Sample records for sub-cooled liquid oxygen

  1. Liquid Acquisition Device Testing with Sub-Cooled Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; McQuillen, John B.

    2008-01-01

    When transferring propellant in space, it is most efficient to transfer single phase liquid from a propellant tank to an engine. In earth s gravity field or under acceleration, propellant transfer is fairly simple. However, in low gravity, withdrawing single-phase fluid becomes a challenge. A variety of propellant management devices (PMD) are used to ensure single-phase flow. One type of PMD, a liquid acquisition device (LAD) takes advantage of capillary flow and surface tension to acquire liquid. Previous experimental test programs conducted at NASA have collected LAD data for a number of cryogenic fluids, including: liquid nitrogen (LN2), liquid oxygen (LOX), liquid hydrogen (LH2), and liquid methane (LCH4). The present work reports on additional testing with sub-cooled LOX as part of NASA s continuing cryogenic LAD development program. Test results extend the range of LOX fluid conditions examined, and provide insight into factors affecting predicting LAD bubble point pressures.

  2. Interfacial condensation induced by sub-cooled liquid jet

    NASA Astrophysics Data System (ADS)

    Rame, Enrique; Balasubramaniam, R.

    2016-11-01

    When a sub-cooled liquid jet impinges on the free surface between a liquid and its vapor, vapor will condense at a rate dependent on the sub-cooling, the jet strength and fluid properties. In 1966 and during the examination of a different type of condensation flow, Shekriladeze found an approximate result, valid at large condensation rates, that decouples the flow in the liquid phase from that of the vapor, without putting it in the context of a formal asymptotic approximation. In this talk we will develop an asymptotic approximation that contains Shekriladze's result, and extend the calculations to the case when a non-condensable gas is present in the vapor phase.

  3. Simplified thermochemistry of oxygen in lithium and sodium for liquid metal cooling systems

    NASA Technical Reports Server (NTRS)

    Tower, L. K.

    1972-01-01

    Plots of oxygen chemical potential against composition of lithium-oxygen solutions and sodium-oxygen solutions for a range of temperature were constructed. For each liquid metal two such plots were prepared. For one plot ideal solution behavior was assumed. For the other plot, existing solubility limit data for oxygen in the liquid metal were used to determine a first-order term for departure from ideality. The use of the plots in evaluating the oxygen gettering capability of refractory metals in liquid metal cooling systems is illustrated by a simple example involving lithium, oxygen, and hafnium.

  4. Regeneratively Cooled Liquid Oxygen/Methane Technology Development

    NASA Technical Reports Server (NTRS)

    Robinson, Joel W.; Greene, Christopher B.; Stout, Jeffrey

    2012-01-01

    The National Aeronautics & Space Administration (NASA) has identified Liquid Oxygen (LOX)/Liquid Methane (LCH4) as a potential propellant combination for future space vehicles based upon exploration studies. The technology is estimated to have higher performance and lower overall systems mass compared to existing hypergolic propulsion systems. NASA-Marshall Space Flight Center (MSFC) in concert with industry partner Pratt & Whitney Rocketdyne (PWR) utilized a Space Act Agreement to test an oxygen/methane engine system in the Summer of 2010. PWR provided a 5,500 lbf (24,465 N) LOX/LCH4 regenerative cycle engine to demonstrate advanced thrust chamber assembly hardware and to evaluate the performance characteristics of the system. The chamber designs offered alternatives to traditional regenerative engine designs with improvements in cost and/or performance. MSFC provided the test stand, consumables and test personnel. The hot fire testing explored the effective cooling of one of the thrust chamber designs along with determining the combustion efficiency with variations of pressure and mixture ratio. The paper will summarize the status of these efforts.

  5. Sub-cooled liquid nitrogen cryogenic system with neon turbo-refrigerator for HTS power equipment

    NASA Astrophysics Data System (ADS)

    Yoshida, S.; Hirai, H.; Nara, N.; Ozaki, S.; Hirokawa, M.; Eguchi, T.; Hayashi, H.; Iwakuma, M.; Shiohara, Y.

    2014-01-01

    We developed a prototype sub-cooled liquid nitrogen (LN) circulation system for HTS power equipment. The system consists of a neon turbo-Brayton refrigerator with a LN sub-cooler and LN circulation pump unit. The neon refrigerator has more than 2 kW cooling power at 65 K. The LN sub-cooler is a plate-fin type heat exchanger and is installed in a refrigerator cold box. In order to carry out the system performance tests, a dummy cryostat having an electric heater was set instead of a HTS power equipment. Sub-cooled LN is delivered into the sub-cooler by the LN circulation pump and cooled within it. After the sub-cooler, sub-cooled LN goes out from the cold box to the dummy cryostat, and comes back to the pump unit. The system can control an outlet sub-cooled LN temperature by adjusting refrigerator cooling power. The refrigerator cooling power is automatically controlled by the turbo-compressor rotational speed. In the performance tests, we increased an electric heater power from 200 W to 1300 W abruptly. We confirmed the temperature fluctuation was about ±1 K. We show the cryogenic system details and performance test results in this paper.

  6. Test program to provide confidence in liquid oxygen cooling of hydrocarbon fueled rocket thrust chambers

    NASA Technical Reports Server (NTRS)

    Armstrong, E. S.

    1986-01-01

    An experimental program has been planned at the NASA Lewis Research Center to build confidence in the feasibility of liquid oxygen cooling for hydrocarbon fueled rocket engines. Although liquid oxygen cooling has previously been incorporated in test hardware, more runtime is necessary to gain confidence in this concept. In the previous tests, small oxygen leaks developed at the throat of the thrust chamber and film cooled the hot-gas side of the chamber wall without resulting in catastrophic failure. However, more testing is necessary to demonstrate that a catastrophic failure would not occur if cracks developed further upstream between the injector and the throat, where the boundary layer has not been established. Since under normal conditions cracks are expected to form in the throat region of the thrust chamber, cracks must be initiated artificially in order to control their location. Several methods of crack initiation are discussed in this report. Four thrust chambers, three with cracks and one without, should be tested. The axial location of the cracks should be varied parametrically. Each chamber should be instrumented to determine the effects of the cracks, as well as the overall performance and durability of the chambers.

  7. Space Shuttle Upgrade Liquid Oxygen Tank Thermal Stratification

    NASA Technical Reports Server (NTRS)

    Tunc, Gokturk; Wagner, Howard; Bayazitoglu, Yildiz

    2001-01-01

    In 1997, NASA initiated a study of a liquid oxygen and ethanol orbital maneuvering and reaction control system for space shuttle upgrades as well as other reusable launch vehicle applications. The pressure-fed system uses sub-cooled liquid oxygen at 2413.2 KPa (350 psia) stored passively using insulation. Thermal stratification builds up while the space shuttle is docked at the international space station. The venting from the space shuttle's liquid oxygen tank is not desired during this 96-hr time period. Once the shuttle undocks from the space station there could be a pressure collapse in the liquid oxygen tank caused by fluid mixing due to the thruster fU"ings . The thermal stratification and resulting pressure rise in the tank were examined by a computational fluid dynamic model. Since the heat transfer from the pressurant gas to the liquid will result in a decrease in tank pressure the final pressure after the 96 hours will be significantly less when the tank is pressurized with ambient temperature helium. Therefore, using helium at ambient temperature to pressurize the tank is preferred to pressurizing the tank with helium at the liquid oxygen temperature. The higher helium temperature will also result in less mass of helium to pressurize the tank.

  8. Regeneratively Cooled Liquid Oxygen/Methane Technology Development Between NASA MSFC and PWR

    NASA Technical Reports Server (NTRS)

    Robinson, Joel W.; Greene, Christopher B.; Stout, Jeffrey B.

    2012-01-01

    The National Aeronautics & Space Administration (NASA) has identified Liquid Oxygen (LOX)/Liquid Methane (LCH4) as a potential propellant combination for future space vehicles based upon exploration studies. The technology is estimated to have higher performance and lower overall systems mass compared to existing hypergolic propulsion systems. NASA-Marshall Space Flight Center (MSFC) in concert with industry partner Pratt & Whitney Rocketdyne (PWR) utilized a Space Act Agreement to test an oxygen/methane engine system in the Summer of 2010. PWR provided a 5,500 lbf (24,465 N) LOX/LCH4 regenerative cycle engine to demonstrate advanced thrust chamber assembly hardware and to evaluate the performance characteristics of the system. The chamber designs offered alternatives to traditional regenerative engine designs with improvements in cost and/or performance. MSFC provided the test stand, consumables and test personnel. The hot fire testing explored the effective cooling of one of the thrust chamber designs along with determining the combustion efficiency with variations of pressure and mixture ratio. The paper will summarize the status of these efforts.

  9. Oxygen miscibility gap and spin glass formation in the pyrochlore Lu{sub 2}Mo{sub 2}O{sub 7}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Clark, L.; Ritter, C.; Harrison, A.

    2013-07-15

    Rare earth (R) molybdate pyrochlores, R{sub 2}Mo{sub 2}O{sub 7}, are of interest as frustrated magnets. Polycrystalline samples of Lu{sub 2}Mo{sub 2}O{sub 7−x} prepared at 1600 °C display a coexistence of cubic pyrochlore phases. Rietveld fits to powder neutron diffraction data and chemical analyses show that the miscibility gap is between a stoichiometric x=0 and an oxygen-deficient x≈0.4 phase. Lu{sub 2}Mo{sub 2}O{sub 7} behaves as a spin glass material, with a divergence of field cooled and zero field cooled DC magnetic susceptibilities at a spin freezing temperature T{sub f}=16 K, that varies with frequency in AC measurements following a Vogel–Fulcher law.more » Lu{sub 2}Mo{sub 2}O{sub 6.6} is more highly frustrated spin glass and has T{sub f}=20 K. - Graphical abstract: The cubic Lu{sub 2}Mo{sub 2}O{sub 7−x} system exhibits a miscibility gap between coexisting pyrochlore phases at 1600 °C. Neutron powder diffraction refinement and chemical analysis shows that the gap separates stoichiometric x=0 and oxygen-deficient x≈0.4 phases. Lu{sub 2}Mo{sub 2}O{sub 7−x} has a frustrated spin glass ground state that is sensitive to the oxygen content. - Highlights: • The cubic Lu{sub 2}Mo{sub 2}O{sub 7−x} system has a miscibility gap between coexisting pyrochlore phases at 1600 °C. • Neutron powder diffraction shows that the gap separates x=0 and oxygen-deficient x≈0.4 phases. • Lu{sub 2}Mo{sub 2}O{sub 7−x} has a frustrated spin glass ground state that is sensitive to the oxygen content.« less

  10. Subcooled Liquid Oxygen Cryostat for Magneto-Archimedes Particle Separation by Density

    NASA Astrophysics Data System (ADS)

    Hilton, D. K.; Celik, D.; Van Sciver, S. W.

    2008-03-01

    An instrument for the separation of particles by density (sorting) is being developed that uses the magneto-archimedes effect in liquid oxygen. With liquid oxygen strongly paramagnetic, the magneto-archimedes effect is an extension of diamagnetic levitation in the sense of increasing the effective buoyancy of a particle. The instrument will be able to separate ensembles of particles from 100 μm to 100 nm in size, and vertically map or mechanically deliver the separated particles. The instrument requires a column of liquid oxygen that is nearly isothermal, free of thermal convection, subcooled to prevent nucleate boiling, and supported against the strong magnetic field used. Thus, the unique cryostat design that meets these requirements is described in the present article. It consists in part of a column of liquid nitrogen below for cooling the liquid oxygen, with the liquid oxygen pressurized by helium gas to prevent nucleate boiling.

  11. Liquid-liquid reaction of hydrogen peroxide and sodium hypochlorite for the production of singlet oxygen in a centrifugal flow singlet oxygen generator

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cui Rongrong; Deng Liezheng; Shi Wenbo

    An attempt is made to produce gas-phase singlet oxygen O{sub 2}(a{sup 1{Delta}}{sub g}) in a liquid-liquid reaction between acidic hydrogen peroxide (AHP) and sodium hypochlorite (NaOCl). The attempt arises from the fact that basic hydrogen peroxide (BHP) has long been the prime source for producing singlet delta oxygen through its reaction with chlorine. However, BHP suffers from the defect of being unstable during storage. Exploratory experiments were performed in a centrifugal flow singlet oxygen generator (CF-SOG) with two streams of solutions, AHP and NaOCl, mixed in a slit nozzle and then injected into the arc-shaped concavity in the CF-SOG tomore » form a rotating liquid flow with a remarkable centrifugal force. With the help of this centrifugal force, the product of the O{sub 2}({sup 1{Delta}}) reaction was quickly separated from the liquid phase. The gas-phase O{sub 2}({sup 1{Delta}}) was detected via the spectrum of O{sub 2}({sup 1{Delta}}) cooperative dimolecular emission with a CCD spectrograph. Experimental results show that it is feasible to produce gas-phase O{sub 2}({sup 1{Delta}}) from the AHP + NaOCl reaction, and the stronger the acidity, the more efficient the O{sub 2}({sup 1{Delta}}) production. However, since in the AHP + NaOCl reaction, Cl{sub 2} unavoidably appears as a byproduct, its catalytic action on the decomposition of H{sub 2}O{sub 2} into ground-state O{sub 2} remains a major obstacle to utilising the AHP + NaOCl reaction in producing gas-phase O{sub 2}({sup 1{Delta}}). Qualitative interpretation shows that the AHP + NaOCl reaction is virtually the reaction of interaction of molecular H{sub 2}O{sub 2} with molecular HOCl, its mechanism being analogous to that of reaction of BHP with Cl{sub 2}, where HOOCl is the key intermediate. It is difficult to form the intermediate HOOCl via the H{sub 2}O{sub 2} + NaOCl reaction in a basic medium, thus gas-phase O{sub 2}({sup 1{Delta}}) cannot be obtained in appreciable quantities. (active

  12. Gauging Systems Monitor Cryogenic Liquids

    NASA Technical Reports Server (NTRS)

    2009-01-01

    Rocket fuel needs to stay cool - super cool, in fact. The ability to store gas propellants like liquid hydrogen and oxygen at cryogenic temperatures (below -243 F) is crucial for space missions in order to reduce their volumes and allow their storage in smaller (and therefore, less costly) tanks. The Agency has used these cryogenic fluids for vehicle propellants, reactants, and life support systems since 1962 with the Centaur upper stage rocket, which was powered with liquid oxygen and liquid hydrogen. During proposed long-duration missions, super-cooled fluids will also be used in space power systems, spaceports, and lunar habitation systems. In the next generation of launch vehicles, gaseous propellants will be cooled to and stored for extended periods at even colder temperatures than currently employed via a process called densification. Densification sub-cools liquids to temperatures even closer to absolute zero (-459 F), increasing the fluid s density and shrinking its volume beyond common cryogenics. Sub-cooling cryogenic liquid hydrogen, for instance, from 20 K (-423 F) to 15 K (-432.4 F) reduces its mass by 10 percent. These densified liquid gases can provide more cost savings from reduced payload volume. In order to benefit from this cost savings, the Agency is working with private industry to prevent evaporation, leakage, and other inadvertent loss of liquids and gases in payloads - requiring new cryogenic systems to prevent 98 percent (or more) of boil-off loss. Boil-off occurs when cryogenic or densified liquids evaporate, and is a concern during launch pad holds. Accurate sensing of propellants aboard space vehicles is also critical for proper engine shutdown and re-ignition after launch, and zero boil-off fuel systems are also in development for the Altair lunar lander.

  13. Liquid-Cooled Garment

    NASA Technical Reports Server (NTRS)

    1977-01-01

    A liquid-cooled bra, offshoot of Apollo moon suit technology, aids the cancer-detection technique known as infrared thermography. Water flowing through tubes in the bra cools the skin surface to improve resolution of thermograph image.

  14. Liquid cooled garments

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Liquid cooled garments employed in several applications in which severe heat is encountered are discussed. In particular, the use of the garments to replace air line cooling units in a variety of industrial processing situations is discussed.

  15. Multicompartment Liquid-Cooling/Warming Protective Garments

    NASA Technical Reports Server (NTRS)

    Koscheyev, Victor S.; Leon, Gloria R.; Dancisak, Michael J.

    2005-01-01

    Shortened, multicompartment liquid-cooling / warming garments (LCWGs) for protecting astronauts, firefighters, and others at risk of exposure to extremes of temperature are undergoing development. Unlike prior liquid-circulation thermal-protection suits that provide either cooling or warming but not both, an LCWG as envisioned would provide cooling at some body locations and/or heating at other locations, as needed: For example, sometimes there is a need to cool the body core and to heat the extremities simultaneously. An LCWG garment of the type to be developed is said to be shortened because the liquid-cooling and - heating zones would not cover the whole body and, instead, would cover reduced areas selected for maximum heating and cooling effectiveness. Physiological research is under way to provide a rational basis for selection of the liquid-cooling and -heating areas. In addition to enabling better (relative to prior liquid-circulation garments) balancing of heat among different body regions, the use of selective heating and cooling in zones would contribute to a reduction in the amount of energy needed to operate a thermal-protection suit.

  16. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOEpatents

    Jujasz, Albert J.; Burkhart, James A.; Greenberg, Ralph

    1988-01-01

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  17. Cooling of High Pressure Rocket Thrust Chambers with Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Price, H. G.

    1980-01-01

    An experimental program using hydrogen and oxygen as the propellants and supercritical liquid oxygen (LOX) as the coolant was conducted at 4.14 and 8.274 MN/square meters (600 and 1200 psia) chamber pressure. Data on the following are presented: the effect of LOX leaking into the combustion region through small cracks in the chamber wall; and verification of the supercritical oxygen heat transfer correlation developed from heated tube experiments; A total of four thrust chambers with throat diameters of 0.066 m were tested. Of these, three were cyclically tested to 4.14 MN/square meters (600 psia) chamber pressure until a crack developed. One had 23 additional hot cycles accumulated with no apparent metal burning or distress. The fourth chamber was operated at 8.274 MN/square meters (1200 psia) pressure to obtain steady state heat transfer data. Wall temperature measurements confirmed the heat transfer correlation.

  18. Liquid metal cooled nuclear reactors with passive cooling system

    DOEpatents

    Hunsbedt, Anstein; Fanning, Alan W.

    1991-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of cooling medium flow circuits which cooperate to remove and carry heat away from the fuel core upon loss of the normal cooling flow circuit to areas external thereto.

  19. Combustion Stability Characteristics of the Project Morpheus Liquid Oxygen/Liquid Methane Main Engine

    NASA Technical Reports Server (NTRS)

    Melcher, J. C.; Morehead, Robert L.

    2014-01-01

    The Project Morpheus liquid oxygen (LOX) / liquid methane rocket engines demonstrated acousticcoupled combustion instabilities during sea-level ground-based testing at the NASA Johnson Space Center (JSC) and Stennis Space Center (SSC). High-amplitude, 1T, 1R, 1T1R (and higher order) modes appear to be triggered by injector conditions. The instability occurred during the Morpheus-specific engine ignition/start sequence, and did demonstrate the capability to propagate into mainstage. However, the instability was never observed to initiate during mainstage, even at low power levels. The Morpheus main engine is a JSC-designed 5,000 lbf-thrust, 4:1 throttling, pressure-fed cryogenic engine using an impinging element injector design. Two different engine designs, named HD4 and HD5, and two different builds of the HD4 engine all demonstrated similar instability characteristics. Through the analysis of more than 200 hot fire tests on the Morpheus vehicle and SSC test stand, a relationship between ignition stability and injector/chamber pressure was developed. The instability has the distinct characteristic of initiating at high relative injection pressure drop (dP) at low chamber pressure (Pc); i.e., instabilities initiated at high dP/Pc at low Pc during the start sequence. The high dP/Pc during start results during the injector /chamber chill-in, and is enhanced by hydraulic flip in the injector orifice elements. Because of the fixed mixture ratio of the existing engine design (the main valves share a common actuator), it is not currently possible to determine if LOX or methane injector dP/Pc were individual contributors (i.e., LOX and methane dP/Pc typically trend in the same direction within a given test). The instability demonstrated initiation characteristic of starting at or shortly after methane injector chillin. Colder methane (e.g., sub-cooled) at the injector inlet prior to engine start was much more likely to result in an instability. A secondary effect of LOX

  20. Super-cooled liquid water topped sub-arctic clouds and precipitation - investigation based on combination of ground-based in-situ and remote-sensing observations

    NASA Astrophysics Data System (ADS)

    Hirsikko, Anne; Brus, David; O'Connor, Ewan J.; Filioglou, Maria; Komppula, Mika; Romakkaniemi, Sami

    2017-04-01

    In the high and mid latitudes super-cooled liquid water layers are frequently observed on top of clouds. These layers are difficult to forecast with numerical weather prediction models, even though, they have strong influence on atmospheric radiative properties, cloud microphysical properties, and subsequently, precipitation. This work investigates properties of super-cooled liquid water layer topped sub-arctic clouds and precipitation observed with ground-based in-situ (cloud probes) and remote-sensing (a cloud radar, Doppler and multi-wavelength lidars) instrumentation during two-month long Pallas Cloud Experiment (PaCE 2015) in autumn 2015. Analysis is based on standard Cloudnet scheme supplemented with new retrieval products of the specific clouds and their properties. Combination of two scales of observation provides new information on properties of clouds and precipitation in the sub-arctic Pallas region. Current status of results will be presented during the conference. The authors acknowledge financial support by the Academy of Finland (Centre of Excellence Programme, grant no 272041; and ICINA project, grant no 285068), the ACTRIS2 - European Union's Horizon 2020 research and innovation programme under grant agreement No 654109, the KONE foundation, and the EU FP7 project BACCHUS (grant no 603445).

  1. Liquid oxygen-compatible filament-winding matrix resin

    NASA Technical Reports Server (NTRS)

    Harrison, E. S.

    1973-01-01

    Polyurethanes derived from hydroxy terminated polyperfluoro propylene oxide prepolymers were evaluated as matrix resins for filament wound composites which would be exposed to liquid (and 100% gaseous) oxygen environments. A number of structural modifications were brought about by variations in prepolymer molecular weight, and alternative curing agents which allowed retention of the oxygen compatibility. Although satisfactory performance was achieved at sub-ambient temperatures, the derived composites suffered considerable property loss at ambient or slightly elevated temperatures. To attain overall effectiveness of the composite system, upgrading of the polymer thermomechanical properties must first be achieved.

  2. Liquid cooled counter flow turbine bucket

    DOEpatents

    Dakin, James T.

    1982-09-21

    Means and a method are provided whereby liquid coolant flows radially outward through coolant passages in a liquid cooled turbine bucket under the influence of centrifugal force while in contact with countercurrently flowing coolant vapor such that liquid is entrained in the flow of vapor resulting in an increase in the wetted cooling area of the individual passages.

  3. Thermal management of liquid direct cooled split disk laser

    NASA Astrophysics Data System (ADS)

    Yang, Huomu; Feng, Guoying; Zhou, Shouhuan

    2015-02-01

    The thermal effects of a liquid direct cooled split disk laser are modeled and analytically solved. The analytical solutions with the consideration of longitudinal cooling liquid temperature rise have been given to describe the temperature distribution in the split disk and cooling liquid based on the hydrodynamics and heat transfer. The influence of cooling liquid, liquid flowing velocity, thickness of cooling channel and of disk gain medium can also be got from the analytical solutions.

  4. Rockets using Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Busemann, Adolf

    1947-01-01

    It is my task to discuss rocket propulsion using liquid oxygen and my treatment must be highly condensed for the ideas and experiments pertaining to this classic type of rocket are so numerous that one could occupy a whole morning with a detailed presentation. First, with regard to oxygen itself as compared with competing oxygen carriers, it is known that the liquid state of oxygen, in spite of the low boiling point, is more advantageous than the gaseous form of oxygen in pressure tanks, therefore only liquid oxygen need be compared with the oxygen carriers. The advantages of liquid oxygen are absolute purity and unlimited availability at relatively small cost in energy. The disadvantages are those arising from the impossibility of absolute isolation from heat; consequently, allowance must always be made for a certain degree of vaporization and only vented vessels can be used for storage and transportation. This necessity alone eliminates many fields of application, for example, at the front lines. In addition, liquid oxygen has a lower specific weight than other oxygen carriers, therefore many accessories become relatively larger and heavier in the case of an oxygen rocket, for example, the supply tanks and the pumps. The advantages thus become effective only in those cases where definitely scheduled operation and a large ground organization are possible and when the flight requires a great concentration of energy relative to weight. With the aim of brevity, a diagram of an oxygen rocket will be presented and the problem of various component parts that receive particularly thorough investigation in this classic case but which are also often applicable to other rocket types will be referred to.

  5. NREL, LiquidCool Solutions Partner on Energy-Efficient Cooling for

    Science.gov Websites

    denser and generate more heat. Liquid cooling, including the LiquidCool Solutions technology, offers a more energy-efficient solution that also allows for effective reuse of the heat rejected by the water, depending on the coolant temperature and heat exchanger specifications. These water temperatures

  6. High-pressure calorimeter chamber tests for liquid oxygen/kerosene (LOX/RP-1) rocket combustion

    NASA Technical Reports Server (NTRS)

    Masters, Philip A.; Armstrong, Elizabeth S.; Price, Harold G.

    1988-01-01

    An experimental program was conducted to investigate the rocket combustion and heat transfer characteristics of liquid oxygen/kerosene (LOX/RP-1) mixtures at high chamber pressures. Two water-cooled calorimeter chambers of different combustion lengths were tested using 37- and 61-element oxidizer-fuel-oxidizer triplet injectors. The tests were conducted at nominal chamber pressures of 4.1, 8.3, and 13.8 MPa abs (600, 1200, and 2000 psia). Heat flux Q/A data were obtained for the entire calorimeter length for oxygen/fuel mixture ratios of 1.8 to 3.3. Test data at 4.1 MPa abs compared favorably with previous test data from another source. Using an injector with a fuel-rich outer zone reduced the throat heat flux by 47 percent with only a 4.5 percent reduction in the characteristic exhaust velocity efficiency C* sub eff. The throat heat transfer coefficient was reduced approximately 40 percent because of carbon deposits on the chamber wall.

  7. Liquid metal cooled nuclear reactor plant system

    DOEpatents

    Hunsbedt, Anstein; Boardman, Charles E.

    1993-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

  8. Improvement in elastic properties of CuAl{sub 0.4}Fe{sub 1.6}O{sub 4} spinel ferrite by rapid thermal cooling

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Modi, K. B., E-mail: kunalbmodi2003@yahoo.com; Shah, S. J., E-mail: kunalbmodi2003@yahoo.com; Pathak, T. K., E-mail: kunalbmodi2003@yahoo.com

    2014-04-24

    The elastic properties of spinel ferrite composition, CuAl{sub 0.4}Fe{sub 1.6}O{sub 4}, quenched from final sintering temperature of 1373 K to liquid nitrogen temperature (∼ 80K) have been studied by means of X-ray powder diffractometry and pulse echo-overlap technique (9 MHz) at 300 K. The magnitude of elastic constants is found to enhance by 15% compared to slowly-cooled counterpart. The observed mechanical strengthening has been discussed in the light of compressive stress on the surface, with tensile stresses at interior regions and corresponding changes in structural parameters. The B{sub o}/G{sub o} ratio indicates the brittle nature of CuAl{sub 0.4}Fe{sub 1.6}O{sub 4}.

  9. High-Performance Computing Data Center Warm-Water Liquid Cooling |

    Science.gov Websites

    Computational Science | NREL Warm-Water Liquid Cooling High-Performance Computing Data Center Warm-Water Liquid Cooling NREL's High-Performance Computing Data Center (HPC Data Center) is liquid water Liquid cooling technologies offer a more energy-efficient solution that also allows for effective

  10. Liquid Cooling Technology Increases Exercise Efficiency

    NASA Technical Reports Server (NTRS)

    2015-01-01

    To keep astronauts' airtight spacesuits from becoming hot and humid, Ames Research Center developed liquid cooling garments that were integrated into each suit's long underwear. Vasper Systems, in San Jose, California, is using the technology in its liquid-cooled compression cuffs, which help people exercise more efficiently by concentrating lactic acid in their muscles.

  11. An experimental investigation on liquid methane heat transfer enhancement through the use of longitudinal fins in cooling channels

    NASA Astrophysics Data System (ADS)

    Galvan, Manuel de Jesus

    In the past years, hydrocarbon fuels have been the focus of attention as the interest in developing reusable, high-performing liquid rocket engines has grown. Liquid methane (LCH4) has been of particular interest because of the cost, handling, and storage advantages that it presents when compared to currently used propellants. Deep space exploration requires thrusters that can operate reliably during long-duration missions. One of the challenges in the development of a reliable engine has been providing adequate combustion chamber cooling to prevent engine failure. Regenerative (regen) cooling has presented itself as an appealing option because it provides improved cooling and engine efficiency over other types of cooling, such as film or dump cooling. Due to limited availability of experimental sub-critical liquid methane cooling data for pressure-fed regen engine design, there has been an interest in studying the heat transfer characteristics of the propellant. For this reason, recent experimental studies at the Center for Space Exploration Technology Research (cSETR) at the University of Texas at El Paso (UTEP) have focused on investigating the heat transfer characteristics of sub-critical CH4 flowing through smooth sub-scale cooling channels. In addition to investigating smooth channels, the cSETR has conducted experiments to investigate the effects of internal longitudinal fins on the heat transfer of methane. To conduct the experiments, the cSETR developed a conduction-based thermal concentrator known as the High Heat Flux Test Facility (HHFTF) in which the channels are heated. In this study, a smooth channel and three channels with longitudinal fins all with cross sectional geometries of 3.2 mm x 3.2 mm were tested. The Nusselt numbers ranged from 70 and 510, and Reynolds numbers were between 50,000 and 128,000. Sub-cooled film-boiling phenomena were discovered in the data pertaining to the smooth and two finned channels. Sub-cooled film-boiling was not

  12. Liquid cooled approaches for high density avionics

    NASA Astrophysics Data System (ADS)

    Levasseur, Robert

    Next-generation aircraft will require avionics that provide greater system performance in a smaller volume, a process that requires highly developed thermal management techniques. To meet this need, a liquid-cooled approach has been developed to replace the conventional air-cooled approach for high-power applications. Liquid-cooled chassis and flow-through modules have been developed to limit junction temperatures to acceptable levels. Liquid cooling also permits emergency operation after loss of coolant for longer time intervals, which is desirable for flight-critical airborne applications. Activity to date has emphasized the development of chassis and modules that support the US Department of Defense's (DoD) two-level maintenance initiative as governed by the Joint Integrated Avionics Working Group (JIAWG).

  13. 114. WEST SIDE OF LIQUID OXYGEN CONTROL ROOM (205). LIQUID ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    114. WEST SIDE OF LIQUID OXYGEN CONTROL ROOM (205). LIQUID NITROGEN (LN2) SUBCOOLER ON LEFT; SKID 8, LIQUID OXYGEN CONTROLLER FOR SWITCHING BETWEEN RAPID-LOAD AND TOPPING ON RIGHT. LIQUID OXYGEN LINE FROM SKID 9A AT RIGHT EDGE OF PHOTO. - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 East, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  14. Specific cooling capacity of liquid nitrogen

    NASA Technical Reports Server (NTRS)

    Kilgore, R. A.; Adcock, J. B.

    1977-01-01

    The assumed cooling process and the method used to calculate the specific cooling capacity of liquid nitrogen are described, and the simple equation fitted to the calculated specific cooling capacity data, together with the graphical form calculated values of the specific cooling capacity of nitrogen for stagnation temperatures from saturation to 350 K and stagnation pressures from 1 to 10 atmospheres, are given.

  15. Liquid rocket engine fluid-cooled combustion chambers

    NASA Technical Reports Server (NTRS)

    1972-01-01

    A monograph on the design and development of fluid cooled combustion chambers for liquid propellant rocket engines is presented. The subjects discussed are (1) regenerative cooling, (2) transpiration cooling, (3) film cooling, (4) structural analysis, (5) chamber reinforcement, and (6) operational problems.

  16. Thermoelectric-enhanced, liquid-based cooling of a multi-component electronic system

    DOEpatents

    Chainer, Timothy J; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Steinke, Mark E

    2015-11-10

    Methods are provided for facilitating cooling of an electronic component. The methods include providing: a liquid-cooled structure, a thermal conduction path coupling the electronic component and the liquid-cooled structure, a coolant loop in fluid communication with a coolant-carrying channel of the liquid-cooled structure, and an outdoor-air-cooled heat exchange unit coupled to facilitate heat transfer from the liquid-cooled structure via, at least in part, the coolant loop. The thermoelectric array facilitates transfer of heat from the electronic component to the liquid-cooled structure, and the heat exchange unit cools coolant passing through the coolant loop by dissipating heat from the coolant to outdoor ambient air. In one implementation, temperature of coolant entering the liquid-cooled structure is greater than temperature of the outdoor ambient air to which heat is dissipated.

  17. Thermoelectric-enhanced, liquid-based cooling of a multi-component electronic system

    DOEpatents

    Chainer, Timothy J; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Steinke, Mark E

    2015-05-12

    Apparatus and method are provided for facilitating cooling of an electronic component. The apparatus includes a liquid-cooled structure, a thermal conduction path coupling the electronic component and the liquid-cooled structure, a coolant loop in fluid communication with a coolant-carrying channel of the liquid-cooled structure, and an outdoor-air-cooled heat exchange unit coupled to facilitate heat transfer from the liquid-cooled structure via, at least in part, the coolant loop. The thermoelectric array facilitates transfer of heat from the electronic component to the liquid-cooled structure, and the heat exchange unit cools coolant passing through the coolant loop by dissipating heat from the coolant to outdoor ambient air. In one implementation, temperature of coolant entering the liquid-cooled structure is greater than temperature of the outdoor ambient air to which heat is dissipated.

  18. Liquid cooling of aircraft engines

    NASA Technical Reports Server (NTRS)

    Weidinger, Hanns

    1931-01-01

    This report presents a method for solving the problem of liquid cooling at high temperatures, which is an intermediate method between water and air cooling, by experiments on a test-stand and on an airplane. A utilizable cooling medium was found in ethylene glycol, which has only one disadvantage, namely, that of combustibility. The danger, however is very slight. It has one decided advantage, that it simultaneously serves as protection against freezing.

  19. An experimental investigation of liquid methane convection and boiling in rocket engine cooling channels

    NASA Astrophysics Data System (ADS)

    Trujillo, Abraham Gerardo

    In the past decades, interest in developing hydrocarbon-fueled rocket engines for deep spaceflight missions has continued to grow. In particular, liquid methane (LCH4) has been of interest due to the weight efficiency, storage, and handling advantages it offers over several currently used propellants. Deep space exploration requires reusable, long life rocket engines. Due to the high temperatures reached during combustion, the life of an engine is significantly impacted by the cooling system's efficiency. Regenerative (regen) cooling is presented as a viable alternative to common cooling methods such as film and dump cooling since it provides improved engine efficiency. Due to limited availability of experimental sub-critical liquid methane cooling data for regen engine design, there has been an interest in studying the heat transfer characteristics of the propellant. For this reason, recent experimental studies at the Center for Space Exploration Technology Research (cSETR) at the University of Texas at El Paso (UTEP) have focused on investigating the heat transfer characteristics of sub-critical CH4 flowing through sub-scale cooling channels. To conduct the experiments, the csETR developed a High Heat Flux Test Facility (HHFTF) where all the channels are heated using a conduction-based thermal concentrator. In this study, two smooth channels with cross sectional geometries of 1.8 mm x 4.1 mm and 3.2 mm x 3.2 mm were tested. In addition, three roughened channels all with a 3.2 mm x 3.2 mm square cross section were also tested. For the rectangular smooth channel, Reynolds numbers ranged between 68,000 and 131,000, while the Nusselt numbers were between 40 and 325. For the rough channels, Reynolds numbers ranged from 82,000 to 131,000, and Nusselt numbers were between 65 and 810. Sub-cooled film-boiling phenomena were confirmed for all the channels presented in this work. Film-boiling onset at Critical Heat Flux (CHF) was correlated to a Boiling Number (Bo) of

  20. Effects of irradiation distance on supply of reactive oxygen species to the bottom of a Petri dish filled with liquid by an atmospheric O{sub 2}/He plasma jet

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kawasaki, Toshiyuki, E-mail: kawasaki@nbu.ac.jp; Kusumegi, Shota; Kudo, Akihiro

    The impact of irradiation distances on plasma jet-induced specific effects on the supply of reactive oxygen species (ROS) to the bottom of a Petri dish filled with liquid was investigated using a KI-starch gel reagent that can be employed as a ROS indicator even in water. O{sub 3} exposure experiments without plasma irradiation were also performed to elucidate the specific effects of the plasma jet. Relative concentrations of ROS transported to the bottom were evaluated using absorbance measurements. The results indicated that ROS supply to the bottom is markedly enhanced by the plasma jet irradiation at shorter irradiation distances, whereasmore » similar results could not be obtained for the O{sub 3} exposure. In these cases, the liquid mixing in the depth direction was also enhanced by the plasma jet irradiation only, and the supply of reactive atomic oxygen to the liquid surface was markedly increased as well.« less

  1. Passive cooling system for top entry liquid metal cooled nuclear reactors

    DOEpatents

    Boardman, Charles E.; Hunsbedt, Anstein; Hui, Marvin M.

    1992-01-01

    A liquid metal cooled nuclear fission reactor plant having a top entry loop joined satellite assembly with a passive auxiliary safety cooling system for removing residual heat resulting from fuel decay during shutdown, or heat produced during a mishap. This satellite type reactor plant is enhanced by a backup or secondary passive safety cooling system which augments the primary passive auxiliary cooling system when in operation, and replaces the primary cooling system when rendered inoperative.

  2. Oxygen-storage behavior and local structure in Ti-substituted YMnO{sub 3}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Levin, I., E-mail: igor.levin@nist.gov; Krayzman, V.; Vanderah, T.A.

    Hexagonal manganates RMnO{sub 3} (R=Y, Ho, Dy) have been recently shown to exhibit oxygen-storage capacities promising for three-way catalysts, air-separation, and related technologies. Here, we demonstrate that Ti substitution for Mn can be used to chemically tune the oxygen-breathing properties of these materials towards practical applications. Specifically, Y(Mn{sub 1−x}Ti{sub x})O{sub 3} solid solutions exhibit facile oxygen absorption/desorption via reversible Ti{sup 3+}↔Ti{sup 4+} and Mn{sup 3+}↔Mn{sup 4+} reactions already in ambient air at ≈400 °C and ≈250 °C, respectively. On cooling, the oxidation of both cations is accompanied by oxygen uptake yielding a formula YMn{sup 3+}{sub 1−x-y}Mn{sup 4+}{sub y}Ti{sup 4+}{sub x}O{submore » 3+δ}. The presence of Ti promotes the oxidation of Mn{sup 3+} to Mn{sup 4+}, which is almost negligible for YMnO{sub 3} in air, thereby increasing the uptake of oxygen beyond that required for a given Ti{sup 4+} concentration. The reversibility of the redox reactions is limited by sluggish kinetics; however, the oxidation process continues, if slowly, even at room temperature. The extra oxygen atoms are accommodated by the large interstices within a triangular lattice formed by the [MnO{sub 5}] trigonal bipyramids. According to bond distances from Rietveld refinements using the neutron diffraction data, the YMnO{sub 3} structure features under-bonded Mn and even more severely under-bonded oxygen atoms that form the trigonal bases of the [MnO{sub 5}] bipyramids. The tensile bond strain around the 5-fold coordinated Mn site and the strong preference of Ti{sup 4+}(and Mn{sup 4+}) for higher coordination numbers likely provide driving forces for the oxidation reaction. Reverse Monte Carlo refinements of the local atomic displacements using neutron total scattering revealed how the excess oxygen atoms are accommodated in the structure by correlated local displacements of the host atoms. Large displacements of the

  3. Liquid cooling applications on automotive exterior LED lighting

    NASA Astrophysics Data System (ADS)

    Aktaş, Mehmet; Şenyüz, Tunç; Şenyıldız, Teoman; Kılıç, Muhsin

    2018-02-01

    In this study cooling of a LED unit with heatsink and liquid cooling block which is used in automotive head lamp applications has been investigated numerically and experimentally. Junction temperature of a LED which is cooled with heatsink and liquid cooling block obtained in the experiment. 23°C is used both in the simulation and the experiment phase. Liquid cooling block material is choosed aluminium (Al) and polyamide. All tests and simulation are performed with three different flow rate. Temperature distribution of the designed product is investigated by doing the numerical simulations with a commercially software. In the simulations, fluid flow is assumed to be steady, incompressible and laminar and 3 dimensional (3D) Navier-Stokes equations are used. According to the calculations it is obtained that junction temperature is higher in the heatsink design compared to block cooled one. By changing the block material, it is desired to investigate the variation on the LED junction temperature. It is found that more efficient cooling can be obtained in block cooling by using less volume and weight. With block cooling lifetime of LED can be increased and flux loss can be decreased with the result of decreased junction temperature.

  4. LIQUID METAL REACTOR COOLING SYSTEMS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aberdam, M.; Gros, G.

    1965-02-01

    This report is part of a series of bibliographies. The specific purpose of this report is to describe the various elements of the cooling systems in the principal liquid-metal-cooled reactors now operating, being contsructed, or in the design stage. The information given is drawn from reports or publicatios received during or before September 1964.

  5. 21 CFR 868.5655 - Portable liquid oxygen unit.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Portable liquid oxygen unit. 868.5655 Section 868...) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5655 Portable liquid oxygen unit. (a) Identification. A portable liquid oxygen unit is a portable, thermally insulated container of liquid oxygen that...

  6. 21 CFR 868.5655 - Portable liquid oxygen unit.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Portable liquid oxygen unit. 868.5655 Section 868...) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5655 Portable liquid oxygen unit. (a) Identification. A portable liquid oxygen unit is a portable, thermally insulated container of liquid oxygen that...

  7. 21 CFR 868.5655 - Portable liquid oxygen unit.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Portable liquid oxygen unit. 868.5655 Section 868...) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5655 Portable liquid oxygen unit. (a) Identification. A portable liquid oxygen unit is a portable, thermally insulated container of liquid oxygen that...

  8. 21 CFR 868.5655 - Portable liquid oxygen unit.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Portable liquid oxygen unit. 868.5655 Section 868...) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5655 Portable liquid oxygen unit. (a) Identification. A portable liquid oxygen unit is a portable, thermally insulated container of liquid oxygen that...

  9. 21 CFR 868.5655 - Portable liquid oxygen unit.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Portable liquid oxygen unit. 868.5655 Section 868...) MEDICAL DEVICES ANESTHESIOLOGY DEVICES Therapeutic Devices § 868.5655 Portable liquid oxygen unit. (a) Identification. A portable liquid oxygen unit is a portable, thermally insulated container of liquid oxygen that...

  10. Liquid Oxygen/Liquid Methane Component Technology Development at MSFC

    NASA Technical Reports Server (NTRS)

    Robinson, Joel W.

    2010-01-01

    The National Aeronautics & Space Administration (NASA) has identified Liquid Oxygen (LOX)/Liquid Methane (LCH4) as a potential propellant combination for future space vehicles based upon exploration studies. The technology is estimated to have higher performance and lower overall systems mass compared to existing hypergolic propulsion systems. Besides existing in-house risk reduction activities, NASA has solicited from industry their participation on component technologies based on the potential application to the lunar ascent main engine (AME). Contracted and NASA efforts have ranged from valve technologies to engine system testbeds. The application for the AME is anticipated to be an expendable, pressure-fed engine for ascent from the moon at completion of its lunar stay. Additionally, the hardware is expected to provide an abort capability prior to landing, in the event that descent systems malfunction. For the past 4 years, MSFC has been working with the Glenn Research Center and the Johnson Space Center on methane technology development. This paper will focus on efforts specific to MSFC in pursuing ignition, injector performance, chamber material assessments and cryogenic valve technologies. Ignition studies have examined characteristics for torch, spark and microwave systems. Injector testing has yielded insight into combustion performance for shear, swirl and impinging type injectors. The majority of chamber testing has been conducted with ablative and radiatively cooled chambers with planned activities for regenerative and transpiration cooled chambers. Lastly, an effort is underway to examine the long duration exposure issues of cryogenic valve internal components. The paper will summarize the status of these efforts.

  11. Wing-Nacelle-Propeller Tests - Comparative Tests of Liquid-Cooled and Air-Cooled Engine Nacelles

    NASA Technical Reports Server (NTRS)

    Wood, Donald H.

    1934-01-01

    This report gives the results of measurements of the lift, drag, and propeller characteristics of several wing and nacelle combinations with a tractor propeller. The nacelles were so located that the propeller was about 31% of the wing chord directly ahead of the leading edge of the wing, a position which earlier tests (NASA Report No. 415) had shown to be efficient. The nacelles were scale models of an NACA cowled nacelle for a radial air-cooled engine, a circular nacelle with the V-type engine located inside and the radiator for the cooling liquid located inside and the radiator for the type, and a nacelle shape simulating the housing which would be used for an extension shaft if the engine were located entirely within the wing. The propeller used in all cases was a 4-foot model of Navy No. 4412 adjustable metal propeller. The results of the tests indicate that, at the angles of attack corresponding to high speeds of flight, there is no marked advantage of one type of nacelle over the others as far as low drag is concerned, since the drag added by any of the nacelles in the particular location ahead of the wing is very small. The completely cowled nacelle for a radial air-cooled engine appears to have the highest drag, the liquid-cooled engine appears to have the highest drag, the liquid-cooled engine nacelle with external radiator slightly less drag. The liquid-cooled engine nacelle with radiator in the cowling hood has about half the drag of the cowled radial air-cooled engine nacelle. The extension-shaft housing shows practically no increase in drag over that of the wing alone. A large part of the drag of the liquid-cooled engine nacelle appears to be due to the external radiator. The maximum propulsive efficiency for a given propeller pitch setting is about 2% higher for the liquid-cooled engine nacelle with the radiator in the cowling hood than that for the other cowling arrangements.

  12. Passive cooling safety system for liquid metal cooled nuclear reactors

    DOEpatents

    Hunsbedt, Anstein; Boardman, Charles E.; Hui, Marvin M.; Berglund, Robert C.

    1991-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of partitions surrounding the reactor vessel in spaced apart relation forming intermediate areas for circulating heat transferring fluid which remove and carry away heat from the reactor vessel. The passive cooling system includes a closed primary fluid circuit through the partitions surrounding the reactor vessel and a partially adjoining secondary open fluid circuit for carrying transferred heat out into the atmosphere.

  13. Indirect passive cooling system for liquid metal cooled nuclear reactors

    DOEpatents

    Hunsbedt, Anstein; Boardman, Charles E.

    1990-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of partitions surrounding the reactor vessel in spaced apart relation forming intermediate areas for circulating heat transferring fluid which remove and carry away heat from the reactor vessel. The passive cooling system includes a closed primary fluid circuit through the partitions surrounding the reactor vessel and a partially adjoining secondary open fluid circuit for carrying transferred heat out into the atmosphere.

  14. Superconducting cable cooling system by helium gas and a mixture of gas and liquid helium

    DOEpatents

    Dean, John W.

    1977-01-01

    Thermally contacting, oppositely streaming cryogenic fluid streams in the same enclosure in a closed cycle that changes from a cool high pressure helium gas to a cooler reduced pressure helium fluid comprised of a mixture of gas and boiling liquid so as to be near the same temperature but at different pressures respectively in go and return legs that are in thermal contact with each other and in thermal contact with a longitudinally extending superconducting transmission line enclosed in the same cable enclosure that insulates the line from the ambient at a temperature T.sub.1. By first circulating the fluid in a go leg from a refrigerator at one end of the line as a high pressure helium gas near the normal boiling temperature of helium; then circulating the gas through an expander at the other end of the line where the gas becomes a mixture of reduced pressure gas and boiling liquid at its boiling temperature; then by circulating the mixture in a return leg that is separated from but in thermal contact with the gas in the go leg and in the same enclosure therewith; and finally returning the resulting low pressure gas to the refrigerator for compression into a high pressure gas at T.sub.2 is a closed cycle, where T.sub.1 >T.sub.2, the temperature distribution is such that the line temperature is nearly constant along its length from the refrigerator to the expander due to the boiling of the liquid in the mixture. A heat exchanger between the go and return lines removes the gas from the liquid in the return leg while cooling the go leg.

  15. Liquid rocket engine self-cooled combustion chambers

    NASA Technical Reports Server (NTRS)

    1977-01-01

    Self-cooled combustion chambers are chambers in which the chamber wall temperature is controlled by methods other than fluid flow within the chamber wall supplied from an external source. In such chambers, adiabatic wall temperature may be controlled by use of upstream fluid components such as the injector or a film-coolant ring, or by internal flow of self-contained materials; e.g. pyrolysis gas flow in charring ablators, and the flow of infiltrated liquid metals in porous matrices. Five types of self-cooled chambers are considered in this monograph. The name identifying the chamber is indicative of the method (mechanism) by which the chamber is cooled, as follows: ablative; radiation cooled; internally regenerative (Interegen); heat sink; adiabatic wall. Except for the Interegen and heat sink concepts, each chamber type is discussed separately. A separate and final section of the monograph deals with heat transfer to the chamber wall and treats Stanton number evaluation, film cooling, and film-coolant injection techniques, since these subjects are common to all chamber types. Techniques for analysis of gas film cooling and liquid film cooling are presented.

  16. Pressure-induced structural change in liquid GeI<sub>4sub>.

    PubMed

    Fuchizaki, Kazuhiro; Nishimura, Hironori; Hase, Takaki; Saitoh, Hiroyuki

    2017-12-13

    The similarity in the shape of the melting curve of GeI<sub>4</sub> to that of SnI<sub>4</sub> suggests that a liquid-liquid transition as observed in liquid SnI<sub>4</sub> is also expected to occur in liquid GeI<sub>4</sub>. Because the slope of the melting curve of GeI<sub>4</sub> abruptly changes at around 3 GPa, in situ synchrotron diffraction measurements were conducted to examine closely the structural changes upon compression at around 3 GPa. The reduced radial distribution functions of the high- and low-pressure liquid states of GeI<sub>4</sub> share the same feature inherent in the high-pressure (high-density) and low-pressure (low-density) radial distribution functions of liquid SnI<sub>4</sub>. This feature allows us to introduce local order parameters that we may use to observe the transition. Unlike the transition in liquid SnI<sub>4</sub>, the transition from the low-pressure to the high-pressure structure seems sluggish. We speculate that the liquid-liquid critical point of GeI<sub>4</sub> is no longer a thermodynamically stable state and is slightly located below the melting curve. As a result, the structural change is said to be a crossover rather than a transition. The behavior of the local-order parameters implies a metastable extension of the liquid-liquid phase boundary with a negative slope. . © 2017 IOP Publishing Ltd.

  17. Frozen-Plug Technique for Liquid-Oxygen Plumbing

    NASA Technical Reports Server (NTRS)

    McCaskey, C. E. " Mac" ; Lobmeyer, Dennis; Nagy, Zoltan; Peltzer, Rich

    2005-01-01

    A frozen-plug technique has been conceived as a means of temporarily blocking the flow of liquid oxygen or its vapor through a tube or pipe. The technique makes it possible to perform maintenance, repair, or other work on downstream parts of the cryogenic system in which the oxygen is used, without having to empty an upstream liquid-oxygen reservoir and, hence, without wasting the stored liquid oxygen and without subjecting the reservoir to the stresses of thermal cycling.

  18. Simulation and experiment for oxygen-enriched combustion engine using liquid oxygen to solidify CO2

    NASA Astrophysics Data System (ADS)

    Liu, Yongfeng; Jia, Xiaoshe; Pei, Pucheng; Lu, Yong; Yi, Li; Shi, Yan

    2016-01-01

    For capturing and recycling of CO2 in the internal combustion engine, Rankle cycle engine can reduce the exhaust pollutants effectively under the condition of ensuring the engine thermal efficiency by using the techniques of spraying water in the cylinder and optimizing the ignition advance angle. However, due to the water spray nozzle need to be installed on the cylinder, which increases the cylinder head design difficulty and makes the combustion conditions become more complicated. In this paper, a new method is presented to carry out the closing inlet and exhaust system for internal combustion engines. The proposed new method uses liquid oxygen to solidify part of cooled CO2 from exhaust system into dry ice and the liquid oxygen turns into gas oxygen which is sent to inlet system. The other part of CO2 is sent to inlet system and mixed with oxygen, which can reduce the oxygen-enriched combustion detonation tendency and make combustion stable. Computing grid of the IP52FMI single-cylinder four-stroke gasoline-engine is established according to the actual shape of the combustion chamber using KIVA-3V program. The effects of exhaust gas recirculation (EGR) rate are analyzed on the temperatures, the pressures and the instantaneous heat release rates when the EGR rate is more than 8%. The possibility of enclosing intake and exhaust system for engine is verified. The carbon dioxide trapping device is designed and the IP52FMI engine is transformed and the CO2 capture experiment is carried out. The experimental results show that when the EGR rate is 36% for the optimum EGR rate. When the liquid oxygen of 35.80-437.40 g is imported into the device and last 1-20 min, respectively, 21.50-701.30 g dry ice is obtained. This research proposes a new design method which can capture CO2 for vehicular internal combustion engine.

  19. Low NO[sub x], cogeneration process and system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bell, R.D.

    1993-07-06

    A process is described for low NO[sub x] cogeneration to produce electricity and useful heat, which comprises: providing fuel and oxygen to an internal combustion engine connected to drive an electric generator, to thereby generate electricity; recovering from said engine an exhaust stream including elevated NO[sub x] levels and combined oxygen; adding to said exhaust stream sufficient fuel to create a fuel-rich mixture, the quantity of fuel being sufficient to react with the available oxygen and reduce the NO[sub x], in said exhaust stream; providing said fuel-enriched exhaust stream to a thermal reactor and reacting therein said fuel, NO[sub x]more » and available oxygen, to provide a heated oxygen-depleted stream; cooling said oxygen-depleted stream by passing same through a first heat exchanger; adding conversion oxygen to said cooled stream from said heat exchanger, and passing the cooled oxygen-augmented stream over a first catalyst bed operated at a temperature of about 750 to 1,250 F under overall reducing conditions, the quantity of conversion oxygen added being in stoichiometric excess of the amount of NO[sub x], but less than the amount of combustibles; whereby the NO[sub x] is first oxidized to NO[sub 2], and then the NO[sub 2] is reduced by the excess combustibles; cooling said stream from said first catalyst bed to a temperature of about 450 to 650 F by passing said stream through a second heat exchanger; adding air to the resulting cooled stream to produce a further cooled stream at a temperature of about 400 to 600 F, and having a stoichiometric excess of oxygen; and passing said stream having said stoichiometric excess of oxygen over an oxidizing catalyst bed at said temperature of 400 to 600 F to oxidize remaining excess combustibles, to thereby provide an effluent stream having environmentally safe characteristics.« less

  20. Method for passive cooling liquid metal cooled nuclear reactors, and system thereof

    DOEpatents

    Hunsbedt, Anstein; Busboom, Herbert J.

    1991-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of partitions surrounding the reactor vessel in spaced apart relation forming intermediate areas for circulating heat transferring fluid which remove and carry away heat from the reactor vessel.

  1. Lightweight Thermal Insulation for a Liquid-Oxygen Tank

    NASA Technical Reports Server (NTRS)

    Willen, G. Scott; Lock, Jennifer; Nieczkoski, Steve

    2005-01-01

    A proposed lightweight, reusable thermal-insulation blanket has been designed for application to a tank containing liquid oxygen, in place of a non-reusable spray-on insulating foam. The blanket would be of the multilayer-insulation (MLI) type and equipped with a pressure-regulated nitrogen purge system. The blanket would contain 16 layers in two 8-layer sub-blankets. Double-aluminized polyimide 0.3 mil (.0.008 mm) thick was selected as a reflective shield material because of its compatibility with oxygen and its ability to withstand ionizing radiation and high temperature. The inner and outer sub-blanket layers, 1 mil (approximately equals 0.025 mm) and 3 mils (approximately equals 0.076 mm) thick, respectively, would be made of the double-aluminized polyimide reinforced with aramid. The inner and outer layers would provide structural support for the more fragile layers between them and would bear the insulation-to-tank attachment loads. The layers would be spaced apart by lightweight, low-thermal-conductance netting made from polyethylene terephthalate.

  2. Fractional Consumption of Liquid Hydrogen and Liquid Oxygen During the Space Shuttle Program

    NASA Technical Reports Server (NTRS)

    Partridge, Jonathan K.

    2011-01-01

    The Space Shuttle uses the propellants, liquid hydrogen and liquid oxygen, to meet part of the propulsion requirements from ground to orbit. The Kennedy Space Center procured over 25 million kilograms of liquid hydrogen and over 250 million kilograms of liquid oxygen during the 3D-year Space Shuttle Program. Because of the cryogenic nature of the propellants, approximately 55% of the total purchased liquid hydrogen and 30% of the total purchased liquid oxygen were used in the Space Shuttle Main Engines. The balance of the propellants were vaporized during operations for various purposes. This paper dissects the total consumption of liqUid hydrogen and liqUid oxygen and determines the fraction attributable to each of the various processing and launch operations that occurred during the entire Space Shuttle Program at the Kennedy Space Center.

  3. Floating Loop System For Cooling Integrated Motors And Inverters Using Hot Liquid Refrigerant

    DOEpatents

    Hsu, John S [Oak Ridge, TN; Ayers, Curtis W [Kingston, TN; Coomer, Chester [Knoxville, TN; Marlino, Laura D [Oak Ridge, TN

    2006-02-07

    A floating loop vehicle component cooling and air-conditioning system having at least one compressor for compressing cool vapor refrigerant into hot vapor refrigerant; at least one condenser for condensing the hot vapor refrigerant into hot liquid refrigerant by exchanging heat with outdoor air; at least one floating loop component cooling device for evaporating the hot liquid refrigerant into hot vapor refrigerant; at least one expansion device for expanding the hot liquid refrigerant into cool liquid refrigerant; at least one air conditioning evaporator for evaporating the cool liquid refrigerant into cool vapor refrigerant by exchanging heat with indoor air; and piping for interconnecting components of the cooling and air conditioning system.

  4. Control Algorithms For Liquid-Cooled Garments

    NASA Technical Reports Server (NTRS)

    Drew, B.; Harner, K.; Hodgson, E.; Homa, J.; Jennings, D.; Yanosy, J.

    1988-01-01

    Three algorithms developed for control of cooling in protective garments. Metabolic rate inferred from temperatures of cooling liquid outlet and inlet, suitably filtered to account for thermal lag of human body. Temperature at inlet adjusted to value giving maximum comfort at inferred metabolic rate. Applicable to space suits, used for automatic control of cooling in suits worn by workers in radioactive, polluted, or otherwise hazardous environments. More effective than manual control, subject to frequent, overcompensated adjustments as level of activity varies.

  5. Review and status of liquid-cooling technology for gas turbines

    NASA Technical Reports Server (NTRS)

    Vanfossen, G. J., Jr.; Stepka, F. S.

    1979-01-01

    A review was conducted of liquid-cooled turbine technology. Selected liquid-cooled systems and methods are presented along with an assessment of the current technology status and requirements. A comprehensive bibliography is presented.

  6. NREL Evaluates Aquarius Liquid-Cooled High-Performance Computing Technology

    Science.gov Websites

    HPC and influence the modern data center designer towards adoption of liquid cooling. Our shared technology. Aquila and Sandia chose NREL's HPC Data Center for the initial installation and evaluation because the data center is configured for liquid cooling, along with the required instrumentation to

  7. Gaseous oxygen cooling of the Space Transportation System launch pad environment

    NASA Astrophysics Data System (ADS)

    Ahmad, R. A.; Mathias, E. C.; Boraas, S.

    1991-12-01

    The external tank (ET) of the Space Transportation System (STS) contains liquid oxygen and hydrogen as oxidizer and fuel for the Space Shuttle main engines (SSMEs). During and subsequent to the loading of the ET prior to the launch of an STS, the cryogens boil in the near atmospheric conditions existing within their respective tanks. The gaseous oxygen (GOX) formed as a result of this boiling is vented overboard, mixes with air, and may, under certain wind conditions, be transported toward the STS to cause a cooling of its environment. This paper describes a two-dimensional computational fliud dynamics analysis to determine the magnitude of this cooling effect by determining the temperature depression and stratification caused by this GOX/air mixture in the region around the east redesigned solid rocket motor (RSRM), the ET, and below the STS assembly. For a severe wintertime launch temperature of -4.44 C, the maximum local temperature depression of the mixture was calculated to be 32.22 C in the inboard region next to the ET surface, and a surface temperature on the east RSRM was found to be as much as 13.89 C colder than ambient. The computed average surface temperatures on either side of the RSRM were in excellent agreement with a temperature determined from a correlation of prelaunch temperature measurements.

  8. High Resolution Spectroscopy and Dynamics: from Jet Cooled Radicals to Gas-Liquid Interfaces

    NASA Astrophysics Data System (ADS)

    Sharp-Williams, E.; Roberts, M. A.; Roscioli, J. R.; Gisler, A. W.; Ziemkiewicz, M.; Nesbitt, D. J.; Dong, F.; Perkins, B. G., Jr.

    2010-06-01

    This talk will attempt to reflect recent work in our group involving two quite different but complementary applications of high resolution molecular spectroscopy for detailed study of intramolecular as well as intermolecular dynamics in small molecules. The first is based on direct infrared absorption spectroscopy in a 100 KHz slit supersonic discharge, which provides a remarkably versatile and yet highly sensitive probe for study of important chemical transients such as open shell combustion species and molecular ions under jet cooled (10-20K), sub-Doppler conditions. For this talk will focus on gas phase spectroscopic results for a series of unsaturated hydrocarbon radical species (ethynyl, vinyl, and phenyl) reputed to be critical intermediates in soot formation. Secondly, we will discuss recent applications of high resolution IR and velocity map imaging spectroscopy toward quantum state resolved collision dynamics of jet cooled molecules from gas-room temperature ionic liquid (RTIL) and gas-self assembled monolayer (SAM) interfaces. Time permitting, we will also present new results on hyperthermal scattering of jet cooled NO radical from liquid Ga, which offer a novel window into non-adiabatic energy transfer and electron-hole pair dynamics at the gas-molten metal interface.

  9. Liquid-cooling technology for gas turbines review and status

    NASA Technical Reports Server (NTRS)

    Vanfossen, G. J., Jr.; Stepka, F. S.

    1978-01-01

    A review of research related to liquid cooling of gas turbines was conducted and an assessment of the state of the art was made. Various methods of liquid cooling turbines were reviewed. Examples and results with test and demonstrator turbines utilizing these methods along with the advantages and disadvantages of the various methods are discussed.

  10. Method and apparatus of cryogenic cooling for high temperature superconductor devices

    DOEpatents

    Yuan, Xing; Mine, Susumu

    2005-02-15

    A method and apparatus for providing cryogenic cooling to HTS devices, in particular those that are used in high-voltage electric power applications. The method involves pressurizing liquid cryogen to above one atmospheric pressure to improve its dielectric strength, while sub-cooling the liquid cryogen to below its saturation temperature in order to improve the performance of the HTS components of the device. An apparatus utilizing such a cooling method consists of a vessel that contains a pressurized gaseous cryogen region and a sub-cooled liquid cryogen bath, a liquid cryogen heating coupled with a gaseous cryogen venting scheme to maintain the pressure of the cryogen to a value in a range that corresponds to optimum dielectric strength of the liquid cryogen, and a cooling system that maintains the liquid cryogen at a temperature below its boiling point to improve the performance of HTS materials used in the device.

