Sample records for total annual emissions

  1. Emissions of methane in Europe inferred by total column measurements

    NASA Astrophysics Data System (ADS)

    Wunch, D.; Deutscher, N. M.; Hase, F.; Notholt, J.; Sussmann, R.; Toon, G. C.; Warneke, T.

    2017-12-01

    Atmospheric total column measurements have been used to infer emissions of methane in urban centres around the world. These measurements have been shown to be useful for verifying city-scale bottom-up inventories, and they can provide both timely and sub-annual emission information. We will present our analysis of atmospheric total column measurements of methane and carbon monoxide to infer annual and seasonal regional emissions of methane within Europe using five long-running atmospheric observatories. These observatories are part of the Total Carbon Column Observing Network, part of a global network that has been carefully designed to measure these gases on a consistent scale. Our inferred emissions will then be used to evaluate gridded emissions inventories in the region.

  2. New methodology for modeling annual-aircraft emissions at airports

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Woodmansey, B.G.; Patterson, J.G.

    An as-accurate-as-possible estimation of total-aircraft emissions are an essential component of any environmental-impact assessment done for proposed expansions at major airports. To determine the amount of emissions generated by aircraft using present models it is necessary to know the emission characteristics of all engines that are on all planes using the airport. However, the published data base does not cover all engine types and, therefore, a new methodology is needed to assist in estimating annual emissions from aircraft at airports. Linear regression equations relating quantity of emissions to aircraft weight using a known-fleet mix are developed in this paper. Total-annualmore » emissions for CO, NO[sub x], NMHC, SO[sub x], CO[sub 2], and N[sub 2]O are tabulated for Toronto's international airport for 1990. The regression equations are statistically significant for all emissions except for NMHC from large jets and NO[sub x] and NMHC for piston-engine aircraft. This regression model is a relatively simple, fast, and inexpensive method of obtaining an annual-emission inventory for an airport.« less

  3. Nongrowing season methane emissions-a significant component of annual emissions across northern ecosystems.

    PubMed

    Treat, Claire C; Bloom, A Anthony; Marushchak, Maija E

    2018-03-22

    Wetlands are the single largest natural source of atmospheric methane (CH 4 ), a greenhouse gas, and occur extensively in the northern hemisphere. Large discrepancies remain between "bottom-up" and "top-down" estimates of northern CH 4 emissions. To explore whether these discrepancies are due to poor representation of nongrowing season CH 4 emissions, we synthesized nongrowing season and annual CH 4 flux measurements from temperate, boreal, and tundra wetlands and uplands. Median nongrowing season wetland emissions ranged from 0.9 g/m 2 in bogs to 5.2 g/m 2 in marshes and were dependent on moisture, vegetation, and permafrost. Annual wetland emissions ranged from 0.9 g m -2  year -1 in tundra bogs to 78 g m -2  year -1 in temperate marshes. Uplands varied from CH 4 sinks to CH 4 sources with a median annual flux of 0.0 ± 0.2 g m -2  year -1 . The measured fraction of annual CH 4 emissions during the nongrowing season (observed: 13% to 47%) was significantly larger than that was predicted by two process-based model ensembles, especially between 40° and 60°N (modeled: 4% to 17%). Constraining the model ensembles with the measured nongrowing fraction increased total nongrowing season and annual CH 4 emissions. Using this constraint, the modeled nongrowing season wetland CH 4 flux from >40° north was 6.1 ± 1.5 Tg/year, three times greater than the nongrowing season emissions of the unconstrained model ensemble. The annual wetland CH 4 flux was 37 ± 7 Tg/year from the data-constrained model ensemble, 25% larger than the unconstrained ensemble. Considering nongrowing season processes is critical for accurately estimating CH 4 emissions from high-latitude ecosystems, and necessary for constraining the role of wetland emissions in a warming climate. © 2018 John Wiley & Sons Ltd.

  4. Seasonal and inter-annual variation in ecosystem scale methane emission from a boreal fen

    NASA Astrophysics Data System (ADS)

    Rinne, Janne; Li, Xuefei; Raivonen, Maarit; Peltola, Olli; Sallantaus, Tapani; Haapanala, Sami; Smolander, Sampo; Alekseychik, Pavel; Aurela, Mika; Korrensalo, Aino; Mammarella, Ivan; Tuittila, Eeva-Stiina; Vesala, Timo

    2016-04-01

    Northern wetlands are one of the major sources of atmospheric methane. We have measured ecosystem scale methane emissions from a boreal fen continuously since 2005. The site is an oligotrophic fen in boreal vegetation zone situated in Siikaneva wetland complex in Southern Finland. The mean annual temperature in the area is 3.3°C and total annual precipitation 710 mm. We have conducted the methane emission measurements by the eddy covariance method. Additionally we have measured fluxes of carbon dioxide, water vapor, and sensible heat together with a suite of other environmental parameters. We have analyzed this data alongside with a model run with University of Helsinki methane model. The measured fluxes show generally highest methane emission in late summers coinciding with the highest temperatures in saturated peat zone. During winters the fluxes show small but detectable emission despite the snow and ice cover on the fen. More than 90% of the annual methane emission occurs in snow-free period. The methane emission and peat temperature are connected in exponential manner in seasonal scales, but methane emission does not show the expected behavior with water table. The lack of water table position dependence also contrasts with the spatial variation across microtopography. There is no systematic variation in sub-diurnal time scale. The general seasonal cycle in methane emission is captured well with the methane model. We will show how well the model reproduces the temperature and water table position dependencies observed. The annual methane emission is typically around 10 gC m-2. This is a significant part of the total carbon exchange between the fen and the atmosphere and about twice the estimated carbon loss by leaching from the fen area. The inter-annual variability in the methane emission is modest. The June-September methane emissions from different years, comprising most of the annual emission, correlates positively with peat temperature, but not with

  5. 76 FR 71559 - Acid Rain Program: Notice of Annual Adjustment Factors for Excess Emissions Penalty

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-11-18

    ... ENVIRONMENTAL PROTECTION AGENCY [FRL-9494-6] Acid Rain Program: Notice of Annual Adjustment... annual adjustment factors for excess emissions penalty. SUMMARY: The Acid Rain Program under title IV of... emissions for sources that do not meet their annual Acid Rain emissions limitations. This notice states the...

  6. 78 FR 64496 - Acid Rain Program: Notice of Annual Adjustment Factors for Excess Emissions Penalty

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-29

    ... ENVIRONMENTAL PROTECTION AGENCY [FRL-9902-14-OAR] Acid Rain Program: Notice of Annual Adjustment... annual adjustment factors for excess emissions penalty. SUMMARY: The Acid Rain Program under title IV of... emissions for sources that do not meet their annual Acid Rain emissions limitations. This notice states the...

  7. Annual Fossil-Fuel CO2 Emissions: Isomass of Emissions Gridded by One Degree Latitude by One Degree Longitude (1751 - 2009) (V. 2012)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, Thomas A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marlad, Greg [Appalachian State University, Boone, NC (USA)

    2012-01-01

    The annual, isotopic (δ 13C) fossil-fuel CO2 emissions estimates from 1751-2009 provided in this database are derived from time series of global, regional, and national fossil-fuel CO2 emissions (Boden et al. 2012) and references therein. The data accessible here take these tabular, national, mass-emissions data, multiply them by stable carbon isotopic signatures (δ 13C) as described in Andres et al. (2000), and distribute them spatially on a one degree latitude by one degree longitude grid. The within-country spatial distribution is achieved through a fixed population distribution as reported in Andres et al. (1996). Note that the mass-emissions data used here are based on fossil-fuel consumption estimates as these are more representative of within country emissions than fossil-fuel production estimates (see http://cdiac.ess-dive.lbl.gov/faq.html#Q10 for a description why emission totals based upon consumption differ from those based upon production).

  8. Methane emission from high-latitude (>50N) lakes: Annual cycle of climatological emissions using satellite-derived lake-ice phenology and freeze-thaw dynamics

    NASA Astrophysics Data System (ADS)

    Matthews, E.; Romanski, J.; Du, J.; Watts, J. D.

    2017-12-01

    Lakes are increasingly recognized as potentially important contributors to global methane emissions despite occupying only a few percent of Earth's ice-free land surface. More than 40% of the global lake area lies in regions of amplified warming north of 50˚N. As with wetlands, lake emissions are sensitive to interannual fluctuations in, e.g., temperature and duration of thaw season. Several estimates of CH4emission from high-latitude lakes have been published but none relies on geospatial lake distributions and satellite-based duration and timing of thaw seasons. We report on a climatology of weekly, spatially-explicit methane emissions from high-latitude lakes. Lake break-up and freeze-up dates for lakes >50km^2 were determined from a lake-ice phenology data set derived from brightness temperature (Tb) observations of space-borne Advanced Microwave Scanning Radiometer (AMSR-E/2) sensors. The lake-ice conditions for smaller lakes were estimated using an Earth System Data Record for Land Surface Freeze-Thaw State derived from Tb observations of Scanning Multichannel Microwave Radiometer (SMMR), Special Sensor Microwave Imager (SSM/I), and SSM/I Sounder (SSMIS). Climatologies encompass 2002-2015 for lake ice phenology and 1979 to 2010 for the land surface freeze-thaw state. Climatologies encompass 2003-2014 for ice phenology and 1979 to 2010 for freeze-thaw dynamics. Length and timing of typical methane-emission periods, derived from the satellite data, were integrated with daily diffusive and ebulliative methane fluxes for lake types following the work of Wik et al. (Nature, 2016) to estimate a full annual cycle of emissions from lakes >50˚N. We explored several approaches to estimate the large bursts of emissions observed over short periods during lake-ice breakup immediately prior to full lake thaw since several studies suggest that a substantial fraction of total annual emissions may occur at this time. While highly uncertain, we plan to investigate whether

  9. Revised methane emissions factors and spatially distributed annual carbon fluxes for global livestock.

    PubMed

    Wolf, Julie; Asrar, Ghassem R; West, Tristram O

    2017-09-29

    Livestock play an important role in carbon cycling through consumption of biomass and emissions of methane. Recent research suggests that existing bottom-up inventories of livestock methane emissions in the US, such as those made using 2006 IPCC Tier 1 livestock emissions factors, are too low. This may be due to outdated information used to develop these emissions factors. In this study, we update information for cattle and swine by region, based on reported recent changes in animal body mass, feed quality and quantity, milk productivity, and management of animals and manure. We then use this updated information to calculate new livestock methane emissions factors for enteric fermentation in cattle, and for manure management in cattle and swine. Using the new emissions factors, we estimate global livestock emissions of 119.1 ± 18.2 Tg methane in 2011; this quantity is 11% greater than that obtained using the IPCC 2006 emissions factors, encompassing an 8.4% increase in enteric fermentation methane, a 36.7% increase in manure management methane, and notable variability among regions and sources. For example, revised manure management methane emissions for 2011 in the US increased by 71.8%. For years through 2013, we present (a) annual livestock methane emissions, (b) complete annual livestock carbon budgets, including carbon dioxide emissions, and (c) spatial distributions of livestock methane and other carbon fluxes, downscaled to 0.05 × 0.05 degree resolution. Our revised bottom-up estimates of global livestock methane emissions are comparable to recently reported top-down global estimates for recent years, and account for a significant part of the increase in annual methane emissions since 2007. Our results suggest that livestock methane emissions, while not the dominant overall source of global methane emissions, may be a major contributor to the observed annual emissions increases over the 2000s to 2010s. Differences at regional and local scales may help

  10. Annual Carbon Emissions from Deforestation in the Amazon Basin between 2000 and 2010.

    PubMed

    Song, Xiao-Peng; Huang, Chengquan; Saatchi, Sassan S; Hansen, Matthew C; Townshend, John R

    2015-01-01

    Reducing emissions from deforestation and forest degradation (REDD+) is considered one of the most cost-effective strategies for mitigating climate change. However, historical deforestation and emission rates-critical inputs for setting reference emission levels for REDD+-are poorly understood. Here we use multi-source, time-series satellite data to quantify carbon emissions from deforestation in the Amazon basin on a year-to-year basis between 2000 and 2010. We first derive annual deforestation indicators by using the Moderate Resolution Imaging Spectroradiometer Vegetation Continuous Fields (MODIS VCF) product. MODIS indicators are calibrated by using a large sample of Landsat data to generate accurate deforestation rates, which are subsequently combined with a spatially explicit biomass dataset to calculate committed annual carbon emissions. Across the study area, the average deforestation and associated carbon emissions were estimated to be 1.59 ± 0.25 M ha•yr(-1) and 0.18 ± 0.07 Pg C•yr(-1) respectively, with substantially different trends and inter-annual variability in different regions. Deforestation in the Brazilian Amazon increased between 2001 and 2004 and declined substantially afterwards, whereas deforestation in the Bolivian Amazon, the Colombian Amazon, and the Peruvian Amazon increased over the study period. The average carbon density of lost forests after 2005 was 130 Mg C•ha(-1), ~11% lower than the average carbon density of remaining forests in year 2010 (144 Mg C•ha(-1)). Moreover, the average carbon density of cleared forests increased at a rate of 7 Mg C•ha(-1)•yr(-1) from 2005 to 2010, suggesting that deforestation has been progressively encroaching into high-biomass lands in the Amazon basin. Spatially explicit, annual deforestation and emission estimates like the ones derived in this study are useful for setting baselines for REDD+ and other emission mitigation programs, and for evaluating the performance of such efforts.

  11. Annual Carbon Emissions from Deforestation in the Amazon Basin between 2000 and 2010

    PubMed Central

    Song, Xiao-Peng; Huang, Chengquan; Saatchi, Sassan S.; Hansen, Matthew C.; Townshend, John R.

    2015-01-01

    Reducing emissions from deforestation and forest degradation (REDD+) is considered one of the most cost-effective strategies for mitigating climate change. However, historical deforestation and emission rates―critical inputs for setting reference emission levels for REDD+―are poorly understood. Here we use multi-source, time-series satellite data to quantify carbon emissions from deforestation in the Amazon basin on a year-to-year basis between 2000 and 2010. We first derive annual deforestation indicators by using the Moderate Resolution Imaging Spectroradiometer Vegetation Continuous Fields (MODIS VCF) product. MODIS indicators are calibrated by using a large sample of Landsat data to generate accurate deforestation rates, which are subsequently combined with a spatially explicit biomass dataset to calculate committed annual carbon emissions. Across the study area, the average deforestation and associated carbon emissions were estimated to be 1.59 ± 0.25 M ha•yr−1 and 0.18 ± 0.07 Pg C•yr−1 respectively, with substantially different trends and inter-annual variability in different regions. Deforestation in the Brazilian Amazon increased between 2001 and 2004 and declined substantially afterwards, whereas deforestation in the Bolivian Amazon, the Colombian Amazon, and the Peruvian Amazon increased over the study period. The average carbon density of lost forests after 2005 was 130 Mg C•ha−1, ~11% lower than the average carbon density of remaining forests in year 2010 (144 Mg C•ha−1). Moreover, the average carbon density of cleared forests increased at a rate of 7 Mg C•ha−1•yr−1 from 2005 to 2010, suggesting that deforestation has been progressively encroaching into high-biomass lands in the Amazon basin. Spatially explicit, annual deforestation and emission estimates like the ones derived in this study are useful for setting baselines for REDD+ and other emission mitigation programs, and for evaluating the performance of such efforts

  12. Inter-annual variability in fossil-fuel CO2 emissions due to temperature anomalies

    NASA Astrophysics Data System (ADS)

    Bréon, F.-M.; Boucher, O.; Brender, P.

    2017-07-01

    It is well known that short-term (i.e. interannual) variations in fossil-fuel CO2 emissions are closely related to the evolution of the national economies. Nevertheless, a fraction of the CO2 emissions are linked to domestic and business heating and cooling, which can be expected to be related to the meteorology, independently of the economy. Here, we analyse whether the signature of the inter-annual temperature anomalies is discernible in the time series of CO2 emissions at the country scale. Our analysis shows that, for many countries, there is a clear positive correlation between a heating-degree-person index and the component of the CO2 emissions that is not explained by the economy as quantified by the gross domestic product (GDP). Similarly, several countries show a positive correlation between a cooling-degree-person (CDP) index and CO2 emissions. The slope of the linear relationship for heating is on the order of 0.5-1 kg CO2 (degree-day-person)-1 but with significant country-to-country variations. A similar relationship for cooling shows even greater diversity. We further show that the inter-annual climate anomalies have a small but significant impact on the annual growth rate of CO2 emissions, both at the national and global scale. Such a meteorological effect was a significant contribution to the rather small and unexpected global emission growth rate in 2014 while its contribution to the near zero emission growth in 2015 was insignificant.

  13. Modeling global annual N2O and NO emissions from fertilized fields

    NASA Astrophysics Data System (ADS)

    Bouwman, A. F.; Boumans, L. J. M.; Batjes, N. H.

    2002-12-01

    Information from 846 N2O emission measurements in agricultural fields and 99 measurements for NO emissions was used to describe the influence of various factors regulating emissions from mineral soils in models for calculating global N2O and NO emissions. Only those factors having a significant influence on N2O and NO emissions were included in the models. For N2O these were (1) environmental factors (climate, soil organic C content, soil texture, drainage and soil pH); (2) management-related factors (N application rate per fertilizer type, type of crop, with major differences between grass, legumes and other annual crops); and (3) factors related to the measurements (length of measurement period and frequency of measurements). The most important controls on NO emission include the N application rate per fertilizer type, soil organic-C content and soil drainage. Calculated global annual N2O-N and NO-N emissions from fertilized agricultural fields amount to 2.8 and 1.6 Mtonne, respectively. The global mean fertilizer-induced emissions for N2O and NO amount to 0.9% and 0.7%, respectively, of the N applied. These overall results account for the spatial variability of the main N2O and NO emission controls on the landscape scale.

  14. CH4 and N2O Emissions from Rice Paddy Soils in Vietnam - Identifying Regional Hotspots and Quantifying the Total Emission Strength using a Biogeochemical Model

    NASA Astrophysics Data System (ADS)

    Werner, C.; Kraus, D.; Mai, T. V.; Butterbach-Bahl, K.

    2016-12-01

    Agriculture is the economic backbone for over two thirds of Vietnam's population, providing food security, employment and income. However, agriculture in Vietnam is challenged by climate change and climate extremes and at the same time, agriculture remains a key source of greenhouse gas (GHG) emissions. The first bi-annual update report (BUR1), published in 2014 indicated that while the proportion of GHG emissions from agriculture had fallen from 43.1% to 33.2% from 2000 to 2010, the emission total increased from 65.1 mio to 88.4 mio t CO2e. Reducing GHG emissions from agriculture has thus become a key issue within the national strategy of GHG emission management. Here we present first data using IPCC Tier 3 modeling for quantifying the source strength of rice based crop systems for CH4 and N2O. We used LandscapeDNDC and linked it to a newly developed spatial landuse and land management database (climate, soil properties, and detailed field management data). Site application showed good agreement of simulated biomass, yield and GHG emissions with field observations, providing confidence for model use at national scale. Our results also show good agreement with national yield data and total annual emissions of the simulated period (2006-2015) ranged from 1060 - 1502 kt CH4 and 6.2 - 7.7 kt N2O, respectively. The dominating emission hotspot for CH4 is the Mekong Delta region with its double and triple rice cropping systems (819 kt CH4/yr, Fig. 1). With regard to N2O, emission hotspots have been identified to be closely related to regions with high fertilizer use and single to double rice cropping systems (Fig. 1). Though, our emission estimates are likely representing the best of current knowledge on national GHG emissions from rice based systems in Vietnam, the uncertainty is significant as information on rice system management remains vague. Sensitivity studies show that changes in field management affecting the soil organic carbon dynamics (duration of flooding

  15. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2010)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Appalachian State University, Boone, NC (USA)

    2010-01-01

    The 2010 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2007. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2007 were published earlier (Boden et al. 2010). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  16. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2013)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Appalachian State University, Boone, NC (USA)

    2013-01-01

    The 2013 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2010. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2010 were published earlier (Boden et al. 2013). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  17. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2015)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Appalachian State University, Boone, NC (USA)

    2015-01-01

    The 2015 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2011. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2011 were published earlier (Boden et al. 2015). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  18. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2011)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA)

    2011-01-01

    The 2011 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2008. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2008 were published earlier (Boden et al. 2011). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  19. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2012)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Appalachian State University, Boone, NC (USA)

    2012-01-01

    The 2012 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2009. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2009 were published earlier (Boden et al. 2012). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  20. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2016)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA)

    2016-01-01

    The 2016 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2013. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2013 were published earlier (Boden et al. 2016). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  1. 10 CFR 300.7 - Net emission reductions.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... DEPARTMENT OF ENERGY CLIMATE CHANGE VOLUNTARY GREENHOUSE GAS REPORTING PROGRAM: GENERAL GUIDELINES § 300.7... practicable, on a full assessment and sum total of all changes in an entity's emissions, eligible avoided... include the annual changes in the total emissions of the entity, including the total emissions of each of...

  2. 10 CFR 300.7 - Net emission reductions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... DEPARTMENT OF ENERGY CLIMATE CHANGE VOLUNTARY GREENHOUSE GAS REPORTING PROGRAM: GENERAL GUIDELINES § 300.7... practicable, on a full assessment and sum total of all changes in an entity's emissions, eligible avoided... include the annual changes in the total emissions of the entity, including the total emissions of each of...

  3. 10 CFR 300.7 - Net emission reductions.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... DEPARTMENT OF ENERGY CLIMATE CHANGE VOLUNTARY GREENHOUSE GAS REPORTING PROGRAM: GENERAL GUIDELINES § 300.7... practicable, on a full assessment and sum total of all changes in an entity's emissions, eligible avoided... include the annual changes in the total emissions of the entity, including the total emissions of each of...

  4. 10 CFR 300.7 - Net emission reductions.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... DEPARTMENT OF ENERGY CLIMATE CHANGE VOLUNTARY GREENHOUSE GAS REPORTING PROGRAM: GENERAL GUIDELINES § 300.7... practicable, on a full assessment and sum total of all changes in an entity's emissions, eligible avoided... include the annual changes in the total emissions of the entity, including the total emissions of each of...

  5. 10 CFR 300.7 - Net emission reductions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... DEPARTMENT OF ENERGY CLIMATE CHANGE VOLUNTARY GREENHOUSE GAS REPORTING PROGRAM: GENERAL GUIDELINES § 300.7... practicable, on a full assessment and sum total of all changes in an entity's emissions, eligible avoided... include the annual changes in the total emissions of the entity, including the total emissions of each of...

  6. Annual N2O emissions from conventionally grazed typical alpine grass meadows in the eastern Qinghai-Tibetan Plateau.

    PubMed

    Zhang, Han; Yao, Zhisheng; Wang, Kai; Zheng, Xunhua; Ma, Lei; Wang, Rui; Liu, Chunyan; Zhang, Wei; Zhu, Bo; Tang, Xiangyu; Hu, Zhenghua; Han, Shenghui

    2018-06-01

    Annual nitrous oxide (N 2 O) emissions from high-altitude alpine meadow grasslands have not been effectively characterized because of the scarcity of whole-year measurements. The authors performed a year-round measurement of N 2 O fluxes from three conventionally grazed alpine meadows that represent the typical meadow landscape in the eastern Qinghai-Tibetan Plateau (QTP). The results showed that annual N 2 O emissions averaged 0.123±0.053 (2SD, i.e., the double standard deviation indicating the 95% confidence interval) kgNha -1 yr -1 across the three meadow sites. N 2 O flux pulses during the spring freezing-thawing period (FTP) were observed at only one site, indicating a large spatial variability in association with soil moisture differences. Approximately 34-57% (mean: 46%) of the annual N 2 O emissions occurred in the non-growing season, highlighting the substantial importance of accurate flux observations during this period. The simultaneous observations showed conservative, marginal nitric oxide (NO) fluxes of 0.058±0.032 (2SD) kgNha -1 yr -1 . The N 2 O fluxes across the three field sites correlated negatively with the soil nitrate concentrations during the entire year-round period (P<0.05). Furthermore, a significant joint regulatory effect of topsoil temperature and moisture on the N 2 O and NO fluxes was observed during the relatively warm periods. Based on the results of the present and previous studies, a simple extrapolation roughly estimated the annual total N 2 O emission from Chinese grasslands to be 73±15 (2SD) GgNyr -1 (1Gg=10 9 g). A linear dependence of the annual N 2 O fluxes on the aboveground net primary productivity (ANPP) was also found. This result may provide a simple approach for estimating the N 2 O emission inventories of frigid alpine or temperate grasslands that are ungrazed either in the summer or year round. However, further confirmation of this relationship with a wider ANPP range is still needed in the future studies

  7. Evaluating the effects of China's pollution control on inter-annual trends and uncertainties of atmospheric mercury emissions

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Zhong, H.; Zhang, J.; Nielsen, C. P.

    2014-10-01

    China's atmospheric mercury (Hg) emissions of anthropogenic origin have been effectively restrained through the national policy of air pollution control. Improved methods based on available field measurements are developed to quantify the benefits of Hg abatement through various emission control measures. Those measures include increased use of flue gas desulfurization (FGD) and selective catalyst reduction (SCR) systems for power sector, precalciners with fabric filter (FF) for cement production, machinery coking with electrostatic precipitator (ESP) for iron and steel production, and advanced manufacturing technologies for nonferrous metal smelting. Declining trends in emissions factors for those sources are revealed, leading to a much slower growth of national total Hg emissions than that of energy and economy, from 679 in 2005 to 750 metric tons (t) in 2012. In particular, nearly half of emissions from the above-mentioned four types of sources are expected to be reduced in 2012, attributed to expansion of technologies with high energy efficiencies and air pollutant removal rates after 2005. The speciation of Hg emissions keeps stable for recent years, with the mass fractions of around 55, 39 and 6% for Hg0, Hg2+ and Hgp, respectively. The lower estimate of Hg emissions than previous inventories is supported by limited chemistry simulation work, but middle-to-long term observation on ambient Hg levels is further needed to justify the inter-annual trends of estimated Hg emissions. With improved implementation of emission controls and energy saving, 23% reduction in annual Hg emissions for the most optimistic case in 2030 is expected compared to 2012, with total emissions below 600 t. While Hg emissions are evaluated to be gradually constrained, increased uncertainties are quantified with Monte-Carlo simulation for recent years, particularly for power and certain industrial sources. The uncertainty of Hg emissions from coal-fired power plants, as an example

  8. EVALUATION OF TOTAL ORGANIC EMISSIONS ANALYSIS METHODS

    EPA Science Inventory

    The rationale and supporting experimental data for revising EPA's 1996 "Guidance for Total Organics" are summarized in this document. It reports the results of reseach and investigation of improvements to the Total Organic Emissions (TOE) guidance used by EPA to measure recovera...

  9. Anthropogenic Chromium Emissions in China from 1990 to 2009

    PubMed Central

    Cheng, Hongguang; Zhou, Tan; Li, Qian; Lu, Lu; Lin, Chunye

    2014-01-01

    An inventory of chromium emission into the atmosphere and water from anthropogenic activities in China was compiled for 1990 through to 2009. We estimate that the total emission of chromium to the atmosphere is about 1.92×105t. Coal and oil combustion were the two leading sources of chromium emission to the atmosphere in China, while the contribution of them showed opposite annual growth trend. In total, nearly 1.34×104t of chromium was discharged to water, mainly from six industrial categories in 20 years. Among them, the metal fabrication industry and the leather tanning sector were the dominant sources of chromium emissions, accounting for approximately 68.0% and 20.0% of the total emissions and representing increases of15.6% and 10.3% annually, respectively. The spatial trends of Cr emissions show significant variation based on emissions from 2005 to 2009. The emission to the atmosphere was heaviest in Hebei, Shandong, Guangdong, Zhejiang and Shanxi, whose annual emissions reached more than 1000t for the high level of coal and oil consumption. In terms of emission to water, the largest contributors were Guangdong, Jiangsu, Shandong and Zhejiang, where most of the leather production and metal manufacturing occur and these four regions accounted for nearly 47.4% of the total emission to water. PMID:24505309

  10. 16 CFR 801.11 - Annual net sales and total assets.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 16 Commercial Practices 1 2010-01-01 2010-01-01 false Annual net sales and total assets. 801.11 Section 801.11 Commercial Practices FEDERAL TRADE COMMISSION RULES, REGULATIONS, STATEMENTS AND... person; and (2) The total assets of a person shall be as stated on the last regularly prepared balance...

  11. Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (1751-2006) (NDP-058.2009)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA)

    2009-01-01

    The 2009 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2006. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2006 were published earlier (Boden et al. 2009). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

  12. Further Evaluation of an Emperical Equation for Annual Total Evaporation

    NASA Technical Reports Server (NTRS)

    Choudhury, Bhaskar J.

    1999-01-01

    An empirical equation for annual total evaporation based on annual precipitation and net radiation was found to provide evaporation within 10% of the observed values at seven locations within temperate and tropical regions, but it overestimated evaporation by 90% at one location within the tundra region. A synthesis of observations at two other locations within the tundra region gives overestimates of about 65%. A general analysis of observed precipitation, net radiation, and runoff within the tundra region shows that the empirical equation is generally biased to overestimate annual evaporation within the tundra region. A theoretical analysis is being done to understand the reason behind this bias.

  13. Toward an annual estimate of methane emissions from Lake Erie

    NASA Astrophysics Data System (ADS)

    Fernandez, J.; Townsend-Small, A.

    2017-12-01

    Lake Erie is the shallowest, warmest, and most eutrophic of all of the North American Great Lakes. The central basin of Lake Erie exhibits seasonally hypoxic bottom waters, which contributes to biological methane (CH4) production. Leaks from extensive natural gas wells and pipelines in Canadian waters are a potential source of thermogenic CH4 to the lake. The shallow western basin lacks water column hypoxia, but experiences increasingly frequent algal blooms and hypoxic sediments. Our past research, focused on the central basin, indicated that Lake Erie is a positive source of CH4 during late summer (August - September), emitting 1.3 ± 0.6 × 105 kg CH4-C day. Here, we present a seasonal dataset of CH4 fluxes measured throughout a 16-month period starting in the spring of 2015 and ending late summer in 2016 to estimate an annual lake wide CH4 emission. Our results indicate that the western basin experienced the greatest CH4 emissions, and the highest rates of CH4 flux co-occur with the highest rates of nutrient loading and largest algal blooms near the mouth of the Maumee River. Winter CH4 fluxes were minimal and similar throughout the lake, indicating that natural gas wells are a minimal source of CH4 emissions. Emissions were highest in August and tapered off through the fall and winter, rising again in spring. The estimated annual CH4 emission in Lake Erie was 4.41 × 107 kg CH4-C yr-1. We compared this to other CH4 sources in Michigan and Ohio in the USEPA Greenhouse Gas Reporting Program Database, and found that Lake Erie is second largest emitter of CH4 in Ohio (a landfill in Cincinnati is a larger source), and the largest in Michigan. Recent work has shown that eutrophication in lakes such as Lake Erie may be on the rise due to climate change induced increases in precipitation. If so, these large CH4 emissions may have positive feedback consequences to climate warming. Therefore, more research is needed to indicate whether or not these CH4 emissions are

  14. Daily, monthly, seasonal, and annual ammonia emissions from Southern High Plains cattle feedyards.

    PubMed

    Todd, Richard W; Cole, N Andy; Rhoades, Marty B; Parker, David B; Casey, Kenneth D

    2011-01-01

    Ammonia emitted from beef cattle feedyards adds excess reactive N to the environment, contributes to degraded air quality as a precursor to secondary particulate matter, and represents a significant loss of N from beef cattle feedyards. We used open path laser spectroscopy and an inverse dispersion model to quantify daily, monthly, seasonal, and annual NH emissions during 2 yr from two commercial cattle feedyards in the Panhandle High Plains of Texas. Annual patterns of NH fluxes correlated with air temperature, with the greatest fluxes (>100 kg ha d) during the summer and the lowest fluxes (<15 kg ha d) during the winter. Mean monthly per capita emission rate (PCER) of NH-N at one feedyard ranged from 31 g NH-N head d (January) to 207 g NH-N head d (October), when increased dietary crude protein from wet distillers grains elevated emissions. Ammonia N emissions at the other feedyard ranged from 36 g NH-N head d (January) to 121 g NH-N head d (September). Monthly fractional NH-N loss ranged from a low of 19 to 24% to a high of 80 to 85% of fed N at the two feedyards. Seasonal PCER at the two feedyards averaged 60 to 71 g NH-N head d during winter and 103 to 158 g NH-N head d during summer. Annually, PCER was 115 and 80 g NH-N head d at the two feedyards, which represented 59 and 52% of N fed to the cattle. Detailed studies are needed to determine the effect of management and environmental variables such as diet, temperature, precipitation, and manure water content on NH emissions. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  15. A regional mass balance model based on total ammoniacal nitrogen for estimating ammonia emissions from beef cattle in Alberta Canada

    NASA Astrophysics Data System (ADS)

    Chai, Lilong; Kröbel, Roland; Janzen, H. Henry; Beauchemin, Karen A.; McGinn, Sean M.; Bittman, Shabtai; Atia, Atta; Edeogu, Ike; MacDonald, Douglas; Dong, Ruilan

    2014-08-01

    Animal feeding operations are primary contributors of anthropogenic ammonia (NH3) emissions in North America and Europe. Mathematical modeling of NH3 volatilization from each stage of livestock manure management allows comprehensive quantitative estimates of emission sources and nutrient losses. A regionally-specific mass balance model based on total ammoniacal nitrogen (TAN) content in animal manure was developed for estimating NH3 emissions from beef farming operations in western Canada. Total N excretion in urine and feces was estimated from animal diet composition, feed dry matter intake and N utilization for beef cattle categories and production stages. Mineralization of organic N, immobilization of TAN, nitrification, and denitrification of N compounds in manure, were incorporated into the model to account for quantities of TAN at each stage of manure handling. Ammonia emission factors were specified for different animal housing (feedlots, barns), grazing, manure storage (including composting and stockpiling) and land spreading (tilled and untilled land), and were modified for temperature. The model computed NH3 emissions from all beef cattle sub-classes including cows, calves, breeding bulls, steers for slaughter, and heifers for slaughter and replacement. Estimated NH3 emissions were about 1.11 × 105 Mg NH3 in Alberta in 2006, with a mean of 18.5 kg animal-1 yr-1 (15.2 kg NH3-N animal-1 yr-1) which is 23.5% of the annual N intake of beef cattle (64.7 kg animal-1 yr-1). The percentage of N intake volatilized as NH3-N was 50% for steers and heifers for slaughter, and between 11 and 14% for all other categories. Steers and heifers for slaughter were the two largest contributors (3.5 × 104 and 3.9 × 104 Mg, respectively) at 31.5 and 32.7% of total NH3 emissions because most growing animals were finished in feedlots. Animal housing and grazing contributed roughly 63% of the total NH3 emissions (feedlots, barns and pastures contributed 54.4, 0.2 and 8.1% of

  16. Greenhouse gas emissions of drained fen peatlands in Belarus are controlled by water table, land use, and annual weather conditions

    NASA Astrophysics Data System (ADS)

    Burlo, Andrei; Minke, Merten; Chuvashova, Hanna; Augustin, Jürgen; Hoffmann, Mathias; Narkevitch, Ivan

    2014-05-01

    Drainage of peatlands causes strong emission of the greenhouse gases (GHG) CO2 and N2O, sometimes combined with a weak CH4 uptake. In Belarus drained peatlands occupy about 1505000 ha or more than 7.2 % of the country area. Joosten (2009) estimates CO2 emission from degraded peatlands in Belarus as 41.3 Mt yr-1 what equals to 47 % of total anthropogenic greenhouse gases (GHGs) emission of country in 2011. However, it could not be checked if these numbers are correct since there are no GHG measurements on these sites up to now. Therefore we studied the GHG emissions with the closed chamber approach in four peatlands situated in central and southern Belarus over a period from August 2010 to August 2012. The measurements comprised eight site types representing different water level conditions, and ranging from grassland and arable land over abandoned fields and peat cuts to near-natural sedge fens. Fluxes of CH4 and N2O were determined using the close-chamber approach every second week in snow free periods and every fourth week during winter time. The annual emissions were calculated based on linear interpolation. Carbon dioxide exchange was measured with transparent and opaque chambers every 3-4 weeks and the annual net ecosystem exchange (NEE) was modeled according to Drösler (2005). Most of the drained sites were sources of CO2 in both years. NEE increased with lower mean annual water table level. The highest NEE value (1263.5 g CO2-C m-1yr-1) was observed at the driest site of the study; an abandoned fen formerly used for agriculture. In contrast, a former peat extraction site with moist peat and small Pinus sylvestris tress were sinks of CO2 with uptake to 389.6 g CO2-C m-1yr-1. The highest N2O emissions were recorded at a drained agricultural fen with mean annual rates of up to 2347 mg N2O-N m-2 yr-1. Significant fluxes of CH4 (15 g CH4C m-2 h-1) were observed only at the near-natural site in the first year of investigation when precipitation and the mean water

  17. N2O emissions from a nitrogen-enriched river

    USGS Publications Warehouse

    McMahon, P.B.; Dennehy, K.F.

    1999-01-01

    Nitrous oxide (N2O) emissions from the South Platte River in Colorado were measured using closed chambers in the fall, winter, and summer of 1994- 1995. The South Platte River was enriched in inorganic N (9-800 ??M) derived from municipal wastewater effluent and groundwater return flows from irrigated agricultural fields. River water was as much as 2500% supersaturated with N2O, and median N2O emission rates from the river surface ranged from less than 90 to 32 600 ??g-N m-2 d-1. Seventy-nine percent of the variance in N2O emission rates was explained by concentrations of total inorganic N in river water and by water temperature. The estimated total annual N2O emissions from the South Platte River were 2 x 1013-6 x 1013 ??g-N yr-1. This amount of annual N2O emissions was similar to the estimated annual N2O emissions from all primary municipal wastewater treatment processes in the United States (1). Results from this study indicate that N-enriched rivers could be important anthropogenic sources of N2O to the atmosphere. However, N2O emission measurements from other N-enriched rivers are needed to better quantify this source.Nitrous oxide (N2O) emissions from the South Platte River in Colorado were measured using closed chambers in the fall, winter, and summer of 1994-1995. The South Platte River was enriched in inorganic N (9-800 ??M) derived from municipal wastewater effluent and groundwater return flows from irrigated agricultural fields. River water was as much as 2500% supersaturated with N2O, and median N2O emission rates from the river surface ranged from less than 90 to 32 600 ??g-N m-2 d-1. Seventy-nine percent of the variance in N2O emission rates was explained by concentrations of total inorganic N in river water and by water temperature. The estimated total annual N2O emissions from the South Platte River were 2??1013-6??1013 ??g-N yr-1. This amount of annual N2O emissions was similar to the estimated annual N2O emissions from all primary municipal

  18. 40 CFR 63.1431 - Process vent annual epoxides emission factor plan requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., recovery, or recapture device, along with the expected percent efficiency. (iii) Annual emissions after the... section, kg/yr. R = Expected control efficiency of the combustion, recovery, or recapture device, percent....1426(c) to determine the epoxide control efficiency of the combustion, recovery, or recapture device...

  19. 40 CFR 63.1431 - Process vent annual epoxides emission factor plan requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., recovery, or recapture device, along with the expected percent efficiency. (iii) Annual emissions after the... section, kg/yr. R = Expected control efficiency of the combustion, recovery, or recapture device, percent....1426(c) to determine the epoxide control efficiency of the combustion, recovery, or recapture device...

  20. Comparative study of radiometric and calorimetric methods for total hemispherical emissivity measurements

    NASA Astrophysics Data System (ADS)

    Monchau, Jean-Pierre; Hameury, Jacques; Ausset, Patrick; Hay, Bruno; Ibos, Laurent; Candau, Yves

    2018-05-01

    Accurate knowledge of infrared emissivity is important in applications such as surface temperature measurements by infrared thermography or thermal balance for building walls. A comparison of total hemispherical emissivity measurement was performed by two laboratories: the Laboratoire National de Métrologie et d'Essais (LNE) and the Centre d'Études et de Recherche en Thermique, Environnement et Systèmes (CERTES). Both laboratories performed emissivity measurements on four samples, chosen to cover a large range of emissivity values and angular reflectance behaviors. The samples were polished aluminum (highly specular, low emissivity), bulk PVC (slightly specular, high emissivity), sandblasted aluminum (diffuse surface, medium emissivity), and aluminum paint (slightly specular surface, medium emissivity). Results obtained using five measurement techniques were compared. LNE used a calorimetric method for direct total hemispherical emissivity measurement [1], an absolute reflectometric measurement method [2], and a relative reflectometric measurement method. CERTES used two total hemispherical directional reflectometric measurement methods [3, 4]. For indirect techniques by reflectance measurements, the total hemispherical emissivity values were calculated from directional hemispherical reflectance measurement results using spectral integration when required and directional to hemispherical extrapolation. Results were compared, taking into account measurement uncertainties; an added uncertainty was introduced to account for heterogeneity over the surfaces of the samples and between samples. All techniques gave large relative uncertainties for a low emissive and very specular material (polished aluminum), and results were quite scattered. All the indirect techniques by reflectance measurement gave results within ±0.01 for a high emissivity material. A commercial aluminum paint appears to be a good candidate for producing samples with medium level of emissivity

  1. Apparatus for Measuring Total Emissivity of Small, Low-Emissivity Samples

    NASA Technical Reports Server (NTRS)

    Tuttle, James; DiPirro, Michael J.

    2011-01-01

    An apparatus was developed for measuring total emissivity of small, lightweight, low-emissivity samples at low temperatures. The entire apparatus fits inside a small laboratory cryostat. Sample installation and removal are relatively quick, allowing for faster testing. The small chamber surrounding the sample is lined with black-painted aluminum honeycomb, which simplifies data analysis. This results in the sample viewing a very high-emissivity surface on all sides, an effect which would normally require a much larger chamber volume. The sample and chamber temperatures are individually controlled using off-the-shelf PID (proportional integral derivative) controllers, allowing flexibility in the test conditions. The chamber can be controlled at a higher temperature than the sample, allowing a direct absorptivity measurement. The lightweight sample is suspended by its heater and thermometer leads from an isothermal bar external to the chamber. The wires run out of the chamber through small holes in its corners, and the wires do not contact the chamber itself. During a steady-state measurement, the thermometer and bar are individually controlled at the same temperature, so there is zero heat flow through the wires. Thus, all of sample-temperature-control heater power is radiated to the chamber. Double-aluminized Kapton (DAK) emissivity was studied down to 10 K, which was about 25 K colder than any previously reported measurements. This verified a minimum in the emissivity at about 35 K and a rise as the temperature dropped to lower values.

  2. A synthesis of growing-season, non-growing season, and annual methane emission measurements among temperate, boreal, and tundra wetlands and uplands

    NASA Astrophysics Data System (ADS)

    Treat, C. C.; Bloom, A. A.; Marushchak, M. E.

    2017-12-01

    Wetlands are the largest natural source of methane to the atmosphere, while upland soils are a consistent sink of atmospheric methane. Wetland methane emissions are highly variable among sites, years, and temporal scales due to differences in production, oxidation, and transport pathways. Currently, process model predictions of methane emissions from wetlands remain challenging due to uncertain parameterizations of net methane production and emission processes. Here, we synthesize growing season, non-growing season, and annual methane emissions from chamber and eddy-covariance measurements for more than 150 sites in undisturbed temperate, boreal, and tundra wetlands and uplands. We compare the magnitude of fluxes among regions, wetland classifications, vegetation classifications, and environmental variables. Growing season measurements were most abundant in bogs, fens, and tundra sites, while marshes and swamps were relatively undersampled. Annual methane emissions were largest from marshes and lowest from upland mineral soils. Non-growing season emissions accounted for large fraction of annual methane emissions, especially in tundra sites. These results provide constraints for methane emissions from temporal, boreal, and arctic wetlands utilizing the numerous flux measurements conducted over the past 25 years. We find that state-of-the-art model ensembles are seasonally biased; in particular, the vast majority of models overestimate predictions of the growing season to annual wetland methane emission ratio across all biomes.

  3. Evaluating the effects of China's pollution controls on inter-annual trends and uncertainties of atmospheric mercury emissions

    NASA Astrophysics Data System (ADS)

    Zhao, Y.; Zhong, H.; Zhang, J.; Nielsen, C. P.

    2015-04-01

    China's anthropogenic emissions of atmospheric mercury (Hg) are effectively constrained by national air pollution control and energy efficiency policies. In this study, improved methods, based on available data from domestic field measurements, are developed to quantify the benefits of Hg abatement by various emission control measures. Those measures include increased use of (1) flue gas desulfurization (FGD) and selective catalyst reduction (SCR) systems in power generation; (2) precalciner kilns with fabric filters (FF) in cement production; (3) mechanized coking ovens with electrostatic precipitators (ESP) in iron and steel production; and (4) advanced production technologies in nonferrous metal smelting. Investigation reveals declining trends in emission factors for each of these sources, which together drive a much slower growth of total Hg emissions than the growth of China's energy consumption and economy, from 679 metric tons (t) in 2005 to 750 t in 2012. In particular, estimated emissions from the above-mentioned four source types declined 3% from 2005 to 2012, which can be attributed to expanded deployment of technologies with higher energy efficiencies and air pollutant removal rates. Emissions from other anthropogenic sources are estimated to increase by 22% during the period. The species shares of total Hg emissions have been stable in recent years, with mass fractions of around 55, 39, and 6% for gaseous elemental Hg (Hg0), reactive gaseous mercury (Hg2+), and particle-bound mercury (Hgp), respectively. The higher estimate of total Hg emissions than previous inventories is supported by limited simulation of atmospheric chemistry and transport. With improved implementation of emission controls and energy saving, a 23% reduction in annual Hg emissions from 2012 to 2030, to below 600 t, is expected at the most. While growth in Hg emissions has been gradually constrained, uncertainties quantified by Monte Carlo simulation for recent years have increased

  4. 30 CFR 250.218 - What air emissions information must accompany the EP?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the EP? 250.218 Section 250.218 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE... list: (i) The projected peak hourly emissions; (ii) The total annual emissions in tons per year; (iii... emissions; and (v) The total of all emissions listed in paragraphs (a)(1)(i) through (iv) of this section...

  5. Annual land cover change mapping using MODIS time series to improve emissions inventories.

    NASA Astrophysics Data System (ADS)

    López Saldaña, G.; Quaife, T. L.; Clifford, D.

    2014-12-01

    Understanding and quantifying land surface changes is necessary for estimating greenhouse gas and ammonia emissions, and for meeting air quality limits and targets. More sophisticated inventories methodologies for at least key emission source are needed due to policy-driven air quality directives. Quantifying land cover changes on an annual basis requires greater spatial and temporal disaggregation of input data. The main aim of this study is to develop a methodology for using Earth Observations (EO) to identify annual land surface changes that will improve emissions inventories from agriculture and land use/land use change and forestry (LULUCF) in the UK. First goal is to find the best sets of input features that describe accurately the surface dynamics. In order to identify annual and inter-annual land surface changes, a times series of surface reflectance was used to capture seasonal variability. Daily surface reflectance images from the Moderate Resolution Imaging Spectroradiometer (MODIS) at 500m resolution were used to invert a Bidirectional Reflectance Distribution Function (BRDF) model to create the seamless time series. Given the limited number of cloud-free observations, a BRDF climatology was used to constrain the model inversion and where no high-scientific quality observations were available at all, as a gap filler. The Land Cover Map 2007 (LC2007) produced by the Centre for Ecology & Hydrology (CEH) was used for training and testing purposes. A prototype land cover product was created for 2006 to 2008. Several machine learning classifiers were tested as well as different sets of input features going from the BRDF parameters to spectral Albedo. We will present the results of the time series development and the first exercises when creating the prototype land cover product.

  6. Foreword: Proceedings From the First Annual Lumbar Total Disc Replacement Summit.

    PubMed

    Blumenthal, Scott; Buttermann, Glenn; Garcia, Rolando; Gornet, Matthew; Grunch, Betsy; Guyer, Richard; Janssen, Michael; Kimball, Brent; Lewis, Adam; Mesiwala, Ali; Miller, Lynn; Morreale, Joseph; Reed, William; Sandhu, Faheem; Shackleford, Ian; Yue, James; Zigler, Jack; OConnell, Brent; Ferko, Nicole; Hollmann, Sarah

    2017-12-15

    : This publication focuses on proceedings from the First Annual Lumbar Total Disc Replacement Summit, held October 25, 2016 in Boston, MA. The Summit brought together 17 thought leading surgeons who employed a modified-Delphi method to determine where consensus existed pertaining to the utilization of lumbar total disc replacement as a standard of care for a subpopulation of patients suffering from degenerative disc disease.

  7. Statistic analysis of annual total ozone extremes for the period 1964-1988

    NASA Technical Reports Server (NTRS)

    Krzyscin, Janusz W.

    1994-01-01

    Annual extremes of total column amount of ozone (in the period 1964-1988) from a network of 29 Dobson stations have been examined using the extreme value analysis. The extremes have been calculated as the highest deviation of daily mean total ozone from its long-term monthly mean, normalized by the monthly standard deviations. The extremes have been selected from the direct-Sun total ozone observations only. The extremes resulting from abrupt changes in ozone (day to day changes greater than 20 percent) have not been considered. The ordered extremes (maxima in ascending way, minima in descending way) have been fitted to one of three forms of the Fisher-Tippet extreme value distribution by the nonlinear least square method (Levenberg-Marguard method). We have found that the ordered extremes from a majority of Dobson stations lie close to Fisher-Tippet type III. The extreme value analysis of the composite annual extremes (combined from averages of the annual extremes selected at individual stations) has shown that the composite maxima are fitted by the Fisher-Tippet type III and the composite minima by the Fisher-Tippet type I. The difference between the Fisher-Tippet types of the composite extremes seems to be related to the ozone downward trend. Extreme value prognoses for the period 1964-2014 (derived from the data taken at: all analyzed stations, the North American, and the European stations) have revealed that the prognostic extremes are close to the largest annual extremes in the period 1964-1988 and there are only small regional differences in the prognoses.

  8. 30 CFR 250.218 - What air emissions information must accompany the EP?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the EP? 250.218 Section 250.218 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION, AND... structure installation), you must list: (i) The projected peak hourly emissions; (ii) The total annual...) The frequency and duration of emissions; and (v) The total of all emissions listed in paragraphs (a)(1...

  9. Greenhouse Gas Emissions Increase Following the Termination of a Perennial Legume Phase of an Annual Crop Rotation within the Red River Valley, Manitoba

    NASA Astrophysics Data System (ADS)

    Hanis, K. L.; Tenuta, M.; Amiro, B. D.; Glenn, A. J.; Maas, S.; Gervais, M.

    2013-12-01

    Perennial legume forages may have the potential to increase soil carbon sequestration and decrease nitrous oxide (N2O) emissions to the atmosphere when introduced into annual cropping systems. However, little is known about what short-term effect the return to annual cropping following termination of perennial legume forage would have on carbon dioxide (CO2) and N2O emissions. Furthermore, there are few quantitative measurements about this impact on the Canadian Prairies. A long-term field experiment to continuously measure CO2 and N2O fluxes was established at the Trace Gas Manitoba (TGAS-MAN) Long Term Greenhouse Gas Monitoring Site at Glenlea, Manitoba using the flux gradient micrometeorlogical technique with a tunable diode laser analyzer. The soil is poorly drained clay in the Red River Valley. The field experiment consisted of four 4-hectare plots planted to corn in 2006 and faba bean in 2007. In 2008, grass-alfalfa forage was introduced to two plots (annual - perennial) and grown until 2011 whereas the other two plots (annual) were planted to annual crops: spring wheat, rapeseed, barley and spring wheat in 2008, 2009, 2010 and 2011, respectively. In late September of 2011 the grass-alfalfa forage was killed and in 2012 all four plots were planted with corn. Termination of the grass-alfalfa forage resulted in greater fall CO2 emissions in 2011, greater spring melt CO2 emissions and net annual N2O emissions in 2012 from the annual-perennial plots when compared to the annual plots. Over seven crop years (2006-2012), the annual - perennial system increased carbon uptake by 3.4 Mg C ha-1 and reduced N2O emissions by 3.0 Mg CO2-eq ha-1 compared to the annual system. However after accounting for harvest removals both the annual and annual-perennial systems were net carbon sources of 5.7 and 2.5 Mg C ha-1 and net GHG sources of 38 and 24 Mg CO2-eq ha-1 respectively. We are currently following the long-term impacts of inclusion of perennial forages in an annual

  10. 30 CFR 250.249 - What air emissions information must accompany the DPP or DOCD?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the DPP or DOCD? 250.249 Section 250.249 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF... must list: (i) The projected peak hourly emissions; (ii) The total annual emissions in tons per year... frequency and duration of emissions; and (v) The total of all emissions listed in paragraph (a)(1)(i...

  11. 40 CFR Appendix A to Part 72 - Methodology for Annualization of Emissions Limits

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Methodology for Annualization of Emissions Limits A Appendix A to Part 72 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Pt. 72, App. A Appendix A to Part 72—Methodology for...

  12. 40 CFR Appendix A to Part 72 - Methodology for Annualization of Emissions Limits

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Methodology for Annualization of Emissions Limits A Appendix A to Part 72 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Pt. 72, App. A Appendix A to Part 72—Methodology for...

  13. 500 years of mercury production: global annual inventory by region until 2000 and associated emissions.

    PubMed

    Hylander, Lars D; Meili, Markus

    2003-03-20

    Since pre-industrial times, anthropogenic emissions of Hg have at least doubled global atmospheric Hg deposition rates. In order to minimize environmental and human health effects, efforts have been made to reduce Hg emissions from industries and power plants, while less attention has been paid to Hg mining. This paper is a compilation of available data on primary Hg production and associated emissions with regional and annual resolution since colonial times. Globally, approximately one million tons of metallic Hg has been extracted from cinnabar and other ores during the past five centuries, half already before 1925. Roughly half has been used for mining of gold and silver, but the annual Hg production peaked during a short period of recent industrial uses. Comparison with total historic Hg deposition from global anthropogenic emissions (0.1-0.2 Mtons) suggests that only a few percent of all mined Hg have escaped to the atmosphere thus far. While production of primary Hg has changed dramatically over time and among mines, the global production has always been dominant in the region of the mercuriferous belt between the western Mediterranean and central Asia, but appears to be shifting to the east. Roughly half of the registered Hg has been extracted in Europe, where Spanish mines alone have contributed one third of the world's mined Hg. Approximately one fourth has been mined in the Americas, and most of the remaining registered Hg in Asia. However, the Asian figures may be largely underestimated. Presently, the dominant Hg mines are in Almadén in Spain (236 t of Hg produced in 2000), Khaydarkan in Kyrgyzstan (550 t), Algeria (estimated 240 t) and China (ca. 200 t). Mercury by-production from mining of other metals (e.g. copper, zinc, gold, silver) in 2000 includes 48 t from Peru, 45 t from Finland and at least 15 t from the USA. Since 1970, the recorded production of primary Hg has been reduced by almost an order of magnitude to approximately 2000 t in the year

  14. Annual Estimates of Global Anthropogenic Methane Emissions: 1860-1994

    DOE Data Explorer

    Stern, David I. [Boston Univ., MA (United States); Kaufmann, Robert K. [Boston Univ., MA (United States)

    1998-01-01

    The authors provide the first estimates, by year, of global man-made emissions of methane, from 1860 through 1994. The methods, including the rationale for the various coefficients and assumptions used in deriving the estimates, are described fully in Stern and Kaufmann (1995, 1996), which provides the estimates for the period 1860-1993; the data presented here are revised and updated through 1994. Some formulae and coefficients were also revised in that process. Estimates are provided for total anthropogenic emissions, as well as emissions for the following component categories: Flaring and Venting of Natural Gas; Oil and Gas Supply Systems, Excluding Flaring; Coal Mining; Biomass Burning; Livestock Farming; Rice Farming and Related Activities; Landfills. Changes in emissions over time were estimated by treating emissions as a function of variables (such as population or coal production) for which historical time series are available.

  15. 30 CFR 250.249 - What air emissions information must accompany the DPP or DOCD?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the DPP or DOCD? 250.249 Section 250.249 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT...) The total annual emissions in tons per year; (iii) Emissions over the duration of the proposed development and production activities; (iv) The frequency and duration of emissions; and (v) The total of all...

  16. 12 CFR Appendix K to Part 226 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 12 Banks and Banking 3 2014-01-01 2014-01-01 false Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions K Appendix K to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED..., App. K Appendix K to Part 226—Total Annual Loan Cost Rate Computations for Reverse Mortgage...

  17. 12 CFR Appendix K to Part 226 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 3 2013-01-01 2013-01-01 false Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions K Appendix K to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED..., App. K Appendix K to Part 226—Total Annual Loan Cost Rate Computations for Reverse Mortgage...

  18. CO2 emissions from German drinking water reservoirs.

    PubMed

    Saidi, Helmi; Koschorreck, Matthias

    2017-03-01

    Globally, reservoirs are a significant source of atmospheric CO 2 . However, precise quantification of greenhouse gas emissions from drinking water reservoirs on the regional or national scale is still challenging. We calculated CO 2 fluxes for 39 German drinking water reservoirs during a period of 22years (1991-2013) using routine monitoring data in order to quantify total emission of CO 2 from drinking water reservoirs in Germany and to identify major drivers. All reservoirs were a net CO 2 source with a median flux of 167gCm -2 y -1 , which makes gaseous emissions a relevant process for the carbon budget of each reservoir. Fluxes varied seasonally with median fluxes of 13, 48, and 201gCm -2 y -1 in spring, summer, and autumn respectively. Differences between reservoirs appeared to be primarily caused by the concentration of CO 2 in the surface water rather than by the physical gas transfer coefficient. Consideration of short term fluctuations of the gas transfer coefficient due to varying wind speed had only a minor effect on the annual budgets. High CO 2 emissions only occurred in reservoirs with pH<7 and total alkalinity <0.2mEql -1 . Annual CO 2 emissions correlated exponentially with pH but not with dissolved organic carbon (DOC). There was significant correlation between land use in the catchment and CO 2 emissions. In total, German drinking water reservoirs emit 44000t of CO 2 annually, which makes them a negligible CO 2 source (<0.005% of national CO 2 emissions) in Germany. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. China CO2 emission accounts 1997-2015

    NASA Astrophysics Data System (ADS)

    Shan, Yuli; Guan, Dabo; Zheng, Heran; Ou, Jiamin; Li, Yuan; Meng, Jing; Mi, Zhifu; Liu, Zhu; Zhang, Qiang

    2018-01-01

    China is the world's top energy consumer and CO2 emitter, accounting for 30% of global emissions. Compiling an accurate accounting of China's CO2 emissions is the first step in implementing reduction policies. However, no annual, officially published emissions data exist for China. The current emissions estimated by academic institutes and scholars exhibit great discrepancies. The gap between the different emissions estimates is approximately equal to the total emissions of the Russian Federation (the 4th highest emitter globally) in 2011. In this study, we constructed the time-series of CO2 emission inventories for China and its 30 provinces. We followed the Intergovernmental Panel on Climate Change (IPCC) emissions accounting method with a territorial administrative scope. The inventories include energy-related emissions (17 fossil fuels in 47 sectors) and process-related emissions (cement production). The first version of our dataset presents emission inventories from 1997 to 2015. We will update the dataset annually. The uniformly formatted emission inventories provide data support for further emission-related research as well as emissions reduction policy-making in China.

  20. 12 CFR Appendix K to Part 1026 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 12 Banks and Banking 8 2012-01-01 2012-01-01 false Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions K Appendix K to Part 1026 Banks and Banking BUREAU OF CONSUMER FINANCIAL PROTECTION TRUTH IN LENDING (REGULATION Z) Pt. 1026, App. K Appendix K to Part 1026—Total Annual Loan Cost...

  1. 12 CFR Appendix K to Part 1026 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 12 Banks and Banking 8 2013-01-01 2013-01-01 false Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions K Appendix K to Part 1026 Banks and Banking BUREAU OF CONSUMER FINANCIAL PROTECTION TRUTH IN LENDING (REGULATION Z) Pt. 1026, App. K Appendix K to Part 1026—Total Annual Loan Cost...

  2. Sulfur dioxide emissions from combustion in china: from 1990 to 2007.

    PubMed

    Su, Shenshen; Li, Bengang; Cui, Siyu; Tao, Shu

    2011-10-01

    China has become the world's largest emitter of SO(2) since 2005, and aggressive deployment of flue gas desulfurization (FGD) at coal-fired power plants appeared in China when facing the formidable pressure of environment pollution. In this work, we estimate the annual emission from combustion sources at provincial levels in China from 1990 to 2007, with updated data investigations. We have implemented the method of transportation matrix to gain a better understanding of sulfur content of coal in consuming provinces, which in turn improved the inventory. The total emissions from combustion in 2007 were 28.3 Tg, half of which was contributed by coal-fired power plants. Meanwhile, the industrial boiler coal combustion and residential coal consumed in centralized heating were responsible for another 32% of the total emissions. From 1990 to 2007, annual SO(2) emission was fluctuated with two peaks (1996 and 2006), and total emission doubled from 15.4 Tg to 30.8 Tg, at an annual growth rate of 4.4% (6.3% since 2000). Due to the extensive application of FGD technology and the phase-out of small, high emitting units, the SO(2) emission began to decrease after 2006. Furthermore, the differences among estimates reported in literatures highlight a great need for further research to reduce the uncertainties with more detailed information on key sources and actual operation of devices.

  3. Kyoto-Related Fossil-Fuel CO2 Emission Totals (1990 - 2009) (Version 2012) (Updated 01/16/2013)

    DOE Data Explorer

    Marland, Greg [Appalachian State University, Boone, NC (USA); Boden, Thomas A. [Carbon Dioxide Information Analysis Center (CDIAC), Oak Ridge National Laboratory (ORNL), Oak Ridge, TN

    2013-01-16

    This table shows the total of CO2 emissions from fossil-fuel use and cement manufacture for those countries listed in Annex B of the Kyoto Protocol and for those countries not listed in Annex B. In keeping with the convention of the IPCC methodology for calculating national greenhouse gas emissions, emissions from international bunker fuels (fuels used in international commerce) are not included in the country totals but are shown separately under the country group in which final fuel loading occurred. Note, that the list of countries in Annex B of the Kyoto Protocol differs from the list of countries in Annex I of the Framework Convention on Climate Change by the addition of Croatia, Liechtenstein, Monaco, and Slovenia and the removal of Belarus and Turkey. We have estimated emissions for 1990 and 1991 from the republics that were formerly part of the USSR and of Yugoslavia by taking total emissions from the USSR (and Yugoslavia) for 1990 and 1991 and distributing them among the new republics in the same ratio as emissions from those republics in 1992. Because of minor differences in the method of estimating the global total of emissions and the national totals of emissions, the sum of emissions from all countries produces a number that is less than the global total by about 2%. Consequently we have inflated the sum of emissions from all Annex B countries and the sum of emissions from all non-Annex B countries by about 2% (the value differs from year to year) so that the sum of the two values plus emissions from bunker fuels is equal to our best estimate of the global total of emissions.

  4. Annual methane and nitrous oxide emissions from rice paddies and inland fish aquaculture wetlands in southeast China

    NASA Astrophysics Data System (ADS)

    Wu, Shuang; Hu, Zhiqiang; Hu, Tao; Chen, Jie; Yu, Kai; Zou, Jianwen; Liu, Shuwei

    2018-02-01

    Inland aquaculture ponds have been documented as important sources of atmospheric methane (CH4) and nitrous oxide (N2O), while their regional or global source strength remains unclear due to lack of direct flux measurements by covering more typical habitat-specific aquaculture environments. In this study, we compared the CH4 and N2O fluxes from rice paddies and nearby inland fish aquaculture wetlands that were converted from rice paddies in southeast China. Both CH4 and N2O fluxes were positively related to water temperature and sediment dissolved organic carbon, but negatively related to water dissolved oxygen concentration. More robust response of N2O fluxes to water mineral N was observed than to sediment mineral N. Annual CH4 and N2O fluxes from inland fish aquaculture averaged 0.51 mg m-2 h-1 and 54.78 μg m-2 h-1, amounting to 42.31 kg CH4 ha-1 and 2.99 kg N2O-N ha-1, respectively. The conversion of rice paddies to conventional fish aquaculture significantly reduced CH4 and N2O emissions by 23% and 66%, respectively. The emission factor for N2O was estimated to be 0.46% of total N input in the feed or 1.23 g N2O-N kg-1 aquaculture production. The estimate of sustained-flux global warming potential of annual CH4 and N2O emissions and the net economic profit suggested that such conversion of rice paddies to inland fish aquaculture would help to reconcile the dilemma for simultaneously achieving both low climatic impacts and high economic benefits in China. More solid direct field measurements from inland aquaculture are in urgent need to direct the overall budget of national or global CH4 and N2O fluxes.

  5. Methane and nitrous oxide (N{sub 2}O) emission characteristics from automobiles

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Koike, Noriyuki; Odaka, Matsuo

    Exhaust gases discharged from automobiles are noticed as one of the reasons for recent increase in atmospheric methane and nitrous oxide concentration, which have been considered as greenhouse gases. In order to make an accurate estimation of methane and nitrous oxide discharged from automobiles, measurement methods were experimentally developed and emissions were measured for different kinds of automobiles under various driving conditions. Then, the authors have tried to estimate the annual global emissions from automobiles using these measurement results and statistical data such as the number of automobiles, the total annual mileage, and the total annual fuel consumption, etc. Themore » emissions from passenger vehicles which have been estimated from the global number of automobiles were 477.263 t/year for methane and 313.472 t/year for nitrous oxide. These numbers are higher than what had been estimated.« less

  6. India Co2 Emissions

    NASA Astrophysics Data System (ADS)

    Sharan, S.; Diffenbaugh, N. S.

    2010-12-01

    Is there a way to find a balance between improving living conditions for the people on the margins and also reducing emissions while limiting our negative impacts on the climate? This is a critical question today because there are many arguments between developed and developing countries about who is responsible for global warming. Developed countries believe that it is the poor countries because they are not educated enough to know about how they are affecting the climate. While the developing countries hold wealthy nations responsible because they are using the most resources. However it is important to acknowledge the fact that if there was no gap in between the developed and developing countries our emissions total would be much higher. This “gap” has been a natural controlling factor in climate change. This is why I wanted to see if I could plot what it would look like if a developing country such as India were to produce emissions that the US or Switzerland or Norway are producing as developed countries. India has a population total of 1.1 billion compared to the US with only 298 million, Switzerland with 7.5 million, and Norway with 4.6 million people. When the population is compared to the emissions output in metric tons, per capita, India produced the least emissions out of these countries, 1.4 tons per person while having the second largest population in the world, while the US produced 19 tons per capita, Switzerland produced 5.6 and Norway produced 8.7 tons per capita in 2006. The emissions rate is growing every year and increases widely and globally. If India was producing emissions that equal Norway, Switzerland and the US the total emissions it would be producing annually would be 9 billion for Norway, 6 billion for Switzerland and 20 billion emissions for the US, all in the year 2006 alone. This shows how the balance between countries with huge populations and very little emission output and average population and high emission out put has

  7. 40 CFR 98.33 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... you co-fire biomass fuels with fossil fuels, report CO2 emissions from the combustion of biomass... quarterly totals are summed to determine the annual CO2 mass emissions. (vii) If both biomass and fossil... by 1.1 to convert it to metric tons. (D) If both biomass and fossil fuel are combusted during the...

  8. China CO2 emission accounts 1997–2015

    PubMed Central

    Shan, Yuli; Guan, Dabo; Zheng, Heran; Ou, Jiamin; Li, Yuan; Meng, Jing; Mi, Zhifu; Liu, Zhu; Zhang, Qiang

    2018-01-01

    China is the world’s top energy consumer and CO2 emitter, accounting for 30% of global emissions. Compiling an accurate accounting of China’s CO2 emissions is the first step in implementing reduction policies. However, no annual, officially published emissions data exist for China. The current emissions estimated by academic institutes and scholars exhibit great discrepancies. The gap between the different emissions estimates is approximately equal to the total emissions of the Russian Federation (the 4th highest emitter globally) in 2011. In this study, we constructed the time-series of CO2 emission inventories for China and its 30 provinces. We followed the Intergovernmental Panel on Climate Change (IPCC) emissions accounting method with a territorial administrative scope. The inventories include energy-related emissions (17 fossil fuels in 47 sectors) and process-related emissions (cement production). The first version of our dataset presents emission inventories from 1997 to 2015. We will update the dataset annually. The uniformly formatted emission inventories provide data support for further emission-related research as well as emissions reduction policy-making in China. PMID:29337312

  9. Dust emission inventory in Northern China

    NASA Astrophysics Data System (ADS)

    Xuan, Jie; Liu, Guoliang; Du, Ke

    This paper deals with mineral dust emission inventory from surfaces of Northern China. The inventory was calculated with a US EPA formula by inputting the pre-processed Chinese data of pedology and climatology. Mainly, the emission factor (emission rate) of the dust particles whose diameters are less than 0.03 mm increases from east to west of the area by five orders of magnitude and there are two strong emission regions, one is in Takelamagan desert, Xinjiang Province, and the other in Central Gobi-desert, western part of inner-Mongolia plateau. The maximum rate is at center of the Takelamagan desert, i.e., 1.5 ton ha yr -1. Also, the total annual emission amount of the area is equal to some 25 million tons, and spring is the worst dust-emitting season in the area, which takes more than half of the annual emission amount. The results are in good agreement with the previous calculations using a different US EPA formula (Xuan, J., 1999. Dust emission factors for environment of Northern China. Atmospheric Environment 33, 1767-1776).

  10. The travel-related carbon dioxide emissions of atmospheric researchers

    NASA Astrophysics Data System (ADS)

    Stohl, A.

    2008-11-01

    Most atmospheric scientists agree that greenhouse gas emissions have already caused significant changes to the global climate system and that these changes will accelerate in the near future. At the same time, atmospheric scientists who like other scientists rely on international collaboration and information exchange travel a lot and, thereby, cause substantial emissions of CO2. In this paper, the CO2 emissions of the employees working at an atmospheric research institute (the Norwegian Institute for Air Research, NILU) caused by all types of business travel (conference visits, workshops, field campaigns, instrument maintainance, etc.) were calculated for the years 2005 2007. It is estimated that more than 90% of the emissions were caused by air travel, 3% by ground travel and 5% by hotel usage. The travel-related annual emissions were between 1.9 and 2.4 t CO2 per employee or between 3.9 and 5.5 t CO2 per scientist. For comparison, the total annual per capita CO2 emissions are 4.5 t worldwide, 1.2 t for India, 3.8 t for China, 5.9 t for Sweden and 19.1 t for Norway. The travel-related CO2 emissions of a NILU scientist, occurring in 24 days of a year on average, exceed the global average annual per capita emission. Norway's per-capita CO2 emissions are among the highest in the world, mostly because of the emissions from the oil industry. If the emissions per NILU scientist derived in this paper are taken as representative for the average Norwegian researcher, travel by Norwegian scientists would nevertheless account for a substantial 0.2% of Norway's total CO2 emissions. Since most of the travel-related emissions are due to air travel, water vapor emissions, ozone production and contrail formation further increase the relative importance of NILU's travel in terms of radiative forcing.

