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Sample records for su3-flavor chiral perturbation

  1. Chiral Perturbation Theory

    NASA Astrophysics Data System (ADS)

    Tiburzi, Brian C.

    The era of high-precision lattice QCD has led to synergy between lattice computations and phenomenological input from chiral perturbation theory. We provide an introduction to chiral perturbation theory with a bent towards understanding properties of the nucleon and other low-lying baryons. Four main topics are the basis for this chapter. We begin with a discussion of broken symmetries and the procedure to construct the chiral Lagrangian. The second topic concerns specialized applications of chiral perturbation theory tailored to lattice QCD, such as partial quenching, lattice discretization, and finite-volume effects. We describe inclusion of the nucleon in chiral perturbation theory using a heavy-fermion Euclidean action. Issues of convergence are taken up as our final topic. We consider expansions in powers of the strange-quark mass, and the appearance of unphysical singularities in the heavy-particle formulation. Our aim is to guide lattice practitioners in understanding the predictions chiral perturbation theory makes for baryons, and show how the lattice will play a role in testing the rigor of the chiral expansion at physical values of the quark masses.

  2. Baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Scherer, S.

    2012-03-01

    We provide a short introduction to the one-nucleon sector of chiral perturbation theory and address the issue of power counting and renormalization. We discuss the infrared regularization and the extended on-mass-shell scheme. Both allow for the inclusion of further degrees of freedom beyond pions and nucleons and the application to higher-loop calculations. As applications we consider the chiral expansion of the nucleon mass to order Script O(q6) and the inclusion of vector and axial-vector mesons in the calculation of nucleon form factors. Finally, we address the complex-mass scheme for describing unstable particles in effective field theory.

  3. Chiral perturbation theory with nucleons

    SciTech Connect

    Meissner, U.G.

    1991-09-01

    I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, {pi}N scattering and the {sigma}-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon.

  4. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    DOE PAGESBeta

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the ordermore » we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.« less

  5. Lattice calculation of SU(3) flavor breaking ratios in B0-B¯0 mixing

    NASA Astrophysics Data System (ADS)

    Gadiyak, Valeriya; Loktik, Oleg

    2005-12-01

    We present an unquenched lattice calculation for the SU(3) flavor breaking ratios of the heavy-light decay constants and the ΔB=2 matrix elements. The calculation was performed on 163×32 lattices with two dynamical flavors of domain-wall quarks and inverse lattice spacing 1/a=1.69(5)GeV. Heavy quarks were implemented using an improved lattice formulation of the static approximation. In the infinite heavy-quark mass limit we obtain fBs/fBd=1.29(4)(6), BBs/BBd=1.06(6)(4), ξ=1.33(8)(8) where the first error is statistical and the second systematic.

  6. Strong decays of charmed baryons in heavy hadron chiral perturbation theory: An update

    NASA Astrophysics Data System (ADS)

    Cheng, Hai-Yang; Chua, Chun-Khiang

    2015-10-01

    We first give a brief overview of the charmed baryon spectroscopy and discuss their possible structure and spin-parity assignments in the quark model. With the new Belle measurement of the widths of Σc(2455 ) and Σc(2520 ) and the recent CDF measurement of the strong decays of Λc(2595 ) and Λc(2625 ), we give updated coupling constants in heavy hadron chiral perturbation theory. We find g2=0.56 5-0.024+0.011 for P -wave transitions between s -wave and s -wave baryons, and h2, one of the couplings responsible for S -wave transitions between s -wave and p -wave baryons, is extracted from Λc(2595 )+→Λc+π π to be 0.63 ±0.07 . It is substantially enhanced compared to the old value of order 0.437. With the help from the quark model, two of the couplings h10 and h11 responsible for D -wave transitions between s -wave and p -wave baryons are determined from Σc(2880 ) decays. There is a tension for the coupling h2 as its value extracted from Λc(2595 )+→Λc+ππ will imply Ξc(2790 )0→Ξc'π and Ξc(2815 )+→Ξc*π rates slightly above the current limits. It is conceivable that SU(3) flavor symmetry breaking can help account for the discrepancy.

  7. Partially Quenched Chiral Perturbation Theory to NNLO

    SciTech Connect

    Laehde, Timo; Bijnens, Johan; Danielsson, Niclas

    2006-07-11

    This paper summarizes the recent calculations of the masses and decay constants of the pseudoscalar mesons at the two-loop level, or NNLO, in Partially Quenched Chiral Perturbation theory (PQ{chi}PT). Possible applications include chiral extrapolations of Lattice QCD, as well as the determination of the low-energy constants (LEC:s) of QCD.

  8. Staggered heavy baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Bailey, Jon A.

    2008-03-01

    Although taste violations significantly affect the results of staggered calculations of pseudoscalar and heavy-light mesonic quantities, those entering staggered calculations of baryonic quantities have not been quantified. Here I develop staggered chiral perturbation theory in the light-quark baryon sector by mapping the Symanzik action into heavy baryon chiral perturbation theory. For 2+1 dynamical quark flavors, the masses of flavor-symmetric nucleons are calculated to third order in partially quenched and fully dynamical staggered chiral perturbation theory. To this order the expansion includes the leading chiral logarithms, which come from loops with virtual decuplet-like states, as well as terms of O(mπ3), which come from loops with virtual octet-like states. Taste violations enter through the meson propagators in loops and tree-level terms of O(a2). The pattern of taste symmetry breaking and the resulting degeneracies and mixings are discussed in detail. The resulting chiral forms are appropriate to lattice results obtained with operators already in use and could be used to study the restoration of taste symmetry in the continuum limit. I assume that the fourth root of the fermion determinant can be incorporated in staggered chiral perturbation theory using the replica method.

  9. Tests of Chiral Perturbation Theory with COMPASS

    SciTech Connect

    Friedrich, Jan

    2010-12-28

    The COMPASS experiment at CERN studies with high precision pion-photon induced reactions on nuclear targets via the Primakoff effect. This offers the possibility to test chiral perturbation theory (ChPT) in various channels: Pion Compton scattering allows to clarify the longstanding question of the pion polarisabilities, single neutral pion production is related to the chiral anomaly, and for the two-pion production cross sections exist as yet untested ChPT predictions.

  10. Baryon mass splittings and strong CP violation in SU(3) chiral perturbation theory

    SciTech Connect

    de Vries, Jordy; Mereghetti, Emanuele; Walker-Loud, Andre P.

    2015-10-08

    We study SU(3) flavor breaking corrections to the relation between the octet baryon masses and the nucleon-meson CP-violating interactions induced by the QCD theta term. We also work within the framework of SU(3) chiral perturbation theory and work through next-to-next-to-leading order in the SU(3) chiral expansion, which is O(m2q). At lowest order, the CP-odd couplings induced by the QCD θ- term are determined by mass splittings of the baryon octet, the classic result of Crewther et al. We show that for each isospin-invariant CP-violating nucleon-meson interaction there exists one relation which is respected by loop corrections up to the order we work, while other leading-order relations are violated. With these relations we extract a precise value of the pion-nucleon coupling g-0 by using recent lattice QCD evaluations of the proton-neutron mass splitting. Additionally, we derive semi-precise values for CP-violating coupling constants between heavier mesons and nucleons and discuss their phenomenological impact on electric dipole moments of nucleons and nuclei.

  11. CP violation in , B 0 → K +π- decays and tests for SU(3) flavor symmetry predictions

    NASA Astrophysics Data System (ADS)

    He, Xiao-Gang; Li, Siao-Fong; Lin, Hsiu-Hsien

    2013-08-01

    The LHCb collaboration has recently measured the first direct CP violation in decays with a rate asymmetry given by 0 .27 ± 0 .04( stat) ± 0 .01( syst). At the same time they also made the most precise measurement for ACP ( B0 → K +π-) = -0 .080 ± 0 .007( stat) ± 0 .003( syst). These data confirm the predicted relation, , in the standard model with SU(3) flavor symmetry. We discuss possible modifications due to SU(3) breaking effects to this relation. There are several other similar relations in B decays. Using current available data we study whether relevant relations hold in B 0 and to PP and PV decays. Here P and V indicate pesudoscalar and vector mesons in the flavor octet representations.

  12. Applications of partially quenched chiral perturbation theory

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1998-05-01

    Partially quenched theories are theories in which the valence- and sea-quark masses are different. In this paper we calculate the nonanalytic one-loop corrections of some physical quantities: the chiral condensate, weak decay constants, Goldstone boson masses, B{sub K}, and the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude, using partially quenched chiral perturbation theory. Our results for weak decay constants and masses agree with, and generalize, results of previous work by Sharpe. We compare B{sub K} and the K{sup +} decay amplitude with their real-world values in some examples. For the latter quantity, two other systematic effects that plague lattice computations, namely, finite-volume effects and unphysical values of the quark masses and pion external momenta, are also considered. We find that typical one-loop corrections can be substantial. {copyright} {ital 1998} {ital The American Physical Society}

  13. Tests of Chiral perturbation theory with COMPASS

    NASA Astrophysics Data System (ADS)

    Friedrich, Jan M.

    2014-06-01

    The COMPASS experiment at CERN accesses pion-photon reactions via the Primakoff effect., where high-energetic pions react with the quasi-real photon field surrounding the target nuclei. When a single real photon is produced, pion Compton scattering is accessed and from the measured cross-section shape, the pion polarisability is determined. The COMPASS measurement is in contradiction to the earlier dedicated measurements, and rather in agreement with the theoretical expectation from ChPT. In the same experimental data taking, reactions with neutral and charged pions in the final state are measured and analyzed in the context of chiral perturbation theory.

  14. The baryon vector current in the combined chiral and 1/Nc expansions

    SciTech Connect

    Flores-Mendieta, Ruben; Goity, Jose L

    2014-12-01

    The baryon vector current is computed at one-loop order in large-Nc baryon chiral perturbation theory, where Nc is the number of colors. Loop graphs with octet and decuplet intermediate states are systematically incorporated into the analysis and the effects of the decuplet-octet mass difference and SU(3) flavor symmetry breaking are accounted for. There are large-Nc cancellations between different one-loop graphs as a consequence of the large-Nc spin-flavor symmetry of QCD baryons. The results are compared against the available experimental data through several fits in order to extract information about the unknown parameters. The large-Nc baryon chiral perturbation theory predictions are in very good agreement both with the expectations from the 1/Nc expansion and with the experimental data. The effect of SU(3) flavor symmetry breaking for the |Delta S|=1 vector current form factors f1(0) results in a reduction by a few percent with respect to the corresponding SU(3) symmetric values.

  15. One-loop chiral perturbation theory with two fermion representations

    NASA Astrophysics Data System (ADS)

    DeGrand, Thomas; Golterman, Maarten; Neil, Ethan T.; Shamir, Yigal

    2016-07-01

    We develop chiral perturbation theory for chirally broken theories with fermions in two different representations of the gauge group. Any such theory has a nonanomalous singlet U (1 )A symmetry, yielding an additional Nambu-Goldstone boson when spontaneously broken. We calculate the next-to-leading order corrections for the pseudoscalar masses and decay constants, which include the singlet Nambu-Goldstone boson, as well as for the two condensates. The results can be generalized to more than two representations.

  16. Chiral perturbation theory with tensor sources

    SciTech Connect

    Cata, Oscar; Cata, Oscar; Mateu, Vicent

    2007-05-21

    We construct the most general chirally-invariant Lagrangian for mesons in the presence of external sources coupled to the tensor current \\bar psi sigma_mu nu psi. In order to have only even terms in the chiral expansion, we consider the new source of O(p2). With this choice, we build the even-parity effective Lagrangian up to the p6-order (NLO). While there are only 4 new terms at the p4-order, at p6-order we find 78 terms for n_f=2 and 113 terms for n_f=3. We provide a detailed discussion on the different mechanisms that ensure that our final set of operators is complete and non-redundant. We also examine the odd-parity sector, to conclude that the first operators appear at the p8-order (NNLO).

  17. Chiral perturbation theory for the Wilson lattice action

    SciTech Connect

    Rupak, Gautam; Shoresh, Noam

    2002-01-25

    The authors extend chiral perturbation theory to include linear dependence on the lattice spacing a for the Wilson action. The perturbation theory is written as a double expansion in the small quark mass m{sub q} and lattice spacing a. They present formulae for the mass and decay constant of a flavor-non-singlet meson in this scheme to order a and m{sub q}{sup 2}. The extension to the partially quenched theory is also described.

  18. Staggered chiral perturbation theory in the two-flavor case

    SciTech Connect

    Du Xining

    2010-07-01

    I study two-flavor staggered chiral perturbation theory in the light pseudoscalar sector. The pion mass and decay constant are calculated through next-to-leading order in the partially-quenched case. In the limit where the strange quark mass is large compared to the light quark masses and the taste splittings, I show that the SU(2) staggered chiral theory emerges from the SU(3) staggered chiral theory, as expected. Explicit relations between SU(2) and SU(3) low energy constants and taste-violating parameters are given. The results are useful for SU(2) chiral fits to asqtad data and allow one to incorporate effects from varying strange quark masses.

  19. Electroproduction of pions at threshold in chiral perturbation theory

    SciTech Connect

    Lee, T.S.H.; Bernard, V.; Kaiser, N.; Meissner, U.G.

    1995-08-01

    The electroproduction of pions off protons close to threshold is studied within the framework of baryon chiral perturbation theory. The approach is based on the fundamental QCD property that at low energies the strong interactions are dictated by the spontaneously broken chiral symmetry. The calculation was done up to the 1-loop level by carrying out order-by-order renormalization procedures. A thorough study of the low-energy theorems related to electroproduction of pions was carried out. Our study showed how the axial radius of the nucleon can be related to the S-wave multipoles E{sub 0+}{sup (-)} and L{sub 0+}{sup (-)}.

  20. Including the {delta}(1232) resonance in baryon chiral perturbation theory

    SciTech Connect

    Hacker, C.; Wies, N.; Scherer, S.; Gegelia, J.

    2005-11-01

    Baryon chiral perturbation theory with explicit {delta}(1232) degrees of freedom is considered. The most general interactions of pions, nucleons, and {delta} consistent with all underlying symmetries as well as with the constraint structure of higher-spin fields are constructed. By use of the extended on-mass-shell renormalization scheme, a manifestly Lorentz-invariant effective-field theory with a systematic power counting is obtained. As applications, we discuss the mass of the nucleon, the pion-nucleon {sigma} term, and the pole of the {delta} propagator.

  1. Improving the ultraviolet behavior in baryon chiral perturbation theory

    SciTech Connect

    Djukanovic, D.; Schindler, M.R.; Scherer, S.; Gegelia, J.

    2005-08-15

    We introduce a new formulation of baryon chiral perturbation theory which improves the ultraviolet behavior of propagators and can be interpreted as a smooth cutoff regularization scheme. It is equivalent to the standard approach, preserves all symmetries, and therefore satisfies the Ward identities. Our formulation is equally well defined in the vacuum, one-nucleon, and few-nucleon sectors of the theory. The equations (Bethe-Salpeter, Lippmann-Schwinger, etc.) for the scattering amplitudes of the few-nucleon sector are free of divergences in the new approach. Unlike the usual cutoff regularization, our 'cutoffs' are parameters of the Lagrangian and do not have to be removed.

  2. Chiral perturbation theory and off-shell electromagnetic form factors

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S.

    1995-05-10

    The off-shell electromagnetic vertex of pions and kaons is calculated to {ital O}({ital p}{sup 4}) in the momentum expansion within the framework of chiral perturbation theory to one loop. The formalism of Gasser and Leutwyler is extended to accommodate the most general form for off-shell Green`s functions in the pseudoscalar meson sector. To that end we identify the structures at {ital O}({ital p}{sup 4}) which were initially removed by using the equation of motion of the lowest-order lagrangian. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  3. Virtual Compton scattering off the nucleon in chiral perturbation theory

    SciTech Connect

    Hemmert, T.R.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-03-01

    We investigate the spin-independent part of the virtual Compton scattering (VCS) amplitude off the nucleon within the framework of chiral perturbation theory. We perform a consistent calculation to third order in external momenta according to Weinberg`s power counting. With this calculation we can determine the second- and fourth-order structure-dependent coefficients of the general low-energy expansion of the spin-averaged VCS amplitude based on gauge invariance, crossing symmetry, and the discrete symmetries. We discuss the kinematical regime to which our calculation can be applied and compare our expansion with the multipole expansion by Guichon, Liu, and Thomas. We establish the connection of our calculation with the generalized polarizabilities of the nucleon where it is possible. {copyright} {ital 1997} {ital The American Physical Society}

  4. A quenched study of the Schroedinger functional with chirally rotated boundary conditions: non-perturbative tuning

    SciTech Connect

    Gonzalez-Lopez, Jennifer; Jansen, Karl; Renner, Dru B.; Shindler, Andrea

    2013-02-01

    The use of chirally rotated boundary conditions provides a formulation of the Schroedinger functional that is compatible with automatic O(a) improvement of Wilson fermions up to O(a) boundary contributions. The elimination of bulk O(a) effects requires the non-perturbative tuning of the critical mass and one additional boundary counterterm. We present the results of such a tuning in a quenched setup for several values of the renormalized gauge coupling, from perturbative to non-perturbative regimes, and for a range of lattice spacings. We also check that the correct boundary conditions and symmetries are restored in the continuum limit.

  5. Even- and Odd-Parity Charmed Meson Masses in Heavy Hadron Chiral Perturbation Theory

    SciTech Connect

    Thomas Mehen; Roxanne Springer

    2005-03-01

    We derive mass formulae for the ground state, J{sup P} = 0{sup -} and 1{sup -}, and first excited even-parity, J{sup P} = 0{sup +} and 1{sup +}, charmed mesons including one loop chiral corrections and {Omicron}(1/m{sub c}) counterterms in heavy hadron chiral perturbation theory. We show a variety of fits to the current data. We find that certain parameter relations in the parity doubling model are not renormalized at one loop, providing a natural explanation for the equality of the hyperfine splittings of ground state and excited doublets.

  6. Nucleon-to-{delta} axial transition form factors in relativistic baryon chiral perturbation theory

    SciTech Connect

    Geng, L. S.; Camalich, J. Martin; Alvarez-Ruso, L.; Vacas, M. J. Vicente

    2008-07-01

    We report a theoretical study of the axial nucleon-to-delta (1232) (N{yields}{delta}) transition form factors up to one-loop order in relativistic baryon chiral perturbation theory. We adopt a formalism in which the {delta} couplings obey the spin-3/2 gauge symmetry and, therefore, decouple the unphysical spin-1/2 fields. We compare the results with phenomenological form factors obtained from neutrino bubble-chamber data and in quark models.

  7. Comparison of the extended linear {sigma} model and chiral perturbation theory

    SciTech Connect

    Alvarez, W.P.; Kubodera, K.; Myhrer, F.

    2005-09-01

    The pion-nucleon-scattering amplitudes are calculated in tree approximation with the use of the extended linear sigma model (ELSM) as well as heavy-baryon chiral perturbation theory (HB{chi}PT), and the nonrelativistic forms of the ELSM results are compared with those of HB{chi}PT. We find that the amplitudes obtained in ELSM do not agree with those derived from the more fundamental effective approach, HB{chi}PT.

  8. Rare decay {eta}{r_arrow}{pi}{pi}{gamma}{gamma} in chiral perturbation theory

    SciTech Connect

    Knoechlein, G.; Scherer, S.; Drechsel, D.

    1996-04-01

    We investigate the rare radiative {eta} decay modes {eta}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma}{gamma} and {eta}{r_arrow}{pi}{sup 0}{pi}{sup 0}{gamma}{gamma} within the framework of chiral perturbation theory at {ital O}({ital p}{sup 4}). We present photon spectra and partial decay rates for both processes as well as a Dalitz contour plot for the charged decay. {copyright} {ital 1996 The American Physical Society.}

  9. Pseudoscalar meson mass to two loops in three-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.; Danielsson, Niclas

    2004-12-01

    This paper presents a first study of the pseudoscalar meson masses to two loops, or next-to-next-to-leading order, within the supersymmetric formulation of partially quenched chiral perturbation theory (PQ{chi}PT). The expression for the pseudoscalar meson mass in the case of three valence and three sea quarks with equal masses, but different from each other, is given to O(p{sup 6}), along with a numerical analysis.

  10. Consistency tests of Ampcalculator and chiral amplitudes in SU(3) Chiral Perturbation Theory: A tutorial-based approach

    NASA Astrophysics Data System (ADS)

    Ananthanarayan, B.; Das, Diganta; Sentitemsu Imsong, I.

    2012-10-01

    Ampcalculator (AMPC) is a Mathematica © based program that was made publicly available some time ago by Unterdorfer and Ecker. It enables the user to compute several processes at one loop (upto O( p 4) in SU(3) chiral perturbation theory. They include computing matrix elements and form factors for strong and non-leptonic weak processes with at most six external states. It was used to compute some novel processes and was tested against well-known results by the original authors. Here we present the results of several thorough checks of the package. Exhaustive checks performed by the original authors are not publicly available, and hence the present effort. Some new results are obtained from the software especially in the kaon odd-intrinsic parity non-leptonic decay sector involving the coupling G 27. Another illustrative set of amplitudes at tree level we provide is in the context of τ-decays with several mesons including quark mass effects, of use to the BELLE experiment. All eight meson-meson scattering amplitudes have been checked. The Kaon-Compton amplitude has been checked and a minor error in the published results has been pointed out. This exercise is a tutorial-based one, wherein several input and output notebooks are also being made available as ancillary files on the arXiv. Some of the additional notebooks we provide contain explicit expressions that we have used for comparison with established results. The purpose is to encourage users to apply the software to suit their specific needs. An automatic amplitude generator of this type can provide error-free outputs that could be used as inputs for further simplification, and in varied scenarios such as applications of chiral perturbation theory at finite temperature, density and volume. This can also be used by students as a learning aid in low-energy hadron dynamics.

  11. Pion-nucleon scattering in covariant baryon chiral perturbation theory with explicit Delta resonances

    NASA Astrophysics Data System (ADS)

    Yao, De-Liang; Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A. M.; Gegelia, J.; Krebs, H.; Meißner, Ulf-G.

    2016-05-01

    We present the results of a third order calculation of the pion-nucleon scattering amplitude in a chiral effective field theory with pions, nucleons and delta resonances as explicit degrees of freedom. We work in a manifestly Lorentz invariant formulation of baryon chiral perturbation theory using dimensional regularization and the extended on-mass-shell renormalization scheme. In the delta resonance sector, the on mass-shell renormalization is realized as a complex-mass scheme. By fitting the low-energy constants of the effective Lagrangian to the S- and P -partial waves a satisfactory description of the phase shifts from the analysis of the Roy-Steiner equations is obtained. We predict the phase shifts for the D and F waves and compare them with the results of the analysis of the George Washington University group. The threshold parameters are calculated both in the delta-less and delta-full cases. Based on the determined low-energy constants, we discuss the pion-nucleon sigma term. Additionally, in order to determine the strangeness content of the nucleon, we calculate the octet baryon masses in the presence of decuplet resonances up to next-to-next-to-leading order in SU(3) baryon chiral perturbation theory. The octet baryon sigma terms are predicted as a byproduct of this calculation.

  12. Nonfactorization of four-quark condensates at low energies within chiral perturbation theory

    SciTech Connect

    Gomez Nicola, A.; Pelaez, J. R.; Ruiz de Elvira, J.

    2010-10-01

    Four-quark correlators and the factorization hypothesis are analyzed in the meson sector within chiral perturbation theory. We define the four-quark condensate as lim{sub x{yields}0}, which is equivalent to other definitions commonly used in the literature. Factorization of the four-quark condensate holds to leading and next to leading order. However, at next to next to leading order, a term with a nontrivial space-time dependence in the four-quark correlator yields a divergent four-quark condensate, whereas the two-quark condensate and the scalar susceptibility are finite. Such a nonfactorization term vanishes only in the chiral limit. We also comment on how factorization still holds in the large N{sub c} limit, provided such a limit is taken before renormalization.

  13. The width of the Roper resonance in baryon chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Gegelia, Jambul; Meißner, Ulf-G.; Yao, De-Liang

    2016-09-01

    We calculate the width of the Roper resonance at next-to-leading order in a systematic expansion of baryon chiral perturbation theory with pions, nucleons, and the delta and Roper resonances as dynamical degrees of freedom. Three unknown low-energy constants contribute up to the given order. One of them can be fixed by reproducing the empirical value for the width of the Roper decay into a pion and a nucleon. Assuming that the remaining two couplings of the Roper interaction take values equal to those of the nucleon, the result for the width of the Roper decaying into a nucleon and two pions is consistent with the experimental value.

  14. Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2008-06-15

    Recent attempts to determine the pion polarizability by dispersion relations yield values that disagree with the predictions of chiral perturbation theory. These dispersion relations are based on specific forms for the absorptive part of the Compton amplitudes. The analytic properties of these forms are examined, and the strong enhancement of intermediate-meson contributions is shown to be connected with spurious singularities. If the basic requirements of dispersion relations are taken into account, the results of dispersion theory and effective field theory are not inconsistent.

  15. Three-flavor partially quenched chiral perturbation theory at NNLO for meson masses and decay constants

    SciTech Connect

    Bijnens, Johan; Danielsson, Niclas; Laehde, Timo A.

