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Sample records for tepid supergiants chemical

  1. The chemical abundances of galactic, A-type super-giants

    NASA Astrophysics Data System (ADS)

    Venn, Kimberley Ann

    1994-01-01

    The chemical composition of 22 massive, Galactic, A-type supergiants is presented in order to study the evolutionary status of these stars. Various evolution scenarios describe vastly different histories for these stars, which can be distinguished by the atmospheric abundances that they predict. Chemical abundances are determined from observations of weak optical spectral lines gathered at the McDonald Observatory An atmospheric analysis is performed for each star adopting the most recent Kurucz LTE model atmospheres. Atmospheric parameters (Teff, log g, xi) are determined from Mg I/II equilibrium and fitting theoretical H-gamma line profiles; we chose the parameters where the loci of possible Teff-gravity values from each indicator intersect. We show that NLTE effects on the Mg I and Mg II abundances are small, but NLTE can strongly affect Fe I abundances such that Fe I/II equilibrium is a poor atmospheric indicator. The metal abundances are calculated assuming LTE. Most metal abundances are solar to within +/-0.2 dex. Overabundances of Na are found in the A-type supergiant atmospheres; we discuss this as combination of possible NLTE effects and/or pollution of newly synthesized Na from a NeNa proton capture reaction that could occur in the stellar cores. Otherwise, we see no evidence of slight overall abundance enrichments relative to solar in these young stars that might be expected due to Galactic chemical evolution. NLTE line formation calculations have been carried out for the nitrogen and carbon abundances. For carbon, we adopt the Sturenburg & Holweger (1992) model atom and extensively test the effects of the atomic data on the resultant NLTE corrections. We find significant NLTE corrections (=log epsilon(XNLTE - log epsilon(X)LTE) for the cooler supergiants that range from -0.15 in the F0 stars to -0.5 in the A3 stars. The mean NLTE carbon abundance is log epsilon(C/H)NLTE = 8.21 +/- 0.11 for the 14 A3-F0 supergiants. For the hotter stars, we show that the only C I lines that we have observed near 9100 A do not yield reliable elemental abundances. For nitrogen, we have constructed a new, detailed model atom. Application of this model to the A-type supergiants shows that departures from LTE strongly affect the nitrogen abundances. NLTE corrections for weak lines are quite large, ranging from -1.0 in the A0 supergiants to -0.3 in the F0 supergiants. The average NLTE nitrogen abundances is log epsilon(N/H)NLTE = 8.06 +/- 0.18 for the 22 A0-F0 supergiants. The NLTE nitrogen abundances do not show the strong dependence we observed in the LTE abundances on the effective temperature. When the NLTE nitrogen and carbon abundances of the A3-F0 supergiants are compared to those of the main-sequence B-stars, we find (log epsilon(N/C)A I - log epsilon(N/C)B*) = +0.33 +/- 0.24. This value is significantly less than the first dredge-up abundances (approximately +0.65 for 10 solar mass stars predicted by several evolution scenarios. However, the N/C ratio suggests that the A-type supergiants have undergone some partial mixing of CN-cycled gas. This is similar to recent abundance results for some B-type supergiants, suggesting that partial mixing may occur near the main-sequence (possibly by turbulent diffusive mixing). We conclude that the 5 to 20 solar mass A-type supergiants in the Galaxy probably have evolved directly from the main-sequence.

  2. Cool giants and supergiants as probes of the chemical evolution of the Milky Way

    NASA Astrophysics Data System (ADS)

    Origlia, Livia

    2015-08-01

    Evolved, cool giant and supergiant stars are among the brightest populations in any stellar system and easily observable out to large distances, especially at infrared wavelengths.These stars also dominate the integrated light of star clusters in a wide range of ages, making them powerful tracers of stellar populations in more distant galaxies.The current generation of medium-high resolution spectrographs in the optical and near IR with high throughput has allowed to get accurate abundances of the most important metals in giants and supergiants, also in high reddened environments like the inner Galaxy disk and bulge and the Galactic center.In this talk I will review some of the most important results obtained so far in tracing the chemical evolution of the inner Galaxy and future perspectives with the next generation of telescopes and instrumentation.

  3. Chemical compositions of 26 distant late-type supergiants and the metallicity gradient in the galactic disk

    SciTech Connect

    Luck, R.E.; Bond, H.E.

    1980-10-01

    From an analysis of high-dispersion Mount Wilson spectroscopic data, we have obtained atmospheric parameters and chemical abundances for 26 distant supergiants of spectral types G through M. Iron-to-hydrogen ratios wth respect to the Sun, (Fe/H), can be determined from this material with an uncertaintly of +- 0.2 dex.

  4. CHEMICAL ABUNDANCE PATTERNS IN THE INNER GALAXY: THE SCUTUM RED SUPERGIANT CLUSTERS

    SciTech Connect

    Davies, Ben; Origlia, Livia; Kudritzki, Rolf-Peter; Figer, Don F.; Rich, R. Michael; Najarro, Francisco; Negueruela, Ignacio; Clark, J. Simon

    2009-05-10

    The location of the Scutum Red Supergiant (RSG) clusters at the end of the Galactic Bar makes them an excellent probe of the Galaxy's secular evolution, while the clusters themselves are ideal testbeds in which to study the predictions of stellar evolutionary theory. To this end, we present a study of the RSG's surface abundances using a combination of high-resolution Keck/NIRSPEC H-band spectroscopy and spectral synthesis analysis. We provide abundance measurements for elements C, O, Si, Mg, Ti, and Fe. We find that the surface abundances of the stars studied are consistent with CNO burning and deep, rotationally enhanced mixing. The average {alpha}/Fe ratios of the clusters are solar, consistent with a thin-disk population. However, we find significantly subsolar Fe/H ratios for each cluster, a result which strongly contradicts a simple extrapolation of the Galactic metallicity gradient to lower Galactocentric distances. We suggest that a simple one-dimensional parameterization of the Galaxy's abundance patterns is insufficient at low Galactocentric distances, as large azimuthal variations may be present. Indeed, we show that the abundances of O, Si, and Mg are consistent with independent measurements of objects in similar locations in the Galaxy. In combining our results with other data in the literature, we present evidence for large-scale ({approx} kpc) azimuthal variations in abundances at Galactocentric distances of 3-5 kpc. While we cannot rule out that this observed behavior is due to systematic offsets between different measurement techniques, we do find evidence for similar behavior in a study of the barred spiral galaxy NGC 4736 which uses homogeneous methodology. We suggest that these azimuthal abundance variations could result from the intense but patchy star formation driven by the potential of the central bar.

  5. Surface abundances of OC supergiants

    NASA Astrophysics Data System (ADS)

    Martins, F.; Foschino, S.; Bouret, J.-C.; Barbá, R.; Howarth, I.

    2016-04-01

    Context. Some O and B stars show unusually strong or weak lines of carbon and/or nitrogen. These objects are classified as OBN or OBC stars. It has recently been shown that nitrogen enrichment and carbon depletion are the most likely explanations for the existence of the ON class. Aims: We investigate OC stars (all being supergiants) to check that surface abundances are responsible for the observed anomalous line strengths. Methods: We perform a spectroscopic analysis of three OC supergiants using atmosphere models. A fourth star was previously studied by us. Our sample thus comprises all OC stars known to date in the Galaxy. We determine the stellar parameters and He, C, N, and O surface abundances. Results: We show that all stars have effective temperatures and surface gravities fully consistent with morphologically normal O supergiants. However, OC stars show little, if any, nitrogen enrichment and carbon surface abundances consistent with the initial composition. OC supergiants are thus barely chemically evolved, unlike morphologically normal O supergiants. Based on observations obtained at the ESO/La Silla Observatory under programs 081.D-2008, 083.D-0589, 089.D-0975.

  6. In tepid defense of population health: physicians and antibiotic resistance.

    PubMed

    Saver, Richard S

    2008-01-01

    Antibiotic resistance menaces the population as a dire public health threat and costly social problem. Recent proposals to combat antibiotic resistance focus to a large degree on supply side approaches. Suggestions include tinkering with patent rights so that pharmaceutical companies have greater incentives to discover novel antibiotics as well as to resist overselling their newer drugs already on market. This Article argues that a primarily supply side emphasis unfortunately detracts attention from physicians' important demand side influences. Physicians have a vital and unavoidably necessary role to play in ensuring socially optimal access to antibiotics. Dismayingly, physicians' management of the antibiotic supply has been poor and their defense of population health tepid at best. Acting as a prudent steward of the antibiotic supply often seems to be at odds with a physician's commonly understood fiduciary duties, ethical obligations, and professional norms, all of which traditionally emphasize the individual health paradigm as opposed to population health responsibilities. Meanwhile, physicians face limited incentives for antibiotic conservation from other sources, such as malpractice liability, regulatory standards, and reimbursement systems. While multifaceted efforts are needed to combat antibiotic resistance effectively, physician gatekeeping behavior should become a priority area of focus. This Article considers how health law and policy tools could favorably change the incentives physicians face for antibiotic conservation. A clear lesson from the managed care reform battles of the recent past is that interventions, to have the best chance of success, need to respect physician interest in clinical autonomy and individualized medicine even if, somewhat paradoxically, vigorously promoting population health perspectives. Also, physicians' legal and ethical obligations need to be reconceptualized in the antibiotic context in order to better support gatekeeping in defense of population health. The principal recommendation is for increased use of financial incentives to reward physicians for compliance with recommended guidelines on antibiotic prescribing. Although not a panacea, greater experimentation with financial incentives can provide a much needed jump-start to physician interest in antibiotic conservation and likely best address physicians' legitimate clinical autonomy concerns. PMID:19216245

  7. Chemical composition of B-type supergiants in the OB 8, OB 10, OB 48, OB 78 associations of M 31

    NASA Astrophysics Data System (ADS)

    Trundle, C.; Dufton, P. L.; Lennon, D. J.; Smartt, S. J.; Urbaneja, M. A.

    2002-11-01

    Absolute and differential chemical abundances are presented for the largest group of massive stars in M 31 studied to date. These results were derived from intermediate resolution spectra of seven B-type supergiants, lying within four OB associations covering a galactocentric distance of 5-12 kpc. The results are mainly based on an LTE analysis, and we additionally present a full non-LTE, unified model atmosphere analysis of one star (OB 78-277) to demonstrate the reliability of the differential LTE technique. A comparison of the stellar oxygen abundance with that of previous nebular results shows that there is an offset of between ~ 0.15-0.4 dex between the two methods which is critically dependent on the empirical calibration adopted for the R_23 parameter with [O/H]. However within the typical errors of the stellar and nebular analyses (and given the strength of dependence of the nebular results on the calibration used) the oxygen abundances determined in each method are fairly consistent. We determine the radial oxygen abundance gradient from these stars, and do not detect any systematic gradient across this galactocentric range. We find that the inner regions of M 31 are not, as previously thought, very ``metal rich''. Our abundances of C, N, O, Mg, Si, Al, S and Fe in the M 31 supergiants are very similar to those of massive stars in the solar neighbourhood.

  8. Secular resonant dressed orbital diffusion - I. Method and WKB limit for tepid discs

    NASA Astrophysics Data System (ADS)

    Fouvry, Jean-Baptiste; Pichon, Christophe; Prunet, Simon

    2015-05-01

    The equation describing the secular diffusion of a self-gravitating collisionless system induced by an exterior perturbation is derived while assuming that the time-scale corresponding to secular evolution is much larger than that corresponding to the natural frequencies of the system. Its two-dimensional formulation for a tepid galactic disc is also derived using the epicyclic approximation. Its Wentzel-Kramers-Brillouin (WKB) limit is found while assuming that only tightly wound transient spirals are sustained by the disc. It yields a simple quadrature for the diffusion coefficients which provides a straightforward understanding of the loci of maximal diffusion within the disc.

  9. The Winds of B Supergiants

    NASA Technical Reports Server (NTRS)

    Fullerton, A. W.; Massa, D. L.; Prinja, R. K.; Owocki, S. P.; Cranmer, S. R.

    1998-01-01

    This report summarizes the progress of the work conducted under the program "The Winds of B Supergiants," conducted by Raytheon STX Corporation. The report consists of a journal article "Wind variability in B supergiants III. Corotating spiral structures in the stellar wind of HD 64760." The first step in the project was the analysis of the 1996 time series of 2 B supergiants and an O star. These data were analyzed and reported on at the ESO workshop, "Cyclical Variability in Stellar Winds."

  10. Secular resonant dressed orbital diffusion - II. Application to an isolated self-similar tepid galactic disc

    NASA Astrophysics Data System (ADS)

    Fouvry, Jean-Baptiste; Pichon, Christophe

    2015-05-01

    The main orbital signatures of the secular evolution of an isolated self-gravitating stellar Mestel disc are recovered using a dressed Fokker-Planck formalism in angle-action variables. The shot-noise-driven formation of narrow ridges of resonant orbits is recovered in the WKB limit of tightly wound transient spirals, for a tepid Toomre-stable tapered disc. The relative effect of the bulge, the halo, the disc temperature and the spectral properties of the shot noise are investigated in turn. For such galactic discs all elements seem to impact the locus and direction of the ridge. For instance, when the halo mass is decreased, we observe a transition between a regime of heating in the inner regions of the disc through the inner Lindblad resonance to a regime of radial migration of quasi-circular orbits via the corotation resonance in the outer part of the disc. The dressed secular formalism captures both the nature of collisionless systems (via their natural frequencies and susceptibility), and their nurture via the structure of the external perturbing power spectrum. Hence it provides the ideal framework in which to study their long-term evolution.

  11. Model atmospheres and spectroscopy of red supergiants

    NASA Astrophysics Data System (ADS)

    Bergemann, Maria

    2015-08-01

    Cool red supergiants are among the most complex and fascinating stars in the Universe. They can be observed to enormous distances allowing us to study the key property of their host galaxies - chemical abundances. I will review different aspects of spectroscopic diagnosis of giants and show how these impact science done with Galactic and extra-galactic observations. I will also assess the of potential of the planned instruments to provide different stellar information with new generations of models, such as the quality and families of chemical abundances in stars.

  12. The Winds of B Supergiants

    NASA Technical Reports Server (NTRS)

    Massa, D.; Fullerton, A. W.; Prinja, R. K.

    1998-01-01

    This quarterly report is comprised of a paper, "Rotational Modulation of B Supergiant Winds" presented at the ESO workshop "Cyclical Variability in Stellar Winds." Presented is a 30-day IUE time series of the BO Ia HD 91969, a member of the Carina open cluster NGC 3293, which showed, among other things, that wind lines that probe more deeply into the wind vary more regularly.

  13. Atmospheres, magnetism, mass loss of red supergiant stars

    NASA Astrophysics Data System (ADS)

    Josselin, E.; Lambert, J.; Aurire, M.; Petit, P.; Ryde, N.

    2015-10-01

    Red supergiant stars (RSGs) are not only a key evolutionary stage of massive stars participating in the chemical evolution of galaxies, they also represent a fantastic and challenging laboratory of (magneto-)hydrodynamics. We present recent results and on-going research on mass loss, atmospheres, and polarimetric studies of RSGs that reveal a magnetic field of unknown origin. We discuss the potential interplay between these different processes.

  14. Secular diffusion in discrete self-gravitating tepid discs. I. Analytic solution in the tightly wound limit

    NASA Astrophysics Data System (ADS)

    Fouvry, J. B.; Pichon, C.; Chavanis, P. H.

    2015-09-01

    The secular evolution of an infinitely thin tepid isolated galactic disc made of a finite number of particles is described using the inhomogeneous Balescu-Lenard equation. Assuming that only tightly wound transient spirals are present in the disc, a WKB approximation provides a simple and tractable quadrature for the corresponding drift and diffusion coefficients. It provides insight into the physical processes at work during the secular diffusion of a self-gravitating discrete disc and makes quantitative predictions on the initial variations of the distribution function in action space. When applied to the secular evolution of an isolated stationary self-gravitating Mestel disc, this formalism predicts the initial importance of the corotation resonance in the inner regions of the disc leading to a regime involving radial migration and heating. It predicts in particular the formation of a ridge-like feature in action space, in agreement with simulations, but over-estimates the timescale involved in its appearance. Swing amplification is likely needed to resolve this discrepancy. In astrophysics, the inhomogeneous Balescu-Lenard equation and its WKB limit may also describe the secular diffusion of giant molecular clouds in galactic discs, the secular migration and segregation of planetesimals in proto-planetary discs, or even the long-term evolution of population of stars within the Galactic centre. Appendices are available in electronic form at http://www.aanda.org

  15. Open clusters rich in red supergiants

    NASA Astrophysics Data System (ADS)

    Negueruela, Ignacio

    2015-08-01

    In the past few years, several clusters containing large numbers of red supergiants have been discovered. These clusters are amongst the most massive young clusters known in the Milky Way, with stellar masses reaching a few tens of thousands of solar masses. They have provided us, for the first time, with large homogeneous samples of red supergiants of a given age. These large populations make them, despite heavy extinction along their sightlines, powerful laboratories to understand the evolutionary status of red supergiants. While some of the clusters, such as the eponymous RSGC1, are so obscured that their members are only observable in the near-IR, at least van der Bergh-Hagen 222 is observable even in the U band, allowing for an excellent characterisation of cluster and stellar properties. The information gleaned so far from these clusters gives strong support to the idea that late-M type supergiants represent a separate class, characterised by very heavy mass loss. It also shows that the spectral-type distribution of red supergiants in the Milky Way is very strongly peaked towards M1, while providing strong hints about the possible evolutionary sequence of red supergiants. In addition, the clusters of red supergiants represent ideal tools to study metallicity in the inner regions of the Milky Way.

  16. The Winds of B Supergiants

    NASA Technical Reports Server (NTRS)

    Massa, D.; Oliversen, R. (Technical Monitor)

    2002-01-01

    We present the most suitable data sets available in the International Ultraviolet Explorer (IUE) archive for the study of time-dependent stellar winds in early B supergiants. The UV line profile variability in 11 B0 to B3 stars is analyzed, compared and discussed, based on 16 separate data sets comprising over 600 homogeneously reduced high-resolution spectrograms. The targets include 'normal' stars with moderate rotation rates and examples of rapid rotators. A gallery of grey-scale images (dynamic spectra) is presented, which demonstrates the richness and range of wind variability and highlights different structures in the winds of these stars. This work emphasises the suitability of B supergiants for wind studies, under-pinned by the fact that they exhibit unsaturated wind lines for a wide range of ionization. The wind activity of B supergiants is substantial and has highly varied characteristics. The variability evident in individual stars is classified and described in terms of discrete absorption components, spontaneous absorption, bowed structures, recurrence, and ionization variability and stratification. Similar structures can occur in stars of different fundamental parameters, but also different structures may occur in the same star at a given epoch. We discuss the physical phenomena that may be associated with the spectral signatures, and highlight the challenges that these phenomena present to theoretical studies of time-dependent outflows in massive stars. In addition, SEI line-synthesis modelling of the UV wind lines is used to provide further information about the state of the winds in our program stars. Typically the range, implied by the line profile variability, in the product of mass-loss rate and ion fraction (M (dot) q(sub i)) is a factor of approximately 1.5, when integrated between 0.2 and 0.9 v infinity; it can however be several times larger over localized velocity regions. At a given effective temperature the mean relative ion ratios can differ by a factor of 5. The general excess in predicted (forward-scattered) emission in the low velocity regime is discussed in terms of structured outflows. Mean ion fractions are estimated over the B0 to B1 spectral classes, and trends in the ionic ratios as a function of wind velocity are described. The low values obtained for the ion fractions of UV resonance lines may reflect the role of clumping in the wind.

  17. The Winds of B Supergiants

    NASA Technical Reports Server (NTRS)

    Massa, Derck; West, D. (Technical Monitor)

    2002-01-01

    We present the most suitable data sets available in the International Ultraviolet Explorer (IUE) archive for the study of time-dependent stellar winds in early B supergiants. The UV line profile variability in 11 B0 to B3 stars is analyzed, compared and discussed, based on 16 separate data sets comprising over 600 homogeneously reduced high-resolution spectrograms. The targets include 'normal' stars with moderate rotation rates and examples of rapid rotators. A gallery of grey-scale images (dynamic spectra) is presented, which demonstrates the richness and range of wind variability and highlights different structures in the winds of these stars. This work emphasizes the suitability of B supergiants for wind studies, under-pinned by the fact that they exhibit unsaturated wind lines for a wide range of ionization. The wind activity of B supergiants is substantial and has highly varied characteristics. The variability evident in individual stars is classified and described in terms of discrete absorption components, spontaneous absorption, bowed structures, recurrence, and ionization variability and stratification. Similar structures can occur in stars of different fundamental parameters but also different structures may occur in the same star at a given epoch. We discuss the physical phenomena that may be associated with the spectral signatures, and highlight the challenges that these phenomena present to theoretical studies of time-dependent outflows in massive stars. In addition, SEI line-synthesis modelling of the UV wind lines is used to provide further information about the state of the winds in our program stars. Typically the range, implied by the line profile variability, in the product of mass-loss rate and ion fraction (M qi) is a factor of approximately 1.5, when integrated between 0.2 and 0.9 v infinity; it it can however be several times larger over localized velocity regions. At a given effective temperature the mean relative ion ratios can differ by a factor of 5. The general excess in predicted (forward-scattered) emission in the low velocity regime is discussed in turns of structured outflows. Mean ion fractions are estimated over the B0 to B1 spectral classes, and trends in the ionic ratios as a function of wind velocity are described. The low values obtained for the ion fractions of UV resonance lines may reflect the role of clumping in the wind.

  18. Red supergiants as type II supernova progenitors

    NASA Astrophysics Data System (ADS)

    Negueruela, Ignacio; Dorda, Ricardo; González-Fernández, Carlos; Marco, Amparo

    2015-08-01

    Recent searches for supernova IIp progenitors in external galaxies have led to the identification of red objects with magnitudes and colours indicative of red supergiants, in most cases implying quite low luminosities and hence masses well below 10Msol. Stellar models, on the other hand, do not predict explosions from objects below 9 Msol. What does our knowledge of local red supergiants tells us about the expected properties of such objects?We have carried out a comprehensive spectroscopic and photometric study of a sample of hundreds of red supergiants in the Milky Way and both Magellanic Clouds. We have explored correlations between different parameters and the position of stars in the HR diagrams of open clusters. At solar metallicty, there is strong evidence for a phase of very heavy mass loss at the end of the red supergiant phase, but the existence of such a phase is still not confirmed at SMC metallicities. Objects of ~ 7Msol, on the other hand, become very dusty in the SMC, and appear as very luminous Miras.Among Milky Way clusters, we find a surprising lack of objects readily identifiable as the expected 7 to 10 Msol red supergiants or AGB stars. We are carrying out an open cluster survey aimed at filling this region of the HR diagram with reliable data. Finally, we will discuss the implications of all this findings for the expected properties of supernova progenitors, as it looks unlikely that typical red supergiants may explode without undergoing further evolution.

  19. Secular diffusion in discrete self-gravitating tepid discs II. Accounting for swing amplification via the matrix method

    NASA Astrophysics Data System (ADS)

    Fouvry, J. B.; Pichon, C.; Magorrian, J.; Chavanis, P. H.

    2015-12-01

    The secular evolution of an infinitely thin tepid isolated galactic disc made of a finite number of particles is investigated using the inhomogeneous Balescu-Lenard equation expressed in terms of angle-action variables. The matrix method is implemented numerically in order to model the induced gravitational polarisation. Special care is taken to account for the amplification of potential fluctuations of mutually resonant orbits and the unwinding of the induced swing amplified transients. Quantitative comparisons with N-body simulations yield consistent scalings with the number of particles and with the self-gravity of the disc: the fewer the particles and the colder the disc, the faster the secular evolution. Secular evolution is driven by resonances, but does not depend on the initial phases of the disc. For a Mestel disc with Q ~ 1.5, the polarisation cloud around each star boosts its secular effect by a factor of a thousand or more, accordingly promoting the dynamical relevance of self-induced collisional secular evolution. The position and shape of the induced resonant ridge are found to be in very good agreement with the prediction of the Balescu-Lenard equation, which scales with the square of the susceptibility of the disc. In astrophysics, the inhomogeneous Balescu-Lenard equation may describe the secular diffusion of giant molecular clouds in galactic discs, the secular migration and segregation of planetesimals in proto-planetary discs, or even the long-term evolution of population of stars within the Galactic centre. It could be used as a valuable check of the accuracy of N-body integrators on secular timescales. Appendices are available in electronic form at http://www.aanda.orgA copy of the linear matrix response code is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/584/A129

  20. THE TEMPERATURES OF RED SUPERGIANTS

    SciTech Connect

    Davies, Ben; Kudritzki, Rolf-Peter; Gazak, Zach; Plez, Bertrand; Trager, Scott; Lancon, Ariane; Bergemann, Maria; Evans, Chris; Chiavassa, Andrea

    2013-04-10

    We present a re-appraisal of the temperatures of red supergiants (RSGs) using their optical and near-infrared spectral energy distributions (SEDs). We have obtained data of a sample of RSGs in the Magellanic Clouds using VLT+XSHOOTER, and we fit MARCS model atmospheres to different regions of the spectra, deriving effective temperatures for each star from (1) the TiO bands, (2) line-free continuum regions of the SEDs, and (3) the integrated fluxes. We show that the temperatures derived from fits to the TiO bands are systematically lower than the other two methods by several hundred kelvin. The TiO fits also dramatically overpredict the flux in the near-IR, and imply extinctions which are anomalously low compared to neighboring stars. In contrast, the SED temperatures provide good fits to the fluxes at all wavelengths other than the TiO bands, are in agreement with the temperatures from the flux integration method, and imply extinctions consistent with nearby stars. After considering a number of ways to reconcile this discrepancy, we conclude that three-dimensional effects (i.e., granulation) are the most likely cause, as they affect the temperature structure in the upper layers where the TiO lines form. The continuum, however, which forms at much deeper layers, is apparently more robust to such effects. We therefore conclude that RSG temperatures are much warmer than previously thought. We discuss the implications of this result for stellar evolution and supernova progenitors, and provide relations to determine the bolometric luminosities of RSGs from single-band photometry.

  1. Mass loss in red giants and supergiants

    NASA Technical Reports Server (NTRS)

    Sanner, F.

    1975-01-01

    The circumstellar envelopes surrounding late-type giants and supergiants were studied using high resolution, photoelectric scans of strong optical resonance lines. A method for extracting the circumstellar from the stellar components of the lines allowed a quantitative determination of the physical conditions in the envelopes and the rates of mass loss at various positions in the red giant region of the HR diagram. The observed strengthening of the circumstellar spectrum with increasing luminosity and later spectral type is probably caused by an increase in the mass of the envelopes. The mass loss rate for individual stars is proportional to the visual luminosity; high rates for the supergiants suggest that mass loss is important in their evolution. The bulk of the mass return to the interstellar medium in the red giant region comes from the normal giants, at a rate comparable to that of planetary nebulae.

  2. Optical Interferometry of Giants and Supergiants

    NASA Astrophysics Data System (ADS)

    Kloppenborg, Brian; van Belle, Gerard

    Over the last several decades optical interferometers have made substantial gains in ability, evolving from simple two-telescope arrays with 10-m baselines that primarily measured the angular diameters of stars, to four- to six-telescope arrays with 300-m baselines that are capable of imaging objects at high spatial resolution (0.3 milli-arcseconds) and high spectral resolution (R 30, 000). This chapter highlights how optical interferometers have been used during the last three decades to study single and binary systems containing giant and supergiant stars. It reviews diameter measurements and astrometry for single and binary stars, discusses the asymmetric mass-loss processes seen in asymptotic giant-branch stars, shows how resolving stellar disks is helping to solve long-standing problems related to carbon stars, and summarizes some of the state-of-the-art techniques that are now being used to image spots and convective cells on supergiants.

  3. Fossil dust shells around luminous supergiants

    NASA Technical Reports Server (NTRS)

    Stothers, R.

    1975-01-01

    The observed frequency with which infrared excesses appear in F, G, and K supergiants of luminosity class Ia supports the idea that these excesses arise in a 'fossil' circumstellar dust shell that was formed during a prior M-super-giant phase of evolution. The required leftward evolution of the star on the H-R diagram would then imply that the Ledoux, rather than the Schwarzschild, criterion for convective mixing is the correct criterion to use in stellar evolution calculations.

  4. Spectral atlas of A-type supergiants

    NASA Astrophysics Data System (ADS)

    Klochkova, V. G.; Sendzikas, E. G.; Chentsov, E. L.

    2015-01-01

    Using the data from the observations carried out with a high spectral resolution of R = 60 000 at the 6-m BTA telescope in combination with the echelle spectrograph NES, we thoroughly studied the characteristics of the optical spectra of the A supergiants 3 Pup, BD+481220, and ? Cyg, which belong to essentially different stages of evolution. A spectral atlas for these stars was compiled in the wavelength interval of 3920 to 6720 .

  5. The Supergiants in the Andromeda and Triangulum Galaxies

    NASA Astrophysics Data System (ADS)

    Zhang, Huawei; Huang, Yang; Liu, Xiaowei; Luo, Ali; Wu, Zhenyu; Yuan, Haibo; Xiang, Maosheng; Chen, Bingqiu

    2015-08-01

    We present systematic identifications of supergiant in M31/M33 by using LAMOST spectroscopic survey. Radial velocities of nearly 1200 individual photometric candidates were derived from the spectra observed by LAMOST in its past three years spectroscopic survey. By comparing the radial velocities of the targets and those expected from M31/M33's rotation curves, we identify 113 supergiant members of M31 and 106 supergiant members of M33. So far, this is the largest supergiant sample of M31/M33 with spectra covered the full optical range (e.g. 3700supergiant members and thus to constrain the stellar evolution model of massive stars.

  6. Stellar Parameters and Winds of Red Supergiants in Binaries

    NASA Astrophysics Data System (ADS)

    Bennett, K.

    The proposed target stars (zeta Aur, 31 Cyg) are eclipsing binary systems with K supergiant primaries and B-type main sequence companions. From these binaries, we will determine key information about fundamental stellar parameters and outer atmospheric structure that can not be obtained from observations of single red supergiants. The proposed observations are directed towards understanding the mass loss process driving the massive winds of red supergiants. In particular, the proposed FUSE observations will support the following analyses: -- detailed model atmosphere analyses of the B-stars' continua -- determining accurate radial velocities of the B-type secondaries -- analyses of the wind absorption features of the red supergiant primaries. From these FUSE observations, we will determine improved fundamental stellar parameters of red supergiants (effective temperatures, radii, masses and luminosities) and wind properties (velocity laws and mass loss rates).

  7. Fine structure line emission from supergiants

    NASA Technical Reports Server (NTRS)

    Haas, Michael R.; Glassgold, Alfred E.; Tielens, Alexander G. G. M.

    1995-01-01

    We have detected (O I) 63 micron and (Si II) 35 micron emission from the oxygen-rich, M supergiants alpha Orionis (Betelgeuse), alpha Scorpii (Antares), and alpha Herculis (Rasalgethi). The measured fluxes indicate that the emission originates in dense, warm gas in the inner envelope or transition region where molecules and dust are expected to form and the acceleration of the wind occurs. Mass-loss rates are derived, evidence for time variability is presented, and results for other evolved stars are included.

  8. Postexplosion hydrodynamics of supernovae in red supergiants

    NASA Technical Reports Server (NTRS)

    Herant, Marc; Woosley, S. E.

    1994-01-01

    Shock propagation, mixing, and clumping are studied in the explosion of red supergiants as Type II supernovae using a two-dimensional smooth particle hydrodynamic (SPH) code. We show that extensive Rayleigh-Talor instabilities develop in the ejecta in the wake of the reverse shock wave. In all cases, the shell structure of the progenitor is obliterated to leave a clumpy, well-mixed supernova remnant. However, the occurrence of mass loss during the lifetime of the progenitor can significantly reduce the amount of mixing. These results are independent of the Type II supernova explosion mechanism.

  9. RED SUPERGIANT STARS AS COSMIC ABUNDANCE PROBES. II. NLTE EFFECTS IN J-BAND SILICON LINES

    SciTech Connect

    Bergemann, Maria; Kudritzki, Rolf-Peter; Wuerl, Matthias; Plez, Bertrand; Davies, Ben; Gazak, Zach E-mail: Matthias.Wuerl@physik.uni-muenchen.de E-mail: zgazak@ifa.hawaii.edu E-mail: bdavies@ast.cam.ac.uk

    2013-02-20

    Medium-resolution J-band spectroscopy of individual red supergiant stars is a promising tool to investigate the chemical composition of the young stellar population in star-forming galaxies. As a continuation of recent work on iron and titanium, detailed non-LTE (NLTE) calculations are presented to investigate the influence of NLTE on the formation of silicon lines in the J-band spectra of red supergiants. Substantial effects are found resulting in significantly stronger absorption lines of neutral silicon in NLTE. As a consequence, silicon abundances determined in NLTE are significantly smaller than in local thermodynamic equilibrium (LTE) with the NLTE abundance corrections varying smoothly between -0.4 dex and -0.1 dex for effective temperatures between 3400 K and 4400 K. The effects are largest at low metallicity. The physical reasons behind the NLTE effects and the consequences for extragalactic J-band abundance studies are discussed.

  10. Long term variability of B supergiant winds

    NASA Technical Reports Server (NTRS)

    Massa, Derck L.

    1995-01-01

    The object of this observing proposal was to sample wind variability in B supergiants on a daily basis over a period of several days in order to determine the time scale with which density variability occurs in their winds. Three stars were selected for this project: 69 Cyg (B0 Ib), HD 164402 (B0 Ib), and HD 47240 (B1 Ib). Three grey scale representations of the Si IV lambda lambda 1400 doublet in each star are attached. In these figures, time (in days) increases upward, and the wavelength (in terms of velocity relative to the rest wavelength of the violet component of the doublet) is the abscissa. The spectra are normalized by a minimum absorption (maximum flux) template, so that all changes appear as absorptions. As a result of these observations, we can now state with some certainty that typical B supergiants develop significant wind inhomogeneities with recurrence times of a few days, and that some of these events show signs of strong temporal coherence.

  11. Red supergiants as the progenitors of type IIp supernovae

    NASA Astrophysics Data System (ADS)

    Maund, Justyn

    2015-08-01

    The direct observation of the progenitors of supernovae has provided important tests for our understanding of the late stages of massive star evolution and how these stars will eventually explode at the ends of their lives. There has been major success in the identification of red supergiants as the progenitors of hydrogen rich Type II supernovae. Here I will review the latest results from efforts to identify red supergiant progenitors prior toexplosion, and the relationship between the properties of these stars and the general population of red supergiants.

  12. Calcium abundances of F supergiants in the Magellanic Clouds

    SciTech Connect

    Smith, H.A.

    1980-07-01

    Low-dispersion image tube spectra have been obtained for six supergiant stars in the Large Magellanic Cloud and for four supergiants in the Small Magellanic Cloud. These stars are of spectral type F, though differences from galactic MK standards make precise classification difficult. The observed calcium K-line and Balmer-line strengths have been compared with simple synthetic spectra based on the model atmospheres of Kurucz. For the LMC stars, (Ca/H)=-0.2 +- 0.1; for the SMC stars, (Ca/H)=-0.6 +- 0.1. Better model atmospheres and synthetic spectra for supergiant stars are desirable to improve these values.

  13. Hunting for exploding red supergiant stars

    NASA Astrophysics Data System (ADS)

    Messineo, Maria; Menten, Karl M.; Figer, Donald F.; Ivanov, Valentin D.; Zhu, Qingfeng; Kudritzki, Rolf-Peter; Davies, Ben; Clark, J. Simon; Rich, Michael; Chen, Rosie; Trombley, Christine; MacKenty, John W.; Habing, Harm; Churchwell, Edward

    2015-08-01

    Red supergiants (RSGs) are among the brightest Galactic stars at infrared wavelengths. They lose mass at high-rates and, eventually, explode as supernovae, enriching the interstellar medium. I would like to present results on our ongoing searches for candidate obscured-far-luminous late-type stars, which are based on 2MASS, UKIDSS, and GLIMPSE data, on extinction-free colors(Messineo et al. 2012, A&A, 537) and on the analysis of the extinction curve along a given line-of-sight with clump stars. Messineo et al. (2014, A&A, 571, 43) spectroscopically confirmed two clusters of red supergiants, one on the Sagittarius-Carina spiral arm at a distance of ~7 kpc, and another on the Scutum-Crux arm at a distance of ~4 kpc; while Messineo et al. (2014, A&A, 569, 20) have, found several RSGs in the core of SNRs W41 and within the area covered by the SNR G22.7-0.2 in the GMC G23.3-0.3. SNR G22.7-0.2 appears to be most likely a type II SNR.Messineo , M.; Menten, K. M.; Churchwell, E.; Habing, H. 2012A&A...537A..10MMessineo, Maria; Zhu, Qingfeng; Ivanov, Valentin D.; Figer, Donald F.; Davies, Ben; Menten, Karl M.; Kudritzki, Rolf P.; Chen, C.-H. Rosie 2014A&A...571A..43MMessineo, Maria; Menten, Karl M.; Figer, Donald F.; Davies, Ben; Clark, J. Simon; Ivanov, Valentin D.; Kudritzki, Rolf-Peter; Rich, R. Michael; MacKenty, John W.; Trombley, Christine; 2014A&A...569A..20M

  14. X-ray emission from supergiant shell in the LMC.

    NASA Astrophysics Data System (ADS)

    Bomans, D. J.; Chu, Y.-H.; Magnier, E. A.; Points, S.

    1996-02-01

    The authors have used the Snowden & Petre (1995) mosaics of pointed ROSAT PSPC observations of the Large Magellanic Cloud to study the X-ray characteristics of supergiant shells. Diffuse soft X-ray emission above the background is detected in all of the well-defined supergiant shells. The observed large range of X-ray properties can be explained by differential obscuration, temperature and density differences, and localized heating by supernova remnants.

  15. Pulsational instability in B-type supergiant stars

    NASA Astrophysics Data System (ADS)

    Daszy?ska-Daszkiewicz, J.; Ostrowski, J.; Pamyatnykh, A. A.

    2013-07-01

    We present results of the instability analysis of the post-main sequence massive star models against radial and non-radial pulsations. We confirm that both p- and g-modes can be excited by the ?-mechanism acting in the metal opacity bump. However, as opposed to the previous claims, we find that an intermediate convective zone related to the hydrogen burning shell is not necessary for excitation of g-modes. These modes can be reflected at a minimum of the Brunt-Visl frequency, located at the top of the chemical composition gradient region surrounding the radiative helium core. This minimum is associated with the change of the actual temperature gradient from the adiabatic value in the semiconvective zone to the radiative value above it. Thus, the existence of pulsations at this evolutionary stage does not prove the existence of the convective zone but only some reflective layer. Finally, we show that no regular patterns can be expected in the oscillation spectra of blue supergiant pulsators, but there is a prospect for identification of the mode degree, ?, from multicolour photometry.

  16. X-ray Variability in the Hot Supergiant zgr Orionis.

    PubMed

    Berghfer, T W; Schmitt, J H

    1994-09-16

    Hot massive stars represent only a small fraction of the stellar population of the galaxy, but their enormous luminosities make them visible over large distances. Therefore, they are ideal standard candles, used to determine distances of near galaxies. Their mass loss due to supersonic winds driven by radiation pressure contributes significantly to the interstellar medium and thus to the chemical evolution of galaxies. All hot stars are soft x-ray sources; in contrast to the sun with its highly variable x-ray flux, long time scale x-ray variability is not common among hot stars. An analysis is presented here of an unusual increase in x-ray flux observed with the roentgen observatory satellite during a period of 2 days for the hot supergiant zeta Orionis, the only episode of x-ray variability that has been found in a hot star. These observations provide the most direct evidence so far for the scenario of shock-heated gas in the winds of hot stars. PMID:17770897

  17. Wind Variability in Intermediate Luminosity B Supergiants

    NASA Technical Reports Server (NTRS)

    Massa, Derck

    1996-01-01

    This study used the unique spectroscopic diagnostics of intermediate luminosity B supergiants to determine the ubiquity and nature of wind variability. Specifically, (1) A detailed analysis of HD 64760 demonstrated massive ejections into its wind, provided the first clear demonstration of a 'photospheric connection' and ionization shifts in a stellar wind; (2) The international 'IUE MEGA campaign' obtained unprecedented temporal coverage of wind variability in rapidly rotating stars and demonstrated regularly repeating wind features originating in the photosphere; (3) A detailed analysis of wind variability in the rapidly rotating B1 Ib, gamma Ara demonstrated a two component wind with distinctly different mean states at different epochs; (4) A follow-on campaign to the MEGA project to study slowly rotating stars was organized and deemed a key project by ESA/NASA, and will obtain 30 days of IUE observations in May-June 1996; and (5) A global survey of archival IUE time series identified recurring spectroscopic signatures, identified with different physical phenomena. Items 4 and 5 above are still in progress and will be completed this summer in collaboration with Raman Prinja at University College, London.

  18. A Runaway Red Supergiant in M31

    NASA Astrophysics Data System (ADS)

    Evans, Kate Anne; Massey, Philip

    2016-01-01

    A significant percentage of OB stars are runaways, so we should expect a similar percentage of their evolved descendants to also be runaways. However, recognizing such stars presents its own set of challenges, as these older, more evolved stars will have drifted further from their birthplace, and thus their velocities might not be obviously peculiar. Several Galactic red supergiants (RSGs) have been described as likely runaways, based upon the existence of bow shocks, including Betelgeuse. Here we announce the discovery of a runaway RSG in M31, based upon a 300 km s-1 discrepancy with M31's kinematics. The star is found about 21? (4.6 kpc) from the plane of the disk, but this separation is consistent with its velocity and likely age (10 Myr). The star, J004330.06+405258.4, is an M2 I, with MV=-5.7, log L/L?=4.76, an effective temperature of 3700 K, and an inferred mass of 12-15 M?. The star may be a high-mass analog of the hypervelocity stars, given that its peculiar space velocity is probably 400-450 km s-1, comparable to the escape speed from M31's disk. K. A. E.'s work was supported by the NSF's Research Experience for Undergraduates program through AST-1461200, and P. M.'s was partially supported by the NSF through AST-1008020 and through Lowell Observatory.

  19. A Runaway Red Supergiant in M31

    NASA Astrophysics Data System (ADS)

    Evans, Kate Anne; Massey, Philip

    2015-11-01

    A significant percentage of OB stars are runaways, so we can expect a similar percentage of their evolved descendants to also be runaways. However, recognizing such stars presents its own set of challenges, as these older, more evolved stars will have drifted farther from their birthplace, and thus their velocities might not be obviously peculiar. Several Galactic red supergiants (RSGs) have been described as likely runaways based on the existence of bow shocks, including Betelgeuse. Here we announce the discovery of a runaway RSG in M31 based on a 300 km s-1 discrepancy with M31's kinematics. The star is found about 21‧ (4.6 kpc) from the plane of the disk, but this separation is consistent with its velocity and likely age (˜10 Myr). The star, J004330.06+405258.4, is an M2 I, with MV = -5.7, {log}L/{L}⊙ = 4.76, an effective temperature of 3700 K, and an inferred mass of 12-15M⊙. The star may be a high-mass analog of the hypervelocity stars, given that its peculiar space velocity is probably 400-450 km s-1, comparable to the escape speed from M31's disk. Observations reported here were obtained at the MMT Observatory, a joint facility of the University of Arizona and the Smithsonian Institution. This paper uses data products produced by the OIR Telescope Data Center, supported by the Smithsonian Astrophysical Observatory.

  20. Red supergiants around the obscured open cluster Stephenson 2

    NASA Astrophysics Data System (ADS)

    Negueruela, I.; Marco, A.; Gonzlez-Fernndez, C.; Jimnez-Esteban, F.; Clark, J. S.; Garcia, M.; Solano, E.

    2012-11-01

    Context. Several clusters of red supergiants have been discovered in a small region of the Milky Way close to the base of the Scutum-Crux Arm and the tip of the Long Bar. Population synthesis models indicate that they must be very massive to harbour so many supergiants. Amongst these clusters, Stephenson 2, with a core grouping of 26 red supergiants, is a strong candidate to be the most massive young cluster in the Galaxy. Aims: Stephenson 2 is located close to a region where a strong over-density of red supergiants had been found. We explore the actual cluster size and its possible connection to this over-density. Methods: Taking advantage of Virtual Observatory tools, we have performed a cross-match between the DENIS, USNO-B1 and 2MASS catalogues to identify candidate obscured luminous red stars around Stephenson 2, and in a control nearby region. More than 600 infrared bright stars fulfill our colour criteria, with the vast majority having a counterpart in the I band and >400 being sufficiently bright in I to allow observation with a 4-m class telescope. We observed a subsample of ~250 stars, using the multi-object, wide-field, fibre spectrograph AF2 on the WHT telescope in La Palma, obtaining intermediate-resolution spectroscopy in the 7500-9000 range. We derived spectral types and luminosity classes for all these objects and measured their radial velocities. Results: Our targets turned out to be G and K supergiants, late (? M4) M giants, and M-type bright giants (luminosity class II) and supergiants. We found ~35 red supergiants with radial velocities similar to Stephenson 2 members, spread over the two areas surveyed. In addition, we found ~40 red supergiants with radial velocities incompatible in principle with a physical association. Conclusions: Our results show that Stephenson 2 is not an isolated cluster, but part of a huge structure likely containing hundreds of red supergiants, with radial velocities compatible with the terminal velocity at this Galactic longitude (and a distance ~6 kpc). In addition, we found evidence of several populations of massive stars at different distances along this line of sight. Based on observations collected at the William Herschel Telescope (La Palma, Spain).Tables 2 and 3 are available in electronic form at http://www.aanda.org

  1. X-ray emission from Of stars and OB supergiants

    NASA Technical Reports Server (NTRS)

    Cassinelli, J. P.; Waldron, W. L.; Sanders, W. T.; Harnden, F. R., Jr.; Rosner, R.; Vaiana, G. S.

    1981-01-01

    The result of a survey of X-ray emission from luminous early-type stars is reported in which observations were made using the imaging proportional counter on the Einstein Observatory. The survey suggests that all Of stars and OB supergiants earlier than B1 I are X-ray sources with luminosities not less than 10 to the 32nd ergs/s and that some later B supergiants have X-ray luminosities not less than 10 to the 31st ergs/s. The X-ray luminosities are roughly 10 to the -7.2nd of the bolometric luminosities for supergiants earlier than B1 and perhaps a factor of 3 less for later B supergiants. Spectral analysis of the X-rays in conjunction with information on anomalous ionization in the wind from four of the strongest sources implies that the data are not consistent with a model in which the X-rays originate in a thin slab coronal zone at the base of the wind. Constraints on the source of X-rays from B supergiants are derived by combining the X-ray flux information with that on ultraviolet line anomalies.

  2. The 13Carbon footprint of B[e] supergiants

    NASA Astrophysics Data System (ADS)

    Liermann, A.; Kraus, M.; Schnurr, O.; Fernandes, M. Borges

    2010-10-01

    We report on the first detection of 13C enhancement in two B[e] supergiants (B[e]SGs) in the Large Magellanic Cloud. Stellar evolution models predict the surface abundance in 13C to strongly increase during main-sequence and post-main-sequence evolution of massive stars. However, direct identification of chemically processed material on the surface of B[e]SGs is hampered by their dense, disc-forming winds, hiding the stars. Recent theoretical computations predict the detectability of enhanced 13C via the molecular emission in 13CO arising in the circumstellar discs of B[e]SGs. To test this potential method and to unambiguously identify a post-main-sequence B[e] SG by its 13CO emission, we have obtained high-quality K-band spectra of two known B[e] SGs in the Large Magellanic Cloud, using the Very Large Telescope's Spectrograph for INtegral Field Observation in the Near-Infrared (VLT/SINFONI). Both stars clearly show the 13CO band emission, whose strength implies a strong enhancement of 13C, in agreement with theoretical predictions. This first ever direct confirmation of the evolved nature of B[e]SGs thus paves the way to the first identification of a Galactic B[e]SG. Based on observations collected with the ESO VLT Paranal Observatory under programme 384.D-1078(A). E-mail: liermann@mpifr-bonn.mpg.de (AL); kraus@sunstel.asu.cas.cz (MK); oschnurr@aip.de (OS); borges@on.br (MBF)

  3. Red Supergiants as Cosmic Abundance Probes: The Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Davies, Ben; Kudritzki, Rolf-Peter; Gazak, Zach; Plez, Bertrand; Bergemann, Maria; Evans, Chris; Patrick, Lee

    2015-06-01

    Red Supergiants (RSGs) are cool (4000 K), highly luminous stars (L {{10}5} L? ), and are among the brightest near-IR sources in star-forming galaxies. This makes them powerful probes of the properties of their host galaxies, such as kinematics and chemical abundances. We have developed a technique whereby metallicities of RSGs may be extracted from a narrow spectral window around 1 ?m from only moderate resolution data. The method is therefore extremely efficient, allowing stars at large distances to be studied, and so has tremendous potential for extragalactic abundance work. Here, we present an abundance study of the Large and Small Magellanic Clouds (LMC and SMC respectively) using samples of 9-10 RSGs in each. We find average abundances for the two galaxies of {{[Z]}LMC}=-0.37+/- 0.14 and {{[Z]}SMC}=-0.53+/- 0.16 (with respect to a solar metallicity of {{Z}? }=0.012). These values are consistent with other studies of young stars in these galaxies, and though our result for the SMC may appear high it is consistent with recent studies of hot stars which find 0.5-0.8 dex below solar. Our best-fit temperatures are on the whole consistent with those from fits to the optical-infrared spectral energy distributions, which is remarkable considering the narrow spectral range being studied. Combined with our recent study of RSGs in the Galactic cluster Per OB1, these results indicate that this technique performs well over a range of metallicities, paving the way for forthcoming studies of more distant galaxies beyond the Local Group.

  4. Magnetic braking of stellar cores in red giants and supergiants

    SciTech Connect

    Maeder, André; Meynet, Georges E-mail: georges.meynet@unige.ch

    2014-10-01

    Magnetic configurations, stable on the long term, appear to exist in various evolutionary phases, from main-sequence stars to white dwarfs and neutron stars. The large-scale ordered nature of these fields, often approximately dipolar, and their scaling according to the flux conservation scenario favor a fossil field model. We make some first estimates of the magnetic coupling between the stellar cores and the outer layers in red giants and supergiants. Analytical expressions of the truncation radius of the field coupling are established for a convective envelope and for a rotating radiative zone with horizontal turbulence. The timescales of the internal exchanges of angular momentum are considered. Numerical estimates are made on the basis of recent model grids. The direct magnetic coupling of the core to the extended convective envelope of red giants and supergiants appears unlikely. However, we find that the intermediate radiative zone is fully coupled to the core during the He-burning and later phases. This coupling is able to produce a strong spin down of the core of red giants and supergiants, also leading to relatively slowly rotating stellar remnants such as white dwarfs and pulsars. Some angular momentum is also transferred to the outer convective envelope of red giants and supergiants during the He-burning phase and later.

  5. Red supergiants and the past of Cygnus OB2

    NASA Astrophysics Data System (ADS)

    Comerón, F.; Djupvik, A. A.; Schneider, N.; Pasquali, A.

    2016-02-01

    Context. Red supergiants are the evolved descendants of massive stars with initial masses between 7 and 40 M⊙. Their brightness makes them easily detectable in the near infrared, making them useful probes of star formation that occurred several tens of Myr ago. Aims: We investigate the past star formation history of Cygnus OB2, the nearest very massive OB association, using red supergiants as a probe. Our aim is to confirm the evidence, found by previous studies, that star formation in the Cygnus OB2 region started long before the latest burst that gave rise to the dense aggregate of early O-type stars that dominate the appearance of the association at present. Methods: Near-infrared star counts in the Cygnus region reveal moderate evidence for a peak in the areal density of bright, reddened stars approximately coincident with Cygnus OB2. A total of 11 sources are found within a circle of 1° radius centered on the association, of which 4 are non-supergiants based on existing observations. Near-infrared spectroscopy is presented of the remaining seven candidates, including four that have been already classified as M supergiants in the literature. Results: We confirm the presence of seven red supergiants in the region and argue that they are probably physically associated with Cygnus OB2. Their location is roughly coincident with that of the older population identified by previous studies, supporting the scenario in which the main star formation activity in the association has been shifting toward higher Galactic longitudes with time. Their luminosities are compared with the predictions of evolutionary tracks with and without rotation to estimate the mass of their progenitors and ages. In this way, we confirm that massive star formation was already taking place in the area of Cygnus OB2 over 20 Myr ago, and we estimate that the star formation rate in the latest 6 Myr represents a six-fold increase over the massive star formation rate at the time when the progenitors of the current red supergiants were formed. Conclusions: The Cygnus OB2 association has a history of star formation extending into the past for at least about 20 Myr, probably dovetailing with the general history of star formation in the region that gave rise to other associations like the neighboring Cygnus OB9. The sustained massive star formation history also argues for a long lifetime of the giant molecular complex from which Cygnus OB2 formed, whose remnants constitute the present-day Cygnus X complex.

  6. Unveiling the mystery of supergiant fast x-ray transients

    NASA Astrophysics Data System (ADS)

    Bozzo, Enrico

    2008-10-01

    Supergiant Fast X-ray Transients (SFXT) are very variable high mass X-ray binaries in our galaxy. Two models have been proposed to interpret their behavior: (i)a gating mechanism, involving either the centrifugal barrier or ultramagnetic neutron stars (magnetars); (ii)an extermely clumpy wind from the supergiant companion. Here we propose to study the quiescent emission of three SFXTs. By making a comparison between their quiescence and outburst spectra and searching for pulsations and column density variations, we will test the applicability of the above models. These sources might well provide the very first opportunity to detect and study magnetars in binary systems. In any case, very crucial information will be obtained to test the prediction of modern theories of radiatively-driven winds.

  7. Yellow Hypergiants as Dynamically Unstable Post-Red-supergiant Stars

    NASA Technical Reports Server (NTRS)

    Stothers, Richard B.; Chin, Chao-wen; Hansen, James E. (Technical Monitor)

    2001-01-01

    According to recent theoretical studies, the majority of single stars more massive than 30 solar mass successfully evolve into red supergiants, but then lose most of their hydrogen envelopes and metamorphose into hot blue remnants. While they are cool, they become dynamically unstable as a result of high radiation pressure and partial ionization of the gases in their outer layers. It is shown here that these unstable red-supergiant models repeatedly shrink and re-expand on a thermal time scale when perturbed by heavy bursts of mass loss. Consequently, they fill up the domain of yellow hypergiants on the Hertzsprung-Russell diagram and display very fast rates of evolution there, as observed.

  8. Luminosities for two yellow supergiants - Nonvariables and the instability strip

    NASA Technical Reports Server (NTRS)

    Evans, Nancy R.

    1993-01-01

    The luminosities for two yellow supergiants HD 183864 and Psi And = HD 223047 are determined from the IUE spectra of their hot companions. The absolute magnitudes of HD 183864 and HD 223047 are -2.3 and -2.1 mag, respectively, and their companions have spectral types of A0.0 V and B8.8 V. The companion of Psi And is compatible with the orbital motion tentatively detected by speckle interferometric observations. The supergiant luminosities are combined with the Cepheid luminosities determined in the same way, and also the variables and nonvariables from Schmidt's studies of open clusters. As found by Schmidt, the variable and nonvariable supergiants have almost no overlap in the HR diagram. The combined sample defines the locus of the helium burning blue loops of evolutionary tracks. Because no nonvariables are found to the blue of fainter Cepheids, the observed blue edge of the Cepheid region may be partly determined by the blue loops rather than by the region of pulsational instability.

  9. UV emission from he M1 supergiant TV Gem

    NASA Technical Reports Server (NTRS)

    Michalitsianos, A. G.; Kafatos, M.

    1982-01-01

    Low and high dispersion ultraviolet spectra were obtained of the M1 supergiant TV Gem with IUE. Previous IUE observations of this late type supergiant revealed unexpected UV continuum emission, perhaps arising from an early B companion. Low resolution spectra obtained approximately one year apart suggest that the strong Si III in combination perhaps with O I at wavelengths approximately 1300 A varies considerably with time. Large variation in the column density is required to explain these changes. Sporadic mass expulsion with mass loss rates dM/dt approximately 0.00001 solar mass yr minus 1st power from the M supergiant could lead to a dense circumstellar wind near the hot early companion, and thus could account for these observed variations in equivalent width. The high resolution spectrum in the 2000 to 3200 A wavelength range is characterized by narrow absorption lines primarily due to Fe II, Mn II and Mg II (h and k), which are skewed in profile with an extended red wing. This profile structure is tentatively attributed to interstellar absorption and an intervening differentially moving cloud in the direction of Gem OB1, of which TV Gem is a known association member.

  10. GIANO-TNG spectroscopy of red supergiants in the young star cluster RSGC3

    NASA Astrophysics Data System (ADS)

    Origlia, L.; Oliva, E.; Sanna, N.; Mucciarelli, A.; Dalessandro, E.; Scuderi, S.; Baffa, C.; Biliotti, V.; Carbonaro, L.; Falcini, G.; Giani, E.; Iuzzolino, M.; Massi, F.; Sozzi, M.; Tozzi, A.; Ghedina, A.; Ghinassi, F.; Lodi, M.; Harutyunyan, A.; Pedani, M.

    2016-01-01

    Aims: The Scutum complex in the inner disk of the Galaxy has a number of young star clusters dominated by red supergiants that are heavily obscured by dust extinction and observable only at infrared wavelengths. These clusters are important tracers of the recent star formation and chemical enrichment history in the inner Galaxy. Methods: During the technical commissioning and as a first science verification of the GIANO spectrograph at the Telescopio Nazionale Galileo, we secured high-resolution (R ≃ 50 000) near-infrared spectra of five red supergiants in the young Scutum cluster RSGC3. Results: Taking advantage of the full YJHK spectral coverage of GIANO in a single exposure, we were able to measure several tens of atomic and molecular lines that were suitable for determining chemical abundances. By means of spectral synthesis and line equivalent width measurements, we obtained abundances of Fe and iron-peak elements such as Ni, Cr, and Cu, alpha (O, Mg, Si, Ca, Ti), other light elements (C, N, F, Na, Al, and Sc), and some s-process elements (Y, Sr). We found average half-solar iron abundances and solar-scaled [X/Fe] abundance patterns for most of the elements, consistent with a thin-disk chemistry. We found depletion of [C/Fe] and enhancement of [N/Fe], consistent with standard CN burning, and low 12C /13C abundance ratios (between 9 and 11), which require extra-mixing processes in the stellar interiors during the post-main sequence evolution. We also found local standard of rest VLSR = 106 km s-1 and heliocentric Vhel = 90 km s-1 radial velocities with a dispersion of 2.3 km s-1. Conclusions: The inferred radial velocities, abundances, and abundance patterns of RSGC3 are very similar to those previously measured in the other two young clusters of the Scutum complex, RSGC1 and RSGC2, suggesting a common kinematics and chemistry within the Scutum complex.

  11. Disk Tracing for B[e] Supergiants in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Maravelias, G.; Kraus, M.; Aret, A.

    2015-12-01

    B[e] supergiants are evolved massive stars with a complex circumstellar environment. A number of important emission features probe the structure and the kinematics of the circumstellar material. In our survey of Magellanic Cloud B[e] supergiants we focus on the [OI] and [CaII] emission lines, which we identified in four more objects.

  12. Spectroscopic Study of HD 179821 (IRAS 19114+0002): Proto-Planetary Nebula or Supergiant?

    NASA Technical Reports Server (NTRS)

    Reddy, B. E.; Hrivnak, Bruce J.

    1999-01-01

    A detailed chemical composition analysis of the bright post-AGB candidate HD 179821 (IRAS 19114 + 0002) is presented. The LTE analysis, based on high-resolution (R approximately equal 50,000) and high-quality (S/N approximately equal 300) spectra, yields atmospheric parameters T(sub eff) = 6750 K, log g = 0.5, and xi(sub t) = 5.25 km/s. The elemental abundance results of HD 179821 are found to be [Fe/H] = -0.1, [C/Fe] = +0.2, [N/Fe] = +1.3, [O/Fe] = +0.2, [alpha-process/Fe] = +0.5, and [s-process/Fe] = +0.4. These values clearly differ from the elemental abundances of Population I F supergiants. The C, N, and O abundances and the total CNO abundance value relative to Fe, [C+N+O/Fe] = +0.5, indicate that the photosphere of HD 179821 is contaminated with both the H- and He-burning products of the AGB phase. The evidence for He burning through the 3.alpha process and deep AGB mixing also comes from the observed overabundances of s-process elements. Remarkably, the abundance of the element Na is found to be very large, [Na/Fe] = +0.9. The ratio O/C = 2.6 indicates that the atmosphere is oxygen rich. The results of this abundance study support the argument that HD 179821 is a proto-planetary nebula,. probably with an intermediate-mass progenitor. However, the strength of the O I triplet lines at 7774 A and the distance derived from the interstellar Na I D1 and D2 components imply that the star is a luminous object (M(sub bol) approximately -8.9 +/- 1) and thus a massive supergiant. Thus, while this study contributes important new observational results for this star, an unambiguous determination of its evolutionary status has yet to be achieved.

  13. The blue supergiant MN18 and its bipolar circumstellar nebula

    NASA Astrophysics Data System (ADS)

    Gvaramadze, V. V.; Kniazev, A. Y.; Bestenlehner, J. M.; Bodensteiner, J.; Langer, N.; Greiner, J.; Grebel, E. K.; Berdnikov, L. N.; Beletsky, Y.

    2015-11-01

    We report the results of spectrophotometric observations of the massive star MN18 revealed via discovery of a bipolar nebula around it with the Spitzer Space Telescope. Using the optical spectrum obtained with the Southern African Large Telescope, we classify this star as B1 Ia. The evolved status of MN18 is supported by the detection of nitrogen overabundance in the nebula, which implies that it is composed of processed material ejected by the star. We analysed the spectrum of MN18 by using the code CMFGEN, obtaining a stellar effective temperature of ≈21 kK. The star is highly reddened, E(B - V) ≈ 2 mag. Adopting an absolute visual magnitude of MV = -6.8 ± 0.5 (typical of B1 supergiants), MN18 has a luminosity of log L/L⊙ ≈ 5.42 ± 0.30, a mass-loss rate of ≈(2.8-4.5) × 10- 7 M⊙ yr- 1, and resides at a distance of ≈5.6^{+1.5} _{-1.2} kpc. We discuss the origin of the nebula around MN18 and compare it with similar nebulae produced by other blue supergiants in the Galaxy (Sher 25, HD 168625, [SBW2007] 1) and the Large Magellanic Cloud (Sk-69°202). The nitrogen abundances in these nebulae imply that blue supergiants can produce them from the main-sequence stage up to the pre-supernova stage. We also present a K-band spectrum of the candidate luminous blue variable MN56 (encircled by a ring-like nebula) and report the discovery of an OB star at ≈17 arcsec from MN18. The possible membership of MN18 and the OB star of the star cluster Lynga 3 is discussed.

  14. THE YELLOW AND RED SUPERGIANTS OF M33

    SciTech Connect

    Drout, Maria R.; Massey, Philip; Meynet, Georges E-mail: phil.massey@lowell.edu

    2012-05-10

    Yellow and red supergiants are evolved massive stars whose numbers and locations on the Hertzsprung-Russell (H-R) diagram can provide a stringent test for models of massive star evolution. Previous studies have found large discrepancies between the relative number of yellow supergiants (YSGs) observed as a function of mass and those predicted by evolutionary models, while a disagreement between the predicted and observed locations of red supergiants (RSGs) on the H-R diagram was only recently resolved. Here, we extend these studies by examining the YSG and RSG populations of M33. Unfortunately, identifying these stars is difficult as this portion of the color-magnitude diagram is heavily contaminated by foreground dwarfs. We identify the RSGs through a combination of radial velocities and a two-color surface gravity discriminant, and after re-characterizing the rotation curve of M33 with our newly selected RSGs, we identify the YSGs through a combination of radial velocities and the strength of the O I {lambda}7774 triplet. We examine {approx}1300 spectra in total and identify 121 YSGs (a sample that is unbiased in luminosity above log (L/L{sub Sun }) {approx} 4.8) and 189 RSGs. After placing these objects on the H-R diagram, we find that the latest generation of Geneva evolutionary tracks shows excellent agreement with the observed locations of our RSGs and YSGs, the observed relative number of YSGs with mass, and the observed RSG upper mass limit. These models therefore represent a drastic improvement over previous generations.

  15. Massa's star, HD 93840 - A new extreme BN supergiant

    SciTech Connect

    Walborn, N.R.; Fitzpatrick, E.L.; Nichols-Bohlin, J. Princeton Univ. Observatory, NJ Computer Sciences Corp., Lanham, MD )

    1990-05-01

    New optical digital spectrograms of HD 93840 and several comparison objects are presented and discussed, together with IUE high-resolution data for the same stars. The optical observations confirm HD 93840 (BN1 Ib) as an extreme nitrogen-enhanced supergiant, as originally suggested by Massa (1989). The contrasts with HD 96248 (BC1.5 Iab) are especially striking. The rich UV stellar-wind phenomenology of these objects is discussed in some detail. The spectroscopic characteristics and intermediate galactic latitude of HD 93840 suggest a relationship to Rho Leo, and perhaps to HD 105056. 21 refs.

  16. Magnetic main sequence stars as progenitors of blue supergiants

    NASA Astrophysics Data System (ADS)

    Petermann, I.; Castro, N.; Langer, N.

    2015-01-01

    Blue supergiants (BSGs) to the right the main sequence band in the HR diagram can not be reproduced by standard stellar evolution calculations. We investigate whether a reduced convective core mass due to strong internal magnetic fields during the main sequence might be able to recover this population of stars. We perform calculations with a reduced mass of the hydrogen burning convective core of stars in the mass range 3-30 M ⊙ in a parametric way, which indeed lead to BSGs. It is expected that these BSGs would still show large scale magnetic fields in the order of 10 G.

  17. Spectroscopic studies of yellow supergiants in the open cluster NGC 129

    NASA Astrophysics Data System (ADS)

    Usenko, I. A.

    2015-09-01

    Spectroscopic studies of three yellow supergiants in the open cluster NGC 129, the classical Cepheid DL Cas, SAO 21450, and SAO 21482, have been performed on the basis of high-resolution spectra. For the two nonvariable cluster supergiants, the atmospheric parameters and chemical composition have been determined for the first time. SAO 21450 ( T eff = 6541 ± 16 K, log g = 2.00, V t = 4.20 km s-1) has nearly solar abundances of the key elements in the evolution of yellow supergiants (CNO, Na, Mg, and Al), while SAO 21482 ( T eff = 4506 ± 50 K, log g = 1.10, V t = 9.90 km s-1) exhibits an overabundance of carbon ([C/H] = +0.34 dex) and aluminum and nearly solar N, O, Na, and Mg abundances. The abundances of the key elements in the Cepheid DL Cas are typical for an object that has passed the first dredge-up: a C underabundance, N and Na overabundances, and nearly solar O, Mg, and Al abundances. In all objects, the abundances of iron [Fe/H] = -0.01 dex, α-elements, Fe-peak elements, and r- and s-process elements are virtually identical and nearly solar. The radial velocities of SAO 21482 measured from metal absorption lines have confirmed its membership in NGC 129. The knifelike shape of the H α and H β line profiles in SAO 21482 and the asymmetry of the Mg Ib 5183.618 Å line in SAO 21482 and DL Cas as well as the absorption lines of neutral atoms and ions of metals in the Cepheid suggest the existence of extended gaseous envelopes around them. The positions of the objects on the T eff- L diagram among the tracks of evolutionary masses for the objects show the following: (1) the primary component of SAO 21450 has a mass of 6.6 M ⊙ and approaches the blue edge of the Cepheid instability strip (CIS) for the first time, while its companion of possible spectral type B5 V has a mass of 4.8 M ⊙; (2) DL Cas is on the path of its CIS with a mass of 5.8 M ⊙ and has lost ~1.5 M ⊙ after the first dredge-up; (3) SAO 21482 with a mass of no more than 7.3 M ⊙ has passed the red edge of the CIS and probably enters the asymptotic giant branch. The theoretical CNO abundance estimates based on evolutionary tracks approximately coincide with the observed ones, while the age estimates for the supergiants are close to the mean cluster age, (7.6 ± 0.4) × 107 yr.

  18. Clump Accretion in Supergiant Fast X-Ray Transients

    NASA Astrophysics Data System (ADS)

    Chase, Eve; Raymer, E.; Blondin, J. M.

    2014-01-01

    Supergiant Fast X-Ray Transients (SFXTs) are a subclass of High-Mass X-Ray Binaries that consist of a neutron star and OB supergiant donor star. These systems display short, bright x-ray flares lasting a few minutes to a few hours with luminosities reaching 1036 erg/s, several orders of magnitude larger than the quiescent luminosities of 1032 erg/s. The clumpy wind hypothesis has been proposed as a possible mechanism for these transient flares; in this model, a portion of the stellar wind from the donor star forms into clumps and is accreted onto the neutron star, inducing flares. We use high-resolution 3D hydrodynamic simulations to test the clumpy wind hypothesis, tracking the mass and angular momentum accretion rates to infer properties of the resulting x-ray flare and secular evolution of the neutron star rotation. Our results are significantly different from the predictions of Hoyle-Lyttleton Accretion (HLA) theory, which assume steady, laminar, axisymmetric flow. For example, an off-axis clump initiated with an impact parameter greater than the clump radius (for which HLA predicts no effect) produces a small spike in mass accretion and induces a long period of disk-like flow that dramatically reduces the accretion rate below the steady HLA value. The result is a brief, weak flare with a net decrease in total accreted mass compared with steady wind accretion accompanied by a substantial accretion of angular momentum.