  11. Passive cooling system for liquid metal cooled nuclear reactors with backup coolant flow path

    DOEpatents

    Hunsbedt, Anstein; Boardman, Charles E.

    1993-01-01

    A liquid metal cooled nuclear fission reactor plant having a passive auxiliary safety cooling system for removing residual heat resulting from fuel decay during reactor shutdown, or heat produced during a mishap. This reactor plant is enhanced by a backup or secondary passive safety cooling system which augments the primary passive auxiliary cooling system when in operation, and replaces the primary system when rendered inoperable.

  12. Producing liquid oxygen in the classroom

    NASA Astrophysics Data System (ADS)

    Williams, David; Warden, Nicole; Wharton, Barry

    2016-09-01

    A number of organisations have provided instructions on how to produce small quantities of liquid oxygen in the classroom using liquid nitrogen and a copper condensation coil (Lister 1995 Classic Chemistry Demonstrations (London: Royal Society of Chemistry) pp 61-2, French and Hibbert 2010 Phys. Educ. 45 221-2). The method presented below describes a process which is believed to be safer as it contains the oxygen during production and produces a controllable amount of the liquid. The method also has the advantage that it can be conducted using cheap and easily available materials.

  13. Analysis of temperature distribution in liquid-cooled turbine blades

    NASA Technical Reports Server (NTRS)

    Livingood, John N B; Brown, W Byron

    1952-01-01

    The temperature distribution in liquid-cooled turbine blades determines the amount of cooling required to reduce the blade temperature to permissible values at specified locations. This report presents analytical methods for computing temperature distributions in liquid-cooled turbine blades, or in simplified shapes used to approximate sections of the blade. The individual analyses are first presented in terms of their mathematical development. By means of numerical examples, comparisons are made between simplified and more complete solutions and the effects of several variables are examined. Nondimensional charts to simplify some temperature-distribution calculations are also given.

  14. Evaluation of Mechanical Ventilator Use with Liquid Oxygen Systems

    DTIC Science & Technology

    2017-02-22

    patients using long-term liquid oxygen differ from those on traditional treatment with oxygen concentrators and/or compressed gas cylinders? A...AFRL-SA-WP-SR-2017-0006 Evaluation of Mechanical Ventilator Use with Liquid Oxygen Systems Thomas Blakeman, MSc, RRT; Dario...To) August 2014 – September 2016 4. TITLE AND SUBTITLE Evaluation of Mechanical Ventilator Use with Liquid Oxygen Systems 5a. CONTRACT NUMBER

  15. Acoustically Forced Coaxial Hydrogen/Liquid Oxygen Jet Flames

    DTIC Science & Technology

    2016-05-15

    Briefing Charts 3. DATES COVERED (From - To) 25 April 2016 - 15 May 2016 4. TITLE AND SUBTITLE Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet...area code) N/A Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std. 239.18 1 Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet Flames...propellants be stored in condensed form – e.g., kerosene, liquid oxygen in rockets • Combustion systems can no longer be designed to meet modern

  16. Oxygen transport in the Sr{sub 2}Fe{sub 3{minus}x}Co{sub x}O{sub y} system.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ma, B.

    The mixed-conducting Sr-Fe-Co oxide has potential use as a gas separation membrane. Its superior oxygen transport reveals the feasibility of using oxide membranes in large-scale oxygen separation. Sr{sub 2}Fe{sub 3{minus}x}Co{sub x}O{sub y} (with x = 0.0, 0.3, 0.6, and 1.0) samples were made by solid state reaction. To understand the oxygen transport mechanism in this system, conductivity and thermogravimetry experiments were conducted at high temperature in various oxygen partial pressure environments. The oxygen diffusion coefficient was determined from the time relaxation transient behavior of the specimen after switching the surrounding atmosphere. Mobility of the charge carrier was derived from relativemore » conductivity and weight changes. X-ray diffraction experiments were carried out on these samples to determine their crystal structures.« less

  17. A determination of the oxygen non-stoichiometry of the oxygen storage material YBaMn{sub 2}O{sub 5+δ}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jeamjumnunja, Kannika; Gong, Wenquan; Makarenko, Tatyana

    2015-10-15

    The A-site ordered double-perovskite oxide, YBaMn{sub 2}O{sub 5+δ}, has been of recent interest for possible application as an oxygen storage material. In the present study, the oxygen non-stoichiometry of YBaMn{sub 2}O{sub 5+δ} has been determined as a function of pO{sub 2} at 650, 700 and 750 °C by Coulometric titration at near-equilibrium conditions. The results confirm that this perovskite oxide has three distinct phases on oxidation/reduction with δ≈0, 0.5 and 1. The stabilities of the YBaMn{sub 2}O{sub 5+δ} phases span a wide range of oxygen partial pressures (∼10{sup −20}≤pO{sub 2}(atm)≤∼1 ) depending on temperature. The phases interconvert at higher pO{submore » 2} values at higher temperatures. The partial molar free energies (Δμ{sub O}) corresponding to the oxidation of YBaMn{sub 2}O{sub 5} to YBaMn{sub 2}O{sub 5.5} and of YBaMn{sub 2}O{sub 5.5} to YBaMn{sub 2}O{sub ∼6} were determined. The value of Δμ{sub O} in both oxidation steps becomes less negative with increasing temperature. At some T and pO{sub 2} conditions, YBaMn{sub 2}O{sub 5+δ} is unstable with respect to decomposition to BaMnO{sub 3−δ} and YMnO{sub 3}. This instability is anticipated from the previous studies of the synthesis of YBaMn{sub 2}O{sub 5+δ} but is more apparent in the present experiments which are necessarily slow in order to achieve equilibrium with respect to the oxygen content. - Highlights: • Determination of the oxygen non-stoichiometry of YBaMn{sub 2}O{sub 5+δ} as a function of pO{sub 2} and T. • Establishments of pO{sub 2} ranges of stability of O{sub 5} and O{sub 5.5} at 650 °C, 700 °C and 750 °C. • Discovery of the kinetic instability of YBaMn{sub 2}O{sub 5+δ} with respect to decomposition to BaMnO{sub 3}−{sub x} and YMnO{sub 3}. • Evaluation of the thermodynamics of the oxidation of YBaMnO{sub 5}.« less

  18. Liquid Cooling/Warming Garment

    NASA Technical Reports Server (NTRS)

    Koscheyev, Victor S.; Leon, Gloria R.; Dancisak, Michael J.

    2010-01-01

    The NASA liquid cooling/ventilating garment (LCVG) currently in use was developed over 40 years ago. With the commencement of a greater number of extra-vehicular activity (EVA) procedures with the construction of the International Space Station, problems of astronaut comfort, as well as the reduction of the consumption of energy, became more salient. A shortened liquid cooling/warming garment (SLCWG) has been developed based on physiological principles comparing the efficacy of heat transfer of different body zones; the capability of blood to deliver heat; individual muscle and fat body composition as a basis for individual thermal profiles to customize the zonal sections of the garment; and the development of shunts to minimize or redirect the cooling/warming loop for different environmental conditions, physical activity levels, and emergency situations. The SLCWG has been designed and completed, based on extensive testing in rest, exercise, and antiorthostatic conditions. It is more energy efficient than the LCVG currently used by NASA. The total length of tubing in the SLCWG is approximately 35 percent less and the weight decreased by 20 percent compared to the LCVG. The novel features of the innovation are: 1. The efficiency of the SLCWG to maintain thermal status under extreme changes in body surface temperatures while using significantly less tubing than the LCVG. 2. The construction of the garment based on physiological principles of heat transfer. 3. The identification of the body areas that are most efficient in heat transfer. 4. The inclusion of a hood as part of the garment. 5. The lesser consumption of energy.

  19. Pumping Liquid Oxygen by Use of Pulsed Magnetic Fields

    NASA Technical Reports Server (NTRS)

    Youngquist, Robert; Lane, John; Immer, Christopher; Simpson, James

    2004-01-01

    An effort is underway to develop a method of pumping small amounts of liquid oxygen by use of pulsed magnetic fields. This development is motivated by a desire to reduce corrosion and hazards of explosion and combustion by eliminating all moving pump parts in contact with the pumped oxygen. The method exploits the known paramagnetism of liquid oxygen. Since they both behave similarly, the existing theory of ferrofluids (liquids with colloidally suspended magnetic particles) is directly applicable to paramagnetic liquid oxygen. In general, the force density of the paramagnetic interaction is proportional to the magnetic susceptibility multiplied by the gradient of the square of the magnitude of the magnetic field. The local force is in the direction of intensifying magnetic field. In the case of liquid oxygen, the magnetic susceptibility is large enough that a strong magnetic-field gradient can lift the liquid in normal Earth gravitation.

  20. Liquid cooled brassiere and method of diagnosing malignant tumors therewith

    NASA Technical Reports Server (NTRS)

    Elkins, W.; Williams, B. A.; Tickner, E. G. (Inventor)

    1976-01-01

    A device for enhancing the detection of malignant tissue in the breasts of a woman was described. A brassiere-like garment which is fitted with a pair of liquid-perfused cooling panels which completely and compliantly cover the breasts and upper torso was studied. The garment is connected by plastic tubing to a liquid cooling system comprising a fluid pump, a solenoid control valve for controlling the flow of fluid to either the cooling unit or the heating unit, a fluid reservoir, a temperature sensor in the reservoir, and a restrictor valve to control the pressure in the garment inlet cooling line.

  1. 38. DETAIL OF COOLING WATER BOOSTER PUMP FOR OXYGEN FURNACES, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    38. DETAIL OF COOLING WATER BOOSTER PUMP FOR OXYGEN FURNACES, LANCES, AND FUME HOODS IN THE GAS WASHER PUMP HOUSE LOOKING EAST. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  2. Cooling rate dependence of simulated Cu{sub 64.5}Zr{sub 35.5} metallic glass structure

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ryltsev, R. E.; Ural Federal University, 19 Mira Str., 620002 Ekaterinburg; L.D. Landau Institute for Theoretical Physics, Russian Academy of Sciences, 2 Kosygina Str., 119334 Moscow

    Using molecular dynamics simulations with embedded atom model potential, we study structural evolution of Cu{sub 64.5}Zr{sub 35.5} alloy during the cooling in a wide range of cooling rates γ ∈ (1.5 ⋅ 10{sup 9}, 10{sup 13}) K/s. Investigating short- and medium-range orders, we show that the structure of Cu{sub 64.5}Zr{sub 35.5} metallic glass essentially depends on cooling rate. In particular, a decrease of the cooling rate leads to an increase of abundances of both the icosahedral-like clusters and Frank-Kasper Z16 polyhedra. The amounts of these clusters in the glassy state drastically increase at the γ{sub min} = 1.5 ⋅ 10{supmore » 9} K/s. Analysing the structure of the glass at γ{sub min}, we observe the formation of nano-sized crystalline grain of Cu{sub 2}Zr intermetallic compound with the structure of Cu{sub 2}Mg Laves phase. The structure of this compound is isomorphous with that for Cu{sub 5}Zr intermetallic compound. Both crystal lattices consist of two types of clusters: Cu-centered 13-atom icosahedral-like cluster and Zr-centered 17-atom Frank-Kasper polyhedron Z16. That suggests the same structural motifs for the metallic glass and intermetallic compounds of Cu–Zr system and explains the drastic increase of the abundances of these clusters observed at γ{sub min}.« less

  3. [Heat transfer analysis of liquid cooling garment used for extravehicular activity].

    PubMed

    Qiu, Y F; Yuan, X G; Mei, Z G; Jia, S G; Ouyang, H; Ren, Z S

    2001-10-01

    Brief description was given about the construction and function of the LCG (liquid cooling garment) used for EVA (extravehicular activity). The heat convection was analyzed between ventilating gas and LCG, the heat and mass transfer process was analyzed too, then a heat and mass transfer mathematical model of LCG was developed. Thermal physiological experimental study with human body wearing LVCG (liquid cooling and ventilation garment) used for EVA was carried out to verify this mathematical model. This study provided a basis for the design of liquid-cooling and ventilation system for the space suit.

  4. Make Liquid Oxygen in Your Class

    ERIC Educational Resources Information Center

    French, M. M. J.; Hibbert, Michael

    2010-01-01

    Oxygen is one of the component gases of air at room temperature, making up around 20% of the atmosphere. But can oxygen be liquified? This article details a method for making small amounts of liquid oxygen in the classroom if there is no access to a cylinder of compressed oxygen gas, and two methods for identifying the fact that it is liquid…

  5. Foil bearing performance in liquid nitrogen and liquid oxygen

    NASA Technical Reports Server (NTRS)

    Genge, Gary G.; Saville, Marshall; Gu, Alston

    1993-01-01

    Space transfer vehicles and other power and propulsion systems require long-life turbopumps. Rolling-element bearings used in current turbopumps do not have sufficient life for these applications. Process fluid foil bearings have established long life, with exceptional reliability, over a wide range of temperatures and fluids in many high-speed turbomachinery applications. However, actual data on bearing performance in cryogenic fluids has been minimal. The National Aeronautics and Space Administration (NASA) and AlliedSignal Aerospace Systems and Equipment (ASE) have attempted to characterize the leaf-type compliant foil bearing in oxygen and nitrogen. The work performed under a joint internal research and development program between Marshall Space Flight Center (MSFC) and ASE demonstrated that the foil bearing has load capacities of at least 266 psi in liquid oxygen and 352 psi in liquid nitrogen. In addition, the bearing demonstrated a direct damping coefficient of 40 to 50 lb-sec/in. with a damping ratio of .7 to 1.4 in. liquid nitrogen using a bearing sized for upper-stage turbopumps. With the results from this testing and the years of successful use in air cycle machines and other applications, leaf-type compliant foil bearings are ready for testing in liquid oxygen turbopumps.

  6. Cooling rate dependence of structural order in Al{sub 90}Sm{sub 10} metallic glass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sun, Yang; Ames Laboratory, US Department of Energy, Ames, Iowa 50011; Zhang, Yue

    2016-07-07

    The atomic structure of Al{sub 90}Sm{sub 10} metallic glass is studied using molecular dynamics simulations. By performing a long sub-T{sub g} annealing, we developed a glass model closer to the experiments than the models prepared by continuous cooling. Using the cluster alignment method, we found that “3661” cluster is the dominating short-range order in the glass samples. The connection and arrangement of “3661” clusters, which define the medium-range order in the system, are enhanced significantly in the sub-T{sub g} annealed sample as compared with the fast cooled glass samples. Unlike some strong binary glass formers such as Cu{sub 64.5}Zr{sub 35.5},more » the clusters representing the short-range order do not form an interconnected interpenetrating network in Al{sub 90}Sm{sub 10,} which has only marginal glass formability.« less

  7. Algorithmic cooling in liquid-state nuclear magnetic resonance

    NASA Astrophysics Data System (ADS)

    Atia, Yosi; Elias, Yuval; Mor, Tal; Weinstein, Yossi

    2016-01-01

    Algorithmic cooling is a method that employs thermalization to increase qubit purification level; namely, it reduces the qubit system's entropy. We utilized gradient ascent pulse engineering, an optimal control algorithm, to implement algorithmic cooling in liquid-state nuclear magnetic resonance. Various cooling algorithms were applied onto the three qubits of C132-trichloroethylene, cooling the system beyond Shannon's entropy bound in several different ways. In particular, in one experiment a carbon qubit was cooled by a factor of 4.61. This work is a step towards potentially integrating tools of NMR quantum computing into in vivo magnetic-resonance spectroscopy.

  8. Droplet Impact Sub-cavity Histories and PDPA Spray Experiments for Spray Cooling Modeling

    NASA Astrophysics Data System (ADS)

    Hillen, Nicholas Lee

    Spray cooling is a topic of current interest for its ability to uniformly remove high levels of waste heat from densely packed microelectronics. It has demonstrated the ability to achieve very high heat fluxes, up to 500 W/cm2 with water as the coolant, making it an attractive active thermal management tool. Full Computational Fluid Dynamic (CFD) simulations of spray cooling are infeasible due to the complexity of the spray (drops fluxes of 106 drops/cm2-sec) and heater surface physics requiring impractical resources. Thus a Monte-Carlo (MC) spray cooling simulation model based on empirical data is under development to serve as a cost effective design tool. The initial MC model shows promise, but it lacks additional physics necessary to predict accurate heat fluxes based on nozzle conditions and heated surface geometry. This work reports spray and single drop experiments with the goal of computing the volume beneath a droplet impact cavity (the sub-cavity volume) created by a single impinging droplet on an initial liquid layer. A Phase Doppler Particle Analyzer (PDPA) was utilized to characterize a spray of interest in terms of integrated global Weber, Reynolds, and Froude numbers for varying flow conditions. Results showed that the spray droplet diameters decreased and velocities increased with increasing nozzle gage pressure. A relevant test plan for the single drop experiments has been created from the measured PDPA spray profiles combined with residual spray film thickness measurements from literature resulting in: 140≤We≤1,000, 1,200≤ Re≤3,300, and 0.2≤h0*≤1.0. Froude numbers were not able to be matched for the current single drop experiments (spray: 32,800≤Fr≤275,000). Liquid film thicknesses under the cavity formed by a single droplet have been measured versus radius and time via a non-contact optical thickness sensor for the selected range of dimensionless numbers (We, Re, and h0*). Sub-cavity radius histories have also been analyzed

  9. Optimum dry-cooling sub-systems for a solar air conditioner

    NASA Technical Reports Server (NTRS)

    Chen, J. L. S.; Namkoong, D.

    1978-01-01

    Dry-cooling sub-systems for residential solar powered Rankine compression air conditioners were economically optimized and compared with the cost of a wet cooling tower. Results in terms of yearly incremental busbar cost due to the use of dry-cooling were presented for Philadelphia and Miami. With input data corresponding to local weather, energy rate and capital costs, condenser surface designs and performance, the computerized optimization program yields design specifications of the sub-system which has the lowest annual incremental cost.

  10. Combined refrigeration system with a liquid pre-cooling heat exchanger

    DOEpatents

    Gaul, Christopher J.

    2003-07-01

    A compressor-pump unit for use in a vapor-compression refrigeration system is provided. The compressor-pump unit comprises a driving device including a rotatable shaft. A compressor is coupled with a first portion of the shaft for compressing gaseous refrigerant within the vapor-compression refrigeration system. A liquid pump is coupled with a second portion of the shaft for receiving liquid refrigerant having a first pressure and for discharging the received liquid refrigerant at a second pressure with the second pressure being higher than the first pressure by a predetermined amount such that the discharged liquid refrigerant is subcooled. A pre-cooling circuit is connected to the liquid pump with the pre-cooling circuit being exposed to the gaseous refrigerant whereby the gaseous refrigerant absorbs heat from the liquid refrigerant, prior to the liquid refrigerant entering the liquid pump.

  11. Liquid cooled data center design selection

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chainer, Timothy J.; Iyengar, Madhusudan K.; Parida, Pritish R.

    Input data, specifying aspects of a thermal design of a liquid cooled data center, is obtained. The input data includes data indicative of ambient outdoor temperature for a location of the data center; and/or data representing workload power dissipation for the data center. The input data is evaluated to obtain performance of the data center thermal design. The performance includes cooling energy usage; and/or one pertinent temperature associated with the data center. The performance of the data center thermal design is output.

  12. A determination of the oxygen non-stoichiometry of the oxygen storage materials LnBaMn{sub 2}O{sub 5+δ} (Ln=Gd, Pr)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jeamjumnunja, Kannika; Gong, Wenquan; Makarenko, Tatyana

    The A-site ordered double-perovskite oxides, LnBaMn{sub 2}O{sub 5+δ} (Ln=Gd, Pr), were synthesized and investigated to understand the effect of A site cation substitution on the oxygen storage properties of these materials. The present results are compared with our previous data for YBaMn{sub 2}O{sub 5+δ}. The results clearly reveal that changing the Ln cation strongly influences the oxidation/reduction behavior of LnBaMn{sub 2}O{sub 5+δ}. Based on thermogravimetric analysis data, oxygen uptake begins at lower temperatures in both air and oxygen in compounds with Ln{sup 3+} ions larger than Y{sup 3+}. These oxides exhibit almost complete and reversible oxygen uptake/release between fully-reduced LnBaMn{submore » 2}O{sub 5} and fully-oxidized LnBaMn{sub 2}O{sub 6} during changes of the oxygen partial pressure between air and 1.99% H{sub 2}/Ar. In addition, the oxygen non-stoichiometries of GdBaMn{sub 2}O{sub 5+δ} and PrBaMn{sub 2}O{sub 5+δ} were determined as a function of pO{sub 2} at 600, 650, 700 and 750 °C by Coulometric titration at near-equilibrium conditions. The results confirm that these materials have two distinct phases on oxidation/reduction with δ≈0, 0.5 and a third phase with a range of composition with an oxygen content (5+δ) approaching ~6. The stabilities of the LnBaMn{sub 2}O{sub 5+δ} phases extend over a wide range of oxygen partial pressures (∼10{sup −25}≤pO{sub 2} (atm)≤∼1) depending on temperature. Isothermal experiments show that the larger the Ln{sup 3+} cation the lower pO{sub 2} for phase conversion. At some temperatures and pO{sub 2} conditions, the LnBaMn{sub 2}O{sub 5+δ} compounds are unstable with respect to decomposition to BaMnO{sub 3−δ} and LnMnO{sub 3}. This instability is more apparent in Coulometric titration experiments than in thermogravimetric analysis. The Coulometric titration experiments are necessarily slow in order to achieve equilibrium oxygen compositions. - Graphical abstract: Structure of LnBaMn{sub

  13. Sub-micron particle sampler apparatus and method for sampling sub-micron particles

    DOEpatents

    Gay, D.D.; McMillan, W.G.

    1984-04-12

    Apparatus and method steps for collecting sub-micron sized particles include a collection chamber and cryogenic cooling. The cooling is accomplished by coil tubing carrying nitrogen in liquid form, with the liquid nitrogen changing to the gas phase before exiting from the collection chamber in the tubing. Standard filters are used to filter out particles of diameter greater than or equal to 0.3 microns; however, the present invention is used to trap particles of less than 0.3 micron in diameter. A blower draws air to said collection chamber through a filter which filters particles with diameters greater than or equal to 0.3 micron. The air is then cryogenically cooled so that moisture and sub-micron sized particles in the air condense into ice on the coil. The coil is then heated so that the ice melts, and the liquid is then drawn off and passed through a Buchner funnel where the liquid is passed through a Nuclepore membrane. A vacuum draws the liquid through the Nuclepore membrane, with the Nuclepore membrane trapping sub-micron sized particles therein. The Nuclepore membrane is then covered on its top and bottom surfaces with sheets of Mylar and the assembly is then crushed into a pellet. This effectively traps the sub-micron sized particles for later analysis. 6 figures.

  14. Method of shielding a liquid-metal-cooled reactor

    DOEpatents

    Sayre, Robert K.

    1978-01-01

    The primary heat transport system of a nuclear reactor -- particularly for a liquid-metal-cooled fast-breeder reactor -- is shielded and protected from leakage by establishing and maintaining a bed of a powdered oxide closely and completely surrounding all components thereof by passing a gas upwardly therethrough at such a rate as to slightly expand the bed to the extent that the components of the system are able to expand without damage and yet the particles of the bed remain close enough so that the bed acts as a guard vessel for the system. Preferably the gas contains 1 to 10% oxygen and the gas is passed upwardly through the bed at such a rate that the lower portion of the bed is a fixed bed while the upper portion is a fluidized bed, the line of demarcation therebetween being high enough that the fixed bed portion of the bed serves as guard vessel for the system.

  15. Experimental evidence for a liquid-liquid crossover in deeply cooled confined water.

    PubMed

    Cupane, Antonio; Fomina, Margarita; Piazza, Irina; Peters, Judith; Schirò, Giorgio

    2014-11-21

    In this work we investigate, by means of elastic neutron scattering, the pressure dependence of mean square displacements (MSD) of hydrogen atoms of deeply cooled water confined in the pores of a three-dimensional disordered SiO2 xerogel; experiments have been performed at 250 and 210 K from atmospheric pressure to 1200 bar. The "pressure anomaly" of supercooled water (i.e., a mean square displacement increase with increasing pressure) is observed in our sample at both temperatures; however, contrary to previous simulation results and to the experimental trend observed in bulk water, the pressure effect is smaller at lower (210 K) than at higher (250 K) temperature. Elastic neutron scattering results are complemented by differential scanning calorimetry data that put in evidence, besides the glass transition at about 170 K, a first-order-like endothermic transition occurring at about 230 K that, in view of the neutron scattering results, can be attributed to a liquid-liquid crossover. Our results give experimental evidence for the presence, in deeply cooled confined water, of a crossover occurring at about 230 K (at ambient pressure) from a liquid phase predominant at 210 K to another liquid phase predominant at 250 K; therefore, they are fully consistent with the liquid-liquid transition hypothesis.

  16. Oxygen related recombination defects in Ta{sub 3}N{sub 5} water splitting photoanode

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fu, Gao; Yu, Tao, E-mail: yscfei@nju.edu.cn, E-mail: yutao@nju.edu.cn; Zou, Zhigang

    2015-10-26

    A key route to improving the performance of Ta{sub 3}N{sub 5} photoelectrochemical film devices in solar driving water splitting to hydrogen is to understand the nature of the serious recombination of photo-generated carriers. Here, by using the temperature-dependent photoluminescence (PL) spectrum, we confirmed that for the Ta{sub 3}N{sub 5} films prepared by nitriding Ta{sub 2}O{sub 5} precursor, one PL peak at 561 nm originates from deep-level defects recombination of the oxygen-enriched Ta{sub 3}N{sub 5} phases, and another one at 580 nm can be assigned to band recombination of Ta{sub 3}N{sub 5} itself. Both of the two bulk recombination processes may decrease themore » photoelectrochemical performance of Ta{sub 3}N{sub 5}. It was difficult to remove the oxygen-enriched impurities in Ta{sub 3}N{sub 5} films by increasing the nitriding temperatures due to their high thermodynamically stability. In addition, a broadening PL peak between 600 and 850 nm resulting from oxygen related surface defects was observed by the low-temperature PL measurement, which may induce the surface recombination of photo-generated carriers and can be removed by increasing the nitridation temperature. Our results provided direct experimental evidence to understand the effect of oxygen-related crystal defects in Ta{sub 3}N{sub 5} films on its photoelectric performance.« less

  17. High Performance Mars Liquid Cooling and Ventilation Garment Project

    NASA Technical Reports Server (NTRS)

    Terrier, Douglas; Clayton, Ronald; Whitlock, David; Conger, Bruce

    2015-01-01

    EVA space suit mobility in micro-gravity is enough of a challenge and in the gravity of Mars, improvements in mobility will enable the suited crew member to efficiently complete EVA objectives. The idea proposed is to improve thermal efficiencies of the liquid cooling and ventilation garment (LCVG) in the torso area in order to free up the arms and legs by removing the liquid tubes currently used in the ISS EVA suit in the limbs. By using shaped water tubes that greatly increase the contact area with the skin in the torso region of the body, the heat transfer efficiency can be increased to provide the entire liquid cooling requirement and increase mobility by freeing up the arms and legs. Additional potential benefits of this approach include reduced LCVG mass, enhanced evaporation cooling, increased comfort during Mars EVA tasks, and easing of the overly dry condition in the helmet associated with the Advanced Extravehicular Mobility Unit (EMU) ventilation loop currently under development.

  18. Asetek's Warm-Water Liquid Cooling System Yields Energy Cost Savings at

    Science.gov Websites

    NREL | Energy Systems Integration Facility | NREL Asetek Asetek's Warm-Water Liquid Cooling System Yields Energy Cost Savings at NREL Asetek's RackCDU liquid cooling system was installed and tested at the Energy Systems Integration Facility's (ESIF's) ultra-energy-efficient high-performance

  19. Liquid-cooling technology for gas turbines - Review and status

    NASA Technical Reports Server (NTRS)

    Van Fossen, G. J., Jr.; Stepka, F. S.

    1978-01-01

    After a brief review of past efforts involving the forced-convection cooling of gas turbines, the paper surveys the state of the art of the liquid cooling of gas turbines. Emphasis is placed on thermosyphon methods of cooling, including those utilizing closed, open, and closed-loop thermosyphons; other methods, including sweat, spray and stator cooling, are also discussed. The more significant research efforts, design data, correlations, and analytical methods are mentioned and voids in technology are summarized.

  20. Trap seal for open circuit liquid cooled turbines

    DOEpatents

    Grondahl, Clayton M.; Germain, Malcolm R.

    1980-01-01

    An improved trap seal for open circuit liquid cooled turbines is disclosed. The trap seal of the present invention includes an annular recess formed in the supply conduit of cooling channels formed in the airfoil of the turbine buckets. A cylindrical insert is located in the annular recesses and has a plurality of axial grooves formed along the outer periphery thereof and a central recess formed in one end thereof. The axial grooves and central recess formed in the cylindrical insert cooperate with the annular recess to define a plurality of S-shaped trap seals which permit the passage of liquid coolant but prohibit passage of gaseous coolant.

  1. Automatic control of human thermal comfort with a liquid-cooled garment

    NASA Technical Reports Server (NTRS)

    Kuznetz, L. H.

    1977-01-01

    Water cooling in a liquid-cooled garment is used to maintain the thermal comfort of crewmembers during extravehicular activity. The feasibility of a simple control that will operate automatically to maintain the thermal comfort is established. Data on three test subjects are included to support the conclusion that heat balance can be maintained well within allowable medical limits. The controller concept was also successfully demonstrated for ground-based applications and shows potential for any tasks involving the use of liquid-cooled garments.

  2. Synergistic stabilization of metastable Fe{sub 23}B{sub 6} and γ-Fe in undercooled Fe{sub 83}B{sub 17}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Quirinale, D. G.; Rustan, G. E.; Kreyssig, A.

    2015-06-15

    Previous investigations of undercooled liquid Fe{sub 83}B{sub 17} near the eutectic composition have found that metastable crystalline phases, such as Fe{sub 23}B{sub 6}, can be formed and persist down to ambient temperature even for rather modest cooling rates. Using time-resolved high-energy x-ray diffraction on electrostatically levitated samples of Fe{sub 83}B{sub 17}, we demonstrate that the Fe{sub 23}B{sub 6} metastable phase and fcc γ-Fe grow coherently from the undercooled Fe{sub 83}B{sub 17} liquid and effectively suppress the formation of the equilibrium Fe{sub 2}B + bcc α-Fe phases. The stabilization of γ-Fe offers another opportunity for experimental investigations of magnetism in metastable fcc iron.

  3. Empirical model for calculating vapor-liquid equilibrium and associated phase enthalpy for the CO$sub 2$--O$sub 2$--Kr--Xe system for application to the KALC process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Glass, R. W.; Gilliam, T. M.; Fowler, V. L.

    An empirical model is presented for vapor-liquid equilibria and enthalpy for the CO$sub 2$-O$sub 2$ system. In the model, krypton and xenon in very low concentrations are combined with the CO$sub 2$-O$sub 2$ system, thereby representing the total system of primary interest in the High-Temperature Gas- Cooled Reactor program for removing krypton from off-gas generated during the reprocessing of spent fuel. Selected properties of the individual and combined components being considered are presented in the form of tables and empirical equations. (auth)

  4. RF cavity using liquid dielectric for tuning and cooling

    DOEpatents

    Popovic, Milorad [Warrenville, IL; Johnson, Rolland P [Newport News, VA

    2012-04-17

    A system for accelerating particles includes an RF cavity that contains a ferrite core and a liquid dielectric. Characteristics of the ferrite core and the liquid dielectric, among other factors, determine the resonant frequency of the RF cavity. The liquid dielectric is circulated to cool the ferrite core during the operation of the system.

  5. Advanced Liquid-Cooling Garment Using Highly Thermally Conductive Sheets

    NASA Technical Reports Server (NTRS)

    Ruemmele, Warren P.; Bue, Grant C.; Orndoff, Evelyne; Tang, Henry

    2010-01-01

    This design of the liquid-cooling garment for NASA spacesuits allows the suit to remove metabolic heat from the human body more effectively, thereby increasing comfort and performance while reducing system mass. The garment is also more flexible, with fewer restrictions on body motion, and more effectively transfers thermal energy from the crewmember s body to the external cooling unit. This improves the garment s performance in terms of the maximum environment temperature in which it can keep a crewmember comfortable. The garment uses flexible, highly thermally conductive sheet material (such as graphite), coupled with cooling water lines of improved thermal conductivity to transfer the thermal energy from the body to the liquid cooling lines more effectively. The conductive sheets can be layered differently, depending upon the heat loads, in order to provide flexibility, exceptional in-plane heat transfer, and good through-plane heat transfer. A metal foil, most likely aluminum, can be put between the graphite sheets and the external heat source/sink in order to both maximize through-plane heat transfer at the contact points, and to serve as a protection to the highly conductive sheets. Use of a wicking layer draws excess sweat away from the crewmember s skin and the use of an outer elastic fabric ensures good thermal contact of the highly conductive underlayers with the skin. This allows the current state of the art to be improved by having cooling lines that can be more widely spaced to improve suit flexibility and to reduce weight. Also, cooling liquid does not have to be as cold to achieve the same level of cooling. Specific areas on the human body can easily be targeted for greater or lesser cooling to match human physiology, a warmer external environment can be tolerated, and spatial uniformity of the cooling garment can be improved to reduce vasoconstriction limits. Elements of this innovation can be applied to other embodiments to provide effective heat

  6. Cavitating Jet Method and System for Oxygenation of Liquids

    NASA Technical Reports Server (NTRS)

    Chahine, Georges L.

    2012-01-01

    Reclamation and re-use of water is critical for space-based life support systems. A number of functions must be performed by any such system including removal of various contaminants and oxygenation. For long-duration space missions, this must be done with a compact, reliable system that requires little or no use of expendables and minimal power. DynaJets cavitating jets can oxidize selected organic compounds with much greater energy efficiency than ultrasonic devices typically used in sonochemistry. The focus of this work was to develop cavitating jets to simultaneously accomplish the functions of oxygenation and removal of contaminants of importance to space-structured water reclamation systems. The innovation is a method to increase the concentration of dissolved oxygen or other gasses in a liquid. It utilizes a particular form of novel cavitating jet operating at low to moderate pressures to achieve a high-efficiency means of transporting and mixing the gas into the liquid. When such a jet is utilized to simultaneously oxygenate the liquid and to oxidize organic compounds within the liquid, such as those in waste water, the rates of contaminant removal are increased. The invention is directed toward an increase in the dissolved gas content of a liquid, in general, and the dissolved oxygen content of a liquid in particular.

  7. Structural design of liquid oxygen/liquid methane robotic lander JANUS

    NASA Astrophysics Data System (ADS)

    Chaidez, Mariana

    As the attempt to send humans to Mars has gained momentum in the last decade, the need to find alternative propellants that are safer, less toxic, and yields a better performance has become apparent [1]. Liquid methane and oxygen have emerged as a suitable alternative. In addition, the incorporation of liquid methane/liquid oxygen into the propulsion system has demonstrated an increase in engine performance, as well as a reduction in the volume, size and complexity of the propulsion system. In an attempt to further understand the technologies that are possible to develop using liquid oxygen (LO 2) and liquid methane (LCH4), a preliminary design of a robotic lander JANUS is being completed by the Center for Space Exploration and Technology Research (cSTER). The structural design of the vehicle is important because it acts as the skeleton of the vehicle and dictates the maneuverability of the robotic lander. To develop the structure of the robotic lander, six different design vehicle concepts with varying tank configurations were considered. Finite Element Analysis (FEA) was completed on each model to optimize each vehicle. Trade studies were completed to choose the best design for JANUS. Upon completion of the trade studies the design for the first prototype of JANUS was initiated in which the tank and thrust modules were designed. This thesis will describe the design process for the structural design of the JANUS.

  8. DETAIL OF THE LIQUID HYDROGEN AND LIQUID OXYGEN VENT VALVES, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    DETAIL OF THE LIQUID HYDROGEN AND LIQUID OXYGEN VENT VALVES, SIXTH LEVEL OF THE EXTERNAL TANK CHECK-OUT CELLS, HB-2, FACING NORTHEAST - Cape Canaveral Air Force Station, Launch Complex 39, Vehicle Assembly Building, VAB Road, East of Kennedy Parkway North, Cape Canaveral, Brevard County, FL

  9. Sub-micron particle sampler apparatus

    DOEpatents

    Gay, Don D.; McMillan, William G.

    1987-01-01

    Apparatus and method steps for collecting sub-micron sized particles include a collection chamber and cryogenic cooling. The cooling is accomplished by coil tubing carrying nitrogen in liquid form, with the liquid nitrogen changing to the gas phase before exiting from the collection chamber in the tubing. Standard filters are used to filter out particles of diameter greater than or equal to 0.3 microns; however the present invention is used to trap particles of less than 0.3 micron in diameter. A blower draws air to said collection chamber through a filter which filters particles with diameters greater than or equal to 0.3 micron. The air is then cryogenically cooled so that moisture and sub-micron sized particles in the air condense into ice on the coil. The coil is then heated so that the ice melts, and the liquid is then drawn off and passed through a Buchner funnel where the liquid is passed through a Nuclepore membrane. A vacuum draws the liquid through the Nuclepore membrane, with the Nuclepore membrane trapping sub-micron sized particles therein. The Nuclepore membrane is then covered on its top and bottom surfaces with sheets of Mylar.RTM. and the assembly is then crushed into a pellet. This effectively traps the sub-micron sized particles for later analysis.

  10. Producing Liquid Oxygen in the Classroom

    ERIC Educational Resources Information Center

    Williams, David; Warden, Nicole; Wharton, Barry

    2016-01-01

    A number of organisations have provided instructions on how to produce small quantities of liquid oxygen in the classroom using liquid nitrogen and a copper condensation coil (Lister 1995 "Classic Chemistry Demonstrations" (London: Royal Society of Chemistry) pp 61-2, French and Hibbert 2010 "Phys. Educ." 45 221-2). The method…

  11. Liquid oxygen/liquid hydrogen boost/vane pump for the advanced orbit transfer vehicles auxiliary propulsion system

    NASA Technical Reports Server (NTRS)

    Gluzek, F.; Mokadam, R. G.; To, I. H.; Stanitz, J. D.; Wollschlager, J.

    1979-01-01

    A rotating, positive displacement vane pump with an integral boost stage was designed to pump saturated liquid oxygen and liquid hydrogen for auxiliary propulsion system of orbit transfer vehicle. This unit is designed to ingest 10% vapor by volume, contamination free liquid oxygen and liquid hydrogen. The final pump configuration and the predicted performance are included.

  12. Liquid Nitrogen (Oxygen Simulent) Thermodynamic Venting System Test Data Analysis

    NASA Technical Reports Server (NTRS)

    Hedayat, A.; Nelson, S. L.; Hastings, L. J.; Flachbart, R. H.; Tucker, S. P.

    2005-01-01

    In designing systems for the long-term storage of cryogens in low gravity space environments, one must consider the effects of thermal stratification on excessive tank pressure that will occur due to environmental heat leakage. During low gravity operations, a Thermodynamic Venting System (TVS) concept is expected to maintain tank pressure without propellant resettling. The TVS consists of a recirculation pump, Joule-Thomson (J-T) expansion valve, and a parallel flow concentric tube heat exchanger combined with a longitudinal spray bar. Using a small amount of liquid extracted by the pump and passing it though the J-T valve, then through the heat exchanger, the bulk liquid and ullage are cooled, resulting in lower tank pressure. A series of TVS tests were conducted at the Marshall Space Flight Center using liquid nitrogen as a liquid oxygen simulant. The tests were performed at fill levels of 90%, 50%, and 25% with gaseous nitrogen and helium pressurants, and with a tank pressure control band of 7 kPa. A transient one-dimensional model of the TVS is used to analyze the data. The code is comprised of four models for the heat exchanger, the spray manifold and injector tubes, the recirculation pump, and the tank. The TVS model predicted ullage pressure and temperature and bulk liquid saturation pressure and temperature are compared with data. Details of predictions and comparisons with test data regarding pressure rise and collapse rates will be presented in the final paper.

  13. Automatic control of liquid cooling garment by cutaneous and external auditory meatus temperatures

    NASA Technical Reports Server (NTRS)

    Fulcher, C. W. G. (Inventor)

    1971-01-01

    An automatic control apparatus for a liquid cooling garment is described that is responsive to actual physiological needs during work and rest periods of a man clothed in the liquid cooling garment. Four skin temperature readings and a reading taken at the external portion of the auditory meatus are added and used in the control signal for a temperature control valve regulating inlet water temperature for the liquid cooling garment. The control apparatus comprises electronic circuits to which the temperatures are applied as control signals and an electro-pneumatic transducer attached to the control valve.

  14. Experimental investigation of temperature rise in bone drilling with cooling: A comparison between modes of without cooling, internal gas cooling, and external liquid cooling.

    PubMed

    Shakouri, Ehsan; Haghighi Hassanalideh, Hossein; Gholampour, Seifollah

    2018-01-01

    Bone fracture occurs due to accident, aging, and disease. For the treatment of bone fractures, it is essential that the bones are kept fixed in the right place. In complex fractures, internal fixation or external methods are used to fix the fracture position. In order to immobilize the fracture position and connect the holder equipment to it, bone drilling is required. During the drilling of the bone, the required forces to chip formation could cause an increase in the temperature. If the resulting temperature increases to 47 °C, it causes thermal necrosis of the bone. Thermal necrosis decreases bone strength in the hole and, subsequently, due to incomplete immobilization of bone, fracture repair is not performed correctly. In this study, attempts have been made to compare local temperature increases in different processes of bone drilling. This comparison has been done between drilling without cooling, drilling with gas cooling, and liquid cooling on bovine femur. Drilling tests with gas coolant using direct injection of CO 2 and N 2 gases were carried out by internal coolant drill bit. The results showed that with the use of gas coolant, the elevation of temperature has limited to 6 °C and the thermal necrosis is prevented. Maximum temperature rise reached in drilling without cooling was 56 °C, using gas and liquid coolant, a maximum temperature elevation of 43 °C and 42 °C have been obtained, respectively. This resulted in decreased possibility of thermal necrosis of bone in drilling with gas and liquid cooling. However, the results showed that the values obtained with the drilling method with direct gas cooling are independent of the rotational speed of drill.

  15. Mount makes liquid nitrogen-cooled gamma ray detector portable

    NASA Technical Reports Server (NTRS)

    Fessler, T. E.

    1966-01-01

    Liquid nitrogen-cooled gamma ray detector system is made portable by attaching the detector to a fixture which provides a good thermal conductive path between the detector and the liquid nitrogen in a dewar flask and a low heat leak path between the detector and the external environment.

  16. Liquid Oxygen/Liquid Methane Integrated Power and Propulsion

    NASA Technical Reports Server (NTRS)

    Banker, Brian; Ryan, Abigail

    2016-01-01

    The proposed paper will cover ongoing work at the National Aeronautics and Space Administration (NASA) Johnson Space Center (JSC) on integrated power and propulsion for advanced human exploration. Specifically, it will present findings of the integrated design, testing, and operational challenges of a liquid oxygen / liquid methane (LOx/LCH4) propulsion brassboard and Solid Oxide Fuel Cell (SOFC) system. Human-Mars architectures point to an oxygen-methane economy utilizing common commodities, scavenged from the planetary atmosphere and soil via In-Situ Resource Utilization (ISRU), and common commodities across sub-systems. Due to the enormous mass gear-ratio required for human exploration beyond low-earth orbit, (for every 1 kg of payload landed on Mars, 226 kg will be required on Earth) increasing commonality between spacecraft subsystems such as power and propulsion can result in tremendous launch mass and volume savings. Historically, propulsion and fuel cell power subsystems have had little interaction outside of the generation (fuel cell) and consumption (propulsion) of electrical power. This was largely due to a mismatch in preferred commodities (hypergolics for propulsion; oxygen & hydrogen for fuel cells). Although this stove-piped approach benefits from simplicity in the design process, it means each subsystem has its own tanks, pressurization system, fluid feed system, etc. increasing overall spacecraft mass and volume. A liquid oxygen / liquid methane commodities architecture across propulsion and power subsystems would enable the use of common tankage and associated pressurization and commodity delivery hardware for both. Furthermore, a spacecraft utilizing integrated power and propulsion could use propellant residuals - propellant which could not be expelled from the tank near depletion due to hydrodynamic considerations caused by large flow demands of a rocket engine - to generate power after all propulsive maneuvers are complete thus utilizing

  17. The influence of liquid-gas velocity ratio on the noise of the cooling tower

    NASA Astrophysics Data System (ADS)

    Yang, Bin; Liu, Xuanzuo; Chen, Chi; Zhao, Zhouli; Song, Jinchun

    2018-05-01

    The noise from the cooling tower has a great influence on psychological performance of human beings. The cooling tower noise mainly consists of fan noise, falling water noise and mechanical noise. This thesis used DES turbulence model with FH-W model to simulate the flow and sound pressure field in cooling tower based on CFD software FLUENT and analyzed the influence of different kinds noise, which affected by diverse factors, on the cooling tower noise. It can be concluded that the addition of cooling water can reduce the turbulence and vortex noise of the rotor fluid field in the cooling tower at some extent, but increase the impact noise of the liquid-gas two phase. In general, the cooling tower noise decreases with the velocity ratio of liquid to gas increasing, and reaches the lowest when the velocity ratio of liquid to gas is close to l.

  18. Liquid Oxygen/Liquid Methane Propulsion and Cryogenic Advanced Development

    NASA Technical Reports Server (NTRS)

    Klem, Mark D.; Smith, Timothy D.; Wadel, Mary F.; Meyer, Michael L.; Free, James M.; Cikanek, Harry A., III

    2011-01-01

    Exploration Systems Architecture Study conducted by NASA in 2005 identified the liquid oxygen (LOx)/liquid methane (LCH4) propellant combination as a prime candidate for the Crew Exploration Vehicle Service Module propulsion and for later use for ascent stage propulsion of the lunar lander. Both the Crew Exploration Vehicle and Lunar Lander were part the Constellation architecture, which had the objective to provide global sustained lunar human exploration capability. From late 2005 through the end of 2010, NASA and industry matured advanced development designs for many components that could be employed in relatively high thrust, high delta velocity, pressure fed propulsion systems for these two applications. The major investments were in main engines, reaction control engines, and the devices needed for cryogenic fluid management such as screens, propellant management devices, thermodynamic vents, and mass gauges. Engine and thruster developments also included advanced high reliability low mass igniters. Extensive tests were successfully conducted for all of these elements. For the thrusters and engines, testing included sea level and altitude conditions. This advanced development provides a mature technology base for future liquid oxygen/liquid methane pressure fed space propulsion systems. This paper documents the design and test efforts along with resulting hardware and test results.

  19. Effects of oxygen stoichiometry on the scaling behaviors of YBa{sub 2}Cu{sub 3}O{sub x} grain boundary weak-links

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wu, K.H.; Fu, C.M.; Jeng, W.J.

    1994-12-31

    The effects of oxygen stoichiometry on the transport properties of the pulsed laser deposited YBa{sub 2}Cu{sub 3}O{sub x} bicrystalline grain boundary weak-link junctions were studied. It is found that not only the cross boundary resistive transition foot structure can be manipulated repeatedly with oxygen annealling processes but the junction behaviors are also altered in accordance. In the fully oxygenated state i.e. with x=7.0 in YBa{sub 2}Cu{sub 3}O{sub x} stoichiometry, the junction critical current exhibits a power of 2 scaling behavior with temperature. In contrast, when annealed in the conditions of oxygen-deficient state (e.g. with x=6.9 in YBa{sub 2}Cu{sub 3}O{sub x}more » stoichiometry) the junction critical current switches to a linear temperature dependence behavior. The results are tentatively attributed to the modification of the structure in the boundary area upon oxygen annealing, which, in turn, will affect the effective dimension of the geometrically constrained weak-link bridges. The detailed discussion on the responsible physical mechanisms as well as the implications of the present results on device applications will be given.« less

  20. Oxygen deficiency and Sn doping of amorphous Ga{sub 2}O{sub 3}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Heinemann, M. D.; Unold, T.; Berry, J.

    2016-01-11

    The potential of effectively n-type doping Ga{sub 2}O{sub 3} considering its large band gap has made it an attractive target for integration into transistors and solar cells. As a result amorphous GaO{sub x} is now attracting interest as an electron transport layer in solar cells despite little information on its opto-electrical properties. Here we present the opto-electronic properties, including optical band gap, electron affinity, and charge carrier density, for amorphous GaO{sub x} thin films deposited by pulsed laser deposition. These properties are strongly dependent on the deposition temperature during the deposition process. The deposition temperature has no significant influence onmore » the general structural properties but produces significant changes in the oxygen stoichiometry of the films. The density of the oxygen vacancies is found to be related to the optical band gap of the GaO{sub x} layer. It is proposed that the oxygen deficiency leads to defect band below the conduction band minimum that increases the electron affinity. These properties facilitate the use of amorphous GaO{sub x} as an electron transport layer in Cu(In,Ga)Se{sub 2} and in Cu{sub 2}O solar cells. Further it is shown that at low deposition temperatures, extrinsic doping with Sn is effective at low Sn concentrations.« less

  1. Cycle time improvement for plastic injection moulding process by sub groove modification in conformal cooling channel

    NASA Astrophysics Data System (ADS)

    Kamarudin, K.; Wahab, M. S.; Batcha, M. F. M.; Shayfull, Z.; Raus, A. A.; Ahmed, Aqeel

    2017-09-01

    Mould designers have been struggling for the improvement of the cooling system performance, despite the fact that the cooling system complexity is physically limited by the fabrication capability of the conventional tooling methods. However, the growth of Solid Free Form Technology (SFF) allow the mould designer to develop more than just a regular conformal cooling channel. Numerous researchers demonstrate that conformal cooling channel was tremendously given significant result in the improvement of productivity and quality in the plastic injection moulding process. This paper presents the research work that applies the passive enhancement method in square shape cooling channel to enhance the efficiency of cooling performance by adding the sub groove to the cooling channel itself. Previous design that uses square shape cooling channel was improved by adding various numbers of sub groove to meet the best sub groove design that able reduced the cooling time. The effect of sub groove design on cooling time was investigated by Autodesk Modlflow Insight software. The simulation results showed that the various sub groove designs give different values to ejection time. The Design 7 showed the lowest value of ejection time with 24.3% increment. The addition of sub groove significantly increased a coolant velocity and a rate of heat transfer from molten plastic to coolant.

  2. Fabricating cooled electronic system with liquid-cooled cold plate and thermal spreader

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chainer, Timothy J.; Graybill, David P.; Iyengar, Madhusudan K.

    Methods are provided for facilitating cooling of an electronic component. The method includes providing a liquid-cooled cold plate and a thermal spreader associated with the cold plate. The cold plate includes multiple coolant-carrying channel sections extending within the cold plate, and a thermal conduction surface with a larger surface area than a surface area of the component to be cooled. The thermal spreader includes one or more heat pipes including multiple heat pipe sections. One or more heat pipe sections are partially aligned to a first region of the cold plate, that is, where aligned to the surface to bemore » cooled, and partially aligned to a second region of the cold plate, which is outside the first region. The one or more heat pipes facilitate distribution of heat from the electronic component to coolant-carrying channel sections of the cold plate located in the second region of the cold plate.« less

  3. Fabricating cooled electronic system with liquid-cooled cold plate and thermal spreader

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chainer, Timothy J.; Graybill, David P.; Iyengar, Madhusudan K.

    Methods are provided for facilitating cooling of an electronic component. The methods include providing a liquid-cooled cold plate and a thermal spreader associated with the cold plate. The cold plate includes multiple coolant-carrying channel sections extending within the cold plate, and a thermal conduction surface with a larger surface area than a surface area of the component to be cooled. The thermal spreader includes one or more heat pipes including multiple heat pipe sections. One or more heat pipe sections are partially aligned to a first region of the cold plate, that is, where aligned to the surface to bemore » cooled, and partially aligned to a second region of the cold plate, which is outside the first region. The one or more heat pipes facilitate distribution of heat from the electronic component to coolant-carrying channel sections of the cold plate located in the second region of the cold plate.« less

  4. Method for sampling sub-micron particles

    DOEpatents

    Gay, Don D.; McMillan, William G.

    1985-01-01

    Apparatus and method steps for collecting sub-micron sized particles include a collection chamber and cryogenic cooling. The cooling is accomplished by coil tubing carrying nitrogen in liquid form, with the liquid nitrogen changing to the gas phase before exiting from the collection chamber in the tubing. Standard filters are used to filter out particles of diameter greater than or equal to 0.3 microns; however the present invention is used to trap particles of less than 0.3 micron in diameter. A blower draws air to said collection chamber through a filter which filters particles with diameters greater than or equal to 0.3 micron. The air is then cryogenically cooled so that moisture and sub-micron sized particles in the air condense into ice on the coil. The coil is then heated so that the ice melts, and the liquid is then drawn off and passed through a Buchner funnel where the liquid is passed through a Nuclepore membrane. A vacuum draws the liquid through the Nuclepore membrane, with the Nuclepore membrane trapping sub-micron sized particles therein. The Nuclepore membrane is then covered on its top and bottom surfaces with sheets of Mylar.RTM. and the assembly is then crushed into a pellet. This effectively traps the sub-micron sized particles for later analysis.

  5. Cool Flames in Propane-Oxygen Premixtures at Low and Intermediate Temperatures at Reduced-Gravity

    NASA Technical Reports Server (NTRS)

    Pearlman, Howard; Foster, Michael; Karabacak, Devrez

    2003-01-01

    The Cool Flame Experiment aims to address the role of diffusive transport on the structure and the stability of gas-phase, non-isothermal, hydrocarbon oxidation reactions, cool flames and auto-ignition fronts in an unstirred, static reactor. These reactions cannot be studied on Earth where natural convection due to self-heating during the course of slow reaction dominates diffusive transport and produces spatio-temporal variations in the thermal and thus species concentration profiles. On Earth, reactions with associated Rayleigh numbers (Ra) less than the critical Ra for onset of convection (Ra(sub cr) approx. 600) cannot be achieved in laboratory-scale vessels for conditions representative of nearly all low-temperature reactions. In fact, the Ra at 1g ranges from 10(exp 4) - 10(exp 5) (or larger), while at reduced-gravity, these values can be reduced two to six orders of magnitude (below Ra(sub cr)), depending on the reduced-gravity test facility. Currently, laboratory (1g) and NASA s KC-135 reduced-gravity (g) aircraft studies are being conducted in parallel with the development of a detailed chemical kinetic model that includes thermal and species diffusion. Select experiments have also been conducted at partial gravity (Martian, 0.3gearth) aboard the KC-135 aircraft. This paper discusses these preliminary results for propane-oxygen premixtures in the low to intermediate temperature range (310- 350 C) at reduced-gravity.

  6. Liquid over-feeding air conditioning system and method

    DOEpatents

    Mei, Viung C.; Chen, Fang C.

    1993-01-01

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

  7. 9 CFR 590.530 - Liquid egg cooling.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Liquid egg cooling. 590.530 Section 590.530 Animals and Animal Products FOOD SAFETY AND INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE EGG PRODUCTS INSPECTION INSPECTION OF EGGS AND EGG PRODUCTS (EGG PRODUCTS INSPECTION ACT) Sanitary, Processing...

  8. 9 CFR 590.530 - Liquid egg cooling.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 9 Animals and Animal Products 2 2011-01-01 2011-01-01 false Liquid egg cooling. 590.530 Section 590.530 Animals and Animal Products FOOD SAFETY AND INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE EGG PRODUCTS INSPECTION INSPECTION OF EGGS AND EGG PRODUCTS (EGG PRODUCTS INSPECTION ACT) Sanitary, Processing...

  9. NORTH SIDES OF LIQUID OXYGEN TANKS. Looking southwest along railroad ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    NORTH SIDES OF LIQUID OXYGEN TANKS. Looking southwest along railroad track to AF Plant 72 - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Liquid Oxygen & Nitrogen Storage Tank Farm, Intersection of Altair & Jupiter Boulevards, Boron, Kern County, CA

  10. Modular liquid-cooled helmet liner for thermal comfort

    NASA Technical Reports Server (NTRS)

    Williams, B. A.; Shitzer, A.

    1974-01-01

    A modular liquid-cooled helmet liner made of eight form-fitting neoprene patches was constructed. The liner was integrated into the sweatband of an Army SPH-4 helicopter aircrew helmet. This assembly was tested on four subjects seated in a hot (47 C), humid (40%) environment. Results indicate a marked reduction in the rate of increase of physiological body functions. Rectal temperature, weight loss, heart rate, and strain indices are all reduced to approximately 50% of uncooled levels. The cooling liner removed from 10% to 30% of total metabolic heat produced. This study also demonstrated the technical feasilibity of using a cooling liner in conjunction with a standard hard helmet. Potential applications of the cooling liner in thermally stressful environments are numerous, notably for helicopter and other aircrews.

  11. Cooling and solidification of heavy hydrocarbon liquid streams

    DOEpatents

    Antieri, Salvatore J.; Comolli, Alfred G.

    1983-01-01

    A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

  12. Cryogenic Cooling for Myriad Applications-A STAR Is Born

    NASA Technical Reports Server (NTRS)

    2006-01-01

    Cryogenics, the science of generating extremely low temperatures, has wide applicability throughout NASA. The Agency employs cryogenics for rocket propulsion, high-pressure gas supply, breathable air in space, life support equipment, electricity, water, food preservation and packaging, medicine, imaging devices, and electronics. Cryogenic liquid oxygen and liquid hydrogen systems are also replacing solid rocket motor propulsion systems in most of the proposed launch systems, a reversion to old-style liquid propellants. In the late 1980s, NASA wanted a compact linear alternator/motor with reduced size and mass, as well as high efficiency, that had unlimited service life for use in a thermally driven power generator for space power applications. Prior development work with free-piston Stirling converters (a Stirling engine integrated with a linear actuator that produces electrical power output) had shown the promise of that technology for high-power space applications. A dual use for terrestrial applications exists for compact Stirling converters for onsite combined heat and power units. The Stirling cycle is also usable in reverse as a refrigeration cycle suitable for cryogenic cooling, so this Stirling converter work promised double benefits as well as dual uses. The uses for cryogenic coolers within NASA abound; commercial applications are similarly wide-ranging, from cooling liquid oxygen and nitrogen, to cryobiology and bio-storage, cryosurgery, instrument and detector cooling, semiconductor manufacturing, and support service for cooled superconducting power systems.

  13. Contamination of liquid oxygen by pressurized gaseous nitrogen

    NASA Technical Reports Server (NTRS)

    Zuckerwar, Allan J.; King, Tracy K.; Ngo, Kim Chi

    1989-01-01

    The penetration of pressurized gaseous nitrogen (GN2) into liquid oxygen (LOX) was investigated experimentally in the 7-inch High Temperature Tunnel, the pilot tunnel for the 8-foot High Temperature Tunnel (8'HTT) at Langley Research Center. A preliminary test using a nuclear monitor revealed the extent of the liquid nitrogen (LN2) build-up at the LOX interface as a function of GN2 pressure. Then an adaptation of the differential flash vaporization technique was used to determine the binary diffusivity of the LOX-LN2 system at a temperature of 90.2 K. The measured value D equals 0.000086 sq cm/s + or - 25 percent together with two prior measurements at lower temperatures revealed an excellent fit to the Arrhenius equation, yielding a pre-exponential factor D sub 0 equals 0.0452 sq cm/s and an activation enthalpy H equals 1.08 kcal/mol. At a pressure of 1700 psi and holding time of 15 min, the penetration of LN2 into LOX (to a 1 percent contamination level) was found to be 0.9 cm, indicating but minimal impact upon 8'HTT operations.

  14. Effect of core cooling on the radius of sub-Neptune planets

    NASA Astrophysics Data System (ADS)

    Vazan, A.; Ormel, C. W.; Dominik, C.

    2018-02-01

    Sub-Neptune planets are very common in our Galaxy and show a large diversity in their mass-radius relation. In sub-Neptunes most of the planet mass is in the rocky part (hereafter, core), which is surrounded by a modest hydrogen-helium envelope. As a result, the total initial heat content of such a planet is dominated by that of the core. Nonetheless, most studies contend that the core cooling only has a minor effect on the radius evolution of the gaseous envelope because the cooling of the core is in sync with the envelope; that is most of the initial heat is released early on timescales of 10-100 Myr. In this Letter we examined the importance of the core cooling rate for the thermal evolution of the envelope. Thus, we relaxed the early core cooling assumption and present a model in which the core is characterized by two parameters: the initial temperature and the cooling time. We find that core cooling can significantly enhance the radius of the planet when it operates on a timescale similar to the observed age, i.e. Gyr. Consequently, the interpretation of the mass-radius observations of sub-Neptunes depends on the assumed core thermal properties and the uncertainty therein. The degeneracy of composition and core thermal properties can be reduced by obtaining better estimates of the planet ages (in addition to their radii and masses) as envisioned by future observations.

  15. Liquid and gaseous oxygen safety review, volume 1

    NASA Technical Reports Server (NTRS)

    Lapin, A.

    1972-01-01

    Materials used or contained in liquid and gaseous oxygen systems are analyzed for their compatibility; and areas of possible concern in oxygen systems are outlined. Design criteria, cleaning procedures, and quality control methods are covered in detail.

  16. Liquid over-feeding air conditioning system and method

    DOEpatents

    Mei, V.C.; Chen, F.C.

    1993-09-21

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

  17. (abstract) Undercooling Studies of the Bulk Metallic Glass Forming Zr(sub 41.2)Ti(sub 13.8)Cu(sub 12.5)Ni(sub 10.0)Be(sub 22.5) Alloy During Containerless Electrostatic Levitation Processing

    NASA Technical Reports Server (NTRS)

    Kim, Y. J.; Busch, R.; Johnson, W. L.; Rulison, A. J.; Rhim, W. K.

    1995-01-01

    Bulk glass forming metallic alloys have long been desired for technological applications and for investigation into liquid undercooling, solidification processes, and thermophysical properties. A glass forming alloy Zr(sub 41.2)Ti(sub 13.8)Cu(sub 12.5)Ni(sub 10.0)Be(sub 22.5) was used to investigate the thermal treatments affecting undercooling and vitrification. The experiments were performed using the high temperature high vacuum electrostatic levitator at JPL. A sample approximately 3 mm in diameter was melted, superheated, undercooled, and solidified while levitated in high vacuum. The results show that when the sample was held above its melting temperature for a sufficient period of time to dissolve oxides and then cooled faster than a critical cooling rate, it undercooled to the glass transition temperature, T(sub g), and formed a glassy alloy. The required critical cooling rate for metallic glass formation was obtained to be between 0.9 K per second and 1.2 K per second for the 42.4 mg sample.