    2006-04-01

    We discuss partially quenched chiral perturbation theory (PQ{chi}PT) and possible fitting strategies to lattice QCD data at next-to-next-to-leading order (NNLO) in the mesonic sector. We also present a complete calculation of the masses of the charged pseudoscalar mesons, in the supersymmetric formulation of PQ{chi}PT. Explicit analytical results are given for up to three nondegenerate sea-quark flavors, along with the previously unpublished expression for the pseudoscalar meson decay constant for three nondegenerate sea-quark flavors. The numerical analysis in this paper demonstrates that the corrections at NNLO are sizable, as expected from earlier work.

  16. Elastic pion-nucleon scattering in chiral perturbation theory: A fresh look

    NASA Astrophysics Data System (ADS)

    Siemens, D.; Bernard, V.; Epelbaum, E.; Gasparyan, A.; Krebs, H.; Meißner, Ulf-G.

    2016-07-01

    Elastic pion-nucleon scattering is analyzed in the framework of chiral perturbation theory up to fourth order within the heavy-baryon expansion and a covariant approach based on an extended on-mass-shell renormalization scheme. We discuss in detail the renormalization of the various low-energy constants and provide explicit expressions for the relevant β functions and the finite subtractions of the power-counting breaking terms within the covariant formulation. To estimate the theoretical uncertainty from the truncation of the chiral expansion, we employ an approach which has been successfully applied in the most recent analysis of the nuclear forces. This allows us to reliably extract the relevant low-energy constants from the available scattering data at low energy. The obtained results provide clear evidence that the breakdown scale of the chiral expansion for this reaction is related to the Δ resonance. The explicit inclusion of the leading contributions of the Δ isobar is demonstrated to substantially increase the range of applicability of the effective field theory. The resulting predictions for the phase shifts are in an excellent agreement with the predictions from the recent Roy-Steiner-equation analysis of pion-nucleon scattering.

  17. Renormalization of the low-energy constants of chiral perturbation theory from loops with dynamical vector mesons

    NASA Astrophysics Data System (ADS)

    Terschlüsen, Carla; Leupold, Stefan

    2016-07-01

    Starting from a relativistic Lagrangian for pseudoscalar Goldstone bosons and vector mesons in the antisymmetric tensor representation, a one-loop calculation is performed to pin down the divergent structures that appear for the effective low-energy action at chiral orders Q2 and Q4 . The corresponding renormalization-scale dependencies of all low-energy constants up to chiral order Q4 are determined. Calculations are carried out for both the pseudoscalar octet and the pseudoscalar nonet, the latter in the framework of chiral perturbation theory in the limit of a large number of colors.

  18. A Lattice Non-Perturbative Definition of an SO(10) Chiral Gauge Theory and Its Induced Standard Model

    NASA Astrophysics Data System (ADS)

    Wen, Xiao-Gang

    2013-11-01

    The standard model is a chiral gauge theory where the gauge fields couple to the right-hand and the left-hand fermions differently. The standard model is defined perturbatively and describes all elementary particles (except gravitons) very well. However, for a long time, we do not know if we can have a non-perturbative definition of the standard model as a Hamiltonian quantum mechanical theory. Here we propose a way to give a modified standard model (with 48 two-component Weyl fermions) a non-perturbative definition by embedding the modified standard model into an SO (10) chiral gauge theory. We show that the SO (10) chiral gauge theory can be put on a lattice (a 3D spatial lattice with a continuous time) if we allow fermions to interact. Such a non-perturbatively defined standard model is a Hamiltonian quantum theory with a finite-dimensional Hilbert space for a finite space volume. More generally, using the defining connection between gauge anomalies and the symmetry-protected topological orders, one can show that any truly anomaly-free chiral gauge theory can be non-perturbatively defined by putting it on a lattice in the same dimension.

  19. K{yields}{pi} and K{yields}0 in 2+1 flavor partially quenched chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, J.; Li, S.; Lin, M. F.

    2008-11-01

    We calculate results for K{yields}{pi} and K{yields}0 matrix elements to next-to-leading order in 2+1 flavor partially quenched chiral perturbation theory. Results are presented for both the {delta}I=1/2 and 3/2 channels, for chiral operators corresponding to current-current, gluonic penguin, and electroweak penguin 4-quark operators. These formulas are useful for studying the chiral behavior of currently available 2+1 flavor lattice QCD results, from which the low-energy constants of the chiral effective theory can be determined. The low-energy constants of these matrix elements are necessary for an understanding of the {delta}I=1/2 rule, and for calculations of {epsilon}{sup '}/{epsilon} using current lattice QCD simulations.

  20. Mass spectra of heavy-light mesons in heavy hadron chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Alhakami, Mohammad H.

    2016-05-01

    We study the masses of the low-lying charm and bottom mesons within the framework of heavy hadron chiral perturbation theory (HHChPT). We work to third order in the chiral expansion, where meson loops contribute. In contrast to previous approaches, we use physical meson masses in evaluating these loops. This ensures that their imaginary parts are consistent with the observed widths of the D mesons. The lowest odd- and even-parity, strange and nonstrange charm mesons provide enough constraints to determine only certain linear combinations of the low-energy constants in the effective Lagrangian. We comment on how lattice QCD could provide further information to disentangle these constants. Then, we use the results from the charm sector to predict the spectrum of odd and even parity of the bottom mesons. The predicted masses from our theory are in good agreement with experimentally measured masses for the case of the odd-parity sector. For the even-parity sector, the B -meson states have not yet been observed; thus, our results provide useful information for experimentalists investigating such states. The near degeneracy of nonstrange and strange scalar B mesons is confirmed in our predictions using HHChPT. We show why previous approaches of using HHChPT in studying the mass degeneracy in the scalar states of charm and bottom meson sectors gave unsatisfactory results.

  1. Nuclear-matter equation of state with consistent two- and three-body perturbative chiral interactions

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2014-04-01

    We compute the energy per particle of infinite symmetric nuclear matter from chiral NLO3 (next-to-next-to-next-to-leading order) two-body potentials plus NLO2 three-body forces. The low-energy constants of the chiral three-nucleon force that cannot be constrained by two-body observables are fitted to reproduce the triton binding energy and the H3-He3 Gamow-Teller transition matrix element. In this way, the saturation properties of nuclear matter are reproduced in a parameter-free approach. The equation of state is computed up to third order in many-body perturbation theory, with special emphasis on the role of the third-order particle-hole diagram. The dependence of these results on the cutoff scale and regulator function is studied. We find that the inclusion of three-nucleon forces consistent with the applied two-nucleon interaction leads to a reduced dependence on the choice of the regulator only for lower values of the cutoff.

  2. Equation of state of imbalanced cold matter from chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    Carignano, Stefano; Mammarella, Andrea; Mannarelli, Massimo

    2016-03-01

    We study the thermodynamic properties of matter at vanishing temperature for nonextreme values of the isospin chemical potential and of the strange quark chemical potential. From the leading-order pressure obtained by maximizing the static chiral Lagrangian density, we derive a simple expression for the equation of state in the pion condensed phase and in the kaon condensed phase. We find an analytical expression for the maximum of the ratio between the energy density and the Stefan-Boltzmann energy density and for the isospin chemical potential at the peak, both in good agreement with lattice simulations of quantum chromodynamics. We speculate on the location of the crossover from the Bose-Einstein condensate state to the Bardeen-Cooper-Schrieffer state by a simple analysis of the thermodynamic properties of the system. For μI≳2 mπ, the leading-order chiral perturbation theory breaks down; for example, it underestimates the energy density of the system and leads to a wrong asymptotic behavior.

  3. Off-shell electromagnetic form factors of pions and kaons in chiral perturbation theory

    SciTech Connect

    Rudy, T.E.; Fearing, H.W.; Scherer, S. )

    1994-07-01

    The off-shell electromagnetic vertex of a (pseudo)scalar particle contains, in general, two form factors [ital F] and [ital G] which depend, in addition to the squared momentum transfer, on the invariant masses associated with the initial and final legs of the vertex. Chiral perturbation theory to one loop is used to calculate the off-shell form factors of pions and kaons. The formalism of Gasser and Leutwyler, which was previously used to calculate the on-shell limit of the form factor [ital F], is extended to accommodate the most general form for off-shell Green's functions in the pseudoscalar meson sector. We find that chiral symmetry predicts that the form factors [ital F] of the charged pions and kaons go off-shell in the same way, i.e., the off-shell slope at the real photon point is given by the same new phenomenological constant [beta][sub 1]. Furthermore, it is shown that at order [ital p][sup 4] the form factor [ital F] of the [ital K][sup 0] does not show any off-shell dependence. The form factors [ital G] are all related to the form factors [ital F] in the correct fashion as required by the Ward-Takahashi identity. Numerical results for different off-shell kinematics are presented.

  4. Chirality of tensor perturbations for complex values of the Immirzi parameter

    NASA Astrophysics Data System (ADS)

    Bethke, Laura; Magueijo, João

    2012-03-01

    In this communication, we generalize previous work on tensor perturbations in a de Sitter background in terms of Ashtekar variables to cover all complex values of the Immirzi parameter γ (previous work was restricted to imaginary γ). Particular attention is paid to the case of real γ. Following the same approach as in the imaginary case, we can obtain physical graviton states by invoking reality and torsion-free conditions. The Hamiltonian in terms of graviton states has the same form whether γ has a real part or not; however, changes occur for the vacuum energy and fluctuations. Specifically, we observe a γ-dependent chiral asymmetry in the vacuum fluctuations only if γ has an imaginary part. Ordering prescriptions also change this asymmetry. We thus present a measurable result for CMB polarization experiments that could shed light on the workings of quantum gravity.

  5. Heavy-baryon chiral perturbation theory approach to thermal neutron capture on {sup 3}He

    SciTech Connect

    Lazauskas, Rimantas; Park, Tae-Sun

    2011-03-15

    The cross section for radiative thermal neutron capture on {sup 3}He ({sup 3}He+n{yields}{sup 4}He+{gamma}; known as the hen reaction) is calculated based on heavy-baryon chiral perturbation theory. The relevant M1 operators are derived up to next-to-next-to-next-to-leading order (N{sup 3}LO). The initial and final nuclear wave functions are obtained from the rigorous Faddeev-Yakubovski equations for five sets of realistic nuclear interactions. Up to N{sup 3}LO, the M1 operators contain two low-energy constants, which appear as the coefficients of nonderivative two-nucleon contact terms. After determining these two constants using the experimental values of the magnetic moments of the triton and {sup 3}He, we carry out a parameter-free calculation of the hen cross section. The results are in good agreement with the data.

  6. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Kao, C.-W.; Pasquini, Barbara; Vanderhaeghen, Marc

    2004-12-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering at O(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low-energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the virtual Compton scattering amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double-polarization experiments which allow one to access these spin-flip GPs of the nucleon.

  7. New predictions for generalized spin polarizabilities from heavy baryon chiral perturbation theory

    SciTech Connect

    Chung-Wen Kao; Barbara Pasquini; Marc Vanderhaeghen

    2004-08-01

    We extract the next-to-next-to-leading order results for spin-flip generalized polarizabilities (GPs) of the nucleon from the spin-dependent amplitudes for virtual Compton scattering (VCS) at {Omicron}(p{sup 4}) in heavy baryon chiral perturbation theory. At this order, no unknown low energy constants enter the theory, allowing us to make absolute predictions for all spin-flip GPs. Furthermore, by using constraint equations between the GPs due to nucleon crossing combined with charge conjugation symmetry of the VCS amplitudes, we get a next-to-next-to-next-to-leading order prediction for one of the GPs. We provide estimates for forthcoming double polarization experiments which allow to access these spin-flip GPs of the nucleon.

  8. Reply to 'Comment on 'Polarizability of the pion: No conflict between dispersion theory and chiral perturbation theory''

    SciTech Connect

    Pasquini, B.; Drechsel, D.; Scherer, S.

    2010-02-15

    We show that the alleged discrepancies between chiral perturbation theory (ChPT) and dispersion theory, reported for the polarizability of the pion by Fil'kov and Kashevarov [Phys. Rev. C 72, 035211 (2005)], result from applying dispersion theory to nonanalytic functions.

  9. Twisted mass chiral perturbation theory at next-to-leading order

    NASA Astrophysics Data System (ADS)

    Sharpe, Stephen R.; Wu, Jackson M.

    2005-04-01

    We study the properties of pions in twisted mass lattice QCD (with two degenerate flavors) using chiral perturbation theory (χPT). We work to next-to-leading order (NLO) in a power-counting scheme in which mq˜aΛ2QCD, with mq the physical quark mass and a the lattice spacing. We argue that automatic O(a) improvement of physical quantities at maximal twist, which has been demonstrated in general if mq≫aΛ2QCD, holds even if mq˜aΛ2QCD, as long as one uses an appropriate nonperturbative definition of the twist angle, with the caveat that we have shown this only through NLO in our chiral expansion. We demonstrate this with explicit calculations, for arbitrary twist angle, of all pionic quantities that involve no more than a single pion in the initial and final states: masses, decay constants, form factors, and condensates, as well as the differences between alternate definitions of twist angle. We also calculate the axial and pseudoscalar form factors of the pion, quantities which violate flavor and parity, and which vanish in the continuum limit. These are of interest because they are not automatically O(a) improved at maximal twist. They allow a determination of the unknown low-energy constants introduced by discretization errors, and provide tests of the accuracy of χPT at NLO. We extend our results into the regime where mq˜a2Λ3QCD, and argue in favor of a recent proposal that automatic O(a) improvement at maximal twist remains valid in this regime.

  10. Chiral Perturbation Theory, the 1/N_c expansion and Regge behavior determine the structure of the lightest scalar meson

    SciTech Connect

    Pelaez, J. R.; Michael R. Pennington; de Elvira, J. Ruiz; Wilson, D. J.

    2011-11-01

    The leading 1/N{sub c} behavior of Unitarized Chiral Perturbation Theory distinguishes the nature of the {rho} and the {sigma}. At one loop order the {rho} is a {bar q}q meson, while the {sigma} is not. However, semi-local duality between resonances and Regge behaviour cannot be satisfied for larger N{sub c}, if such a distinction holds. While the {sigma} at N{sub c}= 3 is inevitably dominated by its di-pion component, Unitarised Chiral Perturbation Theory beyond one loop order reveals that as N{sub c} increases above 6-8, the {sigma} has a sub-dominant {bar q}q fraction up at 1.2 GeV. Remarkably this ensures semi-local duality is fulfilled for the range of N{sub c} {approx}< 15-30, where the unitarization procedure adopted applies.

  11. Nuclear structure with accurate chiral perturbation theory nucleon-nucleon potential: Application to 6Li and 10B

    SciTech Connect

    Navratil, P; Caurier, E

    2003-10-14

    The authors calculate properties of A = 6 system using the accurate charge-dependent nucleon-nucleon (NN) potential at fourth order of chiral perturbation theory. By application of the ab initio no-core shell model (NCSM) and a variational calculation in the harmonic oscillator basis with basis size up to 16 {h_bar}{Omega} they obtain the {sup 6}Li binding energy of 28.5(5) MeV and a converged excitation spectrum. Also, they calculate properties of {sup 10}B using the same NN potential in a basis space of up to 8 {h_bar}{Omega}. The results are consistent with results obtained by standard accurate NN potentials and demonstrate a deficiency of Hamiltonians consisting of only two-body terms. At this order of chiral perturbation theory three-body terms appear. It is expected that inclusion of such terms in the Hamiltonian will improve agreement with experiment.

  12. Weak solution of the non-perturbative renormalization group equation to describe dynamical chiral symmetry breaking

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Kumamoto, Shin-Ichiro; Sato, Daisuke

    2014-04-01

    We analyze dynamical chiral symmetry breaking (Dχ SB) in the Nambu-Jona-Lasinio model by using the non-perturbative renormalization group equation. The equation takes the form of a two-dimensional partial differential equation for the multi-fermion effective interactions V(x,t) where x is the bar {ψ }ψ operator and t is the logarithm of the renormalization scale. The Dχ SB occurs due to the quantum corrections, which means it emerges at some finite tc while integrating the equation with respect to t. At t_c some singularities suddenly appear in V which is compulsory in the spontaneous symmetry breakdown. Therefore there is no solution of the equation beyond tc. We newly introduce the notion of a weak solution to get the global solution including the infrared limit t rArr ∞ and investigate its properties. The obtained weak solution is global and unique, and it perfectly describes the physically correct vacuum even in the case of the first order phase transition appearing in a finite-density medium. The key logic of deduction is that the weak solution we defined automatically convexifies the effective potential when treating the singularities.

  13. Muon capture by a proton in heavy baryon chiral perturbation theory

    SciTech Connect

    Fearing, H.W.; Lewis, R.; Mobed, N.; Scherer, S.

    1997-08-01

    The matrix element for muon capture by a proton is calculated to O(p{sup 3}) within heavy baryon chiral perturbation theory using the new O(p{sup 3}) Lagrangian of Ecker and Moj{hacek z}i{hacek s}. External nucleon fields are renormalized using the appropriate definition of the wave function renormalization factor Z{sub N}. Our expression for Z{sub N} differs somewhat from that found in the existing literature, but is the one which is consistent with the Lagrangian we use and the one which ensures, within our approach, the nonrenormalization of the vector coupling as required by the conserved vector current. Expressions for the standard muon capture form factors are derived and compared to experimental data and we determine three of the coefficients of the Ecker-Moj{hacek z}i{hacek s} Lagrangian, namely, b{sub 7}, b{sub 19}, and b{sub 23}. {copyright} {ital 1997} {ital The American Physical Society}

  14. Field transformations and the classical equation of motion in chiral perturbation theory

    SciTech Connect

    Scherer, S.; Fearing, H.W.

    1995-12-01

    The construction of effective Lagrangians commonly involves the application of the ``classical equation of motion`` to eliminate redundant structures and thus generate the minimal number of independent terms. We investigate this procedure in the framework of chiral perturbation theory with particular emphasis on the new features which appear at {ital O}({ital p}{sup 6}). The use of the ``classical equation of motion`` is interpreted in terms of field transformations. Such an interpretation is crucial if one wants to bring a given Lagrangian into a canonical form with a minimal number of terms. We emphasize that the application of field transformations leads to a modification of the coefficients of higher-order terms as well as eliminating structures, or what is equivalent, expressing certain structures in terms of already known different structures. This will become relevant once one considers the problem of expressing in canonical form a model effective interaction containing terms beyond next-to-leading order, i.e., beyond {ital O}({ital p}{sup 4}). In such circumstances the naive application of the clasical equation of motion to simply drop terms, as is commonly done at lowest order, leads to subtle errors, which we discuss.

  15. The Kaon B-parameter in mixed action chiral perturbation theory

    SciTech Connect

    Aubin, C.; Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2006-09-01

    We calculate the kaon B-parameter, B{sub K}, in chiral perturbation theory for a partially quenched, mixed action theory with Ginsparg-Wilson valence quarks and staggered sea quarks. We find that the resulting expression is similar to that in the continuum, and in fact has only two additional unknown parameters. At one-loop order, taste-symmetry violations in the staggered sea sector only contribute to flavor-disconnected diagrams by generating an {Omicron}(a{sup 2}) shift to the masses of taste-singlet sea-sea mesons. Lattice discretization errors also give rise to an analytic term which shifts the tree-level value of B{sub K} by an amount of {Omicron}(a{sup 2}). This term, however, is not strictly due to taste-breaking, and is therefore also present in the expression for B{sub K} for pure G-W lattice fermions. We also present a numerical study of the mixed B{sub K} expression in order to demonstrate that both discretization errors and finite volume effects are small and under control on the MILC improved staggered lattices.

  16. Decay constants of pseudoscalar mesons to two loops in three-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.

    2005-05-01

    This paper presents a first study of the decay constants of the charged, or flavor-off-diagonal, pseudoscalar mesons to two loops for three flavors of sea quarks, in partially quenched chiral perturbation theory (PQ{chi}PT). Explicit analytical expressions up to O(p{sup 6}) in the momentum expansion are given. The calculations have been performed within the supersymmetric formulation of PQ{chi}PT. We also present some numerical results to indicate the size of the corrections.

  17. Doubly heavy baryons and quark-diquark symmetry in quenched and partially quenched chiral perturbation theory

    SciTech Connect

    Thomas Mehen; Brian C. Tiburzi

    2006-07-17

    We extend the chiral Lagrangian with heavy quark-diquark symmetry to quenched and partially quenched theories. These theories are used to derive formulae for the chiral extrapolation of masses and hyperfine splittings of doubly heavy baryons in lattice QCD simulations. A quark-diquark symmetry prediction for the hyperfine splittings of heavy mesons and doubly heavy baryons is rather insensitive to chiral corrections in both quenched and partially quenched QCD. Extrapolation formulae for the doubly heavy baryon electromagnetic transition moments are also determined for the partially quenched theory.

  18. Masses and decay constants of pseudoscalar mesons to two loops in two-flavor partially quenched chiral perturbation theory

    SciTech Connect

    Bijnens, Johan; Laehde, Timo A.

    2005-10-01

    This paper presents a first study of the masses and decay constants of the charged, or flavor-off-diagonal, pseudoscalar mesons to two loops for two flavors of sea-quarks, in Partially Quenched Chiral Perturbation Theory (PQ{chi}PT). Explicit analytical expressions up to O(p{sup 6}) in the momentum expansion are given. The calculations have been performed within the supersymmetric formulation of PQ{chi}PT. A numerical analysis is done to indicate the size of the corrections.

  19. Chiral perturbation theory for staggered sea quarks and Ginsparg-Wilson valence quarks

    SciTech Connect

    Baer, Oliver; Bernard, Claude; Rupak, Gautam; Shoresh, Noam

    2005-09-01

    We study lattice QCD with staggered sea and Ginsparg-Wilson valence quarks. The Symanzik effective action for this mixed lattice theory, including the lattice spacing contributions of O(a{sup 2}), is derived. Using this effective theory we construct the leading-order chiral Lagrangian. The masses and decay constants of pseudoscalars containing two Ginsparg-Wilson valence quarks are computed at one-loop order.

  20. B -> d* l nu and b -> d l nu form-factors in staggered chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Van de Water, Ruth S.; /Fermilab

    2005-12-01

    We calculate the B {yields} D and B {yields} D* form factors at zero recoil in Staggered Chiral Perturbation Theory. We consider heavy-light mesons in which only the light (u, d, or s) quark is staggered; current lattice simulations generally use a highly improved action such as the Fermilab or NRQCD action for the heavy (b or c) quark. We work to lowest order in the heavy quark expansion and to next-to-leading order in the chiral expansion. We present results for a partially quenched theory with three sea quarks in which there are no mass degeneracies (the ''1+1+1'' theory) and for a partially quenched theory in which the u and d sea quark masses are equal (the ''2+1'' theory). We also present results for full (2+1) QCD, along with a numerical estimate of the size of staggered discretization errors. Finally, we calculate the finite volume corrections to the form factors and estimate their numerical size in current lattice simulations.

  1. Low energy constants of S U (2 ) partially quenched chiral perturbation theory from Nf=2 +1 domain wall QCD

    NASA Astrophysics Data System (ADS)

    Boyle, P. A.; Christ, N. H.; Garron, N.; Jung, C.; Jüttner, A.; Kelly, C.; Mawhinney, R. D.; McGlynn, G.; Murphy, D. J.; Ohta, S.; Portelli, A.; Sachrajda, C. T.

    2016-03-01

    We have performed fits of the pseudoscalar masses and decay constants, from a variety of the RBC-UKQCD Collaboration's domain wall fermion ensembles, to S U (2 ) partially quenched chiral perturbation theory at next-to-leading order (NLO) and next-to-next-to-leading order (NNLO). We report values for nine NLO and eight linearly independent combinations of NNLO partially quenched low-energy constants, which we compare to other lattice and phenomenological determinations. We discuss the size of successive terms in the chiral expansion and use our large set of low-energy constants to make predictions for mass splittings due to QCD isospin-breaking effects and the S-wave π π scattering lengths. We conclude that, for the range of pseudoscalar masses explored in this work, 115 MeV ≲mPS≲430 MeV , the NNLO S U (2 ) expansion is quite robust and can fit lattice data with percent-scale accuracy.

  2. Higher moments of nucleon spin structure functions in heavy baryon chiral perturbation theory and in a resonance model

    SciTech Connect

    C. Kao; D. Drechsel; S. Kamalov; M. Vanderhaeghen

    2003-11-01

    The third moment d{sub 2} of the twist-3 part of the nucleon spin structure function g{sub 2} is generalized to arbitrary momentum transfer Q{sup 2} and is evaluated in heavy baryon chiral perturbation theory (HBChPT) up to order {Omicron}(p{sup 4}) and in a unitary isobar model (MAID). We show how to link d{sub 2} as well as higher moments of the nucleon spin structure functions g{sub 1} and g{sub 2} to nucleon spin polarizabilities. We compare our results with the most recent experimental data, and find a good description of these available data within the unitary isobar model. We proceed to extract the twist-4 matrix element f{sub 2} which appears in the 1/Q{sup 2} suppressed term in the twist expansion of the spin structure function g{sub 1} for proton and neutron.

  3. Axial, induced pseudoscalar, and pion-nucleon form factors in manifestly Lorentz-invariant chiral perturbation theory

    SciTech Connect

    Schindler, M. R.; Fuchs, T.; Scherer, S.; Gegelia, J.

