Sample records for water sunlight nutrients

  1. Energy from Water and Sunlight: Affordable Energy from Water and Sunlight

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2010-01-01

    Broad Funding Opportunity Announcement Project: Sun Catalytix is developing wireless energy-storage devices that convert sunlight and water into renewable fuel. Learning from nature, one such device mimics the ability of a tree leaf to convert sunlight into storable energy. It is comprised of a silicon solar cell coated with catalytic materials, which help speed up the energy conversion process. When this cell is placed in a container of water and exposed to sunlight, it splits the water into bubbles of oxygen and hydrogen. The hydrogen and oxygen can later be recombined to create electricity, when the sun goes down formore » example. The Sun Catalytix device is novel in many ways: it consists primarily of low-cost, earth-abundant materials where other attempts have required more expensive materials like platinum. Its operating conditions also facilitate the use of less costly construction materials, whereas other efforts have required extremely corrosive conditions.« less

  2. One-Step Device Converts Water, Sunlight Into Fuel of the Future

    Science.gov Websites

    great promise that through further research the technology can bring down the cost of using water and One-Step Device Converts Water, Sunlight Into Fuel of the Future For more information contact the world's most abundant resources, water and sunlight, to directly generate hydrogen, a non

  3. Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters

    PubMed Central

    Bacosa, Hernando P.; Liu, Zhanfei; Erdner, Deana L.

    2015-01-01

    Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters. PMID:26648916

  4. Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters.

    PubMed

    Bacosa, Hernando P; Liu, Zhanfei; Erdner, Deana L

    2015-01-01

    Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters.

  5. Sunlight-induced carbon dioxide emissions from inland waters

    NASA Astrophysics Data System (ADS)

    Koehler, Birgit; Landelius, Tomas; Weyhenmeyer, Gesa A.; Machida, Nanako; Tranvik, Lars J.

    2014-07-01

    The emissions of carbon dioxide (CO2) from inland waters are substantial on a global scale. Yet the fundamental question remains open which proportion of these CO2 emissions is induced by sunlight via photochemical mineralization of dissolved organic carbon (DOC), rather than by microbial respiration during DOC decomposition. Also, it is unknown on larger spatial and temporal scales how photochemical mineralization compares to other C fluxes in the inland water C cycle. We combined field and laboratory data with atmospheric radiative transfer modeling to parameterize a photochemical rate model for each day of the year 2009, for 1086 lakes situated between latitudes from 55°N to 69°N in Sweden. The sunlight-induced production of dissolved inorganic carbon (DIC) averaged 3.8 ± 0.04 g C m-2 yr-1, which is a flux comparable in size to the organic carbon burial in the lake sediments. Countrywide, 151 ± 1 kt C yr-1 was produced by photochemical mineralization, corresponding to about 12% of total annual mean CO2 emissions from Swedish lakes. With a median depth of 3.2 m, the lakes were generally deep enough that incoming, photochemically active photons were absorbed in the water column. This resulted in a linear positive relationship between DIC photoproduction and the incoming photon flux, which corresponds to the absorbed photons. Therefore, the slope of the regression line represents the wavelength- and depth-integrated apparent quantum yield of DIC photoproduction. We used this relationship to obtain a first estimate of DIC photoproduction in lakes and reservoirs worldwide. Global DIC photoproduction amounted to 13 and 35 Mt C yr-1 under overcast and clear sky, respectively. Consequently, these directly sunlight-induced CO2 emissions contribute up to about one tenth to the global CO2 emissions from lakes and reservoirs, corroborating that microbial respiration contributes a substantially larger share than formerly thought, and generate annual C fluxes similar in

  6. Degradation of methadone by the sunlight/FC process: Kinetics, radical species participation and influence of the water matrix.

    PubMed

    Hsieh, Ming-Chi; Panchangam, Sri Chandana; Lai, Webber Wei-Po; Lin, Angela Yu-Chen

    2018-06-12

    Free chlorine sunlight photolysis (sunlight/FC) markedly enhances the degradation rate of methadone, a synthetic opioid used medically, over that obtained using sunlight alone. The pseudo-first-order rate constants of methadone degradation under acidic conditions ([methadone] = 0.2 μM, [free chlorine] = 4 μM, and pH = 4) for sunlight/FC and sunlight photolysis are 7.0 ± 1.1 × 10 -2  min -1 and 1.4 ± 0.2 × 10 -2  min -1 , respectively. The improved methadone degradation can be attributed to the production of HO and reactive chlorine species (RCS) during sunlight/FC photolysis. HO and RCS predominantly accounted for degradation during sunlight/FC photolysis under acidic and neutral conditions, while direct photolysis was the major contributor towards methadone degradation in alkaline conditions. The initial pH (pH 4-11) and free chlorine concentration (1-6 μM) significantly influenced the overall degradation efficiency of methadone. The presence of HCO 3 - , Cl - and dissolved organic matters, which may competitively react with HO and RCS, retard the degradation of methadone in synthetic wastewater. Consequently, a 50% lower methadone degradation rate was observed when deionized (DI) water was replaced with tap water. These results emphasize the need to consider different water matrices when applying sunlight/FC photolysis for water treatment. Copyright © 2018 Elsevier Ltd. All rights reserved.

  7. Photolytic dehalogenation of disinfection byproducts in water by natural sunlight irradiation.

    PubMed

    Abusallout, Ibrahim; Hua, Guanghui

    2016-09-01

    The aqueous photolysis of halogenated disinfection byproducts (DBPs) by natural sunlight irradiation was studied to determine their photolytic dehalogenation kinetics. Total organic halogen analysis was used to quantify the dehalogenation extents of DBPs during outdoor photolysis experiments. Dichloroacetamide, chloral hydrate, chloroform, dichloroacetonitrile, monochloro-, monobromo-, dichloro-, dibromo-, and trichloroacetic acids were generally resistant to photolytic dehalogenation and showed less than 10% reduction after 6 h sunlight irradiation. Monoiodoacetic acid, tribromoacetic acid, bromoform, dibromoacetonitrile, and trichloronitromethane showed moderate to high dehalogenation degrees with half-lives of 4.0-19.3 h. Diiodoacetic acid, triiodoacetic acid, and iodoform degraded rapidly under the sunlight irradiation and exhibited half-lives of 5.3-10.2 min. In general, the photosensitive cleavage of carbon-halogen bonds of DBPs increased with increasing number of halogens (tri- > di- > mono-halogenated) and size of the substituted halogens (I > Br > Cl). Nitrate, nitrite, and pH had little impact on the photodehalogenation of DBPs under typical levels in surface waters. The presence of natural organic matter (NOM) inhibited the photodehalogenation of DBPs by light screening. The NOM inhibiting effects were more pronounced for the fast degrading iodinated DBPs. The results of this study improve our understanding about the photolytic dehalogenation of wastewater-derived DBPs in surface waters during water reuse. Published by Elsevier Ltd.

  8. Bactericidal Effect of Solar Water Disinfection under Real Sunlight Conditions▿

    PubMed Central

    Boyle, M.; Sichel, C.; Fernández-Ibáñez, P.; Arias-Quiroz, G. B.; Iriarte-Puña, M.; Mercado, A.; Ubomba-Jaswa, E.; McGuigan, K. G.

    2008-01-01

    Batch solar disinfection (SODIS) inactivation kinetics are reported for suspensions in water of Campylobacter jejuni, Yersinia enterocolitica, enteropathogenic Escherichia coli, Staphylococcus epidermidis, and endospores of Bacillus subtilis, exposed to strong natural sunlight in Spain and Bolivia. The exposure time required for complete inactivation (at least 4-log-unit reduction and below the limit of detection, 17 CFU/ml) under conditions of strong natural sunlight (maximum global irradiance, ∼1,050 W m−2 ± 10 W m−2) was as follows: C. jejuni, 20 min; S. epidermidis, 45 min; enteropathogenic E. coli, 90 min; Y. enterocolitica, 150 min. Following incomplete inactivation of B. subtilis endospores after the first day, reexposure of these samples on the following day found that 4% (standard error, 3%) of the endospores remained viable after a cumulative exposure time of 16 h of strong natural sunlight. SODIS is shown to be effective against the vegetative cells of a number of emerging waterborne pathogens; however, bacterial species which are spore forming may survive this intervention process. PMID:18359829

  9. Harvesting Water from Air: Using Anhydrous Salt with Sunlight.

    PubMed

    Li, Renyuan; Shi, Yusuf; Shi, Le; Alsaedi, Mossab; Wang, Peng

    2018-05-01

    Atmospheric water is an abundant alternative water resource, equivalent to 6 times the water in all rivers on Earth. This work screens 14 common anhydrous and hydrated salt couples in terms of their physical and chemical stability, water vapor harvesting, and release capacity under relevant application scenarios. Among the salts screened, copper chloride (CuCl 2 ), copper sulfate (CuSO 4 ), and magnesium sulfate (MgSO 4 ) distinguish themselves and are further made into bilayer water collection devices, with the top layer being the photothermal layer, while the bottom layer acts as a salt-loaded fibrous membrane. The water collection devices are capable of capturing water vapor out of the air with low relative humidity (down to 15%) and releasing water under regular and even weakened sunlight (i.e., 0.7 kW/m 2 ). The work shines light on the potential use of anhydrous salt toward producing drinking water in water scarce regions.

  10. Evaluation of SnO2 for sunlight photocatalytic decontamination of water.

    PubMed

    Aslam, M; Qamar, M Tariq; Ali, Shahid; Rehman, Ateeq Ur; Soomro, M T; Ahmed, Ikram; Ismail, I M I; Hameed, A

    2018-07-01

    The broad bandgap tin (IV) oxide (SnO 2 ) is the least investigated semiconductor material for photocatalytic water decontamination in sunlight exposure. A detailed study covering the synthesis, characterization and the evaluation of photocatalytic activity of SnO 2 , in the natural sunlight exposure, is presented. The structural characterization by XRD revealed the formation of phase pure tetragonal SnO 2 with the average crystallite size of ∼41.5 nm whereas minor Sn 2+ states in the material were identified by XPS analysis. As explored by diffuse reflectance (DR) and photoluminescence (PL) spectroscopy, the material exhibited a distinct absorption edge at ∼3.4 eV. The morphological and microstructure analysis of the synthesized SnO 2 was carried out by FESEM and HRTEM. The electrochemical impedance spectroscopy (EIS) and chronopotentiometry (CP) predicted the better charge transport and retention ability of the material under illumination whereas the Mott-Schottky extrapolation prophesied the n-type behavior with the flat-band potential of -0.60 V. The photocatalytic activity of SnO 2 was assessed in the exposure of complete spectrum natural sunlight for the removal of 2,4,6-trichlorophenol. The HPLC and TOC analysis monitored the progress of degradation and mineralization whereas the released chloride ions were evaluated by ion chromatography. The effect of the transition metal ions (Fe 3+ , Cu 2+ , Ni 2+, and Zn 2+ ) as electron capture agents and H 2 O 2 as ROS generator was explored during the degradation process. The utility of the material for the simultaneous removal of chlorophenols in the mixture was also investigated. The SnO 2 exhibited sustained activity in the repeated use. Based on experimental evidence congregated, the mechanism of the removal process and the efficacy of SnO 2 for sunlight photocatalytic decontamination of water was established. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Water Quality Protection from Nutrient Pollution: Case ...

    EPA Pesticide Factsheets

    Water bodies and coastal areas around the world are threatened by increases in upstream sediment and nutrient loads, which influence drinking water sources, aquatic species, and other ecologic functions and services of streams, lakes, and coastal water bodies. For example, increased nutrient fluxes from the Mississippi River Basin have been linked to increased occurrences of seasonal hypoxia in northern Gulf of Mexico. Lake Erie is another example where in the summer of 2014 nutrients, nutrients, particularly phosphorus, washed from fertilized farms, cattle feedlots, and leaky septic systems; caused a severe algae bloom, much of it poisonous; and resulted in the loss of drinking water for a half-million residents. Our current management strategies for point and non-point source nutrient loadings need to be improved to protect and meet the expected increased future demands of water for consumption, recreation, and ecological integrity. This presentation introduces management practices being implemented and their effectiveness in reducing nutrient loss from agricultural fields, a case analysis of nutrient pollution of the Grand Lake St. Marys and possible remedies, and ongoing work on watershed modeling to improve our understanding on nutrient loss and water quality. Presented at the 3rd International Conference on Water Resource and Environment.

  12. Effect of sunlight exposure on the release of intentionally and/or non-intentionally added substances from polyethylene terephthalate (PET) bottles into water: chemical analysis and in vitro toxicity.

    PubMed

    Bach, Cristina; Dauchy, Xavier; Severin, Isabelle; Munoz, Jean-François; Etienne, Serge; Chagnon, Marie-Christine

    2014-11-01

    The effect of sunlight exposure on chemical migration into PET-bottled waters was investigated. Bottled waters were exposed to natural sunlight for 2, 6 and 10 days. Migration was dependent on the type of water. Formaldehyde, acetaldehyde and Sb migration increased with sunlight exposure in ultrapure water. In carbonated waters, carbon dioxide promoted migration and only formaldehyde increased slightly due to sunlight. Since no aldehydes were detected in non-carbonated waters, we conclude that sunlight exposure has no effect. Concerning Sb, its migration levels were higher in carbonated waters. No unpredictable NIAS were identified in PET-bottled water extracts. Cyto-genotoxicity (Ames and micronucleus assays) and potential endocrine disruption effects (transcriptional-reporter gene assays) were checked in bottled water extracts using bacteria (Salmonella typhimurium) and human cell lines (HepG2 and MDA-MB453-kb2). PET-bottled water extracts did not induce any toxic effects (cyto-genotoxicity, estrogenic or anti-androgenic activity) in vitro at relevant consumer-exposure levels. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Sunlight-energy-storing method

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kitao, T.; Ishihara, Sh.; Setsune, J.I.

    1984-05-22

    This invention is a method for storing light energy using an indigo derivative. Among indigo derivatives capable of storing light energy by the photoisomerization of the molecule from the trans-form to the cis-form, compounds heretofore obtained have been soluble only in expensive solvents such as benzene, toluene, chloroform, carbon tetrachloride and the like and harmful substances. On the other hand, the indigo derivative of this invention has the form of a pyridinium salt, is soluble in water and/or ethanol, and permits employment of safe and inexpensive water and/or an alcohol as a solvent. The indigo derivative of this invention convertedmore » from the trans-form to the cis-form by irradiation with sunlight and storing sunlight energy liberates the aforesaid stored energy as heat on addition of a catalyst and/or a heat trigger.« less

  14. Sunlight creates oxygenated species in water-soluble fractions of Deepwater Horizon oil.

    PubMed

    Ray, Phoebe Z; Chen, Huan; Podgorski, David C; McKenna, Amy M; Tarr, Matthew A

    2014-09-15

    In order to assess the impact of sunlight on oil fate, Macondo well oil from the Deepwater Horizon (DWH) rig was mixed with pure water and irradiated with simulated sunlight. After irradiation, the water-soluble organics (WSO) from the dark and irradiated samples were extracted and characterized by ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Liquid-liquid extraction yielded two fractions from dark and irradiated water/oil mixtures: acidic WSOs (negative-ion electrospray (ESI)), and base/neutral WSOs (positive-ion ESI) coupled to FT-ICR MS to catalog molecular-level transformations that occur to Macondo-derived WSOs after solar irradiation. Such direct measure of oil phototransformation has not been previously reported. The most abundant heteroatom class detected in the irradiated WSO acid fractions correspond to molecules that contain five oxygens (O5), while the most abundant acids in the dark samples contain two oxygen atoms per molecule (O2). Higher-order oxygen classes (O5-O9) were abundant in the irradiated samples, but <1.5% relative abundance in the dark sample. The increased abundance of higher-order oxygen classes in the irradiated samples relative to the dark samples indicates that photooxidized components of the Macondo crude oil become water-soluble after irradiation. The base/neutral fraction showed decreased abundance of pyridinic nitrogen (N1) concurrent with an increased abundance of N1Ox classes after irradiation. The predominance of higher-order oxygen classes indicates that multiple photochemical pathways exist that result in oxidation of petroleum compounds. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Oxygen and diverse nutrients influence the water kefir fermentation process.

    PubMed

    Laureys, David; Aerts, Maarten; Vandamme, Peter; De Vuyst, Luc

    2018-08-01

    Eight water kefir fermentation series differing in the presence of oxygen, the nutrient concentration, and the nutrient source were studied during eight consecutive backslopping steps. The presence of oxygen allowed the proliferation of acetic acid bacteria, resulting in high concentrations of acetic acid, and decreased the relative abundance of Bifidobacterium aquikefiri. Low nutrient concentrations resulted in slow water kefir fermentation and high pH values, which allowed the growth of Comamonas testosteroni/thiooxydans. Further, low nutrient concentrations favored the growth of Lactobacillus hilgardii and Dekkera bruxellensis, whereas high nutrient concentrations favored the growth of Lactobacillus nagelii and Saccharomyces cerevisiae. Dried figs, dried apricots, and raisins resulted in stable water kefir fermentation. Water kefir fermentation with dried apricots resulted in the highest pH and water kefir grain growth, whereas that with raisins resulted in the lowest pH and water kefir grain growth. Further, water kefir fermentation with raisins resembled fermentations with low nutrient concentrations, that with dried apricots resembled fermentations with normal nutrient concentrations, and that with fresh figs or a mixture of yeast extract and peptone resembled fermentations with high nutrient concentrations. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Supplementing vitamin D through sunlight: associating health literacy with sunlight exposure behavior.

    PubMed

    Leung, Angela Yee Man; Cheung, Mike Kwun Ting; Chi, Iris

    2015-01-01

    To test whether health literacy is associated with sunlight exposure behavior, we interviewed 648 Chinese adults aged 65 years or older. Using the information-motivation-behavioral skills model and structural equation modeling, we tested whether health literacy was associated with the complex relationships among knowledge about vitamin D, attitudes toward sunlight exposure, doctor recommendations regarding sunlight exposure, and sunlight exposure behavior. Health literacy was directly associated with sunlight exposure (β=.20, p<.01). Indirect relationships also existed between knowledge and sunlight exposure through health literacy (β=.46, p<.001) and between attitudes and sunlight exposure through health literacy (β=-.12, p<.05). The model had good fit (χ(2)/df=2.79; RMSEA=.053, p=.346; CFI=.95; TLI=.92). Health literacy should be considered when educating older adults about vitamin D supplements and sunlight exposure. Providing relevant knowledge or making doctor recommendations might not be effective. Training should focus on individuals with low health literacy who may be less likely to receive sunlight exposure. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  17. How long can culturable bacteria and total DNA persist in environmental waters? The role of sunlight and solid particles.

    PubMed

    Gutiérrez-Cacciabue, Dolores; Cid, Alicia G; Rajal, Verónica B

    2016-01-01

    In this work, sunlight inactivation of two indicator bacteria in freshwater, with and without solid particles, was studied and the persistence of culturable cells and total DNA was compared. Environmental water was used to prepare two matrices, with and without solid particles, which were spiked with Escherichia coli and Enterococcus faecalis. These matrices were used to prepare microcosm bags that were placed in two containers: one exposed to sunlight and the other in the dark. During one month, samples were removed from each container and detection was done by membrane filter technique and real-time PCR. Kinetic parameters were calculated to assess sunlight effect. Indicator bacteria without solid particles exposed to sunlight suffered an immediate decay (<4h) compared with the ones which were shielded from them. In addition, the survival of both bacteria with solid particles varied depending on the situation analyzed (T99 from 3 up to 60days), being always culturable E. coli more persistent than E. faecalis. On the other side, E. faecalis DNA persisted much longer than culturable cells (T99>40h in the dark with particles). In this case active cells were more prone to sunlight than total DNA and the protective effect of solid particles was also observed. Results highlight that the effects caused by the parameters which describe the behavior of culturable microorganisms and total DNA in water are different and must be included in simulation models but without forgetting that these parameters will also depend on bacterial properties, sensitizers, composition, type, and uses of the aquatic environment under assessment. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Sunlight-Sensitive Anti-Fouling Nanostructured TiO2 coated Cu Meshes for Ultrafast Oily Water Treatment

    PubMed Central

    Liu, HaoRan; Raza, Aikifa; Aili, Abulimiti; Lu, JinYou; AlGhaferi, Amal; Zhang, TieJun

    2016-01-01

    Nanostructured materials with desired wettability and optical property can play an important role in reducing the energy consumption of oily water treatment technologies. For effective oily water treatment, membrane materials with high strength, sunlight-sensitive anti-fouling, relative low fabrication cost, and controllable wettability are being explored. In the proposed oily water treatment approach, nanostructured TiO2-coated copper (TNS-Cu) meshes are used. These TNS-Cu meshes exhibit robust superhydrophilicity and underwater oleophobicity (high oil intrusion pressure) as well as excellent chemical and thermal stability (≈250 °C). They have demonstrated high separation efficiency (oil residue in the filtrate ≤21.3 ppm), remarkable filtration flux (≥400 kL h−1 m−2), and sunlight-sensitive anti-fouling properties. Both our theoretical analysis and experimental characterization have confirmed the enhanced light absorption property of TNS-Cu meshes in the visible region (40% of the solar spectrum) and consequently strong anti-fouling capability upon direct solar light illumination. With these features, the proposed approach promises great potential in treating produced oily wastewater from industry and daily life. PMID:27160349

  19. Transformation of acesulfame in water under natural sunlight: joint effect of photolysis and biodegradation.

    PubMed

    Gan, Zhiwei; Sun, Hongwen; Wang, Ruonan; Hu, Hongwei; Zhang, Pengfei; Ren, Xinhao

    2014-11-01

    The transformation of acesulfame in water under environmentally relevant conditions, including direct and indirect photolysis, biodegradation, and hydrolysis, was systematically evaluated. Under natural sunlight, both direct and indirect photolysis of acesulfame were negligible in sterilized systems at neutral or alkaline pH, whereas direct photolysis occurred at pH of 4 with a rate constant of 0.0355 d(-1) in deionized water. No significant reduction in acesulfame contents was found in the dark controls or in the incubation experiments, indicating acesulfame was resistant to hydrolysis and biodegradation. In unsterilized systems, photolysis was substantially enhanced, implying that there was a joint effect of photolysis and biodegradation or that the sterilization process had the secondary effect of inactivating some photosensitizers. The near-surface summer half-life of acesulfame in the water from the Haihe River was 9 d. Specific experiments revealed the involvement of (1)O2/(3)DOM* in acesulfame photolysis, whereas OH exhibited only a slight contribution in the presence of DOM or bicarbonate. As indicated by the total organic carbon data, no significant mineralization occurred in both sterilized and unsterilized systems after acesulfame was irradiated under simulated sunlight for 7 d, suggesting the generation of persistent intermediates. Finally, major degradation intermediates were analyzed, and the degradation pathways of acesulfame under environmentally relevant conditions were proposed for the first time. Copyright © 2014 Elsevier Ltd. All rights reserved.

  20. Diffuse sunlight based calibration of the water vapor channel in the upc raman lidar

    NASA Astrophysics Data System (ADS)

    Muñoz-Porcar, Constantino; Comeron, Adolfo; Sicard, Michaël; Barragan, Ruben; Garcia-Vizcaino, David; Rodríguez-Gómez, Alejandro; Rocadenbosch, Francesc

    2018-04-01

    A method for determining the calibration factor of the water vapor channel of a Raman lidar, based on zenith measurements of diffuse sunlight and on assumptions regarding some system parameters and Raman scattering models, has been applied to the lidar system of Universitat Politècnica de Catalunya (UPC; Technical University of Catalonia, Spain). Results will be analyzed in terms of stability and comparison with typical methods relying on simultaneous radiosonde measurements.

  1. Comparison of Two Spectrophotometric Techniques for Nutrients Analyses in Water Samples

    NASA Astrophysics Data System (ADS)

    Bartošová, Alica; Michalíková, Anna; Sirotiak, Maroš; Soldán, Maroš

    2013-01-01

    The aim of this contribution is to compare two common techniques for determining the concentrations of nitrate, nitrite, ammonium and phosphates in surface water and groundwater. Excess of these nutrients in water can directly affect human health (e.g. methemoglobinaemia) or indirectly through the products of secondary pollution - eutrophication (e.g. cyanotoxins, emanation of hydrogen sulphide, mercaptanes, methane...). Negative impact of nutrients excess in surface water often causes the destruction of water ecosystems, and therefore, common substances of these elements must be monitored and managed. For these experiments two spectrophotometric techniques - ultraviolet spectrophotometry and nutrient photometry were used. These techniques are commonly used for quick and simple analyses of nutrients in waste water. There are calibration curves for each nutrient and for determination of their concentration.

  2. Water Masses and Nutrient Sources to the Gulf of Maine

    PubMed Central

    Townsend, David W.; Pettigrew, Neal R.; Thomas, Maura A.; Neary, Mark G.; McGillicuddy, Dennis J.; O’Donnell, James

    2016-01-01

    The Gulf of Maine, a semi-enclosed basin on the continental shelf of the northwest Atlantic Ocean, is fed by surface and deep water flows from outside the Gulf: Scotian Shelf Water from the Nova Scotian shelf that enters the Gulf at the surface, and Slope Water that enters at depth and along the bottom through the Northeast Channel. There are two types of Slope Water, Labrador Slope Water (LSW) and Warm Slope Water (WSW); it is these deep water masses that are the major source of dissolved inorganic nutrients to the Gulf. It has been known for some time that the volume inflow of Slope Waters of either type that enters the Gulf of Maine is variable, that it co-varies with the magnitude of inflowing Scotian Shelf Water, and that periods of greater inflows of Scotian Shelf Water have become more frequent in recent years, accompanied by reduced Slope Water inflows. We present here analyses of a ten-year record of data collected by moored sensors in Jordan Basin, in the interior Gulf of Maine, and in the Northeast Channel, along with recent and historical hydrographic and nutrient data, that help reveal the nature of Scotian Shelf Water and Slope Water inflows. Proportional inflows of nutrient-rich Slope Waters and nutrient-poor Scotian Shelf Waters alternate episodically with one another on time scales of months to several years, creating a variable nutrient field upon which the biological productivities of the Gulf of Maine and Georges Bank depend. Unlike decades past, the inflows of Slope Waters of either type do not appear to be correlated with the North Atlantic Oscillation, which had been shown earlier to influence the relative proportions of the two Slope Waters, WSW and LSW, that enter the Gulf. We suggest that of greater importance in recent years are more frequent, episodic influxes of colder, fresher, less dense, and low-nutrient Scotian Shelf Water into the Gulf of Maine, and concomitant reductions in the inflow of deep, nutrient-rich Slope Waters. We also

  3. Water Masses and Nutrient Sources to the Gulf of Maine.

    PubMed

    Townsend, David W; Pettigrew, Neal R; Thomas, Maura A; Neary, Mark G; McGillicuddy, Dennis J; O'Donnell, James

    2015-01-01

    The Gulf of Maine, a semi-enclosed basin on the continental shelf of the northwest Atlantic Ocean, is fed by surface and deep water flows from outside the Gulf: Scotian Shelf Water from the Nova Scotian shelf that enters the Gulf at the surface, and Slope Water that enters at depth and along the bottom through the Northeast Channel. There are two types of Slope Water, Labrador Slope Water (LSW) and Warm Slope Water (WSW); it is these deep water masses that are the major source of dissolved inorganic nutrients to the Gulf. It has been known for some time that the volume inflow of Slope Waters of either type that enters the Gulf of Maine is variable, that it co-varies with the magnitude of inflowing Scotian Shelf Water, and that periods of greater inflows of Scotian Shelf Water have become more frequent in recent years, accompanied by reduced Slope Water inflows. We present here analyses of a ten-year record of data collected by moored sensors in Jordan Basin, in the interior Gulf of Maine, and in the Northeast Channel, along with recent and historical hydrographic and nutrient data, that help reveal the nature of Scotian Shelf Water and Slope Water inflows. Proportional inflows of nutrient-rich Slope Waters and nutrient-poor Scotian Shelf Waters alternate episodically with one another on time scales of months to several years, creating a variable nutrient field upon which the biological productivities of the Gulf of Maine and Georges Bank depend. Unlike decades past, the inflows of Slope Waters of either type do not appear to be correlated with the North Atlantic Oscillation, which had been shown earlier to influence the relative proportions of the two Slope Waters, WSW and LSW, that enter the Gulf. We suggest that of greater importance in recent years are more frequent, episodic influxes of colder, fresher, less dense, and low-nutrient Scotian Shelf Water into the Gulf of Maine, and concomitant reductions in the inflow of deep, nutrient-rich Slope Waters. We also

  4. Nutrient Management Certification for Delaware: Developing a Water Quality Curriculum

    ERIC Educational Resources Information Center

    Hansen, David J.; Binford, Gregory D.

    2004-01-01

    Water quality is a critical environmental, social, and political issue in Delaware. In the late 1990s, a series of events related to water quality issues led to the passage of a state nutrient management law. This new law required nutrient management planning and established a state certification program for nutrient users in the agricultural and…

  5. Producing Hydrogen With Sunlight

    NASA Technical Reports Server (NTRS)

    Biddle, J. R.; Peterson, D. B.; Fujita, T.

    1987-01-01

    Costs high but reduced by further research. Producing hydrogen fuel on large scale from water by solar energy practical if plant costs reduced, according to study. Sunlight attractive energy source because it is free and because photon energy converts directly to chemical energy when it breaks water molecules into diatomic hydrogen and oxygen. Conversion process low in efficiency and photochemical reactor must be spread over large area, requiring large investment in plant. Economic analysis pertains to generic photochemical processes. Does not delve into details of photochemical reactor design because detailed reactor designs do not exist at this early stage of development.

  6. Relating watershed nutrient loads to satellite derived estuarine water quality

    EPA Science Inventory

    Nutrient enhanced phytoplankton production is a cause of degraded estuarine water quality. Yet, relationships between watershed nutrient loads and the spatial and temporal scales of phytoplankton blooms and subsequent water quality impairments remain unquantified for most systems...

  7. Staphylococcus aureus Strain Newman Photoinactivation and Cellular Response to Sunlight Exposure.

    PubMed

    McClary, Jill S; Sassoubre, Lauren M; Boehm, Alexandria B

    2017-09-01

    Sunlight influences microbial water quality of surface waters. Previous studies have investigated photoinactivation mechanisms and cellular photostress responses of fecal indicator bacteria (FIB), including Escherichia coli and enterococci, but further work is needed to characterize photostress responses of bacterial pathogens. Here we investigate the photoinactivation of Staphylococcus aureus (strain Newman), a pigmented, waterborne pathogen of emerging concern. We measured photodecay using standard culture-based assays and cellular membrane integrity and investigated photostress response by measuring the relative number of mRNA transcripts of select oxidative stress, DNA repair, and metabolism genes. Photoinactivation experiments were performed in both oxic and anoxic systems to further investigate the role of oxygen-mediated and non-oxygen-mediated photoinactivation mechanisms. S. aureus lost culturability much faster in oxic systems than in anoxic systems, indicating an important role for oxygen in photodecay mechanisms. S. aureus cell membranes were damaged by sunlight exposure in anoxic systems but not in oxic systems, as measured by cell membrane permeability to propidium iodide. After sunlight exposure, S. aureus increased expression of a gene coding for methionine sulfoxide reductase after 12 h of sunlight exposure in the oxic system and after 6 h of sunlight exposure in the anoxic system, suggesting that methionine sulfoxide reductase is an important enzyme for defense against both oxygen-dependent and oxygen-independent photostresses. This research highlights the importance of oxygen in bacterial photoinactivation in environmentally relevant systems and the complexity of the bacterial photostress response with respect to cell structure and transcriptional regulation. IMPORTANCE Staphylococcus aureus is a pathogenic bacterium that causes gastrointestinal, respiratory, and skin infections. In severe cases, S. aureus infection can lead to life

  8. Long-term decline of the canopy-forming algae Gelidium corneum, associated to extreme wave events and reduced sunlight hours, in the southeastern Bay of Biscay

    NASA Astrophysics Data System (ADS)

    Borja, Angel; Chust, Guillem; Fontán, Almudena; Garmendia, Joxe Mikel; Uyarra, María C.

    2018-05-01

    Canopy-forming macroalgae are experiencing large biogeographical shifts due to climate change. One of them (Gelidium corneum) has shown a dramatic decline in biomass in northern Spain, in the past 20 years. We investigate here two most plausible hypotheses to explain its decline: (i) a combination of increasing wave energy and decrease of irradiance in the growth season; and (ii) a combination of increasing light in summer and decreasing nutrient concentration. Using a dataset of biomass and environmental variables (1993-2016), in three sectors and three water depths, we have determined that the variables explaining more biomass variability were: suspended solids, nitrate, sunlight hours, significant wave height threshold exceedances (Hs5m), temperature, silicate, and nitrite. When undertaking multiple regression analyses for the whole depth range, only the model including sunlight hours with Hs5m was selected, being highly significant (p < 0.0001) and explaining 37% of the variability. When comparing the macroalgal biomass between the initial period of the series (where the biomass was stable) and final period (showing biomass decline), 45% decrease was observed while the Hs5m increase was 41%, detaching the algae from the substratum during the growth season. The decline rate in biomass with time, at each sector and depth, was highly correlated (p < 0.001) to the wave energy flux received at each depth, which was higher at 5 m in all sectors, decreasing with depth. In turn, nutrients, instead of decreasing, have increased, and only nitrate presented a significant negative correlation with G. corneum biomass, which was not significant after detrending. The significant (p = 0.001) increase in rainfall over the studied period can explain the increase of those nutrients. Hence, we question whether the effect of nutrients is such, as already described. The most likely factor explaining the decline of this macroalga was the combination of sunlight hours decrease and Hs5

  9. Sunlight Controls Water Column Processing of Carbon in Arctic Freshwaters

    NASA Astrophysics Data System (ADS)

    Cory, R. M.; Ward, C. P.; Crump, B. C.; Kling, G. W.

    2014-12-01

    Carbon (C) in thawing permafrost soils may have global impacts on climate change, yet controls on its processing and fate are poorly understood. The dominant fate of dissolved organic C (DOC) released from soils to inland waters is either complete oxidation to CO2 or partial oxidation and river export to oceans. Both processes are most often attributed to bacterial respiration, but we recently showed that photochemical oxidation exceeds rates of respiration and accounts for 70-95% of total DOC processed in the water column of arctic lakes and rivers. While the overall dominance of photochemical processing in streams and lakes remained, the fate of DOC varied consistently by water type. In small streams DOC was mainly mineralized by sunlight to CO2, while in lakes the main fate of DOC was partial photo-oxidation. Large rivers were intermediate between these end members, and photo-mineralization to CO2 was about equal to or less than partial photo-oxidation. We suggest this pattern is a result of light-exposure history, where DOC leached from soils into headwater streams has little prior light exposure and is labile to complete photo-oxidation, but as light exposure increases moving downstream and into lakes with longer residence times the DOC photo-lability declines. Thus as easily photo-mineralized moieties are removed, DOC fate shifts toward partial photo-oxidation and downstream export in rivers and lakes. At the basin scale, photochemical processing of DOC is about one third of the total CO2 released from surface waters, and is thus an important, newly measured component of the Arctic C budget. We also suggest that these photochemical transformations of DOC will occur in any shallow surface water, and could be important for better understanding inland water carbon cycling.

  10. Roots bridge water to nutrients: a study of utilizing hydraulic redistribution through root systems to extract nutrients in the dry soils

    NASA Astrophysics Data System (ADS)

    Yan, J.; Ghezzehei, T. A.

    2017-12-01

    The rhizosphere is the region of soil that surrounds by individual plant roots. While its small volume and narrow region compared to bulk soil, the rhizosphere regulates numerous processes that determine physical structure, nutrient distribution, and biodiversity of soils. One of the most important and distinct functions of the rhizosphere is the capacity of roots to bridge and redistribute soil water from wet soil layers to drier layers. This process was identified and defined as hydraulic lift or hydraulic redistribution, a passive process driven by gradients in water potentials and it has attracted much research attention due to its important role in global water circulation and agriculture security. However, while previous studies mostly focused on the hydrological or physiological impacts of hydraulic redistribution, limited research has been conducted to elucidate its role in nutrient cycling and uptake. In this study, we aim to test the possibility of utilizing hydraulic redistribution to facilitate the nutrient movement and uptake from resource segregated zone. Our overarching hypothesis is that plants can extract nutrients from the drier but nutrient-rich regions by supplying sufficient amounts of water from the wet but nutrient-deficient regions. To test our hypothesis, we designed split-root systems of tomatoes with unequal supply of water and nutrients in different root compartments. More specifically, we transplanted tomato seedlings into sand or soil mediums, and grew them under conditions with alternate 12-h lightness and darkness. We continuously monitored the temperature, water and nutrient content of soils in these separated compartments. The above and below ground biomass were also quantified to evaluate the impacts on the plant growth. The results were compared to a control with evenly supply of water and nutrients to assess the plant growth, nutrient leaching and uptake without hydraulic redistribution.

  11. Water Quality Protection from Nutrient Pollution: Case Analysis

    EPA Science Inventory

    Water bodies and coastal areas around the world are threatened by increases in upstream sediment and nutrient loads, which influence drinking water sources, aquatic species, and other ecologic functions and services of streams, lakes, and coastal water bodies. For example, incre...

  12. Nutrient Loss in Runoff from Turf: Effect on Surface Water Quality

    USDA-ARS?s Scientific Manuscript database

    Excess nutrients in surface waters may result in enhanced algal blooms and plant growth that can lead to eutrophication and a decline in water quality. The applicatin of fertilizer to golf courses may be a source of nutrients to surface waters. Runoff studies were conducted to measure applied nitrog...

  13. Mechanism, kinetics, and pathways of self-sensitized sunlight photodegradation of phenylarsonic compounds.

    PubMed

    Xie, Xiande; Hu, Yuanan; Cheng, Hefa

    2016-06-01

    Being highly water-soluble, phenylarsonic feed additives discharged in animal wastes can easily accumulate in surface water bodies. The photodegradation mechanism, kinetics, and pathways of p-arsanilic acid (p-ASA), 4-hydrophenylarsonic acid (4-HPAA), and phenylarsonic acid (PAA) in water under simulated and natural sunlight irradiation were investigated. The -AsO(OH)2 group was cleaved from the aromatic ring during photodegradation, and p-benzoquinone and p-hydroquinone were formed as the major organic degradation intermediates. Experimental results did not indicate any significant direct photolysis of the phenylarsonic compounds under simulated and natural sunlight irradiation, but consistently showed that they sensitized the formation of singlet oxygen, which was responsible for their photodegradation and oxidation of the As(III) released. A simple (1)O2-based "heterogeneous" model was developed, which could well describe the kinetics of (1)O2 formation and phenylarsonic compound photodegradation under various conditions. Indirect photolysis caused by inorganic ions commonly present in natural waters was negligible, while natural organic matter could significantly inhibit their photodegradation. The half-lives of p-ASA, 4-HPAA, and PAA photodegradation under simulated sunlight irradiation (765 W m(-2), 25 °C) were 11.82 ± 0.19, 20.06 ± 0.10, and 135 ± 6.0 min, respectively, while their degradation rates under natural sunlight in the Pearl River Delta of southern China were 5 times slower due to lower irradiation intensity and water temperatures (19-23 °C). Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Sunlight-promoted photocatalytic hydrogen gas evolution from water-suspended cellulose: a systematic study.

    PubMed

    Speltini, Andrea; Sturini, Michela; Dondi, Daniele; Annovazzi, Enrico; Maraschi, Federica; Caratto, Valentina; Profumo, Antonella; Buttafava, Armando

    2014-10-01

    This work presents a systematic study of cellulose (CLS) as a sacrificial biomass for photocatalytic H2 evolution from water. The idea is indeed to couple a largely available and not expensive biomass, and water, with a renewable energy like solar radiation. An aqueous CLS suspension irradiated either at 366 nm (UV-A) or under sunlight in the presence of Pt/TiO2 behaves as a H2 evolving system. The effects of irradiation time, catalyst and CLS concentrations, pH and water salinity are studied. Addition of CLS to the sample significantly improved H2 evolution from water splitting, with yields up to ten fold higher than those observed in neat water. The mechanism of the photocatalytic process relies on the TiO2-mediated CLS hydrolysis, under irradiation. The polysaccharide depolymerisation generates water-soluble species and intermediates, among them 5-hydroxymethylfurfural (HMF) was identified. These intermediates are readily oxidized following the glucose photoreforming, thus enhancing water hydrogen ion reduction to give gas-phase H2. The formation of "colored" by-products from HMF self-polymerization involves a sort of "in situ dye sensitization" that allows an effective photoreaction even under solar light. The procedure is evaluated and successfully extended on cellulosic biomasses, i.e. rice husk and alfalfa (Medicago sativa) stems, not previously investigated for this application.

  15. Response of coliform populations in streambed sediment and water column to changes in nutrient concentrations in water.

    PubMed

    Shelton, D R; Pachepsky, Y A; Kiefer, L A; Blaustein, R A; McCarty, G W; Dao, T H

    2014-08-01

    As sediments increasingly become recognized as reservoirs of indicator and pathogen microorganisms, an understanding of the persistence of indicator organisms becomes important for assessment and predictions of microbial water quality. The objective of this work was to observe the response of water column and sediment coliform populations to the change in nutrient concentrations in the water column. Survival experiments were conducted in flow-through chambers containing sandy sediments. Bovine feces were collected fresh and introduced into sediment. Sixteen days later, the same fecal material was autoclaved and diluted to provide three levels - 1×, 0.5×, and 0.1× of nutrient concentrations - spike in water column. Total coliforms, Escherichia coli, and total aerobic heterotrophic bacterial concentrations were monitored in water and sediment. Bacteria responded to the nutrient spike with initial growth both in the water column and in sediment. The response of bacterial concentrations in water column was nonlinear, with no significant changes at 0.1 and .5× spikes, but a substantial change at 1× spike. Bacteria in sediment responded to the spikes at all added nutrient levels. Coliform inactivation rates both in sediment and in water after the initial growth occurred, were not significantly different from the inactivation rates before spike. These results indicate that introduction of nutrients into the water column results in nonlinear response of E. coli concentrations both in water and in sediments, followed by the inactivation with the same rate as before introduction of nutrients. Published by Elsevier Ltd.

  16. Improved hydrological-model design by integrating nutrient and water flow

    NASA Astrophysics Data System (ADS)

    Arheimer, B.; Lindstrom, G.

    2013-12-01

    The potential of integrating hydrologic and nutrient concentration data to better understand patterns of catchment response and to better design hydrological modeling was explored using a national multi-basin model system for Sweden, called ';S-HYPE'. The model system covers more than 450 000 km2 and produce daily values of nutrient concentration and water discharge in 37 000 catchments from 1961 and onwards. It is based on the processed-based and semi-distributed HYdrological Predictions for the Environment (HYPE) code. The model is used operationally for assessments of water status or climate change impacts and for forecasts by the national warning service of floods, droughts and fire. The first model was launched in 2008, but S-HYPE is continuously improved and released in new versions every second year. Observations are available in 400 sites for daily water discharge and some 900 sites for monthly grab samples of nutrient concentrations. The latest version (2012) has an average NSE for water discharge of 0.7 and an average relative error of 5%, including both regulated and unregulated rivers with catchments from ten to several thousands of km2 and various landuse. The daily relative errors of nutrient concentrations are on average 20% for total Nitrogen and 35% for total Phosphorus. This presentation will give practical examples of how the nutrient data has been used to trace errors or inadequate parameter values in the hydrological model. Since 2008 several parts of the model structure has been reconsidered both in the source code, parameter values and input data of catchment characteristics. In this process water quality has been guiding much of the overall model design of catchment hydrological functions and routing along the river network. The model structure has thus been developed iteratively when evaluating results and checking time-series. Examples of water quality driven improvements will be given for estimation of vertical flow paths, such as

  17. Groundwater-driven nutrient inputs to coastal lagoons: The relevance of lagoon water recirculation as a conveyor of dissolved nutrients.

    PubMed

    Rodellas, Valentí; Stieglitz, Thomas C; Andrisoa, Aladin; Cook, Peter G; Raimbault, Patrick; Tamborski, Joseph J; van Beek, Pieter; Radakovitch, Olivier

    2018-06-16

    Evaluating the sources of nutrient inputs to coastal lagoons is required to understand the functioning of these ecosystems and their vulnerability to eutrophication. Whereas terrestrial groundwater processes are increasingly recognized as relevant sources of nutrients to coastal lagoons, there are still limited studies evaluating separately nutrient fluxes driven by terrestrial groundwater discharge and lagoon water recirculation through sediments. In this study, we assess the relative significance of these sources in conveying dissolved inorganic nutrients (NO 3 - , NH 4 + and PO 4 3- ) to a coastal lagoon (La Palme lagoon; France, Mediterranean Sea) using concurrent water and radon mass balances. The recirculation of lagoon water through sediments represents a source of NH 4 + (1900-5500 mol d -1 ) and PO 4 3- (22-71 mol d -1 ), but acts as a sink of NO 3 - . Estimated karstic groundwater-driven inputs of NO 3 - , NH 4 + and PO 4 3- to the lagoon are on the order of 200-1200, 1-12 and 1.5-8.7 mol d -1 , respectively. A comparison between the main nutrient sources to the lagoon (karstic groundwater, recirculation, diffusion from sediments, inputs from a sewage treatment plant and atmospheric deposition) reveals that the recirculation of lagoon water through sediments is the main source of both dissolved inorganic nitrogen (DIN) and phosphorous (DIP) to La Palme lagoon. These results are in contrast with several studies conducted in systems influenced by terrestrial groundwater inputs, where groundwater is often assumed to be the main pathway for dissolved inorganic nutrient loads. This work highlights the important role of lagoon water recirculation through permeable sediments as a major conveyor of dissolved nutrients to coastal lagoons and, thus, the need for a sound understanding of the recirculation-driven nutrient fluxes and their ecological implications to sustainably manage lagoonal ecosystems. Copyright © 2018. Published by Elsevier B.V.

  18. Efficient Solar Concentrators: Affordable Energy from Water and Sunlight

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2010-01-01

    Broad Funding Opportunity Announcement Project: Teledyne is developing a liquid prism panel that tracks the position of the sun to help efficiently concentrate its light onto a solar cell to produce power. Typically, solar tracking devices have bulky and expensive mechanical moving parts that require a lot of power and are often unreliable. Teledyne’s liquid prism panel has no bulky and heavy supporting parts—instead it relies on electrowetting. Electrowetting is a process where an electric field is applied to the liquid to control the angle at which it meets the sunlight above and to control the angle of the sunlightmore » to the focusing lensthe more direct the angle to the focusing lens, the more efficiently the light can be concentrated to solar panels and converted into electricity. This allows the prism to be tuned like a radio to track the sun across the sky and steer sunlight into the solar cell without any moving mechanical parts. This process uses very little power and requires no expensive supporting hardware or moving parts, enabling efficient and quiet rooftop operation for integration into buildings.« less

  19. Phytoremediation to remove nutrients and improve eutrophic stormwaters using water lettuce (Pistia stratiotes L.).

    PubMed

    Lu, Qin; He, Zhenli L; Graetz, Donald A; Stoffella, Peter J; Yang, Xiaoe

    2010-01-01

    Water quality impairment by nutrient enrichment from agricultural activities has been a concern worldwide. Phytoremediation technology using aquatic plants in constructed wetlands and stormwater detention ponds is increasingly applied to remediate eutrophic waters. The objectives of this study were to evaluate the effectiveness and potential of water lettuce (Pistia stratiotes L.) in removing nutrients including nitrogen (N) and phosphorus (P) from stormwater in the constructed water detention systems before it is discharged into the St. Lucie Estuary, an important surface water system in Florida, using phytoremediation technologies. In this study, water lettuce (P. stratiotes) was planted in the treatment plots of two stormwater detention ponds (East and West Ponds) in 2005-2007 and water samples from both treatment and control plots were weekly collected and analyzed for water quality properties including pH, electrical conductivity, turbidity, suspended solids, and nutrients (N and P). Optimum plant density was maintained and plant samples were collected monthly and analyzed for nutrient contents. Water quality in both ponds was improved, as evidenced by decreases in water turbidity, suspended solids, and nutrient concentrations. Water turbidity was decreased by more than 60%. Inorganic N (NH(4) (+) and NO(3) (-)) concentrations in treatment plots were more than 50% lower than those in control plots (without plant). Reductions in both PO(4) (3-) and total P were approximately 14-31%, as compared to the control plots. Water lettuce contained average N and P concentrations of 17 and 3.0 g kg(-1), respectively, and removed 190-329 kg N ha(-1) and 25-34 kg P ha(-1) annually. Many aquatic plants have been used to remove nutrients from eutrophic waters but water lettuce proved superior to most other plants in nutrient removal efficiency, owing to its rapid growth and high biomass yield potential. However, the growth and nutrient removal potential are affected by many

  20. Surface-water nutrient conditions and sources in the United States Pacific Northwest

    USGS Publications Warehouse

    Wise, D.R.; Johnson, H.M.

    2011-01-01

    The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts.

  1. Water and nutrient budgets for Vancouver Lake, Vancouver, Washington, October 2010-October 2012

    USGS Publications Warehouse

    Sheibley, Rich W.; Foreman, James R.; Marshall, Cameron A.; Welch, Wendy B.

    2014-01-01

    Vancouver Lake, a large shallow lake in Clark County, near Vancouver, Washington, has been undergoing water-quality problems for decades. Recently, the biggest concern for the lake are the almost annual harmful cyanobacteria blooms that cause the lake to close for recreation for several weeks each summer. Despite decades of interest in improving the water quality of the lake, fundamental information on the timing and amount of water and nutrients entering and exiting the lake is lacking. In 2010, the U.S. Geological Survey conducted a 2-year field study to quantify water flows and nutrient loads in order to develop water and nutrient budgets for the lake. This report presents monthly and annual water and nutrient budgets from October 2010–October 2012 to identify major sources and sinks of nutrients. Lake River, a tidally influenced tributary to the lake, flows into and out of the lake almost daily and composed the greatest proportion of both the water and nutrient budgets for the lake, often at orders of magnitude greater than any other source. From the water budget, we identified precipitation, evaporation and groundwater inflow as minor components of the lake hydrologic cycle, each contributing 1 percent or less to the total water budget. Nutrient budgets were compiled monthly and annually for total nitrogen, total phosphorus, and orthophosphate; and, nitrogen loads were generally an order of magnitude greater than phosphorus loads across all sources. For total nitrogen, flow from Lake River at Felida, Washington, made up 88 percent of all inputs into the lake. For total phosphorus and orthophosphate, Lake River at Felida flowing into the lake was 91 and 76 percent of total inputs, respectively. Nutrient loads from precipitation and groundwater inflow were 1 percent or less of the total budgets. Nutrient inputs from Burnt Bridge Creek and Flushing Channel composed 12 percent of the total nitrogen budget, 8 percent of the total phosphorus budget, and 21 percent

  2. Proflavine-mediated inactivation of Salmonella dublin exposed to visible sunlight in natural fresh water.

    PubMed

    Kussovski, V K; Hristov, A E; Radoucheva, T S

    2001-01-01

    The survival of Salmonella dublin exposed to visible sunlight, and heterotrophic bacteria in freshwater microcosms in the presence and absence of the photosensitizer proflavine, was studied. Enumeration of S. dublin and the heterotrophic bacteria showed that in both illuminated and nonilluminated systems (without proflavine) the bacteria remained viable and culturable for at least 6 days. The optimal proflavine concentration (no effect in the dark and a maximal photoinactivation of salmonellae after irradiation) was 2 mg l(-1). In contrast to S. dublin, the heterotrophic bacteria overcame the initial inhibitory effect of proflavine. The possible use of photosterilization against contamination with pathogenic bacteria in water model ecosystems, is discussed.

  3. Water Relations, Gas Exchange, and Nutrient Response to a Long Term Constant Water Deficit

    NASA Technical Reports Server (NTRS)

    Berry, Wade L.; Goldstein, Guillermo; Dreschel, Thomas W.; Wheeler, Raymond M.; Sager, John C.; Knott, William M.

    1992-01-01

    Wheat plants (Triticum aestivum) were grown for 43 days in a micro-porous tube nutrient delivery system. Roots were unable to penetrate the microporous tube, but grew on the surface and maintained capillary contact with the nutrient solution on the inside of the tube through the 5-microns pores of the porous tube. Water potential in the system was controlled at -0.4, -0.8, and -3.0 kPa by adjusting the applied pressure (hydrostatic head) to the nutrient solution flowing through the microporous tubes. A relatively small decrease in applied water potential from -0.4 to -3.0 kPa resulted in a 34% reduction of shoot growth but only a moderate reduction in the mid-day leaf water potential from - 1.3 to - 1.7 MPa. Carbon dioxide assimilation decreased and water use efficiency increased with the more negative applied water Potentials, while intercellular C02 concentration remained constant. The physiological responses observed in this study in response to small constant differences in applied water potentials were much greater than expected from either the applied water potential or the observed plant water potential. Even though the micro-porous tube may not represent natural conditions and could possibly introduce morphological and physiological artifacts , it enables a high degree of control of water potential that facilitates the investigation of many aspects of water relations not practical with other experimental systems.

  4. Dissolved organic matter degradation by sunlight coagulates organo-mineral colloids and produces low-molecular weight fraction of metals in boreal humic waters

    NASA Astrophysics Data System (ADS)

    Oleinikova, Olga V.; Drozdova, Olga Yu.; Lapitskiy, Sergey A.; Demin, Vladimir V.; Bychkov, Andrey Yu.; Pokrovsky, Oleg S.

    2017-08-01

    Photochemical degradation of dissolved organic matter (DOM) is recognized as the major driver of CO2 emission to the atmosphere from the inland waters of high latitudes. In contrast to numerous studies of photo-induced DOM transformation, the behavior of trace element (TE) during photodegradation of boreal DOM remains virtually unknown. Towards a better understanding of concentration, size fractionation and speciation change of DOM and TE in boreal waters subjected to solar radiation, we conducted on-site photo-degradation experiments in stream and bog water collected from a pristine zone of the Northern Karelia (Russian subarctic). The removal of Fe and Al occurred only in the bog water (90% and 50% respectively, over 5 days of reaction), whereas no detectable decrease of dissolved (<0.22 μm) Al and Fe concentration was observed in the boreal stream. A number of low-soluble TE linked to Fe-rich organo-mineral colloids followed the behavior of Fe during bog water exposure to sunlight: Al, P, Ti, V, Cr, As, Y, Zr, REEs, Hf, Th, Pb and U. The second group of elements (Li, B, Mg, Ca, Sr, Ba, Na, K, Rb, Si, Mn, Ni, Cu, Co, Cd, Sb) was indifferent to photodegradation of DOM and exhibited a non-systematic variation (±10-15% from the control) of <0.22 μm fraction in the course of sunlight exposure. The bog water insolation yielded a factor of 3 ± 1 increase of low molecular weight (LMW < 1 kDa) fraction of organic carbon, Al, Fe, U, Mg, Ca, Mn, Co, Ni, Sr, Cd and Ba after 200 h of sunlight exposure compared to the dark control. The LMW< 1 kDa fraction was preferentially enriched in Fe, Al, Ca, Mg and other divalent metals relative to Corg. The climate warming leading to water temperature rise in the boreal zone will intensify the Fe and Al hydroxide coagulation while increasing the production of LMW organic ligands and free metals and metal - organic complexes.

  5. Maximizing the accuracy of field-derived numeric nutrient criteria in water quality regulations.

    PubMed

    McLaughlin, Douglas B

    2014-01-01

    High levels of the nutrients nitrogen and phosphorus can cause unhealthy biological or ecological conditions in surface waters and prevent the attainment of their designated uses. Regulatory agencies are developing numeric criteria for these nutrients in an effort to ensure that the surface waters in their jurisdictions remain healthy and productive, and that water quality standards are met. These criteria are often derived using field measurements that relate nutrient concentrations and other water quality conditions to expected biological responses such as undesirable growth or changes in aquatic plant and animal communities. Ideally, these numeric criteria can be used to accurately "diagnose" ecosystem health and guide management decisions. However, the degree to which numeric nutrient criteria are useful for decision making depends on how accurately they reflect the status or risk of nutrient-related biological impairments. Numeric criteria that have little predictive value are not likely to be useful for managing nutrient concerns. This paper presents information on the role of numeric nutrient criteria as biological health indicators, and the potential benefits of sufficiently accurate criteria for nutrient management. In addition, it describes approaches being proposed or adopted in states such as Florida and Maine to improve the accuracy of numeric criteria and criteria-based decisions. This includes a preference for developing site-specific criteria in cases where sufficient data are available, and the use of nutrient concentration and biological response criteria together in a framework to support designated use attainment decisions. Together with systematic planning during criteria development, the accuracy of field-derived numeric nutrient criteria can be assessed and maximized as a part of an overall effort to manage nutrient water quality concerns. © 2013 SETAC.

  6. Submarine groundwater discharge as an important nutrient source influencing nutrient structure in coastal water of Daya Bay, China

    NASA Astrophysics Data System (ADS)

    Wang, Xuejing; Li, Hailong; Zheng, Chunmiao; Yang, Jinzhong; Zhang, Yan; Zhang, Meng; Qi, Zhanhui; Xiao, Kai; Zhang, Xiaolang

    2018-03-01

    As an important nutrient source for coastal waters, submarine groundwater discharge (SGD) has long been largely ignored in Daya Bay, China. In this study, we estimate the fluxes of SGD and associated nutrients into this region using a 224Ra mass balance model and assess the contribution/importance of nutrients by SGD, benthic sediments, local rivers, and atmospheric deposition. The results of 224Ra mass balance show that the estimated SGD ranges from (2.76 ± 1.43) × 106 m3/d to (1.03 ± 0.53) × 107 m3/d with an average of (6.32 ± 2.42) × 106 m3/d, about 16 times the total discharge rate of local rivers. The nutrient loading from SGD is estimated to be (1.05-1.99) × 105 mol/d for NO3-N, (4.04-12.16) × 103 mol/d for DIP, and (3.54-11.35) × 105 mol/d for Si. Among these considered nutrient sources, we find that SGD is the primary source for Si and NO3-N, contributing 68% and 42% of all considered sources, respectively. The atmospheric NO3-N flux is comparable to that from SGD. The local rivers are the most important source for DIP, contributing 75% of all considered sources. SGD with high N:P ratio (NO3-N/DIP) of 37.0 delivers not only a large quantity of nutrients, but also changes nutrient structure in coastal water. Based on a DIP budget, primary productivity is evaluated to be 54-73 mg C/m2 d, in which SGD accounts for approximately 30% of total production. This study indicates that SGD is a key source of nutrients to coastal waters and may cause an obvious change of primary production and nutrient structure in Daya Bay.

  7. Taxicab tipping and sunlight

    PubMed Central

    2017-01-01

    Does the level of sunlight affect the tipping percentage in taxicab rides in New York City? We examined this question using data on 13.82 million cab rides from January to October in 2009 in New York City combined with data on hourly levels of solar radiation. We found a small but statistically significant positive relationship between sunlight and tipping, with an estimated tipping increase of 0.5 to 0.7 percentage points when transitioning from a dark sky to full sunshine. The findings are robust to two-way clustering of standard errors based on hour-of-the-day and day-of-the-year and controlling for day-of-the-year, month-of-the-year, cab driver fixed effects, weather conditions, and ride characteristics. The NYC cab ride context is suitable for testing the association between sunlight and tipping due to the largely random assignment of riders to drivers, direct exposure to sunlight, and low confounding from variation in service experiences. PMID:28594917

  8. Taxicab tipping and sunlight.

    PubMed

    Devaraj, Srikant; Patel, Pankaj C

    2017-01-01

    Does the level of sunlight affect the tipping percentage in taxicab rides in New York City? We examined this question using data on 13.82 million cab rides from January to October in 2009 in New York City combined with data on hourly levels of solar radiation. We found a small but statistically significant positive relationship between sunlight and tipping, with an estimated tipping increase of 0.5 to 0.7 percentage points when transitioning from a dark sky to full sunshine. The findings are robust to two-way clustering of standard errors based on hour-of-the-day and day-of-the-year and controlling for day-of-the-year, month-of-the-year, cab driver fixed effects, weather conditions, and ride characteristics. The NYC cab ride context is suitable for testing the association between sunlight and tipping due to the largely random assignment of riders to drivers, direct exposure to sunlight, and low confounding from variation in service experiences.

  9. Nutrients in ground water and surface water of the United States; an analysis of data through 1992

    USGS Publications Warehouse

    Mueller, D.K.; Hamilton, P.A.; Helsel, D.R.; Hitt, K.J.; Ruddy, B.C.

    1995-01-01

    Historical data on nutrient (nitrogen and phosphorus species) concentrations in ground-and surface-water samples were compiled from 20 study units of the National Water-Quality Assessment (NAWQA) Program and 5 supplemental study areas. The resultant national retrospective data sets contained analyses of about 12,000 Found-water and more than 22,000 surface-water samples. These data were interpreted on regional and national scales by relating the distributions of nutrient concentrations to ancillary data, such as land use, soil characteristics, and hydrogeology, provided by local study-unit personnel. The information provided in this report on environmental factors that affect nutrient concentrations in ground and surface water can be used to identify areas of the Nation where the vulnerability to nutrient contamination is greatest. Nitrate was the nutrient of greatest concern in the historical ground-water data. It is the only nutrient that is regulated by a national drinking-water standard. Nitrate concentrations were significantly different in ground water affected by various land uses. Concentrations in about 16 percent of the samples collected in agricultural areas exceeded the drinking-water standard. However, the standard was exceeded in only about 1 percent of samples collected from public-supply wells. A variety of ancillary factors had significant relations to nitrate concentrations in ground water beneath agricultural areas. Concentrations generally were highest within 100 feet of the land surface. They were also higher in areas where soil and geologic characteristics promoted rapid movement of water to the aquifer. Elevated concentrations commonly occurred in areas underlain by permeable materials, such as carbonate bedrock or unconsolidated sand and gravel, and where soils are generally well drained. In areas where water movement is impeded, denitrification might lead to low concentrations of nitrate in the ground water. Low concentrations were also

  10. Sunlight-Driven Hydrogen Formation by Membrane-Supported Photoelectrochemical Water Splitting

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lewis, Nathan S.

    2014-03-26

    This report describes the significant advances in the development of the polymer-supported photoelectrochemical water-splitting system that was proposed under DOE grant number DE-FG02-05ER15754. We developed Si microwire-array photoelectrodes, demonstrated control over the material and light-absorption properties of the microwire-array photoelectrodes, developed inexpensive processes for synthesizing the arrays, and doped the arrays p-type for use as photocathodes. We also developed techniques for depositing metal-nanoparticle catalysts of the hydrogen-evolution reaction (HER) on the wire arrays, investigated the stability and catalytic performance of the nanoparticles, and demonstrated that Ni-Mo alloys are promising earth-abundant catalysts of the HER. We also developed methods that allowmore » reuse of the single-crystalline Si substrates used for microwire growth and methods of embedding the microwire photocathodes in plastic to enable large-scale processing and deployment of the technology. Furthermore we developed techniques for controlling the structure of WO3 films, and demonstrated that structural control can improve the quantum yield of photoanodes. Thus, by the conclusion of this project, we demonstrated significant advances in the development of all components of a sunlight-driven membrane-supported photoelectrochemical water-splitting system. This final report provides descriptions of some of the scientific accomplishments that were achieved under the support of this project and also provides references to the peer-reviewed publications that resulted from this effort.« less

  11. Growing Hyperbranched Polymers Using Natural Sunlight

    PubMed Central

    Yan, Jun-Jie; Sun, Jiao-Tong; You, Ye-Zi; Wu, De-Cheng; Hong, Chun-Yan

    2013-01-01

    In nature, a sapling can grow into a big tree under irradiation of sunlight. In chemistry, a similar concept that a small molecule only exposing to sunlight grows into a hyperbranched macromolecule has not been realized by now. The achievement of the concept will be fascinating and valuable for polymer synthesis wherein sunlight is inexpensive, abundant, renewable, and nonpolluting. Herein, we report a new strategy in which small monomers can directly grow into big hyperbranched macromolecule under irradiation of sunlight without any catalyst. PMID:24100948

  12. Persistence of marine fish environmental DNA and the influence of sunlight

    PubMed Central

    Andruszkiewicz, Elizabeth A.; Sassoubre, Lauren M.

    2017-01-01

    Harnessing information encoded in environmental DNA (eDNA) in marine waters has the potential to revolutionize marine biomonitoring. Whether using organism-specific quantitative PCR assays or metabarcoding in conjunction with amplicon sequencing, scientists have illustrated that realistic organism censuses can be inferred from eDNA. The next step is establishing ways to link information obtained from eDNA analyses to actual organism abundance. This is only possible by understanding the processes that control eDNA concentrations. The present study uses mesocosm experiments to study the persistence of eDNA in marine waters and explore the role of sunlight in modulating eDNA persistence. We seeded solute-permeable dialysis bags with water containing indigenous eDNA and suspended them in a large tank containing seawater. Bags were subjected to two treatments: half the bags were suspended near the water surface where they received high doses of sunlight, and half at depth where they received lower doses of sunlight. Bags were destructively sampled over the course of 87 hours. eDNA was extracted from water samples and used as template for a Scomber japonicus qPCR assay and a marine fish-specific 12S rRNA PCR assay. The latter was subsequently sequenced using a metabarcoding approach. S. japonicus eDNA, as measured by qPCR, exhibited first order decay with a rate constant ~0.01 hr -1 with no difference in decay rate constants between the two experimental treatments. eDNA metabarcoding identified 190 organizational taxonomic units (OTUs) assigned to varying taxonomic ranks. There was no difference in marine fish communities as measured by eDNA metabarcoding between the two experimental treatments, but there was an effect of time. Given the differences in UVA and UVB fluence received by the two experimental treatments, we conclude that sunlight is not the main driver of fish eDNA decay in the experiments. However, there are clearly temporal effects that need to be

  13. Persistence of marine fish environmental DNA and the influence of sunlight.

    PubMed

    Andruszkiewicz, Elizabeth A; Sassoubre, Lauren M; Boehm, Alexandria B

    2017-01-01

    Harnessing information encoded in environmental DNA (eDNA) in marine waters has the potential to revolutionize marine biomonitoring. Whether using organism-specific quantitative PCR assays or metabarcoding in conjunction with amplicon sequencing, scientists have illustrated that realistic organism censuses can be inferred from eDNA. The next step is establishing ways to link information obtained from eDNA analyses to actual organism abundance. This is only possible by understanding the processes that control eDNA concentrations. The present study uses mesocosm experiments to study the persistence of eDNA in marine waters and explore the role of sunlight in modulating eDNA persistence. We seeded solute-permeable dialysis bags with water containing indigenous eDNA and suspended them in a large tank containing seawater. Bags were subjected to two treatments: half the bags were suspended near the water surface where they received high doses of sunlight, and half at depth where they received lower doses of sunlight. Bags were destructively sampled over the course of 87 hours. eDNA was extracted from water samples and used as template for a Scomber japonicus qPCR assay and a marine fish-specific 12S rRNA PCR assay. The latter was subsequently sequenced using a metabarcoding approach. S. japonicus eDNA, as measured by qPCR, exhibited first order decay with a rate constant ~0.01 hr -1 with no difference in decay rate constants between the two experimental treatments. eDNA metabarcoding identified 190 organizational taxonomic units (OTUs) assigned to varying taxonomic ranks. There was no difference in marine fish communities as measured by eDNA metabarcoding between the two experimental treatments, but there was an effect of time. Given the differences in UVA and UVB fluence received by the two experimental treatments, we conclude that sunlight is not the main driver of fish eDNA decay in the experiments. However, there are clearly temporal effects that need to be

  14. Spectral analysis of extinguished sunlight

    NASA Astrophysics Data System (ADS)

    Zagury, Frédéric; Goutail, Florence

    2003-08-01

    SAOZ (Système d'Analyse par Observation Zénitale) is a balloon-borne experiment which determines the column density of several molecular species from the visible spectrum of sunlight. We will use sequence of spectra collected during a sunset to discuss atmospheric extinction, and the nature of the radiation field in the atmosphere. The radiation field in the atmosphere is, from daylight to sunset, and with a clear sky, dominated by light coming from the direction of the sun. This light is composed of direct sunlight (extinguished by the gas), and of sunlight forward-scattered by aerosols. As the sun sets, aerosol scattering is first perceived towards the UV. It progressively replaces direct sunlight over all of the spectrum. Our analysis permits fixing the main parameters of each component of the radiation field at any time. The fits we find for the extinction of sunlight in the atmosphere must also apply to starlight. Thus, the present work can be used in astronomy to correct ground-based spectral observations for extinction in the atmosphere.

  15. Nutrients in the Nation's Waters--Too Much of a Good Thing?

    USGS Publications Warehouse

    Mueller, David K.; Helsel, Dennis R.

    1996-01-01

    Historical data on nutrients (nitrogen and phosphorus) from about 12,000 ground-water and more than 22,000 stream samples have been compiled and related to possible sources. This existing information was collected by many agencies for a variety of purposes. Therefore, though it can be used to determine where concentrations differ, the exact percentages should not be taken as those for the Nation as a whole. Major findings include: (1) nutrient concentrations in water generally are related to land use in the area overlying ground-water aquifers or upstream from surface-water locations, (2) regional differences are related to differences in soil-drainage properties and agricultural practices, (3) nitrate concentrations in about 12 percent of domestic-supply wells in agricultural areas exceeded the U.S. Environmental Protection Agency's drinking-water standard (10 mg/L), and (4) nitrate concentrations in surface water rarely exceed the drinking-water standard. This information has helped identify locations across the Nation where ground water and streams are most likely to be vulnerable to nutrient contamination. Programs to manage and protect water resources can therefore be targeted to the most critical areas, providing the greatest protection for the least cost.

  16. Maximum Plant Uptakes for Water, Nutrients, and Oxygen Are Not Always Met by Irrigation Rate and Distribution in Water-based Cultivation Systems.

    PubMed

    Blok, Chris; Jackson, Brian E; Guo, Xianfeng; de Visser, Pieter H B; Marcelis, Leo F M

    2017-01-01

    Growing on rooting media other than soils in situ -i.e., substrate-based growing- allows for higher yields than soil-based growing as transport rates of water, nutrients, and oxygen in substrate surpass those in soil. Possibly water-based growing allows for even higher yields as transport rates of water and nutrients in water surpass those in substrate, even though the transport of oxygen may be more complex. Transport rates can only limit growth when they are below a rate corresponding to maximum plant uptake. Our first objective was to compare Chrysanthemum growth performance for three water-based growing systems with different irrigation. We compared; multi-point irrigation into a pond (DeepFlow); one-point irrigation resulting in a thin film of running water (NutrientFlow) and multi-point irrigation as droplets through air (Aeroponic). Second objective was to compare press pots as propagation medium with nutrient solution as propagation medium. The comparison included DeepFlow water-rooted cuttings with either the stem 1 cm into the nutrient solution or with the stem 1 cm above the nutrient solution. Measurements included fresh weight, dry weight, length, water supply, nutrient supply, and oxygen levels. To account for differences in radiation sum received, crop performance was evaluated with Radiation Use Efficiency (RUE) expressed as dry weight over sum of Photosynthetically Active Radiation. The reference, DeepFlow with substrate-based propagation, showed the highest RUE, even while the oxygen supply provided by irrigation was potentially growth limiting. DeepFlow with water-based propagation showed 15-17% lower RUEs than the reference. NutrientFlow showed 8% lower RUE than the reference, in combination with potentially limiting irrigation supply of nutrients and oxygen. Aeroponic showed RUE levels similar to the reference and Aeroponic had non-limiting irrigation supply of water, nutrients, and oxygen. Water-based propagation affected the subsequent

  17. Maximum Plant Uptakes for Water, Nutrients, and Oxygen Are Not Always Met by Irrigation Rate and Distribution in Water-based Cultivation Systems

    PubMed Central

    Blok, Chris; Jackson, Brian E.; Guo, Xianfeng; de Visser, Pieter H. B.; Marcelis, Leo F. M.

    2017-01-01

    Growing on rooting media other than soils in situ -i.e., substrate-based growing- allows for higher yields than soil-based growing as transport rates of water, nutrients, and oxygen in substrate surpass those in soil. Possibly water-based growing allows for even higher yields as transport rates of water and nutrients in water surpass those in substrate, even though the transport of oxygen may be more complex. Transport rates can only limit growth when they are below a rate corresponding to maximum plant uptake. Our first objective was to compare Chrysanthemum growth performance for three water-based growing systems with different irrigation. We compared; multi-point irrigation into a pond (DeepFlow); one-point irrigation resulting in a thin film of running water (NutrientFlow) and multi-point irrigation as droplets through air (Aeroponic). Second objective was to compare press pots as propagation medium with nutrient solution as propagation medium. The comparison included DeepFlow water-rooted cuttings with either the stem 1 cm into the nutrient solution or with the stem 1 cm above the nutrient solution. Measurements included fresh weight, dry weight, length, water supply, nutrient supply, and oxygen levels. To account for differences in radiation sum received, crop performance was evaluated with Radiation Use Efficiency (RUE) expressed as dry weight over sum of Photosynthetically Active Radiation. The reference, DeepFlow with substrate-based propagation, showed the highest RUE, even while the oxygen supply provided by irrigation was potentially growth limiting. DeepFlow with water-based propagation showed 15–17% lower RUEs than the reference. NutrientFlow showed 8% lower RUE than the reference, in combination with potentially limiting irrigation supply of nutrients and oxygen. Aeroponic showed RUE levels similar to the reference and Aeroponic had non-limiting irrigation supply of water, nutrients, and oxygen. Water-based propagation affected the subsequent

  18. Ocean color remote sensing using polarization properties of reflected sunlight

    NASA Technical Reports Server (NTRS)

    Frouin, R.; Pouliquen, E.; Breon, F.-M.

    1994-01-01

    The effects of the atmosphere and surface on sunlight backscattered to space by the ocean may be substantially reduced by using the unpolarized component of reflectance instead of total reflectance. At 450 nm, a wavelength of interest in ocean color remote sensing, and for typical conditions, 45% of the unpolarized reflectance may originate from the water body instead of 20% of the total reflectance, which represents a gain of a factor 2.2 in useful signal for water composition retrieval. The best viewing geometries are adjacent to the glitter region; they correspond to scattering angles around 100 deg, but they may change slightly depending on the polarization characteristics of the aerosols. As aerosol optical thickness increases, the atmosphere becomes less efficient at polarizing sunlight, and the enhancement of the water body contribution to unpolarized reflectance is reduced. Since the perturbing effects are smaller on unpolarized reflectance, at least for some viewing geometries, they may be more easily corrected, leading to a more accurate water-leaving signal and, therefore, more accurate estimates of phytoplankton pigment concentration.

  19. Surface-Water Nutrient Conditions and Sources in the United States Pacific Northwest1

    PubMed Central

    Wise, Daniel R; Johnson, Henry M

    2011-01-01

    Abstract The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts. PMID:22457584

  20. Uniform sunlight concentration reflectors for photovoltaic cells.

    PubMed

    Rabady, Rabi Ibrahim

    2014-03-20

    Sunlight concentration is essential to reach high temperatures of a working fluid in solar-thermal applications and to reduce the cost of photovoltaic (PV) electricity generation systems. Commonly, sunlight concentration is realized by parabolic or cylindrical reflectors, which do not provide uniform concentration on the receiver finite surface. Uniform concentration of sunlight is favored especially for the PV conversion applications since it not only enhances the conversion efficiency of sunlight but also reduces the thermal variations along the receiving PV cell, which can be a performance and life-span limiting factor. In this paper a reflector profile that uniformly infiltrates the concentrated sunlight into the receiving unit is attempted. The new design accounts for all factors that contribute to the nonuniform concentration, like the reflector curvature, which spatially reflects the sunlight nonuniformly, and the angular dependency of both the reflector reflectivity and the sunlight transmission through the PV cell.

  1. Nutrient fluxes across sediment-water interface in Bohai Bay Coastal Zone, China.

    PubMed

    Mu, Di; Yuan, Dekui; Feng, Huan; Xing, Fangwei; Teo, Fang Yenn; Li, Shuangzhao

    2017-01-30

    Sediment cores and overlying water samples were collected at four sites in Tianjin Coastal Zone, Bohai Bay, to investigate nutrient (N, P and Si) exchanges across the sediment-water interface. The exchange fluxes of each nutrient species were estimated based on the porewater profiles and laboratory incubation experiments. The results showed significant differences between the two methods, which implied that molecular diffusion alone was not the dominant process controlling nutrient exchanges at these sites. The impacts of redox conditions and bioturbation on the nutrient fluxes were confirmed by the laboratory incubation experiments. The results from this study showed that the nutrient fluxes measured directly from the incubation experiment were more reliable than that predicted from the porewater profiles. The possible impacts causing variations in the nutrient fluxes include sewage discharge and land reclamation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Stainless steel in coastal seawater: sunlight counteracts biologically enhanced cathodic kinetics.

    PubMed

    Eashwar, M; Lakshman Kumar, A; Sreedhar, G; Kennedy, J; Suresh Bapu, R H

    2014-09-01

    The influence of sunlight of varying intensity on the performance of UNS S30400 stainless steel (SS) was explored under conditions of natural biofilm development in coastal seawater. In a series of tests performed outdoors under an opaque roof, a range of shades were fashioned to impart varied amounts of diurnal light. These were an ambient level where the underwater illumination was ~ 5% of full sunlight, two intermediate ranges of lighting with ~ 2.5% and ~ 1% of the daylight, and a condition of full darkness. In comparison with the dark, increments of sunlight rendered the SS progressively less aggressive as cathodes in galvanic couples with UNS C70600 alloy. Likewise, welded SS with pre-initiated localized corrosion sites exhibited substantially lower rates of propagation with light. Thus, biofilms and sunlight affected cathodic kinetics in opposite ways. Surface analytical tests showed that the accumulation of manganese (Mn) within the biofilms was small relative to reports from waters of lower salinity. These results not only reveal that extremely low amounts of sunlight are adequate to offset the microbial effect, but also highlight the lack of convincing evidence for Mn cycling as a potent mechanism for enhanced cathodic kinetics in full-strength seawater.

  3. Air/water exchange of mercury in the Everglades I: the behavior of dissolved gaseous mercury in the Everglades Nutrient Removal Project

    PubMed

    Zhang; Lindberg

    2000-10-02

    From 1996 to 1998 we determined dissolved gaseous mercury (DGM) in waters of the Everglades Nutrient Removal Project (ENR), a constructed wetlands. The concentrations of DGM measured in these waters (mean 7.3 +/- 9.5 pg l(-1)) are among the lowest reported in the literature, and suggest a system often near or slightly above equilibrium with Hg in ambient air. DGM exhibited both seasonal and diel trends, peaking at midday and during the summer. A simple box budget model of DGM in waters of the Everglades was developed using an interactive spreadsheet based on a mass balance among light-induced reduction of HgII (production of DGM), Hg0 oxidation (removal), and Hg0 evasion in a box (water column) consisting of a surface region with sunlight available and a lower dark region. The modeling results suggest high sensitivity of hourly DGM concentrations to DGM production rates and initial DGM levels. The sensitivity to Hg oxidation is lower than the sensitivity to DGM production. The model performance demonstrates successful simulations of a variety of DGM trends in the Everglades. In particular, it clearly demonstrates how it is possible to measure comparable rates of evasion over several Everglades sites with different DGM concentrations.

  4. Disinfection of Airborne Organisms by Ultraviolet-C Radiation and Sunlight

    DTIC Science & Technology

    2012-07-01

    organisms deposited on surfaces, suspended in water , and contaminating food, all of which have been discussed elsewhere (Block, 2001). In contrast, the... water . Therefore, the primary means for organism inactivation in aerosols is ultraviolet (UV) radiation. Radiation from the sunlight is used as a...cortex is essential for reduction of the water content in the spore core and formation of a dormant spore. The cortex is degraded in spore

  5. Evidence for alteration in chemical and physical properties of water and modulation of its biological functions by sunlight transmitted through color ranges of the visible spectrum-a novel study.

