology: perturbations

    NASA Astrophysics Data System (ADS)

    Ellis, George F. R.; Gibbons, Gary W.

    2015-03-01

    In a previous paper (Gibbons and Ellis 2014 Discrete Newtonian cosmology Class. Quantum Grav. 31 025003), we showed how a finite system of discrete particles interacting with each other via Newtonian gravitational attraction would lead to precisely the same dynamical equations for homothetic motion as in the case of the pressure-free Friedmann-Lemaître-Robertson-Walker cosmological models of general relativity theory, provided the distribution of particles obeys the central configuration equation. In this paper we show that one can obtain perturbed such Newtonian solutions that give the same linearized structure growth equations as in the general relativity case. We also obtain the Dmitriev-Zel’dovich equations for subsystems in this discrete gravitational model, and show how it leads to the conclusion that voids have an apparent negative mass.

  4. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Krämer, Markus

    2016-05-01

    At the COMPASS experiment at CERN, pion-photon reactions are investigated using the Primakoff effect, where high-energetic pions react with the quasi-real photons surrounding the target nuclei. The production of a single hard photon in such a pion scattering, at lowest momentum transfer to the nucleus, is related to pion Compton scattering. Studying the energy distribution of the outgoing photons, the pion polarizability can be extracted. In addition to the measurement with a pion beam, control measurements with a muon beam allow us to estimate the systematics. The COMPASS result is in tension with earlier dedicated measurements and rather in agreement with the theoretical expectation from chiral perturbation theory. Based on the same data set, reactions with neutral and charged pions in the final state are studied. At low invariant mass of the pion-photon system, these reactions are governed by chiral dynamics. Using partial-wave analysis techniques, the absolute cross sections for the production of π-π+π- and π-π0π0 states from π-γ interactions are measured and compared to predictions from chiral perturbation theory. At higher pion-photon masses, the production of 3π resonances is studied with the focus on their radiative couplings.

  5. Synthesis and characterization of mixed ligand chiral nanoclusters.

    PubMed

    Guven, Zekiye P; Ustbas, Burcin; Harkness, Kellen M; Coskun, Hikmet; Joshi, Chakra P; Besong, Tabot M D; Stellacci, Francesco; Bakr, Osman M; Akbulut, Ozge

    2016-07-28

    Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. PMID:27362744

  6. Perturbed effects at radiation physics

    NASA Astrophysics Data System (ADS)

    Külahcı, Fatih; Şen, Zekâi

    2013-09-01

    Perturbation methodology is applied in order to assess the linear attenuation coefficient, mass attenuation coefficient and cross-section behavior with random components in the basic variables such as the radiation amounts frequently used in the radiation physics and chemistry. Additionally, layer attenuation coefficient (LAC) and perturbed LAC (PLAC) are proposed for different contact materials. Perturbation methodology provides opportunity to obtain results with random deviations from the average behavior of each variable that enters the whole mathematical expression. The basic photon intensity variation expression as the inverse exponential power law (as Beer-Lambert's law) is adopted for perturbation method exposition. Perturbed results are presented not only in terms of the mean but additionally the standard deviation and the correlation coefficients. Such perturbation expressions provide one to assess small random variability in basic variables.

  7. Chiral magnetism at oxide interfaces

    NASA Astrophysics Data System (ADS)

    Randeria, Mohit

    2014-03-01

    There are tantalizing hints of magnetism at the n-type LaAlO3/SrTiO3 interface, but the experimental evidence remains controversial in view of some of the differences between different samples and probes. I will argue that if magnetism exists at interfaces, symmetry arguments imply chiral interactions that lead to a spiral ground state in zero external field and skyrmion crystals for H ≠ 0 . I will next present a microscopic model that provides a possible mechanism for the formation of local moments. I will show that the coupling of these moments to itinerant electrons leads to ferromagnetic double exchange together with Dzyaloshinskii-Moriya (DM) interactions and an easy-plane ``compass'' anisotropy, which arise from Rashba spin-orbit coupling (SOC) due to the lack of inversion symmetry at the interface. The compass term, often ignored in the literature on chiral magnetism, is shown to play a crucial role in determining the magnetic ground state. I will compare our results with existing torque magnetometry data on LAO/STO and try to reconcile it with scanning SQUID magnetometry. Finally, I will present the phase diagram in a field and show that easy-plane anisotropy stabilizes an unexpectedly large skyrmion crystal phase and describe its properties. (Work done in collaboration with Sumilan Banerjee, Onur Erten, Daniel Kestner and James Rowland). Supported by DOE-BES DE-SC0005035, NSF-DMR-1006532 and NSF MRSEC DMR-0820414.

  8. Nucleic acids, proteins, and chirality

    NASA Technical Reports Server (NTRS)

    Usher, D. A.; Profy, A. T.; Walstrum, S. A.; Needels, M. C.; Bulack, S. C.; Lo, K. M.

    1984-01-01

    The present investigation is concerned with experimental results related, in one case, to the chirality of nucleotides, and, in another case, to the possibility of a link between the chirality of nucleic acids, and that of peptides. It has been found that aminoacylation of the 'internal' hydroxyl group of a dinucleoside monophosphate can occur stereoselectively. However, this reaction has not yet been made a part of a working peptide synthesis scheme. The formation and cleavage of oligonucleotides is considered. In the event of the formation of a helical complex between the oligonucleotide and the polymer, 1-prime,5-prime-bonds in the oligomer are found to become more resistant towards cleavage. The conditions required for peptide bond formation are examined, taking into account the known structures of RNA and possible mechanisms for prebiotic peptide bond formation. The possibility is considered that the 2-prime,5-prime-internucleotide linkage could have played an important part in the early days of biological peptide synthesis.

  9. Cosmological perturbations in massive bigravity

    SciTech Connect

    Lagos, Macarena; Ferreira, Pedro G. E-mail: p.ferreira1@physics.ox.ac.uk

    2014-12-01

    We present a comprehensive analysis of classical scalar, vector and tensor cosmological perturbations in ghost-free massive bigravity. In particular, we find the full evolution equations and analytical solutions in a wide range of regimes. We show that there are viable cosmological backgrounds but, as has been found in the literature, these models generally have exponential instabilities in linear perturbation theory. However, it is possible to find stable scalar cosmological perturbations for a very particular choice of parameters. For this stable subclass of models we find that vector and tensor perturbations have growing solutions. We argue that special initial conditions are needed for tensor modes in order to have a viable model.

  10. Canonical density matrix perturbation theory.

    PubMed

    Niklasson, Anders M N; Cawkwell, M J; Rubensson, Emanuel H; Rudberg, Elias

    2015-12-01

    Density matrix perturbation theory [Niklasson and Challacombe, Phys. Rev. Lett. 92, 193001 (2004)] is generalized to canonical (NVT) free-energy ensembles in tight-binding, Hartree-Fock, or Kohn-Sham density-functional theory. The canonical density matrix perturbation theory can be used to calculate temperature-dependent response properties from the coupled perturbed self-consistent field equations as in density-functional perturbation theory. The method is well suited to take advantage of sparse matrix algebra to achieve linear scaling complexity in the computational cost as a function of system size for sufficiently large nonmetallic materials and metals at high temperatures. PMID:26764847

  11. Hierarchical chirality transfer in the growth of Towel Gourd tendrils

    NASA Astrophysics Data System (ADS)

    Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua

    2013-10-01

    Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties.

  12. Hierarchical chirality transfer in the growth of Towel Gourd tendrils.

    PubMed

    Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua

    2013-01-01

    Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties. PMID:24173107

  13. Atroposelective Synthesis of Axially Chiral Thiohydantoin Derivatives.

    PubMed

    Sarigul, Sevgi; Dogan, Ilknur

    2016-07-15

    Nonracemic axially chiral thiohydantoins were synthesized atroposelectively by the reaction of o-aryl isothiocyanates with amino acid ester salts in the presence of triethylamine (TEA). The synthesis of the nonaxially chiral derivatives, however, gave thiohydantoins racemized at C-5 of the heterocyclic ring. The micropreparatively resolved enantiomers of the nonaxially chiral derivatives from the racemic products were found to be optically stable under neutral conditions. On formation of the 5-methyl-3-arylthiohydantoin ring, bulky o-aryl substituents at N3 were found to suppress the C-5 racemization and in this way enabled the transfer of chirality from the α-amino acid to the products. The corresponding 5-isopropylthiohydantoins turned out to be more prone to racemization at C-5 during the ring formation. The isomer compositions of the synthesized axially chiral thiohydantoins have been determined through HPLC analyses with chiral stationary phases. In most cases a high prevalence of the P isomers over the M isomers has been obtained. The barriers to rotation determined around the Nsp(2)-Caryl chiral axis were found to be dependent upon the size of the o-halo aryl substituents. PMID:27322739

  14. Chirally symmetric but confining dense, cold matter

    SciTech Connect

    Glozman, L. Ya.; Wagenbrunn, R. F.

    2008-03-01

    The folklore tradition about the QCD phase diagram is that at the chiral restoration phase transition at finite density hadrons are deconfined and there appears the quark matter. We address this question within the only known exactly solvable confining and chirally symmetric model. It is postulated within this model that there exists linear Coulomb-like confining interaction. The chiral symmetry breaking and the quark Green function are obtained from the Schwinger-Dyson (gap) equation while the color-singlet meson spectrum results from the Bethe-Salpeter equation. We solve this model at T=0 and finite chemical potential {mu} and obtain a clear chiral restoration phase transition at the critical value {mu}{sub cr}. Below this value the spectrum is similar to the previously obtained one at {mu}=0. At {mu}>{mu}{sub cr} the quarks are still confined and the physical spectrum consists of bound states which are arranged into a complete set of exact chiral multiplets. This explicitly demonstrates that a chirally symmetric matter consisting of confined but chirally symmetric hadrons at finite chemical potential is also possible in QCD. If so, there must be nontrivial implications for astrophysics.

  15. Chirally symmetric but confining dense, cold matter

    NASA Astrophysics Data System (ADS)

    Glozman, L. Ya.; Wagenbrunn, R. F.

    2008-03-01

    The folklore tradition about the QCD phase diagram is that at the chiral restoration phase transition at finite density hadrons are deconfined and there appears the quark matter. We address this question within the only known exactly solvable confining and chirally symmetric model. It is postulated within this model that there exists linear Coulomb-like confining interaction. The chiral symmetry breaking and the quark Green function are obtained from the Schwinger-Dyson (gap) equation while the color-singlet meson spectrum results from the Bethe-Salpeter equation. We solve this model at T=0 and finite chemical potential μ and obtain a clear chiral restoration phase transition at the critical value μcr. Below this value the spectrum is similar to the previously obtained one at μ=0. At μ>μcr the quarks are still confined and the physical spectrum consists of bound states which are arranged into a complete set of exact chiral multiplets. This explicitly demonstrates that a chirally symmetric matter consisting of confined but chirally symmetric hadrons at finite chemical potential is also possible in QCD. If so, there must be nontrivial implications for astrophysics.

  16. Broken chiral symmetry on a null plane

    SciTech Connect

    Beane, Silas R.

    2013-10-15

    On a null-plane (light-front), all effects of spontaneous chiral symmetry breaking are contained in the three Hamiltonians (dynamical Poincaré generators), while the vacuum state is a chiral invariant. This property is used to give a general proof of Goldstone’s theorem on a null-plane. Focusing on null-plane QCD with N degenerate flavors of light quarks, the chiral-symmetry breaking Hamiltonians are obtained, and the role of vacuum condensates is clarified. In particular, the null-plane Gell-Mann–Oakes–Renner formula is derived, and a general prescription is given for mapping all chiral-symmetry breaking QCD condensates to chiral-symmetry conserving null-plane QCD condensates. The utility of the null-plane description lies in the operator algebra that mixes the null-plane Hamiltonians and the chiral symmetry charges. It is demonstrated that in a certain non-trivial limit, the null-plane operator algebra reduces to the symmetry group SU(2N) of the constituent quark model. -- Highlights: •A proof (the first) of Goldstone’s theorem on a null-plane is given. •The puzzle of chiral-symmetry breaking condensates on a null-plane is solved. •The emergence of spin-flavor symmetries in null-plane QCD is demonstrated.

  17. Chiral Alfvén Wave in Anomalous Hydrodynamics.

    PubMed

    Yamamoto, Naoki

    2015-10-01

    We study the hydrodynamic regime of chiral plasmas at high temperature. We find a new type of gapless collective excitation induced by chiral effects in an external magnetic field. This is a transverse wave, and it is present even in incompressible fluids, unlike the chiral magnetic and chiral vortical waves. The velocity is proportional to the coefficient of the gravitational anomaly. We briefly discuss the possible relevance of this "chiral Alfvén wave" in physical systems. PMID:26551804

  18. Hidden chirality in superficially racemic patchy silver films.

    PubMed

    Larsen, George K; He, Yizhuo; Ingram, Whitney; Zhao, Yiping

    2013-01-01

    Chiral patchy particle films where morphological enantiomers exist in equal proportion are found to have significant circular dichroism. It is determined that the rotation direction during glancing angle deposition breaks the racemic symmetry, resulting in a distribution of material which enhances the chirality of one set of enantiomers relative to the other. Microscopic analysis and geometric chirality calculations reveal that the chirality of the bulk film results from incomplete cancellations of even stronger local chiralities. PMID:24256449

  19. Elastic waves in structurally chiral composites

    SciTech Connect

    Yang, Shiuhkuang.

    1990-01-01

    Elastic wave propagation through structurally chiral (handed) media was studied. The primary objectives are to construct structurally chiral composites and to characterize their properties. Structurally chiral composites are constructed by stacking identical uniaxial plates, whose consecutive symmetric axes describe either a right- or a left-handed spiral. A matrix representation method is used to solve the elastic wave propagation in such layered composites. Numerical computation of the plane wave reflection and transmission characteristics for chiral arrangements are compared with those for the non-chiral one. It is concluded that the co-polarized characteristics are unaffected by the structural chirality, while the cross-polarized reflected and transmitted fields are greatly influenced by it. Numerical modeling is also applied for the real samples. The polarization ellipse of the transmitted field of each sample is calculated. To verify the form chirality, four glass-reinforced chiral and non-chiral composite samples are made from helix tape, molded, debulked, and cured individually under identical temperature and pressure histories. The spiral composites are characterized using shear and longitudinal wave transducers in ultrasonic experiments. Both the material properties and the polarization ellipse of the transmitted field of each sample are measured. It is proved conclusively that left and right handedness in the microstructures of a material rotates the plane of polarization of a propagating shear wave in the opposite directions. Thus it is now possible to say that by reducing the length scale of the handed microstructures tone more appropriate to its propagating wavelength, a medium is obtained that gives rise to effects similar to optical radar and optical dichroism.

  20. Extreme optical chirality of plasmonic nanohole arrays due to chiral Fano resonance

    NASA Astrophysics Data System (ADS)

    Kondratov, A. V.; Gorkunov, M. V.; Darinskii, A. N.; Gainutdinov, R. V.; Rogov, O. Y.; Ezhov, A. A.; Artemov, V. V.

    2016-05-01

    We study the physical origin of extreme optical chirality of subwavelength arrays of chiral holes in metal. We reconstruct the nanoscale relief of the hole arrays by the atomic-force microscopy and post-process the data to acquire an average unit-cell shape clear of noise and defects. For this shape, we perform the electromagnetic finite difference time domain simulations that reproduce all important features observed by the light-transmission experiments, including the notably strong circular dichroism and optical activity covering the whole range of possible values. To interpret the simulation results, we develop a chiral coupled-mode model which yields analytical expressions that fit accurately the numerical data in a broad wavelength range. Our conclusions undoubtedly link the extreme optical chirality to the plasmon resonances of chiral holes and the associated chiral Fano-type transmission resonance.

  1. Determination of the chiral couplings L{sub 10} and C{sub 87} from semileptonic {tau} decays

    SciTech Connect

    Gonzalez-Alonso, Martin; Pich, Antonio; Prades, Joaquim

    2008-12-01

    Using recent precise hadronic {tau}-decay data on the V-A spectral function, and general properties of QCD such as analyticity, the operator product expansion, and chiral perturbation theory, we get accurate values for the QCD chiral order parameters L{sub 10}{sup r}(M{sub {rho}}) and C{sub 87}{sup r}(M{sub {rho}}). These two low-energy constants appear at order p{sup 4} and p{sup 6}, respectively, in the chiral perturbation theory expansion of the V-A correlator. At order p{sup 4} we obtain L{sub 10}{sup r}(M{sub {rho}})=-(5.22{+-}0.06)x10{sup -3}. Including in the analysis the two-loop (order p{sup 6}) contributions, we get L{sub 10}{sup r}(M{sub {rho}})=-(4.06{+-}0.39)x10{sup -3} and C{sub 87}{sup r}(M{sub {rho}})=(4.89{+-}0.19)x10{sup -3} GeV{sup -2}. In the SU(2) chiral effective theory, the corresponding low-energy coupling takes the value l{sub 5}=13.30{+-}0.11 at order p{sup 4}, and l{sub 5}=12.24{+-}0.21 at order p{sup 6}.

  2. Dirac form factors and electric charge radii of baryons in the combined chiral and 1 /Nc expansions

    NASA Astrophysics Data System (ADS)

    Flores-Mendieta, Rubén; Rivera-Ruiz, Mayra Alejandra

    2015-11-01

    The baryon Dirac form factor is computed at one-loop order in large-Nc baryon chiral perturbation theory, where Nc is the number of color charges. Loop graphs with octet and decuplet intermediate states are systematically incorporated into the analysis and the effects of the decuplet-octet mass difference are accounted for. There are large-Nc cancellations between different one-loop graphs as a consequence of the large-Nc spin-flavor symmetry of QCD baryons. As a byproduct, the mean-square charge radius is also computed through a detailed numerical analysis. The predictions of large-Nc baryon chiral perturbation theory are in very good agreement both with the expectations from the 1 /Nc expansion and with the experimental data.

  3. The Macromolecular Route to Chiral Amplification.

    PubMed

    Green; Park; Sato; Teramoto; Lifson; Selinger; Selinger

    1999-11-01

    Cooperative phenomena, described by one-dimensional statistical physical methods, are observed between the enantiomeric characteristics of monomeric materials and the polymers they produce. The effect of minute energies associated with this amplified chirality, although currently not interpretable, can be easily measured. Nonlinear relationships between enantiomeric excess or enantiomeric content and polymer properties may offer the possibility of developing chiral catalysts and chiral chromatographic materials in which the burden of large enantiomeric excess or content may be considerably alleviated. New approaches to information and sensor technology may become possible. PMID:10556885

  4. The convoluted evolution of snail chirality

    NASA Astrophysics Data System (ADS)

    Schilthuizen, M.; Davison, A.

    2005-11-01

    The direction that a snail (Mollusca: Gastropoda) coils, whether dextral (right-handed) or sinistral (left-handed), originates in early development but is most easily observed in the shell form of the adult. Here, we review recent progress in understanding snail chirality from genetic, developmental and ecological perspectives. In the few species that have been characterized, chirality is determined by a single genetic locus with delayed inheritance, which means that the genotype is expressed in the mother's offspring. Although research lags behind the studies of asymmetry in the mouse and nematode, attempts to isolate the loci involved in snail chirality have begun, with the final aim of understanding how the axis of left-right asymmetry is established. In nature, most snail taxa (>90%) are dextral, but sinistrality is known from mutant individuals, populations within dextral species, entirely sinistral species, genera and even families. Ordinarily, it is expected that strong frequency-dependent selection should act against the establishment of new chiral types because the chiral minority have difficulty finding a suitable mating partner (their genitalia are on the ‘wrong’ side). Mixed populations should therefore not persist. Intriguingly, however, a very few land snail species, notably the subgenus Amphidromus sensu stricto, not only appear to mate randomly between different chiral types, but also have a stable, within-population chiral dimorphism, which suggests the involvement of a balancing factor. At the other end of the spectrum, in many species, different chiral types are unable to mate and so could be reproductively isolated from one another. However, while empirical data, models and simulations have indicated that chiral reversal must sometimes occur, it is rarely likely to lead to so-called ‘single-gene’ speciation. Nevertheless, chiral reversal could still be a contributing factor to speciation (or to divergence after speciation) when

  5. New chiral zinc complexes: synthesis, structure, and induction of axial chirality.

    PubMed

    Degenbeck, Helmut; Felten, Anne-Sophie; Escudero-Adán, Eduardo C; Benet-Buchholz, Jordi; Di Bari, Lorenzo; Pescitelli, Gennaro; Vidal-Ferran, Anton

    2012-08-20

    We describe an efficient methodology for the preparation of new chiral zinc complexes by assembling dynamically racemic biphenol derivatives and chiral 1,2-diamines with suitable zinc(II) precursors. Mononuclear and dinuclear zinc(II) complexes were formed from differently substituted biphenols. The solid-state and solution structural characterization of the resulting compounds allowed us to demonstrate a preferential sense of induced axial chirality for mononuclear complexes, a phenomenon that was not observed for the dinuclear ones. PMID:22862880

  6. Pion- and strangeness-baryon σ terms in the extended chiral constituent quark model

    NASA Astrophysics Data System (ADS)

    An, C. S.; Saghai, B.

    2015-07-01

    Within an extended chiral constituent quark formalism, we investigate contributions from all possible five-quark components in the octet baryons to the pion-baryon (σπ B) and strangeness-baryon (σs B) sigma terms: B ≡N ,Λ ,Σ ,Ξ . The probabilities of the quark-antiquark components in the ground-state baryon octet wave functions are calculated by taking the baryons to be admixtures of three- and five-quark components, with the relevant transitions handled via the 3P0 mechanism. Predictions for σπ B and σs B obtained by using input parameters taken from the literature are reported. Our results turn out to be, in general, consistent with the findings via lattice QCD and chiral perturbation theory.

  7. Chiral effective-field theory in the Delta(1232) region : II. radiative pion photoproduction

    SciTech Connect

    Vladimir Pascalutsa; Marc Vanderhaeghen

    2007-10-12

    We present a theoretical study of the radiative pion photoproduction on the nucleon ($\\gamma N \\rightarrow \\pi N \\gamma'$) in the $\\De$-resonance region, with the aim to determine the magnetic dipole moment (MDM) of the $\\Delta^+(1232)$. The study is done within the framework of chiral effective-field theory where the expansion is performed (to next-to-leading order) in the $\\delta$ power-counting scheme which is an extension of chiral perturbation theory to the $\\Delta$-resonance energy region. We present in detail the results for the absorptive part of the $\\Delta$ MDM, as well as a sensitivity study for the radiative pion photoproduction observables on the real part of the $\\Delta$ MDM. We find that an asymmetry for circular polarization of the photon beam may provide a model-independent way to measure the $\\Delta$ MDM.

  8. Low-energy neutron-deuteron reactions with N 3 LO chiral forces

    NASA Astrophysics Data System (ADS)

    Golak, J.; Skibiński, R.; Topolnicki, K.; Witała, H.; Epelbaum, E.; Krebs, H.; Kamada, H.; Meißner, Ulf-G.; Bernard, V.; Maris, P.; Vary, J.; Binder, S.; Calci, A.; Hebeler, K.; Langhammer, J.; Roth, R.; Nogga, A.; Liebig, S.; Minossi, D.