    2007-02-15

    We calculate the nucleon form factors G{sub A} and G{sub P} of the isovector axial-vector current and the pion-nucleon form factor G{sub {pi}}{sub N} in manifestly Lorentz-invariant baryon chiral perturbation theory up to and including order O(p{sup 4}). In addition to the standard treatment including the nucleon and pions, we also consider the axial-vector meson a{sub 1} as an explicit degree of freedom. This is achieved by using the reformulated infrared renormalization scheme. We find that the inclusion of the axial-vector meson effectively results in one additional low-energy coupling constant that we determine by a fit to the data for G{sub A}. The inclusion of the axial-vector meson results in an improved description of the experimental data for G{sub A}, while the contribution to G{sub P} is small.

  4. Neutral pion threshold production at Q(2) = 0.05 GeV(2)/c(2) and chiral perturbation theory.

    PubMed

    Merkel, H; Bartsch, P; Baumann, D; Bermuth, J; Bernstein, A M; Bohinc, K; Böhm, R; Clawiter, N; Derber, S; Ding, M; Distler, M O; Ewald, I; Friedrich, J M; Friedrich, J; Jennewein, P; Kahrau, M; Kohl, M; Krygier, K W; Kuss, M; Liesenfeld, A; Merle, P; Miskimen, R A; Müller, U; Neuhausen, R; Pavan, M M; Pospischil, Th; Potokar, M; Rosner, G; Schmieden, H; Seimetz, M; Sirca, S; Wagner, A; Walcher, Th; Weis, M

    2002-01-01

    New data are presented on the p(e,e'p)pi(0) reaction at threshold at a four-momentum transfer of Q(2) = 0.05 GeV(2)/c(2). The data were taken with the three-spectrometer setup of the A1 Collaboration at the Mainz Microtron MAMI. The complete center of mass solid angle was covered up to a center of mass energy of 4 MeV above threshold. Combined with measurements at three different values of the virtual photon polarization epsilon, the structure functions sigma(T), sigma(L), sigma(TT), and sigma(TL) are determined. The results are compared with calculations in heavy baryon chiral perturbation theory and with a phenomenological model. The measured cross section is significantly smaller than both predictions. PMID:11800938

  5. Weak Solution Method of the Non-Perturbative Renormalization Group Equation to Describe Dynamical Chiral Symmetry Breaking and its Application to Beyond the Ladder Analysis in QCD

    NASA Astrophysics Data System (ADS)

    Aoki, Ken-Ichi; Sato, Daisuke

    The method of non-perturbative renormalization group (NPRG) is applied to the analysis of dynamical chiral symmetry breaking (DχSB) in QCD. We show that the DχSB solution of the NPRG flow equation can be obtained without the bosonization. The solution, having the singular point, can be authorized as the weak solution of partial differential equation, and can be easily evaluated using the method of the characteristic curve. Also we show that our non-ladder extended approximation improves almost perfectly the gauge dependence of the chiral condensates.

  6. Extension of the chiral perturbation theory meson Lagrangian to order {ital p}{sup 6}

    SciTech Connect

    Fearing, H.W.; Scherer, S.

    1996-01-01

    We have constructed the most general chirally invariant Lagrangian {ital scrL}{sub 6} for the meson sector at order {ital p}{sup 6}. The result provides an extension of the standard Gasser-Leutwyler Lagrangian {ital scrL}{sub 4} to one higher order, including as well all the odd intrinsic parity terms in the Lagrangian. The most difficult part of the construction was developing a systematic strategy so as to get all of the independent terms and eliminate the redundant ones in an efficient way. The claim to have obtained the most general Lagrangian relies on this systematic construction and on the elimination of redundant quantities using relations of which we are aware, rather than on a general formal proof of either completeness or independence. The {open_quote}{open_quote}equation-of-motion{close_quote}{close_quote} terms, which are redundant in the sense that they can be transformed away via field transformations, are separated out explicitly. The resulting Lagrangian has been separated into groupings of terms contributing to increasingly more complicated processes, so that one does not have to deal with the full result when calculating {ital p}{sup 6} contributions to simple processes. {copyright} {ital 1995 The American Physical Society.}

  7. Study of K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} in chiral perturbation theory

    SciTech Connect

    Tsuji, K.; Sato, T.

    2008-03-01

    K{sup 0}{yields}{pi}{sup -}e{sup +}{nu}{sub e}e{sup +}e{sup -} decay rates are studied up to the next-to-leading order (O{sup (4)}) in chiral perturbation theory. It is found that the O{sup (4)} terms appreciably modify the shape of the invariant mass distribution of leptons (M{sub 3e{nu}}) and the energy spectrum of neutrinos.

  8. Proton polarisability contribution to the Lamb shift in muonic hydrogen at fourth order in chiral perturbation theory

    NASA Astrophysics Data System (ADS)

    McGovern, Judith

    2013-04-01

    The recent determination of the proton charge radius from the Lamb shift in muonic hydrogen [1] gives a value that differs by many standard deviations from the CODATA value [2] and from the results of recent electron scattering experiments [3]. In the theoretical calculations [4], the least-well-determined contribution is the ``proton polarisability'' contribution. This is the part of the two-photon exchange which involves proton excitations. The dominant effect can be determined via dispersion relations from the proton structure functions, but a subtraction term remains [5,6]. This subtraction term is the amplitude T1(0,Q^2) for forward, zero-energy, doubly-virtual Compton scattering, which we calculate in heavy-baryon chiral perturbation theory, to fourth order in the chiral expansion and with the leading contribution of the γNδ form factor. This provides a model-independent expression for the amplitude in the low-momentum region, which is the dominant one for its contribution to the Lamb shift, and allows us to significantly reduce the theoretical uncertainty in the latter [7].[4pt] [1] R. Pohl et al., Nature 466, 213 (2010).[0pt] [2] P. J. Mohr, B. N. Taylor and D. B. Newell, Rev. Mod. Phys. 80, 633 (2008) [arXiv:0801.0028].[0pt] [3] J. C. Bernauer et al. (A1 Collaboration), Phys. Rev. Lett. 105, 242001 (2010) [arXiv:1007.5076].[0pt] [4] U. D. Jentschura, Ann. Phys. 326, 500 (2011) [arXiv:1011.5275]; E. Borie, Ann. Phys. 327, 733 (2012) [arXiv:1103.1772].[0pt] [5] K. Pachucki, Phys. Rev. A 60, 3593 (1999) [arXiv:physics/9906002].[0pt] [6] C. E. Carlson and M. Vanderhaeghen, Phys. Rev. A 84, 020102 (2011) [arXiv:1101.5965]; also [arXiv:1109.3779].[0pt] [7] M. C. Birse and J. A. McGovern, Eur. Phys. J. A48, 120 (2012) [arXiv:1206.3030].

  9. Chiral perturbation theory for K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay in the continuum and on the lattice

    SciTech Connect

    Golterman, M.F.; Leung, K.C.

    1997-09-01

    In this paper we use one-loop chiral perturbation theory in order to compare lattice computations of the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude with the experimental value. This makes it possible to investigate three systematic effects that plague lattice computations: quenching, finite-volume effects, and the fact that lattice computations have been done at unphysical values of the quark masses and pion external momenta (only this latter effect shows up at the tree level). We apply our results to the most recent lattice computation and find that all three effects are substantial. We conclude that one-loop corrections in chiral perturbation theory help in explaining the discrepancy between lattice results and the real-world value. We also reexamine B{sub K}, which is closely related to the K{sup +}{r_arrow}{pi}{sup +}{pi}{sup 0} decay amplitude by chiral symmetry. {copyright} {ital 1997} {ital The American Physical Society}

  10. Up to N{sup 3}LO heavy-baryon chiral perturbation theory calculation for the M1 properties of three-nucleon systems

    SciTech Connect

    Song, Young-Ho; Lazauskas, Rimantas; Park, Tae-Sun

    2009-06-15

    M1 properties, comprising magnetic moments and radiative capture of thermal neutron observables, are studied in two- and three-nucleon systems. We use meson exchange current derived up to N{sup 3}LO using heavy baryon chiral perturbation theory a la Weinberg. Calculations have been performed for several qualitatively different realistic nuclear Hamiltonians, which permits us to analyze model dependence of our results. Our results are found to be strongly correlated with the effective range parameters such as binding energies and the scattering lengths. Taking into account such correlations, the results are in good agreement with the experimental data with small model dependence.

  11. Determination of SU(2) chiral perturbation theory low energy constants from a precise description of pion-pion scattering threshold parameters

    NASA Astrophysics Data System (ADS)

    Nebreda, J.; Peláez, J. R.; Ríos, G.

    2013-09-01

    We determine the values of the one- and two-loop low energy constants appearing in the SU(2) Chiral Perturbation Theory calculation of pion-pion scattering. For this we use a recent and precise sum rule determination of some scattering lengths and slopes that appear in the effective range expansion. In addition we provide sum rules for these coefficients up to third order in the expansion. Our results when using only the scattering lengths and slopes of the S, P, D, and F waves are consistent with previous determinations but seem to require higher order contributions if they are to accommodate the third order coefficients of the effective range expansion.

  12. Introduction to chiral symmetry

    SciTech Connect

    Koch, V.

    1996-01-08

    These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented.

  13. f{sub 0}(600),{kappa}(800), {rho}(770) and K*(892), quark mass dependence from unitarized SU(3) Chiral Perturbation Theory

    SciTech Connect

    Nebreda, J.; Pelaez, J. R.

    2010-08-05

    We study the strange and non-strange quark mass dependence of the parameters of the f{sub 0}(600),{kappa}(800), {rho}(770) and K*(892) resonances generated from elastic meson-meson scattering using unitarized one-loop Chiral Perturbation Theory. We fit simultaneously all experimental scattering data up to 0.8-1 GeV together with lattice results on decay constants and scattering lengths up to a pion mass of 440 MeV. Then, the strange and non-strange quark masses are varied from the chiral limit up to values of interest for lattice studies. In these amplitudes, the mass and width of the {rho}(770) and K*(892) present a similar and smooth quark mass dependence. In contrast, both scalars present a similar non-analyticity at high quark masses. Nevertheless the f{sub 0}(600) dependence on both quark masses is stronger than for the {kappa}(800) and the vectors. We also confirm the lattice assumption of quark mass independence of the vector two-meson coupling that, in contrast, is violated for scalars.

  14. Nucleon electromagnetic form factors from lattice QCD using 2+1 flavor domain wall fermions on fine lattices and chiral perturbation theory

    SciTech Connect

    Syritsyn, S. N.; Bratt, J. D.; Lin, M. F.; Meyer, H. B.; Negele, J. W.; Pochinsky, A. V.; Procura, M.; Engelhardt, M.; Haegler, Ph.; Hemmert, T. R.; Schroers, W.

    2010-02-01

    We present a high-statistics calculation of nucleon electromagnetic form factors in N{sub f}=2+1 lattice QCD using domain wall quarks on fine lattices, to attain a new level of precision in systematic and statistical errors. Our calculations use 32{sup 3}x64 lattices with lattice spacing a=0.084 fm for pion masses of 297, 355, and 403 MeV, and we perform an overdetermined analysis using on the order of 3600 to 7000 measurements to calculate nucleon electric and magnetic form factors up to Q{sup 2{approx_equal}}1.05 GeV{sup 2}. Results are shown to be consistent with those obtained using valence domain wall quarks with improved staggered sea quarks, and using coarse domain wall lattices. We determine the isovector Dirac radius r{sub 1}{sup v}, Pauli radius r{sub 2}{sup v} and anomalous magnetic moment {kappa}{sub v}. We also determine connected contributions to the corresponding isoscalar observables. We extrapolate these observables to the physical pion mass using two different formulations of two-flavor chiral effective field theory at one loop: the heavy baryon small scale expansion and covariant baryon chiral perturbation theory. The isovector results and the connected contributions to the isoscalar results are compared with experiment, and the need for calculations at smaller pion masses is discussed.

  15. Nucleon and Delta axial-vector couplings in 1/N{sub c}-Baryon Chiral Perturbation Theory

    SciTech Connect

    Goity, Jose Luis; Calle Cordon, Alvaro

    2013-08-01

    In this contribution, baryon axial-vector couplings are studied in the framework of the combined 1/N{sub c} and chiral expansions. This framework is implemented on the basis of the emergent spin-flavor symmetry in baryons at large N{sub c} and HBChPT, and linking both expansions ({xi}-expansion), where 1/N{sub c} is taken to be a quantity order p. The study is carried out including one-loop contributions, which corresponds to order xi to the third for baryon masses and order {xi} square for the axial couplings.

  16. Chiral corrections to the scalar form factor in B{sub q}{yields}D{sub q} transitions

    SciTech Connect

    Eeg, Jan O.; Fajfer, Svjetlana; Kamenik, Jernej F.

    2008-10-01

    We consider chiral loop corrections to the scalar form factor in B{sub q}{yields}D{sub q}l{nu} decays. First we consider chiral corrections to the 1/m{sub Q} suppressed operators and then we propose a procedure for the extraction of the relevant form factor using lattice QCD results. In particular, the extraction of a B*{yields}D* matrix element on the lattice can be used to determine all the necessary 1/m{sub Q} suppressed contributions to the scalar form factor in B{yields}D transitions. In the case of (B{sub s}{yields}D{sub s})/(B{yields}D) decay rate ratios we speculate that effects of kinematics and chiral corrections tend to cancel for the scalar form factor contributions. In particular the 1/m{sub Q} suppression of chiral corrections is compensated by the potentially large SU(3) flavor symmetry breaking corrections. The calculated corrections are relevant for the precise determination of possible new physics effects in B{sub q}{yields}D{sub q}l{nu} decays.

  17. Lattice extraction of K{yields}{pi}{pi} amplitudes to next-to-leading order in partially quenched and in full chiral perturbation theory

    SciTech Connect

    Laiho, Jack; Soni, Amarjit

    2005-01-01

    We show that it is possible to construct {epsilon}{sup '}/{epsilon} to next-to-leading order (NLO) using partially quenched chiral perturbation theory (PQChPT) from amplitudes that are computable on the lattice. We demonstrate that none of the needed amplitudes require 3-momentum on the lattice for either the full theory or the partially quenched theory; nondegenerate quark masses suffice. Furthermore, we find that the electro-weak penguin ({delta}I=3/2 and 1/2) contributions to {epsilon}{sup '}/{epsilon} in PQChPT can be determined to NLO using only degenerate (m{sub K}=m{sub {pi}}) K{yields}{pi} computations without momentum insertion. Issues pertaining to power divergent contributions, originating from mixing with lower dimensional operators, are addressed. Direct calculations of K{yields}{pi}{pi} at unphysical kinematics are plagued with enhanced finite volume effects in the (partially) quenched theory, but in simulations when the sea quark mass is equal to the up and down quark mass the enhanced finite volume effects vanish to NLO in PQChPT. In embedding the QCD penguin left-right operator onto PQChPT an ambiguity arises, as first emphasized by Golterman and Pallante. With one version [the 'PQS' (patially quenched singlet)] of the QCD penguin, the inputs needed from the lattice for constructing K{yields}{pi}{pi} at NLO in PQChPT coincide with those needed for the full theory. Explicit expressions for the finite logarithms emerging from our NLO analysis to the above amplitudes also are given.

  18. The covariant chiral ring

    NASA Astrophysics Data System (ADS)

    Bourget, Antoine; Troost, Jan

    2016-03-01

    We construct a covariant generating function for the spectrum of chiral primaries of symmetric orbifold conformal field theories with N = (4 , 4) supersymmetry in two dimensions. For seed target spaces K3 and T 4, the generating functions capture the SO(21) and SO(5) representation theoretic content of the chiral ring respectively. Via string dualities, we relate the transformation properties of the chiral ring under these isometries of the moduli space to the Lorentz covariance of perturbative string partition functions in flat space.

  19. Extraction of {gamma} from charmless hadronic B {yields} PP decays using SU(3) flavor symmetry

    SciTech Connect

    Suprun, Denis A.

    2006-07-11

    The decays of B mesons to a pair of charmless pseudoscalar mesons (PP decays) have been analyzed within the framework of flavor SU(3) symmetry and quark-diagrammatic topological approach. Flavor symmetry breaking is taken into account in tree (T) amplitudes through ratios of decay constants fK and f{pi}; exact SU(3) is assumed elsewhere. Acceptable fits to B {yields} PP branching ratios and CP asymmetries are obtained with tree, color-suppressed and QCD penguin amplitudes. Singlet penguin amplitude was introduced to describe decay amplitudes of the modes with {eta} and {eta}' mesons in the final state. Electroweak penguin amplitudes were expressed in terms of the corresponding tree-level diagrams. Values of the weak phase {gamma} were found to be consistent with the current indirect bounds from other analyses of CKM parameters.

  20. Complete leading order analysis in Chiral Perturbation Theory of the decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sub +}l{sub {minus}}{gamma}

    SciTech Connect

    J. L. Goity; Longzhe Zhang

    1997-02-01

    The decays K{sub L}{r_arrow}{gamma}{gamma} and K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} are studied at the leading order p{sup 6} in Chiral Perturbation Theory. One-loop contributions stemming from the odd intrinsic parity {vert_bar}{Delta}S{vert_bar}=1 effective Lagrangian of order p{sup 4} are included and shown to be of possible relevance. They affect the decay K{sub L}{r_arrow}{gamma}{gamma} adding to the usual pole terms a piece free of counterterm uncertainties. In the case of the K{sub L}{r_arrow}l{sup +}l{sup {minus}}{gamma} decays the dependence of the form factor on the dilepton invariant mass requires a counterterm. The form factor may receive a sizeable contribution from chiral logarithms. Including considerations from the K{sub L}{r_arrow}{pi}{sup +}{pi}{sup {minus}}{gamma} direct emission amplitude, the authors obtain two consistent scenarios. In one scenario the long distance contributions from the one-loop terms are important, while in the other they are marginal. In both cases the counterterm is shown to be significant.

  1. A lattice formulation of chiral gauge theories

    SciTech Connect

    Bodwin, G.T.

    1996-08-01

    We present a method for implementing gauge theories of chiral fermions on the lattice. Discussed topics include: the lattice as a UV regulator, a chiral QED model, modification of the fermion determinant, large gauge-field momenta, and a non-perturbative problem.

  2. Chiral superconductors.

    PubMed

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed. PMID:27088452

  3. Chiral squaring

    NASA Astrophysics Data System (ADS)

    Nagy, S.

    2016-07-01

    We construct the states and symmetries of N = 4 super-Yang-Mills by tensoring two N = 1 chiral multiplets and introducing two extra SUSY generators. This allows us to write the maximal N = 8 supergravity as four copies of the chiral multiplet. We extend this to higher dimensions and discuss applications to scattering amplitudes.

  4. Chiral superconductors

    NASA Astrophysics Data System (ADS)

    Kallin, Catherine; Berlinsky, John

    2016-05-01

    Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.

  5. Isotopic chirality

    SciTech Connect

    Floss, H.G.

    1994-12-01

    This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.

  6. Chiral nucleon-nucleon forces in nuclear structure calculations

    NASA Astrophysics Data System (ADS)

    Coraggio, L.; Gargano, A.; Holt, J. W.; Itaco, N.; Machleidt, R.; Marcucci, L. E.; Sammarruca, F.

    2016-05-01

    Realistic nuclear potentials, derived within chiral perturbation theory, are a major breakthrough in modern nuclear structure theory, since they provide a direct link between nuclear physics and its underlying theory, namely the QCD. As a matter of fact, chiral potentials are tailored on the low-energy regime of nuclear structure physics, and chiral perturbation theory provides on the same footing two-nucleon forces as well as many-body ones. This feature fits well with modern advances in ab-initio methods and realistic shell-model. Here, we will review recent nuclear structure calculations, based on realistic chiral potentials, for both finite nuclei and infinite nuclear matter.

  7. Punctuated Chirality

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life’s homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average.

  8. Punctuated chirality.

    PubMed

    Gleiser, Marcelo; Thorarinson, Joel; Walker, Sara Imari

    2008-12-01

    Most biomolecules occur in mirror, or chiral, images of each other. However, life is homochiral: proteins contain almost exclusively L-amino acids, while only D-sugars appear in RNA and DNA. The mechanism behind this fundamental asymmetry of life remains an open problem. Coupling the spatiotemporal evolution of a general autocatalytic polymerization reaction network to external environmental effects, we show through a detailed statistical analysis that high intensity and long duration events may drive achiral initial conditions towards chirality. We argue that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events, thus extending the theory of punctuated equilibrium to the prebiotic realm. Applying our arguments to other potentially life-bearing planetary platforms, we predict that a statistically representative sampling will be racemic on average. PMID:18841492

  9. Prebiotic chirality

    NASA Astrophysics Data System (ADS)

    Mekki-Berrada, Ali

    Bringing closer phospholipids each other on a bilayer of liposome, causes their rotation around their fatty acids axis, generating a force which brings closer the two sheets of the bilayer. In this theoretical study I show that for getting the greater cohesion of the liposome, by these forces, the serine in the hydrophilic head must have a L chirality. In the case where the hydrophilic head is absent amino acids with L chirality could contribute to this cohesion by taking the place of L-serine. Some coenzymes having a configuration similar to ethanolamine may also contribute. This is the case of pyridoxamine, thiamine and tetrahydrofolic acid. The grouping of amino acids of L chirality and pyridoxamine on the wall could initialize the prebiotic metabolism of these L amino acids only. This would explain the origin of the homo-chirality of amino acids in living world. Furthermore I show that in the hydrophilic head, the esterification of glycerol-phosphate by two fatty acids go through the positioning of dihydroxyacetone-phosphate and L-glyceraldehyde-3-phosphate, but not of D-glyceraldehyde-3-phosphate, prior their hydrogenation to glycerol-3- phosphate. The accumulation of D-glyceraldehyde-3-phosphate in the cytoplasm displace the thermodynamic equilibria towards the synthesis of D-dATP from D-glyceraldehyde-3-phosphate, acetaldehyde and prebiotic adenine, a reaction which does not require a coenzyme in the biotic metabolism. D-dATP and thiamine, more prebiotic metabolism of L-amino acids on the wall, would initialize D-pentoses phosphate and D-nucleotides pathways from the reaction of D-glyceraldehyde-3-phosphate + dihydroxyacetone-phosphate + prebiotic nucleic bases. The exhaustion of the prebiotic glyceraldehyde (racemic) and the nascent biotic metabolism dominated by D-glyceraldehyde-3-phosphate, would explain the origin of homo-chirality of sugars in living world. References: http://en.wikiversity.org/wiki/Prebiotic_chirality

  10. Quenched QED in the chiral limit. [QED (quantum electrodynamics)

    SciTech Connect

    Vandermark, S.W.

    1993-01-01

    The main goal in this project has been to understand, through analytical methods, whether there could be a continuum limit for QED. This possibility is motivated by recent lattice simulations on quenched QED which apparently exhibit a chiral phase transition at strong coupling in the chiral limit. Another goal is to develop a novel perturbation expansion which may also be usefully applied to other theories. The author begins with the general expression for the chiral order parameter, ([bar [psi

  11. An investigation of meson spectroscopy on isotropic clover lattices at the SU(3) flavor-symmetric point

    SciTech Connect

    Richards, David G.; Orginos, Konstantinos

    2014-06-23

    We present an investigation of the excited meson spectrum at the N_f= 3 point obtained on isotropic clover lattices with a plaquette Wilson gauge action, and a NP-improved clover fermion action, at a lattice spacing of a \\simeq 0.08 fm, and compare with corresponding calculations on an anisotropic lattice at fine temporal lattice spacing but a spatial lattice spacing of a_s \\simeq 0.125 fm. The methodology adopted follows that employed in the calculation of the spectrum on anisotropic lattices, and we test the efficacy of that approach for isotropic lattices. In particular, we explore the extent to which rotational symmetry for predominantly single-hadron states is realized. By comparison of the energy levels with that obtained using the anisotropic lattice, we obtain an indication of discretization uncertainties in the single-hadron spectrum.

  12. Light Nuclei and HyperNuclei from Quantum Chromodynamics in the Limit of SU(3) Flavor Symmetry

    SciTech Connect

    Beane, S R; Cohen, S D; Detmold, W; Lin, H W; Luu, T C; Orginos, K; Parreno, A; Savage, M J; Walker-Loud, A

    2013-02-01

    The binding energies of a range of nuclei and hypernuclei with atomic number A <= 4 and strangeness |s| <= 2, including the deuteron, di-neutron, H-dibaryon, {sup 3}He, {sub {Lambda}}{sup 3}He, {sub {Lambda}}{sup 4}He, and {sub {Lambda}{Lambda}}{sup 4}He, are calculated in the limit of flavor-SU(3) symmetry at the physical strange quark mass with quantum chromodynamics (without electromagnetic interactions). The nuclear states are extracted from Lattice QCD calculations performed with n{sub f}=3 dynamical light quarks using an isotropic clover discretization of the quark-action in three lattice volumes of spatial extent L ~ 3.4 fm, 4.5 fm and 6.7 fm, and with a single lattice spacing b ~ 0.145 fm.

  13. Renormalization of NN Interaction with Relativistic Chiral Two Pion Exchange

    SciTech Connect

    Higa, R; Valderrama, M Pavon; Arriola, E Ruiz

    2007-06-14

    The renormalization of the NN interaction with the Chiral Two Pion Exchange Potential computed using relativistic baryon chiral perturbation theory is considered. The short distance singularity reduces the number of counter-terms to about a half as those in the heavy-baryon expansion. Phase shifts and deuteron properties are evaluated and a general overall agreement is observed.

