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Sample records for texaco gasification process

  1. DEMONSTRATION BULLETIN: TEXACO GASIFICATION PROCESS TEXACO, INC.

    EPA Science Inventory

    The Texaco Gasification Process (TGP) has operated commercially for nearly 45 years on feeds such as natural gas, liquid petroleum fractions, coal, and petroleum coke. More than 45 plants are either operational or under development in the United States and abroad. Texaco has dev...

  2. TEXACO GASIFICATION PROCESS - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    EPA Science Inventory

    This report summarizes the evaluation of the Texaco Gasification Process (TGP) conducted under the U.S. Environmental Protection Agency (EPA) Superfund Innovative Technology Evaluation (SITE) Program. The Texaco Gasification Process was developed by Texaco Inc. The TGP is a comm...

  3. U.S. EPA'S EVALUATION OF A TEXACO GASIFICATION TECHNOLOGY

    EPA Science Inventory

    Gasification technologies are designed to produce, from carbonaceous organic materials (e.g., coal, oil), a useable mixture of carbon monoxide and hydrogen called synthesis gas, or syngas. yngas could be used to produce power or chemicals. he Texaco Gasification Process (TGP) emp...

  4. IsoTex: Texaco`s olefin skeletal isomerization process

    SciTech Connect

    Sawicki, R.A.; Pellet, R.J.; Kuhlmann, E.J.; Huang, H.M.; O`Young, C.L.; Kessler, R.V.; Casey, D.G.

    1995-09-01

    Texaco has developed a new process (IsoTex) for the skeletal isomerization of n-olefins. The IsoTex process can convert normal butenes to isobutylene or normal pentenes to isoamylenes. The resulting product stream is an excellent feed for MTBE, ETBE or TAME units. The process has isomerized an untreated refinery C4 raffinate stream from an MTBE plant. A kinetic model was developed for the butene system. This model accurately predicted IsoTex performance in a one barrel per day skid unit at a Gulf Coast chemical plant. Process economics have been calculated for a once through 54,000 BPD C{sub 4} isomerization plant as well as a 10,000 BPD plant for recycle to an existing MTBE reactor. Economics have also been completed for a 6,800 BPD pentene once through isomerization unit.

  5. Coal Liquefaction Technology Assessment. Phase II. Texaco gasification. Final report

    SciTech Connect

    Not Available

    1984-03-01

    This report represents Phase II (Texaco gasifier cases) of a multi-phase Coal Liquefaction Technology Assessment Study. The purpose of this effort is to provide technical and cost information in support of the task of comparing coal liquefaction processes on a consistent basis. The conceptual designs presented in Phase II are representative of first and second generation processes for producing methanol fuels from coal. These processes are also indirect coal liquefaction processes; coal is gasified, then converted to liquid products. Four conceptual designs have been prepared: Case TXW: Texaco gasifiers - Western subbituminous coal; Case TXE: Texaco gasifiers - Eastern bituminous coal; Case KW: Koppers gasifiers - Western subbituminous coal; and Case KE: Koppers gasifiers - Eastern bituminous coal. Wyoming Wyodak coal (identical to the coal used in Phase I) and Illinois Herrin 6 coal were used in this study as representative of western and eastern coals. Analyses of these coals are presented in Appendix C. In each Phase II case, 16,000 T/D of MAF coal (identical to Phase I) are fed to the gasifiers. Unleaded gasoline via the fixed-bed Mobil MTG process is the primary product. Propane and butane LPG are also produced in each case. Capital investment and operating costs were developed for each of the four cases based on mid-1979 costs. No projection has been included for escalation. Cost estimates are presented for the Texaco gasifier cases only in this report.

  6. SITE TECHNOLOGY CAPSULE: TEXACO GASIFICATION PROCESS

    EPA Science Inventory

    In 1980, the U.S. Congress passed the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), also known as Superfund. to protect human health and the environment from uncontrolled hazardous waste sites. CERCLA was amended by the Superfund Amendments and R...

  7. Residue gasification tests at TVA

    SciTech Connect

    Spencer, D.

    1984-11-01

    The Texaco gasification process was identified as an attractive way to utilise vacuum bottoms from the Exxon Donor Solvent liquefaction process to generate synthesis gas. This gas can then be upgraded to produce the hydrogen required by the EDS plant. Gasification tests were carried out at TVA's 200 t/day Muscle Shoals plant and are reported here. As a result, Texaco expects that a plant could be designed to handle EDS residue from any high-rank coal.

  8. Heavy oil upgrading using an integrated gasification process

    SciTech Connect

    Quintana, M.E.; Falsetti, J.S.

    1995-12-31

    The value of abundant, low-grade heavy crude oil reserves can be enhanced by appropriate upgrade processing at the production site to yield marketable refinery feedstocks or ultimate products. One of the upgrading process sequences most commonly considered involves vacuum distillation followed by a bottoms processing step such as solvent deasphalting or coking. These schemes can be further enhanced with the addition of a gasification step to convert the unsaleable, bottom-of-the-barrel residues into useful products, such as high-purity hydrogen for hydrotreating, electrical power, steam for enhanced oil recovery and distillation, etc. This paper describes the Texaco Gasification Process and the T-STARs hydrotreating process, and their application in an integrated upgrade processing scheme in which an optimal, virtually bottomless oil utilization can be achieved. Illustrative examples of this integration are provided with comparative economic information.

  9. Coal gasification cogeneration process

    SciTech Connect

    Marten, J.H.

    1990-10-16

    This patent describes a process for the coproduction of a combustible first gas stream usable as an energy source, a sulfur-dioxide-containing second gas stream usable as a source for oxidant in the gasification of coal and a sulfur-dioxide-containing third gas stream usable as a feedstock for the production of sulfuric acid. It comprises: reacting coal in a coal gasification zone in the presence of an oxidant under partial coal-gasifying conditions to produce carbonaceous char and a crude gas stream; separating sulfur-containing compounds from the crude gas stream in a sulfur recovery zone to produce a combustible first gas stream and elemental sulfur; reacting the carbonaceous char and gypsum in a reaction zone in proportions such that the non-gypsum portion of the carbonaceous char and gypsum mixture contains sufficient reducing potential to reduce sulfur in the gypsum to gaseous compounds of sulfur in a +4 or lower oxidation state under reducing conditions to produce first a sulfur-dioxide-containing second gas stream which contains weaker SO{sub 2} produced in an early stage of the reaction zone and removed from the reaction zone, and then a sulfur-dioxide-containing third gas stream which contains concentrated SO{sub 2} recovered from a later stage of the reaction zone.

  10. DESIGN, FABRICATION AND BENCH TESTING OF A TEXACO INFRARED RATIO PYROMETER SYSTEM FOR THE MEASUREMENT OF GASIFIER REACTION CHAMBER TEMPERATURE

    SciTech Connect

    Thomas F. Leininger; Hua-Min Huang

    2003-07-01

    Polk Power has decided that the Texaco gasification unit will not be sold to a third party. Therefore, including the ownership transfer of the Texaco gasification unit in the agreement is not an issue any more. The cooperative agreement between Texaco and Polk Power has been revised several times in this quarter. Polk power is making comments on the last draft that Texaco sent to them. The modification fieldwork and testing will start once the cooperative agreement is signed with Polk Power.

  11. Coking and gasification process

    DOEpatents

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  12. Updraft gasification of salmon processing waste

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The purpose of this research is to judge the feasibility of gasification for the disposal of waste streams generated through salmon harvesting. Gasification is the process of converting carbonaceous materials into combustible syngas in a high temperature (above 700 C), oxygen deficient environmen...

  13. Assessment of advanced coal gasification processes

    NASA Technical Reports Server (NTRS)

    Mccarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-01-01

    A technical assessment of the following advanced coal gasification processes is presented: high throughput gasification (HTG) process; single stage high mass flux (HMF) processes; (CS/R) hydrogasification process; and the catalytic coal gasification (CCG) process. Each process is evaluated for its potential to produce synthetic natural gas from a bituminous coal. Key similarities, differences, strengths, weaknesses, and potential improvements to each process are identified. The HTG and the HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging, and syngas as the initial raw product gas. The CS/R hydrogasifier is also SRT, but is nonslagging and produces a raw gas high in methane content. The CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier.

  14. Chicken-Bio Nuggets Gasification process

    SciTech Connect

    Sheth, A.C.

    1996-12-31

    With the cost of landfill disposal skyrocketing and land availability becoming scarce, better options are required for managing our nation`s biomass waste. In response to this need, the University of Tennessee Space Institute (UTSI) is evaluating an innovative idea (described as Chicken-Bio Nuggets Gasification process) to gasify waste products from the poultry industry and industrial wood/biomass-based residues in {open_quotes}as-is{close_quotes} or aggregate form. The presence of potassium salts in the poultry waste as well as in the biomass can act as a catalyst in reducing the severity of the thermal gasification. As a result, the mixture of these waste products can be gasified at a much lower temperature (1,300-1,400{degrees}F versus 1,800-2,000{degrees}F for conventional thermal gasification). Also, these potassium salts act as a catalyst by accelerating the gasification reaction and enhancing the mediation reaction. Hence, the product gas from this UTSI concept can be richer in methane and probably can be used as a source of fuel (to replace propane in hard reach remote places) or as a chemical feed stock. Exxon Research and Engineering Company has tested a similar catalytic gasification concept in a fluid-bed gasifier using coal in a one ton/day pilot plant in Baytown, Texas. If found technically and economically feasible, this concept can be later on extended to include other kinds of waste products such as cow manure and wastes from swine, etc.

  15. Assessment of Advanced Coal Gasification Processes

    NASA Technical Reports Server (NTRS)

    McCarthy, John; Ferrall, Joseph; Charng, Thomas; Houseman, John

    1981-01-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process; Bell Single-Stage High Mass Flux (HMF) Process; Cities Service/Rockwell (CS/R) Hydrogasification Process; Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic, fluidbed reactor producing all of the raw product methane in the gasifier. The report makes the following assessments: 1) while each process has significant potential as coal gasifiers, the CS/R and Exxon processes are better suited for SNG production; 2) the Exxon process is the closest to a commercial level for near-term SNG production; and 3) the SRT processes require significant development including scale-up and turndown demonstration, char processing and/or utilization demonstration, and reactor control and safety features development.

  16. Atmospheric pressure gasification process for power generation

    SciTech Connect

    Morris, M.

    1996-12-31

    Since 1987 TPS Termiska Processer AB has been working on the development of both a biomass-fueled circulating fluidized bed (CFB) gasification process and a downstream dolomite catalytic tar removal process. The combined process has been developed in a 2 MWth pilot plant which was built originally for investigating the use of the product gas in a diesel motor cogeneration plant. A prototype gasification plant comprising two waste-fueled 15 MWth CFB gasifiers has been installed in Greve-in-Chianti, Italy. Since 1990, TPS has been working on the development of a biomass-fueled integrated gasification combined-cycle scheme utilizing both a CFB gasifier and a CFB tar cracker. In 1992, TPS was contracted by the Global Environmental Facility (GEF) to perform work for Phase II of the Brazilian BIG-GT (Biomass Integrated Gasification-Gas Turbine) project. This stage of the project involved both experimental and engineering studies and the basic engineering for a 30 MWe eucalyptus-fueled power plant in Brazil. The plant is based on the GE LM 2500 gas turbine. During this stage of the project the TPS process was in competition with a process from a pressurized gasification technology vendor. However, in 1995 TPS was selected for participation in Phase III of the project. Phase III of the project includes construction and commissioning of the plant. Involvement in the Brazilian BIG-GT project has served as a springboard for the participation of TPS in similar projects in the Netherlands and the UK. In the UK, ARBRE Energy Limited is constructing a coppice-fueled 8 MWe plant with support from the EU THERMIE program and the UKs NFFO (Non Fossil Fuel Obligation). The design contract will be awarded in late 1996. In the Netherlands, a number of projects for biomass and wastes are being pursued by TPS in cooperation with Royal Schelde of the Netherlands.

  17. Updraft gasification of salmon processing waste.

    PubMed

    Rowland, Sarah; Bower, Cynthia K; Patil, Krushna N; DeWitt, Christina A Mireles

    2009-10-01

    The purpose of this study was to judge the feasibility of gasification for the disposal of waste streams generated through salmon harvesting. Gasification is the process of converting carbonaceous materials into combustible "syngas" in a high temperature (above 700 degrees C), oxygen deficient environment. Syngas can be combusted to generate power, which recycles energy from waste products. At 66% to 79% moisture, raw salmon waste streams are too wet to undergo pyrolysis and combustion. Ground raw or de-oiled salmon whole fish, heads, viscera, or frames were therefore "dried" by mixing with wood pellets to a final moisture content of 20%. Ground whole salmon with moisture reduced to 12% moisture was gasified without a drying agent. Gasification tests were performed in a small-scale, fixed-bed, updraft gasifer. After an initial start-up period, the gasifier was loaded with 1.5 kg of biomass. Temperature was recorded at 6 points in the gasifier. Syngas was collected during the short steady-state period during each gasifier run and analyzed. Percentages of each type of gas in the syngas were used to calculate syngas heating value. High heating value (HHV) ranged from 1.45 to 1.98 MJ/kg. Bomb calorimetry determined maximum heating value for the salmon by-products. Comparing heating values shows the efficiency of gasification. Cold gas efficiencies of 13.6% to 26% were obtained from the various samples gasified. Though research of gasification as a means of salmon waste disposal and energy production is ongoing, it can be concluded that pre-dried salmon or relatively low moisture content mixtures of waste with wood are gasifiable. PMID:19799663

  18. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  19. Method for increasing steam decomposition in a coal gasification process

    DOEpatents

    Wilson, M.W.

    1987-03-23

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  20. Method for increasing steam decomposition in a coal gasification process

    DOEpatents

    Wilson, Marvin W. (Fairview, WV)

    1988-01-01

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  1. BIOMASS REACTIVITY IN GASIFICATION BY THE HYNOL PROCESS

    EPA Science Inventory

    A thermobalance reactor was used to evaluate the reactivity of poplar wood in gasification under the operating conditions specific for the Hynol process where biomass is gasified at 30 atm and 800E C with a hydrogen-rich gas recycled from methane synthesis. The gasification invol...

  2. Fluidized bed catalytic coal gasification process

    DOEpatents

    Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  3. Pulsed combustion process for black liquor gasification

    SciTech Connect

    Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

    1991-02-01

    The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

  4. Process for fixed bed coal gasification

    DOEpatents

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  5. Second stage gasifier in staged gasification and integrated process

    DOEpatents

    Liu, Guohai; Vimalchand, Pannalal; Peng, Wan Wang

    2015-10-06

    A second stage gasification unit in a staged gasification integrated process flow scheme and operating methods are disclosed to gasify a wide range of low reactivity fuels. The inclusion of second stage gasification unit operating at high temperatures closer to ash fusion temperatures in the bed provides sufficient flexibility in unit configurations, operating conditions and methods to achieve an overall carbon conversion of over 95% for low reactivity materials such as bituminous and anthracite coals, petroleum residues and coke. The second stage gasification unit includes a stationary fluidized bed gasifier operating with a sufficiently turbulent bed of predefined inert bed material with lean char carbon content. The second stage gasifier fluidized bed is operated at relatively high temperatures up to 1400.degree. C. Steam and oxidant mixture can be injected to further increase the freeboard region operating temperature in the range of approximately from 50 to 100.degree. C. above the bed temperature.

  6. A summary report on combustion and gasification processes

    SciTech Connect

    Rath, L.K.; Lee, G.T.

    1996-08-01

    Six poster papers regarding combustion and gasification were reviewed. These six papers address various different technology subjects: (1) underground coal gasification modeling, (2) wood gasification kinetics, (3) heat transfer surface pretreatment by iron implantation, (4) coal water slurry stabilization technology, (5) coal log pipeline technology, and (6) nuclear reactor decontamination. Summaries and comments of the following papers are presented: Characterization of Flow and Chemical Processes in an Underground Gasifier at Great Depth; Model for Reaction Kinetics in Pyrolysis of Wood; Development of a Stainless Steel Heat Transfer Surface with Low Scaling Tendency; Storage and Transportation of Coal Water Mixtures; Coal Log Pipeline: Development Status of the First Commercial System; and Decontamination of Nuclear Systems at the Grand Gulf Nuclear Station.

  7. Texaco's deepstar: Deepwater staged recovery

    SciTech Connect

    Verret, A.J. )

    1994-04-01

    The deepwater of the Gulf of Mexico (GOM) represents one of the best remaining domestic opportunities accessible to the oil and gas industry and believed to contain significant reserves of producible hydrocarbons. In the last five years 3.5 billion barrels of reserves have been discovered in the deepwater Gulf-defined as water depths from 3,000 to 6,000 feet. The challenges offered by the deep-water GOM are considerable - both commercially and technically. Current production system technology limits are 3,000 - 3,500 foot water depths. There is limited production experience to date from deep-water fields. However, production strategy and equipment to produce these reserves are being developed by DeepStar, an industry effort led by Texaco, Inc. Staged production using subsea techniques allows companies to avoid major financial commitment until production capability has been proven. The project has identified phased subsea production systems operating as extensions of shallow water platforms a key mechanism for commercial development of deepwater prospects. A small number of shallow water platforms tied to subsea production systems, offset up to 60-miles into deep water, are capable of commercially developing in excess of 80 percent of existing deepwater GOM leases. DeepStar may provide the entire offshore producing community with a way to commercially access deep water.

  8. Heat exchanger for coal gasification process

    DOEpatents

    Blasiole, George A. (Greensburg, PA)

    1984-06-19

    This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

  9. The gasification of molten coal hydrogenation residues - experience with the Ruhrkohle/Ruhrchemie coal gasification plant at Oberhausen-Holten

    SciTech Connect

    Langhoff, J.; Schafer, W.; Cornils, B.; Konkol, W.

    1985-01-01

    In the wake of the 1973 oil crisis, ongoing, large-scale development of coal upgrading processes was undertaken in West Germany and around the world. Two of the most successful processes are the coal-oil plant at Bottrop and the Texaco coal gasification plant at Oberhausen-Holten. The fact that developments ran in parallel made possible transfer of the vacuum residue in a molten state from the hydrogenation plant to the gasification plant. The gasification of the residue is in the interest of economical production of the make-up hydrogen required for hydrogenation or-where this hydrogen can be acquired from another source-for production of synthesis gas while at the same time disposing of the residue in an environmentally sound fashion.

  10. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect

    Calderon, A.; Madison, E.; Probert, P.

    1992-01-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H[sub 2] mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO[sub x] (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  11. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect

    Calderon, A.; Madison, E.; Probert, P.

    1992-11-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H{sub 2} mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO{sub x} (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  12. Integration and testing of hot desulfurization and entrained-flow gasification for power generation systems. Phase 2, Process optimization: Volume 1, Program summary and PDU operations

    SciTech Connect

    Robin, A.M.; Kassman, J.S.; Leininger, T.F.; Wolfenbarger, J.K.; Wu, C.M.; Yang, P.P.

    1991-09-01

    This second Topical Report describes the work that was completed between January 1, 1989 and December 31, 1990 in a Cooperative Agreement between Texaco and the US Department of Energy that began on September 30, 1987. During the period that is covered in this report, the development and optimization of in-situ and external desulfurization processes were pursued. The research effort included bench scale testing, PDU scoping tests, process economic studies and advanced instrument testing. Two bench scale studies were performed at the Research Triangle Institute with zinc titanate sorbent to obtain data on its cycle life, sulfur capacity, durability and the effect of chlorides. These studies quantify sulfur capture during simulated air and oxygen-blown gasification for two zinc titanate formulations. Eight PDU runs for a total of 20 days of operation were conducted to evaluate the performance of candidate sorbents for both in-situ and external desulfurization. A total of 47 tests were completed with oxygen and air-blown gasification. Candidate sorbents included iron oxide for in-situ desulfurization and calcium based and mixed metal oxides for external desulfurization. Gasifier performance and sorbent sulfur capture are compared for both air-blown and oxygen-blown operation.

  13. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

    SciTech Connect

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-12-01

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

  14. Integrated coal cleaning, liquefaction, and gasification process

    DOEpatents

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  15. Modeling the underground coal gasification process: part III-subsidence

    SciTech Connect

    Krantz, W.B.; Gunn, R.D.

    1983-01-01

    The cavity created by underground coal gasification (UCG) will be associated with some degree of subsidence in the overburden above the cavity. Subsidence refers to the adjustment in the earth which is made in response to the creation of a subsurface cavity. This subsidence can take a variety of forms, some of which can cause considerable damage both to the environment and to the UCG process and associated equipment. This article reviews the physical and geometrical factors which must be considered in subsidence modeling and the empirical, analytical, numerical, and phenomenological approaches used to model subsidence in UCG. Finally, the results of applying these subsidence models to UCG field tests are reviewed.

  16. Development of an advanced continuous mild gasification process for the production of coproducts. Task 4, Mild gasification tests

    SciTech Connect

    Merriam, N.W.; Cha, C.Y.; Kang, T.W.; Vaillancourt, M.B.

    1990-12-01

    Western Research Institute (WRI) teamed with the AMAX Research and Development Center and Riley Stoker Corporation on Development of an Advanced, Continuous Mild-Gasification Process for the Production of Coproducts under contract DE-AC21-87MC24268 with the Morgantown Energy Technology of the US Department of Energy. The strategy for this project is to produce electrode binder pitch and diesel fuel blending stock by mild gasification of Wyodak coal. The char is upgraded to produce anode-grade carbon, carbon black, and activated carbon. This report describes results of mild-gasification tests conducted by WRI. Char upgrading tests conducted by AMAX will be described in a separate report.

  17. Scaleup of mild gasification to a process development unit

    SciTech Connect

    Campbell, J.A.L.; Carty, R.H.; Saladin, N.; Mead, J.; Foster, H.

    1992-11-01

    The overall objectives of this project is to develop the IGT Mild-Gasification (MILDGAS) process for near-term commercialization. The specific objectives of the program are to: design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scaleup obtain large batches of coal-derived co-products for industrial evaluation prepare a detailed design of a demonstration unit develop technical and economic plans for commercialization of the MILDGAS process. During the first ten months of this project. the NEPA Application for construction and operation of the PDU facility at the SIUC site was written and submitted for approval. In addition, the process design for the PDU was completed, bid packages for the PDU modules were prepared and sent to a slate of prospective bidders, and bids were received from the participating bidders.

  18. Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

    SciTech Connect

    A.M. Gandrik

    2012-04-01

    This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

  19. Thermoeconomic analysis of a gasification-combined-cycle power plant. Final report. [Includes 2nd law evaluation of processes

    SciTech Connect

    Tsatsaronis, G. Winhold, M.; Stojanoff, C.G.

    1986-08-01

    This report presents the results of a study conducted to further develop a thermoeconomic (combined thermodynamic and economic) methodology for the analysis and evaluation of power plants, and to apply the procedures of the methodology to an integrated coal gasification-combined-cycle (IGCC) power plant. The design and cost estimates used in the thermoeconomic analysis are based on the results of a recent comprehensive EPRI study conducted by Fluor Engineers, Inc., with participation of Texaco, Inc., and of the General Electric Company. One basic plant configuration was thermoeconomically analyzed. Results of this study indicate that the cost of net electricity could decrease by increasing capital cost to decrease exergy losses in the gas turbine system, and by improving (reducing the capital cost of) the heat-exchanger network of the total process. Addition of a reheat stage in the gas turbine system can improve overall IGCC plant efficiency by more than 2.5 percentage points. The analyses allow identification and evaluation of the real cost sources, and the opportunities for improvement of any energy-conversion process. The detailed thermoeconomic analysis of the base plant is based on the exergy (useful energy) concept, and enables the costing of the exergy streams flowing between plant components, and the exergy losses (real ''energy'' losses) in these components. The higher the exergy losses, the lower the efficiency of the plant component being investigated. The recommendations from the thermoeconomic analysis are based on comparison between (a) costs of fuel and product of each plant component, and (b) capital costs and costs of exergy losses associated with each plant component. The objective is to find an optimum combination of capital expenditures and efficiency for the major components of the power plant. 21 refs., 19 figs., 33 tabs.

  20. The BGL coal gasification process -- Applications and status

    SciTech Connect

    Davies, H.S.; Vierrath, H.E.; Johnson, K.S.; Kluttz, D.E.

    1994-12-31

    In 1991 British Gas completed a 15 year program for the development and demonstration of the BGL gasification process for Substitute Natural Gas and power generation. The final two objectives in this program at the Westfield Development Centre of British Gas were to demonstrate the suitability of the BGL gasifier for power generation under utility load requirements using typical UK power station coals and to operate the gasifier at pressures up to 65 bar. The first part of the program was an $18 million joint demonstration with National Power and PowerGen and supported by British Coal, the UK Department of Energy and the European Community which confirmed conclusively in tests spanning 40 days of operation that the full range of available UK power station coals can be gasified at very high efficiency in the BGL Gasifier. The development program then concluded with tests on a new, purpose designed, high pressure gasifier to determine the effect of pressure on gasification performance and operability. The use of the new ABB GT 24/26 gas turbines in BGL IGCC plant is explored and the BGL IGCC project in the US Clean Coal Technology Programme (CCTV) is described briefly.

  1. Co-gasification of tire and biomass for enhancement of tire-char reactivity in CO2 gasification process.

    PubMed

    Lahijani, Pooya; Zainal, Zainal Alimuddin; Mohamed, Abdul Rahman; Mohammadi, Maedeh

    2013-06-01

    In this investigation, palm empty fruit bunch (EFB) and almond shell (AS) were implemented as two natural catalysts rich in alkali metals, especially potassium, to enhance the reactivity of tire-char through co-gasification process. Co-gasification experiments were conducted at several blending ratios using isothermal Thermogravimetric analysis (TGA) under CO2. The pronounced effect of inherent alkali content of biomass-chars on promoting the reactivity of tire-char was proven when acid-treated biomass-chars did not exert any catalytic effect on improving the reactivity of tire-char in co-gasification experiments. In kinetic studies of the co-gasified samples in chemically-controlled regime, modified random pore model (M-RPM) was adopted to describe the reactive behavior of the tire-char/biomass-char blends. By virtue of the catalytic effect of biomass, the activation energy for tire-char gasification was lowered from 250 kJ/mol in pure form 203 to 187 kJ/mol for AS-char and EFB-char co-gasified samples, respectively. PMID:23612170

  2. Integration of stripping of fines slurry in a coking and gasification process

    DOEpatents

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  3. Instrumentation for optimizing an underground coal-gasification process

    NASA Astrophysics Data System (ADS)

    Seabaugh, W.; Zielinski, R. E.

    1982-06-01

    While the United States has a coal resource base of 6.4 trillion tons, only seven percent is presently recoverable by mining. The process of in-situ gasification can recover another twenty-eight percent of the vast resource, however, viable technology must be developed for effective in-situ recovery. The key to this technology is system that can optimize and control the process in real-time. An instrumentation system is described that optimizes the composition of the injection gas, controls the in-situ process and conditions the product gas for maximum utilization. The key elements of this system are Monsanto PRISM Systems, a real-time analytical system, and a real-time data acquisition and control system. This system provides from complete automation of the process but can easily be overridden by manual control. The use of this cost effective system can provide process optimization and is an effective element in developing a viable in-situ technology.

  4. Development of an advanced, continuous mild gasification process for the production of co-products: Topical report

    SciTech Connect

    Cha, C.Y.; Merriam, N.W.; Jha, M.C.; Breault, R.W.

    1988-06-01

    Research on mild gasification is discussed. The report is divided into three sections: literature survey of mild gasification processes; literature survey of char, condensibles, and gas upgrading and utilization methods; and industrial market assessment of products of mild gasification. Recommendations are included in each section. (CBS) 248 refs., 58 figs., 62 tabs.

  5. Development of an advanced continuous mild gasification process for the production of coproducts. Final report

    SciTech Connect

    Merriam, N.W.; Jha, M.C.

    1991-11-01

    This report is a final brief summary of development of a mild-gasification and char conversion process. Morgantown Energy Technology Center developed a concept called mild gasification. In this concept, devolatilization of coal under nonoxidizing and relatively mild temperature and pressure conditions can yield three marketable products: (1) a high-heating-value gas, (2) a high-aromatic coal liquid, and (3) a high-carbon char. The objective of this program is to develop an advanced, continuous, mild-gasification process to produce products that will make the concept economically and environmentally viable. (VC)

  6. Development of an advanced continuous mild gasification process for the production of coproducts

    SciTech Connect

    Merriam, N.W.; Jha, M.C.

    1991-11-01

    This report is a final brief summary of development of a mild-gasification and char conversion process. Morgantown Energy Technology Center developed a concept called mild gasification. In this concept, devolatilization of coal under nonoxidizing and relatively mild temperature and pressure conditions can yield three marketable products: (1) a high-heating-value gas, (2) a high-aromatic coal liquid, and (3) a high-carbon char. The objective of this program is to develop an advanced, continuous, mild-gasification process to produce products that will make the concept economically and environmentally viable. (VC)

  7. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  8. Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes

    E-print Network

    Gong, Bo, Ph. D. Massachusetts Institute of Technology

    2011-01-01

    Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

  9. Advanced hot gas cleaning system for coal gasification processes

    NASA Astrophysics Data System (ADS)

    Newby, R. A.; Bannister, R. L.

    1994-04-01

    The United States electric industry is entering a period where growth and the aging of existing plants will mandate a decision on whether to repower, add capacity, or do both. The power generation cycle of choice, today, is the combined cycle that utilizes the Brayton and Rankine cycles. The combustion turbine in a combined cycle can be used in a repowering mode or in a greenfield plant installation. Today's fuel of choice for new combined cycle power generation is natural gas. However, due to a 300-year supply of coal within the United States, the fuel of the future will include coal. Westinghouse has supported the development of coal-fueled gas turbine technology over the past thirty years. Working with the U.S. Department of Energy and other organizations, Westinghouse is actively pursuing the development and commercialization of several coal-fueled processes. To protect the combustion turbine and environment from emissions generated during coal conversion (gasification/combustion) a gas cleanup system must be used. This paper reports on the status of fuel gas cleaning technology and describes the Westinghouse approach to developing an advanced hot gas cleaning system that contains component systems that remove particulate, sulfur, and alkali vapors. The basic process uses ceramic barrier filters for multiple cleaning functions.

  10. Method and system for controlling a gasification or partial oxidation process

    DOEpatents

    Rozelle, Peter L; Der, Victor K

    2015-02-10

    A method and system for controlling a fuel gasification system includes optimizing a conversion of solid components in the fuel to gaseous fuel components, controlling the flux of solids entrained in the product gas through equipment downstream of the gasifier, and maximizing the overall efficiencies of processes utilizing gasification. A combination of models, when utilized together, can be integrated with existing plant control systems and operating procedures and employed to develop new control systems and operating procedures. Such an approach is further applicable to gasification systems that utilize both dry feed and slurry feed.

  11. Texaco scores a first in the Baltic

    SciTech Connect

    Not Available

    1983-10-01

    Wells on the first of 2 small concrete platforms designed specifically for the fragile but harsh environment of the Baltic Sea will produce the first oil from that offshore area by late 1984. The consortium of Deutsche Texaco AG and Wintershall AG awarded contracts late last year for the platforms and drilling equipment needed to develop the Schwedeneck-See field in Kiel Bay, off the northern coast of West Germany. Severe winter weather in the area dictated the use of concrete platforms rather than conventional 6-pile steel structures. Ice forces, generated by high winds and moderate waves, demanded heavy-duty structures in spite of the shallow water. A complicating factor in the field development plan is the presence of a German Navy submarine practice area which influenced location of one of the platforms. This means that all wells will be directionally drilled, and the reach will be greater than under more favorable conditions.

  12. Geochemical Proxies for Enhanced Process Control of Underground Coal Gasification

    NASA Astrophysics Data System (ADS)

    Kronimus, A.; Koenen, M.; David, P.; Veld, H.; van Dijk, A.; van Bergen, F.

    2009-04-01

    Underground coal gasification (UCG) represents a strategy targeting at syngas production for fuel or power generation from in-situ coal seams. It is a promising technique for exploiting coal deposits as an energy source at locations not allowing conventional mining under economic conditions. Although the underlying concept has already been suggested in 1868 and has been later on implemented in a number of field trials and even at a commercial scale, UCG is still facing technological barriers, impeding its widespread application. Field UCG operations rely on injection wells enabling the ignition of the target seam and the supply with oxidants (air, O2) inducing combustion (oxidative conditions). The combustion process delivers the enthalpy required for endothermic hydrogen production under reduction prone conditions in some distance to the injection point. The produced hydrogen - usually accompanied by organic and inorganic carbon species, e.g. CH4, CO, and CO2 - can then be retrieved through a production well. In contrast to gasification of mined coal in furnaces, it is difficult to measure the combustion temperature directly during UCG operations. It is already known that geochemical parameters such as the relative production gas composition as well as its stable isotope signature are related to the combustion temperature and, consequently, can be used as temperature proxies. However, so far the general applicability of such relations has not been proven. In order to get corresponding insights with respect to coals of significantly different rank and origin, four powdered coal samples covering maturities ranging from Ro= 0.43% (lignite) to Ro= 3.39% (anthracite) have been gasified in laboratory experiments. The combustion temperature has been varied between 350 and 900 ? C, respectively. During gasification, the generated gas has been captured in a cryo-trap, dried and the carbon containing gas components have been catalytically oxidized to CO2. Thereafter, the generated CO2 has been analyzed with respect to its stable carbon isotope composition by mass spectrometry. All samples exhibited a similar trend: The ^13C signatures of initially produced CO2 revealed to be relatively light and linearly increasing with temperature until approaching the bulk stable carbon isotope composition of the coal at a certain temperature, where the isotope signature kept virtually constant during further temperature increase. The temperature introducing the range of constant isotope compositions of the produced gas increased with coal rank. Additionally, all coal samples were treated by Rock Eval pyrolysis up to 550 ? C in order to investigate temperature dependent generation of CO and CO2. The results exhibited a linear decrease of the CO2/CO ratio at increasing temperature. Both experimental approaches demonstrated dependencies between the qualitative and the isotope composition of the generated syngas on the one hand and the applied combustion temperature on the other hand and, consequently, the principal applicability of the considered geochemical parameters as temperature proxies for coals of significantly different rank and origin. Although the investigated samples revealed similar trends, the absolute characteristics of the correlation functions (e.g. linear gradients) between geochemical parameters and combustion temperatures differed on an individual sample base, implying a significant additional dependence of the considered geochemical parameters on the coal composition. As a consequence, corresponding experimental approaches are currently continued and refined by involving multi component compound specific isotope analysis, high temperature Rock Eval pyrolysis as well as an enforced consideration of initial coal and oxidant compositions.

  13. Carbon formation and metal dusting in advanced coal gasification processes

    SciTech Connect

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  14. Scale-up research in a dual fluidized bed gasification process.

    PubMed

    Narobe, Miha; Golob, Janvit; Mele, Jernej; Sekav?nik, Mihael; Senega?nik, Andrej; Klinar, Duan

    2015-01-01

    A successful co-gasification of plastics and biomass was achieved on the 100 kW dual fluidized bed (DFB) gasification pilot plant. The results of a pilot plant experiment were used as a sound basis for scale-up prediction to 750 kW semi-industrial DFB plant. By an eightfold increase of mass and heat flows a rather simplified co-gasification process was predicted. Namely, the losses occurring in gasification plants are expected to be relatively smaller in larger plants. The effect of decreased losses was studied with an equilibrium model. Three different situations were simulated with the following fixed values of losses: 70 kW, 115 kW and 160 kW. The model showed an increase in fuel conversion when losses were reduced. PMID:26085423

  15. Low/medium Btu coal-gasification assessment program for potential users in New Jersey. Final report

    SciTech Connect

    Bianco, J.; Schavlan, S.; Ku, W. S.; Piascik, T. M.; Hynds, J. A.; West, A.

    1981-01-01

    In order to evaluate the potential for coal utilization, a preliminary technical and economic assessment of district coal gasification in New Jersey was conducted. This evaluation addressed the possibility of installing a coal gasification plant to use a high sulfur eastern coal to produce a medium Btu content gas (MBG) having a heating value of approximately 300 Btu/SCF. In addition, the work also appraised the regulatory, environmental and marketing, and financial considerations of such a facility. The preliminary study evaluation has manifested an overall technical and economic feasibility for producing a medium Btu quality gas (MBG) from coal at PSE and G's Sewaren Generating Station in New Jersey. The production of MBG for use in on-site power plant boilers or for distribution to industrial customers appears to be economically attractive. The economic attractiveness of MBG is very dependent on the location of sufficient numbers of industrial customers near the gasification facilities and on high utilization of the gasification plant. The Sewaren Generating Station was identified as potentially the most suitable site for a gasification plant. The Texaco Coal Gasification Process was selected as the gasifier type due to a combination of efficiency and pilot plant experience. It is projected that a nominal 2000 tons-per-day coal gasification plant would supply supplemental utility boiler fuel, fuel grade methanol and some by-products.

  16. Fundamental research on novel process alternatives for coal gasification: Final report

    SciTech Connect

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  17. Fluidized bed gasification ash reduction and removal process

    DOEpatents

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  18. Low-temperature catalytic gasification of food processing wastes. 1995 topical report

    SciTech Connect

    Elliott, D.C.; Hart, T.R.

    1996-08-01

    The catalytic gasification system described in this report has undergone continuing development and refining work at Pacific Northwest National Laboratory (PNNL) for over 16 years. The original experiments, performed for the Gas Research Institute, were aimed at developing kinetics information for steam gasification of biomass in the presence of catalysts. From the fundamental research evolved the concept of a pressurized, catalytic gasification system for converting wet biomass feedstocks to fuel gas. Extensive batch reactor testing and limited continuous stirred-tank reactor tests provided useful design information for evaluating the preliminary economics of the process. This report is a follow-on to previous interim reports which reviewed the results of the studies conducted with batch and continuous-feed reactor systems from 1989 to 1994, including much work with food processing wastes. The discussion here provides details of experiments on food processing waste feedstock materials, exclusively, that were conducted in batch and continuous- flow reactors.

  19. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect

    Ness, R.O. Jr.; Aulich, T.R.

    1990-10-01

    The primary objective of the EERC/AMAX Mild Gasification project is to commercialize a process that will produce several value-added products from a high-sulfur midwestern bituminous or a low-sulfur subbituminous coal. Indiana No. 3 and Wyodak coals are being tested in a 100-lb/hr process development unit (PDU) that has undergone shakedown testing and is undergoing parametric testing. This unit will provide the engineering data for use in determining the technical and economic data required for the design of a commercial-scale mild gasification plant. This report discusses results of carbonizer tests, char upgrading and char separations. 12 figs., 16 tabs.

  20. Thermodynamic analysis of the process of formation of sulfur compounds in oxygen gasification of coal

    SciTech Connect

    G.Ya. Gerasimov; T.M. Bogacheva

    2001-05-15

    A thermodynamic approach to the description of the behavior of the system fuel-oxidizer in oxygen gasification of coal is used to reveal the main mechanisms of the process of capture of sulfur by the mineral part of the coal and to determine the fundamental possibility of the process for coals from different coal fields.

  1. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect

    Wolfe, R.A.; Wright, R.E.; Im, C.J.; Henkelman, M.R.; O`Neal, G.W.

    1992-11-01

    The objective of this project is to develop a continuous mild gasification process to convert highly caking coals to coal liquids, char and coke for near term commercial application. Task 3, Bench-Scale Char Upgrading Study, has been underway since September 1989. In char upgrading studies, ``green`` uncured char briquettes have been prepared and calcined in 20-pound batches to evaluate the effects of char, binders, and heating conditions on final coke properties. A total of 150. formulations have been tested thus far in this work. Work on Task 4, Process Development Unit (PDU) Mild Gasification Study, has been in progress since February 1991, with the completion of a Continuous Mild Gasification Unit (CMGU) with a design rate of 1000 lb./hr. Since start-up of the CMGU, there have been 72 runs with a variety of operating conditions and coal types.

  2. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. ); Duthie, R.G. ); Wootten, J.M. )

    1991-09-01

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  3. Scaleup of mild gasification to a process development unit. [MILDGAS Process

    SciTech Connect

    Campbell, J.A.L.; Carty, R.H.; Saladin, N.; Mead, J.; Foster, H.

    1992-01-01

    The overall objectives of this project is to develop the IGT Mild-Gasification (MILDGAS) process for near-term commercialization. The specific objectives of the program are to: design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scaleup obtain large batches of coal-derived co-products for industrial evaluation prepare a detailed design of a demonstration unit develop technical and economic plans for commercialization of the MILDGAS process. During the first ten months of this project. the NEPA Application for construction and operation of the PDU facility at the SIUC site was written and submitted for approval. In addition, the process design for the PDU was completed, bid packages for the PDU modules were prepared and sent to a slate of prospective bidders, and bids were received from the participating bidders.

  4. Development of an advanced continuous mild gasification process for the production of coproducts

    SciTech Connect

    Merriam, N.W.; Cha, C.Y.; Kang, T.W.; Vaillancourt, M.B.

    1990-12-01

    Western Research Institute (WRI) teamed with the AMAX Research and Development Center and Riley Stoker Corporation on Development of an Advanced, Continuous Mild-Gasification Process for the Production of Coproducts under contract DE-AC21-87MC24268 with the Morgantown Energy Technology of the US Department of Energy. The strategy for this project is to produce electrode binder pitch and diesel fuel blending stock by mild gasification of Wyodak coal. The char is upgraded to produce anode-grade carbon, carbon black, and activated carbon. This report describes results of mild-gasification tests conducted by WRI. Char upgrading tests conducted by AMAX will be described in a separate report.

  5. Mathematical Modeling of Coal Gasification Processes in a Well-Stirred Reactor: Effects of Devolatilization and Moisture Content

    E-print Network

    Qiao, Li

    Mathematical Modeling of Coal Gasification Processes in a Well- Stirred Reactor: Effects in coal and biomass play an important role on the gasification performance of these fuels on the syngas composition. The coal conversion time is most sensitive to the heat transfer rates including both

  6. CHEMICALLY ACTIVE FLUID BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF CARBONACEOUS FUELS

    EPA Science Inventory

    The report covers the final 3 years of a 9-year program to evaluate the Chemically Active Fluid Bed (CAFB) process for gasification and desulfurization of liquid and solid fuels in a fluidized bed of hot lime. A range of alternative fuels, including three coals and a lignite, wer...

  7. Considerations on coal gasification

    NASA Technical Reports Server (NTRS)

    Franzen, J. E.

    1978-01-01

    Commercial processes for the gasification of coal with oxygen are discussed. The Koppers-Totzek process for the gasification of coal dust entrained in a stream of gasifying agents is described in particular detail. The outlook for future applications of coal gasification is presented.

  8. Development of an advanced, continuous mild gasification process for the production of co-products (Tasks 2, 3, and 4. 1 to 4. 6), Volume 2

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. ); Duthie, R.G. ); Wootten, J.M. )

    1991-09-01

    Volume 2 contains information on the following topics: (1) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (2) Bench-Scale Char Upgrading Study; (3) Mild Gasification Technology Development: System Integration Studies. (VC)

  9. Process and technological aspects of municipal solid waste gasification. A review

    SciTech Connect

    Arena, Umberto

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Critical assessment of the main commercially available MSW gasifiers. Black-Right-Pointing-Pointer Detailed discussion of the basic features of gasification process. Black-Right-Pointing-Pointer Description of configurations of gasification-based waste-to-energy units. Black-Right-Pointing-Pointer Environmental performance analysis, on the basis of independent sources data. - Abstract: The paper proposes a critical assessment of municipal solid waste gasification today, starting from basic aspects of the process (process types and steps, operating and performance parameters) and arriving to a comparative analysis of the reactors (fixed bed, fluidized bed, entrained bed, vertical shaft, moving grate furnace, rotary kiln, plasma reactor) as well as of the possible plant configurations (heat gasifier and power gasifier) and the environmental performances of the main commercially available gasifiers for municipal solid wastes. The analysis indicates that gasification is a technically viable option for the solid waste conversion, including residual waste from separate collection of municipal solid waste. It is able to meet existing emission limits and can have a remarkable effect on reduction of landfill disposal option.

  10. A new gasification and melting incineration process of MSW with co-current shaft furnace.

    PubMed

    Zhao, Wei; Wang, Qi; Zou, Zongshu; Liu, Haixiao; Zheng, Hongxia; Zhang, Lei

    2009-01-01

    In all the municipal solid waste (MSW) disposal technology, incineration with gasification and melting has been taken as a environmentally sound and zero emission technology owing to avoiding second-pollution of heavy metals and dioxin. In this background, a new direct gasification and melting incineration process with co-current shaft furnace is put forward. In this process, MSW and combustion-supporting air are co-current from top to bottom in a shaft furnace. Fuel gas from pyrolysis and gasification burns completely in the bottom in order to offer energy for slag melting. The simulation experiment of the co-current shaft furnace has been done. The results of simulation experiment show that the temperature on the condition of co-current is much higher than on the condition of countercurrent at the bottom of reaction tube and so is the CO2 quantity discharged from reaction tube. It can be concluded that the co-current shaft furnace is more suitable for direct gasification and melting incineration process. PMID:25084404

  11. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOEpatents

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  12. Raw material recycling of biomass with the VEBA OEL pyrolysis and gasification processes

    SciTech Connect

    Redepenning, K.H.

    1994-12-31

    From the early days of the VEBA OEL refineries originate the upgrading processes for liquid and pasty refinery residues. For treatment of residues or biomass these processes have a special importance because in comparison to combustion they are characterised by low pollutant loads and efficient energy conversion as well as high reliability when handling difficult residues. These processes are: 1. Pyrolysis of particularly heterogenous materials, such as biomass or composting residues. 2. Gasification or inertising of inorganic component, alternatively in conjunction with pyrolysis arranged upstream as a thermal pretreatment. A special feature of these processes with environmental policy relevance is the possibility of the raw material utilisation of the synthesis gases in the chemical or refinery industries. If due to the selection of location, raw material utilisation is not applicable, however, the conversion of the synthesis gases into electricity in a combined cycle unit is possible. What is significant in the process path pyrolysis, gasification and cogeneration is the high electric efficiency achievable. The high efficiency of pyrolysis and gasification is based on the conversion of the residues or biomass into high-energy intermediate products and linking with a co-generation process. In the first step, intermediate products are obtained by means of pyrolysis with condensation of the low-temperature carbonisation vapours which are characterised by their storability and grindability. In the second process step the intermediate pyrolysis products are fed to an entrained flow gasification unit operated at a pressure of approx. 20-23 {times} 10{sup 5} Pa which makes it possible to vitrify the inorganic constituents to form a slag difficult to elute and to obtain synthesis gases particularly low in noxious matter. In the final step the gases present under pressure can be passed on to the gas turbines of a progressive cogeneration gas turbine power station.

  13. Process and technological aspects of municipal solid waste gasification. A review.

    PubMed

    Arena, Umberto

    2012-04-01

    The paper proposes a critical assessment of municipal solid waste gasification today, starting from basic aspects of the process (process types and steps, operating and performance parameters) and arriving to a comparative analysis of the reactors (fixed bed, fluidized bed, entrained bed, vertical shaft, moving grate furnace, rotary kiln, plasma reactor) as well as of the possible plant configurations (heat gasifier and power gasifier) and the environmental performances of the main commercially available gasifiers for municipal solid wastes. The analysis indicates that gasification is a technically viable option for the solid waste conversion, including residual waste from separate collection of municipal solid waste. It is able to meet existing emission limits and can have a remarkable effect on reduction of landfill disposal option. PMID:22035903

  14. Gasoline from coal in the state of Illinois: feasibility study. Volume I. Design. [KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process

    SciTech Connect

    Not Available

    1980-01-01

    Volume 1 describes the proposed plant: KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process, and also with ancillary processes, such as oxygen plant, shift process, RECTISOL purification process, sulfur recovery equipment and pollution control equipment. Numerous engineering diagrams are included. (LTN)

  15. Process for gasification using a synthetic CO.sub.2 acceptor

    DOEpatents

    Lancet, Michael S. (Pittsburgh, PA); Curran, George P. (Pittsburgh, PA)

    1980-01-01

    A gasification process is disclosed using a synthetic CO.sub.2 acceptor consisting essentially of at least one compound selected from the group consisting of calcium oxide and calcium carbonate supported in a refractory carrier matrix, the carrier having the general formula Ca.sub.5 (SiO.sub.4).sub.2 CO.sub.3. A method for producing the synthetic CO.sub.2 acceptor is also disclosed.

  16. Performance analysis of RDF gasification in a two stage fluidized bed-plasma process.

    PubMed

    Materazzi, M; Lettieri, P; Taylor, R; Chapman, C

    2016-01-01

    The major technical problems faced by stand-alone fluidized bed gasifiers (FBG) for waste-to gas applications are intrinsically related to the composition and physical properties of waste materials, such as RDF. The high quantity of ash and volatile material in RDF can provide a decrease in thermal output, create high ash clinkering, and increase emission of tars and CO2, thus affecting the operability for clean syngas generation at industrial scale. By contrast, a two-stage process which separates primary gasification and selective tar and ash conversion would be inherently more forgiving and stable. This can be achieved with the use of a separate plasma converter, which has been successfully used in conjunction with conventional thermal treatment units, for the ability to 'polish' the producer gas by organic contaminants and collect the inorganic fraction in a molten (and inert) state. This research focused on the performance analysis of a two-stage fluid bed gasification-plasma process to transform solid waste into clean syngas. Thermodynamic assessment using the two-stage equilibrium method was carried out to determine optimum conditions for the gasification of RDF and to understand the limitations and influence of the second stage on the process performance (gas heating value, cold gas efficiency, carbon conversion efficiency), along with other parameters. Comparison with a different thermal refining stage, i.e. thermal cracking (via partial oxidation) was also performed. The analysis is supported by experimental data from a pilot plant. PMID:26184896

  17. Fluid bed gasification Plasma converter process generating energy from solid waste: Experimental assessment of sulphur species

    SciTech Connect

    Morrin, Shane; Lettieri, Paola; Chapman, Chris; Taylor, Richard

    2014-01-15

    Highlights: We investigate gaseous sulphur species whilst gasifying sulphur-enriched wood pellets. Experiments performed using a two stage fluid bed gasifier plasma converter process. Notable SO{sub 2} and relatively low COS levels were identified. Oxygen-rich regions of the bed are believed to facilitate SO{sub 2}, with a delayed release. Gas phase reducing regions above the bed would facilitate more prompt COS generation. - Abstract: Often perceived as a Cinderella material, there is growing appreciation for solid waste as a renewable content thermal process feed. Nonetheless, research on solid waste gasification and sulphur mechanisms in particular is lacking. This paper presents results from two related experiments on a novel two stage gasification process, at demonstration scale, using a sulphur-enriched wood pellet feed. Notable SO{sub 2} and relatively low COS levels (before gas cleaning) were interesting features of the trials, and not normally expected under reducing gasification conditions. Analysis suggests that localised oxygen rich regions within the fluid bed played a role in SO{sub 2}s generation. The response of COS to sulphur in the feed was quite prompt, whereas SO{sub 2} was more delayed. It is proposed that the bed material sequestered sulphur from the feed, later aiding SO{sub 2} generation. The more reducing gas phase regions above the bed would have facilitated COS hence its faster response. These results provide a useful insight, with further analysis on a suite of performed experiments underway, along with thermodynamic modelling.

