Sample records for 10sup minus11 cmsup

  1. Physics at 10/sup 34/ cm/sup -2/ s/sup -1/

    SciTech Connect

    Diebold, R.; Wagner, R.


    Most of the detector studies at Snowmass-84 have rightfully concentrated on detailed studies of individual interactions - their rates, signatures, and backgrounds. Depending on the physics and the detector components, there seems to be agreement that general-purpose detectors will likely be able to accept luminosities up to 10/sup 32 -33/ cm/sup -2/ s/sup -1/. The purpose of this paper is to show how the physics reach of the SSC is extended by going to a luminosity of 10/sup 34/ cm/sup -2/ s/sup -1/, to take a first look at what sort of detector could be used at this luminosity, and to discuss how one might trigger on interesting events in the presence of many overlapping minimum bias events. We will assume that the SSC turns on at 10/sup 31/ or 10/sup 32/ cm/sup -2/ s/sup -1/, with an increase of luminosity to 10/sup 33/ over a period of a few years as the machine and detectors become better understood. Thus, the lower mass scale will have been explored and we can set our thresholds high when running 10/sup 34/.

  2. Pattern recognition in the GEM central tracker at luminosity of 10{sup 33} cm{sup {minus}2}s{sup {minus}1}

    SciTech Connect

    Brooks, M.L.; Kinnison, W.W.


    A GEANT based pattern recognition algorithm has been developed for simulations of the GEM central tracker. We describe the pattern recognition algorithm and present the results of studies of the track finding efficiency for single isolated tracks and for all tracks present in a Higgs event with minimum bias background at luminosity 10{sup 33} cm{sup {minus}2}s{sup {minus}l}.

  3. Ultrahigh B doping ({<=}10{sup 22} cm{sup -3}) during Si(001) gas-source molecular-beam epitaxy: B incorporation, electrical activation, and hole transport

    SciTech Connect

    Glass, G.; Kim, H.; Desjardins, P.; Taylor, N.; Spila, T.; Lu, Q.; Greene, J. E.


    Si(001) layers doped with B concentrations C{sub B} between 1x10{sup 17} and 1.2x10{sup 22} cm{sup -3} (24 at %) were grown on Si(001)2x1 at temperatures T{sub s}=500-850 degree sign C by gas-source molecular-beam epitaxy from Si{sub 2}H{sub 6} and B{sub 2}H{sub 6}. C{sub B} increases linearly with the incident precursor flux ratio J{sub B{sub 2}}{sub H{sub 6}}/J{sub Si{sub 2}}{sub H{sub 6}} and B is incorporated into substitutional electrically active sites at concentrations up to C{sub B}{sup *}(T{sub s}) which, for T{sub s}=600 degree sign C, is 2.5x10{sup 20} cm{sup -3}. At higher B concentrations, C{sub B} increases faster than J{sub B{sub 2}}{sub H{sub 6}}/J{sub Si{sub 2}}{sub H{sub 6}} and there is a large and discontinuous decrease in the activated fraction of incorporated B. However, the total activated B concentration continues to increase and reaches a value of N{sub B}=1.3x10{sup 21} cm{sup -3} with C{sub B}=1.2x10{sup 22} cm{sup -3}. High-resolution x-ray diffraction (HR-XRD) and reciprocal space mapping measurements show that all films, irrespective of C{sub B} and T{sub s}, are fully strained. No B precipitates or misfit dislocations were detected by HR-XRD or transmission electron microscopy. The lattice constant in the film growth direction a{sub (perpendicular} {sub sign)} decreases linearly with increasing C{sub B} up to the limit of full electrical activation and continues to decrease, but nonlinearly, with C{sub B}>C{sub B}{sup *}. Room-temperature resistivity and conductivity mobility values are in good agreement with theoretical values for B concentrations up to C{sub B}=2.5x10{sup 20} and 2x10{sup 21} cm{sup -3}, respectively. All results can be explained on the basis of a model which accounts for strong B surface segregation to the second-layer with a saturation coverage {theta}{sub B,sat} of 0.5 ML (corresponding to C{sub B}=C{sub B}{sup *}). At higher C{sub B} (i.e., {theta}{sub B}>{theta}{sub B,sat}), B accumulates in the upper layer as

  4. Measurements of Energy Transport Patterns in Solid Density Laser Plasma Interactions at Intensities of 5x10{sup 20} W cm{sup -2}

    SciTech Connect

    Lancaster, K. L.; Clarke, R. J.; Green, J. S.; Murphy, C. D.; Norreys, P. A.; Hey, D. S.; Akli, K. U.; Davies, J. R.; Habara, H.; Nakatsutsumi, M.; Yabuuchi, T.; Key, M. H.; Kodama, R.; Krushelnick, K.; Simpson, P.; Zepf, M.; Stephens, R.; Stoeckl, C.


    K{sub {alpha}} x-ray emission, extreme ultraviolet emission, and plasma imaging techniques have been used to diagnose energy transport patterns in copper foils ranging in thickness from 5 to 75 {mu}m for intensities up to 5x10{sup 20} W cm{sup -2}. The K{sub {alpha}} emission and shadowgrams both indicate a larger divergence angle than that reported in the literature at lower intensities [R. Stephens et al., Phys. Rev. E 69, 066414 (2004)]. Foils 5 {mu}m thick show triple-humped plasma expansion patterns at the back and front surfaces. Hybrid code modeling shows that this can be attributed to an increase in the mean energy of the fast electrons emitted at large radii, which only have sufficient energy to form a plasma in such thin targets.

  5. Spectroscopic investigations of hard x-ray emission from 120 ps laser-produced plasmas at intensities near 10{sup 17} W cm{sup {minus}2}

    SciTech Connect

    Dunn, J.; Young, B.K.F.; Osterheld, A.L.; Foord, M.E.; Walling, R.S.; Stewart, R.E.; Faenov, A.Y.


    Spectroscopic investigations of the x-ray emission of plasmas heated by 120 ps, frequency doubled pulses from the JANUS Nd: glass laser are presented. High Z K-shell spectra emitted from slab targets heated to near 10{sup 17} W cm{sup {minus}2} intensity are investigated. High resolution ({gamma}/{Delta}{gamma}>5000) x-ray spectra of multicharged ions of H-like Ti, Co, Ni, Cu, and also H-like Sc in the spectral range 1.5--3.0 {angstrom} are obtained in single laser shots using a spherically bent Mica crystal spectrograph with a 186 mm radius of curvature. The spectra- have one dimensional spatial resolution of about 25{mu}m and indicate that the size of the emission zone of the resonance, transitions is <25{mu}m. Simultaneous x-ray images of the plasma from a charge-coupled device pinhole camera confirmed that the plasma x-ray emission is from a similar sized source. Survey spectra {gamma}/{Delta}{gamma}=500--1000) taken with a flat LiF (200) crystal spectrometer with a charge-coupled device detector complement the high resolution data. Two dimensional LASNEX modeling of the laser target conditions indicate that the high K-shell charge states are produced in the hot dense region of the plasma with electron temperature >2 keV and density{approximately}10{sup 22} cm{sup {minus}3}. These experiments demonstrate that with modest laser energy, plasmas heated by high-intensity 120 ps lasers provide a very bright source of hard {approximately}8 keV x-ray emission.

  6. Self-pulsing 10{sup 4} A cm{sup -2} current density discharges in dielectric barrier Al/Al{sub 2}O{sub 3} microplasma devices

    SciTech Connect

    Yarmolich, D.; Krasik, Ya. E.; Stambulchik, E.; Bernshtam, V.; Yoon, J. K.; Herrera, B.; Park, S.-J.; Eden, J. G.


    Excitation of Al/Al{sub 2}O{sub 3} microplasma devices with 50 {mu}s, 800 V pulses produces, in Ar/H{sub 2} gas mixtures at 600 Torr, {approx}6 A current pulses with a duration of {approx}30 ns. Corresponding to peak current and power densities of {approx}10{sup 4} A/cm{sup 2} and {approx}2.5 GW/cm{sup 3}, respectively, these pulses are generated in a 10 {mu}s burst in which the voltage self-pulses at a repetition frequency of {approx}3 MHz. Analysis of the H{sub {alpha}}, H{sub {beta}}, and Ar II emission line profiles yields a plasma density of {approx}10{sup 17} cm{sup -3}, and the emission of O IV ions suggests the presence of energetic electrons. Images of the microplasma indicate that the plasma is initiated by surface flashover and extends {approx}200 {mu}m outside the microcavity.

  7. Logrithmic current simulator generates electrical currents accurately between 10 to the minus 11 ampere to 10 to the minus 3 ampere

    NASA Technical Reports Server (NTRS)

    Wilson, J.


    Current generator accurately simulates electric currents in the range of 10 to the minus 11th power to 0.001 ampere. Compensation networks have been devised to improve the accuracy at the lower current levels.

  8. Parallel processing: The Cm/sup */ experience

    SciTech Connect

    Siewiorek, D.; Gehringer, E.; Segall, Z.


    This book describes the parallel-processing research with CM/sup */ at Carnegie-Mellon University. Cm/sup */ is a tightly coupled 50-processor multiprocessing system that has been in operation since 1977. Two complete operating systems-StarOS and Medusa-are part of its development along with a number of applications.

  9. PROCESS OF PRODUCING Cm$sup 244$ AND Cm$sup 24$$sup 5$


    Manning, W.M.; Studier, M.H.; Diamond, H.; Fields, P.R.


    A process is presented for producing Cm and Cm/sup 245/. The first step of the process consists in subjecting Pu/sup 2339/ to a high neutron flux and subsequently dissolving the irradiated material in HCl. The plutonium is then oxidized to at least the tetravalent state and the solution is contacted with an anion exchange resin, causing the plutonium values to be absorbed while the fission products and transplutonium elements remain in the effluent solution. The effluent solution is then contacted with a cation exchange resin causing the transplutonium, values to be absorbed while the fission products remain in solution. The cation exchange resin is then contacted with an aqueous citrate solution and tbe transplutonium elements are thereby differentially eluted in order of decreasing atomic weight, allowing collection of the desired fractions.

  10. Primordial black holes with mass 10{sup 16}−10{sup 17} g and reionization of the Universe

    SciTech Connect

    Belotsky, K.M.; Kirillov, A.A. E-mail:


    Primordial black holes (PBHs) with mass 10{sup 16}−10{sup 17} g almost escape constraints from observations so could essentially contribute to dark matter density. Hawking evaporation of such PBHs produces with a steady rate γ- and e{sup ±}-radiations in MeV energy range, which can be absorbed by ordinary matter. Simplified estimates show that a small fraction of evaporated energy had to be absorbed by baryonic matter what can turn out to be enough to heat the matter so it is fully ionized at the redshift z∼ 5... 10. The result is found to be close to a borderline case where the effect appears, what makes it sensitive to the approximation used. In our approximation, degree of gas ionization reaches 50-100% by z∼ 5 for PBH mass (3...7)× 10{sup 16} g with their abundance corresponding to the upper limit.

  11. Cosmic rays: the spectrum and chemical composition from 10{sup 10} to 10{sup 20} eV

    SciTech Connect

    Peixoto, C.J. Todero; De Souza, Vitor; Biermann, Peter L. E-mail:


    The production of energetic particles in the universe remains one of the great mysteries of modern science. The mechanisms of acceleration in astrophysical sources and the details about the propagation through the galactic and extragalactic media are still to be defined. In recent years, the cosmic ray flux has been measured with high precision in the energy range from 10{sup 10} to 10{sup 20.5} eV by several experiments using different techniques. In some energy ranges, it has been possible to determine the flux of individual elements (hydrogen to iron nuclei). This paper explores an astrophysical scenario in which only our Galaxy and the radio galaxy Cen A produce all particles measured on Earth in the energy range from 10{sup 10} to 10{sup 20.5} eV . Data from AMS-02, CREAM, KASCADE, KASCADE-Grande and the Pierre Auger Observatories are considered. The model developed here is compared to the total and if available to the individual particle flux of the experiments considered.The flux of each element as determined by AMS-02, CREAM, KASCADE and KASCADE-Grande and the mass sensitivity parameter X{sub max} measured by the Pierre Auger Observatory above 10 eV are also explored within the framework of the model. The transition from 10{sup 16} to 10{sup 18} eV is carefully analyzed. It is shown that the flux measured in this energy range suggest the existence of an extra component of cosmic rays yet to be understood.


    SciTech Connect

    Cheng, K.-S.; Chernyshov, D. O.; Dogiel, V. A.; Ko, C.-M.; Wang, Y.; Ip, W.-H.


    The Fermi Large Area Telescope has recently discovered two giant gamma-ray bubbles that extend north and south of the Galactic center with diameters and heights of the order of H {approx} 10 kpc. We suggest that the periodic star capture processes by the Galactic supermassive black hole Sgr A*, with a capture rate of {tau}{sup -1}{sub cap} {approx} 3 Multiplication-Sign 10{sup -5} yr{sup -1} and an energy release of W {approx} 3 Multiplication-Sign 10{sup 52} erg per capture, can result in hot plasma injecting into the Galactic halo at a wind velocity of u {approx} 10{sup 8} cm s{sup -1}. The periodic injection of hot plasma can produce a series of shocks. Energetic protons in the bubble are re-accelerated when they interact with these shocks. We show that for energy larger than E > 10{sup 15} eV, the acceleration process can be better described by the stochastic second-order Fermi acceleration. We propose that hadronic cosmic rays (CRs) within the 'knee' of the observed CR spectrum are produced by Galactic supernova remnants distributed in the Galactic disk. Re-acceleration of these particles in the Fermi Bubble produces CRs beyond the knee. With a mean CR diffusion coefficient in this energy range in the bubble D{sub B} {approx} 3 Multiplication-Sign 10{sup 30} cm{sup 2} s{sup -1}, we can reproduce the spectral index of the spectrum beyond the knee and within it. The conversion efficiency from shock energy of the bubble into CR energy is about 10%. This model provides a natural explanation of the observed CR flux, spectral indices, and matching of spectra at the knee.

  13. Simulation and design of various configurations of silicon detectors for high irradiation tolerance up to 6x10{sup 14} n/cm{sup 2} in LHC application

    SciTech Connect

    Li, Z.; Chen, W.; Beuttenmuller, R.


    Various new configurations (n{sup +}/p/p{sup +}, n{sup +}/n/p{sup +}, and p{sup +}/n/n{sup +}) of silicon detector designs have been simulated using processing and device simulation tools, before and after irradiation to various fluences. The aim of material selection and detector design is to ensure adequate charge collection after being irradiated up to 10{sup 15} n/cm{sup 2} (or 6x10{sup 14}{pi}/cm{sup 2}) in LHC environment, which corresponds to a net increase (with long term anneal) of space charge of 7x10{sup 13} cm{sup -3}. Starting materials selected for simulations include high resistivity p-type silicon, medium and low resistivity n-type silicon. Design of multi-guard-rings structure for high voltage operation is also considered. First irradiation data of low resistivity silicon detector is presented.

  14. Improving the Bevatron vacuum to 10/sup -10/ torr

    SciTech Connect

    Avery, R.; Elioff, T.; Grunder, H.


    Pressure of approx. 10/sup -10/ torr is needed in the Bevatron to accelerate partially-stripped very-heavy ions (e.g. U/sup 69 +/) in the Bevatron without significant loss due to interactions with the residual gas. This ultra-high vacuum will be achieved by installing (summer and fall 1981) a cryogenic liner, mostly 12/sup 0/K, surrounding the Bevatron circulating beam. The novel construction features are presented along with results from successful tests of prototype sections. This is believed to be the largest application of cryogenic pumping to particle accelerators yet undertaken.

  15. The All-Particle Spectrum of Primary Cosmic Rays in the Wide Energy Range from 10{sup 14} to 10{sup 17} eV Observed with the Tibet-III Air-Shower Array

    SciTech Connect

    Amenomori, M.; Bi, X. J.; Ding, L. K.; Feng, Zhaoyang; He, H. H.; Hu, H. B.; Chen, D.; Cui, S. W.; Danzengluobu; Ding, X. H.; Guo, H. W.; Hu, Haibing; Fan, C.; Feng, C. F.; He, M.; Feng, Z. Y.; Gao, X. Y.; Geng, Q. X.; Hibino, K.; Hotta, N.


    We present an updated all-particle energy spectrum of primary cosmic rays in a wide range from 10{sup 14} to 10{sup 17} eV using 5.5 x 10{sup 7} events collected from 2000 November through 2004 October by the Tibet-III air-shower array located 4300 m above sea level (an atmospheric depth of 606 g cm{sup -2}). The size spectrum exhibits a sharp knee at a corresponding primary energy around 4 PeV. This work uses increased statistics and new simulation calculations for the analysis. We discuss our extensive Monte Carlo calculations and the model dependencies involved in the final result, assuming interaction models QGSJET01c and SIBYLL2.1, and heavy dominant (HD) and proton dominant (PD) primary composition models. Pure proton and pure iron primary models are also examined as extreme cases. A detector simulation was also performed to improve our accuracy in determining the size of the air showers and the energy of the primary particle. We confirmed that the all-particle energy spectra obtained under various plausible model parameters are not significantly different from each other, which was the expected result given the characteristics of the experiment at high altitude, where the air showers of the primary energy around the knee reach near-maximum development, with their features dominated by electromagnetic components, leading to a weak dependence on the interaction model or the primary mass. This is the highest statistical and the best systematics-controlled measurement covering the widest energy range around the knee energy region.

  16. Acceptances for space-based and ground-based fluorescence detectors, and inference of the neutrino-nucleon cross-section above 10{sup 19} eV

    SciTech Connect

    Palomares-Ruiz, Sergio; Irimia, Andrei; Weiler, Thomas J.


    Detection of ultrahigh energy neutrinos will be useful for unraveling the dynamics of the most violent sources in the cosmos and for revealing the neutrino cross-section at extreme energy. If there exists a Greisen-Zatsepin-Kuz'min (GZK) suppression of cosmic-ray events above E{sub GZK}{approx}5x10{sup 19} eV, as predicted by theory, then the only messengers of energies beyond E{sub GZK} are neutrinos. Cosmic neutrino fluxes can initiate air-showers through interaction in the atmosphere, or in the Earth. Neutrino trajectories will be downgoing to nearly horizontal in the former case, and 'Earth-skimming' in the latter case. Thus it is important to know the acceptances (event rate/flux) of proposed air-shower experiments for detecting both types of neutrino-initiated events. We calculate these acceptances for fluorescence detectors, both space-based as with the EUSO and OWL proposals, and ground-based, as with Auger, HiRes and Telescope Array. The neutrino cross-section {sigma}{sub {nu}}{sub N}{sup CC} is unknown at energies above 5.2x10{sup 13} eV. Although the popular QCD extrapolation of lower-energy physics offers the cross-section value of 0.54x10{sup -31}(E{sub {nu}}/10{sup 20} eV){sup 0.36} cm{sup 2}, new physics could raise or lower this value. Therefore, we present the acceptances of horizontal (HAS) and upgoing (UAS) air-showers as a function of {sigma}{sub {nu}}{sub N}{sup CC} over the range 10{sup -34} to 10{sup -30} cm{sup 2}. The dependences of acceptances on neutrino energy, shower-threshold energy, shower length, and shower column density are also studied. We introduce a cloud layer, and study its effect on rates as viewed from space and from the ground. For UAS, we present acceptances for events over land (rock), and over the ocean (water). Acceptances over water are larger by about an order of magnitude, thus favoring space-based detectors. We revisit the idea of Kusenko and Weiler [Phys. Rev. Lett. 88, 161101 (2002)] to infer {sigma}{sub {nu

  17. CO/H{sub 2} abundance ratio ≈ 10{sup –4} in a protoplanetary disk

    SciTech Connect

    France, Kevin; McJunkin, Matthew; Herczeg, Gregory J.; Penton, Steven V.


    The relative abundances of atomic and molecular species in planet-forming disks around young stars provide important constraints on photochemical disk models and provide a baseline for calculating disk masses from measurements of trace species. A knowledge of absolute abundances, those relative to molecular hydrogen (H{sub 2}), are challenging because of the weak rovibrational transition ladder of H{sub 2} and the inability to spatially resolve different emission components within the circumstellar environment. To address both of these issues, we present new contemporaneous measurements of CO and H{sub 2} absorption through the 'warm molecular layer' of the protoplanetary disk around the Classical T Tauri Star RW Aurigae A. We use a newly commissioned observing mode of the Hubble Space Telescope Cosmic Origins Spectrograph to detect warm H{sub 2} absorption in this region for the first time. An analysis of the emission and absorption spectrum of RW Aur shows components from the accretion region near the stellar photosphere, the molecular disk, and several outflow components. The warm H{sub 2} and CO absorption lines are consistent with a disk origin. We model the 1092-1117 Å spectrum of RW Aur to derive log{sub 10} N(H{sub 2}) = 19.90{sub −0.22}{sup +0.33} cm{sup –2} at T {sub rot}(H{sub 2}) = 440 ± 39 K. The CO A - X bands observed from 1410 to 1520 Å are best fit by log{sub 10} N(CO) = 16.1 {sub −0.5}{sup +0.3} cm{sup –2} at T {sub rot}(CO) = 200{sub −125}{sup +650} K. Combining direct measurements of the H I, H{sub 2}, and CO column densities, we find a molecular fraction in the warm disk surface of f {sub H2} ≥ 0.47 and derive a molecular abundance ratio of CO/H{sub 2} = 1.6{sub −1.3}{sup +4.7} × 10{sup –4}, both consistent with canonical interstellar dense cloud values.

  18. Subpicosecond KrF{asterisk}-laser plasma interaction at intensities between 10{sup 14} and 10{sup 17} W/cm{sup 2}

    SciTech Connect

    Teubner, U.; Gibbon, P.; Foerster, E.; Fallies, F.; Audebert, P.; Geindre, J.P.; Gauthier, J.C.


    The interaction of high-intensity subpicosecond KrF{asterisk}-laser pulses with aluminium plasmas is investigated at intensities between 10{sup 14} and 10{sup 17} W/cm{sup 2}. Using a one-dimensional hydrocode, the laser energy absorption and time evolution of plasma parameters have been studied as a function of laser intensity, incidence angle, and polarization. Complementary particle-in-cell simulations have also been performed to check the collisionless absorption component carried by hot electrons and ions. These simulations are compared to previous experiments on laser pulse absorption and x-ray generation. {copyright} {ital 1996 American Institute of Physics.}


    SciTech Connect

    Narayanan, Anand; Wakker, Bart P.; Savage, Blair D.; Keeney, Brian A.; Shull, J. Michael; Stocke, John T.; Sembach, Kenneth R. E-mail: wakker@astro.wisc.ed


    We present a clear detection of a broad Ly{alpha} absorber (BLA) with a matching O VI line in the nearby universe. The BLA is detected at z(Ly{alpha})=0.01028 in the high signal-to-noise ratio spectrum of Mrk 290 obtained using the Cosmic Origins Spectrograph. The Ly{alpha} absorption has two components, with b(H i) = 55{+-}1 km s{sup -1} and b(H i) = 33{+-}1 km s{sup -1}, separated in velocity by v {approx} 115 km s{sup -1}. The O VI, detected by the Far-Ultraviolet Spectroscopic Explorer at z(O vi) = 0.01027, has a b(O vi) = 29{+-}3 km s{sup -1} and is kinematically well aligned with the broader H I component. The non-detection of other ions such as C II, Si II, Fe II, C III, Si III, C IV, Si IV, and N V at the same velocity as the BLA and the O VI implies that the absorber is tracing highly ionized gas. The different line widths of the BLA and O VI suggest a temperature of T = 1.4 x 10{sup 5} K in the absorber. Photoionization, collisional ionization equilibrium as well as non-equilibrium collisional ionization models do not explain the ion ratios at this temperature. The observed line strength ratios and line widths favor an ionization scenario in which both ion-electron collisions and UV photons contribute to the ionization in the gas. Such a model requires a low metallicity of {approx}-1.7 dex, ionization parameter of log U {approx} -1.4, a large total hydrogen column density of N(H) {approx} 4 x 10{sup 19} cm{sup -2}, and a path length of {approx}400 kpc. The line of sight to Mrk 290 intercepts at the redshift of the absorber, a megaparsec scale filamentary structure extending over {approx}20{sup 0} in the sky, with several luminous galaxies distributed within {approx}1.5 h {sup -1} Mpc projected distance from the absorber. The collisionally ionized gas phase of this absorber is most likely tracing a shock-heated gaseous structure, consistent with a few different scenarios for the origin including an overdense region of the warm-hot intergalactic medium in

  20. Production and measurement of flash x-ray dose rates in excess of 10 sup 13 rad (CaF sub 2 )/s

    SciTech Connect

    Sanford, T.W.L.; McAtee, W.H.; Halbleib, J.A.; Beutler, D.E. ); Mock, R.C. ); Knott, D.P. )


    The radiation field from an intense reusable source of flash x-rays that delivers a measured peak dose and dose rate of 370 {plus minus} 60 krad (CaF{sub 2}) and (3.5 {plus minus} 0.7) {times} 10{sup 13} rad (CaF{sub 2})/s over a useful area of 80 cm{sup 2} is characterized. CaF{sub 2}:Mn TLDs (thermo-luminescent dosimeters), which are used to measure the dose field, are shown to be dose-rate independent within {plus minus}15% up to this level. Energy deposition in the CaF{sub 2} TLD chip was analyzed according to the origin of the electrons responsible for that deposition with a new computational tool. 22 refs.

  1. Production and measurement of flash x-ray dose rates in excess of 10{sup 13} rad (CaF{sub 2})/s

    SciTech Connect

    Sanford, T.W.L.; McAtee, W.H.; Halbleib, J.A.; Beutler, D.E.; Mock, R.C.; Knott, D.P.


    The radiation field from an intense reusable source of flash x-rays that delivers a measured peak dose and dose rate of 370 {plus_minus} 60 krad (CaF{sub 2}) and (3.5 {plus_minus} 0.7) {times} 10{sup 13} rad (CaF{sub 2})/s over a useful area of 80 cm{sup 2} is characterized. CaF{sub 2}:Mn TLDs (thermo-luminescent dosimeters), which are used to measure the dose field, are shown to be dose-rate independent within {plus_minus}15% up to this level. Energy deposition in the CaF{sub 2} TLD chip was analyzed according to the origin of the electrons responsible for that deposition with a new computational tool. 22 refs.

  2. Production and measurement of flash x-ray dose rates in excess of 10 sup 13 rad (CaF sub 2 )/s

    SciTech Connect

    Sanford, T.W.L.; Halbleib, J.A.; Beutler, D.E.; McAtee, W.H.; Mock, R.C.; Knott, D.P. )


    In this paper the radiation field from an intense reusable source of flash x-rays that delivers a measured peak dose and dose rate of 370 {plus minus}60 krad (CaF{sub 2}) and (3.5 {plus minus}0.7) {times} 10{sup 13} rad (CaF{sub 2})/s over a useful area of 80 cm{sup 2} is characterized. CaF{sub 2}:Mn TLDs (thermoluminescent dosimeters), which are used to measure the dose field, are shown to be dose-rate independent within {plus minus}15% up to this level. Energy deposition in the CaF{sub 2} TLD chip was analyzed according to the origin of the electrons responsible for that deposition with a new computational tool.

  3. An optical beam frequency reference with 10{sup -14} range frequency instability

    SciTech Connect

    McFerran, J. J.; Hartnett, J. G.; Luiten, A. N.


    The authors report on a thermal beam optical frequency reference with a fractional frequency instability of 9.2x10{sup -14} at 1 s reducing to 2.0x10{sup -14} at 64 s before slowly rising. The {sup 1}S{sub 0}{r_reversible}{sup 3}P{sub 1} intercombination line in neutral {sup 40}Ca is used as a frequency discriminator. A diode laser at 423 nm probes the ground state population after a Ramsey-Borde sequence of 657 nm light-field interactions on the atoms. The measured fractional frequency instability is an order of magnitude improvement on previously reported thermal beam optical clocks. The photon shot-noise of the read-out produces a limiting square root {lambda}-variance of 7x10{sup -14}/{radical}({tau})

  4. Single-qubit-gate error below 10{sup -4} in a trapped ion

    SciTech Connect

    Brown, K. R.; Wilson, A. C.; Colombe, Y.; Ospelkaus, C.; Meier, A. M.; Knill, E.; Leibfried, D.; Wineland, D. J.


    With a {sup 9}Be{sup +} trapped-ion hyperfine-state qubit, we demonstrate an error probability per randomized single-qubit gate of 2.0(2)x10{sup -5}, below the threshold estimate of 10{sup -4} commonly considered sufficient for fault-tolerant quantum computing. The {sup 9}Be{sup +} ion is trapped above a microfabricated surface-electrode ion trap and is manipulated with microwaves applied to a trap electrode. The achievement of low single-qubit-gate errors is an essential step toward the construction of a scalable quantum computer.

  5. Mg dopant in Cu{sub 2}SnSe{sub 3}: An n-type former and a promoter of electrical mobility up to 387 cm{sup 2} V{sup −1} s{sup −1}

    SciTech Connect

    Kuo, Dong-Hau Wubet, Walelign


    Mg-doped Cu{sub 2}SnSe{sub 3} bulk materials with the (Cu{sub 2−x}Mg{sub x})SnSe{sub 3} (Mg-x-CTSe) formula at x=0, 0.05, 0.1, 0.15, and 0.2 were prepared at 550 °C for 2 h with soluble sintering aids of Sb{sub 2}S{sub 3} and Te. Defect chemistry was studied by measuring structural and electrical properties of Mg-doped Cu{sub 2}SnSe{sub 3} as a function of dopant concentration. Mg-x-CTSe pellets show p-type at x=0, 0.05 and 0.1 and n-type at x=0.15 and 0.2. The low hole concentration of 3.2×10{sup 17} cm{sup −3} and high mobility of 387 cm{sup 2} V{sup −1} s{sup −1} were obtained for (Cu{sub 2−x}Mg{sub x})SnSe{sub 3} bulks at x=0.1 (5% Mg) as compared to 2.2×10{sup 18} cm{sup −3} and 91 cm{sup 2} V{sup −1} s{sup −1} for the undoped one. The explanation based upon the Mg-to-Cu antisite donor defect for the changes in electrical property was declared. A high Mg content for Mg-x-CTSe at x≥0.1 can lead to the formation of second phases. The study in bulk Mg-x-CTSe has been based upon defect states and is consistent and supported by the data of structural and electrical properties. - Graphical abstract: The effects of extrinsic doping of Mg{sup 2+} on the electrical properties of Cu{sub 2}SnSe{sub 3} bulks. - Highlights: • p-Type Mg-CTSe with n{sub p} of 3.2×10{sup 17} cm{sup −3} and μ{sub p} of 387 cm{sup 2} V{sup −1} s{sup −1} was obtained. • This p-type occurred for 5%Mg-doped CTSe with the (Cu{sub 1.9}Mg{sub 0.1})SnSe{sub 3} formula. • Mg dopant acts as a donor to lower n{sub p} and an accelerator to increase mobility. • High Mg content leads to the p-to-n transitions. • Defect was explored by measuring electrical property and lattice parameter.


    SciTech Connect

    Jennings, Donald E.; Anderson, C. M.; Samuelson, R. E.; Flasar, F. M.; Nixon, C. A.; Bjoraker, G. L.; Romani, P. N.; Achterberg, R. K.; Cottini, V.; Hesman, B. E.; Kunde, V. G.; Carlson, R. C.; De Kok, R.; Coustenis, A.; Vinatier, S.; Bampasidis, G.; Teanby, N. A.; Calcutt, S. B.


    An emission feature at 220 cm{sup -1} which has been attributed to a cloud of condensed material in Titan's winter stratosphere has been seen for the first time in the south. This feature had previously been found only at high northern latitudes during northern winter and spring. The material emitting at 220 cm{sup -1}, as yet unidentified, may be volatiles associated with nitrile gases that accumulate in the absence of ultraviolet sunlight. Not detected as recently as 2012 February, the 220 cm{sup -1} feature clearly appeared at the south pole in Cassini spectra recorded on 2012 July 24, indicating a rapid onset of the emission. This is the first indication of the winter buildup of condensation in the southern stratosphere that has been expected as the south pole moves deeper into shadow. In the north the 220 cm{sup -1} feature continued to decrease in intensity with a half-life of 3 years.

  7. {sup 87}Sr Lattice Clock with Inaccuracy below 10{sup -15}

    SciTech Connect

    Boyd, Martin M.; Ludlow, Andrew D.; Blatt, Sebastian; Foreman, Seth M.; Ido, Tetsuya; Zelevinsky, Tanya; Ye Jun


    Aided by ultrahigh resolution spectroscopy, the overall systematic uncertainty of the {sup 1}S{sub 0}-{sup 3}P{sub 0} clock resonance for lattice-confined {sup 87}Sr has been characterized to 9x10{sup -16}. This uncertainty is at a level similar to the Cs-fountain primary standard, while the potential stability for the lattice clocks exceeds that of Cs. The absolute frequency of the clock transition has been measured to be 429 228 004 229 874.0(1.1) Hz, where the 2.5x10{sup -15} fractional uncertainty represents the most accurate measurement of a neutral-atom-based optical transition frequency to date.

  8. Lattice-Induced Frequency Shifts in Sr Optical Lattice Clocks at the 10{sup -17} Level

    SciTech Connect

    Westergaard, P. G.; Lodewyck, J.; Lecallier, A.; Millo, J.; Lemonde, P.; Lorini, L.; Burt, E. A.; Zawada, M.


    We present a comprehensive study of the frequency shifts associated with the lattice potential in a Sr lattice clock by comparing two such clocks with a frequency stability reaching 5x10{sup -17} after a 1 h integration time. We put the first experimental upper bound on the multipolar M1 and E2 interactions, significantly smaller than the recently predicted theoretical upper limit, and give a 30-fold improved upper limit on the effect of hyperpolarizability. Finally, we report on the first observation of the vector and tensor shifts in a Sr lattice clock. Combining these measurements, we show that all known lattice related perturbations will not affect the clock accuracy down to the 10{sup -17} level, even for lattices as deep as 150 recoil energies.

  9. Communication: Global minimum search of Ag{sub 10}{sup +} with molecular beam optical spectroscopy

    SciTech Connect

    Shayeghi, A. Schäfer, R.; Johnston, R. L.


    The present study is focused on the optical properties of the Ag{sub 10}{sup +} cluster in the photon energy range ℏω = 1.9–4.4 eV. Absorption spectra are recorded by longitudinal molecular beam depletion spectroscopy and compared to optical response calculations using time-dependent density functional theory. Several cluster isomers obtained by the new pool-based parallel implementation of the Birmingham Cluster Genetic Algorithm, coupled with density functional theory, are used in excited state calculations. The experimental observations, together with additional simulations of ion mobilities for the several geometries found within this work using different models, clearly identify the ground state isomer of Ag{sub 10}{sup +} to be composed of two orthogonal interpenetrating pentagonal bipyramids, having overall D{sub 2d} symmetry.

  10. Breeding 10{sup 10}/s Radioactive Nuclei in a Compact Plasma Focus Device

    SciTech Connect

    Brzosko, JANS.


    In the early 90's, it was discovered that a Plasma Focus (PF) system self-creates a plasma-tarp in which high energy-threshold nuclear-reactions occur at high reaction rates. Short life radioisotopes (SLR)s such as {sup 18}F, {sup 17}F, {sup 15}O, {sup 14}O, {sup 13}N have been generated (10{sup 6} - 10{sup 8} per pulse) with a PF-machine using 7 kJ energy storage to produce the plasmas. {beta}{sup -} radioactivity from the SLRs is measured with rugged, Geiger counters inserted into the PF-chamber, and a specific SLR is identified by its half-life. The PF chamber (before discharge) is filled with a mixture of gases that constitutes the latter plasma-target--beam system, e.g., the elements required to produce specific SLRs through nuclear reactions. In this paper, arguments are presented showing that a modest sized PF-machine, using a 50-75 kJ fast capacitor-bank, when operated at pulse frequencies of 1-10 Hz can produce {ge} 10{sup 9} SLRs/pulse. This paper reports the result s of testing a PF as a breeder of SLRs with dual applications for: (1) Secondary Radioactive Nuclear Beams ion-sources (Z < 35), and (2) as a breeder of radioisotopes for biomedicine (Z {le} 10) and/or PET imaging.

  11. Measurement of the magnetic moment of the 10{sup +} isomer in {sup 132}Ba

    SciTech Connect

    Harissopulos, S.; Gelberg, A.; Dewald, A.; Hass, M.; Weissman, L.; Broude, C.


    The magnetic moment of the 10{sup +} isomeric state of {sup 132}Ba at 3115 keV was measured as {ital g}={minus}0.156(11). A 60 MeV {sup 12}C beam from the Koffler Pelletron accelerator at the Weizmann Institute was used in the reaction {sup 124}Sn({sup 12}C,4{ital n}){sup 132}Ba. The measured {ital g} factor confirms the ({nu}{ital h}{sub 11/2}){sup {minus}2} configuration of the level. The result is compared with other {ital g} factors in neighboring {ital N}=76 isotones.

  12. The measurement of elemental abundances above 10 sup 15 eV at a lunar base

    SciTech Connect

    Swordy, S.P. )


    At {approx}10{sup 15} eV the slope of the energy spectrum of cosmic rays becomes significantly steeper than at lower energies. The measurement of relative elemental abundances at these energies is expected to provide a means to resolve the origin of this feature and greatly contribute to the understanding of the sources of cosmic rays. We describe a moon based detector for making well resolved elemental measurements at these energies using hadronic calorimetry. This detector is particularly well suited for a site on the lunar surface because there is no overlying layer of atmosphere and the large mass required can be provided by the lunar regolith.

  13. A large-scale magnetic shield with 10{sup 6} damping at millihertz frequencies

    SciTech Connect

    Altarev, I.; Bales, M.; Fierlinger, K.; Fierlinger, P.; Kuchler, F.; Marino, M. G.; Niessen, B.; Petzoldt, G.; Singh, J. T.; Stoepler, R.; Stuiber, S.; Sturm, M.; Taubenheim, B.; Beck, D. H.; Chupp, T.; Lins, T.; Schläpfer, U.; Schnabel, A.; Voigt, J.


    We present a magnetically shielded environment with a damping factor larger than 1 × 10{sup 6} at the mHz frequency regime and an extremely low field and gradient over an extended volume. This extraordinary shielding performance represents an improvement of the state-of-the-art in the difficult regime of damping very low-frequency distortions by more than an order of magnitude. This technology enables a new generation of high-precision measurements in fundamental physics and metrology, including searches for new physics far beyond the reach of accelerator-based experiments. We discuss the technical realization of the shield with its improvements in design.

  14. Actively mode-locked diode laser with a mode spacing stability of ∼6 × 10{sup -14}

    SciTech Connect

    Zakharyash, V F; Kashirsky, A V; Klementyev, V M


    We have studied mode spacing stability in an actively mode-locked external-cavity semiconductor laser. It has been shown that, in the case of mode spacing pulling to the frequency of a highly stable external microwave signal produced by a hydrogen standard (stability of 4 × 10{sup -14} over an averaging period τ = 10 s), this configuration ensures a mode spacing stability of 5.92 × 10{sup -14} (τ = 10 s). (control of radiation parameters)

  15. In-situ studies of cascade defect formation at T < 10/sup 0/K

    SciTech Connect

    Haga, K.; Baily, A.C.; King, W.E.; Merkle, K.L.; Meshii, M.


    Thin films of Ag and Au were ion-irradiated at temperature (T) < 10/sup 0/K and simultaneously observed using the Argonne National Laboratory high-voltage electron microscope (HVEM) ion-beam interface system. Displacement cascades were produced by Kr/sup +/ ion bombardment in the energy range 20 to 140 keV. For Ag, 20% of the 20-keV cascades and 100% of the 100-keV cascades produced observable contrast. Analysis of the observed dynamical black-white (BW)-contrast indicates that the clusters are of vacancy type. Subcascades were observed in the high-energy irradiations. The present results demonstrate that, during the evolution of displacement cascades in Ag and Au, extensive athermal rearrangement of vacancies occurs which gives rise to clustering and collapse to dislocation loops.

  16. Raman and infrared studies of the Sharp 890 cm{sup -1} mode in organic superconductors.

    SciTech Connect

    Eldridge, J. E.; Lin, Y.; Schlueter, J. A.; Wang, H. H.; Kini, A. M.


    Raman and infrared spectra of several organic superconductors are presented, showing some unusual behaviors of a sharp line at 890 cm{sup {minus}} in both spectra. These include a frequency shift below T{sub c}, a positive deuterium isotope shift, frequency softening at low temperatures and sensitivity to lattice superstructure. It is proposed that either the ion or the neutral molecule has a distortion with a strong v{sub 60}(B{sub 3g}) mode component.

  17. Permanent Prostate Brachytherapy in Prostate Glands <20 cm{sup 3}

    SciTech Connect

    Mayadev, Jyoti; Merrick, Gregory S.; Reed, Joshua R.; Butler, Wayne M.; Galbreath, Robert W.; Allen, Zachariah A.; Wallner, Kent E.


    Purpose: To investigate the dosimetry, treatment-related morbidity, and biochemical outcomes for brachytherapy in patients with prostate glands <20 cm{sup 3}. Methods and Materials: From November 1996 to October 2006, 104 patients with prostate glands <20 cm{sup 3} underwent brachytherapy. Multiple prostate, urethral, and rectal dosimetric parameters were evaluated. Treatment-related urinary and rectal morbidity were assessed from patient questionnaires. Cause-specific survival, biochemical progression-free survival, and overall survival were recorded. Results: The median patient age, follow up, and pre-treatment ultrasound volume was 64 years, 5.0 years and 17.6cm{sup 3}, respectively. Median day 0 dosimetry was significant for the following: V100 98.5%, D90 126.1% and R100 <0.5% of prescription dose. The mean urethral and maximum urethral doses were 119.6% and 133.8% of prescription. The median time to International Prostate Symptom Score resolution was 4 months. There were no RTOG grade III or IV rectal complications. The cause-specific survival, biochemical progression-free survival, and overall survival rates were 100%, 92.5%, and 77.8% at 9 years. For biochemically disease-free patients, the median most recent postbrachytherapy PSA value was 0.02 ng/mL. Conclusion: Our results demonstrate that brachytherapy for small prostate glands is highly effective, with an acceptable morbidity profile, excellent postimplant dosimetry, acceptable treatment-related morbidity, and favorable biochemical outcomes.

  18. Search for discrete gamma-ray sources emitting at energies greater than 10/sup 15/ eV

    SciTech Connect

    Samorski, M.; Stamm, W.


    The data of the extensive air shower experiment at Kiel have been scanned systematically for possible discrete ..gamma..-ray sources in the energy range E>10/sup 15/ eV and in the declination band delta = 25/sup 0/-75/sup 0/. Photon fluxes for celestial positions with the statistically most significant excesses of showers and 3 sigma upper limit photon fluxes for COS B ..gamma..-ray sources visible to the extensive air shower experiment at Kiel are presented.

  19. Searching for a correlation between cosmic-ray sources above 10{sup 19} eV and large scale structure

    SciTech Connect

    Kashti, Tamar; Waxman, Eli E-mail:


    We study the anisotropy signature which is expected if the sources of ultrahigh energy, >10{sup 19} eV, cosmic rays (UHECRs) are extra-galactic and trace the large scale distribution of luminous matter. Using the PSCz galaxy catalog as a tracer of the large scale structure (LSS), we derive the expected all sky angular distribution of the UHECR intensity. We define a statistic that measures the correlation between the predicted and observed UHECR arrival direction distributions, and show that it is more sensitive to the expected anisotropy signature than the power spectrum and the two-point correlation function. The distribution of the correlation statistic is not sensitive to the unknown redshift evolution of UHECR source density and to the unknown strength and structure of inter-galactic magnetic fields. We show, using this statistic, that recently published >5.7 Multiplication-Sign 10{sup 19} eV Auger data are inconsistent with isotropy at Asymptotically-Equal-To 98% CL, and consistent with a source distribution that traces LSS, with some preference for a source distribution that is biased with respect to the galaxy distribution. The anisotropy signature should be detectable also at lower energy, >4 Multiplication-Sign 10{sup 19} eV. A few-fold increase of the Auger exposure is likely to increase the significance to >99% CL, but not to>99.9% CL (unless the UHECR source density is comparable to or larger than that of galaxies). In order to distinguish between different bias models, the systematic uncertainty in the absolute energy calibration of the experiments should be reduced to well below the current Asymptotically-Equal-To 25%.

  20. Investigation of the role of 10sup>Li resonances in the halo structure of 11Li through the 11Li(p,d)10sup>Li transfer reaction

    SciTech Connect

    Sanetullaev, A.; Kanungo, R.; Tanaka, J.; Alcorta, M.; Andreoiu, C.; Bender, P.; Chen, A. A.; Christian, G.; Davids, B.; Fallis, J.; Fortin, J. P.; Galinski, N.; Gallant, A. T.; Garrett, P. E.; Hackman, G.; Hadinia, B.; Ishimoto, S.; Keefe, M.; Krucken, R.; Lighthall, J.; McNeice, E.; Miller, D.; Purcell, J.; Randhawa, J. S.; Roger, T.; Savajols, H.; Tanihata, I.; Thompson, I. J.; Unsworth, C.; Voss, P.; Wang, Z.


    Here, the first measurement of the one-neutron transfer reaction 11Li(p,d)10sup>Li performed using the IRIS facility at TRIUMF with a 5.7A MeV11Li beam interacting with a solid H2 target is reported. The 10sup>Li residue was populated strongly as a resonance peak with energy Er = 0.62 ± 0.04 MeV having a total width Γ = 0.33 ± 0.07 MeV. The angular distribution of this resonance is characterized by neutron occupying the 1p1/2 orbital. A DWBA analysis yields a spectroscopic factor of 0.67 ± 0.12 for p1/2 removal strength from the ground state of 11Li to the region of the peak.

  1. {sup 39}Ar Detection at the 10{sup -16} Isotopic Abundance Level with Atom Trap Trace Analysis

    SciTech Connect

    Jiang, W.; Williams, W.; Bailey, K.; O'Connor, T. P.; Mueller, P.; Davis, A. M.; Hu, S.-M.; Sun, Y. R.; Lu, Z.-T.; Purtschert, R.; Sturchio, N. C.


    Atom trap trace analysis, a laser-based atom counting method, has been applied to analyze atmospheric {sup 39}Ar (half-life=269 yr), a cosmogenic isotope with an isotopic abundance of 8x10{sup -16}. In addition to the superior selectivity demonstrated in this work, the counting rate and efficiency of atom trap trace analysis have been improved by 2 orders of magnitude over prior results. The significant applications of this new analytical capability lie in radioisotope dating of ice and water samples and in the development of dark matter detectors.

  2. Reducing SS 304/316 hydrogen outgassing to 2x10{sup -15} torr l/cm{sup 2} s

    SciTech Connect

    Sasaki, Y. Tito


    Significant reduction in the outgassing rate of 300-series stainless steel is routinely attained through combination of electropolishing and vacuum baking. Preferential removal of Ni, Fe, and Mn from the surface of stainless steel by electropolishing creates a chromium-enriched surface. It also reduces the atomic surface area of the work piece closer to its geometric surface area. When the material is vacuum fired to remove interstitial hydrogen, the resultant stainless steel exhibits an outgassing rate of about 2x10{sup -15} torr l/cm{sup 2} s, as well as drastically reduced adsorption, absorption, and catalytic behaviors.

  3. Biological effectiveness on live cells of laser driven protons at dose rates exceeding 10{sup 9} Gy/s

    SciTech Connect

    Doria, D.; Kakolee, K. F.; Kar, S.; Litt, S. K.; Ahmed, H.; Lewis, C. L.; Nersisyan, G.; Prasad, R.; Zepf, M.; Borghesi, M.; Fiorini, F.; Kirby, D.; Green, S.; Jeynes, J. C. G.; Kirkby, K. J.; Merchant, M. J.; Kavanagh, J.; Prise, K. M.; Schettino, G.


    The ultrashort duration of laser-driven multi-MeV ion bursts offers the possibility of radiobiological studies at extremely high dose rates. Employing the TARANIS Terawatt laser at Queen's University, the effect of proton irradiation at MeV-range energies on live cells has been investigated at dose rates exceeding 10{sup 9} Gy/s as a single exposure. A clonogenic assay showed consistent lethal effects on V-79 live cells, which, even at these dose rates, appear to be in line with previously published results employing conventional sources. A Relative Biological Effectiveness (RBE) of 1.4{+-}0.2 at 10% survival is estimated from a comparison with a 225 kVp X-ray source.

  4. Large transverse momenta in nuclear interaction at E{sub 0} > 10{sup 16} eV detected in stratosphere

    SciTech Connect

    Managadze, A. K. Osedlo, V. I.; Roganova, T. M.; Sveshnikova, L. G.; Galkin, V. I.; Rakobolskaya, I. V.; Goncharova, L. A.; Kotelnikov, K. A.; Polukhina, N. G.


    A gamma-hadron superfamily of cosmic-rays created by a primary cosmic-ray particle with energy above 10{sup 16} eV was detected at an altitude of 30 km by a stratospheric balloon-borne emulsion chamber. Being of superhigh energy, this event is the unique example in the world statistics of practically pure nuclear interactions in the energy range unattainable for modern accelerators. The present analysis allowed one to estimate the interaction height above the chamber and transverse momenta of the secondaries produced in the interaction. The mean value of transverse momenta appears to be very large ( > 2.5 GeV/c)

  5. A 10{sup 10} solar mass flow of molecular gas in the A1835 brightest cluster galaxy

    SciTech Connect

    McNamara, B. R.; Russell, H. R.; Main, R. A.; Vantyghem, A. N.; Kirkpatrick, C. C.; Nulsen, P. E. J.; Edge, A. C.; Murray, N. W.; Hamer, S.; Combes, F.; Salome, P.; Fabian, A. C.; Baum, S. A.; O'Dea, C. P.; Bregman, J. N.; Donahue, M.; Voit, G. M.; Egami, E.; Oonk, J. B. R.; Tremblay, G.


    We report ALMA Early Science observations of the A1835 brightest cluster galaxy (BCG) in the CO (3-2) and CO (1-0) emission lines. We detect 5 × 10{sup 10} M {sub ☉} of molecular gas within 10 kpc of the BCG. Its ensemble velocity profile width of ∼130 km s{sup –1} FWHM is too narrow for the molecular clouds to be supported in the galaxy by dynamic pressure. The gas may instead be supported in a rotating, turbulent disk oriented nearly face-on. Roughly 10{sup 10} M {sub ☉} of molecular gas is projected 3-10 kpc to the northwest and to the east of the nucleus with line-of-sight velocities lying between –250 km s{sup –1} and +480 km s{sup –1} with respect to the systemic velocity. The high-velocity gas may be either inflowing or outflowing. However, the absence of high-velocity gas toward the nucleus that would be expected in a steady inflow, and its bipolar distribution on either side of the nucleus, are more naturally explained as outflow. Star formation and radiation from the active galactic nucleus (AGN) are both incapable of driving an outflow of this magnitude. The location of the high-velocity gas projected behind buoyantly rising X-ray cavities and favorable energetics suggest an outflow driven by the radio AGN. If so, the molecular outflow may be associated with a hot outflow on larger scales reported by Kirkpatrick and colleagues. The molecular gas flow rate of approximately 200 M {sub ☉} yr{sup –1} is comparable to the star formation rate of 100-180 M {sub ☉} yr{sup –1} in the central disk. How radio bubbles would lift dense molecular gas in their updrafts, how much gas will be lost to the BCG, and how much will return to fuel future star formation and AGN activity are poorly understood. Our results imply that radio-mechanical (radio-mode) feedback not only heats hot atmospheres surrounding elliptical galaxies and BCGs, but it is able to sweep higher density molecular gas away from their centers.

  6. A compact, robust, and transportable ultra-stable laser with a fractional frequency instability of 1 × 10{sup −15}

    SciTech Connect

    Chen, Qun-Feng; Nevsky, Alexander; Cardace, Marco; Schiller, Stephan; Legero, Thomas; Häfner, Sebastian; Uhde, Andre; Sterr, Uwe


    We present a compact and robust transportable ultra-stable laser system with minimum fractional frequency instability of 1 × 10{sup −15} at integration times between 1 and 10 s. The system was conceived as a prototype of a subsystem of a microwave-optical local oscillator to be used on the satellite mission Space-Time Explorer and QUantum Equivalence Principle Space Test (STE-QUEST) ( ). It was therefore designed to be compact, to sustain accelerations occurring during rocket launch, to exhibit low vibration sensitivity, and to reach a low frequency instability. Overall dimensions of the optical system are 40 cm × 20 cm × 30 cm. The acceleration sensitivities of the optical frequency in the three directions were measured to be 1.7 × 10{sup −11}/g, 8.0 × 10{sup −11}/g, and 3.9 × 10{sup −10}/g, and the absolute frequency instability was determined via a three-cornered hat measurement. Two additional cavity-stabilized lasers were used for this purpose, one of which had an instability σ{sub y} < 4 × 10{sup −16} at 1 s integration time. The design is also appropriate and useful for terrestrial applications.

  7. Scaling Time Warp-based Discrete Event Execution to 10<sup>4 Processors on Blue Gene Supercomputer

    SciTech Connect

    Perumalla, Kalyan S


    Lately, important large-scale simulation applications, such as emergency/event planning and response, are emerging that are based on discrete event models. The applications are characterized by their scale (several millions of simulated entities), their fine-grained nature of computation (microseconds per event), and their highly dynamic inter-entity event interactions. The desired scale and speed together call for highly scalable parallel discrete event simulation (PDES) engines. However, few such parallel engines have been designed or tested on platforms with thousands of processors. Here an overview is given of a unique PDES engine that has been designed to support Time Warp-style optimistic parallel execution as well as a more generalized mixed, optimistic-conservative synchronization. The engine is designed to run on massively parallel architectures with minimal overheads. A performance study of the engine is presented, including the first results to date of PDES benchmarks demonstrating scalability to as many as 16,384 processors, on an IBM Blue Gene supercomputer. The results show, for the first time, the promise of effectively sustaining very large scale discrete event execution on up to 10<sup>4 processors.


    SciTech Connect

    Abreu, P.; Andringa, S.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allard, D.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muniz, J.; Alves Batista, R.; Ambrosio, M.; Aramo, C.; Aminaei, A.; Anchordoqui, L.; Antici'c, T.; Arganda, E.; Collaboration: Pierre Auger Collaboration; and others


    A thorough search for large-scale anisotropies in the distribution of arrival directions of cosmic rays detected above 10{sup 18} eV at the Pierre Auger Observatory is presented. This search is performed as a function of both declination and right ascension in several energy ranges above 10{sup 18} eV, and reported in terms of dipolar and quadrupolar coefficients. Within the systematic uncertainties, no significant deviation from isotropy is revealed. Assuming that any cosmic-ray anisotropy is dominated by dipole and quadrupole moments in this energy range, upper limits on their amplitudes are derived. These upper limits allow us to test the origin of cosmic rays above 10{sup 18} eV from stationary Galactic sources densely distributed in the Galactic disk and predominantly emitting light particles in all directions.


    SciTech Connect

    Walsh, Jonelle L.; Van den Bosch, Remco C. E.; Yıldırım, Akın; Gebhardt, Karl; Richstone, Douglas O.; Gültekin, Kayhan; Husemann, Bernd


    The nearby lenticular galaxy NGC 1277 is thought to host one of the largest black holes known, however the black hole mass measurement is based on low spatial resolution spectroscopy. In this paper, we present Gemini Near-infrared Integral Field Spectrometer observations assisted by adaptive optics. We map out the galaxy's stellar kinematics within ∼440 pc of the nucleus with an angular resolution that allows us to probe well within the region where the potential from the black hole dominates. We find that the stellar velocity dispersion rises dramatically, reaching ∼550 km s{sup −1} at the center. Through orbit-based, stellar-dynamical models we obtain a black hole mass of (4.9 ± 1.6) × 10{sup 9} M{sub ⊙} (1σ uncertainties). Although the black hole mass measurement is smaller by a factor of ∼3 compared to previous claims based on large-scale kinematics, NGC 1277 does indeed contain one of the most massive black holes detected to date, and the black hole mass is an order of magnitude larger than expectations from the empirical relation between black hole mass and galaxy luminosity. Given the galaxy's similarities to the higher redshift (z ∼ 2) massive quiescent galaxies, NGC 1277 could be a relic, passively evolving since that period. A population of local analogs to the higher redshift quiescent galaxies that also contain over-massive black holes may suggest that black hole growth precedes that of the host galaxy.

  10. High e+/e– ratio dense pair creation with 10<sup>–2 laser irradiating solid targets

    SciTech Connect

    Liang, E.; Clarke, T.; Henderson, A.; Fu, W.; Lo, W.; Taylor, D.; Chaguine, P.; Zhou, S.; Hua, Y.; Cen, X.; Wang, X.; Kao, J.; Hasson, H.; Dyer, G.; Serratto, K.; Riley, N.; Donovan, M.; Ditmire, T.


    In this study, we report results of new pair creation experiments using ~100 Joule pulses of the Texas Petawatt Laser to irradiate solid gold and platinum targets, with intensities up to ~1.9 × 10<sup>21–2 and pulse durations as short as ~130 fs. Positron to electron (e+/e–) ratios >15% were observed for many thick disk and rod targets, with the highest e+/e– ratio reaching ~50% for a Pt rod. The inferred pair yield was ~ few ×10<sup>10sup> with emerging pair density reaching ~10<sup>15/cm3 so that the pair skin depth becomes < pair jet transverse size. These results represent major milestones towards the goal of creating a significant quantity of dense pair-dominated plasmas with e+/e– approaching 100% and pair skin depth << pair plasma size, which will have wide-ranging applications to astrophysics and fundamental physics.

  11. Measurement of the cosmic ray spectrum above 4×10<sup>18 eV using inclined events detected with the Pierre Auger Observatory

    SciTech Connect

    Aab, Alexander


    A measurement of the cosmic-ray spectrum for energies exceeding 4×10<sup>18 eV is presented, which is based on the analysis of showers with zenith angles greater than 60° detected with the Pierre Auger Observatory between 1 January 2004 and 31 December 2013. The measured spectrum confirms a flux suppression at the highest energies. Above 5.3×10<sup>18 eV, the ``ankle'', the flux can be described by a power law E–γ with index γ=2.70 ± 0.02 (stat) ± 0.1 (sys) followed by a smooth suppression region. For the energy (Es) at which the spectral flux has fallen to one-half of its extrapolated value in the absence of suppression, we find Es=(5.12±0.25 (stat)+1.0–1.2 (sys))×10<sup>19 eV.


    SciTech Connect

    Abreu, P.; Andringa, S.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allard, D.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Castillo, J. Alvarez; Alvarez-Muniz, J.; Alves Batista, R.; Ambrosio, M.; Aramo, C.; Aminaei, A.; Anchordoqui, L.; Antici'c, T.; Arganda, E.; Collaboration: Pierre Auger Collaboration; and others


    A thorough search for large-scale anisotropies in the distribution of arrival directions of cosmic rays detected above 10{sup 18} eV at the Pierre Auger Observatory is reported. For the first time, these large-scale anisotropy searches are performed as a function of both the right ascension and the declination and expressed in terms of dipole and quadrupole moments. Within the systematic uncertainties, no significant deviation from isotropy is revealed. Upper limits on dipole and quadrupole amplitudes are derived under the hypothesis that any cosmic ray anisotropy is dominated by such moments in this energy range. These upper limits provide constraints on the production of cosmic rays above 10{sup 18} eV, since they allow us to challenge an origin from stationary galactic sources densely distributed in the galactic disk and emitting predominantly light particles in all directions.

  13. Measurement of the cosmic ray spectrum above 4 × 10{sup 18} eV using inclined events detected with the Pierre Auger Observatory

    SciTech Connect

    Collaboration: Pierre Augur Collaboration


    A measurement of the cosmic-ray spectrum for energies exceeding 4×10{sup 18} eV is presented, which is based on the analysis of showers with zenith angles greater than 60° detected with the Pierre Auger Observatory between 1 January 2004 and 31 December 2013. The measured spectrum confirms a flux suppression at the highest energies. Above 5.3×10{sup 18} eV, the ''ankle'', the flux can be described by a power law E{sup −γ} with index γ=2.70 ± 0.02 (stat) ± 0.1 (sys) followed by a smooth suppression region. For the energy (E{sub s}) at which the spectral flux has fallen to one-half of its extrapolated value in the absence of suppression, we find E{sub s}=(5.12±0.25 (stat){sup +1.0}{sub −1.2} (sys))×10{sup 19} eV.

  14. Investigation of broadening and shift of vapour absorption lines of H{sub 2}{sup 16}O in the frequency range 7184 – 7186 cm{sup -1}

    SciTech Connect

    Nadezhdinskii, A I; Pereslavtseva, A A; Ponurovskii, Ya Ya


    We present the results of investigation of water vapour absorption spectra in the 7184 – 7186 cm{sup -1} range that is of particular interest from the viewpoint of possible application of the data obtained for monitoring water vapour in the Earth's stratosphere. The doublet of H{sub 2}{sup 16}O near ν = 7185.596 cm{sup -1} is analysed. The coefficients of broadening and shift of water vapour lines are found in the selected range in mixtures with buffer gases and compared to those obtained by other authors. (laser spectroscopy)

  15. L-shell emission from high-Z solid targets by intense 10{sup 19}W/cm{sup 2} irradiation with a 248nm laser

    SciTech Connect

    Nelson, T.R.; Borisov, A.B.; Boyer, K.


    Efficient (1.2% yield) multikilovolt x-ray emission from Ba(L) (2.4--2.8{angstrom}) and Gd(L) (1.7--2.1{angstrom}) is produced by ultraviolet (248nm) laser-excited BaF{sub 2} and Gd solids. The high efficiency is attributed to an inner shell-selective collisional electron ejection. Much effort has been expended recently in attempts to develop an efficient coherent x-ray source suitable for high-resolution biological imaging. To this end, many experiments have been performed studying the x-ray emissions from high-Z materials under intense (>10{sup 18}W/cm{sup 2}) irradiation, with the most promising results coming from the irradiation of Xe clusters with a UV (248nm) laser at intensities of 10{sup 18}--10{sup 19}W/cm{sup 2}. In this paper the authors report the production of prompt x-rays with energies in excess of 5keV with efficiencies on the order of 1% as a result of intense irradiation of BaF{sub 2} and Gd targets with a terawatt 248nm laser. The efficiency is attributed to an inner shell-selective collisional electron ejection mechanism in which the previously photoionized electrons are ponderomotively driven into an ion while retaining a portion of their atomic phase and symmetry. This partial coherence of the laser-driven electrons has a pronounced effect on the collisional cross-section for the electron ion interaction.

  16. On the temperature dependence of collisional linewidths of the 10{sup 0}0 - 00{sup 0}1 laser transition in the CO{sub 2} molecule

    SciTech Connect

    Arshinov, Konstantin I; Arshinov, M K; Nevdakh, Vladimir V


    Unsaturated absorption coefficients in pure carbon dioxide and CO{sub 2} - N{sub 2} and CO{sub 2} - He binary mixtures are measured at a pressure of 100 Torr in the temperature range of 300-700 K using a frequency-stabilised tunable CO{sub 2} laser. The relative coefficients of collisional broadening caused by N{sub 2} and He buffer gases and their temperature dependence are determined for the R(22) absorption line (10{sup 0}0 - 00{sup 0}1 transition) of the CO{sub 2} molecule. (active media)

  17. Ultra-stability Yb-doped fiber optical frequency comb with 2 × 10<sup>-18/s stability in-loop.


    Pang, Lihui; Han, Hainian; Zhao, Zhibin; Liu, Wenjun; Wei, Zhiyi


    We demonstrate a full control ultra-stability Yb-doped fiber optical frequency comb (OFC). The carrier-envelop offset frequency (fceo) and the repetition rate (fr) are locked with the standard phase locked loop (PLL) technique. The fceo is locked to the radio frequency (RF) synthesizer, and the Allan deviation is 1.2 × 10<sup>-17/s. The fr is locked to an ultra-stability continuous wave (CW) laser at 972 nm. The beat signal (fbeat) between the Yb-doped fiber OFC and CW laser is obtained with the signal to noise ratio (SNR) of 43 dB at 300 kHz resolution bandwidth (RBW). The time jitter of the fbeat signal is 278 as, which is integrated from 1 Hz to 10 MHz. The long-term stability is 575 μHz in 3 hours, and the corresponding Allan deviation is 2 × 10<sup>-18/s, which is the best stability result in Yb-doped fiber OFC. The linewidth is narrowed from 200 kHz to subhertz magnitude limited by the instrument resolution bandwidth.

  18. Effect of strain rates from 10/sup -2/ to 10 sec/sup -1/ in triaxial compression tests on three rocks

    SciTech Connect

    Blanton, T.L.


    Room-temperature, compression tests at strain rates from 10/sup -2/ to 10 sec/sup -1/ have been run on Charcoal Granodiorite to 0.45 GPa confining pressure and on Berea Sandstone and Indiana Limestone to 0.25 GPa confining pressure. For each rock at each confining pressure, the differential stress at failure is relatively constant up to a strain rate of 1 sec/sup -1/ and apparently increases abruptly above this strain rate. Dynamic analysis of the testing apparatus indicates that the apparent sudden increase in strength is due to machine inertia and does not reflect a real increase in the strength of the rocks. Taking inertia into account, the actual failure stresses of the three rocks are relatively independent of strain rate betweeen 10/sup -2/ and 10 sec/sup -1/. In the same interval, the strains at which the unconfined rocks begin to fragment tend to be lower at higher strain rates. The combination of decreasing strains and relatively constant stresses with increasing strain rate suggests that the energy necessary to fragment the unconfined rocks is lower at higher strain rates.


    SciTech Connect

    Krolik, Julian H.; Piran, Tsvi E-mail:


    We propose that the remarkable object Swift J1644+57, in which multiple recurring hard X-ray flares were seen over a span of several days, is a system in which a white dwarf was tidally disrupted by an intermediate-mass black hole. Disruption of a white dwarf rather than a main-sequence star offers a number of advantages in understanding the multiple, and short, timescales seen in the light curve of this system. In particular, the short internal dynamical timescale of a white dwarf offers a more natural way of understanding the short rise times ({approx}100 s) observed. The relatively long intervals between flares ({approx}5 Multiplication-Sign 10{sup 4} s) may also be readily understood as the period between successive pericenter passages of the remnant white dwarf. In addition, the expected jet power is larger when a white dwarf is disrupted. If this model is correct, the black hole responsible must have a mass {approx}< 10{sup 5} M{sub Sun }.

  20. High-gain 87 cm>-1 Raman line of KYW and its impact on continuous-wave Raman laser operation.


    Sarang, Soumya; Williams, Robert J; Lux, Oliver; Kitzler, Ondrej; McKay, Aaron; Jasbeer, Hadiya; Mildren, Richard P


    We report a quasi-continuous-wave external cavity Raman laser based on potassium yttrium tungstate (KYW). Laser output efficiency and spectrum are severely affected by the presence of high gain Raman modes of low frequency (< 250 cm>-1) that are characteristic of this crystal class. Output spectra contained frequency combs spaced by the low frequency modes but with the overall pump-to-Stokes conversion efficiency at least an order of magnitude lower than that typically obtained in other crystal Raman lasers. We elucidate the primary factors affecting laser performance by measuring the Raman gain coefficients of the low energy modes and numerically modeling the cascading dynamics. For a pump polarization aligned to the Ng crystallo-optic axis, the 87 cm>-1 Raman mode has a gain coefficient of 9.2 cm/GW at 1064 nm and a dephasing time T2 = 9.6 ps, which are both notably higher than for the 765 cm>-1 mode usually considered to be the prominent Raman mode of KYW. The implications for continuous-wave Raman laser design and the possible advantages for applications are discussed.

  1. 10sup>B(n, Z) measurements in the energy range 0.7 to 5.0 MeV

    SciTech Connect

    Massey, T. N.; Ralston, J.; Grimes, S. M.; Haight, R. C.


    Four ΔE E telescopes were used at the WNR (n,Z) station to investigate the production of charged particles from 10sup>B. The telescope consisted of a gas proportional detector and a silicon surface barrier detector. The flux was determined using a 238U fission chamber. A clear separation of the ground state alpha group and first excited state a was not achieved due to the target thickness. Proton emission was also observed. Furthermore, the proton branch was up to an order of magnitude larger than predicted in ENDF/B-VII A simple R-matrix analysis has been performed on the available data

  2. Cantilever stress measurements for pulsed laser deposition of perovskite oxides at 1000 K in an oxygen partial pressure of 10{sup −4} millibars

    SciTech Connect

    Premper, J.; Sander, D.; Kirschner, J.


    An in situ stress measurement setup using an optical 2-beam curvature technique is described which is compatible with the stringent growth conditions of pulsed laser deposition (PLD) of perovskite oxides, which involves high substrate temperatures of 1000 K and oxygen partial pressures of up to 1 × 10{sup −4} millibars. The stress measurements are complemented by medium energy electron diffraction (MEED), Auger electron spectroscopy, and additional growth rate monitoring by a quartz microbalance. A shielded filament is used to allow for simultaneous stress and MEED measurements at high substrate temperatures. A computer-controlled mirror scans an excimer laser beam over a stationary PLD target. This avoids mechanical noise originating from rotating PLD targets, and the setup does not suffer from limited lifetime issues of ultra high vacuum (UHV) rotary feedthroughs.

  3. Production and measurement of flash x-ray dose rates in excess of 10 sup 13 rad (CaF sub 2 )/s

    SciTech Connect

    Sanford, T.W.L.; Halbleib, J.A.; Beutler, D.E.; McAtee, W.H.; Mock, R.C.; Knott, D.P.


    The radiation field from an intense reusable source of flash x-rays that delivers a measured peak dose and dose rate of 370 {plus minus} 60 krad (CaF{sub 2}) and (3.5 {plus minus}0.7) {times} 10{sup 13} rad (CaF{sub 2})/s over a useful area of 80 cm{sub 2} is characterized. CaF{sub 2}:Mn TLDs (thermoluminescent dosimeters), which are used to measure the dose field, are shown to be dose-rate independent within {plus minus} 15% up to this level. Energy deposition in the CaF{sub 2} TLD chip was analyzed according to the origin of the electrons responsible for that deposition with a new computational tool. 22 refs., 7 figs.

  4. Evaluation of cross sections for neutron-induced reactions in sodium. [10/sup -5/ eV to 20 MeV

    SciTech Connect

    Larson, D.C.


    An evaluation of the neutron-induced cross sections of /sup 23/Na has been done for the energy range from 10/sup -5/ eV to 20 MeV. All significant cross sections are given, including differential cross sections for production of gamma rays. The recommended values are based on experimental data where available, and use results of a consistent model code analysis of available data to predict cross sections where there are no experimental data. This report describes the evaluation that was submitted to the Cross Section Evaluation Working Group (CSEWG) for consideration as a part of the Evaluated Nuclear Data File, Version V, and subsequently issued as MAT 1311. 126 references, 130 figures, 14 tables.

  5. {sup 248}Cm({sup 22}Ne,xn){sup 270-x}Sg reaction and the decay properties of {sup 265}Sg reexamined

    SciTech Connect

    Duellmann, Ch. E.; Tuerler, A.


    Recent studies of the hot fusion reaction {sup 248}Cm({sup 26}Mg,xn){sup 274-x}Hs have provided new nuclear decay data on {sup 265,266}Sg and confirmed the existence of an isomeric state in {sup 261}Rf. The results reported in [J. Dvorak et al., Phys. Rev. Lett. 100, 132503 (2008)] suggest that all decay chains observed in previous studies of the reaction {sup 248}Cm({sup 22}Ne,xn){sup 270-x}Sg, which were originally attributed to {sup 266}Sg, originated from {sup 265}Sg. Here, the decay properties of {sup 265}Sg are reevaluated. Indications for the existence of an isomeric state in {sup 265}Sg are found. The half-lives and main {alpha} particle energies of the two {sup 265}Sg states are 8.9 s/8.85 MeV and 16.2 s/8.70 MeV, respectively. Direct production of this isotope as an evaporation residue of a nuclear fusion reaction populates both states with similar intensity while {alpha} decay of {sup 269}Hs into {sup 265}Sg preferentially populates the longer-lived state, which in turn decays almost exclusively into the short-lived state in {sup 261}Rf. The cross section of the reaction {sup 248}Cm({sup 22}Ne,5n){sup 265}Sg is reanalyzed and found to be of the order of a few hundred pb, assuming that {alpha} decay is the only decay mode of {sup 265}Sg. A decay scheme that is consistent with the published data on {sup 265}Sg and {sup 261}Rf is proposed, which can serve as a working hypothesis in the design of new experiments dedicated to study the production and decay of these two isotopes.

  6. Cannabinoid receptor-2 (CB2) agonist ameliorates colitis in IL-10{sup −/−} mice by attenuating the activation of T cells and promoting their apoptosis

    SciTech Connect

    Singh, Udai P.; Singh, Narendra P.; Singh, Balwan; Price, Robert L.; Nagarkatti, Mitzi; Nagarkatti, Prakash S.


