Sample records for survey treasury vi

  1. The Mega-MUSCLES HST Treasury Survey

    NASA Astrophysics Data System (ADS)

    Froning, Cynthia S.; France, Kevin; Loyd, R. O. Parke; Youngblood, Allison; Brown, Alexander; Schneider, Christian; Berta-Thompson, Zachory; Kowalski, Adam

    2018-01-01

    JWST will be able to observe the atmospheres of rocky planets transiting nearby M dwarfs. A few such planets are already known (around GJ1132, Proxima Cen, and Trappist-1) and TESS is predicted to find many more, including ~14 habitable zone planets. To interpret observations of these exoplanets' atmospheres, we must understand the high-energy SED of their host stars: X-ray/EUV irradiation can erode a planet's gaseous envelope and FUV/NUV-driven photochemistry shapes an atmosphere's molecular abundances, including potential biomarkers like O2, O3, and CH4. Our MUSCLES Treasury Survey (Cycles 19+22) used Hubble/COS+STIS UV observations with contemporaneous X-ray and ground-based data to construct complete SEDs for 11 low-mass exoplanet hosts. MUSCLES is the most widely used database for early-M and K dwarf (>0.3 M_sun) irradiance spectra and has supported a wide range of atmospheric stability and biomarker modeling work. However, TESS will find most of its habitable planets transiting stars less massive than this, and these will be the planets to characterize with JWST. Here, we introduce the Mega-MUSCLES project, an approved HST Cycle 25 Treasury program. Following on the successful MUSCLES survey, Mega-MUSCLES will expand our target list to focus on: (a) new M dwarf exoplanet hosts with varying properties; (b) reference M dwarfs below 0.3 solar masses that may be used as proxies for M dwarf planet hosts discovered after HST's lifetime; and (c) more rapidly rotating stars of GJ1132's mass to probe XUV evolution over gigayear timescales. We will also gather the first panchromatic SEDs of rocky planet hosts GJ1132 and Trappist-1. Here, we present an overview of the Mega-MUSCLES motivation, targets list, and status of the survey and show how it extends proven methods to a key new sample of stars, upon which critically depends the long-term goal of studying habitable planet atmospheres with JWST and beyond.

  2. A survey with Copernicus of interstellar O VI absorption

    NASA Technical Reports Server (NTRS)

    Jenkins, E. B.; Meloy, D. A.

    1974-01-01

    The presence of broad, shallow absorptions caused by O VI ions were revealed from UV spectra observations recorded by the Copernicus satellite for thirty-two stars. A table lists survey data on the stars observed for which values of the O VI column densities or their upper limits are extracted. Interstellar rather than circumstellar origin is evident from observation of the lack of correspondence between radical velocities of the stars and those of the O VI profiles. The presence of a low-density high-temperature phase of interstellar gas produced by supernova explosions is suggested.

  3. 31 CFR 5.9 - When will Treasury entities transfer a Treasury debt to the Treasury Department's Financial...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... a Treasury debt to the Treasury Department's Financial Management Service for collection? 5.9... Treasury Department's Financial Management Service for collection? (a) Treasury entities will transfer any eligible debt that is more than 180 days delinquent to the Financial Management Service for debt collection...

  4. A (Si VI) (1.92 micrometer) coronal line survey of galactic nuclei

    NASA Astrophysics Data System (ADS)

    Marconi, A.; Moorwood, A. F. M.; Salvati, M.; Oliva, E.

    1994-11-01

    We present the results of a (Si VI) lambda 1.962 emission line survey of active, starburst and IRAS luminous galaxies. The line was only detected in known Seyfert type 1 and 2 nuclei confirming previous suggestions that (Si VI) is related to Seyfert activity. By modeling the formation of (Si VI) and (Fe VIII) lambda 6087 we find further strong evidence that these lines arise in gas photoionized by the active nucleus although collisional ionization e.g. by shock fronts may be important in some galaxies exhibiting (Fe VII) much greater than (Si VI). Our failure to detect (Si VI) in the IRAS ultraluminous galaxies does not exclude the possible presence of obscured Active Galactic Nuclei (AGNs), particularly as some of the known Seyferts were also not detected. Molecular hydrogen lines (a by-product of our spectra) are common in all galaxy types including several IRAS ultraluminous galaxies whose H2 equivalent widths (Wlambda less that 20 A) are 'normal'and much lower than the extreme value (Wlambda approximately = 70 A) found in NGC 6240 and NGC 1275. 'Bare' Seyferts have Wlambda(H2) less than 1 A and a factor greater than or approximately 10 lower than starbursts, and we do not confirm previous claims of H2 line emission in the quasar 3C273. Although the ratio of H2 to (Si VI) emission varies over a wide range it does not appear to provide a useful indicator of activity type or to impose constraints on the He excitation mechanism.

  5. Multi-wavelength Characterization of Exoplanet Host Stars with the MUSCLES Treasury Survey

    NASA Astrophysics Data System (ADS)

    France, Kevin; Youngblood, Allison; Loyd, R. O. Parke; Schneider, Christian

    2017-01-01

    High-energy photons (X-ray to NUV) from exoplanet host stars regulate the atmospheric temperature profiles and photochemistry on orbiting planets, influencing the long-term stability of planetary atmospheres and the production of potential “biomarker” gases. However, relatively few observational and theoretical constraints exist on the high-energy irradiance from typical (i.e., weakly active) M and K dwarf exoplanet host stars. In this talk, I will describe results from a panchromatic survey (Chandra/XMM/Hubble/ground) of M and K dwarf exoplanet hosts. The MUSCLES Treasury Survey (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems) combines UV, X-ray, and optical observations with reconstructed Lyman-alpha and EUV (100-900 Ang) radiation to create 5 Angstrom to 5 micron stellar irradiance spectra that are available as a High-Level Science Product on STScI/MAST. I will discuss how we use multi-wavelength observations to study possible abiotic production of the suggested biomarkers O2 and O3, develop scaling relations to infer the high-energy particle fluxes from these stars based on solar UV flare/particle flux measurements, calibrate visible-wavelength proxies for the high-energy irradiance, and characterize the UV variability and flare frequency of “optically inactive” M dwarfs.

  6. Panchromatic Hubble Andromeda Treasury. IX. A photometric survey of planetary nebulae in M31

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Veyette, Mark J.; Williams, Benjamin F.; Dalcanton, Julianne J.

    We search the Hubble Space Telescope (HST) Advanced Camera for Surveys and Wide Field Camera 3 broadband imaging data from the Panchromatic Hubble Andromeda Treasury (PHAT) survey to identify detections of cataloged planetary nebulae (PNs). Of the 711 PNs currently in the literature within the PHAT footprint, we find 467 detected in the broadband. For these 467, we are able to refine their astrometric accuracy from ∼0.''3 to 0.''05. Using the resolution of the HST, we are able to show that 152 objects currently in the catalogs are definitively not PNs, and we show that 32 objects thought to bemore » extended in ground-based images are actually point-like and therefore good PN candidates. We also find one PN candidate that is marginally resolved. If this is a PN, it is up to 0.7 pc in diameter. With our new photometric data, we develop a method of measuring the level of excitation in individual PNs by comparing broadband and narrowband imaging and describe the effects of excitation on a PN's photometric signature. Using the photometric properties of the known PNs in the PHAT catalogs, we search for more PNs, but do not find any new candidates, suggesting that ground-based emission-line surveys are complete in the PHAT footprint to F475W ≅ 24.« less

  7. Natural history and galsulfase treatment in mucopolysaccharidosis VI (MPS VI, Maroteaux-Lamy syndrome)--10-year follow-up of patients who previously participated in an MPS VI Survey Study.

    PubMed

    Giugliani, Roberto; Lampe, Christina; Guffon, Nathalie; Ketteridge, David; Leão-Teles, Elisa; Wraith, James E; Jones, Simon A; Piscia-Nichols, Cheri; Lin, Ping; Quartel, Adrian; Harmatz, Paul

    2014-08-01

    Mucopolysaccharidosis VI (MPS VI) is a clinically heterogeneous and progressive disorder with multiorgan manifestations caused by deficient N-acetylgalactosamine-4-sulfatase activity. A cross-sectional Survey Study in individuals (n = 121) affected with MPS VI was conducted between 2001 and 2002 to establish demographics, urinary glycosaminoglycan (GAG) levels, and clinical progression of disease. We conducted a Resurvey Study (ClinicalTrials.gov: NCT01387854) to obtain 10-year follow-up data, including medical histories and clinical assessments (n = 59), and survival status over 12 years (n = 117). Patients received a mean (SD) of 6.8 (2.2) years of galsulfase ERT between baseline (Survey Study) and follow-up. ERT patients increased in height by 20.4 cm in the 4-7-year-old baseline age group and by 16.8 cm in the 8-12-year-old baseline age group. ERT patients <13 years-old demonstrated improvement in forced vital capacity (FVC) by 68% and forced expiratory volume in 1 sec (FEV1) by 55%, and those ≥13 years-old increased FVC by 12.8% and maintained FEV1. Patients with >200 µg/mg baseline uGAG levels increased FVC by 48% in the <13-year-old baseline age group and by 15% in the ≥13-year-old baseline age group. ERT patients who completed the 6-min walk test demonstrated a mean (SD) increase of 65.7 (100.6) m. Cardiac outcomes did not significantly improve or worsen. Observed mortality rate among naïve patients was 50% (7/14) and 16.5% (17/103) in the ERT group (unadjusted hazard ratio, 0.24; 95% CI, 0.10-0.59). Long-term galsulfase ERT was associated with improvements in pulmonary function and endurance, stabilized cardiac function and increased survival. © 2014 Wiley Periodicals, Inc.

  8. The FUSE Survey of 0 VI in the Galactic Halo

    NASA Technical Reports Server (NTRS)

    Sonneborn, George; Savage, B. D.; Wakker, B. P.; Sembach, K. R.; Jenkins, E. B.; Moos, H. W.; Shull, J. M.

    2003-01-01

    This paper summarizes the results of the Far-Ultraviolet Spectroscopic Explorer (FUSE) program to study 0 VI in the Milky Way halo. Spectra of 100 extragalactic objects and two distant halo stars are analyzed to obtain measures of O VI absorption along paths through the Milky Way thick disk/halo. Strong O VI absorption over the velocity range from -100 to 100 km/s reveals a widespread but highly irregular distribution of O VI, implying the existence of substantial amounts of hot gas with T approx. 3 x 10(exp 5) K in the Milky Way thick disk/halo. The overall distribution of O VI is not well described by a symmetrical plane-parallel layer of patchy O VI absorption. The simplest departure from such a model that provides a reasonable fit to the observations is a plane-parallel patchy absorbing layer with an average O VI mid-plane density of n(sub 0)(O VI) = 1.7 x 10(exp -2)/cu cm, a scale height of approx. 2.3 kpc, and a approx. 0.25 dex excess of O VI in the northern Galactic polar region. The distribution of O VI over the sky is poorly correlated with other tracers of gas in the halo, including low and intermediate velocity H I, Ha emission from the warm ionized gas at approx. l0(exp 4) K, and hot X-ray emitting gas at approx. l0(exp 6) K . The O VI has an average velocity dispersion, b approx. 60 km/s and standard deviation of 15 km/s. Thermal broadening alone cannot explain the large observed profile widths. A combination of models involving the radiative cooling of hot fountain gas, the cooling of supernova bubbles in the halo, and the turbulent mixing of warm and hot halo gases is required to explain the presence of O VI and other highly ionized atoms found in the halo. The preferential venting of hot gas from local bubbles and superbubbles into the northern Galactic polar region may explain the enhancement of O VI in the North.

  9. 31 CFR 5.11 - How will Treasury entities use tax refund offset to collect a Treasury debt?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Treasury entities use tax refund offset to collect a Treasury debt? (a) Tax refund offset. In most cases... Treasury Offset Program any past-due, legally enforceable debt for collection by tax refund offset. See 26... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false How will Treasury entities use tax...

  10. Hubble Tarantula Treasury Project - VI. Identification of Pre-Main-Sequence Stars using Machine Learning techniques

    NASA Astrophysics Data System (ADS)

    Ksoll, Victor F.; Gouliermis, Dimitrios A.; Klessen, Ralf S.; Grebel, Eva K.; Sabbi, Elena; Anderson, Jay; Lennon, Daniel J.; Cignoni, Michele; de Marchi, Guido; Smith, Linda J.; Tosi, Monica; van der Marel, Roeland P.

    2018-05-01

    The Hubble Tarantula Treasury Project (HTTP) has provided an unprecedented photometric coverage of the entire star-burst region of 30 Doradus down to the half Solar mass limit. We use the deep stellar catalogue of HTTP to identify all the pre-main-sequence (PMS) stars of the region, i.e., stars that have not started their lives on the main-sequence yet. The photometric distinction of these stars from the more evolved populations is not a trivial task due to several factors that alter their colour-magnitude diagram positions. The identification of PMS stars requires, thus, sophisticated statistical methods. We employ Machine Learning Classification techniques on the HTTP survey of more than 800,000 sources to identify the PMS stellar content of the observed field. Our methodology consists of 1) carefully selecting the most probable low-mass PMS stellar population of the star-forming cluster NGC2070, 2) using this sample to train classification algorithms to build a predictive model for PMS stars, and 3) applying this model in order to identify the most probable PMS content across the entire Tarantula Nebula. We employ Decision Tree, Random Forest and Support Vector Machine classifiers to categorise the stars as PMS and Non-PMS. The Random Forest and Support Vector Machine provided the most accurate models, predicting about 20,000 sources with a candidateship probability higher than 50 percent, and almost 10,000 PMS candidates with a probability higher than 95 percent. This is the richest and most accurate photometric catalogue of extragalactic PMS candidates across the extent of a whole star-forming complex.

  11. The Muscles Treasury Survey. I. Motivation and Overview

    NASA Technical Reports Server (NTRS)

    France, Kevin; Loyd, R. O. Parke; Youngblood, Allison; Brown, Alexander; Schneider, P. Christian; Hawley, Suzanne L.; Froning, Cynthia S.; Linsky, Jeffrey L.; Roberge, Aki; Buccino, Andrea P.

    2016-01-01

    Ground- and space-based planet searches employing radial velocity techniques and transit photometry have detected thousands of planet-hosting stars in the Milky Way. With so many planets discovered, the next step toward identifying potentially habitable planets is atmospheric characterization. While the Sun-Earth system provides a good framework for understanding the atmospheric chemistry of Earth-like planets around solar-type stars, the observational and theoretical constraints on the atmospheres of rocky planets in the habitable zones (HZs) around low-mass stars (K and M dwarfs) are relatively few. The chemistry of these atmospheres is controlled by the shape and absolute flux of the stellar spectral energy distribution (SED), however, flux distributions of relatively inactive low-mass stars are poorly understood at present. To address this issue, we have executed a panchromatic (X-ray to mid-IR) study of the SEDs of 11 nearby planet-hosting stars, the Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems (MUSCLES) Treasury Survey. The MUSCLES program consists visible observations from Hubble and ground-based observatories. Infrared and astrophysically inaccessible wavelengths (EUV and Lyalpha) are reconstructed using stellar model spectra to fill in gaps in the observational data. In this overview and the companion papers describing the MUSCLES survey, we show that energetic radiation (X-ray and ultraviolet) is present from magnetically active stellar atmospheres at all times for stars as late as M6. The emission line luminosities of C IV and Mg II are strongly correlated with band-integrated luminosities and we present empirical relations that can be used to estimate broadband FUV and XUV (is equivalent to X-ray + EUV) fluxes from individual stellar emission line measurements. We find that while the slope of the SED, FUV/NUV, increases by approximately two orders of magnitude form early K to late M dwarfs (approximately

  12. THE SPITZER SURVEY OF INTERSTELLAR CLOUDS IN THE GOULD BELT. IV. LUPUS V AND VI OBSERVED WITH IRAC AND MIPS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Spezzi, Loredana; Vernazza, Pierre; Merin, Bruno

    2011-04-01

    We present Gould's Belt (GB) Spitzer IRAC and MIPS observations of the Lupus V and VI clouds and discuss them in combination with near-infrared (2MASS) data. Our observations complement those obtained for other Lupus clouds within the frame of the Spitzer 'Core to Disk' (c2d) Legacy Survey. We found 43 young stellar object (YSO) candidates in Lupus V and 45 in Lupus VI, including two transition disks, using the standard c2d/GB selection method. None of these sources was classified as a pre-main-sequence star from previous optical, near-IR, and X-ray surveys. A large majority of these YSO candidates appear to bemore » surrounded by thin disks (Class III; {approx}79% in Lupus V and {approx}87% in Lupus VI). These Class III abundances differ significantly from those observed for the other Lupus clouds and c2d/GB surveyed star-forming regions, where objects with optically thick disks (Class II) dominate the young population. We investigate various scenarios that can explain this discrepancy. In particular, we show that disk photoevaporation due to nearby OB stars is not responsible for the high fraction of Class III objects. The gas surface densities measured for Lupus V and VI lie below the star formation threshold (A{sub V} {approx} 8.6 mag), while this is not the case for other Lupus clouds. Thus, few Myr older age for the YSOs in Lupus V and VI with respect to other Lupus clouds is the most likely explanation of the high fraction of Class III objects in these clouds, while a higher characteristic stellar mass might be a contributing factor. Better constraints on the age and binary fraction of the Lupus clouds might solve the puzzle but require further observations.« less

  13. 31 CFR 363.37 - How do I purchase and make payment for eligible Treasury securities through my TreasuryDirect...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... eligible Treasury securities through my TreasuryDirect ® account? (a) Online purchase. Purchases of eligible Treasury securities through your TreasuryDirect account must be made online. (b) Payment for...

  14. 31 CFR 363.37 - How do I purchase and make payment for eligible Treasury securities through my TreasuryDirect...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... eligible Treasury securities through my TreasuryDirect ® account? (a) Online purchase. Purchases of eligible Treasury securities through your TreasuryDirect account must be made online. (b) Payment for...

  15. 31 CFR 363.37 - How do I purchase and make payment for eligible Treasury securities through my TreasuryDirect...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Treasury securities through my TreasuryDirect ® account? (a) Online purchase. Purchases of eligible Treasury securities through your TreasuryDirect account must be made online. (b) Payment for savings bonds...

  16. 31 CFR 363.37 - How do I purchase and make payment for eligible Treasury securities through my TreasuryDirect...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Treasury securities through my TreasuryDirect ® account? (a) Online purchase. Purchases of eligible Treasury securities through your TreasuryDirect account must be made online. (b) Payment for savings bonds...

  17. 31 CFR 363.37 - How do I purchase and make payment for eligible Treasury securities through my TreasuryDirect...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Treasury securities through my TreasuryDirect ® account? (a) Online purchase. Purchases of eligible Treasury securities through your TreasuryDirect account must be made online. (b) Payment for savings bonds...

  18. The MUSCLES Treasury Survey. I. Motivation and Overview

    NASA Astrophysics Data System (ADS)

    France, Kevin; Loyd, R. O. Parke; Youngblood, Allison; Brown, Alexander; Schneider, P. Christian; Hawley, Suzanne L.; Froning, Cynthia S.; Linsky, Jeffrey L.; Roberge, Aki; Buccino, Andrea P.; Davenport, James R. A.; Fontenla, Juan M.; Kaltenegger, Lisa; Kowalski, Adam F.; Mauas, Pablo J. D.; Miguel, Yamila; Redfield, Seth; Rugheimer, Sarah; Tian, Feng; Vieytes, Mariela C.; Walkowicz, Lucianne M.; Weisenburger, Kolby L.

    2016-04-01

    Ground- and space-based planet searches employing radial velocity techniques and transit photometry have detected thousands of planet-hosting stars in the Milky Way. With so many planets discovered, the next step toward identifying potentially habitable planets is atmospheric characterization. While the Sun-Earth system provides a good framework for understanding the atmospheric chemistry of Earth-like planets around solar-type stars, the observational and theoretical constraints on the atmospheres of rocky planets in the habitable zones (HZs) around low-mass stars (K and M dwarfs) are relatively few. The chemistry of these atmospheres is controlled by the shape and absolute flux of the stellar spectral energy distribution (SED), however, flux distributions of relatively inactive low-mass stars are poorly understood at present. To address this issue, we have executed a panchromatic (X-ray to mid-IR) study of the SEDs of 11 nearby planet-hosting stars, the Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems (MUSCLES) Treasury Survey. The MUSCLES program consists visible observations from Hubble and ground-based observatories. Infrared and astrophysically inaccessible wavelengths (EUV and Lyα) are reconstructed using stellar model spectra to fill in gaps in the observational data. In this overview and the companion papers describing the MUSCLES survey, we show that energetic radiation (X-ray and ultraviolet) is present from magnetically active stellar atmospheres at all times for stars as late as M6. The emission line luminosities of C IV and Mg II are strongly correlated with band-integrated luminosities and we present empirical relations that can be used to estimate broadband FUV and XUV (≡X-ray + EUV) fluxes from individual stellar emission line measurements. We find that while the slope of the SED, FUV/NUV, increases by approximately two orders of magnitude form early K to late M dwarfs (≈0.01-1), the absolute FUV and

  19. THE MUSCLES TREASURY SURVEY. I. MOTIVATION AND OVERVIEW

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    France, Kevin; Loyd, R. O. Parke; Youngblood, Allison

    2016-04-01

    Ground- and space-based planet searches employing radial velocity techniques and transit photometry have detected thousands of planet-hosting stars in the Milky Way. With so many planets discovered, the next step toward identifying potentially habitable planets is atmospheric characterization. While the Sun–Earth system provides a good framework for understanding the atmospheric chemistry of Earth-like planets around solar-type stars, the observational and theoretical constraints on the atmospheres of rocky planets in the habitable zones (HZs) around low-mass stars (K and M dwarfs) are relatively few. The chemistry of these atmospheres is controlled by the shape and absolute flux of the stellar spectralmore » energy distribution (SED), however, flux distributions of relatively inactive low-mass stars are poorly understood at present. To address this issue, we have executed a panchromatic (X-ray to mid-IR) study of the SEDs of 11 nearby planet-hosting stars, the Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems (MUSCLES) Treasury Survey. The MUSCLES program consists visible observations from Hubble and ground-based observatories. Infrared and astrophysically inaccessible wavelengths (EUV and Lyα) are reconstructed using stellar model spectra to fill in gaps in the observational data. In this overview and the companion papers describing the MUSCLES survey, we show that energetic radiation (X-ray and ultraviolet) is present from magnetically active stellar atmospheres at all times for stars as late as M6. The emission line luminosities of C iv and Mg ii are strongly correlated with band-integrated luminosities and we present empirical relations that can be used to estimate broadband FUV and XUV (≡X-ray + EUV) fluxes from individual stellar emission line measurements. We find that while the slope of the SED, FUV/NUV, increases by approximately two orders of magnitude form early K to late M dwarfs (≈0.01–1), the

  20. 31 CFR 5.4 - What notice will Treasury entities send to a debtor when collecting a Treasury debt?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false What notice will Treasury entities send to a debtor when collecting a Treasury debt? 5.4 Section 5.4 Money and Finance: Treasury Office of... Financial Management Service. Refer the debt to the Financial Management Service for collection (see § 5.9...

  1. 31 CFR 363.4 - How is TreasuryDirect ® different from the Legacy Treasury Direct system and the commercial book...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT... Treasury for purchasing, holding and conducting permitted transactions in eligible Treasury securities in electronic form as a computer record on the books of Treasury. TreasuryDirect currently provides for the...

  2. 31 CFR 363.203 - After I purchase my marketable Treasury security in TreasuryDirect ®, is there a period of time...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the security? Once you purchase a marketable Treasury security in TreasuryDirect, you may not transfer that...

  3. 31 CFR 363.203 - After I purchase my marketable Treasury security in TreasuryDirect ®, is there a period of time...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the security? Once you purchase a marketable Treasury security in TreasuryDirect, you may not transfer that...

  4. 31 CFR 363.203 - After I purchase my marketable Treasury security in TreasuryDirect ®, is there a period of time...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the security? Once you purchase a marketable Treasury security in TreasuryDirect, you may not transfer that...

  5. 31 CFR 363.203 - After I purchase my marketable Treasury security in TreasuryDirect ®, is there a period of time...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the security? Once you purchase a marketable Treasury security in TreasuryDirect, you may not transfer that...

  6. 31 CFR 363.203 - After I purchase my marketable Treasury security in TreasuryDirect ®, is there a period of time...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the... Treasury security in TreasuryDirect ®, is there a period of time during which I may not transfer the security? Once you purchase a marketable Treasury security in TreasuryDirect, you may not transfer that...

  7. 31 CFR 363.4 - How is TreasuryDirect® different from the Legacy Treasury Direct® system and the commercial book...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT... Treasury for purchasing, holding and conducting permitted transactions in eligible Treasury securities in electronic form as a computer record on the books of Treasury. TreasuryDirect currently provides for the...

  8. 31 CFR 363.4 - How is TreasuryDirect® different from the Legacy Treasury Direct® system and the commercial book...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT... Treasury for purchasing, holding and conducting permitted transactions in eligible Treasury securities in electronic form as a computer record on the books of Treasury. TreasuryDirect currently provides for the...

  9. 31 CFR 363.4 - How is TreasuryDirect® different from the Legacy Treasury Direct® system and the commercial book...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., DEPARTMENT OF THE TREASURY BUREAU OF THE FISCAL SERVICE REGULATIONS GOVERNING SECURITIES HELD IN... Treasury for purchasing, holding and conducting permitted transactions in eligible Treasury securities in electronic form as a computer record on the books of Treasury. TreasuryDirect currently provides for the...

  10. 31 CFR 363.4 - How is TreasuryDirect® different from the Legacy Treasury Direct® system and the commercial book...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT... Treasury for purchasing, holding and conducting permitted transactions in eligible Treasury securities in electronic form as a computer record on the books of Treasury. TreasuryDirect currently provides for the...

  11. Survey of Land-Grant Colleges and Universities. Bulletin, 1930, No. 9. Volume II. [Part I - Part VI

    ERIC Educational Resources Information Center

    Office of Education, United States Department of the Interior, 1930

    1930-01-01

    The attached document covers the initial sections of the second volume of the Survey of Land-Grant Colleges and Universities, from Part I to Part VI. Part I, Arts and sciences, contains the following chapters: (1) Introduction; (2) Arts and science organization; (3) Specialization; (4) Enrollments and salaries; (5) Articulation with secondary…

  12. 31 CFR 363.208 - Can I transfer my marketable Treasury security from my TreasuryDirect ® account to an account in...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... security from my TreasuryDirect ® account to an account in another book-entry system? 363.208 Section 363..., DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Marketable Treasury Securities § 363.208 Can I transfer my marketable Treasury security from my Treasury...

  13. 31 CFR 363.206 - How can I transfer my marketable Treasury security into my TreasuryDirect ® account from another...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Treasury security into my TreasuryDirect ® account from another book-entry system? 363.206 Section 363.206... transfer your marketable Treasury security from the commercial book-entry system by contacting the..., DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT...

  14. 31 CFR 281.6 - Withdrawals from Treasury accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Withdrawals from Treasury accounts. 281.6 Section 281.6 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT SERVICE FOREIGN EXCHANGE OPERATIONS § 281...

  15. 31 CFR 281.6 - Withdrawals from Treasury accounts.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false Withdrawals from Treasury accounts. 281.6 Section 281.6 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT SERVICE FOREIGN EXCHANGE OPERATIONS § 281...

  16. 31 CFR 5.6 - When will Treasury entities allow a debtor to pay a Treasury debt in installments instead of one...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false When will Treasury entities allow a debtor to pay a Treasury debt in installments instead of one lump sum? 5.6 Section 5.6 Money and Finance... 901.8 and the Treasury entity's policies and procedures. ...

  17. Celestial Treasury

    NASA Astrophysics Data System (ADS)

    Lachièze-Rey, Marc; Luminet, Jean-Pierre

    2001-07-01

    Throughout history, the mysterious dark skies have inspired our imaginations in countless ways, influencing our endeavors in science and philosophy, religion, literature, and art. Filled with 380 full-color illustrations, Celestial Treasury shows the influence of astronomical theories and the richness of illustrations in Western civilization through the ages. The authors explore the evolution of our understanding of astronomy and weave together ancient and modern theories in a fascinating narrative. They incorporate a wealth of detail from Greek verse, medieval manuscripts and Victorian poetry with contemporary spacecraft photographs and computer-generated star charts. Celestial Treasury is more than a beautiful book: it answers a variety of questions that have intrigued scientists and laymen for centuries. -- How did philosophers and scientists try to explain the order that governs celestial motion? -- How did geometers and artists measure and map the skies? -- How many different answers have been proposed for the most fundamental of all questions: When and how did Earth come about? -- Who inhabits the heavens--gods, angels or extraterrestrials? No other book recounts humankind's fascination with the heavens as compellingly as Celestial Treasury. Marc Lachièze-Rey is a director of research at the Centre National pour la Récherche Scientifique and astrophysicist at the Centre d'Etudes de Saclay. He is the author of The Cosmic Background Radiation (Cambridge, 1999), and and The Quest for Unity, (Oxford, 1999 ), as well as many books in French. Jean-Pierre Luminet is a research director of the Centre National pour la Rechérche Scientifique, based at the Paris-Meudon observatory. He is the author of Black Holes, (Cambridge 1992), as well as science documentaries for television.

  18. 47 CFR 32.4530 - Treasury stock.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 2 2010-10-01 2010-10-01 false Treasury stock. 32.4530 Section 32.4530 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES UNIFORM SYSTEM OF ACCOUNTS FOR TELECOMMUNICATIONS COMPANIES Instructions for Balance Sheet Accounts § 32.4530 Treasury stock...

  19. 12 CFR 390.314 - United States Treasury General Account.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 5 2012-01-01 2012-01-01 false United States Treasury General Account. 390.314... Affecting All State Savings Associations § 390.314 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States Treasury the...

  20. 12 CFR 390.314 - United States Treasury General Account.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 5 2014-01-01 2014-01-01 false United States Treasury General Account. 390.314... Affecting All State Savings Associations § 390.314 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States Treasury the...

  1. 12 CFR 390.314 - United States Treasury General Account.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 5 2013-01-01 2013-01-01 false United States Treasury General Account. 390.314... Affecting All State Savings Associations § 390.314 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States Treasury the...

  2. VizieR Online Data Catalog: Hubble Tarantula Treasury Project (HTTP). III. (Sabbi+, 2016)

    NASA Astrophysics Data System (ADS)

    Sabbi, E.; Lennon, D. J.; Anderson, J.; Cignoni, M.; van der Marel, R. P.; Zaritsky, D.; de Marchi, G.; Panagia, N.; Gouliermis, D. A.; Grebel, E. K.; Gallagher, J. S., III; Smith, L. J.; Sana, H.; Aloisi, A.; Tosi, M.; Evans, C. J.; Arab, H.; Boyer, M.; de Mink, S. E.; Gordon, K.; Koekemoer, A. M.; Larsen, S. S.; Ryon, J. E.; Zeidler, P.

    2016-02-01

    Hubble Tarantula Treasury Project (HTTP; HST 12939, PI Elena Sabbi + HST 12499, PI Danny Lennon) was awarded 60 orbits of HST time in cycle 20 to survey the entire Tarantula Nebula (30 Doradus), using both the UVIS and the IR channels of the Wide Field Camera 3 (WFC3), and, in parallel, the Wide Field Channel (WFC) of the Advanced Camera for Surveys (ACS). See log of the observations (from 2011 Oct 03 to 2013 Sep 17) in table 1. (2 data files).

  3. 31 CFR 5.12 - How will Treasury entities offset a Federal employee's salary to collect a Treasury debt?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... § 5.9(a) of this part, Treasury entities will refer Treasury debts to the Financial Management Service... review of the documentary evidence alone. All travel expenses incurred by the Federal employee in... documentary evidence alone (for example, when an issue of credibility or veracity is involved). The hearing...

  4. Replication profile of Saccharomyces cerevisiae chromosome VI.

    PubMed

    Friedman, K L; Brewer, B J; Fangman, W L

    1997-11-01

    An understanding of the replication programme at the genome level will require the identification and characterization of origins of replication through large, contiguous regions of DNA. As a step toward this goal, origin efficiencies and replication times were determined for 10 ARSs spanning most of the 270 kilobase (kb) chromosome VI of Saccharomyces cerevisiae. Chromosome VI shows a wide variation in the percentage of cell cycles in which different replication origins are utilized. Most of the origins are activated in only a fraction of cells, suggesting that the pattern of origin usage on chromosome VI varies greatly within the cell population. The replication times of fragments containing chromosome VI origins show a temporal pattern that has been recognized on other chromosomes--the telomeres replicate late in S phase, while the central region of the chromosome replicates early. As demonstrated here for chromosome VI, analysis of the direction of replication fork movement along a chromosome and determination of replication time by measuring a period of hemimethylation may provide an efficient means of surveying origin activity over large regions of the genome.

  5. The MUSCLES Treasury Survey: Temporally- and Spectrally-Resolved Irradiance from Low-mass Exoplanet Host Stars

    NASA Astrophysics Data System (ADS)

    France, Kevin; Loyd, R. O. Parke; Youngblood, Allison; Linsky, Jeffrey; MUSCLES Treasury Survey Team

    2016-01-01

    The spectral and temporal behavior of exoplanet host stars is a critical input to models of the chemistry and evolution of planetary atmospheres. High-energy photons (X-ray to near-UV; 5 - 3200 Ang) from these stars regulate the atmospheric temperature profiles and photochemistry on orbiting planets, influencing the production of potential "biomarker" gases. It has been shown that the atmospheric signatures of potentially habitable planets around low-mass stars may be significantly different from planets orbiting Sun-like stars owing to the different UV spectral energy distribution. I will present results from a panchromatic survey (Hubble/Chandra/XMM/optical) of M and K dwarf exoplanet hosts, the MUSCLES Treasury Survey (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems). We reconstruct the Lyman-alpha and extreme-UV (100-900 Ang) radiation lost to interstellar attenuation and create 5 Angstrom to 5 micron stellar irradiance spectra; these data will be publically available as a High-Level Science Product on MAST. We find that all low-mass exoplanet host stars exhibit significant chromospheric/transition region/coronal emission -- no "UV inactive" M dwarfs are observed. The F(far-UV)/F(near-UV) flux ratio, a driver for possible abiotic production of the suggested biomarkers O2 and O3, increases by ~3 orders of magnitude as the habitable zone moves inward from 1 to 0.1 AU, while the incident far-UV (912 - 1700 Ang) and XUV (5 - 900 Ang) radiation field strengths decrease by factors of a few across this range. Far-UV flare activity is common in 'optically inactive' M dwarfs; statistics from the entire sample indicate that large UV flares (E(300 - 1700 Ang) >= 10^31 erg) occur several times per day on typical M dwarf exoplanet hosts.

  6. Microwave tomography enhanced GPR surveys in Centaur’s Domus, Regio VI of Pompeii, Italy

    NASA Astrophysics Data System (ADS)

    Catapano, I.; Crocco, L.; Di Napoli, R.; Soldovieri, F.; Brancaccio, A.; Pesando, F.; Aiello, A.

    2012-08-01

    The archaeological area of Pompeii (Naples, Italy) is known worldwide as one of the most remarkable examples of a Roman Empire town, but its origins are prior to the Roman age and there is a huge archeological interest in discovering the history of the forma urbis. With respect to this framework, the paper presents results from microwave tomography enhanced ground penetrating radar (GPR) surveys carried out in the Centaur’s Domus, Regio VI, one of the most ancient housing areas of Pompeii. The GPR prospections aimed at addressing and driving the archeological excavation campaign performed in this area in October 2010. The results of stratigraphic assays are used to assess the reliability of the tomographic images obtained.

  7. A SURVEY OF METAL LINES AT HIGH-REDSHIFT. I. SDSS ABSORPTION LINE STUDIES- THE METHODOLOGY AND FIRST SEARCH RESULTS FOR O VI

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Frank, S.; Mathur, S.; Pieri, M.

    2010-09-15

    We report the results of a systematic search for signatures of metal lines in quasar spectra of the Sloan Digital Sky Survey (SDSS) data release 3 (DR3), focusing on finding intervening absorbers via detection of their O VI doublet. Here, we present the search algorithm and criteria for distinguishing candidates from spurious Ly{alpha} forest lines. In addition, we compare our findings with simulations of the Ly{alpha} forest in order to estimate the detectability of O VI doublets over various redshift intervals. We have obtained a sample of 1756 O VI doublet candidates with rest-frame equivalent width (EW) {>=}0.05 A inmore » 855 active galactic nuclei spectra (out of 3702 objects with redshifts in the accessible range for O VI detection). This sample is further subdivided into three groups according to the likelihood of being real and the potential for follow-up observation of the candidate. The group with the cleanest and most secure candidates is comprised of 145 candidates. Sixty-nine of these reside at a velocity separation {>=}5000 km s{sup -1} from the QSO and can therefore be classified tentatively as intervening absorbers. Most of these absorbers have not been picked up by earlier, automated QSO absorption line detection algorithms. This sample increases the number of known O VI absorbers at redshifts beyond z{sub abs{>=}} 2.7 substantially.« less

  8. A Survey of Metal Lines at High-redshift. I. SDSS Absorption Line Studies—the Methodology and First Search Results for O VI

    NASA Astrophysics Data System (ADS)

    Frank, S.; Mathur, S.; Pieri, M.; York, D. G.

    2010-09-01

    We report the results of a systematic search for signatures of metal lines in quasar spectra of the Sloan Digital Sky Survey (SDSS) data release 3 (DR3), focusing on finding intervening absorbers via detection of their O VI doublet. Here, we present the search algorithm and criteria for distinguishing candidates from spurious Lyα forest lines. In addition, we compare our findings with simulations of the Lyα forest in order to estimate the detectability of O VI doublets over various redshift intervals. We have obtained a sample of 1756 O VI doublet candidates with rest-frame equivalent width (EW) >=0.05 Å in 855 active galactic nuclei spectra (out of 3702 objects with redshifts in the accessible range for O VI detection). This sample is further subdivided into three groups according to the likelihood of being real and the potential for follow-up observation of the candidate. The group with the cleanest and most secure candidates is comprised of 145 candidates. Sixty-nine of these reside at a velocity separation >=5000 km s-1 from the QSO and can therefore be classified tentatively as intervening absorbers. Most of these absorbers have not been picked up by earlier, automated QSO absorption line detection algorithms. This sample increases the number of known O VI absorbers at redshifts beyond z abs>= 2.7 substantially.

  9. 12 CFR 561.53 - United States Treasury General Account.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 6 2012-01-01 2012-01-01 false United States Treasury General Account. 561.53... REGULATIONS AFFECTING ALL SAVINGS ASSOCIATIONS § 561.53 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States...

  10. 12 CFR 161.53 - United States Treasury General Account.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 1 2014-01-01 2014-01-01 false United States Treasury General Account. 161.53... REGULATIONS AFFECTING ALL SAVINGS ASSOCIATIONS § 161.53 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States...

  11. 31 CFR 337.12 - Applicability of TREASURY DIRECT regulations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... DIRECT regulations. The regulations governing the TREASURY DIRECT Book-Entry Securities System (TREASURY... following exceptions: (a) Securities account. (See § 357.20 of this chapter.) An account in the book-entry debenture system may be established by the Department of the Treasury upon receipt of the request that a new...

  12. 12 CFR 561.53 - United States Treasury General Account.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false United States Treasury General Account. 561.53... REGULATIONS AFFECTING ALL SAVINGS ASSOCIATIONS § 561.53 United States Treasury General Account. The term United States Treasury General Account means an account maintained in the name of the United States...

  13. 31 CFR 205.7 - Can a Treasury-State agreement be amended?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Can a Treasury-State agreement be amended? 205.7 Section 205.7 Money and Finance: Treasury Regulations Relating to Money and Finance... Treasury-State Agreement § 205.7 Can a Treasury-State agreement be amended? (a) We or a State may amend a...

  14. 31 CFR 337.12 - Applicability of TREASURY DIRECT regulations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false Applicability of TREASURY DIRECT regulations. 337.12 Section 337.12 Money and Finance: Treasury Regulations Relating to Money and Finance... subject to call, may be called for redemption, in whole or in part, at par and accrued interest, on any...

  15. Notes made by Thomas Harriot on the treatises of François Viète

    NASA Astrophysics Data System (ADS)

    Stedall, Jacqueline

    2008-03-01

    In the Archive for History of Exact Sciences in 1979 Johannes Lohne published "A survey of Harriot's scientific writings". This has remained until now the only survey of the surviving manuscripts of Thomas Harriot (ca. 1560-1621). Lohne's paper is still a useful resource but it touches only very sketchily on Harriot's debt to François Viète (1540-1603), even though dozens of Harriot's manuscript sheets are filled with re-workings of problems or theorems from Viète's various treatises. Many of these sheets carry overt references to page or proposition numbers in Viète's publications, while others reveal themselves through inspection of the problem they contain. The primary aim of the present paper is to offer a new survey, of precisely those sheets where Harriot can be seen working on the mathematics of Viète. In doing so, it also offers an insight into the reception of Viète's work within his own lifetime at the hands of one of his most astute and able readers.

  16. 31 CFR 363.10 - What is a TreasuryDirect ® account?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT General Provisions Governing Securities Held in TreasuryDirect § 363.10 What is a TreasuryDirect ® account? A TreasuryDirect account is an online account maintained by us solely in...

  17. 31 CFR 546.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 546.802 Section 546.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DARFUR SANCTIONS REGULATIONS...

  18. 31 CFR 357.11 - Laws governing other interests in Treasury securities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Laws governing other interests in Treasury securities. 357.11 Section 357.11 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS...

  19. 31 CFR 537.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Delegation by the Secretary of the Treasury. 537.802 Section 537.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BURMESE SANCTIONS REGULATIONS...

  20. 31 CFR 545.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 545.802 Section 545.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY TALIBAN (AFGHANISTAN) SANCTIONS...

  1. 31 CFR 510.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Delegation by the Secretary of the Treasury. 510.802 Section 510.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  2. 31 CFR 551.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 551.802 Section 551.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS REGULATIONS...

  3. 31 CFR 357.20 - Securities account in Legacy Treasury Direct ®.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Securities System (Legacy Treasury Direct) § 357.20 Securities account in Legacy Treasury Direct ®. (a) Account. A securities account consists of: (1) An account master record, and (2) A securities portfolio... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Securities account in Legacy Treasury...

  4. 31 CFR 539.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 539.802 Section 539.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION TRADE...

  5. 31 CFR 593.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 593.802 Section 593.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FORMER LIBERIAN REGIME OF CHARLES...

  6. 31 CFR 593.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Delegation by the Secretary of the Treasury. 593.802 Section 593.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FORMER LIBERIAN REGIME OF CHARLES...

  7. 31 CFR 593.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Delegation by the Secretary of the Treasury. 593.802 Section 593.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FORMER LIBERIAN REGIME OF CHARLES...

  8. 31 CFR 593.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Delegation by the Secretary of the Treasury. 593.802 Section 593.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FORMER LIBERIAN REGIME OF CHARLES...

  9. 31 CFR 593.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Delegation by the Secretary of the Treasury. 593.802 Section 593.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FORMER LIBERIAN REGIME OF CHARLES...

  10. 31 CFR 547.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 547.802 Section 547.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO...

  11. 31 CFR 547.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Delegation by the Secretary of the Treasury. 547.802 Section 547.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO...

  12. 31 CFR 547.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Delegation by the Secretary of the Treasury. 547.802 Section 547.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO...

  13. 31 CFR 547.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Delegation by the Secretary of the Treasury. 547.802 Section 547.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO...

  14. 31 CFR 547.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Delegation by the Secretary of the Treasury. 547.802 Section 547.802 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO...

  15. 31 CFR 598.803 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Delegation by the Secretary of the Treasury. 598.803 Section 598.803 Money and Finance: Treasury Regulations Relating to Money and Finance... REGULATIONS Procedures § 598.803 Delegation by the Secretary of the Treasury. Any action that the Secretary of...

  16. 31 CFR 598.803 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Delegation by the Secretary of the Treasury. 598.803 Section 598.803 Money and Finance: Treasury Regulations Relating to Money and Finance... REGULATIONS Procedures § 598.803 Delegation by the Secretary of the Treasury. Any action that the Secretary of...

  17. 31 CFR 598.803 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Delegation by the Secretary of the Treasury. 598.803 Section 598.803 Money and Finance: Treasury Regulations Relating to Money and Finance... REGULATIONS Procedures § 598.803 Delegation by the Secretary of the Treasury. Any action that the Secretary of...

  18. 31 CFR 598.803 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Delegation by the Secretary of the Treasury. 598.803 Section 598.803 Money and Finance: Treasury Regulations Relating to Money and Finance... REGULATIONS Procedures § 598.803 Delegation by the Secretary of the Treasury. Any action that the Secretary of...

  19. 31 CFR 598.803 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Delegation by the Secretary of the Treasury. 598.803 Section 598.803 Money and Finance: Treasury Regulations Relating to Money and Finance... REGULATIONS Procedures § 598.803 Delegation by the Secretary of the Treasury. Any action that the Secretary of...

  20. 31 CFR 510.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Delegation by the Secretary of the Treasury. 510.802 Section 510.802 Money and Finance: Treasury Regulations Relating to Money and Finance... Procedures § 510.802 Delegation by the Secretary of the Treasury. Any action that the Secretary of the...

  1. 31 CFR 510.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Delegation by the Secretary of the Treasury. 510.802 Section 510.802 Money and Finance: Treasury Regulations Relating to Money and Finance... Procedures § 510.802 Delegation by the Secretary of the Treasury. Any action that the Secretary of the...

  2. 31 CFR 510.802 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Delegation by the Secretary of the Treasury. 510.802 Section 510.802 Money and Finance: Treasury Regulations Relating to Money and Finance... Procedures § 510.802 Delegation by the Secretary of the Treasury. Any action that the Secretary of the...