  19. Blue supergiants as descendants of magnetic main sequence stars

    NASA Astrophysics Data System (ADS)

    Petermann, I.; Langer, N.; Castro, N.; Fossati, L.

    2015-12-01

    About 10% of the massive main sequence stars have recently been found to host a strong, large scale magnetic field. Both, the origin and the evolutionary consequences of these fields are largely unknown. We argue that these fields may be sufficiently strong in the deep interior of the stars to suppress convection near the outer edge of their convective core. We performed parametrised stellar evolution calculations and assumed a reduced size of the convective core for stars in the mass range 16M⊙ to 28M⊙ from the zero age main sequence until core carbon depletion. We find that such models avoid the coolest part of the main sequence band, which is usually filled by evolutionary models that include convective core overshooting. Furthermore, our "magnetic" models populate the blue supergiant region during core helium burning, i.e., the post-main sequence gap left by ordinary single star models, and some of them end their life in a position near that of the progenitor of Supernova 1987A in the Hertzsprung-Russell diagram. Further effects include a strongly reduced luminosity during the red supergiant stage, and downward shift of the limiting initial mass for white dwarf and neutron star formation.

  20. On the atmospheric structure and fundamental parameters of red supergiants

    NASA Astrophysics Data System (ADS)

    Wittkowski, M.; Arroyo-Torres, B.; Marcaide, J. M.; Abellan, F. J.; Chiavassa, A.; Freytag, B.; Scholz, M.; Wood, P. R.; Hauschildt, P. H.

    2015-01-01

    We present near-infrared spectro-interferometric studies of red supergiant (RSG) stars using the VLTI/AMBER instrument, which are compared to previously obtained similar observations of AGB stars. Our observations indicate spatially extended atmospheric molecular layers of water vapor and CO, similar as previously observed for Mira stars. Data of VY~CMa indicate that the molecular layers are asymmetric, possibly clumpy. Thanks to the spectro-interferometric capabilities of the VLTI/AMBER instrument, we can isolate continuum bandpasses, estimate fundamental parameters of our sources, locate them in the HR diagram, and compare their positions to recent evolutionary tracks. For the example of VY CMa, this puts it close to evolutionary tracks of initial mass 25-32 M ⊙. Comparisons of our data to hydrostatic model atmospheres, 3d simulations of convection, and 1d dynamic model atmospheres based on self-excited pulsation models indicate that none of these models can presently explain the observed atmospheric extensions for RSGs. The mechanism that levitates the atmospheres of red supergiant is thus a currently unsolved problem.

  1. YELLOW AND RED SUPERGIANTS IN THE LARGE MAGELLANIC CLOUD

    SciTech Connect

    Neugent, Kathryn F.; Massey, Philip; Skiff, Brian; Meynet, Georges E-mail: phil.massey@lowell.edu E-mail: georges.meynet@unige.ch

    2012-04-20

    Due to their transitionary nature, yellow supergiants (YSGs) provide a critical challenge for evolutionary modeling. Previous studies within M31 and the Small Magellanic Cloud show that the Geneva evolutionary models do a poor job at predicting the lifetimes of these short-lived stars. Here, we extend this study to the Large Magellanic Cloud (LMC) while also investigating the galaxy's red supergiant (RSG) content. This task is complicated by contamination by Galactic foreground stars that color and magnitude criteria alone cannot weed out. Therefore, we use proper-motions and the LMC's large systemic radial velocity ({approx}278 km s{sup -1}) to separate out these foreground dwarfs. After observing nearly 2000 stars, we identified 317 probable YSGs, 6 possible YSGs, and 505 probable RSGs. Foreground contamination of our YSG sample was {approx}80%, while that of the RSG sample was only 3%. By placing the YSGs on the Hertzsprung-Russell diagram and comparing them against the evolutionary tracks, we find that new Geneva evolutionary models do an exemplary job at predicting both the locations and the lifetimes of these transitory objects.

  2. A new survey of cool supergiants in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Gonzlez-Fernndez, Carlos; Dorda, Ricardo; Negueruela, Ignacio; Marco, Amparo

    2015-06-01

    Aims: In this study we conduct a pilot program aimed at the red supergiant population of the Magellanic Clouds. We intend to extend the current known sample to the unexplored low end of the brightness distribution of these stars, building a more representative dataset with which to extrapolate their behaviour to other Galactic and extra-galactic environments. Methods: We select candidates using only near infrared photometry, and with medium resolution multi-object spectroscopy, we perform spectral classification and derive their line-of-sight velocities, confirming the nature of the candidates and their membership in the clouds. Results: Around two hundred new red supergiants have been detected, hinting at a yet to be observed large population. Using near- and mid-infrared photometry we study the brightness distribution of these stars, the onset of mass-loss, and the effect of dust in their atmospheres. Based on this sample, new a priori classification criteria are investigated, combining mid- and near-infrared photometry to improve the observational efficiency of similar programs to this. The catalogue of observed sources is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/578/A3

  3. Detection of a red supergiant progenitor star of a type II-plateau supernova.

    PubMed

    Smartt, Stephen J; Maund, Justyn R; Hendry, Margaret A; Tout, Christopher A; Gilmore, Gerard F; Mattila, Seppo; Benn, Chris R

    2004-01-23

    We present the discovery of a red supergiant star that exploded as supernova 2003gd in the nearby spiral galaxy M74. The Hubble Space Telescope (HST) and the Gemini Telescope imaged this galaxy 6 to 9 months before the supernova explosion, and subsequent HST images confirm the positional coincidence of the supernova with a single resolved star that is a red supergiant of 8(+4)(-2) solar masses. This confirms both stellar evolution models and supernova theories predicting that cool red supergiants are the immediate progenitor stars of type II-plateau supernovae. PMID:14739452

  4. NGC 7419 as a template for red supergiant clusters

    NASA Astrophysics Data System (ADS)

    Marco, A.; Negueruela, I.

    2013-04-01

    Context. The open cluster NGC 7419 is known to contain five red supergiants and a very high number of Be stars. However, there are conflicting reports about its age and distance that prevent a useful comparison with other clusters. Aims: We intend to obtain more accurate parameters for NGC 7419, using techniques different from those of previous authors, so that it may be used as a calibrator for more obscured clusters. Methods: We obtained Strmgren photometry of the open cluster NGC 7419, as well as classification spectroscopy of ~20 stars in the area. We then applied standard analysis and classification techniques. Results: We find a distance of 4 0.4 kpc and an age of 14 2 Myr for NGC 7419. The main-sequence turn-off is found at spectral type B1, in excellent agreement. We identify 179 B-type members, implying that there are more than 1200 M? in B stars at present. Extrapolating this to lower masses indicates an initial cluster mass of between 7000 and 10 000 M?, depending on the shape of the initial mass function. We find a very high fraction (?40%) of Be stars around the turn-off, but very few Be stars at lower masses. We also report for the first time a strong variability in the emission characteristics of Be stars. We verified that the parameters of the red supergiant members can be used to obtain accurate cluster parameters. Conclusions: NGC 7419 is sufficiently massive to serve as a testbed for theoretical predictions and as a template to compare more obscured clusters. The distribution of stars above the main-sequence turn-off is difficult to accommodate with current evolutionary tracks. Though the presence of five red supergiants is marginally consistent with theoretical expectations, the high number of Be stars and very low number of luminous evolved B stars hint at some unknown physical factor that is not considered in current synthesis models. Partially based on observations collected at the Nordic Optical Telescope and the William Herschel Telescope (La Palma) and at the 1.93-m telescope at Observatoire de Haute Provence (CNRS), France.Tables 1 and 2 are available in electronic form at http://www.aanda.orgTables 3, 4 and 7 are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/552/A92

  5. Identification of Red Supergiants in the Magellanic Clouds.

    NASA Astrophysics Data System (ADS)

    Barandi, Brian Allan; Massey, Philip; Levesque, Emily M.

    2015-01-01

    The number and characteristics of red supergiants (RSGs) in the low metallicity environment of the Large and Small Magellanic Clouds (LMC, SMC) provide tests of stellar evolutionary tracks for massive stars. One complication is identifying Magellanic members due to the contamination of foreground stars in the Milky Way. We used the colors and magnitudes from the 2MASS survey to identify RSG candidates in the LMC and SMC, and used the Anglo Australian Telescope coupled with the AAOmega spectrograph to take spectra of 325 LMC and 423 SMC RSG candidates. Using the Ca II triplet, we measured the radial velocity of each candidate by cross correlation and assigned membership. Methods along with physical properties of each star will be presented. We gratefully acknowledge support by the National Science Foundation through the REU program at Lowell Observatory and Northern Arizona University (AST-1004107) and through PM's grant AST-1008020.

  6. Observing Supergiant Fast X-ray Transients in quiescence

    NASA Astrophysics Data System (ADS)

    Bozzo, Enrico

    2007-10-01

    Supergiant Fast X-ray Transients (SFXTs) are a new class of highly variable hard X-ray sources in our galaxy. We propose to perform the first detailed study of the quiescent state of two SFTXs by carrying out XMM observations of IGR J16479-4514 and XTE J1739-302 sources. We will search for pulsations, low-level flaring activity and column density variations, and measure the X-ray spectrum. We will address some key predictions of a recently proposed scenario in which accretion onto the neutron stars of SFXTs is gated by an extremely strong (magnetar-like) magnetic field. SFXTs might thus offer the first opportunity to detect magnetars hosted in binary star systems.

  7. Spectroscopic Analysis of the Supergiant Star HD 54605

    NASA Astrophysics Data System (ADS)

    Peña, L.; Rosenzweig, P.; Guzmán, E.; Hearnshaw, J.

    2009-05-01

    The main purpose of the present study is to analyze a high resolution spectrum of the supergiant star HD 54605, obtained in the year 2003, with a CCD coupled with the spectrograph HERCULES, attached to the 1m reflector telescope of Mt. John Observatory of the University of Canterbury (New Zealand). This spectrum covers the region λλ ≈ 4505-7080Å, with R = 41000 and a dispersion of ≈ 2Å/mm. According to previous spectroscopic observations, of low dispersion, the radial velocity of this star showed that it does not vary in periods of time relatively short. Until the present, we have identified five hundred photospheric lines, from which, with no doubt, we will obtain a satisfactory result that will give an important contribution to the database of the values of the radial velocity of HD 54605. We observe that Hβ, shows a relatively wide and deep profile and is in complete absorption.

  8. Variability and mass loss in IA O-B-A supergiants

    NASA Technical Reports Server (NTRS)

    Schild, R. E.; Garrison, R. F.; Hiltner, W. A.

    1983-01-01

    Recently completed catalogs of MK spectral types and UBV photometry of 1227 OB stars in the southern Milky Way have been analyzed to investigate brightness and color variability among the Ia supergiants. It is found that brightness variability is common among the O9-B1 supergiants with typical amplitudes about 0.1 and time scales longer than a week and shorter than 1000 days. Among the A supergiants fluctuations in U-B color are found on similar time scales and with amplitude about 0.1. For many early Ia supergiants there is a poor correlation between Balmer jump and spectral type, as had been known previously. An attempt to correlate the Balmer jump deficiency with mass loss rate yielded uncertain results.

  9. The energy distributions of B supergiants in the Large Magellanic Cloud

    NASA Technical Reports Server (NTRS)

    Fitzpatrick, Edward L.

    1986-01-01

    It is shown that line-blanketed, LTE, plane-parallel model atmosphere calculations provide excellent fits to the ultraviolet-through-visual energy distributions of B supergiants in the Large Magellanic Cloud. The models were computed using Kurucz's (1979) ATLAS atmosphere program, but with lower gravities than were contained in Kurucz's published model grid. The ultraviolet continua of low gravity stars are found to be sensitive to changes in temperature and gravity. Measurements of Teff and log g for ten LMC B supergiants from model atmosphere fits to the energy distributions yield estimates of their radii, luminosities, and masses. Model atmosphere fits suggest that the late B supergiants have significantly lower masses than the earlier B types of the same luminosity, contrary to stellar evolution theory which predicts that B supergiants are in a post-core hydrogen burning phase and should evolve very quickly and at essentially constant mass.

  10. Time Series Analysis of the A0 Supergiant HR 1040

    NASA Astrophysics Data System (ADS)

    Corliss, David J.

    A time series analysis of spectroscopic and photometric observables of the A0Ia supergiant HR 1040 has been performed. The data, obtained from 1993 through 2007, include 152 spectroscopic observations from the Ritter Observatory and 269 Stromgren photometric observations from the Four College Automated Photoelectric Telescope (FCAPT). A number of spectroscopic and photometric features have been analyzed and compared, including Wlambda, radial velocities and Stromgren photometric indices. Typical of late B- and early A-type supergiants, HR 1040 has a highly variable stellar wind including High Velocity Absorption (HVA) events. The star was found to have an active phase with large variation in the physical characteristics of the wind and with the potential for HVAs. During the active phase, correlation between the H-alpha absorption equivalent width and blue-edge radial velocity was observed. If an HVA was present, the active phase was found to begin before the onset of the HVA and continue after the end of the event by as much as several weeks. This active phase alternated with a more common quiescent phase marked by little variability and equivalent width - radial velocity correlation and no HVAs. The active phase and HVAs were found to exhibit important connections to photospheric activity. Increases in H-alpha absorption and blue-edge radial velocity at the onset of HVAs was preceded by correlated increases in Si II Wlambda and second moment, with the atmospheric changes indicated by the H-alpha line lagging the photospheric changes seen in Si II by an interval of 13 to 23 days. The observed HVAs were found to be preceded by Si II radial velocity oscillations by an interval of 19 to 42 days. The equivalent width and second moment of the photospheric Si II lambdalambda6347, 6371 lines were found to be highly variable and strongly correlated throughout the two active phases when an HVA is observed but not during the quiescent phase or in the one active phase where no HVA was seen. The Si II Wlambda and second moment showed a short-lived increase during the first few weeks of an HVA and then quickly dropped back to quiescent phase levels. Time series cluster analysis of the two HVAs observed on HR 1040, in addition to three HVAs in alpha Orionis, identified four distinct stages in the development of these events. Possible factors contributing to HVA are discussed, including gas ejection and microturbulence at the photosphere, as well as co-rotation interaction regions (CIR) in the wind. HR 1040 exhibits a broad emission feature near Halpha commonly found in late B- and early A-type supergiants. The broad emission in HR 1040 was found to be variable and not correlated to photospheric or wind observables associated with the active phase. Some indication was found that this feature is limited to a wavelength range of 6532 A to 6597 A. While the wavelength range extends roughly the same amount to either side of H-alpha line center, an asymmetry in the flux of the broad emission is observed, with a local maximum in the flux varying between 6555 A to 6564 A. If this asymmetry is real and not an instrumental effect, it argues against a photospheric origin for this broad emission feature as it would require radial velocities up to -300 km/s, well in excess of the terminal wind speed.

  11. HD 50975: a yellow supergiant in a spectroscopic binary system

    NASA Astrophysics Data System (ADS)

    Sperauskas, J.; Za?s, L.; Raudeli?nas, S.; Musaev, F.; Puzin, V.

    2014-10-01

    Context. Recent detection of a yellow supergiant star as a possible progenitor of a supernova has posed serious questions about our understanding of the evolution of massive stars. Aims: The spectroscopic binary star HD 50975 with an unseen hot secondary was studied in detail with the main goal of estimating fundamental parameters of both components and the binary system. Methods: A comprehensive analysis and modeling of collected long-term radial velocity measurements, photometric data, and spectra was performed to calculate orbital elements, atmospheric parameters, abundances, and luminosities. The spectrum in an ultraviolet region was studied to clarify the nature of an unseen companion star. Results: The orbital period was found to be 190.22 0.01 days. The primary star (hereafter HD 50975A) is a yellow supergiant with an effective temperature Teff = 5900 150 K and a surface gravity of log (g) = 1.4 0.3 (cgs). The atmosphere of HD 50975 A is slightly metal deficient relative to solar, [Fe/H] = -0.26 0.06 dex. Abundances of Si and Ca are close to the scaled solar composition. The r-process element europium is enhanced, [Eu/H] = + 0.61 0.07. The bolometric magnitude of the primary was estimated to be Mbol = -5.5 0.3 mag and its mass to be 10.7 2.0 M?. The secondary (hereafter HD 50975B) is a hot star of spectral type ~B2 near ZAMS with an effective temperature of Teff ? 21 000 K and a mass M ? 8.6 M?. The distance between HD 50975A and B is about 370 R?. The binary star is near a semi-detached configuration with a radius, RA ? 107 R?, and a radius of Roche lobe of about 120 R? for the primary star. The reduced spectra are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/570/A3

  12. Recognition of Distant Supergiants among Faint Red Stars in the Galactic Plane

    NASA Astrophysics Data System (ADS)

    MacConnell, Darrell J.; Wing, R. F.; Costa, E.

    2011-05-01

    Surveys along the Galactic plane at red and infrared wavelengths -- e.g. several objective-prism surveys in the photographic infrared, and the recent Spitzer/GLIMPSE survey in the 3-8? region -- record large numbers of faint red stars. Some of these sources must be distant, heavily-reddened supergiants in remote spiral arms, and they would be valuable tracers if their distances could be estimated. Measurement of a TiO band and a color index -- show that the majority of the detected faint, red sources are stars of type M, reddened to different degrees. It is more difficult to distinguish bona fide supergiants from the more common giants (which are also likely to be reddened, but are not confined to spiral arms), and to obtain the luminosity classes needed for the determination of individual distances. We have developed two methods, one using slit spectroscopy and the other narrow-band photometry, for determining the luminosities of reddened M stars. Both methods depend primarily on the measurement of CN absorption in the 0.8? region, often in the face of much stronger TiO bands. The spectroscopic method involves flattening the digital spectra and comparing program stars to standards of the same TiO strength to judge the amount of CN present. The narrow-band method involves fitting a blackbody curve to the calibrated photometry and defining a reddening-free CN index. This CN absorption is measurable in all giants and supergiants of types K and M and is stronger in supergiants. In fact, young, massive supergiants of classes Ia and Iab, which should be excellent spiral-arm tracers, can be distinguished from supergiants of class Ib, which may be older. We illustrate our procedures and apply them to a sample of GLIMPSE sources. We show that our methods give consistent results and can be used to identify distant supergiants among GLIMPSE sources.

  13. Accretion in supergiant High Mass X-ray Binaries

    NASA Astrophysics Data System (ADS)

    Manousakis, A.; Blondin, J.; Walter, R.

    2013-09-01

    Supergiant High Mass X-ray Binary systems (sgHMXBs) consist of a massive, late type, star and a neutron star. The massive stars exhibit strong, radiatively driven, stellar winds. Wind accretion onto compact object triggers X-ray emission, which alters the stellar wind significantly. Hydrodynamic simulation has been used to study the neutron star - stellar wind interaction it two sgHMXBs: i) A heavily obscured sgHMXB (IGR J17252-3616) discovered by INTEGRAL. To account for observable quantities (i.e., absorbing column density) we have to assume a very slow wind terminal velocity of about 500 km/s and a rather massive neutron star. If confirmed in other obscured systems, this could provide a completely new stellar wind diagnostics. ii) A classical sgHMXB (Vela X-1) has been studied in depth to understand the origin of the off-states observed in this system. Among many models used to account for this observed behavior (clumpy wind, gating mechanism) we propose that self-organized criticality of the accretion stream is the likely reason for the observed behavior. In conclusion, the neutron star, in these two examples, acts very efficiently as a probe to study stellar winds.

  14. Accretion in supergiant High Mass X-ray Binaries

    NASA Astrophysics Data System (ADS)

    Manousakis, Antonios; Walter, Roland; Blondin, John

    2014-01-01

    Supergiant High Mass X-ray Binary systems (sgHMXBs) consist of a massive, late type, star and a neutron star. The massive stars exhibits strong, radiatively driven, stellar winds. Wind accretion onto compact object triggers X-ray emission, which alters the stellar wind significantly. Hydrodynamic simulation has been used to study the neutron star - stellar wind interaction it two sgHMXBs: i) A heavily obscured sgHMXB (IGR J17252-3616) discovered by INTEGRAL. To account for observable quantities (i.e., absorbing column density) we have to assume a very slow wind terminal velocity of about 500 km/s and a rather massive neutron star. If confirmed in other obscured systems, this could provide a completely new stellar wind diagnostics. ii) A classical sgHMXB (Vela X-1) has been studied in depth to understand the origin of the off-states observed in this system. Among many models used to account for this observed behavior (clumpy wind, gating mechanism) we propose that self-organized criticality of the accretion stream is the likely reason for the observed behavior. In conclusion, the neutron star, in these two examples, acts very effciently as a probe to study stellar winds.

  15. Stellar winds in supergiant High Mass X-ray Binaries

    NASA Astrophysics Data System (ADS)

    Manousakis, Antonios; Walter, Roland

    2013-06-01

    Supergiant High Mass X-ray Binary systems (sgHMXBs) consist of a massive, late type, star and a neutron star. The massive stars exhibit strong, radiatively driven, stellar winds. Wind accretion onto compact object triggers X-ray emission, which alters the stellar wind significantly. Hydrodynamic simulation has been used to study the neutron star - stellar wind interaction it two sgHMXBs: i) A heavily obscured sgHMXB (IGR J17252-3616) discovered by INTEGRAL. To account for observable quantities (i.e., absorbing column density) we have to assume a very slow wind terminal velocity of about 500 km/s and a rather massive neutron star. If confirmed in other obscured systems, this could provide a completely new stellar wind diagnostics. ii) A classical sgHMXB (Vela X-1) has been studied in depth to understand the origin of the off-states observed in this system. Among many models used to account for this observed behavior (clumpy wind, gating mechanism) we propose that self-organized criticality of the accretion stream is the likely reason for the observed behavior.

  16. THE TYPE IIb SUPERNOVA 2011dh FROM A SUPERGIANT PROGENITOR

    SciTech Connect

    Bersten, Melina C.; Nomoto, Ken'ichi; Folatelli, Gaston; Maeda, Keiichi; Benvenuto, Omar G.; Benetti, Stefano; Ochner, Paolo; Tomasella, Lina; Botticella, Maria Teresa; Fraser, Morgan; Kotak, Rubina

    2012-09-20

    A set of hydrodynamical models based on stellar evolutionary progenitors is used to study the nature of SN 2011dh. Our modeling suggests that a large progenitor star-with R {approx} 200 R{sub Sun }-is needed to reproduce the early light curve (LC) of SN 2011dh. This is consistent with the suggestion that the yellow super-giant star detected at the location of the supernova (SN) in deep pre-explosion images is the progenitor star. From the main peak of the bolometric LC and expansion velocities, we constrain the mass of the ejecta to be Almost-Equal-To 2 M{sub Sun }, the explosion energy to be E = (6-10) Multiplication-Sign 10{sup 50} erg, and the {sup 56}Ni mass to be approximately 0.06 M{sub Sun }. The progenitor star was composed of a helium core of 3-4 M{sub Sun} and a thin hydrogen-rich envelope of Almost-Equal-To 0.1M{sub Sun} with a main-sequence mass estimated to be in the range of 12-15 M{sub Sun }. Our models rule out progenitors with helium-core masses larger than 8 M{sub Sun }, which correspond to M{sub ZAMS} {approx}> 25M{sub Sun }. This suggests that a single star evolutionary scenario for SN 2011dh is unlikely.

  17. Supernovae from yellow, blue supergiants: origin and consequences for stellar evolution

    NASA Astrophysics Data System (ADS)

    Meynet, Georges; Georgy, Cyril; Saio, Hideyuki; Kudritzki, Rolf-Peter; Groh, Jose

    2015-08-01

    A few core collapse supernovae progenitors have been found to be yellow or blue supergiants. We shall discuss possible scenarios involving single and close binary evolution allowing to explain this kind of core collapse supernova progenitors. According to stellar models for both single and close binaries, blue supergiants, at the end of their nuclear lifetimes and thus progenitors of core collapse supernovae, present very different characteristics for what concerns their surface compositions, rotational surface velocities and pulsational properties with respect to blue supergiants in their core helium burning phase. We discuss how the small observed scatter of the flux-weighted gravity-luminosity (FWGL) relation of blue supergiants constrains the evolution of massive stars after the Main-Sequence phase and the nature of the progenitors of supernovae in the mass range between 12 and 40 solar masses. The present day observed surface abundances of blue supergiants, of their pulsational properties, as well as the small scatter of the FWGL relation provide strong constraints on both internal mixing and mass loss in massive stars and therefore on the end point of their evolution.

  18. CO thermal emissions and mass loss of red-supergiants beyond the Milky Way

    NASA Astrophysics Data System (ADS)

    Matsuura, Mikako; Sargent, Benjamin; Yates, J.; Swinyard, B.; Royer, P.; Boyer, M.; Barlow, M. J.; Meixner, Margaret; Katrien Els Decin, Leen; Khouri, T.; van Loon, J.; Woods, P.

    2015-08-01

    It is crucial for understanding stellar evolution to study how red-supergiants lose their mass. Although mass loss of red-supergiants has been well studied in the Milky Way, it is poorly studied beyond the Milky Way. Particularly, galaxies have wide range of metallicities, and the key question is how metallicity affects dust formation in red-supergiants, hence, how dust-driven mass-loss could be affected by the metallicity. Theory predicted that mass loss rate is lower at low metallicity. Testing this hypothesis, we observed CO thermal emission lines in red-supergiants in the Large Magellanic Cloud, using the Herschel Space Observatory. These are the first detections of rotational CO lines from red-supergiants beyond the Milky Way. Although the metallicity of the Large Magellanic Cloud is about the half of the solar metallicity, no obvious metallicity effect was found on the gas mass-loss rate. The key parameter for the mass-loss rate is the luminosity of the star.

  19. Revealing the Complex Dynamics of the Atmospheres of Red Supergiants with the Very Large Telescope Interferometer

    NASA Astrophysics Data System (ADS)

    Ohnaka, K.; Weigelt, G.; Hofmann, K.-H.; Schertl, D.

    2015-12-01

    Massive stars lose a significant fraction of their initial mass when they evolve to red supergiants before they end their life in supernova explosions. The mass loss greatly affects their final fate. However, the mass loss from these dying supergiants is not yet understood well. Here we present our efforts to spatially resolve the dynamics of the atmospheres of red supergiants with the Very Large Telescope Interferometer (VLTI) and the AMBER instrument to clarify the physical mechanism behind the mass loss. The VLTI/AMBER's combination of milliarcsecond spatial resolution and high spectral resolution allows us to spatially resolve stellar atmospheres and extract the dynamical information at each position over the star and the atmosphere just like observations of the Sun.

  20. Expected number of supergiant fast X-ray transients in the Milky Way

    NASA Astrophysics Data System (ADS)

    Ducci, L.; Doroshenko, V.; Romano, P.; Santangelo, A.; Sasaki, M.

    2014-08-01

    In the past fifteen years a new generation of X-ray satellites led to the discovery of a subclass of high-mass X-ray binaries (HMXBs) with supergiant companions and a peculiar transient behaviour: supergiant fast X-ray transients (SFXTs). We calculate the expected number of Galactic SFXTs for the first time, using two different statistical approaches and two sets of data based on Swift and INTEGRAL surveys, with the aim to determine how common the SFXT phenomenon really is. We find that the expected number of SFXTs in the Galaxy is 37+53-22, which shows that SFXTs constitute a large portion of X-ray binaries with supergiant companions in the Galaxy. We compare our estimate with the expected number of Galactic HMXBs predicted from observations and evolutionary models and discuss the implications for the nature of SFXTs.

  1. A spectroscopic survey of B supergiants in the Large Magellanic Cloud

    NASA Technical Reports Server (NTRS)

    Fitzpatrick, Edward L.

    1991-01-01

    The results of a low-dispersion digital optical spectral survey of about 100 B-type supergiants in the Large Magellanic Cloud are presented. The MK spectral classification framework for B supergiants has been transferred to the metal-weak LMC stars, and recommended classification standards have been designated. Variations among the metal line strengths are examined. The most extreme variations are found for the nitrogen lines, for which a range of a factor of 3 or more may be seen in the equivalent widths within some spectral subclasses. It is suggested that these variations indicate a range of nitrogen surface abundances among the B supergiants, resulting from contamination of some of the stellar surfaces by processed material from the original H-burning core.

  2. The nature of the ionised nebula surrounding the red supergiant W26

    NASA Astrophysics Data System (ADS)

    Wesson, Roger

    2015-08-01

    The red supergiant W26 in the massive star cluster Westerlund 1 is surrounded by a compact ionised nebula. This is unique among RSGs, and the excitation mechanism of the nebula is not yet known - it may be ionised by an unseen compact companion, or by a nearby blue supergiant. We present new observations of the nebula: high resolution spatially resolved spectra taken with FLAMES at the VLT show that the nebula is a ring, with velocities consistent with that expected for red supergiant ejecta, and ruling out the possibility of a Luminous Blue Variable-type eruption preceding the RSG phase as the origin of the nebula. A triangular patch of nebulosity outside the ring appears to be associated with W26, and may be material stripped from the expanding ring by the cumulative cluster wind and radiation field.

  3. Accurate luminosities for F-G supergiants from FeII/FeI line depth ratios

    NASA Astrophysics Data System (ADS)

    Kovtyukh, V. V.; Chekhonadskikh, F. A.; Luck, R. E.; Soubiran, C.; Yasinskaya, M. P.; Belik, S. I.

    2010-11-01

    Luminous FG supergiants can be used as extragalactic distance indicators. In order to fully exploit the properties of these bright stars, we must first learn how to measure their luminosities. Based primarily on classical Cepheids and supergiants in clusters and OB associations, we have derived 80 empirical relations connecting the line depth ratios of FeII/FeI lines with the absolute magnitudes Mv and the effective temperatures Teff. These relations have been applied to estimate the absolute magnitudes of 98 FG supergiants with an error of +/-0.26mag. The application range of our calibrations is spectral types F2-G8 and luminosity classes I and II (absolute magnitudes Mv, -0.5 to -8 mag). A comparison of our Mv determinations with values from the literature shows good agreement.

  4. Seven years with the Swift Supergiant Fast X-ray Transients project

    NASA Astrophysics Data System (ADS)

    Romano, P.

    2015-09-01

    Supergiant Fast X-ray Transients (SFXTs) are HMXBs with OB supergiant companions. I review the results of the Swift SFXT project, which since 2007 has been exploiting Swift's capabilities in a systematic study of SFXTs and supergiant X-ray binaries (SGXBs) by combining follow-ups of outbursts, when detailed broad-band spectroscopy is possible, with long-term monitoring campaigns, when the out-of-outburst fainter states can be observed. This strategy has led us to measure their duty cycles as a function of luminosity, to extract their differential luminosity distributions in the soft X-ray domain, and to compare, with unprecedented detail, the X-ray variability in these different classes of sources. I also discuss the "seventh year crisis", the challenges that the recent Swift observations are making to the prevailing models attempting to explain the SFXT behavior.

  5. The missing piece of the puzzle: Neutron stars accreting from supergiant companions

    NASA Astrophysics Data System (ADS)

    Antoniou, Vallia; Zezas, Andreas; Maravelias, Grigoris; Kalogera, Vicky

    2012-09-01

    The supergiant X-ray binaries (SG-XRBs) is a class of High-Mass X-ray Binaries that consists of supergiant fast X-ray transients (SFXTs) and "classical" SG-XRBs exhibiting a strong intrinsic absorption. Nowadays, we know only 3 Galactic "classical" SG-XRBs (with the remaining known wind-fed systems being SFXTs)! Recently, our team discovered the first extragalactic member of this well-hidden population of "classical" SG-XRBs that motivated us to look for additional neutron-star X-ray binaries accreting from supergiant stars. In this talk, I will present the latest results of this reseach based on multi-wavelength observations of the Magellanic Clouds. These first observational constraints of the formation and evolution of "classical" SG-XRBs will help in the planning and interpretation of future multi-wavelength observations of these obscured high-mass X-ray binaries in nearby star-forming galaxies.

  6. Extinction and Scattering Properties of Dust Around Red Supergiants

    NASA Astrophysics Data System (ADS)

    Bright, Stacey; Clayton, G.; Massey, P.; Gordon, K.; Levesque, E.; Plez, B.

    2007-12-01

    We have been amassing a unique dataset which can be used to investigate the amount and nature of dust produced by red supergiants (RSGs) in very different environments. To this end, optical spectra are being obtained for RSGs in various galaxies in the Local Group. Moderate-resolution, high S/N, spectrophotometry, covering 3500-9000A, has been obtained for a sample of RSGs in the Milky Way and the Magellanic Clouds. Using the the MARCS stellar atmosphere models to fit the SEDs, we are deriving extinction curves from 3500A to the K-band for the Local Group RSGs. In particular, for the LMC and SMC stars, the problem is more tractable than for the Milky Way RSGs, given the small and relatively uniform foreground extinction of the Clouds. We will construct extinction curves using the classic "pair method". The feasibility of using the model SEDs as "unreddened" standards will be examined, as well as the more conventional pairing of stars that are closely matched in spectral type but have different reddenings. These extinction curves are actually attenuation curves since the RSG circumstellar dust shells are not resolved and light can be scattered back into the beam. In particular, we plan to examine the apparent NUV excess seen in the Galactic RSG extinction curves. The NUV excess is possibly due to scattering of the star's light by circumstellar dust and/or a larger average size than that typical of grains found in the diffuse interstellar medium. This project is being supported by NSF grant AST-0707691 and a LaSPACE Undergraduate Research Assistantship (NASA grant NNG05GH22H).

  7. Geology of supergiant Cano Limon field and Llanos basin, Colombia

    SciTech Connect

    McCollough, C.N.; Padfield, E.P.

    1986-07-01

    After 40 years of sporadic exploration that yielded negative or marginal results, the Llanos basin of eastern Colombia was thrust to the forefront of world attention by the discovery of the supergiant Cano Limon field in July 1983. This discovery culminated an intensive 3-year exploration effort by Occidental involving 4000 km of dynamite seismic, 20 stratigraphic tests from 1300 to 3500 ft deep, and 13 exploratory wells. Cost prior to discovery was $45 million. The Llanos is an oily basin with abundant excellent reservoir sands. The problem has been to define traps. The basin deep lies along the foot of the eastern Cordillera, from which a sediment thickness of 30,000 ft thins gradually to the east on a homoclinal flank terminating at the Guyana shield. Except for the very young folding along the Andean front, structural traps are generally sparse. An exception is the Cano Limon area, which is dominated by major early Tertiary northeast-southwest strike-slip faulting. Concurrent folding and fault sealing formed Cano Limon and other smaller fields. The Cano Limon field with its other half, the Guafita field in Venezuela, contains an estimated initial potential of 3160 million bbl of oil, of which about 1460 million bbl is expected to be recovered. The bulk of the oil is in deltaic sands of the Eocene Mirador with additional reservoirs in the Upper Cretaceous. Average porosity of the Mirador is 24%, permeability is 4 darcies, and water saturation is 24%. The average initial flow rate of the first 15 wells is 10,000 BOPD. Exploration opportunities exist in a deep unexplored Paleozoic rift, in stratigraphic traps of Cretaceous and Tertiary age, and in fault-related traps along the basin flanks.

  8. On the Explosion Geometry of Red Supergiant Stars

    NASA Astrophysics Data System (ADS)

    Leonard, Douglas Christopher; Dessart, Luc; Pignata, Giuliano; Hillier, D. John; Williams, George Grant; Smith, Paul S.; Khandrika, Harish; Bilinski, Christopher; Duong, Nhieu; Flatland, Kelsi; Gonzalez, Luis; Hoffman, Jennifer L.; Horst, Chuck; Huk, Leah; Milne, Peter; Rachubo, Alisa A.; Smith, Nathan

    2015-08-01

    From progenitor studies, type II-Plateau supernovae (SNe II-P) have been decisively and uniquely determined to arise from isolated red supergiant (RSG) stars with initial masses ranging from 8 to 16 solar masses (Smartt 2009), establishing the most homogeneous -- and well understood -- progenitor class of any type of core-collapse supernova. However, we must admit a fundamental truth: We do not know how these stars explode. A basic discriminant among proposed explosion models is explosion geometry, since some models predict severe distortions from spherical symmetry. A primary method to gain such geometric information is through spectropolarimetry of the expanding (but, unresolved) atmosphere, with higher degrees of linear polarization generally demanding larger departures from spherical symmetry. Initially, as a class, SNe II-P were found to be only weakly polarized at the early epochs observed, suggesting a nearly spherical explosion for RSG stars. However, late-time observations of SN 2004dj captured a dramatic spike in polarization at just the moment the "inner core" of the ejecta was first revealed in this SN II-P (i.e., at the "drop" off of the photometric plateau; Leonard et al. 2006). This raised the possibility that the explosion of RSGs might be driven by a strongly non-spherical mechanism, with the evidence for the asphericity cloaked at early times by the massive, opaque, quasi-spherical hydrogen envelope. In this presentation we shall describe the continuing work on the explosion geometry of RSGs being carried out by the SuperNova SpectroPOLarimetry project (SNSPOL), with a particular focus on SN 2013ej -- an SN II-P that exhibited remarkably high polarization just days after the explosion (Leonard et al. 2013), and for which twelve epochs of spectropolarimetry trace an intriguing tale about its geometry deep into the nebular phase. We acknowledge support from NSF grants AST-1009571 and AST-1210311, under which part of this research was carried out.

  9. Bright flares in supergiant fast X-ray transients

    NASA Astrophysics Data System (ADS)

    Shakura, N.; Postnov, K.; Sidoli, L.; Paizis, A.

    2014-08-01

    At steady low-luminosity states, supergiant fast X-ray transients (SFXTs) can be at the stage of quasi-spherical settling accretion on to slowly rotating magnetized neutron stars from the OB-companion winds. At this stage, a hot quasi-static shell is formed above the magnetosphere, the plasma entry rate into magnetosphere is controlled by (inefficient) radiative plasma cooling, and the accretion rate on to the neutron star is suppressed by a factor of ˜30 relative to the Bondi-Hoyle-Littleton value. Changes in the local wind velocity and density due to, e.g. clumps, can only slightly increase the mass accretion rate (a factor of ˜10) bringing the system into the Compton-cooling-dominated regime and led to the production of moderately bright flares (Lx ≲ 1036 erg s-1). To interpret the brightest flares (Lx > 1036 erg s-1) displayed by the SFXTs within the quasi-spherical settling accretion regimes, we propose that a larger increase in the mass accretion rate can be produced by sporadic capture of magnetized stellar wind plasma. At sufficiently low accretion rates, magnetic reconnection can enhance the magnetospheric plasma entry rate, resulting in copious production of X-ray photons, strong Compton cooling and ultimately in unstable accretion of the entire shell. A bright flare develops on the free-fall time-scale in the shell, and the typical energy released in an SFXT bright flare corresponds to the mass of the shell. This view is consistent with the energy released in SFXT bright flares (˜1038-1040 erg), their typical dynamic range (˜100) and with the observed dependence of these characteristics on the average unflaring X-ray luminosity of SFXTs. Thus, the flaring behaviour of SFXTs, as opposed to steady HMXBs, may be primarily related to their low X-ray luminosity allowing sporadic magnetic reconnection to occur during magnetized plasma entry into the magnetosphere.

  10. Red Supergiants in the Andromeda Galaxy (M31)

    NASA Astrophysics Data System (ADS)

    Massey, Philip; Silva, D. R.; Levesque, E. M.; Plez, B.; Clayton, G. C.

    2009-01-01

    Red supergiants (RSGs) are the He-burning descendants of moderately massive (10-40 Mo) stars. Although they are not the most massive or bolometrically luminous, they are the physically largest stars in the universe, and their high luminosities and red colors result in their dominating the integrated NIR light of low redshift starbursts. Their high visual luminosities (Mv=-6 to -9) put them within reach for detailed studies within the Local Group and beyond. For years the location of these stars in the HRD has been at variance with stellar evolutionary theory, with the "observed" locations more luminous and cooler than theory allow. Our group has recently revised the effective temperature scale of RSGs in the Milky Way and Magellanic Clouds using the new generation of MARCS stellar atmospheres (Levesque et al. 2005, 2006), resulting in excellent agreement in the Milky Way and LMC, and moderately good agreement in the SMC. Here we extend this work to RSGs in the Andromeda Galaxy, M31. The metallicity of M31 is 2x solar, allowing us to now compare the physical properties of RSGS to that of evolution models at high metallicity. The sample was photometrically selected from the recent Local Group Galaxy Survey (Massey et al 2006, 2007), with membership confirmed by radial velocities obtained at WIYN. Optical spectrophotometry was obtained of a small subsample (17) of these objects using the mighty MMT 6.5-m. We also obtained contemporaneous V-K photometry using the Lowell Perkins 1.8-m telescope and the Mayall 4-m. The resulting distribution of stars in the HRD is shown, along with a comparison of their physical properties with lower metallicity RSGs. This work was supported by the NSF through AST-0604569.

  11. Supergiant X-Ray Binaries Observed by Suzaku

    NASA Technical Reports Server (NTRS)

    Bodaghee, A.; Tomsick, J. A.; Rodriquez, J.; Chaty, S.; Pottschmidt, K.; Walter, R.; Romano, P.

    2011-01-01

    Suzaku observations are presented for the high-mass X-ray binaries IGR 116207-5129 and IGR 117391-3021. For IGR 116207-5129, we provide the first X-ray broadband (0.5-60 keV) spectrum from which we confirm a large intrinsic column density (N(sub H) = 1.6 x 10(exp 23)/sq cm), and we constrain the cutoff energy for the first time (E(sub cut) = 19 keV). A prolonged (> 30 ks) attenuation of the X-ray flux was observed which we tentatively attribute to an eclipse of the probable neutron star by its massive companion, in a binary system with an orbital period between 4 and 9 days, and inclination angles> 50 degrees. For IGRJ17391-3021, we witnessed a transition from quiescence to a low-activity phase punctuated by weak flares whose peak luminosities in the 0.5-10keV band are only a factor of 5 times that of the pre-flare emission. These micro flares are accompanied by an increase in NH which suggests the accretion of obscuring clumps of wind. We now recognize that these low-activity epochs constitute the most common emission phase for this system, and perhaps in other supergiant fast X-ray transients (SFXTs) as well. We close with an overview of our upcoming program in which Suzaku will provide the first ever observation of an SFXT (IGRJ16479-4514) during a binary orbit enabling us to probe the accretion wind at every phase.

  12. On the Explosion Geometry of Red Supergiant Stars

    NASA Astrophysics Data System (ADS)

    Leonard, Douglas C.; Dessart, L.; Hillier, D.; Pignata, G.

    2012-01-01

    From progenitor studies, type II-Plateau supernovae (SNe II-P) have been decisively and uniquely determined to arise from isolated red supergiant stars, establishing the most homogeneous --- and well understood --- progenitor class of any type of core-collapse supernova. The precise nature of the mechanism responsible for the stellar explosion, however, remains the subject of considerable debate. A fundamental clue to the nature of the explosion mechanism is explosion geometry: In short, are supernovae round? Because young supernova atmospheres are electron-scattering dominated, their net linear polarization provides a direct probe of early-time supernova geometry, with higher degrees of polarization generally indicating greater departures from spherical symmetry. Here we present spectropolarimetry data for the most well-sampled SN II-P to date, SN 2008bk, and compare (and contrast) the results with those obtained for SN 2004dj, the only other SN II-P for which spectropolarimetry data were obtained with similar fine temporal sampling before, during, and after the fall off of the photometric plateau (Leonard et al. 2006). Both objects are polarized, indicating departures from spherical symmetry, although the timing of the onset -- as well as the persistence -- of the polarization differ between the two objects. Curiously, the detailed spectropolarimetric characteristics of the two objects at the epochs of recorded maximum polarization are extremely similar, feature by feature, suggesting a common cause --- or, at least, geometry. We interpret the data in light of non-Local-Thermodynamic Equilibrium, time-dependent radiative-transfer simulations specifically crafted for SN II-P ejecta. DCL acknowledges support from NSF grant AST-1009571, under which part of this research was carried out. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, under observing programs 081.D-0128, 082.D-0151, and 085.D-0391 (PI: Dessart).

  13. Accurate fundamental parameters for A-, F- and G-type Supergiants in the solar neighbourhood

    NASA Astrophysics Data System (ADS)

    Lyubimkov, Leonid S.; Lambert, David L.; Rostopchin, Sergey I.; Rachkovskaya, Tamara M.; Poklad, Dmitry B.

    2010-02-01

    The following parameters are determined for 63 Galactic supergiants in the solar neighbourhood: effective temperature Teff; surface gravity logg iron abundance log?(Fe) microturbulent parameter Vt; mass M/Msolar age t and distance d. A significant improvement in the accuracy of the determination of logg, and all parameters dependent on it, is obtained through application of van Leeuwen rereduction of the Hipparcos parallaxes. The typical error in the logg values is now +/-0.06dex for supergiants with distances d < 300 pc and +/-0.12dex for supergiants with d between 300 and 700 pc; the mean error in Teff for these stars is +/-120K. For supergiants with d > 700 pc, parallaxes are uncertain or unmeasurable, so typical errors in their logg values are 0.2-0.3dex. A new Teff scale for A5-G5 stars of luminosity classes Ib-II is presented. Spectral subtypes and luminosity classes of several stars are corrected. Combining the Teff and logg with evolutionary tracks, stellar masses and ages are determined; a majority of the sample has masses between 4 and 15Msolar and, hence, their progenitors were early to middle B-type main-sequence stars. Using FeII lines, which are insensitive to departures from local thermodynamic equilibrium, the microturbulent parameter Vt and the iron abundance log?(Fe) are determined from high-resolution spectra. The parameter Vt is correlated with gravity: Vt increases with decreasing logg. The mean iron abundance for the 48 supergiants with distances d < 700 pc is log?(Fe) = 7.48 +/- 0.09, a value close to the solar value of 7.45 +/- 0.05, and thus the local supergiants and the Sun have the same metallicity.

  14. DISCOVERY OF THE FIRST B[e] SUPERGIANTS IN M 31

    SciTech Connect

    Kraus, M.; Oksala, M. E.; Cidale, L. S.; Arias, M. L.; Borges Fernandes, M.

    2014-01-01

    B[e] supergiants (B[e]SGs) are transitional objects in the post-main sequence evolution of massive stars. The small number of B[e]SGs known so far in the Galaxy and the Magellanic Clouds indicates that this evolutionary phase is short. Nevertheless, the strong aspherical mass loss occurring during this phase, which leads to the formation of rings or disk-like structures, and the similarity to possible progenitors of SN1987 A emphasize the importance of B[e]SGs for the dynamics of the interstellar medium as well as stellar and galactic chemical evolution. The number of objects and their mass-loss behavior at different metallicities are essential ingredients for accurate predictions from stellar and galactic evolution calculations. However, B[e]SGs are not easily identified, as they share many characteristics with luminous blue variables (LBVs) in their quiescent (hot) phase. We present medium-resolution near-infrared K-band spectra for four stars in M 31, which have been assigned a hot LBV (candidate) status. Applying diagnostics that were recently developed to distinguish B[e]SGs from hot LBVs, we classify two of the objects as bonafide LBVs; one of them currently in outburst. In addition, we firmly classify the two stars 2MASS J00441709+4119273 and 2MASS J00452257+4150346 as the first B[e]SGs in M 31 based on strong CO band emission detected in their spectra, and infrared colors typical for this class of stars.

  15. Discovery of SiO Band Emission from Galactic B[e] Supergiants

    NASA Astrophysics Data System (ADS)

    Kraus, M.; Oksala, M. E.; Cidale, L. S.; Arias, M. L.; Torres, A. F.; Borges Fernandes, M.

    2015-02-01

    B[e] supergiants (B[e]SGs) are evolved massive stars in a short-lived transition phase. During this phase, these objects eject large amounts of material, which accumulate in a circumstellar disk-like structure. The expelled material is typically dense and cool, providing the cradle for molecule and dust condensation and for a rich, ongoing chemistry. Very little is known about the chemical composition of these disks, beyond the emission from dust and CO revolving around the star on Keplerian orbits. As massive stars preserve an oxygen-rich surface composition throughout their life, other oxygen-based molecules can be expected to form. As SiO is the second most stable oxygen compound, we initiated an observing campaign to search for first-overtone SiO emission bands. We obtained high-resolution near-infrared L-band spectra for a sample of Galactic B[e]SGs with reported CO band emission. We clearly detect emission from the SiO first-overtone bands in CPD-52 9243 and indications for faint emission in HD 62623, HD 327083, and CPD-57 2874. From model fits, we find that in all these stars the SiO bands are rotationally broadened with a velocity lower than observed in the CO band forming regions, suggesting that SiO forms at larger distances from the star. Hence, searching for and analyzing these bands is crucial for studying the structure and kinematics of circumstellar disks, because they trace complementary regions to the CO band formation zone. Moreover, since SiO molecules are the building blocks for silicate dust, their study might provide insight in the early stage of dust formation. Based on observations collected with the ESO VLT Paranal Observatory under program 093.D-0248(A).

  16. DISCOVERY OF SiO BAND EMISSION FROM GALACTIC B[e] SUPERGIANTS

    SciTech Connect

    Kraus, M.; Oksala, M. E.; Cidale, L. S.; Arias, M. L.; Torres, A. F.; Fernandes, M. Borges

    2015-02-20

    B[e] supergiants (B[e]SGs) are evolved massive stars in a short-lived transition phase. During this phase, these objects eject large amounts of material, which accumulate in a circumstellar disk-like structure. The expelled material is typically dense and cool, providing the cradle for molecule and dust condensation and for a rich, ongoing chemistry. Very little is known about the chemical composition of these disks, beyond the emission from dust and CO revolving around the star on Keplerian orbits. As massive stars preserve an oxygen-rich surface composition throughout their life, other oxygen-based molecules can be expected to form. As SiO is the second most stable oxygen compound, we initiated an observing campaign to search for first-overtone SiO emission bands. We obtained high-resolution near-infrared L-band spectra for a sample of Galactic B[e]SGs with reported CO band emission. We clearly detect emission from the SiO first-overtone bands in CPD-52 9243 and indications for faint emission in HD 62623, HD 327083, and CPD-57 2874. From model fits, we find that in all these stars the SiO bands are rotationally broadened with a velocity lower than observed in the CO band forming regions, suggesting that SiO forms at larger distances from the star. Hence, searching for and analyzing these bands is crucial for studying the structure and kinematics of circumstellar disks, because they trace complementary regions to the CO band formation zone. Moreover, since SiO molecules are the building blocks for silicate dust, their study might provide insight in the early stage of dust formation.

  17. The galatic and LMC extreme line supergiants compared: IUE observations of the Henize-Carlson and Zoo star samples of massive supergiants. [Large Magellanic cloud (LMC)

    NASA Technical Reports Server (NTRS)

    Shore, S. N.; Sanduleak, N.; Brown, D. N.; Sonneborn, G.; Bopp, B. W.; Robinson, C. R.

    1988-01-01

    The Henize-Carlson sample of galactic massive supergiants, and a comparison between the Galactic and LMC samples are discussed. Several of the stars, notably He3-395 and S 127/LMC, have very similar shell characteristics. There appears to be little difference, other than luminosity, between the LMC and Galactic samples. One star, He3-1482, was detected with the Very Large Array at 6 cm. The UV data is combined with IRAS and optical information.

  18. RAPIDLY ACCRETING SUPERGIANT PROTOSTARS: EMBRYOS OF SUPERMASSIVE BLACK HOLES?

    SciTech Connect

    Hosokawa, Takashi; Yorke, Harold W.; Omukai, Kazuyuki E-mail: hosokwtk@gmail.com

    2012-09-01

    Direct collapse of supermassive stars (SMSs) is a possible pathway for generating supermassive black holes in the early universe. It is expected that an SMS could form via very rapid mass accretion with M-dot{sub *} {approx} 0.1-1 M{sub Sun} yr{sup -1} during the gravitational collapse of an atomic-cooling primordial gas cloud. In this paper, we study how stars would evolve under such extreme rapid mass accretion, focusing on the early evolution until the stellar mass reaches 10{sup 3} M{sub Sun }. To this end, we numerically calculate the detailed interior structure of accreting stars with primordial element abundances. Our results show that for accretion rates higher than 10{sup -2} M{sub Sun} yr{sup -1}, stellar evolution is qualitatively different from that expected at lower rates. While accreting at these high rates, the star always has a radius exceeding 100 R{sub Sun }, which increases monotonically with the stellar mass. The mass-radius relation for stellar masses exceeding {approx}100 M{sub Sun} follows the same track with R{sub *}{proportional_to}M {sup 1/2}{sub *} in all cases with accretion rates {approx}> 10{sup -2} M{sub Sun} yr{sup -1}; at a stellar mass of 10{sup 3} M{sub Sun }, the radius is {approx_equal} 7000 R{sub Sun} ({approx_equal} 30 AU). With higher accretion rates, the onset of hydrogen burning is shifted toward higher stellar masses. In particular, for accretion rates exceeding M-dot{sub *}{approx}>0.1 M{sub Sun} yr{sup -1}, there is no significant hydrogen burning even after 10{sup 3} M{sub Sun} have accreted onto the protostar. Such 'supergiant' protostars have effective temperatures as low as T{sub eff} {approx_equal} 5000 K throughout their evolution and because they hardly emit ionizing photons, they do not create an H II region or significantly heat their immediate surroundings. Thus, radiative feedback is unable to hinder the growth of rapidly accreting stars to masses in excess of 10{sup 3} M{sub Sun} as long as material is accreted at rates M-dot{sub *}{approx}>10{sup -2} M{sub Sun} yr{sup -1}.

  19. CNO abundances in the quintuplet cluster M supergiant 5-7

    NASA Technical Reports Server (NTRS)

    Ramirez, S. V.; Sellgren, K.; Blum, R.; Terndrup, D. M.

    2002-01-01

    We present and analyze infrared spectra of the supergiant VR 5-7, in the Quintuplet cluster 30 pc from the Galactic center. Within the uncertainties, the [C/H],[N/H], and [O/H] abundances in this star are equal of Ori, a star which exhibits mixing of CNO processed elements, but distinct from the abundance patterns in IRS 7.

  20. THE THIRD SIGNATURE OF GRANULATION IN BRIGHT-GIANT AND SUPERGIANT STARS

    SciTech Connect

    Gray, David F.; Pugh, Teznie

    2012-04-15

    We investigated third-signature granulation plots for 18 bright giants and supergiants and one giant of spectral classes G0 to M3. These plots reveal the net granulation velocities, averaged over the stellar disk, as a function of depth. Supergiants show significant differences from the 'standard' shape seen for lower-luminosity stars. Most notable is a striking reversal of slope seen for three of the nine supergiants, i.e., stronger lines are more blueshifted than weaker lines, opposite the solar case. Changes in the third-signature plot of {alpha} Sco (M1.5 Iab) with time imply granulation cells that penetrate only the lower portion of the photosphere. For those stars showing the standard shape, we derive scaling factors relative to the Sun that serve as a first-order measure of the strength of the granulation relative to the Sun. For G-type stars, the third-signature scale of the bright giants and supergiants is approximately 1.5 times as strong as in dwarfs, but for K stars, there in no discernible difference between higher-luminosity stars and dwarfs. Classical macroturbulence, a measure of the velocity dispersion of the granulation, increases with the third-signature-plot scale factors, but at different rates for different luminosity classes.

  1. Spectroscopic studies of four southern-hemisphere G-K supergiants: HD 192876 (α1 Cap), HD 194215 (HR 7801), HD 206834 (c Cap), and HD 222574 (104 Aqr)

    NASA Astrophysics Data System (ADS)

    Usenko, I. A.; Kniazev, A. Yu.; Berdnikov, L. N.; Kravtsov, V. V.

    2015-11-01

    We have studied the high-resolution spectra taken with the 1.9-m telescope of the South African Astronomical Observatory for four supergiants that are deemed to be nonvariable and to lie beyond the red edge of the Cepheid instability strip (CIS): HD 192876, HD 194215, HD 206834, and HD 222574. The atmospheric parameters, reddenings, luminosities, distances, radii, and chemical composition have been determined for these stars. Based on these results, we have ascertained thatHD194215 is not a mainsequence star but an ordinary supergiant. All objects exhibit a nearly solar metallicity. The abundances of carbon and oxygen in HD 194215 and HD 206834 are nearly solar, while they are underabundant in HD 192876 and HD 222574. The abundances of sodium, magnesium, and aluminum are different for all objects, while those of the remaining elements are nearly solar. For HD 206834, the measured radial velocity exceeds its previously known values by a factor of 3, while the asymmetric knifelike profiles of the Ha and Hß absorption lines suggest the existence of an extended envelope around the star. Similar profiles of hydrogen absorption lines and strong lines of some metals with low lower-level excitation potentials have also been revealed in the spectrum of HD 222574. The positions of the supergiants on the effective temperature-luminosity diagram in comparison with the evolutionary tracks of the stars have shown their masses to lie within the range 3.4-4.3 M ⊙. HD 194215 and HD 206834 have crossed the CIS for the first time, with the latter object being near the stage of transformation into a red supergiant. HD 192876 and HD 222574 have already passed the first dredge-up and probably move from right to left, crossing the CIS for the second time. The position of HD 222574 near the red CIS edge is probably attributable to its Cepheid-like brightness and radial velocity variations.

  2. Discovery of the First B[e] Supergiants in M 31

    NASA Astrophysics Data System (ADS)

    Kraus, M.; Cidale, L. S.; Arias, M. L.; Oksala, M. E.; Borges Fernandes, M.

    2014-01-01

    B[e] supergiants (B[e]SGs) are transitional objects in the post-main sequence evolution of massive stars. The small number of B[e]SGs known so far in the Galaxy and the Magellanic Clouds indicates that this evolutionary phase is short. Nevertheless, the strong aspherical mass loss occurring during this phase, which leads to the formation of rings or disk-like structures, and the similarity to possible progenitors of SN1987 A emphasize the importance of B[e]SGs for the dynamics of the interstellar medium as well as stellar and galactic chemical evolution. The number of objects and their mass-loss behavior at different metallicities are essential ingredients for accurate predictions from stellar and galactic evolution calculations. However, B[e]SGs are not easily identified, as they share many characteristics with luminous blue variables (LBVs) in their quiescent (hot) phase. We present medium-resolution near-infrared K-band spectra for four stars in M 31, which have been assigned a hot LBV (candidate) status. Applying diagnostics that were recently developed to distinguish B[e]SGs from hot LBVs, we classify two of the objects as bonafide LBVs; one of them currently in outburst. In addition, we firmly classify the two stars 2MASS J00441709+4119273 and 2MASS J00452257+4150346 as the first B[e]SGs in M 31 based on strong CO band emission detected in their spectra, and infrared colors typical for this class of stars. Based on observations obtained at the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under a cooperative agreement with the NSF on behalf of the Gemini partnership: the National Science Foundation (United States), the Science and Technology Facilities Council (United Kingdom), the National Research Council (Canada), CONICYT (Chile), the Australian Research Council (Australia), Ministrio da Cincia, Tecnologia e Inovao (Brazil) and Ministerio de Ciencia, Tecnologa e Innovacin Productiva (Argentina), under program ID GN-2013B-Q-10.

  3. The population of M-type supergiants in the starburst cluster Stephenson 2

    NASA Astrophysics Data System (ADS)

    Negueruela, I.; Gonzlez-Fernndez, C.; Dorda, R.; Marco, A.; Clark, J. S.

    2013-05-01

    The open cluster Stephenson 2 contains the largest collection of red supergiants known in the Galaxy, and at present is the second most massive young cluster known in the Milky Way. We have obtained multi-epoch, intermediate-resolution spectra around the Ca ii triplet for more than 30 red supergiants in Stephenson 2 and its surroundings. We find a clear separation between a majority of RSGs having spectral types M0-M2 and the brightest members in the NIR, which have very late spectral types and show strong evidence for heavy mass loss. The distribution of spectral types is similar to that of RSGs in other clusters, such as NGC 7419, or associations, like Per OB1. The cluster data strongly support the idea that heavy mass loss and maser emission is preferentially associated with late-M spectral types, suggesting that they represent an evolutionary phase.

  4. The stellar wind velocity function for red supergiants determined in eclipsing binaries

    NASA Technical Reports Server (NTRS)

    Ahmad, Imad A.; Stencel, Robert E.

    1988-01-01

    The potential for direct measurement of the acceleration of stellar winds from the supergiant component of Zeta Aurigae-type binary stars is discussed. The aberration angle of the interaction shock cone centered on the hot star provides a measure of the velocity of the cool star wind at the orbit of the secondary. This is confirmed by direct observations of stellar wind (P Cygni) line profile variations. This velocity is generally smaller than the final (terminal) velocity of the wind, deduced from the P Cygni line profiles. The contrast between these results and previously published supergiant wind models is discussed. The implication on the physics of energy source dissipation predicted in the theoretical models is considered.

  5. THE CURIOUS CASE OF THE ALPHA PERSEI CORONA: A DWARF IN SUPERGIANT'S CLOTHING?

    SciTech Connect

    Ayres, Thomas R.

    2011-09-10

    Alpha Persei (HD 20902: F5 Iab) is a luminous, nonvariable supergiant located at the blue edge of the Cepheid instability strip. It is one of the brightest coronal X-ray sources in the young open cluster bearing its name, yet warm supergiants as a class generally avoid conspicuous high-energy activity. The Cosmic Origins Spectrograph on the Hubble Space Telescope has recently uncovered additional oddities. The 1290-1430 A far-ultraviolet (FUV) spectrum of {alpha} Per is dominated by photospheric continuum emission, with numerous superposed absorption features, mainly stellar. However, the normal proxies of coronal activity, such as the Si IV 1400 A doublet (T {approx} 8 x 10{sup 4} K), are very weak, as are the chromospheric C II 1335 A multiplet (T {approx} 3 x 10{sup 4} K) and O I 1305 A triplet. In fact, the Si IV features of {alpha} Per are not only narrower than those of later, G-type supergiants of similar L{sub X}/L{sub bol}, but are also fainter (in L{sub SiIV}/L{sub bol}) by two orders of magnitude. Further, a reanalysis of the ROSAT pointing on {alpha} Per finds the X-ray centroid offset from the stellar position by 9'', at a moderate level of significance. The FUV and X-ray discrepancies raise the possibility that the coronal source might be unrelated to the supergiant, perhaps an accidentally close dwarf cluster member; heretofore unrecognized in the optical, lost in the glare of the bright star.

  6. A transient supergiant X-ray binary in IC 10: An extragalactic SFXT?

    SciTech Connect

    Laycock, Silas; Cappallo, Rigel; Oram, Kathleen; Balchunas, Andrew

    2014-07-01

    We report the discovery of a large amplitude (factor of ∼100) X-ray transient (IC 10 X-2, CXOU J002020.99+591758.6) in the nearby dwarf starburst galaxy IC 10 during our Chandra monitoring project. Based on the X-ray timing and spectral properties, and an optical counterpart observed with Gemini, the system is a high-mass X-ray binary consisting of a luminous blue supergiant and a neutron star. The highest measured luminosity of the source was 1.8 × 10{sup 37} erg s{sup –1}during an outburst in 2003. Observations before, during, and after a second outburst in 2010 constrain the outburst duration to be less than 3 months (with no lower limit). The X-ray spectrum is a hard power law (Γ = 0.3) with fitted column density (N{sub H} = 6.3 × 10{sup 21} atom cm{sup –2}), consistent with the established absorption to sources in IC 10. The optical spectrum shows hydrogen Balmer lines strongly in emission at the correct blueshift (-340 km s{sup –1}) for IC 10. The N III triplet emission feature is seen, accompanied by He II [4686] weakly in emission. Together these features classify the star as a luminous blue supergiant of the OBN subclass, characterized by enhanced nitrogen abundance. Emission lines of He I are seen, at similar strength to Hβ. A complex of Fe II permitted and forbidden emission lines are seen, as in B[e] stars. The system closely resembles galactic supergiant fast X-ray transients, in terms of its hard spectrum, variability amplitude, and blue supergiant primary.

  7. An observational evaluation of magnetic confinement in the winds of BA supergiants

    NASA Astrophysics Data System (ADS)

    Shultz, M.; Wade, G. A.; Petit, V.; Grunhut, J.; Neiner, C.; Hanes, D.; MiMeS Collaboration

    2014-02-01

    Magnetic wind confinement has been proposed as one explanation for the complex wind structures of supergiant stars of spectral types B and A. Observational investigation of this hypothesis was undertaken using high-resolution (λ/Δλ ˜ 65 000) circular polarization (Stokes V) spectra of six late B- and early A-type supergiants (β Ori, B8Iae; 4 Lac, B9Iab; η Leo, A0Ib; HR1040, A0Ib; α Cyg, A2Iae; ν Cep, A2Iab), obtained with the instruments ESPaDOnS and Narval at the Canada-France-Hawaii Telescope and the Bernard Lyot Telescope. Least-squares deconvolution (LSD) analysis of the Stokes V spectra of all stars yields no evidence of a magnetic field, with best longitudinal field 1σ error bars ranging from ˜0.5 to ˜4.5 G for most stars. Spectrum synthesis analysis of the LSD profiles using Bayesian inference yields an upper limit with 95.4 per cent credibility on the polar strength of the (undetected) surface dipole fields of individual stars ranging from 3 to 30 G. These results strongly suggest that magnetic wind confinement due to organized dipolar magnetic fields is not the origin of the wind variability of BA supergiant stars. Upper limits for magnetic spots may also be inconsistent with magnetic wind confinement in the limit of large spot size and filling factor, depending on the adopted wind parameters. Therefore, if magnetic spots are responsible for the wind variability of BA supergiant stars, they likely occupy a small fraction of the photosphere.

  8. Mass fluxes for O-type supergiants with metallicity Z = Z?/5

    NASA Astrophysics Data System (ADS)

    Lucy, L. B.

    2015-10-01

    A code used previously to predict O-star mass fluxes as a function of metallicity is used to compute a grid of models with the metallicity of the Small Magellanic Cloud (SMC). These models allow mass-loss rates to be derived by interpolation for all O-type supergiants in the SMC, with the possible exception of extremely massive stars close to the Eddington limit.

  9. A Transient Supergiant X-Ray Binary in IC 10: An Extragalactic SFXT?

    NASA Astrophysics Data System (ADS)

    Laycock, Silas; Cappallo, Rigel; Oram, Kathleen; Balchunas, Andrew

    2014-07-01

    We report the discovery of a large amplitude (factor of ~100) X-ray transient (IC 10 X-2, CXOU J002020.99+591758.6) in the nearby dwarf starburst galaxy IC 10 during our Chandra monitoring project. Based on the X-ray timing and spectral properties, and an optical counterpart observed with Gemini, the system is a high-mass X-ray binary consisting of a luminous blue supergiant and a neutron star. The highest measured luminosity of the source was 1.8 1037 erg s-1during an outburst in 2003. Observations before, during, and after a second outburst in 2010 constrain the outburst duration to be less than 3 months (with no lower limit). The X-ray spectrum is a hard power law (? = 0.3) with fitted column density (NH = 6.3 1021 atom cm-2), consistent with the established absorption to sources in IC 10. The optical spectrum shows hydrogen Balmer lines strongly in emission at the correct blueshift (-340 km s-1) for IC 10. The N III triplet emission feature is seen, accompanied by He II [4686] weakly in emission. Together these features classify the star as a luminous blue supergiant of the OBN subclass, characterized by enhanced nitrogen abundance. Emission lines of He I are seen, at similar strength to H?. A complex of Fe II permitted and forbidden emission lines are seen, as in B[e] stars. The system closely resembles galactic supergiant fast X-ray transients, in terms of its hard spectrum, variability amplitude, and blue supergiant primary.

  10. The Convection of Close Red Supergiant Stars Observed With Near-Infrared Interferometry

    NASA Astrophysics Data System (ADS)

    Montargès, M.; Kervella, P.; Perrin, G.; Chiavassa, A.; Aurière, M.

    2015-12-01

    Our team has obtained observations of the photosphere of the two closest red supergiant stars Betelgeuse (α Ori) and Antares (α Sco) using near infrared interferometry. We have been monitoring the photosphere of Betelgeuse with the VLTI/PIONIER instrument for three years. On Antares, we obtained an unprecedented sampling of the visibility function. These data allow us to probe the convective photosphere of massive evolved stars.