    PubMed

    Cohly, Hari H P; Panja, Asit; Reno, William L; Obenhuber, Don; Koelle, Margot S; Das, Suman K; Angel, Michael F; Rao, M Rajeswara

    2005-08-01

    We investigated the changes in the properties of water when exposed to sunlight for 40 days. We hypothesize and prove that solar irradiation to water entraps electromagnetic radiation as potential energy, which becomes kinetic energy in various systems. It is postulated that photochemically-induced energy transfers, associated with individual spectral emission of visible spectrum of solar light, exert diverse influences on biological systems. Bottles of distilled water, individually wrapped in spectral-colored cellophane were exposed to sunlight and compared to an unwrapped bottle to determine chemical and physical changes as well as modifications of biological properties. Each bottle of water was named according to the color of cellophane paper with letter E (stands for exposed) as a prefix with (E-violet, E-indigo, E-blue, E-green, E-yellow, E-orange, and E-red). E-control (without wrap) was exposed to polychromatic sunlight. This study addresses two main issues viz., the chemical and physical changes in E-water and its effect on biological activities. Chemical and physical composition analysis using inductively coupled plasma atomic emission spectrometry; physical conductance by a Wheatstone Bridge type conductivity meter; osmolarity by a vapor pressure osmometer; and, salt solubility profile of 10% sodium bicarbonate were determined. Furthermore, testing the effect of E-waters on human lymphocyte proliferation, mosquito larvae hatching and seed germination determined the functional role of solar radiation through specific spectrum/s of visible light on various biological processes. We found that water exposed to visible spectral emissions of sunlight had an altered elemental composition, electrical conductance, osmolarity and salt-solubility, as well as differences in bio-modulatory effects. A gradual increase in leaching of Boron from E-violet to E-red was noted. E-indigo showed maximal increase in electrical conductance and maximal salt solubility of sodium

  6. Evidence for Alteration in Chemical and Physical Properties of Water and Modulation of its Biological Functions by Sunlight Transmitted through Color Ranges of the Visible Spectrum-A Novel Study

    PubMed Central

    Cohly, Hari H. P.; Panja, Asit; Reno, William L.; Obenhuber, Don; Koelle, Margot S.; Das, Suman K.; Angel, Michael F.; Rao, M. Rajeswara

    2005-01-01

    We investigated the changes in the properties of water when exposed to sunlight for 40 days. We hypothesize and prove that solar irradiation to water entraps electromagnetic radiation as potential energy, which becomes kinetic energy in various systems. It is postulated that photochemically-induced energy transfers, associated with individual spectral emission of visible spectrum of solar light, exert diverse influences on biological systems. Bottles of distilled water, individually wrapped in spectral-colored cellophane were exposed to sunlight and compared to an unwrapped bottle to determine chemical and physical changes as well as modifications of biological properties. Each bottle of water was named according to the color of cellophane paper with letter E (stands for exposed) as a prefix with (E-violet, E-indigo, E-blue, E-green, E-yellow, E-orange, and Ered). E-control (without wrap) was exposed to polychromatic sunlight. This study addresses two main issues viz., the chemical and physical changes in E-water and its effect on biological activities. Chemical and physical composition analysis using inductively coupled plasma atomic emission spectrometry; physical conductance by a Wheatstone Bridge type conductivity meter; osmolarity by a vapor pressure osmometer; and, salt solubility profile of 10% sodium bicarbonate were determined. Furthermore, testing the effect of E-waters on human lymphocyte proliferation, mosquito larvae hatching and seed germination determined the functional role of solar radiation through specific spectrum/s of visible light on various biological processes. We found that water exposed to visible spectral emissions of sunlight had an altered elemental composition, electrical conductance, osmolarity and salt-solubility, as well as differences in bio-modulatory effects. A gradual increase in leaching of Boron from E-violet to E-red was noted. E-indigo showed maximal increase in electrical conductance and maximal salt solubility of sodium

  7. Nutrients in waters on the inner shelf between Cape Charles and Cape Hatteras

    NASA Technical Reports Server (NTRS)

    Wong, G. T. F.; Todd, J. F.

    1981-01-01

    The distribution of nutrients in the shelf waters of the southern tip of the Middle Atlantic Bight was investigated. It is concluded that the outflow of freshwater from the Chesapeake Bay is a potential source of nutrients to the adjacent shelf waters. However, a quantitative estimation of its importance cannot yet be made because (1) there are other sources of nutrients to the study area and these sources cannot yet be quantified and (2) the concentrations of nutrients in the outflow from Chesapeake Bay exhibit significant short-term and long-term temporal variabilities.

  8. Long term growth responses of loblolly pine to optimal nutrient and water resource availability

    Treesearch

    Timothy J. Albaugh; H. Lee Allen; Phillip M. Dougherty; Kurt H. Johnsen

    2004-01-01

    A factorial combination of four treatments (control (CW), optimal growing season water availability (IW), optimum nutrient availability (FW), and combined optimum water and nutrient availability (FIW)) in four replications were initiated in an 8-year- old Pinus taeda stand growing on a droughty, nutrient-poor, sandy site in Scotland County, NC and...

  9. Effects of nutrient management on nitrate levels in ground water near Ephrata Pennsylvania

    USGS Publications Warehouse

    Hall, David W.

    1992-01-01

    Effects of the implementation of nutrient management practices on ground-water quality were studied at a 55-acre farm in Lancaster County, Pennsylvania, from 1985-90. After nutrient management practices were implemented at the site in October 1986, statistically significant decreases (Wilcoxon Mann-Whitney test) in median nitrate concentrations in ground-water samples occurred at four of the five wells monitored. The largest decreases in nitrate concentration occurred in samples collected at the wells that had the largest nitrate concentrations prior to nutrient management. The decreases in median nitrate concentrations in ground-water samples ranged from 8 to 32 percent of the median concentrations prior to nutrient management and corresponded to nitrogen application decreases of 39 to 67 percent in contributing areas that were defined upgradient of these wells. Changes in nitrogen applications to the contributing areas of five water wells were correlated (Spearman rank-sum test) with nitrate concentrations of the well water. Changes in ground-water nitrate concentrations lagged behind the changes in applied-nitrogen fertilizers (primarily manure) by approximately 4 to 19 months.

  10. Sunlight exposure: Do health benefits outweigh harm?

    PubMed

    Razzaque, Mohammed S

    2018-01-01

    Vitamin D is a fat-soluble vitamin whose levels within the body are elevated following sunlight exposure. Numerous studies have shown that sunlight exposure can provide protection to a wide variety of diseases, ranging from different types of tumors to hypertension to type 1 diabetes to multiple sclerosis. Moreover, studies have shown that avoiding sunlight may influence the initiation and progression of some of these diseases. Avoidance of sunlight, coupled with the inclination towards consuming supplements, is becoming the primary choice to obtain vitamin D. The purpose of this article is to present evidences from published literature, to show that the expected benefits of vitamin D supplements are minimized by the potential risk of cardiovascular events and beyond. Since hypovitaminosis D status usually reflects reduced sunlight exposure, the obvious primary replacement should be safe sunlight exposure, and not exogenous supplements. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Measuring nutrient flux in Pacific Coast salt marshes using fluctuating water-level chambers

    EPA Science Inventory

    Nutrient removal from the water column is an important ecosystem function that contributes to the production of clean water, a final valued ecosystem service of wetlands. However, little data is currently available for nutrient exchange in Pacific Northwest tidal ecosystems. We h...

  12. Sunlight, vitamin D and food allergy.

    PubMed

    Rudders, Susan A; Camargo, Carlos A

    2015-08-01

    The role of vitamin D in the development of food allergy is unclear. We summarize recent data on the epidemiologic link between sunlight (UVB) and food allergy, and evidence for and against a specific role for vitamin D status. Since 2007, most epidemiologic studies have supported low sunlight (as measured by season of birth and latitude) as a risk factor for food allergy. Investigators have also looked directly at vitamin D status (as measured by serum 25OHD level) and its potential role. Although conflicting, the vitamin D studies suggest a more complicated association than a linear dose response in all individuals, with some studies indicating different associations based on host characteristics (e.g. concominant eczema, genetic polymorphisms, country of birth). Most studies have not fully examined the myriad effects of sunlight but have instead focused on a single maternal, neonatal or childhood 25OHD level. Many studies have linked sunlight with the development of food allergy but whether this is directly related to vitamin D status or a myriad of other sunlight-derived, seasonal and/or geographic factors remains uncertain. More studies are needed to investigate the role of sunlight and vitamin D status in food allergy because of their potential for primary prevention and disease modification.

  13. Novel biochar-impregnated calcium alginate beads with improved water holding and nutrient retention properties.

    PubMed

    Wang, Bing; Gao, Bin; Zimmerman, Andrew R; Zheng, Yulin; Lyu, Honghong

    2018-03-01

    Drought conditions and nutrients loss have serious impacts on soil quality as well as crop yields in agroecosystems. New techniques are needed to carry out effective soil water and nutrient conservation and fertilizer application tools. Here, calcium alginate (CA) beads impregnated with ball-milled biochar (BMB) were investigated as a new type of water/nutrients retention agent. Both CA and Ca-alginate/ball milled biochar composite (CA-BMB) beads showed high kinetic swelling ratios in KNO 3 solution and low kinetic swelling ratios in water, indicating that CA-BMB beads have the potential to retain mineral nitrogen and nutrients by ion exchange. Pseudo-second-order kinetic model well-described the swelling kinetics of both beads in KNO 3 solution. Over a range of temperatures, the characteristics of dehydration suggested that impregnation with BMB improved the water holding capacity and postponed the dehydration time of Ca-alginate. The cumulative swelling and release characteristics of water, K + , and NO 3 - indicated that CA-BMB beads have great potential as a soil amendment to improve its nutrient retention and water holding capacity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Root cortical senescence decreases root respiration, nutrient content and radial water and nutrient transport in barley.

    PubMed

    Schneider, Hannah M; Wojciechowski, Tobias; Postma, Johannes A; Brown, Kathleen M; Lücke, Andreas; Zeisler, Viktoria; Schreiber, Lukas; Lynch, Jonathan P

    2017-08-01

    The functional implications of root cortical senescence (RCS) are poorly understood. We tested the hypotheses that RCS in barley (1) reduces the respiration and nutrient content of root tissue; (2) decreases radial water and nutrient transport; and (3) is accompanied by increased suberization to protect the stele. Genetic variation for RCS exists between modern germplasm and landraces. Nitrogen and phosphorus deficiency increased the rate of RCS. Maximal RCS, defined as the disappearance of the entire root cortex, reduced root nitrogen content by 66%, phosphorus content by 63% and respiration by 87% compared with root segments with no RCS. Roots with maximal RCS had 90, 92 and 84% less radial water, nitrate and phosphorus transport, respectively, compared with segments with no RCS. The onset of RCS coincided with 30% greater aliphatic suberin in the endodermis. These results support the hypothesis that RCS reduces root carbon and nutrient costs and may therefore have adaptive significance for soil resource acquisition. By reducing root respiration and nutrient content, RCS could permit greater root growth, soil resource acquisition and resource allocation to other plant processes. RCS merits investigation as a trait for improving the performance of barley, wheat, triticale and rye under edaphic stress. © 2017 John Wiley & Sons Ltd.

  15. Nutrient availability and nutrient use efficiency in plants growing in the transition zone between land and water.

    PubMed

    Cavalli, G; Baattrup-Pedersen, A; Riis, T

    2016-03-01

    The transition zone between terrestrial and freshwater habitats is highly dynamic, with large variability in environmental characteristics. Here, we investigate how these characteristics influence the nutritional status and performance of plant life forms inhabiting this zone. Specifically, we hypothesised that: (i) tissue nutrient content differs among submerged, amphibious and terrestrial species, with higher content in submerged species; and (ii) PNUE gradually increases from submerged over amphibious to terrestrial species, reflecting differences in the availability of N and P relative to inorganic C across the land-water ecotone. We found that tissue nutrient content was generally higher in submerged species and C:N and C:P ratios indicated that content was limiting for growth for ca. 20% of plant individuals, particularly those belonging to amphibious and terrestrial species groups. As predicted, the PNUE increased from submerged over amphibious to terrestrial species. We suggest that this pattern reflects that amphibious and terrestrial species allocate proportionally more nutrients into processes of importance for photosynthesis at saturating CO2 availability, i.e. enzymes involved in substrate regeneration, compared to submerged species that are acclimated to lower availability of CO2 in the aquatic environment. Our results indicate that enhanced nutrient loading may affect relative abundance of the three species groups in the land-water ecotone of stream ecosystems. Thus, species of amphibious and terrestrial species groups are likely to benefit more from enhanced nutrient availability in terms of faster growth compared to aquatic species, and that this can be detrimental to aquatic species growing in the land-water ecotone, e.g. Ranunculus and Callitriche. © 2015 German Botanical Society and The Royal Botanical Society of the Netherlands.

  16. Nutrient storage rates in a national marsh receiving waste water

    Treesearch

    J.A. Nyman

    2000-01-01

    Artificial wetlands are commonly used to improve water quality in rivers and the coastal zone. In most wetlands associated with rivers, denitrification is probably the primary process that reduces nutrient loading. Where rivers meet oceans, however, significant amounts of nutrients might be permanently buried in wetlands because of global sea-level rise and regional...

  17. External nutrient loading from land, sea and atmosphere to all 656 Swedish coastal water bodies.

    PubMed

    Bryhn, Andreas C; Dimberg, Peter H; Bergström, Lena; Fredriksson, Ronny E; Mattila, Johanna; Bergström, Ulf

    2017-01-30

    Identifying the main sources of nutrient loading is a key factor for efficient mitigation of eutrophication. This study has investigated the pathways of external nutrient loading to 656 coastal water bodies along the entire Swedish coastline. The studied water bodies have been delineated to meet requirements in the European Union's Water Framework Directive, and recent status assessments have shown that 57% of them fail to attain good or high ecological status with respect to nutrients. The analysis in the study was performed on data from mass-balance based nutrient budgets computed using the modelling framework Vattenwebb. The external nutrient contribution from the sea to the water bodies was highly variable, ranging from about 1% to nearly 100%, but the median contribution was >99% of the total external loading regarding both nitrogen and phosphorus. External loading from the atmosphere and local catchment area played a minor role in general. However, 45 coastal water bodies received >25% of the external nitrogen and phosphorus from their catchments. Loading from land typically peaked in April following ice-break and snow melting and was comparatively low during summer. The results indicate that for many eutrophicated Swedish coastal water bodies, nutrient abatement is likely to be optimally effective when potential measures in all of the catchment area of the concerned sea basin are considered. Local-scale mitigation in single water bodies will likely be locally effective only in the small proportion of areas where water and thereby also nutrient input from the catchment is high compared to the influx from the sea. Future studies should include nutrient reduction scenarios in order to refine these conclusions and to identify relevant spatial scales for coastal eutrophication mitigation measures from a water body perspective. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Life-cycle analysis on biodiesel production from microalgae: water footprint and nutrients balance.

    PubMed

    Yang, Jia; Xu, Ming; Zhang, Xuezhi; Hu, Qiang; Sommerfeld, Milton; Chen, Yongsheng

    2011-01-01

    This research examines the life-cycle water and nutrients usage of microalgae-based biodiesel production. The influence of water types, operation with and without recycling, algal species, geographic distributions are analyzed. The results confirm the competitiveness of microalgae-based biofuels and highlight the necessity of recycling harvested water and using sea/wastewater as water source. To generate 1 kg biodiesel, 3726 kg water, 0.33 kg nitrogen, and 0.71 kg phosphate are required if freshwater used without recycling. Recycling harvest water reduces the water and nutrients usage by 84% and 55%. Using sea/wastewater decreases 90% water requirement and eliminates the need of all the nutrients except phosphate. The variation in microalgae species and geographic distribution are analyzed to reflect microalgae biofuel development in the US. The impacts of current federal and state renewable energy programs are also discussed to suggest suitable microalgae biofuel implementation pathways and identify potential bottlenecks. Copyright © 2010 Elsevier Ltd. All rights reserved.

  19. Intestinal Water Absorption Varies with Expected Dietary Water Load among Bats but Does Not Drive Paracellular Nutrient Absorption.

    PubMed

    Price, Edwin R; Brun, Antonio; Gontero-Fourcade, Manuel; Fernández-Marinone, Guido; Cruz-Neto, Ariovaldo P; Karasov, William H; Caviedes-Vidal, Enrique

    2015-01-01

    Rapid absorption and elimination of dietary water should be particularly important to flying species and were predicted to vary with the water content of the natural diet. Additionally, high water absorption capacity was predicted to be associated with high paracellular nutrient absorption due to solvent drag. We compared the water absorption rates of sanguivorous, nectarivorous, frugivorous, and insectivorous bats in intestinal luminal perfusions. High water absorption rates were associated with high expected dietary water load but were not highly correlated with previously measured rates of (paracellular) arabinose clearance. In conjunction with these tests, we measured water absorption and the paracellular absorption of nutrients in the intestine and stomach of vampire bats using luminal perfusions to test the hypothesis that the unique elongated vampire stomach is a critical site of water absorption. Vampire bats' gastric water absorption was high compared to mice but not compared to their intestines. We therefore conclude that (1) dietary water content has influenced the evolution of intestinal water absorption capacity in bats, (2) solvent drag is not the only driver of paracellular nutrient absorption, and (3) the vampire stomach is a capable but not critical location for water absorption.

  20. Biodegradation and photooxidation of crude oil under natural sunlight in the northern Gulf of Mexico

    NASA Astrophysics Data System (ADS)

    Bacosa, H. P.; Erdner, D.; Liu, Z.

    2016-02-01

    An enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico (nGoM) following the Deepwater Horizon (DWH) spill. While the oil degradation and bacterial communities in the deep-sea plume have been widely investigated, the effect of sunlight on oil and bacterial assemblages in surface waters have received less attention. In this study, we amended surface water collected near the DWH site with crude oil and/or Corexit dispersant and incubated under natural sunlight in the nGoM for 36 d in summer of 2013. The residual alkanes, polycyclic aromatic hydrocarbons (PAHs), and alkalyted PAHs were analyzed by GC-MS, and bacterial community was determined via pyrosequencing. The results show that n-alkane biodegradation rate constants (first order) were ca. ten-fold higher than the photooxidation rate constants. While biodegradation was characterized by a lag phase, photooxidation rate constants for the 2-3 ring and 4-5 ring PAHs, were 0.08-0.98 day-1 and 0.01-0.07 day-1, respectively. Compared to biodegradation, photooxidation increased the transformation of 4-5 ring PAHs by 70% and 3-4 ring alkylated PAHs by 36%. Sunlight significantly reduced bacterial diversity and a driver of shifts in bacterial community structure in oil and Corexit treatments. In amended treatments, sunlight increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Halomonas and Bartonella, while the dark treatments enriched Thalassobius, Winogradskyella, Alcanivorax, Formosa, Eubacterium, Erythrobacter, Natronocella, and Pseudomonas. This suggests that different bacteria are degrading the hydrocarbons in the dark and under light exposure. In a follow up study using DNA-Stable isotope probing (SIP), we identified the alkane and PAH degraders using 13C-labeled hexadecane and phenanthrene, respectively. The results of metagenomic and metatranscriptomic analyses in the light and dark incubations will be presented. For the first

  1. Fluvial fluxes of water, suspended particulate matter, and nutrients and potential impacts on tropical coastal water Biogeochemistry: Oahu, Hawai'i

    USGS Publications Warehouse

    Hoover, D.J.; MacKenzie, F.T.

    2009-01-01

    Baseflow and storm runoff fluxes of water, suspended particulate matter (SPM), and nutrients (N and P) were assessed in conservation, urban, and agricultural streams discharging to coastal waters around the tropical island of Oahu, Hawai'i. Despite unusually low storm frequency and intensity during the study, storms accounted for 8-77% (median 30%) of discharge, 57-99% (median 93%) of SPM fluxes, 11-79% (median 36%) of dissolved nutrient fluxes and 52-99% (median 85%) of particulate nutrient fluxes to coastal waters. Fluvial nutrient concentrations varied with hydrologic conditions and land use; land use also affected water and particulate fluxes at some sites. Reactive dissolved N:P ratios typically were ???16 (the 'Redfield ratio' for marine phytoplankton), indicating that inputs could support new production by coastal phytoplankton, but uptake of dissolved nutrients is probably inefficient due to rapid dilution and export of fluvial dissolved inputs. Particulate N and P fluxes were similar to or larger than dissolved fluxes at all sites (median 49% of total nitrogen, range 22-82%; median 69% of total phosphorus, range 49-93%). Impacts of particulate nutrients on coastal ecosystems will depend on how efficiently SPM is retained in nearshore areas, and on the timing and degree of transformation to reactive dissolved forms. Nevertheless, the magnitude of particulate nutrient fluxes suggests that they represent a significant nutrient source for many coastal ecosystems over relatively long time scales (weeks-years), and that reductions in particulate nutrient loading actually may have negative impacts on some coastal ecosystems.

  2. Modeling the Endogenous Sunlight Inactivation Rates of Laboratory Strain and Wastewater E. coli and Enterococci Using Biological Weighting Functions.

    PubMed

    Silverman, Andrea I; Nelson, Kara L

    2016-11-15

    Models that predict sunlight inactivation rates of bacteria are valuable tools for predicting the fate of pathogens in recreational waters and designing natural wastewater treatment systems to meet disinfection goals. We developed biological weighting function (BWF)-based numerical models to estimate the endogenous sunlight inactivation rates of E. coli and enterococci. BWF-based models allow the prediction of inactivation rates under a range of environmental conditions that shift the magnitude or spectral distribution of sunlight irradiance (e.g., different times, latitudes, water absorbances, depth). Separate models were developed for laboratory strain bacteria cultured in the laboratory and indigenous organisms concentrated directly from wastewater. Wastewater bacteria were found to be 5-7 times less susceptible to full-spectrum simulated sunlight than the laboratory bacteria, highlighting the importance of conducting experiments with bacteria sourced directly from wastewater. The inactivation rate models fit experimental data well and were successful in predicting the inactivation rates of wastewater E. coli and enterococci measured in clear marine water by researchers from a different laboratory. Additional research is recommended to develop strategies to account for the effects of elevated water pH on predicted inactivation rates.

  3. Influence of Sea Ice Crack Formation on the Spatial Distribution of Nutrients and Microalgae in Flooded Antarctic Multiyear Ice

    NASA Astrophysics Data System (ADS)

    Nomura, Daiki; Aoki, Shigeru; Simizu, Daisuke; Iida, Takahiro

    2018-02-01

    Cracks are common and natural features of sea ice formed in the polar oceans. In this study, a sea ice crack in flooded, multiyear, land-fast Antarctic sea ice was examined to assess its influence on biological productivity and the transport of nutrients and microalgae into the upper layers of neighboring sea ice. The water inside the crack and the surrounding host ice were characterized by a strong discoloration (brown color), an indicator of a massive algal bloom. Salinity and oxygen isotopic ratio measurements indicated that 64-84% of the crack water consisted of snow meltwater supplied during the melt season. Measurements of nutrient and chlorophyll a concentrations within the slush layer pool (the flooded layer at the snow-ice interface) revealed the intrusion of water from the crack, likely forced by mixing with underlying seawater during the tidal cycle. Our results suggest that sea ice crack formation provides conditions favorable for algal blooms by directly exposing the crack water to sunlight and supplying nutrients from the under-ice water. Subsequently, constituents of the crack water modified by biological activity were transported into the upper layer of the flooded sea ice. They were then preserved in the multiyear ice column formed by upward growth of sea ice caused by snow ice formation in areas of significant snow accumulation.

  4. Modeling the Transport and Fate of Fecal Pollution and Nutrients of Miyun Reservoir

    NASA Astrophysics Data System (ADS)

    Liu, L.; Fu, X.; Wang, G.

    2009-12-01

    Miyun Reservoir, a mountain valley reservoir, is located 100 km northeast of Beijing City. Besides the functions of flood control, irrigation and fishery for Beijing area, Miyun Reservoir is the main drinking water storage for Beijing city. The water quality is therefore of great importance. Recently, the concentration of fecal pollution and nutrients in the reservoir are constantly rising to arrest the attention of Beijing municipality. Fecal pollution from sewage is a significant public health concern due to the known presence of human viruses and parasites in these discharges. To investigate the transport and fate of the fecal pollution and nutrients at Miyun reservoir and the health risks associated with drinking and fishery, the reservoir and two tributaries, Chaohe river and Baihe river discharging into it are being examined for bacterial, nutrients and other routine pollution. To understand the relative importance of different processes influencing pollution transport and inactivation, a finite-element model of surf-zone hydrodynamics (coupled with models for temperature, fecal pollution, nutrients and other routine contaminants) is used. The developed models are being verified by the observed water quality data including water temperature, conductivities and dissolved oxygen from the reservoir and its tributaries. Different factors impacting the inactivation of fecal pollution and the transport of nutrients such as water temperature, sedimentation, sunlight insolation are evaluated for Miyun reservoir by a sensitivity analysis analogized from the previous research of Lake Michigan (figure 1, indicating that solar insolation dominates the inactivation of E. Coli, an indicator of fecal pollution, Liu et al. 2006). The calibrated modeling system can be used to temporally and spatially simulate and predict the variation of the concentration of fecal pollution and nutrients of Miyun reservoir. Therefore this research can provide a forecasting tool for the

  5. Couplings of watersheds and coastal waters: Sources and consequences of nutrient enrichment in Waquoit Bay, Massachusetts

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Valiela, I.; Foreman, K.; LaMontagne, M.

    1992-12-01

    Human activities on coastal watersheds provide the major sources of nutrients entering shallow coastal ecosystems. Nutrient loadings from watersheds alter structure and function of receiving aquatic ecosystems. To investigate this coupling of land to marine systems, a series of subwatersheds of Waquoit Bay differing in degree of urbanization and with widely different nutrient loading rates was studied. The subwatersheds differ in septic tanks numbers and forest acreage. Ground water is the major mechanism that transports nutrients to coastal waters. Some attenuation of nutrient concentrations within the aquifer or at the sediment-water interface, but significant increases in the nutrient content ofmore » groundwater arriving at the shore's edge are in urbanized areas. The groundwater flows through the sediment-water boundary, and sufficient groundwater-borne nutrients (nitrogen in particular) traverse the sediment-water boundary to cause significant changes in the aquatic ecosystem. These loading-dependent alterations include increased nutrients in water, greater primary production by phytoplankton, and increased macroalgal biomass and growth. The increased macroalgal biomass dominates the bay ecosystem through second- or third-order effects such as alterations of nutrient status of water columns and increasing frequency of anoxic events. The increases in seaweeds have decreased the areas covered by eelgrass habitats. The change in habitat type, plus the increased frequency of anoxic events, change the composition of the benthic fauna. The importance of bottom-up control in shallow coastal food webs is evident. The coupling of land to sea by groundwater-borne nutrient transport is mediated by a complex series of steps, making it unlikely to find a one-to-one relation between land use and conditions in the aquatic ecosystem. Appropriate models may provide a way to deal with the complexities of the coupling. 22 refs., 14 figs., 5 tabs.« less

  6. Impact of climate change on crop nutrient and water use efficiencies.

    PubMed

    Brouder, Sylvie M; Volenec, Jeffrey J

    2008-08-01

    Implicit in discussions of plant nutrition and climate change is the assumption that we know what to do relative to nutrient management here and now but that these strategies might not apply in a changed climate. We review existing knowledge on interactive influences of atmospheric carbon dioxide concentration, temperature and soil moisture on plant growth, development and yield as well as on plant water use efficiency (WUE) and physiological and uptake efficiencies of soil-immobile nutrients. Elevated atmospheric CO(2) will increase leaf and canopy photosynthesis, especially in C3 plants, with minor changes in dark respiration. Additional CO(2) will increase biomass without marked alteration in dry matter partitioning, reduce transpiration of most plants and improve WUE. However, spatiotemporal variation in these attributes will impact agronomic performance and crop water use in a site-specific manner. Nutrient acquisition is closely associated with overall biomass and strongly influenced by root surface area. When climate change alters soil factors to restrict root growth, nutrient stress will occur. Plant size may also change but nutrient concentration will remain relatively unchanged; therefore, nutrient removal will scale with growth. Changes in regional nutrient requirements will be most remarkable where we alter cropping systems to accommodate shifts in ecozones or alter farming systems to capture new uses from existing systems. For regions and systems where we currently do an adequate job managing nutrients, we stand a good chance of continued optimization under a changed climate. If we can and should do better, climate change will not help us.

  7. Interactions between plant nutrients, water and carbon dioxide as factors limiting crop yields

    PubMed Central

    Gregory, P. J.; Simmonds, L. P.; Warren, G. P.

    1997-01-01

    Biomass production of annual crops is often directly proportional to the amounts of radiation intercepted, water transpired and nutrients taken up. In many places the amount of rainfall during the period of rapid crop growth is less than the potential rate of evaporation, so that depletion of stored soil water is commonplace. The rate of mineralization of nitrogen (N) from organic matter and the processes of nutrient loss are closely related to the availability of soil water. Results from Kenya indicate the rapid changes in nitrate availability following rain.
    Nutrient supply has a large effect on the quantity of radiation intercepted and hence, biomass production. There is considerable scope for encouraging canopy expansion to conserve water by reducing evaporation from the soil surface in environments where it is frequently rewetted, and where the unsaturated hydraulic conductivity of the soil is sufficient to supply water at the energy limited rate (e.g. northern Syria). In regions with high evaporative demand and coarse-textured soils (e.g. Niger), transpiration may be increased by management techniques that reduce drainage.
    Increases in atmospheric [CO2] are likely to have only a small impact on crop yields when allowance is made for the interacting effects of temperature, and water and nutrient supply.

  8. Nutrient and dissolved organic carbon removal from natural waters using industrial by-products.

    PubMed

    Wendling, Laura A; Douglas, Grant B; Coleman, Shandel; Yuan, Zheng

    2013-01-01

    Attenuation of excess nutrients in wastewater and stormwater is required to safeguard aquatic ecosystems. The use of low-cost, mineral-based industrial by-products with high Ca, Mg, Fe or Al content as a solid phase in constructed wetlands potentially offers a cost-effective wastewater treatment option in areas without centralised water treatment facilities. Our objective was to investigate use of water treatment residuals (WTRs), coal fly ash (CFA), and granular activated carbon (GAC) from biomass combustion in in-situ water treatment schemes to manage dissolved organic carbon (DOC) and nutrients. Both CaO- and CaCO(3)-based WTRs effectively attenuated inorganic N species but exhibited little capacity for organic N removal. The CaO-based WTR demonstrated effective attenuation of DOC and P in column trials, and a high capacity for P sorption in batch experiments. Granular activated carbon proved effective for DOC and dissolved organic nitrogen (DON) removal in column trials, but was ineffective for P attenuation. Only CFA demonstrated effective removal of a broad suite of inorganic and organic nutrients and DOC; however, Se concentrations in column effluents exceeded Australian and New Zealand water quality guideline values. Water treated by filtering through the CaO-based WTR exhibited nutrient ratios characteristic of potential P-limitation with no potential N- or Si-limitation respective to growth of aquatic biota, indicating that treatment of nutrient-rich water using the CaO-based WTR may result in conditions less favourable for cyanobacterial growth and more favourable for growth of diatoms. Results show that selected industrial by-products may mitigate eutrophication through targeted use in nutrient intervention schemes. Crown Copyright © 2012. Published by Elsevier B.V. All rights reserved.

  9. Water Relations, Gas Exchange, and Nutrient Response to a Long Term Constant Water Deficit

    NASA Technical Reports Server (NTRS)

    Berry, Wade L.; Goldstein, Guillermo; Dreschel, Thomas W.; Wheeler, Raymond M.; Sager, John C.; Knott, William M.

    1992-01-01

    Wheat plants (Triticum aestivum) were grown for 43 days in a micro-porous tube nutrient delivery system. Roots were unable to penetrate the microporous tube, but grew on the surface and maintained capillary contact with the nutrient solution on the inside of the tube through the 5-micron pores of the porous tube. Water potential in the system was controlled at -0.4, -0.8, and -3.0 kPa by adjusting the applied pressure (hydrostatic head) to the nutrient solution flowing through the microporous tubes. A relatively small decrease in applied water potential from -0.4 to -3.0 kPa resulted in a 34% reduction of shoot growth but only a moderate reduction in the midday leaf water potential from -1.3 to -1.7 MPa. Carbon dioxide assimilation decreased and water use efficiency increased with the more negative applied water potentials, while intercellular CO2 concentration remained constant. This was associated with a decrease in stomatal conductance to water vapor from 1.90 to 0.98 mol/(sq m sec) and a decrease in total apparent hydraulic conductance from 47 to 12 (micro)mol/(sec MPa). Although the applied water potentials were in the -0.4 to -3.0 kPa range, the actual water potential perceived by the plant roots appeared to be in the range of -0.26 to -0.38 MPa as estimated by the leaf water potential of bagged plants. The amount of K, Ca, Mg, Zn, Cu, and B accumulated with each unit of transpired water increased as the applied water potential became less negative. The increase in accumulation ranged from 1.4-fold for K to 2.2-fold for B. The physiological responses observed in this study in response to small constant differences in applied water potentials were much greater than expected from either the applied water potential or the observed plant water potential. Even though the micro-porous tube may not represent natural conditions and could possibly introduce morphological and physiological artifacts, it enables a high degree of control of water potential that

  10. Estimation of Nutrients Flux of Water-sediment Interface in the Chukchi Sea, the Western Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Zhang, H.

    2016-02-01

    Nutrients regeneration in pore water is one of the important ways to supply nutrients of upper water column in the shelf. The pore water in sediment of the central Chukchi Sea continental shelf, showed a typical benthic distribution of nutrients at water-sediment interface, in where physical and bioturbation was weak. The nutrient samples in multi-tubular short column sediment and water column were obtained from the Forth Chinese National Arctic Research Expedition, to measure the nutrient concentrations of pore water, overlying water and water column. The results show that, the typical distribution can be separated into three layers. The first layer is the exponential increasing layer (I), in which the concentrations of nutrients increased rapidly with depth. Then was the steady layer (II), the sediment demineralization was equal to the nutrient transference and nutrients' concentrations were substantially constant at this stage. The third layer was a slowly descending layer (III), in which NO3- and PO43- were reduced by bacteria and lost oxygen ions due to organic materials degradation depleting oxygen. By a two-layer mode and the Fick's first law of diffusion, diffusive fluxes of silicate, phosphate and nitrate in R06 station of the Chukchi Sea shelf can be calculated, and the fluxes were 1.660 mmol/(m2 · d), 0.008 mmol/(m2 · d) and 0.117 mmol/(m2 · d), respectively. The diffusive fluxes of silicate for CC1, R06, C07 and S23 stations were 3.101 mmol/(m2 · d), 1.660 mmol/(m2 · d), 1.307 mmol/(m2 · d) and mmol/(m2 · d), respectively, which show obvious distribution characteristics with latitude. Distribution of N * in the pore water suggested that a strong denitrification process in sedimentary environment of the Chukchi Sea shelf, which is an important sink for nitrate.

  11. NUTRIENT CRITERIA TECHNICAL GUIDANCE MANUAL - ESTUARINE AND COASTAL MARINE WATERS, OCTOBER 2001

    EPA Science Inventory

    Nutrient overenrichment is a major cause of water pollution in the United States. The purpose of this manual is to provide scientifically defensible technical guidance to assist States, authorized Tribes, and other governmental entities in developing numeric nutrient criteria fo...

  12. EUTROPHICATION OF COASTAL WATER BODIES: RELATIONSHIPS BETWEEN NUTRIENT LOADING AND ECOLOGICAL RESPONSE

    EPA Science Inventory

    This newly initiated research will provide environmental managers with an empirical method to develop regional nutrient input limits for East Coast estuaries/coastal water bodies. The goal will be to reduce the current uncertainty associated with nutrient load-response relationsh...

  13. Water budgets, water quality, and analysis of nutrient loading of the Winter Park chain of lakes, central Florida, 1989-92

    USGS Publications Warehouse

    Phelps, G.G.; German, E.R.

    1995-01-01

    The Winter Park chain of lakes (Lakes Maitland, Virginia, Osceola, and Mizell) has a combined area of about 900 acres, an immediate drainage area of about 3,100 acres, and mean depths ranging from 11 to 15 feet. The lakes are an important recreational resource for the surrounding communities, but there is concern about the possible effects of stormwater runoff and seepage of nutrient-enriched ground water on the quality of water in the lakes. The lakes receive water from several sources: rainfall on lake surfaces, inflow from other surface-water bodies, stormflow that enters the lakes through storm drains or by direct runoff from land adjacent to the lakes and ground-water seepage. Water leaves the lakes by evaporation, surface outflow, and ground-water outflow. Of the three, only surface outflow can be measured directly. Rainfall, surface inflow and outflow, and lake-stage data were collected from October 1, 1989, to September 30, 1992. Stormflow, evaporation and ground-water inflow and outflow were estimated for the 3 years of the study. Ground-water outflow was calculated by evaluating the rate of lake-stage decline during dry periods. Estimated ground-water outflow was compared to downward leakage rates estimated by ground-water flow models. Lateral ground-water inflow from surficial sediments was calculated as the residual of the flow budget. Flow budgets were calculated for the 3 years of the study. In water year 1992 (a year with about average rainfall), inflow consisted of rainfall, 48 inches; stormflow, 15 inches; surface inflow, 67 inches; and ground water, 40 inches. The calculated outflows were evaporation, 47 inches; surface outflow, 90 inches; and ground water, 33 inches. Water-quality data also were used to calculate nutrient budgets for the lakes. Bimonthly water samples were collected from the lakes and at surface inflow and outflow sites, and were analyzed for physical characteristics, dissolved oxygen, pH, specific conductance, major ions, the

  14. Photochemical effects of sunlight.

    PubMed

    Daniels, F

    1972-07-01

    The importance of sunlight in bringing about not only photosynthesis in plants, but also other photochemical effects, is reviewed. More effort should be devoted to photochemical storage of the sun's energy without the living plant. There is no theoretical reason to believe that such reactions are impossible. Ground rules for searching for suitable solar photochemical reactions are given, and a few attempts are described, but nothing successful has yet been found. Future possibilities are suggested. Photogalvanic cells which convert sunlight into electricity deserve further research. Eugene Rabinowitch has been an active pioneer in these fields.

  15. Emerging tools for continuous nutrient monitoring networks: Sensors advancing science and water resources protection

    USGS Publications Warehouse

    Pellerin, Brian; Stauffer, Beth A; Young, Dwane A; Sullivan, Daniel J.; Bricker, Suzanne B.; Walbridge, Mark R; Clyde, Gerard A; Shaw, Denice M

    2016-01-01

    Sensors and enabling technologies are becoming increasingly important tools for water quality monitoring and associated water resource management decisions. In particular, nutrient sensors are of interest because of the well-known adverse effects of nutrient enrichment on coastal hypoxia, harmful algal blooms, and impacts to human health. Accurate and timely information on nutrient concentrations and loads is integral to strategies designed to minimize risk to humans and manage the underlying drivers of water quality impairment. Using nitrate sensors as an example, we highlight the types of applications in freshwater and coastal environments that are likely to benefit from continuous, real-time nutrient data. The concurrent emergence of new tools to integrate, manage and share large data sets is critical to the successful use of nutrient sensors and has made it possible for the field of continuous nutrient monitoring to rapidly move forward. We highlight several near-term opportunities for Federal agencies, as well as the broader scientific and management community, that will help accelerate sensor development, build and leverage sites within a national network, and develop open data standards and data management protocols that are key to realizing the benefits of a large-scale, integrated monitoring network. Investing in these opportunities will provide new information to guide management and policies designed to protect and restore our nation’s water resources.

  16. Unravelling the limits to tree height: a major role for water and nutrient trade-offs.

    PubMed

    Cramer, Michael D

    2012-05-01

    Competition for light has driven forest trees to grow exceedingly tall, but the lack of a single universal limit to tree height indicates multiple interacting environmental limitations. Because soil nutrient availability is determined by both nutrient concentrations and soil water, water and nutrient availabilities may interact in determining realised nutrient availability and consequently tree height. In SW Australia, which is characterised by nutrient impoverished soils that support some of the world's tallest forests, total [P] and water availability were independently correlated with tree height (r = 0.42 and 0.39, respectively). However, interactions between water availability and each of total [P], pH and [Mg] contributed to a multiple linear regression model of tree height (r = 0.72). A boosted regression tree model showed that maximum tree height was correlated with water availability (24%), followed by soil properties including total P (11%), Mg (10%) and total N (9%), amongst others, and that there was an interaction between water availability and total [P] in determining maximum tree height. These interactions indicated a trade-off between water and P availability in determining maximum tree height in SW Australia. This is enabled by a species assemblage capable of growing tall and surviving (some) disturbances. The mechanism for this trade-off is suggested to be through water enabling mass-flow and diffusive mobility of P, particularly of relatively mobile organic P, although water interactions with microbial activity could also play a role.

  17. Functioning of a Shallow-Water Sediment System during Experimental Warming and Nutrient Enrichment

    PubMed Central

    Alsterberg, Christian; Sundbäck, Kristina; Hulth, Stefan

    2012-01-01

    Effects of warming and nutrient enrichment on intact unvegetated shallow-water sediment were investigated for 5 weeks in the autumn under simulated natural field conditions, with a main focus on trophic state and benthic nitrogen cycling. In a flow-through system, sediment was exposed to either seawater at ambient temperature or seawater heated 4°C above ambient, with either natural or nutrient enriched water. Sediment–water fluxes of oxygen and inorganic nutrients, nitrogen mineralization, and denitrification were measured. Warming resulted in an earlier shift to net heterotrophy due to increased community respiration; primary production was not affected by temperature but (slightly) by nutrient enrichment. The heterotrophic state was, however, not further strengthened by warming, but was rather weakened, probably because increased mineralization induced a shortage of labile organic matter. Climate-related warming of seawater during autumn could therefore, in contrast to previous predictions, induce shorter but more intensive heterotrophic periods in shallow-water sediments, followed by longer autotrophic periods. Increased nitrogen mineralization and subsequent effluxes of ammonium during warming suggested a preferential response of organisms driving nitrogen mineralization when compared to sinks of ammonium such as nitrification and algal assimilation. Warming and nutrient enrichment resulted in non-additive effects on nitrogen mineralization and denitrification (synergism), as well as on benthic fluxes of phosphate (antagonism). The mode of interaction appears to be related to the trophic level of the organisms that are the main drivers of the affected processes. Despite the weak response of benthic microalgae to both warming and nutrient enrichment, the assimilation of nitrogen by microalgae was similar in magnitude to rates of nitrogen mineralization. This implies a sustained filter function and retention capacity of nutrients by the sediment. PMID

  18. Mycorrhizal fungi enhance plant nutrient acquisition and modulate nitrogen loss with variable water regimes.

    PubMed

    Bowles, Timothy M; Jackson, Louise E; Cavagnaro, Timothy R

    2018-01-01

    Climate change will alter both the amount and pattern of precipitation and soil water availability, which will directly affect plant growth and nutrient acquisition, and potentially, ecosystem functions like nutrient cycling and losses as well. Given their role in facilitating plant nutrient acquisition and water stress resistance, arbuscular mycorrhizal (AM) fungi may modulate the effects of changing water availability on plants and ecosystem functions. The well-characterized mycorrhizal tomato (Solanum lycopersicum L.) genotype 76R (referred to as MYC+) and the mutant mycorrhiza-defective tomato genotype rmc were grown in microcosms in a glasshouse experiment manipulating both the pattern and amount of water supply in unsterilized field soil. Following 4 weeks of differing water regimes, we tested how AM fungi affected plant productivity and nutrient acquisition, short-term interception of a 15NH4+ pulse, and inorganic nitrogen (N) leaching from microcosms. AM fungi enhanced plant nutrient acquisition with both lower and more variable water availability, for instance increasing plant P uptake more with a pulsed water supply compared to a regular supply and increasing shoot N concentration more when lower water amounts were applied. Although uptake of the short-term 15NH4+ pulse was higher in rmc plants, possibly due to higher N demand, AM fungi subtly modulated NO3- leaching, decreasing losses by 54% at low and high water levels in the regular water regime, with small absolute amounts of NO3- leached (<1 kg N/ha). Since this study shows that AM fungi will likely be an important moderator of plant and ecosystem responses to adverse effects of more variable precipitation, management strategies that bolster AM fungal communities may in turn create systems that are more resilient to these changes. © 2017 John Wiley & Sons Ltd.

  19. Technique to separate lidar signal and sunlight.

    PubMed

    Sun, Wenbo; Hu, Yongxiang; MacDonnell, David G; Weimer, Carl; Baize, Rosemary R

    2016-06-13

    Sunlight contamination dominates the backscatter noise in space-based lidar measurements during daytime. The background scattered sunlight is highly variable and dependent upon the surface and atmospheric albedo. The scattered sunlight contribution to noise increases over land and snow surfaces where surface albedos are high and thus overwhelm lidar backscatter from optically thin atmospheric constituents like aerosols and thin clouds. In this work, we developed a novel lidar remote sensing concept that potentially can eliminate sunlight induced noise. The new lidar concept requires: (1) a transmitted laser light that carries orbital angular momentum (OAM); and (2) a photon sieve (PS) diffractive filter that separates scattered sunlight from laser light backscattered from the atmosphere, ocean and solid surfaces. The method is based on numerical modeling of the focusing of Laguerre-Gaussian (LG) laser beam and plane-wave light by a PS. The model results show that after passing through a PS, laser light that carries the OAM is focused on a ring (called "focal ring" here) on the focal plane of the PS filter, very little energy arrives at the center of the focal plane. However, scattered sunlight, as a plane wave without the OAM, focuses at the center of the focal plane and thus can be effectively blocked or ducted out. We also find that the radius of the "focal ring" increases with the increase of azimuthal mode (L) of LG laser light, thus increasing L can more effectively separate the lidar signal away from the sunlight noise.

  20. Photochemical Effects of Sunlight

    PubMed Central

    Daniels, Farrington

    1972-01-01

    The importance of sunlight in bringing about not only photosynthesis in plants, but also other photochemical effects, is reviewed. More effort should be devoted to photochemical storage of the sun's energy without the living plant. There is no theoretical reason to believe that such reactions are impossible. Ground rules for searching for suitable solar photochemical reactions are given, and a few attempts are described, but nothing successful has yet been found. Future possibilities are suggested. Photogalvanic cells which convert sunlight into electricity deserve further research. Eugene Rabinowitch has been an active pioneer in these fields. PMID:5037333

  1. Spatial variation in nutrient and water color effects on lake chlorophyll at macroscales

    USGS Publications Warehouse

    Fergus, C. Emi; Finley, Andrew O.; Soranno, Patricia A.; Wagner, Tyler

    2016-01-01

    The nutrient-water color paradigm is a framework to characterize lake trophic status by relating lake primary productivity to both nutrients and water color, the colored component of dissolved organic carbon. Total phosphorus (TP), a limiting nutrient, and water color, a strong light attenuator, influence lake chlorophyll a concentrations (CHL). But, these relationships have been shown in previous studies to be highly variable, which may be related to differences in lake and catchment geomorphology, the forms of nutrients and carbon entering the system, and lake community composition. Because many of these factors vary across space it is likely that lake nutrient and water color relationships with CHL exhibit spatial autocorrelation, such that lakes near one another have similar relationships compared to lakes further away. Including this spatial dependency in models may improve CHL predictions and clarify how well the nutrient-water color paradigm applies to lakes distributed across diverse landscape settings. However, few studies have explicitly examined spatial heterogeneity in the effects of TP and water color together on lake CHL. In this study, we examined spatial variation in TP and water color relationships with CHL in over 800 north temperate lakes using spatially-varying coefficient models (SVC), a robust statistical method that applies a Bayesian framework to explore space-varying and scale-dependent relationships. We found that TP and water color relationships were spatially autocorrelated and that allowing for these relationships to vary by individual lakes over space improved the model fit and predictive performance as compared to models that did not vary over space. The magnitudes of TP effects on CHL differed across lakes such that a 1 μg/L increase in TP resulted in increased CHL ranging from 2–24 μg/L across lake locations. Water color was not related to CHL for the majority of lakes, but there were some locations where water color had a

  2. Spatial Variation in Nutrient and Water Color Effects on Lake Chlorophyll at Macroscales

    PubMed Central

    Finley, Andrew O.; Soranno, Patricia A.; Wagner, Tyler

    2016-01-01

    The nutrient-water color paradigm is a framework to characterize lake trophic status by relating lake primary productivity to both nutrients and water color, the colored component of dissolved organic carbon. Total phosphorus (TP), a limiting nutrient, and water color, a strong light attenuator, influence lake chlorophyll a concentrations (CHL). But, these relationships have been shown in previous studies to be highly variable, which may be related to differences in lake and catchment geomorphology, the forms of nutrients and carbon entering the system, and lake community composition. Because many of these factors vary across space it is likely that lake nutrient and water color relationships with CHL exhibit spatial autocorrelation, such that lakes near one another have similar relationships compared to lakes further away. Including this spatial dependency in models may improve CHL predictions and clarify how well the nutrient-water color paradigm applies to lakes distributed across diverse landscape settings. However, few studies have explicitly examined spatial heterogeneity in the effects of TP and water color together on lake CHL. In this study, we examined spatial variation in TP and water color relationships with CHL in over 800 north temperate lakes using spatially-varying coefficient models (SVC), a robust statistical method that applies a Bayesian framework to explore space-varying and scale-dependent relationships. We found that TP and water color relationships were spatially autocorrelated and that allowing for these relationships to vary by individual lakes over space improved the model fit and predictive performance as compared to models that did not vary over space. The magnitudes of TP effects on CHL differed across lakes such that a 1 μg/L increase in TP resulted in increased CHL ranging from 2–24 μg/L across lake locations. Water color was not related to CHL for the majority of lakes, but there were some locations where water color had a

  3. An investigation of water nutrient levels associated with forest vegetation in highly altered landscapes

    Treesearch

    M.E.G. Golay; J.R. Thompson; C.M. Mabry; R.K. Kolka

    2013-01-01

    Stream pollution by nutrient loading is a chronic problem in the Midwest, United States, and greater impacts on water quality are expected as agricultural production and urban areas expand. Remnant riparian forests are critical for maintaining ecosystem functions in this landscape context, allowing water infiltration and capture of nutrients before they are lost from...

  4. Groundwater – The disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

    USGS Publications Warehouse

    Lewandowski, Jörg; Meinikmann, Karin; Nützmann, Gunnar; Rosenberry, Donald O.

    2015-01-01

    Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer-lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater-borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer-lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater-borne P loads vary from 0.74 to 2900 mg PO4-P m−2 year−1; for N, these loads vary from 0.001 to 640 g m−2 year−1. Even small amounts of seepage can carry large nutrient loads due to often high

  5. Does suicide have a stronger association with seasonality than sunlight?

    PubMed

    White, Richard A; Azrael, Deborah; Papadopoulos, Fotios C; Lambert, Gavin W; Miller, Matthew

    2015-06-03

    Suicide rates have widely been reported to peak in spring and summer. A frequent hypothesis is that increased sunlight exposure alters biological mechanisms. However, few attempts have been made to systematically untangle the putative suicidogenic risk of sunlight exposure from that of seasonality. We examined whether average hours of daily sunlight in a month confer additional risk over month of year when predicting monthly suicide rates. Historical population-based ecological longitudinal study. We used 3 longitudinal studies (n=31,060 suicides) with monthly suicide and meteorological data from Greece (1992-2001), Victoria, Australia (1990-1998) and Norway (1969-2009). We used a negative binomial regression to observe (1) the association of month of year with suicides, adjusting for different sunlight exposures, and (2) the association of sunlight exposure with suicides, adjusting for month of year. We then investigated claims that suicides were associated with daily sunlight exposures, defined by us as 2550 sunlight exposure combinations corresponding to a 1-50 days exposure window with lags of 0-50 days. Using monthly data, the association between month of year and suicides remained after adjusting for mean daily hours of sunlight and change in the mean daily hours of sunlight. Adjusted for month of year, the associations between sunlight exposure and suicides became non-significant and attenuated towards the null (the coefficient estimate for mean daily hours of sunlight decreased in absolute magnitude by 72%). The findings were consistent across all 3 cohorts, both when analysed separately and combined. When investigating daily sunlight exposures, we found no significant results after correcting for multiple testing. Using monthly data, the robustness of our month of year effects, combined with the transient and modest nature of our sunlight effects, suggested that the association between sunlight exposure and suicide was a proxy for the association between

  6. Does suicide have a stronger association with seasonality than sunlight?

    PubMed Central

    White, Richard A; Azrael, Deborah; Papadopoulos, Fotios C; Lambert, Gavin W; Miller, Matthew

    2015-01-01

    Objectives Suicide rates have widely been reported to peak in spring and summer. A frequent hypothesis is that increased sunlight exposure alters biological mechanisms. However, few attempts have been made to systematically untangle the putative suicidogenic risk of sunlight exposure from that of seasonality. We examined whether average hours of daily sunlight in a month confer additional risk over month of year when predicting monthly suicide rates. Design Historical population-based ecological longitudinal study. Setting and participants We used 3 longitudinal studies (n=31 060 suicides) with monthly suicide and meteorological data from Greece (1992–2001), Victoria, Australia (1990–1998) and Norway (1969–2009). Intervention We used a negative binomial regression to observe (1) the association of month of year with suicides, adjusting for different sunlight exposures, and (2) the association of sunlight exposure with suicides, adjusting for month of year. We then investigated claims that suicides were associated with daily sunlight exposures, defined by us as 2550 sunlight exposure combinations corresponding to a 1–50 days exposure window with lags of 0–50 days. Results Using monthly data, the association between month of year and suicides remained after adjusting for mean daily hours of sunlight and change in the mean daily hours of sunlight. Adjusted for month of year, the associations between sunlight exposure and suicides became non-significant and attenuated towards the null (the coefficient estimate for mean daily hours of sunlight decreased in absolute magnitude by 72%). The findings were consistent across all 3 cohorts, both when analysed separately and combined. When investigating daily sunlight exposures, we found no significant results after correcting for multiple testing. Conclusions Using monthly data, the robustness of our month of year effects, combined with the transient and modest nature of our sunlight effects, suggested that the

  7. Advanced nutrient removal from surface water by a consortium of attached microalgae and bacteria: A review.

    PubMed

    Liu, Junzhuo; Wu, Yonghong; Wu, Chenxi; Muylaert, Koenraad; Vyverman, Wim; Yu, Han-Qing; Muñoz, Raúl; Rittmann, Bruce

    2017-10-01

    Innovative and cost-effective technologies for advanced nutrient removal from surface water are urgently needed for improving water quality. Conventional biotechnologies, such as ecological floating beds, or constructed wetlands, are not effective in removing nutrients present at low-concentration. However, microalgae-bacteria consortium is promising for advanced nutrient removal from wastewater. Suspended algal-bacterial systems can easily wash out unless the hydraulic retention time is long, attached microalgae-bacteria consortium is more realistic. This critical review summarizes the fundamentals and status of attached microalgae-bacteria consortium for advanced nutrient removal from surface water. Key advantages are the various nutrient removal pathways, reduction of nutrients to very low concentration, and diversified photobioreactor configurations. Challenges include poor identification of functional species, poor control of the community composition, and long start-up times. Future research should focus on the selection and engineering of robust microbial species, mathematical modelling of the composition and functionality of the consortium, and novel photobioreactor configurations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Ultra-accelerated natural sunlight exposure testing

    DOEpatents

    Jorgensen, Gary J.; Bingham, Carl; Goggin, Rita; Lewandowski, Allan A.; Netter, Judy C.

    2000-06-13

    Process and apparatus for providing ultra accelerated natural sunlight exposure testing of samples under controlled weathering without introducing unrealistic failure mechanisms in exposed materials and without breaking reciprocity relationships between flux exposure levels and cumulative dose that includes multiple concurrent levels of temperature and relative humidity at high levels of natural sunlight comprising: a) concentrating solar flux uniformly; b) directing the controlled uniform sunlight onto sample materials in a chamber enclosing multiple concurrent levels of temperature and relative humidity to allow the sample materials to be subjected to accelerated irradiance exposure factors for a sufficient period of time in days to provide a corresponding time of about at least a years worth of representative weathering of the sample materials.

  9. Sunlight-Driven Reduction of Silver Ions by Natural Organic Matter: Formation and Transformation of Silver Nanoparticles

    EPA Science Inventory

    Photobiogeochemical reactions involving metal species can be a source of naturally occurring nanoscale materials in the aquatic environment. This study demonstrates that, under simulated sunlight exposure, ionic Ag is photoreduced in river water or synthetic natural water samples...

  10. Water as an essential nutrient: the physiological basis of hydration.

    PubMed

    Jéquier, E; Constant, F

    2010-02-01

    How much water we really need depends on water functions and the mechanisms of daily water balance regulation. The aim of this review is to describe the physiology of water balance and consequently to highlight the new recommendations with regard to water requirements. Water has numerous roles in the human body. It acts as a building material; as a solvent, reaction medium and reactant; as a carrier for nutrients and waste products; in thermoregulation; and as a lubricant and shock absorber. The regulation of water balance is very precise, as a loss of 1% of body water is usually compensated within 24 h. Both water intake and water losses are controlled to reach water balance. Minute changes in plasma osmolarity are the main factors that trigger these homeostatic mechanisms. Healthy adults regulate water balance with precision, but young infants and elderly people are at greater risk of dehydration. Dehydration can affect consciousness and can induce speech incoherence, extremity weakness, hypotonia of ocular globes, orthostatic hypotension and tachycardia. Human water requirements are not based on a minimal intake because it might lead to a water deficit due to numerous factors that modify water needs (climate, physical activity, diet and so on). Water needs are based on experimentally derived intake levels that are expected to meet the nutritional adequacy of a healthy population. The regulation of water balance is essential for the maintenance of health and life. On an average, a sedentary adult should drink 1.5 l of water per day, as water is the only liquid nutrient that is really essential for body hydration.

  11. Relation of nutrient concentrations, nutrient loading, and algal production to changes in water levels in Kabetogama Lake, Voyageurs National Park, northern Minnesota, 2008-09

    USGS Publications Warehouse

    Christensen, Victoria G.; Maki, Ryan P.; Kiesling, Richard L.

    2011-01-01

    Nutrient enrichment has led to excessive algal growth in Kabetogama Lake, Voyageurs National Park, northern Minnesota. Water- and sediment-quality data were collected during 2008-09 to assess internal and external nutrient loading. Data collection was focused in Kabetogama Lake and its inflows, the area of greatest concern for eutrophication among the lakes of Voyageurs National Park. Nutrient and algal data were used to determine trophic status and were evaluated in relation to changes in Kabetogama Lake water levels following changes to dam operation starting in 2000. Analyses were used to estimate external nutrient loading at inflows and assess the potential contribution of internal phosphorus loading. Kabetogama Lake often was mixed vertically, except for a few occasionally stratified areas, including Lost Bay in the northeastern part of Kabetogama Lake. Stratification, combined with larger bottom-water nutrient concentrations, larger sediment phosphorus concentrations, and estimated phosphorus release rates from sediment cores indicate that Lost Bay may be one of several areas that may be contributing substantially to internal loading. Internal loading is a concern because nutrients may cause excessive algal growth including potentially toxic cyanobacteria. The cyanobacterial hepatotoxin, microcystin, was detected in 7 of 14 cyanobacterial bloom samples, with total concentrations exceeding 1.0 microgram per liter, the World Health Organization's guideline for finished drinking water for the congener, microcystin-LR. Comparisons of the results of this study to previous studies indicate that chlorophyll-a concentrations and trophic state indices have improved since 2000, when the rules governing dam operation changed. However, total-phosphorus concentrations have not changed significantly since 2000.

  12. Water, weed, and nutrient management practices in organic blackberries

    USDA-ARS?s Scientific Manuscript database

    The purpose of our study is to investigate the effects of organic management on plant and soil water and nutrient relations, plant growth, yield, and fruit quality in an organic trailing blackberry production system. Treatments include: cultivar ('Marion' and 'Black Diamond'); irrigation (post-harve...

  13. Advancing the Food-Energy-Water Nexus: Closing Nutrient Loops in Arid River Corridors.

    PubMed

    Mortensen, Jacob G; González-Pinzón, Ricardo; Dahm, Clifford N; Wang, Jingjing; Zeglin, Lydia H; Van Horn, David J

    2016-08-16

    Closing nutrient loops in terrestrial and aquatic ecosystems is integral to achieve resource security in the food-energy-water (FEW) nexus. We performed multiyear (2005-2008), monthly sampling of instream dissolved inorganic nutrient concentrations (NH4-N, NO3-N, soluble reactive phosphorus-SRP) along a ∼ 300-km arid-land river (Rio Grande, NM) and generated nutrient budgets to investigate how the net source/sink behavior of wastewater and irrigated agriculture can be holistically managed to improve water quality and close nutrient loops. Treated wastewater on average contributed over 90% of the instream dissolved inorganic nutrients (101 kg/day NH4-N, 1097 kg/day NO3-N, 656 kg/day SRP). During growing seasons, the irrigation network downstream of wastewater outfalls retained on average 37% of NO3-N and 45% of SRP inputs, with maximum retention exceeding 60% and 80% of NO3-N and SRP inputs, respectively. Accurate quantification of NH4-N retention was hindered by low loading and high variability. Nutrient retention in the irrigation network and instream processes together limited downstream export during growing seasons, with total retention of 33-99% of NO3-N inputs and 45-99% of SRP inputs. From our synoptic analysis, we identify trade-offs associated with wastewater reuse for agriculture within the scope of the FEW nexus and propose strategies for closing nutrient loops in arid-land rivers.

  14. Nutrient Loads Flowing into Coastal Waters from the Main Rivers of China (2006-2012).

    PubMed

    Tong, Yindong; Zhao, Yue; Zhen, Gengchong; Chi, Jie; Liu, Xianhua; Lu, Yiren; Wang, Xuejun; Yao, Ruihua; Chen, Junyue; Zhang, Wei

    2015-11-19

    Based on monthly monitoring data of unfiltered water, the nutrient discharges of the eight main rivers flowing into the coastal waters of China were calculated from 2006 to 2012. In 2012, the total load of NH3-N (calculated in nitrogen), total nitrogen (TN, calculated in nitrogen) and total phosphorus (TP, calculated in phosphorus) was 5.1 × 10(5), 3.1 × 10(6) and 2.8 × 10(5) tons, respectively, while in 2006, the nutrient load was 7.4 × 10(5), 2.2 × 10(6) and 1.6 × 10(5) tons, respectively. The nutrient loading from the eight major rivers into the coastal waters peaked in summer and autumn, probably due to the large water discharge in the wet season. The Yangtze River was the largest riverine nutrient source for the coastal waters, contributing 48% of the NH3-N discharges, 66% of the TN discharges and 84% of the TP discharges of the eight major rivers in 2012. The East China Sea received the majority of the nutrient discharges, i.e. 50% of NH3-N (2.7 × 10(5) tons), 70% of TN (2.2 × 10(6) tons) and 87% of TP (2.5 × 10(5) tons) in 2012. The riverine discharge of TN into the Yellow Sea and Bohai Sea was lower than that from the direct atmospheric deposition, while for the East China Sea, the riverine TN input was larger.

  15. Proteomic analysis of grape berry skin responding to sunlight exclusion.

    PubMed

    Niu, Ning; Cao, Yuegang; Duan, Wei; Wu, Benhong; Li, Shaohua

    2013-05-15

    The most obvious effect of sunlight exclusion from grape clusters is the inhibition of anthocyanin biosynthesis in the berry skin so that no color develops. Two-dimensional gel electrophoresis coupled with mass spectrometry was used to characterize the proteins isolated from berry skins that developed under sunlight exclusion versus those from sunlight-exposed berries. Among more than 1500 spots resolved in stained gels, the accumulation patterns of 96 spots differed significantly between sunlight-excluded berry skin and that of sunlight-exposed control berries. Seventy-two proteins, including 35 down-regulated and 37 up-regulated proteins, were identified and categorized. Proteins involved in photosynthesis and secondary metabolism, especially UDP-glucose:flavonoid 3-O-glucosyltransferase (UFGT), the key step for anthocyanin biosynthesis in grape berry skin, were accumulated less in the absence of sunlight. Several isoforms of heat shock proteins were also down-regulated. The proteins that were over-accumulated in sunlight-excluded berry skin were more often related to energy production, glycolysis, the tricarboxylic-acid cycle, protein synthesis and biogenesis of cellular components. Their putative role is discussed in terms of their relevance to sunlight exclusion processes. Crown Copyright © 2013. Published by Elsevier GmbH. All rights reserved.

  16. Potential foraging decisions by a desert ungulate to balance water and nutrient intake in a water-stressed environment

    USGS Publications Warehouse

    Gedir, Jay V.; Cain, James W.; Krausman, Paul R.; Allen, Jamison D.; Duff, Glenn C.; Morgart, John R.

    2016-01-01

    Arid climates have unpredictable precipitation patterns, and wildlife managers often provide supplemental water to help desert ungulates endure the hottest, driest periods. When surface water is unavailable, the only source of water for ungulates comes from the forage they consume, and they must make resourceful foraging decisions to meet their requirements. We compared two desert bighorn sheep (Ovis canadensis nelsoni) populations in Arizona, USA: a treatment population with supplemental water removed during treatment, and a control population. We examined whether sheep altered their seasonal diets without supplemental water. We calculated water and nutrient intake and metabolic water production from dry matter intake and forage moisture and nitrogen content, to determine whether sheep could meet their seasonal daily water and nutrient requirements solely from forage. Diets of sheep were higher in protein (all seasons) and moisture (autumn and winter) during treatment compared to pretreatment. During treatment, sheep diet composition was similar between the treatment and control populations, which suggests, under the climatic conditions of this study, water removal did not influence sheep diets. We estimated that under drought conditions, without any surface water available (although small ephemeral potholes would contain water after rains), female and male sheep would be unable to meet their daily water requirements in all seasons, except winter, when reproductive females had a nitrogen deficit. We determined that sheep could achieve water and nutrient balances in all seasons by shifting their total diet proportions by 8–55% from lower to higher moisture and nitrogen forage species. We elucidate how seasonal forage quality and foraging decisions by desert ungulates allow them to cope with their xeric and uncertain environment, and suggest that, with the forage conditions observed in our study area during this study period, providing supplemental water during

  17. Potential Foraging Decisions by a Desert Ungulate to Balance Water and Nutrient Intake in a Water-Stressed Environment.

    PubMed

    Gedir, Jay V; Cain, James W; Krausman, Paul R; Allen, Jamison D; Duff, Glenn C; Morgart, John R

    2016-01-01

    Arid climates have unpredictable precipitation patterns, and wildlife managers often provide supplemental water to help desert ungulates endure the hottest, driest periods. When surface water is unavailable, the only source of water for ungulates comes from the forage they consume, and they must make resourceful foraging decisions to meet their requirements. We compared two desert bighorn sheep (Ovis canadensis nelsoni) populations in Arizona, USA: a treatment population with supplemental water removed during treatment, and a control population. We examined whether sheep altered their seasonal diets without supplemental water. We calculated water and nutrient intake and metabolic water production from dry matter intake and forage moisture and nitrogen content, to determine whether sheep could meet their seasonal daily water and nutrient requirements solely from forage. Diets of sheep were higher in protein (all seasons) and moisture (autumn and winter) during treatment compared to pretreatment. During treatment, sheep diet composition was similar between the treatment and control populations, which suggests, under the climatic conditions of this study, water removal did not influence sheep diets. We estimated that under drought conditions, without any surface water available (although small ephemeral potholes would contain water after rains), female and male sheep would be unable to meet their daily water requirements in all seasons, except winter, when reproductive females had a nitrogen deficit. We determined that sheep could achieve water and nutrient balances in all seasons by shifting their total diet proportions by 8-55% from lower to higher moisture and nitrogen forage species. We elucidate how seasonal forage quality and foraging decisions by desert ungulates allow them to cope with their xeric and uncertain environment, and suggest that, with the forage conditions observed in our study area during this study period, providing supplemental water during

  18. Potential Foraging Decisions by a Desert Ungulate to Balance Water and Nutrient Intake in a Water-Stressed Environment

    PubMed Central

    Gedir, Jay V.; Cain, James W.; Krausman, Paul R.; Allen, Jamison D.; Duff, Glenn C.

    2016-01-01

    Arid climates have unpredictable precipitation patterns, and wildlife managers often provide supplemental water to help desert ungulates endure the hottest, driest periods. When surface water is unavailable, the only source of water for ungulates comes from the forage they consume, and they must make resourceful foraging decisions to meet their requirements. We compared two desert bighorn sheep (Ovis canadensis nelsoni) populations in Arizona, USA: a treatment population with supplemental water removed during treatment, and a control population. We examined whether sheep altered their seasonal diets without supplemental water. We calculated water and nutrient intake and metabolic water production from dry matter intake and forage moisture and nitrogen content, to determine whether sheep could meet their seasonal daily water and nutrient requirements solely from forage. Diets of sheep were higher in protein (all seasons) and moisture (autumn and winter) during treatment compared to pretreatment. During treatment, sheep diet composition was similar between the treatment and control populations, which suggests, under the climatic conditions of this study, water removal did not influence sheep diets. We estimated that under drought conditions, without any surface water available (although small ephemeral potholes would contain water after rains), female and male sheep would be unable to meet their daily water requirements in all seasons, except winter, when reproductive females had a nitrogen deficit. We determined that sheep could achieve water and nutrient balances in all seasons by shifting their total diet proportions by 8–55% from lower to higher moisture and nitrogen forage species. We elucidate how seasonal forage quality and foraging decisions by desert ungulates allow them to cope with their xeric and uncertain environment, and suggest that, with the forage conditions observed in our study area during this study period, providing supplemental water during

  19. Nutrient dynamics and budget with the surface water-groundwater interaction in the tidal river in Japan

    NASA Astrophysics Data System (ADS)

    Onodera, S.; Saito, M.; Maruyama, Y.; Jin, G.; Miyaoka, K.; Shimizu, Y.

    2013-12-01

    In coastal megacities, sever groundwater depression and water pollution occurred. These impacts affected to river environment change. Especially, the river mouth area has been deposited the polluted matters. These areas have characteristics of water level fluctuation which causes river water-groundwater interaction and the associated change in dynamics of nutrients. However, these effects on the nutrient transport in tidal reaches and nutrient load to the sea have not been fully evaluated in previous studies. Therefore, we aimed to clarify the characteristics of the nutrient transport with the river water-groundwater interaction in the tidal river of Osaka metropolitan city. We conducted the field survey from the river mouth to the 7km upstream area of Yamato River, which has a length of 68km and a watershed area of 1070 km2. Spatial variations in radon (222Rn) concentrations and the difference of hydraulic potential between river waters and the pore waters suggest that the groundwater discharges to the river channel in the upstream area. In contrast, the river water recharged into the groundwater near the river mouth area. It may be caused by the lowering of groundwater level associated with the excess abstraction of groundwater in the urban area. The result also implies the seawater intrusion would accelerate the salinization of groundwater. The spatial and temporal variations in nutrient concentrations indicate that nitrate-nitrogen (NO3-N) concentrations changed temporally and it negative correlated with dissolved organic nitrogen (DON) concentrations. Inorganic phosphorous (PO4-P) concentrations showed the increasing trend with the increase of the river water level. Based on the mass balance, nutrient reproduction from the river bed was suggested in tidal reach. That was estimated to be 10 % of total nitrogen and 3% of phosphorus loads from the upstream.

  20. Methodology to Collect Natural Gas from Methane Hydrate Deposits Using Sunlight: Design of Direct Sunlight Exposure System

    NASA Astrophysics Data System (ADS)

    Shimada, M.; Shimada, J.; Tsunashima, K.; Aoyama, C.

    2017-12-01

    Methane hydrate is anticipated to be the unconventional natural gas energy resource. Two types of methane hydrates are known to exist, based on the settings: "shallow" type and "sand layer" type. In comparison, shallow type is considered an advantage due to its high purity and the more simple exploration. However, not much development methods have been made in the area of extraction techniques. Currently, heating and depressurization are used as methods to collect sand layer methane hydrate, but these methods are still under examination and not yet to be implemented. This is probably because fossil fuel is used for the extraction process instead of natural energy. It is necessary to utilize natural energy instead of relying on fossil fuel. This is why sunlight is believed to be the most significant alternative. Solar power generation is commonly used to extract sunlight, but it is said that this process causes extreme energy loss since solar energy converted to electricity requires conversion to heat energy. A new method is contrived to accelerate the decomposition of methane hydrate with direct sunlight utilizing optical fibers. Authors will present details of this new method to collect methane hydrate with direct sunlight exposure.

  1. Passive flux meter measurement of water and nutrient flux in saturated porous media: bench-scale laboratory tests.

    PubMed

    Cho, Jaehyun; Annable, Michael D; Jawitz, James W; Hatfield, Kirk

    2007-01-01

    The passive nutrient flux meter (PNFM) is introduced for simultaneous measurement of both water and nutrient flux through saturated porous media. The PNFM comprises a porous sorbent pre-equilibrated with a suite of alcohol tracers, which have different partitioning coefficients. Water flux was estimated based on the loss of loaded resident tracers during deployment, while nutrient flux was quantified based on the nutrient solute mass captured on the sorbent. An anionic resin, Lewatit 6328 A, was used as a permeable sorbent and phosphate (PO4(3-)) was the nutrient studied. The phosphate sorption capacity of the resin was measured in batch equilibration tests as 56 mg PO4(3-) g(-1), which was determined to be adequate capacity to retain PO4(3-) loads intercepted over typical PNFM deployment periods in most natural systems. The PNFM design was validated with bench-scale laboratory tests for a range of 9.8 to 28.3 cm d(-1) Darcy velocities and 6 to 43 h deployment durations. Nutrient and water fluxes measured by the PNFM averaged within 6 and 12% of the applied values, respectively, indicating that the PNFM shows promise as a tool for simultaneous measurement of water and nutrient fluxes.

  2. Quality of nutrient data from streams and ground water sampled during water years 1992-2001

    USGS Publications Warehouse

    Mueller, David K.; Titus, Cindy J.

    2005-01-01

    Proper interpretation of water-quality data requires consideration of the effects that bias and variability might have on measured constituent concentrations. In this report, methods are described to estimate the bias due to contamination of samples in the field or laboratory and the variability due to sample collection, processing, shipment, and analysis. Contamination can adversely affect interpretation of measured concentrations in comparison to standards or criteria. Variability can affect interpretation of small differences between individual measurements or mean concentrations. Contamination and variability are determined for nutrient data from quality-control samples (field blanks and replicates) collected as part of the National Water-Quality Assessment (NAWQA) Program during water years 1992-2001. Statistical methods are used to estimate the likelihood of contamination and variability in all samples. Results are presented for five nutrient analytes from stream samples and four nutrient analytes from ground-water samples. Ammonia contamination can add at least 0.04 milligram per liter in up to 5 percent of all samples. This could account for more than 22 percent of measured concentrations at the low range of aquatic-life criteria (0.18 milligram per liter). Orthophosphate contamination, at least 0.019 milligram per liter in up to 5 percent of all samples, could account for more than 38 percent of measured concentrations at the limit to avoid eutrophication (0.05 milligram per liter). Nitrite-plus-nitrate and Kjeldahl nitrogen contamination is less than 0.4 milligram per liter in 99 percent of all samples; thus there is no significant effect on measured concentrations of environmental significance. Sampling variability has little or no effect on reported concentrations of ammonia, nitrite-plus-nitrate, orthophosphate, or total phosphorus sampled after 1998. The potential errors due to sampling variability are greater for the Kjeldahl nitrogen analytes and

  3. Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

    NASA Astrophysics Data System (ADS)

    Yu, Liang; Rozemeijer, Joachim; van Breukelen, Boris M.; Ouboter, Maarten; van der Vlugt, Corné; Broers, Hans Peter

    2018-01-01

    The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban-agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of

  4. Dispersion/dilution enhances phytoplankton blooms in low-nutrient waters

    NASA Astrophysics Data System (ADS)

    Lehahn, Yoav; Koren, Ilan; Sharoni, Shlomit; D'Ovidio, Francesco; Vardi, Assaf; Boss, Emmanuel

    2017-03-01

    Spatial characteristics of phytoplankton blooms often reflect the horizontal transport properties of the oceanic turbulent flow in which they are embedded. Classically, bloom response to horizontal stirring is regarded in terms of generation of patchiness following large-scale bloom initiation. Here, using satellite observations from the North Pacific Subtropical Gyre and a simple ecosystem model, we show that the opposite scenario of turbulence dispersing and diluting fine-scale (~1-100 km) nutrient-enriched water patches has the critical effect of regulating the dynamics of nutrients-phytoplankton-zooplankton ecosystems and enhancing accumulation of photosynthetic biomass in low-nutrient oceanic environments. A key factor in determining ecological and biogeochemical consequences of turbulent stirring is the horizontal dilution rate, which depends on the effective eddy diffusivity and surface area of the enriched patches. Implementation of the notion of horizontal dilution rate explains quantitatively plankton response to turbulence and improves our ability to represent ecological and biogeochemical processes in oligotrophic oceans.

  5. Managed nutrient reduction impacts on nutrient concentrations, water clarity, primary production, and hypoxia in a north temperate estuary

    NASA Astrophysics Data System (ADS)

    Oviatt, Candace; Smith, Leslie; Krumholz, Jason; Coupland, Catherine; Stoffel, Heather; Keller, Aimee; McManus, M. Conor; Reed, Laura

    2017-12-01

    Except for the Providence River and side embayments like Greenwich Bay, Narragansett Bay can no longer be considered eutrophic. In summer 2012 managed nitrogen treatment in Narragansett Bay achieved a goal of reducing effluent dissolved inorganic nitrogen inputs by over 50%. Narragansett Bay represents a small northeast US estuary that had been heavily loaded with sewage effluent nutrients since the late 1800s. The input reduction was reflected in standing stock nutrients resulting in a statistically significant 60% reduction in concentration. In the Providence River estuary, total nitrogen decreased from 100 μm to about 40 μm, for example. We tested four environmental changes that might be associated with the nitrogen reduction. System apparent production was significantly decreased by 31% and 45% in the upper and mid Bay. Nutrient reductions resulted in statistically improved water clarity in the mid and upper Bay and in a 34% reduction in summer hypoxia. Nitrogen reduction also reduced the winter spring diatom bloom; winter chlorophyll levels after nutrient reduction have been significantly lower than before the reduction. The impact on the Bay will continue to evolve over the next few years and be a natural experiment for other temperate estuaries that will be experiencing nitrogen reduction. To provide perspective we review factors effecting hypoxia in other estuaries with managed nutrient reduction and conclude that, as in Narragansett Bay, physical factors can be as important as nutrients. On a positive note managed nutrient reduction has mitigated further deterioration in most estuaries.

  6. Contribution of Nutrient Pollution to Water Scarcity in the Water-Rich Northeastern United States

    NASA Astrophysics Data System (ADS)

    Hale, R. L.; Lopez, C.; Vorosmarty, C. J.

    2015-12-01

    Most studies of water stress focus on water-scarce regions such as drylands. Yet, even water-rich regions can be water stressed due to local water withdrawals that exceed supply or due to water pollution that makes water unusable. The northeastern United States (NE) is a water-rich region relative to the rest of the country, as it concentrates about 50% of total renewable water of the country. Yes the NE features relatively high water withdrawals, ~50 km3/yr, for thermo-power generation, agriculture, and industry, as well as to support a human population of about 70 million. At the same time, rivers and streams in the NE suffer from nutrient pollution, largely from agricultural and urban land uses. We asked: to what extent is the NE water stressed, and how do water withdrawals and water quality each contribute to water scarcity across the NE? We used information on county-level water withdrawals and runoff to calculate a water scarcity index (WSI) for 200 hydrologic units across the NE from 1987 to 2002. We used data on surface water concentrations of nitrogen to calculate the additional water necessary to dilute surface water pollution to weak, moderate, and strong water quality standards derived from the literature. Only considering withdrawals, we found that approximately 10% of the NE was water stressed. Incorporating a moderate water quality standard, 25% of the NE was water stressed. We calculated a dilution burden by sectors of water users and found that public utilities faced 41% of the total dilution burden for the region, followed by irrigation users at 21%. Our results illustrate that even water rich regions can experience water stress and even scarcity, where withdrawals exceed surface water supplies. Water quality contributes to water stress and can change the spatial patterns of water stress across a region. The common approach to address scarcity has required the use of inter-basin water transfers, or in the case of water quality-caused scarcity

  7. The quality of our Nation's waters-Nutrients in the Nation's streams and groundwater, 1992-2004

    USGS Publications Warehouse

    Dubrovsky, N.M.; Burow, K.R.; Clark, G.M.; Gronberg, J.M.; Hamilton, P.A.; Hitt, K.J.; Mueller, D.K.; Munn, M.D.; Nolan, B.T.; Puckett, L.J.; Rupert, M.G.; Short, T.M.; Spahr, N.E.; Sprague, L.A.; Wilber, W.G.

    2010-01-01

    National Findings and Their Implications Although the use of artificial fertilizer has supported increasing food production to meet the needs of a growing population, increases in nutrient loadings from agricultural and, to a lesser extent, urban sources have resulted in nutrient concentrations in many streams and parts of aquifers that exceed standards for protection of human health and (or) aquatic life, often by large margins. Do NAWQA findings substantiate national concerns for aquatic and human health? National Water-Quality Assessment (NAWQA) findings indicate that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or ?background? levels. For example, median concentrations of total nitrogen and phosphorus in agricultural streams are about 6 times greater than background levels. Findings also indicate that concentrations in streams routinely were 2 to 10 times greater than regional nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic life. Such large differences in magnitude suggest that significant reductions in sources of nutrients, as well as greater use of land management strategies to reduce the transport of nutrients to streams, are needed to meet recommended criteria for streams draining areas with significant agricultural and urban development. Nitrate concentrations above the Federal drinking-water standard-or Maximum Contaminant Level (MCL)-of 10 milligrams per liter (mg/L, as nit-ogen) are relatively uncommon in samples from streams used for drinking water or from relatively deep aquifers; the MCL is exceeded, however, in more than 20 percent of shallow (less than 100 feet below the water table) domestic wells in agricultural areas. This finding raises concerns for human health in rural agricultural areas where shallow groundwater is used for domestic supply and may warn of future

  8. The quality of our Nation's waters-Nutrients in the Nation's streams and groundwater, 1992-2004

    USGS Publications Warehouse

    Dubrovsky, Neil M.; Burow, Karen R.; Clark, Gregory M.; Gronberg, JoAnn M.; Hamilton, Pixie A.; Hitt, Kerie J.; Mueller, David K.; Munn, Mark D.; Nolan, Bernard T.; Puckett, Larry J.; Rupert, Michael G.; Short, Terry M.; Spahr, Norman E.; Sprague, Lori A.; Wilber, William G.