  3. 31 CFR 223.22 - Fees for services of the Treasury Department.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Fees for services of the Treasury Department. 223.22 Section 223.22 Money and Finance: Treasury Regulations Relating to Money and Finance... BUSINESS WITH THE UNITED STATES § 223.22 Fees for services of the Treasury Department. (a) Fees shall be...

  4. 31 CFR 223.22 - Fees for services of the Treasury Department.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false Fees for services of the Treasury Department. 223.22 Section 223.22 Money and Finance: Treasury Regulations Relating to Money and Finance... BUSINESS WITH THE UNITED STATES § 223.22 Fees for services of the Treasury Department. (a) Fees shall be...

  5. 31 CFR 223.22 - Fees for services of the Treasury Department.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false Fees for services of the Treasury Department. 223.22 Section 223.22 Money and Finance: Treasury Regulations Relating to Money and Finance... BUSINESS WITH THE UNITED STATES § 223.22 Fees for services of the Treasury Department. (a) Fees shall be...

  6. 31 CFR 223.22 - Fees for services of the Treasury Department.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false Fees for services of the Treasury Department. 223.22 Section 223.22 Money and Finance: Treasury Regulations Relating to Money and Finance... BUSINESS WITH THE UNITED STATES § 223.22 Fees for services of the Treasury Department. (a) Fees shall be...

  7. 31 CFR 223.22 - Fees for services of the Treasury Department.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Fees for services of the Treasury Department. 223.22 Section 223.22 Money and Finance: Treasury Regulations Relating to Money and Finance... BUSINESS WITH THE UNITED STATES § 223.22 Fees for services of the Treasury Department. (a) Fees shall be...

  8. The eta Carinae Treasury Project and the HST/STIS

    NASA Technical Reports Server (NTRS)

    Martin, John C.; Davidson, Kris

    2006-01-01

    The HST Eta Carinae Treasury Project made extensive use of the HST/STIS from 1998 to the time of its failure in 2004. As one of the most prolific users of that instrument, the Treasury Project used the cross-dispersed spatial resolution of the STIS as few projects did. We present several enhancements to the existing STIS data reduction methods that are applicable to non-Treasury Project data in the STIS archive.

  9. Applicability of NASA Polar Technologies to British Antarctic Survey Halley VI Research Station

    NASA Technical Reports Server (NTRS)

    Flynn, Michael

    2005-01-01

    From 1993 through 1997 NASA and the National Science Foundation (NSF), developed a variety of environmental infrastructure technologies for use at the Amundsen-Scott South Pole Station. The objective of this program was to reduce the cost of operating the South Pole Station, reduce the environmental impact of the Station, and to increase the quality of life for Station inhabitants. The result of this program was the development of a set of sustainability technologies designed specifically for Polar applications. In the intervening eight years many of the technologies developed through this program have been commercialized and tested in extreme environments and are now available for use throughout Antarctica and circumpolar north. The objective of this document is to provide information covering technologies that might also be applicable to the British Antarctic Survey s (BAS) proposed new Halley VI Research Station. All technologies described are commercially available.

  10. 31 CFR 363.0 - What is the TreasuryDirect ® system?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES... (TreasuryDirect) is an online account system in which you may hold and conduct transactions in eligible book-entry Treasury securities. ...

  11. 31 CFR 357.20 - Securities account in Legacy Treasury Direct ®.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... number. (c) If a bill is transferred from one Legacy Treasury Direct account to another, the price shown... BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES... the securities portfolio associated with an account master record. (c) Account master record. In order...

  12. 12 CFR 561.54 - United States Treasury Time Deposit Open Account.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 6 2012-01-01 2012-01-01 false United States Treasury Time Deposit Open Account. 561.54 Section 561.54 Banks and Banking OFFICE OF THRIFT SUPERVISION, DEPARTMENT OF THE TREASURY... Open Account. The term United States Treasury Time Deposit Open Account means a non-interest-bearing...

  13. 31 CFR 357.20 - Securities account in Legacy Treasury Direct ®.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... number. (c) If a bill is transferred from one Legacy Treasury Direct account to another, the price shown...-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND... securities portfolio associated with an account master record. (c) Account master record. In order for a...

  14. 31 CFR 357.20 - Securities account in Legacy Treasury Direct ®.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... number. (c) If a bill is transferred from one Legacy Treasury Direct account to another, the price shown...-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND... securities portfolio associated with an account master record. (c) Account master record. In order for a...

  15. 31 CFR 357.20 - Securities account in Legacy Treasury Direct ®.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... number. (c) If a bill is transferred from one Legacy Treasury Direct account to another, the price shown...-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND... securities portfolio associated with an account master record. (c) Account master record. In order for a...

  16. [The sampan dwellers of the Vi Da district (Hue, 1993). Results of a survey preliminary to humanitarian aid intervention].

    PubMed

    Levasseur, G; Lampérin, J M; Le Néel, H; Chambaud, L

    1994-01-01

    This survey is a preliminary step in a cooperative health-care programme, run by the association Le Pélican. It was conducted in July 1993 among the sampan dwellers in the district of Vi Da (Hué), Vietnam. The People's Committee of the town of Hué hopes to improve the living conditions of the inhabitants of the district. The work of the association is part of a wider project of integrated cooperation (Cités unies développement) for the community of sampan dwellers. The survey describes the demography, the state of children's health, the attitudes and behaviour of women and heads of the household towards maternity, contraception, disease and the health-care system. The Vi Da community is young: 40.5% of the inhabitants are under 15 years of age. The main health problems involve mothers and children: 56% of children aged between 5 and 59 months suffer from malnutrition; 71% of those between 0 and 15 years of age have never been vaccinated. The use of contraceptives is inadequate. Health-care services, however, are numerous and are mainly in the private sector. Any health-care project undertaken in this district to improve the state of children's health will have to reinforce the immunisation coverage and set up health education programmes dealing with nutrition and family planning. This will require a better knowledge of the mentality of the sampan dwellers, of their socio-cultural environment and their attitudes to illness and health-care.

  17. Evaluation of Thyroid Hormone Levels and Urinary Iodine Concentrations in Koreans Based on the Data from Korea National Health and Nutrition Examination Survey VI (2013 to 2015).

    PubMed

    Chung, Jae Hoon

    2018-06-01

    No nationwide data have been published about thyroid hormone levels and urinary iodine concentrations (UICs) in Korea. The Korea Centers for Disease Control and Prevention and the Korean Thyroid Association established a project to evaluate the nationwide thyroid hormone profile and UICs in healthy Koreans as part of the Korea National Health and Nutrition Examination Survey (KNHANES) VI (2013 to 2015), a nationwide, cross-sectional survey of the Korean population that enrolled 7,061 individuals who were weighted to represent the entire Korean population. Based on the KNHANES VI, the geometric mean value of serum thyroid stimulating hormone was 2.16 mIU/L, and its reference interval was 0.59 to 7.03 mIU/L. The mean value of serum free thyroxine was 1.25 ng/dL, and its reference interval was 0.92 to 1.60 ng/dL. The median UIC in the Korean population was reported to be 294 μg/L, corresponding to 'above requirements' iodine intake according to the World Health Organization recommendations. A U-shaped relationship of UIC with age was found. The prevalence of overt hyperthyroidism and overt hypothyroidism in the Korean population based on the KNHANES VI was 0.54% and 0.73%, respectively. Copyright © 2018 Korean Endocrine Society.

  18. 77 FR 33634 - U.S. Treasury Securities-State and Local Government Series

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-07

    ... means the current Treasury borrowing rate, less one basis point, as released daily by Treasury in a SLGS rate table. If the current Treasury borrowing rate, together with the one basis point adjustment, results in a negative rate, such corresponding SLGS rate will be set at zero. * * * * * 0 3. Amend Sec...

  19. 76 FR 57907 - Indorsement and Payment of Checks Drawn on the United States Treasury

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-19

    ... Checks Drawn on the United States Treasury AGENCY: Financial Management Service, Fiscal Service, Treasury...), Financial Management Service (FMS), to direct Federal Reserve Banks to debit a financial institution's... the Treasury (Treasury), Financial Management Service (FMS),\\1\\ is amending its regulation at 31 CFR...

  20. 31 CFR 363.13 - How can I open a TreasuryDirect® account?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... can I open a TreasuryDirect® account? (a) General. You must establish a TreasuryDirect account online before you purchase a Treasury security to be held in your account. Instructions for online account...

  1. 31 CFR 363.13 - How can I open a TreasuryDirect® account?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... can I open a TreasuryDirect® account? (a) General. You must establish a TreasuryDirect account online before you purchase a Treasury security to be held in your account. Instructions for online account...

  2. 31 CFR 363.13 - How can I open a TreasuryDirect ® account?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... can I open a TreasuryDirect ® account? (a) General. You must establish a TreasuryDirect account online before you purchase a Treasury security to be held in your account. Instructions for online account...

  3. 31 CFR 363.13 - How can I open a TreasuryDirect ® account?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... can I open a TreasuryDirect ® account? (a) General. You must establish a TreasuryDirect account online before you purchase a Treasury security to be held in your account. Instructions for online account...

  4. 31 CFR 363.13 - How can I open a TreasuryDirect® account?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... can I open a TreasuryDirect® account? (a) General. You must establish a TreasuryDirect account online before you purchase a Treasury security to be held in your account. Instructions for online account...

  5. A Survey of Metal Lines at High Redshift. II. SDSS Absorption Line Studies—O VI Line Density, Space Density, and Gas Metallicity at z abs ~ 3.0

    NASA Astrophysics Data System (ADS)

    Frank, S.; Mathur, S.; Pieri, M.; York, D. G.

    2010-09-01

    We have analyzed a large data set of O VI absorber candidates found in the spectra of 3702 Sloan Digital Sky Survey (SDSS) quasars, focusing on a subsample of 387 active galactic nuclei sight lines with an average S/N >=5.0, allowing for the detection of absorbers above a rest-frame equivalent width limit of W r >= 0.19 Å for the O VI 1032 Å component. Accounting for random interlopers mimicking an O VI doublet, we derive for the first time a secure lower limit for the redshift number density ΔN/Δz for redshifts z abs >= 2.8. With extensive Monte Carlo simulations, we quantify the losses of absorbers due to blending with the ubiquitous Lyα forest lines and estimate the success rate of retrieving each individual candidate as a function of its redshift, the emission redshift of the quasar, the strength of the absorber, and the measured signal-to-noise ratio (S/N) of the spectrum by modeling typical Lyman forest spectra. These correction factors allow us to derive the "incompleteness and S/N-corrected" redshift number densities of O VI absorbers: ΔN O VI,c /Δzc (2.8 < z < 3.2) = 4.6 ± 0.3, ΔN O VI,c /Δzc (3.2 < z < 3.6) = 6.7 ± 0.8, and ΔN O VI,c /Δzc (3.6 < z < 4.0) = 8.4 ± 2.9. We can place a secure lower limit for the contribution of O VI to the closure mass density at the redshifts probed here: ΩO VI (2.8 < z < 3.2) >= 1.9 × 10-8 h -1. We show that the strong lines we probe account for over 65% of the mass in the O VI absorbers; the weak absorbers, while dominant in line number density, do not contribute significantly to the mass density. Making a conservative assumption about the ionization fraction, {O VI}/{O}, and adopting the Anders & Grevesse solar abundance values, we derive the mean metallicity of the gas probed in our search: ζ(2.8 < z < 3.2) >= 3.6 × 10-4 h, in good agreement with other studies. These results demonstrate that large spectroscopic data sets such as SDSS can play an important role in QSO absorption line studies, in spite of

  6. Chromium(VI) release from leather and metals can be detected with a diphenylcarbazide spot test.

    PubMed

    Bregnbak, David; Johansen, Jeanne D; Jellesen, Morten S; Zachariae, Claus; Thyssen, Jacob P

    2015-11-01

    Along with chromium, nickel and cobalt are the clinically most important metal allergens. However, unlike for nickel and cobalt, there is no validated colorimetric spot test that detects chromium. Such a test could help both clinicians and their patients with chromium dermatitis to identify culprit exposures. To evaluate the use of diphenylcarbazide (DPC) as a spot test reagent for the identification of chromium(VI) release. A colorimetric chromium(VI) spot test based on DPC was prepared and used on different items from small market surveys. The DPC spot test was able to identify chromium(VI) release at 0.5 ppm without interference from other pure metals, alloys, or leather. A market survey using the test showed no chromium(VI) release from work tools (0/100). However, chromium(VI) release from metal screws (7/60), one earring (1/50), leather shoes (4/100) and leather gloves (6/11) was observed. We found no false-positive test reactions. Confirmatory testing was performed with X-ray fluorescence (XRF) and spectrophotometrically on extraction fluids. The use of DPC as a colorimetric spot test reagent appears to be a good and valid test method for detecting the release of chromium(VI) ions from leather and metal articles. The spot test has the potential to become a valuable screening tool. © 2015 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  7. Remediation of chromium-slag leakage with electricity cogeneration via a urea-Cr(VI) cell

    PubMed Central

    Yu, Binbin; Zhang, Huimin; Xu, Wei; Li, Gang; Wu, Zucheng

    2014-01-01

    Chromium pollution has been historically widespread throughout the world. Most available remediation technologies often require energy consumption. This study is aimed to develop electrochemical remediation for Cr(VI) in chromium-slag leakage with self-generated electricity. Dynamic leaching experiments of chromium-slag samples were conducted to survey the release and leaching behavior of Cr(VI). Based on previous work, a unique urea-Cr(VI) was designed, in which urea was employed as the fuel and Cr(VI) from the leakage of the dichromate slag served as the oxidant. Furthermore, the electrochemical results showed that the removal percent of Cr(VI) was more than 96% after 18 h with the leakage Cr(VI) concentration of 2.69 mM. The open circuit potential (OCP) varied in the range of 1.56 ~ 1.59 V under different initial Cr(VI) leakage concentrations. The approach explores the feasibility of the promising technique without the need of energy input for simultaneous chromium-slag remediation and generation of electricity. PMID:25168513

  8. 31 CFR 205.8 - What if there is no Treasury-State agreement in effect?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... agreement in effect? 205.8 Section 205.8 Money and Finance: Treasury Regulations Relating to Money and... Included in a Treasury-State Agreement § 205.8 What if there is no Treasury-State agreement in effect? When a State does not have a Treasury-State agreement in effect, we will prescribe default procedures to...

  9. 31 CFR 205.8 - What if there is no Treasury-State agreement in effect?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... agreement in effect? 205.8 Section 205.8 Money and Finance: Treasury Regulations Relating to Money and... Included in a Treasury-State Agreement § 205.8 What if there is no Treasury-State agreement in effect? When a State does not have a Treasury-State agreement in effect, we will prescribe default procedures to...

  10. 31 CFR 205.8 - What if there is no Treasury-State agreement in effect?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... agreement in effect? 205.8 Section 205.8 Money and Finance: Treasury Regulations Relating to Money and... Included in a Treasury-State Agreement § 205.8 What if there is no Treasury-State agreement in effect? When a State does not have a Treasury-State agreement in effect, we will prescribe default procedures to...

  11. 31 CFR 205.8 - What if there is no Treasury-State agreement in effect?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... agreement in effect? 205.8 Section 205.8 Money and Finance: Treasury Regulations Relating to Money and... Included in a Treasury-State Agreement § 205.8 What if there is no Treasury-State agreement in effect? When a State does not have a Treasury-State agreement in effect, we will prescribe default procedures to...

  12. 45 CFR 79.45 - Deposit in Treasury of United States.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Deposit in Treasury of United States. 79.45 Section 79.45 Public Welfare DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL ADMINISTRATION PROGRAM FRAUD CIVIL REMEDIES § 79.45 Deposit in Treasury of United States. All amounts collected pursuant to this part...

  13. 6 CFR 13.45 - Deposit in Treasury of United States.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 6 Domestic Security 1 2010-01-01 2010-01-01 false Deposit in Treasury of United States. 13.45 Section 13.45 Domestic Security DEPARTMENT OF HOMELAND SECURITY, OFFICE OF THE SECRETARY PROGRAM FRAUD CIVIL REMEDIES § 13.45 Deposit in Treasury of United States. All amounts collected pursuant to this part...

  14. 31 CFR 363.12 - Who may purchase and hold book-entry securities in TreasuryDirect ®?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Who may purchase and hold book-entry securities in TreasuryDirect ®? 363.12 Section 363.12 Money and Finance: Treasury Regulations Relating to... TreasuryDirect § 363.12 Who may purchase and hold book-entry securities in TreasuryDirect ®? (a) A Treasury...

  15. 31 CFR 357.24 - Availability and disclosure of Legacy Treasury Direct ® records.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN LEGACY TREASURY DIRECT Legacy... Direct account are held confidential. Consistent with the Privacy Act (5 U.S.C. 552a), information... identify the Legacy Treasury Direct account. (c) Conditions for release. A request for information will be...

  16. 48 CFR 1019.202-70 - The Treasury Mentor-Protégé Program.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false The Treasury Mentor-Protégé Program. 1019.202-70 Section 1019.202-70 Federal Acquisition Regulations System DEPARTMENT OF THE TREASURY SOCIOECONOMIC PROGRAMS SMALL BUSINESS PROGRAMS Policies 1019.202-70 The Treasury Mentor...

  17. 31 CFR 357.24 - Availability and disclosure of Legacy Treasury Direct ® records.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY... Privacy Act (5 U.S.C. 552a), information relating to those accounts will be released only to the owner...) Sufficient information is provided to identify the Legacy Treasury Direct account. (c) Conditions for release...

  18. 31 CFR 357.24 - Availability and disclosure of Legacy Treasury Direct ® records.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY... Privacy Act (5 U.S.C. 552a), information relating to those accounts will be released only to the owner...) Sufficient information is provided to identify the Legacy Treasury Direct account. (c) Conditions for release...

  19. 31 CFR 357.24 - Availability and disclosure of Legacy Treasury Direct ® records.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY... Privacy Act (5 U.S.C. 552a), information relating to those accounts will be released only to the owner...) Sufficient information is provided to identify the Legacy Treasury Direct account. (c) Conditions for release...

  20. 31 CFR 357.24 - Availability and disclosure of Legacy Treasury Direct ® records.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY... Privacy Act (5 U.S.C. 552a), information relating to those accounts will be released only to the owner...) Sufficient information is provided to identify the Legacy Treasury Direct account. (c) Conditions for release...

  1. A survey of infrared and visual image fusion methods

    NASA Astrophysics Data System (ADS)

    Jin, Xin; Jiang, Qian; Yao, Shaowen; Zhou, Dongming; Nie, Rencan; Hai, Jinjin; He, Kangjian

    2017-09-01

    Infrared (IR) and visual (VI) image fusion is designed to fuse multiple source images into a comprehensive image to boost imaging quality and reduce redundancy information, which is widely used in various imaging equipment to improve the visual ability of human and robot. The accurate, reliable and complementary descriptions of the scene in fused images make these techniques be widely used in various fields. In recent years, a large number of fusion methods for IR and VI images have been proposed due to the ever-growing demands and the progress of image representation methods; however, there has not been published an integrated survey paper about this field in last several years. Therefore, we make a survey to report the algorithmic developments of IR and VI image fusion. In this paper, we first characterize the IR and VI image fusion based applications to represent an overview of the research status. Then we present a synthesize survey of the state of the art. Thirdly, the frequently-used image fusion quality measures are introduced. Fourthly, we perform some experiments of typical methods and make corresponding analysis. At last, we summarize the corresponding tendencies and challenges in IR and VI image fusion. This survey concludes that although various IR and VI image fusion methods have been proposed, there still exist further improvements or potential research directions in different applications of IR and VI image fusion.

  2. 31 CFR 223.15 - Paid up capital and surplus for Treasury rating purposes; how determined.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Paid up capital and surplus for Treasury rating purposes; how determined. 223.15 Section 223.15 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT...

  3. 31 CFR 223.15 - Paid up capital and surplus for Treasury rating purposes; how determined.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Paid up capital and surplus for Treasury rating purposes; how determined. 223.15 Section 223.15 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT...

  4. 31 CFR 223.15 - Paid up capital and surplus for Treasury rating purposes; how determined.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false Paid up capital and surplus for Treasury rating purposes; how determined. 223.15 Section 223.15 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT...

  5. 31 CFR 223.15 - Paid up capital and surplus for Treasury rating purposes; how determined.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false Paid up capital and surplus for Treasury rating purposes; how determined. 223.15 Section 223.15 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT...

  6. 31 CFR 223.15 - Paid up capital and surplus for Treasury rating purposes; how determined.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false Paid up capital and surplus for Treasury rating purposes; how determined. 223.15 Section 223.15 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE FISCAL...

  7. 31 CFR 363.131 - What is a TreasuryDirect ® zero-percent certificate of indebtedness?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false What is a TreasuryDirect ® zero... DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.131 What is a TreasuryDirect ® zero-percent certificate of indebtedness? A TreasuryDirect...

  8. 31 CFR 363.131 - What is a TreasuryDirect ® zero-percent certificate of indebtedness?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What is a TreasuryDirect ® zero... DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.131 What is a TreasuryDirect ® zero-percent certificate of indebtedness? A TreasuryDirect...

  9. 31 CFR 363.131 - What is a TreasuryDirect ® zero-percent certificate of indebtedness?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false What is a TreasuryDirect ® zero... DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.131 What is a TreasuryDirect ® zero-percent certificate of indebtedness? A TreasuryDirect...

  10. 31 CFR 363.131 - What is a TreasuryDirect ® zero-percent certificate of indebtedness?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false What is a TreasuryDirect ® zero... SERVICE REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.131 What is a TreasuryDirect ® zero-percent certificate of indebtedness? A TreasuryDirect...

  11. The Mega-MUSCLES Treasury Survey: Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems

    NASA Astrophysics Data System (ADS)

    Froning, Cynthia

    2017-08-01

    JWST will be able to observe the atmospheres of rocky planets transiting nearby M dwarfs. A few such planets are already known (around GJ1132, Proxima Cen, and Trappist-1) and TESS is predicted to find many more, including 14 habitable zone planets. To interpret observations of these exoplanets' atmospheres, we must understand the high-energy SED of their host stars: X-ray/EUV irradiation can erode a planet's gaseous envelope and FUV/NUV-driven photochemistry shapes an atmosphere's molecular abundances, including potential biomarkers like O2, O3, and CH4. Our MUSCLES Treasury Survey (Cycles 19+22) used Hubble/COS+STIS UV observations with contemporaneous X-ray and ground-based data to construct complete SEDs for 11 low-mass exoplanet hosts. MUSCLES is the most widely used database for early-M and K dwarf (>0.3 M_sun) irradiance spectra and has supported a wide range of atmospheric stability and biomarker modeling work. However, TESS will find most of its habitable planets transiting stars less massive than this, and these will be the planets to characterize with JWST. Here, we propose to expand the MUSCLES project to: (a) new M dwarf exoplanet hosts with varying properties; (b) reference M dwarfs below 0.3 solar masses that may be used as proxies for M dwarf planet hosts discovered after HST's lifetime; and (c) more rapidly rotating stars of GJ1132's mass to probe XUV evolution over gigayear timescales. We propose to gather the first panchromatic SEDs of rocky planet hosts GJ1132 and Trappist-1. This proposal extends proven methods to a key new sample of stars, upon which critically depends the long-term goal of studying habitable planet atmospheres with JWST and beyond.

  12. 22 CFR 23.2 - Endorsing remittances for deposit in the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Endorsing remittances for deposit in the Treasury. 23.2 Section 23.2 Foreign Relations DEPARTMENT OF STATE FEES AND FUNDS FINANCE AND ACCOUNTING § 23.2 Endorsing remittances for deposit in the Treasury. The Office of Finance—Cashier Unit, the...

  13. Galactic and Circumgalactic O VI and its Impact on the Cosmological Metal and Baryon Budgets at 2 < z <~ 3.5

    NASA Astrophysics Data System (ADS)

    Lehner, N.; O'Meara, J. M.; Fox, A. J.; Howk, J. C.; Prochaska, J. X.; Burns, V.; Armstrong, A. A.

    2014-06-01

    We present the first results from our NASA Keck Observatory Database of Ionized Absorbers toward Quasars (KODIAQ) survey which aims to characterize the properties of the highly ionized gas of galaxies and their circumgalactic medium (CGM) at 2 < z < 4. We select absorbers optically thick at the Lyman limit (τLL > 1, log N_{H\\,\\scriptsize{I}} \\textgreater 17.3) as probes of these galaxies and their CGM where both transitions of the O VI doublet have little contamination from the Lyα, β forests. We found 20 absorbers that satisfy these rules: 7 Lyman limit systems (LLSs), 8 super-LLSs (SLLSs) and 5 damped Lyα (DLAs). The O VI detection rate is 100% for the DLAs, 71% for the LLSs, and 63% for the SLLSs. When O VI is detected, log \\langle N_{O\\,\\scriptsize{VI}} \\rangle = 14.9 +/- 0.3, an average O VI column density substantially larger and with a smaller dispersion than found in blind O VI surveys at similar redshifts. Strong O VI absorption is therefore nearly ubiquitous in the CGM of z ~ 2-3 galaxies. The total velocity widths of the O VI profiles are also large (200 \\le \\Delta v_{O\\,\\scriptsize{VI}} \\le 400 km s-1). These properties are quite similar to those seen for O VI in low-z star-forming galaxies, and therefore we hypothesize that these strong CGM O VI absorbers (with τLL > 1) at 2 < z <~ 3.5 also probe outflows of star-forming galaxies. The LLSs and SLLSs with no O VI absorption have properties consistent with those seen in cosmological simulations tracing cold streams feeding galaxies. When the highly ionized (Si IV and O VI) gas is taken into account, we determine that the τLL > 1 absorbers could contain as much as 3%-14% of the cosmic baryon budget at z ~ 2-3, only second to the Lyα forest. We conservatively show that 5%-20% of the metals ever produced at z ~ 2-3 are in form of highly ionized metals ejected in the CGM of galaxies. We dedicate this paper and the KODIAQ project to the memory and families of Wal Sargent and Arthur M. Wolfe

  14. 75 FR 78900 - Regulations Governing Book-Entry Treasury Bonds, Notes and Bills Held in Legacy Treasury Direct...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-17

    ... marketable security to a broker or financial institution in order to effect a sale of the security prior to... bypassing the need to transfer their securities to a broker or financial institution for sale. When Treasury...Direct, less than 1.5 percent of holdings. Alternative services by brokers or financial institutions are...

  15. 31 CFR 356.20 - How does the Treasury determine auction awards?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ..., but not above, par when evaluated at the yield of awards to successful competitive bidders. (2... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false How does the Treasury determine... the yield or discount rate for the securities we are auctioning. (2) Accepting bids at the high yield...

  16. 31 CFR 356.20 - How does the Treasury determine auction awards?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ..., but not above, par when evaluated at the yield of awards to successful competitive bidders. (2... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false How does the Treasury determine... the yield or discount rate for the securities we are auctioning. (2) Accepting bids at the high yield...

  17. 31 CFR 356.20 - How does the Treasury determine auction awards?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., but not above, par when evaluated at the yield of awards to successful competitive bidders. (2... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false How does the Treasury determine... the yield or discount rate for the securities we are auctioning. (2) Accepting bids at the high yield...

  18. 31 CFR 356.20 - How does the Treasury determine auction awards?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false How does the Treasury determine... margin for the securities we are auctioning. (2) Accepting bids at the high yield, discount rate, or... the remaining par amount needed to fill the offering amount by the par amount of the bids at the high...

  19. 31 CFR 357.10 - Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Laws governing a Treasury book-entry... PUBLIC DEBT REGULATIONS GOVERNING BOOK-ENTRY TREASURY BONDS, NOTES AND BILLS HELD IN TREASURY/RESERVE... (TRADES) § 357.10 Laws governing a Treasury book-entry security, TRADES, and security interests or...

  20. 78 FR 59228 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds; Corrections

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-26

    ... DEPARTMENT OF THE TREASURY Fiscal Service 31 CFR Part 356 [Docket No. Fiscal-BPD-2013-0001] Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds; Corrections AGENCY: Fiscal... ISSUE OF MARKETABLE BOOK-ENTRY TREASURY BILLS, NOTES, AND BONDS (DEPARTMENT OF THE TREASURY CIRCULAR...

  1. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: a potential source of geogenic Cr(VI) to groundwater

    USGS Publications Warehouse

    Mills, Christopher T.; Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J.

    2011-01-01

    Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization’s maximum contaminant level for drinking water (50 μg L−1) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 μg L−1. To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to ~1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged from 0 to 42 μg kg−1, representing a minute fraction of total Cr. Chromium(VI) content was typically below detection in surface soils (top 10 cm) where soil organic matter was high, and increased with increasing depth in the soil auger cores as organic matter decreased. Maximum concentrations of Cr(VI) were up to 3 times greater in the deeper drill core samples than the shallow auger cores. Although Cr(VI) in these vadose zone soils and sediments was only a

  2. Natural and man-made hexavalent chromium, Cr(VI), in groundwater near a mapped plume, Hinkley, California—study progress as of May 2017, and a summative-scale approach to estimate background Cr(VI) concentrations

    USGS Publications Warehouse

    Izbicki, John A.; Groover, Krishangi D.

    2018-03-22

    This report describes (1) work done between January 2015 and May 2017 as part of the U.S. Geological Survey (USGS) hexavalent chromium, Cr(VI), background study and (2) the summative-scale approach to be used to estimate the extent of anthropogenic (man-made) Cr(VI) and background Cr(VI) concentrations near the Pacific Gas and Electric Company (PG&E) natural gas compressor station in Hinkley, California. Most of the field work for the study was completed by May 2017. The summative-scale approach and calculation of Cr(VI) background were not well-defined at the time the USGS proposal for the background Cr(VI) study was prepared but have since been refined as a result of data collected as part of this study. The proposed summative scale consists of multiple items, formulated as questions to be answered at each sampled well. Questions that compose the summative scale were developed to address geologic, hydrologic, and geochemical constraints on Cr(VI) within the study area. Each question requires a binary (yes or no) answer. A score of 1 will be assigned for an answer that represents data consistent with anthropogenic Cr(VI); a score of –1 will be assigned for an answer that represents data inconsistent with anthropogenic Cr(VI). The areal extent of anthropogenic Cr(VI) estimated from the summative-scale analyses will be compared with the areal extent of anthropogenic Cr(VI) estimated on the basis of numerical groundwater flow model results, along with particle-tracking analyses. On the basis of these combined results, background Cr(VI) values will be estimated for “Mojave-type” deposits, and other deposits, in different parts of the study area outside the summative-scale mapped extent of anthropogenic Cr(VI).

  3. KENO-VI Primer: A Primer for Criticality Calculations with SCALE/KENO-VI Using GeeWiz

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bowman, Stephen M

    2008-09-01

    The SCALE (Standardized Computer Analyses for Licensing Evaluation) computer software system developed at Oak Ridge National Laboratory is widely used and accepted around the world for criticality safety analyses. The well-known KENO-VI three-dimensional Monte Carlo criticality computer code is one of the primary criticality safety analysis tools in SCALE. The KENO-VI primer is designed to help a new user understand and use the SCALE/KENO-VI Monte Carlo code for nuclear criticality safety analyses. It assumes that the user has a college education in a technical field. There is no assumption of familiarity with Monte Carlo codes in general or with SCALE/KENO-VImore » in particular. The primer is designed to teach by example, with each example illustrating two or three features of SCALE/KENO-VI that are useful in criticality analyses. The primer is based on SCALE 6, which includes the Graphically Enhanced Editing Wizard (GeeWiz) Windows user interface. Each example uses GeeWiz to provide the framework for preparing input data and viewing output results. Starting with a Quickstart section, the primer gives an overview of the basic requirements for SCALE/KENO-VI input and allows the user to quickly run a simple criticality problem with SCALE/KENO-VI. The sections that follow Quickstart include a list of basic objectives at the beginning that identifies the goal of the section and the individual SCALE/KENO-VI features that are covered in detail in the sample problems in that section. Upon completion of the primer, a new user should be comfortable using GeeWiz to set up criticality problems in SCALE/KENO-VI. The primer provides a starting point for the criticality safety analyst who uses SCALE/KENO-VI. Complete descriptions are provided in the SCALE/KENO-VI manual. Although the primer is self-contained, it is intended as a companion volume to the SCALE/KENO-VI documentation. (The SCALE manual is provided on the SCALE installation DVD.) The primer provides specific

  4. 31 CFR 315.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... book-entry bonds in New Treasury Direct. 315.3 Section 315.3 Money and Finance: Treasury Regulations.... SAVINGS NOTES General Information § 315.3 Converting definitive savings bonds to book-entry bonds in New... book-entry bonds through New Treasury Direct, an online system for holding Treasury securities. The Web...

  5. 31 CFR 360.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... book-entry bonds in New Treasury Direct. 360.3 Section 360.3 Money and Finance: Treasury Regulations... Converting definitive savings bonds to book-entry bonds in New Treasury Direct. Series I savings bonds that were originally issued as definitive bonds may be converted to book-entry bonds through New Treasury...

  6. 31 CFR 315.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... to book-entry bonds in New Treasury Direct. 315.3 Section 315.3 Money and Finance: Treasury.... SAVINGS NOTES General Information § 315.3 Converting definitive savings bonds to book-entry bonds in New... book-entry bonds through New Treasury Direct, an online system for holding Treasury securities. The Web...

  7. 31 CFR 128.23 - Special survey reports.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false Special survey reports. 128.23... § 128.23 Special survey reports. The Secretary may prescribe special survey reports with respect to.... Notice of special survey reports will be published in accordance with § 128.1(c). ...

  8. 31 CFR 356.30 - When does the Treasury pay principal and interest on securities?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the next business day. If a bond is callable, we will pay the principal prior to maturity if we call... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false When does the Treasury pay principal... CIRCULAR, PUBLIC DEBT SERIES NO. 1-93) Miscellaneous Provisions § 356.30 When does the Treasury pay...

  9. 77 FR 40302 - Department of the Treasury Acquisition Regulation; Internet Payment Platform

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-09

    ... Treasury Acquisition Regulation; Internet Payment Platform AGENCY: Office of the Procurement Executive... Treasury Acquisition Regulation (DTAR) to implement use of the Internet Payment Platform, a centralized... implement the Internet Payment Platform (IPP) no later than the end of fiscal year 2012; with all new...

  10. 31 CFR 363.12 - Who may purchase and hold book-entry securities in TreasuryDirect ®?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Who may purchase and hold book-entry... TreasuryDirect § 363.12 Who may purchase and hold book-entry securities in TreasuryDirect ®? (a) A TreasuryDirect account owner may purchase and hold securities through his or her account. (b) We do not permit a...

  11. The Hubble Tarantula Treasury Project

    NASA Astrophysics Data System (ADS)

    Sabbi, Elena; Lennon, D. J.; Anderson, J.; Van Der Marel, R. P.; Aloisi, A.; Boyer, M. L.; Cignoni, M.; De Marchi, G.; de Mink, S. E.; Evans, C. J.; Gallagher, J. S.; Gordon, K. D.; Gouliermis, D.; Grebel, E.; Koekemoer, A. M.; Larsen, S. S.; Panagia, N.; Ryon, J. E.; Smith, L. J.; Tosi, M.; Zaritsky, D. F.

    2014-01-01

    The Tarantula Nebula (a.k.a. 30 Doradus) in the Large Magellanic Cloud is one of the most famous objects in astronomy, with first astronomical references being more than 150 years old. Today the Tarantula Nebula and its ionizing cluster R136 are considered one of the few known starburst regions in the Local Group and an ideal test bed to investigate the temporal and spatial evolution of a prototypical starburst on a sub-cluster scale. The Hubble Tarantula Treasury Project (HTTP) is a panchromatic imaging survey of the stellar populations and ionized gas in the Tarantula Nebula that reaches into the sub-solar mass regime (<0.5 M⊙). HTTP utilizes the capability of the Hubble Space Telescope to operate the Advanced Camera for Surveys and the Wide Field Camera 3 in parallel to study this remarkable region in the near-ultraviolet, optical, and near-infrared spectral regions, including narrow-band Hα images. The program was awarded 60 orbits of HST time and is built on the existing 30 orbits monochromatic proper motion program GO-12499 (PI Lennon). The combination of all these bands provides a unique view of the region: the resulting maps of the Tarantula’s stellar content provide the basis for investigations of star formation in an environment resembling the extreme conditions found in starburst galaxies and in the early universe. At the same time access to detailed properties of individual stars allows us to begin to reconstruct the temporal and spatial evolution of the Tarantula Nebula over space and time on a sub-parsec scale. We will deliver high-level data products (i.e. star and cluster catalogs, co-registered stacked images). HTTP will become the definitive catalog of the field, and have lasting value for future. HTTP also has an educational and public outreach component aimed to stimulate interest in STEM disciplines among people with visual impairments. “Reach for the Stars: Touch, Look, Listen, Learn” is a free eBook that explains how stars form and

  12. 32 CFR 728.56 - Treasury Department beneficiaries.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... AND DENTAL CARE FOR ELIGIBLE PERSONS AT NAVY MEDICAL DEPARTMENT FACILITIES Beneficiaries of Other... may be beneficiaries of the Treasury Department and may be rendered care as set forth below. (1.... Customs Service. (5) Prisoners (detainees) of the U.S. Customs Service. (b) Care authorized. (1) Secret...

  13. Occurrence of Cr(VI) in drinking water of Greece and relation to the geological background.

    PubMed

    Kaprara, E; Kazakis, N; Simeonidis, K; Coles, S; Zouboulis, A I; Samaras, P; Mitrakas, M

    2015-01-08

    This study provides a survey on potential Cr(VI) exposure attributed to drinking water in Greece. For this reason, a wide sampling and chemical analysis of tap waters from around 600 sites, supplied by groundwater resources, was conducted focusing on areas in which the geological substrate is predominated by ultramafic minerals. Results indicate that although violations of the current chromium regulation limit in tap water are very rare, 25% of cases showed Cr(VI) concentrations above 10 μg/L, whereas Cr(VI) was detectable in 70% of the samples (>2 μg/L). Mineralogy and conditions of groundwater reservoirs were correlated to suggest a possible Cr(VI) leaching mechanism. Higher Cr(VI) values are observed in aquifers in alluvial and neogene sediments of serpentine and amphibolite, originating from the erosion of ophiolithic and metamorphic rocks. In contrast, Cr(VI) concentration in samples from ophiolithic and metamorphic rocks was always below 10 μg/L due to both low contact time and surface area, as verified by low conductivity and salt concentration values. These findings indicate that under specific conditions, pollution of water by Cr(VI) is favorable by a slow MnO2-catalyzed oxidation of soluble Cr(III) to Cr(VI) in which manganese products [Mn(III)/Mn(II)] are probably re-oxidized by oxygen. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. 31 CFR 360.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Treasury Direct, an online system for holding Treasury securities. The Web address for New Treasury Direct... follow online instructions for conversion. Regulations governing converted bonds are found at 31 CFR part...

  15. 31 CFR 363.39 - Will I receive a confirmation of my request to purchase a Treasury security?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... request to purchase a Treasury security? 363.39 Section 363.39 Money and Finance: Treasury Regulations... DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT General Provisions Governing Securities... security? At the time that you submit a request to purchase a Treasury security through your TreasuryDirect...

  16. Groundwater contaminated with hexavalent chromium [Cr (VI)]: a health survey and clinical examination of community inhabitants (Kanpur, India).

    PubMed

    Sharma, Priti; Bihari, Vipin; Agarwal, Sudhir K; Verma, Vipin; Kesavachandran, Chandrasekharan N; Pangtey, Balram S; Mathur, Neeraj; Singh, Kunwar Pal; Srivastava, Mithlesh; Goel, Sudhir K

    2012-01-01

    We assessed the health effects of hexavalent chromium groundwater contamination (from tanneries and chrome sulfate manufacturing) in Kanpur, India. The health status of residents living in areas with high Cr (VI) groundwater contamination (N = 186) were compared to residents with similar social and demographic features living in communities having no elevated Cr (VI) levels (N = 230). Subjects were recruited at health camps in both the areas. Health status was evaluated with health questionnaires, spirometry and blood hematology measures. Cr (VI) was measured in groundwater samples by diphenylcarbazide reagent method. Residents from communities with known Cr (VI) contamination had more self-reports of digestive and dermatological disorders and hematological abnormalities. GI distress was reported in 39.2% vs. 17.2% males (AOR = 3.1) and 39.3% vs. 21% females (AOR = 2.44); skin abnormalities in 24.5% vs. 9.2% males (AOR = 3.48) and 25% vs. 4.9% females (AOR = 6.57). Residents from affected communities had greater RBCs (among 30.7% males and 46.1% females), lower MCVs (among 62.8% males) and less platelets (among 68% males and 72% females) than matched controls. There were no differences in leucocytes count and spirometry parameters. Living in communities with Cr (VI) groundwater is associated with gastrointestinal and dermatological complaints and abnormal hematological function. Limitations of this study include small sample size and the lack of long term follow-up.

  17. 31 CFR 128.13 - Special survey reports.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false Special survey reports. 128.13... Transactions and Positions § 128.13 Special survey reports. The Secretary may prescribe special survey reports... respect to such data. Notice of special survey reports will be published in accordance with § 128.1(c). ...

  18. 12 CFR 7.2020 - Acquisition and holding of shares as treasury stock.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 12 Banks and Banking 1 2011-01-01 2011-01-01 false Acquisition and holding of shares as treasury stock. 7.2020 Section 7.2020 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY BANK ACTIVITIES AND OPERATIONS Corporate Practices § 7.2020 Acquisition and holding of shares as...

  19. 12 CFR 7.2020 - Acquisition and holding of shares as treasury stock.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 1 2013-01-01 2013-01-01 false Acquisition and holding of shares as treasury stock. 7.2020 Section 7.2020 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY BANK ACTIVITIES AND OPERATIONS Corporate Practices § 7.2020 Acquisition and holding of shares as...

  20. 12 CFR 7.2020 - Acquisition and holding of shares as treasury stock.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 1 2014-01-01 2014-01-01 false Acquisition and holding of shares as treasury stock. 7.2020 Section 7.2020 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY BANK ACTIVITIES AND OPERATIONS Corporate Practices § 7.2020 Acquisition and holding of shares as...

  1. 12 CFR 7.2020 - Acquisition and holding of shares as treasury stock.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 1 2012-01-01 2012-01-01 false Acquisition and holding of shares as treasury stock. 7.2020 Section 7.2020 Banks and Banking COMPTROLLER OF THE CURRENCY, DEPARTMENT OF THE TREASURY BANK ACTIVITIES AND OPERATIONS Corporate Practices § 7.2020 Acquisition and holding of shares as...

  2. 31 CFR 353.3 - Converting definitive savings bonds to book-entry bonds in TreasuryDirect®.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... TreasuryDirect®, an online system for holding Treasury securities. The Web address for TreasuryDirect® is... follow online instructions for conversion. Regulations governing converted bonds are found at 31 CFR part...

  3. 48 CFR 1052.219-73 - Department of the Treasury Mentor-Protégé Program.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... DEPARTMENT OF THE TREASURY CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Texts of Provisions and Clauses 1052.219-73 Department of the Treasury Mentor-Protégé Program. As prescribed in 1019.202...) Large and small businesses are encouraged to participate in the Department of the Treasury Mentor...

  4. 48 CFR 1052.219-73 - Department of the Treasury Mentor-Protégé Program.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... DEPARTMENT OF THE TREASURY CLAUSES AND FORMS SOLICITATION PROVISIONS AND CONTRACT CLAUSES Texts of Provisions and Clauses 1052.219-73 Department of the Treasury Mentor-Protégé Program. As described in DTAR 1019...) (a) Large and small businesses are encouraged to participate in the Department of the Treasury Mentor...

  5. 31 CFR 306.23 - Securities eligible to be held in the TREASURY DIRECT Book-entry Securities System.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... TREASURY DIRECT Book-entry Securities System. 306.23 Section 306.23 Money and Finance: Treasury Regulations... Securities eligible to be held in the TREASURY DIRECT Book-entry Securities System. (a) Eligible issues. The... conversion to the TREASURY DIRECT Book-entry Securities System. The notice shall specify the period during...

  6. 31 CFR 205.9 - What is included in a Treasury-State agreement?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... subpart A, consistent with §§ 205.3 and 205.4. A State must use its most recent Single Audit report as a... period instead of Single Audit data, if specified in the Treasury-State agreement. (c) Funding techniques... (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY FINANCIAL MANAGEMENT SERVICE RULES AND PROCEDURES FOR...

  7. 31 CFR 20.400 - What are my responsibilities as a(n) Department of the Treasury awarding official?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance: Treasury 1 2011-07-01 2011-07-01 false What are my responsibilities as a(n) Department of the Treasury awarding official? 20.400 Section 20.400 Money and Finance: Treasury Office of the Secretary of the Treasury GOVERNMENTWIDE REQUIREMENTS FOR DRUG-FREE WORKPLACE (FINANCIAL ASSISTANCE...

  8. 31 CFR 20.400 - What are my responsibilities as a(n) Department of the Treasury awarding official?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance: Treasury 1 2013-07-01 2013-07-01 false What are my responsibilities as a(n) Department of the Treasury awarding official? 20.400 Section 20.400 Money and Finance: Treasury Office of the Secretary of the Treasury GOVERNMENTWIDE REQUIREMENTS FOR DRUG-FREE WORKPLACE (FINANCIAL ASSISTANCE...