  11. The travel-related carbon dioxide emissions of atmospheric researchers

    NASA Astrophysics Data System (ADS)

    Stohl, A.

    2008-04-01

    Most atmospheric scientists agree that greenhouse gas emissions have already caused significant changes to the global climate system and that these changes will accelerate in the near future. At the same time, atmospheric scientists who - like other scientists - rely on international collaboration and information exchange travel a lot and, thereby, cause substantial emissions of carbon dioxide (CO2). In this paper, the CO2 emissions of the employees working at an atmospheric research institute (the Norwegian Institute for Air Research, NILU) caused by all types of business travel (conference visits, workshops, field campaigns, instrument maintainance, etc.) were calculated for the years 2005-2007. It is estimated that more than 90% of the emissions were caused by air travel, 3% by ground travel and 5% by hotel usage. The travel-related annual emissions were between 1.9 and 2.4 t CO2 per employee or between 3.9 and 5.5 t CO2 per scientist. For comparison, the total annual per capita CO2 emissions are 4.5 t worldwide, 1.2 t for India, 3.8 t for China, 5.9 t for Sweden and 19.1 t for Norway. The travel-related CO2 emissions of a NILU scientist, occurring in 24 days of a year on average, exceed the global average annual per capita emission. Norway's per-capita CO2 emissions are among the highest in the world, mostly because of the emissions from the oil industry. If the emissions per NILU scientist derived in this paper are taken as representative for the average Norwegian researcher, travel by Norwegian scientists would nevertheless account for a substantial 0.2% of Norway's total CO2 emissions. Since most of the travel-related emissions are due to air travel, water vapor emissions, ozone production and contrail formation further increase the relative importance of NILU's travel in terms of radiative forcing.

  12. Ozone response to emission reductions in the southeastern United States

    NASA Astrophysics Data System (ADS)

    Blanchard, Charles L.; Hidy, George M.

    2018-06-01

    Ozone (O3) formation in the southeastern US is studied in relation to nitrogen oxide (NOx) emissions using long-term (1990s-2015) surface measurements of the Southeastern Aerosol Research and Characterization (SEARCH) network, U.S. Environmental Protection Agency (EPA) O3 measurements, and EPA Clean Air Status and Trends Network (CASTNET) nitrate deposition data. Annual fourth-highest daily peak 8 h O3 mixing ratios at EPA monitoring sites in Georgia, Alabama, and Mississippi exhibit statistically significant (p < 0.0001) linear correlations with annual NOx emissions in those states between 1996 and 2015. The annual fourth-highest daily peak 8 h O3 mixing ratios declined toward values of ˜ 45-50 ppbv and monthly O3 maxima decreased at rates averaging ˜ 1-1.5 ppbv yr-1. Mean annual total oxidized nitrogen (NOy) mixing ratios at SEARCH sites declined in proportion to NOx emission reductions. CASTNET data show declining wet and dry nitrate deposition since the late 1990s, with total (wet plus dry) nitrate deposition fluxes decreasing linearly in proportion to reductions of NOx emissions by ˜ 60 % in Alabama and Georgia. Annual nitrate deposition rates at Georgia and Alabama CASTNET sites correspond to 30 % of Georgia emission rates and 36 % of Alabama emission rates, respectively. The fraction of NOx emissions lost to deposition has not changed. SEARCH and CASTNET sites exhibit downward trends in mean annual nitric acid (HNO3) concentrations. Observed relationships of O3 to NOz (NOy-NOx) support past model predictions of increases in cycling of NO and increasing responsiveness of O3 to NOx. The study data provide a long-term record that can be used to examine the accuracy of process relationships embedded in modeling efforts. Quantifying observed O3 trends and relating them to reductions in ambient NOy species concentrations offers key insights into processes of general relevance to air quality management and provides important information supporting strategies for

  13. Annual and Semi-Annual Temperature Oscillations in the Upper Mesosphere

    NASA Technical Reports Server (NTRS)

    Niciejewski, R. J.; Killeen, T. L.

    1995-01-01

    Fourier transform spectrometer observations of the mesosphere have been performed at the University of Michigan (latitude: 42.5 N) on a long term basis. A database of near infrared Meinel hydroxyl spectra has been accumulated from which rotational temperatures have been determined. Harmonic analysis of one-day averaged temperatures for the period 1992.0 to 1994.5 has shown a distinct annual and semi-annual variation. Subsequent fitting of a five term periodic function characterizing the annual and semi-annual temperature oscillations to the daily averaged temperatures was performed. The resultant mean temperature and the amplitudes and phases of the annual and semi-annual variations are shown to coincide with an emission height slightly above 85 km which is consistent with the mean rocket derived altitude for peak nocturnal hydroxyl emission.

  14. 77 FR 24382 - Approval and Promulgation of Air Quality Implementation Plans; North Carolina; Annual Emissions...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-24

    ..., Lincoln, Rowan, and Union Counties in their entireties and Davidson Township and Coddle Creek Township in..., Durham, Forsyth, Gaston, Guilford, Mecklenburg, and Wake County, the Dutchville Township in Granville... entireties and Davidson Township and Coddle Creek Township in Iredell County to the annual emissions...

  15. European emissions of the powerful greenhouse gases hydrofluorocarbons inferred from atmospheric measurements and their comparison with annual national reports to UNFCCC

    NASA Astrophysics Data System (ADS)

    Graziosi, F.; Arduini, J.; Furlani, F.; Giostra, U.; Cristofanelli, P.; Fang, X.; Hermanssen, O.; Lunder, C.; Maenhout, G.; O'Doherty, S.; Reimann, S.; Schmidbauer, N.; Vollmer, M. K.; Young, D.; Maione, M.

    2017-06-01

    Hydrofluorocarbons are powerful greenhouse gases developed by industry after the phase-out of the ozone depleting chlorofluorocarbons and hydrochlorofluorocarbons required by the Montreal Protocol. The climate benefit of reducing the emissions of hydrofluorocarbons has been widely recognised, leading to an amendment of the Montreal Protocol (Kigali Amendment) calling for developed countries to start to phase-down hydrofluorocarbons by 2019 and in developing countries to follow with a freeze between 2024 and 2028. In this way, nearly half a degree Celsius of warming would be avoided by the end of the century. Hydrofluorocarbons are also included in the basket of gases controlled under the Kyoto Protocol of the United Nations Framework Convention on Climate Change. Annex I parties to the Convention submit annual national greenhouse gas inventories based on a bottom-up approach, which relies on declared anthropogenic activities. Top-down methodologies, based on atmospheric measurements and modelling, can be used in support to the inventory compilation. In this study we used atmospheric data from four European sites combined with the FLEXPART dispersion model and a Bayesian inversion method, in order to derive emissions of nine individual hydrofluorocarbons from the whole European Geographic Domain and from twelve regions within it, then comparing our results with the annual emissions that the European countries submit every year to the United Nations Framework Convention on Climate Change, as well as with the bottom-up Emissions Database for Global Atmospheric Research. We found several discrepancies when considering the specific compounds and on the country level. However, an overall agreement is found when comparing European aggregated data, which between 2008 and 2014 are on average 84.2 ± 28.0 Tg-CO2-eq·yr-1 against the 95.1 Tg-CO2-eq·yr-1 reported by UNFCCC in the same period. Therefore, in agreement with other studies, the gap on the global level between

  16. High methane emissions dominate annual greenhouse gas balances 30 years after bog rewetting

    NASA Astrophysics Data System (ADS)

    Vanselow-Algan, M.; Schmidt, S. R.; Greven, M.; Fiencke, C.; Kutzbach, L.; Pfeiffer, E.-M.

    2015-02-01

    Natural peatlands are important carbon sinks and sources of methane (CH4). In contrast, drained peatlands turn from a carbon sink to a carbon source and potentially emit nitrous oxide (N2O). Rewetting of peatlands thus implies climate change mitigation. However, data about the time span that is needed for the re-establishment of the carbon sink function by restoration is scarce. We therefore investigated the annual greenhouse gas (GHG) balances of three differently vegetated bog sites 30 years after rewetting. All three vegetation communities turned out to be sources of carbon dioxide (CO2) ranging between 0.6 ± 1.43 t CO2 ha-2 yr-1 (Sphagnum-dominated vegetation) and 3.09 ± 3.86 t CO2 ha-2 yr-1 (vegetation dominated by heath). While accounting for the different global warming potential (GWP) of the three greenhouse gases, the annual GHG balance was calculated. Emissions ranged between 25 and 53 t CO2-eq ha-1 yr-1 and were dominated by large emissions of CH4 (22 up to 51 t CO2-eq ha-1 yr-1), while highest rates were found at purple moor grass (Molinia caerulea) stands. These are to our knowledge the highest CH4 emissions so far reported for bog ecosystems in temperate Europe. As the restored area was subject to large fluctuations in water table, we conclude that the high CH4 emission rates were caused by a combination of both the temporal inundation of the easily decomposable plant litter of this grass species and the plant-mediated transport through its tissues. In addition, as a result of the land use history, the mixed soil material can serve as an explanation. With regards to the long time span passed since rewetting, we note that the initial increase in CH4 emissions due to rewetting as described in the literature is not limited to a short-term period.

  17. High methane emissions dominated annual greenhouse gas balances 30 years after bog rewetting

    NASA Astrophysics Data System (ADS)

    Vanselow-Algan, M.; Schmidt, S. R.; Greven, M.; Fiencke, C.; Kutzbach, L.; Pfeiffer, E.-M.

    2015-07-01

    Natural peatlands are important carbon sinks and sources of methane (CH4). In contrast, drained peatlands turn from a carbon sink to a carbon source and potentially emit nitrous oxide (N2O). Rewetting of peatlands thus potentially implies climate change mitigation. However, data about the time span that is needed for the re-establishment of the carbon sink function by restoration are scarce. We therefore investigated the annual greenhouse gas (GHG) balances of three differently vegetated sites of a bog ecosystem 30 years after rewetting. All three vegetation communities turned out to be sources of carbon dioxide (CO2) ranging between 0.6 ± 1.43 t CO2 ha-2 yr-1 (Sphagnum-dominated vegetation) and 3.09 ± 3.86 t CO2 ha-2 yr-1 (vegetation dominated by heath). While accounting for the different global warming potential (GWP) of CO2, CH4 and N2O, the annual GHG balance was calculated. Emissions ranged between 25 and 53 t CO2-eq ha-1 yr-1 and were dominated by large emissions of CH4 (22-51 t CO2-eq ha-1 yr-1), with highest rates found at purple moor grass (Molinia caerulea) stands. These are to our knowledge the highest CH4 emissions so far reported for bog ecosystems in temperate Europe. As the restored area was subject to large fluctuations in the water table, we assume that the high CH4 emission rates were caused by a combination of both the temporal inundation of the easily decomposable plant litter of purple moor grass and the plant-mediated transport through its tissues. In addition, as a result of the land use history, mixed soil material due to peat extraction and refilling can serve as an explanation. With regards to the long time span passed since rewetting, we note that the initial increase in CH4 emissions due to rewetting as described in the literature is not inevitably limited to a short-term period.

  18. Methane and nitrous oxide emissions from three paddy rice based cultivation systems in Southwest China

    NASA Astrophysics Data System (ADS)

    Jiang, Changsheng; Wang, Yuesi; Zheng, Xunhua; Zhu, Bo; Huang, Yao; Hao, Qingju

    2006-05-01

    To understand methane (CH4) and nitrous oxide (N2O) emissions from permanently flooded rice paddy fields and to develop mitigation options, a field experiment was conducted in situ for two years (from late 2002 to early 2005) in three rice-based cultivation systems, which are a permanently flooded rice field cultivated with a single time and followed by a non-rice season (PF), a rice-wheat rotation system (RW) and a rice-rapeseed rotation system (RR) in a hilly area in Southwest China. The results showed that the total CH4 emissions from PF were 646.3±52.1 and 215.0±45.4 kg CH4 hm-2 during the rice-growing period and non-rice period, respectively. Both values were much lower than many previous reports from similar regions in Southwest China. The CH4 emissions in the rice-growing season were more intensive in PF, as compared to RW and RR. Only 33% of the total annual CH4 emission in PF occurred in the non-rice season, though the duration of this season is two times longer than the rice season. The annual mean N2O flux in PF was 4.5±0.6 kg N2O hm-2 yr-1. The N2O emission in the rice-growing season was also more intensive than in the non-rice season, with only 16% of the total annual emission occurring in the non-rice season. The amounts of N2O emission in PF were ignorable compared to the CH4 emission in terms of the global warming potential (GWP). Changing PF to RW or RR not only eliminated CH4 emissions in the non-rice season, but also substantially reduced the CH4 emission during the following rice-growing period (ca. 58%, P<0.05). However, this change in cultivation system substantially increased N2O emissions, especially in the non-rice season, by a factor of 3.7 to 4.5. On the 100-year horizon, the integrated GWP of total annual CH4 and N2O emissions satisfies PF≫RR≈RW. The GWP of PF is higher than that of RW and RR by a factor of 2.6 and 2.7, respectively. Of the total GWP of CH4 and N2O emissions, CH4 emission contributed to 93%, 65% and 59% in PF, RW

  19. Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone, 1958-1987 (1991)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Angell, J. K.; Korshover, J.; Planet, W. G.

    For 1958 through 1987, this data base presents total ozone variations and layer mean ozone variations expressed as percent deviations from the 1958 to 1977 mean. The total ozone variations were derived from mean monthly ozone values published in Ozone Data for the World by the Atmospheric Environment Service in cooperation with the World Meteorological Organization. The layer mean ozone variations are derived from ozonesonde and Umkehr observations. The data records include year, seasonal and annual total ozone variations, and seasonal and annual layer mean ozone variations. The total ozone data are for four regions (Soviet Union, Europe, North America,more » and Asia); five climatic zones (north and south polar, north and south temperate, and tropical); both hemispheres; and the world. Layer mean ozone data are for four climatic zones (north and south temperate and north and south polar) and for the stratosphere, troposphere, and tropopause layers. The data are in two files [seasonal and year-average total ozone (13.4 kB) and layer mean ozone variations (24.2 kB)].« less

  20. Estimation of mercury emission from different sources to atmosphere in Chongqing, China.

    PubMed

    Wang, Dingyong; He, Lei; Wei, Shiqiang; Feng, Xinbin

    2006-08-01

    This investigation presents a first assessment of the contribution to the regional mercury budget from anthropogenic and natural sources in Chongqing, an important industrial region in southwest China. The emissions of mercury to atmosphere from anthropogenic sources in the region were estimated through indirect approaches, i.e. using commonly acceptable emission factors method, which based on annual process throughputs or consumption for these sources. The natural mercury emissions were estimated from selected natural sources by the dynamic flux chamber technique. The results indicated that the anthropogenic mercury emissions totaled approximately 8.85 tons (t), more than 50% of this total originated in coal combustion and 23.7% of this total emission in the industrial process (include cement production, metal smelting and chemical industry). The natural emissions represented approximately 17% of total emissions (1.78 t yr(-1)). The total mercury emission to atmosphere in Chongqing in 2001 was 10.63 t.

  1. Annual Fossil-Fuel CO2 Emissions: Uncertainty of Emissions Gridded by On Degree Latitude by One Degree Longitude (1950-2013) (V. 2016)

    DOE Data Explorer

    Andres, R. J. [CDIAC; Boden, T. A. [CDIAC

    2016-01-01

    The annual, gridded fossil-fuel CO2 emissions uncertainty estimates from 1950-2013 provided in this database are derived from time series of global, regional, and national fossil-fuel CO2 emissions (Boden et al. 2016). Andres et al. (2016) describes the basic methodology in estimating the uncertainty in the (gridded fossil fuel data product ). This uncertainty is gridded at the same spatial and temporal scales as the mass magnitude maps. This gridded uncertainty includes uncertainty contributions from the spatial, temporal, proxy, and magnitude components used to create the magnitude map of FFCO2 emissions. Throughout this process, when assumptions had to be made or expert judgment employed, the general tendency in most cases was toward overestimating or increasing the magnitude of uncertainty.

  2. The total hemispheric emissivity of painted aluminum honeycomb at cryogenic temperatures

    NASA Astrophysics Data System (ADS)

    Tuttle, J.; Canavan, E.; DiPirro, M.; Li, X.; Knollenberg, P.

    2014-01-01

    NASA uses high-emissivity surfaces on deep-space radiators and thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and compare the results with predictions from a detailed thermal model of each honeycomb configuration.

  3. The Total Hemispheric Emissivity of Painted Aluminum Honeycomb at Cryogenic Temperatures

    NASA Technical Reports Server (NTRS)

    Tuttle, J.; Canavan, E.; DiPirro, M.; Li, X.; Knollenberg, K.

    2013-01-01

    NASA uses high-emissivity surfaces on deep-space radiators or thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and compare the results with predictions from a detailed thermal model of each honeycomb configuration.

  4. Summary Report of the Seventh Annual NASA/Contractors Conference on Quality and Productivity: "Total Quality Leadership"

    NASA Technical Reports Server (NTRS)

    1991-01-01

    More than 750 NASA, government, contractor, and academic representatives attended the Seventh Annual NASA/Contractors Conference on Quality and Productivity on October 12-13, 1990, in Grenelefe, Florida. The panel presentations and keynote speeches revolving around the theme of 'Total Quality Leadership" provided a solid base of understanding of the importance, benefits, and principles of total quality management. The implementation of these strategies is critical if we are to effectively pursue our mission of continuous quality improvement and reliability in our products, processes, and services. The annual NASA/contractors conferences serve as catalysts for achieving success in this mission.

  5. Have the annual trends of total hip arthroplasty in rheumatoid arthritis patients decreased?

    PubMed Central

    Onuoha, Kemjika O.; Solow, Max; Newman, Jared M.; Sodhi, Nipun; Pivec, Robert; Khlopas, Anton; Sultan, Assem A.; Chughtai, Morad; Shah, Neil V.; George, Jaiben

    2017-01-01

    Background Rheumatoid arthritis (RA) is characterized by chronic systemic and synovial inflammation, resulting in damage to both cartilage and bone. Medical treatment, which has increasingly relied upon disease modifying anti-rheumatic drugs (DMARDs), may fail to slow disease progression and limit joint damage, ultimately warranting surgical intervention. Up to 25% of RA patients will require lower extremity total joint arthroplasty. Though total hip arthroplasty (THA) is known to improve quality of life and functional measures, clarification is still required with respect to the impact of increased DMARD use on annual rates of THA. Thus, the purpose of this study was to evaluate: (I) the annual trends of THAs due to RA in the United States population; (II) the annual trends in the proportion of THAs due to RA in the United States. Methods This study utilized the Nationwide Inpatient Sample (NIS) to identify all patients who underwent THA between 2002 and 2013 (n=3,135,904). Then, THA patients who had a diagnosis of RA, which was defined by the International Classification of Disease 9th revision diagnosis code 714.0, were identified. The incidence of THAs with a diagnosis of RA in the United States was calculated using the United States population as the denominator. Regression models were used to analyze the annual trends of RA in patients who underwent THA. Results Review of the database identified 90,487 patients who had a diagnosis of RA and underwent THA from 2002 to 2013. The annual prevalence of RA in those who underwent THA slightly decreased over the specified time period, with 28.7 per 1,000 THAs in 2002 and 28.6 per 1,000 THAs in 2013; however, this change was not statistically significant (R2=0.158, P=0.200). Conclusions The annual rates of THA among RA patients did not show any significant change between 2002 and 2013. DMARD use has decreased both disease progression and joint destruction, and DMARDs are now often utilized as primary treatment. The

  6. Importance of the autumn overturn and anoxic conditions in the hypolimnion for the annual methane emissions from a temperate lake.

    PubMed

    Encinas Fernández, Jorge; Peeters, Frank; Hofmann, Hilmar

    2014-07-01

    Changes in the budget of dissolved methane measured in a small temperate lake over 1 year indicate that anoxic conditions in the hypolimnion and the autumn overturn period represent key factors for the overall annual methane emissions from lakes. During periods of stable stratification, large amounts of methane accumulate in anoxic deep waters. Approximately 46% of the stored methane was emitted during the autumn overturn, contributing ∼80% of the annual diffusive methane emissions to the atmosphere. After the overturn period, the entire water column was oxic, and only 1% of the original quantity of methane remained in the water column. Current estimates of global methane emissions assume that all of the stored methane is released, whereas several studies of individual lakes have suggested that a major fraction of the stored methane is oxidized during overturns. Our results provide evidence that not all of the stored methane is released to the atmosphere during the overturn period. However, the fraction of stored methane emitted to the atmosphere during overturn may be substantially larger and the fraction of stored methane oxidized may be smaller than in the previous studies suggesting high oxidation losses of methane. The development or change in the vertical extent and duration of the anoxic hypolimnion, which can represent the main source of annual methane emissions from small lakes, may be an important aspect to consider for impact assessments of climate warming on the methane emissions from lakes.

  7. The total hemispheric emissivity of painted aluminum honeycomb at cryogenic temperatures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tuttle, J.; Canavan, E.; DiPirro, M.

    NASA uses high-emissivity surfaces on deep-space radiators and thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and comparemore » the results with predictions from a detailed thermal model of each honeycomb configuration.« less

  8. TRASER - Total Reflection Amplification of Spontaneous Emission of Radiation

    PubMed Central

    Zachary, Christopher B.; Gustavsson, Morgan

    2012-01-01

    Background and Objective Light and lasers in medical therapy have made dramatic strides since their invention five decades ago. However, the manufacture of lasers can be complex and expensive which often makes treatments limited and costly. Further, no single laser will provide the correct parameters to treat all things. Hence, laser specialists often need multiple devices to practice their specialty. A new concept is described herein that has the potential to replace many lasers and light sources with a single ‘tunable’ device. Study Design/Material and Methods This device amplifies spontaneous emission of radiation by capturing and retaining photons through total internal reflection, hence the acronym Total Reflection Amplification of Spontaneous Emission of Radiation, or TRASER. Results Specific peaks of light can be produced in a reproducible manner with high peak powers of variable pulse durations, a large spot size, and high repetition rate. Conclusion Considering the characteristics and parameters of Traser technology, it is possible that this one device would likely be able to replace the pulsed dye laser and many other light based systems. PMID:22558261

  9. Implications of emission inventory choice for modeling fire-related pollution in the U.S.

    EPA Science Inventory

    Fires are a major source of particulate matter (PM), one of the most harmful ambient pollutants for human health globally. Within the U.S., fire emissions can account for more than 30% of total PM emissions annually. In order to represent the influence of fire emissions on atmosp...

  10. Airport emissions quantification: Impacts of electrification. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Geba, V.

    1998-07-01

    Four airports were assessed to demonstrate that electrification of economically viable air- and land-side vehicles and equipment can significantly reduce total airport emissions. Assessments were made using the FAA`s Emissions and Dispersion Modeling System and EPRI Airport Electrification Project data. Development and implementation of cost-effective airport emissions reduction strategies can be complex, requiring successful collaboration of local, state, and federal regulatory agencies with airport authorities. The methodology developed in this study helps to simplify this task. The objectives of this study were: to develop a methodology to quantify annual emissions at US airports from all sources--aircraft, vehicles, and infrastructure; andmore » to demonstrate that electrification of economically viable air- and land-side vehicles and equipment can significantly reduce total airport emissions on-site, even when allowing for emissions from the generation of electricity.« less

  11. Guidance for creating annual on-road mobile source emission inventories for PM2.5 nonattainment areas for use in SIPs and conformity.

    DOT National Transportation Integrated Search

    2005-08-01

    The purpose of this document is to provide areas that are nonattainment or maintenance for the annual PM2.5 national ambient air quality standard (standard) with guidance on developing annual PM2.5 on-road motor vehicle emissions estimates to m...

  12. Assessing global radiative forcing due to regional emissions of tropospheric ozone precursors: a step towards climate credit for ozone reductions

    NASA Astrophysics Data System (ADS)

    Mauzerall, D. L.; Naik, V.; Horowitz, L. W.; Schwarzkopf, D.; Ramaswamy, V.; Oppenheimer, M.

    2005-05-01

    Carbon dioxide emissions from fossil-fuel consumption are presented for the five Asian countries that are among the global leaders in anthropogenic carbon emissions: China (13% of global total), Japan (5% of global total), India (5% of global total), South Korea (2% of global total), and Indonesia (1% of global total). Together, these five countries represent over a quarter of the world's fossil-fuel based carbon emissions. Moreover, these countries are rapidly developing and energy demand has grown dramatically in the last two decades. A method is developed to estimate the spatial and seasonal flux of fossil-fuel consumption, thereby greatly improving the temporal and spatial resolution of anthropogenic carbon dioxide emissions. Currently, only national annual data for anthropogenic carbon emissions are available, and as such, no understanding of seasonal or sub-national patterns of emissions are possible. This methodology employs fuel distribution data from representative sectors of the fossil-fuel market to determine the temporal and spatial patterns of fuel consumption. These patterns of fuel consumption are then converted to patterns of carbon emissions. The annual total emissions estimates produced by this method are consistent to those maintained by the United Nations. Improved estimates of temporal and spatial resolution of the human based carbon emissions allows for better projections about future energy demands, carbon emissions, and ultimately the global carbon cycle.

  13. Consumption-based Total Suspended Particulate Matter Emissions in Jing-Jin-Ji Area of China

    NASA Astrophysics Data System (ADS)

    Yang, S.; Chen, S.; Chen, B.

    2014-12-01

    The highly-industrialized regions in China have been facing a serious problem of haze mainly consisted of total suspended particulate matter (TSPM), which has attracted great attention from the public since it directly impairs human health and clinically increases the risks of various respiratory and pulmonary diseases. In this paper, we set up a multi-regional input-output (MRIO) model to analyze the transferring routes of TSPM emissions between regions through trades. TSPM emission from particulate source regions and sectors are identified by analyzing the embodied TSPM flows through monetary flow and carbon footprint. The track of TSPM from origin to end via consumption activities are also revealed by tracing the product supply chain associated with the TSPM emissions. Beijing-Tianjin-Hebei (Jing-Jin-Ji) as the most industrialized area of China is selected for a case study. The result shows that over 70% of TSPM emissions associated with goods consumed in Beijing and Tianjin occurred outside of their own administrative boundaries, implying that Beijing and Tianjin are net embodied TSPM importers. Meanwhile, 63% of the total TSPM emissions in Hebei Province are resulted from the outside demand, indicating Hebei is a net exporter. In addition, nearly half of TSPM emissions are the by-products related to electricity and heating supply and non-metal mineral products in Jing-Jin-Ji Area. Based on the model results, we provided new insights into establishing systemic strategies and identifying mitigation priorities to stem TSPM emissions in China. Keywords: total suspended particulate matter (TSPM); urban ecosystem modeling; multi-regional input-output (MRIO); China

  14. Estimates of Fossil Fuel Carbon Dioxide Emissions From Mexico at Monthly Time Intervals

    NASA Astrophysics Data System (ADS)

    Losey, L. M.; Andres, R. J.

    2003-12-01

    Human consumption of fossil fuels has greatly contributed to the rise of carbon dioxide in the Earth's atmosphere. To better understand the global carbon cycle, it is important to identify the major sources of these fossil fuels. Mexico is among the top fifteen nations in the world for producing fossil fuel carbon dioxide emissions. Based on this information and that emissions from Mexico are a focus of the North American Carbon Program, Mexico was selected for this study. Mexican monthly inland sales volumes for January 1988-May 2003 were collected on natural gas and liquid fuels from the Energy Information Agency in the United States Department of Energy. These sales figures represent a major portion of the total fossil fuel consumption in Mexico. The fraction of a particular fossil fuel consumed in a given month was determined by dividing the monthly sales volumes by the annual sum of monthly sales volumes for a given year. This fraction was then multiplied by the annual carbon dioxide values reported by the Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL) to estimate the monthly carbon dioxide emissions from the respective fuels. The advantages of this methodology are: 1) monthly fluxes are consistent with the annual flux as determined by the widely-accepted CDIAC values, and 2) its general application can be easily adapted to other nations for determining their sub-annual time scale emissions. The major disadvantage of this methodology is the proxy nature inherent to it. Only a fraction of the total emissions are used as an estimate in determining the seasonal cycle. The error inherent in this approach increases as the fraction of total emissions represented by the proxy decreases. These data are part of a long-term project between researchers at the University of North Dakota and ORNL which attempts to identify and understand the source(s) of seasonal variations of global, fossil-fuel derived, carbon dioxide emissions

  15. The importance of policy in emissions inventory accuracy--a lesson from British Columbia, Canada.

    PubMed

    Krzyzanowski, Judi

    2009-04-01

    Actual atmospheric emissions in northeast British Columbia, Canada, are much higher than reported emissions. The addition of upstream oil and gas sector sources not included in the year-2000 emissions inventory of Criteria Air Contaminants (CACs) increases annual totals of nitrogen oxides, sulfur oxides, and volatile organic compound emissions by 115.1, 89.9, and 109.5%, respectively. These emissions arise from numerous small and unregulated point sources (N = 10,129). CAC summaries are given by source type and source sector. An analysis of uncertainty and reporting policy suggests that inventory omissions are not limited to the study area and that Canadian pollutant emissions are systematically underestimated. The omissions suggest that major changes in reporting procedures are needed in Canada if true estimates of annual pollutant emissions are to be documented.

  16. Mercury emissions from biomass burning in China.

    PubMed

    Huang, Xin; Li, Mengmeng; Friedli, Hans R; Song, Yu; Chang, Di; Zhu, Lei

    2011-11-01

    Biomass burning covers open fires (forest and grassland fires, crop residue burning in fields, etc.) and biofuel combustion (crop residues and wood, etc., used as fuel). As a large agricultural country, China may produce large quantities of mercury emissions from biomass burning. A new mercury emission inventory in China is needed because previous studies reflected outdated biomass burning with coarse resolution. Moreover, these studies often adopted the emission factors (mass of emitted species per mass of biomass burned) measured in North America. In this study, the mercury emissions from biomass burning in China (excluding small islands in the South China Sea) were estimated, using recently measured mercury concentrations in various biomes in China as emission factors. Emissions from crop residues and fuelwood were estimated based on annual reports distributed by provincial government. Emissions from forest and grassland fires were calculated by combining moderate resolution imaging spectroradiometer (MODIS) burned area product with combustion efficiency (ratio of fuel consumption to total available fuels) considering fuel moisture. The average annual emission from biomass burning was 27 (range from 15.1 to 39.9) Mg/year. This inventory has high spatial resolution (1 km) and covers a long period (2000-2007), making it useful for air quality modeling.

  17. Ammonia emissions from dairy production in Wisconsin.

    PubMed

    Harper, L A; Flesch, T K; Powell, J M; Coblentz, W K; Jokela, W E; Martin, N P

    2009-05-01

    Ammonia gas is the only significant basic gas that neutralizes atmospheric acid gases produced from combustion of fossil fuels. This reaction produces an aerosol that is a component of atmospheric haze, is implicated in nitrogen (N) deposition, and may be a potential human health hazard. Because of the potential impact of NH3 emissions, environmentally and economically, the objective of this study was to obtain representative and accurate NH3 emissions data from large dairy farms (>800 cows) in Wisconsin. Ammonia concentrations and climatic measurements were made on 3 dairy farms during winter, summer, and autumn to calculate emissions using an inverse-dispersion analysis technique. These study farms were confinement systems utilizing freestall housing with nearby sand separators and lagoons for waste management. Emissions were calculated from the whole farm including the barns and any waste management components (lagoons and sand separators), and from these components alone when possible. During winter, the lagoons' NH3 emissions were very low and not measurable. During autumn and summer, whole-farm emissions were significantly larger than during winter, with about two-thirds of the total emissions originating from the waste management systems. The mean whole-farm NH3 emissions in winter, autumn, and summer were 1.5, 7.5, and 13.7% of feed N inputs emitted as NH3-N, respectively. Average annual emission comparisons on a unit basis between the 3 farms were similar at 7.0, 7.5, and 8.4% of input feed N emitted as NH3-N, with an annual average for all 3 farms of 7.6 +/- 1.5%. These winter, summer, autumn, and average annual NH3 emissions are considerably smaller than currently used estimates for dairy farms, and smaller than emissions from other types of animal-feeding operations.

  18. Historical evaluation of vehicle emission control in Guangzhou based on a multi-year emission inventory

    NASA Astrophysics Data System (ADS)

    Zhang, Shaojun; Wu, Ye; Liu, Huan; Wu, Xiaomeng; Zhou, Yu; Yao, Zhiliang; Fu, Lixin; He, Kebin; Hao, Jiming

    2013-09-01

    The Guangzhou government adopted many vehicle emission control policies and strategies during the five-year preparation (2005-2009) to host the 2010 Asian Games. This study established a multi-year emission inventory for vehicles in Guangzhou during 2005-2009 and estimated the uncertainty in total vehicle emissions by taking the assumed uncertainties in fleet-average emission factors and annual mileage into account. In 2009, the estimated total vehicle emissions in Guangzhou were 313 000 (242 000-387 000) tons of CO, 60 900 (54 000-70 200) tons of THC, 65 600 (56 800-74 100) tons of NOx and 2740 (2100-3400) tons of PM10. Vehicle emissions within the urban area of Guangzhou were estimated to be responsible for ˜40% of total gaseous pollutants and ˜25% of total PM10 in the entire city. Although vehicle use intensity increased rapidly in Guangzhou during 2005-2009, vehicle emissions were estimated to have been reduced by 12% for CO, 21% for THC and 20% for PM10 relative to those in 2005. NOx emissions were estimated to have remained almost constant during this period. Compared to the "without control" scenario, 19% (15%-23%) of CO, 20% (18%-23%) of THC, 9% (8%-10%) of NOx and 16% (12%-20%) of PM10 were estimated to have been mitigated from a combination of the implementation of Euro III standards for light-duty vehicles (LDVs) and heavy-duty diesel vehicles and improvement of fuel quality. This study also evaluated several enhanced vehicle emission control actions taken recently. For example, the enhanced I/M program for LDVs was estimated to reduce 11% (9%-14%) of CO, 9% (8%-10%) of THC and 2% (2%-3%) of NOx relative to total vehicle emissions in 2009. Total emission reductions by temporary traffic controls for the Asian Games were estimated equivalent to 9% (7%-11%) of CO, 9% (8%-10%) of THC, 5% (5%-6%) of NOx and 10% (8%-13%) of PM10 estimated total vehicle emissions in 2009. Those controls are essential to further vehicle emission mitigation in Guangzhou

  19. 12 CFR Appendix L to Part 226 - Assumed Loan Periods for Computations of Total Annual Loan Cost Rates

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Annual Loan Cost Rates L Appendix L to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED) BOARD OF GOVERNORS OF THE FEDERAL RESERVE SYSTEM TRUTH IN LENDING (REGULATION Z) Pt. 226, App. L Appendix L to Part 226—Assumed Loan Periods for Computations of Total Annual Loan Cost Rates (a) Required...

  20. Forest carbon in North America: annual storage and emissions from British Columbia’s harvest, 1965–2065

    PubMed Central

    2012-01-01

    Background The default international accounting rules estimate the carbon emissions from forest products by assuming all harvest is immediately emitted to the atmosphere. This makes it difficult to assess the greenhouse gas (GHG) consequences of different forest management or manufacturing activities that maintain the storage of carbon. The Intergovernmental Panel on Climate Change (IPCC) addresses this issue by allowing other accounting methods. The objective of this paper is to provide a new model for estimating annual stock changes of carbon in harvested wood products (HWP). Results The model, British Columbia Harvested Wood Products version 1 (BC-HWPv1), estimates carbon stocks and fluxes for wood harvested in BC from 1965 to 2065, based on new parameters on local manufacturing, updated and new information for North America on consumption and disposal of wood and paper products, and updated parameters on methane management at landfills in the USA. Based on model results, reporting on emissions as they occur would substantially lower BC’s greenhouse gas inventory in 2010 from 48 Mt CO2 to 26 Mt CO2 because of the long-term forest carbon storage in-use and in the non-degradable material in landfills. In addition, if offset projects created under BC’s protocol reported 100 year cumulative emissions using the BC-HWPv1 the emissions would be lower by about 11%. Conclusions This research showed that the IPCC default methods overestimate the emissions North America wood products. Future IPCC GHG accounting methods could include a lower emissions factor (e.g. 0.52) multiplied by the annual harvest, rather than the current multiplier of 1.0. The simulations demonstrated that the primary opportunities for climate change mitigation are in shifting from burning mill waste to using the wood for longer-lived products. PMID:22828161

  1. 29 CFR 779.253 - What is included in computing the total annual inflow volume.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... FAIR LABOR STANDARDS ACT AS APPLIED TO RETAILERS OF GOODS OR SERVICES Employment to Which the Act May... taxes and other charges which the enterprise must pay for such goods. Generally, all charges will be... computing the total annual inflow volume. The goods which the establishment purchases or receives for resale...

  2. 7th Annual NASA/Contractors Conference on Quality and Productivity: "Total Quality Leadership"

    NASA Technical Reports Server (NTRS)

    1991-01-01

    More than 750 NASA, government, contractor, and academic representatives attended the Seventh Annual NASA/Contractors Conference on Quality and Productivity on October 12-13, 1990, in Grenelefe, Florida. The panel presentations and keynote speeches revolving around the theme of 'Total Quality Leadership' provided a solid base of understanding of the importance, benefits, and principles of total quality management. The implementation of these strategies is critical if we are to effectively pursue our mission of continuous quality improvement and reliability in our products, processess, and services. The annual NASA/contractors conferences serve as catalysts for achieving success in this mission. The conference was highlighted by the announcement of the first recipients of the George M. Low Trophy: NASA's Quality and Excellence Award. My congratulations go out to all nine finalist organizations and to the two recipients of this prestigious honor: Rockwell Space Systems Division and Marotta Scientific Controls, Inc. (the first small business to achieve this honor). These organizations have demonstrated a commitment to quality that is unsurpassed in the aerospace industry. This report summarizes the presentations and is not intended to be a verbatim proceedings document. You are encouraged to contact the speakers with any requests for further information.

  3. A Comparison of Anthropogenic Carbon Dioxide Emissions Datasets: UND and CDIAC

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Andres, R. J.

    2005-05-01

    Using data from the Department of Energy's Energy Information Administration (EIA), a technique is developed to estimate the monthly consumption of solid, liquid and gaseous fossil fuels for each state in the union. This technique employs monthly sales data to estimate the relative monthly proportions of the total annual carbon dioxide emissions from fossil-fuel use for all states in the union. The University of North Dakota (UND) results are compared to those published by Carbon Dioxide Information Analysis Center (CDIAC) at the Oak Ridge National Laboratory (ORNL). Recently, annual emissions per U.S. state (Blasing, Broniak, Marland, 2004a) as well as monthly CO2 emissions for the United States (Blasing, Broniak, Marland, 2004b) have been added to the CDIAC website. To determine the success of this technique, the individual state results are compared to the annual state totals calculated by CDIAC. In addition, the monthly country totals are compared with those produced by CDIAC. In general, the UND technique produces estimates that are consistent with those available on the CDIAC Trends website. Comparing the results from these two methods permits an improved understanding of the strengths and shortcomings of both estimation techniques. The primary advantages of the UND approach are its ease of implementation, the improved spatial and temporal resolution it can produce, and its universal applicability.

  4. Modeling Seasonality in Carbon Dioxide Emissions From Fossil Fuel Consumption

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Andres, R. J.

    2004-05-01

    Using United States data, a method is developed to estimate the monthly consumption of solid, liquid and gaseous fossil fuels using monthly sales data to estimate the relative monthly proportions of the total annual national fossil fuel use. These proportions are then used to estimate the total monthly carbon dioxide emissions for each state. From these data, the goal is to develop mathematical models that describe the seasonal flux in consumption for each type of fuel, as well as the total emissions for the nation. The time series models have two components. First, the general long-term yearly trend is determined with regression models for the annual totals. After removing the general trend, two alternatives are considered for modeling the seasonality. The first alternative uses the mean of the monthly proportions to predict the seasonal distribution. Because the seasonal patterns are fairly consistent in the United States, this is an effective modeling technique. Such regularity, however, may not be present with data from other nations. Therefore, as a second alternative, an ordinary least squares autoregressive model is used. This model is chosen for its ability to accurately describe dependent data and for its predictive capacity. It also has a meaningful interpretation, as each coefficient in the model quantifies the dependency for each corresponding time lag. Most importantly, it is dynamic, and able to adapt to anomalies and changing patterns. The order of the autoregressive model is chosen by the Akaike Information Criterion (AIC), which minimizes the predicted variance for all models of increasing complexity. To model the monthly fuel consumption, the annual trend is combined with the seasonal model. The models for each fuel type are then summed together to predict the total carbon dioxide emissions. The prediction error is estimated with the root mean square error (RMSE) from the actual estimated emission values. Overall, the models perform very well

  5. TOTAL PARTICLE, SULFATE, AND ACIDIC AEROSOL EMISSIONS FROM KEROSENE SPACE HEATERS

    EPA Science Inventory

    Chamber studies were conducted on four unvented kerosene space heaters to assess emissions of total particle, sulfate, and acidic aerosol. The heaters tested represented four burner designs currently in use by the public. Kerosene space heaters are a potential source of fine part...

  6. Implications of emission inventory choice for modeling fire-related pollution in the U.S. (2017 CMAS)

    EPA Science Inventory

    Fires are a major source of fine particulate matter (PM2.5), one of the most harmful ambient pollutants for human health globally. Within the U.S., fire emissions can account for more than 30% of total PM2.5 emissions annually. In order to represent the influence of fire emission...

  7. Identifying potential exposure reduction priorities using regional rankings based on emissions of known and suspected carcinogens to outdoor air in Canada.

    PubMed

    Setton, Eleanor M; Veerman, Basil; Erickson, Anders; Deschenes, Steeve; Cheasley, Roz; Poplawski, Karla; Demers, Paul A; Keller, C Peter

    2015-08-22

    Emissions inventories aid in understanding the sources of hazardous air pollutants and how these vary regionally, supporting targeted reduction actions. Integrating information on the relative toxicity of emitted pollutants with respect to cancer in humans helps to further refine reduction actions or recommendations, but few national programs exist in North America that use emissions estimates in this way. The CAREX Canada Emissions Mapping Project provides key regional indicators of emissions (total annual and total annual toxic equivalent, circa 2011) of 21 selected known and suspected carcinogens. The indicators were calculated from industrial emissions reported to the National Pollutant Release Inventory (NPRI) and estimates of emissions from transportation (airports, trains, and car and truck traffic) and residential heating (oil, gas and wood), in conjunction with human toxicity potential factors. We also include substance-specific annual emissions in toxic equivalent kilograms and annual emissions in kilograms, to allow for ranking substances within any region. For provinces and territories in Canada, the indicators suggest the top five substances contributing to the total toxic equivalent emissions in any region could be prioritized for further investigation. Residents of Quebec and New Brunswick may be more at risk of exposure to industrial emissions than those in other regions, suggesting that a more detailed study of exposure to industrial emissions in these provinces is warranted. Residential wood smoke may be an important emission to control, particularly in the north and eastern regions of Canada. Residential oil and gas heating, along with rail emissions contribute little to regional emissions and therefore may not be an immediate regional priority. The developed indicators support the identification of pollutants and sources for additional investigation when planning exposure reduction actions among Canadian provinces and territories, but have

  8. Estimation of Nitrous Oxide Emissions from US Grasslands.

    PubMed

    Mummey; Smith; Bluhm

    2000-02-01

    / Nitrous oxide (N(2)O) emissions from temperate grasslands are poorly quantified and may be an important part of the atmospheric N(2)O budget. In this study N(2)O emissions were simulated for 1052 grassland sites in the United States using the NGAS model of Parton and others (1996) coupled with an organic matter decomposition model. N(2)O flux was calculated for each site using soil and land use data obtained from the National Resource Inventory (NRI) database and weather data obtained from NASA. The estimates were regionalized based upon temperature and moisture isotherms. Annual N(2)O emissions for each region were based on the grassland area of each region and the mean estimated annual N(2)O flux from NRI grassland sites in the region. The regional fluxes ranged from 0.18 to 1.02 kg N(2)O N/ha/yr with the mean flux for all regions being 0.28 kg N(2)O N/ha/yr. Even though fluxes from the western regions were relatively low, these regions made the largest contribution to total emissions due to their large grassland area. Total US grassland N(2)O emissions were estimated to be about 67 Gg N(2)O N/yr. Emissions from the Great Plains states, which contain the largest expanse of natural grassland in the United States, were estimated to average 0.24 kg N(2)O N/ha/yr. Using the annual flux estimate for the temperate Great Plains, we estimate that temperate grasslands worldwide may potentially produce 0.27 Tg N(2)O N/yr. Even though our estimate for global temperate grassland N(2)O emissions is less than published estimates for other major temperate and tropical biomes, our results indicate that temperate grasslands are a significant part of both United States and global atmospheric N(2)O budgets. This study demonstrates the utility of models for regional N(2)O flux estimation although additional data from carefully designed field studies is needed to further validate model results.

  9. [Estimation of carbonaceous gases emission from forest fires in Xiao Xing'an Mountains of Northeast China in 1953-2011].

    PubMed

    Hu, Hai-Qing; Luo, Bi-Zhen; Wei, Shu-Jing; Sun, Long; Wei, Shu-Wei; Wen, Zheng-Min

    2013-11-01

    Based on the forest resources investigation data and the forest fire inventory in 1953-2011, in combining with our field research in burned areas and our laboratory experiments, this paper estimated the carbonaceous gases carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), and nonmethane hydrocarbons (NMHC) emission from the forest fires in Xiao Xing' an Mountains of Heilongjiang Province, Northeast China in 1953-2011. The total carbon emission from the forest fires in the Xiao Xing'an Mountains in 1953-2011 was 1.12 x 10(7) t, and the annual emission was averagely 1.90 x10(5) t, accounting for 1.7% of the annual average total carbon emission from the forest fires in China. The emission of CO2, CO, CH4, and NMHC was 3.39 x 10(7), 1.94 x 10(5), 1.09 x 10(5), and 7.46 x 10(4) t, respectively, and the corresponding annual average emission was 5.74 x 10(5), 3.29 x 10(4), 1.85 x 10(3), and 1.27 x 10(3) t, accounting for 1.4%, 1.2%, 1.7%, and 1.1% of the annual carbonaceous gases emitted from the forest fires in China, respectively. The combustion efficiency and the carbon emission per unit burned area of different forest types decreased in order of coniferous forest > broad-leaved forest > coniferous broadleaved mixed forest. Some rational forest fire management measures were put forward.

  10. 77 FR 44488 - Method 16C for the Determination of Total Reduced Sulfur Emissions From Stationary Sources

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-30

    ... Method 16C for the Determination of Total Reduced Sulfur Emissions From Stationary Sources AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: This action promulgates Method 16C for measuring total reduced sulfur (TRS) emissions from stationary sources. Method 16C offers the advantages of...

  11. 77 FR 62396 - Annual Company-Run Stress Test Requirements for Banking Organizations With Total Consolidated...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-12

    ... in the stress test, for each quarter of the planning horizon, aggregate losses, pre-provision net... Company-Run Stress Test Requirements for Banking Organizations With Total Consolidated Assets Over $10... regulatory agency to conduct stress tests on an annual basis. The Board is adopting this final rule to...

  12. Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotope Signature (DB1013, V. 2016)

    DOE Data Explorer

    Andres, R. J. [CDIAC, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [CDIAC, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [Appalachian State University, Boone, NC (USA)

    2016-01-01

    The 2016 revision of this database contains estimates of the annual, global mean value of δ 13C of CO2 emissions from fossil-fuel consumption and cement manufacture for 1751-2013. These estimates of the carbon isotopic signature account for the changing mix of coal, petroleum, and natural gas being consumed and for the changing mix of petroleum from various producing areas with characteristic isotopic signatures. This time series of global fossil-fuel del 13C signature provides an additional constraint for balancing the sources and sinks of the global carbon cycle and complements the atmospheric δ 13C measurements that are used to partition the uptake of fossil carbon emissions among the ocean, atmosphere, and terrestrial biosphere reservoirs.

  13. Anthropogenic atmospheric nickel emissions and its distribution characteristics in China.

    PubMed

    Tian, H Z; Lu, L; Cheng, K; Hao, J M; Zhao, D; Wang, Y; Jia, W X; Qiu, P P

    2012-02-15

    Nickel and its compounds are considered as potential human carcinogens, and atmospheric nickel is one of the major routes for human exposure. By applying the best available fuel-based or product-based emission factors and annual activity levels, a multiple-year comprehensive inventory of anthropogenic atmospheric nickel emissions in China is presented with temporal trend and spatial resolutions for the period of 1980-2009 from both fuels combustion sources and industrial producing processes. We estimate that the total atmospheric nickel emissions from all the sources have increased from 1096.07 t in 1980 to 3933.71 t in 2009, at an average annual growth rate of 4.5%. Therein, coal combustion is the leading source, attributing 63.4% of the national total nickel emissions in 2009; liquid fuels consumption ranks the second, contributing 12.4% of the totals; biofuels burning accounts for 8.4% and the remaining sources together contribute 15.8% of the totals. Significant spatial variations are demonstrated among provincial emissions and the most concentrated regions are the highly industrialized and densely populated areas like the Yangtze River Delta, the Pearl River Delta and the Beijing-Tianjin-Hebei region. Moreover, the overall uncertainties are estimated at -32.6%-37.7% by using Monte Carlo simulation, most of which come from non-ferrous metals smelting category, implying the urgent need for further investigation and field tests. This article may help to combat the increasing stress on air heavy metals pollution in China and provide useful information to calculate global mass balance models for hazardous trace elements. Copyright © 2011 Elsevier B.V. All rights reserved.

  14. Emissions from miombo woodland and dambo grassland savanna fires

    NASA Astrophysics Data System (ADS)

    Sinha, Parikhit; Hobbs, Peter V.; Yokelson, Robert J.; Blake, Donald R.; Gao, Song; Kirchstetter, Thomas W.

    2004-06-01

    Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in Zambia are described. The measurements include profiles through the smoke plumes of condensation nucleus concentrations and normalized excess mixing ratios of particles and gases, emission factors for 42 trace gases and seven particulate species, and vertical profiles of ambient conditions. The fires were ignited in plots of miombo woodland savanna, the most prevalent savanna type in southern Africa, and dambo grassland savanna, an important enclave of miombo woodland ecosystems. Emission factors for the two fires are combined with measurements of fuel loading, combustion factors, and burned area (derived from satellite burn scar retrievals) to estimate the emissions of trace gases and particles from woodland and grassland savanna fires in Zambia and southern Africa during the dry season (May-October) of 2000. It is estimated that the emissions of CO2, CO, total hydrocarbons, nitrogen oxides (NOx as NO), sulfur dioxide (SO2), formaldehyde, methyl bromide, total particulate matter, and black carbon from woodland and grassland savanna fires during the dry season of 2000 in southern Africa contributed 12.3%, 12.6%, 5.9%, 10.3%, 7.5%, 24.2%, 2.8%, 17.5%, and 11.1%, respectively, of the average annual emissions from all types of savanna fires worldwide. In 2000 the average annual emissions of methane, ethane, ethene, acetylene, propene, formaldehyde, methanol, and acetic acid from the use of biofuels in Zambia were comparable to or exceeded dry season emissions of these species from woodland and grassland savanna fires in Zambia.

  15. Emissions from Miombo Woodland and Dambo Grassland Savanna Fires

    NASA Technical Reports Server (NTRS)

    Sinha, Parikhit; Hobbs, Peter V.; Yokelson, Robert J.; Blake, Donald R.; Gao, Song; Kirchstetter, Thomas W.

    2004-01-01

    Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in Zambia are described. The measurements include profiles through the smoke plumes of condensation nucleus concentrations and normalized excess mixing ratios of particles and gases, emission factors for 42 trace gases and seven particulate species, and vertical profiles of ambient conditions. The fires were ignited in plots of miombo woodland savanna, the most prevalent savanna type in southern Africa, and dambo grassland savanna, an important enclave of miombo woodland ecosystems. Emission factors for the two fires are combined with measurements of fuel loading, combustion factors, and burned area (derived from satellite burn scar retrievals) to estimate the emissions of trace gases and particles from woodland and grassland savanna fires in Zambia and southern Africa during the dry season (May-October) of 2000. It is estimated that the emissions of CO2, CO, total hydrocarbons, nitrogen oxides (NOx as NO), sulfur dioxide (SO2), formaldehyde, methyl bromide, total particulate matter, and black carbon from woodland and grassland savanna fires during the dry season of 2000 in southern Africa contributed 12.3%, 12.6%, 5.9%, 10.3%, 7.5%, 24.2%, 2.8%, 17.5%, and 11.1%, respectively, of the average annual emissions from all types of savanna fires worldwide. In 2000 the average annual emissions of methane, ethane, ethene, acetylene, propene, formaldehyde, methanol, and acetic acid from the use of biofuels in Zambia were comparable to or exceeded dry season emissions of these species from woodland and grassland savanna fires in Zambia.

  16. Real-World Emission Factors of Gaseous and Particulate Pollutants from Marine Fishing Boats and Their Total Emissions in China.

    PubMed

    Zhang, Fan; Chen, Yingjun; Chen, Qi; Feng, Yanli; Shang, Yu; Yang, Xin; Gao, Huiwang; Tian, Chongguo; Li, Jun; Zhang, Gan; Matthias, Volker; Xie, Zhiyong

    2018-04-17

    Pollutants from fishing boats have generally been neglected worldwide, and there is an acute shortage of measured emission data, especially in China. Therefore, on-board measurements of pollutants emitted from 12 different fishing boats in China (including gill net, angling, and trawler boats) were carried out in this study to investigate emission factors (EFs), characteristics and total emissions. The average EFs for CO 2 , CO, NO x , PM, and SO 2 were 3074 ± 55.9, 50.6 ± 31.7, 54.2 ± 30.7, 9.54 ± 2.24, and 5.94 ± 6.38 g (kg fuel) -1 , respectively, which were higher than those from previous studies of fishing boats. When compared to medium-speed and slow-speed engine vessels, high-speed engines on fishing boats had higher CO EFs but lower NO x EFs. Notably, when fishing boats were in low-load conditions, they always had higher EFs of CO, PM, and NO 2 compared to other operating modes. The estimated results showed that emissions from motor-powered fishing boats in China in 2012 (232, 379, and 61.8 kt CO, NO x and PM) accounted for 10.7%, 10.9%, and 19.3% of the total CO, NO x and PM emitted from nonroad mobile sources, which means significant contribution of fishing boats to air pollution, especially in southern China areas.

  17. Aircraft-Based Estimate of Total Methane Emissions from the Barnett Shale Region.

    PubMed

    Karion, Anna; Sweeney, Colm; Kort, Eric A; Shepson, Paul B; Brewer, Alan; Cambaliza, Maria; Conley, Stephen A; Davis, Ken; Deng, Aijun; Hardesty, Mike; Herndon, Scott C; Lauvaux, Thomas; Lavoie, Tegan; Lyon, David; Newberger, Tim; Pétron, Gabrielle; Rella, Chris; Smith, Mackenzie; Wolter, Sonja; Yacovitch, Tara I; Tans, Pieter

    2015-07-07

    We present estimates of regional methane (CH4) emissions from oil and natural gas operations in the Barnett Shale, Texas, using airborne atmospheric measurements. Using a mass balance approach on eight different flight days in March and October 2013, the total CH4 emissions for the region are estimated to be 76 ± 13 × 10(3) kg hr(-1) (equivalent to 0.66 ± 0.11 Tg CH4 yr(-1); 95% confidence interval (CI)). We estimate that 60 ± 11 × 10(3) kg CH4 hr(-1) (95% CI) are emitted by natural gas and oil operations, including production, processing, and distribution in the urban areas of Dallas and Fort Worth. This estimate agrees with the U.S. Environmental Protection Agency (EPA) estimate for nationwide CH4 emissions from the natural gas sector when scaled by natural gas production, but it is higher than emissions reported by the EDGAR inventory or by industry to EPA's Greenhouse Gas Reporting Program. This study is the first to show consistency between mass balance results on so many different days and in two different seasons, enabling better quantification of the related uncertainty. The Barnett is one of the largest production basins in the United States, with 8% of total U.S. natural gas production, and thus, our results represent a crucial step toward determining the greenhouse gas footprint of U.S. onshore natural gas production.

  18. Greenhouse gas emission from the total process of swine manure composting and land application of compost

    NASA Astrophysics Data System (ADS)

    Zhong, Jia; Wei, Yuansong; Wan, Hefeng; Wu, Yulong; Zheng, Jiaxi; Han, Shenghui; Zheng, Bofu

    2013-12-01

    Greenhouse gas (GHG) emissions from animal manure management are of great concern in China. However, there are still great uncertainties about China's GHG inventory due to the GHG emission factors partly used default values from the Intergovernmental Panel of Climate Change (IPCC) guidelines. The purpose of this study was to use a case study in Beijing to determine the regional GHG emission factors based on the combination of swine manure composting and land application of the compost with both on-site examination and a life cycle assessment (LCA). The results showed that the total GHG emission factor was 240 kgCO2eq tDS-1 (dry solids), including the direct GHG emission factor of 115 kgCO2eq tDS-1 for swine manure composting and 48 kgCO2eq tDS-1 for land application of the compost. Among the total GHG emissions of 5.06 kgCH4 tDS-1 and 0.13 kgN2O tDS-1, the swine manure composting contributed approximately 89% to CH4 emissions while land application accounted for 92% of N2O emission. Meanwhile, the GHG emission profile from the full process in Beijing in 2015 and 2020 was predicted by the scenario analysis. The composting and land application is a cost-effective way for animal manure management in China considering GHG emissions.

  19. Readily implementable techniques can cut annual CO2 emissions from the production of concrete by over 20%

    NASA Astrophysics Data System (ADS)

    Miller, Sabbie A.; Horvath, Arpad; Monteiro, Paulo J. M.

    2016-07-01

    Due to its prevalence in modern infrastructure, concrete is experiencing the most rapid increase in consumption among globally common structural materials; however, the production of concrete results in approximately 8.6% of all anthropogenic CO2 emissions. Many methods have been developed to reduce the greenhouse gas emissions associated with the production of concrete. These methods range from the replacement of inefficient manufacturing equipment to alternative binders and the use of breakthrough technologies; nevertheless, many of these methods have barriers to implementation. In this research, we examine the extent to which the increased use of several currently implemented methods can reduce the greenhouse gas emissions in concrete material production without requiring new technologies, changes in production, or novel material use. This research shows that, through increased use of common supplementary cementitious materials, appropriate selection of proportions for cement replacement, and increased concrete design age, 24% of greenhouse gas emissions from global concrete production or 650 million tonnes (Mt) CO2-eq can be eliminated annually.

  20. Annual Fossil-Fuel CO2 Emissions: Isomass of Emissions Gridded by One Degree Latitude by One Degree Longitude (V. 2015)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center Environmental Sciences Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830-6290 U.S.A.; Boden, T. A. [Carbon Dioxide Information Analysis Center Environmental Sciences Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830-6290 U.S.A.; Marland, G. [Appalachian State University, Boone, North Carolina (USA)

    2015-01-01

    The monthly, isotopic (δ 13C) fossil-fuel CO2 emissions estimates from 1950-2013 provided in this database are derived from time series of global, regional, and national fossil-fuel CO2 emissions (Boden et al. 2016), the references therein, and the methodology described in Andres et al. (2011). The data accessible here take these tabular, national, mass-emissions data, multiply them by stable carbon isotopic signatures (δ 13C) as described in Andres et al. (2000), and distribute them spatially on a one degree latitude by one degree longitude grid. The within-country spatial distribution is achieved through a fixed population distribution as reported in Andres et al. (1996). Note that the mass-emissions data used here are based on fossil-fuel consumption estimates as these are more representative of within country emissions than fossil-fuel production estimates (see http://cdiac.ess-dive.lbl.gov/faq.html#Q10 for a description why emission totals based upon consumption differ from those based upon production).

  1. Annual Fossil-Fuel CO2 Emissions: Isomass of Emissions Gridded by One Degree latitude by One Degree Longitude (V. 2013)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center Environmental Sciences Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830-6290 U.S.A.; Boden, T. A. [Carbon Dioxide Information Analysis Center Environmental Sciences Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830-6290 U.S.A.; Marland, G. [Appalachian State University, Boone, North Carolina (USA).

    2013-01-01

    The monthly, isotopic (δ 13C) fossil-fuel CO2 emissions estimates from 1950-2013 provided in this database are derived from time series of global, regional, and national fossil-fuel CO2 emissions (Boden et al. 2016), the references therein, and the methodology described in Andres et al. (2011). The data accessible here take these tabular, national, mass-emissions data, multiply them by stable carbon isotopic signatures (δ 13C) as described in Andres et al. (2000), and distribute them spatially on a one degree latitude by one degree longitude grid. The within-country spatial distribution is achieved through a fixed population distribution as reported in Andres et al. (1996). Note that the mass-emissions data used here are based on fossil-fuel consumption estimates as these are more representative of within country emissions than fossil-fuel production estimates (see http://cdiac.ess-dive.lbl.gov/faq.html#Q10 for a description why emission totals based upon consumption differ from those based upon production).

  2. 78 FR 19262 - Notice of Annual Adjustment of the Cap on Average Total Assets That Defines Community Financial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-29

    ... FEDERAL HOUSING FINANCE AGENCY [No. 2013-N-04] Notice of Annual Adjustment of the Cap on Average.... ACTION: Notice. SUMMARY: The Federal Housing Finance Agency (FHFA) has adjusted the cap on average total... Federal Deposit Insurance Corporation and that has average total assets below a statutory cap.\\2\\ The Bank...

  3. Nitrous oxide emission inventory of German forest soils

    NASA Astrophysics Data System (ADS)

    Schulte-Bisping, Hubert; Brumme, Rainer; Priesack, Eckart

    2003-02-01

    Annual fluxes of N2O trace gas emissions were assessed after stratifying German forest soils into Seasonal Emission Pattern (SEP) and Background Emission Pattern (BEP). Broad-leaved forests with soil pH(KCl) ≤ 3.3 were assigned to have SEP, broad-leaved forests with soil pH(KCl) > 3.3 and all needle-leaved forests to have BEP. BEPs were estimated by a relationship between annual N2O emissions and carbon content of the O-horizon. SEPs were primarily controlled by temperature and moisture and simulated by the model Expert-N after calibration to a 9-year record of N2O measurements. Analysis with different climate and soil properties indicated that the model reacts highly sensitive to changes in soil temperature, soil moisture, and soil texture. A geographic information system (ARC/INFO) was used for a spatial resolution of 1 km × 1 km grid where land cover, dominant soil units, and hygro climate classes were combined. The mean annual N2O emission flux from German forest soils was estimated as 0.32 kg ha-1 yr-1. Broad-leaved forests with SEP had the highest emissions (2.05 kg ha-1 yr-1) followed by mixed forests (0.38 kg ha-1 yr-1), broad-leaved forests (0.37 kg ha-1 yr-1), and needle-leaved forests with BEP (0.17 kg ha-1 yr-1). The annual N2O emission from German forest soils was calculated as 3.26 Gg N2O-N yr-1. Although needle-leaved trees cover about 57% of the entire forest area in Germany, their contribution is low (0.96 Gg N2O-N yr-1). Broad-leaved forests cover about 22% of the forest area but have 55% higher emissions (1.49 Gg N2O-N yr-1) than needle-leaved. Mixed forests cover 21% of the area and contribute 0.81 Gg N2O-N yr-1. Compared to the total N2O emissions in Germany of 170 Gg N yr-1, forest soils contribute only 1.9%. However, there are some uncertainties in this emission inventory, which are intensely discussed.

  4. Novel Sampling Techniques for Measurement of Turbine Engine Total Particulate Matter Emissions

    EPA Science Inventory

    This is the first progress report of a study to evaluate two different condensation devices for the measurement of the total (volatile + non-volatile) particulate matter (PM) emissions from aircraft turbine engines by direct sampling at the engine exit. The characteristics of th...

  5. Temporalization of Electric Generation Emissions for Improved Representation of Peak Air Quality Episodes

    NASA Astrophysics Data System (ADS)

    Farkas, C. M.; Moeller, M.; Carlton, A. G.

    2013-12-01

    Photochemical transport models routinely under predict peak air quality events. This deficiency may be due, in part, to inadequate temporalization of emissions from the electric generating sector. The National Emissions Inventory (NEI) reports emissions from Electric Generating Units (EGUs) by either Continuous Emission Monitors (CEMs) that report hourly values or as an annual total. The Sparse Matrix Operator Kernel Emissions preprocessor (SMOKE), used to prepare emissions data for modeling with the CMAQ air quality model, allocates annual emission totals throughout the year using specific monthly, weekly, and hourly weights according to standard classification code (SCC) and location. This approach represents average diurnal and seasonal patterns of electricity generation but does not capture spikes in emissions due to episodic use as with peaking units or due to extreme weather events. In this project we use a combination of state air quality permits, CEM data, and EPA emission factors to more accurately temporalize emissions of NOx, SO2 and particulate matter (PM) during the extensive heat wave of July and August 2006. Two CMAQ simulations are conducted; the first with the base NEI emissions and the second with improved temporalization, more representative of actual emissions during the heat wave. Predictions from both simulations are evaluated with O3 and PM measurement data from EPA's National Air Monitoring Stations (NAMS) and State and Local Air Monitoring Stations (SLAMS) during the heat wave, for which ambient concentrations of criteria pollutants were often above NAAQS. During periods of increased photochemistry and high pollutant concentrations, it is critical that emissions are most accurately represented in air quality models.

  6. 40 CFR Table Jj-1 to Subpart Jj of... - Animal Population Threshold Level Below Which Facilities Are Not Required To Report Emissions...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Emissions Under Subpart JJ 1 2 Animal group Average annual animal population (Head) 3 Beef 29,300 Dairy 3... groups except dairy, the average annual animal population represents the total number of animals present at the facility. For dairy facilities, the average annual animal population represents the number of...

  7. 40 CFR Table Jj-1 to Subpart Jj of... - Animal Population Threshold Level Below Which Facilities Are Not Required To Report Emissions...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Emissions Under Subpart JJ 1,2 Animal group Average annual animal population (Head) 3 Beef 29,300 Dairy 3... groups except dairy, the average annual animal population represents the total number of animals present at the facility. For dairy facilities, the average annual animal population represents the number of...

  8. 75 FR 9601 - Notice of Annual Adjustment of the Cap on Average Total Assets That Defines Community Financial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-03

    ... FEDERAL HOUSING FINANCE AGENCY [No. 2010-N-01] Notice of Annual Adjustment of the Cap on Average.... ACTION: Notice. SUMMARY: The Federal Housing Finance Agency (FHFA) has adjusted the cap on average total... Deposit Insurance Corporation and that has average total assets below a statutory cap. See 12 U.S.C. 1422...

  9. Seasonal and interannual variations in whole-ecosystem BVOC emissions from a subtropical plantation in China

    NASA Astrophysics Data System (ADS)

    Bai, Jianhui; Guenther, Alex; Turnipseed, Andrew; Duhl, Tiffany; Greenberg, James

    2017-07-01

    Measurements of BVOC emissions, ozone concentration and environmental parameters were carried out from May 2013 to January 2016 in a subtropical Pinus plantation in China. Isoprene and monoterpene emissions were measured using a relaxed eddy accumulation (REA) system and a gradient technique on an above-canopy tower. In 2013, isoprene comprised 21.2% of total terpenoid emissions, while α-pinene, camphene, β-pinene and limonene constituting 51.5%, 2.4%, 9.1%, and 13.0% of total emissions, respectively. Monoterpenes together were the dominant VOCs measured contributing 71.6%. α-pinene, camphene, β-pinene and limonene constituted 67.7%, 3.2%, 11.9%, 17.2% of total monoterpene emissions. Isoprene and monoterpene emissions displayed strong diurnal variations, with lower emissions in the morning and late evening, and the highest emissions around noon. BVOC peak emissions typically occurred a few hours after the noon PAR peak. Isoprene and monoterpene emissions varied with season and were the highest in summer, contributing more than half of the total annual emission, and the lowest emissions were in winter. Evident interannual variations of isoprene, monoterpenes and total BVOCs were observed. Compared to 2013, annual BVOC emissions decreased in 2015, associated with decreases of PAR, Temperature, water vapor, and an increase of all substances in gas, liquid and solid phases in the atmospheric column (e.g., S/Q, the ratio of solar scattered radiation to global radiation). Ozone concentration showed clear diurnal variation with PAR, higher around noon and lower in the early morning and late evening. Generally, there were no evident correlations between ozone concentrations and BVOC emissions, or the vertical gradients of ozone concentrations and BVOC concentrations. Under all sky conditions (including cloudy skies), no strong correlations at a high confidence level or very similar variation patterns were observed between any two following parameters, BVOC emissions

  10. 76 FR 3142 - Notice of Annual Adjustment of the Cap on Average Total Assets That Defines Community Financial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-19

    ... FEDERAL HOUSING FINANCE AGENCY [No. 2011-N-01] Notice of Annual Adjustment of the Cap on Average.... ACTION: Notice. SUMMARY: The Federal Housing Finance Agency (FHFA) has adjusted the cap on average total... average total assets below a statutory cap. See 12 U.S.C. 1422(10)(A); 12 CFR 1263.1. The Bank Act was...

  11. Carbon emissions from spring 1998 fires in tropical Mexico

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cairns, M.A.; Hao, W.M.; Alvarado, E.

    1999-04-01

    The authors used NOAA-AVHRR satellite imagery, biomass density maps, fuel consumption estimates, and a carbon emission factor to estimate the total carbon (C) emissions from the Spring 1998 fires in tropical Mexico. All eight states in southeast Mexico were affected by the wildfires, although the activity was concentrated near the common border of Oaxaca, Chiapas, and Veracruz. The fires burned approximately 482,000 ha and the land use/land cover classes most extensively impacted were the tall/medium selvas (tropical evergreen forests), open/fragmented forests, and perturbed areas. The total prompt emissions were 4.6 TgC during the two-month period of the authors` study, contributingmore » an additional 24% to the region`s average annual net C emissions from forestry and land-use change. Mexico in 1998 experienced its driest Spring since 1941, setting the stage for the widespread burning.« less

  12. Urban stress-induced biogenic VOC emissions impact secondary aerosol formation in Beijing

    NASA Astrophysics Data System (ADS)

    Ghirardo, A.; Xie, J.; Zheng, X.; Wang, Y.; Grote, R.; Block, K.; Wildt, J.; Mentel, T.; Kiendler-Scharr, A.; Hallquist, M.; Butterbach-Bahl, K.; Schnitzler, J.-P.