    Inflammatory bowel disease (IBD) is a chronic intestinal inflammation caused by hyperactivated effector immune cells that produce pro-inflammatory cytokines. Recent studies have shown that the cannabinoid system may play a critical role in mediating protection against intestinal inflammation. However, the effect of cannabinoid receptor induction after chronic colitis progression has not been investigated. Here, we investigate the effect of cannabinoid receptor-2 (CB2) agonist, JWH-133, after chronic colitis in IL-10{sup −/−} mice. JWH-133 effectively attenuated the overall clinical score, and reversed colitis-associated pathogenesis and decrease in body weight in IL-10{sup −/−} mice. After JWH-133 treatment, the percentage of CD4{sup +} T cells, neutrophils, mast cells, natural killer (NK1.1) cells, and activated T cells declined in the intestinal lamina propria (LP) and mesenteric lymph nodes (MLN) of mice with chronic colitis. JWH-133 was also effective in ameliorating dextran sodium sulfate (DSS)-induced colitis. In this model, JWH-133 reduced the number and percentage of macrophages and IFN-γ expressing cells that were induced during colitis progression. Treatment with aminoalkylindole 6-iodo-pravadoline (AM630), a CB2 receptor antagonist, reversed the colitis protection provided by JWH-133 treatment. Also, activated T cells were found to undergo apoptosis following JWH-133 treatment both in-vivo and in-vitro. These findings suggest that JWH-133 mediates its effect through CB2 receptors, and ameliorates chronic colitis by inducing apoptosis in activated T cells, reducing the numbers of activated T cells, and suppressing induction of mast cells, NK cells, and neutrophils at sites of inflammation in the LP. These results support the idea that the CB2 receptor agonists may serve as a therapeutic modality against IBD. -- Highlights: ► JWH-133, a cannnabinoid receptor-2 agonist ameliorates experimental colitis. ► JWH-133 suppressed inflammation and

  7. Cross section limits for the {sup 248}Cm({sup 25}Mg,4n-5n){sup 268,269}Hs reactions

    SciTech Connect

    Dvorak, J.; Dvorakova, Z.; Schuber, R.; Tuerler, A.; Yakushev, A.; Bruechle, W.; Duellmann, Ch. E.; Jaeger, E.; Schaedel, M.; Schausten, B.; Schimpf, E.; Eberhardt, K.; Thoerle, P.; Eichler, R.; Nagame, Y.; Qin, Z.; Semchenkov, A.; Wegrzecki, M.


    We report on an attempt to produce and detect {sup 268}Hs and {sup 269}Hs in the nuclear fusion reaction {sup 25}Mg+{sup 248}Cm using the gas phase chemistry apparatus COMPACT. No decay chains attributable to the decay of hassium isotopes were observed during the course of this experiment. From the nonobservation of {sup 269}Hs we derive a cross section limit of 0.4 pb (63% confidence limit) for the reaction {sup 248}Cm({sup 25}Mg,4n){sup 269}Hs at a center-of-target beam energy of 140 MeV. The evaluated cross section limit for the {sup 248}Cm({sup 25}Mg,5n){sup 268}Hs reaction depends on the assumed half-life of unknown {sup 268}Hs. Current systematics of the half-lives for even-even Hs isotopes suggests a value of 0.5 s, resulting in a cross section limit of 1.3 pb.

  8. Intramolecular energy transfer in actinide complexes of 6-methyl-2-(2-pyridyl)-benzimidazole (biz): comparison between Cm{sup 3+} and Tb{sup 3+} systems

    SciTech Connect

    Assefa, Zerihun . E-mail:; Yaita, T.; Haire, R.G.; Tachimori, S.


    Coordination of the 6-methyl-2-(2-pyridyl)-benzimidazole ligand with actinide and lanthanide species can produce enhanced emission due to increased efficiency of intramolecular energy transfer to metal centers. A comparison between the curium and terbium systems indicates that the position of the ligand's triplet state is critical for the enhanced emission. The energy gap between the ligand's triplet state and the acceptor level in curium is about 1000cm{sup -1}, as compared to a {approx}600cm{sup -1} gap in the terbium system. Due to the larger gap, the back transfer with curium is reduced and the radiative yield is significantly higher. The quantum yield for this 'sensitized' emission increases to 6.2%, compared to the 0.26% value attained for the metal centered excitation prior to ligand addition. In the terbium case, the smaller donor/acceptor gap enhances back transfer and the energy transfer is less efficient than with the curium system.

  9. Uniaxial Compression of Cellular Materials at a 10<sup>-1 s-1 Strain Rate Simultaneously with Synchrotron X-ray Computed Tomographic Imaging

    SciTech Connect

    Patterson, Brian M.


    The topic is presented as a series of slides. Motivation for the work included the following: X-ray tomography is a fantastic technique for characterizing a material’s starting structure as well as for non-destructive, in situ experiments to investigate material response; 3D X-ray tomography is needed to fully characterize the morphology of cellular materials; and synchrotron micro-CT can capture 3D images without pausing experiment. Among the conclusions reached are these: High-rate radiographic and tomographic imaging (0.25 s 3D frame rate) using synchrotron CT can capture full 3D images of hyper-elastic materials at a 10<sup>-2 strain rate; dynamic true in situ uniaxial loading can be accurately captured; the three stages of compression can be imaged: bending, buckling, and breaking; implementation of linear modeling is completed; meshes have been imported into LANL modeling codes--testing and validation is underway and direct comparison and validation between in situ data and modeled mechanical response is possible.

  10. Pressure induced polymerization of acetylide anions in CaC2 and 10<sup>7 fold enhancement of electrical conductivity

    SciTech Connect

    Zheng, Haiyan; Wang, Lijuan; Li, Kuo; Yang, Youyou; Wang, Yajie; Wu, Jiajia; Dong, Xiao; Wang, Chun -Hai; Tulk, Christopher A.; Molaison, Jamie J.; Ivanov, Ilia N.; Feygenson, Mikhail; Yang, Wenge; Guthrie, Malcolm; Zhao, Yusheng; Mao, Ho -Kwang; Jin, Changqing


    Transformation between different types of carbon–carbon bonding in carbides often results in a dramatic change of physical and chemical properties. Under external pressure, unsaturated carbon atoms form new covalent bonds regardless of the electrostatic repulsion. It was predicted that calcium acetylide (also known as calcium carbide, CaC2) polymerizes to form calcium polyacetylide, calcium polyacenide and calcium graphenide under high pressure. In this work, the phase transitions of CaC2 under external pressure were systematically investigated, and the amorphous phase was studied in detail for the first time. Polycarbide anions like C66– are identified with gas chromatography-mass spectrometry and several other techniques, which evidences the pressure induced polymerization of the acetylide anions and suggests the existence of the polyacenide fragment. Additionally, the process of polymerization is accompanied with a 10<sup>7 fold enhancement of the electrical conductivity. As a result, the polymerization of acetylide anions demonstrates that high pressure compression is a viable route to synthesize novel metal polycarbides and materials with extended carbon networks, while shedding light on the synthesis of more complicated metal organics.

  11. Conditions for efficient and stable ion acceleration by moderate circularly polarized laser pulses at intensities of 10{sup 20} W/cm{sup 2}

    SciTech Connect

    Qiao, B.; Zepf, M.; Borghesi, M.; Dromey, B.; Kar, S.; Geissler, M.; Gibbon, P.; Schreiber, J.


    Conditions for efficient and stable ion radiation pressure acceleration (RPA) from thin foils by circularly polarized laser pulses at moderate intensities are theoretically and numerically investigated. It is found that the unavoidable decompression of the co-moving electron layer in Light-Sail RPA leads to a change of the local electrostatic field from a ''bunching'' to a ''debunching'' profile, ultimately resulting in premature termination of ion acceleration. One way to overcome this instability is the use of a multispecies foil where the high-Z ions act as a sacrificial species to supply excess co-moving electrons for preserving stable acceleration of the lower-Z ion species. It is shown by 2D particle-in-cell simulations that 100 MeV/u monoenergetic C{sup 6+} ion beams are produced by irradiation of a Cu-C-mixed foil with laser pulses at intensities 5 x 10{sup 20} W/cm{sup 2}, which can be easily achieved by current day lasers.


    SciTech Connect

    Gonzalez, Anthony H.; Gettings, Daniel P.; Decker, Bandon; Brodwin, Mark; Eisenhardt, Peter R. M.; Stern, Daniel; Marrone, Daniel P.; Greer, Christopher H.; Stanford, S. A.; Wylezalek, Dominika; Aldering, Greg; Boone, Kyle; Fagrelius, Parker; Hayden, Brian; Abdulla, Zubair; Carlstrom, John; Leitch, Erik M.; Lin, Yen-Ting; Mantz, Adam B.; Muchovej, Stephen; and others


    We present confirmation of the cluster MOO J1142+1527, a massive galaxy cluster discovered as part of the Massive and Distant Clusters of WISE Survey. The cluster is confirmed to lie at z = 1.19, and using the Combined Array for Research in Millimeter-wave Astronomy we robustly detect the Sunyaev–Zel’dovich (SZ) decrement at 13.2σ. The SZ data imply a mass of M{sub 200m} = (1.1 ± 0.2) × 10{sup 15}M{sub ⊙}, making MOO J1142+1527 the most massive galaxy cluster known at z > 1.15 and the second most massive cluster known at z > 1. For a standard ΛCDM cosmology it is further expected to be one of the ∼5 most massive clusters expected to exist at z ≥ 1.19 over the entire sky. Our ongoing Spitzer program targeting ∼1750 additional candidate clusters will identify comparably rich galaxy clusters over the full extragalactic sky.


    SciTech Connect

    Willott, Chris J.; Omont, Alain; Bergeron, Jacqueline


    We present Atacama Large Millimeter Array observations of rest-frame far-infrared continuum and [C II] line emission in two z = 6.4 quasars with black hole masses of Almost-Equal-To 10{sup 8} M{sub Sun }. CFHQS J0210-0456 is detected in the continuum with a 1.2 mm flux of 120 {+-} 35 {mu}Jy, whereas CFHQS J2329-0301 is undetected at a similar noise level. J2329-0301 has a star formation rate limit of <40 M{sub Sun} yr{sup -1}, considerably below the typical value at all redshifts for this bolometric luminosity. Through comparison with hydro simulations, we speculate that this quasar is observed at a relatively rare phase where quasar feedback has effectively shut down star formation in the host galaxy. [C II] emission is also detected only in J0210-0456. The ratio of [C II] to far-infrared luminosity is similar to that of low-redshift galaxies of comparable luminosity, suggesting that the previous finding of an offset in the relationships between this ratio and far-infrared luminosity at low and high redshifts may be partially due to a selection effect due to the limited sensitivity of previous continuum data. The [C II] line of J0210-0456 is relatively narrow (FWHM = 189 {+-} 18 km s{sup -1}), indicating a dynamical mass substantially lower than expected from the local black hole-velocity dispersion correlation. The [C II] line is marginally resolved at 0.''7 resolution with the blue and red wings spatially offset by 0.''5 (3 kpc) and a smooth velocity gradient of 100 km s{sup -1} across a scale of 6 kpc, possibly due to the rotation of a galaxy-wide disk. These observations are consistent with the idea that stellar mass growth lags black hole accretion for quasars at this epoch with respect to more recent times.

  14. Kinetics of the reaction of OH with HI between 246 and 353 K

    SciTech Connect

    Campuzano-Jost, P.; Crowley, J.N.


    Iodine chemistry is believed to play a role in tropospheric, and, potentially, also stratospheric ozone loss. The laser-flash photolysis technique combined with resonance fluorescence detection of OH was used to investigate the kinetics of the title reaction at temperatures between 246 and 353 K and at a total pressure of 75 {+-} 1 Torr Ar. Under these conditions the rate coefficient shows a negative temperature dependence which is described by {kappa}{sub 4}(246--353 K) = 7.0{sub {minus}0.4}{sup +1.9} {times} 10{sup {minus}11}(T/298){sup 1.5{+-}0.5} cm{sup 3} s{sup {minus}1}. Both the large rate coefficient and trends in the reactivity of OH with HCl, HBr, and HI are suggestive of a reaction mechanism that proceeds without a significant activation barrier. The room temperature (294 K) rate constant is {kappa}{sub 4} = 6.5{sub {minus}0.4}{sup +2} {times} 10{sup {minus}11} cm{sup 3} s{sup {minus}1}, which is significantly larger than previous measurements. Reasons for this difference and the implications of the new rate coefficients for the lifetime of HI in the atmosphere are discussed.

  15. Diode laser probes of tert-butyl radical reaction kinetics: Reaction of C(CH sub 3 ) sub 3 with HBr, DBr, and HI

    SciTech Connect

    Richards, P.D.; Ryther, R.J.; Weitz, E. )


    The rate constants for reaction of tert-butyl radical with HBr, DBr, and HI have been measured by use of a tunable infrared diode laser probe. The measured rate constants at room temperature are 1.0 {times} 10{sup {minus}11}, 8 {times} 10{sup {minus}12}, and 2.5 {times} 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, respectively. The reaction with HI exhibits a negative activation energy of 1.5 kcal mol{sup {minus}1}. The reaction rates of HBr and DBr with tert-butyl radical at elevated temperatures are also slower than the corresponding rates at room temperature. The rate constant for reaction of tert-butyl radicals with HBr is in excellent agreement with the faster of the two conflicting previously reported measurements for the tert-butyl-HBr system. From this study the heat of formation of the tert-butyl radical has been calculated to be 11.5 {plus minus} 0.8 kcal mol{sup {minus}1}.

  16. Stimulated-emission cross sections of the /sup 5/F/sub 1/--/sup 5/I/sub 5/ and /sup 5/F/sub 1/--/sup 5/I/sub 6/ transitions of Pm/sup 3+/ in a phosphate glass

    SciTech Connect

    Beach, R.; Weinzapfel, S.; Staver, R.; Solarz, R.; Shinn, M.; Krupke, W.


    We report a laser cavity measurement of stimulated-emission cross sections for both the /sup 5//ital F//sub 1/--/sup 5//ital I//sub 5/ (0.93-/mu/m) and /sup 5//ital F//sub 1/--/sup 5//ital I//sub 6/ (1.1-/mu/m) laser transitions of Pm/sup 3+/ ions in a lead--indium--phosphate glass host. The measured cross sections for these two transitions are 1.8/times/10/sup /minus/20/ (/plus minus/11%) and 2.8/times/10/sup /minus/20/ cm/sup 2/ (/plus minus/22%), respectively. These values agree with previously reported values based on a Judd--Ofelt-type analysis of spectroscopic data.

  17. Long-term phase-locking technique for locking the repetition rate of an optical frequency comb laser with 1.67 × 10<sup>-19 precision.


    Ci, Cheng; Zhang, Xuesong; Li, Xinran; Chen, Xing; Cui, Yifan; Zhao, Yingxin; Liu, Bo; Wu, Hong


    An ultrahigh stable phase-locked loop system for synchronization of an optical frequency comb to a hydrogen maser has been proposed and experimentally demonstrated. A mathematical model has been set up to investigate the feasibility and steady state of the phase-locking system. The fractional frequency instability is evaluated by measuring the mixed-phase signal of an improved experimental system. Experimental results show that the fractional frequency instability of the phase-locked loop system lies from 8.83×10<sup>-16 at 1 s to 1.67×10<sup>-19 at 1000 s, which indicates our proposed phase-locking system possesses ultrahigh measurement precision with good long-term stabilization performance.

  18. Molecular eigenstate spectroscopy: Application to the intramolecular dynamics of some polyatomic molecules in the 3000 to 7000 cm{sup {minus}1} region

    SciTech Connect

    Perry, D.S.


    Intramolecular vibrational redistribution (IVR) appears to be a universal property of polyatomic molecules in energy regions where the vibrational density of states is greater than about 5 to 30 states per cm{sup {minus}1}. Interest in IVR stems from its central importance to the spectroscopy, photochemistry, and reaction kinetics of these molecules. A bright state, {var_phi}{sub s}, which may be a C-H stretching vibration, carries the oscillator strength from the ground state. This bright state may mix with bath rotational-vibrational levels to form a clump of molecular eigenstates, each of which carries a portion of the oscillator strength from the ground state. In this work the authors explicitly resolve transitions to each of these molecular eigenstates. Detailed information about the nature of IVR is contained in the frequencies and intensities of the observed discrete transitions. The primary goal of this research is to probe the coupling mechanisms by which IVR takes place. The most fundamental distinction to be made is between anharmonic coupling which is independent of molecular rotation and rotationally-mediated coupling. The authors are also interested in the rate at which IVR takes place. Measurements are strictly in the frequency domain but information is obtained about the decay of the zero order state, {var_phi}{sub s}, which could be prepared in a hypothetical experiment as a coherent excitation of the clump of molecular eigenstates. As the coherent superposition dephases, the energy would flow from the initially prepared mode into nearby overtones and combinations of lower frequency vibrational modes. The decay of the initially prepared mode is related to a pure sequence infrared absorption spectrum by a Fourier transform.

  19. Origin of the 900 cm{sup −1} broad double-hump OH vibrational feature of strongly hydrogen-bonded carboxylic acids

    SciTech Connect

    Van Hoozen, Brian L.; Petersen, Poul B.


    Medium and strong hydrogen bonds are common in biological systems. Here, they provide structural support and can act as proton transfer relays to drive electron and/or energy transfer. Infrared spectroscopy is a sensitive probe of molecular structure and hydrogen bond strength but strongly hydrogen-bonded structures often exhibit very broad and complex vibrational bands. As an example, strong hydrogen bonds between carboxylic acids and nitrogen-containing aromatic bases commonly display a 900 cm{sup −1} broad feature with a remarkable double-hump structure. Although previous studies have assigned this feature to the OH, the exact origin of the shape and width of this unusual feature is not well understood. In this study, we present ab initio calculations of the contributions of the OH stretch and bend vibrational modes to the vibrational spectrum of strongly hydrogen-bonded heterodimers of carboxylic acids and nitrogen-containing aromatic bases, taking the 7-azaindole—acetic acid and pyridine—acetic acid dimers as examples. Our calculations take into account coupling between the OH stretch and bend modes as well as how both of these modes are affected by lower frequency dimer stretch modes, which modulate the distance between the monomers. Our calculations reproduce the broadness and the double-hump structure of the OH vibrational feature. Where the spectral broadness is primarily caused by the dimer stretch modes strongly modulating the frequency of the OH stretch mode, the double-hump structure results from a Fermi resonance between the out of the plane OH bend and the OH stretch modes.

  20. [4+2[sup +

    SciTech Connect

    Becker, H.; Javahery, G.; Petrie, S.; Bohme, D.K. )


    Results of an experimental study using the selected-ion flow tube (SIFT) technique are reported for ion-molecule reactions of C[sub 60][sup [center dot]+] with a variety of cycloalkenes and acyclic and cyclic dienes at 294 [+-] 2 K in helium gas at a pressure of 0.35 [+-] 0.01 Torr. Addition is observed only with 1,3-cyclopentadiene and 1,3-cyclohexadiene. Rate coefficients were measured to be 1.0 and 1.5 x 10[sup [minus]11] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1], respectively. No reactions, k < 3 x 10[sup [minus]12] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1], were observed with 1,3-butadiene, isoprene, 1,3-pentadiene, cyclopentene, cyclohexene, furan, and 1,4-cyclohexadiene. These results provide indirect evidence for the occurrence of a Diels - Alder cycloaddition with 1,3-cyclopentadiene and 1,3-cyclohexadine. The addition reactions of these two molecules with C[sub 60][sup +] were found to be 5 [+-] 1 and 6 [+-] 2, respectively, faster than the addition reactions with C[sub 70][sup [center dot]+] for which rate coefficients of 2.0 and 2.5 x 10[sup [minus]12] cm[sup 3] molecule[sup [minus]1], respectively, were measured. 15 refs., 1 fig., 1 tab.

  1. Diffusion coefficients in gravel under unsaturated conditions

    SciTech Connect

    Conca, J.L.; Wright, J. )


    Diffusion coefficients were experimentally determined in unsaturated gravel to evaluate the effectiveness of gravel as a diffusion barrier to ionic transport in the vadose zone. Water contents were fixed by use of an ultracentrifuge with an ultralow constant rate flow pump supplying solution to the sample via a rotating seal. Once the gravel was at hydraulic steady state, the electrical conductivity was measured, and the diffusion coefficient calculated using the Nernst-Einstein equation. Diffusion coefficient values for potassium ion (D{sub e}) in four types of angular gravel ranged from 1.7 {times} 10{sup {minus}11} m{sup 2}/s (1.7 {times} 10{sup {minus}7} cm{sup 2}/s) for a 6.3-9.5 mm angular granitic gravel at a volumetric water content of 5.5% to 2.2 {times} 10{sup {minus}14} m{sup 2}/s (2.2 {times} 10{sup {minus}10} cm{sup 2}/s) in a 4.0-6.3 mm quartzite gravel at a volumetric water content of 0.47%. Variations in D{sub e} values resulted primarily from differences in water content which depends on gravel type and particle size.

  2. Infrared spectrum of the simplest Criegee intermediate CH{sub 2}OO at resolution 0.25 cm{sup −1} and new assignments of bands 2ν{sub 9} and ν{sub 5}

    SciTech Connect

    Huang, Yu-Hsuan; Li, Jun E-mail:; Guo, Hua; Lee, Yuan-Pern E-mail:


    The simplest Criegee intermediate CH{sub 2}OO is important in atmospheric chemistry. It has been detected in the reaction of CH{sub 2}I + O{sub 2} with various spectral methods, including infrared spectroscopy; infrared absorption of CH{sub 2}OO was recorded at resolution 1.0 cm{sup −1} in our laboratory. We have improved our system and recorded the infrared spectrum of CH{sub 2}OO at resolution 0.25 cm{sup −1} with rotational structures partially resolved. Observed vibrational wavenumbers and relative intensities are improved from those of the previous report and agree well with those predicted with quantum-mechanical calculations using the MULTIMODE method on an accurate potential energy surface. Observed rotational structures also agree with the simulated spectra according to theoretical predictions. In addition to derivation of critical vibrational and rotational parameters of the vibrationally excited states to confirm the assignments, the spectrum with improved resolution provides new assignments for bands 2ν{sub 9} at 1234.2 cm{sup −1} and ν{sub 5} at 1213.3 cm{sup −1}; some hot bands and combination bands are also tentatively assigned.

  3. Electrocatalytic H2 production with a turnover frequency >10<sup>7 s-1: the medium provides an increase in rate but not overpotential

    SciTech Connect

    Hou, Jianbo; Fang, Ming; Cardenas, Allan Jay P.; Shaw, Wendy J.; Helm, Monte L.; Bullock, R. Morris; Roberts, John A. S.; O'Hagan, Molly


    In this paper, rapid proton movement results in exceptionally fast electrocatalytic H2 production (up to 3 × 10<sup>7 s-1) at overpotentials of ~400 mV when catalysed by [Ni(PPh2NC6H4x2)2]2+ complexes in an acidic ionic liquid–water medium ([(DMF)H]NTf2–H2O, χH2O = 0.71).

  4. Probing of the neutrino magnetic moment at the level of 10{sup -22} μ{sub B} with an intense tritium source of (anti)neutrino and helium target (project)

    SciTech Connect

    Martemyanov, V.P.; Aleshin, V.I.; Tarasenko, V.G.; Tsinoev, V.G.; Sabelnikov, A.A.; Yukhimchuk, A.A.; Popov, V.V.; Baluev, V.V.; Golubkov, A.N.; Klevtsov, V.G.; Kuryakin, A.V.; Sitdikov, D.T.; Bogdanova, L.N.


    We present research results of the preparation project for the experimental measurement of the (anti)neutrino magnetic moment at the level of 10{sup -12} μ{sub B} using an intense tritium source of antineutrinos and a liquid helium scintillation detector. The neutrino detection in the scintillation detector is based on the scattering of neutrinos by the electrons of the helium atoms that produces fast electrons able to ionize and exciting helium atoms. The detection of the atomic radiation emitted during the relaxation process of the helium atoms and the knowledge of its parameters will allow us to conclude on the neutrino properties.

  5. Searches for large-scale anisotropy in the arrival directions of cosmic rays detected above energy of 10{sup 19} eV at the Pierre Auger observatory and the telescope array

    SciTech Connect

    Aab, A.; Abreu, P.; Andringa, S.; Aglietta, M.; Ahn, E. J.; Al Samarai, I.; Albuquerque, I. F. M.; Allekotte, I.; Asorey, H.; Allen, J.; Allison, P.; Almela, A.; Castillo, J. Alvarez; Alvarez-Muñiz, J.; Batista, R. Alves; Ambrosio, M.; Aramo, C.; Aminaei, A.; Anchordoqui, L.; Arqueros, F.; Collaboration: Pierre Auger Collaboration; Telescope Array Collaboration; and others


    Spherical harmonic moments are well-suited for capturing anisotropy at any scale in the flux of cosmic rays. An unambiguous measurement of the full set of spherical harmonic coefficients requires full-sky coverage. This can be achieved by combining data from observatories located in both the northern and southern hemispheres. To this end, a joint analysis using data recorded at the Telescope Array and the Pierre Auger Observatory above 10{sup 19} eV is presented in this work. The resulting multipolar expansion of the flux of cosmic rays allows us to perform a series of anisotropy searches, and in particular to report on the angular power spectrum of cosmic rays above 10{sup 19} eV. No significant deviation from isotropic expectations is found throughout the analyses performed. Upper limits on the amplitudes of the dipole and quadrupole moments are derived as a function of the direction in the sky, varying between 7% and 13% for the dipole and between 7% and 10% for a symmetric quadrupole.

  6. Unconfined compression experiments on Topopah Spring Member tuff at 22{degrees}C and a strain rate of 10{sup {minus}9} s{sup {minus}1}: Data report; Yucca Mountain Site Characterization Project

    SciTech Connect

    Martin, R.J. III; Boyd, P.J.; Noel, J.S.; Price, R.H.


    Experiment results are presented for unconfined compressive strength and elastic moduli of tuffaceous rocks from Busted Butte near Yucca Mountain, Nevada. The data have been compiled for the Yucca Mountain Site Characterization Project Site and Engineering Properties Data Base. Experiments were conducted on water-saturated specimens of the potential nuclear waste repository horizon Topopah Spring Member tuff (thermal/mechanical unit TSw2). The influence of strain rate on mechanical properties of the tuff was examined by loading six specimens in uniaxial compression at a strain rate of 10{sup {minus}9} s{sup {minus}1}. The experiments performed under ambient pressure and temperature conditions and conformed to Technical Procedure 91, titled ``Unconfined Compression Experiments at 22{degrees}C and a Strain Rate of 10{sup {minus}9} s{sup {minus}1}.`` The mean and standard deviation values of ultimate strength, Young`s modulus and Poisson`s ratio determined from these experiments are 85.4{plus_minus}21.7 MPa, 33.9{plus_minus}4.6 GPa, and 0.09{plus_minus}0.07, respectively.

  7. Synchrotron-based far infrared study of the rotation-vibration-inversion spectrum of silacyclobutane below 500 cm{sup −1}: The ν{sub 29} and ν{sub 30} bands

    SciTech Connect

    Chen, Ziqiu; Wijngaarden, Jennifer van


    Fourier transform spectra of the four-membered heterocycle silacyclobutane (c-C{sub 3}H{sub 8}Si) were recorded in the far infrared region from 100 to 500 cm{sup −1} with a maximum resolution of 0.000959 cm{sup −1} using synchrotron radiation from the Canadian Light Source. The two fundamental bands observed in this region correspond to motions best described as the out-of-plane modes related to ring puckering (ν{sub 30}) at ∼158 cm{sup −1} and SiH{sub 2} rocking (ν{sub 29}) at ∼410 cm{sup −1}. Both bands exhibit complex, dense spectral patterns that arise from ring inversion tunneling of the puckered SCB ring through a planar (C{sub 2v}) intermediate configuration. Analysis of these patterns revealed rotation-vibration transitions between states of the same inversion symmetry as well as rotation-vibration-inversion transitions that connect states of different inversion symmetry. Infrared ground state combination differences from 1871 pairs of P and R branch transitions were used to accurately determine the spectroscopic parameters for the tunneling-doubled ground state based on a broad range of quantum levels. With the ground state energy levels well-determined, 8255 infrared transitions were assigned and analyzed to derive the band centers, rotational and centrifugal distortion constants for the inversion split ν{sub 29} and ν{sub 30} vibrational states. Comparison with the band centers predicted via DFT (B3LYP) and MP2 calculations [6-311++G(2d,2p)] suggests that anharmonic corrections found via perturbation theory typically agree within 2% when compared with the observed spectrum of SCB.

  8. Highly accurate potential energy surface, dipole moment surface, rovibrational energy levels, and infrared line list for {sup 32}S{sup 16}O{sub 2} up to 8000 cm{sup −1}

    SciTech Connect

    Huang, Xinchuan E-mail:; Schwenke, David W.; Lee, Timothy J. E-mail:


    A purely ab initio potential energy surface (PES) was refined with selected {sup 32}S{sup 16}O{sub 2} HITRAN data. Compared to HITRAN, the root-mean-squares error (σ{sub RMS}) for all J = 0–80 rovibrational energy levels computed on the refined PES (denoted Ames-1) is 0.013 cm{sup −1}. Combined with a CCSD(T)/aug-cc-pV(Q+d)Z dipole moment surface (DMS), an infrared (IR) line list (denoted Ames-296K) has been computed at 296 K and covers up to 8000 cm{sup −1}. Compared to the HITRAN and CDMS databases, the intensity agreement for most vibrational bands is better than 85%–90%. Our predictions for {sup 34}S{sup 16}O{sub 2} band origins, higher energy {sup 32}S{sup 16}O{sub 2} band origins and missing {sup 32}S{sup 16}O{sub 2} IR bands have been verified by most recent experiments and available HITRAN data. We conclude that the Ames-1 PES is able to predict {sup 32/34}S{sup 16}O{sub 2} band origins below 5500 cm{sup −1} with 0.01–0.03 cm{sup −1} uncertainties, and the Ames-296K line list provides continuous, reliable and accurate IR simulations. The K{sub a}-dependence of both line position and line intensity errors is discussed. The line list will greatly facilitate SO{sub 2} IR spectral experimental analysis, as well as elimination of SO{sub 2} lines in high-resolution astronomical observations.

  9. Electron velocity of 6 × 10{sup 7 }cm/s at 300 K in stress engineered InAlN/GaN nano-channel high-electron-mobility transistors

    SciTech Connect

    Arulkumaran, S. Manoj Kumar, C. M.; Ranjan, K.; Teo, K. L.; Ng, G. I.; Shoron, O. F.; Rajan, S.; Bin Dolmanan, S.; Tripathy, S.


    A stress engineered three dimensional (3D) Triple T-gate (TT-gate) on lattice matched In{sub 0.17}Al{sub 0.83}N/GaN nano-channel (NC) Fin-High-Electron-Mobility Transistor (Fin-HEMT) with significantly enhanced device performance was achieved that is promising for high-speed device applications. The Fin-HEMT with 200-nm effective fin-width (W{sub eff}) exhibited a very high I{sub Dmax} of 3940 mA/mm and a highest g{sub m} of 1417 mS/mm. This dramatic increase of I{sub D} and g{sub m} in the 3D TT-gate In{sub 0.17}Al{sub 0.83}N/GaN NC Fin-HEMT translated to an extracted highest electron velocity (v{sub e}) of 6.0 × 10{sup 7 }cm/s, which is ∼1.89× higher than that of the conventional In{sub 0.17}Al{sub 0.83}N/GaN HEMT (3.17 × 10{sup 7 }cm/s). The v{sub e} in the conventional III-nitride transistors are typically limited by highly efficient optical-phonon emission. However, the unusually high v{sub e} at 300 K in the 3D TT-gate In{sub 0.17}Al{sub 0.83}N/GaN NC Fin-HEMT is attributed to the increase of in-plane tensile stress component by SiN passivation in the formed NC which is also verified by micro-photoluminescence (0.47 ± 0.02 GPa) and micro-Raman spectroscopy (0.39 ± 0.12 GPa) measurements. The ability to reach the v{sub e} = 6 × 10{sup 7 }cm/s at 300 K by a stress engineered 3D TT-gate lattice-matched In{sub 0.17}Al{sub 0.83}N/GaN NC Fin-HEMTs shows they are promising for next-generation ultra-scaled high-speed device applications.

  10. Electronic state spectroscopy of diiodomethane (CH{sub 2}I{sub 2}): Experimental and computational studies in the 30 000–95 000 cm{sup −1} region

    SciTech Connect

    Mandal, Anuvab; Jagatap, B. N.; Singh, Param Jeet; Shastri, Aparna


    The electronic absorption spectrum of diiodomethane in the 30 000–95 000 cm{sup −1} region is investigated using synchrotron radiation; the spectrum in the 50 000–66 500 cm{sup −1} region is reported for the first time. The absorption bands in the 30 000–50 000 cm{sup −1} region are attributed to valence transitions, while the vacuum ultraviolet (VUV) spectrum (50 000–95 000 cm{sup −1}) is dominated by several Rydberg series converging to the first four ionization potentials of CH{sub 2}I{sub 2} at 9.46, 9.76, 10.21, and 10.56 eV corresponding to the removal of an electron from the outermost 3b{sub 2}, 2b{sub 1}, 1a{sub 2}, and 4a{sub 1} non-bonding orbitals, respectively. Rydberg series of ns, np, and nd type converging to each of the four ionization potentials are assigned based on a quantum defect analysis. Time dependent density functional theory calculations of excited states support the analysis and help in interpretation of the Rydberg and valence nature of observed transitions. Density functional theory calculations of the neutral and ionic ground state geometries and vibrational frequencies are used to assign the observed vibronic structure. Vibronic features accompanying the Rydberg series are mainly due to excitation of the C-I symmetric stretch (ν{sub 3}) and CH{sub 2} wag (ν{sub 8}) modes, with smaller contributions from the C-H symmetric stretch (ν{sub 1}). UV absorption bands are assigned to low lying valence states 1{sup 1}B{sub 2}, 1{sup 1}B{sub 1}, 2{sup 1}A{sub 1}, 3{sup 1}A{sub 1}, 2{sup 1}B{sub 1}, and 2{sup 1}B{sub 2} and the unusually high underlying intensity in parts of the VUV spectrum is attributed to valence states with high oscillator strength. This is the first report of a comprehensive Rydberg series and vibronic analysis of the VUV absorption spectrum of CH{sub 2}I{sub 2} in the 50 000–85 000 cm{sup −1} region. The VUV absorption spectrum of CD{sub 2}I{sub 2} which serves to verify and

  11. Neutrino magnetic moment

    SciTech Connect

    Chang, D. . Dept. of Physics and Astronomy Fermi National Accelerator Lab., Batavia, IL ); Senjanovic, G. . Dept. of Theoretical Physics)


    We review attempts to achieve a large neutrino magnetic moment ({mu}{sub {nu}} {le} 10{sup {minus}11}{mu}{sub B}), while keeping neutrino light or massless. The application to the solar neutrino puzzle is discussed. 24 refs.

  12. Decay Properties of {sup 266}Bh and {sup 262}Db Produced in the {sup 248}Cm+{sup 23}Na Reaction - Further Confirmation of the {sup 278}113 Decay Chain

    SciTech Connect

    Morita, K.; Morimoto, K.; Kaji, D.; Haba, H.; Ozeki, K.; Kudou, Y.; Yoneda, A.; Ichikawa, T.; Katori, K.; Yoshida, A.; Sato, N.; Sumita, T.; Fujimori, Y.; Tokanai, F.; Goto, S.; Ideguchi, E.; Kasamatsu, Y.; Koura, H.; Tsukada, K.; Komori, Y.


    Decay properties of an isotope {sup 266}Bh and its daughter nucleus {sup 262}Db produced by the {sup 248}Cm({sup 23}Na,5n) reaction were studied by using a gas-filled recoil separator coupled with a position-sensitive semiconductor detector. {sup 266}Bh was clearly identified from the correlation of the known nuclide, {sup 262}Db. The obtained decay properties of {sup 266}Bh and {sup 262}Db are consistent with those observed in the {sup 278}113 chain by RIKEN collaboration, which provided further confirmation of the discovery of {sup 278}113.

  13. Influence of the active medium composition on the gain in the 00/sup 0/2--(10/sup 0/1, 02/sup 0/1)/sub I/ band for a TEA CO/sub 2/ laser with ultraviolet preionization

    SciTech Connect

    Bertel', I.M.; Petukhov, V.O.; Trushin, S.A.; Churakov, V.V.


    An experimental and theoretical investigation was made of the small-signal gains of lines in the second sequence band, and of the temperature of the asymmetric 3/ mode of the CO/sub 2/ molecule in a TEA CO/sub 2/ amplifier as a function of the composition of the CO/sub 2/--N/sub 2/--He mixture. The optimal partial pressures of the component were determined. In a TEA CO/sub 2/ amplifier with ultraviolet preionization provided by auxiliary lateral discharges it was found that the maximum gain of approx.0.01 cm/sup -1/ for the 10P(19) line of the second sequence band was achieved in a CO/sub 2/:N/sub 2/:He = 1:1:3 mixture.

  14. Rate constant for the reaction of atomic chlorine with acetaldehyde from 210 to 343 K

    SciTech Connect

    Payne, W.A.; Nava, D.F.; Nesbitt, F.L.; Stief, L.J. )


    The absolute rate constant for the reaction of atomic chlorine with acetaldehyde has been measured from 210 to 343 K by use of the flash photolysis-resonance fluorescence technique. The rate constant is shown to be independent of variations in (CH{sub 3}CHO), total pressure (Ar), and, to a lesser extent, flash intensity (initial (Cl)). The rate constant is also independent of temperature over the range studied. The average of all experiments yields k{sub 1} = (6.6 {plus minus} 1.4) {times} 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, where the error limit is two standard deviations. This result is compared with previous measurements of k{sub 1}, all of which were relative measurements at 298 K.

  15. Magnetic characterization of a hydrogen phase trapped inside deep dislocation cores in a hydrogen-cycled PdH{sub x} (x {approx} 4.5 x 10{sup -4}) single crystal

    SciTech Connect

    Lipson, A. G. Heuser, B. J.; Castano, C. H.; Lyakhov, B. F.; Tsivadze, A. Yu.


    The magnetic characterization of Pd single crystals deformed by cycling in a hydrogen atmosphere has been performed. Based on evidence obtained from thermal desorption analysis, it is shown that the condensed hydrogen phase formed inside deep dislocation cores in PdH{sub x} (x = H/Pd {approx} 4.5 x 10{sup -4}) is tightly bound with a Pd matrix. The activation energy of hydrogen desorption from these cores was found to be as high as e = 1.6eV/H-atom, suggesting the occurrence of a strong band overlapping between Pd and H atoms. SQUID measurements carried out in a weak magnetic field (H < 5.0 Oe) showed an anomalous diamagnetic contribution to the DC and AC magnetic susceptibilities of the PdH{sub x} sample at T < 30 K resulting in the presence of the hydrogen phase. It is suggested that the anomalous diamagnetic response in PdH{sub x} is caused by the presence of a hydrogen dominant phase, tightly bound with a Pd matrix inside the dislocation cores (nanotubes)

  16. Poster — Thur Eve — 21: Off-axis dose perturbation effects in water in a 5 × 5 cm{sup 2} 18 MV photon beam for the PTW microLion and Exradin A1SL ionization chambers

    SciTech Connect

    O'Grady, K; Davis, S D; Papaconstadopoulos, P; Seuntjens, J


    A PTW microLion liquid ionization chamber and an Exradin A1SL air-filled ionization chamber have been modeled using the egs-chamber user code of the EGSnrc system to determine their perturbation effects in water in a 5 × 5 cm{sup 2} 18 MV photon beam. A model of the Varian CL21EX linear accelerator was constructed using the BEAMnrc Monte Carlo code, and was validated by comparing measured PDDs and profiles from the microLion and A1SL chambers to calculated results that included chamber models. Measured PDDs for a 5 × 5 cm{sup 2} field for the microLion chamber agreed with calculations to within 1.5% beyond a depth of 0.5 cm, and the A1SL PDDs agreed within 1.0% beyond 1.0 cm. Measured and calculated profiles at 10 cm depth agreed within 1.0% for both chambers inside the field, and within 4.0% near the field edge. Local percent differences increased up to 15% at 4 cm outside the field. The ratio of dose to water in the absence of the chamber relative to dose in the chamber's active volume as a function of off-axis distance was calculated using the egs-chamber correlated sampling technique. The dose ratio was nearly constant inside the field and consistent with the stopping power ratios of water to detector material, but varied up to 3.3% near the field edge and 5.2% at 4 cm outside the field. Once these perturbation effects are fully characterized for more field sizes and detectors, they could be applied to clinical water tank measurements for improved dosimetric accuracy.

  17. Results of Charpy V-Notch Impact Testing of Structural Steel Specimens Irradiated at ~30°C to 1 x 10<sup>16 neutrons/cm2 in a Commercial Reactor Cavity

    SciTech Connect

    Iskander, S. K.; Stoller, R. E.


    A capsule containing Charpy V-notch (CVN) and mini-tensile specimens was irradiated at ~30°C (~ 85°F) in the cavity of a commercial nuclear power plant to a fluence of 1 x 10<sup>16 neutrons/cm2 (>1 MeV). The capsule included six CVN impact specimens of archival High Flux Isotope Reactor A212 grade B ferritic steel and five CVN impact specimens of a well-studied A36 structural steel. This irradiation was part of the ongoing study of neutron-induced damage effects at the low temperature and flux experienced by reactor supports. The plant operators shut down the plant before the planned exposure was reached. The exposure of these specimens produced no significant irradiation-induced embrittlement. Of interest were the data on unirradiated specimens in the L-T orientation machined from a single plate of A36 structural steel, which is the same specification for the structural steel used in some reactor supports. The average CVN energy of five unirradiated specimens obtained from one region of the plate and tested at room temperature was ~ 99 J, while the energy of 11 unirradiated specimens from other locations of the same plate was 45 J, a difference of ~ 220%. The CVN impact energies for all 18 specimens ranged from a low of 32 J to a high of 111 J. Moreover, it appears that the University of Kansas CVN impact energy data of the unirradiated specimens at the 100-J level are shifted toward higher temperatures by about 20 K. The results were an example of the extent of scatter possible in CVN impact testing. Generic values for the CVN impact energy of A36 should be used with caution in critical applications.

  18. Infrared absorption spectroscopy and chemical kinetics of free radicals. Progress report, February 1, 1991--March 1, 1994

    SciTech Connect

    Curl, R.F.; Glass, G.P.


    Rate of reaction of ketenyl radical with O{sub 2} at room temperature was determined as 6.5(6) {times} 10-{sup {minus}13} CM{sup 3} molecules{sup {minus}1} s{sup {minus}1} and an upper bound of 1 {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1} was estimated for the reaction rate of acetylene with ketenyl. The high resolution spectrum of the {nu}1 acetylenic CH stretch of propargy1 radical (HCCCH{sub 2}) near 3322 cm{sup {minus}1} has obtained and analyzed. Nuclear spin weights demonstrate that the CH{sub 2} hydrogen atoms are in the carbon atom plane. We have attempted to measure the propargy1 recombination rate constant at 296 K; however, the observed rate constant of (1.2{times}0.2) x 10{sup {minus}10} cc-molecule{sup {minus}1}-s{sup {minus}1} may be affected by other reactions. The CH stretch fundamental, {nu}1, of HCCN has been observed, assigned, and analyzed. Analysis of the hot bands associated with bending shows that HCCN is a quasilinear molecule with a very floppy potential function for the HCC bending angle. The barrier to linearity is estimated to be about 100 cm{sup {minus}1}. Rate of the reaction between C{sub 2}H and H{sub 2} has been measured at 295--855 K. The rate constant exhibited a non-Arrhenius form well represented by k = (9.44{plus_minus}0.50) {times} 10{sup {minus}14}T{sup 0.9}exp(-1003{plus_minus}40/T)cm{sup 3}molecule{sup {minus}1}s{sup {minus}1}. The reaction between atomic oxygen and the amidogen radical, NH{sub 2} has been studied at 295 K; the room temperature rate constant was measured as (6.5 {plus_minus} 1.3) {times} 10{sup {minus}1} s{sup {minus}1}. The minor channel leading to NH + OH was observed but accounted for at most about 8% of the NH{sub 2} reacting. The rate constant for the reaction NH+O was determined from fitting the NH time profile to be 6.6{plus_minus}10{sub {minus}11} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}.

  19. Stationary and pulsed photolysis and pyrolysis of 1,1-dimethylsilacyclobutane

    SciTech Connect

    Brix, T.; Arthur, N.L.; Potzinger, P. )


    A study of the photolysis of 1,1-dimethylsilacyclobutane at 147-214 nm shows that of the four primary processes identified the predominant mode of decomposition is to C{sub 2}H{sub 4} and dimethylsilaethene. Evidence from experiments in the presence of SF{sub 6} suggests that the dimethylsilaethene is formed initially in a vibrationally excited state. Laser pulsed photolysis experiments at 193 nm have been carried out to measure the absorption spectrum of Me{sub 2}SiCH{sub 2}, its absorption cross section, and the rate constant for Me{sub 2}SCH{sub 2} combination. The values obtained are {sigma} (240 nm, base e) = (1.0 {plus minus} 0.2) {times} 10{sup {minus}17} cm{sup 2} and k{sub 7} = (3.3 {plus minus} 0.8) {times} 10{sup {minus}11} cm{sup 3} s{sup {minus}1}. The kinetics of the pyrolysis of Me{sub 2}SiCH{sub 2}CH{sub 2}CH{sub 2} have also been reexamined.

  20. Measurements of production cross sections of 10sup>Be and 26Al by 120 GeV and 392 MeV proton bombardment of 89Y, 159Tb, and natCu targets

    SciTech Connect

    Sekimoto, S.; Okumura, S.; Yashima, H.; Matsushi, Y.; Matsuzaki, H.; Matsumura, H.; Toyoda, A.; Oishi, K.; Matsuda, N.; Kasugai, Y.; Sakamoto, Y.; Nakashima, H.; Boehnlein, D.; Coleman, R.; Lauten, G.; Leveling, A.; Mokhov, N.; Ramberg, E.; Soha, A.; Vaziri, K.; Ninomiya, K.; Omoto, T.; Shima, T.; Takahashi, N.; Shinohara, A.; Caffee, M. W.; Welten, K. C.; Nishiizumi, K.; Shibata, S.; Ohtsuki, T.


    The production cross sections of 10sup>Be and 26Al were measured by accelerator mass spectrometry using 89Y, 159Tb, and natCu targets bombarded by protons with energies Ep of 120 GeV and 392 MeV. The production cross sections obtained for 10sup>Be and 26Al were compared with those previously reported using Ep = 50 MeV–24 GeV and various targets. It was found that the production cross sections of 10sup>Be monotonically increased with increasing target mass number when the proton energy was greater than a few GeV. On the other hand, it was also found that the production cross sections of 10sup>Be decreased as the target mass number increased from that of carbon to those near the mass numbers of nickel and zinc when the proton energy was below approximately 1 GeV. They also increased as the target mass number increased from near those of nickel and zinc to that of bismuth, in the same proton energy range. Similar results were observed in the production cross sections of 26Al, though the absolute values were quite different between 10sup>Be and 26Al. As a result, the difference between these production cross sections may depend on the impact parameter (nuclear radius) and/or the target nucleus stiffness.

  1. Estimation of Ni{sup 63}, Pu{sup 241}, Pu{sup 242} and Am{sup 243} from Co{sup 60}, Pu{sup 239}, and Cm{sup 244} activities in groundwater samples

    SciTech Connect

    Holcomb, H.P.


    The Part B Permit for F&H Seepage Basins calls for analysis of several constituents of concern in groundwater monitoring wells. Four of these analytes are the radionuclides Ni{sup 63}, Pu{sup 241}, Pu{sup 242}, and Am{sup 243}. These are currently not being analyzed due to their very difficult, tedious analytical schemes coupled with their relatively low activity values. This report demonstrates how the activity value for Ni{sup 63}, a week beta emitter, can be estimated from that of Co{sup 60}, an easily detectable, high-energy gamma emitter. Similarly, estimates of Pu{sup 241}, a beta emitter, and the alpha-emitting Pu{sup 242} can be made from the activity value of the more easily detected Pu{sup 239}. Am{sup 243} can be estimated from the activity of Cm{sup 244}, which is easier to detect because of a shorter half-life (higher specific activity) and the emission of higher energy alpha particles. These correlations are made under very specific parameters in order to ensure the validity of this approach. Therefore, assumptions must be established setting ground rules for establishing these activity relationships. Bases for these assumptions are explained and/or referenced. Their degree of uncertainty limits the accuracy of the data so that the term ``estimate`` is used. Such soundly-based, conservative estimates for these four rads can provide a tool for evaluating any hazards from their presence over the next several years. Hopefully, during this time, sufficient advances will be made in their radiochemical analyses and in counting techniques so that in the future, their activities may be quantitatively determined more easily and also more cost effectively.

  2. Measurements of cross sections and decay properties of the isotopes of elements 112, 114, and 116 produced in the fusion reactions {sup 233,238}U, {sup 242}Pu, and {sup 248}Cm+{sup 48}Ca

    SciTech Connect

    Oganessian, Yu.Ts.; Utyonkov, V.K.; Lobanov, Yu.V.; Abdullin, F.Sh.; Polyakov, A.N.; Shirokovsky, I.V.; Tsyganov, Yu.S.; Gulbekian, G.G.; Bogomolov, S.L.; Gikal, B.N.; Mezentsev, A.N.; Iliev, S.; Subbotin, V.G.; Sukhov, A.M.; Voinov, A.A.; Buklanov, G.V.; Subotic, K.; Zagrebaev, V.I.; Itkis, M.G.; Patin, J.B.


    We have studied the dependence of the production cross sections of the isotopes {sup 282,283}112 and {sup 286,287}114 on the excitation energy of the compound nuclei {sup 286}112 and {sup 290}114. The maximum cross section values of the xn-evaporation channels for the reaction {sup 238}U({sup 48}Ca,xn){sup 286-x}112 were measured to be {sigma}{sub 3n}=2.5{sub -1.1}{sup +1.8} pb and {sigma}{sub 4n}=0.6{sub -0.5}{sup +1.6} pb; for the reaction {sup 242}Pu({sup 48}Ca,xn){sup 290-x}114: {sigma}{sub 2n}{approx}0.5 pb, {sigma}{sub 3n}=3.6{sub -1.7}{sup +3.4} pb, and {sigma}{sub 4n}=4.5{sub -1.9}{sup +3.6} pb. In the reaction {sup 233}U({sup 48}Ca,2-4n){sup 277-279}112 at E*=34.9=2.2 MeV we measured an upper cross section limit of {sigma}{sub xn}{<=}0.6 pb. The observed shift of the excitation energy associated with the maximum sum evaporation residue cross section {sigma}{sub ER}(E*) to values significantly higher than that associated with the calculated Coulomb barrier can be caused by the orientation of the deformed target nucleus in the entrance channel of the reaction. An increase of {sigma}{sub ER} in the reactions of actinide targets with {sup 48}Ca is consistent with the expected increase of the survivability of the excited compound nucleus upon closer approach to the closed neutron shell N=184. In the present work we detected 33 decay chains arising in the decay of the known nuclei {sup 282}112, {sup 283}112, {sup 286}114, {sup 287}114, and {sup 288}114. In the decay of {sup 287}114({alpha}){yields}{sup 283}112({alpha}){yields}{sup 279}110(SF), in two cases out of 22, we observed decay chains of four and five sequential {alpha} transitions that end in spontaneous fission of {sup 271}Sg (T{sub {alpha}}{sub /SF}=2.4{sub -1.0}{sup +4.3} min) and {sup 267}Rf (T{sub SF}{approx}2.3 h), longer decay chains than reported previously. We observed the new nuclide {sup 292}116 (T{sub {alpha}}=18{sub -6}{sup +16} ms,E{sub {alpha}}=10.66{+-}0.07 MeV) in the irradiation of the {sup 248}Cm target at a higher energy than in previous experiments. The observed nuclear decay properties of the nuclides with Z=104-118 are compared with theoretical nuclear mass calculations and the systematic trends of spontaneous fission properties. As a whole, they give a consistent pattern of decay of the 18 even-Z neutron-rich nuclides with Z=104-118 and N=163-177. The experiments were performed with the heavy-ion beam delivered by the U400 cyclotron of the FLNR (JINR, Dubna) employing the Dubna gas-filled recoil separator.

  3. A novel waste form for disposal of spent-nuclear-fuel reprocessing waste: A vitrifiable cement

    SciTech Connect

    Gougar, M.L.D.; Scheetz, B.E.; Siemer, D.D.


    A cement capable of being hot isostatically pressed into a glass ceramic has been proposed as the waste form for spent-nuclear-fuel reprocessing wastes at the Idaho National Engineering and Environmental Laboratory (INEEL). This intermediate cement, with a composition based on that of common glasses, has been designed and tested. The cement formulations included mixed INEEL wastes, blast furnace slag, reactive silica, and INEEL soil or vermiculite, which were activated with potassium or sodium hydroxide. Following autoclave processing, the cements were characterized. X-ray diffraction analysis revealed three notable crystalline phases: quartz, calcite, and fluorite. Results of compressive strength testing ranged from 1452 and 4163 psi, exceeding the US Nuclear Regulatory Commission (NRC)-suggested standard of >500 psi. From American National Standards Institute/American Nuclear Society 16.1-1986 leach testing, effective diffusivities for Cs were determined to be on the order of 10{sup {minus}11} to 10{sup {minus}10} cm{sup 2}/s and for Sr were 10{sup {minus}12} cm{sup 2}/s, which are four orders of magnitude less than diffusivities in some other radwaste materials. Average leach indices (LI) were 9.6 and 11.9 for Cs and Sr, respectively, meeting the NRC Standard of LI > 6. The 28-day Materials Characterization Center-1 leach testing resulted in normalized elemental mass losses between 0.63 and 28 g/(m{sup 2}{center_dot}day) for Cs and between 0.34 and 0.70 g/(m{sup 2}{center_dot}day) industry-accepted standard while Cs losses indicate a process sensitive parameter.

  4. Mg dopant in Cu{sub 2}ZnSnSe{sub 4}: An n-type former and a promoter of electrical mobility up to 120 cm{sup 2} V{sup −1} s{sup −1}

    SciTech Connect

    Kuo, Dong-Hau Wubet, Walelign


    Mg-doped Cu{sub 2}ZnSnSe{sub 4} (CZTSe) bulk materials with the (Cu{sub 2−x}Mg{sub x})ZnSnSe{sub 4} formula at x=0, 0.1, 0.2, 0.3, and 0.4 were prepared at 600 °C for 2 h with soluble sintering aids of Sb{sub 2}S{sub 3} and Te. Defect chemistry was studied by measuring structural and electrical properties of Mg-doped CZTSe as a function of dopant concentration. Except at x=0, all Mg-doped CZTSe pellets showed an n-type behavior. The Mg-doped CZTSe pellets showed an n-type behavior. n-Type Mg-CZTSe pellets at x=0.1 showed the highest electrical conductivity of 24.6 S cm{sup −1} and the net hole mobility of 120 cm{sup 2} V{sup −1} s{sup −1}, while they were 11.8 S cm{sup −1} and 36.5 cm{sup 2} V{sup −1} s{sup −1} for the undoped p-type CZTSe. Mg dopant is a strong promoter of electrical mobility. Mg dopant behaves as a donor defect in CZTSe at a 5% doping content, but is also used as an acceptor at a high content above 5%. Mg doping has further developed CZTSe into a promising semiconductor. - Graphical abstract: The effects of extrinsic doping of Mg{sup 2+} on the electrical properties of Cu{sub 2}ZnSnSe{sub 4} bulks. - Highlights: • (Cu{sub 2−x}Mg{sub x})ZnSnSe{sub 4} bulks were fabricated by liquid-phase sintering at 600 °C. • All Mg-x-CZTSe pellets except at x=0 exhibited n-type conductivity. • Electrical properties of CZTSe pellets changed with the Cu and Mg ratios. • Mg{sup 2+} goes to the Cu{sup 1+} site to form the Mg{sub Cu}{sup 1+} donor defect for the n-type CZTSe. • n-Type Mg-0.1-CZTSe bulk with 5% Mg showed the highest mobility of 120 cm{sup 2} V{sup −1} s{sup −1}.


    SciTech Connect

    Vikas, Shailendra; Wood-Vasey, W. Michael; Lundgren, Britt; Ross, Nicholas P.; Myers, Adam D.; AlSayyad, Yusra; York, Donald G.; Schneider, Donald P.; Brinkmann, J.; Bizyaev, Dmitry; Brewington, Howard; Malanushenko, Elena; Malanushenko, Viktor; Oravetz, Daniel; Pan, Kaike; Snedden, Stephanie; Ge, Jian; Muna, Demitri; Paris, Isabelle; Petitjean, Patrick; and others


    We measure the two-point cross-correlation function of C IV absorber systems and quasars, using spectroscopic data from the Sloan Digital Sky Survey III Baryon Oscillation Spectroscopic Survey (BOSS; Data Release 9). The 19,701 quasars and 6149 C IV ''moderate'' absorbers, 0.28 A < rest-frame equivalent width (EW) < 5 A, in our study cover a redshift range of 2.1 < z < 2.5 over 3300 deg{sup 2} and represent a factor of two increase in sample size over previous investigations. We find a correlation scale length and slope of the redshift-space cross-correlation function of s{sub 0} = 8.46 {+-} 1.24 Mpc, {gamma} = 1.68 {+-} 0.19, in the redshift-space range 10 < s < 100 Mpc. We find a projected cross-correlation function of C IV absorption systems and quasars of r{sub 0} = 7.76 {+-} 2.80 Mpc, {gamma} = 1.74 {+-} 0.21. We measure the combined quasar and C IV bias to be b{sub QSO} b{sub C{sub IV}} = 8.81 {+-} 2.28. Using an estimate of b{sub QSO} from the quasar auto-correlation function we find b{sub CIV} = 2.38 {+-} 0.62. This b{sub CIV} implies that EW > 0.28 A C IV absorbers at z {approx} 2.3 are typically found in dark matter halos that have masses {>=}10{sup 11.3}-10{sup 13.4} M{sub Sun} at that redshift. The complete BOSS sample will triple the number of both quasars and absorption systems and increase the power of this cross-correlation measurement by a factor of two.

  6. The thermal reactions of CH{sub 3}

    SciTech Connect

    Lim, K.P.; Michael, J.V.


    The thermal reactions of CH{sub 3}-radicals have been investigated in reflected shock waves experiments at temperatures between 1224--2520 K. The fast dissociation of CH{sub 3}I served as the source of CH{sub 3}. Experiments were performed at three loading pressures with variations in [CH{sub 3}I]{sub 0}. H-atoms formed in the reaction, 2CH{sub 3} {yields} C{sub 2}H{sub 5} + H, were measured by the atomic resonance absorption spectrometric (ARAS) technique. The product ethyl radicals subsequently decompose to give a second H-atom and ethylene. A reaction mechanism was used to fit the data, and the resulting value for the rate constant was 5.25 {times} 10{sup {minus}11} exp({minus}7384 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. This value is compared to earlier determinations. At higher temperatures, 2150--2520 K, the H-atom formation rate was dominated by CH{sub 3} thermal dissociation. With simulations, the rate constant for CH{sub 3} + Kr {yields} CH{sub 2} + H + Kr could be determined. The rate constant for this process is: k = 4.68 {times} 10{sup {minus}9} exp({minus}42506 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. This result is compared to earlier experimental determinations and also to theoretical calculations using the semi-empirical Troe formalism.

  7. Laser flash photolysis studies of radical-radical reaction kinetics: The HO{sub 2} + IO reaction

    SciTech Connect

    Cronkhite, J.M.; Stickel, R.E.; Nicovich, J.M.; Wine, P.H.


    Reactive iodine as a potential tropospheric O{sub 3} sink has received considerable attention recently. Laser flash photolysis of Cl{sub 2}/CH{sub 3}OH/O{sub 2}/I{sub 2}/NO{sub 2}/SF{sub 6}N{sub 2} mixtures at 308 nm has been coupled with simultaneous time-resolved detection of HO{sub 2} (by infrared tunable diode laser absorption spectroscopy) and IO (by visible absorption spectroscopy) to investigate the kinetics of the atmospherically important reaction HO{sub 2} + IO {r_arrow} products over the temperature range 274--373 K in N{sub 2} buffer gas at pressures of 12 and 25 Torr. All experiments were performed under near pseudo-first-order conditions with HO{sub 2} in excess over IO. At 298 K, the rate coefficient was determined to be (9.7 {+-} 2.9) {times} 10{sup {minus}11} cm{sup 3} molecule{sup {minus}1}s{sup {minus}1}, with the primary source of uncertainty being knowledge of the infrared line strength(s) required to convert measured HO{sub 2} absorbances to absolute concentrations. The temperature dependence of the HO{sub 2} + IO rate coefficient was found to be adequately described by the Arrhenius expression k = 9.3 {times} 10{sup {minus}12} exp(680/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. The results reported in this study are compared with other recent studies of HO{sub 2} + IO kinetics, and the potential roles of this reaction in atmospheric chemistry are discussed.

  8. Analysis of the crystal-field spectra of the actinide tetrafluorides. II. AmF[sub 4], CmF[sub 4], Cm[sup 4+]:CeF[sub 4], and Bk[sup 4+]:CeF[sub 4

    SciTech Connect

    Liu, G.K.; Carnall, W.T.; Jursich, G.; Williams, C.W. )


    We report a systematic analysis of the crystal-field spectra of four fluoride compounds containing tetravalent actinide ions. The first part of this work [J. Chem. Phys. [bold 95], 7194 (1991)] provided interpretation of the absorption spectra of UF[sub 4], NpF[sub 4], and PuF[sub 4]. To extend our analysis to heavier elements of the series, low-temperature absorption spectra of AmF[sub 4] and CmF[sub 4], and site selective laser-induced emission and excitation spectra of Cm[sup 4+]:CeF[sub 4] and Bk[sup 4+]:CeF[sub 4] were obtained. A model energy level calculation was found to be in good agreement with the experimental results. It is shown that the crystal-field interaction in combination with spin--orbital coupling results in significant [ital J] mixing in the excited states, but ground state wave functions are still relatively pure in [ital J] character for the tetravalent actinide ions Am[sup 4+], Cm[sup 4+], and Bk[sup 4+]. Trends in the parameters of the effective operator Hamiltonian are compared with those of a Hartree--Fock free-ion model. Interpretation of the ground-state splitting of the nominal [ital S]-state ion Bk[sup 4+] in CeF[sub 4] and color center formation in AmF[sub 4] are also discussed.

  9. Photon burst mass spectrometry for the measurement of {sup 85}Kr at ambient levels

    SciTech Connect

    Fairbank, W.M. Jr.; LaBelle, R.D.; Hansen, C.S.


    Photon Burst Mass Spectrometry has been used to measure {sup 85}Kr in a sample with an abundance of 6 x 10{sup {minus}9}. Improvements in detection efficiency by the use of avalanche photodiodes cooled to liquid nitrogen temperature are reported, which should make possible measurement of {sup 85}Kr at the ambient atmospheric abundance of 10{sup {minus}11}. Potential applications include nuclear monitoring, atmospheric transport, and dating young ground water up to 40 years.

  10. Temperature dependence of the reaction of nitrogen atoms with methyl radicals

    SciTech Connect

    Nava, D.F.; Payne, W.A.; Stief, L.J. ); Nesbitt, F.L. ); Marston, G.


    The discharge-flow mass spectrometry technique has been used to measure the kinetics of the reaction N + CH{sub 3} {yields} products over the temperature range 200-423 K. The results are as follows (10{sup {minus}11} cm{sup 3} s{sup {minus}1}): k{sub 1}(200 K) = (6.4 {plus minus} 2.1), k{sub 1}(298 K) = (8.5 {plus minus} 2.0), k{sub 1}(363 K) = (14 {plus minus} 3.0), and k{sub 1}(423 K) = (17 {plus minus} 5.0). Quoted uncertainties include statistical (95% confidence) and systematic (15%) errors. Interpreting the temperature dependence is difficult, as there is a possibility that the reaction behaves in a non-Arrhenius manner. Possible causes of this behavior are discussed, and comparisons are made with reactions showing similar properties. The results of this study have implications regarding the formation of HCN in the atmosphere of Titan.

  11. Kinetic studies of the reactions of H sub 2 CN and D sub 2 CN radicals with N and H

    SciTech Connect

    Nesbitt, F.L.; Marston, G.; Stief, L.J. )


    Absolute rate constants for the reactions of H{sub 2}CN and D{sub 2}CN with N atoms have been measured by using the discharge flow-mass spectrometry technique between 200 and 363 K. No isotope effect was observed. The results are as follows (10{sup {minus}11} cm{sup 3} s{sup {minus}1}): k{sub 1}(200 K) = 3.9 {plus minus} 2.2, K{sub 1}(298 K) = 4.4 {plus minus} 1.4, k{sub 1}(363 K) = 6.7 {plus minus} 2.0. The reactions of D{sub 2}CN with H and with D atoms were also studied. This study represents the first determination of the rate constants for these reactions. The significance of these processes in models of the atmospheres of Titan and Jupiter and in the chemistry of circumstellar and interstellar clouds is discussed; their role in laboratory experiments on active nitrogen/hydrocarbon reactions is also considered.

  12. Flow barrier system for long-term high-level-waste isolation: Experimental results

    SciTech Connect

    Conca, J.L.; Apted, M.J.; Zhou, W.; Arthur, R.C.; Kessler, J.H.


    A flow barrier system (FBS) that includes a Richards barrier acts in an unsaturated hydrogeologic system to prevent the advective flow of water down through the barrier. Thus, an FBS placed above any solid waste material buried in the unsaturated zone could greatly aid in isolating the waste by keeping the waste away from flowing water. The FBS, consisting of a layer of highly conductive, fine-grained material overlying a sloped gravel layer, is proposed to isolate high-level radioactive waste (HLW) at a candidate disposal facility located in the unsaturated zone at Yucca Mountain in Nevada. A series of laboratory experiments were conducted to (a) assure that the FBS of a specific design can divert the anticipated maximum advective flow (under ideal conditions as well as for the case of a disturbed interface between the two layers caused by, for example, improper initial emplacement or faulting due to seismic activity), (b) investigate water inhibition into the gravel, and (c) measure the diffusion coefficient of the tuff gravel under partially saturated conditions. The main results show that (a) the FBS used in the study can divert point-source flow rates as high as 2.6 {times} 10{sup 5} {ell}/yr; (b) this FBS will continue performing with offsets of the interface as great as 50 cm or more; (c) after 12 months of testing, moisture penetrates the gravel only several grain diameters; and (d) the gravel effective diffusion coefficient is <10{sup {minus}11} cm{sup 2}/s under such low partial saturations. These results indicate that a properly designed FBS can be successful at isolating the HLW under the anticipated range of environmental conditions that exist both now and in the future at Yucca Mountain.

  13. Controlled in situ boron doping of short silicon nanowires grown by molecular beam epitaxy

    SciTech Connect

    Das Kanungo, Pratyush; Zakharov, Nikolai; Bauer, Jan; Breitenstein, Otwin; Werner, Peter; Goesele, Ulrich


    Epitaxial silicon nanowires (NWs) of short heights ({approx}280 nm) on Si <111> substrate were grown and doped in situ with boron on a concentration range of 10{sup 15}-10{sup 19} cm{sup -3} by coevaporation of atomic Si and B by molecular beam epitaxy. Transmission electron microscopy revealed a single-crystalline structure of the NWs. Electrical measurements of the individual NWs confirmed the doping. However, the low doped (10{sup 15} cm{sup -3}) and medium doped (3x10{sup 16} and 1x10{sup 17} cm{sup -3}) NWs were heavily depleted by the surface states while the high doped (10{sup 18} and 10{sup 19} cm{sup -3}) ones showed volume conductivities expected for the corresponding intended doping levels.

  14. Atom trap trace analysis of krypton isotopes

    SciTech Connect

    Bailey, K.; Chen, C. Y.; Du, X.; Li, Y. M.; Lu, Z.-T.; O'Connor, T. P.; Young, L.


    A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

  15. Spectroscopy and reaction kinetics of HCO

    SciTech Connect

    Guo, Yili


    The high-resolution infrared spectrum of the C-H stretching fundamental of HCO has been studied by means of infrared flash kinetic spectroscopy. HCO was generated by flash photolysis of acetaldehyde or formaldehyde using a 308 nm (XeCl) excimer laser. The transient absorption was probed with an infrared difference frequency laser system. The high resolution spectra obtained were assigned and fitted with rotational, spin-rotational, and centrifugal distortion constants. The 1/ band origin is 2434.48 cm/sup /minus/1/. New ground state constants have been derived from a least-squares fit combining the 1/ data with previous microwave and FIR LMR measurements. A new set of spectroscopic constants for the (1, 0, 0) state, the equilibrium rotational constants, and the orientation of the transition dipole moment are also reported. The kinetics and product branching ratios of the HCO + NO/sub 2/ reaction have been studied using visible and infrared laser flash kinetic spectroscopy. The rate constant for the disappearance of HCO radical at 296 K is (5.7 +- 0.9) /times/ 10/sup /minus/11/ cm/sup 3/ molec/sup /minus/1/ sec/sup /minus/1/, and it is independent of the pressure of SF/sub 6/ buffer gas up to 700 torr. Less than 10% of the reaction goes through the most exothermic product channel, HNO + CO/sub 2/. The product channel, H + CO/sub 2/ + NO, is responsible for 52% of the reaction. HONO has been observed, though not quantitatively, as a reaction product corresponding to the HONO + CO channel. 51 refs., 21 figs., 8 tabs.

  16. New magnetic monopole flux limits from the IMB proton decay detector

    SciTech Connect

    Becker-Szendy, R.; Bratton, C.B.; Breault, J.; Casper, D.; Dye, S.T.; Ganezer, K.; Gajewski, W.; Goldhaber, M.; Haines, T.J.; Halverson, P.G.; Kielczewska, D.; Kropp, W.R.; Learned, J.G.; LoSecco, J.; Matsuno, S.; McGrath, G.; McGrew, C.; Miller, R.S.; Price, L.; Reines, F.; Schultz, J.; Sobel, H.W.; Stone, J.L.; Sulak, L.R.; Svoboda, R. |||||||||


    An improved limit on the flux of magnetic monopoles in the vicinity of the solar system is obtained, assuming that monopoles strongly catalyze nucleon decay (the Rubakov-Callan effect). Flux limits are presented for monopole velocities from 10{sup {minus}5}{ital c} to 10{sup {minus}1}{ital c} and for monopole-nucleon cross sections between 10{sup {minus}27} cm{sup 2} and 10{sup {minus}21} cm{sup 2}. For a representative velocity {beta}{approx}10{sup {minus}3}, and cross section {sigma}{approx}10{sup {minus}24} cm{sup 2}, we obtain a limit {ital F}{sub {ital m}}{lt}2.7{times}10{sup {minus}15} cm{sup {minus}2} sr{minus}1 sec {sup {minus}1} and for {sigma}{approx}10{sup {minus}25} cm{sup 2}, {ital F}{sub {ital m}}{lt}1.0{times}10{sup {minus}15} cm{sup {minus}2}sr{sup {minus}1}sec{sup {minus}1} at 90% C.L.

  17. Emission of electrons with energies from 10/sup 4/ to 10/sup 5/ eV upon the fracture of. gamma. -irradiated NaCl crystals

    SciTech Connect

    Khrustalev, Yu.A.; Serdyuk, O.M.; Savenko, V.I.; Bardyshev, I.I.; Deryagin, B.V.


    The influence of gamma quanta (in doses up to 100 Mrd) on the parameters of the emission of high-energy electrons upon the fracture of preliminarily irradiated samples of sodium chloride has been studied. No correlation between the concentration of the F color centers, which is linearly dependent on the dose, and the flux of electrons emitted by the freshly formed surface has been discovered. The appearance of vacancy lattice defects of a type more complicated than F centers upon irradiation has an effect on the process of fracture of the crystal, which results in considerable changes in the parameters of the electrons emitted.

  18. Atom trap trace analysis

    SciTech Connect

    Lu, Z.-T.; Bailey, K.; Chen, C.-Y.; Du, X.; Li, Y.-M.; O'Connor, T. P.; Young, L.


    A new method of ultrasensitive trace-isotope analysis has been developed based upon the technique of laser manipulation of neutral atoms. It has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. The atom counts are free of contamination from other isotopes, elements,or molecules. The method is applicable to other trace-isotopes that can be efficiently captured with a magneto-optical trap, and has a broad range of potential applications.