  9. 31 CFR 20.400 - What are my responsibilities as a(n) Department of the Treasury awarding official?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 1 2014-07-01 2014-07-01 false What are my responsibilities as a(n) Department of the Treasury awarding official? 20.400 Section 20.400 Money and Finance: Treasury Office of the Secretary of the Treasury GOVERNMENTWIDE REQUIREMENTS FOR DRUG-FREE WORKPLACE (FINANCIAL ASSISTANCE...

  10. 31 CFR 20.400 - What are my responsibilities as a(n) Department of the Treasury awarding official?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance: Treasury 1 2012-07-01 2012-07-01 false What are my responsibilities as a(n) Department of the Treasury awarding official? 20.400 Section 20.400 Money and Finance: Treasury Office of the Secretary of the Treasury GOVERNMENTWIDE REQUIREMENTS FOR DRUG-FREE WORKPLACE (FINANCIAL ASSISTANCE...

  11. 31 CFR 20.400 - What are my responsibilities as a(n) Department of the Treasury awarding official?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 1 2010-07-01 2010-07-01 false What are my responsibilities as a(n) Department of the Treasury awarding official? 20.400 Section 20.400 Money and Finance: Treasury Office of the Secretary of the Treasury GOVERNMENTWIDE REQUIREMENTS FOR DRUG-FREE WORKPLACE (FINANCIAL ASSISTANCE...

  12. 29 CFR 1926.1126 - Chromium (VI).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... activity involving chromium cannot release dusts, fumes, or mists of chromium (VI) in concentrations at or... 29 Labor 8 2014-07-01 2014-07-01 false Chromium (VI). 1926.1126 Section 1926.1126 Labor... Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI) in all forms...

  13. 29 CFR 1926.1126 - Chromium (VI).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... activity involving chromium cannot release dusts, fumes, or mists of chromium (VI) in concentrations at or... 29 Labor 8 2012-07-01 2012-07-01 false Chromium (VI). 1926.1126 Section 1926.1126 Labor... Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI) in all forms...

  14. 29 CFR 1926.1126 - Chromium (VI).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... activity involving chromium cannot release dusts, fumes, or mists of chromium (VI) in concentrations at or... 29 Labor 8 2011-07-01 2011-07-01 false Chromium (VI). 1926.1126 Section 1926.1126 Labor... Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI) in all forms...

  15. 29 CFR 1926.1126 - Chromium (VI).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... activity involving chromium cannot release dusts, fumes, or mists of chromium (VI) in concentrations at or... 29 Labor 8 2013-07-01 2013-07-01 false Chromium (VI). 1926.1126 Section 1926.1126 Labor... Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI) in all forms...

  16. 29 CFR 1650.206 - Notification to Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Regulations Relating to Labor (Continued) EQUAL EMPLOYMENT OPPORTUNITY COMMISSION DEBT COLLECTION Procedures... referring a debt to Treasury, EEOC will certify that the debt meets all of the requirements in § 1650.202..., the amount of the debt, the date on which the debt became past-due, and the designation of EEOC as the...

  17. 29 CFR 1650.206 - Notification to Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Regulations Relating to Labor (Continued) EQUAL EMPLOYMENT OPPORTUNITY COMMISSION DEBT COLLECTION Procedures... referring a debt to Treasury, EEOC will certify that the debt meets all of the requirements in § 1650.202..., the amount of the debt, the date on which the debt became past-due, and the designation of EEOC as the...

  18. 29 CFR 1650.206 - Notification to Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Regulations Relating to Labor (Continued) EQUAL EMPLOYMENT OPPORTUNITY COMMISSION DEBT COLLECTION Procedures... referring a debt to Treasury, EEOC will certify that the debt meets all of the requirements in § 1650.202..., the amount of the debt, the date on which the debt became past-due, and the designation of EEOC as the...

  19. 29 CFR 1650.206 - Notification to Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Regulations Relating to Labor (Continued) EQUAL EMPLOYMENT OPPORTUNITY COMMISSION DEBT COLLECTION Procedures... referring a debt to Treasury, EEOC will certify that the debt meets all of the requirements in § 1650.202..., the amount of the debt, the date on which the debt became past-due, and the designation of EEOC as the...

  20. 29 CFR 1650.206 - Notification to Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Regulations Relating to Labor (Continued) EQUAL EMPLOYMENT OPPORTUNITY COMMISSION DEBT COLLECTION Procedures... referring a debt to Treasury, EEOC will certify that the debt meets all of the requirements in § 1650.202..., the amount of the debt, the date on which the debt became past-due, and the designation of EEOC as the...

  1. Groundwater Contaminated with Hexavalent Chromium [Cr (VI)]: A Health Survey and Clinical Examination of Community Inhabitants (Kanpur, India)

    PubMed Central

    Sharma, Priti; Bihari, Vipin; Agarwal, Sudhir K.; Verma, Vipin; Kesavachandran, Chandrasekharan N.; Pangtey, Balram S.; Mathur, Neeraj; Singh, Kunwar Pal; Srivastava, Mithlesh; Goel, Sudhir K.

    2012-01-01

    Background We assessed the health effects of hexavalent chromium groundwater contamination (from tanneries and chrome sulfate manufacturing) in Kanpur, India. Methods The health status of residents living in areas with high Cr (VI) groundwater contamination (N = 186) were compared to residents with similar social and demographic features living in communities having no elevated Cr (VI) levels (N = 230). Subjects were recruited at health camps in both the areas. Health status was evaluated with health questionnaires, spirometry and blood hematology measures. Cr (VI) was measured in groundwater samples by diphenylcarbazide reagent method. Results Residents from communities with known Cr (VI) contamination had more self-reports of digestive and dermatological disorders and hematological abnormalities. GI distress was reported in 39.2% vs. 17.2% males (AOR = 3.1) and 39.3% vs. 21% females (AOR = 2.44); skin abnormalities in 24.5% vs. 9.2% males (AOR = 3.48) and 25% vs. 4.9% females (AOR = 6.57). Residents from affected communities had greater RBCs (among 30.7% males and 46.1% females), lower MCVs (among 62.8% males) and less platelets (among 68% males and 72% females) than matched controls. There were no differences in leucocytes count and spirometry parameters. Conclusions Living in communities with Cr (VI) groundwater is associated with gastrointestinal and dermatological complaints and abnormal hematological function. Limitations of this study include small sample size and the lack of long term follow-up. PMID:23112863

  2. 31 CFR 5.2 - Why is the Treasury Department issuing these regulations and what do they cover?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Department employees). (2) This part does not apply to tax debts nor to any debt for which there is an... the Secretary of the Treasury TREASURY DEBT COLLECTION General Provisions § 5.2 Why is the Treasury... collection of Treasury debts. This part also provides procedures for collection of other debts owed to the...

  3. 31 CFR 357.10 - Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements. 357.10 Section 357.10 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE FISCAL SERVICE REGULATIONS...

  4. 31 CFR 357.10 - Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements. 357.10 Section 357.10 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS...

  5. 31 CFR 357.10 - Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false Laws governing a Treasury book-entry security, TRADES, and security interests or entitlements. 357.10 Section 357.10 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS...

  6. 31 CFR 356.5 - What types of securities does the Treasury auction?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... securities. (a) Treasury bills. (1) Are issued at a discount or at par, depending upon the auction results; (2) Are redeemed at their par amount at maturity; and (3) Have maturities of not more than one year... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What types of securities does the...

  7. 31 CFR 356.5 - What types of securities does the Treasury auction?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... securities. (a) Treasury bills. (1) Are issued at a discount or at par, depending upon the auction results; (2) Are redeemed at their par amount at maturity; and (3) Have maturities of not more than one year... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false What types of securities does the...

  8. 31 CFR 356.5 - What types of securities does the Treasury auction?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... securities. (a) Treasury bills. (1) Are issued at a discount or at par, depending upon the auction results; (2) Are redeemed at their par amount at maturity; and (3) Have maturities of not more than one year... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false What types of securities does the...

  9. 31 CFR 356.5 - What types of securities does the Treasury auction?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... securities. (a) Treasury bills. (1) Are issued at a discount or at par, depending upon the auction results; (2) Are redeemed at their par amount at maturity; and (3) Have maturities of not more than one year... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false What types of securities does the...

  10. 31 CFR 128.13 - Special survey reports.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 1 2014-07-01 2014-07-01 false Special survey reports. 128.13... Reports on International Capital Transactions and Positions § 128.13 Special survey reports. The Secretary may prescribe special survey reports at such times as the Secretary determines there is a need for...

  11. 31 CFR 128.13 - Special survey reports.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance: Treasury 1 2012-07-01 2012-07-01 false Special survey reports. 128.13... Reports on International Capital Transactions and Positions § 128.13 Special survey reports. The Secretary may prescribe special survey reports at such times as the Secretary determines there is a need for...

  12. 31 CFR 128.23 - Special survey reports.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance: Treasury 1 2012-07-01 2012-07-01 false Special survey reports. 128.23... Reports on Foreign Currency Positions § 128.23 Special survey reports. The Secretary may prescribe special survey reports with respect to foreign exchange positions and related information at such times as the...

  13. 31 CFR 128.23 - Special survey reports.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance: Treasury 1 2011-07-01 2011-07-01 false Special survey reports. 128.23... Reports on Foreign Currency Positions § 128.23 Special survey reports. The Secretary may prescribe special survey reports with respect to foreign exchange positions and related information at such times as the...

  14. 31 CFR 128.23 - Special survey reports.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance: Treasury 1 2013-07-01 2013-07-01 false Special survey reports. 128.23... Reports on Foreign Currency Positions § 128.23 Special survey reports. The Secretary may prescribe special survey reports with respect to foreign exchange positions and related information at such times as the...

  15. 31 CFR 128.13 - Special survey reports.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance: Treasury 1 2013-07-01 2013-07-01 false Special survey reports. 128.13... Reports on International Capital Transactions and Positions § 128.13 Special survey reports. The Secretary may prescribe special survey reports at such times as the Secretary determines there is a need for...

  16. 31 CFR 128.13 - Special survey reports.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance: Treasury 1 2011-07-01 2011-07-01 false Special survey reports. 128.13... Reports on International Capital Transactions and Positions § 128.13 Special survey reports. The Secretary may prescribe special survey reports at such times as the Secretary determines there is a need for...

  17. 31 CFR 128.23 - Special survey reports.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 1 2014-07-01 2014-07-01 false Special survey reports. 128.23... Reports on Foreign Currency Positions § 128.23 Special survey reports. The Secretary may prescribe special survey reports with respect to foreign exchange positions and related information at such times as the...

  18. 76 FR 60707 - Supplemental Standards for Ethical Conduct for Employees of the Department of the Treasury

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-30

    ... DEPARTMENT OF THE TREASURY Office of Financial Research 12 CFR Chapter XVI RIN 1505-AC38... Financial Research, Treasury. ACTION: Interim rule. SUMMARY: The Department of the Treasury (Department... chapter in Title 12 of the Code of Federal Regulations to incorporate certain post-employment prohibitions...

  19. Diverse anaerobic Cr(VI) tolerant bacteria from Cr(VI)-contaminated 100H site at Hanford

    NASA Astrophysics Data System (ADS)

    Chakraborty, R.; Phan, R.; Lam, S.; Leung, C.; Brodie, E. L.; Hazen, T. C.

    2007-12-01

    Hexavalent Chromium [Cr(VI)] is a widespread contaminant found in soil, sediment, and ground water. Cr(VI) is more soluble, toxic, carcinogenic, and mutagenic compared to its reduced form Cr(III). In order to stimulate microbially mediated reduction of Cr(VI), a poly-lactate compound HRC was injected into the chromium contaminated aquifers at site 100H at Hanford. Based on the results of the bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products, we recently investigated the diversity of the dominant anaerobic culturable microbial population present at this site and their role in Cr(VI) reduction. Positive enrichments set up at 30°C using specific defined anaerobic media resulted in the isolation of an iron reducing isolate strain HAF, a sulfate reducing isolate strain HBLS and a nitrate reducing isolate, strain HLN among several others. Preliminary 16S rDNA sequence analysis identifies strain HAF as Geobacter metallireducens, strain HLN as Pseudomonas stutzeri and strain HBLS as a member of Desulfovibrio species. Strain HAF isolated with acetate as the electron donor utilized propionate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Growth was optimal at 37°C, pH of 6.5 and 0% salinity. Strain HLN isolated with lactate as electron donor utilized acetate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Optimal growth was observed at 37°C, at a pH of 7.5 and 0.3% salinity. Anaerobic active washed cell suspension of strain HLN reduced almost 95 micromolar Cr(VI) within 4 hours relative to controls. Further, with 100 micromolar Cr(VI) as the sole electron acceptor, cells of strain HLN grew to cell numbers of 4.05X 107/ml over a period of 24hrs after an initial lag, demonstrating direct enzymatic Cr(VI) reduction by this species. 10mM lactate served as the sole electron donor. These results demonstrate that Cr(VI

  20. The MUSCLES Treasury Survey. IV. Scaling Relations for Ultraviolet, Ca II K, and Energetic Particle Fluxes from M Dwarfs

    NASA Astrophysics Data System (ADS)

    Youngblood, Allison; France, Kevin; Loyd, R. O. Parke; Brown, Alexander; Mason, James P.; Schneider, P. Christian; Tilley, Matt A.; Berta-Thompson, Zachory K.; Buccino, Andrea; Froning, Cynthia S.; Hawley, Suzanne L.; Linsky, Jeffrey; Mauas, Pablo J. D.; Redfield, Seth; Kowalski, Adam; Miguel, Yamila; Newton, Elisabeth R.; Rugheimer, Sarah; Segura, Antígona; Roberge, Aki; Vieytes, Mariela

    2017-07-01

    Characterizing the UV spectral energy distribution (SED) of an exoplanet host star is critically important for assessing its planet’s potential habitability, particularly for M dwarfs, as they are prime targets for current and near-term exoplanet characterization efforts and atmospheric models predict that their UV radiation can produce photochemistry on habitable zone planets different from that on Earth. To derive ground-based proxies for UV emission for use when Hubble Space Telescope (HST) observations are unavailable, we have assembled a sample of 15 early to mid-M dwarfs observed by HST and compared their nonsimultaneous UV and optical spectra. We find that the equivalent width of the chromospheric Ca II K line at 3933 Å, when corrected for spectral type, can be used to estimate the stellar surface flux in ultraviolet emission lines, including H I Lyα. In addition, we address another potential driver of habitability: energetic particle fluxes associated with flares. We present a new technique for estimating soft X-ray and >10 MeV proton flux during far-UV emission line flares (Si IV and He II) by assuming solar-like energy partitions. We analyze several flares from the M4 dwarf GJ 876 observed with HST and Chandra as part of the MUSCLES Treasury Survey and find that habitable zone planets orbiting GJ 876 are impacted by large Carrington-like flares with peak soft X-ray fluxes ≥10-3 W m-2 and possible proton fluxes ˜102-103 pfu, approximately four orders of magnitude more frequently than modern-day Earth.

  1. 77 FR 10714 - Department of the Treasury Acquisition Regulation; Internet Payment Platform

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-23

    ...The Department of the Treasury is proposing to amend the Department of the Treasury Acquisition Regulation (DTAR) to implement use of the Internet Payment Platform, a centralized electronic invoicing and payment information system, and to change the definition of bureau to reflect the consolidation on July 21, 2011 of the Office of Thrift Supervision with the Office of the Comptroller of the Currency.

  2. Hubble Tarantula Treasury Project: Unraveling Tarantula's Web. I. Observational Overview and First Results

    NASA Technical Reports Server (NTRS)

    Sabbi, E.; Anderson, J.; Lennon, D. J.; van der Marel, R. P.; Aloisi, A.; Boyer, Martha L.; Cignoni, M.; De Marchi, G.; De Mink, S. E.; Evans, C. J.; hide

    2013-01-01

    The Hubble Tarantula Treasury Project (HTTP) is an ongoing panchromatic imaging survey of stellar populations in the Tarantula Nebula in the Large Magellanic Cloud that reaches into the sub-solar mass regime (<0.5 Stellar Mass). HTTP utilizes the capability of the Hubble Space Telescope to operate the Advanced Camera for Surveys and the Wide Field Camera 3 in parallel to study this remarkable region in the near-ultraviolet, optical, and near-infrared spectral regions, including narrow-band H(alpha) images. The combination of all these bands provides a unique multi-band view. The resulting maps of the stellar content of the Tarantula Nebula within its main body provide the basis for investigations of star formation in an environment resembling the extreme conditions found in starburst galaxies and in the early universe. Access to detailed properties of individual stars allows us to begin to reconstruct the temporal and spatial evolution of the stellar skeleton of the Tarantula Nebula over space and time on a sub-parsec scale. In this first paper we describe the observing strategy, the photometric techniques, and the upcoming data products from this survey and present preliminary results obtained from the analysis of the initial set of near-infrared observations.

  3. 12 CFR 987.9 - Reference to certain Department of Treasury commentary and determinations.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... commentary and determinations. 987.9 Section 987.9 Banks and Banking FEDERAL HOUSING FINANCE BOARD OFFICE OF FINANCE BOOK-ENTRY PROCEDURE FOR CONSOLIDATED OBLIGATIONS § 987.9 Reference to certain Department of Treasury commentary and determinations. (a) The Department of Treasury TRADES Commentary (31 CFR part 357...

  4. The MUSCLES Treasury Survey: Intrinsic Lyα Profile Reconstructions and UV, X-ray, and Optical Correlations of Low-mass Exoplanet Host Stars

    NASA Astrophysics Data System (ADS)

    Youngblood, Allison; France, Kevin; Loyd, R. O. Parke

    2016-01-01

    UV stellar radiation can significantly impact planetary atmospheres through heating and photochemistry, even regulating production of potential biomarkers. Cool stars emit the majority of their UV radiation in the form of emission lines, and the incident UV radiation on close-in habitable-zone planets is significant. Lyα (1215.67 Å) dominates the 912 - 3200 Å spectrum of cool stars, but strong absorption from the interstellar medium (ISM) makes direct observations of the intrinsic Lyα emission of even nearby stars challenging. The MUSCLES Hubble Space Telescope Treasury Survey (Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanetary Systems) has completed observations of 7 M and 4 K stars hosting exoplanets (d < 22 pc) with simultaneous X-ray and ground-based optical spectroscopy for many of the targets. We have reconstructed the intrinsic Lyα profiles using an MCMC technique and used the results to estimate the extreme ultraviolet (100 - 911 Å) spectrum. We also present empirical relations between chromospheric UV and optical lines, e.g., Lyα, Mg II, Ca II H & K, and Hα, for use when direct UV observations of low-mass exoplanet host stars are not possible. The spectra presented here will be made publicly available through MAST to support exoplanet atmosphere modeling.

  5. 31 CFR 2.2 - Access to classified information by historical researchers, former Treasury Presidential and Vice...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... and Vice Presidents. 2.2 Section 2.2 Money and Finance: Treasury Office of the Secretary of the Treasury NATIONAL SECURITY INFORMATION § 2.2 Access to classified information by historical researchers... research projects; (2) Previously occupied a position in the Treasury to which they were appointed by the...

  6. 31 CFR 2.2 - Access to classified information by historical researchers, former Treasury Presidential and Vice...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... and Vice Presidents. 2.2 Section 2.2 Money and Finance: Treasury Office of the Secretary of the Treasury NATIONAL SECURITY INFORMATION § 2.2 Access to classified information by historical researchers... research projects; (2) Previously occupied a position in the Treasury to which they were appointed by the...

  7. 31 CFR 2.2 - Access to classified information by historical researchers, former Treasury Presidential and Vice...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... and Vice Presidents. 2.2 Section 2.2 Money and Finance: Treasury Office of the Secretary of the Treasury NATIONAL SECURITY INFORMATION § 2.2 Access to classified information by historical researchers... research projects; (2) Previously occupied a position in the Treasury to which they were appointed by the...

  8. 31 CFR 2.2 - Access to classified information by historical researchers, former Treasury Presidential and Vice...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... and Vice Presidents. 2.2 Section 2.2 Money and Finance: Treasury Office of the Secretary of the Treasury NATIONAL SECURITY INFORMATION § 2.2 Access to classified information by historical researchers... research projects; (2) Previously occupied a position in the Treasury to which they were appointed by the...

  9. 31 CFR 306.117 - Withdrawal of eligible book-entry Treasury securities for conversion to registered form.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Withdrawal of eligible book-entry... PUBLIC DEBT GENERAL REGULATIONS GOVERNING U.S. SECURITIES Book-Entry Procedure § 306.117 Withdrawal of eligible book-entry Treasury securities for conversion to registered form. (a) Eligible book-entry Treasury...

  10. 31 CFR 306.117 - Withdrawal of eligible book-entry Treasury securities for conversion to registered form.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false Withdrawal of eligible book-entry... PUBLIC DEBT GENERAL REGULATIONS GOVERNING U.S. SECURITIES Book-Entry Procedure § 306.117 Withdrawal of eligible book-entry Treasury securities for conversion to registered form. (a) Eligible book-entry Treasury...

  11. 31 CFR 353.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... book-entry bonds in New Treasury Direct. 353.3 Section 353.3 Money and Finance: Treasury Regulations... § 353.3 Converting definitive savings bonds to book-entry bonds in New Treasury Direct. Series EE savings bonds that were originally issued as definitive bonds may be converted to book-entry bonds through...

  12. Ferrate(VI) oxidation of zinc-cyanide complex.

    PubMed

    Yngard, Ria; Damrongsiri, Seelawut; Osathaphan, Khemarath; Sharma, Virender K

    2007-10-01

    Zinc-cyanide complexes are found in gold mining effluents and in metal finishing rinse water. The effect of Zn(II) on the oxidation of cyanide by ferrate(VI) (Fe(VI)O(4)(2-), Fe(VI)) was thus investigated by studying the kinetics of the reaction of Fe(VI) with cyanide present in a potassium salt of a zinc cyanide complex (K(2)Zn(CN)(4)) and in a mixture of Zn(II) and cyanide solutions as a function of pH (9.0-11.0). The rate-law for the oxidation of Zn(CN)(4)(2-) by Fe(VI) was found to be -d[Fe(VI)]/dt=k[Fe(VI)][Zn(CN)(4)(2-)](0.5). The rate constant, k, decreased with an increase in pH. The effect of temperature (15-45 degrees C) on the oxidation was studied at pH 9.0, which gave an activation energy of 45.7+/-1.5kJmol(-1). The cyanide oxidation rate decreased in the presence of the Zn(II) ions. However, Zn(II) ions had no effect on the cyanide removal efficiency by Fe(VI) and the stoichiometry of Fe(VI) to cyanide was approximately 1:1; similar to the stoichiometry in absence of Zn(II) ions. The destruction of cyanide by Fe(VI) resulted in cyanate. The experiments on removal of cyanide from rinse water using Fe(VI) demonstrated complete conversion of cyanide to cyanate.

  13. 76 FR 60593 - Title VI; Proposed Circular

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-29

    ... DEPARTMENT OF TRANSPORTATION Federal Transit Administration [Docket No. FTA-2011-0054] Title VI... complying with Title VI of the Civil Rights Act of 1964. The purpose of this Circular is to provide.... Department of Transportation's Title VI regulations (49 CFR part 21). FTA is updating its Title VI Circular...

  14. 75 FR 95 - Endorsement and Payment of Checks Drawn on the United States Treasury

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-04

    ... Checks Drawn on the United States Treasury AGENCY: Financial Management Service, Fiscal Service, Treasury..., Financial Management Service (FMS), is proposing to amend its regulation governing the endorsement and... Financial Management Service (FMS) participates in the U.S. government's eRulemaking Initiative by...

  15. The MUSCLES Treasury Survey. IV. Scaling Relations for Ultraviolet, Ca ii K, and Energetic Particle Fluxes from M Dwarfs

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Youngblood, Allison; France, Kevin; Loyd, R. O. Parke

    Characterizing the UV spectral energy distribution (SED) of an exoplanet host star is critically important for assessing its planet’s potential habitability, particularly for M dwarfs, as they are prime targets for current and near-term exoplanet characterization efforts and atmospheric models predict that their UV radiation can produce photochemistry on habitable zone planets different from that on Earth. To derive ground-based proxies for UV emission for use when Hubble Space Telescope ( HST ) observations are unavailable, we have assembled a sample of 15 early to mid-M dwarfs observed by HST and compared their nonsimultaneous UV and optical spectra. We findmore » that the equivalent width of the chromospheric Ca ii K line at 3933 Å, when corrected for spectral type, can be used to estimate the stellar surface flux in ultraviolet emission lines, including H i Ly α . In addition, we address another potential driver of habitability: energetic particle fluxes associated with flares. We present a new technique for estimating soft X-ray and >10 MeV proton flux during far-UV emission line flares (Si iv and He ii) by assuming solar-like energy partitions. We analyze several flares from the M4 dwarf GJ 876 observed with HST and Chandra as part of the MUSCLES Treasury Survey and find that habitable zone planets orbiting GJ 876 are impacted by large Carrington-like flares with peak soft X-ray fluxes ≥10{sup −3} W m{sup −2} and possible proton fluxes ∼10{sup 2}–10{sup 3} pfu, approximately four orders of magnitude more frequently than modern-day Earth.« less

  16. Design, measures and sample characteristics of the CadeViMa-Spain survey on quality of life in community-dwelling older adults.

    PubMed

    Fernandez-Mayoralas, Gloria; Giraldez-Garcia, Carolina; Forjaz, Maria João; Rojo-Perez, Fermina; Martinez-Martin, Pablo; Prieto-Flores, Maria-Eugenia

    2012-03-01

    The survey "Quality of life in older adults-Spain" (CadeViMa-Spain) was designed to obtain information about objective and subjective determinants of Quality of Life (QoL) in old age, from a multidimensional perspective. This paper presents the overall description, methodology, sample characteristics and reliability of the measures used. A cross-sectional survey was carried out in a representative sample of 1106 community-dwelling adults aged 60 years and over in Spain. The sample was obtained by a geodemographically-based proportional multistage stratified sampling. A home-based questionnaire included validated scales and questions about sociodemographic characteristics, global QoL, health, family and social networks, financial means and retirement, leisure and social participation, residential environment, and satisfaction with those issues. Face-to-face semi-structured interviews were conducted. Cronbach's α coefficients were used to assess internal consistency of the scales. This nationally representative survey furnishes information about global QoL, health-related QoL, resources availability, living conditions, and satisfaction with the assessed aspects, including life domains most valued by this group. In general, community-dwelling older adults reported positive assessments of health, living conditions, and high levels of satisfaction with the different aspects of QoL. The reliability of the measures in this population was good. This survey provides comprehensive and useful information, based on the view of older people themselves, with potential to contribute to health and social policies towards promoting active aging. The database is available for in-depth comparisons.

  17. Reduction of ferrate(VI) and oxidation of cyanate in a Fe(VI)-TiO2-UV-NCO- system.

    PubMed

    Winkelmann, Kurt; Sharma, Virender K; Lin, Yekaterina; Shreve, Katherine A; Winkelmann, Catherine; Hoisington, Laura J; Yngard, Ria A

    2008-08-01

    The aqueous photocatalytic degradation of cyanate (NCO(-)), which is a long-lived neurotoxin formed during the remediation of cyanide in industrial waste streams, was studied in the ferrate(VI)-UV-TiO2-NCO(-) system. Kinetics measurements of the photocatalytic reduction of ferrate(VI) were carried out as a function of [NCO(-)], [ferrate(VI)], [O(2)], light intensity (I(o)), and amount of TiO2 in suspensions at pH 9.0. The photocatalytic reduction rate of ferrate(VI) in the studied system can be expressed as -d[Fe(VI)]/dt=kI(o)(0.5) [NCO(-)] [TiO2]. The rate of photocatalytic oxidation of cyanate with ferrate(VI) was greater than the rate in the analogous system without ferrate(VI). The possibility of involvement of reactive ferrate(V) species for this enhancement was determined by studying the reactivity of ferrate(V) with NCO(-) in a homogeneous solution using a premix pulse radiolysis technique. The rate constant for the reaction of ferrate(V) and NCO(-) in alkaline medium was estimated to be (9.60+/-0.07) x 10(2) M(-1) s(-1), which is much slower than the ferrate(VI) self-decomposition reaction (k approximately 10(7) M(-1) s(-1)). An analysis of the kinetic data in the Fe(VI)-UV-TiO2-NCO(-) system suggests that ferrate(V) is not directly participating in the oxidation of cyanate. Possible reactions in the system are presented to explain results of ferrate(VI) reduction and oxidation of cyanate.

  18. 29 CFR 1915.1026 - Chromium (VI).

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... a specific process, operation, or activity involving chromium cannot release dusts, fumes, or mists... 29 Labor 7 2012-07-01 2012-07-01 false Chromium (VI). 1915.1026 Section 1915.1026 Labor... § 1915.1026 Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI...

  19. 29 CFR 1915.1026 - Chromium (VI).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... a specific process, operation, or activity involving chromium cannot release dusts, fumes, or mists... 29 Labor 7 2011-07-01 2011-07-01 false Chromium (VI). 1915.1026 Section 1915.1026 Labor... § 1915.1026 Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI...

  20. 29 CFR 1915.1026 - Chromium (VI).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... a specific process, operation, or activity involving chromium cannot release dusts, fumes, or mists... 29 Labor 7 2013-07-01 2013-07-01 false Chromium (VI). 1915.1026 Section 1915.1026 Labor... § 1915.1026 Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI...

  1. 29 CFR 1915.1026 - Chromium (VI).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... a specific process, operation, or activity involving chromium cannot release dusts, fumes, or mists... 29 Labor 7 2014-07-01 2014-07-01 false Chromium (VI). 1915.1026 Section 1915.1026 Labor... § 1915.1026 Chromium (VI). (a) Scope. (1) This standard applies to occupational exposures to chromium (VI...

  2. 29 CFR 1926.1126 - Chromium (VI).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... is present or is likely to be present from skin or eye contact with chromium (VI), the employer shall... cleaned in a manner that minimizes skin or eye contact with chromium (VI) and effectively prevents the... CFR 1926.51 Where skin contact with chromium (VI) occurs, the employer shall provide washing...

  3. The new geographic information system in ETVA VI.PE.

    NASA Astrophysics Data System (ADS)

    Xagoraris, Zafiris; Soulis, George

    2016-08-01

    ETVA VI.PE. S.A. is a member of the Piraeus Bank Group of Companies and its activities include designing, developing, exploiting and managing Industrial Areas throughout Greece. Inside ETVA VI.PE.'s thirty-one Industrial Parks there are currently 2,500 manufacturing companies established, with 40,000 employees and € 2.5 billion of invested funds. In each one of the industrial areas ETVA VI.PE guarantees the companies industrial lots of land (sites) with propitious building codes and complete infrastructure networks of water supply, sewerage, paved roads, power supply, communications, cleansing services, etc. The development of Geographical Information System for ETVA VI.PE.'s Industrial Parks started at the beginning of 1992 and consists of three subsystems: Cadastre, that manages the information for the land acquisition of Industrial Areas; Street Layout - Sites, that manages the sites sold to manufacturing companies; Networks, that manages the infrastructure networks (roads, water supply, sewerage etc). The mapping of each Industrial Park is made incorporating state-of-the-art photogrammetric, cartographic and surveying methods and techniques. Passing through the phases of initial design (hybrid GIS) and system upgrade (integrated Gis solution with spatial database), the system is currently operating on a new upgrade (integrated gIS solution with spatial database) that includes redesigning and merging the system's database schemas, along with the creation of central security policies, and the development of a new web GIS application for advanced data entry, highly customisable and standard reports, and dynamic interactive maps. The new GIS bring the company to advanced levels of productivity and introduce the new era for decision making and business management.

  4. 31 CFR 256.1 - What is Treasury's role in paying awards and settlements from the Judgment Fund?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false What is Treasury's role in paying... Information § 256.1 What is Treasury's role in paying awards and settlements from the Judgment Fund? (a) The... amount exceeds $2,500 (for administrative awards) and is in compliance with the regulatory requirements...

  5. Mucopolysaccharidosis VI in cats - clarification regarding genetic testing.

    PubMed

    Lyons, Leslie A; Grahn, Robert A; Genova, Francesca; Beccaglia, Michela; Hopwood, John J; Longeri, Maria

    2016-07-02

    The release of new DNA-based diagnostic tools has increased tremendously in companion animals. Over 70 different DNA variants are now known for the cat, including DNA variants in disease-associated genes and genes causing aesthetically interesting traits. The impact genetic tests have on animal breeding and health management is significant because of the ability to control the breeding of domestic cats, especially breed cats. If used properly, genetic testing can prevent the production of diseased animals, causing the reduction of the frequency of the causal variant in the population, and, potentially, the eventual eradication of the disease. However, testing of some identified DNA variants may be unwarranted and cause undo strife within the cat breeding community and unnecessary reduction of gene pools and availability of breeding animals. Testing for mucopolysaccharidosis Type VI (MPS VI) in cats, specifically the genetic testing of the L476P (c.1427T>C) and the D520N (c.1558G>A) variants in arylsulfatase B (ARSB), has come under scrutiny. No health problems are associated with the D520N (c.1558G>A) variant, however, breeders that obtain positive results for this variant are speculating as to possible correlation with health concerns. Birman cats already have a markedly reduced gene pool and have a high frequency of the MPS VI D520N variant. Further reduction of the gene pool by eliminating cats that are heterozygous or homozygous for only the MPS VI D520N variant could lead to more inbreeding depression effects on the breed population. Herein is debated the genetic testing of the MPS VI D520N variant in cats. Surveys from different laboratories suggest the L476P (c.1427T>C) disease-associated variant should be monitored in the cat breed populations, particularly breeds with Siamese derivations and outcrosses. However, the D520N has no evidence of association with disease in cats and testing is not recommended in the absence of L476P genotyping. Selection

  6. 75 FR 75725 - Survey of Information Sharing Practices With Affiliates

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-06

    ... DEPARTMENT OF THE TREASURY Office of Thrift Supervision Survey of Information Sharing Practices... comments concerning the following information collection. Title of Proposal: Survey of Information Sharing...'') Public Law 108-159, 117 Stat. 1952. The OTS will gather information by means of a Survey to be completed...

  7. Oxidation of octylphenol by ferrate(VI).

    PubMed

    Anquandah, George A K; Sharma, Virender K

    2009-01-01

    The rates of the oxidation of octylphenols (OP) by potassium ferrate(VI) (K(2)FeO(4)) in water were determined as a function of pH (8.0-10.9) at 25 degrees C. The rate law for the oxidation of OP by Fe(VI) was found to be first order with each reactant. The observed second-order rate constants, k(obs), for the oxidation of alkylphenols decreased with an increase in pH. The speciation of Fe(VI) (HFeO(4)(-) and FeO(4)(2 -)) and OP (OP-OH and OP-O(-)) species were used to determine individual rate constants of the reactions. Comparison of rate constants and half-lives of oxidation of OP by Fe(VI) with nonylphenol (NP) and bisphenol-A (BPA) were conducted to demonstrate that Fe(VI) efficiently oxidizes environmentally relevant alkylphenols in water.

  8. 31 CFR 315.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... book-entry bonds through New Treasury Direct, an online system for holding Treasury securities. The Web... definitive savings bonds should follow online instructions for conversion. Regulations governing converted...

  9. 31 CFR 315.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... book-entry bonds through New Treasury Direct, an online system for holding Treasury securities. The Web... definitive savings bonds should follow online instructions for conversion. Regulations governing converted...

  10. 31 CFR 315.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... book-entry bonds through New Treasury Direct, an online system for holding Treasury securities. The Web... definitive savings bonds should follow online instructions for conversion. Regulations governing converted...

  11. 31 CFR 353.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... New Treasury Direct, an online system for holding Treasury securities. The Web address for New... bonds should follow online instructions for conversion. Regulations governing converted bonds are found...

  12. 31 CFR 353.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... New Treasury Direct, an online system for holding Treasury securities. The Web address for New... bonds should follow online instructions for conversion. Regulations governing converted bonds are found...

  13. 31 CFR 353.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... New Treasury Direct, an online system for holding Treasury securities. The Web address for New... bonds should follow online instructions for conversion. Regulations governing converted bonds are found...

  14. The biomineralization process of uranium(VI) by Saccharomyces cerevisiae - transformation from amorphous U(VI) to crystalline chernikovite.

    PubMed

    Shen, Yanghao; Zheng, Xinyan; Wang, Xiaoyu; Wang, Tieshan

    2018-05-01

    Microorganisms play a significant role in uranium(VI) biogeochemistry and influence U(VI) transformation through biomineralization. In the present work, the process of uranium mineralization was investigated by Saccharomyces cerevisiae. The toxicity experiments showed that the viability of cell was not significantly affected by 100 mg L -1 U(VI) under 4 days of exposure time. The batch experiments showed that the phosphate concentration and pH value increased over time during U(VI) adsorption. Meanwhile, thermodynamic calculations demonstrated that the adsorption system was supersaturated with respect to UO 2 HPO 4 . The X-ray powder diffraction spectroscopy (XRD), field emission scanning electron microscopy (FE-SEM) equipped with energy dispersive spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) analyses indicated that the U(VI) was first attached onto the cell surface and reacted with hydroxyl, carboxyl, and phosphate groups through electrostatic interactions and complexation. As the immobilization of U(VI) transformed it from the ionic to the amorphous state, lamellar uranium precipitate was formed on the cell surface. With the prolongation of time, the amorphous uranium compound disappeared, and there were some crystalline substances observed extracellularly, which were well-characterized as tetragonal-chernikovite. Furthermore, the size of chernikovite was regulated at nano-level by cells, and the perfect crystal was formed finally. These findings provided an understanding of the non-reductive transformation process of U(VI) from the amorphous to crystalline state within microbe systems, which would be beneficial for the U(VI) treatment and reuse of nuclides and heavy metals.

  15. 31 CFR 356.30 - When does the Treasury pay principal and interest on securities?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false When does the Treasury pay principal... between the discounted amount paid by the investor at original issue and the par value we pay to the... more than the par amount of the security. we will pay the inflation-adjusted principal. (ii) the...

  16. 31 CFR 356.30 - When does the Treasury pay principal and interest on securities?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false When does the Treasury pay principal... between the discounted amount paid by the investor at original issue and the par value we pay to the... more than the par amount of the security. we will pay the inflation-adjusted principal. (ii) the...

  17. 31 CFR 356.30 - When does the Treasury pay principal and interest on securities?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false When does the Treasury pay principal... between the discounted amount paid by the investor at original issue and the par value we pay to the... more than the par amount of the security. we will pay the inflation-adjusted principal. (ii) the...

  18. 31 CFR 356.30 - When does the Treasury pay principal and interest on securities?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false When does the Treasury pay principal... between the discounted amount paid by the investor at original issue and the par value we pay to the... more than the par amount of the security. we will pay the inflation-adjusted principal. (ii) the...

  19. THE MUSCLES TREASURY SURVEY. II. INTRINSIC LY α AND EXTREME ULTRAVIOLET SPECTRA OF K AND M DWARFS WITH EXOPLANETS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Youngblood, Allison; France, Kevin; Loyd, R. O. Parke

    2016-06-20

    The ultraviolet (UV) spectral energy distributions (SEDs) of low-mass (K- and M-type) stars play a critical role in the heating and chemistry of exoplanet atmospheres, but are not observationally well-constrained. Direct observations of the intrinsic flux of the Ly α line (the dominant source of UV photons from low-mass stars) are challenging, as interstellar H i absorbs the entire line core for even the closest stars. To address the existing gap in empirical constraints on the UV flux of K and M dwarfs, the MUSCLES Hubble Space Telescope Treasury Survey has obtained UV observations of 11 nearby M and Kmore » dwarfs hosting exoplanets. This paper presents the Ly α and extreme-UV spectral reconstructions for the MUSCLES targets. Most targets are optically inactive, but all exhibit significant UV activity. We use a Markov Chain Monte Carlo technique to correct the observed Ly α profiles for interstellar absorption, and we employ empirical relations to compute the extreme-UV SED from the intrinsic Ly α flux in ∼100 Å bins from 100–1170 Å. The reconstructed Ly α profiles have 300 km s{sup −1} broad cores, while >1% of the total intrinsic Ly α flux is measured in extended wings between 300 and 1200 km s{sup −1}. The Ly α surface flux positively correlates with the Mg ii surface flux and negatively correlates with the stellar rotation period. Stars with larger Ly α surface flux also tend to have larger surface flux in ions formed at higher temperatures, but these correlations remain statistically insignificant in our sample of 11 stars. We also present H i column density measurements for 10 new sightlines through the local interstellar medium.« less

  20. 31 CFR 360.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Direct, an online system for holding Treasury securities. The Web address for New Treasury Direct is www.treasurydirect.gov. Bond owners who wish to convert their definitive savings bonds should follow online...

  1. 31 CFR 360.3 - Converting definitive savings bonds to book-entry bonds in New Treasury Direct.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Direct, an online system for holding Treasury securities. The Web address for New Treasury Direct is www.treasurydirect.gov. Bond owners who wish to convert their definitive savings bonds should follow online...

  2. 77 FR 16116 - Public Input on the Development and Potential Issuance of Treasury Floating Rate Notes

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-19

    ... appropriate coupon payment frequency of a Treasury FRN? 5. What changes to trading, settlement and accounting systems would be needed to accommodate FRNs? 6. Are there any other operational issues that Treasury...

  3. Technology-derived storage solutions for stabilizing insulin in extreme weather conditions I: the ViViCap-1 device.

    PubMed

    Pfützner, Andreas; Pesach, Gidi; Nagar, Ron

    2017-06-01

    Injectable life-saving drugs should not be exposed to temperatures <4°C/39°F or >30°C/86°F. Frequently, weather conditions exceed these temperature thresholds in many countries. Insulin is to be kept at 4-8°C/~ 39-47°F until use and once opened, is supposed to be stable for up to 31 days at room temperature (exception: 42 days for insulin levemir). Extremely hot or cold external temperature can lead to insulin degradation in a very short time with loss of its glucose-lowering efficacy. Combined chemical and engineering solutions for heat protection are employed in ViViCap-1 for disposable insulin pens. The device works based on vacuum insulation and heat consumption by phase-change material. Laboratory studies with exposure of ViViCap-1 to hot outside conditions were performed to evaluate the device performance. ViViCap-1 keeps insulin at an internal temperature < 29°C/84.2°F for a minimum of 12 h without external power requirement, even when constantly exposed to an outside temperature of 37.8°C/100°F. Bringing the device into an ambient temperature < 26°C/78.8°F reverses the phase-change process and 'recharges' the device for further use. ViViCap-1 performed within its specifications. The small and convenient device maintains the efficacy and safety of using insulin even when carried under hot weather conditions.

  4. The Vi conjugate typhoid vaccine is safe, elicits protective levels of IgG anti-Vi, and is compatible with routine infant vaccines.

    PubMed

    Thiem, Vu Dinh; Lin, Feng-Ying C; Canh, Do Gia; Son, Nguyen Hong; Anh, Dang Duc; Mao, Nguyen Duc; Chu, Chiayung; Hunt, Steven W; Robbins, John B; Schneerson, Rachel; Szu, Shousun C

    2011-05-01

    Typhoid fever remains a serious problem in developing countries. Current vaccines are licensed for individuals who are 5 years old or older. A conjugate of the capsular polysaccharide (CP) of Salmonella enterica serovar Typhi (Vi) bound to recombinant exoprotein A of Pseudomonas aeruginosa (Vi-rEPA) enhanced Vi immunogenicity and protected 2- to 5-year-olds in Vietnam. In this study, Vi-rEPA was evaluated for use in infants. A total of 301 full-term Vietnamese infants received Expanded Program on Immunization (EPI) vaccines alone or with Vi-rEPA or Haemophilus influenzae type b-tetanus toxoid conjugate (Hib-TT) at 2, 4, and 6 months and Vi-rEPA or Hib-TT alone at 12 months. Infants were visited 6, 24, and 48 h after each injection to monitor adverse reactions. Maternal, cord, and infant sera were assayed for IgG anti-Vi and for IgG antibodies to Hib CP and the diphtheria, tetanus, and pertussis toxins at 7, 12, and 13 months. No vaccine-related serious adverse reactions occurred. In the Vi-rEPA group, the IgG anti-Vi geometric mean (GM) increased from the cord level of 0.66 to 17.4 enzyme-linked immunosorbent assay units (EU) at 7 months, declined to 4.76 EU at 12 months, and increased to 50.1 EU 1 month after the 4th dose (95% of infants had levels of ≥ 3.5 EU, the estimated protective level). Controls had no increase of the IgG anti-Vi GM. Infants with cord anti-Vi levels of <3.5 EU responded with significantly higher IgG anti-Vi levels than those with levels of ≥ 3.5 EU. Anti-diphtheria, -tetanus, and -pertussis toxin levels were similar in all groups. Vi-rEPA was safe, induced protective anti-Vi levels, and was compatible with EPI vaccines, and it can be used in infants. High cord IgG anti-Vi levels partially suppressed infant responses to Vi-rEPA.

  5. 31 CFR 363.201 - What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds? 363.201 Section 363.201 Money and Finance... Securities § 363.201 What other regulations govern book-entry marketable book-entry Treasury bills, notes...

  6. 31 CFR 363.201 - What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 2 2012-07-01 2012-07-01 false What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds? 363.201 Section 363.201 Money and Finance... Securities § 363.201 What other regulations govern book-entry marketable book-entry Treasury bills, notes...

  7. 31 CFR 363.201 - What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds? 363.201 Section 363.201 Money and Finance... Securities § 363.201 What other regulations govern book-entry marketable book-entry Treasury bills, notes...

  8. 31 CFR 363.201 - What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds? 363.201 Section 363.201 Money and Finance... Securities § 363.201 What other regulations govern book-entry marketable book-entry Treasury bills, notes...

  9. 31 CFR 363.201 - What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false What other regulations govern book-entry marketable book-entry Treasury bills, notes, and bonds? 363.201 Section 363.201 Money and Finance... Securities § 363.201 What other regulations govern book-entry marketable book-entry Treasury bills, notes...