    2015-08-01

    Trees can significantly impact the urban air chemistry by the uptake and emission of reactive biogenic volatile organic compounds (BVOCs), which are involved in ozone and particle formation. Here we present the emission potentials of "constitutive" (cBVOCs) and "stress-induced" BVOCs (sBVOCs) from the dominant broadleaf woody plant species in the megacity of Beijing. Based on an inventory of BVOC emissions and the tree census, we assessed the potential impact of BVOCs on secondary particulate matter formation in 2005 and 2010, i.e., before and after realizing the large tree-planting program for the 2008 Olympic Games. We found that sBVOCs, such as fatty acid derivatives, benzenoids and sesquiterpenes, constituted a significant fraction (∼ 15 %) of the total annual BVOC emissions, and we estimated that the overall annual BVOC budget may have doubled from ∼ 3.6 × 109 g C year-1 in 2005 to ∼ 7.1 × 109 g C year-1 in 2010 due to the increase in urban greens, while at the same time, the emission of anthropogenic VOCs (AVOCs) could be lowered by 24 %. Based on our BVOC emission assessment, we estimated the biological impact on SOA mass formation in Beijing. Compared to AVOCs, the contribution of biogenic precursors (2-5 %) for secondary particulate matter in Beijing was low. However, sBVOCs can significantly contribute (∼ 40 %) to the formation of total secondary organic aerosol (SOA) from biogenic sources; apparently, their annual emission increased from 1.05 μg m-3 in 2005 to 2.05 μg m-3 in 2010. This study demonstrates that biogenic and, in particular, sBVOC emissions contribute to SOA formation in megacities. However, the main problems regarding air quality in Beijing still originate from anthropogenic activities. Nevertheless, the present survey suggests that in urban plantation programs, the selection of plant species with low cBVOC and sBVOC emission potentials have some possible beneficial effects on urban air quality.

  13. Total sulfur dioxide emissions and pre-eruption vapor-saturated magma at Mount St. Helens, 1980-88

    NASA Astrophysics Data System (ADS)

    Gerlach, T. M.; McGee, K. A.

    1994-12-01

    SO2 from explosive volcanism can cause significant climatic and atmospheric impacts, but the source of the sulfur is controversial. Total ozone mapping spectrometer (TOMS), correlation spectrometer (COSPEC), and ash leachate data for Mount St. Helens from the time of the climactic eruption on 18 May 1980 to the final stages of non-explosive degassing in 1988 give a total SO2 emission of 2 Mt. COSPEC data show a sharp drop in emission rate that was apparently controlled by a decreasing rate of magma supply. A total SO2 emission of only 0.08 Mt is estimated from melt inclusion data and the conventional assumption that the main sulfur source was pre-eruption melt; commonly invoked sources of 'excess sulfur' (anhydrite decomposition, basaltic magma, and degassing of non-erupted magma) are unlikely in this case. Thus melt inclusions may significantly underestimate SO2 emissions and impacts of explosive volcanism on climate and the atmosphere. Measured CO2 emissions, together with the H2O content of melt inclusions and experimental solubility data, indicate the Mount St. Helens dacite was vapor-saturated at depth prior to ascent and suggest that a vapor phase was the main source of sulfur for the 2-Mt of SO2. A vapor source is consistent with experimental studies on the Mount St. Helens dacite and removes the need for a much debated shallow magma body.

  14. Inter-annual variability and trend detection of urban CO2, CH4 and CO emissions

    NASA Astrophysics Data System (ADS)

    Lauvaux, T.; Deng, A.; Gurney, K. R.; Nathan, B.; Ye, X.; Oda, T.; Karion, A.; Hardesty, M.; Harvey, R. M.; Richardson, S.; Whetstone, J. R.; Hutyra, L.; Davis, K. J.; Brewer, A.; Gaudet, B. J.; Turnbull, J. C.; Sweeney, C.; Shepson, P. B.; Miles, N.; Bonin, T.; Wu, K.; Balashov, N. V.

    2017-12-01

    The Indianapolis Flux (INFLUX) Experiment has conducted an unprecedented volume of atmospheric greenhouse gas measurements across the Indianapolis metropolitan area from aircraft, remote-sensing, and tower-based observational platforms. Assimilated in a high-resolution urban inversion system, atmospheric data provide an independent constraint to existing emission products, directly supporting the integration of economic data into urban emission systems. We present here the first multi-year assessment of carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) emissions from anthropogenic activities in comparison to multiple bottom-up emission products. Biogenic CO2 fluxes are quantified using an optimized biogeochemical model at high resolution, further refined within the atmospheric inversion system. We also present the first sector-based inversion by jointly assimilating CO2 and CO mixing ratios to quantify the dominant sectors of emissions over the entire period (2012-2015). The detected trend in CO2 emissions over 2012-2015 from both bottom-up emission products and tower-based inversions agree within a few percent, with a decline in city emissions over the 3-year time period. Major changes occur at the primary power plant, suggesting a decrease in energy production within the city limits. The joint assimilation of CO2 and CO mixing ratios confirms the absence of trends in other sectors. However, top-down and bottom-up approaches tend to disagree annually, with a decline in urban emissions suggested by atmospheric data in 2014 that is several months earlier than is observed in the bottom-up products. Concerning CH4 emissions, the inversion shows a decrease since mid-2014 which may be due to lower landfill emissions or lower energy consumption (from coal and natural gas). This first demonstration of a high-accuracy long-term greenhouse gas measurement network merged with a high-resolution bottom-up information system highlights the potential for informing

  15. Determining national greenhouse gas emissions from waste-to-energy using the Balance Method.

    PubMed

    Schwarzböck, Therese; Rechberger, Helmut; Cencic, Oliver; Fellner, Johann

    2016-03-01

    Different directives of the European Union require operators of waste-to-energy (WTE) plants to report the amount of electricity that is produced from biomass in the waste feed, as well as the amount of fossil CO2 emissions generated by the combustion of fossil waste materials. This paper describes the application of the Balance Method for determining the overall amount of fossil and thus climate relevant CO2 emissions from waste incineration in Austria. The results of 10 Austrian WTE plants (annual waste throughput of around 2,300 kt) demonstrate large seasonal variations in the specific fossil CO2 emissions of the plants as well as large differences between the facilities (annual means range from 32±2 to 51±3 kg CO(2,foss)/GJ heating value). An overall amount of around 924 kt/yr of fossil CO2 for all 10 WTE plants is determined. In comparison biogenic (climate neutral) CO2 emissions amount to 1,187 kt/yr, which corresponds to 56% of the total CO2 emissions from waste incineration. The total energy input via waste feed to the 10 facilities is about 22,500 TJ/yr, of which around 48% can be assigned to biogenic and thus renewable sources. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. 40 CFR 89.125 - Production engines, annual report.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Production engines, annual report. 89... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE NONROAD COMPRESSION-IGNITION ENGINES Emission Standards and Certification Provisions § 89.125 Production engines, annual report. (a) Upon the Administrator's...

  17. 40 CFR 89.125 - Production engines, annual report.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Production engines, annual report. 89... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE NONROAD COMPRESSION-IGNITION ENGINES Emission Standards and Certification Provisions § 89.125 Production engines, annual report. (a) Upon the Administrator's...

  18. 40 CFR 89.125 - Production engines, annual report.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Production engines, annual report. 89... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE NONROAD COMPRESSION-IGNITION ENGINES Emission Standards and Certification Provisions § 89.125 Production engines, annual report. (a) Upon the Administrator's...

  19. 40 CFR 89.125 - Production engines, annual report.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Production engines, annual report. 89... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE NONROAD COMPRESSION-IGNITION ENGINES Emission Standards and Certification Provisions § 89.125 Production engines, annual report. (a) Upon the Administrator's...

  20. Have the annual trends of total knee arthroplasty in ankylosing spondylitis patients decreased?

    PubMed Central

    Abraham, Roby; Kelly, John J.; Newman, Jared M.; Naziri, Qais; Sodhi, Nipun; Khlopas, Anton; George, Jaiben; Shah, Neil V.; Sultan, Assem A.; Chughtai, Morad; Barrington, John W.; Paulino, Carl B.

    2017-01-01

    Background Ankylosing spondylitis (AS) is characterized by osteoproliferation-induced structural damage and spinal inflammation, which lead to spinal deformity and functional disability. Though AS commonly affects the axial skeleton and sacroiliac joints, up to 70% of patients have involvement of the knees and other joints. Despite pharmacological efforts, advancing joint involvement may ultimately require surgical intervention. Total knee arthroplasty (TKA) is effective in managing patients with AS, yet it remains unclear whether or not the annual rates of TKA have been affected. Therefore, the purpose of this study was to evaluate the annual trends of AS patients who underwent TKA. Specifically, we evaluated: (I) the annual trends of TKAs due to AS in the United States population; (II) the annual trends in the proportion of TKAs due to AS in the United States. Methods The Nationwide Inpatient Sample (NIS) was used to identify all patients who underwent TKA between 2002 and 2013 (n=6,492,873). Then, a subsequent query was performed to identify TKA patients who had a diagnosis of AS, defined by the International Classification of Disease 9th revision diagnosis code 720.0. The incidence of TKAs with a diagnosis of AS in the United States was calculated using the United States population as the denominator. Regression models were used to analyze the annual trends of AS in patients who underwent TKA. Results During the study period, 2,986 patients who had AS who underwent TKA were identified. The annual number of TKAs with a diagnosis of AS increased by 168% from 125 to 335. After normalizing to the US population, the incidence of TKAs with AS increased from 0.58 to 1.38 TKAs per million US adults [IRR =1.08 (95% CI: 1.07–1.09), P<0.001]. Out of the 350,122 TKAs in 2002, 125 (0.04%) were due to AS, whereas, out of the 640,695 TKAs in 2013, 335 (0.05%) were due to AS. The prevalence of AS in those who underwent TKA increased from 2002 to 2013 [coefficient =0.002 (95

  1. Source Partitioning of Methane Emissions and its Seasonality in the U.S. Midwest

    NASA Astrophysics Data System (ADS)

    Chen, Zichong; Griffis, Timothy J.; Baker, John M.; Millet, Dylan B.; Wood, Jeffrey D.; Dlugokencky, Edward J.; Andrews, Arlyn E.; Sweeney, Colm; Hu, Cheng; Kolka, Randall K.

    2018-02-01

    The methane (CH4) budget and its source partitioning are poorly constrained in the Midwestern United States. We used tall tower (185 m) aerodynamic flux measurements and atmospheric scale factor Bayesian inversions to constrain the monthly budget and to partition the total budget into natural (e.g., wetlands) and anthropogenic (e.g., livestock, waste, and natural gas) sources for the period June 2016 to September 2017. Aerodynamic flux observations indicated that the landscape was a CH4 source with a mean annual CH4 flux of +13.7 ± 0.34 nmol m-2 s-1 and was rarely a net sink. The scale factor Bayesian inversion analyses revealed a mean annual source of +12.3 ± 2.1 nmol m-2 s-1. Flux partitioning revealed that the anthropogenic source (7.8 ± 1.6 Tg CH4 yr-1) was 1.5 times greater than the bottom-up gridded United States Environmental Protection Agency inventory, in which livestock and oil/gas sources were underestimated by 1.8-fold and 1.3-fold, respectively. Wetland emissions (4.0 ± 1.2 Tg CH4 yr-1) were the second largest source, accounting for 34% of the total budget. The temporal variability of total CH4 emissions was dominated by wetlands with peak emissions occurring in August. In contrast, emissions from oil/gas and other anthropogenic sources showed relatively weak seasonality.

  2. Have precipitation extremes and annual totals been increasing in the world's dry regions over the last 60 years?

    NASA Astrophysics Data System (ADS)

    Sippel, Sebastian; Zscheischler, Jakob; Heimann, Martin; Lange, Holger; Mahecha, Miguel D.; van Oldenborgh, Geert Jan; Otto, Friederike E. L.; Reichstein, Markus

    2017-01-01

    Daily precipitation extremes and annual totals have increased in large parts of the global land area over the past decades. These observations are consistent with theoretical considerations of a warming climate. However, until recently these trends have not been shown to consistently affect dry regions over land. A recent study, published by Donat et al. (2016), now identified significant increases in annual-maximum daily extreme precipitation (Rx1d) and annual precipitation totals (PRCPTOT) in dry regions. Here, we revisit the applied methods and explore the sensitivity of changes in precipitation extremes and annual totals to alternative choices of defining a dry region (i.e. in terms of aridity as opposed to precipitation characteristics alone). We find that (a) statistical artifacts introduced by data pre-processing based on a time-invariant reference period lead to an overestimation of the reported trends by up to 40 %, and that (b) the reported trends of globally aggregated extremes and annual totals are highly sensitive to the definition of a dry region of the globe. For example, using the same observational dataset, accounting for the statistical artifacts, and based on different aridity-based dryness definitions, we find a reduction in the positive trend of Rx1d from the originally reported +1.6 % decade-1 to +0.2 to +0.9 % decade-1 (period changes for 1981-2010 averages relative to 1951-1980 are reduced to -1.32 to +0.97 % as opposed to +4.85 % in the original study). If we include additional but less homogenized data to cover larger regions, the global trend increases slightly (Rx1d: +0.4 to +1.1 % decade-1), and in this case we can indeed confirm (partly) significant increases in Rx1d. However, these globally aggregated estimates remain uncertain as considerable gaps in long-term observations in the Earth's arid and semi-arid regions remain. In summary, adequate data pre-processing and accounting for uncertainties regarding the definition of

  3. High resolution of anthropogenic atmospheric emissions of 12 heavy metals in the three biggest metropolitan areas, China

    NASA Astrophysics Data System (ADS)

    Tian, H.; Zhu, C.

    2015-12-01

    Atmospheric emissions of typical toxic heavy metals from anthropogenic sources have received worldwide concerns due to their adverse effects on human health and the ecosystem. An integrated inventory of anthropogenic emissions of twelve HMs (Hg, As, Se, Pb, Cd, Cr, Ni, Sb, Mn, Co, Cu and Zn) in the three biggest metropolitan areas, including Beijing-Tianjin-Hebei (BTH) region, Yangtze River Delta (YRD) region and Pearl River Delta (PRD) region, are developed for 1980-2012 by combining with detailed activity data and inter-annual dynamic emission factors which are determined by S-shaped curves on account of technology progress, economic development, and emission control. The results indicate total emissions of twelve HMs in the three metropolitan regions have increased from 5448.8 tons in 1980 to 19054.9 tons in 2012, with an annual average growth rate of about 4.0%. Due to significant difference in industrial structures and energy consumption compositions, remarkable distinctions can be observed with respect to source contributions of total HM emissions from above three metropolitan areas. Specifically, the ferrous metal smelting sector, coal combustion by industrial boilers and coal combustion by power plants are found to be the primary source of total HM emissions in the BTH region (about 34.2%), YRD region (about 28.2%) and PRD region (about 24.3%), respectively. Furthermore, we allocate the annual emissions of these heavy metals in 2012 at a high spatial resolution of 9 km × 9 km grid with ArcGIS methodology and surrogate indexes, such as regional population and gross domestic product (GDP). The peak of HM emissions are mainly distributed over the grid cells of Beijing, Tianjin, Tangshan, Shijiazhuang, Handan and Baoding in the BTH region; Shanghai, Suzhou, Wuxi, Nanjing, Hangzhou, Ningbo in the YRD region; Guangzhou, Shenzhen, Dongguan, Foshan in the PYD region, respectively. Additionally, monthly emission profiles are established in order to further identify

  4. Soil carbon dioxide emissions from a rubber plantation on tropical peat.

    PubMed

    Wakhid, Nur; Hirano, Takashi; Okimoto, Yosuke; Nurzakiah, Siti; Nursyamsi, Dedi

    2017-03-01

    Land-use change in tropical peatland potentially results in a large amount of carbon dioxide (CO 2 ) emissions owing to drainage, which lowers groundwater level (GWL) and consequently enhances oxidative peat decomposition. However, field information on carbon balance is lacking for rubber plantations, which are expanding into Indonesia's peatlands. To assess soil CO 2 emissions from an eight-year-old rubber plantation established on peat after compaction, soil CO 2 efflux was measured monthly using a closed chamber system from December 2014 to December 2015, in which a strong El Niño event occurred, and consequently GWL lowered deeply. Total soil respiration (SR) and oxidative peat decomposition (PD) were separately quantified by trenching. In addition, peat surface elevation was measured to determine annual subsidence along with GWL. With GWL, SR showed a negative logarithmic relationship (p<0.01), whereas PD showed a strong negative linearity (p<0.001). Using the significant relationships, annual SR and PD were calculated from hourly GWL data to be 3293±1039 and 1408±214gCm -2 yr -1 (mean±1 standard deviation), respectively. PD accounted for 43% of SR on an annual basis. SR showed no significant difference between near and far positions from rubber trees (p>0.05). Peat surface elevation varied seasonally in almost parallel with GWL. After correcting for GWL difference, annual total subsidence was determined at 5.64±3.20 and 5.96±0.43cmyr -1 outside and inside the trenching, respectively. Annual subsidence only through peat oxidation that was calculated from the annual PD, peat bulk density and peat carbon content was 1.50cmyr -1 . As a result, oxidative peat decomposition accounted for 25% of total subsidence (5.96cmyr -1 ) on average on an annual basis. The contribution of peat oxidation was lower than those of previous studies probably because of compaction through land preparation. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Total hemispherical emissivity of very high temperature reactor (VHTR) candidate materials: Hastelloy X, Haynes 230, and Alloy 617

    NASA Astrophysics Data System (ADS)

    Maynard, Raymond K.

    An experimental system was constructed in accordance with the standard ASTM C835-06 to measure the total hemispherical emissivity of structural materials of interest in Very High Temperature Reactor (VHTR) systems. The system was tested with304 stainless steel as well as for oxidized and un-oxidized nickel, and good reproducibility and agreement with the literature data was found. Emissivity of Hastelloy X was measured under different conditions that included: (i) "as received" (original sample) from the supplier; (ii) with increased surface roughness; (iii) oxidized, and; (iv) graphite coated. Measurements were made over a wide range of temperatures. Hastelloy X, as received from the supplier, was cleaned before additional roughening of the surface and coating with graphite. The emissivity of the original samples (cleaned after received) varied from around 0.18 to 0.28 in the temperature range of 473 K to 1498 K. The apparent emissivity increased only slightly as the roughness of the surface increased (without corrections for the increased surface area due to the increased surface roughness). When Hastelloy X was coated with graphite or oxidized however, its emissivity was observed to increase substantially. With a deposited graphite layer on the Hastelloy, emissivity increased from 0.2 to 0.53 at 473 K and from 0.25 to 0.6 at 1473 K; a finding that has strong favorable safety implications in terms of decay heat removal in post-accident VHTR environments. Although initial oxidation of Hastelloy X increased the emissivity prolonged oxidation did not significantly increase emissivity. However as there is some oxidation of Hastelloy X used in the construction of VHTRs, this represents an essentially neutral finding in terms of the safety implications in post-accident VHTR environments. The total hemispherical emissivity of Haynes 230 alloy, which is regarded as a leading candidate material for heat exchangers in VHTR systems, was measured under various surface

  6. Measurement of total hemispherical emissivity of contaminated mirror surfaces

    NASA Technical Reports Server (NTRS)

    Facey, T. A.; Nonnenmacher, A. L.

    1989-01-01

    The effects of dust contamination on the total hemispherical emissivity (THE) of a 1.5-inch-diameter Al/MgF2-coated telescope mirror are investigated experimentally. The THE is determined by means of cooling-rate measurements in the temperature range 10-14.5 C in a vacuum of 100 ntorr or better. Photographs and drawings of the experimental setup are provided, and results for 11 dust levels are presented in tables and graphs. It is shown that dust has a significant effect on THE, but the experimental losses are only about half those predicted for perfectly black dust in perfect thermal contact with the mirror surface.

  7. Projections of emissions from burning of biomass foruse in studies of global climate and atmospheric chemistry

    Treesearch

    Darold E. Ward; Weimin Hao

    1991-01-01

    Emissions of trace gases and particulate matter from burning of biomass are generally factored into global climate models. Models for improving the estimates of the global annual release of emissions from biomass fires are presented. Estimates of total biomass consumed on a global basis range from 2 to 10 Pg (1 petagram = 1015 g) per year. New...

  8. Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (1751-2008) (DB1013 V.2011)

    DOE Data Explorer

    Andres, R. J. [CDIAC, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Boden, T. A. [CDIAC, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA); Marland, G. [CDIAC, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (USA)

    1996-01-01

    The 2011 revision of this database contains estimates of the annual, global mean value of del 13C of CO2 emissions from fossil-fuel consumption and cement manufacture for 1751-2008. These estimates of the carbon isotopic signature account for the changing mix of coal, petroleum, and natural gas being consumed and for the changing mix of petroleum from various producing areas with characteristic isotopic signatures. This time series of global fossil-fuel del 13C signature provides an additional constraint for balancing the sources and sinks of the global carbon cycle and complements the atmospheric del 13C measurements that are used to partition the uptake of fossil carbon emissions among the ocean, atmosphere, and terrestrial biosphere reservoirs.

  9. Electric Power Annual

    EIA Publications

    2016-01-01

    The Electric Power Annual 2015 presents 11 years (2005-15) of national-level data on electricity generating capacity, electricity generation and useful thermal output, fuel receipts, consumption, and emissions.

  10. Otoacoustic emission responses of the cochlea to acute and total ischemia.

    PubMed

    Yıldırım, Yavuz Selim; Aksoy, Fadlullah; Ozturan, Orhan; Veyseller, Bayram; Demirhan, Hasan

    2013-12-01

    In the present experimental study, we sought to monitor distortion product otoacoustic emissions (DPOAEs) as an indicator of cochlear function, after sudden, total, and irreversible interruption of cochlear blood flow, to provide information on the time course of cochlear response to ischemia. Twenty rats with normal hearing function were included. Complete and abrupt ischemia was provided by decapitation. DPOAEs at 3-8 kHz frequencies were recorded at baseline and exactly every consecutive minute after decapitation, until emissions in all frequencies disappeared completely. Mean DPOAE values decreased significantly and progressively after decapitation for all frequencies. The mean duration of emissions was 8.20 ± 1.96 min (minimum 3 min, maximum 11 min). The longest durations of DPOAEs were observed with 4 and 5 kHz frequencies, and 3 and 6 kHz had the shortest durations. The outer hair cells exposed to acute ischemia seem to exhibit a rapid functional loss; thus, cautious handling of the cochlear vasculature and surrounding structures is necessary in surgical interventions. Additionally, our results provide some idea of the normal tolerance range of the cochlea to ischemia, which could be useful for future studies.

  11. Modelling carbon dioxide emissions from agricultural soils in Canada.

    PubMed

    Yadav, Dhananjay; Wang, Junye

    2017-11-01

    Agricultural soils are a leading source of atmospheric greenhouse gas (GHG) emissions and are major contributors to global climate change. Carbon dioxide (CO 2 ) makes up 20% of the total GHG emitted from agricultural soil. Therefore, an evaluation of CO 2 emissions from agricultural soil is necessary in order to make mitigation strategies for environmental efficiency and economic planning possible. However, quantification of CO 2 emissions through experimental methods is constrained due to the large time and labour requirements for analysis. Therefore, a modelling approach is needed to achieve this objective. In this paper, the DeNitrification-DeComposition (DNDC), a process-based model, was modified to predict CO 2 emissions for Canada from regional conditions. The modified DNDC model was applied at three experimental sites in the province of Saskatchewan. The results indicate that the simulations of the modified DNDC model are in good agreement with observations. The agricultural management of fertilization and irrigation were evaluated using scenario analysis. The simulated total annual CO 2 flux changed on average by ±13% and ±1% following a ±50% variance of the total amount of N applied by fertilising and the total amount of water through irrigation applications, respectively. Therefore, careful management of irrigation and applications of fertiliser can help to reduce CO 2 emissions from the agricultural sector. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. 12 CFR Appendix K to Part 226 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Reverse Mortgage Transactions K Appendix K to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED) BOARD OF GOVERNORS OF THE FEDERAL RESERVE SYSTEM TRUTH IN LENDING (REGULATION Z) Pt. 226, App. K Appendix K to Part 226—Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions (a...

  13. 12 CFR Appendix K to Part 226 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Reverse Mortgage Transactions K Appendix K to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED) BOARD OF GOVERNORS OF THE FEDERAL RESERVE SYSTEM TRUTH IN LENDING (REGULATION Z) Pt. 226, App. K Appendix K to Part 226—Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions (a...

  14. 12 CFR Appendix K to Part 226 - Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Reverse Mortgage Transactions K Appendix K to Part 226 Banks and Banking FEDERAL RESERVE SYSTEM (CONTINUED) BOARD OF GOVERNORS OF THE FEDERAL RESERVE SYSTEM TRUTH IN LENDING (REGULATION Z) Pt. 226, App. K Appendix K to Part 226—Total Annual Loan Cost Rate Computations for Reverse Mortgage Transactions (a...

  15. Emission Sectoral Contributions of Foreign Emissions to Particulate Matter Concentrations over South Korea

    NASA Astrophysics Data System (ADS)

    Kim, E.; Kim, S.; Kim, H. C.; Kim, B. U.; Cho, J. H.; Woo, J. H.

    2017-12-01

    In this study, we investigated the contributions of major emission source categories located upwind of South Korea to Particulate Matter (PM) in South Korea. In general, air quality in South Korea is affected by anthropogenic air pollutants emitted from foreign countries including China. Some studies reported that foreign emissions contributed 50 % of annual surface PM total mass concentrations in the Seoul Metropolitan Area, South Korea in 2014. Previous studies examined PM contributions of foreign emissions from all sectors considering meteorological variations. However, little studies conducted to assess contributions of specific foreign source categories. Therefore, we attempted to estimate sectoral contributions of foreign emissions from China to South Korea PM using our air quality forecasting system. We used Model Inter-Comparison Study in Asia 2010 for foreign emissions and Clean Air Policy Support System 2010 emission inventories for domestic emissions. To quantify contributions of major emission sectors to South Korea PM, we applied the Community Multi-scale Air Quality system with brute force method by perturbing emissions from industrial, residential, fossil-fuel power plants, transportation, and agriculture sectors in China. We noted that industrial sector was pre-dominant over the region except during cold season for primary PMs when residential emissions drastically increase due to heating demand. This study will benefit ensemble air quality forecasting and refined control strategy design by providing quantitative assessment on seasonal contributions of foreign emissions from major source categories.

  16. Spatial and temporal variation of historical anthropogenic NMVOCs emission inventories in China

    NASA Astrophysics Data System (ADS)

    Bo, Y.; Cai, H.; Xie, S. D.

    2008-12-01

    Multiyear emission inventories of anthropogenic NMVOCs in China for 1980-2005 were established based on time-varying statistical data, literature surveyed and model calculated emission factors, which were further gridded at a high spatial resolution of 40 km×40 km using the GIS methodology. Results show a continuous growth trend of China's historical NMVOCs emissions during the period of 1980-2005, with the emission increasing by 4.2 times at an annual average rate of 10.6% from 3.91 Tg in 1980 to 16.49 Tg in 2005. Vehicles, biomass burning, industrial processes, fossil fuel combustion, solvent utilization, and storage and transport generated 5.50 Tg, 3.84 Tg, 2.76 Tg, 1.98 Tg, 1.87 Tg, and 0.55 Tg of NMVOCs, respectively, in 2005. Motorcycles, biofuel burning, heavy duty vans, synthetic fibre production, biomass open burning, and industrial and commercial consumption were primary emission sources. Besides, source contributions of NMVOCs emissions showed remarkable annual variation. However, emissions of these sources had been continuously increasing, which coincided well with China's economic growth. Spatial distribution of NMVOCs emissions illustrates that high emissions mainly concentrates in developed regions of northern, eastern and southern coastal areas, which produced more emissions than the relatively underdeveloped western and inland regions. Particularly, southeastern, northern, and central China covering 35.2% of China's territory, generated 59.4% of the total emissions, while the populous capital cities covering merely 4.5% of China's territory, accounted for 24.9% of the national emissions. Annual variation of regional emission intensity shows that emissions concentrating in urban areas tended to transfer to rural areas year by year. Moreover, eastern, southern, central, and northeastern China were typical areas of high emission intensity and had a tendency of expanding to the northwestern China, which revealed the transfer of emission

  17. Wastewater treatment process impact on energy savings and greenhouse gas emissions.

    PubMed

    Mamais, D; Noutsopoulos, C; Dimopoulou, A; Stasinakis, A; Lekkas, T D

    2015-01-01

    The objective of this research was to assess the energy consumption of wastewater treatment plants (WWTPs), to apply a mathematical model to evaluate their carbon footprint, and to propose energy saving strategies that can be implemented to reduce both energy consumption and greenhouse gas (GHG) emissions in Greece. The survey was focused on 10 WWTPs in Greece with a treatment capacity ranging from 10,000 to 4,000,000 population equivalents (PE). Based on the results, annual specific energy consumption ranged from 15 to 86 kWh/PE. The highest energy consumer in all the WWTPs was aeration, accounting for 40-75% of total energy requirements. The annual GHG emissions varied significantly according to the treatment schemes employed and ranged between 61 and 161 kgCO₂e/PE. The highest values of CO₂emissions were obtained in extended aeration systems and the lowest in conventional activated sludge systems. Key strategies that the wastewater industry could adopt to mitigate GHG emissions are identified and discussed. A case study is presented to demonstrate potential strategies for energy savings and GHG emission reduction. Given the results, it is postulated that the reduction of dissolved oxygen (DO) set points and sludge retention time can provide significant energy savings and decrease GHG emissions.

  18. Annual Fossil-Fuel CO2 Emissions: Isomass of Emissions Gridded by One Degree Latitude by One Degree Longitude (1751 - 2008) (V. 2011)

    DOE Data Explorer

    Andres, R. J. [Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S.; Boden, T. A. [Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S.; Marland, G. [Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S.

    2012-01-01

    The basic data provided in these data files are derived from time series of Global, Regional, and National Fossil-Fuel CO2 Emissions (http://cdiac.ess-dive.lbl.gov/trends/emis/overview_2008.html) and references therein. The data accessible here take these tabular, national, mass-emissions data, multiply them by stable carbon isotopic signature (del 13C) as described in Andres et al. (2000), and distribute them spatially on a one degree latitude by one degree longitude grid. The within-country spatial distribution is achieved through a fixed population distribution as reported in Andres et al. (1996). Note that the mass-emissions data used here are based on fossil-fuel consumption estimates as these are more representative of within country emissions than fossil-fuel production estimates (see http://cdiac.ess-dive.lbl.gov/faq.html#Q10 for a description why emission totals based upon consumption differ from those based upon production).

  19. Particle size distribution characteristics of cotton gin battery condenser system total particulate emissions

    USDA-ARS?s Scientific Manuscript database

    This report is part of a project to characterize cotton gin emissions from the standpoint of total particulate stack sampling and particle size analyses. In 2013, EPA published a more stringent standard for particulate matter with nominal diameter less than or equal to 2.5 µm (PM2.5). This created a...

  20. Methane emissions to the troposphere from the Amazon floodplain

    NASA Technical Reports Server (NTRS)

    Devol, Allen H.; Richey, Jeffrey E.; Clark, Wayne A.; King, Stagg L.; Martinelli, Luiz A.

    1988-01-01

    The magnitudes of CH4 emissions to the troposphere from the Amazon River floodplain and the mechanism of these emissions were investigated using the data of 94 individual flux measurements made along a 1700-km stretch of the river during July/August 1985. The overall average rate of CH4 emission from wetlands was found to be 390 mg CH4/sq m per day, with the highest emissions (590 mg CH4/sq m per day) attributed to the water surfaces covered by aquatic macrophytes. Ebullition was the dominant mechanism of emission, accounting for 85 percent of the total. Surface-water CH4 concentrations were highly supersaturated, averaging 6.4 micromolar. The annual emission of CH4 from the Amazon Basin to the troposphere, estimated from the area and the known emission rate, is about 10 CH4 Tg/yr, indicating the importance of the area in the global atmospheric CH4 cycle.

  1. Gridded emission inventory of short-chain chlorinated paraffins and its validation in China.

    PubMed

    Jiang, Wanyanhan; Huang, Tao; Mao, Xiaoxuan; Wang, Li; Zhao, Yuan; Jia, Chenhui; Wang, Yanan; Gao, Hong; Ma, Jianmin

    2017-01-01

    China produces approximately 20%-30% of the total global chlorinated paraffins (CPs). The establishment of a short-chain CP (SCCP) emission inventory is a significant step toward risk assessment and regulation of SCCPs in China and throughout the globe. This study developed a gridded SCCPs emission inventory with a 1/4° longitude by 1/4° latitude resolution from 2008 to 2012 for China, which was based on the total annual CPs emissions for the nation. The total national SCCPs emission during this 5-year period was 5651.5 tons. An additive in metal cutting fluids was a major emission source in China, contributing 2680.2 tons to the total atmospheric emissions of SCCPs from 2008 to 2012, followed by the production of CPs (2281.8 tons), plasticizers (514.3 tons), flame retardants (108.6 tons), and net import (66.6 tons). Most of these emission sources are located along the eastern seaboard of China and southern China. A coupled atmospheric transport model was employed to simulate environmental contamination by SCCPs using the gridded emission inventory of SCCPs from 2008 to 2012 as the model initial conditions. Simulated atmospheric and soil concentrations were compared with field monitoring data to validate the emission inventory. The results showed good consistency between modeled and field sampling data, supporting the reliability and credibility of the gridded SCCPs emission inventory that was developed in the present study. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Inter-Annual Variability of Area-Scaled Gaseous Carbon Emissions from Wetland Soils in the Liaohe Delta, China.

    PubMed

    Ye, Siyuan; Krauss, Ken W; Brix, Hans; Wei, Mengjie; Olsson, Linda; Yu, Xueyang; Ma, Xueying; Wang, Jin; Yuan, Hongming; Zhao, Guangming; Ding, Xigui; Moss, Rebecca F

    2016-01-01

    Global management of wetlands to suppress greenhouse gas (GHG) emissions, facilitate carbon (C) sequestration, and reduce atmospheric CO2 concentrations while simultaneously promoting agricultural gains is paramount. However, studies that relate variability in CO2 and CH4 emissions at large spatial scales are limited. We investigated three-year emissions of soil CO2 and CH4 from the primary wetland types of the Liaohe Delta, China, by focusing on a total wetland area of 3287 km2. One percent is Suaeda salsa, 24% is Phragmites australis, and 75% is rice. While S. salsa wetlands are under somewhat natural tidal influence, P. australis and rice are managed hydrologically for paper and food, respectively. Total C emissions from CO2 and CH4 from these wetland soils were 2.9 Tg C/year, ranging from 2.5 to 3.3 Tg C/year depending on the year assessed. Primary emissions were from CO2 (~98%). Photosynthetic uptake of CO2 would mitigate most of the soil CO2 emissions, but CH4 emissions would persist. Overall, CH4 fluxes were high when soil temperatures were >18°C and pore water salinity <18 PSU. CH4 emissions from rice habitat alone in the Liaohe Delta represent 0.2% of CH4 carbon emissions globally from rice. With such a large area and interannual sensitivity in soil GHG fluxes, management practices in the Delta and similar wetlands around the world have the potential not only to influence local C budgeting, but also to influence global biogeochemical cycling.

  3. Inter-Annual Variability of Area-Scaled Gaseous Carbon Emissions from Wetland Soils in the Liaohe Delta, China

    PubMed Central

    Ye, Siyuan; Krauss, Ken W.; Brix, Hans; Wei, Mengjie; Olsson, Linda; Yu, Xueyang; Ma, Xueying; Wang, Jin; Yuan, Hongming; Zhao, Guangming; Ding, Xigui; Moss, Rebecca F.

    2016-01-01

    Global management of wetlands to suppress greenhouse gas (GHG) emissions, facilitate carbon (C) sequestration, and reduce atmospheric CO2 concentrations while simultaneously promoting agricultural gains is paramount. However, studies that relate variability in CO2 and CH4 emissions at large spatial scales are limited. We investigated three-year emissions of soil CO2 and CH4 from the primary wetland types of the Liaohe Delta, China, by focusing on a total wetland area of 3287 km2. One percent is Suaeda salsa, 24% is Phragmites australis, and 75% is rice. While S. salsa wetlands are under somewhat natural tidal influence, P. australis and rice are managed hydrologically for paper and food, respectively. Total C emissions from CO2 and CH4 from these wetland soils were 2.9 Tg C/year, ranging from 2.5 to 3.3 Tg C/year depending on the year assessed. Primary emissions were from CO2 (~98%). Photosynthetic uptake of CO2 would mitigate most of the soil CO2 emissions, but CH4 emissions would persist. Overall, CH4 fluxes were high when soil temperatures were >18°C and pore water salinity <18 PSU. CH4 emissions from rice habitat alone in the Liaohe Delta represent 0.2% of CH4 carbon emissions globally from rice. With such a large area and interannual sensitivity in soil GHG fluxes, management practices in the Delta and similar wetlands around the world have the potential not only to influence local C budgeting, but also to influence global biogeochemical cycling. PMID:27501148

  4. Absorption of infrared radiation by carbon monoxide at elevated temperatures and pressures: Part B. Total emissivity charts and correlations

    NASA Astrophysics Data System (ADS)

    Alberti, Michael; Weber, Roman; Mancini, Marco

    2017-10-01

    The line-by-line procedure developed in the associated paper (Part A ) has been used to generate the total emissivity chart for pure CO and CO -N2 /air mixtures at 1 bar total pressure, in the 300 to 3000 K temperature and 0.01 to 3000 bar cm pressure path length range. Methods of scaling the emissivity to pressures different to 1 bar, in the range 0.1 to 40 bar, are provided through pressure correction graphs and EXCEL interpolator (Supplementary Material). The interpolated emissivities are within ± 2% margin from the line-by-line calculated values. The newly developed emissivity graphs are substantially more accurate than the existing Ulrich (1936) & Hottel (1954) and Abu-Romia & Tien (1966) charts.

  5. Greenhouse gas emissions from green waste composting windrow.

    PubMed

    Zhu-Barker, Xia; Bailey, Shannon K; Paw U, Kyaw Tha; Burger, Martin; Horwath, William R

    2017-01-01

    The process of composting is a source of greenhouse gases (GHG) that contribute to climate change. We monitored three field-scale green waste compost windrows over a one-year period to measure the seasonal variance of the GHG fluxes. The compost pile that experienced the wettest and coolest weather had the highest average CH 4 emission of 254±76gCday -1 dry weight (DW) Mg -1 and lowest average N 2 O emission of 152±21mgNday -1 DW Mg -1 compared to the other seasonal piles. The highest N 2 O emissions (342±41mgNday -1 DW Mg -1 ) came from the pile that underwent the driest and hottest weather. The compost windrow oxygen (O 2 ) concentration and moisture content were the most consistent factors predicting N 2 O and CH 4 emissions from all seasonal compost piles. Compared to N 2 O, CH 4 was a higher contributor to the overall global warming potential (GWP) expressed as CO 2 equivalents (CO 2 eq.). Therefore, CH 4 mitigation practices, such as increasing O 2 concentration in the compost windrows through moisture control, feedstock changes to increase porosity, and windrow turning, may reduce the overall GWP of composting. Based on the results of the present study, statewide total GHG emissions of green waste composting were estimated at 789,000Mg of CO 2 eq., representing 2.1% of total annual GHG emissions of the California agricultural sector and 0.18% of the total state emissions. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. [Estimation of VOC emission from forests in China based on the volume of tree species].

    PubMed

    Zhang, Gang-feng; Xie, Shao-dong

    2009-10-15

    Applying the volume data of dominant trees from statistics on the national forest resources, volatile organic compounds (VOC) emissions of each main tree species in China were estimated based on the light-temperature model put forward by Guenther. China's VOC emission inventory for forest was established, and the space-time and age-class distributions of VOC emission were analyzed. The results show that the total VOC emissions from forests in China are 8565.76 Gg, of which isoprene is 5689.38 Gg (66.42%), monoterpenes is 1343.95 Gg (15.69%), and other VOC is 1532.43 Gg (17.89%). VOC emissions have significant species variation. Quercus is the main species responsible for emission, contributing 45.22% of the total, followed by Picea and Pinus massoniana with 6.34% and 5.22%, respectively. Southwest and Northeast China are the major emission regions. In specific, Yunnan, Sichuan, Heilongjiang, Jilin and Shaanxi are the top five provinces producing the most VOC emissions from forests, and their contributions to the total are 15.09%, 12.58%, 10.35%, 7.49% and 7.37%, respectively. Emissions from these five provinces occupy more than half (52.88%) of the national emissions. Besides, VOC emissions show remarkable seasonal variation. Emissions in summer are the largest, accounting for 56.66% of the annual. Forests of different ages have different emission contribution. Half-mature forests play a key role and contribute 38.84% of the total emission from forests.

  7. Estimation of vehicular emissions using dynamic emission factors: A case study of Delhi, India

    NASA Astrophysics Data System (ADS)

    Mishra, Dhirendra; Goyal, P.

    2014-12-01

    The estimation of vehicular emissions depends mainly on the values of emission factors, which are used for the development of a comprehensive emission inventory of vehicles. In this study the variations of emission factors as well as the emission rates have been studied in Delhi. The implementation of compressed natural gas (CNG), in the diesel and petrol, public vehicles in the year 2001 has changed the complete air quality scenario of Delhi. The dynamic emission factors of criteria pollutants viz. carbon monoxide (CO), nitrogen oxide (NOx) and particulate matter (PM10) for all types of vehicles have been developed after, which are based on the several factors such as regulated emission limits, number of vehicle deterioration, vehicle increment, vehicle age etc. These emission factors are found to be decreased continuously throughout the study years 2003-2012. The International Vehicle Emissions (IVE) model is used to estimate the emissions of criteria pollutants by utilizing a dataset available from field observations at different traffic intersections in Delhi. Thus the vehicular emissions, based on dynamic emission factors have been estimated for the years 2003-2012, which are found to be comparable with the monitored concentrations at different locations in Delhi. It is noticed that the total emissions of CO, NOx, and PM10 are increased by 45.63%, 68.88% and 17.92%, respectively up to the year 2012 and the emissions of NOx and PM10 are grown continuously with an annual average growth rate of 5.4% and 1.7% respectively.

  8. Nitrogenous fertilizers: Global distribution of consumption and associated emissions of nitrous oxide and ammonia

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Matthews, E.

    1994-12-01

    The global distribution of nitrogen input via application of chemical nitrogenous fertilizers to agricultural ecosystems is presented. The suite of 1{degrees} (latitude/longitude) resolution data bases includes primary data on fertilizer consumption, as well as supporting data sets defining the distribution and intensity of agriculture associated with fertilizer use. The data were developed from a variety of sources and reflect conditions for the mid-1980s. East Asia, where fertilizer use is increasing at {approximately}10%/year, accounted for {approximately}37% of the total, while North America and western Europe, where fertilizer use is leveling off, accounted for 40% of the world`s total in the mid-1980s.more » While almost every country consumes urea, {approximately}75% of the large East Asian fertilizer use is supplied by this one fertilizer. Ammonium nitrate, used primarily in the former centrally planned economies of Europe, in West Asia, and in Africa, accounted for about one quarter of global consumption. These data were used to estimate distributions of the annual emission of nitrous oxide (N{sub 2}O) and ammonia (NH{sub 3}) associated with the use of fertilizers. Applying published ranges of emission coefficients for fertilizer types in the data base yields a median emission of 0.1 Tg N{sub 2}O-N, with lower and upper values of 0.03 and 2.0 Tg N{sub 2}O-N in 1984. This equals <1% to {approximately}3% of the total nitrogen applied via commercial fertilizers and represents ,=<1% to 15% of the annual emission of N{sub 2}O from terrestrial sources. Assuming that the {approximately}4% annual increase in consumption of nitrogenous fertilizers during the 1980s corresponds to a {approximately}4% rise in the release of N{sub 2}O-N, yearly increases in emissions from fertilizer use are <0.01 to 0.08 Tg N{sub 2}O-N equal to <1% to 3% of the current growth of atmospheric nitrous oxide. 98 refs., 3 figs., 5 tabs.« less

  9. Estimating fire severity and carbon emissions over Australian tropical savannas based on passive microwave satellite observations

    NASA Astrophysics Data System (ADS)

    Chen, X.; Liu, Y.; Evans, J. P.; Parinussa, R.

    2017-12-01

    Carbon emissions from large-scale fire activity over the Australian tropical savannas have strong inter-annual variability, due mainly to variations in fuel accumulation in response to rainfall. We investigated the use of a recently developed satellite-based vegetation optical depth (VOD) dataset to estimate fire severity and carbon emission. VOD is sensitive to the dynamics of all aboveground vegetation and available nearly every two days. For areas burned during 2003 - 2010, we calculated the VOD change (ΔVOD) pre- and post-fire and the associated loss in above ground biomass carbon. Both results compare well with widely-accepted approaches: ΔVOD agreed well with the Normalized Burn Ratio change (ΔNBR) and carbon loss with modelled emissions from the Global Fire Emissions Database (GFED). We found that the ΔVOD and ΔNBR are generally linearly related. The Pearson correlation coefficients (R) between VOD- and GFED-based fire carbon emissions for monthly and annual total estimates are very high, 0.92 and 0.96 respectively. A key feature of fire carbon emissions is the strong inter-annual variation, ranging from 21.1 million tonnes in 2010 to 84.3 million tonnes in 2004. This study demonstrates that a reasonable estimate of fire carbon emissions can be achieved in a timely manner based on multiple satellite observations over the regions where the emissions are primarily from aboveground vegetation loss, which can be complementary to the currently used approaches.

  10. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, providesmore » estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.« less

  11. Measurements of the Temperature-Dependent Total Hemispherical Emissivity Using an Electrostatic Levitation Facility

    NASA Astrophysics Data System (ADS)

    Gangopadhyay, A. K.; Kelton, K. F.

    2017-01-01

    Among the three fundamental processes of heat transfer (conduction, convection, and radiation), radiation is the most dominant at high temperatures. The total hemispherical emissivity is an important property that determines the amount of heat loss by radiation. Unfortunately, the emissivity, especially its temperature dependence (ɛ (T)), is unknown for most materials. Here, we demonstrate the feasibility of measuring ɛ (T) using an electrostatic levitation (ESL) technique that allows such measurements to be made on levitated solid and liquid samples in a contamination-free, high-vacuum environment. The ɛ (T) for solid Ni and liquid Zr_{60}Al_{10}Cu_{18}Ni9Co3 from these measurements is consistent with the existing literature data.

  12. Air Toxics Emissions from Open Burning of Crop Residues in Southeast Asia

    NASA Astrophysics Data System (ADS)

    KIM Oanh, N. T.; Permadi, D. A.; Hopke, P. K.; Smith, K. R.; Nguyet, D. A.

    2016-12-01

    Agricultural crops production in Southeast Asia (SEA) increases annually to meet domestic consumption of growing population and also for export. Crop residue open burning (CROB) is commonly practiced by farmers to quickly dispose of huge amounts of the agricultural waste, such as rice straw, generated after each crop cycle. This CROB activity emits various toxic air pollutants as well as short-lived climate pollutants such as black carbon particles. Our study focused on quantifying the 2015 annual emissions of semi-volatile organic compounds including polycyclic aromatic hydrocarbons (PAHs), dioxins/furans (PCDD/PCDF), organochlorine pesticides (OCP), along with other conventional trace gases, particulate matter, and greenhouse gases from CROB in 10 major agricultural crop producing SEA countries. Crop production statistics and current field OB practices were gathered from our primary surveys and relevant secondary data sources. Emission factors for rice straw and maize residue burning were taken mainly from our measurements in Thailand while for other crops relevant published data were used. The best emission estimates of air toxics from CROB in SEA were 112 g-TEQ/yr of PCDD/PCDF, 33 t/yr of OCP, and 25 Gg/yr of total PAH of which the well-known carcinogenic benzo[a]pyrene was 0.3 Gg/yr. The CROB of rice production had the highest shares of emissions (33-95%) among considered 8 crop types. Indonesia was the top contributor to the total SEA emissions (30-45%) followed by Vietnam (16-26%), Thailand (6-22%) and Myanmar (5-18%). The spatial distributions of emissions, 0.1º x 0.1º, for each specie were prepared using MODIS land cover data. Temporally, higher emissions were observed in the harvesting months of the main rice crops. This emissions database can be used in regional air quality modeling studies to assess the impacts of CROB activity and to promote non-open burning alternatives.

  13. Estimation of vegetative mercury emissions in China.

    PubMed

    Quan, Jiannong; Zhang, Xiaoshan; Shim, Shang Gyoo

    2008-01-01

    Vegetative mercury emissions were estimated within the framework of Biogenic Emission Inventory System (BEIS3 V3.11). In this estimation, the 19 categories of U.S. Geological Survey landcover data were incorporated to generate the vegetation-specific mercury emissions in a 81-km Lambert Conformal model grid covering the total Chinese continent. The surface temperature and cloud-corrected solar radiation from a Mesoscale Meteorological model (MM5) were retrieved and used for calculating the diurnal variation. The implemented emission factors were either evaluated from the measured mercury flux data for forest, agriculture and water, or assumed for other land fields without available flux data. Annual simulations using the MM5 data were performed to investigate the seasonal emission variation. From the sensitivity analysis using two sets of emission factors, the vegetative mercury emissions in China domain were estimated to range from a lower limit of 79 x 10(3) kg/year to an upper limit of 177 x 10(3) kg/year. The modeled vegetative emissions were mainly generated from the eastern and southern China. Using the estimated data, it is shown that mercury emissions from vegetation are comparable to that from anthropogenic sources during summer. However, the vegetative emissions decrease greatly during winter, leaving anthropogenic sources as the major sources of emission.

  14. Assessment of volatile organic compound emissions from ecosystems of China

    NASA Astrophysics Data System (ADS)

    Klinger, L. F.; Li, Q.-J.; Guenther, A. B.; Greenberg, J. P.; Baker, B.; Bai, J.-H.

    2002-11-01

    Isoprene, monoterpene, and other volatile organic compound (VOC) emissions from grasslands, shrublands, forests, and peatlands in China were characterized to estimate their regional magnitudes and to compare these emissions with those from landscapes of North America, Europe, and Africa. Ecological and VOC emission sampling was conducted at 52 sites centered in and around major research stations located in seven different regions of China: Inner Mongolia (temperate), Changbai Mountain (boreal-temperate), Beijing Mountain (temperate), Dinghu Mountain (subtropical), Ailao Mountain (subtropical), Kunming (subtropical), and Xishuangbanna (tropical). Transects were used to sample plant species and growth form composition, leafy (green) biomass, and leaf area in forests representing nearly all the major forest types of China. Leafy biomass was determined using generic algorithms based on tree diameter, canopy structure, and absolute cover. Measurements of VOC emissions were made on 386 of the 541 recorded species using a portable photo-ionization detector method. For 105 species, VOC emissions were also measured using a flow-through leaf cuvette sampling/gas chromatography analysis method. Results indicate that isoprene and monoterpene emissions, as well as leafy biomass, vary systematically along gradients of ecological succession in the same manner found in previous studies in the United States, Canada, and Africa. Applying these results to a regional VOC emissions model, we arrive at a value of 21 Tg C for total annual biogenic VOC emissions from China, compared to 5 Tg C of VOCs released annually from anthropogenic sources there. The isoprene and monoterpene emissions are nearly the same as those reported for Europe, which is comparable in size to China.

  15. Inter-annual variability of area-scaled gaseous carbon emissions from wetland soils in the Liaohe Delta, China

    USGS Publications Warehouse

    Ye, Siyuan; Krauss, Ken W.; Brix, Hans; Wei, Mengjie; Olsson, Linda; Yu, Xueyang; Ma, Yueying; Wang, Jin; Yuan, Hongming; Zhao, Guangming; Ding, Xigui; Moss, Rebecca

    2016-01-01

    Global management of wetlands to suppress greenhouse gas (GHG) emissions, facilitate carbon (C) sequestration, and reduce atmospheric CO2 concentrations while simultaneously promoting agricultural gains is paramount. However, studies that relate variability in CO2 and CH4 emissions at large spatial scales are limited. We investigated three-year emissions of soil CO2 and CH4 from the primary wetland types of the Liaohe Delta, China, by focusing on a total wetland area of 3287 km2. One percent is Suaeda salsa, 24% is Phragmites australis, and 75% is rice. While S. salsa wetlands are under somewhat natural tidal influence, P. australis and rice are managed hydrologically for paper and food, respectively. Total C emissions from CO2 and CH4 from these wetland soils were 2.9 Tg C/year, ranging from 2.5 to 3.3 Tg C/year depending on the year assessed. Primary emissions were from CO2 (~98%). Photosynthetic uptake of CO2 would mitigate most of the soil CO2 emissions, but CH4 emissions would persist. Overall, CH4 fluxes were high when soil temperatures were >18°C and pore water salinity <18 PSU. CH4 emissions from rice habitat alone in the Liaohe Delta represent 0.2% of CH4 carbon emissions globally from rice. With such a large area and interannual sensitivity in soil GHG fluxes, management practices in the Delta and similar wetlands around the world have the potential not only to influence local C budgeting, but also to influence global biogeochemical cycling.

  16. Understanding Excess Emissions from Industrial Facilities: Evidence from Texas.

    PubMed

    Zirogiannis, Nikolaos; Hollingsworth, Alex J; Konisky, David M

    2018-03-06

    We analyze excess emissions from industrial facilities in Texas using data from the Texas Commission on Environmental Quality. Emissions are characterized as excess if they are beyond a facility's permitted levels and if they occur during startups, shutdowns, or malfunctions. We provide summary data on both the pollutants most often emitted as excess emissions and the industrial sectors and facilities responsible for those emissions. Excess emissions often represent a substantial share of a facility's routine (or permitted) emissions. We find that while excess emissions events are frequent, the majority of excess emissions are emitted by the largest events. That is, the sum of emissions in the 96-100th percentile is often several orders of magnitude larger than the remaining excess emissions (i.e., the sum of emissions below the 95th percentile). Thus, the majority of events emit a small amount of pollution relative to the total amount emitted. In addition, a small group of high emitting facilities in the most polluting industrial sectors are responsible for the vast majority of excess emissions. Using an integrated assessment model, we estimate that the health damages in Texas from excess emissions are approximately $150 million annually.

  17. 40 CFR 98.313 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    .... You must calculate and report the annual process CO2 emissions for each chloride process line using... subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation... (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the annual...

  18. 40 CFR 98.283 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    .... You must calculate and report the combined annual process CO2 emissions from all silicon carbide.... (a) Calculate and report under this subpart the combined annual process CO2 emissions by operating... all associated requirements for Tier 4 in subpart C of this part (General Stationary Fuel Combustion...

  19. 40 CFR 98.313 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    .... You must calculate and report the annual process CO2 emissions for each chloride process line using... subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation... (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the annual...

  20. 40 CFR 98.313 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    .... You must calculate and report the annual process CO2 emissions for each chloride process line using... subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation... (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the annual...

  1. 40 CFR 98.313 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    .... You must calculate and report the annual process CO2 emissions for each chloride process line using... subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation... (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the annual...

  2. 40 CFR 98.313 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... You must calculate and report the annual process CO2 emissions for each chloride process line using... subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation... (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the annual...

  3. Implementation of the MEGAN (v2.1) biogenic emission model in the ECHAM6-HAMMOZ chemistry climate model

    NASA Astrophysics Data System (ADS)

    Henrot, Alexandra-Jane; Stanelle, Tanja; Schröder, Sabine; Siegenthaler, Colombe; Taraborrelli, Domenico; Schultz, Martin G.

    2017-02-01

    A biogenic emission scheme based on the Model of Emissions of Gases and Aerosols from Nature (MEGAN) version 2.1 (Guenther et al., 2012) has been integrated into the ECHAM6-HAMMOZ chemistry climate model in order to calculate the emissions from terrestrial vegetation of 32 compounds. The estimated annual global total for the reference simulation is 634 Tg C yr-1 (simulation period 2000-2012). Isoprene is the main contributor to the average emission total, accounting for 66 % (417 Tg C yr-1), followed by several monoterpenes (12 %), methanol (7 %), acetone (3.6 %), and ethene (3.6 %). Regionally, most of the high annual emissions are found to be associated with tropical regions and tropical vegetation types. In order to evaluate the implementation of the biogenic model in ECHAM-HAMMOZ, global and regional biogenic volatile organic compound (BVOC) emissions of the reference simulation were compared to previous published experiment results with MEGAN. Several sensitivity simulations were performed to study the impact of different model input and parameters related to the vegetation cover and the ECHAM6 climate. BVOC emissions obtained here are within the range of previous published estimates. The large range of emission estimates can be attributed to the use of different input data and empirical coefficients within different setups of MEGAN. The biogenic model shows a high sensitivity to the changes in plant functional type (PFT) distributions and associated emission factors for most of the compounds. The global emission impact for isoprene is about -9 %, but reaches +75 % for α-pinene when switching from global emission factor maps to PFT-specific emission factor distributions. The highest sensitivity of isoprene emissions is calculated when considering soil moisture impact, with a global decrease of 12.5 % when the soil moisture activity factor is included in the model parameterization. Nudging ECHAM6 climate towards ERA-Interim reanalysis has an impact on the

  4. Deforestation and greenhouse gas emissions associated with fuelwood consumption of the brick making industry in Sudan.

    PubMed

    Alam, Syed Ashraful; Starr, Mike

    2009-01-01

    The study focuses on the role of the fired clay brick making industry (BMI) on deforestation and greenhouse gas (GHG) emissions in Sudan. The BMI is based on numerous kilns that use biomass fuel, mainly wood which is largely harvested unsustainably. This results in potential deforestation and land degradation. Fuelwood consumption data was collected using interviews and questionnaires from 25 BMI enterprises in three administrative regions, namely Khartoum, Kassala and Gezira. Annual fuelwood consumption data (t dm yr(-1)) was converted into harvested biomass (m(3)) using a wood density value of 0.65 t dm m(-3). For annual GHG estimations, the methodological approach outlined by the Intergovernmental Panel on Climate Change (IPCC) was used. According to our results, the annual deforestation associated with the BMI for the whole of Sudan is 508.4x10(3) m(3) of wood biomass, including 267.6x10(3) m(3) round wood and 240.8x10(3) m(3) branches and small trees. Total GHG emissions from the Sudanese BMI are estimated at 378028 t CO(2), 15554 t CO, 1778 t CH(4), 442 t NO(X), 288 t NO and 12 t N(2)O per annum. The combined CO(2)-equivalent (global warming potential for 100-year time horizon) of the GHG emissions (excluding NO(X) and NO) is 455666 t yr(-1). While these emissions form only a small part of Sudan's total GHG emissions, the associated deforestation and land degradation is of concern and effort should be made for greater use of sustainable forest resources and management.

  5. 77 FR 14366 - Notice of Annual Adjustment of the Cap on Average Total Assets That Defines Community Financial...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-09

    ... FEDERAL HOUSING FINANCE AGENCY [No. 2012-N-02] Notice of Annual Adjustment of the Cap on Average.... ACTION: Notice. SUMMARY: The Federal Housing Finance Agency (FHFA) has adjusted the cap on average total... statutory cap.\\2\\ The Bank Act was amended in 2008 to set the statutory cap at $1 billion and to require the...

  6. Sensitivity of terrestrial N2O emission to atmospheric nitrogen deposition

    NASA Astrophysics Data System (ADS)

    Ito, A.; Sudo, K.; Nishina, K.; Ishijima, K.; Inatomi, M. I.

    2015-12-01

    Terrestrial N2O emission is generated from several nitrogen sources including biological fixation, agricultural fertilizer, and atmospheric deposition. There remain large uncertainties how much N2O is produced from atmospheric deposition. This is a crosscutting issue between global warming and atmospheric pollution. In this study, we assessed the sensitivity of global terrestrial N2O emission to atmospheric deposition, using a process-based model VISIT. In the model, N2O emission is estimated separately for nitrification and denitrfication with the NGAS parameterization. The global simulations were conducted from 1901 to 2014 at spatial resolution of 0.5 degree. Atmospheric deposition of ammonium, NOy, and organic nitrogen simulated by the atmospheric chemistry model CHASER from the pre-industrial time to the present was used. Annual total nitrogen deposition was estimated to increase from 27 Tg N in 1901 to 77 Tg N in 2014. The total N2O emission was also estimated to increase in the period, but it was largely attributable to the increased emission from croplands. We need further investigations for the N2O emission from natural soils, which may be nitrogen-limited.

  7. 40 CFR 98.223 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Nitric Acid Production § 98.223 Calculating GHG emissions. (a) You must determine annual N2O process emissions from each nitric acid train according to paragraphs (a...) You must conduct an annual performance test for each nitric acid train according to paragraphs (b)(1...

  8. 40 CFR 98.223 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Nitric Acid Production § 98.223 Calculating GHG emissions. (a) You must determine annual N2O process emissions from each nitric acid train according to paragraphs (a...) You must conduct an annual performance test for each nitric acid train according to paragraphs (b)(1...

  9. 40 CFR 98.223 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Nitric Acid Production § 98.223 Calculating GHG emissions. (a) You must determine annual N2O process emissions from each nitric acid train according to paragraphs (a...) You must conduct an annual performance test for each nitric acid train according to paragraphs (b)(1...

  10. 40 CFR 98.223 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Nitric Acid Production § 98.223 Calculating GHG emissions. (a) You must determine annual N2O process emissions from each nitric acid train according to paragraphs (a...) You must conduct an annual performance test for each nitric acid train according to paragraphs (b)(1...

  11. Atmospheric inversion for cost effective quantification of city CO2 emissions

    NASA Astrophysics Data System (ADS)

    Wu, L.; Broquet, G.; Ciais, P.; Bellassen, V.; Vogel, F.; Chevallier, F.; Xueref-Remy, I.; Wang, Y.

    2015-11-01

    Cities, currently covering only a very small portion (< 3 %) of the world's land surface, directly release to the atmosphere about 44 % of global energy-related CO2, and are associated with 71-76 % of CO2 emissions from global final energy use. Although many cities have set voluntary climate plans, their CO2 emissions are not evaluated by Monitoring, Reporting and Verification (MRV) procedures that play a key role for market- or policy-based mitigation actions. Here we propose a monitoring tool that could support the development of such procedures at the city scale. It is based on an atmospheric inversion method that exploits inventory data and continuous atmospheric CO2 concentration measurements from a network of stations within and around cities to estimate city CO2 emissions. We examine the cost-effectiveness and the performance of such a tool. The instruments presently used to measure CO2 concentrations at research stations are expensive. However, cheaper sensors are currently developed and should be useable for the monitoring of CO2 emissions from a megacity in the near-term. Our assessment of the inversion method is thus based on the use of several types of hypothetical networks, with a range of numbers of sensors sampling at 25 m a.g.l. The study case for this assessment is the monitoring of the emissions of the Paris metropolitan area (~ 12 million inhabitants and 11.4 Tg C emitted in 2010) during the month of January 2011. The performance of the inversion is evaluated in terms of uncertainties in the estimates of total and sectoral CO2 emissions. These uncertainties are compared to a notional ambitious target to diagnose annual total city emissions with an uncertainty of 5 % (2-sigma). We find that, with 10 stations only, which is the typical size of current pilot networks that are deployed in some cities, the uncertainty for the 1-month total city CO2 emissions is significantly reduced by the inversion by ~ 42 % but still corresponds to an annual

  12. Impacts of urban forests on offsetting carbon emissions from industrial energy use in Hangzhou, China.

    PubMed

    Zhao, Min; Kong, Zheng-hong; Escobedo, Francisco J; Gao, Jun

    2010-01-01

    This study quantified carbon storage and sequestration by urban forests and carbon emissions from energy consumption by several industrial sources in Hangzhou, China. Carbon (C) storage and sequestration were quantified using urban forest inventory data and by applying volume-derived biomass equations and other models relating net primary productivity (NPP) and mean annual biomass increments. Industrial energy use C emissions were estimated by accounting for fossil fuel use and assigning C emission factors. Total C storage by Hangzhou's urban forests was estimated at 11.74 Tg C, and C storage per hectare was 30.25 t C. Carbon sequestration by urban forests was 1,328, 166.55 t C/year, and C sequestration per ha was 1.66 t C/ha/year. Carbon emissions from industrial energy use in Hangzhou were 7 Tg C/year. Urban forests, through sequestration, annually offset 18.57% of the amount of carbon emitted by industrial enterprises, and store an amount of C equivalent to 1.75 times the amount of annual C emitted by industrial energy uses within the city. Management practices for improving Hangzhou's urban forests function of offsetting C emissions from energy consumption are explored. These results can be used to evaluate the urban forests' role in reducing atmospheric carbon dioxide. Copyright 2009 Elsevier Ltd. All rights reserved.

  13. Road traffic emission factors for heavy metals

    NASA Astrophysics Data System (ADS)

    Johansson, Christer; Norman, Michael; Burman, Lars

    Quantifying the emissions and concentrations of heavy metals in urban air is a prerequisite for assessing their health effects. In this paper a combination of measurements and modelling is used to assess the contribution from road traffic emissions. Concentrations of particulate heavy metals in air were measured simultaneously during 1 year at a densely trafficked street and at an urban background site in Stockholm, Sweden. Annual mean concentrations of cadmium were 50 times lower than the EU directive and for nickel and arsenic concentrations were 10 and six times lower, respectively. More than a factor of two higher concentrations was in general observed at the street in comparison to roof levels indicating the strong influence from local road traffic emissions. The only compound with a significantly decreasing trend in the urban background was Pb with 9.1 ng m -3 in 1995/96 compared to 3.4 ng m -3 2003/04. This is likely due to decreased emissions from wear of brake linings and reduced emissions due to oil and coal combustion in central Europe. Total road traffic emission factors for heavy metals were estimated using parallel measurements of NOx concentrations and knowledge of NOx emission factors. In general, the emission factors for the street were higher than reported in road tunnel measurements. This could partly be due to different driving conditions, since especially for metals which are mainly emitted from brake wear, more stop and go driving in the street compared to in road tunnels is likely to increase emissions. Total emissions were compared with exhaust emissions, obtained from the COPERT model and brake wear emissions based on an earlier study in Stockholm. For Cu, Ni and Zn the sum of brake wear and exhaust emissions agreed very well with estimated total emission factors in this study. More than 90% of the road traffic emissions of Cu were due to brake wear. For Ni more than 80% is estimated to be due to exhaust emissions and for Zn around 40% of

  14. Limb observations of the 12.32 micron solar emission line during the 1991 July total eclipse

    NASA Technical Reports Server (NTRS)

    Deming, Drake; Jennings, Donald E.; Mccabe, George; Noyes, Robert; Wiedemann, Gunter; Espenak, Fred

    1992-01-01

    The limb profile of the Mg I 12.32-micron emission line is determined by occultation in the July 11, 1991 total solar eclipse over Mauna Kea. It is shown that the emission peaks are very close to the 12-micron continuum limb, as predicted by recent theory for this line as a non-LTE photospheric emission. The increase in optical depth for this extreme limb-viewing situation indicates that most of the observed emission arises from above the chromospheric temperature minimum, and it is found that this emission is extended to heights well in excess of the model predictions. The line emission can be observed as high as 2000 km above the 12-micron continuum limb, whereas theory predicts it to remain observable no higher than about 500 km above the continuum limb. The substantial limb extension observed in this line is quantitatively consistent with limb extensions seen in the far-IR continuum, and it is concluded that it is indicative of departures from gravitational hydrostatic equilibrium, or spatial inhomogeneities, in the upper solar atmosphere.

  15. Cold season emissions dominate the Arctic tundra methane budget

    NASA Astrophysics Data System (ADS)

    Zona, Donatella; Gioli, Beniamino; Commane, Róisín; Lindaas, Jakob; Wofsy, Steven C.; Miller, Charles E.; Dinardo, Steven J.; Dengel, Sigrid; Sweeney, Colm; Karion, Anna; Chang, Rachel Y.-W.; Henderson, John M.; Murphy, Patrick C.; Goodrich, Jordan P.; Moreaux, Virginie; Liljedahl, Anna; Watts, Jennifer D.; Kimball, John S.; Lipson, David A.; Oechel, Walter C.

    2016-01-01

    Arctic terrestrial ecosystems are major global sources of methane (CH4); hence, it is important to understand the seasonal and climatic controls on CH4 emissions from these systems. Here, we report year-round CH4 emissions from Alaskan Arctic tundra eddy flux sites and regional fluxes derived from aircraft data. We find that emissions during the cold season (September to May) account for ≥50% of the annual CH4 flux, with the highest emissions from noninundated upland tundra. A major fraction of cold season emissions occur during the "zero curtain" period, when subsurface soil temperatures are poised near 0 °C. The zero curtain may persist longer than the growing season, and CH4 emissions are enhanced when the duration is extended by a deep thawed layer as can occur with thick snow cover. Regional scale fluxes of CH4 derived from aircraft data demonstrate the large spatial extent of late season CH4 emissions. Scaled to the circumpolar Arctic, cold season fluxes from tundra total 12 ± 5 (95% confidence interval) Tg CH4 y-1, ∼25% of global emissions from extratropical wetlands, or ∼6% of total global wetland methane emissions. The dominance of late-season emissions, sensitivity to soil environmental conditions, and importance of dry tundra are not currently simulated in most global climate models. Because Arctic warming disproportionally impacts the cold season, our results suggest that higher cold-season CH4 emissions will result from observed and predicted increases in snow thickness, active layer depth, and soil temperature, representing important positive feedbacks on climate warming.

  16. Cold season emissions dominate the Arctic tundra methane budget.

    PubMed

    Zona, Donatella; Gioli, Beniamino; Commane, Róisín; Lindaas, Jakob; Wofsy, Steven C; Miller, Charles E; Dinardo, Steven J; Dengel, Sigrid; Sweeney, Colm; Karion, Anna; Chang, Rachel Y-W; Henderson, John M; Murphy, Patrick C; Goodrich, Jordan P; Moreaux, Virginie; Liljedahl, Anna; Watts, Jennifer D; Kimball, John S; Lipson, David A; Oechel, Walter C

    2016-01-05

    Arctic terrestrial ecosystems are major global sources of methane (CH4); hence, it is important to understand the seasonal and climatic controls on CH4 emissions from these systems. Here, we report year-round CH4 emissions from Alaskan Arctic tundra eddy flux sites and regional fluxes derived from aircraft data. We find that emissions during the cold season (September to May) account for ≥ 50% of the annual CH4 flux, with the highest emissions from noninundated upland tundra. A major fraction of cold season emissions occur during the "zero curtain" period, when subsurface soil temperatures are poised near 0 °C. The zero curtain may persist longer than the growing season, and CH4 emissions are enhanced when the duration is extended by a deep thawed layer as can occur with thick snow cover. Regional scale fluxes of CH4 derived from aircraft data demonstrate the large spatial extent of late season CH4 emissions. Scaled to the circumpolar Arctic, cold season fluxes from tundra total 12 ± 5 (95% confidence interval) Tg CH4 y(-1), ∼ 25% of global emissions from extratropical wetlands, or ∼ 6% of total global wetland methane emissions. The dominance of late-season emissions, sensitivity to soil environmental conditions, and importance of dry tundra are not currently simulated in most global climate models. Because Arctic warming disproportionally impacts the cold season, our results suggest that higher cold-season CH4 emissions will result from observed and predicted increases in snow thickness, active layer depth, and soil temperature, representing important positive feedbacks on climate warming.