  18. Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char

    SciTech Connect

    Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao

    2008-11-15

    In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

  19. Hydrogen production by gasification of municipal solid waste

    SciTech Connect

    Rogers, R. III

    1994-05-20

    As fossil fuel reserves run lower and lower, and as their continued widespread use leads toward numerous environmental problems, the need for clean and sustainable energy alternatives becomes ever clearer. Hydrogen fuel holds promise as such as energy source, as it burns cleanly and can be extracted from a number of renewable materials such as municipal solid waste (MSW), which can be considered largely renewable because of its high content of paper and biomass-derived products. A computer model is being developed using ASPEN Plus flow sheeting software to simulate a process which produces hydrogen gas from MSW; the model will later be used in studying the economics of this process and is based on an actual Texaco coal gasification plant design. This paper gives an overview of the complete MSW gasification process, and describes in detail the way in which MSW is modeled by the computer as a process material. In addition, details of the gasifier unit model are described; in this unit modified MSW reacts under pressure with oxygen and steam to form a mixture of gases which include hydrogen.

  20. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect

    Rizzo, Jeffrey J.

    2010-04-30

    The Wabash gasification facility, owned and operated by sgSolutions LLC, is one of the largest single train solid fuel gasification facilities in the world capable of transforming 2,000 tons per day of petroleum coke or 2,600 tons per day of bituminous coal into synthetic gas for electrical power generation. The Wabash plant utilizes Phillips66 proprietary E-Gas (TM) Gasification Process to convert solid fuels such as petroleum coke or coal into synthetic gas that is fed to a combined cycle combustion turbine power generation facility. During plant startup in 1995, reliability issues were realized in the gas filtration portion of the gasification process. To address these issues, a slipstream test unit was constructed at the Wabash facility to test various filter designs, materials and process conditions for potential reliability improvement. The char filtration slipstream unit provided a way of testing new materials, maintenance procedures, and process changes without the risk of stopping commercial production in the facility. It also greatly reduced maintenance expenditures associated with full scale testing in the commercial plant. This char filtration slipstream unit was installed with assistance from the United States Department of Energy (built under DOE Contract No. DE-FC26-97FT34158) and began initial testing in November of 1997. It has proven to be extremely beneficial in the advancement of the E-Gas (TM) char removal technology by accurately predicting filter behavior and potential failure mechanisms that would occur in the commercial process. After completing four (4) years of testing various filter types and configurations on numerous gasification feed stocks, a decision was made to investigate the economic and reliability effects of using a particulate removal gas cyclone upstream of the current gas filtration unit. A paper study had indicated that there was a real potential to lower both installed capital and operating costs by implementing a char cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  1. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-06-01

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. The technical and economic performances of the selected processes were evaluated using computer models and available literature. Using these results, the carbon sequestration potential of the three technologies was then evaluated. The results of these evaluations are given in this final report.

  2. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-04-01

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. During this reporting period, the technical and economic performances of the selected processes were evaluated using computer models and available literature. The results of these evaluations are summarized in this report.

  3. Low/medium-Btu coal-gasification assessment program for specific sites of two New York utilities

    SciTech Connect

    Not Available

    1980-12-01

    The scope of this study is to investigate the technical and economic aspects of coal gasification to supply low- or medium-Btu gas to the two power plant boilers selected for study. This includes the following major studies (and others described in the text): investigate coals from different regions of the country, select a coal based on its availability, mode of transportation and delivered cost to each power plant site; investigate the effects of burning low- and medium-Btu gas in the selected power plant boilers based on efficiency, rating and cost of modifications and make recommendations for each; and review the technical feasibility of converting the power plant boilers to coal-derived gas. The following two coal gasification processes have been used as the basis for this Study: the Combustion Engineering coal gasification process produces a low-Btu gas at approximately 100 Btu/scf at near atmospheric pressure; and the Texaco coal gasification process produces a medium-Btu gas at 292 Btu/scf at 800 psig. The engineering design and economics of both plants are described. Both plants meet the federal, state, and local environmental requirements for air quality, wastewater, liquid disposal, and ground level disposal of byproduct solids. All of the synthetic gas alternatives result in bus bar cost savings on a yearly basis within a few years of start-up because the cost of gas is assumed to escalate at a lower rate than that of fuel oil, approximately 4 to 5%.

  4. Molten salt coal gasification process development unit. Phase 1. Volume 2. Commercial plant study. Final report

    SciTech Connect

    Kohl, Arthur L.

    1980-05-01

    This report summarizes the results of a test program conducted on the Molten Salt Coal Gasification Process, which included the design, construction, and operation of a Process Development Unit (PDU). This process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for regeneration of the salt. The process can handle a wide variety of feed materials, including highly caking coals, and produces a gas relatively free from tars and other impurities. The gasification step is carried out at approximately 1800/sup 0/F. The PDU was designed to process 1 ton per hour of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur and ash in forms suitable for disposal. Five extended test runs were made. The observed product gas composition was quite close to that predicted on the basis of earlier small-scale tests and thermodynamic considerations. All plant systems were operated in an integrated manner. Test data and discussions regarding plant equipment and process performance are presented. The program also included a commercial plant study which showed the process to be attractive for use in a combined cycle, electric power plant. The report is presented in two volumes, Volume 1, PDU Operations, and Volume 2, Commercial Plant Study.

  5. Development of biological coal gasification (MicGAS Process)

    SciTech Connect

    Not Available

    1992-04-30

    In order for the coal biogasification process to be economically feasible, an inexpensive nutrient amendment must be found to replace the Difco[trademark] yeast extract and tryptic soy broth (YE/TSB) used in the current medium formulation. Five products have been identified which support greater methane production from Texas lignite than YE/TSB.

  6. Development of biological coal gasification (MicGAS process)

    SciTech Connect

    Not Available

    1992-10-30

    Laboratory scale studies examining biogasification of Texas lignite at various coal solids loadings have been completed. Bench scale bioreactors are currently being used to scale up the biogasification process to higher coal solids loadings (5% and 10%) Specific observations reported this quarter are that methane production was not curtailed when B-vitamin solution was not added to the biogasification medium and that aeration of Mic-1 did not sufficiently oxidize the medium to eliminate strict anaerobic bacteria including methanogens.

  7. Bi-flow rotary kiln coal gasification process

    SciTech Connect

    Garside, P.G.

    1983-02-22

    A process is disclosed for gasifying solid coal particles in a rotary kiln that produces simultaneously and continuously two distinctly different fuel gas streams from the opposite ends of a single kiln. A relatively low temperature gas is discharged from the solids inlet end of the kiln, which contains substantially all tars produced by the process. A second of the gas streams is discharged from the solids discharge end of the kiln at approximately 1,900* F. And substantially tar-free. Heat is recovered from this tar-free gas after only a simple cleaning of particulate matter, as may be provided by a cyclone separator. The discharge of gas out the solids inlet end of the kiln and the gas discharged out the solids discharge end of the kiln, is adjustably proportioned relative to each other so that at least some high temperature tar-free gas will mix inside the kiln with the lower temperature tar-containing gas, in an amount sufficient to keep such mixed gases at a temperature high enough to avoid the tars condensing on equipment surfaces. Several process parameters are disclosed for adjusting the proportion of the gas flows out each end of the kiln to maintain the aforesaid condition of both gas streams.

  8. Development of biological coal gasification (MicGAS Process)

    SciTech Connect

    Walia, D.S.; Srivastava, K.C.

    1994-10-01

    The overall goal of the project is to develop an advanced, clean coal biogasification (MicGAS) Process. The objectives of the research during FY 1993--94 were to: (1) enhance kinetics of methane production (biogasification, biomethanation) from Texas lignite (TxL) by the Mic-1 consortium isolated and developed at ARCTECH, (2) increase coal solids loading, (3) optimize medium composition, and (4) reduce retention time. A closer analysis of the results described here indicate that biomethanation of TxL at >5% solids loading is feasible through appropriate development of nutrient medium and further adaptation of the microorganisms involved in this process. Further understanding of the inhibitory factors and some biochemical manipulations to overcome those inhibitions will hasten the process considerably. Results are discussed on the following: products of biomethanation and enhance of methane production including: bacterial adaptation; effect of nutrient amendment substitutes; effects of solids loading; effect of initial pH of the culture medium; effect of hydrogen donors and carbon balance.

  9. Evaluating the status of the Texaco gasifier

    SciTech Connect

    Perry, H.

    1981-01-01

    Conclusions after a series of runs at steady state conditions in the pilot plant are: (1) Western Kentucky No. 9 coal (either run-of-mine or washed) can be gasified without pretreatment; (2) other coking bituminous coal may also be able to be gasified without pretreatment; (3) pretreatment is not required to achieve satisfactory ash agglomeration; (4) balanced ash agglomeration with satisfactory removal of the agglomerates has been achieved and stable operation of ash agglomeration is possible during periods of short upset; (5) solutions appear to have been found for prevention of clinkering and sintering by alternative venturi design, modification in the oxygen feed system and increasing the superficial velocity of the gas; (6) under certain circumstances fines recycle has been achieved with stable operation and fluidization; (7) the process can be operated at pressures up to 60 psig without adversely affecting other process parameters; (8) a wide range of operating conditions can be used while maintaining system operability; and (9) in a single test water cooling of the cyclone appears to prevent ash deposition on the cooled surfaces which confirms the experience of Westinghouse with ash deposition prevention in their fluidized bed gasifier. 11 references, 12 tables.

  10. Gasification. 2nd. ed.

    SciTech Connect

    Christopher Higman; Maarten van der Burgt

    2008-02-15

    This book covers gasification as a comprehensive topic, covering its many uses, from refining, to natural gas, to coal. It provides an overview of commercial processes and covers applications relevant to today's demands. The new edition is expanded and provides more detail on the integration issues for current generation, state-of-the-art Integrated Gasification Combined Cycles (IGCC); CO{sub 2} capture in the IGCC context addressing the issues of pre-investment and retrofitting as well as defining what the term 'CO{sub 2} capture ready' might mean in practice; issues of plant reliability, availability and maintainability (RAM) including as evaluation of feedback from existing plants; implementation of fuel cell technology in IGCC concepts. Contents are: Introduction; The Thermodynamics of Gasification; The Kinetics of Gasification and Reactor Theory; Feedstocks and Feedstock Characteristics; Gasification Processes; Practical Issues; Applications; Auxiliary Technologies; Economics, environmental, and Safety Issues; Gasification and the Future. 5 apps.

  11. Coal gasification systems engineering and analysis. Appendix G: Commercial design and technology evaluation

    NASA Technical Reports Server (NTRS)

    1980-01-01

    A technology evaluation of five coal gasifier systems (Koppers-Totzek, Texaco, Babcock and Wilcox, Lurgi and BGC/Lurgi) and procedures and criteria for evaluating competitive commercial coal gasification designs is presented. The technology evaluation is based upon the plant designs and cost estimates developed by the BDM-Mittelhauser team.

  12. Selecting the process arrangement for preparing the gas turbine working fluid for an integrated gasification combined-cycle power plant

    NASA Astrophysics Data System (ADS)

    Ryzhkov, A. F.; Gordeev, S. I.; Bogatova, T. F.

    2015-11-01

    Introduction of a combined-cycle technology based on fuel gasification integrated in the process cycle (commonly known as integrated gasification combined cycle technology) is among avenues of development activities aimed at achieving more efficient operation of coal-fired power units at thermal power plants. The introduction of this technology is presently facing the following difficulties: IGCC installations are characterized by high capital intensity, low energy efficiency, and insufficient reliability and availability indicators. It was revealed from an analysis of literature sources that these drawbacks are typical for the gas turbine working fluid preparation system, the main component of which is a gasification plant. Different methods for improving the gasification plant chemical efficiency were compared, including blast air high-temperature heating, use of industrial oxygen, and a combination of these two methods implying limited use of oxygen and moderate heating of blast air. Calculated investigations aimed at estimating the influence of methods for achieving more efficient air gasification are carried out taking as an example the gasifier produced by the Mitsubishi Heavy Industries (MHI) with a thermal capacity of 500 MW. The investigation procedure was verified against the known experimental data. Modes have been determined in which the use of high-temperature heating of blast air for gasification and cycle air upstream of the gas turbine combustion chamber makes it possible to increase the working fluid preparation system efficiency to a level exceeding the efficiency of the oxygen process performed according to the Shell technology. For the gasification plant's configuration and the GTU working fluid preparation system be selected on a well-grounded basis, this work should be supplemented with technical-economic calculations.

  13. Gasification system

    DOEpatents

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1985-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  14. Gasification system

    DOEpatents

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1983-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  15. High Temperature Electrochemical Polishing of H(2)S from Coal Gasification Process Streams.

    SciTech Connect

    Winnick, J.

    1997-12-31

    An advanced process for the separation of hydrogen sulfide from coal gasification streams through an electrochemical membrane is being perfected. H{sub 2}S is removed from a synthetic gas stream, split into hydrogen, which enriches the exiting syngas, and sulfur, which is condensed downstream from an inert sweep gas stream. The process allows for continuous removal of H{sub 2}S without cooling the gas stream while allowing negligible pressure loss through the separator. Moreover, the process is economically attractive due to the elimination of the need for a Claus process for sulfur recovery. To this extent the project presents a novel concept for improving utilization of coal for more efficient power generation.

  16. Gasification of Woody Biomass.

    PubMed

    Dai, Jianjun; Saayman, Jean; Grace, John R; Ellis, Naoko

    2015-07-24

    Interest in biomass to produce heat, power, liquid fuels, hydrogen, and value-added chemicals with reduced greenhouse gas emissions is increasing worldwide. Gasification is becoming a promising technology for biomass utilization with a positive environmental impact. This review focuses speci-fically on woody biomass gasification and recent advances in the field. The physical properties, chemical structure, and composition of biomass greatly affect gasification performance, pretreatment, and handling. Primary and secondary catalysts are of key importance to improve the conversion and cracking of tars, and lime-enhanced gasification advantageously combines CO2 capture with gasification. These topics are covered here, including the reaction mechanisms and biomass characterization. Experimental research and industrial experience are investigated to elucidate concepts, processes, and characteristics of woody biomass gasification and to identify challenges. PMID:26247289

  17. Test summary and detailed test plan for Mild Gasification Process Unit

    SciTech Connect

    Not Available

    1992-01-01

    The objectives of this task are: (1) to shake down the DOE's Mild Gasification Process Unit (PU) constructed in Task 4, and (2) to perform tests to determine the effect of operating conditions (temperature, residence time, particle size, sweep gas, solid additive, and feedstock) on the unit operability and products quality, quantity and characteristics. Figure 1 depicts the reactor and salient features of the Mild Gasification process. Sized coal is transferred from a coal hopper to the volumetric coal bins by a flexible screw conveyor. The coal bins are vacuum sealed after they are filled to a predetermined level. Coal is then fed, by gravity, to the reactor tubes where it undergoes devolatilization for 3 to 5 hours. Reactor tubes are designed to operate at atmospheric pressures and temperatures of up to 13OO[degrees]F. The evolved gases from each reactor is led through a gas exit pipe to a condenser system. Each condenser system includes four water cooled condensers which separate the liquid products into four fractions. The condensate from each condenser is collected intermittently in a product pot. The non-condensable gases leaving the condenser systems are then combined, passed through provides a small negative pressure which facilitate withdrawal of evolved gases from the reactor tubes. Provisions are also made for addition of sweep gases to the reactors. Twenty four tests are planned to determine the effects of feedstock, temperature, solid residence time, particle size, solid additive, and sweep gas.

  18. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - THIRD PHASE

    EPA Science Inventory

    The report describes the third phase of studies on the CAFB process for desulfurization/gasification of heavy fuel oil in a bed of hot lime. Major conclusions relating to process performance and operability are: (1) water, either in the fuel or in the fluidizing air, has a strong...

  19. Molten salt coal gasification process development unit. Phase 1. Volume 1. PDU operations. Final report

    SciTech Connect

    Kohl, A.L.

    1980-05-01

    This report summarizes the results of a test program conducted on the Molten Salt Coal Gasification Process, which included the design, construction, and operation of a Process Development Unit. In this process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for regeneration of sodium carbonate, removal of sulfur, and disposal of the ash. The process can handle a wide variety of feed materials, including highly caking coals, and produces a gas relatively free from tars and other impurities. The gasification step is carried out at approximately 1800/sup 0/F. The PDU was designed to process 1 ton per hour of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur and ash in forms suitable for disposal. Five extended test runs were made. The observed product gas composition was quite close to that predicted on the basis of earlier small-scale tests and thermodynamic considerations. All plant systems were operated in an integrated manner during one of the runs. The principal problem encountered during the five test runs was maintaining a continuous flow of melt from the gasifier to the quench tank. Test data and discussions regarding plant equipment and process performance are presented. The program also included a commercial plant study which showed the process to be attractive for use in a combined-cycle, electric power plant. The report is presented in two volumes, Volume 1, PDU Operations, and Volume 2, Commercial Plant Study.

  20. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1. Final report

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H.; Duthie, R.G.; Wootten, J.M.

    1991-09-01

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  1. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect

    Wright, R.E.; Wolfe, R.A.; Im, C.J.; Henkelman, M.R.; O`Neal, G.W.; McKinney, D.A.

    1993-12-31

    The objective of this project is to develop a continuous mild gasification process to convert highly caking coals to coal liquids, char and coke for near term commercial application. Coal liquids after fractionation can be blended with petroleum and used interchangeably with conventional fuels without modifications in gasoline and diesel engines. Char can be used as a carbon source in the production of ferroalloys and in mini-mills. Coke can be produced by upgrading char through briquetting and calcining and for use in the steel industry foundries and blast furnaces. In a step beyond the scope of the project, the plan is to finance, design and construct, in a partnership with others, a plant to produce coal liquid, char and coke in the initial range of 250,000 tons/year. In the Coal Technology Corporation CTC/CLC{reg_sign} Process, coal is continuously moved by interfolded twin screws through a heated retort in the absence of air. The residence time of the coal in the Continuous Mild Gasification Unit (CMGU) is in the range of 20--30 minutes. The coal is heated to controlled temperatures between 800{degree} and 1400{degree}F and is converted into char, condensible hydrocarbon liquids, small quantities of water, and non-condensible fuel gases. The coal derived fuel gases could supply all the required process heat, but for convenience, natural gas is used in the experimental unit. The process concept particularly suitable for highly caking coals which cannot be processed in fluidized bed or moving bed furnaces.

  2. Gasification: A Cornerstone Technology

    SciTech Connect

    Gary Stiegel

    2008-03-26

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  3. Gasification: A Cornerstone Technology

    ScienceCinema

    Gary Stiegel

    2010-01-08

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  4. Evaluation of gasification and novel thermal processes for the treatment of municipal solid waste

    SciTech Connect

    Niessen, W.R.; Marks, C.H.; Sommerlad, R.E.

    1996-08-01

    This report identifies seven developers whose gasification technologies can be used to treat the organic constituents of municipal solid waste: Energy Products of Idaho; TPS Termiska Processor AB; Proler International Corporation; Thermoselect Inc.; Battelle; Pedco Incorporated; and ThermoChem, Incorporated. Their processes recover heat directly, produce a fuel product, or produce a feedstock for chemical processes. The technologies are on the brink of commercial availability. This report evaluates, for each technology, several kinds of issues. Technical considerations were material balance, energy balance, plant thermal efficiency, and effect of feedstock contaminants. Environmental considerations were the regulatory context, and such things as composition, mass rate, and treatability of pollutants. Business issues were related to likelihood of commercialization. Finally, cost and economic issues such as capital and operating costs, and the refuse-derived fuel preparation and energy conversion costs, were considered. The final section of the report reviews and summarizes the information gathered during the study.

  5. Numerical simulation of the pyrolysis zone in a downdraft gasification process.

    PubMed

    Jaojaruek, K; Kumar, S

    2009-12-01

    Models of the gasification process are mostly based on lumped analysis with distinct zones of the process treated as one entity. The study presented here was conducted to develop a more useful model specifically for the pyrolysis zone of the reactor of a downdraft gasifier based on finite computation method. Applying principles of energy and mass conservation, governing equations formed were solved by implicit finite difference method on the node of 100 throughout the length of the considered pyrolysis range (20 cm). Heat transfer considered convection, conduction, and the influence of solid radiation components. Chemical kinetics concept was also adopted to simultaneously solve the temperature profile and feedstock consumption rate on the pyrolysis zone. The convergence criteria were set at 10(-6) and simulation used Fortran Power Station 4.0. Validation experiments were also conducted resulting in maximum deviation of 24 degrees C and 0.37 kg/h for temperature and feedstock feed rate, respectively. PMID:19631526

  6. Molten salt coal gasification process development unit. Phase 2. Final report

    SciTech Connect

    Kohl, A.L.; Slater, M.H.

    1982-04-01

    This report summarizes Phase 2 of the Molten Salt Coal Gasification program. In this process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate at a nominal temperature of 1800/sup 0/F. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for removal of sulfur, disposal of the ash, and regeneration of sodium carbonate. The process can handle a wide variety of feed materials, including highly caking coals, and produces an environmentally clean gas, relatively free of sulfur, tars, heavy hydrocarbons, and NO/sub x/. The PDU was designed to produce low-Btu gas while processing 1 TPH of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur as dry powdered sodium sulfate/sulfite salt and ash as a moist filter cake. During Phase I of the contract, the plant was designed and built and five test runs were made. Phase 2 was initiated for the purpose of demonstrating improved operation of the entire system over a range of gasifier pressures. Of primary interest was improving the reliability of melt overflow system and obtaining process data up to 20 atmospheres pressure. Four PDU runs, ranging in length from 83 to 170 hours of continuous gasifier operation, included operating periods at the design coal feed rate (1 TPH), design pressure (20 atm), and design ash concentration in the melt pool (20% ash). Excellent data were obtained on the gasification step which verified the model for predicting product gas composition. Performance data were also obtained on the ash removal, sulfur removal, and sodium carbonate regeneration systems of the PDU.

  7. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - SECOND PHASE

    EPA Science Inventory

    The report describes the second phase of studies on the CAFB process for desulfurizing gasification of heavy fuel oil in a bed of hot lime. The first continuous pilot plant test with U.S. limestone BCR 1691 experienced local stone sintering and severe production of sticky dust du...

  8. CHEMICALLY ACTIVE FLUID-BED PROCESS FOR SULPHUR REMOVAL DURING GASIFICATION OF HEAVY FUEL OIL - FOURTH PHASE

    EPA Science Inventory

    The report gives results of Phase 4 of a study on the CAFB process for gasification/desulfurization of liquid and solid fuels in a bed of hot lime. A new pilot unit was designed and constructed, incorporating such novel features as: a new fluidizing air distributor, high-flow/low...

  9. Process modeling and supply chain design for advanced biofuel production based on bio-oil gasification

    NASA Astrophysics Data System (ADS)

    Li, Qi

    As a potential substitute for petroleum-based fuel, second generation biofuels are playing an increasingly important role due to their economic, environmental, and social benefits. With the rapid development of biofuel industry, there has been an increasing literature on the techno-economic analysis and supply chain design for biofuel production based on a variety of production pathways. A recently proposed production pathway of advanced biofuel is to convert biomass to bio-oil at widely distributed small-scale fast pyrolysis plants, then gasify the bio-oil to syngas and upgrade the syngas to transportation fuels in centralized biorefinery. This thesis aims to investigate two types of assessments on this bio-oil gasification pathway: techno-economic analysis based on process modeling and literature data; supply chain design with a focus on optimal decisions for number of facilities to build, facility capacities and logistic decisions considering uncertainties. A detailed process modeling with corn stover as feedstock and liquid fuels as the final products is presented. Techno-economic analysis of the bio-oil gasification pathway is also discussed to assess the economic feasibility. Some preliminary results show a capital investment of 438 million dollar and minimum fuel selling price (MSP) of $5.6 per gallon of gasoline equivalent. The sensitivity analysis finds that MSP is most sensitive to internal rate of return (IRR), biomass feedstock cost, and fixed capital cost. A two-stage stochastic programming is formulated to solve the supply chain design problem considering uncertainties in biomass availability, technology advancement, and biofuel price. The first-stage makes the capital investment decisions including the locations and capacities of the decentralized fast pyrolysis plants and the centralized biorefinery while the second-stage determines the biomass and biofuel flows. The numerical results and case study illustrate that considering uncertainties can be pivotal in this supply chain design and optimization problem. Also, farmers' participation has a significant effect on the decision making process.

  10. Development of an advanced, continuous mild gasification process for the production of co-products (Tasks 2, 3, and 4.1 to 4.6), Volume 2. Final report

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H.; Duthie, R.G.; Wootten, J.M.

    1991-09-01

    Volume 2 contains information on the following topics: (1) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (2) Bench-Scale Char Upgrading Study; (3) Mild Gasification Technology Development: System Integration Studies. (VC)

  11. Brazing as a Means of Sealing Ceramic Membranes for use in Advanced Coal Gasification Processes

    SciTech Connect

    Weil, K. Scott; Hardy, John S.; Rice, Joseph P.; Kim, Jin Yong Y.

    2006-01-02

    Coal is potentially a very inexpensive source of clean hydrogen fuel for use in fuel cells, turbines, and various process applications. To realize its potential however, efficient, low-cost gas separation systems are needed to provide high purity oxygen to enhance the coal gasification reaction and to extract hydrogen from the resulting gas product stream. Several types of inorganic membranes are being developed for hydrogen or oxygen separation, including porous alumina, transition metal oxide perovskites, and zirconia. One of the key challenges in developing solid-state membrane based gas separation systems is in hermetically joining the membrane to the metallic body of the separation device. In an effort to begin addressing this issue, a new brazing concept has been developed, referred to as reactive air brazing. This paper discusses the details of this joining technique and illustrates its use in bonding a wide variety of materials, including alumina, lanthanum strontium cobalt ferrite, and yttria stabilized zirconia.

  12. Brazing as a Means of Sealing Ceramic Membranes for Use in Advanced Coal Gasification Processes

    SciTech Connect

    Weil, K. Scott; Hardy, John S.; Rice, Joseph P.; Kim, Jin Yong

    2006-01-31

    Coal is a potentially a very inexpensive source of clean hydrogen fuel for use in fuel cells, turbines, and various process applications. To realize its potential however, efficient, low-cost gas separation systems are needed to provide high purity oxygen to enhance the coal gasification reaction and to extract hydrogen from the resulting gas product stream. Several types of inorganic membranes are being developed for hydrogen or oxygen separation, including porous alumina, transition metal oxide perovskites, and zirconia. One of the key challenges in developing solid-state membrane based gas separation systems is in hermetically joining the membrane to the metallic body of the separation device. In an effort to begin addressing this issue, a new brazing concept has been developed, referred to as reactive air brazing. This paper discusses the details of this joining technique and illustrates its use in bonding a wide variety of materials, including alumina, lanthanum strontium cobalt ferrite, and yttria stabilized zirconia.

  13. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system: Topical report, Process analysis, FY 1983

    SciTech Connect

    1987-07-31

    KRW Energy Systems, Inc., is engaged in the continuing development of a pressurized, fluidized-bed gasification process at its Waltz Mill Site in Madison, Pennsylvania. The overall objective of the program is to demonstrate the viability of the KRW process for the environmentally-acceptable production of low- and medium-Btu fuel gas from a variety of fossilized carbonaceous feedstocks and industrial fuels. This report presents process analysis of the 24 ton-per-day Process Development Unit (PDU) operations and is a continuation of the process analysis work performed in 1980 and 1981. Included is work performed on PDU process data; gasification; char-ash separation; ash agglomeration; fines carryover, recycle, and consumption; deposit formation; materials; and environmental, health, and safety issues. 63 figs., 43 tabs.

  14. Hydrothermal gasification of waste biomass: process design and life cycle asessment.

    PubMed

    Luterbacher, Jeremy S; Frling, Morgan; Vogel, Frederic; Marchal, Franois; Tester, Jefferson W

    2009-03-01

    A process evaluation methodology is presented that incorporates flowsheet mass and energy balance modeling, heat and power integration, and life cycle assessment Environmental impacts are determined by characterizing and weighting (using CO2 equivalents, Eco-indicator 99, and Eco-scarcity) the flowsheet and inventory modeling results. The methodology is applied to a waste biomass to synthetic natural gas (SNG) conversion process involving a catalytic hydrothermal gasification step. Several scenarios are constructed for different Swiss biomass feedstocks and different scales depending on logistical choices: large-scale (155 MW(SNG)) and small-scale (5.2 MW(SNG)) scenarios for a manure feedstock and one scenario (35.6 MW(SNG))for a wood feedstock. Process modeling shows that 62% of the manure's lower heating value (LHV) is converted to SNG and 71% of wood's LHV is converted to SNG. Life cycle modeling shows that, for all processes, about 10% of fossil energy use is imbedded in the produced renewable SNG. Converting manure and replacing it, as a fertilizer, with the process mineral byproduct leads to reduced N20 emissions and an improved environmental performance such as global warming potential: -0.6 kg(CO2eq)/MJ(SNG) vs. -0.02 kg(CO2eq)/MJ(SNG) for wood scenarios. PMID:19350938

  15. Development of an advanced continuous mild gasification process for the production of coproducts: Task 4. 6, Technical and economic evaluation

    SciTech Connect

    Hogsett, R.F.; Jha, M.C.

    1991-12-01

    Morgantown Energy Technology Center (METC) of DOE has sponsored, and continues to sponsor, programs for the development of technology and market strategies which will lead to the commercialization of processes for the production of coproducts from mild gasification of coal. It has been recognized by DOE and industry that mild gasification is a promising technology with potential to economically convert coal into marketable products, thereby increasing domestic coal utilization. In this process, coal is devolatilized under non- oxidizing conditions at mild temperature (900--1100{degrees}F) and pressure (1--15psig). Condensation of the vapor will yield a liquid product that can be upgraded to a petroleum substitute, and the remaining gas can provide the fuel for the process. The residual char can be burned in a power plant. Thus, in a long-term national scenario, implementation of this process will result in significant decrease of imported oil and increase in coal utilization.

  16. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect

    Michael Schwartz

    2004-12-01

    This report describes the work performed, accomplishments and conclusion obtained from the project entitled ''Novel Composite Membranes for Hydrogen Separation in Gasification Processes in Vision 21 Energy Plants'' under the United States Department of Energy Contract DE-FC26-01NT40973. ITN Energy Systems was the prime contractor. Team members included: the Idaho National Engineering and Environmental Laboratory; Nexant Consulting; Argonne National Laboratory and Praxair. The objective of the program was to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The separation technology module is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner. The program developed and evaluated composite membranes and catalysts for hydrogen separation. Components of the monolithic modules were fabricated by plasma spray processing. The engineering and economic characteristics of the proposed Ion Conducting Ceramic Membrane (ICCM) approach, including system integration issues, were also assessed. This resulted in a comprehensive evaluation of the technical and economic feasibility of integration schemes of ICCM hydrogen separation technology within Vision 21 fossil fuel plants. Several results and conclusion were obtained during this program. In the area of materials synthesis, novel pyrochlore-based proton conductors were identified, synthesized and characterized. They exhibited conductivity as high as 0.03 S/cm at 900 C. Long-term stability under CO{sub 2} and H{sub 2} atmospheres was also demonstrated. In the area of membrane fabrication by plasma spray processing, the initial results showed that the pyrochlore materials could be processed in a spray torch. Although leak-tight membranes were obtained, cracking, most likely due to differences in thermal expansion, remained a problem. More modeling and experimental work can be used to solve this problem. Finally the techno-economic analyses showed that the ITN ICCM approach for separating H{sub 2} is comparable to conventional pressure swing adsorption (PSA) technology in efficiency and economics. Enhanced membrane flux and lower operating temperatures may make the ICCM approach superior to PSA.

  17. Evaluation of US coal performance in the shell coal gasification process (SCGP). Volume 1. Texas lignite. Final report

    SciTech Connect

    Heitz, W.L.; McCullough, G.R.; Gierman, H.; van Kessel, M.M.

    1984-02-01

    The Shell Coal Gasificaton Process was included in the EPRI evaluation of the more promising gasification technologies. This report evaluates the performance of Texas lignite in the SCGP. A companion report (RP2094-1) evaluates the performance of an Illinois No. 5 seam coal. Tests were conducted in the Shell Internationale Research Maatschappij B.V. Amsterdam laboratory process development unit (6 metric ton per day nominal throughput). Shell also has a 150 metric ton per day gasification process development unit at Deutsche Shell's Harburg Refinery, Federal Republic of Germany. These initial tests indicate that Texas lignite is as suitable for the Shell Coal Gasification Process as any bituminous coal previously tested and that only moderate conditions are required for gasification. Process variables included oxygen/MAF (moisture and ash free) coal ratios of 0.82 to 0.96 kg/kg, throughputs of 74 to 207 kg MAF coal/hr, and pressures of 2.1 to 2.8 MPa (1 MPa = 10 bar or 145 psia). Extensive environmental sampling programs were carried out with 50% of normal bleed water recycled to the process via an evaporating venturi. Carbon conversion was nearly complete (99+ %) at reactor outlet temperatures as low as 1250/sup 0/C; at a pressure of 2.1 MPa, a maximum thermal efficiency (76% of LHV-coal) was obtained at an oxygen/MAF coal ratio of 0.90 kg/kg. Process results were only marginally influenced by variations in coal throughput but an increase in pressure at constant throughput increased the cold gas efficiency by two percentage points to 78% of LHV coal (mainly through a reduction in heat loss). In a test on load-following characteristics of the process, the unit pressure remained constant and the flow of product gas responded within one minute to a stepwise change in coal feed rate.

  18. Chemical process modelling of Underground Coal Gasification (UCG) and evaluation of produced gas quality for end use

    NASA Astrophysics Data System (ADS)

    Korre, Anna; Andrianopoulos, Nondas; Durucan, Sevket

    2015-04-01

    Underground Coal Gasification (UCG) is an unconventional method for recovering energy from coal resources through in-situ thermo-chemical conversion to gas. In the core of the UCG lays the coal gasification process which involves the engineered injection of a blend of gasification agents into the coal resource and propagating its gasification. Athough UCG technology has been known for some time and considered a promising method for unconventional fossil fuel resources exploitation, there are limited modelling studies which achieve the necessary accuracy and realistic simulation of the processes involved. This paper uses the existing knowledge for surface gasifiers and investigates process designs which could be adapted to model UCG. Steady state simulations of syngas production were developed using the Advanced System for Process ENgineering (Aspen) Plus software. The Gibbs free energy minimisation method was used to simulate the different chemical reactor blocks which were combined using a FORTRAN code written. This approach facilitated the realistic simulation of the gasification process. A number of model configurations were developed to simulate different subsurface gasifier layouts considered for the exploitation of underground coal seams. The two gasifier layouts considered here are the linked vertical boreholes and the controlled retractable injection point (CRIP) methods. Different stages of the UCG process (i.e. initialisation, intermediate, end-phase) as well as the temperature level of the syngas collection point in each layout were found to be the two most decisive and distinctive parameters during the design of the optimal model configuration for each layout. Sensitivity analyses were conducted to investigate the significance of the operational parameters and the performance indicators used to evaluate the results. The operational parameters considered were the type of reagents injected (i.e. O2, N2, CO2, H2O), the ratio between the injected reagents and the feedstock quantity (i.e. coal), the pressure, the gasification and the combustion temperatures. The performance indicators included the composition and the energy content of the product gas as well as the carbon and energy efficiency achieved under each operational scenario. Different operational scenarios for every model configuration facilitated the cross-comparison among different configurations. The proximate and ultimate analysis data for the coal seams modelled were taken from a number of candidate UCG sites (Durucan et al., 2014) .The model findings were validated using the results of field trials reported in the literature. It was found that, increased gasification temperature leads to higher H2 and CO quantities in the product gas. Moreover, CH4 and CO2 concentrations increased as reaction pressure increased, while the CH4 quantity reached its highest value at the highest operational pressure, when combined with the lowest gasification temperature. The simulation models developed can be used to design and validate experimental UCG studies and offer significant advantages in terms of time and resource savings. As the UCG process consists of interrelated stages and a number of diverse phenomena, therefore, the gasification designs developed could act as the basis for an integrated UCG model tailored to the needs of a UCG pilot plant.

  19. Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?

    SciTech Connect

    Sulc, Jindrich; Stojdl, Jiri; Richter, Miroslav; Popelka, Jan; Svoboda, Karel; Smetana, Jiri; Vacek, Jiri; Skoblja, Siarhei; Buryan, Petr

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Comparison of one stage (co-current) and two stage gasification of wood pellets. Black-Right-Pointing-Pointer Original arrangement with grate-less reactor and upward moving bed of the pellets. Black-Right-Pointing-Pointer Two stage gasification leads to drastic reduction of tar content in gas. Black-Right-Pointing-Pointer One stage gasification produces gas with higher LHV at lower overall ER. Black-Right-Pointing-Pointer Content of ammonia in gas is lower in two stage moving bed gasification. - Abstract: A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW{sub th}. The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 Degree-Sign C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound contents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER = 0.71) led to substantial reduction of gas heating value (LHV = 3.15 MJ/Nm{sup 3}), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950 Degree-Sign C) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the second stage presented only few mass% of the inlet biomass stream.

  20. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOEpatents

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  1. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    SciTech Connect

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  2. Simulation and Life Cycle Assessment of Algae Gasification Process in Dual Fluidized Bed Gasifiers

    E-print Network

    Azadi, Pooya; Brownbridge, George; Mosbach, Sebastian; Inderwildi, Oliver; Kraft, Markus

    2015-01-01

    We present simulation results for the production of algae-derived syngas using dual fluidized bed (DFB) gasifiers. A global sensitivity analysis was performed to determine the impact of key input parameters (i.e. algae composition, gasification...

  3. Biodiesel production by supercritical process with crude bio-methanol prepared by wood gasification.

    PubMed

    Isayama, Yohei; Saka, Shiro

    2008-07-01

    In order to prepare a genuine biodiesel, it is essential to use methanol prepared from biomass but not natural gas for biodiesel production. Thus, we have proposed to use crude bio-methanol produced by wood gasification for biodiesel production. Since such a bio-methanol contains some impurities, an effect of its impurities was studied on the biodiesel production by supercritical method. In general, impurities in crude bio-methanol are reported to include methyl formate, ethanol, 1-butanol, diisopropyl ether, water, etc. Triglycerides and oleic acids were, thus, treated with these impurities under supercritical conditions. As a result, it was found that methyl formate, ethanol and 1-butanol could convert them to fatty acid alkyl esters (BDF), whereas no conversion was achieved with diisopropyl ether. Thus, crude bio-methanol can be used for BDF production as a substitute for methanol from fossil resources. However, due to more efficient reaction, crude bio-methanol can be more applicable to the two-step supercritical methanol process, consisting of hydrolysis of triglycerides and subsequent esterification of fatty acids, compared with the one-step supercritical methanol process, where transesterification of triglycerides is a major reaction. PMID:17977720

  4. Chemical and biological characterization of high-Btu coal gasification: (The HYGAS process) I

    SciTech Connect

    Stamoudis, V.C.; Bourne, S.; Haugen, D.A.; Peak, M.J.; Reilly, C.A.; Stetter, J.R.; Wilzbach, K.

    1980-01-01

    We have examined the relationships between mutagenic activity and chemical composition for fractions prepared from process stream materials obtained from a high-Btu coal-gasification pilot plant in which the HYGAS process is employed. Fractionation procedures have included fractional distillation; extraction of acidic, basic, and neutral components; liquid/liquid partitioning; and column chromatography on silica gel. A large number of organic compounds in the fractions have been identified by fused-silica, capillary-column gas chromatography, and gas chromatography/mass spectrometry (GC/MS). Some fractions contain components that are mutagenic as indicated by the Ames salmonella/microsome mutagenicity assay. Fractionation and GC/MS analysis indicate that the mutagenic components are relatively nonvolatile and that they may include neutral polycyclic aromatic hydrocarbons (PAHs) as well as more polar components such as primary aromatic amines (PAAs), azaarenes (AAs), and hydroxy-PAHs. In the basic mutagenic fractions that exhibited the highest specific biological activity, PAAs may be largely responsible for the mutagenicity, as supported by its observed loss subsequent to treatment with nitrous acid. Based on the observation that the recycle oil stream (which has the highest flow of potentially hazardous organic compounds) exhibits a mutagenicity well below 1% that of benz(a)pyrene, we tentatively conclude that the health and environmental risks due to commercialization of the HYGAS would be relatively low.

  5. Integration and testing of hot desulfurization and entrained-flow gasification for power generation systems

    SciTech Connect

    Robin, A.M.; Kassman, J.S.; Leininger, T.F.; Wolfenbarger, J.K.; Wu, C.M.; Yang, P.P.

    1991-09-01

    This second Topical Report describes the work that was completed between January 1, 1989 and December 31, 1990 in a Cooperative Agreement between Texaco and the US Department of Energy that began on September 30, 1987. During the period that is covered in this report, the development and optimization of in-situ and external desulfurization processes were pursued. The research effort included bench scale testing, PDU scoping tests, process economic studies and advanced instrument testing. Two bench scale studies were performed at the Research Triangle Institute with zinc titanate sorbent to obtain data on its cycle life, sulfur capacity, durability and the effect of chlorides. These studies quantify sulfur capture during simulated air and oxygen-blown gasification for two zinc titanate formulations. Eight PDU runs for a total of 20 days of operation were conducted to evaluate the performance of candidate sorbents for both in-situ and external desulfurization. A total of 47 tests were completed with oxygen and air-blown gasification. Candidate sorbents included iron oxide for in-situ desulfurization and calcium based and mixed metal oxides for external desulfurization. Gasifier performance and sorbent sulfur capture are compared for both air-blown and oxygen-blown operation.

  6. Development of an advanced, continuous mild gasification process for the production of co-products (Task 4. 7), Volume 3

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. ); Duthie, R.G. ); Wootten, J.M. )

    1991-09-01

    The focus of this task is the preparation of (1) preliminary piping and instrument diagrams (P IDs) and single line electrical diagrams for a site-specific conceptual design and (2) a factored cost estimate for a 24 ton/day (tpd) capacity mild gasification process development unit (PDU) and an associated form coke preparation PDU. The intended site for this facility is the Illinois Coal Development Park at Carterville, Illinois, which is operated by Southern Illinois University at Carbondale. (VC)

  7. Novel Low-Cost Process for the Gasification of Biomass and Low-Rank Coals

    SciTech Connect

    Thomas Barton

    2009-03-05

    Farm Energy envisaged a phased demonstration program, in which a pilot-scale straw gasifier will be installed on a farm. The synthesis gas product will be used to initially (i) generate electricity in a 300 kW diesel generator, and subsequently (ii) used as a feedstock to produce ethanol or mixed alcohols. They were seeking straw gasification and alcohol synthesis technologies that may be implemented on farm-scale. The consortium, along with the USDA ARS station in Corvallis, OR, expressed interest in the dual-bed gasification concept promoted by WRI and Taylor Energy, LLC. This process operated at atmospheric pressure and employed a solids-circulation type oxidation/reduction cycle significantly different from traditional fluidized-bed or up-draft type gasification reactors. The objectives of this project were to perform bench-scale testing to determine technical feasibility of gasifier concept, to characterize the syngas product, and to determine the optimal operating conditions and configuration. We used the bench-scale test data to complete a preliminary design and cost estimate for a 1-2 ton per hour pilot-scale unit that is also appropriate for on-farm scale applications. The gasifier configuration with the 0.375-inch stainless steel balls recirculating media worked consistently and for periods up to six hours of grass feed. The other principle systems like the boiler, the air pump, and feeder device also worked consistently during all feeding operations. Minor hiccups during operation tended to come from secondary systems like the flare or flammable material buildup in the exit piping. Although we did not complete the extended hour tests to 24 or 48 hours due to time and budget constraints, we developed the confidence that the gasifier in its current configuration could handle those tests. At the modest temperatures we operated the gasifier, slagging was not a problem. The solid wastes were dry and low density. The majority of the fixed carbon from the grass ended up in the solid waste collected in the external cyclone. The volatiles were almost all removed in the gasifier. While the average gas heating value of the collected gas products was 50 BTUs/scf or less, addition a of the second gas exit for combustion gases would increase that value by a factor of two or three. Other changes to the current design such as shortening the gasifier body and draft tube would lead to lower air use and shorter heating times. There was no evidence of steam reforming at the current operating temperature. Likewise there was no indication of significant tar production. Reconfiguration of the gasifier at the on farm site may yet yield more significant results that would better qualify this gasifier for small scale biomass operations.

  8. Treatment of biomass gasification wastewater using a combined wet air oxidation/activated sludge process

    SciTech Connect

    English, C.J.; Petty, S.E.; Sklarew, D.S.

    1983-02-01

    A lab-scale treatability study for using thermal and biological oxidation to treat a biomass gasification wastewater (BGW) having a chemical oxygen demand (COD) of 46,000 mg/l is described. Wet air oxidation (WA0) at 300/sup 0/C and 13.8 MPa (2000 psi) was used to initially treat the BGW and resulted in a COD reduction of 74%. This was followed by conventional activated sludge treatment using operating conditions typical of municipal sewage treatment plants. This resulted in an additional 95% COD removal. Overall COD reduction for the combined process was 99%. A detailed chemical analysis of the raw BGW and thermal and biological effluents was performed using gas chromatography/mass spectrometry (GC/MS). These results showed a 97% decrease in total extractable organics with WA0 and a 99.6% decrease for combined WA0 and activated sludge treatment. Components of the treated waters tended to be fewer in number and more highly oxidized. An experiment was conducted to determine the amount of COD reduction caused by volatilization during biological treatment. Unfortunately, this did not yield conclusive results. Treatment of BGW using WA0 followed by activated sludge appears to be very effective and investigations at a larger scale are recommended.

  9. Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report

    SciTech Connect

    Prausnitz, J.M.

    1980-05-01

    This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

  10. Fluid bed gasification--plasma converter process generating energy from solid waste: experimental assessment of sulphur species.

    PubMed

    Morrin, Shane; Lettieri, Paola; Chapman, Chris; Taylor, Richard

    2014-01-01

    Often perceived as a Cinderella material, there is growing appreciation for solid waste as a renewable content thermal process feed. Nonetheless, research on solid waste gasification and sulphur mechanisms in particular is lacking. This paper presents results from two related experiments on a novel two stage gasification process, at demonstration scale, using a sulphur-enriched wood pellet feed. Notable SO2 and relatively low COS levels (before gas cleaning) were interesting features of the trials, and not normally expected under reducing gasification conditions. Analysis suggests that localised oxygen rich regions within the fluid bed played a role in SO2's generation. The response of COS to sulphur in the feed was quite prompt, whereas SO2 was more delayed. It is proposed that the bed material sequestered sulphur from the feed, later aiding SO2 generation. The more reducing gas phase regions above the bed would have facilitated COS--hence its faster response. These results provide a useful insight, with further analysis on a suite of performed experiments underway, along with thermodynamic modelling. PMID:24176239

  11. Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 3: Energy conversion subsystems and components. Part 3: Gasification, process fuels, and balance of plant

    NASA Technical Reports Server (NTRS)

    Boothe, W. A.; Corman, J. C.; Johnson, G. G.; Cassel, T. A. V.

    1976-01-01

    Results are presented of an investigation of gasification and clean fuels from coal. Factors discussed include: coal and coal transportation costs; clean liquid and gas fuel process efficiencies and costs; and cost, performance, and environmental intrusion elements of the integrated low-Btu coal gasification system. Cost estimates for the balance-of-plant requirements associated with advanced energy conversion systems utilizing coal or coal-derived fuels are included.

  12. Chemical Processing in High-Pressure Aqueous Environments. 9. Process Development for Catalytic Gasification of Algae Feedstocks

    SciTech Connect

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.

    2012-07-26

    Through the use of a metal catalyst, gasification of wet algae slurries can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In a pressurized-water environment (20 MPa), near-total conversion of the organic structure of the algae to gases has been achieved in the presence of a supported ruthenium metal catalyst. The process is essentially steam reforming, as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high levels of methane, as dictated by thermodynamic equilibrium. As opposed to earlier work, biomass trace components were removed by processing steps so that they did not cause processing difficulties in the fixed catalyst bed tubular reactor system. As a result, the algae feedstocks, even those with high ash contents, were much more reliably processed. High conversions were obtained even with high slurry concentrations. Consistent catalyst operation in these short-term tests suggested good stability and minimal poisoning effects. High methane content in the product gas was noted with significant carbon dioxide captured in the aqueous byproduct in combination with alkali constituents and the ammonia byproduct derived from proteins in the algae. High conversion of algae to gas products was found with low levels of byproduct water contamination and low to moderate loss of carbon in the mineral separation step.

  13. Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Ma, Wencheng; Hou, Baolin; Jia, Shengyong; Zhao, Qian

    2015-07-01

    Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon (SBAC) with ZnCl2 as activation agent, which was used as a support for ferric oxides to form a catalyst (FeOx/SBAC) by a simple impregnation method. The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater (CGW). The results indicated that the prepared FeOx/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide pH range from 2 to 7, temperature 30C, 15 mg/L of H2O2 and 1g/L of catalyst, and the treated effluent concentrations of COD, total phenols, BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated FeOx/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, FeOx/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by FeOx/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application. PMID:26141873

  14. Simultaneous removal of H{sub 2}S and NH{sub 3} in coal gasification processes. Final report

    SciTech Connect

    Jothimurugesan, K.; Adeyiga, A.A.; Gangwal, S.K.