  10. The MUSCLES Treasury Survey. II. Intrinsic LYα and Extreme Ultraviolet Spectra of K and M Dwarfs with Exoplanets*

    NASA Astrophysics Data System (ADS)

    Youngblood, Allison; France, Kevin; Loyd, R. O. Parke; Linsky, Jeffrey L.; Redfield, Seth; Schneider, P. Christian; Wood, Brian E.; Brown, Alexander; Froning, Cynthia; Miguel, Yamila; Rugheimer, Sarah; Walkowicz, Lucianne

    2016-06-01

    The ultraviolet (UV) spectral energy distributions (SEDs) of low-mass (K- and M-type) stars play a critical role in the heating and chemistry of exoplanet atmospheres, but are not observationally well-constrained. Direct observations of the intrinsic flux of the Lyα line (the dominant source of UV photons from low-mass stars) are challenging, as interstellar H I absorbs the entire line core for even the closest stars. To address the existing gap in empirical constraints on the UV flux of K and M dwarfs, the MUSCLES Hubble Space Telescope Treasury Survey has obtained UV observations of 11 nearby M and K dwarfs hosting exoplanets. This paper presents the Lyα and extreme-UV spectral reconstructions for the MUSCLES targets. Most targets are optically inactive, but all exhibit significant UV activity. We use a Markov Chain Monte Carlo technique to correct the observed Lyα profiles for interstellar absorption, and we employ empirical relations to compute the extreme-UV SED from the intrinsic Lyα flux in ˜100 Å bins from 100-1170 Å. The reconstructed Lyα profiles have 300 km s-1 broad cores, while >1% of the total intrinsic Lyα flux is measured in extended wings between 300 and 1200 km s-1. The Lyα surface flux positively correlates with the Mg II surface flux and negatively correlates with the stellar rotation period. Stars with larger Lyα surface flux also tend to have larger surface flux in ions formed at higher temperatures, but these correlations remain statistically insignificant in our sample of 11 stars. We also present H I column density measurements for 10 new sightlines through the local interstellar medium. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the data archive at the Space Telescope Science Institute. STScI is operated by the Association of Universities for Research in Astronomy, Inc. under NASA contract NAS 5-26555.

  11. 31 CFR 205.6 - What is a Treasury-State agreement?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... documents the accepted funding techniques and methods for calculating interest agreed upon by us and a State... have any effect and this subpart A will govern. (b) A Treasury-State agreement will be effective until...

  12. 31 CFR 205.6 - What is a Treasury-State agreement?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... documents the accepted funding techniques and methods for calculating interest agreed upon by us and a State... have any effect and this subpart A will govern. (b) A Treasury-State agreement will be effective until...

  13. 76 FR 11079 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds; Minimum Interest Rate

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-01

    ... of the Treasury Circular, Public Debt Series No. 1-93] Sale and Issue of Marketable Book-Entry... CFR 356.20(b) of the Uniform Offering Circular for the Sale and Issue of Marketable Book-Entry... conditions for the sale and issuance by the Treasury to the public of marketable book-entry Treasury bills...

  14. Factors Affecting Formation of Incomplete Vi Antibody in Mice

    PubMed Central

    Gaines, Sidney; Currie, Julius A.; Tully, Joseph G.

    1965-01-01

    Gaines, Sidney (Walter Reed Army Institute of Research, Washington, D.C.), Julius A. Currie, and Joseph G. Tully. Factors affecting formation of incomplete Vi antibody in mice. J. Bacteriol. 90:635–642. 1965.—Single immunizing doses of purified Vi antigen elicited complete and incomplete Vi antibodies in BALB/c mice, but only incomplete antibody in Cinnamon mice. Three of six other mouse strains tested responded like BALB/c mice; the remaining three, like Cinnamon mice. Varying the quantity of antigen injected or the route of administration failed to stimulate the production of detectable complete Vi antibody in Cinnamon mice. Such antibody was evoked in these animals by multiple injections of Vi antigen or by inoculating them with Vi-containing bacilli or Vi-coated erythrocytes. The early protection afforded by serum from Vi-immunized BALB/c mice coincided with the appearance of incomplete Vi antibody, 1 day prior to the advent of complete antibody. Persistence of incomplete as well as complete antibody in the serum of immunized mice was demonstrated for at least 56 days after injection of 10 μg of Vi antigen. Incomplete Vi antibody was shown to have blocking ability, in vitro bactericidal activity, and the capability of protecting mice against intracerebral as well as intraperitoneal challenge with virulent typhoid bacilli. Production of incomplete and complete Vi antibodies was adversely affected by immunization with partially depolymerized Vi antigens. PMID:16562060

  15. Coronal gas in the galaxy. II. A statistical analysis of O VI absorptions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jenkins, E.B.

    Results from the survey of interstellar O VI by Jenkins and by Jenkins and Meloy are analyzed to synthesize a global description of the properties of the coronal gas. Tests for correlations of column densities or velocities with properties of the target stars showed no evidence for a circumstellar origin for the absorption lines. An overall average density n (O VI) =2.8 x 10/sup -8/ cm/sup -3/ was found in the galactic plane, with a decrease which approximately follows exp (-z/300 pc) away from the plane.Fluctuations in column densities over various lines of sight suggest that existence of six hotmore » gas regions kpc/sup -/1, randomly distributed in space, each with an O VI column density of about 10/sup 13/ cm/sup -2/. These regions account for an average density n (O VI) =2.1 x 10/sup -8/ cm/sup -3/; the remaining 7 x 10/sup -9/ cm/sup -3/ is produced by more sparsely distributed but thicker parcels of hot gas which are seen toward 10% of the stars. The statistics of radial velocity centroids and widths support the interpretation of distinct domains; each region has an internal velocity dispersion consistent with a Doppler broadening of a plasma at T> or approx. =2 x 10/sup 5/ K (near the characteristic temperature for a maximum concentration of O VI in collisional equilibrium), while the regions themselves move about with a dispersion of radial velocities equal to 26 km s/sup -1/. Systematic motions of gas away from the galactic plane could not be seen, however.Excursions from the normal O VI per unit distance have no perceptible anicorrelation with deviations in reddening by cool interstellar coulds: a fact which suggests that the average filling factor of O VI gas is less than 20% if coronal gas really displaces the cooler material and does not have large variations in density and temperature.« less

  16. Effect of uranium(VI) speciation on simultaneous microbial reduction of uranium(VI) and iron(III).

    PubMed

    Stewart, Brandy D; Amos, Richard T; Fendorf, Scott

    2011-01-01

    Uranium is a pollutant of concern to both human and ecosystem health. Uranium's redox state often dictates whether it will reside in the aqueous or solid phase and thus plays an integral role in the mobility of uranium within the environment. In anaerobic environments, the more oxidized and mobile form of uranium (UO2(2+) and associated species) may be reduced, directly or indirectly, by microorganisms to U(IV) with subsequent precipitation of UO. However, various factors within soils and sediments, such as U(VI) speciation and the presence of competitive electron acceptors, may limit biological reduction of U(VI). Here we examine simultaneous dissimilatory reduction of Fe(III) and U(VI) in batch systems containing dissolved uranyl acetate and ferrihydrite-coated sand. Varying amounts of calcium were added to induce changes in aqueous U(VI) speciation. The amount of uranium removed from solution during 100 h of incubation with S. putrefaciens was 77% in absence of Ca or ferrihydrite, but only 24% (with ferrihydrite) and 14% (without ferrihydrite) were removed for systems with 0.8 mM Ca. Dissimilatory reduction of Fe(III) and U(VI) proceed through different enzyme pathways within one type of organism. We quantified the rate coefficients for simultaneous dissimilatory reduction of Fe(III) and U(VI) in systems varying in Ca concecentration (0-0.8 mM). The mathematical construct, implemented with the reactive transport code MIN3P, reveals predominant factors controlling rates and extent of uranium reduction in complex geochemical systems.

  17. 77 FR 52116 - Title VI; Final Circular

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-28

    ... DEPARTMENT OF TRANSPORTATION Federal Transit Administration [Docket No. FTA-2011-0054] Title VI... Web site, guidance in the form of a Circular to assist grantees in complying with Title VI of the... Title VI regulations (49 CFR part 21). DATES: Effective Date: The effective date of the Circular is...

  18. Kinetic investigations of quinoline oxidation by ferrate(VI).

    PubMed

    Luo, Zhiyong; Li, Xueming; Zhai, Jun

    2016-01-01

    Quinoline is considered as one of the most toxic and carcinogenic compounds and is commonly found in industrial wastewaters, which require treatment before being discharged. Removal of quinoline by the use of an environmentally friendly oxidant, potassium ferrate(VI) (K2FeO4), was assessed by studying the kinetics of the oxidation of quinoline by ferrate(VI) (Fe(VI)) as a function of pH (8.53-10.53) and temperature (21-36°C) in this work. The reaction of quinoline with Fe(VI) was found to be first order in Fe(VI), half order in quinoline, and 1.5 order overall. The observed rate constant at 28°C decreased non-linearly from 0.5334 to 0.2365 M(-0.5) min(-1) with an increase in pH from 8.53 to 10.03. Considering the equilibria of Fe(VI) and quinoline, the reaction between quinoline and Fe(VI) contained two parallel reactions under the given pH conditions. The individual rate constants of these two reactions were determined. The results indicate that the protonated species of Fe(VI) reacts more quickly with quinoline than the deprotonated form of Fe(VI). The reaction activation energy Ea was obtained to be 51.44 kJ·mol(-1), and it was slightly lower than that of conventional chemical reaction. It reveals that the oxidation of quinoline by Fe(VI) is feasible in the routine water treatment.

  19. Identifying the need for a multidisciplinary approach for early recognition of mucopolysaccharidosis VI (MPS VI).

    PubMed

    Choy, Yew Sing; Bhattacharya, Kaustuv; Balasubramaniam, Shanti; Fietz, Michael; Fu, Antony; Inwood, Anita; Jin, Dong-Kyu; Kim, Ok-Hwa; Kosuga, Motomichi; Kwun, Young Hee; Lin, Hsiang-Yu; Lin, Shuan-Pei; Mendelsohn, Nancy J; Okuyama, Torayuki; Samion, Hasri; Tan, Adeline; Tanaka, Akemi; Thamkunanon, Verasak; Thong, Meow-Keong; Toh, Teck-Hock; Yang, Albert D; McGill, Jim

    2015-05-01

    Mucopolysaccharidosis VI (MPS VI, Maroteaux-Lamy syndrome) is caused by deficient activity of the enzyme, N-acetylgalactosamine-4-sulfatase, resulting in impaired degradation of the glycosaminoglycan dermatan sulfate. Patients experience a range of manifestations including joint contractures, short stature, dysostosis multiplex, coarse facial features, decreased pulmonary function, cardiac abnormalities, corneal clouding and shortened life span. Recently, clinicians from institutions in the Asia-Pacific region met to discuss the occurrence and implications of delayed diagnosis and misdiagnosis of MPS VI in the patients they have managed. Eighteen patients (44% female) were diagnosed. The most common sign presented by the patients was bone deformities in 11 patients (65%). Delays to diagnosis occurred due to the lack of or distance to diagnostic facilities for four patients (31%), alternative diagnoses for two patients (15%), and misleading symptoms experienced by two patients (15%). Several patients experienced manifestations that were subtler than would be expected and were subsequently overlooked. Several cases highlighted the unique challenges associated with diagnosing MPS VI from the perspective of different specialties and provide insights into how these patients initially present, which may help to elucidate strategies to improve the diagnosis of MPS VI. Copyright © 2015 Elsevier Inc. All rights reserved.

  20. Immunization with the conjugate vaccine Vi-CRM₁₉₇ against Salmonella typhi induces Vi-specific mucosal and systemic immune responses in mice.

    PubMed

    Fiorino, Fabio; Ciabattini, Annalisa; Rondini, Simona; Pozzi, Gianni; Martin, Laura B; Medaglini, Donata

    2012-09-21

    Typhoid fever is a public health problem, especially among young children in developing countries. To address this need, a glycoconjugate vaccine Vi-CRM₁₉₇, composed of the polysaccharide antigen Vi covalently conjugated to the non-toxic mutant of diphtheria toxin CRM₁₉₇, is under development. Here, we assessed the antibody and cellular responses, both local and systemic, following subcutaneous injection of Vi-CRM₁₉₇. The glycoconjugate elicited Vi-specific serum IgG titers significantly higher than unconjugated Vi, with prevalence of IgG1 that persisted for at least 60 days after immunization. Vi-specific IgG, but not IgA, were present in intestinal washes. Lymphocytes proliferation after restimulation with Vi-CRM₁₉₇ was observed in spleen and mesenteric lymph nodes. These data confirm the immunogenicity of Vi-CRM₁₉₇ and demonstrate that the vaccine-specific antibody and cellular immune responses are present also in the intestinal tract, thus strengthening the suitability of Vi-CRM₁₉₇ as a promising candidate vaccine against Salmonella Typhi. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. 78 FR 46425 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-31

    ... a simple-interest money market yield computed on an actual/360 basis, subject to an appropriate... 13-week Treasury bill auction High Rate (stop out rate) converted into a simple actual/360 interest...-week Treasury bill auction High Rate that has been translated into a simple-interest money market yield...

  2. 77 FR 72278 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-05

    ... whether it would be more important to issue a new floating rate security each month. Maturities: We intend.... SUMMARY: The Department of the Treasury (``Treasury'') intends to issue a new type of marketable security... security. We also invite other comments relevant to the issuance of this new security. DATES: Submit...

  3. 78 FR 50335 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-19

    ... DEPARTMENT OF THE TREASURY Fiscal Service 31 CFR Part 356 [Docket No. Fiscal-BPD-2013-0001] Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds Correction In rule document 2013-18178 appearing on pages 46426-46445 in the issue of July 31, 2013, make the following corrections...

  4. 78 FR 52857 - Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-27

    ... DEPARTMENT OF THE TREASURY Fiscal Service 31 CFR Part 356 [Docket No. Fiscal-BPD-2013-0001] Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds Correction In rule document C1-2013-18178 appearing on page 50335 in the issue of August 19, 2013, make the following correction...

  5. Electrochemical alkaline Fe(VI) water purification and remediation.

    PubMed

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  6. 31 CFR 2.2 - Access to classified information by historical researchers, former Treasury Presidential and Vice...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Treasury NATIONAL SECURITY INFORMATION § 2.2 Access to classified information by historical researchers... security; and (2) Receipt of the individual's written agreement to safeguard classified information... granting of a security clearance for access to classified information. (d) Treasury personnel will...

  7. 77 FR 13388 - Treasury Inspector General for Tax Administration; Privacy Act of 1974: Computer Matching Program

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-06

    ...: Computer Matching Program AGENCY: Treasury Inspector General for Tax Administration, Treasury. ACTION... Internal Revenue Service (IRS) concerning the conduct of TIGTA's computer matching program. DATES... INFORMATION: TIGTA's computer matching program assists in the detection and deterrence of fraud, waste, and...

  8. 76 FR 18062 - U.S. Securities; Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds; Book...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-01

    ...; Sale and Issue of Marketable Book-Entry Treasury Bills, Notes, and Bonds; Book-Entry Treasury Bonds... longer be opened and transfers of securities from other book-entry systems will no longer be [email protected] . SUPPLEMENTARY INFORMATION: Legacy Treasury Direct [supreg] is a book- entry, non...

  9. Myosin VI facilitates connexin 43 gap junction accretion.

    PubMed

    Waxse, Bennett J; Sengupta, Prabuddha; Hesketh, Geoffrey G; Lippincott-Schwartz, Jennifer; Buss, Folma

    2017-03-01

    In this study, we demonstrate myosin VI enrichment at Cx43 (also known as GJA1)-containing gap junctions (GJs) in heart tissue, primary cardiomyocytes and cell culture models. In primary cardiac tissue and in fibroblasts from the myosin VI-null mouse as well as in tissue culture cells transfected with siRNA against myosin VI, we observe reduced GJ plaque size with a concomitant reduction in intercellular communication, as shown by fluorescence recovery after photobleaching (FRAP) and a new method of selective calcein administration. Analysis of the molecular role of myosin VI in Cx43 trafficking indicates that myosin VI is dispensable for the delivery of Cx43 to the cell surface and connexon movement in the plasma membrane. Furthermore, we cannot corroborate clathrin or Dab2 localization at gap junctions and we do not observe a function for the myosin-VI-Dab2 complex in clathrin-dependent endocytosis of annular gap junctions. Instead, we found that myosin VI was localized at the edge of Cx43 plaques by using total internal reflection fluorescence (TIRF) microscopy and use FRAP to identify a plaque accretion defect as the primary manifestation of myosin VI loss in Cx43 homeostasis. A fuller understanding of this derangement may explain the cardiomyopathy or gliosis associated with the loss of myosin VI. © 2017. Published by The Company of Biologists Ltd.

  10. Biosorption of Cr(VI) by coconut coir: spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material.

    PubMed

    Shen, Ying-Shuian; Wang, Shan-Li; Huang, Shiuh-Tsuen; Tzou, Yu-Min; Huang, Jang-Hung

    2010-07-15

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment. 2010 Elsevier B.V. All rights reserved.

  11. 31 CFR 363.36 - What securities can I purchase and hold in my TreasuryDirect ® account?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... are available for purchase through the TreasuryDirect Web site. In addition, you can hold converted... Treasury Direct system or the commercial book-entry system. [70 FR 57443, Sept. 30, 2005] ...

  12. Title VI Summary 2000-2001.

    ERIC Educational Resources Information Center

    Huskey, Barton

    Title VI provides federal funds to states under the Elementary and Secondary Education Act of 1965. This document describes Title VI programs and the use of funds in the Austin Independent School District (AISD), Texas for 2000-2001. The AISD allocation of $481,559 was based on the May 2000 projected school enrollment, including projected…

  13. The adsorption behavior of U(VI) on granite.

    PubMed

    Fan, Q H; Hao, L M; Wang, C L; Zheng, Z; Liu, C L; Wu, W S

    2014-03-01

    The effects of pH, counter ions and temperature on the adsorption of U(VI) on Beishan granite (BsG) were investigated in the presence and absence of fulvic acid (FA) and humic acid (HA). The adsorption edge of U(VI) on BsG suggested that U(VI) adsorption was mainly controlled by ion exchange and outer-sphere complexation at low pH, whereas inner-sphere complex was the dominant adsorption species in the pH range of 4.0-9.0. Above pH 9.0, Na2U2O7 might play an important role in the rise of U(VI) adsorption again. Counter ions such as Cl(-), SO4(2-) and PO4(3-) can provoke U(VI) adsorption on BsG to some extent, which was directly correlated to the complexing ability of U(VI)-ligand. More noticeably, the large enhancement of U(VI) adsorption in the presence of phosphate can be attributed to the ternary complex formation (BsG-PO4-UO2), precipitation ((UO2)3(PO4)2(s)) and secondary phase (Na-autunite). Both FA and HA can slightly increase U(VI) adsorption at low pH, whereas they strongly inhibited U(VI) adsorption at high pH range. Artificial synthesized granite (AsG) prepared in the laboratory is impossible to use as an analogue of natural granite because of the large difference in the adsorption and surface properties.

  14. 31 CFR 306.23 - Securities eligible to be held in the Legacy Treasury Direct® Book-entry Securities System.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Legacy Treasury Direct® Book-entry Securities System. 306.23 Section 306.23 Money and Finance: Treasury... Securities eligible to be held in the Legacy Treasury Direct® Book-entry Securities System. (a) Eligible... book-entry securities system. (b) Conversion of Registered Security to book-entry form to be held in...

  15. Reactivity of nitrido complexes of ruthenium(VI), osmium(VI), and manganese(V) bearing Schiff base and simple anionic ligands.

    PubMed

    Man, Wai-Lun; Lam, William W Y; Lau, Tai-Chu

    2014-02-18

    Nitrido complexes (M≡N) may be key intermediates in chemical and biological nitrogen fixation and serve as useful reagents for nitrogenation of organic compounds. Osmium(VI) nitrido complexes bearing 2,2':6',2″-terpyridine (terpy), 2,2'-bipyridine (bpy), or hydrotris(1-pyrazolyl)borate anion (Tp) ligands are highly electrophilic: they can react with a variety of nucleophiles to generate novel osmium(IV)/(V) complexes. This Account describes our recent results studying the reactivity of nitridocomplexes of ruthenium(VI), osmium(VI), and manganese(V) that bear Schiff bases and other simple anionic ligands. We demonstrate that these nitrido complexes exhibit rich chemical reactivity. They react with various nucleophiles, activate C-H bonds, undergo N···N coupling, catalyze the oxidation of organic compounds, and show anticancer activities. Ruthenium(VI) nitrido complexes bearing Schiff base ligands, such as [Ru(VI)(N)(salchda)(CH3OH)](+) (salchda = N,N'-bis(salicylidene)o-cyclohexyldiamine dianion), are highly electrophilic. This complex reacts readily at ambient conditions with a variety of nucleophiles at rates that are much faster than similar reactions using Os(VI)≡N. This complex also carries out unique reactions, including the direct aziridination of alkenes, C-H bond activation of alkanes and C-N bond cleavage of anilines. The addition of ligands such as pyridine can enhance the reactivity of [Ru(VI)(N)(salchda)(CH3OH)](+). Therefore researchers can tune the reactivity of Ru≡N by adding a ligand L trans to nitride: L-Ru≡N. Moreover, the addition of various nucleophiles (Nu) to Ru(VI)≡N initially generate the ruthenium(IV) imido species Ru(IV)-N(Nu), a new class of hydrogen-atom transfer (HAT) reagents. Nucleophiles also readily add to coordinated Schiff base ligands in Os(VI)≡N and Ru(VI)≡N complexes. These additions are often stereospecific, suggesting that the nitrido ligand has a directing effect on the incoming nucleophile. M≡N is also

  16. Ferrate(VI) oxidation of cyanide in water.

    PubMed

    Costarramone, N; Kneip, A; Castetbon, A

    2004-08-01

    Experiments were conducted to test removal of cyanide (free cyanide and several cyanide complexes) in water, under alkaline medium (pH > or = 11), by a new potassium ferrate salt. The removal rate of free cyanide by oxidation with Fe(VI) was greater at pH 11.0 than at pH 12.0. A complete oxidation was obtained with a 2.67 Fe(VI)/CN ratio at pH 11.0. In these conditions, the rate of cyanide oxidation by Fe(VI) was slow, with a reaction rate constant estimated at 0.95 +/- 0.10 s(-1) l mol(-1) at pH 11.0 and 19.6 degrees C in this study. This study revealed that Fe(VI) did not decompose all cyanide complexes. Copper, cadmium and zinc complexes were removed efficiently by Fe(VI). Moreover, these metals were also removed from the solution by coagulation effect of Fe(OH)3, the Fe(VI) product of reaction. A particular behaviour was reported with copper, as a rapid oxidation of cyanide was observed in the presence of this metal. On the contrary, oxidation of nickel and silver complexes was incomplete.

  17. Mechanisms of chromium (VI)-induced apoptosis in anterior pituitary cells.

    PubMed

    Quinteros, Fernanda A; Machiavelli, Leticia I; Miler, Eliana A; Cabilla, Jimena P; Duvilanski, Beatriz H

    2008-07-30

    Hexavalent chromium (Cr (VI)) is a highly toxic metal. Exposure to Cr (VI) compounds may affect reproductive functions. Due to the importance of anterior pituitary hormones on reproductive physiology we have studied the effects of Cr (VI) on anterior pituitary. We previously demonstrated that, after in vivo Cr (VI) administration, Cr accumulates in the pituitary gland and affects prolactin secretion. In vitro, Cr (VI) causes apoptosis in anterior pituitary cells due to oxidative stress generation. To better understand the mechanisms involved in Cr (VI)-induced apoptosis we studied: (a) whether Cr (VI) affects the intracellular antioxidant response and (b) which of the apoptotic factors participates in Cr (VI) effect. Our results show that Cr (VI) treatment induces a decrease in catalase and glutathione peroxidase (GPx) activity but does not modify glutathione reductase (GR) activity. Cr (VI) exposure causes an increase of GSH levels. p53 and Bax mRNA are also upregulated by the metal. Pifithrin alpha, a p53 transcriptional inhibitor, increases Cr (VI) cytotoxicity, suggesting a role of p53 as a survival molecule. The antioxidant N-acetyl-cysteine (NAC) could prevent Bax mRNA increase and caspase 3 activation, confirming that Cr (VI)-induced apoptosis involves oxidative stress generation.

  18. 31 CFR 592.702 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ROUGH DIAMONDS CONTROL REGULATIONS... any further Executive orders relating to the Clean Diamond Trade Act (Pub. L. 108-19) may be taken by...

  19. 31 CFR 592.702 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ROUGH DIAMONDS CONTROL REGULATIONS... any further Executive orders relating to the Clean Diamond Trade Act (Pub. L. 108-19) may be taken by...

  20. 31 CFR 592.702 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ROUGH DIAMONDS CONTROL REGULATIONS... any further Executive orders relating to the Clean Diamond Trade Act (Pub. L. 108-19) may be taken by...

  1. 31 CFR 592.702 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ROUGH DIAMONDS CONTROL REGULATIONS... any further Executive orders relating to the Clean Diamond Trade Act (Pub. L. 108-19) may be taken by...

  2. 31 CFR 592.702 - Delegation by the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ROUGH DIAMONDS CONTROL REGULATIONS... any further Executive orders relating to the Clean Diamond Trade Act (Pub. L. 108-19) may be taken by...

  3. 78 FR 60020 - Proposed Collection: Comment Request for Voluntary Customer Satisfaction Surveys

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-09-30

    ... Voluntary Customer Satisfaction Surveys ACTION: Notice and request for comments. SUMMARY: The Department of... Treasury is soliciting comments concerning the Customer Satisfaction Survey. DATES: Written comments should..., WV 26106-1328, (304) 480- 8150. SUPPLEMENTARY INFORMATION: Title: Voluntary Customer Satisfaction...

  4. 31 CFR 205.7 - Can a Treasury-State agreement be amended?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... subpart A; (2) Changes in funding techniques; and (3) Changes in clearance patterns. (d) Additions or deletions to the list of Federal assistance programs subject to this subpart A take effect when a Treasury...

  5. Emissions of chromium (VI) from arc welding.

    PubMed

    Heung, William; Yun, Myoung-Jin; Chang, Daniel P Y; Green, Peter G; Halm, Chris

    2007-02-01

    The presence of Cr in the +6 oxidation state (Cr[VI]) is still observed in ambient air samples in California despite steps taken to reduce emissions from plating operations. One known source of emission of Cr(VI) is welding, especially with high Cr-content materials, such as stainless steels. An experimental effort was undertaken to expand and update Cr(VI) emission factors by conducting tests on four types of arc-welding operations: gas-metal arc welding (GMAW), shielded metal arc welding (SMAW), fluxcore arc welding, and pulsed GMAW. Standard American Welding Society hood results were compared with a total enclosure method that permitted isokinetic sampling for particle size-cut measurement, as well as total collection of the aerosol. The fraction of Cr(VI) emitted per unit mass of Cr electrode consumed was determined. Consistent with AP-42 data, initial results indicate that a significant fraction of the total Cr in the aerosol is in the +6 oxidation state. The fraction of Cr(VI) and total aerosol mass produced by the different arc welding methods varies with the type of welding process used. Self-shielded electrodes that do not use a shield gas, for example, SMAW, produce greater amounts of Cr(VI) per unit mass of electrode consumed. The formation of Cr(VI) from standard electrode wires used for welding mild steel was below the method detection limit after eliminating an artifact in the analytical method used.

  6. ETS-VI multibeam satellite communications systems

    NASA Astrophysics Data System (ADS)

    Kawai, Makoto; Tanaka, Masayoshi; Ohtomo, Isao

    1989-10-01

    The fixed and mobile satellite communications systems of the Japanese Engineering Test Satellite-VI (ETS-VI) are described. The system requirements are outlined along with the system configuration. The ETS-VI multibeam system employs three frequency bands. When used for Ka-band fixed communications, it covers the Japanese main islands with thirteen 0.3-degree-wide spot beam. Four of the beams are active for ETS-VI. When used for S-band mobile communications, five beams cover the area within 200 nautical miles from the Japanese coast. The C-band beam for fixed communications covers the central area of the Japanese main islands with a single beam. The onboard antenna system is described along with the transponders and their associated onboard systems. A discussion of the system technology follows, covering the TDMA transmisssion system, the relay function, rainfall compensation, and the antenna and propagation performance.

  7. The Chrysalis Opens? Photometry from the η Carinae Hubble Space Telescope Treasury Project, 2002-2006

    NASA Astrophysics Data System (ADS)

    Martin, J. C.; Davidson, Kris; Koppelman, M. D.

    2006-12-01

    During the past decade η Car has brightened markedly, possibly indicating a change of state. Here we summarize photometry gathered by the Hubble Space Telescope (HST) as part of the HST Treasury Project on this object. Our data include Space Telescope Imaging Spectrograph (STIS) CCD acquisition images, Advanced Camera for Surveys HRC images in four filters, and synthetic photometry in flux-calibrated STIS spectra. The HST's spatial resolution allows us to examine the central star separate from the bright circumstellar ejecta. Its apparent brightness continued to increase briskly during 2002-2006, especially after the mid-2003 spectroscopic event. If this trend continues, the central star will soon become brighter than its ejecta, quite different from the state that existed only a few years ago. One precedent may be the rapid change observed in 1938-1953. We conjecture that the star's mass-loss rate has been decreasing throughout the past century. This research was conducted as part of the η Car Hubble Space Telescope Treasury project via grant GO-9973 from the Space Telescope Science Institute. HST is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-26555. Some of the data presented in this paper were obtained from the Multimission Archive at the Space Telescope Science Institute (MAST). STScI is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-26555. Support for MAST for non-HST data is provided by the NASA Office of Space Science via grant NAG5-7584 and by other grants and contracts.

  8. 78 FR 13760 - Proposed Collection of Information: Application Form for U.S. Department of the Treasury Stored...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-28

    ... U.S. Department of the Treasury Stored Value Card (SVC) Program AGENCY: Financial Management Service, Fiscal Service, Treasury. ACTION: Notice and request for comments. SUMMARY: The Financial Management... written comments to Financial Management Service, Records and Information Management Branch, Room 135...

  9. 77 FR 67062 - Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-11-08

    ... DEPARTMENT OF THE TREASURY Fiscal Service Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book-Entry System AGENCY: Bureau of the Public Debt, Fiscal... fee schedule applicable to transfers of U.S. Treasury book-entry securities maintained on the National...

  10. 76 FR 68523 - Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-04

    ... DEPARTMENT OF THE TREASURY Fiscal Service Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book-Entry System AGENCY: Bureau of the Public Debt, Fiscal... fee schedule applicable to transfers of U.S. Treasury book-entry securities maintained on the National...

  11. 31 CFR 363.209 - How can I direct that my marketable Treasury security be sold on the open market (Sell Direct ®)?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false How can I direct that my marketable Treasury security be sold on the open market (Sell Direct ®)? 363.209 Section 363.209 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) FISCAL SERVICE, DEPARTMENT OF THE TREASURY...

  12. Vi-da: vitiligo diagnostic assistance mobile application

    NASA Astrophysics Data System (ADS)

    Nugraha, G. A.; Nurhudatiana, A.; Bahana, R.

    2018-03-01

    Vitiligo is a skin disorder in which white patches of depigmentation appear on different parts of the body. Usually, patients come to hospitals or clinics to have their vitiligo conditions assessed. This can be very tiring to the patients, as vitiligo treatments usually take a relatively long period of time, which can range from months to years. To address this challenge, we present in this paper a prototype of an Android-based mobile application called Vi-DA, which stands for Vitiligo Diagnostic Assistance. Vi-DA consists of three subsystems, which are user sign-up subsystem, camera and image analysis subsystem, and progress report subsystem. The mobile application was developed in Java programming language and uses MySQL as the database system. Vi-DA adopts a vitiligo segmentation algorithm to segment input image into normal skin area, vitiligo skin area, and non-skin area. Results showed that Vi-DA gave comparable results to the previous system implemented in Matlab. User acceptance testing results also showed that all respondents agreed on the usefulness of the system and agreed to use Vi-DA again in the future. Vi-DA benefits both dermatologists and patients as not only a computer-aided diagnosis (CAD) tool but also as a smart application that can be used for self-assessment at home.

  13. ViA: a perceptual visualization assistant

    NASA Astrophysics Data System (ADS)

    Healey, Chris G.; St. Amant, Robert; Elhaddad, Mahmoud S.

    2000-05-01

    This paper describes an automated visualized assistant called ViA. ViA is designed to help users construct perceptually optical visualizations to represent, explore, and analyze large, complex, multidimensional datasets. We have approached this problem by studying what is known about the control of human visual attention. By harnessing the low-level human visual system, we can support our dual goals of rapid and accurate visualization. Perceptual guidelines that we have built using psychophysical experiments form the basis for ViA. ViA uses modified mixed-initiative planning algorithms from artificial intelligence to search of perceptually optical data attribute to visual feature mappings. Our perceptual guidelines are integrated into evaluation engines that provide evaluation weights for a given data-feature mapping, and hints on how that mapping might be improved. ViA begins by asking users a set of simple questions about their dataset and the analysis tasks they want to perform. Answers to these questions are used in combination with the evaluation engines to identify and intelligently pursue promising data-feature mappings. The result is an automatically-generated set of mappings that are perceptually salient, but that also respect the context of the dataset and users' preferences about how they want to visualize their data.

  14. 1. Photocopy of drawing (from U.S. Corps of Engineers, Treasury ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. Photocopy of drawing (from U.S. Corps of Engineers, Treasury Department, Washington, D.C., A.B. Young, Architect, 1856) Photographer unknown, Date unknown FRONTISPIECE FOR PLANS OF MARINE HOSPITAL - Marine Hospital, New Orleans, Orleans Parish, LA

  15. 75 FR 67807 - Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-11-03

    ... DEPARTMENT OF THE TREASURY Fiscal Service Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book-Entry System Authority: 31 CFR 357.45. AGENCY: Bureau of the...) is announcing a new fee schedule applicable to transfers of U.S. Treasury book-entry securities...

  16. Cranial mononeuropathy VI

    MedlinePlus

    ... palsy; Cranial nerve VI palsy; Sixth nerve palsy; Neuropathy - sixth nerve ... with: Brain aneurysms Nerve damage from diabetes( diabetic neuropathy ) Gradenigo syndrome (which also causes discharge from the ...

  17. Uranium(VI) Reduction by Anaeromyxobacter dehalogenans Strain 2CP-C

    PubMed Central

    Wu, Qingzhong; Sanford, Robert A.; Löffler, Frank E.

    2006-01-01

    Previous studies demonstrated growth of Anaeromyxobacter dehalogenans strain 2CP-C with acetate or hydrogen as the electron donor and Fe(III), nitrate, nitrite, fumarate, oxygen, or ortho-substituted halophenols as electron acceptors. In this study, we explored and characterized U(VI) reduction by strain 2CP-C. Cell suspensions of fumarate-grown 2CP-C cells reduced U(VI) to U(IV). More-detailed growth studies demonstrated that hydrogen was the required electron donor for U(VI) reduction and could not be replaced by acetate. The addition of nitrate to U(VI)-reducing cultures resulted in a transitory increase in U(VI) concentration, apparently caused by the reoxidation of reduced U(IV), but U(VI) reduction resumed following the consumption of N-oxyanions. Inhibition of U(VI) reduction occurred in cultures amended with Fe(III) citrate, or citrate. In the presence of amorphous Fe(III) oxide, U(VI) reduction proceeded to completion but the U(VI) reduction rates decreased threefold compared to control cultures. Fumarate and 2-chlorophenol had no inhibitory effects on U(VI) reduction, and both electron acceptors were consumed concomitantly with U(VI). Since cocontaminants (e.g., nitrate, halogenated compounds) and bioavailable ferric iron are often encountered at uranium-impacted sites, the metabolic versatility makes Anaeromyxobacter dehalogenans a promising model organism for studying the complex interaction of multiple electron acceptors in U(VI) reduction and immobilization. PMID:16672509

  18. 23 CFR 200.7 - FHWA Title VI policy.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false FHWA Title VI policy. 200.7 Section 200.7 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.7 FHWA Title VI policy. It is the policy of the FHWA to...

  19. 23 CFR 200.7 - FHWA Title VI policy.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 23 Highways 1 2011-04-01 2011-04-01 false FHWA Title VI policy. 200.7 Section 200.7 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.7 FHWA Title VI policy. It is the policy of the FHWA to...

  20. 23 CFR 200.7 - FHWA Title VI policy.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 23 Highways 1 2014-04-01 2014-04-01 false FHWA Title VI policy. 200.7 Section 200.7 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.7 FHWA Title VI policy. It is the policy of the FHWA to...

  1. 23 CFR 200.7 - FHWA Title VI policy.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 23 Highways 1 2013-04-01 2013-04-01 false FHWA Title VI policy. 200.7 Section 200.7 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.7 FHWA Title VI policy. It is the policy of the FHWA to...

  2. 31 CFR 356.4 - What are the book-entry systems in which auctioned Treasury securities may be issued or maintained?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 2 2011-07-01 2011-07-01 false What are the book-entry systems in... BUREAU OF THE PUBLIC DEBT SALE AND ISSUE OF MARKETABLE BOOK-ENTRY TREASURY BILLS, NOTES, AND BONDS... book-entry systems in which auctioned Treasury securities may be issued or maintained? There are three...

  3. 78 FR 66803 - Fee Schedule for the Transfer of U.S. Treasury Book-Entry Securities Held on the National Book...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-06

    ... Transfer of U.S. Treasury Book-Entry Securities Held on the National Book-Entry System AGENCY: Bureau of... (Treasury) is announcing a new fee schedule applicable to transfers of U.S. Treasury book-entry securities maintained on the National Book-Entry System (NBES) that occur on or after January 2, 2014. DATES: Effective...

  4. 31 CFR 356.20 - How does the Treasury determine auction awards?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... and bond issues. We set the interest rate at a 1/8 of one percent increment. If a Treasury inflation-protected securities auction results in a negative or zero yield, the interest rate will be set at zero, and...

  5. 1. COMPARISON OF PLANS, SHOWING KONGENSGADE 6 (see photograph VI50 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. COMPARISON OF PLANS, SHOWING KONGENSGADE 6 (see photograph VI-50 50-2 for elevation), KONGENSGADE 8 (see photograph VI-50-3 for elevation), KONGENSGADE 9 (see photograph VI-50-3 for elevation), KONGENSGADE 17 (see photograph VI-50-5 for elevation), KONGENSGADE 56 (see photograph VI-50-8 for elevation), & KONGENSGADE 57 (see photograph VI-50-9 for elevation) - King Street Area Study, Kongensgade 5-18, 36, 37B, 51-58 (Houses), 5-18, 36-37B, 51-58 King Street, Frederiksted, St. Croix, VI

  6. 29 CFR 1915.1026 - Chromium (VI).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... present from skin or eye contact with chromium (VI), the employer shall provide appropriate personal... clothing and equipment should be laundered or cleaned in a manner that minimizes skin or eye contact with... shall provide change rooms in conformance with 29 CFR 1910.141. Where skin contact with chromium (VI...

  7. 31 CFR 363.28 - Does Public Debt reserve the right to require that any TreasuryDirect ® transaction be conducted...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false Does Public Debt reserve the right to... Provisions Governing Securities Held in TreasuryDirect § 363.28 Does Public Debt reserve the right to require that any TreasuryDirect ® transaction be conducted in paper form? We reserve the right to require any...

  8. Characterization of Amoeba proteus myosin VI immunoanalog.

    PubMed

    Dominik, Magdalena; Kłopocka, Wanda; Pomorski, Paweł; Kocik, Elzbieta; Redowicz, Maria Jolanta

    2005-07-01

    Amoeba proteus, the highly motile free-living unicellular organism, has been widely used as a model to study cell motility. However, molecular mechanisms underlying its unique locomotion and intracellular actin-based-only trafficking remain poorly understood. A search for myosin motors responsible for vesicular transport in these giant cells resulted in detection of 130-kDa protein interacting with several polyclonal antibodies against different tail regions of human and chicken myosin VI. This protein was binding to actin in the ATP-dependent manner, and immunoprecipitated with anti-myosin VI antibodies. In order to characterize its possible functions in vivo, its cellular distribution and colocalization with actin filaments and dynamin II during migration and pinocytosis were examined. In migrating amoebae, myosin VI immunoanalog localized to vesicular structures, particularly within the perinuclear and sub-plasma membrane areas, and colocalized with dynamin II immunoanalog and actin filaments. The colocalization was even more evident in pinocytotic cells as proteins concentrated within pinocytotic pseudopodia. Moreover, dynamin II and myosin VI immunoanalogs cosedimented with actin filaments, and were found on the same isolated vesicles. Blocking endogenous myosin VI immunoanalog with anti-myosin VI antibodies inhibited the rate of pseudopodia protrusion (about 19% decrease) and uroidal retraction (about 28% decrease) but did not affect cell morphology and the manner of cell migration. Treatment with anti-human dynamin II antibodies led to changes in directionality of amebae migration and affected the rate of only uroidal translocation (about 30% inhibition). These results indicate that myosin VI immunoanalog is expressed in protist Amoeba proteus and may be involved in vesicle translocation and cell locomotion.

  9. The panchromatic Hubble Andromeda Treasury. VI. The reliability of far-ultraviolet flux as a star formation tracer on subkiloparsec scales

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simones, Jacob E.; Skillman, Evan D.; Weisz, Daniel R.

    We have used optical observations of resolved stars from the Panchromatic Hubble Andromeda Treasury to measure the recent (<500 Myr) star formation histories (SFHs) of 33 far-UV (FUV)-bright regions in M31. The region areas ranged from ∼10{sup 4} to 10{sup 6} pc{sup 2}, which allowed us to test the reliability of FUV flux as a tracer of recent star formation on subkiloparsec scales. The star formation rates (SFRs) derived from the extinction-corrected observed FUV fluxes were, on average, consistent with the 100 Myr mean SFRs of the SFHs to within the 1σ scatter. Overall, the scatter was larger than themore » uncertainties in the SFRs and particularly evident among the smallest regions. The scatter was consistent with an even combination of discrete sampling of the initial mass function and high variability in the SFHs. This result demonstrates the importance of satisfying both the full-IMF and the constant-SFR assumptions for obtaining precise SFR estimates from FUV flux. Assuming a robust FUV extinction correction, we estimate that a factor of 2.5 uncertainty can be expected in FUV-based SFRs for regions smaller than 10{sup 5} pc{sup 2} or a few hundred parsecs. We also examined ages and masses derived from UV flux under the common assumption that the regions are simple stellar populations (SSPs). The SFHs showed that most of the regions are not SSPs, and the age and mass estimates were correspondingly discrepant from the SFHs. For those regions with SSP-like SFHs, we found mean discrepancies of 10 Myr in age and a factor of 3-4 in mass. It was not possible to distinguish the SSP-like regions from the others based on integrated FUV flux.« less

  10. 40 CFR Appendix Vi to Part 266 - Stack Plume Rise

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Stack Plume Rise VI Appendix VI to Part 266 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... FACILITIES Pt. 266, App. VI Appendix VI to Part 266—Stack Plume Rise [Estimated Plume Rise (in Meters) Based...

  11. 19 CFR Annex Vi to Part 351 - Countervailing Investigations Timeline

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 19 Customs Duties 3 2010-04-01 2010-04-01 false Countervailing Investigations Timeline VI Annex VI to Part 351 Customs Duties INTERNATIONAL TRADE ADMINISTRATION, DEPARTMENT OF COMMERCE ANTIDUMPING AND COUNTERVAILING DUTIES Pt. 351, Annex VI Annex VI to Part 351—Countervailing Investigations Timeline ER19MY97.000 ...

  12. 19 CFR Annex Vi to Part 351 - Countervailing Investigations Timeline

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 19 Customs Duties 3 2013-04-01 2013-04-01 false Countervailing Investigations Timeline VI Annex VI to Part 351 Customs Duties INTERNATIONAL TRADE ADMINISTRATION, DEPARTMENT OF COMMERCE ANTIDUMPING AND COUNTERVAILING DUTIES Pt. 351, Annex VI Annex VI to Part 351—Countervailing Investigations Timeline ER19MY97.000 ...

  13. 19 CFR Annex Vi to Part 351 - Countervailing Investigations Timeline

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 19 Customs Duties 3 2014-04-01 2014-04-01 false Countervailing Investigations Timeline VI Annex VI to Part 351 Customs Duties INTERNATIONAL TRADE ADMINISTRATION, DEPARTMENT OF COMMERCE ANTIDUMPING AND COUNTERVAILING DUTIES Pt. 351, Annex VI Annex VI to Part 351—Countervailing Investigations Timeline ER19MY97.000 ...

  14. 19 CFR Annex Vi to Part 351 - Countervailing Investigations Timeline

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 19 Customs Duties 3 2012-04-01 2012-04-01 false Countervailing Investigations Timeline VI Annex VI to Part 351 Customs Duties INTERNATIONAL TRADE ADMINISTRATION, DEPARTMENT OF COMMERCE ANTIDUMPING AND COUNTERVAILING DUTIES Pt. 351, Annex VI Annex VI to Part 351—Countervailing Investigations Timeline ER19MY97.000 ...

  15. 19 CFR Annex Vi to Part 351 - Countervailing Investigations Timeline

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 19 Customs Duties 3 2011-04-01 2011-04-01 false Countervailing Investigations Timeline VI Annex VI to Part 351 Customs Duties INTERNATIONAL TRADE ADMINISTRATION, DEPARTMENT OF COMMERCE ANTIDUMPING AND COUNTERVAILING DUTIES Pt. 351, Annex VI Annex VI to Part 351—Countervailing Investigations Timeline ER19MY97.000 ...