    2014-11-01

    We solve three-nucleon Faddeev equations with nucleon-nucleon and three-nucleon forces derived consistently in the framework of chiral perturbation theory at next-to-next-to-next-to-leading order in the chiral expansion. In this first investigation we include only matrix elements of the three-nucleon force for partial waves with the total two-nucleon (three-nucleon) angular momenta up to 3 (5/2). Low-energy neutron-deuteron elastic scattering and deuteron breakup reaction are studied. Emphasis is put on A y puzzle in elastic scattering and cross sections in symmetric-space-star and neutron-neutron quasi-free-scattering breakup configurations, for which large discrepancies between data and theory have been reported.

  9. Effective chiral description of an exciton-polariton superfluid in one and two dimensions

    NASA Astrophysics Data System (ADS)

    Kulkarni, Manas; Kolmakov, German

    There has been remarkable experiments recently on capturing hydrodynamic features of exciton-polariton condensates in optical microcavities which have potential implications for quantum and optical computing and information technologies. We present an effective chiral description for such one and two dimensional systems. This description captures the fingerprints of hydrodynamics, namely, nonlinearity, dispersion and dissipation. The resulting chiral equation for the condensate perturbation wave dynamics is found to be of the generalized-KdV-type. We describe the phenomenon of polariton shock waves, solitons and defects in such systems. Our mapping is expected to have broad implications for other systems and can further help one in engineering a delicate balance between the pump and damping to produce stable optical signals propagating in polariton circuits.

  10. Controlled chiral supramolecular assemblies of water soluble achiral porphyrins induced by chiral counterions.

    PubMed

    Rananaware, Anushri; La, Duong Duc; Al Kobaisi, Mohammad; Bhosale, Rajesh S; Bhosale, Sidhanath V; Bhosale, Sheshanath V

    2016-08-11

    We demonstrate a controlled chiral supramolecular assembly of achiral porphyrins induced by chiral d- and l-arginine (Arg) in water. Induction of chirality was confirmed by circular dichroism. TEM and SEM images confirm that these twisted ribbons are indeed formed by right- and left-handed helices with d- and l-Arg in water, respectively. The chiral assembly pathways described here are hierarchical, opening up the possibility that simple changes on microscopic (nm) length scales can be used to control structures on macroscopic (mm) length scales. PMID:27464524

  11. Chiral supramolecular polymers consisting of planar-chiral pillar[5]arene enantiomers.

    PubMed

    Ogoshi, Tomoki; Furuta, Takuya; Yamagishi, Tada-Aki

    2016-09-14

    Supramolecular polymers with diverse chiralities were constructed by supramolecular polymerization of planar-chiral host-guest conjugates in pS and pR forms. Hetero-chiral supramolecular polymerization using a racemic mixture of host-guest conjugates with pS and pR forms afforded a supramolecular polymer with a larger hydrodynamic radius than that obtained through homo-chiral supramolecular polymerization of host-guest conjugates with either pS or pR forms alone. PMID:27510359

  12. Characteristics of surface plasmon polaritons in a dielectrically chiral-metal-chiral waveguiding structure.

    PubMed

    Zhang, Qiang; Li, Junqing

    2016-07-15

    We demonstrate theoretically the characteristics of surface plasmon polaritons (SPPs) with an asymmetric chiral-metal-chiral (CMC) waveguide structure, under realistic frequency dependencies of the permittivity and chirality parameters. Generalized dispersion relations are derived which can be applied to the nonchiral SPPs. We find that the existence of cutoffs in different modes for the CMC structures may facilitate the design of mode-selective surface plasmon waveguides. CMC-SPPs also exhibit an interesting dependence of the polarization on the chiral strength. These novel characteristics of CMC-SPPs provide new possibilities for the design of more compact nanophotonic devices. PMID:27420505

  13. Resumming the string perturbation series

    NASA Astrophysics Data System (ADS)

    Grassi, Alba; Mariño, Marcos; Zakany, Szabolcs

    2015-05-01

    We use the AdS/CFT correspondence to study the resummation of a perturbative genus expansion appearing in the type II superstring dual of ABJM theory. Although the series is Borel summable, its Borel resummation does not agree with the exact non-perturbative answer due to the presence of complex instantons. The same type of behavior appears in the WKB quantization of the quartic oscillator in Quantum Mechanics, which we analyze in detail as a toy model for the string perturbation series. We conclude that, in these examples, Borel summability is not enough for extracting non-perturbative information, due to non-perturbative effects associated to complex instantons. We also analyze the resummation of the genus expansion for topological string theory on local , which is closely related to ABJM theory. In this case, the non-perturbative answer involves membrane instantons computed by the refined topological string, which are crucial to produce a well-defined result. We give evidence that the Borel resummation of the perturbative series requires such a non-perturbative sector.

  14. Pion and Kaon Masses and Pion Form Factors from Dynamical Chiral-Symmetry Breaking with Light Constituent Quarks

    SciTech Connect

    Scadron, Michael D.; Kleefeld, Frieder; Rupp, George

    2007-02-27

    Light constituent quark masses and the corresponding dynamical quark masses are determined by data, the quark-level linear {sigma} model, and infrared QCD. This allows to define effective nonstrange and strange current quark masses, which reproduce the experimental pion and kaon masses very accurately, by simple additivity. In contrast, the usual nonstrange and strange current quarks employed by the Particle Data Group and Chiral Perturbation Theory do not allow a straightforward quantitative explanation of the pion and kaon masses.

  15. Sea quark transverse momentum distributions and dynamical chiral symmetry breaking

    SciTech Connect

    Schweitzer, Peter; Strikman, Mark; Weiss, Christian

    2014-01-01

    Recent theoretical studies have provided new insight into the intrinsic transverse momentum distributions of valence and sea quarks in the nucleon at a low scale. The valence quark transverse momentum distributions (q - qbar) are governed by the nucleon's inverse hadronic size R{sup -1} ~ 0.2 GeV and drop steeply at large p{sub T}. The sea quark distributions (qbar) are in large part generated by non-perturbative chiral-symmetry breaking interactions and extend up to the scale rho{sup -1} ~ 0.6 GeV. These findings have many implications for modeling the initial conditions of perturbative QCD evolution of TMD distributions (starting scale, shape of p{sub T}. distributions, coordinate-space correlation functions). The qualitative difference between valence and sea quark intrinsic p{sub T}. distributions could be observed experimentally, by comparing the transverse momentum distributions of selected hadrons in semi-inclusive deep-inelastic scattering, or those of dileptons produced in pp and pbar-p scattering.

  16. Magnetohydrodynamics of chiral relativistic fluids

    NASA Astrophysics Data System (ADS)

    Boyarsky, Alexey; Fröhlich, Jürg; Ruchayskiy, Oleg

    2015-08-01

    We study the dynamics of a plasma of charged relativistic fermions at very high temperature T ≫m , where m is the fermion mass, coupled to the electromagnetic field. In particular, we derive a magnetohydrodynamical description of the evolution of such a plasma. We show that, compared to conventional magnetohydronamics (MHD) for a plasma of nonrelativistic particles, the hydrodynamical description of the relativistic plasma involves new degrees of freedom described by a pseudoscalar field originating in a local asymmetry in the densities of left-handed and right-handed fermions. This field can be interpreted as an effective axion field. Taking into account the chiral anomaly we present dynamical equations for the evolution of this field, as well as of other fields appearing in the MHD description of the plasma. Due to its nonlinear coupling to helical magnetic fields, the axion field significantly affects the dynamics of a magnetized plasma and can give rise to a novel type of inverse cascade.

  17. {Lambda}* hypernuclei with chiral dynamics

    SciTech Connect

    Uchino, Toshitaka; Hyodo, Tetsuo; Oka, Makoto

    2011-10-21

    As a strangeness S = -1 and baryon number B = 2 system, the two-body bound state of {Lambda}* = {Lambda}(1405) and a nucleon is studied. To solve the {Lambda}*N system, we construct the {Lambda}*N potential by extending the Juelich model with couplings estimated in the chiral unitary approach. We have the {Lambda}*N quasi-bound state with the mass, M{sub {Lambda}}*N{approx}2366 MeV which is shallowly bound with the binding energy B{approx}9 MeV in terms of the K-barNN system. Decay width of the fall apart process, where the {Lambda}*N resonance decays to {pi}{Sigma}N with a nucleon being as a spectator, is estimated to be {Gamma}{sub F.A}{approx}49 MeV.

  18. Deformations in chiral liquid crystals

    NASA Astrophysics Data System (ADS)

    Shibaev, Petr; Reddy, Kathryn; Bateman, Daniel; Iljin, Andrey

    2014-03-01

    Deformations and their relaxation in chiral liquid crystals are studied experimentally and theoretically in planar geometry for liquid crystalline mixtures of varying viscosities. It is shown by both methods that shear deformation in liquid crystals results in the inclination and extension of cholesteric helix in samples with high viscosity. Stretching deformation results in shrinking cholesteric helix. This leads to a possibility of detecting deformations on a nanometer scale by observing changes in selective reflection spectra. Theoretical model takes into account elastic strain of physical network formed by the entanglements between components of liquid crystalline mixture, viscosity of the matrix and elasticity of the liquid crystalline subsystem. This allows to model mechanical response of the matrix with different viscosities to stretching and shear of various amplitudes. It is shown that relaxation of the cholesteric helix takes much shorter time than mechanical relaxation of the mixtures. The model perfectly agrees with experimental data. The model is compared with theoretical model describing behavior of elastomers.

  19. On dark energy isocurvature perturbation

    SciTech Connect

    Liu, Jie; Zhang, Xinmin; Li, Mingzhe E-mail: limz@nju.edu.cn

    2011-06-01

    Determining the equation of state of dark energy with astronomical observations is crucially important to understand the nature of dark energy. In performing a likelihood analysis of the data, especially of the cosmic microwave background and large scale structure data the dark energy perturbations have to be taken into account both for theoretical consistency and for numerical accuracy. Usually, one assumes in the global fitting analysis that the dark energy perturbations are adiabatic. In this paper, we study the dark energy isocurvature perturbation analytically and discuss its implications for the cosmic microwave background radiation and large scale structure. Furthermore, with the current astronomical observational data and by employing Markov Chain Monte Carlo method, we perform a global analysis of cosmological parameters assuming general initial conditions for the dark energy perturbations. The results show that the dark energy isocurvature perturbations are very weakly constrained and that purely adiabatic initial conditions are consistent with the data.

  20. Computing singularities of perturbation series

    SciTech Connect

    Kvaal, Simen; Jarlebring, Elias; Michiels, Wim

    2011-03-15

    Many properties of current ab initio approaches to the quantum many-body problem, both perturbational and otherwise, are related to the singularity structure of the Rayleigh-Schroedinger perturbation series. A numerical procedure is presented that in principle computes the complete set of singularities, including the dominant singularity which limits the radius of convergence. The method approximates the singularities as eigenvalues of a certain generalized eigenvalue equation which is solved using iterative techniques. It relies on computation of the action of the Hamiltonian matrix on a vector and does not rely on the terms in the perturbation series. The method can be useful for studying perturbation series of typical systems of moderate size, for fundamental development of resummation schemes, and for understanding the structure of singularities for typical systems. Some illustrative model problems are studied, including a helium-like model with {delta}-function interactions for which Moeller-Plesset perturbation theory is considered and the radius of convergence found.

  1. Chiral Pesticide Pharmacokinetics: A Range of Values

    EPA Science Inventory

    Approximately 30% of pesticides are chiral and used as mixtures of two or more stereoisomers. In biological systems, these stereoisomers can exhibit significantly different pharmacokinetics (absorption, distribution, metabolism, and elimination). In spite of these differences, th...

  2. Electronic circular dichroism behavior of chiral Phthiobuzone

    PubMed Central

    Li, Li; Wang, Lin; Si, Yikang

    2014-01-01

    Phthiobuzone is a bis(thiosemicarbazone) derivative with a single chiral center which has been used as a racemate in the clinical treatment of herpes and trachoma diseases. In this study, its two enantiomers were prepared from chiral amino acids and their absolute configurations were investigated by electronic circular dichroism (ECD) combined with modern quantum-chemical calculations using time-dependent density functional theory. It was found that solvation changed both the conformational distribution and the ECD spectrum of each conformer. The theoretical ECD spectra of the two enantiomers were in good agreement with the experimentally determined spectra of the corresponding isomers in dimethyl sulfoxide. The ECD behavior of the bis(thiosemicarbazone) chromophore in a chiral environment is also discussed. Our results indicate that ECD spectroscopy may be a useful tool for the stereochemical evaluation of chiral drugs. PMID:26579380

  3. How center vortices break chiral symmetry

    NASA Astrophysics Data System (ADS)

    Faber, Manfried; Höllwieser, Roman

    2016-01-01

    We investigate the chiral properties of near-zero modes for thick classical center vortices in SU(2) lattice gauge theory as examples of the phenomena which may arise in a vortex vacuum. In particular we analyze the creation of near-zero modes from would-be zero modes of various topological charge contributions from center vortices. We show that classical colorful spherical vortex and instanton ensembles have almost identical Dirac spectra and the low-lying eigenmodes from spherical vortices show all characteristic properties for chiral symmetry breaking. We further show that also vortex intersections are able to give rise to a finite density of near-zero modes, leading to chiral symmetry breaking via the Banks-Casher formula. We discuss the mechanism by which center vortex fluxes contribute to chiral symmetry breaking.

  4. Controlling and imaging chiral spin textures

    NASA Astrophysics Data System (ADS)

    Chen, Gong

    Chirality in magnetic materials is fundamentally interesting and holds potential for logic and memory applications. Using spin-polarized low-energy electron microscopy at National Center for Electron Microscopy, we recently observed chiral domain walls in thin films. We developed ways to tailor the Dzyaloshinskii-Moriya interaction, which drives the chirality, by interface engineering and by forming ternary superlattices. We find that spin-textures can be switched between left-handed, right-handed, cycloidal, helical and mixed domain wall structures by controlling uniaxial strain in magnetic films. We also demonstrate an experimental approach to stabilize skyrmions in magnetic multilayers without external magnetic field. These results exemplify the rich physics of chirality associated with interfaces of magnetic materials

  5. Drag suppression in anomalous chiral media

    NASA Astrophysics Data System (ADS)

    Sadofyev, Andrey V.; Yin, Yi

    2016-06-01

    We study a heavy impurity moving longitudinal with the direction of an external magnetic field in an anomalous chiral medium. Such system would carry a nondissipative current of chiral magnetic effect associated with the anomaly. We show, by generalizing Landau's criterion for superfluidity, that the "anomalous component" which gives rise to the anomalous transport will not contribute to the drag experienced by an impurity. We argue on a very general basis that those systems with a strong magnetic field would exhibit an interesting transport phenomenon—the motion of the heavy impurity is frictionless, in analogy to the case of a superfluid. We demonstrate and confirm our general results with two complementary examples: weakly coupled chiral fermion gases and strongly interacting chiral liquids.

  6. Chiral chemistry of metal-camphorate frameworks.

    PubMed

    Gu, Zhi-Gang; Zhan, Caihong; Zhang, Jian; Bu, Xianhui

    2016-06-01

    This critical review presents the various synthetic approaches and chiral chemistry of metal-camphorate frameworks (MCamFs), which are homochiral metal-organic frameworks (MOFs) constructed from a camphorate ligand. The interest in this unique subset of homochiral MOFs is derived from the many interesting chiral features for both materials and life sciences, such as asymmetrical synthesis or crystallization, homochiral structural design, chiral induction, absolute helical control and ligand handedness. Additionally, we discuss the potential applications of homochiral MCamFs. This review will be of interest to researchers attempting to design other homochiral MOFs and those engaged in the extension of MOFs for applications such as chiral recognition, enantiomer separation, asymmetric catalysis, nonlinear sensors and devices. PMID:27021070

  7. Personal recollections on chiral symmetry breaking

    NASA Astrophysics Data System (ADS)

    Kobayashi, Makoto

    2016-07-01

    The author's work on the mass of pseudoscalar mesons is briefly reviewed. The emergence of the study of CP violation in the renormalizable gauge theory from consideration of chiral symmetry in the quark model is discussed.

  8. Optically active particles of chiral polymers.

    PubMed

    Song, Ci; Liu, Xuan; Liu, Dong; Ren, Chonglei; Yang, Wantai; Deng, Jianping

    2013-09-01

    Particles constructed by chiral polymers (defined as PCPs) have emerged as a rapidly expanding research field in recent years because of their potentially wide-ranging applications in asymmetric catalysis, enantioselective crystallization, enantioselective release, amongst many others. The particles show considerable optical activity, due to the chirality of the corresponding polymers from which the particles are derived. This review article presents an overview on PCPs with emphasis on our group's recent achievements in the preparation of PCPs derived from optically active helical polymers and their applications. PCPs can be prepared via emulsion polymerization, precipitation polymerization, and suspension polymerization by starting from monomers. Emulsification of preformed chiral polymers and self-assembly approaches also can lead to PCPs. Chiral polymer-based core/shell particles, hollow particles, and magnetic particles are also covered because of their remarkable properties and significant potential applications. PMID:24030962

  9. DH(*) in chiral smectics under electric field.

    PubMed

    Meyer, C; Rabette, C; Gisse, P; Antonova, K; Dozov, I

    2016-07-01

    The behavior of double helices (DH(*) formed in the temperature interval N(*) -SmA(*) in compounds of non-chiral liquid crystals doped with chiral molecules was investigated. Two different systems presenting left-handed and right-handed chirality were studied. A statistics of the handedness of the DH(*) revealed a correlation with the mixture chirality, as predicted theoretically in C. Meyer, Yu. A. Nastishin, M. Kleman, Phys. Rev. E 82, 031704 (2010). By applying a gradually increasing AC electric field, one can observe the shrinking of the cylinder circumscribing the DH(*) . This shrink is accompanied by a reduction of the DH(*) 's pitch. This effect was similar to the one produced by the decrease of temperature in the absence of the field. PMID:27465656

  10. Statistical anisotropy of the curvature perturbation from vector field perturbations

    SciTech Connect

    Dimopoulos, Konstantinos; Karciauskas, Mindaugas; Lyth, David H.; Rodriguez, Yeinzon E-mail: m.karciauskas@lancaster.ac.uk E-mail: yeinzon.rodriguez@uan.edu.co

    2009-05-15

    The {delta}N formula for the primordial curvature perturbation {zeta} is extended to include vector as well as scalar fields. Formulas for the tree-level contributions to the spectrum and bispectrum of {zeta} are given, exhibiting statistical anisotropy. The one-loop contribution to the spectrum of {zeta} is also worked out. We then consider the generation of vector field perturbations from the vacuum, including the longitudinal component that will be present if there is no gauge invariance. Finally, the {delta}N formula is applied to the vector curvaton and vector inflation models with the tensor perturbation also evaluated in the latter case.

  11. Chiral extrapolation of SU(3) amplitudes

    SciTech Connect

    Ecker, Gerhard

    2011-05-23

    Approximations of chiral SU(3) amplitudes at NNLO are proposed to facilitate the extrapolation of lattice data to the physical meson masses. Inclusion of NNLO terms is essential for investigating convergence properties of chiral SU(3) and for determining low-energy constants in a controllable fashion. The approximations are tested with recent lattice data for the ratio of decay constants F{sub K}/F{sub {pi}}.

  12. Control of normal chirality at hexagonal interfaces

    SciTech Connect

    Haraldsen, Jason T; Fishman, Randy Scott

    2010-01-01

    We study the net chirality created by the Dzyaloshinkii-Moriya interaction (DMI) at the boundary between hexagonal layers of magnetic and non-magnetic materials. It is shown that another mechanism besides elastic torsion is required to understand the change in chirality observed in Dy/Y multilayers during field-cooling. The paper shows that due to the overlap between magnetic and non-magnetic atoms, interfacial steps may produce a DMI normal to the interface in magnetic heterostructures.

  13. Microbial production and applications of chiral hydroxyalkanoates.

    PubMed

    Chen, Guo-Qiang; Wu, Qiong

    2005-06-01

    Polyhydroxyalkanoates (PHA) are a family of polyesters consisting of over 150 chiral hydroxyalkanoic acids (HA). This paper reviews the physiological functions of (R)-3-hydroxybutyric acid (3HB) and (R)-4-hydroxybutyric acid and summarizes the technologies developed to produce various HA [3HB, (R)-3-hydroxyoctanoic acid, (R)-3-hydroxydecanoic acid, etc.] and the applications of chiral HA. Their outlooks and perspectives are discussed. PMID:15700123

  14. Nondipole Photoemission from Chiral Enantiomers of Camphor

    NASA Astrophysics Data System (ADS)

    Bowen, K. P.; Stolte, W. C.; Young, J. A.; Demchenko, I. N.; Guillemin, R.; Hemmers, O.; Piancastelli, M. N.; Lindle, D. W.

    2010-03-01

    K-shell photoemission from the carbonyl carbon in the chiral molecule camphor has been studied in the region just above the core-shell ionization threshold. Differences between angular distributions of emitted photoelectrons from the two enantiomers are attributed to the influence of chirality combined with nondipole effects in the photoemission process, despite the fact the measurements were taken using linearly polarized x-rays. The results suggest the possibility of a new form of linear dichroism.

  15. Interference and isospin of disoriented chiral condensates

    SciTech Connect

    Suzuki, M.

    1995-09-01

    If coherent states describe the disoriented chiral condensates (DCC`s), many states of different chiral orientations should equally contribute to a given hadronic process. However, in the classical field description, we ignore the interference between the different DCC amplitudes. It results in a disregard of isospin invariance. We examine quantitatively how good this approximation is for the DCC`s of a typical size.

  16. Analysis of rainbow scattering by a chiral sphere.

    PubMed

    Shang, Qing-Chao; Wu, Zhen-Sen; Qu, Tan; Li, Zheng-Jun; Bai, Lu; Gong, Lei

    2013-09-23

    Based on the scattering theory of a chiral sphere, rainbow phenomenon of a chiral sphere is numerically analyzed in this paper. For chiral spheres illuminated by a linearly polarized wave, there are three first-order rainbows, with whose rainbow angles varying with the chirality parameter. The spectrum of each rainbow structure is presented and the ripple frequencies are found associated with the size and refractive indices of the chiral sphere. Only two rainbow structures remain when the chiral sphere is illuminated by a circularly polarized plane wave. Finally, the rainbows of chiral spheres with slight chirality parameters are found appearing alternately in E-plane and H-plane with the variation of the chirality. PMID:24104080

  17. A Molecular Model for Chiral Symmetry Breaking

    NASA Astrophysics Data System (ADS)

    Latinwo, Folarin; Stillinger, Frank; Debenedetti, Pablo

    In this work, we present a new class of molecular models for chiral phenomena in condensed matter systems. A key feature of these models is the ability of the four-site (tetramer) ``molecules'' to inter-convert between two distinct chiral forms (enantiomers). Given this feature, we use analytical theory and computer simulations to investigate the emergent chiral properties (including symmetry breaking) over a range of conditions. In particular, we consider the single-molecule level and condensed-phase behavior of our model system. Interestingly, we find that our liquid-phase predictions are in excellent agreement with recent experimental reports on chiral self-sorting in isotropic liquids. From this perspective, our model demonstrates accurate predictive capabilities, as well as a platform for understanding the microscopic origins of a variety of chiral phenomena. In a broader context, we anticipate that this class of models will be relevant to chirality-dominated areas such as the pharmaceutical industry and pre-biotic geochemistry.