  18. Experimental Studies of Liquefaction and Densification of Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Partridge, Jonathan Koert

    2010-01-01

    The propellant combination that offers optimum performance is very reactive with a low average molecular weight of the resulting combustion products. Propellant combinations such as oxygen and hydrogen meet the above criteria, however, the propellants in gaseous form require large propellant tanks due to the low density of gas. Thus, rocketry employs cryogenic refrigeration to provide a more dense propellant stored as a liquid. In addition to propellant liquefaction, cryogenic refrigeration can also conserve propellant and provide propellant subcooling and propellant densification. Previous studies analyzed vapor conditioning of a cryogenic propellant, with the vapor conditioning by either a heat exchanger position in the vapor or by using the vapor in a refrigeration cycle as the working fluid. This study analyzes the effects of refrigeration heat exchanger located in the liquid of the common propellant oxidizer, liquid oxygen. This study predicted and determined the mass condensation rate and heat transfer coefficient for liquid oxygen.

  19. Cable Feedthrough Between Liquid Oxygen And Ambient

    NASA Technical Reports Server (NTRS)

    Myers, Don A.

    1992-01-01

    Encapsulant and back pressure provide double protection. Cable-feedthrough tube between ambient air and interior of vessel containing liquid oxygen protects external instrumentation and cable from oxygen. Cable in tube surrounded by potting compound. Provides flow of gaseous nitrogen to dilute oxidant and makes it harmless in case of leakage through crack in potting compound.

  20. Film-Cooling Heat-Transfer Measurements Using Liquid Crystals

    NASA Technical Reports Server (NTRS)

    Hippensteele, Steven A.

    1997-01-01

    The following topics are discussed: (1) The Transient Liquid-Crystal Heat-Transfer Technique; (2) 2-D Film-Cooling Heat-Transfer on an AlliedSignal Vane; and (3) Effects of Tab Vortex Generators on Surface Heat Transfer. Downstream of a Jet in Crossflow.

  1. Self-cooled liquid-metal blanket concept

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Malang, S.; Arheidt, K.; Barleon, L.

    1988-11-01

    A blanket concept for the Next European Torus (NET) where 83Pb-17Li serves both as breeder material and as coolant is described. The concept is based on the use of novel flow channel inserts for a decisive reduction of the magnetohydrodynamic (MHD) pressure drop and employs beryllium as neutron multiplier in order to avoid the need for breeding blankets at the inboard side of the torus. This study includes the design, neutronics, thermal hydraulics, stresses, MHDs, corrosion, tritium recovery, and safety of a self-cooled liquid-metal blanket. The results of the investigations indicate that the self-cooled blanket is an attractive alternative tomore » other driver blanket concepts for NET and that it can be extrapolated to the conditions of a DEMO reactor.« less

  2. Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet Flames

    DTIC Science & Technology

    2016-05-15

    serious problems in the development of liquid rocket engines. In order to understand and predict them, it is necessary to understand how representative...liquid rocket injector flames react to acoustic waves. In this study, a representative coaxial gaseous hydrogen / liquid oxygen (LOX) jet flame is...Combustion instabilities can pose serious problems in the development of liquid rocket engines. In order to under- stand and predict them, it is

  3. Development of a Very Dense Liquid Cooled Compute Platform

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hughes, Phillip N.; Lipp, Robert J.

    2013-12-10

    The objective of this project was to design and develop a prototype very energy efficient high density compute platform with 100% pumped refrigerant liquid cooling using commodity components and high volume manufacturing techniques. Testing at SLAC has indicated that we achieved a DCIE of 0.93 against our original goal of 0.85. This number includes both cooling and power supply and was achieved employing some of the highest wattage processors available.

  4. Liquid-liquid phase separation and solidification behavior of Al55Bi36Cu9 monotectic alloy with different cooling rates

    NASA Astrophysics Data System (ADS)

    Bo, Lin; Li, Shanshan; Wang, Lin; Wu, Di; Zuo, Min; Zhao, Degang

    2018-03-01

    The cooling rate has a significant effect on the solidification behavior and microstructure of monotectic alloy. In this study, different cooling rate was designed through casting in the copper mold with different bore diameters. The effects of different cooling rate on the solidification behavior of Al55Bi36Cu9 (at.%) immiscible alloy have been investigated. The liquid-liquid phase separation of Al55Bi36Cu9 immiscible alloy melt was investigated by resistivity test. The solidification microstructure and phase analysis of Al55Bi36Cu9 immiscible alloy were performed by the SEM and XRD, respectively. The results showed that the liquid-liquid phase separation occurred in the solidification of Al55Bi36Cu9 monotectic melt from 917 °C to 653 °C. The monotectic temperature, liquid phase separation temperature and immiscibility zone of Al55Bi36Cu9 monotectic alloy was lower than those of Al-Bi binary monotectic alloy. The solidification morphology of Al55Bi36Cu9 monotectic alloy was very sensitive to the cooling rate. The Al/Bi core-shell structure formed when Al55Bi36Cu9 melt was cast in the copper mold with a 8 mm bore diameter.

  5. Experimental Investigation of Shear Driven Liquid Films for Film Cooling Applications in Liquid Rocket Engines

    DTIC Science & Technology

    2012-12-01

    6 1.1.1 Differences Between Hot-Fire at Subcritical Conditions and Cold Flow ........10 1.1.2 Differences at Supercritical Conditions...cooling. 1.1.2 Differences at Supercritical Conditions Liquid film cooling is expected to behave even more differently at supercritical conditions...phase will behave more like the mixing of two gases of dissimilar densities. Once enough heat is imparted into the supercritical fuel film, it

  6. Liquid helium-cooled MOSFET preamplifier for use with astronomical bolometer

    NASA Technical Reports Server (NTRS)

    Goebel, J. H.

    1977-01-01

    A liquid helium-cooled p-channel enhancement mode MOSFET, the 3N167, is found to have sufficiently low noise for use as a preamplifier with helium-cooled bolometers that are used in infrared astronomy. Its characteristics at 300, 77, and 4.2 K are presented. It is also shown to have useful application with certain photoconductive and photovoltaic infrared detectors.

  7. Critical Current Test of Liquid Hydrogen Cooled HTC Superconductors under External Magnetic Field

    NASA Astrophysics Data System (ADS)

    Shirai, Yasuyuki; Shiotsu, Masahiro; Tatsumoto, Hideki; Kobayashi, Hiroaki; Naruo, Yoshihiro; Nonaka, Satoshi; Inatani, Yoshifumi

    High-Tc (HTC) superconductors including MgB2 will show excellent properties under temperature of Liquid Hydrogen (LH2:20K), which has large latent heat and low viscosity coefficient. In order to design and fabricate the LH2 cooled superconducting energy devices, we must clear the cooling property of LH2 for superconductors, the cooling system and safety design of LH2 cooled superconducting devices and electro-magnetic property evaluation of superconductors (BSCCO, REBCO and MgB2) and their magnets cooled by LH2. As the first step of the study, an experimental setup which can be used for investigating heat transfer characteristics of LH2 in a pool and also in forced flow (circulation loop with a pump), and also for evaluation of electro-magnetic properties of LH2 cooled superconductors under external magnetic field (up to 7 T). In this paper, we will show a short sketch of the experimental set-up, practical experiences in safety operation of liquid hydrogen cooling system and example test results of critical current evaluation of HTC superconductors cooled by LH2.

  8. Heat-driven liquid metal cooling device for the thermal management of a computer chip

    NASA Astrophysics Data System (ADS)

    Ma, Kun-Quan; Liu, Jing

    2007-08-01

    The tremendous heat generated in a computer chip or very large scale integrated circuit raises many challenging issues to be solved. Recently, liquid metal with a low melting point was established as the most conductive coolant for efficiently cooling the computer chip. Here, by making full use of the double merits of the liquid metal, i.e. superior heat transfer performance and electromagnetically drivable ability, we demonstrate for the first time the liquid-cooling concept for the thermal management of a computer chip using waste heat to power the thermoelectric generator (TEG) and thus the flow of the liquid metal. Such a device consumes no external net energy, which warrants it a self-supporting and completely silent liquid-cooling module. Experiments on devices driven by one or two stage TEGs indicate that a dramatic temperature drop on the simulating chip has been realized without the aid of any fans. The higher the heat load, the larger will be the temperature decrease caused by the cooling device. Further, the two TEGs will generate a larger current if a copper plate is sandwiched between them to enhance heat dissipation there. This new method is expected to be significant in future thermal management of a desk or notebook computer, where both efficient cooling and extremely low energy consumption are of major concern.

  9. Photodissociation of van der Waals clusters of isoprene with oxygen, C{sub 5}H{sub 8}-O{sub 2}, in the wavelength range 213-277 nm

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vidma, Konstantin V.; Frederix, Pim W. J. M.; Parker, David H.

    2012-08-07

    The speed and angular distribution of O atoms arising from the photofragmentation of C{sub 5}H{sub 8}-O{sub 2}, the isoprene-oxygen van der Waals complex, in the wavelength region of 213-277 nm has been studied with the use of a two-color dissociation-probe method and the velocity map imaging technique. Dramatic enhancement in the O atoms photo-generation cross section in comparison with the photodissociation of individual O{sub 2} molecules has been observed. Velocity map images of these 'enhanced' O atoms consisted of five channels, different in their kinetic energy, angular distribution, and wavelength dependence. Three channels are deduced to be due to themore » one-quantum excitation of the C{sub 5}H{sub 8}-O{sub 2} complex into the perturbed Herzberg III state ({sup 3}{Delta}{sub u}) of O{sub 2}. This excitation results in the prompt dissociation of the complex giving rise to products C{sub 5}H{sub 8}+O+O when the energy of exciting quantum is higher than the complex photodissociation threshold, which is found to be 41740 {+-} 200 cm{sup -1} (239.6{+-}1.2 nm). This last threshold corresponds to the photodissociation giving rise to an unexcited isoprene molecule. The second channel, with threshold shifted to the blue by 1480 {+-} 280 cm{sup -1}, corresponds to dissociation with formation of rovibrationally excited isoprene. A third channel was observed at wavelengths up to 243 nm with excitation below the upper photodissociation threshold. This channel is attributed to dissociation with the formation of a bound O atom C{sub 5}H{sub 8}-O{sub 2}+hv{yields} C{sub 5}H{sub 8}-O{sub 2}({sup 3}{Delta}{sub u}) {yields} C{sub 5}H{sub 8}O + O and/or to dissociation of O{sub 2} with borrowing of the lacking energy from incompletely cooled complex internal degrees of freedom C{sub 5}H{sub 8}{sup *}-O{sub 2}+hv{yields} C{sub 5}H{sub 8}{sup *}-O{sub 2}({sup 3}{Delta}{sub u}) {yields} C{sub 5}H{sub 8}+ O + O. The kinetic energy of the O atoms arising in two other observed

  10. Performance of the dark energy camera liquid nitrogen cooling system

    NASA Astrophysics Data System (ADS)

    Cease, H.; Alvarez, M.; Alvarez, R.; Bonati, M.; Derylo, G.; Estrada, J.; Flaugher, B.; Flores, R.; Lathrop, A.; Munoz, F.; Schmidt, R.; Schmitt, R. L.; Schultz, K.; Kuhlmann, S.; Zhao, A.

    2014-01-01

    The Dark Energy Camera, the Imager and its cooling system was installed onto the Blanco 4m telescope at the Cerro Tololo Inter-American Observatory in Chile in September 2012. The imager cooling system is a LN2 two-phase closed loop cryogenic cooling system. The cryogenic circulation processing is located off the telescope. Liquid nitrogen vacuum jacketed transfer lines are run up the outside of the telescope truss tubes to the imager inside the prime focus cage. The design of the cooling system along with commissioning experiences and initial cooling system performance is described. The LN2 cooling system with the DES imager was initially operated at Fermilab for testing, then shipped and tested in the Blanco Coudé room. Now the imager is operating inside the prime focus cage. It is shown that the cooling performance sufficiently cools the imager in a closed loop mode, which can operate for extended time periods without maintenance or LN2 fills.

  11. Hemoglobin crystals immersed in liquid oxygen reveal diffusion channels.

    PubMed

    Terrell, James Ross; Gumpper, Ryan H; Luo, Ming

    2018-01-08

    Human hemoglobin (HbA) transports molecular oxygen (O 2 ) from the lung to tissues where the partial pressure of O 2 is lower. O 2 binds to HbA at the heme cofactor and is stabilized by a distal histidine (HisE7). HisE7 has been observed to occupy opened and closed conformations, and is postulated to act as a gate controlling the binding/release of O 2 . However, it has been suggested that HbA also contains intraprotein oxygen channels for entrances/exits far from the heme. In this study, we developed a novel method of crystal immersion in liquid oxygen prior to X-ray data collection. In the crystals immersed in liquid oxygen, the heme center was oxidized to generate aquomethemoglobin. Increases of structural flexibility were also observed in regions that are synonymous with previously postulated oxygen channels. These regions also correspond to medically relevant mutations which affect O 2 affinity. The way HbA utilizes these O 2 channels could have a profound impact on understanding the relationship of HbA O 2 transport within these disease conditions. Finally, the liquid oxygen immersion technique can be utilized as a new tool to crystallographically examine proteins and protein complexes which utilize O 2 for enzyme catalysis or transport. Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Theoretical model for Sub-Doppler Cooling with EIT System

    NASA Astrophysics Data System (ADS)

    He, Peiru; Tengdin, Phoebe; Anderson, Dana; Rey, Ana Maria; Holland, Murray

    2016-05-01

    We propose a of sub-Doppler cooling mechanism that takes advantage of the unique spectral features and extreme dispersion generated by the so-called Electromagnetically Induced Transparency (EIT) effect, a destructive quantum interference phenomenon experienced by atoms with Lambda-shaped energy levels when illuminated by two light fields with appropriate frequencies. By detuning the probe lasers slightly from the ``dark resonance'', we observe that atoms can be significantly cooled down by the strong viscous force within the transparency window, while being just slightly heated by the diffusion caused by the small absorption near resonance. In contrast to polarization gradient cooling or EIT sideband cooling, no external magnetic field or external confining potential are required. Using a semi-classical method, analytical expressions, and numerical simulations, we demonstrate that the proposed EIT cooling method can lead to temperatures well below the Doppler limit. This work is supported by NSF and NIST.

  13. Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

    DOEpatents

    Mei, Viung C.; Chen, Fang C.

    1997-01-01

    A refrigeration system having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle.

  14. Oxygen potentials and phase equilibria in the system Ca–Co–O and thermodynamic properties of Ca{sub 3}Co{sub 2}O{sub 6} and Ca{sub 3}Co{sub 4}O{sub 9.163}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jacob, K.T., E-mail: katob@materials.iisc.ernet.in; Gupta, Preeti

    2015-01-15

    Oxygen potentials established by the equilibrium between three condensed phases, CaO{sub ss}+CoO{sub ss}+Ca{sub 3}Co{sub 2}O{sub 6} and CoO{sub ss}+Ca{sub 3}Co{sub 2}O{sub 6}+Ca{sub 3}Co{sub 3.93+α}O{sub 9.36−δ}, are measured as a function of temperature using solid-state electrochemical cells incorporating yttria-stabilized zirconia as the electrolyte and pure oxygen as the reference electrode. Cation non-stoichiometry and oxygen non-stoichiometry in Ca{sub 3}Co{sub 3.93+α}O{sub 9.36−δ} are determined using different techniques under defined conditions. Decomposition temperatures and thermodynamic properties of Ca{sub 3}Co{sub 2}O{sub 6} and Ca{sub 3}Co{sub 4}O{sub 9.163} are calculated from the results. The standard entropy and enthalpy of formation of Ca{sub 3}Co{sub 2}O{sub 6} atmore » 298.15 K are evaluated. Using thermodynamic data from this study and auxiliary information from the literature, phase diagram for the ternary system Ca–Co–O is computed. Isothermal sections at representative temperatures are displayed to demonstrate the evolution of phase relations with temperature. - Graphical abstract: Isothermal section of the phase diagram of the system Ca–Co–O at 1250 K. - Highlights: • Improved definition of cation and oxygen nonstoichiometry of Ca{sub 3}Co{sub 3.93+α}O{sub 9.36−δ}. • Measurement of Δμ{sub O{sub 2}} associated with two 3-phase fields as a function of temperature. • Use of solid-state electrochemical cells for accurate measurement of Δμ{sub O{sub 2}}. • Decomposition temperatures and thermodynamic properties for ternary oxides. • Characterization of ternary phase diagram of the system Ca–Co–O.« less

  15. Lumped Multi-Bubble Analysis of Injection Cooling System for Storage of Cryogenic Liquids

    NASA Astrophysics Data System (ADS)

    Saha, Pritam; Sandilya, Pavitra

    2017-12-01

    Storage of cryogenic liquids is a critical issue in many cryogenic applications. Subcooling of the liquid by bubbling a gas has been suggested to extend the storage period by reducing the boil-off loss. Liquid evaporation into the gas may cause liquid subcooling by extracting the latent heat of vaporization from the liquid. The present study aims at studying the factors affecting the liquid subcooling during gas injection. A lumped parameter model is presented to capture the effects of bubble dynamics (coalescence, breakup, deformation etc.) on the heat and mass transport between the gas and the liquid. The liquid subcooling has been estimated as a function of the key operating variables such as gas flow rate and gas injection temperature. Numerical results have been found to predict the change in the liquid temperature drop reasonably well when compared with the previously reported experimental results. This modelling approach can therefore be used in gauging the significance of various process variables on the liquid subcooling by injection cooling, as well as in designing and rating an injection cooling system.

  16. Microscale Demonstration of the Paramagnetism of Liquid Oxygen with a Neodymium Magnet

    ERIC Educational Resources Information Center

    Mattson, Bruce

    2007-01-01

    A microscale classroom demonstration of the paramagnetic behavior of various samples of liquid oxygen with neodymium magnet is being presented. The experiment should be done with extreme caution, as liquid oxygen reacts violently with organic matters.

  17. Effect of oxygen compounds addition on the hydrocracking of coal derived liquid

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sato, Yoshiki; Kodera, Yoichi; Kamo, Tohru

    1998-12-31

    Coal derived liquid from liquefaction, coking and low temperature pyrolysis contains considerable amounts of alkylphenols with alkylbenzenes and alkylnaphthalenes. To produce and purify useful chemicals from coal-derived liquid, hydrocracking and hydrotreating of alkylphenol mixture is a very important process. In this study the effects of oxygen compounds such as dimethylcarbonate (DMC) addition on the hydrocracking of alkylphenols and coal-derived liquid were investigated to decrease hydrogen consumption due to the production of water from the removal of OH group. From the hydrocracking of 3,5-dimethylphenol (3,5-DMP) without DMC at 700 C, residence time of 3--10 sec under hydrogen-to-reactant molar ratio of moremore » than 10 using atmospheric flow apparatus with quartz reactor, m-xylene and m-cresol were produced with the production ratio of 1:1.8. However the dehydroxylation to produce m-xylene was decreased by the addition of 10% DMC with the 50% increased production ratio of 1:2.7. These are considered due to the strong interaction between OH group and DMC. Similar reaction behavior was observed in the hydrocracking of 2,5-DMP and the production ratio of (o-cresol + m-cresol)/p-xylene slightly increased from 3.0 to 3.5 by the addition of DMC. On the other hand, the products distribution did not change with and without DMC in the case of 2,6-DMP. This indicates the interaction is hindered by steric effect by the neighboring CH{sub 3} group. The effect of other oxygen compounds on the hydrocracking and the products distribution from the hydrocracking of coal-derived liquids is also discussed.« less

  18. Performance of a Small Gas Generator Using Liquid Hydrogen and Liquid Oxygen

    NASA Technical Reports Server (NTRS)

    Acker, Loren W.; Fenn, David B.; Dietrich, Marshall W.

    1961-01-01

    The performance and operating problems of a small hot-gas generator burning liquid hydrogen with liquid oxygen are presented. Two methods of ignition are discussed. Injector and combustion chamber design details based on rocket design criteria are also given. A carefully fabricated showerhead injector of simple design provided a gas generator that yielded combustion efficiencies of 93 and 96 percent.

  19. Thermal management of VECSELs by front surface direct liquid cooling

    NASA Astrophysics Data System (ADS)

    Smyth, Conor J. C.; Mirkhanov, Shamil; Quarterman, Adrian H.; Wilcox, Keith G.

    2016-03-01

    Efficient thermal management is vital for VECSELs, affecting the output power and several aspects of performance of the device. Presently there exist two distinct methods of effective thermal management which both possess their merits and disadvantages. Substrate removal of the VECSEL gain chip has proved a successful method in devices emitting at a wavelength near 1μm. However for other wavelengths the substrate removal technique has proved less effective primarily due to the thermal impedance of the distributed Bragg reflectors. The second method of thermal management involves the use of crystalline heat spreaders bonded to the gain chip surface. Although this is an effective thermal management scheme, the disadvantages are additional loss and the etalon effect that filters the gain spectrum, making mode locking more difficult and normally resulting in multiple peaks in the spectrum. There are considerable disadvantages associated with both methods attributed to heatspreader cost and sample processing. It is for these reasons that a proposed alternative, front surface liquid cooling, has been investigated in this project. Direct liquid cooling involves flowing a temperature-controlled liquid over the sample's surface. In this project COMSOL was used to model surface liquid cooling of a VECSEL sample in order to investigate and compare its potential thermal management with current standard thermal management techniques. Based on modelling, experiments were carried out in order to evaluate the performance of the technique. While modelling suggests that this is potentially a mid-performance low cost alternative to existing techniques, experimental measurements to date do not reflect the performance predicted from modelling.

  20. The oxygen content of the high-temperature superconducting compound Bi{sub 2+x}Sr{sub 3-y}CayCu{sub 2}O{sub 8+d} with respect to varying Ca and Bi contents

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Majewski, P.; Su, H.L.; Aldinger, F.

    1994-12-31

    The oxygen content of Bi{sub 2+x}Sr{sub 3-y}Ca{sub y}Cu{sub 2}O{sub 8+d} (2212 phase) has been determined as a function of its cation concentration. With increasing Ca and Bi content the oxygen content increases and T{sub c} decreases. The oxygen content of Ca rich 2212 phase increases with decreasing annealing temperatures. The study shows that the T{sub c} of the 2212 phase primarily is controlled by its cation concentration.

  1. Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

    DOEpatents

    Mei, V.C.; Chen, F.C.

    1997-04-22

    A refrigeration system is described having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle. 4 figs.

  2. Design study of steady-state 30-tesla liquid-neon-cooled magnet

    NASA Technical Reports Server (NTRS)

    Prok, G. M.; Brown, G. V.

    1976-01-01

    A design for a 30-tesla, liquid-neon-cooled magnet was reported which is capable of continuous operation. Cooled by nonboiling, forced-convection heat transfer to liquid neon flowing at 2.8 cu m/min in a closed, pressurized heat-transfer loop and structurally supported by a tapered structural ribbon, the tape-wound coils with a high-purity-aluminum conductor will produce over 30 teslas for 1 minute at 850 kilowatts. The magnet will have an inside diameter of 7.5 centimeters and an outside diameter of 54 centimeters. The minimum current density at design field will be 15.7 kA/sq cm.

  3. Liquid-cooled clothing for hot mine rescue work

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1979-04-01

    To prevent exhaustion caused by thermal stress, a rescuer can wear a liquid-cooled hood and vest which absorbs heat, thereby reducing the heat-induced strain on the rescuer's heart and circulatory system. Liquid coolant is continuously circulated through a self-contained system in which the coolant is chilled by a heat sink on the wearer's belt. Cooling duration is approximately 40 minutes when both the hood and vest are worn. Tests were conducted at NASA's Ames Research Center to evaluate the effectiveness of this system. When using the hood and vest with a refrigerated water supply, thermal strain on the wearer wasmore » cut in half and the heart rate was reduced by 30 to 50 beats per minute. Body temperature was significantly lowered, about 0.65/sup 0/C. This system can increase safety for rescue workers who must work in a hot environment, especially when they are not acclimated to high temperaures. Laboratory tests also were conducted using members of a mine rescue team.« less

  4. Liquid oxygen/metal gelled monopropellants

    NASA Technical Reports Server (NTRS)

    Wickman, John H.

    1991-01-01

    The objectives of this program were to establish the feasibility of metallized/liquid oxygen monopropellants and select the best monopropellant formulation for continued study. The metal powders mixed with the liquid oxygen were aluminum/magnesium (80/20), silicon and iron (Iron was only tested for burning properties). The formulations were first evaluated on whether they detonated when ignited or burned. The formulations only burned when ignited. The viscosity for the formulations ranged from 900 cps to 100 cps at shear rates up to 300 seconds(sup -1). Two percent (by weight) of Cab-O-Sil was added to the aluminum and aluminum/magnesium formulations for gelling while the silicon formulation used three percent. Within a seven hour period, settling was suggested only in the 29 percent aluminum and 29 percent aluminum/magnesium formulations. The monopropellants were burned in a cylinder submerged in a liquid nitrogen bath. Experimental data at ambient pressure indicated that the monopropellants were extinguished when the flame front reached regions submerged under the liquid nitrogen. The burn rate increased dramatically when burned in a cylinder enclosure with less heat sink available to the monopropellant. The test results were inconclusive as to whether the increased burn rate was due to the lower heat sink capacity or the small amount of pressure (2 psi) generated during the burning of the monopropellant. The burning of the aluminum and aluminum/magnesium resulted in a brilliant white flame similar to that of an arc welder. These monopropellants burned in a pulsating manner with the aluminum/magnesium appearing to have less pulsating combustion. The silicon monopropellant burned with an orange glow. No sparks or energetic burning was apparent as with the aluminum or aluminum/magnesium.

  5. Oxygen mobility in CeO{sub 2} and Ce{sub x}Zr({sub 1-x})O{sub 2} compounds: Study by CO transient oxidation and {sup 18}O/{sup 16}O isotopic exchange

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Madier, Y.; Descorme, C.; Govic, A.M. Le

    Cerium-zirconium mixed oxides (Ce{sub x}Zr{sub 1{minus}x}O{sub 2}), precalcined at 900 C in dry air, were supplied by Rhodia Terres Rares as monophasic solid solutions. Introduction of some zirconium atoms in the ceria lattice by isomorphous substitution clearly influences the final properties of these materials as long as the cubic structure of ceria is maintained. Modifications in oxygen storage capacity (OSC measurements), redox properties (CO TPR), and oxygen exchange processes (TPIE) were studied. Ce{sub 0.63}Zr{sub 0.37}O{sub 2} was shown to have the most promising properties with the largest OSC at 400 C and the highest reactivity in O{sub 2} exchange. Allmore » mixed oxides are able to exchange very large amounts of oxygen compared to ceria, implying the participation of bulk oxygen. Furthermore, on Ce{sub x}Zr{sub (1{minus}x)}O{sub 2} samples, oxygen is predominantly exchanged via a multiple heteroexchange mechanism involving surface dioxygen species as superoxides or peroxides.« less

  6. Establishment of a total liquid ventilation system using saline-based oxygen micro/nano-bubble dispersions in rats.

    PubMed

    Kakiuchi, Kenta; Matsuda, Kenichi; Harii, Norikazu; Sou, Keitaro; Aoki, Junko; Takeoka, Shinji

    2015-09-01

    Micro/nano-bubbles are practical nanomaterials designed to increase the gas content in liquids. We attempted to use oxygen micro/nano-bubble dispersions as an oxygen-rich liquid as a means for total liquid ventilation. To determine the oxygen content in the bubble dispersion, a new method based on a spectrophotometric change between oxy- and deoxy-hemoglobin was established. The oxygen micro/nano-bubble dispersion was supplied to an experimental total ventilation liquid in anesthetic rats. Though the amount of dissolving oxygen was as low as 6 mg/L in physiological saline, the oxygen content in the oxygen micro/nano-bubble dispersion was increased to 45 mg/L. The positive correlation between the oxygen content and the life-saving time under liquid ventilation clearly indicates that the life-saving time is prolonged by increasing the oxygen content in the oxygen micro/nano-bubble dispersion. This is the first report indicating that the oxygen micro/nano-bubbles containing a sufficient amount of oxygen are useful in producing oxygen-rich liquid for the process of liquid ventilation.

  7. Enhancement of Cognitive Processing by Multiple Sclerosis Patients Using Liquid Cooling Technology: A Case Study

    NASA Technical Reports Server (NTRS)

    Montgomery, Leslie D.; Montgomery, Richard W.; Ku, Yu-Tsuan; Luna, Bernadette (Technical Monitor)

    1997-01-01

    Cognitive dysfunction is a common symptom in patients with multiple sclerosis (MS). This can have a significant impact on the quality of life of both the patient and of their primary care giver. This case study explores the possibility that liquid cooling therapy may be used to enhance the cognitive processing of MS patients in the same way that it provides temporary relief of some physical impairment. Two MS patients were presented a series of pattern discrimination tasks before and after being cooled with a liquid cooling garment for a one hour period. The subject whose ear temperature was reduced during cooling showed greater electroencephalographic (EEG) activity and scored much better on the task after cooling. The patient whose ear temperature was unaffected by cooling showed less EEG activity and degraded performance after the one hour cooling period.

  8. Innovation Incubator: LiquidCool Solutions Technical Evaluation. Laboratory Study and Demonstration Results of a Directed-Flow, Liquid Submerged Server for High-Efficiency Data Centers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kozubal, Eric J

    LiquidCool Solutions (LCS) has developed liquid submerged server (LSS) technology that changes the way computer electronics are cooled. The technology provides an option to cool electronics by the direct contact flow of dielectric fluid (coolant) into a sealed enclosure housing all the electronics of a single server. The intimate dielectric fluid contact with electronics improves the effectiveness of heat removal from the electronics.

  9. Crystal structure and magnetic properties of high-oxygen pressure annealed Sr{sub 1-x}La{sub x}Co{sub 0.5}Fe{sub 0.5}O{sub 3-{delta}} (0{<=}x{<=}0.5)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Swierczek, Konrad; Materials Science Division, Argonne National Laboratory, Argonne, IL 60439; Dabrowski, Bogdan

    2009-02-15

    Structural and magnetic studies are presented for the perovskite type Sr{sub 1-x}La{sub x}Co{sub 0.5}Fe{sub 0.5}O{sub 3-{delta}} (0{<=}x{<=}0.5) materials annealed under moderately high-oxygen pressures of {approx}200 atm. A detailed analysis of the room temperature neutron time-of-flight diffraction data reveals that the crystal structure of the sample SrCo{sub 0.5}Fe{sub 0.5}O{sub 2.89(1)}, previously described as vacancy-disordered cubic, is similar to the formerly reported, oxygen-vacancy ordered Sr{sub 8}Fe{sub 8}O{sub 23} compound, i.e. Sr{sub 8}Co{sub 4}Fe{sub 4}O{sub 23} is tetragonal with the I4/mmm symmetry. With an increase of the La content the studied materials become nearly oxygen stoichiometric and a lowering of the crystal symmetrymore » is observed from cubic Pm3-barm (x=0.1 and 0.2) to tetragonal I4/mcm (x=0.3 and 0.4), and finally to monoclinic I12/c1 (x=0.5). Low-temperature structural and magnetic measurements show a ferromagnetic ordering with the maximum Curie temperature near 290 K at x=0.2. - Graphical Abstract: Room temperature Rietveld refinement profile using I4/mmm space group for the oxygen vacancy ordered SrCo{sub 0.5}Fe{sub 0.5}O{sub 2.89} (Sr{sub 8}Co{sub 4}Fe{sub 4}O{sub 23}). Top tick-marks denote allowed reflections in I4/mmm, bottom one emphasize the possibility of inexact indexing using Pm3-barm symmetry. Previous reports indicate that similar ordering is common for SrCo{sub 1-x}Fe{sub x}O{sub 3-{delta}} compounds possibly hindering their applications.« less

  10. Cooled electronic system with liquid-cooled cold plate and thermal spreader coupled to electronic component

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chainer, Timothy J.; Graybill, David P.; Iyengar, Madhusudan K.

    Apparatus and method are provided for facilitating cooling of an electronic component. The apparatus includes a liquid-cooled cold plate and a thermal spreader associated with the cold plate. The cold plate includes multiple coolant-carrying channel sections extending within the cold plate, and a thermal conduction surface with a larger surface area than a surface area of the component to be cooled. The thermal spreader includes one or more heat pipes including multiple heat pipe sections. One or more heat pipe sections are partially aligned to a first region of the cold plate, that is, where aligned to the surface tomore » be cooled, and partially aligned to a second region of the cold plate, which is outside the first region. The one or more heat pipes facilitate distribution of heat from the electronic component to coolant-carrying channel sections of the cold plate located in the second region of the cold plate.« less

  11. Cooled electronic system with liquid-cooled cold plate and thermal spreader coupled to electronic component

    DOEpatents

    Chainer, Timothy J.; Graybill, David P.; Iyengar, Madhusudan K.; Kamath, Vinod; Kochuparambil, Bejoy J.; Schmidt, Roger R.; Steinke, Mark E.

    2016-08-09

    Apparatus and method are provided for facilitating cooling of an electronic component. The apparatus includes a liquid-cooled cold plate and a thermal spreader associated with the cold plate. The cold plate includes multiple coolant-carrying channel sections extending within the cold plate, and a thermal conduction surface with a larger surface area than a surface area of the component to be cooled. The thermal spreader includes one or more heat pipes including multiple heat pipe sections. One or more heat pipe sections are partially aligned to a first region of the cold plate, that is, where aligned to the surface to be cooled, and partially aligned to a second region of the cold plate, which is outside the first region. The one or more heat pipes facilitate distribution of heat from the electronic component to coolant-carrying channel sections of the cold plate located in the second region of the cold plate.

  12. Cooled electronic system with liquid-cooled cold plate and thermal spreader coupled to electronic component

    DOEpatents

    Chainer, Timothy J.; Graybill, David P.; Iyengar, Madhusudan K.; Kamath, Vinod; Kochuparambil, Bejoy J.; Schmidt, Roger R.; Steinke, Mark E.

    2016-04-05

    Apparatus and method are provided for facilitating cooling of an electronic component. The apparatus includes a liquid-cooled cold plate and a thermal spreader associated with the cold plate. The cold plate includes multiple coolant-carrying channel sections extending within the cold plate, and a thermal conduction surface with a larger surface area than a surface area of the component to be cooled. The thermal spreader includes one or more heat pipes including multiple heat pipe sections. One or more heat pipe sections are partially aligned to a first region of the cold plate, that is, where aligned to the surface to be cooled, and partially aligned to a second region of the cold plate, which is outside the first region. The one or more heat pipes facilitate distribution of heat from the electronic component to coolant-carrying channel sections of the cold plate located in the second region of the cold plate.

  13. Liquid Hydrogen Recirculation System for Forced Flow Cooling Test of Superconducting Conductors

    NASA Astrophysics Data System (ADS)

    Shirai, Y.; Kainuma, T.; Shigeta, H.; Shiotsu, M.; Tatsumoto, H.; Naruo, Y.; Kobayashi, H.; Nonaka, S.; Inatani, Y.; Yoshinaga, S.

    2017-12-01

    The knowledge of forced flow heat transfer characteristics of liquid hydrogen (LH2) is important and necessary for design and cooling analysis of high critical temperature superconducting devices. However, there are few test facilities available for LH2 forced flow cooling for superconductors. A test system to provide a LH2 forced flow (∼10 m/s) of a short period (less than 100 s) has been developed. The test system was composed of two LH2 tanks connected by a transfer line with a controllable valve, in which the forced flow rate and its period were limited by the storage capacity of tanks. In this paper, a liquid hydrogen recirculation system, which was designed and fabricated in order to study characteristics of superconducting cables in a stable forced flow of liquid hydrogen for longer period, was described. This LH2 loop system consists of a centrifugal pump with dynamic gas bearings, a heat exchanger which is immersed in a liquid hydrogen tank, and a buffer tank where a test section (superconducting wires or cables) is set. The buffer tank has LHe cooled superconducting magnet which can produce an external magnetic field (up to 7T) at the test section. A performance test was conducted. The maximum flow rate was 43.7 g/s. The lowest temperature was 22.5 K. It was confirmed that the liquid hydrogen can stably circulate for 7 hours.

  14. Induced polarized state in intentionally grown oxygen deficient KTaO{sub 3} thin films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mota, D. A.; Romaguera-Barcelay, Y.; Tkach, A.

    2013-07-21

    Deliberately oxygen deficient potassium tantalate thin films were grown by RF magnetron sputtering on Si/SiO{sub 2}/Ti/Pt substrates. Once they were structurally characterized, the effect of oxygen vacancies on their electric properties was addressed by measuring leakage currents, dielectric constant, electric polarization, and thermally stimulated depolarization currents. By using K{sub 2}O rich KTaO{sub 3} targets and specific deposition conditions, KTaO{sub 3-{delta}} oxygen deficient thin films with a K/Ta = 1 ratio were obtained. Room temperature X-ray diffraction patterns show that KTaO{sub 3-{delta}} thin films are under a compressive strain of 2.3% relative to KTaO{sub 3} crystals. Leakage current results reveal themore » presence of a conductive mechanism, following the Poole-Frenkel formalism. Furthermore, dielectric, polarization, and depolarization current measurements yield the existence of a polarized state below T{sub pol} {approx} 367 Degree-Sign C. A Cole-Cole dipolar relaxation was also ascertained apparently due to oxygen vacancies induced dipoles. After thermal annealing the films in an oxygen atmosphere at a temperature above T{sub pol}, the aforementioned polarized state is suppressed, associated with a drastic oxygen vacancies reduction emerging from annealing process.« less

  15. Cycle Design of Reverse Brayton Cryocooler for HTS Cable Cooling Using Exergy Analysis

    NASA Astrophysics Data System (ADS)

    Gupta, Sudeep Kumar; Ghosh, Parthasarathi

    2017-02-01

    The reliability and price of cryogenic refrigeration play an important role in the successful commercialization of High Temperature Superconducting (HTS) cables. For cooling HTS cable, sub-cooled liquid nitrogen (LN2) circulation system is used. One of the options to maintain LN2 in its sub-cooled state is by providing refrigeration with the help of Reverse Brayton Cryo-cooler (RBC). The refrigeration requirement is 10 kW for continuously sub-cooling LN2 from 72 K to 65 K for cooling 1 km length of HTS cable [1]. In this paper, a parametric evaluation of RBC for sub-cooling LN2 has been performed using helium as a process fluid. Exergy approach has been adopted for this analysis. A commercial process simulator, Aspen HYSYS® V8.6 has been used for this purpose. The critical components have been identified and their exergy destruction and exergy efficiency have been obtained for a given heat load condition.

  16. The Productivity of Oxygenic Photosynthesis around Cool, M Dwarf Stars

    NASA Astrophysics Data System (ADS)

    Lehmer, Owen R.; Catling, David C.; Parenteau, Mary N.; Hoehler, Tori M.

    2018-06-01

    In the search for life around cool stars, the presence of atmospheric oxygen is a prominent biosignature, as it may indicate oxygenic photosynthesis (OP) on the planetary surface. On Earth, most oxygenic photosynthesizing organisms (OPOs) use photons between 400 and 750 nm, which have sufficient energy to drive the photosynthetic reaction that generates O2 from H2O and CO2. OPOs around cool stars may evolve similar biological machinery capable of producing oxygen from water. However, in the habitable zones (HZs) of the coolest M dwarf stars, the flux of 400–750 nm photons may be just a few percent that of Earth’s. We show that the reduced flux of 400–750 nm photons around M dwarf stars could result in Earth-like planets being growth limited by light, unlike the terrestrial biosphere, which is limited by nutrient availability. We consider stars with photospheric temperatures between 2300 and 4200 K and show that such light-limited worlds could occur at the outer edge of the HZ around TRAPPIST-1-like stars. We find that even if OP can use photons longer than 750 nm, there would still be insufficient energy to sustain the Earth’s extant biosphere throughout the HZ of the coolest stars. This is because such stars emit largely in the infrared and near-infrared, which provide sufficient energy to make the planet habitable, but limits the energy available for OP. TRAPPIST-1f and g may fall into this category. Biospheres on such planets, potentially limited by photon availability, may generate small biogenic signals, which could be difficult for future observations to detect.

  17. Liquid-like cationic sub-lattice in copper selenide clusters

    NASA Astrophysics Data System (ADS)

    White, Sarah L.; Banerjee, Progna; Jain, Prashant K.

    2017-02-01

    Super-ionic solids, which exhibit ion mobilities as high as those in liquids or molten salts, have been employed as solid-state electrolytes in batteries, improved thermoelectrics and fast-ion conductors in super-capacitors and fuel cells. Fast-ion transport in many of these solids is supported by a disordered, `liquid-like' sub-lattice of cations mobile within a rigid anionic sub-lattice, often achieved at high temperatures or pressures via a phase transition. Here we show that ultrasmall clusters of copper selenide exhibit a disordered cationic sub-lattice under ambient conditions unlike larger nanocrystals, where Cu+ ions and vacancies form an ordered super-structure similar to the bulk solid. The clusters exhibit an unusual cationic sub-lattice arrangement wherein octahedral sites, which serve as bridges for cation migration, are stabilized by compressive strain. The room-temperature liquid-like nature of the Cu+ sub-lattice combined with the actively tunable plasmonic properties of the Cu2Se clusters make them suitable as fast electro-optic switches.

  18. Nano scale dynamics of bubble nucleation in confined liquid subjected to rapid cooling: Effect of solid-liquid interfacial wettability

    NASA Astrophysics Data System (ADS)

    Hasan, Mohammad Nasim; Rabbi, Kazi Fazle; Mukut, K. M.; Tamim, Saiful Islam; Faisal, A. H. M.

    2017-06-01

    This study focuses on the occurrence of bubble nucleation in a liquid confined in a nano scale confinement and subjected to rapid cooling at one of its wall. Due to the very small size scale of the present problem, we adopt the molecular dynamics (MD) approach. The liquid (Argon) is confined within two solid (Platinum) walls. The temperature of the upper wall of the confinement is maintained at 90 K while the lower wall is being cooled rapidly to 50 K from initial equilibrium temperature of 90 K within 0.1 ns. This results in the nucleation and formation of nanobubbles in the liquid. The pattern of bubble nucleation has been studied for three different conditions of solid-liquid interfacial wettability such as hydrophilic, hydrophobic and neutral. Behavior of bubble nucleation is significantly different in the three case of solid-liquid interfacial wettability. In case of the hydrophobic confinement (weakly adsorbing), the liquid cannot achieve deeper metastability; vapor layers appear immediately on the walls. In case of the neutral confinement (moderately adsorbing), bubble nucleation is promoted by the walls where the nucleation is heterogeneous. In case of the hydrophilic walls (strongly adsorbing) bubbles are developed inside the liquid; that is the nucleation process is homogeneous. The variation in bubble nucleation under different conditions of surface wettability has been studied by the analysis of number density distribution, spatial temperature distribution, spatial number density distribution and heat flux through the upper and lower walls of the confinement. The present study indicates that the variation of heat transfer efficiency due to different surface wettability has significant effect on the size, shape and location of bubble nucleation in case rapid cooling of liquid in nano confinement.

  19. Desorption of oxygen from alloyed Ag/Pt(111)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jankowski, Maciej; Wormeester, Herbert, E-mail: h.wormeester@utwente.nl; Zandvliet, Harold J. W.

    2014-06-21

    We have investigated the interaction of oxygen with the Ag/Pt(111) surface alloy by thermal desorption spectroscopy (TDS). The surface alloy was formed during the deposition of sub-monolayer amounts of silver on Pt(111) at 800 K and subsequent cooling to 300 K. The low-temperature phase of the surface alloy is composed of nanometer-sized silver rich stripes, embedded within platinum-rich domains, which were characterized with spot profile analysis low energy electron diffraction. The TDS measurements show that oxygen adsorption is blocked on Ag sites: the saturation coverage of oxygen decreases with increasing Ag coverage. Also, the activation energy for desorption (E{sub des})more » decreases with Ag coverage. The analysis of the desorption spectra from clean Pt(111) shows a linear decay of E{sub des} with oxygen coverage, which indicates repulsive interactions between the adsorbed oxygen atoms. In contrast, adsorption on alloyed Ag/Pt(111) leads to an attractive interaction between adsorbed oxygen atoms.« less

  20. Passive air cooling of liquid metal-cooled reactor with double vessel leak accommodation capability

    DOEpatents

    Hunsbedt, A.; Boardman, C.E.

    1995-04-11

    A passive and inherent shutdown heat removal method with a backup air flow path which allows decay heat removal following a postulated double vessel leak event in a liquid metal-cooled nuclear reactor is disclosed. The improved reactor design incorporates the following features: (1) isolation capability of the reactor cavity environment in the event that simultaneous leaks develop in both the reactor and containment vessels; (2) a reactor silo liner tank which insulates the concrete silo from the leaked sodium, thereby preserving the silo`s structural integrity; and (3) a second, independent air cooling flow path via tubes submerged in the leaked sodium which will maintain shutdown heat removal after the normal flow path has been isolated. 5 figures.

  1. Passive air cooling of liquid metal-cooled reactor with double vessel leak accommodation capability

    DOEpatents

    Hunsbedt, Anstein; Boardman, Charles E.

    1995-01-01

    A passive and inherent shutdown heat removal method with a backup air flow path which allows decay heat removal following a postulated double vessel leak event in a liquid metal-cooled nuclear reactor. The improved reactor design incorporates the following features: (1) isolation capability of the reactor cavity environment in the event that simultaneous leaks develop in both the reactor and containment vessels; (2) a reactor silo liner tank which insulates the concrete silo from the leaked sodium, thereby preserving the silo's structural integrity; and (3) a second, independent air cooling flow path via tubes submerged in the leaked sodium which will maintain shutdown heat removal after the normal flow path has been isolated.

  2. High Voltage, Sub Nanosecond Feedthrough Design for Liquid Breakdown Studies

    NASA Astrophysics Data System (ADS)

    Cevallos, Michael; Dickens, James; Neuber, Andreas; Krompholz, Herman

    2002-12-01

    Experiments in self-breakdown mode and pulsed breakdown at high over-voltages in standard electrode geometries are performed for liquids to gain a better understanding of their fundamental breakdown physics. Different liquids of interest include liquids such as super-cooled liquid nitrogen, oils, glycerols and water. A typical setup employs a discharge chamber with a cable discharge into a coaxial system with axial discharge, and a load line to simulate a matched terminating impedance, thus providing a sub-nanosecond response. This study is focused on the feed-through design of the coaxial cable into this type of discharge chamber, with the feed-through being the critical element with respect to maximum hold-off voltage. Diverse feedthroughs were designed and simulated using Maxwell 3-D Field Simulator Version 5. Several geometrically shaped feed-through transitions were simulated, including linearly and exponentially tapered, to minimize electrostatic fields, thus ensuring that the discharge occurs in the volume of interest and not between the inner and outer conductor at the transition from the insulation of the coaxial cable to the liquid. All feedthroughs are designed to match the incoming impedance of the coaxial cable. The size of the feedthroughs will vary from liquid to liquid in order to match the coaxial cable impedance of 50Ω. The discharge chamber has two main ports where the feed-through will enter the chamber. Each feed-through is built through a flange that covers the two main ports. This allows the use of the same discharge chamber for various liquids by changing the flanges on the main ports to match the particular liquid. The feedthroughs were designed and built to withstand voltages of up to 200 kV. The feedthroughs are also fitted with transmission line type current sensors and capacitive voltage dividers with fast amplifiers/attenuators in order to attain a complete range of information from amplitudes of 0.1mA to 1 kA with a temporal

  3. Performance and Stability Analyses of Rocket Combustion Devices Using Liquid Oxygen/Liquid Methane Propellants

    NASA Technical Reports Server (NTRS)

    Hulka, James R.; Jones, G. W.

    2010-01-01

    Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in flight-qualified engine systems, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented programs with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations on these programs. This paper summarizes these analyses. Test and analysis results of impinging and coaxial element injectors using liquid oxygen and liquid methane propellants are included. Several cases with gaseous methane are included for reference. Several different thrust chamber configurations have been modeled, including thrust chambers with multi-element like-on-like and swirl coax element injectors tested at NASA MSFC, and a unielement chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods.

  4. Moessbauer spectroscopy analysis of {sup 57}Fe-doped YBaCo{sub 4}O{sub 7+{delta}}: Effects of oxygen intercalation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tsipis, E.V.; Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro; Waerenborgh, J.C.

    2009-03-15

    Moessbauer spectroscopy of layered YBaCo{sub 3.96}Fe{sub 0.04}O{sub 7+{delta}} ({delta}=0.02 and 0.80), where 1% cobalt is substituted with {sup 57}Fe isotope, revealed no evidence of charge ordering at 4-293 K. The predominant state of iron cations was found trivalent, irrespective of their coordination and oxygen stoichiometry variations determined by thermogravimetric analysis. The extremely slow kinetics of isothermal oxidation at 598 K in air, and the changes of Fe{sup 3+} fractions in the alternating triangular and Kagome layers in oxidized YBaCo{sub 3.96}Fe{sub 0.04}O{sub 7.80}, may suggest that oxygen intercalation is accompanied with a substantial structural reconstruction stagnated due to sluggish cation diffusion.more » Decreasing temperature below 75-80 K leads to gradual freezing of the iron magnetic moments in inverse correlation with the content of extra oxygen. The formation of metal-oxygen octahedra and resultant structural distortions extend the temperature range where the paramagnetic and frozen states co-exist, down to 45-50 K. - Graphical abstract: Moessbauer spectroscopy of layered YBaCo{sub 3.96}Fe{sub 0.04}O{sub 7+{delta}} ({delta}=0.02 and 0.80), with 1% {sup 57}Fe isotope substituted for cobalt, revealed no evidence of charge ordering at 4-293 K. The predominant state of iron cations was found trivalent, irrespective of their coordination and oxygen stoichiometry variations determined by thermogravimetric analysis. Decreasing temperature below 75-80 K leads to gradual freezing of the iron magnetic moments in inverse correlation with the content of extra oxygen extending the temperature range where the paramagnetic and frozen states co-exist down to 45-50 K.« less

  5. Oxygen Candle Background for Subs and Space

    NASA Technical Reports Server (NTRS)

    Graf, John

    2017-01-01

    pressurized air to control oxygen caused swings in ambient pressure that was uncomfortable to the crew, reference (1). As early as 1919, liquid oxygen was a commercially available product and its use on submarines was contemplated, reference (1). It is interesting that even at this date, 1919, the danger of oils or greases when exposed to compressed or liquid oxygen was recognized: "One precaution must be always taken. No oil or grease should be used in the gauge or fittings or a dangerous explosion may result."

  6. Ionic liquid-assisted preparation of square-shaped Y{sub 2}O{sub 3} nanoplates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Lei; Fang, Hao; Xu, Hualan

    Highlights: • Y{sub 4}O(OH){sub 9}(NO{sub 3}) nanosheets were prepared by an ionic liquid-assisted mixed solvothermal route. • Y{sub 2}O{sub 3} nanosheets were obtained after calcining the Y{sub 4}O(OH){sub 9}(NO{sub 3}) nanosheets. • The Y{sub 2}O{sub 3} nanosheets are with length of about 300 nm and thickness of several nanometers. - Abstract: Uniform square-shaped Y{sub 4}O(OH){sub 9}(NO{sub 3}) nanoplates with side length of about 300 nm and thickness of tens of nanometers have been successfully prepared by an ionic liquid-assisted mixed solvothermal route. Y{sub 2}O{sub 3} nanoplates with similar size were obtained after calcining the Y{sub 4}O(OH){sub 9}(NO{sub 3}) nanoplates atmore » 800 °C. The products were analyzed by powder X-ray diffraction (XRD), thermogravimetric analysis (TG), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution TEM (HRTEM), and electron diffraction (ED). The effects of reaction time, composition of solvents, and the molar ratio of reagents on the morphology of the products have been investigated. The possible formation mechanism of the Y{sub 4}O(OH){sub 9}(NO{sub 3}) nanoplates was also discussed. Y{sub 2}O{sub 3}:Eu{sup 3+} nanoplates were also synthesized and their photoluminescent properties were examined.« less

  7. Dynamic evolution of liquid–liquid phase separation during continuous cooling

    DOE PAGES

    Imhoff, Seth D.; Gibbs, Paul J.; Katz, Martha R.; ...

    2015-01-06

    Solidification from a multiphase fluid involves many unknown quantities due to the difficulty of predicting the impact of fluid flow on chemical partitioning. Real-time x-ray radiography was used to observe liquid-liquid phase separation in Al 90In 10 prior to solidification. Quantitative image analysis was used to measure the motion and population characteristics of the dispersed indium-rich liquid phase during cooling. Here we determine that the droplet growth characteristics resemble well known steady-state coarsening laws with likely enhancement by concurrent growth due to supersaturation. Simplistic views of droplet motion are found to be insufficient until late in the reaction due tomore » a hydrodynamic instability caused by the large density difference between the dispersed and matrix liquid phases.« less

  8. A liquid cooled garment temperature controller based on sweat rate

    NASA Technical Reports Server (NTRS)

    Chambers, A. B.; Blackaby, J. R.

    1972-01-01

    An automatic controller for liquid cooled space suits is reported that utilizes human sweat rate as the primary input signal. The controller is so designed that the coolant inlet temperature is inversely proportional to the subject's latent heat loss as evidenced by evaporative water loss.

  9. Combustion and Performance Analyses of Coaxial Element Injectors with Liquid Oxygen/Liquid Methane Propellants

    NASA Technical Reports Server (NTRS)

    Hulka, J. R.; Jones, G. W.

    2010-01-01

    Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in a flight-qualified engine system, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented activities with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, the NASA Marshall Space Flight Center has conducted combustion, performance, and combustion stability analyses of several of the configurations. This paper summarizes the analyses of combustion and performance as a follow-up to a paper published in the 2008 JANNAF/LPS meeting. Combustion stability analyses are presented in a separate paper. The current paper includes test and analysis results of coaxial element injectors using liquid oxygen and liquid methane or gaseous methane propellants. Several thrust chamber configurations have been modeled, including thrust chambers with multi-element swirl coax element injectors tested at the NASA MSFC, and a uni-element chamber with shear and swirl coax injectors tested at The Pennsylvania State University. Configurations were modeled with two one-dimensional liquid rocket combustion analysis codes, the Rocket Combustor Interaction Design and Analysis (ROCCID), and the Coaxial Injector Combustion Model (CICM). Significant effort was applied to show how these codes can be used to model combustion and performance with oxygen/methane propellants a priori, and what anchoring or calibrating features need to be applied or developed in the future. This paper describes the test hardware configurations, presents the results of all the analyses, and compares the results from the two analytical methods

  10. Combustion Stability Analyses of Coaxial Element Injectors with Liquid Oxygen/Liquid Methane Propellants

    NASA Technical Reports Server (NTRS)

    Hulka, J. R.

    2010-01-01

    Liquid rocket engines using oxygen and methane propellants are being considered by the National Aeronautics and Space Administration (NASA) for in-space vehicles. This propellant combination has not been previously used in a flight-qualified engine system, so limited test data and analysis results are available at this stage of early development. NASA has funded several hardware-oriented activities with oxygen and methane propellants over the past several years with the Propulsion and Cryogenic Advanced Development (PCAD) project, under the Exploration Technology Development Program. As part of this effort, the NASA Marshall Space Flight Center has conducted combustion stability analyses of several of the configurations. This paper presents test data and analyses of combustion stability from the recent PCAD-funded test programs at the NASA MSFC. These test programs used swirl coaxial element injectors with liquid oxygen and liquid methane propellants. Oxygen was injected conventionally in the center of the coaxial element, and swirl was provided by tangential entry slots. Injectors with 28-element and 40-element patterns were tested with several configurations of combustion chambers, including ablative and calorimeter spool sections, and several configurations of fuel injection design. Low frequency combustion instability (chug) occurred with both injectors, and high-frequency combustion instability occurred at the first tangential (1T) transverse mode with the 40-element injector. In most tests, a transition between high-amplitude chug with gaseous methane flow and low-amplitude chug with liquid methane flow was readily observed. Chug analyses of both conditions were conducted using techniques from Wenzel and Szuch and from the Rocket Combustor Interactive Design and Analysis (ROCCID) code. The 1T mode instability occurred in several tests and was apparent by high-frequency pressure measurements as well as dramatic increases in calorimeter-measured heat flux

  11. Trace detection of oxygen--ionic liquids in gas sensor design.

    PubMed

    Baltes, N; Beyle, F; Freiner, S; Geier, F; Joos, M; Pinkwart, K; Rabenecker, P

    2013-11-15

    This paper presents a novel electrochemical membrane sensor on basis of ionic liquids for trace analysis of oxygen in gaseous atmospheres. The faradaic response currents for the reduction of oxygen which were obtained by multiple-potential-step-chronoamperometry could be used for real time detection of oxygen down to concentrations of 30 ppm. The theoretical limit of detection was 5 ppm. The simple, non-expensive sensors varied in electrolyte composition and demonstrated a high sensitivity, a rapid response time and an excellent reproducibility at room temperature. Some of them were continuously used for at least one week and first results promise good long term stability. Voltammetric, impedance and oxygen detection studies at temperatures up to 200 °C (in the presence and absence of humidity and CO2) revealed also the limitations of certain ionic liquids for some electrochemical high temperature applications. Application areas of the developed sensors are control and analysis processes of non oxidative and oxygen free atmospheres. Copyright © 2013 Elsevier B.V. All rights reserved.

  12. 12 CFR 563b.470 - Must I adjust liquidation sub-accounts?

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Must I adjust liquidation sub-accounts? 563b... liquidation sub-accounts? (a)(1) You must reduce the balance of an eligible account holder's or supplemental eligible account holder's sub-account if the deposit balance in the account holder's savings account at the...

  13. The effect of oxygen on density of liquid iron at high pressure

    NASA Astrophysics Data System (ADS)

    Takubo, Y.; Terasaki, H.; Shimoyama, Y.; Urakawa, S.; Suzuki, A.; Nishida, K.; Kamuro, R.; Kishimoto, S.; Kondo, T.; Ohtani, E.; Yoshinori, K.

    2012-12-01

    The Earth's outer core has been thought to be composed of liquid iron alloys with 10 % of light elements, such as sulfur, carbon, silicon and oxygen. Density of liquid iron alloy is one of the key parameters to understand the composition and structure of the Earth's outer core. The effect of various light elements (e.g., S, Si, and C) on the density of liquid iron at high pressure and high temperature has been studied (Nishida et al., 2011; Tateyama et al., 2011 Sanloup et al., 2011; Terasaki et al., 2010). It was revealed that the density depression is quite different depending on dissolving light element. However the effect of oxygen on the density of liquid iron has not been investigated due to high liquidus temperature of Fe-O system, although oxygen is one of the major candidates of the light elements in the Earth's outer core (e.g., Ringwood, 1977). Oxygen could be incorporated into the core during early terrestrial evolution (Corgne et al., 2009). In this study, we have measured the density of liquid Fe-O in the pressure and temperature ranges of 2.3-3.0 GPa and 2000-2250 K using X-ray absorption method. High pressure experiment was performed using a cubic-type multi-anvil press installed at BL22XU of the SPring-8 synchrotron radiation facility in Japan. Monochromatic X-ray of 35 keV was used. Mixture of Fe and FeO powders with 0.5 wt% oxygen, which corresponds to the eutectic composition at 3 GPa (Ohtani et al., 1984) was used as a sample. The sample was inserted in a single crystal sapphire capsule. The obtained density of this study is 6.7 g/cm3 at 3 GPa and 2005 K. Compared to the density of pure liquid iron (Anderson and Ahrens, 1994) at the present experimental condition, the density of liquid Fe-O is about 5.3 % smaller than that of pure liquid iron. On the other hand, thermal expansion coefficient of liquid Fe-O shows similar value to that of liquid iron.

  14. Experimental research on rock fracture failure characteristics under liquid nitrogen cooling conditions

    NASA Astrophysics Data System (ADS)

    Gao, Feng; Cai, Chengzheng; Yang, Yugui

    2018-06-01

    As liquid nitrogen is injected into a wellbore as fracturing fluid, it can rapidly absorb heat from warmer rock and generate cryogenic condition in downhole region. This will alter the physical conditions of reservoir rocks and further affect rock failure characteristics. To investigate rock fracture failure characteristics under liquid nitrogen cooling conditions, the fracture features of four types of sandstones and one type of marble were tested on original samples (the sample without any treatment) and cryogenic samples (the samples just taken out from the liquid nitrogen), respectively. The differences between original samples and cryogenic samples in load-displacement curves, fracture toughness, energy evolution and the crack density of ruptured samples were compared and analyzed. The results showed that at elastic deformation stage, cryogenic samples presented less plastic deformation and more obvious brittle failure characteristics than original ones. The average fracture toughness of cryogenic samples was 10.47%-158.33% greater than that of original ones, indicating that the mechanical strength of rocks used were enhanced under cooling conditions. When the samples ruptured, the cryogenic ones were required to absorb more energy and reserve more elastic energy. In general, the fracture degree of cryogenic samples was higher than that of original ones. As the samples were entirely fractured, the crack density of cryogenic samples was about 536.67% at most larger than that of original ones. This indicated that under liquid nitrogen cooling conditions, the stimulation reservoir volume is expected to be improved during fracturing. This work could provide a reference to the research on the mechanical properties and fracture failure of rock during liquid nitrogen fracturing.

  15. Alkali injection system with controlled CO.sub.2 /O.sub.2 ratios for combustion of coal

    DOEpatents

    Berry, Gregory F.

    1988-01-01

    A high temperature combustion process for an organic fuel containing sulfur n which the nitrogen of air is replaced by carbon dioxide for combination with oxygen with the ratio of CO.sub.2 /O.sub.2 being controlled to generate combustion temperatures above 2000 K. for a gas-gas reaction with SO.sub.2 and an alkali metal compound to produce a sulfate and in which a portion of the carbon-dioxide rich gas is recycled for mixing with oxygen and/or for injection as a cooling gas upstream from heating exchangers to limit fouling of the exchangers, with the remaining carbon-dioxide rich gas being available as a source of CO.sub.2 for oil recovery and other purposes.

  16. Orthorhombic YBaCo{sub 4}O{sub 8.4} crystals as a result of saturation of hexagonal YBaCo{sub 4}O{sub 7} crystals with oxygen

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Podberezskaya, N. V., E-mail: podberez@niic.nsc.ru; Bolotina, N. B., E-mail: nb-bolotina@mail.ru; Komarov, V. Yu., E-mail: komarov-v-y@niic.nsc.ru

    Hexagonal YBaCo{sub 4}O{sub 7} crystals (sp. gr. P6{sub 3}mc, a{sub h} = 6.3058(4) Å, c{sub h} = 10.2442(7) Å, Z = 2) are saturated with oxygen to the YBaCo{sub 4}O{sub 8.4} composition and studied by X-ray diffraction (XRD) analysis. The saturation is completed by a structural first-order phase transition to orthorhombic crystals (sp. gr. Pbc2{sub 1}, a{sub o} = 31.8419(2) Å, b{sub o} = 10.9239(5) Å, c{sub o} = 10.0960(5) Å, Z = 20). The connection of two lattices is expressed in terms of the action of matrix (500/120/001) on the hexagonal basis. Five structural fragments of the same typemore » but with different degrees of order alternate along the long axis of the oxygen-saturated orthorhombic structure. The XRD data on single crystals differ from the results obtained by other researchers on ceramic samples; possible causes of these differences are discussed.« less

  17. Roles of grain boundary and oxygen vacancies in Ba{sub 0.6}Sr{sub 0.4}TiO{sub 3} films for resistive switching device application

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yan, Xiaobing, E-mail: xiaobing-yan@126.com, E-mail: mseyanx@nus.edu.sg; Department of Materials Science and Engineering, National University of Singapore, Singapore, Singapore 117576; Li, Yucheng

    2016-01-18

    Oxygen vacancies are widely thought to be responsible for resistive switching (RS) effects based on polycrystalline oxides films. It is also well known that grain boundaries (GB) serve as reservoirs for accumulating oxygen vacancies. Here, Ar gas was introduced to enlarge the size of GB and increase the quantity of oxygen vacancies when the Ba{sub 0.6}Sr{sub 0.4}TiO{sub 3} (BST) films were deposited by pulse laser deposition technique. The experimental results indicate that the RS properties of the device exhibits better in the Ar-introduced BST films than in the O{sub 2}-grown BST films. High resolution transmission electron microscopy images show thatmore » an amorphous region GB with large size appears between two lattice planes corresponding to oxygen vacancies defects in the Ar-introduced BST. Fourier-transform infrared reflectivity spectroscopy results also reveal highly accumulated oxygen vacancies in the Ar-introduced BST films. And we propose that the conduction transport of the cell was dominantly contributed from not ions migration of oxygen vacancies but the electrons in our case according to the value of activation energies of two kinds of films.« less

  18. Influence of coolant injector configuration on film cooling effectiveness for gaseous and liquid film coolants

    NASA Astrophysics Data System (ADS)

    Shine, S. R.; Sunil Kumar, S.; Suresh, B. N.