  17. Optimization of heavy metals total emission, case study: Bor (Serbia)

    NASA Astrophysics Data System (ADS)

    Ilić, Ivana; Bogdanović, Dejan; Živković, Dragana; Milošević, Novica; Todorović, Boban

    2011-07-01

    The town of Bor (Serbia) is one of the most polluted towns in southeastern Europe. The copper smelter which is situated in the centre of the town is the main pollutant, mostly because of its old technology, which leads to environmental pollution caused by higher concentrations of SO 2 and PM 10. These facts show that the word is about a very polluted region in Europe which, apart from harming human health in the region itself, poses a particular danger for wider area of southeastern Europe. Optimization of heavy metal's total emission was undertaken because years of long contamination of the soil with heavy metals of anthropogenic origin created a danger that those heavy metals may enter the food chains of animals and people, which can lead to disastrous consequences. This work represents the usage of Geographic Information System (GIS) for establishing a multifactor assessment model to quantitatively divide polluted zones and for selecting control sites in a linear programming model, combined with PROMETHEE/GAIA method, Screen View modeling system, and linear programming model. The results show that emissions at some control sites need to be cut for about 40%. In order to control the background of heavy metal pollution in Bor, the ecological environment must be improved.

  18. Increased biogenic volatile organic compounds emission in Beijing

    NASA Astrophysics Data System (ADS)

    Wang, H.; Liu, H.; Wu, Q.

    2017-12-01

    Beijing is suffering the severe ozone pollution during the summer period and reliable biogenic volatile organic compounds (BVOCs) emission inventories would help to understand the local ozone pollution. According to the National Forest Resource Survey (NFRS), the forest coverage rate rises from 20.56% to 35.84% during 1998-2013 in Beijing. In this study, we recalculated local BVOC inventory in Beijing based on the latest MEGAN v2.1 model and satellite products. We adopted three independent leaf area index (LAI) products and three independent land cover (LC) products and designed five experiments, E1-E5, to test the sensitivity and uncertainty of local BVOC inventory. According to the estimation from the model, we conclude that: (1) the total amount of BVOCs is about 73.99 98.88 Gg. The estimated annual amount of isoprene, monoterpene, sesquiterpene and other VOC kinds are 38.79 50.93 Gg, 8.39 10.95 Gg, 1.04 1.49 Gg and 25.77 35.64 Gg, respectively. (2) Indicated by results of baseline experiment (E1), the proportions of isoprene, monoterpene, sesquiterpene and other VOCs are 52.57 %, 11.09 %, 1.39 % and 34.95%. (3) The variance of GEOV2 and GLASS LAI products only lead to 1% difference of total BVOC emissions. (4) The difference of PFTs affects the spatial distribution and emission density. The E4 with MODIS land cover leads to about 5.0% decline of BVOC compared with the E1 because of uneven meteorological conditions, e.g. DSW. The CCI-LC leads to a sharp decline of total BVOC emissions with percentage of 25.95%, which is owing to the relative low cover percentage of forest. (5) The broadleaf trees, as the dominant contributor, account for the 68.25% total annual BVOCs in Beijing in 2013. For the specific species, broadleaf trees contribute 94.52% of isoprene, 53.30% of monoterpene, 53.78% of sesquiterpene and 34.06% of other VOCs. (6) The estimated emission of BVOC in this study is much higher than the earlier estimation, and the development of forest area as

  19. Effects of soil dry-wet cycles and nitrogen fertilization on soil nitrous oxide emission: Simulation using the DNDC model

    NASA Astrophysics Data System (ADS)

    Hui, D.; Chen, H.; Deng, Q.; Wang, G.; Schadt, C. W.

    2017-12-01

    The major source of atmospheric nitrous oxide (N2O) is from croplands. A rapid pulse response of soil N2O emission to precipitation (PPT) is often reported, especially after a drought period. However, how precipitation pattern (i.e. frequency) and intensity, and nitrogen (N) fertilization would interactively influence soil N2O emission has not been well investigated. In this modeling study, we took advantage of a validated biogeochemical model (DNDC) in a cornfield and simulated soil N2O emission under manipulated precipitation treatments and three levels (Low, medium and high) of N application rate. The PPT treatments included precipitation pattern (from very frequent, to medium, and rare dry-wet cycles without changes in total annual precipitation) and intensity (from ambient, to -50%, +50%, and +100% ambient precipitation without changes in precipitation pattern). Results showed that both precipitation pattern and intensity, as well as nitrogen application rate had significant influences on the pulse responses and annual soil N2O emission. Very frequent dry-wet cycles tended to increase soil N2O emission while long drought-wet cycles had lower soil N2O emission, but the timing of N fertilization and precipitation also played an important role in the magnitude of pulse response and annual budget of N2O emission. As expected, soil N2O emission was higher under the high N application and lower under the low N application rate. Double precipitation (+100%) had the highest soil N2O emission, but showed no significant differences with +50% and ambient precipitation. The drought (-50%) treatment significantly reduced soil N2O emission. Annual soil N2O emission could be described as N2O=-6.7436+0.1098N+0.0049PPT, R2=0.86. Our results demonstrate that not only the intensity and pattern of precipitation greatly influence soil N2O emission, but also the timing of rainfall and N fertilization may play an important role in soil N2O pulse responses and annual N2O emission in

  20. Ammonia Emissions from agricultural fertilizer in China: From 1978 to 2008

    NASA Astrophysics Data System (ADS)

    Xu, P.

    2015-12-01

    The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. Chinese agricultural fertilizer (CAF), which is widely used in China, is the nation's largest source of NH3 emissions. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new CAF NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 ´1 km gridded map on the county level was developed for 2008; (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters; (3) time trends were derived for 1978-2008 in which the spatial and temporal patterns and the uncertainties associated with the inventory were quantified; and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 TgNH3·yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0%. During the study period, the contribution of livestock manure spreading increased from 37.0% to 45.5% because of changing fertilization practices and the rapid increase in egg, milk and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3% (minimum: 33.4%; maximum: 42.7%). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3% and 8.5%. The average contributions of cake fertilizer and straw returning were approximately 3.8% and 4.5%, respectively, thus small and stable. Collectively, the CAF NH3

  1. 40 CFR 61.254 - Annual reporting requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Annual reporting requirements. 61.254 Section 61.254 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standards for Radon...

  2. Comparison of two U.S. power-plant carbon dioxide emissions data sets

    USGS Publications Warehouse

    Ackerman, K.V.; Sundquist, E.T.

    2008-01-01

    Estimates of fossil-fuel CO2 emissions are needed to address a variety of climate-change mitigation concerns over a broad range of spatial and temporal scales. We compared two data sets that report power-plant CO 2 emissions in the conterminous U.S. for 2004, the most recent year reported in both data sets. The data sets were obtained from the Department of Energy's Energy Information Administration (EIA) and the Environmental Protection Agency's eGRID database. Conterminous U.S. total emissions computed from the data sets differed by 3.5% for total plant emissions (electricity plus useful thermal output) and 2.3% for electricity generation only. These differences are well within previous estimates of uncertainty in annual U.S. fossil-fuel emissions. However, the corresponding average absolute differences between estimates of emissions from individual power plants were much larger, 16.9% and 25.3%, respectively. By statistical analysis, we identified several potential sources of differences between EIA and eGRID estimates for individual plants. Estimates that are based partly or entirely on monitoring of stack gases (reported by eGRID only) differed significantly from estimates based on fuel consumption (as reported by EIA). Differences in accounting methods appear to explain differences in estimates for emissions from electricity generation from combined heat and power plants, and for total and electricity generation emissions from plants that burn nonconventional fuels (e.g., biomass). Our analysis suggests the need for care in utilizing emissions data from individual power plants, and the need for transparency in documenting the accounting and monitoring methods used to estimate emissions.

  3. Assessment of biomass open burning emissions in Indonesia and potential climate forcing impact

    NASA Astrophysics Data System (ADS)

    Permadi, Didin Agustian; Kim Oanh, Nguyen Thi

    2013-10-01

    This paper presents an emission inventory (EI) for biomass open burning (OB) sources including forest, agro-residue and municipal solid waste (MSW) in Indonesia for year 2007. The EI covered toxic air pollutants and greenhouse gases (GHGs) and was presented as annual and monthly average for every district, and further on a grid of 0.25° × 0.25°. A rigorous analysis of activity data and emission factor ranges was done to produce the low, best and high emission estimates for each species. Development of EI methodology for MSW OB which, to our best knowledge, has not been presented in detail in the literature was a focus of this paper. The best estimates of biomass OB emission of toxic air pollutants for the country, in Gg, were: 9.6 SO2; 98 NOx; 7411 CO; 335 NMVOC; 162 NH3; 439 PM10; 357 PM2.5; 24 BC; and 147 OC. The best emission estimates of GHGs, in Gg, were: 401 CH4, 57,247 CO2; and 3.6 N2O. The low and high values of the emission estimates for different species were found to range from -86% to +260% of the corresponding best estimates. Crop residue OB contributed more than 80% of the total biomass OB emissions, followed by forest fire of 2-12% (not including peat soil fire emission) and MSW (1-8%). An inter-annual active fires count for Indonesia showed relatively low values in 2007 which may be attributed to the high rainfall intensity under the influence of La Niña climate pattern in the year. Total estimated net climate forcing from OB in Indonesia was 110 (20 year horizon) and 73 (100 year horizon) Tg CO2 equivalents which is around 0.9-1.1% of that reported for the global biomass OB for both time horizons. The spatial distribution showed higher emissions in large urban areas in Java and Sumatra Island, while the monthly emissions indicated higher values during the dry months of August-October.

  4. Frozen Cropland Soil in Northeast China as Source of N2O and CO2 Emissions

    PubMed Central

    Qiao, Yunfa; Han, Xiaozeng; Brancher Franco, Roberta

    2014-01-01

    Agricultural soils are important sources of atmospheric N2O and CO2. However, in boreal agro-ecosystems the contribution of the winter season to annual emissions of these gases has rarely been determined. In this study, soil N2O and CO2 fluxes were measured for 6 years in a corn-soybean-wheat rotation in northeast China to quantify the contribution of wintertime N2O and CO2 fluxes to annual emissions. The treatments were chemical fertilizer (NPK), chemical fertilizer plus composted pig manure (NPKOM), and control (Cont.). Mean soil N2O fluxes among all three treatments in the winter (November–March), when soil temperatures are below −7°C for extended periods, were 0.89–3.01 µg N m−2 h−1, and in between the growing season and winter (October and April), when freeze-thaw events occur, 1.73–5.48 µg N m−2 h−1. The cumulative N2O emissions were on average 0.27–1.39, 0.03–0.08 and 0.03–0.11 kg N2O–N ha−1 during the growing season, October and April, and winter, respectively. The average contributions of winter N2O efflux to annual emissions were 6.3–12.1%. In all three seasons, the highest N2O emissions occurred in NPKOM, while NPK and Cont. emissions were similar. Cumulative CO2 emissions were 2.73–4.94, 0.13–0.20 and 0.07–0.11 Mg CO2-C ha−1 during growing season, October and April, and winter, respectively. The contribution of winter CO2 to total annual emissions was 2.0–2.4%. Our results indicate that in boreal agricultural systems in northeast China, CO2 and N2O emissions continue throughout the winter. PMID:25536036

  5. Spatial and Temporal Trends in Global Emissions of Nitrogen Oxides from 1960 to 2014.

    PubMed

    Huang, Tianbo; Zhu, Xi; Zhong, Qirui; Yun, Xiao; Meng, Wenjun; Li, Bengang; Ma, Jianmin; Zeng, Eddy Y; Tao, Shu

    2017-07-18

    The quantification of nitrogen oxide (NO x ) emissions is critical for air quality modeling. Based on updated fuel consumption and emission factor databases, a global emission inventory was compiled with high spatial (0.1° × 0.1°), temporal (monthly), and source (87 sources) resolutions for the period 1960 to 2014. The monthly emission data have been uploaded online ( http://inventory.pku.edu.cn ), along with a number of other air pollutant and greenhouse gas data for free download. Differences in source profiles, not global total quantities, between our results and those reported previously were found. There were significant differences in total and per capita emissions and emission intensities among countries, especially between the developing and developed countries. Globally, the total annual NO x emissions finally stopped increasing in 2013 after continuously increasing over several decades, largely due to strict control measures taken in China in recent years. Nevertheless, the peak year of NO x emissions was later than for many other major air pollutants. Per capita emissions, either among countries or over years, follow typical inverted U-shaped environmental Kuznets curves, indicating that the emissions increased during the early stage of development and were restrained when socioeconomic development reached certain points. Although the trends are similar among countries, the turning points of developing countries appeared sooner than those of developed countries in terms of development status, confirming late-move advantages.

  6. How do emission patterns in megacities affect regional air pollution?

    NASA Astrophysics Data System (ADS)

    Heil, A.; Richter, C.; Schroeder, S.; Schultz, M. G.

    2010-12-01

    ) creation potential. Compared to the emissions used in the reference simulation, changing per capita urban emissions in BNL into those of IST or SAP will lead to reduction in total megacity emissions of CO and NOx by between 40 to 80% and of between 5 to 20% for NMVOC. When the per capita emissions for PRD are applied, only NOx decreases (by 50%) while CO and NMVOC increase by between 20 and 40%. Similar changes occur when the emissions are interchanged in the other three regions. Annual mean ambient O_3 concentrations in the entire BNL megacity domain are elevated by 3 to 8 ppb in all sensitivity runs and a significant effect is also found outside the main megacity area. In the IST and PRD megacity areas, O_3 levels increase or decrease by 1 to 5 ppb when the per capita emissions from the other regions are used. For the SAP megacity area, all scenarios lead to a reduction of annual mean O_3 levels by more than 4 ppb in the north-western section of the domain while increases up to 3 ppb are predicted for some southern regions. We will also present an analysis of changes in the photochemical regimes related to altered emission patterns. The study can contribute directly to the development of air pollution abatement strategies.

  7. Global mercury emissions from combustion in light of international fuel trading.

    PubMed

    Chen, Yilin; Wang, Rong; Shen, Huizhong; Li, Wei; Chen, Han; Huang, Ye; Zhang, Yanyan; Chen, Yuanchen; Su, Shu; Lin, Nan; Liu, Junfeng; Li, Bengang; Wang, Xilong; Liu, Wenxin; Coveney, Raymond M; Tao, Shu

    2014-01-01

    The spatially resolved emission inventory is essential for understanding the fate of mercury. Previous global mercury emission inventories for fuel combustion sources overlooked the influence of fuel trading on local emission estimates of many countries, mostly developing countries, for which national emission data are not available. This study demonstrates that in many countries, the mercury content of coal and petroleum locally consumed differ significantly from those locally produced. If the mercury content in locally produced fuels were used to estimate emission, then the resulting global mercury emissions from coal and petroleum would be overestimated by 4.7 and 72%, respectively. Even higher misestimations would exist in individual countries, leading to strong spatial bias. On the basis of the available data on fuel trading and an updated global fuel consumption database, a new mercury emission inventory for 64 combustion sources has been developed. The emissions were mapped at 0.1° × 0.1° resolution for 2007 and at country resolution for a period from 1960 to 2006. The estimated global total mercury emission from all combustion sources (fossil fuel, biomass fuel, solid waste, and wildfires) in 2007 was 1454 Mg (1232-1691 Mg as interquartile range from Monte Carlo simulation), among which elementary mercury (Hg(0)), divalent gaseous mercury (Hg(2+)), and particulate mercury (Hg(p)) were 725, 548, and 181 Mg, respectively. The total emission from anthropogenic sources, excluding wildfires, was 1040 Mg (886-1248 Mg), with coal combustion contributing more than half. Globally, total annual anthropogenic mercury emission from combustion sources increased from 285 Mg (263-358 Mg) in 1960 to 1040 Mg (886-1248 Mg) in 2007, owing to an increased fuel consumption in developing countries. However, mercury emissions from developed countries have decreased since 2000.

  8. Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions.

    PubMed

    Shen, Huizhong; Huang, Ye; Wang, Rong; Zhu, Dan; Li, Wei; Shen, Guofeng; Wang, Bin; Zhang, Yanyan; Chen, Yuanchen; Lu, Yan; Chen, Han; Li, Tongchao; Sun, Kang; Li, Bengang; Liu, Wenxin; Liu, Junfeng; Tao, Shu

    2013-06-18

    Global atmospheric emissions of 16 polycyclic aromatic hydrocarbons (PAHs) from 69 major sources were estimated for a period from 1960 to 2030. Regression models and a technology split method were used to estimate country and time specific emission factors, resulting in a new estimate of PAH emission factor variation among different countries and over time. PAH emissions in 2007 were spatially resolved to 0.1° × 0.1° grids based on a newly developed global high-resolution fuel combustion inventory (PKU-FUEL-2007). The global total annual atmospheric emission of 16 PAHs in 2007 was 504 Gg (331-818 Gg, as interquartile range), with residential/commercial biomass burning (60.5%), open-field biomass burning (agricultural waste burning, deforestation, and wildfire, 13.6%), and petroleum consumption by on-road motor vehicles (12.8%) as the major sources. South (87 Gg), East (111 Gg), and Southeast Asia (52 Gg) were the regions with the highest PAH emission densities, contributing half of the global total PAH emissions. Among the global total PAH emissions, 6.19% of the emissions were in the form of high molecular weight carcinogenic compounds and the percentage of the carcinogenic PAHs was higher in developing countries (6.22%) than in developed countries (5.73%), due to the differences in energy structures and the disparities of technology. The potential health impact of the PAH emissions was greatest in the parts of the world with high anthropogenic PAH emissions, because of the overlap of the high emissions and high population densities. Global total PAH emissions peaked at 592 Gg in 1995 and declined gradually to 499 Gg in 2008. Total PAH emissions from developed countries peaked at 122 Gg in the early 1970s and decreased to 38 Gg in 2008. Simulation of PAH emissions from 2009 to 2030 revealed that PAH emissions in developed and developing countries would decrease by 46-71% and 48-64%, respectively, based on the six IPCC SRES scenarios.

  9. Global atmospheric emissions of polycyclic aromatic hydrocarbons from 1960 to 2008 and future predictions

    PubMed Central

    Shen, Huizhong; Huang, Ye; Wang, Rong; Zhu, Dan; Li, Wei; Shen, Guofeng; Wang, Bin; Zhang, Yanyan; Chen, Yuanchen; Lu, Yan; Chen, Han; Li, Tongchao; Sun, Kang; Li, Bengang; Liu, Wenxin; Liu, Junfeng; Tao, Shu

    2013-01-01

    Global atmospheric emissions of 16 polycyclic aromatic hydrocarbons (PAHs) from 69 major sources were estimated for a period from 1960 to 2030. Regression models and a technology split method were used to estimate country and time specific emission factors, resulting in a new estimate of PAH emission factor variation among different countries and over time. PAH emissions in 2007 were spatially resolved to 0.1°× 0.1° grids based on a newly developed global high-resolution fuel combustion inventory (PKU-FUEL-2007). The global total annual atmospheric emission of 16 PAHs in 2007 was 504 Gg (331-818 Gg, as interquartile range), with residential/commercial biomass burning (60.5%), open-field biomass burning (agricultural waste burning, deforestation, and wildfire, 13.6%), and petroleum consumption by on-road motor vehicles (12.8%) as the major sources. South (87 Gg), East (111 Gg), and Southeast Asia (52 Gg) were the regions with the highest PAH emission densities, contributing half of the global total PAH emissions. Among the global total PAH emissions, 6.19% of the emissions were in the form of high molecular weight carcinogenic compounds and the percentage of the carcinogenic PAHs was higher in developing countries (6.22%) than in developed countries (5.73%), due to the differences in energy structures and the disparities of technology. The potential health impact of the PAH emissions was greatest in the parts of the world with high anthropogenic PAH emissions, because of the overlap of the high emissions and high population densities. Global total PAH emissions peaked at 592 Gg in 1995 and declined gradually to 499 Gg in 2008. Total PAH emissions from developed countries peaked at 122 Gg in the early 1970s and decreased to 38 Gg in 2008. Simulation of PAH emissions from 2009 to 2030 revealed that PAH emissions in developed and developing countries would decrease by 46-71% and 48-64%, respectively, based on the six IPCC SRES scenarios. PMID:23659377

  10. Total particle, sulfate, and acidic aerosol emissions from kerosene space heaters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Leaderer, B.P.; Boone, P.M.; Hammond, S.K.

    1990-06-01

    Chamber studies were conducted on four unvented kerosene space heaters to assess emissions of total particle, sulfate, and acidic aerosol. The heaters tested represented four burner designs currently in use by the public. Kerosene space heaters are a potential source of fine particles ({<=} 2.5-{mu}m diameter), sulfate, and acidic aerosol indoors. Fine particle concentrations in homes in which the heaters are used may be increased in excess of 20 {mu}g/m{sup 3} over background levels. Sulfate and acidic aerosol levels in such homes could exceed average and peak outdoor concentrations. Maltuned heaters could produce exceptionally high levels of all air contaminantsmore » measured.« less

  11. Total particle, sulfate, and acidic aerosol emissions from kerosene space heaters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Leaderer, B.P.; Boone, P.M.; Hammond, S.K.

    1990-01-01

    The article discusses chamber studies of four unvented kerosene space heaters to assess emissions of total particle, sulfate, and acidic aerosol. The heaters tested represented four burner designs currently in use by the public. Kerosene space heaters are a potential source of fine particles (= or < 2.5 micrometer diameter), sulfate, and acidic aerosol indoors. Fine particle concentrations in houses in which the heaters are used may be increased in excess of 20 micrograms/m3 over background levels. Sulfate and acidic aerosol levels in such houses could exceed average and peak outdoor concentrations. Maltuned heaters could produce exceptionally high levels ofmore » all air contaminants measured.« less

  12. Cold season emissions dominate the Arctic tundra methane budget

    PubMed Central

    Zona, Donatella; Gioli, Beniamino; Lindaas, Jakob; Wofsy, Steven C.; Miller, Charles E.; Dinardo, Steven J.; Dengel, Sigrid; Sweeney, Colm; Karion, Anna; Chang, Rachel Y.-W.; Henderson, John M.; Murphy, Patrick C.; Goodrich, Jordan P.; Moreaux, Virginie; Liljedahl, Anna; Watts, Jennifer D.; Kimball, John S.; Lipson, David A.; Oechel, Walter C.

    2016-01-01

    Arctic terrestrial ecosystems are major global sources of methane (CH4); hence, it is important to understand the seasonal and climatic controls on CH4 emissions from these systems. Here, we report year-round CH4 emissions from Alaskan Arctic tundra eddy flux sites and regional fluxes derived from aircraft data. We find that emissions during the cold season (September to May) account for ≥50% of the annual CH4 flux, with the highest emissions from noninundated upland tundra. A major fraction of cold season emissions occur during the “zero curtain” period, when subsurface soil temperatures are poised near 0 °C. The zero curtain may persist longer than the growing season, and CH4 emissions are enhanced when the duration is extended by a deep thawed layer as can occur with thick snow cover. Regional scale fluxes of CH4 derived from aircraft data demonstrate the large spatial extent of late season CH4 emissions. Scaled to the circumpolar Arctic, cold season fluxes from tundra total 12 ± 5 (95% confidence interval) Tg CH4 y−1, ∼25% of global emissions from extratropical wetlands, or ∼6% of total global wetland methane emissions. The dominance of late-season emissions, sensitivity to soil environmental conditions, and importance of dry tundra are not currently simulated in most global climate models. Because Arctic warming disproportionally impacts the cold season, our results suggest that higher cold-season CH4 emissions will result from observed and predicted increases in snow thickness, active layer depth, and soil temperature, representing important positive feedbacks on climate warming. PMID:26699476

  13. Cold season emissions dominate the Arctic tundra methane budget

    DOE PAGES

    Zona, Donatella; Gioli, Beniamino; Commane, Róisín; ...

    2015-12-22

    Arctic terrestrial ecosystems are major global sources of methane (CH 4); hence, it is important to understand the seasonal and climatic controls on CH 4 emissions from these systems. Here, we report year-round CH 4 emissions from Alaskan Arctic tundra eddy flux sites and regional fluxes derived from aircraft data. We find that emissions during the cold season (September to May) account for ≥ 50% of the annual CH 4 flux, with the highest emissions from noninundated upland tundra. A major fraction of cold season emissions occur during the “zero curtain” period, when subsurface soil temperatures are poised near 0more » °C. The zero curtain may persist longer than the growing season, and CH 4 emissions are enhanced when the duration is extended by a deep thawed layer as can occur with thick snow cover. Regional scale fluxes of CH 4 derived from aircraft data demonstrate the large spatial extent of late season CH 4 emissions. Scaled to the circumpolar Arctic, cold season fluxes from tundra total 12 ± 5 (95% confidence interval) Tg CH 4 y –1, ~25% of global emissions from extratropical wetlands, or ~6% of total global wetland methane emissions. Here, the dominance of late-season emissions, sensitivity to soil environmental conditions, and importance of dry tundra are not currently simulated in most global climate models. Because Arctic warming disproportionally impacts the cold season, our results suggest that higher cold-season CH 4 emissions will result from observed and predicted increases in snow thickness, active layer depth, and soil temperature, representing important positive feedbacks on climate warming.« less

  14. Nitrous oxide emissions in cover crop-based corn production systems

    NASA Astrophysics Data System (ADS)

    Davis, Brian Wesley

    Nitrous oxide (N2O) is a potent greenhouse gas; the majority of N2O emissions are the result of agricultural management, particularly the application of N fertilizers to soils. The relationship of N2O emissions to varying sources of N (manures, mineral fertilizers, and cover crops) has not been well-evaluated. Here we discussed a novel methodology for estimating precipitation-induced pulses of N2O using flux measurements; results indicated that short-term intensive time-series sampling methods can adequately describe the magnitude of these pulses. We also evaluated the annual N2O emissions from corn-cover crop (Zea mays; cereal rye [Secale cereale], hairy vetch [Vicia villosa ], or biculture) production systems when fertilized with multiple rates of subsurface banded poultry litter, as compared with tillage incorporation or mineral fertilizer. N2O emissions increased exponentially with total N rate; tillage decreased emissions following cover crops with legume components, while the effect of mineral fertilizer was mixed across cover crops.

  15. Inventory of anthropogenic methane emissions in mainland China from 1980 to 2010

    NASA Astrophysics Data System (ADS)

    Peng, Shushi; Piao, Shilong; Bousquet, Philippe; Ciais, Philippe; Li, Bengang; Lin, Xin; Tao, Shu; Wang, Zhiping; Zhang, Yuan; Zhou, Feng

    2016-11-01

    Methane (CH4) has a 28-fold greater global warming potential than CO2 over 100 years. Atmospheric CH4 concentration has tripled since 1750. Anthropogenic CH4 emissions from China have been growing rapidly in the past decades and contribute more than 10 % of global anthropogenic CH4 emissions with large uncertainties in existing global inventories, generally limited to country-scale statistics. To date, a long-term CH4 emission inventory including the major sources sectors and based on province-level emission factors is still lacking. In this study, we produced a detailed annual bottom-up inventory of anthropogenic CH4 emissions from the eight major source sectors in China for the period 1980-2010. In the past 3 decades, the total CH4 emissions increased from 24.4 [18.6-30.5] Tg CH4 yr-1 in 1980 (mean [minimum-maximum of 95 % confidence interval]) to 44.9 [36.6-56.4] Tg CH4 yr-1 in 2010. Most of this increase took place in the 2000s decade with averaged yearly emissions of 38.5 [30.6-48.3] Tg CH4 yr-1. This fast increase of the total CH4 emissions after 2000 is mainly driven by CH4 emissions from coal exploitation. The largest contribution to total CH4 emissions also shifted from rice cultivation in 1980 to coal exploitation in 2010. The total emissions inferred in this work compare well with the EPA inventory but appear to be 36 and 18 % lower than the EDGAR4.2 inventory and the estimates using the same method but IPCC default emission factors, respectively. The uncertainty of our inventory is investigated using emission factors collected from state-of-the-art published literatures. We also distributed province-scale emissions into 0.1° × 0.1° maps using socioeconomic activity data. This new inventory could help understanding CH4 budgets at regional scale and guiding CH4 mitigation policies in China.

  16. Recent NASA/GSFC cryogenic measurements of the total hemispheric emissivity of black surface preparations

    NASA Astrophysics Data System (ADS)

    Tuttle, J.; Canavan, E.

    2015-12-01

    High-emissivity (black) surfaces are commonly used on deep-space radiators and thermal radiation absorbers in test chambers. Since 2011 NASA Goddard Space Flight Center has measured the total hemispheric emissivity of such surfaces from 20 to 300 K using a test apparatus inside a small laboratory cryostat. We report the latest data from these measurements, including Aeroglaze Z307 paint, Black Kapton, and a configuration of painted aluminum honeycomb that was not previously tested. We also present the results of batch-to- batch reproducibility studies in Ball Infrared BlackTM and painted aluminum honeycomb. Finally, we describe a recently-adopted temperature control method which significantly speeds the data acquisition, and we discuss efforts to reduce the noise in future data.

  17. The contribution of evaporative emissions from gasoline vehicles to the volatile organic compound inventory in Mexico City.

    PubMed

    Schifter, I; Díaz, L; Rodríguez, R; González-Macías, C

    2014-06-01

    The strategy for decreasing volatile organic compound emissions in Mexico has been focused much more on tailpipe emissions than on evaporative emissions, so there is very little information on the contribution of evaporative emissions to the total volatile organic compound inventory. We examined the magnitudes of exhaust and evaporative volatile organic compound emissions, and the species emitted, in a representative fleet of light-duty gasoline vehicles in the Metropolitan Area of Mexico City. The US "FTP-75" test protocol was used to estimate volatile organic compound emissions associated with diurnal evaporative losses, and when the engine is started and a journey begins. The amount and nature of the volatile organic compounds emitted under these conditions have not previously been accounted in the official inventory of the area. Evaporative emissions from light-duty vehicles in the Metropolitan Area of Mexico City were estimated to be 39 % of the total annual amount of hydrocarbons emitted. Vehicles built before 1992 (16 % of the fleet) were found to be responsible for 43 % of the total hydrocarbon emissions from exhausts and 31 % of the evaporative emissions of organic compounds. The relatively high amounts of volatile organic compounds emitted from older vehicles found in this study show that strong emission controls need to be implemented in order to decrease the contribution of evaporative emissions of this fraction of the fleet.

  18. Methane Emissions from United States Natural Gas Gathering and Processing.

    PubMed

    Marchese, Anthony J; Vaughn, Timothy L; Zimmerle, Daniel J; Martinez, David M; Williams, Laurie L; Robinson, Allen L; Mitchell, Austin L; Subramanian, R; Tkacik, Daniel S; Roscioli, Joseph R; Herndon, Scott C

    2015-09-01

    New facility-level methane (CH4) emissions measurements obtained from 114 natural gas gathering facilities and 16 processing plants in 13 U.S. states were combined with facility counts obtained from state and national databases in a Monte Carlo simulation to estimate CH4 emissions from U.S. natural gas gathering and processing operations. Total annual CH4 emissions of 2421 (+245/-237) Gg were estimated for all U.S. gathering and processing operations, which represents a CH4 loss rate of 0.47% (±0.05%) when normalized by 2012 CH4 production. Over 90% of those emissions were attributed to normal operation of gathering facilities (1697 +189/-185 Gg) and processing plants (506 +55/-52 Gg), with the balance attributed to gathering pipelines and processing plant routine maintenance and upsets. The median CH4 emissions estimate for processing plants is a factor of 1.7 lower than the 2012 EPA Greenhouse Gas Inventory (GHGI) estimate, with the difference due largely to fewer reciprocating compressors, and a factor of 3.0 higher than that reported under the EPA Greenhouse Gas Reporting Program. Since gathering operations are currently embedded within the production segment of the EPA GHGI, direct comparison to our results is complicated. However, the study results suggest that CH4 emissions from gathering are substantially higher than the current EPA GHGI estimate and are equivalent to 30% of the total net CH4 emissions in the natural gas systems GHGI. Because CH4 emissions from most gathering facilities are not reported under the current rule and not all source categories are reported for processing plants, the total CH4 emissions from gathering and processing reported under the EPA GHGRP (180 Gg) represents only 14% of that tabulated in the EPA GHGI and 7% of that predicted from this study.

  19. Does extreme precipitation intensity depend on the emissions scenario?

    NASA Astrophysics Data System (ADS)

    Pendergrass, Angeline; Lehner, Flavio; Sanderson, Benjamin; Xu, Yangyang

    2016-04-01

    The rate of increase of global-mean precipitation per degree surface temperature increase differs for greenhouse gas and aerosol forcings, and therefore depends on the change in composition of the emissions scenario used to drive climate model simulations for the remainder of the century. We investigate whether or not this is also the case for extreme precipitation simulated by a multi-model ensemble driven by four realistic emissions scenarios. In most models, the rate of increase of maximum annual daily rainfall per degree global warming in the multi-model ensemble is statistically indistinguishable across the four scenarios, whether this extreme precipitation is calculated globally, over all land, or over extra-tropical land. These results indicate that, in most models, extreme precipitation depends on the total amount of warming and does not depend on emissions scenario, in contrast to mean precipitation.

  20. Impact of using fishing boat fuel with high poly aromatic content on the emission of polycyclic aromatic hydrocarbons from the diesel engine

    NASA Astrophysics Data System (ADS)

    Lin, Yuan-Chung; Lee, Wen-Jhy; Li, Hsing-Wang; Chen, Chung-Ban; Fang, Guor-Cheng; Tsai, Perng-Jy

    Because of the fishery subsidy policy, the fishing boat fuel oil (FBFO) exemption from commodity taxes, business taxes and air pollution control fees, resulted in the price of FBFO was ˜50% lower than premium diesel fuel (PDF) in Taiwan. It is estimated that ˜650,000 kL FBFO was illegally used by traveling diesel-vehicles (TDVs) with a heavy-duty diesel engine (HDDE), which accounted for ˜16.3% of the total diesel fuel consumed by TDVs. In this study, sulfur, poly aromatic and total-aromatic contents in both FBFO and PDF were measured and compared. Exhaust emissions of polycyclic aromatic hydrocarbons (PAHs) and their carcinogenic potencies (BaP eq) from a HDDE under transient cycle testing for both FBFO and PDF were compared and discussed. Finally, the impact caused by the illegal use of FBFO on the air quality was examined. Results show that the mean sulfur-, poly aromatic and aromatic-contents in FBFO were 43.0, 3.89 and 1.04 times higher than that of PDF, respectively. Emission factors of total-PAHs and total-BaP eq obtained by utilizing FBFO were 51.5 and 0.235 mg L -1-Fuel, which were 3.41 and 5.82 times in magnitude higher than obtained by PDF, respectively. The estimated annual emissions of total-PAHs and total-BaP eq to the ambient environment due to the illegally used FBFO were 23.6 and 0.126 metric tons, respectively, which resulted in a 17.9% and a 25.0% increment of annual emissions from all mobile sources, respectively. These results indicated that the FBFO used illegally by TDVs had a significant impact on PAH emissions to the ambient environment.

  1. Inter-annual trend of the primary contribution of ship emissions to PM2.5 concentrations in Venice (Italy): Efficiency of emissions mitigation strategies

    NASA Astrophysics Data System (ADS)

    Contini, Daniele; Gambaro, Andrea; Donateo, Antonio; Cescon, Paolo; Cesari, Daniela; Merico, Eva; Belosi, Franco; Citron, Marta

    2015-02-01

    Ships and harbour emissions are currently increasing, due to the increase of tourism and trade, with potential impact on global air pollution and climate. At local scale, in-port ship emissions influence air quality in coastal areas impacting on health of coastal communities. International legislations to reduce ship emissions, both at Worldwide and European levels, are mainly based on the use of low-sulphur content fuel. In this work an analysis of the inter-annual trends of primary contribution, ε, of tourist shipping to the atmospheric PM2.5 concentrations in the urban area of Venice has been performed. Measurements have been taken in the summer periods of 2007, 2009 and 2012. Results show a decrease of ε from 7% (±1%) in 2007 to 5% (±1%) in 2009 and to 3.5% (±1%) in 2012. The meteorological and micrometeorological conditions of the campaigns were similar. Tourist ship traffic during measurement campaigns increased, in terms of gross tonnage, of about 25.4% from 2007 to 2009 and of 17.6% from 2009 to 2012. The decrease of ε was associated to the effect of a voluntary agreement (Venice Blue Flag) for the use of low-sulphur content fuel enforced in the area between 2007 and 2009 and to the implementation of the 2005/33/CE Directive in 2010. Results show that the use of low-sulphur fuel could effectively reduce the impact of shipping to atmospheric primary particles at local scale. Further, voluntary agreement could also be effective in reducing the impact of shipping on local air quality in coastal areas.

  2. U.S. broiler housing ammonia emissions inventory

    NASA Astrophysics Data System (ADS)

    Gates, R. S.; Casey, K. D.; Wheeler, E. F.; Xin, H.; Pescatore, A. J.

    Using recently published baseline ammonia emissions data for U.S. broiler chicken housing, we present a method of estimating their contribution to an annual ammonia budget that is different from that used by USEPA. Emission rate increases in a linear relationship with flock age from near zero at the start of the flock to a maximum at the end of the flock, 28-65 days later. Market weight of chickens raised for meat varies from "broilers" weighing about 2 kg to "roasters" weighing about 3 kg. Multiple flocks of birds are grown in a single house annually, with variable downtime to prepare the house between flocks. The method takes into account weight and number of chickens marketed. Uncertainty in baseline emissions estimates is used so that inventory estimates are provided with error estimates. The method also incorporates the condition of litter that birds are raised upon and the varying market weight of birds grown. Using 2003 USDA data on broiler production numbers, broiler housing is estimated to contribute 8.8-11.7 kT ammonia for new and built-up litter, respectively, in Kentucky and 240-324 kT ammonia for new and built-up litter, respectively, nationally. Results suggest that a 10% uncertainty in annual emission rate is expected for the market weight categories of broilers, heavy broilers, and roasters. A 27-47% reduction in annual housing emission rate is predicted if new rather than built-up litter were used for every flock. The estimating method can be adapted to other meat bird building emissions and future ammonia emission strategies, with suitable insertion of an age-dependent emission factor or slope into a predictive model equation. The method can be readily applied and is an alternative to that used by USEPA.

  3. Trends and Projected Estimates of GHG Emissions from Indian Livestock in Comparisons with GHG Emissions from World and Developing Countries.

    PubMed

    Patra, Amlan Kumar

    2014-04-01

    This study presents trends and projected estimates of methane and nitrous oxide emissions from livestock of India vis-à-vis world and developing countries over the period 1961 to 2010 estimated based on IPCC guidelines. World enteric methane emission (EME) increased by 54.3% (61.5 to 94.9 ×10(9) kg annually) from the year 1961 to 2010, and the highest annual growth rate (AGR) was noted for goat (2.0%), followed by buffalo (1.57%) and swine (1.53%). Global EME is projected to increase to 120×10(9) kg by 2050. The percentage increase in EME by Indian livestock was greater than world livestock (70.6% vs 54.3%) between the years 1961 to 2010, and AGR was highest for goat (1.91%), followed by buffalo (1.55%), swine (1.28%), sheep (1.25%) and cattle (0.70%). In India, total EME was projected to grow by 18.8×10(9) kg in 2050. Global methane emission from manure (MEM) increased from 6.81 ×10(9) kg in 1961 to 11.4×10(9) kg in 2010 (an increase of 67.6%), and is projected to grow to 15×10(9) kg by 2050. In India, the annual MEM increased from 0.52×10(9) kg to 1.1×10(9) kg (with an AGR of 1.57%) in this period, which could increase to 1.54×10(9) kg in 2050. Nitrous oxide emission from manure in India could be 21.4×10(6) kg in 2050 from 15.3×10(6) kg in 2010. The AGR of global GHG emissions changed a small extent (only 0.11%) from developed countries, but increased drastically (1.23%) for developing countries between the periods of 1961 to 2010. Major contributions to world GHG came from cattle (79.3%), swine (9.57%) and sheep (7.40%), and for developing countries from cattle (68.3%), buffalo (13.7%) and goat (5.4%). The increase of GHG emissions by Indian livestock was less (74% vs 82% over the period of 1961 to 2010) than the developing countries. With this trend, world GHG emissions could reach 3,520×10(9) kg CO2-eq by 2050 due to animal population growth driven by increased demands for meat and dairy products in the world.

  4. Trends and Projected Estimates of GHG Emissions from Indian Livestock in Comparisons with GHG Emissions from World and Developing Countries

    PubMed Central

    Patra, Amlan Kumar

    2014-01-01

    This study presents trends and projected estimates of methane and nitrous oxide emissions from livestock of India vis-à-vis world and developing countries over the period 1961 to 2010 estimated based on IPCC guidelines. World enteric methane emission (EME) increased by 54.3% (61.5 to 94.9 ×109 kg annually) from the year 1961 to 2010, and the highest annual growth rate (AGR) was noted for goat (2.0%), followed by buffalo (1.57%) and swine (1.53%). Global EME is projected to increase to 120×109 kg by 2050. The percentage increase in EME by Indian livestock was greater than world livestock (70.6% vs 54.3%) between the years 1961 to 2010, and AGR was highest for goat (1.91%), followed by buffalo (1.55%), swine (1.28%), sheep (1.25%) and cattle (0.70%). In India, total EME was projected to grow by 18.8×109 kg in 2050. Global methane emission from manure (MEM) increased from 6.81 ×109 kg in 1961 to 11.4×109 kg in 2010 (an increase of 67.6%), and is projected to grow to 15×109 kg by 2050. In India, the annual MEM increased from 0.52×109 kg to 1.1×109 kg (with an AGR of 1.57%) in this period, which could increase to 1.54×109 kg in 2050. Nitrous oxide emission from manure in India could be 21.4×106 kg in 2050 from 15.3×106 kg in 2010. The AGR of global GHG emissions changed a small extent (only 0.11%) from developed countries, but increased drastically (1.23%) for developing countries between the periods of 1961 to 2010. Major contributions to world GHG came from cattle (79.3%), swine (9.57%) and sheep (7.40%), and for developing countries from cattle (68.3%), buffalo (13.7%) and goat (5.4%). The increase of GHG emissions by Indian livestock was less (74% vs 82% over the period of 1961 to 2010) than the developing countries. With this trend, world GHG emissions could reach 3,520×109 kg CO2-eq by 2050 due to animal population growth driven by increased demands for meat and dairy products in the world. PMID:25049993

  5. Endosulfan in China 2-emissions and residues.

    PubMed

    Jia, Hongliang; Sun, Yeqing; Li, Yi-Fan; Tian, Chongguo; Wang, Degao; Yang, Meng; Ding, Yongshen; Ma, Jianmin

    2009-05-01

    Endosulfan is one of the organochlorine pesticides (OCPs) and also a candidate to be included in a group of new persistent organic pollutants (UNEP 2007). The first national endosulfan usage inventories in China with 1/4 degrees longitude by 1/6 degrees latitude resolution has been reported in an accompanying paper. In the second part of the paper, we compiled the gridded historical emissions and soil residues of endosulfan in China from the usage inventories. Based on the residue/emission data, gridded concentrations of endosulfan in Chinese soil and air have been calculated. These inventories will provide valuable data for the further study of endosulfan. Emission and residue of endosulfan were calculated from endosulfan usage by using a simplified gridded pesticide emission and residue model-SGPERM, which is an integrated modeling system combining mathematical model, database management system, and geographic information system. By using the emission and residue inventories, annual air and soil concentrations of endosulfan in each cell were determined. Historical gridded emission and residue inventories of alpha- and beta-endosulfan in agricultural soil in China with 1/4 degrees longitude by 1/6 degrees latitude resolution have been created. Total emissions were around 10,800 t, with alpha-endosulfan at 7,400 t and beta-endosulfan at 3,400 t from 1994 to 2004. The highest residues were 140 t for alpha-endosulfan and 390 t for beta-endosulfan, and the lowest residues were 0.7 t for alpha-endosulfan and 170 t for beta-endosulfan in 2004 in Chinese agricultural soil where endosulfan was applied. Based on the emission and residue inventories, concentrations of alpha- and beta-endosulfan in Chinese air and agricultural surface soil were also calculated for each grid cell. We have estimated annual averaged air concentrations and the annual minimum and maximum soil concentrations across China. The real concentrations will be different from season to season. Although

  6. Assessment of conservation easements, total phosphorus, and total suspended solids in West Fork Beaver Creek, Minnesota, 1999-2012

    USGS Publications Warehouse

    Christensen, Victoria G.; Kieta, Kristen A.

    2014-01-01

    This study examined conservation easements and their effectiveness at reducing phosphorus and solids transport to streams. The U.S. Geological Survey cooperated with the Minnesota Board of Water and Soil Resources and worked collaboratively with the Hawk Creek Watershed Project to examine the West Fork Beaver Creek Basin in Renville County, which has the largest number of Reinvest In Minnesota land retirement contracts in the State (as of 2013). Among all conservation easement programs, a total of 24,218 acres of agricultural land were retired throughout Renville County, and 2,718 acres were retired in the West Fork Beaver Creek Basin from 1987 through 2012. Total land retirement increased steadily from 1987 until 2000. In 2000, land retirement increased sharply because of the Minnesota River Conservation Reserve Enhancement Program, then leveled off when the program ended in 2002. Streamflow data were collected during 1999 through 2011, and total phosphorus and total suspended solids data were collected during 1999 through 2012. During this period, the highest peak streamflow of 1,320 cubic feet per second was in March 2010. Total phosphorus and total suspended solids are constituents that tend to increase with increases in streamflow. Annual flow-weighted mean total-phosphorus concentrations ranged from 0.140 to 0.759 milligrams per liter, and annual flow-weighted mean total suspended solids concentrations ranged from 21.3 to 217 milligrams per liter. Annual flow-weighted mean total phosphorus and total suspended solids concentrations decreased steadily during the first 4 years of water-quality sample collection. A downward trend in flow-weighted mean total-phosphorus concentrations was significant from 1999 through 2008; however, flow-weighted total-phosphorus concentrations increased substantially in 2009, and the total phosphorus trend was no longer significant. The high annual flow-weighted mean concentrations for total phosphorus and total suspended solids

  7. Aircraft-Based Measurements of Point Source Methane Emissions in the Barnett Shale Basin.

    PubMed

    Lavoie, Tegan N; Shepson, Paul B; Cambaliza, Maria O L; Stirm, Brian H; Karion, Anna; Sweeney, Colm; Yacovitch, Tara I; Herndon, Scott C; Lan, Xin; Lyon, David

    2015-07-07

    We report measurements of methane (CH4) emission rates observed at eight different high-emitting point sources in the Barnett Shale, Texas, using aircraft-based methods performed as part of the Barnett Coordinated Campaign. We quantified CH4 emission rates from four gas processing plants, one compressor station, and three landfills during five flights conducted in October 2013. Results are compared to other aircraft- and surface-based measurements of the same facilities, and to estimates based on a national study of gathering and processing facilities emissions and 2013 annual average emissions reported to the U.S. EPA Greenhouse Gas Reporting Program (GHGRP). For the eight sources, CH4 emission measurements from the aircraft-based mass balance approach were a factor of 3.2-5.8 greater than the GHGRP-based estimates. Summed emissions totaled 7022 ± 2000 kg hr(-1), roughly 9% of the entire basin-wide CH4 emissions estimated from regional mass balance flights during the campaign. Emission measurements from five natural gas management facilities were 1.2-4.6 times larger than emissions based on the national study. Results from this study were used to represent "super-emitters" in a newly formulated Barnett Shale Inventory, demonstrating the importance of targeted sampling of "super-emitters" that may be missed by random sampling of a subset of the total.

  8. N2O, NO, N2 and CO2 emissions from tropical savanna and grassland of northern Australia: an incubation experiment with intact soil cores

    NASA Astrophysics Data System (ADS)

    Werner, C.; Reiser, K.; Dannenmann, M.; Hutley, L. B.; Jacobeit, J.; Butterbach-Bahl, K.

    2014-11-01

    Strong seasonal variability of hygric and thermal soil conditions are a defining environmental feature in northern Australia. However, how such changes affect the soil-atmosphere exchange of nitrous oxide (N2O), nitric oxide (NO) and dinitrogen (N2) is still not well explored. By incubating intact soil cores from four sites (three savanna, one pasture) under controlled soil temperatures (ST) and soil moisture (SM) we investigated the release of the trace gas fluxes of N2O, NO and carbon dioxide (CO2). Furthermore, the release of N2 due to denitrification was measured using the helium gas flow soil core technique. Under dry pre-incubation conditions NO and N2O emissions were very low (<7.0 ± 5.0 μg NO-N m-2 h-1; <0.0 ± 1.4 μg N2O-N m-2 h-1) or in the case of N2O, even a net soil uptake was observed. Substantial NO (max: 306.5 μg N m-2 h-1) and relatively small N2O pulse emissions (max: 5.8 ± 5.0 μg N m-2 h-1) were recorded following soil wetting, but these pulses were short lived, lasting only up to 3 days. The total atmospheric loss of nitrogen was generally dominated by N2 emissions (82.4-99.3% of total N lost), although NO emissions contributed almost 43.2% to the total atmospheric nitrogen loss at 50% SM and 30 °C ST incubation settings (the contribution of N2 at these soil conditions was only 53.2%). N2O emissions were systematically higher for 3 of 12 sample locations, which indicates substantial spatial variability at site level, but on average soils acted as weak N2O sources or even sinks. By using a conservative upscale approach we estimate total annual emissions from savanna soils to average 0.12 kg N ha-1 yr-1 (N2O), 0.68 kg N ha-1 yr-1 (NO) and 6.65 kg N ha-1 yr-1 (N2). The analysis of long-term SM and ST records makes it clear that extreme soil saturation that can lead to high N2O and N2 emissions only occurs a few days per year and thus has little impact on the annual total. The potential contribution of nitrogen released due to pulse events

  9. Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements

    DOE PAGES

    Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen; ...

    2017-06-05

    Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. In our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in themore » western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ~1/3 of the total emissions detected midday by the aircraft and ~2/3 of the west–east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. And while the aircraft approach is valid, quantitative, and independent, this study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.« less

  10. Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements.

    PubMed

    Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen; Pickering, Cody; Mielke-Maday, Ingrid; Dlugokencky, Edward J; Tans, Pieter P; Vaughn, Tim; Bell, Clay; Zimmerle, Daniel; Wolter, Sonja; King, Clark W; White, Allen B; Coleman, Timothy; Bianco, Laura; Schnell, Russell C

    2017-06-20

    Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. Our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in the western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ∼1/3 of the total emissions detected midday by the aircraft and ∼2/3 of the west-east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. While the aircraft approach is valid, quantitative, and independent, our study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.

  11. Improved Mechanistic Understanding of Natural Gas Methane Emissions from Spatially Resolved Aircraft Measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schwietzke, Stefan; Pétron, Gabrielle; Conley, Stephen

    Divergence in recent oil and gas related methane emission estimates between aircraft studies (basin total for a midday window) and emissions inventories (annualized regional and national statistics) indicate the need for better understanding the experimental design, including temporal and spatial alignment and interpretation of results. In our aircraft-based methane emission estimates in a major U.S. shale gas basin resolved from west to east show (i) similar spatial distributions for 2 days, (ii) strong spatial correlations with reported NG production (R 2 = 0.75) and active gas well pad count (R 2 = 0.81), and (iii) 2× higher emissions in themore » western half (normalized by gas production) despite relatively homogeneous dry gas and well characteristics. Operator reported hourly activity data show that midday episodic emissions from manual liquid unloadings (a routine operation in this basin and elsewhere) could explain ~1/3 of the total emissions detected midday by the aircraft and ~2/3 of the west–east difference in emissions. The 22% emission difference between both days further emphasizes that episodic sources can substantially impact midday methane emissions and that aircraft may detect daily peak emissions rather than daily averages that are generally employed in emissions inventories. And while the aircraft approach is valid, quantitative, and independent, this study sheds new light on the interpretation of previous basin scale aircraft studies, and provides an improved mechanistic understanding of oil and gas related methane emissions.« less

  12. Historical (1750-2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS)

    NASA Astrophysics Data System (ADS)

    Hoesly, Rachel M.; Smith, Steven J.; Feng, Leyang; Klimont, Zbigniew; Janssens-Maenhout, Greet; Pitkanen, Tyler; Seibert, Jonathan J.; Vu, Linh; Andres, Robert J.; Bolt, Ryan M.; Bond, Tami C.; Dawidowski, Laura; Kholod, Nazar; Kurokawa, June-ichi; Li, Meng; Liu, Liang; Lu, Zifeng; Moura, Maria Cecilia P.; O'Rourke, Patrick R.; Zhang, Qiang

    2018-01-01

    We present a new data set of annual historical (1750-2014) anthropogenic chemically reactive gases (CO, CH4, NH3, NOx, SO2, NMVOCs), carbonaceous aerosols (black carbon - BC, and organic carbon - OC), and CO2 developed with the Community Emissions Data System (CEDS). We improve upon existing inventories with a more consistent and reproducible methodology applied to all emission species, updated emission factors, and recent estimates through 2014. The data system relies on existing energy consumption data sets and regional and country-specific inventories to produce trends over recent decades. All emission species are consistently estimated using the same activity data over all time periods. Emissions are provided on an annual basis at the level of country and sector and gridded with monthly seasonality. These estimates are comparable to, but generally slightly higher than, existing global inventories. Emissions over the most recent years are more uncertain, particularly in low- and middle-income regions where country-specific emission inventories are less available. Future work will involve refining and updating these emission estimates, estimating emissions' uncertainty, and publication of the system as open-source software.

  13. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado and Utah using mobile stable isotope (13CH4) analysis

    NASA Astrophysics Data System (ADS)

    Rella, Chris; Jacobson, Gloria; Crosson, Eric; Karion, Anna; Petron, Gabrielle; Sweeney, Colm

    2013-04-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation. However, given that the global warming potential of methane is many times greater than that of carbon dioxide (Solomon et al. 2007), the importance of quantifying the fugitive emissions of methane throughout the natural gas production and distribution process becomes clear (Howarth et al. 2011). A key step in the process of assessing the emissions arising from natural gas production activities is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis. In particular, the 13CH4 signature of natural gas (-35 to -40 permil) is significantly different that the signature of other significant sources of methane, such as landfills or ruminants (-45 to -70 permil). In this paper we present measurements of mobile field 13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in two intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, and the Uintah basin in Utah. Mobile isotope measurements in the nocturnal boundary layer have been made, over a total path of 100s of km throughout the regions, allowing spatially resolved measurements of the regional isotope signature. Secondly, this analyzer was used to quantify the isotopic signature of those individual sources (natural gas fugitive emissions, concentrated animal feeding operations, and landfills) that constitute the majority of methane emissions in these regions, by making measurements of the isotope ratio directly in the downwind plume from each source. These

  14. Estimates of spatially and temporally resolved constrained black carbon emission over the Indian region using a strategic integrated modelling approach

    NASA Astrophysics Data System (ADS)

    Verma, S.; Reddy, D. Manigopal; Ghosh, S.; Kumar, D. Bharath; Chowdhury, A. Kundu

    2017-10-01

    We estimated the latest spatially and temporally resolved gridded constrained black carbon (BC) emissions over the Indian region using a strategic integrated modelling approach. This was done extracting information on initial bottom-up emissions and atmospheric BC concentration from a general circulation model (GCM) simulation in conjunction with the receptor modelling approach. Monthly BC emission (83-364 Gg) obtained from the present study exhibited a spatial and temporal variability with this being the highest (lowest) during February (July). Monthly BC emission flux was considerably high (> 100 kg km- 2) over the entire Indo-Gangetic plain (IGP), east and the west coast during winter months. This was relatively higher over the central and western India than over the IGP during summer months. Annual BC emission rate was 2534 Gg y- 1 with that over the IGP and central India respectively comprising 50% and 40% of the total annual BC emissions over India. A high relative increase was observed in modified BC emissions (more than five times the initial emissions) over the most part of the IGP, east coast, central/northwestern India. The relative predominance of monthly BC emission flux over a region (as depicted from z-score distribution maps) was inferred being consistent with the prevalence of region- and season-specific anthropogenic activity.

  15. 40 CFR 98.193 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (General Stationary Fuel Combustion Sources) the combustion CO2 emissions from each lime kiln according to... must calculate and report the annual process CO2 emissions from all lime kilns combined using the... combustion CO2 emissions from all lime kilns by operating and maintaining a CEMS to measure CO2 emissions...

  16. Energy Use and Carbon Dioxide Emissions from Cropland Production in the United States, 1990-2004

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, Tristram O.; Brandt, Craig C; Marland, Gregg

    2009-01-01

    Changes in cropland production and management influence energy consumption and emissions of CO2 from fossil-fuel combustion. A method was developed to calculate on-site and off-site energy and CO2 emissions for cropping practices in the US at the county scale. Energy consumption and emissions occur on-site from the operation of farm machinery and occur off-site from the manufacture and transport of cropland production inputs, such as fertilizers, pesticides, and agricultural lime. Estimates of fossil-fuel consumption and associated CO2 emissions for cropping practices enable (a) the monitoring of energy and emissions with changes in land management, and (b) the calculation and balancingmore » of regional and national carbon budgets. Results indicate on-site energy use and total energy use (i.e., the sum of on-site and off-site) on US croplands in 2004 ranged from 1.6-7.9 GJ ha-1 yr-1 and from 5.5-20.5 GJ ha-1 yr-1, respectively. On-site and total CO2 emissions in 2004 ranged from 23-176 kg C ha-1 yr-1 and from 91-365 kg C ha-1 yr-1, respectively. During the period of this analysis (1990-2004), national total energy consumption for crop production ranged from 1204-1297 PJ yr-1 (Petajoule = 1 1015 Joule) with associated total fossil CO2 emissions ranging from 22.0-23.2 Tg C yr-1 (Teragram = 1 1012 gram). The annual proportion of on-site CO2 to total CO2 emissions changed depending on the diversity of crops planted. Adoption of reduced tillage practices in the US from 1990 to 2004 resulted in a net emissions reduction of 2.4 Tg C.« less

  17. Annual methane budgets of sheep grazing systems were regulated by grazing intensities in the temperate continental steppe: A two-year case study

    NASA Astrophysics Data System (ADS)

    Ma, Lei; Zhong, Mengying; Zhu, Yuhao; Yang, Helong; Johnson, Douglas A.; Rong, Yuping

    2018-02-01

    Methane (CH4) emission from animal husbandry accounts for a large percentage of anthropogenic contributions to CH4 emissions. Fully understanding of grazing management effects on the CH4 budget is essential for mitigating CH4 emissions in the temperate grazing steppe systems. Annual CH4 budgets for the sheep grazed steppes at various grazing intensities, un-grazing (UG, 0 sheep ha-1year-1), defer grazing (DG, 1.0 sheep ha-1 year-1), moderate grazing (MG, 1.43 sheep ha-1year-1), and heavy grazing (HG, 2.43 sheep ha-1year-1) were assessed across 2012-2014 in the agro-pastoral region of northern China. Annual soil CH4 uptake averaged across 2012-2014 were 1.1 ± 0.1, 2.4 ± 0.2, 2.2 ± 0.2, and 1.3 ± 0.1 kg CH4-C ha-1 for UG, DG (only 2013-2014), MG and HG sites. Non-growing season CH4 uptake comprised 50.0 ± 4.3% of annual CH4 uptake in 2012-2013 and 37.7 ± 2.0% in 2013-2014. DG and MG significantly promoted annual soil CH4 uptake (P < 0.05), while there was no difference between HG and UG (P > 0.05). Bell-shaped relationship was presented between stocking rates and soil CH4 uptake (r2 = 0.59, P < 0.05). Annual soil CH4 uptake significant linearly and positively correlated with root biomass (r2 = 0.30, P < 0.05). Annual CH4 budgets for the grazed grasslands were -1.1 ± 0.1, 5.7 ± 0.6, 11.5 ± 1.5 and 15.5 ± 1.3 kg CH4-C ha-1 year-1 in UG, DG (only 2013-2014), MG and HG across 2012-2014. Soil CH4 uptake could offset 29.7 ± 5.6, 15.9 ± 4.3 and 6.8 ± 1.0% of total annual CH4 emissions from sheep, sheepfold and faeces in DG, MG, and HG. All grazed steppes are sources for atmospheric CH4 and the magnitude is regulated by grazing intensities. Sheep CH4 emissions for 1-g liveweight gain were 0.21, 0.32 and 0.37 g CH4-C in DG, MG and HG, respectively. DG is the recommended grazing management in this region to achieve greater herbage mass, higher sheep performance and lower CH4 emissions simultaneously.

  18. 40 CFR 98.83 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (General Stationary Fuel Combustion Sources) the combustion CO2 emissions from the kiln according to the... calculate and report the annual process CO2 emissions from each kiln using the procedure in paragraphs (a... combustion CO2 emissions by operating and maintaining a CEMS to measure CO2 emissions according to the Tier 4...

  19. 40 CFR 98.83 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (General Stationary Fuel Combustion Sources) the combustion CO2 emissions from the kiln according to the... calculate and report the annual process CO2 emissions from each kiln using the procedure in paragraphs (a... combustion CO2 emissions by operating and maintaining a CEMS to measure CO2 emissions according to the Tier 4...

  20. 40 CFR 98.83 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (General Stationary Fuel Combustion Sources) the combustion CO2 emissions from the kiln according to the... calculate and report the annual process CO2 emissions from each kiln using the procedure in paragraphs (a... combustion CO2 emissions by operating and maintaining a CEMS to measure CO2 emissions according to the Tier 4...

  1. A Global Catalogue of Large SO2 Sources and Emissions Derived from the Ozone Monitoring Instrument

    NASA Technical Reports Server (NTRS)

    Fioletov, Vitali E.; McLinden, Chris A.; Krotkov, Nickolay; Li, Can; Joiner, Joanna; Theys, Nicolas; Carn, Simon; Moran, Mike D.

    2016-01-01

    Sulfur dioxide (SO2) measurements from the Ozone Monitoring Instrument (OMI) satellite sensor processed with the new principal component analysis (PCA) algorithm were used to detect large point emission sources or clusters of sources. The total of 491 continuously emitting point sources releasing from about 30 kt yr(exp -1) to more than 4000 kt yr(exp -1) of SO2 per year have been identified and grouped by country and by primary source origin: volcanoes (76 sources); power plants (297); smelters (53); and sources related to the oil and gas industry (65). The sources were identified using different methods, including through OMI measurements themselves applied to a new emission detection algorithm, and their evolution during the 2005- 2014 period was traced by estimating annual emissions from each source. For volcanic sources, the study focused on continuous degassing, and emissions from explosive eruptions were excluded. Emissions from degassing volcanic sources were measured, many for the first time, and collectively they account for about 30% of total SO2 emissions estimated from OMI measurements, but that fraction has increased in recent years given that cumulative global emissions from power plants and smelters are declining while emissions from oil and gas industry remained nearly constant. Anthropogenic emissions from the USA declined by 80% over the 2005-2014 period as did emissions from western and central Europe, whereas emissions from India nearly doubled, and emissions from other large SO2-emitting regions (South Africa, Russia, Mexico, and the Middle East) remained fairly constant. In total, OMI-based estimates account for about a half of total reported anthropogenic SO2 emissions; the remaining half is likely related to sources emitting less than 30 kt yr(exp -1) and not detected by OMI.

  2. A probabilistic approach to emissions from transportation sector in the coming decades

    NASA Astrophysics Data System (ADS)

    Yan, F.; Winijkul, E.; Bond, T. C.; Streets, D. G.

    2010-12-01

    how these uncertainties will affect total emissions if any input parameter that has inherent the uncertainties is substituted by a range of values-probability distribution and varies at the same time; the 95% confidence interval of global emission annual growth rate is -1.9% to +0.2% per year.

  3. 40 CFR 98.353 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... anaerobic reactor and anaerobic lagoon from which biogas is not recovered, estimate annual CH4 emissions... wastewater treatment process n from which biogas is not recovered (metric tons). CH4Gn = Annual mass of CH4... some biogas is recovered, estimate the annual mass of CH4 recovered according to the requirements in...

  4. 40 CFR 98.353 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... anaerobic reactor and anaerobic lagoon from which biogas is not recovered, estimate annual CH4 emissions... wastewater treatment process n from which biogas is not recovered (metric tons). CH4Gn = Annual mass of CH4... some biogas is recovered, estimate the annual mass of CH4 recovered according to the requirements in...

  5. 40 CFR 98.353 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... anaerobic reactor and anaerobic lagoon from which biogas is not recovered, estimate annual CH4 emissions... wastewater treatment process n from which biogas is not recovered (metric tons). CH4Gn = Annual mass of CH4... some biogas is recovered, estimate the annual mass of CH4 recovered according to the requirements in...

  6. 40 CFR 98.353 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... anaerobic reactor and anaerobic lagoon from which biogas is not recovered, estimate annual CH4 emissions... wastewater treatment process n from which biogas is not recovered (metric tons). CH4Gn = Annual mass of CH4... biogas is recovered, estimate the annual mass of CH4 recovered according to the requirements in...

  7. Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hoesly, Rachel M.; Smith, Steven J.; Feng, Leyang

    Here, we present a new data set of annual historical (1750–2014) anthropogenic chemically reactive gases (CO, CH 4, NH 3, NO x, SO 2, NMVOCs), carbonaceous aerosols (black carbon – BC, and organic carbon – OC), and CO 2 developed with the Community Emissions Data System (CEDS). We improve upon existing inventories with a more consistent and reproducible methodology applied to all emission species, updated emission factors, and recent estimates through 2014. The data system relies on existing energy consumption data sets and regional and country-specific inventories to produce trends over recent decades. All emission species are consistently estimated using the samemore » activity data over all time periods. Emissions are provided on an annual basis at the level of country and sector and gridded with monthly seasonality. These estimates are comparable to, but generally slightly higher than, existing global inventories. Emissions over the most recent years are more uncertain, particularly in low- and middle-income regions where country-specific emission inventories are less available. Future work will involve refining and updating these emission estimates, estimating emissions' uncertainty, and publication of the system as open-source software.« less

  8. Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS)

    DOE PAGES

    Hoesly, Rachel M.; Smith, Steven J.; Feng, Leyang; ...

    2018-01-29

    Here, we present a new data set of annual historical (1750–2014) anthropogenic chemically reactive gases (CO, CH 4, NH 3, NO x, SO 2, NMVOCs), carbonaceous aerosols (black carbon – BC, and organic carbon – OC), and CO 2 developed with the Community Emissions Data System (CEDS). We improve upon existing inventories with a more consistent and reproducible methodology applied to all emission species, updated emission factors, and recent estimates through 2014. The data system relies on existing energy consumption data sets and regional and country-specific inventories to produce trends over recent decades. All emission species are consistently estimated using the samemore » activity data over all time periods. Emissions are provided on an annual basis at the level of country and sector and gridded with monthly seasonality. These estimates are comparable to, but generally slightly higher than, existing global inventories. Emissions over the most recent years are more uncertain, particularly in low- and middle-income regions where country-specific emission inventories are less available. Future work will involve refining and updating these emission estimates, estimating emissions' uncertainty, and publication of the system as open-source software.« less

  9. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shen, Bo; Price, Lynn K; Lu, Hongyou

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO 2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissionsmore » and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.« less

  10. 40 CFR 98.73 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

  11. 40 CFR 98.73 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

  12. 40 CFR 98.73 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

  13. 40 CFR 98.73 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

  14. 40 CFR 98.73 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Ammonia Manufacturing § 98.73 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each ammonia manufacturing process unit... ammonia manufacturing unit, the CO2 process emissions from gaseous feedstock according to Equation G-1 of...

  15. 40 CFR 98.213 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... emissions. You must determine CO2 process emissions from carbonate use in accordance with the procedures specified in either paragraphs (a) or (b) of this section. (a) Calculate the process emissions of CO2 using calcination fractions with Equation U-1 of this section. ER30OC09.077 Where: ECO2 = Annual CO2 mass emissions...

  16. 40 CFR 98.213 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... emissions. You must determine CO2 process emissions from carbonate use in accordance with the procedures specified in either paragraphs (a) or (b) of this section. (a) Calculate the process emissions of CO2 using calcination fractions with Equation U-1 of this section. ER30OC09.077 Where: ECO2 = Annual CO2 mass emissions...

  17. 40 CFR 98.213 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... emissions. You must determine CO2 process emissions from carbonate use in accordance with the procedures specified in either paragraphs (a) or (b) of this section. (a) Calculate the process emissions of CO2 using calcination fractions with Equation U-1 of this section. ER30OC09.077 Where: ECO2 = Annual CO2 mass emissions...

  18. 40 CFR 98.213 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... emissions. You must determine CO2 process emissions from carbonate use in accordance with the procedures specified in either paragraphs (a) or (b) of this section. (a) Calculate the process emissions of CO2 using calcination fractions with Equation U-1 of this section. ER30OC09.077 Where: ECO2 = Annual CO2 mass emissions...

  19. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Weld County Colorado using δ13CH4 analysis

    NASA Astrophysics Data System (ADS)

    Rella, C.; Jacobson, G. A.; Crosson, E.; Sweeney, C.; Karion, A.; Petron, G.

    2012-12-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Given that the global warming potential of methane is many times greater than that of carbon dioxide (Forster et al. 2007), the importance of quantifying methane emissions becomes clear. Companion presentations at this meeting describe efforts to quantify the overall methane emissions in two separate gas producing areas in Colorado and Utah during intensive field campaigns undertaken in 2012. A key step in the process of assessing the emissions arising from natural gas production activities is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One method for assessing the contribution of these different sources is stable isotope analysis. In particular, the δ13CH4 signature of natural gas (-37 permil) is significantly different that the signature of other significant sources of methane, such as landfills or ruminants (-50 to -70 permil). In this paper we present measurements of δ13CH4 in Colorado in Weld County, a region of intense natural gas production, using a mobile δ13CH4¬ analyzer capable of high-precision measurements of the stable isotope ratio of methane at ambient levels. This analyzer was used to make stable isotope measurements at a fixed location near the center of the gas producing region, from which an overall isotope ratio for the regional emissions is determined. In addition, mobile measurements in the nocturnal boundary layer have been made, over a total distance of 150 km throughout Weld County, allowing spatially resolved measurements of this isotope signature. Finally, this analyzer was used to quantify the isotopic signature of those individual sources (natural gas fugitive emissions, concentrated animal feeding operations, and landfills) that constitute the majority of methane emissions in this region, by making

  20. A Method for Improving Temporal and Spatial Resolution of Carbon Dioxide Emissions

    NASA Astrophysics Data System (ADS)

    Gregg, J. S.; Andres, R. J.