  18. Cosmological perturbations during radion stabilization

    NASA Astrophysics Data System (ADS)

    Ashcroft, P. R.; van de Bruck, C.; Davis, A.-C.

    2005-01-01

    We consider the evolution of cosmological perturbations during radion stabilization, which we assume to happen after a period of inflation in the early universe. Concentrating on the Randall-Sundrum brane world scenario, we find that, if matter is present both on the positive and negative tension branes, the coupling of the radion to matter fields could have significant impact on the evolution of the curvature perturbation and on the production of entropy perturbations. We investigate both the case of a long-lived and a short-lived radion and outline similarities and differences to the curvaton scenario.

  19. A study of steric chirality: the chiral nematic phase of a system of chiral two-site HGO molecules

    NASA Astrophysics Data System (ADS)

    Varga, Szabolcs; Jackson, George

    2011-03-01

    The liquid crystalline phase behaviour of a chiral two-site hard Gaussian overlap fluid is examined using the well-known Parsons-Lee extension of the theory of Onsager. The hard-core model is constructed such that the vector connecting the centers of two hard Gaussian segments is perpendicular to the long axes of both segments. The microscopic chirality of the particle can be controlled with the dihedral angle between the long axes of the hard Gaussian segments, the distance between the two segments, and the length-to-breath ratios of each segment. In the framework of the Parsons-Lee approach three different types of phases are considered, namely, the isotropic liquid state, and the nematic and the chiral nematic (cholesteric) liquid crystalline states. For simplicity, the orientation of the particles is restricted to the plane perpendicular to the twist axis, and the particles do not have internal freedom to rotate around their main symmetry axes. The geometric condition for the formation of a chiral nematic phase, the properties of the helical structure, and the phase boundary of the ordering transition are determined by means of a free energy minimization. It is shown that steric (shape) chirality always gives rise to a helical structure in the nematic phase, and that the low density chiral systems can undergo a transition from an isotropic liquid to a twisted nematic phase on increasing the density. Analytical expressions are obtained for the twist period (pitch) in the limit of parallel stacking of the rod-like segments in layers normal to the helical axis, which are only valid for systems characterized by weak chiral strengths. A key finding of the numerical calculations is that the pitch is very sensitive to the segment separation, but not to the density or aspect ratio. It is interesting to note that the inverse of the pitch is predicted to depend linearly on the dihedral angle in all of the cases studied.

  20. Enantioselectively controlled release of chiral drug (metoprolol) using chiral mesoporous silica materials

    NASA Astrophysics Data System (ADS)

    Guo, Zhen; Du, Yu; Liu, Xianbin; Ng, Siu-Choon; Chen, Yuan; Yang, Yanhui

    2010-04-01

    Chiral porous materials have attracted burgeoning attention on account of their potential applications in many areas, such as enantioseparation, chiral catalysis, chemical sensors and drug delivery. In this report, chiral mesoporous silica (CMS) materials with various pore sizes and structures were prepared using conventional achiral templates (other than chiral surfactant) and a chiral cobalt complex as co-template. The synthesized CMS materials were characterized by x-ray diffraction, nitrogen physisorption, scanning electron microscope and transmission electron microscope. These CMS materials, as carriers, were demonstrated to be able to control the enantioselective release of a representative chiral drug (metoprolol). The release kinetics, as modeled by the power law equation, suggested that the release profiles of metoprolol were remarkably dependent on the pore diameter and pore structure of CMS materials. More importantly, R- and S-enantiomers of metoprolol exhibited different release kinetics on CMS compared to the corresponding achiral mesoporous silica (ACMS), attributable to the existence of local chirality on the pore wall surface of CMS materials. The chirality of CMS materials on a molecular level was further substantiated by vibrational circular dichroism measurements.

  1. Chiral polymerization in open systems from chiral-selective reaction rates.

    PubMed

    Gleiser, Marcelo; Nelson, Bradley J; Walker, Sara Imari

    2012-08-01

    We investigate the possibility that prebiotic homochirality can be achieved exclusively through chiral-selective reaction rate parameters without any other explicit mechanism for chiral bias. Specifically, we examine an open network of polymerization reactions, where the reaction rates can have chiral-selective values. The reactions are neither autocatalytic nor do they contain explicit enantiomeric cross-inhibition terms. We are thus investigating how rare a set of chiral-selective reaction rates needs to be in order to generate a reasonable amount of chiral bias. We quantify our results adopting a statistical approach: varying both the mean value and the rms dispersion of the relevant reaction rates, we show that moderate to high levels of chiral excess can be achieved with fairly small chiral bias, below 10%. Considering the various unknowns related to prebiotic chemical networks in early Earth and the dependence of reaction rates to environmental properties such as temperature and pressure variations, we argue that homochirality could have been achieved from moderate amounts of chiral selectivity in the reaction rates. PMID:22610131

  2. Integration of inherent and induced chirality into subphthalocyanine analogue

    NASA Astrophysics Data System (ADS)

    Zhao, Luyang; Qi, Dongdong; Wang, Kang; Wang, Tianyu; Han, Bing; Tang, Zhiyong; Jiang, Jianzhuang

    2016-06-01

    Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inherent and induced chirality. Impressively, an obviously enhanced optical activity is discerned for (R/S)-1 molecules, and corresponding enhancement mechanism is elucidated in detail. The synthesis strategy based on rational molecular design will open the door towards fabrication of chiral materials with giant optical activity, which will have great potential in chiroptical devices.

  3. Updated determination of chiral couplings and vacuum condensates from hadronic τ decay data

    NASA Astrophysics Data System (ADS)

    González-Alonso, Martín; Pich, Antonio; Rodríguez-Sánchez, Antonio

    2016-07-01

    We analyze the lowest spectral moments of the left-right two-point correlation function, using all known short-distance constraints and the recently updated ALEPH V -A spectral function from τ decays. This information is used to determine the low-energy couplings L10 and C87 of chiral perturbation theory and the lowest-dimensional contributions to the operator product expansion of the left-right correlator. A detailed statistical analysis is implemented to assess the theoretical uncertainties, including violations of quark-hadron duality.

  4. Chiral phase from three-spin interactions in an optical lattice

    SciTech Connect

    D'Cruz, Christian; Pachos, Jiannis K.

    2005-10-15

    A spin-1/2 chain model that includes three-spin interactions can effectively describe the dynamics of two species of bosons trapped in an optical lattice with a triangular-ladder configuration. A perturbative theoretical approach and numerical study of its ground state is performed that reveals a rich variety of phases and criticalities. We identify phases with periodicity one, two, or three, as well as critical points that belong in the same universality class as the Ising or the three-state Potts model. We establish a range of parameters, corresponding to a large degeneracy present between phases with period 2 and 3, that nests a gapless incommensurate chiral phase.

  5. Strangeness S =-1 hyperon-nucleon scattering in covariant chiral effective field theory

    NASA Astrophysics Data System (ADS)

    Li, Kai-Wen; Ren, Xiu-Lei; Geng, Li-Sheng; Long, Bingwei

    2016-07-01

    Motivated by the successes of covariant baryon chiral perturbation theory in one-baryon systems and in heavy-light systems, we study relevance of relativistic effects in hyperon-nucleon interactions with strangeness S =-1 . In this exploratory work, we follow the covariant framework developed by Epelbaum and Gegelia to calculate the Y N scattering amplitude at leading order. By fitting the five low-energy constants to the experimental data, we find that the cutoff dependence is mitigated, compared with the heavy-baryon approach. Nevertheless, the description of the experimental data remains quantitatively similar at leading order.

  6. Causal compensated perturbations in cosmology

    NASA Technical Reports Server (NTRS)

    Veeraraghavan, Shoba; Stebbins, Albert

    1990-01-01

    A theoretical framework is developed to calculate linear perturbations in the gravitational and matter fields which arise causally in response to the presence of stiff matter sources in a FRW cosmology. It is shown that, in order to satisfy energy and momentum conservation, the gravitational fields of the source must be compensated by perturbations in the matter and gravitational fields, and the role of such compensation in containing the initial inhomogeneities in their subsequent evolution is discussed. A complete formal solution is derived in terms of Green functions for the perturbations produced by an arbitrary source in a flat universe containing cold dark matter. Approximate Green function solutions are derived for the late-time density perturbations and late-time gravitational waves in a universe containing a radiation fluid. A cosmological energy-momentum pseudotensor is defined to clarify the nature of energy and momentum conservation in the expanding universe.

  7. Isocurvature perturbations in extra radiation

    SciTech Connect

    Kawasaki, Masahiro; Miyamoto, Koichi; Nakayama, Kazunori; Sekiguchi, Toyokazu E-mail: miyamone@icrr.u-tokyo.ac.jp E-mail: oyokazu.sekiguchi@nagoya-u.jp

    2012-02-01

    Recent cosmological observations, including measurements of the CMB anisotropy and the primordial helium abundance, indicate the existence of an extra radiation component in the Universe beyond the standard three neutrino species. In this paper we explore the possibility that the extra radiation has isocurvatrue fluctuations. A general formalism to evaluate isocurvature perturbations in the extra radiation is provided in the mixed inflaton-curvaton system, where the extra radiation is produced by the decay of both scalar fields. We also derive constraints on the abundance of the extra radiation and the amount of its isocurvature perturbation. Current observational data favors the existence of an extra radiation component, but does not indicate its having isocurvature perturbation. These constraints are applied to some particle physics motivated models. If future observations detect isocurvature perturbations in the extra radiation, it will give us a hint to the origin of the extra radiation.

  8. Robust stability under additive perturbations

    NASA Technical Reports Server (NTRS)

    Bhaya, A.; Desoer, C. A.

    1985-01-01

    A MIMO linear time-invariant feedback system 1S(P,C) is considered which is assumed to be U-stable. The plant P is subjected to an additive perturbation Delta P which is proper but not necessarily stable. It is proved that the perturbed system is U-stable if and only if Delta P(I + Q x Delta P) exp -1 is U-stable.

  9. Formation of Enhanced Uniform Chiral Fields in Symmetric Dimer Nanostructures.

    PubMed

    Tian, Xiaorui; Fang, Yurui; Sun, Mengtao

    2015-01-01

    Chiral fields with large optical chirality are very important in chiral molecules analysis, sensing and other measurements. Plasmonic nanostructures have been proposed to realize such super chiral fields for enhancing weak chiral signals. However, most of them cannot provide uniform chiral near-fields close to the structures, which makes these nanostructures not so efficient for applications. Plasmonic helical nanostructures and blocked squares have been proved to provide uniform chiral near-fields, but structure fabrication is a challenge. In this paper, we show that very simple plasmonic dimer structures can provide uniform chiral fields in the gaps with large enhancement of both near electric fields and chiral fields under linearly polarized light illumination with polarization off the dimer axis at dipole resonance. An analytical dipole model is utilized to explain this behavior theoretically. 30 times of volume averaged chiral field enhancement is gotten in the whole gap. Chiral fields with opposite handedness can be obtained simply by changing the polarization to the other side of the dimer axis. It is especially useful in Raman optical activity measurement and chiral sensing of small quantity of chiral molecule. PMID:26621558

  10. Formation of Enhanced Uniform Chiral Fields in Symmetric Dimer Nanostructures

    PubMed Central

    Tian, Xiaorui; Fang, Yurui; Sun, Mengtao

    2015-01-01

    Chiral fields with large optical chirality are very important in chiral molecules analysis, sensing and other measurements. Plasmonic nanostructures have been proposed to realize such super chiral fields for enhancing weak chiral signals. However, most of them cannot provide uniform chiral near-fields close to the structures, which makes these nanostructures not so efficient for applications. Plasmonic helical nanostructures and blocked squares have been proved to provide uniform chiral near-fields, but structure fabrication is a challenge. In this paper, we show that very simple plasmonic dimer structures can provide uniform chiral fields in the gaps with large enhancement of both near electric fields and chiral fields under linearly polarized light illumination with polarization off the dimer axis at dipole resonance. An analytical dipole model is utilized to explain this behavior theoretically. 30 times of volume averaged chiral field enhancement is gotten in the whole gap. Chiral fields with opposite handedness can be obtained simply by changing the polarization to the other side of the dimer axis. It is especially useful in Raman optical activity measurement and chiral sensing of small quantity of chiral molecule. PMID:26621558

  11. B- and D-meson decay constants from three-flavor lattice QCD

    SciTech Connect

    Bazavov, A.; et al.

    2012-06-01

    We calculate the leptonic decay constants of B_{(s)} and D_{(s)} mesons in lattice QCD using staggered light quarks and Fermilab bottom and charm quarks. We compute the heavy-light meson correlation functions on the MILC asqtad-improved staggered gauge configurations which include the effects of three light dynamical sea quarks. We simulate with several values of the light valence- and sea-quark masses (down to ~m_s/10) and at three lattice spacings (a ~ 0.15, 0.12, and 0.09 fm) and extrapolate to the physical up and down quark masses and the continuum using expressions derived in heavy-light meson staggered chiral perturbation theory. We renormalize the heavy-light axial current using a mostly nonperturbative method such that only a small correction to unity must be computed in lattice perturbation theory and higher-order terms are expected to be small. We obtain f_{B^+} = 196.9(8.9) MeV, f_{B_s} = 242.0(9.5) MeV, f_{D^+} = 218.9(11.3) MeV, f_{D_s} = 260.1(10.8) MeV, and the SU(3) flavor-breaking ratios f_{B_s}/f_{B} = 1.229(26) and f_{D_s}/f_{D} = 1.188(25), where the numbers in parentheses are the total statistical and systematic uncertainties added in quadrature.

  12. Chiral dynamics and peripheral transverse densities

    SciTech Connect

    Granados, Carlos G.; Weiss, Christian

    2014-01-01

    In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at transverse distances b = O(M{sub {pi}}{sup -1}) and compute them in a parametrically controlled manner. A dispersion relation connects the large-distance behavior of the transverse charge and magnetization densities to the spectral functions of the Dirac and Pauli form factors near the two--pion threshold at timelike t = 4 M{ sub {pi}}{sup 2}, which can be computed in relativistic chiral effective field theory. Using the leading-order approximation we (a) derive the asymptotic behavior (Yukawa tail) of the isovector transverse densities in the "chiral" region b = O(M{sub {pi}}{sup -1}) and the "molecular" region b = O(M{sub N}{sup 2}/M{sub {pi}}{sup 3}); (b) perform the heavy-baryon expansion of the transverse densities; (c) explain the relative magnitude of the peripheral charge and magnetization densities in a simple mechanical picture; (d) include Delta isobar intermediate states and study the peripheral transverse densities in the large-N{ sub c} limit of QCD; (e) quantify the region of transverse distances where the chiral components of the densities are numerically dominant; (f) calculate the chiral divergences of the b{sup 2}-weighted moments of the isovector transverse densities (charge and anomalous magnetic radii) in the limit M{sub {pi}} -> 0 and determine their spatial support. Our approach provides a concise formulation of the spatial structure of the nucleon's chiral component and offers new insights into basic properties of the chiral expansion. It relates the information extracted from low-t elastic form factors to the generalized parton distributions probed in peripheral high-energy scattering processes.

  13. Chiral pesticides: identification, description, and environmental implications.

    PubMed

    Ulrich, Elin M; Morrison, Candice N; Goldsmith, Michael R; Foreman, William T

    2012-01-01

    Of the 1,693 pesticides considered in this review, 1,594 are organic chemicals, 47 are inorganic chemicals, 53 are of biological origin (largely non chemical; insect,fungus, bacteria, virus, etc.), and 2 have an undetermined structure. Considering that the EPA's Office of Pesticide Programs found 1,252 pesticide active ingredients(EPA Pesticides Customer Service 2011), we consider this dataset to be comprehensive; however, no direct comparison of the compound lists was undertaken. Of all pesticides reviewed, 482 (28%) are chiral; 30% are chiral when considering only the organic chemical pesticides. A graph of this distribution is shown in Fig. 7a. Each pesticide is classified with up to three pesticidal utilities (e.g., fungicide, plant growth regulator, rodenticide, etc.), taken first from the Pesticide Manual as a primary source, and the Compendium of Common Pesticide Names website as a secondary source. Of the chiral pesticides, 195 (34%) are insecticides (including attractants, pheromones, and repellents), 150 (27%) are herbicides (including plant growth regulators and herbicide safeners), 104 (18%) are fungicides, and 55 (10%)are acaricides. The distribution of chiral pesticides by utility is shown in Fig. 7b,including categories of pesticides that make up 3%t or less of the usage categories.Figure 7c shows a similar distribution of non chiral pesticide usage categories. Of the chiral pesticides, 270 (56%) have one chiral feature, 105 (22%) have two chiral features, 30 (6.2%) have three chiral features, and 29 (6.0%) have ten or more chiral features.Chiral chemicals pose many difficulties in stereospecific synthesis, characterization, and analysis. When these compounds are purposely put into the environment,even more interesting complications arise in tracking, monitoring, and predicting their fate and risks. More than 475 pesticides are chiral, as are other chiral contaminants such as pharmaceuticals, polychlorinated biphenyls, brominated flame retardants

  14. Improved Measure of Local Chirality

    SciTech Connect

    Terrence Draper; Andrei Alexandru; Ying Chen; Shao-Jing Dong; Ivan Horvath; Frank Lee; Nilmani Mathur; Harry B. Thacker; Sonali Tamhankar; Jianbo Zhang

    2004-06-01

    It is popular to probe the structure of the QCD vacuum indirectly by studying individual fermion eigenmodes, because this provides a natural way to filter out UV fluctuations. The double-peaking in the distribution of the local chiral orientation parameter (X) has been offered as evidence, by some, in support of a particular model of the vacuum. Here we caution that the X-distribution peaking varies significantly with various versions of the definition of X. Furthermore, each distribution varies little from that resulting from a random reshuffling of the left-handed (and independently the right-handed) fields, which destroys any QCD-induced left-right correlation; that is, the double-peaking is mostly a phase-space effect. We propose a new universal definition of the X parameter whose distribution is uniform for randomly reshuffled fields. Any deviations from uniformity for actual data can then be directly attributable to QCD-induced dynamics. We find that the familiar double peak disappears.

  15. Chiral Properties in ^134Pr

    NASA Astrophysics Data System (ADS)

    Starosta, K.; Chiara, C. J.; Fossan, D. B.; Koike, T.; Beausang, C. W.; Hecht, A. A.; Boston, A. J.; Chantler, H. J.; Paul, E. S.; Scraggs, H. C.; Simons, A.; Wadsworth, R.; Clark, R. M.

    2001-04-01

    The πh_11/2νh_11/2 doublet bands in ^134Pr, which represent the best evidence to date for chiral symmetry breaking in odd-odd nuclei [1], were investigated with the GAMMASPHERE array using the ^116Cd(^23Na,5n) reaction at 115 MeV. From thin-target data, the nearly degenerate ΔI=1 side band was extended from a 9^+ bandhead up to a spin of 24^+ with E2 crossovers, a total of 15 units of spin, while the main yrast band was observed from an 8^+ bandhead to 24^+. Measured γ-ray intensities suggest a staggering of the B(M1)/B(E2) ratios in the main band with the ratio smaller for even-spin initial states; these compare well with those of other N=75 isotones. Relative transition rates for γ-rays linking the doublet bands have also been extracted. Analysis of backed-target data aimed at absolute transition rates is underway. The results will be compared to calculations with particle-hole triaxial-rotor and 3-D TAC models. [1mm] [1] C.M.Petrache, et al., Nucl.Phys.A597(1996)106; V.I.Dimitrov, et al., PRL 84(2000)5732; K. Starosta, et al., PRL 86(2001).

  16. Vibrational circular dichroism from ab initio molecular dynamics and nuclear velocity perturbation theory in the liquid phase.

    PubMed

    Scherrer, Arne; Vuilleumier, Rodolphe; Sebastiani, Daniel

    2016-08-28

    We report the first fully ab initio calculation of dynamical vibrational circular dichroism spectra in the liquid phase using nuclear velocity perturbation theory (NVPT) derived electronic currents. Our approach is rigorous and general and thus capable of treating weak interactions of chiral molecules as, e.g., chirality transfer from a chiral molecule to an achiral solvent. We use an implementation of the NVPT that is projected along the dynamics to obtain the current and magnetic dipole moments required for accurate intensities. The gauge problem in the liquid phase is resolved in a twofold approach. The electronic expectation values are evaluated in a distributed origin gauge, employing maximally localized Wannier orbitals. In a second step, the gauge invariant spectrum is obtained in terms of a scaled molecular moments, which allows to systematically include solvent effects while keeping a significant signal-to-noise ratio. We give a thorough analysis and discussion of this choice of gauge for the liquid phase. At low temperatures, we recover the established double harmonic approximation. The methodology is applied to chiral molecules ((S)-d2-oxirane and (R)-propylene-oxide) in the gas phase and in solution. We find an excellent agreement with the theoretical and experimental references, including the emergence of signals due to chirality transfer from the solute to the (achiral) solvent. PMID:27586898

  17. The two-photon exchange contribution to muonic hydrogen from chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Peset, Clara; Pineda, Antonio

    2014-10-01

    We compute the spin-dependent and spin-independent structure functions of the forward virtual-photon Compton tensor of the proton at O(p3) using heavy baryon effective theory including the Delta particle. We compare with previous results when existing. Using these results we obtain the leading hadronic contributions, associated to the pion and Delta particles, to the Wilson coefficients of the lepton-proton four fermion operators in NRQED. The spin-independent coefficient yields a pure prediction for the two-photon exchange contribution to the muonic hydrogen Lamb shift, ΔETPE(π&Δ)=34(13) μeV. We also compute the charge, , and Zemach, (2), moments for n≥3. Finally, we discuss the spin-dependent case, for which we compute the difference between the four-fermion Wilson coefficients relevant for hydrogen and muonic hydrogen.

  18. Consistency of the {pi}{delta} interaction in chiral perturbation theory

    SciTech Connect

    Wies, N.; Scherer, S.; Gegelia, J.

    2006-05-01

    We analyze the constraint structure of a spin-3/2 particle interacting with a pseudoscalar. Requiring the self consistency of the considered effective field theory imposes restrictions on the possible interaction terms. In the present case we derive two constraints among the three lowest-order {pi}{delta} interaction terms. From these constraints we find that the total Lagrangian is invariant under the so-called point transformation. On the other hand, demanding the invariance under the point transformation alone is less stringent and produces only classes of relations among the coupling constants.