  16. 40 CFR Appendix Vi to Part 266 - Stack Plume Rise

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Stack Plume Rise VI Appendix VI to Part 266 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... FACILITIES Pt. 266, App. VI Appendix VI to Part 266—Stack Plume Rise [Estimated Plume Rise (in Meters) Based...

  17. Dynamics of Chromium(VI) Removal from Drinking Water by Iron Electrocoagulation.

    PubMed

    Pan, Chao; Troyer, Lyndsay D; Catalano, Jeffrey G; Giammar, Daniel E

    2016-12-20

    The potential for new U.S. regulations for Cr(VI) in drinking water have spurred strong interests in improving technologies for Cr(VI) removal. This study examined iron electrocoagulation for Cr(VI) removal at conditions directly relevant to drinking water treatment. Cr(VI) is chemically reduced to less soluble Cr(III) species by the Fe(II) produced from an iron anode, and XANES spectra indicate that the Cr is entirely Cr(III) in solid-phases produced in electrocoagulation. The dynamics of Cr(VI) removal in electrocoagulation at pH 6 and pH 8 at both oxic and anoxic conditions can be described by a new model that incorporates Fe(II) release from the anode and heterogeneous and homogeneous reduction of Cr(VI) by Fe(II). Heterogeneous Cr(VI) reduction by adsorbed Fe(II) was critical to interpreting Cr(VI) removal at pH 6, and the Fe- and Cr-containing EC product was found to catalyze the redox reaction. Dissolved oxygen (DO) did not observably inhibit Cr(VI) removal because Fe(II) reacts with DO more slowly than it does with Cr(VI), and Cr(VI) removal was faster at higher pH. Even in the presence of common groundwater solutes, iron electrocoagulation lowered Cr(VI) concentrations to levels well below California's 10 μg/L.

  18. 76 FR 65107 - Recovery of Delinquent Debts-Treasury Offset Program Enhancements

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-20

    ... SOCIAL SECURITY ADMINISTRATION 20 CFR Parts 404, 408, 416, and 422 [Docket No. SSA-2010-0010] RIN 0960-AH19 Recovery of Delinquent Debts--Treasury Offset Program Enhancements AGENCY: Social Security... Recovery Policy, Social Security Administration, 6401 Security Boulevard, Baltimore, MD 21235-6401, (410...

  19. Kinetics of microbial reduction of Solid phase U(VI).

    PubMed

    Liu, Chongxuan; Jeon, Byong-Hun; Zachara, John M; Wang, Zheming; Dohnalkova, Alice; Fredrickson, James K

    2006-10-15

    Sodium boltwoodite (NaUO2SiO3OH x 1.5 H2O) was used to assess the kinetics of microbial reduction of solid-phase U(VI) by a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. The bioreduction kinetics was studied with Na-boltwoodite in suspension or within alginate beads in a nongrowth medium with lactate as electron donor at pH 6.8 buffered with PIPES. Concentrations of U(VI)tot and cell number were varied to evaluate the coupling of U(VI) dissolution, diffusion, and microbial activity. Microscopic and spectroscopic analyses with transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and laser-induced fluorescence spectroscopy (LIFS) collectively indicated that solid-phase U(VI) was first dissolved and diffused out of grain interiors before it was reduced on bacterial surfaces and/or within the periplasm. The kinetics of solid-phase U(VI) bioreduction was well described by a coupled model of bicarbonate-promoted dissolution of Na-boltwoodite, intragrain uranyl diffusion, and Monod type bioreduction kinetics with respect to dissolved U(VI) concentration. The results demonstrated that microbial reduction of solid-phase U(VI) is controlled by coupled biological, chemical, and physical processes.

  20. Influence of calcium on microbial reduction of solid phase uranium(VI).

    PubMed

    Liu, Chongxuan; Jeon, Byong-Hun; Zachara, John M; Wang, Zheming

    2007-08-15

    The effect of calcium on the dissolution and microbial reduction of a representative solid phase uranyl [U(VI)], sodium boltwoodite (NaUO(2)SiO(3)OH . 1.5H(2)O), was investigated to evaluate the rate-limiting step of microbial reduction of the solid phase U(VI). Microbial reduction experiments were performed in a culture of a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1, in a bicarbonate medium with lactate as electron donor at pH 6.8 buffered with PIPES. Calcium increased the rate of Na-boltwoodite dissolution and U(VI) bioavailability by increasing its solubility through the formation of a ternary aqueous calcium-uranyl-carbonate species. The ternary species, however, decreased the rates of microbial reduction of aqueous U(VI). Laser-induced fluorescence spectroscopy (LIFS) and transmission electron microscopy (TEM) collectively revealed that microbial reduction of solid phase U(VI) was a sequentially coupled process of Na-boltwoodite dissolution, U(VI) aqueous speciation, and microbial reduction of dissolved U(VI) to U(IV) that accumulated on bacterial surfaces/periplasm. Under studied experimental conditions, the overall rate of microbial reduction of solid phase U(VI) was limited by U(VI) dissolution reactions in solutions without calcium and limited by microbial reduction in solutions with calcium. Generally, the overall rate of microbial reduction of solid phase U(VI) was determined by the coupling of solid phase U(VI) dissolution, U(VI) aqueous speciation, and microbial reduction of dissolved U(VI) that were all affected by calcium. (c) 2007 Wiley Periodicals, Inc.

  1. 40 CFR Appendixes Vi-Vii to Part 600 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false [Reserved] VI Appendixes VI-VII to Part 600 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Appendixes VI-VII to Part 600 [Reserved] ...

  2. 40 CFR Appendixes Vi-Vii to Part 600 - [Reserved

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 30 2011-07-01 2011-07-01 false [Reserved] VI Appendixes VI-VII to Part 600 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Appendixes VI-VII to Part 600 [Reserved] ...

  3. Lack of Collagen VI Promotes Wound-Induced Hair Growth.

    PubMed

    Chen, Peiwen; Cescon, Matilde; Bonaldo, Paolo

    2015-10-01

    Collagen VI is an extracellular matrix molecule that is abundantly expressed in the skin. However, the role of collagen VI in hair follicle growth is unknown. Here, we show that collagen VI is strongly deposited in hair follicles, and is markedly upregulated by skin wounding. Lack of collagen VI in Col6a1(-/-) mice delays hair cycling and growth under physiological conditions, but promotes wound-induced hair regrowth without affecting skin regeneration. Conversely, addition of purified collagen VI rescues the abnormal wound-induced hair regrowth in Col6a1(-/-) mice. Mechanistic studies revealed that the increased wound-induced hair regrowth of Col6a1(-/-) mice is triggered by activation of the Wnt/β-catenin signaling pathway, and is abolished by inhibition of this pathway. These findings highlight the essential relationships between extracellular matrix (ECM) and hair follicle regeneration, and suggest that collagen VI could be a potential therapeutic target for hair loss and other skin-related diseases.

  4. 31 CFR Appendix to Part 321 - Appendix to Department of the Treasury Circular No. 750, Fourth Revision

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... following publications: (a) Offering circulars. Department of the Treasury Circulars, Public Debt Series Nos. 1-80 (31 CFR part 351, Series EE bonds), 2-80 (31 CFR part 352, Series HH bonds), 1-98 (31 CFR part 359, Series I bonds), and 3-67 (31 CFR part 342, savings notes), and Department of the Treasury...

  5. Trigonal Cu2-II-Sn-VI4 (II = Ba, Sr and VI = S, Se) quaternary compounds for earth-abundant photovoltaics.

    PubMed

    Hong, Feng; Lin, Wenjun; Meng, Weiwei; Yan, Yanfa

    2016-02-14

    We propose trigonal Cu2-II-Sn-VI4 (II = Ba, Sr and VI = S, Se) quaternary compounds for earth-abundant solar cell applications. Through density functional theory calculations, we show that these compounds exhibit similar electronic and optical properties to kesterite Cu2ZnSnS4 (CZTS): high optical absorption with band gaps suitable for efficient single-junction solar cell applications. However, the trigonal Cu2-II-Sn-VI4 compounds exhibit defect properties more suitable for photovoltaic applications than those of CZTS. In CZTS, the dominant defects are the deep acceptors, Cu substitutions on Zn sites, which cause non-radiative recombination and limit the open-circuit voltages of CZTS solar cells. On the contrary, the dominant defects in trigonal Cu2-II-Sn-VI4 are the shallow acceptors, Cu vacancies, similar to those in CuInSe2. Our results suggest that the trigonal Cu2-II-Sn-VI4 quaternary compounds could be promising candidates for efficient earth-abundant thin-film solar cell and photoeletrochemical water-splitting applications.

  6. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    NASA Astrophysics Data System (ADS)

    Uygun, Murat; Feyzioğlu, Esra; Özçalışkan, Emir; Caka, Müşerref; Ergen, Aygen; Akgöl, Sinan; Denizli, Adil

    2013-08-01

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m2/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.

  7. Rheology of water ices V and VI

    USGS Publications Warehouse

    Durham, W.B.; Stern, L.A.; Kirby, S.H.

    1996-01-01

    We have measured the mechanical strength (??) of pure water ices V and VI under steady state deformation conditions. Constant displacement rate compressional tests were conducted in a gas apparatus at confining pressures from 400 250 K. Ices V and VI are thus Theologically distinct but by coincidence have approximately the same strength under the conditions chosen for these experiments. To avoid misidentification, these tests are therefore accompanied by careful observations of the occurrences and characteristics of phase changes. One sample each of ice V and VI was quenched at pressure to metastably retain the high-pressure phase and the acquired deformation microstructures; X ray diffraction analysis of these samples confirmed the phase identification. Surface replicas of the deformed and quenched samples suggest that ice V probably deforms largely by dislocation creep, while ice VI deforms by a more complicated process involving substantial grain size reduction through recrystallization.

  8. Hydrocarbon oxidation by beta-halogenated dioxoruthenium(VI) porphyrin complexes: effect of reduction potential (RuVI/V) and C-H bond-dissociation energy on rate constants.

    PubMed

    Che, Chi-Ming; Zhang, Jun-Long; Zhang, Rui; Huang, Jie-Sheng; Lai, Tat-Shing; Tsui, Wai-Man; Zhou, Xiang-Ge; Zhou, Zhong-Yuan; Zhu, Nianyong; Chang, Chi Kwong

    2005-11-18

    beta-Halogenated dioxoruthenium(VI) porphyrin complexes [Ru(VI)(F(28)-tpp)O(2)] [F(28)-tpp=2,3,7,8,12,13, 17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato(2-)] and [Ru(VI)(beta-Br(8)-tmp)O(2)] [beta-Br(8)-tmp=2,3,7,8,12,13,17,18-octabromo-5,10,15,20- tetrakis(2,4,6-trimethylphenyl)porphyrinato(2-)] were prepared from reactions of [Ru(II)(por)(CO)] [por=porphyrinato(2-)] with m-chloroperoxybenzoic acid in CH(2)Cl(2). Reactions of [Ru(VI)(por)O(2)] with excess PPh(3) in CH(2)Cl(2) gave [Ru(II)(F(20)-tpp)(PPh(3))(2)] [F(20)-tpp=5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato(2-)] and [Ru(II)(F(28)-tpp)(PPh(3))(2)]. The structures of [Ru(II)(por)(CO)(H(2)O)] and [Ru(II)(por)(PPh(3))(2)] (por=F(20)-tpp, F(28)-tpp) were determined by X-ray crystallography, revealing the effect of beta-fluorination of the porphyrin ligand on the coordination of axial ligands to ruthenium atom. The X-ray crystal structure of [Ru(VI)(F(20)-tpp)O(2)] shows a Ru=O bond length of 1.718(3) A. Electrochemical reduction of [Ru(VI)(por)O(2)] (Ru(VI) to Ru(V)) is irreversible or quasi-reversible, with the E(p,c)(Ru(VI/V)) spanning -0.31 to -1.15 V versus Cp(2)Fe(+/0). Kinetic studies were performed for the reactions of various [Ru(VI)(por)O(2)], including [Ru(VI)(F(28)-tpp)O(2)] and [Ru(VI)(beta-Br(8)-tmp)O(2)], with para-substituted styrenes p-X-C(6)H(4)CH=CH(2) (X=H, F, Cl, Me, MeO), cis- and trans-beta-methylstyrene, cyclohexene, norbornene, ethylbenzene, cumene, 9,10-dihydroanthracene, xanthene, and fluorene. The second-order rate constants (k(2)) obtained for the hydrocarbon oxidations by [Ru(VI)(F(28)-tpp)O(2)] are up to 28-fold larger than by [Ru(VI)(F(20)-tpp)O(2)]. Dual-parameter Hammett correlation implies that the styrene oxidation by [Ru(VI)(F(28)-tpp)O(2)] should involve rate-limiting generation of a benzylic radical intermediate, and the spin delocalization effect is more important than the polar effect. The k(2) values for the oxidation of styrene and

  9. 31 CFR 356.4 - What are the book-entry systems in which auctioned Treasury securities may be issued?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... in which auctioned Treasury securities may be issued? There are three book-entry securities systems... marketable Treasury securities. We maintain and transfer securities in these three book-entry systems at... inflation. Securities may be transferred from one system to the other, unless the securities are not...

  10. Oxidation of trimethoprim by ferrate(VI): kinetics, products, and antibacterial activity.

    PubMed

    Anquandah, George A K; Sharma, Virender K; Knight, D Andrew; Batchu, Sudha Rani; Gardinali, Piero R

    2011-12-15

    Kinetics, stoichiometry, and products of the oxidation of trimethoprim (TMP), one of the most commonly detected antibacterial agents in surface waters and municipal wastewaters, by ferrate(VI) (Fe(VI)) were determined. The pH dependent second-order rate constants of the reactions of Fe(VI) with TMP were examined using acid-base properties of Fe(VI) and TMP. The kinetics of reactions of diaminopyrimidine (DAP) and trimethoxytoluene (TMT) with Fe(VI) were also determined to understand the reactivity of Fe(VI) with TMP. Oxidation products of the reactions of Fe(VI) with TMP and DAP were identified by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Reaction pathways of oxidation of TMP by Fe(VI) are proposed to demonstrate the cleavage of the TMP molecule to ultimately result in 3,4,5,-trimethoxybenzaldehyde and 2,4-dinitropyrimidine as among the final identified products. The oxidized products mixture exhibited no antibacterial activity against E. coli after complete consumption of TMP. Removal of TMP in the secondary effluent by Fe(VI) was achieved.

  11. Kinetics of Microbial Reduction of Solid Phase U(VI)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Chongxuan; Jeon, Byong Hun; Zachara, John M.

    2006-10-01

    Sodium boltwoodite (NaUO2SiO3OH ?1.5H2O) was used to assess the kinetics of microbial reduction of solid phase U(VI) by a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. The bioreduction kinetics was studied with Na-boltwoodite in suspension or within alginate beads. Concentrations of U(VI)tot and cell number were varied to evaluate the coupling of U(VI) dissolution, diffusion, and microbial activity. Batch experiments were performed in a non-growth medium with lactate as electron donor at pH 6.8 buffered with PIPES. Microscopic and spectroscopic analyses with transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and laser-induced fluorescence spectroscopy (LIFS) collectively indicated that solidmore » phase U(VI) was first dissolved and diffused out of grain interiors before it was reduced on bacterial surfaces and/or within the periplasm. The kinetics of solid phase U(VI) bioreduction was well described by a coupled model of bicarbonate-promoted dissolution of Na-boltwoodite, intraparticle uranyl diffusion, and Monod type bioreduction kinetics with respect to dissolved U(VI) concentration. The results demonstrated the intimate coupling of biological, chemical, and physical processes in microbial reduction of solid phase U(VI).« less

  12. Design, baseline characteristics, and early findings of the MPS VI (mucopolysaccharidosis VI) Clinical Surveillance Program (CSP).

    PubMed

    Hendriksz, Christian J; Giugliani, Roberto; Harmatz, Paul; Lampe, Christina; Martins, Ana Maria; Pastores, Gregory M; Steiner, Robert D; Leão Teles, Elisa; Valayannopoulos, Vassili

    2013-03-01

    To outline the design, baseline data, and 5-year follow-up data of patients with mucopolysaccharidosis (MPS) VI enrolled in the Clinical Surveillance Program (CSP), a voluntary, multinational, observational program. The MPS VI CSP was opened in 2005 to collect, for at least 15 years, observational data from standard clinical and laboratory assessments of patients with MPS VI. Baseline and follow-up data are documented by participating physicians in electronic case report forms. Between September 2005 and March 2010 the CSP enrolled 132 patients, including 123 who received enzyme replacement therapy (ERT) with galsulfase. Median age at enrolment was 13 years (range 1-59). Mean baseline data showed impaired growth, hepatosplenomegaly, and reduced endurance and pulmonary function. The most common findings were heart valve disease (90%), reduced visual acuity (79%), impaired hearing (59%), and hepatosplenomegaly (54%). Follow-up data up to 5 years in patients with pre- and post-ERT measurements showed a decrease in urinary glycosaminoglycans and increases in height and weight in patients <16 years and suggested reductions in liver and spleen size and improvements in endurance and pulmonary function after ERT was started. Vision, hearing, and cardiac function were unchanged. Safety data were in line with previous reports. The CSP represents the largest cross-sectional study of MPS VI to date. This first report provides information on the design and implementation of the program and population statistics for several clinical variables in patients with MPS VI. Data collected over 5 years suggest that ERT provides clinical benefit and is well-tolerated with no new safety concerns.

  13. 7 CFR 1951.136 - Procedures for Department of Treasury offset and cross-servicing for the Rural Housing Service...

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ...-Servicing (Cross-Servicing) Program, which centralizes all Government debt collection actions. A borrower... debts which are over 180 days delinquent to the Secretary of the Treasury for collection by centralized... the debt is reported to Treasury. The notice will include: (1) The nature and amount of the debt, the...

  14. 76 FR 75781 - Treasury Inflation-Protected Securities Issued at a Premium

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-12-05

    ... Services and Enforcement. Emily S. McMahon, Acting Assistant Secretary of the Treasury (Tax Policy). [FR... principal amount of the security times the number of complete years to the security's maturity). In Notice... Administrative Procedure Act (5 U.S.C. chapter 5) does not apply to these regulations, and because the...

  15. 41 CFR 102-73.220 - What types of special purpose space may the Department of the Treasury lease?

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... purpose space may the Department of the Treasury lease? 102-73.220 Section 102-73.220 Public Contracts and... REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Lease Special Purpose Space Delegations § 102-73.220 What types of special purpose space may the Department of the Treasury lease? The...

  16. 41 CFR 102-73.220 - What types of special purpose space may the Department of the Treasury lease?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... purpose space may the Department of the Treasury lease? 102-73.220 Section 102-73.220 Public Contracts and... REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Lease Special Purpose Space Delegations § 102-73.220 What types of special purpose space may the Department of the Treasury lease? The...

  17. 41 CFR 102-73.220 - What types of special purpose space may the Department of the Treasury lease?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... purpose space may the Department of the Treasury lease? 102-73.220 Section 102-73.220 Public Contracts and... REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Lease Special Purpose Space Delegations § 102-73.220 What types of special purpose space may the Department of the Treasury lease? The...

  18. 41 CFR 102-73.220 - What types of special purpose space may the Department of the Treasury lease?

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... purpose space may the Department of the Treasury lease? 102-73.220 Section 102-73.220 Public Contracts and... REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Lease Special Purpose Space Delegations § 102-73.220 What types of special purpose space may the Department of the Treasury lease? The...

  19. 41 CFR 102-73.220 - What types of special purpose space may the Department of the Treasury lease?

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... purpose space may the Department of the Treasury lease? 102-73.220 Section 102-73.220 Public Contracts and... REGULATION REAL PROPERTY 73-REAL ESTATE ACQUISITION Acquisition by Lease Special Purpose Space Delegations § 102-73.220 What types of special purpose space may the Department of the Treasury lease? The...

  20. 31 CFR 5.10 - How will Treasury entities use administrative offset (offset of non-tax Federal payments) to...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Offset Program. (1) In most cases, the Financial Management Service uses the Treasury Offset Program to... transferred to the Financial Management Service under § 5.9 of this part, Treasury entities will refer any... Management Service, in writing, that the debt is valid, delinquent, legally enforceable, and that there are...

  1. Modelling biological Cr(VI) reduction in aquifer microcosm column systems.

    PubMed

    Molokwane, Pulane E; Chirwa, Evans M N

    2013-01-01

    Several chrome processing facilities in South Africa release hexavalent chromium (Cr(VI)) into groundwater resources. Pump-and-treat remediation processes have been implemented at some of the sites but have not been successful in reducing contamination levels. The current study is aimed at developing an environmentally friendly, cost-effective and self-sustained biological method to curb the spread of chromium at the contaminated sites. An indigenous Cr(VI)-reducing mixed culture of bacteria was demonstrated to reduce high levels of Cr(VI) in laboratory samples. The effect of Cr(VI) on the removal rate was evaluated at concentrations up to 400 mg/L. Following the detailed evaluation of fundamental processes for biological Cr(VI) reduction, a predictive model for Cr(VI) breakthrough through aquifer microcosm reactors was developed. The reaction rate in batch followed non-competitive rate kinetics with a Cr(VI) inhibition threshold concentration of approximately 99 mg/L. This study evaluates the application of the kinetic parameters determined in the batch reactors to the continuous flow process. The model developed from advection-reaction rate kinetics in a porous media fitted best the effluent Cr(VI) concentration. The model was also used to elucidate the logistic nature of biomass growth in the reactor systems.

  2. Diverse functions of myosin VI elucidated by an isoform-specific α-helix domain.

    PubMed

    Wollscheid, Hans-Peter; Biancospino, Matteo; He, Fahu; Magistrati, Elisa; Molteni, Erika; Lupia, Michela; Soffientini, Paolo; Rottner, Klemens; Cavallaro, Ugo; Pozzoli, Uberto; Mapelli, Marina; Walters, Kylie J; Polo, Simona

    2016-04-01

    Myosin VI functions in endocytosis and cell motility. Alternative splicing of myosin VI mRNA generates two distinct isoform types, myosin VI(short) and myosin VI(long), which differ in the C-terminal region. Their physiological and pathological roles remain unknown. Here we identified an isoform-specific regulatory helix, named the α2-linker, that defines specific conformations and hence determines the target selectivity of human myosin VI. The presence of the α2-linker structurally defines a new clathrin-binding domain that is unique to myosin VI(long) and masks the known RRL interaction motif. This finding is relevant to ovarian cancer, in which alternative myosin VI splicing is aberrantly regulated, and exon skipping dictates cell addiction to myosin VI(short) in tumor-cell migration. The RRL interactor optineurin contributes to this process by selectively binding myosin VI(short). Thus, the α2-linker acts like a molecular switch that assigns myosin VI to distinct endocytic (myosin VI(long)) or migratory (myosin VI(short)) functional roles.

  3. 32 CFR 2003.6 - Voting (Article VI).

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 32 National Defense 6 2014-07-01 2014-07-01 false Voting (Article VI). 2003.6 Section 2003.6 National Defense Other Regulations Relating to National Defense INFORMATION SECURITY OVERSIGHT OFFICE...) BYLAWS, RULES, AND APPEAL PROCEDURES Bylaws § 2003.6 Voting (Article VI). (a) Motions. When the Panel is...

  4. 32 CFR 2003.6 - Voting (Article VI).

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 32 National Defense 6 2013-07-01 2013-07-01 false Voting (Article VI). 2003.6 Section 2003.6 National Defense Other Regulations Relating to National Defense INFORMATION SECURITY OVERSIGHT OFFICE...) BYLAWS, RULES, AND APPEAL PROCEDURES Bylaws § 2003.6 Voting (Article VI). (a) Motions. When the Panel is...

  5. Distribution and Kinematics of O VI in the Galactic Halo

    NASA Astrophysics Data System (ADS)

    Savage, B. D.; Sembach, K. R.; Wakker, B. P.; Richter, P.; Meade, M.; Jenkins, E. B.; Shull, J. M.; Moos, H. W.; Sonneborn, G.

    2003-05-01

    Far-Ultraviolet Spectroscopic Explorer (FUSE) spectra of 100 extragalactic objects and two distant halo stars are analyzed to obtain measures of O VI λλ1031.93, 1037.62 absorption along paths through the Milky Way thick disk/halo. Strong O VI absorption over the velocity range from -100 to 100 km s-1 reveals a widespread but highly irregular distribution of O VI, implying the existence of substantial amounts of hot gas with T~3×105 K in the Milky Way thick disk/halo. The integrated column density, log[N(O VI) cm-2], ranges from 13.85 to 14.78 with an average value of 14.38 and a standard deviation of 0.18. Large irregularities in the gas distribution are found to be similar over angular scales extending from <1° to 180°, implying a considerable amount of small- and large-scale structure in the absorbing gas. The overall distribution of O VI is not well described by a symmetrical plane-parallel layer of patchy O VI absorption. The simplest departure from such a model that provides a reasonable fit to the observations is a plane-parallel patchy absorbing layer with an average O VI midplane density of n0(O VI)=1.7×10-8 cm-3, a scale height of ~2.3 kpc, and a ~0.25 dex excess of O VI in the northern Galactic polar region. The distribution of O VI over the sky is poorly correlated with other tracers of gas in the halo, including low- and intermediate-velocity H I, Hα emission from the warm ionized gas at ~104 K, and hot X-ray-emitting gas at ~106 K. The O VI has an average velocity dispersion, b~60 km s-1, and standard deviation of 15 km s-1. Thermal broadening alone cannot explain the large observed profile widths. The average O VI absorption velocities toward high-latitude objects (|b|>45deg) range from -46 to 82 km s-1, with a high-latitude sample average of 0 km s-1 and a standard deviation of 21 km s-1. High positive velocity O VI absorbing wings extending from ~100 to ~250 km s-1 observed along 21 lines of sight may be tracing the flow of O VI into the halo

  6. Degradation of chloramphenicol by potassium ferrate (VI) oxidation: kinetics and products.

    PubMed

    Zhou, Jia-Heng; Chen, Kai-Bo; Hong, Qian-Kun; Zeng, Fan-Cheng; Wang, Hong-Yu

    2017-04-01

    The oxidation of chloramphenicol (CAP) by potassium ferrate (VI) in test solution was studied in this paper. A series of jar tests were performed at bench scale with pH of 5-9 and molar ratio [VI/CAP] of 16.3:1-81.6:1. Results showed that raising VI dose could improve the treatment performance and the influence of solution pH was significant. VI is more reactive in neutral conditions, presenting the highest removal efficiency of CAP. The rate law for the oxidation of CAP by VI was first order with respect to each reactant, yielding an overall second-order reaction. Furthermore, five oxidation products were observed during CAP oxidation by VI. Results revealed that VI attacked the amide group of CAP, leading to the cleavage of the group, while benzene ring remained intact.

  7. Stabilization of Cr(VI) from fine ferrochrome dust using exfoliated vermiculite.

    PubMed

    Mulange Wa Mulange, Delphin; Garbers-Craig, Andrie Mariana

    2012-07-15

    This study proved that vermiculite, a natural occurring mineral, can effectively remove and stabilize Cr(VI) from fine ferrochrome dust leachate. Batch adsorption studies were carried out to determine the effect of pH, contact time and adsorbent dose on the removal of Cr(VI). The process was found to be highly pH dependent. The optimum conditions for the Cr(VI) removal are at a pH of 1.5, contact time of 2h and adsorbent dose of 10gL(-1). The stability of the Cr(VI)-loaded vermiculite remained unchanged after 12 months, when the vermiculite was evaluated with the ASTM and TCLP Cr(VI) leach methods. However, Cr(VI) desorption did take place when the Acid Rain Test was used. The adsorption kinetic data fits the pseudo-second order model, while the equilibrium data of Cr(VI) adsorption onto vermiculite are best described by the Langmuir isotherm. The presence of hydrobiotite and biotite in the industrial vermiculite slightly decreased the degree of adsorption of Cr(VI). Copyright © 2012 Elsevier B.V. All rights reserved.

  8. 36 CFR 1201.40 - Which debts can NARA refer to the Treasury for collection by offsetting tax refunds?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Refund Offset § 1201.40 Which debts can NARA refer to the Treasury for collection by offsetting tax... reduce a tax refund by the amount of a past-due, legally enforceable debt owed to a Federal agency. (b) For purposes of this section, a past-due, legally enforceable debt referrable to the Treasury for tax...

  9. Cranial nerve VI palsy after dural-arachnoid puncture.

    PubMed

    Hofer, Jennifer E; Scavone, Barbara M

    2015-03-01

    In this article, we provide a literature review of cranial nerve (CN) VI injury after dural-arachnoid puncture. CN VI injury is rare and ranges in severity from diplopia to complete lateral rectus palsy with deviated gaze. The proposed mechanism of injury is cerebrospinal fluid leakage causing intracranial hypotension and downward displacement of the brainstem. This results in traction on CN VI leading to stretch and neural demyelination. Symptoms may present 1 day to 3 weeks after dural-arachnoid puncture and typically are associated with a postdural puncture (spinal) headache. Resolution of symptoms may take weeks to months. Use of small-gauge, noncutting spinal needles may decrease the risk of intracranial hypotension and subsequent CN VI injury. When ocular symptoms are present, early administration of an epidural blood patch may decrease morbidity or prevent progression of ocular symptoms.

  10. Vi-CRM 197 as a new conjugate vaccine against Salmonella Typhi.

    PubMed

    Micoli, F; Rondini, S; Pisoni, I; Proietti, D; Berti, F; Costantino, P; Rappuoli, R; Szu, S; Saul, A; Martin, L B

    2011-01-17

    An efficacious, low cost vaccine against typhoid fever, especially for young children, would make a major impact on disease burden in developing countries. The virulence capsular polysaccharide of Salmonella Typhi (Vi) coupled to recombinant mutant Pseudomonas aeruginosa exoprotein A (Vi-rEPA) has been shown to be highly efficacious. We investigated the use of carrier proteins included in infant vaccines, standardized the conjugation process and developed key assays required for routine lot release at production scale. Vi from a BSL1 organism, Citrobacter freundii, strain WR7011, was used as an alternative to Vi from S. Typhi. We showed that Vi conjugated to CRM(197), a non-toxic mutant of diphtheria toxin, widely used in commercial vaccines, was produced at high yield. Vi-CRM(197) proved immunogenic in animal studies, even without adjuvant. Thus, Vi-CRM(197) appears to be a suitable candidate for the development of a commercially viable, effective typhoid vaccine for developing countries. Copyright © 2010 Elsevier Ltd. All rights reserved.

  11. 76 FR 16038 - Proposed Collection; Comment Request for Prepaid Card Marketing Customer Survey, CS-10-251.

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-22

    ... of social marketing. Social marketing principles and practices apply marketing principles to social... Prepaid Card Marketing Customer Survey, CS-10-251. AGENCY: Internal Revenue Service (IRS), Treasury..., the IRS is soliciting comments concerning Prepaid Card Marketing Customer Survey, CS-10-251 DATES...

  12. Forensic investigation of a chromium(VI) groundwater plume in Thiva, Greece.

    PubMed

    Panagiotakis, I; Dermatas, D; Vatseris, C; Chrysochoou, M; Papassiopi, N; Xenidis, A; Vaxevanidou, K

    2015-01-08

    A forensic investigation was conducted with the aim of decoupling the contribution of geogenic and anthropogenic Cr(VI) sources in the wider area of Thiva. Groundwater and topsoil samples were collected from two Cr(VI) groundwater plumes of 160 μg/L and 75 μg/L. A series of evidence support the view that the origin of Cr(VI) detected in groundwater is mainly geogenic. These are: (a) the presence of Cr in topsoil of the wider area, (b) the moderate Cr(VI) groundwater concentrations, (c) the high Ni levels within the Cr(VI) plumes, (d) the predominance of Mn(IV), which is a prerequisite for Cr(III) oxidation to Cr(VI), and (e) the absence of co-contaminants. The present study also revealed that, although both Cr(VI) plumes are clearly of geogenic origin, the plume with the elevated Cr(VI) values, in the north of Thiva town, exhibits also an anthropogenic component, which can potentially be attributed to the alkaline environment associated with the old uncontrolled landfill of Thiva and the industrial cluster located in this area. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. 25 CFR 513.20 - What debts can the Commission refer to Treasury for collection by administrative and tax refund...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... COMMISSION, DEPARTMENT OF THE INTERIOR GENERAL PROVISIONS DEBT COLLECTION Administrative and Tax Refund Offset § 513.20 What debts can the Commission refer to Treasury for collection by administrative and tax... person to the Treasury for administrative and tax refund offset if the debt: (1) Has been delinquent for...

  14. Influence of Calcium on Microbial Reduction of Solid Phase Uranium (VI)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Chongxuan; Jeon, Byong-Hun; Zachara, John M.

    2007-06-27

    The effect of calcium on microbial reduction of a solid phase U(VI), sodium boltwoodite (NaUO2SiO3OH ∙1.5H2O), was evaluated in a culture of a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. Batch experiments were performed in a non-growth bicarbonate medium with lactate as electron donor at pH 7 buffered with PIPES. Calcium increased both the rate and extent of Na-boltwoodite dissolution by increasing its solubility through the formation of a ternary aqueous calcium-uranyl-carbonate species. The ternary species, however, decreased the rates of microbial reduction of aqueous U(VI). Laser-induced fluorescence spectroscopy (LIFS) and transmission electron microscopy (TEM) revealed that microbial reductionmore » of solid phase U(VI) is a sequentially coupled process of Na-boltwoodite dissolution, U(VI) aqueous speciation, and microbial reduction of dissolved U(VI) to U(IV) that accumulated on bacterial surfaces/periplasm. The overall rates of microbial reduction of solid phase U(VI) can be described by the coupled rates of dissolution and microbial reduction that were both influenced by calcium. The results demonstrated that dissolved U(VI) concentration during microbial reduction was a complex function of solid phase U(VI) dissolution kinetics, aqueous U(VI) speciation, and microbial activity.« less

  15. Singular Instantons and Painlevé VI

    NASA Astrophysics Data System (ADS)

    Muñiz Manasliski, Richard

    2016-06-01

    We consider a two parameter family of instantons, which is studied in [Sadun L., Comm. Math. Phys. 163 (1994), 257-291], invariant under the irreducible action of SU_2 on S^4, but which are not globally defined. We will see that these instantons produce solutions to a one parameter family of Painlevé VI equations (P_VI}) and we will give an explicit expression of the map between instantons and solutions to P_{VI}. The solutions are algebraic only for that values of the parameters which correspond to the instantons that can be extended to all of S^4. This work is a generalization of [Muñiz Manasliski R., Contemp. Math., Vol. 434, Amer. Math. Soc., Providence, RI, 2007, 215-222] and [Muñiz Manasliski R., J. Geom. Phys. 59 (2009), 1036-1047, arXiv:1602.07221], where instantons without singularities are studied.

  16. Formic acid interaction with the uranyl(VI) ion: structural and photochemical characterization.

    PubMed

    Lucks, Christian; Rossberg, André; Tsushima, Satoru; Foerstendorf, Harald; Fahmy, Karim; Bernhard, Gert

    2013-10-07

    Complex formation between the uranyl(VI) ion and formic acid was studied by infrared absorption (IR) and X-ray absorption (EXAFS) spectroscopy as well as density functional theory (DFT) calculations. In contrast to the acetate ion which forms exclusively a bidentate complex with uranyl(VI), the formate ion binds to uranyl(VI) in a unidentate fashion. The photochemistry of the uranyl(VI)-formic acid system was explored by DFT calculations and photoreduction of uranyl(VI) in the presence of formic acid was found to occur via an intermolecular process, that is, hydrogen abstraction from hydrogenformate by the photo-excited uranyl(VI). There is no photo-induced decarboxylation of uranyl(VI) formate via an intramolecular process, presumably due to lack of a C=C double bond.

  17. U(VI) adsorption on aquifer sediments at the Hanford Site.

    PubMed

    Um, Wooyong; Serne, R Jeffrey; Brown, Christopher F; Last, George V

    2007-08-15

    Aquifer sediments collected via split-spoon sampling in two new groundwater wells in the 200-UP-1 operable unit at the Hanford Site were characterized and showed typical Ringold Unit E Formation properties dominated by gravel and sand. High iron-oxide content in Fe oxide/clay coatings caused the highest U(VI) adsorption as quantified by batch K(d) values, indicating iron oxides are the key solid adsorbent in the 200-UP-1 sediments that affect U(VI) fate and mobility. Even though U(VI) adsorption on the gravel-sized fraction of the sediments is considered to be negligible, careful characterization should be conducted to determine U(VI) adsorption on gravel, because of presence of Fe oxides coatings and diffusion-controlled adsorption into the gravel particles' interior surfaces. A linear adsorption isotherm was observed up to 10(-6) M (238 microg/L) of total U(VI) concentration in batch U(VI) adsorption tests with varying total U(VI) concentrations in spiked groundwater. U(VI) adsorption decreased with increasing concentrations of dissolved carbonate, because strong anionic aqueous uranium-carbonate complexes formed at high pH and high alkalinity conditions. Noticeable uranium desorption hysteresis was observed in a flow-through column experiment, suggesting that desorption K(d) values for aged uranium-contaminated sediments at the Hanford Site can be larger than adsorption K(d) values determined in short-term laboratory experiments and slow uranium release from contaminated sediments into the groundwater is expected.

  18. 31 CFR 356.5 - What types of securities does the Treasury auction?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... part to distinguish such securities from “inflation-protected” securities. We refer to fixed-principal... years. (2) Treasury inflation-protected notes. (i) Are issued with a stated rate of interest to be applied to the inflation-adjusted principal on each interest payment date; (ii) Have interest payable...

  19. Remediation of Cr(VI)-Contaminated Soil Using the Acidified Hydrazine Hydrate.

    PubMed

    Ma, Yameng; Li, Fangfang; Jiang, Yuling; Yang, Weihua; Lv, Lv; Xue, Haotian; Wang, Yangyang

    2016-09-01

    Acidified hydrazine hydrate was used to remediate Cr(VI)-contaminated soil. The content of water-soluble Cr(VI) in contaminated soil was 4977.53 mg/kg. The optimal initial pH of hydrazine hydrate solution, soil to solution ratio and molar ratio of Cr(VI) to hydrazine hydrate for remediation of Cr(VI)-contaminated soil were 5.0, 3:1 and 1:3, respectively. Over 99.50 % of water-soluble Cr(VI) in the contaminated soil was reduced at the optimal condition within 30 min. The remediated soil can keep stable within 4 months. Meanwhile the total phosphorus increased from 0.47 to 4.29 g/kg, indicating that using of acidified hydrazine hydrate is an effective method to remediate Cr(VI)-contaminated soil.

  20. Detection and Persistence of Vi Antigen in Tissues of Actively Immunized Mice1

    PubMed Central

    Gaines, Sidney; Currie, Julius A.; Tully, Joseph G.

    1965-01-01

    Gaines, Sidney (Walter Reed Army Institute of Research, Washington, D.C.), Julius A. Currie, and Joseph G. Tully. Detection and persistence of Vi antigen in tissues of actively immunized mice. J. Bacteriol. 89:776–781. 1965.—The presence, distribution, and persistence of Vi antigen in mouse tissue was determined by means of active immunization tests with tissue extracts. Mice were injected intraperitoneally with purified Vi antigen or Vi-containing bacilli. At appropriate intervals, animals were killed, and saline extracts of their tissues were prepared. Mice were immunized with these extracts and challenged 6 days later with 10 ld50 of Salmonella typhosa Ty2. Protection was afforded by tissue extracts from Vi-injected mice, but not by normal tissue extracts. That the immunizing capacity of tissue extracts from Vi-injected mice was attributable to Vi antigen was affirmed by the demonstration that these extracts stimulated the production of Vi antibody in mice, coated erythrocytes for agglutination by Vi antiserum, and inhibited agglutination of Vi-sensitized red blood cells by known Vi antisera. Vi antigen could be detected in the liver and spleen of mice injected with as little as 1 μg. In mice given 150 μg, the antigen was still present in liver tissue 231 days later. PMID:14273660

  1. Simultaneous Cr(VI) bio-reduction and methane production by anaerobic granular sludge.

    PubMed

    Hu, Qian; Sun, Jiaji; Sun, Dezhi; Tian, Lan; Ji, Yanan; Qiu, Bin

    2018-08-01

    Wastewater containing toxic hexavalent chromium (Cr(VI)) were treated with well-organized anaerobic granular sludge in this study. Results showed that the anaerobic granular sludge rapidly removed Cr(VI), and 2000 µg·L -1 Cr(VI) was completely eliminated within 6 min, which was much faster than the reported duration of removal by reported artificial materials. Sucrose added as a carbon source acted as an initial electron donor to reduce Cr(VI) to Cr(III). This process was considered as the main mechanism of Cr(VI) removal. Methane production by anaerobic granular sludge was improved by the addition of Cr(VI) at a concentration lower than 500 µg·L -1 . Anaerobic granular sludge had a well-organized structure, which presented good resistance against toxic Cr(VI). Trichoccus accelerated the degradation of organic substances to generate acetates with a low Cr(VI) concentration, thereby enhancing methane production by acetotrophic methanogens. Copyright © 2018 Elsevier Ltd. All rights reserved.

  2. 31 CFR 380.3 - What collateral may I pledge if I am a Treasury Tax and Loan depositary under 31 CFR part 203...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 2 2010-07-01 2010-07-01 false What collateral may I pledge if I am a Treasury Tax and Loan depositary under 31 CFR part 203, and what value will you assign to it? 380...) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT COLLATERAL ACCEPTABILITY AND...

  3. Re-examination of immune response and estimation of anti-Vi IgG protective threshold against typhoid fever-based on the efficacy trial of Vi conjugate in young children.

    PubMed

    Szu, Shousun C; Klugman, Keith P; Hunt, Steven

    2014-04-25

    The capsular polysaccharide of Salmonella enterica serovar Typhi, Vi antigen, is an essential virulence factor and a protective antigen. Similar to other polysaccharide vaccines, the protective action of Vi, both to the polysaccharide alone or when presented as a conjugate, is mediated by serum IgG Vi antibodies. The evaluation of Vi capsular polysaccharide based vaccines to prevent typhoid fever would be significantly facilitated by the identification of a "protective level" of serum antibodies to Vi antigen. The protective level of anti-Vi IgG against typhoid fever was derived from the protective efficacy and immune response of a Vi-rEPA conjugate vaccine efficacy trial. The estimation was derived by two methods: correlation of the percent efficacy and the antibody distribution profile in the vaccine group at a given period of observation, and use of the relative ratio of anti-Vi IgG levels between the vaccine and placebo groups greater or equal to the Relative Risk of typhoid fever used in the efficacy determination. Both methods predicted a similar range of a minimum protective level of anti-Vi IgG between 1.4 and 2.0μg/ml (short term threshold). When applying a protective threshold of 10μg/ml at 6 months post immunization, an IgG level in excess of 1.4μg/ml was achieved by 90% of children at 46 months post immunization, consistent with an 89% level of protection over the duration of the study. We thus suggest that the proportion of children with Vi IgG>10μg/ml (long term threshold) 6 months after immunization may reflect the proportion protected over at least a 4 year period. The current assignment of an anti-Vi IgG protective level may be of value when evaluating vaccine performance of future Vi conjugate vaccines. Published by Elsevier Ltd.

  4. Re-examination of immune response and estimation of anti-Vi IgG protective threshold against typhoid fever-based on the efficacy trial of Vi conjugate in young children

    PubMed Central

    Szu, Shousun C.; Klugman, Keith P.; Hunt, Steven

    2014-01-01

    Background The capsular polysaccharide of Salmonella enterica serovar Typhi, Vi antigen, is an essential virulence factor and a protective antigen. Similar to other polysaccharide vaccines, the protective action of Vi, both to the polysaccharide alone or when presented as a conjugate, is mediated by serum IgG Vi antibodies. The evaluation of Vi capsular polysaccharide based vaccines to prevent typhoid fever would be significantly facilitated by the identification of a “protective level” of serum antibodies to Vi antigen. Methods The protective level of anti-Vi IgG against typhoid fever was derived from the protective efficacy and immune response of a Vi-rEPA conjugate vaccine efficacy trial. The estimation was derived by two methods: correlation of the percent efficacy and the antibody distribution profile in the vaccine group at a given period of observation, and use of the relative ratio of anti-Vi IgG levels between the vaccine and placebo groups greater or equal to the Relative Risk of typhoid fever used in the efficacy determination. Results Both methods predicted a similar range of a minimum protective level of anti-Vi IgG between 1.4 and 2.0 μg/ml (short term threshold). When applying a protective threshold of 10 μg/ml at 6 months post immunization, an IgG level in excess of 1.4 μg/ml was achieved by 90% of children at 46 months post immunization, consistent with an 89% level of protection over the duration of the study. We thus suggest that the proportion of children with Vi IgG > 10 μg/ml (long term threshold) 6 months after immunization may reflect the proportion protected over at least a 4 year period. Conclusion The current assignment of an anti-Vi IgG protective level may be of value when evaluating vaccine performance of future Vi conjugate vaccines. PMID:24630869

  5. Oxidation of Oil Sands Process-Affected Water by Potassium Ferrate(VI).

    PubMed

    Wang, Chengjin; Klamerth, Nikolaus; Huang, Rongfu; Elnakar, Haitham; Gamal El-Din, Mohamed

    2016-04-19

    This paper investigates the oxidation of oil sands process-affected water (OSPW) by potassium ferrate(VI). Due to the selectivity of ferrate(VI) oxidation, two-ring and three-ring fluorescing aromatics were preferentially removed at doses <100 mg/L Fe(VI), and one-ring aromatics were removed only at doses ≥100 mg/L Fe(VI). Ferrate(VI) oxidation achieved 64.0% and 78.4% removal of naphthenic acids (NAs) at the dose of 200 mg/L and 400 mg/L Fe(VI) respectively, and NAs with high carbon number and ring number were removed preferentially. (1)H nuclear magnetic resonance ((1)H NMR) spectra indicated that the oxidation of fluorescing aromatics resulted in the opening of some aromatic rings. Electron paramagnetic resonance (EPR) analysis detected signals of organic radical intermediates, indicating that one-electron transfer is one of the probable mechanisms in the oxidation of NAs. The inhibition effect of OSPW on Vibrio fischeri and the toxicity effect on goldfish primary kidney macrophages (PKMs) were both reduced after ferrate(VI) oxidation. The fluorescing aromatics in OSPW were proposed to be an important contributor to this acute toxicity. Degradation of model compounds with ferrate(VI) was also investigated and the results confirmed our findings in OSPW study.