  11. Near-infrared spectroscopy of candidate red supergiant stars in clusters

    NASA Astrophysics Data System (ADS)

    Messineo, Maria; Zhu, Qingfeng; Ivanov, Valentin D.; Figer, Donald F.; Davies, Ben; Menten, Karl M.; Kudritzki, Rolf P.; Chen, C.-H. Rosie

    2014-11-01

    Context. Clear identifications of Galactic young stellar clusters farther than a few kpc from the Sun are rare, despite the large number of candidate clusters. Aims: We aim to improve the selection of candidate clusters rich in massive stars with a multiwavelength analysis of photometric Galactic data that range from optical to mid-infrared wavelengths. Methods: We present a photometric and spectroscopic analysis of five candidate stellar clusters, which were selected as overdensities with bright stars (Ks< 7 mag) in GLIMPSE and 2MASS images. Results: A total of 48 infrared spectra were obtained. The combination of photometry and spectroscopy yielded six new red supergiant stars with masses from 10 M? to 15 M?. Two red supergiants are located at Galactic coordinates (l,b) = (16.7, -0.63) and at a distance of about ~3.9 kpc; four other red supergiants are members of a cluster at Galactic coordinates (l,b) = (49.3, + 0.72) and at a distance of ~7.0 kpc. Conclusions: Spectroscopic analysis of the brightest stars of detected overdensities and studies of interstellar extinction along their line of sights are fundamental to distinguish regions of low extinction from actual stellar clusters. The census of young star clusters containing red supergiants is incomplete; in the existing all-sky near-infrared surveys, they can be identified as overdensities of bright stars with infrared color-magnitude diagrams characterized by gaps. Based on observations collected at the European Southern Observatory (ESO Programme 60.A-9700(E), and 089.D-0876), and on observations collected at the UKIRT telescope (programme ID H243NS).MM is currently employed by the MPIfR. Part of this work was performed at RIT (2009), at ESA (2010), and at the MPIfR.Tables 3, 4, and 6 are available in electronic form at http://www.aanda.org

  12. SUPERGIANT SHELLS AND MOLECULAR CLOUD FORMATION IN THE LARGE MAGELLANIC CLOUD

    SciTech Connect

    Dawson, J. R.; Dickey, John M.; McClure-Griffiths, N. M.; Wong, T.; Hughes, A.; Fukui, Y.; Kawamura, A.

    2013-01-20

    We investigate the influence of large-scale stellar feedback on the formation of molecular clouds in the Large Magellanic Cloud (LMC). Examining the relationship between H I and {sup 12}CO(J = 1-0) in supergiant shells (SGSs), we find that the molecular fraction in the total volume occupied by SGSs is not enhanced with respect to the rest of the LMC disk. However, the majority of objects ({approx}70% by mass) are more molecular than their local surroundings, implying that the presence of a supergiant shell does on average have a positive effect on the molecular gas fraction. Averaged over the full SGS sample, our results suggest that {approx}12%-25% of the molecular mass in supergiant shell systems was formed as a direct result of the stellar feedback that created the shells. This corresponds to {approx}4%-11% of the total molecular mass of the galaxy. These figures are an approximate lower limit to the total contribution of stellar feedback to molecular cloud formation in the LMC, and constitute one of the first quantitative measurements of feedback-triggered molecular cloud formation in a galactic system.

  13. Interacting supernovae from photoionization-confined shells around red supergiant stars.

    PubMed

    Mackey, Jonathan; Mohamed, Shazrene; Gvaramadze, Vasilii V; Kotak, Rubina; Langer, Norbert; Meyer, Dominique M-A; Moriya, Takashi J; Neilson, Hilding R

    2014-08-21

    Betelgeuse, a nearby red supergiant, is a fast-moving star with a powerful stellar wind that drives a bow shock into its surroundings. This picture has been challenged by the discovery of a dense and almost static shell that is three times closer to the star than the bow shock and has been decelerated by some external force. The two physically distinct structures cannot both be formed by the hydrodynamic interaction of the wind with the interstellar medium. Here we report that a model in which Betelgeuse's wind is photoionized by radiation from external sources can explain the static shell without requiring a new understanding of the bow shock. Pressure from the photoionized wind generates a standing shock in the neutral part of the wind and forms an almost static, photoionization-confined shell. Other red supergiants should have much more massive shells than Betelgeuse, because the photoionization-confined shell traps up to 35 per cent of all mass lost during the red supergiant phase, confining this gas close to the star until it explodes. After the supernova explosion, massive shells dramatically affect the supernova light curve, providing a natural explanation for the many supernovae that have signatures of circumstellar interaction. PMID:25119040

  14. Gas kinematics and the structure of extragalactic giant and supergiant H II regions

    NASA Astrophysics Data System (ADS)

    Gallagher, J. S.; Hunter, D. A.

    1983-11-01

    We examine the hypothesis of Terlevich and Melnick that velocity widths of emission lines in luminous H II regions reflect the gravitationally bound state of these systems. Observational data to test this concept are taken from our homogeneous sets of flux calibrated H? images and high-resolution echelle Hoc intensity line velocity profiles for nearby irregular galaxies. Giant H II regions with diameters in the range 50-500 pc show well-known supersonic gas velocities, but no convincing evidence is found to associate these motions with gravitational binding of the H II complexes. Large-scale gas flows induced by embedded OB stellar populations provide a more plausible explanation for observed velocity line widths in the giant H II regions. Supergiant H II complexes with diameters of more than 500 pc have some features which are consistent with self-gravitating models and are in any case kinematically distinct from more common giant H II regions. Since supergiant H II complexes extend over significant fractions of their parent galaxies, observed velocities in the ionized gas are likely to be substantially influenced by kinematic properties of the galaxian environment. It thus is unlikely that pressure supported, bound self-gravitating models can provide a complete explanation for the gas kinematics of supergiant H II regions.

  15. Do All Stars Form in Clusters?: Masses and Ages of Young Supergiants in Andromeda

    NASA Astrophysics Data System (ADS)

    Choudhury, Zareen; Debs, C.; Kirby, E. N.; Guhathakurta, P.

    2013-01-01

    Currently it is not understood whether seemingly isolated stars formed in situ or were ejected from star clusters as runaway stars. Previous studies determined the origins of isolated stars by measuring their velocities, but past research was limited to OB stars in the Milky Way and Magellanic Clouds due to the difficulty of computing velocities of distant objects. This study proposed an innovative velocity test to statistically determine whether six seemingly isolated BA-type supergiants in Andromeda are runaways. We calculated the minimum relative transverse velocity needed for each supergiant to travel to its current location from the nearest open cluster. By comparing the minimum velocity with Andromedas known velocity dispersion, a statistical measure of the stars actual velocities, we determined whether the star had the necessary velocity to be a runaway. Minimum velocity was computed from the age of the star, which was calculated from its effective temperature and surface gravity. To compute effective temperature and surface gravity, we applied three new techniques based on Balmer absorption features. The results suggest that all six supergiants had the necessary velocities to be runaways. Although the proposed velocity test is a statistical assessment, it offers a valuable new tool for future investigation of isolated stars beyond the Milky Way and its satellites. This research was supported by the Science Internship Program (SIP) at UCSC, the National Science Foundation, NASA, and Palomar Observatory.

  16. SiO and H2O Maser Observations of Red Supergiants in Star Clusters Embedded in the Galactic Disk

    NASA Astrophysics Data System (ADS)

    Deguchi, Shuji; Nakashima, Jun-Ichi; Zhang, Yong; Chong, Selina S. N.; Koike, Kazutaka; Kwok, Sun

    2010-04-01

    We present the results of radio observations of red supergiants in a star cluster, Stephenson (1990, AJ, 99, 1867)'s #2, and of candidates for red supergiants in three star clusters, Mercer et al. (2005, ApJ, 635, 560)'s #4, #8, and #13, in the SiO and H2O maser lines. The Stephenson's #2 cluster and nearby aggregation at the southwest contain more than 15 red supergiants. We detected one red supergiant at the center of Stephenson's #2 and three in a southwest aggregation in the SiO maser line; three out of these four were also detected in the H2O maser line. The average radial velocity of the four detected objects is 97 km s-1, giving a kinematic distance of 5.5 kpc, which locates this cluster near the base of the Scutum-Crux spiral arm. We also detected six SiO emitting objects associated with other star clusters. In addition, mapping observations in the CO J = 1-0 line toward these clusters revealed that an appreciable amount of molecular gas still remains around the Stephenson's #2 cluster in contrast to the prototypical red-supergiant cluster, Bica et al. (2003, A&A, 404, 223)'s #122. This indicates that the time scale of gas expulsion differs considerably in individual clusters.

  17. Massive star evolution: The formation of massive stars in clusters and the evolution of the atmospheres of supergiants

    NASA Astrophysics Data System (ADS)

    Lipscy, Sarah Jane

    This dissertation presents the results of three distinct projects regarding the evolution of massive stars. Mid-infrared observations of the central 400 pc of the starburst galaxy M82 disclose the existence of multiple star forming region each with sizes and inferred masses comparable to globular clusters. Hundreds to thousands of massive stars have formed in each of the identified clusters. At least 20% of the star formation in M82 is found to occur in super star clusters. Radio observations of the nearby supergiant VY CMa are fit to an isothermal outer atmosphere with a radio photosphere. An extrapolation of the model can account for the observed total mass-loss rate of the star. Additionally, mid-infrared observations of VY CMa suggests that warm dust is extended in the anisotropically around the star, in a direction consistent with the asymmetric near-infrared reflection nebula. A mid-IR imaging survey of 18 red supergiants is presented. Beyond the asymmetries found in VY CMa, the supergiants NML Cyg, TV Gem, and a Ori are tentatively reported to have an anisotropic distribution of dust. The remaining supergiants in the survey show no asymmetry or are unresolved. The resolved sizes and upper limits to the sizes of the sources are used to find a best fit to the dust emissivity index for this sample of oxygen-rich supergiants.

  18. Microwave continuum measurements and estimates of mass loss rates for cool giants and supergiants

    NASA Technical Reports Server (NTRS)

    Drake, S. A.; Linsky, J. L.

    1986-01-01

    Attention is given to the results of a sensitive, 6-cm radio continuum survey conducted with the NRAO VLA of 39 of the nearest single cool giants and supergiants of G0-M5 spectral types; the survey was conducted in order to obtain accurate measurements of the mass loss rates of ionized gas for a representative sample of such stars, in order to furnish constraints for, and a better understanding of, the total mass loss rates. The inferred angular diameters for the cool giant sources are noted to be twice as large as photospheric angular diameters, implying that these stars are surrounded by extended chromospheres containing warm partially ionized gas.

  19. The intrinsic values and color excesses of (B-V) for 115 F-K supergiants

    NASA Technical Reports Server (NTRS)

    Kelsall, T.

    1972-01-01

    Color excesses in B-V are determined indirectly from a study of Stromgren's b-y color for a sample of F0 - K5 supergiants. The resulting E(B-V)'s are estimated to have an expected precision of + or - 0.05. With the calculated color excesses and the observed values of B-V given in various catalogs, the run of B-V with spectral type is obtained. This B-V/(spectral type) relationship is compared with those found previously by other investigators.

  20. Global-scale 3-D RMHD Simulations of Red-Supergiant Convective Envelopes

    NASA Astrophysics Data System (ADS)

    Augustson, Kyle C.; Jiang, Yanfei; Cantiello, Matteo

    2015-08-01

    The radiative magnetohydrodynamic CSS code is used to simulate 3-D spherical segments of the convective regions of two red-supergiants of differing masses. Much as in the recent work of Y. Jiang (2015), it is found that the density inversion characteristic of 1-D stellar evolution calculations can instead become monotonically decreasing in 3-D. In particular, it vanishes when the Fe-bump region of the convection zone is optically thick. However, the density inversion can remain, though is temporally intermittent, when that region is sufficiently optically thin. The effects of curvature and magnetism on the large-scale convective cells are also assessed.

  1. Supersized: A Spitzer Survey of Dusty Disks around B[e] Supergiants in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Kastner, Joel; Buchanan, Catherine; Forrest, Bill; Sahai, Raghvendra; Sargent, Ben

    2006-05-01

    The enigmatic class of B[e] super/hypergiants include among the most luminous individual stars known. These stars are of great interest and importance to the study of massive stars and their environments. Via Cycle 1 Spitzer IRS observations, we discovered that two Large Magellanic Cloud (LMC) B[e] hypergiants, R 126 and R 66, display similar, flat IR spectral enegy distributions indicative of the presence of massive, dusty circumstellar disks; R 66 displays, in addition, spectral evidence for crystalline grains and PAHs. This Spitzer/IRS discovery of ``fraternal twin'' disks around R 126 and R 66 has provided new insight into the origin and composition of dusty disks around the most massive stars. We now propose to build on these results via a comprehensive Spitzer IRS and photometric survey of thermal dust emission from a complete sample of all B[e] supergiants and hypergiants in the Magellanic Clouds. The IRS spectra and IRAC/MIPS photometry data will establish the fraction of B[e] supergiants that are encircled by dusty disks and, through modeling, will yield the range of masses, radii, and scale heights that characterize B[e] star dust disks. These results will provide crucial constraints on models of the origin of disks around massive stars , as well as on mechanisms for the production of crystalline silicate grains and for the shaping of supernova remnants.

  2. The 100-month Swift Catalogue of Supergiant Fast X-ray Transients

    NASA Astrophysics Data System (ADS)

    Romano, P.; Ducci, L.; Krimm, H.; Palmer, D.; Esposito, P.; Vercellone, S.; Evans, P.; Guidorzi, C.; Mangano, V.; Kennea, J.

    2014-07-01

    We present the 100-month Swift Catalogue of Supergiant Fast X-ray Transients, a collection of over a thousand Swift/BAT flares from 11 Supergiant Fast X-ray Transients (SFXT), complete down to 15-150 keV fluxes of about 610^{-10} erg cm^{-2} s^{-1} (daily timescale) and about 1.510^{-9} erg cm^{-2} s^{-1} (orbital timescale, averaging about 800 s). This population is characterized by short (a few hundred seconds) and relatively bright (in excess of 100 mCrab, 15-50 keV) events, lasting much less than a day in the hard X-rays. The outbursts are a much longer phenomenon however, as testified by the clustering of flares in orbital phase-space. They last up to a few days, as previously discovered from Swift deeper soft X-ray observations. We use this large dataset to probe the properties of the high and intermediate emission states in SFXTs, and to infer the properties of these binary systems. We also present preliminary results from our analysis of spectral evolution dependent flux light curves and broad-band spectroscopy of the outbursts. Finally, we provide a recipe to estimate the number of flares per year each source is likely to produce as a function of the detection threshold and limiting flux.

  3. The red supergiant and supernova rate problems: implications for core-collapse supernova physics

    NASA Astrophysics Data System (ADS)

    Horiuchi, S.; Nakamura, K.; Takiwaki, T.; Kotake, K.; Tanaka, M.

    2014-11-01

    Mapping supernovae to their progenitors is fundamental to understanding the collapse of massive stars. We investigate the red supergiant problem, which concerns why red supergiants with masses 16-30 M? have not been identified as progenitors of Type IIP supernovae, and the supernova rate problem, which concerns why the observed cosmic supernova rate is smaller than the observed cosmic star formation rate. We find key physics to solving these in the compactness parameter, which characterizes the density structure of the progenitor. If massive stars with compactness above ?2.5 0.2 fail to produce canonical supernovae, (i) stars in the mass range 16-30 M? populate an island of stars that have high ?2.5 and do not produce canonical supernovae, and (ii) the fraction of such stars is consistent with the missing fraction of supernovae relative to star formation. We support this scenario with a series of two- and three-dimensional radiation hydrodynamics core-collapse simulations. Using more than 300 progenitors covering initial masses 10.8-75 M? and three initial metallicities, we show that high compactness is conducive to failed explosions. We then argue that a critical compactness of 0.2 as the divide between successful and failed explosions is consistent with state-of-the-art three-dimensional core-collapse simulations. Our study implies that numerical simulations of core collapse need not produce robust explosions in a significant fraction of compact massive star initial conditions.

  4. The progenitor of supernova 1993J - A stripped supergiant in a binary system?

    NASA Technical Reports Server (NTRS)

    Podsiaklowski, PH.; Hsu, J. J. L.; Joss, P. C.; Ross, R. R.

    1993-01-01

    Supernova 1993J in the spiral galaxy M81 is the brightest supernova since SN1987A and, like the latter, appears to be another 'peculiar' type II supernova. The available photometry of the supernova region before the explosion requires the presence of at least two supergiants (one of early spectral type and the other of late type), but the actual progenitor has yet to be identified. We show that the explosion of a late-type supergiant can explain the initial sharp peak in the supernova light curve, provided that the star had lost almost all of its hydrogen-rich envelope before the explosion. In our model, the secondary brightening of the supernova, about 10 days later, is then a consequence of the radioactive decay of Ni-56 (and subsequently Co-56) produced in the explosion. The progenitor could have lost its hydrogen-rich envelope either in a strong stellar wind or, as seems more likely, through mass transfer to a companion star. In the latter case, the companion should reappear after the supernova photosphere has receded, the system having become a binary composed of a neutron star with a massive stellar companion.

  5. SPECTROSCOPIC STUDY OF THE VARIABILITY OF THREE NORTHERN Of{sup +} SUPERGIANTS

    SciTech Connect

    De Becker, M.

    2009-10-20

    The transition from early Of stars to WN-type objects is poorly understood. O-type supergiants with emission lines (OIf{sup +}) are considered to be intermediate between these two classes. The scope of this paper is to investigate the spectral variability of three Of{sup +} supergiants. We constituted spectral time series of unprecedented quality for our targets (approx200 spectra in total), essentially in the blue domain, covering timescales from a few hours up to a few years. Temporal Variance Spectrum and Fourier analyses were performed in order to characterize their spectral variability. We report on a correlated significant line profile variability in the prominent He II lambda4686 and Hbeta lines most likely related to the strong stellar winds. The variability pattern is similar for the three stars investigated (HD 14947, HD 15570, and HD 16691), and the main differences are more quantitative than qualitative. However, the reported timescales are somewhat different, and the most striking variability pattern is reported for HD 16691. We did not find any clear evidence for binarity, and we focus mainly on an interpretation based on a single-star scenario. We show that the behavior of the three stars investigated in this study present strong similarities, pointing to a putative common scenario, even though a few differences should be noted. Our preferred interpretation scheme is that of Large-Scale Corotating Structures modulating the profile of the lines that are produced in the strong stellar wind.

  6. DOUBLE BOW SHOCKS AROUND YOUNG, RUNAWAY RED SUPERGIANTS: APPLICATION TO BETELGEUSE

    SciTech Connect

    Mackey, Jonathan; Mohamed, Shazrene; Neilson, Hilding R.; Langer, Norbert; Meyer, Dominique M.-A.

    2012-05-20

    A significant fraction of massive stars are moving supersonically through the interstellar medium (ISM), either due to disruption of a binary system or ejection from their parent star cluster. The interaction of their wind with the ISM produces a bow shock. In late evolutionary stages these stars may undergo rapid transitions from red to blue and vice versa on the Hertzsprung-Russell diagram, with accompanying rapid changes to their stellar winds and bow shocks. Recent three-dimensional simulations of the bow shock produced by the nearby runaway red supergiant (RSG) Betelgeuse, under the assumption of a constant wind, indicate that the bow shock is very young (<30, 000 years old), hence Betelgeuse may have only recently become an RSG. To test this possibility, we have calculated stellar evolution models for single stars which match the observed properties of Betelgeuse in the RSG phase. The resulting evolving stellar wind is incorporated into two-dimensional hydrodynamic simulations in which we model a runaway blue supergiant (BSG) as it undergoes the transition to an RSG near the end of its life. We find that the collapsing BSG wind bubble induces a bow shock-shaped inner shell around the RSG wind that resembles Betelgeuse's bow shock, and has a similar mass. Surrounding this is the larger-scale retreating bow shock generated by the now defunct BSG wind's interaction with the ISM. We suggest that this outer shell could explain the bar feature located (at least in projection) just in front of Betelgeuse's bow shock.

  7. SOFIA-EXES: Probing the Thermal Structure of M Supergiant Wind Acceleration Zones

    NASA Astrophysics Data System (ADS)

    Harper, Graham M.; O'Gorman, Eamon; Guinan, Edward F.; EXES Instrument Team, EXES Science Team

    2016-01-01

    There is no standard model for mass loss from cool evolved stars, particularly for non-pulsating giants and supergiants. For the early-M supergiants, radiation pressure, convective ejections, magnetic fields, and Alfven waves have all been put forward as potential mass loss mechanisms. A potential discriminator between these ideas is the thermal structure resulting from the heating-cooling balance in the acceleration zone - the most important region to study mass loss physics.We present mid-IR [Fe II] emission line profiles of Betelgeuse and Antares obtained with NASA-DLR SOFIA-EXES and NASA IRTF-TEXES that were obtained as part of a GO program (Harper: Cycle 2-0004) and EXES instrument commissioning observations. The intra-term transitions sample a range of excitation conditions, Texc=540K, 3,400K, and 11,700K, i.e., from the warm chromospheric plasma, that also emits in the cm-radio and ultraviolet, to the cold inner circumstellar envelope. The spectrally-resolved profiles, when combined with VLA cm-radio observations, provide new constraints on the temperature and flow velocity in the outflow accelerating region. The semi-empirical energy balance can be used to test theoretical predictions of wind heating.

  8. INTEGRAL study of temporal properties of bright flares in Supergiant Fast X-ray Transients

    NASA Astrophysics Data System (ADS)

    Sidoli, L.; Paizis, A.; Postnov, K.

    2016-04-01

    We have characterized the typical temporal behaviour of the bright X-ray flares detected from the three Supergiant Fast X-ray Transients (SFXTs) showing the most extreme transient behaviour (XTE J1739-302, IGR J17544-2619, SAX J1818.6-1703). We focus here on the cumulative distributions of the waiting-time (time interval between two consecutive X-ray flares), and the duration of the hard X-ray activity (duration of the brightest phase of an SFXT outburst), as observed by INTEGRAL/IBIS in the energy band 17-50 keV. Adopting the cumulative distribution of waiting-times, it is possible to identify the typical time-scale that clearly separates different outbursts, each composed by several single flares at ˜ks time-scale. This allowed us to measure the duration of the brightest phase of the outbursts from these three targets, finding that they show heavy-tailed cumulative distributions. We observe a correlation between the total energy emitted during SFXT outbursts and the time interval covered by the outbursts (defined as the elapsed time between the first and the last flare belonging to the same outburst as observed by INTEGRAL). We show that temporal properties of flares and outbursts of the sources, which share common properties regardless different orbital parameters, can be interpreted in the model of magnetized stellar winds with fractal structure from the OB-supergiant stars.

  9. Departure from centrosymmetry of red giants and supergiants measured with VLTI/AMBER

    NASA Astrophysics Data System (ADS)

    Cruzalèbes, P.; Jorissen, A.; Chiavassa, A.; Paladini, C.; Rabbia, Y.; Spang, A.

    2015-02-01

    We study a sample of 16 bright and well-resolved late-type stars (10 O-rich giants, 2 red supergiants, and 4 C-rich giants) using the ESO VLTI/AMBER facility at medium resolution (R=1500}) in the K band to detect and measure the deviation from centrosymmetry of their resolved surface brightness distribution. As indicator for departure from centrosymmetry, we use the centrosymmetry parameter (CSP). We observe that CSP increases along the asymptotic giant branch, reaching values as large as 30°. These large CSP values are likely attributable to a few large photospheric convective cells. Carbon stars like W Ori and R Scl, being close to the AGB tip, have the second largest CSP values (17.6° and 22.3°, respectively), being only surpassed by the M5.5Ib/II supergiant T Cet (with CSP of 30.4°.). For K and early M giants, CSP values are smaller, never exceeding 10°, with a clear tendency to increase with the atmospheric pressure scaleheight. This supports the hypothesis that the observed deviations from centrosymmetry are somehow related to convective cells, whose size depends upon the atmospheric pressure scaleheight.

  10. Spectroscopic and Photometric Variability in the A0 Supergiant HR 1040

    NASA Astrophysics Data System (ADS)

    Corliss, David J.; Morrison, Nancy D.; Adelman, Saul J.

    2015-12-01

    A time-series analysis of spectroscopic and photometric observables of the A0 Ia supergiant HR 1040 has been performed, including equivalent widths, radial velocities, and Strömgren photometric indices. The data, obtained from 1993 through 2007, include 152 spectroscopic observations from the Ritter Observatory 1 m telescope and 269 Strömgren photometric observations from the Four College Automated Photoelectric Telescope. Typical of late B- and early A-type supergiants, HR 1040 has a highly variable Hα profile. The star was found to have an intermittent active phase marked by correlation between the Hα absorption equivalent width and blue-edge radial velocity and by photospheric connections observed in correlations to equivalent width, second moment and radial velocity in Si ii λλ6347, 6371. High-velocity absorption (HVA) events were observed only during this active phase. HVA events in the wind were preceded by photospheric activity, including Si ii radial velocity oscillations 19-42 days prior to onset of an HVA event and correlated increases in Si ii Wλ and second moment from 13 to 23 days before the start of the HVA event. While increases in various line equivalent widths in the wind prior to HVA events have been reported in the past in other stars, our finding of precursors in enhanced radial velocity variations in the wind and at the photosphere is a new result.

  11. Study of the extinction law in M31 and selection of red supergiants

    NASA Astrophysics Data System (ADS)

    Nedialkov, Petko; Veltchev, Todor

    2015-01-01

    An average value of the total-to-selective-extinction ratio R_{V}=3.8 ± 0.4 in M31 is obtained by means of two independent methods and by use of the analytical formula of Cardelli, Clayton & Mathis (1989). This result differs from previous determinations as well from the `standard' value 3.1 for the Milky Way. The derived individual extinctions for blue and red luminous stars from the catalogue of Magnier et al. (1992) are in good agreement with recent estimates for several OB associations in M31 and thus the issue about the assumed optical opacity of the spiral disk still remains open. The presented list of 113 red supergiant candidates in M31 with their extinctions and luminosities contains 60 new objects of this type which are not identified in other publications. It is supplemented with further 290 stars dereddened on the base of results for their closest neighbors. The luminosity function of all red supergiant candidates and the percentage of those with progenitors over 20 M_{⊙} suggests that the evolution of massive stars in M31 resembles that in other Local Group galaxies.

  12. INTEGRAL study of temporal properties of bright flares in Supergiant Fast X-ray Transients

    NASA Astrophysics Data System (ADS)

    Sidoli, L.; Paizis, A.; Postnov, K.

    2016-01-01

    We have characterized the typical temporal behaviour of the bright X-ray flares detected from the three Supergiant Fast X-ray Transients showing the most extreme transient behaviour (XTE J1739-302, IGR J17544-2619, SAX J1818.6-1703). We focus here on the cumulative distributions of the waiting-time (time interval between two consecutive X-ray flares), and the duration of the hard X-ray activity (duration of the brightest phase of an SFXT outburst), as observed by INTEGRAL/IBIS in the energy band 17-50 keV. Adopting the cumulative distribution of waiting-times, it is possible to identify the typical timescale that clearly separates different outbursts, each composed by several single flares at ks timescale. This allowed us to measure the duration of the brightest phase of the outbursts from these three targets, finding that they show heavy-tailed cumulative distributions. We observe a correlation between the total energy emitted during SFXT outbursts and the time interval covered by the outbursts (defined as the elapsed time between the first and the last flare belonging to the same outburst as observed by INTEGRAL). We show that temporal properties of flares and outbursts of the sources, which share common properties regardless different orbital parameters, can be interpreted in the model of magnetized stellar winds with fractal structure from the OB-supergiant stars.

  13. LUMINOUS AND VARIABLE STARS IN M31 AND M33. I. THE WARM HYPERGIANTS AND POST-RED SUPERGIANT EVOLUTION

    SciTech Connect

    Humphreys, Roberta M.; Davidson, Kris; Grammer, Skyler; Kneeland, Nathan; Martin, John C.; Weis, Kerstin; Burggraf, Birgitta

    2013-08-10

    The progenitors of Type IIP supernovae (SNe) have an apparent upper limit to their initial masses of about 20 M{sub Sun }, suggesting that the most massive red supergiants evolve to warmer temperatures before their terminal explosion. But very few post-red supergiants are known. We have identified a small group of luminous stars in M31 and M33 that are candidates for post-red supergiant evolution. These stars have A-F-type supergiant absorption line spectra and strong hydrogen emission. Their spectra are also distinguished by the Ca II triplet and [Ca II] doublet in emission formed in a low-density circumstellar environment. They all have significant near- and mid-infrared excess radiation due to free-free emission and thermal emission from dust. We estimate the amount of mass they have shed and discuss their wind parameters and mass loss rates, which range from a few Multiplication-Sign 10{sup -6} to 10{sup -4} M{sub Sun} yr{sup -1}. On an H-R diagram, these stars will overlap the region of the luminous blue variables (LBVs) at maximum light; however, the warm hypergiants are not LBVs. Their non-spherical winds are not optically thick, and they have not exhibited any significant variability. We suggest, however, that the warm hypergiants may be the progenitors of the ''less luminous'' LBVs such as R71 and even SN1987A.

  14. IUE observations of the Henize-Carlson sample of peculiar emission line supergiants: The galactic analogs of the Magellanic Zoo

    NASA Technical Reports Server (NTRS)

    Shore, Steven N.; Brown, Douglas N.; Sanduleak, N.

    1986-01-01

    Some 15 stars from the Carlson-Henize survey of southern peculiar emission line stars were studied. From both the optical and UV spectra, they appear to be galactic counterparts of the most extreme early-type emission line supergiants of the Magellanic Clouds.

  15. Interplay between pulsations and mass loss in the blue supergiant 55 Cygnus = HD 198 478

    NASA Astrophysics Data System (ADS)

    Kraus, M.; Haucke, M.; Cidale, L. S.; Venero, R. O. J.; Nickeler, D. H.; Németh, P.; Niemczura, E.; Tomić, S.; Aret, A.; Kubát, J.; Kubátová, B.; Oksala, M. E.; Curé, M.; Kamiński, K.; Dimitrov, W.; Fagas, M.; Polińska, M.

    2015-09-01

    Context. Blue supergiant stars are known to display photometric and spectroscopic variability that is suggested to be linked to stellar pulsations. Pulsational activity in massive stars strongly depends on the star's evolutionary stage and is assumed to be connected with mass-loss episodes, the appearance of macroturbulent line broadening, and the formation of clumps in the wind. Aims: To investigate a possible interplay between pulsations and mass-loss, we carried out an observational campaign of the supergiant 55 Cyg over a period of five years to search for photospheric activity and cyclic mass-loss variability in the stellar wind. Methods: We modeled the H, He i, Si ii, and Si iii lines using the nonlocal thermal equilibrium atmosphere code FASTWIND and derived the photospheric and wind parameters. In addition, we searched for variability in the intensity and radial velocity of photospheric lines and performed a moment analysis of the line profiles to derive frequencies and amplitudes of the variations. Results: The Hα line varies with time in both intensity and shape, displaying various types of profiles: P Cygni, pure emission, almost complete absence, and double or multiple peaked. The star undergoes episodes of variable mass-loss rates that change by a factor of 1.7-2 on different timescales. We also observe changes in the ionization rate of Si ii and determine a multiperiodic oscillation in the He i absorption lines, with periods ranging from a few hours to 22.5 days. Conclusions: We interpret the photospheric line variations in terms of oscillations in p-, g-, and strange modes. We suggest that these pulsations can lead to phases of enhanced mass loss. Furthermore, they can mislead the determination of the stellar rotation. We classify the star as a post-red supergiant, belonging to the group of α Cyg variables. Based on observations taken with the Perek 2m telescope at Ondřejov Observatory, Czech Republic, and the Poznan Spectroscopic Telescope 2 at the Winer Observatory in Arizona, USA.Tables 1 and 2, Figs. 3 to 7 are available in electronic form at http://www.aanda.org

  16. Investigating the transitional nature of extreme O-type supergiants in X-rays

    NASA Astrophysics Data System (ADS)

    De Becker, Michael

    2011-10-01

    We propose to investigate the X-ray properties of HD14947, an O5 supergiant believed to be a transition object between O and Wolf-Rayet stars. Stars belonging to this scarce category display several properties strongly pointing to their transitional status, including broad and strong emission lines in the visible and infrared, and the existence is some cases of surrounding nebulae similar to those existing close to WR stars. We request observation time with XMM-Newton to check whether the X-ray emission of HD14947 deviates significantly from the expected behaviour of regular O-type stars, as recently revealed by our team on the basis of an XMM-Newton observation of a similar object, attempting to establish an additional transition criterion in X-rays for evolved O-type stars.

  17. Ultraviolet spectral morphology of the O stars. IV - The OB supergiant sequence

    NASA Technical Reports Server (NTRS)

    Walborn, Nolan R.; Nichols-Bohlin, Joy

    1987-01-01

    An atlas of 25 O3-B8 supergiant spectra in the wavelength ranges 1320-1580 A and 1620-1880 A is presented, based on high-resolution data from the IUE archives. The remarkably detailed relationship between the stellar-wind profiles and the optical spectral classifications throughout this sequence is emphasized. For instance, the (Si IV)/(C IV) ratio reverses between O4 and O6.5; and the B0, B0.5, and B0.7 Ia wind characteristics are each qualitatively unique and distinct from one another. The systematic behavior of nine stellar-wind features with ionization potentials ranging from 114 to 19 eV is summarized as a function of advancing spectral type.

  18. IUE observations of HR 6902 - Effect of luminosity on supergiant chromospheres

    NASA Technical Reports Server (NTRS)

    Ahmad, Imad A.

    1990-01-01

    IUE observations of the most recently discovered Zeta Aurigae system, HR 6902, are reported to reveal profound differences in the spectrum of the chromosphere of the cool primary from those of all other Zeta Aurigae systems. Unlike its sister systems, HR 6902 shows evidence of neither strong wind nor an extended chromosphere for the cool primary. Instead, the spectrum is like that of a single blue dwarf. The most likely reason for this contrast to all other Zeta Aur systems observed with IUE is the lower luminosity of the HR 6902 primary: a type-II 'bright giant' as opposed to the type I (or Ib-II in the case of 22 Vul) 'supergiants' in the other Zeta Aur systems.

  19. Physical conditions near red giant and supergiant stars - An interpretation of SiO VLBI maps

    NASA Technical Reports Server (NTRS)

    Alcock, Charles; Ross, Randy R.

    1986-01-01

    Understanding the dynamical structure of circumstellar envelopes around cool giant and supergiant stars depends critically on the knowledge of what happens in the 'near zone' of the envelope, within a few stellar radii of the star. One probe with adequate angular resolution to study the near zone is VLBI observation of the SiO masers. It is shown that VLBI maps of VX Sgr establish that the particle density in the SiO masers is very high (about 10 to the 12th/cu cm), indicating that the masers form in dense cloudlets and not in a spherically expanding wind. The implications of these results for the mechanism of mass loss are discussed.

  20. The Swift Supergiant Fast X-Ray Transients Project:. [A Review, New Results and Future Perspectives

    NASA Technical Reports Server (NTRS)

    Romano, P.; Mangano, V.; Ducci, L.; Esposito, P.; Vercellone, S.; Bocchino, F.; Burrows, D. N.; Kennea, J. A.; Krimm, H. A.; Gehrels, N.; Farinelli, R.; Ceccobello, C.

    2013-01-01

    We present a review of the Supergiant Fast X-ray Transients (SFXT) Project, a systematic investigation of the properties of SFXTs with a strategy that combines Swift monitoring programs with outburst follow-up observations. This strategy has quickly tripled the available sets of broad-band data of SFXT outbursts, and gathered a wealth of out-of-outburst data, which have led us to a broad-band spectral characterization, an assessment of the fraction of the time these sources spend in each phase, and their duty cycle of inactivity. We present some new observational results obtained through our outburst follow-ups, as fitting examples of the exceptional capabilities of Swift in catching bright flares and monitor them panchromatically.

  1. Impact of mass-loss on the evolution and pre-supernova properties of red supergiants

    NASA Astrophysics Data System (ADS)

    Meynet, G.; Chomienne, V.; Ekström, S.; Georgy, C.; Granada, A.; Groh, J.; Maeder, A.; Eggenberger, P.; Levesque, E.; Massey, P.

    2015-03-01

    Context. The post-main-sequence evolution of massive stars is very sensitive to many parameters of the stellar models. Key parameters are the mixing processes, the metallicity, the mass-loss rate, and the effect of a close companion. Aims: We study the change in the red supergiant (RSG) lifetimes, the tracks in the Hertzsprung-Russel diagram (HRD), the positions in this diagram of the pre-supernova progenitor and the structure of the stars at that time for various mass-loss rates during the RSG phase and for two different initial rotation velocities. Methods: Stellar models were computed with the Geneva code for initial masses between 9 and 25 M⊙ at solar metallicity (Z = 0.014) with 10 times and 25 times the standard mass-loss rates during the RSG phase, with and without rotation. Results: The surface abundances of RSGs are much more sensitive to rotation than to the mass-loss rates during that phase. A change of the RSG mass-loss rate has a strong impact on the RSG lifetimes and in turn on the luminosity function of RSGs. An observed RSG is associated with a model of higher initial mass when models with an enhanced RSG mass-loss rate are used to deduce that mass. At solar metallicity, models with an enhanced mass-loss rate produce significant changes in the populations of blue, yellow, and RSGs. When extended blue loops or blueward excursions are produced by enhanced mass-loss, the models predict that a majority of blue (yellow) supergiants are post-RSG objects. These post-RSG stars are predicted to show much lower surface rotational velocities than similar blue supergiants on their first crossing of the HR gap. Enhanced mass-loss rates during the RSG phase have little impact on the Wolf-Rayet populations. The position in the HRD of the end point of the evolution depends on the mass of the hydrogen envelope. More precisely, whenever at the pre-supernova stage the H-rich envelope contains more than about 5% of the initial mass, the star is a RSG, and whenever the H-rich envelope contains less than 1% of the total mass, the star is a blue supergiant. For intermediate situations, intermediate colors and effective temperatures are obtained. Yellow progenitors for core-collapse supernovae can be explained by models with an enhanced mass-loss rate, while the red progenitors are better fitted by models with the standard mass-loss rate. Tracks of the enhanced mass loss rates models are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/575/A60

  2. Detection of Rotational CO Emission From the Red-supergiants in the Large Magellanic Cloud

    NASA Astrophysics Data System (ADS)

    Matsuura, M.; Sargent, B.; Swinyard, B.; Yates, J. A.; Royer, P.; Barlow, M. J.; Boyer, M. L.; Decin, L.; Khouri, T.; Meixner, M.; van Loon, J. Th.; Woods, P. M.

    2015-12-01

    It is yet well understood how mass-loss rates from evolved stars depend on metallicities. With a half of the solar metallicity and the distance of only 50 kpc, the evolved stars of the Large Magellanic Cloud (LMC) are an ideal target for studying mass loss at low metallicity. We have obtained spectra of red-supergiants in the LMC, using the Hershel Space Observatory, detecting CO thermal lines fro J=6-5 up to 15-14 lines. Modelling CO lines with non-LTE Radiative transfer code suggests that CO lines intensities can be well explained with high gas-to-dust ratio, with no obvious reduction in mass-loss rate at the LMC. We conclude that the luminosities of the stars are dominant factors on mass-loss rates, rather than the metallicity.

  3. OBSERVATIONAL EVIDENCE FOR A CORRELATION BETWEEN MACROTURBULENT BROADENING AND LINE-PROFILE VARIATIONS IN OB SUPERGIANTS

    SciTech Connect

    Simon-Diaz, S.; Herrero, A.; Castro, N.; Uytterhoeven, K.; Puls, J.

    2010-09-10

    The spectra of O and B supergiants (Sgs) are known to be affected by a significant form of extra line broadening (usually referred to as macroturbulence) in addition to that produced by stellar rotation. Recent analyses of high-resolution spectra have shown that the interpretation of this line broadening as a consequence of large-scale turbulent motions would imply highly supersonic velocity fields in photospheric regions, making this scenario quite improbable. Stellar oscillations have been proposed as a likely alternative explanation. As part of a long-term observational project, we are investigating the macroturbulent broadening in O and B Sgs and its possible connection with spectroscopic variability phenomena and stellar oscillations. In this Letter, we present the first encouraging results of our project, namely, firm observational evidence for a strong correlation between the extra broadening and photospheric line-profile variations in a sample of 13 Sgs with spectral types ranging from O9.5 to B8.

  4. Microvariability of line profiles in the spectra of OB stars: III. The supergiant ρ LEO

    NASA Astrophysics Data System (ADS)

    Kholtygin, A. F.; Fabrika, S. N.; Burlakova, T. E.; Valyavin, G. G.; Chuntonov, G. A.; Kudryavtsev, D. O.; Kang, D.; Yushkin, M. V.; Galazutdinov, G. A.

    2007-11-01

    We observed the bright supergiant ρ Leo (B1 lab) in January-February 2004 using the 6-m telescope of the Special Astrophysical Observatory (Russia) and the 1.8-m telescope of the Bohyunsan Optical Astronomy Observatory (South Korea). 47 spectra with high time resolution (4-10 min), signal-to-noise ratios 300-1000, and spectral resolutions 45 000-60 000 were obtained. We detected variability in the HeI, SiII, SiIII, and NII line profiles, which may be due to rotational modulation of the profiles and photospheric pulsations of ρ Leo. The possible influence of the stellar magnetic field on the line-profile variations is discussed.

  5. Properties of Supergiant Fast X-Ray Transients as Observed by Swift

    NASA Technical Reports Server (NTRS)

    Romano, P.; Vercellone, S.; Krimm, H. A.; Esposito, P.; Cusumano, C.; LaParola, V.; Mangano, V.; Kennea, J. A.; Burrows, D. N.; Pagani, C.; Gehrels, N.

    2011-01-01

    We present the most recent results from our investigation on Supergiant Fast X-ray Transients, a class of High-Mass X-ray Binaries, with a possible counterpart in the gamma-ray energy band. Since 2007 Swift has contributed to this new field by detecting outbursts from these fast transients with the BAT and by following them for days with the XRT. Thus, we demonstrated that while the brightest phase of the outburst only lasts a few hours, further activity is observed at lower fluxes for a remarkably longer time, up to weeks. Furthermore, we have performed several campaigns of intense monitoring with the XRT, assessing the fraction of the time these sources spend in each phase, and their duty cycle of inactivity.

  6. Pulsating red giants and supergiants as probes of galaxy formation and evolution

    NASA Astrophysics Data System (ADS)

    Theodorus van Loon, Jacco; Javadi, Atefeh; Khosroshahi, Habib; Rezaei, Sara; Golshan, Roya; Saberi, Maryam

    2015-08-01

    We have developed new techniques to use pulsating red giant and supergiants stars to reconstruct the star formation history of galaxies over cosmological time, as well as using them to map the dust production across their host galaxies. We describe the large programme on the Local Group spiral galaxy Triangulum (M33), which we have monitored at near-infrared wavelengths for several years using the United Kingdom InfraRed Telescope in Hawai'i. We outline the methodology and present the results for the central square kiloparsec (Javadi et al. 2011a,b, 2013) and - fresh from the press - the disc of M33 (Javadi et al. 2015, and in preparation). We also describe the results from our application of this new technique to other nearby galaxies: the Magellanic Clouds (published in Rezaei et al. 2014), the dwarf galaxies NGC 147 and 185 (Golshan et al. in preparation), and Centaurus A.

  7. The early-type strong emission-line supergiants of the Magellanic Clouds - A spectroscopic zoology

    NASA Technical Reports Server (NTRS)

    Shore, S. N.; Sanduleak, N.

    1984-01-01

    The results of a spectroscopic survey of 21 early-type extreme emission line supergiants of the Large and Small Magellanic Clouds using IUE and optical spectra are presented. The combined observations are discussed and the literature on each star in the sample is summarized. The classification procedures and the methods by which effective temperatures, bolometric magnitudes, and reddenings were assigned are discussed. The derived reddening values are given along with some results concerning anomalous reddening among the sample stars. The derived mass, luminosity, and radius for each star are presented, and the ultraviolet emission lines are described. Mass-loss rates are derived and discussed, and the implications of these observations for the evolution of the most massive stars in the Local Group are addressed.

  8. THE RED SUPERGIANT PROGENITOR OF SUPERNOVA 2012aw (PTF12bvh) IN MESSIER 95

    SciTech Connect

    Van Dyk, Schuyler D.; and others

    2012-09-10

    We report on the direct detection and characterization of the probable red supergiant (RSG) progenitor of the intermediate-luminosity Type II-Plateau (II-P) supernova (SN) 2012aw in the nearby (10.0 Mpc) spiral galaxy Messier 95 (M95; NGC 3351). We have identified the star in both Hubble Space Telescope images of the host galaxy, obtained 17-18 yr prior to the explosion, and near-infrared ground-based images, obtained 6-12 yr prior to the SN. The luminous supergiant showed evidence for substantial circumstellar dust, manifested as excess line-of-sight extinction. The effective total-to-selective ratio of extinction to the star was R'{sub V} Almost-Equal-To 4.35, which is significantly different from that of diffuse interstellar dust (i.e., R{sub V} = 3.1), and the total extinction to the star was therefore, on average, A{sub V} Almost-Equal-To 3.1 mag. We find that the observed spectral energy distribution for the progenitor star is consistent with an effective temperature of 3600 K (spectral type M3), and that the star therefore had a bolometric magnitude of -8.29. Through comparison with recent theoretical massive-star evolutionary tracks we can infer that the RSG progenitor had an initial mass 15 {approx}< M{sub ini}(M{sub Sun }) < 20. Interpolating by eye between the available tracks, we surmise that the star had initial mass {approx}17-18 M{sub Sun }. The circumstellar dust around the progenitor must have been destroyed in the explosion, as the visual extinction to the SN is found to be low (A{sub V} = 0.24 mag with R{sub V} = 3.1).

  9. Spectroscopic and Photometric Variability in the A0 Supergiant HR 1040

    NASA Astrophysics Data System (ADS)

    Corliss, David; Morrison, N. D.; Adelman, S. J.

    2014-01-01

    A longitudinal time series analysis of spectroscopic and photometric variability of the A0Ia supergiant HR 1040 has been performed, including equivalent widths, radial velocities and Strmgren photometric indices. The data, obtained from 1993 through 2007, include 152 spectroscopic observations from the Ritter Observatory and 269 Strmgren photometric observations from the Four College Automated Photoelectric Telescope (FCAPT). Typical of late B- and early A-type supergiants, HR 1040 has a highly variable stellar wind. The star was found to have an intermittent active phase marked by correlation between the H? absorption equivalent width and blue-edge radial velocity and photospheric connections observed in correlations to equivalent widths, second moment and radial velocity in the Si II ??6347, 6371 lines. Variable H? emission components were also studied, along with nearby weak absorption lines Mg II ? 6546 and C II ?? 6578, 6583. High-velocity absorption (HVA) events were observed only during this active phase. HVA events in the wind were preceded by photospheric activity, including Si II radial velocity oscillations similar in form to a Morlet wavelet 19 to 42 days prior to onset of an HVA and correlated increases in Si II equivalent width and second moment from 13 to 23 days before the start of the HVA. In the photometric data, the y magnitude is found to be strongly correlated the Si II observables, indicating a possible relationship between photometric changes and the variable microturbulence. While increases in various line equivalent widths in the wind prior to HVA events have been reported in the past in other stars, our finding of precursors in radial velocity variations in the wind and at the photosphere and intervals of increased photospheric microturbulence is a new result.

  10. Texes Observations of M Supergiants: Dynamics and Thermodynamics of Wind Acceleration

    NASA Astrophysics Data System (ADS)

    Harper, Graham M.; Richter, Matthew J.; Ryde, Nils; Brown, Alexander; Brown, Joanna; Greathouse, Thomas K.; Strong, Shadrian

    2009-08-01

    We have detected [Fe II] 17.94 ?m and 24.52 ?m emission from a sample of M supergiants (? Cep, ? Sco, ? Ori, CE Tau, AD Per, and ? Her) using the Texas Echelon Cross Echelle Spectrograph on NASA's Infrared Telescope Facility. These low opacity emission lines are resolved at R sime 50, 000 and provide new diagnostics of the dynamics and thermodynamics of the stellar wind acceleration zone. The [Fe II] lines, from the first excited term (a 4 F), are sensitive to the warm plasma where energy is deposited into the extended atmosphere to form the chromosphere and wind outflow. These diagnostics complement previous Kuiper Airborne Observatory and Infrared Space Observatory observations which were sensitive to the cooler and more extended circumstellar envelopes. The turbulent velocities of V turb sime 12-13 km s-1 observed in the [Fe II] a 4 F forbidden lines are found to be a common property of our sample, and are less than that derived from the hotter chromospheric C II] 2325 lines observed in ? Ori, where V turb sime 17-19 km s-1. For the first time, we have dynamically resolved the motions of the dominant cool atmospheric component discovered in ? Ori from multiwavelength radio interferometry by Lim et al. Surprisingly, the emission centroids are quite Gaussian and at rest with respect to the M supergiants. These constraints combined with model calculations of the infrared emission line fluxes for ? Ori imply that the warm material has a low outflow velocity and is located close to the star. We have also detected narrow [Fe I] 24.04 ?m emission that confirms Fe II is the dominant ionization state in ? Ori's extended atmosphere.

  11. Tests of two convection theories for red giant and red supergiant envelopes

    NASA Technical Reports Server (NTRS)

    Stothers, Richard B.; Chin, Chao-Wen

    1995-01-01

    Two theories of stellar envelope convection are considered here in the context of red giants and red supergiants of intermediate to high mass: Boehm-Vitense's standard mixing-length theory (MLT) and Canuto & Mazzitelli's new theory incorporating the full spectrum of turbulence (FST). Both theories assume incompressible convection. Two formulations of the convective mixing length are also evaluated: l proportional to the local pressure scale height (H(sub P)) and l proportional to the distance from the upper boundary of the convection zone (z). Applications to test both theories are made by calculating stellar evolutionary sequences into the red zone (z). Applications to test both theories are made by calculating stellar evolutionary sequences into the red phase of core helium burning. Since the theoretically predicted effective temperatures for cool stars are known to be sensitive to the assigned value of the mixing length, this quantity has been individually calibrated for each evolutionary sequence. The calibration is done in a composite Hertzsprung-Russell diagram for the red giant and red supergiant members of well-observed Galactic open clusters. The MLT model requires the constant of proportionality for the convective mixing length to vary by a small but statistically significant amount with stellar mass, whereas the FST model succeeds in all cases with the mixing lenghth simply set equal to z. The structure of the deep stellar interior, however, remains very nearly unaffected by the choices of convection theory and mixing lenghth. Inside the convective envelope itself, a density inversion always occurs, but is somewhat smaller for the convectively more efficient MLT model. On physical grounds the FST model is preferable, and seems to alleviate the problem of finding the proper mixing length.

  12. The type IIb supernova 2013df and its cool supergiant progenitor

    SciTech Connect

    Van Dyk, Schuyler D.; Cenko, S. Bradley; Foley, Ryan J.; Miller, Adam A.; Smith, Nathan; Lee, William H.; Ben-Ami, Sagi; Gal-Yam, Avishay

    2014-02-01

    We have obtained early-time photometry and spectroscopy of supernova (SN) 2013df in NGC 4414. The SN is clearly of Type IIb, with notable similarities to SN 1993J. From its luminosity at secondary maximum light, it appears that less {sup 56}Ni (? 0.06 M {sub ?}) was synthesized in the SN 2013df explosion than was the case for the SNe IIb 1993J, 2008ax, and 2011dh. Based on a comparison of the light curves, the SN 2013df progenitor must have been more extended in radius prior to explosion than the progenitor of SN 1993J. The total extinction for SN 2013df is estimated to be A{sub V} = 0.30 mag. The metallicity at the SN location is likely to be solar. We have conducted Hubble Space Telescope (HST) Target of Opportunity observations of the SN with the Wide Field Camera 3, and from a precise comparison of these new observations to archival HST observations of the host galaxy obtained 14 yr prior to explosion, we have identified the progenitor of SN 2013df to be a yellow supergiant, somewhat hotter than a red supergiant progenitor for a normal Type II-Plateau SN. From its observed spectral energy distribution, assuming that the light is dominated by one star, the progenitor had effective temperature T {sub eff} = 4250 100 K and a bolometric luminosity L {sub bol} = 10{sup 4.940.06} L {sub ?}. This leads to an effective radius R {sub eff} = 545 65 R {sub ?}. The star likely had an initial mass in the range of 13-17 M {sub ?}; however, if it was a member of an interacting binary system, detailed modeling of the system is required to estimate this mass more accurately. The progenitor star of SN 2013df appears to have been relatively similar to the progenitor of SN 1993J.

  13. Quantitative spectroscopy of blue supergiants in metal-poor dwarf galaxy NGC 3109

    SciTech Connect

    Hosek, Matthew W. Jr.; Kudritzki, Rolf-Peter; Bresolin, Fabio; Urbaneja, Miguel A.; Przybilla, Norbert; Evans, Christopher J.; Pietrzy?ski, Grzegorz; Gieren, Wolfgang; Carraro, Giovanni E-mail: kud@ifa.hawaii.edu E-mail: Miguel.Urbaneja-Perez@uibk.ac.at E-mail: chris.evans@stfc.ac.uk E-mail: wgieren@astro-udec.cl

    2014-04-20

    We present a quantitative analysis of the low-resolution (?4.5 ) spectra of 12 late-B and early-A blue supergiants (BSGs) in the metal-poor dwarf galaxy NGC 3109. A modified method of analysis is presented which does not require use of the Balmer jump as an independent T {sub eff} indicator, as used in previous studies. We determine stellar effective temperatures, gravities, metallicities, reddening, and luminosities, and combine our sample with the early-B-type BSGs analyzed by Evans et al. to derive the distance to NGC 3109 using the flux-weighted gravity-luminosity relation (FGLR). Using primarily Fe-group elements, we find an average metallicity of [ Z-bar ] = 0.67 0.13, and no evidence of a metallicity gradient in the galaxy. Our metallicities are higher than those found by Evans et al. based on the oxygen abundances of early-B supergiants ([ Z-bar ] = 0.93 0.07), suggesting a low ?/Fe ratio for the galaxy. We adjust the position of NGC 3109 on the BSG-determined galaxy mass-metallicity relation accordingly and compare it to metallicity studies of H II regions in star-forming galaxies. We derive an FGLR distance modulus of 25.55 0.09 (1.27 Mpc) that compares well with Cepheid and tip of the red giant branch distances. The FGLR itself is consistent with those found in other galaxies, demonstrating the reliability of this method as a measure of extragalactic distances.

  14. The Type IIb Supernova 2013df and its Cool Supergiant Progenitor

    NASA Astrophysics Data System (ADS)

    Van Dyk, Schuyler D.; Zheng, WeiKang; Fox, Ori D.; Cenko, S. Bradley; Clubb, Kelsey I.; Filippenko, Alexei V.; Foley, Ryan J.; Miller, Adam A.; Smith, Nathan; Kelly, Patrick L.; Lee, William H.; Ben-Ami, Sagi; Gal-Yam, Avishay

    2014-02-01

    We have obtained early-time photometry and spectroscopy of supernova (SN) 2013df in NGC 4414. The SN is clearly of Type IIb, with notable similarities to SN 1993J. From its luminosity at secondary maximum light, it appears that less 56Ni (lsim 0.06 M ?) was synthesized in the SN 2013df explosion than was the case for the SNe IIb 1993J, 2008ax, and 2011dh. Based on a comparison of the light curves, the SN 2013df progenitor must have been more extended in radius prior to explosion than the progenitor of SN 1993J. The total extinction for SN 2013df is estimated to be AV = 0.30 mag. The metallicity at the SN location is likely to be solar. We have conducted Hubble Space Telescope (HST) Target of Opportunity observations of the SN with the Wide Field Camera 3, and from a precise comparison of these new observations to archival HST observations of the host galaxy obtained 14 yr prior to explosion, we have identified the progenitor of SN 2013df to be a yellow supergiant, somewhat hotter than a red supergiant progenitor for a normal Type II-Plateau SN. From its observed spectral energy distribution, assuming that the light is dominated by one star, the progenitor had effective temperature T eff = 4250 100 K and a bolometric luminosity L bol = 104.94 0.06 L ?. This leads to an effective radius R eff = 545 65 R ?. The star likely had an initial mass in the range of 13-17 M ? however, if it was a member of an interacting binary system, detailed modeling of the system is required to estimate this mass more accurately. The progenitor star of SN 2013df appears to have been relatively similar to the progenitor of SN 1993J.

  15. TEXES OBSERVATIONS OF M SUPERGIANTS: DYNAMICS AND THERMODYNAMICS OF WIND ACCELERATION

    SciTech Connect

    Harper, Graham M.; Richter, Matthew J.; Ryde, Nils; Brown, Alexander; Brown, Joanna; Greathouse, Thomas K.; Strong, Shadrian

    2009-08-20

    We have detected [Fe II] 17.94 {mu}m and 24.52 {mu}m emission from a sample of M supergiants ({mu} Cep, {alpha} Sco, {alpha} Ori, CE Tau, AD Per, and {alpha} Her) using the Texas Echelon Cross Echelle Spectrograph on NASA's Infrared Telescope Facility. These low opacity emission lines are resolved at R {approx_equal} 50, 000 and provide new diagnostics of the dynamics and thermodynamics of the stellar wind acceleration zone. The [Fe II] lines, from the first excited term (a {sup 4} F), are sensitive to the warm plasma where energy is deposited into the extended atmosphere to form the chromosphere and wind outflow. These diagnostics complement previous Kuiper Airborne Observatory and Infrared Space Observatory observations which were sensitive to the cooler and more extended circumstellar envelopes. The turbulent velocities of V{sub turb} {approx_equal} 12-13 km s{sup -1} observed in the [Fe II] a {sup 4} F forbidden lines are found to be a common property of our sample, and are less than that derived from the hotter chromospheric C II] 2325 A lines observed in {alpha} Ori, where V{sub turb} {approx_equal} 17-19 km s{sup -1}. For the first time, we have dynamically resolved the motions of the dominant cool atmospheric component discovered in {alpha} Ori from multiwavelength radio interferometry by Lim et al. Surprisingly, the emission centroids are quite Gaussian and at rest with respect to the M supergiants. These constraints combined with model calculations of the infrared emission line fluxes for {alpha} Ori imply that the warm material has a low outflow velocity and is located close to the star. We have also detected narrow [Fe I] 24.04 {mu}m emission that confirms Fe II is the dominant ionization state in {alpha} Ori's extended atmosphere.

  16. The Type IIb Supernova 2013df and its Cool Supergiant Progenitor

    NASA Technical Reports Server (NTRS)

    VanDyk, Schuyler D.; Zeng, Weikang; Fox, Ori D.; Cenko, S. Bradley; Clubb, Kelsey I.; Filippenko, Alexei; Foley, Ryan J.; Miller, Adam A.; Smith, Nathan; Kelly, Patrick L.; Lee, William H.; Ben-Ami, Sagi; Gal-Yam, Avishay

    2014-01-01

    We have obtained early-time photometry and spectroscopy of supernova (SN) 2013df in NGC 4414. The SN is clearly of Type II b, with notable similarities to SN 1993J. From its luminosity at secondary maximum light, it appears that less Ni-56 (is approximately less than 0.06M) was synthesized in the SN 2013df explosion than was the case for the SNe II b 1993J, 2008ax, and 2011dh. Based on a comparison of the light curves, the SN 2013df progenitor must have been more extended in radius prior to explosion than the progenitor of SN 1993J. The total extinction for SN 2013dfis estimated to be A(sub V) = 0.30 mag. The metallicity at the SN location is likely to be solar. We have conducted Hubble Space Telescope(HST) Target of Opportunity observations of the SN with the Wide Field Camera 3, and from a precise comparison of these new observations to archival HST observations of the host galaxy obtained 14 yr prior to explosion, we have identified the progenitor of SN 2013df to be a yellow supergiant, somewhat hotter than a red supergiant progenitor for a normal Type II-Plateau SN. From its observed spectral energy distribution, assuming that the light is dominated by one star, the progenitor had effective temperature T(sub eff) = 4250+/-100 K and a bolometric luminosity L(sub bol) =10(exp 4.94+/-0.06) Solar Luminosity. This leads to an effective radius Reff = 545+/-65 Solar Radius. The star likely had an initial mass in the range of 13-17Solar Mass; however, if it was a member of an interacting binary system, detailed modeling of the system is required to estimate this mass more accurately. The progenitor star of SN 2013df appears to have been relatively similar to the progenitor of SN 1993J.

  17. Line-depth Ratios in H-band Spectra to Determine Effective Temperatures of G- and K-type Giants and Supergiants

    NASA Astrophysics Data System (ADS)

    Fukue, Kei; Matsunaga, Noriyuki; Yamamoto, Ryo; Kondo, Sohei; Kobayashi, Naoto; Ikeda, Yuji; Hamano, Satoshi; Yasui, Chikako; Arasaki, Takayuki; Tsujimoto, Takuji; Bono, Giuseppe; Inno, Laura

    2015-10-01

    The stellar effective temperature is the fundamental parameter of stellar atmospheres. It characterizes the spectra and plays an essential role in chemical abundance analysis. Previous optical studies have shown that line-depth ratios (LDRs) are good indicators of the effective temperature. Essentially, the ratios of absorption lines with different excitation potentials can be used as temperature scales. The most important advantage of LDRs is their robustness against interstellar reddening and extinction. Furthermore, the scales are constructed and calibrated empirically by observables. Although this method is well-established for optical spectra, we require infrared high-resolution spectroscopy to access the most obscured stars in the Galactic disk and thereby understand the Milky Ways structure and evolution in the innermost region. This study newly derives the temperature scales from the LDRs in infrared spectra. We explored LDRs in the high-resolution H-band spectra (1.4-1.8 ?m) of well-known stars in the solar neighborhood obtained with Subaru/infrared camera and spectrograph. We found nine pairs of absorption lines whose LDRs allow us to determine the temperatures of G- and K-type giants/supergiants to an accuracy of 60 K. Checking the dependency of our scales on stellar parameters, we found that our developed temperature scales may slightly bias the estimates for low-metal stars, [Fe/H] < -0.3 dex.

  18. Luminous and Variable Stars in M31 and M33. I. The Warm Hypergiants and Post-red Supergiant Evolution

    NASA Astrophysics Data System (ADS)

    Humphreys, Roberta M.; Davidson, Kris; Grammer, Skyler; Kneeland, Nathan; Martin, John C.; Weis, Kerstin; Burggraf, Birgitta

    2013-08-01

    The progenitors of Type IIP supernovae (SNe) have an apparent upper limit to their initial masses of about 20 M ?, suggesting that the most massive red supergiants evolve to warmer temperatures before their terminal explosion. But very few post-red supergiants are known. We have identified a small group of luminous stars in M31 and M33 that are candidates for post-red supergiant evolution. These stars have A-F-type supergiant absorption line spectra and strong hydrogen emission. Their spectra are also distinguished by the Ca II triplet and [Ca II] doublet in emission formed in a low-density circumstellar environment. They all have significant near- and mid-infrared excess radiation due to free-free emission and thermal emission from dust. We estimate the amount of mass they have shed and discuss their wind parameters and mass loss rates, which range from a few 10-6 to 10-4 M ? yr-1. On an H-R diagram, these stars will overlap the region of the luminous blue variables (LBVs) at maximum light; however, the warm hypergiants are not LBVs. Their non-spherical winds are not optically thick, and they have not exhibited any significant variability. We suggest, however, that the warm hypergiants may be the progenitors of the "less luminous" LBVs such as R71 and even SN1987A. Based on observations with the Multiple Mirror Telescope, a joint facility of the Smithsonian Institution and the University of Arizona and on observations obtained with the Large Binocular Telescope (LBT), an international collaboration among institutions in the United States, Italy, and Germany. LBT Corporation partners are: The University of Arizona on behalf of the Arizona University system; Istituto Nazionale di Astrofisica, Italy; LBT Beteiligungsgesellschaft, Germany, representing the Max-Planck Society, the Astrophysical Institute Potsdam, and Heidelberg University; The Ohio State University, and The Research Corporation, on behalf of The University of Notre Dame, University of Minnesota, and University of Virginia.

  19. Discovery of a red supergiant counterpart to RX J004722.4-252051, a ULX in NGC 253

    NASA Astrophysics Data System (ADS)

    Heida, M.; Torres, M. A. P.; Jonker, P. G.; Servillat, M.; Repetto, S.; Roberts, T. P.; Walton, D. J.; Moon, D.-S.; Harrison, F. A.

    2015-11-01

    We present two epochs of near-infrared spectroscopy of the candidate red supergiant counterpart to RX J004722.4-252051, a ULX in NGC 253. We measure radial velocities of the object and its approximate spectral type by cross-correlating our spectra with those of known red supergiants. Our VLT/X-shooter spectrum is best matched by that of early M-type supergiants, confirming the red supergiant nature of the candidate counterpart. The radial velocity of the spectrum, taken on 2014 August 23, is 417 ± 4 km s-1. This is consistent with the radial velocity measured in our spectrum taken with Magellan/MMIRS on 2013 June 28, of 410 ± 70 km s-1, although the large error on the latter implies that a radial velocity shift expected for a black hole of tens of M⊙ can easily be hidden. Using nebular emission lines we find that the radial velocity due to the rotation of NGC 253 is 351 ± 4 km s-1 at the position of the ULX. Thus the radial velocity of the counterpart confirms that the source is located in NGC 253, but also shows an offset with respect to the local bulk motion of the galaxy of 66 ± 6 km s-1. We argue that the most likely origin for this displacement lies either in a SN kick, requiring a system containing a ≳ 50 M⊙ black hole, and/or in orbital radial velocity variations in the ULX binary system, requiring a ≳ 100 M⊙ black hole. We therefore conclude that RX J004722.4-252051 is a strong candidate for a ULX containing a massive stellar black hole.

  20. The eccentric short-period orbit of the supergiant fast X-ray transient HD 74194 (=LM Vel)

    NASA Astrophysics Data System (ADS)

    Gamen, R.; Barbà, R. H.; Walborn, N. R.; Morrell, N. I.; Arias, J. I.; Maíz Apellániz, J.; Sota, A.; Alfaro, E. J.

    2015-11-01

    Aims. We present the first orbital solution for the O-type supergiant star HD 74194, which is the optical counterpart of the supergiant fast X-ray transient IGR J08408-4503. Methods. We measured the radial velocities in the optical spectrum of HD 74194, and we determined the orbital solution for the first time. We also analysed the complex Hα profle. Results. HD 74194 is a binary system composed of an O-type supergiant and a compact object in a short-period (P=9.5436 ± 0.0002 d) and high-eccentricity (e=0.63 ± 0.03) orbit. The equivalent width of the Hα line is not modulated entirely with the orbital period, but seems to vary in a superorbital period (P=285 ± 10 d) nearly 30 times longer than the orbital one. Table 3 is available in electronic form at http://www.aanda.org/10.1051/0004-6361/201527140/olm

  1. INTEGRAL Long-Term Monitoring of the Supergiant Fast X-Ray Transient XTE J1739-302

    NASA Technical Reports Server (NTRS)

    Blay, P.; Martinez-Nunez, S.; Negueruela, I.; Pottschmidt, K.; Smith, D. M.; Torrejon, J. M.; Reig, P.; Kretschmar, P.; Kreykenbohm, I.

    2008-01-01

    Context. In the past few years, a new class of High Mass X-Ray Binaries (HMXRB) has been claimed to exist, the Supergiant Fast X-ray Transients (SFXT). These are X-ray binary systems with a compact companion orbiting a supergiant star which show very short and bright outbursts in a series of activity periods overimposed on longer quiescent periods. Only very recently the first attempts to model the behaviour of these sources have been published, some of them within the framework of accretion from clumpy stellar winds. Aims. Our goal is to analyze the properties of XTE J1739-302/IGR J17391-3021 within the context of the clumpy structure of the supergiant wind. Methods. We have used INTEGRAL and RXTE/PCA observations in order to obtain broad band (1 - 200 keV) spectra and light curves of XTE J1739-302 and investigate its X-ray spectrum and temporal variability. Results. We have found that XTE J1739-302 follows a much more complex behaviour than expected. Far from presenting a regular variability pattern, XTE J1739-302 shows periods of high, intermediate, and low flaring activity.

  2. Dynamical mass of the O-type supergiant in ? Orionis A

    NASA Astrophysics Data System (ADS)

    Hummel, C. A.; Rivinius, Th.; Nieva, M.-F.; Stahl, O.; van Belle, G.; Zavala, R. T.

    2013-06-01

    Aims: A close companion of ? Orionis A was found in 2000 with the Navy Precision Optical Interferometer (NPOI), and shown to be a physical companion. Because the primary is a supergiant of type O, for which dynamical mass measurements are very rare, the companion was observed with NPOI over the full 7-year orbit. Our aim was to determine the dynamical mass of a supergiant that, due to the physical separation of more than 10 AU between the components, cannot have undergone mass exchange with the companion. Methods: The interferometric observations allow measuring the relative positions of the binary components and their relative brightness. The data collected over the full orbital period allows all seven orbital elements to be determined. In addition to the interferometric observations, we analyzed archival spectra obtained at the Calar Alto, Haute Provence, Cerro Armazones, and La Silla observatories, as well as new spectra obtained at the VLT on Cerro Paranal. In the high-resolution spectra we identified a few lines that can be associated exclusively to one or the other component for the measurement of the radial velocities of both. The combination of astrometry and spectroscopy then yields the stellar masses and the distance to the binary star. Results: The resulting masses for components Aa of 14.0 2.2 M? and Ab of 7.4 1.1 M? are low compared to theoretical expectations, with a distance of 294 21 pc which is smaller than a photometric distance estimate of 387 54 pc based on the spectral type B0III of the B component. If the latter (because it is also consistent with the distance to the Orion OB1 association) is adopted, the mass of the secondary component Ab of 14 3 M? would agree with classifying a star of type B0.5IV. It is fainter than the primary by about 2.2 0.1 magnitudes in the visual. The primary mass is then determined to be 33 10 M?. The possible reasons for the distance discrepancy are most likely related to physical effects, such as small systematic errors in the radial velocities due to stellar winds. Based in part on observations collected at the European Southern Observatory, Chile (Prop. No. 076.C-0431, 080.A-9021, 083.D-0589, 285.D-5042).