    2003-12-01

    Using United States data, a method is developed to estimate the monthly consumption of solid, liquid and gaseous fossil fuels for each state in the union. This technique employs monthly sales data to estimate the relative monthly proportions of the total annual national fossil fuel use. These proportions are then used to estimate the total monthly carbon dioxide emissions for each state. To assess the success of this technique, the results from this method are compared with the data obtained from other independent methods. To determine the temporal success of the method, the resulting national time series is compared to the model produced by Carbon Dioxide Information Analysis Center (CDIAC) and the current model being developed by T. J. Blasing and C. Broniak at the Oak Ridge National Laboratory (ORNL). The University of North Dakota (UND) method fits well temporally with the results of the CDIAC and current ORNL research. To determine the success of the spatial component, the individual state results are compared to the annual state totals calculated by ORNL. Using ordinary least squares regression, the annual state totals of this method are plotted against the ORNL data. This allows a direct comparison of estimates in the form of ordered pairs against a one-to-one ideal correspondence line, and allows for easy detection of outliers in the results obtained by this estimation method. Analyzing the residuals of the linear regression model for each type of fuel permits an improved understanding of the strengths and shortcomings of the spatial component of this estimation technique. Spatially, the model is successful when compared to the current ORNL research. The primary advantages of this method are its ease of implementation and universal applicability. In general, this technique compares favorably to more labor-intensive methods that rely on more detailed data. The more detailed data is generally not available for most countries in the world. The methodology used

  1. Model-independent comparison of annual modulation and total rate with direct detection experiments

    NASA Astrophysics Data System (ADS)

    Kahlhoefer, Felix; Reindl, Florian; Schäffner, Karoline; Schmidt-Hoberg, Kai; Wild, Sebastian

    2018-05-01

    The relative sensitivity of different direct detection experiments depends sensitively on the astrophysical distribution and particle physics nature of dark matter, prohibiting a model-independent comparison. The situation changes fundamentally if two experiments employ the same target material. We show that in this case one can compare measurements of an annual modulation and exclusion bounds on the total rate while making no assumptions on astrophysics and no (or only very general) assumptions on particle physics. In particular, we show that the dark matter interpretation of the DAMA/LIBRA signal can be conclusively tested with COSINUS, a future experiment employing the same target material. We find that if COSINUS excludes a dark matter scattering rate of about 0.01 kg‑1 days‑1 with an energy threshold of 1.8 keV and resolution of 0.2 keV, it will rule out all explanations of DAMA/LIBRA in terms of dark matter scattering off sodium and/or iodine.

  2. The Health Impacts of Energy Policy Pathways in Ulaanbaatar, Mongolia: A Total Exposure Assessment

    NASA Astrophysics Data System (ADS)

    Hill, L. A.; Damdinsuren, Y.; Olkhanud, P. B.; Smith, K. R.; Turner, J. R.; Edwards, R.; Odsuren, M.; Ochir, C.

    2015-12-01

    Ulaanbaatar is home to nearly half of Mongolia's 2.8 million residents. The city's rapid growth, frigid winters, valley topography, and reliance on coal-fired stoves have led to some of the worst winter pollution levels in the world. To better understand this issue, we modeled integrated PM2.5exposures and related health impacts for various city-wide heating policies through 2024. This assessment is one of the first to employ a total exposure approach and results of the 2014 Comparative Risk Assessments of the Global Burden of Disease Project (CRA/GBD) in a policy-relevant energy study. Emissions related to heating, traffic, and power generation were considered under Business as Usual, Moderate Improvement, and Max Improvement scenarios. Calibrated outdoor models were combined with indoor models, local infiltration and time activity estimates, and demographic projections to estimate PM2.5exposures in 2014 and 2024. Indoor exposures were assigned by heating type, home type, and smoking status; outdoor exposures were assigned through geocoding. Population average annual exposures were calculated and applied to local disease rates and integrated exposure-response curves (2014 CRA/GBD) to arrive at annual projections of premature deaths and DALYs. We estimate 2014 annual average exposures at 68 μg/m3, dictated almost exclusively by indoor winter exposures. Under current trends, annual exposures increase 10% to 75 μg/m3 in 2024. This is in stark contrast to the moderate and max improvement scenarios, which lead to 2024 annual exposures that are 31%, and 68% lower, respectively. Under the Moderate scenario, 2024 per capita annual DALY and death burdens drop 26% and 22%, respectively, from 2014 levels. Under the Max scenario, 2024 per capita annual DALY and death burdens drop 71% and 66%, respectively, from 2014. SHS becomes a major contributor as emissions from other sectors decrease. Reductions are dominated by cardiovascular and lower respiratory diseases in children.

  3. Implications of burned area approaches in emission inventories for modeling wildland fire pollution in the contiguous U.S.

    EPA Science Inventory

    Wildland fires are a major source of fine particulate matter (PM2.5), one of the most harmful ambient pollutants for human health globally. Within the U.S., wildland fires can account for more than 30% of total annual PM2.5 emissions. In order to represent the influence of fire e...

  4. Implications of burned area approaches in emission inventories for modeling wildland fire pollution in the contiguous U.S

    EPA Science Inventory

    Wildland fires are a major source of fine particulate matter (PM2.5), one of the most harmful ambient pollutants for human health globally. Within the U.S., wildland fires can account for more than 30% of total annual PM2.5 emissions. In order to represent the influence of fire e...

  5. Trends in onroad transportation energy and emissions.

    PubMed

    Frey, H Christopher

    2018-06-01

    Globally, 1.3 billion on-road vehicles consume 79 quadrillion BTU of energy, mostly gasoline and diesel fuels, emit 5.7 gigatonnes of CO 2 , and emit other pollutants to which approximately 200,000 annual premature deaths are attributed. Improved vehicle energy efficiency and emission controls have helped offset growth in vehicle activity. New technologies are diffusing into the vehicle fleet in response to fuel efficiency and emission standards. Empirical assessment of vehicle emissions is challenging because of myriad fuels and technologies, intervehicle variability, multiple emission processes, variability in operating conditions, and varying capabilities of measurement methods. Fuel economy and emissions regulations have been effective in reducing total emissions of key pollutants. Real-world fuel use and emissions are consistent with official values in the United States but not in Europe or countries that adopt European standards. Portable emission measurements systems, which uncovered a recent emissions cheating scandal, have a key role in regulatory programs to ensure conformity between "real driving emissions" and emission standards. The global vehicle fleet will experience tremendous growth, especially in Asia. Although existing data and modeling tools are useful, they are often based on convenience samples, small sample sizes, large variability, and unquantified uncertainty. Vehicles emit precursors to several important secondary pollutants, including ozone and secondary organic aerosols, which requires a multipollutant emissions and air quality management strategy. Gasoline and diesel are likely to persist as key energy sources to mid-century. Adoption of electric vehicles is not a panacea with regard to greenhouse gas emissions unless coupled with policies to change the power generation mix. Depending on how they are actually implemented and used, autonomous vehicles could lead to very large reductions or increases in energy consumption. Numerous other

  6. Characteristics of Biogenic VOCs Emission and its High-Resolution Emission Inventory in China

    NASA Astrophysics Data System (ADS)

    Li, L.; Li, Y.; Xie, S.

    2017-12-01

    Biogenic volatile organic compounds (BVOCs), with high emission and reactivity, can have substantial impacts on the haze and photochemical pollution. It is essential to establish an accurate high-resolution BVOC emission inventory in China for air quality simulation and decision making. Firstly, a semi-static enclosure technique is developed for the field measurements of BVOC emission rates from 50 plant species in China. Using the GC-MS/FID system, 103 VOC species for each plant species are measured. Based on the field measurements in our study and the reported emission rates at home and abroad, a methodology for determining the emission categories of BVOCs is developed using statistical analysis. The isoprene and monoterpene emission rates of 192 plant species/genera in China are determined based on the above emission categories. Secondly, a new vegetation classification with 82 plant functional types (PFTs) is developed based on the most detailed and latest vegetation investigations, China's official statistical data and Vegetation Atlas of China (1:1,000,000). The leaf biomass is estimated based on provincial vegetation volume and production with biomass-apportion models. The WRF model is used to determine meteorological variables at a high spatio-temporal resolution. Using MEAGNv2.1 and the determined emission rates in our study, the high-resolution emission inventories of isoprene, 37 monoterpene species, 32 sesquiterpene species, and other VOCs (OVOCs) from 82 PFTs in China for 1981-2013 are established. The total annual BVOC emissions in 2013 are 55.88 Tg, including 33.87 Tg isoprene, 6.36 Tg monoterpene, 1.29 Tg sesquiterpene, and 14.37 Tg OVOCs. The distribution of isoprene emission fluxes is consistent with the distribution of broadleaf trees, especially tree species with high or higher emission potential. During 1981-2013, China's BVOC emissions have increased by 47.48% at an average rate of 1.80% yr-1. Emissions of isoprene have the largest enhancement

  7. Radioactive emission data from Canadian nuclear generating stations, 1988 to 1997. Report number INFO-0210/Rev.8

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-12-31

    This edition incorporates histograms for each nuclear generating station (NGS) displaying the annual gaseous emissions containing tritium, in the form of tritium oxide, noble gases, iodine-131, and radioactive particulates, as well as the annual liquid emissions containing tritium, in the form of tritiated water, and gross beta-gamma activity. For Pickering NGS A and Gentilly 2, annual emissions of carbon-14 are depicted; and for Darlington NGS A, airborne emissions of elemental tritium since 1988 are shown. In each case, the emission data are compared to the derived emission limits.

  8. Hybrid Gama Emission Tomography (HGET): FY16 Annual Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Miller, Erin A.; Smith, Leon E.; Wittman, Richard S.

    2017-02-01

    Current International Atomic Energy Agency (IAEA) methodologies for the verification of fresh low-enriched uranium (LEU) and mixed oxide (MOX) fuel assemblies are volume-averaging methods that lack sensitivity to individual pins. Further, as fresh fuel assemblies become more and more complex (e.g., heavy gadolinium loading, high degrees of axial and radial variation in fissile concentration), the accuracy of current IAEA instruments degrades and measurement time increases. Particularly in light of the fact that no special tooling is required to remove individual pins from modern fuel assemblies, the IAEA needs new capabilities for the verification of unirradiated (i.e., fresh LEU and MOX)more » assemblies to ensure that fissile material has not been diverted. Passive gamma emission tomography has demonstrated potential to provide pin-level verification of spent fuel, but gamma-ray emission rates from unirradiated fuel emissions are significantly lower, precluding purely passive tomography methods. The work presented here introduces the concept of Hybrid Gamma Emission Tomography (HGET) for verification of unirradiated fuels, in which a neutron source is used to actively interrogate the fuel assembly and the resulting gamma-ray emissions are imaged using tomographic methods to provide pin-level verification of fissile material concentration.« less

  9. 40 CFR 98.143 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Fuel Combustion Sources). (2) Calculate and report the process and combustion CO2 emissions separately... Fuel Combustion Sources) the combustion CO2 emissions in the glass furnace according to the applicable... calculate and report the annual process CO2 emissions from each continuous glass melting furnace using the...

  10. 40 CFR 98.193 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... Stationary Fuel Combustion Sources) the combustion CO2 emissions from each lime kiln according to the... must calculate and report the annual process CO2 emissions from all lime kilns combined using the...

  11. 40 CFR 98.193 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... Stationary Fuel Combustion Sources) the combustion CO2 emissions from each lime kiln according to the... must calculate and report the annual process CO2 emissions from all lime kilns combined using the...

  12. 40 CFR 98.143 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Fuel Combustion Sources). (2) Calculate and report the process and combustion CO2 emissions separately... Fuel Combustion Sources) the combustion CO2 emissions in the glass furnace according to the applicable... calculate and report the annual process CO2 emissions from each continuous glass melting furnace using the...

  13. Refinery evaluation of optical imaging to locate fugitive emissions.

    PubMed

    Robinson, Donald R; Luke-Boone, Ronke; Aggarwal, Vineet; Harris, Buzz; Anderson, Eric; Ranum, David; Kulp, Thomas J; Armstrong, Karla; Sommers, Ricky; McRae, Thomas G; Ritter, Karin; Siegell, Jeffrey H; Van Pelt, Doug; Smylie, Mike

    2007-07-01

    Fugitive emissions account for approximately 50% of total hydrocarbon emissions from process plants. Federal and state regulations aiming at controlling these emissions require refineries and petrochemical plants in the United States to implement a Leak Detection and Repair Program (LDAR). The current regulatory work practice, U.S. Environment Protection Agency Method 21, requires designated components to be monitored individually at regular intervals. The annual costs of these LDAR programs in a typical refinery can exceed US$1,000,000. Previous studies have shown that a majority of controllable fugitive emissions come from a very small fraction of components. The Smart LDAR program aims to find cost-effective methods to monitor and reduce emissions from these large leakers. Optical gas imaging has been identified as one such technology that can help achieve this objective. This paper discusses a refinery evaluation of an instrument based on backscatter absorption gas imaging technology. This portable camera allows an operator to scan components more quickly and image gas leaks in real time. During the evaluation, the instrument was able to identify leaking components that were the source of 97% of the total mass emissions from leaks detected. More than 27,000 components were monitored. This was achieved in far less time than it would have taken using Method 21. In addition, the instrument was able to find leaks from components that are not required to be monitored by the current LDAR regulations. The technology principles and the parameters that affect instrument performance are also discussed in the paper.

  14. The Annual Cycle of Water Vapor on Mars as Observed by the Thermal Emission Spectrometer

    NASA Technical Reports Server (NTRS)

    Smith, Michael D.; Vondrak, Richard R. (Technical Monitor)

    2001-01-01

    Spectra taken by the Mars Global Surveyor Thermal Emission Spectrometer (TES) have been used to monitor the latitude, longitude, and seasonal dependence of water vapor for over one full Martian year (March 1999-March 2001). A maximum in water vapor abundance is observed at high latitudes during mid-summer in both hemispheres, reaching a maximum value of approximately 100 pr-micrometer in the north and approximately 50 pr-micrometer in the south. Low water vapor abundance (<5 pr-micrometer) is observed at middle and high latitudes in the fall and winter of both hemispheres. There are large differences in the hemispheric (north versus south) and seasonal (perihelion versus aphelion) behavior of water vapor. The latitudinal and seasonal dependence of the decay of the northern summer water vapor maximum implies cross-equatorial transport of water to the southern hemisphere, while there is little or no corresponding transport during the decay of the southern hemisphere summer maximum. The latitude-longitude dependence of annually-averaged water vapor (corrected for topography) has a significant positive correlation with albedo and significant negative correlations with thermal inertia and surface pressure. Comparison of TES results with those retrieved from the Viking Orbiter Mars Atmospheric Water Detectors (MAWD) experiments shows some similar features, but also many significant differences. The southern hemisphere maximum observed by TES was not observed by MAWD and the large latitudinal gradient in annually-averaged water vapor observed by MAWD does not appear in the TES results.

  15. Indoor emission, dispersion and exposure of total particle-bound polycyclic aromatic hydrocarbons during cooking

    NASA Astrophysics Data System (ADS)

    Gao, Jun; Jian, Yating; Cao, Changsheng; Chen, Lei; Zhang, Xu

    2015-11-01

    Cooking processes highly contribute to indoor polycyclic aromatic hydrocarbon (PAH) pollution. High molecular weight and potentially carcinogenic PAHs are generally found attached to small particles, i.e., particulate phase PAHs (PPAHs). Due to the fact that indoor particle dynamics have been clear, describing the indoor dynamics of cooking-generated PPAHs within a specific time span is possible. This paper attempted to quantify the dynamic emission rate, simultaneous spatial dispersion and individual exposure of PPAHs using a cooking source. Experiments were conducted in a real-scale kitchen chamber to elucidate the time-resolved emission and effect of edible oil temperature and mass. Numerical simulations based on indoor particle dynamics were performed to obtain the spatial dispersion and individual inhalation intake of PPAHs under different emission and ventilation conditions. The present work examined the preheating cooking stage, at which edible oil is heated up to beyond its smoke point. The dynamic emission rate peak point occurred much earlier than the oil heating temperature. The total PPAH emission ranged from 2258 to 6578 ng upon heating 40-85 g of edible oil. The overall intake fraction by an individual within a period of 10 min, including 3 min for heating and 7 min for natural cooling, was generally ∼1/10,000. An important outcome of this work was that the overall intake fraction could be represented by multiplying the range hood escape efficiency by the inhalation-to-ventilation rate ratio, which would be no greater than the same ratio. The methodology and results of this work were extendible for the number-based assessment of PPAHs. This work is expected to help us understand the health risks due to inhalation exposure to cooking-generated PPAHs in the kitchen.

  16. Satellite-derived methane hotspot emission estimates using a fast data-driven method

    NASA Astrophysics Data System (ADS)

    Buchwitz, Michael; Schneising, Oliver; Reuter, Maximilian; Heymann, Jens; Krautwurst, Sven; Bovensmann, Heinrich; Burrows, John P.; Boesch, Hartmut; Parker, Robert J.; Somkuti, Peter; Detmers, Rob G.; Hasekamp, Otto P.; Aben, Ilse; Butz, André; Frankenberg, Christian; Turner, Alexander J.

    2017-05-01

    Methane is an important atmospheric greenhouse gas and an adequate understanding of its emission sources is needed for climate change assessments, predictions, and the development and verification of emission mitigation strategies. Satellite retrievals of near-surface-sensitive column-averaged dry-air mole fractions of atmospheric methane, i.e. XCH4, can be used to quantify methane emissions. Maps of time-averaged satellite-derived XCH4 show regionally elevated methane over several methane source regions. In order to obtain methane emissions of these source regions we use a simple and fast data-driven method to estimate annual methane emissions and corresponding 1σ uncertainties directly from maps of annually averaged satellite XCH4. From theoretical considerations we expect that our method tends to underestimate emissions. When applying our method to high-resolution atmospheric methane simulations, we typically find agreement within the uncertainty range of our method (often 100 %) but also find that our method tends to underestimate emissions by typically about 40 %. To what extent these findings are model dependent needs to be assessed. We apply our method to an ensemble of satellite XCH4 data products consisting of two products from SCIAMACHY/ENVISAT and two products from TANSO-FTS/GOSAT covering the time period 2003-2014. We obtain annual emissions of four source areas: Four Corners in the south-western USA, the southern part of Central Valley, California, Azerbaijan, and Turkmenistan. We find that our estimated emissions are in good agreement with independently derived estimates for Four Corners and Azerbaijan. For the Central Valley and Turkmenistan our estimated annual emissions are higher compared to the EDGAR v4.2 anthropogenic emission inventory. For Turkmenistan we find on average about 50 % higher emissions with our annual emission uncertainty estimates overlapping with the EDGAR emissions. For the region around Bakersfield in the Central Valley we

  17. 40 CFR 98.333 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the process CO2 emissions by... calculate and report the annual process CO2 emissions using the procedures specified in either paragraph (a... and combustion CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation...

  18. 40 CFR 98.333 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the process CO2 emissions by... calculate and report the annual process CO2 emissions using the procedures specified in either paragraph (a... and combustion CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation...

  19. 40 CFR 98.333 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the process CO2 emissions by... calculate and report the annual process CO2 emissions using the procedures specified in either paragraph (a... and combustion CO2 emissions by operating and maintaining a CEMS according to the Tier 4 Calculation...

  20. 40 CFR 98.143 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Stationary Fuel Combustion Sources) the combustion CO2 emissions in the glass furnace according to the... calculate and report the annual process CO2 emissions from each continuous glass melting furnace using the... subpart the combined process and combustion CO2 emissions by operating and maintaining a CEMS to measure...

  1. Greenhouse gas emissions from septic systems in New York State

    NASA Astrophysics Data System (ADS)

    Truhlar, A. M.; Rahm, B. G.; Brooks, R. A.; Nadeau, S. A.; Walter, M. T.

    2015-12-01

    Onsite septic systems are a practical way to treat wastewater in rural or less-densely populated areas. Septic systems utilize microbial processes to eliminate organic wastes and nutrients such as nitrogen; these processes can contribute to air pollution through the release of greenhouse gases (GHGs). At each of nine septic systems, we measured fluxes of CH4, CO2, and N2O from the soil over the leach field and sand filter, and from the roof outlet vent. These are the most likely locations for gas emissions during normal operation of the septic system. The majority of all septic system gas emissions were released from the roof vent. However, our comparisons of the gas fluxes from these locations suggest that biological processes in the soil, especially the soil over the leach field, can influence the type and quantity of gas that is released from the system. The total vent, sand filter, and leach field GHG emissions were 0.12, 0.045, and 0.046 tonne CO2e capita-1 year-1, respectively. In total, this represents about 1.5% of the annual carbon footprint of an individual living in the US.

  2. Emission of PCDD/Fs and dioxin-like PCBs from metallurgy industries in S. Korea.

    PubMed

    Yu, Byeong-Woon; Jin, Guang-Zhu; Moon, Young-Hoon; Kim, Min-Kwan; Kyoung, Jong-Dai; Chang, Yoon-Seok

    2006-01-01

    The metallurgy industry and municipal waste incinerators are considered the main sources of polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) in many countries. This study investigated the emission factors and total emissions of PCDD/Fs and dioxin-like polychlorinated biphenyls (PCBs) emitted from metallurgy industries (including ferrous and nonferrous foundries) in Korea. The toxic equivalency (TEQ) emission factor of PCDD/Fs was the highest for secondary copper production, at 24451 ng I-TEQ/ton. The total estimated emissions of PCDD/Fs from these sources were 35.259 g I-TEQ/yr, comprising 0.088 g I-TEQ/yr from ferrous foundries, 31.713 g I-TEQ/yr from copper production, 1.716 g I-TEQ/yr from lead production, 0.111 g I-TEQ/yr from zinc production, and 1.631 g I-TEQ/yr from aluminum production. The total estimated annual amounts of dioxin-like PCBs emitted from these sources were 13.260 g WHO-TEQ/yr, comprising 0.014 g WHO-TEQ/yr from ferrous foundries, 12.675 g WHO-TEQ/yr from copper production, 0.170 g WHO-TEQ/yr from lead production, 0.017 g WHO-TEQ/yr from zinc production, and 0.384 g WHO-TEQ/yr from aluminum production. The highest emission factor was found for secondary copper smelting, at 9770 ng WHO-TEQ/ton.

  3. Dinitrogen emissions as an overlooked key component of the N balance of montane grasslands

    NASA Astrophysics Data System (ADS)

    Zistl-Schlingmann, Marcus; Feng, Jinchao; Kiese, Ralf; Stephan, Ruth; Dannenmann, Michael

    2017-04-01

    Numerous studies have been conducted on the emission dynamics and annual budget of the atmospheric pollutants and primary or secondary greenhouse gases NOx, NH3 and N2O, i.e. gaseous N losses which can play an important role in the N budget of ecosystems. Due to still existing methodical problems in their quantification, considerably less is known on soil dinitrogen (N2) emissions, an inert gas with no hazardous effects on the environment. Understanding of soil N2 emissions however may be important to better understand and manage the N balance of ecosystems and also to mitigate the emissions of the precursor and potent greenhouse gas N2O. Here we quantified soil N2 emissions from montane grasslands used for dairy farming as affected by climate change simulation (reduced annual precipitation, increased temperature). For this purpose, plant-soil-mesocosms were brought from field sites of different elevation to the laboratory for direct simultaneous quantification of soil N2 and N2O emissions by use of the Helium soil core method. Immediately after the measurements, the plant-soil mesocosms were reburied at the sites. Using this approach we found that under current climate conditions, soil N2 emissions exceeded soil N2O emissions by several orders of magnitude and increased from 25 kg N ha-1 year-1 (present climate) to 50 kg N ha-1 year-1 (climate change treatment). Because this approach based on monthly sampling cannot accurately consider N gas emission peaks after manure fertilization, measurements were supplemented by a laboratory incubation approach. In this experiment, the response of all N gas emissions (NH3, NO, N2O, N2) to manure fertilization (50 kg N ha-1) was monitored with subdaily temporal resolution until emissions had diminished. Total N gas losses amounted to roughly half of the supplied N by manure application. Surprisingly, we found that N2 but not NH3 dominated fertilizer-derived gaseous N losses, accounting for 78 to 85 % of total gaseous N losses

  4. Emission projections of the transport Sector in China: 2015-2040

    NASA Astrophysics Data System (ADS)

    Yan, L.

    2016-12-01

    Driven by the significant growth freight and passenger transport demand, transport sector has become a sector that is largely responsible for increases in emissions of atmospheric pollutants (NOx, CO, HC, PM2.5) in China. Figuring out the emission trend in China's transport sector has great influence on formulating emission reduction measures in the future. In this work, both on-road and off-road transport emissions in China were estimated from 2015 to 2040 for CO, NOx, HC and PM2.5. The projection was conducted based on on the energy consumption structure forecast from IEA (International Energy Agency), the future national average annual distance traveled per vehicle and fuel consumption per distance derived from simulation results of the Fuel Economy and Environmental Impact (FEEI) model. The results show that the ownership of on-road vehicles in China increases rapidly during 2015 to 2030 and then the growth slows down. Finally, the total amount reaches up to 522 million in 2040 in which 84.5% turns out to be light-duty vehicles. Because current control legislations for the transport sector in China will continue to be strengthened in the future, the total emissions of China's transport sector were projected to peak around 2030, due to the improvement of vehicle emission standard and the retirement of old vehicles are the most effective measures. The off-road transport will become the main contributor to emissions from transport sector in China since 2030. This work provides a new perspective to understand emissions from both on-road and off-road transport in China, which can support the achievement of improving air quality promised by the Chinese government. This work provides a new perspective to understand the emission trends of on-road and off-road transport sector in China from 2015 to 2040, which can support the achievement of the air quality goal promised by the Chinese government. Driven by the significant growth freight and passenger transport demand

  5. Non-relativistic Free–Free Emission due to the n -distribution of Electrons—Radiative Cooling and Thermally Averaged and Total Gaunt Factors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    De Avillez, Miguel A.; Breitschwerdt, Dieter, E-mail: mavillez@galaxy.lca.uevora.pt

    Tracking the thermal evolution of plasmas, characterized by an n -distribution, using numerical simulations, requires the determination of the emission spectra and of the radiative losses due to free–free emission from the corresponding temperature-averaged and total Gaunt factors. Detailed calculations of the latter are presented and associated with n -distributed electrons with the parameter n ranging from 1 (corresponding to the Maxwell–Boltzmann distribution) to 100. The temperature-averaged and total Gaunt factors with decreasing n tend toward those obtained with the Maxwell–Boltzmann distribution. Radiative losses due to free–free emission in a plasma evolving under collisional ionization equilibrium conditions and composed bymore » H, He, C, N, O, Ne, Mg, Si, S, and Fe ions, are presented. These losses decrease with a decrease in the parameter n , reaching a minimum when n  = 1, and thus converge with the loss of thermal plasma. Tables of the thermal-averaged and total Gaunt factors calculated for n -distributions, and a wide range of electron and photon energies, are presented.« less

  6. Unregulated pollutant emissions from on-road vehicles in China, 1999-2014.

    PubMed

    Lang, Jianlei; Zhou, Ying; Cheng, Shuiyuan; Zhang, Yanyun; Dong, Meng; Li, Shengyue; Wang, Gang; Zhang, Yonglin

    2016-12-15

    Multi-year (1999-2014) vehicular unregulated pollutants emissions in China, including SO 2 , CH 4 , N 2 O, NH 3 , Indeno(1,2,3-cd)pyrene (IPY), Benzo(k)fluoranthene (BkF), Benzo(b)fluoranthene (BbF), Benzo(a)pyrene (BaP), dioxins and furans, were estimated based on emission factors calculated by COPERT. The inter-annual trends, correlation with GDP and population, spatial distribution characteristics, contributions from various vehicle types for the ten pollutants emissions were analyzed. Results showed that the emissions of the above ten pollutants changed from approximately 576.9Gg, 130.0Gg, 8.1Gg, 2.1Gg, 1.0Mg, 1.1Mg, 1.4Mg, 0.5Mg, 7.4g and 15.6g in 1999 to 193.8Gg, 171.1Gg, 79.1Gg, 117.8Gg, 3.5Mg, 6.7Mg, 6.8Mg, 2.9Mg, 37.6g and 79.1g in 2014, respectively. Implementation of stringent sulfur content limit during the past decade reduced approximately 94.4% of the SO 2 emission in 2014. CH 4 and N 2 O increased from 1999 to 2011, but began to decrease since 2012; NH 3 emission had the highest annual average change rate (35.5%) from 1999 to 2014; PAHs, dioxins and furans increased continuously during the past decade. The vehicular emissions were higher in Guangdong, Shandong, Henan, Jiangsu, Zhejiang and Hebei. Good linear correlation between vehicular emissions and GDP was found (except SO 2 ); in the provinces/municipalities with higher population density, the emission density was also larger, indicating more significant vehicular emissions' potential damage on human health. HDT and PC, PC and MC, PC and BUS were the major contributors to SO 2 , CH 4 , N 2 O emissions, respectively. In 2014, PC was the dominant contributor to NH 3 emission; PC, BUS and HDT had higher fraction in the total IPY and BaP emissions; HDT was the major contributor to BkF and BbF emissions. In addition, the uncertainties of estimated emissions were also analyzed based on Monte Carlo simulation. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. COMPACT NON-CONTACT TOTAL EMISSION DETECTION FOR IN-VIVO MULTI-PHOTON EXCITATION MICROSCOPY

    PubMed Central

    Glancy, Brian; Karamzadeh, Nader S.; Gandjbakhche, Amir H.; Redford, Glen; Kilborn, Karl; Knutson, Jay R.; Balaban, Robert S.

    2014-01-01

    Summary We describe a compact, non-contact design for a Total Emission Detection (c-TED) system for intra-vital multi-photon imaging. To conform to a standard upright two-photon microscope design, this system uses a parabolic mirror surrounding a standard microscope objective in concert with an optical path that does not interfere with normal microscope operation. The non-contact design of this device allows for maximal light collection without disrupting the physiology of the specimen being examined. Tests were conducted on exposed tissues in live animals to examine the emission collection enhancement of the c-TED device compared to heavily optimized objective-based emission collection. The best light collection enhancement was seen from murine fat (5×-2× gains as a function of depth), while murine skeletal muscle and rat kidney showed gains of over two and just under two-fold near the surface, respectively. Gains decreased with imaging depth (particularly in the kidney). Zebrafish imaging on a reflective substrate showed close to a two-fold gain throughout the entire volume of an intact embryo (approximately 150 μm deep). Direct measurement of bleaching rates confirmed that the lower laser powers (enabled by greater light collection efficiency) yielded reduced photobleaching in vivo. The potential benefits of increased light collection in terms of speed of imaging and reduced photo-damage, as well as the applicability of this device to other multi-photon imaging methods is discussed. PMID:24251437

  8. Greenhouse Gas Emissions from Septic Systems in New York State.

    PubMed

    Truhlar, Allison M; Rahm, Brian G; Brooks, Rachael A; Nadeau, Sarah A; Makarsky, Erin T; Walter, M Todd

    2016-07-01

    Onsite septic systems use microbial processes to eliminate organic wastes and nutrients such as nitrogen; these processes can contribute to air pollution through the release of greenhouse gases (GHGs). Current USEPA estimates for septic system GHG emissions are based on one study conducted in north-central California and are limited to methane; therefore, the contribution of these systems to the overall GHG emission budget is unclear. This study quantified and compared septic system GHG emissions from the soil over leach fields and the roof vent, which are the most likely locations for gas emissions during normal septic system operation. At each of eight septic systems, we measured fluxes of CH, CO, and NO using a static chamber method. The roof vent released the majority of septic system gas emissions. In addition, the leach field was a significant source of NO fluxes. Comparisons between leach field and vent emissions suggest that biological processes in the leach field soil may influence the type and quantity of gas released. Overall, our results suggest that (i) revisions are needed in USEPA guidance (e.g., septic systems are not currently listed as a source of NO emissions) and (ii) similar studies representing a wider range of climatic and geographic settings are needed. The total vent, sand filter, and leach field GHG emissions were 0.17, 0.045, and 0.050 t CO-equivalents capita yr, respectively. In total, this represents about 1.5% of the annual carbon footprint of an individual living in the United States. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  9. Unanticipated benefits of automotive emission control: reduction in fatalities by motor vehicle exhaust gas.

    PubMed

    Shelef, M

    1994-05-23

    In 1970, before the implementation of strict controls on emissions in motor vehicle exhaust gas (MVEG), the annual USA incidence of fatal accidents by carbon monoxide in the MVEG was approximately 800 and that of suicides approximately 2000 (somewhat less than 10% of total suicides). In 1987, there were approximately 400 fatal accidents and approximately 2700 suicides by MVEG. Accounting for the growth in population and vehicle registration, the yearly lives saved in accidents by MVEG were approximately 1200 in 1987 and avoided suicides approximately 1400. The decrease in accidents continues unabated while the decrease in expected suicides by MVEG reached a plateau in 1981-1983. The reasons for this disparity are discussed. Juxtaposition of these results with the projected cancer risk avoidance of less than 500 annually in 2005 (as compared with 1986) plainly shows that, in terms of mortality, the unanticipated benefits of emission control far overshadow the intended benefits. With the spread of MVEG control these benefits will accrue worldwide.

  10. Comparing N2O emissions at varying N rates from irrigated and rainfed corn in the US Midwest

    NASA Astrophysics Data System (ADS)

    Millar, N.; Kahmark, K.; Basso, B.; Robertson, G. P.

    2011-12-01

    Global N2O emissions from agriculture are estimated to be ~2.8 Pg CO2e yr-1 accounting for 60% of total anthropogenic emissions. N2O is the largest contributor to the GHG burden of cropping systems in the US, with annual estimated emissions of ~0.5 Tg primarily due to N fertilizer inputs and other soil management activities. Currently 23 million acres of corn, soybean and wheat are irrigated annually in the US with increased N2O emissions due to the practice likely under-reported in GHG inventories. Here we compare N2O emissions and yield from irrigated and rainfed corn at varying N rates between 0 and 246 kg N ha-1 from the Kellogg Biological Station in SW Michigan. Initial results show that N2O emissions increase with increasing N rate and are significantly higher from irrigated corn compared to rainfed corn at the same N rate. At increasing N rates daily emissions following an irrigation event were between 2.4 - 77.5 g N2O-N ha-1 from irrigated corn and 1.6 - 13.0 g N2O-N ha-1 from rainfed corn. Emissions data from automated and static chambers will be presented and trade-offs between N2O emissions, N fertilizer rate, crop yield and irrigation practice will be evaluated from an environmental and economic standpoint.

  11. Carbon dioxide emissions and energy balance closure before, during, and after biomass burning in mid-South rice fields

    NASA Astrophysics Data System (ADS)

    Fong, B.; Adviento-Borbe, A.; Reba, M. L.; Runkle, B.; Suvocarev, K.

    2017-12-01

    Biomass burning or field burning is a crop management practice that removes rice straw, reduces tillage, controls pests and releases nutrients for the next cropping season. Current field burning emissions are not included in agricultural field annual emissions largely because of the lack of studies, especially on the field scale. Field burning measurements are important for greenhouse gas emission inventories and quantifying the annual carbon footprint of rice. Paired eddy covariance systems were used to measure energy balance, CO2 fluxes, and H2O fluxes in mid-South US rice fields (total area of 25 ha) before, during and after biomass burning for 20 days after harvest. During the biomass burning, air temperatures increased 29°C, while ambient CO2 concentration increased from 402 to 16,567 ppm and H2O concentrations increased from 18.73 to 25.62 ppt. For the burning period, 67-86 kg CO2 ha-1 period-1 was emitted calculated by integrating fluxes over the biomass burning event. However, the estimated emission using aboveground biomass and combustion factors was calculated as 11,733 kg CO2 ha-1 period-1. Part of the difference could be attributed to sensor sensitivity decreasing 80% during burning for two minutes due to smoke. Net ecosystem exchange (NEE) increased by a factor of two, 1.14 before burning to 2.44 μmol m-2 s-1 possibly due to greater reduction of plant material and photosynthesis following burning. This study highlights the contribution of rice straw burning to total CO2 emissions from rice production.

  12. Estimating historical anthropogenic global sulfur emission patterns for the period 1850-1990

    NASA Astrophysics Data System (ADS)

    Lefohn, Allen S.; Husar, Janja D.; Husar, Rudolf B.

    It is important to establish a reliable regional emission inventory of sulfur as a function of time when assessing the possible effects of global change and acid rain. This study developed a database of annual estimates of national sulfur emissions from 1850 to 1990. A common methodology was applied across all years and countries allowing for global totals to be produced by adding estimates from all countries. The consistent approach facilitates the modification of the database and the observation of changes at national, regional, or global levels. The emission estimates were based on net production (i.e., production plus imports minus exports), sulfur content, and sulfur retention for each country's production activities. Because the emission estimates were based on the above considerations, our database offers an opportunity to independently compare our results with those estimates based on individual country estimates. Fine temporal resolution clearly shows emission changes associated with specific historical events (e.g., wars, depressions, etc.) on a regional, national, or global basis. The spatial pattern of emissions shows that the US, the USSR, and China were the main sulfur emitters (i.e., approximately 50% of the total) in the world in 1990. The USSR and the US appear to have stabilized their sulfur emissions over the past 20 yr, and the recent increases in global sulfur emissions are linked to the rapid increases in emissions from China. Sulfur emissions have been reduced in some cases by switching from high- to low-sulfur coals. Flue gas desulfurization (FGD) has apparently made important contributions to emission reductions in only a few countries, such as Germany.

  13. Ammonia emissions from outdoor concrete yards used by livestock—quantification and mitigation

    NASA Astrophysics Data System (ADS)

    Misselbrook, T. H.; Webb, J.; Gilhespy, S. L.

    Outdoor concrete yards are commonly found on UK livestock farms, and, to a lesser extent, elsewhere in Europe, and represent a potentially significant source of ammonia (NH 3) emissions to the atmosphere. This study provided further measurements from a larger sample than previously made, to improve the robustness of the estimate of total NH 3 emission for inclusion in the UK NH 3 emission inventory. In addition, an assessment was made of a number of potential mitigation strategies. Measurements were made using the equilibrium concentration technique, employing small dynamic chambers and passive diffusion samplers, from 20 yards used by livestock on commercial farms. Mean emission rates (±standard error) were 0.31±0.07, 0.23±0.12, 0.19±0.05 and 0.18±0.09 g NH 3-N m -2 h -1 (0.70±0.21, 0.53±0.34, 0.76±0.22 and 0.18±0.14 g NH 3-N animal -1 h -1) for dairy cow-collecting yards, dairy cow-feeding yards, beef-feeding yards and sheep-feeding/handling areas, respectively, with mean respective livestock densities of 0.3, 0.5, 0.2 and 1.1 animals per m 2. There was a significant effect of season, with lower emission rates in the winter. There was a significant, albeit poor, positive linear relationship between emission rate and ambient air temperature ( r2=0.22) and between emission rate and total ammoniacal N content on the yard surface ( r2=0.14), but not with ambient wind speed. Pooling data from the present study with that from previous studies gave mean emission factors of 0.47±0.09, 0.98±0.39 and 0.13±0.09 g NH 3-N animal -1 h -1 for yards used by dairy cattle, beef cattle and sheep, respectively. Inclusion of these values, together with survey data on yard use, gave a total annual UK emission of approximately 25 kt NH 3 (95% confidence interval of 12-40 kt NH 3), representing almost 10% of total NH 3 emission from UK agriculture. In controlled studies, pressure washing and the use of a urease inhibitor in addition to yard scraping were found to be

  14. Mercury emissions to the atmosphere from natural and anthropogenic sources in the Mediterranean region

    NASA Astrophysics Data System (ADS)

    Pirrone, N.; Costa, P.; Pacyna, J. M.; Ferrara, R.

    This report discusses past, current and projected mercury emissions to the atmosphere from major industrial sources, and presents a first assessment of the contribution to the regional mercury budget from selected natural sources. Emissions (1995 estimates) from fossil fuels combustion (29.8 t yr -1) , cement production (28.8 t yr -1) and incineration of solid wastes (27.6 t yr -1) , all together account for about 82% of the regional anthropogenic total (105.7 t yr -1) . Other industrial sources in the region are smelters (4.8 t yr -1) , iron-steel plants (4.8 t yr -1) and other minor sources (chlor-alkali plants, crematoria, chemicals production) that have been considered together in the miscellaneous category (9.6 t yr -1) . Regional emissions from anthropogenic sources increased at a rate of 3% yr-1 from 1983 to 1995 and are projected to increase at a rate of 1.9% yr-1 in the next 25 years, if no improvement in emission control policy occurs. On a country-by-country basis, France is the leading emitter country with 22.6 t yr -1 followed by Turkey (16.1 t yr -1) , Italy (11.4 t yr -1) , Spain (9.1 t yr -1) , the former Yugoslavia 7.9 ( t yr -1) , Morocco (6.9 t yr -1) , Bulgaria (6.8 t yr -1) , Egypt (6.1 t yr -1) , Syria (3.6 t yr -1) , Libya (2.9 t yr -1) , Tunisia (2.8 t yr -1) and Greece (2.7 t yr -1) , whereas the remaining countries account for less than 7% of the regional total. The annual emission from natural sources is 110 t yr -1, although this figure only includes the volatilisation of elemental mercury from surface waters and emissions from volcanoes, whereas the contribution due to the degassing of mercury from top soil and vegetation has not been included in this first assessment. Therefore, natural and anthropogenic sources in the Mediterranean region release annually about 215 t of mercury, which represents a significant contribution to the total mercury budget released in Europe and to the global atmosphere.

  15. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile δ13CH4 analysis

    NASA Astrophysics Data System (ADS)

    Rella, C.; Crosson, E.; Petron, G.; Sweeney, C.; Karion, A.

    2013-12-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the δ13CH4 signature to distinguish between natural gas and landfills or ruminants. We present measurements of mobile field δ13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to arrive at an overall isotope ratio for the region. (left panel) Distribution of oil and gas well pads (yellow) and landfills (blue) in the Dallas / Ft. Worth area. Mobile nocturnal measurements

  16. High-resolution ammonia emissions inventories in Fujian, China, 2009-2015

    NASA Astrophysics Data System (ADS)

    Wu, Shui-Ping; Zhang, Yin-Ju; Schwab, James J.; Li, Yang-Fan; Liu, Yuan-Long; Yuan, Chung-Shin

    2017-08-01

    A high-resolution NH3 emission inventory was developed based on the corrected emission factors and county-level activity data. To provide model-ready emission input, the NH3 emission inventory was gridded for the modeling domain at 1 × 1 km resolution using source-based spatial surrogates and a GIS system. The best estimate of total NH3 emission for the province was 228.02 kt in 2015 with a percentage uncertainty of ±16.3%. Four major contributors were farmland ecosystem, livestock wastes, humans and waste treatment, which contributed 39.4%, 43.1%, 4.9%, and 4.2% of the total emissions, respectively. The averaged NH3 emission density for the whole region was 1.88 t km-2 yr-1 and the higher values were found in coastal areas with higher dense populations. The seasonal patterns, with higher emissions in summer, were consistent with the patterns of temperature and planting practices. From 2009 to 2015, annual NH3 emissions increased from 218.49 kt to 228.02 kt. All of these changes are insignificant compared to the estimated overall uncertainties in the analysis, but indicative of changes in the source categories over this period. Between 2009 and 2015, the largest changes occurred in human emissions and waste treatment plants, which were consistent with the process of rapid urbanization. Meanwhile, the decrease of emissions from pigs was slightly higher than the increased emissions from broilers and the increased emissions from meat goats and beef cattle due to the combine effects of increasingly stringent environmental requirements for pig farms and shift away from pork consumption to beef, chicken and mutton. The validity of the estimates was further evaluated using uncertainty analysis, comparison with previous studies, and correlation analysis between emission density and observed ground ammonia. The inventories reflect the changes in economic progress and environmental protection and can provide scientific basis for the establishment of effective PM2.5 control

  17. High-resolution inventory of ammonia emissions from agricultural fertilizer in China from 1978 to 2008

    NASA Astrophysics Data System (ADS)

    Xu, P.; Liao, Y. J.; Lin, Y. H.; Zhao, C. X.; Yan, C. H.; Cao, M. N.; Wang, G. S.; Luan, S. J.

    2016-02-01

    The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new Chinese agricultural fertilizer NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 × 1 km gridded map on the county level was developed for 2008; (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters; (3) the temporal patterns of historical time trends for 1978-2008 were estimated and the uncertainties were quantified for the inventories; and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 TgNH3 yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0 %. During the study period, the contribution of livestock manure spreading increased from 37.0 to 45.5 % because of changing fertilization practices and the rapid increase in egg, milk, and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3 % (minimum: 33.4 %; maximum: 42.7 %). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3 % and 8.5 %. The average contributions of cake fertilizer and straw returning were approximately 3.8 and 4.5 %, respectively, thus small and stable. Collectively, the CAF_NH3 emissions reflect the nation's agricultural policy to a certain extent. An effective approach to

  18. Temperature dependence of feedyard ammonia emissions: The Arrhenius equation

    USDA-ARS?s Scientific Manuscript database

    Ammonia emissions from beef cattle feedyards exhibit an annual pattern-like temperature. This suggests that ammonia emissions may obey the Arrhenius temperature relationship. Our objective was to determine the Arrhenius relationship between mean monthly ammonia emissions from cattle feedyards and me...

  19. Documentation for Emissions of Greenhouse Gases in the United States 2008

    EIA Publications

    2011-01-01

    The Energy Policy Act of 1992 required the U.S. Energy Information Administration (EIA) to prepare an inventory of aggregate U.S. national emissions of greenhouse gases for the period 1987-1990, with annual updates thereafter. This report documents the methodology for the seventeenth annual inventory, covering national emissions over the period 1990-2008.

  20. Hotspots of gross emissions from the land use sector: patterns, uncertainties, and leading emission sources for the period 2000-2005 in the tropics

    NASA Astrophysics Data System (ADS)

    Roman-Cuesta, Rosa Maria; Rufino, Mariana C.; Herold, Martin; Butterbach-Bahl, Klaus; Rosenstock, Todd S.; Herrero, Mario; Ogle, Stephen; Li, Changsheng; Poulter, Benjamin; Verchot, Louis; Martius, Christopher; Stuiver, John; de Bruin, Sytze

    2016-07-01

    According to the latest report of the Intergovernmental Panel on Climate Change (IPCC), emissions must be cut by 41-72 % below 2010 levels by 2050 for a likely chance of containing the global mean temperature increase to 2 °C. The AFOLU sector (Agriculture, Forestry and Other Land Use) contributes roughly a quarter ( ˜ 10-12 Pg CO2e yr-1) of the net anthropogenic GHG emissions mainly from deforestation, fire, wood harvesting, and agricultural emissions including croplands, paddy rice, and livestock. In spite of the importance of this sector, it is unclear where the regions with hotspots of AFOLU emissions are and how uncertain these emissions are. Here we present a novel, spatially comparable dataset containing annual mean estimates of gross AFOLU emissions (CO2, CH4, N2O), associated uncertainties, and leading emission sources, in a spatially disaggregated manner (0.5°) for the tropics for the period 2000-2005. Our data highlight the following: (i) the existence of AFOLU emissions hotspots on all continents, with particular importance of evergreen rainforest deforestation in Central and South America, fire in dry forests in Africa, and both peatland emissions and agriculture in Asia; (ii) a predominant contribution of forests and CO2 to the total AFOLU emissions (69 %) and to their uncertainties (98 %); (iii) higher gross fluxes from forests, which coincide with higher uncertainties, making agricultural hotspots appealing for effective mitigation action; and (iv) a lower contribution of non-CO2 agricultural emissions to the total gross emissions (ca. 25 %), with livestock (15.5 %) and rice (7 %) leading the emissions. Gross AFOLU tropical emissions of 8.0 (5.5-12.2) were in the range of other databases (8.4 and 8.0 Pg CO2e yr-1 in FAOSTAT and the Emissions Database for Global Atmospheric Research (EDGAR) respectively), but we offer a spatially detailed benchmark for monitoring progress in reducing emissions from the land sector in the tropics. The location of

  1. 28 CFR 16.208 - Annual report.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 28 Judicial Administration 1 2012-07-01 2012-07-01 false Annual report. 16.208 Section 16.208... Observation of Parole Commission Meetings § 16.208 Annual report. The Commission shall report annually to Congress regarding its compliance with Sunshine Act requirements, including a tabulation of the total...

  2. 28 CFR 16.208 - Annual report.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 28 Judicial Administration 1 2011-07-01 2011-07-01 false Annual report. 16.208 Section 16.208... Observation of Parole Commission Meetings § 16.208 Annual report. The Commission shall report annually to Congress regarding its compliance with Sunshine Act requirements, including a tabulation of the total...

  3. 28 CFR 16.208 - Annual report.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Annual report. 16.208 Section 16.208... Observation of Parole Commission Meetings § 16.208 Annual report. The Commission shall report annually to Congress regarding its compliance with Sunshine Act requirements, including a tabulation of the total...

  4. 28 CFR 16.208 - Annual report.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 28 Judicial Administration 1 2014-07-01 2014-07-01 false Annual report. 16.208 Section 16.208... Observation of Parole Commission Meetings § 16.208 Annual report. The Commission shall report annually to Congress regarding its compliance with Sunshine Act requirements, including a tabulation of the total...

  5. Impacts of natural factors and farming practices on greenhouse gas emissions in the North China Plain: A meta-analysis.

    PubMed

    Xu, Cong; Han, Xiao; Bol, Roland; Smith, Pete; Wu, Wenliang; Meng, Fanqiao

    2017-09-01

    Requirements for mitigation of the continued increase in greenhouse gas (GHG) emissions are much needed for the North China Plain (NCP). We conducted a meta-analysis of 76 published studies of 24 sites in the NCP to examine the effects of natural conditions and farming practices on GHG emissions in that region. We found that N 2 O was the main component of the area-scaled total GHG balance, and the CH 4 contribution was <5%. Precipitation, temperature, soil pH, and texture had no significant impacts on annual GHG emissions, because of limited variation of these factors in the NCP. The N 2 O emissions increased exponentially with mineral fertilizer N application rate, with y  =   0.2389e 0.0058 x for wheat season and y  =   0.365e 0.0071 x for maize season. Emission factors were estimated at 0.37% for wheat and 0.90% for maize at conventional fertilizer N application rates. The agronomic optimal N rates (241 and 185 kg N ha -1 for wheat and maize, respectively) exhibited great potential for reducing N 2 O emissions, by 0.39 (29%) and 1.71 (56%) kg N 2 O-N ha -1  season -1 for the wheat and maize seasons, respectively. Mixed application of organic manure with reduced mineral fertilizer N could reduce annual N 2 O emissions by 16% relative to mineral N application alone while maintaining a high crop yield. Compared with conventional tillage, no-tillage significantly reduced N 2 O emissions by ~30% in the wheat season, whereas it increased those emissions by ~10% in the maize season. This may have resulted from the lower soil temperature in winter and increased soil moisture in summer under no-tillage practice. Straw incorporation significantly increased annual N 2 O emissions, by 26% relative to straw removal. Our analysis indicates that these farming practices could be further tested to mitigate GHG emission and maintain high crop yields in the NCP.

  6. The Establishment of LTO Emission Inventory of Civil Aviation Airports Based on Big Data

    NASA Astrophysics Data System (ADS)

    Lu, Chengwei; Liu, Hefan; Song, Danlin; Yang, Xinyue; Tan, Qinwen; Hu, Xiang; Kang, Xue

    2018-03-01

    An estimation model on LTO emissions of civil aviation airports was developed in this paper, LTO big data was acquired by analysing the internet with Python, while the LTO emissions was dynamically calculated based on daily LTO data, an uncertainty analysis was conducted with Monte Carlo method. Through the model, the emission of LTO in Shuangliu International Airport was calculated, and the characteristics and temporal distribution of LTO in 2015 was analysed. Results indicates that compared with the traditional methods, the model established can calculate the LTO emissions from different types of airplanes more accurately. Based on the hourly LTO information of 302 valid days, it was obtained that the total number of LTO cycles in Chengdu Shuangliu International Airport was 274,645 and the annual amount of emission of SO2, NOx, VOCs, CO, PM10 and PM2.5 was estimated, and the uncertainty of the model was around 7% to 10% varies on pollutants.

  7. Hypergolic oxidizer and fuel scrubber emissions

    NASA Technical Reports Server (NTRS)

    Parrish, Clyde F.; Barile, Ronald G.; Curran, Dan; Hodge, Tim; Lueck, Dale E.; Young, Rebecca C.

    1995-01-01

    Hypergolic fuels and oxidizer are emitted to the environment during fueling and deservicing shuttle and other spacecraft. Such emissions are difficult to measure due to the intermittent purge flow and to the presence of suspended scrubber liquor. A new method for emissions monitoring was introduced in a previous paper. This paper is a summary of the results of a one-year study of shuttle launch pads and orbiter processing facilities (OPF's) which proved that emissions can be determined from field scrubbers without direct measurement of vent flow rate and hypergol concentration. This new approach is based on the scrubber efficiency, which was measured during normal operations, and on the accumulated weight of hypergol captured in the scrubber liquor, which is part of the routine monitoring data of scrubber liquors. To validate this concept, three qualification tests were performed, logs were prepared for each of 16 hypergol scrubbers at KSC, the efficiencies of KSC scrubbers were measured during normal operations, and an estimate of the annual emissions was made based on the efficiencies and the propellant buildup data. The results have confirmed that the emissions from the KSC scrubbers can be monitored by measuring the buildup of hypergol propellant in the liquor, and then using the appropriate efficiency to calculate the emissions. There was good agreement between the calculated emissions based on outlet concentration and flow rate, and the emissions calculated from the propellant buildup and efficiency. The efficiencies of 12 KSC scrubbers, measured under actual servicing operations and special test conditions, were assumed to be valid for all subsequent operations until a significant change in hardware occurred. An estimate of the total emissions from 16 scrubbers for three years showed that 0.3 kg/yr of fuel and 234 kg/yr of oxidizer were emitted.

  8. N2O emissions from secondary clarifiers and their contribution to the total emissions of the WWTP.

    PubMed

    Mikola, Anna; Heinonen, Mari; Kosonen, Heta; Leppänen, Maarit; Rantanen, Pirjo; Vahala, Riku

    2014-01-01

    Recent studies have indicated that the emissions of nitrous oxide, N2O, constitute a major part of the carbon footprint of wastewater treatment plants (WWTPs). Denitrification occurring in the secondary clarifier basins has been observed by many researchers, but until now N2O emissions from secondary clarifiers have not been widely reported. The objective of this study was to measure the N2O emissions from secondary clarifiers and weigh the portion they could represent of the overall emissions at WWTPs. Online measurements over several days were carried out at four different municipal WWTPs in Finland in cold weather conditions (March) and in warm weather conditions (June-July). An attempt was made to define the conditions in which N2O emissions from secondary clarifiers may occur. It was evidenced that large amounts of N2O can be emitted from the secondary clarifiers, and that the emissions have long-term variation. It was assumed that part of the N2O released in secondary clarification was originally formed in the activated sludge basin. The emissions from secondary clarification thus seem to be dependent on conditions of the nitrification and denitrification accomplished in the denitrification-nitrification process and on the amount of sludge stored in the secondary clarifiers.

  9. Greenhouse Gas Emission from Beef Cattle Grazing Systems on Temperate Grasslands

    NASA Astrophysics Data System (ADS)

    Rice, C. W.; Rivera-Zayas, J.

    2017-12-01

    At a global scale, cattle production is responsible for 65% of GHG emissions. During 2014 cattle management was the largest emitters of methane (CH4) representing a 23.2% of the total CH4 from anthropogenic activities. Since 2014, gas samples have been gathered and analyzed for carbon dioxide (CO2), CH4 and nitrous oxide (N2O) from three grazing areas under three different burning regimes at the temperate grassland of Konza Prairie Biological Station in Kansas. Burning regimes included one site in annually burned, and two sites with patch burned every three years on offset years. Burning regimes showed no effect in N2O emissions (p<0.05). Annual burning lowered CO2 emissions relative to patch burned. There was a significant effect of interaction between emissions and season. Maximum CO2 and CH4 fluxes were gathered during summer and fall; which coincided with high biomass seasons. Weather and edaphological conditions during fall and winter increase N2O emissions. A decrease in CO2 and CH4 fluxes, and N2O and CH4 soil uptake occurred during winter. Data gathered since 2014 implies CH4 and N2O are consumed on grazed grassland soils; with an increase in consumption with patch burning. Results quantify the role of temperate grasslands as a sink of CH4, and a possible sink of N2O. This experiment evidence CO2, CH4 and N2O emissions behavior as a consequence of burning regimes, and quantify the role of temperate grasslands as a sink of CH4 and N2O in order to understand best practice for resilience of beef cattle management.

  10. Radiocarbon measurements constrain the fossil and biological components of total CO2

    NASA Astrophysics Data System (ADS)

    Miller, J. B.; Lehman, S. J.; Tans, P. P.; Turnbull, J. C.

    2009-12-01

    In a rapidly evolving environment in which binding treaties and laws at the international, national and state levels are likely to limit greenhouse gas emissions, it will be critical for society to have independent verification of emissions and their accumulation in the atmosphere. Current treaties and laws like the Kyoto Protocol and California’s AB32 rely upon “bottom-up” reporting by governments and industry from inventories and process models to assess emissions. What we propose here is that to promote accuracy and transparency, it will also be necessary to verify these “bottom-up” approaches from the “top-down” perspective of the atmosphere. In particular, total CO2, which is the bottom line for climate forcing, and fossil fuel CO2, which is the primary driver of the observed increase need to be monitored. Total CO2 is already measured at high precision and accuracy at numerous sites nationally and globally by a variety of university and government entities (see e.g., www.esrl.noaa.gov/gmd/ccgg/globalview/). CO2 measurements in more locations and at higher frequencies are required to establish tighter constraints to emissions. For fossil fuel CO2, however, we require measurements of the rare isotopic species 14CO2. Fossil fuel emissions of CO2 are devoid of 14 (radiocarbon), because, by definition, these fuels are many millions of years old and the 14 half-life is only 5730 years. This makes 14CO2 an ideal tracer for fossil fuel emissions. Here we will present results of a nascent United States 14CO2 observation program that together with model simulations suggest a large number of 14CO2 measurements over the coterminous USA would allow for tight (~20%) regional (~105 - 106 km2) constraints on fossil fuel emissions at annual or seasonal time scales. Additionally, correlations of our 14CO2 observations with a wide suite of anthropogenic tracers suggest that “tuning” of these tracers with 14CO2 for fossil fuel detection may be possible

  11. Simple approximation of total emissivity of CO2-H2O mixture used in the zonal method of calculation of heat transfer by radiation

    NASA Astrophysics Data System (ADS)

    Lisienko, V. G.; Malikov, G. K.; Titaev, A. A.

    2014-12-01

    The paper presents a new simple-to-use expression to calculate the total emissivity of a mixture of gases CO2 and H2O used for modeling heat transfer by radiation in industrial furnaces. The accuracy of this expression is evaluated using the exponential wide band model. It is found that the time taken to calculate the total emissivity in this expression is 1.5 times less than in other approximation methods.

  12. Direct Nitrous Oxide Emissions From Tropical And Sub-Tropical Agricultural Systems - A Review And Modelling Of Emission Factors.

    PubMed

    Albanito, Fabrizio; Lebender, Ulrike; Cornulier, Thomas; Sapkota, Tek B; Brentrup, Frank; Stirling, Clare; Hillier, Jon

    2017-03-10

    There has been much debate about the uncertainties associated with the estimation of direct and indirect agricultural nitrous oxide (N 2 O) emissions in developing countries and in particular from tropical regions. In this study, we report an up-to-date review of the information published in peer-review journals on direct N 2 O emissions from agricultural systems in tropical and sub-tropical regions. We statistically analyze net-N 2 O-N emissions to estimate tropic-specific annual N 2 O emission factors (N 2 O-EFs) using a Generalized Additive Mixed Model (GAMM) which allowed the effects of multiple covariates to be modelled as linear or smooth non-linear continuous functions. Overall the mean N 2 O-EF was 1.2% for the tropics and sub-tropics, thus within the uncertainty range of IPCC-EF. On a regional basis, mean N 2 O-EFs were 1.4% for Africa, 1.1%, for Asia, 0.9% for Australia and 1.3% for Central &South America. Our annual N 2 O-EFs, estimated for a range of fertiliser rates using the available data, do not support recent studies hypothesising non-linear increase N 2 O-EFs as a function of applied N. Our findings highlight that in reporting annual N 2 O emissions and estimating N 2 O-EFs, particular attention should be paid in modelling the effect of study length on response of N 2 O.

  13. Direct Nitrous Oxide Emissions From Tropical And Sub-Tropical Agricultural Systems - A Review And Modelling Of Emission Factors

    PubMed Central

    Albanito, Fabrizio; Lebender, Ulrike; Cornulier, Thomas; Sapkota, Tek B.; Brentrup, Frank; Stirling, Clare; Hillier, Jon

    2017-01-01

    There has been much debate about the uncertainties associated with the estimation of direct and indirect agricultural nitrous oxide (N2O) emissions in developing countries and in particular from tropical regions. In this study, we report an up-to-date review of the information published in peer-review journals on direct N2O emissions from agricultural systems in tropical and sub-tropical regions. We statistically analyze net-N2O-N emissions to estimate tropic-specific annual N2O emission factors (N2O-EFs) using a Generalized Additive Mixed Model (GAMM) which allowed the effects of multiple covariates to be modelled as linear or smooth non-linear continuous functions. Overall the mean N2O-EF was 1.2% for the tropics and sub-tropics, thus within the uncertainty range of IPCC-EF. On a regional basis, mean N2O-EFs were 1.4% for Africa, 1.1%, for Asia, 0.9% for Australia and 1.3% for Central & South America. Our annual N2O-EFs, estimated for a range of fertiliser rates using the available data, do not support recent studies hypothesising non-linear increase N2O-EFs as a function of applied N. Our findings highlight that in reporting annual N2O emissions and estimating N2O-EFs, particular attention should be paid in modelling the effect of study length on response of N2O. PMID:28281637

  14. Direct Nitrous Oxide Emissions From Tropical And Sub-Tropical Agricultural Systems - A Review And Modelling Of Emission Factors

    NASA Astrophysics Data System (ADS)

    Albanito, Fabrizio; Lebender, Ulrike; Cornulier, Thomas; Sapkota, Tek B.; Brentrup, Frank; Stirling, Clare; Hillier, Jon

    2017-03-01

    There has been much debate about the uncertainties associated with the estimation of direct and indirect agricultural nitrous oxide (N2O) emissions in developing countries and in particular from tropical regions. In this study, we report an up-to-date review of the information published in peer-review journals on direct N2O emissions from agricultural systems in tropical and sub-tropical regions. We statistically analyze net-N2O-N emissions to estimate tropic-specific annual N2O emission factors (N2O-EFs) using a Generalized Additive Mixed Model (GAMM) which allowed the effects of multiple covariates to be modelled as linear or smooth non-linear continuous functions. Overall the mean N2O-EF was 1.2% for the tropics and sub-tropics, thus within the uncertainty range of IPCC-EF. On a regional basis, mean N2O-EFs were 1.4% for Africa, 1.1%, for Asia, 0.9% for Australia and 1.3% for Central & South America. Our annual N2O-EFs, estimated for a range of fertiliser rates using the available data, do not support recent studies hypothesising non-linear increase N2O-EFs as a function of applied N. Our findings highlight that in reporting annual N2O emissions and estimating N2O-EFs, particular attention should be paid in modelling the effect of study length on response of N2O.

  15. CO2 Emissions Generated by a Fall AGU Meeting

    NASA Astrophysics Data System (ADS)

    osborn, G.; Malowany, K. S.; Samolczyk, M. A.

    2011-12-01

    The process of reporting on and discussing geophysical phenomena, including emissions of greenhouse gases, generates more greenhouse gases. At the 2010 fall meeting of the AGU, 19,175 delegates from 81 countries, including, for example, Eritrea, Nepal, and Tanzania, traveled a total of 156,000,000 km to congregate in San Francisco for five days. With data on home bases of participants provided by AGU, we estimated the CO2 emissions generated by travel and hotel stays of those participants. The majority of the emissions from the meeting resulted from air travel . In order to estimate the footprint of such travel, (a) distances from the largest airport in each country and American state (except Canada and California) to San Francisco were tabulated , (b) basic distances were converted to emissions using the TerraPass (TRX Travel Analytics) carbon calculator, (c) it was assumed that half the California participants would fly and half would drive, (d) it was assumed that half of Canadians would fly out of Toronto and half out of Vancouver, and (e) a fudge factor of 10% was added to air travel emissions to account for connecting flights made by some participants to the main airports in the respective countries (connecting flights are disproportionately significant because of high output during takeoff acceleration). Driving impacts were estimated with a Transport Direct/RAC Motoring Services calculator using a 2006 Toyota Corolla as a standard car. An average driving distance of 50 km to the departure airport, and from the airport upon return, was assumed. Train impacts were estimated using the assumption that all flying participants would take BART from SFO. Accomodation impacts were estimated using an Environmental Protection Agency calculator, an assumed average stay of 3 nights, and the assumption that 500 participants commuted from local residences or stayed with friends. The above assumptions lead to an estimate, which we consider conservative, of 19 million kg of

  16. International energy annual 1996

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-02-01

    The International Energy Annual presents an overview of key international energy trends for production, consumption, imports, and exports of primary energy commodities in over 220 countries, dependencies, and areas of special sovereignty. Also included are population and gross domestic product data, as well as prices for crude oil and petroleum products in selected countries. Renewable energy reported in the International Energy Annual includes hydroelectric power, geothermal, solar, and wind electric power, biofuels energy for the US, and biofuels electric power for Brazil. New in the 1996 edition are estimates of carbon dioxide emissions from the consumption of petroleum and coal,more » and the consumption and flaring of natural gas. 72 tabs.« less

  17. Assessing the impacts of tillage and fertilization management on nitrous oxide emissions in a cornfield using the DNDC model

    NASA Astrophysics Data System (ADS)

    Deng, Qi; Hui, Dafeng; Wang, Junming; Yu, Chih-Li; Li, Changsheng; Reddy, K. Chandra; Dennis, Sam

    2016-02-01

    Quantification and prediction of N2O emissions from croplands under different agricultural management practices are vital for sustainable agriculture and climate change mitigation. We simulated N2O emissions under tillage and no-tillage,and different nitrogen (N) fertilizer types and application methods (i.e., nitrification inhibitor, chicken manure, and split applications) in a cornfield using the DeNitrification-DeComposition (DNDC) model. The model was parameterized with field experimental data collected in Nashville, Tennessee, under various agricultural management treatments and run for a short term (3 years) and a long term (100 years). Results showed that the DNDC model could adequately simulate N2O emissions as well as soil properties under different agricultural management practices. The modeled emissions of N2O significantly increased by 35% with tillage, and decreased by 24% with the use of nitrification inhibitor, compared with no-tillage and normal N fertilization. Chicken manure amendment and split applications of N fertilizer had minor impact on N2O emission in a short term, but over a long term (100 years) the treatments significantly altered N2O emission (+35%, -10%, respectively). Sensitivity analysis showed that N2O emission was sensitive to mean annual precipitation, mean annual temperature, soil organic carbon, and the amount of total N fertilizer application. Our model results provide valuable information for determining agricultural best management practice to maintain highly productive corn yield while reducing greenhouse gas emissions.

  18. Estimating methane emissions in California's urban and rural regions using multitower observations

    DOE PAGES

    Jeong, Seongeun; Newman, Sally; Zhang, Jingsong; ...

    2016-11-05

    Here, we present an analysis of methane (CH 4) emissions using atmospheric observations from 36 thirteen sites in California during June 2013 – May 2014. A hierarchical Bayesian inversion 37 method is used to estimate CH 4 emissions for spatial regions (0.3° pixels for major regions) by 38 comparing measured CH 4 mixing ratios with transport model (WRF-STILT) predictions based 39 on seasonally varying California-specific CH 4 prior emission models. The transport model is 40 assessed using a combination of meteorological and carbon monoxide (CO) measurements 41 coupled with the gridded California Air Resources Board (CARB) carbon monoxide (CO) 42more » emission inventory. Hierarchical Bayesian inversion suggests that state annual anthropogenic 43 CH 4 emissions are 2.42 ± 0.49 Tg CH 4/yr (at 95% confidence, including transport bias 44 uncertainty), higher (1.2 - 1.8 times) than the CARB current inventory (1.64 Tg CH 4/yr in 2013). 45 We note that the estimated CH 4 emissions drop to 1.0 - 1.6 times the CARB inventory if we 46 correct for the 10% median CH 4 emissions assuming the bias in CO analysis is applicable to 47 CH 4. The CH 4 emissions from the Central Valley and urban regions (San Francisco Bay and 48 South Coast Air Basins) account for ~58% and 26% of the total posterior emissions, 49 respectively. This study suggests that the livestock sector is likely the major contributor to the 50 state total CH 4 emissions, in agreement with CARB’s inventory. Attribution to source sectors for 51 sub-regions of California using additional trace gas species would further improve the 52 quantification of California’s CH 4 emissions and mitigation efforts towards the California Global 53 Warming Solutions Act of 2006 (AB-32).« less

  19. Estimating methane emissions in California's urban and rural regions using multitower observations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jeong, Seongeun; Newman, Sally; Zhang, Jingsong

    Here, we present an analysis of methane (CH 4) emissions using atmospheric observations from 36 thirteen sites in California during June 2013 – May 2014. A hierarchical Bayesian inversion 37 method is used to estimate CH 4 emissions for spatial regions (0.3° pixels for major regions) by 38 comparing measured CH 4 mixing ratios with transport model (WRF-STILT) predictions based 39 on seasonally varying California-specific CH 4 prior emission models. The transport model is 40 assessed using a combination of meteorological and carbon monoxide (CO) measurements 41 coupled with the gridded California Air Resources Board (CARB) carbon monoxide (CO) 42more » emission inventory. Hierarchical Bayesian inversion suggests that state annual anthropogenic 43 CH 4 emissions are 2.42 ± 0.49 Tg CH 4/yr (at 95% confidence, including transport bias 44 uncertainty), higher (1.2 - 1.8 times) than the CARB current inventory (1.64 Tg CH 4/yr in 2013). 45 We note that the estimated CH 4 emissions drop to 1.0 - 1.6 times the CARB inventory if we 46 correct for the 10% median CH 4 emissions assuming the bias in CO analysis is applicable to 47 CH 4. The CH 4 emissions from the Central Valley and urban regions (San Francisco Bay and 48 South Coast Air Basins) account for ~58% and 26% of the total posterior emissions, 49 respectively. This study suggests that the livestock sector is likely the major contributor to the 50 state total CH 4 emissions, in agreement with CARB’s inventory. Attribution to source sectors for 51 sub-regions of California using additional trace gas species would further improve the 52 quantification of California’s CH 4 emissions and mitigation efforts towards the California Global 53 Warming Solutions Act of 2006 (AB-32).« less

  20. Total Quality Leadership

    NASA Technical Reports Server (NTRS)

    1991-01-01

    More than 750 NASA, government, contractor, and academic representatives attended the Seventh Annual NASA/Contractors Conference on Quality and Productivity. The panel presentations and Keynote speeches revolving around the theme of total quality leadership provided a solid base of understanding of the importance, benefits, and principles of total quality management (TQM). The presentations from the conference are summarized.