    2012-05-01

    An experimental investigation is conducted to bring out the effects of coolant injector configuration on film cooling effectiveness, film cooled length and film uniformity associated with gaseous and liquid coolants. A series of measurements are performed using hot air as the core gas and gaseous nitrogen and water as the film coolants in a cylindrical test section simulating a thrust chamber. Straight and compound angle injection at two different configurations of 30°-10° and 45°-10° are investigated for the gaseous coolant. Tangential injection at 30° and compound angle injection at 30°-10° are examined for the liquid coolant. The analysis is based on measurements of the film-cooling effectiveness and film uniformity downstream of the injection location at different blowing ratios. Measured results showed that compound angle configuration leads to lower far-field effectiveness and shorter film length compared to tangential injection in the case of liquid film cooling. For similar injector configurations, effectiveness along the stream wise direction showed flat characteristics initially for the liquid coolant, while it was continuously dropping for the gaseous coolant. For liquid coolant, deviations in temperature around the circumference are very low near the injection point, but increases to higher values for regions away from the coolant injection locations. The study brings out the existance of an optimum gaseous film coolant injector configuration for which the effectiveness is maximum.

  19. Effect of cathode cooling efficiency and oxygen plasma gas pressure on the hafnium cathode wall temperature

    NASA Astrophysics Data System (ADS)

    Ashtekar, Koustubh; Diehl, Gregory; Hamer, John

    2012-10-01

    The hafnium cathode is widely used in DC plasma arc cutting (PAC) under an oxygen gas environment to cut iron and iron alloys. The hafnium erosion is always a concern which is controlled by the surface temperature. In this study, the effect of cathode cooling efficiency and oxygen gas pressure on the hafnium surface temperature are quantified. The two layer cathode sheath model is applied on the refractive hafnium surface while oxygen species (O2, O, O+, O++, e-) are considered within the thermal dis-equilibrium regime. The system of non-linear equations comprising of current density balance, heat flux balance at both the cathode surface and the sheath-ionization layer is coupled with the plasma gas composition solver. Using cooling heat flux, gas pressure and current density as inputs; the cathode wall temperature, electron temperature, and sheath voltage drop are calculated. Additionally, contribution of emitted electron current (Je) and ions current (Ji) to the total current flux are estimated. Higher gas pressure usually reduces Ji and increases Je that reduces the surface temperature by thermionic cooling.

  20. Data center cooling system

    DOEpatents

    Chainer, Timothy J; Dang, Hien P; Parida, Pritish R; Schultz, Mark D; Sharma, Arun

    2015-03-17

    A data center cooling system may include heat transfer equipment to cool a liquid coolant without vapor compression refrigeration, and the liquid coolant is used on a liquid cooled information technology equipment rack housed in the data center. The system may also include a controller-apparatus to regulate the liquid coolant flow to the liquid cooled information technology equipment rack through a range of liquid coolant flow values based upon information technology equipment temperature thresholds.

  1. International Space Station Active Thermal Control Sub-System On-Orbit Pump Performance and Reliability Using Liquid Ammonia as a Coolant

    NASA Technical Reports Server (NTRS)

    Morton, Richard D.; Jurick, Matthew; Roman, Ruben; Adamson, Gary; Bui, Chinh T.; Laliberte, Yvon J.

    2011-01-01

    The International Space Station (ISS) contains two Active Thermal Control Sub-systems (ATCS) that function by using a liquid ammonia cooling system collecting waste heat and rejecting it using radiators. These subsystems consist of a number of heat exchangers, cold plates, radiators, the Pump and Flow Control Subassembly (PFCS), and the Pump Module (PM), all of which are Orbital Replaceable Units (ORU's). The PFCS provides the motive force to circulate the ammonia coolant in the Photovoltaic Thermal Control Subsystem (PVTCS) and has been in operation since December, 2000. The Pump Module (PM) circulates liquid ammonia coolant within the External Active Thermal Control Subsystem (EATCS) cooling the ISS internal coolant (water) loops collecting waste heat and rejecting it through the ISS radiators. These PM loops have been in operation since December, 2006. This paper will discuss the original reliability analysis approach of the PFCS and Pump Module, comparing them against the current operational performance data for the ISS External Thermal Control Loops.

  2. Tested Demonstrations: Paramagnetism and Color of Liquid Oxygen: A Lecture Demonstration.

    ERIC Educational Resources Information Center

    Shakhashiri, Bassam Z.; And Others

    1980-01-01

    Presents materials and procedures for a lecture demonstration in which liquid nitrogen or liquid oxygen is poured between the poles of a powerful magnet. Hazards of these procedures are included in the discussion. (CS)

  3. 19. NBS SUIT LAB. STORAGE SHELF WITH LIQUID COOLING VENTILATION ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. NBS SUIT LAB. STORAGE SHELF WITH LIQUID COOLING VENTILATION GARMENT (LCVG), SUIT GLOVES, WAIST INSERTS, UPPER AND LOWER ARMS (LEFT, FROM TOP TO BOTTOM), LOWER TORSO ASSEMBLIES (LTA) (MIDDLE RIGHT TO LOWER RIGHT). - Marshall Space Flight Center, Neutral Buoyancy Simulator Facility, Rideout Road, Huntsville, Madison County, AL

  4. Understanding the mechanisms of interfacial reactions during TiO{sub 2} layer growth on RuO{sub 2} by atomic layer deposition with O{sub 2} plasma or H{sub 2}O as oxygen source

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chaker, A.; Szkutnik, P. D.; Pointet, J.

    2016-08-28

    In this paper, TiO{sub 2} layers grown on RuO{sub 2} by atomic layer deposition (ALD) using tetrakis (dimethyla-mino) titanium (TDMAT) and either oxygen plasma or H{sub 2}O as oxygen source were analyzed using X-ray diffraction (XRD), Raman spectroscopy, and depth-resolved X-ray Photoelectron spectroscopy (XPS). The main objective is to investigate the surface chemical reactions mechanisms and their influence on the TiO{sub 2} film properties. The experimental results using XRD show that ALD deposition using H{sub 2}O leads to anatase TiO{sub 2} whereas a rutile TiO{sub 2} is obtained when oxygen-plasma is used as oxygen source. Depth-resolved XPS analysis allows tomore » determine the reaction mechanisms at the RuO{sub 2} substrate surface after growth of thin TiO{sub 2} layers. Indeed, the XPS analysis shows that when H{sub 2}O assisted ALD process is used, intermediate Ti{sub 2}O{sub 3} layer is obtained and RuO{sub 2} is reduced into Ru as evidenced by high resolution transmission electron microscopy. In this case, there is no possibility to re-oxidize the Ru surface into RuO{sub 2} due to the weak oxidation character of H{sub 2}O and an anatase TiO{sub 2} layer is therefore grown on Ti{sub 2}O{sub 3}. In contrast, when oxygen plasma is used in the ALD process, its strong oxidation character leads to the re-oxidation of the partially reduced RuO{sub 2} following the first Ti deposition step. Consequently, the RuO{sub 2} surface is regenerated, allowing the growth of rutile TiO{sub 2}. A surface chemical reaction scheme is proposed that well accounts for the observed experimental results.« less

  5. 69. GENERAL VIEW OF SOUTH SIDE OF SLC3W LIQUID OXYGEN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    69. GENERAL VIEW OF SOUTH SIDE OF SLC-3W LIQUID OXYGEN APRON. EQUIPMENT SKIDS IN FOREGROUND. LARGE LIQUID OXYGEN TANKS FLANKING NITROGEN GAS STORAGE TANKS VISIBLE BEHIND SKIDS. LAUNCH DECK VISIBLE IMMEDIATELY WEST. MST IN PARKED POSITION AT NORTHERN TERMINUS OF RAILS IN BACKGROUND. - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 West, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  6. Detection of the liquid-liquid transition in the deeply cooled water confined in MCM-41 with elastic neutron scattering technique

    NASA Astrophysics Data System (ADS)

    Wang, Zhe; Ito, Kanae; Chen, Sow-Hsin

    2016-05-01

    In this paper we present a review on our recent experimental investigations into the phase behavior of the deeply cooled water confined in a nanoporous silica material, MCM-41, with elastic neutron scattering technique. Under such strong confinement, the homogeneous nucleation process of water is avoided, which allows the confined water to keep its liquid state at temperatures and pressures that are inaccessible to the bulk water. By measuring the average density of the confined heavy water, we observe a likely first-order low-density liquid (LDL) to high-density liquid (HDL) transition in the deeply cooled region of the confined heavy water. The phase separation starts from 1.12±0.17{ kbar} and 215±1{ K} and extends to higher pressures and lower temperatures in the phase diagram. This starting point could be the liquid-liquid critical point of the confined water. The locus of the Widom line is also estimated. The observation of the liquid-liquid transition in the confined water has potential to explain the mysterious behaviors of water at low temperatures. In addition, it may also have impacts on other disciplines, because the confined water system represents many biological and geological systems in which water resides in nanoscopic pores or in the vicinity of hydrophilic or hydrophobic surfaces.

  7. Visualisation of gas-liquid mass transfer around a rising bubble in a quiescent liquid using an oxygen sensitive dye

    NASA Astrophysics Data System (ADS)

    Dietrich, Nicolas; Hebrard, Gilles

    2018-02-01

    An approach for visualizing and measuring the mass transfer around a single bubble rising in a quiescent liquid is reported. A colorimetric technique, developed by (Dietrich et al. Chem Eng Sci 100:172-182, 2013) using an oxygen sensitive redox dye was implemented. It was based on the reduction of the colorimetric indicator in presence of oxygen, this reduction being catalysed by sodium hydroxide and glucose. In this study, resazurin was selected because it offered various reduced forms with colours ranging from transparent (without oxygen) to pink (in presence of oxygen). These advantages made it possible to visualize the spatio-temporal oxygen mass transfer around rising bubbles. Images were recorded by a CCD camera and, after post-processing, the shape, size, and velocity of the bubbles were measured and the colours around the bubbles mapped. A calibration, linking the level of colour with the dissolved oxygen concentration, enabled colour maps to be converted into oxygen concentration fields. A rheoscopic fluid was used to visualize the wake of the bubbles. A calculation method was also developed to determine the transferred oxygen fluxes around bubbles of two sizes (d = 0.82 mm and d = 2.12 mm) and the associated liquid-side mass transfer coefficients. The results compared satisfactorily with classical global measurements made by oxygen micro-sensors or from the classical models. This study thus constitutes a striking example of how this new colorimetric method could become a remarkable tool for exploring gas-liquid mass transfer in fluids.

  8. Visualisation of gas-liquid mass transfer around a rising bubble in a quiescent liquid using an oxygen sensitive dye

    NASA Astrophysics Data System (ADS)

    Dietrich, Nicolas; Hebrard, Gilles

    2018-07-01

    An approach for visualizing and measuring the mass transfer around a single bubble rising in a quiescent liquid is reported. A colorimetric technique, developed by (Dietrich et al. Chem Eng Sci 100:172-182, 2013) using an oxygen sensitive redox dye was implemented. It was based on the reduction of the colorimetric indicator in presence of oxygen, this reduction being catalysed by sodium hydroxide and glucose. In this study, resazurin was selected because it offered various reduced forms with colours ranging from transparent (without oxygen) to pink (in presence of oxygen). These advantages made it possible to visualize the spatio-temporal oxygen mass transfer around rising bubbles. Images were recorded by a CCD camera and, after post-processing, the shape, size, and velocity of the bubbles were measured and the colours around the bubbles mapped. A calibration, linking the level of colour with the dissolved oxygen concentration, enabled colour maps to be converted into oxygen concentration fields. A rheoscopic fluid was used to visualize the wake of the bubbles. A calculation method was also developed to determine the transferred oxygen fluxes around bubbles of two sizes (d = 0.82 mm and d = 2.12 mm) and the associated liquid-side mass transfer coefficients. The results compared satisfactorily with classical global measurements made by oxygen micro-sensors or from the classical models. This study thus constitutes a striking example of how this new colorimetric method could become a remarkable tool for exploring gas-liquid mass transfer in fluids.

  9. Liquid oxygen dicting cleaned by falling film method

    NASA Technical Reports Server (NTRS)

    Paul, H. I.

    1967-01-01

    Principle of a vertical falling film is used to clean contaminated large diameter and length liquid oxygen /LOX/ cylindrical ducting. The cleaning cycle is performed by flowing trichloroethylene in a falling film down a vertically mounted duct for approximately one hour.

  10. Sound speed measurements in liquid oxygen-liquid nitrogen mixtures

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.; Mazel, D. S.

    1985-01-01

    The sound speed in liquid oxygen (LOX), liquid nitrogen (LN2), and five LOX-LN2 mixtures was measured by an ultrasonic pulse-echo technique at temperatures in the vicinity of -195.8C, the boiling point of N2 at a pressure of I atm. Under these conditions, the measurements yield the following relationship between sound speed in meters per second and LN2 content M in mole percent: c = 1009.05-1.8275M+0.0026507 M squared. The second speeds of 1009.05 m/sec plus or minus 0.25 percent for pure LOX and 852.8 m/sec plus or minus 0.32 percent for pure LN2 are compared with those reported by past investigators. Measurement of sound speed should prove an effective means for monitoring the contamination of LOX by Ln2.

  11. A study of the transient performance of annular hydrostatic journal bearings in liquid oxygen

    NASA Astrophysics Data System (ADS)

    Scharrer, J. K.; Tellier, J. G.; Hibbs, R. I.

    1992-07-01

    A test apparatus was used to simulate a cryogenic turbopump start transient in order to determine the liftoff and touchdown speed and amount of wear of an annular hydrostatic bearing in liquid oxygen. The bearing was made of sterling silver and the journal made of Inconel 718. The target application of this configuration is the pump end bearing of the Space Shuttle Main Engine High Pressure Liquid Oxygen Turbopump. Sixty-one transient cycles were performed in liquid oxygen with an additional three tests in liquid nitrogen to certify the test facility and configuration. The bearing showed no appreciable wear during the testing, and the results indicate that the performance of the bearing was not significantly degraded during the testing.

  12. Determination of Time Required for Materials Exposed to Oxygen to Return to Reduced Flammability

    NASA Technical Reports Server (NTRS)

    Harper, Susana; Hirsch, David; Smith, Sarah

    2009-01-01

    Increased material flammability due to exposure to high oxygen concentrations is a concern from both a safety and operational perspective. Localized, high oxygen concentrations can occur when exiting a higher oxygen concentration environment due to material saturation, as well as oxygen entrapment between barrier materials. Understanding of oxygen diffusion and permeation and its correlation to flammability risks can reduce the likelihood of fires while improving procedures as NASA moves to longer missions with increased extravehicular activities in both spacecraft and off-Earth habitats. This paper examines the time required for common spacecraft materials exposed to oxygen to return to reduced flammability after removal from the increased oxygen concentration environment. Specifically, NASA-STD-6001A maximum oxygen concentration testing and ASTM F-1927 permeability testing were performed on Nomex 4 HT90-40, Tiburon 5 Surgical Drape, Cotton, Extravehicular Mobility Unit (EMU) Liquid-Cooled Ventilation Garment, EMU Thermal Comfort Undergarment, EMU Mosite Foam with Spandex Covering, Advanced Crew Escape Suit (ACES) Outer Cross-section, ACES Liquid Cooled Garment (LCG), ACES O2 Hose Material, Minicel 6 Polyethylene Foam, Minicel Polyethylene Foam with Nomex Covering, Pyrell Polyurethane Foam, and Zotek 7 F-30 Foam.

  13. Performance of a 10-kJ SMES model cooled by liquid hydrogen thermo-siphon flow for ASPCS study

    NASA Astrophysics Data System (ADS)

    Makida, Y.; Shintomi, T.; Hamajima, T.; Ota, N.; Katsura, M.; Ando, K.; Takao, T.; Tsuda, M.; Miyagi, D.; Tsujigami, H.; Fujikawa, S.; Hirose, J.; Iwaki, K.; Komagome, T.

    2015-12-01

    We propose a new electrical power storage and stabilization system, called an Advanced Superconducting Power Conditioning System (ASPCS), which consists of superconducting magnetic energy storage (SMES) and hydrogen energy storage, converged on a liquid hydrogen station for fuel cell vehicles. A small 10- kJ SMES system, in which a BSCCO coil cooled by liquid hydrogen was installed, was developed to create an experimental model of an ASPCS. The SMES coil is conductively cooled by liquid hydrogen flow through a thermo-siphon line under a liquid hydrogen buffer tank. After fabrication of the system, cooldown tests were carried out using liquid hydrogen. The SMES coil was successfully charged up to a nominal current of 200 A. An eddy current loss, which was mainly induced in pure aluminum plates pasted onto each pancake coils for conduction cooling, was also measured.

  14. The integration of liquid cryogen cooling and cryocoolers withsuperconducting electronic systems

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Green, Michael A.

    2003-07-09

    The need for cryogenic cooling has been a critical issuethat has kept superconducting electronic devices from reaching the marketplace. Even though the performance of many of the superconductingcircuits is superior to silicon electronics, the requirement forcryogenic cooling has put the superconducting devices at a seriousdisadvantage. This report discusses the process of refrigeratingsuperconducting devices with cryogenic liquids and small cryocoolers.Three types of cryocoolers are compared for vibration, efficiency, andreliability. The connection of a cryocooler to the load is discussed. Acomparison of using flexible copper straps to carry the heat load andusing heat pipe is shown. The type of instrumentation needed formonitoringmore » and controlling the cooling is discussed.« less

  15. Liquid Oxygen Thermodynamic Vent System Testing with Helium Pressurization

    NASA Technical Reports Server (NTRS)

    VanDresar, Neil T.

    2014-01-01

    This report presents the results of several thermodynamic vent system (TVS) tests with liquid oxygen plus a test with liquid nitrogen. In all tests, the liquid was heated above its normal boiling point to 111 K for oxygen and 100 K for nitrogen. The elevated temperature was representative of tank conditions for a candidate lunar lander ascent stage. An initial test series was conducted with saturated oxygen liquid and vapor at 0.6 MPa. The initial series was followed by tests where the test tank was pressurized with gaseous helium to 1.4 to 1.6 MPa. For these tests, the helium mole fraction in the ullage was quite high, about 0.57 to 0.62. TVS behavior is different when helium is present than when helium is absent. The tank pressure becomes the sum of the vapor pressure and the partial pressure of helium. Therefore, tank pressure depends not only on temperature, as is the case for a pure liquid-vapor system, but also on helium density (i.e., the mass of helium divided by the ullage volume). Thus, properly controlling TVS operation is more challenging with helium pressurization than without helium pressurization. When helium was present, the liquid temperature would rise with each successive TVS cycle if tank pressure was kept within a constant control band. Alternatively, if the liquid temperature was maintained within a constant TVS control band, the tank pressure would drop with each TVS cycle. The final test series, which was conducted with liquid nitrogen pressurized with helium, demonstrated simultaneous pressure and temperature control during TVS operation. The simultaneous control was achieved by systematic injection of additional helium during each TVS cycle. Adding helium maintained the helium partial pressure as the liquid volume decreased because of TVS operation. The TVS demonstrations with liquid oxygen pressurized with helium were conducted with three different fluid-mixer configurations-a submerged axial jet mixer, a pair of spray hoops in the tank

  16. Simplified liquid oxygen propellant conditioning concepts

    NASA Technical Reports Server (NTRS)

    Cleary, N. L.; Holt, K. A.; Flachbart, R. H.

    1995-01-01

    Current liquid oxygen feed systems waste propellant and use hardware, unnecessary during flight, to condition the propellant at the engine turbopumps prior to launch. Simplified liquid oxygen propellant conditioning concepts are being sought for future launch vehicles. During a joint program, four alternative propellant conditioning options were studied: (1) passive recirculation; (2) low bleed through the engine; (3) recirculation lines; and (4) helium bubbling. The test configuration for this program was based on a vehicle design which used a main recirculation loop that was insulated on the downcomer and uninsulated on the upcomer. This produces a natural convection recirculation flow. The test article for this program simulated a feedline which ran from the main recirculation loop to the turbopump. The objective was to measure the temperature profile of this test article. Several parameters were varied from the baseline case to determine their effects on the temperature profile. These parameters included: flow configuration, feedline slope, heat flux, main recirculation loop velocity, pressure, bleed rate, helium bubbling, and recirculation lines. The heat flux, bleed rate, and recirculation configurations produced the greatest changes from the baseline temperature profile. However, the temperatures in the feedline remained subcooled. Any of the options studied could be used in future vehicles.

  17. Oxygen stabilization induced enhancement in J(sub c) and T(sub c) of superconducting oxides

    NASA Technical Reports Server (NTRS)

    Wu, M. K.; Chen, J. T.; Huang, C. Y.

    1990-01-01

    In an attempt to enhance the electrical and mechanical properties of the high temperature superconducting oxides, high T(sub c) composites were prepared composed of the 123 compounds and AgO. The presence of extra oxygen due to the decomposition of AgO at high temperature is found to stabilize the superconducting 123 phase. Ag is found to serve as clean flux for grain growth and precipitates as pinning center. Consequently, almost two orders of magnitude enhancement in critical current densities were also observed in these composites. In addition, these composites also show much improvement in workability and shape formation. On the other hand, proper oxygen treatment of Y5Ba6Cu11Oy was found to possibly stabilize superconducting phase with T(sub c) near 250 K. I-V, ac susceptibility, and electrical resistivity measurements indicate the existence of this ultra high T(sub c) phase in this compound. Detailed structure, microstructure, electrical, magnetic and thermal studies of the superconducting composites and the ultra high T(sub c) compound are presented and discussed.

  18. Liquid Cooling Garment Technology Transfer: A Biomedical Case Study

    NASA Technical Reports Server (NTRS)

    Ku, Yu-Tsuan E.; Montgomery, Leslie D.; Lomax, W. Curtis; Webbon, Bruce W.

    1995-01-01

    Liquid cooling garments (LCGs) are routinely used to remove the body heat generated in a space-suit during extravehicular activity (EVA). Garments based upon LCG design have been used in various biomedical situations. The objectives of this investigation is to describe one recent LCG application to provide relief of the pain associated with peripheral neuritis and to report the physiologic changes responsible for this relief.

  19. Effect of limb cooling on peripheral and global oxygen consumption in neonates

    PubMed Central

    Hassan, I; Wickramasinghe, Y; Spencer, S

    2003-01-01

    Aim: To evaluate peripheral oxygen consumption (VO2) measurements using near infrared spectroscopy (NIRS) with arterial occlusion in healthy term neonates by studying the effect of limb cooling on peripheral and global VO2. Subjects and methods: Twenty two healthy term neonates were studied. Peripheral VO2 was measured by NIRS using arterial occlusion and measurement of the oxyhaemoglobin (HbO2) decrement slope. Global VO2 was measured by open circuit calorimetry. Global and peripheral VO2 was measured in each neonate before and after limb cooling. Results: In 10 neonates, a fall in forearm temperature of 2.2°C (mild cooling) decreased forearm VO2 by 19.6% (p < 0.01). Global VO2 did not change. In 12 neonates, a fall in forearm temperature of 4°C (moderate cooling) decreased forearm VO2 by 34.7% (p < 0.01). Global VO2 increased by 17.6% (p < 0.05). Conclusions: The NIRS arterial occlusion method is able to measure changes in peripheral VO2 induced by limb cooling. The changes are more pronounced with moderate limb cooling when a concomitant rise in global VO2 is observed. Change in peripheral temperature must be taken into consideration in the interpretation of peripheral VO2 measurements in neonates. PMID:12598504

  20. Effect of limb cooling on peripheral and global oxygen consumption in neonates.

    PubMed

    Hassan, I A-A; Wickramasinghe, Y A; Spencer, S A

    2003-03-01

    To evaluate peripheral oxygen consumption (VO(2)) measurements using near infrared spectroscopy (NIRS) with arterial occlusion in healthy term neonates by studying the effect of limb cooling on peripheral and global VO(2). Twenty two healthy term neonates were studied. Peripheral VO(2) was measured by NIRS using arterial occlusion and measurement of the oxyhaemoglobin (HbO(2)) decrement slope. Global VO(2) was measured by open circuit calorimetry. Global and peripheral VO(2) was measured in each neonate before and after limb cooling. In 10 neonates, a fall in forearm temperature of 2.2 degrees C (mild cooling) decreased forearm VO(2) by 19.6% (p < 0.01). Global VO(2) did not change. In 12 neonates, a fall in forearm temperature of 4 degrees C (moderate cooling) decreased forearm VO(2) by 34.7% (p < 0.01). Global VO(2) increased by 17.6% (p < 0.05). The NIRS arterial occlusion method is able to measure changes in peripheral VO(2) induced by limb cooling. The changes are more pronounced with moderate limb cooling when a concomitant rise in global VO(2) is observed. Change in peripheral temperature must be taken into consideration in the interpretation of peripheral VO(2) measurements in neonates.

  1. Floating loop method for cooling integrated motors and inverters using hot liquid refrigerant

    DOEpatents

    Hsu, John S.; Ayers, Curtis W.; Coomer, Chester; Marlino, Laura D.

    2007-03-20

    A method for cooling vehicle components using the vehicle air conditioning system comprising the steps of: tapping the hot liquid refrigerant of said air conditioning system, flooding a heat exchanger in the vehicle component with said hot liquid refrigerant, evaporating said hot liquid refrigerant into hot vapor refrigerant using the heat from said vehicle component, and returning said hot vapor refrigerant to the hot vapor refrigerant line in said vehicle air conditioning system.

  2. Applying Additive Manufacturing to a New Liquid Oxygen Turbopump Design

    NASA Technical Reports Server (NTRS)

    O'Neal, Derek

    2016-01-01

    A liquid oxygen turbopump has been designed at Marshall Space Flight Center as part of the in-house, Advanced Manufacturing Demonstrator Engine (AMDE) project. Additive manufacturing, specifically direct metal laser sintering (DMLS) of Inconel 718, is used for 77% of the parts by mass. These parts include the impeller, turbine components, and housings. The near-net shape DMLS parts have been delivered and final machining is underway. Fabrication of the traditionally manufactured hardware is also proceeding. Testing in liquid oxygen is planned for Q2 of FY2017. This topic explores the design of the turbopump along with fabrication and material testing of the DMLS hardware.

  3. Oxygen vacancies induced switchable and nonswitchable photovoltaic effects in Ag/Bi{sub 0.9}La{sub 0.1}FeO{sub 3} /La{sub 0.7}Sr{sub 0.3}MnO{sub 3} sandwiched capacitors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gao, R. L., E-mail: gaorongli2008@163.com, E-mail: jrsun@iphy.ac.cn; Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Science, Beijing 100190; Yang, H. W.

    2014-01-20

    The short circuit photocurrent (I{sub sc}) was found to be strongly dependent on the oxygen vacancies (V{sub Os}) distribution in Ag/Bi{sub 0.9}La{sub 0.1}FeO{sub 3}/La{sub 0.7}Sr{sub 0.3}MnO{sub 3} heterostructures. In order to manipulate the V{sub Os} accumulated at either the Ag/Bi{sub 0.9}La{sub 0.1}FeO{sub 3} or the Bi{sub 0.9}La{sub 0.1}FeO{sub 3}/La{sub 0.7}Sr{sub 0.3}MnO{sub 3} interface by pulse voltages, switchable or nonswitchable photocurrent can be observed without or with changing the polarization direction. The sign of photocurrent could be independent of the direction of polarization when the variation of diffusion current and the modulation of the Schottky barrier at the Ag/Bi{sub 0.9}La{sub 0.1}FeO{submore » 3} interface induced by oxygen vacancies are large enough to offset those induced by polarization. Our work provides deep insights into the nature of photovoltaic effects in ferroelectric films, and will facilitate the advanced design of switchable devices combining spintronic, electronic, and optical functionalities.« less

  4. Espresso coffee foam delays cooling of the liquid phase.

    PubMed

    Arii, Yasuhiro; Nishizawa, Kaho

    2017-04-01

    Espresso coffee foam, called crema, is known to be a marker of the quality of espresso coffee extraction. However, the role of foam in coffee temperature has not been quantitatively clarified. In this study, we used an automatic machine for espresso coffee extraction. We evaluated whether the foam prepared using the machine was suitable for foam analysis. After extraction, the percentage and consistency of the foam were measured using various techniques, and changes in the foam volume were tracked over time. Our extraction method, therefore, allowed consistent preparation of high-quality foam. We also quantitatively determined that the foam phase slowed cooling of the liquid phase after extraction. High-quality foam plays an important role in delaying the cooling of espresso coffee.

  5. Magnetic cooling close to a quantum phase transition—The case of Er{sub 2}Ti{sub 2}O{sub 7}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolf, B.; Tutsch, U.; Dörschug, S.

    Magnetic cooling, first introduced in the late twenties of last century, has regained considerable interest recently as a cost-efficient and easy-to-handle alternative to {sup 3}He-based refrigeration techniques. Especially, adiabatic demagnetization of paramagnets—the standard materials for magnetic refrigeration—has become indispensable for the present space applications. To match the growing demand for increasing the efficiency in these applications, a new concept for magnetic cooling based on many-body effects around a quantum-critical-point has been introduced and successfully tested [B. Wolf et al., Proc. Natl. Acad. Sci. U.S.A. 108, 6862 (2011)]. By extending this concept to three-dimensional magnetic systems, we present here the magnetothermalmore » response of the cubic pyrochlore material Er{sub 2}Ti{sub 2}O{sub 7} in the vicinity of its B-induced quantum-critical point which is located around 1.5 T. We discuss performance characteristics such as the range of operation, the efficiency, and the hold time. These figures are compared with those of state-of-the-art paramagnetic coolants and with other quantum-critical systems which differ by the dimensionality of the magnetic interactions and the degree of frustration.« less

  6. Hydrothermal synthesis of superparamagnetic Fe{sub 3}O{sub 4} nanoparticles with ionic liquids as stabilizer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Xiao-Di, E-mail: liuxiaodiny@126.com; Chen, Hao; Liu, Shan-Shan

    2015-02-15

    Highlights: • Superparamagnetic Fe{sub 3}O{sub 4} nanoparticles with good dispersity have been synthesized via hydrothermal method. • Ionic liquid [C{sub 16}mim]Cl acts as stabilizer for the Fe{sub 3}O{sub 4} nanoparticles. • Fe{sub 3}O{sub 4} nanoparticles have a saturation magnetization of 67.69 emu/g at 300 K. - Abstract: Superparamagnetic Fe{sub 3}O{sub 4} nanoparticles have been successfully synthesized under hydrothermal condition with the assistant of ionic liquid 1-hexadecyl-3-methylimidazolium chloride ([C{sub 16}mim]Cl). The structure and morphology of the sample have been investigated by X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), transmission electron microscopy (TEM), and high-resolution TEM (HRTEM), and the results indicate thatmore » the as-synthesized inverse spinel Fe{sub 3}O{sub 4} nanoparticles have an average diameter of about 10 nm and exhibit relatively good dispersity. More importantly, it is found that [C{sub 16}mim]Cl acts as stabilizer for the Fe{sub 3}O{sub 4} nanoparticles by adsorbing on the particles surfaces to prevent the agglomeration. In addition, the obtained superparamagnetic Fe{sub 3}O{sub 4} nanoparticles have a saturation magnetization of 67.69 emu/g at 300 K.« less

  7. Design and simulation of liquid cooled system for power battery of PHEV

    NASA Astrophysics Data System (ADS)

    Wang, Jianpeng; Xu, Haijun; Xu, Xiaojun; Pan, Cunyun

    2017-09-01

    Various battery chemistries have different responses to failure, but the most common failure mode of a cell under abusive conditions is the generation of heat and gas. To prevent battery thermal abuse, a battery thermal management system is essential. An excellent design of battery thermal management system can ensure that the battery is working at a suitable temperature and keeps the battery temperature diffenence at 2-3 °C. This paper presents a thermal-elcetric coupling model for a 37Ah lithium battery using AMESim. A liquid cooled system of hybrid electric vehicle power battery is designed to control the battery temperature.A liquid cooled model of thermal management system is built using AMESim, the simulation results showed that the temperature difference within 3°C of cell in the pack.

  8. Comparison of immersed liquid and air cooling of NASA's Airborne Information Management System

    NASA Technical Reports Server (NTRS)

    Hoadley, A. W.; Porter, A. J.

    1992-01-01

    The Airborne Information Management System (AIMS) is currently under development at NASA Dryden Flight Research Facility. The AIMS is designed as a modular system utilizing surface mounted integrated circuits in a high-density configuration. To maintain the temperature of the integrated circuits within manufacturer's specifications, the modules are to be filled with Fluorinert FC-72. Unlike ground based liquid cooled computers, the extreme range of the ambient pressures experienced by the AIMS requires the FC-72 be contained in a closed system. This forces the latent heat absorbed during the boiling to be released during the condensation that must take within the closed module system. Natural convection and/or pumping carries the heat to the outer surface of the AIMS module where the heat transfers to the ambient air. This paper will present an evaluation of the relative effectiveness of immersed liquid cooling and air cooling of the Airborne Information Management System.

  9. Comparison of immersed liquid and air cooling of NASA's Airborne Information Management System

    NASA Astrophysics Data System (ADS)

    Hoadley, A. W.; Porter, A. J.

    1992-07-01

    The Airborne Information Management System (AIMS) is currently under development at NASA Dryden Flight Research Facility. The AIMS is designed as a modular system utilizing surface mounted integrated circuits in a high-density configuration. To maintain the temperature of the integrated circuits within manufacturer's specifications, the modules are to be filled with Fluorinert FC-72. Unlike ground based liquid cooled computers, the extreme range of the ambient pressures experienced by the AIMS requires the FC-72 be contained in a closed system. This forces the latent heat absorbed during the boiling to be released during the condensation that must take within the closed module system. Natural convection and/or pumping carries the heat to the outer surface of the AIMS module where the heat transfers to the ambient air. This paper will present an evaluation of the relative effectiveness of immersed liquid cooling and air cooling of the Airborne Information Management System.

  10. Assessment of external heat transfer coefficient during oocyte vitrification in liquid and slush nitrogen using numerical simulations to determine cooling rates.

    PubMed

    Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J

    2012-01-01

    In oocyte vitrification, plunging directly into liquid nitrogen favor film boiling and strong nitrogen vaporization. A survey of literature values of heat transfer coefficients (h) for film boiling of small metal objects with different geometries plunged in liquid nitrogen revealed values between 125 to 1000 W per per square m per K. These h values were used in a numerical simulation of cooling rates of two oocyte vitrification devices (open-pulled straw and Cryotop), plunged in liquid and slush nitrogen conditions. Heat conduction equation with convective boundary condition was considered a linear mathematical problem and was solved using the finite element method applying the variational formulation. COMSOL Multiphysics was used to simulate the cooling process of the systems. Predicted cooling rates for OPS and Cryotop when cooled at -196 degree C (liquid nitrogen) or -207 degree C (average for slush nitrogen) for heat transfer coefficients estimated to be representative of film boiling, indicated lowering the cooling temperature produces only a maximum 10 percent increase in cooling rates; confirming the main benefit of plunging in slush over liquid nitrogen does not arise from their temperature difference. Numerical simulations also demonstrated that a hypothetical four-fold increase in the cooling rate of vitrification devices when plunging in slush nitrogen would be explained by an increase in heat transfer coefficient. This improvement in heat transfer (i.e., high cooling rates) in slush nitrogen is attributed to less or null film boiling when a sample is placed in slush (mixture of liquid and solid nitrogen) because it first melts the solid nitrogen before causing the liquid to boil and form a film.

  11. Lung lavage with oxygenated perfluorochemical liquid in acute lung injury.

    PubMed

    Richman, P S; Wolfson, M R; Shaffer, T H

    1993-05-01

    To investigate the effects of lung lavage with oxygenated liquid perfluorochemical on gas exchange, lung mechanics, and cardiac function in animals with acute lung injury. Prospective, randomized, controlled trial. Animal laboratory. Eight adult cats (2 to 4 kg, random sex). Two insults were combined to cause lung injury: oleic acid infusion and saline whole-lung wash. Animals were assigned to either the control or treatment group which consisted of a perfluorochemical liquid (Rimar 101) lavage. Perfluorochemical liquid lavage was performed three times at hourly intervals after lung injury. Three other cats with identical injury but no perfluorochemical liquid lavage served as control animals. All cats were ventilated with an FIO2 of 0.95 and positive end-expiratory pressure of 2 cm H2O continuously. Arterial blood gas tensions and pH, dynamic pulmonary compliance were measured at 15-min intervals. Cardiac index was assessed hourly, and lung fluid was collected after each of the three perfluorochemical liquid lavages. Arterial oxygen tension and pulmonary compliance deteriorated abruptly after lung injury in all cats, and improved significantly (p < .001, two-way analysis of variance) 15 mins after perfluorochemical liquid lavage. These parameters gradually returned to their baseline over 60 mins. Arterial blood pressure and cardiac index decreased after injury in all cats, and were not significantly changed after perfluorochemical liquid lavage. Hemorrhagic fluid was recovered from distal airways by perfluorochemical liquid lavage, despite prior suctioning of the airway. Perfluorochemical liquid lavage removes pulmonary edema fluid and improves gas exchange and the mechanical properties of the lung, after acute severe lung injury.

  12. Oxygen stoichiometry: A key parameter to tune structural phase diagram of La{sub 0.2}Sr{sub 0.8}MnO{sub 3-δ}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shahee, Aga, E-mail: agashahee@gmail.com; Lalla, N. P.

    2015-06-24

    Low temperature x-ray powder diffraction studies, in conjunction with transmission electron microscopy on stoichiometric (δ = 0.01) and oxygen deficient (δ =0.12) samples of La{sub 0.2}Sr{sub 0.8}MnO{sub 3-δ} manganites have been carried out. These studies revealed that oxygen stoichiometry plays a key role in controlling ground state of electron doped manganites. It is observed that the La{sub 0.2}Sr{sub 0.8}MnO{sub 2.99} undergoes a first order phase transition from cubic (Pm-3m) to JT-distorted twin tetragonal (I4/mcm) phase associated with C-type antiferromagnetic ordering at ∼260K. This JT-distortion induced cubic to tetragonal phase transition get totally suppressed in La{sub 0.2}Sr{sub 0.8}MnO{sub 2.88}. The basicmore » perovskite lattice of the off-stoichiometric La{sub 0.2}Sr{sub 0.8}MnO{sub 2.88} remains cubic down to 80K but undergoes a well-developed charge-ordering transition with 9x9 modulations at ∼260K.« less

  13. Molecular beam epitaxy growth of niobium oxides by solid/liquid state oxygen source and lithium assisted metal-halide chemistry

    NASA Astrophysics Data System (ADS)

    Tellekamp, M. Brooks; Greenlee, Jordan D.; Shank, Joshua C.; Doolittle, W. Alan

    2015-09-01

    In order to consistently grow high quality niobium oxides and lithium niobium oxides, a novel solid/liquid state oxygen source, LiClO4, has been implemented in a molecular beam epitaxy (MBE) system. LiClO4 is shown to decompose into both molecular and atomic oxygen upon heating. This allows oxidation rates similar to that of molecular oxygen but at a reduced overall beam flux, quantified by in situ Auger analysis. LiClO4 operation is decomposition limited to less than 400 °C, and other material limitations are identified. The design of a custom near-ambient NbCl5 effusion cell is presented, which improves both short and long term stability. Films of Nb oxidation state +2, +3, and +5 are grown using these new tools, including the multi-functional sub-oxide LiNbO2.

  14. Liquid-Oxygen-Compatible Cement for Gaskets

    NASA Technical Reports Server (NTRS)

    Elmore, N. L.; Neale, B. C.

    1984-01-01

    Fluorelastomer and metal bonded reliably by new procedure. To cure fluoroelastomer cement, metal plate/gasket assembly placed in vacuum bag evacuated to minimum vacuum of 27 inches (69 cm) of mercury. Vacuum maintained throughout heating process and until assembly returns to ambient room temperature. Used to seal gaskets and O-rings or used to splice layers of elastomer to form non-standard sized O-rings. Another possible use is to apply protective, liquid-oxygen-compatible coating to metal parts.

  15. Thermal conductivity of Glycerol’s liquid, glass, and crystal states, glass-liquid-glass transition, and crystallization at high pressures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Andersson, Ove; Johari, G. P., E-mail: joharig@mcmaster.ca

    2016-02-14

    To investigate the effects of local density fluctuations on phonon propagation in a hydrogen bonded structure, we studied the thermal conductivity κ of the crystal, liquid, and glassy states of pure glycerol as a function of the temperature, T, and the pressure, p. We find that the following: (i) κ{sub crystal} is 3.6-times the κ{sub liquid} value at 140 K at 0.1 MPa and 2.2-times at 290 K, and it varies with T according to 138 × T{sup −0.95}; (ii) the ratio κ{sub liquid} (p)/κ{sub liquid} (0.1 MPa) is 1.45 GPa{sup −1} at 280 K, which, unexpectedly, is about themore » same as κ{sub crystal} (p)/κ{sub crystal} (0.1 MPa) of 1.42 GPa{sup −1} at 298 K; (iii) κ{sub glass} is relatively insensitive to T but sensitive to the applied p (1.38 GPa{sup −1} at 150 K); (iv) κ{sub glass}-T plots show an enhanced, pressure-dependent peak-like feature, which is due to the glass to liquid transition on heating; (v) continuous heating cold-crystallizes ultraviscous glycerol under pressure, at a higher T when p is high; and (vi) glycerol formed by cooling at a high p and then measured at a low p has a significantly higher κ than the glass formed by cooling at a low p. On heating at a fixed low p, its κ decreases before its glass-liquid transition range at that p is reached. We attribute this effect to thermally assisted loss of the configurational and vibrational instabilities of a glass formed at high p and recovered at low p, which is different from the usual glass-aging effect. While the heat capacity, entropy, and volume of glycerol crystal are less than those for its glass and liquid, κ{sub crystal} of glycerol, like its elastic modulus and refractive index, is higher. We discuss these findings in terms of the role of fluctuations in local density and structure, and the relations between κ and the thermodynamic quantities.« less

  16. Validation of High Aspect Ratio Cooling in a 89 kN (20,000 lb(sub f)) Thrust Combustion Chamber

    NASA Technical Reports Server (NTRS)

    Wadel, Mary F.; Meyer, Michael L.

    1996-01-01

    In order to validate the benefits of high aspect ratio cooling channels in a large scale rocket combustion chamber, a high pressure, 89 kN (20,000 lbf) thrust, contoured combustion chamber was tested in the NASA Lewis Research Center Rocket Engine Test Facility. The combustion chamber was tested at chamber pressures from 5.5 to 11.0 MPa (800-1600 psia). The propellants were gaseous hydrogen and liquid oxygen at a nominal mixture ratio of six, and liquid hydrogen was used as the coolant. The combustion chamber was extensively instrumented with 30 backside skin thermocouples, 9 coolant channel rib thermocouples, and 10 coolant channel pressure taps. A total of 29 thermal cycles, each with one second of steady state combustion, were completed on the chamber. For 25 thermal cycles, the coolant mass flow rate was equal to the fuel mass flow rate. During the remaining four thermal cycles, the coolant mass flow rate was progressively reduced by 5, 6, 11, and 20 percent. Computer analysis agreed with coolant channel rib thermocouples within an average of 9 percent and with coolant channel pressure drops within an average of 20 percent. Hot-gas-side wall temperatures of the chamber showed up to 25 percent reduction, in the throat region, over that of a conventionally cooled combustion chamber. Reducing coolant mass flow yielded a reduction of up to 27 percent of the coolant pressure drop from that of a full flow case, while still maintaining up to a 13 percent reduction in a hot-gas-side wall temperature from that of a conventionally cooled combustion chamber.

  17. Liquid oxygen sloshing in Space Shuttle External Tank

    NASA Technical Reports Server (NTRS)

    Kannapel, M. D.; Przekwas, A. J.; Singhal, A. K.; Costes, N. C.

    1987-01-01

    This paper describes a numerical simulation of the hydrodynamics within the liquid oxygen tank of the Space Shuttle External Tank during liftoff. Before liftoff, the tank is filled with liquid oxygen (LOX) to approximately 97 percent with the other 3 percent containing gaseous oxygen (GOX) and helium. During liftoff, LOX is drained from the bottom of the tank, and GOX is pumped into the tank's ullage volume. There is a delay of several seconds before the GOX reaches the tank which causes the ullage pressure to decrease for several seconds after liftoff; this pressure 'slump' is a common phenomenon in rocket propulsion. When four slosh baffles were removed from the tank, the ullage gas pressure dropped more rapidly than in all previous flights. The purpose of this analysis was to determine whether the removal of the baffles could have caused the increased pressure 'slump' by changing the LOX surface dynamics. The results show that the LOX surface undergoes very high vertical accelerations (up to 5 g) and, therefore, splashing almost certainly occurs. The number of baffles does not affect the surface if the structural motion is assumed; but, the number of baffles may affect the structural motion of the tank.

  18. Free-surface flow of liquid oxygen under non-uniform magnetic field

    NASA Astrophysics Data System (ADS)

    Bao, Shi-Ran; Zhang, Rui-Ping; Wang, Kai; Zhi, Xiao-Qin; Qiu, Li-Min

    2017-01-01

    The paramagnetic property of oxygen makes it possible to control the two-phase flow at cryogenic temperatures by non-uniform magnetic fields. The free-surface flow of vapor-liquid oxygen in a rectangular channel was numerically studied using the two-dimensional phase field method. The effects of magnetic flux density and inlet velocity on the interface deformation, flow pattern and pressure drop were systematically revealed. The liquid level near the high-magnetic channel center was lifted upward by the inhomogeneous magnetic field. The interface height difference increased almost linearly with the magnetic force. For all inlet velocities, pressure drop under 0.25 T was reduced by 7-9% due to the expanded local cross-sectional area, compared to that without magnetic field. This work demonstrates the effectiveness of employing non-uniform magnetic field to control the free-surface flow of liquid oxygen. This non-contact method may be used for promoting the interface renewal, reducing the flow resistance, and improving the flow uniformity in the cryogenic distillation column, which may provide a potential for enhancing the operating efficiency of cryogenic air separation.

  19. Influence of nickel doping on oxygen-ionic conductivity of the n = 1 Ruddlesden-Popper Phases La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4−δ} (δ = 0.0905)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Midouni, Adnene; Université de Tunis El Manar, Campus Universitaire Farhat Hached, B.P. No 94- Rommana, 1068 Tunis; Houchati, Mohamed Ikbal, E-mail: ikb_med@yahoo.fr

    2016-08-15

    The results of the synthesis and characterization of the optimally doped La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4-δ} solid solution with x = 0, 0.1, 0.2 and 0.3 are reported. The versatility of these La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4−δ} materials is explained on the basis of structural features and the ability to accommodate oxygen nonstoichiometry. According to powder X-ray and neutron diffraction data, La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4−δ} adopts the tetragonal structure with oxygen vacancies occurring preferentially at the O{sub ap} sites within the {(La/Ca)O} layers of the perovskite blocks and the oxygen deviation from stoichiometry δ was foundmore » to be δ=0.0905(6). The bulk conductivity indicated an Arrhenius-type thermally activated process and oxygen vacancies are the possible ionic charge carriers at T=270 °C. An increase of the conductivity was detected when Ni was introduced. With nickel ratio variation, a strong correlation was observed between the Cu(Ni)-O{sub ap} apical bond length variation and the conductivity variation through controlling the O{sup 2−} ion migration. - Highlights: • We report the synthesis and structure of the La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4−δ} (0≤x≤0.3; δ=0.0905) compounds. • La{sub 1.85}Ca{sub 0.15}(Cu{sub 1−x}Ni{sub x})O{sub 4−δ} (x=0.0, 0.2, 0.3) doped with Ni{sup 2+} have a higher conductivity than undoped La{sub 1.85}Ca{sub 0.15}CuO{sub 4−δ}. • At T=270 °C, sample x=0.3 has the highest conductivity (0.2915 sm{sup −1}).« less

  20. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazardsmore » related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present

  1. Device for measuring oxygen activity in liquid sodium

    DOEpatents

    Roy, P.; Young, R.S.

    1973-12-01

    A composite ceramic electrolyte in a configuration (such as a closed end tube or a plate) suitable to separate liquid sodium from a reference electrode with a high impedance voltmeter connected to measure EMF between the sodium and the reference electrode as a measure of oxygen activity in the sodium is described. The composite electrolyte consists of zirconiacalcia with a bonded layer of thoria-yttria. The device is used with a gaseous reference electrode on the zirconia-calcia side and liquid sodium on the thoria-yttria side of the electrolyte. (Official Gazette)

  2. Development of modified poly(perfluoropropyleneoxide) urethane systems for use in liquid oxygen and in enriched 100 percent oxygen atmosphere

    NASA Technical Reports Server (NTRS)

    Harrison, E. S.

    1973-01-01

    This program consisted of two separate though related phases. The initial phase was directed toward improving the mechanical and adhesive properties of the very highly fluorinated-polyurethane resin system derived from the hydroxyl-terminated polyperfluoropropylene oxide and 6-chloro-2,4,5-trifluoro-m-phenylene diisocyanate. Various new curing agents for this system were investigated, with the goal of providing a more thermally stable crosslink (cure) mechanism to provide wider applicability and fuller utilization of the outstanding oxygen resistance of the PFPO system. Complete resistance to liquid- and gaseous-oxygen impact at presures as high as 1035 N/sq cm were attained with the use of the PFPO resin castings. The second corollary phase was directed toward investigating the feasibility and optimization of the allophanate cured, urethane extended polymer derived from hydroxyl-terminated polyperfluoropropyleneoxide and 6-chloro-2,4,5-trifluoro-m-phenylene diisocyanate, as the adhesive system for use in a weld-bond configuration for liquid oxygen tankage. The synthesis and application procedures of the adhesive system to insure liquid oxygen compatibility (under 10 kg-m loading), and the development of procedures and techniques to provide high quality weld-bonded joint configurations were studied.

  3. Oxygen Extraction from Regolith Using Ionic Liquids

    NASA Technical Reports Server (NTRS)

    Barrios, Elizabeth A.; Curreri, Peter A.; Karr, Laurel J.

    2011-01-01

    An important concern with long-duration manned space travel is the need to furnish enough materials to the vehicle, as well as the crew, for the duration of the mission. By extracting oxygen from the oxides present in regolith, propellant and life support could be supplied to the vehicle and the crew while in space, thereby limiting the amount of supplies needed prior to lift-off. Using a class of compounds known as ionic liquids, we have been able to lower the electrolysis operating temperature from 1600 C (molten oxide electrolysis) to less than 200 C, making this process much more feasible in terms of energy consumption and materials handling. To make this process ready for deployment into space, we have investigated what steps of the process would be affected by the low-gravity environment in space. In the lab, the solubilization of lunar regolith simulant in ionic liquid produces water vapor that is normally distilled out of solution and subsequently electrolyzed for oxygen production. This distillation is not possible in space, so we have tested a method known as pervaporation and have suggested a way this technique could be incorporated into a reactor design.

  4. Provisioning cooling elements for chillerless data centers

    DOEpatents

    Chainer, Timothy J.; Parida, Pritish R.

    2016-12-13

    Systems and methods for cooling include one or more computing structure, an inter-structure liquid cooling system that includes valves configured to selectively provide liquid coolant to the one or more computing structures; a heat rejection system that includes one or more heat rejection units configured to cool liquid coolant; and one or more liquid-to-liquid heat exchangers that include valves configured to selectively transfer heat from liquid coolant in the inter-structure liquid cooling system to liquid coolant in the heat rejection system. Each computing structure further includes one or more liquid-cooled servers; and an intra-structure liquid cooling system that has valves configured to selectively provide liquid coolant to the one or more liquid-cooled servers.

  5. Provisioning cooling elements for chillerless data centers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chainer, Timothy J.; Parida, Pritish R.

    Systems and methods for cooling include one or more computing structure, an inter-structure liquid cooling system that includes valves configured to selectively provide liquid coolant to the one or more computing structures; a heat rejection system that includes one or more heat rejection units configured to cool liquid coolant; and one or more liquid-to-liquid heat exchangers that include valves configured to selectively transfer heat from liquid coolant in the inter-structure liquid cooling system to liquid coolant in the heat rejection system. Each computing structure further includes one or more liquid-cooled servers; and an intra-structure liquid cooling system that has valvesmore » configured to selectively provide liquid coolant to the one or more liquid-cooled servers.« less

  6. Growth of In/sub 2/S/sub 3/ and CdIn/sub 2/S/sub 4/ single crystals from a solution in a melt

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Buzhor, V.P.; Lyalikova, R. Yu.; Radautsan, S.I.

    1986-08-01

    The authors studied the reaction of In/sub 2/S/sub 3/ and CdIn/sub 2/S/sub 4/ with melts based on cadmium chloride. As the initial materials, they used polycrystalline In/sub 2/S/sub 3/ and CdIn/sub 2/S/sub 4/, cadmium chloride, and cadmium sulfide. The studies were carried out by the method of thermal analysis in sealed quartz ampules on an MOM derivatotograph. The solubility curve of In/sub 2/S/sub 3/ in a cadmium chloride melt is given. Nucleation occurs both within the liquid pahse and on the walls of the reaction container. At cooling rates of 4-5 K/h, with a charge of 100 g in amore » reaction container of diameter 20 mm the authors obtained In/sub 2/S/sub 3/ and CdIn/sub 2/S/sub 4/ crystals measuring 10-12 mm in size.« less

  7. Oxygen Production from Lunar Regolith using Ionic Liquids

    NASA Technical Reports Server (NTRS)

    Paley, Mark Steven; Karr, Laurel J.; Curreri, Peter

    2009-01-01

    The objective of this work and future follow-on work is to develop a safe, efficient, and recyclable method for oxygen and/or metals extraction from lunar regolith, in support of establishing a manned lunar outpost. The approach is to solubilize the oxides that comprise lunar regolith in media consisting of ionic liquids (ILs) and/or their mixtures at temperatures at or below 300 C. Once in solution, electrolysis can either be performed in-situ to generate oxygen at the anode and hydrogen and/or metals (silicon, iron, aluminum, titanium, etc.) at the cathode. Alternatively, the water that is generated during the solubilization process can be distilled out and condensed into a separate IL and then electrolysized to produce hydrogen and oxygen. In the case of lunar regolith, this method could theoretically produce 44g oxygen per 100g of regolith. The oxygen can be used for human life support and/or as an oxidizer for rocket fuels, and the metals can be used as raw materials for construction and/or device fabrication. Moreover, the hydrogen produced can be used to re-generate the acidic medium, which can then be used to process additional regolith, thereby making the materials recyclable and limiting upmass requirements. An important advantage of IL acid systems is that they are much "greener" and safer than conventional materials used for regolith processing such as sulfuric or hydrochloric acids. They have very low vapor pressures, which means that they contain virtually no toxic and/or flammable volatile content, they are relatively non-corrosive, and they can exhibit good stability in harsh environments (extreme temperatures, hard vacuum, etc.). Furthermore, regolith processing can be achieved at lower temperatures than other processes such as molten oxide electrolysis or hydrogen reduction, thereby reducing initial power requirements. Six ILs have been synthesized and tested for their capability to dissolve lunar simulant, and for electrochemical and thermal

  8. Boson peak in deeply cooled confined water: a possible way to explore the existence of the liquid-to-liquid transition in water.

    PubMed

    Wang, Zhe; Liu, Kao-Hsiang; Le, Peisi; Li, Mingda; Chiang, Wei-Shan; Leão, Juscelino B; Copley, John R D; Tyagi, Madhusudan; Podlesnyak, Andrey; Kolesnikov, Alexander I; Mou, Chung-Yuan; Chen, Sow-Hsin

    2014-06-13

    The boson peak in deeply cooled water confined in nanopores is studied with inelastic neutron scattering. We show that in the (P, T) plane, the locus of the emergence of the boson peak is nearly parallel to the Widom line below ∼ 1600 bar. Above 1600 bar, the situation is different and from this difference the end pressure of the Widom line is estimated. The frequency and width of the boson peak correlate with the density of water, which suggests a method to distinguish the hypothetical "low-density liquid" and "high-density liquid" phases in deeply cooled water.

  9. Prospects for Boiling of Subcooled Dielectric Liquids for Supercomputer Cooling

    NASA Astrophysics Data System (ADS)

    Zeigarnik, Yu. A.; Vasil'ev, N. V.; Druzhinin, E. A.; Kalmykov, I. V.; Kosoi, A. S.; Khodakov, K. A.

    2018-02-01

    It is shown experimentally that using forced-convection boiling of dielectric coolants of the Novec 649 Refrigerant subcooled relative to the saturation temperature makes possible removing heat flow rates up to 100 W/cm2 from modern supercomputer chip interface. This fact creates prerequisites for the application of dielectric liquids in cooling systems of modern supercomputers with increased requirements for their operating reliability.

  10. In-situ activation of CuO/ZnO/Al.sub.2 O.sub.3 catalysts in the liquid phase

    DOEpatents

    Brown, Dennis M.; Hsiung, Thomas H.; Rao, Pradip; Roberts, George W.

    1989-01-01

    The present invention relates to a method of activation of a CuO/ZnO/Al.sub.2 O.sub.3 catalyst slurried in a chemically inert liquid. Successful activation of the catalyst requires the use of a process in which the temperature of the system at any time is not allowed to exceed a certain critical value, which is a function of the specific hydrogen uptake of the catalyst at that same time. This process is especially critical for activating highly concentrated catalyst slurries, typically 25 to 50 wt %. Activation of slurries of CuO/ZnO/Al.sub.2 O.sub.3 catalyst is useful in carrying out the liquid phase methanol or the liquid phase shift reactions.

  11. Comparison of different cooling regimes within a shortened liquid cooling/warming garment on physiological and psychological comfort during exercise

    NASA Technical Reports Server (NTRS)

    Leon, Gloria R.; Koscheyev, Victor S.; Coca, Aitor; List, Nathan

    2004-01-01

    The aim of this study was to compare the effectiveness of different cooling regime intensities to maintain physiological and subjective comfort during physical exertion levels comparable to that engaged in during extravehicular activities (EVA) in space. We studied eight subjects (six males, two females) donned in our newly developed physiologically based shortened liquid cooling/warming garment (SLCWG). Rigorous (condition 1) and mild (condition 2) water temperature cooling regimes were compared at physical exertion levels comparable to that performed during EVA to ascertain the effectiveness of a lesser intensity of cooling in maintaining thermal comfort, thus reducing energy consumption in the portable life support system. Exercise intensity was varied across stages of the session. Finger temperature, rectal temperature, and subjective perception of overall body and hand comfort were assessed. Finger temperature was significantly higher in the rigorous cooling condition and showed a consistent increase across exercise stages, likely due to the restriction of heat extraction because of the intensive cold. In the mild cooling condition, finger temperature exhibited an overall decline with cooling, indicating greater heat extraction from the body. Rectal temperature was not significantly different between conditions, and showed a steady increase over exercise stages in both rigorous and mild cooling conditions. Ratings of overall comfort were 30% higher (more positive) and more stable in mild cooling (p<0.001). The mild cooling regime was more effective than rigorous cooling in allowing the process of heat exchange to occur, thus maintaining thermal homeostasis and subjective comfort during physical exertion.

  12. Electron diffraction study of the sillenites Bi{sub 12}SiO{sub 20}, Bi{sub 25}FeO{sub 39} and Bi{sub 25}InO{sub 39}: Evidence of short-range ordering of oxygen-vacancies in the trivalent sillenites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Scurti, Craig A.; Arenas, D. J.; Auvray, Nicolas

    We present an electron diffraction study of three sillenites, Bi{sub 12}SiO{sub 20}, Bi{sub 25}FeO{sub 39}, and Bi{sub 25}InO{sub 39} synthesized using the solid-state method. We explore a hypothesis, inspired by optical studies in the literature, that suggests that trivalent sillenites have additional disorder not present in the tetravalent compounds. Electron diffraction patterns of Bi{sub 25}FeO{sub 39} and Bi{sub 25}InO{sub 39} show streaks that confirm deviations from the ideal sillenite structure. Multi-slice simulations of electron-diffraction patterns are presented for different perturbations to the sillenite structure - partial substitution of the M site by Bi{sup 3+}, random and ordered oxygen-vacancies, and amore » frozen-phonon model. Although comparison of experimental data to simulations cannot be conclusive, we consider the streaks as evidence of short-range ordered oxygen-vacancies.« less

  13. Measurements of solar and terrestrial heating and cooling rate profiles in Arctic and sub-tropic stratocumulus

    NASA Astrophysics Data System (ADS)

    Gottschalk, Matthias; Lauermann, Felix; Ehrlich, André; Siebert, Holger; Wendisch, Manfred

    2017-04-01

    Stratocumulus covers approximately 20 % (annually averaged) of the Earth's surface and thus strongly influences the atmospheric and surface radiative energy budget resulting in radiative cooling and heating effects. Globally, the solar cooling effect of the widespread sub-tropical stratocumulus dominates. However, in the Arctic the solar cloud albedo effect (cooling) is often smaller than the thermal-infrared greenhouse effect (warming), which is a result of the lower incoming solar radiation and the low cloud base height. Therefore, Arctic stratocumulus mostly warms the atmosphere and surface below the cloud. Additionally, different environmental conditions lead to differences between sub-tropical and Arctic stratocumulus. Broadband pyranometers and pyrgeometers will be used to measure heating and cooling rate profiles in and above stratocumulus. For this purpose two slowly moving platforms are used (helicopter and tethered balloon) in order to consider for the long response times of both broadband radiation sensors. Two new instrument packages are developed for the applied tethered balloon and helicopter platforms, which will be operated within Arctic and sub-tropical stratocumulus, respectively. In June 2017, the balloon will be launched from a sea ice floe north of 80 °N during the Arctic Balloon-borne profiling Experiment (ABEX) as part of (AC)3 (Arctic Amplification: Climate Relevant Atmospheric and Surface Processes and Feedback Mechanisms) Transregional Collaborative Research Center. The helicopter will sample sub-tropical stratocumulus over the Azores in July 2017.