  14. Chiral streamers

    SciTech Connect

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya

    2015-10-15

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  15. Chiral streamers

    NASA Astrophysics Data System (ADS)

    Zou, Dandan; Cao, Xin; Lu, Xinpei; Ostrikov, Kostya Ken

    2015-10-01

    The interaction of time-varying electromagnetic fields and solid, liquid, and gaseous matter may lead to electrical breakdown phenomena through the excitation of ionization waves or streamers that control the dynamics of localized plasma propagation through the media. The streamers usually propagate along straight lines, either between random points in space or along a certain direction in a guided mode. Here, we report on a new type of plasma discharges with the regular helical propagation pattern driven by a pulsed dc voltage in nitrogen at sub-atmospheric-pressure conditions. The helical guided streamers, named chiral streamers or chi-streamers, are excited without any external magnetic fields, which commonly cause helical plasma motions. We also demonstrate a hybrid propagation mode involving the interchangeable chiral streamers and the straight-line propagating plasmas. High-speed, time-resolved optical imaging reveals that the chiral streamers and the hybrid patterns are made of spatially localized discrete plasma bullets, similar to the straight-line guided streamers. These results may enable effective control of propagation of confined plasmas and electromagnetic energy along pre-determined, potentially deterministic paths, which have important implications for the development of next-generation plasma-based radiation sources, communication devices, and medical treatments.

  16. Chiral Dynamics 2006

    NASA Astrophysics Data System (ADS)

    Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry

    2007-10-01

    pt. A. Plenary session. Opening remarks: experimental tests of chiral symmetry breaking / A. M. Bernstein. [Double pie symbols] scattering / H. Leutwyler. Chiral effective field theory in a [Triangle]-resonance region / V. Pascalutsa. Some recent developments in chiral perturbation theory / Ulf-G. Mei ner. Chiral extrapolation and nucleon structure from the lattice / R.D. Young. Recent results from HAPPEX / R. Michaels. Chiral symmetries and low energy searches for new physics / M.J. Ramsey-Musolf. Kaon physics: recent experimental progress / M. Moulson. Status of the Cabibbo angle / V. Cirigliano. Lattice QCD and nucleon spin structure / J.W. Negele. Spin sum rules and polarizabilities: results from Jefferson lab / J-P Chen. Compton scattering and nucleon polarisabilities / Judith A. McGovern. Virtual compton scattering at MIT-bates / R. Miskimen. Physics results from the BLAST detector at the BATES accelerator / R.P. Redwine. The [Pie sympbol]NN system, recent progress / C. Hanhart. Application of chiral nuclear forces to light nuclei / A. Nogga. New results on few-body experiments at low energy / Y. Nagai. Few-body lattice calculations / M.J. Savage. Research opportunities at the upgraded HI?S facility / H.R. Weller -- pt. B. Goldstone boson dynamics. Working group summary: Goldstone Boson dynamics / G. Colangelo and S. Giovannella. Recent results on radiative Kaon decays from NA48 and NA48/2 / S.G. López. Cusps in K-->3 [Pie symbol] decays / B. Kubis. Recent KTeV results on radiative Kaon decays / M.C. Ronquest. The [Double pie symbols] scattering amplitude / J.R. Peláez. Determination of the Regge parameters in the [Double pie symbols] scattering amplitude / I. Caprini. e+e- Hadronic cross section measurement at DA[symbol]NE with the KLOE detector / P. Beltrame. Measurement of the form factors of e+e- -->2([Pie symbol]+[Pie symbol]-), pp and the resonant parameters of the heavy charmonia at BES / H. Hu. Measurement of e+e- multihadronic cross section below 4

  17. Nuclear electromagnetic charge and current operators in Chiral EFT

    SciTech Connect

    Girlanda, Luca; Marcucci, Laura Elisa; Pastore, Saori; Piarulli, Maria; Schiavilla, Rocco; Viviani, Michele

    2013-08-01

    We describe our method for deriving the nuclear electromagnetic charge and current operators in chiral perturbation theory, based on time-ordered perturbation theory. We then discuss possible strategies for fixing the relevant low-energy constants, from the magnetic moments of the deuteron and of the trinucleons, and from the radiative np capture cross sections, and identify a scheme which, partly relying on {Delta} resonance saturation, leads to a reasonable pattern of convergence of the chiral expansion.

  18. Spontaneous Planar Chiral Symmetry Breaking in Cells

    NASA Astrophysics Data System (ADS)

    Hadidjojo, Jeremy; Lubensky, David

    Recent progress in animal development has highlighted the central role played by planar cell polarity (PCP) in epithelial tissue morphogenesis. Through PCP, cells have the ability to collectively polarize in the plane of the epithelium by localizing morphogenetic proteins along a certain axis. This allows direction-dependent modulation of tissue mechanical properties that can translate into the formation of complex, non-rotationally invariant shapes. Recent experimental observations[1] show that cells, in addition to being planar-polarized, can also spontaneously develop planar chirality, perhaps in the effort of making yet more complex shapes that are reflection non-invariant. In this talk we will present our work in characterizing general mechanisms that can lead to spontaneous chiral symmetry breaking in cells. We decompose interfacial concentration of polarity proteins in a hexagonal cell packing into irreducible representations. We find that in the case of polar concentration distributions, a chiral state can only be reached from a secondary instability after the cells are polarized. However in the case of nematic distributions, we show that a finite-amplitude (subcritical, or ``first-order'') nematic transition can send the system from disorder directly to a chiral state. In addition, we find that perturbing the system by stretching the hexagonal packing enables direct (supercritical, or ``second-order'') chiral transition in the nematic case. Finally, we do a Landau expansion to study competition between stretch-induced chirality and the tendency towards a non-chiral state in packings that have retained the full 6-fold symmetry.

  19. Chiral mirrors

    SciTech Connect

    Plum, Eric; Zheludev, Nikolay I.

    2015-06-01

    Mirrors are used in telescopes, microscopes, photo cameras, lasers, satellite dishes, and everywhere else, where redirection of electromagnetic radiation is required making them arguably the most important optical component. While conventional isotropic mirrors will reflect linear polarizations without change, the handedness of circularly polarized waves is reversed upon reflection. Here, we demonstrate a type of mirror reflecting one circular polarization without changing its handedness, while absorbing the other. The polarization-preserving mirror consists of a planar metasurface with a subwavelength pattern that cannot be superimposed with its mirror image without being lifted out of its plane, and a conventional mirror spaced by a fraction of the wavelength from the metasurface. Such mirrors enable circularly polarized lasers and Fabry-Pérot cavities with enhanced tunability, gyroscopic applications, polarization-sensitive detectors of electromagnetic waves, and can be used to enhance spectroscopies of chiral media.

  20. Nuclear chiral dynamics and thermodynamics

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Kaiser, Norbert; Weise, Wolfram

    2013-11-01

    This presentation reviews an approach to nuclear many-body systems based on the spontaneously broken chiral symmetry of low-energy QCD. In the low-energy limit, for energies and momenta small compared to a characteristic symmetry breaking scale of order 1 GeV, QCD is realized as an effective field theory of Goldstone bosons (pions) coupled to heavy fermionic sources (nucleons). Nuclear forces at long and intermediate distance scales result from a systematic hierarchy of one- and two-pion exchange processes in combination with Pauli blocking effects in the nuclear medium. Short distance dynamics, not resolved at the wavelengths corresponding to typical nuclear Fermi momenta, are introduced as contact interactions between nucleons. Apart from a set of low-energy constants associated with these contact terms, the parameters of this theory are entirely determined by pion properties and low-energy pion-nucleon scattering observables. This framework (in-medium chiral perturbation theory) can provide a realistic description of both isospin-symmetric nuclear matter and neutron matter, with emphasis on the isospin-dependence determined by the underlying chiral NN interaction. The importance of three-body forces is emphasized, and the role of explicit Δ(1232)-isobar degrees of freedom is investigated in detail. Nuclear chiral thermodynamics is developed and a calculation of the nuclear phase diagram is performed. This includes a successful description of the first-order phase transition from a nuclear Fermi liquid to an interacting Fermi gas and the coexistence of these phases below a critical temperature Tc. Density functional methods for finite nuclei based on this approach are also discussed. Effective interactions, their density dependence and connections to Landau Fermi liquid theory are outlined. Finally, the density and temperature dependences of the chiral (quark) condensate are investigated.

  1. Long-range interactions between chiral molecules

    SciTech Connect

    Salam, A.

    2015-01-22

    Results of molecular quantum electrodynamics calculations of discriminatory interactions between two chiral molecules undergoing resonance energy transfer, van der Waals dispersion, and optical binding are presented. A characteristic feature of the theory is that the radiation field is quantized with signals consequently propagating between centres at the speed of light. In order to correctly describe optically active chromophores, it is necessary to include magnetic as well as electric dipole coupling terms in the time-dependent perturbation theory computations. Recent work investigating the effect of an absorptive and dispersive chiral medium on the rate of migration of energy will also be discussed.

  2. Chiral logarithms in the massless limit tamed.

    PubMed

    Kivel, Nikolai; Polyakov, Maxim V; Vladimirov, Alexei

    2008-12-31

    We derive nonlinear recursion relations for the leading chiral logarithms (LLs) in massless theories. These relations not only provide a very efficient method of computation of LLs (e.g., the 33-loop contribution is calculated in a dozen of seconds on a PC) but also equip us with a powerful tool for the summation of the LLs. Our method is not limited to chiral perturbation theory only; it is pertinent to any nonrenormalizable effective field theory such as, for instance, the theory of critical phenomena, low-energy quantum gravity, etc. PMID:19437635

  3. Chirality of Viral Capsids

    NASA Astrophysics Data System (ADS)

    Dharmavaram, Sanjay; Xie, Fangming; Bruinsma, Robijn; Klug, William; Rudnick, Joseph

    Most icosahedral viruses are classified by their T-number which identifies their capsid in terms of the number of capsomers and their relative arrangement. Certain T-numbers (T = 7 for instance) are inherently chiral (with no reflection planes) while others (e.g. T = 1) are achiral. We present a Landau-Brazovskii (LB) theory for weak crystallization in which a scalar order parameter that measures density of capsid proteins successfully predicts the various observed T-numbers and their respective chiralities. We find that chiral capsids gain stability by spontaneously breaking symmetry from an unstable chiral state. The inherently achiral LB-free energy does not preferentially select a particular chiral state from its mirror reflection. Based on the physical observation that proteins are inherently chiral molecules with directional interactions, we propose a new chiral term to the LB energy as a possible selection mechanism for chirality.

  4. Chiral logarithms in quenched QCD

    SciTech Connect

    Y. Chen; S. J. Dong; T. Draper; I. Horvath; F. X. Lee; K. F. Liu; N. Mathur; and J. B. Zhang

    2004-08-01

    The quenched chiral logarithms are examined on a 163x28 lattice with Iwasaki gauge action and overlap fermions. The pion decay constant fpi is used to set the lattice spacing, a = 0.200(3) fm. With pion mass as low as {approx}180 MeV, we see the quenched chiral logarithms clearly in mpi2/m and fP, the pseudoscalar decay constant. The authors analyze the data to determine how low the pion mass needs to be in order for the quenched one-loop chiral perturbation theory (chiPT) to apply. With the constrained curve-fitting method, they are able to extract the quenched chiral logarithmic parameter delta together with other low-energy parameters. Only for mpi<=300 MeV do we obtain a consistent and stable fit with a constant delta which they determine to be 0.24(3)(4) (at the chiral scale Lambdachi = 0.8 GeV). By comparing to the 123x28 lattice, they estimate the finite volume effect to be about 2.7% for the smallest pion mass. They also fitted the pion mass to the form for the re-summed cactus diagrams and found that its applicable region is extended farther than the range for the one-loop formula, perhaps up to mpi {approx}500-600 MeV. The scale independent delta is determined to be 0.20(3) in this case. The authors study the quenched non-analytic terms in the nucleon mass and find that the coefficient C1/2 in the nucleon mass is consistent with the prediction of one-loop chiPT. They also obtain the low energy constant L5 from fpi. They conclude from this study that it is imperative to cover only the range of data with the pion mass less than {approx}300 MeV in order to examine the chiral behavior of the hadron masses and decay constants in quenched QCD and match them with quenched one-loop chiPT.

  5. Pion Photo- and Electroproduction and the Chiral MAID Interface

    NASA Astrophysics Data System (ADS)

    Hilt, Marius; Lehnhart, Björn C.; Scherer, Stefan; Tiator, Lothar

    We discuss the extended on-mass-shell scheme for manifestly Lorentz-invariant baryon chiral perturbation theory. We present a calculation of pion photo- and electroproduction up to and including order q4. The low-energy constants have been fixed by fitting experimental data in all available reaction channels. Our results can be accessed via a web interface, the so-called chiral MAID (http://www.kph.uni-mainz.de/MAID/chiralmaid/).

  6. Chirality in nonlinear optics.

    PubMed

    Haupert, Levi M; Simpson, Garth J

    2009-01-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made approximately 50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity. PMID:19046125

  7. Chirality in Nonlinear Optics

    NASA Astrophysics Data System (ADS)

    Haupert, Levi M.; Simpson, Garth J.

    2009-05-01

    The past decade has witnessed the emergence of new measurement approaches and applications for chiral thin films and materials enabled by the observations of the high sensitivity of second-order nonlinear optical measurements to chirality. In thin films, the chiral response to second harmonic generation and sum frequency generation (SFG) from a single molecular monolayer is often comparable with the achiral response. The chiral specificity also allows for symmetry-allowed SFG in isotropic chiral media, confirming predictions made ˜50 years ago. With these experimental demonstrations in hand, an important challenge is the construction of intuitive predictive models that allow the measured chiral response to be meaningfully related back to molecular and macromolecular structure. This review defines and considers three distinct mechanisms for chiral effects in uniaxially oriented assemblies: orientational chirality, intrinsic chirality, and isotropic chirality. The role of each is discussed in experimental and computational studies of bacteriorhodopsin films, binaphthol, and collagen. Collectively, these three model systems support a remarkably simple framework for quantitatively recovering the measured chiral-specific activity.

  8. Chiral symmetry and chiral-symmetry breaking

    SciTech Connect

    Peskin, M.E.

    1982-12-01

    These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed. (WHK)

  9. Chiral corrections to the anomalous 2. gamma. decays of. pi. sup 0 ,. eta. and. eta. prime

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  10. PERTURBING LIGNIFICATION

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Perturbing lignification is possible in multiple and diverse ways. Without obvious growth/development phenotypes, transgenic angiosperms can have lignin levels reduced to half the normal level, can have compositions ranging from very high-guaiacyl/low-syringyl to almost totally syringyl, and can eve...

  11. Planar plasmonic chiral nanostructures.

    PubMed

    Zu, Shuai; Bao, Yanjun; Fang, Zheyu

    2016-02-21

    A strong chiral optical response induced at a plasmonic Fano resonance in a planar Au heptamer nanostructure was experimentally and theoretically demonstrated. The scattering spectra show the characteristic narrow-band feature of Fano resonances for both left and right circular polarized lights, with a chiral response reaching 30% at the Fano resonance. Specifically, we systematically investigate the chiral response of planar heptamers with gradually changing the inter-particle rotation angles and separation distance. The chiral spectral characteristics clearly depend on the strength of Fano resonances and the associated near-field optical distributions. Finite element method simulations together with a multipole expansion method demonstrate that the enhanced chirality is caused by the excitation of magnetic quadrupolar and electric toroidal dipolar modes. Our work provides an effective method for the design of 2D nanostructures with a strong chiral response. PMID:26818746

  12. Axially chiral BODIPYs.

    PubMed

    Lerrick, Reinner I; Winstanley, Thomas P L; Haggerty, Karen; Wills, Corinne; Clegg, William; Harrington, Ross W; Bultinck, Patrick; Herrebout, Wouter; Benniston, Andrew C; Hall, Michael J

    2014-05-11

    The synthesis and resolution of a class of chiral organic fluorophores, axially chiral 4,4-difluoro-4-bora-3a,4a-diaza-s-indacenes (Ax*-BODIPY), is described. Ax*-BODIPYs were prepared through a modular synthesis combined with a late stage Heck functionalisation. Resolution was achieved by preparative chiral HPLC. Absolute stereochemical assignment was performed by comparison of experimental ECD spectra with TD-DFT calculations. PMID:24676233

  13. Chiral atomically thin films

    NASA Astrophysics Data System (ADS)

    Kim, Cheol-Joo; Sánchez-Castillo, A.; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm–1) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra.

  14. Chiral atomically thin films.

    PubMed

    Kim, Cheol-Joo; Sánchez-Castillo, A; Ziegler, Zack; Ogawa, Yui; Noguez, Cecilia; Park, Jiwoong

    2016-06-01

    Chiral materials possess left- and right-handed counterparts linked by mirror symmetry. These materials are useful for advanced applications in polarization optics, stereochemistry and spintronics. In particular, the realization of spatially uniform chiral films with atomic-scale control of their handedness could provide a powerful means for developing nanodevices with novel chiral properties. However, previous approaches based on natural or grown films, or arrays of fabricated building blocks, could not offer a direct means to program intrinsic chiral properties of the film on the atomic scale. Here, we report a chiral stacking approach, where two-dimensional materials are positioned layer-by-layer with precise control of the interlayer rotation (θ) and polarity, resulting in tunable chiral properties of the final stack. Using this method, we produce left- and right-handed bilayer graphene, that is, a two-atom-thick chiral film. The film displays one of the highest intrinsic ellipticity values (6.5 deg μm(-1)) ever reported, and a remarkably strong circular dichroism (CD) with the peak energy and sign tuned by θ and polarity. We show that these chiral properties originate from the large in-plane magnetic moment associated with the interlayer optical transition. Furthermore, we show that we can program the chiral properties of atomically thin films layer-by-layer by producing three-layer graphene films with structurally controlled CD spectra. PMID:26900756

  15. Cosmological Perturbations

    NASA Astrophysics Data System (ADS)

    Lesgourges, J.

    2013-08-01

    We present a self-contained summary of the theory of linear cosmological perturbations. We emphasize the effect of the six parameters of the minimal cosmological model, first, on the spectrum of Cosmic Microwave Background temperature anisotropies, and second, on the linear matter power spectrum. We briefly review at the end the possible impact of a few non-minimal dark matter and dark energy models.

  16. Chiral geometry in multiple chiral doublet bands

    NASA Astrophysics Data System (ADS)

    Zhang, Hao; Chen, Qibo

    2016-02-01

    The chiral geometry of multiple chiral doublet bands with identical configuration is discussed for different triaxial deformation parameters γ in the particle rotor model with . The energy spectra, electromagnetic transition probabilities B(M1) and B(E2), angular momenta, and K-distributions are studied. It is demonstrated that the chirality still remains not only in the yrast and yrare bands, but also in the two higher excited bands when γ deviates from 30°. The chiral geometry relies significantly on γ, and the chiral geometry of the two higher excited partner bands is not as good as that of the yrast and yrare doublet bands. Supported by Plan Project of Beijing College Students’ Scientific Research and Entrepreneurial Action, Major State 973 Program of China (2013CB834400), National Natural Science Foundation of China (11175002, 11335002, 11375015, 11461141002), National Fund for Fostering Talents of Basic Science (NFFTBS) (J1103206), Research Fund for Doctoral Program of Higher Education (20110001110087) and China Postdoctoral Science Foundation (2015M580007)

  17. Chiral Drugs: An Overview

    PubMed Central

    Nguyen, Lien Ai; He, Hua; Pham-Huy, Chuong

    2006-01-01

    About more than half of the drugs currently in use are chiral compounds and near 90% of the last ones are marketed as racemates consisting of an equimolar mixture of two enantiomers. Although they have the same chemical structure, most isomers of chiral drugs exhibit marked differences in biological activities such as pharmacology, toxicology, pharmacokinetics, metabolism etc. Some mechanisms of these properties are also explained. Therefore, it is important to promote the chiral separation and analysis of racemic drugs in pharmaceutical industry as well as in clinic in order to eliminate the unwanted isomer from the preparation and to find an optimal treatment and a right therapeutic control for the patient. In this article, we review the nomenclature, pharmacology, toxicology, pharmacokinetics, metabolism etc of some usual chiral drugs as well as their mechanisms. Different techniques used for the chiral separation in pharmaceutical industry as well as in clinical analyses are also examined. PMID:23674971

  18. Chiral corrections to the hyperon vector form factors

    NASA Astrophysics Data System (ADS)

    Villadoro, Giovanni

    2006-07-01

    We present a complete calculation of the SU(3)-breaking corrections to the hyperon vector form factors up to O(p4) in heavy baryon chiral perturbation theory. Because of the Ademollo-Gatto theorem, at this order the results do not depend on unknown low energy constants and allow to test the convergence of the chiral expansion. We complete and correct previous calculations and find that O(p3) and O(1/M0) corrections are important. We also study the inclusion of the decuplet degrees of freedom, showing that in this case the perturbative expansion is jeopardized. These results raise doubts on the reliability of the chiral expansion for hyperons.

  19. Chiral Extrapolation of Lattice Data for Heavy Meson Hyperfine Splittings

    SciTech Connect

    X.-H. Guo; P.C. Tandy; A.W. Thomas

    2006-03-01

    We investigate the chiral extrapolation of the lattice data for the light-heavy meson hyperfine splittings D*-D and B*-B to the physical region for the light quark mass. The chiral loop corrections providing non-analytic behavior in m{sub {pi}} are consistent with chiral perturbation theory for heavy mesons. Since chiral loop corrections tend to decrease the already too low splittings obtained from linear extrapolation, we investigate two models to guide the form of the analytic background behavior: the constituent quark potential model, and the covariant model of QCD based on the ladder-rainbow truncation of the Dyson-Schwinger equations. The extrapolated hyperfine splittings remain clearly below the experimental values even allowing for the model dependence in the description of the analytic background.

  20. Generalized Polarizabilities and the Chiral Structure of the Nucleon

    SciTech Connect

    Hemmert, T.R.; Knoechlein, G.; Holstein, B.R.; Knoechlein, G.; Scherer, S.

    1997-07-01

    We present results of the first chiral perturbation theory calculation for the generalized polarizabilities of the nucleon and discuss the response functions in virtual Compton scattering to be measured in the scheduled electron scattering experiments. {copyright} {ital 1997} {ital The American Physical Society}

  1. Pion scattering poles and chiral symmetry restoration

    SciTech Connect

    Fernandez-Fraile, D.; Nicola, A. Gomez; Herruzo, E. T.

    2007-10-15

    Using unitarized chiral perturbation theory methods, we perform a detailed analysis of the {pi}{pi} scattering poles f{sub 0}(600) and {rho}(770) behavior when medium effects such as temperature or density drive the system towards chiral symmetry restoration. In the analysis of real poles below threshold, we show that it is crucial to extend properly the unitarized amplitudes so that they match the perturbative Adler zeros. Our results do not show threshold enhancement effects at finite temperature in the f{sub 0}(600) channel, which remains as a pole of broad nature. We also implement T=0 finite-density effects related to chiral symmetry restoration, by varying the pole position with the pion decay constant. Although this approach takes into account only a limited class of contributions, we reproduce the expected finite-density restoration behavior, which drives the poles towards the real axis, producing threshold enhancement and {pi}{pi} bound states. We compare our results with several model approaches and discuss the experimental consequences, both in relativistic heavy ion collisions and in {pi}{yields}{pi}{pi} and {gamma}{yields}{pi}{pi} reactions in nuclei.

  2. Kagome antiferromagnet: a chiral topological spin liquid?

    PubMed

    Messio, Laura; Bernu, Bernard; Lhuillier, Claire

    2012-05-18

    Inspired by the recent discovery of a new instability towards a chiral phase of the classical Heisenberg model on the kagome lattice, we propose a specific chiral spin liquid that reconciles different, well-established results concerning both the classical and quantum models. This proposal is analyzed in an extended mean-field Schwinger boson framework encompassing time reversal symmetry breaking phases, which allows both a classical and a quantum phase description. At low temperatures, we find that quantum fluctuations favor this chiral phase, which is stable against small perturbations of second- and third-neighbor interactions. For spin-1/2, this phase may be, beyond the mean field, a chiral gapped spin liquid. Such a phase is consistent with the density matrix renormalization group results of Yan et al. [Science 332, 1173 (2011)]. Mysterious features of the low-lying excitations of exact diagonalization spectra also find an explanation in this framework. Moreover, thermal fluctuations compete with quantum ones and induce a transition from this flux phase to a planar zero flux phase at a nonzero value of the renormalized temperature (T/S2), reconciling these results with those obtained for the classical system. PMID:23003183

  3. Applications of chiral symmetry

    SciTech Connect

    Pisarski, R.D.

    1995-03-01

    The author discusses several topics in the applications of chiral symmetry at nonzero temperature. First, where does the rho go? The answer: up. The restoration of chiral symmetry at a temperature T{sub {chi}} implies that the {rho} and a{sub 1} vector mesons are degenerate in mass. In a gauged linear sigma model the {rho} mass increases with temperature, m{sub {rho}}(T{sub {chi}}) > m{sub {rho}}(0). The author conjectures that at T{sub {chi}} the thermal {rho} - a{sub 1}, peak is relatively high, at about {approximately}1 GeV, with a width approximately that at zero temperature (up to standard kinematic factors). The {omega} meson also increases in mass, nearly degenerate with the {rho}, but its width grows dramatically with temperature, increasing to at least {approximately}100 MeV by T{sub {chi}}. The author also stresses how utterly remarkable the principle of vector meson dominance is, when viewed from the modern perspective of the renormalization group. Secondly, he discusses the possible appearance of disoriented chiral condensates from {open_quotes}quenched{close_quotes} heavy ion collisions. It appears difficult to obtain large domains of disoriented chiral condensates in the standard two flavor model. This leads to the last topic, which is the phase diagram for QCD with three flavors, and its proximity to the chiral critical point. QCD may be very near this chiral critical point, and one might thereby generated large domains of disoriented chiral condensates.