  1. 49 CFR 219.800 - Annual reports.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Annual reports. 219.800 Section 219.800 Transportation Other Regulations Relating to Transportation (Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION CONTROL OF ALCOHOL AND DRUG USE Annual Report § 219.800 Annual reports. (a) Each railroad that has a total of 400,000 or more...

  2. Reducing N2O and NO emissions while sustaining crop productivity in a Chinese vegetable-cereal double cropping system.

    PubMed

    Yao, Zhisheng; Yan, Guangxuan; Zheng, Xunhua; Wang, Rui; Liu, Chunyan; Butterbach-Bahl, Klaus

    2017-12-01

    High nitrogen (N) inputs in Chinese vegetable and cereal productions played key roles in increasing crop yields. However, emissions of the potent greenhouse gas nitrous oxide (N 2 O) and atmospheric pollutant nitric oxide (NO) increased too. For lowering the environmental costs of crop production, it is essential to optimize N strategies to maintain high crop productivity, while reducing the associated N losses. We performed a 2 year-round field study regarding the effect of different combinations of poultry manure and chemical N fertilizers on crop yields, N use efficiency (NUE) and N 2 O and NO fluxes from a Welsh onion-winter wheat system in the North China Plain. Annual N 2 O and NO emissions averaged 1.14-3.82 kg N ha -1 yr -1 (or 5.54-13.06 g N kg -1 N uptake) and 0.57-1.87 kg N ha -1 yr -1 (or 2.78-6.38 g N kg -1 N uptake) over all treatments, respectively. Both N 2 O and NO emissions increased linearly with increasing total N inputs, and the mean annual direct emission factors (EF d ) were 0.39% for N 2 O and 0.19% for NO. Interestingly, the EF d for chemical N fertilizers (N 2 O: 0.42-0.48%; NO: 0.07-0.11%) was significantly lower than for manure N (N 2 O: 1.35%; NO: 0.76%). Besides, a negative power relationship between yield-scaled N 2 O, NO or N 2 O + NO emissions and NUE was observed, suggesting that improving NUE in crop production is crucial for increasing crop yields while decreasing nitrogenous gas release. Compared to the current farmers' fertilization rate, alternative practices with reduced chemical N fertilizers increased NUE and decreased annual N 2 O + NO emissions substantially, while crop yields remained unaffected. As a result, annual yield-scaled N 2 O + NO emissions were reduced by > 20%. Our study shows that a reduction of current application rates of chemical N fertilizers by 30-50% does not affect crop productivity, while at the same time N 2 O and NO emissions would be reduced significantly. Copyright © 2017 Elsevier Ltd. All rights

  3. Annual Certification Data for Vehicles and Engines

    EPA Pesticide Factsheets

    The Annual Certification Test Results Report (often referred to as Federal Register Test Results Report) includes light-duty vehicle and heavy-duty engine reports of projected emission levels at the end of the useful life of a vehicle.

  4. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to physicochemical limnology and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included Direct Ebullition, Diffusion, Storage flux, and a newly identified Ice-Bubble Storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, but themore » climate warming impact of lake CH 4 emissions was two times higher than that of CO 2. Ebullition and Diffusion were the dominant modes of CH 4 and CO 2 emissions respectively. IBS, ~ 10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, dystrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. Total CH 4 emission was correlated with concentrations of phosphate and total nitrogen in lake water, Secchi depth and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

  5. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE PAGES

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; ...

    2014-09-12

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to physicochemical limnology and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included Direct Ebullition, Diffusion, Storage flux, and a newly identified Ice-Bubble Storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, but themore » climate warming impact of lake CH 4 emissions was two times higher than that of CO 2. Ebullition and Diffusion were the dominant modes of CH 4 and CO 2 emissions respectively. IBS, ~ 10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, dystrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. Total CH 4 emission was correlated with concentrations of phosphate and total nitrogen in lake water, Secchi depth and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

  6. Amtrak annual report, 2007

    DOT National Transportation Integrated Search

    2007-01-01

    In FY 2007, Amtrak earned approximately : $2.15 billion in total revenue and incurred about : $3.18 billion in expenses. Amtrak relies on an : annual federal appropriation, which in FY 2007 : totaled $1.294 billion, including $521 million in : operat...

  7. Amtrak annual report, 2008

    DOT National Transportation Integrated Search

    2008-01-01

    In FY 2008, Amtrak earned approximately $2.45 billion in total revenue and incurred about $3.41 billion in : expenses. The annual federal appropriation on which Amtrak relies : totaled $1.325 billion in FY 2008, comprising $475 million in : operating...

  8. Seasonal variations in VOC emission rates from gorse (Ulex europaeus)

    NASA Astrophysics Data System (ADS)

    Boissard, C.; Cao, X.-L.; Juan, C.-Y.; Hewitt, C. N.; Gallagher, M.

    Seasonal variations of biogenic volatile organic compound (VOC) emission rates and standardised emission factors from gorse (Ulex europaeus) have been measured at two sites in the United Kingdom, from October 1994 to September 1995, within temperature and PAR conditions ranging from 3 to 34°C and 10-1300 μmol m-2 s-1, respectively. Isoprene was the dominant emitted compound with a relative composition fluctuating from 7% of the total VOC (winter) to 97% (late summer). The monoterpenes α-pinene, camphene, sabinene, β-pinene, myrcene, limonene, trans-ocimene and γ-terpinene were also emitted, with α-pinene being the dominant monoterpene during most the year. Trans-ocimene represented 33-66% of the total monoterpene during the hottest months from June to September. VOC emissions were found to be accurately predicted using existing algorithms. Standard (normalised) emission factors of VOCs from gorse were calculated using experimental parameters measured during the experiment and found to fluctuate with season, from 13.3±2.1 to 0.1±0.1 μg C (g dwt)-1 h-1 in August 1995 and January 1995, respectively, for isoprene, and from 2.5±0.2 to 0.4±0.2 μg C (g dwt)-1 h-1 in July and November 1995, respectively, for total monoterpenes. No simple clear relation was found to allow prediction of these seasonal variations with respect to temperature and light intensity. The effects of using inappropriate algorithms to derive VOC fluxes from gorse were assessed for isoprene and monoterpenes. Although on an annual basis the discrepancies are not significant, monthly estimation of isoprene were found to be overestimated by more than a factor of 50 during wintertime when the seasonality of emission factors is not considered.

  9. 40 CFR 98.163 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.163 Calculating GHG emissions. You must calculate and report the annual CO2 emissions from each hydrogen production process unit using the... associated with each fuel and feedstock used for hydrogen production by following paragraphs (b)(1) through...

  10. 40 CFR 98.163 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.163 Calculating GHG emissions. You must calculate and report the annual CO2 emissions from each hydrogen production process unit using the... associated with each fuel and feedstock used for hydrogen production by following paragraphs (b)(1) through...

  11. 40 CFR 98.163 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.163 Calculating GHG emissions. You must calculate and report the annual CO2 emissions from each hydrogen production process unit using the... associated with each fuel and feedstock used for hydrogen production by following paragraphs (b)(1) through...

  12. 40 CFR 98.163 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Hydrogen Production § 98.163 Calculating GHG emissions. You must calculate and report the annual CO2 emissions from each hydrogen production process unit using the... associated with each fuel and feedstock used for hydrogen production by following paragraphs (b)(1) through...

  13. A patient-centred approach to estimate total annual healthcare cost by body mass index in the UK Counterweight programme.

    PubMed

    Tigbe, W W; Briggs, A H; Lean, M E J

    2013-08-01

    Previous studies, based on relative risks for certain secondary diseases, have shown greater healthcare costs in higher body mass index (BMI) categories. The present study quantifies the relationship between BMI and total healthcare expenditure, with the patient as the unit of analysis. Analyses of cross-sectional data, collected over 18-months in 2002-2003, from 3324 randomly selected patients, in 65 general practices across UK. Healthcare costs estimated from primary care, outpatient, accident/emergency and hospitalisation attendances, weighted by unit costs taken from standard sources. In univariate analyses, significant associations (P<0.05) were found between total healthcare expenditure and all dependent variables (women>men, drinkernon-smokers, and increasing with greater physical activity, age and BMI. In multivariate analysis, age, sex, BMI, smoking and alcohol consumption remained significantly associated with healthcare cost, and together explained just 9% of the variance in healthcare expenditure. Adjusted total annual healthcare cost was £16 (95% CI £11-£21) higher per unit BMI. All cost categories were significantly (P<0.003) higher for those with BMI >40 compared with BMI <20 kg m(-2): prescription drugs (men: £390 versus £16; women: £211 versus £73), hospitalisation (men: £72 versus £0; women: £243 versus £107), primary care (men: £191 versus £69; women: £268 versus £153) and outpatient care (£234 versus £107 women only). Annual healthcare expenditure rose a mean of £16 per unit greater BMI, doubling between BMI 20-40 kg m(-2). This gradient may be an underestimate if the lower-BMI patients with heights and weights recorded had other costly diseases.

  14. Inventory of methane emissions from U.S. cattle

    NASA Astrophysics Data System (ADS)

    Westberg, H.; Lamb, B.; Johnson, K. A.; Huyler, M.

    2001-01-01

    Many countries, including the United States, are in the process of inventorying greenhouse gas emissions as a prerequisite for designing control strategies. We have developed a measurement-based inventory of methane emissions from cattle in the United States. Methane emission factors were established for the major livestock groups using an internal tracer method. The groups studied included cows, replacement heifers, slaughter cattle, calves, and bulls in the beef sector and cows plus replacement heifers in the dairy industry. Since methane emission is dependent on the quality and quantity of feed, diets were chosen that are representative of the feed regimes utilized by producers in the United States. Regional cattle populations, obtained from U.S. Department of Agriculture statistics, were combined with the methane emission factors to yield regional emission estimates. The methane totals from the five regions were then summed to give a U.S. inventory of cattle emissions for 1990, 1992, 1994, 1996, and 1998. Annual releases ranged from 6.50 Tg in 1990 to a high of 6.98 Tg in 1996. On a regional scale the North Central region of the United States had the largest methane emissions from livestock followed by the South Central and the West. The beef cow group released the most methane (˜2.5 Tg yr-1) followed by slaughter cattle (˜1.7 Tg yr-1) and dairy cows at about 1.5 Tg yr-1. Methane released by cattle in the United States contributes about 11% of the global cattle source.

  15. Sunlight-induced carbon dioxide emissions from inland waters

    NASA Astrophysics Data System (ADS)

    Koehler, Birgit; Landelius, Tomas; Weyhenmeyer, Gesa A.; Machida, Nanako; Tranvik, Lars J.

    2014-07-01

    The emissions of carbon dioxide (CO2) from inland waters are substantial on a global scale. Yet the fundamental question remains open which proportion of these CO2 emissions is induced by sunlight via photochemical mineralization of dissolved organic carbon (DOC), rather than by microbial respiration during DOC decomposition. Also, it is unknown on larger spatial and temporal scales how photochemical mineralization compares to other C fluxes in the inland water C cycle. We combined field and laboratory data with atmospheric radiative transfer modeling to parameterize a photochemical rate model for each day of the year 2009, for 1086 lakes situated between latitudes from 55°N to 69°N in Sweden. The sunlight-induced production of dissolved inorganic carbon (DIC) averaged 3.8 ± 0.04 g C m-2 yr-1, which is a flux comparable in size to the organic carbon burial in the lake sediments. Countrywide, 151 ± 1 kt C yr-1 was produced by photochemical mineralization, corresponding to about 12% of total annual mean CO2 emissions from Swedish lakes. With a median depth of 3.2 m, the lakes were generally deep enough that incoming, photochemically active photons were absorbed in the water column. This resulted in a linear positive relationship between DIC photoproduction and the incoming photon flux, which corresponds to the absorbed photons. Therefore, the slope of the regression line represents the wavelength- and depth-integrated apparent quantum yield of DIC photoproduction. We used this relationship to obtain a first estimate of DIC photoproduction in lakes and reservoirs worldwide. Global DIC photoproduction amounted to 13 and 35 Mt C yr-1 under overcast and clear sky, respectively. Consequently, these directly sunlight-induced CO2 emissions contribute up to about one tenth to the global CO2 emissions from lakes and reservoirs, corroborating that microbial respiration contributes a substantially larger share than formerly thought, and generate annual C fluxes similar in

  16. Climatology of nocturnal low-level jets over North Africa and implications for modeling mineral dust emission.

    PubMed

    Fiedler, S; Schepanski, K; Heinold, B; Knippertz, P; Tegen, I

    2013-06-27

    [1] This study presents the first climatology for the dust emission amount associated with Nocturnal Low-Level Jets (NLLJs) in North Africa. These wind speed maxima near the top of the nocturnal boundary layer can generate near-surface peak winds due to shear-driven turbulence in the course of the night and the NLLJ breakdown during the following morning. The associated increase in the near-surface wind speed is a driver for mineral dust emission. A new detection algorithm for NLLJs is presented and used for a statistical assessment of NLLJs in 32 years of ERA-Interim reanalysis from the European Centre for Medium-Range Weather Forecasts. NLLJs occur in 29% of the nights in the annual and spatial mean. The NLLJ climatology shows a distinct annual cycle with marked regional differences. Maxima of up to 80% NLLJ frequency are found where low-level baroclinicity and orographic channels cause favorable conditions, e.g., over the Bodélé Depression, Chad, for November-February and along the West Saharan and Mauritanian coast for April-September. Downward mixing of NLLJ momentum to the surface causes 15% of mineral dust emission in the annual and spatial mean and can be associated with up to 60% of the total dust amount in specific areas, e.g., the Bodélé Depression and south of the Hoggar-Tibesti Channel. The sharp diurnal cycle underlines the importance of using wind speed information with high temporal resolution as driving fields for dust emission models. Citation: Fiedler, S., K. Schepanski, B. Heinold, P. Knippertz, and I. Tegen (2013), Climatology of nocturnal low-level jets over North Africa and implications for modeling mineral dust emission, J. Geophys. Res. Atmos., 118, 6100-6121, doi:10.1002/jgrd.50394.

  17. Climatology of nocturnal low-level jets over North Africa and implications for modeling mineral dust emission

    PubMed Central

    Fiedler, S; Schepanski, K; Heinold, B; Knippertz, P; Tegen, I

    2013-01-01

    [1] This study presents the first climatology for the dust emission amount associated with Nocturnal Low-Level Jets (NLLJs) in North Africa. These wind speed maxima near the top of the nocturnal boundary layer can generate near-surface peak winds due to shear-driven turbulence in the course of the night and the NLLJ breakdown during the following morning. The associated increase in the near-surface wind speed is a driver for mineral dust emission. A new detection algorithm for NLLJs is presented and used for a statistical assessment of NLLJs in 32 years of ERA-Interim reanalysis from the European Centre for Medium-Range Weather Forecasts. NLLJs occur in 29% of the nights in the annual and spatial mean. The NLLJ climatology shows a distinct annual cycle with marked regional differences. Maxima of up to 80% NLLJ frequency are found where low-level baroclinicity and orographic channels cause favorable conditions, e.g., over the Bodélé Depression, Chad, for November–February and along the West Saharan and Mauritanian coast for April–September. Downward mixing of NLLJ momentum to the surface causes 15% of mineral dust emission in the annual and spatial mean and can be associated with up to 60% of the total dust amount in specific areas, e.g., the Bodélé Depression and south of the Hoggar-Tibesti Channel. The sharp diurnal cycle underlines the importance of using wind speed information with high temporal resolution as driving fields for dust emission models. Citation: Fiedler, S., K. Schepanski, B. Heinold, P. Knippertz, and I. Tegen (2013), Climatology of nocturnal low-level jets over North Africa and implications for modeling mineral dust emission, J. Geophys. Res. Atmos., 118, 6100-6121, doi:10.1002/jgrd.50394 PMID:25893154

  18. High resolution inventory of re-estimating ammonia emissions from agricultural fertilizer in China from 1978 to 2008

    NASA Astrophysics Data System (ADS)

    Xu, P.; Lin, Y. H.; Liao, Y. J.; Zhao, C. X.; Wang, G. S.; Luan, S. J.

    2015-09-01

    The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new Chinese agricultural fertilizer NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 km × 1 km gridded map on the county level was developed for 2008, (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters, (3) the spatial and temporal patterns of historical time trends for 1978-2008 were estimated and the uncertainties were quantified for the inventories, and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 Tg NH3 yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0 %. During the study period, the contribution of livestock manure spreading increased from 37.0 to 45.5 % because of changing fertilization practices and the rapid increase in egg, milk and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3 % (minimum: 33.4 %; maximum: 42.7 %). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3 and 8.5 %. The average contributions of cake fertilizer and straw returning were approximately 3.8 and 4.5 %, respectively, thus small and stable. Collectively, the CAF_NH3 emissions reflect the nation's agricultural policy to a certain extent. An effective

  19. Long-term nitrous oxide fluxes in annual and perennial agricultural and unmanaged ecosystems in the upper Midwest USA

    DOE PAGES

    Gelfand, Ilya; Shcherbak, Iurii; Millar, Neville; ...

    2016-08-11

    Differences in soil nitrous oxide (N 2O) fluxes among ecosystems are often difficult to evaluate and predict due to high spatial and temporal variabilities and few direct experimental comparisons. For 20 years, we measured N 2O fluxes in 11 ecosystems in southwest Michigan USA: four annual grain crops (corn–soybean–wheat rotations) managed with conventional, no-till, reduced input, or biologically based/organic inputs; three perennial crops (alfalfa, poplar, and conifers); and four unmanaged ecosystems of different successional age including mature forest. Average N 2O emissions were higher from annual grain and N-fixing cropping systems than from nonleguminous perennial cropping systems and were low across unmanaged ecosystems. Among annual cropping systems full-rotation fluxes were indistinguishable from one another but rotation phase mattered. For example, those systems with cover crops and reduced fertilizer N emitted more N 2O during the corn and soybean phases, but during the wheat phase fluxes were ~40% lower. Likewise, no-till did not differ from conventional tillage over the entire rotation but reduced emissions ~20% in the wheat phase and increased emissions 30–80% in the corn and soybean phases. Greenhouse gas intensity for the annual crops (flux per unit yield) was lowest for soybeans produced under conventional management, while for the 11 other crop 9 management combinations intensities were similar to one another. Among the fertilized systems, emissions ranged from 0.30 to 1.33 kg N 2O-N ha -1 yr -1 and were best predicted by IPCC Tier 1 and DEF emission factor approaches. Annual cumulative fluxes from perennial systems were best explained by soil NOmore » $$-\\atop{3}$$ pools (r 2 = 0.72) but not so for annual crops, where management differences overrode simple correlations. Daily soil N 2O emissions were poorly predicted by any measured variables. Overall, long-term measurements reveal lower fluxes in nonlegume perennial vegetation and, for

  20. Amtrak annual report, 2009

    DOT National Transportation Integrated Search

    2009-01-01

    In FY 2009, Amtrak earned just over $2.35 billion in total revenue and incurred $3.5 billion in expenses. The annual federal : appropriation on which Amtrak relies totaled $1.49 billion in FY 2009, comprising $475 million in operating funds, $75 : mi...

  1. Greenhouse gas emissions from diverse Arctic Alaskan lakes are dominated by young carbon

    USGS Publications Warehouse

    Elder, Clayton D.; Xu, Xiaomei; Walker, Jennifer; Schnell, Jordan L.; Hinkel, Kenneth M.; Townsend-Small, Amy; Arp, Christopher D.; Pohlman, John; Gaglioti, Benjamin V.; Czimzik, Claudia I.

    2018-01-01

    Climate-sensitive Arctic lakes have been identified as conduits for ancient permafrost-carbon (C) emissions and as such accelerate warming. However, the environmental factors that control emission pathways and their sources are unclear; this complicates upscaling, forecasting and climate-impact-assessment efforts. Here we show that current whole-lake CH4 and CO2 emissions from widespread lakes in Arctic Alaska primarily originate from organic matter fixed within the past 3–4 millennia (modern to 3,300 ± 70 years before the present), and not from Pleistocene permafrost C. Furthermore, almost 100% of the annual diffusive C flux is emitted as CO2. Although the lakes mostly processed younger C (89 ± 3% of total C emissions), minor contributions from ancient C sources were two times greater in fine-textured versus coarse-textured Pleistocene sediments, which emphasizes the importance of the underlying geological substrate in current and future emissions. This spatially extensive survey considered the environmental and temporal variability necessary to monitor and forecast the fate of ancient permafrost C as Arctic warming progresses.

  2. Greenhouse gas emissions from diverse Arctic Alaskan lakes are dominated by young carbon

    NASA Astrophysics Data System (ADS)

    Elder, Clayton D.; Xu, Xiaomei; Walker, Jennifer; Schnell, Jordan L.; Hinkel, Kenneth M.; Townsend-Small, Amy; Arp, Christopher D.; Pohlman, John W.; Gaglioti, Benjamin V.; Czimczik, Claudia I.

    2018-01-01

    Climate-sensitive Arctic lakes have been identified as conduits for ancient permafrost-carbon (C) emissions and as such accelerate warming. However, the environmental factors that control emission pathways and their sources are unclear; this complicates upscaling, forecasting and climate-impact-assessment efforts. Here we show that current whole-lake CH4 and CO2 emissions from widespread lakes in Arctic Alaska primarily originate from organic matter fixed within the past 3-4 millennia (modern to 3,300 ± 70 years before the present), and not from Pleistocene permafrost C. Furthermore, almost 100% of the annual diffusive C flux is emitted as CO2. Although the lakes mostly processed younger C (89 ± 3% of total C emissions), minor contributions from ancient C sources were two times greater in fine-textured versus coarse-textured Pleistocene sediments, which emphasizes the importance of the underlying geological substrate in current and future emissions. This spatially extensive survey considered the environmental and temporal variability necessary to monitor and forecast the fate of ancient permafrost C as Arctic warming progresses.

  3. Concentrations, loads, and yields of total phosphorus, total nitrogen, and suspended sediment and bacteria concentrations in the Wister Lake Basin, Oklahoma and Arkansas, 2011-13

    USGS Publications Warehouse

    Buck, Stephanie D.

    2014-01-01

    The Poteau Valley Improvement Authority uses Wister Lake in southeastern Oklahoma as a public water supply. Total phosphorus, total nitrogen, and suspended sediments from agricultural runoff and discharges from wastewater treatment plants and other sources have degraded water quality in the lake. As lake-water quality has degraded, water-treatment cost, chemical usage, and sludge production have increased for the Poteau Valley Improvement Authority. The U.S. Geological Survey (USGS), in cooperation with the Poteau Valley Improvement Authority, investigated and summarized concentrations of total phosphorus, total nitrogen, suspended sediment, and bacteria (Escherichia coli and Enterococcus sp.) in surface water flowing to Wister Lake. Estimates of total phosphorus, total nitrogen, and suspended sediment loads, yields, and flow-weighted mean concentrations of total phosphorus and total nitrogen concentrations were made for the Wister Lake Basin for a 3-year period from October 2010 through September 2013. Data from water samples collected at fixed time increments during base-flow conditions and during runoff conditions at the Poteau River at Loving, Okla. (USGS station 07247015), the Poteau River near Heavener, Okla. (USGS station 07247350), and the Fourche Maline near Leflore, Okla. (USGS station 07247650), water-quality stations were used to evaluate water quality over the range of streamflows in the basin. These data also were collected to estimate annual constituent loads and yields by using regression models. At the Poteau River stations, total phosphorus, total nitrogen, and suspended sediment concentrations in surface-water samples were significantly larger in samples collected during runoff conditions than in samples collected during base-flow conditions. At the Fourche Maline station, in contrast, concentrations of these constituents in water samples collected during runoff conditions were not significantly larger than concentrations during base

  4. 40 CFR 98.143 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.143 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each continuous glass melting furnace using the procedure in paragraphs (a) and (b) of this section. (a) For each continuous glass melting furnace that...

  5. 40 CFR 98.143 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.143 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from each continuous glass melting furnace using the procedure in paragraphs (a) and (b) of this section. (a) For each continuous glass melting furnace that...

  6. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile isotopic methane analysis based on Cavity Ringdown Spectroscopy

    NASA Astrophysics Data System (ADS)

    Rella, Chris; Winkler, Renato; Sweeney, Colm; Karion, Anna; Petron, Gabrielle; Crosson, Eric

    2014-05-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of carbon dioxide emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the isotopic carbon signature to distinguish between natural gas and landfills or ruminants. We present measurements of methane using a mobile spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Performance of the CRDS isotope analyzer is presented, including precision, calibration, stability, and the potential for measurement bias due to other atmospheric constituents. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to

  7. Implications of emission inventory choice for modeling fire-related pollution in the U.S.

    NASA Astrophysics Data System (ADS)

    Koplitz, S. N.; Nolte, C. G.; Pouliot, G.

    2017-12-01

    Wildland fires are a major source of fine particulate matter (PM2.5), one of the most harmful ambient pollutants for human health globally. Within the U.S., wildland fires can account for more than 30% of total annual PM2.5 emissions. In order to represent the influence of fire emissions on atmospheric composition, regional and global chemical transport models (CTMs) rely on fire emission inventories developed from estimates of burned area (i.e. fire size and location). Burned area can be estimated using a range of top-down and bottom-up approaches, including satellite-derived remote sensing and on-the-ground incident reports. While burned area estimates agree with each other reasonably well in the western U.S. (within 20-30% for most years during 2002-2014), estimates for the southern U.S. vary by more than a factor of 3. Differences in burned area estimation methods lead to significant variability in the spatial and temporal allocation of emissions across fire emission inventory platforms. In this work, we implement fire emission estimates for 2011 from three different products - the USEPA National Emission Inventory (NEI), the Fire INventory of NCAR (FINN), and the Global Fire Emission Database (GFED4s) - into the Community Multiscale Air Quality (CMAQ) model to quantify and characterize differences in simulated fire-related PM2.5 and ozone concentrations across the contiguous U.S. due solely to the emission inventory used. Preliminary results indicate that the estimated contribution to national annual average PM2.5 from wildland fire in 2011 is highest using GFED4s emissions (1.0 µg m-3) followed by NEI (0.7 µg m-3) and FINN (0.3 µg m-3), with comparisons varying significantly by region and season. Understanding the sensitivity of modeling fire-related PM2.5 and ozone in the U.S. to fire emission inventory choice will inform future efforts to assess the implications of present and future fire activity for air quality and human health at national and global

  8. Modeling of pesticide emissions from agricultural ecosystems

    NASA Astrophysics Data System (ADS)

    Li, Rong

    2012-04-01

    Pesticides are applied to crops and soils to improve agricultural yields, but the use of pesticides has become highly regulated because of concerns about their adverse effects on human health and environment. Estimating pesticide emission rates from soils and crops is a key component for risk assessment for pesticide registration, identification of pesticide sources to the contamination of sensitive ecosystems, and appreciation of transport and fate of pesticides in the environment. Pesticide emission rates involve processes occurring in the soil, in the atmosphere, and on vegetation surfaces and are highly dependent on soil texture, agricultural practices, and meteorology, which vary significantly with location and/or time. To take all these factors into account for simulating pesticide emissions from large agricultural ecosystems, this study coupled a comprehensive meteorological model with a dynamic pesticide emission model. The combined model calculates hourly emission rates from both emission sources: current applications and soil residues resulting from historical use. The coupled modeling system is used to compute a gridded (36 × 36 km) hourly toxaphene emission inventory for North America for the year 2000 using a published U.S. toxaphene residue inventory and a Mexican toxaphene residue inventory developed using its historical application rates and a cropland inventory. To my knowledge, this is the first such hourly toxaphene emission inventory for North America. Results show that modeled emission rates have strong diurnal and seasonal variations at a given location and over the entire domain. The simulated total toxaphene emission from contaminated agricultural soils in North America in 2000 was about 255 t, which compares reasonably well to a published annual estimate. Most emissions occur in spring and summer, with domain-wide emission rates in April, May and, June of 36, 51, and 35 t/month, respectively. The spatial distribution of emissions depends

  9. An Emission Inventory of Polycyclic Aromatic Hydrocarbons in China

    NASA Astrophysics Data System (ADS)

    Mu, Xilong; Zhu, Xianlei; Wang, Xuesong

    2015-04-01

    Polycyclic Aromatic Hydrocarbons (PAHs) are among the most dangerous compounds due to their high carcinogenic and mutagenic character. Emission inventory provides the primary data to account for the sources of ambient PAHs and server as a necessary database for effective PAHs pollution control. China is experiencing fast economic growth and large energy consumption, which might result in a large amount of PAHs anthropogenic emissions. Therefore, based on the previous studies and combined recently field emission measurements as well as socio-economic activity data, the development of a nationwide PAHs emission inventory is needed. In this work, the emission inventory of 16 PAHs listed as U.S. Environmental Protection Agency priority pollutants in China in the year 2012 is compiled. The emission amounts of PAHs were estimated as annual rates of emission-related activities multiplied by respective emission factors. The activities such as fuel consumption, including fossil fuel and biofuel, and socio-economic statistics were obtained from yearbook released by Chinese central government and/or provincial governments, as well as related industry reports. Emission factors were derived from the related literature. Recently reported emission factors from local measurements were used. The total emissions of PAHs were 120611 ton in 2012. In China, PAHs were emitted predominantly from domestic combustion of coal and biofuel, coking industry and motor vehicles, accounting for 72% of the total amount. PAHs emission profiles were significantly different between China and the other countries. The emission profile in China featured a relatively higher portion of high molecular weight species with carcinogenic potential due to large contributions of domestic combustion and coking industry. Domestic combustion of straw, coal and firewood emitted 19464 ton, 8831 ton, and 5062 ton of PAHs, respectively, which were much higher than those in other countries. Emission per capita showed

  10. On-road vehicle emission control in Beijing: past, present, and future.

    PubMed

    Wu, Ye; Wang, Renjie; Zhou, Yu; Lin, Bohong; Fu, Lixin; He, Kebin; Hao, Jiming

    2011-01-01

    Beijing, the capital of China, has experienced rapid motorization since 1990; a trend that is likely to continue. The growth in vehicles and the corresponding emissions create challenges to improving the urban air quality. In an effort to reduce the impact of vehicle emissions on urban air quality, Beijing has adopted a number of vehicle emission control strategies and policies since the mid 1990 s. These are classified into seven categories: (1) emission control on new vehicles; (2) emission control on in-use vehicles; (3) fuel quality improvements; (4) alternative-fuel and advanced vehicles; (5) economic policies; (6) public transport; and (7) temporal traffic control measures. Many have proven to be successful, such as the Euro emission standards, unleaded gasoline and low sulfur fuel, temporal traffic control measures during the Beijing Olympic Games, etc. Some, however, have been failures, such as the gasoline-to-LPG taxi retrofit program. Thanks to the emission standards for new vehicles as well as other controls, the fleet-average emission rates of CO, HC, NO(X), and PM(10) by each major vehicle category are decreasing over time. For example, gasoline cars decreased fleet-average emission factors by 12.5% for CO, 10.0% for HC, 5.8% for NO(X), and 13.0% for PM(10) annually since 1995, and such a trend is likely to continue. Total emissions for Beijing's vehicle fleet increased from 1995 to 1998. However, they show a clear and steady decrease between 1999 and 2009. In 2009, total emissions of CO, HC, NO(X), and PM(10) were 845,000 t, 121,000 t, 84,000 t, and 3700 t, respectively; with reductions of 47%, 49%, 47%, and 42%, relative to 1998. Beijing has been considered a pioneer in controlling vehicle emissions within China, similar to the role of California to the U.S. The continued rapid growth of vehicles, however, is challenging Beijing's policy-makers.

  11. Spatial and temporal disaggregation of transport-related carbon dioxide emissions in Bogota - Colombia

    NASA Astrophysics Data System (ADS)

    Hernandez-Gonzalez, L. A.; Jimenez Pizarro, R.; Néstor Y. Rojas, N. Y.

    2011-12-01

    As a result of rapid urbanization during the last 60 years, 75% of the Colombian population now lives in cities. Urban areas are net sources of greenhouse gases (GHG) and contribute significantly to national GHG emission inventories. The development of scientifically-sound GHG mitigation strategies require accurate GHG source and sink estimations. Disaggregated inventories are effective mitigation decision-making tools. The disaggregation process renders detailed information on the distribution of emissions by transport mode, and the resulting a priori emissions map allows for optimal definition of sites for GHG flux monitoring, either by eddy covariance or inverse modeling techniques. Fossil fuel use in transportation is a major source of carbon dioxide (CO2) in Bogota. We present estimates of CO2 emissions from road traffic in Bogota using the Intergovernmental Panel on Climate Change (IPCC) reference method, and a spatial and temporal disaggregation method. Aggregated CO2 emissions from mobile sources were estimated from monthly and annual fossil fuel (gasoline, diesel and compressed natural gas - CNG) consumption statistics, and estimations of bio-ethanol and bio-diesel use. Although bio-fuel CO2 emissions are considered balanced over annual (or multi-annual) agricultural cycles, we included them since CO2 generated by their combustion would be measurable by a net flux monitoring system. For the disaggregation methodology, we used information on Bogota's road network classification, mean travel speed and trip length for each vehicle category and road type. The CO2 emission factors were taken from recent in-road measurements for gasoline- and CNG-powered vehicles and also estimated from COPERT IV. We estimated emission factors for diesel from surveys on average trip length and fuel consumption. Using IPCC's reference method, we estimate Bogota's total transport-related CO2 emissions for 2008 (reference year) at 4.8 Tg CO2. The disaggregation method estimation is

  12. Multi-source SO2 emission retrievals and consistency of satellite and surface measurements with reported emissions

    NASA Astrophysics Data System (ADS)

    Fioletov, Vitali; McLinden, Chris A.; Kharol, Shailesh K.; Krotkov, Nickolay A.; Li, Can; Joiner, Joanna; Moran, Michael D.; Vet, Robert; Visschedijk, Antoon J. H.; Denier van der Gon, Hugo A. C.

    2017-10-01

    Reported sulfur dioxide (SO2) emissions from US and Canadian sources have declined dramatically since the 1990s as a result of emission control measures. Observations from the Ozone Monitoring Instrument (OMI) on NASA's Aura satellite and ground-based in situ measurements are examined to verify whether the observed changes from SO2 abundance measurements are quantitatively consistent with the reported changes in emissions. To make this connection, a new method to link SO2 emissions and satellite SO2 measurements was developed. The method is based on fitting satellite SO2 vertical column densities (VCDs) to a set of functions of OMI pixel coordinates and wind speeds, where each function represents a statistical model of a plume from a single point source. The concept is first demonstrated using sources in North America and then applied to Europe. The correlation coefficient between OMI-measured VCDs (with a local bias removed) and SO2 VCDs derived here using reported emissions for 1° by 1° gridded data is 0.91 and the best-fit line has a slope near unity, confirming a very good agreement between observed SO2 VCDs and reported emissions. Having demonstrated their consistency, seasonal and annual mean SO2 VCD distributions are calculated, based on reported point-source emissions for the period 1980-2015, as would have been seen by OMI. This consistency is further substantiated as the emission-derived VCDs also show a high correlation with annual mean SO2 surface concentrations at 50 regional monitoring stations.

  13. The impact of residential combustion emissions on atmospheric aerosol, human health, and climate

    NASA Astrophysics Data System (ADS)

    Butt, E. W.; Rap, A.; Schmidt, A.; Scott, C. E.; Pringle, K. J.; Reddington, C. L.; Richards, N. A. D.; Woodhouse, M. T.; Ramirez-Villegas, J.; Yang, H.; Vakkari, V.; Stone, E. A.; Rupakheti, M.; Praveen, P. S.; van Zyl, P. G.; Beukes, J. P.; Josipovic, M.; Mitchell, E. J. S.; Sallu, S. M.; Forster, P. M.; Spracklen, D. V.

    2016-01-01

    Combustion of fuels in the residential sector for cooking and heating results in the emission of aerosol and aerosol precursors impacting air quality, human health, and climate. Residential emissions are dominated by the combustion of solid fuels. We use a global aerosol microphysics model to simulate the impact of residential fuel combustion on atmospheric aerosol for the year 2000. The model underestimates black carbon (BC) and organic carbon (OC) mass concentrations observed over Asia, Eastern Europe, and Africa, with better prediction when carbonaceous emissions from the residential sector are doubled. Observed seasonal variability of BC and OC concentrations are better simulated when residential emissions include a seasonal cycle. The largest contributions of residential emissions to annual surface mean particulate matter (PM2.5) concentrations are simulated for East Asia, South Asia, and Eastern Europe. We use a concentration response function to estimate the human health impact due to long-term exposure to ambient PM2.5 from residential emissions. We estimate global annual excess adult (> 30 years of age) premature mortality (due to both cardiopulmonary disease and lung cancer) to be 308 000 (113 300-497 000, 5th to 95th percentile uncertainty range) for monthly varying residential emissions and 517 000 (192 000-827 000) when residential carbonaceous emissions are doubled. Mortality due to residential emissions is greatest in Asia, with China and India accounting for 50 % of simulated global excess mortality. Using an offline radiative transfer model we estimate that residential emissions exert a global annual mean direct radiative effect between -66 and +21 mW m-2, with sensitivity to the residential emission flux and the assumed ratio of BC, OC, and SO2 emissions. Residential emissions exert a global annual mean first aerosol indirect effect of between -52 and -16 mW m-2, which is sensitive to the assumed size distribution of carbonaceous emissions

  14. Comparison of calculation methods for estimating annual carbon stock change in German forests under forest management in the German greenhouse gas inventory.

    PubMed

    Röhling, Steffi; Dunger, Karsten; Kändler, Gerald; Klatt, Susann; Riedel, Thomas; Stümer, Wolfgang; Brötz, Johannes

    2016-12-01

    The German greenhouse gas inventory in the land use change sector strongly depends on national forest inventory data. As these data were collected periodically 1987, 2002, 2008 and 2012, the time series on emissions show several "jumps" due to biomass stock change, especially between 2001 and 2002 and between 2007 and 2008 while within the periods the emissions seem to be constant due to the application of periodical average emission factors. This does not reflect inter-annual variability in the time series, which would be assumed as the drivers for the carbon stock changes fluctuate between the years. Therefore additional data, which is available on annual basis, should be introduced into the calculations of the emissions inventories in order to get more plausible time series. This article explores the possibility of introducing an annual rather than periodical approach to calculating emission factors with the given data and thus smoothing the trajectory of time series for emissions from forest biomass. Two approaches are introduced to estimate annual changes derived from periodic data: the so-called logging factor method and the growth factor method. The logging factor method incorporates annual logging data to project annual values from periodic values. This is less complex to implement than the growth factor method, which additionally adds growth data into the calculations. Calculation of the input variables is based on sound statistical methodologies and periodically collected data that cannot be altered. Thus a discontinuous trajectory of the emissions over time remains, even after the adjustments. It is intended to adopt this approach in the German greenhouse gas reporting in order to meet the request for annually adjusted values.

  15. Seasonal and annual variations and regional characteristics of wet and dry deposition amounts in East Asian region

    NASA Astrophysics Data System (ADS)

    Sato, K.; Tsuyoshi, O.; Endo, T.; Yagoh, H.; Matsuda, K.

    2011-12-01

    Emission of sulfur and nitrogen compounds in Asian region has been remarkably increased with recent rapid economical growth (Ohara et al., 2007). To appropriately assess the influence of air pollutants on the ecosystem, it is important to quantitatively determine the atmospheric deposition of air pollutants. Here, Seasonal and annual variations and regional characteristics of estimated wet and dry deposition amounts at 27 monitoring sites of Acid Deposition Monitoring Network in East Asia (EANET) from 2003 to 2009 are discussed. Wet deposition sample was collected every 24 hours or 1 week by a wet only sampler. Wet deposition amounts were calculated by the product of the volume-weighted concentrations of ionic species (SO42-, NO3-, and NH4+) in the precipitation and precipitation amount measured by a standard rain gauge at each site. Dry deposition amount was estimated by the inferential method which was originated the model developed by Wesely and Hicks (1977) and modified by Matsuda (2008). The components examined for dry deposition were sulfur compounds (gaseous SO2 and particulate SO42-) and nitrogen compounds (gaseous HNO3 and NH3, particulate NO3- and NH4+). Dry deposition was calculated by the product of the deposition velocity estimated by the inferential method for forest and grass surfaces and the monitored air concentration of each compound. The mean annual dry deposition amounts for sulfur and nitrogen compounds in Japanese sites were in the range of 5-37 and 7-50 mmol m-2 year-1, respectively. The regional characteristics of dry deposition amounts in Japan were similar between sulfur and nitrogen compounds, which showed higher deposition in the Sea of Japan side and the western Japan. The mean annual total (wet + dry) deposition amounts for sulfur and nitrogen compounds in Japanese sites were in the range of 28-77 and 22-130 mmol m-2 year-1, respectively. The contributions of dry deposition to the total deposition amounts were 10-55% and 13-56% for

  16. 40 CFR 98.193 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Lime Manufacturing § 98.193 Calculating GHG emissions. You must calculate and report the annual process CO2 emissions from all lime kilns combined using the procedure in paragraphs (a) and (b) of this section. (a) If all lime kilns meet the conditions specified in...

  17. Emission Database for Global Atmospheric Research (EDGAR).

    ERIC Educational Resources Information Center

    Olivier, J. G. J.; And Others

    1994-01-01

    Presents the objective and methodology chosen for the construction of a global emissions source database called EDGAR and the structural design of the database system. The database estimates on a regional and grid basis, 1990 annual emissions of greenhouse gases, and of ozone depleting compounds from all known sources. (LZ)

  18. 40 CFR 98.53 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Adipic Acid Production § 98.53 Calculating GHG emissions. (a) You must determine annual N2O emissions from adipic acid production according to paragraphs (a)(1) or... must conduct the test on the vent stream from the nitric acid oxidation step of the process, referred...

  19. 40 CFR 98.53 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Adipic Acid Production § 98.53 Calculating GHG emissions. (a) You must determine annual N2O emissions from adipic acid production according to paragraphs (a)(1) or... must conduct the test on the vent stream from the nitric acid oxidation step of the process, referred...

  20. 40 CFR 98.53 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Adipic Acid Production § 98.53 Calculating GHG emissions. (a) You must determine annual N2O emissions from adipic acid production according to paragraphs (a)(1) or... must conduct the test on the vent stream from the nitric acid oxidation step of the process, referred...

  1. 40 CFR 98.263 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    .... You must calculate and report the annual process CO2 emissions from each wet-process phosphoric acid... under this subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4... this part (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the...

  2. 40 CFR 98.263 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... You must calculate and report the annual process CO2 emissions from each wet-process phosphoric acid... under this subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4... this part (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the...

  3. 40 CFR 98.263 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    .... You must calculate and report the annual process CO2 emissions from each wet-process phosphoric acid... under this subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4... this part (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the...

  4. 40 CFR 98.263 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    .... You must calculate and report the annual process CO2 emissions from each wet-process phosphoric acid... under this subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4... this part (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the...

  5. 40 CFR 98.263 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    .... You must calculate and report the annual process CO2 emissions from each wet-process phosphoric acid... under this subpart the process CO2 emissions by operating and maintaining a CEMS according to the Tier 4... this part (General Stationary Fuel Combustion Sources). (b) Calculate and report under this subpart the...

  6. Emissions of air pollutants and greenhouse gases over Asian regions during 2000-2008: Regional Emission inventory in ASia (REAS) version 2

    NASA Astrophysics Data System (ADS)

    Kurokawa, J.; Ohara, T.; Morikawa, T.; Hanayama, S.; Janssens-Maenhout, G.; Fukui, T.; Kawashima, K.; Akimoto, H.

    2013-11-01

    We have updated the Regional Emission inventory in ASia (REAS) as version 2.1. REAS 2.1 includes most major air pollutants and greenhouse gases from each year during 2000 and 2008 and following areas of Asia: East, Southeast, South, and Central Asia and the Asian part of Russia. Emissions are estimated for each country and region using updated activity data and parameters. Monthly gridded data with a 0.25° × 0.25° resolution are also provided. Asian emissions for each species in 2008 are as follows (with their growth rate from 2000 to 2008): 56.9 Tg (+34%) for SO2, 53.9 Tg (+54%) for NOx, 359.5 Tg (+34%) for CO, 68.5 Tg (+46%) for non-methane volatile organic compounds, 32.8 Tg (+17%) for NH3, 36.4 Tg (+45%) for PM10, 24.7 Tg (+42%) for PM2.5, 3.03 Tg (+35%) for black carbon, 7.72 Tg (+21%) for organic carbon, 182.2 Tg (+32%) for CH4, 5.80 Tg (+18%) for N2O, and 16.0 Pg (+57%) for CO2. By country, China and India were respectively the largest and second largest contributors to Asian emissions. Both countries also had higher growth rates in emissions than others because of their continuous increases in energy consumption, industrial activities, and infrastructure development. In China, emission mitigation measures have been implemented gradually. Emissions of SO2 in China increased from 2000 to 2006 and then began to decrease as flue-gas desulphurization was installed to large power plants. On the other hand, emissions of air pollutants in total East Asia except for China decreased from 2000 to 2008 owing to lower economic growth rates and more effective emission regulations in Japan, South Korea, and Taiwan. Emissions from other regions generally increased from 2000 to 2008, although their relative shares of total Asian emissions are smaller than those of China and India. Tables of annual emissions by country and region broken down by sub-sector and fuel type, and monthly gridded emission data with a resolution of 0.25° × 0.25° for the major sectors are

  7. Emissions of air pollutants and greenhouse gases over Asian regions during 2000-2008: Regional Emission inventory in ASia (REAS) version 2

    NASA Astrophysics Data System (ADS)

    Kurokawa, J.; Ohara, T.; Morikawa, T.; Hanayama, S.; Greet, J.-M.; Fukui, T.; Kawashima, K.; Akimoto, H.

    2013-04-01

    We have updated the Regional Emission inventory in ASia (REAS) as version 2.1. REAS 2.1 includes most major air pollutants and greenhouse gases from each year during 2000 and 2008 and following areas of Asia: East, Southeast, South, and Central Asia and the Asian part of Russia. Emissions are estimated for each country and region using updated activity data and parameters. Monthly gridded data with a 0.25 × 0.25° resolution are also provided. Asian emissions for each species in 2008 are as follows (with their growth rate from 2000 to 2008): 56.9 Tg (+34%) for SO2, 53.9 Tg (+54%) for NOx, 359.5 Tg (+34%) for CO, 68.5 Tg (+46%) for non-methane volatile organic compounds, 32.8 Tg (+17%) for NH3, 36.4 Tg (+45%) for PM10, 24.7 Tg (+42%) for PM2.5, 3.03 Tg (+35%) for black carbon, 7.72 Tg (+21%) for organic carbon, 182.2 Tg (+32%) for CH4, 5.80 Tg (+18%) for N2O, and 16.7 Pg (+59%) for CO2. By country, China and India were respectively the largest and second largest contributors to Asian emissions. Both countries also had higher growth rates in emissions than others because of their continuous increases in energy consumption, industrial activities, and infrastructure development. In China, emission mitigation measures have been implemented gradually. Emissions of SO2 in China increased from 2000 to 2006 and then began to decrease as flue-gas desulfurization was installed to large power plants. On the other hand, emissions of air pollutants in total East Asia except for China decreased from 2000 to 2008 owing to lower economic growth rates and more effective emission regulations in Japan, South Korea, and Taiwan. Emissions from other regions generally increased from 2000 to 2008, although their relative shares of total Asian emissions are smaller than those of China and India. Tables of annual emissions by country and region broken down by sub-sector and fuel type, and monthly gridded emission data with a resolution of 0.25 × 0.25° for the major sectors are available

  8. 40 CFR 98.333 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... in your calculation using Equation R-1 of § 98.183. ER30OC09.126 Where: ECO2k = Annual CO2 process emissions from individual Waelz kiln or electrothermic furnace “k” (metric tons). 44/12 = Ratio of molecular weights, CO2 to carbon. 2000/2205 = Conversion factor to convert tons to metric tons. (Zinc)k = Annual...

  9. Impact of Biogenic Emission Uncertainties on the Simulated Response of Ozone and Fine Particulate Matter to Anthropogenic Emission Reductions

    PubMed Central

    Hogrefe, Christian; Isukapalli, Sastry S.; Tang, Xiaogang; Georgopoulos, Panos G.; He, Shan; Zalewsky, Eric E.; Hao, Winston; Ku, Jia-Yeong; Key, Tonalee; Sistla, Gopal

    2011-01-01

    The role of emissions of volatile organic compounds and nitric oxide from biogenic sources is becoming increasingly important in regulatory air quality modeling as levels of anthropogenic emissions continue to decrease and stricter health-based air quality standards are being adopted. However, considerable uncertainties still exist in the current estimation methodologies for biogenic emissions. The impact of these uncertainties on ozone and fine particulate matter (PM2.5) levels for the eastern United States was studied, focusing on biogenic emissions estimates from two commonly used biogenic emission models, the Model of Emissions of Gases and Aerosols from Nature (MEGAN) and the Biogenic Emissions Inventory System (BEIS). Photochemical grid modeling simulations were performed for two scenarios: one reflecting present day conditions and the other reflecting a hypothetical future year with reductions in emissions of anthropogenic oxides of nitrogen (NOx). For ozone, the use of MEGAN emissions resulted in a higher ozone response to hypothetical anthropogenic NOx emission reductions compared with BEIS. Applying the current U.S. Environmental Protection Agency guidance on regulatory air quality modeling in conjunction with typical maximum ozone concentrations, the differences in estimated future year ozone design values (DVF) stemming from differences in biogenic emissions estimates were on the order of 4 parts per billion (ppb), corresponding to approximately 5% of the daily maximum 8-hr ozone National Ambient Air Quality Standard (NAAQS) of 75 ppb. For PM2.5, the differences were 0.1–0.25 μg/m3 in the summer total organic mass component of DVFs, corresponding to approximately 1–2% of the value of the annual PM2.5 NAAQS of 15 μg/m3. Spatial variations in the ozone and PM2.5 differences also reveal that the impacts of different biogenic emission estimates on ozone and PM2.5 levels are dependent on ambient levels of anthropogenic emissions. PMID:21305893

  10. Annual Quality Assurance Conference Abstracts by Barbara Marshik

    EPA Pesticide Factsheets

    25th Annual Quality Assurance Conference. Abstracts: Material and Process Conditions for Successful Use of Extractive Sampling Techniques and Certification Methods Errors in the Analysis of NMHC and VOCs in CNG-Based Engine Emissions by Barbara Marshik

  11. Urban Greenhouse Gas Emissions Monitoring in Davos, Switzerland, Before, During and After the World Economic Forum Annual Meeting 2012

    NASA Astrophysics Data System (ADS)

    Jacobson, Gloria; Davis, Ken; Richardson, Scott; Miles, Natasha; Lauvaux, Thomas; Deng, Aijun; Calonder, Gian-Paul; Ruesch, Marc; Lehning, Michael; Bals, Andre; DeCola, Phil; Rella, Chris

    2013-04-01

    Efforts to reduce anthropogenic greenhouse gas emissions require validation. Atmospheric measurements capture all emissions, and provide a unique and powerful means of continuous validation and feedback. To demonstrate the utility of real time greenhouse gas measurements, in-situ GHG mixing ratio instruments were deployed in Davos, Switzerland to measure emissions from the city before, during and after the World Economic Forum (WEF). Three Instruments were deployed at two separate locations over 3 months (late December 2011 to February 2012). One site was located in the middle of the Davos urban area and a second site was located out of the valley in the surrounding mountains. Carbon Dioxide (CO2), Methane (CH4), Carbon Monoxide (CO) and water vapor (H2O) were measured continuously by Picarro G2401 instruments at both sites. Additionally, a Picarro flux analyzer was deployed in the city to evaluate the inverse fluxes. The mesoscale atmospheric model, WRF nudged to meteorological observations (WRF-FDDA), was used to simulate the transport of GHG over the valley of Davos at 1.3km resolution. A Mini Micro Pulse LiDAR (MiniMPL) from Sigma Space was deployed to evaluate the simulated planetary boundary layer depth from the WRF-FDDA model. The initial flux estimates for CO2 were constructed based on inventories reported for 2005. CO2 mixing ratio measurements prior to WEF suggest the difference between modeled (real-time) and inventory (annual) emissions to be on the order of +40%. The enhancement is likely due to the increased use of heating fuel in the winter. We present here the temporal variability in the inverse fluxes, which are correlated with a cold wave severely affecting Western Europe during the past winter, as well as changes in anthropogenic activities during the week of the WEF meeting. Also presented are new analyses of composite diurnal cycles of hourly CO/CO2 ratios, which provide additional information on the contributions of traffic relative to heating

  12. An ecoregion-specific ammonia emissions inventory of Ontario dairy farming: Mitigation potential of diet and manure management practices

    NASA Astrophysics Data System (ADS)

    Chai, Lilong; Kröbel, Roland; MacDonald, Douglas; Bittman, Shabtai; Beauchemin, Karen A.; Janzen, H. Henry; McGinn, Sean M.; Vanderzaag, Andrew

    2016-02-01

    The Canadian ammonia (NH3) emissions model and a survey of dairy farm practices were used to quantify effects of management on emissions from dairy farms in Ontario Canada. Total NH3 emissions from dairy farming were 21 Gg NH3-N yr-1 for the four ecoregions of the province. Annual emission rates ranged from 12.8 (for calves in ecoregions of Manitoulin-Lake Simcoe-Frontenac) to 50 kg NH3-N animal-1 yr-1 (for lactating cows in ecoregions of St. Lawrence Lowlands) (mean of 27 kg NH3-N animal-1 yr-1). The St. Lawrence Lowlands ecoregion had the highest emission rate because more dairy manure was managed as solid manure in that ecoregion. Total dairy cattle N intake (diet-N) was 81 Gg N yr-1, 23% of which was retained in animal products (e.g., milk, meat, and fetus), 47% was returned to the land, and 30% was emitted as gas (i.e., NH3-N, N2O-N, NO-N, and N2-N) and nitrate-N leaching/runoff. Ammonia volatilization constituted the largest loss of diet-N (26%), as well as manure-N (34%). Reducing the fraction of solid manure by 50% has the potential to mitigate NH3 emissions by 18% in Ontario ecoregions.

  13. 40 CFR 98.293 - Calculating GHG emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... subpart C of this part (General Stationary Fuel Combustion Sources) the combustion CO2, CH4, and N2O... must calculate and report the annual process CO2 emissions from each soda ash manufacturing line using... report under this subpart the combined process and combustion CO2 emissions by operating and maintaining...

  14. 40 CFR 98.183 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... calculate and report the annual process CO2 emissions from each smelting furnace using the procedure in... § 98.33(b)(4)(ii) or (b)(4)(iii), you must calculate and report combined process and combustion CO2...

  15. 40 CFR 98.293 - Calculating GHG emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... subpart C of this part (General Stationary Fuel Combustion Sources) the combustion CO2, CH4, and N2O... must calculate and report the annual process CO2 emissions from each soda ash manufacturing line using... report under this subpart the combined process and combustion CO2 emissions by operating and maintaining...

  16. 40 CFR 98.293 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... subpart C of this part (General Stationary Fuel Combustion Sources) the combustion CO2, CH4, and N2O... must calculate and report the annual process CO2 emissions from each soda ash manufacturing line using... report under this subpart the combined process and combustion CO2 emissions by operating and maintaining...

  17. 40 CFR 98.183 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... calculate and report the annual process CO2 emissions from each smelting furnace using the procedure in... § 98.33(b)(4)(ii) or (b)(4)(iii), you must calculate and report combined process and combustion CO2...

  18. 40 CFR 98.183 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... calculate and report the annual process CO2 emissions from each smelting furnace using the procedure in... § 98.33(b)(4)(ii) or (b)(4)(iii), you must calculate and report combined process and combustion CO2...

  19. 40 CFR 98.183 - Calculating GHG emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Stationary Fuel Combustion Sources). (2) Calculate and report process and combustion CO2 emissions separately... calculate and report the annual process CO2 emissions from each smelting furnace using the procedure in... § 98.33(b)(4)(ii) or (b)(4)(iii), you must calculate and report combined process and combustion CO2...

  20. 40 CFR 98.293 - Calculating GHG emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... subpart C of this part (General Stationary Fuel Combustion Sources) the combustion CO2, CH4, and N2O... must calculate and report the annual process CO2 emissions from each soda ash manufacturing line using... report under this subpart the combined process and combustion CO2 emissions by operating and maintaining...

  1. 40 CFR 98.293 - Calculating GHG emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... subpart C of this part (General Stationary Fuel Combustion Sources) the combustion CO2, CH4, and N2O... must calculate and report the annual process CO2 emissions from each soda ash manufacturing line using... report under this subpart the combined process and combustion CO2 emissions by operating and maintaining...

  2. Nitrogen soil emissions and belowground plant processes in Mediterranean annual pastures are altered by ozone exposure and N-inputs

    NASA Astrophysics Data System (ADS)

    Sánchez-Martín, L.; Bermejo-Bermejo, V.; García-Torres, L.; Alonso, R.; de la Cruz, A.; Calvete-Sogo, H.; Vallejo, A.

    2017-09-01

    Increasing tropospheric ozone (O3) and atmospheric nitrogen (N) deposition alter the structure and composition of pastures. These changes could affect N and C compounds in the soil that in turn can influence soil microbial activity and processes involved in the emission of N oxides, methane (CH4) and carbon dioxide (CO2), but these effects have been scarcely studied. Through an open top chamber (OTC) field experiment, the combined effects of both pollutants on soil gas emissions from an annual experimental Mediterranean community were assessed. Four O3 treatments and three different N input levels were considered. Fluxes of nitric (NO) and nitrous (N2O) oxide, CH4 and CO2 were analysed as well as soil mineral N and dissolved organic carbon. Belowground plant parameters like root biomass and root C and N content were also sampled. Ozone strongly increased soil N2O emissions, doubling the cumulative emission through the growing cycle in the highest O3 treatment, while N-inputs enhanced more slightly NO; CH4 and CO2 where not affected. Both N-gases had a clear seasonality, peaking at the start and at the end of the season when pasture physiological activity is minimal; thus, higher microorganism activity occurred when pasture had a low nutrient demand. The O3-induced peak of N2O under low N availability at the end of the growing season was counterbalanced by the high N inputs. These effects were related to the O3 x N significant interaction found for the root-N content in the grass and the enhanced senescence of the community. Results indicate the importance of the belowground processes, where competition between plants and microorganisms for the available soil N is a key factor, for understanding the ecosystem responses to O3 and N.

  3. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to lakes' physicochemical properties and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included direct ebullition, diffusion, storage flux, and a newly identified ice-bubble storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, butmore » the climate warming impact of lake CH 4 emissions was 2 times higher than that of CO 2. Ebullition and diffusion were the dominant modes of CH 4 and CO 2 emissions, respectively. IBS, ~10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, mixotrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. The relationship between CO 2 emissions and geographic parameters was weak, suggesting high variability among sources and sinks that regulate CO 2 emissions (e.g., catchment waters, pH equilibrium). Total CH 4 emission was correlated with concentrations of soluble reactive phosphorus and total nitrogen in lake water, Secchi depth, and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. In conclusion, our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to

  4. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE PAGES

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; ...

    2015-06-02

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH 4) and carbon dioxide (CO 2) emissions from northern lakes. Here we assessed the relationship between CH 4 and CO 2 emission modes in 40 lakes along a latitudinal transect in Alaska to lakes' physicochemical properties and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included direct ebullition, diffusion, storage flux, and a newly identified ice-bubble storage (IBS) flux. We found that all lakes were net sources of atmospheric CH 4 and CO 2, butmore » the climate warming impact of lake CH 4 emissions was 2 times higher than that of CO 2. Ebullition and diffusion were the dominant modes of CH 4 and CO 2 emissions, respectively. IBS, ~10% of total annual CH 4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH 4 emissions from stratified, mixotrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. The relationship between CO 2 emissions and geographic parameters was weak, suggesting high variability among sources and sinks that regulate CO 2 emissions (e.g., catchment waters, pH equilibrium). Total CH 4 emission was correlated with concentrations of soluble reactive phosphorus and total nitrogen in lake water, Secchi depth, and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. In conclusion, our findings suggest that permafrost type plays important roles in determining CH 4 emissions from lakes by both supplying organic matter to

  5. Evaluation of greenhouse gas emissions from waste management approaches in the islands.

    PubMed

    Chen, Ying-Chu

    2017-07-01

    Concerns about waste generation and climate change have attracted worldwide attention. Small islands, which account for more than one-sixth of the global land area, are facing problems caused by global climate change. This study evaluated the greenhouse gas emissions from five small islands surrounding Taiwan. These islands - Penghu County, Liuqui Island, Kinmen County, Matsu Island and Green Island - have their own waste management approaches that can serve as a guideline for waste management with greenhouse gas mitigation. The findings indicate that the total annual greenhouse gas emissions of the islands ranged from 292.1 to 29,096.2 [metric] tonne CO 2 -equivalent. The loading waste volumes and shipping distances were positively related to greenhouse gas emissions from transportation. The greenhouse gas emissions from waste-to-energy plants, mainly carbon dioxide and nitrous oxide, can be offset by energy recovery (approximately 38.6% of greenhouse gas emissions from incineration). In addition, about 34% and 11% of waste generated on the islands was successfully recycled and composted, respectively. This study provides valuable insights into the applicability of a policy framework for waste management approaches for greenhouse gas mitigation.

  6. Arrhenius equation for modeling feedyard ammonia emissions using temperature and diet crude protein.

    PubMed

    Todd, Richard W; Cole, N Andy; Waldrip, Heidi M; Aiken, Robert M

    2013-01-01

    Temperature controls many processes of NH volatilization. For example, urea hydrolysis is an enzymatically catalyzed reaction described by the Arrhenius equation. Diet crude protein (CP) controls NH emission by affecting N excretion. Our objectives were to use the Arrhenius equation to model NH emissions from beef cattle () feedyards and test predictions against observed emissions. Per capita NH emission rate (PCER), air temperature (), and CP were measured for 2 yr at two Texas Panhandle feedyards. Data were fitted to analogs of the Arrhenius equation: PCER = () and PCER = (,CP). The models were applied at a third feedyard to predict NH emissions and compare predicted to measured emissions. Predicted mean NH emissions were within -9 and 2% of observed emissions for the () and (T,CP) models, respectively. Annual emission factors calculated from models underestimated annual NH emission by 11% [() model] or overestimated emission by 8% [(,CP) model]. When from a regional weather station and three classes of CP drove the models, the () model overpredicted annual NH emission of the low CP class by 14% and underpredicted emissions of the optimum and high CP classes by 1 and 39%, respectively. The (,CP) model underpredicted NH emissions by 15, 4, and 23% for low, optimum, and high CP classes, respectively. Ammonia emission was successfully modeled using only, but including CP improved predictions. The empirical () and (,CP) models can successfully model NH emissions in the Texas Panhandle. Researchers are encouraged to test the models in other regions where high-quality NH emissions data are available. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  7. Evaluation of mobile emissions contributions to Mexico City's emissions inventory using on-road and cross-road emission measurements and ambient data

    NASA Astrophysics Data System (ADS)

    Zavala, M.; Herndon, S. C.; Wood, E. C.; Onasch, T. B.; Knighton, W. B.; Marr, L. C.; Kolb, C. E.; Molina, L. T.

    2009-09-01

    Mobile emissions represent a significant fraction of the total anthropogenic emissions burden in the Mexico City Metropolitan Area (MCMA) and, therefore, it is crucial to use top-down techniques informed by on-road exhaust measurements to evaluate and improve traditional bottom-up official emissions inventory (EI) for the city. We present the measurements of on-road fleet-average emission factors obtained using the Aerodyne mobile laboratory in the MCMA in March 2006 as part of the MILAGRO/MCMA-2006 field campaign. A comparison of our on-road emission measurements with those obtained in 2003 using essentially the same measurement techniques and analysis methods indicates that, in the three year span, NO emission factors remain within the measured variability ranges whereas emission factors of aldehydes and aromatics species were reduced for all sampled driving conditions. We use a top-down fuel-based approach to evaluate the mobile emissions from the gasoline fleet estimated in the bottom-up official 2006 MCMA mobile sources. Within the range of measurement uncertainties, we found probable slight overpredictions of mean EI estimates on the order of 20-28% for CO and 14-20% for NO. However, we identify a probable EI discrepancy of VOC mobile emissions between 1.4 and 1.9; although estimated benzene and toluene mobile emissions in the inventory seem to be well within the uncertainties of the corresponding emissions estimates. Aldehydes mobile emissions in the inventory, however, seem to be underpredicted by factors of 3 for HCHO and 2 for CH3CHO. Our on-road measurement-based estimate of annual emissions of organic mass from PM1 particles suggests a severe underprediction (larger than a factor of 4) of PM2.5 mobile emissions in the inventory. Analyses of ambient CO, NOx and CO/NOx concentration trends in the MCMA indicate that the early morning ambient CO/NOx ratio has decreased at a rate of about 1.9 ppm/ppm/year over the last two decades due to reductions in CO

  8. Costs of IQ Loss from Leaded Aviation Gasoline Emissions

    PubMed Central

    Wolfe, Philip J.; Giang, Amanda; Ashok, Akshay; Selin, Noelle E.; Barrett, Steven R. H.

    2017-01-01

    In the United States, general aviation piston-driven aircraft are now the largest source of lead emitted to the atmosphere. Elevated lead concentrations impair children’s IQ and can lead to lower earnings potentials. This study is the first assessment of the nationwide annual costs of IQ losses from aircraft lead emissions. We develop a general aviation emissions inventory for the continental United States and model its impact on atmospheric concentrations using the Community Multi-Scale Air Quality Model (CMAQ). We use these concentrations to quantify the impacts of annual aviation lead emissions on the U.S. population using two methods: through static estimates of cohort-wide IQ deficits and through dynamic economy-wide effects using a computational general equilibrium model. We also examine the sensitivity of these damage estimates to different background lead concentrations, showing the impact of lead controls and regulations on marginal costs. We find that aircraft-attributable lead contributes to $1.06 billion 2006 USD ($0.01 – $11.6) in annual damages from lifetime earnings reductions, and that dynamic economy-wide methods result in damage estimates that are 54% larger. Because the marginal costs of lead are dependent on background concentration, the costs of piston-driven aircraft lead emissions are expected to increase over time as regulations on other emissions sources are tightened. PMID:27494542

  9. Costs of IQ Loss from Leaded Aviation Gasoline Emissions.

    PubMed

    Wolfe, Philip J; Giang, Amanda; Ashok, Akshay; Selin, Noelle E; Barrett, Steven R H

    2016-09-06

    In the United States, general aviation piston-driven aircraft are now the largest source of lead emitted to the atmosphere. Elevated lead concentrations impair children's IQ and can lead to lower earnings potentials. This study is the first assessment of the nationwide annual costs of IQ losses from aircraft lead emissions. We develop a general aviation emissions inventory for the continental United States and model its impact on atmospheric concentrations using the community multi-scale air quality model (CMAQ). We use these concentrations to quantify the impacts of annual aviation lead emissions on the U.S. population using two methods: through static estimates of cohort-wide IQ deficits and through dynamic economy-wide effects using a computational general equilibrium model. We also examine the sensitivity of these damage estimates to different background lead concentrations, showing the impact of lead controls and regulations on marginal costs. We find that aircraft-attributable lead contributes to $1.06 billion 2006 USD ($0.01-$11.6) in annual damages from lifetime earnings reductions, and that dynamic economy-wide methods result in damage estimates that are 54% larger. Because the marginal costs of lead are dependent on background concentration, the costs of piston-driven aircraft lead emissions are expected to increase over time as regulations on other emissions sources are tightened.

  10. 40 CFR 80.90 - Conventional gasoline baseline emissions determination.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Conventional gasoline baseline... gasoline baseline emissions determination. (a) Annual average baseline values. For any facility of a refiner or importer of conventional gasoline, the annual average baseline values of the facility's exhaust...

  11. 40 CFR 80.90 - Conventional gasoline baseline emissions determination.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Conventional gasoline baseline... gasoline baseline emissions determination. (a) Annual average baseline values. For any facility of a refiner or importer of conventional gasoline, the annual average baseline values of the facility's exhaust...

  12. 40 CFR 80.90 - Conventional gasoline baseline emissions determination.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Conventional gasoline baseline... gasoline baseline emissions determination. (a) Annual average baseline values. For any facility of a refiner or importer of conventional gasoline, the annual average baseline values of the facility's exhaust...

  13. 40 CFR 80.90 - Conventional gasoline baseline emissions determination.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Conventional gasoline baseline... gasoline baseline emissions determination. (a) Annual average baseline values. For any facility of a refiner or importer of conventional gasoline, the annual average baseline values of the facility's exhaust...

  14. 40 CFR 80.90 - Conventional gasoline baseline emissions determination.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Conventional gasoline baseline... gasoline baseline emissions determination. (a) Annual average baseline values. For any facility of a refiner or importer of conventional gasoline, the annual average baseline values of the facility's exhaust...

  15. [Air pollutant emissions of aircraft in China in recent 30 years].