    1996-11-01

    Nitrogen (N{sub 2}) occurs in coal in the form of tightly bound organic ring compounds, typically at levels of 1 to 2 wt.% on a dry-ash-free basis. During gasification, this fuel-bound nitrogen is released principally as ammonia. The formation of NH{sub 3} in coal gasification processes is a function of the coal N{sub 2} content and the gasifier operating conditions.During the use of coal gas to generate electricity in gas-fired turbines or molten carbonate fuel cells, fuel bound N{sub 2} is converted to nitrogen oxides (NO{sub x}), which are difficult to remove and are highly undesirable as atmospheric pollutants. Thus it is desirable to remove NH{sub 3} from coal gas in addition to other major contaminants such as hydrogen sulfide (H{sub 2}S) and particulates. The objective of this study was to develop a successful sorbent-catalyst combination of an NH{sub 3} decomposition catalyst with a zinc-based mixed-metal oxide H{sub 2}S sorbent with stable NH{sub 3} decomposition and H{sub 2}S removal efficiency under cyclic sulfidation-regeneration conditions in the temperature range of 500 to 700 C. Combining the NH{sub 3} and H{sub 2}S removal steps is expected to reduce capital and operating costs in an integrated gasification combined cycle (IGCC) power plant.

  15. Coal gasification systems engineering and analysis. Volume 1: Executive summary

    NASA Technical Reports Server (NTRS)

    1980-01-01

    Feasibility analyses and systems engineering studies for a 20,000 tons per day medium Btu (MBG) coal gasification plant to be built by TVA in Northern Alabama were conducted. Major objectives were as follows: (1) provide design and cost data to support the selection of a gasifier technology and other major plant design parameters, (2) provide design and cost data to support alternate product evaluation, (3) prepare a technology development plan to address areas of high technical risk, and (4) develop schedules, PERT charts, and a work breakdown structure to aid in preliminary project planning. Volume one contains a summary of gasification system characterizations. Five gasification technologies were selected for evaluation: Koppers-Totzek, Texaco, Lurgi Dry Ash, Slagging Lurgi, and Babcock and Wilcox. A summary of the trade studies and cost sensitivity analysis is included.

  16. Biomass waste gasification - can be the two stage process suitable for tar reduction and power generation?

    PubMed

    Sulc, Jind?ich; Stojdl, Ji?; Richter, Miroslav; Popelka, Jan; Svoboda, Karel; Smetana, Ji?; Vacek, Ji?; Skoblja, Siarhei; Buryan, Petr

    2012-04-01

    A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter-current downdraft in the second stage was developed and exploited for studying effects of two stage gasification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass particles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW(th). The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950C) and for gasification reaction of the fuel gas with char. The second stage used additional combustion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound contents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER=0.71) led to substantial reduction of gas heating value (LHV=3.15 MJ/Nm(3)), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950C) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the second stage presented only few mass% of the inlet biomass stream. PMID:21925858

  17. Biomass gasification and in-bed contaminants removal: performance of iron enriched olivine and bauxite in a process of steam/O2 gasification.

    PubMed

    Barisano, D; Freda, C; Nanna, F; Fanelli, E; Villone, A

    2012-08-01

    A modified Olivine, enriched in iron content (10% Fe/Olivine), and a natural bauxite, were tested in the in-bed reduction of tar and alkali halides (NaCl and KCl) released in a process of biomass steam/O(2) gasification. The tests were carried out at an ICBFB bench scale reactor under the operating conditions of: 855-890 C, atmospheric pressure, 0.5 steam/biomass and 0.33 ER ratios. From the use of the two materials, a reduction in the contaminant contents of the fuel gas produced was found. For the alkali halides, a decrease up to 70%(wt) was observed for the potassium concentration, while for sodium, the reduction was found to be quite poor. For the organic content, compared to unmodified Olivine, the chromatographically determined total tar quantity showed a removal efficiency of 38%(wt). Moreover, regarding the particulate content a rough doubling in the fuel gas revealed a certain brittleness of the new bed material. PMID:22705523

  18. Process simulation of biomass gasification integrated with a solid oxide fuel cell stack

    NASA Astrophysics Data System (ADS)

    Doherty, Wayne; Reynolds, Anthony; Kennedy, David

    2015-03-01

    Biomass gasification-solid oxide fuel cell (BG-SOFC) combined heat and power (CHP) systems are of major interest in the context of climate change mitigation, energy security and increasing energy efficiency. Aspen Plus is employed to simulate various BG-SOFC CHP systems. The aim of the research work is to investigate the technical feasibility of these systems and to study the influence of important operating parameters and examine integration options. Systems based on dual fluidised bed steam gasification and tubular SOFC technologies are modelled. The cathode recycle and electric heater integration options are not attractive in comparison to the base case anode recycle system. Thermal integration, i.e. using SOFC flue gas as gasifier oxidant, is desirable. Lowering the syngas preheat temperature (prior to SOFC anodes) is highly recommended and is more practical than lowering the cathode air preheat temperature. Results of the parametric study indicate that: steam to carbon ratio and biomass moisture content should be as low as possible; fuel utilisation factor can change the mode of operation of the plant (focus on electricity or heat); high temperature syngas cleaning is very attractive; gasification air preheating is more attractive than gasification steam superheating. High efficiencies are predicted, proving the technical feasibility of BG-SOFC CHP systems.

  19. Integrated gasification/combined-cycle power plant at Sears Island, Maine: feasibility study. Summary report

    SciTech Connect

    Not Available

    1983-01-01

    This report presents the results of a feasibility study to evaluate the use of medium Btu synthesis gas, produced from high-sulfur coal, in an Integrated Gasification Combined Cycle (IGCC) power plant, as an alternative to a conventional pulverized coal plant with flue gas scrubbers presently planned for the Sears Island, Maine site of Central Maine Power Company. The process configuration is based on the oxygen-blown Texaco Coal Gasification Process and a General Electric Combined Cycle power plant. The plant design includes a 5000 ton per day oxygen plant, four 1200 tons per day gasification trains plus one spare to reduce risk, four gas turbine-generators with heat recovery steam generators, and a reheat steam turbine generator. Plant output at ISO (59/sup 0/F) conditions is 524 MW net. The report includes preliminary design and arrangement drawings, a detailed plant description, detailed cost information, performance data, schedules, and an extensive evaluation of technical, economic, and environmental results. The results of the study indicate that the IGCC power plant is still a rapidly evolving technology. Before Central Maine Power Company can commit to construction of such a plant, several issues raised in the study need to be addressed. These issues deal with refinements in cycle performance, demonstration of various major components, and construction schedule, among others. The IGCC Plant does have less environmental impact than a comparably sized conventional coal plant, while using a high sulfur, high ash, less expensive coal. The life-of-plant levelized busbar cost for the IGCC Plant is estimated to be 5% lower than for the conventional coal-fired plant, although the initial capital cost is approximately 60% higher. Other cycle designs were identified which have the potential for improving plant economics. This Summary is published as one volume for executive review. The full report consists of two volumes detailing the complete study.

  20. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect

    Michael Schwartz

    2004-01-01

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner.

  1. Control technology assessment for coal gasification and liquefaction processes, Rockwell International, Molten Salt Coal Gasification Process Development Unit, Santa Susana, California. Report for the site visit of September 1981. Final report

    SciTech Connect

    Telesca, D.R.

    1982-04-01

    A control technology assessment was conducted at Rockwell International Corporation, Molten Salt Coal Gasification Process Development Unit (PDU) (SIC-3312) in Santa Susana, California, on September 15, 1981. The purpose of the visit was to obtain information concerning engineering controls, work practices, and the monitoring program used to mitigate hazards associated with the molten salt coal gasification PDU. Potential hazards included coal dust, explosions, fires, noise, carbon-monoxide (630080), hydrogen-sulfide (7783064), molten sodium-carbonate (497198), sodium-sulfate (7757826), sulfur-dioxide (7446095), and asphyxiation from carbon-dioxide (124389). The company provided a medical surveillance program that included a complete work and medical history. Annual physical examinations consisted of blood tests, chest X-rays, audiograms, eye and hearing tests, electrocardiograms, and pulmonary function tests. A physical capability profile was outlined for each employee which included job restrictions and limitations. Work practices, and safety, and certification programs were provided for employees. Worker exposures were minimized by the utilization of closed system operations. Natural dilution ventilation dissipated process emissions in workplaces. Engineering controls were supplemented by work practices and personal protective equipment as needed. The author concludes that gasifier stream sampling and maintenance and housekeeping activities are needed.

  2. Development of biological coal gasification (MicGAS process); 14th Quarterly report

    SciTech Connect

    1993-01-28

    Reported here is the progress on the Development of Biological Coal Gasification for DOE contract No. DE-AC21-90MC27226 MOD A006. Task 1, NEPA Compliance and Updated Test Plan has been completed. Progress toward Task 2, Enhanced Methane Production, is reported in the areas of bacterial strain improvement, addition of co-substrates, and low cost nutrient amendment. Conclusions reached as a result of this work are presented. Plans for future work are briefly outlined.

  3. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan

    2008-05-15

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  4. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  5. Evaluation of US coal performance in the Shell Coal Gasification Process (SCGP). Volume 2. Illinois No. 5 seam coal. Final report

    SciTech Connect

    Heitz, W.L.; McCullough, G.R.; Seth, M.; van Kessel, M.M.

    1984-02-01

    The Shell Coal Gasification Process (SCGP) was included in the EPRI evaluation of the more promising gasification technologies. To date, performance data for SCGP have been available mostly for European coals. This report evaluates the performance of an Illinois No. 5 coal in the SCGP. Tests were conducted in the process development unit (6 metric ton per day nominal throughput) at the Shell Internationale Research Maatschappij B.V. Amsterdam laboratory. Shell also has a 150 metric ton per day gasification process development unit at Deutsche Shell's Harburg Refinery, Federal Republic of Germany. A total of 90 metric tons of Illinois No. 5 seam coal was gasified during approximately 390 hours of tests in the SCGP process development unit. Apart from feeding difficulties associated with the first batch of coal, caused by the variability in vendor grinding, the plant operation was normal. Illinois No. 5 seam coal has a gasification and slagging behavior similar to other bituminous coals. Normal carbon conversions of 85 to 99% were obtained for oxygen/MAF coal ratios of 0.90 to 1.04, even with a coal of relatively high moisture content (7 to 12% w). Carbon conversions above 90% were achieved at oxygen/MAF coal ratios of 0.9 and a feed moisture content below 4.8%w. An extensive evaluation of potential environmental problems was conducted. No priority pollutant organics could be detected above 1 ppbw in the aqueous effluent during steady state operation. Electric power generation is a major potential use of medium Btu gas from coal gasification. In order to eliminate the need for gas storage, it is desirable that the gasifier be able to respond rapidly to load changes. To test the transient response, coal throughput was varied by 50% with virtually no effect observed on reactor pressure. Illinois No. 5 seam coal is a good feedstock for the Shell Coal Gasification Process. 35 figures, 24 tables.

  6. Modeling and Numerical Investigation of the Process of Vapor-Oxygen Gasification of Solid Fuels in a Vertical Flow Reactor Under Pressure

    NASA Astrophysics Data System (ADS)

    Rokhman, B. B.

    2014-09-01

    With the use of the developed model, detailed information has been obtained on the working process in a flow reactor with single- and two-stage schemes of vapor-oxygen gasification of coals under a pressure of 3 MPa. The dependence of the ratios of mass flow rates O2/coal and H2O/coal on the type of fuel has been established and their optimal values for the "Shell" process have been found. At a given consumption ratio of gas coal and brown coal of brand B1, the optimum diameters of particles providing minimum combustible loss of the carbon mixture have been determined. It has been found that the content of methane in the syngas in the case of two-stage gasification is much higher than in the case of single-stage gasification.

  7. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous catalytic ozonation and biological process.

    PubMed

    Zhuang, Haifeng; Han, Hongjun; Jia, Shengyong; Hou, Baolin; Zhao, Qian

    2014-08-01

    Advanced treatment of biologically pretreated coal gasification wastewater (CGW) was investigated employing heterogeneous catalytic ozonation integrated with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process. The results indicated that catalytic ozonation with the prepared catalyst (i.e. MnOx/SBAC, sewage sludge was converted into sludge based activated carbon (SBAC) which loaded manganese oxides) significantly enhanced performance of pollutants removal by generated hydroxyl radicals. The effluent of catalytic ozonation process was more biodegradable and less toxic than that in ozonation alone. Meanwhile, ANMBBR-BAF showed efficient capacity of pollutants removal in treatment of the effluent of catalytic ozonation at a shorter reaction time, allowing the discharge limits to be met. Therefore, the integrated process with efficient, economical and sustainable advantages was suitable for advanced treatment of real biologically pretreated CGW. PMID:24928270

  8. Biological gasification coals

    SciTech Connect

    Not Available

    1990-03-01

    This report describes the work performed on the project entitled Biological Gasification of Coal'' under DOE/METC Contract No. AC21-87MC23285. The goal of this project was to develop a novel approach of utilizing microorganisms to convert low-rank coals into methane gas. Two approaches for biological conversion of coals to methane were evaluated. In the first approach, indirect bioconversion, coal is first depolymerized into low molecular weight compounds (chemical or aerobic biological treatment) followed by anaerobic conversion of these compounds to methane. The second approach, direct bioconversion, the coal was treated under anaerobic conditions to produce methane. This report presents the details of experimental procedures and the results obtained from these studies. Preliminary economic analysis of a potential biological gasification scheme was also performed to establish major cost components and recommendations for future research to develop an economical biological gasification process are presented. 8 refs., 20 figs., 53 tabs.

  9. The BTL2 process of biomass utilization entrained-flow gasification of pyrolyzed biomass slurries.

    PubMed

    Raffelt, Klaus; Henrich, Edmund; Koegel, Andrea; Stahl, Ralph; Steinhardt, Joachim; Weirich, Friedhelm

    2006-01-01

    Forschungszentrum Karlsruhe has developed a concept for the utilization of cereal straw and other thin-walled biomass with high ash content. The concept consists of a regional step (drying, chopping, flash-pyrolysis, and mixing) and a central one (pressurized entrained-flow gasification, gas cleaning, synthesis of fuel, and production of byproducts). The purpose of the regional plant is to prepare the biomass by minimizing its volume and producing a stable and safe storage and transport form. In the central gasifier, the pyrolysis products are converted into syngas. The syngas is tar-free and can be used for Fischer-Tropsch synthesis after gas cleaning. PMID:16915637

  10. Assessment of the chemical, microbiological and toxicological aspects of post-processing water from underground coal gasification.

    PubMed

    Pankiewicz-Sperka, Magdalena; Sta?czyk, Krzysztof; P?aza, Gra?yna A; Kwa?niewska, Jolanta; Na??cz-Jawecki, Grzegorz

    2014-10-01

    The purpose of this paper is to provide a comprehensive characterisation (including chemical, microbiological and toxicological parameters) of water after the underground coal gasification (UCG) process. This is the first report in which these parameters were analysed together to assess the environmental risk of the water generated during the simulation of the underground coal gasification (UCG) process performed by the Central Mining Institute (Poland). Chemical analysis of the water indicated many hazardous chemical compounds, including benzene, toluene, ethylbenzene, xylene, phenols and polycyclic aromatic hydrocarbons (PAHs). Additionally, large quantities of inorganic compounds from the coal and ashes produced during the volatilisation process were noted. Due to the presence of refractory and inhibitory compounds in the post-processing water samples, the microbiological and toxicological analyses revealed the high toxicity of the UCG post-processing water. Among the tested microorganisms, mesophilic, thermophilic, psychrophilic, spore-forming, anaerobic and S-oxidizing bacteria were identified. However, the number of detected microorganisms was very low. The psychrophilic bacteria dominated among tested bacteria. There were no fungi or Actinomycetes in any of the water samples. Preliminary study revealed that hydrocarbon-oxidizing bacteria were metabolically active in the water samples. The samples were very toxic to the biotests, with the TU50 reaching 262. None of biotests was the most sensitive to all samples. Cytotoxicity and genotoxicity testing of the water samples in Vicia uncovered strong cytotoxic and clastogenic effects. Furthermore, TUNEL indicated that all of the water samples caused sporadic DNA fragmentation in the nuclei of the roots. PMID:25108176

  11. Methanol production from eucalyptus wood chips. Attachment VIII. The wood-fueled gasification system, Evergreen Energy Corporation's final engineering report

    SciTech Connect

    Fishkind, H.H.

    1982-06-01

    Evergreen Energy Corporation provided projected cost and operating data on the Evergreen/Texaco entrained-bed wood gasification system currently under development as an alternative to the state-of-the-art fixed-bed wood gasification system proposed by Davy McKee. Overall capital costs for the total plant remain about the same at approx. $250 million. The Evergreen/Texaco system will provide significant capital cost savings in the gasifiers, gas cleanup, and waste water treatment sections, and eliminate the need for a large off-site wood-fired power boiler. These reductions are offset by higher investments in the feedstock preparation, drying, and feeding section plus the need for a larger air separation plant and compressor to supply oxygen at high pressure to the gasifier.

  12. Advanced treatment of biologically pretreated coal gasification wastewater by a novel integration of heterogeneous Fenton oxidation and biological process.

    PubMed

    Xu, Peng; Han, Hongjun; Zhuang, Haifeng; Hou, Baolin; Jia, Shengyong; Xu, Chunyan; Wang, Dexin

    2015-04-01

    Laboratorial scale experiments were conducted in order to investigate a novel system integrating heterogeneous Fenton oxidation (HFO) with anoxic moving bed biofilm reactor (ANMBBR) and biological aerated filter (BAF) process on advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that HFO with the prepared catalyst (FeOx/SBAC, sewage sludge based activated carbon (SBAC) which loaded Fe oxides) played a key role in eliminating COD and COLOR as well as in improving the biodegradability of raw wastewater. The surface reaction and hydroxyl radicals (OH) oxidation were the mechanisms for FeOx/SBAC catalytic reaction. Compared with ANMBBR-BAF process, the integrated system was more effective in abating COD, BOD5, total phenols (TPs), total nitrogen (TN) and COLOR and could shorten the retention time. Therefore, the integrated system was a promising technology for engineering applications. PMID:25724695

  13. Process aspects in combustion and gasification Waste-to-Energy (WtE) units.

    PubMed

    Leckner, Bo

    2015-03-01

    The utilisation of energy in waste, Waste to Energy (WtE), has become increasingly important. Waste is a wide concept, and to focus, the feedstock dealt with here is mostly municipal solid waste. It is found that combustion in grate-fired furnaces is by far the most common mode of fuel conversion compared to fluidized beds and rotary furnaces. Combinations of pyrolysis in rotary furnace or gasification in fluidized or fixed bed with high-temperature combustion are applied particularly in Japan in systems whose purpose is to melt ashes and destroy dioxins. Recently, also in Japan more emphasis is put on WtE. In countries with high heat demand, WtE in the form of heat and power can be quite efficient even in simple grate-fired systems, whereas in warm regions only electricity is generated, and for this product the efficiency of boilers (the steam data) is limited by corrosion from the flue gas. However, combination of cleaned gas from gasification with combustion provides a means to enhance the efficiency of electricity production considerably. Finally, the impact of sorting on the properties of the waste to be fed to boilers or gasifiers is discussed. The description intends to be general, but examples are mostly taken from Europe. PMID:24846797

  14. Numerical analysis of the process of combustion and gasification of the polydisperse coke residue of high-ash coal under pressure in a fluidized bed

    SciTech Connect

    A.Y. Maistrenko; V.P. Patskov; A.I. Topal; T.V. Patskova

    2007-09-15

    A numerical analysis of the process of 'wet' gasification of high-ash coal under pressure in a low-temperature fluidized bed has been performed. The applicability of the previously developed computational model, algorithm, and program for the case under consideration has been noted. The presence of 'hot spots' (short-time local heatings) at different points of the bed has been confirmed.

  15. Integrated gasification combined-cycle power plant at Sears Island, Maine: feasibility study. Final report. Volume I. [Sears Island, Maine

    SciTech Connect

    Not Available

    1983-03-30

    This report presents the results of a feasibility study to evaluate the use of medium Btu synthesis gas, produced from high-sulfur coal, in an Integrated Gasification Combined Cycle (IGCC) power plant, as an alternative to a conventional pulverized coal plant with flue gas scrubbers presently planned for the Sears Island, Maine site of Central Maine Power Company. The process configuration is based on the oxygen-blown Texaco Coal Gasification Process and a General Electric Combined Cycle power plant. The plant design includes a 5000 ton per day oxygen plant, four 1200 tons per day gasification trains plus one spare to reduce risk, four gas turbine-generators with heat recovery steam generators, and a reheat steam turbine generator. Plant output at ISO (59/sup 0/F) conditions is 524 MW net. The report includes preliminary design and arrangement drawings, a detailed plant description, detailed cost information, performance data, schedules, and an extensive evaluation of technical, economic, and environmental results. The results of the study indicate that the IGCC power plant is still a rapidly evolving technology. Before Central Maine Power Company can commit to construction of such a plant, several issues raised in the study need to be addressed. These issues deal with refinements in cycle performance, demonstration of various major components, and construction schedule, among others. The IGCC Plant does have less environmental impact than a comparably sized conventional coal plant, while using a high sulfur, high ash, less expensive coal. The life-of-plant levelized busbar cost for the IGCC Plant is estimated to be 5% lower than for the conventional coal-fired plant, although the initial capital cost is approximately 60% higher. Other cycle designs were identified which have the potential for improving plant economics.

  16. Coal Gasification for Power Generation, 3. edition

    SciTech Connect

    2007-11-15

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  17. Development of advanced, continuous mild gasification process for the production of co-products addendum to technical evaluation

    SciTech Connect

    Not Available

    1992-11-01

    This report contains the material balance data for Wyodak, Indiana No. 3, and Cannelton coals that were tested in the mild gasification program. Data include tests conducted using the 1- to 4-lb/hr continuous fluid-bed reactor (CFBR) and the 100-lb/hr Process Research Unit (PRU). All raw analysis data were reduced to calculate product yields as a percentage of the product mass divided by the maf coal feed. The material closure was then determined, and losses were assigned to one or a combination of the three product streams: char, condensate (includes condensed steam), and gas. Mass was added proportionally to each constituent of the stream until the closure was 100%.

  18. Development of advanced, continuous mild gasification process for the production of co-products addendum to technical evaluation. Final report

    SciTech Connect

    Not Available

    1992-11-01

    This report contains the material balance data for Wyodak, Indiana No. 3, and Cannelton coals that were tested in the mild gasification program. Data include tests conducted using the 1- to 4-lb/hr continuous fluid-bed reactor (CFBR) and the 100-lb/hr Process Research Unit (PRU). All raw analysis data were reduced to calculate product yields as a percentage of the product mass divided by the maf coal feed. The material closure was then determined, and losses were assigned to one or a combination of the three product streams: char, condensate (includes condensed steam), and gas. Mass was added proportionally to each constituent of the stream until the closure was 100%.

  19. Plasma gasification of coal in different oxidants

    SciTech Connect

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B.

    2008-12-15

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  20. Advanced hybrid gasification facility

    SciTech Connect

    Sadowski, R.S.; Skinner, W.H.; Johnson, S.A.; Dixit, V.B.

    1993-08-01

    The objective of this procurement is to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology for electric power generation applications. The proprietary CRS Sirrine Engineers, Inc. PyGas{trademark} staged gasifier has been selected as the initial gasifier to be developed under this program. The gasifier is expected to avoid agglomeration when used on caking coals. It is also being designed to crack tar vapors and ammonia, and to provide an environment in which volatilized alkali may react with aluminosilicates in the coal ash thereby minimizing their concentration in the hot raw coal gas passing through the system to the gas turbine. This paper describes a novel, staged, airblown, fixed-bed gasifier designed to solve both through the incorporation of pyrolysis (carbonization) with gasification. It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration which occurs in a fixed-bed process when coal is gradually heated through the 400{degrees}F to 900{degrees}F range. In a pyrolyzer, the coal is rapidly heated such that coal tar is immediately vaporized. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can be chemically bound to aluminosilicates in (or added to) the ash. To reduce NOx from fuel home nitrogen, moisture is minimized to control ammonia generation, and HCN in the upper gasifier region is partially oxidized to NO which reacts with NH3/HCN to form N2.

  1. EARLY ENTRANCE CO-PRODUCTION PLANT - DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect

    Unknown

    2003-01-01

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the technoeconomic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from July 1, 2002 through September 30, 2002.

  2. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect

    Winnick, J.

    1996-03-01

    Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam-cycle is the conventional conversion method; however total energy conversion efficiencies for this type of process are only slightly over 30%. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40%. Conversion processes based on gasification offer efficiencies above 50%. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. This process is concerned with the removal of H{sub 2} from coal gas through an electrochemical membrane technology.

  3. Integrated mild gasification processing at the Homer City Electric Power Generating Station site. Final report, July 1989--June 1993

    SciTech Connect

    Battista, J.J.; Zawadzki, E.A.

    1993-07-01

    A new process for the production of commercial grade coke, char, and carbon products has been evaluated by Penelec/NYSEG. The process, developed by Coal Technology Corporation, CTC, utilizes a unique screw reactor to produce a devolatilized char from a wide variety of coals for the production of commercial grade coke for use in blast furnaces, foundries, and other processes requiring high quality coke. This process is called the CTC Mild Gasification Process (MGP). The process economics are significantly enhanced by integrating the new technology into an existing power generating complex. Cost savings are realized by the coke producer, the coke user, and the electric utility company. Site specific economic studies involving the Homer City Generating Station site in Western Pennsylvania, confirmed that an integrated MGP at the Homer City site, using coal fines produced at the Homer City Coal Preparation Plant, would reduce capital and operating costs significantly and would enable the HC Owners to eliminate thermal dryers, obtain low cost fuel in the form of combustible gases and liquids, and obtain lower cost replacement coal on the spot market. A previous report, identified as the Interim Report on the Project, details the technical and economic studies.

  4. Process simulation for a new conceptual design of LNG terminal coupling NGL recovery and LNG re-gasification for maximum energy savings

    NASA Astrophysics Data System (ADS)

    Muqeet, Mohammed A.

    With the high demands of shale gas and promising development of LNG terminals, a lot of research has focused towards the process development for effective recovery of C2+ hydrocarbons (NGL). Shale gas requires a large amount of cold energy to cool down and recover the NGL; and the LNG re-gasification process requires a lot of heat energy to evaporate for NGL recovery. Thus, coupling the shale gas NGL recovery process and LNG re-gasification process, for utilizing the cold energy from LNG re-gasification process to assist NGL recovery from shale gas has significant economic benefits on both energy saving and high value product recovery. Wang et al. developed new conceptual design of such coupled process in 2013 and later Wang and Xu developed an optimal design considering uncertainties in 2014. This work deals with process simulation of both these designs and the feasibility of the process is verified. A steady state model is developed based on the plant design proposed by Wang et al. using Aspen plusRTM and then a dynamic model of the process is developed using Aspen dynamicsRTM. An effective control strategy is developed and the flexibility of the dynamic model is examined by giving disturbances in the shale gas feed. A comparison is made between the two proposed design and the prospects of the design for real plant scenario is discussed.

  5. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect

    Howard Meyer

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process ?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  6. Development of an advanced continuous mild gasification process for the production of coproducts: Task 4.6, Technical and economic evaluation

    SciTech Connect

    Hogsett, R.F.; Jha, M.C.

    1991-12-01

    Morgantown Energy Technology Center (METC) of DOE has sponsored, and continues to sponsor, programs for the development of technology and market strategies which will lead to the commercialization of processes for the production of coproducts from mild gasification of coal. It has been recognized by DOE and industry that mild gasification is a promising technology with potential to economically convert coal into marketable products, thereby increasing domestic coal utilization. In this process, coal is devolatilized under non- oxidizing conditions at mild temperature (900--1100{degrees}F) and pressure (1--15psig). Condensation of the vapor will yield a liquid product that can be upgraded to a petroleum substitute, and the remaining gas can provide the fuel for the process. The residual char can be burned in a power plant. Thus, in a long-term national scenario, implementation of this process will result in significant decrease of imported oil and increase in coal utilization.

  7. Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol: Thermochemical Pathway by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect

    Dutta, A.; Talmadge, M.; Hensley, J.; Worley, M.; Dudgeon, D.; Barton, D.; Groendijk, P.; Ferrari, D.; Stears, B.; Searcy, E. M.; Wright, C. T.; Hess, J. R.

    2011-05-01

    This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing. The design features a processing capacity of 2,205 U.S. tons (2,000 metric tonnes) of dry biomass per day and an ethanol yield of 83.8 gallons per dry U.S. ton of feedstock. The ethanol selling price corresponding to this design is $2.05 per gallon in 2007 dollars, assuming a 30-year plant life and 40% equity financing with a 10% internal rate of return and the remaining 60% debt financed at 8% interest. This ethanol selling price corresponds to a gasoline equivalent price of $3.11 per gallon based on the relative volumetric energy contents of ethanol and gasoline.

  8. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  9. Modeling of the coal gasification processes in a hybrid plasma torch

    SciTech Connect

    Matveev, I.B.; Serbin, S.I.

    2007-12-15

    The major advantages of plasma treatment systems are cost effectiveness and technical efficiency. A new efficient electrodeless 1-MW hybrid plasma torch for waste disposal and coal gasification is proposed. This product merges several solutions such as the known inductive-type plasma torch, innovative reverse-vortex (RV) reactor and the recently developed nonequilibrium plasma pilot and plasma chemical reactor. With the use of the computational-fluid-dynamics-computational method, preliminary 3-D calculations of heat exchange in a 1-MW plasma generator operating with direct vortex and RV have been conducted at the air flow rate of 100 g/s. For the investigated mode and designed parameters, reduction of the total wall heat transfer for the reverse scheme is about 65 kW, which corresponds to an increase of the plasma generator efficiency by approximately 6.5%. This new hybrid plasma torch operates as a multimode, high power plasma system with a wide range of plasma feedstock gases and turn down ratio, and offers convenient and simultaneous feeding of several additional reagents into the discharge zone.

  10. Energy from gasification of solid wastes.

    PubMed

    Belgiorno, V; De Feo, G; Della Rocca, C; Napoli, R M A

    2003-01-01

    Gasification technology is by no means new: in the 1850s, most of the city of London was illuminated by "town gas" produced from the gasification of coal. Nowadays, gasification is the main technology for biomass conversion to energy and an attractive alternative for the thermal treatment of solid waste. The number of different uses of gas shows the flexibility of gasification and therefore allows it to be integrated with several industrial processes, as well as power generation systems. The use of a waste-biomass energy production system in a rural community is very interesting too. This paper describes the current state of gasification technology, energy recovery systems, pre-treatments and prospective in syngas use with particular attention to the different process cycles and environmental impacts of solid wastes gasification. PMID:12623097

  11. Modelling of Underground Coal Gasification Process Using CFD Methods / Modelowanie Procesu Podziemnego Zgazowania W?gla Kamiennego Z Zastosowaniem Metod CFD

    NASA Astrophysics Data System (ADS)

    Wachowicz, Jan; ??czny, Jacek Marian; Iwaszenko, Sebastian; Janoszek, Tomasz; Cempa-Balewicz, Magdalena

    2015-09-01

    The results of model studies involving numerical simulation of underground coal gasification process are presented. For the purpose of the study, the software of computational fluid dynamics (CFD) was selected for simulation of underground coal gasification. Based on the review of the literature, it was decided that ANSYS-Fluent will be used as software for the performance of model studies. The ANSYS- -Fluent software was used for numerical calculations in order to identify the distribution of changes in the concentration of syngas components as a function of duration of coal gasification process. The nature of the calculations was predictive. A geometric model has been developed based on construction data of the georeactor used during the researches in Experimental Mine "Barbara" and Coal Mine "Wieczorek" and it was prepared by generating a numerical grid. Data concerning the georeactor power supply method and the parameters maintained during the process used to define the numerical model. Some part of data was supplemented based on the literature sources. The main assumption was to base the simulation of the georeactor operation on a mathematical models describing reactive fluid flow. Components of the process gas and the gasification agent move along the gasification channel and simulate physicochemical phenomena associated with the transfer of mass and energy as well as chemical reactions (together with the energy effect). Chemical reactions of the gasification process are based on a kinetic equation which determines the course of a particular type of equation of chemical coal gasification. The interaction of gas with the surrounding coal layer has also been described as a part of the model. The description concerned the transport of thermal energy. The coal seam and the mass rock are treated as a homogeneous body. Modelling studies assumed the coal gasification process is carried out with the participation of separately oxygen and air as a gasification agent, under the specific conditions of the georeactor operations within the time interval of 100 hours and 305 hours. The results of the numerical solution have been compared with the results of experimental results under in-situ conditions. Zaprezentowano wyniki bada? modelowych polegaj?cych na numerycznej symulacji procesu podziemnego zgazowania w?gla. Dla potrzeb realizowanej pracy dokonano wyboru oprogramowania wykorzystywanego do symulacji procesu podziemnego zgazowania w?gla. Na podstawie przegl?du literatury zdecydowano, ?e oprogramowaniem, za pomoc?, ktrego b?d? realizowane badania modelowe, b?dzie oprogramowanie informatyczne ANSYS-Fluent. Za jego pomoc? przeprowadzano obliczenia numeryczne z zamiarem zidentyfikowania rozk?adu zmian st??enia sk?adnikw gazu procesowego w funkcji czasu trwania procesu zgazowania w?gla. Przeprowadzone obliczenia mia?y charakter predykcji. W oparciu o dane konstrukcyjne georeaktora stosowanego podczas bada? na KD Barbara oraz KWK Wieczorek, opracowano model geometryczny oraz wykonano jego dyskretyzacj? poprzez wygenerowanie odpowiedniej siatki numerycznej w oparciu, o ktr? wykonywane s? obliczenia. Dane dotycz?ce sposobu zasilania georeaktora oraz parametrw utrzymywanych podczas procesu wykorzystano do definiowania modelu numerycznego. Cz??? danych zosta?a uzupe?niona w oparciu o ?rd?a literaturowe. G?wnym przyj?tym za?o?eniem by?o oparcie symulacji pracy georeaktora o modele opisuj?ce reaktywny przep?yw p?ynu. Sk?adniki gazu procesowego oraz czynnik zgazowuj?cy przemieszczaj? si? wzd?u? kana?u zgazowuj?cego symuluj?c zjawiska fizykochemiczne zwi?zane z transportem masy i energii oraz zachodz?ce reakcje chemiczne (wraz z efektem energetycznym). Chemizm procesu zgazowania oparto o rwnanie kinetyczne, ktre determinuje przebieg danego typu rwnania chemicznego zgazowania w?gla. W ramach modelu opisano te? interakcj? gazu z otaczaj?c? warstw? w?gla. Opis ten dotyczy? transportu energii cieplnej. Wars

  12. Economics of synfuel and gasification systems

    SciTech Connect

    Hahn, O.J.

    1981-01-01

    The performance characteristics of several gasification systems are discussed. Cost estimates of various synthetic fuels are presented. The lowest cost synthetic fuel is significantly above the current natural gas price of about $2.75/MMBtu and about equivalent to present oil prices at the plant gate. Gas prices for the Welman-Galusha gasifier would have to be increased significantly if the plant ran on two shifts only or if the gasifiers were not fully loaded. For industrial application the lowest cost fuel is probably the direct use of low sulfur coal with some post combustion pollution control. This is followed by the atmospheric fluidized bed combustor. Coal/oil mixtures and solvent refined coal liquids (SRC I or SRC II) are the next options. High Btu gas from a large coal gasification plant will be more competitive for industrial use. Large industrial uses in the range of 1000 tons of coal a day may find reduced costs with an entrained coal conversion unit such as a Texaco or the Saarberg-Otto Gasifiers. However, before 1985 when the gas price decontrol has been felt, it is unlikely that low Btu gas, medium Btu gas and methanol will be an economical choice for industrial users.

  13. Investigation of plasma-aided bituminous coal gasification

    SciTech Connect

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B.

    2009-04-15

    This paper presents thermodynamic and kinetic modeling of plasma-aided bituminous coal gasification. Distributions of concentrations, temperatures, and velocities of the gasification products along the gasifier are calculated. Carbon gasification degree, specific power consumptions, and heat engineering characteristics of synthesis gas at the outlet of the gasifier are determined at plasma air/steam and oxygen/steam gasification of Powder River Basin bituminous coal. Numerical simulation showed that the plasma oxygen/steam gasification of coal is a more preferable process in comparison with the plasma air/steam coal gasification. On the numerical experiments, a plasma vortex fuel reformer is designed.

  14. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  15. Analysis of Integrated Gasification Combined Cycle power plants and process integration with pre-combustion carbon capture

    E-print Network

    Kapetaki, Zoe

    2015-06-29

    Integrated Gasification Combined Cycle (IGCC) power plants have been considered as one of the best options for energy production in an environmental friendly manner. IGCC power plants are demonstrating better results, ...

  16. 2007 gasification technologies conference papers

    SciTech Connect

    2007-07-01

    Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

  17. Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation. Final report

    SciTech Connect

    Ness, R.O. Jr.; Runge, B.; Sharp, L.

    1992-11-01

    The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930{degree} and 1470{degree}F (500{degree}and 800{degree}C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a ``coal refinery`` system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R&D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

  18. Development of an advanced, continuous mild gasification process for the production of co-products technical evaluation

    SciTech Connect

    Ness, R.O. Jr.; Runge, B.; Sharp, L.

    1992-11-01

    The University of North Dakota Energy and Environmental Research Center (EERC) and the AMAX Research and Development Center are cooperating in the development of a Mild Gasification process that will rapidly devolatilize coals of all ranks at relatively low temperatures between 930[degree] and 1470[degree]F (500[degree]and 800[degree]C) and near atmospheric pressure to produce primary products that include a reactive char, a hydrocarbon condensate, and a low-Btu gas. These will be upgraded in a coal refinery'' system having the flexibility to optimize products based on market demand. Task 2 of the four-task development sequence primarily covered bench-scale testing on a 10-gram thermogravimetric analyzer (TGA) and a 1 to 4-lb/hr continuous fluidized-bed reactor (CFBR). Tests were performed to determine product yields and qualities for the two major test coals-one a high-sulfur bituminous coal from the Illinois Basin (Indiana No. 3) and the other a low-sulfur subbituminous coal from the Powder River Basin (Wyodak). Results from Task 3, on product upgrading tests performed by AMAX Research and Development (R D), are also reported. Task 4 included the construction, operation of a Process Research Unit (PRU), and the upgrading of the products. An economic evaluation of a commercial facility was made, based on the data produced in the PRU, CFBR, and the physical cleaning steps.

  19. Development of an advanced, continuous mild gasification process for the production of co-products (Task 4.7), Volume 3. Final report

    SciTech Connect

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H.; Duthie, R.G.; Wootten, J.M.

    1991-09-01

    The focus of this task is the preparation of (1) preliminary piping and instrument diagrams (P&IDs) and single line electrical diagrams for a site-specific conceptual design and (2) a factored cost estimate for a 24 ton/day (tpd) capacity mild gasification process development unit (PDU) and an associated form coke preparation PDU. The intended site for this facility is the Illinois Coal Development Park at Carterville, Illinois, which is operated by Southern Illinois University at Carbondale. (VC)

  20. Development of an advanced, continuous mild gasification process for the production of co-products. Quarterly technical progress report, April--June 1988

    SciTech Connect

    Ness, R.O. Jr.

    1988-07-01

    The Department of Energy is investigating a process concept called Mild Gasification in which rapid devolatilization of coal under mild conditions of temperature and pressure would yield three product slates: a low- or medium-BTU gas, a valuable hydrocarbon condensate, and a reactive char. The ongoing objective of this program is to develop a continuous mild gasification process which will produce a product mix that optimizes process economics. In order to provide the incentive for private industry to commercialize the process, it is necessary to demonstrate yields and qualities in a versatile continuous process development unit (PDU). This unit must be capable of assessing both coal- and process-specific effects in a cost-effective and timely manner. Based on literature reviews and experimental verification, a data base will be developed correlating coal and process parameters with product characteristics. This will provide process developers with the information necessary to derive site-specific economics which will be crucial for the commercialization of the mild gasification process. The literature review and market assessment has been completed under Task 1 of the program. Under Task 2, coal-specific tests are being conducted on three AMAX coals: Chinook, an Indiana {number_sign}3 bituminous coal; Delta, an Illinois {number_sign}6 bituminous coal; and Eagle Butte, a Wyodak subbituminous coal. Various methods of char upgrading are being conducted by AMAX R&D of Golden, Colorado. The upgraded char is then combined with iron ore and tested for pig iron production under an AMAX subcontract to Pellet Technology Corporation of Marquette, Michigan. In addition to the test program, process development and scaleup information is being developed for a 1 ton/hr pilot plant unit. Plans for Tasks 2 and 3, equipment modifications, and report. Results include: char analysis, condensable analysis, waste water analysis, and gas analysis.

  1. Improved catalysts for carbon and coal gasification

    DOEpatents

    McKee, D.W.; Spiro, C.L.; Kosky, P.G.

    1984-05-25

    This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

  2. EARLY ENTRANCE CO-PRODUCTION PLANT--DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect

    John W. Rich

    2001-03-01

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power and Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement with the USDOE, National Energy Technology Laboratory (NETL) to assess the techno-economic viability of building an Early Entrance Co-Production Plant (EECP) in the US to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co--product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases: Phase 1 is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase 2 is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase 3 updates the original EECP design based on results from Phase 2, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report is WMPI's third quarterly technical progress report. It covers the period performance from October 1, 2001 through December 31, 2001.

  3. ANALYTICAL METHODS FOR HAZARDOUS ORGANICS IN LIQUID WASTES FROM COAL GASIFICATION AND LIQUEFACTION PROCESSES

    EPA Science Inventory

    This study was conducted by the University of Southern California group to provide methods for the analysis of coal liquefaction wastes from coal conversion processing plants. Several methods of preliminary fractionation prior to analysis were considered. The most satisfactory me...

  4. Catalytic Hydrothermal Gasification

    SciTech Connect

    Elliott, Douglas C.

    2015-05-31

    The term hydrothermal used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  5. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, January 1, 1996--March 31, 1996

    SciTech Connect

    Winnick, J.

    1996-09-01

    Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam- cycle is the conventional conversion method; however, total energy conversion efficiencies for this type of process are only slightly over 30{percent}. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40{percent}. Conversion processes based on gasification offer efficiencies above 50{percent}. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. Problems arise due to the corrosive nature of H{sub 2}S on metal components contained in these cycles. Because of this, H{sub 2}S concentrations must be reduced to low levels corresponding to certain power applications. An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed using funds from this grant. Past experiments using this concept dealt with identifying removal of 1-2{percent} H{sub 2}S from gases containing only H{sub 2}S in N{sub 2}, simulated natural gas, and simulated coal gas. Other goals include optimization of cell materials capable of improving cell performance. Once cell materials are defined, cell experiments determining maximum removal capabilities and current efficiencies will be conducted. Also, a model theoretically describing the preferred reduction of H{sub 2}S, the transport of S{sup 2{minus}}, and the competing transport of CO{sub 2} will be investigated. The model should identify the maximum current efficiency for H{sub 2}S removal, depending on variables such as flow rate, temperature, current application, and the total cell potential. 21 refs., 10 figs., 9 tabs.

  6. Development of biological coal gasification (MicGAS Process). Seventh quarterly report

    SciTech Connect

    Not Available

    1992-04-30

    In order for the coal biogasification process to be economically feasible, an inexpensive nutrient amendment must be found to replace the Difco{trademark} yeast extract and tryptic soy broth (YE/TSB) used in the current medium formulation. Five products have been identified which support greater methane production from Texas lignite than YE/TSB.

  7. Syngas chemical looping gasification process: oxygen carrier particle selection and performance

    SciTech Connect

    Fanxing Li; Hyung Ray Kim; Deepak Sridhar; Fei Wang; Liang Zeng; Joseph Chen; L.-S. Fan

    2009-08-15

    The syngas chemical looping (SCL) process coproduces hydrogen and electricity. The process involves reducing metal oxides with syngas followed by regeneration of reduced metal oxides with steam and air in a cyclic manner. Iron oxide is determined to be a desired oxygen carrier for hydrogen production considering overall properties including oxygen carrying capacity, thermodynamic properties, reaction kinetics, physical strength, melting points, and environmental effects. An iron oxide based particle can maintain good reactivity for more than 100 reduction-oxidation (redox) cycles in a thermogravimetric analyzer (TGA). The particle exhibits a good crushing strength (>20 MPa) and low attrition rate. Fixed bed experiments are carried out which reaffirm its reactivity. More than 99.75% of syngas is converted during the reduction stage. During the regeneration stage, hydrogen with an average purity of 99.8% is produced. 23 refs., 6 figs., 10 tabs.

  8. Development of biological coal gasification (MicGAS process). Nineth quarterly report, [July--September 1992

    SciTech Connect

    Not Available

    1992-10-30

    Laboratory scale studies examining biogasification of Texas lignite at various coal solids loadings have been completed. Bench scale bioreactors are currently being used to scale up the biogasification process to higher coal solids loadings (5% and 10%) Specific observations reported this quarter are that methane production was not curtailed when B-vitamin solution was not added to the biogasification medium and that aeration of Mic-1 did not sufficiently oxidize the medium to eliminate strict anaerobic bacteria including methanogens.

  9. 2010 Worldwide Gasification Database

    DOE Data Explorer

    The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

  10. Test and evaluate the tri-gas low-Btu coal-gasification process. Final report, October 21, 1977-October 31, 1980

    SciTech Connect

    Zabetakis, M.G.

    1980-12-01

    This report describes the continuation of work done to develop the BCR TRI-GAS multiple fluidized-bed gasification process. The objective is the gasification of all ranks of coals with the only product being a clean, low-Btu fuel gas. Design and construction of a 100 lb/h process and equipment development unit (PEDU) was completed on the previous contract. The process consists of three fluid-bed reactors in series, each having a specific function: Stage 1 - pretreatment; Stage 2- - gasification; Stage 3 - maximization of carbon utilization. Under the present contract, 59 PEDU tests have been conducted. A number of these were single-stage tests, mostly in Stage 1; however, integrated PEDU tests were conducted with a western coal (Rosebud) and two eastern coals (Illinois No. 6 and Pittsburgh seam). Both Rosebud and Pittsburgh seam coals were gasified with the PEDU operating in the design mode. Operation with Illinois No. 6 seam coal was also very promising; however, time limitations precluded further testing with this coal. One of the crucial tasks was to operate the Stage 1 reactor to pretreat and devolatilize caking coals. By adding a small amount of air to the fluidizing gas, the caking properties of the coal can be eliminated. However, it was also desirable to release a high percentage of the volatile matter from the coal in this vessel. To accomplish this, the reactor had to be operated above the agglomerating temperature of caking coals. By maintaining a low ratio of fresh to treated coal, this objective was achieved. Both Illinois No. 6 and Pittsburgh seam coals were treated at temperatures of 800 to 900 F without agglomerating in the vessel.

  11. Development of Biological Coal Gasification (MicGAS Process). Topical report, July 1991--February 1993

    SciTech Connect

    Srivastava, K.C.

    1993-06-01

    Laboratory and bench scale reactor research carried out during the report period confirms the feasibility of biomethanation of Texas lignite (TxL) and some other low-rank coals to methane by specifically developed unique anaerobic microbial consortia. The data obtained demonstrates specificity of a particular microbial consortium to a given lignite. Development of a suitable microbial consortium is the key to the success of the process. The Mic-1 consortium was developed to tolerate higher coal loadings of 1 and 5% TxL in comparison to initial loadings of 0.01% and 0.1% TxL. Moreover, the reaction period was reduced from 60 days to 14 to 21 days. The cost of the culture medium for bioconversion was reduced by studying the effect of different growth factors on the biomethanation capability of Mic-1 consortium. Four different bench scale bioreactor configurations, namely Rotating Biological Contactor (RBC), Upflow Fluidized Bed Reactor (UFBR), Trickle Bed Reactor (TBR), and Continuously Stirred Tank Reactor (CSTR) were evaluated for scale up studies. Preliminary results indicated highest biomethanation of TxL by the Mic-1 consortium in the CSTR, and lowest in the trickle bed reactor. However, highest methane production and process efficiency were obtained in the RBC.

  12. Theoretical Investigation of the Process of Steam-Oxygen Gasification of Coke-Ash Particles in a Fluidized Bed Under Pressure

    NASA Astrophysics Data System (ADS)

    Rokhman, B. B.

    2015-03-01

    The problem on the evolution of the state of an ensemble of reacting coke-ash particles in a fluidized-bed gas generator is considered. A kinetic equation for the distribution function of particles within small ranges of carbon concentration variation for the stages of surface and bulk reaction has been constructed and integrated. Boundary conditions ("matching" conditions) at the boundaries between these ranges are formulated. The influence of the granulometric composition of the starting coal, height, porosity, and of the bed temperature on the process of steam-oxygen gasification of coke-ash particles of individual sorts of fuel and of a binary coal mixture has been investigated.

  13. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect

    Cohen, L.R. ); Hogsett, R.F. ); Sinor, J.E. Consultants, Inc., Niwot, CO ); Ness, R.O. Jr.; Runge, B.D. . Energy and Environmental Research Center)

    1992-10-01

    The principal finding of this study was the high capital cost and poor financial performance predicted for the size and configuration of the plant design presented. The XBi financial assessment gave a disappointingly low base-case discounted cash flow rate of return (DCFRR) of only 8.1% based on a unit capital cost of $900 per ton year (tpy) for their 129,000 tpy design. This plant cost is in reasonable agreement with the preliminary estimates developed by J.E. Sinor Associates for a 117,000 tpy plant based on the FMC process with similar auxiliaries (Sinor, 1989), for which a unit capital costs of $938 tpy was predicted for a design that included char beneficiation and coal liquids upgrading--or about $779 tpy without the liquid upgrading facilities. The XBi assessment points out that a unit plant cost of $900 tpy is about three times the cost for a conventional coke oven, and therefore, outside the competitive range for commercialization. Modifications to improve process economics could involve increasing plant size, expanding the product slate that XBi has restricted to form coke and electricity, and simplifying the plant flow sheet by eliminating marginally effective cleaning steps and changing other key design parameters. Improving the financial performance of the proposed formed coke design to the level of a 20% DCFRR based on increased plant size alone would require a twenty-fold increase to a coal input of 20,000 tpd and a coke production of about 2.6 minion tpy--a scaling exponent of 0.70 to correct plant cost in relation to plant size.

  14. Phototype plant for Nuclear Process Heat (NPH), reference phase. R and D work on Hydrogenated Coal Gasification (HCG). Further operation of semi-industrial plant for hydrogenated coal gasification

    NASA Astrophysics Data System (ADS)

    Fladerer, R.; Schrader, L.