  4. Chirality control in oligothiophene through chiral wrapping.

    PubMed

    Sanji, Takanobu; Kato, Nobu; Tanaka, Masato

    2006-01-19

    [structure: see text] Mixing oligothiophenes and polysaccharides, such as amylose and schizophyllan, affords novel inclusion complexes, in which oligothiophene guests adopt twisted conformation in the chiral channel created by left- or right-handed helical wrapping with the polysaccharide host polymers, leading to optical activity. PMID:16408883

  5. Synthesis of Chiral Cyclopentenones.

    PubMed

    Simeonov, Svilen P; Nunes, João P M; Guerra, Krassimira; Kurteva, Vanya B; Afonso, Carlos A M

    2016-05-25

    The cyclopentenone unit is a very powerful synthon for the synthesis of a variety of bioactive target molecules. This is due to the broad diversity of chemical modifications available for the enone structural motif. In particular, chiral cyclopentenones are important precursors in the asymmetric synthesis of target chiral molecules. This Review provides an overview of reported methods for enantioselective and asymmetric syntheses of cyclopentenones, including chemical and enzymatic resolution, asymmetric synthesis via Pauson-Khand reaction, Nazarov cyclization and organocatalyzed reactions, asymmetric functionalization of the existing cyclopentenone unit, and functionalization of chiral building blocks. PMID:27101336

  6. Chiral extrapolations in 2+1 flavor domain wall fermion simulations

    NASA Astrophysics Data System (ADS)

    Lin, Meifeng

    2006-12-01

    Simulations with 2+1 flavors of domain wall fermions provide us with the opportunity to compare the lattice data directly to the predictions of continuum chiral perturbation theory, up to correc- tions from the residual chiral symmetry breaking, mres , and O(a) lattice artefacts, which are rela- tively small for domain wall fermions. We present preliminary results for the pseudoscalar meson masses and decay constants from partially quenched simulations and examine the next-to-leading order chiral extrapolations at small quark masses. The simulations were carried out on two lattice volumes : 163 × 32 and 243 × 64, with the lattice spacing fixed at about 0.1 fm. The subtleties of the chiral fits are discussed. We also explore the roles of mres and O(a) terms in the NLO chiral expansions and their effects on the chiral extrapolations for the pseudoscalar masses and decay constants.

  7. Criteria of backscattering in chiral one-way photonic crystals

    NASA Astrophysics Data System (ADS)

    Cheng, Pi-Ju; Chang, Shu-Wei

    2016-03-01

    Optical isolators are important devices in photonic circuits. To reduce the unwanted reflection in a robust manner, several setups have been realized using nonreciprocal schemes. In this study, we show that the propagating modes in a strongly-guided chiral photonic crystal (no breaking of the reciprocity) are not backscattering-immune even though they are indeed insensitive to many types of scatters. Without the protection from the nonreciprocity, the backscattering occurs under certain circumstances. We present a perturbative method to calculate the backscattering of chiral photonic crystals in the presence of chiral/achiral scatters. The model is, essentially, a simplified analogy to the first-order Born approximation. Under reasonable assumptions based on the behaviors of chiral photonic modes, we obtained the expression of reflection coefficients which provides criteria for the prominent backscattering in such chiral structures. Numerical examinations using the finite-element method were also performed and the results agree well with the theoretical prediction. From both our theory and numerical calculations, we find that the amount of backscattering critically depends on the symmetry of scatter cross sections. Strong reflection takes place when the azimuthal Fourier components of scatter cross sections have an order l of 2. Chiral scatters without these Fourier components would not efficiently reflect the chiral photonic modes. In addition, for these chiral propagating modes, disturbances at the most significant parts of field profiles do not necessarily result in the most effective backscattering. The observation also reveals what types of scatters or defects should be avoided in one-way applications of chiral structures in order to minimize the backscattering.

  8. Nonlinear chiral transport phenomena

    NASA Astrophysics Data System (ADS)

    Chen, Jiunn-Wei; Ishii, Takeaki; Pu, Shi; Yamamoto, Naoki

    2016-06-01

    We study the nonlinear responses of relativistic chiral matter to the external fields such as the electric field E , gradients of temperature and chemical potential, ∇T and ∇μ . Using the kinetic theory with Berry curvature corrections under the relaxation time approximation, we compute the transport coefficients of possible new electric currents that are forbidden in usual chirally symmetric matter but are allowed in chirally asymmetric matter by parity. In particular, we find a new type of electric current proportional to ∇μ ×E due to the interplay between the effects of the Berry curvature and collisions. We also derive an analog of the "Wiedemann-Franz" law specific for anomalous nonlinear transport in relativistic chiral matter.

  9. Spintronics: Chiral damping

    PubMed Central

    Kim, Kyoung-Whan; Lee, Hyun-Woo

    2016-01-01

    The analysis of the magnetic domain wall motion in a nanostructured magnetic system with strong spin-orbit coupling shows that the energy dissipation can be chiral when the inversion symmetry is broken. PMID:26906956

  10. Kaon Thresholds and Two-Flavor Chiral Expansions for Hyperons

    SciTech Connect

    Fu-Jiun Jiang, Brian C. Tiburzi, Andre Walker-Loud

    2011-01-01

    Two-flavor chiral expansions provide a useful perturbative framework to study hadron properties. Such expansions should exhibit marked improvement over the conventional three-flavor chiral expansion. Although one can theoretically formulate two-flavor theories for the various hyperon multiplets, the nearness of kaon thresholds can seriously undermine the effectiveness of the perturbative expansion in practice. We investigate the importance of virtual kaon thresholds on hyperon properties, specifically their masses and isovector axial charges. Using a three-flavor expansion that includes SU(3) breaking effects, we uncover the underlying expansion parameter governing the description of virtual kaon thresholds. For spin-half hyperons, this expansion parameter is quite small. Consequently virtual kaon contributions are well described in the two-flavor theory by terms analytic in the pion mass-squared. For spin three-half hyperons, however, one is closer to the kaon production threshold, and the expansion parameter is not as small. Breakdown of SU(2) chiral perturbation theory is shown to arise from a pole in the expansion parameter associated with the kaon threshold. Estimating higher-order corrections to the expansion parameter is necessary to ascertain whether the two-flavor theory of spin three-half hyperons remains perturbative. We find that, despite higher-order corrections, there is a useful perturbative expansion for the masses and isovector axial charges of both spin-half and spin three-half hyperons.

  11. Chiral plasma instabilities.

    PubMed

    Akamatsu, Yukinao; Yamamoto, Naoki

    2013-08-01

    We study the collective modes in relativistic electromagnetic or quark-gluon plasmas with an asymmetry between left- and right-handed chiral fermions, based on the recently formulated kinetic theory with Berry curvature corrections. We find that there exists an unstable mode, signaling the presence of a plasma instability. We argue the fate of this "chiral plasma instability" including the effect of collisions, and briefly discuss its relevance in heavy ion collisions and compact stars. PMID:23952387

  12. Chiral corrections to the anomalous 2{gamma} decays of {pi}{sup 0}, {eta} and {eta}{prime}

    SciTech Connect

    Issler, D.

    1990-11-01

    To any order in chiral perturbation theory, the anomalous Wess-Zumino term is shown to generate only chirally invariant counterterms. Explicit examples of 0(p{sub 6}) terms generated by one-loop graphs are given, some of which are relevant to the two-photon decays of {pi}{sup o}, {eta} and {eta}{prime}.

  13. Perturbative fragmentation

    SciTech Connect

    Kopeliovich, B. Z.; Pirner, H.-J.; Potashnikova, I. K.; Schmidt, Ivan; Tarasov, A. V.

    2008-03-01

    The Berger model of perturbative fragmentation of quarks to pions is improved by providing an absolute normalization and keeping all terms in a (1-z) expansion, which makes the calculation valid at all values of fractional pion momentum z. We also replace the nonrelativistic wave function of a loosely bound pion by the more realistic procedure of projecting to the light-cone pion wave function, which in turn is taken from well known models. The full calculation does not confirm the (1-z){sup 2} behavior of the fragmentation function (FF) predicted in [E. L. Berger, Z. Phys. C 4, 289 (1980); Phys. Lett. 89B, 241 (1980] for z>0.5, and only works at very large z>0.95, where it is in reasonable agreement with phenomenological FFs. Otherwise, we observe quite a different z-dependence which grossly underestimates data at smaller z. The disagreement is reduced after the addition of pions from decays of light vector mesons, but still remains considerable. The process dependent higher twist terms are also calculated exactly and found to be important at large z and/or p{sub T}.

  14. Spontaneous chiral symmetry breaking by hydromagnetic buoyancy

    NASA Astrophysics Data System (ADS)

    Chatterjee, Piyali; Mitra, Dhrubaditya; Brandenburg, Axel; Rheinhardt, Matthias

    2011-08-01

    Evidence for the parity-breaking nature of the magnetic buoyancy instability in a stably stratified gas is reported. In the absence of rotation, no helicity is produced, but the nonhelical state is found to be unstable to small helical perturbations during the development of the instability. The parity-breaking nature of this magnetohydrodynamic instability appears to be the first of its kind and has properties similar to those in chiral symmetry breaking in biochemistry. Applications to the production of mean fields in galaxy clusters are discussed.

  15. Nuclear axial currents in chiral effective field theory

    DOE PAGESBeta

    Baroni, Alessandro; Girlanda, Luca; Pastore, Saori; Schiavilla, Rocco; Viviani, Michele

    2016-01-11

    Two-nucleon axial charge and current operators are derived in chiral effective field theory up to one loop. The derivation is based on time-ordered perturbation theory and accounts for cancellations between the contributions of irreducible diagrams and the contributions owing to nonstatic corrections from energy denominators of reducible diagrams. Ultraviolet divergencies associated with the loop corrections are isolated in dimensional regularization. The resulting axial current is finite and conserved in the chiral limit, while the axial charge requires renormalization. As a result, a complete set of contact terms for the axial charge up to the relevant order in the power countingmore » is constructed.« less

  16. Circular Dichroism in the Photoionization of Nanoparticles from Chiral Compounds

    SciTech Connect

    Paul, J.; Doerzbach, A.; Siegmann, K.

    1997-10-01

    The dichroism in photoemission from chiral molecules is observed for the first time. Particles consisting of chiral molecules are suspended in air and irradiated alternately with right and left circularly polarized uv light. We found a polarization dependence in the total photoelectric current. The asymmetries observed are of the order of 10{sup {minus}2} to 10{sup {minus}3} , as expected from perturbation theory, and reverse their sign when the handedness of the molecules is changed. {copyright} {ital 1997} {ital The American Physical Society}

  17. Chiral Graphene Quantum Dots.

    PubMed

    Suzuki, Nozomu; Wang, Yichun; Elvati, Paolo; Qu, Zhi-Bei; Kim, Kyoungwon; Jiang, Shuang; Baumeister, Elizabeth; Lee, Jaewook; Yeom, Bongjun; Bahng, Joong Hwan; Lee, Jaebeom; Violi, Angela; Kotov, Nicholas A

    2016-02-23

    Chiral nanostructures from metals and semiconductors attract wide interest as components for polarization-enabled optoelectronic devices. Similarly to other fields of nanotechnology, graphene-based materials can greatly enrich physical and chemical phenomena associated with optical and electronic properties of chiral nanostructures and facilitate their applications in biology as well as other areas. Here, we report that covalent attachment of l/d-cysteine moieties to the edges of graphene quantum dots (GQDs) leads to their helical buckling due to chiral interactions at the "crowded" edges. Circular dichroism (CD) spectra of the GQDs revealed bands at ca. 210-220 and 250-265 nm that changed their signs for different chirality of the cysteine edge ligands. The high-energy chiroptical peaks at 210-220 nm correspond to the hybridized molecular orbitals involving the chiral center of amino acids and atoms of graphene edges. Diverse experimental and modeling data, including density functional theory calculations of CD spectra with probabilistic distribution of GQD isomers, indicate that the band at 250-265 nm originates from the three-dimensional twisting of the graphene sheet and can be attributed to the chiral excitonic transitions. The positive and negative low-energy CD bands correspond to the left and right helicity of GQDs, respectively. Exposure of liver HepG2 cells to L/D-GQDs reveals their general biocompatibility and a noticeable difference in the toxicity of the stereoisomers. Molecular dynamics simulations demonstrated that d-GQDs have a stronger tendency to accumulate within the cellular membrane than L-GQDs. Emergence of nanoscale chirality in GQDs decorated with biomolecules is expected to be a general stereochemical phenomenon for flexible sheets of nanomaterials. PMID:26743467

  18. Non-Perturbative Field Theories.

    NASA Astrophysics Data System (ADS)

    Stephenson, David

    Available from UMI in association with The British Library. Requires signed TDF. Some non-perturbative aspects of field theories are studied by applying lattice gauge theory techniques. The low-lying hadronic mass spectrum is calculated numerically using quenched lattice quantum chromodynamics. The results of large numerical simulations performed on a distributed array processor are presented and analysed. Particular emphasis is stressed upon the understanding of systematic and statistical errors in the calculation. In addition, the pion decay constant and the chiral condensate are evaluated. An attempt is made to relate the numerical findings to the experimentally measured quantities. A pioneering attempt to understand Yukawa couplings is discussed. A toy Fermion-Higgs system is studied numerically on a transputer array. Dynamical fermions are included in the investigation of the behavior of the system over a wide range of Yukawa couplings. A phase diagram is found for the model which shows evidence of spontaneous chiral symmetry breaking transitions. Extensions of the model are discussed together some speculations concerning the behaviour of Yukawa couplings in general. The possibility of using the lattice as a model for space-time is investigated by studying the propagation of particles on a fractal lattice. In addition, the use of truncated fractals as novel regulators is studied numerically in the hope that the problem of fermion doubling will be alleviated.

  19. Chiral quirkonium decays

    NASA Astrophysics Data System (ADS)

    Fok, R.; Kribs, Graham D.

    2011-08-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N)ic infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between “chiral quirkonia” versus “vectorlike quirkonia” are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, tt¯, tb¯/bt¯, and γH, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and Wγ, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  20. Chiral Quirkonium Decays

    SciTech Connect

    Fok, R.; Kribs, Graham D.; /Fermilab

    2011-06-01

    We calculate the two-body decay rates of quirkonium states formed from quirks that acquire mass solely through electroweak symmetry breaking. We consider SU(N){sub ic} infracolor with two flavors of quirks transforming under the electroweak group (but not QCD) of the standard model. In one case, the quirks are in a chiral representation of the electroweak group, while in the other case, a vectorlike representation. The differences in the dominant decay channels between 'chiral quirkonia' versus 'vectorlike quirkonia' are striking. Several chiral quirkonia states can decay into the unique two-body resonance channels WH, ZH, t{bar t}, t{bar b}/b{bar t}, and {gamma}H, which never dominate for vectorlike quirkonia. Additionally, the channels WW, WZ, ZZ, and W{gamma}, are shared among both chiral and vectorlike quirkonia. Resonances of dileptons or light quarks (dijets) can dominate for some vectorlike quirkonia states throughout their mass range, while these modes never dominate for chiral quirkonia unless the decays into pairs of gauge or Higgs bosons are kinematically forbidden.

  1. Spontaneous chirality in simple systems

    PubMed

    Pickett; Gross; Okuyama

    2000-10-23

    Two simple examples of spontaneous chiral symmetry breaking are presented. The first is close-packed cylindrically confined spheres. As the cylinder diameter is varied, one obtains a variety of chiral phases. The second example involves unconfined dipolar particles with an isotropic attraction, which also exhibits chiral ground states. We speculate that a dilute magnetorheological fluid film, with the addition of smaller particles to provide an attractive entropic interaction, will exhibit a chiral columnar ground state. PMID:11030973

  2. The chiral phase transition and the role of vacuum fluctuations

    NASA Astrophysics Data System (ADS)

    Khan, Rashid; Andersen, Jens O.; Kyllingstad, Lars T.; Khan, Majid

    2016-03-01

    We apply optimized perturbation theory to the quark-meson model at finite temperature T and quark chemical potential μ. The effective potential is calculated to one loop both in the chiral limit and at the physical point and used to study the chiral dynamics of two-flavor QCD. The critical temperature and the order of the phase transition depend heavily on whether or not one includes the bosonic and fermionic vacuum fluctuations in the effective potential. A full one-loop calculation in the chiral limit predicts a first-order transition for all values of μ. At the physical point, one finds a crossover in the whole μ-T plane.

  3. Vibrational evidence for chiral recognition phenomena in vacuo

    NASA Astrophysics Data System (ADS)

    Suhm, Martin A.

    2007-06-01

    Molecules and molecular conformations which cannot be superimposed on their mirror image are chiral. Chirality or handedness plays an important role throughout the life sciences. When two molecules interact, they can sense their relative handedness, giving rise to spectroscopic signatures of chiral recognition. This is often mediated by hydrogen bonds, most versatile and directional intermolecular interactions. If the distinction between the homo- and heteroconfigurational pairs of molecules is large enough, chiral discrimination, i.e. differences in abundance may occur. The contact between two flexible, transiently chiral molecules may induce a matching of their handedness, i.e. chirality synchronization. Such phenomena are best studied at low temperatures in vacuum isolation, without perturbing interactions [1]. Structural information on the isolated molecular complexes can be obtained by rotational spectroscopy [2], if there is a sufficient dipole moment. Vibrational spectroscopy [3] provides a more universal, but also more coarse-grained access to these phenomena. Our group has reported the first spectroscopic example of chiral recognition between constitutionally identical molecules in the gas phase [4]. We have found a case of chiral discrimination in tetrameric aggregates of methyl lactate, where the relative configuration controls the hydrogen bond topology [5]. In the case of alcohols, we have observed different degrees of chirality synchronization up to a quantitative chirality matching in dimers of trifluoroethanol [6]. These discoveries became possible through the use of a powerful combination of FTIR spectroscopy and high-throughput, pulsed supersonic nozzle expansions into large vacuum chambers [7]. The isolated and elementary character of the investigated molecular assemblies is favourable for quantum chemical treatments [8]. Valuable benchmarks for the modeling of more complex chiral recognition phenomena are thus established. [1] A. Al-Rabaa, E. Br

  4. Contesting the paradigm of chirality

    NASA Astrophysics Data System (ADS)

    Efrati, Efi

    2012-02-01

    In 1893 Lord Kelvin coined the term chirality, and stated what is to become the elementary paradigm of chirality: 'I call any geometrical figure, or any group of points, chiral, and say it has chirality, if its image in a plane mirror , ideally realized cannot be brought to coincide with itself'. While the notion of chirality has greatly advanced our understanding of the structures of molecules and crystals, it has been shown to be inconsistent with every pseudo-scalar quantification. In this talk I will present a tabletop demonstration of a chiral structure which is constructed through the achiral summation of identical elementary units which are symmetric under reflection. The seeming contradiction to the definition of chirality is reconciled by proposing an alternative definition, relying on the physicist interpretation of the right hand rule.

  5. Determination of the chiral condensate from QCD Dirac spectrum on the lattice

    SciTech Connect

    Fukaya, H.; Onogi, T.; Aoki, S.; Chiu, T. W.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.

    2011-04-01

    We calculate the chiral condensate of QCD with 2, 2+1, and 3 flavors of sea quarks. Lattice QCD simulations are performed employing dynamical overlap fermions with up- and down-quark masses covering a range between 3 and 100 MeV. On L{approx}1.8-1.9 fm lattices at a lattice spacing {approx}0.11 fm, we calculate the eigenvalue spectrum of the overlap-Dirac operator. By matching the lattice data with the analytical prediction from chiral perturbation theory at the next-to-leading order, the chiral condensate in the massless limit of up and down quarks is determined.

  6. Chiral dynamics in the γ → p → pπ0 reaction

    NASA Astrophysics Data System (ADS)

    Hiller Blin, A. N.; Ledwig, T.; Vicente Vacas, M. J.

    2015-07-01

    We investigate the neutral pion photoproduction on the proton near threshold in covariant chiral perturbation theory with the explicit inclusion of Δ degrees of freedom. This channel is specially sensitive to chiral dynamics and the advent of very precise data from the Mainz microtron has shown the limits of the convergence of the chiral series for both the heavy baryon and the covariant approaches. We show that the inclusion of the Δ resonance substantially improves the convergence leading to a good agreement with data for a wider range of energies.

  7. Staggered fermions and chiral symmetry breaking in transverse lattice regulated QED

    SciTech Connect

    Griffin, P.A.

    1992-07-01

    Staggered fermions are constructed for the transverse lattice regularization scheme. The weak perturbation theory of transverse lattice non-compact QED is developed in light-cone gauge, and we argue that for fixed lattice spacing this theory is ultraviolet finite, order by order in perturbation theory. However, by calculating the anomalous scaling dimension of the link fields, we find that the interaction Hamiltonian becomes non-renormalizable for g{sup 2}(a) > 4{pi}, where g(a) is the bare (lattice) QED coupling constant. We conjecture that this is the critical point of the chiral symmetry breaking phase transition in QED. Non-perturbative chiral symmetry breaking is then studied in the strong coupling limit. The discrete remnant of chiral symmetry that remains on the lattice is spontaneously broken, and the ground state to lowest order in the strong coupling expansion corresponds to the classical ground state of the two-dimensional spin one-half Heisenberg antiferromagnet.

  8. Chiral symmetry restoration and scalar-pseudoscalar partners in QCD

    NASA Astrophysics Data System (ADS)

    Gómez Nicola, A.; Ruiz de Elvira, J.; Torres Andrés, R.

    2013-10-01

    We describe scalar-pseudoscalar partner degeneration at the QCD chiral transition in terms of the dominant low-energy physical states for the light quark sector. First, we obtain within model-independent one-loop chiral perturbation theory that the QCD pseudoscalar susceptibility is proportional to the quark condensate at low T. Next, we show that this chiral-restoring behavior for χP is compatible with recent lattice results for screening masses and gives rise to degeneration between the scalar and pseudoscalar susceptibilities (χS,χP) around the transition point, consistently with an O(4)-like current restoration pattern. This scenario is clearly confirmed by lattice data when we compare χS(T) with the quark condensate, expected to scale as χP(T). Finally, we show that saturating χS with the σ/f0(500) broad resonance observed in pion scattering and including its finite temperature dependence, allows us to describe the peak structure of χS(T) in lattice data and the associated critical temperature. This is carried out within a unitarized chiral perturbation theory scheme which generates the resonant state dynamically and is also consistent with partner degeneration.

  9. Intrinsic transverse momentum and dynamical chiral symmetry breaking

    SciTech Connect

    Christian Weiss, Peter Schweitzer, Mark Strikman

    2013-01-01

    We study the effect of QCD vacuum structure on the intrinsic transverse momentum distribution of partons in the nucleon at a low scale. The dynamical breaking of chiral symmetry is caused by non-perturbative interactions at distances of the order rho ~ 0.2 - 0.3 fm, much smaller than the typical nucleon size R ~ 1 fm, resulting in a two-scale picture of nucleon structure. Using an effective dynamical model based on chiral constituent quark degrees of freedom and the 1/N_c expansion (chiral quark-soliton model), we calculate the transverse momentum distribution of quarks and antiquarks at a low scale. The distribution of valence quarks is localized at p_T ~ 1/R. The distribution of flavor-singlet unpolarized sea quarks exhibits a power-like tail extending up to the chiral-symmetry-breaking scale 1/{rho}. A similar tail is present in the flavor-nonsinglet polarized sea. These features are model-independent and represent the imprint of the QCD vacuum on the nucleon's partonic structure. At the level of the nucleon's light-cone wave function, we show that sea quarks partly exist in correlated pairs of transverse size {rho} << R, analogous to short-range NN correlations in nuclei. We discuss the implications of our findings for the transverse momentum distributions in hard scattering processes (semi-inclusive DIS, Drell-Yan pair production) and possible experimental tests of the non-perturbative parton correlations induced by QCD vacuum structure.

  10. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD.

    PubMed

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-19

    We show that there exists a special compactification of QCD on R^{3}×S^{1} in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation m_{π}^{2}f_{π}^{2}=-m_{q}⟨q[over ¯]q⟩. Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S^{1}, and yield strong support for adiabatic continuity between the small-S^{1} and large-S^{1} regimes. We also find concrete microscopic connections between N=1 and N=2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics. PMID:27588843

  11. Chiral Lagrangian from Duality and Monopole Operators in Compactified QCD

    NASA Astrophysics Data System (ADS)

    Cherman, Aleksey; Schäfer, Thomas; Ünsal, Mithat

    2016-08-01

    We show that there exists a special compactification of QCD on R3×S1 in which the theory has a domain where continuous chiral symmetry breaking is analytically calculable. We give a microscopic derivation of the chiral Lagrangian, the chiral condensate, and the Gell-Mann-Oakes-Renner relation mπ2fπ2=-mq⟨q ¯ q ⟩ . Abelian duality, monopole operators, and flavor-twisted boundary conditions play the main roles. The flavor twisting leads to the new effect of fractional jumping of fermion zero modes among monopole instantons. Chiral symmetry breaking is induced by monopole-instanton operators, and the Nambu-Goldstone pions arise by color-flavor transmutation from gapless "dual photons." We also give a microscopic picture of the "constituent quark" masses. Our results are consistent with expectations from chiral perturbation theory at large S1, and yield strong support for adiabatic continuity between the small-S1 and large-S1 regimes. We also find concrete microscopic connections between N =1 and N =2 supersymmetric gauge theory dynamics and nonsupersymmetric QCD dynamics.