  3. An HST COS 'SNAPSHOT' spectrum of the K supergiant λ Vel (K4Ib-II)

    SciTech Connect

    Carpenter, Kenneth G.; Harper, Graham M.; Kober, Gladys; Nielsen, Krister E.; Wahlgren, Glenn M.

    2014-10-10

    We present a far-ultraviolet spectrum of the K4 Ib-II supergiant λ Vel obtained with the Hubble Space Telescope's Cosmic Origins Spectrograph (COS) as a part of the SNAPshot program 'SNAPing coronal iron' (GO 11687). The observation covers a wavelength region (1326-1467 Å) not previously recorded for λ Vel at a spectral resolving power of R ∼ 20,000 and displays strong emission and absorption features, superposed on a bright chromospheric continuum. Fluorescent excitation is responsible for much of the observed emission, mainly powered by strong H I Lyα and the O I (UV 2) triplet emission near λ1304. The molecular CO and H{sub 2} fluorescences are weaker than in the early-K giant α Boo while the Fe II and Cr II lines, also pumped by H I Lyα, are stronger in λ Vel. This pattern of relative line strengths between the two stars is explained by the lower iron-group element abundance in α Boo, which weakens that star's Fe II and Cr II emission without reducing the molecular fluorescences. The λ Vel spectrum shows fluorescent Fe II, Cr II, and H{sub 2} emission similar to that observed in the M supergiant α Ori, but more numerous well-defined narrow emissions from CO. The additional CO emissions are visible in the spectrum of λ Vel since that star does not have the cool, opaque circumstellar shells that surround α Ori and produce broad circumstellar CO (A-X) band absorptions that hide those emissions in the cooler star. The presence of Si IV emission in λ Vel indicates a ∼8 × 10{sup 4} K plasma that is mixed into the cooler chromosphere. Evidence of the stellar wind is seen in the C II λλ1334,1335 lines and in the blueshifted Fe II and Ni II wind absorption lines. Line modeling using Sobolev with Exact Integration for the C II lines indicates a larger terminal velocity (∼45 versus ∼30 km s{sup –1}) and turbulence (∼27 versus <21 km s{sup –1}) with a more quickly accelerating wind (β = 0.35 versus 0.7) at the time of this COS observation in 2010 than derived from Goddard High Resolution Spectrograph data obtained in 1994. The Fe II and Ni II absorptions are blueshifted by 7.6 km s{sup –1} relative to the chromospheric emission, suggesting formation in lower levels of the accelerating wind and their widths indicate a higher turbulence in the λ Vel wind compared to α Ori.

  4. The quest for blue supergiants : The evolution of the progenitor of SN 1987A

    NASA Astrophysics Data System (ADS)

    Menon, Athira; Heger, Alexander

    2015-08-01

    SN 1987A is historically one of the most remarkable supernova explosions to be seen from Earth. Due to the proximity of its location in the LMC, it remains the most well-studied object outside the solar system. It was also the only supernova whose progenitor was observed prior to its explosion.SN 1987A however, was a unique and enigmatic core collapse supernova. It was the first Type II supernova to have been observed to have exploded while its progenitor was a blue supergiant (BSG). Until then Type II supernovae were expected to originate from explosions of red supergiants (RSGs). A spectacular triple-ring nebula structure, rich in helium and nitrogen, was observed around the remnant, indicating a recent RSG phase before becoming a BSG. Even today it is not entirely understood what the evolutionary history may have been to cause a BSG to explode. The most commonly accepted hypothesis for its origin is the merger of a massive binary star system.An evolutionary scenario for such a binary system, was proposed by Podsiadlowski (1992) (P92). Through SPH simulations of the merger and the stellar evolution of the post-merger remnant, Ivanova & Podsiadlowski (2002) and (2003) (I&M) could successfully obtain the RSG to BSG transition of the progenitor.The aim of the present work is to produce the evolutionary history of the progenitor of SN 1987A and its explosion. We construct our models based on the results of P92 and I&M. Here, the secondary (less massive) star is accreted on the primary, while being simultaneously mixed in its envelope over a period of 100 years. The merged star is evolved until the onset of core collapse. For this work we use the 1-dimensional, implicit, hydrodynamical stellar evolution code, KEPLER. A large parameter space is explored, consisting of primary (16-20 Ms) and secondary masses (5-8 Ms), mixing boundaries, and accreting timescales. Those models whose end states match the observed properties of the progenitor of SN 1987A are exploded. The nuclear yields and light curve of the explosion are then compared with the observed data of SN 1987A.

  5. Core collapse supernovae from blue supergiant progenitors : The evolutionary history of SN 1987A

    NASA Astrophysics Data System (ADS)

    Menon, Athira

    2015-08-01

    SN 1987A is historically one of the most remarkable supernova explosions to be seen from Earth. Due to the proximity of its location in the LMC, it remains the most well-studied object outside the solar system. It was also the only supernova whose progenitor was observed prior to its explosion.SN 1987A however, was a unique and enigmatic core collapse supernova. It was the first Type II supernova to have been observed to have exploded while its progenitor was a blue supergiant (BSG). Until then Type II supernovae were expected to originate from explosions of red supergiants (RSGs). A spectacular triple-ring nebula structure, rich in helium and nitrogen, was observed around the remnant, indicating a recent RSG phase before becoming a BSG. Even today it is not entirely understood what the evolutionary history may have been to cause a BSG to explode. The most commonly accepted hypothesis for its origin is the merger of a massive binary star system.An evolutionary scenario for such a binary system, was proposed by Podsiadlowski (1992) (P92). Through SPH simulations of the merger and the stellar evolution of the post-merger remnant, Ivanova & Podsiadlowski (2002) and (2003) (I&M) could successfully obtain the RSG to BSG transition of the progenitor.The aim of the present work is to produce the evolutionary history of the progenitor of SN 1987A and its explosion. We construct our models based on the results of P92 and I&M. Here, the secondary (less massive) star is accreted on the primary, while being simultaneously mixed in its envelope over a period of 100 years. The merged star is evolved until the onset of core collapse. For this work we use the 1-dimensional, implicit, hydrodynamical stellar evolution code, KEPLER. A large parameter space is explored, consisting of primary (16-20 Ms) and secondary masses (5-8 Ms), mixing boundaries, and accreting timescales. Those models whose end states match the observed properties of the progenitor of SN 1987A are exploded. The nuclear yields and light curve of the explosion are then compared with the observed data of SN 1987A.

  6. Identification of red supergiants in nearby galaxies with mid-IR photometry

    NASA Astrophysics Data System (ADS)

    Britavskiy, N. E.; Bonanos, A. Z.; Mehner, A.; García-Álvarez, D.; Prieto, J. L.; Morrell, N. I.

    2014-02-01

    Context. The role of episodic mass loss in massive-star evolution is one of the most important open questions of current stellar evolution theory. Episodic mass loss produces dust and therefore causes evolved massive stars to be very luminous in the mid-infrared and dim at optical wavelengths. Aims: We aim to increase the number of investigated luminous mid-IR sources to shed light on the late stages of these objects. To achieve this we employed mid-IR selection criteria to identity dusty evolved massive stars in two nearby galaxies. Methods: The method is based on mid-IR colors, using 3.6 μm and 4.5 μm photometry from archival Spitzer Space Telescope images of nearby galaxies and J-band photometry from 2MASS. We applied our criteria to two nearby star-forming dwarf irregular galaxies, Sextans A and IC 1613, selecting eight targets, which we followed-up with spectroscopy. Results: Our spectral classification and analysis yielded the discovery of two M-type supergiants in IC 1613, three K-type supergiants and one candidate F-type giant in Sextans A, and two foreground M giants. We show that the proposed criteria provide an independent way for identifying dusty evolved massive stars that can be extended to all nearby galaxies with available Spitzer/IRAC images at 3.6 μm and 4.5 μm. Based on observations made with the Gran Telescopio Canarias (GTC), installed in the Spanish Observatorio de El Roque de Los Muchachos of the Instituto de Astrofísica de Canarias, on the island of La Palma, and the 2.5 m du Pont telescope in operation at Las Campanas Observatory, Chile.Spectra are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/562/A75

  7. SPECTRAL TYPES OF RED SUPERGIANTS IN NGC 6822 AND THE WOLF-LUNDMARK-MELOTTE GALAXY

    SciTech Connect

    Levesque, Emily M.; Massey, Philip

    2012-07-15

    We present moderate-resolution spectroscopic observations of red supergiants (RSGs) in the low-metallicity Local Group galaxies NGC 6822 (Z = 0.4 Z{sub Sun} ) and Wolf-Lundmark-Melotte (WLM; Z = 0.1 Z{sub Sun} ). By combining these observations with reduction techniques for multislit data reduction and flux calibration, we are able to analyze spectroscopic data of 16 RSGs in NGC 6822 and spectrophotometric data of 11 RSGs in WLM. Using these observations, we determine spectral types for these massive stars, comparing them to Milky Way and Magellanic Cloud RSGs and thus extending observational evidence of the abundance-dependent shift of RSG spectral types to lower metallicities. In addition, we have uncovered two RSGs with unusually late spectral types (J000158.14-152332.2 in WLM, with a spectral type of M3 I, and J194453.46-144552.6 in NGC 6822, with a spectral type of M4.5 I) and a third RSG (J194449.96-144333.5 in NGC 6822) whose spectral type has varied from an M2.5 in 1997 to a K5 in 2008. All three of these stars could potentially be members of a recently discovered class of extreme RSG variables.

  8. Ejecting the envelope of red supergiant stars with jets launched by an inspiralling neutron star

    NASA Astrophysics Data System (ADS)

    Papish, Oded; Soker, Noam; Bukay, Inbal

    2015-05-01

    We study the properties of jets launched by a neutron star (NS) spiralling inside the envelope and core of a red supergiant (RSG). We propose that Thorne-?ytkow objects (TZO) are unlikely to be formed via common envelope (CE) evolution if accretion on to the NS can exceed the Eddington rate with much of the accretion energy directed into jets that subsequently dissipate within the giant envelope. We use the jet-feedback mechanism, where energy deposited by the jets drives the ejection of the entire envelope and part of the core, and find a very strong interaction of the jets with the core material at late phases of the CE evolution. Following our results, we speculate on two rare processes that might take place in the evolution of massive stars. (1) Recent studies have claimed that the peculiar abundances of the HV2112 RSG star can be explained if this star is a TZO. We instead speculate that the rich-calcium envelope comes from a supernova (SN) explosion of a stellar companion that was only slightly more massive than HV2112, such that during its explosion HV2112 was already a giant that intercepted a relatively large fraction of the SN ejecta. (2) We raise the possibility that strong r-process nucleosynthesis, where elements with high atomic weight of A ? 130 are formed, occurs inside the jets that are launched by the NS inside the core of the RSG star.

  9. Quantitative spectroscopic J-band study of red supergiants in Perseus OB-1

    SciTech Connect

    Gazak, J. Zachary; Kudritzki, Rolf; Davies, Ben; Bergemann, Maria; Plez, Bertrand

    2014-06-10

    We demonstrate how the metallicities of red supergiant (RSG) stars can be measured from quantitative spectroscopy down to resolutions of ≈3000 in the J-band. We have obtained high resolution spectra on a sample of the RSG population of h and χ Persei, a double cluster in the solar neighborhood. We show that careful application of the MARCS model atmospheres returns measurements of Z consistent with solar metallicity. Using two grids of synthetic spectra–one in pure LTE and one with non-LTE (NLTE) calculations for the most important diagnostic lines–we measure Z = +0.04 ± 0.10 (LTE) and Z = –0.04 ± 0.08 (NLTE) for the sample of eleven RSGs in the cluster. We degrade the spectral resolution of our observations and find that those values remain consistent down to resolutions of less than λ/δλ of 3000. Using measurements of effective temperatures we compare our results with stellar evolution theory and find good agreement. We construct a synthetic cluster spectrum and find that analyzing this composite spectrum with single-star RSG models returns an accurate metallicity. We conclude that the RSGs make ideal targets in the near infrared for measuring the metallicities of star forming galaxies out to 7-10 Mpc and up to 10 times farther by observing the integrated light of unresolved super star clusters.

  10. X-RAY EMISSION FROM THE SUPERGIANT SHELL IN IC 2574

    SciTech Connect

    Yukita, Mihoko; Swartz, Douglas A.

    2012-05-01

    The M81 group member dwarf galaxy IC 2574 hosts a supergiant shell of current and recent star formation activity surrounding a 1000 Multiplication-Sign 500 pc hole in the ambient H I gas distribution. Chandra X-ray Observatory imaging observations reveal a luminous, L{sub X} {approx} 6.5 Multiplication-Sign 10{sup 38} erg s{sup -1} in the 0.3-8.0 keV band, point-like source within the hole but offset from its center and fainter diffuse emission extending throughout and beyond the hole. The star formation history at the location of the point source indicates a burst of star formation beginning {approx}25 Myr ago and currently weakening and there is a young nearby star cluster, at least 5 Myr old, bracketing the likely age of the X-ray source at between 5 and {approx}25 Myr. The source is thus likely a bright high-mass X-ray binary-either a neutron star or black hole accreting from an early B star undergoing thermal-timescale mass transfer through Roche lobe overflow. The properties of the residual diffuse X-ray emission are consistent with those expected from hot gas associated with the recent star formation activity in the region.

  11. Quantitative Spectroscopic J-band study of Red Supergiants in Perseus OB-1

    NASA Astrophysics Data System (ADS)

    Gazak, J. Zachary; Davies, Ben; Kudritzki, Rolf; Bergemann, Maria; Plez, Bertrand

    2014-06-01

    We demonstrate how the metallicities of red supergiant (RSG) stars can be measured from quantitative spectroscopy down to resolutions of ?3000 in the J-band. We have obtained high resolution spectra on a sample of the RSG population of h and ? Persei, a double cluster in the solar neighborhood. We show that careful application of the MARCS model atmospheres returns measurements of Z consistent with solar metallicity. Using two grids of synthetic spectra-one in pure LTE and one with non-LTE (NLTE) calculations for the most important diagnostic lines-we measure Z = +0.04 0.10 (LTE) and Z = -0.04 0.08 (NLTE) for the sample of eleven RSGs in the cluster. We degrade the spectral resolution of our observations and find that those values remain consistent down to resolutions of less than ?/?? of 3000. Using measurements of effective temperatures we compare our results with stellar evolution theory and find good agreement. We construct a synthetic cluster spectrum and find that analyzing this composite spectrum with single-star RSG models returns an accurate metallicity. We conclude that the RSGs make ideal targets in the near infrared for measuring the metallicities of star forming galaxies out to 7-10 Mpc and up to 10 times farther by observing the integrated light of unresolved super star clusters. Based in part on data collected at Subaru Telescope, which is operated by the National Astronomical Observatory of Japan.

  12. IUE observations of a luminous M supergiant that exhibits intense continuum in the far ultraviolet

    NASA Technical Reports Server (NTRS)

    Michalitsianos, A. G.; Kafatos, M.; Hobbs, R. W.

    1980-01-01

    Observations of the late type M supergiant TV Gem (M1Iab) reveal strong UV continuum between 1200 A and 3200 A. The continuum is essentially featureless with the exception of a number of broad absorption features in the short wavelength spectra range. An absorption feature centered around 1400 A could be due to Si IV absorption found typically in spectra of middle B type stars. UV emission from this star is unexpected because earlier ground-based observations give no indication of a possible association with an early companion or circumstellar ionized nebulosity. A B9 or A1 III - IV type star approximately 2to 3 magnitudes fainter than the M star could explain the level of UV continuum observed, but a fully self consistent explanation that includes the B-V color index of TV Gem is not as yet possible. The continuum flux dependence with wavelength in the UV spectral range could be attributed to a high energy source such as an accretion disc. It is suggested TV Gem is a good candidate for HEAO-2 (Einstein) satellite observations because a high energy object in close proximity to the M star would likely be a source of soft X-ray emission.

  13. Identification of red supergiants in the Local Group with mid-IR photometry

    NASA Astrophysics Data System (ADS)

    Britavskiy, Nikolay; Bonanos, Alceste; Mehner, Andrea

    2015-08-01

    Star forming dwarf irregular (dIrr) galaxies serve as ideal laboratories for investigating the evolution and mass loss phenomenon of red supergiants (RSGs) within the context of different metallicities of host galaxies. Also, RSGs may be used for abundance determinations in dIrrs. The extremely low number of spectroscopically confirmed RSGs in external galaxies makes the identification of new RSGs statistically significant. We present a systematic survey of RSGs and luminous blue variables (LBVs) with the goal to complete the census of these objects in the Local Group. Using the fact that RSGs and LBVs are bright in mid-infrared colors due to dust, we propose and apply a technique that allows us to select dusty massive stars based on their [3.6] and [4.5] Spitzer photometry (Britavskiy et al. 2014). We present the results of our spectroscopic follow-up of luminous infrared sources in 7 nearby dIrrs (Phoenix, Pegasus, Sextans A, Sextans B, WLM, IC 10 and IC 1613) based on VLT/FORS2 and GTC/OSIRIS observations. In total we have observed 100 targets, among which we have so far identified 16 RSGs and 2 new emission line objects in these galaxies. Moreover, using the newly discovered RSGs, we have revised the mid-IR and optical photometric selection criteria for this type of objects, which can be applied to other galaxies of the Local Group and beyond.

  14. Investigation of atmosphere nonstationarity in the supergiant 55Cyg. I. Temporal line profile variability

    NASA Astrophysics Data System (ADS)

    Rzaev, A. Kh.

    2012-07-01

    The CCD spectra taken with echelle spectrographs of the 2-m telescope of the Shemakha Astrophysical Observatory of the National Academy of Sciences of Azerbaijan and the 1-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences are used to study the line profile variations in the spectrum of the hot supergiant 55Cyg. The variability of the radial velocity and profiles of the lines of heavy elements is shown to be due to radial pulsation type motions. The corresponding variations for He I lines are due to nonradial pulsations. In the case of the H ? and H ? lines the pattern and behavior of variations differ for different observing periods. The variability of these lines is mostly due to the photometric and positional variability of the absorption and emission components of their profiles. The profiles of these lines show additional emission components, which move from the blue toward the red line wing. Such a behavior is indicative of the clumpy structure of the stellar envelope.

  15. Wolf-Rayet, Yellow and Red Supergiant in the single massive stars perspective

    NASA Astrophysics Data System (ADS)

    Georgy, Cyril; Hirschi, R.; Ekstrom, S.; Meynet, G.

    2013-06-01

    Rotation and mass loss are the key ingredients determining the fate of single massive stars. In recent years, a large effort has been made to compute whole grids of stellar models at different metallicities, including or not the effects of rotation, with the Geneva evolution code. In this talk, I will focus on the evolved stages of massive star evolution (red and yellow supergiants, Wolf-Rayet stars), in the framework of these new grids of models. I will highlight the effects of rotation and mass loss on the post-main sequence evolution of massive stars at solar and lower metallicity. In particular, I will discuss their impact on the maximum mass for a star to end its life as a RSG (leading to a type IIP supernova), on the possibility for a star to finish as a YSG, and on the initial mass ranges leading to various WR star subtypes. I will then compare the results predicted by our code with observed populations of evolved massive stars, bringing constraints on our computations, as well as some indications on the binary star fraction needed to reproduce them.

  16. 3-D radiative transfer modeling of rotational modulations in the blue supergiant J Puppis

    NASA Astrophysics Data System (ADS)

    Lobel, Alex

    2013-06-01

    The fast increase of multi-CPU/core computing power over the last decade has dramatically advanced our understanding of the structuring mechanisms in the winds of the most massive stars. I present an overview of research results obtained with the Wind3D radiative transfer code that reveal intricate internal wind structures on both large and intermediate length-scales. Hydrodynamic models computed with Zeus3D of the so-called ``co-rotating interaction (wind) regions'' correctly fit Discrete Absorption Components observed in UV P Cygni-type wind lines of many massive hot stars. Recent 3-D radiative transfer modeling research with Wind3D shows that the enigmatic Rotational Modulations observed in wind lines of blue supergiants (such as J Puppis; HD 64760) are caused by a remarkably regular pattern of radial density enhancements that protrude almost linearly into the equatorial wind. I discuss very recent advanced hydrodynamical simulations of these radiatively-driven winds and demonstrate that the linearly shaped radial wind pattern is caused by mechanical wave action at the base of the wind, which can result from non-radial stellar pulsations.

  17. THE ULTRA-LONG GAMMA-RAY BURST 111209A: THE COLLAPSE OF A BLUE SUPERGIANT?

    SciTech Connect

    Gendre, B.; Cutini, S.; D'Elia, V.; Stratta, G.; Atteia, J. L.; Klotz, A.; Basa, S.; Boeer, M.; Coward, D. M.; Howell, E. J; Piro, L.

    2013-03-20

    We present optical, X-ray and gamma-ray observations of GRB 111209A, observed at a redshift of z = 0.677. We show that this event was active in its prompt phase for about 25000 s, making it the longest burst ever observed. This rare event could have been detected up to z {approx} 1.4 in gamma-rays. Compared to other long gamma-ray bursts (GRBs), GRB 111209A is a clear outlier in the energy-fluence and duration plane. The high-energy prompt emission shows no sign of a strong blackbody component, the signature of a tidal disruption event, or a supernova shock breakout. Given the extreme longevity of this event, and lack of any significant observed supernova signature, we propose that GRB 111209A resulted from the core-collapse of a low-metallicity blue supergiant star. This scenario is favored because of the necessity to supply enough mass to the central engine over a duration of thousands of seconds. Hence, we suggest that GRB 111209A could have more in common with population III stellar explosions, rather than those associated with normal long GRBs.

  18. Interferometric Measurements Of The A-type Supergiant Deneb With The CHARA Array

    NASA Astrophysics Data System (ADS)

    Aufdenberg, Jason P.; Mrand, A.; Ridgway, S. T.; Coud du Foresto, V.; Kervella, P.; Berger, D.; Sturmann, J.; Sturmann, L.; ten Brummelaar, T. A.; Turner, N. H.; McAlister, H. A.

    2006-06-01

    We have obtained precise interferometric measurements of the A-type supergiant Deneb (A2Ia) at the Center for High Angular Resolution Astronomy (CHARA) Array in the infrared K' band (1.94 to 2.34 microns) using the Fiber Linked Unit for Optical Recombination (FLUOR). Our observations were obtained over 20 nights in 2004 and 2005 with five telescope pairs E2-W2, W2-S2, W1-E2, E1-W1, and S1-W2. The projected baselines span 106 to 312 meters and sample the first and second lobes of Deneb's visibility curve. Our preliminary analysis reveals that the amplitude of the second lobe of the visibility curve is weaker than that predicted by a spherical hydrostatic model atmosphere.We also find that Deneb's angular diameter varies with position angle at the level of a few percent. We will present these data and discuss our analysis using a unified expanding model atmosphere and a rotationally distorted model atmosphere.This work was performed in part under contract with the Jet Propulsion Laboratory (JPL) funded by NASA through the Michelson Fellowship Program. JPL is managed for NASA by the California Institute of Technology. The CHARA Array is operated by the Center for High Angular Resolution Astronomy, Georgia State University, Atlanta, GA. Additional support comes from the National Science Foundation, the Keck Foundation and the Packard Foundation.

  19. Period Changes in Pulsating Red Supergiant Stars: A Science and Education Project

    NASA Astrophysics Data System (ADS)

    Percy, J. R.; Favaro, E.; Glasheen, J.; Ho, B.; Sato, H.

    2008-12-01

    We describe research done as part of the University of Toronto Mentorship Program, which enables outstanding senior high school students to work on research projects at the university. The students began with extensive background reading on variable stars, and became familiar with various forms of time-series analysis by applying them to a few red supergiant variables in the AAVSO International Database; we report on the results. They also prepared a useful manual for our publicly-available self-correlation analysis software. They undertook an intensive analysis of the period changes in BC Cyg, using the AAVSO and Turner data and the (O-C) method, in the hope that evolutionary period changes could be observed. The (O-C) diagram, however, is dominated by errors in determining the times of maximum, and by the effects of cycle-to-cycle period fluctuations. As a result, the (O-C) method is generally not effective for these stars. We also describe the Mentorship Program and its elements, and reflect on the students' experience.

  20. Probing the mass-loss history of AGB and red supergiant stars from CO rotational line profiles. II. CO line survey of evolved stars: derivation of mass-loss rate formulae

    NASA Astrophysics Data System (ADS)

    De Beck, E.; Decin, L.; de Koter, A.; Justtanont, K.; Verhoelst, T.; Kemper, F.; Menten, K. M.

    2010-11-01

    Context. The evolution of intermediate and low-mass stars on the asymptotic giant branch is dominated by their strong dust-driven winds. More massive stars evolve into red supergiants with a similar envelope structure and strong wind. These stellar winds are a prime source for the chemical enrichment of the interstellar medium. Aims: We aim to (1) set up simple and general analytical expressions to estimate mass-loss rates of evolved stars, and (2) from those calculate estimates for the mass-loss rates of the asymptotic giant branch, red supergiant, and yellow hypergiant stars in our galactic sample. Methods: The rotationally excited lines of carbon monoxide (CO) are a classic and very robust diagnostic in the study of circumstellar envelopes. When sampling different layers of the circumstellar envelope, observations of these molecular lines lead to detailed profiles of kinetic temperature, expansion velocity, and density. A state-of-the-art, nonlocal thermal equilibrium, and co-moving frame radiative transfer code that predicts CO line intensities in the circumstellar envelopes of late-type stars is used in deriving relations between stellar and molecular-line parameters, on the one hand, and mass-loss rate, on the other. These expressions are applied to our extensive CO data set to estimate the mass-loss rates of 47 sample stars. Results: We present analytical expressions for estimating the mass-loss rates of evolved stellar objects for 8 rotational transitions of the CO molecule and thencompare our results to those of previous studies. Our expressions account for line saturation and resolving of the envelope, thereby allowing accurate determination of very high mass-loss rates. We argue that, for estimates based on a single rotational line, the CO(2-1) transition provides the most reliable mass-loss rate. The mass-loss rates calculated for the asympotic giant branch stars range from 4 10-8 M? yr-1 up to 8 10-5 M? yr-1. For red supergiants they reach values between 2 10-7 M? yr-1 and 3 10-4 M? yr-1. The estimates for the set of CO transitions allow time variability to be identified in the mass-loss rate. Possible mass-loss-rate variability is traced for 7 of the sample stars. We find a clear relation between the pulsation periods of the asympotic giant branch stars and their derived mass-loss rates, with a levelling off at ~3 10-5 M? yr-1 for periods exceeding 850 days. Conclusions: Appendices are only available in electronic form at http://www.aanda.org

  1. An HST COS "SNAPshot" Spectrum of the K Supergiant λ Vel (K4Ib-II)

    NASA Astrophysics Data System (ADS)

    Carpenter, Kenneth G.; Ayres, Thomas R.; Harper, Graham M.; Kober, Gladys; Nielsen, Krister E.; Wahlgren, Glenn M.

    2014-10-01

    We present a far-ultraviolet spectrum of the K4 Ib-II supergiant λ Vel obtained with the Hubble Space Telescope's Cosmic Origins Spectrograph (COS) as a part of the SNAPshot program "SNAPing coronal iron" (GO 11687). The observation covers a wavelength region (1326-1467 Å) not previously recorded for λ Vel at a spectral resolving power of R ~ 20,000 and displays strong emission and absorption features, superposed on a bright chromospheric continuum. Fluorescent excitation is responsible for much of the observed emission, mainly powered by strong H I Lyα and the O I (UV 2) triplet emission near λ1304. The molecular CO and H2 fluorescences are weaker than in the early-K giant α Boo while the Fe II and Cr II lines, also pumped by H I Lyα, are stronger in λ Vel. This pattern of relative line strengths between the two stars is explained by the lower iron-group element abundance in α Boo, which weakens that star's Fe II and Cr II emission without reducing the molecular fluorescences. The λ Vel spectrum shows fluorescent Fe II, Cr II, and H2 emission similar to that observed in the M supergiant α Ori, but more numerous well-defined narrow emissions from CO. The additional CO emissions are visible in the spectrum of λ Vel since that star does not have the cool, opaque circumstellar shells that surround α Ori and produce broad circumstellar CO (A-X) band absorptions that hide those emissions in the cooler star. The presence of Si IV emission in λ Vel indicates a ~8 × 104 K plasma that is mixed into the cooler chromosphere. Evidence of the stellar wind is seen in the C II λλ1334,1335 lines and in the blueshifted Fe II and Ni II wind absorption lines. Line modeling using Sobolev with Exact Integration for the C II lines indicates a larger terminal velocity (~45 versus ~30 km s-1) and turbulence (~27 versus <21 km s-1) with a more quickly accelerating wind (β = 0.35 versus 0.7) at the time of this COS observation in 2010 than derived from Goddard High Resolution Spectrograph data obtained in 1994. The Fe II and Ni II absorptions are blueshifted by 7.6 km s-1 relative to the chromospheric emission, suggesting formation in lower levels of the accelerating wind and their widths indicate a higher turbulence in the λ Vel wind compared to α Ori. Based on observations with the NASA/ESA Hubble Space Telescope obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Incorporated, under NASA contract NAS5-26555.

  2. New spectroscopic and polarimetric observations of the A0 supergiant HD 92207

    NASA Astrophysics Data System (ADS)

    Hubrig, S.; Kholtygin, A. F.; Schller, M.; Anderson, R. I.; Saesen, S.; Gonzlez, J. F.; Ilyin, I.; Briquet, M.

    2015-02-01

    Our recent search for the presence of a magnetic field in the bright early A-type supergiant HD 92207 using FORS 2 in spectropolarimetric mode revealed the presence of a longitudinal magnetic field of the order of a few hundred Gauss. However, the definite confirmation of the magnetic nature of this object remained pending due to the detection of short-term spectral variability probably affecting the position of line profiles in left- and right-hand polarized spectra. We present new magnetic field measurements of HD 92207 obtained on three different epochs in 2013 and 2014 using FORS 2 in spectropolarimetric mode. A 3? detection of the mean longitudinal magnetic field using the entire spectrum, _all=10434 G, was achieved in observations obtained in 2014 January. At this epoch, the position of the spectral lines appeared stable. Our analysis of spectral line shapes recorded in opposite circularly polarized light, i.e. in light with opposite sense of rotation, reveals that line profiles in the light polarized in a certain direction appear slightly split. The mechanism causing such a behaviour in the circularly polarized light is currently unknown. Trying to settle the issue of short-term variability, we searched for changes in the spectral line profiles on a time scale of 8-10 min using HARPS polarimetric spectra and on a time scale of 3-4 min using time series obtained with the CORALIE spectrograph. No significant variability was detected on these time scales during the epochs studied. Based on observations collected with the CORALIE echelle spectrograph mounted on the 1.2-m Swiss telescope at La Silla Observatory, data obtained at the European Southern Observatory (ESO Prg. 092.D-0209(A), and data obtained from the ESO Science Archive Facility under request MSCHOELLER 102067).

  3. Dense Molecular Clumps Associated with the Large Magellanic Cloud Supergiant Shells LMC 4 and LMC 5

    NASA Astrophysics Data System (ADS)

    Fujii, Kosuke; Minamidani, Tetsuhiro; Mizuno, Norikazu; Onishi, Toshikazu; Kawamura, Akiko; Muller, Erik; Dawson, Joanne; Tatematsu, Ken'ichi; Hasegawa, Tetsuo; Tosaki, Tomoka; Miura, Rie E.; Muraoka, Kazuyuki; Sakai, Takeshi; Tsukagoshi, Takashi; Tanaka, Kunihiko; Ezawa, Hajime; Fukui, Yasuo

    2014-12-01

    We investigate the effects of supergiant shells (SGSs) and their interaction on dense molecular clumps by observing the Large Magellanic Cloud (LMC) star-forming regions N48 and N49, which are located between two SGSs, LMC 4 and LMC 5. 12CO (J = 3-2, 1-0) and 13CO(J = 1-0) observations with the ASTE and Mopra telescopes have been carried out toward these regions. A clumpy distribution of dense molecular clumps is revealed with 7 pc spatial resolution. Large velocity gradient analysis shows that the molecular hydrogen densities (n(H2)) of the clumps are distributed from low to high density (103-105 cm-3) and their kinetic temperatures (T kin) are typically high (greater than 50 K). These clumps seem to be in the early stages of star formation, as also indicated from the distribution of H?, young stellar object candidates, and IR emission. We found that the N48 region is located in the high column density H I envelope at the interface of the two SGSs and the star formation is relatively evolved, whereas the N49 region is associated with LMC 5 alone and the star formation is quiet. The clumps in the N48 region typically show high n(H2) and T kin, which are as dense and warm as the clumps in LMC massive cluster-forming areas (30 Dor, N159). These results suggest that the large-scale structure of the SGSs, especially the interaction of two SGSs, works efficiently on the formation of dense molecular clumps and stars.

  4. Dense molecular clumps associated with the Large Magellanic Cloud supergiant shells LMC 4 and LMC 5

    SciTech Connect

    Fujii, Kosuke; Mizuno, Norikazu; Minamidani, Tetsuhiro; Onishi, Toshikazu; Muraoka, Kazuyuki; Kawamura, Akiko; Muller, Erik; Tatematsu, Ken'ichi; Hasegawa, Tetsuo; Miura, Rie E.; Ezawa, Hajime; Dawson, Joanne; Tosaki, Tomoka; Sakai, Takeshi; Tsukagoshi, Takashi; Tanaka, Kunihiko; Fukui, Yasuo

    2014-12-01

    We investigate the effects of supergiant shells (SGSs) and their interaction on dense molecular clumps by observing the Large Magellanic Cloud (LMC) star-forming regions N48 and N49, which are located between two SGSs, LMC 4 and LMC 5. {sup 12}CO (J = 3-2, 1-0) and {sup 13}CO(J = 1-0) observations with the ASTE and Mopra telescopes have been carried out toward these regions. A clumpy distribution of dense molecular clumps is revealed with 7 pc spatial resolution. Large velocity gradient analysis shows that the molecular hydrogen densities (n(H{sub 2})) of the clumps are distributed from low to high density (10{sup 3}-10{sup 5} cm{sup 3}) and their kinetic temperatures (T {sub kin}) are typically high (greater than 50 K). These clumps seem to be in the early stages of star formation, as also indicated from the distribution of H?, young stellar object candidates, and IR emission. We found that the N48 region is located in the high column density H I envelope at the interface of the two SGSs and the star formation is relatively evolved, whereas the N49 region is associated with LMC 5 alone and the star formation is quiet. The clumps in the N48 region typically show high n(H{sub 2}) and T {sub kin}, which are as dense and warm as the clumps in LMC massive cluster-forming areas (30 Dor, N159). These results suggest that the large-scale structure of the SGSs, especially the interaction of two SGSs, works efficiently on the formation of dense molecular clumps and stars.

  5. ASPHERICAL CORE-COLLAPSE SUPERNOVAE IN RED SUPERGIANTS POWERED BY NONRELATIVISTIC JETS

    SciTech Connect

    Couch, Sean M.; Wheeler, J. Craig; Milosavljevic, Milos

    2009-05-01

    We explore the observational characteristics of jet-driven supernovae (SNe) by simulating bipolar-jet-driven explosions in a red supergiant (RSG) progenitor. We present results of four models in which we hold the injected kinetic energy at a constant 10{sup 51} erg across all jet models but vary the specific characteristics of the jets to explore the influence of the nature of jets on the structure of the SN ejecta. We evolve the explosions past shock-breakout and into quasi-homologous expansion of the SN envelope into a RSG wind. The simulations have sufficient numerical resolution to study the stability of the flow. Our simulations show the development of fluid instabilities that produce pristine helium clumps in the hydrogen envelope. The oppositely directed, nickel-rich jets give a large-scale asymmetry that may account for the nonspherical excitation and substructure of spectral lines such as H{alpha} and He I 10830 A. Jets with a large fraction of kinetic to thermal energy punch through the progenitor envelope and give rise to explosions that would be observed to be asymmetric from the earliest epochs, inconsistent with spectropolarimetric measurements of Type II SNe. Jets with higher thermal energy fractions result in explosions that are roughly spherical at large radii but are significantly elongated at smaller radii, deep inside the ejecta, in agreement with the polarimetric observations. We present shock-breakout light curves that indicate that strongly aspherical shock breakouts are incompatible with recent Galaxy Evolution Explorer observations of shock breakout from RSG stars. Comparison with observations indicates that jets must deposit their kinetic energy efficiently throughout the ejecta while in the hydrogen envelope. Thermal-energy-dominated jets satisfy this criterion and yield many of the observational characteristics of Type II SNe.

  6. IGR J16328-4726: A NEW CANDIDATE SUPERGIANT FAST X-RAY TRANSIENT

    SciTech Connect

    Fiocchi, M.; Bazzano, A.; Natalucci, L.; Ubertini, P.; Sguera, V.; Bassani, L.; Bird, A. J.

    2010-12-10

    The unidentified source IGR J16328-4726 was covered with INTEGRAL observations for a long period ({approx}9.8 Ms) and was undetectable for most of the time while showing a very recurrent micro-activity with a duration from tens of minutes to several hours. We report the discovery of two strong outbursts started at 53420.65 MJD and 54859.99 MJD, respectively, the first with a duration of {approx}1 hr and the second with a lower limit on the duration of {approx}3.5 hr. Furthermore, the sources have been detected in nine other short pointings with significance between 4{sigma} and 5{sigma} as well as in one of the revolutions (during the exposure {approx}130 ks) at a significance level of {approx}7{sigma}. The stronger outburst spectrum is well described by a power-law model with a photon index of {approx}2.0 and a flux of {approx}3.3 x10{sup -10} erg cm{sup -2} s{sup -1} in the 20-50 keV energy band. The weaker outburst and revolution spectra show the same spectral shape and different fluxes. The combined timing and spectral properties observed during the outburst, the recurrent nature of this transient source, the Galactic plane location, a dynamic range >170 in the 0.3-10 keV band and >165 in the 20-50 keV, and the presence of an IR star in the error circle of a Swift X-ray Telescope pointing are suggesting this source as a member of the class of the supergiant fast X-ray transients.

  7. RED SUPERGIANT STARS IN THE LARGE MAGELLANIC CLOUD. I. THE PERIOD-LUMINOSITY RELATION

    SciTech Connect

    Yang Ming; Jiang, B. W. E-mail: bjiang@bnu.edu.cn

    2011-01-20

    From previous samples of red supergiants (RSGs) by various groups, 191 objects are assembled to compose a large sample of RSG candidates in LMC. For 189 of them, the identity as an RSG is verified by their brightness and color indexes in several near- and mid-infrared bands related to the Two Micron All Sky Survey (2MASS) JHK{sub S} bands and the Spitzer/IRAC and Spitzer/MIPS bands. From the visual time-series photometric observations by the ASAS and MACHO projects which cover nearly 8-10 years, the period and amplitude of light variation are analyzed carefully using both the phase dispersion minimization and Period04 methods. According to the properties of light variation, these objects are classified into five categories: (1) 20 objects are saturated in photometry or located in crowded stellar field with poor photometric results, (2) 35 objects with too complex variation to have any certain period, (3) 23 objects with irregular variation, (4) 16 objects with semi-regular variation, and (5) 95 objects with long secondary period (LSP) among which 31 have distinguishable short period and 51 have a long period shorter than 3000 days that can be determined with reasonable accuracy. For the semi-regular variables and the LSP variables with distinguishable short periods, the period-luminosity (P-L) relation is analyzed in the visual, near-infrared, and mid-infrared bands. It is found that the P-L relation is tight in the infrared bands such as the 2MASS JHK{sub S} bands and the Spitzer/IRAC bands, in particular in the Spitzer/IRAC [3.6] and [4.5] bands; meanwhile, the P-L relation is relatively sparse in the V band which may be caused by inhomogeneous interstellar extinction. The results are compared with others' P-L relationships for RSGs and the P-L sequences of red giants in LMC.

  8. A NEW DISTANCE TO M33 USING BLUE SUPERGIANTS AND THE FGLR METHOD

    SciTech Connect

    U, Vivian; Urbaneja, Miguel A.; Kudritzki, Rolf-Peter; Jacobs, Bradley A.; Bresolin, Fabio; Przybilla, Norbert E-mail: urbaneja@ifa.hawaii.ed E-mail: bjacobs@ifa.hawaii.ed E-mail: przybilla@sternwarte.uni-erlangen.d

    2009-10-20

    The quantitative spectral analysis of medium resolution optical spectra of A and B supergiants obtained with DEIMOS and ESI at the Keck Telescopes is used to determine a distance modulus of 24.93 +- 0.11 mag (968 +- 50 kpc) for the Triangulum Galaxy M33. The analysis yields stellar effective temperatures, gravities, interstellar reddening, and extinction, the combination of which provides a distance estimate via the flux-weighted gravity-luminosity relationship (FGLR). This result is based on an FGLR calibration that is continually being polished. An average reddening of (E(B - V)) approx 0.08 mag is found, with a large variation ranging from 0.01 to 0.16 mag, however, demonstrating the importance of accurate individual reddening measurements for stellar distance indicators in galaxies with evident signatures of interstellar absorption. The large-distance modulus found is in good agreement with recent work on eclipsing binaries, planetary nebulae, long-period variables, RR Lyrae stars, and also with Hubble Space Telescope (HST) observations of Cepheids, if reasonable reddening assumptions are made for the Cepheids. Since distances based on the tip of the red giant branch (TRGB) method found in the literature give conflicting results, we have used HST Advanced Camera for Surveys V- and I-band images of outer regions of M33 to determine a TRGB distance of 24.84 +- 0.10 mag, in basic agreement with the FGLR result. We have also determined stellar metallicities and discussed the metallicity gradient in the disk of M33. We find metallicity of Z {sub sun} at the center and 0.3 Z {sub sun} in the outskirts at a distance of one isophotal radius. The average logarithmic metallicity gradient is -0.07 +- 0.01 dex kpc{sup -1}. However, there is a large scatter around this average value, very similar to what has been found for the H II regions in M33.

  9. X-ray observation of the shocked red supergiant wind of Cassiopeia A

    SciTech Connect

    Lee, Jae-Joon; Park, Sangwook; Hughes, John P.; Slane, Patrick O.

    2014-07-01

    Cas A is a Galactic supernova remnant whose supernova explosion is observed to be of Type IIb from spectroscopy of its light echo. Having its SN type known, observational constraints on the mass-loss history of Cas A's progenitor can provide crucial information on the final fate of massive stars. In this paper, we study X-ray characteristics of the shocked ambient gas in Cas A using the 1 Ms observation carried out with the Chandra X-Ray Observatory and try to constrain the mass-loss history of the progenitor star. We identify thermal emission from the shocked ambient gas along the outer boundary of the remnant. Comparison of measured radial variations of spectroscopic parameters of the shocked ambient gas to the self-similar solutions of Chevalier show that Cas A is expanding into a circumstellar wind rather than into a uniform medium. We estimate a wind density n {sub H} ∼ 0.9 ± 0.3 cm{sup –3} at the current outer radius of the remnant (∼3 pc), which we interpret as a dense slow wind from a red supergiant (RSG) star. Our results suggest that the progenitor star of Cas A had an initial mass around 16 M {sub ☉}, and its mass before the explosion was about 5 M {sub ☉}, with uncertainties of several tens of percent. Furthermore, the results suggest that, among the mass lost from the progenitor star (∼11 M {sub ☉}), a significant amount (more than 6 M {sub ☉}) could have been via its RSG wind.

  10. The chromosphere of VV cephei and the distribution of circumstellar dust around red giants and supergiants

    NASA Technical Reports Server (NTRS)

    Bauer, Wendy Hagen

    1992-01-01

    The work on this project has followed two separate paths of inquiry. The first project was entitled 'the Chromosphere of VV Cephei.' The examination of the archival spectra revealed significant changes in the spectra. Therefore, we obtained additional observing time with IUE to monitor the system during the summer of 1991. Short-term changes continue to be seen in both the overall spectrum and individual line profiles. Work continues on this object. The second project was entitled 'the Distribution of Circumstellar Dust around Red Giants and Supergiants.' A number of cool evolved stars are surrounded by dust shells of sufficient angular size as to appear extended in the IRAS survey data. The aim of this project has been to convolve the predictions of the flux distribution from model dust shells with the IRAS beam profiles in order to reproduce the observed IRAS scans. At the time of the last status report, the cross-scan profiles of the IRAS detectors had just been added to the modeling procedure. For scans in which the star passed near the detector center, there was no significant variation in predicted scan profile for different detectors. Scans in which the detector did not pass over the bright central star had been anticipated to be particularly useful in determining the dust distribution; however, significant differences in the predicted scan profiles were seen for different detector profiles. For this reason, and due to the cross-talk effects discussed in the previous status report, further work on the scans not including a central star has been postponed in favor of further analysis of scans passing over the central star.

  11. Radio continuum emission from winds, chromospheres, and coronae of cool giants and supergiants

    SciTech Connect

    Drake, S.A.; Linsky, J.L.

    1986-03-01

    In this paper we present the results of a sensitive VLA radio continuum survey at 6 cm of 39 of the nearest, single cool giants and supergiants with spectral types in the range G0--M5. We discuss our findings in the context of the various mechanisms that might be producing radio emission in these cool stars. We have definitely detected four K and M giants ( Her, Boo, rho Per, and Gem) and probably detected a fifth ( US UMi) at flux levels of 0.1--1.0 mJy. We believe that in all five of these cases the radio emission is thermal emission from cool stellar winds. We have made additional 2 cm observations of several stars, including the four stars definitely detected at 6 cm. We have derived spectral indices for Boo, Her, and rho Per of 0.80, 0.84, and 0.95, respectively, that are close to the 0.6 value predicted by standard stellar wind models in the optically thick regime. An additional cool giant ( Tau) was detected only at 2 cm, implying a spectral index of > or =0.87. None of the coronal or hybrid-chromosphere giants observed were detected in this study, with the exception of Aur, a 0.2 mJy radio source at 6 cm, which is in fact a widely separated, long-period (P/sub orb/approx.104/sup d/) RS CVn system containing two cool giant stars. In this case, we believe that the 6 cm radio emission is optically thin, thermal emission from the corona(e) of one or both of the components, since the radio-emission measure is consistent with that of the observed x-ray emission.

  12. Exploring jet-launching conditions for supergiant fast X-ray transients

    NASA Astrophysics Data System (ADS)

    Garca, Federico; Aguilera, Deborah N.; Romero, Gustavo E.

    2014-05-01

    Context. In the magneto-centrifugal mechanism for jet formation, accreting neutron stars are assumed to produce relativistic jets only if their surface magnetic field is weak enough (B ~ 108 G). However, the most common manifestation of neutron stars are pulsars, whose magnetic field distribution peaks at B ~ 1012 G. If the neutron star magnetic field has at least this strength at birth, it must decay considerably before jets can be launched in binary systems. Aims: We study the magnetic field evolution of a neutron star that accretes matter from the wind of a high-mass stellar companion so that we can constrain the accretion rate and the impurities in the crust, which are necessary conditions for jet formation. Methods: We solved the induction equation for the diffusion and convection of the neutron star magnetic field confined to the crust, assuming spherical accretion in a simpliflied one-dimensional treatment. We incorporated state-of-the-art microphysics, including consistent thermal evolution profiles, and assumed two different neutron star cooling scenarios based on the superfluidity conditions at the core. Results: We find that in this scenario, magnetic field decay at long timescales is governed mainly by the accretion rate, while the impurity content and thermal evolution of the neutron star play a secondary role. For accretion rates ? ? 10-10 M? yr-1, surface magnetic fields can decay up to four orders of magnitude in ~107 yr, which is the timescale imposed by the evolution of the high-mass stellar companion in these systems. Based on these results, we discuss the possibility of transient jet-launching in strong wind-accreting high-mass binary systems like supergiant fast X-ray transients.

  13. Chemistry and Kinematics of Red Supergiant Stars in the Young Massive Cluster NGC 2100

    NASA Astrophysics Data System (ADS)

    Patrick, L. R.; Evans, C. J.; Davies, B.; Kudritzki, R.-P.; Hénault-Brunet, V.; Bastian, N.; Lapenna, E.; Bergemann, M.

    2016-03-01

    We have obtained K-band Multi-Object Spectrograph (KMOS) near-IR spectroscopy for 14 red supergiant stars (RSGs) in the young massive star cluster NGC 2100 in the Large Magellanic Cloud (LMC). Stellar parameters including metallicity are estimated using the J-band analysis technique, which has been rigorously tested in the Local Universe. We find an average metallicity for NGC 2100 of [Z] = -0.43 ± 0.10 dex, in good agreement with estimates from the literature for the LMC. Comparing our results in NGC 2100 with those for a Galactic cluster (at Solar-like metallicity) with a similar mass and age we find no significant difference in the location of RSGs in the Hertzsprung-Russell diagram. We combine the observed KMOS spectra to form a simulated integrated-light cluster spectrum and show that, by analysing this spectrum as a single RSG, the results are consistent with the average properties of the cluster. Radial velocities are estimated for the targets and the dynamical properties are estimated for the first time within this cluster. The data are consistent with a flat velocity dispersion profile, and with an upper limit of 3.9 kms-1, at the 95% confidence level, for the velocity dispersion of the cluster. However, the intrinsic velocity dispersion is unresolved and could, therefore, be significantly smaller than the upper limit reported here. An upper limit on the dynamical mass of the cluster is derived as Mdyn ≤ 15.2 × 104M⊙ assuming virial equilibrium.

  14. ISOLATED WOLF-RAYET STARS AND O SUPERGIANTS IN THE GALACTIC CENTER REGION IDENTIFIED VIA PASCHEN-{alpha} EXCESS

    SciTech Connect

    Mauerhan, J. C.; Stolovy, S. R.; Cotera, A.; Dong, H.; Wang, Q. D.; Morris, M. R.; Lang, C.

    2010-12-10

    We report the discovery of 19 hot, evolved, massive stars near the Galactic center region (GCR). These objects were selected for spectroscopy owing to their detection as strong sources of Paschen-{alpha} (P{alpha}) emission-line excess, following a narrowband imaging survey of the central 0.{sup 0}65 x 0.{sup 0}25 (l, b) around Sgr A* with the Hubble Space Telescope. Discoveries include six carbon-type (WC) and five nitrogen-type (WN) Wolf-Rayet stars, six O supergiants, and two B supergiants. Two of the O supergiants have X-ray counterparts having properties consistent with solitary O stars and colliding-wind binaries. The infrared photometry of 17 stars is consistent with the Galactic center distance, but 2 of them are located in the foreground. Several WC stars exhibit a relatively large infrared excess, which is possibly thermal emission from hot dust. Most of the stars appear scattered throughout the GCR, with no relation to the three known massive young clusters; several others lie near the Arches and Quintuplet clusters and may have originated within one of these systems. The results of this work bring the total sample of Wolf-Rayet (WR) stars in the GCR to 88. All sources of strong P{alpha} excess have been identified in the area surveyed with HST, which implies that the sample of WN stars in this region is near completion, and is dominated by late (WNL) types. The current WC sample, although probably not complete, is almost exclusively dominated by late (WCL) types. The observed WR subtype distribution in the GCR is a reflection of the intrinsic rarity of early subtypes (WNE and WCE) in the inner Galaxy, an effect that is driven by metallicity.

  15. Coronal Temperature and Emission Measure Distributions for he Active G Supergiant Beta Dra and other ASCA Projects

    NASA Technical Reports Server (NTRS)

    Brown, Alexander

    1998-01-01

    This NASA grant supported my ASCA observing and data analysis programs during AOs 1-4. This research involved four Guest Observer projects. Analysis of data from all four programs has been completed. This grant included the following ASCA GO programs: AO1 - "Coronal Temperature and Emission Measure Distributions for the Active G Supergiant Beta Dra" AO2 - "Contemporaneous ASCA, EUVE, IUE, and VLA/AT Observations of Atmospheric Structure of the RS CVn Binary HR1099". AO3 - "Coronal Temperature and Emission Measure Distributions for the hybrid-chromosphere star alpha TrA". AO4-"Activity on the edge of convection: The atmosphere of Canopus (alpha Car, FO Ib-II)".

  16. Cold gas in hot star clusters: the wind from the red supergiant W26 in Westerlund 1

    NASA Astrophysics Data System (ADS)

    Mackey, Jonathan; Castro, Norberto; Fossati, Luca; Langer, Norbert

    2015-10-01

    The massive red supergiant W26 in Westerlund 1 is one of a growing number of red supergiants shown to have winds that are ionized from the outside in. The fate of this dense wind material is important for models of second generation star formation in massive star clusters. Mackey et al. (2014, Nature, 512, 282) showed that external photoionization can stall the wind of red supergiants and accumulate mass in a dense static shell. We use spherically symmetric radiation-hydrodynamic simulations of an externally photoionized wind to predict the brightness distribution of Hα and [N II] emission arising from photoionized winds both with and without a dense shell. We analyse spectra of the Hα and [N II] emission lines in the circumstellar environment around W26 and compare them with simulations to investigate whether W26 has a wind that is confined by external photoionization. Simulations of slow winds that are decelerated into a dense shell show strongly limb-brightened line emission, with line radial velocities that are independent of the wind speed. Faster winds (≳22 km s-1) do not form a dense shell, have less limb-brightening, and the line radial velocity is a good tracer of the wind speed. The brightness of the [N II] and Hα lines as a function of distance from W26 agrees reasonably well with observations when only the line flux is considered. The radial velocity of the simulated winds disagrees with observations, however: the brightest observed emission is blueshifted by ≈25 km s-1 relative to the radial velocity of the star, whereas a spherically symmetric wind has the brightest emission at zero radial velocity because of limb brightening. Our results show that the bright nebula surrounding W26 must be asymmetric, and we suggest that it is confined by external ram pressure from the extreme wind of the nearby supergiant W9. We obtain a lower limit on the nitrogen abundance within the nebula of 2.35 times solar. The line ratio strongly favours photoionization over shock ionization, and so even if the observed nebula is pressure confined there should still be an ionization front and a photoionization-confined shell closer to the star that is not resolved by the current observations, which could be tested with better spectral resolution and spatial coverage. Appendices are available in electronic form at http://www.aanda.org

  17. The identification of extreme asymptotic giant branch stars and red supergiants in M33 with 24 μm variability

    SciTech Connect

    Montiel, Edward J.; Clayton, Geoffrey C.; Johnson, Christopher B.; Srinivasan, Sundar; Engelbracht, Charles W.

    2015-02-01

    We present the first detection of 24 μm variability in 24 sources in the Local Group galaxy M33. These results are based on 4 epochs of Multiband Imaging Photometer for Spitzer observations, which are irregularly spaced over ∼750 days. We find that these sources are constrained exclusively to the Holmberg radius of the galaxy, which increases their chances of being members of M33. We have constructed spectral energy distributions (SEDs) ranging from the optical to the submillimeter to investigate the nature of these objects. We find that 23 of our objects are most likely heavily self-obscured, evolved stars, while the remaining source is the Giant H ii region, NGC 604. We believe that the observed variability is the intrinsic variability of the central star reprocessed through their circumstellar dust shells. Radiative transfer modeling was carried out to determine their likely chemical composition, luminosity, and dust production rate (DPR). As a sample, our modeling has determined an average luminosity of (3.8±0.9)×10{sup 4} L{sub ⊙} and a total DPR of (2.3±0.1)×10{sup −5} M{sub ⊙} yr{sup −1}. Most of the sources, given the high DPRs and short wavelength obscuration, are likely extreme asymptotic giant branch (XAGB) stars. Five of the sources are found to have luminosities above the classical AGB limit (M{sub bol} <−7.1 mag, L > 54,000 L{sub ⊙}), which classifies them as probable red supergiants (RSGs). Almost all of the sources are classified as oxygen-rich. As also seen in the LMC, a significant fraction of the dust in M33 is produced by a handful of XAGB and RSG stars.

  18. Integral-Field Spectroscopy of the Post-Red Supergiant IRC +10420: Evidence for an Axisymmetric Wind

    NASA Astrophysics Data System (ADS)

    Davies, Ben; Oudmaijer, Ren D.; Sahu, Kailash C.

    2007-12-01

    We present NAOMI/OASIS adaptive-optics-assisted integral-field spectroscopy of the transitional massive hypergiant IRC +10420, an extreme mass-losing star apparently in the process of evolving from a red supergiant toward the Wolf-Rayet phase. To investigate the present-day mass-loss geometry of the star, we study the appearance of the line emission from the inner wind as viewed when reflected off the surrounding nebula. We find that, contrary to previous work, there is strong evidence for wind axisymmetry, based on the equivalent width and velocity variations of H? and Fe II ?6516. We attribute this behavior to the appearance of the complex line profiles when viewed from different angles. We also speculate that the Ti II emission originates in the outer nebula in a region analogous to the strontium filament of ? Carinae, based on the morphology of the line emission. Finally, we suggest that the present-day axisymmetric wind of IRC +10420, combined with its continued blueward evolution, is evidence that the star is evolving toward the B[e] supergiant phase.

  19. Giant outburst from the supergiant fast X-ray transient IGR J17544-2619: accretion from a transient disc?

    NASA Astrophysics Data System (ADS)

    Romano, P.; Bozzo, E.; Mangano, V.; Esposito, P.; Israel, G.; Tiengo, A.; Campana, S.; Ducci, L.; Ferrigno, C.; Kennea, J. A.

    2015-04-01

    Supergiant fast X-ray transients (SFXTs) are high mass X-ray binaries associated with OB supergiant companions and characterized by an X-ray flaring behaviour whose dynamical range reaches 5 orders of magnitude on time scales of a few hundred to thousands of seconds. Current investigations concentrate on finding possible mechanisms to inhibit accretion in SFXTs and to explain their unusually low average X-ray luminosity. We present the Swift observations of an exceptionally bright outburst displayed by the SFXT IGR J17544-2619 on 2014 October 10 when the source achieved a peak luminosity of 3 1038 erg s-1. This extends the total source dynamic range to ?106, the largest (by a factor of 10) recorded so far from an SFXT. Tentative evidence for pulsations at a period of 11.6 s is also reported. We show that these observations challenge, for the first time, the maximum theoretical luminosity achievable by an SFXT and propose that this giant outburst was due to the formation of a transient accretion disc around the compact object. Tables 1 and 2, and Fig. 2 are available in electronic form at http://www.aanda.org

  20. DISCOVERY OF A POSSIBLY SINGLE BLUE SUPERGIANT STAR IN THE INTRA-CLUSTER REGION OF VIRGO CLUSTER OF GALAXIES

    SciTech Connect

    Ohyama, Youichi; Hota, Ananda

    2013-04-20

    IC 3418 is a dwarf irregular galaxy falling into the Virgo cluster, and a 17 kpc long trail is seen behind the galaxy, which is considered to have formed due to ram pressure stripping. The trail contains compact knots and diffuse blobs of ultraviolet and blue optical emission and, thus, it is a clear site of recent star formation but in an unusual environment, surrounded by a million degree intra-cluster medium. We report on our optical spectroscopy of a compact source in the trail, SDSS J122952.66+112227.8, and show that the optical spectrum is dominated by emission from a massive blue supergiant star. If confirmed, our report would mark the farthest star with spectroscopic observation. We interpret that a massive O-type star formed in situ in the trail has evolved recently out of the main sequence into this blue supergiant phase, and now lacks any detectable spectral sign of its associated H II region. We argue that turbulence within the ram pressure striped gaseous trail may play a dominant role for the star formation within such trails.

  1. VLTI/AMBER Studies of the Atmospheric Structure and Fundamental Parameters of Red Giant and Supergiant Stars

    NASA Astrophysics Data System (ADS)

    Arroyo-Torres, B.; Wittkowski, M.; Marcaide, J. M.; Abellan, F. J.; Chiavassa, A.; Fabregat, J.; Freytag, B.; Guirado, J. C.; Hauschildt, P. H.; Marti-Vidal, I.; Quirrenbach, A.; Scholz, M.; Wood, P. R.

    2015-08-01

    We present recent near-IR interferometric studies of red giant and supergiant stars, which are aimed at obtaining information on the structure of the atmospheric layers and constraining the fundamental parameters of these objects. The observed visibilities of six red supergiants (RSGs), and also of one of the five red giants observed, indicate large extensions of the molecular layers, as previously observed for Mira stars. These extensions are not predicted by hydrostatic PHOENIX model atmospheres, hydrodynamical (RHD) simulations of stellar convection, or self-excited pulsation models. All these models based on parameters of RSGs lead to atmospheric structures that are too compact compared to our observations. We discuss how alternative processes might explain the atmospheric extensions for these objects. As the continuum appears to be largely free of contamination by molecular layers, we can estimate reliable Rosseland angular radii for our stars. Together with distances and bolometric fluxes, we estimate the effective temperatures and luminosities of our targets, locate them in the HR diagram, and compare their positions to recent evolutionary tracks.

  2. Swift-X-Ray Telescope Monitoring of the Candidate Supergiant Fast X-ray Transient IGR J16418-4532

    NASA Technical Reports Server (NTRS)

    Romano, P.; Mangano, V.; Ducci, L.; Esposito, P.; Evans, P. A.; Vercellone, S.; Kennea, J. A.; Burrows, D. N.; Gehrels, N.

    2012-01-01

    We report on the Swift monitoring of the candidate supergiant fast X-ray transient (SFXT) IGR J16418-4532, for which both orbital and spin periods are known (approx. 3.7 d and approx.1250 s, respectively). Our observations, for a total of approx. 43 ks, span over three orbital periods and represent the most intense and complete sampling of the light curve of this source with a sensitive X-ray instrument. With this unique set of observations, we can address the nature of this transient. By applying the clumpy wind model for blue supergiants to the observed X-ray light curve, and assuming a circular orbit, the X-ray emission from this source can be explained in terms of the accretion from a spherically symmetric clumpy wind, composed of clumps with different masses, ranging from approx. 5 × 10(exp 16) to 10(exp 21) g. Our data suggest, based on the X-ray behaviour, that this is an intermediate SFXT.

  3. Swift/XRT Monitoring of the Candidate Supergiant Fast X-ray Transient IGR J16418-4532

    NASA Technical Reports Server (NTRS)

    Romano, P.; Mangano, V.; Ducci, L.; Esposito, P.; Evans, P. A.; Vercellone, S.; Kennea, J. A.; Burrows, D. N.; Gehrels, N.

    2011-01-01

    We report on the Swift monitoring of the candidate supergiant fast X-ray transient (SFXT) IGR J16418.4532, for which both orbital and spin periods are known (approx. 3.7d and approx. 1250 s, respectively). Our observations, for a total of approx. 43 ks, span over three orbital periods and represent the most intense and complete sampling of the light curve of this source with a sensitive X-ray instrument. With this unique set of observations we can address the nature of this transient. By applying the clumpy wind model for blue supergiants to the observed X-ray light curve, and assuming a circular orbit, the X-ray emission from this source can be explained in terms of the accretion from a spherically symmetric clumpy wind, composed of clumps with different masses, ranging from 5 X 10(exp 16) g to 10(exp 21) g. Our data suggest, based on the X-ray behaviour, that this is an intermediate SFXT

  4. Pulsations in B-type supergiants with masses M<20 M_{?} before and after core helium ignition

    NASA Astrophysics Data System (ADS)

    Ostrowski, J.; Daszy?ska-Daszkiewicz, J.

    2015-03-01

    Evolutionary tracks and pulsational analysis of models with masses of 13-18 M? are presented. We address two important questions. The first one deals with one of the most unresolved problems in astrophysics, i.e. the existence of a blue loop after core helium ignition; the so-called to loop or not to loop problem. We show that inward overshooting from the outer convective zone in the red giant phase is prerequisite for the development of the blue loop. Our second question concerns pulsational instability of models in the core helium burning phase. We present for the first time that models on the blue loop can have unstable modes driven by the ? mechanism operating in the Z-bump. Contrary to post-main-sequence models in the shell hydrogen burning phases, pulsational instability of the blue loop models depends mainly on effective temperature and metallicity is of secondary importance. Finally, we try to interpret the oscillation spectrum of the blue supergiant HD 163899, the only member of the slowly pulsating B-type supergiant class and to get some clue on the evolutionary status of the star.

  5. Studies of Evolved Star Mass Loss: GRAMS Modeling of Red Supergiant and Asymptotic Giant Branch Stars in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Sargent, Benjamin A.; Srinivasan, S.; Riebel, D.; Boyer, M.; Meixner, M.

    2012-01-01

    As proposed in our NASA Astrophysics Data Analysis Program (ADAP) proposal, my colleagues and I are studying mass loss from evolved stars. Such stars lose their own mass in their dying stages, and in their expelled winds they form stardust. To model mass loss from these evolved stars, my colleagues and I have constructed GRAMS: the Grid of Red supergiant and Asymptotic giant branch star ModelS. These GRAMS radiative transfer models are fit to optical through mid-infrared photometry of red supergiant (RSG) stars and asymptotic giant branch (AGB) stars. I will discuss our current studies of mass loss from AGB and RSG stars in the Small Magellanic Cloud (SMC), fitting GRAMS models to the photometry of SMC evolved star candidates identified from the SAGE-SMC (PI: K. Gordon) Spitzer Space Telescope Legacy survey. This work will be briefly compared to similar work we have done for the LMC. I will also discuss Spitzer Infrared Spectrograph (IRS) studies of the dust produced by AGB and RSG stars in the LMC. BAS is grateful for support from the NASA-ADAP grant NNX11AB06G.

  6. Modelling Dusty Circumbinary Disk around B[e] Supergiant RY Sct

    NASA Astrophysics Data System (ADS)

    Men'shchikov, Alexander; Miroshnichenko, Anatoly

    2005-08-01

    The supergiant RY Sct is an eclipsing binary system with a fairly large infrared (IR) excess caused by the presence of circumbinary dust. Many strong forbidden lines ([O i], [N ii], [S iii], [Fe ii]), in combination with the near-IR excess, put it in the list of peculiar Be or B[e] stars. Although RY Sct is one of the best-studied systems, even its basic physical parameters remain unreliable. Recent IR images of the system, obtained with a 0.3 arcsec resolution at the 10-m Keck telescope, showed the dusty disk at the wavelengths 3-20 ?m and stimulated us to perform its detailed modelling using our 2-D radiative transfer code. Our model reproduces all available observations of RY Sct obtained during the last few decades. The modelling demonstrated that the observations cannot be described by a single model at one moment in time, implying rapid changes in the dusty disk during the last 20 years. Assuming that a temperature of 27,000 K describes both components of the binary and that its distance is 1.8 kpc, its total luminosity is 4.2 - 105 solar luminosity. The model disk has the optical depth of 0.04 and the opening angle of 26 (between the boundaries). Dust in the disk exists between 60 AU and 105 AU, where it blends into the interstellar medium. We observe the disk almost edge-on, at an angle of 14 to its midplane. The total mass of the disk is 0.017 solar mass. There is a strong density enhancement at 1800 AU from the binary, which emits most of the IR radiation and is prominent in the Keck telescope images. Presumably, the dense ring has been created by a fast wind that swept out and compressed the previously lost material in the older and slower stellar wind. Our model predicts that presently there is a large amount of small, hot dust grains in the dust formation zone, whose emission changed the shape of the SED of RY Sct in the near IR. The dust density must now be significantly greater in the dust formation zone, suggesting a much higher massloss rate or dust-to-gas mass ratio or much lower wind velocities than before, or a combination of these factors.

  7. X-ray, UV and optical analysis of supergiants: ɛ Ori

    NASA Astrophysics Data System (ADS)

    Puebla, Raul E.; Hillier, D. John; Zsargó, Janos; Cohen, David H.; Leutenegger, Maurice A.

    2016-03-01

    We present a multi-wavelength (X-ray to optical) analysis, based on non-local thermodynamic equilibrium photospheric+wind models, of the B0 Ia-supergiant: ɛ Ori. The aim is to test the consistency of physical parameters, such as the mass-loss rate and CNO abundances, derived from different spectral bands. The derived mass-loss rate is {dot {M}} / {√{f_{∞}}} {˜} 1.6 × 10-6 M⊙ yr-1 where f∞ is the volume filling factor. However, the S IV λλ1062,1073 profiles are too strong in the models; to fit the observed profiles it is necessary to use f∞ <0.01. This value is a factor of 5 to 10 lower than inferred from other diagnostics, and implies {dot{M}} ≲ 1 × 10^{-7} M⊙ yr-1. The discrepancy could be related to porosity-vorosity effects or a problem with the ionization of sulphur in the wind. To fit the UV profiles of N V and O VI it was necessary to include emission from an interclump medium with a density contrast (ρcl/ρICM) of ˜100. X-ray emission in H/He like and Fe L lines was modelled using four plasma components located within the wind. We derive plasma temperatures from 1 × 106 to 7 × 106 K, with lower temperatures starting in the outer regions (R0 ˜ 3-6 R*), and a hot component starting closer to the star (R0 ≲ 2.9 R*). From X-ray line profiles we infer {dot{M}} < 4.9 × 10-7 M⊙ yr-1. The X-ray spectrum (≥0.1 kev) yields an X-ray luminosity LX ˜ 2.0 × 10-7Lbol, consistent with the superion line profiles. X-ray abundances are in agreement with those derived from the UV and optical analysis: ɛ Ori is slightly enhanced in nitrogen and depleted in carbon and oxygen, evidence for CNO processed material.