    1982-07-01

    In view of a scale up, leading to a commercial HCG, futher R and D work was performed on the 100 kg C/hr prototype plant. The inclined tube for feeding coal into the fluidized bed, the raw gas/hydrogenation gas heat exchanger, and the modified hydrogen source were tested. Influence on carbon gasification efficiency of dimension of coal particles, humidity of coal, hydrogen content of gasification gas, introduction place of coal in gasifier, height of fluidized bed, and ash content of coal were studied. The plant was operated for 19,400 hr, of which more than 7400 hr under gasification conditions. Carbon gasification rates up to 82% with methane content up to 48% were obtained.

  15. Processes forming Gas, Tar, and Coke in Cellulose Gasification from Gas-Phase Reactions of Levoglucosan as Intermediate.

    PubMed

    Fukutome, Asuka; Kawamoto, Haruo; Saka, Shiro

    2015-07-01

    The gas-phase pyrolysis of levoglucosan (LG), the major intermediate species during cellulose gasification, was studied experimentally over the temperature range of 400-900?C. Gaseous LG did not produce any dehydration products, which include coke, furans, and aromatic substances, although these are characteristic products of the pyrolysis of molten LG. Alternatively, at >500?C, gaseous LG produced only fragmentation products, such as noncondensable gases and condensable C1 -C3 fragments, as intermediates during noncondensable gas formation. Therefore, it was determined that secondary reactions of gaseous LG can result in the clean (tar- and coke-free) gasification of cellulose. Cooling of the remaining LG in the gas phase caused coke formation by the transition of the LG to the molten state. The molecular mechanisms that govern the gas- and molten-phase reactions of LG are discussed in terms of the acid catalyst effect of intermolecular hydrogen bonding to promote the molten-phase dehydration reactions. PMID:26099988

  16. Four stage, fluidized bed gasification process minimizes NO{sub x}

    SciTech Connect

    Lewis, F.M.; Haug, R.T.

    1999-07-01

    In 1981, after a long and thorough study of alternative methods of sewage sludge (biosolids) disposal, the City of Los Angeles (CLA) embarked on a pilot test program to incinerate dried sewage sludge from its Hyperion Wastewater Treatment Plant. This dried sludge is typically 47% ash, 53% combustible, and has an average higher heating value (HHV), moisture, ash-free (MAF) of 10,675 Btu/Lbm. The dried sludge is called sludge derived fuel (SDF). Approximately 8% of the MAF fraction of SDF is fuel-bound nitrogen. When SDF, with its extremely high fuel-bound nitrogen, was combusted in conventional multiple hearth and fluidized bed pilot plant furnaces, NO{sub x} emissions were extremely high ({gt}1,000 ppm). Faced with this dilemma, the CLA initiated an R and D program to reduce NO{sub x}. The pilot tests with a sub-stoichiometric fluid bed and an excess air afterburner (two-stages) reduced NO{sub x} to 400--600 ppm. With one intermediate stage added (three-stage), NO{sub x} was reduced to 130--150 ppm. However, when the following four-stage process was developed and tested, NO{sub x} was reduced to 50--75 ppm. Stage 1: Sub-stoichiometric fluidized bed operating at a nominal 30% stoichiometric air (SA). Stage 2:Sub-stoichiometric zone operating at a nominal 80% SA. Stage 3: Stoichiometric zone operating at a nominal 100% SA. Stage 4: Excess air zone (Afterburner) operating at a nominal 135% SA (35% excess air). After pilot testing was complete and design parameters established, three full-size, fluid bed gasifiers (two operational--one standby) were designed, constructed and operated until 1996. This paper describes the design, operation, and emission testing of these four-stage fluid bed gasifiers with special emphasis on the problems of (a) pneumatic feeding of SDF powder into the pressurized bed and (b) baghouse fabrics (expanded PTEE membrane on PTFE scrim). Final emission test results for NO{sub x} and other criteria pollutants are also presented.

  17. Mild gasification technology development process: Task 3, Bench-scale char upgrading study, February 1988--November 1990

    SciTech Connect

    Carty, R.H.; Onischak, M.; Babu, S.P.; Knight, R.A.; Wootten, J.M.; Duthie, R.G.

    1990-12-01

    The overall objective of this program is to develop mild gasification technology and co-product utilization. The objective of Task 3 was to investigate the necessary steps for upgrading the mild gasification char into potential high-market-value solid products. Recommendations of the Task 1 market survey section formed the basis for selecting three value-added solid products from mild gasification char: form coke, smokeless fuel, and activated adsorbent char. The formation and testing for the form coke co-product involved an evaluation of its briquette strength and reactivity. The measured tensile strength and reactivity of the form coke sample briquettes were in the range of commercial coke, and development tests on a larger scale are recommended. The reaction rate of the form coke carbon with carbon dioxide at 1825{degree}F was measured using a standard procedure. A smokeless fuel briquette with limestone added to control sulfur can be made from mild gasification char in a simple manner. Test results have shown that briquettes with limestone have a heating value comparable to other solid fuels and the limestone can retain up to 88% of the sulfur during combustion in a simple bench-scale combustion test, almost all of it as a stable calcium sulfate. Adsorbent chars were prepared with a standard steam activation procedure and tested for a variety of pertinent property and performance values. Such adsorbents may be better suited for use in some areas, such as the adsorption of low-molecular-weight substances, because of the smaller pore sizes measured in the char. 5 refs., 17 figs., 6 tabs.

  18. Development of an advanced continuous mild gasification process for the production of co-products. Final report, September 1987--September 1996

    SciTech Connect

    1996-12-31

    Char, the major co-product of mild coal gasification, represents about 70 percent of the total product yield. The only viable use for the char is in the production of formed coke. Early work to develop formed coke used char from a pilot plant sized mild gasification unit (MGU), which was based on commercial units of the COALITE plant in England. Formed coke was made at a bench-scale production level using MGU chars from different coals. An evolutionary formed coke development process over a two-year period resulted in formed coke production at bench-scale levels that met metallurgical industries` specifications. In an ASTM D5341 reactivity test by a certified lab, the coke tested CRI 30.4 and CSR 67.0 which is excellent. The standard is CRI < 32 and CSR > 55. In 1991, a continuous 1000 pounds per hour coal feed mild coal gasification pilot plant (CMGU) was completed. The gasification unit is a heated unique screw conveyor designed to continuously process plastic coal, vent volatiles generated by pyrolysis of coal, and convert the plastic coal to free flowing char. The screw reactor auxiliary components are basic solids materials handling equipment. The screw reactor will convert coal to char and volatile co-products at a rate greater than 1000 pounds per hour of coal feed. Formed coke from CMGU char is comparable to that from the MGU char. In pilot-plant test runs, up to 20 tons of foundry coke were produced. Three formed coke tests at commercial foundries were successful. In all of the cupola tests, the iron temperature and composition data indicated that the formed coke performed satisfactorily. No negative change in the way the cupola performed was noticed. The last 20-ton test was 100 percent CTC/DOE coke. With conventional coke in this cupola charging rates were 10 charges per hour. The formed coke charges were 11 to 12 charges per hour. This equates to a higher melt rate. A 10 percent increase in cupola production would be a major advantage. 13 figs., 13 tabs.

  19. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect

    Winnick, J.

    1995-12-31

    An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the exiting syn-gas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need for a Claus process for sulfur recovery. Membrane manufacturing coupled with full-cell experimentation was the primary focus this quarter. A tape-casted zirconia membrane was developed and utilized in one full-cell experiment (run 25); run 24 utilized a fabricated membrane purchased from Zircar Corporation. Results are discussed.

  20. Scale-up of mild gasification to be a process development unit mildgas 24 ton/day PDU design report. Final report, November 1991--July 1996

    SciTech Connect

    1996-03-01

    From November 1991 to April 1996, Kerr McGee Coal Corporation (K-M Coal) led a project to develop the Institute of Gas Technology (IGT) Mild Gasification (MILDGAS) process for near-term commercialization. The specific objectives of the program were to: design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scale-up; obtain large batches of coal-derived co-products for industrial evaluation; prepare a detailed design of a demonstration unit; and develop technical and economic plans for commercialization of the MILDGAS process. The project team for the PDU development program consisted of: K-M Coal, IGT, Bechtel Corporation, Southern Illinois University at Carbondale (SIUC), General Motors (GM), Pellet Technology Corporation (PTC), LTV Steel, Armco Steel, Reilly Industries, and Auto Research.

  1. Coal gasification for Sears Island

    SciTech Connect

    Cummings, R.C.; Halporn, A.D.; Hastings, P.C.; Vivenzio, T.A.

    1983-01-01

    This paper reports on the construction of an integrated gasification combined-cycle (IGCC) demonstration plant on Sears Island, Maine. The current state-of-the-art, the incentives to continue work on plants using a gasification process, and the necessary successive steps to go from the current state-of-the-art to a mature technology are discussed. A DOE-sponsored study was undertaken to evaluate the feasibility of licensing, designing, constructing, and operating a nominal 500-MW commercial-sized IGCC power plant using Eastern high-sulfur coal at Sears Island. The major systems of the IGCC plant configuration include coal receiving, handling and storage; the air separation plant; slurry preparation; the gasification train; raw gas conditioning; acid gas removal and sulfur recovery; combined-cycle power generation; and water and waste treatment. The application of the coal gasification process to produce synthesis fuel gas for power generation offers many advantages over the conventional coal-fired steam unit, including lower busbar cost, better environmental compatibility and modular construction.

  2. Prediction and measurement of entrained flow coal gasification processes. Interim report, September 8, 1981-September 7, 1983

    SciTech Connect

    Hedman, P.O.; Smoot, L.D.; Fletcher, T.H.; Smith, P.J.; Blackham, A.U.

    1984-01-31

    This volume reports interim experimental and theoretical results of the first two years of a three year study of entrained coal gasification with steam and oxygen. The gasifier facility and testing methods were revised and improved. The gasifier was also modified for high pressure operation. Six successful check-out tests at elevated pressure were performed (55, 75, 100, 130, 170, and 215 psig), and 8 successful mapping tests were performed with the Utah bituminous coal at an elevated pressure of 137.5 psig. Also, mapping tests were performed at atmospheric pressure with a Utah bituminous coal (9 tests) and with a Wyoming subbituminous coal (14 tests). The LDV system was used on the cold-flow facility to make additional nonreactive jets mixing measurements (local mean and turbulent velocity) that could be used to help validate the two-dimensional code. The previously completed two-dimensional entrained coal gasification code, PCGC-2, was evaluated through rigorous comparison with cold-flow, pulverized coal combustion, and entrained coal gasification data. Data from this laboratory were primarily used but data from other laboratories were used when available. A complete set of the data used has been compiled into a Data Book which is included as a supplemental volume of this interim report. A revised user's manual for the two-dimensional code has been prepared and is also included as a part of this interim report. Three technical papers based on the results of this study were published or prepared. 107 references, 57 figures, 35 tables.

  3. EMERY BIOMASS GASIFICATION POWER SYSTEM

    SciTech Connect

    Benjamin Phillips; Scott Hassett; Harry Gatley

    2002-11-27

    Emery Recycling Corporation (now Emery Energy Company, LLC) evaluated the technical and economical feasibility of the Emery Biomass Gasification Power System (EBGPS). The gasifier technology is owned and being developed by Emery. The Emery Gasifier for this project was an oxygen-blown, pressurized, non-slagging gasification process that novelly integrates both fixed-bed and entrained-flow gasification processes into a single vessel. This unique internal geometry of the gasifier vessel will allow for tar and oil destruction within the gasifier. Additionally, the use of novel syngas cleaning processes using sorbents is proposed with the potential to displace traditional amine-based and other syngas cleaning processes. The work scope within this project included: one-dimensional gasifier modeling, overall plant process modeling (ASPEN), feedstock assessment, additional analyses on the proposed syngas cleaning process, plant cost estimating, and, market analysis to determine overall feasibility and applicability of the technology for further development and commercial deployment opportunities. Additionally, the project included the development of a detailed technology development roadmap necessary to commercialize the Emery Gasification technology. Process modeling was used to evaluate both combined cycle and solid oxide fuel cell power configurations. Ten (10) cases were evaluated in an ASPEN model wherein nine (9) cases were IGCC configurations with fuel-to-electricity efficiencies ranging from 38-42% and one (1) case was an IGFC solid oxide case where 53.5% overall plant efficiency was projected. The cost of electricity was determined to be very competitive at scales from 35-71 MWe. Market analysis of feedstock availability showed numerous market opportunities for commercial deployment of the technology with modular capabilities for various plant sizes based on feedstock availability and power demand.

  4. Gasification-based biomass

    SciTech Connect

    None, None

    2009-01-18

    The gasification-based biomass section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  5. POLLUTANTS FROM SYNTHETIC FUELS PRODUCTION: SAMPLING AND ANALYSIS METHODS FOR COAL GASIFICATION

    EPA Science Inventory

    The report describes sampling and analysis methods involving a laboratory-scale coal gasification facility used to study the generation, sampling, chemical analysis, process evaluation, and environmental assessment of pollutants from coal gasification. It describes methods for pa...

  6. Biothermal gasification of biomass

    SciTech Connect

    Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

    1980-01-01

    The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

  7. Coal gasification vessel

    DOEpatents

    Loo, Billy W. (Oakland, CA)

    1982-01-01

    A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

  8. Materials of Gasification

    SciTech Connect

    2005-09-15

    The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

  9. Coal gasification. Quarterly report, July-September 1979

    SciTech Connect

    1980-07-01

    The status of 18 coal gasification pilot plants or supporting projects supported by US DOE is reviewed under the following headings: company involved, location, contract number, funding, gasification process, history, process description, flowsheet and progress in the July-September 1979 quarter. (LTN)

  10. EARLY ENTRANCE CO-PRODUCTION PLANT - DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect

    Unknown

    2001-12-01

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification, SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the US Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the techno-economic viability of building an Early Entrance Co-Production Plant (EECP) in the US to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP designs emphasize on recovery and gasification of low-cost coal waste (culm) from coal clean operations and will assess blends of the culm and coal or petroleum coke as feedstocks. The project is being carried out in three phases. Phase I involves definition of concept and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II consists of an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III involves updating the original EECP design, based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 BPD coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania.

  11. Development of an advanced, continuous mild gasification process for the production of co-products. Quarterly report, April--June 1995

    SciTech Connect

    1995-08-01

    The objective of this research and development effort was to develop an advanced, continuous ``mild gasification`` process. The relative quantities and properties of the products are appropriate for making the concept economically and environmentally viable. In ``mild gasification,`` coal is converted under relatively mild conditions of temperature and pressure in the absence of air into products which include a high heating value gas, high aromatic condensibles, char and coke all with physical and chemical properties suitable for the anticipated end uses. Two tons of CTC/DOE continuous coke of 6 in. {times} 5 in. {times} 4 in. size was produced in the Pilot Demonstration Unit. This coke was tested under actual foundry conditions in a 96 in. diameter commercial cupola. The test was run on the first shift on April 19, 1995. The coke sample was used as a direct replacement for 25 percent of the coke charge. A total of 51 scrap iron charges were run with the CTC/DOE continuous coke. Results of the test were excellent. The two main indicators improved., Tap temperature increased from an average of 2846{degrees}F to 2890{degrees}F. Carbon pickup improved from 3.49 percent C to 3.59 percent C when the CTC coke, hit the bed. These results are very meaningful because they cannot be measured in the lab. ChemChar Research, Inc. in Columbia, Missouri, is evaluating CTC chars as potential agents for removing pollutants from gas streams. Composite CTC char treated with the ChemChar activation process resulted in promising results. A 11.8 percent toluene adsorption and 13.4 percent monochlorobenzene adsorption were achieved with CTC char after activation.

  12. An integrated process for hydrogen-rich gas production from cotton stalks: The simultaneous gasification of pyrolysis gases and char in an entrained flow bed reactor.

    PubMed

    Chen, Zhiyuan; Zhang, Suping; Chen, Zhenqi; Ding, Ding

    2015-12-01

    An integrated process (pyrolysis, gas-solid simultaneous gasification and catalytic steam reforming) was utilized to produce hydrogen-rich gas from cotton stalks. The simultaneous conversion of the pyrolysis products (char and pyrolysis gases) was emphatically investigated using an entrained flow bed reactor. More carbon of char is converted into hydrogen-rich gas in the simultaneous conversion process and the carbon conversion is increased from 78.84% to 92.06% compared with the two stages process (pyrolysis and catalytic steam reforming). The distribution of tar components is also changed in this process. The polycyclic aromatic compounds (PACs) of tar are converted into low-ring compounds or even chain compounds due to the catalysis of char. In addition, the carbon deposition yield over NiO/MgO catalyst in the steam reforming process is approximately 4 times higher without the simultaneous process. The potential H2 yield increases from 47.71 to 78.19g/kg cotton stalks due to the simultaneous conversion process. PMID:26433156

  13. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, October 1, 1996--December 31, 1996

    SciTech Connect

    Winnick, J.

    1996-12-31

    An advanced process for the separation of hydrogen sulfide H{sub 2}S from coal gasification product streams through an electrochemical membrane is developed using funds from this grant. H{sub 2}S is removed from the syngas stream, split into hydrogen, which enriches the exiting syngas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need of a Claus process for sulfur recovery. To this extent the project presents a novel concept for improving utilization of coal for more efficient power generation. This quarter focused on replacing the MACOR cell housings with stainless steel, which is more industrially suitable. Three runs were attempted this quarter, with successful results achieved in Run 34. The purpose of these experiments was: (1) test the electrochemical membrane separator`s ability to concentrate CO{sub 2}, (2) test the electrochemical membrane separator`s ability to remove H{sub 2}S; and (3) test stainless steel as an alternative cell housing to MACOR as well as test nickel cathode performance at the reduced temperature.

  14. THEORETICAL INVESTIGATION OF SELECTED TRACE ELEMENTS IN COAL GASIFICATION PLANTS

    EPA Science Inventory

    The report gives results of a theoretical investigation of the disposition of five volatile trace elements (arsenic, boron, lead, selenium, and mercury) in SNG-producing coal gasification plants. Three coal gasification processes (dry-bottom Lurgi, Koppers-Totzek, and HYGAS) were...

  15. Coal conversion processes and analysis methodologies for synthetic fuels production. [technology assessment and economic analysis of reactor design for coal gasification

    NASA Technical Reports Server (NTRS)

    1979-01-01

    Information to identify viable coal gasification and utilization technologies is presented. Analysis capabilities required to support design and implementation of coal based synthetic fuels complexes are identified. The potential market in the Southeast United States for coal based synthetic fuels is investigated. A requirements analysis to identify the types of modeling and analysis capabilities required to conduct and monitor coal gasification project designs is discussed. Models and methodologies to satisfy these requirements are identified and evaluated, and recommendations are developed. Requirements for development of technology and data needed to improve gasification feasibility and economies are examined.

  16. The U.S. coal gasification program - Progress and projects

    NASA Astrophysics Data System (ADS)

    Miller, C. L.

    1980-08-01

    Progress in the development of coal gasification processes in the United States is reviewed. The evolution of coal gasifier design and processes is traced from first-generation facilities with fixed-bed reactors having separate areas for heating and devolatilization, syngas reactions and char gasification, through optimized second-generation reactors consisting of separate sections for the three stages, to third-generation hydropyrolysis reactors with a combined gasification reactor and secondary hydrogen generation and separation. The current status of development work on gasifiers is discussed, noting the availability of first-generation devices, the late development stages of the second generation and the early development status of the third generation. It is pointed out that although gasification technology exists that is ready for use, gasification plants are not in operation due to a range of institutional difficulties.

  17. ENCOAL Mild Coal Gasification Project

    SciTech Connect

    Not Available

    1992-02-01

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  18. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect

    Unknown

    2000-09-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  19. Evaluation of treatment technologies for water reuse in coal gasification

    SciTech Connect

    Luthy, R.G.; Campbell, J.R.; McLaughlin, L.; Walters, R.W.

    1980-07-01

    This investigation assessed significant issues and conducted bench scale experiments pertinent to management and reuse of coal coking and coal gasification process wastewaters. For the case of high-BTU coal gasification processes, the cooling tower is the most likely target for reuse of process wastewater. Treatment studies were performed with high BTU pilot coal gasification process quench waters to evaluate enhanced organic removal via powdered activated carbon-activated sludge treatment, and to evaluate a coal gasification wastewater treatment train comprised of sequential processing via ammonia removal, biological oxidation, lime-soda softening, granular activated carbon adsorption and reverse osmosis. Biological oxidation of coal gasification wastewater showed excellent removal efficiencies at moderate loadings; addition of powdered activated carbon provided lower effluent COD and color. Gasification process wastewater treated through activated carbon adsorption appears suitable for reuse as cooling tower make-up water. Screening studies indicate that reverse osmosis is an attractive technique for reducing wastewater dissolved solids. Additional study is needed to determine quality constraints regarding acceptable wastewater organic loading in cooling tower make-up water, and to evaluate possible release of toxic/hazardous organics to the environment via cooling tower drift. Additional follow-up work to this study is in progress to evaluate solvent extraction of gasification process wastewaters to recover phenolics and to reduce priority organic pollutants.

  20. Development of an advanced continuous mild gasification process for the production of co-products. Quarterly report, October--December 1995

    SciTech Connect

    O`Neal, G.W.

    1996-01-01

    Efforts continued to obtain financing for a commercial continuous formed coke plant. Discussions were held with two steel companies that are interested in producing coke for their use in steel production and foundry operations. Planning for production of 40 tons of foundry formed coke is underway. This coke will be used in two 20-ton tests at General Motors` foundries. During this production, it is planned to determine if a tunnel kiln can be used as a coking furnace as an alternative for a rotary hearth. A rotary hearth is about three times more costly than a competitive-sized tunnel kiln. Work continued on using Western non-caking coals to produce formed coke. Successful tests were made by using Eastern caking coals and other binders to permit using up to 50% of the cheaper Western non-caking coals in formed coke production. The primary objective of this project is to develop an advanced continuous mild gasification process and product upgrading processes which will be capable of eventual commercialization.

  1. The feasibility of using combined TiO2 photocatalysis oxidation and MBBR process for advanced treatment of biologically pretreated coal gasification wastewater.

    PubMed

    Xu, Peng; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng; Jia, Shengyong; Wang, Dexin; Li, Kun; Zhao, Qian

    2015-08-01

    The study examined the feasibility of using combined heterogeneous photocatalysis oxidation (HPO) and moving bed biofilm reactor (MBBR) process for advanced treatment of biologically pretreated coal gasification wastewater (CGW). The results indicated that the TOC removal efficiency was significantly improved in HPO. Gas chromatography-mass spectrometry (GC-MS) analysis indicated that the HPO could be employed to eliminate bio-refractory and toxic compounds. Meanwhile, the BOD5/COD of the raw wastewater was increased from 0.08 to 0.49. Furthermore, in the integration of TiO2 photocatalysis oxidation and MBBR process, the effluent of COD, BOD5, TOC, NH4(+)-N and TN were 22.1 mg/L, 1.1 mg/L, 11.8 mg/L, 4.1mg/L and 13.7 mg/L, respectively, which all met class-I criteria of the Integrated Wastewater Discharge Standard (GB18918-2002, China). The total operating cost was 2.8CNY/t. Therefore, there is great potential for the combined system in engineering applications as a final treatment for biologically pretreated CGW. PMID:25934578

  2. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industrys energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

  3. Continuous Removal of Coal-Gasification Residue

    NASA Technical Reports Server (NTRS)

    Collins, Earl R., Jr.; Suitor, J.; Dubis, D.

    1986-01-01

    Continuous-flow hopper processes solid residue from coal gasification, converting it from ashes, cinders, and clinkers to particles size of sand granules. Unit does not require repeated depressurization of lockhopper to admit and release materials. Therefore consumes less energy. Because unit has no airlock valves opened and closed repeatedly on hot, abrasive particles, subjected to lesser wear. Coal-gasification residue flows slowly through pressure-letdown device. Material enters and leaves continuously. Cleanout door on each pressure-letdown chamber allows access for maintenance and emergencies.

  4. Gasification of various coals in molten salts

    SciTech Connect

    Yosim, S.J.; Barclay, K.M.

    1980-01-01

    The utilization of the US coal reserves in a manner which does not add to the existing pollution problem is of utmost importance in the interest of conservation of more valuable natural resources in the national economy. Gasification of coal and generation of clean fuel gas offers one of the most promising approaches to the utilization of coal. It has been assigned a high priority in the US Energy Development Program. Several of the coal gasification processes presently under development are now at the initial pilot plant operation stage. One of these processes is the Rockwell International Molten Salt Coal Gasification Process (Rockgas Process). In this process, the coal is gasified at a temperature of about 1800/sup 0/F and at pressures up to 30 atm by reaction with air in a highly turbulent mixture of molten sodium carbonate containing sodium sulfide, ash, and unreacted carbonaceous material. The sulfur and ash of the coal are retained in the melt, a small stream of which is continuously circulated through a process system for regeneration of the sodium carbonate, removal of the ash, and recovery of elemental sulfur. A molten salt coal gasification process development unit capable of converting 1 ton of coal per hour into low-Btu fuel gas at pressures up to 20 atm is currently undergoing testing under contract to the Department of Energy. Preliminary to the PDU, a considerable amount of laboratory testing took place. These tests were conducted in a bench-scale, 6-in.-dia gasifier in which coals of different rank were continuously gasified in the melt. The tests resulted in a better understanding of the gasification process. The purpose of this paper is to describe these laboratory tests and to discuss some of the chemistry taking place in the gasifier. Emphasis is placed on the effect of coal rank on the chemistry.

  5. Numerical simulation of waste tyres gasification.

    PubMed

    Janajreh, Isam; Raza, Syed Shabbar

    2015-05-01

    Gasification is a thermochemical pathway used to convert carbonaceous feedstock into syngas (CO and H2) in a deprived oxygen environment. The process can accommodate conventional feedstock such as coal, discarded waste including plastics, rubber, and mixed waste owing to the high reactor temperature (1000?C-1600?C). Pyrolysis is another conversion pathway, yet it is more selective to the feedstock owing to the low process temperature (350?C-550?C). Discarded tyres can be subjected to pyrolysis, however, the yield involves the formation of intermediate radicals additional to unconverted char. Gasification, however, owing to the higher temperature and shorter residence time, is more opted to follow quasi-equilibrium and being predictive. In this work, tyre crumbs are subjected to two levels of gasification modelling, i.e. equilibrium zero dimension and reactive multi-dimensional flow. The objective is to investigate the effect of the amount of oxidising agent on the conversion of tyre granules and syngas composition in a small 20?kW cylindrical gasifier. Initially the chemical compositions of several tyre samples are measured following the ASTM procedures for proximate and ultimate analysis as well as the heating value. The measured data are used to carry out equilibrium-based and reactive flow gasification. The result shows that both models are reasonably predictive averaging 50% gasification efficiency, the devolatilisation is less sensitive than the char conversion to the equivalence ratio as devolatilisation is always complete. In view of the high attained efficiency, it is suggested that the investigated tyre gasification system is economically viable. PMID:25755167

  6. Novel Feed System for Pressurised Gasification

    E-print Network

    High Pressure Gasifier Pressurised Lock Hopper Pressure Equalisation Atmospheric Top Hopper Atmospheric Water Pump Atmospheric Middle Hopper Valve 2 High Pressure Collection Vessel Bottom Hopper at Pressure of process downtime in the field of high pressure gasification, and are vastly inefficient in their operation

  7. Underground coal gasification. Presentations

    SciTech Connect

    2007-07-01

    The 8 presentations are: underground coal gasification (UCG) and the possibilities for carbon management (J. Friedmann); comparing the economics of UCG with surface gasification technologies (E. Redman); Eskom develops UCG technology project (C. Gross); development and future of UCG in the Asian region (L. Walker); economically developing vast deep Powder River Basin coals with UCG (S. Morzenti); effectively managing UCG environmental issues (E. Burton); demonstrating modelling complexity of environmental risk management; and UCG research at the University of Queensland, Australia (A.Y. Klimenko).

  8. Gasification and combustion modeling for porous char particles

    E-print Network

    Singer, Simcha Lev

    2012-01-01

    Gasification and combustion of porous char particles occurs in many industrial applications. Reactor-scale outputs of importance depend critically on processes that occur at the particle-scale. Because char particles often ...

  9. Methane Production from Catalytic Wet Gasification of Animal Manure

    Technology Transfer Automated Retrieval System (TEKTRAN)

    This research investigates the technical and economical viability of a proprietary catalytic wet gasification process in treating animal wastewater, capturing nutrients, destroying pharmaceutically active compounds (PACs) and estrogens, and producing methane. This study reviews and analyzes physicoc...

  10. Coal gasification: New challenge for the Beaumont rotary feeder

    NASA Technical Reports Server (NTRS)

    Stelian, J.

    1977-01-01

    The use of rotary feeders in the coal gasification process is described with emphasis on the efficient conversion of coal to clean gaseous fuels. Commercial applications of the rotary feeder system are summarized.

  11. EARLY ENTRANCE CO-PRODUCTION PLANT - DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect

    John W. Rich

    2003-12-01

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the techno-economic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from July 1, 2003 through September 30, 2003. The DOE/WMPI Cooperative Agreement was modified on May 2003 to expand the project team to include Shell Global Solutions, U.S. and Uhde GmbH as the engineering contractor. The addition of Shell and Uhde strengthen both the technical capability and financing ability of the project. Uhde, as the prime EPC contractor, has the responsibility to develop a LSTK (lump sum turnkey) engineering design package for the EECP leading to the eventual detailed engineering, construction and operation of the proposed concept. Major technical activities during the reporting period include: (1) finalizing contractual agreements between DOE, Uhde and other technology providers, focusing on intellectual-property-right issues, (2) Uhde's preparation of a LSTK project execution plan and other project engineering procedural documents, and (3) Uhde's preliminary project technical concept assessment and trade-off evaluations.

  12. GASIFICATION FOR DISTRIBUTED GENERATION

    SciTech Connect

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01

    A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  13. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology

    SciTech Connect

    Swanson, Michael; Henderson, Ann

    2012-04-01

    The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPEs technology refines coal by employing a novel catalyst to crack the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild catalytic gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPEs catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to fluidize the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A PdCu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

  14. Gasification of black liquor

    DOEpatents

    Kohl, A.L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  15. Gasification of black liquor

    DOEpatents

    Kohl, Arthur L. (Woodland Hills, CA)

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  16. Gasification of solid fuel

    SciTech Connect

    Brachthauser, K.; Kaimann, W.

    1980-04-29

    Solid fuel is acted on by a gasifying medium in a fluidized bed. The resulting gas enters a cyclone having an outlet for solid particles connected to a gasification chamber in which the particles are gasified by a separate stream of gasifying medium supplied by an injector.

  17. Start-up method for coal gasification plant

    SciTech Connect

    Farnia, K.; Petit, P.J.

    1983-04-05

    A method is disclosed for initiating operation of a coal gasification plant which includes a gasification reactor and gas cleansing apparatus fabricated in part from materials susceptible to chloride induced stress corrosion cracking the presence of oxygen. The reactor is preheated by combusting a stoichiometric mixture of air and fuel to produce an exhaust gas which is then diluted with steam to produce product gas which contains essentially no free oxygen. The product gas heats the reactor to a temperature profile necessary to maintain autothermic operation of the gasification process while maintaining air oxygen-free environment within the plant apparatus while chlorine is liberated from coal being gasified.

  18. Integrated bioenergy conversion concepts for small scale gasification power systems

    NASA Astrophysics Data System (ADS)

    Aldas, Rizaldo Elauria

    Thermal and biological gasification are promising technologies for addressing the emerging concerns in biomass-based renewable energy, environmental protection and waste management. However, technical barriers such as feedstock quality limitations, tars, and high NOx emissions from biogas fueled engines impact their full utilization and make them suffer at the small scale from the need to purify the raw gas for most downstream processes, including power generation other than direct boiler use. The two separate gasification technologies may be integrated to better address the issues of power generation and waste management and to complement some of each technologies' limitations. This research project investigated the technical feasibility of an integrated thermal and biological gasification concept for parameters critical to appropriately matching an anaerobic digester with a biomass gasifier. Specific studies investigated the thermal gasification characteristics of selected feedstocks in four fixed-bed gasification experiments: (1) updraft gasification of rice hull, (2) indirect-heated gasification of rice hull, (3) updraft gasification of Athel wood, and (4) downdraft gasification of Athel and Eucalyptus woods. The effects of tars and other components of producer gas on anaerobic digestion at mesophilic temperature of 36C and the biodegradation potentials and soil carbon mineralization of gasification tars during short-term aerobic incubation at 27.5C were also examined. Experiments brought out the ranges in performance and quality and quantity of gasification products under different operating conditions and showed that within the conditions considered in the study, these gasification products did not adversely impact the overall digester performance. Short-term aerobic incubation demonstrated variable impacts on carbon mineralization depending on tar and soil conditions. Although tars exhibited low biodegradation indices, degradation may be improved if the microorganisms used to deal with tars are selected and pre-conditioned to the tar environment. Overall, the results provided a basis for operational and design strategy for a combined gasification system but further study is recommended such as determination of the impacts in terms of emissions, power, efficiency and costs associated with the use of producer gas-enriched biogas taking advantage of hydrogen enrichment to reduce NOx and other pollutants in reciprocating engines and other energy conversion systems.

  19. Apparatus for solar coal gasification

    DOEpatents

    Gregg, D.W.

    1980-08-04

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  20. Fabrication of Pd/Pd-Alloy Films by Surfactant Induced Electroless Plating for Hydrogen Separation from Advanced Coal Gasification Processes

    SciTech Connect

    Ilias, Shamsuddin; Kumar, Dhananjay

    2012-07-31

    Dense Pd, Pd-Cu and Pd-Ag composite membranes on microporous stainless steel substrate (MPSS) were fabricated by a novel electroless plating (EP) process. In the conventional Pd-EP process, the oxidation-reduction reactions between Pd-complex and hydrazine result in an evolution of NH{sub 3} and N{sub 2} gas bubbles. When adhered to the substrate surface and in the pores, these gas bubbles hinder uniform Pd-film deposition which results in dendrite growth leading to poor film formation. This problem was addressed by introducing cationic surfactant in the electroless plating process known as surfactant induced electroless plating (SIEP). The unique features of this innovation provide control of Pd-deposition rate, and Pd-grain size distribution. The surfactant molecules play an important role in the EP process by tailoring grain size and the process of agglomeration by removing tiny gas bubbles through adsorption at the gas-liquid interface. As a result surfactant can tailor a nanocrystalline Pd, Cu and Ag deposition in the film resulting in reduced membrane film thickness. Also, it produces a uniform, agglomerated film structure. The Pd-Cu and Pd-Ag membranes on MPSS support were fabricated by sequential deposition using SIEP method. The pre- and post-annealing characterizations of these membranes (Pd, Pd-Cu and Pd-Ag on MPSS substrate) were carried out by SEM, EDX, XRD, and AFM studies. The SEM images show significant improvement of the membrane surface morphology, in terms of metal grain structures and grain agglomeration compared to the membranes fabricated by conventional EP process. The SEM images and helium gas-tightness studies indicate that dense and thinner films of Pd, Pd-Cu and Pd-Ag membranes can be produced with shorter deposition time using surfactant. H{sub 2} Flux through the membranes fabricated by SIEP shows large improvement compared to those by CEP with comparable permselectivity. Pd-MPSS composite membrane was subjected to test for long term performance and thermal cycling (573 - 723 - 573 K) at 15 psi pressure drop for 1200 hours. Pd membranes showed excellent hydrogen permeability and thermal stability during the operational period. Under thermal cycling (573 K - 873 K - 573 K), Pd-Cu-MPSS membrane was stable and retained hydrogen permeation characteristics for over three months of operation. From this limited study, we conclude that SIEP is viable method for fabrication of defect-free, robust Pd-alloy membranes for high-temperature H{sub 2}-separation applications.

  1. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    SciTech Connect

    1998-12-31

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  2. GASIFICATION BASED BIOMASS CO-FIRING - PHASE I

    SciTech Connect

    Babul Patel; Kevin McQuigg; Robert F. Toerne

    2001-12-01

    Biomass gasification offers a practical way to use this locally available fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be fed directly into the boiler. This strategy of co-firing is compatible with variety of conventional boilers including natural gas fired boilers as well as pulverized coal fired and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a reduction in the primary fossil fuel consumption in the boiler and thereby reducing the greenhouse gas emissions to the atmosphere.

  3. Conceptual design report -- Gasification Product Improvement Facility (GPIF)

    SciTech Connect

    Sadowski, R.S.; Skinner, W.H.; House, L.S.; Duck, R.R.; Lisauskas, R.A.; Dixit, V.J.; Morgan, M.E.; Johnson, S.A.; Boni, A.A.

    1994-09-01

    The problems heretofore with coal gasification and IGCC concepts have been their high cost and historical poor performance of fixed-bed gasifiers, particularly on caking coals. The Gasification Product Improvement Facility (GPIF) project is being developed to solve these problems through the development of a novel coal gasification invention which incorporates pyrolysis (carbonization) with gasification (fixed-bed). It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration caused in the conventional process of gradually heating coal through the 400 F to 900 F range. In so doing, the coal is rapidly heated sufficiently such that the coal tar exists in gaseous form rather than as a liquid. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can become chemically bound to aluminosilicates in (or added to) the ash. To reduce NH{sub 3} and HCN from fuel born nitrogen, steam injection is minimized, and residual nitrogen compounds are partially chemically reduced in the cracking stage in the upper gasifier region. Assuming testing confirms successful deployment of all these integrated processes, future IGCC applications will be much simplified, require significantly less mechanical components, and will likely achieve the $1,000/kWe commercialized system cost goal of the GPIF project. This report describes the process and its operation, design of the plant and equipment, site requirements, and the cost and schedule. 23 refs., 45 figs., 23 tabs.

  4. Evaluation of gasification and gas-cleanup processes for use in molten-carbonate fuel-cell power plants

    NASA Astrophysics Data System (ADS)

    Jablonski, G.; Alvin, M. A.; Wenglarz, R. A.; Patel, P.

    1981-07-01

    A draft of the gasifier listing, a low temperature gas cleanup system listing and data acquisition for the hot gas cleaning systems listing were completed. Iron oxide, dolomite, zinc oxide, molten carbonate and other such systems were included in that listing. The molten carbonate fuel cell (MCFC) contaminant data available in the open literature are reported. Particulate and chemical species for assessing the effect of contaminants on MCFC operating characteristics are thermodynamically evaluated. Data and process insights, indispensable to the evaluation of suitable coal gas supply systems for molten carbonate fuel cell power plants are provided.

  5. High temperature steam gasification of solid wastes: Characteristics and kinetics

    NASA Astrophysics Data System (ADS)

    Gomaa, Islam Ahmed

    Greater use of renewable energy sources is of pinnacle importance especially with the limited reserves of fossil fuels. It is expected that future energy use will have increased utilization of different energy sources, including biomass, municipal solid wastes, industrial wastes, agricultural wastes and other low grade fuels. Gasification is a good practical solution to solve the growing problem of landfills, with simultaneous energy extraction and nonleachable minimum residue. Gasification also provides good solution to the problem of plastics and rubber in to useful fuel. The characteristics and kinetics of syngas evolution from the gasification of different samples is examined here. The characteristics of syngas based on its quality, distribution of chemical species, carbon conversion efficiency, thermal efficiency and hydrogen concentration has been examined. Modeling the kinetics of syngas evolution from the process is also examined. Models are compared with the experimental results. Experimental results on the gasification and pyrolysis of several solid wastes, such as, biomass, plastics and mixture of char based and plastic fuels have been provided. Differences and similarities in the behavior of char based fuel and a plastic sample has been discussed. Global reaction mechanisms of char based fuel as well polystyrene gasification are presented based on the characteristic of syngas evolution. The mixture of polyethylene and woodchips gasification provided superior results in terms of syngas yield, hydrogen yield, total hydrocarbons yield, energy yield and apparent thermal efficiency from polyethylene-woodchips blends as compared to expected weighed average yields from gasification of the individual components. A possible interaction mechanism has been established to explain the synergetic effect of co-gasification of woodchips and polyethylene. Kinetics of char gasification is presented with special consideration of sample temperature, catalytic effect of ash, geometric changes of pores inside char and diffusion limitations inside and outside the char particle.

  6. EARLY ENTRANCE CO-PRODUCTION PLANT--DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect

    John W. Rich

    2003-06-01

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the technoeconomic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from January 1, 2003 through March 31, 2003. Phase I Task 6 activities of Preliminary Site Analysis were documented and reported as a separate Topical Report on February 2003. Most of the other technical activities were on hold pending on DOE's announcement of the Clean Coal Power Initiative (CCPI) awards. WMPI was awarded one of the CCPI projects in late January 2003 to engineer, construct and operate a first-of-kind gasification/liquefaction facility in the U.S. as a continued effort for the current WMPI EECP engineering feasibility study. Since then, project technical activities were focused on: (1) planning/revising the existing EECP work scope for transition into CCPI, and (2) ''jump starting'' all environmentally related work in pursue of NEPA and PA DEP permitting approval.

  7. Development of biological coal gasification (MicGas process): 13th Quarterly report, [July 1--September 30, 1993

    SciTech Connect

    Not Available

    1993-10-28

    In examining methods for enhancing the biomethanation of TxL, several experiments were conducted to study the mechanisms of lowering the pH during biomethanation of Texas lignite (TxL) at higher solids loadings. Results indicated that: Treatment of TxL with different pH solutions did not influence the biomethanation process; The decrease in methane production at higher solids loadings still needs further investigations; Anaerobic conditions containing deoxygenated nitrogen:carbon dioxide provide better methanation of TxL; The most promising combination between the isolates from Mic-1 and Mic-4 was found to be combination D (KS14RMK8-1458); The KS14RMK8 shows the highest accumulation of acetate in the cell-free culture broth from this consortium.

  8. Development of Highly Durable and Reactive Regenerable Magnesium-Based Sorbents for CO2 Separation in Coal Gasification Process

    SciTech Connect

    Javad Abbasian; Armin Hassanzadeh Khayyat; Rachid B. Slimane

    2005-06-01

    The specific objective of this project was to develop physically durable and chemically regenerable MgO-based sorbents that can remove carbon dioxide from raw coal gas at operating condition prevailing in IGCC processes. A total of sixty two (62) different sorbents were prepared in this project. The sorbents were prepared either by various sol-gel techniques (22 formulations) or modification of dolomite (40 formulations). The sorbents were prepared in the form of pellets and in granular forms. The solgel based sorbents had very high physical strength, relatively high surface area, and very low average pore diameter. The magnesium content of the sorbents was estimated to be 4-6 % w/w. To improve the reactivity of the sorbents toward CO{sub 2}, The sorbents were impregnated with potassium salts. The potassium content of the sorbents was about 5%. The dolomite-based sorbents were prepared by calcination of dolomite at various temperature and calcination environment (CO{sub 2} partial pressure and moisture). Potassium carbonate was added to the half-calcined dolomite through wet impregnation method. The estimated potassium content of the impregnated sorbents was in the range of 1-6% w/w. In general, the modified dolomite sorbents have significantly higher magnesium content, larger pore diameter and lower surface area, resulting in significantly higher reactivity compared to the sol-gel sorbents. The reactivities of a number of sorbents toward CO{sub 2} were determined in a Thermogravimetric Analyzer (TGA) unit. The results indicated that at the low CO{sub 2} partial pressures (i.e., 1 atm), the reactivities of the sorbents toward CO{sub 2} are very low. At elevated pressures (i.e., CO{sub 2} partial pressure of 10 bar) the maximum conversion of MgO obtained with the sol-gel based sorbents was about 5%, which corresponds to a maximum CO{sub 2} absorption capacity of less than 1%. The overall capacity of modified dolomite sorbents were at least one order of magnitude higher than those of the sol-gel based sorbents. The results of the tests conducted with various dolomite-based sorbent indicate that the reactivity of the modified dolomite sorbent increases with increasing potassium concentration, while higher calcination temperature adversely affects the sorbent reactivity. Furthermore, the results indicate that as long as the absorption temperature is well below the equilibrium temperature, the reactivity of the sorbent improves with increasing temperature (350-425 C). As the temperature approaches the equilibrium temperature, because of the significant increase in the rate of reverse (i.e., regeneration) reaction, the rate of CO{sub 2} absorption decreases. The results of cyclic tests show that the reactivity of the sorbent gradually decreases in the cyclic process. To improve long-term durability (i.e., reactivity and capacity) of the sorbent, the sorbent was periodically re-impregnated with potassium additive and calcined. The results indicate that, in general, re-treatment improves the performance of the sorbent, and that, the extent of improvement gradually decreases in the cyclic process. The presence of steam significantly enhances the sorbent reactivity and significantly decreases the rate of decline in sorbent deactivation in the cyclic process.

  9. Plasma gasification of municipal solid waste

    SciTech Connect

    Carter, G.W.; Tsangaris, A.V.

    1995-12-31

    Resorption Canada Limited (RCL) has conducted extensive operational testing with plasma technology in their plasma facility near Ottawa, Ontario, Canada to develop an environmentally friendly waste disposal process. Plasma technology, when utilized in a reactor vessel with the exclusion of oxygen, provides for the complete gasification of all combustibles in source materials with non-combustibles being converted to a non-hazardous slag. The energy and environmental characteristics of the plasma gasification of carbonaceous waste materials were studied over a period of eight years during which RCL completed extensive experimentation with MSW. A plasma processing system capable of processing 200--400 lbs/hr of MSW was designed and built. The experimentation on MSW concentrated on establishing the optimum operating parameters and determining the energy and environmental characteristics at these operating parameters.

  10. Biomass Gasification Combined Cycle

    SciTech Connect

    Judith A. Kieffer

    2000-07-01

    Gasification combined cycle continues to represent an important defining technology area for the forest products industry. The ''Forest Products Gasification Initiative'', organized under the Industry's Agenda 2020 technology vision and supported by the DOE ''Industries of the Future'' program, is well positioned to guide these technologies to commercial success within a five-to ten-year timeframe given supportive federal budgets and public policy. Commercial success will result in significant environmental and renewable energy goals that are shared by the Industry and the Nation. The Battelle/FERCO LIVG technology, which is the technology of choice for the application reported here, remains of high interest due to characteristics that make it well suited for integration with the infrastructure of a pulp production facility. The capital cost, operating economics and long-term demonstration of this technology area key input to future economically sustainable projects and must be verified by the 200 BDT/day demonstration facility currently operating in Burlington, Vermont. The New Bern application that was the initial objective of this project is not currently economically viable and will not be implemented at this time due to several changes at and around the mill which have occurred since the inception of the project in 1995. The analysis shows that for this technology, and likely other gasification technologies as well, the first few installations will require unique circumstances, or supportive public policies, or both to attract host sites and investors.

  11. Development of biological coal gasification (MicGAS Process). Fifteenth quarterly report, [January 1, 1994--March 31, 1994

    SciTech Connect

    Srivastava, K.C.

    1994-04-26

    Maximum methane production was obtained in the experimental vials that contained 0.2% SNTM supplemented with 10 mM sodium citrate and 1% TxL (144 cc), while in the control vials CH{sub 4} production was only 58 cc. The conversion efficiency was 24%. This clearly shows citrate to be an important mediator for the formation of acetate (main precursor for CH{sub 4} formation) in the glyoxylate cycle, on the one hand, and as a sequestering agent, on the other. These results further indicate that citrate can, be successfully used as co-substrate for enhancement of the TxL biogasification process. The results obtained reconfirmed our hypothesis that the metals (such as Fe{sup 3+}, Mn{sup 2+}, Mg{sup 2+}, CO{sup 2+}, Zr{sup 2+}, etc., present in the coal structure) are chelated/sequestered by the addition of citrate. Mass balance calculations show that this increase in CH{sup 4} production is due to the biomethanation of TxL and not because of the chemical conversion of co-substrate(s) to CH{sub 4} (Table 1). The effect of sodium citrate on biomethanation of TXL from the first experiment ``Effect of co-substrate addition No. 1`` was reconfirmed in this experiment. The peak in acetate concentration (1317 ppm) on day 7 was followed by a rapid conversion of this precursor to CH{sub 4} (Figure 16). The VFA data obtained from both experiments (``Effect of co-substrate addition No. 1 and No. 2``) confirms the hypothesis that citrate and methanol can significantly enhance the biomethanation of TxL (Figure 17).

  12. HIGH TEMPERATURE REMOVAL OF H{sub 2}S FROM COAL GASIFICATION PROCESS STREAMS USING AN ELECTROCHEMICAL MEMBRANE SYSTEM

    SciTech Connect

    Jack Winnick; Meilin Liu

    2003-06-01

    A bench scale set-up was constructed to test the cell performance at 600-700 C and 1 atm. The typical fuel stream inlet proportions were 34% CO, 22% CO{sub 2}, 35% H{sub 2}, 8% H{sub 2}O, and 450-2000 ppm H{sub 2}S. The fundamental transport restrictions for sulfur species in an electrochemical cell were examined. Temperature and membrane thickness were varied to examine how these parameters affect the maximum flux of H{sub 2}S removal. It was found that higher temperature allows more sulfide species to enter the electrolyte, thus increasing the sulfide flux across the membrane and raising the maximum flux of H{sub 2}S removal. The results identify sulfide diffusion across the membrane as the rate-limiting step in H{sub 2}S removal. The maximum H{sub 2}S removal flux of 1.1 x 10-6 gmol H{sub 2}S min{sup -1} cm{sup -2} (or 3.5 mA cm{sup -2}) was obtained at 650 C, with a membrane that was 0.9 mm thick, 36% porous, and had an estimated tortuosity of 3.6. Another focus of this thesis was to examine the stability of cathode materials in full cell trials. A major hurdle that remains in process scale-up is cathode selection, as the lifetime of the cell will depend heavily on the lifetime of the cathode material, which is exposed to very sour gas. Materials that showed success in the past (i.e. cobalt sulfides and Y{sub 0.9}Ca{sub 0.1}FeO{sub 3}) were examined but were seen to have limitations in operating environment and temperature. Therefore, other novel metal oxide compounds were studied to find possible candidates for full cell trials. Gd{sub 2}TiMoO{sub 7} and La{sub 0.7}Sr{sub 0.3}VO{sub 3} were the compounds that retained their structure best even when exposed to high H{sub 2}S, CO{sub 2}, and H{sub 2}O concentrations.

  13. The direction and scope of the U.S. Department of Energy's surface coal gasification program

    NASA Astrophysics Data System (ADS)

    Miller, C. L.

    The Coal Gasification Program is briefly reviewed with reference to the program development strategy, analysis of energy consumption patterns, technological capabilities of coal gasification, and the program plan. The program plan includes: technical support to improving first generation gasifiers and systems, the development of advanced second generation medium-Btu/synthesis gasifiers and gasification systems, and the development of new, sophisticated third generation processes for the production of high-Btu gas.