  19. Macroscopic chirality of a liquid crystal from nonchiral molecules

    NASA Astrophysics Data System (ADS)

    Jákli, A.; Nair, G. G.; Lee, C. K.; Sun, R.; Chien, L. C.

    2001-06-01

    The transfer of chirality from nonchiral polymer networks to the racemic B2 phase of nonchiral banana-shaped molecules is demonstrated. This corresponds to the transfer of chirality from an achiral material to another achiral material. There are two levels of chirality transfers. (a) On a microscopic level the presence of a polymer network (chiral or nonchiral) favors a chiral state over a thermodynamically stable racemic state due to the inversion symmetry breaking at the polymer-liquid crystal interfaces. (b) A macroscopically chiral (enantimerically enriched) sample can be produced if the polymer network has a helical structure, and/or contains chemically chiral groups. The chirality transfer can be locally suppressed by exposing the liquid crystal to a strong electric field treatment.

  20. METHODS DEVELOPMENT FOR THE ANALYSIS OF CHIRAL PESTICIDES

    EPA Science Inventory

    Chiral compounds exist as a pair of nonsuperimposable mirror images called enantiomers. Enantiomers have identical physical-chemical properties, but their interactions with other chiral molecules, toxicity, biodegradation, and fate are often different. Many pharmaceutical com...

  1. PESTICIDE EXPOSURE AND CHIRAL CHEMISTRY: THE PYRETHROID FAMILY

    EPA Science Inventory

    Advances in chiral chromatography significantly advanced the ability to analyze individual enantiomers of chiral compounds. These techniques are being employed at the U.S. EPA for human exposure and ecological research studies. Enantiomer fractions (EFs) were measured for cisp...

  2. On the chiral imbalance and Weibel instabilities

    NASA Astrophysics Data System (ADS)

    Kumar, Avdhesh; Bhatt, Jitesh R.; Kaw, P. K.

    2016-06-01

    We study the chiral-imbalance and the Weibel instabilities in presence of the quantum anomaly using the Berry-curvature modified kinetic equation. We argue that in many realistic situations, e.g. relativistic heavy-ion collisions, both the instabilities can occur simultaneously. The Weibel instability depends on the momentum anisotropy parameter ξ and the angle (θn) between the propagation vector and the anisotropy direction. It has maximum growth rate at θn = 0 while θn = π / 2 corresponds to a damping. On the other hand the pure chiral-imbalance instability occurs in an isotropic plasma and depends on difference between the chiral chemical potentials of right and left-handed particles. It is shown that when θn = 0, only for a very small values of the anisotropic parameter ξ ∼ξc, growth rates of the both instabilities are comparable. For the cases ξc < ξ ≪ 1 or ξ ≳ 1 at θn = 0, the Weibel modes dominate over the chiral-imbalance instability if μ5 / T ≤ 1. However, when μ5 / T ≥ 1, it is possible to have dominance of the chiral-imbalance modes at certain values of θn for an arbitrary ξ.

  3. Chiral density wave in nuclear matter

    NASA Astrophysics Data System (ADS)

    Heinz, Achim; Giacosa, Francesco; Rischke, Dirk H.

    2015-01-01

    Inspired by recent work on inhomogeneous chiral condensation in cold, dense quark matter within models featuring quark degrees of freedom, we investigate the chiral density-wave solution in nuclear matter at zero temperature and nonvanishing baryon number density in the framework of the so-called extended linear sigma model (eLSM). The eLSM is an effective model for the strong interaction based on the global chiral symmetry of quantum chromodynamics (QCD). It contains scalar, pseudoscalar, vector, and axial-vector mesons as well as baryons. In the latter sector, the nucleon and its chiral partner are introduced as parity doublets in the mirror assignment. The eLSM simultaneously provides a good description of hadrons in vacuum as well as nuclear matter ground-state properties. We find that an inhomogeneous phase in the form of a chiral density wave is realized, but only for densities larger than 2.4ρ0, where ρ0 is the nuclear matter ground-state density.

  4. Ratchet transport powered by chiral active particles

    PubMed Central

    Ai, Bao-quan

    2016-01-01

    We numerically investigate the ratchet transport of mixtures of active and passive particles in a transversal asymmetric channel. A big passive particle is immersed in a ‘sea’ of active particles. Due to the chirality of active particles, the longitudinal directed transport is induced by the transversal asymmetry. For the active particles, the chirality completely determines the direction of the ratchet transport, the counterclockwise and clockwise particles move to the opposite directions and can be separated. However, for the passive particle, the transport behavior becomes complicated, the direction is determined by competitions among the chirality, the self-propulsion speed, and the packing fraction. Interestingly, within certain parameters, the passive particle moves to the left, while active particles move to the right. In addition, there exist optimal parameters (the chirality, the height of the barrier, the self-propulsion speed and the packing fraction) at which the rectified efficiency takes its maximal value. Our findings could be used for the experimental pursuit of the ratchet transport powered by chiral active particles. PMID:26795952

  5. Chirality dependent spin polarization of carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Wang, Jia; Jiang, Wanrun; Wang, Bo; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2016-02-01

    The spin polarization of carbon nanotubes (CNTs) offers a tunable building block for spintronic devices and is also crucial for realizing carbon-based electronics. However, the effect of chiral CNTs is still unclear. In this paper, we use the density functional theory (DFT) method to investigate the spin polarization of a series of typical finite-length chiral CNTs (9, m). The results show that the spin density of chiral CNTs (9, m) decreases gradually with the increase in m and vanishes altogether when m is larger than or equal to 6. The armchair edge units on both ends of the (9, m) CNTs exhibit a clear inhibition of spin polarization, allowing control of the spin density of (9, m) CNTs by adjusting the number of armchair edge units on the tube end. Furthermore, analysis of the orbitals shows that the spin of the ground state for (9, m) CNTs mainly comes from the contributions of the frontier molecular orbitals (MOs), and the energy gap decreases gradually with the spin density for chiral CNTs. Our work further develops the study of the spin polarization of CNTs and provides a strategy for controlling the spin polarization of functional molecular devices through chiral vector adjustment.

  6. Chiral effects in uniformly loaded rods

    NASA Astrophysics Data System (ADS)

    Ieşan, D.

    2010-09-01

    Examples of chiral materials include some auxetic materials, bones, some honeycomb structures, as well as composites with inclusions. The chiral effects cannot be described within classical elasticity. In the context of the linear theory of Cosserat elastic solids, we investigate the deformation of a chiral rod subjected to tractions on the lateral surface, to body loads, and to resultant forces and moments on the ends. The work is motivated by the recent interest in the using of the Cosserat elastic solid as model for auxetic composites, carbon nanotubes and bones. The three-dimensional problem is reduced to the study of some generalized plane strain problems. New chiral effects are presented. In the case of cylinders of arbitrary cross-section, the flexure produced by a transversal force, in contrast with the case of achiral materials, is accompanied by extension and bending by terminal couples. The body loads and the tractions on the lateral surface produce extension, flexure, torsion, bending by terminal couples and a plane strain. It is shown that a uniform pressure acting on the lateral surface of a chiral circular cylinder does not produce bending effects.

  7. Ratchet transport powered by chiral active particles

    NASA Astrophysics Data System (ADS)

    Ai, Bao-Quan

    2016-01-01

    We numerically investigate the ratchet transport of mixtures of active and passive particles in a transversal asymmetric channel. A big passive particle is immersed in a ‘sea’ of active particles. Due to the chirality of active particles, the longitudinal directed transport is induced by the transversal asymmetry. For the active particles, the chirality completely determines the direction of the ratchet transport, the counterclockwise and clockwise particles move to the opposite directions and can be separated. However, for the passive particle, the transport behavior becomes complicated, the direction is determined by competitions among the chirality, the self-propulsion speed, and the packing fraction. Interestingly, within certain parameters, the passive particle moves to the left, while active particles move to the right. In addition, there exist optimal parameters (the chirality, the height of the barrier, the self-propulsion speed and the packing fraction) at which the rectified efficiency takes its maximal value. Our findings could be used for the experimental pursuit of the ratchet transport powered by chiral active particles.

  8. Ratchet transport powered by chiral active particles.

    PubMed

    Ai, Bao-quan

    2016-01-01

    We numerically investigate the ratchet transport of mixtures of active and passive particles in a transversal asymmetric channel. A big passive particle is immersed in a 'sea' of active particles. Due to the chirality of active particles, the longitudinal directed transport is induced by the transversal asymmetry. For the active particles, the chirality completely determines the direction of the ratchet transport, the counterclockwise and clockwise particles move to the opposite directions and can be separated. However, for the passive particle, the transport behavior becomes complicated, the direction is determined by competitions among the chirality, the self-propulsion speed, and the packing fraction. Interestingly, within certain parameters, the passive particle moves to the left, while active particles move to the right. In addition, there exist optimal parameters (the chirality, the height of the barrier, the self-propulsion speed and the packing fraction) at which the rectified efficiency takes its maximal value. Our findings could be used for the experimental pursuit of the ratchet transport powered by chiral active particles. PMID:26795952

  9. Two-color QCD with chiral chemical potential

    NASA Astrophysics Data System (ADS)

    Braguta, V. V.; Goy, V. A.; Ilgenfritz, E.-M.; Kotov, A. Yu.; Molochkov, A. V.; Müller-Preussker, M.; Petersson, B.; Schreiber, A.

    2016-01-01

    The phase diagram of two-color QCD with a chiral chemical potential is studied on the lattice. The focus is on the confinement/deconfinement phase transition and the breaking/restoration of chiral symmetry. The simulations are carried out with dynamical staggered fermions without rooting. The dependence of the Polyakov loop, the chiral condensate and the corresponding susceptibilities on the chiral chemical potential and the temperature are presented.

  10. Inhomogeneous Polyakov loop induced by inhomogeneous chiral condensates

    NASA Astrophysics Data System (ADS)

    Hayata, Tomoya; Yamamoto, Arata

    2015-05-01

    We study the spatial inhomogeneity of the Polyakov loop induced by inhomogeneous chiral condensates. We formulate an effective model of gluons on the background fields of chiral condensates, and perform its lattice simulation. On the background of inhomogeneous chiral condensates, the Polyakov loop exhibits an in-phase spatial oscillation with the chiral condensates. We also analyze the heavy quark potential and show that the inhomogeneous Polyakov loop indicates the inhomogeneous confinement of heavy quarks.

  11. Chiral representation of the πN scattering amplitude and the pion-nucleon sigma term

    NASA Astrophysics Data System (ADS)

    Alarcón, J. M.; Camalich, J. Martin; Oller, J. A.

    2012-03-01

    We present a novel analysis of the πN scattering amplitude in Lorentz covariant baryon chiral perturbation theory renormalized in the extended-on-mass-shell scheme. This amplitude, valid up to O(p3) in the chiral expansion, systematically includes the effects of the Δ(1232) in the δ-counting, has the right analytic properties, and is renormalization-scale independent. This approach overcomes the limitations that previous chiral analyses of the πN scattering amplitude had, providing an accurate description of the partial wave phase shifts of the Karlsruhe-Helsinki and George-Washington groups up to energies just below the resonance region. We also study the solution of the Matsinos group which focuses on the parameterization of the data at low energies. Once the values of the low-energy constants are determined by adjusting the center-of-mass energy dependence of the amplitude to the scattering data, we obtain predictions on different observables. In particular, we extract an accurate value for the pion-nucleon sigma term, σπN. This allows us to avoid the usual method of extrapolation to the unphysical region of the amplitude. Our study indicates that the inclusion of modern meson-factory and pionic-atom data favors relatively large values of the sigma term. We report the value σπN=59(7)MeV and comment on implications that this result may have.

  12. Asymmetric Autocatalysis Induced by Chiral Crystals of Achiral Tetraphenylethylenes

    NASA Astrophysics Data System (ADS)

    Kawasaki, Tsuneomi; Nakaoda, Mai; Kaito, Nobuhiro; Sasagawa, Taisuke; Soai, Kenso

    2010-02-01

    The achiral hydrocarbon tetraphenylethylene crystallizes in enantiomorphous forms (chiral space group: P21) to afford right- and left-handed hemihedral crystals, which can be recognized by solid-state circular dichroism spectroscopic analysis. Chiral organic crystals of tetraphenylethylene mediated enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde to give, in conjunction with asymmetric autocatalysis with amplification of chirality, almost enantiomerically pure ( S)- and ( R)-5-pyrimidyl alkanols whose absolute configurations were controlled efficiently by the crystalline chirality of the tetraphenylethylene substrate. Tetrakis( p-chlorophenyl)ethylene and tetrakis( p-bromophenyl)ethylene also show chirality in the crystalline state, which can also act as a chiral substrate and induce enantioselectivity of diisopropylzinc addition to pyrimidine-5-carbaldehyde in asymmetric autocatalysis to give enantiomerically enriched 5-pyrimidyl alkanols with the absolute configuration correlated with that of the chiral crystals. Highly enantioselective synthesis has been achieved using chiral crystals composed of achiral hydrocarbons, tetraphenylethylenes, as chiral inducers. This chemical system enables significant amplification of the amount of chirality using spontaneously formed chiral crystals of achiral organic compounds as the seed for the chirality of asymmetric autocatalysis.

  13. Chirality Change by Grinding Crystals in Solution

    SciTech Connect

    Viedma, Cristobal

    2010-07-22

    One of the greatest unsolved problems in chemistry is the origin of homochirality in the biosphere, that is, the fact that l-amino acids and d-sugars dominate in biology, while laboratory experiments with stereoselective reactions only produce racemic mixtures. Several models have been proposed to address the question of how enantiomerically pure solutions or crystalline phases could have emerged from a presumably racemic prebiotic world. Here we show that two populations of amino acid crystals of 'left' and 'right' hand cannot coexist in solution: one of the chiral populations disappears in an irreversible autocatalytic process that nurtures the other one. Final and complete chiral purity seems to be an inexorable fate in our systems, under grinding, in the course of the common process of growth-dissolution. This unexpected chiral symmetry breaking has become firmly established but the underlying mechanism is being debated and we have no definitive answer.

  14. Spontaneous chiral symmetry breaking in metamaterials

    NASA Astrophysics Data System (ADS)

    Liu, Mingkai; Powell, David A.; Shadrivov, Ilya V.; Lapine, Mikhail; Kivshar, Yuri S.

    2014-07-01

    Spontaneous chiral symmetry breaking underpins a variety of areas such as subatomic physics and biochemistry, and leads to an impressive range of fundamental phenomena. Here we show that this prominent effect is now available in artificial electromagnetic systems, enabled by the advent of magnetoelastic metamaterials where a mechanical degree of freedom leads to a rich variety of strong nonlinear effects such as bistability and self-oscillations. We report spontaneous symmetry breaking in torsional chiral magnetoelastic structures where two or more meta-molecules with opposite handedness are electromagnetically coupled, modifying the system stability. Importantly, we show that chiral symmetry breaking can be found in the stationary response of the system, and the effect is successfully demonstrated in a microwave pump-probe experiment. Such symmetry breaking can lead to a giant nonlinear polarization change, energy localization and mode splitting, which provides a new possibility for creating an artificial phase transition in metamaterials, analogous to that in ferrimagnetic domains.

  15. Heterogeneous chiral catalysis: Past, present, and future

    SciTech Connect

    Brenner, J.R.

    1996-12-31

    In order to improve the scalability of the synthesis of chiral compounds, considerable effort has been devoted to the design of heterogeneous chiral catalysts. The attachment of {open_quotes}curved{close_quotes} chiral ligands, such as cinchona alkaloids, to supported metal complexes has permitted enantioselectivities approaching those in homogeneous solution. While the nature of the support has received less attention, the increased pore structure control gained during the gradual shift from polymeric supports to pillared clays, and finally to mesoporous zeolites and controlled pore glasses will hopefully allow better molecular size and shape control. Future work in this area likely will entail the use of polymeric templates as molecular imprints for protein synthesis and for antibody delivery systems.

  16. A semiclassical formulation of the chiral magnetic effect and chiral anomaly in even d + 1 dimensions

    NASA Astrophysics Data System (ADS)

    Dayi, Ömer F.; Elbistan, Mahmut

    2016-05-01

    In terms of the matrix valued Berry gauge field strength for the Weyl Hamiltonian in any even space-time dimensions a symplectic form whose elements are matrices in spin indices is introduced. Definition of the volume form is modified appropriately. A simple method of finding the path integral measure and the chiral current in the presence of external electromagnetic fields is presented. It is shown that within this new approach the chiral magnetic effect as well as the chiral anomaly in even d + 1 dimensions are accomplished straightforwardly.

  17. Enantioselective synthesis of chiral heterocycles containing both chroman and pyrazolone derivatives catalysed by a chiral squaramide.

    PubMed

    Li, Jun-Hua; Du, Da-Ming

    2015-05-28

    An efficient chiral squaramide-catalysed enantioselective Michael addition of pyrazolin-5-ones to 3-nitro-2H-chromenes for the synthesis of chiral heterocyclic systems containing both chroman and pyrazolone derivatives has been developed. This reaction afforded the desired products in high to excellent yields (up to 98%) with high enantioselectivities (up to 96%) and excellent diastereoselectivities (up to 99 : 1) under very low catalyst loading (0.2 mol%). This catalytic asymmetric reaction provides an efficient route toward the synthesis of chiral heterocyclic systems containing both chroman and pyrazolone derivatives, which possess potential pharmaceutical activities. PMID:25882378

  18. Chiral Molecules Revisited by Broadband Microwave Spectroscopy

    NASA Astrophysics Data System (ADS)

    Schnell, Melanie

    2014-06-01

    Chiral molecules have fascinated chemists for more than 150 years. While their physical properties are to a very good approximation identical, the two enantiomers of a chiral molecule can have completely different (bio)chemical activities. For example, the right-handed enantiomer of carvone smells of spearmint while the left-handed one smells of caraway. In addition, the active components of many drugs are of one specific handedness, such as in the case of ibuprofen. However, in nature as well as in pharmaceutical applications, chiral molecules often exist in mixtures with other chiral molecules. The analysis of these complex mixtures to identify the molecular components, to determine which enantiomers are present, and to measure the enantiomeric excesses (ee) remains a challenging task for analytical chemistry, despite its importance for modern drug development. We present here a new method of differentiating enantiomers of chiral molecules in the gas phase based on broadband rotational spectroscopy. The phase of the acquired signal bares the signature of the enantiomer, as it depends upon the combined quantity, μ_a μ_b μ_c, which is of opposite sign between enantiomers. It thus also provides information on the absolute configuration of the particular enantiomer. Furthermore, the signal amplitude is proportional to the ee. A significant advantage of our technique is its inherent mixture compatibility due to the fingerprint-like character of rotational spectra. In this contribution, we will introduce the technique and present our latest results on chiral molecule spectroscopy and enantiomer differentiation. D. Patterson, M. Schnell, J.M. Doyle, Nature 497 (2013) 475-477 V.A. Shubert, D. Schmitz, D. Patterson, J.M. Doyle, M. Schnell, Angewandte Chemie International Edition 53 (2014) 1152-1155

  19. Gravitational waves from perturbed stars

    NASA Astrophysics Data System (ADS)

    Ferrari, V.

    2011-12-01

    Non radial oscillations of neutron stars are associated with the emission of gravitational waves. The characteristic frequencies of these oscillations can be computed using the theory of stellar perturbations, and they are shown to carry detailed information on the internal structure of the emitting source. Moreover, they appear to be encoded in various radiative processes, as for instance, in the tail of the giant flares of Soft Gamma Repeaters. Thus, their determination is central to the theory of stellar perturbation. A viable approach to the problem consists in formulating this theory as a problem of resonant scattering of gravitational waves incident on the potential barrier generated by the spacetime curvature. This approach discloses some unexpected correspondences between the theory of stellar perturbations and the theory of quantum mechanics, and allows us to predict new relativistic effects.

  20. Gravitational waves from perturbed stars

    NASA Astrophysics Data System (ADS)

    Ferrari, V.

    2011-03-01

    Non radial oscillations of neutron stars are associated with the emission of gravitational waves. The characteristic frequencies of these oscillations can be computed using the theory of stellar perturbations, and they are shown to carry detailed information on the internal structure of the emitting source. Moreover, they appear to be encoded in various radiative processes, as for instance in the tail of the giant flares of Soft Gamma Repeaters. Thus, their determination is central to the theory of stellar perturbation. A viable approach to the problem consists in formulating this theory as a problem of resonant scattering of gravitational waves incident on the potential barrier generated by the spacetime curvature. This approach discloses some unexpected correspondences between the theory of stellar perturbations and the theory of quantum mechanics, and allows us to predict new relativistic effects.

  1. Jet Perturbation by HE target

    SciTech Connect

    Poulsen, P; Kuklo, R M

    2001-03-01

    We have previously reported the degree of attenuation and perturbation by a Cu jet passing through Comp B explosive. Similar tests have now been performed with high explosive (HE) targets having CJ pressures higher than and lower than the CJ pressure of Comp B. The explosives were LX-14 and TNT, respectively. We found that the measured exit velocity of the jet where it transitions from perturbed to solid did not vary significantly as a function of HE type for each HE thickness. The radial momentum imparted to the perturbed jet segment did vary as a function of HE type, however, and we report the radial spreading of the jet and the penetration of a downstream target as a function of HE type and thickness.

  2. Perturbed motion at small eccentricities

    NASA Astrophysics Data System (ADS)

    Emel'yanov, N. V.

    2015-09-01

    In the study of the motion of planets and moons, it is often necessary to have a simple approximate analytical motion model, which takes into account major perturbations and preserves almost the same accuracy at long time intervals. A precessing ellipse model is used for this purpose. In this paper, it is shown that for small eccentricities this model of the perturbed orbit does not correspond to body motion characteristics. There is perturbed circular motion with a constant zero mean anomaly. The corresponding solution satisfies the Lagrange equations with respect to Keplerian orbital elements. There are two families of solutions with libration and circulation changes in the mean anomaly close to this particular solution. The paper shows how the eccentricity and mean anomaly change in these solutions. Simple analytical models of the motion of the four closest moons of Jupiter consistent with available ephemerides are proposed, which in turn are obtained by the numerical integration of motion equations and are refined by observations.

  3. Possible chiral bands in {sup 194}Tl

    SciTech Connect

    Masiteng, P. L.; Ramashidzha, T. M.; Maliage, S. M.; Sharpey-Schafer, J. F.; Vymers, P. A.; Lawrie, E. A.; Lawrie, J. J.; Bark, R. A.; Mullins, S. M.; Murray, S. H. T.; Kau, J.; Komati, F.; Lindsay, R.; Matamba, I.; Mutshena, P.; Zhang, Y.

    2011-10-28

    High spin states in {sup 194}Tl, excited through the {sup 181}Ta({sup 18}O,5n) fusion evaporation reaction, were studied using the AFRODITE array at iThemba LABS. Candidate chiral bands built on the {pi}h{sub 9/2} x {nu}i{sub 13/2}{sup 1} configuration were found. Furthermore these bands were observed through a band crossing caused by the excitation of a {nu}i{sub 13/2} pair. Above the band crossing the excitation energies remain close, suggesting that chirality may persist for the four quasiparticle configuration too.