  8. Wind Variability of B Supergiants. No. 2; The Two-component Stellar Wind of gamma Arae

    NASA Technical Reports Server (NTRS)

    Prinja, R. K.; Massa, D.; Fullerton, A. W.; Howarth, I. D.; Pontefract, M.

    1996-01-01

    The stellar wind of the rapidly rotating early-B supergiant, gamma Ara, is studied using time series, high-resolution IUE spectroscopy secured over approx. 6 days in 1993 March. Results are presented based on an analysis of several line species, including N(N), C(IV), Si(IV), Si(III), C(II), and Al(III). The wind of this star is grossly structured, with evidence for latitude-dependent mass loss which reflects the role of rapid rotation. Independent, co-existing time variable features are identified at low-velocity (redward of approx. -750 km/s) and at higher-speeds extending to approx. -1500 km/s. The interface between these structures is 'defined' by the appearance of a discrete absorption component which is extremely sharp (in velocity space). The central velocity of this 'Super DAC' changes only gradually, over several days, between approx. -400 and -750 km/s in most of the ions. However, its location is shifted redward by almost 400 km/s in Al(III) and C(II), indicating that the physical structure giving rise to this feature has a substantial velocity and ionization jump. Constraints on the relative ionization properties of the wind structures are discussed, together with results based on SEI line-profile-fitting methods. The overall wind activity in gamma Ara exhibits a clear ion dependence, such that low-speed features are promoted in low-ionization species, including Al(III), C(II), and Si(III). We also highlight that - in contrast to most OB stars - there are substantial differences in the epoch-to-epoch time-averaged wind profiles of gamma Ara. We interpret the results in terms of a two-component wind model for gamma Ara, with an equatorially compressed low ionization region, and a high speed, higher-ionization polar outflow. This picture is discussed in the context of the predicted bi-stability mechanism for line-driven winds in rapidly rotating early-B type stars, and the formation of compressed wind regions in rapidly rotating hot stars. The apparent absence of a substantial shift in the wind ionization mixture of gamma Ara, and the normal nature of its photospheric spectrum, suggests wind-compression as the likely dominant cause for the observed equatorial density enhancements.

  9. Synchrotron radiation from the winds of O supergiants - Tb = 10 to the 7. 6th K at 60 stellar radii

    SciTech Connect

    Phillips, R.B.; Titus, M.A. )

    1990-08-01

    Results are presented on VLBI measurements of the nonthermal radio components around two O supergiant stars: Cyg OB2 No. 9 and HD 167971. The measurements were used to characterize the brightness temperature of the emission and to measure the size of compact 5-10 mJy components in these stars, reported by Bieging et al. (1989). The sizes found for the 5-10 mJy components are consistent with the free-free wind radii, indicating that the compact companions are not the sources of nonthermal radiation. Results suggest that there is a small fractional population (10 to the -4th to 10 to the -7th) of ultrarelativistic electrons (Teff of about 10 to the 11th K) coexisting with the stellar wind, which emit optically thin synchrotron radiation. This is in agreement with the synchrotron model of White (1985). 21 refs.

  10. The supergiant amphipod Alicella gigantea (Crustacea: Alicellidae) from hadal depths in the Kermadec Trench, SW Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Jamieson, A. J.; Lacey, N. C.; Lrz, A.-N.; Rowden, A. A.; Piertney, S. B.

    2013-08-01

    Here we provide the first record of the 'supergiant' amphipod Alicella gigantea Chevreux, 1899 (Alicellidae) from the Southern Hemisphere, and extend the known bathymetric range by over 1000 m to 7000 m. An estimated nine individuals were observed across 1500 photographs taken in situ by baited camera at 6979 m in the Kermadec Trench, SW Pacific Ocean. Nine specimens, ranging in length from 102 to 290 mm were recovered by baited trap at depths of 6265 m and 7000 m. Mitochondrial and nuclear DNA sequences obtained indicate a cosmopolitan distribution for the species. Data and observations from the study are used to discuss the reason for gigantism in this species, and its apparently disjunct geographical distribution.

  11. Line-profile microvariability in OB-star spectra: the Supergiant λ Cep (O6If(n))

    NASA Astrophysics Data System (ADS)

    Kholtygin, A. F.; Sudnik, N. P.; Burlakova, T. E.; Valyavin, G. G.

    2011-12-01

    We observed the bright O6If(n) supergiant λ Cep in 1997 with the 6-m optical telescope of the Special Astrophysical Observatory and in 2007 with the 1.8-m telescope of the Bohyunsan Optical Astronomy Observatory (South Korea). A total of 90 spectra of the star were acquired, with good time resolution (10 minutes), signal-to-noise ratios 150-300, and spectral resolutions of 45 000-60 000. We detected line-profile variations of H, HeI, and HeII lines. It is suggested that the detected variations are due to non-radial photospheric pulsations and the star's rotation (rotational profile modulation).

  12. Einstein Observatory magnitude-limited X-ray survey of late-type giant and supergiant stars

    SciTech Connect

    Maggio, A.; Vaiana, G.S.; Haisch, B.M.; Stern, R.A.; Bookbinder, J. Lockheed Research Laboratories, Palo Alto, CA Joint Institute for Laboratory Astrophysics, Boulder, CO Smithsonian Astrophysical Observatory, Cambridge, MA )

    1990-01-01

    Results are presented of an extensive X-ray survey of 380 giant and supergiant stars of spectral types from F to M, carried out with the Einstein Observatory. It was found that the observed F giants or subgiants (slightly evolved stars with a mass M less than about 2 solar masses) are X-ray emitters at the same level of main-sequence stars of similar spectral type. The G giants show a range of emissions more than 3 orders of magnitude wide; some single G giants exist with X-ray luminosities comparable to RS CVn systems, while some nearby large G giants have upper limits on the X-ray emission below typical solar values. The K giants have an observed X-ray emission level significantly lower than F and F giants. None of the 29 M giants were detected, except for one spectroscopic binary. 79 refs.

  13. Einstein Observatory magnitude-limited X-ray survey of late-type giant and supergiant stars

    NASA Technical Reports Server (NTRS)

    Maggio, A.; Vaiana, G. S.; Haisch, B. M.; Stern, R. A.; Bookbinder, J.

    1990-01-01

    Results are presented of an extensive X-ray survey of 380 giant and supergiant stars of spectral types from F to M, carried out with the Einstein Observatory. It was found that the observed F giants or subgiants (slightly evolved stars with a mass M less than about 2 solar masses) are X-ray emitters at the same level of main-sequence stars of similar spectral type. The G giants show a range of emissions more than 3 orders of magnitude wide; some single G giants exist with X-ray luminosities comparable to RS CVn systems, while some nearby large G giants have upper limits on the X-ray emission below typical solar values. The K giants have an observed X-ray emission level significantly lower than F and F giants. None of the 29 M giants were detected, except for one spectroscopic binary.

  14. QUANTITATIVE SPECTROSCOPY OF BLUE SUPERGIANT STARS IN THE DISK OF M81: METALLICITY, METALLICITY GRADIENT, AND DISTANCE

    SciTech Connect

    Kudritzki, Rolf-Peter; Urbaneja, Miguel A.; Gazak, Zachary; Bresolin, Fabio; Przybilla, Norbert; Gieren, Wolfgang; Pietrzynski, Grzegorz E-mail: urbaneja@ifa.hawaii.edu E-mail: bresolin@ifa.hawaii.edu E-mail: wgieren@astro-udec.cl

    2012-03-01

    The quantitative spectral analysis of low-resolution ({approx}5 A) Keck LRIS spectra of blue supergiants in the disk of the giant spiral galaxy M81 is used to determine stellar effective temperatures, gravities, metallicities, luminosities, interstellar reddening, and a new distance using the flux-weighted gravity-luminosity relationship. Substantial reddening and extinction are found with E(B - V) ranging between 0.13 and 0.38 mag and an average value of 0.26 mag. The distance modulus obtained after individual reddening corrections is 27.7 {+-} 0.1 mag. The result is discussed with regard to recently measured tip of the red giant branch and Cepheid distances. The metallicities (based on elements such as iron, titanium, magnesium) are supersolar ( Almost-Equal-To 0.2 dex) in the inner disk (R {approx}< 5 kpc) and slightly subsolar ( Almost-Equal-To - 0.05 dex) in the outer disk (R {approx}> 10 kpc) with a shallow metallicity gradient of 0.034 dex kpc{sup -1}. The comparison with published oxygen abundances of planetary nebulae and metallicities determined through fits of Hubble Space Telescope color-magnitude diagrams indicates a late metal enrichment and a flattening of the abundance gradient over the last 5 Gyr. This might be the result of gas infall from metal-rich satellite galaxies. Combining these M81 metallicities with published blue supergiant abundance studies in the Local Group and the Sculptor Group, a galaxy mass-metallicity relationship based solely on stellar spectroscopic studies is presented and compared with recent studies of Sloan Digital Sky Survey star-forming galaxies.

  15. DISTANCE AND PROPER MOTION MEASUREMENT OF THE RED SUPERGIANT, S PERSEI, WITH VLBI H{sub 2}O MASER ASTROMETRY

    SciTech Connect

    Asaki, Y.; Deguchi, S.; Imai, H.; Hachisuka, K.; Miyoshi, M.; Honma, M. E-mail: deguchi@nro.nao.ac.j E-mail: khachi@shao.ac.c E-mail: mareki.honma@nao.ac.j

    2010-09-20

    We have conducted Very Long Baseline Array phase-referencing monitoring of H{sub 2}O masers around the red supergiant, S Persei, for six years. We have fitted maser motions to a simple expanding-shell model with a common annual parallax and stellar proper motion, and obtained the annual parallax as 0.413 {+-} 0.017 mas and the stellar proper motion as (-0.49 {+-} 0.23 mas yr{sup -1}, -1.19 {+-} 0.20 mas yr{sup -1}) in right ascension and declination, respectively. The obtained annual parallax corresponds to the trigonometric distance of 2.42{sup +0.11}{sub -0.09} kpc. Assuming a Galactocentric distance of the Sun of 8.5 kpc, the circular rotational velocity of the local standard of rest at a distance of the Sun of 220 km s{sup -1}, and a flat Galactic rotation curve, S Persei is suggested to have a non-circular motion deviating from the Galactic circular rotation for 15 km s{sup -1}, which is mainly dominated by the anti-rotation direction component of 12.9 {+-} 2.9 km s{sup -1}. This red supergiant is thought to belong to the OB association, Per OB1, so that this non-circular motion is representative of a motion of the OB association in the Milky Way. This non-circular motion is somewhat larger than that explained by the standard density-wave theory for a spiral galaxy and is attributed to either a cluster shuffling of the OB association, or to non-linear interactions between non-stationary spiral arms and multi-phase interstellar media. The latter comes from a new view of a spiral arm formation in the Milky Way suggested by recent large N-body/smoothed particle hydrodynamics numerical simulations.

  16. SN 2009ip and SN 2010mc: core-collapse Type IIn supernovae arising from blue supergiants

    NASA Astrophysics Data System (ADS)

    Smith, Nathan; Mauerhan, Jon C.; Prieto, Jose L.

    2014-02-01

    The recent supernova (SN) known as SN 2009ip had dramatic precursor eruptions followed by an even brighter explosion in 2012. Its pre-2012 observations make it the best documented SN progenitor in history, but have fuelled debate about the nature of its 2012 explosion - whether it was a true SN or some type of violent non-terminal event. Both could power shock interaction with circumstellar material (CSM), but only a core-collapse SN provides a self-consistent explanation. The persistent broad emission lines in the spectrum require a relatively large ejecta mass, and a corresponding kinetic energy of at least 1051 erg, while the faint 2012a event is consistent with published models of core-collapse SNe from compact (60 R?) blue supergiants. The light curves of SN 2009ip and another Type IIn, SN 2010mc, were nearly identical; we demonstrate that their spectra match as well, and that both are standard SNe IIn. Our observations contradict the recent claim that the late-time spectrum of SN 2009ip is returning to its progenitor's luminous blue variable-like state, and we show the that late-time spectra of SN 2009ip closely resemble the spectra of SN 1987A. Moreover, SN 2009ip's changing H? equivalent width after explosion matches behaviour typically seen in core-collapse SNe IIn. Several key facts about SN 2009ip and SN 2010mc argue strongly in favour of a core-collapse interpretation, and make a non-terminal 1050 erg event implausible. The most straightforward and self-consistent interpretation is that SN 2009ip was an initially faint core-collapse explosion of a blue supergiant that produced about half as much 56Ni as SN 1987A, with most of the peak luminosity from CSM interaction.

  17. High spectral resolution spectroscopy of the SiO fundamental lines in red giants and red supergiants with VLT/VISIR

    NASA Astrophysics Data System (ADS)

    Ohnaka, K.

    2014-01-01

    Context. The mass-loss mechanism in red giants and red supergiants is not yet understood well. The SiO fundamental lines near 8 ?m are potentially useful for probing the outer atmosphere, which is essential for clarifying the mass-loss mechanism. However, these lines have been little explored until now. Aims: We present high spectral resolution spectroscopic observations of the SiO fundamental lines near 8.1 ?m in 16 bright red giants and red supergiants. Our sample consists of seven normal (i.e., non-Mira) K-M giants (from K1.5 to M6.5), three Mira stars, three optically bright red supergiants, two dusty red supergiants, and the enigmatic object GCIRS3 near the Galactic center. Methods: Our program stars were observed between 8.088 ?m and 8.112 ?m with a spectral resolution of 30 000 using VLT/VISIR. Results: We detected SiO fundamental lines in all of our program stars except for GCIRS3. The SiO lines in normal K and M giants as well as optically bright (i.e., not dusty) red supergiants do not show P-Cyg profiles or blueshifts, which means the absence of systematic outflows in the SiO line forming region. We detected P-Cyg profiles in the SiO lines in the dusty red supergiants VY CMa and VX Sgr, with the latter object being a new detection. These SiO lines originate in the outflowing gas with the thermal dust continuum emission seen as the background. The outflow velocities of the SiO line forming region in VY CMa and VX Sgr are estimated to be 27 km s-1 and 17 km s-1, respectively. We derived basic stellar parameters (effective temperature, surface gravity, luminosity, and mass) for the normal K-M giants and optically bright red supergiants in our sample and compared the observed VISIR spectra with synthetic spectra predicted from MARCS photospheric models. Most of the SiO lines observed in the program stars warmer than ~3400 K are reasonably reproduced by the MARCS models, which allowed us to estimate the silicon abundance as well as the 28Si/29Si and 28Si/30Si ratios. However, we detected possible absorption excess in some SiO lines. Moreover, the SiO lines in the cooler red giants and red supergiant cannot be explained by the MARCS models at all, even if the dust emission is taken into account. This disagreement may be a signature of the dense, extended molecular outer atmosphere. Based on VISIR observations made with the Very Large Telescope of the European Southern Observatory. Program ID: 087.D-0522(A).Reduced spectra are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/561/A47

  18. The dynamical state of the atmosphere of the supergiant Alpha Cygni (A2 Iae) derived from high-resolution ultraviolet spectra

    NASA Astrophysics Data System (ADS)

    Boer, B.; de Jager, C.; Nieuwenhuijzen, H.

    1988-03-01

    In order to study the apparent near-instability of supergiant atmospheres, high-resolution BUSS (Balloon-borne Ultraviolet Stellar Spectometer) spectra of the supergiant Alpha Cyg have been investigated. Equivalent widths of lines yield the variation of the line-of-sight microturbulent velocity component zeta(mu) with optical depth tau. At tau(5) = 0.1, zeta(mu) equal to the velocity of sound is found. The consequent turbulent acceleration is directed outward. It increases outward and is about half the effective acceleration at tau(5) = 0.01. The macroturbulent velocity profile is double peaked with upward and downward velocities of 14 km/s. It is suggested that these motions are stochastic pulsations of large elements. At any time there are 30 to 40 such elements on the visible disk.

  19. Quantitative Studies of the Far-Ultraviolet, Ultraviolet, and Optical Spectra of Late O- and Early B-Type Supergiants in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Evans, C. J.; Crowther, P. A.; Fullerton, A. W.; Hillier, D. J.

    2004-08-01

    We present quantitative studies of eight late O- and early B-type supergiants in the Magellanic Clouds using far-ultraviolet Far Ultraviolet Spectroscopic Explorer, ultraviolet International Ultraviolet Explorer/Hubble Space Telescope, and optical VLT-UVES spectroscopy. Temperatures, mass-loss rates, and CNO abundances are obtained using the non-LTE, spherical, line-blanketed model atmosphere code of Hillier & Miller. We support recent results for lower temperatures of OB-type supergiants as a result of stellar winds and blanketing, which amounts to ~2000 K at B0 Ia. In general, Hα-derived mass-loss rates are consistent with UV and far-UV spectroscopy, although from consideration of the S IV λλ1063, 1073 doublet, clumped winds are preferred over homogenous models. AV 235 (B0 Iaw) is a notable exception, which has an unusually strong Hα profile that is inconsistent with the other Balmer lines and UV wind diagnostics. We also derive CNO abundances for our sample, revealing substantial nitrogen enrichment, with carbon and oxygen depletion. Our results are supported by comparison with the Galactic supergiant HD 2905 (BC0.7 Ia) for which near-solar CNO abundances are obtained. This bolsters previous suggestions that ``normal'' OB-type supergiants exhibit atmospheric compositions indicative of partial CNO processing. Based on observations made with the NASA-CNES-CSA Far Ultraviolet Spectroscopic Explorer. FUSE is operated by Johns Hopkins University under NASA contract NAS5-32985. Also based in part on observations collected at the European Southern Observatory Very Large Telescope in program 67.D-0238, plus archival data obtained with the NASA-ESA Hubble Space Telescope and the NASA-ESA-PPARC International Ultraviolet Explorer.

  20. Broad Balmer Wings in BA Hyper/Supergiants Distorted by Diffuse Interstellar Bands: Five Examples in the 30 Doradus Region from the VLT-FLAMES Tarantula Survey

    NASA Astrophysics Data System (ADS)

    Walborn, Nolan R.; Sana, Hugues; Evans, Christopher J.; Taylor, William D.; Sabbi, Elena; Barb, Rodolfo H.; Morrell, Nidia I.; Maz Apellniz, Jess; Sota, Alfredo; Dufton, Philip L.; McEvoy, Catherine M.; Clark, J. Simon; Markova, Nevena; Ulaczyk, Krzysztof

    2015-08-01

    Extremely broad emission wings at H? and H? have been found in VLT-FLAMES Tarantula Survey data for five very luminous BA supergiants in or near 30 Doradus in the Large Magellanic Cloud. The profiles of both lines are extremely asymmetrical, which we have found to be caused by very broad diffuse interstellar bands (DIBs) in the longward wing of H? and the shortward wing of H?. These DIBs are well known to interstellar but not to many stellar specialists, so that the asymmetries may be mistaken for intrinsic features. The broad emission wings are generally ascribed to electron scattering, although we note difficulties for that interpretation in some objects. Such profiles are known in some Galactic hyper/supergiants and are also seen in both active and quiescent Luminous Blue Variables (LBVs). No prior or current LBV activity is known in these 30 Dor stars, although a generic relationship to LBVs is not excluded; subject to further observational and theoretical investigation, it is possible that these very luminous supergiants are approaching the LBV stage for the first time. Their locations in the HRD and presumed evolutionary tracks are consistent with that possibility. The available evidence for spectroscopic variations of these objects is reviewed, while recent photometric monitoring does not reveal variability. A search for circumstellar nebulae has been conducted, with an indeterminate result for one of them.

  1. An HST COS "SNAPshot" Spectrum of the K-Supergiant (Lambda)Vel (K4Ib-II)

    NASA Technical Reports Server (NTRS)

    Carpenter, Kenneth G.; Ayres, Thomas R.; Harper, Graham M.; Kober, Gladys; Nielsen, Krister E.; Wahlgren, Glenn M.

    2014-01-01

    We present a far-ultraviolet spectrum of the K4 Ib-II supergiant (Lambda)Vel obtained with the Hubble Space Telescope's Cosmic Origins Spectrograph (COS) as a part of the SNAPshot program "SNAPing coronal iron" (GO 11687). The observation covers a wavelength region (1326-1467 A) not previously recorded for (Lambda)Vel at a spectral resolving power of R approx. 20,000 and displays strong emission and absorption features, superposed on a bright chromospheric continuum. Fluorescent excitation is responsible for much of the observed emission, mainly powered by strong H I Ly(alpha) and the O I (UV 2) triplet emission near (Lambda)1304. The molecular CO and H2 fluorescences are weaker than in the early-K giant (alpha) Boo while the Fe II and Cr II lines, also pumped by H I Ly(alpha), are stronger in (Lambda)Vel. This pattern of relative lines strengths between the two stars is explained by the lower iron-group element abundance in (alpha) Boo, which weakens that star's Fe II and Cr II emission without reducing the molecular fluorescences. The (Lambda)Vel spectrum shows fluorescent Fe II, Cr II, and H2 emission similar to that observed in the M supergiant (alpha) Ori, but more numerous well-defined narrow emissions from CO. The additional CO emissions are visible in the spectrum of (Lambda)Vel since that star does not have the cool, opaque circumstellar shells that surround a Ori and produce broad circumstellar CO (A-X) band absorptions that hide those emissions in the cooler star. The presence of Si IV emission in (Lambda)Vel indicates a approx.8 × 10(exp 4) K plasma that is mixed into the cooler chromosphere. Evidence of the stellar wind is seen in the CII (Lambda)(Lambda)1334,1335 lines and in the blueshifted Fe II and Ni II wind absorption lines. Line modeling using Sobolev with Exact Integration for the Cii lines indicates a larger terminal velocity (approx.45 versus approx.30 km/s) and turbulence (approx.27 versus <21 km/s) with a more quickly accelerating wind (beta = 0.35 versus 0.7) at the time of this COS observation in 2010 than derived from GHRS data obtained in 1994. The Fe ii and Ni ii absorptions are blueshifted by 7.6 km/s relative to the chromospheric emission, suggesting formation in lower levels of the accelerating wind and their width indicate a higher turbulence in the (Lambda)Vel wind compared to (alpha) Ori. Key words: stars: atmospheres-- stars: chromospheres - stars individual (? Vel, a Boo, a Ori) - stars: late-type - stars: mass loss - supergiants.

  2. HST Studies of the Chromospheres, Wind, and Mass-Loss Rates of Cool Giant and Supergiant Stars

    NASA Technical Reports Server (NTRS)

    Carpenter, Kenneth G.

    2000-01-01

    UV spectra of K-M giant and supergiant stars and of carbon stars have been acquired with the Goddard High Resolution Spectrograph (GHRS) on the Hubble Space Telescope (HST). These spectra have been used to measure chromospheric flow and turbulent velocities, study the acceleration of their stellar winds, acquire constraints on their outer atmospheric structure, and enable estimates of their mass-loss rates. Results from our observations of the giant stars Gamma Dra (K5 III hybrid), Alpha Tau (K5 III), Gamma Cru (M3.4 III), Mu Gem (M3 IIIab), and 30 Her (MG III), the supergiants Alpha Ori (M2 Iab) and Lambda Vel (K5 Ib), and the carbon stars TX Psc (NO; C6,2) and TW Hor (NO; C7,2) will be summarized and compared. The high resolution and wavelength accuracy of these data have allowed the direct measurement of the acceleration of the stellar winds in the chromospheres of several of these stars (from initial velocities of 3-9 km/s to upper velocities of 15-25 km/s) and of the chromospheric macroturbulence (-25-35 km/s). The high signal-to-noise and large dynamic range of these spectra have allowed the detection and identification of numerous new emission features, including weak C IV emission indicative of hot transition-region plasma in the non-coronal giant Alpha Tau, many new fluorescent lines of Fe II, and the first detection of fluorescent molecular hydrogen emission and of Ca II recombination lines in the UV spectrum of a giant star. The UV spectrum of two carbon stars have been studied with unprecedented resolution and reveal extraordinarily complicated Mg II lines nearly smothered by circumstellar absorptions. Finally, comparison of synthetic UV emission line profiles computed with the Lamers et al. (1987) Sobolev with Exact Integration (SEI) code with observations of chromospheric emission lines overlain with wind absorption features provides estimates of the mass-loss rates for four of these stars.

  3. Comparative Studies of the Dust around Red Supergiant and Oxygen-Rich Asymptotic Giant Branch Stars in the Local Universe

    NASA Astrophysics Data System (ADS)

    Sargent, Benjamin; Srinivasan, Sundar; Speck, Angela K.; Volk, Kevin; Kemper, Ciska; Reach, William; Lagadec, Eric; Bernard, Jean-Philippe; McDonald, Iain; Meixner, Margaret; Sloan, Greg; Jones, Olivia

    2015-08-01

    We analyze the dust emission features seen in Spitzer Space Telescope Infrared Spectrograph (IRS) spectra of red supergiant (RSG) and oxygen-rich asymptotic giant branch (AGB) stars in the Large Magellanic Cloud and Small Magellanic Cloud galaxies and in various Milky Way globular clusters. The spectra come from the Spitzer Legacy program SAGE-Spectroscopy (PI: F. Kemper), the Spitzer program SMC-Spec (PI: G. Sloan), and other archival Spitzer-IRS programs. The broad 10 and 20 μm emission features attributed to amorphous dust of silicate composition seen in the spectra show evidence for systematic differences in the centroid of both emission features between O-rich AGB and RSG populations. Radiative transfer modeling using the GRAMS grid of models of AGB and RSG stars suggests that the centroid differences are due to differences in dust properties. We investigate differences in dust composition, size, shape, etc that might be responsible for these spectral differences. We explore how these differences may arise from the different circumstellar environments around RSG and O-rich AGB stars and assess effects of varying metallicity (LMC versus SMC versus Milky Way globular cluster) and other properties (mass-loss rate, luminosity, etc.) on the dust originating from these stars. BAS acknowledges funding from NASA ADAP grant NNX13AD54G.

  4. Mass Loss from Dusty AGB and Red Supergiant Stars in the Magellanic Clouds and in the Galaxy

    NASA Astrophysics Data System (ADS)

    Sargent, Benjamin A.; Srinivasan, Sundar; Meixner, Margaret; Kastner, Joel

    2016-01-01

    Asymptotic giant branch (AGB) and red supergiant (RSG) stars are evolved stars that eject large parts of their mass in outflows of dust and gas. As part of an ongoing effort to measure mass loss from evolved stars in our Galaxy and in the Magellanic Clouds, we are modeling mass loss from AGB and RSG stars in these galaxies. Our approach is twofold. We pursue radiative transfer modeling of the spectral energy distributions (SEDs) of AGB and RSG stars in the Large Magellanic Cloud (LMC), in the Small Magellanic Cloud (SMC), and in the Galactic bulge and in globular clusters of the Milky Way. We are also constructing detailed dust opacity models of AGB and RSG stars in these galaxies for which we have infrared spectra; e.g., from the Spitzer Space Telescope Infrared Spectrograph (IRS). Our sample of infrared spectra largely comes from Spitzer-IRS observations. The detailed dust modeling of spectra informs our choice of dust properties to use in radiative transfer modeling of SEDs. We seek to determine how mass loss from these evolved stars depends upon the metallicity of their host environments. BAS acknowledges funding from NASA ADAP grant NNX15AF15G.

  5. RED SUPERGIANT STARS AS COSMIC ABUNDANCE PROBES: NLTE EFFECTS IN J-BAND IRON AND TITANIUM LINES

    SciTech Connect

    Bergemann, Maria; Kudritzki, Rolf-Peter; Lind, Karin; Plez, Bertrand; Davies, Ben; Gazak, Zach E-mail: klind@mpa-garching.mpg.de E-mail: zgazak@ifa.hawaii.edu E-mail: bdavies@ast.cam.ac.uk

    2012-06-01

    Detailed non-LTE (NLTE) calculations for red supergiant (RSG) stars are presented to investigate the influence of NLTE on the formation of atomic iron and titanium lines in the J band. With their enormous brightness at J band RSG stars are ideal probes of cosmic abundances. Recent LTE studies have found that metallicities accurate to 0.15 dex can be determined from medium-resolution spectroscopy of individual RSGs in galaxies as distant as 10 Mpc. The NLTE results obtained in this investigation support these findings. NLTE abundance corrections for iron are smaller than 0.05 dex for effective temperatures between 3400 K and 4200 K and 0.1 dex at 4400 K. For titanium the NLTE abundance corrections vary smoothly between -0.4 dex and +0.2 dex as a function of effective temperature. For both elements, the corrections also depend on stellar gravity and metallicity. The physical reasons behind the NLTE corrections and the consequences for extragalactic J-band abundance studies are discussed.

  6. Spitzer-IRS Spectroscopic Studies of Oxygen-Rich Asymptotic Giant Branch Star and Red Supergiant Star Dust Properties

    NASA Astrophysics Data System (ADS)

    Sargent, Benjamin A.; Srinivasan, Sundar; Speck, Angela; Volk, Kevin; Kemper, Ciska; Reach, William T.; Lagadec, Eric; Bernard, Jean-Philippe; McDonald, Iain; Meixner, Margaret

    2015-01-01

    We analyze the dust emission features seen in Spitzer Space Telescope Infrared Spectrograph (IRS) spectra of Oxygen-rich (O-rich) asymptotic giant branch (AGB) and red supergiant (RSG) stars. The spectra come from the Spitzer Legacy program SAGE-Spectroscopy (PI: F. Kemper) and other archival Spitzer-IRS programs. The broad 10 and 20 micron emission features attributed to amorphous dust of silicate composition seen in the spectra show evidence for systematic differences in the centroid of both emission features between O-rich AGB and RSG populations. Radiative transfer modeling using the GRAMS grid of models of AGB and RSG stars suggests that the centroid differences are due to differences in dust properties. We present an update of our investigation of differences in dust composition, size, shape, etc that might be responsible for these spectral differences. We explore how these differences may arise from the different circumstellar environments around RSG and O-rich AGB stars. BAS acknowledges funding from NASA ADAP grant NNX13AD54G.

  7. CHARA/MIRC Observations of Two M Supergiants in Perseus OB1: Temperature, Bayesian Modeling, and Compressed Sensing Imaging

    NASA Astrophysics Data System (ADS)

    Baron, F.; Monnier, J. D.; Kiss, L. L.; Neilson, H. R.; Zhao, M.; Anderson, M.; Aarnio, A.; Pedretti, E.; Thureau, N.; ten Brummelaar, T. A.; Ridgway, S. T.; McAlister, H. A.; Sturmann, J.; Sturmann, L.; Turner, N.

    2014-04-01

    Two red supergiants (RSGs) of the Per OB1 association, RS Per and T Per, have been observed in the H band using the Michigan Infra-Red Combiner (MIRC) instrument at the CHARA array. The data show clear evidence of a departure from circular symmetry. We present here new techniques specially developed to analyze such cases, based on state-of-the-art statistical frameworks. The stellar surfaces are first modeled as limb-darkened disks based on SATLAS models that fit both MIRC interferometric data and publicly available spectrophotometric data. Bayesian model selection is then used to determine the most probable number of spots. The effective surface temperatures are also determined and give further support to the recently derived hotter temperature scales of RSGs. The stellar surfaces are reconstructed by our model-independent imaging code SQUEEZE, making use of its novel regularizer based on Compressed Sensing theory. We find excellent agreement between the model-selection results and the reconstructions. Our results provide evidence for the presence of near-infrared spots representing about 3%-5% of the stellar flux.

  8. The Vast Population of Wolf-Rayet and Red Supergiant Stars in M101. I. Motivation and First Results

    NASA Astrophysics Data System (ADS)

    Shara, Michael M.; Bibby, Joanne L.; Zurek, David; Crowther, Paul A.; Moffat, Anthony F. J.; Drissen, Laurent

    2013-12-01

    Assembling a catalog of at least 10,000 Wolf-Rayet (W-R) stars is an essential step in proving (or disproving) that these stars are the progenitors of Type Ib and Type Ic supernovae. To this end, we have used the Hubble Space Telescope (HST) to carry out a deep, He II optical narrowband imaging survey of the ScI spiral galaxy M101. Almost the entire galaxy was imaged with the unprecedented depth and resolution that only the HST affords. Differenced with archival broadband images, the narrowband images allow us to detect much of the W-R star population of M101. We describe the extent of the survey and our images, as well as our data reduction procedures. A detailed broadband-narrowband imaging study of a field east of the center of M101, containing the giant star-forming region NGC 5462, demonstrates our completeness limits, how we find W-R candidates, their properties and spatial distribution, and how we rule out most contaminants. We use the broadband images to locate luminous red supergiant (RSG) candidates. The spatial distributions of the W-R and RSG stars near NGC 5462 are strikingly different. W-R stars dominate the complex core, while RSGs dominate the complex halo. Future papers in this series will describe and catalog more than a thousand W-R and RSG candidates that are detectable in our images, as well as spectra of many of those candidates.

  9. CHARA/MIRC observations of two M supergiants in Perseus OB1: Temperature, bayesian modeling, and compressed sensing imaging

    SciTech Connect

    Baron, F.; Monnier, J. D.; Anderson, M.; Aarnio, A.; Kiss, L. L.; Neilson, H. R.; Zhao, M.; Pedretti, E.; Thureau, N.; Ten Brummelaar, T. A.; Sturmann, J.; Sturmann, L.; Turner, N.; Ridgway, S. T.; McAlister, H. A.

    2014-04-10

    Two red supergiants (RSGs) of the Per OB1 association, RS Per and T Per, have been observed in the H band using the Michigan Infra-Red Combiner (MIRC) instrument at the CHARA array. The data show clear evidence of a departure from circular symmetry. We present here new techniques specially developed to analyze such cases, based on state-of-the-art statistical frameworks. The stellar surfaces are first modeled as limb-darkened disks based on SATLAS models that fit both MIRC interferometric data and publicly available spectrophotometric data. Bayesian model selection is then used to determine the most probable number of spots. The effective surface temperatures are also determined and give further support to the recently derived hotter temperature scales of RSGs. The stellar surfaces are reconstructed by our model-independent imaging code SQUEEZE, making use of its novel regularizer based on Compressed Sensing theory. We find excellent agreement between the model-selection results and the reconstructions. Our results provide evidence for the presence of near-infrared spots representing about 3%-5% of the stellar flux.

  10. Evidence for the pulsational origin of the Long Secondary Periods: The red supergiant star V424 Lac (HD 216946)

    NASA Astrophysics Data System (ADS)

    Messina, Sergio

    2007-10-01

    The results of a long-term UBV photometric monitoring of the red supergiant (RSG) star V424 Lac are presented. V424 Lac shows multiperiodic brightness variations which can be attributed to pulsational oscillations. A much longer period ( P = 1601 d), that allows us to classify this star as a long secondary period variable star (LSPV) has been also detected. The B - V and U - B color variations related to the long secondary period (LSP) are similar to those related to the shorter periods, supporting the pulsational nature of LSP. The long period brightness variation of V424 Lac is accompanied by a near-UV (NUV) excess, which was spectroscopically detected in a previous study [Massey, P., Plez, B., Levesque, E.M., et al., 2005. ApJ 634, 1286] and which is now found to be variable from photometry. On the basis of the results found for V424 Lac, the NUV excess recently found in a number of RSGs may be due not solely to circumstellar dust but may also have a contribution from a still undetected LSP variability.

  11. The vast population of Wolf-Rayet and red supergiant stars in M101. I. Motivation and first results

    SciTech Connect

    Shara, Michael M.; Bibby, Joanne L.; Zurek, David; Crowther, Paul A.; Moffat, Anthony F. J.; Drissen, Laurent

    2013-12-01

    Assembling a catalog of at least 10,000 Wolf-Rayet (W-R) stars is an essential step in proving (or disproving) that these stars are the progenitors of Type Ib and Type Ic supernovae. To this end, we have used the Hubble Space Telescope (HST) to carry out a deep, He II optical narrowband imaging survey of the ScI spiral galaxy M101. Almost the entire galaxy was imaged with the unprecedented depth and resolution that only the HST affords. Differenced with archival broadband images, the narrowband images allow us to detect much of the W-R star population of M101. We describe the extent of the survey and our images, as well as our data reduction procedures. A detailed broadband-narrowband imaging study of a field east of the center of M101, containing the giant star-forming region NGC 5462, demonstrates our completeness limits, how we find W-R candidates, their properties and spatial distribution, and how we rule out most contaminants. We use the broadband images to locate luminous red supergiant (RSG) candidates. The spatial distributions of the W-R and RSG stars near NGC 5462 are strikingly different. W-R stars dominate the complex core, while RSGs dominate the complex halo. Future papers in this series will describe and catalog more than a thousand W-R and RSG candidates that are detectable in our images, as well as spectra of many of those candidates.

  12. MASER OBSERVATIONS OF WESTERLUND 1 AND COMPREHENSIVE CONSIDERATIONS ON MASER PROPERTIES OF RED SUPERGIANTS ASSOCIATED WITH MASSIVE CLUSTERS

    SciTech Connect

    Fok, Thomas K. T.; Nakashima, Jun-ichi; Yung, Bosco H. K.; Hsia, Chih-Hao; Deguchi, Shuji

    2012-11-20

    We report the results of Australia Telescope Compact Array observations of the Westerlund 1 (Wd1) region in the SiO v = 1, J = 1-0, and H{sub 2}O 6{sub 16}-5{sub 23} maser lines, and we also report the analysis of maser properties of red supergiants (RSGs) associated with six massive clusters including Wd1. The primary purpose of this research is to explore possibilities of using maser emission for investigating the nature of massive clusters and associated RSGs. The SiO v = 1, J = 1-0, and H{sub 2}O 6{sub 16}-5{sub 23} maser lines are detected toward two of four known RSGs in Wd1. The large velocity ranges of maser emission are consistent with the RSG status. RSGs with maser emission tend to exhibit redder log (F {sub 21}/F {sub 12}) and [K-12.13] colors compared to RSGs with no maser emission. The mass-loss rates derived from dust radiative transfer modeling suggest that RSGs with maser emission tend to exhibit larger mass-loss rates compared to RSGs with no maser emission. In an extended sample of 57 RSGs in six massive clusters, detections in the SiO line tend to homogeneously distribute in absolute luminosity L, whereas those in the H{sub 2}O line tend to distribute in a region with large L values.

  13. The VLT-FLAMES Tarantula Survey. V. The peculiar B[e]-like supergiant, VFTS698, in 30 Doradus

    NASA Astrophysics Data System (ADS)

    Dunstall, P. R.; Fraser, M.; Clark, J. S.; Crowther, P. A.; Dufton, P. L.; Evans, C. J.; Lennon, D. J.; Soszy?ski, I.; Taylor, W. D.; Vink, J. S.

    2012-06-01

    Aims: We present an analysis of a peculiar supergiant B-type star (VFTS698/Melnick 2/Parker 1797) in the 30 Doradus region of the Large Magellanic Cloud which exhibits characteristics similar to the broad class of B[e] stars. Methods: We analyse optical spectra from the VLT-FLAMES survey, together with archival optical and infrared photometry and X-ray imaging to characterise the system. Results: We find radial velocity variations of around 400 km s-1 in the high excitation Si iv, N iii and He ii spectra, and photometric variability of ~0.6 mag with a period of 12.7 d. In addition, we detect long-term photometric variations of ~0.25 mag, which may be due to a longer-term variability with a period of ~400 d. Conclusions: We conclude that VFTS698 is likely an interacting binary comprising an early B-type star secondary orbiting a veiled, more massive companion. Spectral evidence suggests a mid-to-late B-type primary, but this may originate from an optically-thick accretion disc directly surrounding the primary. Based on observations at the European Southern Observatory Very Large Telescope in programme 182.D-0222.Table 8 is available in electronic form at http://www.aanda.org

  14. IGR J17354-3255 as bench test for investigation of ?-ray emission from Supergiant Fast X-ray Transients

    NASA Astrophysics Data System (ADS)

    Sguera, V.

    2013-06-01

    Among the different types of sources shining in the high energy sky, gamma-ray binaries are rapidly becoming the subject of major interest. In fact, in the last few years a number of High Mass X-ray Binaries (HMXBs) have been firmly detected from MeV to TeV energies, providing secure evidences that particles can be efficiently accelerated up to very high energies in such galactic systems. Similarly to this general and emerging class of gamma-ray binaries, in principle Supergiant Fast X-ray Transients (SFXTs) have all the "ingredients" to be transient high energy emitters. In this context, the SFXT IGR J17354-3255 is a good bench test and we present intriguing hints likely suggesting that it is a transient gamma-ray source flaring on short timescales. If fully confirmed by further studies, the implications stemming are huge, both theoretically and observationally, and would add a further extreme characteristic to the already extreme class of SFXTs.

  15. High-latitude supergiant V5112 Sgr: Enrichment of the envelope with heavy s-process metals

    NASA Astrophysics Data System (ADS)

    Klochkova, V. G.

    2013-11-01

    High-resolution ( R = 60 000) echelle spectroscopy of the post-AGB supergiant V5112 Sgr performed in 1996-2012 with the 6-m BTA telescope has revealed peculiarities of the star's optical spectrum and has allowed the variability of the velocity field in the stellar atmosphere and envelope to be studied in detail. An asymmetry and splitting of strong absorption lines with a low lower-level excitation potential have been detected for the first time. The effect is maximal in Ba II lines whose profile is split into three components. The profile shape and positions of the split lines change with time. The short-wavelength components of the split absorption lines are shown to be formed in a structured circumstellar envelope, suggesting an efficient dredge-up of the heavy metals produced during the preceding evolution of this star into the envelope. The envelope expansion velocities have been estimated to be V exp ? 20 and 30 km s-1. The mean radial velocity from diffuse bands in the spectrum of V5112 Sgr coincides with that from the short-wavelength shell component of the Na I D lines, which leads to the conclusion about their formation in the circumstellar envelope. Analysis of the set of radial velocities V r based on symmetric absorption lines has confirmed the presence of pulsations in the stellar atmosphere with an amplitude ? V r ? 8 km s-1.

  16. The Orbit and Position of the X-ray Pulsar XTE J1855-026: An Eclipsing Supergiant System

    NASA Technical Reports Server (NTRS)

    Corbet, Robin H. D.; Mukai, Koji; White, Nicholas E. (Technical Monitor)

    2002-01-01

    A pulse timing orbit has been obtained for the X-ray binary XTEJ1855-026 using observations made with the Proportional Counter Array on board the Rossi X-ray Timing Explorer. The mass function obtained of approximately 16 solar mass together with the detection of an extended near-total eclipse confirm that the primary star is supergiant as predicted. The orbital eccentricity is found to be very low with a best fit value of 0.04 +/- 0.02. The orbital period is also refined to be 6.0724 +/- 0.0009 days using an improved and extended light curve obtained with RXTE's All Sky Monitor. Observations with the ASCA satellite provide an improved source location of R.A.= 18 hr 55 min 31.3 sec, decl.= -02 deg 36 min 24.0 sec (2000) with an estimated systematic uncertainty of less than 12 min. A serendipitous new source, AX J1855.4-0232, was also discovered during the ASCA observations.

  17. The VLT-FLAMES Tarantula Survey. XIX. B-type supergiants: Atmospheric parameters and nitrogen abundances to investigate the role of binarity and the width of the main sequence

    NASA Astrophysics Data System (ADS)

    McEvoy, C. M.; Dufton, P. L.; Evans, C. J.; Kalari, V. M.; Markova, N.; Simn-Daz, S.; Vink, J. S.; Walborn, N. R.; Crowther, P. A.; de Koter, A.; de Mink, S. E.; Dunstall, P. R.; Hnault-Brunet, V.; Herrero, A.; Langer, N.; Lennon, D. J.; Maz Apellniz, J.; Najarro, F.; Puls, J.; Sana, H.; Schneider, F. R. N.; Taylor, W. D.

    2015-03-01

    Context. Model atmosphere analyses have been previously undertaken for both Galactic and extragalactic B-type supergiants. By contrast, little attention has been given to a comparison of the properties of single supergiants and those that are members of multiple systems. Aims: Atmospheric parameters and nitrogen abundances have been estimated for all the B-type supergiants identified in the VLT-FLAMES Tarantula survey. These include both single targets and binary candidates. The results have been analysed to investigate the role of binarity in the evolutionary history of supergiants. Methods: tlusty non-local thermodynamic equilibrium (LTE) model atmosphere calculations have been used to determine atmospheric parameters and nitrogen abundances for 34 single and 18 binary supergiants. Effective temperatures were deduced using the silicon balance technique, complemented by the helium ionisation in the hotter spectra. Surface gravities were estimated using Balmer line profiles and microturbulent velocities deduced using the silicon spectrum. Nitrogen abundances or upper limits were estimated from the N ii spectrum. The effects of a flux contribution from an unseen secondary were considered for the binary sample. Results: We present the first systematic study of the incidence of binarity for a sample of B-type supergiants across the theoretical terminal age main sequence (TAMS). To account for the distribution of effective temperatures of the B-type supergiants it may be necessary to extend the TAMS to lower temperatures. This is also consistent with the derived distribution of mass discrepancies, projected rotational velocities and nitrogen abundances, provided that stars cooler than this temperature are post-red supergiant objects. For all the supergiants in the Tarantula and in a previous FLAMES survey, the majority have small projected rotational velocities. The distribution peaks at about 50 km s-1 with 65% in the range 30 km s-1 ? vesini ? 60 km s-1. About ten per cent have larger vesini (?100 km s-1), but surprisingly these show little or no nitrogen enhancement. All the cooler supergiants have low projected rotational velocities of ?70 km s-1and high nitrogen abundance estimates, implying that either bi-stability braking or evolution on a blue loop may be important. Additionally, there is a lack of cooler binaries, possibly reflecting the small sample sizes. Single-star evolutionary models, which include rotation, can account for all of the nitrogen enhancement in both the single and binary samples. The detailed distribution of nitrogen abundances in the single and binary samples may be different, possibly reflecting differences in their evolutionary history. Conclusions: The first comparative study of single and binary B-type supergiants has revealed that the main sequence may be significantly wider than previously assumed, extending to Teff = 20 000 K. Some marginal differences in single and binary atmospheric parameters and abundances have been identified, possibly implying non-standard evolution for some of the sample. This sample as a whole has implications for several aspects of our understanding of the evolutionary status of blue supergiants. Tables 1, 4, 7 are available in electronic form at http://www.aanda.org

  18. Sharpest views of Betelgeuse reveal how supergiant stars lose mass-Unveiling the true face of a behemoth

    NASA Astrophysics Data System (ADS)

    2009-07-01

    Using different state-of-the-art techniques on ESO's Very Large Telescope, two independent teams of astronomers have obtained the sharpest ever views of the supergiant star Betelgeuse. They show that the star has a vast plume of gas almost as large as our Solar System and a gigantic bubble boiling on its surface. These discoveries provide important clues to help explain how these mammoths shed material at such a tremendous rate. Betelgeuse - the second brightest star in the constellation of Orion (the Hunter) - is a red supergiant, one of the biggest stars known, and almost 1000 times larger than our Sun [1]. It is also one of the most luminous stars known, emitting more light than 100000 Suns. Such extreme properties foretell the demise of a short-lived stellar king. With an age of only a few million years, Betelgeuse is already nearing the end of its life and is soon doomed to explode as a supernova. When it does, the supernova should be seen easily from Earth, even in broad daylight. Red supergiants still hold several unsolved mysteries. One of them is just how these behemoths shed such tremendous quantities of material - about the mass of the Sun - in only 10 000 years. Two teams of astronomers have used ESO's Very Large Telescope (VLT) and the most advanced technologies to take a closer look at the gigantic star. Their combined work suggests that an answer to the long-open mass-loss question may well be at hand. The first team used the adaptive optics instrument, NACO, combined with a so-called "lucky imaging" technique, to obtain the sharpest ever image of Betelgeuse, even with Earth's turbulent, image-distorting atmosphere in the way. With lucky imaging, only the very sharpest exposures are chosen and then combined to form an image much sharper than a single, longer exposure would be. The resulting NACO images almost reach the theoretical limit of sharpness attainable for an 8-metre telescope. The resolution is as fine as 37 milliarcseconds, which is roughly the size of a tennis ball on the International Space Station (ISS), as seen from the ground. "Thanks to these outstanding images, we have detected a large plume of gas extending into space from the surface of Betelgeuse," says Pierre Kervella from the Paris Observatory, who led the team. The plume extends to at least six times the diameter of the star, corresponding to the distance between the Sun and Neptune. "This is a clear indication that the whole outer shell of the star is not shedding matter evenly in all directions," adds Kervella. Two mechanisms could explain this asymmetry. One assumes that the mass loss occurs above the polar caps of the giant star, possibly because of its rotation. The other possibility is that such a plume is generated above large-scale gas motions inside the star, known as convection - similar to the circulation of water heated in a pot. To arrive at a solution, astronomers needed to probe the behemoth in still finer detail. To do this Keiichi Ohnaka from the Max Planck Institute for Radio Astronomy in Bonn, Germany, and his colleagues used interferometry. With the AMBER instrument on ESO's Very Large Telescope Interferometer, which combines the light from three 1.8-metre Auxiliary Telescopes of the VLT, the astronomers obtained observations as sharp as those of a giant, virtual 48-metre telescope. With such superb resolution, the astronomers were able to detect indirectly details four times finer still than the amazing NACO images had already allowed (in other words, the size of a marble on the ISS, as seen from the ground). "Our AMBER observations are the sharpest observations of any kind ever made of Betelgeuse. Moreover, we detected how the gas is moving in different areas of Betelgeuse's surface ? the first time this has been done for a star other than the Sun", says Ohnaka. The AMBER observations revealed that the gas in Betelgeuse's atmosphere is moving vigorously up and down, and that these bubbles are as large as the supergiant star itself. Their unrivalled observations have led the astronomers to propose that these large-scale gas motions roiling under Betelgeuse's red surface are behind the ejection of the massive plume into space. Notes 1] If Betelgeuse were at the centre of our Solar System it would extend out almost to the orbit of Jupiter, engulfing Mercury, Venus, Earth, Mars and the main asteroid belt. More information This research was presented in two papers to appear in Astronomy and Astrophysics: The close circumstellar environment of Betelgeuse: Adaptive optics spectro-imaging in the near-IR with VLT/NACO, by Pierre Kervella et al., and Spatially resolving the inhomogeneous structure of the dynamical atmosphere of Betelgeuse with VLTI/AMBER, by Keiichi Ohnaka et al. The teams are composed of P. Kervella, G. Perrin, S. Lacour, and X. Haubois (LESIA, Observatoire de Paris, France), T. Verhoelst (K. U. Leuven, Belgium), S. T. Ridgway (National Optical Astronomy Observatories, USA), and J. Cami (University of Western Ontario, Canada), and of K. Ohnaka, K.-H. Hofmann, T. Driebe, F. Millour, D. Schertl, and G. Weigelt (Max-Planck-Institute for Radio Astronomy, Bonn, Germany), M. Benisty (INAF-Osservatorio Astrofisico di Arcetri, Firenze, Italy), A. Chelli (LAOG, Grenoble, France), R. Petrov and F. Vakili (Lab. H. Fizeau, OCA, Nice, France), and Ph. Stee (Lab. H. Fizeau, OCA, Grasse, France). ESO, the European Southern Observatory, is the foremost intergovernmental astronomy organisation in Europe and the world's most productive astronomical observatory. It is supported by 14 countries: Austria, Belgium, the Czech Republic, Denmark, France, Finland, Germany, Italy, the Netherlands, Portugal, Spain, Sweden, Switzerland and the United Kingdom. ESO carries out an ambitious programme focused on the design, construction and operation of powerful ground-based observing facilities enabling astronomers to make important scientific discoveries. ESO also plays a leading role in promoting and organising cooperation in astronomical research. ESO operates three unique world-class observing sites in Chile: La Silla, Paranal and Chajnantor. At Paranal, ESO operates the Very Large Telescope, the world's most advanced visible-light astronomical observatory. ESO is the European partner of a revolutionary astronomical telescope ALMA, the largest astronomical project in existence. ESO is currently planning a 42-metre European Extremely Large optical/near-infrared Telescope, the E-ELT, which will become "the world's biggest eye on the sky".

  19. On the metallicity dependence of crystalline silicates in oxygen-rich asymptotic giant branch stars and red supergiants

    NASA Astrophysics Data System (ADS)

    Jones, O. C.; Kemper, F.; Sargent, B. A.; McDonald, I.; Gielen, C.; Woods, Paul M.; Sloan, G. C.; Boyer, M. L.; Zijlstra, A. A.; Clayton, G. C.; Kraemer, K. E.; Srinivasan, S.; Ruffle, P. M. E.

    2012-12-01

    We investigate the occurrence of crystalline silicates in oxygen-rich evolved stars across a range of metallicities and mass-loss rates. It has been suggested that the crystalline silicate feature strength increases with increasing mass-loss rate, implying a correlation between lattice structure and wind density. To test this, we analyse Spitzer Infrared Spectrograph and Infrared Space Observatory Short Wavelength Spectrometer spectra of 217 oxygen-rich asymptotic giant branch and 98 red supergiants in the Milky Way, the Large and Small Magellanic Clouds, and Galactic globular clusters. These encompass a range of spectral morphologies from the spectrally rich which exhibit a wealth of crystalline and amorphous silicate features to 'naked' (dust-free) stars. We combine spectroscopic and photometric observations with the GRAMS grid of radiative transfer models to derive (dust) mass-loss rates and temperature. We then measure the strength of the crystalline silicate bands at 23, 28 and 33 ?m. We detect crystalline silicates in stars with dust mass-loss rates which span over 3 dex, down to rates of 10-9 M? yr-1. Detections of crystalline silicates are more prevalent in higher mass-loss rate objects, though the highest mass-loss rate objects do not show the 23-?m feature, possibly due to the low temperature of the forsterite grains or it may indicate that the 23-?m band is going into absorption due to high column density. Furthermore, we detect a change in the crystalline silicate mineralogy with metallicity, with enstatite seen increasingly at low metallicity.

  20. Blue Supergiant Model for Ultra-long Gamma-Ray Burst with Superluminous-supernova-like Bump

    NASA Astrophysics Data System (ADS)

    Nakauchi, Daisuke; Kashiyama, Kazumi; Suwa, Yudai; Nakamura, Takashi

    2013-11-01

    Long gamma-ray bursts (LGRBs) have a typical duration of ~30 s, and some of them are associated with hypernovae, such as Type Ic SN 1998bw. Wolf-Rayet stars are the most plausible LGRB progenitors, since the free fall time of the envelope is consistent with the duration, and the natural outcome of the progenitor is a Type Ic SN. While a new population of ultra-long GRBs (ULGRBs), GRB 111209A, GRB 101225A, and GRB 121027A, has a duration of ~104 s, two of them are accompanied by superluminous-supernova-like (SLSN-like) bumps, which are <~ 10 times brighter than typical hypernovae. Wolf-Rayet progenitors cannot explain ULGRBs because of durations that are too long and SN-like bumps that are too bright. A blue supergiant (BSG) progenitor model, however, can explain the duration of ULGRBs. Moreover, SLSN-like bumps can be attributed to the so-called cocoon fireball photospheric emissions (CFPEs). Since a large cocoon is inevitably produced during the relativistic jet piercing though the BSG envelope, this component can be smoking gun evidence of the BSG model for ULGRBs. In this paper, we examine u-, g-, r-, i-, and J-band light curves of three ULGRBs and demonstrate that they can be fitted quite well by our BSG model with the appropriate choices of the jet opening angle and the number density of the ambient gas. In addition, we predict that for 121027A, SLSN-like bump could have been observed for ~20-80 days after the burst. We also propose that some SLSNe might be CFPEs of off-axis ULGRBs without visible prompt emissions.

  1. Blue supergiant model for ultra-long gamma-ray burst with superluminous-supernova-like bump

    SciTech Connect

    Nakauchi, Daisuke; Nakamura, Takashi; Kashiyama, Kazumi; Suwa, Yudai

    2013-11-20

    Long gamma-ray bursts (LGRBs) have a typical duration of ∼30 s, and some of them are associated with hypernovae, such as Type Ic SN 1998bw. Wolf-Rayet stars are the most plausible LGRB progenitors, since the free fall time of the envelope is consistent with the duration, and the natural outcome of the progenitor is a Type Ic SN. While a new population of ultra-long GRBs (ULGRBs), GRB 111209A, GRB 101225A, and GRB 121027A, has a duration of ∼10{sup 4} s, two of them are accompanied by superluminous-supernova-like (SLSN-like) bumps, which are ≲ 10 times brighter than typical hypernovae. Wolf-Rayet progenitors cannot explain ULGRBs because of durations that are too long and SN-like bumps that are too bright. A blue supergiant (BSG) progenitor model, however, can explain the duration of ULGRBs. Moreover, SLSN-like bumps can be attributed to the so-called cocoon fireball photospheric emissions (CFPEs). Since a large cocoon is inevitably produced during the relativistic jet piercing though the BSG envelope, this component can be smoking gun evidence of the BSG model for ULGRBs. In this paper, we examine u-, g-, r-, i-, and J-band light curves of three ULGRBs and demonstrate that they can be fitted quite well by our BSG model with the appropriate choices of the jet opening angle and the number density of the ambient gas. In addition, we predict that for 121027A, SLSN-like bump could have been observed for ∼20-80 days after the burst. We also propose that some SLSNe might be CFPEs of off-axis ULGRBs without visible prompt emissions.

  2. Luminous and variable stars in M31 and M33. II. Luminous blue variables, candidate LBVs, Fe II emission line stars, and other supergiants

    SciTech Connect

    Humphreys, Roberta M.; Davidson, Kris; Weis, Kerstin; Bomans, D. J.; Burggraf, Birgitta E-mail: kweis@astro.rub.de

    2014-07-20

    An increasing number of non-terminal eruptions are being found in the numerous surveys for optical transients. Very little is known about these giant eruptions, their progenitors and their evolutionary state. A greatly improved census of the likely progenitor class, including the most luminous evolved stars, the luminous blue variables (LBVs), and the warm and cool hypergiants is now needed for a complete picture of the final pre-supernova stages of very massive stars. We have begun a survey of the evolved and unstable luminous star populations in several nearby resolved galaxies. In this second paper on M31 and M33, we review the spectral characteristics, spectral energy distributions, circumstellar ejecta, and evidence for mass loss for 82 luminous and variable stars. We show that many of these stars have warm circumstellar dust including several of the Fe II emission line stars, but conclude that the confirmed LBVs in M31 and M33 do not. The confirmed LBVs have relatively low wind speeds even in their hot, quiescent or visual minimum state compared to the B-type supergiants and Of/WN stars which they spectroscopically resemble. The nature of the Fe II emission line stars and their relation to the LBV state remains uncertain, but some have properties in common with the warm hypergiants and the sgB[e] stars. Several individual stars are discussed in detail. We identify three possible candidate LBVs and three additional post-red supergiant candidates. We suggest that M33-013406.63 (UIT301,B416) is not an LBV/S Dor variable, but is a very luminous late O-type supergiant and one of the most luminous stars or pair of stars in M33.

  3. Soft X-ray characterisation of the long-term properties of supergiant fast X-ray transients

    NASA Astrophysics Data System (ADS)

    Romano, P.; Ducci, L.; Mangano, V.; Esposito, P.; Bozzo, E.; Vercellone, S.

    2014-08-01

    Context. Supergiant fast X-ray transients (SFXTs) are high mass X-ray binaries (HMXBs) that are characterised by a hard X-ray (? 15 keV) flaring behaviour. These flares reach peak luminosities of 1036-1037 erg s-1 and last a few hours in the hard X-rays. Aims: We investigate the long-term properties of SFXTs by examining the soft (0.3-10 keV) X-ray emission of the three least active SFXTs in the hard X-ray and by comparing them with the remainder of the SFXT sample. Methods: We performed the first high-sensitivity soft X-ray long-term monitoring with Swift/XRT of three relatively unexplored SFXTs, IGR J08408-4503, IGR J16328-4726, and IGR J16465-4507, whose hard X-ray duty cycles are the lowest measured among the SFXT sample. We assessed how long each source spends in each flux state and compared their properties with those of the prototypical SFXTs. Results: The behaviour of IGR J08408-4503 and IGR J16328-4726 resembles that of other SFXTs, and it is characterised by a relatively high inactivity duty cycle (IDC) and pronounced dynamic range (DR) in the X-ray luminosity. We found DR ~ 7400, IDC ~ 67% for IGR J08408-4503, and DR ~ 750, IDC ~ 61% for IGR J16328-4726 (in all cases the IDC is given with respect to the limiting flux sensitivity of XRT, that is 1-3 10-12 erg cm-2 s-1). In common with all the most extreme SFXT prototypes (IGR J17544-2619, XTE J1739-302, and IGR J16479-4514), IGR J08408-4503 shows two distinct flare populations. The first one is associated with the brightest outbursts (X-ray luminosity LX ? 1035 - 36 erg s-1), while the second comprises dimmer events with typical luminosities of LX ? 1035 erg s-1. This double-peaked distribution of the flares as a function of the X-ray luminosity seems to be a ubiquitous feature of the extreme SFXTs. The lower DR of IGR J16328-4726 suggests that this is an intermediate SFXT. IGR J16465-4507 is characterised by a low IDC ~ 5% and a relatively narrow DR ~ 40, reminiscent of classical supergiant HMXBs. The duty cycles measured with XRT are found to be comparable with those reported previously by BAT and INTEGRAL, when the higher limiting sensitivities of these instruments are taken into account and sufficiently long observational campaigns are available. By making use of these new results and those we reported previously, we prove that no clear correlation exists between the duty cycles of the SFXTs and their orbital periods. Conclusions: The unique sensitivity and scheduling flexibility of Swift/XRT allowed us to carry out an efficient long-term monitoring of the SFXTs, following their activity across more than 4 orders of magnitude in X-ray luminosity. While it is not possible to exclude that particular distributions of the clump and wind parameters may produce double-peaked differential distributions in the X-ray luminosities of the SFXTs, the lack of a clear correlation between the duty cycles and orbital periods of these sources make it difficult to interpret their peculiar variability by only using arguments related to the properties of supergiant star winds. Our findings favour the idea that a correct interpretation of the SFXT phenomenology requires a mechanism to strongly reduce the mass accretion rate onto the compact object during most of its orbit around the companion, as proposed in a number of theoretical works. Tables 1-4 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/568/A55

  4. IGR J17544-2619 in Depth With Suzaku: Direct Evidence for Clumpy Winds in a Supergiant Fast X-ray Transient

    NASA Astrophysics Data System (ADS)

    Rampy, Rachel A.; Smith, David M.; Negueruela, Ignacio

    2009-12-01

    We present direct evidence for dense clumps of matter in the companion wind in a Supergiant Fast X-ray Transient (SFXT) binary. This is seen as a brief period of enhanced absorption during one of the bright, fast flares that distinguish these systems. The object under study was IGR J17544-2619, and a total of 236 ks of data were accumulated with the Japanese satellite Suzaku. The activity in this period spans a dynamic range of almost 104 in luminosity and gives a detailed look at SFXT behavior.

  5. A Suzaku X-ray Observation of One Orbit of the Supergiant Fast X-ray Transient IGR J16479-4514

    NASA Technical Reports Server (NTRS)

    Sidoli, L.; Esposito, P.; Sguera, V.; Bodaghee, A.; Tomsick, J. A.; Pottschmidt, K.; Rodriguez, J.; Ramano, P.; Wilms, J.

    2013-01-01

    We report on a 250 ks long X-ray observation of the supergiant fast X-ray transient (SFXT) IGR J16479-4514 performed with Suzaku in 2012 February. During this observation, about 80% of the short orbital period (P(sub orb) approximates 3.32 days) was covered as continuously as possible for the first time. The source light curve displays variability of more than two orders of magnitude, starting with a very low emission state (10(exp -13) erg / sq cm/s; 1-10 keV) lasting the first 46 ks, consistent with being due to the X-ray eclipse by the supergiant companion. The transition to the uneclipsed X-ray emission is energy dependent. Outside the eclipse, the source spends most of the time at a level of 6-7X10)(exp-12) erg/sq. cm/s) punctuated by two structured faint flares with a duration of about 10 and 15 ks, respectively, reaching a peak flux of 3-4X10(exp -11) erg/sq. cm./S, separated by about 0.2 in orbital phase. Remarkably, the first faint flare occurs at a similar orbital phase of the bright flares previously observed in the system. This indicates the presence of a phase-locked large scale structure in the supergiant wind, driving a higher accretion rate onto the compact object. The average X-ray spectrum is hard and highly absorbed, with a column density, NH, of 10*exp 23)/sq cm, clearly in excess of the interstellar absorption. There is no evidence for variability of the absorbing column density, except that during the eclipse, where a less absorbed X-ray spectrum is observed. A narrow Fe K-alpha emission line at 6.4 keV is viewed along the whole orbit, with an intensity which correlates with the continuum emission above 7 keV. The scattered component visible during the X-ray eclipse allowed us to directly probe the wind density at the orbital separation, resulting in rho(sub w)=7X10(exp -14) g/cubic cm. Assuming a spherical geometry for the supergiant wind, the derived wind density translates into a ratio M(sub w)/v(sub infinity) = 7X10(exp -17) Solar M/km which, assuming terminal velocities in a large range 500-3000 km/s, implies an accretion luminosity two orders of magnitude higher than that observed. As a consequence, a mechanism should be at work reducing the mass accretion rate. Different possibilities are discussed.

  6. Discovery and Characterization of Luminous Blue Variables, Wolf-Rayet Stars, and Massive Supergiants and Their Shells Using Spitzer, WISE, and Herschel Data

    NASA Astrophysics Data System (ADS)

    Stringfellow, Guy

    The extensive WISE all-sky 12 and 22 micron survey data, the Herschel PACS and SPIRE imaging archive (including the GTO and OT Key Programs), as well as the Spitzer IRAC 8 and MIPS 24 micron imaging archival data (GO, GTO, and Legacy Surveys) are being mined for the discovery of new shell and ring-nebulae. Combined with 2MASS data, the progenitor stars are also being identified, and optical and near-IR spectroscopy obtained to confirm their spectral types. Origin of the nebulae arise from a variety of progenitors that include very massive stars, with the vast majority not having been previously identified. Representative classes for the progenitor stars are Luminous Blue Variables (LBVs), Wolf-Rayet (WR), B[e], OB, and Supergiant stars. The discovery potential for these rare massive evolved stars from the mid-IR imaging archives is greater than any other technique utilized over the past several decades, including extensive broadband infrared photometry-color determinations (Hadfield et al. 2007), and near-IR narrowband methods (Shara et al. 2009). The statistics being provided on this new, previously hidden population of evolved stars may very well enable evolutionary pathways to be better delineated, thereby identifying the physics operating in these extreme stars. The data being collected will more tightly define the evolutionary models that apply to these stars, and that enter into modeling and interpretation of extragalactic massive star formation regions (starbursts). Multi-wavelength color-color maps wil be constructed and used to analyze the dust distribution, the energetics of the nebulae and its interaction with the ISM, and identification of nearby star formation perhaps being triggered by the massive stars and the nebulae they produce. As demonstrated in a recent publication presenting the discovery and analysis of two new candidate LBVs found in the early WISE data release (Gvaramadze et al. 2012), much discovery potential yet resides within the extensive WISE and Herschel imaging archives, which are just now beginning to be mined. We anticipate extensive new discoveries upon completion of the detailed inspection and analysis of these new imaging archival databases. Follow-up ground-based optical and/or near-IR spectroscopy is essential to confirm the nature of the progenitor stars and to investigate the composition and physical conditions present in the nebulae. This program directly relates to NASA Strategic Goals 3.4.2 and 3.4.3. The outbursts, winds, and the eventual explosion as supernovae all can impact the host stars of planetary systems, and affect the formation and survival of planets and substellar companions. Mass lost through the LBV evolution, including major shell ejection events, and the final eventual demise of these stars as supernovae will modify and enrich the chemical evolution of the interstellar medium and future generations of stars yet to form.

  7. Supermassive Star Clusters in Supergiant Galaxies: Tracing the Enrichment of the Earliest Stellar Systems

    NASA Astrophysics Data System (ADS)

    Harris, William

    2010-09-01

    The cD-type Brightest Cluster Galaxies contain the richest globular cluster systems {GCSs} that exist. The wealth of results gathered from previous HST imaging programs in many smaller galaxies show that GCSs are powerful and unique tracers that link to origin and evolution of structure in two directions simultaneously: one direction is inward to the structure of the protoglobular clouds, star formation in the densest known conditions, and their chemical enrichment history. The other direction is outward to constraining early galaxy formation history, the nature of the pregalactic dwarfs, or the spatial and dynamic structure of the halo. But we have not yet tapped the vast mine of GCS data waiting for exploitation in the most luminous galaxies of all, the cDs. Surprisingly, we know little about these systems beyond the globular cluster populations in the nearby cDs M87 {Virgo} and NGC 1399 {Fornax}, and these two cases no longer provide adequate tests of the new phenomena now being uncovered, such as the correlation between GC mass and metallicity, the strikingly different formation efficiencies of metal-poor and metal-rich clusters, the galaxy-to-galaxy differences in GC mass distribution, and connections to Ultra-Compact Dwarfs and dE nuclei.We propose to image 7 cD-type systems within 200 Mpc that are representative of the very biggest galaxies known {Mv < -23}. These lie in far richer Abell-cluster environments than we could ever probe in Virgo, Fornax, or nearer systems. We will use ACS/WFC and WFC3 to image their GCSs down to the turnover point of the GC luminosity function, using the B and I filters for an optimal combination of exposure time, field size, and metallicity sensitivity. Our complete survey will produce luminosities, metallicities, and spatial distribution functions for more than 35,000 GCs, the largest GC database in existence and an order of magnitude larger than even the recent Virgo Cluster Survey. The legacy value of our survey will supply a rich resource for a wide array of other GC science and the formation histories of these unique systems.