  19. Possibility of applying a hydrodynamic model to describe the laser erosion of metals irradiated by high-intensity nanosecond pulses

    SciTech Connect

    Kozadaev, K V


    We report the results of experimental investigations of the production and development of plasma-vapour plumes upon irradiation of metal targets by nanosecond (10–100 ns) pulses with a high (10{sup 8}–10{sup 10} W cm{sup -2}) power density under atmospheric conditions. The transition from a quasi-stationary thermal mechanism of metal erosion to an explosion hydrodynamic one takes place when the radiation power density increases from 10{sup 8} to 10{sup 9} W cm{sup -2}. The resultant experimental information is extremely important for the laser deposition of metal nanostructures under atmospheric conditions, which is possible only for power densities of 10{sup 8}–10{sup 9} W cm{sup -2}. (interaction of laser radiation with matter)

  20. A kinetics study of the O({sup 3}P) + CH{sub 3}Cl reaction over the 556-1485 K range by the HTP and LP-ST techniques

    SciTech Connect

    Ko, Taeho; Fontijn, A.; Lim, K.P.; Michael, J.V.


    The high-temperature photochemistry (HTP) and laser photolysis-shock tube (LP-ST) techniques have been combined to study the kinetics of the reaction between ground-state oxygen atoms with CH{sub 3}Cl over the temperature range, 556--1485 K. In the HTP reactor, used for the 556--1291 K range, O atoms were generated by flash photolysis of O{sub 2}, CO{sub 2} or SO{sub 2}, and the atom concentrations were monitored by resonance fluorescence, while with the LP-ST technique, used for the 916--1485 K range, O atoms were generated by the photolysis of either SO{sub 2} or NO with the 193 nm light from a pulsed ArF excimer laser, and atomic resonance absorption spectroscopy (ARAS) was used to monitor [O]{sub t}. In both studies, rate coefficients were derived from the [O] profiles under the pseudo-first-order condition, [O]{much_lt}[CH{sub 3}Cl]. The data obtained by the two techniques are in excellent agreement and are best represented by the expression, k(T) = 2.57 {times} 10{sup {minus}11} (T/K){sup 0.31} exp({minus}5633 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1} with a 2{sigma} precision varying from {plus_minus}6 {plus_minus}22% and an estimated 2{sigma} accuracy of {plus_minus}21% to {plus_minus}30%, depending on temperature. The rate coefficients for the title reaction are essentially identical to those for the O + CH{sub 4} reaction over the observed temperature range, the reasons for which are discussed.

  1. A kinetics study of the O( sup 3 P) + CH sub 3 Cl reaction over the 556-1485 K range by the HTP and LP-ST techniques

    SciTech Connect

    Ko, Taeho; Fontijn, A. . High-Temperature Reaction Kinetics Lab.); Lim, K.P.; Michael, J.V. )


    The high-temperature photochemistry (HTP) and laser photolysis-shock tube (LP-ST) techniques have been combined to study the kinetics of the reaction between ground-state oxygen atoms with CH{sub 3}Cl over the temperature range, 556--1485 K. In the HTP reactor, used for the 556--1291 K range, O atoms were generated by flash photolysis of O{sub 2}, CO{sub 2} or SO{sub 2}, and the atom concentrations were monitored by resonance fluorescence, while with the LP-ST technique, used for the 916--1485 K range, O atoms were generated by the photolysis of either SO{sub 2} or NO with the 193 nm light from a pulsed ArF excimer laser, and atomic resonance absorption spectroscopy (ARAS) was used to monitor (O){sub t}. In both studies, rate coefficients were derived from the (O) profiles under the pseudo-first-order condition, (O){much lt}(CH{sub 3}Cl). The data obtained by the two techniques are in excellent agreement and are best represented by the expression, k(T) = 2.57 {times} 10{sup {minus}11} (T/K){sup 0.31} exp({minus}5633 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1} with a 2{sigma} precision varying from {plus minus}6 {plus minus}22% and an estimated 2{sigma} accuracy of {plus minus}21% to {plus minus}30%, depending on temperature. The rate coefficients for the title reaction are essentially identical to those for the O + CH{sub 4} reaction over the observed temperature range, the reasons for which are discussed.

  2. Boron- and phosphorus-doped polycrystalline silicon thin films prepared by silver-induced layer exchange

    SciTech Connect

    Antesberger, T.; Wassner, T. A.; Jaeger, C.; Algasinger, M.; Kashani, M.; Scholz, M.; Matich, S.; Stutzmann, M.


    Intentional boron and phosphorus doping of polycrystalline silicon thin films on glass prepared by the silver-induced layer exchange is presented. A silver/(titanium) oxide/amorphous silicon stack is annealed at temperatures below the eutectic temperature of the Ag/Si system, leading to a complete layer exchange and simultaneous crystallization of the amorphous silicon. Intentional doping of the amorphous silicon prior to the exchange process results in boron- or phosphorus-doped polycrystalline silicon. Hall effect measurements show carrier concentrations between 2 Multiplication-Sign 10{sup 17} cm{sup -3} and 3 Multiplication-Sign 10{sup 20} cm{sup -3} for phosphorus and 4 Multiplication-Sign 10{sup 18} cm{sup -3} to 3 Multiplication-Sign 10{sup 19} cm{sup -3} for boron-doped layers, with carrier mobilities up to 90 cm{sup 2}/V s.

  3. High-Dose Neutron Detector Development Using 10sup>B Coated Cells

    SciTech Connect

    Menlove, Howard Olsen; Henzlova, Daniela


    During FY16 the boron-lined parallel-plate technology was optimized to fully benefit from its fast timing characteristics in order to enhance its high count rate capability. To facilitate high count rate capability, a novel fast amplifier with timing and operating properties matched to the detector characteristics was developed and implemented in the 8” boron plate detector that was purchased from PDT. Each of the 6 sealed-cells was connected to a fast amplifier with corresponding List mode readout from each amplifier. The FY16 work focused on improvements in the boron-10 coating materials and procedures at PDT to significantly improve the neutron detection efficiency. An improvement in the efficiency of a factor of 1.5 was achieved without increasing the metal backing area for the boron coating. This improvement has allowed us to operate the detector in gamma-ray backgrounds that are four orders of magnitude higher than was previously possible while maintaining a relatively high counting efficiency for neutrons. This improvement in the gamma-ray rejection is a key factor in the development of the high dose neutron detector.

  4. Preliminary design for a standard 10 sup 7 bit Solid State Memory (SSM)

    NASA Technical Reports Server (NTRS)

    Hayes, P. J.; Howle, W. M., Jr.; Stermer, R. L., Jr.


    A modular concept with three separate modules roughly separating bubble domain technology, control logic technology, and power supply technology was employed. These modules were respectively the standard memory module (SMM), the data control unit (DCU), and power supply module (PSM). The storage medium was provided by bubble domain chips organized into memory cells. These cells and the circuitry for parallel data access to the cells make up the SMM. The DCU provides a flexible serial data interface to the SMM. The PSM provides adequate power to enable one DCU and one SMM to operate simultaneously at the maximum data rate. The SSM was designed to handle asynchronous data rates from dc to 1.024 Mbs with a bit error rate less than 1 error in 10 to the eight power bits. Two versions of the SSM, a serial data memory and a dual parallel data memory were specified using the standard modules. The SSM specification includes requirements for radiation hardness, temperature and mechanical environments, dc magnetic field emission and susceptibility, electromagnetic compatibility, and reliability.

  5. The stability of sodalite in the system NaAlSiO sub 4 -NaCl

    SciTech Connect

    Sharp, Z.D. ); Helffrich, G.R. ); Bohlen, S.R. ); Essene, E.J. )


    The reaction sodalite = {beta}-nepheline + NaCl (s) was reversed in solid-medium apparatus and the reaction sodalite = carnegieite + NaCl (l) was reversed at 1 bar (1,649-1,652 K). The experimental reversals between 923 K and 973 K can be fit with a dP/dT of {minus}11 bar/K, suggesting that the excess entropy for sodalite is present only above 923 K. A phase diagram for the NaAlSiO{sub 4}-NaCl system that is consistent with the measured thermochemical data and the experiments between 973 and 1,650 K can be generated if the 61.7 J/mol{center dot}K entropy contribution is included in the S{sup 0}{sub 298} of sodalite. This entropy contribution must be removed below 973 K for the experiments to fit with calculations. Previously unreported thermodynamic data estimated in this study are {Delta}G{sup 0}{sub 298} for sodalite ({minus}12,697 kJ/mol) and carnegieite (NaAlSiO{sub 4}) ({minus}1,958 kJ/mol), S{sup 0}{sub 298} of carnegieite (129.6 J/mol{center dot}K) and compressibility of NaCl{sub liquid} (V{sup P}{sub 298} (cm{sup 3}) = 31.6{center dot}(1 - 24.7{center dot}10{sup {minus}3}{center dot}P + 800{center dot}10{sup {minus}6}{center dot}P{sup 2}))(T in K; P in kbar). Sodalite is a high-temperature, low-pressure phase, stable well above the solidus in sodic silica-undersaturated magmas enriched in NaCl, and its presence constrains NaCl activities in magmas. Estimates of minimum NaCl (l) activities in the Mont St-Hilaire sodalite syenites are 0.05 at 1,073 K and 0.13 at 1,273 K. Density calculations are consistent with the field observations that sodalite phenocrysts will float in a nepheline syenite liquid. This explains the enrichment of sodalite in the upper levels of the sodalite syenites at Mont St.Hilaire and elsewhere.

  6. Temperature Dependent Capacitance-Voltage And Deep Level Transient Spectroscopy Study Of Self-Assembled Ge Quantum Dots Embedded In P-type Silicon

    SciTech Connect

    Rangel-Kuoppa, Victor-Tapio; Chen Gang; Jantsch, Wolfgang


    Temperature dependent Capacitance-Voltage (TCV) and Deep Level Transient Spectroscopy (DLTS) techniques were used to study how Ge Quantum Dots (QDs) embedded in Silicon trap charge. Atomic Force Microscopy (AFM) is used to obtain the density of QDs, which is in the order of 3x10{sup 11} cm{sup -2}. Three shallow levels, with activation energies of 40, 65 and 90 meV, and densities around 10{sup 16} cm{sup -3}, are found and are related to Boron. Four deep levels, with activation energies of 110, 150, 330 and 380 meV, and densities between 2x10{sup 15} cm{sup -3} and 5x10{sup 15} cm{sup -3}, are also found. TCV results suggest they are related to the Ge QDs.

  7. Long term operation of the 100-cm{sup 2} class single cell of MCFC

    SciTech Connect

    Tanimoto, Kazumi; Yanagida, Masahiro; Kojima, Toshikatsu


    The R&D on Molten Carbonate Fuel Cell (MCFC) is proceeding as one of the New Sun Shine Project sponsored by Japanese government. In ONRI (Osaka National Research Institute), the tested MCFCs were assembled with the state-of-the-art components and operated under the load condition for 40000 hours and 34000 hours. We analyzed the performance reduction.

  8. Charge-transfer processes in F{sup 2+}+H{yields}F{sup +}+H{sup +} collisions and the reverse process at low-keV energies

    SciTech Connect

    Dutta, C. M.; Nordlander, P.; Gu, J. P.; Hirsch, G.; Buenker, R. J.; Kimura, M.


    Theoretical investigations on single charge-transfer processes in collisions of F{sup 2+}+H{yields}F{sup +}+H{sup +} and its reverse process have been carried out at collision energies from 20 eV/u to 10 keV/u. The molecular orbital expansion method within the semiclassical impact parameter formalism has been employed for the scattering dynamics, while the ab initio multireference single- and double-excitation configuration interaction (MRD-CI) method was adopted for determination of molecular electronic states. The initial channels correspond to the quintet and triplet states for the corresponding collision processes, respectively. Four molecular states in the quintet manifold and eight molecular states in the triplet manifold were coupled. In the quintet manifold, the charge-transfer cross sections for F{sup 2+}+H{yields}F{sup +}+H{sup +} range from 1.3x10{sup -22} cm{sup 2} at 20 eV/u to 2.5x10{sup -15}cm{sup 2} at 10 keV/u. The cross sections of the reverse process, F{sup +}+H{sup +}{yields}F{sup 2+}+H, range from 3.0x10{sup -22} cm{sup 2}to 2.3x10{sup -15} cm{sup 2} in the same energy range. In the triplet states, the charge-transfer cross sections for F{sup 2+}+H{yields}F{sup +}+H{sup +} range from 1.1x10{sup -18} cm{sup 2} to 2.5x10{sup -16} cm{sup 2}, and its reverse process gives charge-transfer cross sections ranging from 1.7x10{sup -24} cm{sup 2} to 1.5x10{sup -17} cm{sup 2}.

  9. Comparison of the optical parameters of a CaF{sub 2} single crystal and optical ceramics

    SciTech Connect

    Palashov, O V; Khazanov, E A; Mukhin, I B; Mironov, I A; Smirnov, A N; Dukel'skii, K V; Fedorov, Pavel P; Osiko, Vyacheslav V; Basiev, Tasoltan T


    Single crystal and optical ceramic CaF{sub 2} samples are studied by the method of thermally induced depolarisation of laser radiation at 1076 nm. The absorption coefficients of the single crystal and ceramics are estimated as {alpha} < 4.5x10{sup -4} cm{sup -1} and {alpha} < 1.33x10{sup -3} cm{sup -1}, respectively. (letters)

  10. Structural and Optical Properties Studies Of Ar{sup 2+} Ion Implanted Mn Deposited GaAs

    SciTech Connect

    Tripthi, S.; Dubey, R. L.; Dubey, S. K.; Yadav, A. D.


    Mn thin film deposited GaAs samples were implanted with 250 keV Ar{sup +2} ions for various fluences 5x10{sup 15}, 1x10{sup 16} and 5x10{sup 16} ions cm{sup -2}. Optical and structural properties of the samples have been investigated by using ultraviolet spectroscopy and X-ray diffraction techniques. Optical absorbance of the implanted samples was found to decrease with increase in argon ion fluence. XRD spectra of the samples implanted for ion fluences 5x10{sup 15} and 1x10{sup 16} showed the formation of (GaMn)As at 2{theta} value of 65.34 deg. The XRD spectrum of sample 1x10{sup 16} cm{sup -2} annealed at 450 deg. C showed the formation of magnetic phases.

  11. Detection of vacancy defects in gallium arsenide by positron lifetime spectroscopy

    SciTech Connect

    Saarinen, K.; Kuisma, S.; Hautojaervi, P.


    Vacancy-related native defects were studied in semi-insulating GaAs by positron life-time measurements. Both gallium and arsenic vacancies are observed at concentrations of 10{sup 15} - 10{sup 16} cm{sup -3}. The experiments in the dark after illumination manifest the vacancy nature of the metastable state of the EL2 center.

  12. Silicon PM Radiation Hardness

    SciTech Connect

    Rohlf, James


    Detailed measurements have been made of 9 mm2 SiPMs from Hamamatsu (MPPC) and Zecotek (MAPD) after room temperature annealing after exposure to fluences of 10<sup>12 to 10<sup>13 cm>-2. The data was used to complete the final ADR report.



    Balt, R.O.


    A method is described for conducting mechanical operations necessitating the use of a lubricant in a medium operaject to reactor irradiation of 0.5 x 10/ sup 12/ to 1 x 10/sup 12/ neut rons/ cm/sup 2//sec. A thiopolyether lubricant such as 16, 19-dioxa-13, 22-dithiatetratriacontane is used. (AEC)

  14. Collisional-radiative recombination Ar{sup +} + e + e: Experimental study at 77-180 K

    SciTech Connect

    Kotrik, Tomas; Dohnal, Petr; Roucka, Stepan; Jusko, Pavol; Plasil, Radek; Glosik, Juraj; Johnsen, Rainer


    Rate coefficients for collisional-radiative recombination (CRR) of Ar{sup +} ions with electrons have been measured at temperatures from 77 to 180 K in a helium-buffered flowing-afterglow (Cryo-FALP) experiment at electron densities n{sub e} from 10{sup 8} to 10{sup 10} cm{sup -3}. The measured ternary rate coefficient K{sub CRR} at 77 K is (1.1{+-}0.4)x10{sup -17} cm{sup 6}s{sup -1} and the observed variation with temperature agrees well with the theoretical T{sup -4.5} dependence.

  15. P-type conductivity in annealed strontium titanate

    SciTech Connect

    Poole, Violet M.; Corolewski, Caleb D.; McCluskey, Matthew D.


    Hall-effect measurements indicate p-type conductivity in bulk, single-crystal strontium titanate (SrTiO{sub 3}, or STO) samples that were annealed at 1200°C. Room-temperature mobilities above 100 cm{sup 2}/V s were measured, an order of magnitude higher than those for electrons (5-10 cm{sup 2}/V s). Average hole densities were in the 10{sup 9}-10{sup 10} cm{sup −3} range, consistent with a deep acceptor.

  16. Plasma resistivity measurements in the Wisconsin levitated octupole

    SciTech Connect

    Brouchous, D. A.


    Resistivity measurements parallel to the magnetic field were made on gun injected plasmas ranging in density from 10/sup 9/cm/sup -3/ to 10/sup 1/parallelcm/sup -3/ in the Wisconsin levitated octupole with toroidal and poloidal magnetic fields. The 10/sup 9/cm/sup -3/ plasma was collisionless with lambda/sub mfp/ > 100 mirror lengths, had T/sub e/ = 10 eV, T/sub i/ = 30 eV and was found to have anomalous resistivity scaling like eta = ..sqrt..T/sub e//n/sub e/ when E/sub parallel/ > E/su c/ is the Dreicer critical field. The 10/sup 12/cm/sup -3/ plasma was collisional with lambda/sub mfp/ < mirror length, had T/sub e/ = T/sub i/ approx. = .2 eV and was found to have Spitzer resistivity when E/sub parallel/ < E/sub c/.

  17. Transmittance jump in a thin aluminium layer during laser ablation

    SciTech Connect

    Bykovsky, N E; Senatsky, Yu V; Pershin, S M; Samokhin, A A


    A jump in the transmittance (from ∼0.1% to ∼50% for ∼1 ns) of an optical gate on a Mylar film (a thin aluminium layer on a Lavsan substrate) irradiated by nanosecond (10{sup -7} – 10{sup -8} s) pulses of a neodymium laser with an intensity up to 0.1 GW cm{sup -2} has been recorded. The mechanism of a fast (10{sup -10} – 10{sup -11} s) increase in the transmittance of the aluminium layer upon its overheating (without boiling) to the metal – insulator phase-transition temperature is discussed. (interaction of laser radiation with matter. laser plasma)

  18. FALP-MS measurements of dissociative recombination of cyclic and polycyclic hydrocarbons

    SciTech Connect

    Rowe, B.R.; Abouelaziz, H.; Gomet, J.C.; Pasquerault, D.; Canosa, A.; Mitchell, J.B.A.


    Rate coefficients for the dissociative recombination of electrons with the ions C{sub 3}H{sub 3}{sup +}, C{sub 6}H{sub 6}{sup +} and C{sub 10}H{sub 8}{sup +} have been measured using the Flowing Afterglow Langmuir Probe-Mass Spectrometer technique (FALP-MS). Values of 0.7 x 10{sup {minus}6}, 1.0 x 10{sup {minus}6} and 0.3 x 10{sup {minus}3}cm{sup 3}s{sup {minus}1} have been obtained. Studies are continuing on anthracene, C{sub 14}H{sub 10}{sup +}, and will be reported upon.

  19. Determination of 1 x 10/sup -2/-1 x 10/sup 2/ g/dm/sup 3/ hydrazine in aqueous solutions with EPV-1 and EO-01 electrodes

    SciTech Connect

    Dracheva, L.V.


    The corrosion of copper alloy structures in thermal power plants is inhibited by treating aggressive media with highly reductive hydrazine hydrate. The hydrazine combines chemically with oxygen in the coolant used for steam condensation. The present iodometric method for monitoring and controlling high hydrazine levels in the coolant is lengthy, painstaking, and difficult to automate. This paper describes a potentiometric method for this determination and tests the electrochemical and redox behavior of two electrode materials--glass and platinum--in several electrolytes for this purpose. The potentiometric method is also compared to that of iodometry and found to be much more efficient, simple, and automatable.

  20. Frequency Stability of 1x10(sup -13) in a Compensated Sapphire Oscillator Operating Above 77K

    NASA Technical Reports Server (NTRS)

    Dick, G. J.; Santiago, D. G.; Wang, R. T.


    We report on the design and test of a whispering gallery sapphire resonator for which the dominant (WGH(sub n11)) microwave mode family shows frequency-stable, compensated operation for temperatures above 77 kelvin. The resonator makes possible a new ultra-stable oscillator (USO) capability that promises performance improvements over the best available crystal quartz oscillators in a compact cryogenic package.


    SciTech Connect

    Chen, Chian-Chou; Smail, Ian; Ma, Cheng-Jiun; Simpson, James M.; Swinbank, A. Mark; Ivison, Rob J.; Arumugam, Vinodiran; Mortlock, Alice; Dunlop, James S.; Michałowski, Michał J.; Almaini, Omar; Conselice, Christopher J.; Hartley, Will G.; Geach, James E.; Simpson, Chris; Aretxaga, Itziar; Blain, Andrew; Chapman, Scott C.; Farrah, Duncan; Halpern, Mark; and others


    We present multiwavelength identifications for the counterparts of 1088 submillimeter sources detected at 850 μm in the SCUBA-2 Cosmology Legacy Survey study of the UKIRT Infrared Deep Sky Survey-Ultra-Deep Survey (UDS) field. By utilizing an Atacama Large Millimeter Array (ALMA) pilot study on a subset of our bright SCUBA-2 sample as a training set, along with the deep optical–near-infrared (OIR) data available in this field, we develop a novel technique, Optical–IR Triple Color (OIRTC), using z − K, K − [3.6], [3.6] − [4.5] colors to select the candidate submillimeter galaxy (SMG) counterparts. By combining radio identification and the OIRTC technique, we find counterpart candidates for 80% of the Class = 1 ≥ 4σ SCUBA-2 sample, defined as those that are covered by both radio and OIR imaging and the base sample for our scientific analyses. Based on the ALMA training set, we expect the accuracy of these identifications to be 82% ± 20%, with a completeness of 69% ± 16%, essentially as accurate as the traditional p-value technique but with higher completeness. We find that the fraction of SCUBA-2 sources having candidate counterparts is lower for fainter 850 μm sources, and we argue that for follow-up observations sensitive to SMGs with S{sub 850} ≳ 1 mJy across the whole ALMA beam, the fraction with multiple counterparts is likely to be >40% for SCUBA-2 sources at S{sub 850} ≳ 4 mJy. We find that the photometric redshift distribution for the SMGs is well fit by a lognormal distribution, with a median redshift of z = 2.3 ± 0.1. After accounting for the sources without any radio and/or OIRTC counterpart, we estimate the median redshift to be z = 2.6 ± 0.1 for SMGs with S{sub 850} > 1 mJy. We also use this new large sample to study the clustering of SMGs and the far-infrared properties of the unidentified submillimeter sources by stacking their Herschel SPIRE far-infrared emission.

  2. Frequency Stability of 1X10(sup -13) in a Compensated Sapphire Oscillator Operating Above 77 K

    NASA Technical Reports Server (NTRS)

    Santiago, D. G.; Dick, G. J.; Wang, R. T.


    We report on a frequency-stable temperature compensated sapphire oscillator (CSO) at temperatures above 77 K. Previously, high stability in sapphire oscillators had only been obtained with liquid helium cooling.

  3. Portable TXRF Spectrometer with 10{sup -11}g Detection Limit and Portable XRF Spectromicroscope with Sub-mm Spatial Resolution

    SciTech Connect

    Kunimura, Shinsuke; Hatakeyama, So; Sasaki, Nobuharu; Yamamoto, Takashi; Kawai, Jun


    A portable total reflection X-ray fluorescence (TXRF) spectrometer that we have developed is applied to trace elemental analysis of water solutions. Although a 5 W X-ray tube is used in the portable TXRF spectrometer, detection limits of several ppb are achieved for 3d transition metal elements and trace elements in a leaching solution of soils, a leaching solution of solder, and alcoholic beverages are detected. Portable X-ray fluorescence (XRF) spectromicroscopes with a 1 W X-ray tube and an 8 W X-ray tube are also presented. Using the portable XRF spectromicroscope with the 1 W X-ray tube, 93 ppm of Cr is detected with an about 700 {mu}m spatial resolution. Spatially resolved elemental analysis of a mug painted with blue, red, green, and white is performed using the two portable spectromicroscopes, and the difference in elemental composition at each paint is detected.

  4. Recycler ring conceptual design study

    SciTech Connect

    Jackson, G.


    The Tevatron Collider provides the highest center of mass energy collisions in the world. To fully exploit this unique tool, Fermilab is committed to a program of accelerator upgrades for the purpose of increasing the Collider luminosity. Over the past 7 years the luminosity has been increased from a peak of 1.6{times}10{sup 30}cm{sup {minus}2}sec{sup {minus}1} in 1989 to over 3{times}10{sup 31}cm{sup {minus}2}sec{sup {minus}1} during 1995. The Main Injector will supply a larger flux of protons for antiproton production and more intense proton bunches for use in the Collider, and this is expected to increase the peak luminosity to close to 1{times}10{sup 32}cm{sup {minus}2}sec{sup {minus}1}. Further increases in luminosity will require additional upgrades to the Fermilab accelerator complex. This report documents the design of a new fixed-energy storage ring to be placed in the Main Injector tunnel which will provide an initial factor of 2 increase to 2{times}10{sup 32}cm{sup {minus}2}sec{sup {minus}1}, and ultimately provide the basis for an additional order of magnitude luminosity increase up to 1{times}10{sup 33}cm{sup {minus}2}sec{sup {minus}1}.

  5. Neutron-transmuted carbon-14 in neutron-irradiated GaN: Compensation of DX-like center

    SciTech Connect

    Ida, T.; Oga, T.; Kuriyama, K.; Kushida, K.; Xu, Q.; Fukutani, S.


    The transmuted-C related luminescence and net carrier concentration are studied by combining photoluminescence, liquid scintillation, and Raman scattering. GaN single crystal films grown by metalorganic-vapor-phase epitaxy are irradiated with fast and thermal neutrons at fluxes of 3.9 × 10{sup 13} cm{sup −2}s{sup −1} and 8.15 × 10{sup 13} cm{sup −2}s{sup −1}, respectively. Irradiation time is 48 hours. The calculated {sup 72}Ge and {sup 14}C concentrations are 1.24 × 10{sup 18} cm{sup −3} and 1.13 × 10{sup 18} cm{sup −3}, respectively. The transmuted {sup 14}C is detected by the liquid scintillation method to survey β-rays emitted in the process of {sup 14}C decays from {sup 14}N. Tritium ({sup 3}H) is also emitted by a (n,t) reaction of {sup 14}N due to the neutron irradiation above 4.5 MeV. Photoluminescence relating to C, DX-like center of Ge and yellow luminescence band are observed in 1000 °C annealed NTD-GaN. The free electron concentration estimated from Raman scattering is 4.97 × 10{sup 17} cm{sup −3}. This value is lower than that from the transmuted Ge concentration, suggesting the compensation due to the transmuted {sup 14}C acceptors.

  6. Optical evaluation of multichannel radiative transitions originating from {sup 4}G{sub 5/2} level of Sm{sup 3+} in heavy-metal-gallate glasses

    SciTech Connect

    Zhang, J.; Yang, D. L.; Gong, H.; Lin, H.; Pun, E. Y. B.


    Conventional visible and novel infrared (IR) emissions of Sm{sup 3+} in heavy-metal-gallate glasses (Li{sub 2}O-K{sub 2}O-BaO-PbO-Bi{sub 2}O{sub 3}-Ga{sub 2}O{sub 3}, LKBPBG for short) with low phonon energy have been observed. Judd-Ofelt parameters {Omega}{sub 2} (3.00x10{sup -20} cm{sup 2}), {Omega}{sub 4} (5.19x10{sup -20} cm{sup 2}), and {Omega}{sub 6} (1.69x10{sup -20} cm{sup 2}) indicate a higher asymmetry and stronger covalent environment in the optical glasses. For the visible fluorescence bands peaked at 564, 601, 648, and 710 nm, the maximum stimulated emission cross-sections ({sigma}{sub e}) were derived to be 1.35x10{sup -22}, 9.21x10{sup -22}, 9.58x10{sup -22}, and 3.91x10{sup -22} cm{sup 2}, respectively, the values are larger than those in phosphate, oxyfluoroborate, tellurite, and calibo glasses obviously. The observed 1185 nm IR emission lies in the low-loss window of telecommunication system, and the maximum value of {sigma}{sub e} for this band was obtained to be 6.09x10{sup -23} cm{sup 2}. The characterization of multichannel radiative transitions of Sm{sup 3+} in LKBPBG glasses is beneficial in exposing its potential applications in visible and IR optoelectronic devices.

  7. Properties of iron-doped multicrystalline silicon grown by the float-zone technique

    SciTech Connect

    Ciszek, T.F.; Wang, T.H.; Ahrenkiel, R.K.; Matson, R.


    Multicrystalline Fe-doped Si ingots were float-zoned from high-purity feed rods. Fe was introduced by pill-doping, which gives uniform impurity content for small segregation coefficients (k {approximately} 10{sup {minus}5} for Fe in Si). Fe concentrations were calculated from the initial weight of the Fe pill, the molten zone geomet and the growth parameters. Values in the range of 10{sup 12}-10{sup 16} atoms/cm{sup 3} were targeted. No additional electrically active dopants were introduced. Minority charge carrier lifetime (via YAG-laser-excited, 430-MHz ultra-high-frequency-coupled, photoconductive decay) was measured on the ingots, and wafers were cut to examine grain structure and electron-beam-induced current response of grain boundaries. Observed lifetimes decreased monotonically with increasing Fe content for similar grain sizes (from {approximately}10 {mu}s to 2 {mu}s for < 10{sup {minus}3} cm{sup 2} grains, from {approximately}30 {mu}s to 2 {mu}s for {approximately}5 x 10{sup {minus}3} cm{sup 2} grains, and from {approximately}300 {mu}s to 2 {mu}s for > 10{sup {minus}2} cm{sup 2} grains) as the Fe content increased to 1 {times} 10{sup 16} atoms/cm{sup 3}.

  8. Pesticides sensing by surface plasmon resonance

    SciTech Connect

    Kalabina, N.A.; Ksenevich, T.I.; Beloglazov, A.A.; Nikitin, P.I.


    High toxicity of pesticides and their wide use in agriculture, represent a general danger for environmental welfare and could become a real threat to life. Screening of pesticides in the environment has become very important during last years due to low threshold values for pesticides in drinking water. An optical biosensor has been developed for detection of pesticides, based on surface plasmon resonance (SPR) technique. Concentration of the pesticides was measured in liquid or gas. The authors specially originated organic film on a disposable element. A setup on the base of the Kretschmann arrangement was improved by using a computer-controlled angular scanning system. The detection concentration limit of dinitrophenole (DNP) was 10{sup {minus}9} M. Some samples exhibited effect down to 10{sup {minus}11} M of DNP. The results obtained provide reason for further development of SPR sensor as applied to pesticides monitoring.

  9. Processing and evaluation of the AGS Booster ultra-high vaccum system

    SciTech Connect

    Hseuh, H.C.; Mapes, M.; Schnitzenbaumer, P.; Shen, B.; Sikora, R.; Stattel, P.


    The AGS Booster is a synchrotron for the acceleration of both protons and heavy ions. To minimize the beam loss due to charge exchange of the partially stripped, low {Beta} very heavy ions with the residual gas molecules, pressure of low 10{sup {minus}11} Torr is required for the 200 m booster ring. To achieve this ultra high vacuum, chemical cleaning, vacuum furnace degassing and insitu bake were employed for all chambers and beam components. Using these procedures, vacuums of low 10{sup {minus}11} Torr have been routinely achieved during the testing of individual half cells and beam components, and during the commissioning of the vacuum sectors. In this paper, the design and layout of chambers, flanges and bakeout hardware is briefly described. The vacuum processing of different components and the results of bakeout and evaluation are summarized. The experience gained during the construction and commissioning of this ultra-high vacuum system is also given. 3 refs., 3 figs., 1 tab.

  10. AGS proposal: A new search for very rare K{sub L} decays

    SciTech Connect

    Heinson, A.; Molzon, W.R.; Diwan, M.


    The authors propose to carry out a new search for the decays K{sub L} {r_arrow} {mu}e and K{sub L} {r_arrow} ee, building upon the experience and reusing some of the equipment from the recently completed Expt. 791. They also improve the K{sub L} {r_arrow} {mu}{mu} branching ratio measurement. The final E791 single event sensitivity for K{sub L} {r_arrow} {mu}e will be about 1--2 {times} 10{sup {minus}11} (corresponding to a 90% CL limit of roughly 3--5 {times} 10{sup {minus}11}). The new experiment will reach a single event sensitivity below 10{sup {minus}12} and if no events are observed, will set an upper limit of about 2 {times} 10{sup {minus}12}. A few K{sub L} {r_arrow} ee events should be observed, if it occurs at the Standard model level, or more if a new physics process contributes to this decay. About 10,000 K{sub L} {r_arrow} {mu}{mu} decays will also be observed. The experiment will take the novel approach of stopping the neutral beam in a beam stop (or plug) near the upstream end of the spectrometer. A beam test with the beam plug in place will be necessary in the 1991 SEB cycle in order to establish the efficacy of this approach. Another novel feature will be the operation of a tracking detector (probably scintillating fibers) inside the vacuum decay region. The improvements over E791 can be identified as due to: increased beam (approximately a factor of 4, made possible by the Booster), increased acceptance (more than a factor of 2), and improvements in various efficiencies (more than a factor of 2). More precise comparison to E791 is made within this proposal.

  11. Time-resolved electron thermal conduction by probing of plasma formation in transparent solids with high power subpicosecond laser pulses

    SciTech Connect

    Vu, B.T.V.


    This dissertation work includes a series of experimental measurements in a search for better understanding of high temperature (10{sup 4}-10{sup 6}K) and high density plasmas (10{sup 22}-10{sup 24}cm{sup {minus}3}) produced by irradiating a transparent solid target with high intensity (10{sup 13} - 10{sup 15}W/cm{sup 2}) and subpicosecond (10{sup {minus}12}-10{sup {minus}13}s) laser pulses. Experimentally, pump and probe schemes with both frontside (vacuum-plasma side) and backside (plasma-bulk material side) probes are used to excite and interrogate or probe the plasma evolution, thereby providing useful insights into the plasma formation mechanisms. A series of different experiments has been carried out so as to characterize plasma parameters and the importance of various nonlinear processes. Experimental evidence shows that electron thermal conduction is supersonic in a time scale of the first picosecond after laser irradiation, so fast that it was often left unresolved in the past. The experimental results from frontside probing demonstrate that upon irradiation with a strong (pump) laser pulse, a thin high temperature ({approximately}40eV) super-critical density ({approximately}10{sup 23}/cm{sup 3}) plasma layer is quickly formed at the target surface which in turn becomes strongly reflective and prevents further transmission of the remainder of the laser pulse. In the bulk region behind the surface, it is also found that a large sub-critical ({approximately}10{sup 18}/cm{sup 3}) plasma is produced by inverse Bremsstrahlung absorption and collisional ionization. The bulk underdense plasma is evidenced by large absorption of the backside probe light. A simple and analytical model, modified from the avalanche model, for plasma evolution in transparent materials is proposed to explain the experimental results. Elimination of the bulk plasma is then experimentally illustrated by using targets overcoated with highly absorptive films.

  12. Nanostructures from hydrogen implantation of metals.

    SciTech Connect

    McWatters, Bruce Ray; Causey, Rion A.; DePuit, Ryan J.; Yang, Nancy Y. C.; Ong, Markus D.


    This study investigates a pathway to nanoporous structures created by hydrogen implantation in aluminum. Previous experiments for fusion applications have indicated that hydrogen and helium ion implantations are capable of producing bicontinuous nanoporous structures in a variety of metals. This study focuses specifically on hydrogen and helium implantations of aluminum, including complementary experimental results and computational modeling of this system. Experimental results show the evolution of the surface morphology as the hydrogen ion fluence increases from 10{sup 17} cm{sup -2} to 10{sup 18} cm{sup -2}. Implantations of helium at a fluence of 10{sup 18} cm{sup -2} produce porosity on the order of 10 nm. Computational modeling demonstrates the formation of alanes, their desorption, and the resulting etching of aluminum surfaces that likely drives the nanostructures that form in the presence of hydrogen.

  13. Critical oxygen concentration in hydrogenated amorphous silicon solar cells dependent on the contamination source

    SciTech Connect

    Woerdenweber, Jan; Merdzhanova, Tsvetelina; Gordijn, Aad; Stiebig, Helmut; Beyer, Wolfhard


    For hydrogenated amorphous silicon (a-Si:H) solar cells, the critical concentration of a given impurity defines the lowest concentration which causes a decay of solar cell efficiency. Values of 2-5x10{sup 19} cm{sup -3} are commonly found for the critical oxygen concentration (C{sub O}{sup crit}) of a-Si:H. Here we report a dependence of C{sub O}{sup crit} on the contamination source. For state-of-the-art a-Si:H solar cells prepared at the same plasma deposition conditions, we obtain with a (controllable) chamber wall leak C{sub O}{sup crit} approx2x10{sup 19} cm{sup -3} while for a leak in the gas supply line a higher C{sub O}{sup crit} of approx2x10{sup 20} cm{sup -3} is measured. No such dependence is observed for nitrogen.

  14. Permanent optical doping of amorphous metal oxide semiconductors by deep ultraviolet irradiation at room temperature

    SciTech Connect

    Seo, Hyungtak; Cho, Young-Je; Bobade, Santosh M.; Park, Kyoung-Youn; Choi, Duck-Kyun; Kim, Jinwoo; Lee, Jaegab


    We report an investigation of two photon ultraviolet (UV) irradiation induced permanent n-type doping of amorphous InGaZnO (a-IGZO) at room temperature. The photoinduced excess electrons were donated to change the Fermi-level to a conduction band edge under the UV irradiation, owing to the hole scavenging process at the oxide interface. The use of optically n-doped a-IGZO channel increased the carrier density to approx10{sup 18} cm{sup -3} from the background level of 10{sup 16} cm{sup -3}, as well as the comprehensive enhancement upon UV irradiation of a-IGZO thin film transistor parameters, such as an on-off current ratio at approx10{sup 8} and field-effect mobility at 22.7 cm{sup 2}/V s.

  15. Electrical properties of molecular beam epitaxial GaAs grown at 300-450{degrees}C

    SciTech Connect

    Look, D.C.; Robinson, G.D.; Sizelove, J.R.; Stutz, C.E.


    We use the Hall effect and a new charge-transfer technique to study molecular beam epitaxial GaAs grown at the low substrate temperatures of 300-450{degrees}C. Layers grown from 350-450{degrees}C are semi-insulating (resistivity greater than 10{sup 7}{Omega}-cm), as grown, because of an As{sub Ga}-related donor (not EL2) at E{sub c} - 0.65 eV. The donor concentrations are about 2 x 10{sup 18} cm{sup -3} and 2 x 10{sup 17} cm{sup -3} at growth temperatures of 300 and 400{degrees}C, respectively, and acceptor concentrations are about an order of magnitude lower. Relatively high mobilities ({approximately}5000 cm{sup 2}/V s) along with the high resistivities make this material potentially useful for certain device applications. 8 refs., 2 figs., 2 tabs.

  16. Deactivation of krypton atoms in the metastable 5s({sup 3}P{sub 2}) state in collisions with krypton and argon atoms

    SciTech Connect

    Zayarnyi, D A; L'dov, A Yu; Kholin, I V


    The collision deactivation of the metastable 5s[3/2]{sub 2}{sup o}({sup 3}P{sub 2}) state of krypton atoms is studied by the absorption probe method in electron-beam-excited high-pressure Ar-Kr mixtures with a low krypton content. The rate constants of plasma-chemical reactions Kr* + Kr + Ar {yields} Kr{sub 2}* + Ar [(4.1{+-}0.4)x10{sup -33} cm{sup 6} s{sup -1}] and Kr* + 2Ar {yields} ArKr* + Ar (less than 10{sup -35} cm{sup 6} s{sup -1}) are measured for the first time and the rate constant of the reaction Kr* + Ar {yields} products + Ar [(3.8{+-}0.4)x10{sup -15} cm{sup 3} s{sup -1}] is refined. (active media)

  17. A compact laser head with high-frequency stability for Rb atomic clocks and optical instrumentation

    SciTech Connect

    Affolderbach, Christoph; Mileti, Gaetano


    We present a compact and frequency-stabilized laser head based on an extended-cavity diode laser. The laser head occupies a volume of 200 cm{sup 3} and includes frequency stabilization to Doppler-free saturated absorption resonances on the hyperfine components of the {sup 87}Rb D{sub 2} lines at 780 nm, obtained from a simple and compact spectroscopic setup using a 2 cm{sup 3} vapor cell. The measured frequency stability is {<=}2x10{sup -12} over integration times from 1 s to 1 day and shows the potential to reach 2x10{sup -13} over 10{sup 2}-10{sup 5} s. Compact laser sources with these performances are of great interest for applications in gas-cell atomic frequency standards, atomic magnetometers, interferometers and other instruments requiring stable and narrow-band optical sources.

  18. Thomson Scattering at FLASH - Status Report

    SciTech Connect

    Toleikis, S; Bornath, T; Cao, L; Doppner, T; Dusterer, S; Faustlin, R; Forster, E; Fortmann, C; Glenzer, S H; Gode, S; Gregori, G; Holl, A; Irsig, R; Laarmann, T; Lee, H J; Meiwes-Broer, K H; Przystawik, A; Radcliffe, P; Redmer, R; Reinholz, H; Ropke, G; Thiele, R; Tiggesbaumker, J; Truong, N X; Tschentscher, T; Uschmann, I; Zastrau, U


    The basic idea is to implement Thomson scattering with free electron laser (FEL) radiation at near-solid density plasmas as a diagnostic method which allows the determination of plasma temperatures and densities in the warm dense matter (WDM) regime (free electron density of n{sub e} = 10{sup 21}-10{sup 26} cm{sup -3} with temperatures of several eV). The WDM regime [1] at near-solid density (n{sub e} = 10{sup 21}-10{sup 22} cm{sup -3}) is of special interest because, it is where the transition from an ideal plasma to a degenerate, strongly coupled plasma occurs. A systematic understanding of this largely unknown WDM domain is crucial for the modeling and understanding of contemporary plasma experiments, like laser shock-wave or Z-pinch experiments as well as for inertial confinement fusion (ICF) experiments as the plasma evolution follows its path through this domain.

  19. Hot electron generation in a dense plasma by femtosecond laser pulses of subrelativistic intensity

    SciTech Connect

    Bolshakov, V V; Vorob'ev, A A; Uryupina, D S; Ivanov, K A; Morshedian, Nader; Volkov, Roman V; Savel'ev, Andrei B


    We report a study of hot electron generation via the interaction of femtosecond laser pulses of subrelativistic intensity (10{sup 15} to 2x10{sup 17} W cm{sup -2}), having different linear polarisations and nanosecond-scale contrasts, with the surface of 'transparent' (quartz glass) and 'absorbing' (silicon) targets. As the incident pulse intensity increases from 10{sup 15} to 10{sup 17} W cm{sup -2}, the difference in hard X-ray yield and average hot electron energy between s- and p-polarised beams rapidly decreases. This effect can be understood in terms of relativistic electron acceleration mechanisms. (special issue devoted to the 80th birthday of S.A. Akhmanov)

  20. Effect of molarity on properties of spray pyrolysed SnO{sub 2}:F thin films

    SciTech Connect

    Deepu, D. R. Kartha, C. Sudha Vijayakumar, K. P.


    Fluorine doped tin oxide (FTO) thin films were prepared by using automated Chemical Spray Pyrolysis (CSP) machine and the effect of concentration of the precursors on the conductivity and transmittance of the films were studied. The resistivity (ρ) and mobility (μ) are in the range of 10{sup −3}–10{sup −4} Ω-cm and 8.2–13.5 cm{sup 2}V{sup −1}s{sup −1} respectively. The electron density lies between 3.4 × 10{sup 20} and 6.6×10{sup 20} cm{sup −3}. The film transmittance varies between 70 to 80% and the films shows very good reflectivity in the IR-NIR region. Prepared films can be used as transparent electrodes in photo voltaic and optoelectronic devices.

  1. Minority carrier lifetime in iodine-doped molecular beam epitaxy-grown HgCdTe

    SciTech Connect

    Madni, I.; Umana-Membreno, G. A.; Lei, W.; Gu, R.; Antoszewski, J.; Faraone, L.


    The minority carrier lifetime in molecular beam epitaxy grown layers of iodine-doped Hg{sub 1−x}Cd{sub x}Te (x ∼ 0.3) on CdZnTe substrates has been studied. The samples demonstrated extrinsic donor behavior for carrier concentrations in the range from 2 × 10{sup 16} cm{sup −3} to 6 × 10{sup 17} cm{sup −3} without any post-growth annealing. At a temperature of 77 K, the electron mobility was found to vary from 10{sup 4} cm{sup 2}/V s to 7 × 10{sup 3} cm{sup 2}/V s and minority carrier lifetime from 1.6 μs to 790 ns, respectively, as the carrier concentration was increased from 2 × 10{sup 16} cm{sup −3} to 6 × 10{sup 17} cm{sup −3}. The diffusion of iodine is much lower than that of indium and hence a better alternative in heterostructures such as nBn devices. The influence of carrier concentration and temperature on the minority carrier lifetime was studied in order to characterize the carrier recombination mechanisms. Measured lifetimes were also analyzed and compared with the theoretical models of the various recombination processes occurring in these materials, indicating that Auger-1 recombination was predominant at higher doping levels. An increase in deep-level generation-recombination centers was observed with increasing doping level, which suggests that the increase in deep-level trap density is associated with the incorporation of higher concentrations of iodine into the HgCdTe.

  2. Ionic conductivity of Bi{sub 2}Ni{sub x}V{sub 1−x}O{sub 5.5−3x/2} (0.1 ≤ x ≤ 0.2) oxides prepared by a low temperature sol-gel route

    SciTech Connect

    Rusli, Rolan; Patah, Aep Prijamboedi, Bambang Ismunandar; Abrahams, Isaac


    Solid oxides fuel cells (SOFCs) is one technology that could contribute toward future sustainable energy. One of the most important components of an SOFC is the electrolyte, which must have high ionic conductivity. Cation substitution of vanadium in Bi{sub 4}V{sub 2}O{sub 11} yields a family of fast oxide ion conducting solids known collectively as the BIMEVOXes (bismuth metal vanadium oxide), which have the potential to be applied as electrolytes in SOFCs. The purpose of this work is to study the effect of Ni concentration, when used as a dopant, on the ionic conductivity of Bi{sub 2}Ni{sub x}V{sub 1−x}O{sub 5.5−3x/2} (BINIVOX) oxides (0.1 ≤ x ≤ 0.2) when prepared by a sol gel method. The gels were calcined at 600 °C for 24 h to produce pure BINIVOX. These oxides were found to exhibit the γ-phase structure with tetragonal symmetry in space group I4/mmm. Ionic conductivity of BINIVOX at 300 °C were 6.9 × 10{sup −3} S cm{sup −1}, 1.2 × 10{sup −3} S cm{sup −1}, and 8.2 × 10{sup −4} S cm{sup −1}, for x = 0.1; 0.15; and 0.2; respectively; and at 600 °C were 1.1 × 10{sup −1} S cm{sup −1}, 5.3 × 10{sup −2} S cm{sup −1}, and 2.8 ×10{sup −2} S cm{sup −1}, for x = 0.1; 0.15; and 0.2; respectively.

  3. Terahertz emission from p-lnAs due to the instantaneous polarization

    SciTech Connect

    Adomavicius, R.; Urbanowicz, A.; Molis, G.; Krotkus, A.; Satkovskis, E.


    Terahertz radiation from differently doped n- and p-type InAs crystal surfaces was investigated by time-resolved measurement. Large increase of the emitted terahertz power has been observed for p-InAs samples with the p-doping levels of approximately 10{sup 16}-10{sup 17} cm{sup -3}. This increase was explained by a large surface depletion layer and an electric-field-induced optical rectification effect in this layer.

  4. Measurements of the Ultraviolet Fluorescence Cross Sections and Spectra of Bacillus Anthracis Simulants

    SciTech Connect

    Stephens, J.R.


    Measurements of the ultraviolet autofluorescence spectra and absolute cross sections of the Bacillus anthracis (Ba) simulants Bacillus globigii (Bg), Bacillus megaterium (Bm), Bacillus subtilis (Bs), and Bacillus cereus (Bc) were measured. Fluorescence spectra and cross sections of pine pollen (Pina echinata) were measured for comparison. Both dried vegetative cells and spores separated from the sporulated vegetative material were studied. The spectra were obtained by suspending a small number (<10) of particles in air in our Single Particle Spectroscopy Apparatus (SPSA), illuminating the particles with light from a spectrally filtered arc lamp, and measuring the fluorescence spectra of the particles. The illumination was 280 nm (20 nm FWHM) and the fluorescence spectra was measured between 300 and 450 nm. The fluorescence cross section of vegetative Bg peaks at 320 nm with a maximum cross section of 5 X 10{sup -14} cm{sup 2}/sr-nm-particle while the Bg spore fluorescence peaks at 310 nm with peak fluorescence of 8 X 10{sup -15} cm{sup 2}/sr-nm-particle. Pine pollen particles showed a higher fluorescence peaking at 355 nm with a cross section of 1.7 X 10{sup -13} cm{sup 2}/sr-nm-particle. Integrated cross sections ranged from 3.0 X 10{sup -13} for the Bg spores through 2.25 X 10{sup -12} (cm{sup 2}/sr-particle) for the vegetative cells.

  5. Hot Electron Diagnostic in a Solid Laser Target by K-Shell Lines Measurement from Ultra-Intense Laser-Plasma Interactions R=1.06 (micron)m, 3x10 W/cm -2(less than or equal to) 500 J

    SciTech Connect

    Yasuike, K.; Wharton, K.B.; Key, M.; Hatchett, S.; Snavely, R.


    Characterization of hot electron production (a conversion efficiency from laser energy into electrons) from ultra intense laser-solid target interaction by observing molybdenum (Mo) K{beta} as well as K{alpha} emissions from a buried fluorescence tracer layer in the targets has been done. The experiments used 1.06 {micro}m laser light with an intensity of from 2 x 10{sup 18} up to 3 x 10{sup 20} W cm{sup -2} (20-0.5 ps pulse width) and an on target laser energy of 280-500 J. The conversion efficiency from the laser energy into the energy, carried by hot electrons, has been estimated to be {approx}50% for the 0.5 ps shots at an on-target laser intensity of 3 x 10{sup 20} W cm{sup -2}, which increased from {approx}30% at 1 x 10{sup 19} W cm{sup -2} 5 ps shots and {approx} 12% at 2 x 10{sup 18} W cm{sup -2} 20 ps shots.

  6. Kinetics of the gas-phase reactions of NO/sub 3/ radicals with a series of dialkenes, cycloalkenes, and monoterpenes at 295 +/- 1 K

    SciTech Connect

    Atkinson, R.; Aschmann, S.M.; Winer, A.M.; Pitts, J.N. Jr.


    Rate constants for the gas-phase reactions of the NO/sub 3/ radical, an important reactive constituent of nighttime ambient atmospheres, have been determined for the first time for a series of dialkenes, cycloalkenes, and monoterpenes by using a relative rate technique. By use of a rate constant for the reaction of NO/sub 3/ radicals with trans-2-butene of (2.11 +/- 0.24) x 10 /sup -13/ cm/sup 3/ molecule /sup -1/s/sup -1/, the rate constants obtained at 295 +/- 1 K were the following (in cm/sup 3/ molecule/sup -1/s/sup -1/ units): 1,3-butadiene, (5.34 +/- 0.62) x 10/sup -14/; isoprene, (3.23 +/- 0.38) x 10/sup -13/; cyclohexene, (2.87 +/- 0.34) x 10/sup -13/; 1,3-cyclohexadiene, (7.2 +/- 1.7) x 10/sup -12/; 1,4-cyclohexadiene, (2.89 +/- 0.35) x 10/sup -13/; 1,3-cycloheptadiene, (3.8 +/- 0.9) x 10/sup -12/; ..cap alpha..-pinene, (3.4 +/- 0.8) x 10/sup -12/; ..beta..-pinene, (1.4 +/- 0.3) x 10/sup -12/; 3/-carene, (5.9 +/- 1.3) x 10/sup -12/; d-limonene, (7.7 +/- 1.7) x 10/sup -12/. These NO/sub 3/ radical rate constants for the naturally emitted hydrocarbons isoprene and the monoterpenes, in conjunction with measured ambient NO/sub 3/ radical concentrations, show that nighttime reaction with the NO/sub 3/ radical can be an important, if not dominant, loss process for these organics. Similarly, these reactions can also be an important loss process for NO/sub 3/ radicals, and hence for NO/sub x/, during nighttime hours. 43 references.

  7. Methods of enhancing conductivity of a polymer-ceramic composite electrolyte


    Kumar, Binod


    Methods for enhancing conductivity of polymer-ceramic composite electrolytes are provided which include forming a polymer-ceramic composite electrolyte film by a melt casting technique and uniaxially stretching the film from about 5 to 15% in length. The polymer-ceramic composite electrolyte is also preferably annealed after stretching such that it has a room temperature conductivity of from 10.sup.-4 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1. The polymer-ceramic composite electrolyte formed by the methods of the present invention may be used in lithium rechargeable batteries.

  8. Methods of enhancing conductivity of a polymer-ceramic composite electrolyte

    NASA Technical Reports Server (NTRS)

    Kumar, Binod (Inventor)


    Methods for enhancing conductivity of polymer-ceramic composite electrolytes are provided which include forming a polymer-ceramic composite electrolyte film by a melt casting technique and uniaxially stretching the film from about 5 to 15% in length. The polymer-ceramic composite electrolyte is also preferably annealed after stretching such that it has a room temperature conductivity of from 10.sup.-4 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1. The polymer-ceramic composite electrolyte formed by the methods of the present invention may be used in lithium rechargeable batteries.

  9. Handling collision debris in quad- and dipole-first LHC IR options

    SciTech Connect

    Mokhov, N.V.; Rakhno, I.L.; /Fermilab


    Detailed MARS15 Monte Carlo energy deposition calculations are performed for two main designs of the LHC interaction regions (IR) capable to achieve a luminosity of 10{sup 35} cm{sup -2} s{sup -1}: a traditional quadrupole-first scheme and the one with a dual-bore inner triplet with separation dipoles placed in front of the quadrupoles. It is shown that with the appropriate design of the Nb3Sn magnets, IR layout and a number of protective measures implemented, both schemes are feasible for the LHC luminosity upgrade up to 10{sup 35} cm{sup -2} s{sup -1}.

  10. Transient loss of plasma from a theta pinch having an initially reversed magnetic field

    SciTech Connect

    Heidrich, J. E.


    The results of an experimental study of the transient loss of plasma from a 25-cm-long theta pinch initially containing a reversed trapped magnetic field are presented. The plasma, amenable to MHD analyses, was a doubly ionized helium plasma characterized by an ion density N/sub i/ = 2 x 10/sup 16/ cm/sup -3/ and an ion temperature T/sub i/ = 15 eV at midcoil and by N/sub i/ = 0.5 x 10/sup 16/ cm/sup -3/ and T/sub i/ = 6 eV at a position 2.5 cm beyond the end of the theta coil.


    SciTech Connect

    Hunter, Deidre A.; Zahedy, Fakhri; Bowsher, Emily C.; Wilcots, Eric M.; Kepley, Amanda A.; Gaal, Veronika E-mail: E-mail:


    We present large field H I-line emission maps obtained with the single-dish Green Bank Telescope centered on the dwarf irregular galaxies Sextans A, NGC 2366, and WLM. We do not detect the extended skirts of emission associated with the galaxies that were reported from Effelsberg observations. The ratio of H I at 10{sup 19} atoms cm{sup -2} to optical extents of these galaxies is instead 2-3, which is normal for this type of galaxy. There is no evidence for a truncation in the H I distribution {>=}10{sup 19} atoms cm{sup -2}.

  12. Spectrally resolved four-wave mixing experiments on bulk GaAs with 14-fs pulses

    SciTech Connect

    Wehner, M.U.; Steinbach, D.; Wegener, M.; Marschner, T.; Stolz, W.


    We investigate the coherent dynamics at the band edge of GaAs at low temperatures for carrier densities ranging from 4.3{times}10{sup 14} cm{sup {minus}3} to 4.4{times}10{sup 17} cm{sup {minus}3} by means of spectrally resolved transient four-wave mixing with 14-fs pulses. At large nonequilibrium carrier densities we observe oscillations with an energy-dependent oscillation period related to interference among continuum states. The experimental findings are compared with a simple model. This comparison delivers a weak energy dependence of dephasing in the initial buildup phase of screening. {copyright} {ital 1996 Optical Society of America.}

  13. Population inversion in a stationary recombining plasma

    SciTech Connect

    Otsuka, M.


    Population inversion, which occurs in a recombining plasma when a stationary He plasma is brought into contact with a neutral gas, is examined. With hydrogen as a contact gas, noticeable inversion between low-lying levels of H as been found. The overpopulation density is of the order of 10/sup 8/ cm/sup -3/, which is much higher then that (approx. =10/sup 5/ cm/sup -3/) obtained previously with He as a contact gas. Relations between these experimental results and the conditions for population inversion are discussed with the CR model.

  14. Solid composite electrolytes for lithium batteries


    Kumar, Binod; Scanlon, Jr., Lawrence G.


    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a polymer-ceramic composite electrolyte containing poly(ethylene oxide), lithium tetrafluoroborate and titanium dioxide is provided in the form of an annealed film having a room temperature conductivity of from 10.sup.-5 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1 and an activation energy of about 0.5 eV.

  15. Magneto-transport of an electron bilayer system in an undoped Si/SiGe double-quantum-well heterostructure

    SciTech Connect

    Laroche, Dominique; Huang, ShiHsien; Nielsen, Erik; Liu, Chee Wee; Li, Jiun -Yun; Lu, Tzu -Ming


    We report the design, the fabrication, and the magneto-transport study of an electron bilayer system embedded in an undoped Si/SiGe double-quantum-well heterostructure. Additionally, the combined Hall densities (n Hall ) ranging from 2.6 × 10<sup>10sup> cm>-2 to 2.7 × 10<sup>11 cm>-2 were achieved, yielding a maximal combined Hall mobility (μHall ) of 7.7 × 10<sup>5 cm>2/(V • s) at the highest density. Simultaneous electron population of both quantum wells is clearly observed through a Hall mobility drop as the Hall density is increased to nHall > 3.3 × 10<sup>10 sup>cm-2, consistent with Schrödinger-Poisson simulations. Furthermore, the integer and fractional quantum Hall effects are observed in the device, and single-layer behavior is observed when both layers have comparable densities, either due to spontaneous interlayer coherence or to the symmetric-antisymmetric gap.

  16. Effect of residual impurities on transport properties of {beta}-FeSi{sub 2} epitaxial films grown by molecular beam epitaxy

    SciTech Connect

    Terai, Y.; Yoneda, K.; Noda, K.; Miura, N.; Fujiwara, Y.


    Unintentionally doped {beta}-FeSi{sub 2} epitaxial films were grown on silicon-on-insulator substrates by molecular beam epitaxy using a high-purity (5N) Fe source to investigate the effect of residual impurities on the transport properties of {beta}-FeSi{sub 2}. From secondary ion mass spectroscopy analysis, impurities of As, Al, and Mn ({approx}10{sup 17} cm{sup -3}); P and B ({approx}10{sup 16} cm{sup -3}); and Cr and Pb ({approx}10{sup 15} cm{sup -3}) were detected in the epitaxial layer. In Hall measurements at room temperature, the films exhibited n-type conduction with a carrier density of 4-6 Multiplication-Sign 10{sup 16} cm{sup -3} and a Hall mobility of 400-440 cm{sup 2}/Vs. In the temperature (T) dependence of the transport properties, a transition from band conduction to hopping conduction was observed at approximately T = 230 K. At temperatures of 110-150 K, both negative and positive magnetoresistance (MR) were observed depending on the temperature and magnetic field. The MR exhibits mixed conduction of defect band conduction and band conduction in this temperature range.

  17. Amorphous tin-cadmium oxide films and the production thereof

    SciTech Connect

    Li, Xiaonan; Gessert, Timothy A


    A tin-cadmium oxide film having an amorphous structure and a ratio of tin atoms to cadmium atoms of between 1:1 and 3:1. The tin-cadmium oxide film may have an optical band gap of between 2.7 eV and 3.35 eV. The film may also have a charge carrier concentration of between 1.times.10.sup.20 cm.sup.-3 and 2.times.10.sup.20 cm.sup.-3. The tin cadmium oxide film may also exhibit a Hall mobility of between 40 cm.sup.2V.sup.-1 s.sup.-1 and 60 cm.sup.2V.sup.-1 s.sup.-1. Also disclosed is a method of producing an amorphous tin-cadmium oxide film as described and devices using same.

  18. High quality transparent conducting oxide thin films


    Gessert, Timothy A.; Duenow, Joel N.; Barnes, Teresa; Coutts, Timothy J.


    A transparent conducting oxide (TCO) film comprising: a TCO layer, and dopants selected from the elements consisting of Vanadium, Molybdenum, Tantalum, Niobium, Antimony, Titanium, Zirconium, and Hafnium, wherein the elements are n-type dopants; and wherein the transparent conducting oxide is characterized by an improved electron mobility of about 42 cm.sup.2/V-sec while simultaneously maintaining a high carrier density of .about.4.4e.times.10.sup.20 cm.sup.-3.

  19. Linear collider approach to a B anti B factory

    SciTech Connect

    Wilson, P.B.


    In this paper we consider the basic design expression and principal design constraints for a linear collider suitable for a B anti-B factory: Energy approx. =10 GeV, luminosity 10/sup 33/-10/sup 34/ cm/sup -2/s/sup -1/, energy resolution approx. =10/sup -2/. The design of room temperature linear colliders for a B factory is discussed. In such colliders, the rf energy stored in the linac structure is thrown away after each linac pulse. Linear colliders using superconducting rf cavities are considered. Some brief conclusions are presented.

  20. Preliminary performance assessment of the engineered barriers for a low- and intermediate-level radioactive waste repository

    SciTech Connect

    Cho, W.J.; Lee, J.O.; Hahn, P.S.; Chun, K.S.


    Radionuclide release from an engineered barrier in a low- and intermediate-level waste repository is evaluated. The results of experimental studies conducted to determine the radionuclide diffusion coefficients and the hydraulic conductivities of calcium bentonite and crushed granite mixtures are presented. The hydraulic conductivity of the mixture is relatively low even at low dry density and clay content, and the principal mechanism of radionuclide migration through the mixture is diffusion. The measured values of apparent diffusion coefficients in calcium bentonite with a dry density of 1.4 Mg/m{sup 3} are of the order of 10{sup {minus}13} to 10{sup {minus}12} m{sup 2}/s for cations and 10{sup {minus}11} m{sup 2}/s for iodine. These values are similar to those in sodium bentonite. The radionuclide release rates from the engineered barrier composed of the concrete structure and the clay-based backfill were calculated. Carbon-14 and {sup 99}Tc are the important nuclides; however, their maximum release rates are <10{sup {minus}5} GBq/yr. To quantify the effect of uncertainties of input parameters on the radionuclide release rates, Latin Hypercube sampling was used, and the ranges of release rates were estimated statistically with a confidence level of 95%. The uncertainties of the assessment results of the radionuclide release rate are larger in the case of the sorbing nuclides such as {sup 137}Cs. Finally, the sensitivity of the input parameter to release rate is also evaluated.

  1. RF plasma source for heavy ion beam charge neutralization

    SciTech Connect

    Efthimion, Philip C.; Gilson, Erik; Grisham, Larry; Davidson, Ronald C.; Yu, Simon S.; Logan, B. Grant


    Highly ionized plasmas are being used as a medium for charge neutralizing heavy ion beams in order to focus the ion beam to a small spot size. A radio frequency (RF) plasma source has been built at the Princeton Plasma Physics Laboratory (PPPL) in support of the joint Neutralized Transport Experiment (NTX) at the Lawrence Berkeley National Laboratory (LBNL) to study ion beam neutralization with plasma. The goal is to operate the source at pressures {approx} 10{sup -5} Torr at full ionization. The initial operation of the source has been at pressures of 10{sup -4}-10{sup -1} Torr and electron densities in the range of 10{sup 8}-10{sup 11} cm{sup -3}. Recently, pulsed operation of the source has enabled operation at pressures in the 10{sup -6} Torr range with densities of 10{sup 11} cm{sup -3}. Near 100% ionization has been achieved. The source has been integrated with the NTX facility and experiments have begun.

  2. IR laser power transmission through silver halide crystals and polycrystalline fibers

    SciTech Connect

    Nagli, L.; Burstein, D.; Shalem, S.; German, A.


    Laser-induced breakdown (LIB) thresholds in AgC{sub x},Br{sub 1-x} crystals and fibers were studied under CO{sub 2} laser pulsed and CW excitation. The value of LIB threshold P{sub c} of the bulk crystals is about 7.2{center_dot}10{sup 8} W/cm{sup 2} for AgCl and 4{center_dot}10{sup 9} W/cm{sup 2} for AgBr under 60 ns TEA laser excitation. The LIB threshold in fibers is much smaller; about 2{center_dot}10{sup 8} W/cm{sup 2}. The absorption of the crystals at 10.6 {mu}m changes from 8{center_dot}10{sup -5} cm{sup -1} for AgCl to 2{center_dot}10{sup -5 }cm{sup -1} for AgBr; for fibers with the same composition absorption is much greater (3{center_dot}10{sup -4 }cm{sup -1} for AgCl; 2{center_dot}10{sup -4} cm{sup -1} for AgBr). The dependence of the LIB and IR absorption on composition, and mechanical and temperature treatments suggests that the LIB in silver halide crystals and fibers is due to the avalanche electrons in a high electric field. The initial free electrons for this process are supplied by ionization of the cation vacancy - charged dislocation complexes. The relatively lower optical stability of the fibers is due to the increased concentration of defects formed in the hot extrusion of the crystal. A simple thermal annealing method for reduction of the IR absorption is proposed.


    SciTech Connect

    Muccino, M.; Ruffini, R.; Bianco, C. L.; Izzo, L.; Penacchioni, A. V.; Pisani, G. B.


    GRB 090510, observed by both Fermi and AGILE satellites, is the first bright short-hard gamma-ray burst (GRB) with an emission from the keV up to the GeV energy range. Within the Fireshell model, we interpret the faint precursor in the light curve as the emission at the transparency of the expanding e {sup +} e {sup -} plasma: the Proper-GRB. From the observed isotropic energy, we assume a total plasma energy E{sup tot}{sub e{sup +}e{sup -}}=(1.10{+-}0.06) Multiplication-Sign 10{sup 53} erg and derive a Baryon load B = (1.45 {+-} 0.28) Multiplication-Sign 10{sup -3} and a Lorentz factor at transparency {Gamma}{sub tr} = (6.7 {+-} 1.6) Multiplication-Sign 10{sup 2}. The main emission {approx}0.4 s after the initial spike is interpreted as the extended afterglow, due to the interaction of the ultrarelativistic baryons with the CircumBurst Medium (CBM). Using the condition of fully radiative regime, we infer a CBM average spherically symmetric density of (n{sub CBM}) = (1.85 {+-} 0.14) Multiplication-Sign 10{sup 3} particles cm{sup -3}, one of the highest found in the Fireshell model. The value of the filling factor, 1.5 Multiplication-Sign 10{sup -10}{<=}R{<=}3.8 Multiplication-Sign 10{sup -8}, leads to the estimate of filaments with densities n{sub fil} = n{sub CBM}/R approx. (10{sup 6}-10{sup 14}) particles cm{sup -3}. The sub-MeV and the MeV emissions are well reproduced. When compared to the canonical GRBs with (n{sub CBM}) Almost-Equal-To 1 particles cm{sup -3} and to the disguised short GRBs with (n{sub CBM}) Almost-Equal-To 10{sup -3} particles cm{sup -3}, the case of GRB 090510 leads to the existence of a new family of bursts exploding in an overdense galactic region with (n{sub CBM}) Almost-Equal-To 10{sup 3} particles cm{sup -3}. The joint effect of the high {Gamma}{sub tr} and the high density compresses in time and 'inflates' in intensity the extended afterglow, making it appear as a short burst, which we here define as a 'disguised short GRB by excess

  4. Dy{sup 3+}-doped Ga–Sb–S chalcogenide glasses for mid-infrared lasers

    SciTech Connect

    Zhang, Mingjie; Yang, Anping; Peng, Yuefeng; Zhang, Bin; Ren, He; Guo, Wei; Yang, Yan; Zhai, Chengcheng; Wang, Yuwei; Yang, Zhiyong; Tang, Dingyuan


    Highlights: • Novel Ga–Sb–S chalcogenide glasses doped with Dy{sup 3+} ions were synthesized. • The glasses show good thermal stability and excellent infrared transparency. • The glasses show low phonon energy and intense mid-infrared emissions. • The mid-infrared emissions have high quantum efficiency. • The mid-infrared emissions have large stimulated emission cross sections. - Abstract: Novel Ga–Sb–S chalcogenide glasses doped with different amount of Dy{sup 3+} ions were prepared. Their thermal stability, optical properties, and mid-infrared (MIR) emission properties were investigated. The glasses show good thermal stability, excellent infrared transparency, very low phonon energy (∼306 cm{sup −1}), and intense emissions centered at 2.95, 3.59, 4.17 and 4.40 μm. Three Judd–Ofelt intensity parameters (Ω{sub 2} = 8.51 × 10{sup −20} cm{sup 2}, Ω{sub 4} = 2.09 × 10{sup −20} cm{sup 2}, and Ω{sub 6} = 1.60 × 10{sup −20} cm{sup 2}) are obtained, and the related radiative transition properties are evaluated. The high quantum efficiencies and large stimulated emission cross sections of the MIR emissions (88.10% and 1.11 × 10{sup −20} cm{sup 2} for 2.95 μm emission, 75.90% and 0.38 × 10{sup −20} cm{sup 2} for 4.40 μm emission, respectively) in the Dy{sup 3+}-doped Ga–Sb–S glasses make them promising gain materials for the MIR lasers.

  5. Excited-state absorption in the lasing wavelength region of Alexandrite

    SciTech Connect

    Shand, M.L.; Walling, J.C.


    The excited-state absorption cross section sigma/sub 2/ /sub a/ (E) in the gain wavelength region of alexandrite has been determined and is shown to limit the vibronic laser range at both high and low energy. The maximum in vibronic laser emission is due to a minimum in sigma/sub 2/ /sub a/ (E) near 13 000 cm/sup -1/. sigma/sub 2/ /sub a/ (E) is less than 10/sup -20/ cm/sup 2/ between 12 000 and 14 000 cm/sup -1/.

  6. The Structure of Sapphire Implanted with Carbon at Room Temperature and 1000 deg. C

    SciTech Connect

    Alves, E.; Marques, C.; Safran, G.; McHargue, Carl J.


    Carbon was implanted into sapphire at various temperatures as part of a study of the different defect structures produced by a series of light ions. Implantations were made with 150 keV ions to fluences of 1x10{sup 16} and 1x10{sup 17} ions/cm{sup 2} at room temperature (RT) and 1000 deg. C. The defect structures were characterized using Rutherford backscattering-channeling (RBS-C) and transmission electron microscopy (TEM). The RBS-C spectra indicated low residual disorder for RT implantation at 1x10{sup 16} C{sup +}/cm{sup 2}. The de-channeling approached the random value at 1x10{sup 17} C{sup +}/cm{sup 2} and the TEM examination revealed a buried amorphous layer containing embedded sapphire nanocrystals. Damaged layers containing planar defects generally aligned parallel to the surface surrounded this layer. The RBS-C spectra for the sample implanted at 1000 deg. C with 1x10{sup 17} C{sup +}/cm{sup 2} suggested a highly damaged but crystalline surface that was confirmed by TEM micrographs.

  7. Contacts for high-resistivity (Cd,Mn)Te crystals

    SciTech Connect

    Witkowska-Baran, M.; James, R.; Mycielski, A.; Kochanowska, D.; Szadkowski, A.J.; Jakiela, R.; Witkowska, B.; Kaliszek, W.; Domagala, J.; Lusakowska, E.; Domukhovski, V.; Dybko, K.; Cui, Y.; and James, R.B.


    Semi-insulating (Cd,Mn)Te crystals offer a material that may compete well with the commonly used (Cd,Zn)Te crystals for manufacturing large-area X- and gamma-ray detectors. The Bridgman growth method yields good quality, high-resistivity (10{sup 9} - 10{sup 10} {Omega} {center_dot} cm) crystals of (Cd,Mn)Te:V. Doping the as-grown crystals with the compensating agent vanadium ({approx} 10{sup 16} cm{sup -3}) ensures their high resistivity; thereafter, annealing them in cadmium vapors reduces the number of cadmium vacancies. Applying the crystals as detectors necessitates having satisfactory electrical contacts. Accordingly, we explored various techniques of ensuring good electrical contacts to these semi-insulating (Cd,Mn)Te crystals, assessing metallic layers, monocrystalline semiconductor layers, and amorphous (or nanocrystalline) semiconductor layers. We found that ZnTe heavily doped ({approx} 10{sup 18} cm{sup -3}) with Sb, and CdTe heavily doped ({approx} 10{sup 17} cm{sup -3}) with In, proved satisfactory semiconductor contact layers. They subsequently enabled us to establish good contacts (with only narrow tunneling barriers) to the Au layer that usually constitutes the most external contact layer. We outline our technology of applying electrical contacts to semi-insulating (Cd,Mn)Te, and describe some important properties.