    2010-01-01

    National Findings and Their ImplicationsAlthough the use of artificial fertilizer has supported increasing food production to meet the needs of a growing population, increases in nutrient loadings from agricultural and, to a lesser extent, urban sources have resulted in nutrient concentrations in many streams and parts of aquifers that exceed standards for protection of human health and (or) aquatic life, often by large margins.Do NAWQA findings substantiate national concerns for aquatic and human health?National Water-Quality Assessment (NAWQA) findings indicate that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or “background” levels. For example, median concentrations of total nitrogen and phosphorus in agricultural streams are about 6 times greater than background levels. Findings also indicate that concentrations in streams routinely were 2 to 10 times greater than regional nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic life. Such large differences in magnitude suggest that significant reductions in sources of nutrients, as well as greater use of land management strategies to reduce the transport of nutrients to streams, are needed to meet recommended criteria for streams draining areas with significant agricultural and urban development.Nitrate concentrations above the Federal drinking-water standard—or Maximum Contaminant Level (MCL)—of 10 milligrams per liter (mg/L, as nitrogen) are relatively uncommon in samples from streams used for drinking water or from relatively deep aquifers; the MCL is exceeded, however, in more than 20 percent of shallow (less than 100 feet below the water table) domestic wells in agricultural areas. This finding raises concerns for human health in rural agricultural areas where shallow groundwater is used for domestic supply and may warn of future

  9. EPA Office of Water (OW): Nutrient, Sediment, and Pathogens Water Impairments

    EPA Pesticide Factsheets

    National dataset consisting of a snapshot of 303(d) Listed Impaired Waters combined with Impaired Waters with TMDLs whose parent cause is Nutrients, Sediments, and Pathogens. The snapshot constitutes the top water impairments. The Impaired Waters with TMDLs and the 303(d) Listed Impaired Waters are combined into three mapping service layers in MyWaters Mapper application to provide a comprehensive view of each of these impairments. These waters are linked to the 303(d) information stored in EPAs Assessment and TMDL Tracking and Implementation System (ATTAINS). Below is a brief description of the two programs.The 303(d) Listed Impaired Waters program system provides impaired water data and impaired water features reflecting river segments, lakes, and estuaries designated under Section 303(d) of the Clean Water Act. Each State will establish Total Maximum Daily Loads (TMDLs) for these waters. Note the CWA Section 303(d) list of impaired waters does not represent waters that are impaired but have an EPA-approved TMDL established, impaired waters for which other pollution control mechanisms are in place and expected to attain water quality standards, or waters impaired as a result of pollution and is not caused by a pollutant; therefore, the Impaired Waters layers do not represent all impaired waters reported in a state's Integrated Report, but only the waters comprised of a state's approved 303(d) list. For more information regarding impaired waters refer to EPA's

  10. Time-scale Dependence of Response of an Estuarine Water Quality Model to Nutrient Loading

    EPA Science Inventory

    We describe calibration and evaluation of a water quality model being implemented for Narragansett Bay to quantify the response of concentrations of nutrients, phytoplankton chlorophyll a and dissolved oxygen in the Bay to loading rates of nutrients and other boundary conditions....

  11. Converting Sunlight to Electricity--Some Practical Concerns

    ERIC Educational Resources Information Center

    Roman, Harry T.

    2005-01-01

    A photovoltaic panel can convert sunlight directly into electricity. If one connects enough of them in a series-parallel arrangement called a solar array, they can provide about half of a home's annual electricity needs. The panels comprise specially treated electronic materials that when exposed to sunlight will give up electrons freely, and…

  12. Analysis of Dissolved Organic Nutrients in the Interstitial Water of Natural Biofilms.

    PubMed

    Tsuchiya, Yuki; Eda, Shima; Kiriyama, Chiho; Asada, Tomoya; Morisaki, Hisao

    2016-07-01

    In biofilms, the matrix of extracellular polymeric substances (EPSs) retains water in the interstitial region of the EPS. This interstitial water is the ambient environment for microorganisms in the biofilms. The nutrient condition in the interstitial water may affect microbial activity in the biofilms. In the present study, we measured the concentrations of dissolved organic nutrients, i.e., saccharides and proteins, contained in the interstitial water of biofilms formed on the stones. We also analyzed the molecular weight distribution, chemical species, and availability to bacteria of some saccharides in the interstitial water. Colorimetric assays showed that the concentrations of saccharides and proteins in the biofilm interstitial water were significantly higher (ca. 750 times) than those in the surrounding lake waters (p < 0.05). Chromatographic analyses demonstrated that the saccharides in the interstitial waters were mainly of low molecular-weight saccharides such as glucose and maltose, while proteins in the interstitial water were high molecular-weight proteins (over 7000 Da). Bacterial growth and production of EPS occurred simultaneously with the decrease in the low molecular-weight saccharide concentrations when a small portion of biofilm suspension was inoculated to the collected interstitial water, suggesting that the dissolved saccharides in the interstitial water support bacterial growth and formation of biofilms.

  13. The influence of nutrient and water availability on carbohydrate storage in loblolly pine

    Treesearch

    K.H. Ludovici; H.L. Allen; T.J. Albaugh; P.M. Dougherty

    2002-01-01

    We quantified the effects of nutrient and water availability on monthly whole-tree carbohydrate budgets and determined allocation patterns of storage carbohydrates in loblolly pine (Pinus taeda) to test site resource impacts on internal carbon (C) storage. A factorial combination of two nutrient and two irrigation treatments were imposed on a 7-year...

  14. [Nutrient spatiotemporal distribution and eutrophication process in subsidence waters of Huainan and Huaibei mining areas, China].

    PubMed

    Qu, Xi-Jie; Yi, Qi-Tao; Hu, You-Biao; Yan, Jia-Ping; Yu, Huai-Jun; Dong, Xiang-Lin

    2013-11-01

    A total of eight mining subsidence waters, including five sites in Huainan "Panxie" Mining Areas (PXS-1, PXS-2, PXS-3, PXS-4, and PXS-5) and three sites in Huaibei "Zhu-Yang huang" Mining Areas (HBDH, HBZH, HBNH), were selected to study the nutrient temporal and spatial distribution and trophic states. Among the sites, three sites (PXS-1, PXS-3, and HBDH) showed higher nutrient level and could be classified into moderate eutrophication, whereas the other five were in moderate nutrient level and mild eutrophication. Overall, the nutrient level of Huainan mining subsidence waters was higher than that of Huaibei mining subsidence waters. All the test samples in the two mining areas had a higher ratio of nitrogen to phosphorus (N:P), being 25-117 in Huainan and 17-157 in Huaibei, and with a seasonal variety, the lowest in growth season. The dissolved inorganic phosphorus (DIP) in total phosphorous (TP) occupied a small percentage, being averagely 15.4% and 18.4% in Huainan and Huaibei mining areas, respectively. Nitrate was the main specie of dissolved inorganic nitrogen (DIN), with the ratio of nitrate to DIN being 74% and 89% in Huainan and Huaibei mining areas, respectively. Relative to the waters age, human activities could be one of the main factors responsible for the high nutrient level and the faster eutrophication process of these waters.

  15. Water: an essential but overlooked nutrient.

    PubMed

    Kleiner, S M

    1999-02-01

    Water is an essential nutrient required for life. To be well hydrated, the average sedentary adult man must consume at least 2,900 mL (12 c) fluid per day, and the average sedentary adult woman at least 2,200 mL (9 c) fluid per day, in the form of noncaffeinated, nonalcoholic beverages, soups, and foods. Solid foods contribute approximately 1,000 mL (4 c) water, with an additional 250 mL (1 c) coming from the water of oxidation. The Nationwide Food Consumption Surveys indicate that a portion of the population may be chronically mildly dehydrated. Several factors may increase the likelihood of chronic, mild dehydration, including a poor thirst mechanism, dissatisfaction with the taste of water, common consumption of the natural diuretics caffeine and alcohol, participation in exercise, and environmental conditions. Dehydration of as little as 2% loss of body weight results in impaired physiological and performance responses. New research indicates that fluid consumption in general and water consumption in particular can have an effect on the risk of urinary stone disease; cancers of the breast, colon, and urinary tract; childhood and adolescent obesity; mitral valve prolapse; salivary gland function; and overall health in the elderly. Dietitians should be encouraged to promote and monitor fluid and water intake among all of their clients and patients through education and to help them design a fluid intake plan. The influence of chronic mild dehydration on health and disease merits further research.

  16. Nutrients levels in paddy soils and flood waters from Tagus-Sado basin: the impact of farming system

    NASA Astrophysics Data System (ADS)

    Santos, Erika S.; Abreu, Maria Manuela; Magalhães, Maria Clara; Viegas, Wanda; Amâncio, Sara; Cordovil, Cláudia

    2017-04-01

    Application of fertilizers for crops can contribute to nutrients surplus, namely nitrogen, in both groundwater and surface waters resulting in serious environmental problems. The impacts on water quality due to fertilizers are related to land management. In paddy fields using high amounts of water, the nutrient dynamic knowledge is essential to evaluate the impact of farming system. The aims of this study were to evaluate: i)nutrients levels in soils and floodwaters from rice cultivation in Tagus-Sado basin (Portugal); ii)the effect, under controlled conditions, of different irrigation techniques on nutrient enrichment of floodwaters from rice cultivation. Composite samples (n=24) of paddy soils (0-15 cm) and floodwaters were collected, during rice flooding period. In the field, pH and electrical conductivity (EC) were determined in waters. Soil pH, concentrations of Corganic, NPK and nutrients (Ca, Cu, Fe, Mg, Mn, Zn) in soils and floodwaters (nitrites, nitrates, phosphates) were determined. A mesocosm assay was performed in lysimeters with a paddy soil (pH: 5.6; g/kg- Ntotal: 2.0, Pextractable: 0.04, Kextractable: 0.6, Corganic: 35.5) and different irrigation techniques (n=3): a)flood; b)four floods per day (great water renewal); c)flood until rice flowering and then a normal superficial irrigation. Rice cultivation was done by transplant as in the field. Irrigation water come from a well. Same chemical characterization than in field assay were determined in floodwater and irrigation water. In field conditions, paddy soils had values of pH between 5.1 and 8.1 and a great fertility range (g/kg; Ntotal: 0.4‒2.2; Pextractable: 0.01‒0.2; Kextractable: 0.04‒0.7; Corganic: 6.5‒37.9). Total soil concentrations of Cu, Fe, and Zn in soils were in same range and below maximum admissible values for agriculture. Total soil concentrations of Ca, Mg and Mn, showed higher heterogeneity (g/kg; 1.2‒19.3, 7.6‒34.2 and 0.2‒1.5 respectively). Floodwaters presented pH

  17. Sunlight penetration through the Martian polar caps: Effects on the thermal and frost budgets

    NASA Technical Reports Server (NTRS)

    Lindner, Bernhard Lee

    1992-01-01

    An energy balance model of the seasonal polar caps on Mars is modified to include penetration of solar radiation into and through the ice. Penetration of solar radiation has no effect on subsurface temperature or total frost sublimation if seasonal ice overlies a dust surface. An effect is noted for seasonal ice which overlies the residual polar caps. For the case of an exposed water-ice residual polar cap, the temperature at depth is calculated to be up to several degrees warmer and the calculated lifetime of seasonal CO2 frost is slightly lower when penetration of sunlight is properly treated in the model. For the case of a residual polar cap which is perennially covered by CO2 frost, the calculated lifetime of seasonal CO2 frost is very slightly increased as a result of sunlight penetration through the ice. Hence, penetration of sunlight into the ice helps to stabilize the observed dichotomy in the residual polar caps on Mars, although it is a small effect.

  18. Sunlight penetration through the Martian polar caps - Effects on the thermal and frost budgets

    NASA Technical Reports Server (NTRS)

    Lindner, Bernhard L.

    1992-01-01

    An energy balance model of the seasonal polar caps on Mars is modified to include penetration of solar radiation into and through the ice. Penetration of solar radiation has no effect on subsurface temperature or total frost sublimation if seasonal ice overlies a dust surface. An effect is noted for seasonal ice which overlies the residual polar caps. For the case of an exposed water-ice residual polar cap, the temperature at depth is calculated to be up to several degrees warmer, and the calculated lifetime of seasonal CO2 frost is slightly lower when penetration of sunlight is properly treated in the model. For the case of a residual polar cap which is perennially covered by CO2 frost, the calculated lifetime of seasonal CO2 frost is very slightly increased as a result of sunlight penetration through the ice. Hence, penetration of sunlight into the ice helps to stabilize the observed dichotomy in the residual polar caps on Mars, although it is a small effect.

  19. Nutrient Loads Flowing into Coastal Waters from the Main Rivers of China (2006–2012)

    PubMed Central

    Tong, Yindong; Zhao, Yue; Zhen, Gengchong; Chi, Jie; Liu, Xianhua; Lu, Yiren; Wang, Xuejun; Yao, Ruihua; Chen, Junyue; Zhang, Wei

    2015-01-01

    Based on monthly monitoring data of unfiltered water, the nutrient discharges of the eight main rivers flowing into the coastal waters of China were calculated from 2006 to 2012. In 2012, the total load of NH3-N (calculated in nitrogen), total nitrogen (TN, calculated in nitrogen) and total phosphorus (TP, calculated in phosphorus) was 5.1 × 105, 3.1 × 106 and 2.8 × 105 tons, respectively, while in 2006, the nutrient load was 7.4 × 105, 2.2 × 106 and 1.6 × 105 tons, respectively. The nutrient loading from the eight major rivers into the coastal waters peaked in summer and autumn, probably due to the large water discharge in the wet season. The Yangtze River was the largest riverine nutrient source for the coastal waters, contributing 48% of the NH3-N discharges, 66% of the TN discharges and 84% of the TP discharges of the eight major rivers in 2012. The East China Sea received the majority of the nutrient discharges, i.e. 50% of NH3-N (2.7 × 105 tons), 70% of TN (2.2 × 106 tons) and 87% of TP (2.5 × 105 tons) in 2012. The riverine discharge of TN into the Yellow Sea and Bohai Sea was lower than that from the direct atmospheric deposition, while for the East China Sea, the riverine TN input was larger. PMID:26582206

  20. Field investigation to assess nutrient emission from paddy field to surface water in river catchment

    NASA Astrophysics Data System (ADS)

    Kogure, Kanami; Aichi, Masaatsu; Zessner, Matthias

    2015-04-01

    In order to maintain good river environment, it is remarkably important to understand and to control nutrient behavior such as Nitrogen and Phosphorus. Our former research dealing with nutrient emission analysis in the Tone River basin area in Japan, in addition to urban and industrial waste water, nutrient emission from agricultural activity is dominant pollution source into the river system. Japanese style agriculture produces large amount of rice and paddy field occupies large areas in Japanese river basin areas. While paddy field can deteriorate river water quality by outflow of fertilizer, it is also suggested that paddy field has water purification function. As we carried out investigation in the Tone River Basin area, data were obtained which dissolved nitrogen concentration is lower in discharging water from paddy field than inflowing water into the field. Regarding to nutrient emission impact from paddy field, sufficient data are required to discuss quantitatively seasonal change of material behavior including flooding season and dry season, difference of climate condition, soil type, and rice species, to evaluate year round comprehensive impact from paddy field to the river system. In this research, field survey in paddy field and data collection relating rice production were carried out as a preliminary investigation to assess how Japanese style paddy field contributes year round on surface water quality. Study sites are three paddy fields located in upper reach of the Tone River basin area. The fields are flooded from June to September. In 2014, field investigations were carried out three times in flooding period and twice in dry period. To understand characteristics of each paddy field and seasonal tendency accompanying weather of agricultural event, short term investigations were conducted and we prepare for further long term investigation. Each study site has irrigation water inflow and outflow. Two sites have tile drainage system under the field and

  1. Characterization of biomass residues and their amendment effects on water sorption and nutrient leaching in sandy soil.

    PubMed

    Wang, Letian; Tong, Zhaohui; Liu, Guodong; Li, Yuncong

    2014-07-01

    In this study, we evaluated the efficiency of two types of biomass residues (fermentation residues from a bioethanol process, FB; brown mill residues from a papermaking process, BM) as amendments for a sandy soil. The characteristics of these residues including specific surface areas, morphologies and nutrient sorption capacity were measured. The effects of biorefinery residues on water and nutrient retention were investigated in terms of different particle sizes and loadings. The results indicated that bio-based wastes FB and BM were able to significantly improve water and nutrient retention of sandy soil. The residues with larger surface areas had better water and nutrient retention capability. Specifically, in the addition of 10% loading, FB and BM was able to improve water retention by approximately 150% and 300%, while reduce 99% of ammonium and phosphate concentration in the leachate compare to the soil control, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Heterotrophic bacterium Pseudomonas saponiphila and sunlight as impact factors on organo-mineral colloids transformations in boreal humic waters

    NASA Astrophysics Data System (ADS)

    Oleinikova, Olga; Drozdova, Olga; Shirokova, Liudmila; Lapitskiy, Sergey; Bychkov, Andrew; Pokrovsky, Oleg

    2017-04-01

    Two of the main factors of carbon balance in high latitudes, known to govern the CO2 flux from the lakes and rivers to the atmosphere, are bacterial mineralization (respiration) of allochthonous dissolved organic matter (DOM) and photochemical degradation of DOM. Yet, in contrast to large numbers of experimental and field studies on these factors impact on the utilization of DOM of different origin, the fate of metals bound to colloids during bacterial processing of DOM and behavior of trace element (TE) during photodegradation of DOM remains poorly constrained. This is especially important in view of essentially organic and organo-mineral colloidal status of TE in most boreal waters. To answer this questions, a monoculture of Pseudomonas saponiphila from a boreal creek in NW Karelia (Russia) was separated and allowed to interact with boreal peat leachate in nutrient-free media. We quantified colloidal transformation of the peat leachate during 5-days activity of live bacteria using 3 kDa, 50 kDa Amicon® centrifugal filtration and 0.45 µm syringe filtration. The total net decrease of the concentration of Dissolved Organic Carbon (DOC) over 93 h of exposure was within 5% of the initial value for all fractions except low molecular weight one (< 3 kDa), which yielded a 16%-decrease due to long-term bio-uptake or coagulation. Elements most affected by bacterial presence were Al, Mn, (Ni), Cu, Ga, REEs, Y, U which exhibited essentially the adsorption at the cell surface over first hrs of reaction, and Fe, Ti, (Zr), and Nb showing short-term adsorption and long-term assimilation. Towards a better understanding of concentration, size fractionation and speciation change of TE in boreal waters subjected to solar radiation, we conducted on-site photo-degradation experiments in stream and bog water from pristine zone of Northern Karelia (Russian subarctic). After 5 days of exposure, the DOM in stream photodegraded in a much smaller degree than that in the bog water with 25

  3. Impacts of Cropland Changes on Water Balance, Sediment and Nutrient Transport in Eden River, UK

    NASA Astrophysics Data System (ADS)

    Huang, Yumei; Quinn, Paul; Liang, Qiuhua; Adams, Russell

    2017-04-01

    Water is the key to food and human life. Farming is the main part of economic and society in Eden, with approximately 2000 farms which covers 95% of under crops. However, with the growth of farming practice and global climate changes, Eden has presented great challenges and bringing uncertainty in the water quality caused by the agricultural diffuse pollution. This expected to reduce negative impacts of the water diffuse pollution from agriculture in Eden. Therefore, there is a high need to ensure effective water resource management to enhance water quality, to address the flow pathways and sediment transport in different farming practice and cropland changes. Hence we need to understand nutrient and the hydrological flow pathways from soil to Hillslope to channel. The aim of this research is to evaluate the impacts of different cropland changes on water balance, sediment and nutrient transport. By using the hydrological models Soil and Water Assessment Tool (SWAT) and the Catchment Runoff Attenuation Flux Tool (CRAFT), it can show the sediment and nutrient export from the load for each flow pathways (overland flow, soil water flow and ground water flow). We will show results from a small research catchment (10km2) area to the whole of Eden (800km2) at a daily time step.

  4. Sunlight Responsive Thermochromic Window System

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Millett, F,A; Byker,H, J

    2006-10-27

    Pleotint has embarked on a novel approach with our Sunlight Responsive Thermochromic, SRT™, windows. We are integrating dynamic sunlight control, high insulation values and low solar heat gain together in a high performance window. The Pleotint SRT window is dynamic because it reversibly changes light transmission based on thermochromics activated directly by the heating effect of sunlight. We can achieve a window package with low solar heat gain coefficient (SHGC), a low U value and high insulation. At the same time our windows provide good daylighting. Our innovative window design offers architects and building designers the opportunity to choose theirmore » desired energy performance, excellent sound reduction, external pane can be self-cleaning, or a resistance to wind load, blasts, bullets or hurricanes. SRT windows would provide energy savings that are estimated at up to 30% over traditional window systems. Glass fabricators will be able to use existing equipment to make the SRT window while adding value and flexibility to the basic design. Glazing installers will have the ability to fit the windows with traditional methods without wires, power supplies and controllers. SRT windows can be retrofit into existing buildings,« less

  5. Thermal and other tests of photovoltaic modules performed in natural sunlight

    NASA Technical Reports Server (NTRS)

    Stultz, J. W.

    1979-01-01

    The nominal operating cell temperature (NOCT), an effective way to characterize the thermal performance of a photovoltaic module in natural sunlight, is developed. NOCT measurements for more than twenty different modules are presented. Changes in NOCT reflect changes in module design, residential roof mounting, and dirt accumulation. Other test results show that electrical performance is improved by cooling modules with water and by use of a phase change wax. Electrical degradation resulting from the marriage of photovoltaic and solar water heating modules is demonstrated. Cost-effectiveness of each of these techniques is evaluated.

  6. Persistence of Bacteroides ovatus under simulated sunlight irradiation

    PubMed Central

    2014-01-01

    Background Bacteroides ovatus, a member of the genus Bacteroides, is considered for use in molecular-based methods as a general fecal indicator. However, knowledge on its fate and persistence after a fecal contamination event remains limited. In this study, the persistence of B. ovatus was evaluated under simulated sunlight exposure and in conditions similar to freshwater and seawater. By combining propidium monoazide (PMA) treatment and quantitative polymerase chain reaction (qPCR) detection, the decay rates of B. ovatus were determined in the presence and absence of exogenous photosensitizers and in salinity up to 39.5 parts per thousand at 27°C. Results UVB was found to be important for B. ovatus decay, averaging a 4 log10 of decay over 6 h of exposure without the presence of extracellular photosensitizers. The addition of NaNO2, an exogenous sensitizer producing hydroxyl radicals, did not significantly change the decay rate of B. ovatus in both low and high salinity water, while the exogenous sensitizer algae organic matter (AOM) slowed down the decay of B. ovatus in low salinity water. At seawater salinity, the decay rate of B. ovatus was slower than that in low salinity water, except when both NaNO2 and AOM were present. Conclusion The results of laboratory experiments suggest that if B. ovatus is released into either freshwater or seawater environment in the evening, 50% of it may be intact by the next morning; if it is released at noon, only 50% may be intact after a mere 5 min of full spectrum irradiation on a clear day. This study provides a mechanistic understanding to some of the important environmental relevant factors that influenced the inactivation kinetics of B. ovatus in the presence of sunlight irradiation, and would facilitate the use of B. ovatus to indicate the occurrence of fecal contamination. PMID:24993443

  7. Ultra-Accelerated Natural Sunlight Exposure Testing Facilities

    DOEpatents

    Lewandowski, Allan A.; Jorgensen, Gary J.

    2004-11-23

    A multi-faceted concentrator apparatus for providing ultra-accelerated natural sunlight exposure testing for sample materials under controlled weathering conditions comprising: facets that receive incident natural sunlight, transmits VIS/NIR and reflects UV/VIS onto a secondary reflector that delivers a uniform flux of UV/VIS onto a sample exposure plane located near a center of a facet array in a chamber that provide concurrent levels of temperature and/or relative humidity at high levels of up to 100.times. of natural sunlight that allow sample materials to be subjected to accelerated irradiance exposure factors for a significant period of time of about 3 to 10 days to provide a corresponding time of about at least a years worth representative weathering of sample materials.

  8. Ultra-accelerated natural sunlight exposure testing facilities

    DOEpatents

    Lewandowski, Allan A.; Jorgensen, Gary J.

    2003-08-12

    A multi-faceted concentrator apparatus for providing ultra-accelerated natural sunlight exposure testing for sample materials under controlled weathering conditions comprising: facets that receive incident natural sunlight, transmits VIS/NIR and reflects UV/VIS to deliver a uniform flux of UV/VIS onto a sample exposure plane located near a center of a facet array in chamber means that provide concurrent levels of temperature and/or relative humidity at high levels of up to 100.times. of natural sunlight that allow sample materials to be subjected to accelerated irradiance exposure factors for a significant period of time of about 3 to 10 days to provide a corresponding time of about at least a years worth representative weathering of sample materials.

  9. Conformal Nitrogen-Doped TiO 2 Photocatalytic Coatings for Sunlight-Activated Membranes

    DOE PAGES

    Lee, Anna; Libera, Joseph A.; Waldman, Ruben Z.; ...

    2017-01-24

    Photocatalytic degradation of organic contaminants is enticing for addressing challenging, nontraditional water sources. A novel nitrogen-doping method is utilized to grow conformal titania coatings with visible-light activity on porous membranes. Here, the resulting membranes exhibit effective degradation of model organic species in simulated sunlight while at the same time requiring substantially lower transmembrane pressure than undoped membranes.

  10. Monitoring of nutrients, pesticides, and metals in waters, sediments, and fish of a wetland.

    PubMed

    Salvadó, V; Quintana, X D; Hidalgo, M

    2006-10-01

    Wetland areas are of extraordinary importance for the conservation of wildlife. The Aiguamolls de l'Empordà Natural Park, located in Girona (northeast Spain), is one of the few areas in Europe acting as a way station for migratory birds. The natural park is made up of a brackish water reserve and a fresh water reserve. Agriculture and tourism, which are concentrated especially around coastal population centers, are the main activities in this area and result in the release into the environment of nutrients, pesticides, and heavy metals. This article aims to investigate the presence of nutrients, selected pesticides (organochlorine compounds, permethrin and triazines) and metals (Cr, Cu, Cd, Ni and Pb) in water, sediments, and fish samples. In the case of water, seasonal variations in levels of contamination were also monitored. Comparison was made of the fresh and brackish water reserves and concentration factors for metals and pesticides in sediment were determined. We conclude that the most significant sources of contamination in the natural park are from the entry of pesticides and nutrients into surface waters and sediments as a result of the intensive farming activity of the surrounding areas. The pesticides with the greatest presence were found to be lindane, heptachlor epoxide, permethrin, and atrazine. Among the metals analyzed, Cu and Cr presented the highest concentrations in surface waters and sediments.

  11. Representation of solid and nutrient concentrations in irrigation water from tailwater recovery systems by surface water grab samples

    USDA-ARS?s Scientific Manuscript database

    Tailwater recovery (TWR) systems are being implemented on agricultural landscapes to create an additional source of irrigation water. Existing studies have sampled TWR systems using grab samples; however, the applicability of solids and nutrient concentrations in these samples to water being irrigat...

  12. Hierarchical FeTiO3-TiO2 hollow spheres for efficient simulated sunlight-driven water oxidation.

    PubMed

    Han, Taoran; Chen, Yajie; Tian, Guohui; Wang, Jian-Qiang; Ren, Zhiyu; Zhou, Wei; Fu, Honggang

    2015-10-14

    Oxygen generation is the key step for the photocatalytic overall water splitting and considered to be kinetically more challenging than hydrogen generation. Here, an effective water oxidation catalyst of hierarchical FeTiO3-TiO2 hollow spheres are prepared via a two-step sequential solvothermal processes and followed by thermal treatment. The existence of an effective heterointerface and built-in electric field in the surface space charge region in FeTiO3-TiO2 hollow spheres plays a positive role in promoting the separation of photoinduced electron-hole pairs. Surface photovoltage, transient-state photovoltage, fluorescence and electrochemical characterization are used to investigate the transfer process of photoinduced charge carriers. The photogenerated charge carriers in the hierarchical FeTiO3-TiO2 hollow spheres with a proper molar ratio display much higher separation efficiency and longer lifetime than those in the FeTiO3 alone. Moreover, it is suggested that the hierarchical porous hollow structure can contribute to the enhancement of light utilization, surface active sites and material transportation through the framework walls. This specific synergy significantly contributes to the remarkable improvement of the photocatalytic water oxidation activity of the hierarchical FeTiO3-TiO2 hollow spheres under simulated sunlight (AM1.5).

  13. Traceable calibration of photovoltaic reference cells using natural sunlight

    NASA Astrophysics Data System (ADS)

    Müllejans, H.; Zaaiman, W.; Pavanello, D.; Dunlop, E. D.

    2018-02-01

    At the European Solar Test Installation (ESTI) photovoltaic (PV) reference cells are calibrated traceably to SI units via the World Radiometric Reference (WRR) using natural sunlight. The Direct Sunlight Method (DSM) is described in detail and the latest measurement results and an updated uncertainty budget are reported. These PV reference cells then provide a practical means for measuring the irradiance of natural or simulated sunlight during the calibration of other PV devices.

  14. Stoichiometry, Metabolism and Nutrient Limitation Across the Periodic Table in Natural Flowing-Water Chemostats

    NASA Astrophysics Data System (ADS)

    Cohen, M. J.; Nifong, R. L.; Kurz, M. J.; Cropper, W. P.; Martin, J. B.

    2014-12-01

    Relative supplies of macro and micronutrients (C,N,P, various metals), along with light and water, controls ecosystem metabolism, trophic energy transfer and community structure. Here we test the hypothesis, using measurements from 41 spring-fed rivers in Florida, that tissue stoichiometry indicates autotroph nutrient limitation status. Low variation in discharge, temperature and chemical composition within springs, but large variation across springs creates an ideal setting to assess the relationship between limitation and resource supply. Molar N:P ranges from 0.4 to 90, subjecting autotrophs to dramatically different nutrient supply. Over this gradient, species-specific autotroph tissue C:N:P ratios are strictly homeostatic, and with no evidence that nutrient supply affects species composition. Expanding to include 19 metals and micronutrients revealed autotrophs are more plastic in response to micronutrient variation, particularly for iron and manganese whose supply fluxes are small compared to biotic demand. Using a Droop model modified to reflect springs conditions (benthic production, light limitation, high hydraulic turnover), we show that tissue stoichiometry transitions from homeostatic to plastic with the onset of nutrient limitation, providing a potentially powerful new tool for predicting nutrient limitation and thus eutrophication in flowing waters.

  15. Sunlight modulates the relative importance of heterotrophic bacteria and picophytoplankton in DMSP-sulphur uptake

    PubMed Central

    Ruiz-González, Clara; Simó, Rafel; Vila-Costa, Maria; Sommaruga, Ruben; Gasol, Josep M

    2012-01-01

    There is a large body of evidence supporting a major role of heterotrophic bacteria in dimethylsulphoniopropionate (DMSP) utilisation as a source of reduced sulphur. However, a role for phototrophic microorganisms has been only recently described and little is known about their contribution to DMSP consumption and the potential modulating effects of sunlight. In an attempt to ascertain the relative quantitative roles of heterotrophic bacteria and picophytoplankton in the osmoheterotrophic uptake of DMSP-sulphur upon exposure to natural sunlight conditions, we incubated northwestern Mediterranean waters under various optical filters and used an array of bulk and single-cell activity methods to trace the fate of added 35S-DMSP. Flow cytometry cell sorting confirmed dark 35S uptake by Prochlorococcus, Synechococcus and heterotrophic bacteria, the latter being the most efficient in terms of uptake on a cell volume basis. Under exposure to full sunlight, however, the relative contribution of Synechococcus was significantly enhanced, mainly because of the inhibition of heterotrophic bacteria. Microautoradiography showed a strong increase in the proportion of Synechococcus cells actively taking up 35S-DMSP, which, after full sunlight exposure, made up to 15% of total active Bacteria. Parallel incubations with 3H-leucine generally showed no clear responses to light. Finally, size-fractionated assimilation experiments showed greater relative cyanobacterial assimilation during the day than at night compared with that of heterotrophic bacteria. Our results show for the first time a major influence of sunlight in regulating the competition among autotrophic and heterotrophic picoplankton for DMSP uptake at both the daily and seasonal time scales. PMID:21955992

  16. Vitamin D and Sunlight Exposure in Newly-Diagnosed Parkinson's Disease.

    PubMed

    Wang, Juan; Yang, Deyu; Yu, Yu; Shao, Gaohai; Wang, Qunbo

    2016-03-04

    Circulating vitamin D has previously been found to be lower in patients with Parkinson's disease (PD), while the effects of sunlight exposure have not yet been fully investigated. Therefore, we evaluated the associations between serum vitamin D, vitamin D intake, sunlight exposure, and newly-diagnosed PD patients in a Chinese population. This case-control study measured serum 25-hydroxyvitamin D (25(OH)D) levels and sunlight exposure in 201 patients with newly-diagnosed PD and 199 controls without neurodegenerative diseases. Data on vitamin D intake and sunlight exposure were obtained using a self-report questionnaire. Multivariable logistic regressions were employed to evaluate the associations between serum 25(OH)D levels, sunlight exposure, and PD. Adjustments were made for sex, age, smoking, alcohol use, education, BMI, and vitamin D intake. There were significantly lower levels of serum 25(OH)D (20.6 ± 6.5 ng/mL), daily vitamin D intake (8.3 ± 3.7 g/day), and sunlight exposure (9.7 ± 4.1 h/week) in patients with PD compared to healthy controls (p < 0.05). Crude odds ratios (ORs) for PD in the quartiles of serum 25(OH)D were 1 (reference), 0.710 (0.401, 1.257), 0.631 (0.348, 1.209), and 0.483 (0.267, 0.874), respectively. Crude ORs for PD in quartiles of sunlight exposure were 1 (reference), 0.809 (0.454, 1.443), 0.623 (0.345, 1.124) and 0.533 (0.294, 0.966), respectively. A significant positive correlation between serum 25(OH)D and sunlight exposure was found, but serum 25(OH)D was not correlated with daily vitamin D intake. This study indicates that lower levels of serum 25(OH)D and sunlight exposure are significantly associated with an increased risk for PD.

  17. Sunlight Diffusing Tent for Lunar Worksite

    NASA Technical Reports Server (NTRS)

    Burleson, Blair; Clark, Todd; Deese, Todd; Gentry, Ernest; Samad, Abdul

    1990-01-01

    The purpose is to provide a solution to problems astronauts encounter with sunlight on the lunar surface. Due to the absence of an atmosphere the Moon is subjected to intense sunlight creating problems with color and contrast. This problem can be overcome by providing a way to reduce intensity and diffuse the light in a working environment. The solution to the problem utilizes an umbrella, tent-like structure covered with a diffusing material. The design takes into account structural materials, stresses, fabrics, and deployment.

  18. Impacts of Cover Crops on Water and Nutrient Dynamics in Agroecosystems

    NASA Astrophysics Data System (ADS)

    Williard, K.; Swanberg, S.; Schoonover, J.

    2013-05-01

    Intensive cropping systems of corn (Zea Mays L.) and soybeans (Glycine max) are commonly leaky systems with respect to nitrogen (N). Reactive N outputs from agroecosystems can contribute to eutrophication and hypoxic zones in downstream water bodies and greenhouse gas (N2O) emissions. Incorporating cover crops into temperate agroecosystem rotations has been promoted as a tool to increase nitrogen use efficiency and thus limit reactive N outputs to the environment. Our objective was determine how cereal rye (Secale cereal L.) and annual ryegrass (Lolium multiflorum) cover crops impact nutrient and soil water dynamics in an intensive corn and soybean cropping rotation in central Illinois. Cover crops were planted in mid to late October and terminated in early April prior to corn or soybean planting. In the spring just prior to cover crop termination, soil moisture levels were lower in the cover crop plots compared to no cover plots. This can be a concern for the subsequent crop in relatively dry years, which the Midwestern United States experienced in 2012. No cover plots had greater nutrient leaching below the rooting zone compared to cover crop areas, as expected. The cover crops were likely scavenging nutrients during the fall and early spring and should provide nutrients to the subsequent crop via decomposition and mineralization of the cover crop residue. Over the long term, cover crop systems should produce greater inputs and cycling of carbon and N, increasing the productivity of crops due to the long-term accumulation of soil organic matter. This study demonstrates that there may be short term trade-offs in reduced soil moisture levels that should be considered alongside the long term nutrient scavenging and recycling benefits of cover crops.

  19. Effects of Humic Acid and Sunlight on the Generation and Aggregation State of Aqu/C60 Nanoparticles

    EPA Science Inventory

    Aqueous suspensions of nanoscale C60 aggregates (aqu/C60) were produced by stirring in water with Suwanee River Humic Acid (humic acid) and water from Call’s Creek, a small stream near Athens, GA. Time course experiments were conducted to determine the effects of sunlight and sol...

  20. Water Mass Classification on a Highly Variable Arctic Shelf Region: Origin of Laptev Sea Water Masses and Implications for the Nutrient Budget

    NASA Astrophysics Data System (ADS)

    Bauch, D.; Cherniavskaia, E.

    2018-03-01

    Large gradients and inter annual variations on the Laptev Sea shelf prevent the use of uniform property ranges for a classification of major water masses. The central Laptev Sea is dominated by predominantly marine waters, locally formed polynya waters and riverine summer surface waters. Marine waters enter the central Laptev Sea from the northwestern Laptev Sea shelf and originate from the Kara Sea or the Arctic Ocean halocline. Local polynya waters are formed in the Laptev Sea coastal polynyas. Riverine summer surface waters are formed from Lena river discharge and local melt. We use a principal component analysis (PCA) in order to assess the distribution and importance of water masses within the Laptev Sea. This mathematical method is applied to hydro-chemical summer data sets from the Laptev Sea from five years and allows to define water types based on objective and statistically significant criteria. We argue that the PCA-derived water types are consistent with the Laptev Sea hydrography and indeed represent the major water masses on the central Laptev Sea shelf. Budgets estimated for the thus defined major Laptev Sea water masses indicate that freshwater inflow from the western Laptev Sea is about half or in the same order of magnitude as freshwater stored in locally formed polynya waters. Imported water dominates the nutrient budget in the central Laptev Sea; and only in years with enhanced local polynya activity is the nutrient budget of the locally formed water in the same order as imported nutrients.

  1. Spectral comparisons of sunlight and different lamps

    NASA Technical Reports Server (NTRS)

    Deitzer, Gerald

    1994-01-01

    The tables in this report were compiled to characterize the spectra of available lamp types and provide comparison to the spectra of sunlight. Table 1 reports the spectral distributions for various lamp sources and compares them to those measured for sunlight. Table 2 provides the amount of energy in Wm(exp -2) relative to the number of photons of PAR (photosynthetically active radiation) (400-700 nm) for each light source.

  2. The Thames Science Plan: Suggested Hydrologic Investigations to Support Nutrient-Related Water-Quality Improvements in the Thames River Basin, Connecticut

    DTIC Science & Technology

    2005-01-01

    Nutrient- Related Water-Quality Improvements in the Thames River Basin, Connecticut Open-File Report 2005-1208 U.S. Department of the Interior U.S...Investigations to Support Nutrient- Related Water-Quality Improvements in the Thames River Basin, Connecticut 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM...Suggested Hydrologic Investigations to Support Nutrient- Related Water-Quality Improvements in the Thames River Basin, Connecticut By Elaine C. Todd

  3. Carry-Over Effects of Water and Nutrient Supply on Water Use of Pinus Taeda

    Treesearch

    Brent E. Ewers; Ram Oren; Timothy J. Albaugh; Phillip M. Dougherty

    1999-01-01

    Abstract. A study of the effects of nutrients and water supply (2 X 2 factorial experiment) was conducted in a 12-yr-old stand of loblolly pine (Pinus taeda L.) during a period in which soil moisture was not augmented by irrigation because of frequent rain events. Information on the responses of sapwood-to-leaf area ratio and...

  4. Water quality assessment of the San Joaquin--Tulare basins, California; analysis of available data on nutrients and suspended sediment in surface water, 1972-1990

    USGS Publications Warehouse

    Kratzer, Charles R.; Shelton, Jennifer L.

    1998-01-01

    Nutrients and suspended sediment in surface water of the San Joaquin-Tulare basins in California were assessed using 1972-1990 data from the U.S. Geological Survey's National Water Information System and the U.S. Environmental Protection Agency's STOrage and RETrieval database. Loads of nutrients and suspended sediment were calculated at several sites and the contributions from point and nonpoint sources were estimated. Trends in nutrient and suspended-sediment concentrations were evaluated at several sites, especially at the basin outlet on the San Joaquin River. Comparisons of nutrient and suspended sediment concentrations were made among three environmental settings: the San Joaquin Valley--west side, the San Joaquin Valley--east side, and the Sierra Nevada.

  5. Exogenous indirect photoinactivation of bacterial pathogens and indicators in water with natural and synthetic photosensitizers in simulated sunlight with reduced UVB.

    PubMed

    Maraccini, P A; Wenk, J; Boehm, A B

    2016-08-01

    To investigate the UVB-independent and exogenous indirect photoinactivation of eight human health-relevant bacterial species in the presence of photosensitizers. Eight bacterial species were exposed to simulated sunlight with greatly reduced UVB light intensity in the presence of three synthetic photosensitizers and two natural photosensitizers. Inactivation curves were fit with shoulder log-linear or first-order kinetic models, from which the presence of a shoulder and magnitude of inactivation rate constants were compared. Eighty-four percent reduction in the UVB light intensity roughly matched a 72-95% reduction in the overall bacterial photoinactivation rate constants in sensitizer-free water. With the UVB light mostly reduced, the exogenous indirect mechanism contribution was evident for most bacteria and photosensitizers tested, although most prominently with the Gram-positive bacteria. Results confirm the importance of UVB light in bacterial photoinactivation and, with the reduction of the UVB light intensity, that the Gram-positive bacteria are more vulnerable to the exogenous indirect mechanism than Gram-negative bacteria. UVB is the most important range of the sunlight spectrum for bacterial photoinactivation. In aquatic environments where photosensitizers are present and there is high UVB light attenuation, UVA and visible wavelengths can contribute to exogenous indirect photoinactivation. © 2016 The Society for Applied Microbiology.

  6. Export of nutrient rich Northern Component Water preceded early Oligocene Antarctic glaciation

    NASA Astrophysics Data System (ADS)

    Coxall, Helen K.; Huck, Claire E.; Huber, Matthew; Lear, Caroline H.; Legarda-Lisarri, Alba; O'Regan, Matt; Sliwinska, Kasia K.; van de Flierdt, Tina; de Boer, Agatha M.; Zachos, James C.; Backman, Jan

    2018-03-01

    The onset of the North Atlantic Deep Water formation is thought to have coincided with Antarctic ice-sheet growth about 34 million years ago (Ma). However, this timing is debated, in part due to questions over the geochemical signature of the ancient Northern Component Water (NCW) formed in the deep North Atlantic. Here we present detailed geochemical records from North Atlantic sediment cores located close to sites of deep-water formation. We find that prior to 36 Ma, the northwestern Atlantic was stratified, with nutrient-rich, low-salinity bottom waters. This restricted basin transitioned into a conduit for NCW that began flowing southwards approximately one million years before the initial Antarctic glaciation. The probable trigger was tectonic adjustments in subarctic seas that enabled an increased exchange across the Greenland-Scotland Ridge. The increasing surface salinity and density strengthened the production of NCW. The late Eocene deep-water mass differed in its carbon isotopic signature from modern values as a result of the leakage of fossil carbon from the Arctic Ocean. Export of this nutrient-laden water provided a transient pulse of CO2 to the Earth system, which perhaps caused short-term warming, whereas the long-term effect of enhanced NCW formation was a greater northward heat transport that cooled Antarctica.

  7. Life-threatening motor vehicle crashes in bright sunlight

    PubMed Central

    Redelmeier, Donald A.; Raza, Sheharyar

    2017-01-01

    Abstract Bright sunlight may create visual illusions that lead to driver error, including fallible distance judgment from aerial perspective. We tested whether the risk of a life-threatening motor vehicle crash was increased when driving in bright sunlight. This longitudinal, case-only, paired-comparison analysis evaluated patients hospitalized because of a motor vehicle crash between January 1, 1995 and December 31, 2014. The relative risk of a crash associated with bright sunlight was estimated by evaluating the prevailing weather at the time and place of the crash compared with the weather at the same hour and location on control days a week earlier and a week later. The majority of patients (n = 6962) were injured during daylight hours and bright sunlight was the most common weather condition at the time and place of the crash. The risk of a life-threatening crash was 16% higher during bright sunlight than normal weather (95% confidence interval: 9–24, P < 0.001). The increased risk was accentuated in the early afternoon, disappeared at night, extended to patients with different characteristics, involved crashes with diverse features, not apparent with cloudy weather, and contributed to about 5000 additional patient-days in hospital. The increased risk extended to patients with high crash severity as indicated by ambulance involvement, surgical procedures, length of hospital stay, intensive care unit admission, and patient mortality. The increased risk was not easily attributed to differences in alcohol consumption, driving distances, or anomalies of adverse weather. Bright sunlight is associated with an increased risk of a life-threatening motor vehicle crash. An awareness of this risk might inform driver education, trauma staffing, and safety warnings to prevent a life-threatening motor vehicle crash. Level of evidence: Epidemiologic Study, level III. PMID:28072708

  8. Life-threatening motor vehicle crashes in bright sunlight.

    PubMed

    Redelmeier, Donald A; Raza, Sheharyar

    2017-01-01

    Bright sunlight may create visual illusions that lead to driver error, including fallible distance judgment from aerial perspective. We tested whether the risk of a life-threatening motor vehicle crash was increased when driving in bright sunlight.This longitudinal, case-only, paired-comparison analysis evaluated patients hospitalized because of a motor vehicle crash between January 1, 1995 and December 31, 2014. The relative risk of a crash associated with bright sunlight was estimated by evaluating the prevailing weather at the time and place of the crash compared with the weather at the same hour and location on control days a week earlier and a week later.The majority of patients (n = 6962) were injured during daylight hours and bright sunlight was the most common weather condition at the time and place of the crash. The risk of a life-threatening crash was 16% higher during bright sunlight than normal weather (95% confidence interval: 9-24, P < 0.001). The increased risk was accentuated in the early afternoon, disappeared at night, extended to patients with different characteristics, involved crashes with diverse features, not apparent with cloudy weather, and contributed to about 5000 additional patient-days in hospital. The increased risk extended to patients with high crash severity as indicated by ambulance involvement, surgical procedures, length of hospital stay, intensive care unit admission, and patient mortality. The increased risk was not easily attributed to differences in alcohol consumption, driving distances, or anomalies of adverse weather.Bright sunlight is associated with an increased risk of a life-threatening motor vehicle crash. An awareness of this risk might inform driver education, trauma staffing, and safety warnings to prevent a life-threatening motor vehicle crash. Epidemiologic Study, level III.

  9. Sunlight exposure and multiple sclerosis in a tropical country.

    PubMed

    Espinosa-Ramírez, Guillermo; Ordoñez, Graciela; Flores-Rivera, Jose; Sotelo, Julio

    2014-07-01

    We analysed past and current sun exposure in multiple sclerosis (MS) patients as compared with matched controls in Mexico, a country with tropical climate. In a case-controlled study that include 83 MS patients and 166 matched controls, we inquired about sunlight exposure in two different periods: during adolescence and during the immediate past 5 years. Indicators were: exposure on quotidian and weekend outdoor activities with direct sunlight contact as expressed on frequency by mean number of days, daytime (morning, noon, afternoon), number of hours, visits to sunny places, and use of sunblocking agents. Additional elements were socioeconomic status, skin colour, and antecedent of varicella infection during childhood. MS patients showed a larger proportion of white skin. MS patients had more sunlight exposure during adolescence (80% versus 60%, P = 0·002); this tendency prevailed on current indicators (46% versus 30%, P = 0·02). However, current exposure on weekends (10% versus 22%, P = 0·02) and visits to the beach (64% versus 98%, P = 0·002) were lower in MS than in controls. Mexico gets more sunlight through the year than areas with high incidence of MS; nevertheless, its prevalence has greatly increased over the last decades, making it a relevant emerging disease. Our results indicate that in a tropical country, there is no association between sunlight exposure and the risk to develop MS, given the immunological effects of sunlight exposure either through UV radiation or vitamin D metabolism.

  10. Photosensitized rose Bengal-induced phototoxicity on human melanoma cell line under natural sunlight exposure.

    PubMed

    Srivastav, Ajeet K; Mujtaba, Syed Faiz; Dwivedi, Ashish; Amar, Saroj K; Goyal, Shruti; Verma, Ankit; Kushwaha, Hari N; Chaturvedi, Rajnish K; Ray, Ratan Singh

    2016-03-01

    Rose Bengal (RB) is an anionic water-soluble xanthene dye, which used for many years to assess eye cornea and conjunctiva damage. RB showed strong absorption maxima (λmax) under visible light followed by UV-B and UV-A. RB under sunlight exposure showed a time-dependent photodegradation. Our results show that photosensitized RB generates (1)O2 via Type-II photodynamic pathway and induced DNA damage under sunlight/UV-R exposure. 2'dGuO degradation, micronuclei formation, and single- and double-strand breakage were the outcome of photogenotoxicity caused by RB. Quenching studies with NaN3 advocate the involvement of (1)O2 in RB photogenotoxicity. RB induced linoleic acid photoperoxidation, which was parallel to (1)O2-mediated DNA damage. Oxidative stress in A375 cell line (human melanoma cell line) was detected through DCF-DA assay. Photosensitized RB decreased maximum cellular viability under sunlight followed by UV-B and UV-A exposures. Apoptosis was detected as a pattern of cell death through the increased of caspase-3 activity, decreased mitochondrial membrane potential, and PS translocation through inner to outer plasma membrane. Increased cytosolic levels of Bax also advocate the apoptotic cell death. We propose a p53-mediated apoptosis via increased expression of Bax gene and protein. Thus, the exact mechanism behind RB phototoxicity was the involvement of (1)O2, which induced oxidative stress-mediated DNA and membrane damage, finally apoptotic cell death under natural sunlight exposure. The study suggests that after the use of RB, sunlight exposure may avoid to prevent from its harmful effects. Copyright © 2015. Published by Elsevier B.V.

  11. Report: EPA Needs to Accelerate Adoption of Numeric Nutrient Water Quality Standards

    EPA Pesticide Factsheets

    Report #09-P-0223, August 26, 2009. EPA’s 1998 National Strategy and Plan to promote State adoption of nutrient water quality standards (which better protect aquatic life and human health) has been ineffective.

  12. Estimates of Nutrient Loading by Ground-Water Discharge into the Lynch Cove Area of Hood Canal, Washington

    USGS Publications Warehouse

    Simonds, F. William; Swarzenski, Peter W.; Rosenberry, Donald O.; Reich, Christopher D.; Paulson, Anthony J.

    2008-01-01

    Low dissolved oxygen concentrations in the waters of Hood Canal threaten marine life in late summer and early autumn. Oxygen depletion in the deep layers and landward reaches of the canal is caused by decomposition of excess phytoplankton biomass, which feeds on nutrients (primarily nitrogen compounds) that enter the canal from various sources, along with stratification of the water column that prevents mixing and replenishment of oxygen. Although seawater entering the canal is the largest source of nitrogen, ground-water discharge to the canal also contributes significant quantities, particularly during summer months when phytoplankton growth is most sensitive to nutrient availability. Quantifying ground-water derived nutrient loads entering an ecologically sensitive system such as Hood Canal is a critical component of constraining the total nutrient budget and ultimately implementing effective management strategies to reduce impacts of eutrophication. The amount of nutrients entering Hood Canal from ground water was estimated using traditional and indirect measurements of ground-water discharge, and analysis of nutrient concentrations. Ground-water discharge to Hood Canal is variable in space and time because of local geology, variable hydraulic gradients in the ground-water system adjacent to the shoreline, and a large tidal range of 3 to 5 meters. Intensive studies of ground-water seepage and hydraulic-head gradients in the shallow, nearshore areas were used to quantify the freshwater component of submarine ground-water discharge (SGD), whereas indirect methods using radon and radium geochemical tracers helped quantify total SGD and recirculated seawater. In areas with confirmed ground-water discharge, shore-perpendicular electrical resistivity profiles, continuous electromagnetic seepage-meter measurements, and continuous radon measurements were used to visualize temporal variations in ground-water discharge over several tidal cycles. The results of these

  13. Nutrient and water addition effects on day- and night-time conductance and transpiration in a C3 desert annual.

    PubMed

    Ludwig, Fulco; Jewitt, Rebecca A; Donovan, Lisa A

    2006-06-01

    Recent research has shown that many C3 plant species have significant stomatal opening and transpire water at night even in desert habitats. Day-time stomatal regulation is expected to maximize carbon gain and prevent runaway cavitation, but little is known about the effect of soil resource availability on night-time stomatal conductance (g) and transpiration (E). Water (low and high) and nutrients (low and high) were applied factorially during the growing season to naturally occurring seedlings of the annual Helianthus anomalus. Plant height and biomass were greatest in the treatment where both water and nutrients were added, confirming resource limitations in this habitat. Plants from all treatments showed significant night-time g (approximately 0.07 mol m(-2) s(-1)) and E (approximately 1.5 mol m(-2) s(-1)). In July, water and nutrient additions had few effects on day- or night-time gas exchange. In August, however, plants in the nutrient addition treatments had lower day-time photosynthesis, g and E, paralleled by lower night-time g and E. Lower predawn water potentials and higher integrated photosynthetic water-use efficiency suggests that the nutrient addition indirectly induced a mild water stress. Thus, soil resources can affect night-time g and E in a manner parallel to day-time, although additional factors may also be involved.

  14. Municipal water reuse for urban agriculture in Namibia: Modeling nutrient and salt flows as impacted by sanitation user behavior.

    PubMed

    Woltersdorf, L; Scheidegger, R; Liehr, S; Döll, P

    2016-03-15

    Adequate sanitation, wastewater treatment and irrigation infrastructure often lacks in urban areas of developing countries. While treated, nutrient-rich reuse water is a precious resource for crop production in dry regions, excessive salinity might harm the crops. The aim of this study was to quantify, from a system perspective, the nutrient and salt flows a new infrastructure connecting water supply, sanitation, wastewater treatment and nutrient-rich water reuse for the irrigation of agriculture, from a system perspective. For this, we developed and applied a quantitative assessment method to understand the benefits and to support the management of the new water infrastructure in an urban area in semi-arid Namibia. The nutrient and salt flows, as affected by sanitation user behavior, were quantified by mathematical material flow analysis that accounts for the low availability of suitable and certain data in developing countries, by including data ranges and by assessing the effects of different assumptions in cases. Also the nutrient and leaching requirements of a crop scheme were calculated. We found that, with ideal sanitation use, 100% of nutrients and salts are reclaimed and the slightly saline reuse water is sufficient to fertigate 10 m(2)/cap/yr (90% uncertainty interval 7-12 m(2)/cap/yr). However, only 50% of the P contained in human excreta could be finally used for crop nutrition. During the pilot phase fewer sanitation users than expected used slightly more water per capita, used the toilets less frequently and practiced open defecation more frequently. Therefore, it was only possible to reclaim about 85% of nutrients from human excreta, the reuse water was non-saline and contained less nutrient so that the P was the limiting factor for crop fertigation. To reclaim all nutrients from human excreta and fertigate a larger agricultural area, sanitation user behavior needs to be improved. The results and the methodology of this study can be generalized and

  15. Potential of diatom consortium developed by nutrient enrichment for biodiesel production and simultaneous nutrient removal from waste water.

    PubMed

    Marella, Thomas Kiran; Parine, Narasimha Reddy; Tiwari, Archana

    2018-05-01

    Because of the decreasing fossil fuel supply and increasing greenhouse gas (GHG) emissions, microalgae have been identified as a viable and sustainable feedstock for biofuel production. The major effect of the release of wastewater rich in organic compounds has led to the eutrophication of freshwater ecosystems. A combined approach of freshwater diatom cultivation with urban sewage water treatment is a promising solution for nutrient removal and biofuel production. In this study, urban wastewater from eutrophic Hussain Sagar Lake was used to cultivate a diatom algae consortium, and the effects of silica and trace metal enrichment on growth, nutrient removal, and lipid production were evaluated. The nano-silica-based micronutrient mixture Nualgi containing Si, Fe, and metal ions was used to optimize diatom growth. Respectively, N and P reductions of 95.1% and 88.9%, COD and BOD reductions of 91% and 51% with a biomass yield of 122.5 mg L -1  day -1 and lipid productivity of 37 mg L -1  day -1 were observed for cultures grown in waste water using Nualgi. Fatty acid profiles revealed 13 different fatty acids with slight differences in their percentage of dry cell weight (DCW) depending on enrichment level. These results demonstrate the potential of diatom algae grown in wastewater to produce feedstock for renewable biodiesel production. Enhanced carbon and excess nutrient utilization makes diatoms ideal candidates for co-processes such as CO 2 sequestration, biodiesel production, and wastewater phycoremediation.

  16. Phytoplankton succession in an isolated upwelled Benguela water body in relation to different initial nutrient conditions

    NASA Astrophysics Data System (ADS)

    Wasmund, Norbert; Nausch, Günther; Hansen, Anja

    2014-11-01

    Freshly upwelled water is poor in phytoplankton biomass but rich in nutrients. With its ageing, phytoplankton biomass increases whereas the nutrients are consumed. The overall aim of our investigation was to check the succession in the phytoplankton composition as a consequence of changing nutrient conditions. The experiments were carried out in mesocosms filled with surface water in the northern Benguela region and installed on board of R/V "Maria S. Merian". In the freshly upwelled water, phytoplankton took up nitrogen at a higher rate than phosphorus if compared with the Redfield ratio. Therefore, nitrogen was exhausted already by day 6. Nitrogen limitation after day 6 was indicated by decreasing chlorophyll a (chla) concentrations, primary production rates and productivity indices and increasing C/N ratios in particulate matter. Despite nitrogen limitation, phosphorus addition stimulated further growth, mainly of diatoms, pointing to luxury uptake. Cyanobacteria did not develop and nitrogen fixation was zero even with phosphorus and iron addition. Diatoms stay the most important group in the freshly upwelled water, but autotrophic and heterotrophic dinoflagellates increase strongly in the matured upwelled water. Mesocosms excluded disturbances by advective water transports, which influence the study of succssions under field conditions.

  17. The effect of restored and native oxbows on hydraulic loads of nutrients and stream water quality

    USGS Publications Warehouse

    Kalkhoff, Stephen J.; Hubbard, Laura E.; Joseph P.Schubauer-Berigan,

    2016-01-01

    The use of oxbow wetlands has been identified as a potential strategy to reduce nutrient transport from agricultural drainage tiles to streams in Iowa. In 2013 and 2014, a study was conducted in north-central Iowa in a native oxbow in the Lyons Creek watershed and two restored oxbow wetlands in the Prairie Creek watershed (Smeltzer west and Smeltzer east) to assess their effectiveness at reducing nitrogen and phosphorus loads. The tile line inlets carrying agricultural runoff to the oxbows, the outfall from the oxbows, and the surface waters in the streams receiving the outfall water were monitored for discharge and nutrients from February 2013 to September 2015. Smeltzer west and east also had four monitoring wells each, two in the upland and two between the oxbow and Prairie Creek to monitor surface water-groundwater interaction. The Smeltzer west and east oxbow sites also were instrumented to continuously measure the nitrate concentration. Rainfall was measured at one Lyons Creek and one Smeltzer site. Daily mean nitrate-N concentrations in Lyons Creek in 2013 ranged from 11.8 mg/L to 40.9 mg/L, the median daily mean nitrate-N concentration was 33.0 mg/L. Daily mean nitrate-N concentrations in Prairie Creek in 2013 ranged from 0.07 mg/L in August to 32.2 mg/L in June. In 2014, daily mean nitrate-N concentrations in Prairie Creek ranged from 0.17 mg/L in April to 26.7 mg/L in July; the daily mean nitrate-N concentration for the sampled period was 9.78 mg/L. Nutrient load reduction occurred in oxbow wetlands in Lyons and Prairie Creek watersheds in north-central Iowa but efficiency of reduction was variable. Little nutrient reduction occurred in the native Lyons Creek oxbow during 2013. Concentrations of all nutrient constituents were not significantly (P>0.05, Wilcoxon rank sum) different in water discharging from the tile line than in water leaving the Lyons Creek oxbow. A combination of physical features and flow conditions suggest that the residence time of

  18. Photocatalytic dye degradation with copper-titanium dioxide nanocomposites under sunlight and visible light irradiation

    NASA Astrophysics Data System (ADS)

    Qayyum Khan, Abdul; Yuan, Shuai; Niu, Sheng; Liu, Fengjiang; Feng, Guang; Jiang, Mengci; Zeng, Heping

    2018-01-01

    Photocatalytic methalyne blue dye degradation was carried out with copper (Cu)-titanium dioxide (TiO2) nanocomposites under sunlight and visible light irradiation. The Cu-TiO2 nanocomposites were fabricated via femtosecond laser ablation of pressed targets in water. The current method provides a facile route for Cu-TiO2 nanocomposites preparation, which is free from impurities on the catalysts surface. The Cu-TiO2 nanocomposites (with Cu content of 5 wt%) have shown 3 folds faster dye degradation kinetics compared with TiO2 nanoparticles under sunlight irradiation. While under visible light irradiation, the same nanocomposites exhibited 2.6 folds faster kinetics compared with TiO2 nanoparticles. The faster light harvesting efficiency of the catalysts is attributed to more hydroxyl radical generation.

  19. Food web efficiency differs between humic and clear water lake communities in response to nutrients and light.

    PubMed

    Faithfull, C L; Mathisen, P; Wenzel, A; Bergström, A K; Vrede, T

    2015-03-01

    This study demonstrates that clear and humic freshwater pelagic communities respond differently to the same environmental stressors, i.e. nutrient and light availability. Thus, effects on humic communities cannot be generalized from existing knowledge about these environmental stressors on clear water communities. Small humic lakes are the most numerous type of lake in the boreal zone, but little is known about how these lakes will respond to increased inflows of nutrients and terrestrial dissolved organic C (t-DOC) due to climate change and increased human impacts. Therefore, we compared the effects of nutrient addition and light availability on pelagic humic and clear water lake communities in a mesocosm experiment. When nutrients were added, phytoplankton production (PPr) increased in both communities, but pelagic energy mobilization (PEM) and bacterial production (BP) only increased in the humic community. At low light conditions, the addition of nutrients led to increased PPr only in the humic community, suggesting that, in contrast to the clear water community, humic phytoplankton were already adapted to lower ambient light levels. Low light significantly reduced PPr and PEM in the clear water community, but without reducing total zooplankton production, which resulted in a doubling of food web efficiency (FWE = total zooplankton production/PEM). However, total zooplankton production was not correlated with PEM, PPr, BP, PPr:BP or C:nutrient stoichiometry for either community type. Therefore, other factors such as food chain length, food quality, ultra-violet radiation or duration of the experiment, must have determined total zooplankton production and ultimately FWE.

  20. Effect of Sunlight Exposure on Bone Mineral Density in Children with Severe Disability.

    PubMed

    Kanemura, Hideaki; Hatakeyama, Kazuo; Sano, Fumikazu; Yagasaki, Hideaki; Sugita, Kanji; Aihara, Masao

    2016-08-01

    The aim of this study was to determine the efficacy of sunlight exposure for increasing bone mineral density (BMD) in children with severe disability. The subjects were five children with severe disability, aged 6 to 8 years. BMD was measured at baseline and after 3, 6, 9, and 12 months of starting sunlight exposure. All caregivers of patients were instructed to create opportunities to stay outdoors. Daily sunlight exposure time was defined as hours of staying outdoors. Mean hours of sunbathing per day were calculated at baseline and after 3, 6, 9, and 12 months of starting sunlight exposure. Sunlight exposure tended to be longer after starting than before starting in all patients, but the difference was not significant (p = 0.052). Along with the increase in sunlight exposure, BMD increased significantly after the start of sunlight exposure in all patients (p < 0.01). The serum values of total alkaline phosphatase and intact parathyroid hormone were significantly decreased and that of 25-hydroxyvitamin D was significantly increased 12 months after starting sunlight exposure. No patients had bone fractures after the start of sunlight exposure. These results suggest that sunlight exposure increased BMD, and that this may reduce the risk of bone fracture in children with disability. Georg Thieme Verlag KG Stuttgart · New York.

  1. Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense.

    PubMed

    Townsend, D W; McGillicuddy, D J; Thomas, M A; Rebuck, N R

    2014-05-01

    We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense . Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in

  2. Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense

    PubMed Central

    Townsend, D.W.; McGillicuddy, D.J.; Thomas, M.A.; Rebuck, N.R.

    2015-01-01

    We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense. Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in their

  3. Efficacy of algal metrics for assessing nutrient and organic enrichment in flowing waters

    USGS Publications Warehouse

    Porter, S.D.; Mueller, D.K.; Spahr, N.E.; Munn, M.D.; Dubrovsky, N.M.

    2008-01-01

    4. Although algal species tolerance to nutrient and organic enrichment is well documented, additional taxonomic and autecological research on sensitive, endemic algal species would further enhance water-quality assessments.

  4. Dietary calcein marking of shovelnose sturgeon and the effect of sunlight on mark retention

    USGS Publications Warehouse

    Honeyfield, D.C.; Kindschi, G.A.; Bell, T.A.; Mohler, J.W.

    2011-01-01

    Calcein, a fluorochrome dye, is a potential fish-marking agent that has not been evaluated in sturgeon. Shovelnose sturgeon Scaphirhynchus platorynchus (average weight, 9.7 g) were fed calcein, immersed in a calcein bath, or left unmarked to determine calcein mark intensity. In the first study, six treatments were evaluated in a two-by-three factorial arrangement. Feed was formulated with 2.0 g of SE-MARK/kg either as powder or in an encapsulated form. Sturgeon were fed the test diets for 5, 10, or 15 d. They readily ate feed containing powdered or encapsulated calcein. Sturgeon fed powdered calcein had more brilliant marks than those fed encapsulated calcein (8.27 versus 4.66 lm; P < 0.03) 6 months postexposure. Fish fed calcein for 15 d (11.26 lm) were more brilliant (P < 0.002) than fish fed for either 5 d (3.02 lm) or 10 d (5.11 lm). Post hoc comparison of the three treatment groups showed that sturgeon fed powdered calcein for 15 d (14.06 lm) were brighter (P < 0.01) than fish fed encapsulated calcein (8.46 lm) or fish immersed in calcein (9.68 lm). In the second study, previouslymarked sturgeon were exposed to sunlight for 14months to determine their retention of calcein marks. Dorsal marks were no longer visible on fish exposed to 100% sunlight after 8 weeks. Most but not all fish exposed to 20% sunlight had no discernable dorsalmarks after 8 weeks, but ventral marks at the pectoral fin girdle were present on all fish in the 0% and 20% sunlight exposure treatments. Feeding calcein for 15 d appears to have excellent potential for practical application, such as distinguishing hatchery-reared from wild fish. Ventral calcein marks remained visible after 14 months of exposure to 20% sunlight when sturgeon were reared in clear water. ?? American Fisheries Society 2011.

  5. Successful pacing using a batteryless sunlight-powered pacemaker.

    PubMed

    Haeberlin, Andreas; Zurbuchen, Adrian; Schaerer, Jakob; Wagner, Joerg; Walpen, Sébastien; Huber, Christoph; Haeberlin, Heinrich; Fuhrer, Juerg; Vogel, Rolf

    2014-10-01

    Today's cardiac pacemakers are powered by batteries with limited energy capacity. As the battery's lifetime ends, the pacemaker needs to be replaced. This surgical re-intervention is costly and bears the risk of complications. Thus, a pacemaker without primary batteries is desirable. The goal of this study was to test whether transcutaneous solar light could power a pacemaker. We used a three-step approach to investigate the feasibility of sunlight-powered cardiac pacing. First, the harvestable power was estimated. Theoretically, a subcutaneously implanted 1 cm(2) solar module may harvest ∼2500 µW from sunlight (3 mm implantation depth). Secondly, ex vivo measurements were performed with solar cells placed under pig skin flaps exposed to a solar simulator and real sunlight. Ex vivo measurements under real sunlight resulted in a median output power of 4941 µW/cm(2) [interquartile range (IQR) 3767-5598 µW/cm(2), median skin flap thickness 3.0 mm (IQR 2.7-3.3 mm)]. The output power strongly depended on implantation depth (ρSpearman = -0.86, P < 0.001). Finally, a batteryless single-chamber pacemaker powered by a 3.24 cm(2) solar module was implanted in vivo in a pig to measure output power and to pace. In vivo measurements showed a median output power of >3500 µW/cm(2) (skin flap thickness 2.8-3.84 mm). Successful batteryless VVI pacing using a subcutaneously implanted solar module was performed. Based on our results, we estimate that a few minutes of direct sunlight (irradiating an implanted solar module) allow powering a pacemaker for 24 h using a suitable energy storage. Thus, powering a pacemaker by sunlight is feasible and may be an alternative energy supply for tomorrow's pacemakers. Published on behalf of the European Society of Cardiology. All rights reserved. © The Author 2014. For permissions please email: journals.permissions@oup.com.

  6. U.S. Geological Survey nutrient preservation experiment; nutrient concentration data for surface-, ground-, and municipal-supply water samples and quality-assurance samples

    USGS Publications Warehouse

    Patton, Charles J.; Truitt, Earl P.

    1995-01-01

    This report is a compilation of analytical results from a study conducted at the U.S. Geological Survey, National Water Quality Laboratory (NWQL) in 1992 to assess the effectiveness of three field treatment protocols to stabilize nutrient concentra- tions in water samples stored for about 1 month at 4C. Field treatments tested were chilling, adjusting sample pH to less than 2 with sulfuric acid and chilling, and adding 52 milligrams of mercury (II) chloride per liter of sample and chilling. Field treatments of samples collected for determination of ammonium, nitrate plus nitrite, nitrite, dissolved Kjeldahl nitrogen, orthophosphate, and dissolved phosphorus included 0.45-micrometer membrane filtration. Only total Kjeldahl nitrogen and total phosphorus were determined in unfiltered samples. Data reported here pertain to water samples collected in April and May 1992 from 15 sites within the continental United States. Also included in this report are analytical results for nutrient concentrations in synthetic reference samples that were analyzed concurrently with real samples.

  7. Analysis of nutrients in the surface waters of the Georgia-Florida Coastal Plain study unit, 1970-91

    USGS Publications Warehouse

    Ham, L.K.; Hatzell, H.H.

    1996-01-01

    During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface- water sites between October 1, 1970, and September 30,1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used-(1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were generally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the

  8. Nutrient Enrichment in Estuaries from Discharge of Shallow Ground Water, Mt. Desert Island, Maine

    USGS Publications Warehouse

    Culbertson, Charles W.; Huntington, Thomas G.; Caldwell, James M.

    2007-01-01

    Nutrient enrichment from atmospheric deposition, agricultural activities, wildlife, and domestic sources is a concern at Acadia National Park because of the potential problem of water-quality degradation and eutrophication in its estuaries. Water-quality degradation has been observed at the Park?s Bass Harbor Marsh estuary but not in Northeast Creek estuary. Previous studies at Acadia National Park have estimated nutrient inputs to estuaries from atmospheric deposition and surface-water runoff, but the importance of shallow ground water that may contain nutrients derived from domestic or other sources is unknown. Northeast Creek and Bass Harbor Marsh estuaries were studied to (1) identify shallow ground-water seeps, (2) assess the chemistry of the water discharged from selected seeps, and (3) assess the chemistry of ground water in shallow ground-water hyporheic zones. The hyporheic zone is defined here as the region beneath and lateral to a stream bed, where there is mixing of shallow ground water and surface water. This study also provides baseline chemical data for ground water in selected bedrock monitoring wells and domestic wells on Mt. Desert Island. Water samples were analyzed for concentrations of nutrients, wastewater compounds, dissolved organic carbon, pH, dissolved oxygen, temperature and specific conductance. Samples from bedrock monitoring wells also were analyzed for alkalinity, major cations and anions, and trace metals. Shallow ground-water seeps to Northeast Creek and Bass Harbor Marsh estuaries at Acadia National Park were identified and georeferenced using aerial infrared digital imagery. Monitoring included the deployment of continuously recording temperature and specific conductance sensors in the seep discharge zone to access marine or freshwater signatures related to tidal flooding, gradient-driven shallow ground-water flow, or shallow subsurface flow related to precipitation events. Many potential shallow ground-water discharge zones were

  9. Nutrient characteristics of the water masses and their seasonal variability in the eastern equatorial Indian Ocean.

    PubMed

    Sardessai, S; Shetye, Suhas; Maya, M V; Mangala, K R; Prasanna Kumar, S

    2010-01-01

    Nutrient characteristics of four water masses in the light of their thermohaline properties are examined in the eastern Equatorial Indian Ocean during winter, spring and summer monsoon. The presence of low salinity water mass with "Surface enrichments" of inorganic nutrients was observed relative to 20 m in the mixed layer. Lowest oxygen levels of 19 microM at 3 degrees N in the euphotic zone indicate mixing of low oxygen high salinity Arabian Sea waters with the equatorial Indian Ocean. The seasonal variability of nutrients was regulated by seasonally varying physical processes like thermocline elevation, meridional and zonal transport, the equatorial undercurrent and biological processes of uptake and remineralization. Circulation of Arabian Sea high salinity waters with nitrate deficit could also be seen from low N/P ratio with a minimum of 8.9 in spring and a maximum of 13.6 in winter. This large deviation from Redfield N/P ratio indicates the presence of denitrified high salinity waters with a seasonal nitrate deficit ranging from -4.85 to 1.52 in the Eastern Equatorial Indian Ocean. 2010 Elsevier Ltd. All rights reserved.

  10. Combined effects between temporal heterogeneity of water supply, nutrient level, and population density on biomass of four broadly distributed herbaceous species.

    PubMed

    Hagiwara, Yousuke; Kachi, Naoki; Suzuki, Jun-Ichirou

    2012-01-01

    Temporal heterogeneity of water supply affects grassland community productivity and it can interact with nutrient level and intraspecific competition. To understand community responses, the responses of individual species to water heterogeneity must be evaluated while considering the interactions of this heterogeneity with nutrient levels and population density. We compared responses of four herbaceous species grown in monocultures to various combinations of water heterogeneity, nutrient level, and population density: two grasses (Cynodon dactylon and Lolium perenne), a forb (Artemisia princeps), and a legume (Trifolium repens). Treatment effects on shoot and root biomass were analyzed. In all four species, shoot biomass was larger under homogeneous than under heterogeneous water supply. Shoot responses of L. perenne tended to be greater at high nutrient levels. Although root biomass was also larger under homogeneous water supply, effects of water heterogeneity on root biomass were not significant in the grasses. Trifolium repens showed marked root responses, particularly at high population density. Although greater shoot and root growth under homogeneous water supply appears to be a general trend among herbaceous species, our results suggested differences among species could be found in the degree of response to water heterogeneity and its interactions with nutrient level and intraspecific competition.

  11. Reuse potential of laundry greywater for irrigation based on growth, water and nutrient use of tomato

    NASA Astrophysics Data System (ADS)

    Misra, R. K.; Patel, J. H.; Baxi, V. R.

    2010-05-01

    SummaryGreywater is considered as a valuable resource with a high reuse potential for irrigation of household lawns and gardens. However, there are possibilities of surfactant and sodium accumulation in soil from reuse of greywater which may affect agricultural productivity and environmental sustainability adversely. We conducted a glasshouse experiment to examine variation in growth, water and nutrient use of tomato ( Lycopersicon esculentum Mill. cv. Grosse Lisse) using tap water (TW), laundry greywater (GW) and solutions of low and high concentration of a detergent surfactant (LC and HC, respectively) as irrigation treatments. Each treatment was replicated five times using a randomised block design. Measurements throughout the experiment showed greywater to be significantly more alkaline and saline than the other types of irrigation water. Although all plants received 16 irrigations over a period of 9 weeks until flowering, there were little or no significant effects of irrigation treatments on plant growth. Soil water retention following irrigation reduced significantly when plants were irrigated with GW or surfactant solutions on only three of 12 occasions. On one occasion, water use measured as evapotranspiration (ET) with GW irrigation was similar to TW, but it was significantly higher than the plants receiving HC irrigation. At harvest, various components of plant biomass and leaf area for GW irrigated plants were found to be similar or significantly higher than the TW irrigated plants with a common trend of GW ⩾ TW > LC ⩾ HC. Whole-plant concentration was measured for 12 essential plant nutrients (N, P, K, Ca, Mg, S, Fe, Cu, Mn, Zn, Mo and B) and Na (often considered as a beneficial nutrient). Irrigation treatments affected the concentration of four nutrients (P, Fe, Zn and Na) and uptake of seven nutrients (P, K, Ca, Mg, Na, Fe and B) significantly. Uptake of these seven nutrients by tomato was generally in the order GW ⩾ TW > HC ⩾ LC. GW

  12. The Effect of Sunlight in Parenchyma Pith Cells Diameter of Manihot esculenta

    NASA Astrophysics Data System (ADS)

    Susanti, D.; Aziz, D. N.; Astuti, W.; Nuraeni, E.

    2017-03-01

    Sunlight is one of the factors that effect on the grow of a plant. Manihot esculenta is one of the plants that easily found in Indonesia because its role as staple food. The aim of this research is to know the correlation between sunlight the grow of parenchyma pith cells diameter of Manihot esculenta. Independent variable in this research is sunlight, and dependent variable is the parenchyma pith cells diameter of Manihot esculenta. Data was collected is in qualitative and quantitative form. Qualitative data gotten gained by morphology observation. The parenchyma pith cells of Manihot esculenta that is affected by sunlight in 1310 x 10 Lux, morphologically has hexagon, cell walls thick, solid state, and regular composition. Meanwhile, the parenchyma pith cells that has less sunlight (363 x 10 Lux) has a hexagon shape, thin cell walls thin, soft state, and irregular composition. Qualitative data suported by quantitative data. The size of parenchyma pith cells diameter that is affected by sunlight in 1310 x 10 Lux 96,4 µm. While, the stem parenchyma pith cells diameter empulur that has less sunlight (363 x 10 Lux) is 129,8 µm.

  13. 40 CFR 795.70 - Indirect photolysis screening test: Sunlight photolysis in waters containing dissolved humic...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... test system has been designed that is buffered to maintain pH and is pre-aged in sunlight to produce, subsequently, a predictable bleaching behavior. (v) The purpose of Phase 1 is to prepare, pre-age, and dilute... reason, kpE, which contains kIE, is likewise valid only for the experimental data and latitude. (8) The...

  14. 40 CFR 795.70 - Indirect photolysis screening test: Sunlight photolysis in waters containing dissolved humic...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... test system has been designed that is buffered to maintain pH and is pre-aged in sunlight to produce, subsequently, a predictable bleaching behavior. (v) The purpose of Phase 1 is to prepare, pre-age, and dilute... reason, kpE, which contains kIE, is likewise valid only for the experimental data and latitude. (8) The...

  15. 40 CFR 795.70 - Indirect photolysis screening test: Sunlight photolysis in waters containing dissolved humic...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... test system has been designed that is buffered to maintain pH and is pre-aged in sunlight to produce, subsequently, a predictable bleaching behavior. (v) The purpose of Phase 1 is to prepare, pre-age, and dilute... reason, kpE, which contains kIE, is likewise valid only for the experimental data and latitude. (8) The...

  16. Sunlight readable avionics displays

    NASA Astrophysics Data System (ADS)

    Visinski, Joseph R.

    1998-09-01

    The theme of the Cockpit Displays V Conference of 'Custom versus Consumer -- Grade Displays in Defense Applications' reflects the Raytheon Systems Company field emission display (FED) development effort. Raytheon chose to license commercial FED technology and subsequently participate in a commercial industry 'FED Alliance' to insert this technology into commercial and avionics defense applications. The unaffordability of custom military displays makes them an unfeasible choice to build a business upon. The major differences between consumer FEDs and those adapted for military/avionics installations are: (1) high brightness for sunlight visibility; (2) extended environmental range; (3) high resolution; (4) wider dimming range for sunlight to NVIS operation; (5) extended gray scales; (6) lifetime product support well beyond two year consumer market life. The transition to defense applications is further being accomplished via industry/government partnerships as the DARPA Technology Reinvestment Project (TRP) and BAA 97-31. FEDs combine cathode ray tube (CRT) and matrix addressed flat panel display technology, parts, manufacturing, and test equipment, plus open systems interfaces into a new display.

  17. Research to Inform Nutrient Thresholds and Prioritization of Watersheds for Nutrient Management

    EPA Science Inventory

    The information in this presentation focuses on SSWR's 4.02 project, which will advance the science needed to inform decisions to prioritize watersheds and nutrient sources for nutrient management and define appropriate nutrient levels for the nation’s waters, two importan...