  6. Sorption characteristic of uranium(VI) ion onto K-feldspar.

    PubMed

    Gao, Xiaoqing; Bi, Mingliang; Shi, Keliang; Chai, Zhifang; Wu, Wangsuo

    2017-10-01

    The effect of pH, contact time, temperature, ionic strength and initial U(VI) concentration on U(VI) sorption onto K-feldspar was investigated using batch techniques. The sorption kinetics was evaluated and the activation energy was obtained based on the rate constants at different temperature. Graphical correlations of sorption isotherm models have been evaluated and applied for U(VI) uptake by K-feldspar. Various thermodynamic parameters, such as, Gibb's free energy, entropy and enthalpy of the on-going sorption process have been calculated and the possible sorption mechanism of U(VI) was deduced. The results are expected to help better understand the migration of uranium in the host materials of granite. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Microstructural analyses of Cr(VI) speciation in chromite ore processing Residue (COPR)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    CHRYSOCHOOU, MARIA; FAKRA, SIRINE C .; Marcus, Matthew A.

    2010-03-01

    The speciation and distribution of Cr(VI) in the solid phase was investigated for two types of chromite ore processing residue (COPR) found at two deposition sites in the United States: gray-black (GB) granular and hard brown (HB) cemented COPR. COPR chemistry and mineralogy were investigated using micro-X-ray absorption spectroscopy and micro-X-ray diffraction, complemented by laboratory analyses. GB COPR contained 30percent of its total Cr(VI) (6000 mg/kg) as large crystals(>20 ?m diameter) of a previously unreported Na-rich analog of calcium aluminum chromate hydrates. These Cr(VI)-rich phases are thought to be vulnerable to reductive and pH treatments. More than 50percent of themore » Cr(VI) was located within nodules, not easily accessible to dissolved reductants, and bound to Fe-rich hydrogarnet, hydrotalcite, and possibly brucite. These phases are stable over a large pH range, thus harder to dissolve. Brownmilleritewasalso likely associated with physical entrapment of Cr(VI) in the interior of nodules. HB COPR contained no Cr(VI)-rich phases; all Cr(VI) was diffuse within the nodules and absent from the cementing matrix, with hydrogarnet and hydrotalcite being the main Cr(VI) binding phases. Treatment ofHBCOPRis challenging in terms of dissolving the acidity-resistant, inaccessible Cr(VI) compounds; the same applies to ~;;50percent of Cr(VI) in GB COPR.« less

  8. 76 FR 62148 - Title VI; Proposed Circular, Environmental Justice; Proposed Circular

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-06

    ...-0055] Title VI; Proposed Circular, Environmental Justice; Proposed Circular AGENCY: Federal Transit... the September 29, 2011, Federal Register Notices titled ``Title VI; Proposed Circular'' and... September 29, 2011, Federal Register Notices titled ``Title VI; Proposed Circular'' (76 FR 60593) and...

  9. Cross-correlation analysis between Chinese TF contracts and treasury ETF based on high-frequency data

    NASA Astrophysics Data System (ADS)

    Zhou, Yu; Chen, Shi

    2016-02-01

    In this paper, we investigate the high-frequency cross-correlation relationship between Chinese treasury futures contracts and treasury ETF. We analyze the logarithmic return of these two price series, from which we can conclude that both return series are not normally distributed and the futures markets have greater volatility. We find significant cross-correlation between these two series. We further confirm the relationship using the DCCA coefficient and the DMCA coefficient. We quantify the long-range cross-correlation with DCCA method, and we further show that the relationship is multifractal. An arbitrage algorithm based on DFA regression with stable return is proposed in the last part.

  10. 5. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  11. 11. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  12. 7. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  13. 12. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  14. 10. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    10. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  15. 6. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  16. 14. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  17. 8. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  18. 13. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  19. 9. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  20. 4. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. Historic American Buildings Survey ARCHITECT'S DRAWING Copy negative from book published by Secretary of Treasury, 1857, consisting of 21 plates. In office of the Building Manager, General Services Administration, New Orleans - U.S. Custom House, 423 Canal Street, New Orleans, Orleans Parish, LA

  1. Synthesis of surface Cr (VI)-imprinted magnetic nanoparticles for selective dispersive solid-phase extraction and determination of Cr (VI) in water samples.

    PubMed

    Qi, Xue; Gao, Shuang; Ding, Guosheng; Tang, An-Na

    2017-01-01

    A facile, rapid and selective magnetic dispersed solid-phase extraction (dSPE) method for the extraction and enrichment of Cr (VI) prior to flame atomic absorption spectrometry (AAS) was introduced. For highly selective and efficient extraction, magnetic Cr (VI)-imprinted nanoparticles (Fe 3 O 4 @ Cr (VI) IIPs) were prepared by hyphenating surface ion-imprinted with sol-gel techniques. In the preparation process, chromate (Cr(VI)) was used as the template ion; vinylimidazole and 3-aminopropyltriethoxysilane were selected as organic functional monomer and co-monomer respectively. Another reagent, methacryloxypropyltrimethoxysilane was adopted as coupling agent to form the stable covalent bonding between organic and inorganic phases. The effects of various parameters on the extraction efficiency, such as pH of sample solution, the amount of adsorbent, extraction time, the type and concentration of eluent were systematically investigated. Furthermore, the thermodynamic and kinetic properties of the adsorption process were studied to explore the internal adsorption mechanism. Under optimized conditions, the preconcentration factor, limit of detection and linear range of the established dSPE-AAS method for Cr (VI) were found to be 98, 0.29μgL -1 and 4-140μgL -1 , respectively. The developed method was also successfully applied to the analysis of Cr (VI) in different water samples with satisfactory results, proving its reliability and feasibility in real sample analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

  2. Major Management Challenges and Program Risks. Department of the Treasury

    DTIC Science & Technology

    2001-01-01

    Major Management Challenges and Program Risks Department of the TreasuryGAO-01-254 Form SF298 Citation Data Report Date ("DD MON YYYY") 00JAN2001...Report Type N/A Dates Covered (from... to) ("DD MON YYYY") Title and Subtitle Major Management Challenges and Program Risks Department of the...High Risks (GAO-01-159SP), in November 2000.This report addresses the major performance and accountability challenges facing the Department of the

  3. 31 CFR 356.4 - What are the book-entry systems in which auctioned Treasury securities may be issued or maintained?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... government and international agencies and foreign central banks. In their accounts, depository institutions... BUREAU OF THE PUBLIC DEBT SALE AND ISSUE OF MARKETABLE BOOK-ENTRY TREASURY BILLS, NOTES, AND BONDS... Direct®—into which we issue marketable Treasury securities. We maintain and transfer securities in these...

  4. Ferrate(VI) oxidation of weak-acid dissociable cyanides

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ria A. Yngard; Virender K. Sharma; Jan Filip

    2008-04-15

    Cyanide is commonly found in electroplating, mining, coal gasification, and petroleum refining effluents, which require treatment before being discharged. Cyanide in effluents exists either as free cyanide or as a metal complex. The kinetics of the oxidation of weak-acid dissociable cyanides by an environmentally friendly oxidant, ferrate, were studied as a function of pH (9.1-10.5) and temperature (15-45{sup o}C) using a stopped-flow technique. The weak-acid dissociable cyanides were Cd(CN){sub 4}{sup 2-} and Ni(CN){sub 4}{sup 2-}, and the rate-laws for the oxidation may be -d(Fe(VI))/dt = k (Fe(VI))(M(CN){sub 4}{sup 2-}){sup n} where n = 0.5 and 1 for Cd(CN){sub 4}{sup 2-}more » and Ni(CN){sub 4}{sup 2-}, respectively. The rates decreased with increasing pH and were mostly related to a decrease in concentration of the reactive protonated Fe(VI) species, HFeO{sub 4}{sup -}. The stoichiometries with Fe(VI) were determined to be: 4HFeO{sub 4}{sup -} + M(CN){sub 4}{sup 2-} + 6H{sub 2}O {yields} 4Fe(OH){sub 3} + M{sup 2+} + 4NCO{sup -} + O{sub 2} + 4OH{sup -}. Mechanisms are proposed that agree with the observed reaction rate-laws and stoichiometries of the oxidation of weak-acid dissociable cyanides by Fe(VI). Results indicate that Fe(VI) is effective in removing cyanide in coke oven plant effluent, where organics are also present. 27 refs., 3 figs., 2 tabs.« less

  5. 45 CFR 1150.30 - Which debts can the Endowment refer to the Treasury for collection by offsetting tax refunds?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ENDOWMENT FOR THE ARTS COLLECTION OF CLAIMS Tax Refund Offset § 1150.30 Which debts can the Endowment refer... enforceable debt referable to the Treasury for tax refund offset is a debt that is owed to the Endowment and... the Treasury regulations relating to the eligibility of a debt for tax return offset (31 CFR 285.2...

  6. The abundance, distribution, and physical nature of highly ionized oxygen O VI, O VII, and O VIII in IllustrisTNG

    NASA Astrophysics Data System (ADS)

    Nelson, Dylan; Kauffmann, Guinevere; Pillepich, Annalisa; Genel, Shy; Springel, Volker; Pakmor, Rüdiger; Hernquist, Lars; Weinberger, Rainer; Torrey, Paul; Vogelsberger, Mark; Marinacci, Federico

    2018-06-01

    We explore the abundance, spatial distribution, and physical properties of the O VI, O VII, and O VIII ions of oxygen in circumgalactic and intergalactic media (the CGM, IGM, and WHIM). We use the TNG100 and TNG300 large volume cosmological magnetohydrodynamical simulations. Modelling the ionization states of simulated oxygen, we find good agreement with observations of the low-redshift O VI column density distribution function (CDDF), and present its evolution for all three ions from z = 0 to z = 4. Producing mock quasar absorption line spectral surveys, we show that the IllustrisTNG simulations are fully consistent with constraints on the O VI content of the CGM from COS-haloes and other low-redshift observations, producing columns as high as observed. We measure the total amount of mass and average column densities of each ion using hundreds of thousands of simulated galaxies spanning 10^{11} < {M}_halo/ M⊙<1015 corresponding to 109 < M⋆/ M⊙<1012 in stellar mass. Stacked radial profiles of O VI are computed in 3D number density and 2D projected column density, decomposing into 1-halo and 2-halo terms. Relating halo O VI to properties of the central galaxy, we find a correlation between the (g - r) colour of a galaxy and the total amount of O VI in its CGM. In comparison to the COS-Haloes finding, this leads to a dichotomy of columns around star-forming versus passive galaxies at fixed stellar (or halo) mass. We demonstrate that this correlation is a direct result of black hole feedback associated with quenching and represents a causal consequence of galactic-scale baryonic feedback impacting the physical state of the circumgalactic medium.

  7. Inhibition of nitrate reduction by chromium (VI) in anaerobic soil microcosms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kourtev, P. S.; Nakatsu, C. H.; Konopka, Allan

    2009-10-01

    Chromium (VI) is often found as a co-contaminant at sites polluted with organic compounds. We used microcosms amended with glucose or protein, nitrate and increasing concentrations of chromium to study nitrate reduction in Cr(VI) polluted soils. Organic carbon stimulated bacterial activity, but the addition of Cr(VI) caused a lag and then slower rates 5 of CO2 accumulation. Nitrate reduction only occurred after Cr(VI) had been reduced. Bacterial activity was again inhibited when Cr(VI) was added a second time; thus not all Cr-sensitive bacteria were removed in the first phase. Glucose and protein selected for relatively similar bacterial communities, as assayedmore » by PCR-DGGE of the 16S rRNA gene; this selection was modified by the addition of 10 Cr(VI). Cr-resistant bacteria isolated from microcosms were closely related to members of Bacillus, Enterococcus and Propionibacterium sp. Our results indicate that carbon utilization and nitrate reduction in these soils in the presence of Cr(VI) are contingent upon the reduction of the added heavy metal by a limited subset of the bacterial community. The amount of Cr(VI) required to inhibit nitrate reduction was 10-fold less than for aerobic catabolism of the same 15 substrate. We hypothesize that the resistance level of a microbial process is directly related to the diversity of microbes capable of conducting it.« less

  8. [Treasury Law Enforcement School. Course 14. "Evidence." Student Guide, Text, and Handout.

    ERIC Educational Resources Information Center

    Department of the Treasury, Washington, DC. Consolidated Law Enforcement Training Center.

    This packet of three booklets, which includes a student guide, textbook, and handbook, is illustrative of other booklets available from the Treasury Law Enforcement School designed for training law enforcement officers in Federal law. The material in this course, related primarily to criminal cases, focuses on presenting evidence to the court to…

  9. Effect of phosphate on U(VI) sorption to montmorillonite: Ternary complexation and precipitation barriers

    NASA Astrophysics Data System (ADS)

    Troyer, Lyndsay D.; Maillot, Fabien; Wang, Zheming; Wang, Zimeng; Mehta, Vrajesh S.; Giammar, Daniel E.; Catalano, Jeffrey G.

    2016-02-01

    Phosphate addition is a potential treatment method to lower the solubility of U(VI) in soil and groundwater systems by causing U(VI) phosphate precipitation as well as enhancing adsorption. Previous work has shown that iron oxide surfaces may facilitate the nucleation of U(VI) phosphate minerals and, that under weakly acidic conditions, phosphate also enhances U(VI) adsorption to such phases. Like iron oxides, clays are important reactive phases in the subsurface but little is known about the interaction of U(VI) and phosphate with these minerals. The effect of aqueous phosphate on U(VI) binding to Wyoming montmorillonite (SWy-2) in air-equilibrated systems was investigated. Equilibrium U(VI) uptake to montmorillonite was determined at pH 4, 6 and 8 at discrete initial phosphate concentrations between 0 and 100 μM. The observed behavior of U(VI) indicates a transition from adsorption to precipitation with increasing total uranium and phosphate concentrations at all pH values. At the highest phosphate concentration examined at each pH value, a barrier to U(VI) phosphate nucleation is observed. At lower concentrations, phosphate has no effect on macroscopic U(VI) adsorption. To assess the mechanisms of U(VI)-phosphate interactions on smectite surfaces, U(VI) speciation was investigated under selected conditions using laser-induced fluorescence spectroscopy (LIFS) and extended X-ray absorption fine-structure (EXAFS) spectroscopy. Samples above the precipitation threshold display EXAFS and LIFS spectral signatures consistent with the autunite family of U(VI) phosphate minerals. However, at lower U(VI) concentrations, changes in LIFS spectra upon phosphate addition suggest that U(VI)-phosphate ternary surface complexes form on the montmorillonite surface at pH 4 and 6 despite the lack of a macroscopic effect on adsorption. The speciation of solid-associated U(VI) below the precipitation threshold at pH 8 is dominated by U(VI)-carbonate surface complexes. This work

  10. Effect of Phosphate on U(VI) Sorption to Montmorillonite: Ternary Complexation and Precipitation Barriers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Troyer, Lyndsay D.; Maillot, Fabien; Wang, Zheming

    Phosphate addition is a potential treatment method to lower the solubility of U(VI) in soil and groundwater systems by causing U(VI) phosphate precipitation as well as enhancing adsorption. Previous work has shown that iron oxide surfaces may facilitate the nucleation of U(VI) phosphate minerals and, that under weakly acidic conditions, phosphate also enhances U(VI) adsorption to such phases. Like iron oxides, clays are important reactive phases in the subsurface but little is known about the interaction of U(VI) and phosphate with these minerals. The effect of aqueous phosphate on U(VI) binding to Wyoming montmorillonite (SWy-2) in air-equilibrated systems was investigated.more » Equilibrium U(VI) uptake to montmorillonite was determined at pH 4, 6 and 8 at discrete initial phosphate concentrations between 0 and 100 μM. The observed behavior of U(VI) indicates a transition from adsorption to precipitation with increasing total uranium and phosphate concentrations at all pH values. At the highest phosphate concentration examined at each pH value, a barrier to U(VI) phosphate nucleation is observed. At lower concentrations, phosphate has no effect on macroscopic U(VI) adsorption. To assess the mechanisms of U(VI)-phosphate interactions on smectite surfaces, U(VI) speciation was investigated under selected conditions using laser-induced fluorescence spectroscopy (LIFS) and extended X-ray absorption fine-structure (EXAFS) spectroscopy. Samples above the precipitation threshold display EXAFS and LIFS spectral signatures consistent with the autunite family of U(VI) phosphate minerals. However, at lower U(VI) concentrations, changes in LIFS spectra upon phosphate addition suggest that U(VI)-phosphate ternary surface complexes form on the montmorillonite surface at pH 4 and 6 despite the lack of a macroscopic effect on adsorption. The speciation of solid-associated U(VI) below the precipitation threshold at pH 8 is dominated by U(VI)-carbonate surface complexes. This

  11. The XXL Survey. VI. The 1000 brightest X-ray point sources

    NASA Astrophysics Data System (ADS)

    Fotopoulou, S.; Pacaud, F.; Paltani, S.; Ranalli, P.; Ramos-Ceja, M. E.; Faccioli, L.; Plionis, M.; Adami, C.; Bongiorno, A.; Brusa, M.; Chiappetti, L.; Desai, S.; Elyiv, A.; Lidman, C.; Melnyk, O.; Pierre, M.; Piconcelli, E.; Vignali, C.; Alis, S.; Ardila, F.; Arnouts, S.; Baldry, I.; Bremer, M.; Eckert, D.; Guennou, L.; Horellou, C.; Iovino, A.; Koulouridis, E.; Liske, J.; Maurogordato, S.; Menanteau, F.; Mohr, J. J.; Owers, M.; Poggianti, B.; Pompei, E.; Sadibekova, T.; Stanford, A.; Tuffs, R.; Willis, J.

    2016-06-01

    Context. X-ray extragalactic surveys are ideal laboratories for the study of the evolution and clustering of active galactic nuclei (AGN). Usually, a combination of deep and wide surveys is necessary to create a complete picture of the population. Deep X-ray surveys provide the faint population at high redshift, while wide surveys provide the rare bright sources. Nevertheless, very wide area surveys often lack the ancillary information available for modern deep surveys. The XXL survey spans two fields of a combined 50 deg2 observed for more than 6Ms with XMM-Newton, occupying the parameter space that lies between deep surveys and very wide area surveys; at the same time it benefits from a wealth of ancillary data. Aims: This paper marks the first release of the XXL point source catalogue including four optical photometry bands and redshift estimates. Our sample is selected in the 2 - 10 keV energy band with the goal of providing a sizable sample useful for AGN studies. The limiting flux is F2 - 10 keV = 4.8 × 10-14 erg s-1 cm-2. Methods: We use both public and proprietary data sets to identify the counterparts of the X-ray point-like sources by means of a likelihood ratio test. We improve upon the photometric redshift determination for AGN by applying a Random Forest classification trained to identify for each object the optimal photometric redshift category (passive, star forming, starburst, AGN, quasi-stellar objects (QSO)). Additionally, we assign a probability to each source that indicates whether it might be a star or an outlier. We apply Bayesian analysis to model the X-ray spectra assuming a power-law model with the presence of an absorbing medium. Results: We find that the average unabsorbed photon index is ⟨Γ⟩ = 1.85 ± 0.40 while the average hydrogen column density is log ⟨NH⟩ = 21.07 ± 1.2 cm-2. We find no trend of Γ or NH with redshift and a fraction of 26% absorbed sources (log NH> 22) consistent with the literature on bright sources (log

  12. 6. Historic American Buildings Survey, from Annual Report of the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Historic American Buildings Survey, from Annual Report of the Supervising Architect to the Secretary of the Treasury for the Calendar Year Ending December 31, 1888, Washington, D.C., Government Printing Office, 1889 PHOTOCOPY. - U. S. Post Office Building, Broad & Meeting Streets, Charleston, Charleston County, SC

  13. The MK VI - A second generation attitude control system

    NASA Astrophysics Data System (ADS)

    Meredith, P. J.

    1986-10-01

    The MK VI, a new multipurpose attitude control system for the exoatmospheric attitude control of sounding rocket payloads, is described. The system employs reprogrammable microcomputer memory for storage of basic control logic and for specific mission event control data. The paper includes descriptions of MK VI specifications and configuration; sensor characteristics; the electronic, analog, and digital sections; the pneumatic system; ground equipment; the system operation; and software. A review of the MK VI performance for the Comet Halley flight is presented. Block diagrams are included.

  14. National Interim Energy-Consumption Survey. Part VI. Energy assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The goal of energy assessment of the housing unit is to obtain physical information which can be combined with other survey results to give a more complete picture of the residential environment. A limited pretest of an energy assessment procedure was carried out in April-June 1979 with a subsample of 44 households that had been originally interviewed in the National Interim Energy Consumption Survey. In order to gain experience under a variety of environmental conditions, the pretest sites included locations in the Northeast, North Central, and South regions. As developed for the pretest, the energy assessment was a 90-minute inspectionmore » of the housing unit by a trained technician. Data collected during the inspection included square footage of the unit; age, make, and characteristics of appliances; insulation characteristics, characteristics of siting and apertures; and detailed information on the heating and cooling systems in the unit. The report describes the data collection procedures for the pretest.« less

  15. The October 2014 United States Treasury bond flash crash and the contributory effect of mini flash crashes

    PubMed Central

    Levine, Zachary S.; Floridi, Luciano

    2017-01-01

    We investigate the causal uncertainty surrounding the flash crash in the U.S. Treasury bond market on October 15, 2014, and the unresolved concern that no clear link has been identified between the start of the flash crash at 9:33 and the opening of the U.S. equity market at 9:30. We consider the contributory effect of mini flash crashes in equity markets, and find that the number of equity mini flash crashes in the three-minute window between market open and the Treasury Flash Crash was 2.6 times larger than the number experienced in any other three-minute window in the prior ten weekdays. We argue that (a) this statistically significant finding suggests that mini flash crashes in equity markets both predicted and contributed to the October 2014 U.S. Treasury Bond Flash Crash, and (b) mini-flash crashes are important phenomena with negative externalities that deserve much greater scholarly attention. PMID:29091931

  16. Kandinsky's "Composition VI": Heideggerian Poetry in Noah's Ark

    ERIC Educational Resources Information Center

    Hall, Joshua M.

    2012-01-01

    The author will begin his investigation of Wassily Kandinsky's painting "Composition VI" with Kandinsky's own commentary on the painting. He will then turn to the analysis of Kandinsky and the "Compositions" in John Sallis's book "Shades." Using this analysis as his point of departure, the author will consider how "Composition VI" resonates with…

  17. Quantifying Cr(VI) Production and Export from Serpentine Soil of the California Coast Range.

    PubMed

    McClain, Cynthia N; Fendorf, Scott; Webb, Samuel M; Maher, Kate

    2017-01-03

    Hexavalent chromium (Cr(VI)) is generated in serpentine soils and exported to surface and groundwaters at levels above health-based drinking water standards. Although Cr(VI) concentrations are elevated in serpentine soil pore water, few studies have reported field evidence documenting Cr(VI) production rates and fluxes that govern Cr(VI) transport from soil to water sources. We report Cr speciation (i) in four serpentine soil depth profiles derived from the California Coast Range serpentinite belt and (ii) in local surface waters. Within soils, we detected Cr(VI) in the same horizons where Cr(III)-minerals are colocated with biogenic Mn(III/IV)-oxides, suggesting Cr(VI) generation through oxidation by Mn-oxides. Water-extractable Cr(VI) concentrations increase with depth constituting a 7.8 to 12 kg/km 2 reservoir of Cr(VI) in soil. Here, Cr(VI) is produced at a rate of 0.3 to 4.8 kg Cr(VI)/km 2 /yr and subsequently flushed from soil during water infiltration, exporting 0.01 to 3.9 kg Cr(VI)/km 2 /yr at concentrations ranging from 25 to 172 μg/L. Although soil-derived Cr(VI) is leached from soil at concentrations exceeding 10 μg/L, due to reduction and dilution during transport to streams, Cr(VI) levels measured in local surface waters largely remain below California's drinking water limit.

  18. Removal of chromium (VI) from aqueous solution using walnut hull.

    PubMed

    Wang, Xue Song; Li, Zhi Zhong; Tao, Sheng Rong

    2009-02-01

    In this study, removal of chromium (VI) from aqueous solution by walnut hull (a local low-cost adsorbent) was studied. The extent of adsorption was investigated as a function of solution pH, contact time, adsorbent and adsorbate concentration, reaction temperature and supporting electrolyte (sodium chloride). The Cr (VI) removal was pH-dependent, reaching a maximum (97.3%) at pH 1.0. The kinetic experimental data were fitted to the first-order, modified Freundlich, intraparticle diffusion and Elovich models and the corresponding parameters were obtained. A 102.78 kJ/mol Ea (activation energy) for the reaction of chromium (VI) adsorption onto walnut indicated that the rate-limiting step in this case might be a chemically controlled process. Both the Langmuir and Freundlich isotherms were suitable for describing the biosorption of chromium (VI) onto walnut hull. The uptake of chromium (VI) per weight of adsorbent increased with increasing initial chromium (VI) concentration up to 240-480 mg/L, and decreased sharply with increasing adsorbent concentration ranging from 1.0 to 5.0 g/L. An increase in sodium chloride (as supporting electrolyte) concentration was found to induce a negative effect while an increase in temperature was found to give rise to a positive effect on the chromium (VI) adsorption process. Compared to the various other adsorbents reported in the literature, the walnut hull in this study shows very good promise for practical applicability.

  19. Kinetic evaluation of chromium(VI) sorption by water lettuce (Pistia).

    PubMed

    Chakraborty, Rupa; Karmakar, Sukalpa; Mukherjee, Somnath; Kumar, Sunil

    2014-01-01

    An investigation was performed to evaluate the uptake capacity of Pistia in living condition for adsorptive removal of chromium(VI) from spiked solution for examining a remedial measure for disposal of chrome-laden wastewater in an urban wetland system. Kinetics results show about 78% removal was achieved for 3 mg/L initial concentration of Cr(VI). Experimental data showed that the root portion absorbed more Cr(VI) (28.54 μg/g) compared to accumulation in leaf (5.73 μg/g). It was also noted that the plant could effectively remove Cr(VI) from the solution with minor damage up to an initial Cr(VI) concentration of 3 mg/L, for which the adsorption isotherm studies were conducted. The maximum uptake capacity of the plant was recorded as 0.05 mg/g of Cr(VI) at the equilibrium level after a contact period of 7 days for an initial concentration of 8 mg /L, although severe physiological damage occurred. The experimental results were plotted in Langmuir and Freundlich isotherm models and both were found to be well fitted (r(2) = 0.979 and r(2) = 0.974 respectively). The high value of n (2.16) reveals a strong bond between the plant root and dissolved Cr(VI), which favours the adsorption process. The order of the reaction was also examined on the basis of uptake capacity and it was found that the second order model fitted best.

  20. 21 CFR 17.54 - Deposit in the Treasury of the United States.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Deposit in the Treasury of the United States. 17.54 Section 17.54 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES... assessed pursuant to this part shall be delivered to the Director, Division of Financial Management (HFA...

  1. 75 FR 80818 - Funding Availability for Title VI Grant Applications; Extension

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-23

    ... DEPARTMENT OF HEALTH AND HUMAN SERVICES Administration on Aging Funding Availability for Title VI... Administration on Aging is extending the date for which the Title VI grants applications for the grant period... on March 31, 2011. Funding Opportunity Title/Program Name: Older Americans Act (OAA), Title VI, Part...

  2. 47 CFR 1.1917 - Referrals to the Department of Justice and transfer of delinquent debt to the Secretary of Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Commission will cease all collection activity related to that debt. (c) All non-tax debts of claims owed to... transfer of delinquent debt to the Secretary of Treasury. 1.1917 Section 1.1917 Telecommunication FEDERAL... of Justice and transfer of delinquent debt to the Secretary of Treasury. (a) Referrals to the...

  3. GWM-VI: groundwater management with parallel processing for multiple MODFLOW versions

    USGS Publications Warehouse

    Banta, Edward R.; Ahlfeld, David P.

    2013-01-01

    Groundwater Management–Version Independent (GWM–VI) is a new version of the Groundwater Management Process of MODFLOW. The Groundwater Management Process couples groundwater-flow simulation with a capability to optimize stresses on the simulated aquifer based on an objective function and constraints imposed on stresses and aquifer state. GWM–VI extends prior versions of Groundwater Management in two significant ways—(1) it can be used with any version of MODFLOW that meets certain requirements on input and output, and (2) it is structured to allow parallel processing of the repeated runs of the MODFLOW model that are required to solve the optimization problem. GWM–VI uses the same input structure for files that describe the management problem as that used by prior versions of Groundwater Management. GWM–VI requires only minor changes to the input files used by the MODFLOW model. GWM–VI uses the Joint Universal Parameter IdenTification and Evaluation of Reliability Application Programming Interface (JUPITER-API) to implement both version independence and parallel processing. GWM–VI communicates with the MODFLOW model by manipulating certain input files and interpreting results from the MODFLOW listing file and binary output files. Nearly all capabilities of prior versions of Groundwater Management are available in GWM–VI. GWM–VI has been tested with MODFLOW-2005, MODFLOW-NWT (a Newton formulation for MODFLOW-2005), MF2005-FMP2 (the Farm Process for MODFLOW-2005), SEAWAT, and CFP (Conduit Flow Process for MODFLOW-2005). This report provides sample problems that demonstrate a range of applications of GWM–VI and the directory structure and input information required to use the parallel-processing capability.

  4. Integrated Cr(VI) removal using constructed wetlands and composting.

    PubMed

    Sultana, Mar-Yam; Chowdhury, Abu Khayer Md Muktadirul Bari; Michailides, Michail K; Akratos, Christos S; Tekerlekopoulou, Athanasia G; Vayenas, Dimitrios V

    2015-01-08

    The present work was conducted to study integrated chromium removal from aqueous solutions in horizontal subsurface (HSF) constructed wetlands. Two pilot-scale HSF constructed wetlands (CWs) units were built and operated. One unit was planted with common reeds (Phragmites australis) and one was kept unplanted. Influent concentrations of Cr(VI) ranged from 0.5 to 10mg/L. The effect of temperature and hydraulic residence time (8-0.5 days) on Cr(VI) removal were studied. Temperature was proved to affect Cr(VI) removal in both units. In the planted unit maximum Cr(VI) removal efficiencies of 100% were recorded at HRT's of 1 day with Cr(VI) concentrations of 5, 2.5 and 1mg/L, while a significantly lower removal rate was recorded in the unplanted unit. Harvested reed biomass from the CWs was co-composted with olive mill wastes. The final product had excellent physicochemical characteristics (C/N: 14.1-14.7, germination index (GI): 145-157%, Cr: 8-10mg/kg dry mass), fulfills EU requirements and can be used as a fertilizer in organic farming. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Experimental Monitoring of Cr(VI) Bio-reduction Using Electrochemical Geophysics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Birsen Canan; Gary R. Olhoeft; William A. Smith

    2007-09-01

    Many Department of Energy (DOE) sites are contaminated with highly carcinogenic hexavalent chromium (Cr(VI)). In this research, we explore the feasibility of applying complex resistivity to the detection and monitoring of microbially-induced reduction of hexavalent chromium (Cr(VI)) to a less toxic form (Cr(III)). We hope to measure the change in ionic concentration that occurs during this reduction reaction. This form of reduction promises to be an attractive alternative to more expensive remedial treatment methods. The specific goal of this research is to define the minimum and maximum concentration of the chemical and biological compounds in contaminated samples for which themore » Cr(VI) - Cr(III) reduction processes could be detected via complex resistivity. There are three sets of experiments, each comprised of three sample columns. The first experiment compares three concentrations of Cr(VI) at the same bacterial cell concentration. The second experiment establishes background samples with, and without, Cr(VI) and bacterial cells. The third experiment examines the influence of three different bacterial cell counts on the same concentration of Cr(VI). A polarization relaxation mechanism was observed between 10 and 50 Hz. The polarization mechanism, unfortunately, was not unique to bio-chemically active samples. Spectral analysis of complex resistivity data, however, showed that the frequency where the phase minimum occurred was not constant for bio-chemically active samples throughout the experiment. A significant shifts in phase minima occurred between 10 to 20 Hz from the initiation to completion of Cr(VI) reduction. This phenomena was quantified using the Cole-Cole model and the Marquardt-Levenberg nonlinear least square minimization method. The data suggests that the relaxation time and the time constant of this relaxation are the Cole-Cole parameters most sensitive to changes in biologically-induced reduction of Cr(VI).« less

  6. 40 CFR Appendix Vi to Part 1039 - Nonroad Compression-ignition Composite Transient Cycle

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Nonroad Compression-ignition Composite Transient Cycle VI Appendix VI to Part 1039 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... ENGINES Pt. 1039, App. VI Appendix VI to Part 1039—Nonroad Compression-ignition Composite Transient Cycle...

  7. PANCHROMATIC HUBBLE ANDROMEDA TREASURY. XII. MAPPING STELLAR METALLICITY DISTRIBUTIONS IN M31

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gregersen, Dylan; Seth, Anil C.; Williams, Benjamin F.

    We present a study of spatial variations in the metallicity of old red giant branch stars in the Andromeda galaxy. Photometric metallicity estimates are derived by interpolating isochrones for over seven million stars in the Panchromatic Hubble Andromeda Treasury (PHAT) survey. This is the first systematic study of stellar metallicities over the inner 20 kpc of Andromeda’s galactic disk. We see a clear metallicity gradient of −0.020 ± 0.004 dex kpc{sup −1} from ∼4–20 kpc assuming a constant red giant branch age. This metallicity gradient is derived after correcting for the effects of photometric bias and completeness and dust extinction, and ismore » quite insensitive to these effects. The unknown age gradient in M31's disk creates the dominant systematic uncertainty in our derived metallicity gradient. However, spectroscopic analyses of galaxies similar to M31 show that they typically have small age gradients that make this systematic error comparable to the 1σ error on our metallicity gradient measurement. In addition to the metallicity gradient, we observe an asymmetric local enhancement in metallicity at radii of 3–6 kpc that appears to be associated with Andromeda’s elongated bar. This same region also appears to have an enhanced stellar density and velocity dispersion.« less

  8. Delineation and Diagnostic Criteria of Oral-Facial-Digital Syndrome Type VI

    PubMed Central

    2012-01-01

    Oral-Facial-Digital Syndrome type VI (OFD VI) represents a rare phenotypic subtype of Joubert syndrome and related disorders (JSRD). In the original report polydactyly, oral findings, intellectual disability, and absence of the cerebellar vermis at post-mortem characterized the syndrome. Subsequently, the molar tooth sign (MTS) has been found in patients with OFD VI, prompting the inclusion of OFD VI in JSRD. We studied the clinical, neurodevelopmental, neuroimaging, and genetic findings in a cohort of 16 patients with OFD VI. We derived the following inclusion criteria from the literature: 1) MTS and one oral finding and polydactyly, or 2) MTS and more than one typical oral finding. The OFD VI neuroimaging pattern was found to be more severe than in other JSRD subgroups and includes severe hypoplasia of the cerebellar vermis, hypoplastic and dysplastic cerebellar hemispheres, marked enlargement of the posterior fossa, increased retrocerebellar collection of cerebrospinal fluid, abnormal brainstem, and frequently supratentorial abnormalities that occasionally include characteristic hypothalamic hamartomas. Additionally, two new JSRD neuroimaging findings (ascending superior cerebellar peduncles and fused thalami) have been identified. Tongue hamartomas, additional frenula, upper lip notch, and mesoaxial polydactyly are specific findings in OFD VI, while cleft lip/palate and other types of polydactyly of hands and feet are not specific. Involvement of other organs may include ocular findings, particularly colobomas. The majority of the patients have absent motor development and profound cognitive impairment. In OFD VI, normal cognitive functions are possible, but exceptional. Sequencing of known JSRD genes in most patients failed to detect pathogenetic mutations, therefore the genetic basis of OFD VI remains unknown. Compared with other JSRD subgroups, the neurological findings and impairment of motor development and cognitive functions in OFD VI are significantly

  9. Quantifying Cr(VI) Production and Export from Serpentine Soil of the California Coast Range

    DOE PAGES

    McClain, Cynthia N.; Fendorf, Scott; Webb, Samuel M.; ...

    2016-11-22

    Here, hexavalent chromium (Cr(VI)) is generated in serpentine soils and exported to surface and groundwaters at levels above health-based drinking water standards. Although Cr(VI) concentrations are elevated in serpentine soil pore water, few studies have reported field evidence documenting Cr(VI) production rates and fluxes that govern Cr(VI) transport from soil to water sources. We report Cr speciation (i) in four serpentine soil depth profiles derived from the California Coast Range serpentinite belt and (ii) in local surface waters. Within soils, we detected Cr(VI) in the same horizons where Cr(III)-minerals are colocated with biogenic Mn(III/IV)-oxides, suggesting Cr(VI) generation through oxidation bymore » Mn-oxides. Water-extractable Cr(VI) concentrations increase with depth constituting a 7.8 to 12 kg/km 2 reservoir of Cr(VI) in soil. Here, Cr(VI) is produced at a rate of 0.3 to 4.8 kg Cr(VI)/km 2/yr and subsequently flushed from soil during water infiltration, exporting 0.01 to 3.9 kg Cr(VI)/km 2/yr at concentrations ranging from 25 to 172 μg/L. Although soil-derived Cr(VI) is leached from soil at concentrations exceeding 10 μg/L, due to reduction and dilution during transport to streams, Cr(VI) levels measured in local surface waters largely remain below California’s drinking water limit.« less

  10. [Treatment of wastewater containing Cr(VI) by LDH synthesizing in situ].

    PubMed

    Chen, Tian-hu; Feng, You-liang; Xu, Hui-fang; Peng, Shu-chuan; Huang, Chuan-hui; Tang, Shu-pei

    2004-03-01

    The objective of this work was to investigate the efficiency and factors impacting of removal Cr(VI) from wastewater by layer double hydroxide synthesizing in situ. Principle of the method may be described as follow: Mg2+ and Al3+ hydrolysis and forms Mg/Al-LDH by adding Mg2+, Al3+ and NaOH into wastewater containing Cr(VI), Cr(VI) anions are selectively intercalated into interlayer of LDH to balance positive structural charge. While Mg2+ and Al3+ co-precipitates and forms LDH, the Cr(VI) in wastewater is removal by settle of LDH synthesizing in situ, which are confirmed by analysis of X-ray diffraction on settle and chemical analysis on aqueous. The results indicate that factors of impacting on efficiency of removal Cr(VI) include in amount of adding Mg2+ and Al3+, Mg/Al ratio, pH and concentration of Cr(VI) in wastewater. The maximal removal efficiency of Cr(VI) can be reached when pH values are between 8.5 and 9, and Mg/Al ratios are between 1:1 and 2:1, meanwhile, Mg and Al added can be taken good use of. This technology has present extraordinary efficiency of wastewater treatment.

  11. Thermodynamic analysis of Cr(VI) extraction using TOPO impregnated membranes.

    PubMed

    Praveen, Prashant; Loh, Kai-Chee

    2016-08-15

    Solid/liquid extraction of Cr(VI) was accomplished using trioctylphosphine oxide impregnated polypropylene hollow fiber membranes. Extraction of 100-500mg/L Cr(VI) by the extractant impregnated membranes (EIM) was characterized by high uptake rate and capacity, and equilibrium was attained within 45min of contact. Extraction equilibrium was pH-dependent (at an optimal pH 2), whereas stripping using 0.2M sodium hydroxide yielded the highest recovery of 98% within 60min. The distribution coefficient was independent of initial Cr(VI) concentration, and the linear distribution equilibrium isotherm could be modeled using Freundlich isotherm. The mass transfer kinetics of Cr(VI) was examined using pseudo-second-order and intraparticle diffusion models and a mass transfer mechanism was deduced. The distribution coefficient increased with temperature, which indicated endothermic nature of the reaction. Enthalpy and entropy change during Cr(VI) extraction were positive and varied in the range of 37-49kJ/mol and 114-155J/mol, respectively. The free energy change was negative, confirming the feasibility and spontaneity of the mass transfer process. Results obtained suggest that EIMs are efficient and sustainable for extraction of Cr(VI) from wastewater. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Kinetics of reduction of plutonium(VI) and neptunium(VI) by sulfide in neutral and alkaline solutions

    USGS Publications Warehouse

    Nash, K.L.; Cleveland, J.M.; Sullivan, J.C.; Woods, M.

    1986-01-01

    The rate of reduction of plutonium(VI) and neptunium(VI) by bisulfide ion in neutral and mildly alkaline solutions has been investigated by the stopped-flow technique. The reduction of both of these ions to the pentavalent oxidation state appears to occur in an intramolecular reaction involving an unusual actinide(VI)-hydroxide-bisulfide complex. For plutonium the rate of reduction is 27.4 (??4.1) s-1 at 25??C with ??H* = +33.2 (??1.0) kJ/mol and ??S* = -106 (??4) J/(mol K). The apparent stability constant for the transient complex is 4.66 (??0.94) ?? 103 M-1 at 25??C with associated thermodynamic parameters of ??Hc = +27.7 (??0.4) kJ/mol and ??Sc = +163 (??2) J/(mol K). The corresponding rate and stability constants are determined for the neptunium system at 25??C (k3 = 139 (??30) s-1, Kc. = 1.31 (??0.32) ?? 103 M-1), but equivalent parameters cannot be determined at reduced temperatures. The reaction rate is decreased by bicarbonate ion. At pH > 10.5, a second reaction mechanism, also involving a sulfide complex, is indicated. ?? 1986 American Chemical Society.

  13. A highly selective chemiluminescent probe for the detection of chromium(VI)

    NASA Astrophysics Data System (ADS)

    Jin, Yan; Sun, Yonghua; Li, Chongying; Yang, Chao

    2018-03-01

    In present work, rhodamine B hydrazide and rhodamine 6G hydrazide were synthesized and the chemiluminescence performance has been investigated. Based on the chemiluminescence of rhodamine 6G hydrazide-chromium(VI), a selective and sensitive method for the direct detection of chromium(VI) was developed. The chemiluminescence intensity was linearly related to the concentration of chromium(VI) in the range of 2.60 × 10- 8-8.00 × 10- 6 mol/L with a correlation coefficient of r = 0.998 and a detection limit of 1.4 × 10- 8 mol/L (S/N = 3). The results indicated rhodamine 6G hydrazide was an excellent chemiluminescent probe for chromium(VI) without reduction of chromium(VI) to chromium(III). A possible mechanism of CL emission was also suggested.

  14. 31 CFR 356.4 - What are the book-entry systems in which auctioned Treasury securities may be issued or maintained?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 2 2013-07-01 2013-07-01 false What are the book-entry systems in... system) at their par amount. Par amounts of Treasury inflation-protected securities do not include... Circular, Public Debt Series No. 2-86, as amended (part 357 of this chapter) and part 363 of this chapter...

  15. 31 CFR 356.4 - What are the book-entry systems in which auctioned Treasury securities may be issued or maintained?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance: Treasury 2 2014-07-01 2014-07-01 false What are the book-entry systems in... system) at their par amount. Par amounts of Treasury inflation-protected securities do not include... Circular, Fiscal Service Series No. 2-86, as amended (part 357 of this chapter) and part 363 of this...

  16. Long-term diffusion of U(VI) in bentonite: Dependence on density

    DOE PAGES

    Joseph, Claudia; Mibus, Jens; Trepte, Paul; ...

    2016-10-12

    As a contribution to the safety assessment of nuclear waste repositories, U(VI) diffusion through the potential buffer material MX-80 bentonite was investigated at three clay dry densities over six years. Synthetic MX-80 model pore water was used as background electrolyte. Speciation calculations showed that Ca 2UO 2(CO 3) 3(aq) was the main U(VI) species. The in- and out-diffusion of U(VI) was investigated separately. U(VI) diffused about 3 mm, 1.5 mm, and 1 mm into the clay plug at ρ = 1.3, 1.6, and 1.9 g/cm 3, respectively. No through-diffusion of the U(VI) tracer was observed. However, leaching of natural uraniummore » contained in the clay occurred and uranium was detected in all receiving reservoirs. As expected, the effective and apparent diffusion coefficients, D e and D a, decreased with increasing dry density. The D a values for the out-diffusion of natural U(VI) were in good agreement with previously determined values. Surprisingly, D a values for the in-diffusion of U(VI) were about two orders of magnitude lower than values obtained in short-term in-diffusion experiments reported in the literature. Some potential reasons for this behavior that were evaluated are changes of the U(VI) speciation within the clay (precipitation, reduction) or changes of the clay porosity and pore connectivity with time. By applying Archie's law and the extended Archie's law, it was estimated that a significantly smaller effective porosity must be present for the long-term in-diffusion of U(VI). Finally, the results suggest that long-term studies of key transport phenomena may reveal additional processes that can directly impact long-term repository safety assessments.« less

  17. HNO3 modified biochars for uranium (VI) removal from aqueous solution.

    PubMed

    Jin, Jie; Li, Shiwei; Peng, Xianqiang; Liu, Wei; Zhang, Chenlu; Yang, Yan; Han, Lanfang; Du, Ziwen; Sun, Ke; Wang, Xiangke

    2018-05-01

    The HNO 3 treatment was used to chemically modify the biochars produced from wheat straw (WH) and cow manure for U(VI) removal from aqueous solution. Macroscopic experiments proved that the enrichment of U(VI) on the biochars was regulated by surface complexation and electrostatic interactions. FTIR and XPS analyses confirmed that the highly efficient adsorption of U(VI) was due to the carboxyl groups on the biochar surfaces. The reducing agents of the R-CH 2 OH groups facilitated U(VI) adsorption on the untreated biochars. Owing to the higher contents of surface COO groups and more negative surface charge, the modified biochars showed enhanced U(VI) adsorption ability than the untreated ones. The maximum adsorption capacity of U(VI) by the oxidized WH was calculated to be 355.6 mg/g at pH 4.5 and 298 K, which was an improvement of 40 times relative to the untreated WH and was higher than that of most carbon-based adsorbents. Copyright © 2018 Elsevier Ltd. All rights reserved.