  4. Asymmetric petasis reactions catalyzed by chiral biphenols.

    PubMed

    Lou, Sha; Schaus, Scott E

    2008-06-01

    Chiral biphenols catalyze the enantioselective Petasis reaction of alkenyl boronates, secondary amines, and ethyl glyoxylate. The reaction requires the use of 15 mol % of (S)-VAPOL as the catalyst, alkenyl boronates as nucleophiles, ethyl glyoxylate as the aldehyde component, and 3 A molecular sieves as an additive. The chiral alpha-amino ester products are obtained in good yields (71-92%) and high enantiomeric ratios (89:11-98:2). Mechanistic investigations indicate single ligand exchange of acyclic boronate with VAPOL and tetracoordinate boronate intermediates. PMID:18459782

  5. Chiral pesticides: Identification, description, and environmental implications

    USGS Publications Warehouse

    Ulrich, Elin M.; Morrison, Candice N.; Goldsmith, Michael R.; Foreman, William T.

    2012-01-01

    Anthropogenic chemicals, including pesticides, are a major source of contamination and pollution in the environment. Pesticides have many positive uses: increased food production, decreased damage to crops and structures, reduced disease vector populations, and more. Nevertheless, pesticide exposure can pose risks to humans and the environment, so various mitigation strategies are exercised to make them safer, minimize their use, and reduce their unintended environment effects. One strategy that may help achieve these goals relies on the unique properties of chirality or molecular asymmetry. Some common terms related to chirality are defined in Table 1.

  6. Steering Chiral Swimmers along Noisy Helical Paths

    NASA Astrophysics Data System (ADS)

    Friedrich, Benjamin M.; Jülicher, Frank

    2009-08-01

    Chemotaxis along helical paths towards a target releasing a chemoattractant is found in sperm cells and many microorganisms. We discuss the stochastic differential geometry of the noisy helical swimming path of a chiral swimmer. A chiral swimmer equipped with a simple feedback system can navigate in a concentration gradient of chemoattractant. We derive an effective equation for the alignment of helical paths with a concentration gradient which is related to the alignment of a dipole in an external field and discuss the chemotaxis index.

  7. A multichannel magneto-chiral dichroism spectrometer

    NASA Astrophysics Data System (ADS)

    Kopnov, G.; Rikken, G. L. J. A.

    2014-05-01

    In this work, we describe a multichannel magneto-chiral dichroism spectrometer for the visible and near infrared wavelength ranges. The optical signal acquisition is based on commercially available Czerny-Turner spectrograph systems equipped with solid state detector arrays. The signal analysis method is based on post-processing phase sensitive detection, where the optical properties of the sample are modulated by an alternating external magnetic field. As an illustration of the performance of this spectrometer, magneto-chiral dichroism was measured in crystals of α - NiSO4 . 6H2O and good agreement with literature results was obtained.

  8. Chiral Thermoelectrics with Quantum Hall Edge States

    NASA Astrophysics Data System (ADS)

    Sánchez, Rafael; Sothmann, Björn; Jordan, Andrew N.

    2015-04-01

    The thermoelectric properties of a three-terminal quantum Hall conductor are investigated. We identify a contribution to the thermoelectric response that relies on the chirality of the carrier motion rather than on spatial asymmetries. The Onsager matrix becomes maximally asymmetric with configurations where either the Seebeck or the Peltier coefficients are zero while the other one remains finite. Reversing the magnetic field direction exchanges these effects, which originate from the chiral nature of the quantum Hall edge states. The possibility to generate spin-polarized currents in quantum spin Hall samples is discussed.

  9. Phenomenology of chiral damping in noncentrosymmetric magnets

    NASA Astrophysics Data System (ADS)

    Akosa, Collins Ashu; Miron, Ioan Mihai; Gaudin, Gilles; Manchon, Aurélien

    2016-06-01

    A phenomenology of magnetic chiral damping is proposed in the context of magnetic materials lacking inversion symmetry. We show that the magnetic damping tensor acquires a component linear in magnetization gradient in the form of Lifshitz invariants. We propose different microscopic mechanisms that can produce such a damping in ferromagnetic metals, among which local spin pumping in the presence of an anomalous Hall effect and an effective "s-d" Dzyaloshinskii-Moriya antisymmetric exchange. The implication of this chiral damping in terms of domain-wall motion is investigated in the flow and creep regimes.

  10. Band structure controlled by chiral imprinting

    NASA Astrophysics Data System (ADS)

    Castro-Garay, P.; Adrian Reyes, J.; Ramos-Garcia, R.

    2007-09-01

    Using the configuration of an imprinted cholesteric elastomer immersed in a racemic solvent, the authors find the solution of the boundary-value problem for the reflection and transmission of incident optical waves due to the elastomer. They show a significant width reduction of the reflection band for certain values of nematic penetration depth, which depends on the volume fraction of molecules from the solvent, whose handedness is preferably absorbed. The appearance of nested band gaps of both handednesses during the sorting mixed chiral process is also obtained. This suggests the design of chemically controlled optical filters and optically monitored chiral pumps.

  11. Band Structure Controlled by Chiral Imprinting

    NASA Astrophysics Data System (ADS)

    Reyes Cervantes, Adrian; Castro-Garay, P.; Ramos-Garcia, Ruben

    2008-03-01

    Using the configuration of an imprinted cholesteric elastomer immersed in a racemic solvent, we find the solution of the boundary--value problem for the reflection and transmission of incident optical waves due to the elastomer. We show a significant width reduction of the reflection band for certain values of nematic penetration depth, which depends on the volume fraction of molecules from the solvent, whose handedness is preferably absorbed. The appearance of nested bandgaps of both handednesses during the sorting mixed chiral process is also obtained. This suggests the design of chemically controlled optical filters and optically monitored chiral pumps.

  12. Terahertz wave emission from plasmonic chiral metasurfaces

    NASA Astrophysics Data System (ADS)

    Matsui, Takahiro; Tomita, Satoshi; Asai, Motoki; Tadokoro, Yuzuru; Takano, Keisuke; Nakajima, Makoto; Hangyo, Masanori; Yanagi, Hisao

    2016-03-01

    Plasmonic chiral metasurfaces with pinwheel-like structures are fabricated on silver films using a focused ion-beam milling technique. In time-domain spectroscopy, we observe terahertz (THz) wave emission from metasurfaces irradiated by a near-infrared Ti:sapphire ultrashort pulsed laser. The origin of the THz wave generation is likely to be tunnelling ionization accompanied with photoelectron acceleration by ponderomotive force. Numerical simulation is carried out toward improvement of the chiral metasurfaces for better emission of circularly polarized THz waves.

  13. Disoriented chiral condensate: Theory and phenomenology

    SciTech Connect

    Bjorken, J.D.

    1997-12-01

    These notes are an abbreviated version of lectures given at the 1997 Zakopane School. They contain two topics. The first is a description in elementary terms of the basic ideas underlying the speculative hypothesis that pieces of strong-interaction vacuum with a rotated chiral order parameter, disoriented chiral condensate or DCC, might be produced in high energy elementary particle collisions. The second topic is a discussion of the phenomenological techniques which may be applied to data in order to experimentally search for the existence of DCC.

  14. Topologically nontrivial time-dependent chiral condensates

    SciTech Connect

    Suzuki, M.

    1996-11-01

    Topologically nontrivial time-dependent solutions of the classical nonlinear {sigma} model are studied as candidates of the disoriented chiral condensate (DCC) in 3+1 dimensions. Unlike the analytic solutions so far discussed, these solutions cannot be transformed into isospin-uniform ones by chiral rotations. If they are produced as DCC{close_quote}s, they can be detected by a distinct pattern in the angle-rapidity distribution of the neutral-to-charged pion ratio. {copyright} {ital 1996 The American Physical Society.}

  15. Thermal perturbation of the Sun

    NASA Technical Reports Server (NTRS)

    Twigg, L. W.; Endal, A. S.

    1981-01-01

    An investigation of thermal perturbations of the solar convective zone via changes in the mixing length parameter were carried out, with a view toward understanding the possible solar radius and luminosity changes cited in the literature. The results show that: (a) a single perturbation of alpha is probably not the cause of the solar radius change and (b) the parameter W = d lambda nR./d lambda nL. can not be characterized by a single value, as implied in recent work.

  16. CHIRAL LIMIT AND LIGHT QUARK MASSES IN 2+1 FLAVOR DOMAIN WALL QCD.

    SciTech Connect

    SCHOLZ,E.; LIN, M.

    2007-07-30

    We present results for meson masses and decay constants measured on 24{sup 3} x 64 lattices using the domain wall fermion formulation with an extension of the fifth dimension of L{sub s} = 16 for N{sub f} 2 + 1 dynamical quark flavors. The lightest dynamical meson mass in our set-up is around 331MeV. while partially quenched mesons reach masses as low as 250MeV. The applicability of SU(3) x SU(3) and SU(2) x SU(2) (partially quenched) chiral perturbation theory will be compared and we quote values for the low-energy constants from both approaches. We will extract the average light quark and strange quark masses and use a non-perturbative renormalization technique (RI/MOM) to quote their physical values. The pion and kaon decay constants are determined at those values from our chiral fits and their ratio is used to obtain the CKM-matrix element |V{sub us}|. The results presented here include statistical errors only.

  17. Dispersion relations for electromagnetic wave propagation in chiral plasmas

    SciTech Connect

    Gao, M. X.; Guo, B. Peng, L.; Cai, X.

    2014-11-15

    The dispersion relations for electromagnetic wave propagation in chiral plasmas are derived using a simplified method and investigated in detail. With the help of the dispersion relations for each eignwave, we explore how the chiral plasmas exhibit negative refraction and investigate the frequency region for negative refraction. The results show that chirality can induce negative refraction in plasmas. Moreover, both the degree of chirality and the external magnetic field have a significant effect on the critical frequency and the bandwidth of the frequency for negative refraction in chiral plasmas. The parameter dependence of the effects is calculated and discussed.

  18. Multiple chiral doublet bands of identical configuration in 103Rh.

    PubMed

    Kuti, I; Chen, Q B; Timár, J; Sohler, D; Zhang, S Q; Zhang, Z H; Zhao, P W; Meng, J; Starosta, K; Koike, T; Paul, E S; Fossan, D B; Vaman, C

    2014-07-18

    Three sets of chiral doublet band structures have been identified in the ^{103}Rh nucleus. The properties of the observed chiral doublet bands are in good agreement with theoretical results obtained using constrained covariant density functional theory and particle rotor model calculations. Two of them belong to an identical configuration and provide the first experimental evidence for a novel type of multiple chiral doublets, where an "excited" chiral doublet of a configuration is seen together with the "yrast" one. This observation shows that the chiral geometry in nuclei can be robust against the increase of the intrinsic excitation energy. PMID:25083635

  19. Chirally Symmetric but Confined Hadrons at Finite Density

    NASA Astrophysics Data System (ADS)

    Ya. Glozman, L.; Wagenbrunn, R. F.

    At a critical finite chemical potential and low temperature QCD undergoes the chiral restoration phase transition. The folklore tradition is that simultaneously hadrons are deconfined and there appears the quark matter. We demonstrate that it is possible to have confined but chirally symmetric hadrons at a finite chemical potential and hence beyond the chiral restoration point at a finite chemical potential and low temperature there could exist a chirally symmetric matter consisting of chirally symmetric but confined hadrons. If it does happen in QCD, then the QCD phase diagram should be reconsidered with obvious implications for heavy ion programs and astrophysics.

  20. Synthesis of a Chiral Crystal Form of MOF-5, CMOF-5, by Chiral Induction.

    PubMed

    Zhang, Shi-Yuan; Li, Dan; Guo, Dong; Zhang, Hui; Shi, Wei; Cheng, Peng; Wojtas, Lukasz; Zaworotko, Michael J

    2015-12-16

    Chiral variants of the prototypal metal-organic framework MOF-5, Λ-CMOF-5 and Δ-CMOF-5, have been synthesized by preparing MOF-5 in the presence of L-proline or D-proline, respectively. CMOF-5 crystallizes in chiral space group P213 instead of Fm3̅m as exhibited by MOF-5. The phase purity of CMOF-5 was validated by single-crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, N2 adsorption, microanalysis, and solid-state vibrational circular dichroism. CMOF-5 undergoes a reversible single crystal-to-single crystal phase change to MOF-5 when immersed in a variety of organic solvents, although N-methyl-2-pyrrolidone (NMP) does not induce loss of chirality. Indeed, MOF-5 undergoes chiral induction when immersed in NMP, affording racemic CMOF-5. PMID:26606156

  1. When Chiral Photons Meet Chiral Fermions: Photoinduced Anomalous Hall Effects in Weyl Semimetals.

    PubMed

    Chan, Ching-Kit; Lee, Patrick A; Burch, Kenneth S; Han, Jung Hoon; Ran, Ying

    2016-01-15

    The Weyl semimetal is characterized by three-dimensional linear band touching points called Weyl nodes. These nodes come in pairs with opposite chiralities. We show that the coupling of circularly polarized photons with these chiral electrons generates a Hall conductivity without any applied magnetic field in the plane orthogonal to the light propagation. This phenomenon comes about because with all three Pauli matrices exhausted to form the three-dimensional linear dispersion, the Weyl nodes cannot be gapped. Rather, the net influence of chiral photons is to shift the positions of the Weyl nodes. Interestingly, the momentum shift is tightly correlated with the chirality of the node to produce a net anomalous Hall signal. Application of our proposal to the recently discovered TaAs family of Weyl semimetals leads to an order-of-magnitude estimate of the photoinduced Hall conductivity which is within the experimentally accessible range. PMID:26824561

  2. Geometric Triangular Chiral Hexagon Crystal-Like Complexes Organization in Pathological Tissues Biological Collision Order

    PubMed Central

    Díaz, Jairo A.; Jaramillo, Natalia A.; Murillo, Mauricio F.

    2007-01-01

    The present study describes and documents self-assembly of geometric triangular chiral hexagon crystal like complex organizations (GTCHC) in human pathological tissues.The authors have found this architectural geometric expression at macroscopic and microscopic levels mainly in cancer processes. This study is based essentially on macroscopic and histopathologic analyses of 3000 surgical specimens: 2600 inflammatory lesions and 400 malignant tumours. Geometric complexes identified photographically at macroscopic level were located in the gross surgical specimen, and these areas were carefully dissected. Samples were taken to carry out histologic analysis. Based on the hypothesis of a collision genesis mechanism and because it is difficult to carry out an appropriate methodological observation in biological systems, the authors designed a model base on other dynamic systems to obtain indirect information in which a strong white flash wave light discharge, generated by an electronic device, hits over the lines of electrical conductance structured in helicoidal pattern. In their experimental model, the authors were able to reproduce and to predict polarity, chirality, helicoid geometry, triangular and hexagonal clusters through electromagnetic sequential collisions. They determined that similar events among constituents of extracelular matrix which drive and produce piezoelectric activity are responsible for the genesis of GTCHC complexes in pathological tissues. This research suggests that molecular crystals represented by triangular chiral hexagons derived from a collision-attraction event against collagen type I fibrils emerge at microscopic and macroscopic scales presenting a lateral assembly of each side of hypertrophy helicoid fibers, that represent energy flow in cooperative hierarchically chiral electromagnetic interaction in pathological tissues and arises as a geometry of the equilibrium in perturbed biological systems. Further interdisciplinary studies must

  3. Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts

    PubMed Central

    Ariga, Katsuhiko; Richards, Gary J.; Ishihara, Shinsuke; Izawa, Hironori; Hill, Jonathan P.

    2010-01-01

    Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized. PMID:22163577

  4. AGK Rules in Perturbative QCD

    NASA Astrophysics Data System (ADS)

    Bartels, Jochen

    2006-06-01

    I summarize the present status of the AGK cutting rules in perturbative QCD. Particular attention is given to the application of the AGK analysis to diffraction and multiple scattering in DIS at HERA and to pp collisions at the LHC. I also discuss the bootstrap conditions which appear in pQCD.

  5. VHS Movies: Perturbations for Morphogenesis.

    ERIC Educational Resources Information Center

    Holmes, Danny L.

    This paper discusses the concept of a family system in terms of an interactive system of interrelated, interdependent parts and suggests that VHS movies can act as perturbations, i.e., change promoting agents, for certain dysfunctional family systems. Several distinct characteristics of a family system are defined with particular emphasis on…

  6. Adaptation Strategies in Perturbed /s/

    ERIC Educational Resources Information Center

    Brunner, Jana; Hoole, Phil; Perrier, Pascal

    2011-01-01

    The purpose of this work is to investigate the role of three articulatory parameters (tongue position, jaw position and tongue grooving) in the production of /s/. Six normal speakers' speech was perturbed by a palatal prosthesis. The fricative was recorded acoustically and through electromagnetic articulography in four conditions: (1) unperturbed,…

  7. Basics of QCD perturbation theory

    SciTech Connect

    Soper, D.E.

    1997-06-01

    This is an introduction to the use of QCD perturbation theory, emphasizing generic features of the theory that enable one to separate short-time and long-time effects. The author also covers some important classes of applications: electron-positron annihilation to hadrons, deeply inelastic scattering, and hard processes in hadron-hadron collisions. 31 refs., 38 figs.

  8. Generalized perturbations in neutrino mixing

    NASA Astrophysics Data System (ADS)

    Liao, Jiajun; Marfatia, D.; Whisnant, K.

    2015-10-01

    We derive expressions for the neutrino mixing parameters that result from complex perturbations on (1) the Majorana neutrino mass matrix (in the basis of charged lepton mass eigenstates) and on (2) the charged lepton mass matrix, for arbitrary initial (unperturbed) mixing matrices. In the first case, we find that the phases of the elements of the perturbation matrix, and the initial values of the Dirac and Majorana phases, strongly impact the leading-order corrections to the neutrino mixing parameters and phases. For experimentally compatible scenarios wherein the initial neutrino mass matrix has μ -τ symmetry, we find that the Dirac phase can take any value under small perturbations. Similarly, in the second case, perturbations to the charged lepton mass matrix can generate large corrections to the mixing angles and phases of the Pontecorvo-Maki-Nakagawa-Sakata (PMNS) matrix. As an illustration of our generalized procedure, we apply it to a situation in which nonstandard scalar and nonstandard vector interactions simultaneously affect neutrino oscillations.

  9. Seven topics in perturbative QCD

    SciTech Connect

    Buras, A.J.

    1980-09-01

    The following topics of perturbative QCD are discussed: (1) deep inelastic scattering; (2) higher order corrections to e/sup +/e/sup -/ annihilation, to photon structure functions and to quarkonia decays; (3) higher order corrections to fragmentation functions and to various semi-inclusive processes; (4) higher twist contributions; (5) exclusive processes; (6) transverse momentum effects; (7) jet and photon physics.

  10. Resurgence in η-deformed Principal Chiral Models

    NASA Astrophysics Data System (ADS)

    Demulder, Saskia; Dorigoni, Daniele; Thompson, Daniel C.

    2016-07-01

    We study the SU(2) Principal Chiral Model (PCM) in the presence of an integrable η-deformation. We put the theory on {R}× {S}^1 with twisted boundary conditions and then reduce the circle to obtain an effective quantum mechanics associated with the Whittaker-Hill equation. Using resurgent analysis we study the large order behaviour of perturbation theory and recover the fracton events responsible for IR renormalons. The fractons are modified from the standard PCM due to the presence of this η-deformation but they are still the constituents of uniton-like solutions in the deformed quantum field theory. We also find novel SL(2,{C}) saddles, thus strengthening the conjecture that the semi-classical expansion of the path integral gives rise to a resurgent transseries once written as a sum over Lefschetz thimbles living in a complexification of the field space. We conclude by connecting our quantum mechanics to a massive deformation of the {N} = 2 4-d gauge theory with gauge group SU(2) and N f = 2.

  11. Monopoles and fractional vortices in chiral superconductors

    PubMed Central

    Volovik, G. E.

    2000-01-01

    I discuss two exotic objects that must be experimentally identified in chiral superfluids and superconductors. These are (i) the vortex with a fractional quantum number (N = 1/2 in chiral superfluids, and N = 1/2 and N = 1/4 in chiral superconductors), which plays the part of the Alice string in relativistic theories and (ii) the hedgehog in the ^l field, which is the counterpart of the Dirac magnetic monopole. These objects of different dimensions are topologically connected. They form the combined object that is called a nexus in relativistic theories. In chiral superconductors, the nexus has magnetic charge emanating radially from the hedgehog, whereas the half-quantum vortices play the part of the Dirac string. Each half-quantum vortex supplies the fractional magnetic flux to the hedgehog, representing 1/4 of the “conventional” Dirac string. I discuss the topological interaction of the superconductor's nexus with the ‘t Hooft–Polyakov magnetic monopole, which can exist in Grand Unified Theories. The monopole and the hedgehog with the same magnetic charge are topologically confined by a piece of the Abrikosov vortex. Such confinement makes the nexus a natural trap for the magnetic monopole. Other properties of half-quantum vortices and monopoles are discussed as well, including fermion zero modes. PMID:10716980

  12. Chiral damping of magnetic domain walls.

    PubMed

    Jué, Emilie; Safeer, C K; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles

    2016-03-01

    Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics, current-induced spin-orbit torques and some topological magnetic structures. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii-Moriya interaction (DMI) exhibit identical spatial symmetry. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. ). PMID:26689141

  13. Dispersing carbon nanotubes by chiral network surfactants.

    PubMed

    Lin, Pengcheng; Cong, Yuehua; Zhang, Baoyan

    2015-04-01

    Chiral network surfactants (CNSs) possessing miscibility with carbon nanotubes (CNTs) and chiral materials are applied to disperse CNTs. Ultraviolet-visible absorption spectroscopy is used to quantitatively determine the CNT concentration in homogeneous CNT-CNS dispersions, results indicate that CNSs with more mole fraction of polycyclic conjugated structure have better ability to load and disperse CNTs and the maximal concentration reaches 0.79 mg mL(-1). Fourier transform infrared imaging system is utilized to analyze the dispersibility of CNTs in CNT-CNS composites, and CNS with 6 mol % nonmesogens (S6) induces the best dispersibility. The CNT doped CNSs exhibit lower glass transition temperature, strengthened thermal stability, decreased the thermochromic temperature and enriched reflected colors of CNSs. Furthermore, S6 are used as a promoter to disperse CNTs in chiral host, here, a left-handed chiral liquid crystal (CLC) is selected, the miscibility between CNTs and CLCs is studied by polarized optical microscope, and CNTs can be effectively dispersed in CLCs by S6. The CNT dispersed CLCs can exhibit a faster electro-optical response process than neat CLCs. PMID:25789867

  14. Excitations in the chiral spin liquid

    NASA Astrophysics Data System (ADS)

    Schroeter, Darrell

    2009-03-01

    Recently, a spin-Hamiltonian was presented [Schroeter et al, Phys. Rev. Lett. 99, 097202 (2007)] for which the chiral spin liquid is the exact ground state. This poster will present a numerical study of the excitations of the model, including results obtained by exact diagonalization of the model on 16 and 25-site lattices.