  14. Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994

    SciTech Connect

    1995-05-01

    This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

  15. Sewage sludge gasification: First studies

    SciTech Connect

    Garcia-Bacaicoa, P.; Bilbao, R.; Uson, C.

    1995-11-01

    Wastewater treatment installations produce a large quantity of sewage sludge, the disposal and treatment of which causes several problems because of its volume, its toxic organic constituents and the heavy metals that it contains. Certain methods of treatment and disposal do exist, but they are not entirely satisfactory. Moreover, it is important to develop a technology for the adequate treatment of sewage sludge in order to reduce the environmental problem and the costs of treatment. It can be assumed that gasification is a suitable technology because it reduces the waste volume, destroys the toxic organic compounds and fixes the heavy metals in the resultant solid. In order to gain knowledge of the processes occurring in the gasifier, the results obtained in experiments on the thermal decomposition of sewage sludge at different heating rates are shown.

  16. Calculation of the fixed bed coal gasification regimes by the use of thermodynamic model with macrokinetic constraints

    NASA Astrophysics Data System (ADS)

    Donskoi, I. G.; Keiko, A. V.; Kozlov, A. N.; Svishchev, D. A.; Shamanskii, V. A.

    2013-12-01

    We discuss an equilibrium model of a fixed-bed solid fuel gasification process that takes into account macrokinetic constraints imposed on the rates of heterophase processes and allows the pyrolysis and gasification processes to be described in a fairly simple manner with the use of thermal analysis data. The results of calculations are compared with the measured parameters characterizing the Azeisk coal steam-air gasification process that were obtained in experiments on a laboratory setup.

  17. Fluidized bed injection assembly for coal gasification

    DOEpatents

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  18. Considerations Based on Reaction Rate on Char Gasification Behavior in Two-stage Gasifier for Biomass

    NASA Astrophysics Data System (ADS)

    Taniguchi, Miki; Nishiyama, Akio; Sasauchi, Kenichi; Ito, Yusuke; Akamatsu, Fumiteru

    In order to develop a small-scale gasifier in which biomass can be converted to energy with high efficiency, we planned a gasification process that consists of two parts: pyrolysis part (rotary kiln) and gasification part (downdraft gasifier). We performed fundamental experiments on gasification part and discussed the appropriate conditions such as air supply location, air ratio, air temperature and hearth load. We considered the results by calculating reaction rates of representative reactions on char gasification part and found that water gas reaction is dominant in the reduction area and its behavior gives important information to decide the adequate length of the char layer.

  19. GASIFICATION BASED BIOMASS CO-FIRING

    SciTech Connect

    Babul Patel; Kevin McQuigg; Robert Toerne; John Bick

    2003-01-01

    Biomass gasification offers a practical way to use this widespread fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be used as a supplemental fuel in an existing utility boiler. This strategy of co-firing is compatible with a variety of conventional boilers including natural gas and oil fired boilers, pulverized coal fired conventional and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a wider selection of biomass as fuel and providing opportunity in reduction of carbon dioxide emissions to the atmosphere through the commercialization of this technology. This study evaluated two plants: Wester Kentucky Energy Corporation's (WKE's) Reid Plant and TXU Energy's Monticello Plant for technical and economical feasibility. These plants were selected for their proximity to large supply of poultry litter in the area. The Reid plant is located in Henderson County in southwest Kentucky, with a large poultry processing facility nearby. Within a fifty-mile radius of the Reid plant, there are large-scale poultry farms that generate over 75,000 tons/year of poultry litter. The local poultry farmers are actively seeking environmentally more benign alternatives to the current use of the litter as landfill or as a farm spread as fertilizer. The Monticello plant is located in Titus County, TX near the town of Pittsburgh, TX, where again a large poultry processor and poultry farmers in the area generate over 110,000 tons/year of poultry litter. Disposal of this litter in the area is also a concern. This project offers a model opportunity to demonstrate the feasibility of biomass co-firing and at the same time eliminate poultry litter disposal problems for the area's poultry farmers.

  20. Solar coal gasification reactor with pyrolysis gas recycle

    DOEpatents

    Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

    1983-01-01

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  1. PNNL Coal Gasification Research

    SciTech Connect

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  2. Catalytic steam gasification of bagasse for the production of methanol

    SciTech Connect

    Baker, E.G.; Brown, M.D.

    1983-12-01

    Pacific Northwest Laboratory (PNL) tested the catalytic gasification of bagasse for the production of methanol synthesis gas. The process uses steam, indirect heat, and a catalyst to produce synthesis gas in one step in fluidized bed gasifier. Both laboratory and process development scale (nominal 1 ton/day) gasifiers were used to test two different catalyst systems: (1) supported nickel catalysts and (2) alkali carbonates doped on the bagasse. This paper presents the results of laboratory and process development unit gasification tests and includes an economic evaluation of the process. 20 references, 6 figures, 9 tables.

  3. Gasification Plant Cost and Performance Optimization

    SciTech Connect

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  4. Solar heated fluidized bed gasification system

    NASA Technical Reports Server (NTRS)

    Qader, S. A. (inventor)

    1981-01-01

    A solar-powered fluidized bed gasification system for gasifying carbonaceous material is presented. The system includes a solar gasifier which is heated by fluidizing gas and steam. Energy to heat the gas and steam is supplied by a high heat capacity refractory honeycomb which surrounds the fluid bed reactor zone. The high heat capacity refractory honeycomb is heated by solar energy focused on the honeycomb by solar concentrator through solar window. The fluid bed reaction zone is also heated directly and uniformly by thermal contact of the high heat capacity ceramic honeycomb with the walls of the fluidized bed reactor. Provisions are also made for recovering and recycling catalysts used in the gasification process. Back-up furnace is provided for start-up procedures and for supplying heat to the fluid bed reaction zone when adequate supplies of solar energy are not available.

  5. Solar heated fluidized bed gasification system

    NASA Astrophysics Data System (ADS)

    Qader, S. A.

    1981-09-01

    A solar-powered fluidized bed gasification system for gasifying carbonaceous material is presented. The system includes a solar gasifier which is heated by fluidizing gas and steam. Energy to heat the gas and steam is supplied by a high heat capacity refractory honeycomb which surrounds the fluid bed reactor zone. The high heat capacity refractory honeycomb is heated by solar energy focused on the honeycomb by solar concentrator through solar window. The fluid bed reaction zone is also heated directly and uniformly by thermal contact of the high heat capacity ceramic honeycomb with the walls of the fluidized bed reactor. Provisions are also made for recovering and recycling catalysts used in the gasification process. Back-up furnace is provided for start-up procedures and for supplying heat to the fluid bed reaction zone when adequate supplies of solar energy are not available.

  6. Apparatus and method for solar coal gasification

    DOEpatents

    Gregg, David W. (Moraga, CA)

    1980-01-01

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  7. Supercritical droplet gasification experiments with forced convection

    NASA Technical Reports Server (NTRS)

    Litchford, Ron; Parigger, Chris; Jeng, San-Mou

    1992-01-01

    Preliminary results of a comprehensive experimental program are presented which offer the first direct observations of suspended n-heptane droplet gasifications in pure nitrogen with forced convection without the interference to optical probing associated with a flame. Measurements show attainment of a wet-bulb temperature until reduced pressures exceed about 1.0 under supercritical gas temperatures. Thereafter, temperature measurements indicate fully transient heat-up through the critical temperature. The surface is found to regress in a continuous manner with the measured temperature approaching the critical value at the end of the droplet lifetime under supercritical conditions with very mild level of convection. At increased level of convection for the same ambient conditions, similar sized droplets will undergo significant deformation during the gasification process until partially convected away as a dense vapor cloud as the critical temperature is approached.

  8. Modeling and comparative assessment of municipal solid waste gasification for energy production.

    PubMed

    Arafat, Hassan A; Jijakli, Kenan

    2013-08-01

    Gasification is the thermochemical conversion of organic feedstocks mainly into combustible syngas (CO and H(2)) along with other constituents. It has been widely used to convert coal into gaseous energy carriers but only has been recently looked at as a process for producing energy from biomass. This study explores the potential of gasification for energy production and treatment of municipal solid waste (MSW). It relies on adapting the theory governing the chemistry and kinetics of the gasification process to the use of MSW as a feedstock to the process. It also relies on an equilibrium kinetics and thermodynamics solver tool (Gasify()) in the process of modeling gasification of MSW. The effect of process temperature variation on gasifying MSW was explored and the results were compared to incineration as an alternative to gasification of MSW. Also, the assessment was performed comparatively for gasification of MSW in the United Arab Emirates, USA, and Thailand, presenting a spectrum of socioeconomic settings with varying MSW compositions in order to explore the effect of MSW composition variance on the products of gasification. All in all, this study provides an insight into the potential of gasification for the treatment of MSW and as a waste to energy alternative to incineration. PMID:23726119

  9. Gasification of refuse derived fuel in the Battelle high throughput gasification system

    SciTech Connect

    Paisley, M.A.; Creamer, K.S.; Tweksbury, T.L.; Taylor, D.R. )

    1989-07-01

    This report presents the results of an experimental program to demonstrate the suitability of the Battelle High Throughput Gasification Process to non-wood biomass fuels. An extensive data base on wood gasification was generated during a multi-year experimental program. This data base and subsequent design and economic analysis activities led to the discussion to study the gasification character of other fuels. The specific fuel studied was refuse derived fuel (RDF) which is a prepared municipal solid waste (MSW). The use of RDF, while providing a valuable fuel, can also provide a solution to MSW disposal problems. Gasification of MSW provides advantages over land fill or mass burn technology since a more usable form of energy, medium Btu gas, is produced. Land filling of wastes produces no usable products and mass burning while greatly reducing the volume of wastes for disposal can produce only steam. This steam must be used on site or very nearby this limiting the potential locations for mass burn facilities. Such a gas, if produced from currently available supplies of MSW, can contribute 2 quads to the US energy supply. 3 refs., 12 figs., 7 tabs.

  10. Hydrogen manufacture by Lurgi gasification of Oklahoma coal

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Advantages and disadvantages of using the Lurgi gasification process to produce hydrogen from Oklahoma coal are listed. Special attention was given to the production of heat for the process; heat is generated by burning part of pretreated coal in the steam generator. Overall performance of the Lurgi process is summarized in tabular form.

  11. Coal gasification systems engineering and analysis. Appendix A: Coal gasification catalog

    NASA Technical Reports Server (NTRS)

    1980-01-01

    The scope of work in preparing the Coal Gasification Data Catalog included the following subtasks: (1) candidate system subsystem definition, (2) raw materials analysis, (3) market analysis for by-products, (4) alternate products analysis, (5) preliminary integrated facility requirements. Definition of candidate systems/subsystems includes the identity of and alternates for each process unit, raw material requirements, and the cost and design drivers for each process design.

  12. Co-gasification of solid waste and lignite - a case study for Western Macedonia.

    PubMed

    Koukouzas, N; Katsiadakis, A; Karlopoulos, E; Kakaras, E

    2008-01-01

    Co-gasification of solid waste and coal is a very attractive and efficient way of generating power, but also an alternative way, apart from conventional technologies such as incineration and landfill, of treating waste materials. The technology of co-gasification can result in very clean power plants using a wide range of solid fuels but there are considerable economic and environmental challenges. The aim of this study is to present the available existing co-gasification techniques and projects for coal and solid wastes and to investigate the techno-economic feasibility, concerning the installation and operation of a 30MW(e) co-gasification power plant based on integrated gasification combined cycle (IGCC) technology, using lignite and refuse derived fuel (RDF), in the region of Western Macedonia prefecture (WMP), Greece. The gasification block was based on the British Gas-Lurgi (BGL) gasifier, while the gas clean-up block was based on cold gas purification. The competitive advantages of co-gasification systems can be defined both by the fuel feedstock and production flexibility but also by their environmentally sound operation. It also offers the benefit of commercial application of the process by-products, gasification slag and elemental sulphur. Co-gasification of coal and waste can be performed through parallel or direct gasification. Direct gasification constitutes a viable choice for installations with capacities of more than 350MW(e). Parallel gasification, without extensive treatment of produced gas, is recommended for gasifiers of small to medium size installed in regions where coal-fired power plants operate. The preliminary cost estimation indicated that the establishment of an IGCC RDF/lignite plant in the region of WMP is not profitable, due to high specific capital investment and in spite of the lower fuel supply cost. The technology of co-gasification is not mature enough and therefore high capital requirements are needed in order to set up a direct co-gasification plant. The cost of electricity estimated was not competitive, compared to the prices dominating the Greek electricity market and thus further economic evaluation is required. The project would be acceptable if modular construction of the unit was first adopted near operating power plants, based on parallel co-gasification, and gradually incorporating the remaining process steps (gas purification, power generation) with the aim of eventually establishing a true direct co-gasification plant. PMID:17631995

  13. Coal gasification. Quarterly report, January-March 1979. [US DOE supported

    SciTech Connect

    1980-01-01

    Progress in DOE-supported coal gasification pilot plant projects is reported: company, location, contract number, funding, process description, history and progress in the current quarter. Two support projects are discussed: preparation of a technical data book and mathematical modeling of gasification reactors. (LTN)

  14. Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed

    SciTech Connect

    Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li

    2008-05-15

    Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

  15. Hydrogen recovery from the thermal plasma gasification of solid waste.

    PubMed

    Byun, Youngchul; Cho, Moohyun; Chung, Jae Woo; Namkung, Won; Lee, Hyeon Don; Jang, Sung Duk; Kim, Young-Suk; Lee, Jin-Ho; Lee, Carg-Ro; Hwang, Soon-Mo

    2011-06-15

    Thermal plasma gasification has been demonstrated as one of the most effective and environmentally friendly methods for solid waste treatment and energy utilization in many of studies. Therefore, the thermal plasma process of solid waste gasification (paper mill waste, 1.2 ton/day) was applied for the recovery of high purity H(2) (>99.99%). Gases emitted from a gasification furnace equipped with a nontransferred thermal plasma torch were purified using a bag-filter and wet scrubber. Thereafter, the gases, which contained syngas (CO+H(2)), were introduced into a H(2) recovery system, consisting largely of a water gas shift (WGS) unit for the conversion of CO to H(2) and a pressure swing adsorption (PSA) unit for the separation and purification of H(2). It was successfully demonstrated that the thermal plasma process of solid waste gasification, combined with the WGS and PSA, produced high purity H(2) (20 N m(3)/h (400 H(2)-Nm(3)/PMW-ton), up to 99.99%) using a plasma torch with 1.6 MWh/PMW-ton of electricity. The results presented here suggest that the thermal plasma process of solid waste gasification for the production of high purity H(2) may provide a new approach as a future energy infrastructure based on H(2). PMID:21497018

  16. Gasification Product Improvement Facility (GPIF). Final report

    SciTech Connect

    1995-09-01

    The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

  17. The Caterpillar Coal Gasification Facility

    E-print Network

    Welsh, J.; Coffeen, W. G., III

    1983-01-01

    ' in 1981 and won the 'energy conservation award' for 1983. The decision to install and operate a coal gasification plant was based on severe natural gas curtailments at York with continuing supply interruptions. This paper will present a detailed...

  18. Influence of pressure on coal pyrolysis and char gasification

    SciTech Connect

    Haiping Yang; Hanping Chen; Fudong Ju; Rong Yan; Shihong Zhang

    2007-12-15

    Coal char structure varied greatly with pyrolysis pressure, which has a significant influence on the gasification reactivity. In this study, the influence of pressure on the behavior of coal pyrolysis and physicochemical structure and gasification characteristics of the resultant coal char was investigated using a pressurized thermogravimetric analyzer combined with an ambient thermogravimetric analyzer. First, the pyrolysis of Shenfu (SF) bituminous coal was performed in a pressurized thermogravimetric analyzer (TGA) at different pressures (0.1, 0.8, 1.5, 3, and 5 MPa). The volatile mainly evolved out at 400-800{sup o}C. The gas products are mainly CO{sub 2}, CO, CH{sub 4}, and light aliphatics with some water. It was observed that the pyrolysis of coal was shifted to lower temperature (50{sup o}C) with pressure increasing from ambient to 5 MPa, and the devolatilization rate of coal pyrolysis was decreased and the coal char yield was increased slightly. The structure of solid coal char was analyzed using FTIR, ASAP2020, and CNHS. In the solid char, the main organic functional groups are mainly CO, C-C (alkane), C-H ar, C-O-C, and C=C ar. The carbon content was increased while H content decreased. Finally, the gasification of the solid char was preformed at ambient pressure with CO{sub 2} as gasify agent. The gasification process of coal char can be divided into postpyrolysis and char gasification. Higher pressure accelerated the initial stage of char gasification, and higher gasification reactivity was observed for char derived at 5 MPa. 23 refs., 8 figs., 5 tabs.

  19. Modelling coal gasification with CFD and discrete phase method

    SciTech Connect

    Shi, S.P.; Zitney, S.E.; Shahnam, M.; Syamlal, M; Rogers, W.A.

    2006-12-01

    In the present paper the authors describe a computational fluid dynamics model of a two-stage, oxygen blown, entrained flow, coal slurry gasifier for use in advanced power plant simulations. The discrete phase method is used to simulate the coal slurry flow. The physical and chemical processing of coal slurry gasification is implemented by calculating the discrete phase trajectory using a Lagrangian formulation. The particle tracking is coupled with specific physical processes, in which the coal particles sequentially undergo moisture release, vaporisation, devolatilisation, char oxidation and char gasification. Using specified plant boundary conditions, the gasification model predicts a synthesis gas composition that is very close to the values calculated by a restricted equilibrium reactor model tuned to represent typical experimental data. The char conversions are 100 and 86% for the first stage and second stage respectively.

  20. Pipeline-gas Demonstration Plant: Phase I. Quarterly technical process report, 1 January 1981 - 31 March 1981. [Proprietary process for coal gasification plants

    SciTech Connect

    DiFulgentiz, R. A.

    1981-01-01

    Contract No EF-77-C-01-2542 between Conoco Inc. and the U.S. Department of Energy provides for the design, construction, and operation of a demonstration plant capable of processing bituminous caking coal into clean pipeline quality gas. During the reporting period of January 1, 1981, through March 31, 1981, the major work effort of the project was focused on Task VI, Demonstration Plant Engineering and Design, and on Task VII, Construction Planning. Work continued on plans for obtaining coal, catalysts, chemicals, and flux, and on plans for sale of the products and by-products. Work on Task VIII, Economic Reassessment, was started during the reporting period. The design phase of the project, Phase I, is scheduled for completion on June 30, 1981. Conoco Inc. expects to meet all major milestone dates and complete Phase I on schedule.

  1. Solar gasification of biomass: design and characterization of a molten salt gasification reactor

    NASA Astrophysics Data System (ADS)

    Hathaway, Brandon Jay

    The design and implementation of a prototype molten salt solar reactor for gasification of biomass is a significant milestone in the development of a solar gasification process. The reactor developed in this work allows for 3 kWth operation with an average aperture flux of 1530 suns at salt temperatures of 1200 K with pneumatic injection of ground or powdered dry biomass feedstocks directly into the salt melt. Laboratory scale experiments in an electrically heated reactor demonstrate the benefits of molten salt and the data was evaluated to determine the kinetics of pyrolysis and gasification of biomass or carbon in molten salt. In the presence of molten salt overall gas yields are increased by up to 22%; pyrolysis rates double due to improved heat transfer, while carbon gasification rates increase by an order of magnitude. Existing kinetic models for cellulose pyrolysis fit the data well, while carbon gasification in molten salt follows kinetics modeled with a 2/3 order shrinking-grain model with a pre-exponential factor of 1.5*106 min-1 and activation energy of 158 kJ/mol. A reactor concept is developed based around a concentric cylinder geometry with a cavity-style solar receiver immersed within a volume of molten carbonate salt. Concentrated radiation delivered to the cavity is absorbed in the cavity walls and transferred via convection to the salt volume. Feedstock is delivered into the molten salt volume where biomass gasification reactions will be carried out producing the desired product gas. The features of the cavity receiver/reactor concept are optimized based on modeling of the key physical processes. The cavity absorber geometry is optimized according to a parametric survey of radiative exchange using a Monte Carlo ray tracing model, resulting in a cavity design that achieves absorption efficiencies of 80%-90%. A parametric survey coupling the radiative exchange simulations to a CFD model of molten salt natural convection is used to size the annulus containing the molten salt to maximize utilization of absorbed solar energy, resulting in a predicted utilization efficiency of 70%. Finite element analysis was used to finalize the design to achieve acceptable thermal stresses less than 34.5 MPa to avoid material creep.

  2. Survey of biomass gasification. Volume III. Current technology and research

    SciTech Connect

    1980-04-01

    This survey of biomass gasification was written to aid the Department of Energy and the Solar Energy Research Institute Biological and Chemical Conversion Branch in determining the areas of gasification that are ready for commercialization now and those areas in which further research and development will be most productive. Chapter 8 is a survey of gasifier types. Chapter 9 consists of a directory of current manufacturers of gasifiers and gasifier development programs. Chapter 10 is a sampling of current gasification R and D programs and their unique features. Chapter 11 compares air gasification for the conversion of existing gas/oil boiler systems to biomass feedstocks with the price of installing new biomass combustion equipment. Chapter 12 treats gas conditioning as a necessary adjunct to all but close-coupled gasifiers, in which the product is promptly burned. Chapter 13 evaluates, technically and economically, synthesis-gas processes for conversion to methanol, ammonia, gasoline, or methane. Chapter 14 compiles a number of comments that have been assembled from various members of the gasifier community as to possible roles of the government in accelerating the development of gasifier technology and commercialization. Chapter 15 includes recommendations for future gasification research and development.

  3. Thermodynamics Analysis of Refinery Sludge Gasification in Adiabatic Updraft Gasifier

    PubMed Central

    Ahmed, Reem; Sinnathambi, Chandra M.; Eldmerdash, Usama; Subbarao, Duvvuri

    2014-01-01

    Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.955.5%, 43.772.4%, and 42.550.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values. PMID:24672368

  4. Countercurrent fixed-bed gasification of biomass at laboratory scale

    SciTech Connect

    Di Blasi, C.; Signorelli, G.; Portoricco, G.

    1999-07-01

    A laboratory-scale countercurrent fixed-bed gasification plant has been designed and constructed to produce data for process modeling and to compare the gasification characteristics of several biomasses (beechwood, nutshells, olive husks, and grape residues). The composition of producer gas and spatial temperature profiles have been measured for biomass gasification at different air flow rates. The gas-heating value always attains a maximum as a function of this operating variable, associated with a decrease of the air-to-fuel ratio. Optical gasification conditions of wood and agricultural residues give rise to comparable gas-heating values, comprised in the range 5--5.5 MJ/Nm{sup 3} with 28--30% CO, 5--7% CO{sub 2}, 6--8% H{sub 2}, 1--2% CH{sub 4}, and small amounts of C{sub 2}- hydrocarbons (apart from nitrogen). However, gasification of agricultural residues is more difficult because of bed transport, partial ash sintering, nonuniform flow distribution, and the presence of a muddy phase in the effluents, so that proper pretreatments are needed for largescale applications.

  5. Thermodynamics analysis of refinery sludge gasification in adiabatic updraft gasifier.

    PubMed

    Ahmed, Reem; Sinnathambi, Chandra M; Eldmerdash, Usama; Subbarao, Duvvuri

    2014-01-01

    Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9-55.5%, 43.7-72.4%, and 42.5-50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values. PMID:24672368

  6. Hybrid Combustion-Gasification Chemical Looping

    SciTech Connect

    Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

    2009-01-07

    For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2} separation, and also syngas production from coal with the calcium sulfide (CaS)/calcium sulfate (CaSO{sub 4}) loop utilizing the PDU facility. The results of Phase I were reported in Reference 1, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase I Report' The objective for Phase II was to develop the carbonate loop--lime (CaO)/calcium carbonate (CaCO{sub 3}) loop, integrate it with the gasification loop from Phase I, and ultimately demonstrate the feasibility of hydrogen production from the combined loops. The results of this program were reported in Reference 3, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase II Report'. The objective of Phase III is to operate the pilot plant to obtain enough engineering information to design a prototype of the commercial Chemical Looping concept. The activities include modifications to the Phase II Chemical Looping PDU, solids transportation studies, control and instrumentation studies and additional cold flow modeling. The deliverable is a report making recommendations for preliminary design guidelines for the prototype plant, results from the pilot plant testing and an update of the commercial plant economic estimates.

  7. Technology Assessment Report: Aqueous Sludge Gasification Technologies

    EPA Science Inventory

    The study reveals that sludge gasification is a potentially suitable alternative to conventional sludge handling and disposal methods. However, very few commercial operations are in existence. The limited pilot, demonstration or commercial application of gasification technology t...

  8. Characterization of cellulosic wastes and gasification products from chicken farms

    SciTech Connect

    Joseph, Paul; Tretsiakova-McNally, Svetlana; McKenna, Siobhan

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer The gas chromatography indicated the variable quality of the producer gas. Black-Right-Pointing-Pointer The char had appreciable NPK values, and can be used as a fertiliser. Black-Right-Pointing-Pointer The bio-oil produced was of poor quality, having high moisture content and low pH. Black-Right-Pointing-Pointer Mass and energy balances showed inadequate level energy recovery from the process. Black-Right-Pointing-Pointer Future work includes changing the operating parameters of the gasification unit. - Abstract: The current article focuses on gasification as a primary disposal solution for cellulosic wastes derived from chicken farms, and the possibility to recover energy from this process. Wood shavings and chicken litter were characterized with a view to establishing their thermal parameters, compositional natures and calorific values. The main products obtained from the gasification of chicken litter, namely, producer gas, bio-oil and char, were also analysed in order to establish their potential as energy sources. The experimental protocol included bomb calorimetry, pyrolysis combustion flow calorimetry (PCFC), thermo-gravimetric analyses (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, elemental analyses, X-ray diffraction (XRD), mineral content analyses and gas chromatography. The mass and energy balances of the gasification unit were also estimated. The results obtained confirmed that gasification is a viable method of chicken litter disposal. In addition to this, it is also possible to recover some energy from the process. However, energy content in the gas-phase was relatively low. This might be due to the low energy efficiency (19.6%) of the gasification unit, which could be improved by changing the operation parameters.

  9. Experimental investigations of biomass gasification with carbon-dioxide

    NASA Astrophysics Data System (ADS)

    Sircar, Indraneel

    A sustainable energy cycle may include enhanced utilization of solar energy and atmospheric CO2 to produce biomass and enhanced utilization of exhaust CO2 from power plants for synthetic gas production. The reaction of carbon with CO2 is potentially one of the important processes in a future sustainable carbon cycle. Reactions involving carbon and CO2 are also relevant to the chemical process and metal industries. Biomass char has been recognized as a present and future alternative to fossil-fuels for energy production and fuel synthesis. Therefore, biomass char gasification with CO2 recycling is proposed as a sustainable and carbon-neutral energy technology. Biomass char is a complex porous solid and its gasification involves heat and mass transfer processes within pores of multiple sizes from nanometer to millimeter scales. These processes are coupled with heterogeneous chemistry at the internal and external surfaces. Rates for the heterogeneous carbon gasification reactions are affected by inorganic content of the char. Furthermore, pore structure of the char develops with conversion and influences apparent gasification rates. Effective modeling of the gasification reactions has relied on the best available understanding of diffusion processes and kinetic rate property constants from state of the art experiments. Improvement of the influences of inorganic composition, and process parameters, such as pressure and temperature on the gasification reaction rates has been a continuous process. Economic viability of gasification relies on use of optimum catalysts. These aspects of the current status of gasification technologies have motivated the work reported in this dissertation. The reactions between biomass chars and CO2 are investigated to determine the effects of temperature and pressure on the reaction rates for large char particles of relevance to practical gasification technologies. An experimental apparatus consisting of a high-pressure fixed-bed reactor with product gas sampling for tracking the reaction progress, supported by independent gravimetric measurements of mass loss, is described. The effects of pressure and temperature on the char-CO2 reaction are investigated at elevated pressures up to 10 atm. Measurements of reaction rates at multiple temperatures and pressures for a low-ash pinewood char are presented. Kinetic rate parameters for the char-CO2 reaction are reported with detailed uncertainty calculations and discussed in the context of the structural changes of the char with mass loss. The effects of pressure and temperature on the internal mass transfer processes and the intrinsic reaction rates are assessed using Thiele analysis for non-isothermal particles with the nth order and the Langmuir-Hinshelwood kinetic rate models. The effects of potassium, calcium and iron catalysts on the CO2 gasification rates of an activated coconut char are investigated. A catalyst treatment method for obtaining high catalyst loadings (~12 wt. %) is described. The effects of the catalysts on the surface reaction rates and the activation energies are reported. The results of this study are encouraging in the context of potential future discovery of a viable low-temperature catalytic gasification process for sustainable use of biomass as a renewable energy resource. Utilization of plant based substances such as citric acid to provide higher catalytic activity and the potential for utilizing the high initial activity of iron by using rust proofing compounds for maintaining high reactivity are recommended for further development.

  10. Biodesulfurization of mild gasification liquid products. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect

    Kilbanes, J.J. II; Ho, K.

    1993-05-01

    The mild gasification of coal, as being developed at IGT and elsewhere, is a promising new technology that can convert coal to multiple products: gas, solid, and liquids. Mild gasification liquids can be used as feedstock to make transportation fuels and chemicals. However, the sulfur content and aromaticity of mild gasification liquids limits their usefulness and biodesulfurization can potentially decrease both sulfur content and aromaticity. The objective of this project is to investigate the feasibility of using biodesulfurization to upgrade the quality of mild gasification liquids. During the current quarter a laboratory-scale mild gasification reactor was used to produce additional liquid derived from IBC-105 coal. The liquid has an organic sulfur content of 2.88%. The biocatalyst is apparently inhibited by chemical constituents in the light oil fraction of mild coal gasification liquids, but functions quite well in other liquid fractions or in unfractionated mild coal gasification liquid. Even when excess biocatalyst is used, approximately 12% of the organosulfur compounds appear to be recalcitrant to biodesulfurization. Biodesulfurization tests utilizing membrane fragments purified from IGTS8 and freeze-dried IGTS8 cell preparations added directly to mild coal gasification liquids have been performed. The processing and analysis of those samples is currently under way.

  11. The thermochemical analysis of the effectiveness of various gasification technologies

    NASA Astrophysics Data System (ADS)

    Ivanov, P. P.; Kovbasyuk, V. I.; Medvedev, Yu. V.

    2013-05-01

    The authors studied the process of gasification of solid fuels and wastes by means of modified model accounting the absence of equilibrium in the Boudouard reaction. A comparison was made between auto- and allothermal gasification, and it was demonstrated that the former method is more advantageous with respect to (as an indicator) thermochemical efficiency. The feasibility of producing highly calorific synthesis gas using an oxygen blast is discussed. A thermodynamic model of the facility for producing such synthesis gas has been developed that involves the gas turbine used for driving an oxygen plant of the adsorption type.

  12. Treatment of biomass-gasification wastewater

    SciTech Connect

    Maxham, J.V.

    1981-03-01

    One way of utilizing biomass as a renewable energy resource is to thermochemically convert it into a gaseous fuel. During conversion, wastewaters are generated that will require treatment prior to reuse in the production process or discharge to the environment. Development of cost-effective wastewater treatment technologies is necessary at the pilot plant stage of production technology development. The principal task of this research effort has been to assess the technical feasibility and cost effectiveness of several promising process technologies for the treatment of biomass gasification wastewaters (BGW) by conducting bench-scale treatability studies. In addition to conventional treatment process options, innovative process technologies have been investigated that promise to dramatically reduce treatment time, cost, energy consumption, and/or sludge production while preserving the simplicity of operation and mechanical reliability of conventional treatment process options. This paper reports results obtained recently in innovative biological wastewater treatment process studies.

  13. Beluga Coal Gasification - ISER

    SciTech Connect

    Steve Colt

    2008-12-31

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  14. Modeling and comparative assessment of municipal solid waste gasification for energy production

    SciTech Connect

    Arafat, Hassan A. Jijakli, Kenan

    2013-08-15

    Highlights: Study developed a methodology for the evaluation of gasification for MSW treatment. Study was conducted comparatively for USA, UAE, and Thailand. Study applies a thermodynamic model (Gibbs free energy minimization) using the Gasify software. The energy efficiency of the process and the compatibility with different waste streams was studied. - Abstract: Gasification is the thermochemical conversion of organic feedstocks mainly into combustible syngas (CO and H{sub 2}) along with other constituents. It has been widely used to convert coal into gaseous energy carriers but only has been recently looked at as a process for producing energy from biomass. This study explores the potential of gasification for energy production and treatment of municipal solid waste (MSW). It relies on adapting the theory governing the chemistry and kinetics of the gasification process to the use of MSW as a feedstock to the process. It also relies on an equilibrium kinetics and thermodynamics solver tool (Gasify) in the process of modeling gasification of MSW. The effect of process temperature variation on gasifying MSW was explored and the results were compared to incineration as an alternative to gasification of MSW. Also, the assessment was performed comparatively for gasification of MSW in the United Arab Emirates, USA, and Thailand, presenting a spectrum of socioeconomic settings with varying MSW compositions in order to explore the effect of MSW composition variance on the products of gasification. All in all, this study provides an insight into the potential of gasification for the treatment of MSW and as a waste to energy alternative to incineration.

  15. Gasification characteristics of an activated carbon catalyst during the decomposition of hazardous waste materials in supercritical water

    SciTech Connect

    Matsumura, Yukihiko; Nuessle, F.W.; Antal, M.J. Jr.

    1996-10-01

    Recently, carbonaceous materials were proved to be effective catalysts for hazardous waste decomposition in supercritical water. Gasification of the carbonaceous catalyst itself is also expected, however, under supercritical conditions. Thus, it is essential to determine the gasification rate of the carbonaceous materials during this process to determine the active lifetime of the catalysts. For this purpose, the gasification characteristics of granular coconut shell activated carbon in supercritical water alone (600-650{degrees}C, 25.5-34.5 MPa) were investigated. The gasification rate at subatmospheric pressure agreed well with the gasification rate at supercritical conditions, indicating the same reaction mechanism. Methane generation under these conditions is via pyrolysis, and thus is not affected by the water pressure. An iodine number increase of 25% was observed as a result of the supercritical water gasification.

  16. Effect of Microwave Pre-Processing of Pelletized Biomass on its Gasification and Combustion / Mikrovi?nu Priekapstr?des Ietekme Uz Granul?tas Biomasas Gazifik?cijas Un Deganas Procesiem

    NASA Astrophysics Data System (ADS)

    Barmina, I.; L?ckrasti?a, A.; Valdmanis, J.; Valdmanis, R.; Za?e, M.; Arshanitsa, A.; Telysheva, G.; Solodovnik, V.

    2013-08-01

    To effectively produce clean heat energy from biomass, microwave (mw) pre-processing of its different types - pelletized wood (spruce), herbaceous biomass (reed canary grass) and their mixture (50:50) - was carried out at the 2.45 GHz frequency with different durations of biomass exposure to high-frequency oscillations. To estimate the mw pre-processing effect on the structure, composition and fuel characteristics of biomass, its thermogravimetric (TG), infrared spectroscopy (FTIR) measurements and elemental analysis were made. The pre-processing is shown to enhance the release of moisture and low-calorific volatiles and the partial destruction of biomass constituents (hemicelluloses, cellulose), promoting variations in the elemental composition and heating values of biomass. The field-enhanced variations of biomass characteristics and their influence on its gasification and combustion were studied using an integrated system of a biomass gasifier and a combustor with swirl-enhanced stabilization of the flame reaction zone. The results show that the mw pre-processing of biomass pellets provides a faster weight loss at the gasification, and, therefore, faster ignition and combustion of the activated pellets along with increased output of heat energy at their burnout Veikti kompleksi eksperiment?lie p?t?jumi par mikrovi??u (2,45 GHz) priekapstr?des ietekmi uz da?das izcelsmes biomasas granulu (egles, mieabr??a un to mais?jumu 50:50) gazifik?cijas un deganas procesiem. P?t?jumi apvieno granul?t?s biomasas element?r? sast?va un termogravimetriskos m?r?jumus, k? ar? granul?t?s biomasas gazifik?cijas un deganas procesu kompleksu izp?ti, apvienojot biomasas svara izmai?u kin?tiskos m?r?jumus ar deganas zonas temperat?ras, iek?rtas jaudas un deganas produktu sast?va kin?tiskiem m?r?jumiem. P?t?jumiem izmantota mazas jaudas eksperiment?l? iek?rta (l?dz 2,5 kW), kuru veido integr?ts gazifik?tors un deganas kamera. P?t?jumu rezult?t? konstat?ts, ka mikrovi??u priekapstr?de nodroina intens?v?ku biomasas gazifik?ciju, ?tr?ku gaistoo savienojumu veidoanos, uzliesmoanu un piln?g?ku sadedzin?anu ar sekojou saraot?s ?patn?j? siltuma ener?ijas pieaugumu

  17. Underground Coal Gasification Program

    Energy Science and Technology Software Center (ESTSC)

    1994-12-01

    CAVSIM is a three-dimensional, axisymmetric model for resource recovery and cavity growth during underground coal gasification (UCG). CAVSIM is capable of following the evolution of the cavity from near startup to exhaustion, and couples explicitly wall and roof surface growth to material and energy balances in the underlying rubble zones. Growth mechanisms are allowed to change smoothly as the system evolves from a small, relatively empty cavity low in the coal seam to a large,morealmost completely rubble-filled cavity extending high into the overburden rock. The model is applicable to nonswelling coals of arbitrary seam thickness and can handle a variety of gas injection flow schedules or compositions. Water influx from the coal aquifer is calculated by a gravity drainage-permeation submodel which is integrated into the general solution. The cavity is considered to consist of up to three distinct rubble zones and a void space at the top. Resistance to gas flow injected from a stationary source at the cavity floor is assumed to be concentrated in the ash pile, which builds up around the source, and also the overburden rubble which accumulates on top of this ash once overburden rock is exposed at the cavity top. Char rubble zones at the cavity side and edges are assumed to be highly permeable. Flow of injected gas through the ash to char rubble piles and the void space is coupled by material and energy balances to cavity growth at the rubble/coal, void/coal and void/rock interfaces. One preprocessor and two postprocessor programs are included - SPALL calculates one-dimensional mean spalling rates of coal or rock surfaces exposed to high temperatures and generates CAVSIM input: TAB reads CAVSIM binary output files and generates ASCII tables of selected data for display; and PLOT produces dot matrix printer or HP printer plots from TAB output.less

  18. 75 FR 17397 - Hydrogen Energy California's Integrated Gasification Combined Cycle Project, Kern County, CA...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-06

    ...DEPARTMENT OF ENERGY Hydrogen Energy California's Integrated Gasification...and operation of a project proposed by Hydrogen Energy California LLC (HECA). DOE...be processed and purified to produce a hydrogen-rich fuel. The hydrogen would be...

  19. Combustion, pyrolysis, gasification, and liquefaction of biomass

    SciTech Connect

    Reed, T.B.

    1980-09-01

    All the products now obtained from oil can be provided by thermal conversion of the solid fuels biomass and coal. As a feedstock, biomass has many advantages over coal and has the potential to supply up to 20% of US energy by the year 2000 and significant amounts of energy for other countries. However, it is imperative that in producing biomass for energy we practice careful land use. Combustion is the simplest method of producing heat from biomass, using either the traditional fixed-bed combustion on a grate or the fluidized-bed and suspended combustion techniques now being developed. Pyrolysis of biomass is a particularly attractive process if all three products - gas, wood tars, and charcoal - can be used. Gasification of biomass with air is perhaps the most flexible and best-developed process for conversion of biomass to fuel today, yielding a low energy gas that can be burned in existing gas/oil boilers or in engines. Oxygen gasification yields a gas with higher energy content that can be used in pipelines or to fire turbines. In addition, this gas can be used for producing methanol, ammonia, or gasoline by indirect liquefaction. Fast pyrolysis of biomass produces a gas rich in ethylene that can be used to make alcohols or gasoline. Finally, treatment of biomass with high pressure hydrogen can yield liquid fuels through direct liquefaction.

  20. Combustion, pyrolysis, gasification, and liquefaction of biomas

    NASA Astrophysics Data System (ADS)

    Reed, T. B.

    1980-09-01

    The advantages of biomass as a feedstock are examined and biomass conversion techniques are described. Combustion is the simplest method of producing heat from biomass, using either the traditional fixed bed combustion on a grate or the fluidized bed and suspended combustion techniques now being developed. Pyrolysis of biomass is a particularly attractive process if all three products gas, wood tars, and charcoal can be used. Gasification of biomass with air is perhaps the most flexible and best developed process for conversion of biomass to fuel, yielding a low energy gas that can be burned in existing gas/oil boilers or in engines. Oxygen gasification yields a gas with higher energy content that can be used in pipelines or to fire turbines. In addition, this gas can be used for producing methanol, ammonia, or gasoline by indirect liquefaction. Fast pyrolysis of biomass produces a gas rich in ethylene that can be used to make alcohols or gasoline. Finally, treatment of biomass with high pressure hydrogen can yield liquid fuels through direct liquefaction.

  1. Study of Indonesia low rank coal utilization on modified fixed bed gasification for combined cycle power plant

    NASA Astrophysics Data System (ADS)

    Hardianto, T.; Amalia, A. R.; Suwono, A.; Riauwindu, P.

    2015-09-01

    Gasification is a conversion process converting carbon-based solid fuel into gaseous products that have considerable amount of calorific value. One of the carbon-based solid fuel that serves as feed for gasification is coal. Gasification gaseous product is termed as syngas (synthetic gas) that is composed of several different gases. Syngas produced from gasification vary from one process to another, this is due to several factors which are: feed characteristics, operation condition, gasified fluid condition, and gasification method or technology. One of the utilization of syngas is for combined cycle power plant fuel. In order to meet the need to convert carbon-based solid fuel into gaseous fuel for combined cycle power plant, engineering adjustment for gasification was done using related software to create the syngas with characteristics of natural gas that serve as fuel for combined cycle power plant in Indonesia. Feed used for the gasification process in this paper was Indonesian Low Rank Coal and the method used to obtain syngas was Modified Fixed Bed Gasifier. From the engineering adjustment process, the yielded syngas possessed lower heating value as much as 31828.32 kJ/kg in gasification condition of 600C, 3.5 bar, and steam to feed ratio was 1 kg/kg. Syngas characteristics obtained from the process was used as a reference for the adjustment of the fuel system modification in combined cycle power plant that will have the same capacity with the conversion of the system's fuel from natural gas to syngas.

  2. Coal gasification systems engineering and analysis. Appendix D: Cost and economic studies

    NASA Technical Reports Server (NTRS)

    1980-01-01

    The detailed cost estimate documentation for the designs prepared in this study are presented. The include: (1) Koppers-Totzek, (2) Texaco (3) Babcock and Wilcox, (4) BGC-Lurgi, and (5) Lurgi. The alternate product cost estimates include: (1) Koppers-Totzek and Texaco single product facilities (methane, methanol, gasoline, hydrogen), (2) Kopers-Totzek SNG and MBG, (3) Kopers-Totzek and Texaco SNG and MBG, and (4) Lurgi-methane and Lurgi-methane and methanol.

  3. Catalytic Gasification of Coal using Eutectic Salt Mixtures

    SciTech Connect

    Atul Sheth; Pradeep Agrawal; Yaw D. Yeboah

    1998-12-04

    The objectives of this study are to: identify appropriate eutectic salt mixture catalysts for coal gasification; assess agglomeration tendency of catalyzed coal; evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; evaluate the recovery, regeneration and recycle of the spent catalysts; and conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process. A review of the collected literature was carried out. The catalysts which have been used for gasification can be roughly classified under the following five groups: alkali metal salts; alkaline earth metal oxides and salts; mineral substances or ash in coal; transition metals and their oxides and salts; and eutectic salt mixtures. Studies involving the use of gasification catalysts have been conducted. However, most of the studies focused on the application of individual catalysts. Only two publications have reported the study of gasification of coal char in CO2 and steam catalyzed by eutectic salt mixture catalysts. By using the eutectic mixtures of salts that show good activity as individual compounds, the gasification temperature can be reduced possibly with still better activity and gasification rates due to improved dispersion of the molten catalyst on the coal particles. For similar metal/carbon atomic ratios, eutectic catalysts were found to be consistently more active than their respective single salts. But the exact roles that the eutectic salt mixtures play in these are not well understood and details of the mechanisms remain unclear. The effects of the surface property of coals and the application methods of eutectic salt mixture catalysts with coal chars on the reactivity of gasification will be studied. Based on our preliminary evaluation of the literature, a ternary eutectic salt mixture consisting of Li- Na- and K- carbonates has the potential as gasification catalyst. To verify the literature reported, melting points for various compositions consisting of these three salts and the temperature range over which the mixture remained molten were determined in the lab. For mixtures with different concentrations of the three salts, the temperatures at which the mixtures were found to be in complete molten state were recorded. By increasing the amount of Li2CO3, the melting temperature range was reduced significantly. In the literature, the eutectic mixtures of Li- Na- and K-carbonates are claimed to have a lower activation energy than that of K2CO3 alone and they remain molten at a lower temperature than pure K2CO3. The slow increase in the gasification rates with eutectics reported in the literature is believed to be due to a gradual penetration of the coals and coal char particles by the molten and viscous catalyst phase. The even spreading of the salt phase seems to increase the overall carbon conversion rate. In the next reporting period, a number of eutectic salts and methods of their application on the coal will be identified and tested.

  4. BIMOMASS GASIFICATION PILOT PLANT STUDY

    EPA Science Inventory

    The report gives results of a gasification pilot program using two biomass feedstocks: bagasse pellets and wood chips. he object of the program was to determine the properties of biomass product gas and its suitability as a fuel for gas-turbine-based power generation cycles. he f...

  5. High temperature air-blown woody biomass gasification model for the estimation of an entrained down-flow gasifier.

    PubMed

    Kobayashi, Nobusuke; Tanaka, Miku; Piao, Guilin; Kobayashi, Jun; Hatano, Shigenobu; Itaya, Yoshinori; Mori, Shigekatsu

    2009-01-01

    A high temperature air-blown gasification model for woody biomass is developed based on an air-blown gasification experiment. A high temperature air-blown gasification experiment on woody biomass in an entrained down-flow gasifier is carried out, and then the simple gasification model is developed based on the experimental results. In the experiment, air-blown gasification is conducted to demonstrate the behavior of this process. Pulverized wood is used as the gasification fuel, which is injected directly into the entrained down-flow gasifier by the pulverized wood banner. The pulverized wood is sieved through 60 mesh and supplied at rates of 19 and 27kg/h. The oxygen-carbon molar ratio (O/C) is employed as the operational condition instead of the air ratio. The maximum temperature achievable is over 1400K when the O/C is from 1.26 to 1.84. The results show that the gas composition is followed by the CO-shift reaction equilibrium. Therefore, the air-blown gasification model is developed based on the CO-shift reaction equilibrium. The simple gasification model agrees well with the experimental results. From calculations in large-scale units, the cold gas is able to achieve 80% efficiency in the air-blown gasification, when the woody biomass feedrate is over 1000kg/h and input air temperature is 700K. PMID:18653324

  6. Power Systems Development Facility Gasification Test Campaign TC22

    SciTech Connect

    Southern Company Services

    2008-11-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC22, the first test campaign using a high moisture lignite from Mississippi as the feedstock in the modified Transport Gasifier configuration. TC22 was conducted from March 24 to April 17, 2007. The gasification process was operated for 543 hours, increasing the total gasification operation at the PSDF to over 10,000 hours. The PSDF gasification process was operated in air-blown mode with a total of about 1,080 tons of coal. Coal feeder operation was challenging due to the high as-received moisture content of the lignite, but adjustments to the feeder operating parameters reduced the frequency of coal feeder trips. Gasifier operation was stable, and carbon conversions as high as 98.9 percent were demonstrated. Operation of the PCD and other support equipment such as the recycle gas compressor and ash removal systems operated reliably.

  7. Status of health and environmental research relative to coal gasification 1976 to the present

    SciTech Connect

    Wilzbach, K.E.; Reilly, C.A. Jr.

    1982-10-01

    Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

  8. Novel approach to coal gasification using chemically incorporated catalysts (Phase II). Final report, May 1978-June 1981

    SciTech Connect

    Feldmann, H.F.; Conkle, H.N.; Appelbaum, H.R.; Chauhan, S.P.

    1981-01-01

    Since 1974, Battelle has been developing a catalytic treatment process that would allow more economic, efficient and reliable utilization of the vast deposits of eastern coals in gasification systems. In order to keep the process simple and economic, a disposable catalyst lime (CaO), was employed. It was found that the effectiveness of low concentrations of CaO was greatly increased by thorough incorporation into the coal. As a result of these efforts, a catalytic treatment system has been developed that promises to allow simplifications and improvements in existing commercial gasification processes as well as advanced gasification systems. One gasification system that appears exceptionally attractive utilizing the treatment system is direct fluid-bed hydrogasification or hydropyrolysis. A simple pressurized fluid-bed steam/oxygen gasification system is also an attractive option which could be commercialized quickly. Data generated under this program demonstrated the technical and economic advantages of these approaches.

  9. Development of a high-temperature air-blown gasification system.

    PubMed

    Pian, C C; Yoshikawa, K

    2001-09-01

    Current status of high-temperature air-blown gasification technology development is reviewed. This advanced gasification system utilizes preheated air to convert coal and waste-derived fuels into synthetic fuel gas and value-added byproducts. A series of demonstrated, independent technologies are combined to form the core of this gasification system. A high-temperature, rapid devolatilization process is used to enhance the volatile yields from the fuel and to improve the gasification efficiency. A high-temperature pebble bed filter is used to remove to the slag and particulates from the synthetic fuel gas. Finally, a novel regenerative heater is used to supply the high-temperature air for the gasifier. Component development tests have shown that higher gasification efficiencies can be obtained at more fuel-rich operating conditions when high-temperature air is used as the gasification agent. Test results also demonstrated the flex-fuel capabilities of the gasifier design. Potential uses of this technology range from large-scale integrated gasification power plants to small-scale waste-to-energy applications. PMID:11499577

  10. Biomass Gasification Research Facility Final Report

    SciTech Connect

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature of the vapor phase components of the conveyed sample gas. In addition, to minimize adsorption or chemical changes in the syngas components prior to analysis, the temperature of the transported stream is maintained as hot as is practical, while still being cooled only as much necessary prior to entering the analyzer(s). The successful transport of the sample gas stream to the analyzer(s) is accomplished through the managed combination of four basic gas conditioning methods that are applied as specifically called for by the process conditions, the gas constituent concentrations, the analyzer requirements, and the objectives of the syngas analyses: 1) removing entrained particulate matter from the sample stream; 2) maintaining the temperature of the sample gas stream; 3) lowering the pressure of the sample gas stream to decrease the vapor pressures of all the component vapor species in the sample stream; and 4) diluting the gas stream with a metered, inert gas, such as nitrogen. Proof-of-concept field demonstrations of the sampling approach were conducted for gasification process streams from a black liquor gasifier, and from the gasification of biomass and coal feedstocks at GTIs Flex-Fuel Test Facility. In addition to the descriptions and data included in this Final Report, GTI produced a Special Topical Report, Design and Protocol for Monitoring Gaseous Species in Thermochemical Processes, that explains and describes in detail the objectives, principles, design, hardware, installation, operation and representative data produced during this successful developmental effort. Although the specific analyzers used under Cooperative Agreement DE-FC36-02GO12024 were referenced in the Topical Report and this Final Report, the sampling interface design they present is generic enough to adapt to other analyzers that may be more appropriate to alternate process streams or facilities.