  18. Childhood cancer incidence in relation to sunlight exposure

    PubMed Central

    Musselman, J R B; Spector, L G

    2011-01-01

    Background: There is increasing interest in the possible association between cancer incidence and vitamin D through its role as a regulator of cell growth and differentiation. Epidemiological studies in adults and one paediatric study suggest an inverse association between sunlight exposure and cancer incidence. Methods: We carried out an ecological study using childhood cancer registry data and two population-level surrogates of sunlight exposure, (1) latitude of the registry city or population centroid of the registry nation and (2) annual solar radiation. All models were adjusted for nation-level socioeconomic status using socioeconomic indicators. Results: Latitude and radiation were significantly associated with cancer incidence, and the direction of association was consistent between the surrogates. Findings were not consistent across tumour types. Conclusion: Our ecological study offers some evidence to support an association between sunlight exposure and risk of childhood cancer. PMID:21102587

  19. Sunlight photolysis of benzotriazoles - Identification of transformation products and pathways.

    PubMed

    Weidauer, Cindy; Davis, Caroline; Raeke, Julia; Seiwert, Bettina; Reemtsma, Thorsten

    2016-07-01

    Benzotriazoles (BTs) are widely used corrosion inhibitors, incompletely removed in municipal wastewater treatment. The photochemical fate of the three BTs 1H-benzotriazole (1H-BT), 4-methyl-1H-benzotriazole (4Me-BT) and 5-methyl-1H-benzotriazole (5Me-BT) and of three microbial metabolites, was studied under simulated sunlight (290-800 nm) at neutral pH in aqueous solution for 24 h. The half-life, the quantum yield and the reaction rate were determined and a total of 36 photolysis products were detected and identified using liquid chromatography-high resolution-mass spectrometry. The half-lives of all six BTs were in the range of 6-24 h under the experimental conditions. Though the quantum yields were comparatively low (0.0007-0.0021), the environmental half-lives ranged from 2.4 to 8 d, suggesting that sunlight photolysis is still a relevant degradation process of BTs in surface waters. The photolysis pathway of 1H-BT under simulated sunlight differed from that suggested for UV-radiation, in that aminophenol is formed directly rather than via aniline. Similar pathways were found for the other BTs, except for 4-hydroxy-1H-benzotriazole (4OH-BT). Most identified transformation products of the BTs showed a high reactivity and appear not to persist in the environment. Upon co-photolysis of BTs with dissolved organic matter (DOM), however, series of reaction products were determined by Fourier transform - ion cyclotron resonance - mass spectrometry (FTICR-MS) which are formed by reaction of photolysis intermediates of the BTs with DOM. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Sunlight exclusion from Muscat grape alters volatile profiles during berry development.

    PubMed

    Zhang, Haohao; Fan, Peige; Liu, Cuixia; Wu, Benhong; Li, Shaohua; Liang, Zhenchang

    2014-12-01

    The effects of sunlight exclusion on the volatile profiles of grapes during different stages of berry development were investigated by placing clusters of grapes in special boxes. Terpenes and aldehydes were the main volatile compounds in the ripe 'Jingxiangyu' berries. Sunlight exclusion was found to change volatile profiles at any stage. Sunlight exclusion from berries significantly inhibited the synthesis and accumulation of terpenes, which contribute to the characteristic aroma of Muscat grapes. However, sunlight exclusion during berry formation and veraison promoted the accumulation of aldehydes, alcohols, and ketones during the ripening stage. These results may provide important information regarding the metabolism of volatile compounds in grapes. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Nutrients: Learner's Guide for a Critical Path in Water Quality Monitoring.

    ERIC Educational Resources Information Center

    Glazer, Richard B.; And Others

    This learner's guide on nutrients is derived from a water monitoring curriculum developed at Ulster County Community College. There are 30 modules in this guide; each introduced with a statement of purpose and then broken down into an objective, learning conditions, and performance level. The modules cover: (1) safety; (2) chemical compounds; (3)…

  2. Nutrient management

    USDA-ARS?s Scientific Manuscript database

    Nutrient management has been defined as “the science and art directed to link soil, crop, weather and hydrologic factors with cultural, irrigation and soil and water conservation practices to achieve the goals of optimizing nutrient use efficiency, yields, crop quality, and economic returns, while r...

  3. DOES SUNLIGHT ENHANCE THE EFFECTIVENESS OF AVIAN PREENING FOR ECTOPARASITE CONTROL?

    PubMed Central

    Koop, Jennifer A. H.; Huber, Sarah K.; Clayton, Dale H.

    2013-01-01

    Preening is a bird’s first line of defense against harmful ectoparasites. Ectoparasites, in turn, have evolved adaptations for avoiding preening such as hardened exoskeletons and escape behavior. Earlier work suggests that some groups of ectoparasites, such as feather lice, leave hiding places in feathers that are exposed to direct sunlight, making them more vulnerable to preening. It is, therefore, conceivable that birds may choose to preen in direct sunlight, assuming it improves the effectiveness of preening. Using mourning doves and their feather lice, we tested 2 related hypotheses; (1) that birds with access to direct sunlight preen more often than birds in shade, and (2) that birds with access to direct sunlight are more effective at controlling their ectoparasites than birds in shade. To test these hypotheses, we conducted an experiment in which we manipulated both sunlight and preening ability. Our results provided no support for either hypothesis, i.e., birds given the opportunity to preen in direct sunlight did not preen significantly more often, or more effectively, than did birds in shade. Thus, the efficiency of preening for ectoparasite control appears to be independent of light intensity, at least in the case of mourning doves and their feather lice. PMID:21942474

  4. A shallow lake remediation regime with Phragmites australis: Incorporating nutrient removal and water evapotranspiration.

    PubMed

    Zhao, Ying; Yang, Zhifeng; Xia, Xinghui; Wang, Fei

    2012-11-01

    Shallow lake eutrophication has been an important issue of global water environment. Based on the simulation and field sampling experiments in Baiyangdian Lake, the largest shallow lake in North China, this study proposed a shallow lake remediation regime with Phragmites australis (reed) incorporating its opposite effects of nutrient removal and water evapotranspiration on water quality. The results of simulation experiments showed that both total nitrogen (TN) and phosphorus (TP) removal efficiencies increased with the increasing reed coverage. The TN removal efficiencies by reed aboveground uptake and rhizosphere denitrification were 11.2%, 13.8%, 22.6%, 28.4%, and 29.6% for the reed coverage of 20%, 40%, 60%, 80%, and 100%, respectively. Correspondingly, TP removal efficiencies by aboveground reed uptake were 1.4%, 2.5%, 4.4%, 7.4% and 7.9%, respectively. However, the water quality was best when the reed coverage was 60% (72 plants m(-2)). This was due to the fact that the concentration effect of reed evapotranspiration on nutrient increased with reed coverage. When the reed coverage was 100% (120 plants m(-2)), the evapotranspiration was approximately twice that without reeds. The field sampling results showed that the highest aboveground nutrient storages occurred in September. Thus, the proposed remediation regime for Baiyangdian Lake was that the reed coverage should be adjusted to 60%, and the aboveground biomass of reeds should be harvested in each September. With this remediation regime, TN and TP removal in Baiyangdian Lake were 117.8 and 4.0 g m(-2), respectively, and the corresponding removal efficiencies were estimated to be 49% and 8.5% after six years. This study suggests that reed is an effective plant for the remediation of shallow lake eutrophication, and its contrasting effects of nutrient removal and evapotranspiration on water quality should be considered for establishing the remediation regime in the future. Copyright © 2012 Elsevier

  5. Relationship of nutrient dynamics and bacterial community structure at the water-sediment interface using a benthic chamber experiment.

    PubMed

    Ki, Bo-Min; Huh, In Ae; Choi, Jung-Hyun; Cho, Kyung-Suk

    2018-04-16

    The relationships between nutrient dynamics and the bacterial community at the water-sediment interface were investigated using the results of nutrient release fluxes, bacterial communities examined by 16S rRNA pyrosequencing and canonical correlation analysis (CCA) accompanied by lab-scale benthic chamber experiment. The nutrient release fluxes from the sediments into the water were as follows: -3.832 to 12.157 mg m -2 d -1 for total phosphorus, 0.049 to 9.993 mg m -2 d -1 for PO 4 -P, -2.011 to 41.699 mg m -2 d -1 for total nitrogen, -7.915 to -0.074 mg m -2 d -1 for NH 3 -N, and -17.940 to 1.209 mg m -2 d -1 for NO 3 -N. To evaluate the relationship between the bacterial communities and environmental variables, CCA was conducted in three representative conditions: in the overlying water, in the sediment at a depth of 0-5 cm, and in the sediment at a depth of 5-15 cm. CCA results showed that environmental variables such as nutrient release fluxes (TN, NH 4 , NO 3 , TP, and PO 4 ) and water chemical parameters (pH, DO, COD, and temperature) were highly correlated with the bacterial communities. From the results of the nutrient release fluxes and the bacterial community, this study proposed the hypothesis for bacteria involved in the nutrient dynamics at the interface between water and sediment. In the sediment, sulfate-reducing bacteria (SRB) such as Desulfatibacillum, Desulfobacterium, Desulfomicrobium, and Desulfosalsimonas are expected to contribute to the decomposition of organic matter, and release of ammonia (NH 4 + ) and phosphate (PO 4 3- ). The PO 4 3- released into the water layer was observed by the positive fluxes of PO 4 3- . The NH 4 + released from the sediment was rapidly oxidized by the methane-oxidizing bacteria (MOB). This study observed in the water layer dominantly abundant MOB of Methylobacillus, Methylobacter, Methylocaldum, and Methylophilus. The nitrate (NO 3 - ) accumulation caused by the oxidation environment of the water layer

  6. Potential changes in bacterial metabolism associated with increased water temperature and nutrient inputs in tropical humic lagoons.

    PubMed

    Scofield, Vinicius; Jacques, Saulo M S; Guimarães, Jean R D; Farjalla, Vinicius F

    2015-01-01

    Temperature and nutrient concentrations regulate aquatic bacterial metabolism. However, few studies have focused on the effect of the interaction between these factors on bacterial processes, and none have been performed in tropical aquatic ecosystems. We analyzed the main and interactive effects of changes in water temperature and N and P concentrations on bacterioplankton production (BP), bacterioplankton respiration (BR) and bacterial growth efficiency (BGE) in tropical coastal lagoons. We used a factorial design with three levels of water temperature (25, 30, and 35°C) and four levels of N and/or P additions (Control, N, P, and NP additions) in five tropical humic lagoons. When data for all lagoons were pooled together, a weak interaction was observed between the increase in water temperature and the addition of nutrients. Water temperature alone had the greatest impact on bacterial metabolism by increasing BR, decreasing BP, and decreasing BGE. An increase of 1°C lead to an increase of ~4% in BR, a decrease of ~0.9% in BP, and a decrease of ~4% in BGE. When data were analyzed separately, lagoons responded differently to nutrient additions depending on Dissolved Organic Carbon (DOC) concentration. Lagoons with lowest DOC concentrations showed the strongest responses to nutrient additions: BP increased in response to N, P, and their interaction, BR increased in response to N and the interaction between N and P, and BGE was negatively affected, mainly by the interaction between N and P additions. Lagoons with the highest DOC concentrations showed almost no significant relationship with nutrient additions. Taken together, these results show that different environmental drivers impact bacterial processes at different scales. Changes of bacterial metabolism related to the increase of water temperature are consistent between lagoons, therefore their consequences can be predicted at a regional scale, while the effect of nutrient inputs is specific to different

  7. Potential changes in bacterial metabolism associated with increased water temperature and nutrient inputs in tropical humic lagoons

    PubMed Central

    Scofield, Vinicius; Jacques, Saulo M. S.; Guimarães, Jean R. D.; Farjalla, Vinicius F.

    2015-01-01

    Temperature and nutrient concentrations regulate aquatic bacterial metabolism. However, few studies have focused on the effect of the interaction between these factors on bacterial processes, and none have been performed in tropical aquatic ecosystems. We analyzed the main and interactive effects of changes in water temperature and N and P concentrations on bacterioplankton production (BP), bacterioplankton respiration (BR) and bacterial growth efficiency (BGE) in tropical coastal lagoons. We used a factorial design with three levels of water temperature (25, 30, and 35°C) and four levels of N and/or P additions (Control, N, P, and NP additions) in five tropical humic lagoons. When data for all lagoons were pooled together, a weak interaction was observed between the increase in water temperature and the addition of nutrients. Water temperature alone had the greatest impact on bacterial metabolism by increasing BR, decreasing BP, and decreasing BGE. An increase of 1°C lead to an increase of ~4% in BR, a decrease of ~0.9% in BP, and a decrease of ~4% in BGE. When data were analyzed separately, lagoons responded differently to nutrient additions depending on Dissolved Organic Carbon (DOC) concentration. Lagoons with lowest DOC concentrations showed the strongest responses to nutrient additions: BP increased in response to N, P, and their interaction, BR increased in response to N and the interaction between N and P, and BGE was negatively affected, mainly by the interaction between N and P additions. Lagoons with the highest DOC concentrations showed almost no significant relationship with nutrient additions. Taken together, these results show that different environmental drivers impact bacterial processes at different scales. Changes of bacterial metabolism related to the increase of water temperature are consistent between lagoons, therefore their consequences can be predicted at a regional scale, while the effect of nutrient inputs is specific to different

  8. Sunlight Exposure, Work Hours, Caffeine Consumption, and Sleep Duration in the Naval Environment.

    PubMed

    Shattuck, Nita L; Matsangas, Panagiotis

    2017-06-01

    Sailors in the U.S. Navy are habitual shiftworkers, often experiencing circadian misalignment due to their irregular work/rest schedules. This study assessed the effect of sunlight exposure, work hours, and caffeinated beverage consumption on the daily sleep duration of crewmembers of a U.S. Navy ship during a 2-wk underway period. Working in an artificially lit area with no access to sunlight during work hours, U.S. Navy crew members (N = 91) used daily logs to report their daily activity, caffeinated beverage consumption, and exposure to sunlight while off-duty; sleep was assessed by wrist-worn actigraphy. Hours of sunlight exposure, work duration, and the amount of coffee/tea/soft drinks were statistically significant predictors of sleep duration. On average, crewmembers who reported more than one half-hour of sunlight each day slept on average ∼40 min (10%) less than their peers working the same shifts who received less than one half-hour of sunlight (on average 6.05 ± 0.90 h vs. 6.71 ± 0.91 h, respectively). Exposure to sunlight, work hours, and consumption of caffeinated beverages are important factors when planning watchstanding schedules at sea. Even though further research is needed, our results suggest that even brief exposure to sunlight may contribute to circadian misalignment that negatively affects sleep in the operational environment. Educating crewmembers about sleep hygiene, especially the important roles played by sunlight and caffeine, could potentially improve the sleep and fatigue levels of this population of maritime shiftworkers.Shattuck NL, Matsangas P. Sunlight exposure, work hours, caffeine consumption, and sleep duration in the naval environment. Aerosp Med Hum Perform. 2017; 88(6):579-585.

  9. Hair cortisol and cortisone are decreased by natural sunlight.

    PubMed

    Wester, Vincent L; van der Wulp, Nils R P; Koper, Jan W; de Rijke, Yolanda B; van Rossum, Elisabeth F C

    2016-10-01

    Hair glucocorticoids (cortisol and cortisone) are increasingly used as measures of long-term integrated exposure to glucocorticoid hormones. Glucocorticoids gradually disappear from the hair shaft, which may result from exposure to ultraviolet (UV) radiation in natural sunlight. We aimed to study the influence of sun exposure on hair glucocorticoids. Scalp hair samples were obtained from nine volunteers (median age 33 [range 21-81], 7 females), and part of each hair sample was exposed to three experimental conditions: repeated exposure to natural sunlight for 40h (natural UV), exposure to a high amount of artificial UV radiation, and storage in the dark (control). Hair cortisol (HairF) and cortisone (HairE) were quantified by liquid chromatography-tandem mass spectrometry. When compared to control, HairF was decreased in 9 out of 9 hair samples after natural sunlight exposure (median decrease -3.1pg/mg or -54%, P<0.001) and artificial UV radiation (-4.7pg/mg or -75%, P=0.003). HairE decreased in 8 out of 9 samples, both after natural sunlight (-7.6pg/mg or -32%, P=0.012) and artificial UV (-10.7pg/mg or -52%, P=0.026). Exposure to natural sunlight decreases the glucocorticoid content of scalp hair, apparently through UV radiation, and is therefore an important confounder that should be considered in studies involving the measurement of hair glucocorticoids. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Application of the SPARROW model to assess surface-water nutrient conditions and sources in the United States Pacific Northwest

    USGS Publications Warehouse

    Wise, Daniel R.; Johnson, Henry M.

    2013-01-01

    The watershed model SPARROW (Spatially Referenced Regressions on Watershed attributes) was used to estimate mean annual surface-water nutrient conditions (total nitrogen and total phosphorus) and to identify important nutrient sources in catchments of the Pacific Northwest region of the United States for 2002. Model-estimated nutrient yields were generally higher in catchments on the wetter, western side of the Cascade Range than in catchments on the drier, eastern side. The largest source of locally generated total nitrogen stream load in most catchments was runoff from forestland, whereas the largest source of locally generated total phosphorus stream load in most catchments was either geologic material or livestock manure (primarily from grazing livestock). However, the highest total nitrogen and total phosphorus yields were predicted in the relatively small number of catchments where urban sources were the largest contributor to local stream load. Two examples are presented that show how SPARROW results can be applied to large rivers—the relative contribution of different nutrient sources to the total nitrogen load in the Willamette River and the total phosphorus load in the Snake River. The results from this study provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to researchers and water-quality managers performing local nutrient assessments.

  11. Identifying biotic integrity and water chemistry relations in nonwadeable rivers of Wisconsin: Toward the development of nutrient criteria

    USGS Publications Warehouse

    Weigel, B.M.; Robertson, Dale M.

    2007-01-01

    We sampled 41 sites on 34 nonwadeable rivers that represent the types of rivers in Wisconsin, and the kinds and intensities of nutrient and other anthropogenic stressors upon each river type. Sites covered much of United States Environmental Protection Agency national nutrient ecoregions VII-Mostly Glaciated Dairy Region, and VIII-Nutrient Poor, Largely Glaciated upper Midwest. Fish, macroinvertebrates, and three categories of environmental variables including nutrients, other water chemistry, and watershed features were collected using standard protocols. We summarized fish assemblages by index of biotic integrity (IBI) and its 10 component measures, and macroinvertebrates by 2 organic pollution tolerance and 12 proportional richness measures. All biotic and environmental variables represented a wide range of conditions, with biotic measures ranging from poor to excellent status, despite nutrient concentrations being consistently higher than reference concentrations reported for the regions. Regression tree analyses of nutrients on a suite of biotic measures identified breakpoints in total phosphorus (~0.06 mg/l) and total nitrogen (~0.64 mg/l) concentrations at which biotic assemblages were consistently impaired. Redundancy analyses (RDA) were used to identify the most important variables within each of the three environmental variable categories, which were then used to determine the relative influence of each variable category on the biota. Nutrient measures, suspended chlorophyll a, water clarity, and watershed land cover type (forest or row-crop agriculture) were the most important variables and they explained significant amounts of variation within the macroinvertebrate (R 2 = 60.6%) and fish (R 2 = 43.6%) assemblages. The environmental variables selected in the macroinvertebrate model were correlated to such an extent that partial RDA analyses could not attribute variation explained to individual environmental categories, assigning 89% of the explained

  12. Identifying biotic integrity and water chemistry relations in nonwadeable rivers of Wisconsin: toward the development of nutrient criteria.

    PubMed

    Weigel, Brian M; Robertson, Dale M

    2007-10-01

    We sampled 41 sites on 34 nonwadeable rivers that represent the types of rivers in Wisconsin, and the kinds and intensities of nutrient and other anthropogenic stressors upon each river type. Sites covered much of United States Environmental Protection Agency national nutrient ecoregions VII--Mostly Glaciated Dairy Region, and VIII--Nutrient Poor, Largely Glaciated upper Midwest. Fish, macroinvertebrates, and three categories of environmental variables including nutrients, other water chemistry, and watershed features were collected using standard protocols. We summarized fish assemblages by index of biotic integrity (IBI) and its 10 component measures, and macroinvertebrates by 2 organic pollution tolerance and 12 proportional richness measures. All biotic and environmental variables represented a wide range of conditions, with biotic measures ranging from poor to excellent status, despite nutrient concentrations being consistently higher than reference concentrations reported for the regions. Regression tree analyses of nutrients on a suite of biotic measures identified breakpoints in total phosphorus (approximately 0.06 mg/l) and total nitrogen (approximately 0.64 mg/l) concentrations at which biotic assemblages were consistently impaired. Redundancy analyses (RDA) were used to identify the most important variables within each of the three environmental variable categories, which were then used to determine the relative influence of each variable category on the biota. Nutrient measures, suspended chlorophyll a, water clarity, and watershed land cover type (forest or row-crop agriculture) were the most important variables and they explained significant amounts of variation within the macroinvertebrate (R(2) = 60.6%) and fish (R(2) = 43.6%) assemblages. The environmental variables selected in the macroinvertebrate model were correlated to such an extent that partial RDA analyses could not attribute variation explained to individual environmental categories

  13. Effects of salt pond restoration on benthic flux: Sediment as a source of nutrients to the water column

    USGS Publications Warehouse

    Topping, Brent R.; Kuwabara, James S.; Carter, James L.; Garrettt, Krista K.; Mruz, Eric; Piotter, Sarah; Takekawa, John Y.

    2016-01-01

    Understanding nutrient flux between the benthos and the overlying water (benthic flux) is critical to restoration of water quality and biological resources because it can represent a major source of nutrients to the water column. Extensive water management commenced in the San Francisco Bay, Beginning around 1850, San Francisco Bay wetlands were converted to salt ponds and mined extensively for more than a century. Long-term (decadal) salt pond restoration efforts began in 2003. A patented device for sampling porewater at varying depths, to calculate the gradient, was employed between 2010 and 2012. Within the former ponds, the benthic flux of soluble reactive phosphorus and that of dissolved ammonia were consistently positive (i.e., moving out of the sediment into the water column). The lack of measurable nitrate or nitrite concentration gradients across the sediment-water interface suggested negligible fluxes for dissolved nitrate and nitrite. The dominance of ammonia in the porewater indicated anoxic sediment conditions, even at only 1 cm depth, which is consistent with the observed, elevated sediment oxygen demand. Nearby openestuary sediments showed much lower benthic flux values for nutrients than the salt ponds under resortation. Allochthonous solute transport provides a nutrient advective flux for comparison to benthic flux. For ammonia, averaged for all sites and dates, benthic flux was about 80,000 kg/year, well above the advective flux range of −50 to 1500 kg/year, with much of the variability depending on the tidal cycle. By contrast, the average benthic flux of soluble reactive phosphorus was about 12,000 kg/year, of significant magnitude, but less than the advective flux range of 21,500 to 30,000 kg/year. These benthic flux estimates, based on solute diffusion across the sediment-water interface, reveal a significant nutrient source to the water column of the pond which stimulates algal blooms (often autotrophic). This benthic source may be

  14. Contributions to the Nutrient Toolbox: Identifying Drivers, Nutrient Sources, and Attribution of Exceedances

    EPA Science Inventory

    Nutrients are a leading cause of impairments in the United States, and as a result tools are needed to identify drivers of nutrients and response variables (such as chlorophyll a), nutrient sources, and identify causes of exceedances of water quality thresholds. This presentatio...

  15. Improving water management practices to reduce nutrient export from rice paddy fields.

    PubMed

    Zhang, Zhi-Jian; Yao, Ju-Xiang; Wang, Zhao-De; Xu, Xin; Lin, Xian-Yong; Czapar, George F; Zhang, Jian-Ying

    2011-01-01

    Nitrogen (N) and phosphorus (P) loss from rice paddy fields represents a significant threat to water quality in China. In this project, three irrigation-drainage regimes were compared, including one conventional irrigation-drainage regime, i.e. continuous submergence regime (CSR), and two improved regimes, i.e. the alternating submergence-nonsubmergence regime (ASNR) and the zero-drainage irrigation technology (ZDIT), to seek cost-effective practices for reducing nutrient loss. The data from these comparisons showed that, excluding the nutrient input from irrigation, the net exports of total N and total P via surface field drainage ranged from -3.93 to 2.39 kg ha and 0.17 to 0.95 g ha(-1) under the CSR operation, respectively, while N loss was -2.46 to -2.23 kg ha(-1) and P export was -0.65 to 0.31 kg ha(-1) under the improved regimes. The intensity of P export was positively correlated to the rate of P application. Reducing the draining frequency or postponing the draining operation would shift the ecological role of the paddy field from a nutrient export source to an interception sink when ASNR or the zero-drainage water management was used. In addition, since the rice yields are being guaranteed at no additional cost, the improved irrigation-drainage operations would have economic as well as environmental benefits.

  16. LINKING GREAT WATERSHEDS AND RIVERS TO FORECAST THE IMPACT OF NUTRIENTS ON LARGE RECEIVING WATERS

    EPA Science Inventory

    Assessment of our nation's waters, as per sections 305(b) and 303(d) of the Clean Water Act, indicates that approximately 40% are impacted by chemical and non-chemical stressors that impair designated beneficial uses and ecological habitat. Excess nutrients are often listed as a ...

  17. Conservation of soil, water and nutrients in surface runoff using riparian plant species.

    PubMed

    Srivastava, Prabodh; Singh, Shipra

    2012-01-01

    Three riparian plant species viz. Cynodon dactylon (L.) Pers., Saccharum bengalensis Retz. and Parthenium hysterophorus L. were selected from the riparian zone of Kali river at Aligarh to conduct the surface runoff experiment to compare their conservation efficiencies for soil, water and nutrients (phosphorus and nitrogen). Experimental plots were prepared on artificial slopes in botanical garden and on natural slopes on study site. Selected riparian plant species showed the range of conservation values for soil and water from 47.11 to 95.22% and 44.06 to 72.50%, respectively on artificial slope and from 44.53 to 95.33% and 48.36 to 73.15%, respectively on natural slope. Conservation values for phosphorus and nitrogen ranged from 40.83 to 88.89% and 59.78 to 82.22%, respectively on artificial slope and from 50.01 to 90.16% and 68.07 to 85.62%, respectively on natural slope. It was observed that Cynodon dactylon was the most efficient riparian species in conservation of soil, water and nutrients in surface runoff.

  18. Nutrient Fluxes From Profundal Sediment of Ultra-Oligotrophic Lake Tahoe, California/Nevada: Implications for Water Quality and Management in a Changing Climate

    NASA Astrophysics Data System (ADS)

    Beutel, Marc W.; Horne, Alexander J.

    2018-03-01

    A warming climate is expected to lead to stronger thermal stratification, less frequent deep mixing, and greater potential for bottom water anoxia in deep, temperate oligotrophic lakes. As a result, there is growing interest in understanding nutrient cycling at the profundal sediment-water interface of these rare ecosystems. This paper assessed nutrient content and nutrient flux rates from profundal sediment at Lake Tahoe, California/Nevada, USA. Sediment is a large reservoir of nutrients, with the upper 5 cm containing reduced nitrogen (˜6,300 metric tons) and redox-sensitive phosphorus (˜710 metric tons) equivalent to ˜15 times the annual external load. Experimental results indicate that if deep water in Lake Tahoe goes anoxic, profundal sediment will release appreciable amounts of phosphate (0.13-0.29 mg P/m2·d), ammonia (0.49 mg N/m2·d), and iron to overlaying water. Assuming a 10 year duration of bottom water anoxia followed by a deep-water mixing event, water column phosphate, and ammonia concentrations would increase by an estimated 1.6 µg P/L and 2.9 µg N/L, nearly doubling ambient concentrations. Based on historic nutrient enrichment assays this could lead to a ˜40% increase in algal growth. Iron release could have the dual effect of alleviating nitrate limitation on algal growth while promoting the formation of fine iron oxyhydroxide particles that degrade water clarity. If the depth and frequency of lake mixing decrease in the future as hydrodynamic models suggest, large-scale in-lake management strategies that impede internal nutrient loading in Lake Tahoe, such as bottom water oxygen addition or aluminum salt addition, may need to be considered.

  19. Diagnosing oceanic nutrient deficiency

    PubMed Central

    2016-01-01

    The supply of a range of nutrient elements to surface waters is an important driver of oceanic production and the subsequent linked cycling of the nutrients and carbon. Relative deficiencies of different nutrients with respect to biological requirements, within both surface and internal water masses, can be both a key indicator and driver of the potential for these nutrients to become limiting for the production of new organic material in the upper ocean. The availability of high-quality, full-depth and global-scale datasets on the concentrations of a wide range of both macro- and micro-nutrients produced through the international GEOTRACES programme provides the potential for estimation of multi-element deficiencies at unprecedented scales. Resultant coherent large-scale patterns in diagnosed deficiency can be linked to the interacting physical–chemical–biological processes which drive upper ocean nutrient biogeochemistry. Calculations of ranked deficiencies across multiple elements further highlight important remaining uncertainties in the stoichiometric plasticity of nutrient ratios within oceanic microbial systems and caveats with regards to linkages to upper ocean nutrient limitation. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035255

  20. Diagnosing oceanic nutrient deficiency

    NASA Astrophysics Data System (ADS)

    Moore, C. Mark

    2016-11-01

    The supply of a range of nutrient elements to surface waters is an important driver of oceanic production and the subsequent linked cycling of the nutrients and carbon. Relative deficiencies of different nutrients with respect to biological requirements, within both surface and internal water masses, can be both a key indicator and driver of the potential for these nutrients to become limiting for the production of new organic material in the upper ocean. The availability of high-quality, full-depth and global-scale datasets on the concentrations of a wide range of both macro- and micro-nutrients produced through the international GEOTRACES programme provides the potential for estimation of multi-element deficiencies at unprecedented scales. Resultant coherent large-scale patterns in diagnosed deficiency can be linked to the interacting physical-chemical-biological processes which drive upper ocean nutrient biogeochemistry. Calculations of ranked deficiencies across multiple elements further highlight important remaining uncertainties in the stoichiometric plasticity of nutrient ratios within oceanic microbial systems and caveats with regards to linkages to upper ocean nutrient limitation. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

  1. Digital data used to relate nutrient inputs to water quality in the Chesapeake Bay watershed, version 3.0

    USGS Publications Warehouse

    Brakebill, John W.; Preston, Stephen D.

    2004-01-01

    Chesapeake Bay restoration efforts are focused on improving water quality, living resources, and ecological habitats by 2010. One aspect of the water-quality restoration is the refinement of strategies designed to implement nutrient-reduction practices within the Bay watershed. These strategies are being refined and implemented by resource managers of the Chesapeake Bay Program (CBP), a partnership comprised of various Federal, State, and local agencies that includes jurisdictions within Delaware, Maryland, New York, Pennsylvania, Virginia, West Virginia, and the District of Columbia. The U.S. Geological Survey (USGS), an active member of the CBP, provides necessary water-quality information for these Chesapeake Bay nutrient-reduction strategy revisions and evaluations. The formulation and revision of effective nutrient-reduction strategies requires detailed scientific information and an analytical understanding of the sources, transport, and delivery of nutrients to the Chesapeake Bay. The USGS is supporting these strategies by providing scientific information to resource managers that can help them evaluate and understand these processes. One statistical model available to resource managers is a collection of SPAtially Referenced Regressions On Watershed (SPARROW) attributes, which uses a nonlinear regression approach to spatially relate nutrient sources and watershed characteristics to nutrient loads of streams throughout the Chesapeake Bay watershed. Developed by the USGS, information generated by SPARROW can help resource managers determine the geographical distribution and relative contribution of nutrient sources and the factors that affect their transport to the Bay. Nutrient source information representing the late 1990s time period was obtained from several agencies and used to create and compile digital spatial datasets of total nitrogen and total phosphorus contributions that served as input sources to the SPARROW models. These data represent

  2. Constructed wetlands may lower inorganic nutrient inputs but enhance DOC loadings into a drinking water reservoir in North Wales.

    PubMed

    Scholz, C; Jones, T G; West, M; Ehbair, A M S; Dunn, C; Freeman, C

    2016-09-01

    The objective of this study was to monitor a newly constructed wetland (CW) in north Wales, UK, to assess whether it contributes to an improvement in water quality (nutrient removal) of a nearby drinking water reservoir. Inflow and outflow of the Free Water Surface (FWS) CW were monitored on a weekly basis and over a period of 6 months. Physicochemical parameters including pH, conductivity and dissolved oxygen (DO) were measured, as well as nutrients and dissolved organic and inorganic carbon (DOC, DIC) concentration. The CW was seen to contribute to water quality improvement; results show that nutrient removal took place within weeks after construction. It was found that 72 % of initial nitrate (N03 (-)), 53 % of initial phosphate (PO4 (3-)) and 35 % of initial biological oxygen demand (BOD) were removed, calculated as a total over the whole sampling period. From our study, it can be concluded that while inorganic nutrients do decline in CWs, the DOC outputs increases. This may suggest that CWs represent a source for DOC. To assess the carbon in- and output a C budget was calculated.

  3. Impact of Seasonal Variability in Water, Plant and Soil Nutrient Dynamics in Agroecosystems

    NASA Astrophysics Data System (ADS)

    Pelak, N. F., III; Revelli, R.; Porporato, A. M.

    2017-12-01

    Agroecosystems cover a significant fraction of the Earth's surface, making their water and nutrient cycles a major component of global cycles across spatial and temporal scales. Most agroecosystems experience seasonality via variations in precipitation, temperature, and radiation, in addition to human activities which also occur seasonally, such as fertilization, irrigation, and harvesting. These seasonal drivers interact with the system in complex ways which are often poorly characterized. Crop models, which are widely used for research, decision support, and prediction of crop yields, are among the best tools available to analyze these systems. Though normally constructed as a set of dynamical equations forced by hydroclimatic variability, they are not often analyzed using dynamical systems theory and methods from stochastic ecohydrology. With the goal of developing this viewpoint and thus elucidating the roles of key feedbacks and forcings on system stability and on optimal fertilization and irrigation strategies, we develop a minimal dynamical system which contains the key components of a crop model, coupled to a carbon and nitrogen cycling model, driven by seasonal fluctuations in water and nutrient availability, temperature, and radiation. External drivers include seasonally varying climatic conditions and random rainfall forcing, irrigation and fertilization as well as harvesting. The model is used to analyze the magnitudes and interactions of the effects of seasonality on carbon and nutrient cycles, crop productivity, nutrient export of agroecosystems, and optimal management strategies with reference to productivity, sustainability and profitability. The impact of likely future climate scenarios on these systems is also discussed.

  4. Surface modifications of chalcopyrite CuInS2 thin films for photochatodes in photoelectrochemical water splitting under sunlight irradiation

    NASA Astrophysics Data System (ADS)

    Gunawan; Haris, A.; Widiyandari, H.; Septina, W.; Ikeda, S.

    2017-02-01

    Copper chalcopyrite semiconductors include a wide range of compounds that are of interest for photoelectrochemical water splitting which enables them to be used as photochatodes for H2 generation. Among them, CuInS2 is one of the most important materials due to its optimum band gap energy for sunlight absorption. In the present study, we investigated the application of CuInS2 fabricated by electrodeposition as photochatodes for water splitting. Thin film of CuInS2 chalcopyrite was formed on Mo-coated glass substrate by stacked electrodeposition of copper and indium followed by sulfurization under H2S flow. The films worked as a H2 liberation electrode under cathodic polarization from a solution containing Na2SO4 after loading Pt deposits on the film. Introduction of an n-type CdS layer by chemical bath deposition on the CuInS2 surface before the Pt loading resulted appreciable improvements of H2 liberation efficiency and a higher photocurrent onset potential. Moreover, the use of In2S3 layer as an alternative n-type layer to the CdS significantly improved the H2 liberation performance: the CuInS2 film modified with In2S3 and Pt deposits worked as an efficient photocathode for photoelectrochemical water splitting.

  5. Associations among cataract prevalence, sunlight hours, and altitude in the Himalayas.

    PubMed

    Brilliant, L B; Grasset, N C; Pokhrel, R P; Kolstad, A; Lepkowski, J M; Brilliant, G E; Hawks, W N; Pararajasegaram, R

    1983-08-01

    The relationship between cataract prevalence, altitude, and sunlight hours was investigated in a large national probability sample survey of 105 sites in the Himalayan kingdom of Nepal, December 1980 through April 1981. Cataract of senile or unknown etiology was diagnosed by ophthalmologists in 873 of 30,565 full-time life-long residents of survey sites. Simultaneously, the altitude of sites was measured using a standard mountain altimeter. Seasonally adjusted average daily duration of sunlight exposure for each site was calculated by a method which took into account latitude and obstructions along the skyline. Age- and sex-standardized cataract prevalence was 2.7 times higher in sites at an altitude of 185 meters or less than in sites over 1000 meters. Cataract prevalence was negatively correlated with altitude (r = -0.533, p less than 0.0001). However, a positive correlation between cataract prevalence and sunlight was observed (r = 0.563, p less than 0.0001). Sites with an average of 12 hours of sunlight exposure had 3.8 times as much cataract as sites with an average of only seven hours of exposure. Sunlight was blocked from reaching certain high altitude sites by tall neighboring mountains.

  6. Profiling contents of water-soluble metabolites and mineral nutrients to evaluate the effects of pesticides and organic and chemical fertilizers on tomato fruit quality.

    PubMed

    Watanabe, Masami; Ohta, Yuko; Licang, Sun; Motoyama, Naoki; Kikuchi, Jun

    2015-02-15

    In this study, the contents of water-soluble metabolites and mineral nutrients were measured in tomatoes cultured using organic and chemical fertilizers, with or without pesticides. Mineral nutrients and water-soluble metabolites were determined by inductively coupled plasma-atomic emission spectrometry and (1)H nuclear magnetic resonance spectrometry, respectively, and results were analysed by principal components analysis (PCA). The mineral nutrient and water-soluble metabolite profiles differed between organic and chemical fertilizer applications, which accounted for 88.0% and 55.4%, respectively, of the variation. (1)H-(13)C-hetero-nuclear single quantum coherence experiments identified aliphatic protons that contributed to the discrimination of PCA. Pesticide application had little effect on mineral nutrient content (except Fe and P), but affected the correlation between mineral nutrients and metabolites. Differences in the content of mineral nutrients and water-soluble metabolites resulting from different fertilizer and pesticide applications probably affect tomato quality. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Sunlight + Water = Tomorrow's Energy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jones, Anne Katherine

    Representing the Center for Bio-Inspired Solar Fuel Production (BISfuel), this document is one of the entries in the Ten Hundred and One Word Challenge. As part of the challenge, the 46 Energy Frontier Research Centers were invited to represent their science in images, cartoons, photos, words and original paintings, but any descriptions or words could only use the 1000 most commonly used words in the English language, with the addition of one word important to each of the EFRCs and the mission of DOE: energy. The mission of BISfuel is to construct a complete system for solar-powered production of hydrogenmore » fuel via water splitting; design principles are drawn from the fundamental concepts that underlie photosynthetic energy conversion.« less

  8. Investigation of sunlight-induced deterioration of aroma of pummelo (Citrus maxima) essential oil.

    PubMed

    Sun, Hao; Ni, Hui; Yang, Yuanfan; Wu, Ling; Cai, Hui-nong; Xiao, An-feng; Chen, Feng

    2014-12-10

    Deterioration of aromas of pummelo essential oil (EO) induced by sunlight was compared to those induced by heat and oxygen exposure using the techniques of sensory evaluation and GC-MS analysis. The sunlight-exposed EO was found to possess an oily off-flavor odor, which was significantly different from its counterparts induced by oxygen and heat. The strong oily note of the sunlight-exposed EO was attributed to the existence of linalool oxides and limonene oxides, as well as the lack of neral and geranial, for which UV sunlight was revealed to be the critical contributor causing the chemical reactions for the aroma changes. The results demonstrated that UV sunlight could significantly affect the aroma of the pummelo EO, providing valuable information that will benefit the production and storage of EO-based aromatic products.

  9. Surface-Water Quality and Nutrient Loads in the Nepaug Reservoir Watershed, Northwestern Connecticut, 1999-2001

    USGS Publications Warehouse

    Morrison, Jonathan; Colombo, Michael J.

    2006-01-01

    Water quality was characterized at three tributary watersheds to the Nepaug Reservoir-Nepaug River, Phelps Brook, and Clear Brook-from October 1998 through September 2001 to document existing water-quality conditions and evaluate potential future effects of the removal of sand and gravel from areas of the watershed. Some removal operations may include removal of vegetation and top soil and steepening of slopes. Routine water samples collected monthly in all three watersheds were analyzed for nutrients, organic carbon, major ions, and fecal indicator bacteria. Results of the analyses indicate that, in general, the water quality in all three tributary watersheds is good and meets standards established for drinking-water supplies for nitrate, but does not always meet contact-recreation standards for bacteria. Median concentrations of total nitrogen, total phosphorus, and total organic carbon were highest in the routine monthly samples from Phelps Brook and lowest from Clear Brook. Samples also were collected during selected storms to examine changes in concentrations of nutrients during periods of high streamflow. The maximum values measured for total nitrogen, total phosphorus, and total organic carbon were in storm samples from Clear Brook. The Nepaug River watershed delivered the largest loads of total nitrogen, total phosphorus, and total organic carbon to the reservoir. Yields of nutrients and organic carbon differed significantly from year to year and among the three watersheds. Yields of total nitrogen and total organic carbon were largest from Phelps Brook and smallest from Clear Brook. The yields of total phosphorus were largest from Nepaug River and smallest from Phelps Brook. In comparison to other watersheds in Connecticut, annual loads and yields from the three streams were lower than those of developed urban areas and comparable to those of other rural and forested basins. Delivery of nutrients and organic carbon to the reservoir took place mostly during

  10. Stream restoration and sewers impact sources and fluxes of water,carbon, and nutrients in urban watersheds

    EPA Science Inventory

    An improved understanding of sources and timing of water and nutrient fluxes associated with urban stream restoration is critical for guiding effective watershed management. We investigated how sources, fluxes, and flowpaths of water, carbon (C), nitrogen (N), and phosphorus (P)...

  11. Tree planting in Haiti: How to plant and care for your nursery grown seedlings

    Treesearch

    Kyrstan Hubbel; Yvonne Barkley; Jeremiah R. Pinto; R. Kasten Dumroese; Sabine Deristin; Raymond Joseph; Randy Brooks; Anthony S. Davis

    2016-01-01

    Seedlings need the right amounts of sunlight, water and nutrients to live and grow into healthy trees. Different types of trees have different requirements, so seedlings will need planting sites that meet all of their requirements. For example, pine trees need full sun, a moderate amount of water and a certain combination of nutrients to grow into healthy trees. If you...

  12. Particle water and pH in the eastern Mediterranean: source variability and implications for nutrient availability

    NASA Astrophysics Data System (ADS)

    Bougiatioti, Aikaterini; Nikolaou, Panayiota; Stavroulas, Iasonas; Kouvarakis, Giorgos; Weber, Rodney; Nenes, Athanasios; Kanakidou, Maria; Mihalopoulos, Nikolaos

    2016-04-01

    Particle water (liquid water content, LWC) and aerosol pH are important parameters of the aerosol phase, affecting heterogeneous chemistry and bioavailability of nutrients that profoundly impact cloud formation, atmospheric composition, and atmospheric fluxes of nutrients to ecosystems. Few measurements of in situ LWC and pH, however, exist in the published literature. Using concurrent measurements of aerosol chemical composition, cloud condensation nuclei activity, and tandem light scattering coefficients, the particle water mass concentrations associated with the aerosol inorganic (Winorg) and organic (Worg) components are determined for measurements conducted at the Finokalia atmospheric observation station in the eastern Mediterranean between June and November 2012. These data are interpreted using the ISORROPIA-II thermodynamic model to predict the pH of aerosols originating from the various sources that influence air quality in the region. On average, closure between predicted aerosol water and that determined by comparison of ambient with dry light scattering coefficients was achieved to within 8 % (slope = 0.92, R2 = 0.8, n = 5201 points). Based on the scattering measurements, a parameterization is also derived, capable of reproducing the hygroscopic growth factor (f(RH)) within 15 % of the measured values. The highest aerosol water concentrations are observed during nighttime, when relative humidity is highest and the collapse of the boundary layer increases the aerosol concentration. A significant diurnal variability is found for Worg with morning and afternoon average mass concentrations being 10-15 times lower than nighttime concentrations, thus rendering Winorg the main form of particle water during daytime. The average value of total aerosol water was 2.19 ± 1.75 µg m-3, contributing on average up to 33 % of the total submicron mass concentration. Average aerosol water associated with organics, Worg, was equal to 0.56 ± 0.37 µg m-3; thus, organics

  13. Water quality and nutrient loading in the Klamath River between Keno, Oregon and Seiad Valley, CA from 1996-1998

    USGS Publications Warehouse

    Campbell, Sharon G.

    2001-01-01

    Implementing management strategies for reservoir operations to improve water quality and reduce nutrient concentration or loading in the Klamath River study area to benefit anadromous fisheries may be difficult and expensive. However, improving the thermal regime in spring to benefit YOY salmonids may be possible as is short-term relief in late summer for oversummering species. Decreases in nutrient concentration or loading accomplished through best management practices in the water shed may allow general protection of water resources in the Klamath Basin for future needs.

  14. Sunlight and health: attitudes of older people living in intermediate care facilities in southern Australia.

    PubMed

    Durvasula, Seeta; Kok, Cindy; Sambrook, Philip N; Cumming, Robert G; Lord, Stephen R; March, Lynette M; Mason, Rebecca S; Seibel, Markus J; Simpson, Judy M; Cameron, Ian D

    2010-01-01

    Older people have a high prevalence of falls and fractures, partly due to vitamin D deficiency. Sunlight is a major source of vitamin D, but many older people living in intermediate care facilities have inadequate sunlight exposure. The aim of this study was to determine the sun exposure practices and attitudes to sunlight in this population. Fifty-seven older residents of intermediate care facilities in Sydney, Australia were interviewed to determine their sun exposure practices, their views on sunlight and health and whether these have changed over their lives, factors affecting sunlight exposure and their knowledge of vitamin D. Sixty percent of the participants preferred to be outdoors, despite more than 92% believing that sunlight was healthy. In their youth however, almost 90% had preferred to be outdoors. Poor health, physical constraints and a sense of lack of ownership of outdoor spaces were barriers to sunlight exposure. Improved physical access, more outdoor leisure activities and promotion of greater autonomy may improve safe and appropriate sunlight exposure in this population. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.

  15. Pore Water Pumping by Upside-Down Jellyfish

    NASA Astrophysics Data System (ADS)

    Gaddam, Manikantam; Santhanakrishnan, Arvind

    2016-11-01

    Patchy aggregations of Cassiopea medusae, commonly called upside-down jellyfish, are found in sheltered marine environments with low-speed ambient flows. These medusae exhibit a sessile, non-swimming lifestyle, and are oriented such that their bells are attached to the substrate and oral arms point towards sunlight. Pulsations of their bells are used to generate currents for suspension feeding. Their pulsations have also been proposed to generate forces that can release sediment locked nutrients into the surrounding water. The goal of this study is to examine pore water pumping by Cassiopea individuals in laboratory aquaria, as a model for understanding pore water pumping in unsteady flows. Planar laser-induced fluorescence (PLIF) measurements were conducted to visualize the release of pore water via bell motion, using fluorescent dye introduced underneath the substrate. 2D particle image velocimetry (PIV) measurements were conducted on the same individuals to correlate PLIF-based concentration profiles with the jets generated by pulsing of medusae. The effects of varying bell diameter on pore water release and pumping currents will be discussed.

  16. Interacting effects of sunlight, agriculturally derived dissolved organic matter and reactive oxygen species on fecal indicator bacteria growth dynamics

    EPA Science Inventory

    Bacterial survival in agriculturally impacted surface waters is dependent on resource availability and also on potential resource transformations, mediated by biotic and abiotic processes. In this study, we focused on the effect of sunlight irradiated cattle fecal extract (CFE) a...

  17. Interactions between soil texture, water, and nutrients control patterns of biocrusts abundance and structure

    NASA Astrophysics Data System (ADS)

    Young, Kristina; Bowker, Matthew; Reed, Sasha; Howell, Armin

    2017-04-01

    Heterogeneity in the abiotic environment structures biotic communities by controlling niche space and parameters. This has been widely observed and demonstrated in vascular plant and other aboveground communities. While soil organisms are presumably also strongly influenced by the physical and chemical dimensions of the edaphic environment, there are fewer studies linking the development, structure, productivity or function of surface soil communities to specific edaphic gradients. Here, we use biological soil crusts (biocrusts) as a model system to determine mechanisms regulating community structure of soil organisms. We chose soil texture to serve as an edaphic gradient because of soil texture's influence over biocrust distribution on a landscape level. We experimentally manipulated texture in constructed soil, and simultaneously manipulated two main outcomes of texture, water and nutrient availability, to determine the mechanism underlying texture's influence on biocrust abundance and structure. We grew biocrust communities from a field-sourced inoculum on four different soil textures, sieved from the same parent soil material, manipulating watering levels and nutrient additions across soil textures in a full-factorial design over a 5-month period of time. We measured abundance and structure of biocrusts over time, and measured two metrics of function, N2 fixation rates and soil stabilization, at the conclusion of the experiment. Our results showed finer soil textures resulted in faster biocrust community development and dominance by mosses, whereas coarser textures grew more slowly and had biocrust communities dominated by cyanobacteria and lichen. Additionally, coarser textured soils contained cyanobacterial filaments significantly deeper into the soil profile than fine textured soils. N2-fixation values increased with increasing moss cover and decreased with increasing cyanobacterial cover, however, the rate of change depended on soil texture and water amount

  18. Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania; effects of nutrient management on water quality in the Little Conestoga Creek headwaters, 1983-89

    USGS Publications Warehouse

    Koerkle, E.H.; Fishel, D.K.; Brown, M.J.; Kostelnik, K.M.

    1996-01-01

    Water quality in the headwaters of the Little Conestoga Creek, Lancaster County, Pa., was investigated from April 1986 through September 1989 to determine possible effects of agricultural nutrient management on water quality. Nutrient management, an agricultural Best-Management Practice, was promoted in the 5.8-square-mile watershed by the U.S. Department of Agriculture Rural Clean Water Program. Nonpoint-source- agricultural contamination was evident in surface water and ground water in the watershed; the greatest contamination was in areas underlain by carbonate rock and with intensive row-crop and animal production. Initial implementation of nutrient management covered about 30 percent of applicable land and was concentrated in the Nutrient-Management Subbasin. By 1989, nutrient management covered about 45 percent of the entire Small Watershed, about 85 percent of the Nutrient- Management Subbasin, and less than 10 percent of the Nonnutrient-Management Subbasin. The number of farms implementing nutrient management increased from 14 in 1986 to 25 by 1989. Nutrient applications to cropland in the Nutrient- Management Subbasin decreased by an average of 35 percent after implementation. Comparison of base- flow surface-water quality from before and after implementation suggests that nutrient management was effective in slowing or reversing increases in concentrations of dissolved nitrate plus nitrite in the Nutrient-Management Subbasin. Although not statistically significant, the Mann-Whitney step-trend coefficient for the Nutrient-Management Subbasin was 0.8 milligram per liter, whereas trend coefficients for the Nonnutrient-Management Subbasin and the Small Watershed were 0.4 and 1.4 milligrams per liter, respectively, for the period of study. Analysis of covariance comparison of concurrent concentrations from the two sub- basins showed a significant decrease in concen- trations from the Nutrient-Management Subbasin compared to the Nonnutrient-Management Subbasin

  19. Nutrient availability constrains the hydraulic architecture and water relations of savannah trees.

    Treesearch

    S.J. Bucci; F.G. Scholz; G. Goldstein; F.C. Meinzer; A.C. Franco; P.I. Campanello; R. Villalobos-Vega; M. Bustamante; F. Miralles-Wilhelm

    2006-01-01

    Several plant functional traits were studied in five dominant woody savanna species in a Brazilian savanna to determine whether removal of nutrient limitations has an effect on carbon allocation, water relations, and hydraulic architecture. Four treatments consisting of a control, and nitrogen (N), phosphorus (P), and N plus P additions were maintained for 5 years....

  20. Sunlight-induced changes in chromophores and fluorophores of wastewater-derived organic matter in receiving waters--the role of salinity.

    PubMed

    Yang, Xiaofang; Meng, Fangang; Huang, Guocheng; Sun, Li; Lin, Zheng

    2014-10-01

    Wastewater-derived organic matter (WOM) is an important constituent of discharge to urban rivers and is suspected of altering the naturally occurring dissolved organic matter (DOM) in water systems. This study investigated sunlight-induced changes in chromophores and fluorophores of WOM with different salinities (S = 0, 10, 20 and 30) that were collected from two wastewater treatment plants (WWTP-A and WWTP-B). The results showed that exposure to sunlight for 5.3 × 10(5) J/m(2) caused significant decreases in UV254-absorbing WOM (45-59% loss) compared to gross dissolved organic carbon (<15% loss). An increase in salinity accelerated the overall photo-degradation rates of the UV254-absorbing chromophores from both WOM and natural DOM. In addition, irradiated WOM at a higher salinity had a larger molecular size than that at a lower salinity. However, natural DOM did not display such behavior. Parallel factor analysis of the excitation-emission matrix determined the presence of two humic-like components (C1 and C2) and two protein-like components (C3 and C4). All the components in WOM followed second-order kinetics, except for the C4 component in WWTP-A, which fit zero-order photoreaction kinetics. The photo-degradation of the C1 component in both WWTPs appeared to be independent of salinity; however, the photo-degradation rates of the C2 and C3 components in both WWTPs and C4 in WWTP-B increased significantly with increasing salinity. In comparison, the photo-degradation of the C1 component was significantly facilitated by increased salinity in natural DOM, fitting first-order photoreaction kinetics. As such, the current knowledge concerning the photo-degradation of naturally occurring DOM cannot be extrapolated for the understanding of WOM photo-degradation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Energy-neutral sustainable nutrient recovery incorporated with the wastewater purification process in an enlarged microbial nutrient recovery cell

    NASA Astrophysics Data System (ADS)

    Sun, Dongya; Gao, Yifan; Hou, Dianxun; Zuo, Kuichang; Chen, Xi; Liang, Peng; Zhang, Xiaoyuan; Ren, Zhiyong Jason; Huang, Xia

    2018-04-01

    Recovery of nutrient resources from the wastewater is now an inevitable strategy to maintain the supply of both nutrient and water for our huge population. While the intensive energy consumption in conventional nutrient recovery technologies still remained as the bottleneck towards the sustainable nutrient recycle. This study proposed an enlarged microbial nutrient recovery cell (EMNRC) which was powered by the energy contained in wastewater and achieved multi-cycle nutrient recovery incorporated with in situ wastewater treatment. With the optimal recovery solution of 3 g/L NaCl and the optimal volume ratio of wastewater to recovery solution of 10:1, >89% of phosphorus and >62% of ammonium nitrogen were recovered into struvite. An extremely low water input ratio of <1% was required to obtain the recovered fertilizer and the purified water. It was proved the EMNRC system was a promising technology which could utilize the chemical energy contained in wastewater itself and energy-neutrally recover nutrient during the continuous wastewater purification process.

  2. Eutrophication and macroalgal blooms in temperate and tropical coastal waters: nutrient enrichment experiments with Ulva spp.

    PubMed Central

    Teichberg, Mirta; Fox, Sophia E; Olsen, Ylva S; Valiela, Ivan; Martinetto, Paulina; Iribarne, Oscar; Muto, Elizabeti Yuriko; Petti, Monica A V; Corbisier, Thaïs N; Soto-Jiménez, Martín; Páez-Osuna, Federico; Castro, Paula; Freitas, Helena; Zitelli, Andreina; Cardinaletti, Massimo; Tagliapietra, Davide

    2010-01-01

    Receiving coastal waters and estuaries are among the most nutrient-enriched environments on earth, and one of the symptoms of the resulting eutrophication is the proliferation of opportunistic, fast-growing marine seaweeds. Here, we used a widespread macroalga often involved in blooms, Ulva spp., to investigate how supply of nitrogen (N) and phosphorus (P), the two main potential growth-limiting nutrients, influence macroalgal growth in temperate and tropical coastal waters ranging from low- to high-nutrient supplies. We carried out N and P enrichment field experiments on Ulva spp. in seven coastal systems, with one of these systems represented by three different subestuaries, for a total of nine sites. We showed that rate of growth of Ulva spp. was directly correlated to annual dissolved inorganic nitrogen (DIN) concentrations, where growth increased with increasing DIN concentration. Internal N pools of macroalgal fronds were also linked to increased DIN supply, and algal growth rates were tightly coupled to these internal N pools. The increases in DIN appeared to be related to greater inputs of wastewater to these coastal waters as indicated by high δ15N signatures of the algae as DIN increased. N and P enrichment experiments showed that rate of macroalgal growth was controlled by supply of DIN where ambient DIN concentrations were low, and by P where DIN concentrations were higher, regardless of latitude or geographic setting. These results suggest that understanding the basis for macroalgal blooms, and management of these harmful phenomena, will require information as to nutrient sources, and actions to reduce supply of N and P in coastal waters concerned.

  3. Contribution of UVB radiation to bacterial inactivation by natural sunlight.

    PubMed

    Oppezzo, Oscar J

    2012-10-03

    The contribution of different components of sunlight to the lethal action exerted by this radiation on bacteria was studied using Pseudomonas aeruginosa ATCC27853 as a model organism. When solar UVB was excluded from the incident radiation by filtering it through a naphthalene solution (cut off 327 nm), significant modifications were observed in the cell-death kinetics. These modifications were comparable to those expected for a reduction of 27-32% in the dose rate, according to the model used in the analysis of the survival curves, and were also observed when the effects of sunlight filtered through polyethylene terephthalate (cut off 331 nm) or polystyrene (cut off 298 nm) were compared. Viability of P. aeruginosa remained almost unchanged when the incident radiation was filtered through a sodium nitrite solution (cut off 406 nm) in order to exclude the UVA and UVB components of sunlight. Nevertheless, a delay in colony formation was detected in bacteria treated in this way, suggesting that a non-lethal effect was exerted by visible light. The results are not consistent with a generally accepted notion which attributes the lethal action of sunlight to the radiation with wavelengths above 320 nm. The characterization of UVB contribution to the lethal effect of sunlight on bacteria is relevant for understanding of the mechanism of cell death, and for improvement of dosimetry techniques and irradiation procedures. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. Utilization of the water soluable fraction of wheat straw as a plant nutrient source

    NASA Technical Reports Server (NTRS)

    Mackowiak, C. L.; Garland, J. L.

    1990-01-01

    Recovery of water soluble, inorganic nutrients from the inedible portion of wheat was found to be an effective means of recycling nutrients within hydroponic systems. Through aqueous extraction (leaching), 60 percent of the total inorganic nutrient weight was removed from wheat straw and roots, although the recovery of individual nutrients varied. Leaching also removed about 20 percent of the total organic carbon from the biomass. In terms of dry weight, the leachate was comprised of approximately 60 percent organic and 40 percent inorganic compounds. Direct use of wheat straw leachate in static hydroponic systems had an inhibitory effect on wheat growth, both in the presence and absence of microorganisms. Biological treatment of leachate either with a mixed microbial community or the oyster mushroom Pleurotus ostreatus L., prior to use in hydroponic solutions, significantly reduced both the organic content and the inhibitory effects of the leachate. The inhibitory effects of unprocessed leachate appear to be a result of rapidly acting phytotoxic compounds that are detoxified by microbial activity. Leaching holds considerable promise as a method for nutrient recycling in a Controlled Ecological Life Support System (CELSS).

  5. EFFECTS OF SUNLIGHT ON CARBOXYL CONTENT OF DISSOLVED ORGANIC MATTER IN THE SATILLA RIVER OF GEORGIA, UNITED STATES

    EPA Science Inventory

    A study examined the effect of sunlight-initiated photo-degradation of dissolved organic matter (DOM) on its carboxyl content, and the role of oxygen and iron in this process. Solar-simulated irradiations were performed on 0.2-mm filtered water samples collected from the highly c...

  6. Particle water and pH in the Eastern Mediterranean: sources variability and implications for nutrients availability

    NASA Astrophysics Data System (ADS)

    Nikolaou, P.; Bougiatioti, A.; Stavroulas, I.; Kouvarakis, G.; Nenes, A.; Weber, R.; Kanakidou, M.; Mihalopoulos, N.

    2015-10-01

    Particle water (LWC) and aerosol pH drive the aerosol phase, heterogeneous chemistry and bioavailability of nutrients that profoundly impact cloud formation, atmospheric composition and atmospheric fluxes of nutrients to ecosystems. Few measurements of in-situ LWC and pH however exist in the published literature. Using concurrent measurements of aerosol chemical composition, cloud condensation nuclei activity and tandem light scattering coefficients, the particle water mass concentrations associated with the aerosol inorganic (Winorg) and organic (Worg) components are determined for measurements conducted at the Finokalia atmospheric observation station in the eastern Mediterranean between August and November 2012. These data are interpreted using the ISORROPIA-II thermodynamic model to predict pH of aerosols originating from the various sources that influence air quality in the region. On average, closure between predicted aerosol water and that determined by comparison of ambient with dry light scattering coefficients was achieved to within 8 % (slope = 0.92, R2 = 0.8, n = 5201 points). Based on the scattering measurements a parameterization is also derived, capable of reproducing the hygroscopic growth factor (f(RH)) within 15 % of the measured values. The highest aerosol water concentrations are observed during nighttime, when relative humidity is highest and the collapse of the boundary layer increases the aerosol concentration. A significant diurnal variability is found for Worg with morning and afternoon average mass concentrations being 10-15 times lower than nighttime concentrations, thus rendering Winorg the main form of particle water during daytime. The average value of total aerosol water was 2.19 ± 1.75 μg m-3, contributing on average up to 33 % of the total submicron mass concentration. Average aerosol water associated with organics, Worg, was equal to 0.56 ± 0.37 μg m-3, thus organics contributed about 27.5 % to the total aerosol water, mostly

  7. Growth and nutrient status of black spruce seedlings as affected by water table depth

    Treesearch

    Miroslaw M. Czapowskyj; Robert V. Rourke; Walter J. Grant; Walter J. Grant

    1986-01-01

    The objective of this study was to determine the effect of different soil water table levels on growth, biomass production, and nutrient accumulation in black spruce seedlings growing under greenhouse conditions over three growing seasons after transplanting.

  8. A mathematical model of water and nutrient transport in xylem vessels of a wheat plant.

    PubMed

    Payvandi, S; Daly, K R; Jones, D L; Talboys, P; Zygalakis, K C; Roose, T

    2014-03-01

    At a time of increasing global demand for food, dwindling land and resources, and escalating pressures from climate change, the farming industry is undergoing financial strain, with a need to improve efficiency and crop yields. In order to improve efficiencies in farming, and in fertiliser usage in particular, understanding must be gained of the fertiliser-to-crop-yield pathway. We model one aspect of this pathway; the transport of nutrients within the vascular tissues of a crop plant from roots to leaves. We present a mathematical model of the transport of nutrients within the xylem vessels in response to the evapotranspiration of water. We determine seven different classes of flow, including positive unidirectional flow, which is optimal for nutrient transport from the roots to the leaves; and root multidirectional flow, which is similar to the hydraulic lift process observed in plants. We also investigate the effect of diffusion on nutrient transport and find that diffusion can be significant at the vessel termini especially if there is an axial efflux of nutrient, and at night when transpiration is minimal. Models such as these can then be coupled to whole-plant models to be used for optimisation of nutrient delivery scenarios.

  9. Optimal Management of Water, Nutrient and Carbon Cycles of Green Urban Spaces

    NASA Astrophysics Data System (ADS)

    Revelli, R.; Pelak, N. F., III; Porporato, A. M.

    2016-12-01

    The urban ecosystem is a complex, metastable system with highly coupled flows of mass, energy, people and capital. Their sustainability is in part linked to the existence of green spaces which provide important ecosystem services, whose sustainable management requires quantification of their benefits in terms of impacts on water, carbon and energy fluxes. An exploration of problems of optimal management of such green urban spaces and the related biogeochemical fluxes is presented, extending probabilistic ecohydrological models of the soil-plant system to the urban context, where biophysical and ecological conditions tend to be radically different from the surrounding rural and natural environment (e.g. heat islands, air and water pollution, low quality soils, etc…). The coupled soil moisture, nutrient and plant dynamics are modeled to compute water requirements, carbon footprint, nutrient demand and losses, and related fluxes under different design, management and climate scenarios. The goal is to provide operative rules for a sustainable water use through focused irrigation and fertilization strategies, optimal choice of plants, soil and cultivation conditions, accounting for the typical hydroclimatic variability that occur in the urban environment. This work is part of a project that has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 701914. The work is also cofounded by USDA Agricultural Research Service cooperative agreement 58-6408-3-027; National Science Foundation (NSF) grants: EAR-1331846, EAR-1316258, and the DGE-1068871 and FESD EAR-1338694.

  10. Removing Constraints on the Biomass Production of Freshwater Macroalgae by Manipulating Water Exchange to Manage Nutrient Flux

    PubMed Central

    Cole, Andrew J.; de Nys, Rocky; Paul, Nicholas A.

    2014-01-01

    Freshwater macroalgae represent a largely overlooked group of phototrophic organisms that could play an important role within an industrial ecology context in both utilising waste nutrients and water and supplying biomass for animal feeds and renewable chemicals and fuels. This study used water from the intensive aquaculture of freshwater fish (Barramundi) to examine how the biomass production rate and protein content of the freshwater macroalga Oedogonium responds to increasing the flux of nutrients and carbon, by either increasing water exchange rates or through the addition of supplementary nitrogen and CO2. Biomass production rates were highest at low flow rates (0.1–1 vol.day−1) using raw pond water. The addition of CO2 to cultures increased biomass production rates by between 2 and 25% with this effect strongest at low water exchange rates. Paradoxically, the addition of nitrogen to cultures decreased productivity, especially at low water exchange rates. The optimal culture of Oedogonium occurred at flow rates of between 0.5–1 vol.day−1, where uptake rates peaked at 1.09 g.m−2.day−1 for nitrogen and 0.13 g.m−2.day−1 for phosphorous. At these flow rates Oedogonium biomass had uptake efficiencies of 75.2% for nitrogen and 22.1% for phosphorous. In this study a nitrogen flux of 1.45 g.m−2.day−1 and a phosphorous flux of 0.6 g.m−2.day−1 was the minimum required to maintain the growth of Oedogonium at 16–17 g DW.m−2.day−1 and a crude protein content of 25%. A simple model of minimum inputs shows that for every gram of dry weight biomass production (g DW.m−2.day−1), Oedogonium requires 0.09 g.m−2.day−1 of nitrogen and 0.04 g.m−2.day−1 of phosphorous to maintain growth without nutrient limitation whilst simultaneously maintaining a high-nutrient uptake rate and efficiency. As such the integrated culture of freshwater macroalgae with aquaculture for the purposes of nutrient recovery is a feasible solution for the

  11. Removing constraints on the biomass production of freshwater macroalgae by manipulating water exchange to manage nutrient flux.

    PubMed

    Cole, Andrew J; de Nys, Rocky; Paul, Nicholas A

    2014-01-01

    Freshwater macroalgae represent a largely overlooked group of phototrophic organisms that could play an important role within an industrial ecology context in both utilising waste nutrients and water and supplying biomass for animal feeds and renewable chemicals and fuels. This study used water from the intensive aquaculture of freshwater fish (Barramundi) to examine how the biomass production rate and protein content of the freshwater macroalga Oedogonium responds to increasing the flux of nutrients and carbon, by either increasing water exchange rates or through the addition of supplementary nitrogen and CO2. Biomass production rates were highest at low flow rates (0.1-1 vol.day-1) using raw pond water. The addition of CO2 to cultures increased biomass production rates by between 2 and 25% with this effect strongest at low water exchange rates. Paradoxically, the addition of nitrogen to cultures decreased productivity, especially at low water exchange rates. The optimal culture of Oedogonium occurred at flow rates of between 0.5-1 vol.day-1, where uptake rates peaked at 1.09 g.m-2.day-1 for nitrogen and 0.13 g.m-2.day-1 for phosphorous. At these flow rates Oedogonium biomass had uptake efficiencies of 75.2% for nitrogen and 22.1% for phosphorous. In this study a nitrogen flux of 1.45 g.m-2.day-1 and a phosphorous flux of 0.6 g.m-2.day-1 was the minimum required to maintain the growth of Oedogonium at 16-17 g DW.m-2.day-1 and a crude protein content of 25%. A simple model of minimum inputs shows that for every gram of dry weight biomass production (g DW.m-2.day-1), Oedogonium requires 0.09 g.m-2.day-1 of nitrogen and 0.04 g.m-2.day-1 of phosphorous to maintain growth without nutrient limitation whilst simultaneously maintaining a high-nutrient uptake rate and efficiency. As such the integrated culture of freshwater macroalgae with aquaculture for the purposes of nutrient recovery is a feasible solution for the bioremediation of wastewater and the supply of a

  12. Representation of deforestation impacts on climate, water, and nutrient cycles in the ACME earth system model

    NASA Astrophysics Data System (ADS)

    Cai, X.; Riley, W. J.; Zhu, Q.

    2017-12-01

    Deforestation causes a series of changes to the climate, water, and nutrient cycles. Employing a state-of-the-art earth system model—ACME (Accelerated Climate Modeling for Energy), we comprehensively investigate the impacts of deforestation on these processes. We first assess the performance of the ACME Land Model (ALM) in simulating runoff, evapotranspiration, albedo, and plant productivity at 42 FLUXNET sites. The single column mode of ACME is then used to examine climate effects (temperature cooling/warming) and responses of runoff, evapotranspiration, and nutrient fluxes to deforestation. This approach separates local effects of deforestation from global circulation effects. To better understand the deforestation effects in a global context, we use the coupled (atmosphere, land, and slab ocean) mode of ACME to demonstrate the impacts of deforestation on global climate, water, and nutrient fluxes. Preliminary results showed that the land component of ACME has advantages in simulating these processes and that local deforestation has potentially large impacts on runoff and atmospheric processes.

  13. Plain Water and Sugar-Sweetened Beverage Consumption in Relation to Energy and Nutrient Intake at Full-Service Restaurants

    PubMed Central

    An, Ruopeng

    2016-01-01

    Background: Drinking plain water, such as tap or bottled water, provides hydration and satiety without adding calories. We examined plain water and sugar-sweetened beverage (SSB) consumption in relation to energy and nutrient intake at full-service restaurants. Methods: Data came from the 2005–2012 National Health and Nutrition Examination Survey, comprising a nationally-representative sample of 2900 adults who reported full-service restaurant consumption in 24-h dietary recalls. Linear regressions were performed to examine the differences in daily energy and nutrient intake at full-service restaurants by plain water and SSB consumption status, adjusting for individual characteristics and sampling design. Results: Over 18% of U.S. adults had full-service restaurant consumption on any given day. Among full-service restaurant consumers, 16.7% consumed SSBs, 2.6% consumed plain water but no SSBs, and the remaining 80.7% consumed neither beverage at the restaurant. Compared to onsite SSB consumption, plain water but no SSB consumption was associated with reduced daily total energy intake at full-service restaurants by 443.4 kcal, added sugar intake by 58.2 g, saturated fat intake by 4.4 g, and sodium intake by 616.8 mg, respectively. Conclusion: Replacing SSBs with plain water consumption could be an effective strategy to balance energy/nutrient intake and prevent overconsumption at full-service restaurant setting. PMID:27153083

  14. Plain Water and Sugar-Sweetened Beverage Consumption in Relation to Energy and Nutrient Intake at Full-Service Restaurants.

    PubMed

    An, Ruopeng

    2016-05-04

    Drinking plain water, such as tap or bottled water, provides hydration and satiety without adding calories. We examined plain water and sugar-sweetened beverage (SSB) consumption in relation to energy and nutrient intake at full-service restaurants. Data came from the 2005-2012 National Health and Nutrition Examination Survey, comprising a nationally-representative sample of 2900 adults who reported full-service restaurant consumption in 24-h dietary recalls. Linear regressions were performed to examine the differences in daily energy and nutrient intake at full-service restaurants by plain water and SSB consumption status, adjusting for individual characteristics and sampling design. Over 18% of U.S. adults had full-service restaurant consumption on any given day. Among full-service restaurant consumers, 16.7% consumed SSBs, 2.6% consumed plain water but no SSBs, and the remaining 80.7% consumed neither beverage at the restaurant. Compared to onsite SSB consumption, plain water but no SSB consumption was associated with reduced daily total energy intake at full-service restaurants by 443.4 kcal, added sugar intake by 58.2 g, saturated fat intake by 4.4 g, and sodium intake by 616.8 mg, respectively. Replacing SSBs with plain water consumption could be an effective strategy to balance energy/nutrient intake and prevent overconsumption at full-service restaurant setting.

  15. Research to Inform Nutrient Thresholds and Prioritization of ...

    EPA Pesticide Factsheets

    The information in this presentation focuses on SSWR's 4.02 project, which will advance the science needed to inform decisions to prioritize watersheds and nutrient sources for nutrient management and define appropriate nutrient levels for the nation’s waters, two important elements of EPA’s framework for managing nutrient pollution. The information in this presentation focuses on SSWR's 4.02 project, which will advance the science needed to inform decisions to prioritize watersheds and nutrient sources for nutrient management and define appropriate nutrient levels for the nation’s waters, two important elements of EPA’s framework for managing nutrient pollution.

  16. Patterns and processes of nutrient transfers from land to water: a catchment approach to evaluate Good Agricultural Practice in Ireland

    NASA Astrophysics Data System (ADS)

    Mellander, P.-E.; Melland, A. R.; Shortle, G.; Wall, D.; Mechan, S.; Buckley, C.; Fealy, R.; Jordan, P.

    2009-04-01

    Eutrophication of fresh, transitional and coastal waters by excessive nutrient inputs is one of the most widespread water quality problems in developed countries. Sources of nutrient nitrogen (N) and phosphorus (P) can come from a multiplicity of sources and be dependent on numerous hydrological controls from catchments with both urban and agricultural landuses. Aquatic impacts are widely reported as a result of excessive nutrient transfers from land to water and include changes in ecological integrity and loss of amenity. In the European Union, the Water Framework Directive (WFD) and associated Directives are the key structures with which member states must develop national and often trans-national polices to deal with issues of water resources management. The linked Nitrates Directive is particularly concerned with integrating sustainable agriculture and good water quality objectives and is written into national polices. In Ireland this policy is the Nitrates Directive National Action Programme (NAP), Statutory Instruction 378, Good Agricultural Practise regulation, and amongst other things, sets targets and limits on the use of organic and inorganic fertilisers, soil fertility and slurry/fertiliser spreading and cultivation times. To evaluate the effectiveness of this policy, Teagasc, the Irish Agriculture and Food Development Authority, is undertaking a catchment scale audit on sources, sinks, and changes in nutrient use and export over several years. The Agricultural Catchments Programme is based on a science-stakeholder-management partnership to generate knowledge and specifically to protect water quality from nitrogen and phosphorus transfers within the constraints of the requirements of modern Irish agricultural practises. Eight catchments of 5-12 km2 have been selected for the programme to represent a range of agricultural intensities and vulnerabilities to nitrogen and phosphorus loss including catchments that are situated on permeable and impermeable

  17. Nutrient pressures and ecological responses to nutrient loading reductions in Danish streams, lakes and coastal waters

    NASA Astrophysics Data System (ADS)

    Kronvang, Brian; Jeppesen, Erik; Conley, Daniel J.; Søndergaard, Martin; Larsen, Søren E.; Ovesen, Niels B.; Carstensen, Jacob

    2005-03-01

    The Danish National Aquatic Monitoring and Assessment Programme (NOVA) was launched in 1988 following the adoption of the first Danish Action Plan on the Aquatic Environment in 1987 with the aim to reduce by 50% the nitrogen (N) loading and by 80% the phosphorus (P) loading to the aquatic environment. The 14 years of experience gathered from NOVA have shown that discharges of total N (TN) and P (TP) from point sources to the Danish Aquatic Environment have been reduced by 69% (N) and 82% (P) during the period 1989 2002. Consequently, the P concentration has decreased markedly in most Danish lakes and estuaries. Considerable changes in agricultural practice have resulted in a reduction of the net N-surplus from 136 to 88 kg N ha-1 yr-1 (41%) and the net P-surplus from 19 to 11 kg P ha-1 yr-1 (42%) during the period 1985 2002. Despite these efforts Danish agriculture is today the major source of both N (>80%) and P (>50%) in Danish streams, lakes and coastal waters. A non-parametric statistical trend analysis of TN concentrations in streams draining dominantly agricultural catchments has shown a significant (p<0.05) downward trend in 48 streams with the downward trend being stronger in loamy compared to sandy catchments, and more pronounced with increasing dominance of agricultural exploitation in the catchments. In contrast, a statistical trend analysis of TP concentrations in streams draining agricultural catchments did not reveal any significant trends. The large reduction in nutrient loading from point and non-point sources has in general improved the ecological conditions of Danish lakes in the form of increased summer Secchi depth, decreased chlorophyll a and reduced phytoplankton biomass. Major changes have also occurred in the fish communities in lakes, with positive cascading effects on water quality. In Danish estuaries and coastal waters only a few significant improvements in the ecological quality have been observed, although it is expected that the

  18. Soil, water, and nutrient losses from management alternatives for degraded pasture in Brazilian Atlantic Rainforest biome.

    PubMed

    Rocha Junior, Paulo Roberto da; Andrade, Felipe Vaz; Mendonça, Eduardo de Sá; Donagemma, Guilherme Kangussú; Fernandes, Raphael Bragança Alves; Bhattharai, Rabin; Kalita, Prasanta Kumar

    2017-04-01

    The objective of this study was to evaluate sediment, water and nutrient losses from different pasture managements in the Atlantic Rainforest biome. A field study was carried out in Alegre Espiríto Santo, Brazil, on a Xanthic Ferralsol cultivated with braquiaria (Brachiaria brizantha). The six pasture managements studied were: control (CON), chisel (CHI), fertilizer (FER), burned (BUR), plowing and harrowing (PH), and integrated crop-livestock (iCL). Runoff and sediment samples were collected and analyzed for calcium (Ca), magnesium (Mg), potassium (K), phosphorus (P) and organic carbon contents. Soil physical attributes and above and below biomass were also evaluated. The results indicated that higher water loss was observed for iCL (129.90mm) and CON (123.25mm) managements, and the sediment losses were higher for CON (10.24tha -1 ) and BUR (5.20tha -1 ) managements when compared to the other managements. Majority of the nutrients losses occurred in dissolved fraction (99% of Ca, 99% of Mg, 96% of K, and 65% of P), whereas a significant fraction of organic carbon (80%) loss occurred in a particulate form. Except for P, other nutrients (Ca, Mg and K) and organic carbon losses were higher in coarse sediment compared to fine sediment. The greater losses of sediment, organic carbon, and nutrients were observed for CON followed by BUR management (p<0.05). Our findings indicated that the traditional pasture management adopted in the Atlantic Rainforest needs to be rethought and burned management should be avoided. Based on the water, soil, and nutrient losses from various practices, to reduce pasture degradation, farmers should adopt edaphic practices by applying lime and fertilize to improve pasture growth and soil cover, and reducing soil erosion in the hilly Brazilian Atlantic Rainforest biome. Copyright © 2016. Published by Elsevier B.V.

  19. Eutrophication of Buttermilk Bay, a cape cod coastal embayment: Concentrations of nutrients and watershed nutrient budgets

    NASA Astrophysics Data System (ADS)

    Valiela, Ivan; Costa, Joseph E.

    1988-07-01

    Nutrient concentrations in Buttermilk Bay, a coastal embayment on the northern end of Buzzards Bay, MA, are higher in the nearshore where salinities are lower. This pattern suggests that freshwater sources may contribute significantly to nutrient inputs into Buttermilk Bay. To evaluate the relative importance of the various sources we estimated inputs of nutrients by each major source into the watershed and into the bay itself. Septic systems contributed about 40% of the nitrogen and phosphorus entering the watershed, with precipitation and fertilizer use adding the remainder. Groundwater transported over 85% of the nitrogen and 75% of the phosphorus entering the bay. Most nutrients entering the watershed failed to reach the bay; uptake by forests, soils, denitrification, and adsorption intercepted two-thirds of the nitrogen and nine-tenths of the phosphorus that entered the watershed. The nutrients that did reach the bay most likely originated from subsoil injections into groundwater by septic tanks, plus some leaching of fertilizers. Buttermilk Bay water has relatively low nutrient concentrations, probably because of uptake of nutrients by macrophytes and because of relatively rapid tidal flushing. Annual budgets of nutrients entering the watershed showed a low nitrogen-to-phosphorus ratio of 6, but passage of nutrients through the watershed raised N/P to 23, probably because of adsorption of PO4 during transit. The N/P ratio of water that leaves the watershed and presumably enters the bay is probably high enough to maintain active growth of nitrogenlimited coastal producers. There is a seasonal shift in N/P in the water column of Buttermilk Bay. N/P exceeded the 16∶1 Redfield ratio during midwinter; the remainder of the year N/P fell below 16∶1. This suggests that annual budgets do not provide sufficiently detailed data with which to interpret nutrient-limitation of producers. Further, some idea of water turnover is also needed to evaluate impact of loading

  20. Photodegradation of diclofenac in aqueous solution by simulated sunlight irradiation: kinetics, thermodynamics and pathways.

    PubMed

    Zhang, N; Li, J M; Liu, G G; Chen, X L; Jiang, K

    2017-05-01

    Diclofenac (DCF) is one of the most frequently detected pharmaceuticals in various water samples. This paper studied the effects of aquatic environmental factors (pH, temperature and dissolved organic matter) on photodegradation of DCF under simulated sunlight. The results demonstrate that degradation pathways proceed via pseudo first-order kinetics in all cases and the photodegradation of DCF by simulated sunlight. Thermodynamic study indicated that the photodegradation course is spontaneous, exothermic and irreversible. The rate constant gradually increased when the pH increased from 3 to 5, then decreased when the pH increased from 5 to 8, and finally increased when the pH further increased from 8 to 12. Humic acid inhibited the photodegradation of DCF. Three kinds of main degradation products were observed by high performance liquid chromatography/mass spectrometry and the degradation pathways were suggested. A toxicity test using Photobacterium phosphoreum T 3 Sp indicated the generation of some more toxic products than DCF.