    PubMed

    He, Ji-Cheng

    2012-01-01

    Although aircrafts are of great importance in transportation in China, there has been rare study on air pollutant emissions of aircrafts until now. Based on the annually statistical data collected by the Statistic Center of Civil Aviation of China, using the emission factor method derived from fuel consumption, the air pollutant emissions of aircrafts during 1980-2009 were calculated, and their emission intensities and dynamic characteristics were analyzed. The results show that the emissions of SO2, CO, NO(x) and HC from aircrafts of China Civil Aviation increased from 0.31 thousand, 1.89 thousand, 2.25 thousand and 3.14 thousand tons in 1980 to 11.83 thousand, 72.98 thousand, 87.05 thousand and 121.59 thousand tons in 2009, indicating a increase of 0.397 thousand, 2.45 thousand, 2.92 thousand and 4.08 thousand tons per year, respectively. The emission intensities of SO2, CO, NO(x) and HC decreased significantly from 0.624, 3.806, 4.53 and 6.322 g x (t x km)(-1) in 1980 to 0.275, 1.697, 2.025 and 2.828 g x (t x km)(-1) in 2009, respectively. SO2, CO, NO(x) emissions of aircrafts of China Civil Aviation accounted very little of each total emissions in China, and the air pollutant emissions from aircrafts of China Civil Aviation was less than those from other industries in China.

  16. Variability of OH(3-1) and OH(6-2) emission altitude and volume emission rate from 2003 to 2011

    NASA Astrophysics Data System (ADS)

    Teiser, Georg; von Savigny, Christian

    2017-08-01

    In this study we report on variability in emission rate and centroid emission altitude of the OH(3-1) and OH(6-2) Meinel bands in the terrestrial nightglow based on spaceborne nightglow measurements with the SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) instrument on the Envisat satellite. The SCIAMACHY observations cover the time period from August 2002 to April 2012 and the nighttime observations used in this study are performed at 10:00 p.m. local solar time. Characterizing variability in OH emission altitude - particularly potential long-term variations - is important for an appropriate interpretation of ground-based OH rotational temperature measurements, because simultaneous observations of the vertical OH volume emission rate profile are usually not available for these measurements. OH emission altitude and vertically integrated emission rate time series with daily resolution for the OH(3-1) band and monthly resolution for the OH(6-2) band were analyzed using a standard multilinear regression approach allowing for seasonal variations, QBO-effects (Quasi-Biennial Oscillation), solar cycle (SC) variability and a linear long-term trend. The analysis focuses on low latitudes, where SCIAMACHY nighttime observations are available all year. The dominant sources of variability for both OH emission rate and altitude are the semi-annual and annual variations, with emission rate and altitude being highly anti-correlated. There is some evidence for a 11-year solar cycle signature in the vertically integrated emission rate and in the centroid emission altitude of both the OH(3-1) and OH(6-2) bands.

  17. N2O and CO2 emissions following repeated application of organic and mineral N fertiliser from a vegetable crop rotation.

    PubMed

    De Rosa, Daniele; Rowlings, David W; Biala, Johannes; Scheer, Clemens; Basso, Bruno; Grace, Peter R

    2018-05-11

    Accounting for nitrogen (N) release from organic amendments (OA) can reduce the use of synthetic N-fertiliser, sustain crop production, and potentially reduce soil borne greenhouse gases (GHG) emissions. However, it is difficult to assess the GHG mitigation potential for OA as a substitute of N-fertiliser over the long term due to only part of the organic N added to soil is being released in the first year after application. High-resolution nitrous oxide (N 2 O) and carbon dioxide (CO 2 ) emissions monitored from a horticultural crop rotation over 2.5 years from conventional urea application rates were compared to treatments receiving an annual application of raw and composted chicken manure combined with conventional and reduced N-fertiliser rates. The repeated application of composted manure did not increase annual N 2 O emissions while the application of raw manure resulted in N 2 O emissions up to 35.2 times higher than the zero N fertiliser treatment and up to 4.7 times higher than conventional N-fertiliser rate due to an increase in C and N availability following the repeated application of raw OA. The main factor driving N 2 O emissions was the incorporation of organic material accompanied by high soil moisture while the application of synthetic N-fertiliser induced only short-term N 2 O emission pulse. The average annual N 2 O emission factor calculated accounting for the total N applied including OA was equal to 0.27 ± 0.17%, 3.7 times lower than the IPCC default value. Accounting for the estimated N release from OA only enabled a more realistic N 2 O emission factor to be defined for organically amended field that was equal to 0.48 ± 0.3%. This study demonstrated that accounting for the N released from repeated application of composted rather than raw manure can be a viable pathway to reduce N 2 O emissions and maintain soil fertility. Copyright © 2017. Published by Elsevier B.V.

  18. 78 FR 68023 - Annual Surveys in the Manufacturing Area

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-11-13

    ... Manufacturing Area. The 2014 Annual Surveys consist of the Annual Survey of Manufactures, the Business R&D and... economic census will be conducted for the year 2017. Annual Survey of Manufactures The Annual Survey of Manufactures collects industry statistics, such as total value of shipments, employment, payroll, workers...

  19. Quantitative assessment of industrial VOC emissions in China: Historical trend, spatial distribution, uncertainties, and projection

    NASA Astrophysics Data System (ADS)

    Zheng, Chenghang; Shen, Jiali; Zhang, Yongxin; Huang, Weiwei; Zhu, Xinbo; Wu, Xuecheng; Chen, Linghong; Gao, Xiang; Cen, Kefa

    2017-02-01

    The temporal trends of industrial volatile organic compound (VOC) emissions was comprehensively summarized for the 2011 to 2013 period, and the projections for 2020 to 2050 for China were set. The results demonstrate that industrial VOC emissions in China increased from 15.3 Tg in 2011 to 29.4 Tg in 2013 at an annual average growth rate of 38.3%. Guangdong (3.45 Tg), Shandong (2.85 Tg), and Jiangsu (2.62 Tg) were the three largest contributors collectively accounting for 30.4% of the national total emissions in 2013. The top three average industrial VOC emissions per square kilometer were Shanghai (247.2 ton/km2), Tianjin (62.8 ton/km2), and Beijing (38.4 ton/km2), which were 12-80 times of the average level in China. The data from the inventory indicate that the use of VOC-containing products, as well as the production and use of VOCs as raw materials, as well as for storage and transportation contributed 75.4%, 10.3%, 9.1%, and 5.2% of the total emissions, respectively. ArcGIS was used to display the remarkable spatial distribution variation by allocating the emission into 1 km × 1 km grid cells with a population as surrogate indexes. Combined with future economic development and population change, as well as implementation of policy and upgrade of control technologies, three scenarios (scenarios A, B, and C) were set to project industrial VOC emissions for the years 2020, 2030, and 2050, which present the industrial VOC emissions in different scenarios and the potential of reducing emissions. Finally, the result shows that the collaborative control policies considerably influenced industrial VOC emissions.

  20. Long-term nitrous oxide fluxes in annual and perennial agricultural and unmanaged ecosystems in the upper Midwest USA.

    PubMed

    Gelfand, Ilya; Shcherbak, Iurii; Millar, Neville; Kravchenko, Alexandra N; Robertson, G Philip

    2016-11-01

    Differences in soil nitrous oxide (N 2 O) fluxes among ecosystems are often difficult to evaluate and predict due to high spatial and temporal variabilities and few direct experimental comparisons. For 20 years, we measured N 2 O fluxes in 11 ecosystems in southwest Michigan USA: four annual grain crops (corn-soybean-wheat rotations) managed with conventional, no-till, reduced input, or biologically based/organic inputs; three perennial crops (alfalfa, poplar, and conifers); and four unmanaged ecosystems of different successional age including mature forest. Average N 2 O emissions were higher from annual grain and N-fixing cropping systems than from nonleguminous perennial cropping systems and were low across unmanaged ecosystems. Among annual cropping systems full-rotation fluxes were indistinguishable from one another but rotation phase mattered. For example, those systems with cover crops and reduced fertilizer N emitted more N 2 O during the corn and soybean phases, but during the wheat phase fluxes were ~40% lower. Likewise, no-till did not differ from conventional tillage over the entire rotation but reduced emissions ~20% in the wheat phase and increased emissions 30-80% in the corn and soybean phases. Greenhouse gas intensity for the annual crops (flux per unit yield) was lowest for soybeans produced under conventional management, while for the 11 other crop × management combinations intensities were similar to one another. Among the fertilized systems, emissions ranged from 0.30 to 1.33 kg N 2 O-N ha -1  yr -1 and were best predicted by IPCC Tier 1 and ΔEF emission factor approaches. Annual cumulative fluxes from perennial systems were best explained by soil NO3- pools (r 2  = 0.72) but not so for annual crops, where management differences overrode simple correlations. Daily soil N 2 O emissions were poorly predicted by any measured variables. Overall, long-term measurements reveal lower fluxes in nonlegume perennial vegetation and, for

  1. Quantifying direct carbon dioxide emissions from wastewater treatment units by nondispersive infrared sensor (NDIR) - A pilot study.

    PubMed

    Kosse, Pascal; Kleeberg, Tasja; Lübken, Manfred; Matschullat, Jörg; Wichern, Marc

    2018-08-15

    Treatment of nutrient-rich wastewater potentially results in direct release of greenhouse gases (GHGs) such as CO 2 , N 2 O or CH 4 - and thus affects Waste Water Treatment Plant's carbon footprint. Accurate CO 2 quantification is challenging due to various chemical, physical and operational conditions. A floating chamber equipped with a nondispersive infrared, single beam, dual wavelength sensor has been evaluated for a pilot approach to quantify fugitive CO 2 emissions above different wastewater treatment units. Total average CO 2 flux was 1182gCO 2 ·m -2 ·d -1 with minimum and maximum fluxes of 829gCO 2 ·m -2 ·d -1 and 1493gCO 2 ·m -2 ·d -1 , respectively. Total observed CO 2 emissions were in 7 to 17kgCO 2 ·PE -1 ·a -1 (average 12kgCO 2 ·PE -1 ·a -1 ). The nitrification tank accounted for about 94.3% of the emissions, followed by secondary clarification (ca. 4.3%) and denitrification (ca. 1.4%), based on those average annual CO 2 emissions per population equivalent (PE). Copyright © 2018 Elsevier B.V. All rights reserved.

  2. 21 CFR 1315.11 - Assessment of annual needs.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 9 2012-04-01 2012-04-01 false Assessment of annual needs. 1315.11 Section 1315... QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Assessment of Annual Needs § 1315.11 Assessment of annual needs. (a) The Administrator shall determine the total quantity of ephedrine...

  3. 21 CFR 1315.11 - Assessment of annual needs.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 9 2014-04-01 2014-04-01 false Assessment of annual needs. 1315.11 Section 1315... QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Assessment of Annual Needs § 1315.11 Assessment of annual needs. (a) The Administrator shall determine the total quantity of ephedrine...

  4. 21 CFR 1315.11 - Assessment of annual needs.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 9 2013-04-01 2013-04-01 false Assessment of annual needs. 1315.11 Section 1315... QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Assessment of Annual Needs § 1315.11 Assessment of annual needs. (a) The Administrator shall determine the total quantity of ephedrine...

  5. 21 CFR 1315.11 - Assessment of annual needs.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 9 2011-04-01 2011-04-01 false Assessment of annual needs. 1315.11 Section 1315... QUOTAS FOR EPHEDRINE, PSEUDOEPHEDRINE, AND PHENYLPROPANOLAMINE Assessment of Annual Needs § 1315.11 Assessment of annual needs. (a) The Administrator shall determine the total quantity of ephedrine...

  6. Measuring and modeling of soil N2O emissions - How well are we doing?

    NASA Astrophysics Data System (ADS)

    Butterbach-Bahl, K.; Ralf, K.; Werner, C.; Wolf, B.

    2017-12-01

    Microbial processes in soils are the primarily source of atmospheric N2O. Fertilizer use to boost food and feed production of agricultural systems as well as nitrogen deposition to natural and semi-natural ecosystems due to emissions of NOx and NH3 from agriculture and energy production and re-deposition to terrestrial ecosystems has likely nearly doubled the pre-industrial source strength of soils for atmospheric N2O. Quantifying soil emissions and identifying mitigation options is becoming a major focus in the climate debate as N2O emissions from agricultural soils are a major contributor to the greenhouse gas footprint of agricultural systems, with agriculture incl. land use change contributing up to 30% to total anthropogenic GHG emissions. The increasing number of annual datasets show that soil emissions a) are largely depended on soil N availability and thus e.g. fertilizer application, b) vary with management (e.g. timing of fertilization, residue management, tillage), c) depend on soil properties such as organic matter content and pH, e) are affected by plant N uptake, and e) are controlled by environmental factors such as moisture and temperature regimes. It is remarkable that the magnitude of annual emissions is largely controlled by short-term N2O pulses occurring due to fertilization, wetting and drying or freezing and thawing of soils. All of this contributes to a notorious variability of soil N2O emissions in space and time. Overcoming this variability for quantification of source strengths and identifying tangible mitigation options requires targeted measuring approaches as well as the translation of our knowledge on mechanisms underlying emissions into process oriented models, which finally might be used for upscaling and scenario studies. This paper aims at reviewing current knowledge on measurements, modelling and upscaling of soil N2O emissions, thereby identifying short comes and uncertainties of the various approaches and fields for future

  7. Emissions From Miombo Woodland and Dambo Grassland Savanna Fires in Southern Africa

    NASA Astrophysics Data System (ADS)

    Sinha, P.; Hobbs, P. V.; Yokelson, R. J.; Blake, D. R.; Gao, S.; Kirchstetter, T. W.

    2003-12-01

    African savanna fires are the largest source of biomass burning emissions worldwide, and the miombo woodland ecosystem is the most abundant type of savanna in southern Africa. Dambo grasslands are major enclaves within miombo woodlands. Savanna fires in these two ecosystems accounted for over one-third of the total area burned in southern Africa during the dry season of 2000. Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in plots of miombo woodland and dambo grassland were obtained on September 1 and September 5, 2000, respectively. These measurements provide emission factors for a number of gaseous species including carbon dioxide (CO2), carbon monoxide (CO), sulfur dioxide (SO2), dimethyl sulfide (DMS), nitrogen oxides (NOx), ammonia (NH3), hydrogen cyanide (HCN), methane (CH4), non-methane hydrocarbons (NMHC), halocarbons, oxygenated compounds, as well as for particulates. Emission factors for the two fires are combined with measurements of fuel loading, combustion completeness, and burned area to estimate the emissions of trace gases and particles from miombo woodland and dambo grassland fires in southern Africa during the dry season of 2000. These estimates indicate that in August and September of 2000 miombo woodland and dambo grassland fires in southern Africa accounted for about 30%, 25%, 15%, and 64% of the emissions of CO2, CO, total hydrocarbons, and total particulate matter, respectively, emitted from all types of savanna fires in southern Africa. It is also estimated that the ratios of dry season emissions from miombo woodland and dambo grassland fires in Zambia to annual emissions from the use of biofuels in Zambia for CO2, CO, NOx, formic acid, CH4, NH3, ethane, ethene, propene, acetylene, formaldehyde, methanol, and acetic acid are 3.2, 1.5, 7.2, 2.5, 0.2, 0.6, 0.2, 0.5, 0.4, 0.3, 0.6, 0.3, and 0.5, respectively.

  8. Ammonia emission factors from broiler litter in barns, in storage, and after land application.

    PubMed

    Moore, Philip A; Miles, Dana; Burns, Robert; Pote, Dan; Berg, Kess; Choi, In Hag

    2011-01-01

    We measured NH₃ emissions from litter in broiler houses, during storage, and after land application and conducted a mass balance of N in poultry houses. Four state-of-the-art tunnel-ventilated broiler houses in northwest Arkansas were equipped with NH₃ sensors, anemometers, and data loggers to continuously record NH₃ concentrations and ventilation for 1 yr. Gaseous fluxes of NH₃, N₂O, CH₄, and CO₂ from litter were measured. Nitrogen (N) inputs and outputs were quantified. Ammonia emissions during storage and after land application were measured. Ammonia emissions during the flock averaged approximately 15.2 kg per day-house (equivalent to 28.3 g NH₃per bird marketed). Emissions between flocks equaled 9.09 g NH₃ per bird. Hence, in-house NH₃ emissions were 37.5 g NH₃ per bird, or 14.5 g kg(-1) bird marketed (50-d-old birds). The mass balance study showed N inputs for the year to the four houses totaled 71,340 kg N, with inputs from bedding, chicks, and feed equal to 303, 602, and 70,435 kg, respectively (equivalent to 0.60, 1.19, and 139.56 g N per bird). Nitrogen outputs totaled 70,396 kg N. Annual N output from birds marketed, NH₃ emissions, litter or cake, mortality, and NO₂ emissions was 39,485, 15,571, 14,464, 635, and 241 kg N, respectively (equivalent to 78.2, 30.8, 28.7, 1.3, and 0.5 g N per bird). The percent N recovery for the N mass balance study was 98.8%. Ammonia emissions from stacked litter during a 16-d storage period were 172 g Mg(-1) litter, which is equivalent to 0.18 g NH₃ per bird. Ammonia losses from poultry litter broadcast to pastures were 34 kg N ha (equivalent to 15% of total N applied or 7.91 g NH₃ per bird). When the litter was incorporated into the pasture using a new knifing technique, NH₃ losses were virtually zero. The total NH₃ emission factor for broilers measured in this study, which includes losses in-house, during storage, and after land application, was 45.6 g NH₃ per bird marketed. by the

  9. Soil efflux and total emission rates of magmatic CO2 at the horseshoe lake tree kill, mammoth mountain, California, 1995-1999

    USGS Publications Warehouse

    Gerlach, T.M.; Doukas, M.P.; McGee, K.A.; Kessler, R.

    2001-01-01

    We report the results of eight soil CO2 efflux surveys by the closed circulation chamber method at the Horseshoe Lake tree kill (HLTK) - the largest tree kill on Mammoth Mountain. The surveys were undertaken from 1995 to 1999 to constrain total HLTK CO2 emissions and to evaluate occasional efflux surveys as a surveillance tool for the tree kills. HLTK effluxes range from 1 to > 10,000 g m -2 day -1 (grams CO2 per square meter per day); they are not normally distributed. Station efflux rates can vary by 7-35% during the course of the 8- to 16-h surveys. Disturbance of the upper 2 cm of ground surface causes effluxes to almost double. Semivariograms of efflux spatial covariance fit exponential or spherical models; they lack nugget effects. Efflux contour maps and total CO2 emission rates based on exponential, spherical, and linear kriging models of survey data are nearly identical; similar results are also obtained with triangulation models, suggesting that the kriging models are not seriously distorted by the lack of normal efflux distributions. In addition, model estimates of total CO2 emission rates are relatively insensitive to the measurement precision of the efflux rates and to the efflux value used to separate magmatic from forest soil sources of CO2. Surveys since 1997 indicate that, contrary to earlier speculations, a termination of elevated CO2 emissions at the HLTK is unlikely anytime soon. The HLTK CO2 efflux anomaly fluctuated greatly in size and intensity throughout the 1995-1999 surveys but maintained a N-S elongation, presumably reflecting fault control of CO2 transport from depth. Total CO2 emission rates also fluctuated greatly, ranging from 46 to 136 t day-1 (metric tons CO2 per day) and averaging 93 t day-1. The large inter-survey variations are caused primarily by external (meteorological) processes operating on time scales of hours to days. The externally caused variations can mask significant changes occurring at depth; a striking example is

  10. Quantifying the impact of sub-grid surface wind variability on sea salt and dust emissions in CAM5

    NASA Astrophysics Data System (ADS)

    Zhang, Kai; Zhao, Chun; Wan, Hui; Qian, Yun; Easter, Richard C.; Ghan, Steven J.; Sakaguchi, Koichi; Liu, Xiaohong

    2016-02-01

    This paper evaluates the impact of sub-grid variability of surface wind on sea salt and dust emissions in the Community Atmosphere Model version 5 (CAM5). The basic strategy is to calculate emission fluxes multiple times, using different wind speed samples of a Weibull probability distribution derived from model-predicted grid-box mean quantities. In order to derive the Weibull distribution, the sub-grid standard deviation of surface wind speed is estimated by taking into account four mechanisms: turbulence under neutral and stable conditions, dry convective eddies, moist convective eddies over the ocean, and air motions induced by mesoscale systems and fine-scale topography over land. The contributions of turbulence and dry convective eddy are parameterized using schemes from the literature. Wind variabilities caused by moist convective eddies and fine-scale topography are estimated using empirical relationships derived from an operational weather analysis data set at 15 km resolution. The estimated sub-grid standard deviations of surface wind speed agree well with reference results derived from 1 year of global weather analysis at 15 km resolution and from two regional model simulations with 3 km grid spacing.The wind-distribution-based emission calculations are implemented in CAM5. In terms of computational cost, the increase in total simulation time turns out to be less than 3 %. Simulations at 2° resolution indicate that sub-grid wind variability has relatively small impacts (about 7 % increase) on the global annual mean emission of sea salt aerosols, but considerable influence on the emission of dust. Among the considered mechanisms, dry convective eddies and mesoscale flows associated with topography are major causes of dust emission enhancement. With all the four mechanisms included and without additional adjustment of uncertain parameters in the model, the simulated global and annual mean dust emission increase by about 50 % compared to the default model

  11. Quantifying the impact of sub-grid surface wind variability on sea salt and dust emissions in CAM5

    DOE PAGES

    Zhang, Kai; Zhao, Chun; Wan, Hui; ...

    2016-02-12

    This paper evaluates the impact of sub-grid variability of surface wind on sea salt and dust emissions in the Community Atmosphere Model version 5 (CAM5). The basic strategy is to calculate emission fluxes multiple times, using different wind speed samples of a Weibull probability distribution derived from model-predicted grid-box mean quantities. In order to derive the Weibull distribution, the sub-grid standard deviation of surface wind speed is estimated by taking into account four mechanisms: turbulence under neutral and stable conditions, dry convective eddies, moist convective eddies over the ocean, and air motions induced by mesoscale systems and fine-scale topography overmore » land. The contributions of turbulence and dry convective eddy are parameterized using schemes from the literature. Wind variabilities caused by moist convective eddies and fine-scale topography are estimated using empirical relationships derived from an operational weather analysis data set at 15 km resolution. The estimated sub-grid standard deviations of surface wind speed agree well with reference results derived from 1 year of global weather analysis at 15 km resolution and from two regional model simulations with 3 km grid spacing.The wind-distribution-based emission calculations are implemented in CAM5. In terms of computational cost, the increase in total simulation time turns out to be less than 3 %. Simulations at 2° resolution indicate that sub-grid wind variability has relatively small impacts (about 7 % increase) on the global annual mean emission of sea salt aerosols, but considerable influence on the emission of dust. Among the considered mechanisms, dry convective eddies and mesoscale flows associated with topography are major causes of dust emission enhancement. With all the four mechanisms included and without additional adjustment of uncertain parameters in the model, the simulated global and annual mean dust emission increase by about 50 % compared to the

  12. Quantifying the impact of sub-grid surface wind variability on sea salt and dust emissions in CAM5

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Kai; Zhao, Chun; Wan, Hui

    This paper evaluates the impact of sub-grid variability of surface wind on sea salt and dust emissions in the Community Atmosphere Model version 5 (CAM5). The basic strategy is to calculate emission fluxes multiple times, using different wind speed samples of a Weibull probability distribution derived from model-predicted grid-box mean quantities. In order to derive the Weibull distribution, the sub-grid standard deviation of surface wind speed is estimated by taking into account four mechanisms: turbulence under neutral and stable conditions, dry convective eddies, moist convective eddies over the ocean, and air motions induced by mesoscale systems and fine-scale topography overmore » land. The contributions of turbulence and dry convective eddy are parameterized using schemes from the literature. Wind variabilities caused by moist convective eddies and fine-scale topography are estimated using empirical relationships derived from an operational weather analysis data set at 15 km resolution. The estimated sub-grid standard deviations of surface wind speed agree well with reference results derived from 1 year of global weather analysis at 15 km resolution and from two regional model simulations with 3 km grid spacing.The wind-distribution-based emission calculations are implemented in CAM5. In terms of computational cost, the increase in total simulation time turns out to be less than 3 %. Simulations at 2° resolution indicate that sub-grid wind variability has relatively small impacts (about 7 % increase) on the global annual mean emission of sea salt aerosols, but considerable influence on the emission of dust. Among the considered mechanisms, dry convective eddies and mesoscale flows associated with topography are major causes of dust emission enhancement. With all the four mechanisms included and without additional adjustment of uncertain parameters in the model, the simulated global and annual mean dust emission increase by about 50 % compared to the

  13. Assessment of vehicle emission programs in China during 1998-2013: Achievement, challenges and implications.

    PubMed

    Wu, Xiaomeng; Wu, Ye; Zhang, Shaojun; Liu, Huan; Fu, Lixin; Hao, Jiming

    2016-07-01

    China has been embracing rapid motorization since the 1990s, and vehicles have become one of the major sources of air pollution problems. Since the late 1990s, thanks to the international experience, China has adopted comprehensive control measures to mitigate vehicle emissions. This study employs a local emission model (EMBEV) to assess China's first fifteen-year (1998-2013) efforts in controlling vehicles emissions. Our results show that China's total annual vehicle emissions in 2013 were 4.16 million tons (Mt) of HC, 27.4 Mt of CO, 7.72 Mt of NOX, and 0.37 Mt of PM2.5, respectively. Although vehicle emissions are substantially reduced relative to the without control scenarios, we still observe significantly higher emission density in East China than in developed countries with longer histories of vehicle emission control. This study further informs China's policy-makers of the prominent challenges to control vehicle emissions in the future. First, unlike other major air pollutants, total NOX emissions have rapidly increased due to a surge of diesel trucks and the postponed China IV standard nationwide. Simultaneous implementation of fuel quality improvements and vehicle-engine emission standards will be of great importance to alleviate NOX emissions for diesel fleets. Second, the enforcement of increasingly stringent standards should include strict oversight of type-approval conformity, in-use complacence and durability, which would help reduce gross emitters of PM2.5 that are considerable among in-use diesel fleets at the present. Third, this study reveals higher HC emissions than previous results and indicates evaporative emissions may have been underestimated. Considering that China's overall vehicle ownership is far from saturation, persistent efforts are required through economic tools, traffic management and emissions regulations to lower vehicle-use intensity and limit both exhaust and evaporative emissions. Furthermore, in light of the complex

  14. Estimates of global biomass burning emissions for reactive greenhouse gases (CO, NMHCs, and NOx) and CO2

    NASA Astrophysics Data System (ADS)

    Jain, Atul K.; Tao, Zhining; Yang, Xiaojuan; Gillespie, Conor

    2006-03-01

    Open fire biomass burning and domestic biofuel burning (e.g., cooking, heating, and charcoal making) algorithms have been incorporated into a terrestrial ecosystem model to estimate CO2 and key reactive GHGs (CO, NOx, and NMHCs) emissions for the year 2000. The emissions are calculated over the globe at a 0.5° × 0.5° spatial resolution using tree density imagery, and two separate sets of data each for global area burned and land clearing for croplands, along with biofuel consumption rate data. The estimated global and annual total dry matter (DM) burned due to open fire biomass burning ranges between 5221 and 7346 Tg DM/yr, whereas the resultant emissions ranges are 6564-9093 Tg CO2/yr, 438-568 Tg CO/yr, 11-16 Tg NOx/yr (as NO), and 29-40 Tg NMHCs/yr. The results indicate that land use changes for cropland is one of the major sources of biomass burning, which amounts to 25-27% (CO2), 25 -28% (CO), 20-23% (NO), and 28-30% (NMHCs) of the total open fire biomass burning emissions of these gases. Estimated DM burned associated with domestic biofuel burning is 3,114 Tg DM/yr, and resultant emissions are 4825 Tg CO2/yr, 243 Tg CO/yr, 3 Tg NOx/yr, and 23 Tg NMHCs/yr. Total emissions from biomass burning are highest in tropical regions (Asia, America, and Africa), where we identify important contributions from primary forest cutting for croplands and domestic biofuel burning.

  15. Cross-scale controls on carbon emissions from boreal forest megafires.

    PubMed

    Walker, Xanthe J; Rogers, Brendan M; Baltzer, Jennifer L; Cumming, Steven G; Day, Nicola J; Goetz, Scott J; Johnstone, Jill F; Schuur, Edward A G; Turetsky, Merritt R; Mack, Michelle C

    2018-04-26

    Climate warming and drying is associated with increased wildfire disturbance and the emergence of megafires in North American boreal forests. Changes to the fire regime are expected to strongly increase combustion emissions of carbon (C) which could alter regional C balance and positively feedback to climate warming. In order to accurately estimate C emissions and thereby better predict future climate feedbacks, there is a need to understand the major sources of heterogeneity that impact C emissions at different scales. Here, we examined 211 field plots in boreal forests dominated by black spruce (Picea mariana) or jack pine (Pinus banksiana) of the Northwest Territories (NWT), Canada after an unprecedentedly large area burned in 2014. We assessed both aboveground and soil organic layer (SOL) combustion, with the goal of determining the major drivers in total C emissions, as well as to develop a high spatial resolution model to scale emissions in a relatively understudied region of the boreal forest. On average, 3.35 kg C m -2 was combusted and almost 90% of this was from SOL combustion. Our results indicate that black spruce stands located at landscape positions with intermediate drainage contribute the most to C emissions. Indices associated with fire weather and date of burn did not impact emissions, which we attribute to the extreme fire weather over a short period of time. Using these results, we estimated a total of 94.3 Tg C emitted from 2.85 Mha of burned area across the entire 2014 NWT fire complex, which offsets almost 50% of mean annual net ecosystem production in terrestrial ecosystems of Canada. Our study also highlights the need for fine-scale estimates of burned area that represent small water bodies and regionally specific calibrations of combustion that account for spatial heterogeneity in order to accurately model emissions at the continental scale. © 2018 John Wiley & Sons Ltd.

  16. Attributing land-use change carbon emissions to exported biomass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saikku, Laura, E-mail: laura.saikku@helsinki.fi; Soimakallio, Sampo, E-mail: sampo.soimakallio@vtt.fi; Pingoud, Kim, E-mail: kim.pingoud@vtt.fi

    2012-11-15

    In this study, a simple, transparent and robust method is developed in which land-use change (LUC) emissions are retrospectively attributed to exported biomass products based on the agricultural area occupied for the production. LUC emissions account for approximately one-fifth of current greenhouse gas emissions. Increasing agricultural exports are becoming an important driver of deforestation. Brazil and Indonesia are used as case studies due to their significant deforestation in recent years. According to our study, in 2007, approximately 32% and 15% of the total agricultural land harvested and LUC emissions in Brazil and Indonesia respectively were due to exports. The mostmore » important exported single items with regard to deforestation were palm oil for Indonesia and bovine meat for Brazil. To reduce greenhouse gas (GHG) emissions effectively worldwide, leakage of emissions should be avoided. This can be done, for example, by attributing embodied LUC emissions to exported biomass products. With the approach developed in this study, controversial attribution between direct and indirect LUC and amortization of emissions over the product life cycle can be overcome, as the method operates on an average basis and annual level. The approach could be considered in the context of the UNFCCC climate policy instead of, or alongside with, other instruments aimed at reducing deforestation. However, the quality of the data should be improved and some methodological issues, such as the allocation procedure in multiproduct systems and the possible dilution effect through third parties not committed to emission reduction targets, should be considered. - Highlights: Black-Right-Pointing-Pointer CO{sub 2} emissions from land use changes are highly important. Black-Right-Pointing-Pointer Attribution of land use changes for products is difficult. Black-Right-Pointing-Pointer Simple and robust method is developed to attribute land use change emissions.« less

  17. The global distribution of ammonia emissions from seabird colonies

    NASA Astrophysics Data System (ADS)

    Riddick, S. N.; Dragosits, U.; Blackall, T. D.; Daunt, F.; Wanless, S.; Sutton, M. A.

    2012-08-01

    Seabird colonies represent a significant source of atmospheric ammonia (NH3) in remote maritime systems, producing a source of nitrogen that may encourage plant growth, alter terrestrial plant community composition and affect the surrounding marine ecosystem. To investigate seabird NH3 emissions on a global scale, we developed a contemporary seabird database including a total seabird population of 261 million breeding pairs. We used this in conjunction with a bioenergetics model to estimate the mass of nitrogen excreted by all seabirds at each breeding colony. The results combined with the findings of mid-latitude field studies of volatilization rates estimate the global distribution of NH3 emissions from seabird colonies on an annual basis. The largest uncertainty in our emission estimate concerns the potential temperature dependence of NH3 emission. To investigate this we calculated and compared temperature independent emission estimates with a maximum feasible temperature dependent emission, based on the thermodynamic dissociation and solubility equilibria. Using the temperature independent approach, we estimate global NH3 emissions from seabird colonies at 404 Gg NH3 per year. By comparison, since most seabirds are located in relatively cold circumpolar locations, the thermodynamically dependent estimate is 136 Gg NH3 per year. Actual global emissions are expected to be within these bounds, as other factors, such as non-linear interactions with water availability and surface infiltration, moderate the theoretical temperature response. Combining sources of error from temperature (±49%), seabird population estimates (±36%), variation in diet composition (±23%) and non-breeder attendance (±13%), gives a mid estimate with an overall uncertainty range of NH3 emission from seabird colonies of 270 [97-442] Gg NH3 per year. These emissions are environmentally relevant as they primarily occur as "hot-spots" in otherwise pristine environments with low anthropogenic

  18. Ozone monitoring instrument observations of interannual increases in SO2 emissions from Indian coal-fired power plants during 2005-2012.

    PubMed

    Lu, Zifeng; Streets, David G; de Foy, Benjamin; Krotkov, Nickolay A

    2013-12-17

    Due to the rapid growth of electricity demand and the absence of regulations, sulfur dioxide (SO2) emissions from coal-fired power plants in India have increased notably in the past decade. In this study, we present the first interannual comparison of SO2 emissions and the satellite SO2 observations from the Ozone Monitoring Instrument (OMI) for Indian coal-fired power plants during the OMI era of 2005-2012. A detailed unit-based inventory is developed for the Indian coal-fired power sector, and results show that its SO2 emissions increased dramatically by 71% during 2005-2012. Using the oversampling technique, yearly high-resolution OMI maps for the whole domain of India are created, and they reveal a continuous increase in SO2 columns over India. Power plant regions with annual SO2 emissions greater than 50 Gg year(-1) produce statistically significant OMI signals, and a high correlation (R = 0.93) is found between SO2 emissions and OMI-observed SO2 burdens. Contrary to the decreasing trend of national mean SO2 concentrations reported by the Indian Government, both the total OMI-observed SO2 and annual average SO2 concentrations in coal-fired power plant regions increased by >60% during 2005-2012, implying the air quality monitoring network needs to be optimized to reflect the true SO2 situation in India.

  19. The Boston Methane Project: Mapping Surface Emissions to Inform Atmospheric Estimation of Urban Methane Flux

    NASA Astrophysics Data System (ADS)

    Phillips, N.; Crosson, E.; Down, A.; Hutyra, L.; Jackson, R. B.; McKain, K.; Rella, C.; Raciti, S. M.; Wofsy, S. C.

    2012-12-01

    Lost and unaccounted natural gas can amount to over 6% of Massachusetts' total annual greenhouse gas inventory (expressed as equivalent CO2 tonnage). An unknown portion of this loss is due to natural gas leaks in pipeline distribution systems. The objective of the Boston Methane Project is to estimate the overall leak rate from natural gas systems in metropolitan Boston, and to compare this flux with fluxes from the other primary methane emissions sources. Companion talks at this meeting describe the atmospheric measurement and modeling framework, and chemical and isotopic tracers that can partition total atmospheric methane flux into natural gas and non-natural gas components. This talk focuses on estimation of surface emissions that inform the atmospheric modeling and partitioning. These surface emissions include over 3,300 pipeline natural gas leaks in Boston. For the state of Massachusetts as a whole, the amount of natural gas reported as lost and unaccounted for by utility companies was greater than estimated landfill emissions by an order of magnitude. Moreover, these landfill emissions were overwhelmingly located outside of metro Boston, while gas leaks are concentrated in exactly the opposite pattern, increasing from suburban Boston toward the urban core. Work is in progress to estimate spatial distribution of methane emissions from wetlands and sewer systems. We conclude with a description of how these spatial data sets will be combined and represented for application in atmospheric modeling.

  20. Impact of reduced anthropogenic emissions and century flood on the phosphorus stock, concentrations and loads in the Upper Danube

    PubMed Central

    Zoboli, Ottavia; Viglione, Alberto; Rechberger, Helmut; Zessner, Matthias

    2015-01-01

    Patterns of changes in the concentration of total and soluble reactive phosphorus (TP, SRP) and suspended sediments at different flow levels from 1991 to 2013 in the Austrian Danube are statistically analyzed and related to point and diffuse emissions, as well as to extreme hydrological events. Annual loads are calculated with three methods and their development in time is examined taking into consideration total emissions and hydrological conditions. The reduction of point discharges achieved during the 1990s was well translated into decreasing TP and SRP baseflow concentrations during the same period, but it did not induce any change in the concentrations at higher flow levels nor in the annual transport of TP loads. A sharp and long-lasting decline in TP concentration, affecting all flow levels, took place after a major flood in 2002. It was still visible during another major flood in 2013, which recorded lower TP concentrations than its predecessor. Such decline could not be linked to changes in point or diffuse emissions. This suggests that, as a result of the flood, the river system experienced a significant depletion of its in-stream phosphorus stock and a reduced mobilization of TP rich sediments afterwards. This hypothesis is corroborated by the decoupling of peak phosphorus loads from peak maximum discharges after 2002. These results are highly relevant for the design of monitoring schemes and for the correct interpretation of water quality data in terms of assessing the performance of environmental management measures. PMID:25747371

  1. Methane Emissions from Semi-natural, Drained and Re-wetted Peatlands in Germany

    NASA Astrophysics Data System (ADS)

    Tiemeyer, B.; Bechtold, M.; Albiac Borraz, E.; Augustin, J.; Drösler, M.; Beetz, S.; Beyer, C.; Eickenscheidt, T.; Fiedler, S.; Förster, C.; Giebels, M.; Glatzel, S.; Heinichen, J.; Höper, H.; Leiber-Sauheitl, K.; Peichl-Brak, M.; Rosskopf, N.; Sommer, M.; Zeitz, J.; Freibauer, A.

    2014-12-01

    Drained peatlands contribute around 5% to the total German greenhouse gas emissions. While these areas are hotspots for carbon dioxide (CO2) and nitrous oxide (N2O) emissions, some re-wetted peatlands may emit large amounts of methane (CH4). To quantify the GHG emission reductions achieved by the re-wetting of peatlands, the reduced CO2 emissions and the potential CH4fluxes need to be balanced. We synthesized methane flux data from 14 peatlands with 122 sites. At each site, methane fluxes were measured for one to three years with static chambers. The sites comprise arable land, intensive and extensive grassland, forest and peat mining areas as well as semi-natural and re-wetted peatlands on both bog peat, fen peat and other soils rich in organic carbon. Besides the groundwater table we consider further potential drivers for the CH4fluxes such as soil properties (carbon, nitrogen, pH, and physical properties), climatic parameters, land use, and vegetation composition. Annual methane fluxes ranged from low uptake rates (around -1 g CH4-C m² a-1) to very high emissions (> 200 g CH4-C m² a-1). Intensively drained sites showed very low emissions, while for annual mean water levels higher than 5-10 cm below ground, elevated emissions of more than 20 g CH4-C may occur. At some re-wetted sites CH4 emissions of more than 100 g CH4-C m² a-1 were measured, which roughly equal the Global Warming Potential of the CO2-emissions from intensively drained agricultural sites. These high fluxes were probably caused by a combination of nutrient-rich conditions, the dieback of poorly adapted plants and a fast accumulation of organic sediments. However, this was the exception and not the rule even for very wet re-wetted sites. Achieving a model efficiency of 0.72 during cross-validation, a boosted regression tree (BRT) model was well able to describe logarithmic CH4-fluxes. Groundwater level, biotope type, soil nitrogen content, and ponding duration during summer were the most

  2. Interannual variation in nitrous oxide emissions from perennial ryegrass/white clover grassland used for dairy production.

    PubMed

    Burchill, William; Li, Dejun; Lanigan, Gary J; Williams, Micheal; Humphreys, James

    2014-10-01

    Nitrous oxide (N2 O) emissions are subject to intra- and interannual variation due to changes in weather and management. This creates significant uncertainties when quantifying estimates of annual N2 O emissions from grazed grasslands. Despite these uncertainties, the majority of studies are short-term in nature (<1 year) and as a consequence, there is a lack of data on interannual variation in N2 O emissions. The objectives of this study were to (i) quantify annual N2 O emissions and (ii) assess the causes of interannual variation in emissions from grazed perennial ryegrass/white clover grassland. Nitrous oxide emissions were measured from fertilized and grazed perennial ryegrass/white clover grassland (WC) and from perennial ryegrass plots that were not grazed and did not receive N input (GB), over 4 years from 2008 to 2012 in Ireland (52°51'N, 08°21'W). The annual N2 O-N emissions (kg ha(-1); mean ± SE) ranged from 4.4 ± 0.2 to 34.4 ± 5.5 from WC and from 1.7 ± 0.8 to 6.3 ± 1.2 from GB. Interannual variation in N2 O emissions was attributed to differences in annual rainfall, monthly (December) soil temperatures and variation in N input. Such substantial interannual variation in N2 O emissions highlights the need for long-term studies of emissions from managed pastoral systems. © 2014 The Authors. Global Change Biology Published by John Wiley & Sons Ltd.

  3. Daily black carbon emissions from fires in northern Eurasia for 2002-2015

    NASA Astrophysics Data System (ADS)

    Hao, Wei Min; Petkov, Alexander; Nordgren, Bryce L.; Corley, Rachel E.; Silverstein, Robin P.; Urbanski, Shawn P.; Evangeliou, Nikolaos; Balkanski, Yves; Kinder, Bradley L.

    2016-12-01

    Black carbon (BC) emitted from fires in northern Eurasia is transported and deposited on ice and snow in the Arctic and can accelerate its melting during certain times of the year. Thus, we developed a high spatial resolution (500 m × 500 m) dataset to examine daily BC emissions from fires in this region for 2002-2015. Black carbon emissions were estimated based on MODIS (Moderate Resolution Imaging Spectroradiometer) land cover maps and detected burned areas, the Forest Inventory Survey of the Russian Federation, the International Panel on Climate Change (IPCC) Tier-1 Global Biomass Carbon Map for the year 2000, and vegetation specific BC emission factors. Annual BC emissions from northern Eurasian fires varied greatly, ranging from 0.39 Tg in 2010 to 1.82 Tg in 2015, with an average of 0.71 ± 0.37 Tg from 2002 to 2015. During the 14-year period, BC emissions from forest fires accounted for about two-thirds of the emissions, followed by grassland fires (18 %). Russia dominated the BC emissions from forest fires (92 %) and central and western Asia was the major region for BC emissions from grassland fires (54 %). Overall, Russia contributed 80 % of the total BC emissions from fires in northern Eurasia. Black carbon emissions were the highest in the years 2003, 2008, and 2012. Approximately 58 % of the BC emissions from fires occurred in spring, 31 % in summer, and 10 % in fall. The high emissions in spring also coincide with the most intense period of ice and snow melting in the Arctic.

  4. 40 CFR 60.3040 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous emission monitoring systems? 60.3040 Section 60.3040 Protection of Environment ENVIRONMENTAL... continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring... emission monitoring systems daily and quarterly as specified in appendix F of this part. ...

  5. 40 CFR 60.2941 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous emission monitoring systems? 60.2941 Section 60.2941 Protection of Environment ENVIRONMENTAL... emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems... emission monitoring systems daily and quarterly as specified in appendix F of this part. ...

  6. Development of a road transport emission inventory for Greece and the Greater Athens Area: effects of important parameters.

    PubMed

    Fameli, K M; Assimakopoulos, V D

    2015-02-01

    Traffic is considered one of the major polluting sectors and as a consequence a significant cause for the measured exceedances of ambient air quality limit values mainly in urban areas. The Greater Athens Area (located in Attica), the most populated area in Greece, faces severe air pollution problems due to the combination of high road traffic emissions, complex topography and local meteorological conditions. Even though several efforts were made to construct traffic emission inventories for Greece and Attica, still there is not a spatially and temporally resolved one, based on data from relevant authorities and organisations. The present work aims to estimate road emissions in Greece and Attica based on the top down approach. The programme COPERT 4 was used to calculate the annual total emissions from the road transport sector for the period 2006-2010 and an emission inventory for Greece and Attica was developed with high spatial (6 × 6 km(2) for Greece and 2 × 2 km(2) for Attica) and temporal (1-hour) resolutions. The results revealed that about 40% of national CO₂, CO, VOC and NMVOC values and 30% of NOx and particles are emitted in Attica. The fuel consumption and the subsequent reduction of annual mileage driven in combination with the import of new engine anti-pollution technologies affected CO₂, CO, VOC and NMVOC emissions. The major part of CO (56.53%) and CO₂ (66.15%) emissions was due to passenger cars (2010), while heavy duty vehicles (HDVs) were connected with NOx, PM₂.₅ and PM₁₀ emissions with 51.27%, 43.97% and 38.13% respectively (2010). The fleet composition, the penetration of diesel fuelled cars, the increase of urban average speed and the fleet renewal are among the most effective parameters towards the emission reduction strategies. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. Concentration and flux of total and dissolved phosphorus, total nitrogen, chloride, and total suspended solids for monitored tributaries of Lake Champlain, 1990-2012

    USGS Publications Warehouse

    Medalie, Laura

    2014-01-01

    Annual and daily concentrations and fluxes of total and dissolved phosphorus, total nitrogen, chloride, and total suspended solids were estimated for 18 monitored tributaries to Lake Champlain by using the Weighted Regressions on Time, Discharge, and Seasons regression model. Estimates were made for 21 or 23 years, depending on data availability, for the purpose of providing timely and accessible summary reports as stipulated in the 2010 update to the Lake Champlain “Opportunities for Action” management plan. Estimates of concentration and flux were provided for each tributary based on (1) observed daily discharges and (2) a flow-normalizing procedure, which removed the random fluctuations of climate-related variability. The flux bias statistic, an indicator of the ability of the Weighted Regressions on Time, Discharge, and Season regression models to provide accurate representations of flux, showed acceptable bias (less than ±10 percent) for 68 out of 72 models for total and dissolved phosphorus, total nitrogen, and chloride. Six out of 18 models for total suspended solids had moderate bias (between 10 and 30 percent), an expected result given the frequently nonlinear relation between total suspended solids and discharge. One model for total suspended solids with a very high bias was influenced by a single extreme value; however, removal of that value, although reducing the bias substantially, had little effect on annual fluxes.

  8. Total prompt γ-ray emission in fission

    NASA Astrophysics Data System (ADS)

    Wu, C. Y.; Chyzh, A.; Kwan, E.; Henderson, R. A.; Bredeweg, T. A.; Haight, R. C.; Hayes-Sterbenz, A. C.; Lee, H. Y.; O'Donnell, J. M.; Ullmann, J. L.

    2017-09-01

    The total prompt γ-ray energy distributions were measured for the neutron-induced fission of 235U, 239,241Pu at incident neutron energy of 0.025 eV-100 keV, and the spontaneous fission of 252Cf using the Detector for Advanced Neutron Capture Experiments (DANCE) array in coincidence with the detection of fission fragments by a parallel-plate avalanche counter. Corrections were made to the measured distribution by unfolding the two-dimension spectrum of total prompt γ-ray energy vs multiplicity using a simulated DANCE response matrix. A summary of this work is presented with the emphasis on the comparison of total prompt fission γ-ray energy between our results and previous ones. The mean values of the total prompt γ-ray energy ⟨Eγ,tot⟩, determined from the unfolded distributions, are ˜20% higher than those derived from measurements using single γ-ray detector for all the fissile nuclei studied.

  9. Dimethylsulfide Chemistry: Annual, Seasonal, and Spatial Impacts on Sulfate

    EPA Science Inventory

    We incorporated oceanic emissions and atmospheric chemistry of dimethylsulfide (DMS) into the hemispheric Community Multiscale Air Quality model and performed annual model simulations without and with DMS chemistry. The model without DMS chemistry predicts higher concentrations o...

  10. Testing and modeling the influence of reclamation and control methods for reducing nonpoint mercury emissions associated with industrial open pit gold mines.

    PubMed

    Miller, Matthieu B; Gustin, Mae S

    2013-06-01

    Industrial gold mining is a significant source of mercury (Hg) emission to the atmosphere. To investigate ways to reduce these emissions, reclamation and dust and mercury control methods used at open pit gold mining operations in Nevada were studied in a laboratory setting. Using this information along with field data, and building off previous work, total annual Hg emissions were estimated for two active gold mines in northern Nevada. Results showed that capping mining waste materials with a low-Hg substrate can reduce Hg emissions from 50 to nearly 100%. The spraying of typical dust control solutions often results in higher Hg emissions, especially as materials dry after application. The concentrated application of a dithiocarbamate Hg control reagent appears to reduce Hg emissions, but further testing mimicking the actual distribution of this chemical within an active leach solution is needed to make a more definitive assessment.

  11. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Xiaoxi; Huey, L. Gregory; Yokelson, Robert J.

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM 1) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements ofmore » temperate wildfires, boreal forest fires, and temperate prescribed fires. Furthermore, the wildfires emitted high amounts of PM 1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than 2 times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM 1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM 1 emission estimate (1530 ± 570 Gg yr -1) is over 3 times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from biomass burning in the western states is significantly underestimated. Additionally, our results indicate that prescribed burning may be an effective method to reduce fine particle emissions.« less

  12. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

    DOE PAGES

    Liu, Xiaoxi; Huey, L. Gregory; Yokelson, Robert J.; ...

    2017-06-14

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM 1) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements ofmore » temperate wildfires, boreal forest fires, and temperate prescribed fires. Furthermore, the wildfires emitted high amounts of PM 1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than 2 times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM 1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM 1 emission estimate (1530 ± 570 Gg yr -1) is over 3 times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from biomass burning in the western states is significantly underestimated. Additionally, our results indicate that prescribed burning may be an effective method to reduce fine particle emissions.« less

  13. Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Xiaoxi; Huey, L. Gregory; Yokelson, Robert J.

    Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds, and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM1) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements of temperatemore » wildfires, boreal forest fires, and temperate prescribed fires. The wildfires emitted high amounts of PM1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than two times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM1 emission estimate (1530 ± 570 Gg yr-1) is over three times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from BB in the western states is significantly underestimated. In addition, our results indicate prescribed burning may be an effective method to reduce fine particle emissions.« less

  14. Mercury emission estimates from fires: an initial inventory for the United States.

    PubMed

    Wiedinmyer, Christine; Friedli, Hans

    2007-12-01

    Recent studies have shown that emissions of mercury (Hg), a hazardous air pollutant, from fires can be significant. However, to date, these emissions have not been well-quantified for the entire United States. Daily emissions of Hg from fires in the lower 48 states of the United States (LOWER48) and in Alaska were estimated for 2002-2006 using a simple fire emissions model. Emission factors of Hg from fires in different ecosystems were compiled from published plume studies and from soil-based assessments. Annual averaged emissions of Hg from fires in the LOWER48 and Alaska were 44 (20-65) metric tons yr(-1), equivalent to approximately 30% of the U.S. EPA 2002 National Emissions Inventory for Hg. Alaska had the highest averaged monthly emissions of all states; however, the emissions have a high temporal variability. Emissions from forests dominate the inventory, suggesting that Hg emissions from agricultural fires are not significant on an annual basis. The uncertainty in the Hg emission factors due to limited data leads to an uncertainty in the emission estimates on the order of +/-50%. Research is still needed to better constrain Hg emission factors from fires, particularly in the eastern U.S. and for ecosystems other than forests.

  15. Assessment of ecotoxicity and total volatile organic compound (TVOC) emissions from food and children's toy products.

    PubMed

    Szczepańska, Natalia; Marć, Mariusz; Kudłak, Błażej; Simeonov, Vasil; Tsakovski, Stefan; Namieśnik, Jacek

    2018-09-30

    The development of new methods for identifying a broad spectrum of analytes, as well as highly selective tools to provide the most accurate information regarding the processes and relationships in the world, has been an area of interest for researchers for many years. The information obtained with these tools provides valuable data to complement existing knowledge but, above all, to identify and determine previously unknown hazards. Recently, attention has been paid to the migration of xenobiotics from the surfaces of various everyday objects and the resulting impacts on human health. Since children are among those most vulnerable to health consequences, one of the main subjects of interest is the migration of low-molecular-weight compounds from toys and products intended for children. This migration has become a stimulus for research aimed at determining the degree of release of compounds from popular commercially available chocolate/toy sets. One of main objectives of this research was to determine the impact of time on the ecotoxicity (with Vibrio fischeri bioluminescent bacteria) of extracts of products intended for children and to assess the correlation with total volatile organic compound emissions using basic chemometric methods. The studies on endocrine potential (with XenoScreen YES/YAS) of the extracts and showed that compounds released from the studied objects (including packaging foils, plastic capsules storing toys, most of toys studied and all chocolate samples) exhibit mostly androgenic antagonistic behavior while using artificial saliva as extraction medium increased the impact observed. The impact of time in most cases was positive one and increased with prolonging extraction time. The small-scale stationary environmental test chambers - μ-CTE™ 250 system was employed to perform the studies aimed at determining the profile of total volatile organic compounds (TVOCs) emissions. Due to this it was possible to state that objects from which the

  16. Greenhouse gas exchange in West African savanna ecosystems - how important are emissions from termite mounds?

    NASA Astrophysics Data System (ADS)

    Brümmer, C.; Brüggemann, N.

    2012-04-01

    Savannas cover large areas of the Earth's surface and play an important role in global carbon and nitrogen cycling. In this study, we present the soil-atmosphere exchange of N2O, CH4, and CO2 during two field campaigns throughout the growing seasons 2005 and 2006 at a natural savanna site that was not subject to human disturbances except for annual burning, and four agricultural sites planted with sorghum (n=2), cotton and peanut in Burkina Faso. The annual N2O emission of the nature reserve site amounted to 0.52 kg N2O-N ha-1 yr-1 in 2005 and to 0.67 kg N2O-N ha-1 yr-1 in 2006, whereas the calculated average annual N2O release of the crop sites was only 0.19 and 0.20 kg N2O-N ha-1 yr-1 in 2005 and 2006, respectively. As a result of a temporal up-scaling approach, a lower bound of annual N2O release could be given for two fertilized sorghum plots, that is, 0.83 kg N2O-N ha-1 yr-1 for a highly fertilized plot and 0.44 kg N2O-N ha-1 yr-1 for a moderately fertilized plot. During the rainy season both CH4 uptake in the range of up to 20 μg CH4-C m-2 h-1 as well as CH4 emission up to 300 μg CH4-C m-2 h-1 were observed at the nature reserve site, which was on average a CH4 source of 87.4 and 30.8 μg CH4-C m-2 h-1 in 2005 and 2006, respectively. All crop sites were on average weak CH4 sinks without significant seasonal variation. Uptake rates ranged between 2.5 and 8.7 μg CH4-C m-2 h-1. Occasionally very low net CH4 emission was observed after heavy rainfall events. Mean annual CH4 rates could be estimated to 2.48 kg CH4-C ha-1 yr-1 and -0.68 kg CH4-C ha-1 yr-1 for the nature reserve site and the crop sites, respectively. Trace gas emissions from termite (Cubitermes fungifaber) mounds that were almost exclusively found at the nature reserve were one order of magnitude higher for N2O and CO2, and two orders of magnitude higher for CH4 than soil emissions of the respective trace gas. Termite N2O, CH4 and CO2 release at the nature reserve contributed only 3.2%, 8.1% and

  17. 40 CFR 60.1250 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous emission monitoring systems? 60.1250 Section 60.1250 Protection of Environment ENVIRONMENTAL... Continuous Emission Monitoring § 60.1250 What is my schedule for evaluating continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems no more than 13...

  18. FY2014 Fuel & Lubricant Technologies Annual Progress Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stork, Kevin

    2016-02-01

    Annual progress report for Fuel & Lubricant Technologies. The Fuel & Lubricant Technologies Program supports fuels and lubricants research and development (R&D) to provide vehicle manufacturers and users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement.

  19. 2008 annual merit review

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None, None

    2009-01-18

    The 2008 DOE Vehicle Technologies Program Annual Merit Review was held February 25-28, 2008 in Bethesda, Maryland. The review encompassed all of the work done by the Vehicle Technologies Program: a total of 280 individual activities were reviewed, by a total of just over 100 reviewers. A total of 1,908 individual review responses were received for the technical reviews, and an additional 29 individual review responses were received for the plenary session review.

  20. Modeling study of natural emissions, source apportionment, and emission control of atmospheric mercury

    NASA Astrophysics Data System (ADS)

    Shetty, Suraj K.

    Mercury (Hg) is a toxic pollutant and is important to understand its cycling in the environment. In this dissertation, a number of modeling investigations were conducted to better understand the emission from natural surfaces, the source-receptor relationship of the emissions, and emission reduction of atmospheric mercury. The first part of this work estimates mercury emissions from vegetation, soil and water surfaces using a number of natural emission processors and detailed (LAI) Leaf Area Index data from GIS (Geographic Information System) satellite products. East Asian domain was chosen as it contributes nearly 50% of the global anthropogenic mercury emissions into the atmosphere. The estimated annual natural mercury emissions (gaseous elemental mercury) in the domain are 834 Mg yr-1 with 462 Mg yr-1 contributing from China. Compared to anthropogenic sources, natural sources show greater seasonal variability (highest in simmer). The emissions are significant, sometimes dominant, contributors to total mercury emission in the regions. The estimates provide possible explanation for the gaps between the anthropogenic emission estimates based on activity data and the emission inferred from field observations in the regions. To understand the contribution of domestic emissions to mercury deposition in the United States, the second part of the work applies the mercury model of Community Multi-scale Air Quality Modeling system (CMAQ-Hg v4.6) to apportion the various emission sources attributing to the mercury wet and dry deposition in the 6 United States receptor regions. Contributions to mercury deposition from electric generating units (EGU), iron and steel industry (IRST), industrial point sources excluding EGU and IRST (OIPM), the remaining anthropogenic sources (RA), natural processes (NAT), and out-of-boundary transport (BC) in domain was estimated. The model results for 2005 compared reasonably well to field observations made by MDN (Mercury Deposition Network

  1. Inverse modeling of fossil fuel CO2 emissions at urban scale using OCO-2 retrievals of total column CO2

    NASA Astrophysics Data System (ADS)

    Ye, X.; Lauvaux, T.; Kort, E. A.; Lin, J. C.; Oda, T.; Yang, E.; Wu, D.

    2016-12-01

    Rapid economic development has given rise to a steady increase of global carbon emissions, which have accumulated in the atmosphere for the past 200 years. Urbanization has concentrated about 70% of the global fossil-fuel CO2 emissions in large metropolitan areas distributed around the world, which represents the most significant anthropogenic contribution to climate change. However, highly uncertain quantifications of urban CO2 emissions are commonplace for numerous cities because of poorly-documented inventories of energy consumption. Therefore, accurate estimates of carbon emissions from global observing systems are a necessity if mitigation strategies are meant to be implemented at global scales. Space-based observations of total column averaged CO2 concentration (XCO2) provide a very promising and powerful tool to quantify urban CO2 fluxes. For the first time, measurements from the Orbiting Carbon Observatory 2 (OCO-2) mission are assimilated in a high resolution inverse modeling system to quantify fossil-fuel CO2 emissions of multiple cities around the globe. The Open-source Data Inventory for Anthropogenic CO2 (ODIAC) emission inventory is employed as a first guess, while the atmospheric transport is simulated using the WRF-Chem model at 1-km resolution. Emission detection and quantification is performed with an Ensemble Kalman Filter method. We demonstrate here the potential of the inverse approach for assimilating thousands of OCO-2 retrievals along tracks near metropolitan areas. We present the detection potential of the system with real-case applications near power plants and present inverse emissions using actual OCO-2 measurements on various urban landscapes. Finally, we will discuss the potential of OCO-2-like satellite instruments for monitoring temporal variations of fossil-fuel CO2 emissions over multiple years, which can provide valuable insights for future satellite observation strategies.

  2. Drainage and tillage practices in the winter fallow season mitigate CH4 and N2O emissions from a double-rice field in China

    NASA Astrophysics Data System (ADS)

    Zhang, Guangbin; Yu, Haiyang; Fan, Xianfang; Yang, Yuting; Ma, Jing; Xu, Hua

    2016-09-01

    Traditional land management (no tillage, no drainage, NTND) during the winter fallow season results in substantial CH4 and N2O emissions from double-rice fields in China. A field experiment was conducted to investigate the effects of drainage and tillage during the winter fallow season on CH4 and N2O emissions and to develop mitigation options. The experiment had four treatments: NTND, NTD (drainage but no tillage), TND (tillage but no drainage), and TD (both drainage and tillage). The study was conducted from 2010 to 2014 in a Chinese double-rice field. During winter, total precipitation and mean daily temperature significantly affected CH4 emission. Compared to NTND, drainage and tillage decreased annual CH4 emissions in early- and late-rice seasons by 54 and 33 kg CH4 ha-1 yr-1, respectively. Drainage and tillage increased N2O emissions in the winter fallow season but reduced it in early- and late-rice seasons, resulting in no annual change in N2O emission. Global warming potentials of CH4 and N2O emissions were decreased by 1.49 and 0.92 t CO2 eq. ha-1 yr-1, respectively, and were reduced more by combining drainage with tillage, providing a mitigation potential of 1.96 t CO2 eq. ha-1 yr-1. A low total C content and high C / N ratio in rice residues showed that tillage in the winter fallow season reduced CH4 and N2O emissions in both early- and late-rice seasons. Drainage and tillage significantly decreased the abundance of methanogens in paddy soil, and this may explain the decrease of CH4 emissions. Greenhouse gas intensity was significantly decreased by drainage and tillage separately, and the reduction was greater by combining drainage with tillage, resulting in a reduction of 0.17 t CO2 eq. t-1. The results indicate that drainage combined with tillage during the winter fallow season is an effective strategy for mitigating greenhouse gas releases from double-rice fields.

  3. Committed CO2 Emissions of China's Coal-fired Power Plants

    NASA Astrophysics Data System (ADS)

    Suqin, J.

    2016-12-01

    The extent of global warming is determined by the cumulative effects of CO2 in the atmosphere. Coal-fired power plants, the largest anthropogenic source of CO2 emissions, produce large amount of CO2 emissions during their lifetimes of operation (committed emissions), which thus influence the future carbon emission space under specific targets on mitigating climate change (e.g., the 2 degree warming limit relative to pre-industrial levels). Comprehensive understanding of committed CO2 emissions for coal-fired power generators is urgently needed in mitigating global climate change, especially in China, the largest global CO2emitter. We calculated China's committed CO2 emissions from coal-fired power generators installed during 1993-2013 and evaluated their impact on future emission spaces at the provincial level, by using local specific data on the newly installed capacities. The committed CO2 emissions are calculated as the product of the annual coal consumption from newly installed capacities, emission factors (CO2emissions per unit crude coal consumption) and expected lifetimes. The sensitivities about generators lifetimes and the drivers on provincial committed emissions are also analyzed. Our results show that these relatively recently installed coal-fired power generators will lead to 106 Gt of CO2 emissions over the course of their lifetimes, which is more than three times the global CO2 emissions from fossil fuels in 2010. More than 80% (85 Gt) of their total committed CO2 will be emitted after 2013, which are referred to as the remaining emissions. Due to the uncertainties of generators lifetime, these remaining emissions would increase by 45 Gt if the lifetimes of China's coal-fired power generators were prolonged by 15 years. Furthermore, the remaining emissions are very different among various provinces owing to local developments and policy disparities. Provinces with large amounts of secondary industry and abundant coal reserves have higher committed

  4. A preliminary survey of household and personal carbon dioxide emissions in Ireland.

    PubMed

    Kenny, Tricia; Gray, N F

    2009-02-01

    A model specifically designed for Ireland was used to measure CO(2)e emissions (CO(2), CH(4) and N(2)O) from Irish households for the first time. A total of 103 Irish households with occupancy rates varying between 1 and 6 (mean 2.9) were surveyed. The average annual household emission was found to be 16.55 t CO(2)e y(-1), which is equivalent to an average personal emission of 5.70 t CO(2)e Ca(-1) y(-1) comprising 42.2% related to home energy use, 35.1% to transport, 20.6% to air travel and other fuel intensive leisure activities, and just 2.1% associated with household waste disposal. Air travel accounts for an average personal emission of 1.152 t CO(2)e Ca(-1) y(-1), although this is highest in single and two person households at 1.693 and 2.227 t CO(2)e Ca(-1) y(-1) respectively. Household energy consumption becomes more efficient when occupancy rate increases. The most energy efficient homes in the survey were terraced with a natural gas heating systems. The least efficient were detached house with oil fuelled heating system.

  5. Building the Fire Energetics and Emissions Research (FEER) Smoke Emissions Inventory Version 1.0

    NASA Technical Reports Server (NTRS)

    Ellison, Luke; Ichoku, Charles; Zhang, Feng; Wang, Jun

    2014-01-01

    The Fire Energetics and Emissions Research (FEER) group's new coefficient of emission global gridded product at 1x1 resolution that directly relates fire readiative energy (FRE) to smoke aerosol release, FEERv1.0 Ce, made its public debut in August 2013. Since then, steps have been taken to generate corresponding maps and totals of total particulate matter (PM) emissions using different sources of FRE, and subsequently to simulate the resulting PM(sub 2.5) in the WRF-Chem 3.5 model using emission rates from FEERv1.0 as well as other standard biomass burning emission inventories. An flowchart of the FEER algorithm to calculate Ce is outlined here along with a display of the resulting emissions of total PM globally and also regionally. The modeling results from the WRF-Chem3.5 simulations are also shown.

  6. The National Emissions Inventory Significantly Overestimates NOx Emissions: Analysis of CMAQ and in situ observations from DISCOVER-AQ

    NASA Astrophysics Data System (ADS)

    Anderson, D. C.; Dickerson, R. R.; Loughner, C.

    2013-12-01

    NOx and CO not only adversely impact human health, but they, along with associated VOCs, are also important precursors for O3 formation. While ambient NOx and CO concentrations have decreased dramatically over the past 10-20 years, O3 has remained a more recalcitrant problem, particularly in the Baltimore/Washington region. Reduction of O3 production requires that emissions inventories, such as the National Emissions Inventory (NEI), accurately capture total emissions of CO and NOx while also correctly apportioning them among different sectors. Previous evaluations of the NEI paint different pictures of its accuracy, with assertions that it overestimates either one or both of CO and NOx from anywhere between 25 percent to a factor of 2. These conflicting claims warrant further investigation. In this study, measurements of NOx and CO taken aboard the NOAA P3B airplane during the 2011 DISCOVER-AQ field campaign were used to determine the NOx/CO emissions ratio at 6 locations in the Washington/Baltimore region. An average molar emissions ratio of 12.8 × 1.2 CO/NOx was found by calculating the change in CO over the change in NOx from vertical concentration profiles in the planetary boundary layer. Ratios showed little variation with location. Observed values were approximately a factor of 1.35 - 1.75 times greater than that predicted by the annual, countywide emissions ratio from the 2008 NEI. When compared to a temporalized, gridded version of the inventory processed by SMOKE, ratio observations were greater than that predicted by inventories by up to a factor of 2. Comparison of the in situ measurements and remotely sensed observations from MOPITT of CO to the Community Multiscale Air Quality (CMAQ) model agree within 10-35 percent, with the model higher on average. Measurements of NOy by two separate analytical techniques, on the other hand, show that CMAQ consistently and significantly overestimates NOy concentrations. Combined with the CO observations, this

  7. Measurements of methane emissions at natural gas production sites in the United States.

    PubMed

    Allen, David T; Torres, Vincent M; Thomas, James; Sullivan, David W; Harrison, Matthew; Hendler, Al; Herndon, Scott C; Kolb, Charles E; Fraser, Matthew P; Hill, A Daniel; Lamb, Brian K; Miskimins, Jennifer; Sawyer, Robert F; Seinfeld, John H

    2013-10-29

    Engineering estimates of methane emissions from natural gas production have led to varied projections of national emissions. This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States (150 production sites, 27 well completion flowbacks, 9 well unloadings, and 4 workovers). For well completion flowbacks, which clear fractured wells of liquid to allow gas production, methane emissions ranged from 0.01 Mg to 17 Mg (mean = 1.7 Mg; 95% confidence bounds of 0.67-3.3 Mg), compared with an average of 81 Mg per event in the 2011 EPA national emission inventory from April 2013. Emission factors for pneumatic pumps and controllers as well as equipment leaks were both comparable to and higher than estimates in the national inventory. Overall, if emission factors from this work for completion flowbacks, equipment leaks, and pneumatic pumps and controllers are assumed to be representative of national populations and are used to estimate national emissions, total annual emissions from these source categories are calculated to be 957 Gg of methane (with sampling and measurement uncertainties estimated at ± 200 Gg). The estimate for comparable source categories in the EPA national inventory is ~1,200 Gg. Additional measurements of unloadings and workovers are needed to produce national emission estimates for these source categories. The 957 Gg in emissions for completion flowbacks, pneumatics, and equipment leaks, coupled with EPA national inventory estimates for other categories, leads to an estimated 2,300 Gg of methane emissions from natural gas production (0.42% of gross gas production).

  8. Measurements of methane emissions at natural gas production sites in the United States

    PubMed Central

    Allen, David T.; Torres, Vincent M.; Thomas, James; Sullivan, David W.; Harrison, Matthew; Hendler, Al; Herndon, Scott C.; Kolb, Charles E.; Fraser, Matthew P.; Hill, A. Daniel; Lamb, Brian K.; Miskimins, Jennifer; Sawyer, Robert F.; Seinfeld, John H.

    2013-01-01

    Engineering estimates of methane emissions from natural gas production have led to varied projections of national emissions. This work reports direct measurements of methane emissions at 190 onshore natural gas sites in the United States (150 production sites, 27 well completion flowbacks, 9 well unloadings, and 4 workovers). For well completion flowbacks, which clear fractured wells of liquid to allow gas production, methane emissions ranged from 0.01 Mg to 17 Mg (mean = 1.7 Mg; 95% confidence bounds of 0.67–3.3 Mg), compared with an average of 81 Mg per event in the 2011 EPA national emission inventory from April 2013. Emission factors for pneumatic pumps and controllers as well as equipment leaks were both comparable to and higher than estimates in the national inventory. Overall, if emission factors from this work for completion flowbacks, equipment leaks, and pneumatic pumps and controllers are assumed to be representative of national populations and are used to estimate national emissions, total annual emissions from these source categories are calculated to be 957 Gg of methane (with sampling and measurement uncertainties estimated at ±200 Gg). The estimate for comparable source categories in the EPA national inventory is ∼1,200 Gg. Additional measurements of unloadings and workovers are needed to produce national emission estimates for these source categories. The 957 Gg in emissions for completion flowbacks, pneumatics, and equipment leaks, coupled with EPA national inventory estimates for other categories, leads to an estimated 2,300 Gg of methane emissions from natural gas production (0.42% of gross gas production). PMID:24043804

  9. Greenhouse gas emissions from Australian open-cut coal mines: contribution from spontaneous combustion and low-temperature oxidation.