  12. Chiral EFT based nuclear forces: achievements and challenges

    NASA Astrophysics Data System (ADS)

    Machleidt, R.; Sammarruca, F.

    2016-08-01

    During the past two decades, chiral effective field theory has become a popular tool to derive nuclear forces from first principles. Two-nucleon interactions have been worked out up to sixth order of chiral perturbation theory and three-nucleon forces up to fifth order. Applications of some of these forces have been conducted in nuclear few- and many-body systems—with a certain degree of success. But in spite of these achievements, we are still faced with great challenges. Among them is the issue of a proper uncertainty quantification of predictions obtained when applying these forces in ab initio calculations of nuclear structure and reactions. A related problem is the order by order convergence of the chiral expansion. We start this review with a pedagogical introduction and then present the current status of the field of chiral nuclear forces. This is followed by a discussion of representative examples for the application of chiral two- and three-body forces in the nuclear many-body system including convergence issues.

  13. Computer-based analytical simulations of chiral hadronic processes

    NASA Astrophysics Data System (ADS)

    Aleksejevs, A.; Butler, M.

    2010-03-01

    The availability of computational modeling tools for subatomic physics (Form, FeynArts, FormCalc and FeynCalc) has made it possible to perform sophisticated calculations in perturbative quantum field theory. We have adapted these packages in order to apply them to the effective chiral field theory of hadronic interactions. A detailed description of this computational hadronic model is presented here, along with sample calculations.

  14. Chiral electron-chiral target scattering

    SciTech Connect

    Trantham, K.W.; Gay, T.J. Johnston, M.E.

    1996-05-01

    It is possible to have an electronic counterpart to the well known effect of optical circular dichroism: electron circular dichroism (ECD) is the preferential scattering of longitudinally polarized electrons by a chiral target. Resulting essentially from a difference in total scattering cross section for different incident electron helicities, this {open_quotes}parity-violating{close_quotes} effect is allowed by symmetry because the scattering target is handed. The authors have searched for ECD in camphor by measuring the transmitted intensity of electrons with positive (negative) helicity I{sub +({minus})} through a gas cell containing stereoisomers of camphor vapor and constructing the asymmetry A = (I{sub +} {minus} I{sub {minus}}). Within their sensitivity (2x10{sup {minus}4}) the authors were not able to detect ECD at the energies investigated (10 eV). Prospects for future investigations, particularly in light of the recent positive results measured in Muenster, will be discussed.

  15. Chiral symmetry and pentaquarks

    SciTech Connect

    Dmitri Diakonov

    2004-07-01

    Spontaneous chiral symmetry breaking, mesons and baryons are illustrated in the language of the Dirac theory. Various forces acting between quarks inside baryons are discussed. I explain why the naive quark models typically overestimate pentaquark masses by some 500 MeV and why in the fully relativistic approach to baryons pentaquarks turn out to be light. I discuss briefly why it can be easier to produce pentaquarks at low than at high energies.

  16. Chiral Biomarkers in Meteorites

    NASA Technical Reports Server (NTRS)

    Hoover, Richard B.

    2010-01-01

    The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be

  17. A Chiral Granular Gas

    NASA Astrophysics Data System (ADS)

    Tsai, J.-C.; Ye, Fangfu; Rodriguez, Juan; Gollub, J. P.; Lubensky, T. C.

    2005-05-01

    Inspired by rattleback toys, we created small chiral wires that rotate in a preferred direction on a vertically oscillating platform and quantified their motion with experiment and simulation. We demonstrate experimentally that angular momentum of rotation about particle centers of mass is converted to collective angular momentum of center-of-mass motion in a granular gas of these wires, and we introduce a continuum model that explains our observations.

  18. A chiral granular gas.

    PubMed

    Tsai, J-C; Ye, Fangfu; Rodriguez, Juan; Gollub, J P; Lubensky, T C

    2005-06-01

    Inspired by rattleback toys, we created small chiral wires that rotate in a preferred direction on a vertically oscillating platform and quantified their motion with experiment and simulation. We demonstrate experimentally that angular momentum of rotation about particle centers of mass is converted to collective angular momentum of center-of-mass motion in a granular gas of these wires, and we introduce a continuum model that explains our observations. PMID:16090323

  19. Chirality and protein folding

    NASA Astrophysics Data System (ADS)

    Kwiecinska, Joanna I.; Cieplak, Marek

    2005-05-01

    There are several simple criteria of folding to a native state in model proteins. One of them involves crossing of a threshold value of the root mean square deviation distance away from the native state. Another checks whether all native contacts are established, i.e. whether the interacting amino acids come closer than some characteristic distance. We use Go-like models of proteins and show that such simple criteria may prompt one to declare folding even though fragments of the resulting conformations have a wrong sense of chirality. We propose that a better condition of folding should augment the simple criteria with the requirement that most of the local values of the chirality should be nearly native. The kinetic discrepancy between the simple and compound criteria can be substantially reduced in the Go-like models by providing the Hamiltonian with a term which favours native values of the local chirality. We study the effects of this term as a function of its amplitude and compare it to other models such as ones with side groups and ones with angle-dependent potentials.

  20. Chirality and equilibrium biopolymer bundles.

    PubMed

    Grason, Gregory M; Bruinsma, Robijn F

    2007-08-31

    We use continuum theory to show that chirality is a key thermodynamic control parameter for the aggregation of biopolymers: chirality produces a stable disperse phase of hexagonal bundles under moderately poor solvent conditions, as has been observed in in vitro studies of F actin [O. Pelletier et al., Phys. Rev. Lett. 91, 148102 (2003)]. The large characteristic radius of these chiral bundles is not determined by a mysterious long-range molecular interaction but by in-plane shear elastic stresses generated by the interplay between a chiral torque and an unusual, but universal, nonlinear gauge term in the strain tensor of ordered chains that is imposed by rotational invariance. PMID:17931038

  1. Chiral drag force

    NASA Astrophysics Data System (ADS)

    Rajagopal, Krishna; Sadofyev, Andrey V.

    2015-10-01

    We provide a holographic evaluation of novel contributions to the drag force acting on a heavy quark moving through strongly interacting plasma. The new contributions are chiral in the sense that they act in opposite directions in plasmas containing an excess of left- or right-handed quarks. The new contributions are proportional to the coefficient of the axial anomaly, and in this sense also are chiral. These new contributions to the drag force act either parallel to or antiparallel to an external magnetic field or to the vorticity of the fluid plasma. In all these respects, these contributions to the drag force felt by a heavy quark are analogous to the chiral magnetic effect (CME) on light quarks. However, the new contribution to the drag force is independent of the electric charge of the heavy quark and is the same for heavy quarks and antiquarks, meaning that these novel effects do not in fact contribute to the CME current. We show that although the chiral drag force can be non-vanishing for heavy quarks that are at rest in the local fluid rest frame, it does vanish for heavy quarks that are at rest in a suitably chosen frame. In this frame, the heavy quark at rest sees counterpropagating momentum and charge currents, both proportional to the axial anomaly coefficient, but feels no drag force. This provides strong concrete evidence for the absence of dissipation in chiral transport, something that has been predicted previously via consideration of symmetries. Along the way to our principal results, we provide a general calculation of the corrections to the drag force due to the presence of gradients in the flowing fluid in the presence of a nonzero chemical potential. We close with a consequence of our result that is at least in principle observable in heavy ion collisions, namely an anticorrelation between the direction of the CME current for light quarks in a given event and the direction of the kick given to the momentum of all the heavy quarks and

  2. Optical activity of chirally distorted nanocrystals

    NASA Astrophysics Data System (ADS)

    Tepliakov, Nikita V.; Baimuratov, Anvar S.; Baranov, Alexander V.; Fedorov, Anatoly V.; Rukhlenko, Ivan D.

    2016-05-01

    We develop a general theory of optical activity of semiconductor nanocrystals whose chirality is induced by a small perturbation of their otherwise achiral electronic subsystems. The optical activity is described using the quantum-mechanical expressions for the rotatory strengths and dissymmetry factors introduced by Rosenfeld. We show that the rotatory strengths of optically active transitions are decomposed on electric dipole and magnetic dipole contributions, which correspond to the electric dipole and magnetic dipole transitions between the unperturbed quantum states. Remarkably, while the two kinds of rotatory strengths are of the same order of magnitude, the corresponding dissymmetry factors can differ by a factor of 105. By maximizing the dissymmetry of magnetic dipole absorption one can significantly enhance the enantioselectivity in the interaction of semiconductor nanocrystals with circularly polarized light. This feature may advance chiral and analytical methods, which will benefit biophysics, chemistry, and pharmaceutical science. The developed theory is illustrated by an example of intraband transitions inside a semiconductor nanocuboid, whose rotatory strengths and dissymmetry factors are calculated analytically.

  3. Forming disoriented chiral condensates through fluctuations

    SciTech Connect

    Rischke, D.H.

    1998-10-01

    Using the influence functional formalism, classical equations of motion for the O(N) model are derived in the presence of a heat bath, in both the symmetric phase as well as the phase of spontaneously broken symmetry. The heat bath leads to dissipation and fluctuation terms in the classical equations of motion, which are explicitly computed to lowest order in perturbation theory. In the broken phase these terms are found to be large for the {sigma} field, even at zero temperature, due to the decay process {sigma}{r_arrow}{pi}{pi}, while they are small for the {pi} fields at temperatures below T{sub c}{approx_equal}160 MeV. It is shown that in large volumes the presence of dissipation and fluctuations suppresses the formation of disoriented chiral condensates (DCC{close_quote}s). In small volumes, however, fluctuations become sufficiently large to induce the formation of DCC{close_quote}s even if chiral symmetry has not been restored in the initial stage of the system{close_quote}s evolution. {copyright} {ital 1998} {ital The American Physical Society}

  4. Chiral vacuum fluctuations in quantum gravity

    NASA Astrophysics Data System (ADS)

    Bethke, Laura; Magueijo, João

    2012-05-01

    In this paper we investigate cosmological tensor modes in terms of the Ashtekar variables of loop quantum gravity, for complex values of the Immirzi parameter. While, on-shell, the classical Hamiltonian reduces to the usual expression found in cosmological perturbation theory, the quantum Hamiltonian displays significant differences. We can find a physical Fourier space Hamiltonian in terms of graviton creation and annihilation operators, after selecting out the non-physical modes through the inner product which itself is determined by the reality conditions. We are left with the usual graviton modes but with a chiral asymmetry in the the vacuum energy and fluctuations. The latter depends on γ (in particular it vanishes for purely real γ) and on the ordering of the 2-point function. Such an effect would leave a distinctive imprint in the polarisation of the cosmic microwave background, thus finally engaging quantum gravity in meaningful experimental test.

  5. Hypernuclei and in-medium chiral dynamics

    NASA Astrophysics Data System (ADS)

    Finelli, P.

    2008-04-01

    A recently introduced relativistic nuclear energy density functional, constrained by features of low-energy QCD, is extended to describe the structure of hypernuclei. The density-dependent mean field and the spin-orbit potential of a Λ-hyperon in a nucleus, are consistently calculated using the SU(3) extension of in-medium chiral perturbation theory. The leading long-range ΛN interaction arises from kaon-exchange and 2π-exchange with a Σ-hyperon in the intermediate state. Scalar and vector mean fields, originating from in-medium changes of the quark condensates, produce a sizeable short-range spin-orbit interaction. The model, when applied to oxygen as a test case, provides a natural explanation for the smallness of the effective Λ spin-orbit potential: an almost complete cancellation between the background contributions (scalar and vector) and the long-range terms generated by two-pion exchange.

  6. Chiral plaquette polaron theory of cuprate superconductivity

    NASA Astrophysics Data System (ADS)

    Tahir-Kheli, Jamil; Goddard, William A., III

    2007-07-01

    separation distance from (π/a,π/a) given by δQ≈(2π/a)x , where x is the doping. When the perturbed x2-y2 band energy in mean field is included, incommensurability along the Cu-O bond direction is favored. A resistivity ˜Tμ+1 arises when the polaron energy separation density is of the form ˜Δμ due to Coulomb scattering of the x2-y2 band with polarons. A uniform density leads to linear resistivity. The coupling of the x2-y2 band to the undoped Cud9 spins leads to the angle-resolved photoemission pseudogap and its qualitative doping and temperature dependence. The chiral plaquette polaron leads to an explanation of the evolution of the bilayer splitting in Bi-2212.

  7. CHIRAL POLLUTANTS: OCCURRENCE AND SIGNIFICANCE

    EPA Science Inventory

    This task involves process research to determine the environmental occurrence and fate of enantiomers of selected chiral pesticides, PCBs and other chiral pollutants with an emphasis on currently-used modern pesticides expected to have short to intermediate environmental half-liv...

  8. Chiral Crystallization of Ethylenediamine Sulfate

    ERIC Educational Resources Information Center

    Koby, Lawrence; Ningappa, Jyothi B.; Dakesssian, Maria; Cuccia, Louis A.

    2005-01-01

    The optimal conditions for the crystallization of achiral ethylenediamine sulfate into large chiral crystals that are ideal for polarimetry studies and observation using Polaroid sheets are presented. This experiment is an ideal undergraduate experiment, which clearly demonstrates the chiral crystallization of an achiral molecule.

  9. CHIRAL PESTICIDES: OCCURRENCE AND SIGNIFICANCE

    EPA Science Inventory

    Like amino acids, certain pesticides exist in "left-handed" and "right-handed" (chiral) forms. Commercially available chiral pesticides are produced as racemic mixtures in which the ratio of the two forms (or enantiomers) is 1:1. Enantiomers have the same ...

  10. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo F.; Karas, Andrew S.; Schultz, Benjamin A.; Engel, Michael; Glotzer, Sharon C.

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams.

  11. Mass-Selective Chiral Analysis.

    PubMed

    Boesl, Ulrich; Kartouzian, Aras

    2016-06-12

    Three ways of realizing mass-selective chiral analysis are reviewed. The first is based on the formation of diastereomers that are of homo- and hetero- type with respect to the enantiomers of involved chiral molecules. This way is quite well-established with numerous applications. The other two ways are more recent developments, both based on circular dichroism (CD). In one, conventional or nonlinear electronic CD is linked to mass spectrometry (MS) by resonance-enhanced multiphoton ionization. The other is based on CD in the angular distribution of photoelectrons, which is measured in combination with MS via photoion photoelectron coincidence. Among the many important applications of mass-selective chiral analysis, this review focuses on its use as an analytical tool for the development of heterogeneous enantioselective chemical catalysis. There exist other approaches to combine chiral analysis and mass-selective detection, such as chiral chromatography MS, which are not discussed here. PMID:27070181

  12. Mass-Selective Chiral Analysis

    NASA Astrophysics Data System (ADS)

    Boesl, Ulrich; Kartouzian, Aras

    2016-06-01

    Three ways of realizing mass-selective chiral analysis are reviewed. The first is based on the formation of diastereomers that are of homo- and hetero- type with respect to the enantiomers of involved chiral molecules. This way is quite well-established with numerous applications. The other two ways are more recent developments, both based on circular dichroism (CD). In one, conventional or nonlinear electronic CD is linked to mass spectrometry (MS) by resonance-enhanced multiphoton ionization. The other is based on CD in the angular distribution of photoelectrons, which is measured in combination with MS via photoion photoelectron coincidence. Among the many important applications of mass-selective chiral analysis, this review focuses on its use as an analytical tool for the development of heterogeneous enantioselective chemical catalysis. There exist other approaches to combine chiral analysis and mass-selective detection, such as chiral chromatography MS, which are not discussed here.

  13. Controlling Chirality of Entropic Crystals.

    PubMed

    Damasceno, Pablo F; Karas, Andrew S; Schultz, Benjamin A; Engel, Michael; Glotzer, Sharon C

    2015-10-01

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. PMID:26550757

  14. Density perturbation theory

    SciTech Connect

    Palenik, Mark C.; Dunlap, Brett I.

    2015-07-28

    Despite the fundamental importance of electron density in density functional theory, perturbations are still usually dealt with using Hartree-Fock-like orbital equations known as coupled-perturbed Kohn-Sham (CPKS). As an alternative, we develop a perturbation theory that solves for the perturbed density directly, removing the need for CPKS. This replaces CPKS with a true Hohenberg-Kohn density perturbation theory. In CPKS, the perturbed density is found in the basis of products of occupied and virtual orbitals, which becomes ever more over-complete as the size of the orbital basis set increases. In our method, the perturbation to the density is expanded in terms of a series of density basis functions and found directly. It is possible to solve for the density in such a way that it makes the total energy stationary even if the density basis is incomplete.

  15. Pion-photon reactions and chiral dynamics in Primakoff processes at COMPASS

    NASA Astrophysics Data System (ADS)

    Friedrich, Jan Michael

    2016-01-01

    With the COMPASS experiment at CERN, pion-photon reactions are investigated via the Primakoff effect, implying that high-energetic pions react with the quasi-real photon field surrounding the target nuclei. The production of a single hard photon in such a pion scattering at lowest momentum transfer to the nucleus is related to pion Compton scattering. From the measured cross-section shape, the pion polarisability is determined. The COMPASS measurement is in contradiction to the earlier dedicated measurements, and rather in agreement with the theoretical expectation from chiral perturbation theory. In the same data taking, reactions with neutral and charged pions in the final state are measured and analyzed. At low energy in the pion-photon centre-of-momentum system, these reactions are governed by chiral dynamics and contain information relevant for chiral perturbation theory. At higher energies, resonances are produced and their radiative coupling is investigated.

  16. Chiral symmetry and effective field theories for hadronic, nuclear and stellar matter

    NASA Astrophysics Data System (ADS)

    Holt, Jeremy W.; Rho, Mannque; Weise, Wolfram

    2016-03-01

    Chiral symmetry, first entering in nuclear physics in the 1970s for which Gerry Brown played a seminal role, has led to a stunningly successful framework for describing strongly-correlated nuclear dynamics both in finite and infinite systems. We review how the early, germinal idea conceived with the soft-pion theorems in the pre-QCD era has evolved into a highly predictive theoretical framework for nuclear physics, aptly assessed by Steven Weinberg: "it (chiral effective field theory) allows one to show in a fairly convincing way that what they (nuclear physicists) have been doing all along... is the correct first step in a consistent approximation scheme". Our review recounts both how the theory presently fares in confronting Nature and how one can understand its extremely intricate workings in terms of the multifaceted aspects of chiral symmetry, namely, chiral perturbation theory, skyrmions, Landau Fermi-liquid theory, the Cheshire cat phenomenon, and hidden local and mended symmetries.

  17. Visualizing the chiral anomaly in Dirac and Weyl semimetals with photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Behrends, Jan; Grushin, Adolfo G.; Ojanen, Teemu; Bardarson, Jens H.

    2016-02-01

    Quantum anomalies are the breaking of a classical symmetry by quantum fluctuations. They dictate how physical systems of diverse nature, ranging from fundamental particles to crystalline materials, respond topologically to external perturbations, insensitive to local details. The anomaly paradigm was triggered by the discovery of the chiral anomaly that contributes to the decay of pions into photons and influences the motion of superfluid vortices in 3He-A. In the solid state, it also fundamentally affects the properties of topological Weyl and Dirac semimetals, recently realized experimentally. In this work we propose that the most identifying consequence of the chiral anomaly, the charge density imbalance between fermions of different chirality induced by nonorthogonal electric and magnetic fields, can be directly observed in these materials with the existing technology of photoemission spectroscopy. With angle resolution, the chiral anomaly is identified by a characteristic note-shaped pattern of the emission spectra, originating from the imbalanced occupation of the bulk states and a previously unreported momentum dependent energy shift of the surface state Fermi arcs. We further demonstrate that the chiral anomaly likewise leaves an imprint in angle averaged emission spectra, facilitating its experimental detection. Thereby, our work provides essential theoretical input to foster the direct visualization of the chiral anomaly in condensed matter, in contrast to transport properties, such as negative magnetoresistance, which can also be obtained in the absence of a chiral anomaly.

  18. Off-equilibrium photon production during the chiral phase transition

    SciTech Connect

    Michler, Frank; Hees, Hendrik van; Dietrich, Dennis D.; Leupold, Stefan; Greiner, Carsten

    2013-09-15

    In the early stage of ultrarelativistic heavy-ion collisions chiral symmetry is restored temporarily. During this so-called chiral phase transition, the quark masses change from their constituent to their bare values. This mass shift leads to the spontaneous non-perturbative creation of quark–antiquark pairs, which effectively contributes to the formation of the quark–gluon plasma. We investigate the photon production induced by this creation process. We provide an approach that eliminates possible unphysical contributions from the vacuum polarization and renders the resulting photon spectra integrable in the ultraviolet domain. The off-equilibrium photon numbers are of quadratic order in the perturbative coupling constants while a thermal production is only of quartic order. Quantitatively, we find, however, that for the most physical mass-shift scenarios and for photon momenta larger than 1 GeV the off-equilibrium processes contribute less photons than the thermal processes. -- Highlights: •We investigate first-order photon emission arising from the chiral mass shift. •We provide an ansatz eliminating possible unphysical vacuum contributions. •Our ansatz leads to photon spectra being integrable in the ultraviolet domain.

  19. Microscopically constrained mean-field models from chiral nuclear thermodynamics

    NASA Astrophysics Data System (ADS)

    Rrapaj, Ermal; Roggero, Alessandro; Holt, Jeremy W.

    2016-06-01

    We explore the use of mean-field models to approximate microscopic nuclear equations of state derived from chiral effective field theory across the densities and temperatures relevant for simulating astrophysical phenomena such as core-collapse supernovae and binary neutron star mergers. We consider both relativistic mean-field theory with scalar and vector meson exchange as well as energy density functionals based on Skyrme phenomenology and compare to thermodynamic equations of state derived from chiral two- and three-nucleon forces in many-body perturbation theory. Quantum Monte Carlo simulations of symmetric nuclear matter and pure neutron matter are used to determine the density regimes in which perturbation theory with chiral nuclear forces is valid. Within the theoretical uncertainties associated with the many-body methods, we find that select mean-field models describe well microscopic nuclear thermodynamics. As an additional consistency requirement, we study as well the single-particle properties of nucleons in a hot/dense environment, which affect e.g., charged-current weak reactions in neutron-rich matter. The identified mean-field models can be used across a larger range of densities and temperatures in astrophysical simulations than more computationally expensive microscopic models.

  20. Chiral current generation in QED by longitudinal photons

    NASA Astrophysics Data System (ADS)

    Acosta Avalo, J. L.; Pérez Rojas, H.

    2016-08-01

    We report the generation of a pseudovector electric current having imbalanced chirality in an electron-positron strongly magnetized gas in QED. It propagates along the external applied magnetic field B as a chiral magnetic effect in QED. It is triggered by a perturbative electric field parallel to B, associated to a pseudovector longitudinal mode propagating along B. An electromagnetic chemical potential was introduced, but our results remain valid even when it vanishes. A nonzero fermion mass was assumed, which is usually considered vanishing in the literature. In the quantum field theory formalism at finite temperature and density, an anomaly relation for the axial current was found for a medium of massive fermions. It bears some analogy to the Adler-Bell-Jackiw anomaly. From the expression for the chiral current in terms of the photon self-energy tensor in a medium, it is obtained that electrons and positrons scattered by longitudinal photons (inside the light cone) contribute to the chiral current, as well as the to pair creation due to longitudinal photons (out of light cone). In the static limit, an electric pseudovector current is obtained in the lowest Landau level.

  1. Chiral fiber optical isolator

    NASA Astrophysics Data System (ADS)

    Kopp, Victor I.; Zhang, Guoyin; Zhang, Sheng; Genack, Azriel Z.; Neugroschl, Dan

    2009-02-01

    We propose an in-fiber chiral optical isolator based on chiral fiber polarizer technology and calculate its performance by incorporating the magnetic field into the scattering matrix. The design will be implemented in a special preform, which is passed through a miniature heat zone as it is drawn and twisted. The birefringence of the fiber is controlled by adjusted the diameter of a dual-core optical fiber. By adjusting the twist, the fiber can convert linear to circular polarization and reject one component of circular polarization. In the novel central portion of the isolator, the fiber diameter is large. The effective birefringence of the circular central core with high Verdet constant embedded in an outer core of slightly smaller index of refraction is small. The central potion is a non-reciprocal polarization converter which passes forward traveling left circularly polarized (LCP) light as LCP, while converting backward propagating LCP to right circularly polarized (RCP) light. Both polarizations of light traveling backwards are scattered out of the isolator. Since it is an all-glass structure, we anticipate that the isolator will be able to handle several watts of power and will be environmentally robust.

  2. Chiral quantum dot based materials

    NASA Astrophysics Data System (ADS)

    Govan, Joseph; Loudon, Alexander; Baranov, Alexander V.; Fedorov, Anatoly V.; Gun'ko, Yurii

    2014-05-01

    Recently, the use of stereospecific chiral stabilising molecules has also opened another avenue of interest in the area of quantum dot (QD) research. The main goal of our research is to develop new types of technologically important quantum dot materials containing chiral defects, study their properties and explore their applications. The utilisation of chiral penicillamine stabilisers allowed the preparation of new water soluble white emitting CdS quantum nanostructures which demonstrated circular dichroism in the band-edge region of the spectrum. It was also demonstrated that all three types of QDs (D-, L-, and Rac penicillamine stabilised) show very broad emission bands between 400 and 700 nm due to defects or trap states on the surfaces of the nanocrystals. In this work the chiral CdS based quantum nanostructures have also been doped by copper metal ions and new chiral penicilamine stabilized CuS nanoparticles have been prepared and investigated. It was found that copper doping had a strong effect at low levels in the synthesis of chiral CdS nanostructures. We expect that this research will open new horizons in the chemistry of chiral nanomaterials and their application in biotechnology, sensing and asymmetric synthesis.