  1. Absorption of Sunlight by Water Vapor in Cloudy Conditions: A Partial Explanation for the Cloud Absorption Anomaly

    NASA Technical Reports Server (NTRS)

    Crisp, D.

    1997-01-01

    The atmospheric radiative transfer algorithms used in most global general circulation models underestimate the globally-averaged solar energy absorbed by cloudy atmospheres by up to 25 W/sq m. The origin of this anomalous absorption is not yet known, but it has been attributed to a variety of sources including oversimplified or missing physical processes in these models, uncertainties in the input data, and even measurement errors. Here, a sophisticated atmospheric radiative transfer model was used to provide a more comprehensive description of the physical processes that contribute to the absorption of solar radiation by the Earth's atmosphere. We found that the amount of sunlight absorbed by a cloudy atmosphere is inversely proportional to the solar zenith angle and the cloud top height, and directly proportional to the cloud optical depth and the water vapor concentration within the clouds. Atmospheres with saturated, optically-thick, low clouds absorbed about 12 W/sq m more than clear atmospheres. This accounts for about 1/2 to 1/3 of the anomalous ab- sorption. Atmospheres with optically thick middle and high clouds usually absorb less than clear atmospheres. Because water vapor is concentrated within and below the cloud tops, this absorber is most effective at small solar zenith angles. An additional absorber that is distributed at or above the cloud tops is needed to produce the amplitude and zenith angle dependence of the observed anomalous absorption.

  2. Nutrient Status of Adults with Cystic Fibrosis

    PubMed Central

    GORDON, CATHERINE M.; ANDERSON, ELLEN J.; HERLYN, KAREN; HUBBARD, JANE L.; PIZZO, ANGELA; GELBARD, RONDI; LAPEY, ALLEN; MERKEL, PETER A.

    2011-01-01

    Nutrition is thought to influence disease status in patients with cystic fibrosis (CF). This cross-sectional study sought to evaluate nutrient intake and anthropometric data from 64 adult outpatients with cystic fibrosis. Nutrient intake from food and supplements was compared with the Dietary Reference Intakes for 16 nutrients and outcomes influenced by nutritional status. Attention was given to vitamin D and calcium given potential skeletal implications due to cystic fibrosis. Measurements included weight, height, body composition, pulmonary function, and serum metabolic parameters. Participants were interviewed about dietary intake, supplement use, pulmonary function, sunlight exposure, and pain. The participants’ mean body mass index (±standard deviation) was 21.8±4.9 and pulmonary function tests were normal. Seventy-eight percent used pancreatic enzyme replacement for malabsorption. Vitamin D deficiency [25-hydroxyvitamin D (25OHD)<37.5 nmol/L] was common: 25 (39%) were deficient despite adequate vitamin D intake. Lipid profiles were normal in the majority, even though total and saturated fat consumption represented 33.0% and 16.8% of energy intake, respectively. Reported protein intake represented 16.9% of total energy intake (range 10%–25%). For several nutrients, including vitamin D and calcium, intake from food and supplements in many participants exceeded recommended Tolerable Upper Intake Levels. Among adults with cystic fibrosis, vitamin D deficiency was common despite reported adequate intake, and lipid profiles were normal despite a relatively high fat intake. Mean protein consumption was adequate, but the range of intake was concerning, as both inadequate or excessive intake may have deleterious skeletal effects. These findings call into question the applicability of established nutrient thresholds for patients with cystic fibrosis. PMID:18060897

  3. Martian base agriculture: The effect of low gravity on water flow, nutrient cycles, and microbial biomass dynamics

    NASA Astrophysics Data System (ADS)

    Maggi, Federico; Pallud, Céline

    2010-11-01

    The latest advances in bioregenerative strategies for long-term life support in extraterrestrial outposts such as on Mars have indicated soil-based cropping as an effective approach for waste decomposition, carbon sequestration, oxygen production, and water biofiltration as compared to hydroponics and aeroponics cropping. However, it is still unknown if cropping using soil systems could be sustainable in a Martian greenhouse under a gravity of 0.38 g. The most challenging aspects are linked to the gravity-induced soil water flow; because water is crucial in driving nutrient and oxygen transport in both liquid and gaseous phases, a gravitational acceleration lower than g = 9.806 m s -2 could lead to suffocation of microorganisms and roots, with concomitant emissions of toxic gases. The effect of Martian gravity on soil processes was investigated using a highly mechanistic model previously tested for terrestrial crops that couples soil hydraulics and nutrient biogeochemistry. Net leaching of NO3- solute, gaseous fluxes of NH 3, CO 2, N 2O, NO and N 2, depth concentrations of O 2, CO 2 and dissolved organic carbon (DOC), and pH in the root zone were calculated for a bioregenerative cropping unit under gravitational acceleration of Earth and for its homologous on Mars, but under 0.38 g. The two cropping units were treated with the same fertilizer type and rate, and with the same irrigation regime, but under different initial soil moisture content. Martian gravity reduced water and solute leaching by about 90% compared to Earth. This higher water holding capacity in soil under Martian gravity led to moisture content and nutrient concentrations that favoured the metabolism of various microbial functional groups, whose density increased by 5-10% on Mars as compared to Earth. Denitrification rates became substantially more important than on Earth and ultimately resulted in 60%, 200% and 1200% higher emissions of NO, N 2O and N 2 gases, respectively. Similarly, O 2 and DOC

  4. HISTORY OF SUNLIGHT EXPOSURE IS A RISK FACTOR FOR AGE-RELATED MACULAR DEGENERATION.

    PubMed

    Schick, Tina; Ersoy, Lebriz; Lechanteur, Yara T E; Saksens, Nicole T M; Hoyng, Carel B; den Hollander, Anneke I; Kirchhof, Bernd; Fauser, Sascha

    2016-04-01

    To evaluate effects of current and past sunlight exposure and iris color on early and late age-related macular degeneration (AMD). Of 3,701 individuals from the EUGENDA database, 752 (20.3%) showed early AMD, 1,179 (31.9%) late AMD, and 1,770 (47.8%) were controls. Information about current and past sunlight exposure, former occupation type, subdivided in indoor working and outdoor working, and iris color were obtained by standardized interviewer-assisted questionnaires. Associations between environmental factors adjusted for age, gender, and smoking and early and late AMD were performed by multivariate regression analysis. Current sunlight exposure showed no association with early AMD or late AMD, but past sunlight exposure (≥8 hours outside daily) was significantly associated with early AMD (odds ratio: 5.54, 95% confidence interval 1.25-24.58, P = 0.02) and late AMD (odds ratio: 2.77, 95% confidence interval 1.25-6.16, P = 0.01). Outside working was found to be associated with late AMD (odds ratio: 2.57, 95% confidence interval 1.89-3.48, P = 1.58 × 10). No association was observed between iris color and early or late AMD. Sunlight exposure during working life is an important risk factor for AMD, whereas sunlight exposure after retirement seems to have less influence on the disease development. Therefore, preventive measures, for example, wearing sunglasses to minimize sunlight exposure, should start early to prevent development of AMD later in life.

  5. Morphology-dependent water budgets and nutrient fluxes in arctic thaw ponds

    USGS Publications Warehouse

    Koch, Joshua C.; Gurney, Kirsty; Wipfli, Mark S.

    2014-01-01

    Thaw ponds on the Arctic Coastal Plain of Alaska are productive ecosystems, providing habitat and food resources for many fish and bird species. Permafrost in this region creates unique pond morphologies: deep troughs, shallow low-centred polygons (LCPs) and larger coalescent ponds. By monitoring seasonal trends in pond volume and chemistry, we evaluated whether pond morphology and size affect water temperature and desiccation, and nitrogen (N) and phosphorus (P) fluxes. Evaporation was the largest early-summer water flux in all pond types. LCPs dried quickly and displayed high early-summer nutrient concentrations and losses. Troughs consistently received solute-rich subsurface inflows, which accounted for 12 to 42 per cent of their volume and may explain higher P in the troughs. N to P ratios increased and ammonium concentrations decreased with pond volume, suggesting that P and inorganic N availability may limit ecosystem productivity in older, larger ponds. Arctic summer temperatures will likely increase in the future, which may accelerate mid-summer desiccation. Given their morphology, troughs may remain wet, become warmer and derive greater nutrient loads from their thawing banks. Overall, seasonal- to decadal-scale warming may increase ecosystem productivity in troughs relative to other Arctic Coastal Plain ponds. 

  6. Visual performance with sport-tinted contact lenses in natural sunlight.

    PubMed

    Erickson, Graham B; Horn, Fraser C; Barney, Tyler; Pexton, Brett; Baird, Richard Y

    2009-05-01

    The use of tinted and clear contact lenses (CLs) in all aspects of life is becoming a more popular occurrence, particularly in athletic activities. This study broadens previous research regarding performance-tinted CLs and their effects on measures of visual performance. Thirty-three subjects (14 male, 19 female) were fitted with clear B&L Optima 38, 50% visible light transmission Amber and 36% visible light transmission Gray-Green Nike Maxsight CLs in an individualized randomized sequence. Subjects were dark-adapted with welding goggles before testing and in between subtests involving a Bailey-Lovie chart and the Haynes Distance Rock test. The sequence of testing was repeated for each lens modality. The Amber and Gray-Green lenses enabled subjects to recover vision faster in bright sunlight compared with clear lenses. Also, subjects were able to achieve better visual recognition in bright sunlight when compared with clear lenses. Additionally, the lenses allowed the subjects to alternate fixation between a bright and shaded target at a more rapid rate in bright sunlight as compared with clear lenses. Subjects preferred both the Amber and Gray-Green lenses over clear lenses in the bright and shadowed target conditions. The results of the current study show that Maxsight Amber and Gray-Green lenses provide better contrast discrimination in bright sunlight, better contrast discrimination when alternating between bright and shaded target conditions, better speed of visual recovery in bright sunlight, and better overall visual performance in bright and shaded target conditions compared with clear lenses.

  7. Nutrient transport in the mammary gland: calcium, trace minerals and water soluble vitamins.

    PubMed

    Montalbetti, Nicolas; Dalghi, Marianela G; Albrecht, Christiane; Hediger, Matthias A

    2014-03-01

    Milk nutrients are secreted by epithelial cells in the alveoli of the mammary gland by several complex and highly coordinated systems. Many of these nutrients are transported from the blood to the milk via transcellular pathways that involve the concerted activity of transport proteins on the apical and basolateral membranes of mammary epithelial cells. In this review, we focus on transport mechanisms that contribute to the secretion of calcium, trace minerals and water soluble vitamins into milk with particular focus on the role of transporters of the SLC series as well as calcium transport proteins (ion channels and pumps). Numerous members of the SLC family are involved in the regulation of essential nutrients in the milk, such as the divalent metal transporter-1 (SLC11A2), ferroportin-1 (SLC40A1) and the copper transporter CTR1 (SLC31A1). A deeper understanding of the physiology and pathophysiology of these transporters will be of great value for drug discovery and treatment of breast diseases.

  8. USA Nutrient managment forecasting via the "Fertilizer Forecaster": linking surface runnof, nutrient application and ecohydrology.

    NASA Astrophysics Data System (ADS)

    Drohan, Patrick; Buda, Anthony; Kleinman, Peter; Miller, Douglas; Lin, Henry; Beegle, Douglas; Knight, Paul

    2017-04-01

    USA and state nutrient management planning offers strategic guidance that strives to educate farmers and those involved in nutrient management to make wise management decisions. A goal of such programs is to manage hotspots of water quality degradation that threaten human and ecosystem health, water and food security. The guidance provided by nutrient management plans does not provide the day-to-day support necessary to make operational decisions, particularly when and where to apply nutrients over the short term. These short-term decisions on when and where to apply nutrients often make the difference between whether the nutrients impact water quality or are efficiently utilized by crops. Infiltrating rainfall events occurring shortly after broadcast nutrient applications are beneficial, given they will wash soluble nutrients into the soil where they are used by crops. Rainfall events that generate runoff shortly after nutrients are broadcast may wash off applied nutrients, and produce substantial nutrient losses from that site. We are developing a model and data based support tool for nutrient management, the Fertilizer Forecaster, which identifies the relative probability of runoff or infiltrating events in Pennsylvania (PA) landscapes in order to improve water quality. This tool will support field specific decisions by farmers and land managers on when and where to apply fertilizers and manures over 24, 48 and 72 hour periods. Our objectives are to: (1) monitor agricultural hillslopes in watersheds representing four of the five Physiographic Provinces of the Chesapeake Bay basin; (2) validate a high resolution mapping model that identifies soils prone to runoff; (3) develop an empirically based approach to relate state-of-the-art weather forecast variables to site-specific rainfall infiltration or runoff occurrence; (4) test the empirical forecasting model against alternative approaches to forecasting runoff occurrence; and (5) recruit farmers from the four

  9. Water uptake and nutrient concentrations under a floodplain oak savanna during a non-flood period, lower Cedar River, Iowa

    USGS Publications Warehouse

    Schilling, K.E.; Jacobson, P.

    2009-01-01

    Floodplains during non-flood periods are less well documented than when flooding occurs, but non-flood periods offer opportunities to investigate vegetation controls on water and nutrient cycling. In this study, we characterized water uptake and nutrient concentration patterns from 2005 to 2007 under an oak savanna located on the floodplain of the Cedar River in Muscatine County, Iowa. The water table ranged from 0.5 to 2.5 m below ground surface and fluctuated in response to stream stage, plant water demand and rainfall inputs. Applying the White method to diurnal water table fluctuations, daily ET from groundwater averaged more than 3.5 mm/day in June and July and approximately 2 mm/day in May and August. Total annual ET averaged 404 mm for a growing season from mid-May to mid-October. Savanna groundwater concentrations of nitrate-N, ammonium-N, and phosphate-P were very low (mean <0.18, <0.14, <0.08 mg/l, respectively), whereas DOC concentrations were high (7.1 mg/l). Low concentrations of N and P were in contrast to high nutrient concentrations in the nearby Cedar River, where N and P averaged 7.5 mg/ l and 0.13, respectively. In regions dominated by intensive agriculture, study results document valuable ecosystem services for native floodplain ecosystems in reducing watershed-scale nutrient losses and providing an oasis for biological complexity. Improved understanding of the environmental conditions of regionally significant habitats, including major controls on water table elevations and water quality, offers promise for better management aimed at preserving the ecology of these important habitats. Copyright ?? 2009 John Wiley & Sons, Ltd.

  10. Sunlight-readable display technology: a dual-use case study

    NASA Astrophysics Data System (ADS)

    Blanchard, Randall D.

    1996-05-01

    This paper describes our vision of sunlight readable color display requirements, an alternate technology that offers a high level of performance, and how we implemented it for the military avionics display market. This knowledge base and product development experience was then applied with a comparable level of performance to commercial applications. The successful dual use of this technology for these two diverse markets is presented. Details of the technical commonality and a comparison of the design and performance differences are presented. A basis for specifying the required level of performance for a sunlight readable full color display is discussed. With the objective of providing a high level of image brightness and high ambient light rejection, a display architecture using collimated light is used. The resulting designs of two military cockpit display products, with contrast ratios above 20:1 in sunlight are shown. The performance of a commercial display providing several thousand foot- Lamberts of image brightness is presented.

  11. Duration of Casual Sunlight Exposure Necessary for Adequate Vitamin D Status in Indian Men

    PubMed Central

    Patwardhan, Vivek G.; Mughal, Zulf M.; Chiplonkar, Shashi A.; Webb, Ann R.; Kift, Richard; Khadilkar, Vaman V.; Padidela, Raja; Khadilkar, Anuradha V.

    2018-01-01

    Objectives: To investigate the duration of casual sunlight ultraviolet-B (UVB) exposure required to maintain optimal Vitamin D status (25-hydroxyvitamin-D [25(OH)D]) >50 nmol/L in urban Indian men, using polysulfone (PSU) dosimeters and a sunlight exposure questionnaire. Methods: In healthy men (aged 40–60 years) from Pune (18.52° N, 73.86° E), India, serum 25(OH)D was measured using enzyme-linked immunosorbent assay. Sunlight exposure was assessed using PSU dosimeter and by questionnaire. Results: Of 160 men (48.3 ± 5.6 years), 26.8% were deficient and 40.6% had insufficient Vitamin D concentrations. A hyperbolic function for the relationship between PSU measured sunlight exposure in standard erythema dose (SED) and serum 25(OH)D concentrations (r = 0.87, P < 0.01) revealed that daily exposure of 1 SED was sufficient to maintain serum 25(OH)D concentrations over 50 nmol/L. The curve plateaued around 5 SED (80 nmol/L) and extrapolation of the curve (>5 SED) did not increase 25(OH)D concentrations above 90 nmol/L. Receiver operating curve analysis confirmed that 1 SED-UV exposure was sufficient to maintain 25(OH)D concentrations over 50 nmol/L. Based on the questionnaire data, >1 h of midday casual sunlight exposure was required to maintain serum 25(OH)D concentrations above 50 nmol/L. Duration of sunlight exposure assessed by questionnaire and PSU dosimeter showed a significant correlation (r = 0.517, P < 0.01). Conclusion: In urban Indian men, >1 h of casual midday sunlight exposure daily was required to maintain serum 25(OH)D concentrations above 50 nmol/L, and >2 h of casual sunlight exposure was needed to maintain 25(OH)D concentrations above 75 nmol/L. Excess sunlight did not increase 25(OH)D linearly. The sunlight exposure questionnaire was validated for use in clinical studies and surveys.

  12. Nutrient Content and Nutritional Water Productivity of Selected Grain Legumes in Response to Production Environment.

    PubMed

    Chibarabada, Tendai Polite; Modi, Albert Thembinkosi; Mabhaudhi, Tafadzwanashe

    2017-10-26

    There is a need to incorporate nutrition into aspects of crop and water productivity to tackle food and nutrition insecurity (FNS). The study determined the nutritional water productivity (NWP) of selected major (groundnut, dry bean) and indigenous (bambara groundnut and cowpea) grain legumes in response to water regimes and environments. Field trials were conducted during 2015/16 and 2016/17 at three sites in KwaZulu-Natal, South Africa (Ukulinga, Fountainhill and Umbumbulu). Yield and evapotranspiration (ET) data were collected. Grain was analysed for protein, fat, Ca, Fe and Zn nutrient content (NC). Yield, ET and NC were then used to compute NWP. Overall, the major legumes performed better than the indigenous grain legumes. Groundnut had the highest NWP fat . Groundnut and dry bean had the highest NWP protein . For NWP Fe, Zn and Ca , dry bean and cowpea were more productive. Yield instability caused fluctuations in NWP. Water treatments were not significant ( p > 0.05). While there is scope to improve NWP under rainfed conditions, a lack of crop improvement currently limits the potential of indigenous grain legumes. This provides an initial insight on the nutrient content and NWP of a limited number of selected grain legumes in response to the production environment. There is a need for follow-up research to include cowpea data. Future studies should provide more experimental data and explore effects of additional factors such as management practices (fertiliser levels and plant density), climate and edaphic factors on nutrient content and NWP of crops.

  13. Nutrient Content and Nutritional Water Productivity of Selected Grain Legumes in Response to Production Environment

    PubMed Central

    Chibarabada, Tendai Polite; Modi, Albert Thembinkosi

    2017-01-01

    There is a need to incorporate nutrition into aspects of crop and water productivity to tackle food and nutrition insecurity (FNS). The study determined the nutritional water productivity (NWP) of selected major (groundnut, dry bean) and indigenous (bambara groundnut and cowpea) grain legumes in response to water regimes and environments. Field trials were conducted during 2015/16 and 2016/17 at three sites in KwaZulu-Natal, South Africa (Ukulinga, Fountainhill and Umbumbulu). Yield and evapotranspiration (ET) data were collected. Grain was analysed for protein, fat, Ca, Fe and Zn nutrient content (NC). Yield, ET and NC were then used to compute NWP. Overall, the major legumes performed better than the indigenous grain legumes. Groundnut had the highest NWPfat. Groundnut and dry bean had the highest NWPprotein. For NWPFe, Zn and Ca, dry bean and cowpea were more productive. Yield instability caused fluctuations in NWP. Water treatments were not significant (p > 0.05). While there is scope to improve NWP under rainfed conditions, a lack of crop improvement currently limits the potential of indigenous grain legumes. This provides an initial insight on the nutrient content and NWP of a limited number of selected grain legumes in response to the production environment. There is a need for follow-up research to include cowpea data. Future studies should provide more experimental data and explore effects of additional factors such as management practices (fertiliser levels and plant density), climate and edaphic factors on nutrient content and NWP of crops. PMID:29072620

  14. Sources of nitrogen and phosphorus emissions to Irish rivers and coastal waters: Estimates from a nutrient load apportionment framework.

    PubMed

    Mockler, Eva M; Deakin, Jenny; Archbold, Marie; Gill, Laurence; Daly, Donal; Bruen, Michael

    2017-12-01

    More than half of surface water bodies in Europe are at less than good ecological status according to Water Framework Directive assessments, and diffuse pollution from agriculture remains a major, but not the only, cause of this poor performance. Agri-environmental policy and land management practices have, in many areas, reduced nutrient emissions to water. However, additional measures may be required in Ireland to further decouple the relationship between agricultural productivity and emissions to water, which is of vital importance given on-going agricultural intensification. The Source Load Apportionment Model (SLAM) framework characterises sources of phosphorus (P) and nitrogen (N) emissions to water at a range of scales from sub-catchment to national. The SLAM synthesises land use and physical characteristics to predict emissions from point (wastewater, industry discharges and septic tank systems) and diffuse sources (agriculture, forestry, etc.). The predicted annual nutrient emissions were assessed against monitoring data for 16 major river catchments covering 50% of the area of Ireland. At national scale, results indicate that total average annual emissions to surface water in Ireland are over 2700tyr -1 of P and 82,000tyr -1 of N. The proportional contributions from individual sources show that the main sources of P are from municipal wastewater treatment plants and agriculture, with wide variations across the country related to local anthropogenic pressures and the hydrogeological setting. Agriculture is the main source of N emissions to water across all regions of Ireland. These policy-relevant results synthesised large amounts of information in order to identify the dominant sources of nutrients at regional and local scales, contributing to the national nutrient risk assessment of Irish water bodies. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

  15. Nutrient additions by waterfowl to lakes and reservoirs: predicting their effects on productivity and water quality

    USGS Publications Warehouse

    Manny, Bruce A.; Johnson, W.C.; Wetzel, R.G.

    1994-01-01

    Lakes and reservoirs provide water for human needs and habitat for aquatic birds. Managers of such waters may ask whether nutrients added by waterfowl degrade water quality. For lakes and reservoirs where primary productivity is limited by phosphorus (P), we developed a procedure that integrates annual P loads from waterfowl and other external sources, applies a nutrient load-response model, and determines whether waterfowl that used the lake or reservoir degraded water quality. Annual P loading by waterfowl can be derived from a figure in this report, using the days per year that each kind spent on any lake or reservoir. In our example, over 6500 Canada geese (Branta canadensis) and 4200 ducks (mostly mallards, Anas platyrhynchos) added 4462 kg of carbon (C), 280 kg of nitrogen (N), and 88 kg of P y-1 to Wintergreen Lake in southwestern Michigan, mostly during their migration. These amounts were 69% of all C, 27% of all N, and 70% of all P that entered the lake from external sources. Loads from all external sources totaled 840 mg P m-2 y-1. Application of a nutrient load-response model to this concentration, the hydraulic load (0.25 m y-1), and the water residence time (9.7 y) of Wintergreen Lake yielded an average annual concentration of total P in the lake of 818 mg m-3 that classified the lake as hypertrophic. This trophic classification agreed with independent measures of primary productivity, chlorophyll-a, total P, total N, and Secchi disk transparency made in Wintergreen Lake. Our procedure showed that waterfowl caused low water quality in Wintergreen Lake.

  16. Hydrology, nutrient concentrations, and nutrient yields in nearshore areas of four lakes in northern Wisconsin, 1999-2001

    USGS Publications Warehouse

    Graczyk, David J.; Hunt, Randall J.; Greb, Steven R.; Buchwald, Cheryl A.; Krohelski, James T.

    2003-01-01

    The effects of shoreline development on water quality and nutrient yields in nearshore areas of four lakes in northern Wisconsin were investigated from October 1999 through September 2001. The study measured surface runoff and ground-water flows from paired developed (sites containing lawn, rooftops, sidewalks, and driveways) and undeveloped (mature and immature woods) catchments adjacent to four lakes in northern Wisconsin. Water samples from surface runoff and ground water were collected and analyzed for nutrients. Coupled with water volumes, loads and subsequent yields of selected constituents were computed for developed and undeveloped catchments. The median runoff from lawn surfaces ranged from 0.0019 to 0.059 inch over the catchment area. Median surface runoff estimates from the wooded catchments were an order of magnitude less than those from the lawn catchments. The increased water volumes from the lawn catchments resulted in greater nutrient loads and subsequent annual nutrient yields from the developed sites. Soil temperature and soil moisture were measured at two sites with mixed lawn and wooded areas. At both of these sites, the area covered with a lawn commonly was warmer than the wooded area. No consistent differences in soil moisture were found. A ground-water model was constructed to simulate the local flow systems at two of the paired catchments. Model simulations showed that much of the ground water delivered to the lake originated from distant areas that did not contribute runoff directly to the lake. Surface runoff and ground-water nutrient concentrations from the lawn and wooded catchments did not have apparent patterns. Some of the median concentrations from lawns were significantly different (at the 0.05 significance level) from those at wooded catchments. Water wells and piezometers were sampled for chemical analyses three times during the study period. Variability in the shallow ground-water chemistry over time in the lawn samples was

  17. Statistical modelling of variability in sediment-water nutrient and oxygen fluxes

    NASA Astrophysics Data System (ADS)

    Serpetti, Natalia; Witte, Ursula; Heath, Michael

    2016-06-01

    Organic detritus entering, or produced, in the marine environment is re-mineralised to inorganic nutrient in the seafloor sediments. The flux of dissolved inorganic nutrient between the sediment and overlying water column is a key process in the marine ecosystem, which binds the biogeochemical sub-system to the living food web. These fluxes are potentially affected by a wide range of physical and biological factors and disentangling these is a significant challenge. Here we develop a set of General Additive Models (GAM) of nitrate, nitrite, ammonia, phosphate, silicate and oxygen fluxes, based on a year-long campaign of field measurements off the north-east coast of Scotland. We show that sediment grain size, turbidity due to sediment re-suspension, temperature, and biogenic matter content were the key factors affecting oxygen consumption, ammonia and silicate fluxes. However, phosphate fluxes were only related to suspended sediment concentrations, whilst nitrate fluxes showed no clear relationship to any of the expected drivers of change, probably due to the effects of denitrification. Our analyses show that the stoichiometry of nutrient regeneration in the ecosystem is not necessarily constant and may be affected by combinations of processes. We anticipate that our statistical modelling results will form the basis for testing the functionality of process-based mathematical models of whole-sediment biogeochemistry.

  18. Sunlight Exposure and Vitamin D Status in Breastfed Infants.

    PubMed

    Meena, Pinky; Dabas, Aashima; Shah, Dheeraj; Malhotra, Rajeev Kumar; Madhu, S V; Gupta, Piyush

    2017-02-15

    To correlate the sunlight exposure in first 6 months to vitamin D status at 6 months of age in predominantly breastfed infants; and to quantify the sunlight exposure required to achieve serum 25(OH)D level >20 ng/mL, by 6 months of age. Design: Prospective cohort. Tertiary-care hospital predominantly catering to urban poor population in Delhi. 132 healthy infants, delivered at term, and predominantly breastfed were enrolled at 6-8 weeks of age. Of these, 100 infants were available for final evaluation at 6 months of age (mean (SD) follow-up: 126 (17) days). Baseline maternal vitamin D (serum 25(OH)D) levels were obtained at enrolment. The mothers were asked to maintain a daily record of duration of sunlight exposure, timing of exposure, and body surface area exposed, for the infant, on a pre-designed proforma, till the child was 6 months of age. Infant's serum 25(OH)D was measured at 6 months of age. Cumulative Sun Index was calculated as a composite measure of overall duration/time/body surface area exposed to sunlight; and correlated with the infant serum 25(OH)D after adjusting for baseline maternal serum 25(OH)D levels, season of exposure, and skin color of the infant. Sun index for exposure in morning (before 10 am) and afternoon (10 am-3 pm) were also correlated to vitamin D status. Of 100 mother-infant pairs completing the study, 90 mothers had vitamin D deficiency (serum 25(OH)D <12 ng/mL). The median duration of exposure of infants to sunlight was 17 min per week, on 6% of body surface area. Vitamin D levels of 67 (67%) infants at 6 months were less than 12 ng/mL and another 23% had insufficient levels (12-20 ng/mL). Cumulative sun index correlated positively to infant's serum 25(OH)D level at 6 months of age (r= 0.461, P<0.001). Increment in afternoon sun index by 1 unit increased the serum 25(OH)D level by 1.07 ng/mL (95% CI 0.37, 1.78; P= 0.003). A minimum 30 minute weekly afternoon sunlight exposure, between 10 am and 3 pm, over 40% body area (infant

  19. Sunlight Has Cardiovascular Benefits Independently of Vitamin D.

    PubMed

    Weller, Richard B

    2016-01-01

    High blood pressure (BP) is the leading risk factor for disability adjusted life years lost globally. Epidemiological data show a correlation between increased sun exposure and reduced population BP and cardiovascular mortality. Individuals with high serum vitamin D levels are at reduced risk of hypertension, cardiovascular disease and metabolic syndrome, yet multiple trial data show that oral vitamin D supplementation has no effect on these endpoints. Sunlight is a risk factor for skin cancers, but no link has been shown with increased all-cause mortality. Cohort studies from Scandinavia show a dose-dependent fall in mortality with increased sun-seeking behaviour. Skin contains significant stores of nitrogen oxides, which can be converted to NO by UV radiation and exported to the systemic circulation. Human studies show that this pathway can cause arterial vasodilatation and reduced BP. Murine studies suggest the same mechanism may reduce metabolic syndrome. Sunlight has beneficial effects on cardiovascular risk factors independently of vitamin D. All-cause mortality should be the primary determinant of public health messages. Sunlight is a risk factor for skin cancer, but sun avoidance may carry more of a cost than benefit for overall good health. © 2016 S. Karger AG, Basel.

  20. Assessment of macrophyte, heavy metal, and nutrient concentrations in the water of the Nairobi River, Kenya.

    PubMed

    Njuguna, Samwel Maina; Yan, Xue; Gituru, Robert Wahiti; Wang, Qingfeng; Wang, Jun

    2017-08-16

    Nairobi River tributaries are the main source of the Athi River. The Athi River basin is the fourth largest and important drainage system in Kenya covering 650 km and with a drainage area of 70,000 km 2 . Its water is used downstream by about four million people not only for irrigation but also for domestic purposes. However, its industrial, raw sewer, and agricultural pollution is alarming. In order to understand distribution and concentration of heavy metals and nutrients in the water of Nairobi River, 28 water samples were collected in the rainy season (October) of 2015 and dry season (June) of 2016. Cd, Cu, Cr, Zn, As, Pb, Fe, Ni, Mn, NO 3 - , and TP were analyzed. Only Cr, Pb, Fe, and Mn had concentrations exceeding the WHO permissible limit for drinking water. Out of the 28 sites examined in the study, one site had Pb exceeding the WHO recommended level. Similarly, three sites exceeded the same level for Cr. Only three sites were within the WHO permissible limits for drinking water for Mn while just four sites were within USEPA limit for Fe. Industrial effluent, domestic sewerage, agricultural activities, and solid waste were the main sources of pollution. Significant spatial variation of both heavy metals and nutrients concentration was observed and emanated from point source pollution. Eleven out of 31 macrophytes species that were identified along the river and its tributaries are effective heavy metal and nutrient bioaccumulators and may be used in phytoremediation.

  1. Bulk water phase and biofilm growth in drinking water at low nutrient conditions.

    PubMed

    Boe-Hansen, Rasmus; Albrechtsen, Hans-Jørgen; Arvin, Erik; Jørgensen, Claus

    2002-11-01

    In this study, the bacterial growth dynamics of a drinking water distribution system at low nutrient conditions was studied in order to determine bacterial growth rates by a range of methods, and to compare growth rates in the bulk water phase and the biofilm. A model distribution system was used to quantify the effect of retention times at hydraulic conditions similar to those in drinking water distribution networks. Water and pipe wall samples were taken and examined during the experiment. The pipes had been exposed to drinking water at approximately 13 degrees C, for at least 385 days to allow the formation of a mature quasi-stationary biofilm. At retention times of 12 h, total bacterial counts increased equivalent to a net bacterial growth rate of 0.048 day(-1). The bulk water phase bacteria exhibited a higher activity than the biofilm bacteria in terms of culturability, cell-specific ATP content, and cell-specific leucine incorporation rate. Bacteria in the bulk water phase incubated without the presence of biofilm exhibited a bacterial growth rate of 0.30 day(-1). The biofilm was radioactively labelled by the addition of 14C-benzoic acid. Subsequently, a biofilm detachment rate of 0.013 day(-1) was determined by measuring the release of 14C-labelled bacteria of the biofilm. For the quasi-stationary phase biofilm, the detachment rate was equivalent to the net growth rate. The growth rates determined in this study by different independent experimental approaches were comparable and within the range of values reported in the literature.

  2. Bioremediating Oil Spills in Nutrient Poor Ocean Waters Using Fertilized Clay Mineral Flakes: Some Experimental Constraints

    PubMed Central

    Warr, Laurence N.; Friese, André; Schwarz, Florian; Schauer, Frieder; Portier, Ralph J.; Basirico, Laura M.; Olson, Gregory M.

    2013-01-01

    Much oil spill research has focused on fertilizing hydrocarbon oxidising bacteria, but a primary limitation is the rapid dilution of additives in open waters. A new technique is presented for bioremediation by adding nutrient amendments to the oil spill using thin filmed minerals comprised largely of Fullers Earth clay. Together with adsorbed N and P fertilizers, filming additives, and organoclay, clay flakes can be engineered to float on seawater, attach to the oil, and slowly release contained nutrients. Our laboratory experiments of microbial activity on weathered source oil from the Deepwater Horizon spill in the Gulf of Mexico show fertilized clay treatment significantly enhanced bacterial respiration and consumption of alkanes compared to untreated oil-in-water conditions and reacted faster than straight fertilization. Whereas a major portion (up to 98%) of the alkane content was removed during the 1 month period of experimentation by fertilized clay flake interaction; the reduced concentration of polyaromatic hydrocarbons was not significantly different from the non-clay bearing samples. Such clay flake treatment could offer a way to more effectively apply the fertilizer to the spill in open nutrient poor waters and thus significantly reduce the extent and duration of marine oil spills, but this method is not expected to impact hydrocarbon toxicity. PMID:23864952

  3. Bioremediating oil spills in nutrient poor ocean waters using fertilized clay mineral flakes: some experimental constraints.

    PubMed

    Warr, Laurence N; Friese, André; Schwarz, Florian; Schauer, Frieder; Portier, Ralph J; Basirico, Laura M; Olson, Gregory M

    2013-01-01

    Much oil spill research has focused on fertilizing hydrocarbon oxidising bacteria, but a primary limitation is the rapid dilution of additives in open waters. A new technique is presented for bioremediation by adding nutrient amendments to the oil spill using thin filmed minerals comprised largely of Fullers Earth clay. Together with adsorbed N and P fertilizers, filming additives, and organoclay, clay flakes can be engineered to float on seawater, attach to the oil, and slowly release contained nutrients. Our laboratory experiments of microbial activity on weathered source oil from the Deepwater Horizon spill in the Gulf of Mexico show fertilized clay treatment significantly enhanced bacterial respiration and consumption of alkanes compared to untreated oil-in-water conditions and reacted faster than straight fertilization. Whereas a major portion (up to 98%) of the alkane content was removed during the 1 month period of experimentation by fertilized clay flake interaction; the reduced concentration of polyaromatic hydrocarbons was not significantly different from the non-clay bearing samples. Such clay flake treatment could offer a way to more effectively apply the fertilizer to the spill in open nutrient poor waters and thus significantly reduce the extent and duration of marine oil spills, but this method is not expected to impact hydrocarbon toxicity.

  4. Bacterial invasion potential in water is determined by nutrient availability and the indigenous community.

    PubMed

    Van Nevel, Sam; De Roy, Karen; Boon, Nico

    2013-09-01

    In drinking water (DW) and the distribution systems, bacterial growth and biofilm formation have to be controlled both for limiting taste or odour development and preventing clogging or biocorrosion problems. After a contamination with undesired bacteria, factors like nutrient availability and temperature will influence the survival of these invaders. Understanding the conditions enabling invaders to proliferate is essential for a holistic approach towards microbial risk assessment in DW. Pseudomonas putida was used as a model invader because this easy-growing bacterium can use a wide range of substrates. Invasion experiments in oligo- to eutrophic waters showed the requirement of both a carbon and phosphate source for survival of P. putida in DW. Addition of C, N and P enabled P. putida to grow in DW from 5.80 × 10(4) to 1.84 × 10(8) cells mL(-1) and survive for at least 12 days. However, in surface water with similar nutrient concentrations, P. putida did not survive, indicating the concomitant importance of the present indigenous microbial community of the specific water sample. Either extensive carbon or phosphate limitation can be used in water treatment design in order to obtain a DW which is not susceptible for unwanted bacterial growth. © 2013 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

  5. Degradation of emerging contaminants from water under natural sunlight: The effect of season, pH, humic acids and nitrate and identification of photodegradation by-products.

    PubMed

    Koumaki, Elena; Mamais, Daniel; Noutsopoulos, Constantinos; Nika, Maria-Christina; Bletsou, Anna A; Thomaidis, Nikolaos S; Eftaxias, Alexander; Stratogianni, Georgia

    2015-11-01

    Both photodegradation and hydrolysis of non-steroidal anti-inflammatory drugs (NSAIDs) and endocrine disrupting chemicals (EDCs) were investigated in order to evaluate their photochemical fate in aquatic environment and to assess the effect of season and specific characteristics of water (pH, humic acids and nitrate concentration) on the removal of target EDCs and NSAIDs through photodegradation. An additional objective was the identification of the photodegradation by-products of specific NSAIDs and their dependence on irradiation time. Selected compounds' transformation was investigated under natural sunlight radiation while control experiments were conducted in the dark. As expected, most of compounds' degradation rate decreased with decreasing light intensity between two different experimental periods. Most of the tested compounds exhibited different rates of degradation during direct and indirect photolysis. The degradation rate of the selected compounds increased in the presence of NO3(-) and the photodegradation rate was higher for some compounds in alkaline than in acidic solution. The effect of humic acids' presence in the water depends on the absorbance spectrum of the compound and the produced photosensitizers. More specifically, humic acids act as inner filter toward most of the selected NSAIDs and as photosensitizers toward most of the EDCs. The results of the irradiation experiments in the presence of both humic acids and NO3(-), indicate that the direct photolysis is much more efficient than indirect photochemical processes. Finally, several degradation by-products of ketoprofen and diclofenac were identified in the samples, exposed to sunlight. The dependence of these by-products on radiation time is also demonstrated. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Wintering birds avoid warm sunshine: predation and the costs of foraging in sunlight.

    PubMed

    Carr, Jennie M; Lima, Steven L

    2014-03-01

    Wintering birds can gain significant thermal benefits by foraging in direct sunlight. However, exposure to bright sunlight might make birds easier to detect by predators and may also cause visual glare that can reduce a bird's ability to monitor the environment. Thus, birds likely experience a trade-off between the thermal benefits and predation-related costs of foraging in direct sunlight. To examine this possible thermoregulation-predation trade-off, we monitored the behavior of mixed-species flocks of wintering emberizid sparrows foraging in alternating strips of sunlight and shade. On average, these sparrows routinely preferred to forage in the shade, despite midday air temperatures as much as 30 °C below their thermoneutral zone. This preference for shade was strongest at relatively high temperatures when the thermal benefits of foraging in sunlight were reduced, suggesting a thermoregulation-predation trade-off. Glare could be reduced if birds faced away from the sun while feeding in direct sunlight, but we found that foraging birds tended to face southward (the direction of the sun). We speculate that other factors, such as the likely direction of predator approach, may explain this southerly orientation, particularly if predators use solar glare to their advantage during an attack. This interpretation is supported by the fact that birds had the weakest southerly orientation on cloudy days. Wintering birds may generally avoid foraging in direct sunlight to minimize their risk of predation. However, given the thermal benefits of sunshine, such birds may benefit from foraging in habitats that provide a mosaic of sunlit and shaded microhabitats.

  7. Intensity correlation imaging with sunlight-like source

    NASA Astrophysics Data System (ADS)

    Wang, Wentao; Tang, Zhiguo; Zheng, Huaibin; Chen, Hui; Yuan, Yuan; Liu, Jinbin; Liu, Yanyan; Xu, Zhuo

    2018-05-01

    We show a method of intensity correlation imaging of targets illuminated by a sunlight-like source both theoretically and experimentally. With a Faraday anomalous dispersion optical filter (FADOF), we have modulated the coherence time of a thermal source up to 0.167 ns. And we carried out measurements of temporal and spatial correlations, respectively, with an intensity interferometer setup. By skillfully using the even Fourier fitting on the very sparse sampling data, the images of targets are successfully reconstructed from the low signal-noise-ratio(SNR) interference pattern by applying an iterative phase retrieval algorithm. The resulting imaging quality is as well as the one obtained by the theoretical fitting. The realization of such a case will bring this technique closer to geostationary satellite imaging illuminated by sunlight.

  8. Dynamic light absorption of biomass burning organic carbon photochemically aged under natural sunlight

    NASA Astrophysics Data System (ADS)

    Zhong, M.; Jang, M.

    2013-08-01

    Wood burning aerosol produced under smoldering conditions was photochemically aged with different relative humidity (RH) and NOx conditions using a 104 m3 dual outdoor chamber under natural sunlight. Light absorption of organic carbon (OC) was measured over the course of photooxidation using a UV-visible spectrometer connected to an integrating sphere. At high RH, the color decayed rapidly. NOx slightly prolonged the color of wood smoke, suggesting that NOx promotes the formation of chromophores via secondary processes. Overall, the mass absorption cross-section (integrated between 280 nm and 600 nm) of OC increased by 11-54% (except high RH) in the morning and then gradually decreased by 19-68% in the afternoon. This dynamic change in light absorption of wood burning OC can be explained by two mechanisms: chromophore formation and sunlight bleaching. To investigate the effect of chemical transformation on light absorption, wood smoke particles were characterized using various spectrometers. The intensity of fluorescence, which is mainly related to polycyclic aromatic hydrocarbons (PAHs), rapidly decreased with time indicating the potential bleaching of PAHs. A decline of levoglucosan concentrations evinced the change of POA with time. The aerosol water content measured by Fourier transform infrared spectroscopy showed that wood burning aerosol became less hygroscopic as photooxidation proceeded. A similar trend in light absorption changes has been observed in ambient smoke aerosol originating from the 2012 County Line Wildfire in Florida. We conclude that the biomass burning OC becomes less light absorbing after 8-9 h sunlight exposure compared to fresh wood burning OC.

  9. Dynamic light absorption of biomass-burning organic carbon photochemically aged under natural sunlight

    NASA Astrophysics Data System (ADS)

    Zhong, M.; Jang, M.

    2014-02-01

    Wood-burning aerosol produced under smoldering conditions was photochemically aged with different relative humidity (RH) and NOx conditions using a 104 m3 dual outdoor chamber under natural sunlight. Light absorption of organic carbon (OC) was measured over the course of photooxidation using a UV-visible spectrometer connected to an integrating sphere. At high RH, the color decayed rapidly. NOx slightly prolonged the color of wood smoke, suggesting that NOx promotes the formation of chromophores via secondary processes. Overall, the mass absorption cross section (integrated between 280 and 600 nm) of OC increased by 11-54% (except high RH) in the morning and then gradually decreased by 19-68% in the afternoon. This dynamic change in light absorption of wood-burning OC can be explained by two mechanisms: chromophore formation and sunlight bleaching. To investigate the effect of chemical transformation on light absorption, wood smoke particles were characterized using various spectrometers. The intensity of fluorescence, which is mainly related to polycyclic aromatic hydrocarbons (PAHs), rapidly decreased with time, indicating the potential bleaching of PAHs. A decline of levoglucosan concentrations evinced the change of primary organic aerosol with time. The aerosol water content measured by Fourier transform infrared spectroscopy showed that wood-burning aerosol became less hygroscopic as photooxidation proceeded. A similar trend in light absorption changes has been observed in ambient smoke aerosol originating from the 2012 County Line wildfire in Florida. We conclude that the biomass-burning OC becomes less light absorbing after 8-9 h sunlight exposure compared to fresh wood-burning OC.

  10. The Impact of High-Turbidity Water's Seasonal and Decadal Variations on Offshore Phytoplankton and Nutrients Dynamics around The Changjiang Estuary

    NASA Astrophysics Data System (ADS)

    Ge, J.; Torres, R.; Chen, C.; Bellerby, R. G. J.

    2017-12-01

    The Changjiang Estuary is characterized as strong river discharge into the inner shelf of the East China Sea with abundant sediment load, producing significant high-turbidity water coverage from river mouth to deep region. The growth of offshore phytoplankton is dynamically controlled by river flushed low-salinity and high-turbidity water, and salter water from inner shelf of East China Sea. During last decade, the sediment and nutrients from the Changjiang River has significantly changed, which lead to the variation of offshore phytoplankton dynamics. The variations of sediment, nutrients, and their influenced phytoplankton has been simulated through a comprehensive modeling system, which integrated a multi-scale current-wave-sediment FVCOM model and generic marine biogeochemistry and ecosystem ERSEM model through The Framework for Aquatic Biogeochemical Models (FABM). This model system has successfully revealed the seasonal and decadal variations of sediment, nutrients transport around the inner shelf of the East China Sea. The spring and autumn peaks of phytoplankton growth were correctly captured by simulation. The modeling results, as well as MODIS and GOCI remote sensing, shows a strong sediment decreasing from northern to southern region, which creates different patterns of Chlorophyll-a distribution and seasonal variations. These results indicate the high-turbidity water in northern region strongly influenced the light attenuation in the water column and limits the phytoplankton growth in this relatively higher-nutrient area, especially in the wintertime. The relatively low-turbidity southern region has significant productivity of phytoplankton, even during low-temperature winter. The phytoplankton growth increased in the northern region from 2005 to 2010, with the increase of the nutrient load during this period. Then it became a decreasing trend after 2010.

  11. Study on shrimp waste water and vermicompost as a nutrient source for bell peppers

    USDA-ARS?s Scientific Manuscript database

    The aquaculture industry generates significant nutrient-rich wastewater that is released into streams and rivers causing environmental concern. The objective of this controlled environment study was to evaluate the effect of waste shrimp water (SW), vermicompost (VC), at rates of 10%, 20%, 40%, and ...

  12. Short-term effect of nutrient availability and rainfall distribution on biomass production and leaf nutrient content of savanna tree species.

    PubMed

    Barbosa, Eduardo R M; Tomlinson, Kyle W; Carvalheiro, Luísa G; Kirkman, Kevin; de Bie, Steven; Prins, Herbert H T; van Langevelde, Frank

    2014-01-01

    Changes in land use may lead to increased soil nutrient levels in many ecosystems (e.g. due to intensification of agricultural fertilizer use). Plant species differ widely in their response to differences in soil nutrients, and for savannas it is uncertain how this nutrient enrichment will affect plant community dynamics. We set up a large controlled short-term experiment in a semi-arid savanna to test how water supply (even water supply vs. natural rainfall) and nutrient availability (no fertilisation vs. fertilisation) affects seedlings' above-ground biomass production and leaf-nutrient concentrations (N, P and K) of broad-leafed and fine-leafed tree species. Contrary to expectations, neither changes in water supply nor changes in soil nutrient level affected biomass production of the studied species. By contrast, leaf-nutrient concentration did change significantly. Under regular water supply, soil nutrient addition increased the leaf phosphorus concentration of both fine-leafed and broad-leafed species. However, under uneven water supply, leaf nitrogen and phosphorus concentration declined with soil nutrient supply, this effect being more accentuated in broad-leafed species. Leaf potassium concentration of broad-leafed species was lower when growing under constant water supply, especially when no NPK fertilizer was applied. We found that changes in environmental factors can affect leaf quality, indicating a potential interactive effect between land-use changes and environmental changes on savanna vegetation: under more uneven rainfall patterns within the growing season, leaf quality of tree seedlings for a number of species can change as a response to changes in nutrient levels, even if overall plant biomass does not change. Such changes might affect herbivore pressure on trees and thus savanna plant community dynamics. Although longer term experiments would be essential to test such potential effects of eutrophication via changes in leaf nutrient concentration

  13. Sunlight supply and gas exchange systems in microalgal bioreactor

    NASA Technical Reports Server (NTRS)

    Mori, K.; Ohya, H.; Matsumoto, K.; Furune, H.

    1987-01-01

    The bioreactor with sunlight supply system and gas exchange systems presented has proved feasible in ground tests and shows much promise for space use as a closed ecological life support system device. The chief conclusions concerning the specification of total system needed for a life support system for a man in a space station are the following: (1) Sunlight supply system - compactness and low electrical consumption; (2) Bioreactor system - high density and growth rate of chlorella; and (3) Gas exchange system - enough for O2 production and CO2 assimilation.

  14. Effect of exposure to sunlight and phosphorus-limitation on bacterial degradation of coloured dissolved organic matter (CDOM) in freshwater.

    PubMed

    Kragh, Theis; Søndergaard, Morten; Tranvik, Lars

    2008-05-01

    This study reports on the interacting effect of photochemical conditioning of dissolved organic matter and inorganic phosphorus on the metabolic activity of bacteria in freshwater. Batch cultures with lake-water bacteria and dissolved organic carbon (DOC) extracted from a humic boreal river were arranged in an experimental matrix of three levels of exposure to simulated sunlight and three levels of phosphorus concentration. We measured an increase in bacterial biomass, a decrease in DOC and bacterial respiration as CO(2) production and O(2) consumption over 450 h. These measurements were used to calculate bacterial growth efficiency (BGE). Bacterial degradation of DOC increased with increasing exposure to simulated sunlight and availability of phosphorus and no detectable growth occurred on DOC that was not pre-exposed to simulated sunlight. The outcome of photochemical degradation of DOC changed with increasing availability of phosphorus, resulting in an increase in BGE from about 5% to 30%. Thus, the availability of phosphorus has major implications for the quantitative transfer of carbon in microbial food webs.

  15. Effects of Eichhornia crassipes and Ceratophyllum demersum on Soil and Water Environments and Nutrient Removal in Wetland Microcosms.

    PubMed

    Sung, Kijune; Lee, Geun-Joo; Munster, Clyde

    2015-01-01

    Wetland plants are important components that influence the biogeochemistry of wetland ecosystems. Therefore, remediation performance in wetlands can differ depending on the growth forms of plants. In this study, the effects of Eichhornia crassipes (floating plant) and Ceratophyllum demersum (submerged plant) on the wetland soil and water environments were investigated using a microcosm study with simulated hydrology of retention-type wetlands between rainfall events. The C. demersum microcosm (SP) showed the fastest recovery with a diel fluctuation pattern of dissolved oxygen, pH, and oxidation-reduction potential (ORP) from the impacts of nutrient inflow. Moreover, SP exhibited the lowest decrease in sediment ORP, the highest dehydrogenase activity, and more organic forms of nitrogen and phosphorus. E. crassipes microcosms exhibited the lowest water temperature, and efficiently controlled algae. In the presence of plants, the total nitrogen and phosphorus concentrations in water rapidly decreased, and the composition of organic and inorganic nutrient forms was altered along with a decrease in concentration. The results indicate that wetland plants help retain nutrients in the system, but the effects varied based on the wetland plant growth forms.

  16. Railway suicide attempts are associated with amount of sunlight in recent days.

    PubMed

    Kadotani, Hiroshi; Nagai, Yumiko; Sozu, Takashi

    2014-01-01

    To assess the relationship between hours of sunlight and railway suicide attempts, 3-7 days before these attempts. All railway suicide attempts causing railway suspensions or delays of 30 min or more between 2002 and 2006. We used a linear probability model to assess this relationship. This study was conducted at Tokyo, Kanagawa, and Osaka prefectures in Japan. Data were collected from the railway delay incident database of the Japanese Railway Technical Research Institute and public weather database of the Japan Meteorological Agency. About 971 railway suicides attempts occurred between 2002 and 2006 in Tokyo, Kanagawa, and Osaka. Less sunlight in the 7 days leading up to the railway suicide attempts was associated with a higher proportion of attempts (p=0.0243). Sunlight over the 3 days before an attempt had a similar trend (p=0.0888). No difference was found in sunlight hours between the days with (median: 5.6 [IQR: 1.1-8.8]) and without (median: 5.7 [IQR: 1.0-8.9]) railway suicide attempts in the evening. Finally, there was no apparent correlation between the railway suicide attempts and the monthly average sunlight hours of the attempted month or those of a month before. Railway suicides were not the main suicidal methods in Japan, We observed an increased proportion of railway suicide attempts after several days without sunlight. Light exposure (blue light or bright white light) in trains may be useful in reducing railway suicides, especially when consecutive days without sunshine are forecasted. © 2013 Elsevier B.V. All rights reserved.

  17. Siletz River nutrients: Effects of biosolids application

    EPA Science Inventory

    Stream water nutrients were measured in the Siletz River, Oregon, with the goal of comparing dissolved nutrient concentrations, primarily the nitrogenous nutrients nitrate and ammonium, with previously collected data for the Yaquina and Alsea Rivers for the nutrient criteria prog...

  18. Estimated Nutrient Concentrations and Continuous Water-Quality Monitoring in the Eucha-Spavinaw Basin, Northwestern Arkansas and Northeastern Oklahoma, 2004-2007

    USGS Publications Warehouse

    Christensen, Victoria G.; Esralew, Rachel A.; Allen, Monica L.

    2008-01-01

    The Eucha-Spavinaw basin is the source of water for Lake Eucha and Spavinaw Lake, which are part of the water supply for the City of Tulsa. The City of Tulsa has received complaints of taste and odor in the finished drinking water because of deteriorating water quality. The deterioration is largely because of algal growth from the input of nutrients from the Eucha-Spavinaw basin. The U.S. Geological Survey, in cooperation with the City of Tulsa, implemented a continuous, real-time water-quality monitoring program in the Eucha-Spavinaw basin to better understand the source of the nutrient loading. This program included the manual collection of samples analyzed for nutrients and the collection of continuous, in-stream data from water-quality monitors. Continuous water-quality monitors were installed at two existing continuous streamflow-gaging stations - Spavinaw Creek near Colcord, Oklahoma, and Beaty Creek near Jay, Oklahoma, from October 2004 through September 2007. Total nitrogen concentrations for manually collected water samples ranged from 2.08 to 9.66 milligrams per liter for the water samples collected from Spavinaw Creek near Colcord, Oklahoma, and from 0.67 to 5.12 milligrams per liter for manually collected water samples from Beaty Creek near Jay, Oklahoma. Total phosphorus concentrations ranged from 0.04 to 1.5 milligrams per liter for the water samples collected from Spavinaw Creek near Colcord and from 0.028 to 1.0 milligram per liter for the water samples collected from Beaty Creek near Jay. Data from water samples and in-stream monitors at Spavinaw and Beaty Creeks (specific conductance and turbidity) were used to develop linear regression equations relating in-stream water properties to total nitrogen and total phosphorus concentrations. The equations developed for the Spavinaw and Beaty sites are site specific and only valid for the concentration ranges of the explanatory variables used in the analysis. The range in estimated and measured

  19. Sunlight damage to cellular DNA: Focus on oxidatively generated lesions.

    PubMed

    Schuch, André Passaglia; Moreno, Natália Cestari; Schuch, Natielen Jacques; Menck, Carlos Frederico Martins; Garcia, Camila Carrião Machado

    2017-06-01

    The routine and often unavoidable exposure to solar ultraviolet (UV) radiation makes it one of the most significant environmental DNA-damaging agents to which humans are exposed. Sunlight, specifically UVB and UVA, triggers various types of DNA damage. Although sunlight, mainly UVB, is necessary for the production of vitamin D, which is necessary for human health, DNA damage may have several deleterious consequences, such as cell death, mutagenesis, photoaging and cancer. UVA and UVB photons can be directly absorbed not only by DNA, which results in lesions, but also by the chromophores that are present in skin cells. This process leads to the formation of reactive oxygen species, which may indirectly cause DNA damage. Despite many decades of investigation, the discrimination among the consequences of these different types of lesions is not clear. However, human cells have complex systems to avoid the deleterious effects of the reactive species produced by sunlight. These systems include antioxidants, that protect DNA, and mechanisms of DNA damage repair and tolerance. Genetic defects in these mechanisms that have clear harmful effects in the exposed skin are found in several human syndromes. The best known of these is xeroderma pigmentosum (XP), whose patients are defective in the nucleotide excision repair (NER) and translesion synthesis (TLS) pathways. These patients are mainly affected due to UV-induced pyrimidine dimers, but there is growing evidence that XP cells are also defective in the protection against other types of lesions, including oxidized DNA bases. This raises a question regarding the relative roles of the various forms of sunlight-induced DNA damage on skin carcinogenesis and photoaging. Therefore, knowledge of what occurs in XP patients may still bring important contributions to the understanding of the biological impact of sunlight-induced deleterious effects on the skin cells. Copyright © 2017 The Authors. Published by Elsevier Inc. All

  20. Growth characteristics of aquatic macrophytes cultured in nutrient-enriched water. I. Water hyacinth, water lettuce, and pennywort

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reddy, K.R.; DeBusk, W.F.

    Seasonal growth characteristics and biomass yield potential of 3 floating aquatic macrophytes cultured in nutrient nonlimiting conditions were evaluated in central Florida's climatic conditions. Growth cycle (growth curve) of the plants was found to be complete when maximum plant density was reached and no additional increase in growth was recorded. Biomass yield per unit area and time was found to be maximum in the linear phase of the growth curve; plant density in this phase was defined as ''operational plant density,'' a density range in which a biomass production system is operated to obtain the highest possible yields. Biomass yieldsmore » were found to be 106, 72, and 41 t(dry wt) ha/sup -1/yr/sup -1/, respectively, for water hyacinth (Eichhornia crassipes), water lettuce (Pistia stratiotes), and pennywort (Hydrocotyle umbellata). Operational plant density was found to be in the range of 500-2000 g dry wt m/sup -2/ for water hyacinth, 200-700 g dry wt m/sup -2/ for water lettuce, and 250-650 g dry wt/sup -2/ for pennywort. Seasonality was observed in growth rates but not in operational plant density. Specific growth rate (% increase per day) was found to maximum at low plant densities and decreased as the plant density increased. Results show that water hyacinth and water lettuce can be successfully grown for a period of about 10 mo, while pennywort, a cool season plant, can be integrated into water hyacinth/water lettuce biomass production system to obtain high yields in the winter.« less

  1. Growth characteristics of aquatic macrophytes cultured in nutrient-enriched water. I. Water hyacinth, water lettuce, and pennywort

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reddy, K.R.; DeBusk, W.F.

    Seasonal growth characteristics and biomass yield potential of 3 floating aquatic macrophytes cultured in nutrient nonlimiting conditions were evaluated in central Florida's climatic conditions. Growth cycle (growth curve) of the plants was found to be complete when maximum plant density was reached and no additional increase in growth was recorded. Biomass yield per unit area and time was found to be maximum in the linear phase of the growth curve; plant density in this phase was defined as operational plant density, a density range in which a biomass production system is operated to obtain the highest possible yields. Biomass yieldsmore » were found to be 106, 72, and 41 t (dry wt) ha/sup -1/ yr/sup -1/, respectively, for water hyacinth (Eichhornia crassipes), water lettuce (Pistia stratiotes), and pennywort (Hydrocotyle umbellata). Operational plant density was found to be in the range of 500-2,000 g dry wt m/sup -2/ for water hyacinth, 200-700 g dry wt m/sup -2/ for water lettuce, and 250-650 g dry wt m/sup -2/ for pennywort. Seasonality was observed in growth rates but not in operational plant density. Specific growth rate (% increase per day) was found to maximum at low plant densities and decreased as the plant density increased. Results show that water hyacinth and water lettuce can be successfully grown for a period of about 10 mo, while pennywort, a cool season plant, can be integrated into water hyacinth/water lettuce biomass production system to obtain high yields in the winter.« less

  2. Trends in nutrients

    USGS Publications Warehouse

    Heathwaite, A.L.; Johnes, P.J.; Peters, N.E.

    1996-01-01

    The roles of nitrogen (N) and phosphorus (P) as key nutrients determining the trophic status of water bodies are examined, and evidence reviewed for trends in concentrations of N and P species which occur in freshwaters, primarily in northern temperate environments. Data are reported for water bodies undergoing eutrophication and acidification, especially water bodies receiving increased nitrogen inputs through the atmospheric deposition of nitrogen oxides (NOx). Nutrient loading on groundwaters and surface freshwaters is assessed with respect to causes and rates of (change, relative rates of change for N and P, and implications of change for the future management of lakes, rivers and groundwaters. In particular, the nature and emphasis of studies for N species and P fractions in lakes versus rivers and groundwaters are contrasted. This review paper primarily focuses on results from North America and Europe, particularly for the UK where a wide range of data sets exists. Few nutrient loading data have been published on water bodies in less developed countries; however, some of the available data are presented to provide a global perspective. In general, N and P concentrations have increased dramatically (>20 times background concentrations) in many areas and causes vary considerably, ranging from urbanization to changes in agricultural practices.

  3. Effects of sunlight exclusion on the profiles of monoterpene biosynthesis and accumulation in grape exocarp and mesocarp.

    PubMed

    Zhang, Erpeng; Chai, Fengmei; Zhang, Haohao; Li, Shaohua; Liang, Zhenchang; Fan, Peige

    2017-12-15

    Terpenes are important aroma compounds in table Muscat grape and wine, and their content in the berry can be affected by sunlight. The effects of sunlight exclusion on monoterpene profiles and relevant gene expression profiles in the exocarp and mesocarp of table Muscat grape 'Jingxiangyu' at different development stages were thoroughly surveyed by bagging pre-veraison clusters in special opaque boxes. The responses of monoterpenes to sunlight treatments varied in three types, representatively linalool, ocimene and geraniol. Linalool was the most sensitive compound to sunlight, whose biosynthesis was severely inhibited by sunlight exclusion and then was elevated by re-exposure. Ocimene and glycosylated geraniol showed a certain suppressive and stimulative responses to sunlight exclusion respectively. Further transcription analysis revealed that VvPNLinNer1, VvCSbOci, VvGT7 and VvGT14 genes were mainly responsible for monoterpene accumulation and sensitivity to sunlight. VvDXS2 and VvDXR genes were partially related to the differential accumulation of total terpenes under different sunlight treatments. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Photochemical alteration of dissolved organic matter and the subsequent effects on bacterial carbon cycling and diversity.

    PubMed

    Lønborg, Christian; Nieto-Cid, Mar; Hernando-Morales, Victor; Hernández-Ruiz, Marta; Teira, Eva; Álvarez-Salgado, Xosé Antón

    2016-05-01

    The impact of solar radiation on dissolved organic matter (DOM) derived from 3 different sources (seawater, eelgrass leaves and river water) and the effect on the bacterial carbon cycling and diversity were investigated. Seawater with DOM from the sources was first either kept in the dark or exposed to sunlight (4 days), after which a bacterial inoculum was added and incubated for 4 additional days. Sunlight exposure reduced the coloured DOM and carbon signals, which was followed by a production of inorganic nutrients. Bacterial carbon cycling was higher in the dark compared with the light treatment in seawater and river samples, while higher levels were found in the sunlight-exposed eelgrass experiment. Sunlight pre-exposure stimulated the bacterial growth efficiency in the seawater experiments, while no impact was found in the other experiments. We suggest that these responses are connected to differences in substrate composition and the production of free radicals. The bacterial community that developed in the dark and sunlight pre-treated samples differed in the seawater and river experiments. Our findings suggest that impact of sunlight exposure on the bacterial carbon transfer and diversity depends on the DOM source and on the sunlight-induced production of inorganic nutrients. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  5. Urbanization Changes the Temporal Dynamics of Nutrients and Water Chemistry

    NASA Astrophysics Data System (ADS)

    Steele, M.; Badgley, B.

    2017-12-01

    Recent studies find that urban development alters the seasonal dynamics of nutrient concentrations, where the highest concentrations of nitrogen occurred during the winter in urban watersheds, rather than the summer. However, the effects of urbanization on the seasonal concentrations of other nutrients and chemical components is unknown. Therefore, to determine how urbanization changes the seasonal dynamics, once a week we measured concentrations of dissolved organic carbon (DOC), nutrients (NO3, DON, TN, PO4), base cations (Ca, Mg, Na, K), anions (F, Cl, SO4), pH, sediment, temperature, conductivity, and dissolved oxygen (DO) of nine urban, agricultural, and minimally developed watersheds in southwest Virginia, USA. We found that urbanization disrupted the seasonal dynamics of all metrics, except DON, PO4, Ca, sediment, and DO, where some shifted to high concentrations during the winter (Cl, conductivity), highs during late winter or spring (DOC, Na), a season low (TN, SO4, NO3) or high (NH4) during the summer, or remained more constant throughout the year compared to the reference watersheds (Mg, K, pH). The complex changes in seasonal dynamics coincide with a decoupling of common correlations between constituents; for example, DO and NO3 are negatively correlated in reference watersheds (NO3 increases, DO decreases), but positively correlated in urban watersheds. These results suggest that as watersheds become more intensely developed, the influence of natural drivers like temperature and vegetation become steadily overcome by the influence of urban drivers like deicing salts and wastewater leakage, which exert increasing control of seasonal water quality and aquatic habitat.

  6. Water: a neglected nutrient in the young child? A South African perspective.

    PubMed

    Bourne, Lesley T; Harmse, Berna; Temple, Norman

    2007-10-01

    Water is considered an essential nutrient because the body cannot produce enough water itself, by metabolism of food, to fulfil its need. When the quantity or quality of water is inadequate, health problems result, most notably dehydration and diarrhoea. As a result of contaminated water and poor hygiene, related infections are still a serious problem. Indeed, in the South African setting water availability and sanitation are critical issues because of the prevalence of childhood diarrhoea and also the HIV/AIDS crisis. Though considerable efforts have been made to improve the water and sanitation problems in South Africa - especially with regard to water supply infrastructure - there is still room for much improvement. Water is a healthy alternative to calorie-dense, non-nutritive beverages, such as artificial fruit drinks and soda. The latter should be avoided as they contribute little other than energy and may contribute to overweight and obesity. Also, they displace more nutritious foods from the child's diet. Consumption of fruit juice should also be limited. These issues highlight the need for a specific guideline relating to water intake in the paediatric food-based dietary guidelines.

  7. Hydrology, water quality, and nutrient loads to the Bauman Park Lake, Cherry Valley, Winnebago County, Illinois, May 1996-April 1997

    USGS Publications Warehouse

    Kay, Robert T.; Trugestaad, Aaron

    1998-01-01

    The Bauman Park Lake occupies a former sand and gravel quarry in the Village of Cherry Valley, Illinois. The lake is eutrophic, and nuisance growths of algae and aquatic macrophytes are supported by nutrients (nitrogen and phosphorus) that are derived primarily from ground-water inflow, the main source of water for the lake. The lake has an average depth of about 18 feet, a maximum depth of about 28 feet, and a volume of 466 acre-feet at a stage of about 717 feet above sea level. The lake also is subject to thermal stratification, and although most of the lake is well oxidized, nearly anoxic conditions were present at the lake bottom during part of the summer of 1996. 4,648 pounds of nitrogen compounds were added to the Bauman Park Lake from May 1996 through April 1997. Phosphorus compounds were derived primarily from inflow from ground water (68.7 percent), sediments derived from shoreline erosion (15.6 percent), internal regeneration (11.7 percent), waterfowl excrement (1.6 percent), direct precipitation and overland runoff (1.2 percent), and particulate matter deposited from the atmosphere (1.2 percent). Nitrogen compounds were derived from inflow from ground water (62.1 percent), internal regeneration (19.6 percent), direct precipitation and overland runoff (10.1 percent), particulate matter deposited from the atmosphere (3.5 percent), sediments derived from shoreline erosion (4.4 percent), and waterfowl excrement (0.3 percent). About 13 pounds of phosphorus and 318 pounds of nitrogen compounds flow out of the lake to ground water. About 28 pounds of nitrogen is removed by denitrification. Algae and aquatic macrophytes utilize nitrate, nitrite, ammonia, and dissolved phosphorus. The availability of dissolved phosphorus in the lake water controls algal growth. Uptake of the nutrients, by aquatic macrophytes and algae, temporarily removes nutrients from the water column but not from the lake basin. Because the amount of nutrients entering the lake greatly exceeds

  8. Nutrient elements in large Chinese estuaries

    NASA Astrophysics Data System (ADS)

    Zhang, Jing

    1996-07-01

    Based on comprehensive observations since 1983, this study summarizes major features of nutrient elements (nitrogen, phosphorus and silicon) in large Chinese river/estuary systems. Elevated nutrient element levels were observed in Chinese rivers, when compared to large and less disturbed aquatic systems (e.g. the Amazon, Zaire and Orinoco). Data from this study are similar to those obtained from the polluted and/or eutrophic rivers in Europe and North America (e.g. the Rhóne and Loire). Nutrient elements may have either conservative or active distributions, or both, in the mixing zone, depending on the element and the estuary. For example, non-conservative behaviors were observed in the upper estuary, where nutrient elements may be remobilized due to the strong desorption and variations of the fresh water end-member, but conservative distributions were found afterwards in the lower estuary. Outside the riverine effluent plumes, nutrient elements may be depleted in surface waters relative to elevated bioproduction, whereas the regeneration with respect to decomposition of organic material and/or nitrification/denitrification offshore, may sustain high levels of nutrient elements in near-bottom waters. Laboratory experiment data generally compares well with field observations. The high fluxes and area] yields of nutrient elements from large Chinese rivers, indicate the extensive use of chemical fertilizers and domestic waste drainage over watersheds in China.

  9. Quality of water and bottom sediments, and nutrient and dissolved-solids loads in the Apopka-Beauclair Canal, Lake County, Florida, 1986-90

    USGS Publications Warehouse

    Schiffer, D.M.

    1994-01-01

    Nutrient-rich water enters Lake Beauclair and other lakes downstream from Lake Apopka in the Ocklawaha River chain of lakes in central Florida. Two sources of the nutrient-rich water are Lake Apopka outflow and drainage from farming operations adjacent to the Apopka-Beauclair Canal. Two flow and water- quality monitoring sites were established to measure nutrient and dissolved-solids loads at the outflow from lake Apopka and at a control structure on the Apopka-Beauclair Canal downstream from farming activities. Samples were collected biweekly for analysis of nutrients and monthly for analysis of major ions for 4 years. Most of the nutrient load transported through the lock and dam on the Apopka-Beauclair Canal was transported during periods of high discharge. In April 1987, when discharges were as high as 589 cubic feet per second, loads transported through the lock and dam accounted for 59 percent of the ammonia-plus- organic nitrogen load, 61 percent of the total nitrogen load, and 59 percent of the phosphorus load transported during the 1987 water year. Constituent concentrations in annual bottom sediment samples from the canal indicated that most of the constituent load is not being transported down- stream. An alternative approach was derived for determining the relative constituent load from farm input along the canal: Load computations using this approach indicated that, with the exception of phosphorus, nutrient and dissolved-solids loads due to farm activity along the canal account for 10 percent or less of the total load at the Apopka-Beauclair canal lock and dam. (USGS)

  10. Progress and limitations on quantifying nutrient and carbon loading to coastal waters

    NASA Astrophysics Data System (ADS)

    Stets, E.; Oelsner, G. P.; Stackpoole, S. M.

    2017-12-01

    Riverine export of nutrients and carbon to estuarine and coastal waters are important determinants of coastal ecosystem health and provide necessary insight into global biogeochemical cycles. Quantification of coastal solute loads typically relies upon modeling based on observations of concentration and discharge from selected rivers draining to the coast. Most large-scale river export models require unidirectional flow and thus are referenced to monitoring locations at the head of tide, which can be located far inland. As a result, the contributions of the coastal plain, tidal wetlands, and concentrated coastal development are often poorly represented in regional and continental-scale estimates of solute delivery to coastal waters. However, site-specific studies have found that these areas are disproportionately active in terms of nutrient and carbon export. Modeling efforts to upscale fluxes from these areas, while not common, also suggest an outsized importance to coastal flux estimates. This presentation will focus on illustrating how the problem of under-representation of near-shore environments impacts large-scale coastal flux estimates in the context of recent regional and continental-scale assessments. Alternate approaches to capturing the influence of the near-coastal terrestrial inputs including recent data aggregation efforts and modeling approaches will be discussed.

  11. [Effects of different water and fertilizer supply on cucumber soil nutrient content, enzyme activity, and microbial diversity].

    PubMed

    Wei, Ze-Xiu; Liang, Yin-Li; Inoue, Mitsuhiro; Zhou, Mao-Juan; Huang, Mao-Lin; Gu, Jian-Feng; Wu, Yan

    2009-07-01

    With cucumber (Cucumis sativus L.) variety Jinyou 1 as test material, a greenhouse experiment was conducted to study the effects of different water and fertilizer supply on the cucumber soil nutrient content, enzyme activity, and microbial diversity. Three water regimes (50%-60%, 70%-80%, and 90%-100% soil relative moisture content) and two fertilization practices (600 kg N x hm(-2) + 420 kg P2O5 x hm(-2) and 420 kg N x hm(-2) + 294 kg P2O5 x hm(-2)) were designed. The increase of water and fertilizer supply benefited the increase of soil available P content and sucrase activity. Increasing fertilization rate increased soil NH(4+)-N content but decreased soil protease activity, and increasing soil relative moisture content decreased the soil NH(4+)-N content and urease activity. Soil microbial diversity had no significant correlations with soil nutrient contents, but significantly positively correlated with soil urease activity and negatively correlated with soil sucrase activity. Among the treatments, the treatment 70%-80% soil relative moisture content + 600 kg N x hm(-2) and 420 kg P2O5 x hm(-2) had the highest soil nutrient contents, soil urease, sucrase, and phosphatase activities, and soil microbial diversity and evenness, being the best in soil potential productivity.

  12. Nutrient Enrichment Increases Mortality of Mangroves

    PubMed Central

    Lovelock, Catherine E.; Ball, Marilyn C.; Martin, Katherine C.; C. Feller, Ilka

    2009-01-01

    Nutrient enrichment of the coastal zone places intense pressure on marine communities. Previous studies have shown that growth of intertidal mangrove forests is accelerated with enhanced nutrient availability. However, nutrient enrichment favours growth of shoots relative to roots, thus enhancing growth rates but increasing vulnerability to environmental stresses that adversely affect plant water relations. Two such stresses are high salinity and low humidity, both of which require greater investment in roots to meet the demands for water by the shoots. Here we present data from a global network of sites that documents enhanced mortality of mangroves with experimental nutrient enrichment at sites where high sediment salinity was coincident with low rainfall and low humidity. Thus the benefits of increased mangrove growth in response to coastal eutrophication is offset by the costs of decreased resilience due to mortality during drought, with mortality increasing with soil water salinity along climatic gradients. PMID:19440554

  13. Nutrient enrichment increases mortality of mangroves.

    PubMed

    Lovelock, Catherine E; Ball, Marilyn C; Martin, Katherine C; C Feller, Ilka

    2009-01-01

    Nutrient enrichment of the coastal zone places intense pressure on marine communities. Previous studies have shown that growth of intertidal mangrove forests is accelerated with enhanced nutrient availability. However, nutrient enrichment favours growth of shoots relative to roots, thus enhancing growth rates but increasing vulnerability to environmental stresses that adversely affect plant water relations. Two such stresses are high salinity and low humidity, both of which require greater investment in roots to meet the demands for water by the shoots. Here we present data from a global network of sites that documents enhanced mortality of mangroves with experimental nutrient enrichment at sites where high sediment salinity was coincident with low rainfall and low humidity. Thus the benefits of increased mangrove growth in response to coastal eutrophication is offset by the costs of decreased resilience due to mortality during drought, with mortality increasing with soil water salinity along climatic gradients.

  14. Influence of iron availability on nutrient consumption ratio of diatoms in oceanic waters

    NASA Astrophysics Data System (ADS)

    Takeda, Shigenobu

    1998-06-01

    The major nutrients (nitrate, phosphate and silicate) needed for phytoplankton growth are abundant in the surface waters of the subarctic Pacific, equatorial Pacific and Southern oceans, but this growth is limited by the availability of iron. Under iron-deficient conditions, phytoplankton exhibit reduced uptake of nitrate and lower cellular levels of carbon, nitrogen and phosphorus. Here I describe seawater and culture experiments which show that iron limitation can also affect the ratio of consumed silicate to nitrate and phosphate. In iron-limited waters from all three of the aforementioned environments, addition of iron to phytoplankton assemblages in incubation bottles halved the silicate:nitrate and silicate:phosphate consumption ratios, in spite of the preferential growth of diatoms (silica-shelled phytoplankton). The nutrient consumption ratios of the phytoplankton assemblage from the Southern Ocean were similar to those of an iron-deficient laboratory culture of Antarctic diatoms, which exhibit increased cellular silicon or decreased cellular nitrogen and phosphorus in response to iron limitation. Iron limitation therefore increases the export of biogenic silicon, relative to nitrogen and phosphorus, from the surface to deeper waters. These findings suggest how the sedimentary records of carbon and silicon deposition in the glacial Southern Ocean can be consistent with the idea that changes in productivity, and thus in drawdown of atmospheric CO2, during the last glaciation were stimulated by changes in iron inputs from atmospheric dust.

  15. Setting nutrient thresholds to support an ecological assessment based on nutrient enrichment, potential primary production and undesirable disturbance.

    PubMed

    Devlin, Michelle; Painting, Suzanne; Best, Mike

    2007-01-01

    The EU Water Framework Directive recognises that ecological status is supported by the prevailing physico-chemical conditions in each water body. This paper describes an approach to providing guidance on setting thresholds for nutrients taking account of the biological response to nutrient enrichment evident in different types of water. Indices of pressure, state and impact are used to achieve a robust nutrient (nitrogen) threshold by considering each individual index relative to a defined standard, scale or threshold. These indices include winter nitrogen concentrations relative to a predetermined reference value; the potential of the waterbody to support phytoplankton growth (estimated as primary production); and detection of an undesirable disturbance (measured as dissolved oxygen). Proposed reference values are based on a combination of historical records, offshore (limited human influence) nutrient concentrations, literature values and modelled data. Statistical confidence is based on a number of attributes, including distance of confidence limits away from a reference threshold and how well the model is populated with real data. This evidence based approach ensures that nutrient thresholds are based on knowledge of real and measurable biological responses in transitional and coastal waters.

  16. Effects of water addition to total mixed ration on water intake, nutrient digestibility, wool cortisol and blood indices in Corriedale ewes.

    PubMed

    Nejad, Jalil Ghassemi; Kim, Byong-Wan; Lee, Bae-Hun; Kim, Ji-Yung; Sung, Kyung-Il

    2017-10-01

    The objective of this study was to determine the effect of adding water to total mixed ration (TMR) on fresh water intake, nutrient digestibility, wool cortisol, and blood indices in Corriedale ewes under hot and humid conditions. Nine non-pregnant Corriedale ewes (ave. body weight = 41±3.5 kg) were individually fed diets based on maintenance requirements in metabolic crates. Ewes were assigned to three treatment groups according to a triplicate 3×3 Latin Square design for 3 periods of 21 days duration each (9 ewes per treatment, 27 replications). Treatments were TMR (crude protein [CP] = 16.1, total digestible nutrients = 69.1%) moisture levels for 40%, 50%, and 60%. No differences were found in body weight gain among all treatment groups (p>0.05). Nitrogen balance including digestible N, retained N, and urinary and fecal N showed no change among the treatment groups (p>0.05). Fresh water intake was the lower in 50% TMR moisture group than in the other groups (p<0.05). Other than ether extract which was higher in 60% TMR moisture group (p<0.05) the differences among nutrient digestibilities including CP, organic matter, dry matter, neutral detergent fiber, acid detergent fiber, and non-fiber carbohydrate were not significant (p>0.05). No significant difference was observed for serum protein, blood urea nitrogen, glucose, and triglyceride among the treatment groups (p>0.05). Wool and blood cortisol were not different among the treatment groups (p>0.05). Blood hematology including red blood cell, white blood cells, hemoglobin, hematocrit, basophils, and eosinophils were not different among the treatment groups (p>0.05). It is concluded that TMR moisture at 40%, 50%, and 60% had no effects on N balance parameters, and nutrient digestibilities except for the ether extract under hot and humid conditions. Additionally there were no effects on stress conditions include wool cortisol, as well as blood cortisol levels of ewes.

  17. Effect of nutrients on the biodegradation of tributyltin (TBT) by alginate immobilized microalga, Chlorella vulgaris, in natural river water.