  18. Regulations of the United States Geological Survey

    USGS Publications Warehouse

    ,

    1903-01-01

    The following regulation have been prepared for the guidance of officers and employees of the United States Geological Survey. They are derived in large part from statute law, from decisions of the accounting officers of the Treasury Department, and from official circulars of the Department of the Interior. It is believed that close adherence to these directions will prove helpful to all members of the Geological Survey. This manual of "Regulations," approved by the Secretary, is intended to cover the more important matters relating to the general administrative work of the Survey. A separate series of "Instructions" is issued by the Director for the guidance of the various field assistants and party chiefs.

  19. Clinical evaluation of complete solo surgery with the "ViKY®" robotic laparoscope manipulator.

    PubMed

    Takahashi, Masahiro; Takahashi, Masanori; Nishinari, Naoto; Matsuya, Hideki; Tosha, Tsutomu; Minagawa, Yukihiro; Shimooki, Osamu; Abe, Tadashi

    2017-02-01

    Advancement in both surgical technique and medical equipment has enabled solo surgery. ViKY ® Endoscope Positioning System (ViKY ® ) is a robotic system that remotely controls an endoscope and provides direct vision control to the surgeon. Here, we report our experience with ViKY ® -assisted solo surgery. We retrospectively examined 25 cases of solo surgery TAPP with ViKY ® . ViKY ® was setup by the surgeon alone, and the setup duration was determined as the time at which the side rail was positioned and that when the endoscope was installed. For assessing the control unit, the number of false movements was counted. We compared the operative results between ViKY ® -assisted solo surgery TAPP and the conventional method with an assistant. The average time to set up ViKY ® was 7.9 min. The average number of commands for ViKY ® during surgery was 98.3, and the average number of errors and no response of control unit was 7.9. The mean duration of surgery was 136 min for the ViKY ® group, including the setup time, and 117 min for the conventional method. No case required an assistant during the operation. There was also no difference between the two groups with regard to postoperative complications and the rate of recurrence. ViKY ® proved reliable in recognizing orders with very few failures, and the operations were performed safely and were comparable to the conventional operations with assistants. Solo surgery with ViKY ® was beneficial in this clinical evaluation.

  20. Treatment of Alkaline Cr(VI)-Contaminated Leachate with an Alkaliphilic Metal-Reducing Bacterium.

    PubMed

    Watts, Mathew P; Khijniak, Tatiana V; Boothman, Christopher; Lloyd, Jonathan R

    2015-08-15

    Chromium in its toxic Cr(VI) valence state is a common contaminant particularly associated with alkaline environments. A well-publicized case of this occurred in Glasgow, United Kingdom, where poorly controlled disposal of a cementitious industrial by-product, chromite ore processing residue (COPR), has resulted in extensive contamination by Cr(VI)-contaminated alkaline leachates. In the search for viable bioremediation treatments for Cr(VI), a variety of bacteria that are capable of reduction of the toxic and highly soluble Cr(VI) to the relatively nontoxic and less mobile Cr(III) oxidation state, predominantly under circumneutral pH conditions, have been isolated. Recently, however, alkaliphilic bacteria that have the potential to reduce Cr(VI) under alkaline conditions have been identified. This study focuses on the application of a metal-reducing bacterium to the remediation of alkaline Cr(VI)-contaminated leachates from COPR. This bacterium, belonging to the Halomonas genus, was found to exhibit growth concomitant to Cr(VI) reduction under alkaline conditions (pH 10). Bacterial cells were able to rapidly remove high concentrations of aqueous Cr(VI) (2.5 mM) under anaerobic conditions, up to a starting pH of 11. Cr(VI) reduction rates were controlled by pH, with slower removal observed at pH 11, compared to pH 10, while no removal was observed at pH 12. The reduction of aqueous Cr(VI) resulted in the precipitation of Cr(III) biominerals, which were characterized using transmission electron microscopy and energy-dispersive X-ray analysis (TEM-EDX) and X-ray photoelectron spectroscopy (XPS). The effectiveness of this haloalkaliphilic bacterium for Cr(VI) reduction at high pH suggests potential for its use as an in situ treatment of COPR and other alkaline Cr(VI)-contaminated environments. Copyright © 2015, Watts et al.

  1. 32 CFR 274.9 - Delegation of authority to the Secretary of the Treasury.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 32 National Defense 2 2010-07-01 2010-07-01 false Delegation of authority to the Secretary of the Treasury. 274.9 Section 274.9 National Defense Department of Defense (Continued) OFFICE OF THE SECRETARY OF DEFENSE (CONTINUED) MISCELLANEOUS REGULATIONS GOVERNING COMPETITIVE BIDDING ON U.S. GOVERNMENT GUARANTEED...

  2. 32 CFR 274.9 - Delegation of authority to the Secretary of the Treasury.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 32 National Defense 2 2011-07-01 2011-07-01 false Delegation of authority to the Secretary of the Treasury. 274.9 Section 274.9 National Defense Department of Defense (Continued) OFFICE OF THE SECRETARY OF DEFENSE (CONTINUED) MISCELLANEOUS REGULATIONS GOVERNING COMPETITIVE BIDDING ON U.S. GOVERNMENT GUARANTEED...

  3. A study of the kinetics and isotherms for Cr(VI) adsorption in a binary mixture of Cr(VI)-Ni(II) using hierarchical porous carbon obtained from pig bone.

    PubMed

    Li, Chengxian; Huang, Zhe; Huang, Bicheng; Liu, Changfeng; Li, Chengming; Huang, Yaqin

    2014-01-01

    Cr(VI) adsorption in a binary mixture Cr(VI)-Ni(II) using the hierarchical porous carbon prepared from pig bone (HPC) was investigated. The various factors affecting adsorption of Cr(VI) ions from aqueous solutions such as initial concentration, pH, temperature and contact time were analyzed. The results showed excellent efficiency of Cr(VI) adsorption by HPC. The kinetics and isotherms for Cr(VI) adsorption from a binary mixture Cr(VI)-Ni(II) by HPC were studied. The adsorption equilibrium described by the Langmuir isotherm model is better than that described by the Freundlich isotherm model for the binary mixture in this study. The maximum adsorption capacity was reliably found to be as high as 192.68 mg/g in the binary mixture at pH 2. On fitting the experimental data to both pseudo-first- and second-order equations, the regression analysis of the second-order equation gave a better R² value.

  4. New drainage tunnel of the tunnel Višňové - design and excavation

    NASA Astrophysics Data System (ADS)

    Jurík, Igor; Grega, Ladislav; Valko, Jozef; Janega, Peter

    2017-09-01

    The actual pilot tunnel dated to the period of geological and hydrogeological survey, is designed as a part of the tunnel Višňové, which is located at the section of the D1 motorway Lietavská Lúčka - Višňové - Dubná Skala in Slovakia. Drainage tunnel will be used for the drainage of the main tunnel tubes, where the maximum inflow from the eastern portal is greater than 250 l.s-1. Overlapping of the initial pilot tunnel with the profile of the southern tunnel tube led to the demolition of the portal sections of the pilot tunnel during the excavation of main tunnel tubes. These sections were replaced by new drainage tunnels, with the lengths of 288.0 meters from west portal and 538.0 meters from eastern portal, to ensure access from both portals. The new drainage tunnel is excavated under the level of the two main tunnel tubes. Drainage pipes with a diameter of 250 mm will be installed from cleaning niches in the main tunnel tubes to the new drainage tunnel.

  5. Multi-crystalline II-VI based multijunction solar cells and modules

    DOEpatents

    Hardin, Brian E.; Connor, Stephen T.; Groves, James R.; Peters, Craig H.

    2015-06-30

    Multi-crystalline group II-VI solar cells and methods for fabrication of same are disclosed herein. A multi-crystalline group II-VI solar cell includes a first photovoltaic sub-cell comprising silicon, a tunnel junction, and a multi-crystalline second photovoltaic sub-cell. A plurality of the multi-crystalline group II-VI solar cells can be interconnected to form low cost, high throughput flat panel, low light concentration, and/or medium light concentration photovoltaic modules or devices.

  6. 31 CFR 363.138 - Is Treasury liable for the purchase of a zero-percent certificate of indebtedness that is made in...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... a zero-percent certificate of indebtedness that is made in error? 363.138 Section 363.138 Money and... TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.138 Is Treasury liable for the purchase of a zero-percent...

  7. 31 CFR 363.138 - Is Treasury liable for the purchase of a zero-percent certificate of indebtedness that is made in...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... a zero-percent certificate of indebtedness that is made in error? 363.138 Section 363.138 Money and... TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.138 Is Treasury liable for the purchase of a zero-percent...

  8. 31 CFR 363.138 - Is Treasury liable for the purchase of a zero-percent certificate of indebtedness that is made in...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... a zero-percent certificate of indebtedness that is made in error? 363.138 Section 363.138 Money and... TREASURY BUREAU OF THE PUBLIC DEBT REGULATIONS GOVERNING SECURITIES HELD IN TREASURYDIRECT Zero-Percent Certificate of Indebtedness General § 363.138 Is Treasury liable for the purchase of a zero-percent...

  9. Uranium(VI) adsorption to ferrihydrite: Application of a surface complexation model

    USGS Publications Warehouse

    Waite, T.D.; Davis, J.A.; Payne, T.E.; Waychunas, G.A.; Xu, N.

    1994-01-01

    A study of U(VI) adsorption by ferrihydrite was conducted over a wide range of U(VI) concentrations, pH, and at two partial pressures of carbon dioxide. A two-site (strong- and weak-affinity sites, FesOH and FewOH, respectively) surface complexation model was able to describe the experimental data well over a wide range of conditions, with only one species formed with each site type: an inner-sphere, mononuclear, bidentate complex of the type (FeO2)UO2. The existence of such a surface species was supported by results of uranium EXAFS spectroscopy performed on two samples with U(VI) adsorption density in the upper range observed in this study (10 and 18% occupancy of total surface sites). Adsorption data in the alkaline pH range suggested the existence of a second surface species, modeled as a ternary surface complex with UO2CO30 binding to a bidentate surface site. Previous surface complexation models for U(VI) adsorption have proposed surface species that are identical to the predominant aqueous species, e.g., multinuclear hydrolysis complexes or several U(VI)-carbonate complexes. The results demonstrate that the speciation of adsorbed U(VI) may be constrained by the coordination environment at the surface, giving rise to surface speciation for U(VI) that is significantly less complex than aqueous speciation.

  10. 24 CFR 972.115 - Relationship between required conversions and HOPE VI developments.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... conversions and HOPE VI developments. 972.115 Section 972.115 Housing and Urban Development Regulations... Relationship between required conversions and HOPE VI developments. HUD actions to approve or deny proposed HOPE VI revitalization plans must be consistent with the requirements of this subpart. Developments...

  11. Ferrate(VI) oxidation of polychlorinated diphenyl sulfides: Kinetics, degradation, and oxidized products.

    PubMed

    Chen, Jing; Xu, Xinxin; Zeng, Xiaolan; Feng, Mingbao; Qu, Ruijuan; Wang, Zunyao; Nesnas, Nasri; Sharma, Virender K

    2018-06-13

    This paper presents oxidation of polychlorinated diphenyl sulfides (PCDPSs), dioxin-like compounds, by ferrate(VI) (Fe VI O 4 2- , Fe(VI)). Kinetics of the reactions of Fe(VI) with seventeen PCDPSs, differ in number and positions of chlorine atoms (from 2 to 7), were investigated at pH 8.0. The second-order rate constants (k, M -1 s -1 ) of the reactions varied with the numbers and positions of chlorine atoms and appeared to be related with standard Gibbs free energy of formation (Δ f G 0 ) of PCDPSs. Degradation experiments in the presence of ions and humic acid demonstrated complete removal of PeCDPS by Fe(VI) in minutes. Pathways of the reaction were investigated by identifying oxidized products (OPs) of the reaction between Fe(VI) and 2,2',3',4,5-pentachlorodiphenyl sulfide (PeCDPS) at pH 8.0. Pathways of oxidation involved major pathway of attack on sulfur(II) by Fe(VI) in steps to yield sulfoxide type products, and subsequent breakage of C-S bond with the formation of sulfonic acid-containing trichloro compound. Minor pathways were hydroxylation of benzene ring and substitution of chlorine atom with hydroxyl group. Estimation of toxicity of OPs of the oxidation of PeCDPS by Fe(VI) suggested the decreased toxicity from the parent contaminant. Copyright © 2018. Published by Elsevier Ltd.

  12. Enhanced Cr(VI) removal by polyethylenimine- and phosphorus-codoped hierarchical porous carbons.

    PubMed

    Chen, Shixia; Wang, Jun; Wu, Zeliang; Deng, Qiang; Tu, Wenfeng; Dai, Guiping; Zeng, Zheling; Deng, Shuguang

    2018-08-01

    The amino- and phosphorus-codoped (N,P-codoped) porous carbons derived from oil-tea shells were facilely fabricated through a combination of phosphoric acid (H 3 PO 4 ) activation and amino (polyethylenimine, PEI) modification method. The as-synthesized carbon adsorbents were systematically characterized and evaluated for Cr(VI) removal in aqueous solutions. The relationship between adsorbent properties and adsorption behaviors was illustrated. Moreover, the influences of contact time, initial Cr(VI) concentration, pH, coexisting anions and temperature were also investigated. The adsorption behavior of Cr(VI) could be perfectly described by the pseudo-second-order kinetic model and Sips adsorption model. The maximum adsorption capacity of Cr(VI) on the carbon adsorbents synthesized in this work was 355.0 mg/g, and this excellent Cr(VI) capacity could be sustained with other coexisting anions. In addition to high surface area and suitable pore size distribution, the high Cr(VI) removal capacity is induced by rich heteroatoms incorporation and the Cr(VI) removal mechanism was clearly illustrated. Furthermore, the continuous column breakthrough experiment on obtained N,P-codoped carbon was conducted and well fitted by the Thomas model. This work revealed that PEI modification and P-containing groups could significantly enhance Cr(VI) adsorption capacity and make these N,P-codoped biomass-derived carbons potent adsorbents in practical water treatment applications. Copyright © 2018 Elsevier Inc. All rights reserved.

  13. 77 FR 15319 - Treasury Inflation-Protected Securities Issued at a Premium; Hearing Cancellation

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-15

    ... in testifying at the public hearing to submit a request to speak and an outline of the topics to be addressed. As of Monday, March 12, 2012, no one has requested to speak. Therefore, the public hearing... Service (IRS), Treasury. ACTION: Cancellation of notice of public hearing on proposed rulemaking. SUMMARY...

  14. Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization.

    PubMed

    Cao, Bin; Ahmed, Bulbul; Kennedy, David W; Wang, Zheming; Shi, Liang; Marshall, Matthew J; Fredrickson, Jim K; Isern, Nancy G; Majors, Paul D; Beyenal, Haluk

    2011-07-01

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.

  15. Inactivation of bacteriophage MS2 with potassium ferrate(VI).

    PubMed

    Hu, Lanhua; Page, Martin A; Sigstam, Therese; Kohn, Tamar; Mariñas, Benito J; Strathmann, Timothy J

    2012-11-06

    Ferrate [Fe(VI); FeO(4)(2-)] is an emerging oxidizing agent capable of controlling chemical and microbial water contaminants. Here, inactivation of MS2 coliphage by Fe(VI) was examined. The inactivation kinetics observed in individual batch experiments was well described by a Chick-Watson model with first-order dependences on disinfectant and infective phage concentrations. The inactivation rate constant k(i) at a Fe(VI) dose of 1.23 mgFe/L (pH 7.0, 25 °C) was 2.27(±0.05) L/(mgFe × min), corresponding to 99.99% inactivation at a Ct of ~4 (mgFe × min)/L. Measured k(i) values were found to increase with increasing applied Fe(VI) dose (0.56-2.24 mgFe/L), increasing temperature (5-30 °C), and decreasing pH conditions (pH 6-11). The Fe(VI) dose effect suggested that an unidentified Fe byproduct also contributed to inactivation. Temperature dependence was characterized by an activation energy of 39(±6) kJ mol(-1), and k(i) increased >50-fold when pH decreased from 11 to 6. The pH effect was quantitatively described by parallel reactions with HFeO(4)(-) and FeO(4)(2-). Mass spectrometry and qRT-PCR analyses demonstrated that both capsid protein and genome damage increased with the extent of inactivation, suggesting that both may contribute to phage inactivation. Capsid protein damage, localized in the two regions containing oxidant-sensitive cysteine residues, and protein cleavage in one of the two regions may facilitate genome damage by increasing Fe(VI) access to the interior of the virion.

  16. Research progress in the use of ferrate(VI) for the environmental remediation.

    PubMed

    Jiang, J Q

    2007-07-31

    The aim of this paper is to review the research progress of using ferrate(VI) in following fields of environmental remediation: (1) water disinfection; (2) degradation of synthetic organic pollutants; (3) treatment of emerging organic pollutants; (4) oxidation of inorganic pollutants; (5) removing humic substance; (6) wastewater treatment and disinfection; and (7) sewage sludge treatment. Whilst the superior performance of potassium ferrate(VI) as an oxidant/disinfectant for the environmental remediation has been demonstrated in various recent researches, challenges have existed to the implementation of ferrate(VI) technology in full-scale water, wastewater and sewage sludge treatment owing to either the instability property of a ferrate(VI) solution or a high preparation cost of a solid ferrate(VI). In addition to this, there are some fundamental issues which have not yet been studied thoroughly which are crucial for the implementation of ferrate(VI)-these lead to the future research work recommended by this paper.

  17. Characterization of U(VI)-carbonato ternary complexes on hematite: EXAFS and electrophoretic mobility measurements

    USGS Publications Warehouse

    Bargar, John R.; Reitmeyer, Rebecca; Lenhart, John J.; Davis, James A.

    2000-01-01

    We have measured U(VI) adsorption on hematite using EXAFS spectroscopy and electrophoresis under conditions relevant to surface waters and aquifers (0.01 to 10 μM dissolved uranium concentrations, in equilibrium with air, pH 4.5 to 8.5). Both techniques suggest the existence of anionic U(VI)-carbonato ternary complexes. Fits to EXAFS spectra indicate that U(VI) is simultaneously coordinated to surface FeO6 octahedra and carbonate (or bicarbonate) ligands in bidentate fashions, leading to the conclusion that the ternary complexes have an inner-sphere metal bridging (hematite-U(VI)-carbonato) structure. Greater than or equal to 50% of adsorbed U(VI) was comprised of monomeric hematite-U(VI)-carbonato ternary complexes, even at pH 4.5. Multimeric U(VI) species were observed at pH ≥ 6.5 and aqueous U(VI) concentrations approximately an order of magnitude more dilute than the solubility of crystalline β-UO2(OH)2. Based on structural constraints, these complexes were interpreted as dimeric hematite-U(VI)-carbonato ternary complexes. These results suggest that Fe-oxide-U(VI)-carbonato complexes are likely to be important transport-limiting species in oxic aquifers throughout a wide range of pH values.

  18. Cr(VI) Adsorption on Red Mud Modified by Lanthanum: Performance, Kinetics and Mechanisms

    PubMed Central

    Cui, You-Wei; Li, Jie; Du, Zhao-Fu; Peng, Yong-Zhen

    2016-01-01

    Water pollution caused by the highly toxic metal hexavalent chromium (Cr(VI)) creates significant human health and ecological risks. In this study, a novel adsorbent was used to treat Cr(VI)-containing wastewater; the adsorbent was prepared using red mud (RM) generated from the alumina production industry and the rare earth element lanthanum. This study explored adsorption performance, kinetics, and mechanisms. Results showed that the adsorption kinetics of the RM modified by lanthanum (La-RM), followed the pseudo-second-order model, with a rapid adsorption rate. Cr(VI) adsorption was positively associated with the absorbent dose, pH, temperature, and initial Cr(VI) concentration; coexisting anions had little impact. The maximum Cr(VI) adsorption capacity was 17.35 mg/g. Cr(VI) adsorption on La-RM was a mono-layer adsorption pattern, following the Langmuir isotherm model. Thermodynamic parameters showed the adsorption was spontaneous and endothermic. The adsorption of Cr(VI) on La-RM occurred as a result of LaOCl formation on the RM surface, which in turn further reacted with Cr(VI) in the wastewater. This study highlighted a method for converting industrial waste into a valuable material for wastewater treatment. The novel absorbent could be used as a potential adsorbent for treating Cr(VI)-contaminating wastewater, due to its cost-effectiveness and high adsorption capability. PMID:27658113

  19. THE PANCHROMATIC HUBBLE ANDROMEDA TREASURY. X. ULTRAVIOLET TO INFRARED PHOTOMETRY OF 117 MILLION EQUIDISTANT STARS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Williams, Benjamin F.; Dalcanton, Julianne J.; Weisz, Daniel R.

    We have measured stellar photometry with the Hubble Space Telescope Wide Field Camera 3 (WFC3) and Advanced Camera for Surveys in near ultraviolet (F275W, F336W), optical (F475W, F814W), and near infrared (F110W, F160W) bands for 117 million resolved stars in M31. As part of the Panchromatic Hubble Andromeda Treasury survey, we measured photometry with simultaneous point-spread function (PSF) fitting across all bands and at all source positions after precise astrometric image alignment (<5-10 mas accuracy). In the outer disk, the photometry reaches a completeness-limited depth of F475W ∼ 28, while in the crowded, high surface brightness bulge, the photometry reachesmore » F475W ∼ 25. We find that simultaneous photometry and optimized measurement parameters significantly increase the detection limit of the lowest-resolution filters (WFC3/IR) providing color-magnitude diagrams (CMDs) that are up to 2.5 mag deeper when compared with CMDs from WFC3/IR photometry alone. We present extensive analysis of the data quality including comparisons of luminosity functions and repeat measurements, and we use artificial star tests to quantify photometric completeness, uncertainties and biases. We find that the largest sources of systematic error in the photometry are due to spatial variations in the PSF models and charge transfer efficiency corrections. This stellar catalog is the largest ever produced for equidistant sources, and is publicly available for download by the community.« less

  20. Cr(VI) remediation by enriched sediment with anthraquinone-2,6-disulfonate as electron shuttles

    NASA Astrophysics Data System (ADS)

    Chen, Hong; Li, Xiaojuan; Xu, Zhiwei

    Hexavalent chromium (Cr(VI)) is a priority pollutant in the USA and many other countries. This study investigated the simultaneous remediation of Cr(VI) in sediment enriched with quinone-reducing microorganisms via a closely coupled, biotic-abiotic pathway. The results showed that Cr(VI) remediation was achieved by sediment adsorption and reduction of quinone-reducing microorganism. Moreover, microorganism reduction of Cr(VI) could be continued when sediment adsorption was saturated after long-term Cr(VI) remediation. The acetate and anthraquinone-2,6-disulfonate (AQDS), which acted as exogenous carbon and electron shuttle, respectively, were two crucial factors. The optimum concentrations of acetate and AQDS were 5 mM and 1 mM when the initial Cr(VI) concentration was 10 mg/L. AQDS was recycled, and it acted in a catalytic-type manner for the bacterial reduction of Cr(VI). Thus, biological humus reduction might provide an extensive pathway for the sequestration and detoxification of Cr(VI) in anaerobic soils, water, and industrial effluents.

  1. Intervening O vi Quasar Absorption Systems at Low Redshift: A Significant Baryon Reservoir.

    PubMed

    Tripp; Savage; Jenkins

    2000-05-01

    Far-UV echelle spectroscopy of the radio-quiet QSO H1821+643 (zem=0.297), obtained with the Space Telescope Imaging Spectrograph (STIS) at approximately 7 km s-1 resolution, reveals four definite O vi absorption-line systems and one probable O vi absorber at 0.15vi absorbers are located near galaxies and are highly displaced from the quasar in redshift; these are likely intervening systems unrelated to the background QSO. In the case of the strong O vi system at zabs=0.22497, multiple components are detected in Si iii and O vi as well as H i Lyman series lines, and the differing component velocity centroids and b-values firmly establish that this is a multiphase absorption system. A weak O vi absorber is detected at zabs=0.22637, i.e., offset by approximately 340 km s-1 from the zabs=0.22497 system. Lyalpha absorption is detected at zabs=0.22613, but no Lyalpha absorption is significantly detected at 0.22637. Other weak O vi absorbers at zabs=0.24531 and 0.26659 and the probable O vi system at 0.21326 have widely diverse O vi/H i column density ratios with N(O vi)/N(H i) ranging from vi absorbers with rest equivalent width greater than 30 mÅ in the H1821+643 spectrum is remarkably high, dN&solm0;dz approximately 48, which implies with a high (90%) confidence that it is greater than 17 in the low-redshift intergalactic medium. We conservatively estimate that the cosmological mass density of the O vi systems is Omegab(Ovi&parr0; greater, similar0.0008 h-175. With an assumed metallicity of 1/10 solar and a conservative assumption that the fraction of oxygen in the O vi ionization stage is 0.2, we obtain Omegab(Ovi&parr0; greater, similar0.004 h-175. This is comparable to the combined cosmological mass density of stars and cool gas in galaxies and X-ray-emitting gas in galaxy clusters at low redshift.

  2. Contribution of Extracellular Polymeric Substances from Shewanella sp. HRCR-1 Biofilms to U(VI) Immobilization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cao, Bin; Ahmed, B.; Kennedy, David W.

    2011-06-05

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) in U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells without EPS, we showed that i) bEPS from Shewanella sp. HRCR-1 biofilms contributed significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; ii) bEPS could be considered as a functional extension of the cells for U(VI) immobilization and they likely play more important roles at initial U(VI) concentrations; and iii) U(VI) reduction efficiency was found to be dependent uponmore » initial U(VI) concentration and the efficiency decreased at lower concentrations. To quantify relative contribution of sorption and reduction in U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(V). We found that, when in reduced form, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated reactivity of laEPS while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, might facilitate U(VI) reduction.« less

  3. Bicarbonate Impact on U(VI) Bioreduction in a Shallow Alluvial Aquifer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Long, Philip E.; Williams, Kenneth H.; Davis, James A.

    Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al. 2003, Williams et al. 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al. 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggestedmore » the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, that the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ~3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in aquifers.« less

  4. Bicarbonate impact on U(VI) bioreduction in a shallow alluvial aquifer

    NASA Astrophysics Data System (ADS)

    Long, Philip E.; Williams, Kenneth H.; Davis, James A.; Fox, Patricia M.; Wilkins, Michael J.; Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.; Berman, Elena S. F.; Gupta, Manish; Chandler, Darrell P.; Murray, Chris; Peacock, Aaron D.; Giloteaux, Ludovic; Handley, Kim M.; Lovley, Derek R.; Banfield, Jillian F.

    2015-02-01

    Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al., 2003; Williams et al., 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al., 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggested the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer sediments desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ∼3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction in the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in

  5. [Kinetics modeling and reaction mechanism of ferrate(VI) oxidation of triclosan].

    PubMed

    Yang, Bin; Ying, Guang-Guo; Zhao, Jian-Liang

    2011-09-01

    Triclosan (TCS) is a broad-spectrum antibacterial agent widely used in many personal care products. We investigated oxidation of TCS by aqueous ferrate Fe(VI) to determine reaction kinetics, interpreted the reaction mechanism by a linear free-energy relationship, and evaluated the degradation efficiency. Second-order reaction kinetics was used to model Fe (VI) oxidation of TCS, with the apparent second-order rate constant (k(app)) being 531.9 L x (mol x s)(-1) at pH 8.5 and (24 +/- 1) degrees C. The half life (t1/2) is 25.8 s for an Fe( VI) concentration of 10 mg x L(-1). The rate constants of the reaction decrease with increasing pH values. These pH-dependent variations in k(app) could be distributed by considering species-specific reactions between Fe(VI) species and acid-base species of an ionizable TCS. Species-specific second-order reaction rate constants, k, were determined for reaction of HFeO4(-) with each of TCS's acid-base species. The value of k determined for neutral TCS was (4.1 +/- 3.5) x 10(2) L x (mol x s)(-1), while that measured for anionic TCS was (1.8 +/- 0.1) x 10(4) L x (mol x s)(-1). The reaction between HFeO4(-) and the dissociated TCS controls the overall reaction. A linear free-energy relationship illustrated the electrophilic oxidation mechanism. Fe (VI) reacts initially with TCS by electrophilic attack at the latter's phenol moiety. At a n[Fe(VI)]: n(TCS) > 7: 1, complete removal of TCS was achieved. And lower concentration of the humic acid could enhance the k(app) of Fe( VI) with TCS. In conclusion, Fe(VI) oxidation technology appears to be a promising tool for applications of WWTPs effluents and other decontamination processes.

  6. Hereditary motor and sensory neuropathy type VI with optic atrophy.

    PubMed

    Voo, Irene; Allf, Bryan E; Udar, Nitin; Silva-Garcia, Rosamaria; Vance, Jeffrey; Small, Kent W

    2003-10-01

    To present the detailed clinical findings of a large family with hereditary motor and sensory neuropathy type VI (HMSN VI), a syndrome featuring optic atrophy. Observational case series. A detailed history was obtained and physical examination was made of the extended family of the proband for evidence of neurologic dysfunction. The OPA1 gene was screened for mutations by direct DNA sequencing. Twelve of 97 family members examined are affected with signs of HMSN VI. Three other members have either optic atrophy or peripheral neuropathy, thus allowing an appreciation of the full clinical spectrum of disease. No mutations were found in the OPA1 gene. This family demonstrates the variable expressivity of this disorder as well as incomplete penetrance. This is the largest known family with HMSN VI. No association was found with changes in the OPA1 gene.

  7. Determination of Cr(III) solids formed by reduction of Cr(VI) in a contaminated fractured bedrock aquifer: evidence for natural attenuation of Cr(VI)

    EPA Science Inventory

    Hexavalent chromium Cr(VI) is toxic and can be highly mobile in many aquifer systems. Redox reactions with naturally occurring minerals and organic compounds can reduce Cr(VI) to Cr(III), forming labile Cr(III) oxyhydroxide precipitates, which is a natural attenuation process. In...

  8. Enhanced abiotic reduction of Cr(VI) in a soil slurry system by natural biomaterial addition.

    PubMed

    Park, Donghee; Ahn, Chi Kyu; Kim, Young Mi; Yun, Yeoung-Sang; Park, Jong Moon

    2008-12-30

    Among various plant-based natural biomaterials, pine bark was chosen as an efficient biomaterial capable of removing toxic Cr(VI) from aqueous solution. XPS spectra indicated that Cr(VI) was abiotically reduced to Cr(III) in both liquid and solid phases. The Cr(VI)-reducing capacity of pine bark was determined as 545 (+/-1.3)mg-Cr(VI)g(-1) of it, which was 8.7 times higher than that of a common chemical Cr(VI)-reductant, FeSO4 x 7H2O. Because pine bark could completely reduce toxic Cr(VI) to less toxic or nontoxic Cr(III) even at neutral pH, it was used as an organic reductant to remediate Cr(VI)-contaminated soil in this study. Soil slurry system using a bottle roller was applied to ex situ slurry-phase remediation experiments. In the soil slurry system, pine bark completely reduced Cr(VI) to Cr(III) and adsorbed the reduced-Cr(III) on its surface. Abiotic remediation rate of Cr(VI)-contaminated soil increased with the increase of pine bark dosage and with the decreases of Cr(VI) and water contents. In conclusion, pine bark can be used to remediate Cr(VI)-contaminated soil efficiently and environmentally friendly.

  9. Cr(VI) Occurrence and Geochemistry in Water From Public-Supply Wells in California

    DOE PAGES

    Izbicki, John A.; Wright, Michael T.; Seymour, Whitney A.; ...

    2015-08-18

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment Program—Priority Basin Project (GAMA—PBP) ranged from less than the study reporting limit (SRL) of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of sampled wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of sampled wells. Cr(VI) data collected for regulatory purposes overestimate Cr(VI) occurrence. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and atmore » higher concentrations in alkaline (pH > 8), oxic water, and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium abundance in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.« less

  10. Cr(VI) occurrence and geochemistry in water from public-supply wells in California

    USGS Publications Warehouse

    Izbicki, John; Wright, Michael; Seymour, Whitney A.; McCleskey, R. Blaine; Fram, Miranda S.; Belitz, Kenneth; Esser, Bradley K.

    2015-01-01

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment-Priority Basin Project (GAMA-PBP) ranged from less than the study reporting limit of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of wells. Cr(VI) data collected for regulatory purposes overestimated Cr(VI) occurrence compared to spatially-distributed GAMA-PBP data. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and at higher concentrations in alkaline (pH ≥ 8), oxic water; and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that can mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.

  11. Characterization of the biochemical-pathway of uranium (VI) reduction in facultative anaerobic bacteria.

    PubMed

    Mtimunye, Phalazane J; Chirwa, Evans M N

    2014-10-01

    Cultures of U(VI) reducing bacteria sourced from abandoned uranium mine tailing dam were evaluated for their ability to reduce U(VI) to U(IV). The species in the cultures reduced U(VI) in solutions with initial U(VI) concentration up to 400mgL(-)(1) under a near neutral pH of 6.5. The electron flow pathway and fate of reduced species was also analysed in the individual species in order to evaluate the potential for control and optimisation of the reduction potential at the biochemical level. The results showed that U(VI) reduction in live cells was completely blocked by the NADH-dehydrogenase inhibitor, rotenone (C23H22O6), and thioredoxin inhibitor, cadmium chloride (CdCl2), showing that U(VI) reduction involves the electron flow through NADH-dehydrogenase, a primary electron donor to the electron transport respiratory (ETR) system. Mass balance analysis of uranium species aided by visual and electron microscopy suggest that most U(VI) reduction occurred on the cell surface of the isolated species. This finding indicates the possibility of easy uranium recovery for beneficial use through biological remediation. Should the U(VI) be reduced inside the cell, recovery would require complete disruption of the cells and therefore would be difficult. The study contributes new knowledge on the underlying mechanisms in the U(VI) reduction in facultative anaerobes. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. 31 CFR 357.2 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND LEGACY TREASURY DIRECT General... the claimant for another Person to hold, transfer, or deal with the Security. Bill means an obligation... an entity described in section 19(b)(1)(A)(i)-(vi) of the Federal Reserve Act (12 U.S.C. 461(b)(1)(A...

  13. 31 CFR 357.2 - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND LEGACY TREASURY DIRECT General... the claimant for another Person to hold, transfer, or deal with the Security. Bill means an obligation... an entity described in section 19(b)(1)(A)(i)-(vi) of the Federal Reserve Act (12 U.S.C. 461(b)(1)(A...

  14. 31 CFR 357.2 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., NOTES AND BILLS HELD IN TREASURY/RESERVE AUTOMATED DEBT ENTRY SYSTEM (TRADES) AND LEGACY TREASURY DIRECT... the rights of the claimant for another Person to hold, transfer, or deal with the Security. Bill means... means an entity described in section 19(b)(1)(A)(i)-(vi) of the Federal Reserve Act (12 U.S.C. 461(b)(1...

  15. Mobilization of Cr(VI) from chromite ore processing residue through acid treatment.

    PubMed

    Tinjum, James M; Benson, Craig H; Edil, Tuncer B

    2008-02-25

    Batch leaching studies on chromite ore processing residue (COPR) were performed using acids to investigate leaching of hexavalent chromium, Cr(VI), with respect to particle size, reaction time, and type of acid (HNO(3) and H(2)SO(4)). Aqueous Cr(VI) is maximized at approximately 0.04 mol Cr(VI) per kg of dry COPR at pH 7.6-8.1. Cr(VI) mobilized more slowly for larger particles, and the pH increased with time and increased more rapidly for smaller particles, suggesting that rate limitations occur in the solid phase. With H(2)SO(4), the pH stabilized at a higher value (8.8 for H(2)SO(4) vs. 8.0 for HNO(3)) and more rapidly (16 h vs. 30 h), and the differences in pH for different particle sizes were smaller. The acid neutralization capacity (ANC) of COPR is very large (8 mol HNO(3) per kg of dry COPR for a stable eluate pH of 7.5). Changes to the elemental and mineralogical composition and distribution in COPR particles after mixing with acid indicate that Cr(VI)-bearing solids dissolved. However, concentrations of Cr(VI) >2800 mg kg(-1) (>50% of the pre-treatment concentration) were still found after mixing with acid, regardless of the particle size, reaction time, or type of acid used. The residual Cr(VI) appears to be partially associated with poorly-ordered Fe and Al oxyhydroxides that precipitated in the interstitial areas of COPR particles. Remediation strategies that use HNO(3) or H(2)SO(4) to neutralize COPR or to maximize Cr(VI) in solution are likely to require extensive amounts of acid, may not mobilize all of the Cr(VI), and may require extended contact time, even under well-mixed conditions.

  16. Bioreduction of U(VI) and stability of immobilized uranium under suboxic conditions.

    PubMed

    Hu, Nan; Ding, De-xin; Li, Shi-mi; Tan, Xiang; Li, Guang-yue; Wang, Yong-dong; Xu, Fei

    2016-04-01

    In order to study the bioreduction of U(VI) and stability of immobilized uranium under suboxic conditions, microcosm were amended with ethanol, lactate and glucose, and incubated under suboxic conditions. During the incubation, total dissolved U in amended microcosms decreased from 0.95 mg/L to 0.03 mg/L. Pyrosequencing results showed that, the proportion of anaerobic microorganisms capable of reducing U(VI) under suboxic conditions was small compared with that under anoxic conditions; the proportion of aerobic and facultative anaerobic microorganisms capable of consuming the dissolved oxygen was large; and some of the facultative anaerobic microorganisms could reduce U(VI). These results indicated that different microbial communities were responsible for the bioreduction of U(VI) under suboxic and anoxic conditions. After the electron donors were exhausted, total dissolved U in the amended microcosms remained unchanged, while the U(VI)/U(IV) ratio in the solid phase of sediments increased obviously. This implied that the performance of bioreduction of the U(VI) can be maintained under suboxic condition. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Oxidation of diclofenac by potassium ferrate (VI): reaction kinetics and toxicity evaluation.

    PubMed

    Wang, Yingling; Liu, Haijin; Liu, Guoguang; Xie, Youhai; Gao, Shuyan

    2015-02-15

    The reaction kinetics and toxicity of diclofenac (DCF) oxidation by ferrate (VI) under simulated water disinfection conditions were investigated. Experimental results indicated that the reaction between DCF and Fe(VI) followed first-order kinetics with respect to each reactant. Furthermore, the effects of pH and temperature on DCF oxidation by Fe(VI) were elucidated using a systematic examination. The apparent second-order rate constants (kapp) increased significantly from 2.54 to 11.6M(-1)s(-1), as the pH of the solution decreased from 11.0 to 7.0, and the acid-base equilibriums of Fe(VI) and DCF were proposed to explain the pH dependence of kapp. The acute toxicity of DCF solution during Fe(VI) oxidation was evaluated using a Microtox bioassay. Overall, the DCF degradation process resulted in a rapid increase of the inhibition rate of luminescent bacteria. These toxicity tests suggest that the formation of enhanced toxic intermediates during the Fe(VI) disinfection process may pose potential health risk to consumers. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. [Mechanism and promotion effect of K+ on yield of Fe(VI)].

    PubMed

    Zhang, Yan-Ping; Xu, Guo-Ren; Li, Gui-Bai

    2008-03-01

    The mechanism and promotion effects of K+ on the yield of Fe(VI) were studied during the reaction of forming ferrate. The experiment results showed that K+ is far better than Na+ for the preparation of Fe(VI) at temperatures higher than 50 degrees C. The optimal temperature for the preparation of Fe(VI) with K+ is 65 degrees C. During the reaction, the yield of ferrate increases with the concentration of K+, and the promotion effect of K+ is obviously with ferric nitrate dosage increase. The Fe(VI) concentration prepared with 4.4 mol/L KOH is 0.05 mol/L at 85 g/L ferric nitrate; and which achieves 0.15 mol/L when added 2 mol/L K+. The promotion effect of K+ on the yield of ferrate is remarkable when ferric nitrate dosage is higher than 75 g/L, reaction temperature is below 55 degrees C and ClO(-) concentration is lower than 1.16 mol/L. The K+ can substitute for partly alkalinity and reduce the concentration of OH(-) in the reaction solution. During the reaction, the K+ can enwrap around FeO4(2-) that can reduce the contact between Fe(3+) and FeO4(2-), and decrease the catalysis effect of Fe(3+) on FeO4(2-). At the same time, K+ can react with FeO4(2-) to form solid K4FeO4, whichwill lower the Fe(VI) concentration, decrease the decomposition rate of Fe(VI), enhance the stability and improve the yield of Fe(VI).

  19. Clinical and serological responses following primary and booster immunization with Salmonella typhi Vi capsular polysaccharide vaccines.

    PubMed

    Keitel, W A; Bond, N L; Zahradnik, J M; Cramton, T A; Robbins, J B

    1994-01-01

    Clinical and serum antibody responses following intramuscular injection of two formulations of Salmonella typhi Vi capsular polysaccharide (Vi) were assessed in a double-blind evaluation. Healthy adults were randomly assigned to receive a 25 micrograms dose of liquid (Vi-Liq; n = 182) or freeze-dried Vi vaccine (Vi-Lyoph; n = 55), or placebo (n = 86). Erythema and/or induration > or = 1 cm in diameter at the injection site developed in 13/182 (7%) of Vi-Liq and 3/55 (5%) of Vi-Lyoph recipients (not significant, n.s.). Fever (oral temperature > or = 100 degrees F (37.8 degrees C)) occurred in < 2% of vaccinees. The frequencies of rises of fourfold or greater and of maximal Vi antibody levels were similar in the two vaccine groups. Fourfold or greater rises in serum Vi antibody levels (RIA) developed in 53% of Vi-Lyoph and 60% of Vi-Liq recipients by 1 week (n.s.), and 98 and 93%, respectively, by 1 month (n.s.). The frequencies of adverse reactions and mean Vi antibody levels following booster immunization with Vi-Liq 27 to 34 months after primary immunization (n = 55) were similar to those observed following primary immunization, although subjects given a booster dose were more likely to develop local reactions > or = 1 cm in diameter than those given a first dose (10/55 versus 13/182, p = 0.013 by the chi 2 test). Primary and booster immunizations with the Vi vaccines are well tolerated in healthy adults; mean Vi antibody levels remain significantly elevated for up to 34 months after primary immunization.

  20. Methods for Estimating Adsorbed Uranium(VI) and Distribution Coefficients of Contaminated Sediments

    USGS Publications Warehouse

    Kohler, M.; Curtis, G.P.; Meece, D.E.; Davis, J.A.

    2004-01-01

    Assessing the quantity of U(VI) that participates in sorption/desorption processes in a contaminated aquifer is an important task when investigating U migration behavior. U-contaminated aquifer sediments were obtained from 16 different locations at a former U mill tailings site at Naturita, CO (U.S.A.) and were extracted with an artificial groundwater, a high pH sodium bicarbonate solution, hydroxylamine hydrochloride solution, and concentrated nitric acid. With an isotopic exchange method, both a KD value for the specific experimental conditions as well as the total exchangeable mass of U(VI) was determined. Except for one sample, KD values determined by isotopic exchange with U-contaminated sediments that were in equilibrium with atmospheric CO2 agreed within a factor of 2 with KD values predicted from a nonelectrostatic surface complexation model (NEM) developed from U(VI) adsorption experiments with uncontaminated sediments. The labile fraction of U(VI) and U extracted by the bicarbonate solution were highly correlated (r2 = 0.997), with a slope of 0.96 ?? 0.01. The proximity of the slope to one suggests that both methods likely access the same reservoir of U(VI) associated with the sediments. The results indicate that the bicarbonate extraction method is useful for estimating the mass of labile U(VI) in sediments that do not contain U(IV). In-situ KD values calculated from the measured labile U(VI) and the dissolved U(VI) in the Naturita alluvial aquifer agreed within a factor of 3 with in-situ K D values predicted with the NEM and groundwater chemistry at each well.

  1. Mechanism of uranium (VI) removal by two anaerobic bacterial communities.

    PubMed

    Martins, Mónica; Faleiro, Maria Leonor; da Costa, Ana M Rosa; Chaves, Sandra; Tenreiro, Rogério; Matos, António Pedro; Costa, Maria Clara

    2010-12-15

    The mechanism of uranium (VI) removal by two anaerobic bacterial consortia, recovered from an uncontaminated site (consortium A) and other from an uranium mine (consortium U), was investigated. The highest efficiency of U (VI) removal by both consortia (97%) occurred at room temperature and at pH 7.2. Furthermore, it was found that U (VI) removal by consortium A occurred by enzymatic reduction and bioaccumulation, while the enzymatic process was the only mechanism involved in metal removal by consortium U. FTIR analysis suggested that after U (VI) reduction, U (IV) could be bound to carboxyl, phosphate and amide groups of bacterial cells. Phylogenetic analysis of 16S rRNA showed that community A was mainly composed by bacteria closely related to Sporotalea genus and Rhodocyclaceae family, while community U was mainly composed by bacteria related to Clostridium genus and Rhodocyclaceae family. Copyright © 2010 Elsevier B.V. All rights reserved.