  3. Automated Lattice Perturbation Theory

    SciTech Connect

    Monahan, Christopher

    2014-11-01

    I review recent developments in automated lattice perturbation theory. Starting with an overview of lattice perturbation theory, I focus on the three automation packages currently "on the market": HiPPy/HPsrc, Pastor and PhySyCAl. I highlight some recent applications of these methods, particularly in B physics. In the final section I briefly discuss the related, but distinct, approach of numerical stochastic perturbation theory.

  4. Chiral Bosonic Phases on the Haldane Honeycomb Lattice

    NASA Astrophysics Data System (ADS)

    Vasic, Ivana; Petrescu, Alexandru; Le Hur, Karyn; Hofstetter, Walter; Collaboration Collaboration

    2015-03-01

    Motivated by its recent realization in an ultracold atom experiment, we investigate the honeycomb lattice tight-binding model introduced by Haldane, for bosons with local interactions at the average filling of one boson per site. We uncover in the ground state phase diagram three phases: a uniform superfluid (SF), a chiral superfluid (CSF) and a plaquette Mott insulator with local current loops (PMI). Nearest-neighbor and next-nearest neighbor currents distinguish CSF from SF, and the phase transition between them is first order. We apply bosonic dynamical mean field theory and exact diagonalization to obtain the zero temperature phase diagram, complementing numerics with calculations of excitation spectra in strong and weak coupling perturbation theory. Furthermore, we explore the possibility of chiral Mott insulating phases at the average filling of one boson every two sites. The characteristic density fluctuations, current correlation functions, and excitation spectra are measurable in ultracold atom experiments.

  5. Amino Acids and Chirality

    NASA Technical Reports Server (NTRS)

    Cook, Jamie E.

    2012-01-01

    Amino acids are among the most heavily studied organic compound class in carbonaceous chondrites. The abundance, distributions, enantiomeric compositions, and stable isotopic ratios of amino acids have been determined in carbonaceous chondrites fi'om a range of classes and petrographic types, with interesting correlations observed between these properties and the class and typc of the chondritcs. In particular, isomeric distributions appear to correlate with parent bodies (chondrite class). In addition, certain chiral amino acids are found in enantiomeric excess in some chondrites. The delivery of these enantiomeric excesses to the early Earth may have contributed to the origin of the homochirality that is central to life on Earth today. This talk will explore the amino acids in carbonaceous chondritcs and their relevance to the origin of life.

  6. Chiral Bosonization of Superconformal Ghosts

    NASA Technical Reports Server (NTRS)

    Shi, Deheng; Shen, Yang; Liu, Jinling; Xiong, Yongjian

    1996-01-01

    We explain the difference of the Hilbert space of the superconformal ghosts (beta,gamma) system from that of its bosonized fields phi and chi. We calculate the chiral correlation functions of phi, chi fields by inserting appropriate projectors.

  7. Life's chirality from prebiotic environments

    NASA Astrophysics Data System (ADS)

    Gleiser, Marcelo; Walker, Sara Imari

    2012-10-01

    A key open question in the study of life is the origin of biomolecular homochirality: almost every life-form on Earth has exclusively levorotary amino acids and dextrorotary sugars. Will the same handedness be preferred if life is found elsewhere? We review some of the pertinent literature and discuss recent results suggesting that life's homochirality resulted from sequential chiral symmetry breaking triggered by environmental events. In one scenario, autocatalytic prebiotic reactions undergo stochastic fluctuations due to environmental disturbances, in a mechanism reminiscent of evolutionary punctuated equilibrium: short-lived destructive events may lead to long-term enantiomeric excess. In another, chiral-selective polymerization reaction rates influenced by environmental effects lead to substantial chiral excess even in the absence of autocatalysis. Applying these arguments to other potentially life-bearing platforms has implications to the search for extraterrestrial life: we predict that a statistically representative sampling of extraterrestrial stereochemistry will be racemic (chirally neutral) on average.

  8. Critical dimensions for chiral bosons

    SciTech Connect

    Mezincescu, L.; Nepomechie, R.I.

    1988-05-15

    We give the Lagrangian formulation of a Bose model in 1+1 dimensions which describes a free chiral Lie-algebra-valued current. This model is a non-Abelian generalization of the chiral scalar model of Siegel. Both the Abelian and non-Abelian actions have a gauge invariance, which becomes anomalous when the models are quantized. The condition that this anomaly be canceled coincides with the string no-ghost condition.

  9. Frame independent cosmological perturbations

    SciTech Connect

    Prokopec, Tomislav; Weenink, Jan E-mail: j.g.weenink@uu.nl

    2013-09-01

    We compute the third order gauge invariant action for scalar-graviton interactions in the Jordan frame. We demonstrate that the gauge invariant action for scalar and tensor perturbations on one physical hypersurface only differs from that on another physical hypersurface via terms proportional to the equation of motion and boundary terms, such that the evolution of non-Gaussianity may be called unique. Moreover, we demonstrate that the gauge invariant curvature perturbation and graviton on uniform field hypersurfaces in the Jordan frame are equal to their counterparts in the Einstein frame. These frame independent perturbations are therefore particularly useful in relating results in different frames at the perturbative level. On the other hand, the field perturbation and graviton on uniform curvature hypersurfaces in the Jordan and Einstein frame are non-linearly related, as are their corresponding actions and n-point functions.

  10. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    PubMed Central

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-01-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application. PMID:27401541

  11. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation

    NASA Astrophysics Data System (ADS)

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-07-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application.

  12. Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation.

    PubMed

    Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping

    2016-01-01

    Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enantiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application. PMID:27401541

  13. Correlation between structures of chiral polymers and their efficiency for chiral resolution by crystallization.

    PubMed

    Menahem, Tali; Pravda, Martin; Mastai, Yitzhak

    2009-10-01

    In this work, we describe the correlation between chiral polymer structures, particularly alpha-helical and random coil conformations, and their efficiency as chiral resolving agents in crystallization processes. A set of chiral block copolymers based on polyethylene oxide with chiral glutamic acid oligopeptide segments (PEG(113)-b-(+)-(S)-Glu(20)) were synthesized and employed as additives in the crystallization of rac-threonine. CD spectroscopy demonstrates that structures of chiral polymers could be switched between a helical and a disordered random coil by pH. The effect of these polymers at different conformations on the crystallization kinetics, crystal morphology, and chiral resolution of rac-threonine is reported. Our study demonstrates that only chiral polymers with alpha-helical conformations of the chiral segment are effective as additives for chiral resolution throughout crystallization. Overall, our results provide useful guidelines for the selection and design of chiral polymer additives that will act efficiently for chiral resolution by crystallization. PMID:19455618

  14. Ward identities and chiral anomalies for coupled fermionic chains

    NASA Astrophysics Data System (ADS)

    Costa, L. C.; Ferraz, A.; Mastropietro, Vieri

    2013-12-01

    Coupled fermionic chains are usually described by an effective model written in terms of bonding and anti-bonding fermionic fields with linear dispersion in the vicinities of the respective Fermi points. We derive for the first time exact Ward Identities (WI) for this model, proving the existence of chiral anomalies which verify the Adler-Bardeen non-renormalization property. Such WI are expected to play a crucial role in the understanding of the thermodynamic properties of the system. Our results are non-perturbative and are obtained analyzing Grassmann functional integrals by means of constructive quantum field theory methods.

  15. Peripheral NN scattering from subtractive renormalization of chiral interactions

    SciTech Connect

    Batista, E. F.; Szpigel, S.; Timóteo, V. S.

    2014-11-11

    We apply five subtractions in the Lippman-Schwinger (LS) equation in order to perform a non-perturbative renormalization of chiral N3LO nucleon-nucleon interactions. Here we compute the phase shifts for the uncoupled peripheral waves at renormalization scales between 0.1 fm{sup −1} and 1 fm{sup −1}. In this range, the results are scale invariant and provide an overall good agreement with the Nijmegen partial wave analysis up to at least E{sub lab} = 150 MeV, with a cutoff at Λ = 30 fm{sup −1}.

  16. The Perturbed Puma Model

    NASA Astrophysics Data System (ADS)

    Rong, Shu-Jun; Liu, Qiu-Yu

    2012-04-01

    The puma model on the basis of the Lorentz and CPT violation may bring an economical interpretation to the conventional neutrinos oscillation and part of the anomalous oscillations. We study the effect of the perturbation to the puma model. In the case of the first-order perturbation which keeps the (23) interchange symmetry, the mixing matrix element Ue3 is always zero. The nonzero mixing matrix element Ue3 is obtained in the second-order perturbation that breaks the (23) interchange symmetry.

  17. Neutron matter with Quantum Monte Carlo: chiral 3N forces and static response

    DOE PAGESBeta

    Buraczynski, M.; Gandolfi, S.; Gezerlis, A.; Schwenk, A.; Tews, I.

    2016-03-01

    Neutron matter is related to the physics of neutron stars and that of neutron-rich nuclei. Moreover, Quantum Monte Carlo (QMC) methods offer a unique way of solving the many-body problem non-perturbatively, providing feedback on features of nuclear interactions and addressing scenarios that are inaccessible to other approaches. Our contribution goes over two recent accomplishments in the theory of neutron matter: a) the fusing of QMC with chiral effective field theory interactions, focusing on local chiral 3N forces, and b) the first attempt to find an ab initio solution to the problem of static response.

  18. Neutron matter with Quantum Monte Carlo: chiral 3N forces and static response

    NASA Astrophysics Data System (ADS)

    Buraczynski, M.; Gandolfi, S.; Gezerlis, A.; Schwenk, A.; Tews, I.

    2016-03-01

    Neutron matter is related to the physics of neutron stars and that of neutron-rich nuclei. Quantum Monte Carlo (QMC) methods offer a unique way of solving the many-body problem non-perturbatively, providing feedback on features of nuclear interactions and addressing scenarios that are inaccessible to other approaches. In this contribution we go over two recent accomplishments in the theory of neutron matter: a) the fusing of QMC with chiral effective field theory interactions, focusing on local chiral 3N forces, and b) the first attempt to find an ab initio solution to the problem of static response.

  19. Nucleon sigma term and strange quark content from lattice QCD with exact chiral symmetry

    SciTech Connect

    Ohki, H.; Fukaya, H.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Matsufuru, H.; Noaki, J.; Shintani, E.; Onogi, T.

    2008-09-01

    We calculate the nucleon sigma term in two-flavor lattice QCD utilizing the Feynman-Hellman theorem. Both sea and valence quarks are described by the overlap fermion formulation, which preserves exact chiral and flavor symmetries on the lattice. We analyze the lattice data for the nucleon mass using the analytical formulae derived from the baryon chiral perturbation theory. From the data at valence quark mass set different from sea quark mass, we may extract the sea quark contribution to the sigma term, which corresponds to the strange quark content. We find that the strange quark content is much smaller than the previous lattice calculations and phenomenological estimates.

  20. Chiral symmetry in rotating systems

    NASA Astrophysics Data System (ADS)

    Malik, Sham S.

    2015-08-01

    The triaxial rotating system at critical angular momentum I ≥Iband exhibits two enatiomeric (the left- and right-handed) forms. These enatiomers are related to each other through dynamical chiral symmetry. The chiral symmetry in rotating system is defined by an operator χ ˆ =Rˆy (π) T ˆ, which involves the product of two distinct symmetries, namely, continuous and discrete. Therefore, new guidelines are required for testing its commutation with the system Hamiltonian. One of the primary objectives of this study is to lay down these guidelines. Further, the possible impact of chiral symmetry on the geometrical arrangement of angular momentum vectors and investigation of observables unique to nuclear chiral-twins is carried out. In our model, the angular momentum components (J1, J2, J3) occupy three mutually perpendicular axes of triaxial shape and represent a non-planar configuration. At certain threshold energy, the equation of motion in angular momentum develops a second order phase transition and as a result two distinct frames (i.e., the left- and right-handed) are formed. These left- and right-handed states correspond to a double well system and are related to each other through chiral operator. At this critical angular momentum, the centrifugal and Coriolis interactions lower the barrier in the double well system. The tunneling through the double well starts, which subsequently lifts the degeneracy among the rotational states. A detailed analysis of the behavior of rotational energies, spin-staggering, and the electromagnetic transition probabilities of the resulting twin-rotational bands is presented. The ensuing model results exhibit similarities with many observed features of the chiral-twins. An advantage of our formalism is that it is quite simple and it allows us to pinpoint the understanding of physical phenomenon which lead to chiral-twins in rotating systems.

  1. Towards the chiral limit in QCD

    SciTech Connect

    Shailesh Chandrasekharan

    2006-02-28

    Computing hadronic observables by solving QCD from first principles with realistic quark masses is an important challenge in fundamental nuclear and particle physics research. Although lattice QCD provides a rigorous framework for such calculations many difficulties arise. Firstly, there are no good algorithms to solve lattice QCD with realistically light quark masses. Secondly, due to critical slowing down, Monte Carlo algorithms are able to access only small lattice sizes on coarse lattices. Finally, due to sign problems it is almost impossible to study the physics of finite baryon density. Lattice QCD contains roughly three mass scales: the cutoff (or inverse lattice spacing) a{sup -1}, the confinement scale {Lambda}{sub QCD}, and the pion mass m{sub {pi}}. Most conventional Monte Carlo algorithms for QCD become inefficient in two regimes: when {Lambda}{sub QCD} becomes small compared to a{sup -1} and when m{sub {pi}} becomes small compared to {Lambda}{sub QCD}. The former can be largely controlled by perturbation theory thanks to asymptotic freedom. The latter is more difficult since chiral extrapolations are typically non-analytic and can be unreliable if the calculations are not done at sufficiently small quark masses. For this reason it has been difficult to compute quantities close to the chiral limit. The essential goal behind this proposal was to develop a new approach towards understanding QCD and QCD-like theories with sufficiently light quarks. The proposal was based on a novel cluster algorithm discovered in the strong coupling limit with staggered fermions [1]. This algorithm allowed us to explore the physics of exactly massless quarks and as well as light quarks. Thus, the hope was that this discovery would lead to the complete solution of at least a few strongly coupled QCD-like theories. The solution would be far better than those achievable through conventional methods and thus would be able to shed light on the chiral physics from a new

  2. Can a Non-Chiral Object Be Made of Two Identical Chiral Moieties?

    ERIC Educational Resources Information Center

    LeMarechal, Jean Francois

    2008-01-01

    Several pedagogical objects can be used to discuss chirality. Here, we use the cut of an apple to show that the association of identical chiral moieties can form a non-chiral object. Octahedral chirality is used to find situations equivalent to the cut of the apple. (Contains 5 figures.)

  3. Chiral Chlordane Components in Environmental Matrices

    EPA Science Inventory

    Chlordane, a persistent, bioaccumulative and toxic organochlorine pesticide, has been studied for many years. Since the advent of chiral analysis for environmental samples, over 2,400 measurements have been made of various chiral chlordane components. Chlordane enantiomer fractio...

  4. Effects of chirality and surface stresses on the bending and buckling of chiral nanowires

    NASA Astrophysics Data System (ADS)

    Wang, Jian-Shan; Shimada, Takahiro; Wang, Gang-Feng; Kitamura, Takayuki

    2014-01-01

    Due to their superior optical, elastic and electrical properties, chiral nanowires have many applications as sensors, probes, and building blocks of nanoelectromechanical systems. In this paper, we develop a refined Euler-Bernoulli beam model for chiral nanowires with surface effects and material chirality incorporated. This refined model is employed to investigate the bending and buckling of chiral nanowires. It is found that surface effects and material chirality significantly affect the elastic behaviour of chiral nanowires. This study is helpful not only for understanding the size-dependent behaviour of chiral nanowires, but also for characterizing their mechanical properties.

  5. Controlling Chirality of Entropic Crystals

    NASA Astrophysics Data System (ADS)

    Damasceno, Pablo; Karas, Andrew; Schultz, Benjamin; Engel, Michael; Glotzer, Sharon

    Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, thus far homochiral colloidal crystals, which are candidates for photonic metamaterials, are absent. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness. Building blocks with stronger faceting exhibit higher selectivity and assemble a chiral crystal with handedness uniquely determined by the particle chirality. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals. We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. Work supported by the National Science Foundation, Division of Materials Research Award No. DMR 1120923, U.S. Army Research Office under Grant Award No. W911NF-10-1-0518, and also by the DOD/ASD (R&E) under Award No. N00244-09-1-0062.

  6. Hydrogen-Regulated Chiral Nanoplasmonics.

    PubMed

    Duan, Xiaoyang; Kamin, Simon; Sterl, Florian; Giessen, Harald; Liu, Na

    2016-02-10

    Chirality is a highly important topic in modern chemistry, given the dramatically different pharmacological effects that enantiomers can have on the body. Chirality of natural molecules can be controlled by reconfiguration of molecular structures through external stimuli. Despite the rapid progress in plasmonics, active regulation of plasmonic chirality, particularly in the visible spectral range, still faces significant challenges. In this Letter, we demonstrate a new class of hybrid plasmonic metamolecules composed of magnesium and gold nanoparticles. The plasmonic chirality from such plasmonic metamolecules can be dynamically controlled by hydrogen in real time without introducing macroscopic structural reconfiguration. We experimentally investigate the switching dynamics of the hydrogen-regulated chiroptical response in the visible spectral range using circular dichroism spectroscopy. In addition, energy dispersive X-ray spectroscopy is used to examine the morphology changes of the magnesium particles through hydrogenation and dehydrogenation processes. Our study can enable plasmonic chiral platforms for a variety of gas detection schemes by exploiting the high sensitivity of circular dichroism spectroscopy. PMID:26745446

  7. Tactoids of chiral liquid crystals

    NASA Astrophysics Data System (ADS)

    Palacio-Betancur, Viviana; Villada-Gil, Stiven; Zhou, Ye; Armas-Pérez, Julio C.; de Pablo, Juan José; Hernández-Ortiz, Juan Pablo

    The phase diagram of chiral liquid crystals confined in ellipsoids is obtained, by following a theoretically informed Monte Carlo relaxation of the tensor alignment field Q. The free energy of the system is described by a functional in the framework of the Landau-de Gennes formalism. This study also includes the effect of anchoring strength, curvature, and chirality of the system. In the low chirality region of the phase diagram we found the twist bipolar (BS) phase and some cholesteric phases such as the radial spherical structure (RSS), twist cylinder (TC) and double twist cylinder (DTC) whose axis of rotation is not necessarily aligned with the major axis of the geometry. For high chirality scenarios, the disclination lines are twisted or bent near the surface preventing the formation of symmetric networks of defects, although an hexagonal pattern is formed on the surface which might serve as open sites for collocation of colloids. By analyzing the free energies of isochoric systems, prolate geometries tend to be more favorable for high chirality and low anchoring conditions. Universidad Nacional de Colombia Ph.D. grant and COLCIENCIAS under the Contract No. 110-165-843-748. CONACYT for Postdoctoral Fellowships Nos. 186166 and 203840.

  8. Chiral Thirring–Wess model

    SciTech Connect

    Rahaman, Anisur

    2015-10-15

    The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson.

  9. Field induced spin chirality and chirality switching in magnetic multilayers

    NASA Astrophysics Data System (ADS)

    Tartakovskaya, Elena V.

    2015-05-01

    The physical origin of the field-induced spin chirality experimentally observed in rare earth multilayers is determined. It is shown that the effect is possible due to the interplay between solid-state exchange interactions (the Ruderman-Kittel-Kasuya-Yosida and the Dsyaloshinsky-Moriya interactions), the external magnetic field and a special confinement of magnetic constituents. The presented model describes a certain temperature dependence of the chirality factor in agreement with experimental data and opens a new way to design nanostructured objects with predicted handedness.

  10. Chiral lattice fermions with correct vacuum polarization and chiral anomaly

    SciTech Connect

    Pryor, C. )

    1991-04-15

    An action for chiral lattice fermions is proposed, which avoids the Nielsen-Ninomiya theorem by virtue of its nonlocality and nonbilinearity. The action is constructed by eliminating the extra fermion modes with a gauge-violating Majorana-type Wilson mass, which is then rendered invariant by an integration over gauge transformations. The free propagator is calculated, and the one-loop vacuum polarization is shown to be identical to that for Wilson fermions, even at nonzero lattice spacing. Also the chiral anomaly is shown to be the same as for Wilson fermions in the continuum limit.

  11. Repulsive Casimir force in chiral metamaterials.

    PubMed

    Zhao, R; Zhou, J; Koschny, Th; Economou, E N; Soukoulis, C M

    2009-09-01

    We demonstrate theoretically that one can obtain repulsive Casimir forces and stable nanolevitations by using chiral metamaterials. By extending the Lifshitz theory to treat chiral metamaterials, we find that a repulsive force and a minimum of the interaction energy possibly exist for strong chirality, under realistic frequency dependencies and correct limiting values (for zero and infinite frequencies) of the permittivity, permeability, and chiral coefficients. PMID:19792309

  12. Chiral order and fluctuations in multi-flavour QCD

    NASA Astrophysics Data System (ADS)

    Descotes-Genon, S.; Girlanda, L.; Stern, J.

    2003-03-01

    Multi-flavour (N_f ge 3) chiral perturbation theory (χPT) may exhibit instabilities due to vacuum fluctuations of sea bar q q pairs. Keeping the fluctuations small would require a very precise fine tuning of the low-energy constants L_4(μ) and L_6(μ) to L_4^{crit}(M_ρ) = - 0.51 \\cdot 10^{-3}, L_6^{crit}(M_ρ) = - 0.26 \\cdot 10^{-3}. A small deviation from these critical values - like the one suggested by the phenomenology of OZI-rule violation in the scalar channel - is amplified by huge numerical factors inducing large effects of vacuum fluctuations. This would lead in particular to a strong Nf dependence of chiral symmetry breaking (χSB) and a suppression of the multi-flavour chiral order parameters. A simple resummation is shown to cure the instability of N_fge 3 χPT, but it modifies the standard expressions of some O( p 2 ) and O( p 4 ) low-energy parameters in terms of observables. On the other hand, for r= m s / m & gt; 15, the two-flavour condensate is not suppressed, due to the contribution induced by massive vacuum bar ss pairs. Thanks to the latter, the standard two-flavour χPT is protected from multi-flavour instabilities and could provide a well-defined expansion scheme in powers of non-strange quark masses.

  13. Power counting regime of chiral effective field theory and beyond.

    SciTech Connect

    Hall, J. M.M.; Leinweber, D. B.; Young, R. D.; Physics; Univ. of Adelaide

    2010-08-10

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  14. Power counting regime of chiral effective field theory and beyond

    SciTech Connect

    Hall, J. M. M.; Leinweber, D. B.; Young, R. D.

    2010-08-01

    Chiral effective field theory ({chi}EFT) complements numerical simulations of quantum chromodynamics (QCD) on a space-time lattice. It provides a model-independent formalism for connecting lattice simulation results at finite volume and a variety of quark masses to the physical world. The asymptotic nature of the chiral expansion places the focus on the first few terms of the expansion. Thus, knowledge of the power-counting regime (PCR) of {chi}EFT, where higher-order terms of the expansion may be regarded as negligible, is as important as knowledge of the expansion itself. Through the consideration of a variety of renormalization schemes and associated parameters, techniques to identify the PCR where results are independent of the renormalization scheme are established. The nucleon mass is considered as a benchmark for illustrating this general approach. Because the PCR is small, the numerical simulation results are also examined to search for the possible presence of an intrinsic scale which may be used in a nonperturbative manner to describe lattice simulation results outside of the PCR. Positive results that improve on the current optimistic application of chiral perturbation theory ({chi}PT) beyond the PCR are reported.

  15. Chiral Sensor for Enantiodiscrimination of Varied Acids.

    PubMed

    Huang, Huayin; Bian, Guangling; Zong, Hua; Wang, Yabai; Yang, Shiwei; Yue, Huifeng; Song, Ling; Fan, Hongjun

    2016-06-01

    A chiral thiophosphoroamide 4 derived from (1R,2R)-1,2-diaminocyclohexane is used as a highly effective chiral sensor for the chiral recognition of varied acids via ion-pairing and hydrogen-bonding interactions using (1)H, (19)F and (31)P NMR. PMID:27192021

  16. Chirality and gravitational parity violation.

    PubMed

    Bargueño, Pedro

    2015-06-01

    In this review, parity-violating gravitational potentials are presented as possible sources of both true and false chirality. In particular, whereas phenomenological long-range spin-dependent gravitational potentials contain both truly and falsely chiral terms, it is shown that there are models that extend general relativity including also coupling of fermionic degrees of freedom to gravity in the presence of torsion, which give place to short-range truly chiral interactions similar to that usually considered in molecular physics. Physical mechanisms which give place to gravitational parity violation together with the expected size of the effects and their experimental constraints are discussed. Finally, the possible role of parity-violating gravity in the origin of homochirality and a road map for future research works in quantum chemistry is presented. PMID:25919812

  17. Microwave propagation in chiral metamaterials

    NASA Astrophysics Data System (ADS)

    Prybylski, Aida; Yon, Luis; Noginova, Natalia

    Chiral hyperbolic metamaterials are predicted to show interesting properties associated with possible topological photonic states in these materials, which present new opportunities for light control and manipulation. As prototypes, we consider two metal-dielectric systems designed for microwave range: a twisted wires array, where chirality is associated with shape of metal inclusions, and a rotated layer system, with parallel wires in each layer, and direction of the wires orientation rotated from layer to layer. Systems with different content of metal and layer-to-layer distance were fabricated and studied in the free space propagation experiment. The results were discussed in terms of effective media consideration.