  8. GALEX AND PAN-STARRS1 DISCOVERY OF SN IIP 2010aq: THE FIRST FEW DAYS AFTER SHOCK BREAKOUT IN A RED SUPERGIANT STAR

    SciTech Connect

    Gezari, S.; Huber, M. E.; Grav, T.; Rest, A.; Narayan, G.; Forster, K.; Neill, J. D.; Martin, D. C.; Valenti, S.; Smartt, S. J.; Chornock, R.; Berger, E.; Soderberg, A. M.; Mattila, S.; Kankare, E.; Burgett, W. S.; Chambers, K. C.; Dombeck, T.; Heasley, J. N.; Hodapp, K. W.

    2010-09-01

    We present the early UV and optical light curve of Type IIP supernova (SN) 2010aq at z = 0.0862, and compare it to analytical models for thermal emission following SN shock breakout in a red supergiant star. SN 2010aq was discovered in joint monitoring between the Galaxy Evolution Explorer (GALEX) Time Domain Survey (TDS) in the NUV and the Pan-STARRS1 Medium Deep Survey (PS1 MDS) in the g, r, i, and z bands. The GALEX and Pan-STARRS1 observations detect the SN less than 1 day after the shock breakout, measure a diluted blackbody temperature of 31, 000 {+-} 6000 K 1 day later, and follow the rise in the UV/optical light curve over the next 2 days caused by the expansion and cooling of the SN ejecta. The high signal-to-noise ratio of the simultaneous UV and optical photometry allows us to fit for a progenitor star radius of 700 {+-} 200R {sub sun}, the size of a red supergiant star. An excess in UV emission two weeks after shock breakout compared with SNe well fitted by model atmosphere-code synthetic spectra with solar metallicity is best explained by suppressed line blanketing due to a lower metallicity progenitor star in SN 2010aq. Continued monitoring of PS1 MDS fields by the GALEX TDS will increase the sample of early UV detections of Type II SNe by an order of magnitude and probe the diversity of SN progenitor star properties.

  9. A FIVE-YEAR SPECTROSCOPIC AND PHOTOMETRIC CAMPAIGN ON THE PROTOTYPICAL {alpha} CYGNI VARIABLE AND A-TYPE SUPERGIANT STAR DENEB

    SciTech Connect

    Richardson, N. D.; Morrison, N. D.; Kryukova, E. E.; Adelman, S. J. E-mail: nmorris@utnet.utoledo.edu E-mail: adelmans@citadel.edu

    2011-01-15

    Deneb is often considered the prototypical A-type supergiant and is one of the visually most luminous stars in the Galaxy. A-type supergiants are potential extragalactic distance indicators, but the variability of these stars needs to be better characterized before this technique can be considered reliable. We analyzed 339 high-resolution echelle spectra of Deneb obtained over the five-year span of 1997 through 2001 as well as 370 Stroemgren photometric measurements obtained during the same time frame. Our spectroscopic analysis included dynamical spectra of the H{alpha} profile, H{alpha} equivalent widths, and radial velocities measured from Si II {lambda}{lambda} 6347, 6371. Time-series analysis reveals no obvious cyclic behavior that proceeds through multiple observing seasons, although we found a suspected 40 day period in two, non-consecutive observing seasons. Some correlations are found between photometric and radial velocity data sets and suggest radial pulsations at two epochs. No correlation is found between the variability of the H{alpha} profiles and that of the radial velocities or the photometry. Lucy found evidence that Deneb was a long-period single-lined spectroscopic binary star, but our data set shows no evidence for radial velocity variations caused by a binary companion.

  10. GALEX and Pan-STARRS1 Discovery of SN IIP 2010aq: The First Few Days After Shock Breakout in a Red Supergiant Star

    NASA Astrophysics Data System (ADS)

    Gezari, S.; Rest, A.; Huber, M. E.; Narayan, G.; Forster, K.; Neill, J. D.; Martin, D. C.; Valenti, S.; Smartt, S. J.; Chornock, R.; Berger, E.; Soderberg, A. M.; Mattila, S.; Kankare, E.; Burgett, W. S.; Chambers, K. C.; Dombeck, T.; Grav, T.; Heasley, J. N.; Hodapp, K. W.; Jedicke, R.; Kaiser, N.; Kudritzki, R.; Luppino, G.; Lupton, R. H.; Magnier, E. A.; Monet, D. G.; Morgan, J. S.; Onaka, P. M.; Price, P. A.; Rhoads, P. H.; Siegmund, W. A.; Stubbs, C. W.; Tonry, J. L.; Wainscoat, R. J.; Waterson, M. F.; Wynn-Williams, C. G.

    2010-09-01

    We present the early UV and optical light curve of Type IIP supernova (SN) 2010aq at z = 0.0862, and compare it to analytical models for thermal emission following SN shock breakout in a red supergiant star. SN 2010aq was discovered in joint monitoring between the Galaxy Evolution Explorer (GALEX) Time Domain Survey (TDS) in the NUV and the Pan-STARRS1 Medium Deep Survey (PS1 MDS) in the g, r, i, and z bands. The GALEX and Pan-STARRS1 observations detect the SN less than 1 day after the shock breakout, measure a diluted blackbody temperature of 31, 000 6000 K 1 day later, and follow the rise in the UV/optical light curve over the next 2 days caused by the expansion and cooling of the SN ejecta. The high signal-to-noise ratio of the simultaneous UV and optical photometry allows us to fit for a progenitor star radius of 700 200R sun, the size of a red supergiant star. An excess in UV emission two weeks after shock breakout compared with SNe well fitted by model atmosphere-code synthetic spectra with solar metallicity is best explained by suppressed line blanketing due to a lower metallicity progenitor star in SN 2010aq. Continued monitoring of PS1 MDS fields by the GALEX TDS will increase the sample of early UV detections of Type II SNe by an order of magnitude and probe the diversity of SN progenitor star properties.

  11. Anomaly distribution of quasar magnitudes: a test of lensing by a hypothetic supergiant molecular cloud in the Galactic halo

    NASA Astrophysics Data System (ADS)

    Giraud, E.

    2012-07-01

    Context. An anomaly in the distribution of quasar magnitudes based on the Sloan Digital Sky survey, was reported by Longo. The angular size of this quasar anomaly is on the order of ±15° on the sky. A smooth low surface brightness structure detected in γ-rays and at 408 MHz, coincides with the sky location and extent of the anomaly, and is close to the northern component of a pair of γ-ray bubbles discovered in the Fermi Gamma-ray Space Telescope survey. Molecular clouds are thought to be illuminated by cosmic rays. Molecular gas in the Galaxy, in the form of cold H2, may be a significant component of dark matter as suggested by Pfenniger et al. Aims: I test the hypothesis that the magnitude anomaly in the quasar distribution, is due to lensing by a hypothetical supergiant molecular cloud (SGMC) either in or falling into the Galactic halo. Methods: A series of grid lens models are built by assuming that a SGMC is a fractal structure constructed with clumps of 10-3 M⊙, 10 AU in size, and considering various fractal dimensions. Local amplifications are computed by using the single-plane approximation. Results: A complex network of caustics due to the clumpy structure is present. Our best single plane lens model capable of explaining Longo's effect, at least in sparse regions, requires a mass (1.5-4.1) × 1010 M⊙ within 8.7 × 8.7 × (5-8.6) kpc3 at a lens plane distance of 20 kpc, and is constructed from a molecular-cloud building-block of 5 × 105 M⊙ within a scale of 30 pc expanded by fractal scaling with dimension D = 1.8-2 out to 5-8.6 kpc for the SGMC. The mass budget depends on the cloud depth and on the fractal dimension. Conclusions: If such a SGMC were found to exist, it may provide at least part of a lensing explanation for the luminous anomaly discovered in quasars and red galaxies.

  12. Wind Variability of B Supergiants. No. 1; The Rapid Rotator HD 64760 (B0.5 Ib)

    NASA Technical Reports Server (NTRS)

    Massa, Derck; Prinja, Raman K.; Fullerton, Alexander W.

    1995-01-01

    We present the results of a 6 day time series of observations of the rapidly rotating B0.5 Ib star HD 64760. We point out several reasons why such intermediate luminosity B supergiants are ideal targets for wind variability studies and then present our results that show the following: continuous wind activity throughout the 6 day run with the wind never in steady state for more than a few hr; wind variability very near nu = 0 km sec(exp -1) in the resonance lines from the lower ionization stages (Al III and C II); a distinct correlation between variability in the Si III ; lambda(lambda)1300 triplets, the strong C III (lambda)1247 singlet, and the onset of extremely strong wind activity, suggesting a connection between photospheric and wind activity; long temporal coherence in the behavior of the strong absorption events; evidence for large-scale spatial coherence, implied by a whole scale, simultaneous weakening in the wind absorption over a wide range in velocities; and ionization variability in the wind accompanying the largest changes in the absorption strengths of the wind lines. In addition, modeling of the wind lines provides the following information about the state the wind in HD 64760. The number of structures on the portion of a constant velocity surface occulting the stellar disk at a particular time must be quite small, while the number on the entire constant velocity surface throughout the wind must be large. The escape probability at low velocity is overestimated by a normal beta approx. 1 velocity law, perhaps due to the presence of low-velocity shocks deep in the wind or a shallow velocity gradient at low velocity. Estimates of the ionization structure in the wind indicate that the ionization ratios are not those expected from thermal equilibrium wind models or from an extrapolation of previous O star results. The large observed q(N V)/q(Si IV) ratio is almost certainly due to distributed X-rays, but the level of ionization predicted by distributed X-ray wind models is inconsistent with the predicted mass-loss rate. Thus, it is impossible to reconcile the observed ionization ratios and the predicted mass-loss rate within the framework of the available models.

  13. Photometry of the Variable Bright Red Supergiant Betelgeuse from the Ground and from Space with the BRITE Nano-satellites

    NASA Astrophysics Data System (ADS)

    Minor, Robert; Guinan, Edward F.

    2016-01-01

    Robert B. Minor, Edward Guinan, Richard Wasatonic Betelgeuse (Alpha Orionis) is a large, luminous semi-regular red supergiant of spectral class M1.5-2Iab. It is the 8th brightest star in the night sky. Betelgeuse is 30,000 times more luminous than the Sun and 700 times larger. It has an estimated age of ~8 +/- 2 Myr. Betelgeuse explode in a Type II supernova (anytime within the next million years). When it explodes, it will shine with about the intensity of a full moon and may be visible during the day. However, it is too far away to cause any major damage to Earth. Photometry of this pre-supernova star has been ongoing at Villanova for nearly 45 years. These observations are being used to define the complex brightness variations of this star. Semi-regular periodic light variations have been found with periods of 385 days up to many years. These light variations are used to study its unstable atmosphere and resulting complex pulsations. Over the last 15 years, it has been observed by Wasatonic who has accumulated a large photometric database. The ground-based observations are limited to precisions of 1.5%, and due to poor weather, limit observations to about 1-2 times per week. However, with the recent successful launch of the BRITE Nano-satellites (http://www.brite-constellation.at) during 2013-14, it is possible to secure high precision photometry of bright stars, including Betelgeuse, continuously for up to 3 months. Villanova has participated in the BRITE guest investigators program and has been awarded observing time and data rights many bright stars, including Betelgeuse. BRITE blue and red observations of Betelgeuse were carried out during the Nov-Feb 2013-14 season and the 2014-15. These datasets were given to Villanova and have been combined with coexistent photometry from Wasatonic. Although BRITE's red data is saturated, the blue data is useable. The BRITE datasets were combined with our ground-based V, red, and near-IR photometry. Problems were uncovered with the some of the BRITE data, but they were resolved for the most part. We present and discuss the results obtained so far.

  14. The atmospheric structure and fundamental parameters of the red supergiants AH Scorpii, UY Scuti, and KW Sagittarii

    NASA Astrophysics Data System (ADS)

    Arroyo-Torres, B.; Wittkowski, M.; Marcaide, J. M.; Hauschildt, P. H.

    2013-06-01

    Aims: We present the atmospheric structure and the fundamental properties of the red supergiants (RSGs) AH Sco, UY Sct, and KW Sgr based on VLTI/AMBER observations. Methods: We carried out spectro-interferometric observations of AH Sco, UY Sct, and KW Sgr in the near-infrared K band (1.92-2.47 ?m) with the VLTI/AMBER instrument with spatial and spectral resolutions of 3 milliarcsec and 1500, respectively, and compared the data to a new grid of hydrostatic PHOENIX model atmospheres. Results: In our visibility data, we observe molecular layers of water and CO in extended atmospheres. For a uniform disk modeling, we observe size increases at the water band centered at 1.9 ?m of 10% to 25% and at the CO bandheads at 2.3-2.5 ?m of 20%-35% with respect to the near-continuum bandpass at around 2.20 ?m. Our near-infrared spectra of AH Sco, UY Sct, and KW Sgr are well reproduced by the PHOENIX model atmospheres. The continuum visibility values are consistent with a limb-darkened disk as predicted by the PHOENIX models. However, the model visibilities do not predict the large observed extensions of the molecular layers. Comparing the continuum visibility values to PHOENIX models, we estimate the Rosseland-mean photospheric angular diameters of AH Sco, UY Sct, and KW Sgr to be 5.81 0.15 mas, 5.48 0.10 mas, and 3.91 0.25 mas, respectively. Together with the distance and the spectro-photometry, we calculate radii of 1411 124 R? for AH Sco, 1708 192 R? for UY Sct, and 1009 142 R? for KW Sgr and effective temperatures of 3682 190 K for AH Sco, 3365 134 K for UY Sct, and 3720 183 K for KW Sgr. Conclusions: AH Sco, UY Sct, and KW Sgr exhibit extended atmospheric layers of H2O and CO. The PHOENIX atmosphere models predict the spectra and the continuum visibility values, but cannot reproduce the large extensions of the molecular layers. This indicates that the opacities of the molecular bands are included, but that the model atmospheres are too compact compared to the observations. The observed extended layers may be levitated by processes such as pulsation or convection, which are not included in the hydrostatic atmospheric models. The location of the targets in the HR-diagram is confirmed to be close to, and possibly slightly to the right of, the Hayashi limit of recent evolutionary tracks corresponding to masses between about 20 M? and 40 M?.

  15. Luminous and Variable Stars in M31 and M33. II. Luminous Blue Variables, Candidate LBVs, Fe II Emission Line Stars, and Other Supergiants

    NASA Astrophysics Data System (ADS)

    Humphreys, Roberta M.; Weis, Kerstin; Davidson, Kris; Bomans, D. J.; Burggraf, Birgitta

    2014-07-01

    An increasing number of non-terminal eruptions are being found in the numerous surveys for optical transients. Very little is known about these giant eruptions, their progenitors and their evolutionary state. A greatly improved census of the likely progenitor class, including the most luminous evolved stars, the luminous blue variables (LBVs), and the warm and cool hypergiants is now needed for a complete picture of the final pre-supernova stages of very massive stars. We have begun a survey of the evolved and unstable luminous star populations in several nearby resolved galaxies. In this second paper on M31 and M33, we review the spectral characteristics, spectral energy distributions, circumstellar ejecta, and evidence for mass loss for 82 luminous and variable stars. We show that many of these stars have warm circumstellar dust including several of the Fe II emission line stars, but conclude that the confirmed LBVs in M31 and M33 do not. The confirmed LBVs have relatively low wind speeds even in their hot, quiescent or visual minimum state compared to the B-type supergiants and Of/WN stars which they spectroscopically resemble. The nature of the Fe II emission line stars and their relation to the LBV state remains uncertain, but some have properties in common with the warm hypergiants and the sgB[e] stars. Several individual stars are discussed in detail. We identify three possible candidate LBVs and three additional post-red supergiant candidates. We suggest that M33-013406.63 (UIT301,B416) is not an LBV/S Dor variable, but is a very luminous late O-type supergiant and one of the most luminous stars or pair of stars in M33. Based on observations with the Multiple Mirror Telescope, a joint facility of the Smithsonian Institution and the University of Arizona and on observations obtained with the Large Binocular Telescope (LBT), an international collaboration among institutions in the United States, Italy and Germany. LBT Corporation partners are: The University of Arizona on behalf of the Arizona university system; Istituto Nazionale di Astrofisica, Italy; LBT Beteiligungsgesellschaft, Germany, representing the Max-Planck Society, the Astrophysical Institute Potsdam, and Heidelberg University; The Ohio State University, and The Research Corporation, on behalf of The University of Notre Dame, University of Minnesota and University of Virginia.

  16. The circumstellar environment and evolutionary state of the supergiant B[e] star Wd1-9

    NASA Astrophysics Data System (ADS)

    Clark, J. S.; Ritchie, B. W.; Negueruela, I.

    2013-12-01

    Context. Historically, supergiant (sg)B[e] stars have been difficult to include in theoretical schemes for the evolution of massive OB stars. Aims: The location of Wd1-9 within the coeval starburst cluster Westerlund 1 means that it may be placed into a proper evolutionary context and we therefore aim to utilise a comprehensive multiwavelength dataset to determine its physical properties and consequently its relation to other sgB[e] stars and the global population of massive evolved stars within Wd1. Methods: Multi-epoch R- and I-band VLT/UVES and VLT/FORS2 spectra are used to constrain the properties of the circumstellar gas, while an ISO-SWS spectrum covering 2.45-45 ?m is used to investigate the distribution, geometry and composition of the dust via a semi-analytic irradiated disk model. Radio emission enables a long term mass-loss history to be determined, while X-ray observations reveal the physical nature of high energy processes within the system. Results: Wd1-9 exhibits the rich optical emission line spectrum that is characteristic of sgB[e] stars. Likewise its mid-IR spectrum resembles those of the LMC sgB[e] stars R66 and 126, revealing the presence of equatorially concentrated silicate dust, with a mass of ~10-4 M?. Extreme historical and ongoing mass loss (?10-4 M? yr-1) is inferred from the radio observations. The X-ray properties of Wd1-9 imply the presence of high temperature plasma within the system and are directly comparable to a number of confirmed short-period colliding wind binaries within Wd1. Conclusions: The most complete explanation for the observational properties of Wd1-9 is that it is a massive interacting binary currently undergoing, or recently exited from, rapid Roche-lobe overflow, supporting the hypothesis that binarity mediates the formation of (a subset of) sgB[e] stars. The mass loss rate of Wd1-9 is consistent with such an assertion, while viable progenitor and descendent systems are present within Wd1 and comparable sgB[e] binaries have been identified in the Galaxy. Moreover, the rarity of sgB[e] stars - only two examples are identified from a census of ~68 young massive Galactic clusters and associations containing ~600 post-Main Sequence stars - is explicable given the rapidity (~104 yr) expected for this phase of massive binary evolution. This work is based on observations collected at the European Southern Observatory, Paranal (programme IDs ESO 087.D-0355, 087.D-0440, 087.D-0673, and 073.D-0327) and uses the ISO-SWS database of Sloan et al. (2003).Table 1 and Appendix A are available in electronic form at http://www.aanda.org

  17. A study of several F and G supergiant-like stars with infrared excesses as candidates for proto-planetary nebulae

    NASA Technical Reports Server (NTRS)

    Hrivnak, Bruce J.; Kwok, Sun; Volk, Kevin M.

    1989-01-01

    Ground-based observations have been obtained for eight F and G supergiant-like stars showing large IR excesses. The combination of ground-based and IRAS data shows that these objects have dual-peak energy distributions, with comparable amounts of energy emitted in the visible and the IR. The IR-emitting cool dust shells are likely to represent the remnants of ejecta from an earlier phase of evolution. It is suggested that these eight objects are similar to IRAS 18095 + 2704 and are intermediate-mass stars in a post-AGB phase of evolution. Model fittings to the 0.4-100 micron energy distribution of these objects suggest that they left the AGB within the last 1000 yr.

  18. NuSTAR Detection of a Cyclotron Line in the Supergiant Fast X-Ray Transient IGR J17544-2619

    NASA Technical Reports Server (NTRS)

    Bhalerao, Varun; Romano, Patrizia; Tomsick, John; Natalucci, Lorenzo; Smith, David M.; Bellm, Eric; Boggs, Steven E.; Chakrabarty, Deepto; Christensen, Finn E.; Zhang, William

    2015-01-01

    We present NuSTAR spectral and timing studies of the supergiant fast X-ray transient (SFXT) IGR J17544-2619. The spectrum is well described by an approximately1 keV blackbody and a hard continuum component, as expected from an accreting X-ray pulsar. We detect a cyclotron line at 17 keV, confirming that the compact object in IGR J17544-2619 is indeed a neutron star. This is the first measurement of the magnetic field in an SFXT. The inferred magnetic field strength, B = (1.45 +/- 0.03) × 10(exp 12) G (1 + z) is typical of neutron stars in X-ray binaries, and rules out a magnetar nature for the compact object. We do not find any significant pulsations in the source on time-scales of 1-2000 s.

  19. Ultraviolet observations of close-binary and pulsating nuclei of planetary nebulae; Winds and shells around low-mass supergiants; The close-binary nucleus of the planetary nebula HFG-1; A search for binary nuclei of planetary nebulae; UV monitoring of irregularly variable planetary nuclei; and The pulsating nucleus of the planetary nebula Lo 4

    NASA Technical Reports Server (NTRS)

    Bond, Howard E.

    1992-01-01

    A brief summary of the research highlights is presented. The topics covered include the following: binary nuclei of planetary nebulae; other variable planetary nuclei; low-mass supergiants; and other IUE-related research.

  20. Chemical Emergencies

    MedlinePLUS

    When a hazardous chemical has been released, it may harm people's health. Chemical releases can be unintentional, as in the case of an ... the case of a terrorist attack with a chemical weapon. Some hazardous chemicals have been developed by ...

  1. Chemical Peels

    MedlinePLUS

    ... Z Diseases and treatments A - D Chemical peel Chemical peels Also called chemexfoliation , derma peeling Do you ... the cost of cosmetic treatments. Learn more about chemical peels: Is a chemical peel the right choice ...

  2. Theory of spots on chemically peculiar stars

    NASA Astrophysics Data System (ADS)

    Shulyak, D.

    2014-09-01

    Surface inhomogeneities are found in many stars. In active sun-like stars and cool giants temperature spots similar to that found in the Sun are recovered from the inversion of spectroscopic data. M-dwarfs also show highly inhomogeneous surface structures in polarized light and photometric variability that are believed to be connected with cool regions on their surface, too. Supergiants have highly inhomogeneous atmospheres because large convective cells, and therefore bright and dark regions, have sizes comparable to the size of stars themselves. Hot luminous stars can have dense clamps in their atmospheres caused by an interaction of fast stellar wind, rotation, and the magnetic fields. Finally, a special class of main-sequence B-F stars, called chemically peculiar stars, have spots of abundance origin. Spots in these stars can look bright or dark depending on wavelength of observation. Modern interferometry is capable of reaching a very high angular resolution that will make it possible to study starspots in very detail. In this review we will focus on starspots in general and abundance spots in chemically peculiar stars in particular, as well as possible application of interferometry to study them.

  3. DISTANCE AND PROPER MOTION MEASUREMENT OF THE RED SUPERGIANT, PZ CAS, IN VERY LONG BASELINE INTERFEROMETRY H{sub 2}O MASER ASTROMETRY

    SciTech Connect

    Kusuno, K.; Asaki, Y.; Imai, H.; Oyama, T. E-mail: asaki@vsop.isas.jaxa.jp E-mail: t.oyama@nao.ac.jp

    2013-09-10

    We present the very long baseline interferometry H{sub 2}O maser monitoring observations of the red supergiant, PZ Cas, at 12 epochs from 2006 April to 2008 May. We fitted maser motions to a simple model composed of a common annual parallax and linear motions of the individual masers. The maser motions with the parallax subtracted were well modeled by a combination of a common stellar proper motion and a radial expansion motion of the circumstellar envelope. We obtained an annual parallax of 0.356 {+-} 0.026 mas and a stellar proper motion of {mu}{sub {alpha}}{sup *} cos {delta} = -3.7 {+-} 0.2 and {mu}{sup *}{sub {delta}}=-2.0{+-}0.3 mas yr{sup -1} eastward and northward, respectively. The annual parallax corresponds to a trigonometric parallax of 2.81{sup +0.22}{sub -0.19} kpc. By rescaling the luminosity of PZ Cas in any previous studies using our trigonometric parallax, we estimated the location of PZ Cas on a Hertzsprung-Russell diagram and found that it approaches a theoretically evolutionary track around an initial mass of {approx}25 M{sub Sun }. The sky position and the distance to PZ Cas are consistent with the OB association, Cas OB5, which is located in a molecular gas super shell. The proper motion of PZ Cas is close to that of the OB stars and other red supergiants in Cas OB5 measured by the Hipparcos satellite. We derived the peculiar motion of PZ Cas of U{sub s} = 22.8 {+-} 1.5, V{sub s} = 7.1 {+-} 4.4, and W{sub s} = -5.7 {+-} 4.4 km s{sup -1}. This peculiar motion has rather a large U{sub s} component, unlike those of near high-mass star-forming regions with negatively large V{sub s} motions. The uniform proper motions of the Cas OB5 member stars suggest random motions of giant molecular clouds moving into local potential minima in a time-dependent spiral arm, rather than a velocity field caused by the spiral arm density wave.

  4. Hiding in plain sight - red supergiant imposters? Super-AGB stars - bridging the divide between low/intermediate-mass and high-mass stars

    NASA Astrophysics Data System (ADS)

    Doherty, Carolyn Louise; Gil-Pons, Pilar; Lattanzio, John; Siess, Lionel

    2015-08-01

    Super Asymptotic Giant Branch (Super-AGB) stars reside in the mass range ~ 6.5-10 M? and bridge the divide between low/intermediate-mass and massive stars. They are characterised by off-centre carbon ignition prior to a thermally pulsing phase which can consist of many tens to even thousands of thermal pulses. With their high luminosities and very large, cool, red stellar envelopes, these stars appear seemingly identical to their slightly more massive red supergiant counterparts. Due to their similarities, super-AGB stars may therefore act as stellar imposters and contaminate red supergiant surveys. Super-AGB stars undergo relatively extreme nucleosynthetic conditions, with very efficient proton-capture nucleosynthesis occurring at the base of the convective envelope and also heavy element (s-process) production during the thermal pulse to be later mixed to the surface during third dredge-up events. The surface enrichment from these two processes may result in a clear nucleosynthetic signature to differentiate these two classes of star.The final fate of super-AGB stars is also quite uncertain and depends primarily on the competition between the core growth and mass-loss rates. If the stellar envelope is removed prior to the core reaching the Chandrasekhar mass, an O-Ne white dwarf will remain, otherwise the star will undergo an electron-capture supernova leaving behind a neutron star. We describe the factors which influence these different final fate channels, such as the efficiency of convection, the mass-loss rates, the third dredge-up efficiency and the Fe-peak opacity instability which may lead to expulsion of the entire remaining stellar envelope. We determine the relative fraction of super-AGB stars that end life as either an O-Ne white dwarf or as a neutron star, and provide a mass limit for the lowest mass supernova over a broad range of metallicities from the earliest time (Z=0) right through until today (Z~0.04).

  5. Obama Finding Teacher Support Secure, If Tepid: Policy Rifts Complicate Obama-Teacher Dance

    ERIC Educational Resources Information Center

    Klein, Alyson

    2012-01-01

    Ask Antonio White what he thinks of Race to the Top--President Barack Obama's signature K-12 initiative--and the Florida teacher will tell you the competitive-grant program is a "difficult pill to swallow." Merit pay for teachers based partly on student test scores is "a joke," he says. He's also not a fan of expanding charter schools, or of U.S.

  6. SUZAKU OBSERVES WEAK FLARES FROM IGR J17391-3021 REPRESENTING A COMMON LOW-ACTIVITY STATE IN THIS SUPERGIANT FAST X-RAY TRANSIENT

    SciTech Connect

    Bodaghee, A.; Tomsick, J. A.; Rodriguez, J.; Chaty, S.; Walter, R.; Romano, P.

    2011-01-20

    We present an analysis of a 37 ks observation of the supergiant fast X-ray transient IGR J17391-3021 (= XTE J1739-302) gathered with Suzaku. The source evolved from quiescence to a low-activity level culminating in three weak flares lasting {approx}3 ks each in which the peak luminosity is only a factor of five times that of the pre-flare luminosity. The minimum observed luminosity was 1.3 x 10{sup 33} erg s{sup -1}(d/2.7 kpc){sup 2} in the 0.5-10 keV range. The weak flares are accompanied by significant changes in the spectral parameters including a column density (N{sub H} =(4.1{sup +0.4}{sub -0.5}) x 10{sup 22} cm{sup -2}) that is {approx}2-9 times the absorption measured during quiescence. Accretion of obscuring clumps of stellar wind material can explain both the small flares and the increase in N{sub H}. Placing this observation in the context of the recent Swift monitoring campaign, we find that weak-flaring episodes, or at least epochs of enhanced activity just above the quiescent level but well below the moderately bright or high-luminosity outbursts, represent more than 60% {+-} 5% of all observations in the 0.5-10 keV energy range making this the most common state in the emission behavior of IGR J17391-3021.

  7. DUST PRODUCTION FACTORIES IN THE EARLY UNIVERSE: FORMATION OF CARBON GRAINS IN RED-SUPERGIANT WINDS OF VERY MASSIVE POPULATION III STARS

    SciTech Connect

    Nozawa, Takaya; Yoon, Sung-Chul; Maeda, Keiichi; Kozasa, Takashi; Nomoto, Ken'ichi; Langer, Norbert

    2014-06-01

    We investigate the formation of dust in a stellar wind during the red-supergiant (RSG) phase of a very massive Population III star with a zero-age main sequence mass of 500 M {sub ☉}. We show that, in a carbon-rich wind with a constant velocity, carbon grains can form with a lognormal-like size distribution, and that all of the carbon available for dust formation finally condenses into dust for wide ranges of the mass-loss rate ((0.1-3) × 10{sup –3} M {sub ☉} yr{sup –1}) and wind velocity (1-100 km s{sup –1}). We also find that the acceleration of the wind, driven by newly formed dust, suppresses the grain growth but still allows more than half of the gas-phase carbon to finally be locked up in dust grains. These results indicate that, at most, 1.7 M {sub ☉} of carbon grains can form during the RSG phase of 500 M {sub ☉} Population III stars. Such a high dust yield could place very massive primordial stars as important sources of dust at the very early epoch of the universe if the initial mass function of Population III stars was top-heavy. We also briefly discuss a new formation scenario of carbon-rich ultra-metal-poor stars, considering feedback from very massive Population III stars.

  8. Infrared Space Observatory Observations of Far-Infrared Rotational Emission Lines of Water Vapor Toward the Supergiant Star VY Canis Majoris

    NASA Technical Reports Server (NTRS)

    Neufeld, David A.; Feuchtgruber, Helmut; Harwit, Martin; Melnick, Gary J.

    1999-01-01

    We report the detection of numerous far-infrared emission lines of water vapor toward the supergiant star VY Canis Majoris. A 29.5-45 micron grating scan of VY CMa, obtained using the Short-Wavelength Spectrometer (SWS) of the Infrared Space Observatory at a spectral resolving power lambda/delat.lambda of approximately 2000, reveals at least 41 spectral features due to water vapor that together radiate a total luminosity of approximately 25 solar luminosity . In addition to pure rotational transitions within the ground vibrational state, these features include rotational transitions within the (010) excited vibrational state. The spectrum also shows the (sup 2)product(sub 1/2) (J = 5/2) left arrow (sup 2)product(sub 3/2) (J = 3/2) OH feature near 34.6 micron in absorption. Additional SWS observations of VY CMa were carried out in the instrument's Fabry-Perot mode for three water transitions: the 7(sub 25)-6(sub 16) line at 29.8367 micron, the 4(sub 41)-3(sub 12) line at 31.7721 micron, and the 4(sub 32)-3(sub 03) line at 40.6909 micron. The higher spectral resolving power lambda/delta.lambda of approximately 30,000 thereby obtained permits the line profiles to be resolved spectrally for the first time and reveals the "P Cygni" profiles that are characteristic of emission from an outflowing envelope.

  9. The Contribution of Thermally-Pulsing Asymptotic Giant Branch and Red Supergiant Starts to the Luminosities of the Magellanic Clouds at 1-24 micrometers

    NASA Technical Reports Server (NTRS)

    Melbourne, J.; Boyer, Martha L.

    2013-01-01

    We present the near-through mid-infrared flux contribution of thermally-pulsing asymptotic giant branch (TP-AGB) and massive red supergiant (RSG) stars to the luminosities of the Large and Small Magellanic Clouds (LMC and SMC, respectively). Combined, the peak contribution from these cool evolved stars occurs at approx 3 - 4 micron, where they produce 32% of the SMC light, and 25% of the LMC flux. The TP-AGB star contribution also peaks at approx 3 - 4 micron and amounts to 21% in both galaxies. The contribution from RSG stars peaks at shorter wavelengths, 2.2 micron, where they provide 11% of the SMC flux, and 7% for the LMC. Both TP-AGB and RSG stars are short lived, and thus potentially impose a large stochastic scatter on the near-IR derived mass-to-light (M/L) ratios of galaxies at rest-frame 1 - 4 micron. To minimize their impact on stellar mass estimates, one can use the M/L ratio at shorter wavelengths (e.g., at 0.8 - 1 micron). At longer wavelengths (much > 8 micron), emission from dust in the interstellar medium dominates the flux. In the LMC, which shows strong polycyclic aromatic hydrocarbon (PAH) emission at 8 micron, TP-AGB and RSG contribute less than 4% of the 8 micron flux. However, 19% of the SMC 8 micron flux is from evolved stars, nearly half of which is produced by the rarest, dustiest, carbon-rich TP-AGB stars. Thus, star formation rates of galaxies, based on an 8 micron flux (e.g., observed-frame 24 micron at z = 2), may be biased modestly high, especially for galaxies with little PAH emission.

  10. Aperture Synthesis Observations of CO, HCN, and 89 GHz Continuum Emission Toward NGC 604 in M33: Sequential Star Formation Induced by a Supergiant H II Region

    NASA Astrophysics Data System (ADS)

    Miura, Rie; Okumura, Sachiko K.; Tosaki, Tomoka; Tamura, Yoichi; Kurono, Yasutaka; Kuno, Nario; Nakanishi, Kouichiro; Sakamoto, Seiichi; Hasegawa, Takashi; Kawabe, Ryohei

    2010-12-01

    We present the results from new Nobeyama Millimeter Array observations of CO(1-0), HCN(1-0), and 89 GHz continuum emission toward NGC 604, known as the supergiant H II region in the nearby galaxy M33. Our high spatial resolution images (4farcs2 2farcs6, corresponding to 17 pc 11 pc physical size) of CO emission allowed us to uncover 10 individual molecular clouds that have masses of (0.8-7.4) 105 M sun and sizes of 5-29 pc, comparable to those of typical Galactic giant molecular clouds. Moreover, we detected for the first time HCN emission in the two most massive clouds and 89 GHz continuum emission at the rims of the "H? shells." The HCN and 89 GHz continuum emission are offset from the CO peak and are distributed in the direction of the central cluster. Three out of ten CO clouds are well correlated with the H? shells both in spatial and velocity domains, implying an interaction between molecular gas and the expanding H II region. The CO clouds show varieties in star formation efficiencies (SFEs), which are estimated from the 89 GHz emission and combination of H? and Spitzer 24 ?m data. Furthermore, we found that the SFEs decrease with increasing projected distance measured from the heart of the central OB star cluster in NGC 604, suggesting radial changes in the evolutionary stages of the molecular clouds in the course of stellar cluster formation. Our results provide further support to the picture of sequential star formation in NGC 604 initially proposed by Tosaki et al. with the higher spatially resolved molecular clouds, in which an isotropic expansion of the H II region pushes gases outward, which accumulates to form dense molecular clouds, and then induces massive star formations.

  11. Long-lasting X-ray emission from type IIb supernova 2011dh and mass-loss history of the yellow supergiant progenitor

    SciTech Connect

    Maeda, Keiichi; Katsuda, Satoru; Bamba, Aya; Terada, Yukikatsu; Fukazawa, Yasushi

    2014-04-20

    Type IIb supernova (SN) 2011dh, with conclusive detection of an unprecedented yellow supergiant (YSG) progenitor, provides an excellent opportunity to deepen our understanding on the massive star evolution in the final centuries toward the SN explosion. In this paper, we report on detection and analyses of thermal X-ray emission from SN IIb 2011dh at ∼500 days after the explosion on Chandra archival data, providing a solidly derived mass-loss rate of a YSG progenitor for the first time. We find that the circumstellar media should be dense, more than that expected from a Wolf-Rayet (W-R) star by one order of magnitude. The emission is powered by a reverse shock penetrating into an outer envelope, fully consistent with the YSG progenitor but not with a W-R progenitor. The density distribution at the outermost ejecta is much steeper than that expected from a compact W-R star, and this finding must be taken into account in modeling the early UV/optical emission from SNe IIb. The derived mass-loss rate is ∼3 × 10{sup –6} M {sub ☉} yr{sup –1} for the mass-loss velocity of ∼20 km s{sup –1} in the final ∼1300 yr before the explosion. The derived mass-loss properties are largely consistent with the standard wind mass-loss expected for a giant star. This is not sufficient to be a main driver to expel nearly all the hydrogen envelope. Therefore, the binary interaction, with a huge mass transfer having taken place at ≳ 1300 yr before the explosion, is a likely scenario to produce the YSG progenitor.

  12. APERTURE SYNTHESIS OBSERVATIONS OF CO, HCN, AND 89 GHz CONTINUUM EMISSION TOWARD NGC 604 IN M33: SEQUENTIAL STAR FORMATION INDUCED BY A SUPERGIANT H II REGION

    SciTech Connect

    Miura, Rie; Okumura, Sachiko K.; Kurono, Yasutaka; Nakanishi, Kouichiro; Tosaki, Tomoka; Tamura, Yoichi; Kuno, Nario; Kawabe, Ryohei; Sakamoto, Seiichi; Hasegawa, Takashi

    2010-12-01

    We present the results from new Nobeyama Millimeter Array observations of CO(1-0), HCN(1-0), and 89 GHz continuum emission toward NGC 604, known as the supergiant H II region in the nearby galaxy M33. Our high spatial resolution images (4.''2 x 2.''6, corresponding to 17 pc x 11 pc physical size) of CO emission allowed us to uncover 10 individual molecular clouds that have masses of (0.8-7.4) x10{sup 5} M{sub sun} and sizes of 5-29 pc, comparable to those of typical Galactic giant molecular clouds. Moreover, we detected for the first time HCN emission in the two most massive clouds and 89 GHz continuum emission at the rims of the 'H{alpha} shells'. The HCN and 89 GHz continuum emission are offset from the CO peak and are distributed in the direction of the central cluster. Three out of ten CO clouds are well correlated with the H{alpha} shells both in spatial and velocity domains, implying an interaction between molecular gas and the expanding H II region. The CO clouds show varieties in star formation efficiencies (SFEs), which are estimated from the 89 GHz emission and combination of H{alpha} and Spitzer 24 {mu}m data. Furthermore, we found that the SFEs decrease with increasing projected distance measured from the heart of the central OB star cluster in NGC 604, suggesting radial changes in the evolutionary stages of the molecular clouds in the course of stellar cluster formation. Our results provide further support to the picture of sequential star formation in NGC 604 initially proposed by Tosaki et al. with the higher spatially resolved molecular clouds, in which an isotropic expansion of the H II region pushes gases outward, which accumulates to form dense molecular clouds, and then induces massive star formations.

  13. LUMINOUS SUPERNOVA-LIKE UV/OPTICAL/INFRARED TRANSIENTS ASSOCIATED WITH ULTRA-LONG GAMMA-RAY BURSTS FROM METAL-POOR BLUE SUPERGIANTS

    SciTech Connect

    Kashiyama, Kazumi; Yajima, Hidenobu; Nakauchi, Daisuke; Nakamura, Takashi; Suwa, Yudai

    2013-06-10

    Metal-poor massive stars typically end their lives as blue supergiants (BSGs). Gamma-ray bursts (GRBs) from such progenitors could have an ultra-long duration of relativistic jets. For example, Population III (Pop III) GRBs at z {approx} 10-20 might be observable as X-ray-rich events with a typical duration of T{sub 90} {approx} 10{sup 4}(1 + z) s. The recent GRB111209A at z = 0.677 has an ultra-long duration of T{sub 90} {approx} 2.5 Multiplication-Sign 10{sup 4} s and it has been suggested that its progenitor might have been a metal-poor BSG in the local universe. Here, we suggest that luminous UV/optical/infrared emission is associated with this new class of GRBs from metal-poor BSGs. Before the jet head breaks out of the progenitor envelope, the energy injected by the jet is stored in a hot plasma cocoon, which finally emerges and expands as a baryon-loaded fireball. We show that the photospheric emissions from the cocoon fireball could be intrinsically very bright (L{sub peak} {approx} 10{sup 42}-10{sup 44} erg s{sup -1}) in UV/optical bands ({epsilon}{sub peak} {approx} 10 eV) with a typical duration of {approx}100 days in the rest frame. Such cocoon emissions from Pop III GRBs might be detectable in infrared bands at {approx}years after Pop III GRBs at up to z {approx} 15 by upcoming facilities such as the James Webb Space Telescope. We also suggest that GRB111209A might have been rebrightening in UV/optical bands up to an AB magnitude of {approx}< 26. The cocoon emission from local metal-poor BSGs might have been observed previously as luminous supernovae without GRBs since they can be seen from the off-axis direction of the jet.

  14. Long-lasting X-Ray Emission from Type IIb Supernova 2011dh and Mass-loss History of the Yellow Supergiant Progenitor

    NASA Astrophysics Data System (ADS)

    Maeda, Keiichi; Katsuda, Satoru; Bamba, Aya; Terada, Yukikatsu; Fukazawa, Yasushi

    2014-04-01

    Type IIb supernova (SN) 2011dh, with conclusive detection of an unprecedented yellow supergiant (YSG) progenitor, provides an excellent opportunity to deepen our understanding on the massive star evolution in the final centuries toward the SN explosion. In this paper, we report on detection and analyses of thermal X-ray emission from SN IIb 2011dh at ~500 days after the explosion on Chandra archival data, providing a solidly derived mass-loss rate of a YSG progenitor for the first time. We find that the circumstellar media should be dense, more than that expected from a Wolf-Rayet (W-R) star by one order of magnitude. The emission is powered by a reverse shock penetrating into an outer envelope, fully consistent with the YSG progenitor but not with a W-R progenitor. The density distribution at the outermost ejecta is much steeper than that expected from a compact W-R star, and this finding must be taken into account in modeling the early UV/optical emission from SNe IIb. The derived mass-loss rate is ~3 10-6 M ? yr-1 for the mass-loss velocity of ~20 km s-1 in the final ~1300 yr before the explosion. The derived mass-loss properties are largely consistent with the standard wind mass-loss expected for a giant star. This is not sufficient to be a main driver to expel nearly all the hydrogen envelope. Therefore, the binary interaction, with a huge mass transfer having taken place at >~ 1300 yr before the explosion, is a likely scenario to produce the YSG progenitor.

  15. Spectral variation in the supergiant fast X-ray transient SAX J1818.6-1703 observed by XMM-Newton and INTEGRAL

    NASA Astrophysics Data System (ADS)

    Boon, C. M.; Bird, A. J.; Hill, A. B.; Sidoli, L.; Sguera, V.; Goossens, M. E.; Fiocchi, M.; McBride, V. A.; Drave, S. P.

    2016-03-01

    We present the results of a 30 ks XMM-Newton observation of the supergiant fast X-ray transient (SFXT) SAX J1818.6-1703 - the first in-depth soft X-ray study of this source around periastron. INTEGRAL observations shortly before and after the XMM-Newton observation show the source to be in an atypically active state. Over the course of the XMM-Newton observation, the source shows a dynamic range of ˜100 with a luminosity greater than 1 × 1035 erg s-1 for the majority of the observation. After an ˜6 ks period of low-luminosity (˜1034 erg s-1) emission, SAX J1818.6-1703 enters a phase of fast flaring activity, with flares ˜250 s long, separated by ˜2 ks. The source then enters a larger flare event of higher luminosity and ˜8 ks duration. Spectral analysis revealed evidence for a significant change in spectral shape during the observation with a photon index varying from Γ ˜ 2.5 during the initial low-luminosity emission phase, to Γ ˜ 1.9 through the fast flaring activity, and a significant change to Γ ˜ 0.3 during the main flare. The intrinsic absorbing column density throughout the observation (nH ˜ 5 × 1023 cm-2) is among the highest measured from an SFXT, and together with the XMM-Newton and INTEGRAL luminosities, consistent with the neutron star encountering an unusually dense wind environment around periastron. Although other mechanisms cannot be ruled out, we note that the onset of the brighter flares occurs at 3 × 1035erg s-1, a luminosity consistent with the threshold for the switch from a radiative-dominated to Compton cooling regime in the quasi-spherical settling accretion model.

  16. Toward connecting core-collapse supernova theory with observations. I. Shock revival in a 15 M {sub ☉} blue supergiant progenitor with SN 1987A energetics

    SciTech Connect

    Handy, Timothy; Plewa, Tomasz; Odrzywołek, Andrzej

    2014-03-10

    We study the evolution of the collapsing core of a 15 M {sub ☉} blue supergiant supernova progenitor from the core bounce until 1.5 s later. We present a sample of hydrodynamic models parameterized to match the explosion energetics of SN 1987A. We find the spatial model dimensionality to be an important contributing factor in the explosion process. Compared to two-dimensional (2D) simulations, our three-dimensional (3D) models require lower neutrino luminosities to produce equally energetic explosions. We estimate that the convective engine in our models is 4% more efficient in 3D than in 2D. We propose that the greater efficiency of the convective engine found in 3D simulations might be due to the larger surface-to-volume ratio of convective plumes, which aids in distributing energy deposited by neutrinos. We do not find evidence of the standing accretion shock instability or turbulence being a key factor in powering the explosion in our models. Instead, the analysis of the energy transport in the post-shock region reveals characteristics of penetrative convection. The explosion energy decreases dramatically once the resolution is inadequate to capture the morphology of convection on large scales. This shows that the role of dimensionality is secondary to correctly accounting for the basic physics of the explosion. We also analyze information provided by particle tracers embedded in the flow and find that the unbound material has relatively long residency times in 2D models, while in 3D a significant fraction of the explosion energy is carried by particles with relatively short residency times.

  17. V-Band, Near-IR, and TiO Photometry of the Semi-Regular Red Supergiant TV Geminorum: Long-Term Quasi-Periodic Changes in Temperature, Radius, and Luminosity

    NASA Astrophysics Data System (ADS)

    Wasatonic, Richard P.; Guinan, Edward F.; Durbin, Allyn J.

    2015-10-01

    Seventeen years of V-band and intermediate Wing near-IR TiO (λ719-nm to λ1024-nm) time-series photometry of the M1-4 Iab supergiant TV Geminorum are presented. The observations were conducted from 1997 to 2014 with the primary goals of determining both long-term (years) and short-term (months) periodicities and estimating temporal changes in temperature, luminosity, and radius as the star varies in brightness. Our results suggest a dominant short-term V-band period of ~411 days (~1.12 years) that is superimposed on a long-term cycle of ~3137 days (~8.59 years). Over this long-term cycle, the effective temperature varies between ~3500 K to ~3850 K and, at an adopted distance of 1.5 ± 0.2 kpc, the luminosity varies from ~6.2 × 104 Lsolar to ~8.9 × 104 Lsolar and the radius varies from ~620 Rsolar to ~710 Rsolar. Variations in temperature and luminosity are indicative of a semi-regular long-term pulsation with imposed short-term periods similar to the V-band variations. However, the calculated radius variations are apparently not generally inversely correlated with respect to the long-term temperature and luminosity changes as typically found in Cepheids and Mira-type variables. This observation suggests other undetermined mechanisms, such as the formation and subsequent dissipation of supergranules or possible complex pulsations, are taking place in this evolved red supergiant to account for these variations. Like other young, massive luminous red supergiants such as Betelgeuse (α Orionis) and Antares (α Scorpii), TV Gem shows complicated light variations on time scales that range from months to several years. These evolved high massive stars are important to study because they are nearby, bright progenitors of core-collapsed Type II supernovae.

  18. Chemical Emergencies

    MedlinePLUS

    ... happen underground, on railways or highways, and at manufacturing plants. They may involve fire or explosion, or ... of chemicals as only those substances used in manufacturing processes. But chemicals are found everywhere–in our ...

  19. Chemical sensor

    NASA Technical Reports Server (NTRS)

    Rauh, R. David (Inventor)

    1990-01-01

    A sensor for detecting a chemical substance includes an insertion element having a structure which enables insertion of the chemical substance with a resulting change in the bulk electrical characteristics of the insertion element under conditions sufficient to permit effective insertion; the change in the bulk electrical characteristics of the insertion element is detected as an indication of the presence of the chemical substance.

  20. Carbon abundance and the N/C ratio in atmospheres of A-, F- and G-type supergiants and bright giants

    NASA Astrophysics Data System (ADS)

    Lyubimkov, Leonid S.; Lambert, David L.; Korotin, Sergey A.; Rachkovskaya, Tamara M.; Poklad, Dmitry B.

    2015-02-01

    Based on our prior accurate determination of fundamental parameters for 36 Galactic A-, F- and G-type supergiants and bright giants (luminosity classes I and II), we undertook a non-LTE analysis of the carbon abundance in their atmospheres. It is shown that the non-LTE corrections to the C abundances derived from C I lines are negative and increase with the effective temperature Teff; the corrections are especially significant for the infrared C I lines with wavelengths 9060-9660 Å. The carbon underabundance as a general property of the stars in question is confirmed; a majority of the stars studied has the carbon deficiency [C/Fe] between -0.1 and -0.5 dex, with a minimum at -0.7 dex. When comparing the derived C deficiency with the N excess found by us for the same stars earlier, we obtain a pronounced N versus C anticorrelation, which could be expected from predictions of the theory. We found that the ratio [N/C] spans mostly the range from 0.3 to 1.7 dex. Both these enhanced [N/C] values and the C and N anomalies themselves are an obvious evidence of the presence on a star's surface of mixed material from stellar interiors; so, a majority of programme stars passed through the deep mixing during the main sequence (MS) and/or the first dredge-up (FD) phase. Comparison with theoretical predictions including rotationally induced mixing shows that the stars are either post-MS objects with the initial rotational velocities V0 = 200-300 km s-1 or post-FD objects with V0 = 0-300 km s-1. The observed N versus C anticorrelation reflects a dependence of the C and N anomalies on the V0 value: on average the higher V0 the greater the anomalies. It is shown that an absence of detectable lithium in the atmospheres of the stars, which is accompanied with the observed N excess and C deficiency, is quite explainable.

  1. The 100-Month Swift Catalogue of Supergiant Fast X-Ray Transients I. BAT On-Board and Transient Monitor Flares

    NASA Technical Reports Server (NTRS)

    Romano, P.; Krimm, H. A.; Palmer, D. M.; Ducci, L.; Esposito, P.; Vercellone, S.; Evans, P. A.; Guidorzi, C.; Mangano, V.; Kennea, J. A.; Barthelmy, S. D.; Burrows, D. N.; Gehrels, N.

    2014-01-01

    Context. Supergiant fast X-ray transients (SFXTs) are high mass X-ray binaries (HMXBs) that are defined by their hard X-ray flaring behaviour. During these flares they reach peak luminosities of 10 (sup 36)-10 (sup 37) ergs per second for a few hours (in the hard X-ray), which are much shorter timescales than those characterizing Be/X-ray binaries. Aims. We investigate the characteristics of bright flares (detections in excess of 5 sigma) for a sample of SFXTs and their relation to the orbital phase. Methods. We have retrieved all Swift/BAT Transient Monitor light curves and collected all detections in excess of 5 sigma from both daily- and orbital-averaged light curves in the time range of 2005 February 12 to 2013 May 31 (MJD 53413-56443). We also considered all on-board detections as recorded in the same time span and selected those in excess of 5 sigma and within 4 arc minutes of each source in our sample. Results. We present a catalogue of over a thousand BAT flares from 11 SFXTs, down to 15-150 kiloelectronvolt fluxes of approximately 6×10 (sup -10) ergs per centimeters squared per second (daily timescale) and approximately 1.5×10 (sup -9) ergs per centimeters squared per second (orbital timescale, averaging approximately 800 seconds); the great majority of these flares are unpublished. The catalogue spans 100 months. This population is characterized by short (a few hundred seconds) and relatively bright (in excess of 100 mCrab, 15-50 kiloelectronvolt) events. In the hard X-ray, these flares last generally much less than a day. Clustering of hard X-ray flares can be used to indirectly measure the length of an outburst, even when the low-level emission is not detected. We construct the distributions of flares, of their significance (in terms of sigma), and of their flux as a function of orbital phase to infer the properties of these binary systems. In particular, we observe a trend of clustering of flares at some phases as P (sub orb) increases, which is consistent with a progression from tight circular or mildly eccentric orbits at short periods to wider and more eccentric orbits at longer orbital periods. Finally, we estimate the expected number of flares for a given source for our limiting flux and provide the recipe for calculating them for the limiting flux of future hard X-ray observatories.

  2. [Chemical weapons and chemical terrorism].

    PubMed

    Nakamura, Katsumi

    2005-10-01

    Chemical Weapons are kind of Weapons of Mass Destruction (WMD). They were used large quantities in WWI. Historically, large quantities usage like WWI was not recorded, but small usage has appeared now and then. Chemical weapons are so called "Nuclear weapon for poor countrys" because it's very easy to produce/possession being possible. They are categorized (1) Nerve Agents, (2) Blister Agents, (3) Cyanide (blood) Agents, (4) Pulmonary Agents, (5) Incapacitating Agents (6) Tear Agents from the viewpoint of human body interaction. In 1997 the Chemical Weapons Convention has taken effect. It prohibits chemical weapons development/production, and Organization for the Prohibition of Chemical Weapons (OPCW) verification regime contributes to the chemical weapons disposal. But possibility of possession/use of weapons of mass destruction by terrorist group represented in one by Matsumoto and Tokyo Subway Sarin Attack, So new chemical terrorism countermeasures are necessary. PMID:16296384

  3. Chemical microsensors

    DOEpatents

    Li, DeQuan (Los Alamos, NM); Swanson, Basil I. (Los Alamos, NM)

    1995-01-01

    An article of manufacture is provided including a substrate having an oxide surface layer and a selective thin film of a cyclodextrin derivative chemically bound upon said substrate, said film is adapted for the inclusion of a selected organic compound therewith. Such an article can be either a chemical sensor capable of detecting a resultant mass change from inclusion of the selected organic compound or a chemical separator capable of reversibly selectively separating a selected organic compound.

  4. Chemical sensors

    DOEpatents

    Lowell, Jr., James R. (Bend, OR); Edlund, David J. (Bend, OR); Friesen, Dwayne T. (Bend, OR); Rayfield, George W. (Bend, OR)

    1991-01-01

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising (a) a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, operatively coupled to (b) a transducer capable of directly converting said expansion or contraction to a measurable electrical response.

  5. Chemical preconcentrator

    DOEpatents

    Manginell, Ronald P.; Frye-Mason, Gregory C.

    2001-01-01

    A chemical preconcentrator is disclosed with applications to chemical sensing and analysis. The preconcentrator can be formed by depositing a resistive heating element (e.g. platinum) over a membrane (e.g. silicon nitride) suspended above a substrate. A coating of a sorptive material (e.g. a microporous hydrophobic sol-gel coating or a polymer coating) is formed on the suspended membrane proximate to the heating element to selective sorb one or more chemical species of interest over a time period, thereby concentrating the chemical species in the sorptive material. Upon heating the sorptive material with the resistive heating element, the sorbed chemical species are released for detection and analysis in a relatively high concentration and over a relatively short time period. The sorptive material can be made to selectively sorb particular chemical species of interest while not substantially sorbing other chemical species not of interest. The present invention has applications for use in forming high-sensitivity, rapid-response miniaturized chemical analysis systems (e.g. a "chem lab on a chip").

  6. Chemical sensors

    DOEpatents

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1991-07-02

    Sensors responsive to small changes in the concentration of chemical species are disclosed. The sensors comprise a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment. They are operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical response. 9 figures.

  7. The 100-month Swift catalogue of supergiant fast X-ray transients. I. BAT on-board and transient monitor flares

    NASA Astrophysics Data System (ADS)

    Romano, P.; Krimm, H. A.; Palmer, D. M.; Ducci, L.; Esposito, P.; Vercellone, S.; Evans, P. A.; Guidorzi, C.; Mangano, V.; Kennea, J. A.; Barthelmy, S. D.; Burrows, D. N.; Gehrels, N.

    2014-02-01

    Context. Supergiant fast X-ray transients (SFXTs) are high mass X-ray binaries (HMXBs) that are defined by their hard X-ray flaring behaviour. During these flares they reach peak luminosities of 1036-1037 erg s-1 for a few hours (in the hard X-ray), which are much shorter timescales than those characterizing Be/X-ray binaries. Aims: We investigate the characteristics of bright flares (detections in excess of 5?) for a sample of SFXTs and their relation to the orbital phase. Methods: We have retrieved all Swift/BAT Transient Monitor light curves and collected all detections in excess of 5? from both daily- and orbital-averaged light curves in the time range of 2005 February 12 to 2013 May 31 (MJD 53 413-56 443). We also considered all on-board detections as recorded in the same time span and selected those in excess of 5? and within 4 arcmin of each source in our sample. Results: We present a catalogue of over a thousand BAT flares from 11 SFXTs, down to 15-150 keV fluxes of ~6 10-10 erg cm-2 s-1 (daily timescale) and ~1.5 10-9 erg cm-2 s-1 (orbital timescale, averaging ~800 s); the great majority of these flares are unpublished. The catalogue spans 100 months. This population is characterized by short (a few hundred seconds) and relatively bright (in excess of 100 mCrab, 15-50 keV) events. In the hard X-ray, these flares last generally much less than a day. Clustering of hard X-ray flares can be used to indirectly measure the length of an outburst, even when the low-level emission is not detected. We construct the distributions of flares, of their significance (in terms of ?), and of their flux as a function of orbital phase to infer the properties of these binary systems. In particular, we observe a trend of clustering of flares at some phases as Porb increases, which is consistent with a progression from tight circular or mildly eccentric orbits at short periods to wider and more eccentric orbits at longer orbital periods. Finally, we estimate the expected number of flares for a given source for our limiting flux and provide the recipe for calculating them for the limiting flux of future hard X-ray observatories. Project web page: http://www.ifc.inaf.it/sfxt/Full Table 4 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/562/A2

  8. Unnecessary Chemicals

    ERIC Educational Resources Information Center

    Johnson, Anita

    1978-01-01

    Discusses the health hazards resulting from chemical additions of many common products such as cough syrups, food dyes, and cosmetics. Steps being taken to protect consumers from these health hazards are included. (MDR)

  9. Chemical sensors

    DOEpatents

    Lowell, Jr., James R. (Bend, OR); Edlund, David J. (Bend, OR); Friesen, Dwayne T. (Bend, OR); Rayfield, George W. (Eugene, OR)

    1992-01-01

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material.

  10. Chemical sensors

    DOEpatents

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1992-06-09

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material. 12 figs.

  11. Chemical sensors

    SciTech Connect

    Hubbard, C.W.; Gordon, R.L.

    1987-05-01

    The revolution in analytical chemistry promised by recent developments in the field of chemical sensors has potential for significant positive impact on both research and production activities conducted by and for the Department of Energy. Analyses which were, in the past, performed only with a roomful of expensive equipment can now be performed with miniature solid-state electronic devices or small optical probes. Progress in the development of chemical sensors has been rapid, and the field is currently growing at a great rate. In accordance, Pacific Northwest Laboratory initiated a survey of recent literature so that contributors to active programs in research on analytical methods could be made aware of principles and applications of this new technology. This report presents the results of that survey. The sensors discussed here are divided into three types: micro solid-state devices, optical sensors, and piezoelectric crystal devices. The report is divided into three corresponding sections. The first section, ''Micro Solid-State Devices,'' discusses the design, operation, and application of electronic sensors that are produced in much the same way as standard solid-state electronic devices. The second section, ''Optrodes,'' covers the design and operation of chemical sensors that use fiber optics to detect chemically induced changes in optical properties. The final section, ''Piezoelectric Crystal Detectors,'' discusses two types of chemical sensors that depend on the changes in the properties of an oscillating piezoelectric crystal to detect the presence of certain materials. Advantages and disadvantages of each type of sensor are summarized in each section.

  12. Chemical networks

    NASA Astrophysics Data System (ADS)

    Thi, Wing-Fai

    2015-09-01

    This chapter discusses the fundamental ideas of how chemical networks are build, their strengths and limitations. The chemical reactions that occur in disks combine the cold phase reactions used to model cold molecular clouds with the hot chemistry applied to planetary atmosphere models. With a general understanding of the different types of reactions that can occur, one can proceed in building a network of chemical reactions and use it to explain the abundance of species seen in disks. One on-going research subject is finding new paths to synthesize species either in the gas-phase or on grain surfaces. Specific formation routes for water or carbon monoxide are discussed in more details. 13th Lecture of the Summer School "Protoplanetary Disks: Theory and Modelling Meet Observations"

  13. Chemical abundances of massive stars in Local Group galaxies

    NASA Astrophysics Data System (ADS)

    Venn, Kim A.; Kaufer, Andreas; Tolstoy, Eline; Kudritzki, Rolf-Peter; Przybilla, Norbert; Smartt, Stephen J.; Lennon, Daniel J.

    The relative abundances of elements in galaxies can provide valuable information on the stellar and chemical evolution of a galaxy. While nebulae can provide abundances for a variety of light elements, stars are the only way to directly determine the abundances of iron-group and s-process and r-process elements in a galaxy. The new 8m and 10m class telescopes and high-efficiency spectrographs now make high-quality spectral observations of bright supergiants possible in dwarf galaxies in the Local Group. We have been concentrating on elemental abundances in the metal-poor dwarf irregular galaxies, NGC 6822, WLM, Sextants A, and GR 8. Comparing abundance ratios to those predicted from their star formation histories, determined from color-magnitude diagrams, and comparing those ratios between these galaxies can give us new insights into the evolution of these dwarf irregular galaxies. Iron-group abundances also allow us to examine the metallicities of the stars in these galaxies directly, which affects their inferred mass loss rates and predicted stellar evolution properties.

  14. Chemical lasers

    NASA Astrophysics Data System (ADS)

    Ablekov, V. K.; Denisov, Iu. N.; Proshkin, V. V.

    1983-08-01

    Recent developments in the theory and application of chemical lasers (CLs) are surveyed in a translation of a book published in Russian in 1980. The laws governing the gas-phase chemical reactions typical of CLs are introduced, the principles of quantum-mechanical description of molecular systems are reviewed, and the kinetics of CL processes are examined. The four general classes of CL are then presented in detail: static-gas, subsonic, supersonic, and detonation CLs. Graphs, diagrams, and drawings of experimental setups are provided.

  15. Chemical Mahjong

    ERIC Educational Resources Information Center

    Cossairt, Travis J.; Grubbs, W. Tandy

    2011-01-01

    An open-access, Web-based mnemonic game is described whereby introductory chemistry knowledge is tested using mahjong solitaire game play. Several tile sets and board layouts are included that are themed upon different chemical topics. Introductory tile sets can be selected that prompt the player to match element names to symbols and metric

  16. Chemical Mahjong

    ERIC Educational Resources Information Center

    Cossairt, Travis J.; Grubbs, W. Tandy

    2011-01-01

    An open-access, Web-based mnemonic game is described whereby introductory chemistry knowledge is tested using mahjong solitaire game play. Several tile sets and board layouts are included that are themed upon different chemical topics. Introductory tile sets can be selected that prompt the player to match element names to symbols and metric…

  17. Chemical Indicators.

    ERIC Educational Resources Information Center

    Prombain, Dorothy R.; And Others

    This science sourcebook was written for intermediate grade teachers to provide guidance in teaching a specially developed unit on chemical indicators. Directions and suggestions for guiding student science activities are given. Some of the activities concern soil testing, crystals, and household powders such as sugar and salt. A list of necessary

  18. Delicious Chemicals.

    ERIC Educational Resources Information Center

    Barry, Dana M.

    This paper presents an approach to chemistry and nutrition that focuses on food items that people consider delicious. Information is organized according to three categories of food chemicals that provide energy to the human body: (1) fats and oils; (2) carbohydrates; and (3) proteins. Minerals, vitamins, and additives are also discussed along with…

  19. Chemical intolerance.

    PubMed

    Dantoft, Thomas M; Andersson, Linus; Nordin, Steven; Skovbjerg, Sine

    2015-01-01

    Chemical intolerance (CI) is a term used to describe a condition in which the sufferer experiences a complex array of recurrent unspecific symptoms attributed to low-level chemical exposure that most people regard as unproblematic. Severe CI constitutes the distinguishing feature of multiple chemical sensitivity (MCS). The symptoms reported by CI subjects are manifold, involving symptoms from multiple organs systems. In severe cases of CI, the condition can cause considerable life-style limitations with severe social, occupational and economic consequences. As no diagnostic tools for CI are available, the presence of the condition can only be established in accordance to criteria definitions. Numerous modes of action have been suggested to explain CI, with the most commonly discussed theories involving the immune system, central nervous system, olfactory and respiratory systems as well as altered metabolic capacity, behavioral conditioning and emotional regulation. However, in spite of more than 50 years of research, there is still a great deal of uncertainties regarding the event(s) and underlying mechanism( s) behind symptom elicitation. As a result, patients are often misdiagnosed or offered health care solutions with limited or no effect, and they experience being met with mistrust and doubt by health care professionals, the social care system and by friends and relatives. Evidence-based treatment options are currently unavailable, however, a person-centered care model based on a multidisciplinary treatment approach and individualized care plans have shown promising results. With this in mind, further research studies and health care solutions should be based on a multifactorial and interdisciplinary approach. PMID:26088215

  20. Chemical durability

    SciTech Connect

    Kreuer, K.D.; Warhus, U.

    1986-03-01

    The chemical durability of NASICON (Na/sub 1+x/Zr/sub 2/Si/sub x/P/sub 3-x/O/sub 12/, x=0-3) versus molten sodium and sulfur at 600 K has been investigated. Degradation by molten sodium has been observed for phosphorus-containing compositions only. The pure silicate (x=3), however, appeared to be stable, because reduction of silicon demanded by thermodynamics did not occur at the given temperature for kinetic reasons. The latter composition has also been shown to have good durability against molten sulfur.

  1. The VLT-FLAMES survey of massive stars: constraints on stellar evolution from the chemical compositions of rapidly rotating Galactic and Magellanic Cloud B-type stars

    NASA Astrophysics Data System (ADS)

    Hunter, I.; Brott, I.; Langer, N.; Lennon, D. J.; Dufton, P. L.; Howarth, I. D.; Ryans, R. S. I.; Trundle, C.; Evans, C. J.; de Koter, A.; Smartt, S. J.

    2009-03-01

    Aims: We have previously analysed the spectra of 135 early B-type stars in the Large Magellanic Cloud (LMC) and found several groups of stars that have chemical compositions that conflict with the theory of rotational mixing. Here we extend this study to Galactic and Small Magellanic Cloud (SMC) metallicities. Methods: We provide chemical compositions for ~50 Galactic and ~100 SMC early B-type stars and compare these to the LMC results. These samples cover a range of projected rotational velocities up to ~300 km s-1 and hence are well suited to testing rotational mixing models. The surface nitrogen abundances are utilised as a probe of the mixing process since nitrogen is synthesized in the core of the stars and mixed to the surface. Results: In the SMC, we find a population of slowly rotating nitrogen-rich stars amongst the early B type core-hydrogen burning stars, which is comparable to that found previously in the LMC. The identification of non-enriched rapid rotators in the SMC is not possible due to the relatively high upper limits on the nitrogen abundance for the fast rotators. In the Galactic sample we find no significant enrichment amongst the core hydrogen-burning stars, which appears to be in contrast with the expectation from both rotating single-star and close binary evolution models. However, only a small number of the rapidly rotating stars have evolved enough to produce a significant nitrogen enrichment, and these may be analogous to the non-enriched rapid rotators previously found in the LMC sample. Finally, in each metallicity regime, a population of highly enriched supergiants is observed, which cannot be the immediate descendants of core-hydrogen burning stars. Their abundances are, however, compatible with them having gone through a previous red supergiant phase. Together, these observations paint a complex picture of the nitrogen enrichment in massive main sequence and supergiant stellar atmospheres, where age and binarity cause crucial effects. Whether rotational mixing is required to understand our results remains an open question at this time, but could be answered by identifying the true binary fraction in those groups of stars that do not agree with single-star evolutionary models. Based on observations at the European Southern Observatory in programmes 171.0237 and 073.0234. Figure 1 and Tables 1 and 2 are only available in electronic form at http://www.aanda.org

  2. Chemical Analyses

    NASA Technical Reports Server (NTRS)

    Bulluck, J. W.; Rushing, R. A.