  15. Skyrme-Einstein closed cosmic chiral strings

    SciTech Connect

    Rybakov, Yu. P. Ivanova, I. S.

    2007-07-15

    Within the theory of general relativity, the configuration of a closed string (vortex) characterized by a topological charge of the degree type is described for the Skyrme-Einstein SU (2) chiral model. In the approximation of a large vortex-closure radius (a), a solution to equations of motion is obtained, along with estimates for the vortex energy and radius.

  16. Quantum group extended chiral p-models

    NASA Astrophysics Data System (ADS)

    Hadjiivanov, L. K.; Paunov, R. R.; Todorov, I. T.

    1991-06-01

    The quantum symmetry group U q of an extended chiral conformal model is determined by the requirement that symmetry transformations commute with braid group statistics operators and by the relation between fusion rules and tensor product expansions of a certain class of U 4 representations. For thermal minimal " p-models", involving no more than p - 1 unitary lowest weight representations of the Virasoro algebra Vir, U 4 is the quantum universal enveloping (QUE) algebra U 4(sl(2)) with deformation parameter q satisfying q + q-1 = 2 cos π/ p ( qp = - 1, p = 4, 5,…). To each 2-dimensional local field labelled by a pair of nonnegative integers v, v¯ (0 ⩽ v, v¯ ⩽ p - 2) we make correspond an analytic chiral field φv, of weight Δ vand q- spin I v¯. The correlation functions of φv, transform under an 1-dimensional unitary representation of the braid group. As a result we reproduce the ADE classification of 2-dimensional p models in terms of their extended chiral counterparts. It turns out that U q-extended chiral p-models always involve non-unitary and indecomposable representations of Vir.

  17. Chiral electron transport in CVD bilayer graphene

    NASA Astrophysics Data System (ADS)

    Lee, Kyunghoon; Eo, Yun Suk; Kurdak, Cagliyan; Zhong, Zhaohui

    2014-03-01

    Charge carriers in bilayer graphene have a parabolic energy spectrum. Due to this band structure they are massive quasiparticles having a finite density of state at zero energy like other non-relativistic charge carriers in conventional two dimensional materials. However, they are massive Dirac fermions which have a chiral nature similar to the case of massless Dirac fermions in single layer graphene. Coupling of pseudospin and motion of charge carrier via chirality can result in dramatic consequence for transport in bipolar regime like Klein tunneling, Fabry-Perot interference, collimation of charge carrier, Veslago lens, etc. However, little attention has been paid to chiral dependent electron transport in bilayer graphene. Here we study these properties by probing phase coherent transport behavior in CVD bilayer graphene devices with sub-200nm channel length. Complex Fabry-Perot interference patterns are observed in resonant cavities defined by local gating. By applying Fourier analysis technique, we successfully analyze and identify the origin of each individual interference pattern in bipolar and monopolar regime. Our initial results also hint at the observation of cloaking of electronic states against chiral electrons in bilayer graphene.

  18. Weighted power counting and chiral dimensional regularization

    NASA Astrophysics Data System (ADS)

    Anselmi, Damiano

    2014-06-01

    We define a modified dimensional-regularization technique that overcomes several difficulties of the ordinary technique, and is specially designed to work efficiently in chiral and parity violating quantum field theories, in arbitrary dimensions greater than 2. When the dimension of spacetime is continued to complex values, spinors, vectors and tensors keep the components they have in the physical dimension; therefore, the γ matrices are the standard ones. Propagators are regularized with the help of evanescent higher-derivative kinetic terms, which are of the Majorana type in the case of chiral fermions. If the new terms are organized in a clever way, weighted power counting provides an efficient control on the renormalization of the theory, and allows us to show that the resulting chiral dimensional regularization is consistent to all orders. The new technique considerably simplifies the proofs of properties that hold to all orders, and makes them suitable to be generalized to wider classes of models. Typical examples are the renormalizability of chiral gauge theories and the Adler-Bardeen theorem. The difficulty of explicit computations, on the other hand, may increase.

  19. Chiral separation and twin-beam photonics

    NASA Astrophysics Data System (ADS)

    Bradshaw, David S.; Andrews, David L.

    2016-03-01

    It is well-known that, in a homogeneous fluid medium, most optical means that afford discrimination between molecules of opposite handedness are intrinsically weak effects. The reason is simple: the wide variety of origins for differential response commonly feature real or virtual electronic transitions that break a parity condition. Despite being electric dipole allowed, they manifest the chirality of the material in which they occur by breaking a selection rule that would otherwise preclude the simultaneous involvement of magnetic dipole or electric quadrupole forms of coupling. Although the latter are typically weaker than electric dipole effects by several orders of magnitude, it is the involvement of these weak forms of interaction that are responsible for chiral sensitivity. There have been a number of attempts to cleverly exploit novel optical configurations to enhance the relative magnitude - and hence potentially the efficiency - of chiral discrimination. The prospect of success in any such venture is enticing, because of the huge impact that such an advance might be expected to have in the health, food and medical sectors. Some of these proposals have utilized mirror reflection, and others surface plasmon coupling, or optical binding methods. Several recent works in the literature have drawn attention to a further possibility: the deployment of optical beam interference as a means to achieve chiral separations of sizeable extent. In this paper the underlying theory is fully developed to identify the true scope and limitations of such an approach.

  20. Efficient Biocatalytic Synthesis of Chiral Chemicals.

    PubMed

    Zhang, Zhi-Jun; Pan, Jiang; Ma, Bao-Di; Xu, Jian-He

    2016-01-01

    Chiral chemicals are a group of important chiral synthons for the synthesis of a series of pharmaceuticals, agrochemicals, and fine chemicals. In past decades, a number of biocatalytic approaches have been developed for the green and effective synthesis of various chiral chemicals. However, the practical application of these biocatalytic processes is still hindered by the lack of highly efficient and robust biocatalysts, which usually results in the low volumetric productivity and high cost of the bioprocesses. Further step forward of biocatalysis in industrial application strongly requires the development of versatile and highly efficient biocatalysts, aiming to increase the process efficiency and facilitate the downstream processing. Recently, the fast growth of genome sequences in the database in post-genomic era offers great opportunities for accessing numerous biocatalysts with practical application potential, and the so-called genome mining approach provides time-effective and highly specific strategy for the fast identification of target enzymes with desired properties and outperforms the traditional screening of soil samples for microbial enzyme producers of interest. A number of biocatalytic processes with industrial application potential were developed thereafter. Further development of protein engineering strategies, process optimization, and cooperative work between biologists, organic chemists, and engineers is expected to make biocatalysis technology the first choice approach for the eco-friendly, highly efficient, and cost-effective synthesis of chiral chemicals in the near future. PMID:25537446

  1. Chiral anomaly and transport in Weyl metals

    NASA Astrophysics Data System (ADS)

    Burkov, A. A.

    2015-03-01

    We present an overview of our recent work on transport phenomena in Weyl metals, which may be connected to their nontrivial topological properties, particularly to chiral anomaly. We argue that there are two basic phenomena, which are related to chiral anomaly in Weyl metals: anomalous Hall effect (AHE) and chiral magnetic effect (CME). While AHE is in principle present in any ferromagnetic metal, we demonstrate that a magnetic Weyl metal is distinguished from an ordinary ferromagnetic metal by the absence of the extrinsic and the Fermi surface part of the intrinsic contributions to the AHE, as long as the Fermi energy is sufficiently close to the Weyl nodes. The AHE in a Weyl metal is thus shown to be a purely intrinsic, universal property, fully determined by the location of the Weyl nodes in the first Brillouin zone. In other words, a ferromagnetic Weyl metal may be thought of as the only example of a ferromagnetic metal with a purely intrinsic AHE. We further develop a fully microscopic theory of diffusive magnetotransport in Weyl metals. We derive coupled diffusion equations for the total and axial (i.e. node-antisymmetric) charge densities and show that chiral anomaly manifests as a magnetic-field-induced coupling between them. We demonstrate that an experimentally-observable consequence of CME in magnetotransport in Weyl metals is a quadratic negative magnetoresistance, which will dominate all other contributions to magnetoresistance under certain conditions and may be regarded as a smoking-gun transport characteristic, unique to Weyl metals.

  2. Chiral anomaly and transport in Weyl metals.

    PubMed

    Burkov, A A

    2015-03-25

    We present an overview of our recent work on transport phenomena in Weyl metals, which may be connected to their nontrivial topological properties, particularly to chiral anomaly. We argue that there are two basic phenomena, which are related to chiral anomaly in Weyl metals: anomalous Hall effect (AHE) and chiral magnetic effect (CME). While AHE is in principle present in any ferromagnetic metal, we demonstrate that a magnetic Weyl metal is distinguished from an ordinary ferromagnetic metal by the absence of the extrinsic and the Fermi surface part of the intrinsic contributions to the AHE, as long as the Fermi energy is sufficiently close to the Weyl nodes. The AHE in a Weyl metal is thus shown to be a purely intrinsic, universal property, fully determined by the location of the Weyl nodes in the first Brillouin zone. In other words, a ferromagnetic Weyl metal may be thought of as the only example of a ferromagnetic metal with a purely intrinsic AHE. We further develop a fully microscopic theory of diffusive magnetotransport in Weyl metals. We derive coupled diffusion equations for the total and axial (i.e. node-antisymmetric) charge densities and show that chiral anomaly manifests as a magnetic-field-induced coupling between them. We demonstrate that an experimentally-observable consequence of CME in magnetotransport in Weyl metals is a quadratic negative magnetoresistance, which will dominate all other contributions to magnetoresistance under certain conditions and may be regarded as a smoking-gun transport characteristic, unique to Weyl metals. PMID:25712419

  3. Chiral damping of magnetic domain walls

    NASA Astrophysics Data System (ADS)

    Jué, Emilie; Safeer, C. K.; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles

    2016-03-01

    Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics, current-induced spin-orbit torques and some topological magnetic structures. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii-Moriya interaction (DMI) exhibit identical spatial symmetry. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. ).

  4. Concise theory of chiral lipid membranes

    NASA Astrophysics Data System (ADS)

    Tu, Z. C.; Seifert, U.

    2007-09-01

    A theory of chiral lipid membranes is proposed on the basis of a concise free energy density which includes the contributions of the bending and the surface tension of membranes, as well as the chirality and orientational variation of tilting molecules. This theory is consistent with the previous experiments [J.M. Schnur , Science 264, 945 (1994); M.S. Spector , Langmuir 14, 3493 (1998); Y. Zhao, , Proc. Natl. Acad. Sci. USA 102, 7438 (2005)] on self-assembled chiral lipid membranes of DC8,9PC . A torus with the ratio between its two generated radii larger than 2 is predicted from the Euler-Lagrange equations. It is found that tubules with helically modulated tilting state are not admitted by the Euler-Lagrange equations and that they are less energetically favorable than helical ripples in tubules. The pitch angles of helical ripples are theoretically estimated to be about 0° and 35°, which are close to the most frequent values 5° and 28° observed in the experiment [N. Mahajan , Langmuir 22, 1973 (2006)]. Additionally, the present theory can explain twisted ribbons of achiral cationic amphiphiles interacting with chiral tartrate counterions. The ratio between the width and pitch of twisted ribbons is predicted to be proportional to the relative concentration difference of left- and right-handed enantiomers in the low relative concentration difference region, which is in good agreement with the experiment [R. Oda , Nature (London) 399, 566 (1999)].

  5. The development of chiral nematic mesoporous materials.

    PubMed

    Kelly, Joel A; Giese, Michael; Shopsowitz, Kevin E; Hamad, Wadood Y; MacLachlan, Mark J

    2014-04-15

    Cellulose nanocrystals (CNCs) are obtained from the sulfuric acid-catalyzed hydrolysis of bulk cellulose. The nanocrystals have diameters of ~5-15 nm and lengths of ~100-300 nm (depending on the cellulose source and hydrolysis conditions). This lightweight material has mostly been investigated to reinforce composites and polymers because it has remarkable strength that rivals carbon nanotubes. But CNCs have an additional, less explored property: they organize into a chiral nematic (historically referred to as cholesteric) liquid crystal in water. When dried into a thin solid film, the CNCs retain the helicoidal chiral nematic order and assemble into a layered structure where the CNCs have aligned orientation within each layer, and their orientation rotates through the stack with a characteristic pitch (repeating distance). The cholesteric ordering can act as a 1-D photonic structure, selectively reflecting circularly polarized light that has a wavelength nearly matching the pitch. During CNC self-assembly, it is possible to add sol-gel precursors, such as Si(OMe)4, that undergo hydrolysis and condensation as the solvent evaporates, leading to a chiral nematic silica/CNC composite material. Calcination of the material in air destroys the cellulose template, leaving a high surface area mesoporous silica film that has pore diameters of ~3-10 nm. Importantly, the silica is brilliantly iridescent because the pores in its interior replicate the chiral nematic structure. These films may be useful as optical filters, reflectors, and membranes. In this Account, we describe our recent research into mesoporous films with chiral nematic order. Taking advantage of the chiral nematic order and nanoscale of the CNC templates, new functional materials can be prepared. For example, heating the silica/CNC composites under an inert atmosphere followed by removal of the silica leaves highly ordered, mesoporous carbon films that can be used as supercapacitor electrodes. The composition

  6. Role of pseudoephedrine as chiral auxiliary in the "acetate-type" aldol reaction with chiral aldehydes; asymmetric synthesis of highly functionalized chiral building blocks.

    PubMed

    Ocejo, Marta; Carrillo, Luisa; Vicario, Jose L; Badía, Dolores; Reyes, Efraim

    2011-01-21

    We have studied in depth the aldol reaction between acetamide enolates and chiral α-heterosubstituted aldehydes using pseudoephedrine as chiral auxiliary under double stereodifferentiation conditions, showing that high diastereoselectivities can only be achieved under the matched combination of reagents and provided that the α-heteroatom-containing substituent of the chiral aldehyde is conveniently protected. Moreover, the obtained highly functionalized aldols have been employed as very useful starting materials for the stereocontrolled preparation of other interesting compounds and chiral building blocks such as pyrrolidines, indolizidines, and densely functionalized β-hydroxy and β-amino ketones using simple and high-yielding methodologies. PMID:21188970

  7. A Cross-chiral RNA Polymerase Ribozyme

    PubMed Central

    Sczepanski, Jonathan T.; Joyce, Gerald F.

    2014-01-01

    Thirty years ago it was shown that the non-enzymatic, template-directed polymerization of activated mononucleotides proceeds readily in a homochiral system, but is severely inhibited by the presence of the opposing enantiomer.1 This finding poses a severe challenge for the spontaneous emergence of RNA-based life, and has led to the suggestion that either RNA was preceded by some other genetic polymer that is not subject to chiral inhibition2 or chiral symmetry was broken through chemical processes prior to the origin of RNA-based life.3,4 Once an RNA enzyme arose that could catalyze the polymerization of RNA, it would have been possible to distinguish among the two enantiomers, enabling RNA replication and RNA-based evolution to occur. It is commonly thought that the earliest RNA polymerase and its substrates would have been of the same handedness, but this is not necessarily the case. Replicating D-and L-RNA molecules may have emerged together, based on the ability of structured RNAs of one handedness to catalyze the templated polymerization of activated mononucleotides of the opposite handedness. Such a cross-chiral RNA polymerase has now been developed using in vitro evolution. The D-RNA enzyme, consisting of 83 nucleotides, catalyzes the joining of L-mono- or oligonucleotide substrates on a complementary L-RNA template, and similarly for the L-enzyme with D-substrates and a D-template. Chiral inhibition is avoided because the 106-fold rate acceleration of the enzyme only pertains to cross-chiral substrates. The enzyme's activity is sufficient to generate full-length copies of its enantiomer through the templated joining of 11 component oligonucleotides. PMID:25363769

  8. Chiral Sensitivity in Electron-Molecule Interactions

    NASA Astrophysics Data System (ADS)

    Dreiling, Joan

    2015-09-01

    All molecular forms of life possess a chiral asymmetry, with amino acids and sugars found respectively in L- and D-enantiomers only. The primordial origin of this enantiomeric excess is unknown. One possible explanation is given by the Vester- Ulbricht hypothesis, which suggests that left-handed electrons present in beta-radiation, produced by parity-violating weak decays, interacted with biological precursors and preferentially destroyed one of the two enantiomers. Experimental tests of this idea have thus far yielded inconclusive results. We show direct evidence for chirally-dependent bond breaking through a dissociative electron attachment (DEA) reaction when spin-polarized electrons are incident on gas-phase chiral molecules. This provides unambiguous evidence for a well-defined, chirally-sensitive destructive molecular process and, as such, circumstantial evidence for the Vester-Ulbricht hypothesis. I will also present the results of our systematic study of the DEA asymmetry for different chiral halocamphor molecules. Three halocamphor molecules were investigated: 3-bromocamphor (C10H15BrO), 3-iodocamphor(C10H15IO), and 10-iodocamphor. The DEA asymmetries collected for bromocamphor and iodocamphor are qualitatively different, suggesting that the atomic number of the heaviest atom in the molecule plays a crucial role in the asymmetric interactions. The DEA asymmetry data for 3- and 10-iodocamphor have the same qualitative behavior, but the 10-iodocamphor asymmetry is about twice as large at the lowest energies investigated, so the location of the heavy atom in the camphor molecule also affects the asymmetries. This work was performed at the University of Nebraska-Lincoln. This project is funded by NSF Grant PHY-1206067.

  9. Au nanorod helical superstructures with designed chirality.

    PubMed

    Lan, Xiang; Lu, Xuxing; Shen, Chenqi; Ke, Yonggang; Ni, Weihai; Wang, Qiangbin

    2015-01-14

    A great challenge for nanotechnology is to controllably organize anisotropic nanomaterials into well-defined three-dimensional superstructures with customized properties. Here we successfully constructed anisotropic Au nanorod (AuNR) helical superstructures (helices) with tailored chirality in a programmable manner. By designing the 'X' pattern of the arrangement of DNA capturing strands (15nt) on both sides of a two-dimensional DNA origami template, AuNRs functionalized with the complementary DNA sequences were positioned on the origami and were assembled into AuNR helices with the origami intercalated between neighboring AuNRs. Left-handed (LH) and right-handed (RH) AuNR helices were conveniently accomplished by solely tuning the mirrored-symmetric 'X' patterns of capturing strands on the origami. The inter-rod distance was precisely defined as 14 nm and inter-rod angle as 45°, thus a full helix contains 9 AuNRs with its length up to about 220 nm. By changing the AuNR/origami molar ratio in the assembly system, the average number of AuNR in the helices was tuned from 2 to 4 and 9. Intense chiroptical activities arose from the longest AuNR helices with a maximum anisotropy factor of ∼0.02, which is highly comparable to the reported macroscopic AuNR assemblies. We expect that our strategy of origami templated assembly of anisotropic chiral superstructures would inspire the bottom-up fabrication of optically active nanostructures and shed light on a variety of applications, such as chiral fluids, chiral signal amplification, and fluorescence combined chiral spectroscopy. PMID:25516475

  10. Chemical synthesis of chiral conducting polymers

    DOEpatents

    Wang, Hsing-Lin; Li, Wenguang

    2009-01-13

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts.The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.10.sup.3 degree-cm.sup.2/decimole to about 700.times.10.sup.3 degree-cm.sup.2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  11. Chemical synthesis of chiral conducting polymers

    DOEpatents

    Wang, Hsing-Lin; Li, Wenguang

    2006-07-11

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts. The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.103 degree-cm2/decimole to about 700.times.103 degree-cm2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  12. Enantioselective Recognition for Many Different Kinds of Chiral Guests by One Chiral Receptor Based on Tetraphenylethylene Cyclohexylbisurea.

    PubMed

    Xiong, Jia-Bin; Xie, Wen-Zhao; Sun, Jian-Ping; Wang, Jin-Hua; Zhu, Zhi-Hua; Feng, Hai-Tao; Guo, Dong; Zhang, Hui; Zheng, Yan-Song

    2016-05-01

    A neutral chiral receptor based on TPE cyclohexylbisurea was synthesized and could discriminate the enantiomers of many different kinds of chiral reagents, including chiral acidic compounds, basic compounds, amino acids, and even neutral alcohols. The (1)H NMR spectra disclosed that the ability of chiral recognition could be ascribed to the multiple hydrogen bonds and CH-π interactions between the TPE urea receptor and the enantiomer of the chiral guest, which led to the selective aggregation of the receptor with one of the two enantiomers. This result exhibited a great potential in enantiomer discernment and high-throughput analysis of enantiomer composition of these chiral analytes by one chiral AIE molecule. PMID:27032054

  13. Chiral anomaly and the BaBar and Belle measurements of the γγ*-->π0 transition form factor

    NASA Astrophysics Data System (ADS)

    Pham, T. N.

    2012-10-01

    The recent BaBar measurements of the γγ*→π0 transition form factor show spectacular deviation from perturbative QCD prediction for large space-like Q2 up to 34GeV2. In this talk, I would like to discuss a recent work on the chiral anomaly effects in the γγ*→π0 transition form factor F(Q2) at large momentum squared Q2. Using PCAC and the Adler-Bell-Jackiw chiral anomaly triangle graph, we find that, F(Q2) at large Q2 behaves as (m2/Q2)×(ln(Q2/m2))2 and is in striking agreement with the BaBar data with m = 135MeV which also reproduces very well the CLEO data at lower Q2. The new Belle measurements could also be fitted with m = 120MeV.

  14. Significant Enhancement of the Chiral Correlation Length in Nematic Liquid Crystals by Gold Nanoparticle Surfaces Featuring Axially Chiral Binaphthyl Ligands.