  14. Cardiopulmonary function and oxygen delivery during total liquid ventilation.

    PubMed

    Tsagogiorgas, Charalambos; Alb, Markus; Herrmann, Peter; Quintel, Michael; Meinhardt, Juergen P

    2011-10-01

    Total liquid ventilation (TLV) with perfluorocarbons has shown to improve cardiopulmonary function in the injured and immature lung; however there remains controversy over the normal lung. Hemodynamic effects of TLV in the normal lung currently remain undetermined. This study compared changes in cardiopulmonary and circulatory function caused by either liquid or gas tidal volume ventilation. In a prospective, controlled study, 12 non-injured anesthetized, adult New Zealand rabbits were primarily conventionally gas-ventilated (CGV). After instrumentation for continuous recording of arterial (AP), central venous (CVP), left artrial (LAP), pulmonary arterial pressures (PAP), and cardiac output (CO) animals were randomized into (1) CGV group and (2) TLV group. In the TLV group partial liquid ventilation was initiated with instillation of perfluoroctylbromide (12 ml/kg). After 15 min, TLV was established for 3 hr applying a volume-controlled, pressure-limited, time-cycled ventilation mode using a double-piston configured TLV. Controls (CGV) remained gas-ventilated throughout the experiment. During TLV, heart rate, CO, PAP, MAP, CVP, and LAP as well as derived hemodynamic variables, arterial and mixed venous blood gases, oxygen delivery, PVR, and SVR did not differ significantly compared to CGV. Liquid tidal volumes suitable for long-term TLV in non-injured rabbits do not significantly impair CO, blood pressure, and oxygen dynamics when compared to CGV. Copyright © 2011 Wiley-Liss, Inc.

  15. Correlation of magnetoelectric coupling in multiferroic BaTiO{sub 3}-BiFeO{sub 3} superlattices with oxygen vacancies and antiphase octahedral rotations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lorenz, Michael, E-mail: mlorenz@physik.uni-leipzig.de; Schwinkendorf, Peter; Grundmann, Marius

    2015-01-05

    Multiferroic (BaTiO{sub 3}-BiFeO{sub 3}) × 15 multilayer heterostructures show high magnetoelectric (ME) coefficients α{sub ME} up to 24 V/cm·Oe at 300 K. This value is much higher than that of a single-phase BiFeO{sub 3} reference film (α{sub ME} = 4.2 V/cm·Oe). We found clear correlation of ME coefficients with increasing oxygen partial pressure during growth. ME coupling is highest for lower density of oxygen vacancy-related defects. Detailed scanning transmission electron microscopy and selected area electron diffraction microstructural investigations at 300 K revealed antiphase rotations of the oxygen octahedra in the BaTiO{sub 3} single layers, which are an additional correlated defect structure of the multilayers.

  16. Experimental determination of oxygen diffusion in liquid iron at high pressure

    NASA Astrophysics Data System (ADS)

    Posner, Esther S.; Rubie, David C.; Frost, Daniel J.; Steinle-Neumann, Gerd

    2017-04-01

    Oxygen diffusion experiments in liquid iron have been performed at 3-18 GPa and 1975-2643 K using a multi-anvil apparatus. Diffusion couples consisted of a pure iron rod and a sintered disk of Fe0.85O0.15 placed end-to-end in a vertical orientation. Images and chemical spot analyses were acquired along the full length of the quenched sample on lines perpendicular to the diffusion interface. Exsolution features that formed during quenching consist mostly of spherical oxide blobs of at least two size populations, as well as feathery dendritic textures in more oxygen-rich regions near the top of the samples. Diffusion during heating (i.e. prior to reaching the peak annealing temperature, Tf) is treated numerically to refine Arrhenian parameters from simultaneous least-squares fits to several concentration profiles obtained from experiments at constant pressure and variable Tf. Diffusion coefficients range from ∼ 6 ×10-9 to ∼ 2 ×10-8 m2s-1 over the P-T range of the study, with activation enthalpies of less than 100 kJ mol-1. We find a very weak effect of pressure on oxygen diffusion with an activation volume of 0.1 ± 0.1 cm3mol-1, in agreement with computational studies performed above 100 GPa. Arrhenian extrapolation of diffusion coefficients for oxygen to P-T conditions of the Earth's outer core yields faster average diffusion rates (∼ 3 ×10-8 m2s-1) than for Si or Fe in silicon-rich liquid iron alloys or pure liquid iron (∼ 5 ×10-9 m2s-1) reported previously. Oxygen diffusion data are used to constrain the maximum size of descending liquid metal droplets in a magma ocean that is required for chemical equilibration to be achieved. Our results indicate that if the Earth's core composition is representative of equilibrium chemical exchange with a silicate magma ocean, then it could only have been accomplished by large-scale break-up of impactor cores to liquid iron droplet sizes no larger than a few tens of centimeters.

  17. Development and fabrication of an advanced liquid cooling garment

    NASA Technical Reports Server (NTRS)

    Leith, J. R.; Hixon, C. W.

    1976-01-01

    The elastomeric film fin/tube concept which was developed is a composite of polyurethane film, fine expanded silver mesh, a serpentine pattern polyurethane transport tubing and an integral comfort liner, all bonded via adhesive application and vacuum-bagged for final cure. As demonstrated by thermal analysis, the composite garment material is capable of removing a 293 watt (1000 BTU/hr) metabolic load through a head and torso cooling area of .46 sq m (5 sq ft) with tube spacing of slightly under one inch. A total of 60 test elements, each .15m x .15m (6 in. x 6 in.) were fabricated in support of the liquid cooling garment concept development. In parallel with the fabrication of these elements a continuing series of laboratory tests to support the fabrication techniques was carried out. The elements and supporting tests are described.

  18. Effects of Oxygen Partial Pressure on the Surface Tension of Liquid Nickel

    NASA Technical Reports Server (NTRS)

    SanSoucie, Michael P.; Rogers, Jan R.; Gowda, Vijaya Kumar Malahalli Shankare; Rodriguez, Justin; Matson, Douglas M.

    2015-01-01

    The NASA Marshall Space Flight Center's electrostatic levitation (ESL) laboratory has been recently upgraded with an oxygen partial pressure controller. This system allows the oxygen partial pressure within the vacuum chamber to be measured and controlled, theoretically in the range from 10-36 to 100 bar. The oxygen control system installed in the ESL laboratory's main chamber consists of an oxygen sensor, oxygen pump, and a control unit. The sensor is a potentiometric device that determines the difference in oxygen activity in two gas compartments (inside the chamber and the air outside of the chamber) separated by an electrolyte, which is yttria-stabilized zirconia. The pump utilizes coulometric titration to either add or remove oxygen. The system is controlled by a desktop control unit, which can also be accessed via a computer. The controller performs temperature control for the sensor and pump, PID-based current loop, and a control algorithm. Oxygen partial pressure has been shown to play a significant role in the surface tension of liquid metals. Oxide films or dissolved oxygen may lead to significant changes in surface tension. The effects of oxygen partial pressure on the surface tension of undercooled liquid nickel will be analyzed, and the results will be presented. The surface tension will be measured at several different oxygen partial pressures while the sample is undercooled. Surface tension will be measured using the oscillating drop method. While undercooled, each sample will be oscillated several times consecutively to investigate how the surface tension behaves with time while at a particular oxygen partial pressure.

  19. Close-up of 7/8' gold-plated liquid oxygen post plug

    NASA Technical Reports Server (NTRS)

    1999-01-01

    Engineers are investigating the possibility that a 7/8' gold- plated liquid oxygen post plug became dislodged and created three small holes in the liquid hydrogen tubes inside the nozzle on main engine No. 3 on Space Shuttle Columbia. The holes caused a hydrogen leak during the STS-93 launch of Columbia on July 23.

  20. High-power laser phosphor light source with liquid cooling for digital cinema applications

    NASA Astrophysics Data System (ADS)

    Li, Kenneth

    2014-02-01

    Laser excited phosphor has been used to excite phosphor material, producing high intensity light output with smaller etendue than that of LEDs with the same long lifetime. But due to the high intensity of the laser light, phosphor with organic binder burns at low power, which requires the phosphor to be deposited on a rotating wheel in practical applications. Phosphor with inorganic binders, commonly known as ceramic phosphor, on the other hand, does not burn, but efficiency goes down as temperature goes up under high power excitation. This paper describes cooling schemes in sealed chambers such that the phosphor materials using organic or inorganic binders can be liquid cooled for high efficiency operations. Confined air bubbles are introduced into the sealed chamber accommodating the differential thermal expansion of the liquid and the chamber. For even higher power operation suitable for digital cinema, a suspension of phosphor in liquid is described suitable for screen brightness of over 30,000 lumens. The aging issues of phosphor can also be solved by using replaceable phosphor cartridges.

  1. Diamagnetic levitation enhances growth of liquid bacterial cultures by increasing oxygen availability

    PubMed Central

    Dijkstra, Camelia E.; Larkin, Oliver J.; Anthony, Paul; Davey, Michael R.; Eaves, Laurence; Rees, Catherine E. D.; Hill, Richard J. A.

    2011-01-01

    Diamagnetic levitation is a technique that uses a strong, spatially varying magnetic field to reproduce aspects of weightlessness, on the Earth. We used a superconducting magnet to levitate growing bacterial cultures for up to 18 h, to determine the effect of diamagnetic levitation on all phases of the bacterial growth cycle. We find that diamagnetic levitation increases the rate of population growth in a liquid culture and reduces the sedimentation rate of the cells. Further experiments and microarray gene analysis show that the increase in growth rate is owing to enhanced oxygen availability. We also demonstrate that the magnetic field that levitates the cells also induces convective stirring in the liquid. We present a simple theoretical model, showing how the paramagnetic force on dissolved oxygen can cause convection during the aerobic phases of bacterial growth. We propose that this convection enhances oxygen availability by transporting oxygen around the liquid culture. Since this process results from the strong magnetic field, it is not present in other weightless environments, e.g. in Earth orbit. Hence, these results are of significance and timely to researchers considering the use of diamagnetic levitation to explore effects of weightlessness on living organisms and on physical phenomena. PMID:20667843

  2. Diamagnetic levitation enhances growth of liquid bacterial cultures by increasing oxygen availability.

    PubMed

    Dijkstra, Camelia E; Larkin, Oliver J; Anthony, Paul; Davey, Michael R; Eaves, Laurence; Rees, Catherine E D; Hill, Richard J A

    2011-03-06

    Diamagnetic levitation is a technique that uses a strong, spatially varying magnetic field to reproduce aspects of weightlessness, on the Earth. We used a superconducting magnet to levitate growing bacterial cultures for up to 18 h, to determine the effect of diamagnetic levitation on all phases of the bacterial growth cycle. We find that diamagnetic levitation increases the rate of population growth in a liquid culture and reduces the sedimentation rate of the cells. Further experiments and microarray gene analysis show that the increase in growth rate is owing to enhanced oxygen availability. We also demonstrate that the magnetic field that levitates the cells also induces convective stirring in the liquid. We present a simple theoretical model, showing how the paramagnetic force on dissolved oxygen can cause convection during the aerobic phases of bacterial growth. We propose that this convection enhances oxygen availability by transporting oxygen around the liquid culture. Since this process results from the strong magnetic field, it is not present in other weightless environments, e.g. in Earth orbit. Hence, these results are of significance and timely to researchers considering the use of diamagnetic levitation to explore effects of weightlessness on living organisms and on physical phenomena.

  3. Effects of oxygen plasma etching on Sb{sub 2}Te{sub 3} explored by torque detected quantum oscillations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yan, Yuan, E-mail: yuan.yan@pi1.physik.uni-stuttgart.de, E-mail: martin.dressel@pi1.physik.uni-stuttgart.de; Heintze, Eric; Pracht, Uwe S.

    2016-04-25

    De Haas–van Alphen measurements evidence that oxygen plasma etching strongly affects the properties of the three-dimensional topological insulator Sb{sub 2}Te{sub 3}. The quantum oscillations in magnetization down to low temperature (T ≥ 2 K) and high magnetic field (B ≤ 7 T) have been systematically investigated using a high-sensitive cantilever torque magnetometer. The effective mass and the oscillation frequency obtained from de Haas–van Alphen measurements first increase and then decrease as the oxygen plasma etching time increases from 0 to 12 min, corresponding to an up- and down-shift of the Dirac point. We establish the cantilever torque magnetometer as a powerful contactless tool to investigate themore » oxygen sensitivity of the surface state in topological insulators.« less

  4. Vitrification of human pronuclear oocytes by direct plunging into cooling agent: Non sterile liquid nitrogen vs. sterile liquid air.

    PubMed

    Isachenko, Vladimir; Todorov, Plamen; Seisenbayeva, Akerke; Toishibekov, Yerzhan; Isachenko, Evgenia; Rahimi, Gohar; Mallmann, Peter; Foth, Dolores; Merzenich, Markus

    2018-02-01

    In fact, a full sterilization of commercially-produced liquid nitrogen contaminated with different pathogens is not possible. The aim of this study was to compare the viability of human pronuclear oocytes subjected to cooling by direct submerging of open carrier in liquid nitrogen versus submerging in clean liquid air (aseptic system). One- and three-pronuclei stage embryos (n = 444) were cryopreserved by direct plunging into liquid nitrogen (vitrified) in ethylene glycol (15%), dimethylsulphoxide (15%) and 0.2M sucrose. Oocytes were exposed in 20, 33, 50 and 100% vitrification solution for 2, 1 and 1 min, and 30-50 s, respectively at room temperature. Then first part of oocytes (n = 225) were directly plunged into liquid nitrogen, and second part of oocytes (n = 219) into liquid air. Oocytes were thawed rapidly at a speed of 20,000 °C/min and then subsequently were placed into a graded series of sucrose solutions (0.5, 0.25, 0.12 and 0.06M) at 2.5 min intervals and cultured in vitro for 3 days. In both groups, the rate of high-quality embryos (Grade 6A: 6 blastomeres, no fragmentation; Grade 8A: 8 blastomeres, no fragmentation; Grade 8A compacting: 8 blastomeres, beginning of compacting) was noted. The rates of high-quality embryos developed from one-pronuclear oocytes vitrified by cooling in liquid nitrogen and liquid air were: 39.4% ± 0.6 and 38.7% ± 0.8, respectively (P > 0.1). These rates for three-pronuclear oocytes were: 45.8 ± 0.8% and 52.0 ± 0.7%, respectively (P < 0.05). In conclusion, vitrification by direct submerging of oocytes in clean liquid air (aseptic system) is a good alternative for using of not sterile liquid nitrogen. Copyright © 2017. Published by Elsevier Inc.

  5. Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition.

    PubMed

    Wang, Zhe; Kolesnikov, Alexander I; Ito, Kanae; Podlesnyak, Andrey; Chen, Sow-Hsin

    2015-12-04

    The boson peak in deeply cooled water confined in nanopores is studied to examine the liquid-liquid transition (LLT). Below ∼180  K, the boson peaks at pressures P higher than ∼3.5  kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescaled to a different one. These phenomena agree with the existence of two liquid phases with different densities and local structures and the associated LLT in the measured (P, T) region. In addition, the P dependence of the librational band also agrees with the above conclusion.

  6. Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition

    DOE PAGES

    Wang, Zhe; Kolesnikov, Alexander I.; Ito, Kanae; ...

    2015-12-03

    We studied the boson peak in deeply cooled water confined in nanopores in order to examine the liquid-liquid transition (LLT). Below ~180 K, the boson peaks at pressures P higher than ~3.5 kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescaled to a different one. Moreover, these phenomena agree with the existence of two liquid phases with different densities and local structures and the associated LLT in the measured (P, T) region. Additionally,more » the P dependence of the librational band also agrees with the above conclusion.« less

  7. Coolant and ambient temperature control for chillerless liquid cooled data centers

    DOEpatents

    Chainer, Timothy J.; David, Milnes P.; Iyengar, Madhusudan K.; Parida, Pritish R.; Simons, Robert E.

    2017-08-29

    Cooling control methods and systems include measuring a temperature of air provided to one or more nodes by an air-to-liquid heat exchanger; measuring a temperature of at least one component of the one or more nodes and finding a maximum component temperature across all such nodes; comparing the maximum component temperature to a first and second component threshold and comparing the air temperature to a first and second air threshold; and controlling a proportion of coolant flow and a coolant flow rate to the air-to-liquid heat exchanger and the one or more nodes based on the comparisons.

  8. Coolant and ambient temperature control for chillerless liquid cooled data centers

    DOEpatents

    Chainer, Timothy J.; David, Milnes P.; Iyengar, Madhusudan K.; Parida, Pritish R.; Simons, Robert E.

    2016-02-02

    Cooling control methods include measuring a temperature of air provided to a plurality of nodes by an air-to-liquid heat exchanger, measuring a temperature of at least one component of the plurality of nodes and finding a maximum component temperature across all such nodes, comparing the maximum component temperature to a first and second component threshold and comparing the air temperature to a first and second air threshold, and controlling a proportion of coolant flow and a coolant flow rate to the air-to-liquid heat exchanger and the plurality of nodes based on the comparisons.

  9. Liquid Oxygen/Liquid Methane Ascent Main Engine Technology Development

    NASA Technical Reports Server (NTRS)

    Robinson, Joel W.; Stephenson, David D.

    2008-01-01

    The National Aeronautics & Space Administration (NASA) has identified Liquid Oxygen (LO2)/Liquid Methane (LCH4) as a potential propellant combination for future space vehicles based upon the Exploration Systems Architecture Study (ESAS). The technology is estimated to have higher performance and lower overall systems mass compared to existing hypergolic propulsion systems. The current application considering this technology is the lunar ascent main engine (AME). AME is anticipated to be an expendable, pressure-fed engine to provide ascent from the moon at the completion of a 210 day lunar stay. The engine is expected to produce 5,500 lbf (24,465 N) thrust with variable inlet temperatures due to the cryogenic nature of the fuel and oxidizer. The primary technology risks include establishing reliable and robust ignition in vacuum conditions, maximizing specific impulse, developing rapid start capability for the descent abort, providing the capability for two starts and producing a total engine bum time over 500 seconds. This paper will highlight the efforts of the Marshall Space Flight Center (MSFC) in addressing risk reduction activities for this technology.

  10. Mini-Membrane Evaporator for Contingency Spacesuit Cooling

    NASA Technical Reports Server (NTRS)

    Makinen, Janice V.; Bue, Grant C.; Campbell, Colin; Petty, Brian; Craft, Jesse; Lynch, William; Wilkes, Robert; Vogel, Matthew

    2015-01-01

    The next-generation Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support System (PLSS) is integrating a number of new technologies to improve reliability and functionality. One of these improvements is the development of the Auxiliary Cooling Loop (ACL) for contingency crewmember cooling. The ACL is a completely redundant, independent cooling system that consists of a small evaporative cooler--the Mini Membrane Evaporator (Mini-ME), independent pump, independent feedwater assembly and independent Liquid Cooling Garment (LCG). The Mini-ME utilizes the same hollow fiber technology featured in the full-sized AEMU PLSS cooling device, the Spacesuit Water Membrane Evaporator (SWME), but Mini-ME occupies only approximately 25% of the volume of SWME, thereby providing only the necessary crewmember cooling in a contingency situation. The ACL provides a number of benefits when compared with the current EMU PLSS contingency cooling technology, which relies upon a Secondary Oxygen Vessel; contingency crewmember cooling can be provided for a longer period of time, more contingency situations can be accounted for, no reliance on a Secondary Oxygen Vessel (SOV) for contingency cooling--thereby allowing a reduction in SOV size and pressure, and the ACL can be recharged-allowing the AEMU PLSS to be reused, even after a contingency event. The first iteration of Mini-ME was developed and tested in-house. Mini-ME is currently packaged in AEMU PLSS 2.0, where it is being tested in environments and situations that are representative of potential future Extravehicular Activities (EVA's). The second iteration of Mini-ME, known as Mini-ME2, is currently being developed to offer more heat rejection capability. The development of this contingency evaporative cooling system will contribute to a more robust and comprehensive AEMU PLSS.

  11. Mini-Membrane Evaporator for Contingency Spacesuit Cooling

    NASA Technical Reports Server (NTRS)

    Makinen, Janice V.; Bue, Grant C.; Campbell, Colin; Craft, Jesse; Lynch, William; Wilkes, Robert; Vogel, Matthew

    2014-01-01

    The next-generation Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support System (PLSS) is integrating a number of new technologies to improve reliability and functionality. One of these improvements is the development of the Auxiliary Cooling Loop (ACL) for contingency crewmember cooling. The ACL is a completely redundant, independent cooling system that consists of a small evaporative cooler--the Mini Membrane Evaporator (Mini-ME), independent pump, independent feedwater assembly and independent Liquid Cooling Garment (LCG). The Mini-ME utilizes the same hollow fiber technology featured in the full-sized AEMU PLSS cooling device, the Spacesuit Water Membrane Evaporator (SWME), but Mini-ME occupies only 25% of the volume of SWME, thereby providing only the necessary crewmember cooling in a contingency situation. The ACL provides a number of benefits when compared with the current EMU PLSS contingency cooling technology, which relies upon a Secondary Oxygen Vessel; contingency crewmember cooling can be provided for a longer period of time, more contingency situations can be accounted for, no reliance on a Secondary Oxygen Vessel (SOV) for contingency cooling--thereby allowing a reduction in SOV size and pressure, and the ACL can be recharged-allowing the AEMU PLSS to be reused, even after a contingency event. The first iteration of Mini-ME was developed and tested in-house. Mini-ME is currently packaged in AEMU PLSS 2.0, where it is being tested in environments and situations that are representative of potential future Extravehicular Activities (EVA's). The second iteration of Mini-ME, known as Mini- ME2, is currently being developed to offer more heat rejection capability. The development of this contingency evaporative cooling system will contribute to a more robust and comprehensive AEMU PLSS.

  12. Interactions in ion pairs of protic ionic liquids: Comparison with aprotic ionic liquids

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tsuzuki, Seiji, E-mail: s.tsuzuki@aist.go.jp; Shinoda, Wataru; Miran, Md. Shah

    2013-11-07

    The stabilization energies for the formation (E{sub form}) of 11 ion pairs of protic and aprotic ionic liquids were studied by MP2/6-311G{sup **} level ab initio calculations to elucidate the difference between the interactions of ions in protic ionic liquids and those in aprotic ionic liquids. The interactions in the ion pairs of protic ionic liquids (diethylmethylammonium [dema] and dimethylpropylammonium [dmpa] based ionic liquids) are stronger than those of aprotic ionic liquids (ethyltrimethylammonium [etma] based ionic liquids). The E{sub form} for the [dema][CF{sub 3}SO{sub 3}] and [dmpa][CF{sub 3}SO{sub 3}] complexes (−95.6 and −96.4 kcal/mol, respectively) are significantly larger (more negative)more » than that for the [etma][CF{sub 3}SO{sub 3}] complex (−81.0 kcal/mol). The same trend was observed for the calculations of ion pairs of the three cations with the Cl{sup −}, BF{sub 4}{sup −}, TFSA{sup −} anions. The anion has contact with the N–H bond of the dema{sup +} or dmpa{sup +} cations in the most stable geometries of the dema{sup +} and dmpa{sup +} complexes. The optimized geometries, in which the anions locate on the counter side of the cations, are 11.0–18.0 kcal/mol less stable, which shows that the interactions in the ions pairs of protic ionic liquids have strong directionality. The E{sub form} for the less stable geometries for the dema{sup +} and dmpa{sup +} complexes are close to those for the most stable etma{sup +} complexes. The electrostatic interaction, which is the major source of the attraction in the ion pairs, is responsible for the directionality of the interactions and determining the magnitude of the interaction energy. Molecular dynamic simulations of the [dema][TFSA] and [dmpa][TFSA] ionic liquids show that the N–H bonds of the cations have contact with the negatively charged (oxygen and nitrogen) atoms of TFSA{sup −} anion, while the strong directionality of the interactions was not suggested from the

  13. Whole-body pre-cooling does not alter human muscle metabolism during sub-maximal exercise in the heat.

    PubMed

    Booth, J; Wilsmore, B R; Macdonald, A D; Zeyl, A; Mcghee, S; Calvert, D; Marino, F E; Storlien, L H; Taylor, N A

    2001-06-01

    Muscle metabolism was investigated in seven men during two 35 min cycling trials at 60% peak oxygen uptake, at 35 degrees C and 50% relative humidity. On one occasion, exercise was preceded by whole-body cooling achieved by immersion in water during a reduction in temperature from 29 to 24 degrees C, and, for the other trial, by immersion in water at a thermoneutral temperature (control, 34.8 degrees C). Pre-cooling did not alter oxygen uptake during exercise (P > 0.05), whilst the change in cardiac frequency and body mass both tended to be lower following pre-cooling (0.05 < P < 0.10). When averaged over the exercise period, muscle and oesophageal temperatures after pre-cooling were reduced by 1.5 and 0.6 degrees C respectively, compared with control (P < 0.05). Pre-cooling had a limited effect on muscle metabolism, with no differences between the two conditions in muscle glycogen, triglyceride, adenosine triphosphate, creatine phosphate, creatine or lactate contents at rest, or following exercise. These data indicate that whole-body pre-cooling does not alter muscle metabolism during submaximal exercise in the heat. It is more likely that thermoregulatory and cardiovascular strain are reduced, through lower muscle and core temperatures.

  14. Lunar Oxygen Production and Metals Extraction Using Ionic Liquids

    NASA Technical Reports Server (NTRS)

    Marone, Matthew; Paley, Mark Steven; Donovan, David N.; Karr, Laurel J.

    2009-01-01

    Initial results indicate that ionic liquids are promising media for the extraction of oxygen from lunar regolith. IL acid systems can solubilize regolith and produce water with high efficiency. IL electrolytes are effective for water electrolysis, and the spent IL acid media are capable of regeneration.

  15. Oxidizer Selection for the ISTAR Program (Liquid Oxygen versus Hydrogen Peroxide)

    NASA Technical Reports Server (NTRS)

    Quinn, Jason Eugene; Koelbl, Mary E. (Technical Monitor)

    2002-01-01

    This paper discusses a study of two alternate oxidizers, liquid oxygen and hydrogen peroxide, for use in a rocket based combined cycle (RBCC) demonstrator vehicle. The flight vehicle is baselined as an airlaunched self-powered Mach 0.7 to 7 demonstration of an RBCC engine through all or its air breathing propulsion modes. Selection of an alternate oxidizer has the potential to lower overall vehicle size, system complexity/ cost and ultimately the total program risk. This trade study examined the oxidizer selection effects upon the overall vehicle performance, safety and operations. After consideration of all the technical and programmatic details available at this time, 90% hydrogen peroxide was selected over liquid oxygen for use in this program.

  16. An Hybrid liquid nitrogen system to cool a large detector

    NASA Astrophysics Data System (ADS)

    l'Allemand, J. L. Lizon a.

    2017-12-01

    OmegaCAM is a wide field camera housing a mosaic of 32 CCD detectors. For the optimal trade-off between dark current, sensitivity, and cosmetics, these detectors need to be operated at a temperature of about 155 K. The detectors mosaic with a total area of 630 cm2 directly facing the Dewar entrance window, is exposed to a considerable radiation heat load. This can only be achieved with a high-performing cooling system. In addition this system has to be operated at the moving focal plane of a telescope. The paper describes the cooling system, which is build such that it makes the most efficient use of the cooling power of the liquid nitrogen. This is obtained by forcing the nitrogen through a series of well designed and strategically distributed heat exchangers. Results and performance of the system recorded during the laboratory system testing are reported as well. In addition to the cryogenic performance, the document reports also about the overall performance of the instrument including long term vacuum behavior.

  17. 17. DETAIL, FOURTEENINCH LIQUID OXYGEN BALL VALVE. Looking south southeast. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    17. DETAIL, FOURTEEN-INCH LIQUID OXYGEN BALL VALVE. Looking south southeast. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

  18. 99. LIQUID OXYGEN LINE AND SAMPLING VALVE FOR RAPIDLOAD ON ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    99. LIQUID OXYGEN LINE AND SAMPLING VALVE FOR RAPID-LOAD ON WEST SIDE OF SKID 9A - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 East, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  19. 93. VIEW OF LIQUID OXYGEN TOPPING TANK BEHIND SKID 9 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    93. VIEW OF LIQUID OXYGEN TOPPING TANK BEHIND SKID 9 AND GASEOUS NITROGEN TANKS BEHIND SKID 7 - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 East, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  20. Numerical simulation of the heat transfer at cooling a high-temperature metal cylinder by a flow of a gas-liquid medium

    NASA Astrophysics Data System (ADS)

    Makarov, S. S.; Lipanov, A. M.; Karpov, A. I.

    2017-10-01

    The numerical modeling results for the heat transfer during cooling a metal cylinder by a gas-liquid medium flow in an annular channel are presented. The results are obtained on the basis of the mathematical model of the conjugate heat transfer of the gas-liquid flow and the metal cylinder in a two-dimensional nonstationary formulation accounting for the axisymmetry of the cooling medium flow relative to the cylinder longitudinal axis. To solve the system of differential equations the control volume approach is used. The flow field parameters are calculated by the SIMPLE algorithm. To solve iteratively the systems of linear algebraic equations the Gauss-Seidel method with under-relaxation is used. The results of the numerical simulation are verified by comparing the results of the numerical simulation with the results of the field experiment. The calculation results for the heat transfer parameters at cooling the high-temperature metal cylinder by the gas-liquid flow are obtained with accounting for evaporation. The values of the rate of cooling the cylinder by the laminar flow of the cooling medium are determined. The temperature change intensity for the metal cylinder is analyzed depending on the initial velocity of the liquid flow and the time of the cooling process.

  1. Theoretical Performance of Liquid Hydrogen with Liquid Oxygen as a Rocket Propellant

    NASA Technical Reports Server (NTRS)

    Gordon, Sanford; McBride, Bonnie J.

    1959-01-01

    Theoretical rocket performance for both equilibrium and frozen composition during expansion was calculated for the propellant combination liquid hydrogen and liquid oxygen at four chamber pressures (60, 150, 300, and 600 lb/sq in. abs) and a wide range of pressure ratios (1 to 4000) and oxidant-fuel ratios (1.190 to 39.683). Data are given to estimate performance parameters at chamber pressures other than those for which data are tabulated. The parameters included are specific impulse, specific impulse in vacuum, combustion-chamber temperature, nozzle-exit temperature, molecular weight, molecular-weight derivatives, characteristic velocity, coefficient of thrust, ratio of nozzle-exit area to throat area, specific heat at constant pressure, isentropic exponent, viscosity, thermal conductivity, Mach number, and equilibrium gas compositions.

  2. 16. DETAIL SHOWING LIQUID OXYGEN TANK FOURTEENINCH BALL VALVE. Looking ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    16. DETAIL SHOWING LIQUID OXYGEN TANK FOURTEEN-INCH BALL VALVE. Looking southwest. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

  3. Cooling and solidification of liquid-metal drops in a gaseous atmosphere

    NASA Technical Reports Server (NTRS)

    Mccoy, J. K.; Markworth, A. J.; Collings, E. W.; Brodkey, R. S.

    1992-01-01

    The free fall of a liquid-metal drop, heat transfer from the drop to its environment, and solidification of the drop are described for both gaseous and vacuum atmospheres. A simple model, in which the drop is assumed to fall rectilinearly, with behavior like that of a rigid particle, is developed to describe cooling behavior. Recalescence of supercooled drops is assumed to occur instantaneously when a specified temperature is passed. The effects of solidification and experimental parameters on drop cooling are calculated and discussed. Major results include temperature as a function of time, and of drag, time to complete solidification, and drag as a function of the fraction of the drop solidified.

  4. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    DOEpatents

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  5. High pressure liquid and gaseous oxygen impact sensitivity evaluation of materials for use at Kennedy Space Center

    NASA Technical Reports Server (NTRS)

    Bryan, C. J.

    1976-01-01

    The sensitivity of materials in contact with gaseous oxygen (GOX) or liquid oxygen (LOX) was examined. Specifically, the reactivity of materials when in contact with GOX or LOX if subjected to such stimuli as mechanical impact, adiabatic compression (pneumatic impact), or an electrical discharge in the form of a spark were examined. Generally, materials are more sensitive in gaseous oxygen than in liquid oxygen and impact sensitivity is known to increase with increasing pressure. Materials presently being used or considered for use in oxygen systems at KSC were evaluated. Results are given in tabular form.

  6. Thermal Performance Testing of EMU and OSS Liquid Cooling Garments

    NASA Technical Reports Server (NTRS)

    Rhodes, Richard; Bue, Grant; Hakam, Mary

    2012-01-01

    A test was conducted to evaluate three factors influencing the thermal performance of liquid cooling garments (LCG): (1) the comparable thermal performance of an Oceaneering developed engineering evaluation unit (EEU) prototype LDG, (2) the effect of the thermal comfort undergarment (TCU), and (3) the performance of a torso or upper body only LCG configuration. To evaluate the thermal performance of each configuration a metabolic test was conducted, utilizing suited subjects to generate the metabolic heat. For this study three (3) test subjects of similar health and weight produced a metabolic load on the LDG configuration by either resting (300-600 BTU/hr), walking at a slow pace (1200 BRU/hr), and walking at a brisk pace (2200 BTU/hr), as outlined in Figure 1, the metabolic profile. During the test, oxygen consumption, heart rate, relative humidity, air flow, inlet and outlet air pressure, inlet and outlet air temperature, delta air temperature, water flow (100 lb/hr), inlet water temperature (64 F), delta water temperature, water pressure, core body temperature, skin temperature, and sweat loss data was recorded. Four different test configurations were tested, with one configuration tested twice, as outlined in Table 1. The test was conducted with the suit subjects wearing the Demonstrator Suit, pressurized to vent pressure (approximately 0.5 psig). The demonstrator suit has an integrated ventilation duct system and was used to create a relevant environment with a captured ventilation return, an integrated vent tree, and thermal insulation from the environment.

  7. Triple-channel microreactor for biphasic gas-liquid reactions: Photosensitized oxygenations.

    PubMed

    Maurya, Ram Awatar; Park, Chan Pil; Kim, Dong-Pyo

    2011-01-01

    A triple-channel microreactor fabricated by means of a soft-lithography technique was devised for efficient biphasic gas-liquid reactions. The excellent performance of the microreactor was demonstrated by carrying out photosensitized oxygenations of α-terpinene, citronellol, and allyl alcohols.

  8. Investigation of the reactivity of organic materials in liquid oxygen

    NASA Technical Reports Server (NTRS)

    Chamberlain, D.; Irwin, K.; Kirshen, N.; Mill, T.; Stringham, R.

    1970-01-01

    Measurements of impact-ignition sensitivity and studies of the relative reactivity of t-butoxy and t-butyl peroxy radicals toward a variety of organic compounds reveal improved methods of selection of materials for safe use in a liquid oxygen environment.

  9. Development of a thermal-hydraulics experimental system for high Tc superconductors cooled by liquid hydrogen

    NASA Astrophysics Data System (ADS)

    Tatsumoto, H.; Shirai, Y.; Shiotsu, M.; Hata, K.; Kobayashi, H.; Naruo, Y.; Inatani, Y.; Kato, T.; Futakawa, M.; Kinoshita, K.

    2010-06-01

    A thermal-hydraulics experimental system of liquid hydrogen was developed in order to investigate the forced flow heat transfer characteristics in the various cooling channels for wide ranges of subcoolings, flow velocities, and pressures up to supercritical. A main tank is connected to a sub tank through a hydrogen transfer line with a control valve. A channel heater is located at one end of the transfer line in the main tank. Forced flow through the channel is produced by adjusting the pressure difference between the tanks and the valve opening. The mass flow rate is measured from the weight change of the main tank. For the explosion protection, electrical equipments are covered with a nitrogen gas blanket layer and a remote control system was established. The first cryogenic performance tests confirmed that the experimental system had satisfied with the required performances. The forced convection heat transfer characteristics was successfully measured at the pressure of 0.7 MPa for various flow velocities.

  10. Liquid-Hydrogen-Cooled 450-hp Electric Motor Test Stand Being Developed

    NASA Technical Reports Server (NTRS)

    Kascak, Albert F.; Trudell, Jeffrey J.; Brown, Gerald V.

    2005-01-01

    With growing concerns about global warming, there is a need to develop pollution-free aircraft. One approach is to use hydrogen-fueled aircraft that use fuel cells or turbogenerators to produce electric power to drive the electric motors that turn the aircraft s propulsive fans. Hydrogen fuel would be carried as a liquid, stored at its boiling point of 20.5 K (-422.5 F). Conventional electric motors, however, are too heavy for aircraft propulsion. We need to develop high-power, lightweight electric motors (highpower- density motors). One approach is to increase the conductivity of the wires by cooling them with liquid hydrogen (LH2). This would allow superconducting rotors with an ironless core. In addition, the motor could use very pure aluminum or copper, substances that have low resistances at cryogenic temperatures. A preliminary design of a 450-hp LH2-cooled electric motor was completed and is being manufactured by a contractor. This motor will be tested at the NASA Glenn Research Center and will be used to test different superconducting materials such as magnesium diboride (MgB2). The motor will be able to operate at speeds of up to 6000 rpm.

  11. Bubble Point Measurements with Liquid Methane of a Screen Capillary Liquid Acquisition Device

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; McQuillen, John B.

    2009-01-01

    Liquid acquisition devices (LADs) can be utilized within a propellant tank in space to deliver single-phase liquid to the engine in low gravity. One type of liquid acquisition device is a screened gallery whereby a fine mesh screen acts as a bubble filter and prevents the gas bubbles from passing through until a crucial pressure differential condition across the screen, called the bubble point, is reached. This paper presents data for LAD bubble point data in liquid methane (LCH4) for stainless steel Dutch twill screens with mesh sizes of 325 by 2300 and 200 by 1400 wires per inch. Data is presented for both saturated and sub-cooled LCH4, and is compared with predicted values.

  12. Liquid films on shake flask walls explain increasing maximum oxygen transfer capacities with elevating viscosity.

    PubMed

    Giese, Heiner; Azizan, Amizon; Kümmel, Anne; Liao, Anping; Peter, Cyril P; Fonseca, João A; Hermann, Robert; Duarte, Tiago M; Büchs, Jochen

    2014-02-01

    In biotechnological screening and production, oxygen supply is a crucial parameter. Even though oxygen transfer is well documented for viscous cultivations in stirred tanks, little is known about the gas/liquid oxygen transfer in shake flask cultures that become increasingly viscous during cultivation. Especially the oxygen transfer into the liquid film, adhering on the shake flask wall, has not yet been described for such cultivations. In this study, the oxygen transfer of chemical and microbial model experiments was measured and the suitability of the widely applied film theory of Higbie was studied. With numerical simulations of Fick's law of diffusion, it was demonstrated that Higbie's film theory does not apply for cultivations which occur at viscosities up to 10 mPa s. For the first time, it was experimentally shown that the maximum oxygen transfer capacity OTRmax increases in shake flasks when viscosity is increased from 1 to 10 mPa s, leading to an improved oxygen supply for microorganisms. Additionally, the OTRmax does not significantly undermatch the OTRmax at waterlike viscosities, even at elevated viscosities of up to 80 mPa s. In this range, a shake flask is a somehow self-regulating system with respect to oxygen supply. This is in contrary to stirred tanks, where the oxygen supply is steadily reduced to only 5% at 80 mPa s. Since, the liquid film formation at shake flask walls inherently promotes the oxygen supply at moderate and at elevated viscosities, these results have significant implications for scale-up. © 2013 Wiley Periodicals, Inc.

  13. Extravehicular mobility unit subcritical liquid oxygen storage and supply system

    NASA Technical Reports Server (NTRS)

    Anderson, John; Martin, Timothy; Hodgson, ED

    1992-01-01

    The storage of life support oxygen in the Extravehicular Mobility Unit in the liquid state offers some advantages over the current method of storing the oxygen as a high pressure gas. Storage volume is reduced because of the increased density associated with liquid. The lower storage and operating pressures also reduce the potential for leakage or bursting of the storage tank. The potential for combustion resulting from adiabatic combustion of the gas within lines and components is substantially reduced. Design constraints on components are also relaxed due to the lower system pressures. A design study was performed to determine the requirements for a liquid storage system and prepare a conceptual design. The study involved four tasks. The first was to identify system operating requirements that influence or direct the design of the system. The second was to define candidate storage system concepts that could possibly satisfy the requirements. An evaluation and comparison of the candidate concepts was conducted in the third task. The fourth task was devoted to preparing a conceptual design of the recommended storage system and to evaluate concerns with integration of the concept into the EMU. The results are presented.

  14. Experimental and simulation study of a Gaseous oxygen/Gaseous hydrogen vortex cooling thrust chamber

    NASA Astrophysics Data System (ADS)

    Yu, Nanjia; Zhao, Bo; Li, Gongnan; Wang, Jue

    2016-01-01

    In this paper, RNG k-ε turbulence model and PDF non-premixed combustion model are used to simulate the influence of the diameter of the ring of hydrogen injectors and oxidizer-to-fuel ratio on the specific impulse of the vortex cooling thrust chamber. The simulation results and the experimental tests of a 2000 N Gaseous oxygen/Gaseous hydrogen vortex cooling thrust chamber reveal that the efficiency of the specific impulse improves significantly with increasing of the diameter of the ring of hydrogen injectors. Moreover, the optimum efficiency of the specific impulse is obtained when the oxidizer-to-fuel ratio is near the stoichiometric ratio.

  15. Triple-channel microreactor for biphasic gas–liquid reactions: Photosensitized oxygenations

    PubMed Central

    Maurya, Ram Awatar; Park, Chan Pil

    2011-01-01

    Summary A triple-channel microreactor fabricated by means of a soft-lithography technique was devised for efficient biphasic gas–liquid reactions. The excellent performance of the microreactor was demonstrated by carrying out photosensitized oxygenations of α-terpinene, citronellol, and allyl alcohols. PMID:21915221

  16. 142. STANDBY PRESSURE CONTROL UNIT FOR FUEL AND LIQUID OXYGEN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    142. STANDBY PRESSURE CONTROL UNIT FOR FUEL AND LIQUID OXYGEN IN SOUTHWEST PORTION OF CONTROL ROOM (214), LSB (BLDG. 751), FACING WEST - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 East, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  17. 30 CFR 250.217 - What solid and liquid wastes and discharges information and cooling water intake information must...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What solid and liquid wastes and discharges... of Exploration Plans (ep) § 250.217 What solid and liquid wastes and discharges information and cooling water intake information must accompany the EP? The following solid and liquid wastes and...

  18. Dynamics of a Finite Liquid Oxygen (LOX) Column in a Pulsed Magnetic Field

    NASA Technical Reports Server (NTRS)

    Youngquist, Robert; Immer, Christopher; Lane, John; Simpson, James; Steinrock, T. (Technical Monitor)

    2002-01-01

    It is well known that liquid oxygen has a sufficient paramagnetic susceptibility that a strong magnetic field gradient can lift it in the earth's gravitational field. The movement of liquid oxygen is vital to the space program since it one of the primary oxidizers used for propulsion. Transport of liquid oxygen (LOX) via direct interaction of the magnetic fields (B field) with the fluid is a current topic of research and development at Kennedy Space Center, FL. This method of transporting (i.e. pumping) LOX may have particular advantages on Mars and other reduced gravitational environments, namely safety and reliability. This paper will address transport of a magnetic fluid, LOX, via phased-pulsed electromagnets acting on the edge of the column of fluid. The authors have developed a physical model from first-principles for the motion of a magnetic fluid in a particular U-tube geometry subjected to a pulsed magnetic field from an arbitrary solenoidal electromagnet. Experimental data that have been collected from the analogous geometry correlate well to that of the ab-initio calculations.

  19. Methods and apparatus for cooling electronics

    DOEpatents

    Hall, Shawn Anthony; Kopcsay, Gerard Vincent

    2014-12-02

    Methods and apparatus are provided for choosing an energy-efficient coolant temperature for electronics by considering the temperature dependence of the electronics' power dissipation. This dependence is explicitly considered in selecting the coolant temperature T.sub.0 that is sent to the equipment. To minimize power consumption P.sub.Total for the entire system, where P.sub.Total=P.sub.0+P.sub.Cool is the sum of the electronic equipment's power consumption P.sub.0 plus the cooling equipment's power consumption P.sub.Cool, P.sub.Total is obtained experimentally, by measuring P.sub.0 and P.sub.Cool, as a function of three parameters: coolant temperature T.sub.0; weather-related temperature T.sub.3 that affects the performance of free-cooling equipment; and computational state C of the electronic equipment, which affects the temperature dependence of its power consumption. This experiment provides, for each possible combination of T.sub.3 and C, the value T.sub.0* of T.sub.0 that minimizes P.sub.Total. During operation, for any combination of T.sub.3 and C that occurs, the corresponding optimal coolant temperature T.sub.0* is selected, and the cooling equipment is commanded to produce it.

  20. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gerlach, T.M.

    1993-02-01

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical datamore » shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  1. 30 CFR 250.248 - What solid and liquid wastes and discharges information and cooling water intake information must...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What solid and liquid wastes and discharges...) § 250.248 What solid and liquid wastes and discharges information and cooling water intake information must accompany the DPP or DOCD? The following solid and liquid wastes and discharges information and...

  2. Oxygen-hydrogen thrusters for Space Station auxiliary propulsion systems

    NASA Technical Reports Server (NTRS)

    Berkman, D. K.

    1984-01-01

    The feasibility and technology requirements of a low-thrust, high-performance, long-life, gaseous oxygen (GO2)/gaseous hydrogen (GH2) thruster were examined. Candidate engine concepts for auxiliary propulsion systems for space station applications were identified. The low-thrust engine (5 to 100 lb sub f) requires significant departure from current applications of oxygen/hydrogen propulsion technology. Selection of the thrust chamber material and cooling method needed or long life poses a major challenge. The use of a chamber material requiring a minimum amount of cooling or the incorporation of regenerative cooling were the only choices available with the potential of achieving very high performance. The design selection for the injector/igniter, the design and fabrication of a regeneratively cooled copper chamber, and the design of a high-temperature rhenium chamber were documented and the performance and heat transfer results obtained from the test program conducted at JPL using the above engine components presented. Approximately 115 engine firings were conducted in the JPL vacuum test facility, using 100:1 expansion ratio nozzles. Engine mixture ratio and fuel-film cooling percentages were parametrically investigated for each test configuration.

  3. 73. DETAIL OF LIQUID OXYGEN STORAGE PRESSURE GAUGE IN UPPER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    73. DETAIL OF LIQUID OXYGEN STORAGE PRESSURE GAUGE IN UPPER LEFT CORNER OF WEST SIDE OF CENTER SKID IN CA-133-1-C-69 - Vandenberg Air Force Base, Space Launch Complex 3, Launch Pad 3 West, Napa & Alden Roads, Lompoc, Santa Barbara County, CA

  4. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOEpatents

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  5. Multilayer composite material and method for evaporative cooling

    NASA Technical Reports Server (NTRS)

    Buckley, Theresa M. (Inventor)

    2002-01-01

    A multilayer composite material and method for evaporative cooling of a person employs an evaporative cooling liquid that changes phase from a liquid to a gaseous state to absorb thermal energy. The evaporative cooling liquid is absorbed into a superabsorbent material enclosed within the multilayer composite material. The multilayer composite material has a high percentage of the evaporative cooling liquid in the matrix. The cooling effect can be sustained for an extended period of time because of the high percentage of phase change liquid that can be absorbed into the superabsorbent. Such a composite can be used for cooling febrile patients by evaporative cooling as the evaporative cooling liquid in the matrix changes from a liquid to a gaseous state to absorb thermal energy. The composite can be made with a perforated barrier material around the outside to regulate the evaporation rate of the phase change liquid. Alternatively, the composite can be made with an imperveous barrier material or semipermeable membrane on one side to prevent the liquid from contacting the person's skin. The evaporative cooling liquid in the matrix can be recharged by soaking the material in the liquid. The multilayer composite material can be fashioned into blankets, garments and other articles.

  6. Data center cooling method

    DOEpatents

    Chainer, Timothy J.; Dang, Hien P.; Parida, Pritish R.; Schultz, Mark D.; Sharma, Arun

    2015-08-11

    A method aspect for removing heat from a data center may use liquid coolant cooled without vapor compression refrigeration on a liquid cooled information technology equipment rack. The method may also include regulating liquid coolant flow to the data center through a range of liquid coolant flow values with a controller-apparatus based upon information technology equipment temperature threshold of the data center.

  7. Intermediates of Krebs cycle correct the depression of the whole body oxygen consumption and lethal cooling in barbiturate poisoning in rat.

    PubMed

    Ivnitsky, Jury Ju; Schäfer, Timur V; Malakhovsky, Vladimir N; Rejniuk, Vladimir L

    2004-10-01

    Rats poisoned with one LD50 of thiopental or amytal are shown to increase oxygen consumption when intraperitoneally given sucinate, malate, citrate, alpha-ketoglutarate, dimethylsuccinate or glutamate (the Krebs cycle intermediates or their precursors) but not when given glucose, pyruvate, acetate, benzoate or nicotinate (energy substrates of other metabolic stages etc). Survival was increased with succinate or malate from control groups, which ranged from 30-83% to 87-100%. These effects were unrelated to respiratory depression or hypoxia as judged by little or no effect of succinate on ventilation indices and by the lack of effect of oxygen administration. Body cooling of comatose rats at ambient temperature approximately 19 degrees C became slower with succinate, the rate of cooling correlated well with oxygen consumption decrease. Succinate had no potency to modify oxygen consumption and body temperature in intact rats. A condition for antidote effect of the Krebs intermediate was sufficiently high dosage (5 mmol/kg), further dose increase made no odds. Repeated dosing of succinate had more marked protective effect, than a single one, to oxygen consumption and tended to promote the attenuation of lethal effect of barbiturates. These data suggest that suppression of whole body oxygen consumption with barbiturate overdose could be an important contributor to both body cooling and mortality. Intermediates of Krebs cycle, not only succinate, may have a pronounced therapeutic effect under the proper treatment regimen. Availability of Krebs cycle intermediates may be a limiting factor for the whole body oxygen consumption in barbiturate coma, its role in brain needs further elucidation.

  8. Cryogenics for the MuCool Test Area (MTA)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Darve, Christine; Norris, Barry; Pei, Liu-Jin

    2005-09-01

    MuCool Test Area (MTA) is a complex of buildings at Fermi National Accelerator Laboratory, which are dedicated to operate components of a cooling cell to be used for Muon Collider and Neutrino Factory R&D. The long-term goal of this facility is to test ionization cooling principles by operating a 25-liter liquid hydrogen (LH{sub 2}) absorber embedded in a 5 Tesla superconducting solenoid magnet. The MTA solenoid magnet will be used with RF cavities exposed to a high intensity beam. Cryogens used at the MTA include LHe, LN{sub 2} and LH{sub 2}. The latter dictates stringent system design for hazardous locations.more » The cryogenic plant is a modified Tevatron refrigerator based on the Claude cycle. The implementation of an in-house refrigerator system and two 300 kilowatt screw compressors is under development. The helium refrigeration capacity is 500 W at 14 K. In addition the MTA solenoid magnet will be batch-filled with LHe every 2 days using the same cryo-plant. This paper reviews cryogenic systems used to support the Muon Collider and Neutrino Factory R&D programs and emphasizes the feasibility of handling cryogenic equipment at MTA in a safe manner.« less

  9. KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers install the liquid oxygen feedline for the 17-inch disconnect on orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers install the liquid oxygen feedline for the 17-inch disconnect on orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  10. An experimental investigation of the cooling channel geometry effects on the internal forced convection of liquid methane

    NASA Astrophysics Data System (ADS)

    Trejo, Adrian

    Rocket engine fuel alternatives have been an area of discussion for use in high performance engines and deep spaceflight missions. In particular, LCH4 has showed promise as an alternative option in regeneratively cooled rocket engines due to its non-toxic nature, similar storage temperatures to liquid oxygen, and its potential as an in situ resource. However, data pertaining to the heat transfer characteristics of LCH4 is limited. For this reason, a High Heat Transfer Test Facility (HHTTF) at the University of Texas at El Paso's (UTEP) Center for Space Exploration Technology and Research has been developed for the purpose of flowing LCH4 through several heated tube geometry designs subjected to a constant heat flux. In addition, a Methane Condensing Unit (MCU) is integrated to the system setup to supply LCH4 to the test facility. Through the use of temperature and pressure measurements, this experiment will serve not only to study the heat transfer characteristics of LCH4; it serves as a method of simulating the cooling channels of a regeneratively cooled rocket engine at a subscale level. The cross sections for the cooling channels investigated are a 1.8 mm x 1.8 mm square channel, 1.8 mm x 4.1 mm rectangular channel, 3.2 mm and 6.34 mm inside diameter channel, and a 1.8 mm x 14.2 mm high aspect ratio cooling channel (HARCC). The test facility is currently designed for test pressures between 1.03 MPa to 2.06 MPa and heat fluxes up to 5 MW/m2. Results show that at the given test pressures, the Reynolds number reaches up to 140,000 for smaller cooling channels (3.2 mm diameter tube and 1.8 mm x 4.1 mm rectangle) while larger cooling channel geometries (6.35 mm diameter and HARCC) reached Reynolds number around 70,000. Nusselt numbers reached as high as 320 and 265 for a 3.2 mm diameter tube and 1.8 mm x 4.1 mm rectangular channel respectively. For cooling channel geometries with 6.35 mm diameter and HARCC geometry, Nusselt numbers reached 136 (excluding an outlier

  11. CHARACTERIZATION OF AN ACTIVELY COOLED METAL FOIL THERMAL RADIATION SHIELD

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Feller, J. R.; Salerno, L. J.; Kashani, A.

    2010-04-09

    Zero boil-off (ZBO) or reduced boil-off (RBO) systems that involve active cooling of large cryogenic propellant tanks will most likely be required for future space exploration missions. For liquid oxygen or methane, such systems could be implemented using existing high technology readiness level (TRL) cryocoolers. However, for liquid hydrogen temperatures (approx20 K) no such coolers exist. In order to partially circumvent this technology gap, the concept of broad area cooling (BAC) has been developed, whereby a low mass thermal radiation shield could be maintained at temperatures around 100 K by steady circulation of cold pressurized gas through a network ofmore » narrow tubes. By this method it is possible to dramatically reduce the radiative heat leak to the 20 K tank. A series of experiments, designed to investigate the heat transfer capabilities of BAC systems, have been conducted at NASA Ames Research Center (ARC). Results of the final experiment in this series, investigating heat transfer from a metal foil film to a distributed cooling line, are presented here.« less

  12. Conductor of high electrical current at high temperature in oxygen and liquid metal environment

    DOEpatents

    Powell, IV, Adam Clayton; Pati, Soobhankar; Derezinski, Stephen Joseph; Lau, Garrett; Pal, Uday B.; Guan, Xiaofei; Gopalan, Srikanth

    2016-01-12

    In one aspect, the present invention is directed to apparatuses for and methods of conducting electrical current in an oxygen and liquid metal environment. In another aspect, the invention relates to methods for production of metals from their oxides comprising providing a cathode in electrical contact with a molten electrolyte, providing a liquid metal anode separated from the cathode and the molten electrolyte by a solid oxygen ion conducting membrane, providing a current collector at the anode, and establishing a potential between the cathode and the anode.

  13. Comparison of heat transfer in liquid and slush nitrogen by numerical simulation of cooling rates for French straws used for sperm cryopreservation.

    PubMed

    Sansinena, M; Santos, M V; Zaritzky, N; Chirife, J

    2012-05-01

    Slush nitrogen (SN(2)) is a mixture of solid nitrogen and liquid nitrogen, with an average temperature of -207 °C. To investigate whether plunging a French plastic straw (commonly used for sperm cryopreservation) in SN(2) substantially increases cooling rates with respect to liquid nitrogen (LN(2)), a numerical simulation of the heat conduction equation with convective boundary condition was used to predict cooling rates. Calculations performed using heat transfer coefficients in the range of film boiling confirmed the main benefit of plunging a straw in slush over LN(2) did not arise from their temperature difference (-207 vs. -196 °C), but rather from an increase in the external heat transfer coefficient. Numerical simulations using high heat transfer (h) coefficients (assumed to prevail in SN(2)) suggested that plunging in SN(2) would increase cooling rates of French straw. This increase of cooling rates was attributed to a less or null film boiling responsible for low heat transfer coefficients in liquid nitrogen when the straw is placed in the solid-liquid mixture or slush. In addition, predicted cooling rates of French straws in SN(2) tended to level-off for high h values, suggesting heat transfer was dictated by heat conduction within the liquid filled plastic straw. Copyright © 2012 Elsevier Inc. All rights reserved.

  14. 12 CFR 563b.465 - Do account holders retain any voting rights based on their liquidation sub-accounts?

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... based on their liquidation sub-accounts? 563b.465 Section 563b.465 Banks and Banking OFFICE OF THRIFT... Account § 563b.465 Do account holders retain any voting rights based on their liquidation sub-accounts... their liquidation sub-accounts. ...

  15. Control of liquid cooling garments: technical control of body heat storage.

    PubMed

    Hexamer, M; Werner, J

    1996-07-01

    This paper describes a concept of how liquid cooling garments (LCG) can be automatically controlled by the objective physiological state. The technically controlled parameter was mean body temperature which was calculated from the measured rectal and mean skin temperature. This was motivated by the fact that mean body temperature is the basis for estimating body heat storage, a commonly used measure of thermal strain. Here the setpoint of mean body temperature was the individual value taken in a preceeding resting period and it was the task of the technical controller to keep the actual value of mean body temperature as close as possible to the setpoint. The most important tuning parameters of the controller were the weighting coefficients for rectal and mean skin temperature in the calculation for mean body temperature. The ratio of these two coefficients determined the degree of compensation for any rectal temperature shift by changing mean skin temperature. Test experiments were carried out (n = 5) in which the controller was able to clamp mean body temperature to the setpoint thereby preventing heat storage. Although exercise rate (75 W) was the same, sweating and warm discomfort occurred in some cases due to the individual rectal temperature rise. Another source of discomfort were delays or paradoxical time courses of rectal temperature at the start or end of exercise which were responsible for a delayed onset of cooling or heating. To avoid these effects, the oxygen consumption signal, which is very fast and directly correlated to the exercise rate, was added to the control loop. Each increase of this parameter above its resting level lowered suit temperature. As heat storage should not be completely rejected by this new signal pathway, the controller for mean body temperature still remained active. The repetition of the experiments showed that the load error in the control loop was smaller and the comfort level in transient phases higher. For a further

  16. Fail-safe system for activity cooled supersonic and hypersonic aircraft. [using liquid hydrogen fuel

    NASA Technical Reports Server (NTRS)

    Jones, R. A.; Braswell, D. O.; Richie, C. B.

    1975-01-01

    A fail-safe-system concept was studied as an alternative to a redundant active cooling system for supersonic and hypersonic aircraft which use the heat sink of liquid-hydrogen fuel for cooling the aircraft structure. This concept consists of an abort maneuver by the aircraft and a passive thermal protection system (TPS) for the aircraft skin. The abort manuever provides a low-heat-load descent from normal cruise speed to a lower speed at which cooling is unnecessary, and the passive TPS allows the aircraft skin to absorb the abort heat load without exceeding critical skin temperature. On the basis of results obtained, it appears that this fail-safe-system concept warrants further consideration, inasmuch as a fail-safe system could possibly replace a redundant active cooling system with no increase in weight and would offer other potential advantages.

  17. Liquid-hydrogen rocket engine development at Aerojet, 1944 - 1950

    NASA Technical Reports Server (NTRS)

    Osborn, G. H.; Gordon, R.; Coplen, H. L.; James, G. S.

    1977-01-01

    This program demonstrated the feasibility of virtually all the components in present-day, high-energy, liquid-rocket engines. Transpiration and film-cooled thrust chambers were successfully operated. The first liquid-hydrogen tests of the coaxial injector was conducted and the first pump to successfully produce high pressures in pumping liquid hydrogen was tested. A 1,000-lb-thrust gaseous propellant and a 3,000-lb-thrust liquid-propellant thrust chamber were operated satisfactorily. Also, the first tests were conducted to evaluate the effects of jet overexpansion and separation on performance of rocket thrust chambers with hydrogen-oxygen propellants.

  18. Dendrite-Free Potassium–Oxygen Battery Based on a Liquid Alloy Anode

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yu, Wei; Lau, Kah Chun; Lei, Yu

    The safety issue caused by the dendrite growth is not only a key research problem in lithium-ion batteries but also a critical concern in alkali metal (i.e., Li, Na, and K) oxygen batteries where a solid metal is usually used as the anode. Herein, we demonstrate the first dendrite-free K-O-2 battery at ambient temperature based on a liquid Na K alloy anode. The unique liquid liquid connection between the liquid alloy and the electrolyte in our alloy anode-based battery provides a homogeneous and robust anode electrolyte interface. Meanwhile, we manage to show that the Na K alloy is only compatiblemore » in K-O-2 batteries but not in Na-O-2 batteries, which is mainly attributed to the stronger reducibility of potassium and relatively more favorable thermodynamic formation of KO, over NaO2 during the discharge process. It is observed that our K-O-2 battery based on a liquid alloy anode shows a long cycle life (over 620 h) and a low discharge charge overpotential (about 0.05 V at initial cycles). Moreover, the mechanism investigation into the K-O-2 cell degradation shows that the 02 crossover effect and the ether electrolyte instability are the critical problems for K-O-2 batteries. In a word, this study provides a new route to solve the problems caused by the dendrite growth in alkali metal oxygen batteries.« less

  19. GreenChill Store Certification Protocol for Sub-Cooling Contained on Racks Separate from Refrigeration Equipment

    EPA Pesticide Factsheets

    Document describes the protocol used to determine the total load and refrigerant charge of stores that have placed all sub-cooling on a rack separate from all other commercial refrigeration equipment.

  20. 20. DECOMMISIONED HYDROGEN TANK IN FORMER LIQUID OXYGEN STORAGE AREA, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. DECOMMISIONED HYDROGEN TANK IN FORMER LIQUID OXYGEN STORAGE AREA, BETWEEN TEST STAND 1-A AND INSTRUMENTATION AND CONTROL BUILDING. Looking northwest. - Edwards Air Force Base, Air Force Rocket Propulsion Laboratory, Test Stand 1-A, Test Area 1-120, north end of Jupiter Boulevard, Boron, Kern County, CA

  1. Liquid Oxygen/Liquid Methane Integrated Propulsion System Test Bed

    NASA Technical Reports Server (NTRS)

    Flynn, Howard; Lusby, Brian; Villemarette, Mark

    2011-01-01

    In support of NASA?s Propulsion and Cryogenic Advanced Development (PCAD) project, a liquid oxygen (LO2)/liquid methane (LCH4) Integrated Propulsion System Test Bed (IPSTB) was designed and advanced to the Critical Design Review (CDR) stage at the Johnson Space Center. The IPSTB?s primary objectives are to study LO2/LCH4 propulsion system steady state and transient performance, operational characteristics and to validate fluid and thermal models of a LO2/LCH4 propulsion system for use in future flight design work. Two phase thermal and dynamic fluid flow models of the IPSTB were built to predict the system performance characteristics under a variety of operating modes and to aid in the overall system design work. While at ambient temperature and simulated altitude conditions at the White Sands Test Facility, the IPSTB and its approximately 600 channels of system instrumentation would be operated to perform a variety of integrated main engine and reaction control engine hot fire tests. The pressure, temperature, and flow rate data collected during this testing would then be used to validate the analytical models of the IPSTB?s thermal and dynamic fluid flow performance. An overview of the IPSTB design and analytical model development will be presented.