  11. BIomass GasIfIcaTIon Summary of technology

    E-print Network

    Mucina, Ladislav

    BIomass GasIfIcaTIon Summary of technology Gasification converts a solid fuel, such as biomass Technology Institute (feTI) has developed a novel integrated gasificationtechnologythatconvertslow gasification technology include: simpleandcompactdesign highefficiencyandeconomy

  12. Power Systems Development Facility Gasification Test Campaign TC16

    SciTech Connect

    Southern Company Services

    2004-08-24

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report discusses Test Campaign TC16 of the PSDF gasification process. TC16 began on July 14, 2004, lasting until August 24, 2004, for a total of 835 hours of gasification operation. The test campaign consisted of operation using Powder River Basin (PRB) subbituminous coal and high sodium lignite from the North Dakota Freedom mine. The highest gasifier operating temperature mostly varied from 1,760 to 1,850 F with PRB and 1,500 to 1,600 F with lignite. Typically, during PRB operations, the gasifier exit pressure was maintained between 215 and 225 psig using air as the gasification oxidant and between 145 and 190 psig while using oxygen as the oxidant. With lignite, the gasifier operated only in air-blown mode, and the gasifier outlet pressure ranged from 150 to 160 psig.

  13. Hydrogen production from algal biomass via steam gasification.

    PubMed

    Duman, Gozde; Uddin, Md Azhar; Yanik, Jale

    2014-08-01

    Algal biomasses were tested as feedstock for steam gasification in a dual-bed microreactor in a two-stage process. Gasification experiments were carried out in absence and presence of catalyst. The catalysts used were 10% Fe?O?-90% CeO? and red mud (activated and natural forms). Effects of catalysts on tar formation and gasification efficiencies were comparatively investigated. It was observed that the characteristic of algae gasification was dependent on its components and the catalysts used. The main role of the catalyst was reforming of the tar derived from algae pyrolysis, besides enhancing water gas shift reaction. The tar reduction levels were in the range of 80-100% for seaweeds and of 53-70% for microalgae. Fe?O?-CeO? was found to be the most effective catalyst. The maximum hydrogen yields obtained were 1036 cc/g algae for Fucus serratus, 937 cc/g algae for Laminaria digitata and 413 cc/g algae for Nannochloropsis oculata. PMID:24880809

  14. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

  15. NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE

    SciTech Connect

    Javad Abbasian

    2001-07-01

    The objective of this program is to develop and evaluate novel sorbents for the Siemens Westinghouse Power Company's (SWPC's) ''Ultra-Clean Gas Cleaning Process'' for reducing to near-zero levels the sulfur- and chlorine-containing gas emissions and fine particulate matter (PM2.5) caused by fuel bound constituents found in carbonaceous materials, which are processed in Integrated Gasification Combined Cycle (IGCC) technologies.

  16. Thermogravimetric characterization and gasification of pecan nut shells.

    PubMed

    Aldana, Hugo; Lozano, Francisco J; Acevedo, Joaqun; Mendoza, Alberto

    2015-12-01

    This study focuses on the evaluation of pecan nut shells as an alternative source of energy through pyrolysis and gasification. The physicochemical characteristics of the selected biomass that can influence the process efficiency, consumption rates, and the product yield, as well as create operational problems, were determined. In addition, the thermal decomposition kinetics necessary for prediction of consumption rates and yields were determined. Finally, the performance of a downdraft gasifier fed with pecan nut shells was analyzed in terms of process efficiency and exit gas characteristics. It was found that the pyrolytic decomposition of the nut shells can be modeled adequately using a single equation considering two independent parallel reactions. The performance of the gasification process can be influenced by the particle size and air flow rate, requiring a proper combination of these parameters for reliable operation and production of a valuable syngas. PMID:26433788

  17. Trace metal transformation in gasification

    SciTech Connect

    Benson, S.A.; Erickson, T.A.; Zygarlicke, C.J.; O`Keefe, C.A.; Katrinak, K.A.; Allen, S.E.; Hassett, D.J.; Hauserman, W.B.; Holcombe, N.T.

    1996-12-31

    The Energy & Environmental Research Center (EERC) is carrying out an investigation that will provide methods to predict the fate of selected trace elements in integrated gasification combined cycle (IGCC) and integrated gasification fuel cell (IGFC) systems to aid in the development of methods to control the emission of trace elements determined to be air toxics. The goal of this project is to identify the effects of critical chemical and physical transformations associated with trace element behavior in IGCC and IGFC systems. The trace elements included in this project are arsenic, chromium, cadmium, mercury, nickel, selenium, and lead. The research seeks to identify and fill, experimentally and/or theoretically, data gaps that currently exist on the fate and composition of trace elements. The specific objectives are to 1) review the existing literature to identify the type and quantity of trace elements from coal gasification systems, 2) perform laboratory-scale experimentation and computer modeling to enable prediction of trace element emissions, and 3) identify methods to control trace element emissions.

  18. The assessment of sewage sludge gasification by-products toxicity by ecotoxicologial test.

    PubMed

    Werle, Sebastian; Dudziak, Mariusz

    2015-08-01

    The process of gasification of sewage sludge generates by-products, which may be contaminated with toxic and hazardous substances, both organic and inorganic. It is therefore important to assess the environmental risk associated with this type of waste. The feasibility of using an ecotoxicological tests for this purpose was determined in the presented study. The applied tests contained indicator organisms belonging to various biological groups (bacteria, crustaceans, plants). The subject of the study were solid (ash, char) and liquid (tar) by-products generated during gasification (in a fixed bed reactor) of dried sewage sludge from various wastewater treatment systems. The tested samples were classified based on their toxic effect. The sensitivity of the indicator organisms to the tested material was determined. In-house procedures for the preparation for toxicity analysis of both sewage sludge and by-products generated during the gasification were presented. The scope of work also included the determination of the effect of selected process parameters (temperature, amount of gasifying agent) on the toxicity of gasification by-products depending on the sewage sludge source. It was shown that both the type of sewage sludge and the parameters of the gasification process affects the toxicity of the by-products of gasification. However, the results of toxicity studies also depend on the type of ecotoxicological test used, which is associated with a different sensitivity of the indicator organisms. Nevertheless, it may be concluded that the by-products formed during the gasification of the low toxicity sewage sludge can be regarded as non-toxic or low toxic. However, the results analysis of the gasification of the toxic sludge were not conclusive, which leads to further research needs in this area. PMID:25827844

  19. Underground coal gasification field experiment in the high-dipping coal seams

    SciTech Connect

    Yang, L.H.; Liu, S.Q.; Yu, L.; Zhang, W.

    2009-07-01

    In this article the experimental conditions and process of the underground gasification in the Woniushan Mine, Xuzhou, Jiangsu Province are introduced, and the experimental results are analyzed. By adopting the new method of long-channel, big-section, and two-stage underground coal gasification, the daily gas production reaches about 36,000 m{sup 3}, with the maximum output of 103,700 m{sup 3}. The daily average heating value of air gas is 5.04 MJ/m{sup 3}, with 13.57 MJ/m{sup 3} for water gas. In combustible compositions of water gas, H{sub 2} contents stand at over 50%, with both CO and CH{sub 4} contents over 6%. Experimental results show that the counter gasification can form new temperature conditions and increase the gasification efficiency of coal seams.

  20. Characterization of Scots pine stump-root biomass as feed-stock for gasification.

    PubMed

    Eriksson, Daniel; Weiland, Fredrik; Hedman, Henry; Stenberg, Martin; hrman, Olov; Lestander, Torbjrn A; Bergsten, Urban; hman, Marcus

    2012-01-01

    The main objective was to explore the potential for gasifying Scots pine stump-root biomass (SRB). Washed thin roots, coarse roots, stump heartwood and stump sapwood were characterized (solid wood, milling and powder characteristics) before and during industrial processing. Non-slagging gasification of the SRB fuels and a reference stem wood was successful, and the gasification parameters (synthesis gas and bottom ash characteristics) were similar. However, the heartwood fuel had high levels of extractives (?19%) compared to the other fuels (2-8%) and thereby ?16% higher energy contents but caused disturbances during milling, storage, feeding and gasification. SRB fuels could be sorted automatically according to their extractives and moisture contents using near-infrared spectroscopy, and their amounts and quality in forests can be predicted using routinely collected stand data, biomass functions and drill core analyses. Thus, SRB gasification has great potential and the proposed characterizations exploit it. PMID:22130078

  1. Recent regulatory experience of low-Btu coal gasification. Volume III. Supporting case studies

    SciTech Connect

    Ackerman, E.; Hart, D.; Lethi, M.; Park, W.; Rifkin, S.

    1980-02-01

    The MITRE Corporation conducted a five-month study for the Office of Resource Applications in the Department of Energy on the regulatory requirements of low-Btu coal gasification. During this study, MITRE interviewed representatives of five current low-Btu coal gasification projects and regulatory agencies in five states. From these interviews, MITRE has sought the experience of current low-Btu coal gasification users in order to recommend actions to improve the regulatory process. This report is the third of three volumes. It contains the results of interviews conducted for each of the case studies. Volume 1 of the report contains the analysis of the case studies and recommendations to potential industrial users of low-Btu coal gasification. Volume 2 contains recommendations to regulatory agencies.

  2. Gasification technologies and worldwide refining trends -- Solutions and opportunities in a changing business environment

    SciTech Connect

    Heaven, D.L.

    1996-12-01

    High temperature, entrained flow gasification has been practiced commercially for over forty years. This paper discusses recent trends in the petroleum refining industry and illustrates how gasification is a solution to many of the problems associated with these trends. It illustrates how the technology is moving from its principal use as an alternative source of hydrogen and carbon monoxide for chemicals production to a broader application as a useful and economic refining tool. The convergence of three fundamental market drivers affecting the industry makes gasification an increasingly attractive processing option in today`s petroleum refinery: the growing prevalence of heavy, sour, metals-laden crudes requires more severe processing and leaves refiners with bottoms that are difficult to handle, even more difficult to dispose of, and that, consequently, have zero or negative value streams; and increasingly stringent environmental regulation of plant operations and product characteristics will limit severely the options open to refiners for dealing with air emissions, waste disposal and product slates. This paper addresses the operating characteristics of gasification, how the technology can be incorporated into a refinery setting, reliability and operating experience of gasification technology and major supporting components, environmental characteristics, product slate options, developmental trends and the availability of technology licensing, equipment and services for refinery-based gasification.

  3. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect

    Not Available

    1981-03-31

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  4. Gasification Studies Task 4 Topical Report

    SciTech Connect

    Whitty, Kevin; Fletcher, Thomas; Pugmire, Ronald; Smith, Philip; Sutherland, James; Thornock, Jeremy; Boshayeshi, Babak; Hunsacker, Isaac; Lewis, Aaron; Waind, Travis; Kelly, Kerry

    2014-02-01

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical processes (Subtask 4.4) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation. Highlights of this work include: Verification and validation activities performed with the Arches coal gasification simulation tool on experimental data from the CANMET gasifier (Subtask 4.1). The simulation of multiphase reacting flows with coal particles including detailed gas-phase chemistry calculations using an extension of the one-dimensional turbulence models capability (Subtask 4.2). The demonstration and implementation of the Reverse Monte Carlo ray tracing (RMCRT) radiation algorithm in the ARCHES code (Subtask 4.3). Determination of steam and CO{sub 2} gasification kinetics of bituminous coal chars at high temperature and elevated pressure under entrained-flow conditions (Subtask 4.4). In addition, attempts were made to gain insight into the chemical structure differences between young and mature coal soot, but both NMR and TEM characterization efforts were hampered by the highly reacted nature of the soot. The development, operation, and demonstration of in-situ gas phase measurements from the University of Utahs pilot-scale entrained-flow coal gasifier (EFG) (Subtask 4.6). This subtask aimed at acquiring predictable, consistent performance and characterizing the environment within the gasifier.

  5. Analysis of energy recovery potential using innovative technologies of waste gasification

    SciTech Connect

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Energy recovery from waste by gasification was simulated. Black-Right-Pointing-Pointer Two processes: high temperature gasification and gasification associated to plasma. Black-Right-Pointing-Pointer Two types of feeding waste: Refuse Derived Fuel (RDF) and pulper residues. Black-Right-Pointing-Pointer Different configurations for the energy cycles were considered. Black-Right-Pointing-Pointer Comparison with performances from conventional Waste-to-Energy process. - Abstract: In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production.

  6. COAL GASIFICATION ENVIRONMENTAL DATA SUMMARY: TRACE ELEMENTS

    EPA Science Inventory

    The report summarizes trace element measurements made at several coal gasification facilities. Most of the measurements were made as part of EPA's source testing and evaluation program on low- and medium-Btu gasification. The behavior of trace elements is discussed in light of th...

  7. Gasification of high ash, high ash fusion temperature bituminous coals

    DOEpatents

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  8. Novel Sorption Enhanced Reaction Process for Simultaneous Production of CO2 and H2 from Synthesis Gas Produced by Coal Gasification

    SciTech Connect

    Shivaji Sircar; Hugo S. Caram; Kwangkook Jeong; Michael G. Beaver; Fan Ni; Agbor Tabi Makebe

    2010-06-04

    The goal of this project is to evaluate the extensive feasibility of a novel concept called Thermal Swing Sorption Enhanced Reaction (TSSER) process to simultaneously produce H{sub 2} and CO{sub 2} as a single unit operation in a sorber-reactor. The successful demonstration of the potential feasibility of the TSSER concept implies that it is worth pursuing further development of the idea. This can be done by more extensive evaluation of the basic sorptive properties of the CO{sub 2} chemisorbents at realistic high pressures and by continuing the experimental and theoretical study of the TSSER process. This will allow us to substantiate the assumptions made during the preliminary design and evaluation of the process and firm up the initial conclusions. The task performed under this project consists of (i) retrofitting an existing single column sorption apparatus for measurement of high pressure CO{sub 2} sorption characteristics, (ii) measurement of high pressure CO{sub 2} chemisorption equilibria, kinetics and sorption-desorption column dynamic characteristics under the conditions of thermal swing operation of the TSSER process, (iii) experimental evaluation of the individual steps of the TSSER process (iv) development of extended mathematical model for simulating cyclic continuous operation of TSSER to aid in process scale-up and for guiding future work, (v) simulate and test SER concept using realistic syngas composition, (vi) extensive demonstration of the thermal stability of sorbents using a TGA apparatus, (vii) investigation of the surfaces of the adsorbents and adsorbed CO{sub 2} ,and (viii) test the effects of sulfur compounds found in syngas on the CO{sub 2} sorbents.

  9. Toxicity studies of mild gasification products

    SciTech Connect

    Ong, T.M.; Whong, W.Z.; Ma, J.; Zhong, B.Z.; Bryant, D.

    1992-01-01

    The objectives of this project are: (1) to perform mutagenicity studies with the Ames Salmonella/microsomal assay system on coal liquids produced by mild gasification from different coals and/or processing conditions, (2) to determine whether coal liquids which are mutagenic to bacteria are also genotoxic to mammalian cells, (3) to establish correlations between mutagenicity, aromaticity, and boiling point range of coal liquids, and (4) to identify the chemical classes which are likely to be responsible for the mutagenic activity of gasification products. Four of the seven samples tested so far failed to demonstrate any mutagenic activity under any conditions tested. Those samples were SHELL[number sign]830331, MG-122IBP-420[degree]F, MG-122 420--720[degree]F, and MG-122 720[degree]F+. Table 1 summarizes the results from all samples tested in DMSO and Tween 80. When solvated in DMSO, MG-119 and MG-120 composite materials displayed slight, but ultimately insignificant, genotoxic activity on TA98 and TA1OO in the presence of S9. When Tween 80 was used as the solvent, MG-119 and MG-120 displayed slight, but significant, geno-toxic activity on TA98 with S9 (Figure 4). CTC[number sign]11 in DMSO displayed significant genotoxic activity on both TA98 and TA1OO with and without S9. The activity was higher on TA98 than TA100, and higher with S9 than without, primarily indicating the presence of indirect-acting frameshift mutagen. The results of the testing on CTC[number sign]11 were similar for both solvents, DMSO and Tween 80 (Table 2).

  10. Toxicity studies of mild gasification products

    SciTech Connect

    Ong, T.M.; Whong, W.Z.; Ma, J.; Zhong, B.Z.; Bryant, D.

    1992-11-01

    The objectives of this project are: (1) to perform mutagenicity studies with the Ames Salmonella/microsomal assay system on coal liquids produced by mild gasification from different coals and/or processing conditions, (2) to determine whether coal liquids which are mutagenic to bacteria are also genotoxic to mammalian cells, (3) to establish correlations between mutagenicity, aromaticity, and boiling point range of coal liquids, and (4) to identify the chemical classes which are likely to be responsible for the mutagenic activity of gasification products. Four of the seven samples tested so far failed to demonstrate any mutagenic activity under any conditions tested. Those samples were SHELL{number_sign}830331, MG-122IBP-420{degree}F, MG-122 420--720{degree}F, and MG-122 720{degree}F+. Table 1 summarizes the results from all samples tested in DMSO and Tween 80. When solvated in DMSO, MG-119 and MG-120 composite materials displayed slight, but ultimately insignificant, genotoxic activity on TA98 and TA1OO in the presence of S9. When Tween 80 was used as the solvent, MG-119 and MG-120 displayed slight, but significant, geno-toxic activity on TA98 with S9 (Figure 4). CTC{number_sign}11 in DMSO displayed significant genotoxic activity on both TA98 and TA1OO with and without S9. The activity was higher on TA98 than TA100, and higher with S9 than without, primarily indicating the presence of indirect-acting frameshift mutagen. The results of the testing on CTC{number_sign}11 were similar for both solvents, DMSO and Tween 80 (Table 2).

  11. Gasification characteristics of an activated carbon catalyst during the decomposition of hazardous waste material in supercritical water

    SciTech Connect

    Matsumura, Yukihiko; Nuessle, F.W.; Antal, M.J. Jr.

    1996-12-31

    Recently, carbonaceous materials including activated carbon were proven to be effective catalysts for hazardous waste gasification in supercritical water. Using coconut shell activated carbon catalyst, complete decomposition of industrial organic wastes including methanol and acetic acid was achieved. During this process, the total mass of the activated carbon catalyst changes by two competing processes: a decrease in weight via gasification of the carbon by supercritical water, or an increase in weight by deposition of carbonaceous materials generated by incomplete gasification of the biomass feedstocks. The deposition of carbonaceous materials does not occur when complete gasification is realized. Gasification of the activated carbon in supercritical water is often favored, resulting in changes in the quality and quantity of the catalyst. To thoroughly understand the hazardous waste decomposition process, a more complete understanding of the behavior of activated carbon in pure supercritical water is needed. The gasification rate of carbon by water vapor at subcritical pressures was studied in relation to coal gasification and generating activated carbon.

  12. Coal gasification burner

    SciTech Connect

    Sternling, C.V.

    1988-10-04

    This patent describes a process for burning hydrocarbon in a combustion zone, comprising: introducing combustion oxygen and the hydrocarbon into a combustion chamber as a central gas flow; surrounding the combustion oxygen with a transpiration gas; and passing at least some of the transpiration gas through a porous metal passage surrounding the combustion oxygen and having a non-constricted part of lower porosity metal next to the combustion zone, the porous metal comprising a compressed powdered metal.

  13. High temperature electrochemical polishing of H{sub 2}S from coal gasification process streams. Quarterly progress report, April 1, 1995--June 30, 1995

    SciTech Connect

    Winnick, J.

    1996-02-01

    This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

  14. Advanced Gasification By-Product Utilization

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

    2006-08-31

    With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

  15. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOEpatents

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  16. Survey of integrated gasification combined cycle power plant performance estimates

    NASA Astrophysics Data System (ADS)

    Larson, J. W.

    1980-03-01

    The idea of a combined cycle power plant integrated with a coal gasification process has attracted broad interest in recent years. This interest is based on unique attributes of this concept which include potentially low pollutant emissions, low heat rate and competitive economics as compared to conventional steam plants with stack gas scrubbing. Results from a survey of technical literature containing performance and economic predictions have been compiled for comparison and evaluation of this new technique. These performance and economic results indicate good promise for near-term commercialization of an integrated gasification combined cycle power plant using current gas turbine firing temperatures. Also, these data show that advancements in turbine firing temperature are expected to provide sufficiently favorable economics for the concept to penetrate the market now held by conventional steam power plants.

  17. Power Systems Development Facility Gasification Test Campaing TC14

    SciTech Connect

    Southern Company Services

    2004-02-28

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details test campaign TC14 of the PSDF gasification process. TC14 began on February 16, 2004, and lasted until February 28, 2004, accumulating 214 hours of operation using Powder River Basin (PRB) subbituminous coal. The gasifier operating temperatures varied from 1760 to 1810 F at pressures from 188 to 212 psig during steady air blown operations and approximately 160 psig during oxygen blown operations.

  18. Thermogravimetric analysis of the gasification of microalgae Chlorella vulgaris.

    PubMed

    Figueira, Camila Emilia; Moreira, Paulo Firmino; Giudici, Reinaldo

    2015-12-01

    The gasification of microalgae Chlorella vulgaris under an atmosphere of argon and water vapor was investigated by thermogravimetric analysis. The data were interpreted by using conventional isoconversional methods and also by the independent parallel reaction (IPR) model, in which the degradation is considered to happen individually to each pseudo-component of biomass (lipid, carbohydrate and protein). The IPR model allows obtaining the kinetic parameters of the degradation reaction of each component. Three main stages were observed during the gasification process and the differential thermogravimetric curve was satisfactorily fitted by the IPR model considering three pseudocomponents. The comparison of the activation energy values obtained by the methods and those found in the literature for other microalgae was satisfactory. Quantification of reaction products was performed using online gas chromatography. The major products detected were H2, CO and CH4, indicating the potential for producing fuel gas and syngas from microalgae. PMID:26447558

  19. Power Systems Development Facility Gasification Test Campaing TC18

    SciTech Connect

    Southern Company Services

    2005-08-31

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

  20. From waste to energy -- Catalytic steam gasification of broiler litter

    SciTech Connect

    Jones, J.A.; Sheth, A.C.

    1999-07-01

    In 1996, the production of broiler chickens in the US was approximately 7.60 billion head. The quantity of litter generated is enormous. In 1992, the Southeast region alone produced over five million tons of broiler litter. The litter removed from the broiler houses is rich in nutrients and often spread over land as a fertilizer. Without careful management, the associated agricultural runoff can cause severe environmental damage. With increasing broiler litter production, the implementation of alternative disposal technologies is essential to the sustainable development of the poultry industry. A process originally developed for the conversion of coals to clean gaseous fuel may provide an answer. Catalytic steam gasification utilities an alkali salt catalyst and steam to convert a carbonaceous feedstock to a gas mixture composed primarily of carbon monoxide, carbon dioxide, hydrogen, and methane. The low to medium energy content gas produced may be utilized as an energy source or chemical feedstock. Broiler litter is an attractive candidate for catalytic steam gasification due to its high potassium content. Experiments conducted in UTSI's bench-scale high-pressure fixed bed gasifier have provided data for technical and economic feasibility studies of the process. Experiments have also been performed to examine the effects of temperature, pressure, and additional catalysts on the gasification rate.

  1. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K.

    2009-04-15

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  2. Steam gasification of carbon: Catalyst properties

    SciTech Connect

    Falconer, J.L.

    1993-01-10

    Coal gasification by steam is of critical importance in converting coal to gaseous products (CO, H[sub 2], CO[sub 2], CH[sub 4]) that can then be further converted to synthetic natural gas and higher hydrocarbon fuels. Alkali and alkaline earth metals (present as oxides) catalyze coal gasification reactions and cause them to occur at significantly lower temperatures. A more fundamental understanding of the mechanism of the steam gasification reaction and catalyst utilization may well lead to better production techniques, increased gasification rates, greater yields, and less waste. We are studying the gasification of carbon by steam in the presence of alkali and alkaline earth oxides, using carbonates as the starting materials. Carbon dioxide gasification (CO[sub 2] + C --> 2CO) has been studied in some detail recently, but much less has been done on the actual steam gasification reaction, which is the main thrust of our work. In particular, the form of the active catalyst compound during reaction is still questioned and the dependence of the concentration of active sites on reaction parameters is not known. Until recently, no measurements of active site concentrations during reaction had been made. We have recently used transient isotope tracing to determine active site concentration during CO[sub 2] gasification. We are investigating the mechanism and the concentration of active sites for steam gasification with transient isotopic tracing. For this technique, the reactant feed is switched from H[sub 2]0 to isotopically-labeled water at the same concentration and tow rate. We can then directly measure, at reaction the concentration of active catalytic sites, their kinetic rate constants, and the presence of more than one rate constant. This procedure allows us to obtain transient kinetic data without perturbing the steady-state surface reactions.

  3. Development of an advanced, continuous mild gasification process for the production of co-products. Task 4.6, Economic evaluation

    SciTech Connect

    Cohen, L.R.; Hogsett, R.F.; Sinor, J.E.; Ness, R.O. Jr.; Runge, B.D.

    1992-10-01

    The principal finding of this study was the high capital cost and poor financial performance predicted for the size and configuration of the plant design presented. The XBi financial assessment gave a disappointingly low base-case discounted cash flow rate of return (DCFRR) of only 8.1% based on a unit capital cost of $900 per ton year (tpy) for their 129,000 tpy design. This plant cost is in reasonable agreement with the preliminary estimates developed by J.E. Sinor Associates for a 117,000 tpy plant based on the FMC process with similar auxiliaries (Sinor, 1989), for which a unit capital costs of $938 tpy was predicted for a design that included char beneficiation and coal liquids upgrading--or about $779 tpy without the liquid upgrading facilities. The XBi assessment points out that a unit plant cost of $900 tpy is about three times the cost for a conventional coke oven, and therefore, outside the competitive range for commercialization. Modifications to improve process economics could involve increasing plant size, expanding the product slate that XBi has restricted to form coke and electricity, and simplifying the plant flow sheet by eliminating marginally effective cleaning steps and changing other key design parameters. Improving the financial performance of the proposed formed coke design to the level of a 20% DCFRR based on increased plant size alone would require a twenty-fold increase to a coal input of 20,000 tpd and a coke production of about 2.6 minion tpy--a scaling exponent of 0.70 to correct plant cost in relation to plant size.

  4. Co-gasification of municipal solid waste and material recovery in a large-scale gasification and melting system

    SciTech Connect

    Tanigaki, Nobuhiro; Manako, Kazutaka; Osada, Morihiro

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer This study evaluates the effects of co-gasification of MSW with MSW bottom ash. Black-Right-Pointing-Pointer No significant difference between MSW treatment with and without MSW bottom ash. Black-Right-Pointing-Pointer PCDD/DFs yields are significantly low because of the high carbon conversion ratio. Black-Right-Pointing-Pointer Slag quality is significantly stable and slag contains few hazardous heavy metals. Black-Right-Pointing-Pointer The final landfill amount is reduced and materials are recovered by DMS process. - Abstract: This study evaluates the effects of co-gasification of municipal solid waste with and without the municipal solid waste bottom ash using two large-scale commercial operation plants. From the viewpoint of operation data, there is no significant difference between municipal solid waste treatment with and without the bottom ash. The carbon conversion ratios are as high as 91.7% and 95.3%, respectively and this leads to significantly low PCDD/DFs yields via complete syngas combustion. The gross power generation efficiencies are 18.9% with the bottom ash and 23.0% without municipal solid waste bottom ash, respectively. The effects of the equivalence ratio are also evaluated. With the equivalence ratio increasing, carbon monoxide concentration is decreased, and carbon dioxide and the syngas temperature (top gas temperature) are increased. The carbon conversion ratio is also increased. These tendencies are seen in both modes. Co-gasification using the gasification and melting system (Direct Melting System) has a possibility to recover materials effectively. More than 90% of chlorine is distributed in fly ash. Low-boiling-point heavy metals, such as lead and zinc, are distributed in fly ash at rates of 95.2% and 92.0%, respectively. Most of high-boiling-point heavy metals, such as iron and copper, are distributed in metal. It is also clarified that slag is stable and contains few harmful heavy metals such as lead. Compared with the conventional waste management framework, 85% of the final landfill amount reduction is achieved by co-gasification of municipal solid waste with bottom ash and incombustible residues. These results indicate that the combined production of slag with co-gasification of municipal solid waste with the bottom ash constitutes an ideal approach to environmental conservation and resource recycling.

  5. Pyrolysis and gasification of coal at high temperatures. Final technical report, September 15, 1987--September 14, 1991

    SciTech Connect

    Zygourakis, K.

    1992-02-10

    The macropore structure of chars is a major factor in determining their reactivity during the gasification stage. The major objectives of this contract were to (a) quantify by direct measurements the effect of pyrolysis conditions of the macropore structure, and (b) establish how the macropores affected the reactivity pattern, the ignition behavior and the fragmentation of the char particles during gasification in the regime of strong diffusional limitations. Results from this project provide much needed information on the factors that affect the quality of the solid products (chars) of coal utilization processes (for example, mild gasification processes). The reactivity data will also provide essential parameters for the optimal design of coal gasification processes. (VC)

  6. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect

    Not Available

    1994-03-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 250 citations and includes a subject term index and title list.)

  7. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect

    1997-06-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  8. Coal gasification. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect

    1995-01-01

    The bibliography contains citations of selected patents concerning methods and processes for the gasification of coals. Included are patents for a variety of processes, including fluidized beds, alkali-metal catalytic systems, fixed beds, hot inert heat transfer; and in-situ, pressurized, and steam-iron processes. Topics also include catalyst recovery, desulfurization during gasification, heating methods, pretreatment of coals, heat recovery, electrical power generation, byproduct applications, and pollution control. Liquefaction of coal is examined in a related published bibliography. (Contains 250 citations and includes a subject term index and title list.)

  9. Coal gasification. Quarterly report, April-June 1979

    SciTech Connect

    1980-04-01

    In DOE's program for the conversion of coal to gaseous fuels both high-and low-Btu gasification processes are being developed. High-Btu gas can be distributed economically to consumers in the same pipeline systems now used to carry natural gas. Low-Btu gas, the cheapest of the gaseous fuels produced from coal, can be used economically only on site, either for electric power generation or by industrial and petrochemical plants. High-Btu natural gas has a heating value of 950 to 1000 Btu per standard cubic foot, is composed essentially of methane, and contains virtually no sulfur, carbon monoxide, or free hydrogen. The conversion of coal to High-Btu gas requires a chemical and physical transformation of solid coal. Coals have widely differing chemical and physical properties, depending on where they are mined, and are difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, DOE, together with the American Gas Association (AGA), is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, each of the processes under development have unique characteristics. A number of the processes for converting coal to high-Btu gas have reached the pilot plant Low-Btu gas, with a heating value of up to 350 Btu per standard cubic foot, is an economical fuel for industrial use as well as for power generation in combined gas-steam turbine power cycles. Because different low-Btu gasification processes are optimum for converting different types of coal, and because of the need to provide commercially acceptable processes at the earliest possible date, DOE is sponsoring the concurrent development of several basic types of gasifiers (fixed-bed, fluidized-bed, and entrained-flow).

  10. Aspen Process Flowsheet Simulation Model of a Battelle Biomass-Based Gasification, Fischer-Tropsch Liquefaction and Combined-Cycle Power Plant

    SciTech Connect

    1998-10-30

    This study was done to support the research and development program of the National Renewable Energy Laboratory (NREL) in the thermochemical conversion of biomass to liquid transportation fuels using current state-of-the-art technology. The Mitretek study investigated the use of two biomass gasifiers; the RENUGAS gasifier being developed by the Institute of Gas Technology, and the indirectly heated gasifier being developed by Battelle Columbus. The Battelle Memorial Institute of Columbus, Ohio indirectly heated biomass gasifier was selected for this model development because the syngas produced by it is better suited for Fischer-Tropsch synthesis with an iron-based catalyst for which a large amount of experimental data are available. Bechtel with Amoco as a subcontractor developed a conceptual baseline design and several alternative designs for indirect coal liquefaction facilities. In addition, ASPEN Plus process flowsheet simulation models were developed for each of designs. These models were used to perform several parametric studies to investigate various alternatives for improving the economics of indirect coal liquefaction.

  11. Development of an advanced continuous mild gasification process for the production of co-products. Quarterly report, January--March, 1996

    SciTech Connect

    O`Neal, G.W.

    1996-04-01

    Determination of the best furnace for a commercial coke plant is underway. A shuttle or tunnel kiln has economic advantage over a rotary hearth design. Production of 20 tons of coke in a small shuttle kiln is near completion which will provide experience for this design. Twenty tons of CTC continuous coke are being produced for testing at a General Motors` foundry. The production is approximately 75 percent complete. During this production, variables of the process are being studied to aid in design of a commercial coke plant. Raw material composition, blending, briquetting variables, and calcining heat profile are the major areas of interest. Western SynCoal Company produces a dried coal product from sub-bituminous coal. This upgraded product was evaluated for producing coke products by blending char from this coal product with the coal product along with suitable binders. The green briquettes were then calcined to produce coke. The resulting coke was judged to be usable as part of a cupola coke charge or as a fuel in cement kilns and sugar beet furnaces.

  12. Fixed-bed gasification research using US coals. Volume 10. Gasification of Benton lignite

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the tenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Benton lignite. The period of gasification test was November 1-8, 1983. 16 refs., 22 figs., 19 tabs.

  13. Effect of biomass containing zinc metal at different operating parameters on gasification efficiency.

    PubMed

    Lin, Chiou-Liang; Chen, Hsien

    2015-12-01

    This paper describes the effect of Zn on the gas production of a fluidized-bed gasifier to determine the relationship between Zn and the gasification process. Different concentrations of Zn were used in the preparation of artificial waste to elucidate the effect on gas product composition, gas product heat value, gas production rate, and H2 yield in the gasification process. Zn served to increase H2 generation during the gasification process. The molar percentage of H2 with more than 0.1 wt% additional Zn increased by 33.02% and the H2 yield was increased by 11.34% compared to that without Zn. However, the gas heat value decreased, and no significant change in the gas production rate was noted. PMID:26510615

  14. Power Systems Development Facility Gasification Test Campaign TC17

    SciTech Connect

    Southern Company Services

    2004-11-30

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results gasification operation with Illinois Basin bituminous coal in PSDF test campaign TC17. The test campaign was completed from October 25, 2004, to November 18, 2004. System startup and initial operation was accomplished with Powder River Basin (PRB) subbituminous coal, and then the system was transitioned to Illinois Basin coal operation. The major objective for this test was to evaluate the PSDF gasification process operational stability and performance using the Illinois Basin coal. The Transport Gasifier train was operated for 92 hours using PRB coal and for 221 hours using Illinois Basin coal.

  15. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    SciTech Connect

    Vas Choudhry; Stephen Kwan; Steven R. Hadley

    2001-07-01

    The objective of the project entitled ''Utilization of Lightweight Materials Made from Coal Gasification Slags'' was to demonstrate the technical and economic viability of manufacturing low-unit-weight products from coal gasification slags which can be used as substitutes for conventional lightweight and ultra-lightweight aggregates. In Phase I, the technology developed by Praxis to produce lightweight aggregates from slag (termed SLA) was applied to produce a large batch (10 tons) of expanded slag using pilot direct-fired rotary kilns and a fluidized bed calciner. The expanded products were characterized using basic characterization and application-oriented tests. Phase II involved the demonstration and evaluation of the use of expanded slag aggregates to produce a number of end-use applications including lightweight roof tiles, lightweight precast products (e.g., masonry blocks), structural concrete, insulating concrete, loose fill insulation, and as a substitute for expanded perlite and vermiculite in horticultural applications. Prototypes of these end-use applications were made and tested with the assistance of commercial manufacturers. Finally, the economics of expanded slag production was determined and compared with the alternative of slag disposal. Production of value-added products from SLA has a significant potential to enhance the overall gasification process economics, especially when the avoided costs of disposal are considered.

  16. Method for using fast fluidized bed dry bottom coal gasification

    DOEpatents

    Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  17. Crystalline structure transformation of carbon anodes during gasification

    SciTech Connect

    Kien N. Tran; Adam J. Berkovich; Alan Tomsett; Suresh K. Bhatia

    2008-05-15

    The crystalline structure transformation of five carbon anodes during gasification in air and carbon dioxide was studied using quantitative X-ray diffraction (XRD) analysis and high-resolution transmission electron microscopy (HRTEM). XRD analysis and HRTEM observations confirmed that anodes have a highly ordered graphitic structure. The examination of partially gasified samples indicated that crystalline structure transformation occurred in two stages during gasification. The first stage involved the consumption of disorganized carbon matter in the initial 15% conversion. Oxygen was found to be more reactive toward disorganized carbon at this stage of the gasification process compared to carbon dioxide. Following this stage, as more carbon was consumed, especially with the removal of smaller crystallites, it was found that the crystalline structure became more ordered with increasing conversion levels. This is due to the merging of neighboring crystallites, required to maintain the minimum energy configuration. In addition, the interaction between the pitch and the coke components was found to be strongly linked to the initial coke structure. 'Stress graphitization' occurred at the pitch-coke interface, which helps to enhance the structural development of the anodes. 26 refs., 9 figs., 3 tabs.

  18. Catalysts for carbon and coal gasification

    DOEpatents

    McKee, Douglas W. (Burnt Hills, NY); Spiro, Clifford L. (Scotia, NY); Kosky, Philip G. (Schenectady, NY)

    1985-01-01

    Catalyst for the production of methane from carbon and/or coal by means of catalytic gasification. The catalyst compostion containing at least two alkali metal salts. A particulate carbonaceous substrate or carrier is used.

  19. Numerical and experimental study of strata behavior and land subsidence in an underground coal gasification project

    NASA Astrophysics Data System (ADS)

    Sirdesai, N. N.; Singh, R.; Singh, T. N.; Ranjith, P. G.

    2015-11-01

    Underground Coal Gasification, with enhanced knowledge of hydrogeological, geomechanical and environmental aspects, can be an alternative technique to exploit the existing unmineable reserves of coal. During the gasification process, petro-physical and geomechanical properties undergo a drastic change due to heating to elevated temperatures. These changes, caused due to the thermal anisotropy of various minerals, result in the generation of thermal stresses; thereby developing new fracture pattern. These fractures cause the overhead rock strata to cave and fill the gasification chamber thereby causing subsidence. The degree of subsidence, change in fluid transport and geomechanical properties of the rock strata, in and around the subsidence zone, can affect the groundwater flow. This study aims to predict the thermo-geomechanical response of the strata during UCG. Petro-physical and geomechanical properties are incorporated in the numerical modelling software COMSOL Multiphysics and an analytical strength model is developed to validate and further study the mechanical response and heat conduction of the host rock around the gasification chamber. Once the problems are investigated and solved, the enhanced efficiency and the economic exploitation of gasification process would help meet country's energy demand.

  20. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect

    Dennis Dalrymple

    2004-06-01

    This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

  1. Economic and Technical Assessment of Wood Biomass Fuel Gasification for Industrial Gas Production

    SciTech Connect

    Anastasia M. Gribik; Ronald E. Mizia; Harry Gatley; Benjamin Phillips

    2007-09-01

    This project addresses both the technical and economic feasibility of replacing industrial gas in lime kilns with synthesis gas from the gasification of hog fuel. The technical assessment includes a materials evaluation, processing equipment needs, and suitability of the heat content of the synthesis gas as a replacement for industrial gas. The economic assessment includes estimations for capital, construction, operating, maintenance, and management costs for the reference plant. To perform these assessments, detailed models of the gasification and lime kiln processes were developed using Aspen Plus. The material and energy balance outputs from the Aspen Plus model were used as inputs to both the material and economic evaluations.

  2. Creating power, technology and products: the role of coal gasification in Ohio's economy and energy future

    SciTech Connect

    2007-12-15

    The study examines how coal gasification (CG) combined with Carbon Capture and Sequestration (CCS) technology could play a role in Ohio's economy and energy future - particularly in Northeast Ohio, a major center of manufacturing in the U.S. This working paper focuses primarily on opportunities for gasification projects to augment Ohio's economy. It examines economic activity factors related to coal gasification and how the location of a number of key support industries in Ohio could provide the state with a competitive advantage in this area. The study focuses on a polygeneration facility that would supply electricity and some other products as an example of the type of gasification facility that could, if a sufficient number of similar facilities were located in the area, serve as the stimulus for a new or expanded industry cluster. Although not further discussed in this paper, any Ohio gasification facility would be in close proximity to oil and gas fields that can serve as sites for sequestering the carbon dioxide separated out from the coal-gasification process. The potential economic impact of locating a polygeneration gasifier in Northeast Ohio is large. A significant portion of the inputs required for one $1.1+ billion facility can be supplied either within northeastern Ohio or from elsewhere in the state. Operation of the facility is estimated to increase annual statewide personal income by $39 million and Ohio output by $161 million. The Northeast Ohio region will account for 98 percent of the operational benefits. The report suggests several possible steps to convert this research to an action plan to build support for, and interest in, a coal-gasification industry cluster in Northeast Ohio. Outreach should focus on engaging industry leaders, foundations, and state and regional economic development leaders. 16 tabs., 3 apps.

  3. Utilization of lightweight materials made from coal gasification slags. Quarterly report, September 15--November 30, 1994

    SciTech Connect

    1997-07-01

    Coal gasification technologies are finding increasing commercial applications for power generation or production of chemical feedstocks. The integrated-gasification-combined-cycle (IGCC) coal conversion process has been demonstrated to be a clean, efficient, and environmentally acceptable method of generating power. However, the gasification process produces relatively large quantities of a solid waste termed slag. Regulatory trends with respect to solid waste disposal, landfill development costs, and public concern make utilization of slag a high-priority issue. Therefore, it is imperative that slag utilization methods be developed, tested, and commercialized in order to offset disposal costs. This project aims to demonstrate the technical and economic viability of the slag utilization technologies developed by Praxis to produce lightweight aggregates (LWA) and ultra-lightweight aggregates (ULWA) from slag in a large-scale pilot operation, followed by total utilization of these aggregates in a number of applications.

  4. Simulations and modeling of biomass gasification processes

    E-print Network

    Tarud, Joan

    2005-01-01

    Available, low-cost, energy supplies are vital for the world's economy and stability. The current sources of energy harm our environment and are not renewable. Therefore, technology must accommodate new sustainable sources ...

  5. TVA coal-gasification commercial demonstration plant project. Volume 5. Plant based on Koppers-Totzek gasifier. Final report

    SciTech Connect

    Not Available

    1980-11-01

    This volume presents a technical description of a coal gasification plant, based on Koppers-Totzek gasifiers, producing a medium Btu fuel gas product. Foster Wheeler carried out a conceptual design and cost estimate of a nominal 20,000 TPSD plant based on TVA design criteria and information supplied by Krupp-Koppers concerning the Koppers-Totzek coal gasification process. Technical description of the design is given in this volume.

  6. Interaction and kinetic analysis for coal and biomass co-gasification by TG-FTIR.

    PubMed

    Xu, Chaofen; Hu, Song; Xiang, Jun; Zhang, Liqi; Sun, Lushi; Shuai, Chao; Chen, Qindong; He, Limo; Edreis, Elbager M A

    2014-02-01

    This study aims to investigate the interaction and kinetic behavior of CO2 gasification of coal, biomass and their blends by thermogravimetry analysis (TG). The gas products evolved from gasification were measured online with Fourier Transform Infrared Spectroscopy (FTIR) coupled with TG. Firstly, TG experiments indicated that interaction between the coals and biomasses mainly occurred during co-gasification process. The most significant synergistic interaction occurred for LN with SD at the blending mass ratio 4:1. Furthermore, thermal kinetic analysis indicated that the activation energy involved in co-gasification decreased as the SD content increased until the blending ratio of SD with coal reached 4:1. The rise of the frequency factor indicated that the increase of SD content favored their synergistic interaction. Finally, FTIR analysis of co-gasification of SD with LN indicated that except for CO, most gases including CH3COOH, C6H5OH, H2O, etc., were detected at around 50-700C. PMID:24412857

  7. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    SciTech Connect

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28

    Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical requirement for commercial deployment of biomass-based power/heat co-generation and biofuels production. There are several commonly used syngas clean-up technologies: (1) Syngas cooling and water scrubbing has been commercially proven but efficiency is low and it is only effective at small scales. This route is accompanied with troublesome wastewater treatment. (2) The tar filtration method requires frequent filter replacement and solid residue treatment, leading to high operation and capital costs. (3) Thermal destruction typically operates at temperatures higher than 1000oC. It has slow kinetics and potential soot formation issues. The system is expensive and materials are not reliable at high temperatures. (4) In-bed cracking catalysts show rapid deactivation, with durability to be demonstrated. (5) External catalytic cracking or steam reforming has low thermal efficiency and is faced with problematic catalyst coking. Under this program, catalytic partial oxidation (CPO) is being evaluated for syngas tar clean-up in biomass gasification. The CPO reaction is exothermic, implying that no external heat is needed and the system is of high thermal efficiency. CPO is capable of processing large gas volume, indicating a very compact catalyst bed and a low reactor cost. Instead of traditional physical removal of tar, the CPO concept converts tar into useful light gases (eg. CO, H2, CH4). This eliminates waste treatment and disposal requirements. All those advantages make the CPO catalytic tar conversion system a viable solution for biomass gasification downstream gas clean-up. This program was conducted from October 1 2008 to February 28 2011 and divided into five major tasks. - Task A: Perform conceptual design and conduct preliminary system and economic analysis (Q1 2009 ~ Q2 2009) - Task B: Biomass gasification tests, product characterization, and CPO tar conversion catalyst preparation. This task will be conducted after completing process design and system economics analysis. Major milestones include identification of syngas cleaning requirements for proposed system

  8. Development of a catalytic system for gasification of wet biomass

    SciTech Connect

    Elliott, D.C.; Sealock, L.J.; Phelps, M.R.; Neuenschwander, G.G.; Hart, T.R.

    1993-08-01

    A gasification system is under development at Pacific Northwest Laboratory that can be used with high-moisture biomass feedstocks. The system operates at 350 C and 205 atm using a liquid water phase as the processing medium. Since a pressurized system is used, the wet biomass can be fed as a slurry to the reactor without drying. Through the development of catalysts, a useful processing system has been produced. This paper includes assessment of processing test results of different catalysts. Reactor system results including batch, bench-scale continuous, and engineering-scale processing results are presented to demonstrate the applicability of this catalytic gasification system to biomass. The system has utility both for direct conversion of biomass to fuel gas or as a wastewater cleanup system for treatment of unconverted biomass from bioconversion processes. By the use of this system high conversion of biomass to fuel gas can be achieved. Medium-Btu is the primary product. Potential exists for recovery/recycle of some of the unreacted inorganic components from the biomass in the aqueous byproduct stream.

  9. Development of Foster Wheeler's Vision 21 Partial Gasification Module

    SciTech Connect

    Robertson, A.

    2001-11-06

    The US Department of Energy (DOE) has awarded Foster Wheeler Development Corporation a contract to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% while producing near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The unique aspect of the process is that it utilizes a pressurized circulating fluidized bed partial gasifier and does not attempt to consume the coal in a single step. To convert all the coal to syngas in a single step requires extremely high temperatures ({approx} 2500 to 2800F) that melt and vaporize the coal and essentially drive all coal ash contaminants into the syngas. Since these contaminants can be corrosive to power generating equipment, the syngas must be cooled to near room temperature to enable a series of chemical processes to clean the syngas. Foster Wheeler's process operates at much lower temperatures that control/minimize the release of contaminants; this eliminates/minimizes the need for the expensive, complicated syngas heat exchangers and chemical cleanup systems typical of high temperature gasification. By performing the gasification in a circulating bed, a significant amount of syngas can still be produced despite the reduced temperature and the circulating bed allows easy scale up to large size plants. Rather than air, it can also operate with oxygen to facilitate sequestration of stack gas carbon dioxide gases for a 100% reduction in greenhouse gas emissions. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building block that offers all the advantages of coal gasification but in a more user friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This paper describes the test program and pilot plant that will be used to develop the PGM.

  10. Numerical study on convection diffusion for gasification agent in underground coal gasification. Part I: establishment of mathematical models and solving method

    SciTech Connect

    Yang, L.H.; Ding, Y.M.

    2009-07-01

    The aim of this article is to discuss the distribution law of the gasification agent concentration in a deep-going way during underground coal gasification and the new method of solving the problem for the convection diffusion of the gas. In this paper, the basic features of convection diffusion for the gas produced in underground coal gasification are studied. On the basis of the model experiment, through the analysis of the distribution and patterns of variation for the fluid concentration field in the process of the combustion and gasification of the coal seams within the gasifier, the 3-D non-linear unstable mathematical models on the convection diffusion for oxygen are established. In order to curb such pseudo-physical effects as numerical oscillation and surfeit which frequently occurred in the solution of the complex mathematical models, the novel finite unit algorithm, the upstream weighted multi-cell balance method is advanced in this article, and its main derivation process is introduced.

  11. Solid fuel gasification in the global energy sector (a review)

    NASA Astrophysics Data System (ADS)

    Ol'khovskii, G. G.

    2015-07-01

    In the review of the Conference on Gasification of Solid Fuels, which was held on October 2013 by the United States, the commercial use of the most advanced coal gasification systems in the chemical and power industry is considered. Data on the projects of integrated solid fuel gasification combined-cycle plants, either being developed or exploited in the United States, as well as the nature and results performed in specialized organizations to improve the existing gasification equipment and systems, are presented.