  8. Experimental and theoretical evaluation of density sensitive N VII, Ar XIV and Fe XXII line ratios

    SciTech Connect

    Chen, H; Beiersdorfer, P; Heeter, L A; Liedahl, D A; Naranjo-Rivera, K L; Trabert, E; Gu, M F; Lepson, J K


    The line ratios of the 2p-3d transitions in the B-like spectra Ar XIV and Fe XXII have been measured using the electron beam ion traps at Livermore. Radiative-collisional model calculations show these line ratios to be sensitive to the electron density in the ranges ne = 10{sup 10} to 10{sup 12} cm{sup -3} and ne = 10{sup 13} to 10{sup 15} cm{sup -3}, respectively. In our experiment, the electron beam density of about 10{sup 11} cm{sup -3} was varied by about a factor of 5. Our data show a density effect for the line doublet in Ar XIV, and good agreement with theory is found. The relative intensity of the Fe XXII doublet shows good agreement with our predicted low density limit. The N VI K-shell spectrum was used to infer the actual electron density in the overlap region of ion cloud and electron beam, and systematic measurements and calculations of this spectrum are presented as well. The Ar XIV and Fe XXII spectra promise to be reliable density diagnostics for stellar coronae, complementing the K-shell diagnostics of helium-like ions.

  9. Sinterless Formation Of Contacts On Indium Phosphide

    NASA Technical Reports Server (NTRS)

    Weizer, Victor G.; Fatemi, Navid S.


    Improved technique makes it possible to form low-resistivity {nearly equal to 10(Sup-6) ohm cm(Sup2)} electrical contacts on indium phosphide semiconductor devices without damaging devices. Layer of AgP2 40 Angstrom thick deposited on InP before depositing metal contact. AgP2 interlayer sharply reduces contact resistance, without need for sintering.

  10. Surface segregation as a means of gettering Cu in liquid-phase-epitaxy silicon thin layers grown from Al-Cu-Si solutions

    SciTech Connect

    Wang, T.H.; Ciszek, T.F.; Reedy, R.; Asher, S.; King, D.


    The authors demonstrate that, by using the natural surface segregation phenomenon, Cu can be gettered to the surface from the bulk of silicon layers so that its concentrations in the liquid-phase-epitaxy (LPE) layers are much lower than its solubility at the layer growth temperature and the reported 10{sup 17} cm{sup {minus}3} degradation threshold for solar-cell performance. Secondary-ion mass spectroscopy (SIMS) analysis indicates that, within a micron-deep sub-surface region, Cu accumulates even in as-grown LPE samples. Slower cooling after growth to room temperature enhances this Cu enrichment. X-ray photoelectron spectroscopy (XPS) measurement shows as much as 3.2% Cu in a surface region of about 50 {Angstrom}. More surface-sensitive, ion-scattering spectroscopy (ISS) analysis further reveals about 7% of Cu at the top surface. These results translate to an areal gettering capacity of about 1.0 x 10{sup 16} cm{sup {minus}2}, which is higher than the available total-area density of Cu in the layer and substrate (3.6 x 10{sup 15} cm{sup {minus}2} for a uniform 1.2 x 10{sup 17}cm{sup {minus}3} Cu throughout the layer and substrate with a total thickness of 300 {mu}m).

  11. Schottky barrier detection devices having a 4H-SiC n-type epitaxial layer

    SciTech Connect

    Mandal, Krishna C.; Terry, J. Russell


    A detection device, along with methods of its manufacture and use, is provided. The detection device can include: a SiC substrate defining a substrate surface cut from planar to about; a buffer epitaxial layer on the substrate surface; a n-type epitaxial layer on the buffer epitaxial layer; and a top contact on the n-type epitaxial layer. The buffer epitaxial layer can include a n-type 4H--SiC epitaxial layer doped at a concentration of about 1.times.10.sup.15 cm.sup.-3 to about 5.times.10.sup.18 cm.sup.-3 with nitrogen, boron, aluminum, or a mixture thereof. The n-type epitaxial layer can include a n-type 4H--SiC epitaxial layer doped at a concentration of about 1.times.10.sup.13 cm.sup.-3 to about 5.times.10.sup.15 cm.sup.-3 with nitrogen. The top contact can have a thickness of about 8 nm to about 15 nm.


    SciTech Connect

    Tanaka, T.; Abe, K.; Hayato, Y.; Iida, T.; Kameda, J.; Koshio, Y.; Kouzuma, Y.; Miura, M.; Moriyama, S.; Nakahata, M.; Nakayama, S.; Obayashi, Y.; Sekiya, H.; Shiozawa, M.; Suzuki, Y.; Takeda, A.; Takenaga, Y.; Ueno, K.; Ueshima, K.; Yamada, S.; Collaboration: Super-Kamiokande Collaboration; and others


    We present the result of an indirect search for high energy neutrinos from Weakly Interacting Massive Particle (WIMP) annihilation in the Sun using upward-going muon (upmu) events at Super-Kamiokande. Data sets from SKI-SKIII (3109.6 days) were used for the analysis. We looked for an excess of neutrino signal from the Sun as compared with the expected atmospheric neutrino background in three upmu categories: stopping, non-showering, and showering. No significant excess was observed. The 90% C.L. upper limits of upmu flux induced by WIMPs of 100 GeV c{sup -2} were 6.4 Multiplication-Sign 10{sup -15} cm{sup -2} s{sup -1} and 4.0 Multiplication-Sign 10{sup -15} cm{sup -2} s{sup -1} for the soft and hard annihilation channels, respectively. These limits correspond to upper limits of 4.5 Multiplication-Sign 10{sup -39} cm{sup -2} and 2.7 Multiplication-Sign 10{sup -40} cm{sup -2} for spin-dependent WIMP-nucleon scattering cross sections in the soft and hard annihilation channels, respectively.

  13. High-energy high-luminosity µ+ µ- collider design

    SciTech Connect

    Palmer, Robert B.; Fernow, Richard; Gallardo, Juan C.; Lee, Y. Y.; Torun, Yagmur; Neuffer, David; Winn, David


    We discuss the design of a high luminosity (10<sup>35 cm>-2 s-1), high energy (2 + 2 TeV) µ+µ- collider, starting from the proton accelerator needed to generate the muon beams and proceeding through the muon storage ring.

  14. The CDF LEVEL3 trigger

    SciTech Connect

    Carroll, T.; Joshi, U.; Auchincloss, P.


    CDF is currently taking data at a luminosity of 10{sup 30} cm{sup -2} sec{sup -1} using a four level event filtering scheme. The fourth level, LEVEL3, uses ACP (Fermilab`s Advanced Computer Program) designed 32 bit VME based parallel processors (1) capable of executing algorithms written in FORTRAN. LEVEL3 currently rejects about 50% of the events.

  15. Depth uniformity of electrical properties and doping limitation in neutron-transmutation-doped semi-insulating GaAs

    SciTech Connect

    Satoh, M.; Kuriyama, K. ); Kawakubo, T. )


    Depth uniformity of electrical properties has been evaluated for neutron-transmutation-doped (NTD), semi-insulating GaAs irradiated with thermal neutrons of 1.5{times}10{sup 18} cm{sup {minus}2} by the van der Pauw method combined with iterative etching of the surface. In NTD-GaAs wafers (thickness {similar to}410 {mu}m) annealed for 30 min at 700 {degree}C, the depth profiles of the resistivity, the carrier concentration, and the Hall mobility show constant values of 1{times}10{sup {minus}2} {Omega} cm, 2.0{times}10{sup 17} cm{sup {minus}3}, and 3100 cm{sup 2}/V s, respectively, within an experimental error of 5%. In an annealing process, the redistribution and/or the segregation of NTD impurities is not observed. We also discuss the limitations of low-level NTD in semi-insulating GaAs. It is suggested that the activation of the NTD-impurities below {similar to}1{times}10{sup 16} cm{sup {minus}3} is mainly restricted by the presence of the midgap electron trap (EL2).

  16. Current transport in W and WSI{sub x} ohmic contacts to InGaN and InN

    SciTech Connect

    Vartuli, C.B.; Pearton, S.J.; Abernathy, C.R.


    The temperature dependence of the specific contact resistance of W and WSi{sub 0.44} contacts on n{sup +} In{sub 0.65}Ga{sub 0.35}N and InN was measured in the range -50 {degrees}C to 125 {degrees}C. The results were compared to theoretical values for different conduction mechanisms, to further elucidate the conduction mechanism in these contact schemes for all but as-deposited metal to InN where thermionic emission appears to be the dominant mechanism. The contacts were found to produce low specific resistance ohmic contacts to InGaN at room temperature, e{sup c} {approximately} 10{sup -7} {Omega} {center_dot} cm{sup 2} for W and e{sub c} of 4x 10{sup -7} {Omega} {center_dot} cm{sup 2} for WSi{sub x}. InN metallized with W produced ohmic contacts with e{sub c} {approximately} 10{sup -7} {Omega} {center_dot} cm{sup 2} and e{sub c} {approximately} 10{sup -6} {Omega} {center_dot} cm{sup 2} for WSi{sub x} at room temperature.

  17. Method of preparing thin film polymeric gel electrolytes


    Derzon, D.K.; Arnold, C. Jr.


    Novel hybrid thin film electrolyte is described, based on an organonitrile solvent system, which are compositionally stable, environmentally safe, can be produced efficiently in large quantity and which, because of their high conductivities {approx_equal}10{sup {minus}3}{Omega}{sup {minus}1}cm{sup {minus}1} are useful as electrolytes for rechargeable lithium batteries. 1 fig.

  18. Thin film polymeric gel electrolytes


    Derzon, Dora K.; Arnold, Jr., Charles; Delnick, Frank M.


    Novel hybrid thin film electrolyte, based on an organonitrile solvent system, which are compositionally stable, environmentally safe, can be produced efficiently in large quantity and which, because of their high conductivities .apprxeq.10.sup.-3 .OMEGA..sup.-1 cm.sup.-1 are useful as electrolytes for rechargeable lithium batteries.

  19. Thin film polymeric gel electrolytes


    Derzon, D.K.; Arnold, C. Jr.; Delnick, F.M.


    Novel hybrid thin film electrolytes, based on an organonitrile solvent system, which are compositionally stable, environmentally safe, can be produced efficiently in large quantity and which, because of their high conductivities {approx_equal}10{sup {minus}3}{Omega}{sup {minus}1} cm{sup {minus}1} are useful as electrolytes for rechargeable lithium batteries. 1 fig.

  20. Method of preparing thin film polymeric gel electrolytes


    Derzon, Dora K.; Arnold, Jr., Charles


    Novel hybrid thin film electrolyte, based on an organonitrile solvent system, which are compositionally stable, environmentally safe, can be produced efficiently in large quantity and which, because of their high conductivities .apprxeq.10.sup.-3 .OMEGA..sup.-1 cm.sup.-1 are useful as electrolytes for rechargeable lithium batteries.


    SciTech Connect

    Aota, Takuhiro; Aikawa, Yuri; Inoue, Tsuyoshi


    Recent Atacama Large Millimeter/submillimeter Array observations of young protostellar objects detected warm SO emission, which could be associated with a forming protostellar disk. In order to investigate if such warm gas can be produced by accretion shock onto the forming disk, we calculate the sputtering and thermal desorption of various grain-surface species in one-dimensional shock waves. We find that thermal desorption is much more efficient than the sputtering in the post-shock region. While H{sub 2}O can be thermally desorbed, if the accretion velocity is larger than 8 km s{sup –1} with the pre-shock gas number density of 10{sup 9} cm{sup –3}, SO is desorbed if the accretion velocity ≳2 km s{sup –1} and ≳4 km s{sup –1}, with the pre-shock density of 10{sup 9} cm{sup –3} and 10{sup 8} cm{sup –3}, respectively. We also find that the column density of hydrogen nuclei in warm post-shock gas is N {sub warm} ∼ 10{sup 21} cm{sup –2}.


    SciTech Connect

    Edwards, J. L.; Ziurys, L. M.


    Millimeter and sub-millimeter molecular-line observations of planetary nebula (PN) NGC 6537 (Red Spider) have been carried out using the Sub-Millimeter Telescope and the 12 m antenna of the Arizona Radio Observatory in the frequency range 86-692 GHz. CN, HCN, HNC, CCH, CS, SO, H{sub 2}CO, HCO{sup +} and N{sub 2}H{sup +}, along with the J = 3 {yields} 2 and 6 {yields} 5 lines of CO and those of several isotopologues, were detected toward the Red Spider, estimated to be {approx}1600 yr old. This extremely high excitation PN evidently fosters a rich molecular environment. The presence of CS and SO suggest that sulfur may be sequestered in molecular form in such nebulae. A radiative transfer analysis of the CO and CS spectra indicate a kinetic temperature of T{sub K} {approx} 60-80 K and gas densities of n(H{sub 2}) {approx} 1-8 Multiplication-Sign 10{sup 5} cm{sup -3} in NGC 6537. Column densities of the molecules in the nebula and their fractional abundances relative to H{sub 2} ranged from N{sub tot} {approx} 10{sup 16} cm{sup -2} and f {approx} 10{sup -4} for CO, to {approx}7 Multiplication-Sign 10{sup 11} cm{sup -2} and f {approx} 8 Multiplication-Sign 10{sup -9} for the least abundant species, N{sub 2}H{sup +}. For SO and CS, N{sub tot} {approx} 2 Multiplication-Sign 10{sup 12} cm{sup -2} and 10{sup 13} cm{sup -2}, respectively, with f {approx} 10{sup -7} and 2 Multiplication-Sign 10{sup -8}. It was also found that HCN/HNC Almost-Equal-To 2. A low {sup 12}C/{sup 13}C ratio of {approx}4 was measured, indicative of hot-bottom burning. These results, coupled with past observations, suggest that molecular abundances in PNe are governed principally by the physical and chemical properties of the individual object and its progenitor star, rather than nebular age.

  3. Versatile, high-sensitivity faraday cup array for ion implanters


    Musket, Ronald G.; Patterson, Robert G.


    An improved Faraday cup array for determining the dose of ions delivered to a substrate during ion implantation and for monitoring the uniformity of the dose delivered to the substrate. The improved Faraday cup array incorporates a variable size ion beam aperture by changing only an insertable plate that defines the aperture without changing the position of the Faraday cups which are positioned for the operation of the largest ion beam aperture. The design enables the dose sensitivity range, typically 10.sup.11 -10.sup.18 ions/cm.sup.2 to be extended to below 10.sup.6 ions/cm.sup.2. The insertable plate/aperture arrangement is structurally simple and enables scaling to aperture areas between <1 cm.sup.2 and >750 cm.sup.2, and enables ultra-high vacuum (UHV) applications by incorporation of UHV-compatible materials.

  4. Thermal property measurements in a fresh pumice flow at Mt. St. Helens

    SciTech Connect

    Hardee, H.C.


    A thermal penetrator that was air dropped into a freshly emplaced pumice flow at Mt. St. Helens yielded information on the in-situ thermal properties of the pumice. The in-situ conductivity-density-specific heat product at a depth of 60 cm was found to be 7.24 x 10/sup -5/ cal/sup 2/cm//sup 4/ s- /sup 0/C/sup 2/ at an average pumice temperature of 200 /sup 0/C. Using this data, values for the average in-situ thermal conductivity (2.9 x 10/sup -4/ cal/cm-s-/sup 0/C) and thermal diffusivity (1.2 x 10/sup -3/ cm/sup 2//s) were estimated. These thermal properties are of use in studies of pumice cooling and in the interpretation of infrared remote sensing data.

  5. Characterization of Si implantation and annealing of InP by Raman spectroscopy

    SciTech Connect

    Artus, L.; Cusco, R.; Martin, J.M.; Gonzalez-Diaz, G.


    Raman scattering was used to assess the lattice damage caused by Si{sup +} implantation in InP, as well as the lattice recovery achieved after rapid thermal annealing (RTA). Semi-insulating InP was implanted with Si{sup +} with doses in the range of 10{sup 12} to 5 {times} 10{sup 14}cm{sup {minus}2}. Raman scattering measurements show a progressive intensity reduction of the characteristic first- and second-order InP Raman peaks and an enhancement of the disorder activated modes with increasing dose. The onset of amorphization was found to be at about 10{sup 14} cm{sup {minus}2}. RTA of the implanted samples at 875 C for 10s results in a very good recovery of the InP lattice even for the highest dose, as confirmed by Raman scattering measurements.

  6. High-purity, isotopically enriched bulk silicon

    SciTech Connect

    Ager III, J.W.; Beeman, J.W.; Hansen, W.L.; Haller, E.E.; Sharp, I.D.; Liao, C.; Yang, A.; Thewalt, M.L.W.; Riemann, H.


    The synthesis and characterization of dislocation-free, undoped, single crystals of Si enriched in all 3 stable isotopes is reported: {sup 28}Si (99.92%), {sup 29}Si (91.37%), and {sup 30}Si (89.8%). A silane-based process compatible with the relatively small amounts of isotopically enriched precursors that are practically available was used. The silane is decomposed to silicon on a graphite starter rod heated to 700-750 C in a recirculating flow reactor. A typical run produces 35 gm of polycrystalline Si at a growth rates of 5 {micro}m/min and conversion efficiency >95%. Single crystals are grown by the floating zone method and characterized by electrical and optical measurements. Concentrations of shallow dopants (P and B) are as low as mid-10{sup 13} cm{sup -3}. Concentrations of C and O lie below 10{sup 16} and 10{sup 15} cm{sup -3}, respectively.

  7. Electrical Properties of Er-doped In0.53Ga0.47As

    SciTech Connect

    Burke, Peter G.; Lu, Hong; Rudawski, Nicholas G.; Stemmer, Susanne; Gossard, Arthur C.; Bahk, Je-Hyeong; Bowers, John E.


    The electrical properties of In0.53Ga0.47As As thin films Er-doped to concentrations of 1.5×10<sup>17 –7.2×10<sup>20 cm>-3 grown by molecular beam epitaxy at 490 °C on (001) InP substrates were studied. Electrical conductivity, carrier density, and carrier mobility as a function of Er doping were measured by Hall effect at temperatures of 20–750 K. Additionally, high-angle annular dark-field scanning transmission electron microscopy and infrared absorption spectroscopy confirmed the presence of epitaxially embedded ErAs nanoparticles at Er concentrations ≥8×10<sup>19 cm>-3. The observed electrical properties are discussed in terms of the dependence of ErAs nanoparticle formation with Er doping.

  8. Photoelectric and electrical properties of soluble polyphenylquinolines containing an oxygen or phenylamine bridge group between quinoline moieties

    SciTech Connect

    Aleksandrova, E. L.; Svetlychnyi, V. M. Miagkova, L. A.; Nekrasova, T. N.; Tameev, A. R.; Vannikov, A. V.; Kudryavtsev, V. V.


    Photoelectric and electrical properties of polyphenylquinolines differing in the structure of donor bridge groups between quinoline moieties have been studied. It is demonstrated that films of the polymers synthesized exhibit a photosensitivity at the level of 10{sup 5} cm{sup 2} J{sup -1} (integrated sensitivity 5 x 10{sup -4} lx{sup -1} . s{sup -1}), with a quantum yield of carrier photogeneration of 0.07 and a carrier drift mobility on the order of 10{sup -6} cm{sup 2} V{sup -1} s{sup -1}. The fact that the electron and hole drift mobilities in polyphenylquinoline with a phenylamine bridge group are balanced makes the polymer promising for development of film-type devices based on the bipolar conductivity of a material (e.g., single-layer light-emitting diode)

  9. Magnetic trap for thulium atoms

    SciTech Connect

    Sukachev, D D; Sokolov, A V; Chebakov, K A; Akimov, A V; Kolachevskii, N N; Sorokin, Vadim N


    For the first time ultra-cold thulium atoms were trapped in a magnetic quadrupole trap with a small field gradient (20 Gs cm{sup -1}). The atoms were loaded from a cloud containing 4x10{sup 5} atoms that were preliminarily cooled in a magneto-optical trap to the sub-Doppler temperature of 80 {mu}K. As many as 4x10{sup 4} atoms were trapped in the magnetic trap at the temperature of 40 {mu}K. By the character of trap population decay the lifetime of atoms was determined (0.5 s) and an upper estimate was obtained for the rate constant of inelastic binary collisions for spin-polarised thulium atoms in the ground state (g{sub in} < 10{sup -11}cm{sup 3} s{sup -1}). (magnetic traps)

  10. Studies of runaway electron transport in TEXT

    SciTech Connect

    Wang, Pei-Wen.


    The transport of runaway electrons is studied by a plasma position shift experiment and by imposing an externally applied perturbing magnetic field on the edge. The perturbing magnetic field can produce either magnetic islands or, with overlapping islands, a stochastic field. Hard X-ray signals are then measured and compared with analytic and numerical model results. Diffusion coefficients in the edge, {approximately}10{sup 4} cm{sup 2}/sec, and inside the plasma, {approximately}10{sup 2} {minus} 10{sup 3} cm{sup 2}/sec, are estimated. The averaged drift effects are small and the intrinsic magnetic fluctuations are estimated to be < (b{sub r}/B{sub 0}){sup 2} > {approximately}1-{sup {minus}10} at the edge and decreasing inward. Runaway electrons are a good diagnostic of the magnetic fluctuations. It is considered that the magnetic fluctuations have a negligible effect on electron thermal diffusion in the edge plasma.

  11. Thermophysical and gas-dynamic characteristics of laser-induced gasplasma flows under femtosecond laser ablation of titanium in vacuum

    SciTech Connect

    Loktionov, E Yu; Protasov, Yu S; Protasov, Yu Yu


    We report the results of experimental investigation of thermophysical and gas-dynamic characteristics of the gas-plasma flows induced by ultrashort (45 – 60 fs) laser pulse irradiation (the radiation wavelength λ = 400, 800 nm) of a titanium target in vacuum (∼5 × 10{sup -4} mbar). The use of combined interferometric technique and complex experimental data processing allowed us to estimate the momentum coupling coefficient (C{sub m} ∼ 10{sup -4} N W{sup -1}), the efficiency of laser energy conversion to the kinetic energy of the gas-plasma flow (65% – 85%), the spatiotemporal distributions of the particle density (n{sub e} = 10{sup 18} – 10{sup 20} cm{sup -3}) and velocity ((v)=4 – 9 km s{sup -1}), the static (10{sup 6} – 10{sup 8} Pa) and total (10{sup 7} – 10{sup 11} Pa) pressure and temperature (T=7 – 50 kK) in the flow. Our data are compared with published data obtained by other methods. (interaction of laser radiation with matter. laser plasma)

  12. Atriopeptin II stimulates chloride secretion in the isolated operculum epithelium of Fundulus heteroclitus

    SciTech Connect

    Zadunaisky, J.A.; Scheide, J.I.


    Whole killifish efflux of /sup 36/Cl was increased more than 2x with the addition of 1.4 x 10/sup -7/ M atriopeptin (ANF) to the seawater bath. Atriopeptin II (10/sup -7/ M) added serosally to the isolated Fundulus heteroclitus opercular epithelium resulted in a consistent stimulation of the short-circuit current, from 129.5 +/- 12.3 to 153.5 +/- 13.4 2/. Tissue resistance was decreased 10% from 114.9 +/- 14.2 to 103.9 +/- 11.8 Omega x cm/sup 2/ indicating a change in chloride conductance. The effect of ANF was maximal at 10/sup -7/M and mucosal addition of ANF was ineffective in stimulating the opercular current. The ANF current stimulation did not interfere with the isoproterenol (10/sup -6/ M) response but ANF did not stimulate the current if added after isoproterenol. Serosal addition of propranolol (10/sup -5/ M), sufficient to inhibit 10/sup -6/ M isoproterenol, had no effect on the ANF response. The serosal addition of 10/sup -6/ M tetrodotoxin or 10/sup -4/ M diltiazem did not inhibit the ANF response. The stimulatory effect observed by ANF did not involve the isoproterenol receptor or nerve activation; however, it was a distinct stimulatory response on the isolated opercular epithelium.

  13. Study of damage induced by room-temperature Al ion implantation in Hg{sub 0.8}Cd{sub 0.2}Te by x-ray diffuse scattering

    SciTech Connect

    Renault, P.O.; Declemy, A.; Leveque, P.; Fayoux, C.; Bessiere, M.; Lefebvre, S.; Corbel, C.; Baroux, L.


    Ion-implantation is a widely used doping technique in II{endash}VI semiconductors. Nevertheless, ion-implantation damage has to be better understood to properly control this process. In order to investigate the implantation-induced defects in such compounds, room-temperature implantations of 320 keV Al ions have been performed on crystalline samples of [111] Hg{sub 1{minus}x}Cd{sub x}Te (x{approx}20{percent}) for doses ranging from 10{sup 13} to 10{sup 15}cm{sup {minus}2}. We report the first measurements of x-ray diffuse scattering close to different Bragg reflections on such as-implanted samples. The evolution of the diffuse intensity as a function of the dose has been observed. The defect-induced diffuse intensity arises mainly from interstitial dislocation loops. Nevertheless, vacancy loops are observed above 3{times}10{sup 14}Al/cm{sup 2}. The mean radius of the dislocation loops increases in size by three to four times when the dose rises from 10{sup 13} to 10{sup 15}cm{sup {minus}2}. Finally, the saturation of point defects has been observed independently of their clustering at about 5{times}10{sup 13}Al/cm{sup 2}, that is in the same range as the saturation dose of the sheet electron concentration. {copyright} {ital 1997 American Institute of Physics.}

  14. Interface trap density and mobility extraction in InGaAs buried quantum well metal-oxide-semiconductor field-effect-transistors by gated Hall method

    SciTech Connect

    Chidambaram, Thenappan; Madisetti, Shailesh; Greene, Andrew; Yakimov, Michael; Tokranov, Vadim; Oktyabrsky, Serge; Veksler, Dmitry; Hill, Richard


    In this work, we are using a gated Hall method for measurement of free carrier density and electron mobility in buried InGaAs quantum well metal-oxide-semiconductor field-effect-transistor channels. At room temperature, mobility over 8000 cm{sup 2}/Vs is observed at ∼1.4 × 10{sup 12} cm{sup −2}. Temperature dependence of the electron mobility gives the evidence that remote Coulomb scattering dominates at electron density <2 × 10{sup 11} cm{sup −2}. Spectrum of the interface/border traps is quantified from comparison of Hall data with capacitance-voltage measurements or electrostatic modeling. Above the threshold voltage, gate control is strongly limited by fast traps that cannot be distinguished from free channel carriers just by capacitance-based methods and can be the reason for significant overestimation of channel density and underestimation of carrier mobility from transistor measurements.


    SciTech Connect

    Dressler, Alan; McCarthy, Patrick; Martin, Crystal L.; Henry, Alaina; Sawicki, Marcin E-mail:


    We report results of an unprecedentedly deep, blind search for Ly{alpha} emitters (LAEs) at z = 5.7 using the Inamori-Magellan Areal Camera and Spectrograph (IMACS), with the goal of identifying missing sources of reionization that could also be basic building blocks for today's L* galaxies. We describe how improvements in wide field imaging with the Baade telescope, upgrades to IMACS, and the accumulation of {approx}20 hr of integration per field in excellent seeing led to the detection of single-emission-line sources as faint as F {approx} 2 x 10{sup -18} erg s{sup -1} cm{sup -2}, a sensitivity five times deeper than our first search. A reasonable correction for foreground interlopers implies a steep rise of approximately an order of magnitude in source density for a factor of four drop in flux, from F = 10{sup -17.0} erg s{sup -1} cm{sup -2} to F = 10{sup -17.6} (2.5 x 10{sup -18}) erg s{sup -1} cm{sup -2}. At this flux the putative LAEs have reached a surface density of {approx}1 arcmin{sup -2}-a comoving volume density of 4 x 10{sup -3} Mpc{sup -3}, several times the density of L* galaxies today. Such a population of faint LAEs would account for a significant fraction of the critical flux density required to complete reionization at this epoch, and would be good candidates for building blocks of stellar mass {approx}10{sup 8}-10{sup 9} M{sub sun} for the young galaxies of this epoch.

  16. Mechanism for the generation of 10[sup 9] G magnetic fields in the interaction of ultraintense short laser pulse with an overdense plasma target

    SciTech Connect

    Sudan, R.N. )


    The physical mechanism for the generation of very high dc'' magnetic fields in the interaction of ultraintense short laser pulse with an overdense plasma target originates in the spatial gradients and nonstationary character of the ponderomotive force. A set of model equations to determine the evolution of the dc'' fields is derived and it is shown that the dc'' magnetic field is of the same order of magnitude as the high frequency laser magnetic field.

  17. Gold and silver in stream sediments from reconnaissance of 3 x 10/sup 5/ KM/sup 2/ of the western United States

    SciTech Connect

    Van Konynenburg, R.A.; McMillan, G.G.; Higgins, G.H.


    As part of the National Uranium Resource Evaluation (NURE) Program, Lawrence Livermore National Laboratory analyzed about 30,000 stream sediment samples from selected areas of the western United States for numerous chemical elements. The analysis was performed by neutron activation. Data for the concentrations of gold and silver for the samples in which they were detected are presented. Gold was detected in 310 samples, and silver in 19. Latitudes and longitudes are given for the sites from which these samples were taken.

  18. Strong vortex core pinning and Barkhausen-free magnetization response in thin Permalloy disks induced by implantation of 1 × 10{sup 4} Ga{sup +} ions

    SciTech Connect

    Fani Sani, F. E-mail:; Losby, J. E.; Diao, Z.; Parsons, L. C.; Burgess, J. A. J.; Hiebert, W. K.; Freeman, M. R. E-mail:; Vick, D.


    Artificial vortex core pinning sites are induced in thin Permalloy disks by point exposure to as few as 10 000 ions from a focused Ga{sup +} beam. These pinning sites yield a first-order change in the magnetization response of the disk. A single site can keep the vortex core pinned over an applied field range comparable to the vortex annihilation field of the unaltered disk. Several widely separated sites can work together to keep the core pinned in one place, while the Barkhausen effect is eliminated from the magnetization curve over a range approaching the saturation moment of the disk.

  19. Heavy ion collisions with A = 10/sup 57/: Aspects of nuclear stability and the nuclear equation of state in coalescing neutron-star binary systems

    SciTech Connect

    Mathews, G.J.; Wilson, J.R.; Evans, C.R.; Detweiler, S.L.


    The dynamics of the final stages of the coalescence of two neturon stars (such as the binary pulsar PSR 1913+16) is an unsolved problem in astrophysics. Such systems are probably efficient generators of gravitational radiation, and may be significant contributors to heavy-element nucleosynthesis. The input physics for the study of such systems is similar to that required for the strudy of heavy-ion collision hydrodynamics; e.g., a finite temperature nuclear equation of state, properties of nuclei away from stability, etc. We discuss the development of a relativistic hydrodynamics code in three spatial dimensions for the purpose of studying such neutron-star systems. The properties of the mass-radius relation (determined by the nuclear equation of state) may lead to a proposed mechanism by which hot, highly neutronized matter is ejected from the coalescing stars. This material is photodisintegrated into a free (mostly) neutron gas which may subsequently experience rapid-neutron capture (r-process) nucleosynthesis. 15 refs., 4 figs.

  20. Pressure induced polymerization of acetylide anions in CaC 2 and 10 <sup>7 fold enhancement of electrical conductivity

    SciTech Connect

    Zheng, Haiyan; Wang, Lijuan; Li, Kuo; Yang, Youyou; Wang, Yajie; Wu, Jiajia; Dong, Xiao; Wang, Chun-Hai; Tulk, Christopher A.; Molaison, Jamie J.; Ivanov, Ilia N.; Feygenson, Mikhail; Yang, Wenge; Guthrie, Malcolm; Zhao, Yusheng; Mao, Ho-Kwang; Jin, Changqing


    Transformation between different types of carbon–carbon bonding in carbides often results in a dramatic change of physical and chemical properties. Under external pressure, unsaturated carbon atoms form new covalent bonds regardless of the electrostatic repulsion. It was predicted that calcium acetylide (also known as calcium carbide, CaC2) polymerizes to form calcium polyacetylide, calcium polyacenide and calcium graphenide under high pressure. In this work, the phase transitions of CaC2 under external pressure were systematically investigated, and the amorphous phase was studied in detail for the first time. Polycarbide anions like C66- are identified with gas chromatography-mass spectrometry and several other techniques, which evidences the pressure induced polymerization of the acetylide anions and suggests the existence of the polyacenide fragment. Additionally, the process of polymerization is accompanied with a 107 fold enhancement of the electrical conductivity. The polymerization of acetylide anions demonstrates that high pressure compression is a viable route to synthesize novel metal polycarbides and materials with extended carbon networks, while shedding light on the synthesis of more complicated metal organics.


    SciTech Connect

    Savage, B. D.; Narayanan, A.; Wakker, B. P.; Lehner, N.


    Observations of the QSO HE 0153-4520 (z{sub em} = 0.450) with the Cosmic Origins Spectrograph (COS) from 1134 to 1796 A with a resolution of {approx}17 km s{sup -1} and a signal-to-noise ratio per resolution element of 20-40 are used to study a multiphase partial Lyman limit system (LLS) at z = 0.22601 tracing both cool and hot gas. Far-Ultraviolet Spectroscopic Explorer observations of the Lyman limit break yield log N(H I) = 16.61 (0.12, -0.17). The observed UV absorption lines of H I {lambda}{lambda}1216 to 926, C III, C II, N III, N II, Si III, and Si II imply the existence of cool photoionized gas in the LLS with log U = -2.8 {+-} 0.1 and log N(H) = 19.35 {+-} 0.18, log n{sub H} = -2.9 {+-} 0.2, log T = 4.27 {+-} 0.02, log (P/k) = 1.75 {+-} 0.17, and log L (kpc) = 0.70 {+-} 0.25. The abundances are [X/H] = -0.8 (+0.3, -0.2) for N, Si, and C, but the result is sensitive to the assumed shape of the ionizing background radiation field. The multiphase system has strong O VI and associated broad Ly{alpha} absorption (BLA) with log N(O VI) = 14.21 {+-} 0.02, b(O VI) = 37 {+-} 1 km s{sup -1}, log N(H I) = 13.70 (+0.05, -0.08), b(H I) = 140 (+14, -16) km s{sup -1} and b(H I)/b(O VI) = 3.9 {+-} 0.4. The O VI does not arise in the cool photoionized gas of the LLS. The O VI and BLA imply the direct detection of thermally broadened absorption by hot gas with log T = 6.07 (+0.09, -0.12), [O/H] = -0.28 (+0.09, -0.08), and log N(H) = 20.41 (+0.13, -0.17). The absorber probably occurs in the circumgalactic environment (halo) of a foreground galaxy. The very high sensitivity of UV absorption line spectroscopy to O VI and thermally broadened H I Ly{alpha} now permits the direct detection of hot gas with log T > 6, a determination of the abundance of O/H, and log N(H) in low-redshift intergalactic medium absorption line systems.

  2. Fabrication of an infrared bolometer with a high T sub c superconducting thermometer

    SciTech Connect

    Vergjese, S.; Richards, P.L. . Dept. of Physics Lawrence Berkeley Lab., CA ); Char, K.; Sachtjen, S.A. )


    A sensitive high {Tc} superconducting bolometer has been fabricated on a 20 {mu}m thick sapphire substrate with a YBCO thin film transition edge thermometer. Optical measurements with a He-Ne laser gave a noise equivalent power of 2.4{center dot}10{sup {minus}11} W/Hz{sup 1/2} at 10 Hz and a responsivity of 17 V/W in good agreement with electrical bolometer measurements. Gold black smoke was then deposited on the back side of the assembled bolometer as an absorber. Spectral measurements on a Fourier transform spectrometer show that the bolometer has useful sensitivity from visible wavelengths to beyond {approximately}100 {mu}m. This performance is clearly superior to that of a commercial room temperature pyroelectric detector. Some improvement appears possible. 10 refs., 5 figs.

  3. Measurement of the polarization in the decay B{sup 0} {yields} J/{psi}K{sup *0} in {bar p}p collisions at {radical}s = 1.8 TeV

    SciTech Connect

    CDF Collaboration


    This paper reports on the measurement of the polarization in the decay B{sup o} {yields} J/{psi}K{sup *o} using data collected at the collider Detector at Fermilab in {bar p}p collisions at {radical}s = 1.8 TeV. B{sup O} mesons were reconstructed through the decay chain B{sup o} {yields} J/{psi}K{sup *o}, J/{psi} {yields} {mu}{sup +}{mu}{sup {minus}}, K{sup *o} {yields} K{sup +}{pi}{sup {minus}}. A sample of 50 {plus_minus} 11 events was used in the measurement, yielding the result {Gamma}{sub L}/{Gamma} = 0.66 {plus_minus} 0.10 (stat) {sub {minus}}0.10 {sup +0.08} (sys).

  4. Tunable two-mode Cr{sup 2+} : ZnSe laser with a frequency-noise spectral density of 0.03 Hz Hz{sup -1/2}

    SciTech Connect

    Gubin, Mikhail A; Kireev, A N; Kozlovskii, Vladimir I; Korostelin, Yurii V; Pnev, A B; Podmar'kov, Yu P; Tyurikov, D A; Frolov, M P; Shelestov, D A; Shelkovnikov, Aleksandr S


    An optically pumped cw laser on a Cr{sup 2+} : ZnSe crystal with a tunable (in the range of 2.3 - 2 .6 mm) wavelength, operating with generation of two axial modes, has been developed. It is shown that the minimum laser frequency-noise spectral density does not exceed 0.03 Hz Hz{sup -1/2}. Application of this laser in problems of Doppler and Doppler-free spectroscopy makes it possible to detect spectral absorption lines of gases with sensitivities of 5 Multiplication-Sign 10{sup -12} and 2 Multiplication-Sign 10{sup -10} cm{sup -1}, respectively (averaging time {tau} = 1 s). Having stabilised this laser with respect to the Doppler-free resonances of saturated dispersion of methane molecule, one can obtain a short-term frequency stability of 10{sup -15} - 10{sup -16} ({tau} = 1 s).

  5. Constraints on the extremely-high energy cosmic neutrino flux with the IceCube 2008-2009 data

    SciTech Connect

    Abbasi, R.; Aguilar, J. A.; Andeen, K.; Baker, M.; BenZvi, S.; Berghaus, P.; Braun, J.; Chirkin, D.; Desiati, P.; Diaz-Velez, J. C.; Dumm, J. P.; Eisch, J.; Gladstone, L.; Grullon, S.; Halzen, F.; Hill, G. C.; Hoshina, K.; Jacobsen, J.; Karle, A.; Kelley, J. L.


    We report on a search for extremely-high energy neutrinos with energies greater than 10{sup 6} GeV using the data taken with the IceCube detector at the South Pole. The data was collected between April 2008 and May 2009 with the half-completed IceCube array. The absence of signal candidate events in the sample of 333.5 days of live time significantly improves model-independent limits from previous searches and allows to place a limit on the diffuse flux of cosmic neutrinos with an E{sup -2} spectrum in the energy range 2.0x10{sup 6}-6.3x10{sup 9} GeV to a level of E{sup 2{phi}{<=}}3.6x10{sup -8} GeV cm{sup -2} sec{sup -1} sr{sup -1}.

  6. Dielectric behavior of Ar{sup +} implanted CR-39 polymer

    SciTech Connect

    Shekhawat, Nidhi; Sharma, Annu; Aggarwal, Sanjeev; Deshpande, S. K.; Nair, K. G. M.


    The frequency dependent dielectric response of Ar{sup +} implanted CR-39 specimens has been studied. Samples were implanted with 130 keV Ar{sup +} ions to various doses ranging from 5x10{sup 14} to 1x10{sup 16} cm{sup -2}. The frequency response of dielectric constant (e) and dielectric loss has been studied both in the pristine and argon ion implanted samples of CR-39 polymer in the frequency range 10{sup 4} to 10{sup 8} Hz. Structural changes produced in CR-39 specimens due to implantation have been studied using Attenuated total reflectance (ATR) Fourier transform infrared spectroscopic technique. Results of dielectric analysis indicate the lowering in dielectric constant ({epsilon}') and similar behavior of dielectric loss with increase in ion fluence. An attempt has been made to correlate these changes produced in the dielectric properties of implanted specimens with the structural changes produced due to implantation.

  7. Study of transport properties with relativistic ponderomotive effect in two-electron temperature plasma

    SciTech Connect

    Sen, Sonu Dubey, A.; Varshney, Meenu Asthana; Varshney, Dinesh


    In the present paper we make an analytical investigation to study transport properties with relativistic ponderomotive effect in two-electron temperature plasma. Using fluid model the two-electron temperature are introduced through relativistic ponderomotive force for the transportation of two species of electrons. Applying WKB and paraxial ray approximation the nonlinear dielectric constant and self-focusing equation is evaluated and analyzed with experimental relevance. Numerical calculations are made for different concentration of electron density (10{sup 19}−10{sup 21} per cm{sup 3}) at arbitrary values of laser intensity in the range 10{sup 18}−10{sup 21} W/cm{sup 2}. For a minimum radius depending on the initial conditions it is oscillating between a minimum and maximum value. The hot electrons leading to the increase of the on-axis transportation and favorable effect on relativistic self-focusing.

  8. Open-circuit voltage, fill factor, and efficiency of a CdS/CdTe solar cell

    SciTech Connect

    Kosyachenko, L. A. Grushko, E. V.


    The dependences of the open-circuit voltage, fill factor, and efficiency of the thin-film CdS/CdTe solar cell on the resistivity {rho} and carrier lifetime {tau} in the absorbing CdTe layer were studied. In the common case in which the uncompensated acceptor concentration and the electron lifetime in the CdTe layer are within 10{sup 15}-10{sup 16} cm{sup -3} and 10{sup -10}-10{sup -9} s, the calculation results correspond to the achieved efficiency of the best thin-film CdS/CdTe solar cells. It was shown that, by decreasing {rho} and increasing {tau} in the absorbing CdTe layer, the open-circuit voltage, fill factor, and efficiency can be substantially increased, with their values approaching the theoretical limit for such devices.

  9. Low energy Mott polarimetry of electrons from negative electron affinity photocathodes

    SciTech Connect

    Ciccacci, F.; De Rossi, S.; Campbell, D.M.


    We present data on the spin polarization {ital P} and quantum yield {ital Y} of electrons photoemitted from negative electron affinity semiconductors, including GaAs(100), GaAsP(100) alloy, and strained GaAs layer epitaxially grown on a GaAsP(100) buffer. Near photothreshold the following values for {ital P}({ital Y}) are, respectively, obtained: 26% (2.5{times}10{sup {minus}2}), 40% (1{times}10{sup {minus}3}), and 60% (1.5{times}10{sup {minus}4}). We describe in detail the apparatus used containing a low energy (10--25 keV) Mott polarimeter. The system, completely fitted in a small volume ({similar_to}10{sup 4} cm{sup 3}) ultrahigh vacuum chamber, is intended as a test facility for characterizing candidate photocathode materials for spin polarized electron sources. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  10. Neutrino emissivity from e sup minus synchrotron and e sup minus e+ annihilation processes in a strong magnetic field: General formalism and nonrelativistic limit

    SciTech Connect

    Kaminker, A.D.; Levenfish, K.P.; Yakovlev, D.G. ); Amsterdamski, P.; Haensel, P. )


    A general formalism is developed for calculating the neutrino emissivities of synchrotron and {ital e}{sup {minus}}{ital e+} annihilation radiations in a plasma in the presence of a large magnetic field {ital B}{similar to}10{sup 12}--10{sup 14} G. As a first step, the formalism is used to calculate the synchrotron and annihilation radiations from a nonrelativistic electron plasma (density {rho}{approx lt}10{sup 6} g cm{sup {minus}3}, temperature {ital T}{approx lt}6{times}10{sup 9} K) including the cases of nondegenerate and degenerate electrons, and of quantizing and nonquantizing magnetic fields. We conclude that these processes can be important for neutrino production in a hot plasma of neutron star envelopes.

  11. Influence of radiation defects on electrical losses in silicon diodes irradiated with electrons

    SciTech Connect

    Poklonski, N. A. Gorbachuk, N. I.; Shpakovski, S. V.; Lastovskii, S. B.; Wieck, A.


    Silicon diodes with a p{sup +}-n junction irradiated with 3.5-MeV electrons (the fluence ranged from 10{sup 15} to 4 x 10{sup 16} cm{sup -2}) have been studied. It is established that the dependence of the tangent of the angle of electrical losses tan{delta} on the frequency f of alternating current in the range f = 10{sup 2}-10{sup 6} Hz is a nonmonotonic function with two extrema: a minimum and a maximum. Transformation of the dependences tan{delta}(f) as the electron fluence and annealing temperature are increased is caused by a variation in the resistance of n-Si (the base region of the diodes) as a result of accumulation (as the fluence is increased) or disappearance and reconfiguration (in the course of annealing) of radiation defects. The role of time lag of the defect recharging in the formation of tan{delta}(f) is insignificant.

  12. Magnetic-field generation by pulsed irradiation of aluminium in air

    SciTech Connect

    Chumakov, A N; Chekan, P V


    Magnetic-field generation arising under irradiation of an aluminium barrier in the air by a series of laser pulses is studied experimentally. It is found that the magnetic field increases nonlinearly from 10{sup -5} to 10{sup -3} T with increasing laser power density from 10{sup 7} to 10{sup 9} W cm{sup -2}, the degree of nonlinearity being different for single nanosecond pulses, for a series of such pulses with a repetition rate of 100 – 150 μs and for a combination of a millisecond laser pulse and a series of nanosecond laser pulses. The dependences of the magnetic-field induction on the power density of laser radiation in the above-mentioned regimes are established. (interaction of laser radiation with matter)


    SciTech Connect

    Lockman, Felix J.; Free, Nicole L.; Shields, Joseph C.


    The Green Bank Telescope has been used to search for 21 cm H I emission over a large area between the galaxies M31 and M33 in an attempt to confirm at 9.'1 angular resolution the detection by Braun and Thilker of a very extensive neutral gas 'bridge' between the two systems at the level N{sub HI} Almost-Equal-To 10{sup 17} cm{sup -2}. We detect H I emission at several locations up to 120 kpc in projected distance from M31, at least half the distance to M33, with velocities similar to that of the galaxies, confirming the essence of the Braun and Thilker discovery. The H I does not appear to be associated with the extraplanar high-velocity clouds of either galaxy. In two places we measure N{sub HI} > 3 Multiplication-Sign 10{sup 18} cm{sup -2}, indicative of concentrations of H I with {approx}10{sup 5} M{sub Sun} on scales {approx}< 2 kpc, but over most of the field we have only 5{sigma} upper limits of N{sub HI} {<=} 1.4 Multiplication-Sign 10{sup 18} cm{sup -2}. In very deep measurements in two directions H I lines were detected at a few 10{sup 17} cm{sup -2}. The absence of emission at another location to a 5{sigma} limit N{sub HI} {<=} 1.5 Multiplication-Sign 10{sup 17} cm{sup -2} suggests that the H I bridge is either patchy or confined to within {approx}125 kpc of M31. The measurements also cover two of M31's dwarf galaxies, And II and And XV, but in neither case is there evidence for associated H I at the 5{sigma} level of 1.4 Multiplication-Sign 10{sup 4} M{sub Sun} for And II and 9.3 Multiplication-Sign 10{sup 3} M{sub Sun} for And XV.

  14. Spectroscopic studies of magnesium plasma produced by fundamental and second harmonics of Nd:YAG laser

    SciTech Connect

    Haq, S. U. Ahmat, L.; Mumtaz, M.; Nadeem, A.; Shakeel, Hira; Mahmood, S.


    In the present experimental work, laser induced magnesium plasma has been characterized using plasma parameters. The plasma has been generated by the fundamental (1064 nm) and second harmonics (532 nm) of Nd:YAG laser. The plasma parameters such as electron temperature and electron number density have been extracted using Boltzmann plot method and Stark broadened line profile, respectively. The laser irradiance dependence and spatial behavior of electron temperature and number density in laser induced magnesium plasma have been studied. The electron temperature as a function of laser irradiance (0.5 to 6.5 GW/cm{sup 2}) ranges from (9.16–10.37) × 10{sup 3 }K and (8.5–10.1)× 10{sup 3 }K, and electron number density from (0.99–1.08) × 10{sup 16} cm{sup −3} and (1.04–1.22) × 10{sup 16}cm{sup −3} for 1064 and 532 nm, respectively. These parameters exhibit fast increase at low laser irradiance and slow increase at high irradiance. The spatial distribution of electron temperature and electron number density shows same decreasing trend up to 2.25 mm from the target surface. The electron temperature and number density decrease from (9.5–8.6) × 10{sup 3 }K, (1.27–1.15) × 10{sup 16}cm{sup −3} and (10.56–8.85)× 10{sup 3 }K, (1.08–0.99) × 10{sup 16} cm{sup −3} for 532 nm and 1064 nm laser ablation wavelengths, respectively.


    SciTech Connect

    Haggard, Daryl; Cool, Adrienne M.; Heinke, Craig O.; Van der Marel, Roeland; Anderson, Jay; Cohn, Haldan N.; Lugger, Phyllis M. E-mail:


    We report a sensitive X-ray search for the proposed intermediate-mass black hole (IMBH) in the massive Galactic cluster, {omega} Centauri (NGC 5139). Combining Chandra X-ray Observatory data from Cycles 1 and 13, we obtain a deep ({approx}291 ks) exposure of the central regions of the cluster. We find no evidence for an X-ray point source near any of the cluster's proposed dynamical centers, and place an upper limit on the X-ray flux from a central source of f{sub X}(0.5-7.0 keV) {<=}5.0 Multiplication-Sign 10{sup -16} erg cm{sup -2} s{sup -1}, after correcting for absorption. This corresponds to an unabsorbed X-ray luminosity of L{sub X}(0.5-7.0 keV) {<=}1.6 Multiplication-Sign 10{sup 30} erg s{sup -1}, for a cluster distance of 5.2 kpc, Galactic column density N{sub H} = 1.2 Multiplication-Sign 10{sup 21} cm{sup -2}, and power-law spectrum with {Gamma} = 2.3. If a {approx}10{sup 4} M{sub sun} IMBH resides in the cluster's core, as suggested by some stellar dynamical studies, its Eddington luminosity would be L{sub Edd} {approx}10{sup 42} erg s{sup -1}. The new X-ray limit would then establish an Eddington ratio of L{sub X}/L{sub Edd} {approx}< 10{sup -12}, a factor of {approx}10 lower than even the quiescent state of our Galaxy's notoriously inefficient supermassive black hole Sgr A*, and imply accretion efficiencies as low as {eta} {approx}< 10{sup -6}-10{sup -8}. This study leaves open three possibilities: either {omega} Cen does not harbor an IMBH or, if an IMBH does exist, it must experience very little or very inefficient accretion.

  16. Vacuum surface flashover: A high-pressure phenomenon

    SciTech Connect

    Gray, E.W.


    Desorbed gases from insulator surfaces may be much more important in flashover initiation than properties of the dielectric surface. Ambient neutral densities, immediately above the insulator surface, in the initial stages of flashover have been calculated to lie in the range from 2 x 10/sup 17//cm/sup 3/ to 2 x 10/sup 21//cm/sup 3/ with a mean of about 1 x 10/sup 19//cm/sup 3/, whether flashover occurred on surfaces in air at atmospheric pressure or in vacuum as low as 10/sup -6/ Torr. The evidence presented indicates that, for dc and microsecond pulse voltages, surface flashover is a local, relatively high-pressure phenomenon. Comparison of field strengths of surface flashover for various insulating materials perpendicular to the electrodes, operating pressures, and voltage waveforms appears to indicate that flashover values range well within an order of magnitude (approx.18--80kV/cm). A filamentary nature of the flashover discharge is shown and is consistent with gas breakdown phenomena. Ionization wave front velocities are examined and these compare favorably with those obtained from gaseous breakdown studies.

  17. Electron and ion reactions with hexamethyldisiloxane and pentamethyldisiloxane

    SciTech Connect

    Carles, S.; Le Garrec, J. L.; Mitchell, J. B. A.


    The dissociative recombination of electrons with the hexamethyldisiloxane (HMDSO) cation ((CH{sub 3}){sub 3}Si-O-Si(CH{sub 3}){sub 3}){sup +} and the pentamethyldisiloxane cation ((CH{sub 3}){sub 3}Si-O-Si(CH{sub 2}){sub 2}){sup +} as well as the ion-molecule reaction between Ar{sup +} and HMDSO have been studied at 300 K using a flowing afterglow Langmuir probe-mass spectrometer apparatus. The rate constants for these reactions, measured directly for the first time, are, respectively, {alpha}{sub 1}=1.8x10{sup -6}, {alpha}{sub 2}=3.6x10{sup -6} cm{sup 3}/s, and k=2.0x10{sup -9} cm{sup 3}/s with uncertainties of {+-}30%. In addition, the electronic attachment to neutral HMDSO was also studied and an upper limit value of the rate constant was determined to be {beta}=3.3x10{sup -11} cm{sup 3}/s.

  18. The CH + CO reaction: Rate coefficient for carbon atom exchange at 294 K

    SciTech Connect

    Anderson, S.M.; McCurdy, K.E.; Kolb, C.E. )


    A fast-flow reactor equipped with isotope-specific laser-excited fluorescence detection of CH radicals has been used to study carbon atom exchange in the reaction between CH and CO at 294 K and 2 Torr of total pressure. The rate coefficient for exchange, k{sub 3} = (2.1 {times} 0.3) {times} 10{sup {minus}12} cm{sup 3} s{sup {minus}1}, is about an order of magnitude larger than the bimolecular rate for the addition reaction, k{sub 2} = (2.7 {plus minus} 0.4) {times} 10{sup {minus}13}. High-pressure limiting bimolecular and low-pressure termolecular recombination rate coefficients of 1.1 {times} 10{sup {minus}10} cm{sup 3} s{sup {minus}1} and 4.9 {times} 10{sup {minus}30} cm{sup 6} s{sup {minus}1} are derived. The results are discussed in the context of previous work on the title reaction and on the chemistry of singlet CH{sub 2}.

  19. Results from the first use of low radioactivity argon in a dark matter search

    SciTech Connect

    Agnes, P.


    Liquid argon is a bright scintillator with potent particle identification properties, making it an attractive target for direct-detection dark matter searches. The DarkSide-50 dark matter search here reports the first WIMP search results obtained using a target of low-radioactivity argon. DarkSide-50 is a dark matter detector, using two-phase liquid argon time projection chamber, located at the Laboratori Nazionali del Gran Sasso. The underground argon is shown to contain Ar-39 at a level reduced by a factor (1.4 +- 0.2) x 10<sup>3 relative to atmospheric argon. We report a background-free null result from (2616 +- 43) kg d of data, accumulated over 70.9 live-days. When combined with our previous search using an atmospheric argon, the 90 % C.L. upper limit on the WIMP-nucleon spin-independent cross section based on zero events found in the WIMP search regions, is 2.0 x 10<sup>-44 cm>2 (8.6 x 10<sup>-44 cm>2, 8.0 x 10<sup>-43 cm>2) for a WIMP mass of 100 GeV/c2 (1 TeV/c2 , 10 TeV/c2).

  20. Magneto-optical trap for metastable helium at 389 nm

    SciTech Connect

    Koelemeij, J.C.J.; Stas, R.J.W.; Hogervorst, W.; Vassen, W.


    We have constructed a magneto-optical trap (MOT) for metastable triplet helium atoms utilizing the 2 {sup 3}S{sub 1}{yields}3 {sup 3}P{sub 2} line at 389 nm as the trapping and cooling transition. The far-red-detuned MOT (detuning {delta}=-41 MHz) typically contains few times 10{sup 7} atoms at a relatively high ({approx}10{sup 9} cm{sup -3}) density, which is a consequence of the large momentum transfer per photon at 389 nm and a small two-body loss rate coefficient (2x10{sup -10} cm{sup 3}/s<{beta}<1.0x10{sup -9} cm{sup 3}/s). The two-body loss rate is more than five times smaller than in a MOT on the commonly used 2 {sup 3}S{sub 1}{yields}2 {sup 3}P{sub 2} line at 1083 nm. Furthermore, laser cooling at 389 nm results in temperatures somewhat lower than those achieved using 1083 nm. The 389-nm MOT exhibits small losses due to two-photon ionization, which have been investigated as well.

  1. Polymer-based solar cells having an active area of 1.6 cm{sup 2} fabricated via spray coating

    SciTech Connect

    Scarratt, N. W.; Griffin, J.; Zhang, Y.; Lidzey, D. G.; Wang, T.; Yi, H.; Iraqi, A.


    We demonstrate the fabrication of polymer solar cells in which both a PEDOT:PSS hole transport and a PCDTBT:PC{sub 71}BM photoactive layer are deposited by spray-casting. Two device geometries are explored, with devices having a pixel area of 165 mm{sup 2} attaining a power conversion efficiency of 3.7%. Surface metrology indicates that the PEDOT:PSS and PCDTBT:PC{sub 71}BM layers have a roughness of 2.57 nm and 1.18 nm over an area of 100 μm{sup 2}. Light beam induced current mapping reveals fluctuations in current generation efficiency over length-scales of ∼2 mm, with the average photocurrent being 75% of its maximum value.

  2. Anomalous effects in the character of the carbonyl absorption (ca. 1700 cm/sup -1/) in the infrared spectra of petroleum resins and asphaltenes

    SciTech Connect

    Speight, J.G.; Moschopedis, S.E.


    The presence of the carbonyl functional groups in asphaltenes and resins were detected by ir spectroscopy following saponification. By following the spectra through a reaction sequence, the bituminous extracts from fresh oil sands showed the presence of esters and carboxylic acids. The extracts from a hot water process showed either carboxylic acids or esters. 1 figure, 2 tables.

  3. Two proton-conductive hybrids based on 2-(3-pyridyl)benzimidazole molecules and Keggin-type heteropolyacids

    SciTech Connect

    Wei, Mei-Lin Wang, Yu-Xia; Wang, Xin-Jun


    Two proton-conductive organic/inorganic complexes were constructed by Keggin-type heteropolyacids and 2-(3-pyridyl)benzimidazole molecules. Single-crystal X-ray diffraction analyses revealed that two complexes crystallized in the monoclinic space group P2{sub 1}/c, exhibited different unit cell parameters, and presented different hydrogen-bonded networks constructed by 2-(3-pyridyl)benzimidazole molecules, [PMo{sub 12}O{sub 40}]{sup 3−} anions and solvent molecules. The results of thermogravimetric analyses suggest that two supramolecular complexes have different thermal stability based on the different hydrogen-bonded networks. Two complexes at 100 °C under 35–98% relative humidity showed a good proton conductivity of about 10{sup −3} S cm{sup −1}. The proton conductivities of two complexes under 98% relative humidity both increase on a logarithmic scale with temperature range from 25 to 100 °C. At 100 °C, both complexes showed poor proton conductivities of 10{sup −8}–10{sup −9} S cm{sup −1} under acetonitrile or methanol vapor. - Graphical abstract: Two molecular hybrids constructed by Keggin-type heteropolyacids and 2-(3-pyridyl)benzimidazole molecules showed good proton conductivities of 10{sup −3} S cm{sup −1} at 100 °C under 35–98% relative humidity. Display Omitted - Highlights: • 2-(3-Pyridyl)benzimidazole could form hydrogen bonds via the N–H groups. • Heteropolyacids have suitable characteristics to be used excellent proton conductors. • Two proton-conductive hybrids based on Keggin HPAs and 3-PyBim were constructed. • The structures were determined by using single-crystal X-ray diffraction data. • They showed good proton conductivities of 10{sup −3} S cm{sup −1} at 100 °C under 35–98% RH.

  4. Helium measurements of pore-fluids obtained from SAFOD drillcore

    SciTech Connect

    Ali, S.; Stute, M.; Torgersen, T.; Winckler, G.; Kennedy, B.M.


    {sup 4}He accumulated in fluids is a well established geochemical tracer used to study crustal fluid dynamics. Direct fluid samples are not always collectable; therefore, a method to extract rare gases from matrix fluids of whole rocks by diffusion has been adapted. Helium was measured on matrix fluids extracted from sandstones and mudstones recovered during the San Andreas Fault Observatory at Depth (SAFOD) drilling in California, USA. Samples were typically collected as subcores or from drillcore fragments. Helium concentration and isotope ratios were measured 4-6 times on each sample, and indicate a bulk {sup 4}He diffusion coefficient of 3.5 {+-} 1.3 x 10{sup -8} cm{sup 2}s{sup -1} at 21 C, compared to previously published diffusion coefficients of 1.2 x 10{sup -18} cm{sup 2}s{sup -1} (21 C) to 3.0 x 10{sup -15} cm{sup 2}s{sup -1} (150 C) in the sands and clays. Correcting the diffusion coefficient of {sup 4}He{sub water} for matrix porosity ({approx}3%) and tortuosity ({approx}6-13) produces effective diffusion coefficients of 1 x 10{sup -8} cm{sup 2}s{sup -1} (21 C) and 1 x 10{sup -7} (120 C), effectively isolating pore fluid {sup 4}He from the {sup 4}He contained in the rock matrix. Model calculations indicate that <6% of helium initially dissolved in pore fluids was lost during the sampling process. Complete and quantitative extraction of the pore fluids provide minimum in situ porosity values for sandstones 2.8 {+-} 0.4% (SD, n=4) and mudstones 3.1 {+-} 0.8% (SD, n=4).

  5. Progress in Antiproton Production at the Fermilab Tevatron Collider

    SciTech Connect

    Pasquinelli, Ralph J.; Drendel, Brian; Gollwitzer, Keith; Johnson, Stan; Lebedev, Valeri; Leveling, Anthony; Morgan, James; Nagaslaev, Vladimir; Peterson, Dave; Sondgeroth, Alan; Werkema, Steve; /Fermilab


    Fermilab Collider Run II has been ongoing since 2001. During this time peak luminosities in the Tevatron have increased from approximately 10 x 10{sup 30} cm{sup -2}sec{sup -1} to 300 x 10{sup 30} cm{sup 02}sec{sup -1}. A major contributing factor in this remarkable performance is a greatly improved antiproton production capability. Since the beginning of Run II, the average antiproton accumulation rate has increased from 2 x 10{sup 10}{anti p}/hr to about 24 x 10{sup 10}{anti p}/hr. Peak antiproton stacking rates presently exceed 28 x 10{sup 10}{anti p}/hr. The antiproton stacking rate has nearly doubled since 2005. It is this recent progress that is the focus of this paper. The process of transferring antiprotons to the Recycler Ring for subsequent transfer to the collider has been significantly restructured and streamlined, yielding additional cycle time for antiproton production. Improvements to the target station have greatly increased the antiproton yield from the production target. The performance of the Antiproton Source stochastic cooling systems has been enhanced by upgrades to the cooling electronics, accelerator lattice optimization, and improved operating procedures. In this paper, we will briefly report on each of these modifications.

  6. Multichannel transition emissions of Dy{sup 3+} in fiber-adaptive germanium tellurite glasses

    SciTech Connect

    Li, Y. H.; Chen, B. J.; Lin, H.; Pun, E. Y. B.


    Multichannel transition visible and near-infrared (NIR) fluorescences have been captured in Dy{sup 3+}-doped fiber-adaptive Na{sub 2}O-ZnO-PbO-GeO{sub 2}-TeO{sub 2} glasses. The maximum stimulated emission cross-sections {sigma}{sub em-max} were derived to be 0.33 Multiplication-Sign 10{sup -21}, 3.66 Multiplication-Sign 10{sup -21}, and 0.67 Multiplication-Sign 10{sup -21} cm{sup 2} for conventional visible emissions assigned to {sup 4}F{sub 9/2}{yields}{sup 6}H{sub J} (J = 15/2, 13/2, and 11/2) transitions, respectively. Infrequent multi-peak NIR emissions were recorded in the spectral range of 900-1500 nm, among which the values of {sigma}{sub em-max} were solved to be 1.05 Multiplication-Sign 10{sup -22} and 1.56 Multiplication-Sign 10{sup -22} cm{sup 2} for {approx}1.02 and {approx}1.18 {mu}m emission bands. Internal quantum efficiency for the {sup 4}F{sub 9/2} level and external quantum yield for visible emissions of Dy{sup 3+} were determined to be 88.44% and 12.38%, severally. Effective multichannel radiative emissions reveal a potential in developing fiber-lighting sources, tunable lasers, and NIR optical amplifiers.

  7. Stratospheric HBr mixing ratio obtained from far infrared emission spectra

    SciTech Connect

    Park, J.H. ); Carli, B. ); Barbis, A. )


    Emission features of HBr isotopes have been identified in high-resolution far-infrared emission spectra obtained with a balloon-born Fourier transform spectrometer in the spring of 1979 at 32{degree}N latitude. When six single-scan spectra at a zenith angle of 93.2{degree} were averaged, two features of HBr isotopes at 50.054 and 50.069 cm{sup {minus}1} were obtained with a signal-to-noise ratio of 2.5. The volume mixing ratio retrieved from the average spectrum is 2.0 {times} 10{sub {minus}11}, which is assumed to be constant above 28 km, with an uncertainty of 35%. This stratospheric amount of HBr is about the same as the current level of tropospheric organic bromine compounds, 25 pptv. Thus, HBr could be the major stratospheric bromine species.

  8. Electron attachment to MoF{sub 6}, ReF{sub 6}, and WF{sub 6}; reaction of MoF{sub 6}{sup -} with ReF{sub 6} and reaction of Ar{sup +} with MoF{sub 6}

    SciTech Connect

    Friedman, Jeffrey F.; Stevens, Amy E.; Miller, Thomas M.; Viggiano, A.A.


    Rate constants were measured for electron attachment to MoF{sub 6}, ReF{sub 6}, and WF{sub 6} in 133 Pa of helium gas using a flowing-afterglow Langmuir-probe apparatus. The experiment is a thorny one because the molecules tend to form oxide impurities on feedline surfaces and because of thermal decomposition of MoF{sub 6} on surfaces as the gas temperature is increased. The electron attachment rate constant for MoF{sub 6} is (2.3{+-}0.8)x10{sup -9} cm{sup 3} s{sup -1} at 297 K; only MoF{sub 6}{sup -} is formed in the temperature range of 297-385 K. The rate constant increases with temperature up to the point where decomposition becomes apparent. Electron attachment to ReF{sub 6} occurs with a rate constant of (2.4{+-}0.8)x10{sup -9} cm{sup 3} s{sup -1} at 297 K; only ReF{sub 6}{sup -} is produced. MoF{sub 6}{sup -} reacts with ReF{sub 6} to form ReF{sub 6}{sup -} on essentially every collision, showing definitively that the electron affinity of ReF{sub 6} is greater than that of MoF{sub 6}. A rate constant of (5.0{+-}1.3)x10{sup -10} cm{sup 3} s{sup -1} was measured for this ion-molecule reaction at 304 K. The reverse reaction is not observed. The reaction of Ar{sup +} with MoF{sub 6} was found to produce MoF{sub 5}{sup +}+F, with a rate constant of (1.8{+-}0.5)x10{sup -9} cm{sup 3} s{sup -1}. WF{sub 6} attaches electrons so slowly at room temperature that the attachment rate was below detection level ({<=}10{sup -12} cm{sup 3} s{sup -1}). By 552 K, the attachment rate constant reaches a value of (2{+-}1)x10{sup -10} cm{sup 3} s{sup -1}.


    SciTech Connect

    LaMassa, Stephanie M.; Urry, C. Megan; Ananna, Tonima; Civano, Francesca; Marchesi, Stefano; Pecoraro, Robert; Cappelluti, Nico; Comastri, Andrea; Brusa, Marcella; Böhringer, Hans; Chon, Gayoung; Glikman, Eilat; Richards, Gordon; Cardamone, Carie; Farrah, Duncan; Gilfanov, Marat; Green, Paul; Komossa, S.; Lira, Paulina; Makler, Martin; and others


    We release the next installment of the Stripe 82 X-ray survey point-source catalog, which currently covers 31.3 deg{sup 2} of the Sloan Digital Sky Survey (SDSS) Stripe 82 Legacy field. In total, 6181 unique X-ray sources are significantly detected with XMM-Newton (>5σ) and Chandra (>4.5σ). This catalog release includes data from XMM-Newton cycle AO 13, which approximately doubled the Stripe 82X survey area. The flux limits of the Stripe 82X survey are 8.7 × 10{sup −16} erg s{sup −1} cm{sup −2}, 4.7 × 10{sup −15} erg s{sup −1} cm{sup −2}, and 2.1 × 10{sup −15} erg s{sup −1} cm{sup −2} in the soft (0.5–2 keV), hard (2–10 keV), and full bands (0.5–10 keV), respectively, with approximate half-area survey flux limits of 5.4 × 10{sup −15} erg s{sup −1} cm{sup −2}, 2.9 × 10{sup −14} erg s{sup −1} cm{sup −2}, and 1.7 × 10{sup −14} erg s{sup −1} cm{sup −2}. We matched the X-ray source lists to available multi-wavelength catalogs, including updated matches to the previous release of the Stripe 82X survey; 88% of the sample is matched to a multi-wavelength counterpart. Due to the wide area of Stripe 82X and rich ancillary multi-wavelength data, including coadded SDSS photometry, mid-infrared WISE coverage, near-infrared coverage from UKIDSS and VISTA Hemisphere Survey, ultraviolet coverage from GALEX, radio coverage from FIRST, and far-infrared coverage from Herschel, as well as existing ∼30% optical spectroscopic completeness, we are beginning to uncover rare objects, such as obscured high-luminosity active galactic nuclei at high-redshift. The Stripe 82X point source catalog is a valuable data set for constraining how this population grows and evolves, as well as for studying how they interact with the galaxies in which they live.

  10. Processes of chemoionization in the course of inflammation of a methane-oxygen mixture by a high-current gliding surface discharge in a closed chamber

    SciTech Connect

    Artem’ev, K. V.; Berezhetskaya, N. K.; Kossyi, I. A. Misakyan, M. A.; Popov, N. A.; Tarasova, N. M.


    Results are presented from experiments on the inflammation of a stoichiometric methane-oxygen mixture by a high-current multielectrode spark-gap in a closed cylindrical chamber. It is shown that, in both the preflame and well-developed flame stages, the gas medium is characterized by a high degree of ionization (n{sub e} ≈ 10{sup 12} cm{sup −3}) due to chemoionization processes and a high electron-neutral collision frequency (ν{sub e0} ≈ 10{sup 12} s{sup −1})

  11. Neutrino induced muons in Soudan 2.

    SciTech Connect

    DeMuth, D. M.; Soudan 2 Collaboration


    The neutrino-induced muon rate underground has been measured at Soudan 2. To discriminate from the intense background of atmospheric muons we consider only the through-going muons which originate from horizontal direction ({minus}0.14 < cos{theta} < 0.14). We calculate the horizontal, neutrino-induced muon rate at Soudan 2 from an exposure of 1.23 x 10{sup 8} s as {Phi}{sub {nu}{mu}} = (3.45 {+-} 0.52 {+-} 0.61) x 10{sup {minus}13} (cm{sup 2} sr s){sup {minus}1}.

  12. Radiation trapping in rubidium optical pumping at low buffer-gas pressures

    SciTech Connect

    Rosenberry, M. A.; Reyes, J. P.; Gay, T. J.; Tupa, D.


    We have made a systematic study of rubidium optical pumping in a simple cylindrical cell geometry with a high-power 10 W diode laser array, low magnetic fields, and buffer-gas pressures of less than 50 torr. We have determined rubidium polarizations experimentally for H{sub 2}, N{sub 2}, He, and Ar buffer gases, with Rb number densities from 10{sup 12} to 10{sup 13} cm{sup -3}. Comparison to a relatively simple optical pumping model allows us to extract useful information about radiation trapping and quenching effects.

  13. Coherent synchrotron radiation for broadband terahertz spectroscopy

    SciTech Connect

    Barros, J.; Manceron, L.; Brubach, J.-B.; Tordeux, M.-A.; Brunelle, P.; Nadolski, L.; Loulergue, A.; Couprie, M.-E.; Roy, P.; Evain, C.; Bielawski, S.; Szwaj, C.


    We present the first high resolution (10{sup -3} cm{sup -1}) interferometric measurements in the 200-750 GHz range using coherent synchrotron radiation, achieved with a low momentum compaction factor. The effect of microbunching on spectra is shown, depending on the bunch current. A high signal-to-noise ratio is reached thanks to an artifact correction system based on a double detection scheme. Combined to the broad emitted spectral range and high flux (up to 10{sup 5} times the incoherent radiation), this study demonstrates that coherent synchrotron radiation can now be used for stability-demanding applications, such as gas-phase studies of unstable molecules.

  14. Millimeter observations of CS, HCO{sup +}, and CO toward five planetary nebulae: following molecular abundances with nebular age

    SciTech Connect

    Edwards, J. L.; Ziurys, L. M.; Cox, E. G.