  2. MEMS based pumped liquid cooling systems for micro/nano spacecraft thermal control

    NASA Technical Reports Server (NTRS)

    Birur, G. C.; Shakkottai, P.; Sur, T. W.

    2000-01-01

    The electronic and other payload power densities in future micro/nano spacecraft are expected to exceed 25 Watts/cm(sup 2) and require advanced thermal control concepts and technologies to keep their payload within allowable temperature limits. This paper presents background on the need for pumped liquid cooling systems for future micro/nano spacecraft and results from this ongoing experimental investigation.

  3. Detection of oxygen species generated by WO{sub 3} modification fullerene/TiO{sub 2} in the degradation of 1,5-diphenyl carbazide

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Meng, Ze-Da; Department of Advanced Materials Science and Engineering, Hanseo University, Seosan-si, Chungnam-do 356-706; Zhu, Lei

    2014-08-15

    Highlights: • Reactive oxygen species were detected through oxidation reaction from DPCI to DPCO. • Generated reactive oxygen species and hydroxyl radicals can be analysed by DPCI degradation. • C{sub 60} have good effect in photo/ultrasonic degradation process. • Enhanced adsorption capacity can increase the degradation effect. • Photocatalytic activity attributed to photo-absorption effect by C{sub 60} and cooperative effect of WO{sub 3} and TiO{sub 2}. - Abstract: In the present work, powders with different relative mole ratios of WO{sub 3}-fullerene/TiO{sub 2} were irradiated by visible light and ultrasonic. The composite obtained was characterized by BET surface area measurements, X-raymore » diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), fourier transform infrared (FT-IR), transmission electron microscopy (TEM) and UV–vis analysis. A methylene blue (MB) solution under visible light and ultrasonic irradiation was used to determine the catalytic activity. The generation of reactive oxygen species were detected through the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). Finally, we performed experiments to find the optimum relative mole ratio of fullerene for the degradation of MB.« less

  4. Electrical insulator assembly with oxygen permeation barrier

    DOEpatents

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  5. Neuroprotection of hyperbaric oxygen therapy in sub-acute traumatic brain injury: not by immediately improving cerebral oxygen saturation and oxygen partial pressure.

    PubMed

    Zhou, Bao-Chun; Liu, Li-Jun; Liu, Bing

    2016-09-01

    Although hyperbaric oxygen (HBO) therapy can promote the recovery of neural function in patients who have suffered traumatic brain injury (TBI), the underlying mechanism is unclear. We hypothesized that hyperbaric oxygen treatment plays a neuroprotective role in TBI by increasing regional transcranial oxygen saturation (rSO 2 ) and oxygen partial pressure (PaO 2 ). To test this idea, we compared two groups: a control group with 20 healthy people and a treatment group with 40 TBI patients. The 40 patients were given 100% oxygen of HBO for 90 minutes. Changes in rSO 2 were measured. The controls were also examined for rSO 2 and PaO 2 , but received no treatment. rSO 2 levels in the patients did not differ significantly after treatment, but levels before and after treatment were significantly lower than those in the control group. PaO 2 levels were significantly decreased after the 30-minute HBO treatment. Our findings suggest that there is a disorder of oxygen metabolism in patients with sub-acute TBI. HBO does not immediately affect cerebral oxygen metabolism, and the underlying mechanism still needs to be studied in depth.

  6. Superconducting HTS coil made from round cable cooled by liquid nitrogen flow

    NASA Astrophysics Data System (ADS)

    Šouc, J.; Gömöry, F.; Vojenčiak, M.; Solovyov, M.; Seiler, E.; Kováč, J.; Frolek, L.

    2017-10-01

    The concept of simple cooling arrangement for superconducting coil made from a round cable based on high-temperature superconductor tapes is demonstrated. The cable architecture is similar to the Conductor on Round Core (CORC®) concept: it consists of eight superconducting tapes wound in two layers on a copper tube core in a helical manner. Such a Conductor on Round Tube hand-made cable 4 m long was used to wind the coil with eight turns on 14 cm diameter. Layers of commercial aerogel and polyurethane foam were applied to the coil to provide vacuum-less thermal insulation at its cooling by the flow of liquid nitrogen (LN) in the cable tube. The temperature of superconducting tapes was around 1 K above the coolant temperature in these conditions, causing about 16% reduction of the critical current compared to the LN bath cooling. Electromagnetic performance of the coil was calculated by the model based on the finite element method and the results compared with experimental observations.

  7. Effects of Environmental Oxygen Content and Dissolved Oxygen on the Surface Tension and Viscosity of Liquid Nickel

    NASA Astrophysics Data System (ADS)

    SanSoucie, M. P.; Rogers, J. R.; Kumar, V.; Rodriguez, J.; Xiao, X.; Matson, D. M.

    2016-07-01

    The NASA Marshall Space Flight Center's electrostatic levitation (ESL) laboratory has recently added an oxygen partial pressure controller. This system allows the oxygen partial pressure within the vacuum chamber to be measured and controlled in the range from approximately 10^{-28} {to} 10^{-9} bar, while in a vacuum atmosphere. The oxygen control system installed in the ESL laboratory's main chamber consists of an oxygen sensor, oxygen pump, and a control unit. The sensor is a potentiometric device that determines the difference in oxygen activity in two gas compartments (inside the chamber and the air outside of the chamber) separated by an electrolyte. The pump utilizes coulometric titration to either add or remove oxygen. The system is controlled by a desktop control unit, which can also be accessed via a computer. The controller performs temperature control for the sensor and pump, has a PID-based current loop and a control algorithm. Oxygen partial pressure has been shown to play a significant role in the surface tension of liquid metals. Oxide films or dissolved oxygen may lead to significant changes in surface tension. The effects on surface tension and viscosity by oxygen partial pressure in the surrounding environment and the melt dissolved oxygen content will be evaluated, and the results will be presented. The surface tension and viscosity will be measured at several different oxygen partial pressures while the sample is undercooled. Surface tension and viscosity will be measured using the oscillating droplet method.

  8. Cooling of Gas Turbines, IV - Calculated Temperature Distribution in the Trailing Part of a Turbine Blade Using Direct Liquid Cooling

    NASA Technical Reports Server (NTRS)

    Brown, W. Byron; Monroe, William R.

    1947-01-01

    A theoretical analysis of the temperature distribution through the trailing portion of a blade near the coolant passages of liquid cooled gas turbines was made. The analysis was applied to obtain the hot spot temperatures at the trailing edge and influence of design variables. The effective gas temperature was varied from 2000 degrees to 5000 degrees F in each investigation.

  9. Oxygen quenching in a LAB based liquid scintillator and the nitrogen bubbling model

    NASA Astrophysics Data System (ADS)

    Xiao, Hua-Lin; Deng, Jing-Shan; Wang, Nai-Yan

    2010-05-01

    The oxygen quenching effect in a Linear Alkl Benzene (LAB) based liquid scintillator (LAB as the solvent, 3 g/L 2, 5 diphe-nyloxazole (PPO) as the fluor and 15 mg/L p-bis-(o-methylstyryl)-benzene (bis-MSB) as the λ-shifter) is studied by measuring the light yield as a function of the nitrogen bubbling time. It is shown that the light yield of the fully purged liquid scintillator is increased by 11% at room temperature and the room atmospheric pressure. A simple nitrogen bubbling model is proposed to describe the relationship between the relative light yield (oxygen quenching factor) and the bubbling time.

  10. Ionic liquids as electrolytes for the development of a robust amperometric oxygen sensor.

    PubMed

    Wang, Zhe; Lin, Peiling; Baker, Gary A; Stetter, Joseph; Zeng, Xiangqun

    2011-09-15

    A simple Clark-type online electrochemical cell design, consisting of a platinum gauze working electrode and incorporating ionic liquids (IL) as electrolytes, has been successfully applied for the amperometric sensing of oxygen. Studying ILs comprising the bis(trifluoromethylsulfonyl)imide anion, the obtained analytical parameters were found to be strongly dependent on the choice of cation. Compared with a conventional Clark cell design based on an aqueous supporting electrolyte, the modified oxygen sensor achieves substantial improvements in performance and stability. A limit of detection for oxygen as low as 0.05 vol %, linearity over an oxygen partial pressure between 0% and 20%, and a steady-state response time of 2 min was demonstrated, with a stable analytical response shown over the examined period of 90 days with no obvious fouling of the electrode surface. Based on the attractive physical attributes of ionic liquids (e.g., thermal stability beyond 150 °C), one can envision intriguing utility in nonstandard conditions and long-term online applications, as well as extension to the determination of other gases, such as methane and nitric oxide.

  11. Fabrication and Properties of Micro-Nanoencapsulated Phase Change Materials for Internally-Cooled Liquid Desiccant Dehumidification

    PubMed Central

    Niu, Xiaofeng; Xu, Qing; Zhang, Yi; Zhang, Yue; Yan, Yufeng; Liu, Tao

    2017-01-01

    Micro-nanoencapsulated phase change materials (M-NEPCMs) are proposed to be useful in liquid desiccant dehumidification by restraining the temperature rise in the moisture-removal process and improving the dehumidification efficiency. In this paper, the n-octadecane M-NEPCMs with desirable thermal properties for internally-cooled dehumidification were fabricated by using compound emulsifiers through the in-situ polymerization method. Melamine-formaldehyde resin was used as the shell material. The effects of the mixing ratio, emulsification methods and amount of the compound emulsifiers on the morphology, size and thermal properties of the M-NEPCMs were investigated experimentally. The optimum weight mixing ratio of the compound emulsifiers is SDS (sodium dodecyl sulfate):Tween80 (polyoxyethylene sorbitan monooleate):Span80 (sorbitan monooleate) = 0.1:0.6:0.3, which achieves the best stability of the n-octadecane emulsion. When the compound emulsifiers are 10 wt. % of the core material, the melting enthalpy of M-NEPCMs reaches its maximum of 145.26 J/g of capsules, with an encapsulation efficiency of 62.88% and a mean diameter of 636 nm. The sub-cooling of the prepared M-NEPCMs is lower than 3 °C, with an acceptable thermal reliability after the thermal cycling test. A pre-emulsification prior to the addition of deionized water in the emulsification is beneficial to the morphology of the capsules, as the phase change enthalpy can be increased by 123.7%. PMID:28468282

  12. Fabrication and Properties of Micro-Nanoencapsulated Phase Change Materials for Internally-Cooled Liquid Desiccant Dehumidification.

    PubMed

    Niu, Xiaofeng; Xu, Qing; Zhang, Yi; Zhang, Yue; Yan, Yufeng; Liu, Tao

    2017-04-29

    Micro-nanoencapsulated phase change materials (M-NEPCMs) are proposed to be useful in liquid desiccant dehumidification by restraining the temperature rise in the moisture-removal process and improving the dehumidification efficiency. In this paper, the n -octadecane M-NEPCMs with desirable thermal properties for internally-cooled dehumidification were fabricated by using compound emulsifiers through the in-situ polymerization method. Melamine-formaldehyde resin was used as the shell material. The effects of the mixing ratio, emulsification methods and amount of the compound emulsifiers on the morphology, size and thermal properties of the M-NEPCMs were investigated experimentally. The optimum weight mixing ratio of the compound emulsifiers is SDS (sodium dodecyl sulfate):Tween80 (polyoxyethylene sorbitan monooleate):Span80 (sorbitan monooleate) = 0.1:0.6:0.3, which achieves the best stability of the n -octadecane emulsion. When the compound emulsifiers are 10 wt. % of the core material, the melting enthalpy of M-NEPCMs reaches its maximum of 145.26 J/g of capsules, with an encapsulation efficiency of 62.88% and a mean diameter of 636 nm. The sub-cooling of the prepared M-NEPCMs is lower than 3 °C, with an acceptable thermal reliability after the thermal cycling test. A pre-emulsification prior to the addition of deionized water in the emulsification is beneficial to the morphology of the capsules, as the phase change enthalpy can be increased by 123.7%.

  13. Principles of passive and active cooling of mirror-based hybrid systems employing liquid metals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anglart, Henryk

    This paper presents principles of passive and active cooling that are suitable to mirrorbased hybrid, nuclear fission/fusion systems. It is shown that liquid metal lead-bismuth cooling of the mirror machine with 25 m height and 1.5 GW thermal power is feasible both in the active mode during the normal operation and in the passive mode after the reactor shutdown. In the active mode the achievable required pumping power can well be below 50 MW, whereas the passive mode provides enough coolant flow to keep the clad temperature below the damage limits.

  14. Principles of passive and active cooling of mirror-based hybrid systems employing liquid metals

    NASA Astrophysics Data System (ADS)

    Anglart, Henryk

    2012-06-01

    This paper presents principles of passive and active cooling that are suitable to mirrorbased hybrid, nuclear fission/fusion systems. It is shown that liquid metal lead-bismuth cooling of the mirror machine with 25 m height and 1.5 GW thermal power is feasible both in the active mode during the normal operation and in the passive mode after the reactor shutdown. In the active mode the achievable required pumping power can well be below 50 MW, whereas the passive mode provides enough coolant flow to keep the clad temperature below the damage limits.

  15. Study of liquid oxygen/liquid hydrogen auxiliary propulsion systems for the space tug

    NASA Technical Reports Server (NTRS)

    Nichols, J. F.

    1975-01-01

    Design concepts are considered that permit use of a liquid-liquid (as opposed to gas-gas) oxygen/hydrogen thrust chamber for attitude control and auxiliary propulsion thrusters on the space tug. The best of the auxiliary propulsion system concepts are defined and their principal characteristics, including cost as well as operational capabilities, are established. Design requirements for each of the major components of the systems, including thrusters, are developed at the conceptual level. The competitive concepts considered use both dedicated (separate tanks) and integrated (propellant from main propulsion tanks) propellant supply. The integrated concept is selected as best for the space tug after comparative evaluation against both cryogenic and storable propellant dedicated systems. A preliminary design of the selected system is established and recommendations for supporting research and technology to further the concept are presented.

  16. Synthesis, crystal structure and magnetic properties of a new B-site ordered double perovskite Sr{sub 2}CuIrO{sub 6}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vasala, Sami; Yamauchi, Hisao; Karppinen, Maarit, E-mail: maarit.karppinen@aalto.fi

    2014-12-15

    Here we synthesize and characterize a new double-perovskite oxide Sr{sub 2}CuIrO{sub 6}. The synthesis requires the use of high oxygen pressure to stabilize the VI oxidation state of iridium. The compound has a tetragonally-distorted crystal structure due to the Jahn–Teller active Cu{sup II} ion, and a high degree of B-site cation order. Magnetic transition is apparent at 15 K, but the zero-field-cooled and field-cooled susceptibilities diverge below this temperature. The high degree of cation order would exclude the possibility of a typical spin-glass, indicating that the divergence is probably due to a frustration of the magnetic interactions between Cu andmore » Ir, with a high frustration factor of f≈25. - Graphical abstract: A new member of the A{sub 2}B′B″O{sub 6} double-perovskite family with JT-active Cu{sup II} at the B′ site and Ir{sup VI} at the B″ site is synthesized through high pressure synthesis and characterized for the structural and magnetic properties. - Highlights: • New member of the A{sub 2}CuB″O{sub 6} double-perovskite family is synthesized with B″=Ir. • Stabilization of Ir{sup VI} requires the use of high oxygen pressure synthesis. • Crystal structure is tetragonally distorted due to JT-active Cu{sup II}. • Divergence of ZFC and FC curves is seen below the T{sub N} of 15 K. • This is presumably due to a frustration effect.« less

  17. A study of the thermoregulatory characteristics of a liquid-cooled garment with automatic temperature control based on sweat rate: Experimental investigation and biothermal man-model development

    NASA Technical Reports Server (NTRS)

    Chambers, A. B.; Blackaby, J. R.; Miles, J. B.

    1973-01-01

    Experimental results for three subjects walking on a treadmill at exercise rates of up to 590 watts showed that thermal comfort could be maintained in a liquid cooled garment by using an automatic temperature controller based on sweat rate. The addition of head- and neck-cooling to an Apollo type liquid cooled garment increased its effectiveness and resulted in greater subjective comfort. The biothermal model of man developed in the second portion of the study utilized heat rates and exchange coefficients based on the experimental data, and included the cooling provisions of a liquid-cooled garment with automatic temperature control based on sweat rate. Simulation results were good approximations of the experimental results.

  18. Water Flow Performance of a Superscale Model of the Fastrac Liquid Oxygen Pump

    NASA Technical Reports Server (NTRS)

    Skelley, Stephen; Zoladz, Thomas

    1999-01-01

    As part of the National Aeronautics and Space Administration's ongoing effort to lower the cost of access to space, the Marshall Space Flight Center has developed a rocket engine with 60,000 pounds of thrust for use on the Reusable Launch Vehicle technology demonstrator slated for launch in 2000. This gas generator cycle engine, known as the Fastrac engine, uses liquid oxygen and RP-1 for propellants and includes single stage liquid oxygen and RP-1 pumps and a single stage supersonic turbine on a common shaft. The turbopump design effort included the first use and application of new suction capability prediction codes and three-dimensional blade generation codes in an attempt to reduce the turbomachinery design and certification costs typically associated with rocket engine development. To verify the pump's predicted cavitation performance, a water flow test of a superscale model of the Fastrac liquid oxygen pump was conducted to experimentally evaluate the liquid oxygen pump's performance at and around the design point. The water flow test article replicated the flow path of the Fastrac liquid oxygen pump in a 1.582x scale model, including scaled seal clearances for correct leakage flow at a model operating speed of 5000 revolutions per minute. Flow entered the 3-blade axial-flow inducer, transitioned to a shrouded, 6-blade radial impeller, and discharged into a vaneless radial diffuser and collection volute. The test article included approximately 50 total and static pressure measurement locations as well as flush-mounted, high frequency pressure transducers for complete mapping of the pressure environment. The primary objectives of the water flow test were to measure the steady-state and dynamic pressure environment of the liquid oxygen pump versus flow coefficient, suction specific speed, and back face leakage flow rate. Results showed excellent correlation between the predicted and experimentally measured pump head rise at low suction specific speeds. Likewise

  19. KENNEDY SPACE CENTER, FLA. - Workers in the Orbiter Processing Facility insert the liquid oxygen feedline for the 17-inch disconnect in the orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - Workers in the Orbiter Processing Facility insert the liquid oxygen feedline for the 17-inch disconnect in the orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  20. KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers raise the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers raise the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  1. KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers lift the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers lift the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  2. KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers move the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - In the Orbiter Processing Facility, workers move the liquid oxygen feedline for the 17-inch disconnect toward orbiter Discovery for installation. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  3. Thermal and dissolved oxygen characteristics of a South Carolina cooling reservoir

    USGS Publications Warehouse

    Oliver, James L.; Hudson, Patrick L.

    1987-01-01

    Temperature and dissolved oxygen concentrations were measured monthly from January 1971 to December 1982 at 1-m depth intervals at 13 stations in Keowee Reservoir in order to characterize spatial and temporal changes associated with operation of the Oconee Nuclear Station. The reservoir water column was i to 4°C warmer in operational than in non-operational years. The thermo-dine was at depths of 5 to 15 m before the operation of Oconee Nuclear Station, but was always below the upper level of the intake (20 m) after the station was in full operation; this suggests that pumping by the Oconee Nuclear Station had depleted all available cool hypolimnetic water to this depth. As a result summer water temperatures at depths greater than 10 m were usually 10°C higher after plant operation began than before. By fall the reservoir was nearly homothemious to a depth of 27 m, where a thermocine developed. Seasonal temperature profiles varied with distance from the plant; a cool water plume was evident in spring and a warm water plume was present in the summer, fall, and winter. A cold water plume also developed in the northern section of the reservoir due to the operation of Jocassee Pumped Storage Station. Increases in the mean water temperature of the reservoir during operational periods were correlated with the generating output of the power plant. The annual heat load to the reservoir increased by one-third after plant operations began. The alteration of the thermal stratification of the receiving water during the summer also caused the dissolved oxygen to mix to greater depths.

  4. Simulation of a 20-ton LiBr/H{sub 2}O absorption cooling system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wardono, B.; Nelson, R.M.

    The possibility of using solar energy as the main heat input for cooling systems has led to several studies of available cooling technologies that use solar energy. The results show that double-effect absorption cooling systems give relatively high performance. To further study absorption cooling systems, a computer code was developed for a double-effect lithium bromide/water (LiBr/H{sub 2}O) absorption system. To evaluate the performance, two objective functions were developed including the coefficient of performance (COP) and the system cost. Based on the system cost, an optimization to find the minimum cost was performed to determine the nominal heat transfer areas ofmore » each heat exchanger. The nominal values of other system variables, such as the mass flow rates and inlet temperatures of the hot water, cooling water, and chilled water, are specified as commonly used values for commercial machines. The results of the optimization show that there are optimum heat transfer areas. In this study, hot water is used as the main energy input. Using a constant load of 20 tons cooling capacity, the effects of various variables including the heat transfer ares, mass flow rates, and inlet temperatures of hot water, cooling water, and chilled water are presented.« less

  5. Introduction of oxygen vacancies and fluorine into TiO{sub 2} nanoparticles by co-milling with PTFE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Senna, Mamoru, E-mail: senna@applc.keio.ac.jp; Sepelak, Vladimir; Shi, Jianmin

    2012-03-15

    Solid-state processes of introducing oxygen vacancies and transference of fluorine to n-TiO{sub 2} nanoparticles by co-milling with poly(tetrafluoroethylene) (PTFE) powder were examined by diffuse reflectance spectroscopy (DRS) of UV, visual, near- and mid-IR regions, thermal analyses (TG-DTA), energy-dispersive X-ray spectroscopy (EDXS), X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The broad absorption peak at around 8800 cm{sup -1} (1140 nm) was attributed to the change in the electronic states, viz. electrons trapped at the oxygen vacancies (Vo) and d-d transitions of titanium ions. Incorporation of fluorine into n-TiO{sub 2} was concentrated at the near surfacemore » region and amounted to ca. 40 at% of the total fluorine in PTFE, after co-milling for 3 h, as confirmed by the F1s XPS spectrum. The overall atomic ratio, F/Ti, determined by EDXS was 0.294. By combining these analytical results, a mechanism of the present solid state processes at the boundary between PTFE and n-TiO{sub 2} was proposed. The entire process is triggered by the partial oxidative decomposition of PTFE. This is accompanied by the abstraction of oxygen atoms from the n-TiO{sub 2} lattices. Loss of the oxygen atoms results in the formation of the diverse states of locally distorted coordination units of titania, i.e. TiO{sub 6-n}Vo{sub n}, located at the near surface region. This leads subsequent partial ligand exchange between F and O, to incorporate fluorine preferentially to the near surface region of n-TiO{sub 2} particles, where local non-crystalline states predominate. - Graphical abstract: Scheme of the reaction processes: (a) pristine mixture, (b) oxygen abstraction from TiO{sub 2} and (c) fluorine migration from PTFE to TiO{sub 2}. Highlights: Transfer of fluorine from PTFE to n-TiO{sub 2} in a dry solid state process was confirmed. Black-Right-Pointing-Pointer 40% of F in PTFE was incorporated to

  6. Correlation of cylinder-head temperatures and coolant heat rejections of a multicylinder, liquid-cooled engine of 1710-cubic-inch displacement

    NASA Technical Reports Server (NTRS)

    Lundin, Bruce T; Povolny, John H; Chelko, Louis J

    1949-01-01

    Data obtained from an extensive investigation of the cooling characteristics of four multicylinder, liquid-cooled engines have been analyzed and a correlation of both the cylinder-head temperatures and the coolant heat rejections with the primary engine and coolant variables was obtained. The method of correlation was previously developed by the NACA from an analysis of the cooling processes involved in a liquid-cooled-engine cylinder and is based on the theory of nonboiling, forced-convection heat transfer. The data correlated included engine power outputs from 275 to 1860 brake horsepower; coolant flows from 50 to 320 gallons per minute; coolants varying in composition from 100 percent water to 97 percent ethylene glycol and 3 percent water; and ranges of engine speed, manifold pressure, carburetor-air temperature, fuel-air ratio, exhaust-gas pressure, ignition timing, and coolant temperature. The effect on engine cooling of scale formation on the coolant passages of the engine and of boiling of the coolant under various operating conditions is also discussed.

  7. Solid-phase fullerene-like nanostructures as singlet oxygen photosensitizers in liquid media

    NASA Astrophysics Data System (ADS)

    Belousova, I. M.; Danilov, O. B.; Kiselev, V. M.; Kislyakov, I. M.; Kris'ko, T. K.; Murav'eva, T. D.; Videnichev, D. A.

    2007-04-01

    Singlet oxygen generation by fullerene and astralen containing surfaces and powders under visible irradiation was studied in water and organic liquids by means of 1Δ g state luminescence and chemical scavenger transmittance measurements. The chemical method, pioneered for solid photosensitizers of 10 II, allowed to measure the singlet oxygen concentration in the aqueous medium down to 10 8 cm -3. The singlet oxygen sensitizing by the solid-phase fullerene-containing systems was found to be 100 times less effective then by fullerene in solution. The results obtained confirm the applicability of these structures in biology and medicine.

  8. Liquid oxygen liquid acquisition device bubble point tests with high pressure lox at elevated temperatures

    NASA Astrophysics Data System (ADS)

    Jurns, J. M.; Hartwig, J. W.

    2012-04-01

    When transferring propellant in space, it is most efficient to transfer single phase liquid from a propellant tank to an engine. In earth's gravity field or under acceleration, propellant transfer is fairly simple. However, in low gravity, withdrawing single-phase fluid becomes a challenge. A variety of propellant management devices (PMDs) are used to ensure single-phase flow. One type of PMD, a liquid acquisition device (LAD) takes advantage of capillary flow and surface tension to acquire liquid. The present work reports on testing with liquid oxygen (LOX) at elevated pressures (and thus temperatures) (maximum pressure 1724 kPa and maximum temperature 122 K) as part of NASA's continuing cryogenic LAD development program. These tests evaluate LAD performance for LOX stored in higher pressure vessels that may be used in propellant systems using pressure fed engines. Test data shows a significant drop in LAD bubble point values at higher liquid temperatures, consistent with lower liquid surface tension at those temperatures. Test data also indicates that there are no first order effects of helium solubility in LOX on LAD bubble point prediction. Test results here extend the range of data for LOX fluid conditions, and provide insight into factors affecting predicting LAD bubble point pressures.

  9. Liquid Oxygen Liquid Acquisition Device Bubble Point Tests with High Pressure LOX at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Jurns, John M.; Hartwig, Jason W.

    2011-01-01

    When transferring propellant in space, it is most efficient to transfer single phase liquid from a propellant tank to an engine. In earth s gravity field or under acceleration, propellant transfer is fairly simple. However, in low gravity, withdrawing single-phase fluid becomes a challenge. A variety of propellant management devices (PMD) are used to ensure single-phase flow. One type of PMD, a liquid acquisition device (LAD) takes advantage of capillary flow and surface tension to acquire liquid. The present work reports on testing with liquid oxygen (LOX) at elevated pressures (and thus temperatures) (maximum pressure 1724 kPa and maximum temperature 122K) as part of NASA s continuing cryogenic LAD development program. These tests evaluate LAD performance for LOX stored in higher pressure vessels that may be used in propellant systems using pressure fed engines. Test data shows a significant drop in LAD bubble point values at higher liquid temperatures, consistent with lower liquid surface tension at those temperatures. Test data also indicates that there are no first order effects of helium solubility in LOX on LAD bubble point prediction. Test results here extend the range of data for LOX fluid conditions, and provide insight into factors affecting predicting LAD bubble point pressures.

  10. Generation of singlet oxygen in fullerene-containing media: 2. Fullerene-containing solutions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bagrov, I V; Belousova, I M; Grenishin, A S

    2008-03-31

    The generation of singlet oxygen in fullerene solutions is studied by luminescence methods upon excitation by pulsed, repetitively pulsed, and continuous radiation sources. The concentration of singlet oxygen in solutions is measured in stationary and pulsed irradiation regimes. The rate constants of quenching of O{sub 2}({sup 1}{delta}{sub g}) by fullerenes C{sub 70} and C{sub 60} in the CCl{sub 4} solution are measured to be (7.2{+-}0.1)x10{sup 7} L mol{sup -1} s{sup -1} and less than 6x10{sup 4} L mol{sup -1} s{sup -1}, respectively. The temperature and photolytic variations in the generation properties of the fullerene solution exposed to intense continuous radiationmore » are studied by the methods of optical and EPR spectroscopy. Pulsed irradiation resulted in the production of singlet oxygen in suspensions of fullerene-like structures, in particular, astralenes. A liquid pulsed singlet-oxygen generator based on the fullerene solution in CCl{sub 4} is developed and studied, in which the yield of O{sub 2} ({sup 1}{delta}{sub g}) to the gas phase at concentrations up to 5x10{sup 16} cm{sup -3} is obtained. (laser applications and other topics in quantum electronics)« less

  11. History dependent crystallization of Zr{sub 41}Ti{sub 14}Cu{sub 12}Ni{sub 10}Be{sub 23} melts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schroers, Jan; Johnson, William L.

    The crystallization of Zr{sub 41}Ti{sub 14}Cu{sub 12}Ni{sub 10}Be{sub 23} (Vit 1) melts during constant heating is investigated. (Vit 1) melts are cooled with different rates into the amorphous state and the crystallization temperature upon subsequent heating is studied. In addition, Vit 1 melts are cooled using a constant rate to different temperatures and subsequently heated from this temperature with a constant rate. We investigate the influence of the temperature to which the melt was cooled on the crystallization temperature measured upon heating. In both cases the onset temperature of crystallization shows strong history dependence. This can be explained by anmore » accumulating process during cooling and heating. An attempt is made to consider this process in a simple model by steady state nucleation and subsequent growth of the nuclei which results in different crystallization kinetics during cooling or heating. Calculations show qualitative agreement with the experimental results. However, calculated and experimental results differ quantitatively. This difference can be explained by a decomposition process leading to a nonsteady nucleation rate which continuously increases with decreasing temperature. (c) 2000 American Institute of Physics.« less

  12. Vaporization Would Cool Primary Battery

    NASA Technical Reports Server (NTRS)

    Bhandari, Pradeep; Miyake, Robert N.

    1991-01-01

    Temperature of discharging high-power-density primary battery maintained below specified level by evaporation of suitable liquid from jacket surrounding battery, according to proposal. Pressure-relief valve regulates pressure and boiling temperature of liquid. Less material needed in cooling by vaporization than in cooling by melting. Technique used to cool batteries in situations in which engineering constraints on volume, mass, and location prevent attachment of cooling fins, heat pipes, or like.

  13. Sub- and super-Maxwellian evaporation of simple gases from liquid water

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kann, Z. R.; Skinner, J. L., E-mail: skinner@chem.wisc.edu

    2016-04-21

    Non-Maxwellian evaporation of light atoms and molecules (particles) such as He and H{sub 2} from liquids has been observed experimentally. In this work, we use simulations to study systematically the evaporation of Lennard-Jones particles from liquid water. We find instances of sub- and super-Maxwellian evaporation, depending on the mass of the particle and the particle-water interaction strength. The observed trends are in qualitative agreement with experiment. We interpret these trends in terms of the potential of mean force and the effectiveness and frequency of collisions during the evaporation process. The angular distribution of evaporating particles is also analyzed, and itmore » is shown that trends in the energy from velocity components tangential and normal to the liquid surface must be understood separately in order to interpret properly the angular distributions.« less

  14. Comparing two tetraalkylammonium ionic liquids. II. Phase transitions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lima, Thamires A.; Paschoal, Vitor H.; Faria, Luiz F. O.

    Phase transitions of the ionic liquids n-butyl-trimethylammonium bis(trifluoromethanesulfonyl)imide, [N{sub 1114}][NTf{sub 2}], and methyl-tributylammonium bis(trifluoromethanesulfonyl)imide, [N{sub 1444}][NTf{sub 2}], were investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD) measurements, and Raman spectroscopy. XRD and Raman spectra were obtained as a function of temperature at atmospheric pressure, and also under high pressure at room temperature using a diamond anvil cell (DAC). [N{sub 1444}][NTf{sub 2}] experiences glass transition at low temperature, whereas [N{sub 1114}][NTf{sub 2}] crystallizes or not depending on the cooling rate. Both the ionic liquids exhibit glass transition under high pressure. XRD and low-frequency Raman spectra provide a consistent physical picturemore » of structural ordering-disordering accompanying the thermal events of crystallization, glass transition, cold crystallization, pre-melting, and melting. Raman spectra in the high-frequency range of some specific cation and anion normal modes reveal conformational changes of the molecular structures along phase transitions.« less

  15. The prediction of nozzle performance and heat transfer in hydrogen/oxygen rocket engines with transpiration cooling, film cooling, and high area ratios

    NASA Technical Reports Server (NTRS)

    Kacynski, Kenneth J.; Hoffman, Joe D.

    1993-01-01

    An advanced engineering computational model has been developed to aid in the analysis and design of hydrogen/oxygen chemical rocket engines. The complete multi-species, chemically reacting and diffusing Navier-Stokes equations are modelled, finite difference approach that is tailored to be conservative in an axisymmetric coordinate system for both the inviscid and viscous terms. Demonstration cases are presented for a 1030:1 area ratio nozzle, a 25 lbf film cooled nozzle, and transpiration cooled plug-and-spool rocket engine. The results indicate that the thrust coefficient predictions of the 1030:1 nozzle and the film cooled nozzle are within 0.2 to 0.5 percent, respectively, of experimental measurements when all of the chemical reaction and diffusion terms are considered. Further, the model's predictions agree very well with the heat transfer measurements made in all of the nozzle test cases. The Soret thermal diffusion term is demonstrated to have a significant effect on the predicted mass fraction of hydrogen along the wall of the nozzle in both the laminar flow 1030:1 nozzle and the turbulent plug-and-spool rocket engine analysis cases performed. Further, the Soret term was shown to represent a significant fraction of the diffusion fluxes occurring in the transpiration cooled rocket engine.

  16. Kilowatt-level direct-'refractive index matching liquid'-cooled Nd:YLF thin disk laser resonator.

    PubMed

    Ye, Zhibin; Liu, Chong; Tu, Bo; Wang, Ke; Gao, Qingsong; Tang, Chun; Cai, Zhen

    2016-01-25

    A direct-liquid-cooled Nd:YLF thin disk laser resonator is presented, which features the use of refractive index matching liquid (RIML) as coolant. Highly uniform pump intensity distribution with rectangular shape is realized by using metallic planar waveguides. Much attention has been paid on the design of the gain module, including how to achieve excellent cooling ability with multi-channel coolers and how to choose the doping levels of the crystals for realizing well-distributed pump absorption. The flow velocity of the coolant is found to be a key parameter for laser performance and optimized to keep it in laminar flow status for dissipating unwanted heat load. A single channel device is used to measure the convective heat transfer coefficient (CHTC) at different flow velocities. Accordingly, the thermal stress in the disk is analyzed numerically and the maximum permissible thermal load is estimated. Experimentally, with ten pieces of a-cut Nd:YLF thin disks of different doping levels, a linear polarized laser with an average output power of 1120 W is achieved at the pump power of 5202 W, corresponding to an optical-optical efficiency of 21.5%, and a slope efficiency of 30.8%. Furthermore, the wavefront aberration of the gain module is measured to be quite weak, with a peak to valley (PV) value of 4.0 μm when it is pumped at 5202 W, which enables the feasibility of its application in an unstable resonator. To the best of our knowledge, this is the first demonstration of kilowatt-level direct-'refractive index matching liquid'-cooled Nd:YLF thin disk laser resonator.

  17. Evaluation of the Efficiency of Liquid Cooling Garments using a Thermal Manikin

    DTIC Science & Technology

    2005-05-01

    temperatures. The software also calculates thermal resistances and evaporative resistances. TM tests were run dry (i.e. no sweating ) and wet (i.e...REPORT DOCUMENTATION PAGE Form ApprovedOMB No . 0704-0188 SECURITY CLASSIFICATION OF REPORT SECURITY CLASSIFICATION OF THIS PAGE SECURITY CLASSIFICATION...OF ABSTRACT 8. M05-17 1. AGENCY USE ONLY (Leave blank) 4. TITLE AND SUBTITLE EVALUATION OF THE EFFICIENCY OF LIQUID COOLING GARMENTS USING A THERMAL

  18. Cooling Effectiveness of a Hybrid Microclimate Garment

    DTIC Science & Technology

    1988-04-01

    ELEMENT NO . NO . NO . JCCESSION NO .63747 D669 35 Cooling Effectiveness of a Hybrid Microclimate Garment (U) 12. PERSONAL AUTHOR(S) Barry S...be arranged. Therefore, no direct measurement of the cooling rate achieved by the air garments was obtained. After calculation of the liquid cooling...Cooling Performance. There was no significant difference between the levels of heat removed by the liquid and hybrid-liquid garments . The measured

  19. Natural Convection Heat Transfer in a Rectangular Liquid Metal Pool With Bottom Heating and Top Cooling

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Il S.; Yu, Yong H.; Son, Hyoung M.

    2006-07-01

    An experimental study is performed to investigate the natural convection heat transfer characteristics with subcooled coolant to create engineering database for basic applications in a lead alloy cooled reactor. Tests are performed in the ALTOS (Applied Liquid-metal Thermal Operation Study) apparatus as part of MITHOS (Metal Integrated Thermo Hydrodynamic Operation System). A relationship is determined between the Nusselt number Nu and the Rayleigh number Ra in the liquid metal rectangular pool. Results are compared with correlations and experimental data in the literature. Given the similar Ra condition, the present test results for Nu of the liquid metal pool with topmore » subcooling are found to be similar to those predicted by the existing correlations or experiments. The current test results are utilized to develop natural convection heat transfer correlations applicable to low Prandtl number Pr fluids that are heated from below and cooled by the external coolant above. Results from this study are slated to be used in designing BORIS (Battery Optimized Reactor Integral System), a small lead cooled modular fast reactor for deployment at remote sites cycled with MOBIS (Modular Optimized Brayton Integral System) for electricity generation, tied with NAVIS (Naval Application Vessel Integral System) for ship propulsion, joined with THAIS (Thermochemical Hydrogen Acquisition Integral System) for hydrogen production, and coupled with DORIS (Desalination Optimized Reactor Integral System) for seawater desalination. Tests are performed with Wood's metal (Pb-Bi-Sn-Cd) filling a rectangular pool whose lower surface is heated and upper surface cooled by forced convection of water. The test section is 20 cm long, 11.3 cm high and 15 cm wide. The simulant has a melting temperature of 78 deg. C. The constant temperature and heat flux condition was realized for the bottom heating once the steady state had been met. The test parameters include the heated bottom surface

  20. Preliminary Investigation of Performance and Starting Characteristics of Liquid Fluorine : Liquid Oxygen Mixtures with Jet Fuel

    NASA Technical Reports Server (NTRS)

    Rothenberg, Edward A; Ordin, Paul M

    1954-01-01

    The performance of jet fuel with an oxidant mixture containing 70 percent liquid fluorine and 30 percent liquid oxygen by weight was investigated in a 500-pound-thrust engine operating at a chamber pressure of 300 pounds per square inch absolute. A one-oxidant-on-one-fuel skewed-hole impinging-jet injector was evaluated in a chamber of characteristic length equal to 50 inches. A maximum experimental specific impulse of 268 pound-seconds per pound was obtained at 25 percent fuel, which corresponds to 96 percent of the maximum theoretical specific impulse based on frozen composition expansion. The maximum characteristic velocity obtained was 6050 feet per second at 23 percent fuel, or 94 percent of the theoretical maximum. The average thrust coefficient was 1.38 for the 500-pound thrust combustion-chamber nozzle used, which was 99 percent of the theoretical (frozen) maximum. Mixtures of fluorine and oxygen were found to be self-igniting with jet fuel with fluorine concentrations as low as 4 percent, when low starting propellant flow rated were used.

  1. Liquid oxygen/liquid hydrogen auxiliary power system thruster investigation

    NASA Technical Reports Server (NTRS)

    Eberle, E. E.; Kusak, L.

    1979-01-01

    The design, fabrication, and demonstration of a 111 newton (25 lb) thrust, integrated auxiliary propulsion system (IAPS) thruster for use with LH2/LO2 propellants is described. Hydrogen was supplied at a temperature range of 22 to 33 K (40 to 60 R), and oxygen from 89 to 122 K (160 to 220 R). The thruster was designed to operate in both pulse mode and steady-state modes for vehicle attitude control, space maneuvering, and as an abort backup in the event of failure of the main propulsion system. A dual-sleeve, tri-axial injection system was designed that utilizes a primary injector/combustor where 100 percent of the oxygen and 8 percent of the hydrogen is introduced; a secondary injector/combustor where 45 percent of the hydrogen is introduced to mix with the primary combustor gases; and a boundary layer injector that uses the remaining 45 percent of the hydrogen to cool the thrust throat/nozzle design. Hot-fire evaluation of this thruster with a BLC injection distance of 2.79 cm (1.10 in.) indicated that a specific impulse value of 390 sec can be attained using a coated molybdenum thrust chamber. Pulse mode tests indicated that a chamber pressure buildup to 90 percent thrust can be achieved in a time on the order of 48 msec. Some problems were encountered in achieving ignition of each pulse during pulse trains. This was interpreted to indicate that a higher delivered spark energy level ( 100 mJ) would be required to maintain ignition reliability of the plasma torch ignition system under the extra 'cold' conditions resulting during pulsing.

  2. Electrical insulator assembly with oxygen permeation barrier

    DOEpatents

    Van Der Beck, Roland R.; Bond, James A.

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  3. Role of Oxygen in Ionic Liquid Gating on Two-Dimensional Cr2Ge2Te6: A Non-oxide Material.

    PubMed

    Chen, Yangyang; Xing, Wenyu; Wang, Xirui; Shen, Bowen; Yuan, Wei; Su, Tang; Ma, Yang; Yao, Yunyan; Zhong, Jiangnan; Yun, Yu; Xie, X C; Jia, Shuang; Han, Wei

    2018-01-10

    Ionic liquid gating can markedly modulate a material's carrier density so as to induce metallization, superconductivity, and quantum phase transitions. One of the main issues is whether the mechanism of ionic liquid gating is an electrostatic field effect or an electrochemical effect, especially for oxide materials. Recent observation of the suppression of the ionic liquid gate-induced metallization in the presence of oxygen for oxide materials suggests the electrochemical effect. However, in more general scenarios, the role of oxygen in the ionic liquid gating effect is still unclear. Here, we perform ionic liquid gating experiments on a non-oxide material: two-dimensional ferromagnetic Cr 2 Ge 2 Te 6 . Our results demonstrate that despite the large increase of the gate leakage current in the presence of oxygen, the oxygen does not affect the ionic liquid gating effect on  the channel resistance of Cr 2 Ge 2 Te 6 devices (<5% difference), which suggests the electrostatic field effect as the mechanism on non-oxide materials. Moreover, our results show that ionic liquid gating is more effective on the modulation of the channel resistances compared to the back gating across the 300 nm thick SiO 2 .

  4. Liquid Methane/Oxygen Injector Study for Mars Ascent Engines

    NASA Technical Reports Server (NTRS)

    Trinh, Huu Phuoc

    1999-01-01

    As a part of the advancing technology of the cryogenic propulsion system for the Mars exploration mission, this effort aims at evaluating propellant injection concepts for liquid methane/liquid oxygen (LOX) rocket engines. Split-triplet and unlike impinging injectors were selected for this study. A total of four injector configurations were tested under combustion conditions in a modular combustor test article (MCTA), equipped with optically accessible windows, at MSFC. A series of forty hot-fire tests, which covered a wide range of engine operating conditions with the chamber pressure ranging from 320 to 510 and the mixture ratio from 1.5 to 3.5, were conducted. The test matrix also included a variation in the combustion chamber length for the purpose of investigating its effects on the combustion performance and stability. Initial assessments of the test results showed that the injectors provided stable combustion and there were no injector face overheating problems under all operating conditions. The Raman scattering signal measurement method was successfully demonstrated for the hydrocarbon/oxygen reactive flow field. The near-injector face flow field was visually observed through the use of an infrared camera. Chamber wall temperature, high frequency chamber pressure, and average throat section heat flux were also recorded throughout the test series. Assessments of the injector performance are underway.

  5. Sub-ppb Oxygen Contaminant Detection in Semi-Conductor Processing

    NASA Technical Reports Server (NTRS)

    Man, K. F.

    1995-01-01

    Gaseous contaminants such as oxygen, water vapor, nitrogen and hydrocarbons are often present in the processing environment in semiconductor device fabrication and in containerless materials processing. The contaminants arise as a result of outgassing from hot surfaces or they may be part of the impurities in commercial ultra-high purity gases. Among these gaseous contaminants, oxygen is the most reactive and, therefore, has the most adverse effects on the end product. There has been an intense effort at the Jet Propulsion Laboratory to develop different types of oxygen sorbents to reduce oxygen concentration in a microgravity processing environment to sub-ppb (parts-per-billion) levels. Higher concentrations can lead to rapid surface oxide formation, hence reducing the quality of semiconductor devices. If the concentration of oxygen in a processing chamber at 1000oC is in the ppb level, it will only take approximately 10 seconds for an oxide layer to form on the surface of a sample. The interaction of oxygen with the water surface can lead to the formation of localized defects in semi-conductor devices, hence decreasing the manufacturing yield. For example, efficient production of 64 Mb RAM chips requires contaminations below ppb levels. This paper describes a technique for measuring trace quantities of oxygen contaminants by recording the monoatomic negative ions, O-, using mass spectrometry. The O- formation from the e--O2 interaction utilizes the electron dissociative attachment method that is greatly enhanced at the resonant energy (6.8 eV). The device combines a small gridded electron ionizer with a compact mass spectrometer. The concentrations of oxygen have been measured using the method of standard additions by diluting O2 in N2. The lowest detection limit obtained was 1.2 kHz (O- count rate) at a concentration of 10-10, corresponding to 0.1 ppb.

  6. Preliminary study of gaseous nitrogen-liquid oxygen mixing and self cleaning

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1985-01-01

    The penetration of gaseous nitrogen into liquid oxygen at a pressure of 150 psi was determined by monitoring the composition of the evaporating liquid in a nitrogen analyzer. For pressurization times of about 1 hr the penetration depth varies between 0.0024 and 0.018 in. at an evaporation rate of about 1 gal/day. These are small compared to the penetration depth of 22.2 in. measured in the 7-inch high temperature tunnel at a pressure of 1500 psi, pressurization time of 5 min, and evaporation rate of 121 gal/day.

  7. Process for selection of oxygen-tolerant algal mutants that produce H{sub 2}

    DOEpatents

    Ghirardi, M.L.; Seibert, M.

    1999-02-16

    A process for selection of oxygen-tolerant, H{sub 2}-producing algal mutant cells comprises: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautotrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas and (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light; (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H{sub 2}-producing mutants. 5 figs.

  8. Process for selection of Oxygen-tolerant algal mutants that produce H.sub.2

    DOEpatents

    Ghirardi, Maria L.; Seibert, Michael

    1999-01-01

    A process for selection of oxygen-tolerant, H.sub.2 -producing algal mutant cells comprising: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas; (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light. (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H.sub.2 -producing mutants.

  9. Water Flow Performance of a Superscale Model of the Fastrac Liquid Oxygen Pump

    NASA Technical Reports Server (NTRS)

    Skelley, Stephen; Zoladz, Thomas

    2001-01-01

    As part of the National Aeronautics and Space Administration's ongoing effort to lower the cost of access to space, the Marshall Space Flight Center has developed a rocket engine with 60,000 pounds of thrust for use on the Reusable Launch Vehicle technology demonstrator slated for launch in 2000. This gas generator cycle engine, known as the Fastrac engine, uses liquid oxygen and RP-1 for propellants and includes single stage liquid oxygen and RP-1 pumps and a single stage supersonic turbine on a common shaft. The turbopump design effort included the first use and application of new suction capability prediction codes and three-dimensional blade generation codes in an attempt to reduce the turbomachinery design and certification costs typically associated with rocket engine development. To verify the pump's predicted cavitation performance, a water flow test of a superscale model of the Fastrac liquid oxygen pump was conducted to experimentally evaluate the liquid oxygen pump's performance at and around the design point. The water flow test article replicated the flow path of the Fastrac liquid oxygen pump in a 1.582x scale model, including scaled seal clearances for correct leakage flow at a model operating speed of 5000 revolutions per minute. Flow entered the 3-blade axial-flow inducer, transitioned to a shrouded, 6- blade radial impeller, and discharged into a vaneless radial diffuser and collection volute. The test article included approximately 50 total and static pressure measurement locations as well as flush-mounted, high frequency pressure transducers for complete mapping of the pressure environment. The primary objectives of the water flow test were to measure the steady-state and dynamic pressure environment of the liquid oxygen pump versus flow coefficient, suction specific speed, and back face leakage flow rate. Initial results showed acceptable correlation between the predicted and experimentally measured pump head rise at low suction specific speeds

  10. Effect of oxygen impurities on properties of the ternary superconductor SnMo/sub 6/S/sub 8/: Extended x-ray-absorption fine-structure determination of bond distances and local-density cluster calculations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guenzburger, D.; Ellis, D.E.; Montano, P.A.

    1985-10-01

    Electronic structure calculations were performed for clusters representing the Chevrel-phase SnMo/sub 6/S/sub 8/, with and without oxygen doping. In order to obtain the local structure around the Sn atom, extended x-ray-absorption fine-structure (EXAFS) measurements were made with synchro- tron radiation. The interatomic distances obtained experimentally were used in the calculations. The effect of oxygen doping on the Moessbauer isomer shift and quadrupole splitting values of /sup 119/Sn was investigated theoretically and compared with reported experimental values. The effect of oxygen substitution on the density of states at the Fermi energy of the (Mo/sub 6/S/sub 8/)/sup 2 -/ cluster was alsomore » studied. The results suggest that oxygen doping does not alter significantly the electronic structure of SnMo/sub 6/S/sub 8/.« less

  11. Significance of oxygen carriers and role of liquid paraffin in improving validamycin A production.

    PubMed

    Feng, Jinsong; Jiang, Jing; Liu, Yan; Li, Wei; Azat, Ramila; Zheng, Xiaodong; Zhou, Wen-Wen

    2016-10-01

    Validamycin A (Val-A) synthesized by Streptomyces hygroscopicus 5008 is widely used as a high-efficient antibiotic to protect plants from sheath blight disease. A novel fermentation strategy was introduced to stimulate Val-A production by adding oxygen carriers. About 58 % increase in Val-A production was achieved using liquid paraffin. Further, biomass, carbon source, metabolic genes, and metabolic enzymes were studied. It was also found that the supplementation of liquid paraffin increased the medium dissolved oxygen and intracellular oxidative stress level. The expression of the global regulators afsR and soxR sensitive to ROS, ugp catalyzing synthesis of Val-A precursor, and Val-A structural genes was enhanced. The change of the activities of glucose-6-phosphate dehydrogenase and glyceraldehyde 3-phosphate dehydrogenase was observed, which reflected the redirection of carbon metabolic flux. Based on these results, liquid paraffin addition as an oxygen carrier could be a useful technique in industrial production of Val-A and our study revealed a redox-based secondary metabolic regulation in S. hygroscopicus 5008, which provided a new insight into the regulation of the biosynthesis of secondary metabolites.

  12. KENNEDY SPACE CENTER, FLA. - Workers in the Orbiter Processing Facility oversee installation of the liquid oxygen feedline for the 17-inch disconnect on the orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - Workers in the Orbiter Processing Facility oversee installation of the liquid oxygen feedline for the 17-inch disconnect on the orbiter Discovery. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  13. Liquid Nitrogen (Oxygen Simulant) Thermodynamic Vent System Test Data Analysis

    NASA Technical Reports Server (NTRS)

    Hedayat, A.; Nelson, S. L.; Hastings, L. J.; Flachbart, R. H.; Tucker, S. P.

    2005-01-01

    In designing systems for the long-term storage of cryogens in low-gravity (space) environments, one must consider the effects of thermal stratification on tank pressure that will occur due to environmental heat leaks. During low-gravity operations, a Thermodynamic Vent System (TVS) concept is expected to maintain tank pressure without propellant resettling. A series of TVS tests was conducted at NASA Marshall Space Flight Center (MSFC) using liquid nitrogen (LN2) as a liquid oxygen (LO2) simulant. The tests were performed at tank til1 levels of 90%, 50%, and 25%, and with a specified tank pressure control band. A transient one-dimensional TVS performance program is used to analyze and correlate the test data for all three fill levels. Predictions and comparisons of ullage pressure and temperature and bulk liquid saturation pressure and temperature with test data are presented.

  14. Method for forming a liquid cooled airfoil for a gas turbine

    DOEpatents

    Grondahl, Clayton M.; Willmott, Leo C.; Muth, Myron C.

    1981-01-01

    A method for forming a liquid cooled airfoil for a gas turbine is disclosed. A plurality of holes are formed at spaced locations in an oversized airfoil blank. A pre-formed composite liquid coolant tube is bonded into each of the holes. The composite tube includes an inner member formed of an anti-corrosive material and an outer member formed of a material exhibiting a high degree of thermal conductivity. After the coolant tubes have been bonded to the airfoil blank, the airfoil blank is machined to a desired shape, such that a portion of the outer member of each of the composite tubes is contiguous with the outer surface of the machined airfoil blank. Finally, an external skin is bonded to the exposed outer surface of both the machined airfoil blank and the composite tubes.

  15. Microfabricated Liquid Rocket Motors

    NASA Technical Reports Server (NTRS)

    Epstein, Alan H.; Joppin, C.; Kerrebrock, J. L.; Schneider, Steven J. (Technical Monitor)

    2003-01-01

    Under NASA Glenn Research Center sponsorship, MIT has developed the concept of micromachined, bipropellant, liquid rocket engines. This is potentially a breakthrough technology changing the cost-performance tradeoffs for small propulsion systems, enabling new applications, and redefining the meaning of the term low-cost-access-to-space. With this NASA support, a liquid-cooled, gaseous propellant version of the thrust chamber and nozzle was designed, built, and tested as a first step. DARPA is currently funding MIT to demonstrate turbopumps and controls. The work performed herein was the second year of a proposed three-year effort to develop the technology and demonstrate very high power density, regeneratively cooled, liquid bipropellant rocket engine thrust chamber and nozzles. When combined with the DARPA turbopumps and controls, this work would enable the design and demonstration of a complete rocket propulsion system. The original MIT-NASA concept used liquid oxygen-ethanol propellants. The military applications important to DARPA imply that storable liquid propellants are needed. Thus, MIT examined various storable propellant combinations including N2O4 and hydrazine, and H2O2 and various hydrocarbons. The latter are preferred since they do not have the toxicity of N2O4 and hydrazine. In reflection of the newfound interest in H2O2, it is once again in production and available commercially. A critical issue for the microrocket engine concept is cooling of the walls in a regenerative design. This is even more important at microscale than for large engines due to cube-square scaling considerations. Furthermore, the coolant behavior of rocket propellants has not been characterized at microscale. Therefore, MIT designed and constructed an apparatus expressly for this purpose. The report details measurements of two candidate microrocket fuels, JP-7 and JP-10.

  16. Small, high-pressure liquid oxygen turbopump

    NASA Technical Reports Server (NTRS)

    Csomor, A.; Sutton, R.

    1977-01-01

    A small, high-pressure, liquid oxygen turbopump was designed, fabricated, and tested. The pump was of a single-stage, centrifugal type; power to the pump was supplied by a single-stage, partial emission, axial-impulse turbine. Design conditions included an operating speed of 70,000 rpm, pump discharge pressure of 2977 N/sq cm (4318 psia), and a pump flowrate of 16.4 kg/s (36.21 lb/sec). The turbine was propelled by LO2/LH2 combustion products at 1041 K (1874 R) inlet temperature, and at a design pressure ratio of 1.424. The approaches used in the detail analysis and design of the turbopump are described, and fabrication methods are discussed. Data obtained from gas generator tests, turbine performance calibration, and turbopump testing are presented.

  17. Liquid cooled plate heat exchanger for battery cooling of an electric vehicle (EV)

    NASA Astrophysics Data System (ADS)

    Rahman, M. M.; Rahman, H. Y.; Mahlia, T. M. I.; Sheng, J. L. Y.

    2016-03-01

    A liquid cooled plate heat exchanger was designed to improve the battery life of an electric vehicle which suffers from premature aging or degradation due to the heat generation during discharging and charging period. Computational fluid dynamics (CFD) was used as a tool to analyse the temperature distribution when a constant surface heat flux was set at the bottom surface of the battery. Several initial and boundary conditions were set based on the past studies on the plate heat exchanger in the simulation software. The design of the plate heat exchanger was based on the Nissan Leaf battery pack to analyse the temperature patterns. Water at different mass flow rates was used as heat transfer fluid. The analysis revealed the designed plate heat exchanger could maintain the surface temperature within the range of 20 to 40°C which is within the safe operating temperature of the battery.

  18. Potential of Organic Matrix Composites for Liquid Oxygen Tank

    NASA Technical Reports Server (NTRS)

    Davis, Samuel E.; Herald, Stephen D.; Stolzfus, Joel M.; Engel, Carl D.; Bohlen, James W.; Palm, Tod; Robinson, Michael J.

    2005-01-01

    Composite materials are being considered for the tankage of cryogenic propellants in access to space because of potentially lower structural weights. A major hurdle for composites is an inherent concern about the safety of using flammable structural materials in contact with liquid and gaseous oxygen. A hazards analysis approach addresses a series of specific concerns that must be addressed based upon test data. Under the 2nd Generation Reusable Launch Vehicle contracts, testing was begun for a variety of organic matrix composite materials both to aid in the selection of materials and to provide needed test data to support hazards analyses. The work has continued at NASA MSFC and the NASA WSTF to provide information on the potential for using composite materials in oxygen systems. Appropriate methods for oxygen compatibility testing of structural materials and data for a range of composite materials from impact, friction, flammability and electrostatic discharge testing are presented. Remaining concerns and conclusions about composite tank structures, and recommendations for additional testing are discussed. Requirements for system specific hazards analysis are identified.

  19. Scuffing Characteristics of High-Load Rolling/Sliding Contacts Operating in Liquid Oxygen: Effects of Materials and Surface Roughness

    NASA Technical Reports Server (NTRS)

    Chang, L.; Hall, P. B.; Thom, R.

    1996-01-01

    This research reports on an experimental study of the effects of materials and surface roughness on the scuffing characteristics of rolling/sliding contacts cooled and lubricated with liquid oxygen. Experiments were carried out under heavy loading with a Hertzian pressure in the range of 2.0 GPa to 3.0 GPa and with a high rolling velocity of up to 48 m/s. For contacts between AISI 440 C stainless-steel elements, the results showed that the scuffing behavior of the system was fairly consistent under a wide range of rolling velocity. Scuffing commenced at a small slide-to-roll ratio of around 0.02, and the scuffing behavior of the contact was not sensitive to surface roughness for the test-sample RMS roughness ranging from 0.02 microns to 0.10 microns. For contacts between 440 C and Si3N4 elements, on the other hand, the scuffing behavior of the system was not very consistent and somewhat unpredictable. The results were sensitive to surface roughness particularly that of the Si3N4 test sample. With well polished test samples, consistent results were obtained; the level of traction was lower than that with a 440 C toroid and scuffing did not take place up to a slide-to-roll ratio of near 0.03. The results strongly suggest that significant hydrodynamic effect can be generated by liquid oxygen under heavy loading and high velocity conditions. The results also suggest that the hydrodynamic action is likely generated by the conventional viscous mechanism as it can be largely destroyed by a narrow circumferential surface scratch running through the central region of the contact.

  20. Dynamics of localized charges in dopamine-modified TiO{sub 2} and their effect on the formation of reactive oxygen species.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dimitrijevic, N.; Rozhkova, E.; Rajh, T.

    Modification of TiO{sub 2} nanoparticles with dopamine enables harvesting of visible light and promotes spatial separation of charges. The formation of reactive oxygen species (OH, {sup 1}O{sub 2}, O{sub 2}{sup -}, HO{sub 2}, H{sub 2}O{sub 2}) upon illumination of TiO{sub 2}/dopamine was studied using complementary spin-trap EPR and radical-induced fluorescence techniques. The localization of holes on dopamine suppresses oxidation of adsorbed water molecules at the surface of nanoparticles, and thus formation of OH radicals. At the same time, dopamine does not affect electronic properties of photogenerated electrons and their reaction with dissolved oxygen to produce superoxide anions. Superoxide anions aremore » proposed to generate singlet oxygen through dismutation reaction, resulting in a low yield of {sup 1}O{sub 2} detected.« less

  1. Ice Pack Heat Sink Subsystem - Phase I. [astronaut liquid cooling garment design and testing

    NASA Technical Reports Server (NTRS)

    Roebelen, G. J., Jr.

    1973-01-01

    This paper describes the design and test at one-g of a functional laboratory model (non-flight) Ice Pack Heat Sink Subsystem to be used eventually for astronaut cooling during manned space missions. In normal use, excess heat in the liquid cooling garment (LCG) coolant is transferred to a reusable/regenerable ice pack heat sink. For emergency operation, or for extension of extravehicular activity mission time after all the ice has melted, water from the ice pack is boiled to vacuum, thereby continuing to remove heat from the LCG coolant. This subsystem incorporates a quick connect/disconnect thermal interface between the ice pack heat sink and the subsystem heat exchanger.

  2. Coolant-side heat-transfer rates for a hydrogen-oxygen rocket and a new technique for data correlation

    NASA Technical Reports Server (NTRS)

    Schacht, R. L.; Quentmeyer, R. J.

    1973-01-01

    An experimental investigation was conducted to determine the coolant-side, heat transfer coefficients for a liquid cooled, hydrogen-oxygen rocket thrust chamber. Heat transfer rates were determined from measurements of local hot gas wall temperature, local coolant temperature, and local coolant pressure. A correlation incorporating an integration technique for the transport properties needed near the pseudocritical temperature of liquid hydrogen gives a satisfactory prediction of hot gas wall temperatures.