    1994-01-01

    As a preliminary study on the effects of chemical aging of polymer materials MERL and TRI have examined two polymeric materials that are typically used for offshore umbilical applications. These two materials were Tefzel, a copolymer of ethylene and tetrafluoroethylene, and Coflon, polyvinylidene fluoride. The Coflon specimens were cut from pipe sections and exposed to H2S at various temperatures and pressures. One of these specimens was tested for methane permeation, and another for H2S permeation. The Tefzel specimens were cut from .05 mm sheet stock material and were exposed to methanol at elevated temperature and pressure. One of these specimens was exposed to methanol permeation for 2 days at 100 C and 2500 psi. An additional specimen was exposed to liquid methanol for 3 days at 150 C and 15 Bar. Virgin specimens of each material were similarly prepared and tested.

  3. The Chemical Engineer in the Chemical Industry.

    ERIC Educational Resources Information Center

    Zabicky, Jacob

    1986-01-01

    Describes a course for third- or fourth-year chemical engineering students designed to acquaint them with the chemical industry. The course deals with productivity, characteristics of the chemical industry, sources of information, industrial intelligence, research and development, patent law, technology transfer, and quality control. (TW)

  4. Microfluidic chemical reaction circuits

    SciTech Connect

    Lee, Chung-cheng; Sui, Guodong; Elizarov, Arkadij; Kolb, Hartmuth C.; Huang, Jiang; Heath, James R.; Phelps, Michael E.; Quake, Stephen R.; Tseng, Hsian-rong; Wyatt, Paul; Daridon, Antoine

    2012-06-26

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  5. CHEMICAL SAFETY ALERTS-

    EPA Science Inventory

    Chemical Safety Alerts are short publications which explain specific hazards that have become evident through chemical accident investigation efforts. EPA has produced over a dozen Alerts to date. This year's Alert: Managing Chemical Reactivity Hazards

  6. Chemical Management System

    Energy Science and Technology Software Center (ESTSC)

    1998-10-30

    CMS provides an inventory of all chemicals on order or being held in the laboratory, to provide a specific location for all chemical containers, to ensure that health and safety regulatory codes are being upheld, and to provide PNNL staff with hazardous chemical information to better manage their inventories. CMS is comprised of five major modules: 1) chemical purchasing, 2) chemical inventory, 3) chemical names, properties, and hazard groups, 4) reporting, and 5) system administration.

  7. Nature's chemicals and synthetic chemicals: Comparative toxicology

    SciTech Connect

    Ames, B.N.; Profet, M.; Gold, L.S. )

    1990-10-01

    The toxicology of synthetic chemicals is compared to that of natural chemicals, which represent the vast bulk of the chemicals to which humans are exposed. It is argued that animals have a broad array of inducible general defenses to combat the changing array of toxic chemicals in plant food (nature's pesticides) and that these defenses are effective against both natural and synthetic toxins. Synthetic toxins such as dioxin are compared to natural chemicals, such as indole carbinol (in broccoli) and ethanol. Trade-offs between synthetic and natural pesticides are discussed. The finding that in high-dose tests, a high proportion of both natural and synthetic chemicals are carcinogens, mutagens, teratogens, and clastogens (30-50{percent} for each group) undermines current regulatory efforts to protect public health from synthetic chemicals based on these tests.

  8. PINS chemical identification software

    DOEpatents

    Caffrey, Augustine J.; Krebs, Kennth M.

    2004-09-14

    An apparatus and method for identifying a chemical compound. A neutron source delivers neutrons into the chemical compound. The nuclei of chemical elements constituting the chemical compound emit gamma rays upon interaction with the neutrons. The gamma rays are characteristic of the chemical elements constituting the chemical compound. A spectrum of the gamma rays is generated having a detection count and an energy scale. The energy scale is calibrated by comparing peaks in the spectrum to energies of pre-selected chemical elements in the spectrum. A least-squares fit completes the calibration. The chemical elements constituting the chemical compound can be readily determined, which then allows for identification of the chemical compound.

  9. Ionospheric chemical releases

    NASA Technical Reports Server (NTRS)

    Bernhardt, Paul A.; Scales, W. A.

    1990-01-01

    Ionospheric plasma density irregularities can be produced by chemical releases into the upper atmosphere. F-region plasma modification occurs by: (1) chemically enhancing the electron number density; (2) chemically reducing the electron population; or (3) physically convecting the plasma from one region to another. The three processes (production, loss, and transport) determine the effectiveness of ionospheric chemical releases in subtle and surprising ways. Initially, a chemical release produces a localized change in plasma density. Subsequent processes, however, can lead to enhanced transport in chemically modified regions. Ionospheric modifications by chemical releases excites artificial enhancements in airglow intensities by exothermic chemical reactions between the newly created plasma species. Numerical models were developed to describe the creation and evolution of large scale density irregularities and airglow clouds generated by artificial means. Experimental data compares favorably with theses models. It was found that chemical releases produce transient, large amplitude perturbations in electron density which can evolve into fine scale irregularities via nonlinear transport properties.

  10. Red Supergiants in the Local Group

    NASA Astrophysics Data System (ADS)

    Levesque, E. M.

    2013-05-01

    Galaxies in the Local Group span a factor of 15 in metallicity, ranging from the super-solar M 31 to the Wolf-Lundmark-Melotte (WLM) galaxy, which is the lowest-metallicity (0.1 Z?) Local Group galaxy currently forming stars. Studies of massive star populations across this broad range of environments have revealed important metal-licity-dependent evolutionary trends, allowing us to test the accuracy of stellar evolutionary tracks at these metallicities for the first time. The RSG population is particularly valuable as a key mass-losing phase of moderately massive stars and a source of core-collapse supernova progenitors. By reviewing recent work on the RSG populations in the Local Group, we are able to quantify limits on these stars' effective temperatures and masses and probe the relationship between RSG mass loss behaviors and host environments. Extragalactic surveys of RSGs have also revealed several unusual RSGs that display signs of unusual spectral variability and dust production, traits that may potentially also correlate with the stars' host environments. I will present some of the latest work that has advanced our understanding of RSGs in the Local Group, and consider the many new questions posed by our ever-evolving picture of these stars.

  11. Outer atmospheres of giant and supergiant stars

    NASA Technical Reports Server (NTRS)

    Brown, A.

    1984-01-01

    The properties of the chromospheres, transition regions and coronas of cool evolved stars are reviewed based primarily on recent ultraviolet and X-ray studies. Determinations of mass loss rates using new observational techniques in the ultraviolet and radio spectral regions are discussed and observations indicating general atmospheric motions are considered. The techniques available for the quantitative modeling of these atmospheres are outlined and recent results discussed. Finally, the current rudimentary understanding of the evolution of these outer atmospheres and its causes are considered.

  12. Supergiant pulses from extragalactic neutron stars

    NASA Astrophysics Data System (ADS)

    Cordes, J. M.; Wasserman, Ira

    2016-03-01

    We consider radio bursts that originate from extragalactic neutron stars (NSs) by addressing three questions about source distances. What are the physical limitations on coherent radiation at GHz frequencies? Do they permit detection at cosmological distances? How many bursts per NS are needed to produce the inferred burst rate ˜103-104sky-1 d-1? The burst rate is comparable to the NS formation rate in a Hubble volume, requiring only one per NS if they are bright enough. Radiation physics suggests a closer population, requiring more bursts per NS and increasing the chances for repeats. Bursts comprise sub-ns, coherent shot pulses superposed incoherently to produce ms-duration ˜1 Jy amplitudes; each shot pulse can be much weaker than 1 Jy, placing less restrictive requirements on the emission process. None the less, single shot pulses are similar to the extreme, unresolved (<0.4 ns) MJy shot pulse seen from the Crab pulsar, consistent with coherent curvature radiation emitted near the light cylinder by an almost neutral clump with net charge ˜± 1021e and total energy ≳ 1023 erg. Bursts from Gpc distances require incoherent superposition of {˜ } 10^{12}d_Gpc^2 shot pulses or a total energy ≳ 10^{35} d_Gpc^2 erg. The energy reservoir near the light cylinder limits the detection distance to ≲ few × 100 Mpc for a fluence ˜1 Jy ms unless conditions are more extreme than for the Crab pulsar, such as in magnetars. We discuss contributions to dispersion measures from galaxy clusters and we propose tests for the overall picture presented.

  13. DTP - Chemical Biology Consortium

    Cancer.gov

    Chemical Biology Consortium Home Discovery Development Pathways Grants/Contracts Books/Publications Site Search Data Search What's New Chemical Biology Consortium (CBC) Division of Cancer Treatment and Diagnosis To download Adobe Reader for documents

  14. Chemicals Industry Vision

    SciTech Connect

    none,

    1996-12-01

    Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

  15. Chemical burn or reaction

    MedlinePLUS

    ... different products that contain toxic chemicals such as ammonia and bleach. The mixture can give off hazardous ... chemicals immediately after use. Use paints, petroleum products, ammonia, bleach, and other products that give off fumes ...

  16. Capacitive chemical sensor

    DOEpatents

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  17. Chemical Industry Bandwidth Study

    SciTech Connect

    none,

    2006-12-01

    The Chemical Bandwidth Study provides a snapshot of potentially recoverable energy losses during chemical manufacturing. The advantage of this study is the use of "exergy" analysis as a tool for pinpointing inefficiencies.

  18. Chemical Transformation Simulator

    EPA Science Inventory

    The Chemical Transformation Simulator (CTS) is a web-based, high-throughput screening tool that automates the calculation and collection of physicochemical properties for an organic chemical of interest and its predicted products resulting from transformations in environmental sy...

  19. Tobacco and chemicals (image)

    MedlinePLUS

    Some of the chemicals associated with tobacco smoke include ammonia, carbon dioxide, carbon monoxide, propane, methane, acetone, hydrogen cyanide and various carcinogens. Other chemicals that are associated with chewing ...

  20. Personal Chemical Exposure informatics

    EPA Science Inventory

    Chemical Exposure science is the study of human contact with chemicals (from manufacturing facilities, everyday products, waste) occurring in their environments and advances knowledge of the mechanisms and dynamics of events that cause or prevent adverse health outcomes. (adapted...

  1. Chemicals: friends and foes.

    PubMed

    Singh, Kirpal

    2014-01-01

    There are many chemicals used in and around homes and workplaces that can result in accidents. Can it be said that the insecticides, drugs, polychlorinated biphenyls, DDT, asbestos, cleansers, cosmetics, and other chemicals are worth the price paid in terms of accidental poisonings? That is for the consumer to decide. Generally, it is the misuse of these chemicals that often leads to tragedy. Chemicals can be dangerous, but they can be advantageous when used with care. PMID:24622781

  2. Computing Equilibrium Chemical Compositions

    NASA Technical Reports Server (NTRS)

    Mcbride, Bonnie J.; Gordon, Sanford

    1995-01-01

    Chemical Equilibrium With Transport Properties, 1993 (CET93) computer program provides data on chemical-equilibrium compositions. Aids calculation of thermodynamic properties of chemical systems. Information essential in design and analysis of such equipment as compressors, turbines, nozzles, engines, shock tubes, heat exchangers, and chemical-processing equipment. CET93/PC is version of CET93 specifically designed to run within 640K memory limit of MS-DOS operating system. CET93/PC written in FORTRAN.

  3. The elusive chemical potential

    NASA Astrophysics Data System (ADS)

    Baierlein, Ralph

    2001-04-01

    This paper offers some qualitative understanding of the chemical potential, a topic that students invariably find difficult. Three "meanings" for the chemical potential are stated and then supported by analytical development. Two substantial applicationsdepression of the melting point and batteriesillustrate the chemical potential in action. The origin of the term "chemical potential" has its surprises, and a sketch of the history concludes the paper.

  4. AGRICULTURAL CHEMICAL USAGE DATA

    EPA Science Inventory

    This report, which summarizes the use of agricultural chemicals is issued by the National Agricultural Statistics Service (NASS) as part of its series on Agricultural Chemical Usage. Other publications in the series present statistics for on-farm agricultural chemical usage for f...

  5. Chemicals for worldwide aquaculture

    USGS Publications Warehouse

    Schnick, R.A.

    1991-01-01

    Regulations and therapeutants or other safe chemicals that are approved or acceptable for use in the aquaculture industry in the US, Canada, Europe and Japan are presented, discussing also compounds that are unacceptable for aquaculture. Chemical use practices that could affect public health are considered and details given regarding efforts to increase the number of registered and acceptable chemicals.

  6. Toxicology and Chemical Safety.

    ERIC Educational Resources Information Center

    Hall, Stephen K.

    1983-01-01

    Topics addressed in this discussion of toxicology and chemical safety include routes of exposure, dose/response relationships, action of toxic substances, and effects of exposure to chemicals. Specific examples are used to illustrate the principles discussed. Suggests prudence in handling any chemicals, whether or not toxicity is known. (JN)

  7. Naturally occurring chemical carcinogens

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Natural products are chemicals found in nature which have unique pharmacological effects. Humans are exposed to many of these bioactive naturally occurring chemicals via the air breathed, the water drunk and the food eaten. Exposure also occurs in clinical settings. Naturally occurring chemicals ...

  8. Chemical and Environmental Technology.

    ERIC Educational Resources Information Center

    Sheather, Harry

    The two-year curriculum in chemical technology presented in the document is designed to prepare high school graduates for technical positions in the chemical industry. Course outlines are given for general chemistry, chemical calculations, quantitative analysis, environmental chemistry, organic chemistry 1 and 2, instrumental analysis, and…

  9. Microreactors for chemical synthesis.

    PubMed

    DeWitt, S H

    1999-06-01

    The advances of the past few years in microreactors have demonstrated that the miniaturization of chemistry has significant advantages with respect to cost, safety, throughput, kinetics and scale-up. The use of chemical microreactors for catalytic oxidations, heterocyclic syntheses and photochemical reactions has illustrated the utility and benefits for both chemical discovery and chemical development applications. PMID:10359719

  10. Chemical Synthesis of Proteins

    PubMed Central

    Nilsson, Bradley L.; Soellner, Matthew B.; Raines, Ronald T.

    2010-01-01

    Proteins have become accessible targets for chemical synthesis. The basic strategy is to use native chemical ligation, Staudinger ligation, or other orthogonal chemical reactions to couple synthetic peptides. The ligation reactions are compatible with a variety of solvents and proceed in solution or on a solid support. Chemical synthesis enables a level of control on protein composition that greatly exceeds that attainable with ribosome-mediated biosynthesis. Accordingly, the chemical synthesis of proteins is providing previously unattainable insight into the structure and function of proteins. PMID:15869385

  11. Evolved stars as complex chemical laboratories - the quest for gaseous chemistry

    NASA Astrophysics Data System (ADS)

    Katrien Els Decin, Leen

    2015-08-01

    At the end of their life, most stars lose a large fraction of their mass through a stellar wind. The stellar winds of evolved (super)giant stars are the dominant suppliers for the pristine building blocks of the interstellar medium (ISM). Crucial to the understanding of the chemical life cycle of the ISM is hence a profound insight in the chemical and physical structure governing these stellar winds.These winds are really unique chemical laboratories in which currently more than 70 different molecules and 15 different dust species are detected. Several chemical processes such as neutral-neutral and ion-molecule gas-phase reactions, dust nucleation and growth, and photo-processes determine the chemical content of these winds. However, gas-phase and dust-nucleation chemistry for astronomical environments still faces many challenges. One should realize that only ˜15% of the rate coefficients for gas-phase reactions considered to occur in (inter/circum)stellar regions at temperatures (T) below 300K have been subject to direct laboratory determinations and that the temperature dependence of the rate constants is often not known; only ˜2% have rate constants at T<200K and less than 0.5% at T<100 K. For stellar wind models, an important bottleneck occurs among the reactions involving silicon- and sulfur-bearing species, for which only a few have documented reaction rates. Often, researchers are implementing ‘educated guesses’ for these unknown rates, sometimes forcing the network to yield predictions concurring with (astronomical) observations. Large uncertainties are inherent in this type of ‘optimized’ chemical schemes.Thanks to an ERC-CoG grant, we are now in the position to solve some riddles involved in understanding the gas-phase chemistry in evolved stars. In this presentation, I will demonstrate the need for accurate temperature-dependent gas-phase reaction rate constants and will present our new laboratory equipment built to measure the rate constants for species key in stellar wind chemistry. Specifically, we aim to obtain the rate constants of reactions involving silicon- and sulphur bearing species and HCCO for 30

  12. Chemical exchange program analysis.

    SciTech Connect

    Waffelaert, Pascale

    2007-09-01

    As part of its EMS, Sandia performs an annual environmental aspects/impacts analysis. The purpose of this analysis is to identify the environmental aspects associated with Sandia's activities, products, and services and the potential environmental impacts associated with those aspects. Division and environmental programs established objectives and targets based on the environmental aspects associated with their operations. In 2007 the most significant aspect identified was Hazardous Materials (Use and Storage). The objective for Hazardous Materials (Use and Storage) was to improve chemical handling, storage, and on-site movement of hazardous materials. One of the targets supporting this objective was to develop an effective chemical exchange program, making a business case for it in FY07, and fully implementing a comprehensive chemical exchange program in FY08. A Chemical Exchange Program (CEP) team was formed to implement this target. The team consists of representatives from the Chemical Information System (CIS), Pollution Prevention (P2), the HWMF, Procurement and the Environmental Management System (EMS). The CEP Team performed benchmarking and conducted a life-cycle analysis of the current management of chemicals at SNL/NM and compared it to Chemical Exchange alternatives. Those alternatives are as follows: (1) Revive the 'Virtual' Chemical Exchange Program; (2) Re-implement a 'Physical' Chemical Exchange Program using a Chemical Information System; and (3) Transition to a Chemical Management Services System. The analysis and benchmarking study shows that the present management of chemicals at SNL/NM is significantly disjointed and a life-cycle or 'Cradle-to-Grave' approach to chemical management is needed. This approach must consider the purchasing and maintenance costs as well as the cost of ultimate disposal of the chemicals and materials. A chemical exchange is needed as a mechanism to re-apply chemicals on site. This will not only reduce the quantity of unneeded chemicals and the amount spent on new purchases, but will also avoid disposal costs. If SNL/NM were to realize a 5 percent reduction in chemical inventory and a 10 percent reduction in disposal of unused chemicals the total savings would be $189, 200 per year.

  13. The chemical juggernaut.

    PubMed

    Cadbury, D

    1997-01-01

    Man-made chemicals pervade and support every aspect of modern living. The chemical industry has become such a powerful force in the global economy, sales of synthetic chemicals and products derived from them constitute well in excess of a third of the world's gross national product. But, these man-made chemicals are also 'elixirs of death,' the symbol of human destruction. Laboratory tests have shown that a number of chemicals in common use possess a remarkable property: they can weakly mimic or modify the action of human hormones. It has been proven that some chemicals found in plastics, pesticides, and industrial products are weakly estrogenic, modifying the action of the female hormone. In addition, other chemicals affect the male hormones, androgens, or anti-androgens; others are thought to target different hormone systems, such as thyroid and adrenal glands. Many research studies are being conducted to establish the impact of chemicals on human health. Of special concern are the rising incidence of testicular cancer, decline in human sperm counts, and the sharp rise of breast cancer. In conclusion, although there is a worldwide debate on the effects of chemical exposure on humans, the significance of findings for human health, concerning testicular and breast cancer, are still unknown. An international treaty is called for to control the use of the persistent hormonally active chemicals. PMID:12321044

  14. Toxic Chemical System (TCS)

    SciTech Connect

    Del Gandio, P.

    1994-09-01

    The Toxic Chemical System (TCS) will have the capacity to process chemical data, calculate chemical formulas, and format the data into the United States (US) Environmental Protection Agency (EPA) Toxic Chemical Release Inventory Reporting Form R of Section 313 of the Emergency Planning and Community Right-to-Know Act (EPCRA), hereafter be referred to as ``Form R.`` The filing of this form is required of all industries which manufacture, process or otherwise use any EPA listed chemicals in quantities in excess of their threshold planning quantities (TPQ). Facilities required to file the Form R must report the quantities of both routine and accidental releases of listed toxic chemicals on-site during the calendar year and the amount contained in waste products transferred off-site. This paper describes a specialized computer system designed for regulatory compliance.

  15. Hand chemical burns.

    PubMed

    Robinson, Elliot P; Chhabra, A Bobby

    2015-03-01

    There is a vast and ever-expanding variety of potentially harmful chemicals in the military, industrial, and domestic landscape. Chemical burns make up a small proportion of all skin burns, yet they can cause substantial morbidity and mortality. Additionally, the hand and upper extremity are the most frequently involved parts of the body in chemical burns, and therefore these injuries may lead to severe temporary or permanent loss of function. Despite this fact, discussion of the care of these injuries is sparse in the hand surgery literature. Although most chemical burns require only first response and wound care, some require the attention of a specialist for surgical debridement and, occasionally, skin coverage and reconstruction. Exposure to certain chemicals carries the risk of substantial systemic toxicity and even mortality. Understanding the difference between thermal and chemical burns, as well as special considerations for specific compounds, will improve patient treatment outcomes. PMID:25653184

  16. Excimer laser chemical problems

    SciTech Connect

    Tennant, R.; Peterson, N.

    1982-01-01

    Techniques need to be developed to maintain XeF and XeCl laser performance over long periods of time without degradation resulting from chemical processes occurring within the laser. The dominant chemical issues include optical damage, corrosions of laser materials, gas contamination, and control of halogen concentration. Each of these issues are discussed and summarized. The methods of minimizing or controlling the chemical processes involved are presented.

  17. Miniature chemical measurement systems

    SciTech Connect

    Ramsey, J.M.

    1996-12-31

    Prospect of microfabricated monolithic devices that accomplish complete chemical assays is enticing. Early work with microfabricated chemical analysis devices focused on separations methods. More recently reagent manipulation has been integrated with separation devices to create more powerful capabilities. Examples of procedures, other than separations, that have been demonstrated on micromachined structures include reagent mixing, dilution, and reaction, preconcentration through sample stacking and biopolymer tagging for detection. Developments in liquid phase microfabricated chemical analysis devices are reviewed.

  18. Pool chemical blast injury.

    PubMed

    Shippert, Brian W

    2010-04-01

    Swimming pools are one of the most popular forms of recreation in the United States. Pool-related injuries may produce significant morbidity and mortality, and those related to pool chemicals are of particular importance. The majority of injuries associated with pool chemicals are respiratory, with the remainder composed mainly of dermal exposures. There are few case reports about injuries from pool chemicals, and the potential for significant injury from blast force is presented here. PMID:19853968

  19. Chemical Processing Manual

    NASA Technical Reports Server (NTRS)

    Beyerle, F. J.

    1972-01-01

    Chemical processes presented in this document include cleaning, pickling, surface finishes, chemical milling, plating, dry film lubricants, and polishing. All types of chemical processes applicable to aluminum, for example, are to be found in the aluminum alloy section. There is a separate section for each category of metallic alloy plus a section for non-metals, such as plastics. The refractories, super-alloys and titanium, are prime candidates for the space shuttle, therefore, the chemical processes applicable to these alloys are contained in individual sections of this manual.

  20. Apparatus for chemical synthesis

    DOEpatents

    Kong, Peter C. (Idaho Falls, ID); Herring, J. Stephen (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID)

    2011-05-10

    A method and apparatus for forming a chemical hydride is described and which includes a pseudo-plasma-electrolysis reactor which is operable to receive a solution capable of forming a chemical hydride and which further includes a cathode and a movable anode, and wherein the anode is moved into and out of fluidic, ohmic electrical contact with the solution capable of forming a chemical hydride and which further, when energized produces an oxygen plasma which facilitates the formation of a chemical hydride in the solution.

  1. Field emission chemical sensor

    DOEpatents

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  2. 310 Facility chemical specifications

    SciTech Connect

    Hagerty, K.J.

    1997-05-21

    The 300 area Treated Effluent Disposal Facility (TEDF) was designed and built to treat the waste water from the 300 area process sewer system. Several treatment technologies are employed to remove the trace quantities of contaminants in the stream, including iron coprecipitation, clarification, filtration, ion exchange, and ultra violet light/hydrogen peroxide oxidation of organics. The chemicals that will be utilized in the treatment process are hydrogen peroxide, sulfuric acid, sodium hydroxide, and ferric chloride. This document annotates the required chemical characteristics of TEDF bulk chemicals as well as the criteria that were used to establish these criteria. The chemical specifications in appendix B are generated from this information.

  3. CHEMICAL CATEGORIES IN EPA'S NEW CHEMICALS PROGRAM

    EPA Science Inventory

    Under section 5 of the Toxic Substances Control Act (TSCA),any person who intends to manufacture or import a new chemical substance, or mixture containing such a substance, in the United States for commercial purposes must submit a premanufacture notice (PMN) to the Environmental...

  4. Biomass, Chemicals from

    SciTech Connect

    Elliott, Douglas C.

    2004-03-15

    This chapter describes the use and potential use of biomass resources for chemical production as a means to displace petroleum use. Therefore, the scope of the discussion is limited to large scale, commodity chemical products that can have an impact on the energy market by displacing petroleum conversion to chemical products. This article does not address in detail specialty chemical products whose limited market would have minimal impact on energy markets; nor does it describe in detail the use of biomass for material products such as cellulosic fiber for paper or lignocellulosic material for construction materials. The use of biomass for production of a vast array of specialty chemicals based on unique biochemical structures is another part of the overall concept of a sustainable economy, but is outside the scope of this article. Chemical production from biomass is an energy issue in that biomass-derived chemicals can result in a significant impact on the petroleum requirement for petrochemicals used in modern society. Petroleum thus displaced is available for use in the energy market. Petroleum utilization for chemicals production is reported at 14% of the petroleum market in the United States. Displacement of a significant fraction of this chemical synthesis from petroleum can provide an important impact on the overall market. In 1998 the U.S. Department of Energy stated as its goal the production of at least 10% of the basic chemical building blocks from plant-derived renewables by the year 2020 (a five-fold increase) and 50% by 2050 (another five-fold increase). In the long run, utilization of renewable carbon sources for the chemical requirements of society is the only option as fossil sources become more scarce.

  5. Great Lakes: Chemical Monitoring

    ERIC Educational Resources Information Center

    Delfino, Joseph J.

    1976-01-01

    The Tenth Great Lakes Regional Meeting of the American Chemical Society met to assess current Chemical Research activity in the Great Lakes Basin, and addressed to the various aspects of the theme, Chemistry of the Great Lakes. Research areas reviewed included watershed studies, atmospheric and aquatic studies, and sediment studies. (BT)

  6. Chemicals and Allied Products.

    ERIC Educational Resources Information Center

    Nelson, R. F.; Hovious, J. C.

    1978-01-01

    Presents a literature review of wastes from chemical industry, covering publications of 1976-77. This review covers: (1) wastewater treatment by-product type; (2) biological, and physical/chemical treatments; and (3) source treatment. A list of 80 references is also presented. (HM)

  7. Chemical Reaction Problem Solving.

    ERIC Educational Resources Information Center

    Veal, William

    1999-01-01

    Discusses the role of chemical-equation problem solving in helping students predict reaction products. Methods for helping students learn this process must be taught to students and future teachers by using pedagogical skills within the content of chemistry. Emphasizes that solving chemical reactions should involve creative cognition where…

  8. Chemical Equation Balancing.

    ERIC Educational Resources Information Center

    Blakley, G. R.

    1982-01-01

    Reviews mathematical techniques for solving systems of homogeneous linear equations and demonstrates that the algebraic method of balancing chemical equations is a matter of solving a system of homogeneous linear equations. FORTRAN programs using this matrix method to chemical equation balancing are available from the author. (JN)

  9. Chemical sources of current

    NASA Astrophysics Data System (ADS)

    Bagotskii, V. S.; Skundin, A. M.

    The design and operation of primary cells, storage cells, and electrochemical generators are discussed, with attention given to the principles underlying cell processes. Chemical current sources of various types are described. The primary intent of the study is to explain why a particular chemical current source has the properties that it does.

  10. Elemental Chemical Puzzlers

    ERIC Educational Resources Information Center

    Thomas, Nicholas C.

    2009-01-01

    This paper provides nine short chemically based puzzles or problems extensible for use with students from middle school to college. Some of these will strengthen students' recognition of individual elements and element names. Others require students to focus on the salient properties of given chemical elements.

  11. Chemical cloud tracking systems

    NASA Astrophysics Data System (ADS)

    Grim, Larry B.; Gruber, Thomas C., Jr.; Marshall, Martin; Rowland, Brad

    2002-02-01

    This paper describes the Chemical Cloud Tracking System (CCTS) which has been installed at Dugway Proving Ground. The CCTS allows mapping of chemical clouds in real time from a safe standoff distance. The instruments used are passive standoff chemical agent detectors (FTIRs). Each instrument individually can only measure the total of all the chemical in its line-of-site; the distance to the cloud is unknown. By merging data from multiple vantage points (either one instrument moving past the cloud or two or more instruments spaced so as to view the cloud from different directions) a map of the cloud locations can be generated using tomography. To improve the sensitivity and accuracy of the cloud map, chemical point sensors can be added to the sensor array being used. The equipment required for the CCTS is commercially available. Also, the data fusion techniques (tomography) have been demonstrated previously in the medical field. The Chemical Cloud Tracking System can monitor the movement of many chemical clouds of either military or industrial origin. Since the technique is standoff, the personnel are not exposed to toxic hazards while they follow the cloud. Also, the equipment works on-the-move which allows rapid response to emergency situations (plant explosions, tanker car accidents, chemical terrorism, etc.).

  12. Microorganisms and Chemical Pollution

    ERIC Educational Resources Information Center

    Alexander, M.

    1973-01-01

    Discusses the importance of microorganisms in chemical pollution and pollution abatement. Selected chemical pollutants are chosen to illustrate that microorganisms synthesize hazardous substances from reasonably innocuous precursors, while others act as excellent environmental decontaminating agents by removing undesirable natural and synthetic

  13. Microorganisms and Chemical Pollution

    ERIC Educational Resources Information Center

    Alexander, M.

    1973-01-01

    Discusses the importance of microorganisms in chemical pollution and pollution abatement. Selected chemical pollutants are chosen to illustrate that microorganisms synthesize hazardous substances from reasonably innocuous precursors, while others act as excellent environmental decontaminating agents by removing undesirable natural and synthetic…

  14. Difficult Decisions: Chemical Warfare.

    ERIC Educational Resources Information Center

    Slesnick, Irwin L.; Miller, John A.

    1988-01-01

    Gives the background history and chemistry of modern day chemical warfare from World War I to the present. Provides discussion questions to stimulate deeper thinking on the issue. Contains a discussion activity called "Can New Chemical Weapons Lead to Humane Warfare?" (CW)

  15. Chemical Reaction Problem Solving.

    ERIC Educational Resources Information Center

    Veal, William

    1999-01-01

    Discusses the role of chemical-equation problem solving in helping students predict reaction products. Methods for helping students learn this process must be taught to students and future teachers by using pedagogical skills within the content of chemistry. Emphasizes that solving chemical reactions should involve creative cognition where

  16. Chemicals in Everyday Life.

    ERIC Educational Resources Information Center

    Seymour, Raymond B.

    1987-01-01

    Discusses the dependencies of people on chemicals in various aspects of life. Describes some of the natural and synthetic chemicals currently used in food production, clothing, shelter, travel and exploration, sports and recreation, ventilation, heating and cooling, communications, decoration, sanitation, and education. (TW)

  17. Chemical Compositions of Stars

    NASA Astrophysics Data System (ADS)

    Leckrone, D.; Murdin, P.

    2000-11-01

    In 1835, in a famously inaccurate forecast, the French philosopher Auguste Comte wrote of stars that, `We understand the possibility of determining their shapes, their distances, their sizes and their movements; whereas we would never know how to study by any means their chemical composition…'. At the close of the 20th century the accurate measurement of the abundances of the chemical elements in...

  18. Tortuous path chemical preconcentrator

    DOEpatents

    Manginell, Ronald P. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Adkins, Douglas R. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); Simonson, Robert J. (Cedar Crest, NM)

    2010-09-21

    A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.

  19. Chemical recognition software

    SciTech Connect

    Wagner, J.S.; Trahan, M.W.; Nelson, W.E.; Hargis, P.J. Jr.; Tisone, G.C.

    1994-12-01

    We have developed a capability to make real time concentration measurements of individual chemicals in a complex mixture using a multispectral laser remote sensing system. Our chemical recognition and analysis software consists of three parts: (1) a rigorous multivariate analysis package for quantitative concentration and uncertainty estimates, (2) a genetic optimizer which customizes and tailors the multivariate algorithm for a particular application, and (3) an intelligent neural net chemical filter which pre-selects from the chemical database to find the appropriate candidate chemicals for quantitative analyses by the multivariate algorithms, as well as providing a quick-look concentration estimate and consistency check. Detailed simulations using both laboratory fluorescence data and computer synthesized spectra indicate that our software can make accurate concentration estimates from complex multicomponent mixtures. even when the mixture is noisy and contaminated with unknowns.

  20. Chemical recognition software

    SciTech Connect

    Wagner, J.S.; Trahan, M.W.; Nelson, W.E.; Hargis, P.H. Jr.; Tisone, G.C.

    1994-06-01

    We have developed a capability to make real time concentration measurements of individual chemicals in a complex mixture using a multispectral laser remote sensing system. Our chemical recognition and analysis software consists of three parts: (1) a rigorous multivariate analysis package for quantitative concentration and uncertainty estimates, (2) a genetic optimizer which customizes and tailors the multivariate algorithm for a particular application, and (3) an intelligent neural net chemical filter which pre-selects from the chemical database to find the appropriate candidate chemicals for quantitative analyses by the multivariate algorithms, as well as providing a quick-look concentration estimate and consistency check. Detailed simulations using both laboratory fluorescence data and computer synthesized spectra indicate that our software can make accurate concentration estimates from complex multicomponent mixtures, even when the mixture is noisy and contaminated with unknowns.

  1. Chemical process hazards analysis

    SciTech Connect

    1996-02-01

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  2. Chemical warfare agents

    PubMed Central

    Ganesan, K.; Raza, S. K.; Vijayaraghavan, R.

    2010-01-01

    Among the Weapons of Mass Destruction, chemical warfare (CW) is probably one of the most brutal created by mankind in comparison with biological and nuclear warfare. Chemical weapons are inexpensive and are relatively easy to produce, even by small terrorist groups, to create mass casualties with small quantities. The characteristics of various CW agents, general information relevant to current physical as well as medical protection methods, detection equipment available and decontamination techniques are discussed in this review article. A brief note on Chemical Weapons Convention is also provided. PMID:21829312

  3. Chemical synthesis in microreactors.

    PubMed

    Watts, Paul; Haswell, Stephen J

    2010-01-01

    To develop a new generation of drugs, pharmaceutical companies need to be able to synthesise and screen novel chemicals with enhanced speed. New technology that would enable a cost neutral step change in the number of potential drug candidates would provide a distinct competitive advantage. Indeed the miniaturisation of chemical reactors offers many fundamental and practical advantages of relevance to the pharmaceutical industry, who are constantly searching for controllable, information-rich, high-throughput, environmentally friendly methods of producing products with a high degree of chemical selectivity. This chapter reviews the current and future applications of microreactors that could enhance the drug discovery process. PMID:19763461

  4. Chemical Hygiene Program

    NASA Technical Reports Server (NTRS)

    Mayor, Antoinette C.

    1999-01-01

    The Chemical Management Team is responsible for ensuring compliance with the OSHA Laboratory Standard. The program at Lewis Research Center (LeRC) evolved over many years to include training, developing Standard Operating Procedures (SOPS) for each laboratory process, coordinating with other safety and health organizations and teams at the Center, and issuing an SOP binder. The Chemical Hygiene Policy was first established for the Center. The Chemical Hygiene Plan was established and reviewed by technical, laboratory and management for viability and applicability to the Center. A risk assessment was conducted for each laboratory. The laboratories were prioritized by order of risk, higher risk taking priority. A Chemical Management Team staff member interviewed the lead researcher for each laboratory process to gather the information needed to develop the SOP for the process. A binder containing the Chemical Hygiene Plan, the SOP, a map of the laboratory identifying the personal protective equipment and best egress, and glove guides, as well as other guides for safety and health. Each laboratory process has been captured in the form of an SOP. The chemicals used in the procedure have been identified and the information is used to reduce the number of chemicals in the lab. The Chemical Hygiene Plan binder is used as a training tool for new employees. LeRC is in compliance with the OSHA Standard. The program was designed to comply with the OSHA standard. In the process, we have been able to assess the usage of chemicals in the laboratories, as well as reduce or relocate the chemicals being stored in the laboratory. Our researchers are trained on the hazards of the materials they work with and have a better understanding of the hazards of the process and what is needed to prevent any incident. From the SOP process, we have been able to reduce our chemical inventory, determine and implement better hygiene procedures and equipment in the laboratories, and provide specific training to our employees. As a result of this program, we are adding labeling to the laboratories for emergency responders and initiating a certified chemical user program.

  5. Chemical Principles Exemplified

    ERIC Educational Resources Information Center

    Plumb, Robert C.

    1972-01-01

    Collection of two short descriptions of chemical principles seen in life situations: the autocatalytic reaction seen in the bombardier beetle, and molecular potential energy used for quick roasting of beef. Brief reference is also made to methanol lighters. (PS)

  6. Chemical Bonds II

    ERIC Educational Resources Information Center

    Sanderson, R. T.

    1972-01-01

    The continuation of a paper discussing chemical bonding from a bond energy viewpoint, with a number of examples of single and multiple bonds. (Part I appeared in volume 1 number 3, pages 16-23, February 1972.) (AL)

  7. Reflections on Chemical Equations.

    ERIC Educational Resources Information Center

    Gorman, Mel

    1981-01-01

    The issue of how much emphasis balancing chemical equations should have in an introductory chemistry course is discussed. The current heavy emphasis on finishing such equations is viewed as misplaced. (MP)

  8. Chemical Safety Programs.

    ERIC Educational Resources Information Center

    Shaw, Richard

    2000-01-01

    Discusses the need to enhance understanding of chemical safety in educational facilities that includes adequate staff training and drilling requirements. The question of what is considered proper training is addressed. (GR)

  9. Legendary Chemical Aphrodisiacs.

    ERIC Educational Resources Information Center

    Waddell, Thomas G.; And Others

    1980-01-01

    Presents a survey of the literature and a summary of information regarding aphrodisiacs. Chemical compounds are discussed as groups of plant natural products, animal natural products, and synthetic products. (CS)

  10. Sawmill chemicals and carcinogenesis.

    PubMed

    Huff, J

    2001-03-01

    Workers in wood industries are exposed to variable medleys of chemicals, both natural and synthetic. Additional exposures include fungi, bacteria, bark and wood dusts, solvents, paints, and various other wood coatings. These individual and conglomerate exposures have been associated with diverse occupational illnesses and hazards, including cancers. In this commentary, I summarize both experimental and epidemiologic carcinogenesis results for several chemicals used in the wood industry, as well as for wood dust. Working in the wood industries entails excess risks of cancers, among other diseases and workplace injuries. A key to preventing occupationally and environmentally associated cancers, as in the wood industries, is avoiding exposures to chemicals and wood dusts and, in particular, chemicals known to cause cancer in animals or/and humans. PMID:11333179

  11. Chemical Physics Summer School

    SciTech Connect

    2002-06-28

    The Gordon Research Conference (GRC) on Chemical Physics Summer School was held at Roger Williams University, Bristol, RI. Emphasis was placed on current unpublished research and discussion of the future target areas in this field.

  12. Topics in Chemical Instrumentation.

    ERIC Educational Resources Information Center

    Settle, Frank A. Jr., Ed.

    1989-01-01

    Using Fourier transformation methods in nuclear resonance has made possible increased sensitivity in chemical analysis. This article describes data acquisition, data processing, and the frequency spectrum as they relate to this technique. (CW)

  13. A bionics chemical synapse.

    PubMed

    Thanapitak, Surachoke; Toumazou, Christofer

    2013-06-01

    Implementation of the current mode CMOS circuit for chemical synapses (AMPA and NMDA receptors) with dynamic change of glutamate as the neurotransmitter input is presented in this paper. Additionally, circuit realisation for receptor GABA(A) and GABA(B) with an electrical signal which symbolises γ-Aminobutyric Acid (GABA) perturbation is introduced. The chemical sensor for glutamate sensing is the modified ISFET with enzyme (glutamate oxidase) immobilisation. The measured results from these biomimetics chemical synapse circuits closely match with the simulation result from the mathematical model. The total power consumption of the whole chip (four chemical synapse circuits and all auxiliary circuits) is 168.3 μW. The total chip area is 3 mm(2) in 0.35-μm AMS CMOS technology. PMID:23853329

  14. Chemicals from coal

    SciTech Connect

    Harold A. Wittcoff; Bryan G. Reuben; Jeffrey S. Plotkin

    2004-12-01

    This chapter contains sections titled: Chemicals from Coke Oven Distillate; The Fischer-Tropsch Reaction; Coal Hydrogenation; Substitute Natural Gas (SNG); Synthesis Gas Technology; Calcium Carbide; Coal and the Environment; and Notes and References

  15. Chemical dependence - resources

    MedlinePLUS

    Drug abuse - resources; Resources - chemical dependence ... The following organizations are a good resource for information on drug dependence: National Council on Alcoholism and Drug Dependence -- ncadd.org National Institute on Drug Abuse -- www.drugabuse.gov ...

  16. Chemical Engineering at NASA

    NASA Technical Reports Server (NTRS)

    Collins, Jacob

    2008-01-01

    This viewgraph presentation is a review of the career paths for chemicals engineer at NASA (specifically NASA Johnson Space Center.) The author uses his personal experience and history as an example of the possible career options.

  17. Common chemical agent threats.

    PubMed

    McCafferty, Randall R; Lennarson, Peter J

    2002-03-15

    The events of September 11, 2001, highlight the fact that we live in precarious times. National and global awareness of the resolve and capabilities of terrorists has increased. The possibility that the civilian neurosurgeon may confront a scenario involving the use of chemical warfare agents has heightened. The information reported in this paper serves as a primer on the recognition, decontamination, and treatment of trauma patients exposed to chemical warfare agents. PMID:16212313

  18. Quantum Chemical Calculations

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W.; Arnold, James O. (Technical Monitor)

    1997-01-01

    The current methods of quantum chemical calculations will be reviewed. The accent will be on the accuracy that can be achieved with these methods. The basis set requirements and computer resources for the various methods will be discussed. The utility of the methods will be illustrated with some examples, which include the calculation of accurate bond energies for SiF$_n$ and SiF$_n^+$ and the modeling of chemical data storage.

  19. Integrated Chemical List

    Cancer.gov

    Some Long Island breast cancer advocates, who have been interested in the Long Island Breast Cancer Study Project (LIBCSP), submitted a list of chemicals and other agents of concern to them as possible causes of breast cancer. Many of the agents are already included in the LIBCSP. The table lists both the agents of community interest and those included in the LIBCSP, and is called the Integrated Chemical List.

  20. The U.S. Chemical Industry, Foreign Chemical Industries

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1972

    1972-01-01

    This section of the annual report on the chemical industry provides data on the chemical production of Japan, West Germany, United Kingdom, Italy, and France, including the output of major chemical products in these nations. (PR)

  1. Chemical information systems

    SciTech Connect

    Zebora, M.

    1994-12-31

    The growing number of Federal and State regulations today from EPA to OSHA is putting a large burden on organizations to comply with regard to chemicals in the work place. The cornerstone of chemical information is the Material Safety Data Sheet (MSDS). The MSDS has been a requirement for chemical manufacturers for over fifteen years. Manufacturers of hazardous materials must provide MSDSs to purchasers. However, recent additional regulations from OSHA, in particular the Right To Know and the Hazard Communication Standard (Haz-Com) require that employers who use chemicals must be capable of providing an MSDS to every employee that requests one for a material that they work with. Paper filing systems to managing MSDSs are hard to maintain, costly, and inefficient. In multifacility organizations this can result in delays in distributions of those MSDSs to employees. At AT and T Bell Laboratories the Environmental Health and Safety Center has invested over a decade of development work into producing an integrated Chemical Inventory System/MSDS System. That system meets the requirements discussed in this paper and serves six major R and D laboratory facilities in three states. The system resides on a desktop personal computer. Operation of the system relies on teamwork between several diverse organizations which are involved in management of chemical safety at AT and T Bell Laboratories. The departments represented on that team are Industrial Hygiene and Safety, Environmental Management, Facilities Operations, Purchasing, Health Services, Research, and Environmental Data Management Services.

  2. The Chemical Revolution revisited.

    PubMed

    Chang, Hasok

    2015-02-01

    I respond to the critical comments by Martin Kusch and Ursula Klein on my account of the Chemical Revolution. I comment along three different lines: descriptive, explanatory, and normative. (1) I agree with Klein that Lavoisier did not introduce drastic changes in chemical ontology, but maintain that there was methodological incommensurability in the Chemical Revolution; in response to Kusch's view, I maintain that Lavoisier's victory was slow and incomplete. (2) Admitting that there were many causes shaping the outcome of the Chemical Revolution, including the convenience of Lavoisier's theoretical scheme and various complicated social factors, I still think that the general rise of compositionism was an important factor. (3) I defend my normative pluralist view on the Chemical Revolution, denying Kusch's argument that chemists had overwhelmingly good reasons to trust Lavoisier and his allies over the phlogistonists. Overall, I agree with Kusch that it would be desirable to have a good descriptive-normative sociological account of the Chemical Revolution, but I also think that it should be an account that allows for divergence in individuals' and sub-communities' self-determination. PMID:26109414

  3. Chemical modification of silicene

    NASA Astrophysics Data System (ADS)

    Wang, Rong; Xu, Ming-Sheng; Pi, Xiao-Dong

    2015-08-01

    Silicene is a two-dimensional (2D) material, which is composed of a single layer of silicon atoms with sp2-sp3 mixed hybridization. The sp2-sp3 mixed hybridization renders silicene excellent reactive ability, facilitating the chemical modification of silicene. It has been demonstrated that chemical modification effectively enables the tuning of the properties of silicene. We now review all kinds of chemical modification methods for silicene, including hydrogenation, halogenation, organic surface modification, oxidation, doping and formation of 2D hybrids. The effects of these chemical modification methods on the geometrical, electronic, optical, and magnetic properties of silicene are discussed. The potential applications of chemically modified silicene in a variety of fields such as electronics, optoelectronics, and magnetoelectronics are introduced. We finally envision future work on the chemical modification of silicene for further advancing the development of silicene. Project supported by the National Basic Program of China (Grant No. 2013CB632101), the National Natural Science Foundation of China (Grant Nos. 61222404 and 61474097), and the Fundamental Research Funds for the Central Universities of China (Grant No. 2014XZZX003-09).

  4. Biological and Chemical Security

    SciTech Connect

    Fitch, P J

    2002-12-19

    The LLNL Chemical & Biological National Security Program (CBNP) provides science, technology and integrated systems for chemical and biological security. Our approach is to develop and field advanced strategies that dramatically improve the nation's capabilities to prevent, prepare for, detect, and respond to terrorist use of chemical or biological weapons. Recent events show the importance of civilian defense against terrorism. The 1995 nerve gas attack in Tokyo's subway served to catalyze and focus the early LLNL program on civilian counter terrorism. In the same year, LLNL began CBNP using Laboratory-Directed R&D investments and a focus on biodetection. The Nunn-Lugar-Domenici Defense Against Weapons of Mass Destruction Act, passed in 1996, initiated a number of U.S. nonproliferation and counter-terrorism programs including the DOE (now NNSA) Chemical and Biological Nonproliferation Program (also known as CBNP). In 2002, the Department of Homeland Security was formed. The NNSA CBNP and many of the LLNL CBNP activities are being transferred as the new Department becomes operational. LLNL has a long history in national security including nonproliferation of weapons of mass destruction. In biology, LLNL had a key role in starting and implementing the Human Genome Project and, more recently, the Microbial Genome Program. LLNL has over 1,000 scientists and engineers with relevant expertise in biology, chemistry, decontamination, instrumentation, microtechnologies, atmospheric modeling, and field experimentation. Over 150 LLNL scientists and engineers work full time on chemical and biological national security projects.

  5. Chemically Powered Nanomotors

    NASA Astrophysics Data System (ADS)

    Kapral, Raymond

    2007-03-01

    Molecular motors play important roles in transport in biological systems. These molecular machines are powered by chemical energy and operate in the regime of low Reynolds number hydrodynamics. Recently a class of simple inorganic molecular motors has been constructed and studied experimentally [1,2]. These motors are bimetallic rods, one end of which is chemically active. The talk will describe simple mesoscopic models for the motion of such nanomotors. The motor consists of two linked spheres, one of which catalyzes the conversion between two chemical species. The chemical species interact differently with the the two spheres in the dimer. The nano-dimer motor is solvated by a molecules treated at a mesoscopic level whose evolution is governed by multi-particle collision dynamics. The dynamics conserves mass, momentum and energy so that coupling between the nanomotor and the hydrodynamic modes of the solvent is treated correctly. The simulations allow one to explore the mechanisms of the chemically powered motion and the effects of fluctuations on the motor dynamics. [1] W. F. Paxton, et al., ``Catalytic Nanomotors: Autonomous Movement of Striped Nanorods,'' J. Am. Chem. Soc. (JACS), 126 (41), 13424 (2004). [2] S. Fournier-Bidoz, et al. ``Synthetic Self-Propelled Nanorotors,'' Chem. Commun., (4), 441 (2005).

  6. Chemical Equilibrium And Transport (CET)

    NASA Technical Reports Server (NTRS)

    Mcbride, B. J.

    1991-01-01

    Powerful, machine-independent program calculates theoretical thermodynamic properties of chemical systems. Aids in design of compressors, turbines, engines, heat exchangers, and chemical processing equipment.

  7. Advanced Chemical Propulsion Study

    NASA Technical Reports Server (NTRS)

    Woodcock, Gordon; Byers, Dave; Alexander, Leslie A.; Krebsbach, Al

    2004-01-01

    A study was performed of advanced chemical propulsion technology application to space science (Code S) missions. The purpose was to begin the process of selecting chemical propulsion technology advancement activities that would provide greatest benefits to Code S missions. Several missions were selected from Code S planning data, and a range of advanced chemical propulsion options was analyzed to assess capabilities and benefits re these missions. Selected beneficial applications were found for higher-performing bipropellants, gelled propellants, and cryogenic propellants. Technology advancement recommendations included cryocoolers and small turbopump engines for cryogenic propellants; space storable propellants such as LOX-hydrazine; and advanced monopropellants. It was noted that fluorine-bearing oxidizers offer performance gains over more benign oxidizers. Potential benefits were observed for gelled propellants that could be allowed to freeze, then thawed for use.

  8. Micromachined chemical jet dispenser

    DOEpatents

    Swierkowski, S.P.

    1999-03-02

    A dispenser is disclosed for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 {micro}m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (ca. 200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments. 4 figs.

  9. Micromachined chemical jet dispenser

    DOEpatents

    Swierkowski, Steve P.

    1999-03-02

    A dispenser for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 .mu.m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (.about.200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments.

  10. Chemical Kinetics Database

    National Institute of Standards and Technology Data Gateway

    SRD 17 NIST Chemical Kinetics Database (Web, free access)   The NIST Chemical Kinetics Database includes essentially all reported kinetics results for thermal gas-phase chemical reactions. The database is designed to be searched for kinetics data based on the specific reactants involved, for reactions resulting in specified products, for all the reactions of a particular species, or for various combinations of these. In addition, the bibliography can be searched by author name or combination of names. The database contains in excess of 38,000 separate reaction records for over 11,700 distinct reactant pairs. These data have been abstracted from over 12,000 papers with literature coverage through early 2000.

  11. Chemical Domino Demonstration

    NASA Astrophysics Data System (ADS)

    Alexander, M. Dale

    1998-04-01

    The Chemical Domino Demonstration is both educational and entertaining. It provides an excellent means for a review of chemical concepts at the conclusion of a general chemistry course. This demonstration consists of a number of different chemical reactions occurring in sequence in a Rube Goldberg-type apparatus. These reactions include the reduction of water by an active metal, the oxidation of a moderately active metal by an acid, reduction of metallic ions by a metal of greater activity, acid-base neutralization reactions in solution monitored with indicators, a gas-phase acid-base neutralization reaction, decomposition of a compound, precipitation of an insoluble salt, substitution reactions of coordination complexes, and pyrotechnic oxidation-reduction reactions including a hypergolic oxidation-reduction reaction, an intramolecular oxidation-reduction reaction, and the combustion of a flammable gas.

  12. Equilibria in Chemical Systems

    Energy Science and Technology Software Center (ESTSC)

    1992-01-01

    SOLGASMIX-PV calculates equilibrium relationships in complex chemical systems. Chemical equilibrium calculations involve finding the system composition, within certain constraints, which contains the minimum free energy. The constraints are the preservation of the masses of each element present and either constant pressure or volume. SOLGASMIX-PV can calculate equilibria in systems containing a gaseous phase, condensed phase solutions, and condensed phases of invariant and variable stoichiometry. Either a constant total gas volume or a constant total pressuremore » can be assumed. Unit activities for condensed phases and ideality for solutions are assumed, although nonideal systems can be handled provided activity coefficient relationships are available.« less

  13. Pazufloxacin Toyama Chemical Co.

    PubMed

    Johnson, A P

    2000-09-01

    Toyama Chemical Co Ltd is developing pazufloxacin (T-3761), an orally active synthetic quinolone antibiotic, which is awaiting registration following successful clinical trials that demonstrated its pharmacological similarities to tosufloxacin (Toyama Chemical Co) with respect to clinical efficacy, adverse effects and overall safety [272136]. As of June 2000, the company had filed an NDA for marketing approval in Japan [373027]. The company is also developing an injectable formulation, pazufloxacin mesylate (T-3762), which has entered phase III trials in Japan [228819]. There is a licensing agreement with Welfide Corp (formerly Yoshitomi/The Green Cross Corp) in Japan [228819]. PMID:11249595

  14. Chemical crowd control agents.

    PubMed

    Menezes, Ritesh G; Hussain, Syed Ather; Rameez, Mansoor Ali Merchant; Kharoshah, Magdy A; Madadin, Mohammed; Anwar, Naureen; Senthilkumaran, Subramanian

    2016-03-01

    Chemical crowd control agents are also referred to as riot control agents and are mainly used by civil authorities and government agencies to curtail civil disobedience gatherings or processions by large crowds. Common riot control agents used to disperse large numbers of individuals into smaller, less destructive, and more easily controllable numbers include chloroacetophenone, chlorobenzylidenemalononitrile, dibenzoxazepine, diphenylaminearsine, and oleoresin capsicum. In this paper, we discuss the emergency medical care needed by sufferers of acute chemical agent contamination and raise important issues concerning toxicology, safety and health. PMID:26658556

  15. Idaho Chemical Processing Plant safety document ICPP hazardous chemical evaluation

    SciTech Connect

    Harwood, B.J.

    1993-01-01

    This report presents the results of a hazardous chemical evaluation performed for the Idaho Chemical Processing Plant (ICPP). ICPP tracks chemicals on a computerized database, Haz Track, that contains roughly 2000 individual chemicals. The database contains information about each chemical, such as its form (solid, liquid, or gas); quantity, either in weight or volume; and its location. The Haz Track database was used as the primary starting point for the chemical evaluation presented in this report. The chemical data and results presented here are not intended to provide limits, but to provide a starting point for nonradiological hazards analysis.

  16. Chemical Bonds I

    ERIC Educational Resources Information Center

    Sanderson, R. T.

    1972-01-01

    Chemical bonding is discussed from a bond energy, rather than a wave mechanics, viewpoint. This approach is considered to be more suitable for the average student. (The second part of the article will appear in a later issue of the journal.) (AL)

  17. Endocrine Disrupting Chemicals (EDCs)

    MedlinePLUS

    ... the bloodstream. This hormone is necessary for normal brain development, control of metabolism, and other aspects of maintaining healthy bodies. Studies have shown that many industrial chemicals can ... of nerves in the brain, spine, and throughout the body. It controls overall ...

  18. NETL - Chemical Looping Reactor

    SciTech Connect

    2013-07-24

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  19. Chemical reacting flows

    NASA Technical Reports Server (NTRS)

    Mularz, Edward J.; Sockol, Peter M.

    1990-01-01

    Future aerospace propulsion concepts involve the combustion of liquid or gaseous fuels in a highly turbulent internal airstream. Accurate predictive computer codes which can simulate the fluid mechanics, chemistry, and turbulence-combustion interaction of these chemical reacting flows will be a new tool that is needed in the design of these future propulsion concepts. Experimental and code development research is being performed at LeRC to better understand chemical reacting flows with the long-term goal of establishing these reliable computer codes. Our approach to understand chemical reacting flows is to look at separate, more simple parts of this complex phenomenon as well as to study the full turbulent reacting flow process. As a result, we are engaged in research on the fluid mechanics associated with chemical reacting flows. We are also studying the chemistry of fuel-air combustion. Finally, we are investigating the phenomenon of turbulence-combustion interaction. Research, both experimental and analytical, is highlighted in each of these three major areas.

  20. Electro-chemical grinding

    NASA Technical Reports Server (NTRS)

    Feagans, P. L.

    1972-01-01

    Electro-chemical grinding technique has rotation speed control, constant feed rates, and contour control. Hypersonic engine parts of nickel alloys can be almost 100% machined, keeping tool pressure at virtual zero. Technique eliminates galling and permits constant surface finish and burr-free interrupted cutting.

  1. Chemical Aspects of Dentistry.

    ERIC Educational Resources Information Center

    Helfman, Murry

    1982-01-01

    Dental caries (tooth decay) and periodontal (gum) disease are treated/prevented by procedures utilizing chemical expertise. Procedures and suggestions on how they might be incorporated into the high school chemistry curriculum are described. Specific topics discussed include dental caries, fluoride, diet, tooth decay prevention, silver amalgan,

  2. Chemical hygiene plan

    SciTech Connect

    Not Available

    1994-09-01

    This plan was written to administer and monitor safety measures and chemical hygiene principles in the TAC Uranium Mill Tailing Remedial Action Project sample preparation facility in Albuquerque, New Mexico. It applies to toxic and/or hazardous materials to radioactive materials.

  3. Chemical Aspects of Dentistry.

    ERIC Educational Resources Information Center

    Helfman, Murry

    1982-01-01

    Dental caries (tooth decay) and periodontal (gum) disease are treated/prevented by procedures utilizing chemical expertise. Procedures and suggestions on how they might be incorporated into the high school chemistry curriculum are described. Specific topics discussed include dental caries, fluoride, diet, tooth decay prevention, silver amalgan,…

  4. Endocrine disrupting chemicals

    PubMed Central

    Yeung, Bonnie HY; Wan, Hin T; Law, Alice YS

    2011-01-01

    In the past 200 years, an enormous number of synthetic chemicals with diverse structural features have been produced for industrial, medical and domestic purposes. These chemicals, originally thought to have little or no biological toxicity, are widely used in our daily lives as well as are commonly present in foods. It was not until the first World Wildlife Federation Wingspread Conference held in 1994 were concerns about the endocrine disrupting (ED) effects of these chemicals articulated. The potential hazardous effects of endocrine disrupting chemicals (EDCs) on human health and ecological well-being are one of the global concerns that affect the health and propagation of human beings. Considerable numbers of studies indicated that endocrine disruption is linked to “the developmental basis of adult disease,” highlighting the significant effects of EDC exposure on a developing organism, leading to the propensity of an individual to develop a disease or dysfunction in later life. In this review, we intend to provide environmental, epidemiological and experimental data to associate pollutant exposure with reproductive disorders, in particular on the development and function of the male reproductive system. Possible effects of pollutant exposure on the processes of embryonic development, like sex determination and masculinization are described. In addition, the effects of pollutant exposure on hypothalamus-pituitary-gonadal axis, testicular signaling, steroidogenesis and spermatogenesis are also discussed. PMID:22319671

  5. NETL - Chemical Looping Reactor

    ScienceCinema

    None

    2014-06-26

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  6. CHEMICALLY REACTING TURBULENT JETS

    EPA Science Inventory

    The paper reports additional experimental evidence supporting a new description of the mechanism of turbulent entrainment, mixing, and chemical reactions that is emerging from experiments in the last few years which reveal the presence of large scale structures in turbulent shear...

  7. Advanced Chemical Propulsion

    NASA Technical Reports Server (NTRS)

    Alexander, Leslie, Jr.

    2006-01-01

    Advanced Chemical Propulsion (ACP) provides near-term incremental improvements in propulsion system performance and/or cost. It is an evolutionary approach to technology development that produces useful products along the way to meet increasingly more demanding mission requirements while focusing on improving payload mass fraction to yield greater science capability. Current activities are focused on two areas: chemical propulsion component, subsystem, and manufacturing technologies that offer measurable system level benefits; and the evaluation of high-energy storable propellants with enhanced performance for in-space application. To prioritize candidate propulsion technology alternatives, a variety of propulsion/mission analyses and trades have been conducted for SMD missions to yield sufficient data for investment planning. They include: the Advanced Chemical Propulsion Assessment; an Advanced Chemical Propulsion System Model; a LOx-LH2 small pumps conceptual design; a space storables propellant study; a spacecraft cryogenic propulsion study; an advanced pressurization and mixture ratio control study; and a pump-fed vs. pressure-fed study.

  8. Epigenetics and environmental chemicals

    PubMed Central

    Baccarelli, A; Bollati, V.

    2011-01-01

    Purpose of the review Epigenetics investigates heritable changes in gene expression occurring without changes in DNA sequence. Several epigenetic mechanisms, including DNA methylation, histone modifications, and microRNA (miRNA) expression, can change genome function under exogenous influence. Here, we review current evidence indicating that epigenetic alterations mediate toxicity from environmental chemicals. Recent findings In-vitro, animal, and human investigations have identified several classes of environmental chemicals that modify epigenetic marks, including metals (cadmium, arsenic, nickel, chromium, methylmercury), peroxisome proliferators (trichloroethylene, dichloroacetic acid, trichloroacetic acid), air pollutants (particulate matter, black carbon, benzene), and endocrine-disrupting/reproductive toxicants (diethylstilbestrol, bisphenol A, persistent organic pollutants, dioxin). Most studies conducted so far have been centered on DNA methylation, whereas only a few investigations have studied environmental chemicals in relation to histone modications and miRNA. Summary For several exposures, it has been proved that chemicals can alter epigenetic marks and that the same or similar epigenetic alterations can be found in patients with the disease of concern or in diseased tissues. Future prospective investigations are needed to determine whether exposed subjects develop epigenetic alterations over time and, in turn, which such alterations increase the risk of disease. Also, further research is needed to determine whether environmental epigenetic changes are transmitted transgenerationally. PMID:19663042

  9. Risks and Chemical Substances.

    ERIC Educational Resources Information Center

    Blumberg, Avrom A.

    1994-01-01

    Examines exposure to chemicals within the home and three important ways in which hazardous substances can be identified and evaluated. Suggests a rational picture of human health risks and contains an introductory discussion of reasons for exposure, epidemiology, cancer causes and patterns, animal testing, toxins, and risk. (LZ)

  10. Common Sense and Chemicals

    ERIC Educational Resources Information Center

    Roy, Ken

    2010-01-01

    This month's column features two true stories about the use of chemicals in the middle school science classroom. The lesson of these stories is simple. Certainly, it is prudent to have age-appropriate experiences in science, given the developmental constraints of students in middle school. On the other hand, when the curriculum necessitates

  11. Making a Chemical Rainbow

    ERIC Educational Resources Information Center

    Angelin, Marcus; Ramstrom, Olof

    2010-01-01

    In this laboratory experiment, high school students are challenged to prepare a six-layered chemical "rainbow" in a test tube. Students start with six unknown, colorless liquids and six pigments ranging from violet to red. The experiment is problem based and forces the students to apply their knowledge of solubility and density and combine it with

  12. Countermeasures to hazardous chemicals

    SciTech Connect

    Holmes, J.M.; Byers, C.H.

    1989-04-01

    Recent major incidents involving the airborne release of hazardous chemicals have led to this study of effective strategies must be developed to prevent and to deal with emergencies. The comprehensive study of FEMA and the various other entities required that the project be divided into three tasks. These included Task 1 (the nature of the threat from incidents involving airborne hazardous chemicals is described. Based on available databases, a new methodology for ranking chemical hazards is proposed and tested); Task 2 (Existing responsibilities of federal, state, and local agencies, as well as the part played by the private sector, have been surveyed. Legislation at all levels of government are reviewed and in light of this analysis, the role of FEMA is examined. Institutional options to new and existing approaches for reducing risk are reevaluated, and recommendations are made for these approaches); and Task 3 (Technical options are discussed in light of the most hazardous situations, and recommendations are made for action or research where needed. Emphasis is laid on new and emerging technologies in the area). Recommendations are offered regarding actions which would improve preparation, training, mitigation, and response on the part of FEMA to the release of hazardous chemicals. 180 refs., 13 figs., 34 tabs.

  13. Chemical Calcium Indicators

    PubMed Central

    Paredes, R. Madelaine; Etzler, Julie C.; Watts, Lora Talley; Lechleiter, James D.

    2008-01-01

    Our understanding of the underlying mechanisms of Ca2+ signaling as well as our appreciation for its ubiquitous role in cellular processes and has been rapidly advanced, in large part, due to the development of fluorescent Ca2+ indicators. In this chapter, we discuss some of the most common chemical Ca2+ indicators that are widely used for the investigation of intracellular Ca2+ signaling. Advantages, limitations and relevant procedures will be presented for each dye including their spectral qualities, dissociation constants, chemical forms, loading methods and equipment for optimal imaging. Chemical indicators that are now available allow for intracellular Ca2+ detection over a very large range (<50 nM to >50 ?M). Higher affinity indicators can be used to quantify Ca2+ levels in the cytosol while lower affinity indicators can be optimized for measuring Ca2+ in subcellular compartments with higher concentrations. Indicators can be classified into either single wavelength or ratiometric dyes. Both classes require specific lasers, filters, and/or detection methods that are dependent upon their spectral properties and both classes have advantages and limitations. Single wavelength indicators are generally very bright and optimal for Ca2+ detection when more than one fluorophore is being imaging. Ratiometric indicators can be calibrated very precisely and they minimize the most common problems associated with chemical Ca2+ indicators including uneven dye loading, leakage, photobleaching and changes in cell volume. Recent technical advances that permit in vivo Ca2+ measurements will also be discussed. PMID:18929663

  14. Chemical Principles Exemplified

    ERIC Educational Resources Information Center

    Plumb, Robert C.

    1970-01-01

    This is the first of a new series of brief ancedotes about materials and phenomena which exemplify chemical principles. Examples include (1) the sea-lab experiment illustrating principles of the kinetic theory of gases, (2) snow-making machines illustrating principles of thermodynamics in gas expansions and phase changes, and (3) sunglasses that

  15. Environmental Chemicals in Breast Milk

    EPA Science Inventory

    Most of the information available on environmental chemicals in breast milk is focused on persistent, lipophilic chemicals; the database on levels of these chemicals has expanded substantially since the 1950s. Currently, various types of chemicals are measured in breast milk and ...

  16. Laboratory Safety and Chemical Hazards.

    ERIC Educational Resources Information Center

    Journal of Chemical Education, 1983

    1983-01-01

    Toxicology/chemical hazards, safety policy, legal responsibilities, adequacy of ventilation, chemical storage, evaluating experimental hazards, waste disposal, and laws governing chemical safety were among topics discussed in 10 papers presented at the Seventh Biennial Conference on Chemical Education (Stillwater, Oklahoma 1982). Several topics

  17. Accurate quantum chemical calculations

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Taylor, Peter R.

    1989-01-01

    An important goal of quantum chemical calculations is to provide an understanding of chemical bonding and molecular electronic structure. A second goal, the prediction of energy differences to chemical accuracy, has been much harder to attain. First, the computational resources required to achieve such accuracy are very large, and second, it is not straightforward to demonstrate that an apparently accurate result, in terms of agreement with experiment, does not result from a cancellation of errors. Recent advances in electronic structure methodology, coupled with the power of vector supercomputers, have made it possible to solve a number of electronic structure problems exactly using the full configuration interaction (FCI) method within a subspace of the complete Hilbert space. These exact results can be used to benchmark approximate techniques that are applicable to a wider range of chemical and physical problems. The methodology of many-electron quantum chemistry is reviewed. Methods are considered in detail for performing FCI calculations. The application of FCI methods to several three-electron problems in molecular physics are discussed. A number of benchmark applications of FCI wave functions are described. Atomic basis sets and the development of improved methods for handling very large basis sets are discussed: these are then applied to a number of chemical and spectroscopic problems; to transition metals; and to problems involving potential energy surfaces. Although the experiences described give considerable grounds for optimism about the general ability to perform accurate calculations, there are several problems that have proved less tractable, at least with current computer resources, and these and possible solutions are discussed.