  12. An experimental investigation of sewage sludge gasification in a fluidized bed reactor.

    PubMed

    Calvo, L F; Garca, A I; Otero, M

    2013-01-01

    The gasification of sewage sludge was carried out in a simple atmospheric fluidized bed gasifier. Flow and fuel feed rate were adjusted for experimentally obtaining an air mass : fuel mass ratio (A/F) of 0.2 < A/F < 0.4. Fuel characterization, mass and power balances, produced gas composition, gas phase alkali and ammonia, tar concentration, agglomeration tendencies, and gas efficiencies were assessed. Although accumulation of material inside the reactor was a main problem, this was avoided by removing and adding bed media along gasification. This allowed improving the process heat transfer and, therefore, gasification efficiency. The heating value of the produced gas was 8.4 MJ/Nm, attaining a hot gas efficiency of 70% and a cold gas efficiency of 57%. PMID:24453863

  13. An Experimental Investigation of Sewage Sludge Gasification in a Fluidized Bed Reactor

    PubMed Central

    Calvo, L. F.; Garca, A. I.; Otero, M.

    2013-01-01

    The gasification of sewage sludge was carried out in a simple atmospheric fluidized bed gasifier. Flow and fuel feed rate were adjusted for experimentally obtaining an air mass?:?fuel mass ratio (A/F) of 0.2 < A/F < 0.4. Fuel characterization, mass and power balances, produced gas composition, gas phase alkali and ammonia, tar concentration, agglomeration tendencies, and gas efficiencies were assessed. Although accumulation of material inside the reactor was a main problem, this was avoided by removing and adding bed media along gasification. This allowed improving the process heat transfer and, therefore, gasification efficiency. The heating value of the produced gas was 8.4?MJ/Nm, attaining a hot gas efficiency of 70% and a cold gas efficiency of 57%. PMID:24453863

  14. The Mansfield Two-Stage, Low BTU Gasification System: Report of Operations

    E-print Network

    Blackwell, L. T.; Crowder, J. T.

    1983-01-01

    and steam. Low Btu gas, With these characteristics in mind and a broad which is used near its point of production, elimin base of coke handling experience, the logical evol inates the high costs of oxygen and methanation re ution was to integrate... this process of coke produc quired to produce gas that can be transmitted over tion with fixed bed coke gasification. long distance. Traditionally, coke had been a good fuel for Standard low Btu fixed bed gasifiers have his fixed bed gasification because...

  15. Gasification of biomass as a source of synfuels for developing countries

    NASA Astrophysics Data System (ADS)

    Moreira, J. R.; Antal, M. J., Jr.

    The economic viability of forest biomass gasification in furnishing feedstocks for synfuels production in Brazil is argued, on grounds of high net energy yield (due to minimal use of mechanization in the cultivation of timber such as Eucalyptus) and the high efficiency of acid hydrolysis and fast pyrolysis methods already being used. A thermochemical process still under development promises still-higher efficiency and greater economy than coal gasification and coal-fired electrical generation. Assuming a feedback cost of $1.00 per million Btu, a minimum gasoline precursor cost would be $0.35 a gallon.

  16. Uses found for gasification slag

    SciTech Connect

    Not Available

    1986-12-01

    A study carried out for the Electric Power Research Institute by Praxis Engineers, Inc. has examined possible uses for the gasifier slag produced during coal gasification. After describing some of the problems foreseen to market development, seven categories of uses are listed and briefly discussed. The possible uses for slag identified are: (1) Agriculture (soil conditioner, lime substitute, low analysis fertilizer, carrier for insecticides); (2) Industrial material (abrasive grit, catalyst and adsorbent, roofing granules, industrial filler, mineral wool production, filter media); (3) Cement and Concrete (concrete aggregate, mortar/grouting material, pozzolanic admixture, raw materials for Portland cement production, masonary unit production); (4) Road Construction and Maintenance (de-icing grit, fine aggregate for bituminous pavement, base aggregate, sub-base aggregate, seal-cost aggregate); (5) Synthetic Aggregate (lightweight construction aggregate, landscaping material, sand substitute); (6) Land Fill and Soil Stabilization (soil conditioner for improving stability, structural fill, embankment material); (7) Resource Recovery (source of carbon, magnetite, iron, aluminium, and other metals). 2 tables.

  17. Apparatus for fixed bed coal gasification

    DOEpatents

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  18. Demonstration plant for pressurized gasification of biomass feedstocks

    SciTech Connect

    Trenka, A.R. ); Kinoshita, C.M.; Takahashi, P.K.; Phillips, V.D. ); Caldwell, C. Co., Pasadena, CA ); Kwok, R. ); Onischak, M.; Babu, S.P. (Institute of Gas Technology

    1991-01-01

    A project to design, construct, and operate a pressurized biomass gasification plant in Hawaii will begin in 1991. Negotiations are underway with the United States Department of Energy (DOE) which is co-funding the project with the state of Hawaii and industry. The gasifier is a scale-up of the pressurized fluidized-bed RENUGAS process developed by the Institute of Gas Technology (IGT). The project team consists of Pacific International Center for High Technology Research (PICHTR), Hawaii Natural Energy Institute (HNEI) of the University of Hawaii, Hawaiian Commercial and Sugar Company (HC S), The Ralph M. Parsons Company, and IGT. The gasifier will be designed for 70 tons per day of sugarcane fiber (bagasse) and will be located at the Paia factory of HC S on the island of Maui. In addition to bagasse, other feedstocks such as wood, biomass wastes, and refuse-derived-fuel may be evaluated. The demonstration plant will ultimately supply part of the process energy needs for the sugar factory. The operation and testing phase will provide process information for both air- and oxygen-blown gasification, and at both low and high pressures. The process will be evaluated for both fuel gas and synthesis gas production, and for electrical power production with advanced power generation schemes. 6 refs., 3 figs., 1 tab.

  19. Low-Temperature Catalytic Gasification of Wet Biomass Residues

    SciTech Connect

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, R. Scott

    2004-10-27

    Low-temperature hydrothermal gasification can be applied to biorefinery residues as an efficient energy recovery process. Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to medium heating value gas at relatively low temperature (350 degrees Celsius). In the pressurized-water environment (21 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas is produced with high-levels of methane, as dictated by thermodynamic equilibrium. Processing systems and results will be described for both bench-scale and scaled-up reactor systems. The bench-scale systems include both short-term 1-liter batch reactor tests and longer-term continuous flow reactor tests using a 1-liter fixed bed of catalyst in a tubular reactor. The scaled-up reactor is a 4.4 liter version of the continuous flow system, which also includes a high-pressure heat exchanger to demonstrate process efficiency.

  20. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  1. Power Systems Development Facility Gasification Test Campaign TC25

    SciTech Connect

    Southern Company Services

    2008-12-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC25, the second test campaign using a high moisture lignite coal from the Red Hills mine in Mississippi as the feedstock in the modified Transport Gasifier configuration. TC25 was conducted from July 4, 2008, through August 12, 2008. During TC25, the PSDF gasification process operated for 742 hours in air-blown gasification mode. Operation with the Mississippi lignite was significantly improved in TC25 compared to the previous test (TC22) with this fuel due to the addition of a fluid bed coal dryer. The new dryer was installed to dry coals with very high moisture contents for reliable coal feeding. The TC25 test campaign demonstrated steady operation with high carbon conversion and optimized performance of the coal handling and gasifier systems. Operation during TC25 provided the opportunity for further testing of instrumentation enhancements, hot gas filter materials, and advanced syngas cleanup technologies. The PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane with syngas from the Transport Gasifier.

  2. Power Systems Development Facility Gasification Test Campaign TC24

    SciTech Connect

    Southern Company Services

    2008-03-30

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC24, the first test campaign using a bituminous coal as the feedstock in the modified Transport Gasifier configuration. TC24 was conducted from February 16, 2008, through March 19, 2008. The PSDF gasification process operated for about 230 hours in air-blown gasification mode with about 225 tons of Utah bituminous coal feed. Operational challenges in gasifier operation were related to particle agglomeration, a large percentage of oversize coal particles, low overall gasifier solids collection efficiency, and refractory degradation in the gasifier solids collection unit. The carbon conversion and syngas heating values varied widely, with low values obtained during periods of low gasifier operating temperature. Despite the operating difficulties, several periods of steady state operation were achieved, which provided useful data for future testing. TC24 operation afforded the opportunity for testing of various types of technologies, including dry coal feeding with a developmental feeder, the Pressure Decoupled Advanced Coal (PDAC) feeder; evaluating a new hot gas filter element media configuration; and enhancing syngas cleanup with water-gas shift catalysts. During TC24, the PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane.

  3. Fixed-bed gasification research using US coals. Volume 13. Gasification of Blind Canyon bituminous coal

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the thirteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Blind Canyon bituminous coal, from July 31, 1984 to August 11, 1984. 6 refs., 22 figs., 20 tabs.

  4. Fixed-bed gasification research using US coals. Volume 14. Gasification of Kemmerer subbituminous coal

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the fourteen volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Kemmerer subbituminous coal, from August 11, 1984 to August 15, 1984. 4 refs., 20 figs., 13 tabs.

  5. Fixed-bed gasification research using US coals. Volume 15. Gasification of ''fresh'' Rosebud subbituminous coal

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-09-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and government agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the fifteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Rosebud subbituminous coal, from June 17, 1985 to June 24, 1985. 4 refs., 20 figs., 15 tabs.

  6. Method of producing carbon monoxide and hydrogen by gasification of solid carbonaceous material involving microwave irradiation

    SciTech Connect

    Helm, J.L. Jr.

    1984-03-06

    A process is claimed for the gasification of carbon of solid carbonaceous material to form carbon monoxide and hydrogen by contacting the material with superheated steam and irradiating the product of said contacting with an amount of microwave energy sufficient to gasify said carbon, and apparatus therefor.

  7. VAPOR-PHASE CRACKING AND WET OXIDATION AS POTENTIAL POLLUTANT CONTROL TECHNIQUES FOR COAL GASIFICATION

    EPA Science Inventory

    The report gives results of an investigation of two techniques (hydrocracking of heavy organics in the raw gas prior to quency, and wet oxidation of the gasifier condensate) for pollutant control in coal gasification processes. Bench-scale experiments were used to determine rates...

  8. CO-GASIFICATION OF DENSIFIED SLUDGE AND SOLID WASTE IN A DOWNDRAFT GASIFIER

    EPA Science Inventory

    Thermal gasification, the subject of this report, is a new process for the co-disposal of densified sewage sludge and solid waste in a co-current flow, fixed bed reactor (also called a downdraft gasifier). The advantages of this technology include lower costs than other sewage sl...

  9. Bench-scale development of mild gasification char desulfurization. Technical report, 1 March--31 May 1994

    SciTech Connect

    Knight, R.A.

    1994-09-01

    The goal of this project is to scale up a process, developed under a previous ICCI grant, for desulfurization of mild gasification char by treatment with hydrogen-rich process-derived fuel gas at 650--760 C and 7--15 atm. The char can be converted into a low-sulfur metallurgical form coke. In the prior study, IBC-105 coal with 4.0 wt% sulfur was converted to chars with less than 1.0 wt% sulfur in a laboratory-scale batch reactor. The susceptibility of the char to desulfurization was correlated with physicochemical char properties and mild gasification conditions. Acid pretreatment of the coal prior to mild gasification was also shown to significantly enhance subsequent sulfur removal. In this study, IGT is conducting continuous bench-scale tests in a 1-lb/h fluidized-bed reactor to determine the preferred process conditions and obtain steady-state data necessary for process design and scale-up. The desulfurized chars are to be used to produce low-sulfur form coke, which will be evaluated for density, reactivity, and strength properties relevant to utilization in blast furnaces. This quarter, 2,500 g of mild gasification char was produced from untreated IBC-105 coal in the bench-scale reactor. Half of this char will be subjected to sulfuric acid treatment to enhance subsequent desulfurization. Char-producing runs were also initiated with acid-pretreated coal, which will produce about 1,250 g of char.

  10. Application of CaO-Based Bed Material for Dual Fluidized Bed Steam Biomass Gasification

    NASA Astrophysics Data System (ADS)

    Koppatz, S.; Pfeifer, C.; Kreuzeder, A.; Soukup, G.; Hofbauer, H.

    Gasification of biomass is a suitable option for decentralized energy supply based on renewable sources in the range of up to 50 MW fuel input. The paper presents the dual fluidized bed (DFB) steam gasification process, which is applied to generate high quality and nitrogen-free product gas. Essential part of the DFB process is the bed material used in the fluidized reactors, which has significant impact on the product gas quality. By the use of catalytically active bed materials the performance of the overall process is increased, since the bed material favors reactions of the steam gasification. In particular, tar reforming reactions are favored. Within the paper, the pilot plant based on the DFB process with 100kW fuel input at Vienna University of Technology, Austria is presented. Actual investigations with focus on CaO-based bed materials (limestone) as well as with natural olivine as bed material were carried out at the pilot plant. The application of CaO-based bed material shows mainly decreased tar content in the product gas in contrast to experiments with olivine as bed material. The paper presents the results of steam gasification experiments with limestone and olivine, whereby the product gas composition as well as the tar content and the tar composition are outlined.

  11. Gasification of low-grade fuels in a spouted bed for power generation

    SciTech Connect

    A.A. Belyaev

    2008-12-15

    Experimental data on the autothermal gasification of wastes from the flotation of Kuzbass coal of grade Zh and low-ash coal from the Kansk-Achinsk Basin in a spouted bed of an inert material at atmospheric pressure are presented. Capabilities for the development and use of this process for power generation based on closed-cycle gas turbine plants are analyzed.

  12. Production of hydrogen by direct gasification of coal with steam using nuclear heat

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Problems related to: (1) high helium outlet temperature of the reactor, and (2) gas generator design used in hydrogen production are studied. Special attention was given to the use of Oklahoma coal in the gasification process. Plant performance, operation, and environmental considerations are covered.

  13. Biomass Gasification Technology Assessment: Consolidated Report

    SciTech Connect

    Worley, M.; Yale, J.

    2012-11-01

    Harris Group Inc. (HGI) was commissioned by the National Renewable Energy Laboratory to assess gasification and tar reforming technologies. Specifically, the assessments focused on gasification and tar reforming technologies that are capable of producing a syngas suitable for further treatment and conversion to liquid fuels. HGI gathered sufficient information to analyze three gasification and tar reforming systems. This report summarizes the equipment, general arrangement of the equipment, operating characteristics, and operating severity for each technology. The order of magnitude capital cost estimates are supported by a basis-of-estimate write-up, which is also included in this report. The report also includes Microsoft Excel workbook models, which can be used to design and price the systems. The models can be used to analyze various operating capacities and pressures. Each model produces a material balance, equipment list, capital cost estimate, equipment drawings and preliminary general arrangement drawings. Example outputs of each model are included in the Appendices.

  14. ADVANCED GASIFICATION BY-PRODUCT UTILIZATION

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; M. Mercedes Maroto-Valer; Zhe Lu; Harold Schobert

    2005-04-01

    The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2003 to August 31, 2004. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  15. Production of Hydrogen from Underground Coal Gasification

    DOEpatents

    Upadhye, Ravindra S. (Pleasanton, CA)

    2008-10-07

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  16. Beluga coal gasification feasibility study

    SciTech Connect

    Robert Chaney; Lawrence Van Bibber

    2006-07-15

    The objective of the study was to determine the economic feasibility of developing and siting a coal-based integrated gasification combined-cycle (IGCC) plant in the Cook Inlet region of Alaska for the co-production of electric power and marketable by-products. The by-products, which may include synthesis gas, Fischer-Tropsch (F-T) liquids, fertilizers such as ammonia and urea, alcohols, hydrogen, nitrogen and carbon dioxide, would be manufactured for local use or for sale in domestic and foreign markets. This report for Phase 1 summarizes the investigation of an IGCC system for a specific industrial setting on the Cook Inlet, the Agrium U.S. Inc. ('Agrium') fertilizer plant in Nikiski, Alaska. Faced with an increase in natural gas price and a decrease in supply, the Agrium is investigating alternatives to gas as feed stock for their plant. This study considered all aspects of the installation and infrastructure, including: coal supply and cost, coal transport costs, delivery routes, feedstock production for fertilizer manufacture, plant steam and power, carbon dioxide (CO{sub 2}) uses, markets for possible additional products, and environmental permit requirements. The Cook Inlet-specific Phase 1 results, reported here, provided insight and information that led to the conclusion that the second study should be for an F-T plant sited at the Usibelli Coal Mine near Healy, Alaska. This Phase 1 case study is for a very specific IGCC system tailored to fit the chemical and energy needs of the fertilizer manufacturing plant. It demonstrates the flexibility of IGCC for a variety of fuel feedstocks depending on plant location and fuel availability, as well as the available variety of gas separation, gas cleanup, and power and steam generation technologies to fit specific site needs. 18 figs., 37 tabs., 6 apps.

  17. Transformation of alkali metals during pyrolysis and gasification of a lignite

    SciTech Connect

    Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang

    2008-05-15

    Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

  18. The fate of sulfur in mild gasification liquids

    SciTech Connect

    Knight, R.A.; Koncar, G.J.; Babu, S.P.

    1991-01-01

    This investigation addresses the determination of sulfur distribution in mild gasification liquids produced from untreated coal and from modified in two ways to reduce sulfur in the products: (a) physical mixing with a sulfur scavenger (CaO), and (b) pretreatment with aqueous alkali followed by mixing with CaO. Coal pyrolysis in the presence of CaO has previously been investigated, (3,5) showing that CaO can be effective in reducing the sulfur content of the fuel gas, and possibly that of the product liquids. Pretreatment of coals with alkaline chemicals has also been studied,(6,7) showing reduced sulfur and other changes in the liquid products.(8) Data on sulfur distribution in the liquid products could be useful for understanding the chemistry of alkali pretreatment and CaO interaction with coal sulfur during pyrolysis. In this work, a pyrolysis-gas chromatography (Py-GC) technique that simulates mild gasification on a milligram scale was used in conjunction with a carbon-specific flame ionization detector (FID) and a sulfur-specific flame photometric detector (FPD) to determine the sulfur distribution in oils/tars from Illinois No. 6 coal. A low-resolution packed GC column was employed to resolve oils/tars by carbon number, with ranges selected to approximate distillation fractions which might be recovered from a commercial mild gasification process. Oils/tars up to C{sub 18} were also collected from the pyro-probe effluent into dichloromethane for off-line study using a high-resolution GC with atomic emission detector (GC/AED) and with GC-mass spectrometry (GC/MS) to measure specific sulfur compounds. 9 refs., 1 tab.

  19. An investigation into the impact of CO2 co-feed on pyrolysis and gasification.

    PubMed

    Kwon, Eilhan; Kim, Sungpyo

    2010-08-01

    This paper presents experimental results of the impact of CO(2) co-feed on a gasification/pyrolysis process for various feedstocks (biomass, coal, and municipal solid waste (MSW)). Various feedstocks were thermo-gravimetrically characterized under various atmospheric conditions and heating rates. A substantial amount of char burn out was identified in the presence of CO(2) via a series of thermo-gravimetric analysis tests, which enabled high conversion of final mass (approximately 99%) to be achieved. The impact of CO(2) co-feed on the volatilization regime during the pyrolysis/gasification process was not apparent at a heating rate of 10-40 degrees C min(-1). However, the impact of CO(2) on the volatilization regime at a fast heating rate (950 degrees C min(-1)) was substantial. For example, significant enhancement in the generation of CO, by a factor of approximately 2, was observed in the presence of CO(2). The generation of major chemical species, such as CH(4) and C(2)H(4), were enhanced, but this was not as apparent as in the case with CO. In addition, introducing CO(2) to the pyrolysis/gasification process enabled the amount of condensable liquid hydrocarbons, such as tar (approximately 30-40%) to be significantly reduced in the presence of CO(2), in that injecting CO(2) into the pyrolysis/gasification process expedites cracking the volatilized chemical species. Experimental work confirmed that biomass and MSW could be feasible and desirable feedstocks for the pyrolysis/gasification process as these feedstocks can be easily treated compared to coal. To extend this understanding to a more practical level, various feedstocks were tested in a tubular reactor and drop tube reactor under various experimental conditions. PMID:20546843

  20. Development of Pressurized Circulating Fluidized Bed Partial Gasification Module (PGM)

    SciTech Connect

    A. Robertson

    2003-12-31

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1 - December 31, 2003 time period.

  1. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Archie Robertson

    2002-07-10

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2002 time period.

  2. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Unknown

    2003-01-30

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1--December 31, 2002 time period.

  3. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Archie Robertson

    2003-10-29

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the July 1--September 30, 2003 time period.

  4. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Archie Robertson

    2003-07-23

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2003 time period.

  5. Development of Pressurized Circulating Fluidized Bed Partial Gasification Module (PGM)

    SciTech Connect

    A. Robertson

    2002-09-30

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the July 1-September 30, 2002 time period.

  6. A case-study of landfill minimization and material recovery via waste co-gasification in a new waste management scheme.

    PubMed

    Tanigaki, Nobuhiro; Ishida, Yoshihiro; Osada, Morihiro

    2015-03-01

    This study evaluates municipal solid waste co-gasification technology and a new solid waste management scheme, which can minimize final landfill amounts and maximize material recycled from waste. This new scheme is considered for a region where bottom ash and incombustibles are landfilled or not allowed to be recycled due to their toxic heavy metal concentration. Waste is processed with incombustible residues and an incineration bottom ash discharged from existent conventional incinerators, using a gasification and melting technology (the Direct Melting System). The inert materials, contained in municipal solid waste, incombustibles and bottom ash, are recycled as slag and metal in this process as well as energy recovery. Based on this new waste management scheme with a co-gasification system, a case study of municipal solid waste co-gasification was evaluated and compared with other technical solutions, such as conventional incineration, incineration with an ash melting facility under certain boundary conditions. From a technical point of view, co-gasification produced high quality slag with few harmful heavy metals, which was recycled completely without requiring any further post-treatment such as aging. As a consequence, the co-gasification system had an economical advantage over other systems because of its material recovery and minimization of the final landfill amount. Sensitivity analyses of landfill cost, power price and inert materials in waste were also conducted. The higher the landfill costs, the greater the advantage of the co-gasification system has. The co-gasification was beneficial for landfill cost in the range of 80 Euro per ton or more. Higher power prices led to lower operation cost in each case. The inert contents in processed waste had a significant influence on the operating cost. These results indicate that co-gasification of bottom ash and incombustibles with municipal solid waste contributes to minimizing the final landfill amount and has great possibilities maximizing material recovery and energy recovery from waste. PMID:25182227

  7. BIOMASS GASIFICATION PILOT STUDY PLANT STUDY

    EPA Science Inventory

    The report gives results of a gasification pilot program using two biomass feedstocks: bagasse pellets and wood chips. he object of the program was to determine the properties of biomass product gas and its suitability as a fuel for gas-turbine-based power generation cycles. he f...

  8. EFFECT OF UNDERGROUND COAL GASIFICATION ON GROUNDWATER

    EPA Science Inventory

    The potential effect of underground coal gasification on groundwater has been examined in a laboratory study. The study was directed at Fruitland Formation subbituminous coal of the San Juan Basin and at the groundwater found in this coal seam. Two wells were drilled into the coa...

  9. Comparison of coal gasification and combustion residues

    SciTech Connect

    Turner, R.R.; Lowry, P.D.

    1983-04-01

    Slags produced from the entrained flow gasification and cyclone furnace combustion of Pittsburgh seam coal are morphologically similar and exhibit similar leaching behavior. Both wastes consist predominantly of dense glassy shards with low specific surface area (<1 m/sup 2//g). Based on aqueous extraction and inorganic analyses according to the extraction procedure specified under the Resource Conservation and Recovery Act (RCRA), none of the combustion or gasification solid wastes examined in this study would be classified as hazardous under current federal regulations. The concentrations of most trace elements in RCRA and other batch extracts of the gasification slag and combustion bottom wastes were below current or proposed drinking water levels. In contrast, arsenic, cadmium, chromium, selenium, zinc, manganese, copper, and sulfate in batch extracts of two combustion fly ashes from Pittsburgh coal exceeded drinking water criteria. These results suggest that slags from entrained flow coal gasification should not require solid waste management practices substantially different from those currently used for coal combustion solid wastes.

  10. Biomass Gasification at The Evergreen State College

    E-print Network

    Biomass Gasification at The Evergreen State College Written by Students of the Winter 2011 Program "Applied Research: Biomass, Energy, and Environmental Justice" At The Evergreen State College, Olympia://blogs.evergreen.edu/appliedresearch/ #12; i Table of Contents Chapter 1: Introduction to Biomass at the Evergreen State College by Dani

  11. Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)

    SciTech Connect

    Tarud, J.; Phillips, S.

    2011-08-01

    This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

  12. Techno-economic analysis of wastewater sludge gasification: a decentralized urban perspective.

    PubMed

    Lumley, Nicholas P G; Ramey, Dotti F; Prieto, Ana L; Braun, Robert J; Cath, Tzahi Y; Porter, Jason M

    2014-06-01

    The successful management of wastewater sludge for small-scale, urban wastewater treatment plants, (WWTPs), faces several financial and environmental challenges. Common management strategies stabilize sludge for land disposal by microbial processes or heat. Such approaches require large footprint processing facilities or high energy costs. A new approach considers converting sludge to fuel which can be used to produce electricity on-site. This work evaluated several thermochemical conversion (TCC) technologies from the perspective of small urban WWTPs. Among TCC technologies, air-blown gasification was found to be the most suitable approach. A gasification-based generating system was designed and simulated in ASPEN Plus to determine net electrical and thermal outputs. A technical analysis determined that such a system can be built using currently available technologies. Air-blown gasification was found to convert sludge to electricity with an efficiency greater than 17%, about triple the efficiency of electricity generation using anaerobic digester gas. This level of electricity production can offset up to 1/3 of the electrical demands of a typical WWTP. Finally, an economic analysis concluded that a gasification-based power system can be economically feasible for WWTPs with raw sewage flows above 0.093m(3)/s (2.1 million gallons per day), providing a profit of up to $3.5 million over an alternative, thermal drying and landfill disposal. PMID:24727699

  13. Environmental and economic performance of plasma gasification in Enhanced Landfill Mining.

    PubMed

    Danthurebandara, Maheshi; Van Passel, Steven; Vanderreydt, Ive; Van Acker, Karel

    2015-11-01

    This paper describes an environmental and economic assessment of plasma gasification, one of the viable candidates for the valorisation of refuse derived fuel from Enhanced Landfill Mining. The study is based on life cycle assessment and life cycle costing. Plasma gasification is benchmarked against conventional incineration, and the study indicates that the process could have significant impact on climate change, human toxicity, particulate matter formation, metal depletion and fossil depletion. Flue gas emission, oxygen usage and disposal of residues (plasmastone) are the major environmental burdens, while electricity production and metal recovery represent the major benefits. Reductions in burdens and improvements in benefits are found when the plasmastone is valorised in building materials instead of landfilling. The study indicates that the overall environmental performance of plasma gasification is better than incineration. The study confirms a trade-off between the environmental and economic performance of the discussed scenarios. Net electrical efficiency and investment cost of the plasma gasification process and the selling price of the products are the major economic drivers. PMID:26119012

  14. Analysis of energy recovery potential using innovative technologies of waste gasification.

    PubMed

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2012-04-01

    In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production. PMID:21889326

  15. Mild coal gasification screw pyrolyzer development and design

    SciTech Connect

    Camp, D.W.

    1990-08-01

    Our objective is to produce information and design recommendations needed for the development of an efficient continuous process for the mild gasification of caking bituminous coals. We have focused on the development of an externally heated pyrolyzer in which the sticky, reacting coal is conveyed by one or more screws. We have taken a multifaceted approach to forwarding the development of the externally-heated screw pyrolyzer. Small scale process experiments on a 38-mm single screw pyrolyzer have been a major part of our effort. Engineering analyses aimed at producing design and scaleup equations have also been important. Process design recommendations follow from these. We critically review our experimental data and experience, and information from the literature and equipment manufactures for the purpose of making qualitative recommendations for improving practical pyrolyzer design and operation. Benchscale experiments are used to supply needed data and test some preliminary concepts. 6 refs., 4 figs., 1 tab.

  16. Steam gasification of carbon: Catalyst properties

    SciTech Connect

    Falconer, J.L.; Lauderback, L.L.

    1990-12-15

    This research uses three techniques to study catalyzed gasification of carbon in an effort to determine the concentration of catalyst sites on a carbon surface and thus determine how effectively a catalyst is utilized for steam gasification. Both alkali and alkaline earth oxides are effective catalysts for accelerating the gasification rate of coal chars, but in many cases only a fraction of the catalyst is in a form that is effective for gasification. We will study the steam gasification of carbon in order to determine the concentration of active catalyst sites, the composition of the catalyst, and the location of the catalyst on the surface. Transient isotope tracing (switching reactant feed gases between H{sub 2}{sup 16}O and H{sub 2}{sup 18}O) will be used to measure the concentration of sites at steady-state reaction conditions. A steady flow of H{sub 2}{sup 16}O in He, will be replaced by H{sub 2}{sup 18}O in He, while maintaining the same reaction rate, and the change in product signals will be detected with a computer-controlled mass spectrometer. Secondary ion mass spectrometry (SIMS) will be used for both high surface area samples of carbon/carbonate mixtures that are heated in steam to various temperatures and for model surfaces with deposited ions. Scanning tunneling microscopy (STM), will be used to determine catalyst dispersion and the location of catalyst on the surface. Carbon black, graphite, and coal char will be used in the transient tracing experiments. Both K and Ca catalysts will be used.

  17. Preliminary studies on the treatment of wastewater from biomass gasification.

    PubMed

    Muzyka, Roksana; Chrubasik, Maciej; Stelmach, S?awomir; Sajdak, Marcin

    2015-10-01

    This paper presents completed research on the purification of undiluted raw water and organic condensates obtained in biomass thermal conversion processes such as gasification, which are rarely addressed in published studies. However, similar studies involving the characterization and purification of aqueous solutions obtained from process gas treatment after the gasification of biomass are available. Condensation of water-organic condensate from process gas helps to reduce the amount of water required by the purification process and the cost of the process technology and water consumption. Oil scrubbers can be used in this case instead of water scrubbers. In this case, the obtained condensate must be subjected to purification processes. This paper presents the results of our research, possible methods of treatment (chemical and biological methods), and the approximate cost of the reagents required for the purification of condensate for specific assumed degrees of purification. The best results from the chemical purification using the Fenton method were obtained with the ratio V(H2O2)/V(cond.) = 6.0 and the ratio V(H2O2)/Fe = 0.0375. To prevent precipitation of ferric hydroxide, this value can be reduced 20-fold, which reduces the total degree of purification to 90%. The cost of almost complete cleaning of tested condensates was calculated to be approximately 2000 USD per/m(3). This cost can be reduced by a factor of approximately four assuming 100% cleaning for 2-furaldehyde, furfuryl alcohol and phenol; acetaldehyde, propane-2-one (acetone), methanol and acetic acid are oxidized by 50%. PMID:26184898

  18. Catalytic gasification of wet biomass in supercritical water

    SciTech Connect

    Antal, M.J. Jr.; Matsumura, Yukihiko; Xu, Xiaodong

    1995-12-31

    Wet biomass (water hyacinth, banana trees, cattails, green algae, kelp, etc.) grows rapidly and abundantly around the world. As a biomass crop, aquatic species are particularly attractive because their cultivation does not compete with land-based agricultural activities designed to produce food for consumption or export. However, wet biomass is not regarded as a promising feed for conventional thermochemical conversion processes because the cost associated with drying it is too high. This research seeks to address this problem by employing water as the gasification medium. Prior work has shown that low concentrations of glucose (a model compound for whole biomass) can be completely gasified in supercritical water at 600{degrees}C and 34.5 Wa after a 30 s reaction time. Higher concentrations of glucose (up to 22% by weight in water) resulted in incomplete conversion under these conditions. The gas contained hydrogen, carbon dioxide, carbon monoxide, methane, ethane, propane, and traces of other hydrocarbons. The carbon monoxide and hydrocarbons are easily converted to hydrogen by commercial technology available in most refineries. This prior work utilized capillary tube reactors with no catalyst. A larger reactor system was fabricated and the heterogeneous catalytic gasification of glucose and wet biomass slurry of higher concentration was studied to attain higher conversions.

  19. Gasification coprocessing of Illinois Basin coal and RDF

    SciTech Connect

    Choudhry, V.; Kwan, S.; Pisupati, S.; Klima, M.; Banerjee, D.D.

    1998-12-31

    Gasification coprocessing of refuse-derived fuel (RDF) with coal was investigated with the objective of increasing the utilization of high-sulfur Illinois Basin coals and municipal solid waste (MSW) in an environmentally acceptable manner. MSW is a major recurring solid waste whose disposal entails tipping fees of $30--$40/ton, and poses long-term environmental problems. MSW is routinely processed to recover plastics, aluminum, and other metals as part of state-mandated recycling requirements. Following removal of noncombustibles, the remaining material, primarily paper and food wastes, is shredded to produce RDF fluff which has an as-received calorific value of {approximately} 6,000 Btu/lb. The research addressed the problems of size reduction of RDF fluff (an essential step in making a gasifier feed slurry) and production of a pumpable slurry using additives to maximize coal and RDF solids loading. Gasification evaluation of a 60% solids coal/RDF slurry was conducted in an entrained-flow, oxygen-blown, atmospheric pressure, 0.5 million Btu/h research gasifier. High carbon conversion was achieved, and the product gases contained no furans.

  20. Fate of catechols in coal gasification condensate waters

    SciTech Connect

    Uhrich, K.E.

    1986-02-01

    Even after the wastewater has been subjected to rigorous cleaning, many chemicals still remain. In order to remove these compounds, they must be identified. Catechol is a compound which appears in the condensate water and, because its concentration changes, its fate is somewhat uncertain. In recent experiments modeling the condensate water conditions, catechol solutions were aerated in the presence of ammonia. Upon acidification of the solutions, a polymer precipitates. This polymer was compared to the black compound isolated from the condensate water by spectral and elemental analyses. The structures of the two polymers were reasonably similar. The kinetics of oxidation, as determined by the uptake of oxygen, indicates that the reaction was first order in catechol and oxygen. The rate was significantly enhanced by an increase in pH. Assuming that catechol is the only subunit of the polymers isolated from the different condensate waters, calculations would indicate that the initial catechol concentration varies from 440 to 1700 ppM. An attempt is being made to account for all of the carbon that appears in the water from the gasification process. Presently, only 60% to 70% of the carbon-containing products have been identified. Part of the remaining total organic carbon can be accounted for by the catechol polymer. Studying the fate of catechol in the coal gasification condensate water will help to develop an environmentally and financially feasible treatment of the wastewater. 4 refs.

  1. The ENCOAL Mild Coal Gasification Project, A DOE Assessment

    SciTech Connect

    National Energy Technology Laboratory

    2002-03-15

    This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective, the following goals were established for the ENCOAL{reg_sign} Project: Provide sufficient quantity of products for full-scale test burns; Develop data for the design of future commercial plants; Demonstrate plant and process performance; Provide capital and O&M cost data; and Support future LFC{trademark} technology licensing efforts. Each of these goals has been met and exceeded. The plant has been in operation for nearly 5 years, during which the LFC{trademark} process has been demonstrated and refined. Fuels were made, successfully burned, and a commercial-scale plant is now under contract for design and construction.

  2. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Unknown

    2002-03-29

    Foster Wheeler Development Corporation is working under DOE contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% while producing near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The unique aspect of the process is that it utilizes a pressurized circulating fluidized bed partial gasifier and does not attempt to consume the coal in a single step. To convert all the coal to syngas in a single step requires extremely high temperatures ({approx}2500 to 2800 F) that melt and vaporize the coal and essentially drive all coal ash contaminants into the syngas. Since these contaminants can be corrosive to power generating equipment, the syngas must be cooled to near room temperature to enable a series of chemical processes to clean the syngas. Foster Wheeler's process operates at much lower temperatures that control/minimize the release of contaminants; this eliminates/minimizes the need for the expensive, complicated syngas heat exchangers and chemical cleanup systems typical of high temperature gasification. By performing the gasification in a circulating bed, a significant amount of syngas can still be produced despite the reduced temperature and the circulating bed allows easy scale up to large size plants. Rather than air, it can also operate with oxygen to facilitate sequestration of stack gas carbon dioxide gases for a 100% reduction in greenhouse gas emissions.

  3. Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer

    E-print Network

    Chen, Wei 1981-

    2012-11-27

    Thermal gasification of biomass is being considered as one of the most promising technologies for converting biomass into gaseous fuel. Here we present results of gasification, using an adiabatic bed gasifier with air, steam as gasification medium...

  4. 78 FR 43870 - Hydrogen Energy California's Integrated Gasification Combined Cycle Project; Preliminary Staff...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-22

    ... of Availability Hydrogen Energy California's Integrated Gasification Combined Cycle Project... availability of the Hydrogen Energy California's Integrated Gasification Combined Cycle Project Preliminary... the Hydrogen Energy California's (HECA) Integrated Gasification Combined Cycle Project, which would...

  5. 77 FR 59166 - South Mississippi Electric Cooperative: Plant Ratcliffe, Kemper County Integrated Gasification...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-26

    ...Integrated Gasification Combined-Cycle (IGCC) Project AGENCY: Rural...Integrated Gasification Combined-Cycle Facility located in Kemper County...Integrated Gasification Combined-Cycle (IGCC) technology for commercial...capture approximately 67% of the carbon dioxide (CO 2 )...

  6. Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474

    SciTech Connect

    Wilcox, E.

    2014-09-01

    LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

  7. Biomass Gasification Research Facility Final Report

    SciTech Connect

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology also addressed safety concerns associated with thermochemical process operation that constrain the location and configuration of potential gas analysis equipment. Initial analyzer costs, reliability, accuracy, and operating and maintenance costs were also considered prior to the assembly of suitable analyzers for this work. Initial tests at GTIs Flex-Fuel Test Facility (FFTF) in late 2004 and early 2005 successfully demonstrated the transport and subsequent analysis of a single depressurized, heat-traced syngas stream to a single analyzer (an Industrial Machine and Control Corporation (IMACC) Fourier-transform infrared spectrometer (FT-IR)) provided by GTI. In March 2005, our sampling approach was significantly expanded when this project participated in the U.S. DOEs Novel Gas Cleaning (NGC) project. Syngas sample streams from three process locations were transported to a distribution manifold for selectable analysis by the IMACC FT-IR, a Stanford Research Systems QMS300 Mass Spectrometer (SRS MS) obtained under this Cooperative Agreement, and a Varian micro gas chromatograph with thermal conductivity detector (?GC) provided by GTI. A syngas stream from a fourth process location was transported to an Agilent Model 5890 Series II gas chromatograph for highly sensitive gas analyses. The on-line analyses made possible by this sampling system verified the syngas cleaning achieved by the NGC process. In June 2005, GTI collaborated with Weyerhaeuser to characterize the ChemrecTM black liquor gasifier at Weyerhaeusers New Bern, North Carolina pulp mill. Over a ten-day period, a broad range of process operating conditions were characterized with the IMACC FT-IR, the SRS MS, the Varian ?GC, and an integrated Gas Chromatograph, Mass Selective Detector, Flame Ionization Detector and Sulfur Chemiluminescence Detector (GC/MSD/FID/SCD) system acquired under this Cooperative Agreement from Wasson-ECE. In this field application, a single sample stream was extracted from this low-pressure, low-temperature process and successfully analyzed by these devices. In late 2005,

  8. LLNL Underground-Coal-Gasification Project. Quarterly progress report, July-September 1981

    SciTech Connect

    Stephens, D.R.; Clements, W.

    1981-11-09

    We have continued our laboratory studies of forward gasification in small blocks of coal mounted in 55-gal drums. A steam/oxygen mixture is fed into a small hole drilled longitudinally through the center of the block, the coal is ignited near the inlet and burns toward the outlet, and the product gases come off at the outlet. Various diagnostic measurements are made during the course of the burn, and afterward the coal block is split open so that the cavity can be examined. Development work continues on our mathematical model for the small coal block experiments. Preparations for the large block experiments at a coal outcrop in the Tono Basin of Washington State have required steadily increasing effort with the approach of the scheduled starting time for the experiments (Fall 1981). Also in preparation is the deep gasification experiment, Tono 1, planned for another site in the Tono Basin after the large block experiments have been completed. Wrap-up work continues on our previous gasification experiments in Wyoming. Results of the postburn core-drilling program Hoe Creek 3 are presented here. Since 1976 the Soviets have been granted four US patents on various aspects of the underground coal gasification process. These patents are described here, and techniques of special interest are noted. Finally, we include ten abstracts of pertinent LLNL reports and papers completed during the quarter.

  9. Analysis of energetic and exergetic efficiency, and environmental benefits of biomass integrated gasification combined cycle technology.

    PubMed

    Mnguez, Mara; Jimnez, Angel; Rodrguez, Javier; Gonzlez, Celina; Lpez, Ignacio; Nieto, Rafael

    2013-04-01

    The problem of the high carbon dioxide emissions linked to power generation makes necessary active research on the use of biofuels in gas turbine systems as a promising alternative to fossil fuels. Gasification of biomass waste is particularly of interest in obtaining a fuel to be run in gas turbines, as it is an efficient biomass-to-biofuel conversion process, and an integration into a combined cycle power plant leads to a high performance with regard to energetic efficiency. The goal of this study was to carry out an energetic, exergetic and environmental analysis of the behaviour of an integrated gasification combined cycle (IGCC) plant fuelled with different kinds of biomass waste by means of simulations. A preliminary economic study is also included. Although a technological development in gasification technology is necessary, the results of simulations indicate a high technical and environmental interest in the use of biomass integrated gasification combined cycle (BioIGCC) systems for large-scale power generation from biomass waste. PMID:23444152

  10. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 2

    SciTech Connect

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster dsplays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume II covers papers presented at sessions 5 and 6 on system for the production of synthesis gas, and on system for the production of power. All papers have been processed for inclusion in the Energy Data Base.

  11. Study on CO? gasification properties and kinetics of biomass chars and anthracite char.

    PubMed

    Wang, Guangwei; Zhang, Jianliang; Hou, Xinmei; Shao, Jiugang; Geng, Weiwei

    2015-02-01

    The CO2 gasification properties and kinetics of three biomass chars (WS-char, RL-char and PS-char) and anthracite char (AC-char) were investigated by thermogravimetric analysis method. Three nth-order representative gas-solid reaction models, random pore model (RPM), volume reaction model (VM) and unreacted core model (URCM) were employed to describe the reactive behavior of chars. Results show that gasification reactivity order of different chars from high to low was WS-char, PS-char, RL-char and AC-char. In addition, the chemical components as well as physical structures of four chars were systematically tested. It was found that gasification properties of char were determined by carbonaceous structure. It was concluded from kinetics analysis that RPM model was the best model for describing the reactivities of biomass chars and VM was the model that best fitted the gasification process of anthracite char. The activation energies obtained for the biomass and anthracite char samples lie in the range of 236.4-284.9 kJ/mol. PMID:25479395

  12. Gasification of torrefied Miscanthus giganteus in an air-blown bubbling fluidized bed gasifier.

    PubMed

    Xue, G; Kwapinska, M; Horvat, A; Kwapinski, W; Rabou, L P L M; Dooley, S; Czajka, K M; Leahy, J J

    2014-05-01

    Torrefaction is suggested to be an effective method to improve the fuel properties of biomass and gasification of torrefied biomass should provide a higher quality product gas than that from unprocessed biomass. In this study, both raw and torrefied Miscanthus giganteus (MG) were gasified in an air-blown bubbling fluidized bed (BFB) gasifier using olivine as the bed material. The effects of equivalence ratio (ER) (0.18-0.32) and bed temperature (660-850C) on the gasification performance were investigated. The results obtained suggest the optimum gasification conditions for the torrefied M G are ER 0.21 and 800C. The product gas from these process conditions had a higher heating value (HHV) of 6.70 MJ/m(3), gas yield 2m(3)/kg biomass (H2 8.6%, CO 16.4% and CH4 4.4%) and cold gas efficiency 62.7%. The comparison between raw and torrefied M G indicates that the torrefied M G is more suitable BFB gasification. PMID:24681300

  13. Experimental and predicted approaches for biomass gasification with enriched air-steam in a fluidised bed.

    PubMed

    Fu, Qirang; Huang, Yaji; Niu, Miaomiao; Yang, Gaoqiang; Shao, Zhiwei

    2014-10-01

    Thermo-chemical gasification of sawdust refuse-derived fuel was performed on a bench-scale fluidised bed gasifier with enriched air and steam as fluidising and oxidising agents. Dolomite as a natural mineral catalyst was used as bed material to reform tars and hydrocarbons. A series of experiments were carried out under typical operating conditions for gasification, as reported in the article. A modified equilibrium model, based on equilibrium constants, was developed to predict the gasification process. The sensitivity analysis of operating parameters, such as the fluidisation velocity, oxygen percentage of the enriched air and steam to biomass ratios on the produced gas composition, lower heating value, carbon conversion and cold gas efficiency was investigated. The results showed that the predicted syngas composition was in better agreement with the experimental data compared with the original equilibrium model. The higher fluidisation velocity enhanced gas-solid mixing, heat and mass transfers, and carbon fines elutriation, simultaneously. With the increase of oxygen percentage from 21% to 45%, the lower heating value of syngas increased from 5.52?MJ?m(-3) to 7.75?MJ?m(-3) and cold gas efficiency from 49.09% to 61.39%. The introduction of steam improved gas quality, but a higher steam to biomass ratio could decrease carbon conversion and gasification efficiency owing to a low steam temperature. The optimal value of steam to biomass ratio in this work was 1.0. PMID:25265865

  14. Woody biomass and RPF gasification using reforming catalyst and calcium oxide.

    PubMed

    Kobayashi, Jun; Kawamoto, Katsuya; Fukushima, Ryutaro; Tanaka, Shingo

    2011-05-01

    This study focused on steam gasification and reforming of waste biomass using a reforming catalyst. The purpose of the study was to evaluate the durability of a commercial Ni reforming catalyst and the effect of CaO on the reforming behavior, and to clarify detailed factors of catalytic performance, as well as the effect of operating parameters on the characteristics of produced gas composition. Moreover, catalyst regeneration was carried out and the behavior of catalytic activity based on gas composition was investigated. Using a fluidized bed gasifier and a fixed bed reformer, gasification and reforming of waste biomass were carried out. Commercial Ni-based catalyst and calcined limestone (CaO) were applied to the reforming reaction. Temperature of the gasifier and reformer was almost 1023K. Ratio of steam to carbon in the feedstock [molmol(-1)] and equivalence ratio (i.e., ratio of actual to theoretical amount of oxygen) [-] were set at about 2 and 0.3, respectively. The feed rate of the feedstock into the bench-scale gasifier was almost 15kgh(-1). The results of waste biomass gasification confirmed the improvement in H(2) composition by the CO(2) absorption reaction using the reforming catalyst and CaO. In addition, CaO proved to be especially effective in decreasing the tar concentration in the case of woody biomass gasification. Catalytic activity was maintained by means of catalyst regeneration processing by hydrogen reduction after air oxidation when woody biomass was used as feedstock. PMID:21459406

  15. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 1

    SciTech Connect

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster displays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume I covers information presented at sessions 1 through 4 on systems for the production of Co-products and industrial fuel gas, environmental projects, and components and materials. Individual papers have been processed for the Energy Data Base.

  16. Gasification Studies Task 4 Topical Report, Utah Clean Coal Program

    SciTech Connect

    Whitty, Kevin; Fletcher, Thomas; Pugmire, Ronald; Smith, Philip; Sutherland, James; Thornock, Jeremy; Hunsacker, Isaac; Li, Suhui; Kelly, Kerry; Puntai, Naveen; Reid, Charles; Schurtz, Randy

    2011-09-30

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical (Subtask 4.4) and physical (Subtask 4.5) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation. Highlights of this work include: ???¢???????¢ Verification and validation activities performed with the Arches coal gasification simulation tool (Subtask 4.1). The simulation tool was expanded to handle multiphase flow, and the various submodels required for coal gasification were implemented. Several aspects of the coal gasification model were continually improved, including the numerical behavior of the multiphase model, the direct quadrature method of moments (DQMOM) and the gas-phase combustion model, as well as the parallel scalability of the simulation tool. Validation activities included exploration of several novel statistical concepts applied to constructing surrogate models for expensive functions, all extremely useful in the validation process. Several input variables were investigated, and four were of primary importance, particularly the activation energy of the high-temperature devolatilization reaction (E2). ???¢???????¢ The development of a one-dimensional turbulence (ODT) model and associated validation activities; the exploration of principal component analysis (PCA) for use in developing combustion models; and the development of interfaces to enable the use of these models (Subtask 4.2). ???¢???????¢ The identification of data for verification of the Reverse Monte Carlo ray tracing (RMCRT) radiation algorithm (Subtask 4.3). This data includes analytical solutions to idealized scenarios as well as pseudo-exact solutions from well-accepted numerical benchmark cases. The RMCRT algorithm has proven to be an accurate way to solve for radiation under gasification conditions. This algorithm has demonstrated convergence with an increase in number of rays traced, and has been implemented into the ARCHES code. ???¢???????¢ The use of the Pressurized Flat-Flame Burner (PFFB) to study pyrolysis and CO2 gasification of four coals; the development of a model for coal swelling; and the study of soot formation from a coal tar surrogate with he PFFB (Subtask 4.4). ???¢???????¢ The study of the char-slag transition for three different coals, focusing on the morphology of the partly converted material and associated density and internal surface area. The results indicate that at conversions higher than roughly 95%, the material is completely coalesced, resulting in limited accessibility of the remaining carbon (Subtask 4.5). ???¢???????¢ The development, operation, and preliminary results from the University of Utah???¢????????s pilot-scale entrained-flow coal gasifier.