    PubMed

    Jin, Jing; Yang, Lihua; Chan, Sidney M N; Luan, Tiangang; Li, Yan; Tam, Nora F Y

    2011-01-30

    The removal and degradation of tributyltin (TBT) by alginate immobilized Chlorella vulgaris has been evidenced in our previously published work. The present study was further to investigate the effect of spiked nutrient concentrations on the TBT removal capacity and degradation in the same alginate immobilized C. vulgaris. During the 14-d experiment, compared to the control (natural river water), the spiked nutrient groups (50% or 100% nutrients of the commercial Bristol medium as the reference, marked as 1/2N or 1N) showed more rapid cell proliferation of microalgae and higher TBT removal rate. Moreover, significantly more TBT was adsorbed onto the alginate matrix, but less TBT was taken up by the algal cells of the nutrient groups than that of the control. Mass balance data showed that TBT was lost as inorganic tin in the highest degree in 1N group, followed by 1/2N group and the least was in the control, but the relative abundance of the intermediate products of debutylation (dibutyltin and monobutyltin) were comparable among three groups. In conclusion, the addition of nutrients in contaminated water stimulated the growth and physiological activity of C. vulgaris immobilized in alginate beads and improved its TBT degradation efficiency. Copyright © 2010 Elsevier B.V. All rights reserved.

  18. Nutrient loading and selected water-quality and biological characteristics of Dickinson Bayou near Houston, Texas, 1995-97

    USGS Publications Warehouse

    East, Jeffery W.; Paul, Edna M.; Porter, Stephen D.

    1998-01-01

    Algal samples were collected at seven stations and were analyzed for periphyton identification and enumeration, and chlorophyll a and chlorophyll b concentrations. The large relative abundance of soil algae at stations in the middle of the watershed likely indicates the cumulative effects on water quality of agricultural nonpoint sources. Farther downstream near the State Highway 3 bridge, and downstream of three major tributary inflows, the increase in abundance of soil algae to a larger-than-expected level might reflect water-quality influences from predominantly urban nonpoint sources in the drainage basins of the three major tributary inflows. Nutrient concentrations do not appear to limit algal production in the upper (non-tidal) reach of Dickinson Bayou; but nutrient concentrations could have been limiting benthicalgal production in the lower (tidal) reach of the bayou during the time of the synoptic survey. If nitrogen is the limiting resource for algal productivity in the tidal reach of Dickinson Bayou, eutrophication of the system could be (at least partially) mitigated if nonpoint-source nutrient loads into the Bayou were reduced. 

  19. Photochemical Transformation of Graphene Oxide in Sunlight

    EPA Science Inventory

    Graphene oxide (GO) is a graphene derivative that is more easily manufactured in large scale and used to synthesize reduced graphene oxide (rGO) with properties analogous to graphene. In this study, we investigate the photochemical fate of GO under sunlight conditions. The resu...

  20. Photodegradation of sulfathiazole under simulated sunlight: Kinetics, photo-induced structural rearrangement, and antimicrobial activities of photoproducts.

    PubMed

    Niu, Xi-Zhi; Glady-Croué, Julie; Croué, Jean-Philippe

    2017-11-01

    Photolysis is a core natural process impacting the fate of some sulfonamide antibiotics in sunlit waters. In this study, sunlight-induced phototransformation of sulfathiazole was investigated. A photolytic quantum yield of 0.079 was obtained in buffered water (pH = 8.0). Different natural organic matter isolates inhibited the photolysis of sulfathiazole by light screening effect. A kinetic model was developed to predict the photodegradation rate of sulfathiazole using the light screening correction factor of the water matrix in the wavelength range of 300-350 nm. An isomeric photoproduct of sulfathiazole with a longer retention time was observed on liquid chromatography. Based on its MS/MS spectra and absorption characteristics, the isomer was postulated as 2-imino-3-(p-aminobenzenesulfinyl-oxy)-thiazole. A reaction mechanism for the photo-cleavage and photo-induced structural rearrangement was proposed. The formation mechanism of the isomer was supported by photochemical experiments spiking synthetic 2-aminothiazole; while the formation kinetics were treated with a partly-diffusion-controlled model. The three identified products showed significantly enhanced photo-stability. Antimicrobial assay of irradiated sulfathiazole solutions with Escherichia coli indicated little antimicrobial potency ascribed to photoproducts. This study demonstrates the efficacy of sunlight in rapidly degrading sulfathiazole at a predictable rate, leading to photoproducts of low antimicrobial potency. The mass spectrometry and mechanistic work described here are new insights into the photochemistry of sulfonamides. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Porous graphitic carbon nitride synthesized via direct polymerization of urea for efficient sunlight-driven photocatalytic hydrogen production

    NASA Astrophysics Data System (ADS)

    Zhang, Yuewei; Liu, Jinghai; Wu, Guan; Chen, Wei

    2012-08-01

    Energy captured directly from sunlight provides an attractive approach towards fulfilling the need for green energy resources on the terawatt scale with minimal environmental impact. Collecting and storing solar energy into fuel through photocatalyzed water splitting to generate hydrogen in a cost-effective way is desirable. To achieve this goal, low cost and environmentally benign urea was used to synthesize the metal-free photocatalyst graphitic carbon nitride (g-C3N4). A porous structure is achieved via one-step polymerization of the single precursor. The porous structure with increased BET surface area and pore volume shows a much higher hydrogen production rate under simulated sunlight irradiation than thiourea-derived and dicyanamide-derived g-C3N4. The presence of an oxygen atom is presumed to play a key role in adjusting the textural properties. Further improvement of the photocatalytic function can be expected with after-treatment due to its rich chemistry in functionalization.Energy captured directly from sunlight provides an attractive approach towards fulfilling the need for green energy resources on the terawatt scale with minimal environmental impact. Collecting and storing solar energy into fuel through photocatalyzed water splitting to generate hydrogen in a cost-effective way is desirable. To achieve this goal, low cost and environmentally benign urea was used to synthesize the metal-free photocatalyst graphitic carbon nitride (g-C3N4). A porous structure is achieved via one-step polymerization of the single precursor. The porous structure with increased BET surface area and pore volume shows a much higher hydrogen production rate under simulated sunlight irradiation than thiourea-derived and dicyanamide-derived g-C3N4. The presence of an oxygen atom is presumed to play a key role in adjusting the textural properties. Further improvement of the photocatalytic function can be expected with after-treatment due to its rich chemistry in

  2. Effects of nutrient and water restriction on thermal tolerance: A test of mechanisms and hypotheses.

    PubMed

    Mitchell, Katherine A; Boardman, Leigh; Clusella-Trullas, Susana; Terblanche, John S

    2017-10-01

    Nutritional deprivation or desiccation can influence thermal tolerance by impacting the insects' ability to evaporatively cool, maintain cell membrane integrity and conduct protective or repair processes. Recovery from chilling is also linked to the re-establishment of iono- and osmo-regulatory homeostasis. Here, using Mediterranean fruit fly (Ceratitis capitata, Diptera: Tephritidae), we manipulated water and nutrient availability to test the mechanistic expectation that changes in whole organism lipid and water content can elicit variation in cold or heat tolerance (scored as chill coma recovery time and heat knockdown time). We measured body condition (body water and lipid content) as well as heat shock protein 70 gene (hsp70) and protein (HSP70) levels. A significant reduction in body water content with water restriction did not translate into differences in chill coma recovery. When nutrient restriction was coupled with water deprivation, this resulted in a significant reduction (-54%) of heat knockdown time in females but male flies were unaffected. There was no evidence for an hsp70 or HSP70 response under any of the stress treatments and therefore no correlation with heat or cold tolerance. Heat hardening decreased all hsp levels. Therefore, although body water and total body lipid content differed between the treatment groups, the contribution of these factors to thermal tolerance was inconsistent with mechanistic expectations in heat knockdown time and insignificant for chill coma recovery. These results therefore highlight that the effects of resource restriction on thermal limits in insects are mechanistically more complex than previous models of stress resistance have suggested. Copyright © 2017 Elsevier Inc. All rights reserved.

  3. Roles of sunlight and natural ventilation for controlling infection: historical and current perspectives.

    PubMed

    Hobday, R A; Dancer, S J

    2013-08-01

    Infections caught in buildings are a major global cause of sickness and mortality. Understanding how infections spread is pivotal to public health yet current knowledge of indoor transmission remains poor. To review the roles of natural ventilation and sunlight for controlling infection within healthcare environments. Comprehensive literature search was performed, using electronic and library databases to retrieve English language papers combining infection; risk; pathogen; and mention of ventilation; fresh air; and sunlight. Foreign language articles with English translation were included, with no limit imposed on publication date. In the past, hospitals were designed with south-facing glazing, cross-ventilation and high ceilings because fresh air and sunlight were thought to reduce infection risk. Historical and recent studies suggest that natural ventilation offers protection from transmission of airborne pathogens. Particle size, dispersal characteristics and transmission risk require more work to justify infection control practices concerning airborne pathogens. Sunlight boosts resistance to infection, with older studies suggesting potential roles for surface decontamination. Current knowledge of indoor transmission of pathogens is inadequate, partly due to lack of agreed definitions for particle types and mechanisms of spread. There is recent evidence to support historical data on the effects of natural ventilation but virtually none for sunlight. Modern practice of designing healthcare buildings for comfort favours pathogen persistence. As the number of effective antimicrobial agents declines, further work is required to clarify absolute risks from airborne pathogens along with any potential benefits from additional fresh air and sunlight. Copyright © 2013 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

  4. High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

    NASA Astrophysics Data System (ADS)

    Rozemeijer, J. C.; Visser, A.; Borren, W.; Winegram, M.; van der Velde, Y.; Klein, J.; Broers, H. P.

    2016-01-01

    High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates and the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007-2008) and after (2009-2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. However, this may be counteracted by the higher groundwater levels and the larger contribution of N- and P

  5. Sunlight off the ice

    NASA Image and Video Library

    2017-12-08

    Sunlight reflecting off of ice in the Bellingshausen Sea on Oct. 19, 2012. Credit: NASA / George Hale NASA's Operation IceBridge is an airborne science mission to study Earth's polar ice. For more information about IceBridge, visit: www.nasa.gov/icebridge NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

  6. [The Impact of Sunlight Exposure on the Health of Older Adults].

    PubMed

    Lin, Tzu-Chia; Liao, Yen-Chi

    2016-08-01

    Appropriate exposure to sunlight not only contributes to the production of vitamin D, which has been associated with enhanced bone health, mood, and cognitive functions, but also regulates the secretion of melatonin, which has been associated with the mediation of circadian rhythms, improved sleep quality, and optimized physical and social activity in the elderly. However, damage to the skin, eyes, and immune system has also been widely associated with long-term exposure to sunlight. Several studies have shown that many elderly, especially those that reside in institutions, do not receive sufficient sunlight exposure. Institutionalized elderly tend to participate in indoor activities and spend significant periods of time alone and asleep in front of the television. Furthermore, factors such as poor health, environmental design, indoor/outdoor preference, and activity design may impact the access of institutionalized elderly to sunlight more than their non-institutionalized peers. Therefore, we suggest that in addition to obtaining sufficient levels of vitamin D from their diet and from supplements, the elderly should perform outdoor activities for 20-30 minutes a day for five days each week. Furthermore, we suggest that the environment of the care facility should be made be more accessible and that some activities should be held outdoors.

  7. A Data Base of Nutrient Use, Water Use, CO2 Exchange, and Ethylene Production by Soybeans in a Controlled Environment

    NASA Technical Reports Server (NTRS)

    Wheeler, R. M.; Mackowiak, C. L.; Peterson, B. V.; Sager, J. C.; Knott, W. M.; Berry, W. L.; Sharifi, M. R.

    1998-01-01

    A data set is given describing daily nutrient and water uptake, carbon dioxide (CO2) exchange, ethylene production, and carbon and nutrient partitioning from a 20 sq m stand of soybeans (Glycine max (L.) Merr. cv. McCall] for use in bioregenerative life support systems. Stand CO2 exchange rates were determined from nocturnal increases in CO2 (respiration) and morning drawdowns (net photosynthesis) to a set point of 1000 micromol/ mol each day (i.e., a closed system approach). Atmospheric samples were analyzed throughout growth for ethylene using gas chromatography with photoionization detection (GC/PH)). Water use was monitored by condensate production from the humidity control system, as well as water uptake from the nutrient solution reservoirs each day. Nutrient uptake data were determined from daily additions of stock solution and acid to maintain an EC of 0.12 S/m and pH of 5.8. Dry mass yields of seeds, pods (without seeds), leaves, stems, and roots are provided, as well as elemental and proximate nutritional compositions of the tissues. A methods section is included to qualify any assumptions that might be required for the use of the data in plant growth models, along with a daily event calendar documenting set point adjustments and the occasional equipment or sensor failure.

  8. Mesophyll distribution of 'antioxidant' flavonoid glycosides in Ligustrum vulgare leaves under contrasting sunlight irradiance.

    PubMed

    Agati, Giovanni; Stefano, Giovanni; Biricolti, Stefano; Tattini, Massimiliano

    2009-10-01

    Flavonoids have the potential to serve as antioxidants in addition to their function of UV screening in photoprotective mechanisms. However, flavonoids have long been reported to accumulate mostly in epidermal cells and surface organs in response to high sunlight. Therefore, how leaf flavonoids actually carry out their antioxidant functions is still a matter of debate. Here, the distribution of flavonoids with effective antioxidant properties, i.e. the orthodihydroxy B-ring-substituted quercetin and luteolin glycosides, was investigated in the mesophyll of Ligustrum vulgare leaves acclimated to contrasting sunlight irradiance. In the first experiment, plants were grown at 20 % (shade) or 100% (sun) natural sunlight. Plants were exposed to 100 % sunlight irradiance in the presence or absence of UV wavelengths, in a second experiment. Fluorescence microspectroscopy and multispectral fluorescence microimaging were used in both cross sections and intact leaf pieces to visualize orthodihydroxy B-ring-substituted flavonoids at inter- and intracellular levels. Identification and quantification of individual hydroxycinnamates and flavonoid glycosides were performed via HPLC-DAD. Quercetin and luteolin derivatives accumulated to a great extent in both the epidermal and mesophyll cells in response to high sunlight. Tissue fluorescence signatures and leaf flavonoid concentrations were strongly related. Monohydroxyflavone glycosides, namely luteolin 4'-O-glucoside and two apigenin 7-O-glycosides were unresponsive to changes in sunlight irradiance. Quercetin and luteolin derivatives accumulated in the vacuoles of mesophyll cells in leaves growing under 100 % natural sunlight in the absence of UV wavelengths. The above findings lead to the hypothesis that flavonoids play a key role in countering light-induced oxidative stress, and not only in avoiding the penetration of short solar wavelengths in the leaf.

  9. Hypovitaminosis D in patients undergoing kidney transplant: the importance of sunlight exposure.

    PubMed

    Vilarta, Cristiane F; Unger, Marianna D; Dos Reis, Luciene M; Dominguez, Wagner V; David-Neto, Elias; Moysés, Rosa M; Titan, Silvia; Custodio, Melani R; Hernandez, Mariel J; Jorgetti, Vanda

    2017-07-01

    Recent studies have shown a high prevalence of hypovitaminosis D, defined as a serum 25-hydroxyvitamin D level less than 30 ng/ml, in both healthy populations and patients with chronic kidney disease. Patients undergoing kidney transplant are at an increased risk of skin cancer and are advised to avoid sunlight exposure. Therefore, these patients might share two major risk factors for hypovitaminosis D: chronic kidney disease and low sunlight exposure. This paper describes the prevalence and clinical characteristics of hypovitaminosis D among patients undergoing kidney transplant. We evaluated 25-hydroxyvitamin D serum levels in a representative sample of patients undergoing kidney transplant. We sought to determine the prevalence of hypovitaminosis D, compare these patients with a control group, and identify factors associated with hypovitaminosis D (e.g., sunlight exposure and dietary habits). Hypovitaminosis D was found in 79% of patients undergoing kidney transplant, and the major associated factor was low sunlight exposure. These patients had higher creatinine and intact parathyroid hormone serum levels, with 25-hydroxyvitamin D being inversely correlated with intact parathyroid hormone serum levels. Compared with the control group, patients undergoing kidney transplant presented a higher prevalence of 25-hydroxyvitamin D deficiency and lower serum calcium, phosphate and albumin but higher creatinine and intact parathyroid hormone levels. Our results confirmed the high prevalence of hypovitaminosis D in patients undergoing kidney transplant. Therapeutic strategies such as moderate sunlight exposure and vitamin D supplementation should be seriously considered for this population.

  10. Residential and occupational exposure to sunlight and mortality from non-Hodgkin's lymphoma: composite (threefold) case-control study.

    PubMed Central

    Freedman, D. M.; Zahm, S. H.; Dosemeci, M.

    1997-01-01

    OBJECTIVE: To determine whether non-Hodgkin's lymphoma mortality is associated with sunlight exposure. DESIGN: Three case-control studies based on death certificates of non-Hodgkin's lymphoma, melanoma, and skin cancer mortality examining associations with potential sunlight exposure from residence and occupation. SETTING: 24 states in the United States. SUBJECTS: All cases were deaths from non-Hodgkin's lymphoma, melanoma, and non-melanotic skin cancer between 1984 and 1991. Two age, sex, and race frequency matched controls per case were selected from non-cancer deaths. MAIN OUTCOME MEASURES: Odds ratios for non-Hodgkin's lymphoma, melanoma, and skin cancer from residential and occupational sunlight exposure adjusted for age, sex, race, socioeconomic status, and farming occupation. RESULTS: Non-Hodgkin's lymphoma mortality was not positively associated with sunlight exposure based on residence. Both melanoma and skin cancer were positively associated with residential sunlight exposure. Adjusted odds ratios for residing in states with the highest sunlight exposure were 0.83 (95% confidence interval 0.81 to 0.86) for non-Hodgkin's lymphoma, 1.12 (1.06 to 1.19) for melanoma, and 1.30 (1.18 to 1.43) for skin cancer. In addition, non-Hodgkin's lymphoma mortality was not positively associated with occupational sunlight exposure (odds ratio 0.88; 0.81 to 0.96). Skin cancer was slightly positively associated with occupational sunlight exposure (1.14; 0.96 to 1.36). CONCLUSIONS: Unlike skin cancer and to some extent melanoma, non-Hodgkin's lymphoma mortality was not positively associated with exposure to sunlight. The findings do not therefore support the hypothesis that sunlight exposure contributes to the rising rates of non-Hodgkin's lymphoma. PMID:9167561

  11. The versatility of limb scattered sunlight measurements

    NASA Astrophysics Data System (ADS)

    Bourassa, A. E.; Degenstein, D. A.; Sioris, C.; Rieger, L. A.; Zawada, D.

    2017-12-01

    Vertically resolved measurements of limb scattered sunlight spectra in the UV-Vis-NIR spectral range have been made from several satellite instruments in low earth orbit for many years, and there has been much success in using these measurements for retrievals of trace gas and aerosol from the upper troposphere to the mesosphere. Due in a large part to improvements in radiative transfer modelling, the versatility of the limb scatter measurement has continued to grow over the last several years. Using OSIRIS and OMPS instruments as primary examples, this talk will review the current capability of limb scatter measurements, and highlight recent results on ozone variability and trends in the UTLS, the continuation of the aerosol extinction record, NO2 distributions in the upper troposphere, and a new tomographic retrieval of ozone from the OMPS measurements. The future of limb scatter observations will also be discussed, including the development of two new Canadian suborbital instrument concepts that are targeted at high spatial resolution UTLS water vapor and cloud/aerosol measurements.

  12. Nutrient inputs into the Gulf of Finland: Trends and water protection targets

    NASA Astrophysics Data System (ADS)

    Knuuttila, Seppo; Räike, Antti; Ekholm, Petri; Kondratyev, Sergey

    2017-07-01

    The catchment area of the Gulf of Finland (GOF) is nearly 14 times larger than the sea area and is home to 12 million people. The GOF is thus heavily polluted by nutrients, and eutrophication is one of the major environmental concerns. The aim of this study was to estimate trends in the nutrient input and to evaluate whether current water protection targets (national, EU, HELCOM) will be achieved. We used both national and international (HELCOM) databases to evaluate nutrient inputs from the surrounding three countries (Estonia, Finland and Russia). The average nitrogen (N) input into the GOF was 112,000 t y- 1 for the period 2009-2013, with rivers responsible for 79%, direct point sources accounting for 10% and deposition for 11% of the input. Phosphorus (P) input was 4270 t y- 1, of which rivers were responsible for 88% and point sources for 12%. The largest proportions (61% for N and 73% for P) of the inputs came from Russia, despite the specific areal inputs (input divided by land area) being smaller than in Estonia and Finland. The changes in nutrient inputs into the GOF are largely due to the changes in Russian inputs, and in particular changes in the nutrient fluxes of the River Neva. The latest available flow-normalised data showed that N export decreased slightly from 1994 to 2010, while flow-normalised P export had clearly decreased by 2010. The P input ending up in the GOF as a whole has decreased significantly over the past 10 years as a result of the re-construction of wastewater treatment infrastructure in St Petersburg and following control of a P leak at the Phosphorit factory in 2012. This measure also explains the steep decrease in riverine P export during recent years. Further reduction of inputs to meet the ambitious nutrient reduction goals of HELCOM and of WFD seems to be a challenge for Finland and Estonia in particular. Russia appears to have already reached approximately 90% of the BSAP's reduction target, with fulfilment of the remainder

  13. Control of water and nutrients using a porous tube - A method for growing plants in space

    NASA Technical Reports Server (NTRS)

    Dreschel, Thomas W.; Sager, John C.

    1989-01-01

    A plant nutrient delivery system that uses a microporous, hydrophilic tube was developed with potential application for crop production in the microgravity of space. The tube contains a nutrient solution and delivers it to the roots. Pumps attached to the tubing create a very small suction that holds the solution within the tube. This system was used to grow wheat for 107 d in a controlled environment at suctions of 0.40, 1.48, or 2.58 kPa. The water absorbed through the pores of the tube by baby diaper sections decreased as suction increased. Correspondingly, final plant biomass, seed number, and spikelet number also tended to decrease as suction increased. The reduced yield at higher suction suggests that the plants experienced water stress, although all suctions were below those typical of soils at field capacity.

  14. Sequential nutrient uptake as a potential mechanism for phytoplankton to maintain high primary productivity and balanced nutrient stoichiometry

    NASA Astrophysics Data System (ADS)

    Yin, Kedong; Liu, Hao; Harrison, Paul J.

    2017-05-01

    We hypothesize that phytoplankton have the sequential nutrient uptake strategy to maintain nutrient stoichiometry and high primary productivity in the water column. According to this hypothesis, phytoplankton take up the most limiting nutrient first until depletion, continue to draw down non-limiting nutrients and then take up the most limiting nutrient rapidly when it is available. These processes would result in the variation of ambient nutrient ratios in the water column around the Redfield ratio. We used high-resolution continuous vertical profiles of nutrients, nutrient ratios and on-board ship incubation experiments to test this hypothesis in the Strait of Georgia. At the surface in summer, ambient NO3- was depleted with excess PO43- and SiO4- remaining, and as a result, both N : P and N : Si ratios were low. The two ratios increased to about 10 : 1 and 0. 45 : 1, respectively, at 20 m. Time series of vertical profiles showed that the leftover PO43- continued to be removed, resulting in additional phosphorus storage by phytoplankton. The N : P ratios at the nutricline in vertical profiles responded differently to mixing events. Field incubation of seawater samples also demonstrated the sequential uptake of NO3- (the most limiting nutrient) and then PO43- and SiO4- (the non-limiting nutrients). This sequential uptake strategy allows phytoplankton to acquire additional cellular phosphorus and silicon when they are available and wait for nitrogen to become available through frequent mixing of NO3- (or pulsed regenerated NH4). Thus, phytoplankton are able to maintain high productivity and balance nutrient stoichiometry by taking advantage of vigorous mixing regimes with the capacity of the stoichiometric plasticity. To our knowledge, this is the first study to show the in situ dynamics of continuous vertical profiles of N : P and N : Si ratios, which can provide insight into the in situ dynamics of nutrient stoichiometry in the water column and the inference of

  15. Development Of Nutrient And Water Recycling Capabilities In Algae Biofuels Production Systems. Final Summary Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lundquist, Tryg; Spierling, Ruth; Poole, Kyle

    The objective of this project was to develop and demonstrate methods of recycling of water and nutrients for algal biofuels production. Recycling was accomplished both internal to the system and, in a broader sense, through import and reuse of municipal wastewater. Such an integrated system with wastewater input had not been demonstrated previously, and the performance was unknown, particularly in terms of influence of recycling on algal productivity and the practical extent of nutrient recovery from biomass residuals. Through long-term laboratory and pilot research, the project resulted in the following: 1. Bench-scale pretreatment of algal biomass did not sufficiently increasemore » methane yield of nutrient solubilization during anaerobic digestion to warrant incorporation of pre-treatment into the pilot plant. The trial pretreatments were high-pressure orifice homogenization, sonication, and two types of heat treatment. 2. Solubilization of biomass particulate nutrients by lab anaerobic digesters ranged from 20% to nearly 60% for N and 40-65% for P. Subsequent aerobic degradation of the anaerobically digested biomass simulated raceways receiving whole digestate and resulted in an additional 20-55% N solubilization and additional 20% P solubilization. 3. Comparisons of laboratory and pilot digesters showed that laboratory units were reasonable proxies for pilot-scale. 4. Pilot-scale anaerobic digesters were designed, installed, and operated to digest algal biomass. Nutrient re-solubilization by the digesters was monitored and whole digestate was successfully used as a fertilizer in pilot algae raceways. 5. Unheated, unmixed digesters achieved greater methane yield and nutrient solubilization than heated, mixed digesters, presumably due to longer the solids residence times in unmixed digesters. The unmixed, unheated pilot digesters yielded 0.16 L CH4/g volatile solids (VS) introduced with 0.15 g VS/L-d organic loading and 16oC average temperature. A

  16. Sunlight-switchable light shutter fabricated using liquid crystals doped with push-pull azobenzene.

    PubMed

    Oh, Seung-Won; Baek, Jong-Min; Yoon, Tae-Hoon

    2016-11-14

    We propose a sunlight-switchable light shutter using liquid crystal/polymer composite doped with push-pull azobenzene. The proposed light shutter is switchable between the translucent and transparent states by application of an electric field or by UV irradiation. Switching by UV irradiation is based on the change of the liquid crystal (LC) clearing point by the photo-isomerization effect of push-pull azobenzene. Under sunlight, the light shutter can be switched from the translucent to the transparent state by the nematic-isotropic phase transition of the LC domains triggered by trans-cis photo-isomerization of the push-pull azobenzene molecules. When the amount of sunlight is low because of cloud cover or when there is no sunlight at sunset, the light shutter rapidly relaxes from its transparent state back to its initial translucent state by the isotropic-nematic phase transition induced by cis-trans back-isomerization of the push-pull azobenzene molecules.

  17. Ground-Water Nutrient Flux to Coastal Waters and Numerical Simulation of Wastewater Injection at Kihei, Maui, Hawaii

    USGS Publications Warehouse

    Hunt, Charles D.

    2007-01-01

    Water sampling and numerical modeling were used to estimate ground-water nutrient fluxes in the Kihei area of Maui, where growth of macroalgae (seaweed) on coral reefs raises ecologic concerns and accumulation on beaches has caused odor and removal problems. Fluxes and model results are highly approximate, first-order estimates because very few wells were sampled and there are few field data to constrain model calibration. Ground-water recharge was estimated to be 22.6 Mgal/d (million gallons per day) within a 73-square-mile area having a coastline length of 8 miles or 13 km (kilometers). Nearly all of the recharge discharges at the coast because ground-water withdrawals are small. Another 3.0 Mgal/d of tertiary-treated wastewater effluent is injected into the regional aquifer at a County treatment plant midway along the coast and about a mile from shore. The injection plume is 0.93 miles wide (1.5 km) at the shore, as estimated from a three-dimensional numerical ground-water model. Wastewater injected beneath the brackish ground-water lens rises buoyantly and spreads out at the top of the lens, diverting and mixing with ambient ground water. Ground water discharging from the core of the injection plume is less than 5 years old and is about 60 percent effluent at the shore, according to the model. Dissolved nitrogen and phosphorus concentrations in treated effluent were 7.33 and 1.72 milligrams per liter, roughly 6 and 26 times background concentrations at an upgradient well. Background nitrogen and phosphorus fluxes carried by ground water are 7.7 and 0.44 kg/d-km (kilograms per day per kilometer of coast). Injected wastewater fluxes distributed across the plume width are 55 and 13 kg/d-km nitrogen and phosphorus, roughly 7 and 30 times background flux. However, not all of the injected load reaches coastal waters because nutrients are naturally attenuated in the oxygen-depleted effluent plume. Water from a downgradient well reflects this attenuation and provides a

  18. Environmental Conditions in Water Storage Drums and Influences on Aedes aegypti inTrinidad, West Indies

    PubMed Central

    Hemme, Ryan R.; Tank, Jennifer L.; Chadee, Dave D.; Severson, David W.

    2014-01-01

    Water storage drums are often a primary breeding site for Aedes aegypti in developing countries. Habitat characteristics can impact both adult and larval fitness and survival, which may potentially influence arbovirus transmission. Our objective was to compare fundamental environmental differences in water drums based on the presence or absence of larvae in Trinidad. Drums were categorized according to the larval status, and if the drum was constructed of steel or plastic. Water samples were analyzed for ammonium, nitrate, and soluble reactive phosphorus (SRP). Continuous surface water temperatures were also recorded. Nutrient concentrations were considerably lower than those reported for other container breeding mosquitoes. No nutrient measured differed in concentration between drums positive compared to those that were negative for the presence of Aedes aegypti larvae. Levels of SRP and ammonium in steel drums were significantly lower than in plastic water drums. Both maximum and minimum surface temperatures were significantly lower in drums positive for the presence of larvae than in drums without larvae. Water temperatures in March and May were warmer than during October sampling periods. Larval presence is likely dependent upon the interaction among multiple biotic and abiotic factors. Despite appearance, not all water storage drums are equally suitable for Aedes aegypti development. Exposing water storage drums to direct sunlight or increased heat may be used in conjunction with sealing containers to reduce production of Aedes aegypti when draining and chemical treatment are impractical. PMID:19539592

  19. Environmental conditions in water storage drums and influences on Aedes aegypti in Trinidad, West Indies.

    PubMed

    Hemme, Ryan R; Tank, Jennifer L; Chadee, Dave D; Severson, David W

    2009-10-01

    Water storage drums are often a primary breeding site for Aedes aegypti in developing countries. Habitat characteristics can impact both adult and larval fitness and survival, which may potentially influence arbovirus transmission. Our objective was to compare fundamental environmental differences in water drums based on the presence or absence of larvae in Trinidad. Drums were categorized according to the larval status, and if the drum was constructed of steel or plastic. Water samples were analyzed for ammonium, nitrate, and soluble reactive phosphorus (SRP). Continuous surface water temperatures were also recorded. Nutrient concentrations were considerably lower than those reported for other container breeding mosquitoes. No nutrient measured differed in concentration between drums positive compared to those that were negative for the presence of A. aegypti larvae. Levels of SRP and ammonium in steel drums were significantly lower than in plastic water drums. Both maximum and minimum surface temperatures were significantly lower in drums positive for the presence of larvae than in drums without larvae. Water temperatures in March and May were warmer than during October sampling periods. Larval presence is likely dependent upon the interaction among multiple biotic and abiotic factors. Despite appearance, not all water storage drums are equally suitable for A. aegypti development. Exposing water storage drums to direct sunlight or increased heat may be used in conjunction with sealing containers to reduce production of A. aegypti when draining and chemical treatment are impractical.

  20. Dredging-induced nutrient release from sediments to the water column in a southeastern saltmarsh tidal creek.

    PubMed

    Lohrer, Andrew M; Wetz, Jennifer Jarrell

    2003-09-01

    Dredging is a large-scale anthropogenic disturbance agent in coastal and estuarine habitats that can profoundly affect water quality. We examined the impact of a small-scale dredging operation in a salt marsh in South Carolina by comparing nutrient levels (NH(4)(+), NO(x), PO(4)(-)) and total suspended solid concentrations before and during dredging activities. Nutrient enrichment was evaluated within the context of tidal, seasonal, and inter-annual variability by using long-term water chemistry data provided by the North Inlet-Winyah Bay National Estuarine Research Reserve. The conditions of the dredging permit (i.e., its relatively small scale), the season chosen for the work (fall-winter), the nature of the sediments dredged (coarse-grained), and the amount of natural variability in the estuary's water chemistry (even on a daily time-scale) all minimized the impact of the dredging activities. Results of this study will add to the limited body of empirical data that should be considered in evaluating future dredging permit applications related to shallow estuarine waterways.

  1. A Randomized Trial of Phototherapy with Filtered Sunlight in African Neonates.

    PubMed

    Slusher, Tina M; Olusanya, Bolajoko O; Vreman, Hendrik J; Brearley, Ann M; Vaucher, Yvonne E; Lund, Troy C; Wong, Ronald J; Emokpae, Abieyuwa A; Stevenson, David K

    2015-09-17

    Sequelae of severe neonatal hyperbilirubinemia constitute a substantial disease burden in areas where effective conventional phototherapy is unavailable. We previously found that the use of filtered sunlight for the purpose of phototherapy is a safe and efficacious method for reducing total bilirubin. However, its relative safety and efficacy as compared with conventional phototherapy are unknown. We conducted a randomized, controlled noninferiority trial in which filtered sunlight was compared with conventional phototherapy for the treatment of hyperbilirubinemia in term and late-preterm neonates in a large, urban Nigerian maternity hospital. The primary end point was efficacy, which was defined as a rate of increase in total serum bilirubin of less than 0.2 mg per deciliter per hour for infants up to 72 hours of age or a decrease in total serum bilirubin for infants older than 72 hours of age who received at least 5 hours of phototherapy; we prespecified a noninferiority margin of 10% for the difference in efficacy rates between groups. The need for an exchange transfusion was a secondary end point. We also assessed safety, which was defined as the absence of the need to withdraw therapy because of hyperthermia, hypothermia, dehydration, or sunburn. We enrolled 447 infants and randomly assigned 224 to filtered sunlight and 223 to conventional phototherapy. Filtered sunlight was efficacious on 93% of treatment days that could be evaluated, as compared with 90% for conventional phototherapy, and had a higher mean level of irradiance (40 vs. 17 μW per square centimeter per nanometer, P<0.001). Temperatures higher than 38.0°C occurred in 5% of the infants receiving filtered sunlight and in 1% of those receiving conventional phototherapy (P<0.001), but no infant met the criteria for withdrawal from the study for reasons of safety or required an exchange transfusion. Filtered sunlight was noninferior to conventional phototherapy for the treatment of neonatal

  2. Contribution of Wastewater Treatment Plant Effluents to Nutrient Dynamics in Aquatic Systems: A Review

    NASA Astrophysics Data System (ADS)

    Carey, Richard O.; Migliaccio, Kati W.

    2009-08-01

    Excessive nutrient loading (considering nitrogen and phosphorus) is a major ongoing threat to water quality and here we review the impact of nutrient discharges from wastewater treatment plants (WWTPs) to United States (U.S.) freshwater systems. While urban and agricultural land uses are significant nonpoint nutrient contributors, effluent from point sources such as WWTPs can overwhelm receiving waters, effectively dominating hydrological characteristics and regulating instream nutrient processes. Population growth, increased wastewater volumes, and sustainability of critical water resources have all been key factors influencing the extent of wastewater treatment. Reducing nutrient concentrations in wastewater is an important aspect of water quality management because excessive nutrient concentrations often prevent water bodies from meeting designated uses. WWTPs employ numerous physical, chemical, and biological methods to improve effluent water quality but nutrient removal requires advanced treatment and infrastructure that may be economically prohibitive. Therefore, effluent nutrient concentrations vary depending on the particular processes used to treat influent wastewater. Increasingly stringent regulations regarding nutrient concentrations in discharged effluent, along with greater freshwater demand in populous areas, have led to the development of extensive water recycling programs within many U.S. regions. Reuse programs provide an opportunity to reduce or eliminate direct nutrient discharges to receiving waters while allowing for the beneficial use of reclaimed water. However, nutrients in reclaimed water can still be a concern for reuse applications, such as agricultural and landscape irrigation.

  3. Sunlight Exposure and Breast Density: A Population-Based Study

    PubMed Central

    Wu, Sheng-Hui; So, Edwin; Lam, Tsz-ping; Woo, Jean; Yuen, PY; Qin, Ling; Ku, Susanna

    2013-01-01

    Purpose This study aims to assess the association of sunlight exposure with breast cancer risk, measured by the breast density assessed from Tabár's mammographic pattern in Chinese women. Methods A total of 676 premenopausal women were recruited to participate in this study, in which 650 completed a validated sunlight exposure questionnaire via telephone. The mammograms were classified according to Tabár's classification for parenchyma, and patterns IV & V and I, II & III indicated respectively high and low risk mammographic patterns for breast cancer. The odds ratios (OR) and 95% confidence intervals (CIs) for sun exposure-related variables were estimated using unconditional logistic regression with adjustment for potential confounders. Results Among 646 participants, women with high breast cancer risk (Tabár's patterns IV &V) had less hours spent in the sun than those with low risk (I, II & III) at any age stage. A higher level of sunlight exposure was associated with a significantly lower risk having high risk Tabár's pattern. Women aged 40 to 44 years who were in the highest tertile of lifetime total hours spent in the sun had a multi-adjusted OR of 0.41 (95% CI, 0.18-0.92; p for trend=0.03) compared with those in the lowest tertile (>2.19 hr/day vs. <1.32 hr/day). For hours spent in the sun across the ages of 6 to 12 years, the comparable OR was 0.37 (95% CI, 0.15-0.91; p for trend=0.03). Conclusion These findings suggest that higher sunlight exposure is related to a lower risk of having high risk breast density pattern in premenopausal women. Our results also suggest the most relevant period of exposure is during earlier life. PMID:23843849

  4. Sunlight exposure during leisure activities and risk of prostate cancer in Montréal, Canada, 2005-2009.

    PubMed

    Yu, Jennifer; Lavoué, Jérôme; Parent, Marie-Élise

    2014-07-28

    Prostate cancer (PCa) is the leading cause of cancer in men in many developed countries, but no modifiable risk factors have been identified. A handful of analytical studies have suggested a possible etiological role for sunlight exposure. We report here on the association between leisure-time sunlight exposure during adulthood and PCa risk in the context of a population-based case-control study. In all, 1,904 PCa cases were ascertained across Montreal French hospitals between 2005 and 2009. Concurrently, 1,962 population controls, frequency matched to cases by age (±5 years), were selected from the electoral list for French-speakers in Greater Montreal. Interviews elicited the frequency of engagement in any leisure activity during adulthood. This was used to derive cumulative sunlight exposure indices: a cumulative number of leisure activities events entailing sunlight exposure and a cumulative duration of sunlight exposure during leisure activities. Unconditional logistic regression was conducted to yield odds ratios (OR) and 95% confidence intervals (CI) for estimating the association between sunlight exposure indices and PCa risk, adjusting for age, ancestry, family history of PCa, PCa screening, education, solar protection, body mass index and physical activity. Compared with men in the upper quartile category for the number of sunlight exposure events, men never exposed during leisure time had an OR of 1.32 (95% CI: 0.82-2.14). ORs were 1.11, 0.91 and 1.00 for the first to the third quartiles of exposure, respectively. Similar results were observed for cumulative duration of exposure to sunlight, and by PCa aggressiveness. These findings provide little evidence of an association between sunlight exposure during leisure-time and PCa risk. Men with no sunlight exposure appeared at somewhat higher risks but none of the estimates achieved statistical significance.

  5. Evaluating changes in water quality with respect to nonpoint source nutrient management strategies in the Chesapeake Bay Watershed

    NASA Astrophysics Data System (ADS)

    Keisman, J.; Sekellick, A.; Blomquist, J.; Devereux, O. H.; Hively, W. D.; Johnston, M.; Moyer, D.; Sweeney, J.

    2014-12-01

    Chesapeake Bay is a eutrophic ecosystem with periodic hypoxia and anoxia, algal blooms, diminished submerged aquatic vegetation, and degraded stocks of marine life. Knowledge of the effectiveness of actions taken across the watershed to reduce nitrogen (N) and phosphorus (P) loads to the bay (i.e. "best management practices" or BMPs) is essential to its restoration. While nutrient inputs from point sources (e.g. wastewater treatment plants and other industrial and municipal operations) are tracked, inputs from nonpoint sources, including atmospheric deposition, farms, lawns, septic systems, and stormwater, are difficult to measure. Estimating reductions in nonpoint source inputs attributable to BMPs requires compilation and comparison of data on water quality, climate, land use, point source discharges, and BMP implementation. To explore the relation of changes in nonpoint source inputs and BMP implementation to changes in water quality, a subset of small watersheds (those containing at least 10 years of water quality monitoring data) within the Chesapeake Watershed were selected for study. For these watersheds, data were compiled on geomorphology, demographics, land use, point source discharges, atmospheric deposition, and agricultural practices such as livestock populations, crop acres, and manure and fertilizer application. In addition, data on BMP implementation for 1985-2012 were provided by the Environmental Protection Agency Chesapeake Bay Program Office (CBPO) and the U.S. Department of Agriculture. A spatially referenced nonlinear regression model (SPARROW) provided estimates attributing N and P loads associated with receiving waters to different nutrient sources. A recently developed multiple regression technique ("Weighted Regressions on Time, Discharge and Season" or WRTDS) provided an enhanced understanding of long-term trends in N and P loads and concentrations. A suite of deterministic models developed by the CBPO was used to estimate expected

  6. Contribution of water hyacinth (Eichhornia crassipes (Mart.) Solms) grown under different nutrient conditions to Fe-removal mechanisms in constructed wetlands.

    PubMed

    Jayaweera, Mahesh W; Kasturiarachchi, Jagath C; Kularatne, Ranil K A; Wijeyekoon, Suren L J

    2008-05-01

    Severe contamination of water resources including groundwater with iron (Fe) due to various anthropogenic activities has been a major environmental problem in industrial areas of Sri Lanka. Hence, the use of the obnoxious weed, water hyacinth (Eichhornia crassipes (Mart.) Solms) in constructed wetlands (floating aquatic macrophyte-based plant treatment systems) to phytoremediate Fe-rich wastewaters seems to be an appealing option. Although several studies have documented that hyacinths are good metal-accumulating plants none of these studies have documented the ability of this plant grown under different nutrient conditions to remove heavy metals from wastewaters. This paper, therefore, reports the phytoremediation efficiencies of water hyacinth grown under different nutrient conditions for Fe-rich wastewaters in batch-type constructed wetlands. This study was conducted for 15 weeks after 1-week acclimatization by culturing young water hyacinth plants (average height of 20+/-2cm) in 590L capacity fiberglass tanks under different nutrient concentrations of 1-fold [28 and 7.7mg/L of total nitrogen (TN) and total phosphorous (TP), respectively], 2-fold, 1/2-fold, 1/4-fold and 1/8-fold with synthetic wastewaters containing 9.27Femg/L. Another set-up of hyacinths containing only Fe as a heavy metal but without any nutrients (i.e., 0-fold) was also studied. A mass balance was carried out to investigate the phytoremediation efficiencies and to determine the different mechanisms governing Fe removal from the wastewaters. Fe removal was largely due to phytoremediation mainly through the process of rhizofiltration and chemical precipitation of Fe2O3 and FeOH3 followed by flocculation and sedimentation. However, chemical precipitation was more significant especially during the first 3 weeks of the study. Plants grown in the 0-fold set-up showed the highest phytoremediation efficiency of 47% during optimum growth at the 6th week with a highest accumulation of 6707Femg/kg dry

  7. Hypovitaminosis D in patients undergoing kidney transplant: the importance of sunlight exposure

    PubMed Central

    Vilarta, Cristiane F.; Unger, Marianna D.; dos Reis, Luciene M.; Dominguez, Wagner V.; David-Neto, Elias; Moysés, Rosa M.; Titan, Silvia; Custodio, Melani R.; Hernandez, Mariel J.; Jorgetti, Vanda

    2017-01-01

    OBJECTIVES: Recent studies have shown a high prevalence of hypovitaminosis D, defined as a serum 25-hydroxyvitamin D level less than 30 ng/ml, in both healthy populations and patients with chronic kidney disease. Patients undergoing kidney transplant are at an increased risk of skin cancer and are advised to avoid sunlight exposure. Therefore, these patients might share two major risk factors for hypovitaminosis D: chronic kidney disease and low sunlight exposure. This paper describes the prevalence and clinical characteristics of hypovitaminosis D among patients undergoing kidney transplant. METHODS: We evaluated 25-hydroxyvitamin D serum levels in a representative sample of patients undergoing kidney transplant. We sought to determine the prevalence of hypovitaminosis D, compare these patients with a control group, and identify factors associated with hypovitaminosis D (e.g., sunlight exposure and dietary habits). RESULTS: Hypovitaminosis D was found in 79% of patients undergoing kidney transplant, and the major associated factor was low sunlight exposure. These patients had higher creatinine and intact parathyroid hormone serum levels, with 25-hydroxyvitamin D being inversely correlated with intact parathyroid hormone serum levels. Compared with the control group, patients undergoing kidney transplant presented a higher prevalence of 25-hydroxyvitamin D deficiency and lower serum calcium, phosphate and albumin but higher creatinine and intact parathyroid hormone levels. CONCLUSIONS: Our results confirmed the high prevalence of hypovitaminosis D in patients undergoing kidney transplant. Therapeutic strategies such as moderate sunlight exposure and vitamin D supplementation should be seriously considered for this population. PMID:28793001

  8. Short and Long-Term Sunlight Radiation and Stroke Incidence

    PubMed Central

    McClure, Leslie A.; Judd, Suzanne E.; Howard, Virginia J.; Crosson, William L.; Al-Hamdan, Mohammad Z.; Wadley, Virginia G.; Peace, Fredrick; Kabagambe, Edmond K.

    2012-01-01

    OBJECTIVE Examine whether long and short-term sunlight radiation is related to stroke incidence. METHODS Fifteen-year residential histories merged with satellite, ground monitor, and model reanalysis data were used to determine sunlight radiation (insolation) and temperature exposure for a cohort of 16,606 stroke and coronary artery disease free black and white participants aged 45+ from the 48 contiguous United States. Fifteen, ten, five, two and one-year exposures were used to predict stroke incidence during follow-up in Cox proportional hazard models. Potential confounders and mediators were included during model-building. RESULTS Shorter exposure periods exhibited similar, but slightly stronger relationships than longer exposure periods. After adjustment for other covariates, the previous year’s monthly average insolation exposure below the median gave an HR=1.61 (95% CI: 1.15, 2.26) and the previous year’s highest compared to the second highest quartile of monthly average maximum temperature exposure gave an HR=1.92 (1.27, 2.92). INTERPRETATION These results indicate a relationship between lower levels of sunlight radiation and higher stroke incidence. The biological pathway of this relationship is not clear. Future research will show whether this finding stands, the pathway for this relationship, and if it is due to short or long-term exposures. PMID:23225379

  9. Nutrient trends through time in Sweden's Baltic Drainage Area

    NASA Astrophysics Data System (ADS)

    Fischer, I.; Destouni, G.; Prieto, C.

    2015-12-01

    Changes in climate and land-use have and will continue to modify regional hydrology, in turn impacting environmental health, agricultural productivity and water resource quality and availability. The Baltic region is an area of interest as the coast spans nine countries- serving over 100 million people. The Baltic Sea contains one of the largest human caused hypoxic dead zones due to eutrophication driven by anthropogenic excess loading of nutrients. Policies to reduce these loads include also international directives and agreements, such as the EU Water Framework Directive, adopted in 2000 to protect and improve water quality throughout the European Union, and the Baltic Sea Action Plan under the Helsinki Commission aimed specifically at reducing the nutrient loading to and mitigating the eutrophication of the Baltic Sea. In light of these policies and amidst the number of studies on the Baltic Sea we ask, using the accessible nutrient and discharge data what does nutrient loading look like today? Are the most excessive loads going down? Observed nutrient and flow time series across Sweden allow for answering these questions, by spatial and temporal trend analysis of loads from various parts of Sweden to the Baltic Sea. Analyzing these observed time series in conjunction with the ecological health status classifications of the EU Water Framework Directive, allows in particular for answering the question if the loads into the water bodies with the poorest water quality, and from those to the Baltic Sea, are improving, being maintained or deteriorating. Such insight is required to contribute to relevant and efficient water and nutrient load management. Furthermore, empirically calculating nutrient loads, rather than only modeling, reveals that the water body health classification may not reflect what water bodies actually contribute the heaviest loads to the Baltic Sea. This work also underscores the importance of comprehensive analysis of all available data from

  10. [Maximilian Mehl and the treatment with concentrated sunlight].

    PubMed

    Heyll, U

    2006-12-22

    In 1889, a chance observation made by Maximilian Mehl, an officer of the Berlin police force, lead him to develop a new method of treating Lupus Vulgaris with concentrated sunlight. Although first therapies proved the efficacy of this method, scientific medicine showed little interest. But Mehl found recognition among supporters of natural healing methods who saw their principles confirmed by his discovery. Mehl's tentative therapy was superseded by technological methods of sunlight treatment, as developed by the Danish doctor Niels Ryberg Finsen. In 1903 Finsen was awarded the Nobel Prize for his work while Mehl's discovery remained practically unknown. This episode in the history of medicine demonstrates how the recognition of a new method not only depends on criteria of its efficacy, but equally so on the degree of its conformity with preconceived notions and accepted standards.

  11. Impacts of human activities on nutrient transport in the Yellow River: The role of the Water-Sediment Regulation Scheme.

    PubMed

    Li, Xinyu; Chen, Hontao; Jiang, Xueyan; Yu, Zhigang; Yao, Qingzhen

    2017-08-15

    Anthropogenic activities alter the natural states of large rivers and their surrounding environment. The Yellow River is a well-studied case of a large river with heavy human control. An artificial managed water and sediment release system, known as the Water-Sediment Regulation Scheme (WSRS), has been carried out annually in the Yellow River since 2002. Nutrient concentrations and composition display significant time and space variations during the WSRS period. To figure out the anthropogenic impact of nutrient changes and transport in the Yellow River, biogeochemical observations were carried out in both middle reaches and lower reaches of the Yellow River during 2014 WSRS period. WSRS has a direct impact on water oxidation-reduction environment in the middle reaches; concentrations of nitrite (NO 2 - ) and ammonium (NH 4 + ) increased, while nitrate (NO 3 - ) concentration decreased by enhanced denitrification. WSRS changed transport of water and sediment; dissolved silicate (DSi) in the middle reaches was directly controlled by sediments release during the WSRS while in the lower reaches, DSi changed with both sediments and water released from middle reaches. During the WSRS, the differences of nutrient fluxes and concentrations between lower reaches and middle reaches were significant; dissolved inorganic phosphorous (DIP) and dissolved inorganic nitrogen (DIN) were higher in low reaches because of anthropogenic inputs. Human intervention, especially WSRS, can apparently change the natural states of both the mainstream and estuarine environments of the Yellow River within a short time. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. The Southwest Atlantic intertidal burrowing crab Neohelice granulata modifies nutrient loads of phreatic waters entering coastal area

    NASA Astrophysics Data System (ADS)

    Fanjul, Eugenia; Grela, María A.; Canepuccia, Alejandro; Iribarne, Oscar

    2008-08-01

    Along the coastal areas of the Southwest Atlantic estuaries and embayments, phreatic water often circulates through very extended areas (up to several hundred meters perpendicular to the coast), dominated by dense assemblages of deep burrows of the crab Neohelice granulata (formerly Chasmagnathus granulatus). This crab inhabits the intertidal area, from mudflats to marshes vegetated by species of Spartina, Sarcocornia and Juncus, generating extensive burrowing beds where burrow density may reach up to 60 burrows m -2. Since the lower limit of the crab burrows is usually the water table, we investigated through field experiments the effect of N. granulata and their burrows on the chemical characteristics of this phreatic water. Water analysis from experimental (1) occupied burrows (with crabs), (2) unoccupied burrows (where crabs were excluded), and (3) sediment pore water show remarkable differences. Water oxygenation, and nitrate, ammonium and sulphate concentrations inside occupied burrows were higher than in the water inside unoccupied burrows or pore waters. Moreover, directed sampling of phreatic water entering and leaving the crab bed, shows that dissolved inorganic nitrogen concentration is enhanced as the water crosses the crab bed. These results may be ascribed to the fact that in the salt marsh the crabs spend most of their time within burrows, where presumably they store food (plants) and defecate. These activities generate an area of accumulation of excrements and nutrients in different decomposition states. The present work shows a novel way by which bioturbating organisms can affect nutrients exportation from salt marshes to the open waters.

  13. Saharan dust nutrients promote Vibrio bloom formation in marine surface waters.

    PubMed

    Westrich, Jason R; Ebling, Alina M; Landing, William M; Joyner, Jessica L; Kemp, Keri M; Griffin, Dale W; Lipp, Erin K

    2016-05-24

    Vibrio is a ubiquitous genus of marine bacteria, typically comprising a small fraction of the total microbial community in surface waters, but capable of becoming a dominant taxon in response to poorly characterized factors. Iron (Fe), often restricted by limited bioavailability and low external supply, is an essential micronutrient that can limit Vibrio growth. Vibrio species have robust metabolic capabilities and an array of Fe-acquisition mechanisms, and are able to respond rapidly to nutrient influx, yet Vibrio response to environmental pulses of Fe remains uncharacterized. Here we examined the population growth of Vibrio after natural and simulated pulses of atmospherically transported Saharan dust, an important and episodic source of Fe to tropical marine waters. As a model for opportunistic bacterial heterotrophs, we demonstrated that Vibrio proliferate in response to a broad range of dust-Fe additions at rapid timescales. Within 24 h of exposure, strains of Vibrio cholerae and Vibrio alginolyticus were able to directly use Saharan dust-Fe to support rapid growth. These findings were also confirmed with in situ field studies; arrival of Saharan dust in the Caribbean and subtropical Atlantic coincided with high levels of dissolved Fe, followed by up to a 30-fold increase of culturable Vibrio over background levels within 24 h. The relative abundance of Vibrio increased from ∼1 to ∼20% of the total microbial community. This study, to our knowledge, is the first to describe Vibrio response to Saharan dust nutrients, having implications at the intersection of marine ecology, Fe biogeochemistry, and both human and environmental health.

  14. Assessment of nutrients, suspended sediment, and pesticides in surface water of the upper Snake River basin, Idaho and western Wyoming, water years 1991-95

    USGS Publications Warehouse

    Clark, Gregory M.

    1997-01-01

    Quality Assessment Program. As part of the investigation, intensive monitoring was conducted during water years 1993 through 1995 to assess surface-water quality in the basin. Sampling and analysis focused on nutrients, suspended sediments, and pesticides because of nationwide interest in these constituents. Concentrations of nutrients and suspended sediment in water samples from 19 sites in the upper Snake River Basin, including nine on the main stem, were assessed. In general, concentrations of nutrients and suspended sediment were smaller in water from the 11 sites upstream from American Falls Reservoir than in water from the 8 sites downstream from the reservoir where effects from land-use activities are most pronounced. Median concentrations of dissolved nitrite plus nitrate as nitrogen at the 19 sites ranged from less than 0.05 to 1.60 milligrams per liter; total phosphorus as phosphorus, less than 0.01 to 0.11 milligrams per liter; and suspended sediment, 4 to 72 milligrams per liter. Concentrations of nutrients and suspended sediment in the main stem of the Snake River, in general, increased downstream. The largest concentrations in the main stem were in the middle reach of the Snake River between Milner Dam and the outlet of the upper Snake River Basin at King Hill. Significant differences (p Nutrient and suspended sediment inputs to the middle Snake reach were from a variety of sources. During water year 1995, springs were the primary source of water and total nitrogen to the river and accounted for 66 and 60 percent of the total input, respectively. Isotope and water-table information indicated that the springs derived most of their nitrogen from agricultural activities along the margins of the Snake River. Aquacultural effluent was a major source of ammonia (82 percent), organic nitrogen (30 percent), and total phosphorus (35 percent). Tributary streams were a major source of organic nitrogen (28 percent) and suspended sediment (58 percent). In

  15. Air Ambient-Operated pNIPAM-Based Flexible Actuators Stimulated by Human Body Temperature and Sunlight.

    PubMed

    Yamamoto, Yuki; Kanao, Kenichiro; Arie, Takayuki; Akita, Seiji; Takei, Kuniharu

    2015-05-27

    Harnessing a natural power source such as the human body temperature or sunlight should realize ultimate low-power devices. In particular, macroscale and flexible actuators that do not require an artificial power source have tremendous potential. Here we propose and demonstrate electrically powerless polymer-based actuators operated at ambient conditions using a packaging technique in which the stimulating power source is produced by heat from the human body or sunlight. The actuating angle, force, and reliability are discussed as functions of temperature and exposure to sunlight. Furthermore, a wearable device platform and a smart curtain actuated by the temperature of human skin and sunlight, respectively, are demonstrated as the first proof-of-concepts. These nature-powered actuators should realize a new class of ultimate low-power devices.

  16. Fungal Endophyte (Epichloë festucae) Alters the Nutrient Content of Festuca rubra Regardless of Water Availability

    PubMed Central

    Vázquez-de-Aldana, Beatriz R.; García-Ciudad, Antonia; García-Criado, Balbino; Vicente-Tavera, Santiago; Zabalgogeazcoa, Iñigo

    2013-01-01

    Festuca rubra plants maintain associations with the vertically transmitted fungal endophyte Epichloë festucae. A high prevalence of infected host plants in semiarid grasslands suggests that this association could be mutualistic. We investigated if the Epichloë-endophyte affects the growth and nutrient content of F. rubra plants subjected to drought. Endophyte-infected (E+) and non-infected (E−) plants of two half-sib lines (PEN and RAB) were subjected to three water availability treatments. Shoot and root biomass, nutrient content, proline, phenolic compounds and fungal alkaloids were measured after the treatments. The effect of the endophyte on shoot and root biomass and dead leaves depended on the plant line. In the PEN line, E+ plants had a greater S:R ratio than E-, but the opposite occurred in RAB. In both plant lines and all water treatments, endophyte-infected plants had greater concentrations of N, P and Zn in shoots and Ca, Mg and Zn in roots than E- plants. On average, E+ plants contained in their shoots more P (62%), Zn (58%) and N (19%) than E- plants. While the proline in shoots increased in response to water stress, the endophyte did not affect this response. A multivariate analysis showed that endophyte status and plant line impose stronger differences in the performance of the plants than the water stress treatments. Furthermore, differences between PEN and RAB lines seemed to be greater in E- than in E+ plants, suggesting that E+ plants of both lines are more similar than those of their non-infected version. This is probably due to the endophyte producing a similar effect in both plant lines, such as the increase in N, P and Zn in shoots. The remarkable effect of the endophyte in the nutrient balance of the plants could help to explain the high prevalence of infected plants in natural grasslands. PMID:24367672

  17. Enhanced biofiltration of O&G produced water comparing granular activated carbon and nutrients.

    PubMed

    Riley, Stephanie M; Ahoor, Danika C; Cath, Tzahi Y

    2018-05-31

    Large volumes of water are required for the development of unconventional oil and gas (O&G) wells. Water scarcity coupled with seismicity induced by deep-well disposal promote new O&G wastewater management strategies, specifically treatment and reuse. One technology that has been proven effective for removal of organic matter and solids is biologically active filtration (BAF) with granular active carbon (GAC); however, further optimization is needed to enhance BAF performance. This study evaluated three GAC media (one spent and two new) and two nutrient-mix supplements for enhanced removal of chemical oxygen demand (COD) and dissolved organic carbon (DOC). Biofilm development was also monitored and correlated to BAF performance. The spent GAC with extant biofilm quickly acclimated to PW and demonstrated up to 92% DOC removal (81% COD) in 24h, while little impact by nutrient addition was observed. In addition, virgin GAC was slow to establish a biofilm, indicating that appropriate GAC selection and pre-developed biofilm is critical for efficient BAF performance. Furthermore, the production of high quality BAF effluent (less than 20mg/L DOC) presents the opportunity to apply BAF as a pretreatment for subsequent desalination-expanding the potential for reuse applications of PW. Copyright © 2017. Published by Elsevier B.V.

  18. Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; data on agricultural organic compounds, nutrients, and sediment in water, 1988-90

    USGS Publications Warehouse

    Sullivan, D.J.; Terrio, P.J.

    1994-01-01

    This report describes the sampling design and methods and presents data collected to determine the distribution of agricultural organic compounds, nutrients, and sediment in selected areas of the upper Illinois River Basin as part of the National Water-Quality Assessment program. Four stations in small watersheds (two urban, two agricultural) were sampled in 1988 and 1989. Seventeen stations in an agricultural subbasin were sampled in 1990. Samples were collected before, during, and after runoff events from late spring to midsummer to determine concentrations of agricultural organic compounds in surface waters resulting from storm runoff, as well as background concentrations. Over 200 water samples were analyzed for agricultural organic compound, nutrient, and suspended-sediment concentrations. The agricultural organic compounds included triazine and chlorophenoxy-acid herbicides, and organo-phosphorus insecticides.

  19. Hybrid sunlight/LED illumination and renewable solar energy saving concepts for indoor lighting.

    PubMed

    Tsuei, Chih-Hsuan; Sun, Wen-Shing; Kuo, Chien-Cheng

    2010-11-08

    A hybrid method for using sunlight and light-emitting diode (LED) illumination powered by renewable solar energy for indoor lighting is simulated and presented in this study. We can illuminate an indoor space and collect the solar energy using an optical switching system. When the system is turned off, the full spectrum of the sunlight is concentrated by a concentrator, to be absorbed by solar photovoltaic devices that provide the electricity to power the LEDs. When the system is turned on, the sunlight collected by the concentrator is split into visible and non-visible rays by a beam splitter. The visible rays pass through the light guide into a light box where it is mixed with LED light to ultimately provide uniform illumination by a diffuser. The non-visible rays are absorbed by the solar photovoltaic devices to provide electrical power for the LEDs. Simulation results show that the efficiency of the hybrid sunlight/LED illumination with the renewable solar energy saving design is better than that of LED and traditional lighting systems.

  20. Biomass production and nutrient removal potential of water hyacinth cultured in sewage effluent

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reddy, K.R.; Hueston, F.M.; McKim, T.

    1985-05-01

    Growth and nutrient uptake of water hyacinth (Eichhornia crassipes (Mart) Solms) cultured in sewage effluent were measured over a period of 1 year in a prototype wastewater treatment system which has been in operation at Walt Disney World near Orlando, Florida. Annual productivity of water hyacinth cultured in primary sewage effluent (Channel II) was found to be in the range of 5 to 27 g dry wt m/sup -2/ day/sup -1/ (23.6 dry tons acre/sup -1/ yr/sup -1/). Average growth rate during the months of May through October 1982 for hyacinth cultured in Channel II (primary sewage effluent) and Channelmore » I (treated primary sewage effluent leaving Channel II) was about 16 g dry wt m/sup -2/ day/sup -1/ (27 dry tons acre/sup -1/ yr/sup -1/), compared to the growth rate of 13 g dry wt m/sup -2/ day/sup -1/ (22 dry tons acre/sup -1/ yr/sup -1/) for hyacinths cultured in secondary sewage effluent. Plants cultured in secondary sewage effluent generally had longer roots than the plants cultured in primary sewage effluent. A significant relationship was observed between the growth rate of hyacinth and the solar radiation. Nitrogen and P concentration of the plant tissue were higher in the hyacinths cultured during winter months compared to the plants grown in summer months. Average N and P concentration of the plants cultured in primary sewage effluent were found to be 3.7 percent N and 0.94 percent P, respectively, while the plants cultured in secondary sewage effluent had a total N and P content of 2.8 percent N and 0.79 percent P. Nutrient ratios of the major plant nutrients were found to be approximately the same as the nutrient ratios in the sewage effluent. Annual N and P uptake rates of hyacinth cultured in sewage effluent were found to be in the range of 1176 to 1193 kg N ha/sup -1/ yr/sup -1/ and 321 to 387 kg P ha/sup -1/ yr/sup -1/, respectively.« less

  1. Submarine ground-water discharge: nutrient loading and nitrogen transformations

    USGS Publications Warehouse

    Kroeger, Kevin D.; Swarzenski, Peter W.; Crusius, John; Bratton, John F.; Charette, Matthew A.

    2006-01-01

    Eutrophication of coastal waters due to nonpoint source land-derived nitrogen (N) loads is a worldwide phenomenon and perhaps the greatest agent of change altering coastal ecology (National Research Council, 2000; Howarth and others, 2000). Within the United States, a majority of estuaries have been determined to be moderately to severely impaired by eutrophication associated with increasing nutrient loads (Bricker and others, 1999).In coastal watersheds with soils of high hydraulic conductivity and permeable coastal sediments, ground water is a major route of transport of freshwater and its solutes from land to sea. Freshwater flowing downgradient from aquifers may either discharge from a seepage face near the intertidal zone, or flow directly into the sea as submarine ground-water discharge (SGD) (fig. 1). In the coastal aquifer, entrainment of saline pore water occurs prior to discharge, producing a gradient in ground-water salinity from land to sea, referred to as a subterranean estuary (Moore, 1999). In addition, processes including density-driven flow and tidal pumping create brackish and saline ground-water circulation. Hence, submarine ground-water discharge often consists of a substantial amount of recirculating seawater. Mixing of fresh and saline ground waters in the context of coastal sediments may alter the chemical composition of the discharging fluid. Depending on the biogeochemical setting, removal of fixed N due to processes leading to N2 (dinitrogen gas) production in the nearshore aquifer and subterranean estuary may significantly attenuate land-derived N loads; or, processes such as ion exchange and tidal pumping in the subterranean estuary may substantially accelerate the transport of both land-derived and sediment re-mineralized N to estuarine water columns.As emphasized by Burnett and others (2001, 2002), a fundamental problem in evaluating the importance of ground-water discharge in marine geochemical budgets is the difficulty of collecting

  2. Real-time monitoring of nutrients in the Changjiang Estuary reveals short-term nutrient-algal bloom dynamics

    NASA Astrophysics Data System (ADS)

    Wang, Kui; Chen, Jianfang; Ni, Xiaobo; Zeng, Dingyong; Li, Dewang; Jin, Haiyan; Glibert, Patricia M.; Qiu, Wenxian; Huang, Daji

    2017-07-01

    The Changjiang Estuary is a large-river estuary ecosystem in the East China Sea, and its plume, the Changjiang Diluted Water (CDW), transports a large mass of nutrients (NO3- + NO2-, PO43-, SiO32-) to the shelf sea, leading to substantial eutrophication; the CDW also supports high primary production. However, relationships between nutrient delivery and phytoplankton responses have been difficult to establish, as many nutrient delivery events and algal blooms are episodic, and the CDW may expand or become detached with changing winds. To study the relationship between nutrient delivery events, algal blooms and estuarine metabolism dynamics, a buoy system was deployed in the CDW from 9 September to 10 October 2013, with measurements of chlorophyll a and dissolved nutrients. Day-to-day nutrient increases covaried with salinity decreases, regulated by both the spring-neap tidal cycle and wind events. Several specific nutrient injection periods were detected, each followed by nutrient drawdown and chlorophyll a accumulation (algal blooms). Each algal bloom had its own unique pattern of nutrient uptake based on change in nutrient ratios (ΔN:ΔP; ΔN:ΔSi) and appeared to be dominated by different algal groups. These events occurred under weak wind and stable hydrodynamic conditions. Ecosystem metabolism based on net community production (NCP) showed that the upper estuarine ecosystem was autotrophic when chlorophyll a accumulated, but heterotrophic when wind-induced mixing strengthened, and upwelling brought organic-rich water to the near surface. In spite of several short-lived algal blooms, the average NCPdaily was negative during the observation period, indicating a net source of CO2 to the atmosphere.

  3. What's Upstream? GIS's critical role in developing nutrient ...

    EPA Pesticide Factsheets

    Eutrophication due to excess levels of nitrogen and phosphorus can seriously impair ecological function in estuaries. Protective criteria for nutrients are difficult to establish because the source can vary spatially and seasonally, originate either from the watershed or the ocean, and be natural or anthropogenic. GIS tools and processes can help in developing nutrient criteria by establishing reference conditions representative of natural background nutrient levels. Along the Oregon Coast in the Pacific Northwest, the primary source of nutrients in the wet season (November-April) is generally riverine. We delineated and extracted explicit spatial data from watersheds upstream of riverine water quality monitoring stations for parametric comparison to recorded nutrient levels. The SPARROW model (Wise and Johnson, 2011) was used to estimate relative contributions of nutrient sources at each station. Both raster and vector spatial data were used and include land use / land cover, demography, geology, terrain, precipitation and forest type. The relationships of nutrients to spatial data were then explored as an approach to establishing the reference expectation. The abstract introduces Geographic Information Systems (GIS) tools and processes employed for research conducted under the Safe and Sustainable Water Resources (SSWR) Task 2.3A, entitled “Nutrient Management for Sustainability of Aquatic Ecosystems.” One of the goals of the EPA Office of Water is to

  4. Evaluation of sunlight induced structural changes and their effect on the photocatalytic activity of V2O5 for the degradation of phenols.

    PubMed

    Aslam, M; Ismail, Iqbal M I; Salah, Numan; Chandrasekaran, S; Qamar, M Tariq; Hameed, A

    2015-04-09

    Despite knowing the fact that vanadium pentoxide is slightly soluble in aqueous medium, its photocatalytic activity was evaluated for the degradation of phenol and its derivatives (2-hydroxyphenol, 2-chlorophenol, 2-aminophenol and 2-nitrophenol) in natural sunlight exposure. The prime objective of the study was to differentiate between the homogeneous and heterogeneous photocatalysis incurred by dissolved and undissolved V2O5 in natural sunlight exposure. V2O5 was synthesized by chemical precipitation procedure using Triton X-100 as morphology mediator and characterized by DRS, PLS, Raman, FESEM and XRD. A lower solubility of ∼ 5% per 100ml of water at 23 °C was observed after calcination at 600 °C. The study revealed no contribution of the dissolved V2O5 in the photocatalytic process. In sunlight exposure, V2O5 powder exhibited substantial activity for the degradation, however, a low mineralization of phenolic substrates was observed. The initial low activity of V2O5 followed by a sharp increase both in degradation and mineralization in complete spectrum sunlight exposure, was further investigated that revealed the decrease in the bandgap and the reduction in the particle size with the interaction of UV photons (<420 nm) as this effect was not observable in the exposure of visible region of sunlight. The role of the chemically different substituents attached to an aromatic ring at 2-positions and the secondary interaction of released ions during the degradation process with the reactive oxygen species (ROS) was also explored. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Water-quality assessment of the Albemarle-Pamlico drainage basin, North Carolina and Virginia; characterization of suspended sediment, nutrients, and pesticides

    USGS Publications Warehouse

    Harned, Douglas; McMahon, Gerard; Spruill, T.B.; Woodside, M.D.

    1995-01-01

    The 28,000-square-mile Albemarle-Pamlico drainage basin includes the Roanoke, Dan, Chowan Tar, and Neuse Rivers. The basin extends through four physiographic provinces in North Carolina and Virginia-Valley and Ridge, Blue Ridge, Piedmont and Coastal Plain. The spatial and temporal trends in ground-water and riverine water quality in the study area were characterized by using readily available data sources The primary data sources that were used included the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) database, the U.S. Environmental Protection Agency's Storage and Retrieval System (STORET) database, and results of a few investigations of pesticide occurrence. The principal water-quality constituents examined were suspended sediment, nutrients, and pesticides. The data examined generally spanned the period from 1950 to 1993. The only significant trends in suspended sediment were detected at three Chowan River tributary sites which showed long-term decreases. Suspended- and total-solids concentrations have decreased throughout the Albemarle-Pamlico drainage basin. The decreases are probably a result of (1) construction of new lakes and ponds in the basin, which trap solids, (2) improved agricultural soil management, and (3) improved wastewater treatment. Nutrient point sources are much less than nonpoint nutrient sources at the eight NASQAN basins examined for nutrient loads. The greatest nitrogen inputs are associated with crop fertilizer and biological nitrogen fixation by soybeans and peanuts, whereas atmospheric and animal-related nitrogen inputs are comparable in magnitude. The largest phosphorus inputs are associated with animal wastes. The most commonly detected pesticides in surface water in the STORET database were atrazine and aldrin.Intensive organonitrogen herbicide sampling of Chicod Creek in 1992 showed seasonal variations in pesticide concentration. The most commonly detected herbicides were atrazine, alachlor

  6. Nutrient Removal in Wastewater Treatment

    ERIC Educational Resources Information Center

    Shah, Kanti L.

    1973-01-01

    Discusses the sources and effects of nutrients in wastewater, and the methods of their removal in wastewater treatment. In order to conserve water resources and eliminate the cost of nutrient removal, treated effluent should be used wherever possible for irrigation, since it contains all the ingredients for proper plant growth. (JR)

  7. High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rozemeijer, J. C.; Visser, A.; Borren, W.

    High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates andmore » the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007–2008) and after (2009–2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. Furthermore, this may be counteracted by the higher groundwater levels and the larger contribution

  8. High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

    DOE PAGES

    Rozemeijer, J. C.; Visser, A.; Borren, W.; ...

    2016-01-19

    High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates andmore » the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007–2008) and after (2009–2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. Furthermore, this may be counteracted by the higher groundwater levels and the larger contribution

  9. Water-quality characteristics, trends, and nutrient and sediment loads of streams in the Treyburn development area, North Carolina, 1988–2009

    USGS Publications Warehouse

    Fine, Jason M.; Harned, Douglas A.; Oblinger, Carolyn J.

    2013-01-01

    Streamflow and water-quality data, including concentrations of nutrients, metals, and pesticides, were collected from October 1988 through September 2009 at six sites in the Treyburn development study area. A review of water-quality data for streams in and near a 5,400-acre planned, mixed-use development in the Falls Lake watershed in the upper Neuse River Basin of North Carolina indicated only small-scale changes in water quality since the previous assessment of data collected from 1988 to 1998. Loads and yields were estimated for sediment and nutrients, and temporal trends were assessed for specific conductance, pH, and concentrations of dissolved oxygen, suspended sediment, and nutrients. Water-quality conditions for the Little River tributary and Mountain Creek may reflect development within these basins. The nitrogen and phosphorus concentrations at the Treyburn sites are low compared to sites nationally. The herbicides atrazine, metolachlor, prometon, and simazine were detected frequently at Mountain Creek and Little River tributary but concentrations are low compared to sites nationally. Little River tributary had the lowest median suspended-sediment yield over the 1988–2009 study period, whereas Flat River tributary had the largest median yield. The yields estimated for suspended sediment and nutrients were low compared to yields estimated for other basins in the Southeastern United States. Recent increasing trends were detected in total nitrogen concentration and suspended-sediment concentrations for Mountain Creek, and an increasing trend was detected in specific conductance for Little River tributary. Decreasing trends were detected in dissolved nitrite plus nitrate nitrogen, total ammonia plus organic nitrogen, sediment, and specific conductance for Flat River tributary. Water chemical concentrations, loads, yields, and trends for the Treyburn study sites reflect some effects of upstream development. These measures of water quality are generally low

  10. Competitive interaction of Axonopus compressus and Asystasia gangetica under contrasting sunlight intensity.

    PubMed

    Samedani, B; Juraimi, A S; Anwar, M P; Rafii, M Y; Sheikh Awadz, S H; Anuar, A R

    2013-01-01

    Axonopus compressus is one of the native soft grass species in oil palm in Malaysia which can be used as a cover crop. The competitive ability of A. compressus to overcome A. gangetica was studied using multiple-density, multiple-proportion replacements series under a glasshouse and full sunlight conditions in a poly bag for 10 weeks. A. compressus produced more dry weight and leaf area when competing against A. gangetica than in monoculture at both densities in the full sunlight and at high density in the shade. Moreover, the relative yield and relative crowding coefficients also indicated A. compressus is a stronger competitor than A. gangetica at both densities in the full sunlight and high density in the shade. It seemed that A. gangetica plants in the shade did not compete with each other and were more competitive against A. compressus as could influence A. compressus height in the shade. It is concluded that although suppression of A. gangetica by A. compressus occurred under full sunlight, irrespective of plant density, this ability reduced under shade as A. compressus density decreased. The result suggests that A. compressus in high density could be considered as a candidate for cover crops under oil palm canopy.

  11. Competitive Interaction of Axonopus compressus and Asystasia gangetica under Contrasting Sunlight Intensity

    PubMed Central

    Samedani, B.; Juraimi, A. S.; Anwar, M. P.; Rafii, M. Y.; Sheikh Awadz, S. H.; Anuar, A. R.

    2013-01-01

    Axonopus compressus is one of the native soft grass species in oil palm in Malaysia which can be used as a cover crop. The competitive ability of A. compressus to overcome A. gangetica was studied using multiple-density, multiple-proportion replacements series under a glasshouse and full sunlight conditions in a poly bag for 10 weeks. A. compressus produced more dry weight and leaf area when competing against A. gangetica than in monoculture at both densities in the full sunlight and at high density in the shade. Moreover, the relative yield and relative crowding coefficients also indicated A. compressus is a stronger competitor than A. gangetica at both densities in the full sunlight and high density in the shade. It seemed that A. gangetica plants in the shade did not compete with each other and were more competitive against A. compressus as could influence A. compressus height in the shade. It is concluded that although suppression of A. gangetica by A. compressus occurred under full sunlight, irrespective of plant density, this ability reduced under shade as A. compressus density decreased. The result suggests that A. compressus in high density could be considered as a candidate for cover crops under oil palm canopy. PMID:24163618

  12. Degradation of benzotriazole and benzothiazole in treatment wetlands and by artificial sunlight.

    PubMed

    Felis, Ewa; Sochacki, Adam; Magiera, Sylwia

    2016-11-01

    Laboratory-scale experiments were performed using unsaturated subsurface-flow treatment wetlands and artificial sunlight (with and without TiO 2 ) to study the efficiency of benzotriazole and benzothiazole removal and possible integration of these treatment methods. Transformation products in the effluent from the treatment wetlands and the artificial sunlight reactor were identified by high performance liquid chromatography coupled with tandem mass spectrometry. The removal of benzothiazole in the vegetated treatment wetlands was 99.7%, whereas the removal of benzotriazole was 82.8%. The vegetation positively affected only the removal of benzothiazole. The major transformation products in the effluents from the treatment wetlands were methylated and hydroxylated derivatives of benzotriazole, and hydroxylated derivatives of benzothiazole. Hydroxylation was found to be the main process governing the transformation pathway for both compounds in the artificial sunlight experiment (with and without TiO 2 ). Benzotriazole was not found to be susceptible to photodegradation in the absence of TiO 2 . The integration of the sunlight-induced processes (with TiO 2 ) with subsurface-flow treatment wetlands caused further elimination of the compounds (42% for benzotriazole and 58% for benzothiazole). This was especially significant for the elimination of benzotriazole, because the removal of this compound was 96% in the coupled processes. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Water and Nutrient Balances in a Large Tile-Drained Agricultural Catchment: A Distributed Modeling Study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Li, Hongyi; Sivapalan, Murugesu; Tian, Fuqiang

    This paper presents the development and implementation of a distributed model of coupled water nutrient processes, based on the representative elementary watershed (REW) approach, to the Upper Sangamon River Basin, a large, tile-drained agricultural basin located in central Illinois, mid-west of USA. Comparison of model predictions with the observed hydrological and biogeochemical data, as well as regional estimates from literature studies, shows that the model is capable of capturing the dynamics of water, sediment and nutrient cycles reasonably well. The model is then used as a tool to gain insights into the physical and chemical processes underlying the inter- andmore » intra-annual variability of water and nutrient balances. Model predictions show that about 80% of annual runoff is contributed by tile drainage, while the remainder comes from surface runoff (mainly saturation excess flow) and subsurface runoff. It is also found that, at the annual scale nitrogen storage in the soil is depleted during wet years, and is supplemented during dry years. This carryover of nitrogen storage from dry year to wet year is mainly caused by the lateral loading of nitrate. Phosphorus storage, on the other hand, is not affected much by wet/dry conditions simply because the leaching of it is very minor compared to the other mechanisms taking phosphorous out of the basin, such as crop harvest. The analysis then turned to the movement of nitrate with runoff. Model results suggested that nitrate loading from hillslope into the channel is preferentially carried by tile drainage. Once in the stream it is then subject to in-stream denitrification, the significant spatio-temporal variability of which can be related to the variation of the hydrologic and hydraulic conditions across the river network.« less

  14. Linkages between nutrients and assemblages of macroinvertebrates and fish in wadeable streams: Implication to nutrient criteria development

    USGS Publications Warehouse

    Wang, L.; Robertson, Dale M.; Garrison, P.J.

    2007-01-01

    We sampled 240 wadeable streams across Wisconsin for different forms of phosphorus and nitrogen, and assemblages of macroinvertebrates and fish to (1) examine how macroinvertebrate and fish measures correlated with the nutrients; (2) quantify relationships between key biological measures and nutrient forms to identify potential threshold levels of nutrients to support nutrient criteria development; and (3) evaluate the importance of nutrients in influencing biological assemblages relative to other physicochemical factors at different spatial scales. Twenty-three of the 35 fish and 18 of the 26 macroinvertebrate measures significantly correlated (P < 0.05) with at least one nutrient measure. Percentages of carnivorous, intolerant, and omnivorous fishes, index of biotic integrity, and salmonid abundance were fish measures correlated with the most nutrient measures and had the highest correlation coefficients. Percentages of Ephemeroptera-Plecoptera-Trichoptera individuals and taxa, Hilsenhoff biotic index, and mean tolerance value were macroinvertebrate measures that most strongly correlated with the most nutrient measures. Selected biological measures showed clear trends toward degradation as concentrations of phosphorus and nitrogen increased, and some measures showed clear thresholds where biological measures changed drastically with small changes in nutrient concentrations. Our selected environmental factors explained 54% of the variation in the fish assemblages. Of this explained variance, 46% was attributed to catchment and instream habitat, 15% to nutrients, 3% to other water quality measures, and 36% to the interactions among all the environmental variables. Selected environmental factors explained 53% of the variation in macroinvertebrate assemblages. Of this explained variance, 42% was attributed to catchment and instream habitat, 22% to nutrients, 5% to other water quality measures, and 32% to the interactions among all the environmental variables. ?? 2006

  15. Linkages Between Nutrients and Assemblages of Macroinvertebrates and Fish in Wadeable Streams: Implication to Nutrient Criteria Development

    NASA Astrophysics Data System (ADS)

    Wang, Lizhu; Robertson, Dale M.; Garrison, Paul J.