  3. Study of iron structure stability in high temperature molten lead-bismuth eutectic with oxygen injection using molecular dynamics simulation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Arkundato, Artoto; Su'ud, Zaki; Sudarko

    2014-09-30

    Corrosion of structural materials in high temperature molten lead-bismuth eutectic is a major problem for design of PbBi cooled reactor. One technique to inhibit corrosion process is to inject oxygen into coolant. In this paper we study and focus on a way of inhibiting the corrosion of iron using molecular dynamics method. For the simulation results we concluded that effective corrosion inhibition of iron may be achieved by injection 0.0532 wt% to 0.1156 wt% oxygen into liquid lead-bismuth. At this oxygen concentration the structure of iron material will be maintained at about 70% in bcc crystal structure during interaction withmore » liquid metal.« less

  4. Analysis of the effects of evaporative cooling on the evaporation of liquid droplets using a combined field approach

    PubMed Central

    Xu, Xuefeng; Ma, Liran

    2015-01-01

    During liquid evaporation, the equations for the vapor concentration in the atmosphere and for the temperature in the liquid are coupled and must be solved in an iterative manner. In the present paper, a combined field approach which unifies the coupled fields into one single hybrid field and thus makes the iteration unnecessary is proposed. By using this approach, the influences of the evaporative cooling on the evaporation of pinned sessile droplets are investigated, and its predictions are found in good agreement with the previous theoretical and experimental results. A dimensionless number Ec which can evaluate the strength of the evaporative cooling is then introduced, and the results show that both the evaporation flux along the droplet surface and the total evaporation rate of the droplet decrease as the evaporative cooling number Ec increases. For drying droplets, there exists a critical value EcCrit below which the evaporative cooling effect can be neglected and above which the significance of the effect increases dramatically. The present work may also have more general applications to coupled field problems in which all the fields have the same governing equation. PMID:25721987

  5. Monitoring system for a liquid-cooled nuclear fission reactor

    DOEpatents

    DeVolpi, Alexander

    1987-01-01

    A monitoring system for detecting changes in the liquid levels in various regions of a water-cooled nuclear power reactor, viz., in the downcomer, in the core, in the inlet and outlet plenums, at the head, and elsewhere; and also for detecting changes in the density of the liquid in these regions. A plurality of gamma radiation detectors are used, arranged vertically along the outside of the reactor vessel, and collimator means for each detector limits the gamma-radiation it receives as emitting from only isolated regions of the vessel. Excess neutrons produced by the fission reaction will be captured by the water coolant, by the steel reactor walls, or by the fuel or control structures in the vessel. Neutron capture by steel generates gamma radiation having an energy level of the order of 5-12 MeV, whereas neutron capture by water provides an energy level of approximately 2.2 MeV, and neutron capture by the fission fuel or its cladding provides an energy level of 1 MeV or less. The intensity of neutron capture thus changes significantly at any water-metal interface. Comparative analysis of adjacent gamma detectors senses changes from the normal condition with liquid coolant present to advise of changes in the presence and/or density of the coolant at these specific regions. The gamma detectors can also sense fission-product gas accumulation at the reactor head to advise of a failure of fuel-pin cladding.

  6. Efficacy of Liquid, Air, and Phase Change Material Torso Cooling During Light Exercise While Wearing NBC Clothing

    DTIC Science & Technology

    1998-03-01

    and Thermal Comfort 6 Blood Sampling 6 Statistical Analyses 6 RESULTS 7 Indices of Hydration Status 7 Liquid-Cooling and PCM Cooling Vests...of Uncooled Sites 12 Vapour Pressure 12 Ratings of Thermal Comfort and Perceived Exertion 18 Indices of Heat Tolerance 18 DISCUSSION 20...ill Figures 8A and B Changes in ratings of thermal comfort of the torso and whole body during light exercise at 40°C and 30% relative humidity while

  7. A study of boiling heat transfer as applied to the cooling of ball bearings in the high pressure oxygen turbopump of the space shuttle main engine

    NASA Technical Reports Server (NTRS)

    Schreiber, Will

    1986-01-01

    Two sets of ball bearings support the main shaft within the High Pressure Oxygen Turbopump (HPOTP) in the Space Shuttle Main Engine (SSME). In operation, these bearings are cooled and lubricated with high pressure liquid oxygen (LOX) flowing axially through the bearing assembly. Currently, modifications in the assembly design are being contemplated in order to enhance the lifetime of the bearings and to allow the HPOTP to operate under larger loads. An understanding of the fluid dynamics and heat transfer characteristics of the flowing LOX is necessary for the implementation of these design changes. The proposed computational model of the LOX fluid dynamics, in addition to dealing with a turbulent flow in a complex geometry, must address the complication associated with boiling and two-phase flow. The feasibility of and possible methods for modeling boiling heat transfer are considered. The theory of boiling as pertains to this particular problem is reviewed. Recommendations are given for experiments which would be necessary to establish validity for correlations needed to model boiling.

  8. Evaluation of a liquid cooling garment as a component of the Launch and Entry Suit (LES)

    NASA Technical Reports Server (NTRS)

    Waligora, J.; Charles, J.; Fritsch, I.; Fortney, S.; Siconolfi, S.; Pepper, L.; Bagian, L.; Kumar, V.

    1994-01-01

    The LES is a partial pressure suit and a component of the shuttle life support system used during launch and reentry. The LES relies on gas ventilation with cabin air to provide cooling. There are conditions during nominal launch and reentry, landing, and post-landing phases when cabin temperature is elevated. Under these conditions, gas cooling may result in some discomfort and some decrement in orthostatic tolerance. There are emergency conditions involving loss of cabin ECS capability that would challenge crew thermal tolerance. The results of a series of tests are presented. These tests were conducted to assess the effectiveness of a liquid-cooled garment in alleviating thermal discomfort, orthostatic intolerance, and thermal intolerance during simulated mission phases.

  9. Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products

    DOEpatents

    Nataraj, Shankar; Russek, Steven Lee; Dyer, Paul Nigel

    2000-01-01

    Natural gas or other methane-containing feed gas is converted to a C.sub.5 -C.sub.19 hydrocarbon liquid in an integrated system comprising an oxygenative synthesis gas generator, a non-oxygenative synthesis gas generator, and a hydrocarbon synthesis process such as the Fischer-Tropsch process. The oxygenative synthesis gas generator is a mixed conducting membrane reactor system and the non-oxygenative synthesis gas generator is preferably a heat exchange reformer wherein heat is provided by hot synthesis gas product from the mixed conducting membrane reactor system. Offgas and water from the Fischer-Tropsch process can be recycled to the synthesis gas generation system individually or in combination.

  10. First signal from a broadband cryogenic preamplifier cooled by circulating liquid nitrogen in a 7 T Fourier transform ion cyclotron resonance mass spectrometer.

    PubMed

    Choi, Myoung Choul; Lee, Jeong Min; Lee, Se Gyu; Choi, Sang Hwan; Choi, Yeon Suk; Lee, Kyung Jae; Kim, SeungYong; Kim, Hyun Sik; Stahl, Stefan

    2012-12-18

    Despite the outstanding performance of Fourier transform ion cyclotron/mass spectrometry (FTICR/MS), the complexity of the cellular proteome or natural compounds presents considerable challenges. Sensitivity is a key performance parameter of a FTICR mass spectrometer. By improving this parameter, the dynamic range of the instrument can be increased to improve the detection signal of low-abundance compounds or fragment ion peaks. In order to improve sensitivity, a cryogenic detection system was developed by the KBSI (Korean Basic Science Institute) in collaboration with Stahl-Electronics (Mettenheim, Germany). A simple, efficient liquid circulation cooling system was designed and a cryogenic preamplifier implemented inside a FTICR mass spectrometer. This cooling system circulates a cryoliquid from a Dewar to the "liquid circulation unit" through a CF flange to cool a copper block and a cryopreamplifier; the cooling medium is subsequently exhausted into the air. The cryopreamplifier can be operated over a very wide temperature range, from room temperature to low temperature environments (4.2 K). First, ion signals detected by the cryopreamplifier using a circulating liquid nitrogen cooling system were observed and showed a signal-to-noise ratio (S/N) about 130% better than that obtained at room temperature.

  11. Insights into thermal diffusion of germanium and oxygen atoms in HfO{sub 2}/GeO{sub 2}/Ge gate stacks and their suppressed reaction with atomically thin AlO{sub x} interlayers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ogawa, Shingo, E-mail: Shingo-Ogawa@trc.toray.co.jp; Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871; Asahara, Ryohei

    2015-12-21

    The thermal diffusion of germanium and oxygen atoms in HfO{sub 2}/GeO{sub 2}/Ge gate stacks was comprehensively evaluated by x-ray photoelectron spectroscopy and secondary ion mass spectrometry combined with an isotopic labeling technique. It was found that {sup 18}O-tracers composing the GeO{sub 2} underlayers diffuse within the HfO{sub 2} overlayers based on Fick's law with the low activation energy of about 0.5 eV. Although out-diffusion of the germanium atoms through HfO{sub 2} also proceeded at the low temperatures of around 200 °C, the diffusing germanium atoms preferentially segregated on the HfO{sub 2} surfaces, and the reaction was further enhanced at high temperatures withmore » the assistance of GeO desorption. A technique to insert atomically thin AlO{sub x} interlayers between the HfO{sub 2} and GeO{sub 2} layers was proven to effectively suppress both of these independent germanium and oxygen intermixing reactions in the gate stacks.« less

  12. A pump driving liquid cooling circuit method for the aperture of an infrared cold optical system

    NASA Astrophysics Data System (ADS)

    Xie, RongJian

    2017-06-01

    To enhance the optical recognition and wavelength filtering of an infrared cold optical system, some lens need to be maintained within a certain temperature range, which requires specific thermal management of the aperture. A 250K liquid cooling circuit designed for this purpose is introduced, and the experimental results established and operated in a vacuum environmental simulation chamber is carried out and analyzed. A practical cooling power source of radiation cooling equipment is adopted and the sun exposure heat load is imitated by array of planar membrane heaters attached on the specific designed structure of the aperture. Controlling the aperture temperature and improving the optical system performance are proved effective. Numerical optimization of the cooling circuit and simulation of the aperture are performed , and the factors affect the optical system performance in the mean time are also investigated.

  13. Development and fabrication of an advanced liquid cooling garment

    NASA Technical Reports Server (NTRS)

    Hixon, C. W.

    1978-01-01

    A tube/fin concept liquid cooling garment head cooler was developed, fabricated and delivered to NASA-ARC. The head cooler was fabricated from polyurethane film which sandwiches the transport fluid tubing and a thermally conductive fin material. The head cooler garment is sewn to form a skull cap and covered with a comfort liner. In addition, two Neonate heating garments were fabricated and supplied to NASA for further finishing and use in medical tests. The resulting garment is flexible, elastic and conforms to the head comfortably. Tests on a tube/fin element of identical construction as the head cooler demonstrated good thermal effectiveness. Use of commercially available materials and development of relatively simple fabrication techniques give the potential for a low garment cost.

  14. Cooling of Gas Turbines. 3; Analysis of Rotor and Blade Temperatures in Liquid-Cooled Gas Turbines

    NASA Technical Reports Server (NTRS)

    Brown, W. Byron; Livingood, John N. B.

    1947-01-01

    A theoretical analysis of the radial temperature distribution through the rotor and constant cross sectional area blades near the coolant passages of liquid cooled gas turbines was made. The analysis was applied to obtain the rotor and blade temperatures of a specific turbine using a gas flow of 55 pounds per second, a coolant flow of 6.42 pounds per second, and an average coolant temperature of 200 degrees F. The effect of using kerosene, water, and ethylene glycol was determined. The effect of varying blade length and coolant passage lengths with water as the coolant was also determined. The effective gas temperature was varied from 2000 degrees to 5000 degrees F in each investigation.

  15. Development and Integration of the Janus Robotic Lander: A Liquid Oxygen-Liquid Methane Propulsion System Testbed

    NASA Astrophysics Data System (ADS)

    Ponce, Raul

    Initiatives have emerged with the goal of sending humans to other places in our solar system. New technologies are being developed that will allow for more efficient space systems to transport future astronauts. One of those technologies is the implementation of propulsion systems that use liquid oxygen and liquid methane (LO2-LCH4) as propellants. The benefits of a LO2-LCH4 propulsion system are plenty. One of the main advantages is the possibility of manufacturing the propellants at the destination body. A space vehicle which relies solely on liquid oxygen and liquid methane for its main propulsion and reaction control engines is necessary to exploit this advantage. At the University of Texas at El Paso (UTEP) MIRO Center for Space Exploration Technology Research (cSETR) such a vehicle is being developed. Janus is a robotic lander vehicle with the capability of vertical take-off and landing (VTOL) which integrates several LO2-LCH 4 systems that are being devised in-house. The vehicle will serve as a testbed for the parallel operation of these propulsion systems while being fed from common propellant tanks. The following work describes the efforts done at the cSETR to develop the first prototype of the vehicle as well as the plan to move forward in the design of the subsequent prototypes that will lead to a flight vehicle. In order to ensure an eventual smooth integration of the different subsystems that will form part of Janus, requirements were defined for each individual subsystem as well as the vehicle as a whole. Preliminary testing procedures and layouts have also been developed and will be discussed to detail in this text. Furthermore, the current endeavors in the design of each subsystem and the way that they interact with one another within the lander will be explained.

  16. Cold Helium Pressurization for Liquid Oxygen/Liquid Methane Propulsion Systems: Fully-Integrated Hot-Fire Test Results

    NASA Technical Reports Server (NTRS)

    Morehead, R. L.; Atwell, M. J.; Melcher, J. C.; Hurlbert, E. A.

    2016-01-01

    Hot-fire test demonstrations were successfully conducted using a cold helium pressurization system fully integrated into a liquid oxygen (LOX) / liquid methane (LCH4) propulsion system (Figure 1). Cold helium pressurant storage at near liquid nitrogen (LN2) temperatures (-275 F and colder) and used as a heated tank pressurant provides a substantial density advantage compared to ambient temperature storage. The increased storage density reduces helium pressurant tank size and mass, creating payload increases of 35% for small lunar-lander sized applications. This degree of mass reduction also enables pressure-fed propulsion systems for human-rated Mars ascent vehicle designs. Hot-fire test results from the highly-instrumented test bed will be used to demonstrate system performance and validate integrated models of the helium and propulsion systems. A pressurization performance metric will also be developed as a means to compare different active pressurization schemes.

  17. High-sensitivity cooled coil system for nuclear magnetic resonance in kHz range

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lin, Tingting; Zhao, Jing, E-mail: zhaojing-8239@jlu.edu.cn; Peter Grünberg Institute

    2014-11-15

    In several low-field Nuclear Magnetic Resonance (LF-NMR) and surface nuclear magnetic resonance applications, i.e., in the frequency range of kHz, high sensitivity magnetic field detectors are needed. Usually, low-T{sub c} superconducting quantum interference devices (SQUIDs) with a high field sensitivity of about 1 fT/Hz{sup 1/2} are employed as detectors. Considering the flux trapping and operational difficulties associated with low-T{sub c} SQUIDs, we designed and fabricated liquid-nitrogen-cooled Cu coils for NMR detection in the kHz range. A cooled coil system consisting of a 9-cm diameter Cu coil and a low noise preamplifier was systematically investigated and reached a sensitivity of 2more » fT/Hz{sup 1/2} at 77 K, which is 3 times better compared to the sensitivity at 300 K. A Q-switch circuit as an essential element for damping the ringing effects of the pickup coil was developed to acquire free induction decay signals of a water sample with minimum loss of signal. Our studies demonstrate that cooled Cu coils, if designed properly, can provide a comparable sensitivity to low-T{sub c} SQUIDs.« less

  18. Cooling Duct Analysis for Transpiration/Film Cooled Liquid Propellant Rocket Engines

    NASA Technical Reports Server (NTRS)

    Micklow, Gerald J.

    1996-01-01

    The development of a low cost space transportation system requires that the propulsion system be reusable, have long life, with good performance and use low cost propellants. Improved performance can be achieved by operating the engine at higher pressure and temperature levels than previous designs. Increasing the chamber pressure and temperature, however, will increase wall heating rates. This necessitates the need for active cooling methods such as film cooling or transpiration cooling. But active cooling can reduce the net thrust of the engine and add considerably to the design complexity. Recently, a metal drawing process has been patented where it is possible to fabricate plates with very small holes with high uniformity with a closely specified porosity. Such a metal plate could be used for an inexpensive transpiration/film cooled liner to meet the demands of advanced reusable rocket engines, if coolant mass flow rates could be controlled to satisfy wall cooling requirements and performance. The present study investigates the possibility of controlling the coolant mass flow rate through the porous material by simple non-active fluid dynamic means. The coolant will be supplied to the porous material by series of constant geometry slots machined on the exterior of the engine.

  19. Magnetic-field-induced synthesis of Fe{sub 3}O{sub 4} nanorods by a gas–liquid interfacial process: Microstructure control, magnetic and photocatalytic properties

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Chun; Mo, Zunli, E-mail: mozlnwnu2011@163.com; Guo, Ruibin

    Highlights: • Fe{sub 3}O{sub 4} nanorods were synthesized via a MFI gas–liquid interfacial route. • The morphology of the Fe{sub 3}O{sub 4} nanoparticle can be changed during its growth process. • MF render Fe{sub 3}O{sub 4} nanorods higher degree of crystallinity and better magnetic property. - Abstract: In this paper, we designed a magnetic field (MF) induced gas–liquid interface route to synthesize magnetic Fe{sub 3}O{sub 4} nanorods (NRs). The results showed that the MF can significantly affect the morphology of the particles. In this original method, only relatively inexpensive and environmental chemicals were used. The structure and morphology of themore » Fe{sub 3}O{sub 4} NRs were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and vibrating sample magnetometry technique. The crystal growth mechanisms in the magnetic field induced process were expounded in detail. The as-synthesized Fe{sub 3}O{sub 4} NRs were successfully used as a catalytic carrier for the photo degradation of phenol.« less

  20. Tests of Five Full-Scale Propellers in the Presence of a Radial and a Liquid-Cooled Engine Nacelle, Including Tests of Two Spinners

    NASA Technical Reports Server (NTRS)

    Biermann, David; Hartman, Edwin P

    1938-01-01

    Wind-tunnel tests are reported of five 3-blade 10-foot propellers operating in front of a radial and a liquid-cooled engine nacelle. The range of blade angles investigated extended from 15 degrees to 45 degrees. Two spinners were tested in conjunction with the liquid-cooled engine nacelle. Comparisons are made between propellers having different blade-shank shapes, blades of different thickness, and different airfoil sections. The results show that propellers operating in front of the liquid-cooled engine nacelle had higher take-off efficiencies than when operating in front of the radial engine nacelle; the peak efficiency was higher only when spinners were employed. One spinner increased the propulsive efficiency of the liquid-cooled unit 6 percent for the highest blade-angle setting investigated and less for lower blade angles. The propeller having airfoil sections extending into the hub was superior to one having round blade shanks. The thick propeller having a Clark y section had a higher take-off efficiency than the thinner one, but its maximum efficiency was possibly lower. Of the three blade sections tested, Clark y, R.A.F. 6, and NACA 2400-34, the Clark y was superior for the high-speed condition, but the R.A.F. 6 excelled for the take-off condition.

  1. Internal-liquid-film-cooling Experiments with Air-stream Temperatures to 2000 Degrees F. in 2- and 4-inch-diameter Horizontal Tubes

    NASA Technical Reports Server (NTRS)

    Kinney, George R; Abramson, Andrew E; Sloop, John L

    1952-01-01

    Report presents the results of an investigation conducted to determine the effectiveness of liquid-cooling films on the inner surfaces of tubes containing flowing hot air. Experiments were made in 2- and 4-inch-diameter straight metal tubes with air flows at temperatures from 600 degrees to 2000 degrees F. and diameter Reynolds numbers from 2.2 to 14 x 10(5). The film coolant, water, was injected around the circumference at a single axial position on the tubes at flow rates from 0.02 to .24 pound per second per foot of tube circumference (0.8 to 12 percent of the air flow). Liquid-coolant films were established and maintained around and along the tube wall in concurrent flow with the hot air. The results indicated that, in order to film cool a given surface area with as little coolant flow as possible, it may be necessary to limit the flow of coolant introduced at a single axial position and to introduce it at several axial positions. The flow rate of inert coolant required to maintain liquid-film cooling over a given area of tube surface can be estimated when the gas-flow conditions are known by means of a generalized plot of the film-cooling data.

  2. Determination of heat transfer coefficient for an interaction of sub-cooled gas and metal

    NASA Astrophysics Data System (ADS)

    Zaidi Sidek, Mohd; Syahidan Kamarudin, Muhammad

    2016-02-01

    Heat transfer coefficient (HTC) for a hot metal surface and their surrounding is one of the need be defined parameter in hot forming process. This study has been conducted to determine the HTC for an interaction between sub-cooled gas sprayed on a hot metal surface. Both experiments and finite element have been adopted in this work. Initially, the designated experiment was conducted to obtain temperature history of spray cooling process. Then, an inverse method was adopted to calculate the HTC value before we validate in a finite element simulation model. The result shows that the heat transfer coefficient for interaction of subcooled gas and hot metal surface is 1000 W/m2K.

  3. Cooling for a rotating anode X-ray tube

    DOEpatents

    Smither, Robert K.

    1998-01-01

    A method and apparatus for cooling a rotating anode X-ray tube. An electromagnetic motor is provided to rotate an X-ray anode with cooling passages in the anode. These cooling passages are coupled to a cooling structure located adjacent the electromagnetic motor. A liquid metal fills the passages of the cooling structure and electrical power is provided to the motor to rotate the anode and generate a rotating magnetic field which moves the liquid metal through the cooling passages and cooling structure.

  4. Effect of temperature on reduction of CaSO{sub 4} oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Song, Q.L.; Xiao, R.; Deng, Z.Y.

    2008-12-15

    Chemical-looping combustion (CLC) is a promising combustion technology for gaseous and solid fuel with efficient use of energy and inherent separation of CO{sub 2}. The concept of a coal-fueled CLC system using, calcium sulfate (CaSO{sub 4}) as oxygen carrier is proposed in this study. Reduction tests of CaSO{sub 4} oxygen carrier with simulated coal gas were performed in a laboratory-scale fluidized bed reactor in the temperature range of 890-950{degree}C. A high concentration of CO{sub 2} was obtained at the initial reduction period. CaSO{sub 4} oxygen carrier exhibited high reactivity initially and decreased gradually at the late period of reduction. Themore » sulfur release during the reduction of CaSO{sub 4} as oxygen carrier was also observed and analyzed. H{sub 2} and CO{sub 2} conversions were greatly influenced by reduction temperature. The oxygen carrier conversion and mass-based reaction rates during the reduction at typical temperatures were compared. Higher temperatures would enhance reaction rates and result in high conversion of oxygen carrier. An XRD patterns study indicated that CaS was the dominant product of reduction and the variation of relative intensity with temperature is in agreement with the solid conversion. ESEM analysis indicated that the surface structure of oxygen carrier particles changed significantly from impervious to porous after reduction. EDS analysis also demonstrated the transfer of oxygen from the oxygen carrier to the fuel gas and a certain amount of sulfur loss and CaO formation on the surface at higher temperatures. The reduction kinetics of CaSO{sub 4} oxygen carrier was explored with the shrinking unreacted-core model. The apparent kinetic parameters were obtained, and the kinetic equation well predicted the experimental data. Finally, some basic considerations on the use of CaSO{sub 4} oxygen carrier in a CLC system for solid fuels were discussed.« less

  5. Evaluation of fatty acid oxidation by reactive oxygen species induced in liquids using atmospheric-pressure nonthermal plasma jets

    NASA Astrophysics Data System (ADS)

    Tani, Atsushi; Fukui, Satoshi; Ikawa, Satoshi; Kitano, Katsuhisa

    2015-10-01

    We investigated fatty acid oxidation by atmospheric-pressure nonthermal helium plasma using linoleic acid, an unsaturated fatty acid, together with evaluating active species induced in liquids. If the ambient gas contains oxygen, direct plasma such as plasma jets coming into contact with the liquid surface supplies various active species, such as singlet oxygen, ozone, and superoxide anion radicals, to the liquid. The direct plasma easily oxidizes linoleic acid, indicating that fatty acid oxidation will occur in the direct plasma. In contrast, afterglow flow, where the plasma is terminated in a glass tube and does not touch the surface of the liquid sample, supplies mainly superoxide anion radicals. The fact that there was no clear observation of linoleic acid oxidation using the afterglow reveals that it may not affect lipids, even in an atmosphere containing oxygen. The afterglow flow can potentially be used for the sterilization of aqueous solutions using the reduced pH method, in medical and dental applications, because it provides bactericidal activity in the aqueous solution despite containing a smaller amount of active species.

  6. Development work for a borax internal core-catcher for a gas-cooled fast reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Donne, M.D.; Dorner, S.; Schumacher, G.

    1978-07-01

    Preliminary thermal calculations show that a corecatcher, which is able to cope with the complete meltdown of the core and blankets of a 1000-MW(electric) gas-cooled fast reactor, appears to be feasible. This core-catcher is based on borax (Na/sub 2/B/sub 4/O/sub 7/) dissolving the oxide fuel and the fission products occurring in oxide form. The borax is contained in steel boxes forming a 2.2-m-thick slab on the base of the reactor cavity inside the prestressed concrete reactor vessel (PCRV), just underneath the reactor core. After a complete meltdown accident, the fission products, in oxide form, are dispersed in the pool formedmore » by the liquid borax. The metallic fission products are contained in the steel lying below the borax pool and in contact with the water-cooled PCRV liner. The volumetric power density of the molten core is conveniently reduced as it is dissolved in the borax, and the resulting heat fluxes at the borders of the pool can be safely carried away through the PCRV liner and its water cooling system.« less

  7. Sapphire substrate-induced effects in VO{sub 2} thin films grown by oxygen plasma-assisted pulsed laser deposition

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Skuza, J. R., E-mail: jrskuza@nsu.edu, E-mail: apradhan@nsu.edu; Scott, D. W.; Pradhan, A. K., E-mail: jrskuza@nsu.edu, E-mail: apradhan@nsu.edu

    2015-11-21

    We investigate the structural and electronic properties of VO{sub 2} thin films on c-plane sapphire substrates with three different surface morphologies to control the strain at the substrate-film interface. Only non-annealed substrates with no discernible surface features (terraces) provided a suitable template for VO{sub 2} film growth with a semiconductor-metal transition (SMT), which was much lower than the bulk transition temperature. In addition to strain, oxygen vacancy concentration also affects the properties of VO{sub 2}, which can be controlled through deposition conditions. Oxygen plasma-assisted pulsed laser deposition allows favorable conditions for VO{sub 2} film growth with SMTs that can bemore » easily tailored for device applications.« less

  8. Theoretical analysis and experimental investigation on performance of the thermal shield of accelerator cryomodules by thermo-siphon cooling of liquid nitrogen

    NASA Astrophysics Data System (ADS)

    Datta, T. S.; Kar, S.; Kumar, M.; Choudhury, A.; Chacko, J.; Antony, J.; Babu, S.; Sahu, S. K.

    2015-12-01

    Five beam line cryomodules with total 27 superconducting Radio Frequency (RF) cavities are installed and commissioned at IUAC to enhance the energy of heavy ion from 15 UD Pelletron. To reduce the heat load at 4.2 K, liquid nitrogen (LN2) cooled intermediate thermal shield is used for all these cryomodules. For three linac cryomodules, concept of forced flow LN2 cooling is used and for superbuncher and rebuncher, thermo-siphon cooling is incorporated. It is noticed that the shield temperature of superbuncher varies from 90 K to 110 K with respect to liquid nitrogen level. The temperature difference can't be explained by using the basic concept of thermo-siphon with the heat load on up flow line. A simple thermo-siphon experimental set up is developed to simulate the thermal shield temperature profile. Mass flow rate of liquid nitrogen is measured with different heat load on up flow line for different liquid levels. It is noticed that small amount of heat load on down flow line have a significant effect on mass flow rate. The present paper will be investigating the data generated from the thermosiphon experimental set up and a theoretical analysis will be presented here to validate the measured temperature profile of the cryomodule shield.

  9. KENNEDY SPACE CENTER, FLA. - Viewed from inside the aft section of the orbiter Discovery, a worker installs the liquid oxygen feedline for the 17-inch disconnect, coming up from below. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

    NASA Image and Video Library

    2003-11-11

    KENNEDY SPACE CENTER, FLA. - Viewed from inside the aft section of the orbiter Discovery, a worker installs the liquid oxygen feedline for the 17-inch disconnect, coming up from below. The 17-inch liquid oxygen and liquid hydrogen disconnects provide the propellant feed interface from the external tank to the orbiter main propulsion system and the three Shuttle main engines.

  10. Fluid-electrolyte shifts and thermoregulation - Rest and work in heat with head cooling

    NASA Technical Reports Server (NTRS)

    Greenleaf, J. E.; Van Beaumont, W.; Brock, P. J.; Montgomery, L. D.; Morse, J. T.; Shvartz, E.; Kravik, S.

    1980-01-01

    The effects of head cooling on thermoregulation and associated plasma fluid and electrolyte shifts during rest and submaximal exercise in the heat are investigated. Thermoregulatory responses and plasma volume were measured in four male subjects fitted with liquid-cooled neoprene headgear during 60 min of rest, 60 min of ergometer exercise at 45% maximal oxygen uptake and 30 min of recovery in the supine position at 40.1 C and 40% relative humidity. It is found that, compared to control responses, head cooling decreased thigh sweating and increased mean skin temperature at rest and attenuated increases in thigh sweating, heart rate, rectal temperature and ventilation during exercise. During recovery, cooling is observed to facilitate decreases in sweat rate, heart rate, rectal temperature and forearm blood flow and enhance the increase in average temperature. Cooling had no effect on plasma protein, osmotic or electrolyte shifts, and decreased plasma volume losses. The findings indicate the effectiveness of moderate head cooling for the improvement of human performance during exercise in heat.

  11. Wet/dry cooling tower and method

    DOEpatents

    Glicksman, Leon R.; Rohsenow, Warren R.

    1981-01-01

    A wet/dry cooling tower wherein a liquid to-be-cooled is flowed along channels of a corrugated open surface or the like, which surface is swept by cooling air. The amount of the surface covered by the liquid is kept small compared to the dry part thereof so that said dry part acts as a fin for the wet part for heat dissipation.

  12. Non-invasive transdermal two-dimensional mapping of cutaneous oxygenation with a rapid-drying liquid bandage

    PubMed Central

    Li, Zongxi; Roussakis, Emmanuel; Koolen, Pieter G. L.; Ibrahim, Ahmed M. S.; Kim, Kuylhee; Rose, Lloyd F.; Wu, Jesse; Nichols, Alexander J.; Baek, Yunjung; Birngruber, Reginald; Apiou-Sbirlea, Gabriela; Matyal, Robina; Huang, Thomas; Chan, Rodney; Lin, Samuel J.; Evans, Conor L.

    2014-01-01

    Oxygen plays an important role in wound healing, as it is essential to biological functions such as cell proliferation, immune responses and collagen synthesis. Poor oxygenation is directly associated with the development of chronic ischemic wounds, which affect more than 6 million people each year in the United States alone at an estimated cost of $25 billion. Knowledge of oxygenation status is also important in the management of burns and skin grafts, as well as in a wide range of skin conditions. Despite the importance of the clinical determination of tissue oxygenation, there is a lack of rapid, user-friendly and quantitative diagnostic tools that allow for non-disruptive, continuous monitoring of oxygen content across large areas of skin and wounds to guide care and therapeutic decisions. In this work, we describe a sensitive, colorimetric, oxygen-sensing paint-on bandage for two-dimensional mapping of tissue oxygenation in skin, burns, and skin grafts. By embedding both an oxygen-sensing porphyrin-dendrimer phosphor and a reference dye in a liquid bandage matrix, we have created a liquid bandage that can be painted onto the skin surface and dries into a thin film that adheres tightly to the skin or wound topology. When captured by a camera-based imaging device, the oxygen-dependent phosphorescence emission of the bandage can be used to quantify and map both the pO2 and oxygen consumption of the underlying tissue. In this proof-of-principle study, we first demonstrate our system on a rat ischemic limb model to show its capabilities in sensing tissue ischemia. It is then tested on both ex vivo and in vivo porcine burn models to monitor the progression of burn injuries. Lastly, the bandage is applied to an in vivo porcine graft model for monitoring the integration of full- and partial-thickness skin grafts. PMID:25426308

  13. A comparison of the interaction of nitric oxide with the heteropolytungstic acids H{sub 3}PW{sub 12}O{sub 40}, H{sub 0.5}Cs{sub 2.5}PW{sub 12}O{sub 40}, HMgPW{sub 12}O{sub 40}, H{sub 8}SiW{sub 11}O{sub 38}, H{sub 4}SiW{sub 12}O{sub 40}, and H{sub 10}CoW{sub 12}O{sub 42}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Herring, A.M.; McCormick, R.L.; Boonrueng, S.R.

    2000-05-18

    The interaction between NO and the heteropolytungstic acids (HPAs) H{sub 3}PW{sub 12}O{sub 40} (HPW), H{sub 0.5}Cs{sub 2.5}PW{sub 12}O{sub 40} (HCsPW), HMgPW{sub 12}O{sub 40} (HMgPW), H{sub 8}SiW{sub 11}O{sub 38} (HSiW{sub 11}), H{sub 4}SiW{sub 12}O{sub 40} (HSiW), and H{sub 10}CoW{sub 12}{sub 42}(HCoW) in the presence of O{sub 2}(g) was investigated. The tools employed were in situ diffuse reflectance infrared spectroscopy, X-ray powder diffraction, and solid-state {sup 1}H NMR. It was determined that protons may either be present in the HPAs secondary structure as anhydrous protons or be bound to one or two water molecules as H{sub 3}O{sup +} or H{sub 5}O{sub 2}{supmore » +}, respectively. A previous investigation found that HPW sorbed NO into its bulk structure as NOH{sup +}, whereas the anhydrous potassium salt of HPW exhibited weak chemisorption of NO on its surface. In the present study, it was found that NO chemisorbed weakly on the surface of the anhydrous HCsPW. For HMgPW and HSiW, IR and NMR evidence suggests that water is present as H{sub 3}O{sup +}, and the formation of surface-bound NOH{sup +} was observed. Inclusion of NO into the secondary structure as NOH{sup +} was observed for HPW, HSiW{sub 11}, and HCoW. Literature data for HPW, as well as IR and NMR results reported here, indicate that these HPAs contain water as H{sub 5}O{sub 2}{sup +}. The presence of H{sub 5}O{sub 2}{sup +} is, therefore, a prerequisite for NO incorporation as NOH{sup +} in the HPA secondary structure. These HPAs exhibited two modes of NO bonding in the secondary structure: a strongly hydrogen-bound hydrated form, NOH{sup +}{center_dot}H{sub 2}O, and a more weakly bound anhydrous form, NOH{sup +}. Evidence suggests that it is the hydrated form that decomposes, yielding N{sub 2} upon rapid heating. Both NO-containing species interact with terminal and corner-sharing oxygen atoms of the Keggin ion. Anions that are held apart by terminal oxygen-hydrogen bonds have a larger

  14. Abatement of SF{sub 6} and CF{sub 4} using an enhanced kerosene microwave plasma burner

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shin, Dong Hun; Hong, Yong Cheol; Cho, Soon Cheon

    2006-11-15

    A kerosene microwave plasma burner was presented as a tool for abatement of SF{sub 6} and CF{sub 4} gases, which cause global warming. The plasma burner operates by injecting kerosene as a liquid hydrocarbon fuel into a microwave plasma torch and by mixing the resultant gaseous hydrogen and carbon compounds with air or oxygen (O{sub 2}) gas. The abatement of SF{sub 6} and CF{sub 4}, by making use of the kerosene plasma burner, was conducted in terms of nitrogen (N{sub 2}) flow rates. The destruction and removal efficiency of the burner were achieved up to 99.9999% for 0.1 liters permore » minute (lpm) SF{sub 6} in 120 lpm N{sub 2} and 99.3% for 0.05 lpm CF{sub 4} in 60 lpm N{sub 2}, revealing that the microwave plasma burner can effectively eliminate perfluorocompounds emitted from the semiconductor industries.« less

  15. Rotational coherent anti-stokes Raman spectroscopy measurements in a rotating cavity with axial throughflow of cooling air: oxygen concentration measurements.

    PubMed

    Black, J D; Long, C A

    1992-07-20

    In a rotating cavity rig, which models cooling air flow in the spaces between disks of a gas turbine compressor, the buildup of oxygen concentration after the cooling gas was changed from nitrogen to air was monitored using rotational coherent anti-Stokes Raman spectroscopy (CARS). From this information an estimate of the fraction of the throughflow entering the rotating cavity was obtained. This demonstrates that rotational CARS can be applied as a nonintrusive concentration-measurement technique in a rotating engineering test rig.

  16. Home Oxygen Therapy

    MedlinePlus

    ... acts like a large thermos. When released, the liquid oxygen immediately converts to a gas and you breathe it in, just like the compressed oxygen in the older steel cylinders. An important advantage of liquid oxygen is you can transfer some of the ...

  17. Effect of Single Layer Centrifugation on reactive oxygen species and sperm mitochondrial membrane potential in cooled stallion semen.

    PubMed

    Morrell, J M; Lagerqvist, A; Humblot, P; Johannisson, A

    2016-04-06

    Additional means are needed for evaluating the quality of stallion spermatozoa in semen doses for AI. Mitochondrial membrane potential (ΔΨm) has been linked to fertility in some species, but is rarely used in the evaluation of cooled stallion semen; metabolic activity may be associated with reactive oxygen species production (ROS). In the present study, ΔΨm and ROS production were measured in doses of cooled stallion semen. The effect of colloid centrifugation on these parameters was also investigated. In this case, colloid centrifugation involves centrifuging a sperm sample through a silane-coated silica colloid formulation to retrieve the most robust spermatozoa. High and low ΔΨm in cooled stallion semen varied between stallions and between ejaculates, but was not affected by single-layer centrifugation (SLC). The SLC-selected spermatozoa produced significantly less hydrogen peroxide than controls (P < 0.001), which could explain the increased longevity and retention of fertilising capacity seen in previous studies. For SLC samples, ΔΨm was positively associated with viable spermatozoa that were not producing reactive oxygen species (r = 0.49; P < 0.001) and negatively associated with ROS production (for superoxide: r = -0.4, P < 0.01; for hydrogen peroxide: r = -0.39, P < 0.05). There was no clear association between ΔΨm and ROS production in control samples.

  18. An effective device for gas-liquid oxygen removal in enclosed microalgae culture.

    PubMed

    Su, Zhenfeng; Kang, Ruijuan; Shi, Shaoyuan; Cong, Wei; Cai, Zhaoling

    2010-01-01

    A high-performance gas-liquid transmission device (HPTD) was described in this paper. To investigate the HPTD mass transfer characteristics, the overall volumetric mass transfer coefficients, K(A)(La,CO(2)) for the absorption of gaseous CO(2) and K(A)(La,O(2)) for the desorption of dissolved O(2) were determined, respectively, by titration and dissolved oxygen electrode. The mass transfer capability of carbon dioxide was compared with that of dissolved oxygen in the device, and the operating conditions were optimized to suit for the large-scale enclosed micro-algae cultivation. Based on the effectiveness evaluation of the HPTD applied in one enclosed flat plate Spirulina culture system, it was confirmed that the HPTD can satisfy the demand of the enclosed system for carbon supplement and excessive oxygen removal.

  19. The effects of oxygen pressure on disordering and magneto-transport properties of Ba{sub 2}FeMoO{sub 6} thin films grown via pulsed laser deposition

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kim, Kyeong-Won; Mhin, Sungwook; Jones, Jacob L.

    2015-07-21

    Epitaxial Ba{sub 2}FeMoO{sub 6} thin films were grown via pulsed laser deposition under low oxygen pressure and their structural, chemical, and magnetic properties were examined, focusing on the effects of oxygen pressure. The chemical disorder, off-stoichiometry in B site cations (Fe and Mo) increased with increasing oxygen pressure and thus magnetic properties were degraded. Interestingly, in contrast, negative magneto-resistance, which is the characteristics of this double perovskite material, was enhanced with increasing oxygen pressure. It is believed that phase segregation of highly disordered thin films is responsible for the increased magneto-resistance of thin films grown at high oxygen pressure. Themore » anomalous Hall effect, which behaves hole-like, was also observed due to spin-polarized itinerant electrons under low magnetic field below 1 T and the ordinary electron-like Hall effect was dominant at higher magnetic fields.« less

  20. Multicycle study on chemical-looping combustion of simulated coal gas with a CaSO{sub 4} oxygen carrier in a fluidized bed reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Qilei Song; Rui Xiao; Zhongyi Deng

    2008-11-15

    The cyclic test of a CaSO{sub 4}-based oxygen carrier (natural anhydrite) in alternating reducing simulated coal gas and oxidizing conditions was performed at 950{degree}C in a fluidized bed reactor at atmospheric pressure. A high concentration of CO{sub 2} was obtained in the reduction. The H{sub 2} and CO conversions and CO{sub 2} yield increased initially and final decreased significantly. The release of SO{sub 2} and H{sub 2}S during the cyclic test was found to be responsible for the decrease of reactivity of a CaSO{sub 4} oxygen carrier. The oxygen carrier conversion after the reduction reaction decreased gradually in the cyclicmore » test. Through the comparison of mass-based reaction rates as a function of mass conversion at typical cycles, it was also evident that the reactivity of a CaSO{sub 4} oxygen carrier increased for the initial cycles but finally decreased after around 15 cycles. X-ray diffraction analysis revealed that the presence and intensity of the reduction sulfur species was in accordance with the results of gas conversion. The content of CaO was higher than expected, suggesting the formation of SO{sub 2} and H{sub 2}S during the cycles. Surface morphology analysis demonstrates that the natural anhydrite particle surface varied from impervious to porous after the cyclic test. It was also observed that the small grains on the surface of the oxygen carrier sintered in the cyclic tests. Energy-dispersive spectrum analysis also demonstrated the decrease of oxygen intensity after reduction, and CaO became the main component after the 20th oxidation. Pore structure analysis suggested that the particles agglomerated or sintered in the cyclic tests. The possible method for sulfur mitigation is proposed. Finally, some basic consideration on the design criteria of a CLC system for solid fuels using a CaSO{sub 4} oxygen carrier is discussed by the references and provides direction for future work. 49 refs., 10 figs., 5 tabs.« less

  1. ORIGIN OF MOLECULAR OXYGEN IN COMET 67P/CHURYUMOV–GERASIMENKO

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mousis, O.; Ronnet, T.; Brugger, B.

    2016-06-01

    Molecular oxygen has been detected in the coma of comet 67P/Churyumov–Gerasimenko with abundances in the 1%–10% range by the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis-Double Focusing Mass Spectrometer instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in low-density environments such as the presolar cloud may induce the production of large amounts of molecular oxygen. We also show that molecular oxygen can be efficiently trapped in clathrates formed in the protosolar nebula (PSN), and that its incorporation as crystalline ice is highly implausible, because this would imply much larger abundances of Armore » and N{sub 2} than those observed in the coma. Assuming that radiolysis has been the only O{sub 2} production mechanism at work, we conclude that the formation of comet 67P/Churyumov–Gerasimenko is possible in a dense and early PSN in the framework of two extreme scenarios: (1) agglomeration from pristine amorphous icy grains/particles formed in ISM and (2) agglomeration from clathrates that formed during the disk’s cooling. The former scenario is found consistent with the strong correlation between O{sub 2} and H{sub 2}O observed in comet 67P/Churyumov-Gerasimenko’s coma while the latter scenario requires that clathrates formed from ISM icy grains that crystallized when entering the PSN.« less

  2. Applying Additive Manufacturing to a New Liquid Oxygen Turbopump Design

    NASA Technical Reports Server (NTRS)

    O’Neal, T. Derek

    2016-01-01

    A liquid oxygen turbopump has been designed at Marshall Space Flight Center as part of the in-house, Advanced Manufacturing Demonstrator Engine (AMDE) project. Additive manufacturing, specifically direct metal laser sintering (DMLS) of Inconel 718, is used for 77% of the parts by mass. These parts include the impeller, turbine components, and housings. This paper discusses the impacts of the DMLS fabrication technique on the design of the turbopump and lessons learned during DMLS hardware fabrication and material testing.

  3. Simulation Studies on Cooling of Cryogenic Propellant by Gas Bubbling

    NASA Astrophysics Data System (ADS)

    Sandilya, Pavitra; Saha, Pritam; Sengupta, Sonali

    Injection cooling was proposed to store cryogenic liquids (Larsen et al. [1], Schmidt [2]). When a non-condensable gas is injected through a liquid, the liquid component would evaporate into the bubble if its partial pressure in the bubble is lower than its vapour pressure. This would tend to cool the liquid. Earlier works on injection cooling was analysed by Larsen et al. [1], Schmidt [2], Cho et al. [3] and Jung et al. [4], considering instantaneous mass transfer and finite heat transfer between gas bubble and liquid. It is felt that bubble dynamics (break up, coalescence, deformation, trajectory etc.) should also play a significant role in liquid cooling. The reported work are based on simple assumptions like single bubble, zero bubble deformation, and no inter-bubble interactions. Hence in this work, we propose a lumped parameter model considering both heat and mass interactions between bubble and the liquid to gain a preliminary insight into the cooling phenomenon during gas injection through a liquid.

  4. A Robust Cooling Platform for NIS Junction Refrigeration and sub-Kelvin Cryogenic Systems

    NASA Astrophysics Data System (ADS)

    Wilson, B.; Atlas, M.; Lowell, P.; Moyerman, S.; Stebor, N.; Ullom, J.; Keating, B.

    2014-08-01

    Recent advances in Normal metal-insulator-superconductor (NIS) tunnel junctions (Clark et al. Appl Phys Lett 86: 173508, 2005, Appl Phys Lett 84: 4, 2004) have proven these devices to be a viable technology for sub-Kelvin refrigeration. NIS junction coolers, coupled to a separate cold stage, provide a flexible platform for cooling a wide range of user-supplied payloads. Recently, a stage was cooled from 290 to 256 mK (Lowell et al. Appl Phys Lett 102: 082601 2013), but further mechanical and electrical improvements are necessary for the stage to reach its full potential. We have designed and built a new Kevlar suspended cooling platform for NIS junction refrigeration that is both lightweight and well thermally isolated; the calculated parasitic loading is pW from 300 to 100 mK. The platform is structurally rigid with a measured deflection of 25 m under a 2.5 kg load and has an integrated mechanical heat switch driven by a superconducting stepper motor with thermal conductivity G W/K at 300 mK. An integrated radiation shield limits thermal loading and a modular platform accommodates enough junctions to provide nanowatts of continuous cooling power. The compact stage size of 7.6 cm 8.6 cm 4.8 cm and overall radiation shield size of 8.9 cm 10.0 cm 7.0 cm along with minimal electrical power requirements allow easy integration into a range of cryostats. We present the design, construction, and performance of this cooling platform as well as projections for coupling to arrays of NIS junctions and other future applications.

  5. Renewable Bio-Solar Hydrogen Production From Robust Oxygenic Phototrophs: The Second Generation

    DTIC Science & Technology

    2014-07-14

    FeFe]-hydrogenases exposed to controlled amounts of oxygen. The results of UV/Vis, EPR, and IR spectroscopic characterization indicate the... paper : SD MCP. Isolated the strain: SB BB. References 1. Vignais PM, Billoud B (2007) Occurrence, classification, and biological function of...Scientific) equipped with a Globar IR source, a CaF2 beam splitter, and a liquid- nitrogen-cooled mercury cadmium telluride (MCT) detector.27 All of

  6. Effects of Extrinsic and Intrinsic Proton Activity on The Mechanism of Oxygen Reduction in Ionic Liquids

    NASA Astrophysics Data System (ADS)

    Zeller, Robert August

    Mechanisms for oxygen reduction are proposed for three distinct cases covering two ionic liquids of fundamentally different archetypes and almost thirty orders of magnitude of proton activity. Proton activity is treated both extrinsically by varying the concentration and intrinsically by selecting proton donors with a wide range of aqueous pKa values. The mechanism of oxygen reduction in ionic liquids is introduced by way of the protic ionic liquid (pIL) triethylammonium triflate (TEATf) which shares some similarities with aqueous acid solutions. Oxygen reduction in TEATf begins as the one electron rate limited step to form superoxide, O2 *-, which is then rapidly protonated by the pIL cation forming the perhydroxyl radical, HO2*. The perhydroxyl radical is further reduced to peroxidate (HO2-) and hydrogen peroxide in proportions in accordance with their pKa. The reaction does not proceed beyond this point due to the adsorption of the conjugate base triethylammine interfering with the disproportionation of hydrogen peroxide. This work demonstrates that this mechanism is consistent across Pt, Au, Pd, and Ag electrodes. Two related sets of experiments were performed in the inherently aprotic ionic liquid 1-butyl-2,3-dimethylimidazolium triflate (C4dMImTf). The first involved the titration of acidic species of varying aqueous pKa into the IL while monitoring the extent of oxygen reduction as a function of pKa and potential on Pt and glassy carbon (GC) electrodes. These experiments confirmed the greater propensity of Pt to reduce oxygen by its immediate and abrupt transition from one electron reduction to four electron reduction, while oxygen reduction on GC gradually approaches four electron reduction as the potentials were driven more cathodic. The potential at which oxygen reduction initiates shows general agreement with the Nernst equation and the acid's tabulated aqueous pKa value, however at the extremely acidic end, a small deviation is observed. The second set

  7. Magneto-acoustic study near the quantum critical point of the frustrated quantum antiferromagnet Cs{sub 2}CuCl{sub 4}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cong, P. T., E-mail: t.pham@hzdr.de; Physics Institute, Goethe University Frankfurt, D-60438 Frankfurt am Main; Postulka, L.

    2016-10-14

    Magneto-acoustic investigations of the frustrated triangular-lattice antiferromagnet Cs{sub 2}CuCl{sub 4} were performed for the longitudinal modes c{sub 11} and c{sub 33} in magnetic fields along the a-axis. The temperature dependence of the sound velocity at zero field shows a mild softening at low temperature and displays a small kink-like anomaly at T{sub N}. Isothermal measurements at T < T{sub N} of the sound attenuation α reveal two closely spaced features of different characters on approaching the material's quantum-critical point (QCP) at B{sub s} ≈ 8.5 T for B || a. The peak at slightly lower fields remains sharp down to the lowest temperaturemore » and can be attributed to the ordering temperature T{sub N}(B). The second anomaly, which is rounded and which becomes reduced in size upon cooling, is assigned to the material's spin-liquid properties preceding the long-range antiferromagnetic ordering with decreasing temperature. These two features merge upon cooling suggesting a coincidence at the QCP. The elastic constant at lowest temperatures of our experiment at 32 mK can be well described by a Landau free energy model with a very small magnetoelastic coupling constant G/k{sub B} ≈ 2.8 K. The applicability of this classical model indicates the existence of a small gap in the magnetic excitation spectrum which drives the system away from quantum criticality.« less

  8. Liquid hydrogen and liquid oxygen feedline passive recirculation analysis

    NASA Astrophysics Data System (ADS)

    Holt, Kimberly Ann; Cleary, Nicole L.; Nichols, Andrew J.; Perry, Gretchen L. E.

    The primary goal of the National Launch System (NLS) program was to design an operationally efficient, highly reliable vehicle with minimal recurring launch costs. To achieve this goal, trade studies of key main propulsion subsystems were performed to specify vehicle design requirements. These requirements include the use of passive recirculation to thermally condition the liquid hydrogen (LH2) and liquid oxygen (LO2) propellant feed systems and Space Transportation Main Engine (STME) fuel pumps. Rockwell International (RI) proposed a joint independent research and development (JIRAD) program with Marshall Space Flight Center (MSFC) to study the LH2 feed system passive recirculation concept. The testing was started in July 1992 and completed in November 1992. Vertical and sloped feedline designs were used. An engine simulator was attached at the bottom of the feedline. This simulator had strip heaters that were set to equal the corresponding heat input from different engines. A computer program is currently being used to analyze the passive recirculation concept in the LH2 vertical feedline tests. Four tests, where the heater setting is the independent variable, were chosen. While the JIRAD with RI was underway, General Dynamics Space Systems (GDSS) proposed a JIRAD with MSFC to explore passive recirculation in the LO2 feed system. Liquid nitrogen (LN2) is being used instead of LO2 for safety and economic concerns. To date, three sets of calibration tests have been completed on the sloped LN2 test article. The environmental heat was calculated from the calibration tests in which the strip heaters were turned off. During the LH2 testing, the environmental heat was assumed to be constant. Therefore, the total heat was equal to the environmental heat flux plus the heater input. However, the first two sets of LN2 calibration tests have shown that the environmental heat flux varies with heater input. A Systems Improved Numerical Differencing Analyzer and Fluid

  9. Ultrafast vibrational dynamics of BH{sub 4}{sup −} ions in liquid and crystalline environments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tyborski, Tobias, E-mail: tyborski@mbi-berlin.de; Costard, Rene; Woerner, Michael

    2014-07-21

    Ultrafast vibrational dynamics of BH{sub 4}{sup −} ions, the key units in boron hydride materials for hydrogen storage, are studied in diluted polar liquid solution and in NaBH{sub 4} crystallites by femtosecond infrared spectroscopy. Two-color pump-probe experiments reveal v = 1 lifetimes of 3 ps for the asymmetric BH{sub 4}{sup −} stretching mode ν{sub 3} and of 3.6 ps for the asymmetric bending mode ν{sub 4} in the solvent isopropylamine. We provide direct evidence for the BH{sub 4}{sup −} stretching relaxation pathway via the asymmetric bending mode ν{sub 4} by probing the latter after femtosecond excitation of ν{sub 3}. Pump-probemore » traces measured in the crystalline phase show signatures of radiative coupling between the densely packed BH{sub 4}{sup −} oscillators, most clearly manifested in an accelerated subpicosecond depopulation of the v = 1 state of the ν{sub 4} mode. The radiative decay is followed by incoherent vibrational relaxation similar to the liquid phase. The excess energy released in the relaxation processes of the BH{sub 4}{sup −} intramolecular modes is transferred into the environment with thermal pump-probe signals being much more pronounced in the dense solid than in the diluted solution.« less

  10. Crystallization of belite–melilite clinker minerals in the presence of liquid phase

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kurokawa, Daisuke, E-mail: daisuke_kurokawa@taiheiyo-cement.co.jp; Department of Materials Science and Engineering, Nagoya Institute of Technology, Nagoya 466-8555; Yoshida, Hideto

    2014-06-01

    Crystallization of belite–melilite clinker minerals was studied from the view point of a high temperature equilibrium. Ca{sub 2}SiO{sub 4}–Ca{sub 2}Al{sub 2}SiO{sub 7} and Ca{sub 2}SiO{sub 4}–Ca{sub 2}AlFeSiO{sub 7} clinkers were synthesized at 1330 °C–1650 °C. The constituent phases were determined by X-ray powder diffractometry and optical microscopy. Chemical compositions of the individual clinker minerals were determined using an electron probe microanalyzer. We established the two types of P{sub 2}O{sub 5}-bearing pseudobinary phase diagrams in the systems Ca{sub 2}SiO{sub 4}–Ca{sub 2}Al{sub 2}SiO{sub 7} at 1505 °C–1650 °C and Ca{sub 2}SiO{sub 4}–Ca{sub 2}(Al,Fe){sub 2}SiO{sub 7} at 1330 °C–1550 °C. In the lattermore » system, the liquid phase appeared at 1390 °C, which is approximately 150 °C lower than the temperature of liquid formation in the former system. The melilite phenocrysts larger than 50 μm were observed not only in the slowly cooled Ca{sub 2}SiO{sub 4}–Ca{sub 2}(Al,Fe){sub 2}SiO{sub 7} clinker but also in commercial belite–melilite clinkers. These crystals would be nucleated and grown from a liquid phase which was formed at relatively low temperatures.« less

  11. Cobalt-Bridged Ionic Liquid Polymer on a Carbon Nanotube for Enhanced Oxygen Evolution Reaction Activity.

    PubMed

    Ding, Yuxiao; Klyushin, Alexander; Huang, Xing; Jones, Travis; Teschner, Detre; Girgsdies, Frank; Rodenas, Tania; Schlögl, Robert; Heumann, Saskia

    2018-03-19

    By taking inspiration from the catalytic properties of single-site catalysts and the enhancement of performance through ionic liquids on metal catalysts, we exploited a scalable way to place single cobalt ions on a carbon-nanotube surface bridged by polymerized ionic liquid. Single dispersed cobalt ions coordinated by ionic liquid are used as heterogeneous catalysts for the oxygen evolution reaction (OER). Performance data reveals high activity and stable operation without chemical instability. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  12. Liquid Methane/Liquid Oxygen Propellant Conditioning Feed System (PCFS) Test Rigs

    NASA Technical Reports Server (NTRS)

    Skaff, A.; Grasl, S.; Nguyen, C.; Hockenberry S.; Schubert, J.; Arrington, L.; Vasek, T.

    2008-01-01

    As part of their Propulsion and Cryogenic Advanced Development (PCAD) program, NASA has embarked upon an effort to develop chemical rocket engines which utilize non-toxic, cryogenic propellants such as liquid oxygen (LO2) and liquid methane (LCH4). This effort includes the development and testing of a 100 lbf Reaction Control Engine (RCE) that will be used to evaluate the performance of a LO2/LCH4 rocket engine over a broad range of propellant temperatures and pressures. This testing will take place at NASA-Glenn Research Center's (GRC) Research Combustion Laboratory (RCL) test facility in Cleveland, OH, and is currently scheduled to begin in late 2008. While the initial tests will be performed at sea level, follow-on testing will be performed at NASA-GRC's Altitude Combustion Stand (ACS) for altitude testing. In support of these tests, Sierra Lobo, Inc. (SLI) has designed, developed, and fabricated two separate portable propellant feed systems under the Propellant Conditioning and Feed System (PCFS) task: one system for LCH4, and one for LO2. These systems will be capable of supplying propellants over a large range of conditions from highly densified to several hundred pounds per square inch (psi) saturated. This paper presents the details of the PCFS design and explores the full capability of these propellant feed systems.

  13. Liquid cooled, linear focus solar cell receiver

    DOEpatents

    Kirpich, A.S.

    1983-12-08

    Separate structures for electrical insulation and thermal conduction are established within a liquid cooled, linear focus solar cell receiver for use with parabolic or Fresnel optical concentrators. The receiver includes a V-shaped aluminum extrusion having a pair of outer faces each formed with a channel receiving a string of solar cells in thermal contact with the extrusion. Each cell string is attached to a continuous glass cover secured within the channel with spring clips to isolate the string from the external environment. Repair or replacement of solar cells is effected simply by detaching the spring clips to remove the cover/cell assembly without interrupting circulation of coolant fluid through the receiver. The lower surface of the channel in thermal contact with the cells of the string is anodized to establish a suitable standoff voltage capability between the cells and the extrusion. Primary electrical insulation is provided by a dielectric tape disposed between the coolant tube and extrusion. Adjacent solar cells are soldered to interconnect members designed to accommodate thermal expansion and mismatches. The coolant tube is clamped into the extrusion channel with a releasably attachable clamping strip to facilitate easy removal of the receiver from the coolant circuit.

  14. Liquid cooled, linear focus solar cell receiver

    DOEpatents

    Kirpich, Aaron S.

    1985-01-01

    Separate structures for electrical insulation and thermal conduction are established within a liquid cooled, linear focus solar cell receiver for use with parabolic or Fresnel optical concentrators. The receiver includes a V-shaped aluminum extrusion having a pair of outer faces each formed with a channel receiving a string of solar cells in thermal contact with the extrusion. Each cell string is attached to a continuous glass cover secured within the channel with spring clips to isolate the string from the external environment. Repair or replacement of solar cells is effected simply by detaching the spring clips to remove the cover/cell assembly without interrupting circulation of coolant fluid through the receiver. The lower surface of the channel in thermal contact with the cells of the string is anodized to establish a suitable standoff voltage capability between the cells and the extrusion. Primary electrical insulation is provided by a dielectric tape disposed between the coolant tube and extrusion. Adjacent solar cells are soldered to interconnect members designed to accommodate thermal expansion and mismatches. The coolant tube is clamped into the extrusion channel with a releasably attachable clamping strip to facilitate easy removal of the receiver from the coolant circuit.

  15. Adsorption of oxygen on low-index surfaces of the TiAl{sub 3} alloy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Latyshev, A. M.; Bakulin, A. V.; Kulkova, S. E., E-mail: kulkova@ms.tsc.ru

    Method of the projector augmented waves in the plane-wave basis within the generalized-gradient approximation for the exchange-correlation functional has been used to study oxygen adsorption on (001), (100), and (110) low-index surfaces of the TiAl{sub 3} alloy. It has been established that the sites that are most energetically preferred for the adsorption of oxygen are hollow (H) positions on the (001) surface and bridge (B) positions on the (110) and (100) surfaces. Structural and electronic factors that define their energy preference have been discussed. Changes in the atomic and electronic structure of subsurface layers that occur as the oxygen concentrationmore » increases to three monolayers have been analyzed. It has been shown that the formation of chemical bonds of oxygen with both components of the alloy leads to the appearance of states that are split-off from the bottoms of their valence bands, which is accompanied by the formation of a forbidden gap at the Fermi level and by a weakening of the Ti–Al metallic bonds in the alloy. On the Al-terminated (001) and (110) surfaces, the oxidation of aluminum dominates over that of titanium. On the whole, the binding energy of oxygen on the low-index surfaces with a mixed termination is higher than that at the aluminum-terminated surface. The calculation of the diffusion of oxygen in the TiAl{sub 3} alloy has shown that the lowest barriers correspond to the diffusion between tetrahedral positions in the (001) plane; the diffusion of oxygen in the [001] direction occurs through octahedral and tetrahedral positions. An increase in the concentration of aluminum in the alloy favors a reduction in the height of the energy barriers as compared to the corresponding barriers in the γ-TiAl alloy.« less

  16. Performance enhancement of sub-nanosecond diode-pumped passively Q-switched Yb:YAG microchip laser with diamond surface cooling.

    PubMed

    Zhuang, W Z; Chen, Yi-Fan; Su, K W; Huang, K F; Chen, Y F

    2012-09-24

    We experimentally confirm that diamond surface cooling can significantly enhance the output performance of a sub-nanosecond diode-end-pumped passively Q-switched Yb:YAG laser. It is found that the pulse energy obtained with diamond cooling is approximately 1.5 times greater than that obtained without diamond cooling, where a Cr(4+):YAG absorber with the initial transmission of 84% is employed. Furthermore, the standard deviation of the pulse amplitude peak-to-peak fluctuation is found to be approximately 3 times lower than that measured without diamond cooling. Under a pump power of 3.9 W, the passively Q-switched Yb:YAG laser can generate a pulse train of 3.3 kHz repetition rate with a pulse energy of 287 μJ and with a pulse width of 650 ps.

  17. Synthesis and photocatalytic performance of g-C{sub 3}N{sub 4} nanosheets via liquid phase stripping

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miao, Jilin; Xu, Guangqing; Key Laboratory of Advanced Functional Materials and Devices of Anhui Province, Hefei University of Technology, Hefei 230009

    Well dispersed g-C{sub 3}N{sub 4} nanosheets were prepared by exfoliating the bulk g-C{sub 3}N{sub 4} in concentrated sulfuric acid. Phase structures, morphologies and elemental compositions were characterized by X-ray diffractometer, scanning electron microscope, transmission electron microscope and X-ray photoelectron spectrometer, respectively. Optical absorption and photoluminescence were also used to explain the optical performances of samples. NaI, BQ and IPA were used as the sacrificial agents for studying the surface reactions in the photocatalytic process. By the precipitation of g-C{sub 3}N{sub 4} nanosheets in ethanol with different ratios between concentrated sulfuric acid and ethyl alcohol, well dispersed g-C{sub 3}N{sub 4} nanosheetsmore » with high specific surface area can be obtained. The optimized g-C{sub 3}N{sub 4} (1:10) nanosheets achieve the highest photocatalytic activities under UV light illumination, which can degrade 10 mg/L RhB about 98% in 60 min, which is 6 times that of bulk g-C{sub 3}N{sub 4} under UV light. - Graphical Abstract: The schematic diagram of photocatalysis and excellent photocatalytic performance of g-C{sub 3}N{sub 4} nanosheets. - Highlights: • Well dispersed g-C{sub 3}N{sub 4} were prepared via Liquid Phase Stripping. • The g-C{sub 3}N{sub 4} is in a sheet like structure after being exfoliated. • The g-C{sub 3}N{sub 4} nanosheets possess high photocatalytic performances.« less

  18. Information technology equipment cooling method

    DOEpatents

    Schultz, Mark D.