    Millimeter and sub-millimeter observations of CO, CS, and HCO{sup +} have been conducted toward five planetary nebulae (PNe: K4-47, NGC 6537 (Red Spider), M2-48, NGC 6720 (Ring), and NGC 6853 (Dumbbell)), spanning an age range of 900-10,000 yr, using the Sub-Millimeter Telescope and the 12 m antenna of the Arizona Radio Observatory. The J = 5 → 4, J = 3 → 2, and J = 2 → 1 transitions of CS at 245, 147, and 98 GHz, as well as the J = 3 → 2 and J = 1 → 0 lines of HCO{sup +} at 268 and 89 GHz, were detected toward each source. At least three rotational transitions of CO have also been observed, including the J = 6 → 5 and J = 4 → 3 lines at 691 and 461 GHz. CS had not been definitively identified previously in PNe, and new detections of HCO{sup +} were made in four of the five nebulae. From a radiative transfer analysis of the CO and CS data, kinetic temperatures of T {sub K} ∼ 10-80 K and gas densities of n(H{sub 2}) ∼ 0.1-1 × 10{sup 6} cm{sup –3} were determined for the molecular material in these sources. Column densities for CO, CS, and HCO{sup +} were N {sub tot} ∼ 0.2-5 × 10{sup 16} cm{sup –2}, N {sub tot} ∼ 0.4-9 × 10{sup 12} cm{sup –2}, and N {sub tot} ∼ 0.3-5 × 10{sup 12} cm{sup –2}, respectively, with fractional abundances, relative to H{sub 2}, of f ∼ 0.4-2 × 10{sup –4}, f ∼ 1-4 × 10{sup –8}, and f ∼ 1 × 10{sup –8}, with the exception of M2-48, which had f(HCO{sup +}) ∼ 10{sup –7}. Overall, the molecular abundances do not significantly vary over a duration of 10,000 yr, in contrast to predictions of chemical models. The abundances reflect the remnant asymptotic giant branch shell material, coupled with photochemistry in the early PN phase. These observations also suggest that PNe eject substantial amounts of molecular material into the diffuse interstellar medium.

  15. Search for the Dirac Monopole with 30-bev Protons

    DOE R&D Accomplishments Database

    Purcell, E.M.; Collins, G.B.; Fujii, T.; Hornbostel, J.; Turkot, F.


    A search was made at the Brookhaven alternating gradient synchrotron for magnetic monopoles produced either in collisions of 30-Bev protons with light nuclei, or produced by gamma rays secondary to these protons in the Coulomb field of protons or of carbon nuclei. In runs using 5.7 x 10{sup 15} circulating protons, no monopole-like event was found. This implies an upper limit for production in protonnucleon interactions of about 2 x 10{sup -40} cm{sup 2}. Experimental limits are also derived for the photoproduction of pole pairs. (auth)

  16. Positron plasma control techniques for the production of cold antihydrogen

    SciTech Connect

    Funakoshi, R.; Hayano, R. S.; Amoretti, M.; Macri, M.; Testera, G.; Variola, A.; Bonomi, G.; Bowe, P. D.; Hangst, J. S.; Madsen, N.; Canali, C.; Carraro, C.; Lagomarsino, V.; Manuzio, G.; Cesar, C. L.; Charlton, M.; Joergensen, L. V.; Mitchard, D.; Werf, D. P. van der; Doser, M.


    An observation of a clear dependence of antihydrogen production on positron plasma shapes is reported. For this purpose a plasma control method has been developed combining the plasma rotating-wall technique with a mode diagnostic system. With the help of real-time and nondestructive observations, the rotating-wall parameters have been optimized. The positron plasma can be manipulated into a wide range of shapes (aspect ratio 6.5{<=}{alpha} < or approx. 80) and densities (1.5x10{sup 8}{<=}n < or approx. 7x10{sup 9} cm{sup -3}) within a short duration (25 s) compatible with the ATHENA antihydrogen production cycle.

  17. Ultralow-background study of neutrinoless double. beta. decay of /sup 76/Ge; new limit on the Majorana mass of. nu. /sub e/

    SciTech Connect

    Avignone F.T. III; Brodzinski, R.L.; Brown, D.P.; Evans J.C. Jr.; Hensley, W.K.; Miley, H.S.; Reeves, J.H.; Wogman, N.A.


    A lower limit of 1.16 x 10/sup 23/ yr (1sigma) is reported for the half-life of no-neutrino ..beta../sup -/..beta../sup -/ decay of /sup 76/Ge which results from 3763 h of counting with an ultralow-background, 135-cm/sup 3/ prototype detector located 1438 m underground. A limit of 1.7 x 10/sup 23/ yr (1sigma) results from the best combination of our data with that from other experiments. Straightforward application of shell-model matrix elements to this limit implies that <3.2 eV (1sigma).

  18. Analysis of pumping requirement for exhausting duct in close vicinity of divertor in Tokamak Reactor

    SciTech Connect

    Saito, S.; Abe, T.; Fujisawa, N.; Sugihara, M.; Veda, K.


    An improved method for Monte Carlo simulation is described to calculate the neutral-particle transport in a divertor throat and to evaluate the helium removal efficiency from a burning plasma. The required pumping speed for the helium removal is discussed with special emphasis placed on the effects of long exhausting duct and of scrape-off plasma variables. The analysis for International Tokamak Reactor (INTOR) single null divertor suggests a possibility that the pumping requirement for INTOR could be drastically eased--e.g., <10/sup 4/ l/s, for the high scrape-off plasma density of the order of 10/sup 13/ cm/sup -3/.

  19. A near infrared organic photodiode with gain at low bias voltage

    SciTech Connect

    Campbell, Ian H; Crone, Brian K


    We demonstrate an organic photodiode with near infrared optical response out to about 1100 run with a gain of {approx}10 at 1000 run under 5V reverse bias. The diodes employ a soluble naphthalocyanine with a peak absorption coefficient of {approx}10{sup 5} cm{sup -1} at 1000 nm. In contrast to most organic photodiodes, no exciton dissociating material is used. At zero bias, the diodes are inefficient with an external quantum efficiency of {approx} 10{sup -2}. In reverse bias, large gain occurs and is linear with bias voltage above 4V. The observed gain is consistent with a photoconductive gain mechanism.

  20. Wrought stainless steel compositions having engineered microstructures for improved heat resistance


    Maziasz, Philip J [Oak Ridge, TN; Swindeman, Robert W [Oak Ridge, TN; Pint, Bruce A [Knoxville, TN; Santella, Michael L [Knoxville, TN; More, Karren L [Knoxville, TN


    A wrought stainless steel alloy composition includes 12% to 25% Cr, 8% to 25% Ni, 0.05% to 1% Nb, 0.05% to 10% Mn, 0.02% to 0.15% C, 0.02% to 0.5% N, with the balance iron, the composition having the capability of developing an engineered microstructure at a temperature above C. The engineered microstructure includes an austenite matrix having therein a dispersion of intragranular NbC precipitates in a concentration in the range of 10.sup.10 to 10.sup.17 precipitates per cm.sup.3.

  1. Reticle blanks for extreme ultraviolet lithography: Ion beam sputter deposition of low defect density Mo/Si multilayers

    SciTech Connect

    Vernon, S.P.; Kania, D.R.; Kearney, P.A.; Levesque, R.A.; Hayes, A.V.; Druz, B.; Osten, E.; Rajan, R.; Hedge, H.


    We report on growth of low defect density Mo/Si multilayer (ML) coatings. The coatings were grown in a deposition system designed for EUVL reticle blank fabrication. Complete, 81 layer, high reflectance Mo/Si ML coatings were deposited on 150 mm dia (100) oriented Si wafer substrates using ion beam sputter deposition. Added defects, measured by optical scattering, correspond to defect densities of 2x10{sup -2}/cm{sup 2}. This represents a reduction in defect density of Mo/Si ML coatings by a factor of 10{sup 5}.

  2. Study of ablation by laser irradiation of plane targets at wavelengths 1. 05, 0. 53, and 0. 35. mu. m

    SciTech Connect

    Key, M.H.; Toner, W.T.; Goldsack, T.J.; Kilkenny, J.D.; Veats, S.A.; Cunningham, P.F.; Lewis, C.L.S.


    Ablation by laser irradiation at wavelengths lambda = 1.05, 0.53, and 0.35 has been studied from analysis of time-resolved x-ray spectra of layered targets and of ion emission. Irradiance was varied in the range 2 x 10/sup 13/ to 2 x 10/sup 15/ W cm/sup -2/ with constant laser power and variable focal spot size. Deductions include the effect of lateral energy transport from small focal spots and ablation rates and ablation pressures obtained both in the limit of negligible transport and when lateral transport is significant. Advantages of short wavelengths for ablatively driven implosions are quantified.

  3. Reproducing continuous radio blackout using glow discharge plasma

    SciTech Connect

    Xie, Kai; Li, Xiaoping; Liu, Donglin; Shao, Mingxu; Zhang, Hanlu


    A novel plasma generator is described that offers large-scale, continuous, non-magnetized plasma with a 30-cm-diameter hollow structure, which provides a path for an electromagnetic wave. The plasma is excited by a low-pressure glow discharge, with varying electron densities ranging from 10{sup 9} to 2.5 × 10{sup 11} cm{sup −3}. An electromagnetic wave propagation experiment reproduced a continuous radio blackout in UHF-, L-, and S-bands. The results are consistent with theoretical expectations. The proposed method is suitable in simulating a plasma sheath, and in researching communications, navigation, electromagnetic mitigations, and antenna compensation in plasma sheaths.

  4. Effect of the active-ion concentration on the lasing dynamics of holmium fibre lasers

    SciTech Connect

    Kurkov, Andrei S; Sholokhov, E M; Marakulin, A V; Minashina, L A


    The lasing dynamics of fibre lasers with a core based on quartz glass doped with holmium ions to concentrations in the range of 10{sup 19}-10{sup 20} cm{sup -3} is investigated. It is shown that fibre lasers with a high concentration of active holmium ions generate pulses, but a decrease in the holmium concentration changes the lasing from pulsed to cw regime. At the same time, a decrease in the active-ion concentration and the corresponding increase in the fibre length in the cavity reduce the lasing efficiency. (lasers)

  5. Effect of active-ion concentration on holmium fibre laser efficiency

    SciTech Connect

    Kurkov, Andrei S; Sholokhov, E M; Marakulin, A V; Minashina, L A


    We have measured the fraction of holmium ions that relax nonradiatively to the ground level as a result of interaction at a metastable level in optical fibres with a silica-based core doped with holmium ions to 2 x 10{sup 19} - 2 x 10{sup 20} cm{sup -3}. The percentage of such ions has been shown to depend on the absolute active-ion concentration. The fibres have been used to make a number of 2.05-{mu}m lasers, and their slope efficiency has been measured. The laser efficiency decreases with increasing holmium concentration in the fibres (lasers)

  6. Condensation of ablation plumes in the irradiation of metals by high-intensity nanosecond laser pulses at atmospheric pressure

    SciTech Connect

    Kozadaev, K V


    The Anisimov–Luk'yanchuk model is adapted for describing the condensation of vapour-plasma plumes produced in the irradiation of metal targets by high-intensity (10{sup 8} – 10{sup 10} W cm{sup -2}) nanosecond (10 – 100 ns) pulses at atmospheric pressure. The resultant data suggest that the initial stages of the development of metal ablation plumes correspond with a high degree of accuracy to the Zel'dovich–Raizer theory of dynamic condensation; however, at the stage of the ablation plume decay, the liquid-droplet phase is formed primarily by coalescence of 'nuclei'. (interaction of laser radiation with matter. laser plasma)

  7. High dislocation density of tin induced by electric current

    SciTech Connect

    Liao, Yi-Han; Liang, Chien-Lung; Lin, Kwang-Lung; Wu, Albert T.


    A dislocation density of as high as 10{sup 17} /m{sup 2} in a tin strip, as revealed by high resolution transmission electron microscope, was induced by current stressing at 6.5 x 10{sup 3} A/ cm{sup 2}. The dislocations exist in terms of dislocation line, dislocation loop, and dislocation aggregates. Electron Backscattered Diffraction images reflect that the high dislocation density induced the formation of low deflection angle subgrains, high deflection angle Widmanstätten grains, and recrystallization. The recrystallization gave rise to grain refining.

  8. Hydrodynamic simulations of metal ablation by femtosecond laser irradiation

    SciTech Connect

    Colombier, J.P.; Combis, P.; Bonneau, F.


    Ablation of Cu and Al targets has been performed with 170 fs laser pulses in the intensity range of 10{sup 12}-10{sup 14} W cm{sup -2}. We compare the measured removal depth with 1D hydrodynamic simulations. The electron-ion temperature decoupling is taken into account using the standard two-temperature model. The influence of the early heat transfer by electronic thermal conduction on hydrodynamic material expansion and mechanical behavior is investigated. A good agreement between experimental and numerical matter ablation rates shows the importance of including solid-to-vapor evolution of the metal in the current modeling of the laser matter interaction.

  9. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )


    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  10. Fourier-transform spectroscopy and potential construction of the (2){sup 1}Π state in KCs

    SciTech Connect

    Birzniece, I.; Nikolayeva, O.; Tamanis, M.; Ferber, R.


    The paper presents an empirical pointwise potential energy curve (PEC) of the (2){sup 1}Π state of the KCs molecule constructed by applying the Inverted Perturbation Approach routine. The experimental term values in the energy range E(v′, J′) ∈ [15 407; 16 579] cm{sup −1} involved in the fit were based on Fourier-Transform spectroscopy data obtained with 0.01 cm{sup −1} accuracy from the laser-induced (2){sup 1}Π → X{sup 1}Σ{sup +} fluorescence spectra. Buffer gas Ar was used to facilitate the appearance of rotation relaxation lines in the spectra, thus enlarging the (2){sup 1}Π data set and allowing determination of the Λ-splitting constants. The data set included vibrational v′ ∈ [0, 28] and rotational J′ ∈ [7, 274] quantum numbers covering about 67% of the potential well. The present PEC reproduces the overall set of data included in the fit with a standard deviation of 0.5 cm{sup −1}. The obtained value of the Λ-doubling constant q = + 1.8 × 10{sup −6} cm{sup −1} for J′ > 50 and v′ ∈ [0, 6] is in an excellent agreement with q = + 1.84 × 10{sup −6} cm{sup −1} reported in Kim, Lee, and Stolyarov [J. Mol. Spectrosc. 256, 57-67 (2009)].

  11. Growth of detector-grade CZT by Traveling Heater Method (THM): An advancement

    SciTech Connect



    In this present work we report the growth of Cd{sub 0.9}Zn{sub 0.1}Te doped with In by a modified THM technique. It has been demonstrated that by controlling the microscopically flat growth interface, the size distribution and concentration can be drastically reduced in the as-grown ingots. This results in as-grown detector-grade CZT by the THM technique. The three-dimensional size distribution and concentrations of Te inclusions/precipitations were studied. The size distributions of the Te precipitations/inclusions were observed to be below the 10-{micro}m range with the total concentration less than 10{sup 5} cm{sup -3}. The relatively low value of Te inclusions/precipitations results in excellent charge transport properties of our as-grown samples. The ({mu}{tau}){sub e} values for different as-grown samples varied between 6-20 x 10{sup -3} cm{sup 2}/V. The as-grown samples also showed fairly good detector response with resolution of {approx}1.5%, 2.7% and about 3.8% at 662 keV for quasi-hemispherical geometry for detector volumes of 0.18 cm{sup 3}, 1 cm{sup 3} and 4.2 cm{sup 3}, respectively.

  12. Two-dimensional electron gas in monolayer InN quantum wells

    SciTech Connect

    Pan, Wei; Dimakis, Emmanouil; Wang, George T.; Moustakas, Theodore D.; Tsui, Daniel C.


    We report in this letter experimental results that confirm the two-dimensional nature of the electron systems in monolayer InN quantum wells embedded in GaN barriers. The electron density and mobility of the two-dimensional electron system (2DES) in these InN quantum wells are 5×10<sup>15 cm>-2 and 420 cm>2 /Vs, respectively. Moreover, the diagonal resistance of the 2DES shows virtually no temperature dependence in a wide temperature range, indicating the topological nature of the 2DES.

  13. Effects of copper excess and copper deficiency on the structural and electrical properties of bulk Cu{sub x}SnSe{sub 3} with x=1.6–2.2

    SciTech Connect

    Wubet, Walelign; Kuo, Dong-Hau


    Effects of the Cu variation on the morphological, structural, and electrical properties of bulk Cu{sub x}SnSe{sub 3} (CTSe) with x=1.6–2.2 have been investigated. Dense CTSe pellets with grains of 3–4 µm were obtained after sintering at 550 °C. All CTSe pellets showed a dominant p-type behavior. CTSe at x=2.0 with a hole concentration (n{sub p}) of 1.02×10{sup 18} cm{sup −3} and Hall mobility (μ) of 225 cm{sup 2}/V/s had a highest conductivity (σ) of 39 S/cm. CTSe at x=1.6 with n{sub p} of 5.0×10{sup 17} cm{sup −3} and of 11 cm{sup 2}/V/s had a lowest of 0.90 S/cm. The explanation, based upon vacancies and antisite defects, for the changes in electrical property with the Cu content is supported by the data from lattice parameter. The study in bulk properties of CTSe and its defects is helpful for selecting the suitable absorber composition to fabricate thin film solar cells. - Graphical abstract: Cu{sub 2}SnSe{sub 3} is an absorber candidate for solar cells. The Cu stoichiometry on electrical properties, which is important for CIGS and CZTS, is investigated and the Cu-deficiency composition is recommended. - Highlights: • Cu{sub x}SnSe{sub 3} (CTSe) bulks with 1.6≤x≤2.2 were prepared by reactive sintering. • Cu{sub 2}SnSe{sub 3} with n{sub p} of 1.02×10{sup 18} cm{sup −3} and μ of 225 cm{sup 2}/V/s had highest σ of 39 S/cm. • Cu{sub 1.6}SnSe{sub 3} with n{sub p}=5.0×10{sup 17} cm{sup −3} and μ=11 cm{sup 2}/V/s had lowest σ=0.90 S/cm. • Lower n{sub p} at CTSe at x=1.6 is related to the formation of the Sn-to-Cu defect. • The drop in n{sub p} for CTSe at x=2.2 indicates V{sub Sn}{sup 4−} dominates over Cu{sub Sn}{sup 3−} defect.

  14. Titanium doped silicon layers with very high concentration

    SciTech Connect

    Olea, J.; Toledano-Luque, M.; Pastor, D.; Gonzalez-Diaz, G.; Martil, I.


    Ion implantation of Ti into Si at high doses has been performed. After laser annealing the maximum average of substitutional Ti atoms is about 10{sup 18} cm{sup -3}. Hall effect measurements show n-type samples with mobility values of about 400 cm{sup 2}/V s at room temperature. These results clearly indicate that Ti solid solubility limit in Si has been exceeded by far without the formation of a titanium silicide layer. This is a promising result toward obtaining of an intermediate band into Si that allows the design of a new generation of high efficiency solar cell using Ti implanted Si wafers.

  15. Process for growing epitaxial gallium nitride and composite wafers


    Weber, Eicke R.; Subramanya, Sudhir G.; Kim, Yihwan; Kruger, Joachim


    A novel growth procedure to grow epitaxial Group III metal nitride thin films on lattice-mismatched substrates is proposed. Demonstrated are the quality improvement of epitaxial GaN layers using a pure metallic Ga buffer layer on c-plane sapphire substrate. X-ray rocking curve results indicate that the layers had excellent structural properties. The electron Hall mobility increases to an outstandingly high value of .mu.>400 cm.sup.2 /Vs for an electron background concentration of 4.times.10.sup.17 cm.sup.-3.

  16. Infrared analysis of hole properties of Mg-doped p-type InN films

    SciTech Connect

    Fujiwara, Masayuki; Ishitani, Yoshihiro; Wang Xinqiang; Che, Song-Bek; Yoshikawa, Akihiko


    Mg-doped InN films grown by plasma-assisted molecular beam epitaxy were characterized by infrared reflectance. Signatures of p-type conductivity in the spectra were obtained in the same doping density range where the existence of net acceptors was found by electrolyte capacitance-voltage measurements. Numerical spectrum analysis, which takes into account the large broadening factor of the normal mode energies of longitudinal optical phonon-plasmon coupling yielded high hole densities in the range of (0.1-1.2)x10{sup 19} cm{sup -3} and optical mobilities in the range of 25-70 cm{sup 2}/V s.

  17. Materials erosion and redeposition studies at the PISCES-facility: net erosion under redeposition

    SciTech Connect

    Hirooka, Y.; Goebel, D.M.; Conn, R.W.; Leung, W.K.; Campbell, G.A.


    Simultaneous erosion and redeposition of copper and 304 stainless steel under controlled and continuous plasma (D,He,Ar) bombardment has been investigated in the PISCES-facility, which generates typical edge-plasma conditions of magnetic fusion devices. The plasma bombardment conditions are: incident ion flux in the range from 10/sup 17/ to 10/sup 18/ ions/sec/cm/sup 2/, ion bombarding energy of 100 eV, electron temperature in the range from 5 to 15 eV, plasma density in the range from 10/sup 11/ to 10/sup 13/ cm/sup -3/, target temperature in the range from 300 to 900K, and the total ion fluence in the range from 10/sup 20/ to 10/sup 22/ ions/cm/sup 2/. The net erosion yield under redeposition is found to be significantly smaller than the classical sputtering yield data. A first-order modeling is attempted to interpret the erosion and redeposition behavior of materials under plasma bombardment. It is pointed out both theoretically and experimentally that the mean free path for electron impact ionization of the sputtered material is the key parameter to control the overall mechanism of erosion and redeposition. Strongly modified surface morphologies of bombarded targets are observed and indicate a retrapping effect.

  18. Inelastic cross sections for positron scattering from atomic hydrogen

    SciTech Connect

    Weber, M.; Hofmann, A.; Raith, W.; Sperber, W.; Jacobsen, F.; Lynn, K.G.


    Positronium formation (Ps) cross sections for positrons impinging on atomic hydrogen were measured in the impact energy range from 13eV to 255eV at the High Intensity Positron (HIP) beam at Brookhaven National Laboratory (BNL). The Ps-formation cross section was found to rise rapidly from the threshold at 6.8eV to a maximum value of (2.98 {plus_minus} 0.18) {times} 10{sup {minus}16} cm{sup 2} for {approx} 15eV positrons. By 75eV it drops below the detection limit of 0.17 {times} 10{sup {minus}16} cm{sup 2} which is the present level of statistical uncertainty. The experiment was modified to enable the measurement of doubly differential scattering cross sections.

  19. Mega-electron-volt proton irradiation on supported and suspended graphene: A Raman spectroscopic layer dependent study

    SciTech Connect

    Mathew, S.; Thong, John T. L.; Chan, T. K.; Breese, M. B. H.; Zhan, D.; Shen, Z. X.; Gopinadhan, K.; Dhar, S.; Venkatesan, T.; Roy Barman, A.


    Graphene samples with 1, 2, and 4 layers and 1 + 1 folded bi-layers and graphite have been irradiated with 2 MeV protons at fluences ranging from 1 x 10{sup 15} to 6 x 10{sup 18} ions/cm{sup 2}. The samples were characterized using visible and UV Raman spectroscopy and Raman microscopy. The ion-induced defects were found to decrease with increasing number of layers. Graphene samples suspended over etched holes in SiO{sub 2} have been fabricated and used to investigate the influence of the substrate SiO{sub 2} for defect creation in graphene. While Raman vibrational modes at 1460 cm{sup -1} and 1555 cm{sup -1} have been observed in the visible Raman spectra of substantially damaged graphene samples, these modes were absent in the irradiated-suspended monolayer graphene.

  20. On the electronic properties of GaSb irradiated with reactor neutrons and its charge neutrality level

    SciTech Connect

    Boiko, V. M.; Brudnii, V. N.; Ermakov, V. S.; Kolin, N. G.; Korulin, A. V.


    The electronic properties and the limiting position of the Fermi level in p-GaSb crystals irradiated with full-spectrum reactor neutrons at up to a fluence of 8.6 × 10{sup 18} cm{sup −2} are studied. It is shown that the irradiation of GaSb with reactor neutrons results in an increase in the concentration of free holes to p{sub lim} = (5−6) × 10{sup 18} cm{sup −3} and in pinning of the Fermi level at the limiting position F{sub lim} close to E{sub V} + 0.02 eV at 300 K. The effect of the annealing of radiation defects in the temperature range 100–550°C is explored.

  1. Modified Johnson model for ferroelectric lead lanthanum zirconate titanate at very high fields and below Curie temperature.

    SciTech Connect

    Narayanan, M.; Tong, S.; Ma, B.; Liu, S.; Balachandran, U.


    A modified Johnson model is proposed to describe the nonlinear field dependence of the dielectric constant ({var_epsilon}-E loop) in ferroelectric materials below the Curie temperature. This model describes the characteristic ferroelectric 'butterfly' shape observed in typical {var_epsilon}-E loops. The predicted nonlinear behavior agreed well with the measured values in both the low- and high-field regions for lead lanthanum zirconate titanate films. The proposed model was also validated at different temperatures below the ferroelectric-to-paraelectric Curie point. The anharmonic coefficient in the model decreased from 6.142 x 10{sup -19} cm{sup 2}/V{sup 2} to 2.039 x 10{sup -19} cm{sup 2}/V{sup 2} when the temperature increased from 25 C to 250 C.

  2. Spectrometry of the Rutherford backscattering of ions and the Raman scattering of light in GaS single crystals irradiated with 140-keV H{sub 2}{sup +} ions

    SciTech Connect

    Garibov, A. A.; Madatov, R. S.; Komarov, F. F.; Pilko, V. V.; Mustafayev, Yu. M.; Akhmedov, F. I.; Jakhangirov, M. M.


    The methods of the Raman scattering of light and Rutherford backscattering are used to study the degree of structural disorder in layered GaS crystals before and after irradiation with 140-keV H{sub 2}{sup +} ions. It is shown that the distribution of the crystal’s components over depth is homogeneous; for doses as high as 5 × 10{sup 15} cm{sup −2}, the stoichiometric composition of the compound’s components is retained. The experimental value of the critical dose for the beginning of amorphization amounts to about 5 × 10{sup 15} cm{sup −2} and is in accordance with the calculated value. The results obtained by the method of the Raman scattering of light confirm conservation of crystalline structure and the start of the amorphization process.

  3. Photodetectors on the basis of Ge/Si(001) heterostructures grown by the hot-wire CVD technique

    SciTech Connect

    Shengurov, V. G. Chalkov, V. Yu.; Denisov, S. A.; Alyabina, N. A.; Guseinov, D. V.; Trushin, V. N.; Gorshkov, A. P.; Volkova, N. S.; Ivanova, M. M.; Kruglov, A. V.; Filatov, D. O.


    The fabrication of photodetectors for the wavelength range of communications λ = 1.3–1.55 µm on the basis of Ge/Si(001) heterostructures with thick (∼0.5 µm) Ge layers grown by the hot-wire technique at reduced growth temperatures (350°C) is reported. The single-crystal Ga layers are distinguished by a low density of threading dislocations (∼10{sup 5} cm{sup –2}). The photodetectors exhibit a rather high quantum efficiency (∼0.05 at λ = 1.5 µm and 300 K) at moderate reverse saturation current densities (∼10{sup –2} A cm{sup –2}). Thus, it is shown that the hot-wire technique offers promise for the formation of integrated photodetectors for the wavelength range of communications, especially in the case of limitations on the conditions of heat treatments.

  4. Effect of thermal neutrons on emission characteristics of InGaAs/AlGaAs heterolasers

    SciTech Connect

    Makhsudov, B I


    It is studied how the threshold current of InGaAs/AlGaAs quantum-well injection heterolasers emitting near the wavelength λ = 0.7 μm changes under irradiation by thermal neutrons. It is found that the threshold pump current decreases at small doses (10{sup -2} neutron cm{sup -2}), while doses exceeding 6 × 10{sup 7} neutron cm{sup -2} cause an increase in this current and degradation of the structure. It is found that the main reasons for an increase in the threshold current at high irradiation doses are the nuclear reactions of the {sub 49}In{sup 115} (n, γ) → {sub 49}In{sup 116} type and the β-decay of the {sub 49}In{sup 116} isotope, which results in the appearance of {sub 50}Sn{sup 116} atoms. (lasers)

  5. Carrier mediated reduction of stiffness in nanoindented crystalline Si(100)

    SciTech Connect

    Kataria, S. Dhara, Sandip Dash, S.; Tyagi, A. K.


    We report the observation of carrier mediated decrease in the stiffness of crystalline (c)-Si(100) under nanoindentation. The apparent elastic moduli of heavily doped (∼1 × 10{sup 21} cm{sup −3}) p- and n-type c-Si are observed to be lower by 5.3%–7.5% than the estimated value for intrinsic (∼1 × 10{sup 14} cm{sup −3}) c-Si. The deviation observed with respect to elastic modulus remarkably matches with the estimated value while considering the electronic elastic strain effect on carrier concentration as an influence of negative pressure coefficient of band gap for Si (Γ-X). The value is predominantly higher than the reported value of a decrease of 1%–3% in stiffness as an effect of impurity in c-Si.

  6. Thin film solid-state lithium batteries prepared by convective vapor-phase processes

    SciTech Connect

    Takehara, Z.; Ogumi, Z.; Uchimoto, Y.; Endo, E. . Faculty of Engineering); Kanamori, Y. )


    Thin-film solid-state lithium batteries of total thickness less than 20 {mu}m were prepared. These thin lithium batteries were fabricated using a thin film of TiS{sub 2} prepared by chemical vapor deposition (CVD) as the cathode active material, a thin film of solid polymer prepared by plasma polymerization as the electrolyte, and a thin film of lithium deposited by thermal evaporation as the anode. The solid polymer electrolyte film was formed by complexation of plasma-polymerized tris (2-methoxyethoxy) vinylsilane with lithium perchlorate. Its room temperature conductivity was greater than 10{sup {minus}6} S cm{sup {minus}1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area). The battery's discharge properties at room temperature and different current densities were examined. In this paper the effects of the interfaces between the solid polymer electrolyte and the electrodes on the battery's discharge performance are discussed.

  7. Interaction of divalent plutonium and curium

    SciTech Connect

    Mikheev, N.B.; Kazakevich, M.Z.; Rumer, I.A.


    It has been established that at plutonium concentrations ranging from 10/sup -5/ to 10/sup -4/ mole % the oxidation potentials of the Pu/sup 3 +//Pu/sup 2 +/ and Cm/sup 3 +//Cm/sup 2 +/ pairs increased by 0.15-0.2 V due to the dimerization of Pu/sup 2 +/ and the formation of mixed dimers of plutonium and curium. Promethium(2+) does not have a similar ability to form mixed dimers owing to the fact that Pm/sup 2 +/ does not have a free d electron. The oxidation potential of the Pm/sup 3 +//Pm/sup 2 +/ pair does not vary in the presence of massive quantities of plutonium

  8. Radiative power and electron cooling rates for oxygen in steady-state and transient plasmas at densities beyond the coronal limit

    SciTech Connect

    Keane, C.; Skinner, C.H.


    We have developed a time-dependent, collisional-radiative model to calculate radiative power and electron cooling rates for oxygen at intermediate densities (10/sup 16/ cm/sup -3/ less than or equal to n/sub e/ less than or equal to 10/sup 20/ cm/sup -3/) where the usual coronal approximation is not valid. Large differences from coronal values are predicted. The behavior of the steady-state radiative power loss coefficient, L/sub Z, is investigated as the electron density is increased. Generalized power loss coefficients applicable to transient plasmas are derived and applied to ionizing and recombining oxygen plasmas. Time-dependent effects are found to play a large role both in terms of the total radiated power and the net electron energy loss rate. 41 refs., 11 figs.

  9. Scientific opportunities with advanced facilities for neutron scattering

    SciTech Connect

    Lander, G.H.; Emery, V.J.


    The present report documents deliberations of a large group of experts in neutron scattering and fundamental physics on the need for new neutron sources of greater intensity and more sophisticated instrumentation than those currently available. An additional aspect of the Workshop was a comparison between steady-state (reactor) and pulsed (spallation) sources. The main conclusions were: (1) the case for a new higher flux neutron source is extremely strong and such a facility will lead to qualitatively new advances in condensed matter science and fundamental physics; (2) to a large extent the future needs of the scientific community could be met with either a 5 x 10/sup 15/ n cm/sup -2/s/sup -1/ steady state source or a 10/sup 17/ n cm/sup -2/s/sup -1/ peak flux spallation source; and (3) the findings of this Workshop are consistent with the recommendations of the Major Materials Facilities Committee.

  10. Development of a long-slot microwave plasma source

    SciTech Connect

    Kuwata, Y. Kasuya, T.; Miyamoto, N.; Wada, M.


    A 20 cm long 10 cm wide microwave plasma source was realized by inserting two 20 cm long 1.5 mm diameter rod antennas into the plasma. Plasma luminous distributions around the antennas were changed by magnetic field arrangement created by permanent magnets attached to the source. The distributions appeared homogeneous in one direction along the antenna when the spacing between the antenna and the source wall was 7.5 mm for the input microwave frequency of 2.45 GHz. Plasma density and temperature at a plane 20 cm downstream from the microwave shield were measured by a Langmuir probe array at 150 W microwave power input. The measured electron density and temperature varied over space from 3.0 × 10{sup 9} cm{sup −3} to 5.8 × 10{sup 9} cm{sup −3}, and from 1.1 eV to 2.1 eV, respectively.

  11. Characteristics of the three-half-turn-antenna-driven RF discharge in the Uragan-3M torsatron

    SciTech Connect

    Grigor’eva, L. I.; Chechkin, V. V. Moiseenko, V. E.; Grekov, D. L.; Pavlichenko, R. O.; Lozin, A. V.; Tarasov, I. K.; Kulaga, A. Ye.; Zamanov, N. V.; Tretiak, K. K.; Kozulya, M. M.; Beletskii, A. A.; Kasilov, A. A.; Mironov, Yu. K.; Romanov, V. S.; Voitsenya, V. S.


    In the ℓ = 3 Uragan-3M torsatron hydrogen plasma is produced by RF fields in the Alfvén range of frequencies (ω ≤ ω{sub ci}). The initial (target) plasma with the line-averaged density of units 10{sup 12} cm{sup −3} is produced by a frame antenna with a broad spectrum of generated parallel wavenumbers. After this, to heat the plasma and bring its density to ∼10{sup 13} cm{sup –3}, another, shorter wavelength three-half-turn antenna with large transverse currents is used. The behavior of the density, electron temperature, and loss of the plasma supported by the three-half-turn antenna is studied depending on the RF power fed to the antenna and initial values of the density and electron temperature supplied by the frame antenna.

  12. Characterization of Si volume- and delta-doped InGaAs grown by molecular beam epitaxy

    SciTech Connect

    Fedoryshyn, Y.; Kaspar, P.; Jaeckel, H.; Beck, M.


    Bulk InGaAs layers were grown at 400 deg. C lattice-matched to InP semi-insulating substrates by molecular beam epitaxy. Si doping of the layers was performed by applying volume- and delta-doping techniques. The samples were characterized by capacitance-voltage, van der Pauw-Hall, secondary ion mass spectroscopy and photoluminescence measurements. Good agreement in terms of dependence of mobility and Burstein-Moss shift shift on doping concentration in samples doped by the two different techniques was obtained. Amphoteric behavior of Si was observed at doping concentrations higher than {approx}2.9x10{sup 19} cm{sup -3} in both delta- and volume-doped samples. Degradation of InGaAs crystalline quality occurred in samples with Si concentrations higher than {approx}4x10{sup 19} cm{sup -3}.

  13. Nature of Defects Induced by Au Implantation in Hexagonal Silicon Carbide Single Crystals

    SciTech Connect

    Gentils, Aurelie; Barthe, Marie-France; Egger, Werner; Sperr, Peter


    Pulsed-slow-positron-beam-based positron lifetime spectroscopy was used to investigate the nature of vacancy defects induced by 20 MeV Au implantation in single crystals 6H-SiC. Preliminary analysis of the data shows that at lower fluence, below 10{sup 14} cm{sup -2}, a positron lifetime of 220 ps has been obtained: it could be associated with the divacancy V{sub Si}-V{sub C} in comparison with the literature. At higher fluence, above 10{sup 15} cm{sup -2}, a positron lifetime of 260-270 ps, increasing with the incident positron energy, has been observed after decomposition of the lifetime spectra. By comparison with lifetime calculations, open-volumes such as quadrivacancy (V{sub Si}-V{sub C}){sub 2} clusters could be associated with this value.

  14. Low Band Gap Thiophene-Perylene Diimide Systems with Tunable Charge Transport Properties

    SciTech Connect

    Balaji, Ganapathy; Kale, Tejaswini S.; Keerthi, Ashok; Della Pelle, Andrea M.; Thayumanavan, S.; Vallyaveettil, Surech


    Perylenediimide-pentathiophene systems with varied architecture of thiophene units were synthesized. The photophysical, electrochemical, and charge transport behavior of the synthesized compounds were studied. Both molecules showed a low band gap of ~1.4 eV. Surprisingly, the molecule with pentathiophene attached via β-position to the PDI unit upon annealing showed a predominant hole mobility of 1 × 10<sup>-4 cm>2 V-1 s-1 whereas the compound with branched pentathiophene attached via β-position showed an electron mobility of 9.8 × 10<sup>-7 cm>2 V-1 s-1. This suggests that charge transport properties can be tuned by simply varying the architecture of pentathiophene units.

  15. Nonequilibrium atmospheric pressure plasma with ultrahigh electron density and high performance for glass surface cleaning

    SciTech Connect

    Iwasaki, Masahiro; Matsudaira, Yuto; Hori, Masaru; Inui, Hirotoshi; Kano, Hiroyuki; Yoshida, Naofumi; Ito, Masafumi


    We produced a nonequilibrium atmospheric pressure plasma by applying an alternative current between two electrodes. The gas temperature and electron density were evaluated using optical emission spectroscopy. It was found that the plasma had gas temperatures from 1800 to 2150 K and ultrahigh electron densities in the order of 10{sup 16} cm{sup -3}. A remarkably high oxygen radical concentration of 1.6x10{sup 15} cm{sup -3} was obtained at a 1% O{sub 2}/Ar gas flow rate of 15 slm (standard liters per minute). Contact angles below 10 deg. were obtained in the process of glass cleaning with a plasma exposure time of 23 ms.

  16. Helium-ion-induced release of hydrogen from graphite

    SciTech Connect

    Langley, R.A.


    The ion-induced release of hydrogen from AXF-5Q graphite was studied for 350-eV helium ions. The hydrogen was implanted into the graphite with a low energy (approx.200 eV) and to a high fluence. This achieved a thin (approx.10-nm), saturated near-surface region. The release of hydrogen was measured as a function of helium fluence. A model that includes ion-induced detrapping, retrapping, and surface recombination was used to analyze the experimental data. A value of (1.65 +- 0.2) x 10/sup -16/ cm/sup 2/ was obtained from the detrapping cross section, and a value of (0.5 to 4) x 10/sup -14/ cm/sup 4//atoms was obtained for the recombination coefficient. 11 refs., 4 figs.

  17. Anomalous intense driver (AID) concept

    SciTech Connect

    Thode, L.E.


    An optimized electron bunching mechanism is utilized to efficiently couple the energy of a 5 to 100 MeV, 1 to 30 TW electron beam into a 3 to 50 cm/sup 3/ plasma of electron density 10/sup 17/ to 10/sup 20/ cm-/sup 3/. An efficient coupling of beam energy and momentum to the plasma is possible due to the relativistic nature of the beam dynamics combined with the short wavelength of the bunching mechanism in a high-density plasma. The rapidly produced multi-kilovolt plasma can be used directly to develop a pulsed neutron and x-ray source. Alternatively, the plasma can be used to drive a hierarchy of inertial confinement or x-ray devices. Utilizing this novel concept, controlled thermonuclear fusion may be achievable within present or near term relativistic electron beam technology.

  18. Cathodic decomposition of propylene carbonate at graphite electrodes

    SciTech Connect

    Piao, T.; Doh, C.H.; Moon, S.I.; Park, S.M.


    The decomposition reaction of propylene carbonate has been studied at graphite electrode in 1.0 M LiClO{sub 4} employing a variety of transient electrochemical techniques. Results show that the PC decomposition reaction takes place through an EC{prime} (electron transfer followed by catalytic reduction) reaction path. The pseudo first order rate constants of the chemical decomposition step has been determined. The formation of passive films on the electrode surface has been confirmed. The diffusion coefficients at the fresh and the film covered graphite electrodes have been determined to be 8.2 {times} 10{sup {minus}9} cm{sup 2}/s and 7.1 {times} 10{sup {minus}9} cm{sup 2}/s, respectively.

  19. Results From the DAFNE High Luminosity Test

    SciTech Connect

    Milardi, C.; Alesini, D.; Biagini, M.E.; Boni, R.; Boscolo, M.; Bossi, F.; Buonomo, B.; Clozza, A.; Delle Monache, G.; Demma, T.; Di Pasquale, E.; Di Pirro, G.; Drago, A.; Gallo, A.; Ghigo, A.; Guiducci, S.; Ligi, C.; Marcellini, F.; Mazzitelli, G.; Murtas, F.; Pellegrino, L.; /Frascati /Novosibirsk, IYF /CERN /INFN, Cosenza /INFN, Rome /KEK, Tsukuba /Orsay, LAL /Rome U. /Pisa U. /INFN, Pisa /INFN, Rome3 /SLAC


    The DAPHNE collider, based on a new collision scheme including Large Piwinsky angle and Crab-Waist, has been successfully commissioned and is presently delivering luminosity to the SIDDHARTA detector. Large crossing angle and Crab-Waist scheme proved to be effective in: (1) Increasing luminosity, now a factor 2.7 higher than in the past; and (2) controlling transverse beam blow-up due to the beam-beam. Work is in progress to reach the ultimate design luminosity goal 5.0 {center_dot} 10{sup 32} cm{sup -2}s{sup -1}. The new collision scheme is the main design concept for a new project aimed at building a Super-B factory that is expected to achieve a luminosity of the order of 10{sup 36} cm{sup -2} s{sup -1} and it has been also taken into account to upgrade one of the LHC interaction regions.

  20. Optical limiting effects in nanostructured silicon carbide thin films

    SciTech Connect

    Borshch, A A; Starkov, V N; Volkov, V I; Rudenko, V I; Boyarchuk, A Yu; Semenov, A V


    We present the results of experiments on the interaction of nanosecond laser radiation at 532 and 1064 nm with nanostructured silicon carbide thin films of different polytypes. We have found the effect of optical intensity limiting at both wavelengths. The intensity of optical limiting at λ = 532 nm (I{sub cl} ∼ 10{sup 6} W cm{sup -2}) is shown to be an order of magnitude less than that at λ = 1064 nm (I{sub cl} ∼ 10{sup 7} W cm{sup -2}). We discuss the nature of the nonlinearity, leading to the optical limiting effect. We have proposed a method for determining the amount of linear and two-photon absorption in material media. (nonlinear optical phenomena)

  1. Dissociative electron attachment to C{sub 2}F{sub 5} radicals

    SciTech Connect

    Haughey, Sean A.; Field, Thomas A.; Langer, Judith; Shuman, Nicholas S.; Miller, Thomas M.; Friedman, Jeffrey F.; Viggiano, A. A.


    Dissociative electron attachment to the reactive C{sub 2}F{sub 5} molecular radical has been investigated with two complimentary experimental methods; a single collision beam experiment and a new flowing afterglow Langmuir probe technique. The beam results show that F{sup -} is formed close to zero electron energy in dissociative electron attachment to C{sub 2}F{sub 5}. The afterglow measurements also show that F{sup -} is formed in collisions between electrons and C{sub 2}F{sub 5} molecules with rate constants of 3.7 Multiplication-Sign 10{sup -9} cm{sup 3} s{sup -1} to 4.7 Multiplication-Sign 10{sup -9} cm{sup 3} s{sup -1} at temperatures of 300-600 K. The rate constant increases slowly with increasing temperature, but the rise observed is smaller than the experimental uncertainty of 35%.

  2. Electron attachment to propargyl chloride, 305-540 K

    SciTech Connect

    Bopp, Joseph C.; Miller, Thomas M.; Friedman, Jeffrey F.; Shuman, Nicholas S.; Viggiano, A. A.


    Electron attachment to propargyl chloride (HC{identical_to}C-CH{sub 2}Cl) was studied in a flowing-afterglow Langmuir-probe apparatus from 305 to 540 K. The sole ion product in this temperature range is Cl{sup -}. Electron attachment is very inefficient, requiring correction for a competing process of electron recombination with molecular cations produced in reaction between Ar{sup +} and propargyl chloride and subsequent ion-molecule reactions. The electron attachment rate coefficient was measured to be 1.6x10{sup -10} cm{sup 3} s{sup -1} at 305 K and increased to 1.1x10{sup -9} cm{sup 3} s{sup -1} at 540 K.

  3. Dopant and carrier concentration in silicon, in equilibrium with SiP precipitates

    SciTech Connect

    Solmi, S.; Parisini, A.; Armigliato, A.; Angelucci, R.


    The methods recently reported to study the equilibria hi the Si-As system, were extended to the Si-P. On this line the behaviour of Silicon slices very heavily implanted with 1.5 x 10{sup 17} P{sup +}/cm{sup 2}, was followed by transmission electron microscopy (TEM) and secondary neutral mass spectrometry (SNMS) after annealing at 800, 850, 900 and 1000 C. Precipitation of large monoclinic, and partially orthorhombic, SiP takes place hi the most heavily doped region. From the shape of the SNMS profiles in the dissolution stage of these precipitates, we determined for the First time, the concentration C{sub e} of P hi equilibrium with the conjugate phase: C. = 2.45 x 10{sup 23} exp (- 0.62/ kT) cm{sup -3}, were kT is in eV.

  4. Surface transfer doping of diamond by MoO{sub 3}: A combined spectroscopic and Hall measurement study

    SciTech Connect

    Russell, Stephen A. O. Crawford, Kevin G.; Moran, David A. J.; Cao, Liang; Qi, Dongchen; Tallaire, Alexandre; Wee, Andrew T. S.


    Surface transfer doping of diamond has been demonstrated using MoO{sub 3} as a surface electron acceptor material. Synchrotron-based high resolution photoemission spectroscopy reveals that electrons are transferred from the diamond surface to MoO{sub 3}, leading to the formation of a sub-surface quasi 2-dimensional hole gas within the diamond. Ex-situ electrical characterization demonstrated an increase in hole carrier concentration from 1.00 × 10{sup 13}/cm{sup 2} for the air-exposed hydrogen-terminated diamond surface to 2.16 × 10{sup 13}/cm{sup 2} following MoO{sub 3} deposition. This demonstrates the potential to improve the stability and performance of hydrogen-terminated diamond electronic devices through the incorporation of high electron affinity transition metal oxides.

  5. Measurement of the ozone absorption cross-section at the 253. 7 nm Mercury line

    SciTech Connect

    Mauersberger, K.; Barnes, J.; Hanson, D.; Morton, J.


    The absorption cross-section of ozone at 253.7 nm is frequently used as a standard for the entire UV wavelength range. The presently accepted value is 1.147 x 10/sup -17/ cm/sup 2/, known with an uncertainty of about 2%. The cross-section has been recently measured by simultaneously monitoring the ozone pressure, the impurities in the ozone gas, the gas temperature and the UV beam intensity. The cross-section at room temperature was found to be 1.137 x 10/sup -17/ cm/sup 2/, having an uncertainty of +- .7%. The improved accuracy will aid a number of ozone experiments including the i-italicn-italic s-italici-italict-italicu-italic photometers and Solar Backscatter Ultraviolet instruments.

  6. Radiation field from an extended planar-anode on HERMES III

    SciTech Connect

    Sanford, T.W.L.; Halbleib, J.A.; Poukey, J.W.; Beutler, D.E.; Carlson, G.A.; Baldwin, G.T.; Sheriden, T.; Mock, R.; Klinger, R.S.; Knott, D.P. )


    The bremsstrahlung field from an extended planar-anode diode with an annular cathode tip on the 16-TW HERMES III electron accelerator is measured and compared with predictions. Measurements confirm predictions and demonstrate that the diode provides a versatile large-area source of gamma radiation. Versatility is obtained by adjustment of the anode-cathode gap, which affects electron trajectories while simultaneously maintaining constant diode impedance. The adjustment permits the generation of average dose rates from about 1.2 {times} 10{sup 12} rad/s over 3100 cm{sup 2} to about 5.6 {times} 10{sup 12} rad/s over 700 cm{sup 2}, without destruction of the bremsstrahlung target.

  7. High flux of relativistic electrons produced in femtosecond laser-thin foil target interactions: Characterization with nuclear techniques

    SciTech Connect

    Gerbaux, M.; Gobet, F.; Aleonard, M. M.; Hannachi, F.; Malka, G.; Scheurer, J. N.; Tarisien, M.; Claverie, G.; Meot, V.; Morel, P.


    We present a protocol to characterize the high energy electron beam emitted in the interaction of an ultraintense laser with matter at intensities higher than 10{sup 19} W cm{sup -2}. The electron energies and angular distributions are determined as well as the total number of electrons produced above a 10 MeV threshold. This protocol is based on measurements with an electron spectrometer and nuclear activation techniques, combined with Monte Carlo simulations based on the GEANT3 code. The method is detailed and exemplified with data obtained with polypropylene and copper thin solid targets at a laser intensity of 2x10{sup 19} W cm{sup -2}. Special care is taken of the different sources of uncertainties. In particular, the reproducibility of the laser shots is considered.

  8. Characterization of ι-carrageenan and its derivative based green polymer electrolytes

    SciTech Connect

    Jumaah, Fatihah Najirah; Mobaraka, Nadhratun Naiim; Ahmad, Azizan; Ramli, Nazaruddin


    The new types of green polymer electrolytes based on ι-carrageenan derivative have been prepared. ι-carrageenan act as precursor was reacted with monochloroacetic acid to produce carboxymethyl ι-carrageenan. The powders were characterized by Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy and {sup 1}H nuclear magnetic resonance (NMR) to confirm the substitution of targeted functional group in ι-carrageenan. The green polymer electrolyte based on ι-carrageenan and carboxymethyl ι-carrageenan was prepared by solution-casting technique. The films were characterized by electrochemical impedance spectroscopy to determine the ionic conductivity. The ionic conductivity ι-carrageenan film were higher than carboxymethyl ι-carrageenan which 4.87 ×10{sup −6} S cm{sup −1} and 2.19 ×10{sup −8} S cm{sup −1}, respectively.

  9. Thick amorphous silicon layers suitable for the realization of radiation detectors

    SciTech Connect

    Hong, Wan-Shick; Drewery, J.S.; Jing, Tao; Lee, Hyong-Koo; Perez-Mendez, V.; Petrova-Koch, V.


    Thick silicon films with good electronic quality have been prepared by glow discharge of He-diluted SiH{sub 4} at a substrate temperature {approximately} 150{degree}C and subsequent annealing at 160{degree}C for about 100 hours. The stress in the films obtained this way decreased to {approximately} 100 MPa compared to the 350 MPa in conventional a-Si:H. The post-annealing helped to reduce the ionized dangling bond density from 2.5 {times} 10{sup 15} cm{sup {minus}3} to 7 {times} 10{sup 14} cm{sup {minus}3} without changing the internal stress. IR spectroscopy and hydrogen effusion measurements implied the existence of microvoids and tiny crystallites in the material showing satisfactory electronic properties. P-I-N diodes for radiation detection applications have been realized out of the new material.

  10. Results from the Cryogenic Dark Matter Search at Soudan Underground Laboratory

    SciTech Connect

    Yoo, Jonghee; /Fermilab


    We present results from the Cryogenic Dark Matter Search at Soudan Underground Laboratory for two-tower arrays of detector. Twelve detectors were operated from March 25 to August 8, 2004, or 74.5 detector live days.Within expected background, no statistically significant indication of a WIMP signal was observed. Based on this null observation and combined with our previous results, we exclude a spin-averaged WIMP-nucleon interaction cross section above 1.6 x 10{sup -43} cm{sup 2} for Ge detectors, and 3 x 10{sup -42} cm{sup 2} for Si detectors, for a WIMP mass 60GeV/c{sup 2} with 90%C.L. This result constrains parameter space of minimal supersymmetric standard models (MSSM) and starts to reach the parameter space of a constrained model (CMSSM).

  11. Continuous wave cavity ring-down spectroscopy for velocity distribution measurements in plasma

    SciTech Connect

    McCarren, D.; Scime, E.


    We report the development of a continuous wave cavity ring-down spectroscopic (CW-CRDS) diagnostic for real-time, in situ measurement of velocity distribution functions of ions and neutral atoms in plasma. This apparatus is less complex than conventional CW-CRDS systems. We provide a detailed description of the CW-CRDS apparatus as well as measurements of argon ions and neutrals in a high-density (10{sup 9} cm{sup −3} < plasma density <10{sup 13} cm{sup −3}) plasma. The CW-CRDS measurements are validated through comparison with laser induced fluorescence measurements of the same absorbing states of the ions and neutrals.

  12. Enhanced hard x-ray emission from microdroplet preplasma

    SciTech Connect

    Anand, M.; Kahaly, S.; Ravindra Kumar, G.; Krishnamurthy, M.; Sandhu, A.S.; Gibbon, P.


    We perform a comparative study of hard x-ray emission from femtosecond laser plasmas in 15 {mu}m methanol microdroplets and Perspex target. The hard x-ray yield from droplet plasmas is {approx_equal}68 times more than that obtained from solid plasmas at 2x10{sup 15} W cm{sup -2}. A 10 ns prepulse at about 5% of the main pulse appears to be essential for hard x-ray generation from droplets. Hot electron temperature of 36 keV is measured from the droplets at 8x10{sup 14} W cm{sup -2}, whereas a three times higher intensity is needed to obtain similar hot electron temperatures from Perspex plasmas. Particle-in-cell simulations with very long scale-length density profiles support experimental observations.


    SciTech Connect

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S


    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  14. Supercontinuum generation in thulium-doped fibres

    SciTech Connect

    Kurkov, Andrei S; Kamynin, V A; Tsvetkov, V B; Sadovnikova, Ya E; Marakulin, A V; Minashina, L A


    Supercontinuum generation in thulium-doped fibres under pumping at 1.59 {mu}m is investigated. Amplification of supercontinuum in the range of 1.8--2.0 {mu}m is found for a fibre doped to a level of 2 Multiplication-Sign 10{sup 19} cm{sup -3}. For a fibre with an activator concentration of 2 Multiplication-Sign 10{sup 20} cm{sup -3} amplification is also observed in the (2.1 - 2.45)-{mu}m band, which suggests the occurrence of the {sup 3}H{sub 4} {yields} {sup 3}H{sub 5} optical transition in the fibre. The occupation of the {sup 3}H{sub 4} level can be explained by cooperative effects. (optical fibres, lasers and amplifiers. properties and applications)

  15. Ion Implanted Ge:B Far Infrard Blocked Impurity BandDetectors

    SciTech Connect

    Beeman, J.W.; Goyal, S.; Reichertz, L.A.; Haller, E.E.


    Ge Blocked Impurity Band (BIB) photoconductors have the potential to replace stressed Ge:Ga photoconductors for far-infrared astronomical observations. A novel planar BIB device has been fabricated in which ion-implanted boron is used to form the blocking and absorbing layers of necessary purity and compensation. The effect of doping in the infrared active layer on the far-infrared photoconductive response has been studied, and the optimum doping concentration is found to be {approx} 4 x 10{sup 16} cm{sup -3}. Devices doped near this concentration show good blocking characteristics with low dark currents. The spectral response extends to {approx} 45 cm{sup -1}, clearly showing the formation of an impurity band. Under low background testing conditions these devices attain a responsivity of 0.12 A/W and NEP of 5.23 x 10{sup -15} W/Hz{sup -1/2}.

  16. Molecular beam epitaxy of n-Zn(Mg)O as a low-damping plasmonic material at telecommunication wavelengths

    SciTech Connect

    Sadofev, Sergey; Kalusniak, Sascha; Schaefer, Peter; Henneberger, Fritz


    We demonstrate that Zn(Mg)O:Ga layers can be grown by molecular beam epitaxy in a two-dimensional mode with high structural perfection up to Ga mole fractions of about 6.5%. The doping efficiency is practically 100% so that free-carrier concentrations of almost 10{sup 21} cm{sup -3} can be realized providing a zero-crossover wavelength of the real part of the dielectric function as short as 1.36 {mu}m, while the plasmonic damping does not exceed 50 meV. Structural, electrical, and optical data consistently demonstrate a profound change of the Ga incorporation mode beyond concentrations of 10{sup 21} cm{sup -3} attended by deterioration of the plasmonic features.

  17. Isothermal transient current studies in cellulose acetate films

    SciTech Connect

    Kumar, A.; Nath, R.


    Step voltage transient current studies have been made in cellulose acetate films as a function of field and thickness. A logarithmic plot (Scherr-Montroll plot) of the transient current vs. time gives a knee at a time t/sub T/, which is interpreted as the transit time of the charge carrier. The value of the carrier mobility has been estimated to be 3.9 X 10/sup -9/ cm/sup 2/.V/sup -1/.s/sup -1/ in cellulose acetate film. The carrier mobility in iodine-doped (2% w/w) cellulose acetate film has also been determined from Scher-Montroll plot and is found to be 3.3 X 10/sup -7/ cm/sup 2/.V/sup -1/.s/sup -1/.

  18. Ideal Laser-Beam Propagation through High-Temperature Ignition Hohlraum Plasmas

    SciTech Connect

    Froula, D. H.; Divol, L.; Meezan, N. B.; Dixit, S.; Moody, J. D.; Neumayer, P.; Pollock, B. B.; Ross, J. S.; Glenzer, S. H.


    We demonstrate that a blue (3{omega}, 351 nm) laser beam with an intensity of 2x10{sup 15} W cm{sup -2} propagates nearly within the original beam cone through a millimeter scale, T{sub e}=3.5 keV high density (n{sub e}=5x10{sup 20} cm{sup -3}) plasma. The beam produced less than 1% total backscatter at these high temperatures and densities; the resulting transmission is greater than 90%. Scaling of the electron temperature in the plasma shows that the plasma becomes transparent for uniform electron temperatures above 3 keV. These results are consistent with linear theory thresholds for both filamentation and backscatter instabilities inferred from detailed hydrodynamic simulations. This provides a strong justification for current inertial confinement fusion designs to remain below these thresholds.

  19. Observation of relativistic effects in collective Thomson scattering

    SciTech Connect

    Ross, J S; Glenzer, S H; Palastro, J P; Pollock, B B; Price, D; Divol, L; Tynan, G R; Froula, D H


    We observe relativistic modifications to the Thomson scattering spectrum in a traditionally classical regime: v{sub osc}/c = eE{sub 0}/cm{omega}{sub 0} << 1 and T{sub e} < 1 keV. The modifications result from scattering off electron-plasma fluctuations with relativistic phase velocities. Normalized phase velocities v/c between 0.03 and 0.12 have been achieved in a N{sub 2} gas-jet plasma by varying the plasma density from 3 x 10{sup 18} cm{sup -3} to 7 x 10{sup 19} cm{sup -3} and electron temperature between 85 eV and 700 eV. For these conditions, the complete temporally resolved Thomson scattering spectrum including the electron and ion features has been measured. A fully relativistic treatment of the Thomson scattering form factor has been developed and shows excellent agreement with the experimental data.

  20. Experimental investigations in particle physics at intermediate energies. [Annual] performance report, December 1, 1991--November 30, 1992

    SciTech Connect

    Auerbach, L.B.; Highland, V.L.; McFarlane, K.W.; Kettell, S.H.


    The major emphasis of this project continues to be on fundamental symmetries and parameters of the Standard Model. A test of a quark model prediction was also done. The projects in the current period have been the following: LSND, a neutrino oscillation experiment at LAMPF; E791, a search for the decays K{sub L}{sup 0} {yields} {mu}e and K{sub L}{sup 0} {yields} ee; E871, tests and preparations for an upgrade proposal; and E888, a search for the H dibaryon. The LSND (Large Scintillator Neutrino Detector) is under construction at this time. Progress in the construction schedule has been accelerated with the expectation of being ready to accept beam in March 1993. The automated system for testing photomultiplier tubes is in full production, and should be able to certify a fun complement of tubes for installation by October 1992. Results of an earlier LAMPF experiment, E764, on the interaction of muon neutrinos with carbon nuclei have been submitted for publication. A thorough `blind` analysis of the E791 data set has just been brought to completion. Final results for the upper limits (90% C.L.) on the branching ratios for the decays K{sub L}{sup 0} {yields} {mu}e and K{sub L}{sup 0} {yields} ee are 3.3 {times} 10{sup {minus}11} and 4.1 {times} 10{sup {minus}11}, respectively. The final result for the branching ratio for K{sub L}{sup 0} {yields} {mu}{mu} from all the data (720 events) is (7.0 {plus_minus} 0.4 {plus_minus} 0.2) {times} 10{sup {minus}9}. The potential of the E791 detector for rare K decays has reached its limit. Before disassembly it was used to mount a search (E888) for a possible long-lived six-quark state, the H. At the same time studies have been made of an upgraded version of the experiment (E871) that will make use of a portion of the existing apparatus.

  1. Experimental investigations in particle physics at intermediate energies. [Physics Dept. , Temple Univ

    SciTech Connect

    Auerbach, L.B.; Highland, V.L.; McFarlane, K.W.; Kettell, S.H.


    The major emphasis of this project continues to be on fundamental symmetries and parameters of the Standard Model. A test of a quark model prediction was also done. The projects in the current period have been the following: LSND, a neutrino oscillation experiment at LAMPF; E791, a search for the decays K{sub L}{sup 0} {yields} {mu}e and K{sub L}{sup 0} {yields} ee; E871, tests and preparations for an upgrade proposal; and E888, a search for the H dibaryon. The LSND (Large Scintillator Neutrino Detector) is under construction at this time. Progress in the construction schedule has been accelerated with the expectation of being ready to accept beam in March 1993. The automated system for testing photomultiplier tubes is in full production, and should be able to certify a fun complement of tubes for installation by October 1992. Results of an earlier LAMPF experiment, E764, on the interaction of muon neutrinos with carbon nuclei have been submitted for publication. A thorough 'blind' analysis of the E791 data set has just been brought to completion. Final results for the upper limits (90% C.L.) on the branching ratios for the decays K{sub L}{sup 0} {yields} {mu}e and K{sub L}{sup 0} {yields} ee are 3.3 {times} 10{sup {minus}11} and 4.1 {times} 10{sup {minus}11}, respectively. The final result for the branching ratio for K{sub L}{sup 0} {yields} {mu}{mu} from all the data (720 events) is (7.0 {plus minus} 0.4 {plus minus} 0.2) {times} 10{sup {minus}9}. The potential of the E791 detector for rare K decays has reached its limit. Before disassembly it was used to mount a search (E888) for a possible long-lived six-quark state, the H. At the same time studies have been made of an upgraded version of the experiment (E871) that will make use of a portion of the existing apparatus.

  2. Coupled chemical and diffusion model for compacted bentonite

    SciTech Connect

    Olin, M.; Lehikoinen, J.; Muurinen, A.


    A chemical equilibrium model has been developed for ion-exchange and to a limited extent for other reactions, such as precipitation or dissolution of calcite or gypsum, in compacted bentonite water systems. The model was successfully applied to some bentonite experiments, especially as far as monovalent ions were concerned. The fitted log-binding constants for the exchange of sodium for potassium, magnesium, and calcium were 0.27, 1.50, and 2.10, respectively. In addition, a coupled chemical and diffusion model has been developed to take account of diffusion in pore water, surface diffusion and ion-exchange.d the model was applied to the same experiments as the chemical equilibrium model, and its validation was found partly successful. The above values for binding constants were used also in the coupled model. The apparent (both for anions and cations) and surface diffusion (only for cations) constants yielding the best agreement between calculated and experimental data were 3.0 {times} 10{sup {minus}11} m{sup 2}/s and 6.0 {times} 10{sup {minus}12} m{sup 2}/s, respectively. These values are questionable, however, as experimental results good enough for fitting are currently not available.

  3. Contamination from sand-bentonite seal in monitoring wells installed in aquitards

    SciTech Connect

    Remenda, V.H.; Kamp, G. van der


    A six year field experiment has shown that a sand-bentonite mixture used to seal monitoring wells in aquitards contributes solutes to the ground water sampled from these wells. Monitoring wells were installed at field sites with hydraulic conductivity (K) ranging from 5 {times} 10{sup {minus}9} m/s to 3 {times} 10{sup {minus}11} m/s. In most cases the boreholes remained dry during installation which allowed the placement of a dry powdered bentonite/sand mixture tagged with potassium bromide (KBr) to seal and separate sampling points. Over six years, wells were sampled periodically and ground-water samples were analyzed for Br and Cl and other major ions. Typical Br results ranged from 10 mg/l to 35 mg/l in the first 700 days, as compared to an estimated initial concentration in the seal material of about 75 mg/l. After six years the bromide concentrations had decreased to between 3 mg/l and 5 mg/l. The total mass of Br removed in six years is less than 50% of that placed; therefore the contamination effects, although considerably diminished, persist. The trends of Br, Cl, Na, and SO{sub 4} indicate that varying degrees of contamination occur. These data show that the materials used to seal monitoring wells in aquitards can have a significant and long-lasting impact on the chemistry of the water in the wells.

  4. Measurements of the helium propagation at 4.4 K in a 480 m long stainless steel pipe

    SciTech Connect

    Hseuh, H.C.; Wallen, E.


    The Relativistic Heavy Ion Collider (RHIC), with two concentric rings 3.8 km in circumference, uses superconducting magnets to focus the high energy beams. Each sextant of RHIC will have continuous cryostats up to 480 m in length housing the magnets and the cold beam pipes. For an acceptable lifetime of the stored beam, the pressure in the cold beam pipe will be < 10{sup {minus}11} Torr. The characteristics of He pressure front propagation due to He leaks will be of importance for beam lifetimes and for vacuum monitoring due to the high vapor pressure of He at 4.4 K, even with small surface coverage. The travel of the He pressure fronts along a 480 m long, 6.9 cm I.D. stainless steel beam pipe cooled to 4.4 K has recently been measured during the RHIC first sextant test. The experiment was carried out over a 12-day period by bleeding in a calibrated He leak of 3 {times} 10{sup {minus}5} Torr{center_dot}l/s (20 C) while measuring the He pressures along this 480 m cold tube at {approximately} 30 m intervals. The measured speed of the pressure fronts and the pressure profiles are summarized and compared with the calculated ones.

  5. Measurements of the helium propagation at 4.4 K in a 480 m long stainless steel pipe

    SciTech Connect

    Hseuh, H.C.; Wallen, E.


    The relativistic heavy ion collider (RHIC), with two concentric rings 3.8 km in circumference, uses superconducting magnets to focus the high energy beams. Each sextant of RHIC will have continuous cryostats up to 480 m in length housing the magnets and the cold beam pipes. For an acceptable lifetime of the stored beam, the pressure in the cold beam pipe will be {lt}10{sup {minus}11} Torr. The characteristics of He pressure front propagation due to He leaks will be of importance for beam lifetimes and for vacuum monitoring due to the high vapor pressure of He at 4.4 K, even with small surface coverage. The travels of the He pressure fronts along a 480 m long, 6.9 cm I.D. stainless steel beam pipe cooled to 4.4 K have recently been measured during the RHIC first sextant test. The experiment was carried out over a 12-day period by bleeding in a calibrated He leak of 3{times}10{sup {minus}5}Torrl/s (20{degree}C) while measuring the He pressures along this 480 m cold tube at approximately 30 m intervals. The measured speed of the pressure fronts and the pressure profiles are summarized and compared with the calculated ones. {copyright} {ital 1998 American Vacuum Society.}


    SciTech Connect

    Zack, L. N.; Ziurys, L. M.


    Observations of CO, HCO{sup +}, and H{sub 2}CO have been carried out at nine positions across the Helix Nebula (NGC 7293) using the Submillimeter Telescope and the 12 m antenna of the Arizona Radio Observatory. Measurements of the J = 1 {yields} 0, 2 {yields} 1, and 3 {yields}2 transitions of CO, two transitions of HCO{sup +} (J = 1 {yields} 0 and 3 {yields}2), and five lines of H{sub 2}CO (J{sub Ka,Kc} = 1{sub 0,1} {yields} 0{sub 0,0}, 2{sub 1,2} {yields} 1{sub 1,1}, 2{sub 0,2} {yields} 1{sub 0,1}, 2{sub 1,1} {yields} 1{sub 1,0}, and 3{sub 0,3} {yields}2{sub 0,2}) were conducted in the 0.8, 1, 2, and 3 mm bands toward this highly evolved planetary nebula. HCO{sup +} and H{sub 2}CO were detected at all positions, along with three transitions of CO. From a radiative transfer analysis, the kinetic temperature was found to be T{sub K} {approx} 15-40 K across the Helix with a gas density of n(H{sub 2}) {approx} 0.1-5 Multiplication-Sign 10{sup 5} cm{sup -3}. The warmer gas appears to be closer to the central star, but high density material is distributed throughout the nebula. For CO, the column density was found to be N{sub tot} {approx} 0.25-4.5 Multiplication-Sign 10{sup 15} cm{sup -2}, with a fractional abundance of f (CO/H{sub 2}) {approx} 0.3-6 Multiplication-Sign 10{sup -4}. Column densities for HCO{sup +} and H{sub 2}CO were determined to be N{sub tot} {approx} 0.2-5.5 Multiplication-Sign 10{sup 11} cm{sup -2} and 0.2-1.6 Multiplication-Sign 10{sup 12} cm{sup -2}, respectively, with fractional abundances of f (HCO{sup +}/H{sub 2}) {approx} 0.3-7.3 Multiplication-Sign 10{sup -8} and f (H{sub 2}CO/H{sub 2}) {approx} 0.3-2.1 Multiplication-Sign 10{sup -7}-several orders of magnitude higher than predicted by chemical models. Polyatomic molecules in the Helix appear to be well-protected from photodissociation and may actually seed the diffuse interstellar medium.

  7. Good electrical contacts for high resistivity (Cd,Mn)Te crystals

    SciTech Connect

    Witkowska-Baran,M.; Mycielski, A.; Kochanowska, D.; Szadkowski, A. J.; Jakiela, r.; Witkowska, B.; Kaliszek, W.; Domagala, J.; Lusakowska, E.; Domukhovski, V.; Dybko, K.; Cui, Y.; James, R. B.


    We consider that semi-insulating (Cd,Mn)Te crystals may well successfully replace the commonly used (Cd,Zn)Te crystals as a material for manufacturing large-area X- and gamma-ray detectors. The Bridgman growth method yields good quality and high-resistivity (10{sup 9}-10{sup 10} {Omega}-cm) crystals of (Cd,Mn)Te:V. Doping with vanadium ({approx} 10{sup 16} cm{sup -3}), which acts as a compensating agent, and annealing in cadmium vapors, which reduces the number of cadmium vacancies in the as-grown crystal, ensure this high resistivity. Detector applications of the crystals require satisfactory electrical contacts. Hence, we explored techniques of ensuring good electrical contacts to semi-insulating (Cd,Mn)Te crystals. Our findings are reported here. Before depositing the contact layers, we prepared an 'epi-ready' surface of the crystal platelet by a procedure described earlier for various tellurium-based II-VI compound crystals. A molecular beam epitaxy (MBE) apparatus was used to deposit various types of contact layers: Monocrystalline semiconductor layers, amorphous- and nanocrystalline semiconductor layers, and metal layers were studied. We employed ZnTe heavily doped ({approx} 10{sup 18} cm{sup -3}) with Sb, and CdTe heavily doped ({approx} 10{sup 17} cm{sup -3}) with In as the semiconductors to create contact layers that subsequently enable good contact (with a narrow, tunneling barrier) to the Au layer that usually is applied as the top contact layer. We describe and discuss the technology and some properties of the electrical contacts to semi-insulating (Cd,Mn)Te.

  8. Methods for passivating silicon devices at low temperature to achieve low interface state density and low recombination velocity while preserving carrier lifetime


    Chen, Zhizhang; Rohatgi, Ajeet


    A new process has been developed to achieve a very low SiO.sub.x /Si interface state density, low recombination velocity S (<2 cm/s), and high effective carrier lifetime T.sub.eff (>5 ms) for oxides deposited on silicon substrates at low temperature. The technique involves direct plasma-enhanced chemical vapor deposition (PECVD), with appropriate growth conditions, followed by a photo-assisted rapid thermal annealing (RTA) process. Approximately 500-A-thick SiO.sub.x layers are deposited on Si by PECVD at C. with 0.02 W/cm.sup.-2 rf power, then covered with SiN or an evaporated thin aluminum layer, and subjected to a photo-assisted anneal in forming gas ambient at C., resulting in an interface state density in the range of about 1-4.times.10.sup.10 cm.sup.-2 eV.sup.-1, which sets a record for the lowest interface state density for PECVD oxides fabricated to date. Detailed analysis shows that the PECVD deposition conditions, photo-assisted anneal, forming gas ambient, and the presence of an aluminum layer on top of the oxides during the anneal, all contributed to this low value of interface state density Detailed metal-oxide semiconductor analysis and model calculations show that such a low recombination velocity S is the result of moderately high positive oxide charge (5.times.10.sup.11 -1.times.10.sup.12 cm.sup.-2) and relatively low midgap interface state density (1.times.10.sup.10 -4.times.10.sup.10 cm.sup.-2 eV.sup.-1). Photo-assisted anneal was found to be superior to furnace annealing, and a forming gas ambient was better than a nitrogen ambient for achieving a very low surface recombination velocity S.