  2. Biased Brownian motion mechanism for processivity and directionality of single-headed myosin-VI.

    PubMed

    Iwaki, Mitsuhiro; Iwane, Atsuko Hikikoshi; Ikebe, Mitsuo; Yanagida, Toshio

    2008-01-01

    Conventional form to function as a vesicle transporter is not a 'single molecule' but a coordinated 'two molecules'. The coordinated two molecules make it complicated to reveal its mechanism. To overcome the difficulty, we adopted a single-headed myosin-VI as a model protein. Myosin-VI is an intracellular vesicle and organelle transporter that moves along actin filaments in a direction opposite to most other known myosin classes. The myosin-VI was expected to form a dimer to move processively along actin filaments with a hand-over-hand mechanism like other myosin organelle transporters. However, wild-type myosin-VI was demonstrated to be monomer and single-headed, casting doubt on its processivity. Using single molecule techniques, we show that green fluorescent protein (GFP)-fused single-headed myosin-VI does not move processively. However, when coupled to a 200 nm polystyrene bead (comparable to an intracellular vesicle in size) at a ratio of one head per bead, single-headed myosin-VI moves processively with large (40 nm) steps. Furthermore, we found that a single-headed myosin-VI-bead complex moved more processively in a high-viscous solution (40-fold higher than water) similar to cellular environment. Because diffusion of the bead is 60-fold slower than myosin-VI heads alone in water, we propose a model in which the bead acts as a diffusional anchor for the myosin-VI, enhancing the head's rebinding following detachment and supporting processive movement of the bead-monomer complex. This investigation will help us understand how molecular motors utilize Brownian motion in cells.

  3. 78 FR 666 - Treasury Inflation-Protected Securities Issued at a Premium; Bond Premium Carryforward

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-04

    ... regulations that provide guidance on the tax treatment of a debt instrument with a bond premium carryforward... contains final regulations that provide guidance on the tax treatment of Treasury Inflation-Protected... debt instruments. The text of the temporary regulations in this document also serves as the text of the...

  4. Oxidation of Sulfonamides in Aqueous Solution by UV-TiO2-Fe(VI).

    PubMed

    Ma, Yan; Zhang, Kejia; Li, Cong; Zhang, Tuqiao; Gao, Naiyun

    2015-01-01

    The photocatalytic degradation of sulfonamides in aqueous TiO2 suspension under UV irradiation has been investigated using potassium ferrate as electron acceptors. The results showed that the stability of Fe(VI) is dependent on pH significantly, and the stability reduces obviously in the presence of UV-TiO2. The experiments indicated that Fe(VI) could effectively scavenge the conduction band electrons from the surface of TiO2. The photocatalytic oxidation of sulfonamides with Fe(VI) was found to be much faster than that without Fe(VI). The SD, SM, and SMX concentration was greatly reduced by 89.2%, 83.4%, and 82.0%, respectively, after 10 min with UV-TiO2-Fe(VI), comparing to 65.2%, 66.0%, and 71.9%, respectively, with Fe(VI) only in the dark and 71.3%, 72.7%, and 76.0%, respectively, with UV-TiO2. The pH value of solution significantly influenced the sulfonamides degradation in UV-TiO2-Fe(VI) system. The degradation amount of sulfonamides after 10 min was a maximum at pH 7. The intermediate products of sulfonamides oxidation by UV-TiO2-Fe(VI) were analysed by LC-HESI-MS-MS and the results suggested that a majority of sulfonamides turned into large-molecule products without complete mineralization.

  5. Oxidation of Sulfonamides in Aqueous Solution by UV-TiO2-Fe(VI)

    PubMed Central

    Ma, Yan; Zhang, Kejia; Li, Cong; Zhang, Tuqiao; Gao, Naiyun

    2015-01-01

    The photocatalytic degradation of sulfonamides in aqueous TiO2 suspension under UV irradiation has been investigated using potassium ferrate as electron acceptors. The results showed that the stability of Fe(VI) is dependent on pH significantly, and the stability reduces obviously in the presence of UV-TiO2. The experiments indicated that Fe(VI) could effectively scavenge the conduction band electrons from the surface of TiO2. The photocatalytic oxidation of sulfonamides with Fe(VI) was found to be much faster than that without Fe(VI). The SD, SM, and SMX concentration was greatly reduced by 89.2%, 83.4%, and 82.0%, respectively, after 10 min with UV-TiO2-Fe(VI), comparing to 65.2%, 66.0%, and 71.9%, respectively, with Fe(VI) only in the dark and 71.3%, 72.7%, and 76.0%, respectively, with UV-TiO2. The pH value of solution significantly influenced the sulfonamides degradation in UV-TiO2-Fe(VI) system. The degradation amount of sulfonamides after 10 min was a maximum at pH 7. The intermediate products of sulfonamides oxidation by UV-TiO2-Fe(VI) were analysed by LC-HESI-MS-MS and the results suggested that a majority of sulfonamides turned into large-molecule products without complete mineralization. PMID:26347888

  6. Biological Cr(VI) removal using bio-filters and constructed wetlands.

    PubMed

    Michailides, Michail K; Sultana, Mar-Yam; Tekerlekopoulou, Athanasia G; Akratos, Christos S; Vayenas, Dimitrios V

    2013-01-01

    The bioreduction of hexavalent chromium from aqueous solution was carried out using suspended growth and packed-bed reactors under a draw-fill operating mode, and horizontal subsurface constructed wetlands. Reactors were inoculated with industrial sludge from the Hellenic Aerospace Industry using sugar as substrate. In the suspended growth reactors, the maximum Cr(VI) reduction rate (about 2 mg/L h) was achieved for an initial concentration of 12.85 mg/L, while in the attached growth reactors, a similar reduction rate was achieved even with high initial concentrations (109 mg/L), thus confirming the advantage of these systems. Two horizontal subsurface constructed wetlands (CWs) pilot-scale units were also built and operated. The units contained fine gravel. One unit was planted with common reeds and one was kept unplanted. The mean influent concentrations of Cr(VI) were 5.61 and 5.47 mg/L for the planted and unplanted units, respectively. The performance of the planted CW units was very effective as mean Cr(VI) removal efficiency was 85% and efficiency maximum reached 100%. On the contrary, the unplanted CW achieved very low Cr(VI) removal with a mean value of 26%. Both attached growth reactors and CWs proved efficient and viable means for Cr(VI) reduction.

  7. Phase VI Glove Durability Testing

    NASA Technical Reports Server (NTRS)

    Mitchell, Kathryn

    2011-01-01

    The current state-of-the-art space suit gloves, the Phase VI gloves, have an operational life of 25 -- 8 hour Extravehicular Activities (EVAs) in a dust free, manufactured microgravity EVA environment. Future planetary outpost missions create the need for space suit gloves which can endure up to 90 -- 8 hour traditional EVAs or 576 -- 45 minute suit port-based EVAs in a dirty, uncontrolled planetary environment. Prior to developing improved space suit gloves for use in planetary environments, it is necessary to understand how the current state-of-the-art performs in these environments. The Phase VI glove operational life has traditionally been certified through cycle testing consisting of International Space Station (ISS)-based EVA tasks in a clean environment, and glove durability while performing planetary EVA tasks in a dirty environment has not previously been characterized. Testing was performed in the spring of 2010 by the NASA Johnson Space Center (JSC) Crew and Thermal Systems Division (CTSD) to characterize the durability of the Phase VI Glove and identify areas of the glove design which need improvement to meet the requirements of future NASA missions. Lunar simulant was used in this test to help replicate the dirty lunar environment, and generic planetary surface EVA tasks were performed during testing. A total of 50 manned, pressurized test sessions were completed in the Extravehicular Mobility Unit (EMU) using one pair of Phase VI gloves as the test article. The 50 test sessions were designed to mimic the total amount of pressurized cycling the gloves would experience over a 6 month planetary outpost mission. The gloves were inspected periodically throughout testing, to assess their condition at various stages in the test and to monitor the gloves for failures. Additionally, motion capture and force data were collected during 18 of the 50 test sessions to assess the accuracy of the cycle model predictions used in testing and to feed into the

  8. Chlorine decay and trihalomethane formation following ferrate(VI) preoxidation and chlorination of drinking water.

    PubMed

    Li, Cong; Luo, Feng; Dong, Feilong; Zhao, Jingguo; Zhang, Tuqiao; He, Guilin; Cizmas, Leslie; Sharma, Virender K

    2017-11-01

    This paper presents the effect of preoxidation with ferrate(VI) (Fe VI O 4 2- , Fe(VI)) prior to chlorination on chlorine decay and formation of disinfection by-products in filtered raw water from a full-scale drinking water treatment plant. The rate of chlorine decay became significantly faster as the concentration of ferrate(VI) increased. Chlorine degradation followed two first-order decay reactions with rate constants k 1 and k 2 for fast and slow decay, respectively. Kinetic modeling established the relationships between k 1 and k 2 and varying dosages of chlorine and ferrate(VI). When ferrate(VI) was used as a pre-oxidant, the levels of trihalomethanes (trichloromethane (TCM), dichlorobromomethane (DCBM), dibromochloromethane (DBCM), and tribromomethane (TBM)) in water samples decreased as the ferrate(VI) concentration increased. The concentrations of these trihalomethanes followed the order TCM > DCBM ≈ DBCM > TBM. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Polyaniline (PANI) modified bentonite by plasma technique for U(VI) removal from aqueous solution

    NASA Astrophysics Data System (ADS)

    Liu, Xinghao; Cheng, Cheng; Xiao, Chengjian; Shao, Dadong; Xu, Zimu; Wang, Jiaquan; Hu, Shuheng; Li, Xiaolong; Wang, Weijuan

    2017-07-01

    Polyaniline (PANI) modified bentonite (PANI/bentonie) was synthesized by plasma induced polymerization of aniline on bentonite surface, and applied to uptake of uranium(VI) ions from aqueous solution. The as-synthesized PANI/bentonie was characterized by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Batch adsorption technique was utilized to investigate the adsorption of U(VI) on bentonite and PANI/bentonite. The adsorption of U(VI) (10 mg/L) on PANI/bentonite surface is fairly depend on solution pH, ionic strength, and temperature in solution. The modified PANI on PANI/bentonite surface significantly enhances its adsorption capability for U(VI). The presence of humic acid (HA) can sound enhance U(VI) adsorption on PANI/bentonite at pH < 6.5 because of the strong complexation, and inhibits U(VI) adsorption at pH > 6.5. According to the thermodynamic parameters, the adsorption of U(VI) on PANI/bentonite surface is a spontaneous and endothermic process. The results highlight the application of PANI/bentonite composites as candidate material for the uptake of trace U(VI) from aqueous solution.

  10. 23 CFR 200.11 - Procedures for processing Title VI reviews.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 23 Highways 1 2010-04-01 2010-04-01 false Procedures for processing Title VI reviews. 200.11 Section 200.11 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.11 Procedures for processing Title...

  11. 23 CFR 200.11 - Procedures for processing Title VI reviews.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 23 Highways 1 2014-04-01 2014-04-01 false Procedures for processing Title VI reviews. 200.11 Section 200.11 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.11 Procedures for processing Title...

  12. 23 CFR 200.11 - Procedures for processing Title VI reviews.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 23 Highways 1 2011-04-01 2011-04-01 false Procedures for processing Title VI reviews. 200.11 Section 200.11 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.11 Procedures for processing Title...

  13. 23 CFR 200.11 - Procedures for processing Title VI reviews.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 23 Highways 1 2013-04-01 2013-04-01 false Procedures for processing Title VI reviews. 200.11 Section 200.11 Highways FEDERAL HIGHWAY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CIVIL RIGHTS TITLE VI PROGRAM AND RELATED STATUTES-IMPLEMENTATION AND REVIEW PROCEDURES § 200.11 Procedures for processing Title...

  14. Thermodynamic Insight into the Solvation and Complexation Behavior of U(VI) in Ionic Liquid: Binding of CMPO with U(VI) Studied by Optical Spectroscopy and Calorimetry.

    PubMed

    Wu, Qi; Sun, Taoxiang; Meng, Xianghai; Chen, Jing; Xu, Chao

    2017-03-06

    The complexation of U(VI) with octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO, denoted as L) in ionic liquid (IL) C 4 mimNTf 2 was investigated by UV-vis absorption spectrophotometry and isothermal titration calorimetry. Spectro-photometric titration suggests that three successive complexes, UO 2 L j 2+ (j = 1-3), formed both in "dry" (water content < 250 ppm) and "wet" (water content ≈ 12 500 ppm) ionic liquid. However, the thermodynamic parameters are distinctly different in the two ILs. In dry IL, the complexation strength between CMPO and U(VI) is much stronger, with stability constants of the respective complexes more than 1 order of magnitude higher than that in wet IL. Energetically, the complexation of U(VI) with CMPO in dry IL is mainly driven by negative enthalpies. In contrast, the complexation in wet IL is overwhelmingly driven by highly positive entropies as a result of the release of a large amount of water molecules from the solvation sphere of U(VI). Moreover, comparisons between the fitted absorption spectra of complexes in wet IL and that of extractive samples from solvent extraction have identified the speciation involved in the extraction of U(VI) by CMPO in ionic liquid. The results from this study not only offer a thermodynamic insight into the complexation behavior of U(VI) with CMPO in IL but also provide valuable information for understanding the extraction behavior in the corresponding solvent extraction system.

  15. Kinetics and Products of Chromium(VI) Reduction by Iron(II/III)-Bearing Clay Minerals.

    PubMed

    Joe-Wong, Claresta; Brown, Gordon E; Maher, Kate

    2017-09-05

    Hexavalent chromium is a water-soluble pollutant, the mobility of which can be controlled by reduction of Cr(VI) to less soluble, environmentally benign Cr(III). Iron(II/III)-bearing clay minerals are widespread potential reductants of Cr(VI), but the kinetics and pathways of Cr(VI) reduction by such clay minerals are poorly understood. We reacted aqueous Cr(VI) with two abiotically reduced clay minerals: an Fe-poor montmorillonite and an Fe-rich nontronite. The effects of ionic strength, pH, total Fe content, and the fraction of reduced structural Fe(II) [Fe(II)/Fe(total)] were examined. The last variable had the largest effect on Cr(VI) reduction kinetics: for both clay minerals, the rate constant of Cr(VI) reduction varies by more than 3 orders of magnitude with Fe(II)/Fe(total) and is described by a linear free energy relationship. Under all conditions examined, Cr and Fe K-edge X-ray absorption near-edge structure spectra show that the main Cr-bearing product is a Cr(III)-hydroxide and that Fe remains in the clay structure after reacting with Cr(VI). This study helps to quantify our understanding of the kinetics of Cr(VI) reduction by Fe(II/III)-bearing clay minerals and may improve predictions of Cr(VI) behavior in subsurface environments.

  16. Study on Cr(VI) Leaching from Cement and Cement Composites

    PubMed Central

    Palascakova, Lenka; Kanuchova, Maria

    2018-01-01

    This paper reports an experimental study on hexavalent chromium leaching from cement samples and cement composites containing silica fume and zeolite additions that were subjected to various leaching agents. The water-soluble Cr(VI) concentrations in cements ranged from 0.2 to 3.2 mg/kg and represented only 1.8% of the total chromium content. The presence of chromium compounds with both chromium oxidation states of III and VI was detected in the cement samples by X-ray photoelectron spectroscopy (XPS). Leaching tests were performed in a Britton-Robinson buffer to simulate natural conditions and showed increased dissolution of Cr(VI) up to 6 mg/kg. The highest amount of leached hexavalent chromium was detected after leaching in HCl. The findings revealed that the leaching of chromium from cements was higher by 55–80% than that from the cement composites. A minimum concentration was observed for all cement samples when studying the relationship between the soluble Cr(VI) and the cement storage time. PMID:29690550

  17. Study on Cr(VI) Leaching from Cement and Cement Composites.

    PubMed

    Estokova, Adriana; Palascakova, Lenka; Kanuchova, Maria

    2018-04-22

    This paper reports an experimental study on hexavalent chromium leaching from cement samples and cement composites containing silica fume and zeolite additions that were subjected to various leaching agents. The water-soluble Cr(VI) concentrations in cements ranged from 0.2 to 3.2 mg/kg and represented only 1.8% of the total chromium content. The presence of chromium compounds with both chromium oxidation states of III and VI was detected in the cement samples by X-ray photoelectron spectroscopy (XPS). Leaching tests were performed in a Britton-Robinson buffer to simulate natural conditions and showed increased dissolution of Cr(VI) up to 6 mg/kg. The highest amount of leached hexavalent chromium was detected after leaching in HCl. The findings revealed that the leaching of chromium from cements was higher by 55⁻80% than that from the cement composites. A minimum concentration was observed for all cement samples when studying the relationship between the soluble Cr(VI) and the cement storage time.

  18. A critical review of ferrate(VI)-based remediation of soil and groundwater.

    PubMed

    Rai, Prabhat Kumar; Lee, Jechan; Kailasa, Suresh Kumar; Kwon, Eilhann E; Tsang, Yiu Fai; Ok, Yong Sik; Kim, Ki-Hyun

    2018-01-01

    Over the past few decades, diverse chemicals and materials such as mono- and bimetallic nanoparticles, metal oxides, and zeolites have been used for soil and groundwater remediation. Ferrate (Fe VI O 4 2- ) has been widely employed due to its high-valent iron (VI) oxo compound with high oxidation/reduction potentials. Ferrate has received attention for wide environmental applications including water purification and sewage sludge treatment. Ferrate provides great potential for diverse environmental applications without any environmental problems. Therefore, this paper provides comprehensive information on the recent progress on the use of (Fe VI O 4 2- ) as a green material for use in sustainable treatment processes, especially for soil and water remediation. We reviewed diverse synthesis recipes for ferrates (Fe VI O 4 2- ) and their associated physicochemical properties as oxidants, coagulants, and disinfectants for the elimination of a diverse range of chemical and biological species from water/wastewater samples. A summary of the eco-sustainable performance of ferrate(VI) in water remediation is also provided and the future of ferrate(VI) is discussed in this review. Copyright © 2017 Elsevier Inc. All rights reserved.

  19. Probing chromium(III) from chromium(VI) in cells by a fluorescent sensor

    NASA Astrophysics Data System (ADS)

    Hu, Xiangquan; Chai, Jie; Liu, Yanfei; Liu, Bin; Yang, Binsheng

    2016-01-01

    Cellular uptake of Cr(VI), followed by its reduction to Cr(III) with the formation of kinetically inert Cr(III) complexes, is a complex process. To better understand its physiological and pathological functions, efficient methods for the monitoring of Cr(VI) are desired. In this paper a selective fluorescent probe L, rhodamine hydrazide bearing a benzo[b]furan-2-carboxaldehyde group, was demonstrated as a red chemosensor for Cr(III) at about 586 nm. This probe has been used to probe Cr(III) which is reduced from Cr(VI) by reductants such as glutathione (GSH), vitamin C, cysteine (Cys), H2O2 and Dithiothreitol (DTT) by fluorescence spectra. Cr(VI) metabolism in vivo is primarily driven by Vc and GSH. Vc could reduce CrO42 - to Cr(III) in a faster rate than GSH. The indirectly detection limit for Cr(VI) by L + GSH system was determined to be 0.06 μM at pH = 6.2. Moreover, the confocal microscopy image experiments indicated that Cr(VI) can be reduced to Cr(III) inside cells rapidly and the resulted Cr(III) can be captured and imaged timely by L.

  20. VI-14, a novel flavonoid derivative, inhibits migration and invasion of human breast cancer cells

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Li, Fanni; Li, Chenglin; Zhang, Haiwei

    It has been well characterized that flavonoids possess pronounced anticancer potentials including anti-angiogenesis, anti-metastasis, and pro-apoptosis. Herein, we report, for the first time, that VI-14, a novel flavonoid derivative, possesses anti-cancer properties. The purpose of this study is to investigate the anti-migration and anti-invasion activities of VI-14 in breast cancer cells. Our data indicate that VI-14 inhibits adhesion, migration and invasion of MDA-MB-231 and MDA-MB-435 human breast cancer cells. MDA-MB-231 cells treated with VI-14 display reduced activities and expressions of ECM degradation-associated proteins including matrix metalloproteinase 2 (MMP-2) and 9 (MMP-9) at both the protein and mRNA levels. Meanwhile, VI-14more » treatment induces an up-regulated expression of tissue inhibitor of metalloproteinase 1 (TIMP-1) and 2 (TIMP-2) in MDA-MB-231 cells. Western blotting results show that phosphorylation levels of critical components of the MAPK signaling pathway, including ERK, JNK and P38, are dramatically decreased in VI-14-treated MDA-MB-231 cells. Furthermore, treatment of VI-14 significantly decreases the nuclear levels and the binding ability of nuclear factor-kappa B (NF-κB) and activator protein-1 (AP-1). Taken together, our data suggest that VI-14 treatment suppresses migration and motility of breast cancer cells, and VI-14 may be a potential compound for cancer therapy. Highlights: ► We report for the first time that VI-14 possesses anti-cancer properties. ► VI-14 weakens the adhesion, migration and invasion of human breast cancer cells. ► VI-14 decreases the activities and expressions of MMP-2/9. ► VI-14 suppresses the phosphorylation levels of the MAPK signaling pathway. ► VI-14 decreases the nuclear levels and the binding ability of NF-κB and AP-1.« less

  1. 19 CFR Appendix to 19 Cfr Part 0 - Treasury Department Order No. 100-16

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... completion of entry or substance of entry summary including duty assessment and collection, classification... the Committee on Ways and Means and the Chairman and Ranking Member of the Committee on Finance every... Ranking Member of the Committee on Finance every six months. The Secretary of the Treasury shall list any...

  2. AM(VI) partitioning studies. FY14 final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mincher, Bruce J.

    2014-10-01

    The use of higher oxidation states of americium in partitioning from the lanthanides is under continued investigation by the sigma team. This is based on the hypothesis that Am(VI) can be produced and remain stable in irradiated first cycle raffinate solution long enough to perform solvent extraction for separations. The stability of Am(VI) to autoreduction was measured using millimolar americium concentrations in a 1-cm cell with a Cary 6000 UV/Vis spectrophotometer for data acquisition. At millimolar americium concentrations, Am(VI) is stable enough against its own autoreduction for separations purposes. A second major accomplishment during FY14 was the hot test. Americiummore » oxidation and extraction was performed using a centrifugal contactor-based test bed consisting of an extraction stage and two stripping stages. Sixty-three percent americium extraction was obtained in one extraction stage, in agreement with batch contacts. Promising electrochemical oxidation results have also been obtained, using terpyridine ligand derivatized electrodes for binding of Am(III). Approximately 50 % of the Am(III) was oxidized to Am(V) over the course of 1 hour. It is believed that this is the first demonstration of the electrolytic oxidation of americium in a non-complexing solution. Finally, an initial investigation of Am(VI) extraction using diethylhexylbutyramide (DEHBA) was performed.« less

  3. Reaction kinetics and oxidation product formation in the degradation of acetaminophen by ferrate (VI).

    PubMed

    Wang, Hongyu; Liu, Yibing; Jiang, Jia-Qian

    2016-07-01

    This paper investigates the degradation of acetaminophen (AAP) in aqueous solutions by ferrate (VI), aiming to propose the kinetics, pathways and the oxidation products' formation in the AAP degradation. A series of jar tests were undertaken over ferrate (VI) dosages (molar ratios of ferrate (VI):AAP, 5:1 to 25:1) and pH values (4-11). The effects of co-existing ions (0.2-5 mM) and humic acid (10-50 mg l(-1)) on the AAP removal were investigated. Ferrate (VI) can remove 99.6% AAP (from 1000 μg l(-1)) in 60 min under study conditions when majority of the AAP reduction occurred in the first 5 min. The treatment performance depended on the ferrate(VI) dosage, pH and the type and strength of co-existing ions and humic acid. Raising ferrate (VI) dosage with optimal pH 7 improved the AAP degradation. In the presence of humic acid, the AAP degradation by ferrate (VI) was promoted in a short period (<30 min) but then inhibited with increasing in humic acid contents. The presence of Al(3+), CO3(2-) and PO4(3-) ions declined but the existence of K(+), Na(+), Mg(2+) and Ca(2+) ions can improve the AAP removal. The catalytic function of Al(3+) on the decomposition of ferrate (VI) in aqueous solution was found. The kinetics of the reaction between ferrate (VI) and AAP was pseudo first-order for ferrete (VI) and pseudo second-order for AAP. The pseudo rate constant of ferrate (VI) with AAP was 1.4 × 10(-5) L(2) mg(-2) min(-1). Three oxidation products (OPs) were identified and the AAP degradation pathways were proposed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Group I-III-VI.sub.2 semiconductor films for solar cell application

    DOEpatents

    Basol, Bulent M.; Kapur, Vijay K.

    1991-01-01

    This invention relates to an improved thin film solar cell with excellent electrical and mechanical integrity. The device comprises a substrate, a Group I-III-VI.sub.2 semiconductor absorber layer and a transparent window layer. The mechanical bond between the substrate and the Group I-III-VI.sub.2 semiconductor layer is enhanced by an intermediate layer between the substrate and the Group I-III-VI.sub.2 semiconductor film being grown. The intermediate layer contains tellurium or substitutes therefor, such as Se, Sn, or Pb. The intermediate layer improves the morphology and electrical characteristics of the Group I-III-VI.sub.2 semiconductor layer.

  5. On the Stark broadening of Cr VI spectral lines in astrophysical plasma

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.; Simić, Z.; Sahal-Bréchot, S.

    2017-02-01

    Stark broadening parameters for Cr VI lines have been calculated using semiclassical perturbation method for conditions of interest for stellar plasma. Here are presented, as an example of obtained results, Stark broadening parameters for electron- and proton-impact broadening for Cr VI 4s 2S-4p 2P° λ = 1430 Å and Cr VI 4p 2P°-5s 2S λ = 611.8 Å multiplets. The obtained results are used to demonstrate the importance of Stark broadening of Cr VI in DO white dwarf atmospheres. Also the obtained results will enter in STARK-B database which is included in Virtual Atomic and Molecula Data Center - VAMDC.

  6. Characterization of U(VI) reduction in contaminated sediments with slow-degrading electron donor source

    NASA Astrophysics Data System (ADS)

    Wu, W.; Watson, D. B.; Zhang, G.; Mehlhorn, T.; Lowe, K.; Earles, J.; Phillips, J.; Kelly, S. D.; Boyanov, M.; Kemner, K. M.; Schadt, C.; Criddle, C. S.; Jardine, P. M.; Brooks, S. C.

    2011-12-01

    In order to select sustainable, high efficiency and cost effective electron donor source, oleate and emulsified vegetable oil (EVO) were tested uranium (VI) reduction in comparison with ethanol in microcosms using uranium contaminated sediments and groundwater from the US DOE Oak Ridge Integrated Field Research Challenge (ORIFRC) site. The effect of initial sulfate concentration on U(VI) reduction was also tested. Both oleate and EVO were effective electron donor sources for U(VI) reduction. Accumulation of acetate as a major product and the removal of aqueous U(VI) were observed and were associated with sulfate reduction. Both oleate and EVO supported U(VI) reduction but at slower rates with a comparable but slightly lower extent of reduction than ethanol. X-ray absorption near-edge spectroscopy (XANES) analysis confirmed reduction of U(VI) to U(IV). The extent of U(VI) reduction in solid phase was negatively influenced by aqueous calcium concentration. The majority of electrons of the three substrates were consumed by sulfate reduction, Fe(III) reduction, and methanogenesis. Initial U(VI) concentration in the aqueous phase increased with increased sulfate concentration (1 versus 5 mM), likely due to U(VI) desorption from the solid phase. At the higher initial sulfate concentration more U(VI) was reduced and fewer electrons were used in methanogenesis. Analysis of bacterial and archeal populations using 16S rRNA gene libraries showed a significant increase in Deltaproteobacteria after biostimulation. The microbial community structures developed with oleate and EVO were significantly distinct from those developed with ethanol. Bacteria similar to Desulforegula spp. was predominant for oleate and EVO degradation but were not observed in ethanol-amended microcosms. Known U(VI)-reducing bacteria in the microcosms amended with the three electron donor sources included iron(III) reducing Geobacter spp. but in lower abundances than sulfate-reducing Desulfovibrio spp. The

  7. Diffusion of U(VI) in Opalinus Clay: Influence of temperature and humic acid

    NASA Astrophysics Data System (ADS)

    Joseph, C.; Van Loon, L. R.; Jakob, A.; Steudtner, R.; Schmeide, K.; Sachs, S.; Bernhard, G.

    2013-05-01

    The diffusion of U(VI) (c0 = 1 × 10-6 mol/L) in compacted Opalinus Clay from the Mont Terri underground laboratory, Switzerland, was studied in the absence and presence of humic acid (10 mg/L) at two different temperatures (25 °C, 60 °C) under anaerobic conditions. As background electrolyte synthetic Opalinus Clay pore water (pH 7.6, I = 0.36 mol/L) was used. The diffusion-accessible porosity, ɛ, was determined for each Opalinus Clay bore core sample by through-diffusion experiments with tritiated water (HTO) before the U(VI) diffusion experiments were carried out. The values for the effective diffusion and distribution coefficients De and Kd obtained for U(VI) and humic acid at 25 °C as well as at 60 °C showed that humic acid has no significant influence on the U(VI) diffusion. The diffusion profiles of humic acid in Opalinus Clay at 25 and 60 °C indicate the contributions of two different humic acid particle size fractions (<1 kDa and 10-100 kDa). The small-sized humic acid fraction diffused through the whole Opalinus Clay samples at both temperatures within the 3 month duration of the U(VI) diffusion experiments. At 60 °C, diffusion profiles of two different U(VI) species were observed. In a separate experiment the U(VI) speciation in the source reservoir solution at 60 °C was analyzed by laser-induced fluorescence spectroscopy, photon correlation spectroscopy and scanning electron microscopy with an energy dispersive X-ray detector. The two diffusion profiles could be attributed to an unknown colloidal and a known aquatic U(VI) species (Ca2UO2(CO3)3(aq)). The diffusion results showed that the interaction of U(VI) and of the large-sized humic acid colloid fraction with the clay is stronger at 60 °C. An increase of Kd from 0.025 ± 0.003 m3/kg at 25 °C to 0.25 ± 0.05 m3/kg for U(VI)colloidal at 60 °C was determined. In addition, the value for De of U(VI) increased with increasing temperature. Using the De values at 25 and 60 °C, a preliminary

  8. 31 CFR 360.3 - Converting definitive savings bonds to book-entry bonds in TreasuryDirect®.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... originally issued as definitive bonds may be converted to book-entry bonds through TreasuryDirect®, an online.... Bond owners who wish to convert their definitive savings bonds should follow online instructions for...

  9. Sero-efficacy of Vi-polysaccharide tetanus-toxoid typhoid conjugate vaccine (Typbar-TCV).

    PubMed

    Voysey, Merryn; Pollard, Andrew J

    2018-01-17

    Salmonella Typhi is the major cause of enteric fever in lower income countries. New conjugate vaccines show promise as public health interventions, however there are no efficacy data available from endemic areas. Data were obtained from a previously published phase 3 randomised controlled trial comparing Vi-polysaccharide tetanus-toxoid conjugate vaccine (Typbar-TCV; Bharat Biotech Intl Ltd, India): (Vi-TT) with Vi-polysaccharide (Typbar; Bharat Biotech Intl Ltd, India): (Vi-PS) in participants aged 2- 45 years. An additional open-label arm administered Vi-TT to children aged 6 months to 23 months. The proportion of participants with presumed clinical or subclinical infection ('seroincidence'), was determined using mixture models and compared using relative risks. 81/387 (21%) participants were classified as having presumed typhoid infection during the 2 year period post-vaccination. Seroincidence was lower in those randomised to Vi-TT than Vi-PS in those aged 2-45 years; 21/155 (13.5%) vs 47/129 (36.4%); RR 0.372 (95%CI 0.235-0.588), p<0.0001 and in those aged 2-15 years RR 0.424 (95%CI 0.231-0.778), p=0.0039. There was no difference in seroincidence in those receiving Vi-TT aged 2-45 years and those aged 6-23 months; 21/155 (13.5%) vs 13/103 (12.6%); RR 1.073 (0.563, 2.046), p=0.8293. Vaccine seroefficacy was 85% (95%CI 80-88%). This is the first field estimate of the seroefficacy of a Vi-TT vaccine and shows that Typbar TCV substantially reduces the number of serologically defined (sub)clinical infections in infants, children and adults. These results support the recent World Health Organisation recommendations for deployment of typhoid conjugate vaccines in high burden areas. © The Author(s) 2018. Published by Oxford University Press for the Infectious Diseases Society of America. All rights reserved. For permissions, e-mail: journals.permissions@oup.com.

  10. ESL VI Curriculum Guide.

    ERIC Educational Resources Information Center

    Flander, Leonard

    This curriculum guide for English as a Second Language (ESL) Level VI is the sixth of six in a Guam Community College ESL project series. The other five guides, a companion teacher's guide and pre- and post-tests are available separately (see note). The entire project centers around the Peabody Kits P, Level P, Level 1, Level 2, Level 3, and the…

  11. 78 FR 32303 - Departmental Offices; Renewal of the Treasury Borrowing Advisory Committee of the Securities...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-29

    ... Committee of the Securities Industry and Financial Markets Association ACTION: Notice of renewal. SUMMARY... the Treasury Borrowing Advisory Committee of the Securities Industry and Financial Markets Association... Management (202) 622-1876. SUPPLEMENTARY INFORMATION: The purpose of the Committee is to provide informed...

  12. Ferrate(VI) as a greener oxidant: Electrochemical generation and treatment of phenol.

    PubMed

    Sun, Xuhui; Zhang, Qi; Liang, He; Ying, Li; Xiangxu, Meng; Sharma, Virender K

    2016-12-05

    Ferrate(VI) (Fe(VI)O4(2-), Fe(VI)) is a greener oxidant in the treatment of drinking water and wastewater. The electrochemical synthesis of Fe(VI) may be considered environmentally friendly because it involves one-step process to convert Fe(0) to Fe(VI) without using harmful chemicals. Electrolysis was performed by using a sponge iron as an anode in NaOH solution at different ionic strengths. The cyclic voltammetric (CV) curves showed that the sponge iron had higher electrical activity than the grey cast iron. The optimum current density was 0.054mAcm(-2) in 10M NaOH solution, which is much lower than the electrolyte concentrations used in other electrode materials. A comparison of current efficiency and energy consumption was conducted and is briefly discussed. The generated ferrate solution was applied to degrade phenol in water at two levels (2mgL(-1) and 5mgL(-1)). The maximum removal efficiency was ∼70% and the optimum pH for phenol treatment was 9.0. Experiments on phenol removal using conventional coagulants (ferric chloride (FeCl3) and polyaluminium chloride (PAC)) were performed independently to demonstrate that removal of phenol by Fe(VI) occurred mainly by oxidative transformation. A combination of Fe(VI) and coagulant may be advantageous in enhancing removal efficiency, adjusting pH, and facilitating flocculation. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. The O VI Mystery: Mismatch between X-Ray and UV Column Densities

    NASA Astrophysics Data System (ADS)

    Mathur, S.; Nicastro, F.; Gupta, A.; Krongold, Y.; McLaughlin, B. M.; Brickhouse, N.; Pradhan, A.

    2017-12-01

    The UV spectra of Galactic and extragalactic sightlines often show O VI absorption lines at a range of redshifts, and from a variety of sources from the Galactic circumgalactic medium to active galactic nuclei (AGN) outflows. Inner shell O VI absorption is also observed in X-ray spectra (at λ =22.03 Å), but the column density inferred from the X-ray line was consistently larger than that from the UV line. Here we present a solution to this discrepancy for the z = 0 systems. The O II Kβ line {}4{S}0\\to {(}3D)3{p}4P at 562.40 eV (≡22.04 Å) is blended with the O VI Kα line in X-ray spectra. We estimate the strength of this O II line in two different ways, and show that in most cases the O II line accounts for the entire blended line. The small amount of O VI equivalent width present in some cases has column density entirely consistent with the UV value. This solution to the O VI discrepancy, however, does not apply to high column-density systems like AGN outflows. We discuss other possible causes to explain their UV/X-ray mismatch. The O VI and O II lines will be resolved by gratings on board the proposed mission Arcus and the concept mission Lynx, and would allow the detection of weak O VI lines not just at z = 0, but also at higher redshift.

  14. Chromium VI and stomach cancer: a meta-analysis of the current epidemiological evidence.

    PubMed

    Welling, Roberta; Beaumont, James J; Petersen, Scott J; Alexeeff, George V; Steinmaus, Craig

    2015-02-01

    Chromium VI (hexavalent chromium, Cr(VI)) is an established cause of lung cancer, but its association with gastrointestinal cancer is less clear. The goal of this study was to examine whether the current human epidemiological research on occupationally inhaled Cr(VI) supports the hypothesis that Cr(VI) is associated with human stomach cancer. Following a thorough literature search and review of individual studies, we used meta-analysis to summarise the current epidemiological literature on inhaled Cr(VI) and stomach cancer, explore major sources of heterogeneity, and assess other elements of causal inference. We identified 56 cohort and case-control studies and 74 individual relative risk (RR) estimates on stomach cancer and Cr(VI) exposure or work in an occupation associated with high Cr(VI) exposure including chromium production, chrome plating, leather work and work with Portland cement. The summary RR for all studies combined was 1.27 (95% CI 1.18 to 1.38). In analyses limited to only those studies identifying increased risks of lung cancer, the summary RR for stomach cancer was higher (RR=1.41, 95% CI 1.18 to 1.69). Overall, these results suggest that Cr(VI) is a stomach carcinogen in humans, which is consistent with the tumour results reported in rodent studies. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  15. GeoViQua: quality-aware geospatial data discovery and evaluation

    NASA Astrophysics Data System (ADS)

    Bigagli, L.; Papeschi, F.; Mazzetti, P.; Nativi, S.

    2012-04-01

    GeoViQua (QUAlity aware VIsualization for the Global Earth Observation System of Systems) is a recently started FP7 project aiming at complementing the Global Earth Observation System of Systems (GEOSS) with rigorous data quality specifications and quality-aware capabilities, in order to improve reliability in scientific studies and policy decision-making. GeoViQua main scientific and technical objective is to enhance the GEOSS Common Infrastructure (GCI) providing the user community with innovative quality-aware search and evaluation tools, which will be integrated in the GEO-Portal, as well as made available to other end-user interfaces. To this end, GeoViQua will promote the extension of the current standard metadata for geographic information with accurate and expressive quality indicators, also contributing to the definition of a quality label (GEOLabel). GeoViQua proposed solutions will be assessed in several pilot case studies covering the whole Earth Observation chain, from remote sensing acquisition to data processing, to applications in the main GEOSS Societal Benefit Areas. This work presents the preliminary results of GeoViQua Work Package 4 "Enhanced geo-search tools" (WP4), started in January 2012. Its major anticipated technical innovations are search and evaluation tools that communicate and exploit data quality information from the GCI. In particular, GeoViQua will investigate a graphical search interface featuring a coherent and meaningful aggregation of statistics and metadata summaries (e.g. in the form of tables, charts), thus enabling end users to leverage quality constraints for data discovery and evaluation. Preparatory work on WP4 requirements indicated that users need the "best" data for their purpose, implying a high degree of subjectivity in judgment. This suggests that the GeoViQua system should exploit a combination of provider-generated metadata (objective indicators such as summary statistics), system-generated metadata (contextual

  16. A Salmonella Typhimurium-Typhi Genomic Chimera: A Model to Study Vi Polysaccharide Capsule Function In Vivo

    PubMed Central

    Clare, Simon; Goulding, David; Holt, Kathryn E.; Grant, Andrew J.; Mastroeni, Piero; Dougan, Gordon; Kingsley, Robert A.

    2011-01-01

    The Vi capsular polysaccharide is a virulence-associated factor expressed by Salmonella enterica serotype Typhi but absent from virtually all other Salmonella serotypes. In order to study this determinant in vivo, we characterised a Vi-positive S. Typhimurium (C5.507 Vi+), harbouring the Salmonella pathogenicity island (SPI)-7, which encodes the Vi locus. S. Typhimurium C5.507 Vi+ colonised and persisted in mice at similar levels compared to the parent strain, S. Typhimurium C5. However, the innate immune response to infection with C5.507 Vi+ and SGB1, an isogenic derivative not expressing Vi, differed markedly. Infection with C5.507 Vi+ resulted in a significant reduction in cellular trafficking of innate immune cells, including PMN and NK cells, compared to SGB1 Vi− infected animals. C5.507 Vi+ infection stimulated reduced numbers of TNF-α, MIP-2 and perforin producing cells compared to SGB1 Vi−. The modulating effect associated with Vi was not observed in MyD88−/− and was reduced in TLR4−/− mice. The presence of the Vi capsule also correlated with induction of the anti-inflammatory cytokine IL-10 in vivo, a factor that impacted on chemotaxis and the activation of immune cells in vitro. PMID:21829346

  17. Ferric chloride modified zeolite in wastewater on Cr (VI) adsorption characteristics

    NASA Astrophysics Data System (ADS)

    Wu, Xiaoqing; Zhang, Kang; Chen, Wen; Zhang, Hua

    2018-03-01

    Zeolite was modified by ferric chloride(Fe-Z) removal Cr (VI) ion from wastewater. The results showed that the effect of Cr(VI) adsorption on modified zeolite depended significantly on pH. It is favorable for the adsorption of Cr(VI) in acid condition. The Langmuir isotherm model has high fitting accuracy with experimental data, demonstrated that is monolayer adsorption and chemical adsorption.The pseudo-second-order equation provided the best correlation to the data. The model can describe the adsorption reaction process well.

  18. Aqueous solubility of Cr(VI) compounds in ferrochrome bag filter dust and the implications thereof

    DOE PAGES

    Du Preez, S. P.; Beukes, J. P.; Van Dalen, W. P. J.; ...

    2017-04-21

    The production of ferrochrome (FeCr) is a reducing process. However, it is impossible to completely exclude oxygen from all of the high-temperature production process steps, which may lead to unintentional formation of small amounts of Cr(VI). The majority of Cr(VI) is associated with particles found in the off-gas of the high-temperature processes, which are cleaned by means of venturi scrubbers or bag filter dust (BFD) systems. BFD contains the highest concentration of Cr(VI) of all FeCr wastes. In this study, the solubility of Cr(VI) present in BFD was determined by evaluating four different BFD samples. The results indicate that themore » currently applied Cr(VI) treatment strategies of the FeCr producer (with process water pH ≤ 9) only effectively extract and treat the water-soluble Cr(VI) compounds, which merely represented approximately 31% of the total Cr(VI) present in the BFD samples evaluated. Extended extraction time, within the afore-mentioned pH range, proved futile in extracting sparingly-soluble and water-insoluble Cr(VI) species, which represented approximately 34% and 35% of the total Cr(VI), respectively. Due to the deficiencies of the current treatment strategies, it is highly likely that sparingly water-soluble Cr(VI) compounds will leach from waste storage facilities (e.g. slimes dams) over time. Therefore, it is critical that improved Cr(VI) treatment strategies be formulated, which should be an important future perspective for FeCr producers and researchers alike.« less

  19. Chromium (VI) purification using pine sawdust in batch systems

    NASA Astrophysics Data System (ADS)

    Politi, Dorothea; Sidiras, Dimitris

    2012-12-01

    Pine sawdust, a waste generated in furniture industry, has been used as low-cost potential adsorbent. This low-cost adsorbent was used for the removal of chromium (VI) from an aqueous solution. The kinetics of adsorption and extent of adsorption at equilibrium are dependent on the physical and chemical characteristics of the adsorbent and adsorbate. The effect of hydrogen ion concentration, contact time, adsorbent dose and initial concentration of adsorbate on the uptake of chromium were studied in batch experiments. The adsorption data has been correlated with Lagergren - Eldridge pseudofirst order kinetic model. The efficiency of adsorbent material for the removal of Cr(VI) was found to be between 13.1 and 95.6%, respectively. These results depend on the conditions of pH, contact time, sawdust dose and Cr(VI) concentration.

  20. Experiments indicating a second hydrogen ordered phase of ice VI

    PubMed Central

    Gasser, Tobias M.; Thoeny, Alexander V.; Plaga, Lucie J.; Köster, Karsten W.; Etter, Martin; Böhmer, Roland

    2018-01-01

    In the last twelve years five new ice phases were experimentally prepared. Two of them are empty clathrate hydrates and three of them represent hydrogen ordered counterparts of previously known disordered ice phases. Here, we report on hydrogen ordering in ice VI samples produced by cooling at pressures up to 2.00 GPa. Based on results from calorimetry, dielectric relaxation spectroscopy, Raman spectroscopy, and powder X-ray diffraction the existence of a second hydrogen ordered polymorph related to ice VI is suggested. Powder X-ray data show the oxygen network to be the one of ice VI. For the 1.80 GPa sample the activation energy from dielectric spectroscopy is 45 kJ mol–1, which is much larger than for the known hydrogen ordered proxy of ice VI, ice XV. Raman spectroscopy indicates the 1.80 GPa sample to be more ordered than ice XV. It is further distinct from ice XV in that it experiences hydrogen disordering above ≈103 K which is 26 K below the ice XV to ice VI disordering transition. Consequently, below 103 K it is thermodynamically more stable than ice XV, adding a stability region to the phase diagram of water. For the time being we suggest to call this new phase ice β-XV and to relabel it ice XVIII once its crystal structure is known. PMID:29780552

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