    2015-10-20

    According to one embodiment, a system for removing heat from a rack of information technology equipment may include a sidecar indoor air to liquid heat exchanger that cools air utilized by the rack of information technology equipment to cool the rack of information technology equipment. The system may also include a liquid to liquid heat exchanger and an outdoor heat exchanger. The system may further include configurable pathways to connect and control fluid flow through the sidecar heat exchanger, the liquid to liquid heat exchanger, the rack of information technology equipment, and the outdoor heat exchanger based upon ambient temperature and/or ambient humidity to remove heat generated by the rack of information technology equipment.

  19. Visualizing dissolved oxygen transport for liquid ventilation in an in vitro model of the human airways

    NASA Astrophysics Data System (ADS)

    Janke, T.; Bauer, K.

    2017-04-01

    Up until to now, the measurement of dissolved oxygen concentrations during liquid ventilation is limited to the determination of averaged concentrations of the liquid entering or leaving the body. The work presented in this paper aims to extend the possible measurement techniques in the research of liquid ventilation. Therefore optical measurements of the dissolved oxygen concentration, using a luminescent sensor dye, are performed. The preparation of a suitable sensor liquid, based on the metal complex Dichlorotris(1,10)-(phenanthroline)ruthenium(II), is presented. A transparent simplified human lung geometry is used for conducting the experiments. Inspiratory as well as expiratory flow at three different constant flow rates is investigated, covering the flow regimes \\text{Re}=83 -333 and \\text{Pe}=33 300 -133 000. The applied measurement technique is capable to reveal distinctive concentration patterns during inspiration and expiration caused by the laminar flow characteristics. Allowing a sufficiently long flow duration, local concentration inhomogeneities disappear and an exponential rise and decay of the mean values can be observed for inspiration and expiration.

  20. Method for forming single phase, single crystalline 2122 BCSCO superconductor thin films by liquid phase epitaxy

    NASA Technical Reports Server (NTRS)

    Pandey, Raghvendra K. (Inventor); Raina, Kanwal (Inventor); Solayappan, Narayanan (Inventor)

    1994-01-01

    A substantially single phase, single crystalline, highly epitaxial film of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor which has a T.sub.c (zero resistance) of 83 K is provided on a lattice-matched substrate with no intergrowth. This film is produced by a Liquid Phase Epitaxy method which includes the steps of forming a dilute supercooled molten solution of a single phase superconducting mixture of oxides of Bi, Ca, Sr, and Cu having an atomic ratio of about 2:1:2:2 in a nonreactive flux such as KCl, introducing the substrate, e.g., NdGaO.sub.3, into the molten solution at 850.degree. C., cooling the solution from 850.degree. C. to 830.degree. C. to grow the film and rapidly cooling the substrate to room temperature to maintain the desired single phase, single crystalline film structure.

  1. SNS Resonance Control Cooling Systems and Quadrupole Magnet Cooling Systems DIW Chemistry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Magda, Karoly

    This report focuses on control of the water chemistry for the Spallation Neutron Source (SNS) Resonance Control Cooling System (RCCS)/Quadrupole Magnet Cooling System (QMCS) deionized water (DIW) cooling loops. Data collected from spring 2013 through spring 2016 are discussed, and an operations regime is recommended.It was found that the RCCS operates with an average pH of 7.24 for all lines (from 7.0 to 7.5, slightly alkaline), the average low dissolved oxygen is in the area of < 36 ppb, and the main loop average resistivity of is > 14 MΩ-cm. The QMCS was found to be operating in a similarmore » regime, with a slightly alkaline pH of 7.5 , low dissolved oxygen in the area of < 45 ppb, and main loop resistivity of 10 to 15 MΩ-cm. During data reading, operational corrections were done on the polishing loops to improve the water chemistry regime. Therefore some trends changed over time.It is recommended that the cooling loops operate in a regime in which the water has a resistivity that is as high as achievable, a dissolved oxygen concentration that is as low as achievable, and a neutral or slightly alkaline pH.« less

  2. Dependence of the residual surface resistance of superconducting radio frequency cavities on the cooling dynamics around T{sub c}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Romanenko, A., E-mail: aroman@fnal.gov; Grassellino, A., E-mail: annag@fnal.gov; Melnychuk, O.

    We report a strong effect of the cooling dynamics through T{sub c} on the amount of trapped external magnetic flux in superconducting niobium cavities. The effect is similar for fine grain and single crystal niobium and all surface treatments including electropolishing with and without 120 °C baking and nitrogen doping. Direct magnetic field measurements on the cavity walls show that the effect stems from changes in the flux trapping efficiency: slow cooling leads to almost complete flux trapping and higher residual resistance, while fast cooling leads to the much more efficient flux expulsion and lower residual resistance.

  3. Gel phantom study of a cryosurgical probe with a thermosiphon effect and liquid nitrogen-cooled aluminum thermal storage blocks

    PubMed Central

    Isoda, Haruo; Takehara, Yasuo; Fujino, Hitoshi; Sone, Kazuya; Suzuki, Takeshi; Tsuzaki, Yoshinari; Miyazaki, Kouji; Fujie, Michio; Sakahara, Harumi; Maekawa, Yasuaki

    2015-01-01

    ABSTRACT Cryosurgery is a minimally invasive treatment for certain types of cancers. Argon-based cryosurgical devices are available at present, however a large compressed gas cylinder with the pressure of 300 atmospheres is needed. To overcome these drawbacks, we developed a new cryosurgical probe measuring about 50 cm in length with separate lumens inside for liquid and gaseous ethylene to be used as a thermosiphon and liquid nitrogen-cooled aluminum thermal storage blocks. The probe needle was 8 cm in length and 3 mm in outer diameter. To investigate the freezing capabilities of our new cryosurgical system we inserted the needle 5cm into a poly-acrylamide gel phantom warmed to 36.5 ℃. Thermal storage blocks made of aluminum, cooled at –196 ℃ in liquid nitrogen, were attached to the condenser of the probe and replaced with thermal storage blocks every 4 to 5 minutes to compensate for warming. We took digital camera images of the ice ball at the needle and measured the temperature in certain locations of the cryoprobe. Ice ball formation started at one minute after cooling. The sizes (longest diameter × minimum diameter) at 10, 20 and 30 minutes after the start of the procedure were 4.5×2.1, 4.5×3.1 and 4.6×3.7 cm, respectively. During the procedure the minimum temperature of the condenser was –85 ℃ and the needle was –65 ℃. This newly developed compact cryosurgical probe with thermosiphon effect and cooled thermal storage blocks created an ice ball that can be used for cryosurgery within 20 minutes. PMID:26412886

  4. Cold Helium Pressurization for Liquid Oxygen / Liquid Methane Propulsion Systems: Fully-Integrated Initial Hot-Fire Test Results

    NASA Technical Reports Server (NTRS)

    Morehead, R. L.; Atwell, M. J.; Melcher, J. C.; Hurlbert, E. A.

    2016-01-01

    A prototype cold helium active pressurization system was incorporated into an existing liquid oxygen (LOX) / liquid methane (LCH4) prototype planetary lander and hot-fire tested to collect vehicle-level performance data. Results from this hot-fire test series were used to validate integrated models of the vehicle helium and propulsion systems and demonstrate system effectiveness for a throttling lander. Pressurization systems vary greatly in complexity and efficiency between vehicles, so a pressurization performance metric was also developed as a means to compare different active pressurization schemes. This implementation of an active repress system is an initial sizing draft. Refined implementations will be tested in the future, improving the general knowledge base for a cryogenic lander-based cold helium system.

  5. Flash crystallization kinetics of methane (sI) hydrate in a thermoelectrically-cooled microreactor.

    PubMed

    Chen, Weiqi; Pinho, Bruno; Hartman, Ryan L

    2017-09-12

    The crystallization kinetics of methane (sI) hydrate were investigated in a thermoelectrically-cooled microreactor with in situ Raman spectroscopy. Step-wise and precise control of the temperature allowed acquisition of reproducible data within minutes, while the nucleation of methane hydrates can take up to 24 h in traditional batch reactors. The propagation rates of methane hydrate (from 3.1-196.3 μm s -1 ) at the gas-liquid interface were measured for different Reynolds' numbers (0.7-68.9), pressures (30.0-80.9 bar), and sub-cooling temperatures (1.0-4.0 K). The precise measurement of the propagation rates and their subsequent analyses revealed a transition from mixed heat-transfer-crystallization-rate-limited to mixed heat-transfer-mass-transfer-crystallization-rate-limited kinetics. A theoretical model, based on heat transfer, mass transfer, and intrinsic crystallization kinetics, was derived for the first time to understand the non-linear relationship between the propagation rate and sub-cooling temperature. The molecular diffusivity of methane within a stagnant film (ahead of the propagation front) was discovered to follow Stokes-Einstein, while calculated Hatta (0.50-0.68), Lewis (128-207), and beta (0.79-116) numbers also confirmed that the diffusive flux influences crystal growth. Understanding methane hydrate crystal growth is important to the atmospheric, oceanic, and planetary sciences and to energy production, storage, and transportation. Our discoveries could someday advance the science of other multiphase, high-pressure, and sub-cooled crystallizations.

  6. Optoelectrical Cooling of Formaldehyde to Sub-Millikelvin Temperatures

    NASA Astrophysics Data System (ADS)

    Zeppenfeld, Martin

    2016-05-01

    Due to their strong long-range dipole-dipole interactions and large number of internal states, polar molecules cooled to ultracold temperatures enable fascinating applications ranging from ultracold chemistry to investigation of dipolar quantum gases. However, realizing a simple and general technique to cool molecules to ultracold temperatures, akin to laser cooling of atoms, has been a formidable challenge. We present results for opto-electrical Sisyphus cooling applied to formaldehyde (H2 CO). In this generally applicable cooling scheme, molecules repeatedly move up and down electric field gradients of a trapping potential in different rotational states to efficiently extract kinetic energy. A total of about 300,000 molecules are thereby cooled by a factor of 1000 to 400uK, resulting in a record-large ensemble of ultracold molecules. In addition to cooling of the motional degrees of freedom, optical pumping via a vibrational transition allows us to control the internal rotational state. We thereby achieve a purity of over 80% of formaldehyde molecules in a single rotational M-sublevel. Our experiment provides an excellent starting point for precision spectroscopy and investigation of ultracold collisions.

  7. Sub-ambient non-evaporative fluid cooling with the sky

    NASA Astrophysics Data System (ADS)

    Goldstein, Eli A.; Raman, Aaswath P.; Fan, Shanhui

    2017-09-01

    Cooling systems consume 15% of electricity generated globally and account for 10% of global greenhouse gas emissions. With demand for cooling expected to grow tenfold by 2050, improving the efficiency of cooling systems is a critical part of the twenty-first-century energy challenge. Building upon recent demonstrations of daytime radiative sky cooling, here we demonstrate fluid cooling panels that harness radiative sky cooling to cool fluids below the air temperature with zero evaporative losses, and use almost no electricity. Over three days of testing, we show that the panels cool water up to 5 ∘C below the ambient air temperature at water flow rates of 0.2 l min-1 m-2, corresponding to an effective heat rejection flux of up to 70 W m-2. We further show through modelling that, when integrated on the condenser side of the cooling system of a two-storey office building in a hot dry climate (Las Vegas, USA), electricity consumption for cooling during the summer could be reduced by 21% (14.3 MWh).

  8. Methods for separating oxygen from oxygen-containing gases

    DOEpatents

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  9. Active two-phase cooling of an IR window for a hypersonic interceptor

    NASA Astrophysics Data System (ADS)

    Burzlaff, B. H.; Chivian, Jay S.; Cotten, W. D.; Hemphill, R. B.; Huhlein, Michael A.

    1993-06-01

    A novel actively cooled window for an IR sensor on a hypersonic interceptor is envisioned which achieves an IR window with high transmittance, low emittance, and low image distortion under high aerodynamic heat flux. The cooling concept employs two-phase convective boiling of liquid ammonia. Coolant is confined to narrow, parallel channels within the window to minimize obscuration of the aperture. The high latent heat of vaporization of ammonia minimizes coolant mass-flow requirements. Low boiling temperatures at projected operating pressures promote high thermal conductivity and low emissivity in the window. The concept was tested with thermal measurements on sub-mm width coolant channels in Si. High values for heat transfer coefficient and critical heat flux were obtained. Thermal gradients within the window can be controlled by the coolant channel configuration. Design options are investigated by predicting the effect of aerodynamic heat flux on the image produced by an IR sensor with a cooled window. Ammonia-cooled IR windows will function in the anticipated aerothermal environment.

  10. Overcoming the Gas-Liquid Mass Transfer of Oxygen by Coupling Photosynthetic Water Oxidation with Biocatalytic Oxyfunctionalization.

    PubMed

    Hoschek, Anna; Bühler, Bruno; Schmid, Andreas

    2017-11-20

    Gas-liquid mass transfer of gaseous reactants is a major limitation for high space-time yields, especially for O 2 -dependent (bio)catalytic reactions in aqueous solutions. Herein, oxygenic photosynthesis was used for homogeneous O 2 supply via in situ generation in the liquid phase to overcome this limitation. The phototrophic cyanobacterium Synechocystis sp. PCC6803 was engineered to synthesize the alkane monooxygenase AlkBGT from Pseudomonas putida GPo1. With light, but without external addition of O 2 , the chemo- and regioselective hydroxylation of nonanoic acid methyl ester to ω-hydroxynonanoic acid methyl ester was driven by O 2 generated through photosynthetic water oxidation. Photosynthesis also delivered the necessary reduction equivalents to regenerate the Fe 2+ center in AlkB for oxygen transfer to the terminal methyl group. The in situ coupling of oxygenic photosynthesis to O 2 -transferring enzymes now enables the design of fast hydrocarbon oxyfunctionalization reactions. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Thermochemical cyclic system for decomposing H/sub 2/O and/or CO/sub 2/ by means of cerium-titanium-sodium-oxygen compounds

    DOEpatents

    Bamberger, C.E.

    1980-04-24

    A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO/sub 2/), titanium dioxide (TiO/sub 2/) and sodium titanate (Na/sub 2/TiO/sub 3/) to form sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) and oxygen. Sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) reacted with sodium carbonate (Na/sub 2/CO/sub 3/) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.

  12. Thermochemical cyclic system for decomposing H.sub.2 O and/or CO.sub.2 by means of cerium-titanium-sodium-oxygen compounds

    DOEpatents

    Bamberger, Carlos E.

    1982-01-01

    A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO.sub.2), titanium dioxide (TiO.sub.2) and sodium titanate (Na.sub.2 TiO.sub.3) to form sodium cerous titanate (NaCeTi.sub.2 O.sub.6) and oxygen. Sodium cerous titanate (NaCeTi.sub.2 O.sub.6) reacted with sodium carbonate (Na.sub.2 CO.sub.3) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.

  13. Compression Stripping of Flue Gas with Energy Recovery

    DOEpatents

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO<sub>X> and NO<sub>X> and CO<sub>2sub> and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO<sub>2sub>, SO<sub>2sub>, and H<sub>2sub>O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  14. Cobalt porphyrin-mediated oxygen transport in a polymer membrane. Effect of the cobalt porphyrin structure on the oxygen-binding reaction, oxygen-diffusion constants, and oxygen-transport efficiency

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nishide, Hiroyuki; Suzuki, Takayuki; Kawakami, Hiroyoshi

    1994-05-12

    New derivatives of (meso-[alpha],[alpha],[alpha],[alpha]-tetrakis(o-pivalamidophenyl)porphinato)cobalt (CoPs) were characterized by oxygen-binding equilibrium and rate constants of the cobalt centered in the porphyrins. They depended on the structure of the porphyrin; for example, the rate constants of oxygen binding and dissociation (k[sub on] and k[sub off]) for [alpha][sup 3][beta]-CoP[sub 4]P were 3 and 20 times as large as those for [alpha][sup 4]-CoB[sub 4]P, respectively. Oxygen transport through the polymer membranes containing CoPs as the fixed oxygen carriers was facilitated and was affected by the oxygen-binding character or the structure of CoPs. The logarithmically linear correlation of the oxygen-dissociation rate constant of CoPs (k[submore » off] = (3-66) x 10[sup 3] S[sup [minus]1]) with the diffusion constant of oxygen via CoPs fixed in the membranes (D[sub cc] = (3-140) x 10[sup [minus]9] cm[sup 2] s[sup [minus]1]) was given for those six CoP derivatives. 26 refs., 5 figs., 2 tabs.« less

  15. Liquid Nitrogen Zero Boiloff Testing

    NASA Technical Reports Server (NTRS)

    Plachta, David; Feller, Jeffrey; Johnson, Wesley; Robinson, Craig

    2017-01-01

    Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASAs future space exploration due to their high specific impulse for rocket motors of upper stages suitable for transporting 10s to 100s of metric tons of payload mass to destinations outside of low earth orbit and for their return. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for missions with durations greater than several months. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler to control tank pressure. The active thermal control technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center, in a vacuum chamber and cryo-shroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. Testing consisted of three passive tests with the active cryo-cooler system off, and 7 active tests, with the cryocooler powered up. The test matrix included zero boil-off tests performed at 90 full and 25 full, and several demonstrations at excess cooling capacity and reduced cooling capacity. From this, the tank pressure response with varied cryocooler power inputs was determined. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

  16. Improvement of critical current density in thallium-based (Tl,Bi)Sr{sub 1.6}Ba{sub 0.4}Ca{sub 2}Cu{sub 3}O{sub x} superconductors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ren, Z.F.; Wang, C.A.; Wang, J.H.

    1994-12-31

    Epitaxial (Tl,Bi)Sr{sub 1.6}Ba{sub 0.4}Ca{sub 2}Cu{sub 3}O{sub x} (Tl,Bi)-1223 thin films on (100) single crystal LaAlO{sub 3} substrates were synthesized by a two-step procedure. Phase development, microstructure, and relationships between film and substrate were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Resistance versus temperature, zero-field-cooled and field-cooled magnetization, and transport critical current density (J{sub c}) were measured. The zero-resistance temperature was 105-111 K. J{sub c} at 77 K and zero field was > 2 x 10{sup 6} A/cm{sup 2}. The films exhibited good flux pinning properties.

  17. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    USGS Publications Warehouse

    Gerlach, T.M.

    1993-01-01

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO2. The CO2-poor gases are typical of Type II volcanic gases (gerlach and Graeber, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO2-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032??C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the fO2 buffering process occurs by transfer of oxygen from the major species in the gas phase (H2O, CO2, SO2) to the lava during cooling and that the transfer of oxygen also controls the fugacities of several minor and trace species (H2, CO, H2S, S2, Cl2, F2), in addition to O2 during cooling. Gas/lava exchanges of other components are apparently insignificant and exert little influence, compared to oxygen exchange, during cooling. Oxygen transfer during cooling is variable, presumably reflecting short-term fluctuations in gas flow rates. Higher flow rates restrict the time available for gas/lava oxygen transfer and result in gases with higher equilibrium temperatures. Lower flow rates favor fO2-constrained equilibration by oxygen transfer down to lower temperatures. Thus, the chemical equilibrium preserved in these gases is a heterogeneous equilibrium constrained by oxygen fugacity, and the equilibrium temperatures implied by the compositions of the gases reflect the temperatures at which gas/lava oxygen exchange ceased. This conclusion

  18. Design of a 500 lbf liquid oxygen and liquid methane rocket engine for suborbital flight

    NASA Astrophysics Data System (ADS)

    Trillo, Jesus Eduardo

    Liquid methane (LCH4)is the most promising rocket fuel for our journey to Mars and other space entities. Compared to liquid hydrogen, the most common cryogenic fuel used today, methane is denser and can be stored at a more manageable temperature; leading to more affordable tanks and a lighter system. The most important advantage is it can be produced from local sources using in-situ resource utilization (ISRU) technology. This will allow the production of the fuel needed to come back to earth on the surface of Mars, or the space entity being explored, making the overall mission more cost effective by enabling larger usable mass. The major disadvantage methane has over hydrogen is it provides a lower specific impulse, or lower rocket performance. The UTEP Center for Space Exploration and Technology Research (cSETR) in partnership with the National Aeronautics and Space Administration (NASA) has been the leading research center for the advancement of Liquid Oxygen (LOX) and Liquid Methane (LCH4) propulsion technologies. Through this partnership, the CROME engine, a throattable 500 lbf LOX/LCH4 rocket engine, was designed and developed. The engine will serve as the main propulsion system for Daedalus, a suborbital demonstration vehicle being developed by the cSETR. The purpose of Daedalus mission and the engine is to fire in space under microgravity conditions to demonstrate its restartability. This thesis details the design process, decisions, and characteristics of the engine to serve as a complete design guide.

  19. Oxygen deficiency induced deterioration in microstructure and magnetic properties at Y{sub 3}Fe{sub 5}O{sub 12}/Pt interface

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Song, Dongsheng; Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn; Ma, Li

    2015-07-27

    Transport efficiency of pure spin current across the ferromagnetic films adjacent with a nonmagnetic metal is strongly dependent on the spin mixing conductance, which is very sensitive to atomic-level interface conditions. Here, by the means of advanced electron microscopy techniques, atomic structure, electronic structure, and magnetic properties at Y{sub 3}Fe{sub 5}O{sub 12} (YIG)/Pt interface are detailed characterized to correlate the microstructure and magnetic properties with interfacial transport properties. It is found that the order-disorder structure transformation at the interface is accompanied with oxygen deficiency, thus the reduced iron valence and the break of magnetic atom-O-magnetic atom bridges, which is responsiblemore » for superexchange interaction and magnetic order. It is also found that the magnetic moment of interfacial iron ions is decreased. The disorder interfacial layer with suppressed magnetism finally contributes to the declined spin transport efficiency. Our results provide the knowledge to control and manipulate the interfacial structure and properties in order to obtain higher spin transport efficiency.« less

  20. The liquid nitrogen and supercritical helium cooling loop for the jet pumped divertor cryopump

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Obert, W.; Mayaux, C.; Perinic, G.

    1994-12-31

    A key element for the new experimental phase of the European fusion experiment JET is a new cryopump which will be installed inside the torus in order to pump the new divertor configuration. A forced flow of liquid nitrogen and supercritical helium has been chosen for the cooling of the cryoshields and cryocondensation panels for this cryopump. The reasons for this selection are to minimize the inventory of cryogens (to minimize nuclear heating) good heat transfer conditions and minimum time for transient conditions such as cool-down, regeneration and warm-up. The flow of supercritical helium will be driven by the mainmore » compressor of the refrigerator and enhanced by a dedicated cold ejector. The peak load during the plasma pulse will be absorbed by the high thermal capacity of the bulk supercritical helium inside the cryocondensation panel.« less

  1. Phase development in the Bi 2Sr 2CaCu 2O y system . Effects of oxygen pressure

    NASA Astrophysics Data System (ADS)

    List, F. A.; Hsu, H.; Cavin, O. B.; Porter, W. D.; Hubbard, C. R.; Kroeger, D. M.

    1992-11-01

    Studies have been undertaken using thermal analysis, in conjunction with high-temperature and room temperature X-ray diffraction, fraction, to elucidate phase relationships during thermal processing of thick films of initially phase pure Bi 2Sr 2CaCu 2O y (2212) on silver substrates in various oxygen-containing atmospheres (0.001 to 100% O 2). Exothermic events on cooling at 10°C/min from a partially liquid state vary with oxygen partial pressure and can be grouped into three sets (I-III). Set I is prominent for 0.001% and 0.1% O 2 in the range of 740-775°C and is believed to be associated with the crystallization of a Cu-free ∼ Bi 5Sr 3Ca 1 oxide phase. Set II results from the crystallization of 2212; it is observed for p(O 2)≥1.0% in the temperature range 800-870°C. Set III appears for 21% and 100% O 2 in the temperature range 880-910°C, and its origin is not clear from the results of this study. Subsequent room temperature X-ray diffraction from these samples suggests that in general high oxygen partial pressures (100% O 2) tend to favor the formation of Bi 2Sr 2CuO 6 (2201), whereas low oxygen partial pressures (0.001-0.1% O 2) lead to the formation of a Cu-free, Bi-Sr-Ca oxide phase. The 2212 phase forms at this cooling rate predominantly for intermediate oxygen partial pressures (7.6-21% O 2). High-temperature X-ray diffraction during cooling (2°C/h) from the partially liquid state shows a pronounced dependence of the order of evolution of crystalline 2212 and 2201 phases on p(O 2). For an oxygen partial pressure of 1.0% the formation of 2212 precedes that of 2201, whereas for 0.01% O 2 2201 crystallizes at a higher temperature than 2212. The implications of these results pertaining to thermal processing of thick 2212 films are discussed.

  2. Design and optimization of the heat rejection system for a liquid cooled thermionic space nuclear reactor power system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moriarty, M.P.

    1993-01-15

    The heat transport subsystem for a liquid metal cooled thermionic space nuclear power system was modelled using algorithms developed in support of previous nuclear power system study programs, which date back to the SNAP-10A flight system. The model was used to define the optimum dimensions of the various components in the heat transport subsystem subjected to the constraints of minimizing mass and achieving a launchable package that did not require radiator deployment. The resulting design provides for the safe and reliable cooling of the nuclear reactor in a proven lightweight design.

  3. Design and optimization of the heat rejection system for a liquid cooled thermionic space nuclear reactor power system

    NASA Astrophysics Data System (ADS)

    Moriarty, Michael P.

    1993-01-01

    The heat transport subsystem for a liquid metal cooled thermionic space nuclear power system was modelled using algorithms developed in support of previous nuclear power system study programs, which date back to the SNAP-10A flight system. The model was used to define the optimum dimensions of the various components in the heat transport subsystem subjected to the constraints of minimizing mass and achieving a launchable package that did not require radiator deployment. The resulting design provides for the safe and reliable cooling of the nuclear reactor in a proven lightweight design.

  4. Vitrification and levitation of a liquid droplet on liquid nitrogen.

    PubMed

    Song, Young S; Adler, Douglas; Xu, Feng; Kayaalp, Emre; Nureddin, Aida; Anchan, Raymond M; Maas, Richard L; Demirci, Utkan

    2010-03-09

    The vitrification of a liquid occurs when ice crystal formation is prevented in the cryogenic environment through ultrarapid cooling. In general, vitrification entails a large temperature difference between the liquid and its surrounding medium. In our droplet vitrification experiments, we observed that such vitrification events are accompanied by a Leidenfrost phenomenon, which impedes the heat transfer to cool the liquid, when the liquid droplet comes into direct contact with liquid nitrogen. This is distinct from the more generally observed Leidenfrost phenomenon that occurs when a liquid droplet is self-vaporized on a hot plate. In the case of rapid cooling, the phase transition from liquid to vitrified solid (i.e., vitrification) and the levitation of droplets on liquid nitrogen (i.e., Leidenfrost phenomenon) take place simultaneously. Here, we investigate these two simultaneous physical events by using a theoretical model containing three dimensionless parameters (i.e., Stefan, Biot, and Fourier numbers). We explain theoretically and observe experimentally a threshold droplet radius during the vitrification of a cryoprotectant droplet in the presence of the Leidenfrost effect.

  5. Vitrification and levitation of a liquid droplet on liquid nitrogen

    PubMed Central

    Song, Young S.; Adler, Douglas; Xu, Feng; Kayaalp, Emre; Nureddin, Aida; Anchan, Raymond M.; Maas, Richard L.; Demirci, Utkan

    2010-01-01

    The vitrification of a liquid occurs when ice crystal formation is prevented in the cryogenic environment through ultrarapid cooling. In general, vitrification entails a large temperature difference between the liquid and its surrounding medium. In our droplet vitrification experiments, we observed that such vitrification events are accompanied by a Leidenfrost phenomenon, which impedes the heat transfer to cool the liquid, when the liquid droplet comes into direct contact with liquid nitrogen. This is distinct from the more generally observed Leidenfrost phenomenon that occurs when a liquid droplet is self-vaporized on a hot plate. In the case of rapid cooling, the phase transition from liquid to vitrified solid (i.e., vitrification) and the levitation of droplets on liquid nitrogen (i.e., Leidenfrost phenomenon) take place simultaneously. Here, we investigate these two simultaneous physical events by using a theoretical model containing three dimensionless parameters (i.e., Stefan, Biot, and Fourier numbers). We explain theoretically and observe experimentally a threshold droplet radius during the vitrification of a cryoprotectant droplet in the presence of the Leidenfrost effect. PMID:20176969

  6. Viscosity and thermal conductivity coefficients of gaseous and liquid oxygen

    NASA Technical Reports Server (NTRS)

    Hanley, H. J. M.; Mccarty, R. D.; Sengers, J. V.

    1974-01-01

    Equations and tables are presented for the viscosity and thermal conductivity coefficients of gaseous and liquid oxygen at temperatures between 80 K and 400 K for pressures up to 200 atm. and at temperatures between 80 K and 2000 K for the dilute gas. A description of the anomalous behavior of the thermal conductivity in the critical region is included. The tabulated coefficients are reliable to within about 15% except for a region in the immediate vicinity of the critical point. Some possibilities for future improvements of this reliability are discussed.

  7. SPICA sub-Kelvin cryogenic chains

    NASA Astrophysics Data System (ADS)

    Duband, L.; Duval, J. M.; Luchier, N.; Prouve, T.

    2012-04-01

    SPICA, a Japanese led mission, is part of the JAXA future science program and is planned for launch in 2018. SPICA will perform imaging and spectroscopic observations in the mid- and far-IR waveband, and is developing instrumentation spanning the 5-400 μm range. The SPICA payload features several candidate instruments, some of them requiring temperature down to 50 mK. This is currently the case for SAFARI, a core instrument developed by a European-based consortium, and BLISS proposed by CALTECH/JPL in the US. SPICA's distinctive feature is to actively cool its telescope to below 6 K. In addition, SPICA is a liquid cryogen free satellite and all the cooling will be provided by radiative cooling (L2 orbit) down to 30 K and by mechanical coolers for lower temperatures. The satellite will launch warm and slowly equilibrate to its operating temperatures once in orbit. This warm launch approach makes it possible to eliminate a large liquid cryogen tank and to use the mass saved to launch a large diameter telescope (3.2 m). This 4 K cooled telescope significantly reduces its own thermal radiation, offering superior sensitivity in the infrared region. The cryogenic system that enables this warm launch/cooled telescope concept is a key issue of the mission. This cryogenic chain features a number of cooling stages comprising passive radiators, Stirling coolers and several Joule Thomson loops, offering cooling powers at typically 20, 4.5, 2.5 and 1.7 K. The SAFARI and BLISS detectors require cooling to temperatures as low as 50 mK. The instrument coolers will be operated from these heat sinks. They are composed of a small demagnetization refrigerator (ADR) pre cooled by either a single or a double sorption cooler, respectively for SAFARI and BLISS. The BLISS cooler maintains continuous cooling at 300 mK and thus suppresses the thermal equilibrium time constant of the large focal plane. These hybrid architectures allow designing low weight coolers able to reach 50 mK. Because

  8. The abnormal electrical and optical properties in Na and Ni codoped BiFeO{sub 3} nanoparticles

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Xu, Xunling; Liu, Weifang, E-mail: wfliu@tju.edu.cn, E-mail: shouyu.wang@yahoo.com; Zhang, Hong

    2015-05-07

    Bi{sub 0.97}Na{sub 0.03}Fe{sub 1−x}Ni{sub x}O{sub 3} (x = 0, 0.005, 0.01, 0.015) nanoparticles are prepared via a sol-gel method. Weak ferromagnetism and exchange bias phenomenon without field cooling are observed in the samples. The oxygen vacancy concentration and leakage current density are increased with increasing the Ni content. However, with the increase of Ni content, the band gap of Bi{sub 0.97}Na{sub 0.03}Fe{sub 1−x}Ni{sub x}O{sub 3} nanoparticles first decreases and then increases. To explain the abnormal phenomenon, the interplay of oxygen vacancy donor and hole acceptor is analyzed and a phenomenological qualitative model based on the electronic energy band is proposed. Additionally, themore » threshold switching behavior appears in Bi{sub 0.97}Na{sub 0.03}Fe{sub 1−x}Ni{sub x}O{sub 3} samples with x = 0.01, 0.015 and the effect is qualitatively explained by introducing a conducting channel model based on the high-density mobile charges.« less

  9. Oxygen isotopes in western Australian coral reveal Pinatubo aerosol-induced cooling in the Western Pacific Warm Pool

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gagan, M.K.; Chivas, A.R.

    1995-05-01

    The authors report a 12 year record study of oxygen 18 isotope signals in a coral (Ningaloo Reef), which is situated so as to give an ideal measure of the sea-surface temperature variation of the local Leeuwin Current. This record consists of nearly weekly readings from 1981 to 1993, and brackets the period following the June 1991 eruption of Mt. Pinatubo. Extended study shows a strong correlation of sea-surface temperature on this coral with changes in the Western Pacific Warm Pool (WPWP), with a lag of 2.5 years. A distinct cooling signal was seen in the inferred sea-surface temperatures frommore » coral measurements, in 1992 and 1993, which suggests the WPWP was cooled roughly 0.5{degrees}C by aerosol induced effects.« less

  10. Solubility of oxygen in liquid Fe at high pressure and consequences for the early differentiation of Earth and Mars

    NASA Astrophysics Data System (ADS)

    Rubie, D. C.; Gessmann, C. K.; Frost, D. J.

    2003-04-01

    Knowledge of the solubility of oxygen in liquid iron enables the partitioning of oxygen between metal and silicates and the oxidation state of residual silicates to be constrained during core formation in planetary bodies. We have determined oxygen solubility experimentally at 5--23 GPa, 2100--2700 K and oxygen fugacities 1--4 log units below the iron-wüstite buffer in samples of liquid Ni-Fe alloy contained in magnesiowüstite capsules using a multianvil apparatus. Results show that oxygen solubility increases with increasing temperature but decreases slightly with increasing pressure over the range of experimental conditions, at constant oxygen fugacity. Using an extrapolation of the results to higher pressures and temperatures, we have modeled the geochemical consequences of metal-silicate separation in magma oceans in order to explain the contrasting FeO contents of the mantles of Earth and Mars. We assume that both Earth and Mars accreted originally from material with a chondritic composition; because the initial oxidation state is uncertain, we vary this parameter by defining the initial oxygen content. Two metal-silicate fractionation models are considered: (1) Metal and silicate are allowed to equilibrate at fictive conditions that approximate the pressure and temperature at the base of a magma ocean. (2) The effect of settling Fe droplets in a magma ocean is determined using a simple polybaric metal-silicate fractionation model. We assume that the temperature at the base of a magma ocean is close to the peridotite liquidus. In the case of Earth, high temperatures in a magma ocean with a depth >1200 km would have resulted in significant quantities of oxygen dissolving in the liquid metal with the consequent extraction of FeO from the residual silicate. In contrast, on Mars, even if the magma ocean extended to the depth of the current core-mantle boundary, temperatures would not have been sufficiently high for oxygen solubility in liquid metal to be

  11. Real-Time, Non-Intrusive Detection of Liquid Nitrogen in Liquid Oxygen at High Pressure and High Flow

    NASA Technical Reports Server (NTRS)

    Singh, Jagdish P.; Yueh, Fang-Yu; Kalluru, Rajamohan R.; Harrison, Louie

    2012-01-01

    An integrated fiber-optic Raman sensor has been designed for real-time, nonintrusive detection of liquid nitrogen in liquid oxygen (LOX) at high pressures and high flow rates in order to monitor the quality of LOX used during rocket engine ground testing. The integrated sensor employs a high-power (3-W) Melles Griot diode-pumped, solid-state (DPSS), frequency-doubled Nd:YAG 532- nm laser; a modified Raman probe that has built-in Raman signal filter optics; two high-resolution spectrometers; and photomultiplier tubes (PMTs) with selected bandpass filters to collect both N2 and O2 Raman signals. The PMT detection units are interfaced with National Instruments Lab- VIEW for fast data acquisition. Studies of sensor performance with different detection systems (i.e., spectrometer and PMT) were carried out. The concentration ratio of N2 and O2 can be inferred by comparing the intensities of the N2 and O2 Raman signals. The final system was fabricated to measure N2 and O2 gas mixtures as well as mixtures of liquid N2 and LOX

  12. 29 CFR 1910.104 - Oxygen.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., section VII—Unfired Pressure Vessels—1968. Insulation surrounding the liquid oxygen container shall be... in § 1910.6. (iv) Insulation. Insulation casings on liquid oxygen containers shall be equipped with... oxygen and heating medium sections with safety relief devices. (iii) Heating. Heat used in an oxygen...

  13. 29 CFR 1910.104 - Oxygen.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., section VII—Unfired Pressure Vessels—1968. Insulation surrounding the liquid oxygen container shall be... in § 1910.6. (iv) Insulation. Insulation casings on liquid oxygen containers shall be equipped with... oxygen and heating medium sections with safety relief devices. (iii) Heating. Heat used in an oxygen...

  14. 29 CFR 1910.104 - Oxygen.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., section VII—Unfired Pressure Vessels—1968. Insulation surrounding the liquid oxygen container shall be... in § 1910.6. (iv) Insulation. Insulation casings on liquid oxygen containers shall be equipped with... oxygen and heating medium sections with safety relief devices. (iii) Heating. Heat used in an oxygen...

  15. 29 CFR 1910.104 - Oxygen.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., Section VII—Unfired Pressure Vessels—1968. Insulation surrounding the liquid oxygen container shall be... in § 1910.6. (iv) Insulation. Insulation casings on liquid oxygen containers shall be equipped with... oxygen and heating medium sections with safety relief devices. (iii) Heating. Heat used in an oxygen...

  16. 29 CFR 1910.104 - Oxygen.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., section VII—Unfired Pressure Vessels—1968. Insulation surrounding the liquid oxygen container shall be... in § 1910.6. (iv) Insulation. Insulation casings on liquid oxygen containers shall be equipped with... oxygen and heating medium sections with safety relief devices. (iii) Heating. Heat used in an oxygen...

  17. Next-Generation Evaporative Cooling Systems for the Advanced Extravehicular Mobility Unit Portable Life Support System

    NASA Technical Reports Server (NTRS)

    Makinen, Janice V.; Anchondo, Ian; Bue, Grant C.; Campbell, Colin; Colunga, Aaron

    2012-01-01

    The development of the Advanced Extravehicular Mobility Unit (AEMU) Portable Life Support System (PLSS) is currently underway at NASA Johnson Space Center. The AEMU PLSS features two new evaporative cooling systems, the Reduced Volume Prototype Spacesuit Water Membrane Evaporator (RVP SWME), and the Auxiliary Cooling Loop (ACL). The RVP SWME is the third generation of hollow fiber SWME hardware, and like its predecessors, RVP SWME provides nominal crewmember and electronics cooling by flowing water through porous hollow fibers. Water vapor escapes through the hollow fiber pores, thereby cooling the liquid water that remains inside of the fibers. This cooled water is then recirculated to remove heat from the crewmember and PLSS electronics. Major design improvements, including a 36% reduction in volume, reduced weight, and more flight like back-pressure valve, facilitate the packaging of RVP SWME in the AEMU PLSS envelope. In addition to the RVP SWME, the Auxiliary Cooling Loop (ACL), was developed for contingency crewmember cooling. The ACL is a completely redundant, independent cooling system that consists of a small evaporative cooler--the Mini Membrane Evaporator (Mini-ME), independent pump, independent feed-water assembly and independent Liquid Cooling Garment (LCG). The Mini-ME utilizes the same hollow fiber technology featured in the RVP SWME, but is only 25% of the size of RVP SWME, providing only the necessary crewmember cooling in a contingency situation. The ACL provides a number of benefits when compared with the current EMU PLSS contingency cooling technology; contingency crewmember cooling can be provided for a longer period of time, more contingency situations can be accounted for, no reliance on a Secondary Oxygen Vessel (SOV) for contingency cooling--thereby allowing a SOV reduction in size and pressure, and the ACL can be recharged-allowing the AEMU PLSS to be reused, even after a contingency event. The development of these evaporative cooling

  18. Development of a prototype automatic controller for liquid cooling garment inlet temperature

    NASA Technical Reports Server (NTRS)

    Weaver, C. S.; Webbon, B. W.; Montgomery, L. D.

    1982-01-01

    The development of a computer control of a liquid cooled garment (LCG) inlet temperature is descirbed. An adaptive model of the LCG is used to predict the heat-removal rates for various inlet temperatures. An experimental system that contains a microcomputer was constructed. The LCG inlet and outlet temperatures and the heat exchanger outlet temperature form the inputs to the computer. The adaptive model prediction method of control is successful during tests where the inlet temperature is automatically chosen by the computer. It is concluded that the program can be implemented in a microprocessor of a size that is practical for a life support back-pack.

  19. Stable N-CuInSe.sub.2 /iodide-iodine photoelectrochemical cell

    DOEpatents

    Cahen, David; Chen, Yih W.

    1985-01-01

    In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe.sub.2 electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br.sub.2 /MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu.sup.+ or Cu.sup.2+ salts and In.sup.3+ salts.

  20. Stable n-CuInSe/sub 2/iodide-iodine photoelectrochemical cell

    DOEpatents

    Cahen, D.; Chen, Y.W.

    1984-09-20

    In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe/sub 2/ electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br/sub 2//MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu/sup +/ or Cu/sup 2 +/ salts and in In/sup 3 +/ salts.

  1. Integrated turbomachine oxygen plant

    DOEpatents

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  2. Liquid Methane/Liquid Oxygen Injectors for Potential Future Mars Ascent Engines

    NASA Technical Reports Server (NTRS)

    Trinh, Huu Phuoc

    1999-01-01

    Preliminary mission studies for human exploration of Mars have been performed at Marshall Space Flight Center (MSFC). These studies indicate that for chemical rockets only a cryogenic propulsion system would provide high enough performance to be considered for a Mars ascent vehicle. Although the mission is possible with Earth-supplied propellants for this vehicle, utilization of in-situ propellants is highly attractive. This option would significantly reduce the overall mass of launch vehicles. Consequently, the cost of the mission would be greatly reduced because the number and size of the Earth launch vehicle(s) needed for the mission would decrease. NASA/Johnson Space Center has initiated several concept studies of in-situ propellant production plants. Liquid oxygen (LOX) is the primary candidate for an in-situ oxidizer. In-situ fuel candidates include methane (CH4), ethylene (C2H4), and methanol (CH3OH). MSFC initiated a technology development program for a cryogenic propulsion system for the Mars human exploration mission in 1998. One part of this technology program is the effort described here: an evaluation of propellant injection concepts for a LOX/liquid methane Mars Ascent Engine (MAE) with an emphasis on light-weight, high efficiency, reliability, and thermal compatibility. In addition to the main objective, hot-fire tests of the subject injectors will be used to test other key technologies including light-weight combustion chamber materials and advanced ignition concepts. This paper will address the results of the liquid methane/LOX injector study conducted at MSFC. A total of four impinging injector configurations were tested under combustion conditions in a modular combustor test article (MCTA), equipped with optically accessible windows. A series of forty hot-fire tests, which covered a wide range of engine operating conditions with the chamber pressure varied from 320 to 510 and the mixture ratio from 1.5 to 3.5, were performed. The test matrix also

  3. Immersion Cooling of Electronics in DoD Installations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Coles, Henry; Herrlin, Magnus

    A considerable amount of energy is consumed to cool electronic equipment in data centers. A method for substantially reducing the energy needed for this cooling was demonstrated. The method involves immersing electronic equipment in a non-conductive liquid that changes phase from a liquid to a gas. The liquid used was 3M Novec 649. Two-phase immersion cooling using this liquid is not viable at this time. The primary obstacles are IT equipment failures and costs. However, the demonstrated technology met the performance objectives for energy efficiency and greenhouse gas reduction. Before commercialization of this technology can occur, a root cause analysismore » of the failures should be completed, and the design changes proven.« less

  4. Studies on Materials for Heavy-Liquid-Metal-Cooled Reactors in Japan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Minoru Takahashi; Masayuki Igashira; Toru Obara

    2002-07-01

    Recent studies on materials for the development of lead-bismuth (Pb-Bi)-cooled fast reactors (FR) and accelerator-driven sub-critical systems (ADS) in Japan are reported. The measurement of the neutron cross section of Bi to produce {sup 210}Po, the removal experiment of Po contamination and steel corrosion test in Pb-Bi flow were performed in Tokyo Institute of Technology. A target material corrosion test was performed in the project of Transmutation Experimental Facility for ADS in Japan Atomic Energy Research Institute (JAERI). Steel corrosion test was started in Mitsui Engineering and Shipbuilding Co., LTD (MES). The feasibility study for FR cycle performed in Japanmore » Nuclear Cycle Institute (JNC) are described. (authors)« less

  5. Liquid metal reactor air cooling baffle

    DOEpatents

    Hunsbedt, Anstein

    1994-01-01

    A baffle is provided between a relatively hot containment vessel and a relatively cold silo for enhancing air cooling performance. The baffle includes a perforate inner wall positionable outside the containment vessel to define an inner flow riser therebetween, and an imperforate outer wall positionable outside the inner wall to define an outer flow riser therebetween. Apertures in the inner wall allow thermal radiation to pass laterally therethrough to the outer wall, with cooling air flowing upwardly through the inner and outer risers for removing heat.

  6. Hypersonic aerospace vehicle leading edge cooling using heat pipe, transpiration and film cooling techniques

    NASA Astrophysics Data System (ADS)

    Modlin, James Michael

    An investigation was conducted to study the feasibility of cooling hypersonic vehicle leading edge structures exposed to severe aerodynamic surface heat fluxes using a combination of liquid metal heat pipes and surface mass transfer cooling techniques. A generalized, transient, finite difference based hypersonic leading edge cooling model was developed that incorporated these effects and was demonstrated on an assumed aerospace plane-type wing leading edge section and a SCRAMJET engine inlet leading edge section. The hypersonic leading edge cooling model was developed using an existing, experimentally verified heat pipe model. Two applications of the hypersonic leading edge cooling model were examined. An assumed aerospace plane-type wing leading edge section exposed to a severe laminar, hypersonic aerodynamic surface heat flux was studied. A second application of the hypersonic leading edge cooling model was conducted on an assumed one-quarter inch nose diameter SCRAMJET engine inlet leading edge section exposed to both a transient laminar, hypersonic aerodynamic surface heat flux and a type 4 shock interference surface heat flux. The investigation led to the conclusion that cooling leading edge structures exposed to severe hypersonic flight environments using a combination of liquid metal heat pipe, surface transpiration, and film cooling methods appeared feasible.

  7. Phase change alloy viscosities down to T{sub g} using Adam-Gibbs-equation fittings to excess entropy data: A fragile-to-strong transition

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wei, Shuai, E-mail: shuai.wei@asu.edu; Department of Materials Science and Engineering, University of Arizona, Tucson, Arizona 85712; Lucas, Pierre

    2015-07-21

    A striking anomaly in the viscosity of Te{sub 85}Ge{sub 15} alloys noted by Greer and coworkers from the work of Neumann et al. is reminiscent of the equally striking comparison of liquid tellurium and water anomalies documented long ago by Kanno et al. In view of the power laws that are used to fit the data on water, we analyze the data on Te{sub 85}Ge{sub 15} using the Speedy-Angell power-law form, and find a good account with a singularity T{sub s} only 25 K below the eutectic temperature. However, the heat capacity data in this case are not diverging, but insteadmore » exhibit a sharp maximum like that observed in fast cooling in the Molinero-Moore model of water. Applying the Adam-Gibbs viscosity equation to these calorimetric data, we find that there must be a fragile-to-strong liquid transition at the heat capacity peak temperature, and then predict the 'strong' liquid course of the viscosity down to T{sub g} at 406 K (403.6 K at 20 K min{sup −1} in this study). Since crystallization can be avoided by moderately fast cooling in this case, we can check the validity of the extrapolation by making a direct measurement of fragility at T{sub g}, using differential scanning calorimetric techniques, and then comparing with the value from the extrapolated viscosity at T{sub g}. The agreement is encouraging, and prompts discussion of relations between water and phase change alloy anomalies.« less

  8. Design and testing of a liquid cooled garment for hot environments.

    PubMed

    Guo, Tinghui; Shang, Bofeng; Duan, Bin; Luo, Xiaobing

    2015-01-01

    Liquid cooled garments (LCGs) are considered a viable method to protect individuals from hyperthermia and heat-related illness when working in thermally stressful environments. While the concept of LCGs was proposed over 50 years ago, the design and testing of these systems is undeveloped and stands in need of further study. In this study, a detailed heat transfer model of LCG in a hot environment was built to analyze the effects of different factors on the LCG performance, and to identify the main limitations to achieve maximum performance. An LCG prototype was designed and fabricated. Series of tests were done by a modified thermal manikin method to validate the heat transfer model and to evaluate the thermal properties. Both experimental and predicted results show that the heat flux components match the heat balance equation with an error of less than 10% at different flowrate. Thermal resistance analysis also manifests that the thermal resistance between the cooling water and the ambient (R2) is more sensitive to the flowrate than to the one between the skin surface and the cooling water (R1). When the flowrate increased from 225 to 544 mL/min, R2 decreased from 0.5 to 0.3 °C m(2)/W while R1 almost remained constant. A specific duration time was proposed to assess the durability and an optimized value of 1.68 h/kg was found according to the heat transfer model. The present heat transfer model and specific duration time concept could be used to optimize and evaluate this kind of LCG respectively. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Mixing and transient interface condensation of a liquid hydrogen tank

    NASA Technical Reports Server (NTRS)

    Lin, C. S.; Hasan, M. M.; Nyland, T. W.

    1993-01-01

    Experiments were conducted to investigate the effect of axial jet-induced mixing on the pressure reduction of a thermally stratified liquid hydrogen tank. The tank was nearly cylindrical, having a volume of about 0.144 cu m with 0.559 m in diameter and 0.711 m long. A mixer/pump unit, which had a jet nozzle outlet of 0.0221 m in diameter was located 0.178 m from the tank bottom and was installed inside the tank to generate the axial jet mixing and tank fluid circulation. The liquid fill and jet flow rate ranged from 42 to 85 percent (by volume) and 0.409 to 2.43 cu m/hr, respectively. Mixing tests began with the tank pressure ranging from 187.5 to 238.5 kPa at which the thermal stratification results in 4.9 to 6.2 K liquid sub cooling. The mixing time and transient vapor condensation rate at the liquid-vapor interface are determined. Two mixing time correlations, based on the thermal equilibrium and pressure equilibrium, are developed. Both mixing time correlations are expressed as functions of system and buoyancy parameters and compared well with other experimental data. The steady state condensation rate correlation of Sonin et al. based on steam-water data is modified and expressed as a function of jet subcooling. The limited liquid hydrogen data of the present study shows that the modified steady state condensation rate correlation may be used to predict the transient condensation rate in a mixing process if the instantaneous values of jet sub cooling and turbulence intensity at the interface are employed.

  10. ASRDI oxygen technology survey. Volume 5: Density and liquid level measurement instrumentation for the cryogenic fluids oxygen, hydrogen, and nitrogen

    NASA Technical Reports Server (NTRS)

    Roder, H. M.

    1974-01-01

    Information is presented on instrumentation for density measurement, liquid level measurement, quantity gauging, and phase measurement. Coverage of existing information directly concerned with oxygen was given primary emphasis. A description of the physical principle of measurement for each instrumentation type is included. The basic materials of construction are listed if available from the source document for each instrument discussed. Cleaning requirements, procedures, and verification techniques are included.

  11. Cooling-capacity characteristics of Helium-4 JT cryocoolers

    NASA Astrophysics Data System (ADS)

    Wang, Y. L.; Liu, D. L.; Gan, Z. H.; Guo, Y. X.; Shen, Y. W.; Chen, S. F.

    2017-12-01

    Cooling capacity of a Helium-4 JT cryocooler may be achieved at a temperature higher than liquid helium temperature. The latent cooling capacity, which should be obtained at liquid helium temperature, is defined as a special part of cooling capacity. With the thermodynamic analysis on steady working conditions of a Helium-4 JT cryocooler, its cooling capacity and temperature characteristics are presented systematically. The effects of precooling temperature and high pressure on the cooling capacity and latent cooling capacity are illustrated. Furthermore, the JT cryocoolers using hydrogen and neon as the working fluids are also discussed. It is shown that helium JT cryocooler has a special cooling capacity characteristic which does not exist in JT cryocoolers using other pure working fluids.

  12. Structure determination of {alpha}-La{sub 6}W{sub 2}O{sub 15}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chambrier, M-H., E-mail: marie-helene.chambier.etu@univ-lemans.f; Ibberson, R.M.; Goutenoire, F., E-mail: francois.goutenoire@univ-lemans.f

    2010-06-15

    The structure of the high temperature alpha form of La{sub 6}W{sub 2}O{sub 15} has been determined ab-initio from high temperature laboratory X-ray and neutron time-of-flight data. This tungstate crystallizes in the non-centrosymmetric orthorhombic space group (No. 20) C222{sub 1}, with Z=2, a=12.6250(2) A, b=9.1875(1) A, c=5.9688(1) A. The structure comprises [O{sub 2}La{sub 3}] infinite ribbons and is better described by the structural formula [O{sub 2}La{sub 3}]{sub 2}[WO{sub 5.5}]{sub 2}. Using this description we can understand the strong structural similarity of the present compound with compounds of the general composition BiM{sub 2}AO{sub 6} (M=Cu, Mg, Zn, Mn, Cd, Ca, Pb; A=P,more » As, V) described as [O{sub 2}M{sub 2}Bi][AO{sub 4}]. The [WO{sub 5.5}] entity implies oxygen disorder in the material. - Graphical abstract: Projection of the polyhedra around the tungsten atom. Atoms labelled in grey are occupied at 50%. Short oxygen-oxygen distances are marked. The polyhedra represents WO{sub 5.5} that is related to the structural unit W{sub 2}O{sub 11} unit. Alpha-La{sub 6}W{sub 2}O{sub 15} could be described as [O{sub 2}La{sub 3}]{sub 2}[WO{sub 5.5}]{sub 2}.« less

  13. [Ambient air interference in oxygen intake measurements in liquid incubating media with the use of open polarographic cells].

    PubMed

    Miniaev, M V; Voronchikhina, L I

    2007-01-01

    A model of oxygen intake by aerobic bio-objects in liquid incubating media was applied to investigate the influence air-media interface area on accuracy of measuring the oxygen intake and error value. It was shown that intrusion of air oxygen increases the relative error to 24% in open polarographic cells and to 13% in cells with a reduced interface area. Results of modeling passive media oxygenation laid a basis for proposing a method to reduce relative error by 66% for open cells and by 15% for cells with a reduced interface area.

  14. Liquid metal reactor air cooling baffle

    DOEpatents

    Hunsbedt, A.

    1994-08-16

    A baffle is provided between a relatively hot containment vessel and a relatively cold silo for enhancing air cooling performance. The baffle includes a perforate inner wall positionable outside the containment vessel to define an inner flow riser therebetween, and an imperforate outer wall positionable outside the inner wall to define an outer flow riser therebetween. Apertures in the inner wall allow thermal radiation to pass laterally therethrough to the outer wall, with cooling air flowing upwardly through the inner and outer risers for removing heat. 3 figs.

  15. High field solenoids for muon cooling

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Green, M.A.; Eyssa, Y.; Kenny, S.

    1999-09-08

    The proposed cooling system for the muon collider will consist of a 200 meter long line of alternating field straight solenoids interspersed with bent solenoids. The muons are cooled in all directions using a 400 mm long section liquid hydrogen at high field. The muons are accelerated in the forward direction by about 900 mm long, 805 MHz RF cavities in a gradient field that goes from 6 T to -6 T in about 300 mm. The high field section in the channel starts out at an induction of about 2 T in the hydrogen. As the muons proceed downmore » the cooling channel, the induction in the liquid hydrogen section increases to inductions as high as 30 T. The diameter of the liquid hydrogen section starts at 750 mm when the induction is 2 T. As the induction in the cooling section goes up, the diameter of the liquid hydrogen section decreases. When the high field induction is 30 T, the diameter of the liquid hydrogen section is about 80 mm. When the high field solenoid induction is below 8.5 T or 9T, niobium titanium coils are proposed for generating .the magnetic field. Above 8.5 T or 9 T to about 20 T, graded niobium tin and niobium titanium coils would be used at temperatures down to 1.8 K. Above 20 T, a graded bybrid magnet system is proposed, where the high field magnet section (above 20 T) is either a conventional water cooled coil section or a water cooled Bitter type coil. Two types of superconducting coils have been studied. They include; epoxy impregnated intrinsically stable coils, and cable in conduit conductor (CICC) coils with helium in the conduit.« less

  16. Effects of configurational changes on electrical resistivity during glass-liquid transition of two bulk metal-alloy glasses

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aji, D. P. B.; Johari, G. P., E-mail: joharig@mcmaster.ca

    Consequences of increase in structural fluctuations on heating Pd{sub 40}Ni{sub 10}Cu{sub 30}P{sub 20} and Zr{sub 46.75}Ti{sub 8.25}Cu{sub 7.5}Ni{sub 10}Be{sub 27.5} through their glass to liquid transition range were investigated by measuring the electrical resistivity, ρ, an electron scattering property. The temperature coefficient of resistivity (TCR = (1/ρ) dρ/dT) of the liquid and glassy states is negative. The plots of their ρ against T in the T{sub g} (glass to liquid transition) range show a gradual change in the slope similar to the change observed generally for the plots of the density, elastic modulus, and refractive index. As fluctuations in themore » melt structure involve fewer configurations on cooling, ρ increases. In the energy landscape description, the melt's structure explores fewer minima with decrease in T, vibrational frequencies increase, and electron scattering and ρ increase. Plots of (−dρ/dT) against T resemble the plot of the specific heat of other glasses and show a sub-T{sub g} feature and a rapid rise at T near T{sub g}. Analysis shows that the magnitude of negative TCR is dominated by change in the phonon characteristics, and configurational fluctuations make it more negative. The TCR of the liquid and glassy states seems qualitatively consistent with the variation in the structure factor in Ziman's model for pure liquid metals as extended by Nagel to metal alloys and used to explain the negative TCR of a two-component metal glass.« less

  17. Mechanism of singlet oxygen deactivation in an electric discharge oxygen – iodine laser

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Azyazov, V N; Mikheyev, P A; Torbin, A P

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}Δ) + O{sub 3}(ν) → 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}Δ) in an electric-discharge-driven oxygen – iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}Δ) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}Δ) in the discharge region of the generator. (lasers)

  18. Corrosion behavior of steels in liquid lead bismuth with low oxygen concentrations

    NASA Astrophysics Data System (ADS)

    Kurata, Yuji; Futakawa, Masatoshi; Saito, Shigeru

    2008-02-01

    Corrosion tests in pots were conducted to elucidate corrosion behavior of various steels in liquid lead-bismuth for 3000 h under the condition of an oxygen concentration of 5 × 10 -8 wt% at 450 °C and an oxygen concentration of 3 × 10 -9 wt% at 550 °C, respectively. Significant corrosion was not observed at 450 °C for ferritic/martensitic steels, F82H, Mod.9Cr-1Mo steel, 410SS, 430SS except 2.25Cr-1Mo steel. Pb-Bi penetration into steels and dissolution of elements into Pb-Bi were severe at 550 °C even for ferritic/martensitic steels. Typical dissolution attack occurred for pure iron both at 550 °C without surface Fe 3O 4 and at 450 °C with a thin Fe 3O 4 film. Ferritization due to dissolution of Ni and Cr, and Pb-Bi penetration were recognized for austenitic stainless steels, 316SS and 14Cr-16Ni-2Mo steel at both temperatures of 450 °C and 550 °C. The phenomena were mitigated for 18Cr-20Ni-5Si steel. In some cases oxide films could not be a corrosion barrier in liquid lead-bismuth.

  19. Acclimation of respiratory O{sub 2} uptake in green tissues of field-grown native species after long-term exposure to elevated atmospheric CO{sub 2}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Azcon-Bieto, J.; Gonzalez-Meler, M.A.; Doherty, W.

    1994-11-01

    C{sub 3} and C{sub 4} plants were grown in open-top chambers in the field at two CO{sub 2} concentrations, normal ambient (ambient) and normal ambient + 340 {mu}L L{sup {minus}1} (elevated). Dark oxygen uptake was measured in leaves and stems using a liquid-phase Clark-type oxygen electrode. High CO{sub 2} treatment decreased dark oxygen uptake in stems of Scirpus olneyi (C{sub 3}) and leaves of Lindera benzoin (C{sub 3}) expressed on either a dry weight or area basis. Respiration of Spartina patens (C{sub 4}) leaves was unaffected by CO{sub 2} treatment. Leaf dry weight per unit area was unchanged by CO{submore » 2}, but respiration per unit of carbon or per unit of nitrogen was decreased in the C{sub 3} species grown at high CO{sub 2}. The component of respiration in stems of S. olneyi and leaves of L. benzoin primarily affected by long-term exposure to the elevated CO{sub 2} treatment was the activity of the cytochrome pathway. Elevated CO{sub 2} had no effect on activity and capacity of the alternative pathway in S. olneyi. The cytochrome c oxidase activity, assayed in a cell-free extract, was strongly decreased by growth at high CO{sub 2} in stems of S. olneyi but it was unaffected in S. patens leaves. The activity of cytochrome c oxidase and complex III extracted from mature leaves of L. benzoin was also decreased after one growing season of plant exposure to elevated CO{sub 2} concentration. These results show that in some C{sub 3} species respiration will be reduced when plants are grown in elevated atmospheric CO{sub 2}. The possible physiological causes and implications of these effects are discussed. 34 refs., 1 fig., 6 tabs.« less

  20. Phase relations in the system Cu-Ho-O and stability of Cu{sub 2}Ho{sub 2}O{sub 5}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Matthews, T.; Jacob, K.T.

    1994-01-01

    The phase relations in the system Cu-Ho-O have been determined at 1300 K using X-ray diffraction, optical microscopy, and electron microprobe analysis of samples equilibrated in evacuated quartz ampules and in pure oxygen. Only one ternary compound, Cu{sub 2}Ho{sub 2}O{sub 5}, was found to be stable. The Gibbs free energy of formation of this compound has been measured. Since the formation is endothermic, Cu{sub 2}Ho{sub 2}O{sub 5} becomes thermodynamically unstable with respect to CuO and Ho{sub 2}O{sub 3} below 810 K. When the oxygen partial pressure over Cu{sub 2}Ho{sub 2}O{sub 5} is lowered, it decomposes. The decomposition temperature at anmore » oxygen partial pressure of 1.52 X 10{sup 4} Pa was measured using a combined DTA-TGA apparatus. Based on these results, an oxygen potential diagram for the system Cu-Ho-O at 1300 K is presented.« less