  18. Collisions in Chiral Kinetic Theory.

    PubMed

    Chen, Jing-Yuan; Son, Dam T; Stephanov, Mikhail A

    2015-07-10

    Using a covariant formalism, we construct a chiral kinetic theory Lorentz invariant to order O(ℏ), which includes collisions. We find a new contribution to the particle number current due to the side jumps required by the conservation of angular momentum during collisions. We also find a conserved symmetric stress-energy tensor as well as the H function obeying Boltzmann's H theorem. We demonstrate their use by finding a general equilibrium solution and the values of the anomalous transport coefficients characterizing the chiral vortical effect. PMID:26207458

  19. Mechanical chirality: A chiral catalyst with a ring to it

    NASA Astrophysics Data System (ADS)

    Goldup, Stephen M.

    2016-05-01

    A chiral [2]rotaxane in which the asymmetry is derived from the way in which the two components are mechanically interlocked -- rather than being encoded in the covalent connectivity of the components themselves -- has been shown to act as an enantioselective organocatalyst.

  20. Determination of the Chiral Condensate from (2+1)-Flavor Lattice QCD

    SciTech Connect

    Fukaya, H.; Aoki, S.; Hashimoto, S.; Kaneko, T.; Yamada, N.; Noaki, J.; Onogi, T.

    2010-03-26

    We perform a precise calculation of the chiral condensate in QCD using lattice QCD with 2+1 flavors of dynamical overlap quarks. Up and down quark masses cover a range between 3 and 100 MeV on a 16{sup 3}x48 lattice at a lattice spacing {approx}0.11 fm. At the lightest sea quark mass, the finite volume system on the lattice is in the {epsilon} regime. By matching the low-lying eigenvalue spectrum of the Dirac operator with the prediction of chiral perturbation theory at the next-to-leading order, we determine the chiral condensate in (2+1)-flavor QCD with strange quark mass fixed at its physical value as {Sigma}{sup MS}(2 GeV)=[242(04)((+19/-18)) MeV]{sup 3} where the errors are statistical and systematic, respectively.

  1. Quantum theory of chiral interactions in cholesteric liquid crystals

    NASA Astrophysics Data System (ADS)

    Issaenko, S. A.; Harris, A. B.; Lubensky, T. C.

    1999-07-01

    The effective chiral interaction between molecules arising from long-range quantum interactions between fluctuating charge moments is analyzed in terms of a simple model of chiral molecules. This model is based on the approximations that (a) the dominant excited states of a molecule form a band whose width is small compared to the average energy of excitation above the ground state and (b) biaxial orientational correlation between adjacent molecules can be neglected. Previous treatments of quantum chiral interactions have been based on a multipole expansion of the effective interaction energy within second-order perturbation theory. We consider a system consisting of elongated molecules and, although we invoke the expansion in terms of coordinates transverse to the long axis of constituent molecules, we treat the longitudinal coordinate exactly. Such an approximation is plausible for molecules in real liquid crystals. The macroscopic cholesteric wave vector Q (Q=2π/P, where P is the pitch) is obtained via Q=h/K2, where K2 is the Frank elastic constant for twist and h is the torque field which we calculate from the effective chiral interaction κIJaI×aJ.RIJ, where the unit vector aI specifies the orientation of molecule I and RIJ is the displacement of molecule I relative to molecule J. We identify two distinct physical limits depending on whether one or both of the interacting molecules are excited in the virtual state. When both molecules are excited, we regain the R-8IJ dependence of κIJ on intermolecular separation found previously by Van der Meer et al. [J. Chem. Phys. 65, 3935 (1976)]. The two-molecule, unlike the one-molecule term, can be interpreted in terms of a superposition of pairwise interactions between individual atoms (or local chiral centers) on the two molecules. Contributions to κIJ when one molecule is excited in the virtual state are of order R-7IJ for helical molecules which are assumed not to have a global dipole moment, but whose atoms

  2. Coherent perfect absorption in chiral metamaterials.

    PubMed

    Ye, Yuqian; Hay, Darrick; Shi, Zhimin

    2016-07-15

    We study the coherent perfect absorption (CPA) of a chiral structure and derive analytically the CPA condition for transversely isotropic chiral structures in circular polarization bases. The coherent absorption of such a chiral system is generally polarization dependent and can be tuned by the relative phase between the coherent input beams. To demonstrate our theoretical predictions, a chiral metamaterial absorber operating in the terahertz frequency range is optimized. We numerically demonstrate that a coherent absorption of 99.5% can be achieved. Moreover, we show that an optimized CPA chiral structure can be used as an interferometric control of polarization state of the output beams with constant output intensity. PMID:27420535

  3. Scaling laws in chiral hydrodynamic turbulence

    NASA Astrophysics Data System (ADS)

    Yamamoto, Naoki

    2016-06-01

    We study the turbulent regime of chiral (magneto)hydrodynamics for charged and neutral matter with chirality imbalance. We find that the chiral magnetohydrodynamics for charged plasmas possesses a unique scaling symmetry, only without fluid helicity under the local charge neutrality. We also find a different type of unique scaling symmetry in the chiral hydrodynamics for neutral matter with fluid helicity in the inertial range. We show that these symmetries dictate the self-similar inverse cascade of the magnetic and kinetic energies. Our results imply the possible inverse energy cascade in core-collapse supernovae due to the chiral transport of neutrinos.

  4. Chiral xenobiotics bioaccumulations and environmental health prospectives.

    PubMed

    Hussain, Iqbal; ALOthman, Zeid A; Alwarthan, Abdulrahman A; Sanagi, Mohd Marsin; Ali, Imran

    2015-08-01

    The chiral xenobiotics are very dangerous for all of us due to the different enantioselective toxicities of the enantiomers. Besides, these have different enantioselective bioaccumulations and behaviors in our body and other organisms. It is of urgent need to understand the enantioselective bioaccumulations, toxicities, and the health hazards of the chiral xenobiotics. The present article describes the classification, sources of contamination, distribution, enantioselective bioaccumulation, and the toxicities of the chiral xenobiotics. Besides, the efforts are also made to discuss the prevention and remedial measures of the havoc of the chiral xenobiotics. The challenges of the chiral xenobiotics have also been highlighted. Finally, future prospectives are also discussed. PMID:26148690

  5. Vortex perturbation dynamics

    NASA Technical Reports Server (NTRS)

    Criminale, W. O.; Lasseigne, D. G.; Jackson, T. L.

    1995-01-01

    An initial value approach is used to examine the dynamics of perturbations introduced into a vortex under strain. Both the basic vortex considered and the perturbations are taken as fully three-dimensional. An explicit solution for the time evolution of the vorticity perturbations is given for arbitrary initial vorticity. Analytical solutions for the resulting velocity components are found when the initial vorticity is assumed to be localized. For more general initial vorticity distributions, the velocity components are determined numerically. It is found that the variation in the radial direction of the initial vorticity disturbance is the most important factor influencing the qualitative behavior of the solutions. Transient growth in the magnitude of the velocity components is found to be directly attributable to the compactness of the initial vorticity.

  6. Influence of the Polyakov loop on the chiral phase transition in the two flavor chiral quark model

    NASA Astrophysics Data System (ADS)

    Markó, G.; Szép, Zs.

    2010-09-01

    The SU(2)L×SU(2)R chiral quark model consisting of the (σ,π→) meson multiplet and the constituent quarks propagating on the homogeneous background of a temporal gauge field is solved at finite temperature and quark baryon chemical potential μq using an expansion in the number of flavors Nf, both in the chiral limit and for the physical value of the pion mass. Keeping the fermion propagator at its tree level, several approximations to the pion propagator are investigated. These approximations correspond to different partial resummations of the perturbative series. Comparing their solution with a diagrammatically formulated resummation relying on a strict large-Nf expansion of the perturbative series, one concludes that only when the local part of the approximated pion propagator resums infinitely many orders in 1/Nf of fermionic contributions a sufficiently rapid crossover transition at μq=0 is achieved allowing for the existence of a tricritical point or a critical end point in the μq-T phase diagram. The renormalization and the possibility of determining the counterterms in the resummation provided by a strict large-Nf expansion are investigated.

  7. Helical motion of chiral liquid crystal droplets

    NASA Astrophysics Data System (ADS)

    Yamamoto, Takaki; Sano, Masaki

    Artificial swimmers have been intensively studied to understand the mechanism of the locomotion and collective behaviors of cells and microorganisms. Among them, most of the artificial swimmers are designed to move along the straight path. However, in biological systems, chiral dynamics such as circular and helical motion are quite common because of the chirality of their bodies, which are made of chiral biomolecules. To understand the role of the chirality in the physics of microswimmers, we designed chiral artificial swimmers and the theoretical model for the chiral motion. We found that chiral liquid crystal droplets, when dispersed in surfactant solutions, swim in the helical path induced by the Marangoni effect. We will discuss the mechanism of the helical motion with our phenomenological model. This work is supported by Grant-in-Aid for JSPS Fellows (Grant No. 26.9814), and MEXT KAKENHI Grant No. 25103004.

  8. Chirality effect in disordered graphene ribbon junctions

    NASA Astrophysics Data System (ADS)

    Long, Wen

    2012-05-01

    We investigate the influence of edge chirality on the electronic transport in clean or disordered graphene ribbon junctions. By using the tight-binding model and the Landauer-Büttiker formalism, the junction conductance is obtained. In the clean sample, the zero-magnetic-field junction conductance is strongly chirality-dependent in both unipolar and bipolar ribbons, whereas the high-magnetic-field conductance is either chirality-independent in the unipolar or chirality-dependent in the bipolar ribbon. Furthermore, we study the disordered sample in the presence of magnetic field and find that the junction conductance is always chirality-insensitive for both unipolar and bipolar ribbons with adequate disorders. In addition, the disorder-induced conductance plateaus can exist in all chiral bipolar ribbons provided the disorder strength is moderate. These results suggest that we can neglect the effect of edge chirality in fabricating electronic devices based on the magnetotransport in a disordered graphene ribbon.

  9. Micropatterning of cells reveals chiral morphogenesis

    PubMed Central

    2013-01-01

    Invariant left-right (LR) patterning or chirality is critical for embryonic development. The loss or reversal of LR asymmetry is often associated with malformations and disease. Although several theories have been proposed, the exact mechanism of the initiation of the LR symmetry has not yet been fully elucidated. Recently, chirality has been detected within single cells as well as multicellular structures using several in vitro approaches. These studies demonstrated the universality of cell chirality, its dependence on cell phenotype, and the role of physical boundaries. In this review, we discuss the theories for developmental LR asymmetry, compare various in vitro cell chirality model systems, and highlight possible roles of cell chirality in stem cell differentiation. We emphasize that the in vitro cell chirality systems have great promise for helping unveil the nature of chiral morphogenesis in development. PMID:23672821

  10. On the tensorial nature of chirality

    NASA Astrophysics Data System (ADS)

    Efrati, Efi; Irvine, William

    2013-03-01

    Chirality occupies a central role in fields ranging from biological self assembly to the design of optical meta-materials. The definition of chirality, as given by lord Kelvin in 1893, associates handedness with the lack of mirror symmetry. However, the quantification of chirality based on this definition has proven to be an elusive task. The difficulty in quantifying chirality is contrasted by the ease with which one determines the handedness of objects with a well defined axis such as screws and helices. In this talk I will present table-top demonstrations that show that a single object can simultaneously be left handed and right handed when considered from different directions. The orientation dependence of handedness motivates a tensorial quantification of chirality relating directions to rotations. I will give an explicit example of such a tensorial measure of chirality for embedded surfaces, and show how the tensorial nature of chirality can be probed in experiments and exploited as a design principle.

  11. Chiral phosphines in nucleophilic organocatalysis

    PubMed Central

    Xiao, Yumei; Sun, Zhanhu

    2014-01-01

    Summary This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols. PMID:25246969

  12. Baryon and chiral symmetry breaking

    SciTech Connect

    Gorsky, A.; Krikun, A.

    2014-07-23

    We briefly review the generalized Skyrmion model for the baryon recently suggested by us. It takes into account the tower of vector and axial mesons as well as the chiral symmetry breaking. The generalized Skyrmion model provides the qualitative explanation of the Ioffe’s formula for the baryon mass.

  13. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1994-07-01

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on possible experimental ramifications.

  14. Dynamics of the chiral transition

    SciTech Connect

    Gavin, S.

    1995-07-10

    Measurements of disoriented chiral condensates (DCC) in heavy ion collisions at RHIC can yield fundamental information on the nature of the QCD phase transition. I review theoretical efforts to understand DCC formation and present work in progress on their possible experimental ramifications. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  15. Non-perturbative aspects of hadron structure in QCD

    SciTech Connect

    Thomas, Anthony W.

    2012-09-26

    We review recent developments in the understanding of hadron structure in the context of QCD. These developments build on the success of lattice QCD and discoveries in chiral perturbation theory. We focus particularly on tests of QCD through the strangeness content of the nucleon, the investigation of excited states of the nucleon, where lattice QCD, experiment and phenomenology meet. Lastly, we discuss the implications of these developments in hadron structure for our understanding of nuclear structure and the equation of state of dense matter.

  16. Non-perturbative QCD Modeling and Meson Physics

    SciTech Connect

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-20

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  17. Non-perturbative QCD Modeling and Meson Physics

    NASA Astrophysics Data System (ADS)

    Nguyen, T.; Souchlas, N. A.; Tandy, P. C.

    2009-04-01

    Using a ladder-rainbow kernel previously established for light quark hadron physics, we explore the extension to masses and electroweak decay constants of ground state pseudoscalar and vector quarkonia and heavy-light mesons in the c- and b-quark regions. We make a systematic study of the effectiveness of a constituent mass concept as a replacement for a heavy quark dressed propagator for such states. The difference between vector and axial vector current correlators is explored within the same model to provide an estimate of the four quark chiral condensate and the leading distance scale for the onset of non-perturbative phenomena in QCD.

  18. Cosmological perturbations in antigravity

    NASA Astrophysics Data System (ADS)

    Oltean, Marius; Brandenberger, Robert

    2014-10-01

    We compute the evolution of cosmological perturbations in a recently proposed Weyl-symmetric theory of two scalar fields with oppositely signed conformal couplings to Einstein gravity. It is motivated from the minimal conformal extension of the standard model, such that one of these scalar fields is the Higgs while the other is a new particle, the dilaton, introduced to make the Higgs mass conformally symmetric. At the background level, the theory admits novel geodesically complete cyclic cosmological solutions characterized by a brief period of repulsive gravity, or "antigravity," during each successive transition from a big crunch to a big bang. For simplicity, we consider scalar perturbations in the absence of anisotropies, with potential set to zero and without any radiation. We show that despite the necessarily wrong-signed kinetic term of the dilaton in the full action, these perturbations are neither ghostlike nor tachyonic in the limit of strongly repulsive gravity. On this basis, we argue—pending a future analysis of vector and tensor perturbations—that, with respect to perturbative stability, the cosmological solutions of this theory are viable.

  19. Light meson electromagnetic form factors from three-flavor lattice QCD with exact chiral symmetry

    NASA Astrophysics Data System (ADS)

    Aoki, S.; Cossu, G.; Feng, X.; Hashimoto, S.; Kaneko, T.; Noaki, J.; Onogi, T.

    2016-02-01

    We study the chiral behavior of the electromagnetic (EM) form factors of pions and kaons in three-flavor lattice QCD. In order to make a direct comparison of the lattice data with chiral perturbation theory (ChPT), we employ the overlap quark action that has exact chiral symmetry. Gauge ensembles are generated at a lattice spacing of 0.11 fm with four pion masses ranging between Mπ≃290 MeV and 540 MeV and with a strange quark mass ms close to its physical value. We utilize the all-to-all quark propagator technique to calculate the EM form factors with high precision. Their dependence on ms and on the momentum transfer is studied by using the reweighting technique and the twisted boundary conditions for the quark fields, respectively. A detailed comparison with SU(2) and SU(3) ChPT reveals that the next-to-next-to-leading order terms in the chiral expansion are important to describe the chiral behavior of the form factors in the pion mass range studied in this work. We estimate the relevant low-energy constants and the charge radii, and find reasonable agreement with phenomenological and experimental results.

  20. Mean field theory of the linear sigma-model: chiral solitons

    SciTech Connect

    Kahana, S.; Ripka, G.

    1983-01-01

    The mean field theory of the chiral invariant sigma-model is outlined. bound states (solitons) of valence quarks are obtained self-consistently using a hedgehog shape for the pion field. A schematic model for the coupled fermion-boson fields is presented. Renormalization is worked out for the fermion one-loop corrections and numerical results presented for the purely scalar-field case. The interpretation of the baryon number of the perturbed vacuum is considered.

  1. The Relaxation of Twisted Chiral Nematic Liquid Crystals with Side-Chain Polymeric Layer

    NASA Astrophysics Data System (ADS)

    Zhou, Xuan; Zhang, Zhidong

    2013-09-01

    A generalized form of surface dissipation function, for the description of the relative motion of the nematic director with respect to the polymer side chains in twisted chiral nematic samples is proposed, and the relaxation time of such samples are investigated, using the perturbation analysis method proposed by Alexe-Ionescu et al. Our results show that the presence of both the surface dissipation and the polymer side chains increase the relaxation time.

  2. Nucleon structure in the chiral regime with domain wall fermions on an improved staggered sea

    SciTech Connect

    R.G. Edwards; G. Fleming; Ph. Hagler; J.W. Negele; K. Orginos; A.V. Pochinsky; D.B. Renner; D.G. Richards; W. Schroers

    2006-07-23

    Moments of unpolarized, helicity, and transversity distributions, electromagnetic form factors, and generalized form factors of the nucleon are presented from a preliminary analysis of lattice results using pion masses down to 359 MeV. The twist two matrix elements are calculated using a mixed action of domain wall valence quarks and asqtad staggered sea quarks and are renormalized perturbatively. Several observables are extrapolated to the physical limit using chiral perturbation theory. Results are compared with experimental moments of quark distributions and electromagnetic form factors and phenomenologically determined generalized form factors, and the implications on the transverse structure and spin content of the nucleon are discussed.

  3. Chiral sensing by nonchiral tetrapyrroles.

    PubMed

    Labuta, Jan; Hill, Jonathan P; Ishihara, Shinsuke; Hanyková, Lenka; Ariga, Katsuhiko

    2015-03-17

    Enantiomeric excess (ee) is a measure of the purity of an enantiomer of a chiral compound with respect to the presence of the complementary enantiomer. It is an important aspect of chemistry, especially in the fields of pharmaceuticals and asymmetric catalysis. Existing methods for determination of enantiomeric excesses using nuclear magnetic resonance (NMR) spectroscopy mostly rely on special chiral reagents (auxiliaries) that form two or more diastereomeric complexes with a chiral compound. As a result of this, the NMR spectrum of each enantiomer is different, allowing the determination of enantiomeric excess. In this Account, we describe a molecular design process that has allowed us to prepare prochiral solvating agents for NMR determination of ee of a wide variety of analyte types. At the outset of this work, we initially encountered the phenomenon of NMR peak splitting in the oxoporphyrinogen (OxP) host component of a supramolecular host-guest complex, where the extent of the splitting is apparently proportional to the guests' ee. Upon closer examination of the mechanism of action, it was found that several complicating factors, including prototropic tautomerism, macrocyclic inversion (ring-flipping), and 1:2 host-guest stoichiometry, obstruct potential applications of OxP as a chiral solvating agent. By considering the molecular conformation of the OxP host, a saddle-shaped calix[4]pyrrole, we moved to study the tetraphenylporphyrin (TPP) dication since it has a similar form, and it was found that it could also be used to probe ee. However, although TPP does not suffer from disadvantageous tautomeric processes, it is still subject to macrocyclic inversion and has the additional serious disadvantage of operating for ee sensing only at depressed temperatures. The intrinsic disadvantages of the OxP and TPP systems were finally overcome by covalently modifying the OxP chromophore by regioselective N-alkylation at one face of the molecule. This procedure yields a

  4. Liouvillian perturbations of black holes

    NASA Astrophysics Data System (ADS)

    Couch, W. E.; Holder, C. L.

    2007-10-01

    We apply the well-known Kovacic algorithm to find closed form, i.e., Liouvillian solutions, to the differential equations governing perturbations of black holes. Our analysis includes the full gravitational perturbations of Schwarzschild and Kerr, the full gravitational and electromagnetic perturbations of Reissner-Nordstrom, and specialized perturbations of the Kerr-Newman geometry. We also include the extreme geometries. We find all frequencies ω, in terms of black hole parameters and an integer n, which allow Liouvillian perturbations. We display many classes of black hole parameter values and their corresponding Liouvillian perturbations, including new closed-form perturbations of Kerr and Reissner-Nordstrom. We also prove that the only type 1 Liouvillian perturbations of Schwarzschild are the known algebraically special ones and that type 2 Liouvillian solutions do not exist for extreme geometries. In cases where we do not prove the existence or nonexistence of Liouvillian perturbations we obtain sequences of Diophantine equations on which decidability rests.

  5. Mechanism of chirality conversion by periodic change of temperature: Role of chiral clusters

    NASA Astrophysics Data System (ADS)

    Katsuno, Hiroyasu; Uwaha, Makio

    2016-01-01

    By grinding crystals in a solution, the chirality of crystal structure (and the molecular chirality for the case of chiral molecules as well) can be converted, and the cause of the phenomenon is attributed to crystal growth with chiral clusters. We show that the recently found chirality conversion with a periodic change of temperature can also be explained by crystal growth with chiral clusters. With the use of a generalized Becker-Döring model, which includes enantio-selective incorporation of small chiral clusters to large solid clusters, the change of cluster distribution and the mass flow between clusters are studied. The chiral clusters act as a reservoir to pump out the minority species to the majority, and the exponential amplification of the enantiomeric excess found in the experiment is reproduced in the numerical calculation.

  6. Topology and perturbation theory

    NASA Astrophysics Data System (ADS)

    Manjavidze, J.

    2000-08-01

    This paper contains description of the fields nonlinear modes successive quantization scheme. It is shown that the path integrals for absorption part of amplitudes are defined on the Dirac (δ-like) functional measure. This permits arbitrary transformation of the functional integral variables. New form of the perturbation theory achieved by mapping the quantum dynamics in the space WG of the (action, angle)-type collective variables. It is shown that the transformed perturbation theory contributions are accumulated exactly on the boundary ∂WG. Abilities of the developed formalism are illustrated by the Coulomb problem. This model is solved in the WC=(angle, angular momentum, Runge-Lentz vector) space and the reason of its exact integrability is emptiness of ∂WC.

  7. Renormalized Lie perturbation theory

    SciTech Connect

    Rosengaus, E.; Dewar, R.L.

    1981-07-01

    A Lie operator method for constructing action-angle transformations continuously connected to the identity is developed for area preserving mappings. By a simple change of variable from action to angular frequency a perturbation expansion is obtained in which the small denominators have been renormalized. The method is shown to lead to the same series as the Lagrangian perturbation method of Greene and Percival, which converges on KAM surfaces. The method is not superconvergent, but yields simple recursion relations which allow automatic algebraic manipulation techniques to be used to develop the series to high order. It is argued that the operator method can be justified by analytically continuing from the complex angular frequency plane onto the real line. The resulting picture is one where preserved primary KAM surfaces are continuously connected to one another.

  8. Intermolecular perturbation theory

    NASA Astrophysics Data System (ADS)

    Hayes, I. C.; Hurst, G. J. B.; Stone, A. J.

    The new intermolecular perturbation theory described in the preceding papers is applied to some van der Waals molecules. HeBe is used as a test case, and the perturbation method converges well at interatomic distances down to about 4 a0, giving results in excellent agreement with supermolecule calculations. ArHF and ArHCl have been studied using large basis sets, and the results agree well with experimental data. The ArHX configuration is favoured over the ArXH configuration mainly because of larger polarization and charge-transfer contributions. In NeH2 the equilibrium geometry is determined by a delicate balance between opposing effects; with a double-zeta-polarization basis the correct configuration is predicted.

  9. Aspects of perturbative unitarity

    NASA Astrophysics Data System (ADS)

    Anselmi, Damiano

    2016-07-01

    We reconsider perturbative unitarity in quantum field theory and upgrade several arguments and results. The minimum assumptions that lead to the largest time equation, the cutting equations and the unitarity equation are identified. Using this knowledge and a special gauge, we give a new, simpler proof of perturbative unitarity in gauge theories and generalize it to quantum gravity, in four and higher dimensions. The special gauge interpolates between the Feynman gauge and the Coulomb gauge without double poles. When the Coulomb limit is approached, the unphysical particles drop out of the cuts and the cutting equations are consistently projected onto the physical subspace. The proof does not extend to nonlocal quantum field theories of gauge fields and gravity, whose unitarity remains uncertain.

  10. Asymmetric synthesis using chiral-encoded metal.

    PubMed

    Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander

    2016-01-01

    The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity. PMID:27562028