    SciTech Connect

    Goodman, Michael L.; Judge, Philip G. E-mail:


    An MHD model of a hydrogen plasma with flow, an energy equation, NLTE ionization and radiative cooling, and an Ohm's law with anisotropic electrical conduction and thermoelectric effects is used to self-consistently generate atmospheric layers over a 50 km height range. A subset of these solutions contains current sheets and has properties similar to those of the lower and middle chromosphere. The magnetic field profiles are found to be close to Harris sheet profiles, with maximum field strengths {approx}25-150 G. The radiative flux F{sub R} emitted by individual sheets is {approx}4.9 Multiplication-Sign 10{sup 5}-4.5 Multiplication-Sign 10{sup 6} erg cm{sup -2} s{sup -1}, to be compared with the observed chromospheric emission rate of {approx}10{sup 7} erg cm{sup -2} s{sup -1}. Essentially all emission is from regions with thicknesses {approx}0.5-13 km containing the neutral sheet. About half of F{sub R} comes from sub-regions with thicknesses 10 times smaller. A resolution {approx}< 5-130 m is needed to resolve the properties of the sheets. The sheets have total H densities {approx}10{sup 13}-10{sup 15} cm{sup -3}. The ionization fraction in the sheets is {approx}2-20 times larger, and the temperature is {approx}2000-3000 K higher than in the surrounding plasma. The Joule heating flux F{sub J} exceeds F{sub R} by {approx}4%-34%, the difference being balanced in the energy equation mainly by a negative compressive heating flux. Proton Pedersen current dissipation generates {approx}62%-77% of the positive contribution to F{sub J} . The remainder of this contribution is due to electron current dissipation near the neutral sheet where the plasma is weakly magnetized.

  10. Experimental and theoretical study of the ion-ion mutual neutralization reactions Ar{sup +}+SF{sub n}{sup -} (n=6, 5, and 4)

    SciTech Connect

    Bopp, Joseph C.; Miller, Thomas M.; Viggiano, Albert A.; Troe, Juergen


    The ion-ion mutual neutralization reactions Ar{sup +}+SF{sub n}{sup -}{yields}Ar+SF{sub n} (n=6, 5, and 4) have been studied in a flowing afterglow-Langmuir probe (FALP) apparatus at 300 K and 1 Torr of He buffer gas. Electron concentrations and product ion fractions were measured, and neutralization rate constants of 4.0x10{sup -8}, 3.8x10{sup -8}, and 4x10{sup -8} cm{sup 3} s{sup -1} for SF{sub 6}{sup -}, SF{sub 5}{sup -}, and SF{sub 4}{sup -}, respectively, were derived, with uncertainties of {+-}25% ({+-}35% for SF{sub 4}{sup -}). During the neutralization process, excited neutrals are generated that are able to dissociate to neutral fragments. In the case of SF{sub 6}, the formation of SF{sub 5} and SF{sub 4}, and similarly in the case of SF{sub 5}, the formation of SF{sub 4} and SF{sub 3} were observed and quantified. The mechanism of primary and secondary reaction was analyzed in detail, and rate constants for the dissociative electron attachments e{sup -}+SF{sub 5}{yields}F{sup -}+SF{sub 4} (k=3x10{sup -9} cm{sup 3} s{sup -1},{+-}40%) and e{sup -}+SF{sub 3}{yields}F{sup -}+SF{sub 2} (k=2x10{sup -8} cm{sup 3} s{sup -1},+400%,-75%) were also derived. The experimental ion-ion neutralization rate constants were found to be in good agreement with estimates from an optimum two-state double-passage Landau-Zener model. It was also found that energy partitioning in the neutralization is related to the extent of electronic excitation of Ar generated by the electron transfer processes.

  11. Compact Magneto-optical Trap for Rubidium Atoms

    SciTech Connect

    Chapovsky, P.L.


    The characteristics of a magneto-optical trap (MOT) using small-diameter cooling laser beams are considered. Trapping and cooling of Rb atoms from the surrounding gas of warm atoms takes place in the trap. A compact (140 {mu}m) and stable atomic cloud is obtained with a density of 7 x 10{sup 10} cm{sup -3}, which is three orders of magnitude higher than the density of the surrounding gas.

  12. Photodetectors based on CuInS{sub 2}

    SciTech Connect

    Bulyarsky, S. V. Vostretsova, L. N.; Gavrilov, S. A.


    It is shown that the processes of charge-carrier transport, which determine the “dark” current–voltage characteristics of photodetectors based on CuInS{sub 2} and, consequently, the efficiency of light conversion, are of the tunneling–recombination type. These processes occur via electronic states within the band gap with an activation energy of 0.2 eV and a concentration on the order of 8 × 10{sup 16} cm{sup –2}.

  13. Confinement scaling and ignition in tokamaks

    SciTech Connect

    Perkins, F.W.; Sun, Y.C.


    A drift wave turbulence model is used to compute the scaling and magnitude of central electron temperature and confinement time of tokamak plasmas. The results are in accord with experiment. Application to ignition experiments shows that high density (1 to 2) . 10/sup 15/ cm/sup -3/, high field, B/sub T/ > 10 T, but low temperature T approx. 6 keV constitute the optimum path to ignition.

  14. Highly ionized plasma plume generation by long-pulse CO/sub 2/ laser irradiation of solid targets in strong axial magnetic fields

    SciTech Connect

    Hoffman, A L; Crawford, E A


    The present work utilizes high f number optics and is directed primarily at controlling the conditions in the magnetically confined plume. Typically, fully ionized carbon plasmas have been produced with 10/sup 18/ cm/sup -3/ electron densities and 100 to 150 eV electron temperatures. These carbon plasmas have been doped with high Z atoms in order to study ionization and emission rates at the above conditions.

  15. Are cosmic rays modulated beyond the heliopause?

    SciTech Connect

    Kóta, J.; Jokipii, J. R.


    We discuss the possible spatial variation of Galactic and anomalous cosmic rays (GCRs and ACRs) at and beyond the heliopause (HP). Remaining within the framework of the Parker transport equation and assuming incompressible plasma in the heliosheath, we consider highly idealized simple-flow models and compare our GCR results with recent publications of Scherer et al. and Strauss et al. First, we discuss an order-of-magnitude estimate and a simple spherical model to demonstrate that the modulation of GCRs beyond the HP must be quite small if the diffusion coefficient beyond the HP is greater than ≈10{sup 26} cm{sup 2} s{sup –1}, a value that is two orders of magnitude smaller than the value of 10{sup 28} cm{sup 2} s{sup –1} determined from observations of GCR composition. Second, we construct a non-spherical model, which allows lateral deflection of the flow and uses different diffusion coefficients parallel and perpendicular to the magnetic field. We find that modulation of GCRs beyond the HP remains small even if the perpendicular diffusion coefficient beyond the HP is quite small (≈10{sup 22} cm{sup 2} s{sup –1}) as long as the parallel diffusion is sufficiently fast. We also consider the case when the parallel diffusion beyond the HP is fast, but the perpendicular diffusion is as small as ≈10{sup 20} cm{sup 2} s{sup –1}; this results in a sharp, almost step-like increase of GCR flux (and decrease of ACRs) at the HP. Possible implications are briefly discussed. We further suggest the possibility that the observed sharp gradient of GCRs at the HP might push the HP closer to the Sun than previously thought.

  16. The Fermilab Main Injector: current status and future

    SciTech Connect

    Bhat, C.M.


    The Fermilab Main Injector is a 8-150 GeV proton synchrotron being built as a high intensity injector to the Tevatron. The design incorporates many novel features to achieve {ital p{anti p}} luminosity in the Tevatron exceeding 8 x 10{sup 31} cm{sup -2}sec{sup -1}. An overview of the Main Injector project, current status and future prospects will be discussed.

  17. Absolute excited-state absorption cross section and fluorescence quantum efficiency of Cr/sup 3 +/: gadolinium scandium gallium garnet

    SciTech Connect

    Seelert, W.; Strauss, E.


    Excited-state properties of the laser material Cr/sup 3 +/:Gd/sub 3/Sc/sub 2/(GaO/sub 4/)/sub 3/ were determined by a photocaloric technique. The excited-state absorption cross section at 650 nm is (3.6 +- 0.6)10/sup -20/ cm/sup 2/, and the fluorescence quantum efficiency at ambient temperature is (91 +- 1)%.

  18. Improved dot size uniformity and luminescense of InAs quantum dots on InP substrate

    NASA Technical Reports Server (NTRS)

    Qiu, Y.; Uhl, D.


    InAs self-organized quantum dots have been grown in InGaAs quantum well on InP substrates by metalorganic vapor phase epitaxy. Atomic Force Microscopy confirmed of quantum dot formation with dot density of 3X10(sup 10) cm(sup -2). Improved dot size uniformity and strong room temperature photoluminescence up to 2 micron were observed after modifying the InGaAs well.

  19. Poloidal OHMIC heating in a multipole

    SciTech Connect

    Holly, D.J.


    The feasibility of using poloidal currents to heat plasmas confined by a multipole field has been examined experimentaly in Tokapole II. The machine is operated as a toroidal octupole, with a time-varying toroidal magnetic field driving poloidal plasma currents I/sub plasma/ - 20 kA to give densities n/sub e/ - 10/sup 13/ cm/sup -3/ and temperatures T/sub e/ - 30 eV.

  20. Physics of a high-luminosity Tau-Charm Factory

    SciTech Connect

    King, M.E.


    This paper highlights the physics capabilities of a Tau-Charm Factory; i.e., high luminosity ({approximately}10{sup 33}cm{sup {minus}2}s{sup {minus}1}) e{sup +}e{sup {minus}} collider operating in the center-of-mass energy range of 3-5 GeV, with a high-precision, general-purpose detector. Recent developments in {tau} and charm physics are emphasized.


    SciTech Connect



    A high-energy CO{sub 2} laser is channeled in a capillary discharge. Occurrence of guiding conditions at a relatively low plasma density (<10{sup 18} cm{sup -3}) is confirmed by MHD simulations. Divergence of relativistic electron beam changes depending on the plasma density. Counter-propagation of the electron and laser beams inside the plasma channel results in intense x-ray generation.

  2. Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries

    SciTech Connect

    Zhang, Pengfei; Li, Mingtao; Jiang, Xueguang; Fang, Youxing; Veith, Gabriel M.; Sun, Xiao-Guang; Dai, Sheng


    Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10<sup>-3 S cm>-1 at 22 °C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.

  3. Phosphorus doping of 4H SiC by liquid immersion excimer laser irradiation

    SciTech Connect

    Ikeda, Akihiro; Nishi, Koji; Ikenoue, Hiroshi; Asano, Tanemasa


    Phosphorus doping of 4H SiC is performed by KrF excimer laser irradiation of 4H SiC immersed in phosphoric acid. Phosphorus is incorporated to a depth of a few tens of nanometers at a concentration of over 10{sup 20}/cm{sup 3} without generating significant crystal defects. Formation of a pn junction diode with an ideality factor of 1.06 is demonstrated.

  4. Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same


    Chen, Yok; Gonzalez, R.


    Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10/sup 12/ protons per cm/sup 3/ and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F/sup +/ luminescence is produced when the crystal is optically excited.

  5. Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same


    Chen, Yok; Gonzalez, Roberto


    Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10.sup.12 protons per cm.sup.3 and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F.sup.+ luminescence is produced when the crystal is optically excited.

  6. Spectroscopic characteristics of chromium doped mullite glass-ceramics

    SciTech Connect

    Wojtowicz, A.J.; Meng, W.; Lempicki, A.; Beall, G.H.; Hall, D.W.; Chin, T.C.


    Characteristics of chromium doped mullite ceramics are discussed with reference to possible laser applications. Dominant features are attributed to large and inherent spectroscopic inhomogeneity of mullite. The spectroscopic data are analyzed using a generalized McCumber theory. The peak stimulated emission cross section is 0.54 x 10/sup -20/ cm/sup 2/. This, together with preliminary single-pass measurements, indicate that gain for mullite is about 2.6 times smaller than gain for alexandrite.


    SciTech Connect

    Usman, S. M.; Murray, S. S.; Hickox, R. C.; Brodwin, M.


    We explore the connection between absorption by neutral gas and extinction by dust in mid-infrared (IR) selected luminous quasars. We use a sample of 33 quasars at redshifts 0.7 < z ≲ 3 in the 9 deg{sup 2} Boötes multiwavelength survey field that are selected using Spitzer Space Telescope Infrared Array Camera colors and are well-detected as luminous X-ray sources (with >150 counts) in Chandra observations. We divide the quasars into dust-obscured and unobscured samples based on their optical to mid-IR color, and measure the neutral hydrogen column density N {sub H} through fitting of the X-ray spectra. We find that all subsets of quasars have consistent power law photon indices Γ ≈ 1.9 that are uncorrelated with N {sub H}. We classify the quasars as gas-absorbed or gas-unabsorbed if N {sub H} > 10{sup 22} cm{sup –2} or N {sub H} < 10{sup 22} cm{sup –2}, respectively. Of 24 dust-unobscured quasars in the sample, only one shows clear evidence for significant intrinsic N {sub H}, while 22 have column densities consistent with N {sub H} < 10{sup 22} cm{sup –2}. In contrast, of the nine dust-obscured quasars, six show evidence for intrinsic gas absorption, and three are consistent with N {sub H} < 10{sup 22} cm{sup –2}. We conclude that dust extinction in IR-selected quasars is strongly correlated with significant gas absorption as determined through X-ray spectral fitting. These results suggest that obscuring gas and dust in quasars are generally co-spatial, and confirm the reliability of simple mid-IR and optical photometric techniques for separating quasars based on obscuration.

  8. Doped GaN nanowires on diamond: Structural properties and charge carrier distribution

    SciTech Connect

    Schuster, Fabian Winnerl, Andrea; Weiszer, Saskia; Hetzl, Martin; Garrido, Jose A.; Stutzmann, Martin


    In this work, we present a detailed study on GaN nanowire doping, which is vital for device fabrication. The nanowires (NWs) are grown by means of molecular beam epitaxy on diamond (111) substrates. Dopant atoms are found to facilitate nucleation, thus an increasing NW density is observed for increasing dopant fluxes. While maintaining nanowire morphology, we demonstrate the incorporation of Si and Mg up to concentrations of 9× 10{sup 20}cm{sup −3} and 1 × 10{sup 20}cm{sup −3}, respectively. The dopant concentration in the nanowire cores is determined by the thermodynamic solubility limit, whereas excess dopants are found to segregate to the nanowire surface. The strain state of the NWs is investigated by X-ray diffraction, which confirms a negligible strain compared to planar thin films. Doping-related emissions are identified in low-temperature photoluminescence spectroscopy and the temperature quenching yields ionization energies of Si donors and Mg acceptors of 17 meV and 167 meV, respectively. At room temperature, luminescence and absorption spectra are found to coincide and the sub-band gap absorption is suppressed in n-type NWs. The charge carrier distribution in doped GaN nanowires is simulated under consideration of surface states at the non-polar side facets. For doping concentrations below 10{sup 17}cm{sup −3}, the nanowires are depleted of charge carriers, whereas they become highly conductive above 10{sup 19}cm{sup −3}.

  9. Deep traps in n-type GaN epilayers grown by plasma assisted molecular beam epitaxy

    SciTech Connect

    Kamyczek, P.; Placzek-Popko, E.; Zielony, E.; Gumienny, Z.; Zytkiewicz, Z. R.


    In this study, we present the results of investigations on Schottky Au-GaN diodes by means of conventional DLTS and Laplace DLTS methods within the temperature range of 77 K–350 K. Undoped GaN layers were grown using the plasma-assisted molecular beam epitaxy technique on commercial GaN/sapphire templates. The quality of the epilayers was studied by micro-Raman spectroscopy (μ-RS) which proved the hexagonal phase and good crystallinity of GaN epilayers as well as a slight strain. The photoluminescence spectrum confirmed a high crystal quality by intense excitonic emission but it also exhibited a blue emission band of low intensity. DLTS signal spectra revealed the presence of four majority traps: two high-temperature and two low-temperature peaks. Using the Laplace DLTS method and Arrhenius plots, the apparent activation energy and capture cross sections were obtained. For two high-temperature majority traps, they were equal to E{sub 1} = 0.65 eV, σ{sub 1} = 8.2 × 10{sup −16} cm{sup 2} and E{sub 2} = 0.58 eV, σ{sub 2} = 2.6 × 10{sup −15} cm{sup 2} whereas for the two low-temperature majority traps they were equal to E{sub 3} = 0.18 eV, σ{sub 3} = 9.7 × 10{sup −18} cm{sup 2} and E{sub 4} = 0.13 eV, σ{sub 4} = 9.2 × 10{sup −18} cm{sup 2}. The possible origin of the traps is discussed and the results are compared with data reported elsewhere.

  10. Development of a strong field helicon plasma source

    SciTech Connect

    Shinohara, Shunjiro; Mizokoshi, Hiroshi


    We developed a high-density helicon plasma source with a very strong field of up to 10 kG. Using a double-loop antenna wound around a quartz tube, 9.5 cm in inner diameter and 90 cm in axial length, initial plasmas with a high density more than 10{sup 13} cm{sup -3} were successfully produced with a radio frequency power less than a few kilowatts, and with changing magnetic fields, fill pressures, and gas species.

  11. High luminosity operation, beam-beam effects and their compensation in Tevatron

    SciTech Connect

    Shiltsev, V.; /Fermilab


    Over the past 2 years the Tevatron peak luminosity steadily progressed and reached the level of 3.15 {center_dot} 10{sup 32} cm{sup -2} s{sup -1} which exceeds the Run II Upgrade goal. We discuss the collider performance, illustrate limitations and understanding of beam-beam effects and present experimental results of compensation of the beam-beam effects by electron lenses--a technique of great interest for the LHC.

  12. Breakdown and discharges in dense gases governed by runaway electrons

    SciTech Connect

    Babich, L.P.


    The phenomenon of runaway electrons (REs) at high values of the ratio field intensity/gas number density {ital E}/{ital N} and {ital N} up to the Loshmidt number {ital N}{sub {ital L}}{approx_equal}2.7{times}10{sup 19} cm{sup {minus}3} is described. REs are shown to govern the breakdown and discharges at such condition. {copyright} {ital 1996 American Institute of Physics.}

  13. Thermal resistance of ultra-small-diameter disk microlasers

    SciTech Connect

    Zhukov, A. E. Kryzhanovskaya, N. V.; Maximov, M. V.; Lipovskii, A. A.; Savelyev, A. V.; Shostak, I. I.; Moiseev, E. I.; Kudashova, Yu. V.; Kulagina, M. M.; Troshkov, S. I.


    The thermal resistance of AlGaAs/GaAs microlasers of the suspended-disk type with a diameter of 1.7–4 μm and InAs/InGaAs quantum dots in the active region is inversely proportional to the squared diameter of the microdisk. The proportionality factor is 3.2 × 10{sup −3} (K cm{sup 2})/W, and the thermal resistance is 120–20°C/mW.

  14. Modulation of 17{beta}-estradiol-induced responses in fish by cytochrome P4501A1 inducing compounds

    SciTech Connect

    Anderson, M.J.; Hinton, D.E.


    Some compounds which induce cytochrome P4501A1 (CYP1A1) are antiestrogenic in mammalian bioassay, and this effect is linked to aryl hydrocarbon (Ah) receptor. Liver of fish synthesizes estrogen-inducible egg yolk precursor protein vitellogenin (Vg) which is critical for oocyte maturation and ovarian development. To determine if Ah receptor-linked endocrine modulation could occur in fish liver, primary cultures of juvenile rainbow trout (Oncorhynchus mykiss) liver cells were co-administered 17{beta}-estradiol and CYP1A1 inducing compounds. Vitellogenin and albumin, estimated by ELISA measurement of concentration in the media 48 hrs after treatment, formed the basis for the test. Cellular CYP1A1 protein content and catalytic activity was estimated by ELISA and ethoxyresorufin-O-deethylase (EROD) activity assays respectively. Equivalent viability (mitochondrial dehydrogenase activity) and secretary functional capacity (albumin synthesis) were estimated and correlated with other results. In descending order, 2,3,4,7,8 pentachlorodibenzofuran (10{sup {minus}12} to 10{sup {minus}8} M) > 2,3,7,8 tetrachlorodibenzo-p-dioxin {approx_equal} 2,3,7,8 tetrachlorodibenzofuran (10{sup {minus}11} to 10{sup {minus}8} M) > {beta}-naphthoflavone (10{sup {minus}7} to 10{sup {minus}6} M) inhibited Vg synthesis in 17{beta}-estradiol treated liver cells. Potency of inhibition directly related to strength as an inducer of CYP1A1 protein. At 10-8 M, PCB congeners 77, 126, and 156 did not inhibit Vg synthesis and induced no or only moderate CYP1A1 protein. At 10-8 M, PCB congener 114, a weak CYP1A1 inducer, potentiated Vg synthesis relative to cells treated with 17{beta}-estradiol alone. This study increases their understanding of the consequences of hepatic CYP1A1 induction, forewarns of reproductive impairment of sexually maturing fishes exposed to CYP1A1 inducing compounds and argues for further, more detailed in vivo investigation.

  15. Oxygen Implant Isolation of n-GaN Field-Effect Transistor Structures

    SciTech Connect

    Dang, G.; Cao, X.A.; Ren, F.; Pearton, S.J.; Han, J.; Baca, A.G.; Shul, R.J.


    Multiple-energy (30-325 keV) O{sup +} implantation into GaN field-effect transistor structures (n {approximately} 10{sup 18} cm{sup {minus}3}, 3000 {angstrom} thick) can produce as-implanted sheet resistances of 4 x 10{sup 12} {Omega}/{open_square}, provided care is taken to ensure compensation of the region up to the projected range of the lowest energy implant. The sheet resistance remains above 10{sup 7} {Omega}/{open_square} to annealing temperatures of {approximately} 650 C and displays an activation energy of 0.29 eV. No diffusion of the implanted oxygen was observed for anneals up to 800 C.

  16. A biresonant plasma source based on a gapped linear microwave vibrator

    SciTech Connect

    Gritsinin, S. I.; Davydov, A. M.; Kossyi, I. A.; Arapov, K. A.; Chapkevich, A. A.


    The operating principle of a novel microwave plasma source-a linear microwave vibrator with a gap-is discussed. The source is placed on a microwave-transparent window of a chamber filled with a plasma-forming gas (argon or methane). The device operation is based on the combination of two resonances-geometric and plasma ones. The results of experimental tests of the source are presented. For a microwave frequency of 2.45 GHz, microwave power of {<=}1 kW, and plasma-forming gas pressure in the range 5 Multiplication-Sign 10{sup -2}-10{sup -1} Torr, the source is capable of filling the reactor volume with a plasma having an electron density of about 10{sup 12} cm{sup -3} and electron temperature of a few electronvolts.

  17. Radiation damage testing of transistors for SSC front-end electronics

    SciTech Connect

    Dawson, J.; Ekenberg, T.; Stevens, A. ); Kraner, H.; Radeka, V.; Rescia, S. ); Kerns, S. . Dept. of Electrical Engineering)


    Over the ten year expected lifetime of a typical SSC detector operating at the design luminosity of 10{sup 33} cm{sup {minus}2}s{sup {minus}1}, the front-end electronics at large pseudorapidities may receive total doses as high as 20 MRad(Si) of ionizing radiation and 10{sup 16} neutrons/cm{sup 2}. Discrete JFETs and monolithic MOS and bipolar transistors have been irradiated at 10 MRad(Si) and 10{sup 14} neutrons/cm{sup 2}, and the effect on transfer characteristics and noise performance have been measured. All transistors were still functional after irradiation but suffered increased noise and the MOS transistors showed significant threshold shifts and increased leakage currents. 4 refs., 2 figs.

  18. Stimulated blue emission in reconstituted films of ultrasmall silicon nanoparticles

    SciTech Connect

    Nayfeh, M. H.; Barry, N.; Therrien, J.; Akcakir, O.; Gratton, E.; Belomoin, G.


    We dispersed electrochemical etched Si into a colloid of ultrabright blue luminescent nanoparticles (1 nm in diameter) and reconstituted it into films or microcrystallites. When the film is excited by a near-infrared two-photon process at 780 nm, the emission exhibits a sharp threshold near 10{sup 6}W/cm{sup 2}, rising by many orders of magnitude, beyond which a low power dependence sets in. Under some conditions, spontaneous recrystallization forms crystals of smooth shape from which we observe collimated beam emission, pointing to very large gain coefficients. The results are discussed in terms of population inversion, produced by quantum tunneling or/and thermal activation, and stimulated emission in the quantum confinement-engineered Si--Si phase found only on ultrasmall Si nanoparticles. The Si--Si phase model provides gain coefficients as large as 10{sup 3}--10{sup 5}cm{sup -1}.

  19. Z-scan: A simple technique for determination of third-order optical nonlinearity

    SciTech Connect

    Singh, Vijender; Aghamkar, Praveen


    Z-scan is a simple experimental technique to measure intensity dependent nonlinear susceptibilities of third-order nonlinear optical materials. This technique is used to measure the sign and magnitude of both real and imaginary part of the third order nonlinear susceptibility (χ{sup (3)}) of nonlinear optical materials. In this paper, we investigate third-order nonlinear optical properties of Ag-polymer composite film by using single beam z-scan technique with Q-switched, frequency doubled Nd: YAG laser (λ=532 nm) at 5 ns pulse. The values of nonlinear absorption coefficient (β), nonlinear refractive index (n{sub 2}) and third-order nonlinear optical susceptibility (χ{sup (3)}) of permethylazine were found to be 9.64 × 10{sup −7} cm/W, 8.55 × 10{sup −12} cm{sup 2}/W and 5.48 × 10{sup −10} esu, respectively.

  20. Low-temperature growth of silicon epitaxial layers codoped with erbium and oxygen atoms

    SciTech Connect

    Shengurov, D. V.; Chalkov, V. Yu.; Denisov, S. A.; Shengurov, V. G.; Stepikhova, M. V.; Drozdov, M. N.; Krasilnik, Z. F.


    The fabrication technology and properties of light-emitting Si structures codoped with erbium and oxygen are reported. The layers are deposited onto (100) Si by molecular beam epitaxy (MBE) using an Er-doped silicon sublimation source. The partial pressure of the oxygen-containing gases in the growth chamber of the MBE facility before layer growth is lower than 5 Multiplication-Sign 10{sup -10} Torr. The oxygen and erbium concentrations in the Si layers grown at 450 Degree-Sign C is {approx}1 Multiplication-Sign 10{sup 19} and 10{sup 18} cm{sup -3}, respectively. The silicon epitaxial layers codoped with erbium and oxygen have high crystal quality and yield effective photoluminescence and electroluminescence signals with the dominant optically active Er-1 center forming upon postgrowth annealing at a temperature of 800 Degree-Sign C.

  1. Time-resolved spectroscopy measurements of hydrogen-alpha, -beta, and -gamma emissions

    SciTech Connect

    Parigger, Christian G.; Dackman, Matthew; Hornkohl, James O


    Hydrogen emission spectroscopy results are reported following laser-induced optical breakdown with infrared Nd:YAG laser radiation focused into a pulsed methane flow. Measurements of Stark-broadened atomic hydrogen-alpha, -beta, and -gamma lines show electron number densities of 0.3 to 4x10{sup 17} cm{sup -3} for time delays of 2.1 to 0.4 {mu}s after laser-induced optical breakdown. In methane flow, recombination molecular spectra of the {delta}{nu}=+2 progression of the C2 Swan system are discernable in the H{beta} and H{gamma} plasma emissions within the first few microseconds. The recorded atomic spectra indicate the occurrence of hydrogen self-absorption for pulsed CH4 flow pressures of 2.7x10{sup 5} Pa (25 psig) and 6.5x10{sup 5} Pa (80 psig)

  2. Laser-produced annular plasmas

    SciTech Connect

    Veloso, F.; Chuaqui, H.; Aliaga-Rossel, R.; Favre, M.; Mitchell, I. H.; Wyndham, E.


    A new technique is presented for the formation of annular plasmas on a metal surface with a high-power laser using a combination of axicon and converging lenses. The annular plasma formed on a titanium target in a chamber of hydrogen gas was investigated using schlieren imaging and Mach Zehnder interferometry. Expansion of the plasma was shown to be anisotropic with velocities of {approx}10{sup 3}-10{sup 4} m/s. Electron densities of 10{sup 18} cm{sup -3} were measured with radial profiles that confirm the presence of a hollow structure. The interferometric observations also show the presence of an inward shock wave traveling to the center of the annular plasma, which compresses the background neutrals, reaching a density around 18 times initial gas density, at 95 ns after the initial annular plasma is produced.

  3. Plasma Parameter of a Capillary Discharge-Produced Plasma Channel to Guide an Ultrashort Laser Pulse

    SciTech Connect

    Higashiguchi, Takeshi; Terauchi, Hiromitsu; Bai, Jin-xiang; Yugami, Noboru


    We have observed the optical guiding of a 100-fs laser pulse with the laser intensity in the range of 10{sup 16} W/cm{sup 2} using a 1.5-cm long capillary discharge-produced plasma channel for compact electron acceleration applications. The optical pulse propagation using the plasma channel is achieved with the electron densities of 10{sup 17}-10{sup 18} cm{sup -3} and the electron temperatures of 0.5-4 eV at a discharge time delay of around 150 ns and a discharge current of 500 A with a pulse duration of 100-150 ns. An energy spectrum of the accelerated electrons from a laser-plasma acceleration scheme showed a peak at 1.3 MeV with a maximum energy tail of 1.6 MeV.

  4. Dissociative excitation of the B/sup 2/. sigma. /sup +//sub 1/2/ states of mercury monohalides by electron impact

    SciTech Connect

    Malinin, A.N.; Shuaibov, A.K.; Shevera, V.S.


    An investigation was made of the process of excitation of HgCl/sub 2/, HgBr/sub 2/, and HgI/sub 2/ molecules by electron impact producing B/sup 2/..sigma../sup +//sub 1/2/ states of HgCl*, HgBr*, and HgI*. The maximum values of the cross sections for dissociative excitation were found at low electron energies; the values of these cross sections were sigma = (6 +- 3) x 10/sup -18/, (7.5 +- 3) x 10/sup -17/, and (1.2 +- 0.6) x 10/sup -17/ cm/sup 2/ for HgCl*, HgBr*, and HgI*, respectively. The role of such dissociative excitation in lasing was analyzed.

  5. Dopant diffusion in tungsten silicide

    SciTech Connect

    Pan, P.; Hsieh, N.; Geipel, H.J. Jr.; Slusser, G.J.


    The dopant (B, P, and As) redistribution in a silicide on polycrystalline silicon structure after annealing at 800 and 1000 /sup 0/C was studied. The distribution of boron was found to be quite different from these of phosphorus and arsenic. At 1000 /sup 0/C, the distribution coefficient for boron at the WSi/sub 2//polycrystalline silicon interface was found to be 2.7. The solubilities of phosphorus and arsenic in WSi/sub 2/ at 1000 /sup 0/C were estimated to be 6 x 10/sup 19/ and 1.6 x 10/sup 19/ atoms/cm/sup 3/, respectively. At 800 /sup 0/C, the diffusion coefficient for the dopants was found to be equal to, or greater than 3.3 x 10/sup -12/ cm/sup 2//s, which is at least three orders of magnitude larger than in silicon.

  6. Highly efficient tabletop x-ray laser at {lambda}=41.8 nm in Pd-like xenon pumped by optical-field ionization in a cluster jet

    SciTech Connect

    Ivanova, E. P.


    The atomic-kinetic calculations of gain at 41.8 nm in Pd-like xenon are performed. The interpretation of known experiments has proved that x-ray laser in Pd-like xenon is feasible in the extremely wide range of atomic densities: 10{sup 17}{<=}[Xe{sup 8+}]{<=} 3 x 10{sup 19} cm{sup -3}. This result is due to the large cross sections (and rates) of level excitations in Pd-like xenon by electron impact. We propose a highly efficient tabletop x-ray laser pumped by optical-field ionization in a xenon cluster jet. The efficiency of {approx}0.5% is possible with a pump laser pulse energy of {>=}0.001 J and an intensity of {approx}10{sup 16} W/cm{sup 2}.

  7. Positron trapping at vacancies in electron-irradiated Si at low temperatures

    SciTech Connect

    Maekinen, J.; Corbel, C.; Hautojaervi, P.; Moser, P.; Pierre, F.


    Experimental results on positron trapping at vacancies in electron-irradiated silicon are presented. The positron lifetimes 273 +- 3 and 248 +- 2 ps in pure Si and heavily-phosphorus-doped Si ((P) = 10/sup 20/ cm/sup -3/) are assigned to a negative monovacancy V/sup -/ and a negative vacancy-phosphorus pair (V-P)/sup -/, respectively. In pure Si, positron trapping displays a strong negative temperature dependence, and the specific trapping rate reaches very large values (10/sup 17//sup --/10/sup 18/ s/sup -1/) at low temperatures. In Si:P the trapping rate is independent of temperature. These different temperature behaviors are attributed to different positron-trapping mechanisms, a cascade of one-phonon transitions in pure Si, and an Auger process in Si:P.

  8. Energy upconversion in holmium doped lead-germano-tellurite glass

    SciTech Connect

    Kamma, Indumathi; Reddy, B. Rami


    Holmium doped lead-germano-tellurite glass was prepared by the melt quenching technique. The Judd-Ofelt intensity parameters were estimated as {Omega}{sub 2}=7.6x10{sup -20}, {Omega}{sub 4}=12.9x10{sup -20}, and {Omega}{sub 6}=2.5x10{sup -20} cm{sup 2}. Radiative transition probabilities and lifetimes were also determined for some of the levels. Room temperature upconversion emissions have been observed from Ho{sup 3+} at 497 nm under 532 nm laser excitation, and at 557 and 668 nm under 762 nm laser excitation. The upconversion emission mechanisms were found to be due to a step wise excitation process. Upconversion emission intensity enhanced in a heat treated glass.

  9. Two-color magneto-optical trap for metastable helium

    SciTech Connect

    Tychkov, A.S.; Koelemeij, J.C.J.; Jeltes, T.; Hogervorst, W.; Vassen, W.


    We describe a powerful scheme which combines laser cooling on two transitions of metastable helium to obtain a high phase-space density. By running a sequence of a large 1083 nm magneto-optical trap (MOT) and a compressed 389 nm MOT, a density increase of more than one order of magnitude is achieved within 5 ms. After compression, 8x10{sup 8} atoms at a central density of 5x10{sup 10} cm{sup -3} remain, while the temperature of the cloud has been reduced from 1 mK to 0.4 mK. The resulting phase-space density (4.1x10{sup -6}) is more than one order of magnitude higher than what we achieved by 1083 nm laser cooling only.

  10. Study of the plasma and runaway electrons during inductionless current excitation in the V-20 torsatron

    SciTech Connect

    Bocharov, V.K.; Volkov, Y.F.; Dyatlov, V.G.; Kornienko, V.P.; Mitina, N.I.


    Inductionless current excitation has been studied in the V-20 torsatron with the plasma parameters n = 10/sup 12/--10/sup 13/ cm/sup -3/ and T/sub e/ = 40--60 eV. Since the plasma current was excited only in the initial stage of the discharge, it was possible to study the events in the plasma both with and without current flow. The plasma conductivity determined from measurements of the current and the voltage is an order of magnitude below the classical value calculated from the measured electron temperature. The discharge conditions under which a large number (Nroughly-equal(2--3)x10/sup 11/) of runaway electrons appear were studied. It is shown that the runaway occurs continuously throughout the discharge. When a certain limiting energy is reached (this energy depends on the confining properties of the confinement system), the runaway electrons escape from the confinement volume.

  11. Long-Wavelength Stacked SiGe/Si Heterojunction Internal Photoemission Infrared Detectors Using Multiple SiGe/Si Layers

    NASA Technical Reports Server (NTRS)

    Park, J. S.; Lin, T. L.; Jones, E. W.; Castillo, H. M. Del; Gunapala, S. D.


    Utilizing low temperature silicon molecular beam epitaxy (MBE) growth, long-wavelength stacked SiGe/Si heterojunction internal photoemission (HIP) infrared detectors with multiple SiGe/Si layers have been fabricated and demonstrated. Using an elemental boron source, high doping concentrations (approximately equal to 4 x 10(sup 20) cm(sup -3)) has been achieved and high crystalline quality multiple Si(sub 0.7)Ge(sub 0.3)/Si layers have been obtained. The detector structure consists of several periods of degenerately boron doped (approximately equal to 4 x 10(sup 20) cm(sup -3)) thin (less than or equal to 50 u Si(sub 0.7)Ge(sub 0.3) layers and undoped thick (approximately equal to 300u Si layers. The multiple p(sup +) - Si(sub 0.7)Ge(sub 0.3)/undoped-Si layers show strong infrared absorption in the long-wavelength regime mainly through free carrier absorption. The stacked Si(sub 0.7)Ge(sub 0.3)/Si HIP detectors with p = 4 x 10(sup 20) cm(sup -3) exhibit strong photoresponse at wavelengths ranging from 2 to 20 (micro)m with quantum efficiencies of about 4% and 1.5% at 10 and 15 (micro)m wavelengths, respectively. The detectors show near ideal thermionic-emission limited dark current characteristics.

  12. Simultaneous measurement of nitrogen and hydrogen dissociation from vacuum ultraviolet self-absorption spectroscopy in a developing low temperature plasma at atmospheric pressure

    SciTech Connect

    Laity, George; Fierro, Andrew; Dickens, James; Neuber, Andreas; Frank, Klaus


    We demonstrate a method for determining the dissociation density of N and H atoms present in a developing low temperature plasma, based on the emission and self-absorption of vacuum ultraviolet radiation produced from the plasma. Spark plasmas are produced via pulsed discharge in N{sub 2}/H{sub 2} mixtures at atmospheric pressure, where information on the dissociated densities of the constituent gas molecules is desired without employing invasive diagnostic techniques. By analyzing the self-absorption line profile of 121.5 nm Lyman-{alpha} H radiation emitted within the first {approx}1.0 mm of plasma near the anode tip, a peak dissociated H atom concentration of 5.6 Multiplication-Sign 10{sup 17} cm{sup -3} was observed {approx}100 ns into spark formation, with an estimated electron density of 2.65 Multiplication-Sign 10{sup 18} cm{sup -3} determined from Stark broadening. Similarly, simultaneous line fitting of the N 120.0/124.3 nm emission profiles revealed a peak dissociated N atom concentration of 3.8 Multiplication-Sign 10{sup 17} cm{sup -3} during the same discharge period.

  13. Thomson scattering on ELMO Bumpy Torus

    SciTech Connect

    Cobble, J.A.


    Below 10/sup 12/ cm/sup -3/ density, a Thomson scattering experiment is an exacting task. Aside from the low signal level, the core plasma in this instance is bathed in high-energy x rays, surrounded by a glowing molecular surface plasma, and heated steady state by microwaves. This means that the noise level from radiation is high and the environment is extremely harsh-so harsh that much effort is required to overcome system damage. In spite of this, the ELMO Bumpy Torus (EBT) system has proven itself capable of providing reliable n/sub e/ and T/sub e/ measurements at densities as low as 2 x 10/sup 11/ cm/sup -3/. Radial scans across 20 cm of the plasma diameter have been obtained on a routine basis, and the resulting information has been a great help in understanding confinement in the EBT plasma. The bulk electron properties are revealed as flat profiles of n/sub e/ and T/sub e/, with density ranging from 0.5 to 2.0 x 10/sup 12/ cm/sup -3/ and temperature decreasing from 100 to 20 eV as pressure in the discharge is increased at constant power. Evidence is presented for a suprathermal tail, which amounts to about 10% of the electron distribution at low pressures. The validity of this conclusion is supported by two independent sensitivity calibrations.

  14. Admittance spectroscopy of solar cells based on GaPNAs layers

    SciTech Connect

    Baranov, A. I. Gudovskikh, A. S.; Zelentsov, K. S.; Nikitina, E. V.; Egorov, A. Yu.


    Admittance spectroscopy is used to study defect levels in the layers of a GaPNAs quaternary solid solution. Centers with an activation energy of 0.22 eV and a capture cross section of ∼2.4 × 10{sup −15} cm{sup 2} are found in doped n-GaPNAs layers grown on GaP substrates. These centers correspond to already known Si{sub Ga} + V{sub P} defects in n-GaP; annealing decreases their concentration by several times. A level with an activation energy of 0.23–0.24 eV and capture cross section of ∼9.0 × 10{sup −20} cm{sup 2} is found in undoped GaPNAs layers grown on Si and GaP substrates. The concentration of these centers substantially decreases upon annealing, and, at annealing temperatures exceeding 600°C, there is absolutely no response from these defects. For undoped GaPNAs layers grown on GaP substrates, a level with an activation energy of 0.18 eV and capture cross section of ∼1.1 × 10{sup −16} cm{sup 2} is also found. The concentration of these centers remains unchanged upon annealing.

  15. Optimized deposition and characterization of nanocrystalline magnesium indium oxide thin films for opto-electronic applications

    SciTech Connect

    Raj, A. Moses Ezhil; Ravidhas, C.; Ravishankar, R.; Kumar, A. Rathish; Selvan, G.; Jayachandran, M.; Sanjeeviraja, C.


    Transparent conducting magnesium indium oxide films (MgIn{sub 2}O{sub 4}) were deposited on to quartz substrates without a buffer layer at an optimized deposition temperature of 450 deg. C to achieve high transmittance in the visible spectral range and electrical conductivity in the low temperature region. Magnesium ions are distributed over the tetrahedral and octahedral sites of the inverted spinel structure with preferential orientation along (3 1 1) Miller plane. The possible mechanism that promotes conductivity in this system is the charge transfer between the resident divalent (Mg{sup 2+}) and trivalent (In{sup 3+}) cations in addition to the available oxygen vacancies in the lattice. A room temperature electrical conductivity of 1.5 x 10{sup -5} S cm{sup -1} and an average transmittance >75% have been achieved. Hall measurements showed n-type conductivity with electron mobility value 0.95 x 10{sup -2} cm{sup 2} V{sup -1} s{sup -1} and carrier concentration 2.7 x 10{sup 19} cm{sup -3}. Smoothness of the film surface observed through atomic force microscope measurements favors this material for gas sensing and opto-electronic device development.

  16. Charge transport studies in donor-acceptor block copolymer PDPP-TNT and PC71BM based inverted organic photovoltaic devices processed in room conditions

    SciTech Connect

    Srivastava, Shashi B.; Singh, Samarendra P.; Sonar, Prashant


    Diketopyrrolopyrole-naphthalene polymer (PDPP-TNT), a donor-acceptor co-polymer, has shown versatile behavior demonstrating high performances in organic field-effect transistors (OFETs) and organic photovoltaic (OPV) devices. In this paper we report investigation of charge carrier dynamics in PDPP-TNT, and [6,6]-phenyl C{sub 71} butyric acid methyl ester (PC71BM) bulk-heterojunction based inverted OPV devices using current density-voltage (J-V) characteristics, space charge limited current (SCLC) measurements, capacitance-voltage (C-V) characteristics, and impedance spectroscopy (IS). OPV devices in inverted architecture, ITO/ZnO/PDPP-TNT:PC71BM/MoO{sub 3}/Ag, are processed and characterized at room conditions. The power conversion efficiency (PCE) of these devices are measured ∼3.8%, with reasonably good fill-factor 54.6%. The analysis of impedance spectra exhibits electron’s mobility ∼2 × 10{sup −3} cm{sup 2}V{sup −1}s{sup −1}, and lifetime in the range of 0.03-0.23 ms. SCLC measurements give hole mobility of 1.12 × 10{sup −5} cm{sup 2}V{sup −1}s{sup −1}, and electron mobility of 8.7 × 10{sup −4} cm{sup 2}V{sup −1}s{sup −1}.

  17. Constraining Dark Matter Models from a Combined Analysis of Milky Way Satellites with the Fermi Large Area Telescope

    SciTech Connect

    Ackermann, M.; Ajello, M.; Albert, A.; Atwood, W.B.; Baldini, L.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Bechtol, K.; Bellazzini, R.; Berenji, B.; Blandford, R.D.; Bloom, E.D.; Bonamente, E.; Borgland, A.W.; Bregeon, J.; Brigida, M.; Bruel, P.; Buehler, R.; Burnett, T.H.; Buson, S.; /more authors..


    Satellite galaxies of the Milky Way are among the most promising targets for dark matter searches in gamma rays. We present a search for dark matter consisting of weakly interacting massive particles, applying a joint likelihood analysis to 10 satellite galaxies with 24 months of data of the Fermi Large Area Telescope. No dark matter signal is detected. Including the uncertainty in the dark matter distribution, robust upper limits are placed on dark matter annihilation cross sections. The 95% confidence level upper limits range from about 10{sup -26} cm{sup 3} s{sup -1} at 5 GeV to about 5 x 10{sup -23} cm{sup 3} s{sup -1} at 1 TeV, depending on the dark matter annihilation final state. For the first time, using gamma rays, we are able to rule out models with the most generic cross section ({approx}3 x 10{sup -26} cm{sup 3} s{sup -1} for a purely s-wave cross section), without assuming additional boost factors.

  18. UV absorption spectrum of the C2 Criegee intermediate CH{sub 3}CHOO

    SciTech Connect

    Smith, Mica C.; Ting, Wei-Lun; Chang, Chun-Hung; Takahashi, Kaito; Boering, Kristie A.; Lin, Jim Jr-Min


    The UV spectrum of CH{sub 3}CHOO was measured by transient absorption in a flow cell at 295 K. The absolute absorption cross sections of CH{sub 3}CHOO were measured by laser depletion in a molecular beam to be (1.06 ± 0.09) × 10{sup −17} cm{sup 2} molecule{sup −1} at 308 nm and (9.7 ± 0.6) × 10{sup −18} cm{sup 2} molecule{sup −1} at 352 nm. After scaling the UV spectrum of CH{sub 3}CHOO to the absolute cross section at 308 nm, the peak UV cross section is (1.27 ± 0.11) × 10{sup −17} cm{sup 2} molecule{sup −1} at 328 nm. Compared to the simplest Criegee intermediate CH{sub 2}OO, the UV absorption band of CH{sub 3}CHOO is similar in intensity but blue shifted by 14 nm, resulting in a 20% slower photolysis rate estimated for CH{sub 3}CHOO in the atmosphere.

  19. Fe-rich ejecta in the supernova remnant G352.7–0.1 with Suzaku

    SciTech Connect

    Sezer, A.; Gök, F.


    In this work, we present results from a ∼201.6 ks observation of G352.7–0.1 using the X-ray Imaging Spectrometer on board Suzaku X-ray Observatory. The X-ray emission from the remnant is well described by two-temperature thermal models of non-equilibrium ionization with variable abundances with a column density of N{sub H} ∼ 3.3 × 10{sup 22} cm{sup –2}. The soft component is characterized by an electron temperature of kT{sub e} ∼ 0.6 keV, an ionization timescale of τ ∼ 3.4 × 10{sup 11} cm{sup –3} s, and enhanced Si, S, Ar, and Ca abundances. The hard component has kT{sub e} ∼ 4.3 keV, τ ∼ 8.8 × 10{sup 9} cm{sup –3} s, and enhanced Fe abundance. The elemental abundances of Si, S, Ar, Ca, and Fe are found to be significantly higher than the solar values that confirm the presence of ejecta. We detected strong Fe K-shell emission and determined its origin to be the ejecta for the first time. The detection of Fe ejecta with a lower ionization timescale favors a Type Ia origin for this remnant.

  20. Theoretical study of radiative electron attachment to CN, C{sub 2}H, and C{sub 4}H radicals

    SciTech Connect

    Douguet, Nicolas; Fonseca dos Santos, S.; Orel, Ann E.; Raoult, Maurice; Dulieu, Olivier


    A first-principle theoretical approach to study the process of radiative electron attachment is developed and applied to the negative molecular ions CN{sup −}, C{sub 4}H{sup −}, and C{sub 2}H{sup −}. Among these anions, the first two have already been observed in the interstellar space. Cross sections and rate coefficients for formation of these ions by direct radiative electron attachment to the corresponding neutral radicals are calculated. For the CN molecule, we also considered the indirect pathway, in which the electron is initially captured through non-Born-Oppenheimer coupling into a vibrationally resonant excited state of the anion, which then stabilizes by radiative decay. We have shown that the contribution of the indirect pathway to the formation of CN{sup −} is negligible in comparison to the direct mechanism. The obtained rate coefficients for the direct mechanism at 30 K are 7 × 10{sup −16} cm{sup 3}/s for CN{sup −}, 7 × 10{sup −17} cm{sup 3}/s for C{sub 2}H{sup −}, and 2 × 10{sup −16} cm{sup 3}/s for C{sub 4}H{sup −}. These rates weakly depend on temperature between 10 K and 100 K. The validity of our calculations is verified by comparing the present theoretical results with data from recent photodetachment experiments.

  1. Carrier transport properties of the Group-IV ferromagnetic semiconductor Ge{sub 1-x}Fe{sub x} with and without boron doping

    SciTech Connect

    Ban, Yoshisuke Wakabayashi, Yuki; Akiyama, Ryota; Nakane, Ryosho; Tanaka, Masaaki


    We have investigated the transport and magnetic properties of group-IV ferromagnetic semiconductor Ge{sub 1-x}Fe{sub x} films (x = 1.0 and 2.3%) with and without boron doping grown by molecular beam epitaxy (MBE). In order to accurately measure the transport properties of 100-nm-thick Ge{sub 1-x}Fe{sub x} films, (001)-oriented silicon-on-insulator (SOI) wafers with an ultra-thin Si body layer (∼5 nm) were used as substrates. Owing to the low Fe content, the hole concentration and mobility in the Ge{sub 1-x}Fe{sub x} films were exactly estimated by Hall measurements because the anomalous Hall effect in these films was found to be negligibly small. By boron doping, we increased the hole concentration in Ge{sub 1-x}Fe{sub x} from ∼10{sup 18} cm{sup −3} to ∼10{sup 20} cm{sup −3} (x = 1.0%) and to ∼10{sup 19} cm{sup −3} (x = 2.3%), but no correlation was observed between the hole concentration and magnetic properties. This result presents a contrast to the hole-induced ferromagnetism in III-V ferromagnetic semiconductors.

  2. Ion implantation and dynamic recovery of tin-doped indium oxide films

    SciTech Connect

    Shigesato, Yuzo; Paine, D.C.; Haynes, T.E.


    The effect of O{sup +} on implantation on the electronic (carrier density, mobility), resistivity and microstructural properties of thin film Sn-doped In{sub 2}O{sub 3} (ITO) was studied. Both polycrystalline (c-) and amorphous (a-) ITO thin films, 200 nm thick, were implanted at substrate temperatures ranging from {minus}196 to 300{degrees} C with 80 keV O{sup +} at doses ranging from 0 to 4.0{times}10{sup 15} cm{sup {minus}2}. X-ray diffraction studies show that polycrystalline ITO remains crystalline even after implantation with 80 keV O{sup +} at {minus}196{degrees}C to a dose of 4.0{times}10{sup 15} cm{sup {minus}2} which suggests that dynamic recovery processes are active in ITO at this low temperature. Although the x-ray diffraction pattern of the polycrystalline ITO remains unchanged with implant dose, the electrical properties were seen to degrade when implanted to a dose of 1.0{times}10{sup 15}cm{sup {minus}2} below 200{degrees}C. In contrast, amorphous ITO films remains amorphous upon ion implantation and shows almost no degradation in resistivity when implanted below 16{degrees}C. The recrystallization temperature of amorphous ITO is about 150{degrees}C in the absence of ion implantation.

  3. Electron and Negative Ion Densities in C(2)F(6) and CHF(3) Containing Inductively Coupled Discharges

    SciTech Connect



    Electron and negative ion densities have been measured in inductively coupled discharges containing C{sub 2}F{sub 6} and CHF{sub 3}. Line integrated electron density was determined using a microwave interferometer, negative ion densities were inferred using laser photodetachment spectroscopy, and electron temperature was determined using a Langmuir probe. For the range of induction powers, pressures and bias power investigated, the electron density peaked at 9 x 10{sup 12} cm{sup -2} (line-integrated) or approximately 9 x 10{sup 11} cm{sup -3}. The negative ion density peaked at approximately 1.3 x 10{sup 11} cm{sup -3}. A maximum in the negative ion density as a function of induction coil power was observed. The maximum is attributed to a power dependent change in the density of one or more of the potential negative ion precursor species since the electron temperature did not depend strongly on power. The variation of photodetachment with laser wavelength indicated that the dominant negative ion was F{sup -}. Measurement of the decay of the negative ion density in the afterglow of a pulse modulated discharge was used to determine the ion-ion recombination rate for CF{sub 4}, C{sub 2}F{sub 6} and CHF{sub 3} discharges.

  4. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect


    Cremers, D.A.; Keller, R.A.


    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect have been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical path length of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10[sup [minus]5] cm[sup [minus]1] can then be determined in the presence of background absorptions in excess of 10[sup [minus]3] cm[sup [minus]1]. In addition, the smallest absorption measured with the instant apparatus and method is about 5 [times] 10[sup [minus]6] cm[sup [minus]1]. 6 figs.

  5. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect


    Cremers, David A.; Keller, Richard A.


    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect has been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical pathlength of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10.sup.-5 cm.sup.-1 can then be determined in the presence of background absorptions in excess of 10.sup.-3 cm.sup.-1. In addition, the smallest absorption measured with the instant apparatus and method is about 5.times. 10.sup.-6 cm.sup.-1.

  6. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect


    Cremers, D.A.; Keller, R.A.


    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect has been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical pathlength of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10/sup -5/ cm/sup -1/ can then be determined in the presence of background absorptions in excess of 10/sup -3/ cm/sup -1/. In addition, the smallest absorption measured with the instant apparatus and method is about 5 x 10/sup -6/ cm/sup -1/.

  7. Kinetics of the reaction OH + NH sub 3 in the range 273-433 K

    SciTech Connect

    Diau, Eric Weiguang; Tso, Taily; Lee, Yuanpern )


    The kinetics of the reaction OH + NH{sub 3} have been studied by means of the flash photolysis/laser-induced fluorescence technique. The rate of this reaction was investigated in the range 273-433 K under more extensive conditions (68 < P/Torr < 504, 0.29 < (NH{sub 3})/10{sup 15} molecules cm{sup {minus}3} < 36.1) than previously. The results from experiments with the Xe lamp and with the KrF laser for photolysis agree well within the experimental uncertainties, indicating the absence of interference due to excess NH{sub 2} laser for photolysis agree well within the experimental uncertainties, indicating the absence of interference due to excess NH{sub 2} which was produced by photolysis with the Xe lamp. A fit of rate coefficients to the Arrhenius equation yields k = (3.29 {plus minus} 1.02) {times} 10{sup {minus}12} exp({minus}(922 {plus minus} 100)/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}, with k = (1.47 {plus minus} 0.07) {times} 10{sup {minus}13} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1} at 297 K; the uncertainties represent one standard error.

  8. Defect reduction in (11-20) a-plane GaN by two step epitaxiallateral overgrowth

    SciTech Connect

    Ni, X.; Ozgur, U.; Fu, Y.; Biyikii, N.; Morkoc, H.; Liliental-Weber, Z.


    We report a two-step growth method to obtain uniformly coalesced epitaxial lateral overgrown a-plane GaN by metal-organic chemical vapor deposition (MOCVD). By obtaining a large wing height to width aspect ratio in the first step followed by enhanced lateral growth in the second step via controlling the growth temperature, we reduced the tilt angle between the advancing Ga-polar and N-polar wings for improved properties. Transmission electron microscopy (TEM) showed that the threading dislocation density in the wing area was 1.0 x 10{sup 8}cm{sup -2}, more than two orders of magnitude lower than that in the window area (4.2 x 10{sup 10} cm{sup -2}). However, a high density of basal stacking faults, 1.2 x 10{sup 4} cm{sup -1}, was still observed in the wing area. Near field scanning optical microscopy (NSOM) at room temperature revealed that the luminescence was mainly from the wing regions with very little contribution from the windows and meeting fronts. These observations suggest that due to significant reduction of threading dislocations radiative recombination is enhanced in the wings.

  9. Al{sub 2}O{sub 3}/GeO{sub x}/Ge gate stacks with low interface trap density fabricated by electron cyclotron resonance plasma postoxidation

    SciTech Connect

    Zhang, R.; Iwasaki, T.; Taoka, N.; Takenaka, M.; Takagi, S.


    An electron cyclotron resonance (ECR) plasma postoxidation method has been employed for forming Al{sub 2}O{sub 3}/GeO{sub x}/Ge metal-oxide-semiconductor (MOS) structures. X-ray photoelectron spectroscopy and transmission electron microscope characterizations have revealed that a GeO{sub x} layer is formed beneath the Al{sub 2}O{sub 3} capping layer by exposing the Al{sub 2}O{sub 3}/Ge structures to ECR oxygen plasma. The interface trap density (D{sub it}) of Au/Al{sub 2}O{sub 3}/GeO{sub x}/Ge MOS capacitors is found to be significantly suppressed down to lower than 10{sup 11} cm{sup -2} eV{sup -1}. Especially, a plasma postoxidation time of as short as 10 s is sufficient to reduce D{sub it} with maintaining the equivalent oxide thickness (EOT). As a result, the minimum D{sub it} values and EOT of 5x10{sup 10} cm{sup -2} eV{sup -1} and 1.67 nm, and 6x10{sup 10} cm{sup -2} eV{sup -1} and 1.83 nm have been realized for Al{sub 2}O{sub 3}/GeO{sub x}/Ge MOS structures with p- and n-type substrates, respectively.


    SciTech Connect

    Muller, Sebastien; Dinh-V-Trung


    We have investigated the presence of dense gas toward the radio source Cen A by looking at the absorption of the HCO{sup +} and HCN (3-2) lines in front of the bright continuum source with the Submillimeter Array. We detect narrow HCO{sup +} (3-2) absorption, and tentatively HCN (3-2), close to the systemic velocity. For both molecules, the J = 3 - 2 absorption is much weaker than for the J = 1 - 0 line. From simple excitation analysis, we conclude that the gas density is of the order of a few 10{sup 4} cm{sup -3} for a column density N(HCO{sup +})/{delta}V of 3 x 10{sup 12} cm{sup -2} km{sup -1} s and a kinetic temperature of 10 K. In particular, we find no evidence for molecular gas density higher than a few 10{sup 4} cm{sup -3} on the line of sight to the continuum source. We discuss the implications of our finding on the nature of the molecular gas responsible for the absorption toward Cen A.

  11. InGaN based micro light emitting diodes featuring a buried GaN tunnel junction

    SciTech Connect

    Malinverni, M. Martin, D.; Grandjean, N.


    GaN tunnel junctions (TJs) are grown by ammonia molecular beam epitaxy. High doping levels are achieved with a net acceptor concentration close to ∼10{sup 20 }cm{sup −3}, thanks to the low growth temperature. This allows for the realization of p-n junctions with ultrathin depletion width enabling efficient interband tunneling. n-p-n structures featuring such a TJ exhibit low leakage current densities, e.g., <5 × 10{sup −5} A cm{sup −2} at reverse bias of 10 V. Under forward bias, the voltage is 3.3 V and 4.8 V for current densities of 20 A cm{sup −2} and 2000 A cm{sup −2}, respectively. The specific series resistance of the whole device is 3.7 × 10{sup −4} Ω cm{sup 2}. Then micro-light emitting diodes (μ-LEDs) featuring buried TJs are fabricated. Excellent current confinement is demonstrated together with homogeneous electrical injection, as seen on electroluminescence mapping. Finally, the I-V characteristics of μ-LEDs with various diameters point out the role of the access resistance at the current aperture edge.

  12. Quenching of the resonance 5s({sup 3}P{sub 1}) state of krypton atoms in collisions with krypton and helium atoms

    SciTech Connect

    Zayarnyi, D A; L'dov, A Yu; Kholin, I V


    The processes of collision quenching of the resonance 5s[3/2]{sub 1}{sup o}({sup 3}P{sub 1}) state of the krypton atom are studied by the absorption probe method in electron-beam-excited high-pressure He – Kr mixtures with a low content of krypton. The rate constants of plasmochemical reactions Kr* + Kr + He → Kr*{sub 2} + He [(4.21 ± 0.42) × 10{sup -33} cm{sup 6} s{sup -1}], Kr* + 2He → HeKr* + He [(4.5 ± 1.2) × 10{sup -36} cm{sup 6} s{sup -1}] and Kr* + He → products + He [(2.21 ± 0.22) × 10{sup -15} cm{sup 3} s{sup -1}] are measured for the first time. The rate constants of similar reactions are refined for krypton in the metastable 5s[3/2]{sub 2}{sup o} ({sup 3}P{sub 2}) state. (laser applications and other topics in quantum electronics)

  13. Quenching of krypton atoms in the metastable 5s ({sup 3}P{sub 2}) state in collisions with krypton and helium atoms

    SciTech Connect

    Zayarnyi, D A; L'dov, A Yu; Kholin, I V


    We have used the absorption probe method to study the processes of collisional quenching of the metastable 5s [3/2]{sup o}{sub 2}({sup 3}P{sub 2}) state of the krypton atom in electron-beam-excited high-pressure He – Kr mixtures with a low content of krypton. The rate constants of plasma-chemical reactions Kr* + Kr + He → Kr*{sub 2}+He [(2.88 ± 0.29) × 10{sup -33} cm{sup 6} s{sup -1}], Kr* + 2He → HeKr* + He [(4.6 ± 1.3) × 10{sup -36} cm{sup 6} s{sup -1}] and Kr* + He → products + He [(1.51 ± 0.15) × 10{sup -15} cm{sup 3} s{sup -1}] are measured for the first time. The rate constants of similar reactions in the Ar – Kr mixture are refined. (active media)

  14. Volume generation of negative ions in high density hydrogen discharges. Revision 1

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.


    An optimized tandem two-chamber negative-ion source system is discussed. In the first chamber high energy (E > 20 eV) electron collisions provide for H/sub 2/ vibrational excitation, while in the second chamber negative ions are formed by dissociative attachment. The gas density, electron density, and system scale length are varied as independent parameters. The extracted negative ion current density passes through a maximum as electron and gas densities are varied. This maximum scales inversely with system scale length, R. The optimum extracted current densities occur for electron densities near nR = 10/sup 13/ electrons cm/sup -2/ and for gas densities, N/sub 2/R, in the range 10/sup 14/ to 10/sup 15/ molecules cm/sup -2/. The extracted current densities are sensitive to the atomic concentration in the discharge. The atomic concentration is parametrized by the wall recombination coefficient, ..gamma.., and scale length, R. As ..gamma.. ranges from 0.1 to 1.0 and for system scale lengths of one centimeter, extracted current densities range from 8.0 to 80. mA cm/sup -2/.

  15. Conduction below 100 °C in nominal Li6ZnNb4O14

    SciTech Connect

    Li, Yunchao; Paranthaman, Mariappan Parans; Gill, Lance W.; Edward W. Hagaman; Wang, Yangyang; Sokolov, Alexei P.; Dai, Sheng; Ma, Cheng; Chi, Miaofang; Veith, Gabriel M.; Manthiram, Arumugam; Goodenough, John B.


    The increasing demand for a safe rechargeable battery with a high energy density per cell is driving a search for a novel solid electrolyte with a high Li+ or Na+ conductivity that is chemically stable in a working Li-ion or Na-ion battery. Li6ZnNb4O14 has been reported to exhibit a σ Li > 10<sup>-2 S cm>-1 at 250 °C, but to disproportionate into multiple phases on cooling from 850 °C to room temperature. An investigation of the room-temperature Li-ion conductivity in a porous pellet of a multiphase product of a nominal Li6ZnNb4O14 composition is shown to have bulk σ Li 3.3 x 10<sup>-5 S cm>-1 at room temperature that increases to 1.4 x 10<sup>-4 S cm>-1 by 50 °C. 7Li MAS NMR spectra were fitted to two Lorentzian lines, one of which showed a dramatic increase with increasing temperature. As a result, a test for water stability indicates that Li+ may move to the particle and grain surfaces to react with adsorbed water as occurs in the garnet Li+ conductors.


    SciTech Connect

    Mayer, Lucio; Fiacconi, Davide; Bonoli, Silvia; Quinn, Thomas; Roškar, Rok; Shen, Sijing; Wadsley, James


    We present novel 3D multi-scale smoothed particle hydrodynamics (SPH) simulations of gas-rich galaxy mergers between the most massive galaxies at z ∼ 8–10, designed to scrutinize the direct collapse formation scenario for massive black hole seeds proposed in Mayer et al. The simulations achieve a resolution of 0.1 pc, and include both metallicity-dependent optically thin cooling and a model for thermal balance at high optical depth. We consider different formulations of the SPH hydrodynamical equations, including thermal and metal diffusion. When the two merging galaxy cores collide, gas infall produces a compact, optically thick nuclear disk with densities exceeding 10{sup −10} g cm{sup 3}. The disk rapidly accretes higher angular momentum gas from its surroundings reaching ∼5 pc and a mass of ≳10{sup 9} M{sub ⊙} in only a few 10{sup 4} years. Outside ≳2 pc it fragments into massive clumps. Instead, supersonic turbulence prevents fragmentation in the inner parsec region, which remains warm (∼3000–6000 K) and develops strong non-axisymmetric modes that cause prominent radial gas inflows (>10{sup 4} M{sub ⊙} yr{sup −1}), forming an ultra-dense massive disky core. Angular momentum transport by non-axisymmetric modes should continue below our spatial resolution limit, quickly turning the disky core into a supermassive protostar which can collapse directly into a massive black hole of mass 10{sup 8}–10{sup 9} M{sub ⊙} via the relativistic radial instability. Such a “cold direct collapse” explains naturally the early emergence of high-z QSOs. Its telltale signature would be a burst of gravitational waves in the frequency range of 10{sup −4}–10{sup −1} Hz, possibly detectable by the planned eLISA interferometer.


    SciTech Connect

    Xiang Jingen; Lee, Julia C.; Nowak, Michael A.; Schulz, Norbert S.; Wilms, Joern E-mail:


    We present a detailed spectral study (photoionization modeling and variability) of the 'Big Dipper' 4U 1624-490 based on a Chandra-High Energy Transmission Grating Spectrometer (HETGS) observation over the {approx}76 ks binary orbit of 4U 1624-490 . While the continuum spectrum can be modeled using a blackbody plus power law, a slightly better fit is obtained using a single {gamma} = 2.25 power-law partially (71%) covered by a local absorber of column density N{sub H,Local}=8.1{sub -0.6}{sup +0.7}x10{sup 22} cm{sup -2}. The data show a possible quasi-sinusoidal modulation with period 43{sup +13} {sub -9} ks that might be due to changes in local obscuration. Photoionization modeling with the XSTAR code and variability studies of the observed strong Fe XXV and Fe XXVI absorption lines point to a two-temperature plasma for their origin: a highly ionized component of ionization parameter {xi}{sub hot} {approx} 10{sup 4.3} erg cm s{sup -1} (T {approx} 3.0 x 10{sup 6} K) associated with an extended accretion disk corona of radius R {approx} 3 x 10{sup 10} cm, and a less-ionized more variable component of {xi} {approx} 10{sup 3.4} erg cm s{sup -1} (T {approx} 1.0 x 10{sup 6} K) and {xi}{approx}10{sup 3.1} erg cm s{sup -1} (T {approx} 0.9 x 10{sup 6} K) coincident with the accretion disk rim. We use this, with the observed Fe XXV and Fe XXVI absorption line variations (in wavelength, strength, and width) to construct a viewing geometry that is mapped to changes in plasma conditions over the 4U 1624-490 orbital period.

  18. Properties of Cometary Nuclei

    NASA Technical Reports Server (NTRS)

    Rahe, J.; Vanysek, V.; Weissman, P. R.


    Active long- and short-period comets contribute about 20 to 30 % of the major impactors on the Earth. Cometary nuclei are irregular bodies, typically a few to ten kilometers in diameter, with masses in the range 10(sup 15) to 10(sup 18) g. The nuclei are composed of an intimate mixture of volatile ices, mostly water ice and hydrocarbon and silicate grains. The composition is the closest to solar composition of any known bodies in the solar system. The nuclei appear to be weakly bonded agglomerations of smaller icy planetesimals, and material strengths estimated from observed tidal disruption events are fairly low, typically 10(sup 2) to 10(sup 4) N m(sup -2). Density estimates range between 0.2 and 1.2 g cm(sup -3) but are very poorly determined, if at all. As comets age they develop nonvolitile crusts on their surfaces which eventually render them inactive, similar in appearance to carbonaceous asteroids. However, dormant comets may continue to show sporadic activity and outbursts for some time before they become truly extinct. The source of the long-period comets is the Oort cloud, a vast spherical cloud of perhaps 10(sup 12) to 10(sup 13) comets surrounding the solar system and extending to interstellar distances. The likely source for short-period comets is the Kuiper belt. a ring of perhaps 10(sup 8) to 10(sup 10) remnant icy planetesimals beyond the orbit of Neptune, though some short-period comets may also be long-period comets from the Oort cloud which have been perturbed into short-period orbits.


    SciTech Connect

    Allafort, A.; Bottacini, E.; Cameron, R. A.; Baldini, L.; Ballet, J.; Chaves, R.C.G.; Baring, M. G.; Bastieri, D.; Buson, S.; Bellazzini, R.; Bregeon, J.; Bonamente, E.; Cecchi, C.; Brandt, T. J.; Bruel, P.; Caliandro, G. A.; Caraveo, P. A.; Chekhtman, A. E-mail:; and others


    Long-term monitoring of PSR J2021+4026 in the heart of the Cygnus region with the Fermi Large Area Telescope unveiled a sudden decrease in flux above 100 MeV over a timescale shorter than a week. The 'jump' was near MJD 55850 (2011 October 16), with the flux decreasing from (8.33 ± 0.08) × 10{sup –10} erg cm{sup –2} s{sup –1} to (6.86 ± 0.13) × 10{sup –10} erg cm{sup –2} s{sup –1}. Simultaneously, the frequency spindown rate increased from (7.8 ± 0.1) × 10{sup –13} Hz s{sup –1} to (8.1 ± 0.1) × 10{sup –13} Hz s{sup –1}. Significant (>5σ) changes in the pulse profile and marginal (<3σ) changes in the emission spectrum occurred at the same time. There is also evidence for a small, steady flux increase over the 3 yr preceding MJD 55850. This is the first observation at γ-ray energies of mode changes and intermittent behavior, observed at radio wavelengths for other pulsars. We argue that the change in pulsed γ-ray emission is due to a change in emission beaming and we speculate that it is precipitated by a shift in the magnetic field structure, leading to a change of either effective magnetic inclination or effective current.

  20. Point defects and p-type conductivity in Zn{sub 1–x}Mn{sub x}GeAs{sub 2}

    SciTech Connect

    Kilanski, L.; Podgórni, A.; Dynowska, E.; Dobrowolski, W.


    Positron annihilation spectroscopy is used to study point defects in Zn{sub 1–x}Mn{sub x}GeAs{sub 2} crystals with low Mn content 0≤x≤0.042 with disordered zincblende and chalcopyrite structure. The role of negatively charged vacancies and non-open-volume defects is discussed with respect to the high p-type conductivity with carrier concentration 10{sup 19}≤p≤10{sup 21}cm{sup −3} in our samples. Neutral As vacancies, together with negatively charged Zn vacancies and non-open-volume defects with concentrations around 10{sup 16}−10{sup 18}cm{sup −3}, are observed to increase with increasing Mn content in the alloy. The observed concentrations of defects are not sufficient to be responsible for the strong p-type conductivity of our crystals. Therefore, we suggest that other types of defects, such as extended defects, have a strong influence on the conductivity of Zn{sub 1–x}Mn{sub x}GeAs{sub 2} crystals.

  1. Study of rare processes induced by 209-Gev muons

    SciTech Connect

    Smith, W.H.


    Analysis of dimuon final states from 1.4 x 10/sup 11/ positive and 2.9 x 10/sup 10/ negative 209-Gev muons in a magnetized iron calorimeter has set a lower limit of 9 Gev/c/sup 2/ on the mass of a heavy neutral muon (M/sup 0/), and a 90%-confidence level upper limit of sigma(>..b anti bX)B(b anti b..--> mu..X)<2.9 x 10/sup -36/ cm/sup 2/ for the production of bottom hadrons by muons. The dimuon mass spectrum from 102,678 trimuon final states places a 90%-confidence level upper limit for the muoproduction of upsilon states: sigma(> mu.. UPSILON X)B(UPSILON..--> mu../sup +/ -/)<22 x 10/sup -39/ cm/sup 2/. In addition, analysis of 71 rare multimuon events, including 4- and 5-muon final states, is presented.