    PubMed

    Mori, Taizo; Sharma, Anshul; Hegmann, Torsten

    2016-01-26

    Chirality is a fundamental scientific concept best described by the absence of mirror symmetry and the inability to superimpose an object onto its mirror image by translation and rotation. Chirality is expressed at almost all molecular levels, from single molecules to supramolecular systems, and present virtually everywhere in nature. Here, to explore how chirality propagates from a chiral nanoscale surface, we study gold nanoparticles functionalized with axially chiral binaphthyl molecules. In particular, we synthesized three enantiomeric pairs of chiral ligand-capped gold nanoparticles differing in size, curvature, and ligand density to tune the chirality transfer from nanoscale solid surfaces to a bulk anisotropic liquid crystal medium. Ultimately, we are examining how far the chirality from a nanoparticle surface reaches into a bulk material. Circular dichroism spectra of the gold nanoparticles decorated with binaphthyl thiols confirmed that the binaphthyl moieties form a cisoid conformation in isotropic organic solvents. In the chiral nematic liquid crystal phase, induced by dispersing the gold nanoparticles into an achiral anisotropic nematic liquid crystal solvent, the binaphthyl moieties on the nanoparticle surface form a transoid conformation as determined by imaging the helical twist direction of the induced cholesteric phase. This suggests that the ligand density on the nanoscale metal surfaces provides a dynamic space to alter and adjust the helicity of binaphthyl derivatives in response to the ordering of the surrounding medium. The helical pitch values of the induced chiral nematic phase were determined, and the helical twisting power (HTP) of the chiral gold nanoparticles calculated to elucidate the chirality transfer efficiency of the binaphthyl ligand capped gold nanoparticles. Remarkably, the HTP increases with increasing diameter of the particles, that is, the efficiency of the chirality transfer of the binaphthyl units bound to the nanoparticle

  15. Engineering chiral density waves and topological band structures by multiple-Q superpositions of collinear up-up-down-down orders

    NASA Astrophysics Data System (ADS)

    Hayami, Satoru; Ozawa, Ryo; Motome, Yukitoshi

    2016-07-01

    Magnetic orders characterized by multiple ordering vectors harbor noncollinear and noncoplanar spin textures and can be a source of unusual electronic properties through the spin Berry phase mechanism. We theoretically show that such multiple-Q states are stabilized in itinerant magnets in the form of superpositions of collinear up-up-down-down (UUDD) spin states, which accompany the density waves of vector and scalar chirality. The result is drawn by examining the ground state of the Kondo lattice model with classical localized moments, especially when the Fermi surface is tuned to be partially nested by the symmetry-related commensurate vectors. We unveil the instability toward a double-Q UUDD state with vector chirality density waves on the square lattice and a triple-Q UUDD state with scalar chirality density waves on the triangular lattice, using the perturbative theory and variational calculations. The former double-Q state is also confirmed by large-scale Langevin dynamics simulations. We also show that, for a sufficiently large exchange coupling, the chirality density waves can induce rich nontrivial topology of electronic structures, such as the massless Dirac semimetal, Chern insulator with quantized topological Hall response, and peculiar edge states which depend on the phase of chirality density waves at the edges.

  16. Memorized chiral arrangement of gemini surfactant assemblies in nanometric hybrid organic-silica helices.

    PubMed

    Ryu, Naoya; Okazaki, Yutaka; Hirai, Kana; Takafuji, Makoto; Nagaoka, Shoji; Pouget, Emilie; Ihara, Hirotaka; Oda, Reiko

    2016-04-30

    Hybrid nanohelices were obtained from silicification of self-assemblies of gemini surfactants with tartrate counterions. The chiral arrangement of these non-chiral gemini surfactants was preserved in the silica matrix even after the counterion exchange for a non-chiral bromide, and was capable of inducing the chiral organisation of a non-chiral dye, methyl orange. PMID:26961377

  17. Vector perturbations of galaxy number counts

    NASA Astrophysics Data System (ADS)

    Durrer, Ruth; Tansella, Vittorio

    2016-07-01

    We derive the contribution to relativistic galaxy number count fluctuations from vector and tensor perturbations within linear perturbation theory. Our result is consistent with the the relativistic corrections to number counts due to scalar perturbation, where the Bardeen potentials are replaced with line-of-sight projection of vector and tensor quantities. Since vector and tensor perturbations do not lead to density fluctuations the standard density term in the number counts is absent. We apply our results to vector perturbations which are induced from scalar perturbations at second order and give numerical estimates of their contributions to the power spectrum of relativistic galaxy number counts.

  18. Cosmological perturbations in unimodular gravity

    SciTech Connect

    Gao, Caixia; Brandenberger, Robert H.; Cai, Yifu; Chen, Pisin E-mail: rhb@hep.physics.mcgill.ca E-mail: chen@slac.stanford.edu

    2014-09-01

    We study cosmological perturbation theory within the framework of unimodular gravity. We show that the Lagrangian constraint on the determinant of the metric required by unimodular gravity leads to an extra constraint on the gauge freedom of the metric perturbations. Although the main equation of motion for the gravitational potential remains the same, the shift variable, which is gauge artifact in General Relativity, cannot be set to zero in unimodular gravity. This non-vanishing shift variable affects the propagation of photons throughout the cosmological evolution and therefore modifies the Sachs-Wolfe relation between the relativistic gravitational potential and the microwave temperature anisotropies. However, for adiabatic fluctuations the difference between the result in General Relativity and unimodular gravity is suppressed on large angular scales. Thus, no strong constraints on the theory can be derived.

  19. Neptune's story. [Triton's orbit perturbation

    NASA Technical Reports Server (NTRS)

    Goldreich, P.; Murray, N.; Longaretti, P. Y.; Banfield, D.

    1989-01-01

    It is conjectured that Triton was captured from a heliocentric orbit as the result of a collision with what was then one of Neptune's regular satellites. The immediate post-capture orbit was highly eccentric. Dissipation due to tides raised by Neptune in Triton caused Triton's orbit to evolve to its present state in less than one billion years. For much of this time Triton was almost entirely molten. While its orbit was evolving, Triton cannibalized most of the regular satellites of Neptune and also perturbed Nereid, thus accounting for that satellite's highly eccentric and inclined orbit. The only regular satellites of Neptune that survived were those that formed well within 5 Neptune radii, and they move on inclined orbits as the result of chaotic perturbations forced by Triton.

  20. Classification of the chiral Z2× Z2 fermionic models in the heterotic superstring

    NASA Astrophysics Data System (ADS)

    Faraggi, A. E.; Kounnas, C.; Nooij, S. E. M.; Rizos, J.

    2004-09-01

    The first particle physics observable whose origin may be sought in string theory is the triple replication of the matter generations. The class of Z2× Z2 orbifolds of six-dimensional compactified tori, that have been most widely studied in the free fermionic formulation, correlate the family triplication with the existence of three twisted sectors in this class. In this work we seek an improved understanding of the geometrical origin of the three generation free fermionic models. Using fermionic and orbifold techniques we classify the Z2× Z2 orbifold with symmetric shifts on six-dimensional compactified internal manifolds. We show that perturbative three generation models are not obtained in the case of Z2× Z2 orbifolds with symmetric shifts on complex tori, and that the perturbative three generation models in this class necessarily employ an asymmetric shift. We present a class of three generation models in which the SO(10) gauge symmetry cannot be broken perturbatively, while preserving the Standard Model matter content. We discuss the potential implications of the asymmetric shift for strong-weak coupling duality and moduli stabilization. We show that the freedom in the modular invariant phases in the N=1 vacua that control the chiral content, can be interpreted as vacuum expectation values of background fields of the underlying N=4 theory, whose dynamical components are projected out by the Z2-fermionic projections. In this class of vacua the chiral content of the models is determined by the underlying N=4 mother theory.

  1. Identifying Network Perturbation in Cancer.

    PubMed

    Grechkin, Maxim; Logsdon, Benjamin A; Gentles, Andrew J; Lee, Su-In

    2016-05-01

    We present a computational framework, called DISCERN (DIfferential SparsE Regulatory Network), to identify informative topological changes in gene-regulator dependence networks inferred on the basis of mRNA expression datasets within distinct biological states. DISCERN takes two expression datasets as input: an expression dataset of diseased tissues from patients with a disease of interest and another expression dataset from matching normal tissues. DISCERN estimates the extent to which each gene is perturbed-having distinct regulator connectivity in the inferred gene-regulator dependencies between the disease and normal conditions. This approach has distinct advantages over existing methods. First, DISCERN infers conditional dependencies between candidate regulators and genes, where conditional dependence relationships discriminate the evidence for direct interactions from indirect interactions more precisely than pairwise correlation. Second, DISCERN uses a new likelihood-based scoring function to alleviate concerns about accuracy of the specific edges inferred in a particular network. DISCERN identifies perturbed genes more accurately in synthetic data than existing methods to identify perturbed genes between distinct states. In expression datasets from patients with acute myeloid leukemia (AML), breast cancer and lung cancer, genes with high DISCERN scores in each cancer are enriched for known tumor drivers, genes associated with the biological processes known to be important in the disease, and genes associated with patient prognosis, in the respective cancer. Finally, we show that DISCERN can uncover potential mechanisms underlying network perturbation by explaining observed epigenomic activity patterns in cancer and normal tissue types more accurately than alternative methods, based on the available epigenomic data from the ENCODE project. PMID:27145341

  2. R evolution: Improving perturbative QCD

    SciTech Connect

    Hoang, Andre H.; Jain, Ambar; Stewart, Iain W.; Scimemi, Ignazio

    2010-07-01

    Perturbative QCD results in the MS scheme can be dramatically improved by switching to a scheme that accounts for the dominant power law dependence on the factorization scale in the operator product expansion. We introduce the ''MSR scheme'' which achieves this in a Lorentz and gauge invariant way and has a very simple relation to MS. Results in MSR depend on a cutoff parameter R, in addition to the {mu} of MS. R variations can be used to independently estimate (i.) the size of power corrections, and (ii.) higher-order perturbative corrections (much like {mu} in MS). We give two examples at three-loop order, the ratio of mass splittings in the B*-B and D*-D systems, and the Ellis-Jaffe sum rule as a function of momentum transfer Q in deep inelastic scattering. Comparing to data, the perturbative MSR results work well even for Q{approx}1 GeV, and power corrections are reduced compared to MS.

  3. Path integral for inflationary perturbations

    NASA Astrophysics Data System (ADS)

    Prokopec, Tomislav; Rigopoulos, Gerasimos

    2010-07-01

    The quantum theory of cosmological perturbations in single-field inflation is formulated in terms of a path integral. Starting from a canonical formulation, we show how the free propagators can be obtained from the well-known gauge-invariant quadratic action for scalar and tensor perturbations, and determine the interactions to arbitrary order. This approach does not require the explicit solution of the energy and momentum constraints, a novel feature which simplifies the determination of the interaction vertices. The constraints and the necessary imposition of gauge conditions is reflected in the appearance of various commuting and anticommuting auxiliary fields in the action. These auxiliary fields are not propagating physical degrees of freedom but need to be included in internal lines and loops in a diagrammatic expansion. To illustrate the formalism we discuss the tree-level three-point and four-point functions of the inflaton perturbations, reproducing the results already obtained by the methods used in the current literature. Loop calculations are left for future work.

  4. R evolution: Improving perturbative QCD

    NASA Astrophysics Data System (ADS)

    Hoang, André H.; Jain, Ambar; Scimemi, Ignazio; Stewart, Iain W.

    2010-07-01

    Perturbative QCD results in the MS¯ scheme can be dramatically improved by switching to a scheme that accounts for the dominant power law dependence on the factorization scale in the operator product expansion. We introduce the “MSR scheme” which achieves this in a Lorentz and gauge invariant way and has a very simple relation to MS¯. Results in MSR depend on a cutoff parameter R, in addition to the μ of MS¯. R variations can be used to independently estimate (i.) the size of power corrections, and (ii.) higher-order perturbative corrections (much like μ in MS¯). We give two examples at three-loop order, the ratio of mass splittings in the B*-B and D*-D systems, and the Ellis-Jaffe sum rule as a function of momentum transfer Q in deep inelastic scattering. Comparing to data, the perturbative MSR results work well even for Q˜1GeV, and power corrections are reduced compared to MS¯.

  5. Perturbation growth in accreting filaments

    NASA Astrophysics Data System (ADS)

    Clarke, S. D.; Whitworth, A. P.; Hubber, D. A.

    2016-05-01

    We use smoothed particle hydrodynamic simulations to investigate the growth of perturbations in infinitely long filaments as they form and grow by accretion. The growth of these perturbations leads to filament fragmentation and the formation of cores. Most previous work on this subject has been confined to the growth and fragmentation of equilibrium filaments and has found that there exists a preferential fragmentation length-scale which is roughly four times the filament's diameter. Our results show a more complicated dispersion relation with a series of peaks linking perturbation wavelength and growth rate. These are due to gravo-acoustic oscillations along the longitudinal axis during the sub-critical phase of growth. The positions of the peaks in growth rate have a strong dependence on both the mass accretion rate onto the filament and the temperature of the gas. When seeded with a multiwavelength density power spectrum, there exists a clear preferred core separation equal to the largest peak in the dispersion relation. Our results allow one to estimate a minimum age for a filament which is breaking up into regularly spaced fragments, as well as an average accretion rate. We apply the model to observations of filaments in Taurus by Tafalla & Hacar and find accretion rates consistent with those estimated by Palmeirim et al.

  6. Analysis of Chiral Carboxylic Acids in Meteorites

    NASA Technical Reports Server (NTRS)

    Burton, A. S.; Elsila, J. E.; Hein, J. E.; Aponte, J. C.; Parker, E. T.; Glavin, D. P.; Dworkin, J. P.

    2015-01-01

    Homochirality of amino acids in proteins and sugars in DNA and RNA is a critical feature of life on Earth. In the absence of a chiral driving force, however, reactions leading to the synthesis of amino acids and sugars result in racemic mixtures. It is currently unknown whether homochirality was necessary for the origins of life or if it was a product of early life. The observation of enantiomeric excesses of certain amino acids of extraterrestrial origins in meteorites provides evidence to support the hypothesis that there was a mechanism for the preferential synthesis or destruction of a particular amino acid enantiomer [e.g., 1-3]. The cause of the observed chiral excesses is un-clear, although at least in the case of the amino acid isovaline, the degree of aqueous alteration that occurred on the meteorite parent body is correlated to the isovaline L-enantiomeric excess [3, 4]. This suggests that chiral symmetry is broken and/or amplified within the meteorite parent bodies. Besides amino acids, there have been only a few reports of other meteoritic compounds found in enantiomeric excess: sugars and sugar acids [5, 6] and the hydroxy acid lactic acid [7]. Determining whether or not additional types of molecules in meteorites are also present in enantiomeric excesses of extraterrestrial information will provide insights into mechanisms for breaking chiral symmetry. Though the previous measurements (e.g., enantiomeric composition of lactic acid [7], and chiral carboxylic acids [8]) were made by gas chromatography-mass spectrometry, the potential for increased sensitivity of liquid chromatography-mass spectrometry (LC-MS) analyses is important because for many meteorite samples, only small sample masses are available for study. Furthermore, at least in the case of amino acids, many of the largest amino acid enantiomeric excesses were observed in samples that contained lower abundances (tens of ppb) of a given amino acid enantiomer. In the present work, we describe

  7. An Edge Selection Mechanism for Chirally Selective Solubilization of Binaphthyl Atropisomeric Guests by Cholate and Deoxycholate Micelles.

    PubMed

    Eckenroad, Kyle W; Manley, Gregory A; Yehl, Jenna B; Pirnie, Ross T; Strein, Timothy G; Rovnyak, David

    2016-07-01

    Combining micellar electrokinetic capillary chromatography (MEKC) and nuclear magnetic resonance (NMR) experimentation, we shed light on the structural basis for the chirally selective solubilization of atropisomeric binaphthyl compounds by bile salt micelles comprised of cholate (NaC) or deoxycholate (NaDC). The model binaphthyl analyte R,S-BNDHP exhibits chirally selective interactions with primary micellar aggregates of cholate and deoxycholate, as does the closely related analyte binaphthol (R,S-BN). Chiral selectivity was localized, by NMR chemical shift analysis, to the proton at the C12 position of these bile acids. Correspondingly, MEKC results show that the 12α-OH group of either NaC or NaDC is necessary for chirally selective resolution of these model binaphthyl analytes by bile micelles, and the S isomer is more highly retained by the micelles. With NMR, the chemical shift of 12β-H was perturbed more strongly in the presence of S-BNDHP than R-BNDHP. Intermolecular NOEs demonstrate that R,S-BNDHP and R,S-BN interact with a similar hydrophobic planar pocket lined with the methyl groups of the bile salts, and are best explained by the existence of an antiparallel dimeric unit of bile salts. Finally, chemical shift data and intermolecular NOEs support different interactions of the enantiomers with the edges of dimeric bile units, indicating that R,S-BNDHP enantiomers sample the same binding site preferentially from opposite edges of the dimeric bile unit. Chirality 28:525-533, 2016. © 2016 Wiley Periodicals, Inc. PMID:27300496

  8. Advanced dress-up chiral columns: New removable chiral stationary phases for enantioseparation of chiral carboxylic acids.

    PubMed

    Todoroki, Kenichiro; Ishii, Yasuhiro; Ide, Takafumi; Min, Jun Zhe; Inoue, Koichi; Huang, Xin; Zhang, Wei; Hamashima, Yoshitaka; Toyo'oka, Toshimasa

    2015-07-01

    This paper describes the preparation of new dress-up columns featuring reproducibly removable and replaceable chiral stationary phases. After synthesizing perfluroalkylated quinine and quinidine derivatives as chiral stationary phase compounds (F-CSPs), we adsorbed them reversibly onto a fluorous LC column through pumping of their solutions. Using this dress-up chiral column and fluorophobic elution of aqueous ammonium formate/MeOH mixtures, we could enantioseparate four racemic N-acetyl amino acids, dichlorprop, and sixteen fluorescent 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate (AQC)-derivatized amino acids. Dressing and undressing of the coated F-CSPs could be controlled by varying the fluorophilicity and fluorophobicity of the eluent. The relative standard deviations of the retention times, the retention factors, the number of theoretical plates, the enantioseparation factors, and the resolutions of each of four preparations of such dress-up columns were all less than or equal to 5.26% (from 20 repeated analyses); the reproducibilities from four different preparations were all less than or equal to 10.6%. These columns also facilitated highly sensitive and selective analyses of AQC-amino acids when detected using LC-MS/MS. PMID:26043097

  9. Model of complex chiral drug metabolic systems and numerical simulation of the remaining chirality toward analysis of dynamical pharmacological activity.

    PubMed

    Ogino, Yoshiyuki; Asahi, Toru

    2015-05-21

    In this study, systems of complicated pathways involved in chiral drug metabolism were investigated. The development of chiral drugs resulted in significant improvement in the remedies available for the treatment of various severe sicknesses. Enantiopure drugs undergo various biological transformations that involve chiral inversion and thus result in the generation of multiple enantiomeric metabolites. Identification of the specific active substances determining a given drug׳s efficacy among such a mixture of different metabolites remains a challenge. To comprehend this complexity, we constructed a mathematical model representing the complicated metabolic pathways simultaneously involving chiral inversion. Moreover, this model is applied to the metabolism of thalidomide, which has recently been revived as a potentially effective prescription drug for a number of intractable diseases. The numerical simulation results indicate that retained chirality in the metabolites reflects the original chirality of the unmetabolized drug, and a higher level of enantiomeric purity is preserved during spontaneous degradation. In addition, chirality remaining after equilibration is directly related to the rate constant not only for chiral inversion but also for generation and degradation. Furthermore, the retention of chirality is quantitatively predictable using this combination of kinetic parameters. Our simulation results well explain the behavior of thalidomide in the practical biological experimental data. Therefore, this model promises a comprehensive understanding of dynamic metabolic systems involving chiral drugs that express multiple enantiospecific drug efficacies. PMID:25791284

  10. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration

  11. Chiral assembly of weakly curled hard rods: Effect of steric chirality and polarity

    NASA Astrophysics Data System (ADS)

    Wensink, H. H.; Morales-Anda, L.

    2015-10-01

    We theoretically investigate the pitch of lyotropic cholesteric phases composed of slender rods with steric chirality transmitted via a weak helical deformation of the backbone. In this limit, the model is amenable to analytical treatment within Onsager theory and a closed expression for the pitch versus concentration and helical shape can be derived. Within the same framework, we also briefly review the possibility of alternative types of chiral order, such as twist-bend or screw-like nematic phases, finding that cholesteric order dominates for weakly helical distortions. While long-ranged or "soft" chiral forces usually lead to a pitch decreasing linearly with concentration, steric chirality leads to a much steeper decrease of quadratic nature. This reveals a subtle link between the range of chiral intermolecular interaction and the pitch sensitivity with concentration. A much richer dependence on the thermodynamic state is revealed for polar helices where parallel and anti-parallel pair alignments along the local director are no longer equivalent. It is found that weak temperature variations may lead to dramatic changes in the pitch, despite the lyotropic nature of the assembly.

  12. Chiral assembly of weakly curled hard rods: Effect of steric chirality and polarity.

    PubMed

    Wensink, H H; Morales-Anda, L

    2015-10-14

    We theoretically investigate the pitch of lyotropic cholesteric phases composed of slender rods with steric chirality transmitted via a weak helical deformation of the backbone. In this limit, the model is amenable to analytical treatment within Onsager theory and a closed expression for the pitch versus concentration and helical shape can be derived. Within the same framework, we also briefly review the possibility of alternative types of chiral order, such as twist-bend or screw-like nematic phases, finding that cholesteric order dominates for weakly helical distortions. While long-ranged or "soft" chiral forces usually lead to a pitch decreasing linearly with concentration, steric chirality leads to a much steeper decrease of quadratic nature. This reveals a subtle link between the range of chiral intermolecular interaction and the pitch sensitivity with concentration. A much richer dependence on the thermodynamic state is revealed for polar helices where parallel and anti-parallel pair alignments along the local director are no longer equivalent. It is found that weak temperature variations may lead to dramatic changes in the pitch, despite the lyotropic nature of the assembly. PMID:26472398

  13. Chiral assembly of weakly curled hard rods: Effect of steric chirality and polarity

    SciTech Connect

    Wensink, H. H. Morales-Anda, L.

    2015-10-14

    We theoretically investigate the pitch of lyotropic cholesteric phases composed of slender rods with steric chirality transmitted via a weak helical deformation of the backbone. In this limit, the model is amenable to analytical treatment within Onsager theory and a closed expression for the pitch versus concentration and helical shape can be derived. Within the same framework, we also briefly review the possibility of alternative types of chiral order, such as twist-bend or screw-like nematic phases, finding that cholesteric order dominates for weakly helical distortions. While long-ranged or “soft” chiral forces usually lead to a pitch decreasing linearly with concentration, steric chirality leads to a much steeper decrease of quadratic nature. This reveals a subtle link between the range of chiral intermolecular interaction and the pitch sensitivity with concentration. A much richer dependence on the thermodynamic state is revealed for polar helices where parallel and anti-parallel pair alignments along the local director are no longer equivalent. It is found that weak temperature variations may lead to dramatic changes in the pitch, despite the lyotropic nature of the assembly.

  14. Enantioseparation and chiral recognition mechanism of new chiral derivatives of xanthones on macrocyclic antibiotic stationary phases.