  18. The chemical space project.

    PubMed

    Reymond, Jean-Louis

    2015-03-17

    One of the simplest questions that can be asked about molecular diversity is how many organic molecules are possible in total? To answer this question, my research group has computationally enumerated all possible organic molecules up to a certain size to gain an unbiased insight into the entire chemical space. Our latest database, GDB-17, contains 166.4 billion molecules of up to 17 atoms of C, N, O, S, and halogens, by far the largest small molecule database reported to date. Molecules allowed by valency rules but unstable or nonsynthesizable due to strained topologies or reactive functional groups were not considered, which reduced the enumeration by at least 10 orders of magnitude and was essential to arrive at a manageable database size. Despite these restrictions, GDB-17 is highly relevant with respect to known molecules. Beyond enumeration, understanding and exploiting GDBs (generated databases) led us to develop methods for virtual screening and visualization of very large databases in the form of a "periodic system of molecules" comprising six different fingerprint spaces, with web-browsers for nearest neighbor searches, and the MQN- and SMIfp-Mapplet application for exploring color-coded principal component maps of GDB and other large databases. Proof-of-concept applications of GDB for drug discovery were realized by combining virtual screening with chemical synthesis and activity testing for neurotransmitter receptor and transporter ligands. One surprising lesson from using GDB for drug analog searches is the incredible depth of chemical space, that is, the fact that millions of very close analogs of any molecule can be readily identified by nearest-neighbor searches in the MQN-space of the various GDBs. The chemical space project has opened an unprecedented door on chemical diversity. Ongoing and yet unmet challenges concern enumerating molecules beyond 17 atoms and synthesizing GDB molecules with innovative scaffolds and pharmacophores. PMID:25687211

  19. Chemical force microscopy

    NASA Astrophysics Data System (ADS)

    Noy, Aleksandr

    This thesis describes principles and applications of Chemical Force Microscopy (CFM)-a novel scanning probe microscopy technique that allows direct probing of intermolecular interactions and imaging with chemical sensitivity. Probe tips of an atomic force microscope were modified with self-assembled monolayers (SAMs) that terminated in a variety of terminal chemical functionalities. Use of these tips allowed to measure and quantify adhesion and friction forces between the functional groups on the tip and on the sample. Adhesion force studies between SAMs that terminate with hydrogen-bonding and hydrophobic functional groups have shown that CFM can reproducibly distinguish between different types of intermolecular interactions. The trends observed in these experiments follow chemical intuition and can be interpreted based on modern theory of contact mechanics. This theory also allowed to show that the contact area between the sharp (<50 nm) tips and the sample corresponds to an interaction between only 15-25 molecular pairs. CFM measurements used in the context of contact mechanics model can provide values of surface free energies for solid-liquid interfaces and solid-solid interfacial free energies. A new method-force titrations-has been developed to study surface ionization and determine local pK values. The interactions observed between tip and sample surfaces modified with ionizable functional groups in aqueous solutions also agree with predictions of double-layer and modified JKR models. CFM measurements have been used to extract double layer parameters that are essential to understanding interactions in aqueous media. CFM allowed to observe chemical specificity in friction forces. The magnitude of the friction forces follows the same trend as adhesion forces. The predictable dependence of the friction forces on the tip and sample functionality has been exploited for mapping surface domains of different functional groups with chemical sensitivity. It has been demonstrated that lateral force images can be rationally interpreted in terms of the strength of the interactions between functional groups on the probe and on the surface. It is also shown that CFM approach can be extended to imaging in tapping mode, which opens us possibilities for chemically-sensitive imaging of soft and delicate surfaces of polymers and biological objects. Chemical force microscopy has been also extended to a realm of complex interactions relevant to biophysics. Development of appropriate attachment chemistry enabled direct measurements of forces necessary to elastically stretch, structurally transform and break apart a single DNA duplex formed from short (14 base pair) synthetic oligonucleotides. Complementary and non-complementary sequences can be reproducibly distinguished on the basis of the differences in binding forces. Force microscopy and DNA synthesis can now be used to study the effect of specific DNA sequences on forces and the binding in the presence and absence of DNA binding proteins and molecules. These studies show that chemical force microscopy represents a practical and versatile approach to studying various aspects of intermolecular interactions and mapping surface functional groups on a nanometer scale.

  20. Chemical Debridement of Burns

    PubMed Central

    Levenson, Stanley M.; Kan, Dorinne; Gruber, Charles; Crowley, Leo V.; Lent, Richard; Watford, Alvin; Seifter, Eli

    1974-01-01

    The development of effective, non-toxic (local and systemic) methods for the rapid chemical (enzymatic and non-enzymatic) debridement of third degree burns would dramatically reduce the morbidity and mortality of severely burned patients. Sepsis is still the major cause of death of patients with extensive deep burns. The removal of the devitalized tissue, without damage to unburned skin or skin only partially injured by burning, and in ways which would permit immediate (or very prompt) skin grafting, would lessen substantially the problems of sepsis, speed convalescence and the return of these individuals to society as effective human beings, and would decrease deaths. The usefulness and limitations of surgical excision for patients with extensive third degree burns are discussed. Chemical debridement lends itself to complementary use with surgical excision and has the potential advantage over surgical excision in not requiring anesthesia or a formal surgical operation. The authors' work with the chemical debridement of burns, in particular the use of Bromelain, indicates that this approach will likely achieve clinical usefulness. The experimental studies indicate that rapid controlled debridement, with minimal local and systemic toxicity, is possible, and that effective chemotherapeutic agents may be combined with the Bromelain without either interfering with the actions of the other. The authors believe that rapid (hours) debridement accomplished by the combined use of chemical debriding and chemotherapeutic agents will obviate the possibility of any increase in infection, caused by the use of chemical agents for debridement, as reported for Paraenzyme21 and Travase.39,48 It is possible that the short term use of systemic antibiotics begun just before and continued during, and for a short time after, the rapid chemical debridement may prove useful for the prevention of infection, as appears to be the case for abdominal operations of the clean-contaminated and contaminated types. ImagesFigs. 1a-c.Fig. 1b.Fig. 1c.Fig. 2.Fig. 3.Fig. 4.Fig. 5.Fig. 6.Fig. 7.Fig. 8.Fig. 9a.Fig. 9B.Fig. 10.Fig. 11.Figs. 12a-c.Fig. 12b.Fig. 12c.Figs. 14a-c.Fig. 14b.Fig. 14c.Figs. 15a-c.Fig. 15b.Fig. 15c. PMID:4606330

  1. Chemical Modification of Polysaccharides

    PubMed Central

    Cumpstey, Ian

    2013-01-01

    This review covers methods for modifying the structures of polysaccharides. The introduction of hydrophobic, acidic, basic, or other functionality into polysaccharide structures can alter the properties of materials based on these substances. The development of chemical methods to achieve this aim is an ongoing area of research that is expected to become more important as the emphasis on using renewable starting materials and sustainable processes increases in the future. The methods covered in this review include ester and ether formation using saccharide oxygen nucleophiles, including enzymatic reactions and aspects of regioselectivity; the introduction of heteroatomic nucleophiles into polysaccharide chains; the oxidation of polysaccharides, including oxidative glycol cleavage, chemical oxidation of primary alcohols to carboxylic acids, and enzymatic oxidation of primary alcohols to aldehydes; reactions of uronic-acid-based polysaccharides; nucleophilic reactions of the amines of chitosan; and the formation of unsaturated polysaccharide derivatives. PMID:24151557

  2. Chemical Engineering in Space

    NASA Technical Reports Server (NTRS)

    Lobmeyer, Dennis A.; Meneghelli, Barry; Steinrock, Todd (Technical Monitor)

    2001-01-01

    The aerospace industry has long been perceived as the domain of both physicists and mechanical engineers. This perception has endured even though the primary method of providing the thrust necessary to launch a rocket into space is chemical in nature. The chemical engineering and chemistry personnel behind the systems that provide access to space have labored in the shadows of the physicists and mechanical engineers. As exploration into the cosmos moves farther away from Earth, there is a very distinct need for new chemical processes to help provide the means for advanced space exploration. The state of the art in launch systems uses chemical propulsion systems, primarily liquid hydrogen and liquid oxygen, to provide the energy necessary to achieve orbit. As we move away from Earth, there are additional options for propulsion. Unfortunately, few of these options can compare to the speed or ease of use provided by the chemical propulsion agents. It is with great care and significant cost that gaseous compounds such as hydrogen and oxygen are liquefied and become dense enough to use for rocket fuel. These low-temperature liquids fall within a specialty area known as cryogenics. Cryogenics, the science and art of producing cold operating conditions for use on Earth, in orbit, or on some other nonterrestrial body, has become increasingly important to our ability to travel within our solar system. The production of cryogenic fuels and the long-term storage of these fluids are necessary for travel. As our explorations move farther away from Earth, we need to address how to produce the necessary fuels to make a round-trip. The cost and the size of these expeditions are extreme at best. If we take everything necessary for our survival for the round-trip, we invalidate any chance of travel in the near future. As with the early explorers on Earth, we need to harvest much of our energy and our life support from the celestial bodies. The in situ production of these energy sources is paramount to success. We are currently working on several processes to produce the propellants that would allow us to visit and explore the surface of Mars. The capabilities currently at our disposal for launching and delivering equipment to another planet or satellite dictate that the size and scale of any hardware must be extremely small. The miniaturization of the processes needed to prepare the in situ propellants and life support commodities is a real challenge. Chemical engineers are faced with the prospect of reproducing an entire production facility in miniature so the complex can be lifted into space and delivered to our destination. Another area that does not normally concern chemical engineers is the extreme physical aspects payloads are subjected to with the launch of a spacecraft. Extreme accelerations followed by the sudden loss of nearly all gravitational forces are well outside normal equipment design conditions. If the equipment cannot survive the overall trip, then it obviously will not be able to yield the needed products upon arrival. These launch constraints must be taken into account. Finally, we must consider both the effectiveness and efficiencies of the processes. A facility located on the Moon or Mars will not have an unlimited supply of power or other ancillary utilities. For a Mars expedition, the available electric power is severely limited. The design of both the processes and the equipment must be considered. With these constraints in mind, only the most efficient designs will be viable. Cryogenics, in situ resource utilization, miniaturization, launchability, and power/process efficiencies are only a few of the areas that chemical engineers provide support and expertise for the exploration of space.

  3. Multiple chemical sensitivity syndrome.

    PubMed

    Magill, M K; Suruda, A

    1998-09-01

    Multiple chemical sensitivity (MCS) is a syndrome in which multiple symptoms reportedly occur with low-level chemical exposure. Several theories have been advanced to explain the cause of MCS, including allergy, toxic effects and neurobiologic sensitization. There is insufficient scientific evidence to confirm a relationship between any of these possible causes and symptoms. Patients with MCS have high rates of depression, anxiety and somatoform disorders, but it is unclear if a causal relationship or merely an association exists between MCS and psychiatric problems. Physicians should compassionately evaluate and care for patients who have this distressing condition, while avoiding the use of unproven, expensive or potentially harmful tests and treatments. The first goal of management is to establish an effective physician-patient relationship. The patient's efforts to return to work and to a normal social life should be encouraged and supported. PMID:9750540

  4. Chemical and UV Mutagenesis.

    PubMed

    Bose, Jeffrey L

    2016-01-01

    The ability to create mutations is an important step towards understanding bacterial physiology and virulence. While targeted approaches are invaluable, the ability to produce genome-wide random mutations can lead to crucial discoveries. Transposon mutagenesis is a useful approach, but many interesting mutations can be missed by these insertions that interrupt coding and noncoding sequences due to the integration of an entire transposon. Chemical mutagenesis and UV-based random mutagenesis are alternate approaches to isolate mutations of interest with the potential of only single nucleotide changes. Once a standard method, difficulty in identifying mutation sites had decreased the popularity of this technique. However, thanks to the recent emergence of economical whole-genome sequencing, this approach to making mutations can once again become a viable option. Therefore, this chapter provides an overview protocol for random mutagenesis using UV light or DNA-damaging chemicals. PMID:25646611

  5. Organic chemical evolution

    NASA Technical Reports Server (NTRS)

    Chang, S.

    1981-01-01

    The course of organic chemical evolution preceding the emergence of life on earth is discussed based on evidence of processes occurring in interstellar space, the solar system and the primitive earth. Following a brief review of the equilibrium condensation model for the origin and evolution of the solar system, consideration is given to the nature and organic chemistry of interstellar clouds, comets, Jupiter, meteorites, Venus and Mars, and the prebiotic earth. Major issues to be resolved in the study of organic chemical evolution on earth are identified regarding condensation and accretion in the solar nebula, early geological evolution, the origin and evolution of the atmosphere, organic production rates, organic-inorganic interactions, environmental fluctuations, phase separation and molecular selectivity.

  6. Biocatalysis for Biobased Chemicals

    PubMed Central

    de Regil, Rubén; Sandoval, Georgina

    2013-01-01

    The design and development of greener processes that are safe and friendly is an irreversible trend that is driven by sustainable and economic issues. The use of Biocatalysis as part of a manufacturing process fits well in this trend as enzymes are themselves biodegradable, require mild conditions to work and are highly specific and well suited to carry out complex reactions in a simple way. The growth of computational capabilities in the last decades has allowed Biocatalysis to develop sophisticated tools to understand better enzymatic phenomena and to have the power to control not only process conditions but also the enzyme’s own nature. Nowadays, Biocatalysis is behind some important products in the pharmaceutical, cosmetic, food and bulk chemicals industry. In this review we want to present some of the most representative examples of industrial chemicals produced in vitro through enzymatic catalysis. PMID:24970192

  7. Chemical Sensing with Nanowires

    NASA Astrophysics Data System (ADS)

    Penner, Reginald M.

    2012-07-01

    Transformational advances in the performance of nanowire-based chemical sensors and biosensors have been achieved over the past two to three years. These advances have arisen from a better understanding of the mechanisms of transduction operating in these devices, innovations in nanowire fabrication, and improved methods for incorporating receptors into or onto nanowires. Nanowire-based biosensors have detected DNA in undiluted physiological saline. For silicon nanowire nucleic acid sensors, higher sensitivities have been obtained by eliminating the passivating oxide layer on the nanowire surface and by substituting uncharged protein nucleic acids for DNA as the capture strands. Biosensors for peptide and protein cancer markers, based on both semiconductor nanowires and nanowires of conductive polymers, have detected these targets at physiologically relevant concentrations in both blood plasma and whole blood. Nanowire chemical sensors have also detected several gases at the parts-per-million level. This review discusses these and other recent advances, concentrating on work published in the past three years.

  8. Chemical bonding technology

    NASA Technical Reports Server (NTRS)

    Plueddemann, E.

    1986-01-01

    Primers employed in bonding together the various material interfaces in a photovoltaic module are being developed. The approach develops interfacial adhesion by generating actual chemical bonds between the various materials bonded together. The current status of the program is described along with the progress toward developing two general purpose primers for ethylene vinyl acetate (EVA), one for glass and metals, and another for plastic films.

  9. Chemical sensor system

    NASA Technical Reports Server (NTRS)

    Darrach, Murray R. (Inventor); Chutjian, Ara (Inventor)

    2008-01-01

    A chemical sensing apparatus and method for the detection of sub parts-per-trillion concentrations of molecules in a sample by optimizing electron utilization in the formation of negative ions is provided. A variety of media may be sampled including air, seawater, dry sediment, or undersea sediment. An electrostatic mirror is used to reduce the kinetic energy of an electron beam to zero or near-zero kinetic energy.

  10. Micromachined chemical jet dispenser

    SciTech Connect

    Swierkowski, S.; Ciarlo, D.

    1996-05-13

    Goal is to develop a multi-channel micromachined chemical fluid jet dispenser that is applicable to prototype tests with biological samples that demonstrate its utility for molecular biology experiments. Objective is to demonstrate a new device capable of ultrasonically ejecting droplets from 10-200 {mu}m diameter capillaries that are arranged in an array that is linear or focused. The device is based on several common fabrication procedures used in MEMS (micro electro mechanical systems) technology: piezoelectric actuators, silicon, etc.

  11. Chemical vapor deposition sciences

    SciTech Connect

    1992-12-31

    Chemical vapor deposition (CVD) is a widely used method for depositing thin films of a variety of materials. Applications of CVD range from the fabrication of microelectronic devices to the deposition of protective coatings. New CVD processes are increasingly complex, with stringent requirements that make it more difficult to commercialize them in a timely fashion. However, a clear understanding of the fundamental science underlying a CVD process, as expressed through computer models, can substantially shorten the time required for reactor and process development. Research scientists at Sandia use a wide range of experimental and theoretical techniques for investigating the science of CVD. Experimental tools include optical probes for gas-phase and surface processes, a range of surface analytic techniques, molecular beam methods for gas/surface kinetics, flow visualization techniques and state-of-the-art crystal growth reactors. The theoretical strategy uses a structured approach to describe the coupled gas-phase and gas-surface chemistry, fluid dynamics, heat and mass transfer of a CVD process. The software used to describe chemical reaction mechanisms is easily adapted to codes that model a variety of reactor geometries. Carefully chosen experiments provide critical information on the chemical species, gas temperatures and flows that are necessary for model development and validation. This brochure provides basic information on Sandia`s capabilities in the physical and chemical sciences of CVD and related materials processing technologies. It contains a brief description of the major scientific and technical capabilities of the CVD staff and facilities, and a brief discussion of the approach that the staff uses to advance the scientific understanding of CVD processes.

  12. The Use of Chemical-Chemical Interaction and Chemical Structure to Identify New Candidate Chemicals Related to Lung Cancer

    PubMed Central

    Zheng, Mingyue; Kong, Xiangyin; Huang, Tao; Cai, Yu-Dong

    2015-01-01

    Lung cancer causes over one million deaths every year worldwide. However, prevention and treatment methods for this serious disease are limited. The identification of new chemicals related to lung cancer may aid in disease prevention and the design of more effective treatments. This study employed a weighted network, constructed using chemical-chemical interaction information, to identify new chemicals related to two types of lung cancer: non-small lung cancer and small-cell lung cancer. Then, a randomization test as well as chemical-chemical interaction and chemical structure information were utilized to make further selections. A final analysis of these new chemicals in the context of the current literature indicates that several chemicals are strongly linked to lung cancer. PMID:26047514

  13. Metabolomics in chemical ecology.

    PubMed

    Kuhlisch, Constanze; Pohnert, Georg

    2015-07-01

    Chemical ecology elucidates the nature and role of natural products as mediators of organismal interactions. The emerging techniques that can be summarized under the concept of metabolomics provide new opportunities to study such environmentally relevant signaling molecules. Especially comparative tools in metabolomics enable the identification of compounds that are regulated during interaction situations and that might play a role as e.g. pheromones, allelochemicals or in induced and activated defenses. This approach helps overcoming limitations of traditional bioassay-guided structure elucidation approaches. But the power of metabolomics is not limited to the comparison of metabolic profiles of interacting partners. Especially the link to other -omics techniques helps to unravel not only the compounds in question but the entire biosynthetic and genetic re-wiring, required for an ecological response. This review comprehensively highlights successful applications of metabolomics in chemical ecology and discusses existing limitations of these novel techniques. It focuses on recent developments in comparative metabolomics and discusses the use of metabolomics in the systems biology of organismal interactions. It also outlines the potential of large metabolomics initiatives for model organisms in the field of chemical ecology. PMID:25926134

  14. Chemical and Thermal Analysis

    NASA Technical Reports Server (NTRS)

    Bulluck, J. W.; Rushing, R. A.

    1994-01-01

    Thermal decomposition activation energies have been determined using two methods of Thermogravimetric Analysis (TGA), with good correlation being obtained between the two techniques. Initial heating curves indicated a two-component system for Coflon (i.e. polymer plus placticizer) but a single component system for Tefzel. Two widely differing activation energies were for Coflon supported this view, 15 kcl/mol being associated with plasticizer, and 40 kcal/mol with polymer degradation. With Tefzel, values were 40-45 kcal/mol, the former perhaps being associated with a low molecular weight fraction. Appropriate acceleration factors have been determined. Thermomechanical Analysis (TMA) has shown considerable dimensional change during temperature cycles. For unaged pipe sections heating to 100 C and then holding the temperature resulted in a stable thickness increase of 2%, whereas the Coflon thickness decreased continuously, reaching -4% in 2.7 weeks. Previously strained tensile bars of Tefzel expanded on cooling during TMA. SEM performed on H2S-aged Coflon samples showed significant changes in both physical and chemical nature. The first may have resulted from explosive decompression after part of the aging process. Chemically extensive dehydrofluorination was indicated, and sulfur was present as a result of the aging. These observations indicate that chemical attack of PVDF can occur in some circumstances.

  15. Chemical Reactions at Surfaces

    SciTech Connect

    Michael Henderson and Nancy Ryan Gray

    2010-04-14

    Chemical reactions at surfaces underlie some of the most important processes of today, including catalysis, energy conversion, microelectronics, human health and the environment. Understanding surface chemical reactions at a fundamental level is at the core of the field of surface science. The Gordon Research Conference on Chemical Reactions at Surfaces is one of the premiere meetings in the field. The program this year will cover a broad range of topics, including heterogeneous catalysis and surface chemistry, surfaces in environmental chemistry and energy conversion, reactions at the liquid-solid and liquid-gas interface, electronic materials growth and surface modification, biological interfaces, and electrons and photons at surfaces. An exciting program is planned, with contributions from outstanding speakers and discussion leaders from the international scientific community. The conference provides a dynamic environment with ample time for discussion and interaction. Attendees are encouraged to present posters; the poster sessions are historically well attended and stimulate additional discussions. The conference provides an excellent opportunity for junior researchers (e.g. graduate students or postdocs) to present their work and interact with established leaders in the field.

  16. Chemical and Thermal Analysis

    NASA Technical Reports Server (NTRS)

    Bulluck, J. W.; Rushing, R. A.

    1997-01-01

    Work during the past three years has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-Ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted changes in the molecular weight distribution and the increased crosslinking of the Coflon material using Gel Permeation Chromatographic Analysis. Again these changes may result in variations in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, and Differential Scanning Calorimetry. We investigated a plethora of aged samples of both Tefzel and Coflon that were forwarded from MERL. Pressurized tests were performed on powdered PVDF in a modified Fluid A, which we will call A-2. In this case the ethylene diamine concentration was increased to 3 percent in methanol. Coflon pipe sections and powdered Coflon were exposed in pressure cells at 1700 psi at three separate test temperatures.

  17. Chemical and Thermal Analysis

    NASA Technical Reports Server (NTRS)

    Bulluck, J. W.; Rushing, R. A.; Thornton, C. P.

    1996-01-01

    Work has included significant research in several areas aimed at further clarification of the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. Among the areas investigated were the crystallinity changes associated with both the Coflon and Tefzel after various simulated environmental exposures using X-Ray diffraction analysis. We have found that significant changes in polymer crystallinity levels occur as a function of the exposures. These crystallinity changes may have important consequences on the fracture, fatigue, tensile, and chemical resistance of the materials. We have also noted changes in the molecular weight distribution of the Coflon material using a dual detector Gel Permeation Analysis. Again these changes may result in variation in the mechanical and chemical properties in the material. We conducted numerous analytical studies with methods including X-Ray Diffraction, Gel Permeation Chromatography, Fourier Transform Infrared Spectroscopy, Thermogravimetric Analysis, and Differential Scanning Calorimetry. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. Pressurized tests were performed in a modified Fluid G, which we will call G2. In this case the ethylene diamine concentration was increased to 3 percent in methanol. Coflon pipe sections and powdered Coflon were exposed in pressure cells at 1700 psi at three separate test temperatures, 70 C, 110 C, and 130 C. The primary purpose of the pressure tests in Fluid G2 was to further elucidate the aging mechanism of PVDF degradation.

  18. Miniature Chemical Sensor

    SciTech Connect

    Andrew C. R. Pipino

    2004-12-13

    A new chemical detection technology has been realized that addresses DOE environmental management needs. The new technology is based on a variant of the sensitive optical absorption technique, cavity ring-down spectroscopy (CRDS). Termed evanescent-wave cavity ring-down spectroscopy (EW-CRDS), the technology employs a miniature solid-state optical resonator having an extremely high Q-factor as the sensing element, where the high-Q is achieved by using ultra-low-attenuation optical materials, ultra-smooth surfaces, and ultra-high reflectivity coatings, as well as low-diffraction-loss designs. At least one total-internal reflection (TIR) mirror is integral to the resonator permitting the concomitant evanescent wave to probe the ambient environment. Several prototypes have been designed, fabricated, characterized, and applied to chemical detection. Moreover, extensions of the sensing concept have been explored to enhance selectivity, sensitivity, and range of application. Operating primarily in the visible and near IR regions, the technology inherently enables remote detection by optical fiber. Producing 11 archival publications, 5 patents, 19 invited talks, 4 conference proceedings, a CRADA, and a patent-license agreement, the project has realized a new chemical detection technology providing >100 times more sensitivity than comparable technologies, while also providing practical advantages.

  19. Ionization structure and chemical abundances of the Wolf-Rayet nebula NGC 6888 with integral field spectroscopy

    NASA Astrophysics Data System (ADS)

    Fernndez-Martn, A.; Martn-Gordn, D.; Vlchez, J. M.; Prez Montero, E.; Riera, A.; Snchez, S. F.

    2012-05-01

    Context. The study of nebulae around Wolf-Rayet (WR) stars gives us clues about the mass-loss history of massive stars, as well as about the chemical enrichment of the interstellar medium (ISM). Aims: This work aims to search for the observational footprints of the interactions between the ISM and stellar winds in the WR nebula NGC 6888 in order to understand its ionization structure, chemical composition, and kinematics. Methods: We have collected a set of integral field spectroscopy observations across NGC 6888, obtained with PPAK in the optical range performing both 2D and 1D analyses. Attending to the 2D analysis in the northeast part of NGC 6888, we have generated maps of the extinction structure and electron density. We produced statistical frequency distributions of the radial velocity and diagnostic diagrams. Furthermore, we performed a thorough study of integrated spectra in nine regions over the whole nebula. Results: The 2D study has revealed two main behaviours. We have found that the spectra of a localized region to the southwest of this pointing can be represented well by shock models assuming n = 1000 cm-3, twice solar abundances, and shock velocities from 250 to 400 km s-1. With the 1D analysis we derived electron densities ranging from <100 to 360 cm-3. The electron temperature varies from ~7700 K to ~10 200 K. A strong variation of up to a factor 10 between different regions in the nitrogen abundance has been found: N/H appears lower than the solar abundance in those positions observed at the edges and very enhanced in the observed inner parts. Oxygen appears slightly underabundant with respect to solar value, whereas the helium abundance is found to be above it. We propose a scenario for the evolution of NGC 6888 to explain the features observed. This scheme consists of a structure of multiple shells: i) an inner and broken shell with material from the interaction between the supergiant and WR shells, presenting an overabundance in N/H and a slight underabundance in O/H; ii) an outer shell very intense in [OIII]?5007 corresponding to the main sequence bubble broken up as a consequence of the collision between supergiant and WR shells. Nitrogen and oxygen do not appear enhanced here, but helium appears enriched; iii) and finally it includes an external and faint shell that surrounds the whole nebula like a thin skin representing the early interaction between the winds from the main sequence star with the ISM for which typical circumstellar abundances are derived. Based on observations collected at the Centro Astronmico Hispano Alemn (CAHA) at Calar Alto, operated jointly by the Max-Planck-Institut fr Astronomie and the Instituto de Astrofsica de Andaluca (CSIC).Table 3 is available in electronic form at http://www.aanda.org

  20. Chemical emergency preparedness program: chemical profiles. Interim guidance

    SciTech Connect

    Not Available

    1985-12-01

    The document, developed by the U.S. Environmental Protection Agency (USEPA) is part of the USEPA National Air Toxics Strategy. The document is provided in support of EPA Chemical Emergency Preparedness Program (CEPP) which deals with accidental release of acutely toxic chemicals. For each acutely toxic chemical listed in the CEPP guidance document (report number PB86-155256), a chemical profile is available. A chemical profile is a collection of information on the chemical identity hazardous identity, physical/chemical characteristics, fire and explosive hazard, reactivity, health hazard, use, and precautions for handling and use of the chemical. The information is presented in the format that conforms as closely as possible to the Occupational Safety and Health Administration (OSHA) recommended format for a Material Safety Data Sheet (MSDS).

  1. Chemical Demonstrations with Consumer Chemicals: The Black and White Reaction.

    ERIC Educational Resources Information Center

    Wright, Stephen W.

    2002-01-01

    Describes a dramatic chemical demonstration in which chemicals that are black and white combine to produce a colorless liquid. Reactants include tincture of iodine, bleach, white vinegar, Epsom salt, vitamin C tablets, and liquid laundry starch. (DDR)

  2. CHEMICALS IN THE ENVIRONMENT: OPPT CHEMICAL FACT SHEETS

    EPA Science Inventory

    The OPPT Chemical Fact Sheets are produced by the Office of Pollution, Prevention and Toxics to provide a brief summary of information on selected chemicals. The Fact Sheets cover each chemicals identity, production and use, environmental fate, and health and environmental effect...

  3. The awesome power of synergy from chemical-chemical profiling.

    PubMed

    Piotrowski, Jeff S; Ho, Chuek Hei; Boone, Charles

    2010-08-27

    Chemical-chemical profiling, as described in Farha and Brown (2010), delivers all the power of chemical-genomic profiling while untethering researchers from model systems and thereby enabling us to pursue cell-based drug target identification in almost any organism. PMID:20797605

  4. Ground water chemicals desk reference

    SciTech Connect

    Montgomery, J.J.; Welkom, L.M. )

    1989-01-01

    This new book covers the 137 organic compounds most commonly found in ground water and the unsaturated zone. The authors assess the fate and transport of ground water chemicals. The physical and chemical properties of the compound are described.

  5. Chemical Processing. Resources in Technology.

    ERIC Educational Resources Information Center

    Technology Teacher, 1991

    1991-01-01

    Reviews major organic and inorganic chemicals, their products, and the sociocultural impact of the chemical industry. Provides the following learning activity components: objectives, list of materials and equipment, procedures, student quiz with answers, and three references. (SK)

  6. Devices for collecting chemical compounds

    SciTech Connect

    Scott, Jill R; Groenewold, Gary S

    2013-12-24

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  7. CHEMICAL STORAGE: MYTHS VERSUS REALITY

    SciTech Connect

    Simmons, F

    2007-03-19

    A large number of resources explaining proper chemical storage are available. These resources include books, databases/tables, and articles that explain various aspects of chemical storage including compatible chemical storage, signage, and regulatory requirements. Another source is the chemical manufacturer or distributor who provides storage information in the form of icons or color coding schemes on container labels. Despite the availability of these resources, chemical accidents stemming from improper storage, according to recent reports (1) (2), make up almost 25% of all chemical accidents. This relatively high percentage of chemical storage accidents suggests that these publications and color coding schemes although helpful, still provide incomplete information that may not completely mitigate storage risks. This manuscript will explore some ways published storage information may be incomplete, examine the associated risks, and suggest methods to help further eliminate chemical storage risks.

  8. Explosive chemical emissions from landmines

    NASA Astrophysics Data System (ADS)

    Phelan, James M.; Barnett, James L.; Romero, Joseph V.; Kerr, Dayle R.; Griffin, Fawn A.

    2003-09-01

    Chemical sensing for buried landmines is a complex phenomenon that includes mine chemical emissions, soil chemical transport/degradation, and detection at the ground surface. The technology to assess soil chemical transport has evolved and now provides a complex systems analysis capability using high fidelity computational simulation tools. Data requirements to evaluate a chemical sensing scenario include soil chemodynamic properties, micrometeorological conditions, and mine chemical emissions. Mine chemical emission tests were performed on four antipersonnel landmines using whole landmines in soil flux chambers. Soil flux chambers are simple containers that surround landmines with dry soil that act as an adsorbent. After a certain soak time, residue analysis of the soil provides the total chemical emission - a combination of both permeation and leakage. An evaluation of permeation differences into wet soil versus dry soil was also completed using thin polymer coupon sections.

  9. Chemical Educators Stress Industry Ties

    ERIC Educational Resources Information Center

    Worthy, Ward

    1975-01-01

    Describes various courses and programs designed to better prepare graduates to enter the chemical industry, including courses which stress the chemistry of industrial processes, and the economics of the chemical industry. (MLH)

  10. Control in the Chemical Industry

    ERIC Educational Resources Information Center

    Jones, R. G.

    1974-01-01

    Discusses various control techniques used in chemical processes, including measuring devices, controller functions, control valves, and feedforward and feedback actions. Applications of control to a real chemical plant are exemplified. (CC)

  11. Chemically rechargeable battery

    NASA Technical Reports Server (NTRS)

    Graf, James E. (Inventor); Rowlette, John J. (Inventor)

    1984-01-01

    Batteries (50) containing oxidized, discharged metal electrodes such as an iron-air battery are charged by removing and storing electrolyte in a reservoir (98), pumping fluid reductant such as formalin (aqueous formaldehyde) from a storage tank (106) into the battery in contact with the surfaces of the electrodes. After sufficient iron hydroxide has been reduced to iron, the spent reductant is drained, the electrodes rinsed with water from rinse tank (102) and then the electrolyte in the reservoir (106) is returned to the battery. The battery can be slowly electrically charged when in overnight storage but can be quickly charged in about 10 minutes by the chemical procedure of the invention.

  12. Chemical Microthruster Options

    NASA Technical Reports Server (NTRS)

    DeGroot, Wim; Oleson, Steve

    1996-01-01

    Chemical propulsion systems with potential application to microsatellites are classified by propellant phase, i.e. gas, liquid, or solid. Four promising concepts are selected based on performance, weight, size, cost, and reliability. The selected concepts, in varying stages of development, are advanced monopropellants, tridyne(TM), electrolysis, and solid gas generator propulsion. Tridyne(TM) and electrolysis propulsion are compared vs. existing cold gas and monopropellant systems for selected microsatellite missions. Electrolysis is shown to provide a significant weight advantage over monopropellant propulsion for an orbit transfer and plane change mission. Tridyne(TM) is shown to provide a significant advantage over cold gas thrusters for orbit trimming and spacecraft separation.

  13. Lasers in chemical processing

    SciTech Connect

    Davis, J.I.

    1982-04-15

    The high cost of laser energy is the crucial issue in any potential laser-processing application. It is expensive relative to other forms of energy and to most bulk chemicals. We show those factors that have previously frustrated attempts to find commercially viable laser-induced processes for the production of materials. Having identified the general criteria to be satisfied by an economically successful laser process and shown how these imply the laser-system requirements, we present a status report on the uranium laser isotope separation (LIS) program at the Lawrence Livermore National Laboratory (LLNL).

  14. Chemical and Biological Kinetics

    NASA Astrophysics Data System (ADS)

    Emanuel', N. M.

    1981-10-01

    Examples of the application of the methods and ideas of chemical kinetics in various branches of chemistry and biology are considered and the results of studies on the kinetics and mechanisms of autoxidation and inhibited and catalysed oxidation of organic substances in the liquid phase are surveyed. Problems of the kinetics of the ageing of polymers and the principles of their stabilisation are discussed and certain trends in biological kinetics (kinetics of tumour growth, kinetic criteria of the effectiveness of chemotherapy, problems of gerontology, etc.) are considered. The bibliography includes 281 references.

  15. Chemical sensing flow probe

    DOEpatents

    Laguna, G.R.; Peter, F.J.; Butler, M.A.

    1999-02-16

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir. 7 figs.

  16. Chemical sensing flow probe

    DOEpatents

    Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

    1999-01-01

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

  17. Chemical sensor system

    DOEpatents

    Darrow, Christopher B. (Pleasanton, CA); Satcher, Jr., Joe H. (Modesto, CA); Lane, Stephen M. (Oakland, CA); Lee, Abraham P. (Walnut Creek, CA); Wang, Amy W. (Berkeley, CA)

    2002-01-01

    An implantable chemical sensor system for medical applications is described which permits selective recognition of an analyte using an expandable biocompatible sensor, such as a polymer, that undergoes a dimensional change in the presence of the analyte. The expandable polymer is incorporated into an electronic circuit component that changes its properties (e.g., frequency) when the polymer changes dimension. As the circuit changes its characteristics, an external interrogator transmits a signal transdermally to the transducer, and the concentration of the analyte is determined from the measured changes in the circuit. This invention may be used for minimally invasive monitoring of blood glucose levels in diabetic patients.

  18. Chemical kinetics modeling

    SciTech Connect

    Westbrook, C.K.; Pitz, W.J.

    1993-12-01

    This project emphasizes numerical modeling of chemical kinetics of combustion, including applications in both practical combustion systems and in controlled laboratory experiments. Elementary reaction rate parameters are combined into mechanisms which then describe the overall reaction of the fuels being studied. Detailed sensitivity analyses are used to identify those reaction rates and product species distributions to which the results are most sensitive and therefore warrant the greatest attention from other experimental and theoretical research programs. Experimental data from a variety of environments are combined together to validate the reaction mechanisms, including results from laminar flames, shock tubes, flow systems, detonations, and even internal combustion engines.

  19. LLNL Chemical Kinetics Modeling Group

    SciTech Connect

    Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

    2008-09-24

    The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

  20. Green chemistry for chemical synthesis.

    PubMed

    Li, Chao-Jun; Trost, Barry M

    2008-09-01

    Green chemistry for chemical synthesis addresses our future challenges in working with chemical processes and products by inventing novel reactions that can maximize the desired products and minimize by-products, designing new synthetic schemes and apparati that can simplify operations in chemical productions, and seeking greener solvents that are inherently environmentally and ecologically benign. PMID:18768813

  1. Modern Chemical Technology, Volume 8.

    ERIC Educational Resources Information Center

    Pecsok, Robert L.; Chapman, Kenneth

    This volume is one of a series for the Chemical Technician Curriculum Project (ChemTeC) of the American Chemical Society funded by the National Science Foundation. It consists of discussions, exercises, and experiments on the following topics: amino acids and proteins, carbohydrates, synthetic polymers, other natural products, chemical separations…

  2. Pocket Calculators in Chemical Education.

    ERIC Educational Resources Information Center

    Holdsworth, D. K.

    1980-01-01

    Reviews ways in which programable pocket calculators are used in chemical education. Discussed are simulations of chemical experiments, performance of repetitive calculations, processing chemical data directly from instruments, testing hypotheses, and monitoring class practical results. Lists some calculators and their features and some useful

  3. Modern Chemical Technology, Volume 6.

    ERIC Educational Resources Information Center

    Pecsok, Robert L., Ed.; Chapman, Kenneth, Ed.

    This volume contains chapters 32-39 for the American Chemical Society (ACS) "Modern Chemical Technology" (ChemTeC) instructional materials intended to prepare chemical technologists. The study of organic chemistry is continued as these major topics are considered: alcohols and phenols, alkyl and aryl halides, ethers, aldehydes and ketones,…

  4. Chemical Waste Management and Disposal.

    ERIC Educational Resources Information Center

    Armour, Margaret-Ann

    1988-01-01

    Describes simple, efficient techniques for treating hazardous chemicals so that nontoxic and nonhazardous residues are formed. Discusses general rules for management of waste chemicals from school laboratories and general techniques for the disposal of waste or surplus chemicals. Lists specific disposal reactions. (CW)

  5. Green chemistry for chemical synthesis

    PubMed Central

    Li, Chao-Jun; Trost, Barry M.

    2008-01-01

    Green chemistry for chemical synthesis addresses our future challenges in working with chemical processes and products by inventing novel reactions that can maximize the desired products and minimize by-products, designing new synthetic schemes and apparati that can simplify operations in chemical productions, and seeking greener solvents that are inherently environmentally and ecologically benign. PMID:18768813

  6. The chemical ecology of cyanobacteria

    PubMed Central

    Leão, Pedro N.; Engene, Niclas; Antunes, Agostinho; Gerwick, William H.; Vasconcelos, Vitor

    2014-01-01

    This review covers the literature on the chemically mediated ecology of cyanobacteria, including ultraviolet radiation protection, feeding-deterrence, allelopathy, resource competition, and signalling. To highlight the chemical and biological diversity of this group of organisms, evolutionary and chemotaxonomical studies are presented. Several technologically relevant aspects of cyanobacterial chemical ecology are also discussed. PMID:22237837

  7. Mass Transfer with Chemical Reaction.

    ERIC Educational Resources Information Center

    DeCoursey, W. J.

    1987-01-01

    Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)

  8. Modern Chemical Technology, Volume 8.

    ERIC Educational Resources Information Center

    Pecsok, Robert L.; Chapman, Kenneth

    This volume is one of a series for the Chemical Technician Curriculum Project (ChemTeC) of the American Chemical Society funded by the National Science Foundation. It consists of discussions, exercises, and experiments on the following topics: amino acids and proteins, carbohydrates, synthetic polymers, other natural products, chemical separations

  9. Modern Chemical Technology, Volume 6.

    ERIC Educational Resources Information Center

    Pecsok, Robert L., Ed.; Chapman, Kenneth, Ed.

    This volume contains chapters 32-39 for the American Chemical Society (ACS) "Modern Chemical Technology" (ChemTeC) instructional materials intended to prepare chemical technologists. The study of organic chemistry is continued as these major topics are considered: alcohols and phenols, alkyl and aryl halides, ethers, aldehydes and ketones,

  10. Modern Chemical Technology, Volume 5.

    ERIC Educational Resources Information Center

    Pecsok, Robert L., Ed.; Chapman, Kenneth, Ed.

    This volume contains chapters 26-31 for the American Chemical Society (ACS) "Modern Chemical Technology" (ChemTeC) instructional material intended to prepare chemical technologists. Chapter 26 reviews oxidation and reduction, including applications in titrations with potassium permanganate and iodometry. Coordination compounds are described in the

  11. Modern Chemical Technology, Volume 5.

    ERIC Educational Resources Information Center

    Pecsok, Robert L., Ed.; Chapman, Kenneth, Ed.

    This volume contains chapters 26-31 for the American Chemical Society (ACS) "Modern Chemical Technology" (ChemTeC) instructional material intended to prepare chemical technologists. Chapter 26 reviews oxidation and reduction, including applications in titrations with potassium permanganate and iodometry. Coordination compounds are described in the…

  12. Modern Chemical Technology, Volume 2.

    ERIC Educational Resources Information Center

    Pecsok, Robert L.; Chapman, Kenneth

    This volume contains chapters 8 to 13 of the ACS "Modern Chemical Technology" (ChemTeC) curriculum material which is intended to prepare chemical technologists. The content is centered around the background needed to understand the structure of the atom, covalence, electrovalence, elements and compounds, liquids and solutions, and chemical

  13. Aqueous chemical wash compositions

    SciTech Connect

    Bannister, C.E.

    1987-07-21

    This patent describes an aqueous, substantially unfoamed chemical wash composition having properties making it suitable for use as a pre-flush in well cementing operations and/or for removal of drilling mud from a borehole at a temperature of from about 150/sup 0/F to about 270/sup 0/F, the wash a. being predominantly composed of water, b. containing an active surfactant component comprising a combination of (1) from about 0.1 to about 1.5 weight percent (total weight basis) of a water soluble anionic surfactant; (2) from about 0.1 to about 1.5 weight percent (total weight basis) of a nonionic surfactant; and (3) from about 0.05 to about 0.54 weight percent (total weight basis) of at least one water soluble amphoteric surfactant, and c. having dispersed therein a heterogeneous mixture of distinct particles comprising both a first particulate oil soluble resin which is friable and a second particulate oil soluble resin which is pliable and where the size of the friable resin particles ranges from about 0.5 to about 300 microns and the size of the pliable resin particles ranges from about 0.05 to about 30 microns. The amount of the friable-pliable resin mixture is sufficient to impart effective fluid loss control to the chemical wash composition.

  14. Selective chemical stripping

    NASA Astrophysics Data System (ADS)

    Malavallon, Olivier

    1995-04-01

    At the end of the 80's, some of the large European airlines expressed a wish for paint systems with improved strippability on their aircraft, allowing the possibility to strip down to the primer without altering it, using 'mild' chemical strippers based on methylene chloride. These improvements were initially intended to reduce costs and stripping cycle times while facilitating rapid repainting, and this without the need to change the conventionally used industrial facilities. The level of in-service performance of these paint systems was to be the same as the previous ones. Requirements related to hygiene safety and the environment were added to these initial requirements. To meet customers' expectations, Aerospatiale, within the Airbus Industry GIE, formed a work group. This group was given the task of specifying, following up the elaboration and qualifying the paint systems allowing requirements to be met, in relation with the paint suppliers and the airlines. The analysis made in this report showed the interest of transferring as far upstream as possible (to paint conception level) most of the technical constraints related to stripping. Thus, the concept retained for the paint system, allowing selective chemical stripping, is a 3-coat system with characteristics as near as possible to the previously used paints.

  15. [Chemical food contaminants].

    PubMed

    Schrenk, D

    2004-09-01

    Chemical food contaminants are substances which are neither present naturally in the usual raw material used for food production nor are added during the regular production process. Examples are environmental pollutants or contaminants derived from agricultural production of crops or livestock or from inadequate manufacturing of the food product itself. More difficult is the classification of those compounds formed during regular manufacturing such as products of thermal processes including flavoring substances. In these cases, it is common practice to call those compounds contaminants which are known for their adverse effects such as acrylamide, whereas constituents which add to the food-specific flavor such as Maillard products formed during roasting, baking etc. are not termed contaminants. From a toxicological viewpoint this distinction is not always clear-cut. Important groups of chemical contaminants are metals such as mercury or lead, persistent organic pollutants such as polychlorinated biphenyls and related pollutants, which are regularly found in certain types of food originating from background levels of these compounds in our environment. Furthermore, natural toxins form microorganisms or plants, and compounds formed during thermal treatment of food are of major interest. In general, a scientific risk assessment has to be carried out for any known contaminant. This comprises an exposure analysis and a toxicological and epidemiological assessment. On these grounds, regulatory and/or technological measures can often improve the situation. Major conditions for a scientific risk assessment and a successful implementation of regulations are highly developed food quality control, food toxicology and nutritional epidemiology. PMID:15378171

  16. Chemical Looping Combustion Kinetics

    SciTech Connect

    Edward Eyring; Gabor Konya

    2009-03-31

    One of the most promising methods of capturing CO{sub 2} emitted by coal-fired power plants for subsequent sequestration is chemical looping combustion (CLC). A powdered metal oxide such as NiO transfers oxygen directly to a fuel in a fuel reactor at high temperatures with no air present. Heat, water, and CO{sub 2} are released, and after H{sub 2}O condensation the CO{sub 2} (undiluted by N{sub 2}) is ready for sequestration, whereas the nickel metal is ready for reoxidation in the air reactor. In principle, these processes can be repeated endlessly with the original nickel metal/nickel oxide participating in a loop that admits fuel and rejects ash, heat, and water. Our project accumulated kinetic rate data at high temperatures and elevated pressures for the metal oxide reduction step and for the metal reoxidation step. These data will be used in computational modeling of CLC on the laboratory scale and presumably later on the plant scale. The oxygen carrier on which the research at Utah is focused is CuO/Cu{sub 2}O rather than nickel oxide because the copper system lends itself to use with solid fuels in an alternative to CLC called 'chemical looping with oxygen uncoupling' (CLOU).

  17. Chemical heat pump

    DOEpatents

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1981-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  18. Chemical heat pump

    DOEpatents

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate intallation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  19. Chemical heat pump

    DOEpatents

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to faciliate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  20. Chemical heat pump

    DOEpatents

    Greiner, Leonard (2853-A Hickory Pl., Costa Mesa, CA 92626)

    1984-01-01

    A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

  1. a Submillimeter Chemical Sensor

    NASA Astrophysics Data System (ADS)

    Neese, Christopher F.; Medvedev, Ivan R.; De Lucia, Frank C.; Plummer, Grant M.; Ball, Christopher D.; Frank, Aaron J.

    2010-06-01

    Rotational spectroscopy has been recognized a potentially powerful tool for chemical analysis since the very beginnings of the field. A typical rotational fingerprint consists of 10^5 resolvable spectral channels, leading to `absolute' specificity, even in complex mixtures. Furthermore, rotational spectroscopy requires very small amounts of sample with detection limits as low as picograms. Nevertheless, this technique has not yet been widely applied to analytical science because of the size, cost, and complexity of traditional spectrometers. A resurgence of interest in spectroscopic sensors has been fueled by increases in performance made possible by advances in laser systems and applications in medicine, environmental monitoring, and national security. Most of these new approaches make use of the optical/infrared spectral regions and their well established, but still rapidly evolving technology base. The submillimeter (SMM) spectral region, while much less well known, has also seen significant technological advances, allowing the design of powerful spectroscopic sensors. Using modern solid-state multiplier technology we have built a small bench top SMM spectrometer designed for use as a chemical sensor. This spectrometer includes a sample acquisition system including the vacuum equipment to provide the ideal pressures (1--10 mtorr) for SMM spectroscopy and a sorbent tube for analyte collection and preconcentration. The entire spectrometer, including power supplies, frequency synthesizers, a 1.2 m folded sample cell, and a computer for data analysis fits into a cubic foot box.

  2. Chemical synthetic biology.

    PubMed

    Chiarabelli, Cristiano; Luisi, Pier Luigi

    2014-01-01

    Although both the most popular form of synthetic biology (SB) and chemical synthetic biology (CSB) share the biotechnologically useful aim of making new forms of life, SB does so by using genetic manipulation of extant microorganism, while CSB utilises classic chemical procedures in order to obtain biological structures which are non-existent in nature. The main query concerning CSB is the philosophical question: why did nature do this, and not that? The idea then is to synthesise alternative structures in order to understand why nature operated in such a particular way. We briefly present here some various examples of CSB, including those cases of nucleic acids synthesised with pyranose instead of ribose, and proteins with a reduced alphabet of amino acids; also we report the developing research on the "never born proteins" (NBP) and "never born RNA" (NBRNA), up to the minimal cell project, where the issue is the preparation of semi-synthetic cells that can perform the basic functions of biological cells. PMID:24800469

  3. Chemical Reactions in DSMC

    SciTech Connect

    Bird, G. A.

    2011-05-20

    DSMC simulations of chemically reacting gas flows have generally employed procedures that convert the macroscopic chemical rate equations to reaction cross-sections at the microscopic level. They therefore depend on the availability of experimental data that has been fitted to equations of the Arrhenius form. This paper presents a physical model for dissociation and recombination reactions and a phenomenological model for exchange and chain reactions. These are based on the vibrational states of the colliding molecules and do not require any experimentally-based data. The simplicity of the models allows the corresponding rate equations to be written down and, while these are not required for the implementation of the models, they facilitate their validation. The model is applied to a typical hypersonic atmospheric entry problem and the results are compared with the corresponding results from the traditional method. It is also used to investigate both spontaneous and forced ignition as well as the structure of a deflagration wave in an oxygen-hydrogen mixture.

  4. The Chemical Potential

    NASA Astrophysics Data System (ADS)

    Kaplan, Thomas

    2005-03-01

    The definition of the fundamental quantity, the chemical potential (c.p.), is confused in the literature, there being at least three distinct definitions in various books and papers. Major differences among them can occur for finite systems. We resolve the situation by arguing that the chemical potential defined by the symbol μ conventionally appearing in the grand canonical density operator is the uniquely correct definition, the grand canonical ensemble being the only one of the various ensembles usually discussed (microcanonical, canonical, Gibbs, grand canonical) that is appropriate for statistical thermodynamics, whenever the c.p. is physically relevant. The derivation of the zero-temperature limit of this μ for rather general interacting-electron systems by Perdew et. al.,[1] is discussed and extended. The enormous finite-size corrections (in systems >> a cm^3) for one rather common definition of the c.p., found by Shegelski [2] within the standard effective mass model of an ideal intrinsic semiconductor, are discussed. The quantum dot is mentioned as a small-system application. 1. J. F. Perdew et. al., Phys. Rev. Lett. 23, 1691 (1982); J. F. Perdew, in Density-functional methods in Physics, edited by R. M. Dreizler and J. da Providencia, Plenum Press, 1985. 2. M. R. A. Shegelski, Solid State Commun. 38, 351 (1986); Am. J. Phys. 72, 676 (2004).

  5. Adapting Chemical Mixture Risk Assessment Methods to Assess Chemical and Non-Chemical Stressor Combinations

    EPA Science Inventory

    Presentation based on the following abstract: Chemical mixtures risk assessment methods are routinely used. To address combined chemical and nonchemical stressors, component-based approaches may be applicable, depending on the toxic action among diverse stressors. Such methods a...

  6. Chemical face peels.

    PubMed

    Matarasso, S L; Glogau, R G

    1991-01-01

    Application of caustic chemicals to improve cosmesis and reverse actinic damage has been used for centuries. Although still not an exact science, it was not until the latter part of this century that peeling became more systematized. The indications, patient selection, armamentarium, histology, comprehension of the mechanisms of action, and safety parameters of peels have only recently become more extensively defined. Phenol, when used in the Baker's formula, provides the most dramatic results but also holds the most potential for systemic complications. Ideally suited for fair-skinned women, a phenol peel can provide substantial improvement in rhytidosis and actinic damage. Although the results of medium-depth peels approach those of Baker's peels, they are not quite as profound. Use of TCA and the medium-depth peels has filled an important gap between deep and superficial peels, however. Also ideal for light complexions, this category of peels lightens pigmentary problems and improves rhytides with minimal potential for systemic toxicity; however, local complications, including scarring and pigmentary anomalies, should not be underestimated. [table: see text] Superficial peels do not effectively eradicate the ravages of time and sun, but when done repetitively, they do improve pigmentary irregularities and may improve some minor surface changes and thus impart a fresher appearance to facial skin. Although pigmentary changes can occur, superficial peels are relatively safe, and maximal results can be achieved with serial applications. Peels have been categorized by patient indications and the corresponding depth of peeling required for improvement (Table 4). The depth is determined in turn by a host of factors (Table 5). Neither the classification scheme nor the peel process should be viewed dogmatically. Patients will often benefit from the concurrent use of different skin preparations and wounding agents. Localized gradations can be achieved not only with occlusion but also by employing different solutions as well as different concentrations of the same solution and skin preparation. Selection of the appropriate technique relies on critical analysis of the skin defect one wishes to treat balanced against the risks of treatment. The final protocol should be individualized for the needs of each patient. Despite heightened public awareness of the harmful effects of ultraviolet radiation, actinically damaged skin is no longer a problem restricted to an older-patient population. Fueled by the lay press and practitioners, there is a growing patient demand for chemical peels. Chemical peels alone or combined with ancillary aesthetic procedures can provide a dramatic improvement in facial appearance. The potential for improved cosmesis is not without inherent risk, however.(ABSTRACT TRUNCATED AT 400 WORDS) PMID:2022090

  7. Absence of morphologic correlation between chemical toxicity and chemical carcinogenesis.

    PubMed Central

    Huff, J

    1993-01-01

    The experimental data set used to evaluate site-specific histopathologic correspondence between the morphologic end points of toxicity and carcinogenicity comprises 130 chemical carcinogenesis studies. Nearly 1500 sex-species-exposure-group experiments were evaluated for a) evidence of toxicity or/and carcinogenicity, b) dose-response relationships, c) site-specific correlations of toxicity and carcinogenicity, and d) correspondence with Salmonella mutagenicity. The major conclusions are that chemicals evaluated for long-term toxicity and carcinogenicity in experimental animals divide typically and consistently into three categories: a) chemicals causing organ toxicity without cancer, b) chemicals causing site-specific cancer with no associated toxicity, and c) chemicals causing both toxicity and cancer in the same organ. Few chemicals overall (and none in this data set) fit the remaining group that cause neither toxicity nor carcinogenicity under these protocol conditions. Mutagenicity exhibited no consistent pattern with any of these groupings. Only 7 of 53 "positive" chemicals had target organ toxicity at all sites of carcinogenicity. Just three chemicals showed carcinogenic effects at the highest exposure concentrations without supporting evidence of tumors at the lower levels. From these comparative morphological analyses, and for almost all cases, available data do not support a correlation between chemically induced toxicity or regenerative phenomena and carcinogenicity. Consequently, until scientific knowledge about molecular mechanisms of chemical carcinogenesis becomes better understood and generally accepted, attempts to use toxicity findings to modify risk assessment processes will be fraught with uncertainty and thus could have a negative impact on public health. PMID:8013424

  8. Natural chemicals, synthetic chemicals, risk assessment, and cancer

    SciTech Connect

    Ames, B.N.; Gold, L.S. )

    1990-01-01

    The administration of chemicals at the maximum tolerated dose (MTD) in standard animal cancer tests is postulated to increase cell division (mitogenesis), which in turn increases rates of mutagenesis and thus carcinogenesis. The animal data are consistent with this mechanism, because a high proportion of all chemicals tested are indeed rodent carcinogens. We conclude that at the low doses of most human exposures, where cell killing does not occur, the hazards to humans of rodent carcinogens may be much lower than is commonly assumed. The toxicological significance of exposures to synthetic chemicals is examined in the context of exposures to naturally occurring chemicals. We calculate that 99.99% of the pesticides in the American diet are chemicals that plants produce to defend themselves. Only 52 natural pesticides have been tested in high-dose animal cancer tests, and about half (27) are rodent carcinogens; these 27 are shown to be present in many common foods. We conclude that natural and synthetic chemicals are equally likely to be positive in animal cancer tests. The toxicology of synthetic chemicals is compared to that of natural chemicals, which represent the vast bulk of the chemicals to which humans are exposed. It is argued that animals have a broad array of inducible general defenses to combat the changing array of toxic chemicals in plant food (nature's pesticides) and that these defenses are effective against both natural and synthetic toxins. Synthetic toxins such as dioxin are compared to natural chemicals, such as indole carbinol and ethanol. The finding that in high-dose tests, a high proportion of both natural and synthetic chemicals are carcinogens, mutagens, teratogens, and clastogens (30-50% for each group) undermines current regulatory effects based on these tests to protect public health from low doses of synthetic chemicals.

  9. Volatile chemical reagent detector

    SciTech Connect

    Chen, Liaohai; McBranch, Duncan; Wang, Rong; Whitten, David

    2004-08-24

    A device for detecting volatile chemical reagents based on fluorescence quenching analysis that is capable of detecting neutral electron acceptor molecules. The device includes a fluorescent material, a contact region, a light source, and an optical detector. The fluorescent material includes at least one polymer-surfactant complex. The polymer-surfactant complex is formed by combining a fluorescent ionic conjugated polymer with an oppositely charged surfactant. The polymer-surfactant complex may be formed in a polar solvent and included in the fluorescent material as a solution. Alternatively, the complex may be included in the fluorescent material as a thin film. The use of a polymer-surfactant complex in the fluorescent material allows the device to detect both neutral and ionic acceptor molecules. The use of a polymer-surfactant complex film allows the device and the fluorescent material to be reusable after exposing the fluorescent material to a vacuum for limited time.

  10. [Chemical and electrical burns].

    PubMed

    Sanchez, Raymond

    2002-12-15

    Chemical burns are less frequent in routine practice, but could be very serious owing to the complexity and severity of their actions. Influx of casualty after a civil disaster (industrial explosion) or military (war or terrorism) is possible. The action of these agents could be prolonged and deep. In addition to the skin, respiratory lesions and general intoxication could be observed. The urgent local treatment rely essentially on prolonged washing. Prevention and adequate emergency care could limit the serious consequences of these accidents. Accidents (thermal burns or electrisations) due to high or low voltage electricity are frequent. The severity is linked with the affected skin but especially with internal lesions, muscular, neurological or cardiac lesions. All cases of electrisation need hospital care. Locally, the lesions are often deep with difficult surgical repairs and often require amputation. Aesthetic and functional sequela are therefore frequent. Secondary complications could appear several months after the accident: cataract, dysesthesia and hypotonia. PMID:12621941

  11. [Chemical and electrical burns].

    TOXLINE Toxicology Bibliographic Information

    Sanchez R

    2002-12-15

    Chemical burns are less frequent in routine practice, but could be very serious owing to the complexity and severity of their actions. Influx of casualty after a civil disaster (industrial explosion) or military (war or terrorism) is possible. The action of these agents could be prolonged and deep. In addition to the skin, respiratory lesions and general intoxication could be observed. The urgent local treatment rely essentially on prolonged washing. Prevention and adequate emergency care could limit the serious consequences of these accidents. Accidents (thermal burns or electrisations) due to high or low voltage electricity are frequent. The severity is linked with the affected skin but especially with internal lesions, muscular, neurological or cardiac lesions. All cases of electrisation need hospital care. Locally, the lesions are often deep with difficult surgical repairs and often require amputation. Aesthetic and functional sequela are therefore frequent. Secondary complications could appear several months after the accident: cataract, dysesthesia and hypotonia.

  12. Groundwater and organic chemicals

    SciTech Connect

    Dawson, H.E.

    1995-12-01

    Groundwater is a major source of drinking water for many communities. Unfortunately, organic chemicals such as dry cleaning fluids, solvent, fuels, and pesticides have contaminated groundwater in many areas, rendering the groundwater useless as a drinking water resource. In many cases, the groundwater cannot be cleaned up with current technologies, particularly if the groundwater has been contaminated with immiscible (low solubility) organic liquids. In this talk, I will describe the path I have followed from geologist to geochemist and finally to environmental engineer. As a geologist, I studied the chemistry of rock metamorphosis. As a geochemist, I explored for gold and other metals. Now as an environmental engineer, I investigate the behavior of organic liquids in the subsurface. While these fields all appear very different, in reality I have always focused on the interaction of rocks or sediments with the fluids with which they come in contact.

  13. Chemical Ecology of Neuroptera.

    PubMed

    Aldrich, Jeffrey R; Zhang, Qing-He

    2016-03-11

    With 6,000 species, Neuroptera (lacewings, antlions, dustywings, and allies) is a relatively small order; however, most larval neuropterans are predacious, often in agricultural systems, lending added importance to this group. Advances in neuropteran phylogeny, most recently through genomic studies, stabilized the nomenclature of this ancestral order of Holometabola, facilitating basic and applied research on these important and interesting insects. The first pheromones for green lacewings (Chrysopidae) have been identified; this, and other research on antlions (Myrmeleontidae), suggests that male-produced long-range pheromones are the norm for the order. Characterizations of the myriad neuropteran exocrine gland systems, including prothoracic, metathoracic, abdominal, dermal, and anal glands, are revealing unforeseen trophic relationships with biological control implications. For examples, males of Chrysopa and other lacewing genera evidently must sequester specific chemical precursors from prey or plants to produce their attractant pheromones, and larval antlion venoms are potentially important genetic leads for insecticidal peptides. PMID:26982440

  14. Chemical composition of Mars

    NASA Technical Reports Server (NTRS)

    Morgan, J. W.; Anders, E.

    1979-01-01

    The chemical composition of Mars is estimated from the cosmochemical model of Ganapathy and Anders (1974) with additional petrological and geophysical constraints. The model assumes that planets and chondrites underwent the same fractionation processes in the solar nebula, and constraints are imposed by the abundance of the heat-producing elements, U, Th and K, the volatile-rich component and the high density of the mantle. Global abundances of 83 elements are presented, and it is noted that the mantle is an iron-rich garnet wehrlite, nearly identical to the bulk moon composition of Morgan at al. (1978) and that the core is sulfur poor (3.5% S). The comparison of model compositions for the earth, Venus, Mars, the moon and a eucrite parent body suggests that volatile depletion correlates mainly with size rather than with radial distance from the sun.

  15. Chemical and Thermal Analysis

    NASA Technical Reports Server (NTRS)

    Bulluck, J. W.; Rushing, R. A.

    1995-01-01

    During the past six months we have conducted significant research in several domains in order to clarify and understanding the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. We organized numerous analytical studies with methods including Fourier Transform Infrared Spectroscopy, Dynamic Mechanical Analysis, Differential Scanning Calorimetry, and Stress Relaxation experiments. In addition we have reanalyzed previous thermogravimetric data concerning the rate of deplasticization of Coflon pipe. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. We conducted stress relaxation experiments of Coflon pipe at several temperatures and determined an activation energy. We also examined the dynamic mechanical response PVDF during deplasticization and during methanol plasticization. We performed numerous DSC analyses to research the changing crystalline morphology. We have noted significant changes in crystallinity upon aging for both PVDF and Tefzel. Little variation in elemental composition was noted for many of the aged Coflon and Tefzel samples tested.

  16. Chemical vapor deposition growth

    NASA Technical Reports Server (NTRS)

    Ruth, R. P.; Manasevit, H. M.; Kenty, J. L.; Moudy, L. A.; Simpson, W. I.; Yang, J. J.

    1976-01-01

    The chemical vapor deposition (CVD) method for the growth of Si sheet on inexpensive substrate materials is investigated. The objective is to develop CVD techniques for producing large areas of Si sheet on inexpensive substrate materials, with sheet properties suitable for fabricating solar cells meeting the technical goals of the Low Cost Silicon Solar Array Project. Specific areas covered include: (1) modification and test of existing CVD reactor system; (2) identification and/or development of suitable inexpensive substrate materials; (3) experimental investigation of CVD process parameters using various candidate substrate materials; (4) preparation of Si sheet samples for various special studies, including solar cell fabrication; (5) evaluation of the properties of the Si sheet material produced by the CVD process; and (6) fabrication and evaluation of experimental solar cell structures, using standard and near-standard processing techniques.

  17. Chemical vapor deposition growth

    NASA Technical Reports Server (NTRS)

    Ruth, R. P.; Manasevit, H. M.; Kenty, J. L.; Moudy, L. A.; Simpson, W. I.; Yang, J. J.

    1976-01-01

    A chemical vapor deposition (CVD) reactor system with a vertical deposition chamber was used for the growth of Si films on glass, glass-ceramic, and polycrystalline ceramic substrates. Silicon vapor was produced by pyrolysis of SiH4 in a H2 or He carrier gas. Preliminary deposition experiments with two of the available glasses were not encouraging. Moderately encouraging results, however, were obtained with fired polycrystalline alumina substrates, which were used for Si deposition at temperatures above 1,000 C. The surfaces of both the substrates and the films were characterized by X-ray diffraction, reflection electron diffraction, scanning electron microscopy optical microscopy, and surface profilometric techniques. Several experiments were conducted to establish baseline performance data for the reactor system, including temperature distributions on the sample pedestal, effects of carrier gas flow rate on temperature and film thickness, and Si film growth rate as a function of temperature.

  18. Recover chemicals from wastewater

    SciTech Connect

    1995-01-01

    For years, solution mining near Prague in the Czech Republic has produced acid-laden wastewater, which has accumulated in deep underground caverns. Over the years, this acid waste has spread into a large underground reservoir, which today threatens the aquifer that supplies drinking water to Prague, about 70 miles south of the mine. Later this year, a two-pronged site cleanup will be carried out by Resources Conservation Co. International (RCCI), a subsidiary of Ionics, Inc. (Watertown, Mass.). First, the acid water will be pumped to the surface. Then, the stream, which contains sulfuric acid and aluminum ammonium sulfate (ammonium alum) will undergo evaporation and crystallization to recover the ammonium alum, a widely used water-treatment chemical, and fresh water for reuse.

  19. Concordant Chemical Reaction Networks

    PubMed Central

    Shinar, Guy; Feinberg, Martin

    2015-01-01

    We describe a large class of chemical reaction networks, those endowed with a subtle structural property called concordance. We show that the class of concordant networks coincides precisely with the class of networks which, when taken with any weakly monotonic kinetics, invariably give rise to kinetic systems that are injective a quality that, among other things, precludes the possibility of switch-like transitions between distinct positive steady states. We also provide persistence characteristics of concordant networks, instability implications of discordance, and consequences of stronger variants of concordance. Some of our results are in the spirit of recent ones by Banaji and Craciun, but here we do not require that every species suffer a degradation reaction. This is especially important in studying biochemical networks, for which it is rare to have all species degrade. PMID:22659063

  20. Chemical properties of mendelevium

    SciTech Connect

    Hulet, E.K.

    1980-11-01

    Even with the most intense ion beams and the largest available quantities of target isotope, about 10/sup 6/ atoms at a time is all the Md that can be produced for chemical studies. This lack of sufficient sample size coupled with the very short lifetimes of the few atoms produced has severely restricted the gathering and the broadness of our knowledge concerning the properties of Md and the heavier elements. To illustrate, the literature contains a mere eleven references to the chemical studies of Md, and none of these deal with bulk properties associated with the element bound in solid phases. Some of these findings are: Md was found to be more volatile than other actinide metals which lead to the belief that it is divalent in the metallic state; separation of Md from the other actinides can be accomplished either by reduction of Md/sup 3 +/ to the divalent state or by chromatographic separations with Md remaining in the tripositive state; extraction of Md/sup 2 +/ with bis(2-ethylhexyl)phosphoric acid is much poorer than the extraction of the neighboring tripositive actinides; attempts to oxidize Md/sup 3 +/ with sodium bismuthate failed to show any evidence for Md/sup 4 +/; reduction potential of Md/sup 3 +/ was found to be close to -0.1 volt; Md/sup 3 +/ can be reduced to Md(Hg) by sodium amalgams and by electrolysis; the electrochemical behavior of Md is very similar to that of Fm and can be summarized in the equation, Md/sup 2 +/ + 2e/sup -/ = Md(Hg) and E/sup 0/ = -1.50 V.; and Md cannot be reduced to a monovalent ion with Sm/sup 2 +/.