  17. Operating and environmental performances of commercial-scale waste gasification and melting technology.

    PubMed

    Tanigaki, Nobuhiro; Fujinaga, Yasuka; Kajiyama, Hirohisa; Ishida, Yoshihiro

    2013-11-01

    Gasification technologies for waste processing are receiving increased interest. A lot of gasification technologies, including gasification and melting, have been developed in Japan and Europe. However, the flue gas and heavy metal behaviors have not been widely reported, even though those of grate furnaces have been reported. This article reports flue gas components of gasification and melting technology in different flue gas treatment systems. Hydrogen chloride concentrations at the inlet of the bag filter ranged between 171 and 180 mg Nm(-3) owing to de-acidification by limestone injection to the gasifier. More than 97.8% of hydrogen chlorides were removed by a bag filter in both of the flue gas treatment systems investigated. Sulfur dioxide concentrations at the inlet of the baghouse were 4.8 mg Nm(-3) and 12.7 mg Nm(-3), respectively. Nitrogen oxides are highly decomposed by a selective catalytic reduction system. Owing to the low regenerations of polychlorinated dibenzo-p-dioxins and furans, and the selective catalytic reduction system, the concentrations of polychlorinated dibenzo-p-dioxins and furans at the stacks were significantly lower without activated carbon injection. More than 99% of chlorine is distributed in fly ash. Low-boiling-point heavy metals, such as lead and zinc, are distributed in fly ash at rates of 97.6% and 96.5%, respectively. Most high-boiling-point heavy metals, such as iron and copper, are distributed in metal. It is also clarified that the slag is stable and contains few harmful heavy metals, such as lead. The heavy metal distribution behaviors are almost the same regardless of the compositions of the processed waste. These results indicate that the gasification of municipal solid waste constitutes an ideal approach to environmental conservation and resource recycling. PMID:24019383

  18. CO2 co-gasification of lower sulphur petroleum coke and sugar cane bagasse via TG-FTIR analysis technique.

    PubMed

    Edreis, Elbager M A; Luo, Guangqian; Li, Aijun; Chao, Chen; Hu, Hongyun; Zhang, Sen; Gui, Ben; Xiao, Li; Xu, Kai; Zhang, Pingan; Yao, Hong

    2013-05-01

    This study investigates the non-isothermal mechanism and kinetic behaviour of gasification of a lower sulphur petroleum coke, sugar cane bagasse and blends under carbon dioxide atmosphere conditions using the thermogravimetric analyser (TGA). The gas products were measured online with coupled Fourier transform infrared spectroscopy (FTIR). The achieved results explored that the sugar cane bagasse and blend gasification happened in two steps: at (<500 C) the volatiles are released, and at (>700 C) char gasification occurred, whereas the lower sulphur petroleum coke presented only one char gasification stage at (>800 C). Significant interactions were observed in the whole process. Some solid-state mechanisms were studied by the Coats-Redfern method in order to observe the mechanisms responsible for the gasification of samples. The results show that the chemical first order reaction is the best responsible mechanism for whole process. The main released gases are CO2, CO, CH4, HCOOH, C6H5OH and CH3COOH. PMID:23567736

  19. Gasification CFD Modeling for Advanced Power Plant Simulations

    SciTech Connect

    Zitney, S.E.; Guenther, C.P.

    2005-09-01

    In this paper we have described recent progress on developing CFD models for two commercial-scale gasifiers, including a two-stage, coal slurry-fed, oxygen-blown, pressurized, entrained-flow gasifier and a scaled-up design of the PSDF transport gasifier. Also highlighted was NETLs Advanced Process Engineering Co-Simulator for coupling high-fidelity equipment models with process simulation for the design, analysis, and optimization of advanced power plants. Using APECS, we have coupled the entrained-flow gasifier CFD model into a coal-fired, gasification-based FutureGen power and hydrogen production plant. The results for the FutureGen co-simulation illustrate how the APECS technology can help engineers better understand and optimize gasifier fluid dynamics and related phenomena that impact overall power plant performance.

  20. Catalytic Wet Gasification of Municipal and Animal Wastes

    SciTech Connect

    Ro, Kyoung S.; Cantrell, Keri; Elliott, Douglas C.; Hunt, Patrick G.

    2007-02-21

    Applicability of wet gasification technology for various animal and municipal wastes was examined. Wet gasification of swine manure and raw sewage sludge generated high number of net energies. Furthermore, the moisture content of these wastes is ideal for current wet gasification technology. Significant quantities of water must be added to dry feedstock wastes such as poultry litter, feedlot manures and MSW to make the feedstock pumpable. Because of their high ash contents, MSW and unpaved feedlot manure would not generate positive energy return from wet gasification. The costs of a conceptual wet gasification manure management system for a model swine farm were significantly higher than that of the anaerobic lagoon system. However, many environmental advantages of the wet gasification system were identified, which might reduce the costs significantly. Due to high sulfur content of the wastes, pretreatment to prevent the poisoning of catalysts is critically needed.

  1. Plasma assisted spectroscopic monitoring of alkali metals in pressurised combustion and gasification

    SciTech Connect

    Haeyrinen, V.T.; Hernberg, R.G.

    1995-07-01

    The paper describes an instrument for on-line concentration measurement of vaporised alkali compounds in pressurised industrial combustion and gasification processes. The measurement is based on Plasma Excited Alkali Resonance Line Spectroscopy (PEARLS) at the elevated pressure (1-3 MPa) of the process. Results are presented from laboratory calibration measurements and test measurements of sodium and potassium vapours resulting from the combustion of coal powder in a pressurised entrained flow reactor.

  2. Hydrogen-rich gas production via CaO sorption-enhanced steam gasification of rice husk: a modelling study.

    PubMed

    Beheshti, Sayyed Mohsen; Ghassemi, Hojat; Shahsavan-Markadeh, Rasoul; Fremaux, Sylvain

    2015-01-01

    Gasification is a thermochemical process in which solid or liquid fuels are transformed into synthesis gas through partial oxidation. In this paper, a kinetic model of rice husk gasification has been developed, which is interesting for the applications of the syngas produced. It is a zero-dimensional, steady-state model based on global reaction kinetic, empirical correlation of pyrolysis and is capable of predicting hydrogen yield in the presence of sorbent CaO. The model can also be used as a useful tool to investigate the influence of process parameters including steam/biomass ratio, CaO/fuel ratio (CaO/Fuel), and gasification temperature on hydrogen efficiency, CO2 capture ratio (CCR), and average carbonation conversion (Save). Similar to hydrogen formation, CCR also increases with increasing CaO/Fuel, but an opposite trend is exhibited in Save. Model predictions were compared with available data from the literature, which showed fairly good agreement. PMID:25403373

  3. Plasma gasification of organic containing substances as a promising way of development of alternative renewable power engineering

    NASA Astrophysics Data System (ADS)

    Rutberg, Ph G.; Bratsev, A. N.; Kuznetsov, V. A.; Kumkova, I. I.; Popov, V. E.; Surov, A. V.

    2012-12-01

    The paper deals with perspectives of large-scale implementation of the plasma gasification process of solid organic-containing substances as a source of renewable energy. First of all, such substances as wood waste, agriculture waste, solid household waste are considered. Thanks to the process of the plasma high-temperature gasification the energy of their combustion can be completely converted into the energy of the synthesis gas combustion, which use as a fuel for the combined cycle allows electricity generation with efficiency of ~60 %. Thus, if the psychogenesis production wastes are considered, this technology enables avoiding additional emission of carbon dioxide into biosphere as for production of biomass from biosphere it is extracted the same amount of carbon dioxide as is emitted at its combustion. The report represents the realized and developing designs of plasma gasification, their advantages and deficiencies.

  4. Active sites in char gasification: Final technical report

    SciTech Connect

    Wojtowicz, M.; Lilly, W.D.; Perkins, M.T.; Hradil, G.; Calo, J.M.; Suuberg, E.M.

    1987-09-01

    Among the key variables in the design of gasifiers and combustors is the reactivity of the chars which must be gasified or combusted. Significant loss of unburned char is unacceptable in virtually any process; the provision of sufficient residence time for complete conversion is essential. A very wide range of reactivities are observed, depending upon the nature of the char in a process. The current work focuses on furthering the understanding of gasification reactivities of chars. It has been well established that the reactivity of char to gasification generally depends upon three principal factors: (1) the concentration of ''active sites'' in the char; (2) mass transfer within the char; and (3) the type and concentration of catalytic impurities in the char. The present study primarily addresses the first factor. The subject of this research is the origin, nature, and fate of active sites in chars derived from parent hydrocarbons with coal-like structure. The nature and number of the active sites and their reactivity towards oxygen are examined in ''model'' chars derived from phenol-formaldehyde type resins. How the active sites are lost by the process of thermal annealing during heat treatment of chars are studied, and actual rate for the annealing process is derived. Since intrinsic char reactivities are of primary interest in the present study, a fair amount of attention was given to the model char synthesis and handling so that the effect of catalytic impurities and oxygen-containing functional groups in the chemical structure of the material were minimized, if not completely eliminated. The project would not be considered complete without comparing characteristic features of synthetic chars with kinetic behavior exhibited by natural chars, including coal chars.

  5. Wood gasification in a fluidized bed

    NASA Astrophysics Data System (ADS)

    Beck, S. R.; Wang, M. J.

    1980-04-01

    Gasification of oak sawdust in the Synthesis Gas From Manure (SGFM) pilot plant at Texas Tech University has been evaluated. The SGFM reactor operates as a countercurrent fluidized bed in which a biomass feedstock is fed to the top of the reactor and is fluidized by an air-steam mixture fed to the bottom of the reactor. Using oak sawdust from Missouri as the feedstock, the gas yields were 1.1 to 1.4 L/g daf feed when the average reactor temperature was 600 to 800 C. The gas contained about 4% C2H4 and 11% CH4. The gross heating value of the gas exceeded 11.2 MJ/cu m in all cases. The gasification of wood is compared to previous results obtained for cattle manure. The differences are due to the relative amounts of cellulose, hemicellulose, and lignin in the feedstock.

  6. Fluidized bed gasification of extracted coal

    DOEpatents

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  7. Fluidized bed gasification of extracted coal

    DOEpatents

    Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

    1986-01-01

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  8. Gasification performance of switchgrass pretreated with torrefaction and densification

    SciTech Connect

    Jaya Shankar Tumuluru; Various

    2014-08-01

    The purpose of this study was to investigate gasification performance of four switchgrass pretreatments (torrefaction at 230 and 270 C, densification, and combined torrefaction and densification) and three gasification temperatures (700, 800 and 900 C). Gasification was performed in a fixed-bed externally heated reactor with air as an oxidizing agent. Switchgrass pretreatment and gasification temperature had significant effects on gasification performance such as gas yields, syngas lower heating value (LHV), and carbon conversion and cold gas efficiencies. With an increase in the gasification temperature, yields of H2 and CO, syngas LHV, and gasifier efficiencies increased whereas CH4, CO2 and N2 yields decreased. Among all switchgrass pretreatments, gasification performance of switchgrass with combined torrefaction and densification was the best followed by that of densified, raw and torrefied switchgrass. Gasification of combined torrefied and densified switchgrass resulted in the highest yields of H2 (0.03 kg/kg biomass) and CO (0.72 kg/kg biomass), highest syngas LHV (5.08 MJ m-3), CCE (92.53%), and CGE (68.40%) at the gasification temperature of 900 C.

  9. Steam gasification of tyre waste, poplar, and refuse-derived fuel: A comparative analysis

    SciTech Connect

    Galvagno, S. Casciaro, G.; Casu, S.; Martino, M.; Mingazzini, C.; Russo, A.; Portofino, S.

    2009-02-15

    In the field of waste management, thermal disposal is a treatment option able to recover resources from 'end of life' products. Pyrolysis and gasification are emerging thermal treatments that work under less drastic conditions in comparison with classic direct combustion, providing for reduced gaseous emissions of heavy metals. Moreover, they allow better recovery efficiency since the process by-products can be used as fuels (gas, oils), for both conventional (classic engines and heaters) and high efficiency apparatus (gas turbines and fuel cells), or alternatively as chemical sources or as raw materials for other processes. This paper presents a comparative study of a steam gasification process applied to three different waste types (refuse-derived fuel, poplar wood and scrap tyres), with the aim of comparing the corresponding yields and product compositions and exploring the most valuable uses of the by-products.

  10. Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

  11. Catalytic gasification of bagasse for the production of methanol

    SciTech Connect

    Baker, E.G.; Brown, M.D.; Robertus, R.J.

    1985-10-01

    The purpose of the study was to evaluate the technical and economic feasibility of catalytic gasification of bagasse to produce methanol. In previous studies, a catalytic steam gasification process was developed which converted wood to methanol synthesis gas in one step using nickel based catalysts in a fluid-bed gasifier. Tests in a nominal 1 ton/day process development unit (PDU) gasifier with these same catalysts showed bagasse to be a good feedstock for fluid-bed gasifiers, but the catalysts deactivated quite rapidly in the presence of bagasse. Laboratory catalyst screening tests showed K/sub 2/CO/sub 3/ doped on the bagasse to be a promising catalyst for converting bagasse to methanol synthesis gas. PDU tests with 10 wt % K/sub 2/CO/sub 3/ doped on bagasse showed the technical feasibility of this type of catalyst on a larger scale. A high quality synthesis gas was produced and carbon conversion to gas was high. The gasifier was successfully operated without forming agglomerates of catalyst, ash, and char in the gasifier. There was no loss of activity throughout the runs because catalysts is continually added with the bagasse. Laboratory tests showed about 80% of the potassium carbonate could be recovered and recycled with a simple water wash. An economic evaluation of the process for converting bagasse to methanol showed the required selling price of methanol to be significantly higher than the current market price of methanol. Several factors make this current evaluaton using bagasse as a feedstock less favorable: (1) capital costs are higher due to inflation and some extra costs required to use bagasse, (2) smaller plant sizes were considered so economies of scale are lost, and (3) the market price of methanol in the US has fallen 44% in the last six months. 24 refs., 14 figs., 16 tabs.

  12. Fixed-bed gasification research using US coals. Volume 1. Program and facility description

    SciTech Connect

    Thimsen, D.; Maurer, R.E.; Poole, A.R.; Pui, D.; Liu, B.; Kittleson, D.

    1984-10-01

    The United States Department of Interior, Bureau of Mines, Twin Cities Research Center, Minneapolis, Minnesota is the site of a 6.5 foot diameter Wellman-Galusha gasifier, installed in 1977-1978. This gasifier, combustor/incinerator, and flue gas scrubber system in the past had been operated jointly by Bureau of Mines personnel, personnel from member companies of the Mining and Industrial Fuel Gas Group, and United States Department of Energy personnel-consultants. Numerous tests using a variety of coals have to date been performed. In May of 1982, Black, Sivalls and Bryson, Incorporated (BS and B) was awarded the contract to plan, execute, and report gasification test performance data from this small industrial fixed-bed gasification test facility. BS and B is responsible for program administration, test planning, test execution, and all documentation of program activities and test reports. The University of Minnesota, Particle Technology Laboratory (UMPTL) is subcontractor to BS and B to monitor process parameters, and provide analysis for material inputs and outputs. This report is the initial volume in a series of reports describing the fixed-bed gasification of US coals at the Bureau of Mines, Twin Cities Research Center. A history of the program is given in Section 1 and a thorough description of the facility in Section 2. The operation of the facility is described in Section 3. Monitoring systems and procedures are described in Sections 4 and 5. Data reduction tools are outlined in Section 6. There is no executive summary or conclusions as this volume serves only to describe the research program. Subsequent volumes will detail each gasification test and other pertinent results of the gasification program. 32 references, 23 figures, 15 tables.

  13. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Unknown

    2001-07-10

    Foster Wheeler Development Corporation is working under DOE contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% while producing near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The unique aspect of the process is that it utilizes a pressurized circulating fluidized bed partial gasifier and does not attempt to consume the coal in a single step. To convert all the coal to syngas in a single step requires extremely high temperatures ({approx}2500 to 2800F) that melt and vaporize the coal and essentially drive all coal ash contaminants into the syngas. Since these contaminants can be corrosive to power generating equipment, the syngas must be cooled to near room temperature to enable a series of chemical processes to clean the syngas. Foster Wheeler's process operates at much lower temperatures that control/minimize the release of contaminants; this eliminates/minimizes the need for the expensive, complicated syngas heat exchangers and chemical cleanup systems typical of high temperature gasification. By performing the gasification in a circulating bed, a significant amount of syngas can still be produced despite the reduced temperature and the circulating bed allows easy scale up to large size plants. Rather than air, it can also operate with oxygen to facilitate sequestration of stack gas carbon dioxide gases for a 100% reduction in greenhouse gas emissions. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building block that offers all the advantages of coal gasification but in a more user friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. The PGM consists of a pressurized circulating fluidized bed (PCFB) reactor together with a recycle cyclone and a particulate removing barrier filter. Coal, air, steam, and possibly sand are fed to the bottom of the PCFB reactor and establish a relatively dense bed of coal/char in the bottom section. As these constituents react, a hot syngas is produced which conveys the solids residue vertically up through the reactor and into the recycle cyclone. Solids elutriated from the dense bed and contained in the syngas are collected in the cyclone and drain via a dipleg back to the dense bed at the bottom of the PCFB reactor. This recycle loop of hot solids acts as a thermal flywheel and promotes efficient solid-gas chemical reaction.

  14. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated system that exceeds the U.S. Department of Energy (DOE) goal of 40% (HHV) efficiency at emission levels well below the DOE suggested limits; and (5) An advanced biofueled power system whose levelized cost of electricity can be competitive with other new power system alternatives.

  15. Proceedings of the ninth annual underground coal gasification symposium

    SciTech Connect

    Wieber, P.R.; Martin, J.W.; Byrer, C.W.

    1983-12-01

    The Ninth Underground Coal Gasification Symposium was held August 7 to 10, 1983 at the Indian Lakes Resort and Conference Center in Bloomingdale, Illinois. Over one-hundred attendees from industry, academia, National Laboratories, State Government, and the US Government participated in the exchange of ideas, results and future research plans. Representatives from six countries including France, Belgium, United Kingdom, The Netherlands, West Germany, and Brazil also participated by presenting papers. Fifty papers were presented and discussed in four formal sessions and two informal poster sessions. The presentations described current and future field testing plans, interpretation of field test data, environmental research, laboratory studies, modeling, and economics. All papers were processed for inclusion in the Energy Data Base.

  16. A Hydrodynamic Characteristic of a Dual Fluidized Bed Gasification

    NASA Astrophysics Data System (ADS)

    Sung, Yeon Kyung; Song, Jae Hun; Bang, Byung Ryeul; Yu, Tae U.; Lee, Uen Do

    A cold model dual fluidized bed (DFB) reactor, consisting of two parallel interconnected bubbling and fast fluidized beds, was designed for developing an auto-thermal biomass gasifier. The combustor of this system burns the rest char of the gasification process and provides heat to the gasifier by circulating solids inventory. To find an optimal mixing and circulation of heavy solid inventory and light biomass and char materials, we investigate two types of DFB reactors which have different configuration of distributor and way-out location of the solid inventory and char materials in the gasifier. To determine appropriate operating conditions, we measured minimum fluidization velocity, solid circulation rate, axial solid holdup and gas bypassing between the lower loop seal and the gasifier.

  17. Lock hopper values for coal gasification plant service

    NASA Technical Reports Server (NTRS)

    Schoeneweis, E. F.

    1977-01-01

    Although the operating principle of the lock hopper system is extremely simple, valve applications involving this service for coal gasification plants are likewise extremely difficult. The difficulties center on the requirement of handling highly erosive pulverized coal or char (either in dry or slurry form) combined with the requirement of providing tight sealing against high-pressure (possibly very hot) gas. Operating pressures and temperatures in these applications typically range up to 1600 psi (110bar) and 600F (316C), with certain process requirements going even higher. In addition, and of primary concern, is the need for reliable operation over long service periods with the provision for practical and economical maintenance. Currently available data indicate the requirement for something in the order of 20,000 to 30,000 open-close cycles per year and a desire to operate at least that long without valve failure.

  18. Commercial demonstration of biomass gasification the Vermont project

    SciTech Connect

    Farris, S.G.; Weeks, S.T.

    1996-12-31

    Thermal gasification of biomass for use in gas turbine combined cycle plants will improve efficiencies and reduce capital intensity in the forest and paper industry. One such technology has over 20,000 successful hours of operation at Battelle Columbus Labs (BCL) process research unit (PRU), including the first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification biomass. A commercial scale demo of the technology (rated at 200 dry tons per day) will be constructed and put into operation during the first quarter of 1997. The initial project phase will provide fuel gas to McNeil`s power boiler. A subsequent phase will utilize the fuel gas in a combustion gas turbine. The technology utilizes an extremely high throughput circulating fluid bed (CFB) gasifier in which biomass (which typically contains 85 percent to 90 percent volatiles) is fully devolatilized with hot sand from a CFB char combustor. The fuel gas is then cooled and conditioned by a conventional scrubbing system to remove particulate, condensable organics, ammonia and metal aerosols which could otherwise cause turbine emission and blade fouling problems. Alternate hot gas conditioning systems are also being developed for final gas clean-up. The fuel gas heating value is 450 to 500 Btus per standard cubic foot. A mid size gas turbine combined cycle plant utilizing the technology will have an approximate net cycle efficiency of 35-40 percent. This compares to a conventional biomass plant with an overall net cycle efficiency of 20-25 percent. Capital costs are expected to be low as the process operates at low pressures without the requirement of an oxygen plant.

  19. Environmental report for the Gasification Product Improvement Facility (GPIF)

    SciTech Connect

    Sadowski, R.S.; Skinner, W.H.; Norris, E.S.; Duck, R.R.; Hass, R.B.; Morgan, M.E.; Helble, J.J.; Johnson, S.A.

    1993-01-01

    The Fossil Energy Program has a mission to develop energy systems that utilize national coal resources in power systems with increased efficiency and environmental compatibility. Coal gasification technology is a versatile candidate that meets this goal. This two phased project consists primarily of the design, construction and operation of a 5-foot inside diameter (minimum) fixed-bed gasifier called PyGas{trademark} and supporting infrastructure (Phase I), and an additional follow on phase consisting of the design, construction and operation of a hot fuel gas cleanup unit (Phase II). Issues expected to be successfully overcome by PyGas{trademark} through its application in this test facility include the processing of high-swelling coals, which causes agglomeration in conventional fixed-bed gasifiers. Such coals comprise 87% of all eastern coals. Other issues expected to be eliminated or significantly reduced include: production of ash clinkers, production of ammonia, the presence of significant tars and fines, and the volatilization of alkalinity in the product fuel gas. A second portion of the NEPA report is concerned with the emission of toxic metal compounds by the gasification process improvement facility (GPIF). The GPIF facility will be located on site at the Fort Martin facility of Allegheny Power Company, and the energy produced (steam) will be directly used by Fort Martin to produce electricity. The coal used at the GPIF facility will be the same coal used by the utility. Therefore, the emissions of the GPIF will be put in context of the entire facility. The GPIF assessment will be divided into four sections: Estimation of the toxic metals content of the raw coal; calculation of the emissions from Fort Martin normally; an estimate of the emission from the GPIF; and a comparison of the two flows.

  20. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect

    Archie Robertson

    2004-07-01

    Foster Wheeler Power Group, Inc. is working under US Department of Energy Contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. Under this contract a series of pilot plant tests are being conducted to ascertain PGM performance with a variety of fuels. The performance and economics of a PGM based plant designed for the co-production of hydrogen and electricity will also be determined. This report describes the work performed during the April-June 30, 2004 time period.

  1. Subtask 3.16 - Low-Cost Coal-Water Fuel for Entrained-Flow Gasification

    SciTech Connect

    Anderson, C.M.

    1997-10-01

    The specific objective of this research project is to assess the potential process efficiency and pollution control benefits that may occur by applying the hydrothermal, or hot water-drying, process to low-rank coals as related to entrained-flow gasification systems. Project emphasis is on identifying more efficient coal dewatering and CWF formulation methods prior to gasification. A favorable estimate of incremental cost for integrated hydrothermal drying depends, in part, on increasing the particle size of the feed coal from minus 100 to minus 28 mesh for the purpose of simplifying the slurry concentration process. Two options will be reviewed for dewatering or concentrating the processed slurry: (1) repressurization and then concentration with sieve bends or (2) partial dewatering at system pressure with hydroclones. Both have their own merits, sieve bends being a low-cost alternative, while hydroclone application would not require additional pumping sections prior to gasification. Various CWF samples with different particle-size distributions and solids concentrations will be sent to equipment vendors for application review. Also, EERC cost models will be used to calculate the integral cost of adding the partial dewatering to the hydrothermal technology for a commercial-size facility.

  2. Bench-scale development of mild gasification char desulfurization; [Quarterly] report, September 1--November 30, 1993

    SciTech Connect

    Knight, R.A.

    1994-03-01

    This goal of this project is to scale up a process, developed under a previous ICCI grant, for desulfurization of mild gasification char by treatment with hydrogen-rich process-derived fuel gas at 650{degree}--760{degree}C and 7-15 atm. The char can be converted into a low-sulfur metallurgical form coke. In the prior study, IBC-105 coal with 4.0 wt % sulfur was converted to chars with less than 1.0 wt % sulfur in a laboratory-scale batch reactor. The susceptibility of the char to desulfurization was correlated with physicochemical char properties and mild gasification conditions. Acid pretreatment of the coal prior to mild gasification was also shown to significantly enhance subsequent sulfur removal. In this study, IGT is conducting continuous bench-scale tests in a 1-lb/h fluidized-bed reactor to determine the preferred process conditions and obtain steady-state data necessary for process design and scale-up. The desulfurized chars are to be used to produce low-sulfur form coke, which will be evaluated for density, reactivity, and strength properties relevant to utilization in blast furnaces. During the first quarter, 180 lb (82 kg) of IBC-105 coal was obtained and subjected to crushing, and sizing to prepare 49 lb (22 kg) of material for test operation.

  3. Production of mild gasification coproducts

    SciTech Connect

    1994-12-01

    In summary, the co-product production runs performed by the SGI Development Center yielded sufficient simulated PDF (process derived fuel) and CDL (coal derived liquid) to meet the production needs for each of the four coals. The LFC Process appears to be an attractive method for upgrading all of the coals except for the Knife River Coal because of its limited yield and difficulty in processing. The Buckskin coal appears to be a slightly stronger candidate for upgrading than the other three coals because it has the greatest CDL yield and a more than 50% increase in heating value from ROM to PDF. (LFC processing of Usibelli and Sarpy Creek coal produces more PDF, but the heating value increase is less and the oil yields are low. Processing Knife River coal produces much less PDF but a greater heating value increase because of its higher moisture content). Finally, in all cases, the LFC Process removed significant percentage of the organic sulfur, clearly demonstrating its coal cleaning potential.

  4. Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass

    DOEpatents

    Elliott, Douglas C; Oyler, James

    2013-12-17

    Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogenous catalyst for gasification.

  5. Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass

    DOEpatents

    Elliott, Douglas C; Oyler, James R

    2014-11-04

    Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  6. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect

    Maghzi, Shawn; Subramanian, Ramanathan; Rizeq, George; Singh, Surinder; McDermott, John; Eiteneer, Boris; Ladd, David; Vazquez, Arturo; Anderson, Denise; Bates, Noel

    2011-09-30

    The U.S. Department of Energys National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GEs bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  7. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect

    Shawn Maghzi; Ramanathan Subramanian; George Rizeq; Surinder Singh; John McDermott; Boris Eiteneer; David Ladd; Arturo Vazquez; Denise Anderson; Noel Bates

    2011-09-30

    The U.S. Department of Energy??s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE??s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  8. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  9. ENVIRONMENTAL EFFECTS OF IN SITU GASIFICATION OF TEXAS LIGNITE

    EPA Science Inventory

    A general survey of the environmental effects of the in-situ gasification of Texas lignite was undertaken. The survey emphasized the following subjects: Identification of location, quality and quantity of resources; Assessment of applicable in-situ gasification technologies; Dete...

  10. Methods for sequestering carbon dioxide into alcohols via gasification fermentation

    DOEpatents

    Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

    2013-11-26

    The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

  11. Catalytic wet gasification of municipal and animal wastes

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Currently, there is worldwide interest in deriving energy from bio-based materials via gasification. Our objective was to assess the feasibility of wet gasification for treatment/energy conversion of both animal and municipal wastes. Wet wastes such as swine manure and raw sewage sludge could be pro...

  12. FUGITIVE EMISSION TESTING AT THE KOSOVO COAL GASIFICATION PLANT

    EPA Science Inventory

    The report summarizes results of a test program to characterize fugitive emissions from the Kosovo coal gasification plant in Yugoslavia, a test program implemented by the EPA in response to a need for representative data on the potential environmental impacts of Lurgi coal gasif...

  13. Low-temperature catalytic gasification of wet industrial wastes. FY 1991--1992 interim report

    SciTech Connect

    Elliott, D.C.; Neuenschwander, G.G.; Hart, T.R.; Phelps, M.R.; Sealock, L.J. Jr.

    1993-07-01

    A catalytic gasification system operating in a pressurized water environment has been developed and refined at Pacific Northwest Laboratory (PNL) for over 12 years. Initial experiments were aimed at developing kinetics information for steam gasification of biomass in the presence of catalysts. The combined use of alkali and metal catalysts was reported for gasification of biomass and its components at low temperatures (350{degrees}C to 450{degrees}C). From the fundamental research evolved the concept of a pressurized, catalytic gasification system for converting wet biomass feedstocks to fuel gas. Extensive batch reactor testing and limited continuous reactor system (CRS) testing were undertaken in the development of this system under sponsorship of the US Department of Energy. A wide range of biomass feedstocks were tested, and the importance of the nickel metal catalyst was identified. Specific use of this process for treating food processing wastes was also studied. The concept application was further expanded to encompass cleanup of hazardous wastewater streams, and results were reported for batch reactor tests and continuous reactor tests. Ongoing work at PNL focuses on refining the catalyst and scaling the system to long-term industrial needs. The process is licensed as the Thermochemical Environmental Energy System (TEES{reg_sign}) to Onsite*Ofsite, Inc., of Duarte, California. This report is a follow-on to the 1989--90 interim report [Elliott et al. 1991], which reviewed the results of the studies conducted with a fixed-bed, continuous-feed, tubular reactor. The discussion here provides an overview of experiments on the wide range of potential feedstock materials conducted in a batch reactor; development of new catalyst materials; and tests performed in continuous-flow reactors at three scales. The appendices contain the history and background of the process development, as well as more detailed descriptions and results of the recent studies.

  14. A Texas project illustrates the benefits of integrated gasification

    SciTech Connect

    Philcox, J.; Fenner, G.W.

    1997-07-14

    Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

  15. Retention of chromium (VI) on a macroporous char following ChemChar gasification and successive leaching with water and acids.

    PubMed

    Marrero, Thomas W; Manahan, Stanley E

    2005-01-01

    A granular macroporous char, triple-reverse-burn (TRB) char, was loaded with 23.40 mg Cr/g TRB char from an aqueous solution, and the retained metal was leached by water, 0.66 M nitric acid, concentrated nitric acid, and concentrated hydrochloric acid before and after treatment by a reductive thermal gasification process (ChemChar process developed by ChemChar Research, Inc., Columbia, Missouri). The chromium leachate was analyzed by flame atomic adsorption. Reverse- and forward-mode gasifications were performed on the metal-laden char. With the exception of a 10% mass loss of carbon, the reverse mode gasification process does not change the physical characteristics of the granular char, but does increase the retention of the chromium from 16.7 to 24.2%, depending on the leachant. The forward mode gasification process produces a vitrified (or glasslike) ash residue. There was an 11.6 to 13.1% increase in the retention of the chromium by the slag and ash when compared to the nongasified chromium-loaded TRB char. Chromium (VI) was effectively removed from solution by TRB char and found to be retained to a higher degree on the char after a reductive thermal treatment. PMID:15816678

  16. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect

    Pradeep Agrawal

    2004-09-07

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  17. Effect of pulsation on black liquor gasification. Final report

    SciTech Connect

    Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

    1998-12-01

    Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  18. Model Predictive Control of Integrated Gasification Combined Cycle Power Plants

    SciTech Connect

    B. Wayne Bequette; Priyadarshi Mahapatra

    2010-08-31

    The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

  19. Behavior of metals in ash melting and gasification-melting of municipal solid waste (MSW)

    SciTech Connect

    Jung, C.H.; Matsuto, T. . E-mail: matsuto@eng.hokudai.ac.jp; Tanaka, N.

    2005-07-01

    In this study, metal behavior in ash-melting and municipal solid waste (MSW) gasification-melting facilities were investigated. Eight ash-melting and three MSW gasification-melting facilities with a variety of melting processes and feedstocks were selected. From each facility, melting furnace fly ash (MFA) and molten slag were sampled, and feedstock of the ash-melting processes was also taken. For the ash melting process, the generation rate of MFA was well correlated with the ratio of incineration fly ash (IFA) in feedstock, and this was because MFA was formed mostly by mass transfer from IFA and a limited amount from bottom ash (BA). Distribution ratios of metal elements to MFA were generally determined by volatility of the metal element, but chlorine content in feedstock had a significant effect on Cu and a marginal effect on Pb. Distribution ratio of Zn to MFA was influenced by the oxidizing atmosphere in the furnace. High MFA generation and distribution ratio of non-volatile metals to MFA in gasification-melting facilities was probably caused by carry-over of fine particles to the air pollution control system due to large gas volume. Finally, dilution effect was shown to have a significant effect on metal concentration in MFA.

  20. Design of methodology for wood chips moisture estimation determined for gasification

    NASA Astrophysics Data System (ADS)

    Luk?, Ladislav; Kuna, tefan; Kizek, Jn; Repov, Magdalna

    2014-03-01

    The moisture content of the charged wood chips is a significant factor affecting the gasification process. The increased moisture content increases the demand on the energy consumption, which is needed to cover the heat consumption related to the water evaporation and adversely affects the wood gas quality and input fuel amount. Monitoring of the moisture content in wood chips is therefore the diagnostic tools suitable to evaluate the operational parameters of the whole gasification process. Present paper describes the design of the suitable methodology to measure and estimate the wood chips moisture content. The issues related to the moisture content estimation include preliminary the selection of the suitable methodology based on the assumed moisture content in the wood chips. Further factor which needs to be considered is the fact that the moisture content in wood chips is time dependent due to the changing parameters of the ambient air (as temperature, pressure and air humidity). Correctly estimated moisture content will enable to improve the wood chips gasification process.

  1. Evaluation of a Dow-based gasification-combined-cycle plant using bituminous coal

    SciTech Connect

    Hager, R.L.; Heaven, D.L. )

    1990-06-01

    The Electric Power Research Institute (EPRI) has sponsored a series of engineering and economic evaluations for a number of gasification processes, with an emphasis on second-generation technologies. This report presents the results of a detailed evaluation of the Dow Coal Gasification Process applied to a staged, integrated combined-cycle power plant. Dow's process was evaluated because it offers very attractive performance features while retaining the simplicity of a slurry-fed entrained gasifier. Dow has been operating a 24000 t/d commercial scale demonstration unit in Plaquemine, Louisiana since April 1987. The plant feedstock is a low sulfur subbituminous coal, and through October 1989 the plant gasified 800,000 tons of coal. Consecutive 30 and 90 day production records achieved to date are at an 88 and 69 percent capacity factor respectively. Eleven thousand tons of bituminous coal from Southern Utah have also been successfully gasified during March and May 1989 test runs. A plant design and cost estimate was done for a Dow-based, staged construction IGCC plant employing GE 7F combustion turbines located in the Mid-Atlantic region. Primary plant fuels are No. 2 fuel oil during the simple and combined cycle stages and Eastern bituminous coal during the gasification stage. A financial analysis investigating the effects of coal price and capacity factor was also performed. 7 figs., 28 tabs.

  2. Advanced Gasification By-Product Utilization

    SciTech Connect

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Harold Schobert

    2006-02-01

    With the recent passing of new legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2004 to August 31, 2005. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  3. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, October 1-December 31, 1982

    SciTech Connect

    1983-04-21

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process component engineering and design; and (5) laboratory support studies involving gas solids flow modeling and coal/ash behavior. 9 figures, 19 tables.

  4. Mathematical Modeling of Ultra-Superheated Steam Gasification

    NASA Astrophysics Data System (ADS)

    Xin, Fen

    Pure steam gasification has been of interest in hydrogen production, but with the challenge of supplying heat for endothermic reactions. Traditional solutions included either combusting feedstocks at the price of decreasing carbon conversion ratio, or using costly heating apparatus. Therefore, a distributed gasifier with an Ultra-Superheated-Steam (USS) generator was invented, satisfying the heat requirement and avoiding carbon combustion in steam gasification. This project developed the first version of the Ultra-Superheated-Steam-Fluidization-Model (USSFM V1.0) for the USS gasifier. A stand-alone equilibrium combustion model was firstly developed to calculate the USS mixture, which was the input to the USSFM V1.0. Model development of the USSFM V1.0 included assumptions, governing equations, boundary conditions, supporting equations and iterative schemes of guessed values. There were three nested loops in the dense bed and one loop in the freeboard. The USSFM V1.0 included one main routine and twenty-four subroutines. The USSFM V1.0 was validated with experimental data from the Enercon USS gasifier. The calculated USS mixture had a trace of oxygen, validating the initial expectation of creating an oxygen-free environment in the gasifier. Simulations showed that the USS mixture could satisfy the gasification heat requirement without partial carbon combustion. The USSFM V1.0 had good predictions on the H2% in all tests, and on other variables at a level of the lower oxygen feed. Provided with higher oxygen feed, the USSFM V1.0 simulated hotter temperatures, higher CO% and lower CO2%. Errors were explained by assumptions of equilibrium combustion, adiabatic reactors, reaction kinetics, etc. By investigating specific modeling data, gas-particle convective heat transfers were found to be critical in energy balance equations of both emulsion gas and particles, while bubble size controlled both the mass and energy balance equations of bubble gas. Parametric study suggested a lower level of oxygen feed for higher content of hydrogen. However, too little oxygen would impede fluidization in the bed. The reasonability of iterative schemes and the stability of USSFM V1.0 were tested by the sensitivity analysis of two guessed values. Analytical Hierarchy Process analysis indicated that large-scale gasification is advantageous for hydrogen production but with impediments of high capital cost and CO2 emissions. This study manifested the USS gasifier offering the possibility of generating H2-rich and CO2-lean syngas in a much cheaper distributed way. Currently, the FORTRAN-based USSFM V1.0 had a good correlation with experimental data with a small oxygen feed. On the demand of wider applications, suggestions were proposed at last for the model improvement in future.

  5. Development of a model of entrained flow coal gasification and study of aerodynamic mechanisms of action on gasifier operation

    NASA Astrophysics Data System (ADS)

    Abaimov, N. A.; Ryzhkov, A. F.

    2015-11-01

    Problems requiring solution in development of modern highly efficient gasification reactor of a promising high power integrated gasification combined-cycle plant are formulated. The task of creating and testing a numerical model of an entrained-flow reactor for thermochemical conversion of pulverized coal is solved. The basic method of investigation is computational fluid dynamics. The submodel of thermochemical processes, including a single-stage scheme of volatile substances outlet and three heterogeneous reactions of carbon residue conversion (complete carbon oxidation, Boudouard reaction and hydrogasification), is given. The mass loss rate is determined according to the basic assumptions of the diffusion-kinetic theory. The equations applied for calculation of the process of outlet of volatile substances and three stages of fuel gasifi-cation (diffusion of reagent gas toward the surface of the coal particle, heterogeneous reactions of gas with carbon on its surface, and homogeneous reactions beyond the particle surface) are presented. The universal combined submodel Eddy Dissipation/Finite Rate Chemistry with standard (built-in) constants is used for numerical estimates. Aerodynamic mechanisms of action on thermochemical processes of solid fuel gasification are studied, as exemplified by the design upgrade of a cyclone reactor of preliminary thermal fuel preparation. Volume concentrations of combustible gases and products of complete combustion in the syngas before and after primary air and pulverized coal flows' redistribution are given. Volume concentrations of CO in syngas at different positions of tangential secondary air inlet nozzle are compared.

  6. Analysis of the product gas from biomass gasification by means of laser spectroscopy

    NASA Astrophysics Data System (ADS)

    Karellas, S.; Karl, J.

    2007-09-01

    The use of biomass and waste for decentralised combined heat and power production (CHP) requires highly efficient gasification processes. In the Technische Universitt Mnchen (TUM), an innovative gasification technology has been developed. This allothermal gasifier is producing a hydrogen- rich, high-calorific gas, that can be further used in a microturbine or a fuel cell producing energy. For the operation of such a system, the online analysis of the composition of the product gas is of high importance, since the efficient working of the machines is linked with the gas quality. For this purpose an optical measurement system based on laser spectroscopy has been applied. This system can measure not only the basic components of the product gas (H 2, CH 4, CO, CO 2, H 2O), but it also gives information concerning the content of high hydrocarbons, the so-called tars, in the product gas.

  7. Bench-scale studies on gasification of biomass in the presence of catalysts

    SciTech Connect

    Mudge, L.K.; Baker, E.G.; Brown, M.D.; Wilcox, W.A.

    1987-11-01

    This report summarizes the results of bench-scale studies on the development of catalysts for conversion of biomass to specific gas products. The primary objective of these studies was to define operating conditions that allow long lifetimes for secondary catalysts used in biomass gasification. Nickel-based catalysts that were found to be active for conversion of wood to synthesis gases in previous studies were evaluated. These catalysts remained active indefinitely in laboratory studies but lost activity rapidly when evaluated in a process research unit. Bench-scale equipment was designed and installed to resolve the differences between laboratory and PRU results. Primary catalysts (alkali carbonates) were also evaluated for their effectiveness in improving conversion yields from biomass gasification. 21 refs., 27 figs., 19 tabs.

  8. Synthesis of a high-yield activated carbon by air gasification of macadamia nut shell charcoal

    SciTech Connect

    Dai, X.; Antal, M.J. Jr.

    1999-09-01

    Macadamia nut shell charcoal was heated in an inert environment to temperatures above 1000 K (carbonized), reacted with oxygen (Po{sub 2} = 2.68--11.3 kPa) at temperatures between 525 and 586 K (oxygenated), and heated again in an inert environment to temperatures above 1000 K (activated) to produce an activated carbon. Carbons produced by this process possess surface areas and iodine numbers in the range of 400--550. Overall yields of these carbons (based on the dry, raw macadamia nut shell feed) ranged from 24 to 30 wt %. Under the conditions employed in this work, the rates of chemisorption and gasification were not mass transfer limited. Initially, the gasification reaction was first-order with respect to oxygen concentration but became independent of oxygen concentration as the surface sites of the carbon became saturated with oxygen.

  9. Techno-economic analysis of advanced biofuel production based on bio-oil gasification.

    PubMed

    Li, Qi; Zhang, Yanan; Hu, Guiping

    2015-09-01

    This paper evaluates the economic feasibility of an integrated production pathway combining fast pyrolysis and bio-oil gasification. The conversion process is simulated with Aspen Plus for a 2000 metric ton per day facility. Techno-economic analysis of this integrated pathway has been conducted. A total capital investment of $510 million has been estimated and the minimum fuel selling price (MSP) is $5.59 per gallon of gasoline equivalent. The sensitivity analysis shows that the MSP is most sensitive to internal rate of return, fuel yield, biomass feedstock cost, and fixed capital investment. Monte-Carlo simulation shows that MSP for bio-oil gasification would be more than $6/gal with a probability of 0.24, which indicates this pathway is still at high risk with current economic and technical situation. PMID:25983227

  10. Coal gasification systems engineering and analysis, volume 2

    NASA Technical Reports Server (NTRS)

    1980-01-01

    The major design related features of each generic plant system were characterized in a catalog. Based on the catalog and requirements data, approximately 17 designs and cost estimates were developed for MBG and alternate products. A series of generic trade studies was conducted to support all of the design studies. A set of cost and programmatic analyses were conducted to supplement the designs. The cost methodology employed for the design and sensitivity studies was documented and implemented in a computer program. Plant design and construction schedules were developed for the K-T, Texaco, and B&W MBG plant designs. A generic work breakdown structure was prepared, based on the K-T design, to coincide with TVA's planned management approach. An extensive set of cost sensitivity analyses was completed for K-T, Texaco, and B&W design. Product price competitiveness was evaluated for MBG and the alternate products. A draft management policy and procedures manual was evaluated. A supporting technology development plan was developed to address high technology risk issues. The issues were identified and ranked in terms of importance and tractability, and a plan developed for obtaining data or developing technology required to mitigate the risk.

  11. Experimental and numerical study of steam gasification of a single charcoal particle

    SciTech Connect

    Mermoud, F.; Van de Steene, L.; Salvador, S.; Dirion, J.L.

    2006-04-15

    The present work deals with a study coupling experiments and modeling of charcoal gasification by steam at large particle scale. A reliable set of experiments was first established using a specially developed 'macro-TG' apparatus where a particle was suspended and continuously weighed during its gasification. The main control parameters of a fixed-bed process were modified separately: steam gasification of beech charcoal spheres of different diameters (10 to 30 mm) was studied at different temperatures (830 to 1030{sup o}C), different steam partial pressures (0.1 to 0.4 atm H{sub 2}O), and different gas velocities around the particle (0.09 to 0.30 m/s). Simulations with the particle model were performed for each case. Confrontations with experimental data indicate that the model predictions are both qualitatively and quantitatively satisfactory, with an accuracy of 7%, until 60% of conversion, despite the fact that the phenomena of reactive surface evolution and particle fracturing are not well understood. Anisotropy and peripheral fragmentation make the end of the process difficult to simulate. Finally, an analysis of the thermochemical situation is proposed: it is demonstrated that the usual homogeneous or shrinking core particle models are not satisfying and that only the assumption of thermal equilibrium between the particle and the surrounding gas is valid for a model at bed scale. (author)

  12. Study on Tar Generated from Downdraft Gasification of Oil Palm Fronds

    PubMed Central

    Atnaw, Samson Mekbib; Kueh, Soo Chuan; Sulaiman, Shaharin Anwar

    2014-01-01

    One of the most challenging issues concerning the gasification of oil palm fronds (OPF) is the presence of tar and particulates formed during the process considering its high volatile matter content. In this study, a tar sampling train custom built based on standard tar sampling protocols was used to quantify the gravimetric concentration of tar (g/Nm3) in syngas produced from downdraft gasification of OPF. The amount of char, ash, and solid tar produced from the gasification process was measured in order to account for the mass and carbon conversion efficiency. Elemental analysis of the char and solid tar samples was done using ultimate analysis machine, while the relative concentration of the different compounds in the liquid tar was determined making use of a liquid gas chromatography (GC) unit. Average tar concentration of 4.928?g/Nm3 and 1.923?g/Nm3 was obtained for raw gas and cleaned gas samples, respectively. Tar concentration in the raw gas sample was found to be higher compared to results for other biomass materials, which could be attributed to the higher volatile matter percentage of OPF. Average cleaning efficiency of 61% which is comparable to that of sand bed filter and venturi scrubber cleaning systems reported in the literature was obtained for the cleaning system proposed in the current study. PMID:24526899

  13. Anaerobic digestion and gasification coupling for wastewater sludge treatment and recovery.

    PubMed

    Lacroix, Nicolas; Rousse, Daniel R; Hausler, Robert

    2014-06-27

    Sewage sludge management is an energy intensive process. Anaerobic digestion contributes to energy efficiency improvement but is limited by the biological process. A review has been conducted prior to experimentation in order to evaluate the mass and energy balances on anaerobic digestion followed by gasification of digested sludge. The purpose was to improve energy recovery and reuse. Calculations were based on design parameters and tests that are conducted with the anaerobic digester of a local wastewater treatment plant and a small commercial gasification system. Results showed a very significant potential of energy recovery. More than 90% of the energy content from sludge was extracted. Also, approximately the same amount of energy would be transferred in both directions between the digester (biogas) and the gasifier (thermal energy). This extraction resulted in the same use of biogas as the reference scenario but final product was a totally dry biochar, which represented a fraction of the initial mass. Phosphorus was concentrated and significantly preserved. This analysis suggests that anaerobic digestion followed by dehydration, drying and gasification could be a promising and viable option for energy and nutrient recovery from municipal sludge in replacement of conventional paths. PMID:24972600

  14. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect

    Not Available

    1992-05-01

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.

  15. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect

    Not Available

    1992-05-01

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., ``Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.

  16. Advanced gasification-based biomass power generation

    SciTech Connect

    Williams, R.H.; Larson, E.D.

    1993-12-31

    A promising strategy for modernizing bioenergy is the production of electricity or the cogeneration of electricity and heat using gasified biomass with advanced conversion technologies. Major advances that have been made in coal gasification technology, to marry the gas turbine to coal, are readily adaptable to biomass applications. Integrating biomass gasifiers with aeroderivative gas turbines in particular makes it possible to achieve high efficiencies and low unit capital costs at the modest scales required for bioenergy systems. Electricity produced with biomass-integrated gasifier/gas turbine (BIG/GT) power systems not only offers major environmental benefits but also would be competitive with electricity produced from fossil fuels and nuclear energy under a wide range of circumstances. Initial applications will be with biomass residues generated in the sugarcane, pulp and paper, and other agro- and forest-product industries. Eventually, biomass grown for energy purposes on dedicated energy farms will also be used to fuel these gas turbine systems. Continuing improvements in jet engine and biomass gasification technologies will lead to further gains in the performance of BIG/GT systems over the next couple of decades. Fuel cells operated on gasified biomass offer the promise of even higher performance levels in the period beyond the turn of the century. 79 refs., 21 figs., 11 tabs.

  17. In Situ Causticizing for Black Liquor Gasification

    SciTech Connect

    Scott Alan Sinquefield

    2005-10-01

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  18. Steam gasification of carbon: Catalyst properties

    SciTech Connect

    Falconer, J.L.; Lauderback, L.L.

    1990-09-15

    The objectives of this research are to determine the catalyst composition and concentration for metal oxide (potassium and calcium oxides) catalyzed gasification of carbon. The scope of this research involves determining: the concentration of active catalytic sites (and thus the dispersion), at reaction conditions, as a function of temperature, carbon burnoff, catalyst loading, and catalyst type; the location of catalyst, on the surface, on an atomic scale; catalyst composition; the site-specific rate constant for steam gasification; insight into the reaction mechanism; and how to maximize catalyst dispersion. Isotope tracing will measure the concentration of active catalyst sites, their specific rate constant, and the dependence of sites on initial catalyst loading, carbon conversion (burnoff), and temperature. Transient isotope tracing, secondary ion mass spectrometry (SIMS), and scanning tunneling microscopy (STM), will be used to obtain a complete picture of the catalysts at reaction conditions. Carbon black, coal chars, and graphite will be used in the transient tracing experiment. In the SIMS and STM experiments, graphite and carbon deposited on a metal surface will be models of coal char.

  19. Wabash River coal gasification repowering project: Public design report

    SciTech Connect

    1995-07-01

    The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

  20. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect

    Samuel S. Tam

    2002-05-01

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a multiple train coal-fueled IGCC powerplant, also based on the Subtaks 1.3 cases. The Subtask 1.6 four gasification train plant has a thermal efficiency of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency of 45.4% (HHV) and a plant cost of 1,096 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to coproduce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. As gasification technology matures, SCOHS and other improvements identified in this study will lead to further cost reductions and efficiency improvements.