    PubMed

    Fernandes, Carla; Tiritan, Maria Elizabeth; Cass, Quezia; Kairys, Visvaldas; Fernandes, Miguel Xavier; Pinto, Madalena

    2012-06-01

    A chiral HPLC method using four macrocyclic antibiotic chiral stationary phases (CSPs) has been investigated for determination of the enantiomeric purity of fourteen new chiral derivatives of xanthones (CDXs). The separations were performed with the CSPs Chirobiotic T, Chirobiotic TAG, Chirobiotic V and Chirobiotic R under multimodal elution conditions (normal-phase, reversed-phase and polar ionic mode). The analyses were performed at room temperature in isocratic mode and UV and CD detection at a wavelength of 254 nm. The best enantioselectivity and resolution were achieved on Chirobiotic R and Chirobiotic T CSPs, under normal elution conditions, with R(S) ranging from 1.25 to 2.50 and from 0.78 to 2.06, respectively. The optimized chromatographic conditions allowed the determination of the enantiomeric ratio of eight CDXs, always higher than 99%. In order to better understand the chromatographic behavior at a molecular level, and the structural features associated with the chiral recognition mechanism, computational studies by molecular docking were carried out using VDock. These studies shed light on the mechanisms involved in the enantioseparation for this important class of chiral compounds. PMID:22552201

  15. Chiral solitons in a coupled double Peierls chain

    NASA Astrophysics Data System (ADS)

    Cheon, Sangmo; Kim, Tae-Hwan; Lee, Sung-Hoon; Yeom, Han Woong

    2015-10-01

    Chiral edge states are the hallmark of two- and three-dimensional topological materials, but their one-dimensional (1D) analog has not yet been found. We report that the 1D topological edge states, solitons, of the charge density wave system of indium atomic wires self-assembled on a silicon surface have chirality. The system is described by a coupled double Peierls-dimerized atomic chain, where the interchain coupling induces dynamical sublattice symmetry breaking. This changes its topological symmetry from Z2×Z2 to Z4 and endows solitons with a chiral degree of freedom. Chiral solitons can produce quantized charge transport across the chain that is topologically protected and controllable by the soliton’s chirality. Individual right- and left-chiral solitons in indium wires are directly identified by scanning tunneling microscopy.

  16. Theory of Chirality Transfer in Block Copolymer Melts

    NASA Astrophysics Data System (ADS)

    Prasad, Ishan; Grason, Gregory

    Block copolymers assemble into a rich spectrum of ordered phases, with complexity driven by asymmetry in copolymer architecture. Despite decades of study, influence of intrinsic chirality on equilibrium mesophase assembly of block copolymers is not well understood and largely unexplored. Self-consistent field theory has been largely instrumental in prediction of physical properties of polymeric systems. Recently, a polar orientational self-consistent field (oSCF) theory was adopted to model chiral block copolymers having a thermodynamic preference for cholesteric ordering in chiral segments, and which confirmed the equilibrium stability of a helical cylinder morphology observed for chiral diblocks. Here, I describe a newly developed oSCF theory for chiral nematic copolymers, where segment orientations are characterized by quadrupolar interactions, and focus our study on intra-domain nematic ordering in flexible block copolymer assemblies, and in particular, mechanisms of transfer of segment chirality to mesochiral symmetries of self-assembled bicontinuous network morphologies.

  17. A molecular propeller effect for chiral separation and analysis

    PubMed Central

    Clemens, Jonathon B.; Kibar, Osman; Chachisvilis, Mirianas

    2015-01-01

    Enantiomers share nearly identical physical properties but have different chiral geometries, making their identification and separation difficult. Here we show that when exposed to a rotating electric field, the left- and right-handed chiral molecules rotate with the field and act as microscopic propellers; moreover, owing to their opposite handedness, they propel along the axis of field rotation in opposite directions. We introduce a new molecular parameter called hydrodynamic chirality to characterize the coupling of rotational motion of a chiral molecule into its translational motion and quantify the direction and velocity of such motion. We demonstrate >80% enrichment level of counterpart enantiomers in solution without using chiral selectors or circularly polarized light. We expect our results to have an impact on multiple applications in drug discovery, analytical and chiral chemistry, including determination of absolute configuration, as well as in influencing the understanding of artificial and natural molecular systems where rotational motion of the molecules is involved. PMID:26216219

  18. Achiral flexible liquid crystal trimers exhibiting chiral conglomerates.

    PubMed

    Sasaki, Haruna; Takanishi, Yoichi; Yamamoto, Jun; Yoshizawa, Atsushi

    2016-04-14

    Chiral conglomerates of domains with opposite handedness have attracted much attention from researchers. We prepared a homologous series of achiral liquid crystal trimers in which two phenylpyrimidine units and one biphenyl unit were connected via flexible methylene spacers. We investigated their phase transition behaviour. Some trimers possessing odd-numbered spacers were found to exhibit a nematic phase and a dark chiral conglomerate phase possessing a layered structure. The chiral characteristics were confirmed by uncrossing the polarizers in opposite directions. The layer spacing detected using X-ray diffraction was about 80% of the molecular length. The structure-property relations indicate that intermolecular interactions cause a conformational change in the trimers possessing flexible odd-numbered methylene spacers to form helical conformers with axial chirality, which might induce chiral segregation and layer deformation to drive the chiral conglomerates. PMID:26947890

  19. Chiral solitons in a coupled double Peierls chain.

    PubMed

    Cheon, Sangmo; Kim, Tae-Hwan; Lee, Sung-Hoon; Yeom, Han Woong

    2015-10-01

    Chiral edge states are the hallmark of two- and three-dimensional topological materials, but their one-dimensional (1D) analog has not yet been found. We report that the 1D topological edge states, solitons, of the charge density wave system of indium atomic wires self-assembled on a silicon surface have chirality. The system is described by a coupled double Peierls-dimerized atomic chain, where the interchain coupling induces dynamical sublattice symmetry breaking. This changes its topological symmetry from Z₂× Z₂to Z₄ and endows solitons with a chiral degree of freedom. Chiral solitons can produce quantized charge transport across the chain that is topologically protected and controllable by the soliton's chirality. Individual right- and left-chiral solitons in indium wires are directly identified by scanning tunneling microscopy. PMID:26450206

  20. Detecting Chirality in Molecules by Linearly Polarized Laser Fields.

    PubMed

    Yachmenev, Andrey; Yurchenko, Sergei N

    2016-07-15

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states. PMID:27472111

  1. Development of chiral sulfoxide ligands for asymmetric catalysis.

    PubMed

    Trost, Barry M; Rao, Meera

    2015-04-20

    Nitrogen-, phosphorus-, and oxygen-based ligands with chiral backbones have been the historic workhorses of asymmetric transition-metal-catalyzed reactions. On the contrary, sulfoxides containing chirality at the sulfur atom have mainly been used as chiral auxiliaries for diastereoselective reactions. Despite several distinct advantages over traditional ligand scaffolds, such as the proximity of the chiral information to the metal center and the ability to switch between S and O coordination, these compounds have only recently emerged as a versatile class of chiral ligands. In this Review, we detail the history of the development of chiral sulfoxide ligands for asymmetric catalysis. We also provide brief descriptions of metal-sulfoxide bonding and strategies for the synthesis of enantiopure sulfoxides. Finally, insights into the future development of this underutilized ligand class are discussed. PMID:25801825

  2. Integration of inherent and induced chirality into subphthalocyanine analogue

    PubMed Central

    Zhao, Luyang; Qi, Dongdong; Wang, Kang; Wang, Tianyu; Han, Bing; Tang, Zhiyong; Jiang, Jianzhuang

    2016-01-01

    Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inherent and induced chirality. Impressively, an obviously enhanced optical activity is discerned for (R/S)-1 molecules, and corresponding enhancement mechanism is elucidated in detail. The synthesis strategy based on rational molecular design will open the door towards fabrication of chiral materials with giant optical activity, which will have great potential in chiroptical devices. PMID:27294871

  3. A molecular propeller effect for chiral separation and analysis.

    PubMed

    Clemens, Jonathon B; Kibar, Osman; Chachisvilis, Mirianas

    2015-01-01

    Enantiomers share nearly identical physical properties but have different chiral geometries, making their identification and separation difficult. Here we show that when exposed to a rotating electric field, the left- and right-handed chiral molecules rotate with the field and act as microscopic propellers; moreover, owing to their opposite handedness, they propel along the axis of field rotation in opposite directions. We introduce a new molecular parameter called hydrodynamic chirality to characterize the coupling of rotational motion of a chiral molecule into its translational motion and quantify the direction and velocity of such motion. We demonstrate >80% enrichment level of counterpart enantiomers in solution without using chiral selectors or circularly polarized light. We expect our results to have an impact on multiple applications in drug discovery, analytical and chiral chemistry, including determination of absolute configuration, as well as in influencing the understanding of artificial and natural molecular systems where rotational motion of the molecules is involved. PMID:26216219

  4. Emergence of Chirality from Isotropic Interactions of Three Length Scales.

    PubMed

    Mkhonta, S K; Elder, K R; Huang, Zhi-Feng

    2016-05-20

    Chirality is known to play a pivotal role in determining material properties and functionalities. However, it remains a great challenge to understand and control the emergence of chirality and the related enantioselective process particularly when the building components of the system are achiral. Here we explore the generic mechanisms driving the formation of two-dimensional chiral structures in systems characterized by isotropic interactions and three competing length scales. We demonstrate that starting from isotropic and rotationally invariant interactions, a variety of chiral ordered patterns and superlattices with anisotropic but achiral units can self-assemble. The mechanisms for selecting specific states are related to the length-scale coupling and the selection of resonant density wave vectors. Sample phase diagrams and chiral elastic properties are identified. These findings provide a viable route for predicting chiral phases and selecting the desired handedness. PMID:27258877

  5. Generation of chiral spin state by quantum simulation

    NASA Astrophysics Data System (ADS)

    Tanamoto, Tetsufumi

    2016-06-01

    Chirality of materials in nature appears when there are asymmetries in their lattice structures or interactions in a certain environment. Recent development of quantum simulation technology has enabled the manipulation of qubits. Accordingly, chirality can be realized intentionally rather than passively observed. Here we theoretically provide simple methods to create a chiral spin state in a spin-1/2 qubit system on a square lattice. First, we show that switching on and off the Heisenberg and X Y interactions produces the chiral interaction directly in the effective Hamiltonian without controlling local fields. Moreover, when initial states of spin qubits are appropriately prepared, we prove that the chirality with desirable phase is dynamically obtained. Finally, even for the case where switching on and off the interactions is infeasible and the interactions are always on, we show that, by preparing an asymmetric initial qubit state, the chirality whose phase is π /2 is dynamically generated.

  6. Formation of chiral branched nanowires by the Eshelby Twist.

    PubMed

    Zhu, Jia; Peng, Hailin; Marshall, A F; Barnett, D M; Nix, W D; Cui, Yi

    2008-08-01

    Manipulating the morphology of inorganic nanostructures, such as their chirality and branching structure, has been actively pursued as a means of controlling their electrical, optical and mechanical properties. Notable examples of chiral inorganic nanostructures include carbon nanotubes, gold multishell nanowires, mesoporous nanowires and helical nanowires. Branched nanostructures have also been studied and been shown to have interesting properties for energy harvesting and nanoelectronics. Combining both chiral and branching motifs into nanostructures might provide new materials properties. Here we show a chiral branched PbSe nanowire structure, which is formed by a vapour-liquid-solid branching from a central nanowire with an axial screw dislocation. The chirality is caused by the elastic strain of the axial screw dislocation, which produces a corresponding Eshelby Twist in the nanowires. In addition to opening up new opportunities for tailoring the properties of nanomaterials, these chiral branched nanowires also provide a direct visualization of the Eshelby Twist. PMID:18685634

  7. A molecular propeller effect for chiral separation and analysis

    NASA Astrophysics Data System (ADS)

    Clemens, Jonathon B.; Kibar, Osman; Chachisvilis, Mirianas

    2015-07-01

    Enantiomers share nearly identical physical properties but have different chiral geometries, making their identification and separation difficult. Here we show that when exposed to a rotating electric field, the left- and right-handed chiral molecules rotate with the field and act as microscopic propellers; moreover, owing to their opposite handedness, they propel along the axis of field rotation in opposite directions. We introduce a new molecular parameter called hydrodynamic chirality to characterize the coupling of rotational motion of a chiral molecule into its translational motion and quantify the direction and velocity of such motion. We demonstrate >80% enrichment level of counterpart enantiomers in solution without using chiral selectors or circularly polarized light. We expect our results to have an impact on multiple applications in drug discovery, analytical and chiral chemistry, including determination of absolute configuration, as well as in influencing the understanding of artificial and natural molecular systems where rotational motion of the molecules is involved.

  8. Emergence of Chirality from Isotropic Interactions of Three Length Scales

    NASA Astrophysics Data System (ADS)

    Mkhonta, S. K.; Elder, K. R.; Huang, Zhi-Feng

    2016-05-01

    Chirality is known to play a pivotal role in determining material properties and functionalities. However, it remains a great challenge to understand and control the emergence of chirality and the related enantioselective process particularly when the building components of the system are achiral. Here we explore the generic mechanisms driving the formation of two-dimensional chiral structures in systems characterized by isotropic interactions and three competing length scales. We demonstrate that starting from isotropic and rotationally invariant interactions, a variety of chiral ordered patterns and superlattices with anisotropic but achiral units can self-assemble. The mechanisms for selecting specific states are related to the length-scale coupling and the selection of resonant density wave vectors. Sample phase diagrams and chiral elastic properties are identified. These findings provide a viable route for predicting chiral phases and selecting the desired handedness.

  9. Transport of anisotropic chiral particles in a confined structure

    NASA Astrophysics Data System (ADS)

    Hu, Cai-tian; Ou, Ya-li; Wu, Jian-chun; Ai, Bao-quan

    2016-03-01

    Directed transport of anisotropic chiral particles is numerically investigated in the presence of the regular arrays of rigid half-circle obstacles. It is found that due to the rotational-translational coupling, the transport of anisotropic particles is considerably more complicated compared to the isotropic case. For isotropic chiral particles, the transport direction is completely determined by the chirality of particles. However, for anisotropic chiral particles, the competition between the chirality and the anisotropic degree determines the transport direction. For a given chirality, by suitably tailoring parameters (the anisotropic degree and the self-propulsion speed), particles with different anisotropic degrees (or self-propulsion speed) can move in different directions and can be separated.

  10. Detecting Chirality in Molecules by Linearly Polarized Laser Fields

    NASA Astrophysics Data System (ADS)

    Yachmenev, Andrey; Yurchenko, Sergei N.

    2016-07-01

    A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal anisotropic contributions to the electric polarizability tensor for two enantiomers have different signs. Exploiting this property, we are able to excite a coherent unidirectional rotation of two enantiomers with a π phase difference in the molecular electric dipole moment. The approach is robust and suitable for relatively high temperatures of molecular samples, making it applicable for selective chiral analysis of mixtures, and to chiral molecules with low barriers between enantiomers. As an illustration, we present nanosecond laser-driven dynamics of a tetratomic nonrigid chiral molecule with short-lived chirality. The ultrafast time scale of the proposed technique is well suited to study parity violation in molecular systems in short-lived chiral states.

  11. Supramolecular chirality in self-assembled peptide amphiphile nanostructures.

    PubMed

    Garifullin, Ruslan; Guler, Mustafa O

    2015-08-11

    Induced supramolecular chirality was investigated in the self-assembled peptide amphiphile (PA) nanosystems. Having shown that peptide chirality can be transferred to the covalently-attached achiral pyrene moiety upon PA self-assembly, the chiral information is transferred to molecular pyrene via weak noncovalent interactions. In the first design of a supramolecular chiral system, the chromophore was covalently attached to a peptide sequence (VVAGH) via an ε-aminohexanoic acid spacer. Covalent attachment yielded a PA molecule self-assembling into nanofibers. In the second design, the chromophore was encapsulated within the hydrophobic core of self-assembled nanofibers of another PA consisting of the same peptide sequence attached to lauric acid. We observed that supramolecular chirality was induced in the chromophore by PA assembly into chiral nanostructures, whether it was covalently attached, or noncovalently bound. PMID:26146021

  12. Integration of inherent and induced chirality into subphthalocyanine analogue.

    PubMed

    Zhao, Luyang; Qi, Dongdong; Wang, Kang; Wang, Tianyu; Han, Bing; Tang, Zhiyong; Jiang, Jianzhuang

    2016-01-01

    Conventional conjugated systems are characteristic of only either inherent or induced chirality because of synthetic challenge in combination of chiral segment into the main chromophore. In this work, chiral binaphthyl segment is directly fused into the central chromophore of a subphthalocyanine skeleton, resulting in a novel type of chiral subphthalocyanine analogue (R/S)-1 of integrated inherent and induced chirality. Impressively, an obviously enhanced optical activity is discerned for (R/S)-1 molecules, and corresponding enhancement mechanism is elucidated in detail. The synthesis strategy based on rational molecular design will open the door towards fabrication of chiral materials with giant optical activity, which will have great potential in chiroptical devices. PMID:27294871

  13. Self-shaping of bioinspired chiral composites

    NASA Astrophysics Data System (ADS)

    Rong, Qing-Qing; Cui, Yu-Hong; Shimada, Takahiro; Wang, Jian-Shan; Kitamura, Takayuki

    2014-08-01

    Self-shaping materials such as shape memory polymers have recently drawn considerable attention owing to their high shape-changing ability in response to changes in ambient conditions, and thereby have promising applications in the biomedical, biosensing, soft robotics and aerospace fields. Their design is a crucial issue of both theoretical and technological interest. Motivated by the shape-changing ability of Towel Gourd tendril helices during swelling/deswelling, we present a strategy for realizing self-shaping function through the deformation of micro/nanohelices. To guide the design and fabrication of self-shaping materials, the shape equations of bent configurations, twisted belts, and helices of slender chiral composite are developed using the variation method. Furthermore, it is numerically shown that the shape changes of a chiral composite can be tuned by the deformation of micro/nanohelices and the fabricated fiber directions. This work paves a new way to create self-shaping composites.

  14. Nonperturbative Regulator for Chiral Gauge Theories?

    NASA Astrophysics Data System (ADS)

    Grabowska, Dorota M.; Kaplan, David B.

    2016-05-01

    We propose a nonperturbative gauge-invariant regulator for d -dimensional chiral gauge theories on the lattice. The method involves simulating domain wall fermions in d +1 dimensions with quantum gauge fields that reside on one d -dimensional surface and are extended into the bulk via gradient flow. The result is a theory of gauged fermions plus mirror fermions, where the mirror fermions couple to the gauge fields via a form factor that becomes exponentially soft with the separation between domain walls. The resultant theory has a local d -dimensional interpretation only if the chiral fermion representation is anomaly free. A physical realization of this construction would imply the existence of mirror fermions in the standard model that are invisible except for interactions induced by vacuum topology, and which could gravitate differently than conventional matter.

  15. Mechanically generated surface chirality at the nanoscale.

    PubMed

    Ferjani, Sameh; Choi, Yoonseuk; Pendery, Joel; Petschek, Rolfe G; Rosenblatt, Charles

    2010-06-25

    A substrate coated with an achiral polyimide alignment layer was scribed bidirectionally with the stylus of an atomic force microscope to create an easy axis for liquid crystal orientation. The resulting noncentrosymmetric topography resulted in a chiral surface that manifests itself at the molecular level. To show this unambiguously, a planar-aligned negative dielectric aniostropy achiral nematic liquid crystal was placed in contact with the surface and subjected to an electric field E. The nematic director was found to undergo an azimuthal rotation approximately linear in E. This so-called "surface electroclinic effect" is a signature of surface chirality and was not observed when the polyimide was treated for a centrosymmetric topography, and therefore was nonchiral. PMID:20867414

  16. Sensing and actuation of smart chiral honeycombs

    NASA Astrophysics Data System (ADS)

    Abramovitch, H.; Burgard, M.; Edery-Azulay, Lucy; Evans, K. E.; Hoffmeister, M.; Miller, W.; Scarpa, F.; Smith, C. W.; Tee, K. F.; Schönecker, A.; Seffner, L.

    2008-03-01

    A chiral honeycomb configuration is developed with embedded piezosensors and actuators for smart sandwich panel applications. The chiral honeycomb concept is made of repeating units of cylinders and plates (ligaments), featuring an in-plane negative Poisson's ratio. Rapid Prototyping vacuum-cast and FDM (Fusion Deposition Moulding) techniques are developed to embed micro fibres composites to be used for potential structural health monitoring (SHM) applications, and microwave absorption screens for electromagnetic compatibility. Finite Element models are also developed to prototype and simulate the response, sensing and actuation capability of the honeycombs for design purposes. Dynamic tests using scanning laser vibrometers and acoustic wave propagation are carried out to assess the feasibility of the concept.

  17. Nonperturbative Regulator for Chiral Gauge Theories?

    PubMed

    Grabowska, Dorota M; Kaplan, David B

    2016-05-27

    We propose a nonperturbative gauge-invariant regulator for d-dimensional chiral gauge theories on the lattice. The method involves simulating domain wall fermions in d+1 dimensions with quantum gauge fields that reside on one d-dimensional surface and are extended into the bulk via gradient flow. The result is a theory of gauged fermions plus mirror fermions, where the mirror fermions couple to the gauge fields via a form factor that becomes exponentially soft with the separation between domain walls. The resultant theory has a local d-dimensional interpretation only if the chiral fermion representation is anomaly free. A physical realization of this construction would imply the existence of mirror fermions in the standard model that are invisible except for interactions induced by vacuum topology, and which could gravitate differently than conventional matter. PMID:27284646

  18. Chiral meta-atoms rotated by light

    SciTech Connect

    Liu Mingkai; Powell, David A.; Shadrivov, Ilya V.

    2012-07-16

    We study the opto-mechanical properties of coupled chiral meta-atoms based on a pair of twisted split-ring resonators. By using a simple analytical model in conjunction with the Maxwell stress tensor, we capture insight into the mechanism and find that this structure can be used as a general prototype of subwavelength light-driven actuators over a wide range of frequencies. This coupled structure can provide a strong and tunable torque, and can support different opto-mechanical modes, including uniform rotation, periodically variable rotation and damped oscillations. Our results suggest that chiral meta-atoms are good candidates for creating sub-wavelength motors or wrenches controlled by light.

  19. Optical tractor beam with chiral light

    NASA Astrophysics Data System (ADS)

    Fernandes, David E.; Silveirinha, Mário G.

    2015-06-01

    We suggest a novel mechanism to induce the motion of a chiral material body towards an optical source with no optical traps. Our solution is based on the interference between a chiral light beam and its reflection on an opaque mirror. Surprisingly, it is theoretically shown that the electromagnetic response of the material may be tailored in such a way that independent of the specific body location with respect to the mirror, it is always pulled upstream against the photon flow associated with the incoming wave. Moreover, it is proven that by controlling the handedness of the incoming light it may be possible to harness the sign of the optical force, switching from a pulling force to a pushing force.

  20. On Gauge Independent Dynamical Chiral Symmetry Breaking

    SciTech Connect

    Bashir, A.; Raya, A.

    2006-09-25

    Schwinger-Dyson equations (SDEs) are an ideal framework to study nonperturbative phenomena such as dynamical chiral symmetry breaking (DCSB). Loss of gauge invariance is an obstacle to achieve fully reliable predictions from these equations. In addition to Ward-Green-Takahashi identity (WGTI), Landau-Khalatnikov-Fradkin transformations (LKFT) also play an important role in restoring the said invariance at the level of physical observables. On one hand, they impose useful constraints on the transverse part of the fermion-boson vertex and on the other, they govern the change in dynamically generated fermion propagator with a variation of gauge. We consider the latter in this article and study the gauge (in)dependence of chiral condensate in quantum electrodynamics in (2+1) space-time dimensions (QED3)