    2007-02-01

    We sampled 240 wadeable streams across Wisconsin for different forms of phosphorus and nitrogen, and assemblages of macroinvertebrates and fish to (1) examine how macroinvertebrate and fish measures correlated with the nutrients; (2) quantify relationships between key biological measures and nutrient forms to identify potential threshold levels of nutrients to support nutrient criteria development; and (3) evaluate the importance of nutrients in influencing biological assemblages relative to other physicochemical factors at different spatial scales. Twenty-three of the 35 fish and 18 of the 26 macroinvertebrate measures significantly correlated ( P < 0.05) with at least one nutrient measure. Percentages of carnivorous, intolerant, and omnivorous fishes, index of biotic integrity, and salmonid abundance were fish measures correlated with the most nutrient measures and had the highest correlation coefficients. Percentages of Ephemeroptera-Plecoptera-Trichoptera individuals and taxa, Hilsenhoff biotic index, and mean tolerance value were macroinvertebrate measures that most strongly correlated with the most nutrient measures. Selected biological measures showed clear trends toward degradation as concentrations of phosphorus and nitrogen increased, and some measures showed clear thresholds where biological measures changed drastically with small changes in nutrient concentrations. Our selected environmental factors explained 54% of the variation in the fish assemblages. Of this explained variance, 46% was attributed to catchment and instream habitat, 15% to nutrients, 3% to other water quality measures, and 36% to the interactions among all the environmental variables. Selected environmental factors explained 53% of the variation in macroinvertebrate assemblages. Of this explained variance, 42% was attributed to catchment and instream habitat, 22% to nutrients, 5% to other water quality measures, and 32% to the interactions among all the environmental variables.

  16. The Great Lakes Water Quality Agreement with an emphasis on annex 4 nutrients -and Lake Erie

    EPA Science Inventory

    Presented will be an overview of the Great Lakes Water Quality Act of 2012 including a general description of the Annexes and the new Binational Governance. The talk will focus on the Annex 4 Nutrients Subcommittee and the Objectives and Targets Task Team efforts that have been ...

  17. Modeling the Response of Nutrient Concentrations and Primary Productivity in Lake Michigan to Nutrient Loading Scenarios

    EPA Science Inventory

    A water quality model, LM3 Eutro, will be used to estimate the response of nutrient concentrations and primary productivity in Lake Michigan to nutrient loading scenarios. This work is part of a larger effort, the Future Midwestern landscapes study, that will estimate the produc...

  18. Physical determinants of phytoplankton production, algal stoichiometry, and vertical nutrient fluxes.

    PubMed

    Jäger, Christoph G; Diehl, Sebastian; Emans, Maximilian

    2010-04-01

    Most phytoplankters face opposing vertical gradients in light versus nutrient supplies but have limited capacities for vertical habitat choice. We therefore explored a dynamical model of negatively buoyant algae inhabiting a one-dimensional water column to ask how water column depth and turbulence constrain total (areal) phytoplankton biomass. We show that the population persistence boundaries in water column depth-turbulence space are set by sinking losses and light limitation but that nutrients are most limiting to total biomass in water columns that are neither too shallow or too weakly mixed (where sinking losses prevail) nor too deep and turbulent (where light limitation prevails). In shallow waters, the most strongly limiting process is nutrient influx to the bottom of the water column (e.g., from sediments). In deep waters, the most strongly limiting process is turbulent upward transport of nutrients to the photic zone. Consequently, the highest total biomasses are attained in turbulent waters at intermediate water column depths and in deep waters at intermediate turbulences. These patterns are insensitive to the assumption of fixed versus flexible algal carbon-to-nutrient stoichiometry, and they arise irrespective of whether the water column is a surface layer above a deep water compartment or has direct contact with sediments.

  19. Up-conversion fluorescence: noncoherent excitation by sunlight.

    PubMed

    Baluschev, S; Miteva, T; Yakutkin, V; Nelles, G; Yasuda, A; Wegner, G

    2006-10-06

    We demonstrate up-conversion of noncoherent sunlight realized by ultralow excitation intensity. The bimolecular up-conversion process in our systems relies on the presence of a metastable triplet excited state, and thus has dramatically different photophysical characteristics relative to the other known methods for photon up-conversion (two-photon absorption, parametric processes, second harmonic generation, sequential multiphoton absorption, etc.).

  20. Study of enhanced photogalvanic effect of Naphthol Green B in natural sunlight

    NASA Astrophysics Data System (ADS)

    Koli, Pooran

    2015-07-01

    The photogalvanic cells based on Naphthol Green B sensitizer-Fructose reductant-Sodium Lauryl Sulphate surfactant has been studied in natural sunlight. The cell has been found workable in natural sunlight with greatly enhanced optimum cell performance. The 1159.2 μW power, 4500 μA short-circuit current, 1070 mV open-circuit potential, 14.49% efficiency and 240 min storage capacity (as half change time) has been observed in optimum cell fabrication conditions.

  1. Understanding the influence of nutrients on stream ecosystems in agricultural landscapes

    USGS Publications Warehouse

    Munn, Mark D.; Frey, Jeffrey W.; Tesoriero, Anthony J.; Black, Robert W.; Duff, John H.; Lee, Kathy E.; Maret, Terry R.; Mebane, Christopher A.; Waite, Ian R.; Zelt, Ronald B.

    2018-06-06

    Sustaining the quality of the Nation’s water resources and the health of our diverse ecosystems depends on the availability of sound water-resources data and information to develop effective, science-based policies. Effective management of water resources also brings more certainty and efficiency to important economic sectors. Taken together, these actions lead to immediate and long-term economic, social, and environmental benefits that make a difference to the lives of the almost 400 million people projected to live in the United States by 2050.In 1991, Congress established the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) to address where, when, why, and how the Nation’s water quality has changed, or is likely to change in the future, in response to human activities and natural factors. Since then, NAWQA has been a leading source of scientific data and knowledge used by national, regional, State, and local agencies to develop science-based policies and management strategies to improve and protect water resources used for drinking water, recreation, irrigation, energy development, and ecosystem needs (https://water.usgs.gov/nawqa/applications/). Plans for the third decade of NAWQA (2013–23) address priority water-quality issues and science needs identified by NAWQA stakeholders, such as the Advisory Committee on Water Information and the National Research Council, and are designed to meet increasing challenges related to population growth, increasing needs for clean water, and changing land-use and weather patterns.Excess nutrients are a pervasive problem of streams, lakes, and coastal waters. The current report, “The Quality of Our Nation’s Waters—Understanding the Effects of Nutrients on Stream Ecosystems in Agricultural Landscapes,” presents a summary of results from USGS investigations conducted from 2003 to 2011 on processes that influence nutrients and how nutrient enrichment can alter biological components of

  2. Timber-harvest clearcutting and nutrients in the Northeastern United States

    Treesearch

    K. G. Reinhart

    1973-01-01

    The effect of ecosystem disturbance on nutrients in the system has been receiving widespread attention. An appraisal of research results in the Northeast indicates that timber-harvest clearcutting has not increased nutrient levels sufficiently to reduce water quality below drinking water standards. Losses of nutrients from clearcuttings in New Hampshire over a 2-year...

  3. Effects of sunlight exposure on grapevine powdery mildew development.

    PubMed

    Austin, Craig N; Wilcox, Wayne F

    2012-09-01

    Natural and artificially induced shade increased grapevine powdery mildew (Erysiphe necator) severity in the vineyard, with foliar disease severity 49 to 75% higher relative to leaves in full sun, depending on the level of natural shading experienced and the individual experiment. Cluster disease severities increased by 20 to 40% relative to those on check vines when ultraviolet (UV) radiation was filtered from sunlight reaching vines in artificial shading experiments. Surface temperatures of leaves in full sunlight averaged 5 to 8°C higher than those in natural shade, and in one experiment, filtering 80% of all wavelengths of solar radiation, including longer wavelengths responsible for heating irradiated tissues, increased disease more than filtering UV alone. In controlled environment experiments, UV-B radiation reduced germination of E. necator conidia and inhibited both colony establishment (hyphal formation and elongation) and maturity (latent period). Inhibitory effects of UV-B radiation were significantly greater at 30°C than at 20 or 25°C. Thus, sunlight appears to inhibit powdery mildew development through at least two mechanisms, i.e., (i) UV radiation's damaging effects on exposed conidia and thalli of the pathogen; and (ii) elevating temperatures of irradiated tissues to a level supraoptimal or inhibitory for pathogen development. Furthermore, these effects are synergistic at temperatures near the upper threshold for disease development.

  4. Nutrient uptake of peanut genotypes under different water regimes

    USDA-ARS?s Scientific Manuscript database

    Drought is a serious environmental stress limiting growth and productivity in peanut and other crops. Nutrient uptake of peanut is reduced under drought conditions, which reduces yield. The objectives of this study were to investigate nutrient uptake of peanut genotypes in response to drought and ...

  5. Analysis of Environmental Effects on Leaf Temperature under Sunlight, High Pressure Sodium and Light Emitting Diodes.

    PubMed

    Nelson, Jacob A; Bugbee, Bruce

    2015-01-01

    The use of LED technology is commonly assumed to result in significantly cooler leaf temperatures than high pressure sodium technology. To evaluate the magnitude of this effect, we measured radiation incident to and absorbed by a leaf under four radiation sources: clear sky sunlight in the field, sunlight in a glass greenhouse, and indoor plants under either high pressure sodium or light emitting diodes. We then applied a common mechanistic energy-balance model to compare leaf to air temperature difference among the radiation sources and environments. At equal photosynthetic photon flux, our results indicate that the effect of plant water status and leaf evaporative cooling is much larger than the effect of radiation source. If plants are not water stressed, leaves in all four radiation sources were typically within 2°C of air temperature. Under clear sky conditions, cool sky temperatures mean that leaves in the field are always cooler than greenhouse or indoor plants-when photosynthetic photon flux, stomatal conductance, wind speed, vapor pressure deficit, and leaf size are equivalent. As water stress increases and cooling via transpiration decreases, leaf temperatures can increase well above air temperature. In a near-worst case scenario of water stress and low wind, our model indicates that leaves would increase 6°, 8°, 10°, and 12°C above air temperature under field, LED, greenhouse, and HPS scenarios, respectively. Because LED fixtures emit much of their heat through convection rather than radiative cooling, they result in slightly cooler leaf temperatures than leaves in greenhouses and under HPS fixtures, but the effect of LED technology on leaf temperature is smaller than is often assumed. Quantifying the thermodynamic outputs of these lamps, and their physiological consequences, will allow both researchers and the horticulture industry to make informed decisions when employing these technologies.

  6. Analysis of Environmental Effects on Leaf Temperature under Sunlight, High Pressure Sodium and Light Emitting Diodes

    PubMed Central

    Nelson, Jacob A.; Bugbee, Bruce

    2015-01-01

    The use of LED technology is commonly assumed to result in significantly cooler leaf temperatures than high pressure sodium technology. To evaluate the magnitude of this effect, we measured radiation incident to and absorbed by a leaf under four radiation sources: clear sky sunlight in the field, sunlight in a glass greenhouse, and indoor plants under either high pressure sodium or light emitting diodes. We then applied a common mechanistic energy-balance model to compare leaf to air temperature difference among the radiation sources and environments. At equal photosynthetic photon flux, our results indicate that the effect of plant water status and leaf evaporative cooling is much larger than the effect of radiation source. If plants are not water stressed, leaves in all four radiation sources were typically within 2°C of air temperature. Under clear sky conditions, cool sky temperatures mean that leaves in the field are always cooler than greenhouse or indoor plants-when photosynthetic photon flux, stomatal conductance, wind speed, vapor pressure deficit, and leaf size are equivalent. As water stress increases and cooling via transpiration decreases, leaf temperatures can increase well above air temperature. In a near-worst case scenario of water stress and low wind, our model indicates that leaves would increase 6°, 8°, 10°, and 12°C above air temperature under field, LED, greenhouse, and HPS scenarios, respectively. Because LED fixtures emit much of their heat through convection rather than radiative cooling, they result in slightly cooler leaf temperatures than leaves in greenhouses and under HPS fixtures, but the effect of LED technology on leaf temperature is smaller than is often assumed. Quantifying the thermodynamic outputs of these lamps, and their physiological consequences, will allow both researchers and the horticulture industry to make informed decisions when employing these technologies. PMID:26448613

  7. Centers for Water Research on National Priorities Related to a Systems View of Nutrient Management Kick-off Meeting

    EPA Pesticide Factsheets

    At this meeting, grantees from Centers for Water Research on National Priorities Related to a Systems View of Nutrient Management and Sustainable Chesapeake: A Community-Based Approach to Stormwater Management Using Green Infrastructure

  8. Photochemical transformation of graphene oxide in sunlight (journal)

    EPA Science Inventory

    Graphene oxide (GO) is a graphene derivative that is more easily manufactured in large scale and used to synthesize reduced graphene oxide (rGO) with properties analogous to graphene. In this study, we investigate the photochemical fate of GO under sunlight conditions. The resu...

  9. Mesophyll distribution of ‘antioxidant’ flavonoid glycosides in Ligustrum vulgare leaves under contrasting sunlight irradiance

    PubMed Central

    Agati, Giovanni; Stefano, Giovanni; Biricolti, Stefano; Tattini, Massimiliano

    2009-01-01

    Background and Aims Flavonoids have the potential to serve as antioxidants in addition to their function of UV screening in photoprotective mechanisms. However, flavonoids have long been reported to accumulate mostly in epidermal cells and surface organs in response to high sunlight. Therefore, how leaf flavonoids actually carry out their antioxidant functions is still a matter of debate. Here, the distribution of flavonoids with effective antioxidant properties, i.e. the orthodihydroxy B-ring-substituted quercetin and luteolin glycosides, was investigated in the mesophyll of Ligustrum vulgare leaves acclimated to contrasting sunlight irradiance. Methods In the first experiment, plants were grown at 20 % (shade) or 100% (sun) natural sunlight. Plants were exposed to 100 % sunlight irradiance in the presence or absence of UV wavelengths, in a second experiment. Fluorescence microspectroscopy and multispectral fluorescence microimaging were used in both cross sections and intact leaf pieces to visualize orthodihydroxy B-ring-substituted flavonoids at inter- and intracellular levels. Identification and quantification of individual hydroxycinnamates and flavonoid glycosides were performed via HPLC-DAD. Key Results Quercetin and luteolin derivatives accumulated to a great extent in both the epidermal and mesophyll cells in response to high sunlight. Tissue fluorescence signatures and leaf flavonoid concentrations were strongly related. Monohydroxyflavone glycosides, namely luteolin 4′-O-glucoside and two apigenin 7-O-glycosides were unresponsive to changes in sunlight irradiance. Quercetin and luteolin derivatives accumulated in the vacuoles of mesophyll cells in leaves growing under 100 % natural sunlight in the absence of UV wavelengths. Conclusions The above findings lead to the hypothesis that flavonoids play a key role in countering light-induced oxidative stress, and not only in avoiding the penetration of short solar wavelengths in the leaf. PMID:19633310

  10. Toxicological impact of cadmium-based quantum dots towards aquatic biota: Effect of natural sunlight exposure.

    PubMed

    Silva, B F; Andreani, T; Gavina, A; Vieira, M N; Pereira, C M; Rocha-Santos, T; Pereira, R

    2016-07-01

    Cadmium-based quantum dots (QDs) are increasingly applied in existent and emerging technologies, especially in biological applications due to their exceptional photophysical and functionalization properties. However, they are very toxic compounds due to the high reactive and toxic cadmium core. The present study aimed to determine the toxicity of three different QDs (CdS 380, CdS 480 and CdSeS/ZnS) before and after the exposure of suspensions to sunlight, in order to assess the effect of environmentally relevant irradiation levels in their toxicity, which will act after their release to the environment. Therefore, a battery of ecotoxicological tests was performed with organisms that cover different functional and trophic levels, such as Vibrio fischeri, Raphidocelis subcapitata, Chlorella vulgaris and Daphnia magna. The results showed that core-shell type QDs showed lower toxic effects to V. fischeri in comparison to core type QDs before sunlight exposure. However, after sunlight exposure, there was a decrease of CdS 380 and CdS 480 QD toxicity to bacterium. Also, after sunlight exposure, an effective decrease of CdSeS/ZnS and CdS 480 toxicity for D. magna and R. subcapitata, and an evident increase in CdS 380 QD toxicity, at least for D. magna, were observed. The results of this study suggest that sunlight exposure has an effect in the aggregation and precipitation reactions of larger QDs, causing the degradation of functional groups and formation of larger bulks which may be less prone to photo-oxidation due to their diminished surface area. The same aggregation behaviour after sunlight exposure was observed for bare QDs. These results further emphasize that the shell of QDs seems to make them less harmful to aquatic biota, both under standard environmental conditions and after the exposure to a relevant abiotic factor like sunlight. Copyright © 2016 Elsevier B.V. All rights reserved.

  11. High-resolution monitoring of nutrients in groundwater and surface waters: process understanding, quantification of loads and concentrations, and management applications

    NASA Astrophysics Data System (ADS)

    van Geer, Frans C.; Kronvang, Brian; Broers, Hans Peter

    2016-09-01

    Four sessions on "Monitoring Strategies: temporal trends in groundwater and surface water quality and quantity" at the EGU conferences in 2012, 2013, 2014, and 2015 and a special issue of HESS form the background for this overview of the current state of high-resolution monitoring of nutrients. The overview includes a summary of technologies applied in high-frequency monitoring of nutrients in the special issue. Moreover, we present a new assessment of the objectives behind high-frequency monitoring as classified into three main groups: (i) improved understanding of the underlying hydrological, chemical, and biological processes (PU); (ii) quantification of true nutrient concentrations and loads (Q); and (iii) operational management, including evaluation of the effects of mitigation measures (M). The contributions in the special issue focus on the implementation of high-frequency monitoring within the broader context of policy making and management of water in Europe for support of EU directives such as the Water Framework Directive, the Groundwater Directive, and the Nitrates Directive. The overview presented enabled us to highlight the typical objectives encountered in the application of high-frequency monitoring and to reflect on future developments and research needs in this growing field of expertise.

  12. Waterborne nutrient flow through an upland-peatland watershed in Minnesota

    Treesearch

    Elon S. Verry; D.R. Timmons

    1982-01-01

    Water and nutrient flow were measured on a complex upland-peatland watershed in north central Minnesota. Annual water budgets for upland and peatland components and for the total watershed were developed. Nutrient input and output budgets were developed for each component on a seasonal basis, using net precipitation inputs, and an annual nutrient budget was developed...

  13. ZnO:Ag nanorods as efficient photocatalysts: Sunlight driven photocatalytic degradation of sulforhodamine B

    NASA Astrophysics Data System (ADS)

    Raji, R.; K. S., Sibi; K. G., Gopchandran

    2018-01-01

    Visible light responsive highly photocatalytic ZnO:Ag nanorods with varying Ag concentration were synthesized via co-precipitation method. X-ray diffraction analysis and high resolution transmission electron microscopy investigations confirmed the hexagonal wurtzite phase for these ZnO:Ag nanorods with preferential growth along the (101) plane. Raman shift and luminescence measurements indicated that the incorporation of Ag influences the lattice vibrational modes; there by causing distortion in lattice, inducing silent vibrational modes and emission behavior by quenching of both the band edge and visible emissions respectively. The photocatalytic performance of these nanorods as catalysts was tested by observing the photodegradation of a representative dye pollutant, viz., sulforhodamine B under sunlight irradiation. Photocatalytic performance was evaluated by determining the rate of reaction kinetics, photodegradation efficiency and mineralization efficiency. A high rate constant of 0.552 min-1, chemical oxygen demand value of 5.8 ppm and a mineralization efficiency of 94% were obtained when ZnO: Ag nanorods with an Ag content of 1.5 at.% were used as catalysts. The observed increase in photocatalytic efficiency with Ag content in ZnO:Ag nanorods is attributed to the electron scavenging action of silver, Schottky barrier between the Ag and ZnO interface and the better utilization of sunlight due to enhanced absorption due to plasmons in the visible region. BET analysis indicated that silver doping causes effective surface area of nanorods to increase, which in turn increases the photocatalytic efficiency. The possible mechanism for degradation of dye under sunlight irradiation is described with a schematic and the photostability of the ZnO:Ag nanorods were also tested through five repetitive cycles. This work suggests that the prepared ZnO:Ag nanorods are excellent reusable photocatalysts for the degradation of toxic organic waste in water, which causes severe

  14. Saharan dust nutrients promote Vibrio bloom formation in marine surface waters

    USGS Publications Warehouse

    Westrich, Jason R.; Ebling, Alina M.; Landing, William M.; Joyner, Jessica L.; Kemp, Keri M.; Griffin, Dale W.; Lipp, Erin K.

    2016-01-01

    Vibrio is a ubiquitous genus of marine bacteria, typically comprising a small fraction of the total microbial community in surface waters, but capable of becoming a dominant taxon in response to poorly characterized factors. Iron (Fe), often restricted by limited bioavailability and low external supply, is an essential micronutrient that can limit Vibrio growth. Vibrio species have robust metabolic capabilities and an array of Fe-acquisition mechanisms, and are able to respond rapidly to nutrient influx, yet Vibrio response to environmental pulses of Fe remains uncharacterized. Here we examined the population growth of Vibrioafter natural and simulated pulses of atmospherically transported Saharan dust, an important and episodic source of Fe to tropical marine waters. As a model for opportunistic bacterial heterotrophs, we demonstrated that Vibrio proliferate in response to a broad range of dust-Fe additions at rapid timescales. Within 24 h of exposure, strains of Vibrio cholerae and Vibrio alginolyticus were able to directly use Saharan dust–Fe to support rapid growth. These findings were also confirmed with in situ field studies; arrival of Saharan dust in the Caribbean and subtropical Atlantic coincided with high levels of dissolved Fe, followed by up to a 30-fold increase of culturable Vibrio over background levels within 24 h. The relative abundance of Vibrio increased from ∼1 to ∼20% of the total microbial community. This study, to our knowledge, is the first to describe Vibrio response to Saharan dust nutrients, having implications at the intersection of marine ecology, Fe biogeochemistry, and both human and environmental health.

  15. Integrating seasonal information on nutrients and benthic algal biomass into stream water quality monitoring

    USGS Publications Warehouse

    Konrad, Christopher P.; Munn, Mark D.

    2016-01-01

    Benthic chlorophyll a (BChl a) and environmental factors that influence algal biomass were measured monthly from February through October in 22 streams from three agricultural regions of the United States. At-site maximum BChl a ranged from 14 to 406 mg/m2 and generally varied with dissolved inorganic nitrogen (DIN): 8 out of 9 sites with at-site median DIN >0.5 mg/L had maximum BChl a >100 mg/m2. BChl aaccrued and persisted at levels within 50% of at-site maximum for only one to three months. No dominant seasonal pattern for algal biomass accrual was observed in any region. A linear model with DIN, water surface gradient, and velocity accounted for most of the cross-site variation in maximum chlorophyll a(adjusted R2 = 0.7), but was no better than a single value of DIN = 0.5 mg/L for distinguishing between low and high-biomass sites. Studies of nutrient enrichment require multiple samples to estimate algal biomass with sufficient precision given the magnitude of temporal variability of algal biomass. An effective strategy for regional stream assessment of nutrient enrichment could be based on a relation between maximum BChl a and DIN based on repeat sampling at sites selected to represent a gradient in nutrients and application of the relation to a larger number of sites with synoptic nutrient information.

  16. NREL: News - NREL Researchers Use Sunlight to Power Laser

    Science.gov Websites

    Renewable Energy Laboratory (NREL) and the University of Chicago powered a laser with concentrated sunlight and University of Chicago researchers developed the secondary concentrator used for the solar laser as

  17. Nutrient discharge from China’s aquaculture industry and associated environmental impacts

    NASA Astrophysics Data System (ADS)

    Zhang, Ying; Bleeker, Albert; Liu, Junguo

    2015-04-01

    China’s aquaculture industry accounts for the largest share of the world’s fishery production, and provides a principal source of protein for the nation’s booming population. However, the environmental effects of the nutrient loadings produced by this industry have not been systematically studied or reviewed. Few quantitative estimates exist for nutrient discharge from aquaculture and the resultant nutrient enrichment in waters and sediments. In this paper, we evaluate nutrient discharge from aquacultural systems into aquatic ecosystems and the resulting nutrient enrichment of water and sediments, based on data from 330 cases in 51 peer-reviewed publications. Nitrogen use efficiency ranged from 11.7% to 27.7%, whereas phosphorus use efficiency ranged from 8.7% to 21.2%. In 2010, aquacultural nutrient discharges into Chinese aquatic ecosystems included 1044 Gg total nitrogen (184 Gg N from mariculture; 860 Gg N freshwater culture) and 173 Gg total phosphorus (22 Gg P from mariculture; 151 Gg P from freshwater culture). Water bodies and sediments showed high levels of nutrient enrichment, especially in closed pond systems. However, this does not mean that open aquacultural systems have smaller nutrient losses. Improvement of feed efficiency in cage systems and retention of nutrients in closed systems will therefore be necessary. Strategies to increase nutrient recycling, such as integrated multi-trophic aquaculture, and social measures, such as subsidies, should be increased in the future. We recommend the recycling of nutrients in water and sediments by hybrid agricultural-aquacultural systems and the adoption of nutrient use efficiency as an indicator at farm or regional level for the sustainable development of aquaculture; such indicators; together with water quality indicators, can be used to guide evaluations of technological, policy, and economic approaches to improve the sustainability of Chinese aquaculture.

  18. Subterranean Groundwater Nutrient Input to Coastal Oceans and Coral Reef Sustainability

    NASA Astrophysics Data System (ADS)

    Paytan, A.; Street, J. H.

    2003-12-01

    Coral reefs are often referred to as the tropical rain forests of the oceans because of their high productivity and biodiversity. Recent observations in coral reefs worldwide have shown clear degradation in water quality and coral reef health and diversity. The implications of this are severe, including tremendous economic losses mostly though fishing and tourism. Nutrient loading has been implicated as one possible cause for the ecosystem decline. A previously unappreciated potential source of nutrient loading is submarine ground water discharge (SGW). Ground water in many cases has high nutrient content from sewage pollution and fertilizer application for agriculture and landscaping. To better understand the effect of this potential source of nutrient input and degrading water quality, we are exploring the contribution of SGW to the nutrient levels in coral reefs. A key to this approach is determining the amount and source of SGW that flows into the coast as well as its nutrient concentrations. The SGW flux and associated input of chemical dissolved load (nutrient, DOC, trace elements and other contaminants) is quantified using naturally occurring Ra isotopes. Radium isotopes have been shown to be excellent tracers for SGW inputs into estuaries and coastal areas (Moore, 1996; Hussain et al., 1999; Kerst et al., 2000). Measurements of Ra activity within the coral reef, the lagoons and the open waters adjacent to the reef provide valuable information regarding the input of Ra as well as nutrients and possibly pollutant from groundwater discharge. Through this analysis the effect of SGD on the delicate carbon and nutrient balance of the fragile coral reef ecosystem could be evaluated. In addition to quantifying the contribution of freshwater to the nutrient mass balance in the reef, information regarding the length of time a water parcel has remained in the near-shore region over the reef can be estimated using the Ra isotope quartet.

  19. Watershed modeling and monitoring for assessing nutrient ...

    EPA Pesticide Factsheets

    Presentation for the American Water Works Association Water Sustainability Conference. The presentation highlights latest results from water quality trading research conducted by ORD using the East Fork Watershed in Southwestern Ohio as a case study. The watershed has a nutrient enrichment problem that is creating harmful algal blooms in a reservoir used for drinking water and recreation. Innovative modeling and monitoring is combined to understand how to best manage this water quality problem and costs associated with this endeavor. The presentation will provide an overview of the water quality trading feasibility research. The research includes the development and evaluation of innovative modeling and monitoring approaches to manage watersheds for nutrient pollution using a whole systems approach.

  20. Photosynthesis, photoprotection, and growth of shade-tolerant tropical tree seedlings under full sunlight.

    PubMed

    Krause, G Heinrich; Winter, Klaus; Matsubara, Shizue; Krause, Barbara; Jahns, Peter; Virgo, Aurelio; Aranda, Jorge; García, Milton

    2012-09-01

    High solar radiation in the tropics is known to cause transient reduction in photosystem II (PSII) efficiency and CO(2) assimilation in sun-exposed leaves, but little is known how these responses affect the actual growth performance of tropical plants. The present study addresses this question. Seedlings of five woody neotropical forest species were cultivated under full sunlight and shaded conditions. In full sunlight, strong photoinhibition of PSII at midday was documented for the late-successional tree species Ormosia macrocalyx and Tetragastris panamensis and the understory/forest gap species, Piper reticulatum. In leaves of O. macrocalyx, PSII inhibition was accompanied by substantial midday depression of net CO(2) assimilation. Leaves of all species had increased pools of violaxanthin-cycle pigments. Other features of photoacclimation, such as increased Chl a/b ratio and contents of lutein, β-carotene and tocopherol varied. High light caused strong increase of tocopherol in leaves of T. panamensis and another late-successional species, Virola surinamensis. O. macrocalyx had low contents of tocopherol and UV-absorbing substances. Under full sunlight, biomass accumulation was not reduced in seedlings of T. panamensis, P. reticulatum, and V. surinamensis, but O. macrocalyx exhibited substantial growth inhibition. In the highly shade-tolerant understory species Psychotria marginata, full sunlight caused strongly reduced growth of most individuals. However, some plants showed relatively high growth rates under full sun approaching those of seedlings at 40 % ambient irradiance. It is concluded that shade-tolerant tropical tree seedlings can achieve efficient photoacclimation and high growth rates in full sunlight.

  1. Occupational sunlight exposure and melanoma in the U.S. Navy.

    PubMed

    Garland, F C; White, M R; Garland, C F; Shaw, E; Gorham, E D

    1990-01-01

    Melanoma is the second most common cancer, after testicular cancer, in males in the U.S. Navy. A wide range of occupations with varying exposures to sunlight and other possible etiologic agents are present in the Navy. Person-years at risk and cases of malignant melanoma were ascertained using computerized service history and inpatient hospitalization files maintained at the Naval Health Research Center. A total of 176 confirmed cases of melanoma were identified in active-duty white male enlisted Navy personnel during 1974-1984. Risk of melanoma was determined for individual occupations and for occupations grouped by review of job descriptions into three categories of sunlight exposure: (1) indoor, (2) outdoor, or (3) indoor and outdoor. Compared with the U.S. civilian population, personnel in indoor occupations had a higher age-adjusted incidence rate of melanoma, i.e., 10.6 per 100,000 (p = .06). Persons who worked in occupations that required spending time both indoors and outdoors had the lowest rate, i.e., 7.0 per 100,000 (p = .06). Incidence rates of melanoma were higher on the trunk than on the more commonly sunlight-exposed head and arms. Two single occupations were found to have elevated rates of melanoma: (1) aircrew survival equipmentman, SIR = 6.8 (p less than .05); and (2) engineman, SIR = 2.8 (p less than .05). However, there were no cases of melanoma or no excess risk in occupations with similar job descriptions. Findings on the anatomical site of melanoma from this study suggest a protective role for brief, regular exposure to sunlight and fit with recent laboratory studies that have shown vitamin D to suppress growth of malignant melanoma cells in tissue culture. A mechanism is proposed in which vitamin D inhibits previously initiated melanomas from becoming clinically apparent.

  2. The formation processes of phytoplankton growth and decline in mesoscale eddies in the western North Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Chang, Yu-Lin; Miyazawa, Yasumasa; Oey, Lie-Yauw; Kodaira, Tsubasa; Huang, Shihming

    2017-05-01

    In this study, we investigate the processes of phytoplankton growth and decline in mesoscale eddies in the western North Pacific Ocean based on the in situ chlorophyll data obtained from 52 cruises conducted by the Japan Meteorological Agency together with idealized numerical simulations. Both the observation and model results suggest that chlorophyll/phytoplankton concentrations are higher in cold than in warm eddies in near-surface water (z > -70 m). In the idealized simulation, the isopycnal movements associated with upwelling/downwelling transport phytoplankton and nutrients to different vertical depths during eddy formation (stage A). Phytoplankton and nutrients in cold eddies is transported toward shallower waters while those in warm eddies move toward deeper waters. In the period after the eddy has formed (stage B), sunlight and initially upwelled nutrients together promote the growth of phytoplankton in cold eddies. Phytoplankton in warm eddies decays due to insufficient sunlight in deeper waters. In stage B, upwelling and downwelling coexist in both warm and cold eddies, contributing nearly equally to vertical displacement. The upwelling/downwelling-induced nitrate flux accounts for a small percentage (˜3%) of the total nitrate flux in stage B. The vertical velocity caused by propagating eddies, therefore, is not the primary factor causing differences in phytoplankton concentrations between stage-B warm and cold eddies.

  3. Sustainability of High Intensity Forest Management with Respect to Water QuaIity and Site Nutrient Reserves

    Treesearch

    Virginia R. Tolbert; Carl C. Trettin; Dale W. Johnson; John W. Parsons; Allan E. Houston; David A. Mays

    2001-01-01

    Ensuring sustainability of intensively managed woody crops requires determining soil and water quality effects using a combination of field data and modeling projections. Plot- and catchrnent-scale research, models, and meta-analyses are addressing nutrient availability, site quality, and measures to increase short-rotation woody crop (SRWC) productivity and site...

  4. Soil, water and nutrient conservation in mountain farming systems: case-study from the Sikkim Himalaya.

    PubMed

    Sharma, E; Rai, S C; Sharma, R

    2001-02-01

    The Khanikhola watershed in Sikkim is agrarian with about 50% area under rain-fed agriculture representing the conditions of the middle mountains all over the Himalaya. The study was conducted to assess overland flow, soil loss and subsequent nutrient losses from different land uses in the watershed, and identify biotechnological inputs for management of mountain farming systems. Overland flow, soil and nutrient losses were very high from open agricultural (cropped) fields compared to other land uses, and more than 72% of nutrient losses were attributable to agriculture land use. Forests and large cardamom agroforestry conserved more soil compared to other land uses. Interventions, like cultivation of broom grass upon terrace risers, N2-fixing Albizia trees for maintenance of soil fertility and plantation of horticulture trees, have reduced the soil loss (by 22%). Soil and water conservation values (> 80%) of both large cardamom and broom grass were higher compared to other crops. Use of N2-fixing Albizia tree in large cardamom agroforestry and croplands contributed to soil fertility, and increased productivity and yield. Bio-composting of farm resources ensured increase in nutrient availability specially phosphorus in cropped areas. Agricultural practices in mountain areas should be strengthened with more agroforestry components, and cash crops like large cardamom and broom grass in agroforestry provide high economic return and are hydroecologically sustainable.

  5. PRKCZ methylation is associated with sunlight exposure in a North American but not a Mediterranean population.

    PubMed

    Aslibekyan, Stella; Dashti, Hassan S; Tanaka, Toshiko; Sha, Jin; Ferrucci, Luigi; Zhi, Degui; Bandinelli, Stefania; Borecki, Ingrid B; Absher, Devin M; Arnett, Donna K; Ordovas, Jose M

    2014-11-01

    Sunlight exposure has been shown to alter DNA methylation patterns across several human cell-types, including T-lymphocytes. Since epigenetic changes establish gene expression profiles, changes in DNA methylation induced by sunlight exposure warrant investigation. The purpose of this study was to assess the effects of sunlight exposure on CD4+ T-cell methylation patterns on an epigenome-wide scale in a North American population of European origin (n=991). In addition, we investigated the genetic contribution to epigenetic variation (methylQTL). We used linear regression to test the associations between methylation scores at 461,281 cytosine-phosphate-guanine (CpG) sites and sunlight exposure, followed by a genome-wide association analysis (methylQTL) to test for associations between methylation at the top CpG locus and common genetic variants, assuming an additive genetic model. We observed an epigenome-wide significant association between sunlight exposure and methylation status at cg26930596 (p=9.2×10(-8)), a CpG site located in protein kinase C zeta (PRKCZ), a gene previously shown to be entrained by light. MethylQTL analysis resulted in significant associations between cg26930596 and two intergenic single nucleotide polymorphisms on chromosome 3, rs4574216 (p=1.5×10(-10)) and rs4405858 (p=1.9×10(-9)). These common genetic variants reside downstream of WWTR1, a transcriptional co-activator of PRKCZ. Associations observed in the North American population, however, did not replicate in an independent Mediterranean cohort. Our preliminary results support the role of sunlight exposure in epigenetic processes, and lay the groundwork for future studies of the molecular link between sunlight and physiologic processes such as tumorigenesis and metabolism.

  6. A comparison of observed and analytically derived remote sensing penetration depths for turbid water

    NASA Technical Reports Server (NTRS)

    Morris, W. D.; Usry, J. W.; Witte, W. G.; Whitlock, C. H.; Guraus, E. A.

    1981-01-01

    The depth to which sunlight will penetrate in turbid waters was investigated. The tests were conducted in water with a single scattering albedo range, and over a range of solar elevation angles. Two different techniques were used to determine the depth of light penetration. It showed little change in the depth of sunlight penetration with changing solar elevation angle. A comparison of the penetration depths indicates that the best agreement between the two methods was achieved when the quasisingle scattering relationship was not corrected for solar angle. It is concluded that sunlight penetration is dependent on inherent water properties only.

  7. Artificial Soil With Build-In Plant Nutrients

    NASA Technical Reports Server (NTRS)

    Ming, Douglas W.; Allen, Earl; Henninger, Donald; Golden, D. C.

    1995-01-01

    Nutrients contained in sandlike material. Artificial soil provides nutrients to plants during several growing seasons without need to add fertilizer or nutrient solution. When watered, artificial soil slowly releases all materials a plant needs to grow. Developed as medium for growing crops in space. Also used to grow plants on Earth under controlled conditions or even to augment natural soil.

  8. Biological Effects of Sunlight, Ultraviolet Radiation, Visible Light, Infrared Radiation and Vitamin D for Health.

    PubMed

    Holick, Michael F

    2016-03-01

    Humans evolved in sunlight and had depended on sunlight for its life giving properties that was appreciated by our early ancestors. However, for more than 40 years the lay press and various medical and dermatology associations have denounced sun exposure because of its association with increased risk for skin cancer. The goal of this review is to put into perspective the many health benefits that have been associated with exposure to sunlight, ultraviolet A (UVA) ultraviolet B (UVB), visible and infrared radiation. Copyright© 2016 International Institute of Anticancer Research (Dr. John G. Delinassios), All rights reserved.

  9. Approaches for Development of Nutrient Criteria in Oregon Estuaries

    EPA Science Inventory

    Development of nutrient criteria for all water body types of the US remains a top priority for EPA. Estuaries in the Pacific Northwest receive nutrients from both the watershed and the coastal ocean, and thus are particularly complex systems in which to establish water quality c...

  10. A Worldwide Plan to Eliminate Global Warming, Air Pollution, and Energy Instability With Wind, Water, and Sunlight (WWS)

    NASA Astrophysics Data System (ADS)

    Jacobson, M. Z.; Delucchi, M. A.

    2011-12-01

    Global warming, air pollution mortality, and energy insecurity are three of the most significant problems facing the world today. This talk discusses a plan to solve the problems by powering 100% of the world's energy for all purposes, including electricity, transportation, industrial processes, and heating/cooling, with wind, water, and sunlight (WWS) within the next 20-40 years. It reviews and ranks major proposed energy solutions to global warming, air pollution mortality, and energy insecurity while considering other impacts of the proposed solutions, such as on water supply, land use, resource availability, reliability, wildlife, and catastrophic risk. It then evaluates a scenario for powering the world on the energy options determined to be the best while also considering materials, transmission infrastructure, costs, and politics. The study concludes that powering the world with WWS electric power technologies and a conversion from combustion to electricity and electrolytically-produced hydrogen is the cleanest and safest method of solving these problems. Due to the efficiency of electricity, such a conversion reduces world power demand by 30%. Methods of ensuring reliability of WWS electric power are available and will be demonstrated. We also conclude that neither liquid biofuels for transportation (including ethanol or biodiesel from any source), solid biofuels for home heating and cooking, biomass for electricity, conventional or fracked natural gas for electricity or transportation, nuclear power, nor coal with carbon capture (clean coal) are nearly so clean or safe as WWS technologies so are not recommended, either as bridge technologies or in the long term. Our plan calls for all new energy to be supplied by WWS-electricity-hydrogen resources no later than 2030 and all existing non-WWS infrastructure to be eliminated no later than 2050. We find that the plan is technically and economically feasible but politically challenging.

  11. Freeze concentration for enrichment of nutrients in yellow water from no-mix toilets.

    PubMed

    Gulyas, H; Bruhn, P; Furmanska, M; Hartrampf, K; Kot, K; Lüttenberg, B; Mahmood, Z; Stelmaszewska, K; Otterpohl, R

    2004-01-01

    Separately collected urine ("yellow water") can be utilized as fertilizer. In order to decrease storage volumes and energy consumption for yellow water transport to fields, enrichment of nutrients in yellow water has to be considered. Laboratory-scale batch freeze concentration of yellow water has been tested in ice-front freezing apparatus: a stirred vessel and a falling film freeze concentrator (coolant temperatures: -6 to -16 degrees C). With progressing enrichment of the liquid concentrate, the frozen ice was increasingly contaminated with yellow water constituents (ammonia, total nitrogen, total phosphorus, TOC, and salts determined as conductivity). The higher the initial salinity of the yellow water and the lower the mechanical agitation of the liquid phase contacting the growing ice front, the more the frozen ice was contaminated. The results indicate, that in ice-front freezing devices multistage processes are necessary, i.e. the melted ice phase has to be purified (and the concentrates must be further enriched) in a second or even in a third stage. Energy consumption of this process is very high. However, technical scale suspension freeze concentration is reasonable in centralized ecological sanitation schemes if the population exceeds 0.5 million and distance of yellow water transportation to fields is more than 80 km.

  12. Estimation of Shallow Groundwater Discharge and Nutrient Load into a River

    Treesearch

    Ying Ouyang

    2012-01-01

    Pollution of rivers with excess nutrients due to groundwater discharge, storm water runoff, surface loading,and atmospheric deposition is an increasing environmental concern worldwide. While the storm water runoff and surface loading of nutrients into many rivers have been explored in great detailed, the groundwater discharge of nutrients into the rivers has not yet...

  13. Soil Microbial Properties and Plant Growth Responses to Carbon and Water Addition in a Temperate Steppe: The Importance of Nutrient Availability

    PubMed Central

    Guo, Chengyuan; Wang, Renzhong; Xiao, Chunwang

    2012-01-01

    Background Global climatic change is generally expected to stimulate net primary production, and consequently increase soil carbon (C) input. The enhanced C input together with potentially increased precipitation may affect soil microbial processes and plant growth. Methodology/Principal Findings To examine the effects of C and water additions on soil microbial properties and plant growth, we conducted an experiment lasting two years in a temperate steppe of northeastern China. We found that soil C and water additions significantly affected microbial properties and stimulated plant growth. Carbon addition significantly increased soil microbial biomass and activity but had a limited effect on microbial community structure. Water addition significantly increased soil microbial activity in the first year but the response to water decreased in the second year. The water-induced changes of microbial activity could be ascribed to decreased soil nitrogen (N) availability and to the shift in soil microbial community structure. However, no water effect on soil microbial activity was visible under C addition during the two years, likely because C addition alleviated nutrient limitation of soil microbes. In addition, C and water additions interacted to affect plant functional group composition. Water addition significantly increased the ratio of grass to forb biomass in C addition plots but showed only minor effects under ambient C levels. Our results suggest that soil microbial activity and plant growth are limited by nutrient (C and N) and water availability, and highlight the importance of nutrient availability in modulating the responses of soil microbes and plants to potentially increased precipitation in the temperate steppe. Conclusions/Significance Increased soil C input and precipitation would show significant effects on soil microbial properties and plant growth in the temperate steppe. These findings will improve our understanding of the responses of soil microbes

  14. [Sediment-water flux and processes of nutrients and gaseous nitrogen release in a China River Reservoir].

    PubMed

    Chen, Zhu-hong; Chen, Neng-wang; Wu, Yin-qi; Mo, Qiong-li; Zhou, Xing-peng; Lu, Ting; Tian, Yun

    2014-09-01

    The key processes and fluxes of nutrients (N and P) and gaseous N (N2 and N2O) across the sediment-water interface in a river reservoir (Xipi) of the Jiulong River watershed in southeast China were studied. Intact core sediment incubation of nutrients exchange, in-situ observation and lab incubation of excess dissolved N2 and N2O (products of nitrification, denitrification and Anammox), and determination of physiochemical and microbe parameters were carried out in 2013 for three representative sites along the lacustrine zone of the reservoir. Results showed that ammonium and phosphate were generally released from sediment to overlying water [with averaged fluxes of N (479.8 ± 675.4) mg. (m2. d)-1 and P (4. 56 ± 0.54) mg. (m2 d) -1] , while nitrate and nitrite diffused into the sediment. Flood events in the wet season could introduce a large amount of particulate organic matter that would be trapped by the dam reservoir, resulting in the high release fluxes of ammonium and phosphate observed in the following low-flow season. No clear spatial variation of sediment nutrient release was found in the lacustrine zone of the reservoir. Gaseous N release was dominated by excess dissolved N2 (98% of total), and the N2 flux from sediment was (15.8 ± 12. 5) mg (m2. d) -1. There was a longitudinal and vertical variation of excess dissolved N2, reflecting the combined results of denitrification and Anammox occurring in anoxic sediment and fluvial transport. Nitrification mainly occurred in the lower lacustrine zone, and the enrichment of N2O was likely regulated by the ratio of ammonium to DIN in water.

  15. Data-driven nutrient analysis and reality check: Human inputs, catchment delivery and management effects

    NASA Astrophysics Data System (ADS)

    Destouni, G.

    2017-12-01

    Measures for mitigating nutrient loads to aquatic ecosystems should have observable effects, e.g, in the Baltic region after joint first periods of nutrient management actions under the Baltic Sea Action Plan (BASP; since 2007) and the EU Water Framework Directive (WFD; since 2009). Looking for such observable effects, all openly available water and nutrient monitoring data since 2003 are compiled and analyzed for Sweden as a case study. Results show that hydro-climatically driven water discharge dominates the determination of waterborne loads of both phosphorus and nitrogen. Furthermore, the nutrient loads and water discharge are all similarly well correlated with the ecosystem status classification of Swedish water bodies according to the WFD. Nutrient concentrations, which are hydro-climatically correlated and should thus reflect human effects better than loads, have changed only slightly over the study period (2003-2013) and even increased in moderate-to-bad status waters, where the WFD and BSAP jointly target nutrient decreases. These results indicate insufficient distinction and mitigation of human-driven nutrient components by the internationally harmonized applications of both the WFD and the BSAP. Aiming for better general identification of such components, nutrient data for the large transboundary catchments of the Baltic Sea and the Sava River are compared. The comparison shows cross-regional consistency in nutrient relationships to driving hydro-climatic conditions (water discharge) for nutrient loads, and socio-economic conditions (population density and farmland share) for nutrient concentrations. A data-driven screening methodology is further developed for estimating nutrient input and retention-delivery in catchments. Its first application to nested Sava River catchments identifies characteristic regional values of nutrient input per area and relative delivery, and hotspots of much larger inputs, related to urban high-population areas.

  16. The Brazil Eucalyptus Potential Productivity Project: Influence of water, nutrients and stand uniformity on wood production

    Treesearch

    Jose Luiz Stape; Dan Binkley; Michael G. Ryan; Sebastiao Fonseca; Rodolfo A. Loos; Ernesto N. Takahashi; Claudio R. Silva; Sergio R. Silva; Rodrigo E. Hakamada; Jose Mario de A. Ferreira; Augusto M. N. Lima; Jose Luiz Gava; Fernado P. Leite; Helder B. Andrade; Jacyr M. Alves; Gualter G. C. Silva; Moises R. Azevedo

    2010-01-01

    We examined the potential growth of clonal Eucalyptus plantations at eight locations across a 1000+ km gradient in Brazil by manipulating the supplies of nutrients and water, and altering the uniformity of tree sizes within plots. With no fertilization or irrigation, mean annual increments of stem wood were about 28% lower (16.2 Mg...

  17. Direct and Indirect Phototransformation of Graphene Oxide in Sunlight

    EPA Science Inventory

    Direct and indirect (with added H202 that serves as OH precursor) photoreactions of grapheme oxide (GO) were examined under sunlight exposure. The results indicate that GO photoreacts under both conditions, leading to significant alterations in GO's physicochemical properties. In...

  18. Watershed modeling and monitoring for assessing nutrient trading viability and increasing the adoption of nutrient management practices

    EPA Science Inventory

    Presentation for the American Water Works Association Water Sustainability Conference. The presentation highlights latest results from water quality trading research conducted by ORD using the East Fork Watershed in Southwestern Ohio as a case study. The watershed has a nutrient ...

  19. Water hyacinth removes arsenic from arsenic-contaminated drinking water.

    PubMed

    Misbahuddin, Mir; Fariduddin, Atm

    2002-01-01

    Water hyacinth (Eichhornia crassipes) removes arsenic from arsenic-contaminated drinking water. This effect depends on several factors, such as the amount of water hyacinth, amount of arsenic present in the water, duration of exposure, and presence of sunlight and air. On the basis of the present study, the authors suggest that water hyacinth is useful for making arsenic-contaminated drinking water totally arsenic free. Water hyacinth provides a natural means of removing arsenic from drinking water at the household level without monetary cost.

  20. PRKCZ methylation is associated with sunlight exposure in a North American but not a Mediterranean population

    PubMed Central

    Aslibekyan, Stella; Dashti, Hassan S.; Tanaka, Toshiko; Sha, Jin; Ferrucci, Luigi; Zhi, Degui; Bandinelli, Stefania; Borecki, Ingrid B.; Absher, Devin M.; Arnett, Donna K.; Ordovas, Jose M.

    2015-01-01

    Sunlight exposure has been shown to alter DNA methylation patterns across several human cell-types, including T-lymphocytes. Since epigenetic changes establish gene expression profiles, changes in DNA methylation induced by sunlight exposure warrant investigation. The purpose of this study was to assess the effects of sunlight exposure on CD4+ T-cell methylation patterns on an epigenome-wide scale in a North American population of European origin (n = 991). In addition, we investigated the genetic contribution to epigenetic variation (methylQTL). We used linear regression to test the associations between methylation scores at 461 281 cytosine-phosphate-guanine (CpG) sites and sunlight exposure, followed by a genome-wide association analysis (methylQTL) to test for associations between methylation at the top CpG locus and common genetic variants, assuming an additive genetic model. We observed an epigenome-wide significant association between sunlight exposure and methylation status at cg26930596 (p = 9.2 × 10−8), a CpG site located in protein kinase C zeta (PRKCZ), a gene previously shown to be entrained by light. MethylQTL analysis resulted in significant associations between cg26930596 and two intergenic single nucleotide polymorphisms on chromosome 3, rs4574216 (p = 1.5 × 10−10) and rs4405858 (p = 1.9 × 10−9). These common genetic variants reside downstream of WWTR1, a transcriptional co-activator of PRKCZ. Associations observed in the North American population, however, did not replicate in an independent Mediterranean cohort. Our preliminary results support the role of sunlight exposure in epigenetic processes, and lay the groundwork for future studies of the molecular link between sunlight and physiologic processes such as tumorigenesis and metabolism. PMID:25075435

  1. Biomass production and nutrient removal potential of water hyacinth cultured in sewage effluent

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reddy, K.R.; Hueston, F.M.; McKinn, T.

    1985-05-01

    Growth and nutrient uptake of water hyacinth (Eichhornia crassipes (Mart Solms)) cultured in sewage effluent were measured over a period of one year in a prototype wastewater treatment system which has been in operation at Walt Disney World near Orlando, Florida. Annual productivity of water hyacinth cultured in primary sewage effluent (Channel II) was found to be in the range of 5 to 27 g dry wt/m/sup 2/ day (23.6 dry tons/acre yr). Average growth rate during the months of May through October 1982 for hyacinth cultured in Channel II (primary sewage effluent) and Channel I (treated primary sewage effluentmore » leaving Channel II) was about 16 g dry wt/m/sup 2/ (27 dry tons/acre yr), compared to the growth rate of 13 g dry wt/m/sup 2/ (22 dry tons/acre yr) for hyacinths cultured in secondary sewage effluent. Plants cultured in secondary sewage effluent generally had longer roots than the plants cultured in primary sewage effluent. A significant relationship was observed between the growth rate of hyacinth and the solar radiation. N and P concentration of the plant tissue were higher in the hyacinths cultured during winter months compared to the plants grown in summer months. Average N and P concentration of the plants cultured im primary sewage effluent were found to be 3.7% N and 0.94% P, respectively, while the plants cultured in secondary sewage effluent had a total N and P content of 2.8% N and 0.79% P. Nutrient ratios of the major plant nurtrients were found to be approximately the same as the nutrient ratios in the sewage effluent. Annual N and P uptake rates of hyacinth cultured in sewage effluent were found to be in the range of 1176 to 1193 kg N/ha yr and 321 to 387 kg P/ha yr, respectively.« less

  2. Sunlight persistence and rainfastness of spray-dried formulations of baculovirus isolated from Anagrapha falcifera (Lepidoptera: Noctuidae).

    PubMed

    Tamez-Guerra, P; McGuire, M R; Behle, R W; Hamm, J J; Sumner, H R; Shasha, B S

    2000-04-01

    Nuclear polyhedrosis viruses such as the one isolated from the celery looper, Anagrapha falcifera (Kirby) (AfMNPV), have the potential to be successful bioinsecticides if improved formulations can prevent rapid loss of insecticidal activity from environmental conditions such as sunlight and rainfall. We tested 16 spray-dried formulations of AfMNPV to determine the effect of different ingredients (e.g., lignin, corn flour, and so on) on insecticidal activity after simulated rain and simulated sunlight (at Peoria, IL) and natural sunlight exposures (at Tifton, GA). The most effective formulation contained pregelatinized corn flour and potassium lignate, which retained more than half of its original activity after 5 cm of simulated rain, and almost full activity after 8 h of simulated sunlight. In Georgia, formulations made with and without lignin were compared for persistence of insecticidal activity when exposed to natural sunlight. In addition, the effect of fluorescent brighteners as formulation components and spray tank additives was tested. Results showed that the formulations with lignin had more insecticidal activity remaining after sunlight exposure than formulations without lignin. The inclusion of brighteners in the formulation did not improve initial activity or virus persistence. However, a 1% tank mix significantly enhanced activity and improved persistence. Scanning electron micrographs revealed discreet particles, and transmission electron micrographs showed virus embedded within microgranules. Results demonstrated that formulations made with natural ingredients could improve persistence of virus-based biopesticides.

  3. Modeling Water and Nutrient Transport through the Soil-Root-Canopy Continuum: Explicitly Linking the Below- and Above-Ground Processes

    NASA Astrophysics Data System (ADS)

    Kumar, P.; Quijano, J. C.; Drewry, D.

    2010-12-01

    Vegetation roots provide a fundamental link between the below ground water and nutrient dynamics and above ground canopy processes such as photosynthesis, evapotranspiration and energy balance. The “hydraulic architecture” of roots, consisting of the structural organization of the root system and the flow properties of the conduits (xylem) as well as interfaces with the soil and the above ground canopy, affect stomatal conductance thereby directly linking them to the transpiration. Roots serve as preferential pathways for the movement of moisture from wet to dry soil layers during the night, both from upper soil layer to deeper layers during the wet season (‘hydraulic descent’) and vice-versa (‘hydraulic lift’) as determined by the moisture gradients. The conductivities of transport through the root system are significantly, often orders of magnitude, larger than that of the surrounding soil resulting in movement of soil-moisture at rates that are substantially larger than that through the soil. This phenomenon is called hydraulic redistribution (HR). The ability of the deep-rooted vegetation to “bank” the water through hydraulic descent during wet periods for utilization during dry periods provides them with a competitive advantage. However, during periods of hydraulic lift these deep-rooted trees may facilitate the growth of understory vegetation where the understory scavenges the hydraulically lifted soil water. In other words, understory vegetation with relatively shallow root systems have access to the banked deep-water reservoir. These inter-dependent root systems have a significant influence on water cycle and ecosystem productivity. HR induced available moisture may support rhizosphere microbial and mycorrhizal fungi activities and enable utilization of heterogeneously distributed water and nutrient resources To capture this complex inter-dependent nutrient and water transport through the soil-root-canopy continuum we present modeling

  4. Landfill leachate--a water and nutrient resource for algae-based biofuels.

    PubMed

    Edmundson, Scott J; Wilkie, Ann C

    2013-01-01

    There is a pressing need for sustainable renewable fuels that do not negatively impact food and water resources. Algae have great potential for the production of renewable biofuels but require significant water and fertilizer resources for large-scale production. Municipal solid waste (MSW) landfill leachate (LL) was evaluated as a cultivation medium to reduce both water and elemental fertilizer demands of algae cultivation. Daily growth rate and cell yield of two isolated species of algae (Scenedesmus cf. rubescens and Chlorella cf. ellipsoidea) were cultivated in MSW LL and compared with Bold's Basal Medium (BBM). Results suggest that LL can be used as a nutrient resource and medium for the cultivation of algae biomass. S. cf. rubescens grew well in 100% LL, when pH was regulated, with a mean growth rate and cell yield 91.2% and 92.8% of those observed in BBM, respectively. S. cf. rubescens was more adaptable than C. cf. ellipsoidea to the LL tested. The LL used in this study supported a maximum volumetric productivity of 0.55 g/L/day of S. cf. rubescens biomass. The leachate had sufficient nitrogen to supply 17.8 g/L of algae biomass, but was limited by total phosphorus. Cultivation of algae on LL offsets both water and fertilizer consumption, reducing the environmental footprint and increasing the potential sustainability of algae-based biofuels.

  5. Analysis of daylight performance of solar light pipes influenced by size and shape of sunlight captures

    NASA Astrophysics Data System (ADS)

    Wu, Yanpeng; Jin, Rendong; Zhang, Wenming; Liu, Li; Zou, Dachao

    2009-11-01

    Experimental investigations on three different sunlight captures with diameter 150mm, 212mm, 300mm were carried out under different conditions such as sunny conditions, cloudy conditions and overcast conditions and the two different size solar light pipes with diameter 360mm and 160mm under sunny conditions. The illuminance in the middle of the sunlight capture have relationship with its size, but not linear. To improve the efficiency of the solar light pipes, the structure and the performance of the sunlight capture must be enhanced. For example, University of Science and Technology Beijing Gymnasium, Beijing 2008 Olympic events of Judo and Taekwondo, 148 solar light pipes were installed with the diameter 530mm for each light pipe. Two sunlight captures with different shape were installed and tested. From the measuring results of the illuminance on the work plane of the gymnasium, the improvement sunlight captures have better effects with the size of augmenting and the machining of the internal surface at the same time, so that the refraction increased and the efficiency of solar light pipes improved. The better effects of supplementary lighting for the gymnasium have been achieved.

  6. Fate and Transport of Hydrophobic and Hydrophilic Cyanotoxins through Granular Activated Carbons (abstract)

    EPA Science Inventory

    Cyanobacteria (also known as “blue-green algae”) are microscopic organisms that are found in most bodies of water, which can multiply to form harmful algal blooms (HABs) under favorable conditions (i.e., rich nutrients, strong sunlight, and high temperature). Many genera of cyano...

  7. Assessment of nutrient loadings of a large multipurpose prairie reservoir

    NASA Astrophysics Data System (ADS)

    Morales-Marín, L. A.; Wheater, H. S.; Lindenschmidt, K. E.

    2017-07-01

    The relatively low water flow velocities in reservoirs cause them to have high capacities for retaining sediments and pollutants, which can lead to a reduction in downstream nutrient loading. Hence, nutrients can progressively accumulate in reservoirs, resulting in the deterioration of aquatic ecosystems and water quality. Lake Diefenbaker (LD) is a large multipurpose reservoir, located on the South Saskatchewan River (SSR), that serves as a major source of freshwater in Saskatchewan, Canada. Over the past several years, changes in land use (e.g. expansion of urban areas and industrial developments) in the reservoir's catchment have heightened concerns about future water quality in the catchment and in the reservoir. Intensification of agricultural activities has led to an increase in augmented the application of manure and fertilizer for crops and pasture. Although previous research has attempted to quantify nutrient retention in LD, there is a knowledge gap related to the identification of major nutrient sources and quantification of nutrient export from the catchment at different spatial scales. Using the SPAtially Referenced Regression On Watershed (SPARROW) model, this gap has been addressed by assessing water quality regionally, and identifying spatial patterns of factors and processes that affect water quality in the LD catchment. Model results indicate that LD retains about 70% of the inflowing total nitrogen (TN) and 90% of the inflowing total phosphorus (TP) loads, of which fertilizer and manure applied to agricultural fields contribute the greatest proportion. The SPARROW model will be useful as a tool to guide the optimal implementation of nutrient management plans to reduce nutrient inputs to LD.

  8. Urban trees reduce nutrient leaching to groundwater.

    PubMed

    Nidzgorski, Daniel A; Hobbie, Sarah E

    2016-07-01

    Many urban waterways suffer from excess nitrogen (N) and phosphorus (P), feeding algal blooms, which cause lower water clarity and oxygen levels, bad odor and taste, and the loss of desirable species. Nutrient movement from land to water is likely to be influenced by urban vegetation, but there are few empirical studies addressing this. In this study, we examined whether or not urban trees can reduce nutrient leaching to groundwater, an important nutrient export pathway that has received less attention than stormwater. We characterized leaching beneath 33 trees of 14 species, and seven open turfgrass areas, across three city parks in Saint Paul, Minnesota, USA. We installed lysimeters at 60 cm depth to collect soil water approximately biweekly from July 2011 through October 2013, except during winter and drought periods, measured dissolved organic carbon (C), N, and P in soil water, and modeled water fluxes using the BROOK90 hydrologic model. We also measured soil nutrient pools (bulk C and N, KCl-extractable inorganic N, Brays-P), tree tissue nutrient concentrations (C, N, and P of green leaves, leaf litter, and roots), and canopy size parameters (leaf biomass, leaf area index) to explore correlations with nutrient leaching. Trees had similar or lower N leaching than turfgrass in 2012 but higher N leaching in 2013; trees reduced P leaching compared with turfgrass in both 2012 and 2013, with lower leaching under deciduous than evergreen trees. Scaling up our measurements to an urban subwatershed of the Mississippi River (~17 400 ha, containing ~1.5 million trees), we estimated that trees reduced P leaching to groundwater by 533 kg in 2012 (0.031 kg/ha or 3.1 kg/km 2 ) and 1201 kg in 2013 (0.069 kg/ha or 6.9 kg/km 2 ). Removing these same amounts of P using stormwater infrastructure would cost $2.2 million and $5.0 million per year (2012 and 2013 removal amounts, respectively). © 2016 by the Ecological Society of America.

  9. Stream reconnaissance for nutrients and other water-quality parameters, Greater Pittsburgh Region, Pennsylvania

    USGS Publications Warehouse

    Beall, Robert M.

    1975-01-01

    Eighty-five stream sites in and near the six-county Greater Pittsburgh Region were sampled in mid-June 1971 in mid-October 1972. Data are reported for 89 sites because 4 substitute sites were sampled in the second period. Drainage areas of the basins sampled ranged from 4.1 to 19,5000 square miles (10.6 to 50,500 square kilometres). The chemical analyses included constituents of three general classes: (1) nutrients, (2) activity indicators, and (3) dominant anions. Modification of the natural chemical and physical characteristics of the surface waters by man's activities is evident in some of the data. However, the activities are so diverse in type and in areal extent that their influence in terms of cause and effect is often obscure. Nutrient concentrations were high enough to indicate potential problems at about a quarter of the sampling sites. Temperature, dissolved oxygen, and pH values indicated a generally favorable capacity for regeneration or recovery from degradation, although a number a streams east of the Allegheny and Monongahela Rivers are marginal or lacking in the capacity. Regionally, sulfate is the dominant ion and was observed in concentrations of 40 milligrams per litre or more at 90 percent of the sites. Bicarbonate exceeded 100 milligrams per litre at 22 sites. A moderate to high degree of mineralization, as indicated by conductance readings of more than 500 micromhos per cetrimetre at half of the sampling sites, is a characteristic of the region's surface waters.

  10. Simulated Sunlight-Mediated Photodynamic Therapy for Melanoma Skin Cancer by Titanium-Dioxide-Nanoparticle-Gold-Nanocluster-Graphene Heterogeneous Nanocomposites.

    PubMed

    Cheng, Yan; Chang, Yun; Feng, Yanlin; Liu, Ning; Sun, Xiujuan; Feng, Yuqing; Li, Xi; Zhang, Haiyuan

    2017-05-01

    Simulated sunlight has promise as a light source able to alleviate the severe pain associated with patients during photodynamic therapy (PDT); however, low sunlight utilization efficiency of traditional photosensitizers dramatically limits its application. Titanium-dioxide-nanoparticle-gold-nanocluster-graphene (TAG) heterogeneous nanocomposites are designed to efficiently utilize simulated sunlight for melanoma skin cancer PDT. The narrow band gap in gold nanoclusters (Au NCs), and staggered energy bands between Au NCs, titanium dioxide nanoparticles (TiO 2 NPs), and graphene can result in efficient utilization of simulated sunlight and separation of electron-hole pairs, facilitating the production of abundant hydroxyl and superoxide radicals. Under irradiation of simulated sunlight, TAG nanocomposites can trigger a series of toxicological responses in mouse B16F1 melanoma cells, such as intracellular reactive oxygen species production, glutathione depletion, heme oxygenase-1 expression, and mitochondrial dysfunctions, resulting in severe cell death. Furthermore, intravenous or intratumoral administration of biocompatible TAG nanocomposites in B16F1-tumor-xenograft-bearing mice can significantly inhibit tumor growth and cause severe pathological tumor tissue changes. All of these results demonstrate prominent simulated sunlight-mediated PDT effects. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Subsurface application of poultry litter and its influence on nutrient losses in runoff water from permanent pastures.

    PubMed

    Watts, D B; Way, T R; Torbert, H A

    2011-01-01

    Environmental pressure to reduce nutrient losses from agricultural fields has increased in recent years. To abate this nutrient loss to the environment, better management practices and new technologies need to be developed. Thus, research was conducted to evaluate if subsurface banding poultry litter (PL) would reduce nitrogen (N) and phosphorus (P) loss in surface water runoff using a four-row prototype implement. Rainfall simulations were conducted to create a 40-min runoff event in an established bermudagrass (Cynodon dactylon L.) pasture on soil types common to the Coastal Plain and Piedmont regions. The Coastal Plain soil type was a Marvyn loamy sand (fine-loamy, kaolinitic, thermic Typic Kanhapludults) and the Piedmont soil type was a Hard Labor loamy sand (fine, kaolinitic, thermic Oxyaquic Kanhapludults). Treatments consisted of surface- and subsurface-applied PL at a rate of 9 Mg ha(-1), surface broadcast-applied commercial fertilizer (CF; urea and triple superphosphate blend) at the equivalent N (330 kg N ha(-1)) and P (315 kg N ha(-1)) content of PL, and a nonfertilized control. The greatest loss for inorganic N, total N, dissolved reactive P (DRP), and total P occurred with the surface broadcast treatments, with CF contributing to the greatest loss. Nutrient losses from the subsurface banded treatment reduced N and P in surface water runoff to levels of the control. Subsurface banding of PL reduced concentrations of inorganic N 91%, total N 90%, DRP 86%, and total P 86% in runoff water compared with surface broadcasted PL. These results show that subsurface band-applied PL can greatly reduce the impact of N and P loss to the environment compared with conventional surface-applied PL and CF practices.

  12. Contributions of visible and ultraviolet parts of sunlight to photoinhibition.

    PubMed

    Hakala-Yatkin, Marja; Mäntysaari, Mika; Mattila, Heta; Tyystjärvi, Esa

    2010-10-01

    Photoinhibition is light-induced inactivation of PSII, and action spectrum measurements have shown that UV light causes photoinhibition much more efficiently than visible light. In the present study, we quantified the contribution of the UV part of sunlight in photoinhibition of PSII in leaves. Greenhouse-grown pumpkin leaves were pretreated with lincomycin to block the repair of photoinhibited PSII, and exposed to sunlight behind a UV-permeable or UV-blocking filter. Oxygen evolution and Chl fluorescence measurements showed that photoinhibition proceeds 35% more slowly under the UV-blocking than under the UV-permeable filter. Experiments with a filter that blocks UV-B but transmits UV-A and visible light revealed that UV-A light is almost fully responsible for the UV effect. The difference between leaves illuminated through a UV-blocking and UV-transparent filter disappeared when leaves of field-grown pumpkin plants were used. Thylakoids isolated from field-grown and greenhouse-grown plants were equally sensitive to UV light, and measurements of UV-induced fluorescence from leaves indicated that the protection of the field-grown plants was caused by substances that block the passage of UV light to the chloroplasts. Thus, the UV part of sunlight, especially the UV-A part, is potentially highly important in photoinhibition of PSII but the UV-screening compounds of plant leaves may offer almost complete protection against UV-induced photoinhibition.

  13. Dynamics of nutrient cycling and related benthic nutrient and oxygen fluxes during a spring phytoplankton bloom in South San Francisco Bay (USA)

    USGS Publications Warehouse

    Grenz, C.; Cloern, J.E.; Hager, S.W.; Cole, B.E.

    2000-01-01

    Benthic oxygen uptake and nutrient releases of N, P and Si were measured weekly at 2 sites in South San Francisco Bay around the 1996 spring bloom. Exchanges across the sediment-water interface were estimated from whole core incubations performed in the laboratory at in situ temperature and in dark. Fluxes changed significantly on a weekly time scale. Over a period of 15 wk the fluxes of dissolved inorganic N, P and Si ranged from -40 to +200, 0 to 13 and from 30 to 400 ??mol m-2 h-1 respectively. Sediment oxygen demand increased from 10 before to 64 mg O2 m-2 h-1 just after the bloom period. During the bloom, nutrient fluxes represented about 20, 16 and 9% of the Si, P and N requirements for primary production. Before and after the bloom period, Si fluxes contributed up to 30 and > 100% of this requirement and P and N fluxes up to 15 and 50% respectively. Simple empirical models explain most of the spatial-temporal variability of benthic fluxes of Si, P and NH4 (but not NO3) from 3 predictor variables: sediment porosity, nutrient concentration in bottom waters and chlorophyll content of surficial sediments. These models show that algal blooms influence benthic-pelagic nutrient exchange through 2 processes: (1) depletion of nutrients from the water column (which enhances gradient-driven transports across the sediment-water interface) and (2) sedimentation of labile phytodetritus (which promotes remineralization in or on the surficial sediments). Rates and patterns of nutrient cycling were very different at the shallow and deep study sites, illustrating the challenge of extrapolating measurements of coupled algae-nutrient dynamics to whole ecosystems.

  14. Changes in water mass exchange between the NW shelf areas and the North Atlantic and their impact on nutrient/carbon cycling

    NASA Astrophysics Data System (ADS)

    Gröger, Matthias; Maier-Reimer, Ernst; Mikolajewicz, Uwe; Segschneider, Joachim; Sein, Dimitry

    2010-05-01

    Despite their comparatively small extension on a global scale, shelf areas are of interest for several economic reasons and climatic processes related to nutrient cycling, sea food supply, and biological productivity. Moreover, they constitute an important interface for nutrients, pollutants and freshwater on their pathway from the continents to the open ocean. This modelling study aims to investigate the spatial and temporal variability of water mass exchange between the North Atlantic and the NW European shelf and their impact on nutrient/carbon cycling and biological productivity. For this, a new modeling approach has been set up which bridges the gap between pure shelf models where water mass transports across the model domain too strongly depend on the formulation of open boundaries and global models suffering under their too coarse resolution in shelf regions. The new model consists of the global ocean and carbon cycle model MPIOM/HAMOCC with strongly increased resolution in the North Sea and the North Atlantic coupled to the regional atmosphere model REMO. The model takes the full luni-solar tides into account. It includes further a 12 layer sediment module with the relevant pore water chemistry. The main focus lies on the governing mechanisms of water mass exchange across the shelf break and the imprint on shelf biogeochemistry. For this, artificial tracers with a prescribed decay rate have been implemented to distinguish waters arriving from polar and shelf regions and those that originate from the tropics. Experiments were carried out for the years 1948 - 2007. The relationship to larger scale circulation patterns like the position and variability of the subtropical and subpolar gyres is analyzed. The water mass exchange is analyzed with respect to the nutrient concentration and productivity on the European shelf areas. The implementation of tides leads to an enhanced vertical mixing which causes lower sea surface temperatures compared to simulations

  15. Efficacy of Chlorella pyrenoidosa and Scenedesmus abundans for Nutrient Removal in Rice Mill Effluent (Paddy Soaked Water).

    PubMed

    Abinandan, S; Bhattacharya, Ribhu; Shanthakumar, S

    2015-01-01

    Microalgae are product of sustainable development owing to its ability to treat variety of wastewater effluents and thus produced biomass can serve as value added product for various commercial applications. This paper deals with the cultivation of microalgae species namely Chlorella pyrenoidosa and Scenedesmus abundans in rice mill effluent (i.e., paddy soaked water) for nutrient removal. In order to investigate the nutrient removal capability, microalgae are subjected to cultivation in both raw and autoclaved samples. The maximum phosphate removal by Scenedesmus abundans and Chlorella pyrenoidosa in raw sample was 98.3% and 97.6%, respectively, whereas, the removal of ammoniacal nitrogen by Scenedesmus abundans and Chlorella pyrenoidosa in raw sample was 92% and 90.3%, respectively. The growth (measured in terms of chlorophyll content) of Scenedesmus abundans and Chlorella pyrenoidosa in raw sample was 3.88 mg/l and 5.55 mg/l, respectively. The results indicate the suitability of microalgae cultivation in rice mill effluent treatment for nutrient removal.

  16. PRKCZ methylation is associated with sunlight exposure in a North American but not a Mediterranean population

    USDA-ARS?s Scientific Manuscript database

    Sunlight exposure has been shown to alter DNA methylation patterns across several human cell-types, including T-lymphocytes. Since epigenetic changes establish gene expression profiles, changes in DNA methylation induced by sunlight exposure warrant investigation. The purpose of this study was to as...

  17. The "isohydric trap": a proposed feedback between water shortage, stomatal regulation and nutrient acquisition drives differential growth and survival of European pines under climatic dryness.

    PubMed

    Salazar-Tortosa, D; Castro, J; Villar-Salvador, P; Viñegla, B; Matías, L; Michelsen, A; Rubio de Casas, R; Querejeta, J I

    2018-05-16

    Climatic dryness imposes limitations on vascular plant growth by reducing stomatal conductance, thereby decreasing CO 2 uptake and transpiration. Given that transpiration-driven water flow is required for nutrient uptake, climatic stress-induced nutrient deficit could be a key mechanism for decreased plant performance under prolonged drought. We propose the existence of an "isohydric trap", a dryness-induced detrimental feedback leading to nutrient deficit and stoichiometry imbalance in strict isohydric species. We tested this framework in a common garden experiment with 840 individuals of four ecologically-contrasting European pines (Pinus halepensis, P. nigra, P. sylvestris, and P. uncinata) at a site with high temperature and low soil water availability. We measured growth, survival, photochemical efficiency, stem water potentials, leaf isotopic composition (δ 13 C, δ 18 O), and nutrient concentrations (C, N, P, K, Zn, Cu). After two years, the Mediterranean species Pinus halepensis showed lower δ 18 O and higher δ 13 C values than the other species, indicating higher time-integrated transpiration and water-use efficiency (WUE), along with lower predawn and midday water potentials, higher photochemical efficiency, higher leaf P and K concentrations, more balanced N:P and N:K ratios, and much greater dry-biomass (up to 63-fold) and survival (100%). Conversely, the more mesic mountain pine species showed higher leaf δ 18 O and lower δ 13 C, indicating lower transpiration and WUE, higher water potentials, severe P and K deficiencies and N:P and N:K imbalances, and poorer photochemical efficiency, growth, and survival. These results support our hypothesis that vascular plant species with tight stomatal regulation of transpiration can become trapped in a feedback cycle of nutrient deficit and imbalance that exacerbates the detrimental impacts of climatic dryness on performance. This overlooked feedback mechanism may hamper the ability of isohydric species to

  18. Response of nutrients, minerals, antioxidant leaf pigments, vitamins, polyphenol, flavonoid and antioxidant activity in selected vegetable amaranth under four soil water content.

    PubMed

    Sarker, Umakanta; Oba, Shinya

    2018-06-30

    Four selected vegetable amaranths were grown under four soil water content to evaluate their response in nutrients, minerals, antioxidant leaf pigments, vitamins, polyphenol, flavonoid and total antioxidant activity (TAC). Vegetable amaranth was significantly affected by variety, soil water content and variety × soil water content interactions for all the traits studied. Increase in water stress, resulted in significant changes in proximate compositions, minerals (macro and micro), leaf pigments, vitamin, total polyphenol content (TPC), and total flavonoid content (TFC) of vegetable amaranth. Accessions VA14 and VA16 performed better for all the traits studied. Correlation study revealed a strong antioxidant scavenging activity of leaf pigments, ascorbic acid, TPC and TFC. Vegetable amaranth can tolerate soil water stress without compromising the high quality of the final product in terms of nutrients and antioxidant profiles. Therefore, it could be a promising alternative crop in semi-arid and dry areas and also during dry seasons. Copyright © 2018. Published by Elsevier Ltd.

  19. Scaling up food production in the Upper Mississippi river basin: modeling impacts on water quality and nutrient cycling

    NASA Astrophysics Data System (ADS)

    Bowen, E. E.; Martin, P. A.; Schuble, T. J.; Yan, E.; Demissie, Y.

    2010-12-01

    Agricultural production imposes significant environmental stress on the landscape, both in the intensity and extent of agricultural activities. Among the most significant impacts, agriculture dominates the natural reactive nitrogen cycle, with excess reactive nitrogen leading to the degraded quality of inland and coastal waters. In the U.S., policymakers and stakeholders nationwide continue to debate strategies for decreasing environmental degradation from agricultural lands. Such strategies aim to optimize the balance among competing demands for food, fuel and ecosystem services. One such strategy increasingly discussed in the national debate is that of localizing food production around urban areas, developing what some have recently called “foodsheds”. However, the environmental impacts of localizing food production around population centers are not well-understood given the hard-to-generalize variety seen in management practices currently employed among local farms marketing food crops directly to consumers. As a first, landscape level study of potential impacts from scaling up this type of agriculture, we use the USDA Soil and Water Assessment Tool (SWAT) model to quantify environmental impacts from developing foodsheds for all population centers in the Upper Mississippi river basin. Specifically, we focus on nutrient cycling and water quality impacts determining direct greenhouse gas emissions and changes to nutrient runoff from increased food production in this watershed. We investigate a variety of scenarios in which food production is scaled up to the regional level using different types of farm management practices, ranging from conventional production of fruits and vegetables, to production of these products from small-scale, diversified systems integrating conservation easements. In addition to impacts on nutrient cycling and water quality, we also characterize relative levels of productivity in conjunction with overall demand for food associated

  20. NUTRIENTS IN WATERSHEDS; DEVELOPING ENHANCED MODELING TOOLS

    EPA Science Inventory

    Nutrient enrichment is one of the most detrimental stressors causing water-resource impairment. Of systems surveyed and reported as impaired, 40% of rivers, 51% of lakes, and 57% of estuaries listed nutrients as a primary cause of impairment (USEPA, 1996). In many cases, these ...

  1. Estimated water and nutrient inflows and outflows, Lake Cochituate, eastern Massachusetts, 1977-79

    USGS Publications Warehouse

    Gay, F.B.