  2. Langmuir probe diagnostics of plasma in high current electron cyclotron resonance proton ion source

    SciTech Connect

    Roychowdhury, P.; Kewlani, H.; Mishra, L.; Mittal, K. C.; Patil, D. S.


    A high current Electron Cyclotron Resonance (ECR) proton ion source has been developed for low energy high intensity proton accelerator at Bhabha Atomic Research Centre. Langmuir probe diagnostics of the plasma generated in this proton ion source is performed using Langmuir probe. The diagnostics of plasma in the ion source is important as it determines beam parameters of the ion source, i.e., beam current, emittance, and available species. The plasma parameter measurement in the ion source is performed in continuously working and pulsed mode using hydrogen as plasma generation gas. The measurement is performed in the ECR zone for operating pressure and microwave power range of 10{sup −4}–10{sup −3} mbar and 400–1000 W. An automated Langmuir probe diagnostics unit with data acquisition system is developed to measure these parameters. The diagnostics studies indicate that the plasma density and plasma electron temperature measured are in the range 5.6 × 10{sup 10} cm{sup −3} to 3.8 × 10{sup 11} cm{sup −3} and 4–14 eV, respectively. Using this plasma, ion beam current of tens of mA is extracted. The variations of plasma parameters with microwave power, gas pressure, and radial location of the probe have been studied.

  3. Chemical modification and characterization of Te-doped n-GaSb (111) single crystals for device application

    SciTech Connect

    Basu, S.; Barman, P.


    Ru{sup +3} and Pt{sup +4} modification showed considerable improvement in the surface properties of Te-doped n-GaSb (111) single crystals. The surface carrier concentration (N{sub s}) decreased from 1.24 x 10{sup 17} to 0.42 x 10{sup 17} cm{sup {minus}3} after modification and the surface mobility ({mu}{sub s}) increased from 510.86 to 734.56 cm{sup 2}V{sup {minus}1}s{sup {minus}1}. Au/n-GaSb Schottky diodes prepared after Ru{sup +3} and Pt{sup +4} treatment of GaSb surface showed considerable increase in barrier height (V{sub s}) from 0.55 to 0.68 eV. The dark current density (J{sub o}) decreased from 3.2 x 10{sup {minus}3} to 8 x 10{sup {minus}4} A/cm{sup 2}, and the ideality factor (n) decreased from 3 to 1.54. Although Pt{sup +4} treatment also improved the GaSb surface, temperature with Ru{sup +3} produced superior results. Ru{sup +3} and Pt{sup +4} treatment effectively decreased the etch pit density considerably. 8 refs., 4 figs., 2 tabs.

  4. Transport properties of cubic crystalline Ge2Sb2Te5: a potential low-temperature thermoelectric material.

    SciTech Connect

    Sun, Jifeng; Mukhopadhyay, Saikat; Subedi, Alaska; Siegrist, Theo; Singh, David J.


    Ge2Sb2Te5 (GST) has been widely used as a popular phase change material. In this study, we show that it exhibits high Seebeck coe cients 200 - 300 μV/K in its cubic crystalline phase (c-GST) at remarkably high p-type doping levels of 1 10<sup>19 - 6 10<sup>19 cm>-3 at room temperature. More importantly, at low temperature (T = 200 K), the Seebeck coe cient was found to exceed 200 μV/K for a doping range 1 10<sup>19 - 3.5 10<sup>19 cm>-3. Given that the lattice thermal conductivity in this phase has already been measured to be extremely low ( 0.7 W/m-K at 300 K), our results suggest the possibility of using c-GST as a low-temperature thermoelectric material.

  5. Optical and electrical properties of transparent conducting B-doped ZnO thin films prepared by various deposition methods

    SciTech Connect

    Nomoto, Jun-ichi; Miyata, Toshihiro; Minami, Tadatsugu


    B-doped ZnO (BZO) thin films were prepared with various thicknesses up to about 500 nm on glass substrates at 200 deg. C by dc or rf magnetron sputtering deposition, pulsed laser deposition (PLD), and vacuum arc plasma evaporation (VAPE) methods. Resistivities of 4-6 x 10{sup -4}{Omega} cm were obtained in BZO thin films prepared with a B content [B/(B + Zn) atomic ratio] around 1 at. % by PLD and VAPE methods: Hall mobilities above 40 cm{sup 2}/Vs and carrier concentrations on the order of 10{sup 20} cm{sup -3}. All 500-nm-thick-BZO thin films prepared with a resistivity on the order of 10{sup -3}-10{sup -4}{Omega} cm exhibited an averaged transmittance above 80% in the wavelength range of 400-1100 nm. The resistivity in BZO thin films prepared with a thickness below about 500 nm was found to increase over time with exposure to various high humidity environments. In heat-resistance tests, the resistivity stability of BZO thin films was found to be nearly equal to that of Ga-doped ZnO thin films, so these films were judged suitable for use as a transparent electrode for thin-film solar cells.


    SciTech Connect

    Krasnopolsky, Ruben; Shang Hsien; Li Zhiyun


    Disk formation in magnetized cloud cores is hindered by magnetic braking. Previous work has shown that for realistic levels of core magnetization, the magnetic field suppresses the formation of rotationally supported disks during the protostellar mass accretion phase of low-mass star formation both in the ideal MHD limit and in the presence of ambipolar diffusion for typical rates of cosmic-ray ionization. Additional effects, such as ohmic dissipation, the Hall effect, and protostellar outflow, are needed to weaken the magnetic braking and enable the formation of persistent, rotationally supported, protostellar disks. In this paper, we first demonstrate that the classic microscopic resistivity is not large enough to enable disk formation by itself. We then experiment with a set of enhanced values for the resistivity in the range {eta} = 10{sup 17}-10{sup 22} cm{sup 2} s{sup -1}. We find that a value of order 10{sup 19} cm{sup 2} s{sup -1} is needed to enable the formation of a 10{sup 2} AU scale Keplerian disk; the value depends somewhat on the degree of core magnetization. The required resistivity is a few orders of magnitude larger than the classic microscopic values. Whether it can be achieved naturally during protostellar collapse remains to be determined.

  7. Global analysis of the high temperature infrared emission spectrum of {sup 12}CH{sub 4} in the dyad (ν{sub 2}/ν{sub 4}) region

    SciTech Connect

    Amyay, Badr E-mail:; Louviot, Maud; Boudon, Vincent E-mail:; Pirali, Olivier; Georges, Robert


    We report new assignments of vibration-rotation line positions of methane ({sup 12}CH{sub 4}) in the so-called dyad (ν{sub 2}/ν{sub 4}) region (1100–1500 cm{sup −1}), and the resulting update of the vibration-rotation effective model of methane, previously reported by Nikitin et al. [Phys. Chem. Chem. Phys. 15, 10071 (2013)], up to and including the tetradecad. High resolution (0.01 cm{sup −1}) emission spectra of methane have been recorded up to about 1400 K using the high-enthalpy source developed at Institut de Physique de Rennes associated with the Fourier transform spectrometer of the SOLEIL synchrotron facility (AILES beamline). Analysis of these spectra allowed extending rotational assignments in the well-known cold band (dyad-ground state (GS)) and related hot bands in the pentad–dyad system (3000 cm{sup −1}) up to J{sub max} = 30 and 29, respectively. In addition, 8512 new transitions belonging to the octad–pentad (up to J = 28) and tetradecad-octad (up to J = 21) hot band systems were successfully identified. As a result, the MeCaSDa database of methane was significantly improved. The line positions assigned in this work, together with the information available in the literature, were fitted using 1096 effective parameters with a dimensionless standard deviation σ = 2.09. The root mean square deviations d{sub RMS} are 3.60 × 10{sup −3} cm{sup −1} for dyad-GS cold band, 4.47 ×10{sup −3} cm{sup −1} for the pentad–dyad, 5.43 × 10{sup −3} cm{sup −1} for the octad–pentad, and 4.70 × 10{sup −3} cm{sup −1} for the tetradecad–octad hot bands. The resulting new line list will contribute to improve opacity and radiative transfer models for hot atmospheres, such as those of hot-Jupiter type exoplanets.

  8. Formerly utilized MED/AEC sites remedial action program: radiological survey of the Building Site 421, United States, Watertown Arsenel, Watertown, MA. Final report

    SciTech Connect


    This report contains the results of surveys of the current radiological condition of the Building Site 421, United States Arsenal Watertown, Watertown, Massachusetts. Findings of this survey indicate there are four spots involving an area of less than 6000 cm/sup 2/ of identifiable low-level residual radioactivity on the concrete pad which is all that remains of Building Site 421. The largest spot is approximately 5000 cm/sup 2/. The other three spots are 100 cm/sup 2/ or less. The beta-gamma readings at these spots are 8.4 x 10/sup 2/ dis/min-100 cm/sup 2/, 2.2 x 10/sup 5/ dis/min-100 cm/sup 2/, 2.2 x 10/sup 5/ dis/min-100 cm/sup 2/ and 8.5 x 10/sup 4/ dis/min-100 cm/sup 2/. No alpha contamination was found at these locations. Gamma spectral analysis of a chip of contaminated concrete from one of the spots indicates that the contaminant is natural uranium. This contamination is fixed in the concrete and does not present an internal or external exposure hazard under present conditions. A hypothetical hazard analysis under a conservative set of assumed conditions indicates minimal internal hazard. The highest End Window contact reading was 0.09 mR/h. None of the other three spots indicated an elevated direct reading with the End Window Detector. Radon daughter concentrations were determined at three locations on the Building 421 pad. These were 0.00013 WL, 0.00011 WL and 0.00009 WL. According to the Surgeon General's Guidelines found in 10 CFR 712, radon daughter concentrations below 0.03 WL do not require remedial action in structures other than private dwellings and schools. Soil samples taken about the site indicate no elevated levels above the natural background levels in the soil. A gamma spectral analysis of a water sample obtained from the storm sewer line near the Building 421 pad indicates no elevated radioactivity in the sample. It was therefore felt that no contamination is present in this sewer.


    SciTech Connect

    Seale, Jonathan P.; Looney, Leslie W.; Wong, Tony; Ott, Juergen; Klein, Uli; Pineda, Jorge L.


    We report the results of a high spatial (parsec) resolution HCO{sup +} (J = 1 {yields} 0) and HCN (J = 1 {yields} 0) emission survey toward the giant molecular clouds of the star formation regions N 105, N 113, N 159, and N 44 in the Large Magellanic Cloud (LMC). The HCO{sup +} and HCN observations at 89.2 and 88.6 GHz, respectively, were conducted in the compact configuration of the Australia Telescope Compact Array. The emission is imaged into individual clumps with masses between 10{sup 2} and 10{sup 4} M{sub Sun} and radii of <1 pc to {approx}2 pc. Many of the clumps are coincident with indicators of current massive star formation, indicating that many of the clumps are associated with deeply embedded forming stars and star clusters. We find that massive young stellar object (YSO) bearing clumps tend to be larger ({approx}>1 pc), more massive (M {approx}> 10{sup 3} M{sub Sun }), and have higher surface densities ({approx}1 g cm{sup -2}), while clumps without signs of star formation are smaller ({approx}<1 pc), less massive (M {approx}< 10{sup 3} M{sub Sun }), and have lower surface densities ({approx}0.1 g cm{sup -2}). The dearth of massive (M > 10{sup 3} M{sub Sun }) clumps not bearing massive YSOs suggests that the onset of star formation occurs rapidly once the clump has attained physical properties favorable to massive star formation. Using a large sample of LMC massive YSO mid-IR spectra, we estimate that {approx}2/3 of the massive YSOs for which there are Spitzer mid-IR spectra are no longer located in molecular clumps; we estimate that these young stars/clusters have destroyed their natal clumps on a timescale of at least {approx}3 Multiplication-Sign 10{sup 5} yr.


    SciTech Connect

    Gounelle, Matthieu; Chaussidon, Marc; Rollion-Bard, Claire


    A search for short-lived {sup 10}Be in 21 calcium-aluminum-rich inclusions (CAIs) from Isheyevo, a rare CB/CH chondrite, showed that only 5 CAIs had {sup 10}B/{sup 11}B ratios higher than chondritic correlating with the elemental ratio {sup 9}Be/{sup 11}B, suggestive of in situ decay of this key short-lived radionuclide. The initial ({sup 10}Be/{sup 9}Be){sub 0} ratios vary between {approx}10{sup -3} and {approx}10{sup -2} for CAI 411. The initial ratio of CAI 411 is one order of magnitude higher than the highest ratio found in CV3 CAIs, suggesting that the more likely origin of CAI 411 {sup 10}Be is early solar system irradiation. The low ({sup 26}Al/{sup 27}Al){sub 0} [{<=} 8.9 Multiplication-Sign 10{sup -7}] with which CAI 411 formed indicates that it was exposed to gradual flares with a proton fluence of a few 10{sup 19} protons cm{sup -2}, during the earliest phases of the solar system, possibly the infrared class 0. The irradiation conditions for other CAIs are less well constrained, with calculated fluences ranging between a few 10{sup 19} and 10{sup 20} protons cm{sup -2}. The variable and extreme value of the initial {sup 10}Be/{sup 9}Be ratios in carbonaceous chondrite CAIs is the reflection of the variable and extreme magnetic activity in young stars observed in the X-ray domain.

  11. Kinetic modeling of the reaction of HCl and solid lime at low temperatures

    SciTech Connect

    Fonseca, A.M.; Orfao, J.J.; Salcedo, R.L.


    Calcium hydroxide is a commonly used sorbent in the dry-scrubbing of hydrogen chloride from flue gases. In this study the kinetic parameters for the reaction between gaseous HCl and solid Ca(OH){sub 2} have been obtained at low temperatures in a fixed-bed laboratory reactor. The influence of the operating temperature (323--400 K), HCl concentration (150--1000 ppm), and humidity (0--11% M) was studied. The experimental results show that in the first few seconds a very fast chemical reaction occurs, with a reaction rate constant per unit surface area of solid larger than 10{sup {minus}3} ms{sup {minus}1}. This reaction was found to be first order relative to HCl concentration and its mechanism is apparently independent of the presence of moisture. However, the relative humidity of the gas has a major impact on the progress of the reaction: when no moisture is present the reaction stops after a short period of time (2--3 min), with very low maximum solid reactant conversions (<5%). For the experiments with humidified gas an almost complete conversion of Ca(OH){sub 2} was obtained after about 40 min of reaction time. For this case the grain model with product layer diffusion limitations is in very good agreement with the experimental results. The diffusion coefficient in the product layer obtained through this model varied from 10{sup {minus}13} to 10{sup {minus}11} m{sup 2}/s and the activation energy for this parameter was estimated at {approx}19 kJ/mol for the range of temperatures studied. A simple linear relationship describes well the effect of relative humidity of the gas on the diffusion coefficient in the solid product layer. In the presence of humidity, the very high conversions of the solid reactant show a good potential applicability to continuous dry-scrubbing at HCl at low temperatures.

  12. Fundamental studies of the plasma extraction and ion beam formation processes in inductively coupled plasma mass spectrometry

    SciTech Connect

    Niu, Hongsen


    The fundamental and practical aspects are described for extracting ions from atmospheric pressure plasma sources into an analytical mass spectrometer. Methodologies and basic concepts of inductively coupled plasma mass spectrometry (ICP-MS) are emphasized in the discussion, including ion source, sampling interface, supersonic expansion, slumming process, ion optics and beam focusing, and vacuum considerations. Some new developments and innovative designs are introduced. The plasma extraction process in ICP-MS was investigated by Langmuir measurements in the region between the skimmer and first ion lens. Electron temperature (Te) is in the range 2000--11000 K and changes with probe position inside an aerosol gas flow. Electron density (ne) is in the range 10<sup>8--10<sup>10sup> -cm at the skimmer tip and drops abruptly to 10<sup>6--10<sup>8 cm>-3 near the skimmer tip and drops abruptly to 10<sup>6--10<sup>8 cm>-3 downstream further behind the skimmer. Electron density in the beam leaving the skimmer also depends on water loading and on the presence and mass of matrix elements. Axially resolved distributions of electron number-density and electron temperature were obtained to characterize the ion beam at a variety of plasma operating conditions. The electron density dropped by a factor of 101 along the centerline between the sampler and skimmer cones in the first stage and continued to drop by factors of 10<sup>4--10<sup>5 downstream of skimmer to the entrance of ion lens. The electron density in the beam expansion behind sampler cone exhibited a 1/z2 intensity fall-off (z is the axial position). An second beam expansion originated from the skimmer entrance, and the beam flow underwent with another 1/z2 fall-off behind the skimmer. Skimmer interactions play an important role in plasma extraction in the ICP-MS instrument.

  13. Electrophysical properties of solid solutions of silver in PbTe

    SciTech Connect

    Sharov, M. K.


    The thermopower coefficient {alpha}{sub 0} and the electrical conductivity {sigma} of Pb{sub 1-x}Ag{sub x}Te solid solutions, where x = (0-0.007), are measured at T = 300 K. The hole concentration p is calculated. All samples are of the p type. With increasing silver content, {alpha}{sub 0} decreases, while p and {sigma} increase. For undoped crystals, {alpha}{sub 0} = 251.0 {mu}V/K, p = 1.1 Multiplication-Sign 10{sup 18} cm{sup -3}, and {sigma} = 165 {Omega}{sup -1} cm{sup -1}. At the silver-solubility limit for x = 0.007, {alpha}{sub 0} = 193.8 {mu}V/K, p = 2.3 Multiplication-Sign 10{sup 18} cm{sup -3}, and {sigma} = 216 {Omega}{sup -1} cm{sup -1}. The hole concentration in all samples is much lower than the concentration of introduced silver atoms. The hole gas in Pb{sub 1-x}Ag{sub x}Te solid solutions is weakly degenerate in the entire silver-concentration range.

  14. Donor behavior of Sb in ZnO

    SciTech Connect

    Liu, H. Y.; Izyumskaya, N.; Avrutin, V.; Oezguer, Ue.; Morkoc, H.; Yankovich, A. B.; Kvit, A. V.; Voyles, P. M.


    Electrical behavior of Sb in ZnO:Sb layers doped in a wide concentration range was studied using temperature dependent Hall effect measurements. The layers were grown by plasma-enhanced molecular beam epitaxy, and the Sb concentration was changed by varying the Sb flux, resulting in electron concentrations in the range of 10{sup 16} to nearly 10{sup 20} cm{sup -3}. Upon annealing, the electron concentration increased slightly and more notable was that the electron mobility significantly improved, reaching a room-temperature value of 110 cm{sup 2}/V s and a low-temperature value of 145 cm{sup 2}/V s, close to the maximum of {approx}155 cm{sup 2}/V s set by ionized impurity scattering. Hall data and structural data suggest that Sb predominantly occupies Zn sublattice positions and acts as a shallow donor in the whole concentration range studied. In the layers with high Sb content ({approx}1 at. %), acceptor-type compensating defects (possibly Sb on oxygen sites and/or point-defect complexes involving Sb{sub O}) are formed. The increase of electron concentration with increasing oxygen pressure and the increase in ZnO:Sb lattice parameter at high Sb concentrations suggest that acceptors involving Sb{sub O} rather than Sb{sub Zn}-2V{sub Zn} complexes are responsible for the compensation of the donors.

  15. Investigation of high hole mobility In{sub 0.41}Ga{sub 0.59}Sb/Al{sub 0.91}Ga{sub 0.09}Sb quantum well structures grown by molecular beam epitaxy

    SciTech Connect

    Wang, Juan; Xing, Jun-Liang; Xiang, Wei; Wang, Guo-Wei; Xu, Ying-Qiang; Ren, Zheng-Wei; Niu, Zhi-Chuan


    Modulation-doped In{sub 0.41}Ga{sub 0.59}Sb/Al{sub 0.91}Ga{sub 0.09}Sb quantum-well (QW) structures were grown by molecular beam epitaxy. Cross-sectional transmission electron microscopy and atomic force microscopy studies show high crystalline quality and smooth surface morphology. X-ray diffraction investigations confirm 1.94% compressive strain within In{sub 0.41}Ga{sub 0.59}Sb channel. High room temperature hole mobility with high sheet density of 1000 cm{sup 2}/Vs, 0.877 × 10{sup 12}/cm{sup 2}, and 965 cm{sup 2}/Vs, 1.112 × 10{sup 12}/cm{sup 2} were obtained with different doping concentrations. Temperature dependent Hall measurements show different scattering mechanisms on hole mobility at different temperature range. The sheet hole density keeps almost constantly from 300 K to 77 K. This study shows great potential of In{sub 0.41}Ga{sub 0.59}Sb/Al{sub 0.91}Ga{sub 0.09}Sb QW for high-hole-mobility device applications.

  16. GaN photovoltaic leakage current and correlation to grain size

    SciTech Connect

    Matthews, K. D.; Chen, X.; Hao, D.; Schaff, W. J.; Eastman, L. F.


    GaN p-i-n solar PV structures grown by rf plasma assisted molecular beam epitaxy (MBE) produce high performance IV characteristics with a leakage current density of less than 1x10{sup -4} mA cm{sup -2} at 0.1 V forward bias and an on-resistance of 0.039 {Omega} cm{sup 2}. Leakage current measurements taken for different size diodes processed on the same sample containing the solar cells reveal that current density increases with diode area, indicating that leakage is not a large function of surface leakage along the mesa. Nonannealed Pt/Au Ohmic p-contacts produce a contact resistivity of 4.91x10{sup -4} {Omega} cm{sup -2} for thin Mg doped contact layers with sheet resistivity of 62196 {Omega}/{open_square}. Under concentrated sunlight the cells produce an open-circuit voltage of 2.5 V and short circuit currents as high as 30 mA cm{sup -2}. Multiple growths comprised the study and on each wafer the IV curves representing several diodes showed considerable variation in parasitic leakage current density at low voltages on some wafers and practically no variation on others. It appears that a smaller grain size within the GaN thin film accounts for higher levels of dark current.


    SciTech Connect

    Hsu, W.-H.; Putman, M. E.; Peek, J. E. G.; Heitsch, F.; Clark, S. E.; Stanimirovic, S.


    Observations from the Galactic Arecibo L-band Feed Array H I (GALFA-H I) Survey of the tail of Complex C are presented and the halo clouds associated with this complex are cataloged. The properties of the Complex C clouds are compared to clouds cataloged at the tail of the Magellanic Stream to provide insight into the origin and destruction mechanism of Complex C. Magellanic Stream and Complex C clouds show similarities in their mass distributions (slope = -0.7 and -0.6 log (N( log (mass)))/ log (mass), respectively) and have a common line width of 20-30 km s{sup -1} (indicative of a warm component), which may indicate a common origin and/or physical process breaking down the clouds. The clouds cataloged at the tail of Complex C extend over a mass range of 10{sup 1.1}-10{sup 4.8} M{sub sun}, sizes of 10{sup 1.2}-10{sup 2.6} pc, and have a median volume density and pressure of 0.065 cm{sup -3} and (P/k) = 580 K cm{sup -3}. We do not see a prominent two-phase structure in Complex C, possibly due to its low metallicity and inefficient cooling compared to other halo clouds. Assuming that the Complex C clouds are in pressure equilibrium with a hot halo medium, we find a median halo density of 5.8 x 10{sup -4} cm{sup -3}, which given a constant distance of 10 kpc is at a z-height of {approx}3 kpc. Using the same argument for the Stream results in a median halo density of 8.4 x 10-{sup 5} (60 kpc/d) cm{sup -3}. These densities are consistent with previous observational constraints and cosmological simulations. We also assess the derived cloud and halo properties with three-dimensional grid simulations of halo H I clouds and find that the temperature is generally consistent within a factor of 1.5 and the volume densities, pressures, and halo densities are consistent within a factor of three.


    SciTech Connect

    Shull, J. Michael; Danforth, Charles W.; Smith, Britton D. E-mail:


    Although galaxies, groups, and clusters contain {approx}10% of the baryons, many more reside in the photoionized and shocked-heated intergalactic medium (IGM) and in the circumgalactic medium (CGM). We update the baryon census in the (H I) Ly{alpha} forest and warm-hot IGM (WHIM) at 10{sup 5-6} K traced by O VI {lambda}1032, 1038 absorption. From Enzo cosmological simulations of heating, cooling, and metal transport, we improve the H I and O VI baryon surveys using spatially averaged corrections for metallicity (Z/Z {sub Sun }) and ionization fractions (f {sub HI}, f {sub OVI}). Statistically, the O VI correction product correlates with column density, (Z/Z {sub Sun })f {sub OVI} Almost-Equal-To (0.015)(N {sub OVI}/10{sup 14} cm{sup -2}){sup 0.70}, with an N {sub OVI}-weighted mean of 0.01, which doubles previous estimates of WHIM baryon content. We also update the Ly{alpha} forest contribution to baryon density out to z = 0.4, correcting for the (1 + z){sup 3} increase in absorber density, the (1 + z){sup 4.4} rise in photoionizing background, and cosmological proper length dl/dz. We find substantial baryon fractions in the photoionized Ly{alpha} forest (28% {+-} 11%) and WHIM traced by O VI and broad-Ly{alpha} absorbers (25% {+-} 8%). The collapsed phase (galaxies, groups, clusters, CGM) contains 18% {+-} 4%, leaving an apparent baryon shortfall of 29% {+-} 13%. Our simulations suggest that {approx}15% reside in hotter WHIM (T {>=} 10{sup 6} K). Additional baryons could be detected in weaker Ly{alpha} and O VI absorbers. Further progress requires higher-precision baryon surveys of weak absorbers, down to minimum column densities N {sub HI} {>=} 10{sup 12.0} cm{sup -2}, N {sub OVI} {>=} 10{sup 12.5} cm{sup -2}, N {sub OVII} {>=} 10{sup 14.5} cm{sup -2}, using high signal-to-noise data from high-resolution UV and X-ray spectrographs.

  19. Gaseous time projection chambers for rare event detection: results from the T-REX project. II. Dark matter

    SciTech Connect

    Irastorza, I.G.; Aznar, F.; Castel, J. E-mail: [Grupo de Física Nuclear y Astropartículas, Departamento de Física Teórica, Universidad de Zaragoza, C and others


    As part of the T-REX project, a number of R and D and prototyping activities have been carried out during the last years to explore the applicability of gaseous Time Projection Chambers (TPCs) with Micromesh Gas Structures (Micromegas) in rare event searches like double beta decay, axion research and low-mass WIMP searches. While in the companion paper we focus on double beta decay, in this paper we focus on the results regarding the search for dark matter candidates, both axions and WIMPs. Small (few cm wide) ultra-low background Micromegas detectors are used to image the axion-induced x-ray signal expected in axion helioscopes like the CERN Axion Solar Telescope (CAST) experiment. Background levels as low as 0.8 × 10{sup −6} counts keV{sup −1} cm{sup −2} s{sup −1} have already been achieved in CAST while values down to ∼10{sup −7} counts keV{sup −1} cm{sup −2} s{sup −1} have been obtained in a test bench placed underground in the Laboratorio Subterráneo de Canfranc (LSC). Prospects to consolidate and further reduce these values down to ∼10{sup −8} counts keV{sup −1} cm{sup −2} s{sup −1} will be described. Such detectors, placed at the focal point of x-ray telescopes in the future International Axion Observatory (IAXO), would allow for 10{sup 5} better signal-to-noise ratio than CAST, and search for solar axions with g{sub a}γ down to few 10{sup 12} GeV{sup −1}, well into unexplored axion parameter space. In addition, a scaled-up version of these TPCs, properly shielded and placed underground, can be competitive in the search for low-mass WIMPs. The TREX-DM prototype, with ∼ 0.300 kg of Ar at 10 bar, or alternatively ∼ 0.160 kg of Ne at 10 bar, and energy threshold well below 1 keV, has been built to test this concept. We will describe the main technical solutions developed, as well as the results from the commissioning phase on surface. The anticipated sensitivity of this technique might reach ∼10{sup −44} cm{sup 2} for

  20. Some chemical kinetics issues in reburning: The branching fraction of the HCCO + NO Reaction

    SciTech Connect

    Miller, J.A.; Durant, J.L.; Glarborg, P.


    The authors have determined theoretically some critical kinetic parameters in the mechanism of NOx reburning under flow-reactor conditions. Specifically, using a variety of electronic structure methods to investigate the potential energy surfaces and the maximum free energy method of Quack and Troe to determine the resulting rate coefficients, they have deduced the values of k{sub 2} and k{sub 3} for the reactions, HCNO+O {leftrightarrow} HCO+NO (R2) and HCNO + OH {leftrightarrow} HCOH + NO, (R3) to be k{sub 2} {approx} 7 x 10{sup 13} cm{sup 3}/mole-sec. and k{sub 3} {approx} 2 x 10{sup 13} cm{sup 3}/mole-sec. independent of temperature for 300 K < T < 2,700 K. With such fast reactions converting HCNO to NO, a critical parameter in the reburn mechanism is {alpha}(T) = k{sub 1b}(T)/k{sub 1}(T), the branching fraction of the HCCO + NO reaction, HCCO + NO {leftrightarrow} HCNO+CO (R1a); HCCO + NO {leftrightarrow} HCN + CO{sub 2} (R1b); HCCO + NO {leftrightarrow} HONC + CO (R1c). Again using PES information from a variety of electronic-structure methods, the authors have used the statistical-theoretical methodology of Miller, Parrish, and Brown to determine {alpha} (T) = 0.985 exp({minus}T/1,748), valid for 300 K < T < 2,000 K. Using a value of k{sub 1} = k{sub 1a} + k{sub 1b} + k{sub 1c} = 2.4 x 10{sup 13} cm{sup 3}/mole-sec. independent of temperature (consistent with experiment) they have determined modified Arrhenius expressions for k{sub 1a} and k{sub 1b}, k{sub 1a} = 1.17 x 10{sup 13} T{sup 0.65} cm{sup 3}/mole-sec. and k{sub 1b} = 1.45 x 10{sup 16} T{sup {minus}0.968} exp({minus}648/RT) cm{sup 3}/mole-sec for 300 K < T < 2,000 K. Reaction (R1c) never contributes as much as 1% to the total rate coefficient. The theoretical analyses and the reburn mechanism are discussed in detail.

  1. Infrared reflectance measurement of ion implanted silica

    SciTech Connect

    Magruder, R.H. III; Morgan, S.H.; Weeks, R.A.; Zuhr, R.


    Infrared reflectance spectra of silica glass implanted with Ti, Cr, Mn, Fe, and Bi to doses between 0.5 - 6 /times/10/sup 16/ cm/sup /minus/2/ have been measured from 5000 cm/sup /minus/1/ to 400 cm/sup /minus/1/ at room temperature. The ion energy of the implantation was 160 keV and the current was Alterations in reflectance of bands at 1125 and 481 cm/sup /minus/1/ in the spectrum of an unimplanted sample of the order of 20% are observed. A band attributed to non-bridging oxygen ions at /approximately/1015 cm/sup /minus/1/ is observed to increase in intensity with increasing dose for all species. The band at 1125 cm/sup /minus/1/ is observed to shift to lower wavenumber with implantation. Bands due to implanted ion-oxygen vibrations were not detected. The magnitudes of the effects on the existing bands were ion specific. This ion specificity is attributed to the differing chemical states of the implanted ions after implantation. 15 refs., 8 figs.


    SciTech Connect

    Zhou, A. H.; Li, J. P.; Wang, X. D.


    In this paper, we study a novel spectral component that increases with frequency above 200 GHz in an X28 solar flare that occurred on 2003 November 4. A maximum flux density of {approx}20,000 sfu was observed at 405 GHz at main phase. We model its spectra based on gyrosynchrotron (GS) radiation computations in the case of a magnetic dipole field. Our computations show that the new increasing submillimeter spectral component at the main peak P1 can be generated by energetic electrons with a harder spectral index (2.3), low-energy cutoff of 30 keV, and number density of 10{sup 10} cm{sup -3} in a compact source (0.''5 radius) with a strong local magnetic field varying from 780 to 4590 G via GS emission. The associated microwave (MW) spectral component can be produced by energetic electrons via GS emission, but with a 10 keV low-energy cutoff and number density 1.2 x 10{sup 6} cm{sup -3} in an extended source (40'' radius) with mean magnetic field strengths from 100 to 576 G. The MW and submillimeter emission sources, inferred from the magnetic dipole field model, are located in the corona and {approx}1000 km low atmosphere levels above the photosphere, respectively. Energy flux, energy loss rate, and total energy released by energetic electrons are estimated for the first time. It is found that the energy flux can attain values of 7.2 x 10{sup 13} erg cm{sup -2} s{sup -1} in the submillimeter source. This value is four orders higher than that in the MW source. The energies released by electrons in the submillimeter and MW sources reach, respectively, 1.2 x 10{sup 32} and 1.9 x 10{sup 31} erg. The total energy released by energetic electrons is 1.4 x 10{sup 32} erg during the flare in the MW and submillimeter sources. The mean energy released by energetic electrons for a subsecond pulse, i.e., the fragment energy, is estimated to be about 5.2 x 10{sup 26} erg.

  3. Sb[subscript 2]Te[subscript 3] and Bi[subscript 2]Te[subscript 3] Thin Films Grown by Room-Temperature MBE

    SciTech Connect

    Aabdin, Z.; Peranio, N.; Winkler, M.; Bessas, D.; König, J.; Hermann, R.P.; Böttner, H.; Eibl, O.


    Sb{sub 2}Te3 and Bi{sub 2}Te3 thin films were grown on SiO{sub 2} and BaF{sub 2} substrates at room temperature using molecular beam epitaxy. Metallic layers with thicknesses of 0.2 nm were alternately deposited at room temperature, and the films were subsequently annealed at 250 C for 2 h. x-Ray diffraction and energy-filtered transmission electron microscopy (TEM) combined with high-accuracy energy-dispersive x-ray spectrometry revealed stoichiometric films, grain sizes of less than 500 nm, and a texture. High-quality in-plane thermoelectric properties were obtained for Sb{sub 2}Te3 films at room temperature, i.e., low charge carrier density (2.6 x 10{sup 19} cm{sup -3}, large thermopower (130 {micro}V K{sup -1}), large charge carrier mobility (402 cm{sup 2} V{sup -1} s{sup -1}), and resulting large power factor (29 {micro}W cm{sup -1} K{sup -2}). Bi{sub 2}Te3 films also showed low charge carrier density (2.7 x 10{sup 19} cm{sup -3}), moderate thermopower (-153 {micro}V K{sup -1}), but very low charge carrier mobility (80 cm{sup 2} V{sup -1} s{sup -1}), yielding low power factor (8 {micro}W cm{sup -1} K{sup -2}). The low mobilities were attributed to Bi-rich grain boundary phases identified by analytical energy-filtered TEM.

  4. Gamma-ray generation in ultrahigh-intensity laser-foil interactions

    SciTech Connect

    Nerush, E. N. Kostyukov, I. Yu.; Ji, L.; Pukhov, A.


    Incoherent photon emission by ultrarelativistic electrons in the normal incidence of a laser pulse on a foil is investigated by means of three-dimensional numerical simulations in the range of intensities 2 × 10{sup 21}–2 × 10{sup 25} W cm{sup −2} and electron densities 2 × 10{sup 22}–1 × 10{sup 24} cm{sup −3}. We focus on properties of the resulting synchrotron radiation, such as its overall energy, directivity of the radiation pattern, and slope of the energy spectrum. Regimes of laser-foil interactions are studied in the framework of a simple analytical model. The laser-plasma parameters for efficient gamma-ray generation are found and revealed to be close to the parameters for relativistic foil motion. It is shown that in the case of oblique incidence of a 3 PW, 10 fs laser pulse on a thin foil about 10{sup 8} photons/0.1% bandwidth are produced at the energy level of 1 MeV that significantly exceeds performance of the modern Compton gamma-ray sources. Various applications of the gamma-ray bunches are discussed.

  5. Small-angle neutron scattering study of radiation-induced defects in synthetic quartz

    SciTech Connect

    Lebedev, V. M. Lebedev, V. T.; Orlov, S. P.; Pevzner, B. Z.; Tolstikhin, I. N.


    The supraatomic structure of single crystals of synthetic quartz was studied by thermal neutron small-angle scattering in the initial state (dislocation densities 54 and 570 cm{sup -2}) and after irradiation in the WWR-M reactor (Petersburg Nuclear Physics Institute) by fast neutrons with energies E{sub n} > 0.1 MeV at fluences F{sub n} = 0.2 x 10{sup 17} -5 x 10{sup 18} neutrons/cm{sup 2}. It is established that fast neutrons form point, linear, and volume defects in the lattice throughout the entire volume of a sample. Large-volume structures-amorphous-phase nuclei-reach sizes of {approx}100 nm in quartz, while occupying a small total volume of {approx}0.3% even at the maximum fluence 5 x 10{sup 18} neutrons/cm{sup 2}. The main fraction of the damaged volume (up to 5%) corresponds to point (with a radius of gyration of 1-2 nm) and linear defects, giving a comparable contribution ({approx}1-4%). The extended linear structures with a radius of 2 nm, even at a moderate fluence of 7.7 x 10{sup 17} neutrons/cm{sup 2}, have a significant total length per volume unit ({approx}10{sup 11} cm/cm{sup 3}) and can form a connected network with a cell {approx}30 nm in size in the sample. Foreign atoms and molecules can migrate through channels of this network.

  6. Hot-gas cold-dust pumping for water masers associated with H II regions

    SciTech Connect

    Deguchi, S.


    A collisional pump with an internal sink is proposed for the water masers associated with H II regions, where the population inversion occurs due to the absorption by cold ice-mantle grains in a highly dusty cloud of the far-infrared line radiation of hot water vapor. A new escape probability method is developed to calculate the transfer of line radiation in dusty medium. The pump mechanism explains the power of usual maser sources associated with H II regions and the enormous power of the sources associated with W49 N and external galaxies. Models of maser clouds have a radius of 5 x 10/sup 15/--10/sup 16/ cm, an H/sub 2/ number density of 4 x 10/sup 9/ cm/sup -3/, an expansion velocity of 10--30 km s/sup -1/, a kinetic temperature of 350 K, and a grain temperature of 100 K. Giant maser sources require grains of the size about 1 The apparent size of the emission spots (approx.10/sup 13/ cm) observed by VLBI is interpreted as due to fluctuation in the cloud, and the assembly of the spots is spread within a size of 10/sup 16/ cm. The temperature difference between the dust and gas is due to a relaxation process after an infrared burst accompanying protostar formation.

  7. Maximum drift velocity of electrons in selectively doped InAlAs/InGaAs/InAlAs heterostructures with InAs inserts

    SciTech Connect

    Silenas, A.; Pozela, Yu. Pozela, K.; Juciene, V.; Vasil'evskii, I. S.; Galiev, G. B.; Pushkarev, S. S.; Klimov, E. A.


    The dependence of the electron mobility and drift velocity on the growth conditions, thickness, and doping of an InAs insert placed at the center of the quantum well in a selectively doped InAlAs/InGaAs/InAlAs heterostructure has been investigated. Record enhancement of the maximum drift velocity to (2-4) Multiplication-Sign 10{sup 7} cm/s in an electric field of 5 Multiplication-Sign 10{sup 3} V/cm has been obtained in a 17-nm-wide quantum well with an undoped 4-nm-thick InAs insert. In the structures with additional doping of the InAs insert, which facilitates an increase in the density of electrons in the quantum well to 4.0 Multiplication-Sign 10{sup 12} cm{sup -2}, the maximum drift velocity is as high as 2 Multiplication-Sign 10{sup 7} cm/s in an electric field of 7 Multiplication-Sign 10{sup 3} V/cm.

  8. Intense low energy positron beams

    SciTech Connect

    Lynn, K.G.; Jacobsen, F.M.


    Intense positron beams are under development or being considered at several laboratories. Already today a few accelerator based high intensity, low brightness e{sup +} beams exist producing of the order of 10{sup 8} {minus} 10{sup 9} e{sup +}/sec. Several laboratories are aiming at high intensity, high brightness e{sup +} beams with intensities greater than 10{sup 9} e{sup +}/sec and current densities of the order of 10{sup 13} {minus} 10{sup 14} e{sup +} sec{sup {minus}} {sup 1}cm{sup {minus}2}. Intense e{sup +} beams can be realized in two ways (or in a combination thereof) either through a development of more efficient B{sup +} moderators or by increasing the available activity of B{sup +} particles. In this review we shall mainly concentrate on the latter approach. In atomic physics the main trust for these developments is to be able to measure differential and high energy cross-sections in e{sup +} collisions with atoms and molecules. Within solid state physics high intensity, high brightness e{sup +} beams are in demand in areas such as the re-emission e{sup +} microscope, two dimensional angular correlation of annihilation radiation, low energy e{sup +} diffraction and other fields. Intense e{sup +} beams are also important for the development of positronium beams, as well as exotic experiments such as Bose condensation and Ps liquid studies.

  9. Search for Ultra High-Energy Neutrinos with AMANDA-II

    SciTech Connect

    IceCube Collaboration; Klein, Spencer; Ackermann, M.


    A search for diffuse neutrinos with energies in excess of 10{sup 5} GeV is conducted with AMANDA-II data recorded between 2000 and 2002. Above 10{sup 7} GeV, the Earth is essentially opaque to neutrinos. This fact, combined with the limited overburden of the AMANDA-II detector (roughly 1.5 km), concentrates these ultra high-energy neutrinos at the horizon. The primary background for this analysis is bundles of downgoing, high-energy muons from the interaction of cosmic rays in the atmosphere. No statistically significant excess above the expected background is seen in the data, and an upper limit is set on the diffuse all-flavor neutrino flux of E{sup 2} {Phi}{sub 90%CL} < 2.7 x 10{sup -7} GeV cm{sup -2}s{sup -1} sr{sup -1} valid over the energy range of 2 x 10{sup 5} GeV to 10{sup 9} GeV. A number of models which predict neutrino fluxes from active galactic nuclei are excluded at the 90% confidence level.

  10. ECR plasma source for heavy ion beam charge neutralization

    SciTech Connect

    Efthimion, P.C.; Gilson, E.; Grisham, L.; Kolchin, P.; Davidson, E.C.; Yu, S.S.; Logan, B.G.


    Highly ionized plasmas are being considered as a medium for charge neutralizing heavy ion beams in order to focus beyond the space-charge limit. Calculations suggest that plasma at a density of 1-100 times the ion beam density and at a length {approx} 0.1-2 m would be suitable for achieving a high level of charge neutralization. An ECR source has been built at the Princeton Plasma Physics Laboratory (PPPL) to support a joint Neutralized Transport Experiment (NTX) at the Lawrence Berkeley National Laboratory (LBNL) to study ion beam neutralization with plasma. The ECR source operates at 13.6 MHz and with solenoid magnetic fields of 1-10 gauss. The goal is to operate the source at pressures {approx} 10{sup -6} Torr at full ionization. The initial operation of the source has been at pressures of 10{sup -4}-10{sup -1} Torr. Electron densities in the range of 10{sup 8}-10{sup 11} cm{sup -3} have been achieved. Low-pressure operation is important to reduce ion beam ionization. A cusp magnetic field has been installed to improve radial confinement and reduce the field strength on the beam axis. In addition, axial confinement is believed to be important to achieve lower-pressure operation. To further improve breakdown at low pressure, a weak electron source will be placed near the end of the ECR source.


    SciTech Connect

    Norris, Jay P.; Gehrels, Neil


    The initial pulse complex (IPC) in short gamma-ray bursts is sometimes accompanied by a softer, low-intensity extended emission (EE) component. In cases where such a component is not observed, it is not clear if it is present but below the detection threshold. Using Bayesian Block (BB) methods, we measure the EE component and show that it is present in one-quarter of a Swift/BAT sample of 51 short bursts, as was found for the Compton/BATSE sample. We simulate bursts with EE to calibrate the BAT threshold for EE detection and show that this component would have been detected in nearly half of BAT short bursts if it were present, to intensities {approx}10{sup -2} counts cm{sup -2} s{sup -1}, a factor of 5 lower than actually observed in short bursts. In the BAT sample, the ratio of average EE intensity to IPC peak intensity, R{sub int}, ranges over a factor of 25, R{sub int} {approx} 3 x 10{sup -3} to 8 x 10{sup -2}. In comparison, for the average of the 39 bursts without an EE component, the 2{sigma} upper limit is R{sub int} < 8 x 10{sup -4}. These results suggest that a physical threshold effect operates near R{sub int} {approx} few x 10{sup -3} below which the EE component is not manifest.

  12. Deuterium pumping speed measurements on 77 K cryopanels and implications for D-T retention in neutral beam systems

    SciTech Connect

    Dylla, H.F.


    An upper limit for the pumping speed of deuterium on 77 K surfaces has been determined by in-situ pressure measurements in a TFTR neutral beam line pumped by 423 m/sup 2/ of LN/sub 2/-cooled cryopanels. The measurement has importance for estimating the tritium retention in the beam line following operation of the ion sources with tritium. No D/sub 2/ pumping was observed. An upper limit for D/sub 2/ pumping on 77 K surfaces of less than or equal to2.4 x 10/sup -7/ l/s cm/sup 2/ was determined, corresponding to a D/sub 2/ sticking coefficient of less than or equal to1.5 x 10/sup -8/. Based on the upper limit a D-T retention factor, equal to the ratio of retained D-T to D-T input, has been determined to be less than or equal to5 x 10/sup -3/. This upper limit for D-T retention bounds the tritium inventory within the beam line to a small fraction of the tritium throughput. Comparably small upper limits for hydrogenic sticking coefficients, of the order of 10/sup -6/ - 10/sup -10/, have been determined from a review of H/sub 2/O cryotrapping measurements at 77 K and from the physical adsorption studies of H/sub 2/ on H/sub 2/O at 4 K. 22 refs., 5 figs., 1 tab.

  13. On the capture of dark matter by neutron stars

    SciTech Connect

    Güver, Tolga; Erkoca, Arif Emre; Sarcevic, Ina; Reno, Mary Hall E-mail: E-mail:


    We calculate the number of dark matter particles that a neutron star accumulates over its lifetime as it rotates around the center of a galaxy, when the dark matter particle is a self-interacting boson but does not self-annihilate. We take into account dark matter interactions with baryonic matter and the time evolution of the dark matter sphere as it collapses within the neutron star. We show that dark matter self-interactions play an important role in the rapid accumulation of dark matter in the core of the neutron star. We consider the possibility of determining an exclusion region of the parameter space for dark matter mass and dark matter interaction cross section with the nucleons as well as dark matter self-interaction cross section, based on the observation of old neutron stars. We show that for a dark matter density of 10{sup 3} GeV/cm{sup 3}and dark matter mass m{sub χ} ∼< 10 GeV, there is a potential exclusion region for dark matter interactions with nucleons that is three orders of magnitude more stringent than without self-interactions. The potential exclusion region for dark matter self-interaction cross sections is many orders of magnitude stronger than the current Bullet Cluster limit. For example, for high dark matter density regions, we find that for m{sub χ} ∼ 10 GeV when the dark matter interaction cross section with the nucleons ranges from σ{sub χn} ∼ 10{sup −52} cm{sup 2} to σ{sub χn} ∼ 10{sup −57} cm{sup 2}, the dark matter self-interaction cross section limit is σ{sub χχ} ∼< 10{sup −33} cm{sup 2}, which is about ten orders of magnitude stronger than the Bullet Cluster limit.


    SciTech Connect

    Goldsmith, Paul F.; Yıldız, Umut A.; Langer, William D.; Pineda, Jorge L.


    We present the first large-scale high angular resolution survey of ionized nitrogen in the Galactic Plane through emission of its two fine structure transitions ([N ii]) at 122 and 205 μm. The observations were largely obtained with the PACS instrument onboard the Herschel Space Observatory. The lines of sight were in the Galactic plane, following those of the Herschel OTKP project GOT C+. Both lines are reliably detected at the 10{sup −8}–10{sup −7} Wm{sup −2} sr{sup −1} level over the range –60° ≤ l ≤ 60°. The rms of the intensity among the 25 PACS spaxels of a given pointing is typically less than one third of the mean intensity, showing that the emission is extended. [N ii] is produced in gas in which hydrogen is ionized, and collisional excitation is by electrons. The ratio of the two fine structure transitions provides a direct measurement of the electron density, yielding n(e) largely in the range 10–50 cm{sup −3} with an average value of 29 cm{sup −3} and N{sup +} column densities 10{sup 16}–10{sup 17} cm{sup −2}. [N ii] emission is highly correlated with that of [C ii], and we calculate that between 1/3 and 1/2 of the [C ii] emission is associated with the ionized gas. The relatively high electron densities indicate that the source of the [N ii] emission is not the warm ionized medium (WIM), which has electron densities more than 100 times smaller. Possible origins of the observed [N ii] include the ionized surfaces of dense atomic and molecular clouds, the extended low-density envelopes of H ii regions, and low-filling factor high-density fluctuations of the WIM.

  15. Amorphization effects on pure titanium using C{sup +}, O{sup +} and Cr{sup +} ion implantation

    SciTech Connect

    Athanasiou, N.S.; Lanza, F.; Paracchini, L.; Brossa, F.


    In this work, the influence of the amorphization effect of C{sup +}, O{sup +} and Cr{sup +} implantation on the friction and wettability properties of pure titanium (grade 2) has been studied. Doses from 1 {times} 10{sup 17} to 5 {times} 10{sup 17} ions cm{sup {minus}2} at multiple energies of 50 to 190 keV have been used. Additionally, pin-on-disk tribological tests using Ultra-High-Molecular-Weight-Polyethylene (UHMWPE) pins under lubricated conditions and wettability measurements of implanted and unimplanted titanium samples were carried out. The authors found, that the more suitable material for the wettability and hence wear resistance is C{sup +} implanted titanium, because of its higher surface energy than the unimplanted titanium corresponding energy. Friction tests on monoenergetic 180 keV C{sup +} and O{sup +} modified titanium with 1 {times} 10{sup 17} ions cm{sup {minus}2} have showed an essentially reduced friction compared to samples implanted with the same dose but at multiple energies. A reduction of the wettability by about 7% and the friction coefficient by about 18% was observed for carbon implanted titanium with a dose of 1 {times} 10{sup 17} C{sup +} cm{sup {minus}2}; this effect corresponds to a good correlation between wettability and friction coefficient after C{sup +} implantation in titanium. It was concluded that the reduction of the friction coefficient with monoenergetic C{sup +} implanted titanium is 3.7 times lower compared with those of pure titanium.

  16. Ion-irradiation study of the exotic'' mineral neptunite: LiNa sub 2 K(Fe,Mg,Mn) sub 2 Ti sub 2 Si sub 8 O sub 24

    SciTech Connect

    Eby, R.K.; Wang, L.M.; Ewing, R.C. . Dept. of Geology); Arnold, G.W. )


    Single crystals of the rare silicate neptunite were irradiated with 600 keV Ar{sup 2+} and 1.5 MeV Kr{sup +}, and analyzed by transmission electron microscopy (TEM). Amorphization was observed in a surface layer only several hundred angstroms thick following Ar{sup 2+} irradiations up to 5.0 {times} 10{sup 13} Ar/cm{sup 2}, yet the Ar{sup 2+} ions traveled an average of 1/2 {mu}m in depth. Ionization is the dominant energy-loss process in the near surface region, and thus may contribute to the formation of the amorphous surface layer. The microstructure of the amorphous surface layer depends on the ion fluence, but the amorphous layer thickness remained constant. At the highest fluence, a narrow region below the amorphous layer shows a brittle-to-ductile strain transition, due to tensional volume-expansion of the adjacent ductile amorphous layer. Using 1.5 MeV Kr{sup +}, amorphization of the electron transparent region was completed after a fluence of 1.5 {times} 10{sup 15} Kr{sup +}/cm{sup 2}, and no further damage was observed up to 5.1 {times} 10{sup 15} Kr{sup +}/cm{sup 2}. Then, using a low fluence of 2.0 {times} 10{sup 11} Kr{sup +}/cm{sup +}, a single crystal of neptunite became a polycrystalline aggregate (grain size 10 nm) after aging 10 days at room temperature. 6 refs., 6 figs.

  17. Anatomical and hydraulic properties of sorghum roots exposed to water deficit. [Sorghum bicolor

    SciTech Connect

    Cruz, R.T.; Jordan, W.R.; Drew, M.C. )


    The effects of a severe water stress in the upper 0-0.15 m rooting zone on development of the exodermis, endodermis and xylem and on radial (Lp) and axial (Ls) hydraulic conductances were studied for Sorghum bicolor. Lp and Lx were based on water flow rates obtained by applying a negative hydrostatic pressure to the proximal xylem ends of excised roots placed in aerated nutrient solution. The same roots were stained with fluorescent berberine and acid phloroglucinol to describe the development of the exodermal and endodermal cell walls from formation of the Casparian band (State I), to deposition of suberin lamellae (State II), and lignification (State III). Lp of 1.5 {times} 10{sup {minus}11} m{sup 3}s{sup {minus}1}MPa{sup {minus}1} was 80% lower in stressed roots than in unstressed controls. At 0.01 and 0.07 m from the root apex, stressed roots were in State III while control roots were in States I and II, respectively. SEM-image analysis for stressed roots indicated that in the exodermis a greater proportion of the cross sectional area was occupied by lignified walls than in the endodermis. Cellufluor, an apoplastic tracer, was blocked at the lignified exodermis even at 0.01 m from the apex in stressed roots. Uranin, a symplastic tracer, was taken up only in the apical region in stressed roots but farther from the apex in the controls. Lx of 7.1 {times} 10{sup {minus}11}m{sup 3}s{sup {minus}1}MPa{sup {minus}1} was 90% lower in stressed roots compared with the controls. Cellufluor test and image analysis showed that although the protoxylem and early metaxylem were conductive in both treatments, stress caused more than a 50% reduction in the diameter of the xylem elements. Results suggest that lignification of the exodermis and endodermis to a large extent decreased apoplastic and symplastic flows and hence Lp in stressed roots. The low Lx in stressed roots was due to a decrease in the diameters of the conductive xylem elements.


    SciTech Connect

    McQuinn, Kristen B. W.; Skillman, Evan D.; Dalcanton, Julianne J.; Weisz, Daniel R.; Williams, Benjamin F.; Dolphin, Andrew E.; Cannon, John M.; Holtzman, Jon


    Using star formation histories derived from optically resolved stellar populations in 19 nearby starburst dwarf galaxies observed with the Hubble Space Telescope, we measure the stellar mass surface densities of stars newly formed in the bursts. By assuming a star formation efficiency (SFE), we then calculate the inferred gas surface densities present at the onset of the starbursts. Assuming an SFE of 1%, as is often assumed in normal star-forming galaxies, and assuming that the gas was purely atomic, translates to very high H I surface densities ({approx}10{sup 2}-10{sup 3} M{sub Sun} pc{sup -2}), which are much higher than have been observed in dwarf galaxies. This implies either higher values of SFE in these dwarf starburst galaxies or the presence of significant amounts of H{sub 2} in dwarfs (or both). Raising the assumed SFEs to 10% or greater (in line with observations of more massive starbursts associated with merging galaxies), still results in H I surface densities higher than observed in 10 galaxies. Thus, these observations appear to require that a significant fraction of the gas in these dwarf starbursts galaxies was in the molecular form at the onset of the bursts. Our results imply molecular gas column densities in the range 10{sup 19}-10{sup 21} cm{sup -2} for the sample. In the galaxies where CO observations have been made, these densities correspond to values of the CO-H{sub 2} conversion factor (X{sub CO}) in the range >(3-80) Multiplication-Sign 10{sup 20} cm{sup -2} (K km s{sup -1}){sup -1}, or up to 40 Multiplication-Sign greater than Galactic X{sub CO} values.

  19. The effect of CO2(aq), Al(aq) and temperature on feldspar dissolution

    SciTech Connect

    Carroll, S; Knauss, K


    The authors measured labradorite (Ca{sub 0.6}Na{sub 0.4}Al{sub 1.6}Si{sub 2.4}O{sub 8}) dissolution rates using a mixed flow reactor from 30 to 130 C as a function of CO{sub 2} (3 x 10{sup -3} and 0.6 M), and aluminum (10{sup -6} to 10{sup -3}M) at pH 3.2. Over these conditions, labradorite dissolution can be described with a single rate expression that accounts for observed increases in dissolution rate with temperature and decreases in dissolution rate with dissolved aluminum: Rate{sub Si} (mol Labradorite cm{sup -2} s{sup -1}) = k{double_prime} x 10{sup -Ea/2.303RT} [(a{sub H{sup +}}{sup 3n}/a{sub Al{sup 3+}}{sup n})K{sub T}/(1+K{sub T} (a{sub H{sup +}}{sup 3n}/a{sub Al{sup 3+}}{sup n}))] where the apparent dissolution rate constant, k{double_prime} = 10{sup -5.69} (mol Labradorite cm{sup -2}s{sup -1}); the net activation energy, E{sub a} = 10.06 (kcal mol{sup -1}); H{sup +}-Al{sup 3+} exchange coefficient, n = 0.31; and silica rich surface complex formation constant K{sub T} = 4.5 to 5.6 from 30 to 130 C. The effect of CO{sub 2}(aq) on mineral dissolution is accounted for by changes in solution pH. At temperatures below 60 C, labradorite dissolves incongruently with preferential dissolution of Na, Ca and Al over Si.


    SciTech Connect

    Goodman, Michael L.


    A magnetohydrodynamic model that includes a complete electrical conductivity tensor is used to estimate conditions for photospherically driven, linear, non-plane Alfvenic oscillations extending from the photosphere to the lower corona to drive a chromospheric heating rate due to Pedersen current dissipation that is comparable to the observed net chromospheric radiative loss of {approx}10{sup 7} erg cm{sup -2} s{sup -1}. The heating rates due to electron current dissipation in the photosphere and corona are also computed. The wave amplitudes are computed self-consistently as functions of an inhomogeneous background (BG) atmosphere. The effects of the conductivity tensor are resolved numerically using a resolution of 3.33 m. The oscillations drive a chromospheric heating flux F{sub Ch} {approx} 10{sup 7}-10{sup 8} erg cm{sup -2} s{sup -1} at frequencies {nu} {approx} 10{sup 2}-10{sup 3} mHz for BG magnetic field strengths B {approx}> 700 G and magnetic field perturbation amplitudes {approx}0.01-0.1 B. The total resistive heating flux increases with {nu}. Most heating occurs in the photosphere. Thermalization of Poynting flux in the photosphere due to electron current dissipation regulates the Poynting flux into the chromosphere, limiting F{sub Ch}. F{sub Ch} initially increases with {nu}, reaches a maximum, and then decreases with increasing {nu} due to increasing electron current dissipation in the photosphere. The resolution needed to resolve the oscillations increases from {approx}10 m in the photosphere to {approx}10 km in the upper chromosphere and is {proportional_to}{nu}{sup -1/2}. Estimates suggest that these oscillations are normal modes of photospheric flux tubes with diameters {approx}10-20 km, excited by magnetic reconnection in current sheets with thicknesses {approx}0.1 km.

  1. Sulfur chemistry in the envelope of VY Canis Majoris: Detailed analysis of SO and SO{sub 2} emission

    SciTech Connect

    Adande, G. R.; Edwards, J. L.; Ziurys, L. M.


    Detailed radiative transfer modeling has been carried out for SO{sub 2} and SO originating in the envelope of the O-rich supergiant star VY Canis Majoris (VY CMa). A total of 27 transitions of SO{sub 2} and 7 transitions of SO lying in the energy range 3.0-138.2 cm{sup –1} were analyzed using a new non-LTE radiative transfer code that incorporates non-spherical geometries. The spectra were primarily obtained from the Arizona Radio Observatory (ARO) 1 mm spectral survey of VY CMa, conducted with the Submillimeter Telescope; additional lines were measured with the ARO 12 m antenna at 2 and 3 mm. SO{sub 2} and SO were found to arise from five distinct outflows within the envelope, four which are asymmetric with respect to the star. Three flows arise from high-velocity red-shifted material, one from a blue-shifted wind, and the final from a classic 'spherical' expansion. In the spherical component, the peak fractional abundance, relative to H{sub 2}, of both molecules is f ∼ 2.5 × 10{sup –7} at r ∼ 25 R {sub *}, and steadily decreases outward. SO{sub 2} appears to be a 'parent' molecule, formed near the stellar photosphere. In the asymmetric outflows, both SO and SO{sub 2} are more prominent at large stellar radii in dense (10{sup 6}-10{sup 7} cm{sup –3}), clumpy material, achieving their maximum abundance between 200 and 600 R {sub *} with f ∼ 3.0 × 10{sup –8}-1.5 × 10{sup –7}. These results suggest that in the collimated outflows, both species are either produced by shock chemistry or are remnant inner shell material swept up in the high-velocity winds.

  2. Fast electron propagation in Ti foils irradiated with sub-picosecond laser pulses at Iλ{sup 2}>10{sup 18} Wcm{sup −2}μm{sup 2}

    SciTech Connect

    Makita, M.; Nersisyan, G.; McKeever, K.; Dzelzainis, T.; White, S.; Kettle, B.; Dromey, B.; Doria, D.; Zepf, M.; Lewis, C. L. S.; Riley, D.; Robinson, A. P. L.; Hansen, S. B.


    We have studied the propagation of fast electrons through laser irradiated Ti foils by monitoring the emission of hard X-rays and K-α radiation from bare foils and foils backed by a thick epoxy layer. Key observations include strong refluxing of electrons and divergence of the electron beam in the foil with evidence of magnetic field collimation. Our diagnostics have allowed us to estimate the fast electron temperature and fraction of laser energy converted to fast electrons. We have observed clear differences between the fast electron temperatures observed with bare and epoxy backed targets which may be due to the effects of refluxing.

  3. Possibility of effective lasing at the 02/sup 0/1(10/sup 0/1). -->. 01/sup 1/1 transitions of the CO/sub 2/ molecule

    SciTech Connect

    Petrukhov, V.O.; Tochitskii, S.Ya.; Churakov, V.V.


    The conditions necessary for obtaining effective lasing at the vibrational-rotational transitions of the title bands of the carbon dioxide molecule were examined. The formation of inversion at these transitions was evaluated using an ordinary pulsed TEA carbon dioxide laser and a temperature model used to describe processes occurring in laser materials. The threshold conditions to be realized in the material to create inversion on the 16 (14)micrometer channel were examined and the values of the energy output and peak power were estimated.

  4. NuSTAR and XMM-Newton observations of luminous, heavily obscured, WISE-selected quasars at z ∼ 2

    SciTech Connect

    Stern, D.; Eisenhardt, P. R. M.; Lansbury, G. B.; Alexander, D. M.; Del Moro, A.; Gandhi, P.; Assef, R. J.; Brandt, W. N.; Griffith, R. L.; Ballantyne, D. R.; Baloković, M.; Bridge, C.; Bauer, F. E.; Benford, D.; Blain, A.; Boggs, S. E.; Craig, W. W.; Brightman, M.; Christensen, F. E.; Comastri, A.; and others


    We report on a NuSTAR and XMM-Newton program that has observed a sample of three extremely luminous, heavily obscured WISE-selected active galactic nuclei (AGNs) at z ∼ 2 across a broad X-ray band (0.1 – 79 keV). The parent sample, selected to be faint or undetected in the WISE 3.4 μm (W1) and 4.6 μm (W2) bands but bright at 12 μm (W3) and 22 μm (W4), are extremely rare, with only ∼1000 so-called 'W1W2-dropouts' across the extragalactic sky. Optical spectroscopy reveals typical redshifts of z ∼ 2 for this population, implying rest-frame mid-IR luminosities of νL {sub ν}(6 μm) ∼ 6 × 10{sup 46} erg s{sup –1} and bolometric luminosities that can exceed L {sub bol} ∼ 10{sup 14} L {sub ☉}. The corresponding intrinsic, unobscured hard X-ray luminosities are L(2-10 keV) ∼ 4 × 10{sup 45} erg s{sup –1} for typical quasar templates. These are among the most AGNs known, though the optical spectra rarely show evidence of a broad-line region and the selection criteria imply heavy obscuration even at rest-frame 1.5 μm. We designed our X-ray observations to obtain robust detections for gas column densities N {sub H} ≤ 10{sup 24} cm{sup –2}. In fact, the sources prove to be fainter than these predictions. Two of the sources were observed by both NuSTAR and XMM-Newton, with neither being detected by NuSTAR (f {sub 3-24} {sub keV} ≲ 10{sup –13} erg cm{sup –2} s{sup –1}), and one being faintly detected by XMM-Newton (f {sub 0.5-10} {sub keV} ∼ 5 × 10{sup –15} erg cm{sup –2} s{sup –1}). A third source was observed only with XMM-Newton, yielding a faint detection (f {sub 0.5-10} {sub keV} ∼ 7 × 10{sup –15} erg cm{sup –2} s{sup –1}). The X-ray data imply these sources are either X-ray weak, or are heavily obscured by column densities N {sub H} ≳ 10{sup 24} cm{sup –2}. The combined X-ray and mid-IR analysis seems to favor this second possibility, implying the sources are extremely obscured, consistent with Compton

  5. Shock tube measurements of high temperature rate constants for OH with cycloalkanes and methylcycloalkanes.

    SciTech Connect

    Sivaramakrishnan, R.; Michael, J. V.; Chemical Sciences and Engineering Division


    High temperature experiments were performed with the reflected shock tube technique using multi-pass absorption spectrometric detection of OH radicals at 308 nm. The present experiments span a wide T-range, 801-1347 K, and represent the first direct measurements of the title rate constants at T>500 K for cyclopentane and cyclohexane and the only high temperature measurements for the corresponding methyl derivatives. The present work utilized 48 optical passes corresponding to a total path length 4.2 m. As a result of this increased path length, the high [OH] detection sensitivity permitted unambiguous analyses for measuring the title rate constants. The experimental rate constants in units, cm3 molecule-1 s-1, can be expressed in Arrhenius form as k{sub OH+Cyclopentane} = (1.90 {+-} 0.30) x 10{sup -10} exp(-1705 {+-} 156 K/T) (813-1341 K), k{sub OH+Cyclohexane} = (1.86 {+-} 0.24) x 10{sup -10} exp(-1513 {+-} 123 K/T) (801-1347 K), k{sub OH+Methylcyclopentane} = (2.02 {+-} 0.19) x 10{sup -10} exp(-1799 {+-} 96 K/T) (859-1344 K), k{sub OH+Methylcyclohexane} = (2.55 {+-} 0.30) x 10{sup -10} exp(-1824 {+-} 114 K/T) (836-1273 K). These results and lower-T experimental data were used to obtain three parameter evaluations of the experimental rate constants for the title reactions over an even wider T-range. These experimental three parameter fits to the rate constants in units, cm{sup 3} molecule{sup -1} s{sup -1}, are k{sub OH+Cyclopentane} = 1.390 x 10{sup -16}T{sup 1.779} exp(97 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (209-1341 K), k{sub OH+Cyclohexane} = 3.169 x 10{sup -16} T{sup 1.679} exp(119 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (225-1347 K), k{sub OH+Methylcyclopentane} = 6.903 x 10{sup -18}T{sup 2.148} exp(536 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1344 K), k{sub OH+Methylcyclohexane} = 2.341 x 10{sup -18}T{sup 2.325} exp(602 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1273 K). High level electronic structure methods were used to characterize the


    SciTech Connect

    Spinoglio, Luigi; Pereira-Santaella, Miguel; Busquet, Gemma; Schirm, Maximilien R. P.; Wilson, Christine D.; Parkin, Tara J.; Glenn, Jason; Kamenetzky, Julia; Rangwala, Naseem; Maloney, Philip R.; Bendo, George J.; Madden, Suzanne C.; Boselli, Alessandro; Cooray, Asantha; Page, Mathew J.


    The first complete submillimeter spectrum (190-670 {mu}m) of the Seyfert 2 galaxy NGC 1068 has been observed with the SPIRE Fourier transform spectrometer on board the Herschel Space Observatory. The sequence of CO lines (J {sub up} = 4-13), lines from H{sub 2}O, the fundamental rotational transition of hydrogen fluoride, two o-H{sub 2}O{sup +} lines, and one line each from CH{sup +} and OH{sup +} have been detected, together with the two [C I] lines and the [N II] 205 {mu}m line. The observations in both single pointing mode with sparse image sampling and in mapping mode with full image sampling allow us to disentangle two molecular emission components, one due to the compact circumnuclear disk (CND) and one from the extended region encompassing the star-forming ring (SF-ring). Radiative transfer models show that the two CO components are characterized by densities of n(H{sub 2}) = 10{sup 4.5} and 10{sup 2.9} cm{sup -3} and temperatures of T {sub kin} = 100 K and 127 K, respectively. A comparison of the CO line intensities with the photodissociation region (PDR) and X-ray-dominated region (XDR) models, together with the other observational constraints, such as the observed CO surface brightness and the radiation field, indicates that the best explanation for the CO excitation of the CND is an XDR with a density of n(H{sub 2}) {approx} 10{sup 4} cm{sup -3} and an X-ray flux of 9 erg s{sup -1} cm{sup -2}, consistent with illumination by the active galactic nucleus, while the CO lines in the SF-ring are better modeled by a PDR. The detected water transitions, together with those observed with the Herschel PACS spectrometer, can be modeled by a large velocity gradient model with low temperature (T {sub kin} {approx} 40 K) and high density (n(H{sub 2}) in the range 10{sup 6.7}-10{sup 7.9} cm{sup -3}). The emission of H{sub 2}O{sup +} and OH{sup +} are in agreement with PDR models with cosmic-ray ionization. The diffuse ionized atomic component observed through the [N

  7. Steady-state and transient photoconductivity in c-axis GaN nanowires grown by nitrogen-plasma-assisted molecular beam epitaxy

    SciTech Connect

    Sanford, N. A.; Blanchard, P. T.; Bertness, K. A.; Mansfield, L.; Schlager, J. B.; Sanders, A. W.; Roshko, A.; Burton, B. B.; George, S. M.


    Analysis of steady-state and transient photoconductivity measurements at room temperature performed on c-axis oriented GaN nanowires yielded estimates of free carrier concentration, drift mobility, surface band bending, and surface capture coefficient for electrons. Samples grown (unintentionally n-type) by nitrogen-plasma-assisted molecular beam epitaxy primarily from two separate growth runs were examined. The results revealed carrier concentration in the range of (3-6)x10{sup 16} cm{sup -3} for one growth run, roughly 5x10{sup 14}-1x10{sup 15} cm{sup -3} for the second, and drift mobility in the range of 500-700 cm{sup 2}/(V s) for both. Nanowires were dispersed onto insulating substrates and contacted forming single-wire, two-terminal structures with typical electrode gaps of {approx_equal}3-5 {mu}m. When biased at 1 V bias and illuminated at 360 nm (3.6 mW/cm{sup 2}) the thinner ({approx_equal}100 nm diameter) nanowires with the higher background doping showed an abrupt increase in photocurrent from 5 pA (noise level) to 0.1-1 {mu}A. Under the same conditions, thicker (151-320 nm) nanowires showed roughly ten times more photocurrent, with dark currents ranging from 2 nA to 1 {mu}A. With the light blocked, the dark current was restored in a few minutes for the thinner samples and an hour or more for the thicker ones. The samples with lower carrier concentration showed similar trends. Excitation in the 360-550 nm range produced substantially weaker photocurrent with comparable decay rates. Nanowire photoconductivity arises from a reduction in the depletion layer via photogenerated holes drifting to the surface and compensating ionized surface acceptors. Simulations yielded (dark) surface band bending in the vicinity of 0.2-0.3 V and capture coefficient in the range of 10{sup -23}-10{sup -19} cm{sup 2}. Atomic layer deposition (ALD) was used to conformally deposit {approx_equal}10 nm of Al{sub 2}O{sub 3} on several devices. Photoconductivity, persistent

  8. Liquid phase epitaxial growth and characterization of germanium far infrared blocked impurity band detectors

    SciTech Connect

    Bandaru, Jordana


    Germanium Blocked Impurity Band (BIB) detectors require a high purity blocking layer (< 10<sup>13 cm>-3) approximately 1 mm thick grown on a heavily doped active layer (~ 10<sup>16cm-3) approximately 20 mm thick. Epilayers were grown using liquid phase epitaxy (LPE) of germanium out of lead solution. The effects of the crystallographic orientation of the germanium substrate on LPE growth modes were explored. Growth was studied on substrates oriented by Laue x-ray diffraction between 0.02° and 10° from the {111} toward the {100}. Terrace growth was observed, with increasing terrace height for larger misorientation angles. It was found that the purity of the blocking layer was limited by the presence of phosphorus in the lead solvent. Unintentionally doped Ge layers contained ~10<sup>15 cm>-3 phosphorus as determined by Hall effect measurements and Photothermal Ionization Spectroscopy (PTIS). Lead purification by vacuum distillation and dilution reduced the phosphorus concentration in the layers to ~ 10<sup>14 cm>-3 but further reduction was not observed with successive distillation runs. The graphite distillation and growth components as an additional phosphorus source cannot be ruled out. Antimony (~10<sup>16 cm>-3) was used as a dopant for the active BIB layer. A reduction in the donor binding energy due to impurity banding was observed by variable temperature Hall effect measurements. A BIB detector fabricated from an Sb-doped Ge layer grown on a pure substrate showed a low energy photoconductive onset (~6 meV). Spreading resistance measurements on doped layers revealed a nonuniform dopant distribution with Sb pile-up at the layer surface, which must be removed by chemomechanical polishing. Sb diffusion into the pure substrate was observed by Secondary Ion Mass Spectroscopy (SIMS) for epilayers grown at 650 C. The Sb concentration at the interface dropped by an order of magnitude

  9. DLTS analysis of amphoteric interface defects in high-TiO{sub 2} MOS structures prepared by sol-gel spin-coating

    SciTech Connect

    Kumar, Arvind; Mondal, Sandip; Rao, K. S. R. Koteswara E-mail:


    High-κ TiO{sub 2} thin films have been fabricated from a facile, combined sol – gel spin – coating technique on p and n type silicon substrate. XRD and Raman studies headed the existence of anatase phase of TiO{sub 2} with a small grain size of 18 nm. The refractive index ‘n’ quantified from ellipsometry is 2.41. AFM studies suggest a high quality, pore free films with a fairly small surface roughness of 6 Å. The presence of Ti in its tetravalent state is confirmed by XPS analysis. The defect parameters observed at the interface of Si/TiO{sub 2} were studied by capacitance – voltage (C – V) and deep level transient spectroscopy (DLTS). The flat – band voltage (V{sub FB}) and the density of slow interface states estimated are – 0.9, – 0.44 V and 5.24×10{sup 10}, 1.03×10{sup 11} cm{sup −2}; for the NMOS and PMOS capacitors, respectively. The activation energies, interface state densities and capture cross – sections measured by DLTS are E{sub V} + 0.30, E{sub C} – 0.21 eV; 8.73×10{sup 11}, 6.41×10{sup 11} eV{sup −1} cm{sup −2} and 5.8×10{sup −23}, 8.11×10{sup −23} cm{sup 2} for the NMOS and PMOS structures, respectively. A low value of interface state density in both P- and N-MOS structures makes it a suitable alternate dielectric layer for CMOS applications. And also very low value of capture cross section for both the carriers due to the amphoteric nature of defect indicates that the traps are not aggressive recombination centers and possibly can not contribute to the device operation to a large extent.