    PubMed

    Day, Stuart J; Carras, John N; Fry, Robyn; Williams, David J

    2010-07-01

    Spontaneous combustion and low-temperature oxidation of waste coal and other carbonaceous material at open-cut coal mines are potentially significant sources of greenhouse gas emissions. However, the magnitude of these emissions is largely unknown. In this study, emissions from spontaneous combustion and low-temperature oxidation were estimated for six Australian open-cut coal mines with annual coal production ranging from 1.7 to more than 16 Mt. Greenhouse emissions from all other sources at these mines were also estimated and compared to those from spontaneous combustion and low-temperature oxidation. In all cases, fugitive emission of methane was the largest source of greenhouse gas; however, in some mines, spontaneous combustion accounted for almost a third of all emissions. For one mine, it was estimated that emissions from spontaneous combustion were around 250,000 t CO(2)-e per annum. The contribution from low-temperature oxidation was generally less than about 1% of the total for all six mines. Estimating areas of spoil affected by spontaneous combustion by ground-based surveys was prone to under-report the area. Airborne infrared imaging appears to be a more reliable method.

  10. Quantitative determination of total cesium in highly active liquid waste by using liquid electrode plasma optical emission spectrometry.

    PubMed

    Do, Van-Khoai; Yamamoto, Masahiko; Taguchi, Shigeo; Takamura, Yuzuru; Surugaya, Naoki; Kuno, Takehiko

    2018-06-01

    A sensitive analytical method for determination of total cesium (Cs) in highly active liquid waste (HALW) by using modified liquid electrode plasma optical emission spectrometry (LEP-OES) is developed in this study. The instrument is modified to measure radioactive samples in a glove box. The effects of important factors, including pulsed voltage sequence and nitric acid concentration, on the emission of Cs are investigated. The limit of detection (LOD) and limit of quantification (LOQ) are 0.005 mg/L and 0.02 mg/L, respectively. The achieved LOD is one order lower than that of recently developed spectroscopic methods using liquid discharge plasma. The developed method is validated by subjecting a simulated HALW sample to inductively coupled plasma mass spectrometry (ICP-MS). The recoveries obtained from a spike-and-recovery test are 96-102%, implying good accuracy. The method is successfully applied to the quantification of Cs in a real HALW sample at the Tokai reprocessing plant in Japan. Apart from dilution and filtration of the HALW sample, no other pre-treatment process is required. The results agree well with the values obtained using gamma spectrometry. The developed method offers a reliable technique for rapid analysis of total Cs in HALW samples. Copyright © 2018 Elsevier B.V. All rights reserved.

  11. A more accurate method using MOVES (Motor Vehicle Emission Simulator) to estimate emission burden for regional-level analysis.

    PubMed

    Liu, Xiaobo

    2015-07-01

    The U.S. Environmental Protection Agency's (EPA) Motor Vehicle Emission Simulator (MOVES) is required by the EPA to replace Mobile 6 as an official on-road emission model. Incorporated with annual vehicle mile traveled (VMT) by Highways Performance Monitoring System (HPMS) vehicle class, MOVES allocates VMT from HPMS to MOVES source (vehicle) types and calculates emission burden by MOVES source type. However, the calculated running emission burden by MOVES source type may be deviated from the actual emission burden because of MOVES source population, specifically the population fraction by MOVES source type in HPMS vehicle class. The deviation is also the result of the use of the universal set of parameters, i.e., relative mileage accumulation rate (relativeMAR), packaged in MOVES default database. This paper presents a novel approach by adjusting the relativeMAR to eliminate the impact of MOVES source population on running exhaust emission and to keep start and evaporative emissions unchanged for both MOVES2010b and MOVES2014. Results from MOVES runs using this approach indicated significant improvements on VMT distribution and emission burden estimation for each MOVES source type. The deviation of VMT by MOVES source type is minimized by using this approach from 12% to less than 0.05% for MOVES2010b and from 50% to less than 0.2% for MOVES2014 except for MOVES source type 53. Source type 53 still remains about 30% variation. The improvement of VMT distribution results in the elimination of emission burden deviation for each MOVES source type. For MOVES2010b, the deviation of emission burdens decreases from -12% for particulate matter less than 2.5 μm (PM2.5) and -9% for carbon monoxide (CO) to less than 0.002%. For MOVES2014, it drops from 80% for CO and 97% for PM2.5 to 0.006%. This approach is developed to more accurately estimate the total emission burdens using EPA's MOVES, both MOVES2010b and MOVES2014, by redistributing vehicle mile traveled (VMT) by

  12. Emissions of mercury in Southern Africa derived from long-term observations at Cape Point, South Africa

    NASA Astrophysics Data System (ADS)

    Brunke, E.-G.; Ebinghaus, R.; Kock, H. H.; Labuschagne, C.; Slemr, F.

    2012-05-01

    Mercury emissions in South Africa have so far been estimated only by a bottom-up approach from activities and emission factors for different processes. In this paper we derive GEM/CO (GEM being gaseous elemental mercury, Hg0), GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios from plumes observed during long-term monitoring of these species at Cape Point between March 2007 and December 2009. The average observed GEM/CO, GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios were 2.40 ± 2.65 pg m-3 ppb-1 (n = 47), 62.7 ± 80.2 pg m-3 ppb-1 (n = 44), 3.61 ± 4.66 pg m-3 ppb-1 (n = 46), 35.6 ± 25.4 ppb ppm-1 (n = 52), 20.2 ± 15.5 ppb ppm-1 (n=48), and 0.876 ± 1.106 ppb ppm-1 (n=42), respectively. The observed CO/CO2, CH4/CO2, and CH4/CO emission ratios agree within the combined uncertainties of the observations and emissions with the ratios calculated from EDGAR (version 4.2) CO2, CO, and CH4 inventories for South Africa and Southern Africa (South Africa, Lesotho, Swaziland, Namibia, Botswana, Zimbabwe, and Mozambique) in 2007 and 2008 (inventories for 2009 are not available yet). Total elemental mercury emission of 13.1, 15.2, and 16.1 t Hg yr-1 are estimated independently using the GEM/CO, GEM/CO2, and GEM/CH4 emission ratios and the annual mean CO, CO2, and CH4 emissions, respectively, of South Africa in 2007 and 2008. The average of these independent estimates of 14.8 ± 1.5 t GEM yr-1 is much less than the total emission of 257 t Hg yr-1 from older inventories. Considering that emission of GEM represents only 50-78% of all mercury emissions, our estimates come close to the total mercury emission estimates ranging between 40-50 t Hg yr-1 from more recent inventories.

  13. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Paul Imhoff; Ramin Yazdani; Don Augenstein

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by aboutmore » 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).« less

  14. LLNL NESHAPs 2015 Annual Report - June 2016

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wilson, K. R.; Gallegos, G. M.; MacQueen, D. H.

    2016-06-01

    Lawrence Livermore National Security, LLC operates facilities at Lawrence Livermore National Laboratory (LLNL) in which radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) National Emission Standards for Hazardous Air Pollutants (NESHAPs) in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H, which regulates radionuclide emissions to air from Department of Energy (DOE) facilities. Specifically, NESHAPs limits the emission of radionuclides to the ambient air to levels resulting in an annual effective dose equivalent of 10 mrem (100 μSv) to any member of the public. Using measured and calculated emissions, andmore » building-specific and common parameters, LLNL personnel applied the EPA-approved computer code, CAP88-PC, Version 4.0.1.17, to calculate the dose to the maximally exposed individual member of the public for the Livermore Site and Site 300.« less

  15. Nitrogen emission and deposition budget in West and Central Africa

    NASA Astrophysics Data System (ADS)

    Galy-Lacaux, C.; Delon, C.

    2014-12-01

    Atmospheric nitrogen depends on land surface exchanges of nitrogen compounds. In Sub Saharan Africa, deposition and emission fluxes of nitrogen compounds are poorly quantified, and are likely to increase in the near future due to land use change and anthropogenic pressure. This work proposes an estimate of atmospheric N compounds budget in West and Central Africa, along an ecosystem transect, from dry savanna to wet savanna and forest, for years 2000-2007. The budget may be considered as a one point in time budget, to be included in long term studies as one of the first reference point for Sub Saharan Africa. Gaseous dry deposition fluxes are estimated by considering N compounds concentrations measured in the frame of the IDAF network (IGAC/DEBITS/AFrica) at the monthly scale and modeling of deposition velocities at the IDAF sites, taking into account the bi directional exchange of ammonia. Particulate dry deposition fluxes are calculated using the same inferential method. Wet deposition fluxes are calculated from measurements of ammonium and nitrate chemical content in precipitations at the IDAF sites combined with the annual rainfall amount. In terms of emission, biogenic NO emissions are simulated at each IDAF site with a surface model coupled to an emission module elaborated from an artificial neural network equation. Ammonia emissions from volatilization are calculated from literature data on livestock quantity in each country and N content in manure. NOx and NH3 emission from biomass burning and domestic fires are estimated from satellite data and emission factors. The total budget shows that emission sources of nitrogen compounds are in equilibrium with deposition fluxes in dry and wet savannas, with respectively 7.40 (±1.90) deposited and 9.01 (±3.44) kgN ha-1 yr-1 emitted in dry savanna, 8.38 (±2.04) kgN ha-1 yr-1 deposited and 9.60 (±0.69) kgN ha-1 yr-1 emitted in wet savanna. In forested ecosystems, the total budget is dominated by wet plus dry

  16. Understanding NOx emission trends in China based on OMI observations

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Ga, D.; Smeltzer, C. D.; Yi, R.; Liu, Z.

    2012-12-01

    We analyze OMI observations of NO2 columns over China from 2005 to 2010. Simulations using a regional 3-D chemical transport model (REAM) are used to derive the top-down anthropogenic NOx emissions. The Kendall method is then applied to derive the emission trend. The emission trend is affected by the economic slowdown in 2009. After removing the effect of one year abnormal data, the overall emission trend is 4.35±1.42% per year, which is slower than the linear-regression trend of 5.8-10.8% per year reported for previous years. We find large regional, seasonal, and urban-rural variations in emission trend. The annual emission trends of Northeast China, Central China Plain, Yangtze River Delta and Pearl River Delta are 44.98±1.39%, 5.24±1.63%, 3.31±1.02% and -4.02±1.87%, respectively. The annual emission trends of four megacities, Beijing, Shanghai, Guangzhou and Shenzhen are 0.7±0.27%, -0.75±0.31%, -4.08±1.21% and -6.22±2.85%,, considerably lower than the regional averages. These results appear to suggest that a number of factors, including migration of high-emission industries, vehicle emission regulations, emission control measures of thermal power plants, increased hydro-power usage, have reduced or reversed the increasing trend of NOx emissions in more economically developed megacities and southern coastal regions.

  17. Evaluation of Mobile Source Emissions and Trends

    NASA Astrophysics Data System (ADS)

    Dallmann, Timothy Ryan

    Mobile sources contribute significantly to air pollution problems. Relevant pollutants include numerous gaseous and particle-phase species that can affect human health, ecosystems, and climate. Accurate inventories of emissions from these sources are needed to help understand possible adverse impacts, and to develop effective air quality management strategies. Unfortunately large uncertainties persist in the understanding of mobile source emissions, and how these emissions are changing over time. This dissertation aims to evaluate long-term trends in mobile source emissions in the United States, and to make detailed measurements of emissions from present-day fleets of on-road vehicles operating in California. Long-term trends in mobile source emissions of nitrogen oxides (NO x) and fine particulate matter (PM2.5) in the United States were investigated through development of a fuel-based emission inventory. Annual emissions from on- and off-road gasoline and diesel engines were quantified for the years 1996-2006. Diesel engines were found to be the dominant mobile source of NOx and PM2.5, and on-road diesel vehicles were identified as the single largest anthropogenic source of NOx emissions in the United States as of 2005. The importance of diesel engines as a source of exhaust particulate matter emissions has led to the recent introduction of advanced emission control technologies in the United States, such as diesel particle filters (DPF), which have been required since 2007 for all new on-road heavy-duty (HD) diesel engines. In addition to national requirements for the use of such control devices on new engines, California has mandated accelerated clean-up of statewide emissions from older in-use diesel engines. The plume capture method was further applied to measure emissions from a more diverse population of trucks observed at the Caldecott tunnel in summer 2010. Emissions from hundreds of individual trucks were measured, and emission factor distributions were

  18. Estimating mercury emissions resulting from wildfire in forests of the Western United States.

    PubMed

    Webster, Jackson P; Kane, Tyler J; Obrist, Daniel; Ryan, Joseph N; Aiken, George R

    2016-10-15

    Understanding the emissions of mercury (Hg) from wildfires is important for quantifying the global atmospheric Hg sources. Emissions of Hg from soils resulting from wildfires in the Western United States was estimated for the 2000 to 2013 period, and the potential emission of Hg from forest soils was assessed as a function of forest type and soil-heating. Wildfire released an annual average of 3100±1900kg-Hgy(-1) for the years spanning 2000-2013 in the 11 states within the study area. This estimate is nearly 5-fold lower than previous estimates for the study region. Lower emission estimates are attributed to an inclusion of fire severity within burn perimeters. Within reported wildfire perimeters, the average distribution of low, moderate, and high severity burns was 52, 29, and 19% of the total area, respectively. Review of literature data suggests that that low severity burning does not result in soil heating, moderate severity fire results in shallow soil heating, and high severity fire results in relatively deep soil heating (<5cm). Using this approach, emission factors for high severity burns ranged from 58 to 640μg-Hgkg-fuel(-1). In contrast, low severity burns have emission factors that are estimated to be only 18-34μg-Hgkg-fuel(-1). In this estimate, wildfire is predicted to release 1-30gHgha(-1) from Western United States forest soils while above ground fuels are projected to contribute an additional 0.9 to 7.8gHgha(-1). Land cover types with low biomass (desert scrub) are projected to release less than 1gHgha(-1). Following soil sources, fuel source contributions to total Hg emissions generally followed the order of duff>wood>foliage>litter>branches. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Methane Emissions from the Inland Waters of Alaska

    NASA Astrophysics Data System (ADS)

    Striegl, R. G.; Butman, D. E.; Stackpoole, S. M.; Dornblaser, M.

    2017-12-01

    Inland waters at high latitudes generally emit methane (CH4) continuously to the atmosphere during the open water season and build-up CH4 under ice during winter that is released over a short period following ice melt. Landscape position, stream and river size, water source, and turbulence created by water flow largely control CH4 emissions from streams and rivers. Organic carbon sources for CH4 production in lakes vary widely among lakes and landscapes and include hydrologic inputs from terrestrial sources, releases from permafrost thaw (thermokarst), and autochthonous inputs from aquatic macrophytes and algae. Lake emissions are therefore controlled by the balance between within-lake CH4 production and consumption, surface turbulence at the water-air interface, and CH4 ebullition. This creates a complex range of conditions that are difficult to characterize, where dissolved CH4 concentrations may vary by up to 4 orders of magnitude among lakes and/or within a single lake over an annual seasonal cycle. Moreover, large inputs of organic matter from permafrost thaw or other sources commonly result in high rates of bubble production and ebullition from some lakes, while other lakes have negligible ebullition. We quantified water surface areas and estimated CH4 emission rates for lakes, streams and rivers for the six major hydrologic regions of Alaska and determined that they collectively emit about 0.124 Tg C per year as CH4 to the atmosphere. Lake emissions comprise about 75% of the total. When adjusted for total land surface area in Alaska, our lake emission estimate is substantially smaller than previous global estimates for inland waters north of 50 degrees North latitude. We attribute this to incorporation of results that cover a broad range of lake conditions in interior Alaska and to new data from lakes in southwest Alaska that have very low CH4 concentration but very large surface area.

  20. 40 CFR 60.3040 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... continuous emission monitoring systems? 60.3040 Section 60.3040 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES... continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring...

  1. 40 CFR 60.1740 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... continuous emission monitoring systems? 60.1740 Section 60.1740 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES... evaluating continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission...

  2. 40 CFR 60.2941 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... continuous emission monitoring systems? 60.2941 Section 60.2941 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES... emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems...

  3. Water-saving ground cover rice production system reduces net greenhouse gas fluxes in an annual rice-based cropping system

    NASA Astrophysics Data System (ADS)

    Yao, Z.; Du, Y.; Tao, Y.; Zheng, X.; Liu, C.; Lin, S.; Butterbach-Bahl, K.

    2014-11-01

    To safeguard food security and preserve precious water resources, the technology of water-saving ground cover rice production system (GCRPS) is being increasingly adopted for rice cultivation. However, changes in soil water status and temperature under GCRPS may affect soil biogeochemical processes that control the biosphere-atmosphere exchanges of methane (CH4), nitrous oxide (N2O) and carbon dioxide (CO2). The overall goal of this study is to better understand how net ecosystem greenhouse gas exchanges (NEGE) and grain yields are affected by GCRPS in an annual rice-based cropping system. Our evaluation was based on measurements of the CH4 and N2O fluxes and soil heterotrophic respiration (CO2 emissions) over a complete year, and the estimated soil carbon sequestration intensity for six different fertilizer treatments for conventional paddy and GCRPS. The fertilizer treatments included urea application and no N fertilization for both conventional paddy (CUN and CNN) and GCRPS (GUN and GNN), and solely chicken manure (GCM) and combined urea and chicken manure applications (GUM) for GCRPS. Averaging across all the fertilizer treatments, GCRPS increased annual N2O emission and grain yield by 40 and 9%, respectively, and decreased annual CH4 emission by 69%, while GCRPS did not affect soil CO2 emissions relative to the conventional paddy. The annual direct emission factors of N2O were 4.01, 0.09 and 0.50% for GUN, GCM and GUM, respectively, and 1.52% for the conventional paddy (CUN). The annual soil carbon sequestration intensity under GCRPS was estimated to be an average of -1.33 Mg C ha-1 yr-1, which is approximately 44% higher than the conventional paddy. The annual NEGE were 10.80-11.02 Mg CO2-eq ha-1 yr-1 for the conventional paddy and 3.05-9.37 Mg CO2-eq ha-1 yr-1 for the GCRPS, suggesting the potential feasibility of GCRPS in reducing net greenhouse effects from rice cultivation. Using organic fertilizers for GCRPS considerably reduced annual emissions of CH4

  4. Water-saving ground cover rice production system reduces net greenhouse gas fluxes in an annual rice-based cropping system

    NASA Astrophysics Data System (ADS)

    Yao, Z.; Du, Y.; Tao, Y.; Zheng, X.; Liu, C.; Lin, S.; Butterbach-Bahl, K.

    2014-06-01

    To safeguard food security and preserve precious water resources, the technology of water-saving ground cover rice production system (GCRPS) is being increasingly adopted for the rice cultivation. However, changes in soil water status and temperature under GCRPS may affect soil biogeochemical processes that control the biosphere-atmosphere exchanges of methane (CH4), nitrous oxide (N2O) and carbon dioxide (CO2). The overall goal of this study is to better understand how net ecosystem greenhouse gas exchanges (NEGE) and grain yields are affected by GCRPS in an annual rice-based cropping system. Our evaluation was based on measurements of the CH4 and N2O fluxes and soil heterotrophic respiration (CO2 emission) over a complete year, as well as the estimated soil carbon sequestration intensity for six different fertilizer treatments for conventional paddy and GCRPS. The fertilizer treatments included urea application and no N fertilization for both conventional paddy (CUN and CNN) and GCRPS (GUN and GNN), solely chicken manure (GCM) and combined urea and chicken manure applications (GUM) for GCRPS. Averaging across all the fertilizer treatments, GCRPS increased annual N2O emission and grain yield by 40% and 9%, respectively, and decreased annual CH4 emission by 69%, while GCRPS did not affect soil CO2 emissions relative to the conventional paddy. The annual direct emission factors of N2O were 4.01, 0.087 and 0.50% for GUN, GCM and GUM, respectively, and 1.52% for the conventional paddy (CUN). The annual soil carbon sequestration intensity under GCRPS was estimated to be an average of -1.33 Mg C ha-1 yr-1, which is approximately 44% higher than the conventional paddy. The annual NEGE were 10.80-11.02 Mg CO2-eq ha-1 yr-1 for the conventional paddy and 3.05-9.37 Mg CO2-eq ha-1 yr-1 for the GCRPS, suggesting the potential feasibility of GCRPS in reducing net greenhouse effect from rice cultivation. Using organic fertilizers for GCRPS considerably reduced annual emissions

  5. Cost-effectiveness of reducing sulfur emissions from ships.

    PubMed

    Wang, Chengfeng; Corbett, James J; Winebrake, James J

    2007-12-15

    We model cost-effectiveness of control strategies for reducing SO2 emissions from U.S. foreign commerce ships traveling in existing European or hypothetical U.S. West Coast SO(x) Emission Control Areas (SECAs) under international maritime regulations. Variation among marginal costs of control for individual ships choosing between fuel-switching and aftertreatment reveals cost-saving potential of economic incentive instruments. Compared to regulations prescribing low sulfur fuels, a performance-based policy can save up to $260 million for these ships with 80% more emission reductions than required because least-cost options on some individual ships outperform standards. Optimal simulation of a market-based SO2 control policy for approximately 4,700 U.S. foreign commerce ships traveling in the SECAs in 2002 shows that SECA emissions control targets can be achieved by scrubbing exhaust gas of one out of ten ships with annual savings up to $480 million over performance-based policy. A market-based policy could save the fleet approximately $63 million annually under our best-estimate scenario. Spatial evaluation of ship emissions reductions shows that market-based instruments can reduce more SO2 closer to land while being more cost-effective for the fleet. Results suggest that combining performance requirements with market-based instruments can most effectively control SO2 emissions from ships.

  6. GHG emissions inventory for on-road transportation in the town of Sassari (Sardinia, Italy)

    NASA Astrophysics Data System (ADS)

    Sanna, Laura; Ferrara, Roberto; Zara, Pierpaolo; Duce, Pierpaolo

    2016-04-01

    The IPCC Fifth Assessment Report (AR5) accounts an increase of the total annual anthropogenic GHG emissions between 2000 and 2010 that directly came from the transport sector. In 2010, 14% of GHG emissions were released by transport and fossil-fuel-related CO2 emissions reached about 32 GtCO2 per year. The report also considers adaptation and mitigation as complementary strategies for reducing the risks of climate change for sustainable development of urban areas. This paper describes the on-road traffic emission estimated in the framework of a Sardinian regional project [1] for the town of Sassari (Sardinia, Italy), one of the Sardinian areas where the fuel consumption for on-road transportation purposes is higher [2]. The GHG emissions have been accounted (a) by a calculation-based methodology founded on a linear relationship between source activity and emission, and (b) by the COPERT IV methodology through the EMITRA (EMIssions from road TRAnsport) software tool [3]. Inventory data for annual fossil fuel consumption associated with on-road transportation (diesel, gasoline, gas) have been collected through the Dogane service, the ATP and ARST public transport services and vehicle fleet data are available from the Public Vehicle Database (PRA), using 2010 as baseline year. During this period, the estimated CO2 emissions accounts for more than 180,000 tCO2. The calculation of emissions due to on-road transport quantitatively estimates CO2 and other GHG emissions and represents a useful baseline to identify possible adaptation and mitigation strategies to face the climate change risks at municipal level. Acknowledgements This research was funded by the Sardinian Regional Project "Development, functional checking and setup of an integrated system for the quantification of CO2 net exchange and for the evaluation of mitigation strategies at urban and territorial scale", (Legge Regionale 7 agosto 2007, No. 7). References [1] Sanna L., Ferrara R., Zara P. & Duce P. (2014

  7. Does gasification and biochar amendment provide a viable solution to balance greenhouse gas emissions, energy requirements and orchard residue management?

    NASA Astrophysics Data System (ADS)

    Pereira, Engil; Suddick, Emma; Six, Johan

    2015-04-01

    By converting biomass residue to biochar, we can generate power cleanly and sequester carbon resulting in overall greenhouse gas (GHG) savings when compared to typical fossil fuel burning and waste disposal. This on-farm research study provides a long-term and high frequency assessment of GHG emissions from biochar amended-soils in an organic walnut orchard in the Central Valley of California, USA. We also estimated the GHG offsets from the conversion of walnut residue into energy through gasification at the on-site walnut processing plant. Soil fluxes of carbon dioxide (CO2) and nitrous oxide (N2O) were monitored over 29 months in a 3.6 ha walnut orchard following management and precipitation events. We compared four treatments: control, biochar, compost, and biochar combined with compost. Events involving resource inputs such as fertilization or cover crop mowing induced the largest N2O peaks with average 0.13 kg N2O-N ha-1 day-1, while precipitation events produced the highest CO2 fluxes in average 0.124 Mg CO2-C ha-1 day-1. Biochar alone decreased N2O fluxes in two out of 23 measured events, however, not with enough significant magnitude to modify annual or seasonal totals. This indicates that biochar-induced decreases in N2O fluxes may occasionally occur without significant changes in total emissions. Additionally, biochar alone or in combination with compost did not alter annual or seasonal cumulative CO2 emissions. For this particular study, the conversion of orchard waste into energy and C sequestration through biochar amendment offset 100.3 Mg CO2-Ceq year-1. Thus, given that biochar did not alter cumulative GHG emissions from soils, we conclude that, in the scenario of this study, the use of biochar as a strategy to decrease farm-level GHG emissions is obtained through the gasification of orchard residue into energy and through biochar C sequestration, and not as a tool to decrease soil CO2 and N2O emissions.

  8. Emission of greenhouse gases from waste incineration in Korea.

    PubMed

    Hwang, Kum-Lok; Choi, Sang-Min; Kim, Moon-Kyung; Heo, Jong-Bae; Zoh, Kyung-Duk

    2017-07-01

    Greenhouse gas (GHG) emission factors previously reported from various waste incineration plants have shown significant variations according to country-specific, plant-specific, and operational conditions. The purpose of this study is to estimate GHG emissions and emission factors at nine incineration facilities in Korea by measuring the GHG concentrations in the flue gas samples. The selected incineration plants had different operation systems (i.e., stoker, fluidized bed, moving grate, rotary kiln, and kiln & stoker), and different nitrogen oxide (NO x ) removal systems (i.e., selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR)) to treat municipal solid waste (MSW), commercial solid waste (CSW), and specified waste (SW). The total mean emission factors for A and B facilities for MSW incineration were found to be 134 ± 17 kg CO 2 ton -1 , 88 ± 36 g CH 4 ton -1 , and 69 ± 16 g N 2 O ton -1 , while those for CSW incineration were 22.56 g CH 4 ton -1 and 259.76 g N 2 O ton -1 , and for SW incineration emission factors were 2959 kg CO 2 ton -1 , 43.44 g CH 4 ton -1 and 401.21 g N 2 O ton -1 , respectively. Total emissions calculated using annual incineration for MSW were 3587 ton CO 2 -eq yr -1 for A facility and 11,082 ton CO 2 -eq yr -1 for B facility, while those of IPCC default values were 13,167 ton CO 2- eq yr -1 for A facility and 32,916 ton CO 2- eq yr -1 , indicating that the emissions of IPCC default values were estimated higher than those of the plant-specific emission factors. The emission of CSW for C facility was 1403 ton CO 2 -eq yr -1 , while those of SW for D to I facilities was 28,830 ton CO 2 -eq yr -1 . The sensitivity analysis using a Monte Carlo simulation for GHG emission factors in MSW showed that the GHG concentrations have a greater impact than the incineration amount and flow rate of flue gas. For MSW incineration plants using the same stoker type in operation, the estimated emissions and

  9. Lake Roosevelt Fisheries Evaluation Program; Limnological and Fisheries Monitoring, Annual Report 2000.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Chuck; Scofield, Ben; Pavlik, Deanne

    2003-03-01

    A slightly dryer than normal year yielded flows in Lake Roosevelt that were essentially equal to the past ten year average. Annual mean inflow and outflow were 3,160.3 m3/s and 3,063.4 m3/s respectively. Mean reservoir elevation was 387.2 m above sea level at the Grand Coulee Dam forebay. The forebay elevation was below the mean elevation for a total of 168 days. During the first half of the 2000 forebay elevation changed at a rate of 0.121 m/d and during the last half changed at a rate of 0.208 m/d. The higher rate of elevation change earlier in the yearmore » is due to the drawdown to accommodate spring runoff. Mean annual water retention time was 40 days. Annual mean total dissolved gas was 108%. Total dissolved gas was greatest at upriver locations (110% = US/Canada Border annual mean) and decreased moving toward Grand Coulee Dam (106% = Grand Coulee Dam Forebay annual mean). Total dissolved gas was greatest in May (122% reservoir wide monthly mean). Gas bubble trauma was observed in 16 fish primarily largescale suckers and was low in severity. Reservoir wide mean temperatures were greatest in August (19.5 C) and lowest in January (5.5 C). The Spokane River and Sanpoil River Arms experienced higher temperatures than the mainstem reservoir. Brief stratification was observed at the Sanpoil River shore location in July. Warm water temperatures in the Spokane Arm contributed to low dissolved oxygen concentrations in August (2.6 mg/L at 33 m). However, decomposition of summer algal biomass was likely the main cause of depressed dissolved oxygen concentrations. Otherwise, dissolved oxygen profiles were relatively uniform throughout the water column across other sampling locations. Annual mean Secchi depth throughout the reservoir was 5.7 m. Nutrient concentrations were generally low, however, annual mean total phosphorus (0.016 mg/L) was in the mesotrophic range. Annual mean total nitrogen was in the meso-oligotrophic range. Total nitrogen to total phosphorus

  10. Revised methane emissions factors and spatially distributed annual carbon fluxes for global livestock

    USDA-ARS?s Scientific Manuscript database

    Livestock play an important role in carbon cycling through consumption of biomass and emissions of methane. Recent research suggests that existing bottom-up inventories of livestock methane emissions in the U.S., such as those made using 2006 IPCC Tier 1 livestock emissions factors, are too low. Thi...

  11. Revised methane emissions factors and spatially distributed annual carbon fluxes for global livestock

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolf, Julie; Asrar, Ghassem R.; West, Tristram O.

    Background: Livestock play an important role in carbon cycling through consumption of biomass and emissions of methane. Recent research suggests that existing bottom-up inventories of livestock methane emissions in the US, such as those made using 2006 IPCC Tier 1 livestock emissions factors, are too low. This may be due to outdated information used to develop these emissions factors. In this study, we update information for cattle and swine by region, based on reported recent changes in animal body mass, feed quality and quantity, milk productivity, and management of animals and manure. We then use this updated information to calculatemore » new livestock methane emissions factors for enteric fermentation in cattle, and for manure management in cattle and swine.« less

  12. Sulfur deposition simulations over China, Japan, and Korea: a model intercomparison study for abating sulfur emission.

    PubMed

    Kim, Cheol-Hee; Chang, Lim-Seok; Meng, Fan; Kajino, Mizuo; Ueda, Hiromasa; Zhang, Yuanhang; Son, Hye-Young; Lee, Jong-Jae; He, Youjiang; Xu, Jun; Sato, Keiichi; Sakurai, Tatsuya; Han, Zhiwei; Duan, Lei; Kim, Jeong-Soo; Lee, Suk-Jo; Song, Chang-Keun; Ban, Soo-Jin; Shim, Shang-Gyoo; Sunwoo, Young; Lee, Tae-Young

    2012-11-01

    In response to increasing trends in sulfur deposition in Northeast Asia, three countries in the region (China, Japan, and Korea) agreed to devise abatement strategies. The concepts of critical loads and source-receptor (S-R) relationships provide guidance for formulating such strategies. Based on the Long-range Transboundary Air Pollutants in Northeast Asia (LTP) project, this study analyzes sulfur deposition data in order to optimize acidic loads over the three countries. The three groups involved in this study carried out a full year (2002) of sulfur deposition modeling over the geographic region spanning the three countries, using three air quality models: MM5-CMAQ, MM5-RAQM, and RAMS-CADM, employed by Chinese, Japanese, and Korean modeling groups, respectively. Each model employed its own meteorological numerical model and model parameters. Only the emission rates for SO(2) and NO(x) obtained from the LTP project were the common parameter used in the three models. Three models revealed some bias from dry to wet deposition, particularly the latter because of the bias in annual precipitation. This finding points to the need for further sensitivity tests of the wet removal rates in association with underlying cloud-precipitation physics and parameterizations. Despite this bias, the annual total (dry plus wet) sulfur deposition predicted by the models were surprisingly very similar. The ensemble average annual total deposition was 7,203.6 ± 370 kt S with a minimal mean fractional error (MFE) of 8.95 ± 5.24 % and a pattern correlation (PC) of 0.89-0.93 between the models. This exercise revealed that despite rather poor error scores in comparison with observations, these consistent total deposition values across the three models, based on LTP group's input data assumptions, suggest a plausible S-R relationship that can be applied to the next task of designing cost-effective emission abatement strategies.

  13. A Climatology of dust emission in northern Africa using surface observations from 1984-2012

    NASA Astrophysics Data System (ADS)

    Cowie, Sophie; Knippertz, Peter; Marsham, John

    2014-05-01

    The huge quantity of mineral dust emitted annually from northern Africa makes this area crucial to the global dust cycle. Once in the atmosphere, dust aerosols have a significant impact on the global radiation budget, clouds, the carbon cycle and can even act as a fertilizer to rain forests in South America. Current model estimates of dust production from northern Africa are uncertain. At the heart of this problem is insufficient understanding of key dust emitting processes such as haboobs (cold pools generated through evaporation of convective precipitation), low-level jets (LLJs) and dry convection (dust devils and dust plumes). Scarce observations in this region, in particular in the Sahara, make model evaluation difficult. This work uses long-term surface observations from 70 stations situated in the Sahara and Sahel to explore the diurnal, seasonal and geographical variations in dust emission events and thresholds. Quality flags are applied to each station to indicate a day-time bias or gaps in the time period 1984-2012. The frequency of dust emission (FDE) is calculated using the present weather codes (WW) of SYNOP reports, where WW = 07,08,09,30-35 and 98. Thresholds are investigated by estimating the wind speeds for which there is a 25%, 50% and 75% probability of dust emission. The 50% threshold is used to calculate strong wind frequency (SWF) and the diagnostic parameter dust uplift potential (DUP); a thresholded cubic function of wind-speed which quantifies the dust generating power of winds. Stations are grouped into 6 areas (North Algeria, Central Sahara, Egypt, West Sahel, Central Sahel and Sudan) for more in-depth analysis of these parameters. Spatially, thresholds are highest in northern Algeria and lowest in the Sahel around the latitude band 16N-21N. Annual mean FDE is anti-correlated with the threshold, showing the importance of spatial variations in thresholds for mean dust emission. The annual cycles of FDE and SWF for the 6 grouped areas are

  14. General circulation model response to production-limited fossil fuel emission estimates.

    NASA Astrophysics Data System (ADS)

    Bowman, K. W.; Rutledge, D.; Miller, C.

    2008-12-01

    The differences in emissions scenarios used to drive IPCC climate projections are the largest sources of uncertainty in future temperature predictions. These estimates are critically dependent on oil, gas, and coal production where the extremal variations in fossil fuel production used in these scenarios is roughly 10:1 after 2100. The development of emission scenarios based on production-limited fossil fuel estimates, i.e., total fossil fuel reserves can be reliably predicted from cumulative production, offers the opportunity to significantly reduce this uncertainty. We present preliminary results of the response of the NASA GISS atmospheric general circulation model to input forcings constrained by production-limited cumulative future fossil-fuel CO2 emissions estimates that reach roughly 500 GtC by 2100, which is significantly lower than any of the IPCC emission scenarios. For climate projections performed from 1958 through 2400 and a climate sensitivity of 5C/2xCO2, the change in globally averaged annual mean temperature relative to fixed CO2 does not exceed 3C with most changes occurring at high latitudes. We find that from 2100-2400 other input forcings such as increased in N2O play an important role in maintaining increase surface temperatures.

  15. Military, Charter, Unreported Domestic Traffic and General Aviation 1976, 1984, 1992, and 2015 Emission Scenarios

    NASA Technical Reports Server (NTRS)

    Mortlock, Alan; VanAlstyne, Richard

    1998-01-01

    The report describes development of databases estimating aircraft engine exhaust emissions for the years 1976 and 1984 from global operations of Military, Charter, historic Soviet and Chinese, Unreported Domestic traffic, and General Aviation (GA). These databases were developed under the National Aeronautics and Space Administration's (NASA) Advanced Subsonic Assessment (AST). McDonnell Douglas Corporation's (MDC), now part of the Boeing Company has previously estimated engine exhaust emissions' databases for the baseline year of 1992 and a 2015 forecast year scenario. Since their original creation, (Ward, 1994 and Metwally, 1995) revised technology algorithms have been developed. Additionally, GA databases have been created and all past NIDC emission inventories have been updated to reflect the new technology algorithms. Revised data (Baughcum, 1996 and Baughcum, 1997) for the scheduled inventories have been used in this report to provide a comparison of the total aviation emission forecasts from various components. Global results of two historic years (1976 and 1984), a baseline year (1992) and a forecast year (2015) are presented. Since engine emissions are directly related to fuel usage, an overview of individual aviation annual global fuel use for each inventory component is also given in this report.

  16. Seasonal climate change patterns due to cumulative CO 2 emissions

    DOE PAGES

    Partanen, Antti-Ilari; Leduc, Martin; Matthews, H. Damon

    2017-06-28

    Cumulative CO 2 emissions are near linearly related to both global and regional changes in annual-mean surface temperature. These relationships are known as the transient climate response to cumulative CO 2 emissions (TCRE) and the regional TCRE (RTCRE), and have been shown to remain approximately constant over a wide range of cumulative emissions. Here, we assessed how well this relationship holds for seasonal patterns of temperature change, as well as for annual-mean and seasonal precipitation patterns. We analyzed an idealized scenario with CO 2 concentration growing at an annual rate of 1% using data from 12 Earth system models frommore » the Coupled Model Intercomparison Project Phase 5 (CMIP5). Seasonal RTCRE values for temperature varied considerably, with the highest seasonal variation evident in the Arctic, where RTCRE was about 5.5 °C per Tt C for boreal winter and about 2.0 °C per Tt C for boreal summer. Also the precipitation response in the Arctic during boreal winter was stronger than during other seasons. We found that emission-normalized seasonal patterns of temperature change were relatively robust with respect to time, though they were sub-linear with respect to emissions particularly near the Arctic. Moreover, RTCRE patterns for precipitation could not be quantified robustly due to the large internal variability of precipitation. Here, our results suggest that cumulative CO 2 emissions are a useful metric to predict regional and seasonal changes in precipitation and temperature. This extension of the TCRE framework to seasonal and regional climate change is helpful for communicating the link between emissions and climate change to policy-makers and the general public, and is well-suited for impact studies that could make use of estimated regional-scale climate changes that are consistent with the carbon budgets associated with global temperature targets.« less

  17. Seasonal climate change patterns due to cumulative CO2 emissions

    NASA Astrophysics Data System (ADS)

    Partanen, Antti-Ilari; Leduc, Martin; Damon Matthews, H.

    2017-07-01

    Cumulative CO2 emissions are near linearly related to both global and regional changes in annual-mean surface temperature. These relationships are known as the transient climate response to cumulative CO2 emissions (TCRE) and the regional TCRE (RTCRE), and have been shown to remain approximately constant over a wide range of cumulative emissions. Here, we assessed how well this relationship holds for seasonal patterns of temperature change, as well as for annual-mean and seasonal precipitation patterns. We analyzed an idealized scenario with CO2 concentration growing at an annual rate of 1% using data from 12 Earth system models from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Seasonal RTCRE values for temperature varied considerably, with the highest seasonal variation evident in the Arctic, where RTCRE was about 5.5 °C per Tt C for boreal winter and about 2.0 °C per Tt C for boreal summer. Also the precipitation response in the Arctic during boreal winter was stronger than during other seasons. We found that emission-normalized seasonal patterns of temperature change were relatively robust with respect to time, though they were sub-linear with respect to emissions particularly near the Arctic. Moreover, RTCRE patterns for precipitation could not be quantified robustly due to the large internal variability of precipitation. Our results suggest that cumulative CO2 emissions are a useful metric to predict regional and seasonal changes in precipitation and temperature. This extension of the TCRE framework to seasonal and regional climate change is helpful for communicating the link between emissions and climate change to policy-makers and the general public, and is well-suited for impact studies that could make use of estimated regional-scale climate changes that are consistent with the carbon budgets associated with global temperature targets.

  18. Seasonal climate change patterns due to cumulative CO 2 emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Partanen, Antti-Ilari; Leduc, Martin; Matthews, H. Damon

    Cumulative CO 2 emissions are near linearly related to both global and regional changes in annual-mean surface temperature. These relationships are known as the transient climate response to cumulative CO 2 emissions (TCRE) and the regional TCRE (RTCRE), and have been shown to remain approximately constant over a wide range of cumulative emissions. Here, we assessed how well this relationship holds for seasonal patterns of temperature change, as well as for annual-mean and seasonal precipitation patterns. We analyzed an idealized scenario with CO 2 concentration growing at an annual rate of 1% using data from 12 Earth system models frommore » the Coupled Model Intercomparison Project Phase 5 (CMIP5). Seasonal RTCRE values for temperature varied considerably, with the highest seasonal variation evident in the Arctic, where RTCRE was about 5.5 °C per Tt C for boreal winter and about 2.0 °C per Tt C for boreal summer. Also the precipitation response in the Arctic during boreal winter was stronger than during other seasons. We found that emission-normalized seasonal patterns of temperature change were relatively robust with respect to time, though they were sub-linear with respect to emissions particularly near the Arctic. Moreover, RTCRE patterns for precipitation could not be quantified robustly due to the large internal variability of precipitation. Here, our results suggest that cumulative CO 2 emissions are a useful metric to predict regional and seasonal changes in precipitation and temperature. This extension of the TCRE framework to seasonal and regional climate change is helpful for communicating the link between emissions and climate change to policy-makers and the general public, and is well-suited for impact studies that could make use of estimated regional-scale climate changes that are consistent with the carbon budgets associated with global temperature targets.« less

  19. Battery condenser system total particulate emission factors and rates for cotton gins

    USDA-ARS?s Scientific Manuscript database

    This manuscript is part of a series of manuscripts that characterize cotton gin emissions from the standpoint of stack sampling. The impetus behind this project was the urgent need to collect additional cotton gin emissions data to address current regulatory issues. A key component of this study was...

  20. Underlying Ecosystem Methane Emissions Exceed Cattle-Derived Methane from Subtropical Lowland Pastures.

    NASA Astrophysics Data System (ADS)

    Chamberlain, S. D.; Sparks, J. P.

    2014-12-01

    Grazing cattle are a major methane (CH4) source from pasture ecosystems, however the underlying landscape is a potentially significant CH4 source that has received far less attention. Ecosystem surface emissions of CH4 are poorly quantified, vary widely across time and space, and are easily underestimated if emission hotspots or episodic fluxes are overlooked. We used static chambers, eddy covariance, and mobile cavity-ringdown spectrometry surveys to quantify spatially and temporally variable CH4 emissions from subtropical lowland pastures. We conclude emissions from soil and standing water are the dominant CH4 source, and cattle were responsible for only 13% of annual CH4emissions. The ecosystem emit 33.8 ± 2.2 g CH4 m-2 yr-1, however surface CH4 emissions were highly variable in both time and space. Seasonal flooding of pastures and low-lying landforms (canals, ditches, wetlands) drove high magnitude CH4 emissions. We observed large CH4 emissions from wetlands and, to a lesser extent, the entire landscape during the wet season. In contrast, during the dry season there was no appreciable CH4 accumulation in pastures when cattle were not present, and canals, which comprise 1.7% of the total land area, were responsible 97.7 % of dry season emissions. Ecosystem CH4 fluxes, measured by eddy covariance, varied seasonally and positively correlated to soil and air temperature, topsoil water content, and water table depth. Our work is the first to use mobile spectrometers to map biogenic CH4 emissions at the landscape scale, and demonstrates that soils and water are a strong pasture CH4 source that must be considered in addition to cattle emissions.

  1. Spatial and temporal variability of greenhouse gas emissions from a small and shallow temperate lake

    NASA Astrophysics Data System (ADS)

    Praetzel, Leandra; Schmiedeskamp, Marcel; Broder, Tanja; Hüttemann, Caroline; Jansen, Laura; Metzelder, Ulrike; Wallis, Ronya; Knorr, Klaus-Holger; Blodau, Christian

    2017-04-01

    Small inland waters (< 1 km2) have recently been discovered as significant sources and sinks in the global carbon cycle because they cover larger areas than previously assumed and exhibit a higher metabolic activity than larger lakes. They are further expected to be susceptible to changing climate conditions. So far, little is known about the spatial and temporal variability of carbon dioxide (CO2) and methane (CH4) emissions and in-lake dynamics of CH4 production and oxidation in small, epilimnetic lakes in the temperate zone. Of particular interest is the potential occurrence of "hot spots" and "hot moments" that could contribute significantly to total emissions. To address this knowledge gap, we determined CO2 and CH4 emissions and dynamics to identify their controlling environmental factors in a polymictic small (1.4 ha) and shallow (max. depth approx. 1.5 m) crater lake ("Windsborn") in the Eifel uplands in south-west Germany. As Lake Windsborn has a small catchment area (8 ha) and no surficial inflows, it serves well as a model system for the identification of factors and processes controlling emissions. In 2015, 2016 and 2017 we measured CO2 and CH4 gas fluxes with different techniques across the sediment/water and water/atmosphere interface. Atmospheric exchange was measured using mini-chambers equipped with CO2 sensors and with an infra-red greenhouse gas analyzer for high temporal resolution flux measurements. Ebullition of CH4 was quantified with funnel traps. Sediment properties were examined using pore-water peepers. All measurements were carried out along a transect covering both littoral and central parts of the lake. Moreover, a weather station on a floating platform in the center of the lake recorded meteorological data as well as CO2 concentration in different depths of the water column. So far, Lake Windsborn seems to be a source for both CO2 and CH4 on an annual scale. CO2 emissions generally increased from spring to summer. Even though CO2

  2. Methane and nitrous oxide emissions from livestock agriculture in 16 local administrative districts of Korea.

    PubMed

    Ji, Eun Sook; Park, Kyu-Hyun

    2012-12-01

    This study was conducted to evaluate methane (CH4) and nitrous oxide (N2O) emissions from livestock agriculture in 16 local administrative districts of Korea from 1990 to 2030. National Inventory Report used 3 yr averaged livestock population but this study used 1 yr livestock population to find yearly emission fluctuations. Extrapolation of the livestock population from 1990 to 2009 was used to forecast future livestock population from 2010 to 2030. Past (yr 1990 to 2009) and forecasted (yr 2010 to 2030) averaged enteric CH4 emissions and CH4 and N2O emissions from manure treatment were estimated. In the section of enteric fermentation, forecasted average CH4 emissions from 16 local administrative districts were estimated to increase by 4%-114% compared to that of the past except for Daejeon (-63%), Seoul (-36%) and Gyeonggi (-7%). As for manure treatment, forecasted average CH4 emissions from the 16 local administrative districts were estimated to increase by 3%-124% compared to past average except for Daejeon (-77%), Busan (-60%), Gwangju (-48%) and Seoul (-8%). For manure treatment, forecasted average N2O emissions from the 16 local administrative districts were estimated to increase by 10%-153% compared to past average CH4 emissions except for Daejeon (-60%), Seoul (-4.0%), and Gwangju (-0.2%). With the carbon dioxide equivalent emissions (CO2-Eq), forecasted average CO2-Eq from the 16 local administrative districts were estimated to increase by 31%-120% compared to past average CH4 emissions except Daejeon (-65%), Seoul (-24%), Busan (-18%), Gwangju (-8%) and Gyeonggi (-1%). The decreased CO2-Eq from 5 local administrative districts was only 34 kt, which was insignificantly small compared to increase of 2,809 kt from other 11 local administrative districts. Annual growth rates of enteric CH4 emissions, CH4 and N2O emissions from manure management in Korea from 1990 to 2009 were 1.7%, 2.6%, and 3.2%, respectively. The annual growth rate of total CO2-Eq was 2

  3. 40 CFR 60.1740 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous emission monitoring systems? 60.1740 Section 60.1740 Protection of Environment ENVIRONMENTAL... evaluating continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems no more than 13 months after the previous evaluation was conducted. (b) Evaluate your...

  4. 40 CFR 62.15195 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... continuous emission monitoring systems? 62.15195 Section 62.15195 Protection of Environment ENVIRONMENTAL... evaluating continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems no more than 13 months after the previous evaluation was conducted. (b) Evaluate your...

  5. 40 CFR 62.15195 - What is my schedule for evaluating continuous emission monitoring systems?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... continuous emission monitoring systems? 62.15195 Section 62.15195 Protection of Environment ENVIRONMENTAL... evaluating continuous emission monitoring systems? (a) Conduct annual evaluations of your continuous emission monitoring systems no more than 13 months after the previous evaluation was conducted. (b) Evaluate your...

  6. 47 CFR 101.1417 - Annual report.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Annual report. Each MVDDS licensee shall file with the Broadband Division of the Wireless... the calendar year; (2) The total hours of transmission service rendered during the calendar year to all subscribers; (3) The total hours of transmission service rendered during the calendar year...

  7. Forest carbon emissions from cropland expansion in the Brazilian Cerrado biome

    NASA Astrophysics Data System (ADS)

    Noojipady, Praveen; Morton, C. Douglas; Macedo, N. Marcia; Victoria, C. Daniel; Huang, Chengquan; Gibbs, K. Holly; Edson Bolfe, L.

    2017-02-01

    Land use, land use change, and forestry accounted for two-thirds of Brazil’s greenhouse gas emissions profile in 2005. Amazon deforestation has declined by more than 80% over the past decade, yet Brazil’s forests extend beyond the Amazon biome. Rapid expansion of cropland in the neighboring Cerrado biome has the potential to undermine climate mitigation efforts if emissions from dry forest and woodland conversion negate some of the benefits of avoided Amazon deforestation. Here, we used satellite data on cropland expansion, forest cover, and vegetation carbon stocks to estimate annual gross forest carbon emissions from cropland expansion in the Cerrado biome. Nearly half of the Cerrado met Brazil’s definition of forest cover in 2000 (≥0.5 ha with ≥10% canopy cover). In areas of established crop production, conversion of both forest and non-forest Cerrado formations for cropland declined during 2003-2013. However, forest carbon emissions from cropland expansion increased over the past decade in Matopiba, a new frontier of agricultural production that includes portions of Maranhão, Tocantins, Piauí, and Bahia states. Gross carbon emissions from cropland expansion in the Cerrado averaged 16.28 Tg C yr-1 between 2003 and 2013, with forest-to-cropland conversion accounting for 29% of emissions. The fraction of forest carbon emissions from Matopiba was much higher; between 2010-2013, large-scale cropland conversion in Matopiba contributed 45% of total Cerrado forest carbon emissions. Carbon emissions from Cerrado-to-cropland transitions offset 5%-7% of the avoided emissions from reduced Amazon deforestation rates during 2011-2013. Comprehensive national estimates of forest carbon fluxes, including all biomes, are critical to detect cross-biome leakage within countries and achieve climate mitigation targets to reduce emissions from land use, land use change, and forestry.

  8. [Agro-ecosystem ammonia emission in Sichuan-Chongqing region].

    PubMed

    Li, Fu-chun; Han, Shen-hui; Yang, Jun; Zhang, Xu; Li, Ru-yan; Wei, Yuan-song; Fan, Mao-hong

    2009-10-15

    Ammonia (NH3) emission from agro-ecosystem in the Sichuan-Chongqing region during 1990-2004, was estimated by the regional nitrogen cycling model IAP-N. The county level agricultural activities data were used, and Sichuan-Chongqing region was divided into four sub-areas by the geographical characteristics , environment and local climatic conditions and administrative division. The results showed that average annual ammonia emissions (in nitrogen gauge) in 1990-1994, 1995-1999, 2000-2004 were 626.7, 670.5 and 698.8 Gg x a(-1) respectively. The ammonia emission appeared increasing trend, whereas, the contribution of various ammonia sources presented little change. For instance, in 2000-2004, the contributions of NH3 emission from fertilized cropland, manure management system and field residues burning to the total ammonia emission of agro-ecosystem in the Sichuan-Chongqing region were 53%, 46% and 1%, equals to 374.9, 318.2 and 5.6 Gg x a(-1) respectively. But the contributions were variable in different regions. Ammonia emission was primarily induced by fertilized cropland in Chengdu plain and Chongqing hilly area, whereas, in northwest sub-region of Sichuan province was manure management system. The geographical distribution of ammonia emission from agro-ecosystem in the Sichuan-Chongqing region was generally "east high and west low". Ammonia emissions in sub-regions of Chongqing hilly area, Chengdu plain, southwest and northwest sub-regions were 165.6, 408.8, 85.9 and 38.8 Gg x a(-1), respectively, during 2000-2004. At the same time, ammonia density were 20 and 28 kg x (hm2 x a)(-1) in sub-regions of the Chongqing hilly area and the Chengdu plain, whereas, 9.1 and 1.6 kg x (hm2 x a)(-1) in southwest and northwest sub-regions, respectively. The results will provide a scientific basis for making fertilizer effectively applied and mitigate NH3 and GHG emissions from agro-ecosystem of Sichuan-Chongqing region.

  9. A predictive analysis of CO2 emissions, environmental policy stringency, and economic growth in China.

    PubMed

    Ahmed, Khalid; Ahmed, Sidrah

    2018-03-28

    This study takes environmental policy stringency and economic activity as the controlling variables and forecasts the CO 2 emissions in China up to 2022. In doing so, an application of corrected grey model with convolution is used over the annual time series data between 1990 and 2012. The simulation results show that (1) between 2012 and 2022, CO 2 emissions in China is expected to increase at an average rate of 17.46% annually, raising the emissions intensity from 7.04 in 2012 to 25.461 metric tons per capita by 2022; (2) stringent environmental policies reduce CO 2 emissions-whereas, GDP tends to increase the emissions intensity in China; (3) stringent environmental policies are found to have a negative impact on GDP in China. Based on the empirical findings, the study also provides some policy suggestions to reduce emissions intensity in China.

  10. AGRICULTURAL AMMONIA EMISSIONS AND AMMONIUM DEPOSITION IN THE SOUTHEAST UNITED STATES

    EPA Science Inventory

    The paper gives an estimate of county-scale annual ammonia (NH3) emissions in eight Southeastern States for the year 1997, using emission factors and activity data for all domestic livestock and fertilizer sources. A geographical distribution of the data yields local areas (1000...

  11. Emission projections for the U.S. Environmental Protection Agency Section 812 second prospective Clean Air Act cost/benefit analysis.

    PubMed

    Wilson, James H; Mullen, Maureen A; Bollman, Andrew D; Thesing, Kirstin B; Salhotra, Manish; Divita, Frank; Neumann, James E; Price, Jason C; DeMocker, James

    2008-05-01

    Section 812 of the Clean Air Act Amendments (CAAA) of 1990 requires the U.S. Environmental Protection Agency (EPA) to perform periodic, comprehensive analyses of the total costs and total benefits of programs implemented pursuant to the CAAA. The first prospective analysis was completed in 1999. The second prospective analysis was initiated during 2005. The first step in the second prospective analysis was the development of base and projection year emission estimates that will be used to generate benefit estimates of CAAA programs. This paper describes the analysis, methods, and results of the recently completed emission projections. There are several unique features of this analysis. One is the use of consistent economic assumptions from the Department of Energy's Annual Energy Outlook 2005 (AEO 2005) projections as the basis for estimating 2010 and 2020 emissions for all sectors. Another is the analysis of the different emissions paths for both with and without CAAA scenarios. Other features of this analysis include being the first EPA analysis that uses the 2002 National Emission Inventory files as the basis for making 48-state emission projections, incorporating control factor files from the Regional Planning Organizations (RPOs) that had completed emission projections at the time the analysis was performed, and modeling the emission benefits of the expected adoption of measures to meet the 8-hr ozone National Ambient Air Quality Standards (NAAQS), the Clean Air Visibility Rule, and the PM2.5 NAAQS. This analysis shows that the 1990 CAAA have produced significant reductions in criteria pollutant emissions since 1990 and that these emission reductions are expected to continue through 2020. CAAA provisions have reduced volatile organic compound (VOC) emissions by approximately 7 million t/yr by 2000, and are estimated to produce associated VOC emission reductions of 16.7 million t by 2020. Total oxides of nitrogen (NO(x)) emission reductions attributable to the

  12. Total Particle Number Emissions from Modern Diesel, Natural Gas, and Hybrid Heavy-Duty Vehicles During On-Road Operation.

    PubMed

    Wang, Tianyang; Quiros, David C; Thiruvengadam, Arvind; Pradhan, Saroj; Hu, Shaohua; Huai, Tao; Lee, Eon S; Zhu, Yifang

    2017-06-20

    Particle emissions from heavy-duty vehicles (HDVs) have significant environmental and public health impacts. This study measured total particle number emission factors (PNEFs) from six newly certified HDVs powered by diesel and compressed natural gas totaling over 6800 miles of on-road operation in California. Distance-, fuel- and work-based PNEFs were calculated for each vehicle. Distance-based PNEFs of vehicles equipped with original equipment manufacturer (OEM) diesel particulate filters (DPFs) in this study have decreased by 355-3200 times compared to a previous retrofit DPF dynamometer study. Fuel-based PNEFs were consistent with previous studies measuring plume exhaust in the ambient air. Meanwhile, on-road PNEF shows route and technology dependence. For vehicles with OEM DPFs and Selective Catalytic Reduction Systems, PNEFs under highway driving (i.e., 3.34 × 10 12 to 2.29 × 10 13 particles/mile) were larger than those measured on urban and drayage routes (i.e., 5.06 × 10 11 to 1.31 × 10 13 particles/mile). This is likely because a significant amount of nucleation mode volatile particles were formed when the DPF outlet temperature reached a critical value, usually over 310 °C, which was commonly achieved when vehicle speed sustained over 45 mph. A model year 2013 diesel HDV produced approximately 10 times higher PNEFs during DPF active regeneration events than nonactive regeneration.

  13. Coastal vegetation invasion increases greenhouse gas emission from wetland soils but also increases soil carbon accumulation.

    PubMed

    Chen, Yaping; Chen, Guangcheng; Ye, Yong

    2015-09-01

    Soil properties and soil-atmosphere fluxes of CO2, CH4 and N2O from four coastal wetlands were studied throughout the year, namely, native Kandelia obovata mangrove forest vs. exotic Sonneratia apetala mangrove forest, and native Cyperus malaccensis salt marsh vs. exotic Spartina alterniflora salt marsh. Soils of the four wetlands were all net sources of greenhouse gases while Sonneratia forest contributed the most with a total soil-atmosphere CO2-equivalent flux of 137.27 mg CO2 m(-2) h(-1), which is 69.23%, 99.75% and 44.56% higher than that of Kandelia, Cyperus and Spartina, respectively. The high underground biomass and distinctive root structure of Sonneratia might be responsible for its high greenhouse gas emission from the soil. Soils in Spartina marsh emitted the second largest amount of total greenhouse gases but it ranked first in emitting trace greenhouse gases. Annual average CH4 and N2O fluxes from Spartina soil were 13.77 and 1.14 μmol m(-2) h(-1), respectively, which are 2.08 and 1.46 times that of Kandelia, 1.03 and 1.15 times of Sonneratia, and 1.74 and 1.02 times of Cyperus, respectively. Spartina has longer growing season and higher productivity than native marshes which might increase greenhouse gas emission in cold seasons. Exotic wetland soils had higher carbon stock as compared to their respective native counterparts but their carbon stocks were offset by a larger proportion because of their higher greenhouse gas emissions. Annual total soil-atmosphere fluxes of greenhouse gases reduced soil carbon burial benefits by 8.1%, 9.5%, 6.4% and 7.2% for Kandelia, Sonneratia, Cyperus and Spartina, respectively, which narrowed down the gaps in net soil carbon stock between native and exotic wetlands. The results indicated that the invasion of exotic wetland plants might convert local coastal soils into a considerable atmospheric source of greenhouse gases although they at the same time increase soil carbon accumulation. Copyright © 2015. Published

  14. Autonomous taxis could greatly reduce greenhouse-gas emissions of US light-duty vehicles

    NASA Astrophysics Data System (ADS)

    Greenblatt, Jeffery B.; Saxena, Samveg

    2015-09-01

    Autonomous vehicles (AVs) are conveyances to move passengers or freight without human intervention. AVs are potentially disruptive both technologically and socially, with claimed benefits including increased safety, road utilization, driver productivity and energy savings. Here we estimate 2014 and 2030 greenhouse-gas (GHG) emissions and costs of autonomous taxis (ATs), a class of fully autonomous shared AVs likely to gain rapid early market share, through three synergistic effects: (1) future decreases in electricity GHG emissions intensity, (2) smaller vehicle sizes resulting from trip-specific AT deployment, and (3) higher annual vehicle-miles travelled (VMT), increasing high-efficiency (especially battery-electric) vehicle cost-effectiveness. Combined, these factors could result in decreased US per-mile GHG emissions in 2030 per AT deployed of 87-94% below current conventionally driven vehicles (CDVs), and 63-82% below projected 2030 hybrid vehicles, without including other energy-saving benefits of AVs. With these substantial GHG savings, ATs could enable GHG reductions even if total VMT, average speed and vehicle size increased substantially. Oil consumption would also be reduced by nearly 100%.

  15. Temporal and spatial variation characteristics of atmospheric emissions of Cd, Cr, and Pb from coal in China

    NASA Astrophysics Data System (ADS)

    Tian, Hezhong; Cheng, Ke; Wang, Yan; Zhao, Dan; Lu, Long; Jia, Wenxiao; Hao, Jiming

    2012-04-01

    Multiple-year inventory of atmospheric emissions of cadmium (Cd), chromium (Cr), and lead (Pb) from coal burning in China have been established for the period 1980-2008 by using best available emission factors and annual activity data which are specified by different sub-categories of combustion facilities, coal types, and air pollution control devices. Our results show that the total emissions of Cd, Cr, and Pb have rapidly increased from 31.14 t, 1019.07 t, and 2671.73 t in 1980 to 261.52 t, 8593.35 t, and 12 561.77 t in 2008, respectively. The industrial sector ranks as the leading source, contributing ˜88.3%, ˜86.7%, and ˜81.8% of the total Cd, Cr, and Pb emissions, respectively. Remarkably uneven spatial allocation features are observed. The emissions are primarily concentrated in the provinces of the northern and eastern region of China owing to the dramatic difference in coal use by the industrial and power sectors. Monthly temporal emission profiles for different sectors are established by using indexes such as monthly thermal electricity generation, monthly gross industrial output values and monthly average ambient temperature. For the power plants, there are two peaks during cold and hot season while for the industrial sector, emissions are most substantial in the summer and autumn season. Further, uncertainties in the bottom-up inventories are quantified by Monte Carlo simulation, and the overall uncertainties are demonstrated as -16% to 45% for Cd, -13% to 20% for Cr, and -21% to 48% for Pb, respectively. To better understand the emissions of these metals and to adopt effective measures to prevent poisoning, more specific data collection and analysis are necessary.

  16. Determination of GHG and ammonia emissions from stored dairy cattle slurry by using a floating dynamic chamber.

    PubMed

    Minato, Keiko; Kouda, Yasuyuki; Yamakawa, Masaaki; Hara, Satoshi; Tamura, Tadashi; Osada, Takashi

    2013-02-01

    We developed a system for measuring emissions from stored slurry by using a floating dynamic chamber. CH(4) , CO(2) , N(2) O and NH(3) emitted from the storage tank of a dairy cattle farm in eastern Hokkaido were measured during summer 2008 (7/16-8/6), fall 2008 (10/2-10/26), spring 2009 (6/2-6/21) and winter 2009 (3/11). Average daily gas emission rates in summer, fall and spring were, respectively, 54.8, 54.2 and 34.3 g/m(2) for CH(4) ; 602, 274 and 254 g/m(2) for CO(2) ; 55.4, 68.2 and trace mg/m(2) for N(2) O; and 0.55, 0.73 and 0.46 g/m(2) for NH(3) . CH(4) , CO(2) and NH(3) emission rates during the brief measurement period in winter were reduced to 1/4, 1/23 and 1/2, respectively, of summer emission rate levels. All gas emissions showed diurnal fluctuation and were greatest during the daytime, when the ambient temperature rose. CH(4) , NH(3) and CO(2) emissions increased significantly during the daytime, and the daily emission (in grams) of each gas was positively correlated with maximum daily temperature. According to the combined spring, summer and fall measurements, the CH(4) , N(2) O and NH(3) annual emission factors were 1.42% (g CH(4) /g volatile solids), 0.02% (g N(2) O-N/g total N) and 0.43% (g NH(3) -N/g total N), respectively. © 2012 The Authors. Animal Science Journal © 2012 Japanese Society of Animal Science.

  17. Isoprene emissions over Asia 1979-2012: impact of climate and land use changes

    NASA Astrophysics Data System (ADS)

    Stavrakou, T.; Müller, J.-F.; Bauwens, M.; De Smedt, I.; Van Roozendael, M.; Guenther, A.; Wild, M.; Xia, X.

    2013-11-01

    Due to the scarcity of observational constraints and the rapidly changing environment in East and Southeast Asia, isoprene emissions predicted by models are expected to bear substantial uncertainties. The aim of this study is to improve upon the existing bottom-up estimates, and investigate the temporal evolution of the fluxes in Asia over 1979-2012. To this purpose, we calculate the hourly emissions at 0.5° × 0.5° resolution using the MEGAN-MOHYCAN model driven by ECMWF ERA-Interim climatology. This study incorporates (i) changes in land use, including the rapid expansion of oil palms, (ii) meteorological variability according to ERA-Interim, (iii) long-term changes in solar radiation (dimming/brightening) constrained by surface network radiation measurements, and (iv) recent experimental evidence that South Asian tropical forests are much weaker isoprene emitters than previously assumed, and on the other hand, that oil palms hold a strong isoprene emission capacity. These effects lead to a significant lowering (factor of two) in the total isoprene fluxes over the studied domain, and to emission reductions reaching a~factor of 3.5 in Southeast Asia. The bottom-up annual isoprene emissions for 2005 are estimated at 7.0, 4.8, 8.3, 2.9 Tg in China, India, Indonesia and Malaysia, respectively. Changes in temperature and solar radiation are the major drivers of the interannual variability and trend in the emissions. An annual positive flux trend of 0.2% and 0.52% is found in Asia and China, respectively, through the entire period, related to positive trend in temperature and solar radiation. The impact of oil palm expansion in Indonesia and Malaysia is to enhance the trends over that region, e.g. from 1.17% to 1.5% in 1979-2005 in Malaysia. A negative emission trend is derived in India (-0.4%), owing to the negative trend in solar radiation data associated to the strong dimming effect likely due to increasing aerosol loadings. The bottom-up emissions are evaluated

  18. Annual greenhouse gas budget for a bog ecosystem undergoing restoration by rewetting

    NASA Astrophysics Data System (ADS)

    Lee, Sung-Ching; Christen, Andreas; Black, Andrew T.; Johnson, Mark S.; Jassal, Rachhpal S.; Ketler, Rick; Nesic, Zoran; Merkens, Markus

    2017-06-01

    these exchanges were downwelling photosynthetically active radiation and 5 cm soil temperature. It appears that the high water table caused by ditch blocking suppressed Re. With low temperatures in winter, CH4 emissions were more suppressed than Re. Annual net GHG flux from CO2 and CH4 expressed in terms of CO2 equivalents (CO2 eq.) during the study period totalled -22 ± 103.1 g CO2 eq. m-2 yr-1 (net CO2 eq. sink) and 1248 ± 147.6 g CO2 eq. m-2 yr-1 (net CO2 eq. source) by using 100- and 20-year global warming potential values, respectively. Consequently, the ecosystem was almost CO2 eq. neutral during the study period expressed on a 100-year time horizon but was a significant CO2 eq. source on a 20-year time horizon.

  19. The contribution of reactive carbon emissions from vegetation to the carbon balance of terrestrial ecosystems.

    PubMed

    Guenther, Alex

    2002-12-01

    About 2.4 Pg (1 Pg = 10(15) g) of carbon is emitted annually into the atmosphere as reactive compounds and most of it is eventually oxidized to CO2. Isoprene, alpha-pinene, methanol, carbon monoxide and other compounds emitted by terrestrial vegetation contribute about half of the total flux and are estimated to produce about 1 Pg C as CO2 per year. The global average for vegetated surfaces is about 7 g C m(-2) per year but could exceed 100 g m(-2) per year at some tropical locations. The magnitude of these fluxes on both the landscape and global scales are small relative to the total carbon emission or deposition but are significant relative to the net fluxes. Reactive carbon fluxes are very sensitive to landcover and climate change and may vary significantly due to future perturbations. This paper summarizes what is known about reactive carbon emissions from vegetation including the magnitude of local, landscape, and global scale fluxes and their contribution to atmospheric CO2. Reasons for including this term in carbon flux models are presented as well as the potential importance on various spatial scales. Past, present and future reactive carbon emissions are expected to differ significantly and the implications of this are discussed.

  20. Sources of nitrogen and phosphorus emissions to Irish rivers and coastal waters: Estimates from a nutrient load apportionment framework.

    PubMed

    Mockler, Eva M; Deakin, Jenny; Archbold, Marie; Gill, Laurence; Daly, Donal; Bruen, Michael

    2017-12-01

    More than half of surface water bodies in Europe are at less than good ecological status according to Water Framework Directive assessments, and diffuse pollution from agriculture remains a major, but not the only, cause of this poor performance. Agri-environmental policy and land management practices have, in many areas, reduced nutrient emissions to water. However, additional measures may be required in Ireland to further decouple the relationship between agricultural productivity and emissions to water, which is of vital importance given on-going agricultural intensification. The Source Load Apportionment Model (SLAM) framework characterises sources of phosphorus (P) and nitrogen (N) emissions to water at a range of scales from sub-catchment to national. The SLAM synthesises land use and physical characteristics to predict emissions from point (wastewater, industry discharges and septic tank systems) and diffuse sources (agriculture, forestry, etc.). The predicted annual nutrient emissions were assessed against monitoring data for 16 major river catchments covering 50% of the area of Ireland. At national scale, results indicate that total average annual emissions to surface water in Ireland are over 2700tyr -1 of P and 82,000tyr -1 of N. The proportional contributions from individual sources show that the main sources of P are from municipal wastewater treatment plants and agriculture, with wide variations across the country related to local anthropogenic pressures and the hydrogeological setting. Agriculture is the main source of N emissions to water across all regions of Ireland. These policy-relevant results synthesised large amounts of information in order to identify the dominant sources of nutrients at regional and local scales, contributing to the national nutrient risk assessment of Irish water bodies. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.