    1984-01-01

    Streamflow was the major source of water and nutrients (nitrogen and phosphorus) to Lake Cochituate, followed by ground water, and then precipitation during April 1978 through March 1979. Compared to all sources during that period, streams contributed 7,217 million gallons (a little over 82 percent) of water, 63 ,000 pounds (between 50 and 60 percent) of nitrogen, and 3,000 pounds (94 percent) of phosphorus. A little over 60 percent of all the water that entered Lake Cochituate flowed from Fisk Pond. This single source transported about 38,000 pounds of nitrogen and 2,000 pounds of phosphorus. Ground-water inflow to Lake Cochituate occurs along its shoreline except at the north end of Lake Cochituate 's North Pond where natural seepage from the lake is occurring and at locations on the lake 's Middle and South Ponds where municipal wells induce infiltration of lake water amounting to 1,228 million gallons for that period. Discharge of ground water to the lake was estimated to range from 462 to 816 million gallons and transported from 31,000 to 55,000 pounds of nitrogen and from 46 to 82 pounds of phosphorus. Bulk precipitation was estimated to contribute about the same volume of water to the lake as ground water but double its phosphorus load. However, the load of nitrogen, 8000 pounds, from bulk precipitation was the smallest of any source. (USGS)

  2. Sediment type and benthic fauna control the nutrient release in a coastal bay

    NASA Astrophysics Data System (ADS)

    Voss, Maren; Thoms, Franziska; Dippner, Joachim; Bartl, Ines; Janas, Urzula; Hellemann, Dana; Hietanen, Susanna; Kendzierska, Halina

    2017-04-01

    Eutrophication of coastal seas is still a major problem that may even increase in the near future according to recent model studies. The catchment of the Baltic Sea with nine highly industrialized riparian countries is intensively used and only few major rivers are responsible for more than half of the riverine nutrient input to the coastal zones. It is hypothesized that these nutrient are the main drivers for large anoxic bottom waters in the central Baltic Sea and an increasing hypoxia problem in coastal waters. The sequestration of nutrients was therefore intensively studied in the Baltic Sea, however either in the water column or in the sediments. The role of the benthic pelagic coupling for the nutrient turnover was much less investigated especially due to technical challenges. We therefore used a lander system to quantify the nutrient release from sediments in a river impacted coastal Bay of Gdansk in the framework of the BONUS-COCOA project. Lander deployments and sediment coring were done simultaneously to measure nutrient fluxes over time and to characterize grain size, permeability, organic matter content, and benthic fauna. The benthic communities were analyzed to identify potential linkages between nutrient release and the species composition. Our study revealed close linkages between types/grain-size of sediment and the nutrient release. The activity of the animals in the sediment seems responsible for significant release of nutrients which is more pronounced than the diffusive nutrient release back to the water column. Rates from nineteen stations were used to draw a conclusive picture of the overall nutrient release from sediments and were set into a framework of a nutrient budget for the Bay of Gdansk considering the role of fauna. Moreover, we are able to identify a depth of roughly 50m as a border that separates the dominance of benthic recycling from deeper stations where mainly deposition or organic material takes place. Changes in properties of

  3. Protein oxidative damage and heme oxygenase in sunlight-exposed human skin: roles of MAPK responses to oxidative stress.

    PubMed

    Akasaka, Emiko; Takekoshi, Susumu; Horikoshi, Yosuke; Toriumi, Kentarou; Ikoma, Norihiro; Mabuchi, Tomotaka; Tamiya, Shiho; Matsuyama, Takashi; Ozawa, Akira

    2010-12-20

    Oxidative stress derived from ultraviolet (UV) light in sunlight induces different hazardous effects in the skin, including sunburn, photo-aging and DNA mutagenesis. In this study, the protein-bound lipid peroxidation products 4-hydroxy-2-nonenal (HNE) and the oxidative DNA damage marker 8-hydroxy-2'-deoxyguanosine (8OHdG) were investigated in chronically sun-exposed and sun-protected human skins using immunohistochemistry. The levels of antioxidative enzymes, such as heme oxygenase 1 and 2, Cu/Zn-SOD, Mn-SOD and catalase, were also examined. Oxidative stress is also implicated in the activation of signal transduction pathways, such as mitogen-activated protein kinase (MAPK). Therefore, the expression and distribution of phosphorylated p38 MAPK, phosphorylated Jun N-terminal kinase (JNK) and phosphorylated extracellular signal-regulated kinase (ERK) were observed. Skin specimens were obtained from the surgical margins. Chronically sunlight-exposed skin samples were taken from the ante-auricular (n = 10) and sunlight-protected skin samples were taken from the post-auricular (n = 10). HNE was increased in the chronically sunlight-exposed skin but not in the sunlight-protected skin. The expression of heme oxygenase-2 was markedly increased in the sunlight-exposed skin compared with the sun-protected skin. In contrast, the intensity of immunostaining of Cu/Zn-SOD, Mn-SOD and catalase was not different between the two areas. Phosphorylated p38 MAPK and phosphorylated JNK accumulated in the ante-auricular dermis and epidermis, respectively. These data show that particular anti-oxidative enzymes function as protective factors in chronically sunlight-exposed human skin. Taken together, our results suggest (1) antioxidative effects of heme oxygenase-2 in chronically sunlight-exposed human skin, and that (2) activation of p38 MAPK may be responsible for oxidative stress.

  4. Synergistic effect of solar radiation and solar heating to disinfect drinking water sources.

    PubMed

    Rijal, G K; Fujioka, R S

    2001-01-01

    Waterborne diseases are still common in developing countries as drinking water sources are contaminated and feasible means to reliably treat and disinfect these waters are not available. Many of these developing countries are in the tropical regions of the world where sunlight is plentiful. The objective of this study was to evaluate the effectiveness of combining solar radiation and solar heating to disinfect contaminated water using a modified Family Sol*Saver System (FSP). The non-UV transmittable cover sheet of the former FSP system was replaced with an UV transmittable plastic cover sheet to enable more wavelengths of sunlight to treat the water. Disinfection efficiency of both systems was evaluated based on reduction of the natural populations of faecal coliform, E. coli, enterococci, C. perfringens, total heterotrophic bacteria, hydrogen sulphide producing bacteria and FRNA virus. The results showed that under sunny and partly sunny conditions, water was heated to critical temperature (60 degrees C) in both the FSP systems inactivating more than 3 log (99.9%) of the concentrations of faecal coliform and E. coli to undetectable levels of < 1 CFU/100 mL within 2-5 h exposure to sunlight. However, under cloudy conditions, the two FSP systems did not reduce the concentrations of faecal indicator bacteria to levels of < 1 CFU/100 mL. Nonetheless, sufficient evidence was obtained to show that UV radiation of sunlight plus heat worked synergistically to enhance the inactivation of faecal indicator bacteria. The relative log removal of indicator microorganism in the FSP treated water was total heterotrophic bacteria < C. perfringens < F RNA virus < enterococci < E. coli < faecal coliform. In summary, time of exposure to heat and radiation effects of sunlight were important in disinfecting water by solar units. The data indicated that direct radiation of sunlight worked synergistically with solar heating of the water to disinfect the water. Thus, effective

  5. 76 FR 21402 - Notice of Availability of the Final Environmental Impact Statement for the Desert Sunlight...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-04-15

    ... proposed DSSF which includes a 550-megawatt (MW) solar photovoltaic (PV) facility and associated 220... Holdings, LLC, Desert Sunlight Solar Farm and Proposed California Desert Conservation Area Plan Amendment... Desert Sunlight Solar Farm (DSSF) project and by this notice is announcing its availability. DATES: The...

  6. Dissolved organic carbon biodegradability from thawing permafrost stimulated by sunlight rather than inorganic nitrogen

    NASA Astrophysics Data System (ADS)

    Liu, F.; Chen, L.; Zhang, B.; Wang, G.; Qin, S.; Yang, Y.

    2017-12-01

    Permafrost thaw could result in a large portion of frozen carbon being laterally transferred to aquatic ecosystems as dissolved organic carbon (DOC). During this delivery process, the size of biodegradable DOC (BDOC) determines the proportion of DOC mineralized by microorganisms and associated carbon loss to the atmosphere, which may further trigger positive carbon-climate feedback. Thermokarst is an abrupt permafrost thaw process that can enhance DOC export and also impact DOC processing through increased inorganic nitrogen (N) and sunlight exposure. However, it remains unclear how thermokarst-impacted BDOC responds to inorganic N addition and ultraviolet (UV) light irradiation. Here we explored the responses of DOC concentration, composition and its biodegradability to inorganic N and UV light in a typical thermokarst on the Tibetan Plateau, by combining field observation and laboratory incubation with spectra analyses (UV-visible absorption and three-dimensional fluorescence spectra) and parallel factor analyses. Our results showed that BDOC in thermokarst feature outflows was significantly higher than in reference water. Furthermore, inorganic N addition had no influence on thermokarst-impacted BDOC, whereas exposure to UV light significantly increased BDOC by as much as 2.3 times higher than the dark-control. Moreover, N addition and UV irradiation did not generate additive effects on BDOC. These results imply that sunlight rather than inorganic N can increase thermokarst-derived BDOC, potentially strengthening the positive permafrost carbon-climate feedback.

  7. Sunlight-driven eco-friendly smart curtain based on infrared responsive graphene oxide-polymer photoactuators.

    PubMed

    Leeladhar; Raturi, Parul; Singh, J P

    2018-02-27

    Photomechanical actuation is the conversion of light energy into mechanical energy through some smart materials. Infrared-responsive smart materials have become an emerging field of research due to easy availability and eco-friendly nature of their stimulus in the form of sunlight, which contains about 50% of near-infrared(nIR) making these materials useful at macro-scale photoactuator applications. Here, we demonstrate fabrication of highly versatile nIR triggered photoactuators based on graphene oxide/polycarbonate bilayers that offers fast, low-cost fabrication, large deflection, reversible actuation and wavelength-selective response. The photoactuators are realized by vacuum filtration of graphene oxide/water dispersion through polycarbonate membrane resulting graphene oxide/polymer bilayer structure. The photoactuation response was measured in the form of deflection from equilibrium position as a result of infrared-irradiation. The deflection is caused by the generated thermal stress at the interface of bilayers due to mismatch of thermal expansion coefficient as a results of nIR absorption by graphene oxide and subsequent temperature rise. A maximum deflection of 12 mm (circular-shaped structure with diameter 28 mm) with corresponding bending curvature of 0.33 cm -1 was shown by this photoactuator for illumination intensity of 106 mW/cm 2 . Few applications of these photoactuators such as sunlight-driven smart curtain, infrared actuated curtain and self-folding box are also demonstrated.

  8. Reference Condition Approach for Numeric Nutrient Criteria for Oregon Estuaries

    EPA Science Inventory

    Development of nutrient criteria for all water body types of the US remains a top priority for EPA. Estuaries in the Pacific Northwest receive nutrients from both the watershed and the coastal ocean, and thus are particularly complex systems in which to establish water quality c...

  9. Sequential determination of multi-nutrient elements in natural water samples with a reverse flow injection system.

    PubMed

    Lin, Kunning; Ma, Jian; Yuan, Dongxing; Feng, Sichao; Su, Haitao; Huang, Yongming; Shangguan, Qipei

    2017-05-15

    An integrated system was developed for automatic and sequential determination of NO 2 - , NO 3 - , PO 4 3- , Fe 2+ , Fe 3+ and Mn 2+ in natural waters based on reverse flow injection analysis combined with spectrophotometric detection. The system operation was controlled by a single chip microcomputer and laboratory-programmed software written in LabVIEW. The experimental parameters for each nutrient element analysis were optimized based on a univariate experimental design, and interferences from common ions were evaluated. The upper limits of the linear range (along with detection limit, µmolL -1 ) of the proposed method was 20 (0.03), 200 (0.7), 12 (0.3), 5 (0.03), 5 (0.03), 9 (0.2) µmolL -1 , for NO 2 - , NO 3 - , PO 4 3- , Fe 2+ , Fe 3+ and Mn 2+ , respectively. The relative standard deviations were below 5% (n=9-13) and the recoveries varied from 88.0±1.0% to 104.5±1.0% for spiked water samples. The sample throughput was about 20h -1 . This system has been successfully applied for the determination of multi-nutrient elements in different kinds of water samples and showed good agreement with reference methods (slope 1.0260±0.0043, R 2 =0.9991, n=50). Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Temporal and spatial variations in nutrient stoichiometry and regulation of phytoplankton biomass in Hong Kong waters: influence of the Pearl River outflow and sewage inputs.

    PubMed

    Xu, Jie; Ho, Alvin Y T; Yin, Kedong; Yuan, Xiangcheng; Anderson, Donald M; Lee, Joseph H W; Harrison, Paul J

    2008-01-01

    In 2001, the Hong Kong government implemented the Harbor Area Treatment Scheme (HATS) under which 70% of the sewage that had been formerly discharged into Victoria Harbor is now collected and sent to Stonecutters Island Sewage Works where it receives chemically enhanced primary treatment (CEPT), and is then discharged into waters west of the Harbor. The relocation of the sewage discharge will possibly change the nutrient dynamics and phytoplankton biomass in this area. Therefore, there is a need to examine the factors that regulate phytoplankton growth in Hong Kong waters in order to understand future impacts. Based on a historic nutrient data set (1986-2001), a comparison of ambient nutrient ratios with the Redfield ratio (N:P:Si=16:1:16) showed clear spatial variations in the factors that regulate phytoplankton biomass along a west (estuary) to east (coastal/oceanic) transect through Hong Kong waters. Algal biomass was constrained by a combination of low light conditions, a rapid change in salinity, and strong turbulent mixing in western waters throughout the year. Potential stoichiometric Si limitation (up to 94% of the cases in winter) occurred in Victoria Harbor due to the contribution of sewage effluent with high N and P enrichment all year, except for summer when the frequency of stoichiometric Si limitation (48%) was the same as P, owing to the influence of the high Si in the Pearl River discharge. In the eastern waters, potential N limitation and N and P co-limitation occurred in autumn and winter respectively, because of the dominance of coastal/oceanic water with low nutrients and low N:P ratios. In contrast, potential Si limitation occurred in spring and a switch to potential N, P and Si limitation occurred in eastern waters in summer. In southern waters, there was a shift from P limitation (80%) in summer due to the influence of the N-rich Pearl River discharge, to N limitation (68%) in autumn, and to N and P co-limitation in winter due to the

  11. Temporal and Spatial Variations in Nutrient Stoichiometry and Regulation of Phytoplankton Biomass in Hong Kong waters: Influence of the Pearl River Outflow and Sewage Inputs

    PubMed Central

    Xu, Jie; Ho, Alvin Y. T.; Yin, Kedong; Yuan, Xiangcheng; Anderson, Donald M.; Lee, Joseph H.W.; Harrison, Paul J.

    2017-01-01

    In 2001, the Hong Kong government implemented the Harbor Area Treatment Scheme (HATS) under which 70% of the sewage that had been formerly discharged into Victoria Harbor is now collected and sent to Stonecutters Island Sewage Works where it receives chemically enhanced primary treatment (CEPT), and is then discharged into waters west of the Harbor. The relocation of the sewage discharge will possibly change the nutrient dynamics and phytoplankton biomass in this area. Therefore, there is a need to examine the factors that regulate phytoplankton growth in Hong Kong waters in order to understand future impacts. Based on a historic nutrient data set (1986–2001), a comparison of ambient nutrient ratios with the Redfield ratio (N:P:Si=16:1:16) showed clear spatial variations in the factors that regulate phytoplankton biomass along a west (estuary) to east (coastal/oceanic) transect through Hong Kong waters. Algal biomass was constrained by a combination of low light conditions, a rapid change in salinity, and strong turbulent mixing in western waters throughout the year. Potential stoichiometric Si limitation (up to 94% of the cases in winter) occurred in Victoria Harbor due to the contribution of sewage effluent with high N and P enrichment all year, except for summer when the frequency of stoichiometric Si limitation (48%) was the same as P, owing to the influence of the high Si in the Pearl River discharge. In the eastern waters, potential N limitation and N and P co-limitation occurred in autumn and winter respectively, because of the dominance of coastal/oceanic water with low nutrients and low N:P ratios. In contrast, potential Si limitation occurred in spring and a switch to potential N, P and Si limitation occurred in eastern waters in summer. In southern waters, there was a shift from P limitation (80%) in summer due to the influence of the N-rich Pearl River discharge, to N limitation (68%) in autumn, and to N and P co-limitation in winter due to the

  12. Zinc Oxide-Containing Porous Boron-Carbon-Nitrogen Sheets from Glycine-Nitrate Combustion: Synthesis, Self-Cleaning, and Sunlight-Driven Photocatalytic Activity.

    PubMed

    Bharathidasan, T; Mandalam, Aditya; Balasubramanian, M; Dhandapani, P; Sathiyanarayanan, S; Mayavan, Sundar

    2015-08-26

    We developed a single-step thermal method that enables successful inclusion of ZnO components in the porous boron-carbon-nitrogen (BCN) framework to form a new class of functional hybrid. ZnO-containing BCN hybrids were prepared by treating a mixture of B2O3, glycine, and zinc nitrate at 500 °C. Glycine-nitrate decomposition along with B2O3 acts as a source for ZnO-BCN formation. The incorporation of ZnO onto BCN has extended the photoresponse of ZnO in the visible region, which makes ZnO-BCN a preferable photocatalyst relative to ZnO upon sunlight exposure. It is interesting to note that as-prepared 2D ZnO-BCN sheets dispersed in PDMS form a stable coating over aluminum alloys. The surface exhibited a water contact angle (CA) of 157.6° with 66.6 wt % ZnO-BCN in polydimethylsiloxane (PDMS) and a water droplet (7 μL) roll-off angle of <6° and also demonstrates oil fouling resistant superhydrophobicity. In brief, the present study focuses on the gram scale synthesis of a new class of sunlight-driven photocatalyst and also its application toward the development of superhydrophobic and oleophobic coating.

  13. Identifying multiple stressor controls on phytoplankton dynamics in the River Thames (UK) using high-frequency water quality data.

    PubMed

    Bowes, M J; Loewenthal, M; Read, D S; Hutchins, M G; Prudhomme, C; Armstrong, L K; Harman, S A; Wickham, H D; Gozzard, E; Carvalho, L

    2016-11-01

    River phytoplankton blooms can pose a serious risk to water quality and the structure and function of aquatic ecosystems. Developing a greater understanding of the physical and chemical controls on the timing, magnitude and duration of blooms is essential for the effective management of phytoplankton development. Five years of weekly water quality monitoring data along the River Thames, southern England were combined with hourly chlorophyll concentration (a proxy for phytoplankton biomass), flow, temperature and daily sunlight data from the mid-Thames. Weekly chlorophyll data was of insufficient temporal resolution to identify the causes of short term variations in phytoplankton biomass. However, hourly chlorophyll data enabled identification of thresholds in water temperature (between 9 and 19°C) and flow (<30m(3)s(-1)) that explained the development of phytoplankton populations. Analysis showed that periods of high phytoplankton biomass and growth rate only occurred when these flow and temperature conditions were within these thresholds, and coincided with periods of long sunshine duration, indicating multiple stressor controls. Nutrient concentrations appeared to have no impact on the timing or magnitude of phytoplankton bloom development, but severe depletion of dissolved phosphorus and silicon during periods of high phytoplankton biomass may have contributed to some bloom collapses through nutrient limitation. This study indicates that for nutrient enriched rivers such as the Thames, manipulating residence time (through removing impoundments) and light/temperature (by increasing riparian tree shading) may offer more realistic solutions than reducing phosphorus concentrations for controlling excessive phytoplankton biomass. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

  14. Novel Agricultural Conservation System with Sustained Yield and Decreased Water, Nutrient, Energy, and Carbon Footprints

    NASA Astrophysics Data System (ADS)

    Hansen, K.; Shukla, S.; Holt, N.; Hendricks, G.; Sishodia, R. P.

    2017-12-01

    Fresh fruits and vegetables are conventionally grown in raised bed plasticulture (RBP), a high intensity, high input, and high output production system. In 2016, the fresh market plasticulture industry covered 680,000 ha in the US, producing crops (e.g. tomato, peppers, melons, and strawberries) valued at ten billion dollars. To meet the increasing future demand for fresh fruits and vegetables and sustain the production potential of croplands, a transformation of the conventional food-water-energy nexus is essential. A novel agricultural conservation system, compact bed geometry, has been proposed to shift the paradigm in RBP, sustaining yield and decreasing inputs (e.g. water, nutrients, energy, and carbon). Compact bed geometries fit the shape of the wetting front created when water is applied through drip irrigation on the production soil, creating a taller (23-30 cm) and thinner bed (66-41 cm). Two seasons of tomato (single row) and pepper (double row) production, in the environmentally fragile watershed of the Florida Everglades, highlight the potential impact of compact bed geometry on environmental sustainability in agricultural production. No difference in plant growth or yield was detected, with a reduction of 5-50% in irrigation water, up to 20% less N application, 12% less P, 20% less K, and 5-15% less carbon dioxide emissions. The hydrologic benefits of compact bed geometry include 26% less runoff generation, decreased need for active drainage pumping, and increased residence time for irrigation water within the bed, overall decreasing instances of nutrient leaching. A water related co-benefit observed was a reduction in the occurrences of Phytophthora capsici in pepper, which has the potential to reduce yield by as much as 70%. Non-water co-benefits include up to a 250/ ha reduction in production cost, with the potential to save the industry 200 million dollars annually. This economic benefit has led to rapid industry adoption, with more than 20

  15. Sunlight Induced Preparation of Functionalized Gold Nanoparticles as Recyclable Colorimetric Dual Sensor for Aluminum and Fluoride in Water.

    PubMed

    Kumar, Anshu; Bhatt, Madhuri; Vyas, Gaurav; Bhatt, Shreya; Paul, Parimal

    2017-05-24

    A sunlight induced simple green route has been developed for the synthesis of polyacrylate functionalized gold nanoparticles (PAA-AuNPs), in which poly(acrylic acid) functions as a reducing as well as stabilizing agent. This material has been characterized on the basis of spectroscopic and microscopic studies; it exhibited selective colorimetric detection of Al 3+ in aqueous media, and the Al 3+ induced aggregated PAA-AuNPs exhibited detection of F - with sharp color change and high selectivity and sensitivity out of a large number of metal ions and anions tested. The mechanistic study revealed that, for Al 3+ , the color change is due to a shift of the SPR band because of the Al 3+ induced aggregation of PAA-AuNPs, whereas for F - , the reverse color change (blue to red) with return of the SPR band to its original position is due to dispersion of aggregated PAA-AuNPs, as F - removes Al 3+ from the aggregated species by complex formation. Only concentration-dependent fluoride ion can prevent Al 3+ from aggregating PAA-AuNPs. The method is successfully used for the detection of F - in water collected from various sources by the spiking method, in toothpastes of different brands by the direct method. The solid Al 3+ -PAA-AuNPs were isolated, adsorbed on ZIF@8 (zeolitic imidazolate framework) and on a cotton strip, and applied as solid sensing material for detection of F - in aqueous media.

  16. Drug-nutrient interaction.

    PubMed

    Matsui, M S; Rozovski, S J

    1982-01-01

    The effect of certain drugs on nutrient metabolism is discussed. Antituberculotic drugs such as INH and cycloserine interfere with vitamin B6 metabolism and may produce a secondary niacin deficiency. Oral contraceptives interfere with the metabolism of folic acid and ascorbic acid, and in cases of deficient nutrition, they also seem to interfere with riboflavin. Anticonvulsants can act as folate antagonists and precipitate folic acid deficiency. Therefore, in some cases, supplementation with folate has been recommended simultaneously with anticonvulsant therapy. Cholestyramine therapy has been associated with malabsorption of vitamins; several reports suggest that cholestyramine affects absorption of the fat-soluble vitamins K and D and, in addition, may alter water-soluble vitamins, including folic acid. The study of the interaction of drugs and nutrients is an area that deserves a greater attention in the future, especially in groups where nutrient deficiencies may be prevalent.

  17. NITRATE RELEASE BY SALT MARSH PLANTS: AN OVERLOOKED NUTRIENT FLUX MECHANISM

    EPA Science Inventory

    Salt marshes provide water purification as an important ecosystem service in part by storing, transforming and releasing nutrients. This service can be quantified by measuring nutrient fluxes between marshes and surface waters. Many processes drive these fluxes, including photosy...

  18. Temporal Stability of the Microbial Community in Sewage-Polluted Seawater Exposed to Natural Sunlight Cycles and Marine Microbiota

    PubMed Central

    Sassoubre, Lauren M.; Yamahara, Kevan M.

    2015-01-01

    Billions of gallons of untreated wastewater enter the coastal ocean each year. Once sewage microorganisms are in the marine environment, they are exposed to environmental stressors, such as sunlight and predation. Previous research has investigated the fate of individual sewage microorganisms in seawater but not the entire sewage microbial community. The present study used next-generation sequencing (NGS) to examine how the microbial community in sewage-impacted seawater changes over 48 h when exposed to natural sunlight cycles and marine microbiota. We compared the results from microcosms composed of unfiltered seawater (containing naturally occurring marine microbiota) and filtered seawater (containing no marine microbiota) to investigate the effect of marine microbiota. We also compared the results from microcosms that were exposed to natural sunlight cycles with those from microcosms kept in the dark to investigate the effect of sunlight. The microbial community composition and the relative abundance of operational taxonomic units (OTUs) changed over 48 h in all microcosms. Exposure to sunlight had a significant effect on both community composition and OTU abundance. The effect of marine microbiota, however, was minimal. The proportion of sewage-derived microorganisms present in the microcosms decreased rapidly within 48 h, and the decrease was the most pronounced in the presence of both sunlight and marine microbiota, where the proportion decreased from 85% to 3% of the total microbial community. The results from this study demonstrate the strong effect that sunlight has on microbial community composition, as measured by NGS, and the importance of considering temporal effects in future applications of NGS to identify microbial pollution sources. PMID:25576619

  19. Irrigation water acidification to neutralize alkalinity for nursery crop production: Substrate pH, electrical conductivity, nutrient concentrations, and plant nutrition and growth

    USDA-ARS?s Scientific Manuscript database

    Liming agents in irrigation water, typically associated with carbonates and bicarbonates of calcium and magnesium, contribute to water alkalinity. Repeated application of LA to container crops can cause media-solution pH to rise overtime, that uncorrected, can lead to a nutrient availability imbalan...

  20. Salmonella rarely detected in Mississippi coastal waters and sediment.

    PubMed

    Carr, M R; Wang, S Y; McLean, T I; Flood, C J; Ellender, R D

    2010-12-01

    Standards for the rapid detection of individual pathogens from environmental samples have not been developed, but in their absence, the use of molecular-based detection methods coupled with traditional microbiology techniques allows for rapid and accurate pathogen detection from environmental waters and sediment. The aim of this research was to combine the use of enrichment with PCR for detection of Salmonella in Mississippi coastal waters and sediment and observe if that presence correlated with levels of enterococci and climatological variables. Salmonella were primarily found in samples that underwent nutrient enrichment and were present more frequently in freshwater than marine waters. Salmonella were detected infrequently in marine and freshwater sediments. There was a significant positive correlation between the presence of detectable Salmonella and the average enterococcal count. An inverse relationship, however, was observed between the frequency of detection and the levels of salinity, turbidity and sunlight exposure. Results from this study indicated the presence of Salmonella in Mississippi coastal waters, and sediments are very low with significant differences between freshwater and marine environments. Using pathogenic and novel nonpathogenic molecular markers, Salmonella do not appear to be a significant pathogenic genus along the Mississippi Coast. © 2010 The Authors. Journal of Applied Microbiology © 2010 The Society for Applied Microbiology.

  1. Synthesis of graphenized Au/ZnO plasmonic nanocomposites for simultaneous sunlight mediated photo-catalysis and anti-microbial activity.

    PubMed

    Juneja, Subhavna; Madhavan, Ashwathi Asha; Ghosal, Anujit; Ghosh Moulick, Ranjita; Bhattacharya, Jaydeep

    2018-04-05

    Sunlight mediated photo-degradation and anti-bacterial activity of hetero junctioned plasmonic binary (Au/ZnO, RGO/ZnO) and ternary (RGO/Au/ZnO) nanocomposites (NC) have been reported. Higher photo-charge carrier generation, increased charge separation, improved active sites for catalysis, enhanced LSPR and larger photo-response regions have been achieved. Decoration with Au nanoparticles (ca. 11 ± 3 and 48 ± 5 nm) and RGO of ZnO (3D/1D) microstructures (aspect ratio 15.18) provides ternary NCs an edge over mono/bi component catalysts. The ternary NC have shown improved dye degradation capacity with 100% efficiency (5 μM MB solution) and average adsorption degradation capacity (Q°) of 83.34 mg/g within 30 min of sunlight exposure (900 ± 30 Wm -2 ). Elaborated studies by varying reaction parameters like initial dye concentration, contact time, type of NCs and initial loading of NCs reveals pseudo first order degradation kinetics. 100% microbial killing of Gram positive S.aureus strain with 60 μg/ml of NC using sunlight as activator has proven the simultaneous multiple functionality of the NC. Further, facile green one pot hydrothermal synthesis with water as reaction medium, absence of photo-corrosion of NCs, regeneration ability (ca. 90% for 10 μM solution) of NCs, projects a broader potential application of the synthesized NCs and could reduce the continuous requirement of such material, limiting the environmental toxicity. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Anoxic monimolimnia: Nutrients devious feeders or bombs ready to explode?

    NASA Astrophysics Data System (ADS)

    Gianni, Areti; Zacharias, Ierotheos

    2015-04-01

    Coastal regions are under strong human influence and its environmental impact is reflected into their water quality. Oligotrophic estuaries and coastal systems have changed in mesotrophic and/or eutrophic, shown an increase in toxic algal blooms, hypoxic/anoxic events, and massive mortalities of many aquatic and benthic organisms. In strongly stratified and productive water basins, bottom water dissolved oxygen is depleted due to the excessive organic matter decomposition in these depths. Distribution and recycling of nutrients in their water column is inextricably dependent on oxygenation and redox conditions. Bottom water anoxia accelerates PO43-, NH4+ and H2S recycling and accumulation from organic matter decomposition. The anoxic, H2S, PO43- and NH4+ rich bottom water constitutes a toxic layer, threatening the balance of the entire ecosystem. In permanently stratified water basins, storm events could result in stratification destruction and water column total mixing. The turnover brings large amounts of H2S to the surface resulting in low levels of oxygen and massive fish kills. PO43- and NH4+ are released to the interface and surface waters promoting algal blooms. Μore organic matter is produced fueling anoxia. The arising question is, whether the balance of an anoxic water ecosystem is under the threat of its hypolimnetic nutrient and sulfide load, only in the case of storm events and water column total mixing. In polymictic water basins it is clear that the accumulated, in the bottom layer, nutrients will supply surface waters, after the pycnocline overturn. Besides this mechanism of basins' water quality degradation is nowadays recognized as one of the biggest obstacles in eutrophic environments management and restoration efforts. The role of internal load, in permanently stratified water basins, is not so clear. In the present study the impact of storm events on water column stability and bottom water anoxia of meromictic coastal basins, is investigated

  3. Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas; occurrence and distribution of selected pesticides and nutrients at selected surface-water sites in the Mesilla Valley, 1994-95

    USGS Publications Warehouse

    Healy, D.F.

    1996-01-01

    The Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment Program conducted a two-phase synoptic study of the occurrence and distribution of pesticides and nutrients in the surface water of the Mesilla Valley, New Mexico and Texas. Phase one, conducted in April-May 1994 during the high-flow irrigation season, consisted of a 6-week time- series sampling event during which 17 water-column samples were collected at 3 main-stem sites on the Rio Grande and a synoptic irrigation-run sampling event during which 19 water-column samples were collected at 7 main-stem sites, 10 drain sites, and 2 sites at the discharges of wastewater-treatment plants. Three samples are included in both the time-series and irrigation-run events. Phase two, conducted in January 1995 during the low-flow non-irrigation season, consisted of a non-irrigation synoptic sampling event during which 18 water-column samples were collected at seven main-stem sites, nine drain sites, and two sites at the discharges of wastewater-treatment plants and a bed- material sampling event during which 6 bed-material samples were collected at six sites near the mouths of drains that discharge to the Rio Grande. The 51 water-column samples were analyzed for 78 pesticides and metabolites and 8 nutrients along with other constituents. The six bed-material samples were analyzed for 21 pesticides and metabolites, gross polychlorinated biphenyls, and gross polychlorinated naphthalenes. The presence of dissolved pesticides in the surface water of the Mesilla Valley is erratic. A total of 100 detections of 17 different pesticides were detected in 44 of the water-column samples. As many as 38 percent of these detections may be attributed to pesticide use upstream from the valley or to nonagricultural pesticide use within the valley. There were 29 detections of 10 different pesticides in 17 samples during the irrigation run and 41 detections of 13 pesticides in 16 samples during the non

  4. Strong hydrological control on nutrient cycling of subtropical rainforests

    NASA Astrophysics Data System (ADS)

    Lin, T. C.; Chang, C. T.; Huang, J. C.; Wang, L.; Lin, N. H.

    2016-12-01

    Forest nutrient cycling is strongly controlled by both biological and hydrological factors. However, based on a close examination of earlier reports, we highlight the role of hydrological control on nutrient cycling at a global scale and is more important at humid tropical and subtropical forests. we analyzed the nutrient budget of precipitation input and stream water output from 1994 to 2013 in a subtropical forest in Taiwan and conducted a data synthesis using results from 32 forests across the globe. The results revealed that monthly input and output of ions were positively correlated with water quantity, indicating hydrological control on nutrient cycling. Hydrological control is also evident from the greater ions export via stream water during the warm and wet growing season. The synthesis also illustrates that strong hydrological control leads to lower nitrogen retention and greater net loss of base cations in humid regions, particularly in the humid tropical and subtropical forests. Our result is of great significance in an era of global climate change because climate change could directly affect ecosystem nutrient cycling particularly in the tropics through changes in patterns of precipitation regime.

  5. Oxygen, carbon, and nutrient exchanges at the sediment-water interface in the Mar Piccolo of Taranto (Ionian Sea, southern Italy).

    PubMed

    De Vittor, Cinzia; Relitti, Federica; Kralj, Martina; Covelli, Stefano; Emili, Andrea

    2016-07-01

    In the shallow environment, the nutrient and carbon exchanges at the sediment-water interface contribute significantly to determine the trophic status of the whole water column. The intensity of the allochthonous input in a coastal environment subjected to strong anthropogenic pressures determines an increase in the benthic oxygen demand leading to depressed oxygen levels in the bottom waters. Anoxic conditions resulting from organic enrichment can enhance the exchange of nutrients between sediments and the overlying water. In the present study, carbon and nutrient fluxes at the sediment-water interface were measured at two experimental sites, one highly and one moderately contaminated, as reference point. In situ benthic flux measurements of dissolved species (O2, DIC, DOC, N-NO3 (-), N-NO2 (-), N-NH4 (+), P-PO4 (3-), Si-Si(OH)4, H2S) were conducted using benthic chambers. Furthermore, undisturbed sediment cores were collected for analyses of total and organic C, total N, and biopolymeric carbon (carbohydrates, proteins, and lipids) as well as of dissolved species in porewaters and supernatant in order to calculate the diffusive fluxes. The sediments were characterized by suboxic to anoxic conditions with redox values more negative in the highly contaminated site, which was also characterized by higher biopolymeric carbon content (most of all lipids), lower C/N ratios and generally higher diffusive fluxes, which could result in a higher release of contaminants. A great difference was observed between diffusive and in situ benthic fluxes suggesting the enhancing of fluxes by bioturbation and the occurrence of biogeochemically important processes at the sediment-water interface. The multi-contamination of both inorganic and organic pollutants, in the sediments of the Mar Piccolo of Taranto (declared SIN in 1998), potentially transferable to the water column and to the aquatic trophic chain, is of serious concern for its ecological relevance, also considering the

  6. High-frequency monitoring reveals nutrient sources and transport processes in an agriculture-dominated lowland water system

    NASA Astrophysics Data System (ADS)

    van der Grift, Bas; Broers, Hans Peter; Berendrecht, Wilbert; Rozemeijer, Joachim; Osté, Leonard; Griffioen, Jasper

    2016-05-01

    Many agriculture-dominated lowland water systems worldwide suffer from eutrophication caused by high nutrient loads. Insight in the hydrochemical functioning of embanked polder catchments is highly relevant for improving the water quality in such areas or for reducing export loads to downstream water bodies. This paper introduces new insights in nutrient sources and transport processes in a polder in the Netherlands situated below sea level using high-frequency monitoring technology at the outlet, where the water is pumped into a higher situated lake, combined with a low-frequency water quality monitoring programme at six locations within the drainage area. Seasonal trends and short-scale temporal dynamics in concentrations indicated that the NO3 concentration at the pumping station originated from N loss from agricultural lands. The NO3 loads appear as losses via tube drains after intensive rainfall events during the winter months due to preferential flow through the cracked clay soil. Transfer function-noise modelling of hourly NO3 concentrations reveals that a large part of the dynamics in NO3 concentrations during the winter months can be related to rainfall. The total phosphorus (TP) concentration and turbidity almost doubled during operation of the pumping station, which points to resuspension of particulate P from channel bed sediments induced by changes in water flow due to pumping. Rainfall events that caused peaks in NO3 concentrations did not results in TP concentration peaks. The rainfall induced and NO3 enriched quick interflow, may also be enriched in TP but retention of TP due to sedimentation of particulate P then results in the absence of rainfall induced TP concentration peaks. Increased TP concentrations associated with run-off events is only observed during a rainfall event at the end of a freeze-thaw cycle. All these observations suggest that the P retention potential of polder water systems is primarily due to the artificial pumping regime

  7. Blending water- and nutrient-source wastewaters for cost-effective cultivation of high lipid content microalgal species Micractinium inermum NLP-F014.

    PubMed

    Park, Seonghwan; Kim, Jeongmi; Yoon, Youngjin; Park, Younghyun; Lee, Taeho

    2015-12-01

    The possibility of utilizing blended wastewaters from different streams was investigated for cost-efficient microalgal cultivation. The influent of a domestic wastewater treatment plant and the liquid fertilizer from a swine wastewater treatment plant were selected as water- and nutrient-source wastewaters, respectively. The growth of Micractinium inermum NLP-F014 in the blended wastewater medium without any pretreatment was comparable to that in Bold's Basal Medium. The optimum blending ratio of 5-15% (vv(-1)) facilitated biomass production up to 5.7 g-dry cell weight (DCW) L(-1), and the maximum biomass productivity (1.03 g-DCWL(-1)d(-1)) was achieved after three days of cultivation. Nutrient depletion induced lipid accumulation in the cell up to 39.1% (ww(-1)) and the maximum lipid productivity was 0.19 g-FAMEL(-1)d(-1). These results suggest that blending water- and nutrient-source wastewaters at a proper ratio without pretreatment can significantly cut costs in microalgae cultivation for biodiesel production. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Nutrient fluxes via radium isotopes from the coast to offshore and from the seafloor to upper waters after the 2009 spring bloom in the Yellow Sea

    NASA Astrophysics Data System (ADS)

    Su, Ni; Du, Jinzhou; Liu, Sumei; Zhang, Jing

    2013-12-01

    The horizontal and vertical transport of nutrient-rich water both from the coast and from the seafloor to the overlying water column should play an important role in supplying nutrients required for the periods of vegetative or reproductive growth of phytoplankton. In the present work, radium isotopes (223Ra, 224Ra and 226Ra) in the southern Yellow Sea were measured after a spring bloom in June 2009. The exponential-like decrease of 223Ra away from the coast to offshore waters yielded horizontal eddy diffusivities (Kh) of (2.93±1.47)×107 cm2 s-1 by neglecting the advection. This estimate was smaller than that with advection indicator by as much as 21% when using an analytic model for 223Ra and 226Ra. The corresponding horizontal nutrient fluxes were 1525 µmol m-2 d-1 (DIN), 15.9 µmol m-2 d-1 (DIP) and 826 µmol m-2 d-1 (DSi), which would supply around 16% of N and 3% of P requirements based on the primary productivity. The decrease of 224Ra and 223Ra activities from sediments to the upper water column suggests the vertical eddy diffusion coefficient (Kz) of 6.23±5.58 cm2 s-1 below the thermocline, which was within the Yellow Sea Cold Water Mass (YSCWM). The calculated vertical fluxes of nutrient were 4945 μmol m-2 d-1 (DIN), 236 μmol m-2 d-1 (DIP) and 5315 μmol m-2 d-1 (DSi), accounting for up to 52% of N and 40% of P requirements for the phytoplankton growth. These results demonstrate the role of YSCWM as a relative nutrient-rich pool for the supply of nutrient to the southern Yellow Sea via the vertical diffusion process relative to the horizontal process during the summer season. Such processes will be strengthened during the weak density stratification in spring when algal blooms occur.

  9. Groundwater discharge to lakes (GDL) - the disregarded component of lake nutrient budgets

    NASA Astrophysics Data System (ADS)

    Lewandowski, J.; Meinikmann, K.; Pöschke, F.; Nützmann, G.

    2012-04-01

    Eutrophication is a major threat to lakes in temperate climatic zones. It is necessary to determine the relevance of different nutrient sources to conduct effective management measures, to understand in-lake processes and to model future scenarios. A prerequisite for such nutrient budgets are water budgets. While most components of the water budget can be determined quite accurate the quantification of groundwater discharge to lakes (GDL) and surface water infiltration into the aquifer are much more difficult. For example, it is quite common to determine the groundwater component as residual in the water and nutrient budget which is extremely problematic since in that case all errors of the budget terms are summed up in the groundwater term. In total, we identified 10 different reasons for disregarding the groundwater path in nutrient budgets. We investigated the fate of the nutrients nitrogen and phosphorus on their pathway from the catchment through the reactive aquifer-lake interface into the lake. We reviewed the international literature and summarized numbers reported for GDL of nutrients. Since literature is quite sparse we also had a look at numbers reported for submarine groundwater discharge (SGD) of nutrients for which much more literature exists and which is despite some fundamental differences in principal comparable to GDL.

  10. 77 FR 2508 - Rogue River-Siskiyou National Forest, Powers Ranger District, Coos County, OR; Eden Ridge Timber...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-01-18

    ... Probable Sale Quantity. The planning area is located approximately four (4) air miles southeast of the city... for sunlight, and would also reduce competition for water and soil nutrients when compared to... Ridge planning area is located approximately four (4) air miles southeast of the city of Powers, Oregon...

  11. Nutrient management effects on sweetpotato genotypes under controlled environment

    NASA Technical Reports Server (NTRS)

    David, P. P.; Bonsi, C. K.; Trotman, A. A.; Douglas, D. Z.

    1996-01-01

    Sweetpotato is one of several crops recommended by National Aeronautics and Space Administration (NASA) for bioregenerative life support studies. One of the objectives of the Tuskegee University NASA Center is to optimize growth conditions for adaptability of sweetpotatoes for closed bioregenerative systems. The role of nutrient solution management as it impacts yield has been one of the major thrusts in these studies. Nutrient solution management protocol currently used consists of a modified half Hoagland solution that is changed at 14-day intervals. Reservoirs are refilled with deionized water if the volume of the nutrient solution was reduced to 8 liters or less before the time of solution change. There is the need to recycle and replenish nutrient solution during crop growth, rather than discard at 14 day intervals as previously done, in order to reduce waste. Experiments were conducted in an environmental growth room to examine the effects of container size on the growth of several sweetpotato genotypes grown under a nutrient replenishment protocol. Plants were grown from vine cuttings of 15cm length and were planted in 0.15 x 0.15 x 1.2m growth channels using a closed nutrient film technique system. Nutrient was supplied in a modified half strength Hoagland's solution with a 1:2.4 N:K ratio. Nutrient replenishment protocol consisted of daily water replenishment to a constant volume of 30.4 liters in the small containers and 273.6 liters in the large container. Nutrients were replenished as needed when the EC of the nutrient solution fell below 1200 mhos/cm. The experimental design used was a split-plot with the main plot being container size and genotypes as the subplot. Nine sweetpotato genotypes were evaluated. Results showed no effect of nutrient solution container size on storage root yield, foliage fresh and dry mass, leaf area or vine length. However, plants grown using the large nutrient solution container accumulated more storage root dry mass than

  12. SUNLIGHT AS A FACTOR INFLUENCING THE THICKNESS OF EPIDERMIS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Freeman, R.G.; Cockerell, E.G.; Armstrong, J.

    Measurements of epidermal thickness were made on 28 human volunteers. Shortening of rete ridges was found in exposed white skin but was not seen in unexposed skin nor in Negroes. Differences in epidermal thickness related to age, sex, complexion, or variation in sunlight exposure were not statistically significant. (P.C.H.)

  13. Up Goes the Water

    ERIC Educational Resources Information Center

    Damonte, Kathleen

    2004-01-01

    Water is very important to plants. Plants need water to produce food and grow. Plants make their own food through a complex, sunlight-powered process called photosynthesis. Simply put, in photosynthesis, water absorbed by a plant's roots and carbon dioxide taken from the air by a plant's leaves combine to make the plant's food. This article…

  14. Nutrient availability at Mer Bleue bog measured by PRSTM probes

    NASA Astrophysics Data System (ADS)

    Wang, M.; Moore, T. R.; Talbot, J.

    2015-12-01

    Bogs, covering ~0.7 million km2 in Canada, store a large amount of C and N. As nutrient deficient ecosystems, it's critical to examine the nutrient availabilities and seasonal dynamics. We used Plant Root Simulators (PRSTM) at Mer Bleue bog to provide some baseline data on nutrient availability and its variability. In particular, we focused on ammonium, nitrate, phosphate, calcium, magnesium and potassium, iron, sulphate and aluminum. We placed PRS probes at a depth of 5 - 15 cm in pristine plots and plots with long term N, P and K fertilization for 4 weeks and determined the availability of these nutrients, from spring through to fall. Probes were also placed beneath the water table in hummock and hollow microtopography and along a transect including part of the bog which had been drained through the creation of a ditch 80 years ago. The result showed that there was limited available ammonium, nitrate and phosphate in the bog, the seasonal variation of nutrient availabilities probably due to mineralization, an increase in the availability of some nutrients between different water table depths or as a result of drainage, and the relative availability of nutrients compared to the input from fertilization. We suggest that PRS probes could be a useful tool to examine nutrient availability and dynamics in wetlands, with careful consideration of installing condition, for example, proper exposure period, depth relative to water table etc.

  15. Agriculture and future riverine nitrogen export to US coastal regions: Insights from the Nutrient Export from WaterSheds Model

    EPA Science Inventory

    We examine contemporary (2000) and future (2030) estimates of coastal N loads in the continental US by the Nutrient Export from WaterSheds (NEWS) model. Future estimates are based on Millennium Ecosystem Assessment (MEA) scenarios and two additional scenarios that reflect “...

  16. Nutrient vectors and riparian nutrient processing in African semiarid savanna ecosystems

    USGS Publications Warehouse

    Jacobs, Shayne M.; Bechtold, J.S.; Biggs, Harry C.; Grimm, N. B.; McClain, M.E.; Naiman, R.J.; Perakis, Steven S.; Pinay, G.; Scholes, M.C.

    2007-01-01

    This review article describes vectors for nitrogen and phosphorus delivery to riparian zones in semiarid African savannas, the processing of nutrients in the riparian zone and the effect of disturbance on these processes. Semiarid savannas exhibit sharp seasonality, complex hillslope hydrology and high spatial heterogeneity, all of which ultimately impact nutrient fluxes between riparian, upland and aquatic environments. Our review shows that strong environmental drivers such as fire and herbivory enhance nitrogen, phosphorus and sediment transport to lower slope positions by shaping vegetative patterns. These vectors differ significantly from other arid and semiarid ecosystems, and from mesic ecosystems where the impact of fire and herbivory are less pronounced and less predictable. Also unique is the presence of sodic soils in certain hillslopes, which substantially alters hydrological flowpaths and may act as a trap where nitrogen is immobilized while sediment and phosphorus transport is enhanced. Nutrients and sediments are also deposited in the riparian zone during seasonal, intermittent floods while, during the dry season, subsurface movement of water from the stream into riparian soils and vegetation further enrich riparian zones with nutrients. As is found in mesic ecosystems, nutrients are immobilized in semiarid riparian corridors through microbial and plant uptake, whereas dissimilatory processes such as denitrification may be important where labile nitrogen and carbon are in adequate supply and physical conditions are suitablea??such as in seeps, wallows created by animals, ephemeral wetlands and stream edges. Interaction between temporal hydrologic connectivity and spatial heterogeneity are disrupted by disturbances such as large floods and extended droughts, which may convert certain riparian patches from sinks to sources for nitrogen and phosphorus. In the face of increasing anthropogenic pressure, the scientific challenges are to provide a basic

  17. Nutrient and phytoplankton analysis of a Mediterranean coastal area.

    PubMed

    Sebastiá, M T; Rodilla, M

    2013-01-01

    Identifying and quantifying the key anthropogenic nutrient input sources are essential to adopting management measures that can target input for maximum effect in controlling the phytoplankton biomass. In this study, three systems characterized by distinctive main nutrient sources were sampled along a Mediterranean coast transect. These sources were groundwater discharge in the Ahuir area, the Serpis river discharge in the Venecia area, and a submarine wastewater outfall 1,900 m from the coast. The study area includes factors considered important in determining a coastal area as a sensitive area: it has significant nutrient sources, tourism is a major source of income in the region, and it includes an area of high water residence time (Venecia area) which is affected by the harbor facilities and by wastewater discharges. We found that in the Ahuir and the submarine wastewater outfall areas, the effects of freshwater inputs were reduced because of a greater water exchange with the oligotrophic Mediterranean waters. On the other hand, in the Venecia area, the highest levels of nutrient concentration and phytoplankton biomass were attributed to the greatest water residence time. In this enclosed area, harmful dinoflagellates were detected (Alexandrium sp. and Dinophysis caudata). If the planned enlargement of the Gandia Harbor proceeds, it may increase the vulnerability of this system and provide the proper conditions of confinement for the dinoflagellate blooms' development. Management measures should first target phosphorus inputs as this is the most potential-limiting nutrient in the Venecia area and comes from a point source that is easier to control. Finally, we recommend that harbor environmental management plans include regular monitoring of water quality in adjacent waters to identify adverse phytoplankton community changes.

  18. Modelling heterogeneous interfaces for solar water splitting

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pham, Tuan Anh; Ping, Yuan; Galli, Giulia

    2017-01-09

    The generation of hydrogen from water and sunlight others a promising approach for producing scalable and sustainable carbon-free energy. The key of a successful solar-to-fuel technology is the design of efficient, long-lasting and low-cost photoelectrochemical cells, which are responsible for absorbing sunlight and driving water splitting reactions. To this end, a detailed understanding and control of heterogeneous interfaces between photoabsorbers, electrolytes and catalysts present in photoelectrochemical cells is essential. Here we review recent progress and open challenges in predicting physicochemical properties of heterogeneous interfaces for solar water splitting applications using first-principles-based approaches, and highlights the key role of these calculationsmore » in interpreting increasingly complex experiments.« less

  19. Holick's rule and vitamin D from sunlight.

    PubMed

    Dowdy, John C; Sayre, Robert M; Holick, Michael F

    2010-07-01

    Holick's rule says that sun exposure 1/4 of a minimal erythemal dose (MED) over 1/4 of a body is equivalent to 1000 International Units (IU) oral vitamin D3. Webb and Engelsen recently commented that the ultraviolet (UV) spectrum used to establish Holick's rule is unknown. They consequently used a spring midday Boston solar spectrum to estimate ample sunlight exposures for previtamin D3 (preD3) at various locations. Literature review found the source upon which this rule is based was a fluorescent sunlamp (FS lamp). The FS spectrum is known and its relative weighting against the action spectra for erythema and the preD3 is significantly different from the solar spectrum used to derive the standard vitamin D effective dose (SDD). The preD3 effectiveness of the solar spectrum per unit erythemal hazard is greater than the FS lamp by a factor of 1.32. Consequently, UV exposure estimates based on Boston reference sunlight, instead of the UV lamp employed in the originating experiments, over estimate UV exposure equivalent to approximately 1000 IU orally by approximately 1/3. This redefinition of SDD impacts risk/benefit assessments of optimal/feasible sun exposure for vitamin D maintenance and the application of Holick's rule to rational public health messages. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  20. Early fruiting in Synsepalum dulcificum (Schumach. & Thonn.) Daniell juveniles induced by water and inorganic nutrient management

    PubMed Central

    Tchokponhoué, Dèdéou Apocalypse; N'Danikou, Sognigbé; Hale, Iago; Van Deynze, Allen; Achigan-Dako, Enoch Gbènato

    2017-01-01

    Background. The miracle plant, Synsepalum dulcificum (Schumach. & Thonn.) Daniell is a native African orphan crop species that has recently received increased attention due to its promise as a sweetener and source of antioxidants in both the food and pharmaceutical industries. However, a major obstacle to the species’ widespread utilization is its relatively slow growth rate and prolonged juvenile period. Method. In this study, we tested twelve treatments made up of various watering regimes and exogenous nutrient application (nitrogen, phosphorus and potassium, at varying dosages) on the relative survival, growth, and reproductive development of 15-months-old S. dulcificum juveniles. Results. While the plants survived under most tested growing conditions, nitrogen application at doses higher than 1.5 g [seedling] -1 was found to be highly detrimental, reducing survival to 0%. The treatment was found to affect all growth traits, and juveniles that received a combination of nitrogen, phosphorus, and potassium (each at a rate of 1.5 g [seedling] -1), in addition to daily watering, exhibited the most vegetative growth. The simple daily provision of adequate water was found to greatly accelerate the transition to reproductive maturity in the species (from >36 months to an average of 23 months), whereas nutrient application affected the length of the reproductive phase within a season, as well as the fruiting intensity. Conclusions. This study highlights the beneficial effect of water supply and fertilization on both vegetative and reproductive growth in S. dulcificum. Water supply appeared to be the most important factor unlocking flowering in the species, while the combination of nitrogen, phosphorus and potassium at the dose of 1.5 g (for all) consistently exhibited the highest performance for all growth and yield traits. These findings will help intensify S. dulcificum’s breeding and horticultural development. PMID:28620457

  1. Water Purifier

    NASA Technical Reports Server (NTRS)

    1992-01-01

    The Floatron water purifier combines two space technologies - ionization for water purification and solar electric power generation. The water purification process involves introducing ionized minerals that kill microorganisms like algae and bacteria. The 12 inch unit floats in a pool while its solar panel collects sunlight that is converted to electricity. The resulting current energizes a specially alloyed mineral electrode below the waterline, causing release of metallic ions into the water. The electrode is the only part that needs replacing, and water purified by the system falls within EPA drinking water standards.

  2. Nutrient mitigation in a temporary river basin.

    PubMed

    Tzoraki, Ourania; Nikolaidis, Nikolaos P; Cooper, David; Kassotaki, Elissavet

    2014-04-01

    We estimate the nutrient budget in a temporary Mediterranean river basin. We use field monitoring and modelling tools to estimate nutrient sources and transfer in both high and low flow conditions. Inverse modelling by the help of PHREEQC model validated the hypothesis of a losing stream during the dry period. Soil and Water Assessment Tool model captured the water quality of the basin. The 'total daily maximum load' approach is used to estimate the nutrient flux status by flow class, indicating that almost 60% of the river network fails to meet nitrogen criteria and 50% phosphate criteria. We recommend that existing well-documented remediation measures such as reforestation of the riparian area or composting of food process biosolids should be implemented to achieve load reduction in close conjunction with social needs.

  3. Wildfire Effects on In-stream Nutrient Processing and Hydrologic Transport

    NASA Astrophysics Data System (ADS)

    Rhea, A.; Covino, T. P.; Rhoades, C.; Fegel, T.

    2017-12-01

    In many forests throughout the Western U.S., drought, climate change, and growing fuel loads are contributing to increased fire frequency and severity. Wildfires can influence watershed nutrient retention as they fundamentally alter the biological composition and physical structure in upland landscapes, riparian corridors, and stream channels. While numerous studies have documented substantial short-term increases in stream nutrient concentrations and export (particularly reactive nitrogen, N) following forest fires, the long-term implications for watershed nutrient cycling remain unclear. For example, recent work indicates that nitrate concentrations and export can remain elevated for a decade or more following wildfire, yet the controls on these processes are unknown. In this research, we use empirical observations from nutrient tracer injections, nutrient diffusing substrates, and continuous water quality monitoring to isolate biological and physical controls on nutrient export across a burn-severity gradient. Tracer results demonstrate substantial stream-groundwater exchange, but little biological nutrient uptake in burned streams. This in part explains patterns of elevated nutrient export. Paired nutrient diffusing substrate experiments allow us to further investigate shifts in N, phosphorus, and carbon limitation that may suppress post-fire stream nutrient uptake. By isolating the mechanisms that reduce the capacity of fire-affected streams to retain and transform nutrient inputs, we can better predict dynamics in post-fire water quality and help prioritize upland and riparian restoration.

  4. Nutrient processes at the stream-lake interface for a channelized versus unmodified stream mouth

    USGS Publications Warehouse

    Niswonger, Richard G.; Naranjo, Ramon C.; Smith, David; Constantz, James E.; Allander, Kip K.; Rosenberry, Donald O.; Neilson, Bethany; Rosen, Michael R.; Stonestrom, David A.

    2017-01-01

    Inorganic forms of nitrogen and phosphorous impact freshwater lakes by stimulating primary production and affecting water quality and ecosystem health. Communities around the world are motivated to sustain and restore freshwater resources and are interested in processes controlling nutrient inputs. We studied the environment where streams flow into lakes, referred to as the stream-lake interface (SLI), for a channelized and unmodified stream outlet. Channelization is done to protect infrastructure or recreational beach areas. We collected hydraulic and nutrient data for surface water and shallow groundwater in two SLIs to develop conceptual models that describe characteristics that are representative of these hydrologic features. Water, heat, and solute transport models were used to evaluate hydrologic conceptualizations and estimate mean residence times of water in the sediment. A nutrient mass balance model is developed to estimate net rates of adsorption and desorption, mineralization, and nitrification along subsurface flow paths. Results indicate that SLIs are dynamic sources of nutrients to lakes and that the common practice of channelizing the stream at the SLI decreases nutrient concentrations in pore water discharging along the lakeshore. This is in contrast to the unmodified SLI that forms a barrier beach that disconnects the stream from the lake and results in higher nutrient concentrations in pore water discharging to the lake. These results are significant because nutrient delivery through pore water seepage at the lakebed from the natural SLI contributes to nearshore algal communities and produces elevated concentrations of inorganic nutrients in the benthic zone where attached algae grow.

  5. Key role of organic carbon in the sunlight-enhanced atmospheric aging of soot by O2

    PubMed Central

    Han, Chong; Liu, Yongchun; Ma, Jinzhu; He, Hong

    2012-01-01

    Soot particles are ubiquitous in the atmosphere and have important climatic and health effects. The aging processes of soot during long-range transport result in variability in its morphology, microstructure, and hygroscopic and optical properties, subsequently leading to the modification of soot’s climatic and health effects. In the present study the aging process of soot by molecular O2 under simulated sunlight irradiation is investigated. Organic carbon components on the surface of soot are found to play a key role in soot aging and are transformed into oxygen-containing organic species including quinones, ketones, aldehydes, lactones, and anhydrides. These oxygen-containing species may become adsorption centers of water and thus enhance the cloud condensation nuclei and ice nuclei activities of soot. Under irradiation of 25 mW·cm−2, the apparent rate constants (k1,obs) for loss or formation of species on soot aged by 20% O2 were larger by factors of 1.5–3.5 than those on soot aged by 100 ppb O3. Considering the abundance of O2 in the troposphere and its higher photoreactivity rate, the photochemical oxidation by O2 under sunlight irradiation should be a very important aging process for soot. PMID:23236134

  6. Effect of Integrated Water-Nutrient Management Strategies on Soil Erosion Mediated Nutrient Loss and Crop Productivity in Cabo Verde Drylands

    PubMed Central

    Baptista, Isaurinda; Ritsema, Coen; Geissen, Violette

    2015-01-01

    Soil erosion, runoff and related nutrient losses are a big risk for soil fertility in Cabo Verde drylands. In 2012, field trials were conducted in two agro-ecological zones to evaluate the effects of selected techniques of soil-water management combined with organic amendments (T1: compost/manure + soil surfactant; T2: compost/animal or green manure + pigeon-pea hedges + soil surfactant; T3: compost/animal or green manure + mulch + pigeon-pea hedges) on nitrogen (N) and phosphorus (P) losses in eroded soil and runoff and on crop yields. Three treatments and one control (traditional practice) were tested in field plots at three sites with a local maize variety and two types of beans. Runoff and eroded soil were collected after each erosive rain, quantified, and analysed for NO3-N and PO4-P concentrations. In all treatments runoff had higher concentrations of NO3-N (2.20-4.83 mg L-1) than of PO4-P (0.02-0.07 mg L-1), and the eroded soil had higher content of PO4-P (5.27-18.8 mg g-1) than of NO3-N (1.30-8.51 mg g-1). The control had significantly higher losses of both NO3-N (5.4, 4.4 and 19 kg ha-1) and PO4-P (0.2, 0.1 and 0.4 kg ha-1) than the other treatments. T3 reduced soil loss, runoff and nutrient losses to nearly a 100% while T1 and T2 reduced those losses from 43 to 88%. The losses of NO3-N and PO4-P were highly correlated with the amounts of runoff and eroded soil. Nutrient losses from the applied amendments were low (5.7% maximum), but the losses in the control could indicate long-term nutrient depletion in the soil (19 and 0.4 kg ha-1 of NO3-N and PO4-P, respectively). T1-T3 did not consistently increase crop yield or biomass in all three sites, but T1 increased both crop yield and biomass. We conclude that T3 (combining crop-residue mulch with organic amendment and runoff hedges) is the best treatment for steep slope areas but, the pigeon-pea hedges need to be managed for higher maize yield. T1 (combining organic amendment with soil surfactant) could be a

  7. Effect of Integrated Water-Nutrient Management Strategies on Soil Erosion Mediated Nutrient Loss and Crop Productivity in Cabo Verde Drylands.

    PubMed

    Baptista, Isaurinda; Ritsema, Coen; Geissen, Violette

    2015-01-01

    Soil erosion, runoff and related nutrient losses are a big risk for soil fertility in Cabo Verde drylands. In 2012, field trials were conducted in two agro-ecological zones to evaluate the effects of selected techniques of soil-water management combined with organic amendments (T1: compost/manure + soil surfactant; T2: compost/animal or green manure + pigeon-pea hedges + soil surfactant; T3: compost/animal or green manure + mulch + pigeon-pea hedges) on nitrogen (N) and phosphorus (P) losses in eroded soil and runoff and on crop yields. Three treatments and one control (traditional practice) were tested in field plots at three sites with a local maize variety and two types of beans. Runoff and eroded soil were collected after each erosive rain, quantified, and analysed for NO3-N and PO4-P concentrations. In all treatments runoff had higher concentrations of NO3-N (2.20-4.83 mg L-1) than of PO4-P (0.02-0.07 mg L-1), and the eroded soil had higher content of PO4-P (5.27-18.8 mg g-1) than of NO3-N (1.30-8.51 mg g-1). The control had significantly higher losses of both NO3-N (5.4, 4.4 and 19 kg ha-1) and PO4-P (0.2, 0.1 and 0.4 kg ha-1) than the other treatments. T3 reduced soil loss, runoff and nutrient losses to nearly a 100% while T1 and T2 reduced those losses from 43 to 88%. The losses of NO3-N and PO4-P were highly correlated with the amounts of runoff and eroded soil. Nutrient losses from the applied amendments were low (5.7% maximum), but the losses in the control could indicate long-term nutrient depletion in the soil (19 and 0.4 kg ha-1 of NO3-N and PO4-P, respectively). T1-T3 did not consistently increase crop yield or biomass in all three sites, but T1 increased both crop yield and biomass. We conclude that T3 (combining crop-residue mulch with organic amendment and runoff hedges) is the best treatment for steep slope areas but, the pigeon-pea hedges need to be managed for higher maize yield. T1 (combining organic amendment with soil surfactant) could be a

  8. Fine particle water and pH in the Eastern Mediterranean: Sources, variability and implications for nutrients availability

    NASA Astrophysics Data System (ADS)

    Bougiatioti, Aikaterini; Nikolaou, Panayiota; Stavroulas, Iasonas; Kouvarakis, Giorgos; Nenes, Athanasios; Weber, Rodney; Kanakidou, Maria; Mihalopoulos, Nikolaos

    2016-04-01

    Atmospheric particles have the ability to absorb significant amounts of water, which greatly impacts on their physical and chemical properties. Direclty linked to aerosol pH and LWC is the bioavailability of nutrients contained within mineral dust, involving pH-dependent catalyzed redox-reaction pathways. Liquid water content (LWC) and pH, even though are important constituents of the aerosol phase, are rarely monitored. Direct measurements of aerosol pH "in situ" are scarce and require considerations owing to the non-conserved nature of the hydronium ion and partial dissociation of inorganic and organic electrolytes in the aerosol. To overcome these challenges, indirect alternatives such as measuring the semi-volatile partitioning of key species sensitive to pH, combined with comprehensive models are used to provide a reasonably accurate estimate of pH that can be carried out with routine measurements. Using concurrent measurements of aerosol chemical composition, tandem light scattering coefficients and the thermodynamic model ISORROPIA-II, LWC mass concentrations associated with the aerosol inorganic and organic components are determined for the remote background site of Finokalia, Crete. The predicted water was subsequently compared to the one measured by the ambient versus dry light scattering coefficients. The sum of Winorg and Worg was highly correlated and in close agreement with the measured LWC (on average within 10%), with slope 0.92 (R2=0.8) for the whole measurement period between August and November 2012 (n=5201 points). As expected, the highest fine aerosol water values are observed during night-time, when RH is at its maximum, resulting in important water uptake. The average concentration of total aerosol water was found to be 2.19±1.75 μg m-3, which according to the dry mass measurements, can contribute on average up to 33% to the total aerosol submicron mass. The average Worg was found to be 0.56±0.37 μg m-3, which constitutes about 28% of the

  9. Habitat-specific nutrient removal and release in Oregon salt marshes

    EPA Science Inventory

    Wetlands can be sources, sinks and transformers of nutrients, although it is their role in nutrient removal that is valued as a water purification ecosystem service. In order to quantify that service for any wetland, it is important to understand the drivers of nutrient removal w...

  10. Ventilation History of the Tropical Atlantic Thermocline: New Insights From the Sensitivity of Foraminifera to Water Mass Nutrient Concentrations

    NASA Astrophysics Data System (ADS)

    Sexton, P. F.; Norris, R. D.

    2008-12-01

    The sensitivity of certain species of foraminifera to nutrient distributions throughout today's oceans highlights their potential for reconstructing water mass nutrient distributions in the past. Applying these new insights to reconstructed abundances of several key species during the last glacial, we find that thermocline waters throughout the entire tropical Atlantic were better ventilated than today. These findings are in line with independent evidence for stronger intermediate-depth ventilation driven by widespread Glacial North Atlantic Intermediate Water (GNAIW), supporting the validity of our new approach. Our results also suggest that well- ventilated GNAIW penetrated at least as far as 25 degrees South, thereby confining the northernmost glacial limits of poorly ventilated Antarctic Intermediate Water (AAIW) to the southernmost Atlantic. We show that the glacial Atlantic thermocline switched to its modern, more poorly ventilated state (probably indicative of a return of AAIW dominance) in a two-step process: a transient reduction in ventilation during the Bolling/Allerod, with the definitive switch to a regime of poor thermocline ventilation occurring at the close of the Younger Dryas. Furthermore, longer-term reconstructions of past distributions of these several key foraminiferal species suggest that a major and enduring impact of glacial-interglacial cycles on Atlantic hydrography has been this vacillating behaviour in tropical thermocline ventilation.

  11. Seasonal variation in physicochemical properties of coastal waters of Kalpakkam, east coast of India with special emphasis on nutrients.

    PubMed

    Satpathy, K K; Mohanty, A K; Natesan, U; Prasad, M V R; Sarkar, S K

    2010-05-01

    A study pertaining to the seasonal variation in physicochemical properties of the coastal waters was carried out at Kalpakkam coast for a period of 1 year (February 2006 to January 2007). It revealed that the coastal water was significantly influenced by freshwater input during North East (NE) monsoon and post-monsoon periods. Concentration of all the nutrients and dissolved oxygen (DO) was relatively high during the NE monsoon, whereas, salinity and chlorophyll-a (chl-a) were at their minimum level during this period. Phytoplankton production peak was observed in summer during which a typical marine condition prevailed. The present observed values of nitrate, phosphate, silicate, and turbidity are significantly high (five to ten times) compared to that of the pre-Tsunami period from this coast. Relatively low DO and chl-a concentration was noticed during the post-Tsunami period. A notable feature of this study is that though nutrient concentration in the coastal waters during post-Tsunami period has increased significantly, turbidity, the most single dominating factor, was found to adversely affect the phytoplankton production during post-Tsunami period as reflected by relatively low chl-a concentration. Thus, the post-Tsunami period may result in a change in coastal biodiversity pattern concomitant with change in coastal water quality.

  12. Adding Remote Sensing Data Products to the Nutrient Management Decision Support Toolbox

    NASA Technical Reports Server (NTRS)

    Lehrter, John; Schaeffer, Blake; Hagy, Jim; Spiering, Bruce; Blonski, Slawek; Underwood, Lauren; Ellis, Chris

    2011-01-01

    Some of the primary issues that manifest from nutrient enrichment and eutrophication (Figure 1) may be observed from satellites. For example, remotely sensed estimates of chlorophyll a (chla), total suspended solids (TSS), and light attenuation (Kd) or water clarity, which are often associated with elevated nutrient inputs, are data products collected daily and globally for coastal systems from satellites such as NASA s MODIS (Figure 2). The objective of this project is to inform water quality decision making activities using remotely sensed water quality data. In particular, we seek to inform the development of numeric nutrient criteria. In this poster we demonstrate an approach for developing nutrient criteria based on remotely sensed chla.

  13. Water-quality assessment of the Lower Susquehanna River Basin, Pennsylvania and Maryland; sources, characteristics, analysis and limitations of nutrient and suspended-sediment data, 1975-90

    USGS Publications Warehouse

    Hainly, R.A.; Loper, C.A.

    1997-01-01

    This report describes analyses of available information on nutrients and suspended sediment collected in the Lower Susquehanna River Basin during water years 1975-90. Most of the analyses were applied to data collected during water years 1980-89. The report describes the spatial and temporal availability of nutrient and suspended-sediment data and presents a preliminary concept of the spatial and temporal patterns of concentrations and loads within the basin. Where data were available, total and dissolved forms of nitrogen and phosphorus species from precipitation, surface water, ground water, and springwater, and bottom material from streams and reservoirs were evaluated. Suspended-sediment data from streams also were evaluated. The U.S. Geological Survey National Water Information System (NWIS) database was selected as the primary database for the analyses. Precipitation-quality data from the National Atmospheric Deposition Program (NADP) and bottom-material-quality data from the National Uranium Resource Evaluation (NURE) were used to supplement the water-quality data from NWIS. Concentrations of nutrients were available from 3 precipitation sites established for longterm monitoring purposes, 883 wells (854 synoptic areal survey sites and 29 project and research sites), 23 springs (17 synoptic areal survey sites and 6 project and research sites), and 894 bottom-material sites (840 synoptic areal survey sites and 54 project and research sites). Concentrations of nutrients and (or) suspended sediment were available from 128 streams (36 long-term monitoring sites, 51 synoptic areal survey sites, and 41 project and research sites). Concentrations of nutrients and suspended sediment in streams varied temporally and spatially and were related to land use, agricultural practices, and streamflow. A general north-to-south pattern of increasing median nitrate concentrations, from 2 to 5 mg/L, was detected in samples collected in study unit streams. In streams that drain

  14. Combining Natural Attenuation Capacity and use of Targeted Technological Mitigation Measures for Reducing Diffuse Nutrient Emissions to Surface Waters: The Danish Way

    NASA Astrophysics Data System (ADS)

    Kronvang, B.; Højberg, A. L.; Hoffmann, C. C.; Windolf, J.; Blicher-Mathiesen, G.

    2015-12-01

    Excess nitrogen (N) and phosphorus (P) emissions to surface waters are a high priority environmental problem worldwide for protection of water resources in times of population growth and climate change. As clean water is a scarce resource the struggle for reducing nutrient emissions are an ongoing issue for many countries and regions. Since the mid1980s a wide range of national regulatory general measures have been implemented to reduce land based nitrogen (N) and phosphorus (P) loadings of the Danish aquatic environment. These measures have addressed both point source emissions and emissions from diffuse sources especially from agricultural production. Following nearly 4 decades of combating nutrient pollution our surface waters such as lakes and estuaries are only slowly responding on the 50% reduction in N and 56% reduction in P. Therefore, the implementation of the EU Water Framework Directive in Danish surface waters still call for further reductions of N and P loadings. Therefore, a new era of targeted implemented measures was the outcome of a Commission on Nature and Agriculture established by the Danish Government in 2013. Their White Book points to the need of increased growth and better environment through more targeted and efficient regulation using advanced technological mitigation methods that are implemented intelligently according to the local natural attenuation capacity for nutrients in the landscape. As a follow up a national consensus model for N was established chaining existing leaching, 3D groundwater and surface water models that enable a calculation of the N dynamics and attenuation capacity within a scale of 15 km2. Moreover, several research projects have been conducted to investigate the effect of a suite of targeted mitigation measures such as restored natural wetlands, constructed wetlands, controlled drainage, buffer strips and constructed buffer strips. The results of these studies will be shared in this presentation.

  15. Quantifying the effects of conservation practices on soil, water, and nutrients in the Loess Mesa Ravine Region of the Loess Plateau, China.

    PubMed

    Xu, Xiang-Zhou; Li, Mei-Juan; Liu, Bin; Kuang, Shang-Fu; Xu, Shi-Guo

    2012-05-01

    A large number of soil and water conservation programs have been implemented on the Loess Plateau of China since the 1950s. To comprehensively assess the merits and demerits of the conservation practices is of great importance in further supervising the conservation strategy for the Loess Plateau. This study calculates the impact factors of conservation practices on soil, water, and nutrients during the period 1954-2004 in the Nanxiaohegou Catchment, a representative catchment in the Loess Mesa Ravine Region of the Loess Plateau, China. Brief conclusions could be drawn as follows: (1) Soil erosion and nutrient loss had been greatly mitigated through various conservation practices. About half of the total transported water and 94.8 % of the total transported soil and nutrients, had been locally retained in the selected catchment. The soil retained from small watersheds do not only form large-scale fertile farmland but also safeguard the Yellow River against overflow. (2) Check dam was the most appropriate conservation practice on the Loess Plateau. In the selected catchment, more than 90 % of the retained soil and water were accomplished by the dam farmland, although the dam farmland occupied only 2.3 % of the total area of all conservation measures. Retention abilities of the characteristic conservation practices were in the following order: dam farmland > terrace farmland > forest land and grassland. (3) The conservation practices were more powerful in retaining sediment than in reducing runoff from the Loess Plateau, and the negative effects of the conservation practices on reducing water to the Yellow River were relatively slight.

  16. Incorporated Woodchips as a Novel Intervention to Support Plant Growth through Increased Water Holding Capacity and Nutrient Retention in Sandy Degraded Soils

    NASA Astrophysics Data System (ADS)

    Menzies, E.; Schneider, R.; Walter, T.

    2017-12-01

    According to the World Wildlife Federation's most recent Plow Print report 53 million acres of temperate, water limited, grasslands across the Great Plains have been converted to agriculture since 2009. This conversion very often begins the process of soil degradation which can lead to desertification and the necessity to convert more land to agriculture. The most common solution to this problem is improved crop efficiency to reduce conversion of grasslands to agriculture while still producing enough food for us all. We suggest that while that may be the beginning of the solution, degraded soils need to be rehabilitated and brought back into production to adequately provide food crops for the increasing population of the globe. Incorporated woodchips can be used to improve the soils' water holding capacity and nutrient (N and P) retention. In a previous study we observed an increase in the gravimetric water content and a decrease in soluble N and P losses when fertilizers were applied in liquid form in soil columns with incorporated woodchips (see attached figure). In this study we examine the availability of the retained water and nutrients to grasses to determine the extent to which this intervention might be used to reestablish plant growth in degraded sandy soils. We also begin examining the quantity of woodchips necessary to retain sufficient water and nutrients to sustain the growth of grasses over the course of a growing season. A laboratory soil column study is currently underway to examine these questions; the results of this study will be presented at the Fall Meeting.

  17. Stream-water chemistry, nutrients, and pesticides in Town Brook, a headwater stream of the Cannonsville Reservoir Watershed, Delaware County, New York, 1999

    USGS Publications Warehouse

    McHale, Michael R.; Phillips, Patrick J.

    2001-01-01

    Stream-water chemistry was monitored from January 1 through December 31, 1999, in the Town Brook watershed (TBW) in Delaware County, N.Y. to provide a basis for future evaluation of the effectiveness of Best Management Practices (BMPs) in decreasing agricultural nutrient and pesticide leaching to receiving waters. Total runoff from the watershed during 1999 was 664 millimeters (mm). Annual nutrient export (in kilograms per hectare) values were: ammonia (NH3), 0.25; nitrate (NO3-), 4.3; total nitrogen (TN), 10.6; orthophosphate (OP), 0.26; total dissolved phosphorus (TDP), 0.30; and total phosphorus (TP), 1.2 during 1999. Streamwater samples were collected during baseflow, elevated baseflow, and stormflow conditions. Stormflow, which produced the greatest flowweighted mean nutrient concentrations, represented only 41 percent of the annual runoff but accounted from 49 to 68 percent of the annual nutrient export. The highest seasonal flow-weighted mean concentrations were measured during the summer; the highest concentrations occurred during a large storm on July 4, 1999 with a recurrence interval greater than 100 years. The greatest seasonal export of dissolved nutrients (NH3, NO3-, OP, and TDP) occurred during the winter, whereas the greatest export of TN and TP was during the summer. Most of the TN and TP export during the summer occurred during the July 4 storm. That storm, together with a second large storm on September 16, 1999, accounted for the following percentages of annual export: ammonia, 17 percent; NO3-, 21 percent; TN, 45 percent; OP, 21 percent; TDP, 21 percent; and TP, 56 percent. Although these results provide information on the quantity and timing of nutrient export, they do not indicate the nutrient source nor the transport mechanisms by which nutrients are delivered to the stream.Baseflow and stormflow samples were collected for pesticide analyses at the Town Brook watershed outlet from January through July 1999. Eight pesticides and pesticide

  18. Modified optical fiber daylighting system with sunlight transportation in free space.

    PubMed

    Vu, Ngoc-Hai; Pham, Thanh-Tuan; Shin, Seoyong

    2016-12-26

    We present the design, optical simulation, and experiment of a modified optical fiber daylighting system (M-OFDS) for indoor lighting. The M-OFDS is comprised of three sub-systems: concentration, collimation, and distribution. The concentration part is formed by coupling a Fresnel lens with a large-core plastic optical fiber. The sunlight collected by the concentration sub-system is propagated in a plastic optical fiber and then collimated by the collimator, which is a combination of a parabolic mirror and a convex lens. The collimated beam of sunlight travels in free space and is guided to the interior by directing flat mirrors, where it is diffused uniformly by a distributor. All parameters of the system are calculated theoretically. Based on the designed system, our simulation results demonstrated a maximum optical efficiency of 71%. The simulation results also showed that sunlight could be delivered to the illumination destination at distance of 30 m. A prototype of the M-OFDS was fabricated, and preliminary experiments were performed outdoors. The simulation results and experimental results confirmed that the M-OFDS was designed effectively. A large-scale system constructed by several M-OFDSs is also proposed. The results showed that the presented optical fiber daylighting system is a strong candidate for an inexpensive and highly efficient application of solar energy in buildings.

  19. Trees and Streets as Drivers of Urban Stormwater Nutrient Pollution.

    PubMed

    Janke, Benjamin D; Finlay, Jacques C; Hobbie, Sarah E

    2017-09-05

    Expansion of tree cover is a major management goal in cities because of the substantial benefits provided to people, and potentially to water quality through reduction of stormwater volume by interception. However, few studies have addressed the full range of potential impacts of trees on urban runoff, which includes deposition of nutrient-rich leaf litter onto streets connected to storm drains. We analyzed the influence of trees on stormwater nitrogen and phosphorus export across 19 urban watersheds in Minneapolis-St. Paul, MN, U.S.A., and at the scale of individual streets within one residential watershed. Stormwater nutrient concentrations were highly variable across watersheds and strongly related to tree canopy over streets, especially for phosphorus. Stormwater nutrient loads were primarily related to road density, the dominant control over runoff volume. Street canopy exerted opposing effects on loading, where elevated nutrient concentrations from trees near roads outweighed the weak influence of trees on runoff reduction. These results demonstrate that vegetation near streets contributes substantially to stormwater nutrient pollution, and therefore to eutrophication of urban surface waters. Urban landscape design and management that account for trees as nutrient pollution sources could improve water quality outcomes, while allowing cities to enjoy the myriad benefits of urban forests.

  20. In situ nitrification rates and activity of present nitrifiers in the bottom water layer of two Baltic coastal zones affected by different riverine nutrient loads

    NASA Astrophysics Data System (ADS)

    Bartl, I.; Münster Happel, E.; Riemann, L.; Voss, M.

    2016-02-01

    Baltic coastal zones are among the most eutrophied in the world receiving high loads of nitrogen from riverine inputs. However, not only the loads but also the internal dynamics in coastal zones might have positive feedback on eutrophication through efficient remineralisation of organic material in the bottom water. Therefore, we studied nitrification, which is a vital remineralisation process, near the seafloor along with the community of nitrifying microorganisms. We hypothesize that a high nutrient and organic matter load leads to elevated ammonium concentrations in coastal waters and thus stimulates nitrification rates and alters the nitrifying community. Here we present results from 3 cruises combining nitrification rate measurements by 15N-incubations with sequence-based analyses of present and active nitrifiers in the bottom water of two sites in the Baltic Sea receiving different nutrient loads. The first results from the Bonus projects COCOA and BLUEPRINT indicate an increase of nitrification rates with depth as well as distance from the river mouth. In situ rates in the bottom water of the nutrient rich Vistula plume range from 53 to 197 nmol L-1 d-1 and from 10 to 646 nmol L-1 d-1 during winter and summer, respectively. In the nutrient poor Öre estuary rates increased significantly by 11 nmol L-1 d-1 from the river mouth to the outermost station. The relationship between nitrification rates, nitrifiers and trophic state of the coastal zone shall be discussed.