  10. Results on the spin-dependent scattering of weakly interacting massive particles on nucleons from the Run 3 Data of the LUX Experiment

    SciTech Connect

    Akerib, D. S.


    Here, we present experimental constraints on the spin-dependent WIMP (weakly interacting massive particle)-nucleon elastic cross sections from LUX data acquired in 2013. LUX is a dual-phase xenon time projection chamber operating at the Sanford Underground Research Facility (Lead, South Dakota), which is designed to observe the recoil signature of galactic WIMPs scattering from xenon nuclei. A profile likelihood ratio analysis of 1.4 × 10<sup>4 kg day of fiducial exposure allows 90% C.L. upper limits to be set on the WIMP-neutron (WIMP-proton) cross section of σn = 9.4 × 10<sup>–41 cm>2 (σp = 2.9 × 10<sup>–39 cm>2) at 33 GeV/c2. The spin-dependent WIMP-neutron limit is the most sensitive constraint to date.

  11. Reaction rate constant for OH + HOONO/sub 2/. -->. products over the temperature range 246 to 324 K

    SciTech Connect

    Trevor, P.L.; Black, G.; Barker, J.R.


    Absolute bimolecular reaction rate constants for the title reaction have been determined for temperatures ranging from 246 to 324 K. The laser flash-photolysis resonance-fluorescence (LFPRF) technique was used to generate O(/sup 1/D) which reacted with H/sub 2/ and/or H/sub 2/O to produce OH radicals. The bimolecular rate constants for the title reaction showed no dependence on total (He) pressure over the range approx. 3 to 15 torr, and they did not depend upon initial (OH) or upon its mode of formation. The H/sub 2/O/sub 2/ impurity was explicitly measured in all experiments, and the rate constants were corrected for its contribution. A weighted least-squares analysis of the data obtained at nine temperatures (226 data points) gave the Arrhenius expression (k +- 1sigma) = (8.05 +- 5.69) x 10/sup -12/ exp (-193 +- 194/T) cm/sup 3/ s/sup -1/ with covariance 1.098 x 10/sup -9/. A simple weighted average (temperature independent) fits the data just as well, and when the effects of systematic errors are taken into account, our recommended rate constant is (k +- 2sigma) = (4.0 +- 1.6) x 10/sup -12/ cm/sup 3/ s/sup -1/.

  12. Extended carrier lifetimes and diffusion in hybrid perovskites revealed by Hall effect and photoconductivity measurements

    SciTech Connect

    Chen, Y.; Yi, H. T.; Wu, X.; Haroldson, R.; Gartstein, Y. N.; Rodionov, Y. I.; Tikhonov, K. S.; Zakhidov, A.; Zhu, X. -Y.; Podzorov, V.


    Impressive performance of hybrid perovskite solar cells reported in recent years still awaits a comprehensive understanding of its microscopic origins. In this work, the intrinsic Hall mobility and photocarrier recombination coefficient are directly measured in these materials in steady-state transport studies. The results show that electron-hole recombination and carrier trapping rates in hybrid perovskites are very low. The bimolecular recombination coefficient (10<sup>–11 to 10<sup>–10sup> cm>3 s–1) is found to be on par with that in the best direct-band inorganic semiconductors, even though the intrinsic Hall mobility in hybrid perovskites is considerably lower (up to 60 cm>2 V–1 s–1). Measured here, steady-state carrier lifetimes (of up to 3 ms) and diffusion lengths (as long as 650 μm) are significantly longer than those in high-purity crystalline inorganic semiconductors. As a result, we suggest that these experimental findings are consistent with the polaronic nature of charge carriers, resulting from an interaction of charges with methylammonium dipoles.

  13. Formation of p-type Cu{sub 3}BiS{sub 3} absorber thin films by annealing chemically deposited Bi{sub 2}S{sub 3}{endash}CuS thin films

    SciTech Connect

    Nair, P.K.; Huang, L.; Nair, M.T.; Hu, H.; Meyers, E.A.; Zingaro, R.A.


    Formation of the ternary compound Cu{sub 3}BiS{sub 3} during annealing of chemically deposited CuS ({approximately}0.3 {mu}m) films on Bi{sub 2}S{sub 3} film ({approximately}0.1 {mu}m on glass substrate) is reported. The interfacial atomic diffusion leading to the formation of the compound during the annealing is indicated in x-ray photoelectron depth profile spectra on the films. The formation of Cu{sub 3}BiS{sub 3} (Wittichenite, JCPDS 9-488) is confirmed by the XRD patterns. The films are optically absorbing in the entire visible region (absorption coefficient 4{times}10{sup 4} cm{sup {minus}1} at 2.48 eV or 0.50 {mu}m) and are p-type with electrical conductivity of 10{sup 2}{endash}10{sup 3} {Omega}{sup {minus}1} cm{sup {minus}1}. Potential applications of these films as optical coatings in the control of solar energy transmittance through glazings and as a p-type absorber film in solar cell structures are indicated. {copyright} {ital 1997 Materials Research Society.}

  14. Simultaneous enhancement of carrier mobility and concentration via tailoring of Al-chemical states in Al-ZnO thin films

    SciTech Connect

    Kumar, Manish Wen, Long; Sahu, Bibhuti B.; Han, Jeon Geon


    Simultaneously achieving higher carriers concentration and mobility is a technical challenge against up-scaling the transparent-conductive performances of transparent-conductive oxides. Utilizing one order higher dense (∼1 × 10{sup 11} cm{sup −3}) plasmas (in comparison to the conventional direct current plasmas), highly c-axis oriented Al-doped ZnO films have been prepared with precise control over relative composition and chemical states of constituting elements. Tailoring of intrinsic (O vacancies) and extrinsic (ionic Al and zero-valent Al) dopants provide simultaneous enhancement in mobility and concentration of charge carriers. Room-temperature resistivity as low as 4.89 × 10{sup −4} Ω cm along the carrier concentration 5.6 × 10{sup 20} cm{sup −3} is obtained in 200 nm thick transparent films. Here, the control of atomic Al reduces the charge trapping at grain boundaries and subdues the effects of grain boundary scattering. A mechanism based on the correlation between electron-hole interaction and carrier mobility is proposed for degenerately doped wide band-gap semiconductors.

  15. Characterization of electron cyclotron resonance hydrogen plasmas

    SciTech Connect

    Outten, C.A. . Dept. of Nuclear Engineering); Barbour, J.C.; Wampler, W.R. )


    Electron cyclotron resonance (ECR) plasmas yield low energy and high ion density plasmas. The characteristics downstream of an ECR hydrogen plasma were investigated as a function of microwave power and magnetic field. A fast-injection Langmuir probe and a carbon resistance probe were used to determine plasma potential (V{sub p}), electron density (N{sub e}), electron temperature (T{sub e}), ion energy (T{sub i}), and ion fluence. Langmuir probe results showed that at 17 cm downstream from the ECR chamber the plasma characteristics are approximately constant across the center 7 cm of the plasma for 50 Watts of absorbed power. These results gave V{sub p} = 30 {plus minus} 5 eV, N{sub e} = 1 {times} 10{sup 8} cm{sup {minus}3}, and T{sub e} = 10--13 eV. In good agreement with the Langmuir probe results, carbon resistance probes have shown that T{sub i} {le} 50 eV. Also, based on hydrogen chemical sputtering of carbon, the hydrogen (ion and energetic neutrals) fluence rate was determined to be 1 {times} 10{sup 16}/cm{sup 2}-sec. at a pressure of 1 {times} 10{sup {minus}4} Torr and for 50 Watts of absorbed power. 19 refs.

  16. Neutron activation analysis at the Californium User Facility for Neutron Science

    SciTech Connect

    Martin, R.C.; Smith, E.H.; Glasgow, D.C.; Jerde, E.A.; Marsh, D.L.; Zhao, L.


    The Californium User Facility (CUF) for Neutron Science has been established to provide {sup 252}Cf-based neutron irradiation services and research capabilities including neutron activation analysis (NAA). A major advantage of the CUF is its accessibility and controlled experimental conditions compared with those of a reactor environment The CUF maintains the world`s largest inventory of compact {sup 252}Cf neutron sources. Neutron source intensities of {le} 10{sup 11} neutrons/s are available for irradiations within a contamination-free hot cell, capable of providing thermal and fast neutron fluxes exceeding 10{sup 8} cm{sup {minus}2} s{sup {minus}1} at the sample. Total flux of {ge}10{sup 9} cm{sup {minus}2} s{sup {minus}1} is feasible for large-volume irradiation rabbits within the {sup 252}Cf storage pool. Neutron and gamma transport calculations have been performed using the Monte Carlo transport code MCNP to estimate irradiation fluxes available for sample activation within the hot cell and storage pool and to design and optimize a prompt gamma NAA (PGNAA) configuration for large sample volumes. Confirmatory NAA irradiations have been performed within the pool. Gamma spectroscopy capabilities including PGNAA are being established within the CUF for sample analysis.

  17. Spectroscopic analysis of temperature and density of Sn plasma produced by a CO{sub 2} laser

    SciTech Connect

    Shaikh, Nek M.; Tao, Y.; Burdt, R. A.; Yuspeh, S.; Tillack, M. S.; Amin, N.


    The temporal and spatial evolution of electron temperature and electron density from Sn plasma produced by a CO{sub 2} laser has been investigated in vacuum using spectroscopic methods. The plasma parameters were inferred by the Boltzmann plot method from experimentally observed line profiles of singly ionized Sn and Stark broadened profiles. At a laser intensity of 10{sup 10} W/cm{sup 2}, electron temperature and density were measured to be within 1.13 eV to 0.53 eV and 5.3x10{sup 16} cm{sup -3} to 1.4x10{sup 16} cm{sup -3}, respectively, for delay times between 200 ns and 1100 ns, and at distances up to 5 mm along the target normal. The results show the electron temperature and density from Sn plasma produced by a CO{sub 2} laser with wavelength of 10.6 {mu}m to be lower than previously reported results using a 1064 nm laser in a similar parameter regime. The lower temperature in the region far away from the target surface confirms the smaller interaction region for CO{sub 2} laser as compared with that of neodymium-doped yttrium aluminum garnet laser.

  18. An inverted cylindrical sputter magnetron as metal vapor supply for electron cyclotron resonance ion sources

    SciTech Connect

    Weichsel, T. Hartung, U.; Kopte, T.; Zschornack, G.; Kreller, M.; Silze, A.


    An inverted cylindrical sputter magnetron device has been developed. The magnetron is acting as a metal vapor supply for an electron cyclotron resonance (ECR) ion source. FEM simulation of magnetic flux density was used to ensure that there is no critical interaction between both magnetic fields of magnetron and ECR ion source. Spatially resolved double Langmuir probe and optical emission spectroscopy measurements show an increase in electron density by one order of magnitude from 1 × 10{sup 10} cm{sup −3} to 1 × 10{sup 11} cm{sup −3}, when the magnetron plasma is exposed to the magnetic mirror field of the ECR ion source. Electron density enhancement is also indicated by magnetron plasma emission photography with a CCD camera. Furthermore, photographs visualize the formation of a localized loss-cone - area, when the magnetron is operated at magnetic mirror field conditions. The inverted cylindrical magnetron supplies a metal atom load rate of R > 1 × 10{sup 18} atoms/s for aluminum, which meets the demand for the production of a milliampere Al{sup +} ion beam.

  19. Asymmetrical In{sub 0.1}Ga{sub 0.9}As/Al{sub 0.3}Ga{sub 0.7}As quantum rings and their optical properties

    SciTech Connect

    Tangmettajittakul, O. Changmoung, P. Thainoi, S. Ratanathammaphan, S. Panyakeow, S.


    In{sub 0.1}Ga{sub 0.9}As/Al{sub 0.3}Ga{sub 0.7}As quantum rings were fabricated by droplet epitaxy technique using molecular beam epitaxy (MBE). 7.5 ML In{sub 0.1}Ga{sub 0.9}As droplets are deposited on Al{sub 0.3}Ga{sub 0.7}As epitaxial layer at 350°C and 250°C. After that, they were crystallized under As{sub 4} pressure of 8×10{sup −6} torr at 250°C. The surface morphology of quantum rings is studied by atomic force microscopy. It is found that quantum rings are not symmetrical due to anisotropic behavior of In and Ga atom migration during crystallization process. The quantum ring density of the sample deposition at 350°C and 250°C are 1×10{sup 9} cm{sup −2} and 2.6×10{sup 9} cm{sup −2}, respectively. Consequently, the asymmetric quantum rings with deposition at 350°C give two photoluminescence (PL) peaks at 1.27 and 1.38 eV at 20K. However, the PL peak of quantum rings with deposition at 350°C is merged with GaAs peak due to the poor size distribution.

  20. A view of the implanted SiC damage by Rutherford backscattering spectroscopy, spectroscopic ellipsometry, and transmission electron microscopy

    SciTech Connect

    Battistig, G.; Khanh, N. Q.; Petrik, P.; Lohner, T.; Dobos, L.; Pecz, B.; Garcia Lopez, J.; Morilla, Y.


    4H-SiC single crystalline substrates were implanted at room temperature with 150 keV Al{sup +} ions using fluences of 4x10{sup 14}, 1x10{sup 15}, and 2x10{sup 15} cm{sup -2} with current density of 2.5 {mu}A cm{sup -2}. The samples were subsequently annealed at 1100 deg. C in N{sub 2} for 1 h in order to analyze their structural recovery. The disorder induced in both sublattices by the Al{sup +} ions was studied by backscattering spectrometry in channeling geometry with a 3.5 MeV He{sup 2+} beam. The results were compared with the optical properties of the samples measured by spectroscopic ellipsometry. In a previous work, we concluded that during the postimplantation annealing of a highly damaged SiC crystalline material the short distance order can be recovered, while the long distance disorder remains. We also presented the possibility to have grains of different polytypes oriented faraway from the original direction. Now, this alternative is confirmed by the cross-sectional transmission and high resolution electron microscopy studies, carried out to obtain information about the crystal structure.

  1. Thermal conductivity of color-flavor-locked quark matter

    SciTech Connect

    Braby, Matt; Chao Jingyi; Schaefer, Thomas


    We compute the thermal conductivity of color-flavor-locked (CFL) quark matter. At temperatures below the scale set by the gap in the quark spectrum, transport properties are determined by collective modes. In this work we focus on the contribution from the lightest modes, the superfluid phonon and the massive neutral kaon. The calculation is done in the framework of kinetic theory, using variational solutions of the linearized Boltzmann equation. We find that the thermal conductivity owing to phonons is kappa{sup (P)}approx1.04x10{sup 26} mu{sub 500}{sup 8}DELTA{sub 50}{sup -6} erg cm{sup -1} s{sup -1} K{sup -1} and the contribution of kaons is kappa{sup (K)}approx2.81x10{sup 21} f{sub p}i{sub ,100}{sup 4}T{sub MeV}{sup 1/2}m{sub 10}{sup -5/2} erg cm{sup -1} s{sup -1} K{sup -1}. These values are smaller than previous estimates but still much larger than (in the case of phonons) or similar to (for kaons) the corresponding values in nuclear matter. From the phonon thermal conductivity we estimate that a CFL quark matter core of a compact star becomes isothermal on a time scale of a few seconds.


    SciTech Connect

    Hidaka, Hiroshi; Kondo, Tomoyo; Yoneda, Shigekazu


    Large and heterogeneous isotopic variations of {sup 150}Sm/{sup 149}Sm and {sup 158}Gd/{sup 157}Gd due to neutron capture reactions caused by cosmic-ray irradiation were found in chemical and mineral separates from the Norton County meteorite. The light-colored separates, consisting mainly of enstatite (Mg{sub 2}Si{sub 2}O{sub 6}), have a very large neutron fluence of 1.98 Multiplication-Sign 10{sup 17} n cm{sup -2}, which is 10 times higher than that of the whole rock. Furthermore, four chemical separates showed a large variation in neutron fluences, ranging from 1.82 Multiplication-Sign 10{sup 16} to 1.87 Multiplication-Sign 10{sup 17} n cm{sup -2}. The variable amounts of neutron fluences from a small single fragment of the Norton County meteorite cannot be simply explained by single-stage cosmic-ray irradiation in space. Rare earth element (REE) analyses revealed that the fractions with high neutron fluences have similar chemical properties to those in the early condensates in the solar system, showing depletions of Eu and Yb in their REE abundance patterns. The data provide evidence for an activity of the early Sun (T Tauri), suggesting the migration of early and intense irradiation materials into the Norton County meteorite's parent body.

  3. Gas-phase reaction between calcium monocation and fluoromethane: Analysis of the potential energy hypersurface and kinetics calculations

    SciTech Connect

    Varela-Alvarez, Adrian; Sordo, Jose A.; Rayon, V. M.; Redondo, P.; Barrientos, C.


    The gas-phase reaction between calcium monocation and fluoromethane: Ca{sup +}+CH{sub 3}F{yields}CaF{sup +}+CH{sub 3} was theoretically analyzed. The potential energy hypersurface was explored by using density functional theory methodology with different functionals and Pople's, Dunning's, Ahlrichs', and Stuttgart-Dresden basis sets. Kinetics calculations (energy and total angular momentum resolved microcanonical variational/conventional theory) were accomplished. The theoretically predicted range for the global kinetic rate constant values at 295 K (7.2x10{sup -11}-5.9x10{sup -10} cm{sup 3} molecule{sup -1} s{sup -1}) agrees reasonably well with the experimental value at the same temperature [(2.6{+-}0.8)x10{sup -10} cm{sup 3} molecule{sup -1} s{sup -1}]. Explicit consideration of a two transition state model, where the formation of a weakly bounded prereactive complex is preceded by an outer transition state (entrance channel) and followed by an inner transition state connecting with a second intermediate that finally leads to products, is mandatory. Experimental observations on the correlation, or lack of correlation, between reaction rate constants and second ionization energies of the metal might well be rationalized in terms of this two transition state model.

  4. Design, construction, and operation of a laboratory scale reactorfor the production of high-purity, isotopically enriched bulksilicon

    SciTech Connect

    Ager III, J.W.; Beeman, J.W.; Hansen, W.L.; Haller, E.E.


    The design and operation of a recirculating flow reactor designed to convert isotopically enriched silane to polycrystalline Si with high efficiency and chemical purity is described. The starting material is SiF{sub 4}, which is enriched in the desired isotope by a centrifuge method and subsequently converted to silane. In the reactor, the silane is decomposed to silicon on the surface of a graphite starter rod (3 mm diameter) heated to 700-750 C. Flow and gas composition (0.3-0.5% silane in hydrogen) are chosen to minimize the generation of particles by homogeneous nucleation of silane and to attain uniform deposition along the length of the rod. Growth rates are 5 {micro}m/min, and the conversion efficiency is greater than 95%. A typical run produces 35 gm of polycrystalline Si deposited along a 150 mm length of the rod. After removal of the starter rod, dislocation-free single crystals are formed by the floating zone method. Crystals enriched in all 3 stable isotopes of Si have been made: {sup 28}Si (99.92%), {sup 29}Si (91.37%), and {sup 30}Si (88.25%). Concentrations of electrically active impurities (P and B) are as low as mid-10{sup 13} cm{sup -3}. Concentrations of C and O lie below 10{sup 16} and 10{sup 15} cm{sup -3}, respectively.

  5. Temperature admittance spectroscopy of boron doped chemical vapor deposition diamond

    SciTech Connect

    Zubkov, V. I. Kucherova, O. V.; Zubkova, A. V.; Ilyin, V. A.; Afanas'ev, A. V.; Bogdanov, S. A.; Vikharev, A. L.; Butler, J. E.


    Precision admittance spectroscopy measurements over wide temperature and frequency ranges were carried out for chemical vapor deposition epitaxial diamond samples doped with various concentrations of boron. It was found that the experimentally detected boron activation energy in the samples decreased from 314 meV down to 101 meV with an increase of B/C ratio from 600 to 18000 ppm in the gas reactants. For the heavily doped samples, a transition from thermally activated valence band conduction to hopping within the impurity band (with apparent activation energy 20 meV) was detected at temperatures 120–150 K. Numerical simulation was used to estimate the impurity DOS broadening. Accurate determination of continuously altering activation energy, which takes place during the transformation of conduction mechanisms, was proposed by numerical differentiation of the Arrhenius plot. With increase of boron doping level the gradual decreasing of capture cross section from 3 × 10{sup −13} down to 2 × 10{sup −17} cm{sup 2} was noticed. Moreover, for the hopping conduction the capture cross section becomes 4 orders of magnitude less (∼2 × 10{sup −20} cm{sup 2}). At T > T{sub room} in doped samples the birth of the second conductance peak was observed. We attribute it to a defect, related to the boron doping of the material.


    SciTech Connect

    Ott, Juergen; Henkel, Christian; Weiss, Axel; Staveley-Smith, Lister E-mail: chenkel@mpifr-bonn.mpg.d E-mail:


    The first detection of ammonia (NH{sub 3}) is reported from the Magellanic Clouds. Using the Australia Telescope Compact Array, we present a targeted search for the (J, K) = (1,1) and (2,2) inversion lines toward seven prominent star-forming regions in the Large Magellanic Cloud (LMC). Both lines are detected in the massive star-forming region N 159 W, which is located in the peculiar molecular ridge south of 30 Doradus, a site of extreme star formation strongly influenced by an interaction with the Milky Way halo. Using the ammonia lines, we derive a kinetic temperature of {approx}16 K, which is 2-3 times below the previously derived dust temperature. The ammonia column density, averaged over {approx}17'', is {approx}6 x 10{sup 12} cm{sup -2} (<1.5 x 10{sup 13} cm{sup -2} over 9'' in the other six sources) and we derive an ammonia abundance of {approx}4 x 10{sup -10} with respect to molecular hydrogen. This fractional abundance is 1.5-5 orders of magnitude below those observed in Galactic star-forming regions. The nitrogen abundance in the LMC ({approx}10% solar) and the high UV flux, which can photo-dissociate the particularly fragile NH{sub 3} molecule, both must contribute to the low fractional NH{sub 3} abundance, and we likely only see the molecule in an ensemble of the densest, best shielded cores of the LMC.


    SciTech Connect

    Teng, Stacy H.; Darg, Dan W.; Kaviraj, Sugata; Lintott, Chris J.; Oh, Kyuseok; Cardamone, Carolin N.; Keel, William C.; Simmons, Brooke D.; Treister, Ezequiel


    We present the results from a Chandra pilot study of 12 massive galaxy mergers selected from Galaxy Zoo. The sample includes major mergers down to a host galaxy mass of 10{sup 11} M{sub Sun} that already have optical active galactic nucleus (AGN) signatures in at least one of the progenitors. We find that the coincidences of optically selected active nuclei with mildly obscured (N{sub H} {approx}< 1.1 Multiplication-Sign 10{sup 22} cm{sup -2}) X-ray nuclei are relatively common (8/12), but the detections are too faint (<40 counts per nucleus; f{sub 2-10keV} {approx}< 1.2 Multiplication-Sign 10{sup -13} erg s{sup -1} cm{sup -2}) to reliably separate starburst and nuclear activity as the origin of the X-ray emission. Only one merger is found to have confirmed binary X-ray nuclei, though the X-ray emission from its southern nucleus could be due solely to star formation. Thus, the occurrences of binary AGNs in these mergers are rare (0%-8%), unless most merger-induced active nuclei are very heavily obscured or Compton thick.

  8. High-temperature photochemistry and BAC-MP4 studies of the reaction between ground-state H atoms and N/sub 2/O

    SciTech Connect

    Marshall, P.; Fontijn, A.; Melius, C.F.


    The H+N/sub 2/O reaction has been investigated using the high-temperature photochemistry (HTP) technique. H(1 /sup 2/S) atoms were generated by flash photolysis of NH/sub 3/ and monitored by time-resolved atomic resonance fluorescence with pulse counting. The bimolecular rate coefficient for H-atom consumption, leading essentially to N/sub 2/+OH, from 390 to 1310 K is found to be given by k/sub 1/(T) = 5.5 x 10/sup -14/ exp(-2380 K/T)+7.3 x 10/sup -10/ exp(-9690 K/T) cm/sup 3/ molecule/sup -1/ s/sup -1/; the accuracy is assessed as approximately 25% at the 2sigma confidence level. Above 750 K, k/sub 1/ closely follows the Arrhenius behavior of the second term alone. Distinct curvature is evident below 750 K. k/sub 1/ is compared to theoretical BAC-MP4 predictions and good agreement is found for a model involving rearrangement of an HNNO intermediate coupled with tunneling through an Eckart potential barrier, which dominates at the lower temperatures. The branching ratio for the channel leading to NH+NO is discussed in the context of recent thermochemical information and a maximum rate coefficient of <1 x 10/sup -9/ exp(-15800 K/T) cm/sup 3/ molecule/sup -1/ s/sup -1/ is set for temperatures up to 2000 K.

  9. Tracing Gas Motions in the Centaurus Cluster

    SciTech Connect

    Graham, James; Fabian, A.C.; Sanders, J.S.; Morris, R.G.; /Cambridge U., Inst. of Astron. /KIPAC, Menlo Park


    We apply the stochastic model of iron transport developed by Rebusco et al. (2005) to the Centaurus cluster. Using this model, we find that an effective diffusion coefficient D in the range 2 x 10{sup 28} - 4 x 10{sup 28} cm{sup 2}s{sup -1} can approximately reproduce the observed abundance distribution. Reproducing the flat central profile and sharp drop around 30-70 kpc, however, requires a diffusion coefficient that drops rapidly with radius so that D > 4 x 10{sup 28} cm{sup 2}s{sup -1} only inside about 25 kpc. Assuming that all transport is due to fully-developed turbulence, which is also responsible for offsetting cooling in the cluster core, we calculate the length and velocity scales of energy injection. These length scales are found to be up to a factor of {approx} 10 larger than expected if the turbulence is due to the inflation and rising of a bubble. We also calculate the turbulent thermal conductivity and find it is unlikely to be significant in preventing cooling.

  10. Application of non-porous alumina based ceramics as structural material for devices handling tritium at elevated temperatures

    SciTech Connect

    Yukhimchuk, A.A.; Maksimkin, I.P.; Baluev, V.V.; Boitsov, I.E.; Vertey, A.V.; Malkov, I.L.; Musyaev, R.K.; Popov, V.V.; Sitdikov, D.T.; Khapov, A.S.; Grishechkin, S.K.; Kiselev, V.G.


    The article presents results of comparative tests for the determination of deuterium fluxes permeating through walls of austenitic stainless steel AISI304 (DIN 1.4301) chamber and Al{sub 2}O{sub 3} based ceramic F99.7 chamber. Both chambers represent a piece of φ(ext)=26*φ(int)=22*117 mm{sup 3} tube with spherical bottom ending. It is shown that at 773 K and deuterium pressure of 1200 mbar the permeated deuterium flux through the stainless steel chamber constituted 8*10{sup -5} cm{sup 3}/s, while the flux through ceramic one it did not exceed the sensitivity of the measurement method threshold, namely about 1.5*10{sup -7} cm{sup 3}/s. The ceramic chamber turned out to survive more than 10{sup 3} cycles of heating up to 773 K with no damages. It did not lose its tightness up to 10 bar of internal deuterium pressure. The authors also present test results of a prototype bed for reversible tritium storage. The bed's case was made of alumina based ceramic F99.7, titanium being used as tritide making metal and high frequency induction used for heating the tritide metal. (authors)

  11. Electronic and mechanical properties of Ge films grown on glass substrates

    SciTech Connect

    Ahrenkiel, R.K.; Ahrenkiel, S.P.; Al-Jassim, M.M.; Venkatasubramanian, R.


    As germanium is closed lattice matched to GaAs, it is a suitable substrate for epitaxial growth. In the quest for inexpensive substrates, thin-film Ge grown on glass is an attractive candidate if suitable grain growth can be achieved. Here the authors will describe Ge films that are deposited by an e-beam evaporator on glass and are approximately 2000 {angstrom} thick. The films were annealed at 500 C and 600 C to improve the quality of the material. The growth was done in three steps with 1000 {angstrom} of Ge, 70 {angstrom} of Sb, and followed by another 1000 {angstrom} of Ge. Sb is an n-type dopant in Ge and is included to enhance grain growth. The best films contained the Sb layer and hole concentrations between 1.4 {times} 10{sup 15} to 1.6 {times} 10{sup 17} cm{sup {minus}3}. The largest hole mobility measured was 30.6 cm{sup 2}/Vs in the 1.4 {times} 10{sup 15} p-type sample. The electron lifetime was measured by ultra-high frequency photoconductive decay and the best lifetimes were in the 30- to 40-ns range. Scanning-electron microscope and transmission-electron microscope studies indicated a polycrystalline grain structure with grain size comparable to the film thickness.

  12. The effect of irradiation with high-energy protons on 4H-SiC detectors

    SciTech Connect

    Kazukauskas, V. Jasiulionis, R.; Kalendra, V.; Vaitkus, J.-V.


    The effect of irradiation of 4H-SiC ionizing-radiation detectors with various doses (as high as 10{sup 16} cm{sup -2}) of 24-GeV protons is studied. Isotopes of B, Be, Li, He, and H were produced in the nuclear spallation reactions of protons with carbon. Isotopes of Al, Mg, Na, Ne, F, O, and N were produced in the reactions of protons with silicon. The total amount of the produced stable isotopes varied in proportion with the radiation dose from 1.2 x 10{sup 11} to 5.9 x 10{sup 13} cm{sup -2}. It is shown that, at high radiation doses, the contact characteristics of the detectors change appreciably. The potential-barrier height increased from the initial value of 0.7-0.75 eV to 0.85 eV; the rectifying characteristics of the Schottky contacts deteriorated appreciably. These effects are attributed to the formation of a disordered structure of the material as a result of irradiation.

  13. Vertical GaN power diodes with a bilayer edge termination

    SciTech Connect

    Dickerson, Jeramy R.; Allerman, Andrew A.; Bryant, Benjamin N.; Fischer, Arthur J.; King, Michael P.; Moseley, Michael W.; Armstrong, Andrew M.; Kaplar, Robert J.; Kizilyalli, Isik C.; Aktas, Ozgur; Wierer, Jr., Jonathan J.


    Vertical GaN power diodes with a bilayer edge termination (ET) are demonstrated. The GaN p-n junction is formed on a low threading dislocation defect density (10<sup>4 - 10<sup>5 cm>-2) GaN substrate, and has a 15-μm-thick n-type drift layer with a free carrier concentration of 5 × 10<sup>15 cm>-3. The ET structure is formed by N implantation into the p+-GaN epilayer just outside the p-type contact to create compensating defects. The implant defect profile may be approximated by a bilayer structure consisting of a fully compensated layer near the surface, followed by a 90% compensated (p) layer near the n-type drift region. These devices exhibit avalanche breakdown as high as 2.6 kV at room temperature. In addition simulations show that the ET created by implantation is an effective way to laterally distribute the electric field over a large area. This increases the voltage at which impact ionization occurs and leads to the observed higher breakdown voltages.

  14. Current response of a TlBr detector to {sup 137}Cs {gamma}-ray radiation

    SciTech Connect

    Gazizov, I. M.; Zaletin, V. M.; Kukushkin, V. M.; Khrunov, V. S.


    The current response of a TlBr detector to {sup 137}Cs {gamma}-ray radiation has been studied in the dose-rate range 0.033-3.84 Gy/min and within the voltage range 1-300 V; the detectors are based on pure and doped TlBr crystals grown from the melt by the Bridgman-Stockbarger method. The mass fraction of Pb or Ca introduced into the TlBr crystals was 1-10 ppm for Pb and 150 ppm for Ca. The current response of nominally undoped TlBr samples was nearly linear over two decades of studied dose rates. Deep hole levels associated with cationic vacancies V{sub c}{sup -} determine the dependence of the current response on the voltage in the high electric fields. The parameters of the carriers' transport {mu}{tau} are determined. The TlBr crystals grown in vacuum and in the bromine vapor exhibit a large mobility-lifetime product of 4.3 Multiplication-Sign 10{sup -4} and 6.4 Multiplication-Sign 10{sup -5} cm{sup 2}V{sup -1}, respectively. The value of {mu}{tau} is in the range (4-9) Multiplication-Sign 10{sup -5} cm{sup 2}V{sup -1} for crystals doped with a divalent cation.


    SciTech Connect

    Bricker, Glynn E.; Caffee, Marc W. E-mail: mcaffee@purdue.ed


    We propose a model for the incorporation of {sup 10}Be within calcium-aluminum inclusions (CAIs) in primitive carbonaceous meteorites. In this model, {sup 10}Be is produced by energetic particle reactions in the proto-solar atmosphere of a more active proto-Sun characterized by energetic particle fluxes higher than contemporary particle fluxes. This {sup 10}Be is incorporated into the solar wind that is then implanted into CAI precursor material. This production mechanism is operational in the contemporary solar system implanting {sup 10}Be in lunar materials. The contemporary production rate of {sup 10}Be at the surface of the Sun is {approx}0.1 {sup 10}Be cm{sup -2} s{sup -1}. Scaling up the contemporary {sup 10}Be production in the proto-Sun by a factor of 10{sup 5} would increase the production rate to 10{sup 410}Be cm{sup -2} s{sup -1}. Using this enhanced production value in conjunction with refractory mass inflow rates at 0.06 AU from the proto-Sun we model {sup 10}Be concentrations in CAI precursors. We calculate the content of solar-wind-implanted {sup 10}Be would have been of the order of 10{sup 1210}Be g{sup -1} in CAIs, consistent with initial{sup 10}Be content found from boron-beryllium isotopic systematics in CAIs.

  16. Helium solubility in SON68 nuclear waste glass

    SciTech Connect

    Fares, Toby; Peuget, Sylvain; Bouty, Olivier; Broudic, Veronique; Maugeri, Emilio; Bes, Rene; Jegou, Christophe; Chamssedine, Fadel; Sauvage, Thierry; Deschanels, Xavier


    Helium behavior in a sodium borosilicate glass (SON68) dedicated to the immobilization of high-level nuclear waste is examined. Two experimental approaches on nonradioactive glass specimens are implemented: pressurized helium infusion experiments and {sup 3}He ion implantation experiments. The temperature variation of helium solubility in SON68 glass was determined and analyzed with the harmonic oscillator model to determine values of the energy of interaction E(0) at the host sites (about -4000 J/mol), the vibration frequency (about 1.7 x 10{sup 11} s{sup -1}), and the density of solubility sites (2.2 x 10{sup 21} sites cm{sup -3}). The implantation experiments show that a non diffusive transport phenomenon (i.e., athermal diffusion) is involved in the material when the helium concentration exceeds 2.3 x 10{sup 21} He cm{sup -3}, and thus probably as soon as it exceeds the density of solubility sites accessible to helium in the glass. We propose that this transport mechanism could be associated with the relaxation of the stress gradient induced by the implanted helium profile, which is favored by the glass damage. Microstructural characterization by TEM and ESEM of glass specimens implanted with high helium concentrations showed a homogeneous microstructure free of bubbles, pores, or cracking at a scale of 10 nm. (authors)


    SciTech Connect

    Becker, Andreas; Lorenzen, Winfried; Schöttler, Manuel; Redmer, Ronald; Fortney, Jonathan J.; Nettelmann, Nadine


    We present new equations of state (EOSs) for hydrogen and helium covering a wide range of temperatures from 60 K to 10{sup 7} K and densities from 10{sup –10} g cm{sup –3} to 10{sup 3} g cm{sup –3}. They include an extended set of ab initio EOS data for the strongly correlated quantum regime with an accurate connection to data derived from other approaches for the neighboring regions. We compare linear mixing isotherms based on our EOS tables with available real mixture data. A first important astrophysical application of this new EOS data is the calculation of interior models for Jupiter and comparison with recent results. Second, mass-radius relations are calculated for Brown Dwarfs (BDs) which we compare with predictions derived from the widely used EOS of Saumon, Chabrier, and van Horn. Furthermore, we calculate interior models for typical BDs with different masses, namely, Corot-3b, Gliese-229b, and Corot-15b, and the giant planet KOI-889b. The predictions for the central pressures and densities differ by up to 10% dependent on the EOS used. Our EOS tables are made available in the supplemental material of this paper.


    SciTech Connect

    Krucker, Saem; Raftery, Claire L.; Hudson, Hugh S.


    We report on Transition Region And Coronal Explorer 171 A observations of the GOES X20 class flare on 2001 April 2 that shows EUV flare ribbons with intense diffraction patterns. Between the 11th to 14th order, the diffraction patterns of the compact flare ribbon are dispersed into two sources. The two sources are identified as emission from the Fe IX line at 171.1 A and the combined emission from Fe X lines at 174.5, 175.3, and 177.2 A. The prominent emission of the Fe IX line indicates that the EUV-emitting ribbon has a strong temperature component near the lower end of the 171 A temperature response ({approx}0.6-1.5 MK). Fitting the observation with an isothermal model, the derived temperature is around 0.65 MK. However, the low sensitivity of the 171 A filter to high-temperature plasma does not provide estimates of the emission measure for temperatures above {approx}1.5 MK. Using the derived temperature of 0.65 MK, the observed 171 A flux gives a density of the EUV ribbon of 3 x 10{sup 11} cm{sup -3}. This density is much lower than the density of the hard X-ray producing region ({approx}10{sup 13} to 10{sup 14} cm{sup -3}) suggesting that the EUV sources, though closely related spatially, lie at higher altitudes.

  19. Design of a 10**36 CM-2 S-1 Super-B Factory

    SciTech Connect

    Biagini, M.E.; Boni, R.; Boscolo, M.; Demma, T.; Drago, A.; Guiducci, S.; Raimondi, P.; Tomassini, S.; Zobov, M.; Bertsche, Kirk J.; Novokhatski, A.; Seeman, J.; Sullivan, M.; Wienands, U.; Wittmer, W.; Bettoni, S.; Paoloni, E.; Marchiori, G.; Bogomyagkov, A.; Koop, I.; Levichev, E.; /Novosibirsk, IYF


    Parameters have been studied for a high luminosity e{sup +}e{sup -} collider operating at the Upsilon 4S that would deliver a luminosity of 1 to 4 x 10{sup 36}/cm{sup 2}/s. This collider, called a Super-B Factory, would use a combination of linear collider and storage ring techniques. In this scheme an electron beam and a positron beam are stored in low-emittance damping rings similar to those designed for a Linear Collider (LC) or the next generation light source. A LC style interaction region is included in the ring to produce sub-millimeter vertical beta functions at the collision point. A large crossing angle (+/- 24 mrad) is used at the collision point to allow beam separation. A crab-waist scheme is used to reduce the hourglass effect and restore peak luminosity. Beam currents of 1.8 A at 4 x 7 GeV in 1251 bunches can produce a luminosity of 10{sup 36}/cm{sup 2}/s with upgrade possibilities. Such a collider would produce an integrated luminosity of about 10,000 fb{sup -1} (10 ab{sup -1}) in a running year (10{sup 7} sec) at the {gamma}(4S) resonance. Further possibilities include having longitudinally polarized e- at the IR and operating at the J/Psi and Psi beam energies.

  20. Magnetic relaxation in dysprosium-dysprosium collisions

    SciTech Connect

    Newman, Bonna K.; Johnson, Cort; Kleppner, Daniel; Greytak, Thomas J.; Brahms, Nathan; Au, Yat Shan; Connolly, Colin B.; Doyle, John M.


    The collisional magnetic reorientation rate constant g{sub R} is measured for magnetically trapped atomic dysprosium (Dy), an atom with large magnetic dipole moments. Using buffer gas cooling with cold helium, large numbers (>10{sup 11}) of Dy are loaded into a magnetic trap and the buffer gas is subsequently removed. The decay of the trapped sample is governed by collisional reorientation of the atomic magnetic moments. We find g{sub R}=1.9{+-}0.5x10{sup -11} cm{sup 3} s{sup -1} at 390 mK. We also measure the magnetic reorientation rate constant of holmium (Ho), another highly magnetic atom, and find g{sub R}=5{+-}2x10{sup -12} cm{sup 3} s{sup -1} at 690 mK. The Zeeman relaxation rates of these atoms are greater than expected for the magnetic dipole-dipole interaction, suggesting that another mechanism, such as an anisotropic electrostatic interaction, is responsible. Comparison with estimated elastic collision rates suggests that Dy is a poor candidate for evaporative cooling in a magnetic trap.

  1. Ozone production at the National Synchrotron Light Source

    SciTech Connect

    Weilandics, C.; Rohrig, N.; Gmur, N.F.


    Ozone production by synchrotron radiation as a function of power density in air was investigated using a white beam at the BNL National Synchrotron Light Source (NSLS) x-ray ring. Power densities were calculated from the energy spectrum at 2.52 GeV. Ozone concentrations in small beam pipes were measured for power densities between I = 10/sup 12/ and 10/sup 15/ eV . cm/sup -3/ . sec/sup -1/. The measured ozone half-life was 37 +- 2 min. The measured G-value was 2.69 +- 0.14 mol/100 eV and the ozone destruction factor k was less than 7 x 10/sup -19/ cm/sup 3/ . eV/sup -1/. The random uncertainties stated are approximately one standard error. The large departure of the values for G and k from previous values suggest that some undiscovered systematic error may exist in the experiment. Ozone concentration in excess of the 0.1 ppM ACGIH TLV can be generated in the experimental hutches but can readily be controlled. Industrial hygiene aspects of operation and possible control measures will be discussed. 19 refs., 7 figs., 3 tabs.

  2. Neutrino-induced deuteron disintegration experiment

    SciTech Connect

    Riley, S.P.; Greenwood, Z.D.; Kropp, W.R.; Price, L.R.; Reines, F.; Sobel, H.W.; Declais, Y.; Etenko, A.; Skorokhvatov, M.


    Cross sections for the disintegration of the deuteron via neutral-current (NCD) and charged-current (CCD) interactions with reactor antineutrinos ({bar {nu}}{sub e}d{r_arrow}{bar {nu}}{sub e}pn and {bar {nu}}{sub e}d{r_arrow}e{sup +}nn) are measured to be 6.08{plus_minus}0.77{times}10{sup {minus}45} cm{sup 2} and 9.83{plus_minus}2.04{times}10{sup {minus}45} cm{sup 2} per neutrino, respectively, in excellent agreement with current calculations. Since the experimental NCD value depends upon the CCD value, if we use the theoretical value for the CCD reaction, we obtain the improved value of 5.98{plus_minus}0.54{times}10{sup {minus}45} for the NCD cross section. The neutral-current reaction allows a unique measurement of the isovector{endash}axial vector coupling constant in the hadronic weak interaction, {beta}. In the standard model, this constant is predicted to be exactly 1, independent of the Weinberg angle. We measure a value of {beta}{sup 2}=1.01{plus_minus}0.16. Using the above improved value for the NCD cross section, {beta}{sup 2} becomes 0.99{plus_minus}0.10. {copyright} {ital 1999} {ital The American Physical Society}

  3. Measurement of the Flux and Zenith-Angle Distribution of Upward Throughgoing Muons by Super-Kamiokande

    SciTech Connect

    Fukuda, Y.; Hayakawa, T.; Ichihara, E.; Inoue, K.; Ishihara, K.; Ishino, H.; Itow, Y.; Kajita, T.; Kameda, J.; Kasuga, S.; Kobayashi, K.; Kobayashi, Y.; Koshio, Y.; Miura, M.; Nakahata, M.; Nakayama, S.; Okada, A.; Okumura, K.; Sakurai, N.; Shiozawa, M.; Suzuki, Y.; Takeuchi, Y.; Totsuka, Y.; Yamada, S.; Earl, M.; Habig, A.; Kearns, E.; Messier, M.D.; Scholberg, K.; Stone, J.L.; Sulak, L.R.; Walter, C.W.; Goldhaber, M.; Barszczak, T.; Casper, D.; Gajewski, W.; Kropp, W.R.; Price, L.R.; Reines, F.; Smy, M.; Sobel, H.W.; Vagins, M.R.; Haines, T.J.; Kielczewska, D.; Ganezer, K.S.; Keig, W.E.; Ellsworth, R.W.; Tasaka, S.; Flanagan, J.W.; Kibayashi, A.; Learned, J.G.; Matsuno, S.; Stenger, V.J.; Takemori, D.; Ishii, T.; Kanzaki, J.; Kobayashi, T.; Mine, S.; Nakamura, K.; Nishikawa, K.; Oyama, Y.; Sakai, A.; Sakuda, M.; Sasaki, O.; Echigo, S.; Kohama, M.; Suzuki, A.T.; Haines, T.J.; Blaufuss, E.; Kim, B.K.; and others


    A total of 614 upward throughgoing muons of minimum energy 1.6thinspthinspGeV are observed by Super-Kamiokande during 537 detector live days. The measured muon flux is [1.74{plus_minus}0.07(stat){plus_minus} 0.02(sys)]{times}10{sup {minus}13} cm{sup {minus}2}thinsps{sup {minus}1}thinspsr{sup {minus}1} compared to an expected flux of [1.97{plus_minus}0.44(theor)]{times} 10{sup {minus}13} cm{sup {minus}2}thinsps{sup {minus}1}thinspsr{sup {minus}1} . The absolute measured flux is in agreement with the prediction within the errors. However, the zenith-angle dependence of the observed upward throughgoing muon flux does not agree with no-oscillation predictions. The observed distortion in shape is consistent with the {nu}{sub {mu}}{leftrightarrow}{nu}{sub {tau}} oscillation hypothesis with sin{sup 2}thinsp2{theta} {gt}0.4 and 1{times}10{sup {minus}3}{lt}{Delta}m{sup 2}{lt}1{times}1 0{sup {minus}1} eV{sup 2} at 90{percent} confidence level. {copyright} {ital 1999} {ital The American Physical Society}

  4. Voltammetry and conductivity of a polyether-pyridinium room temperature molten salt electrolyte and of its polymer electrolyte solutions in polydimethylsiloxane

    SciTech Connect

    Pyati, R.; Murray, R.W.


    This report describes the synthesis, microelectrode voltammetry, and ionic conductivity of a new room temperature molten salt N-(methoxy(ethoxy){sub 2}ethyl)pyridinium p-toluene sulfonate (abbreviated as[Py(E{sub 3}M){sup +}][Tos{sup {minus}}]) and of its solution in a hydroxy-terminated polydimethylsiloxane. Both ionically conductive liquids (conductivity = 1 {times} 10{sup {minus}4} {Omega}{sup {minus}1} cm{sup {minus}1}) exhibit voltammetric potential windows of about 1.5 V. The negative potential limit is determined by the reduction of the [Py(E{sub 3}M){sup +}] pyridinium species, with subsequent radical coupling to form a voltammetrically observed viologen dimer. The estimated diffusivities of the [Py(E{sub 3}M){sup +}] species, of a diethyleneglycol-tailed ferrocene redox solute studied, and by application of Nernst-Einstein relation to the ionic charge carriers, all lie in the 10{sup {minus}7} to 10{sup {minus}8} cm{sup 2}/s range. Viscosities and glass transition thermal observations are reported as is the fit of the temperature dependencies of ionic conductivity in [Py(E{sub 3}M){sup +}][Tos{sup {minus}}] and in [Py(E{sub 3}M){sup +}][TOS{sup {minus}}]/PDMS mixtures to Vogel-Tamman-Fulcher predictions.

  5. Potential chlorofluorocarbon replacements: OH reaction rate constants between 250 and 315 K and infrared absorption spectra

    SciTech Connect

    Garland, N.L.; Medhurst, L.J.; Nelson, H.H.


    The authors measured the rate constant for reactions of the OH radical with several potential chlorofluorocarbon replacements over the temperature range 251-314 K using laser photolysis laser-induced fluorescence techniques. The compounds studied and Arrhenius parameters determined from fits to the measured rate constants are as follows: CHF{sub 2}OCHF{sub 2} (E 134), k(T) = (5.4 {+-} 3.5) x 10{sup {minus}13} cm{sup 3} s{sup {minus}1} exp [({minus}3.1 {+-} 0.4 kcal mol{sup {minus}1})/RT]; CF{sub 3}CH{sub 2}CF{sub 3} (FC 236fa), k(T) = (2.0 {+-} 1.0) x 10{sup {minus}14} cm{sup 3} s{sup {minus}1} exp [({minus}1.8 {+-} 0.3 kcal mol{sup {minus}1})/RT]; CF{sub 3}CHFCHF{sub 2} (FC 236ea), k(T) = (2.0 {+-} 0.9) x 10{sup {minus}13} cm{sup 3} s{sup {minus}1} exp [({minus}2.0 {+-} 0.3 kcal mol{sup {minus}1})/RT]; and CF{sub 3}CF{sub 2}CH{sub 2}F (FC 236cb), k(T) = (2.6 {+-} 1.6) x 10{sup {minus}13} cm{sup 3} s{sup {minus}1} exp [({minus}2.2 {+-} 0.4 kcal mol{sup {minus}1})/RT]. The measured activation energies (2-3 kcal mol{sup {minus}1}) are consistent with a mechanism of H atom abstraction. The tropospheric lifetimes, estimated from the measured OH reaction rates, and measured integrated infrared absorption cross sections over the range 770 to 1430 cm{sup {minus}1} suggest that E 134 and FC 236fa may have significant global warming potential, while FC 236ea and FC 236cb do not. 17 refs., 4 figs., 3 tabs.


    SciTech Connect

    Smillie, D. G.; Pickering, J. C.; Nave, G.; Smith, P. L.


    The spectrum of Co iii has been recorded in the region 1562–2564 Å (64,000 cm{sup −1}–39,000 cm{sup −1}) by Fourier transform (FT) spectroscopy, and in the region 1317–2500 Å (164,000 cm{sup −1}–40,000 cm{sup −1}) using a 10.7 m grating spectrograph with phosphor image plate detectors. The spectrum was excited in a cobalt–neon Penning discharge lamp. We classified 514 Co iii lines measured using FT spectroscopy, the strongest having wavenumber uncertainties approaching 0.004 cm{sup −1} (approximately 0.2 mÅ at 2000 Å, or 1 part in 10{sup 7}), and 240 lines measured with grating spectroscopy with uncertainties between 5 and 10 mÅ. The wavelength calibration of 790 lines of Raassen and Ortí Ortin and 87 lines from Shenstone has been revised and combined with our measurements to optimize the values of all but one of the 288 previously reported energy levels. Order of magnitude reductions in uncertainty for almost two-thirds of the 3d{sup 6}4s and almost half of the 3d{sup 6}4p revised energy levels are obtained. Ritz wavelengths have been calculated for an additional 100 forbidden lines. Eigenvector percentage compositions for the energy levels and predicted oscillator strengths have been calculated using the Cowan code.

  7. Transport properties of undoped and Br-doped PbTe sintered at high-temperature and pressure >=4.0 GPa

    SciTech Connect

    Dong, Yongkwan; McGuire, Michael A.; Malik, Abds-Sami; DiSalvo, Francis J.


    The thermoelectric properties of nominally undoped PbTe and Br doped PbTe materials sintered at high-pressure and high-temperature (HPHT) have been studied. All samples show n-type semiconducting behavior with negative thermopower. For undoped PbTe, four different HPHT treatments were performed at pressures between 4.0 and 6.5 GPa. PbTe doped with Br at 0.5, 1.0, 2.0, 3.0x10{sup 19} cm{sup -3} was HPHT treated at 4.0 GPa and 1045 deg. C. As the dopant concentration increases, the absolute thermopower decreases, thermal conductivity increases, and electrical resistivity decreases. At a nominal dopant concentration of 1.0x10{sup 19} cm{sup -3}, carrier mobility of 1165 cm{sup 2}/V s and dimensionless thermoelectric figure-of-merit, ZT, of around 0.27 at 300 K were obtained. These results demonstrate that HPHT post-processing is a viable and controllable way of tuning the thermoelectric properties of PbTe-based materials. - Abstract: The effect, on thermoelectric properties, of sintering undoped and Br doped PbTe at pressures >=4.0 GPa and 1045 deg. C are reported and compared with conventionally sintered materials. Display Omitted

  8. Transport properties of undoped and Br-doped PbTe sintered at high temperature and pressure> 4.0 GPa

    SciTech Connect

    Yongkwan, Dong; McGuire, Michael A; Malik, Abds-Sami; DiSalvo, Francis J.


    The thermoelectric properties of nominally undoped PbTe and Br doped PbTe materials sintered at high-pressure and high-temperature (HPHT) have been studied. All samples show n-type semiconducting behavior with negative thermopower. For undoped PbTe, four different HPHT treatments were performed at pressures between 4.0 and 6.5 GPa. PbTe doped with Br at 0.5, 1.0, 2.0, 3.0 x 10{sup 19} cm{sup -3} was HPHT treated at 4.0 GPa and 1045 C. As the dopant concentration increases, the absolute thermopower decreases, thermal conductivity increases, and electrical resistivity decreases. At a nominal dopant concentration of 1.0 x 10{sup 19} cm{sup -3}, carrier mobility of 1165 cm{sup 2}/V s and dimensionless thermoelectric figure-of-merit, ZT, of around 0.27 at 300 K were obtained. These results demonstrate that HPHT post-processing is a viable and controllable way of tuning the thermoelectric properties of PbTe-based materials.

  9. Characterization of liquid phase epitaxial GaAs forblocked-impurity-band far-infrared detectors

    SciTech Connect

    Cardozo, B.L.; Reichertz, L.A.; Beeman, J.W.; Haller, E.E.


    GaAs Blocked-Impurity-Band (BIB) photoconductor detectors have the potential to become the most sensitive, low noise detectors in the far-infrared below 45.5 cm{sup -1} (220 {micro}m). We have studied the characteristics of liquid phase epitaxial GaAs films relevant to BIB production, including impurity band formation and the infrared absorption of the active section of the device. Knowledge of the far-infrared absorption spectrum as a function of donor concentration combined with variable temperature Hall effect and resistivity studies leads us to conclude that the optimal concentration for the absorbing layer of a GaAs BIB detector lies between 1 x 10{sup 15} and 6.7 x 10{sup 15} cm{sup -3}. At these concentrations there is significant wavefunction overlap which in turn leads to absorption beyond the 1s ground to 2p bound excited state transition of 35.5 cm{sup -1} (282 {micro}m). There still remains a gap between the upper edge of the donor band and the bottom of the conduction band, a necessity for proper BIB detector operation.

  10. Rotational relaxation of CS by collision with ortho- and para-H{sub 2} molecules

    SciTech Connect

    Denis-Alpizar, Otoniel; Stoecklin, Thierry Halvick, Philippe; Dubernet, Marie-Lise


    Quantum mechanical investigation of the rotationally inelastic collisions of CS with ortho- and para-H{sub 2} molecules is reported. The new global four-dimensional potential energy surface presented in our recent work is used. Close coupling scattering calculations are performed in the rigid rotor approximation for ortho- and para-H{sub 2} colliding with CS in the j = 0–15 rotational levels and for collision energies ranging from 10{sup −2} to 10{sup 3} cm{sup −1}. The cross sections and rate coefficients for selected rotational transitions of CS are compared with the ones previously reported for the collision of CS with He. The largest discrepancies are observed at low collision energy, below 1 cm{sup −1}. Above 10 cm{sup −1}, the approximation using the square root of the relative mass of the colliders to calculate the cross sections between a molecule and H{sub 2} from the data available with {sup 4}He is found to be a good qualitative approximation. The rate coefficients calculated with the electron gas model for the He-CS system show more discrepancy with our accurate results. However, scaling up these rates by a factor of 2 gives a qualitative agreement.

  11. Raman Spectroscopy Characterization of Se- Doped Bi{sub 12}SiO{sub 20} Crystals

    SciTech Connect

    Milenov, T. I.; Rafailov, P. M.; Yankova, L.; Veleva, M. N.; Dobreva, S.; Thomsen, C.; Egorysheva, A. V.; Skorikov, V. M.; Titorenkova, R.


    Crystals of BSO doped with Se are successfully grown by the Czochralski method. The measured concentration of Se is 1.75x10{sup 18} cm{sup -3} and of Fe is 6.4x10{sup 18} cm{sup -3}, i.e. the concentration of Fe is significantly increased. It is assumed that the doping takes place through the replacement 3Si{sup 4+}->(Se{sup 6+}+2Fe{sup 3+}). The doping-induced shift of the Raman-active A, E and F-modes is not significant and it is concluded that the lattice distortions caused by doping are very small in BSO crystals doped with Se at low concentrations. The doping with Se at high concentration leads to occasional second phase inclusions. It is observed that all A, E and F- modes in the Raman spectrum are downshifted with 2-5 cm{sup -1}. It is concluded that the doping with Se at high concentrations follows the same mechanism as those with low concentrations but the introduced lattice distortions are more significant.

  12. Investigation of free charge carrier dynamics in single-crystalline CVD diamond by two-photon absorption

    SciTech Connect

    Ivakin, E V; Kisialiou, I G; Ralchenko, V G; Bolshakov, A P; Ashkinazi, E E; Sharonov, G V


    By using the methods of transient gratings (TGs) and induced absorption, we have studied the kinetics of plasma of free charge carriers (FCCs) created by the action of a picosecond laser pulse in two high-purity diamond single crystals synthesised from the gas phase. The gratings with different spatial periods have been excited at the wavelengths of 266 or 213 nm (above and below the fundamental absorption edge in diamond) and probed with continuous-wave radiation in the visible region. At the moderate FCC concentrations (∼7 × 10{sup 17} cm{sup -3}), the coefficient of ambipolar diffusion and the carrier recombination time of two crystals are 20.3 and 18.9 cm{sup 2} s{sup -1} and 30 and 190 ns, respectively. The increase in the carrier concentration up to 5 × 10{sup 19} cm{sup -3} reduces the TG lifetime. We have determined the conditions under which the relaxation of the grating of carriers leads to the formation of a thermal grating, with the amplitude sufficient for its experimental observation. (interaction of laser radiation with matter. laser plasma)

  13. Intercomparison of four methods to determine size distributions of low-concentration (approximately 100 cm[sup [minus]3]), ultrafine aerosols (3 < D[sub p] < 10 nm) with illustrative data from the Arctic

    SciTech Connect

    Wiedensohler, A. ); Aalto, P. ); Covert, D. ); Heintzenberg, J. ); McMurry, P.H. )


    Four different methods for measuring ultrafine particle size distributions in the 3-10-nm particle diameter range are compared and discussed. These methods all use an ultrafine condensation particle counter (TSI Inc. Model 3025 or its prototype) as the detector, but use different approaches to determine the size of the particles counted. Size classification was achieved using a Hauke Model VIE-06 differential mobility analyzer, a specially configured TSI Model 3040S diffusion battery, an ultrafine condensation particle counter with a variable condenser temperature, and an ultrafine condensation particle counter with a pulse height analyzer for signals produced by the optical detector. The response of these systems to ultrafine particles of known size and composition was studied during a workshop held in Lund, Sweden, during July 1991. After this workshop, measurements of ultrafine particles were made on the Swedish icebreaker Oden during the International Arctic Ocean Expedition 1991 (August 1, 1991 through October 7, 1991). In this article, the results of these laboratory and field measurements are discussed. The strengths and limitations of these measurement methods are emphasized. 30 refs., 9 figs., 3 tabs.


    SciTech Connect

    Codella, C.; Fontani, F.; Vasta, M.; Ceccarelli, C.; Lefloch, B.; Kahane, C.; Taquet, V.; Wiesenfeld, L.; Caselli, P.; Lis, D.; Viti, S.


    We present the first study of deuteration toward the protostellar shock L1157-B1, based on spectral surveys performed with the Herschel-HIFI and IRAM 30 m telescopes. The L1157 outflow is driven by a low-mass Class 0 protostar and is considered the prototype of the so-called chemically active outflows. The young (2000 yr), bright blueshifted bow shock, B1, is an ideal laboratory for studying the gas chemically enriched by the release of dust mantles due to the passage of a shock. A total of 12 emission lines (up to E{sub u} = 63 K) of CH{sub 2}DOH, HDCO, and DCN are detected. In addition, two lines of NH{sub 2}D and HDO are tentatively reported. To estimate the deuteration, we also extracted from our spectral survey emission lines of non-deuterated isotopologues ({sup 13}CH{sub 3}OH, H{sub 2} {sup 13}CO, H{sup 13}CN, H{sub 2} {sup 13}CO, and NH{sub 3}). We infer higher deuteration fractions for CH{sub 3}OH (D/H = 0.2-2 Multiplication-Sign 10{sup -2}) and H{sub 2}CO (5-8 Multiplication-Sign 10{sup -3}) than for H{sub 2}O (0.4-2 Multiplication-Sign 10{sup -3}), HCN ({approx}10{sup -3}), and ammonia ({<=}3 Multiplication-Sign 10{sup -2}). The measurement of deuteration of water, formaldehyde, and methanol in L1157-B1 provides a fossil record of the gas before it was shocked by the jet driven by the protostar. A comparison with gas-grain models indicates that the gas passed through a low-density ({<=}10{sup 3} cm{sup -3}) phase, during which the bulk of water ices formed, followed by a phase of increasing density, up to 3 Multiplication-Sign 10{sup 4} cm{sup -3}, during which formaldehyde and methanol ices formed.


    SciTech Connect

    Hollenbach, David; Elitzur, Moshe; McKee, Christopher F.


    We present a model in which the 22 GHz H{sub 2}O masers observed in star-forming regions occur behind shocks propagating in dense regions (preshock density n{sub 0} {approx} 10{sup 6}-10{sup 8} cm{sup -3}). We focus on high-velocity (v{sub s} {approx}> 30 km s{sup -1}) dissociative J shocks in which the heat of H{sub 2} re-formation maintains a large column of {approx}300-400 K gas; at these temperatures the chemistry drives a considerable fraction of the oxygen not in CO to form H{sub 2}O. The H{sub 2}O column densities, the hydrogen densities, and the warm temperatures produced by these shocks are sufficiently high to enable powerful maser action. The observed brightness temperatures (generally {approx} 10{sup 11}-10{sup 14} K) are the result of coherent velocity regions that have dimensions in the shock plane that are 10-100 times the shock thickness of {approx}10{sup 13} cm. The masers are therefore beamed toward the observer, who typically views the shock ''edge-on'', or perpendicular to the shock velocity; the brightest masers are then observed with the lowest line-of-sight velocities with respect to the ambient gas. We present numerical and analytic studies of the dependence of the maser inversion, the resultant brightness temperature, the maser spot size and shape, the isotropic luminosity, and the maser region magnetic field on the shock parameters and the coherence path length; the overall result is that in galactic H{sub 2}O 22 GHz masers, these observed parameters can be produced in J shocks with n{sub 0} {approx} 10{sup 6}-10{sup 8} cm{sup -3} and v{sub s} {approx} 30-200 km s{sup -1}. A number of key observables such as maser shape, brightness temperature, and global isotropic luminosity depend only on the particle flux into the shock, j = n{sub 0} v{sub s} , rather than on n{sub 0} and v{sub s} separately.

  16. Investigation on the long-term radiation hardness of low resistivity starting silicon materials for RT silicon detectors in high energy physics

    SciTech Connect

    Li, Z.


    Relatively low resistivity (200 to 1000 {Omega}-cm) starting silicon materials have been studied in the search of room temperature neutron radiation-hard silicon detectors. It has been found that, moderate resistivity (300-700 {Omega}-cm) silicon detectors, after being irradiated to 5.0 {times} 10{sup 13} to 2.0 {times} 10{sup 14} n/cm{sup 2}, are extremely stable in terms of the detector full depletion voltage (V{sub d}) or the net effective concentration of ionized space charges (N{sub eff} ---- there is little ``reverse annealing`` of N{sub eff} at RT and elevated temperatures as compared with large reverse annealing observed for high resistivity silicon detectors. Detectors with starting resistivity of 300-700 {Omega}-cm have been found to be stable, during the equivalent of one year RT anneal that would reach the saturation of the first stage of reverse anneal, within then N{sub eff} window of {vert_bar}N{sub eff}{vert_bar}{le} 2.5 {times} 10{sup 12} cm{sup {minus}3} (V{sub d} = 180 V for d = 300 {mu}m) in a working range of 5.0 {times} 10{sup 13} to 1.5 {times} 10{sup 14} n/cm{sup 2}, or a net neutron radiation tolerance of 1.0 {times} 10{sup 14} n/cm{sup 2}. The observed effects are in very good agreement with an early proposed model, which predicted among others, that there might be an off set between the reverse annealing effect and the partial annealing of the P-V centers that leads to the partial recovery of the shallow impurity donors.

  17. Magnetic fields in relativistic collisionless shocks

    SciTech Connect

    Santana, Rodolfo; Kumar, Pawan; Barniol Duran, Rodolfo E-mail:


    We present a systematic study on magnetic fields in gamma-ray burst (GRB) external forward shocks (FSs). There are 60 (35) GRBs in our X-ray (optical) sample, mostly from Swift. We use two methods to study ε {sub B} (fraction of energy in magnetic field in the FS): (1) for the X-ray sample, we use the constraint that the observed flux at the end of the steep decline is ≥ X-ray FS flux; (2) for the optical sample, we use the condition that the observed flux arises from the FS (optical sample light curves decline as ∼t {sup –1}, as expected for the FS). Making a reasonable assumption on E (jet isotropic equivalent kinetic energy), we converted these conditions into an upper limit (measurement) on ε {sub B} n {sup 2/(p+1)} for our X-ray (optical) sample, where n is the circumburst density and p is the electron index. Taking n = 1 cm{sup –3}, the distribution of ε {sub B} measurements (upper limits) for our optical (X-ray) sample has a range of ∼10{sup –8}-10{sup –3} (∼10{sup –6}-10{sup –3}) and median of ∼few × 10{sup –5} (∼few × 10{sup –5}). To characterize how much amplification is needed, beyond shock compression of a seed magnetic field ∼10 μG, we expressed our results in terms of an amplification factor, AF, which is very weakly dependent on n (AF∝n {sup 0.21}). The range of AF measurements (upper limits) for our optical (X-ray) sample is ∼1-1000 (∼10-300) with a median of ∼50 (∼50). These results suggest that some amplification, in addition to shock compression, is needed to explain the afterglow observations.

  18. Limits on gamma-ray burst prompt radio emission using the LWA1

    SciTech Connect

    Obenberger, K. S.; Taylor, G. B.; Craig, J.; Dowell, J.; Henning, P. A.; Schinzel, F. K.; Hartman, J. M.; Helmboldt, J. F.; Wilson, T. L.


    As a backend to the first station of the Long Wavelength Array (LWA1), the Prototype All Sky Imager has been imaging the sky > –26° declination during 34 gamma-ray bursts (GRBs) between 2012 January and 2013 May. Using this data, we were able to put the most stringent limits to date on prompt low-frequency emission from GRBs. While our limits depend on the zenith angle of the observed GRB, we estimate a 1σ rms sensitivity of 68, 65, and 70 Jy for 5 s integrations at 37.9, 52.0, and 74.0 MHz at zenith. These limits are relevant for pulses ≥5 s and are limited by dispersion smearing. For 5 s pulses, we are limited to dispersion measures (DMs) ≤ 220, 570, and 1600 pc cm{sup –3} for the frequencies above. For pulses lasting longer than 5 s, the DM limits increase linearly with the duration of the pulse. We also report two interesting transients, which are, as of yet, of unknown origin and are not coincident with any known GRBs. For general transients, we give rate density limits of ≤7.5 × 10{sup –3}, 2.9 × 10{sup –2}, and 1.4 × 10{sup –2} yr{sup –1} deg{sup –2} with pulse energy densities >1.3 × 10{sup –22}, 1.1 × 10{sup –22}, and 1.4 × 10{sup –22} J m{sup –2} Hz{sup –1} and pulse widths of 5 s at the frequencies given above.

  19. Capacitance and conductance versus voltage characterization of Al{sub 2}O{sub 3} layers prepared by plasma enhanced atomic layer deposition at 25 °C≤ T ≤ 200 °C

    SciTech Connect

    Henkel, Karsten Tallarida, Massimo; Schmeißer, Dieter; Gargouri, Hassan; Gruska, Bernd; Arens, Michael


    In this work, plasma enhanced atomic layer deposited (PE-ALD) samples were prepared at substrate temperatures in the range between room temperature (RT) and 200 °C and investigated by capacitance–voltage and conductance–voltage recordings. The measurements are compared to standard thermal atomic layer deposition (T-ALD) at 200 °C. Very low interface state density (D{sub it}) ∼10{sup 11} eV{sup −1} cm{sup −2} could be achieved for the PE-ALD process at 200 °C substrate temperature after postdeposition anneal (PDA) in forming gas at 450 °C. The PDA works very effectively for both the PE-ALD and T-ALD at 200 °C substrate temperature delivering also similar values of negative fixed charge density (N{sub fix}) around −2.5 × 10{sup 12} cm{sup −2}. At the substrate temperature of 150 °C, highest N{sub fix} (−2.9 × 10{sup 12} cm{sup −2}) and moderate D{sub it} (2.7 × 10{sup 11} eV{sup −1} cm{sup −2}) values were observed. The as deposited PE-ALD layer at RT shows both low D{sub it} in the range of (1 to 3) × 10{sup 11} eV{sup −1} cm{sup −2} and low N{sub fix} (−4.4 × 10{sup 11} cm{sup −2}) at the same time. The dependencies of N{sub fix}, D{sub it}, and relative permittivity on the substrate temperatures and its adjustability are discussed.

  20. Extended plasma channels created by UV laser in air and their application to control electric discharges

    SciTech Connect

    Zvorykin, V. D. Ionin, A. A.; Levchenko, A. O.; Seleznev, L. V.; Sinitsyn, D. V.; Smetanin, I. V.; Ustinovskii, N. N.; Shutov, A. V.


    Results are presented from a series of experimental and theoretical studies on creating weakly ionized extended plasma channels in atmospheric air by 248-nm UV laser radiation and their application to control long high-voltage discharges. The main mechanisms of air ionization by UV laser pulses with durations from 100 fs to 25 ns and intensities in the ranges of 3×10{sup 11}–1.5×10{sup 13} and 3×10{sup 6}–3×10{sup 11} W/cm{sup 2}, respectively, which are below the threshold for optical gas breakdown, as well as the main relaxation processes in plasma with a density of 10{sup 9}–10{sup 17} cm{sup −3}, are considered. It is shown that plasma channels in air can be efficiently created by amplitude-modulated UV pulses consisting of a train of subpicosecond pulses producing primary photoelectrons and a long UV pulse suppressing electron attachment and sustaining the density of free electrons in plasma. Different modes of the generation and amplification of trains of subterawatt subpicosecond pulses and amplitude-modulated UV pulses with an energy of several tens of joules were implemented on the GARPUN-MTW hybrid Ti:sapphire-KrF laser facility. The filamentation of such UV laser beams during their propagation in air over distances of up to 100 m and the parameters of the corresponding plasma channels were studied experimentally and theoretically. Laser initiation of high-voltage electric discharges and control of their trajectories by means of amplitude-modulated UV pulses, as well as the spatiotemporal structure of breakdowns in air gaps with length of up to 80 cm, were studied.